Climate change and water table fluctuation: Implications for raised bog surface variability

NASA Astrophysics Data System (ADS)

Taminskas, Julius; Linkevičienė, Rita; Šimanauskienė, Rasa; Jukna, Laurynas; Kibirkštis, Gintautas; Tamkevičiūtė, Marija

2018-03-01

Cyclic peatland surface variability is influenced by hydrological conditions that highly depend on climate and/or anthropogenic activities. A low water level leads to a decrease of peatland surface and an increase of C emissions into the atmosphere, whereas a high water level leads to an increase of peatland surface and carbon sequestration in peatlands. The main aim of this article is to evaluate the influence of hydrometeorological conditions toward the peatland surface and its feedback toward the water regime. A regional survey of the raised bog water table fluctuation and surface variability was made in one of the largest peatlands in Lithuania. Two appropriate indicators for different peatland surface variability periods (increase and decrease) were detected. The first one is an 200 mm y- 1 average net rainfall over a three-year range. The second one is an average annual water depth of 25-30 cm. The application of these indicators enabled the reconstruction of Čepkeliai peatland surface variability during a 100 year period. Processes of peatland surface variability differ in time and in separate parts of peatland. Therefore, internal subbasins in peatland are formed. Subbasins involve autogenic processes that can later affect their internal hydrology, nutrient status, and vegetation succession. Internal hydrological conditions, surface fluctuation, and vegetation succession in peatland subbasins should be taken into account during evaluation of their state, nature management projects, and other peatland research works.

Northwestern Pacific typhoon intensity controlled by changes in ocean temperatures.

PubMed

Mei, Wei; Xie, Shang-Ping; Primeau, François; McWilliams, James C; Pasquero, Claudia

2015-05-01

Dominant climatic factors controlling the lifetime peak intensity of typhoons are determined from six decades of Pacific typhoon data. We find that upper ocean temperatures in the low-latitude northwestern Pacific (LLNWP) and sea surface temperatures in the central equatorial Pacific control the seasonal average lifetime peak intensity by setting the rate and duration of typhoon intensification, respectively. An anomalously strong LLNWP upper ocean warming has favored increased intensification rates and led to unprecedentedly high average typhoon intensity during the recent global warming hiatus period, despite a reduction in intensification duration tied to the central equatorial Pacific surface cooling. Continued LLNWP upper ocean warming as predicted under a moderate [that is, Representative Concentration Pathway (RCP) 4.5] climate change scenario is expected to further increase the average typhoon intensity by an additional 14% by 2100.

78 FR 10262 - Railroad Cost Recovery Procedures-Productivity Adjustment

Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-13

... Cost Recovery Procedures--Productivity Adjustment AGENCY: Surface Transportation Board, DOT. ACTION: Proposed railroad cost recovery procedures productivity adjustment. SUMMARY: In a decision served on... productivity for the 2007-2011 (5-year) averaging period. This represents a 0.1% increase over the average for...

Numerical ages of Holocene tributary debris fans inferred from dissolution pitting on carbonate boulders in the Grand Canyon of Arizona

USGS Publications Warehouse

Hereford, R.; Thompson, K.S.; Burke, K.J.

1998-01-01

Carbonate boulders transported down steep tributary channels by debris flow came to rest on Holocene debris fans beside the Colorado River in Grand Canyon National Park. Weakly acidic rainfall and the metabolic activity of blue-green algae have produced roughly hemispheric dissolution pits as much as 2-cm deep on the initially smooth surfaces of the boulders. The average depth of dissolution pits increases with relative age of fan surfaces. The deepening rate averages 2.4 mm/1000 yr (standard error = 0.2 mm/1000 yr), as calculated from several radiometrically dated surfaces and an archeological structure. This linear rate, which appears constant over at least the past 3000 yr, is consistent with field relations limiting the maximum age of the fans and with the physical chemistry of limestone dissolution. Dissolution-pit measurements (n = 6973) were made on 617 boulders on 71 fan surfaces at the 26 largest debris fans in Grand Canyon. Among these fan surfaces, the average pit depth ranges from 1.2 to 17.4 mm, and the resulting pit dissolution ages range from 500 to 7300 cal yr B.P. Most (75%) surfaces are younger than 3000 yr, probably because of removal of older debris fans by the Colorado River. Many of the ages are close to 800, 1600, 2300, 3100, or 4300 cal yr B.P. If not the result of differential preservation of fan surfaces, this clustering implies periods of heightened debris-flow activity and increased precipitation.

Will surface winds weaken in response to global warming?

NASA Astrophysics Data System (ADS)

Ma, Jian; Foltz, Gregory R.; Soden, Brian J.; Huang, Gang; He, Jie; Dong, Changming

2016-12-01

The surface Walker and tropical tropospheric circulations have been inferred to slow down from historical observations and model projections, yet analysis of large-scale surface wind predictions is lacking. Satellite measurements of surface wind speed indicate strengthening trends averaged over the global and tropical oceans that are supported by precipitation and evaporation changes. Here we use corrected anemometer-based observations to show that the surface wind speed has not decreased in the averaged tropical oceans, despite its reduction in the region of the Walker circulation. Historical simulations and future projections for climate change also suggest a near-zero wind speed trend averaged in space, regardless of the Walker cell change. In the tropics, the sea surface temperature pattern effect acts against the large-scale circulation slow-down. For higher latitudes, the surface winds shift poleward along with the eddy-driven mid-latitude westerlies, resulting in a very small contribution to the global change in surface wind speed. Despite its importance for surface wind speed change, the influence of the SST pattern change on global-mean rainfall is insignificant since it cannot substantially alter the global energy balance. As a result, the precipitation response to global warming remains ‘muted’ relative to atmospheric moisture increase. Our results therefore show consistency between projections and observations of surface winds and precipitation.

Effect of calcination temperatures on microstructures and photocatalytic activity of tungsten trioxide hollow microspheres.

PubMed

Yu, Jiaguo; Qi, Lifang; Cheng, Bei; Zhao, Xiufeng

2008-12-30

Tungsten trioxide hollow microspheres were prepared by immersing SrWO4 microspheres in a concentrated HNO3 solution, and then calcined at different temperatures. The prepared tungsten oxide samples were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, Fourier transform infrared spectra, differential thermal analysis-thermogravimetry, UV-visible spectrophotometry, scanning electron microscopy, N2 adsorption/desorption measurements. The photocatalytic activity of the samples was evaluated by photocatalytic decolorization of rhodamine B aqueous solution under visible-light irradiation. It was found that with increasing calcination temperatures, the average crystallite size and average pore size increased, on the contrary, Brunauer-Emmett-Teller-specific surface areas decreased. However, pore volume and porosity increased firstly, and then decreased. Increasing calcination temperatures resulted in the changes of surface morphology of hollow microspheres. The un-calcined and 300 degrees C-calcined samples showed higher photocatalytic activity than other samples. At 400 degrees C, the photocatalytic activity decreased greatly due to the decrease of specific surface areas. At 500 degrees C, the photocatalytic activity of the samples increased again due to the junction effect of two phases.

Combustion characteristics of paper and sewage sludge in a pilot-scale fluidized bed.

PubMed

Yu, Yong-Ho; Chung, Jinwook

2015-01-01

This study characterizes the combustion of paper and sewage sludge in a pilot-scale fluidized bed. The highest temperature during combustion within the system was found at the surface of the fluidized bed. Paper sludge containing roughly 59.8% water was burned without auxiliary fuel, but auxiliary fuel was required to incinerate the sewage sludge, which contained about 79.3% water. The stability of operation was monitored based on the average pressure and the standard deviation of pressure fluctuations. The average pressure at the surface of the fluidized bed decreased as the sludge feed rate increased. However, the standard deviation of pressure fluctuations increased as the sludge feed rate increased. Finally, carbon monoxide (CO) emissions decreased as oxygen content increased in the flue gas, and nitrogen oxide (NOx) emissions were also tied with oxygen content.

Study of the correlation parameters of the surface structure of disordered semiconductors by the two-dimensional DFA and average mutual information methods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alpatov, A. V.; Vikhrov, S. P.; Rybina, N. V., E-mail: pgnv@mail.ru

The processes of self-organization of the surface structure of hydrogenated amorphous silicon are studied by the methods of fluctuation analysis and average mutual information on the basis of atomic-force-microscopy images of the surface. It is found that all of the structures can be characterized by a correlation vector and represented as a superposition of harmonic components and noise. It is shown that, under variations in the technological parameters of the production of a-Si:H films, the correlation properties of their structure vary as well. As the substrate temperature is increased, the formation of structural irregularities becomes less efficient; in this case,more » the length of the correlation vector and the degree of structural ordering increase. It is shown that the procedure based on the method of fluctuation analysis in combination with the method of average mutual information provides a means for studying the self-organization processes in any structures on different length scales.« less

Large-scale effects on the regulation of tropical sea surface temperature

NASA Technical Reports Server (NTRS)

Hartmann, Dennis L.; Michelsen, Marc L.

1993-01-01

The dominant terms in the surface energy budget of the tropical oceans are absorption of solar radiation and evaporative cooling. If it is assumed that relative humidity in the boundary layer remains constant, evaporative cooling will increase rapidly with sea surface temperature (SST) because of the strong temperature dependence of saturation water vapor pressure. The resulting stabilization of SST provided by evaporative cooling is sufficient to overcome positive feedback contributed by the decrease of surface net longwave cooling with increasing SST. Evaporative cooling is sensitive to small changes in boundary-layer relative humidity. Large and negative shortwave cloud forcing in the regions of highest SST are supported by the moisture convergence associated with largescale circulations. In the descending portions of these circulations the shortwave cloud forcing is suppressed. When the effect of these circulations is taken into account by spatial averaging, the area-averaged cloud forcing shows no sensitivity to area-averaged SST changes associated with the 1987 warming event in the tropical Pacific. While the shortwave cloud forcing is large and important in the convective regions, the importance of its role in regulating the average temperature of the tropics and in modulating temperature gradients within the tropics is less clear. A heuristic model of SST is used to illustrate the possible role of large-scale atmospheric circulations on SST in the tropics and the coupling between SST gradients and mean tropical SST. The intensity of large-scale circulations responds sensitivity to SST gradients and affects the mean tropical SST by supplying dry air to the planetary boundary layer. Large SST gradients generate vigorous circulations that increase evaporation and reduce the mean SST.

Behavior of aircraft antiskid braking systems on dry and wet runway surfaces - A velocity-rate-controlled, pressure-bias-modulated system

NASA Technical Reports Server (NTRS)

Stubbs, S. M.; Tanner, J. A.

1976-01-01

During maximum braking the average ratio of drag-force friction coefficient developed by the antiskid system to maximum drag-force friction coefficient available at the tire/runway interface was higher on dry surfaces than on wet surfaces. The gross stopping power generated by the brake system on the dry surface was more than twice that obtained on the wet surfaces. With maximum braking applied, the average ratio of side-force friction coefficient developed by the tire under antiskid control to maximum side-force friction available at the tire/runway interface of a free-rolling yawed tire was shown to decrease with increasing yaw angle. Braking reduced the side-force friction coefficient on a dry surface by 75 percent as the wheel slip ratio was increased to 0.3; on a flooded surface the coefficient dropped to near zero for the same slip ratio. Locked wheel skids were observed when the tire encountered a runway surface transition from dry to flooded, due in part to the response time required for the system to sense abrupt changes in the runway friction; however, the antiskid system quickly responded by reducing brake pressure and cycling normally during the remainder of the run on the flooded surface.

Our contaminated atmosphere: The danger of climate change, phases 1 and 2. [effect of atmospheric particulate matter on surface temperature and earth's radiation budget

NASA Technical Reports Server (NTRS)

Cimorelli, A. J.; House, F. B.

1974-01-01

The effects of increased concentrations of atmospheric particulate matter on average surface temperature and on the components of the earth's radiation budget are studied. An atmospheric model which couples particulate loading to surface temperature and to changes in the earth's radiation budget was used. A determination of the feasibility of using satellites to monitor the effect of increased atmospheric particulate concentrations is performed. It was found that: (1) a change in man-made particulate loading of a factor of 4 is sufficient to initiate an ice age; (2) variations in the global and hemispheric weighted averages of surface temperature, reflected radiant fluz and emitted radiant flux are nonlinear functions of particulate loading; and (3) a black satellite sphere meets the requirement of night time measurement sensitivity, but not the required day time sensitivity. A nonblack, spherical radiometer whose external optical properties are sensitive to either the reflected radiant fluz or the emitted radiant flux meets the observational sensitivity requirements.

Tropical continental downdraft characteristics: mesoscale systems versus unorganized convection

NASA Astrophysics Data System (ADS)

Schiro, Kathleen A.; Neelin, J. David

2018-02-01

Downdrafts and cold pool characteristics for strong mesoscale convective systems (MCSs) and isolated, unorganized deep precipitating convection are analyzed using multi-instrument data from the DOE Atmospheric Radiation Measurement (ARM) GoAmazon2014/5 campaign. Increases in column water vapor (CWV) are observed leading convection, with higher CWV preceding MCSs than for isolated cells. For both MCSs and isolated cells, increases in wind speed, decreases in surface moisture and temperature, and increases in relative humidity occur coincidentally with system passages. Composites of vertical velocity data and radar reflectivity from a radar wind profiler show that the downdrafts associated with the sharpest decreases in surface equivalent potential temperature (θe) have a probability of occurrence that increases with decreasing height below the freezing level. Both MCSs and unorganized convection show similar mean downdraft magnitudes and probabilities with height. Mixing computations suggest that, on average, air originating at heights greater than 3 km must undergo substantial mixing, particularly in the case of isolated cells, to match the observed cold pool θe, implying a low typical origin level. Precipitation conditionally averaged on decreases in surface equivalent potential temperature (Δθe) exhibits a strong relationship because the most negative Δθe values are associated with a high probability of precipitation. The more physically motivated conditional average of Δθe on precipitation shows that decreases in θe level off with increasing precipitation rate, bounded by the maximum difference between surface θe and its minimum in the profile aloft. Robustness of these statistics observed across scales and regions suggests their potential use as model diagnostic tools for the improvement of downdraft parameterizations in climate models.

Rising Mediterranean Sea Surface Temperatures Amplify Extreme Summer Precipitation in Central Europe

NASA Astrophysics Data System (ADS)

Volosciuk, Claudia; Maraun, Douglas; Semenov, Vladimir A.; Tilinina, Natalia; Gulev, Sergey K.; Latif, Mojib

2016-08-01

The beginning of the 21st century was marked by a number of severe summer floods in Central Europe associated with extreme precipitation (e.g., Elbe 2002, Oder 2010 and Danube 2013). Extratropical storms, known as Vb-cyclones, cause summer extreme precipitation events over Central Europe and can thus lead to such floodings. Vb-cyclones develop over the Mediterranean Sea, which itself strongly warmed during recent decades. Here we investigate the influence of increased Mediterranean Sea surface temperature (SST) on extreme precipitation events in Central Europe. To this end, we carry out atmosphere model simulations forced by average Mediterranean SSTs during 1970-1999 and 2000-2012. Extreme precipitation events occurring on average every 20 summers in the warmer-SST-simulation (2000-2012) amplify along the Vb-cyclone track compared to those in the colder-SST-simulation (1970-1999), on average by 17% in Central Europe. The largest increase is located southeast of maximum precipitation for both simulated heavy events and historical Vb-events. The responsible physical mechanism is increased evaporation from and enhanced atmospheric moisture content over the Mediterranean Sea. The excess in precipitable water is transported from the Mediterranean Sea to Central Europe causing stronger precipitation extremes over that region. Our findings suggest that Mediterranean Sea surface warming amplifies Central European precipitation extremes.

On blockage effects for a marine hydrokinetic turbine in free surface proximity

NASA Astrophysics Data System (ADS)

Banerjee, A.; Kolekar, N.

2016-12-01

Experimental investigation was carried out with a three-bladed, constant chord marine hydrokinetic turbine to understand the influence of free surface proximity on blockage effects and near wake flow field. The turbine was placed at various depths of immersion as rotational speeds and flow speeds were varied; thrust and torque data was acquired through a submerged thrust torque sensor positioned in-line with the turbine axis. Blockage effects were quantified in terms of changes in power coefficient and were found to be dependent on flow velocity, rotational speed and blade-tip clearence (from free-surface). Flow acceleration near turbine rotation plane was attributed to blockage offered by the rotor, wake, and free surface deformation; the resulting performance improvements were calculated based on the measured thrust values. In addition, stereoscopic particle imaging velocimetry was carried out in the near-wake region using time-averaged and phase-averaged techniques to understand the mechanism responsible for variation of torque (and power coefficient) with rotational speed and free-surface proximity. Flow vizualisation revealed slower wake propagation for higher rotational velocities and increased assymetry in the wake with increasing free surface proximity. Improved performance at high rotational speed was attributed to enhanced wake blockage; performance enhancements with free-surface proximity was attributed to additional blockage effects caused by free surface deformation.

SAW Humidity Sensor Sensitivity Enhancement via Electrospraying of Silver Nanowires

PubMed Central

Sayar Irani, Farid; Tunaboylu, Bahadir

2016-01-01

In this research, we investigated the influence of the surface coatings of silver nanowires on the sensitivity of surface acoustic wave (SAW) humidity sensors. Silver nanowires, with poly(vinylpyrrolidone) (PVP), which is a hydrophilic capping agent, were chemically synthesized, with an average length of 15 µm and an average diameter of 60 nm. Humidity sensors, with 433 MHz frequency dual-port resonator Rayleigh-SAW devices, were coated by silver nanowires (AgNWs) using the electrospray coating method. It was demonstrated that increasing thickness of coated AgNW on the surfaces of SAW devices results in increased sensitivity. The highest frequency shift (262 kHz) in these SAW devices was obtained with an injection of 0.5 mL of the AgNW solution with a concentration of 0.5 mg/mL at an injection rate of 1 mL/h. It also showed the highest humidity sensitivity among the other prepared SAW devices. PMID:27916870

Assessment of surface runoff depth changes in S\\varǎţel River basin, Romania using GIS techniques

NASA Astrophysics Data System (ADS)

Romulus, Costache; Iulia, Fontanine; Ema, Corodescu

2014-09-01

S\\varǎţel River basin, which is located in Curvature Subcarpahian area, has been facing an obvious increase in frequency of hydrological risk phenomena, associated with torrential events, during the last years. This trend is highly related to the increase in frequency of the extreme climatic phenomena and to the land use changes. The present study is aimed to highlight the spatial and quantitative changes occurred in surface runoff depth in S\\varǎţel catchment, between 1990-2006. This purpose was reached by estimating the surface runoff depth assignable to the average annual rainfall, by means of SCS-CN method, which was integrated into the GIS environment through the ArcCN-Runoff extension, for ArcGIS 10.1. In order to compute the surface runoff depth, by CN method, the land cover and the hydrological soil classes were introduced as vector (polygon data), while the curve number and the average annual rainfall were introduced as tables. After spatially modeling the surface runoff depth for the two years, the 1990 raster dataset was subtracted from the 2006 raster dataset, in order to highlight the changes in surface runoff depth.

Angle-dependent lubricated tribological properties of stainless steel by femtosecond laser surface texturing

NASA Astrophysics Data System (ADS)

Wang, Zhuo; Li, Yang-Bo; Bai, Feng; Wang, Cheng-Wei; Zhao, Quan-Zhong

2016-07-01

Lubricated tribological properties of stainless steel were investigated by femtosecond laser surface texturing. Regular-arranged micro-grooved textures with different spacing and micro-groove inclination angles (between micro-groove path and sliding direction) were produced on AISI 304L steel surfaces by an 800 nm femtosecond laser. The spacing of micro-groove was varied from 25 to 300 μm, and the inclination angles of micro-groove were measured as 90° and 45°. The tribological properties of the smooth and textured surfaces with micro-grooves were investigated by reciprocating ball-on-flat tests against Al2O3 ceramic balls under starved oil lubricated conditions. Results showed that the spacing of micro-grooves significantly affected the tribological property. With the increase of micro-groove spacing, the average friction coefficients and wear rates of textured surfaces initially decreased then increased. The tribological performance also depended on the inclination angles of micro-grooves. Among the investigated patterns, the micro-grooves perpendicular to the sliding direction exhibited the lowest average friction coefficient and wear rate to a certain extent. Femtosecond laser-induced surface texturing may remarkably improve friction and wear properties if the micro-grooves were properly distributed.

Hydrology of Jumper Creek Canal basin, Sumter County, Florida

USGS Publications Warehouse

Anderson, Warren

1980-01-01

Jumper Creek Canal basin in Sumter County, Florida, was investigated to evaluate the overall hydrology and effects of proposed flood-control works on the hydrologic regiment of the canal. Average annual rainfall in the 83-square mile basin is about 53 inches of which about 10 inches runs off in the canal. Average annual evapotranspiration is estimated at about 37 inches. Pumping from limestone mines has lowered the potentiometeric surface in the upper part of the basin, but it has not significantly altered the basin yield. Channel excavation to reduce flooding is proposed with seven control structures located to prevent overdrainage. The investigation indicates that implementation of the proposed plan will result in a rise in the potentiometric surface n the upper basin, a reduction is surface outflow, an increase in subsurface outflow, an increase in the gradient of the potentiometeric surface of the Floridan aquifer, an increase in leakage from the canal to the aquifer in the upper basin, and an increase in the magnitude of flood flows from the basin. Ground water in Jumper Creek basin is a bicarbonate type. Very high concentrations of dissolved iron were found in shallow wells and in some deep wells. Sulfate and strontium were relatively high in wells in the lower basin. (Kosco-USGS)

Thermal effects on pulp due to laser and handpiece usage.

PubMed

Penn, Christina; Beninati, Christopher; Mariano, Alissa; Dooley, Daniel; Harsono, Masly; Perry, Ronald; Kugel, Gerard

2014-01-01

The study was designed to compare changes in pulpal temperature during ablation of dental hard tissue while using two established erbium dental laser systems, a new CO2 laser system, and a conventional high-speed handpiece. Eighty non-carious human extracted molars were separated into four sample groups of 20 teeth each. Three laser systems were used, respectively, to ablate the occlusal surface of the teeth in three of the groups for 60 seconds each. The high-speed handpiece was used to drill the occlusal surface of the fourth group for 60 seconds. Pulpal temperatures were measured using thermocouples inserted into each tooth's pulpal chamber prior to ablation. None of the average temperature increases approached the threshold of 5.5°C at which pulpal damage begins. On average, the pulpal temperature of teeth ablated with the Waterlase MD system increased the most (3.56°C). The traditional handpiece caused the lowest average temperature increase (1.57°C), followed by the LightWalker DT system (3.20°C) and the Solea CO2 system (3.30°C).

Surface Plasmon Resonance Evaluation of Colloidal Metal Aerogel Filters

NASA Technical Reports Server (NTRS)

Smith, David D.; Sibille, Laurent; Cronise, Raymond J.; Noever, David A.

1997-01-01

Surface plasmon resonance imaging has in the past been applied to the characterization of thin films. In this study we apply the surface plasmon technique not to determine macroscopic spatial variations but rather to determine average microscopic information. Specifically, we deduce the dielectric properties of the surrounding gel matrix and information concerning the dynamics of the gelation process from the visible absorption characteristics of colloidal metal nanoparticles contained in aerogel pores. We have fabricated aerogels containing gold and silver nanoparticles. Because the dielectric constant of the metal particles is linked to that of the host matrix at the surface plasmon resonance, any change 'in the dielectric constant of the material surrounding the metal nanoparticles results in a shift in the surface plasmon wavelength. During gelation the surface plasmon resonance shifts to the red as the average or effective dielectric constant of the matrix increases. Conversely, formation of an aerogel or xerogel through supercritical extraction or evaporation of the solvent produces a blue shift in the resonance indicating a decrease in the dielectric constant of the matrix. From the magnitude of this shift we deduce the average fraction of air and of silica in contact with the metal particles. The surface area of metal available for catalytic gas reaction may thus be determined.

DOE Office of Scientific and Technical Information (OSTI.GOV)

MacDonald, G.; Abarbanel, H.; Carruthers, P.

The questions of the sources of atmospheric carbon dioxide are addressed; distribution of the present carbon dioxide among the atmospheric, oceanic, and biospheric reservoirs is considered; and the impact on climate as reflected by the average ground temperature at each latitude of significant increases in atmospheric carbon dioxide is assessed. A new model for the mixing of carbon dioxide in the oceans is proposed. The proposed model explicitly takes into account the flow of colder and/or saltier water to great depths. We have constructed two models for the case of radiative equilibrium treating the atmosphere as gray and dividing themore » infrared emission region into nine bands. The gray atmosphere model predicts an increase of average surface temperature of 2.8/sup 0/K for a doubling of CO/sub 2/, a result about a degree less than the nine band model. An analytic model of the atmosphere was constructed (JASON Climate Model). Calculation with this zonally averaged model shows an increase of average surface temperature of 2.4/sup 0/ for a doubling of CO/sub 2/. The equatorial temperature increases by 0.7/sup 0/K while the poles warm up by 10 to 12/sup 0/K. The JASON climate model suffers from a number of fundamental weaknesses. The role of clouds in determining the albedo is not adequately taken into account nor are the asymmetries between the northern and southern hemisphere. (JGB)« less

Amplification of warming due to intensification of zonal circulation in the mid-latitudes

NASA Astrophysics Data System (ADS)

Alekseev, Genrikh; Ivanov, Nikolai; Kharlanenkova, Natalia; Kuzmina, Svetlana

2015-04-01

We propose a new index to evaluate the impact of atmospheric zonal transport oscillations on inter-annual variability and trends of average air temperature in mid-latitudes, Northern Hemisphere and globe. A simple model of mid-latitude channel "ocean-land-atmosphere" was used to produce the analytic relationship between the zonal circulation and the land-ocean temperature contrast which was used as a basis for index. An inverse relationship was found between indexes and average mid-latitude, hemisphere and global temperatures during the cold half of year and opposite one in summer. These relationships keep under 400 mb height. In winter relationship describes up to 70, 50 and 40 % of surface air temperature inter-annual variability of these averages, respectively. The contribution of zonal circulation to the increase in the average surface air temperature during warming period 1969-2008 reaches 75% in the mid-latitudes and 40% in the Northern Hemisphere. Proposed mid-latitude index correlates negatively with surface air temperature in the Arctic except summer. ECHAM4 projections with the A1B scenario show that increase of zonal circulation defines more than 74% of the warming in the Northern Hemisphere for 2001-2100. Our analysis confirms that the proposed index is an effective indicator of the climate change caused by variations of the zonal circulation that arise due to anthropogenic and/or natural global forcing mechanisms.

Bioinspired Surface Treatments for Improved Decontamination: Icephobic Surfaces

DTIC Science & Technology

2017-06-26

standing droplets of water (left) and methyl salicylate (right) immediately following liquid application (top) and 5 min after liquid application...average of nine measurements for each liquid ). Geometric surface energy was calculated based on the water and ethylene glycol interactions using software...supporting platform angle was gradually increased up to 60°. Sliding angles for each of the liquids were identified as the angle for which movement

The spatial-temporal dynamics of open surface water bodies in CONUS during 1984-2016

NASA Astrophysics Data System (ADS)

Zou, Z.; Xiao, X.; Dong, J.; Qin, Y.; Doughty, R.; Menarguez, M.; Wang, J.

2017-12-01

Open surface water bodies provided 80% of the total water withdrawals in the Contiguous United States (CONUS) in 1985-2010. The inter-annual variability and changing trends of surface water body areas have various impacts on the human society and ecosystems. This study made use of all Landsat 5, 7, and 8 surface reflectance archives ( 370,000 images) during 1984-2016 and a water index- and pixel-based approach to detect and map open surface water bodies in the cloud-based platform of Google Earth Engine. The year-long water body area and annual average water body area were calculated for each of the last 33 years and their inter-annual variations during 1984-2016 were analyzed through anomaly analysis while their changing trends were analyzed through linear regressions. The national annual average water body areas varied from 265,000 to 281,000 km2 during 1984-2016, which is 3% below to 3% above the mean value 274,000 km2. In state level, significant decreasing trends were found in both year-long and annual average water body areas in some states of dry climates in west and southwest U.S., including Oregon, Nevada, Utah, Arizona, New Mexico, and Oklahoma. In comparison, significant increasing trends were found in some states of wet climates in the southeast and north U.S., including Indiana, Ohio, New Jersey, Delaware, Virginia, Tennessee, North Carolina, South Carolina, Louisiana, Alabama, Georgia, North Dakota and South Dakota. Open surface water body areas in CONUS decreased in relatively dry areas but increased in relatively wet areas. The relationships between open surface water body area variability and climate factors (precipitation, temperature) and human impacts (water exploitation) were also analyzed.

Forensic collection of trace chemicals from diverse surfaces with strippable coatings.

PubMed

Jakubowski, Michael J; Beltis, Kevin J; Drennan, Paul M; Pindzola, Bradford A

2013-11-07

Surface sampling for chemical analysis plays a vital role in environmental monitoring, industrial hygiene, homeland security and forensics. The standard surface sampling tool, a simple cotton gauze pad, is failing to meet the needs of the community as analytical techniques become more sensitive and the variety of analytes increases. In previous work, we demonstrated the efficacy of non-destructive, conformal, spray-on strippable coatings for chemical collection from simple glass surfaces. Here we expand that work by presenting chemical collection at a low spiking level (0.1 g m(-2)) from a diverse array of common surfaces - painted metal, engineering plastics, painted wallboard and concrete - using strippable coatings. The collection efficiency of the strippable coatings is compared to and far exceeds gauze pads. Collection from concrete, a particular challenge for wipes like gauze, averaged 73% over eight chemically diverse compounds for the strippable coatings whereas gauze averaged 10%.

Effect of cutting parameters on surface finish and machinability of graphite reinforced Al-8011 matrix composite

NASA Astrophysics Data System (ADS)

Anil, K. C.; Vikas, M. G.; Shanmukha Teja, B.; Sreenivas Rao, K. V.

2017-04-01

Many materials such as alloys, composites find their applications on the basis of machinability, cost and availability. In the present work, graphite (Grp) reinforced Aluminium 8011 is synthesized by convention stir casting process and Surface finish & machinability of prepared composite is examined by using lathe tool dynamometer attached with BANKA Lathe by varying the machining parameters like spindle speed, Depth of cut and Feed rate in 3 levels. Also, Roughness Average (Ra) of machined surfaces is measured by using Surface Roughness Tester (Mitutoyo SJ201). From the studies it is cleared that mechanical properties of a composites increases with addition of Grp and The cutting force were decreased with the reinforcement percentage and thus increases the machinability of composites and also results in increased surface finish.

Copper foils with gradient structure in thickness direction and different roughnesses on two surfaces fabricated by double rolling

NASA Astrophysics Data System (ADS)

Wang, Xi-yong; Liu, Xue-feng; Zou, Wen-jiang; Xie, Jian-xin

2013-12-01

Copper foils with gradient structure in thickness direction and different roughnesses on two surfaces were fabricated by double rolling. The two surface morphologies of double-rolled copper foils are quite different, and the surface roughness values are 61 and 1095 nm, respectively. The roughness value of matt surface can meet the requirement for bonding the resin matrix with copper foils used for flexible printed circuit boards, thus may omit traditional roughening treatment; the microstructure of double-rolled copper foils demonstrates an obviously asymmetric gradient feature. From bright surface to matt surface in thickness direction, the average grain size first increases from 2.3 to 7.4 μm and then decreases to 3.6 μm; compared with conventional rolled copper foils, the double-rolled copper foils exhibit a remarkably increased bending fatigue life, and the increased range is about 16.2%.

Remote sensing monitoring study of ecological environment change in Qingtu Lake

NASA Astrophysics Data System (ADS)

Han, Tao; Wang, Dawei; Jiang, Youyan; Qian, Li; Chen, Lei; Hao, Xiaocui

2018-03-01

Based on the Environmental Mitigation Satellite (HJ-1) data, this paper has carried on the remote sensing monitoring to change of the surrounding vegetation and water area of the Qingtu Lake since 2009. The result shows that the average area of water has increased by 3.59 square kilometres annually since the reappearance of the waters with the Qingtu Lake in 2010. The area of Qingtu Lake and surrounding vegetation cover has presented an average increase of 1.09 square kilometres per year. Since 2010, the precipitation of the Qingtu Lake and its surrounding area in Minqin county have a significant increase in the trend, the average increase rate of 6.0 mm/year. Compared to 2010 years ago, the average precipitation increased 36.4 mm. And it shows that the change of the Qingtu Lake underlying surface has a positive feedback effect to local heavy rainfall according to the comparative analysis of the precipitation observation in the surrounding weather station.

Is Global Warming Accelerating?

NASA Astrophysics Data System (ADS)

Shukla, J.; Delsole, T. M.; Tippett, M. K.

2009-12-01

A global pattern that fluctuates naturally on decadal time scales is identified in climate simulations and observations. This newly discovered component, called the Global Multidecadal Oscillation (GMO), is related to the Atlantic Meridional Oscillation and shown to account for a substantial fraction of decadal fluctuations in the observed global average sea surface temperature. IPCC-class climate models generally underestimate the variance of the GMO, and hence underestimate the decadal fluctuations due to this component of natural variability. Decomposing observed sea surface temperature into a component due to anthropogenic and natural radiative forcing plus the GMO, reveals that most multidecadal fluctuations in the observed global average sea surface temperature can be accounted for by these two components alone. The fact that the GMO varies naturally on multidecadal time scales implies that it can be predicted with some skill on decadal time scales, which provides a scientific rationale for decadal predictions. Furthermore, the GMO is shown to account for about half of the warming in the last 25 years and hence a substantial fraction of the recent acceleration in the rate of increase in global average sea surface temperature. Nevertheless, in terms of the global average “well-observed” sea surface temperature, the GMO can account for only about 0.1° C in transient, decadal-scale fluctuations, not the century-long 1° C warming that has been observed during the twentieth century.

Stratospheric Ozone Response in Experiments G3 and G4 of the Geoengineering Model Intercomparison Project (GeoMIP)

NASA Technical Reports Server (NTRS)

Pitari, Giovanni; Aquila, Valentina; Kravitz, Ben; Watanabe, Shingo; Tilmes, Simone; Mancini, Eva; DeLuca, Natalia; DiGenova, Glauco

2013-01-01

Geoengineering with stratospheric sulfate aerosols has been proposed as a means of temporarily cooling the planet, alleviating some of the side effects of anthropogenic CO2 emissions. However, one of the known side effects of stratospheric injections of sulfate aerosols is a decrease in stratospheric ozone. Here we show results from two general circulation models and two coupled chemistry climate models that have simulated stratospheric sulfate aerosol geoengineering as part of the Geoengineering Model Intercomparison Project (GeoMIP). Changes in photolysis rates and upwelling of ozone-poor air in the tropics reduce stratospheric ozone, suppression of the NOx cycle increases stratospheric ozone, and an increase in available surfaces for heterogeneous chemistry modulates reductions in ozone. On average, the models show a factor 20-40 increase of the sulfate aerosol surface area density (SAD) at 50 hPa in the tropics with respect to unperturbed background conditions and a factor 3-10 increase at mid-high latitudes. The net effect for a tropical injection rate of 5 Tg SO2 per year is a decrease in globally averaged ozone by 1.1-2.1 DU in the years 2040-2050 for three models which include heterogeneous chemistry on the sulfate aerosol surfaces. GISS-E2-R, a fully coupled general circulation model, performed simulations with no heterogeneous chemistry and a smaller aerosol size; it showed a decrease in ozone by 9.7 DU. After the year 2050, suppression of the NOx cycle becomes more important than destruction of ozone by ClOx, causing an increase in total stratospheric ozone. Contribution of ozone changes in this experiment to radiative forcing is 0.23 W m-2 in GISS-E2-R and less than 0.1 W m-2 in the other three models. Polar ozone depletion, due to enhanced formation of both sulfate aerosol SAD and polar stratospheric clouds, results in an average 5 percent increase in calculated surface UV-B.

Rising Mediterranean Sea Surface Temperatures Amplify Extreme Summer Precipitation in Central Europe

PubMed Central

Volosciuk, Claudia; Maraun, Douglas; Semenov, Vladimir A.; Tilinina, Natalia; Gulev, Sergey K.; Latif, Mojib

2016-01-01

The beginning of the 21st century was marked by a number of severe summer floods in Central Europe associated with extreme precipitation (e.g., Elbe 2002, Oder 2010 and Danube 2013). Extratropical storms, known as Vb-cyclones, cause summer extreme precipitation events over Central Europe and can thus lead to such floodings. Vb-cyclones develop over the Mediterranean Sea, which itself strongly warmed during recent decades. Here we investigate the influence of increased Mediterranean Sea surface temperature (SST) on extreme precipitation events in Central Europe. To this end, we carry out atmosphere model simulations forced by average Mediterranean SSTs during 1970–1999 and 2000–2012. Extreme precipitation events occurring on average every 20 summers in the warmer-SST-simulation (2000–2012) amplify along the Vb-cyclone track compared to those in the colder-SST-simulation (1970–1999), on average by 17% in Central Europe. The largest increase is located southeast of maximum precipitation for both simulated heavy events and historical Vb-events. The responsible physical mechanism is increased evaporation from and enhanced atmospheric moisture content over the Mediterranean Sea. The excess in precipitable water is transported from the Mediterranean Sea to Central Europe causing stronger precipitation extremes over that region. Our findings suggest that Mediterranean Sea surface warming amplifies Central European precipitation extremes. PMID:27573802

Creating a monthly time series of the potentiometric surface in the Upper Floridan aquifer, Northern Tampa Bay area, Florida, January 2000-December 2009

USGS Publications Warehouse

Lee, Terrie M.; Fouad, Geoffrey G.

2014-01-01

In Florida’s karst terrain, where groundwater and surface waters interact, a mapping time series of the potentiometric surface in the Upper Floridan aquifer offers a versatile metric for assessing the hydrologic condition of both the aquifer and overlying streams and wetlands. Long-term groundwater monitoring data were used to generate a monthly time series of potentiometric surfaces in the Upper Floridan aquifer over a 573-square-mile area of west-central Florida between January 2000 and December 2009. Recorded groundwater elevations were collated for 260 groundwater monitoring wells in the Northern Tampa Bay area, and a continuous time series of daily observations was created for 197 of the wells by estimating missing daily values through regression relations with other monitoring wells. Kriging was used to interpolate the monthly average potentiometric-surface elevation in the Upper Floridan aquifer over a decade. The mapping time series gives spatial and temporal coherence to groundwater monitoring data collected continuously over the decade by three different organizations, but at various frequencies. Further, the mapping time series describes the potentiometric surface beneath parts of six regionally important stream watersheds and 11 municipal well fields that collectively withdraw about 90 million gallons per day from the Upper Floridan aquifer. Monthly semivariogram models were developed using monthly average groundwater levels at wells. Kriging was used to interpolate the monthly average potentiometric-surface elevations and to quantify the uncertainty in the interpolated elevations. Drawdown of the potentiometric surface within well fields was likely the cause of a characteristic decrease and then increase in the observed semivariance with increasing lag distance. This characteristic made use of the hole effect model appropriate for describing the monthly semivariograms and the interpolated surfaces. Spatial variance reflected in the monthly semivariograms decreased markedly between 2002 and 2003, timing that coincided with decreases in well-field pumping. Cross-validation results suggest that the kriging interpolation may smooth over the drawdown of the potentiometric surface near production wells. The groundwater monitoring network of 197 wells yielded an average kriging error in the potentiometric-surface elevations of 2 feet or less over approximately 70 percent of the map area. Additional data collection within the existing monitoring network of 260 wells and near selected well fields could reduce the error in individual months. Reducing the kriging error in other areas would require adding new monitoring wells. Potentiometric-surface elevations fluctuated by as much as 30 feet over the study period, and the spatially averaged elevation for the entire surface rose by about 2 feet over the decade. Monthly potentiometric-surface elevations describe the lateral groundwater flow patterns in the aquifer and are usable at a variety of spatial scales to describe vertical groundwater recharge and discharge conditions for overlying surface-water features.

Comparison of dew point temperature estimation methods in Southwestern Georgia

Treesearch

Marcus D. Williams; Scott L. Goodrick; Andrew Grundstein; Marshall Shepherd

2015-01-01

Recent upward trends in acres irrigated have been linked to increasing near-surface moisture. Unfortunately, stations with dew point data for monitoring near-surface moisture are sparse. Thus, models that estimate dew points from more readily observed data sources are useful. Daily average dew temperatures were estimated and evaluated at 14 stations in...

Estimation of surface-level PM2.5 concentration using aerosol optical thickness through aerosol type analysis method

NASA Astrophysics Data System (ADS)

Chen, Qi-Xiang; Yuan, Yuan; Huang, Xing; Jiang, Yan-Qiu; Tan, He-Ping

2017-06-01

Surface-level particulate matter is closely related to column aerosol optical thickness (AOT). Previous researches have successfully used column AOT and different meteorological parameters to estimate surface-level PM concentration. In this study, the performance of a selected linear model that estimates surface-level PM2.5 concentration was evaluated following the aerosol type analysis method (ATAM) for the first time. We utilized 443 daily average data for Xuzhou, Jiangsu province, collected using Aerosol Robotic Network (AERONET) during the period October 2013 to April 2016. Several parameters including atmospheric boundary layer height (BLH), relative humidity (RH), and effective radius of the aerosol size distribution (Ref) were used to assess the relationship between the column AOT and PM2.5 concentration. By including the BLH, ambient RH, and effective radius, the correlation (R2) increased from 0.084 to 0.250 at Xuzhou, and with the use of ATAM, the correlation increased further to 0.335. To compare the results, 450 daily average data for Beijing, pertaining to the same period, were utilized. The study found that model correlations improved by varying degrees in different seasons and at different sites following ATAM. The average urban industry (UI) aerosol ratios at Xuzhou and Beijing were 0.792 and 0.451, respectively, demonstrating poorer air conditions at Xuzhou. PM2.5 estimation at Xuzhou showed lower correlation (R2 = 0.335) compared to Beijing (R2 = 0.407), and the increase of R2 at Xuzhou and Beijing site following use of ATAM were 33.8% and 12.4%, respectively.

Radiative Forcing Due to Enhancements in Tropospheric Ozone and Carbonaceous Aerosols Caused by Asian Fires During Spring 2008

NASA Technical Reports Server (NTRS)

Natarajan, Murali; Pierce, R. Bradley; Lenzen, Allen J.; Al-Saadi, Jassim A.; Soja, Amber J.; Charlock, Thomas P.; Rose, Fred G.; Winker, David M.; Worden, John R.

2012-01-01

Simulations of tropospheric ozone and carbonaceous aerosol distributions, conducted with the Real-time Air Quality Modeling System (RAQMS), are used to study the effects of major outbreaks of fires that occurred in three regions of Asia, namely Thailand, Kazakhstan, and Siberia, during spring 2008. RAQMS is a global scale meteorological and chemical modeling system. Results from these simulations, averaged over April 2008, indicate that tropospheric ozone column increases by more than 10 Dobson units (DU) near the Thailand region, and by lesser amounts in the other regions due to the fires. Widespread increases in the optical depths of organic and black carbon aerosols are also noted. We have used an off-line radiative transfer model to evaluate the direct radiative forcing due to the fire-induced changes in atmospheric composition. For clear sky, the monthly averaged radiative forcing at the top of the atmosphere (TOA) is mostly negative with peak values less than -12 W/sq m occurring near the fire regions. The negative forcing represents the increased outgoing shortwave radiation caused by scattering due to carbonaceous aerosols. At high latitudes, the radiative forcing is positive due to the presence of absorbing aerosols over regions of high surface albedo. Regions of positive forcing at TOA are more pronounced under total sky conditions. The monthly averaged radiative forcing at the surface is mostly negative, and peak values of less than -30 W/sq m occur near the fire regions. Persistently large negative forcing at the surface could alter the surface energy budget and potentially weaken the hydrological cycle.

Porosity control in nanoporous carbide-derived carbon by oxidation in air and carbon dioxide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Osswald, S.; Portet, C.; Gogotsi, Y., E-mail: gogotsi@drexel.ed

2009-07-15

Carbide-derived carbons (CDC) allow a precise control over the pore size through the selection of the carbide precursor and varying of the synthesis conditions. However, their pore volume is limited by the carbide stoichiometry. While activation of carbons derived from various organic precursors has been widely studied, this process may similarly be able to increase the pore volume and specific surface area of CDC. Oxidation of carbide-derived carbon in air and CO{sub 2} at different temperatures and times allows for significant increase in pore volume and specific surface area as well as control over average pore size with subnanometer accuracy.more » The effect of activation and associated changes in the pore volume and surface area on the hydrogen uptake are also discussed. - Graphical abstract: Carbide-derived carbons (CDC) provide great potential for sorption of toxicants and gas storage applications. Activation of CDC in air and CO{sub 2} at different temperatures and times is applied in order to maximize pore volume and specific surface area, and control the average pore size with subnanometer accuracy.« less

Correlation between average tissue depth data and quantitative accuracy of forensic craniofacial reconstructions measured by geometric surface comparison method.

PubMed

Lee, Won-Joon; Wilkinson, Caroline M; Hwang, Hyeon-Shik; Lee, Sang-Mi

2015-05-01

Accuracy is the most important factor supporting the reliability of forensic facial reconstruction (FFR) comparing to the corresponding actual face. A number of methods have been employed to evaluate objective accuracy of FFR. Recently, it has been attempted that the degree of resemblance between computer-generated FFR and actual face is measured by geometric surface comparison method. In this study, three FFRs were produced employing live adult Korean subjects and three-dimensional computerized modeling software. The deviations of the facial surfaces between the FFR and the head scan CT of the corresponding subject were analyzed in reverse modeling software. The results were compared with those from a previous study which applied the same methodology as this study except average facial soft tissue depth dataset. Three FFRs of this study that applied updated dataset demonstrated lesser deviation errors between the facial surfaces of the FFR and corresponding subject than those from the previous study. The results proposed that appropriate average tissue depth data are important to increase quantitative accuracy of FFR. © 2015 American Academy of Forensic Sciences.

Synthesis of antimony-doped tin oxide (ATO) nanoparticles by the nitrate-citrate combustion method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang Jianrong; Gao Lian

2004-12-02

Antimony-doped tin oxide (ATO) nanoparticles having rutile structure have been synthesized by the combustion method using citric acid (CA) as fuel and nitrate as an oxidant, the metal sources were granulated tin and Sb{sub 2}O{sub 3}. The influence of citric acid (fuel) to metal ratio on the average crystallite size, specific surface area and morphology of the nanoparticles has been investigated. X-ray diffraction showed the tin ions were reduced to elemental tin during combustion reaction. The average ATO crystallite size increased with the increase of citric acid (fuel). Powder morphology and the comparison of crystallite size and grain size showsmore » that the degree of agglomeration of the powder decreased with an increase of the ratio. The highest specific surface area was 37.5 m{sup 2}/g when the citric acid to tin ratio was about 6.« less

Detection, causes and projection of climate change over China: An overview of recent progress

NASA Astrophysics Data System (ADS)

Ding, Yihui; Ren, Guoyu; Zhao, Zongci; Xu, Ying; Luo, Yong; Li, Qiaoping; Zhang, Jin

2007-11-01

This article summarizes the main results and findings of studies conducted by Chinese scientists in the past five years. It is shown that observed climate change in China bears a strong similarity with the global average. The country-averaged annual mean surface air temperature has increased by 1.1°C over the past 50 years and 0.5-0.8°C over the past 100 years, slightly higher than the global temperature increase for the same periods. Northern China and winter have experienced the greatest increases in surface air temperature. Although no significant trend has been found in country-averaged annual precipitation, interdecadal variability and obvious trends on regional scales are detectable, with northwestern China and the mid and lower Yangtze River basin having undergone an obvious increase, and North China a severe drought. Some analyses show that frequency and magnitude of extreme weather and climate events have also undergone significant changes in the past 50 years or so. Studies of the causes of regional climate change through the use of climate models and consideration of various forcings, show that the warming of the last 50 years could possibly be attributed to an increased atmospheric concentration of greenhouse gases, while the temperature change of the first half of the 20th century may be due to solar activity, volcanic eruptions and sea surface temperature change. A significant decline in sunshine duration and solar radiation at the surface in eastern China has been attributed to the increased emission of pollutants. Projections of future climate by models of the NCC (National Climate Center, China Meteorological Administration) and the IAP (Institute of Atmospheric Physics, Chinese Academy of Sciences), as well as 40 models developed overseas, indicate a potential significant warming in China in the 21st century, with the largest warming set to occur in winter months and in northern China. Under varied emission scenarios, the country-averaged annual mean temperature is projected to increase by 1.5-2.1°C by 2020, 2.3-3.3°C by 2050, and by 3.9-6.0°C by 2100, in comparison to the 30-year average of 1961-1990. Most models project a 10%-12% increase in annual precipitation in China by 2100, with the trend being particularly evident in Northeast and Northwest China, but with parts of central China probably undergoing a drying trend. Large uncertainty exists in the projection of precipitation, and further studies are needed. Furthermore, anthropogenic climate change will probably lead to a weaker winter monsoon and a stronger summer monsoon in eastern Asia.

Effect of crack curvature on stress intensity factors for ASTM standard compact tension specimens

NASA Technical Reports Server (NTRS)

Alam, J.; Mendelson, A.

1983-01-01

The stress intensity factors (SIF) are calculated using the method of lines for the compact tension specimen in tensile and shear loading for curved crack fronts. For the purely elastic case, it was found that as the crack front curvature increases, the SIF value at the center of the specimen decreases while increasing at the surface. For the higher values of crack front curvatures, the maximum value of the SIF occurs at an interior point located adjacent to the surface. A thickness average SIF was computed for parabolically applied shear loading. These results were used to assess the requirements of ASTM standards E399-71 and E399-81 on the shape of crack fronts. The SIF is assumed to reflect the average stress environment near the crack edge.

Ice-sheet contributions to future sea-level change.

PubMed

Gregory, J M; Huybrechts, P

2006-07-15

Accurate simulation of ice-sheet surface mass balance requires higher spatial resolution than is afforded by typical atmosphere-ocean general circulation models (AOGCMs), owing, in particular, to the need to resolve the narrow and steep margins where the majority of precipitation and ablation occurs. We have developed a method for calculating mass-balance changes by combining ice-sheet average time-series from AOGCM projections for future centuries, both with information from high-resolution climate models run for short periods and with a 20km ice-sheet mass-balance model. Antarctica contributes negatively to sea level on account of increased accumulation, while Greenland contributes positively because ablation increases more rapidly. The uncertainty in the results is about 20% for Antarctica and 35% for Greenland. Changes in ice-sheet topography and dynamics are not included, but we discuss their possible effects. For an annual- and area-average warming exceeding 4.5+/-0.9K in Greenland and 3.1+/-0.8K in the global average, the net surface mass balance of the Greenland ice sheet becomes negative, in which case it is likely that the ice sheet would eventually be eliminated, raising global-average sea level by 7m.

Impacts of peatland forestation on regional climate conditions in Finland

NASA Astrophysics Data System (ADS)

Gao, Yao; Markkanen, Tiina; Backman, Leif; Henttonen, Helena M.; Pietikäinen, Joni-Pekka; Laaksonen, Ari

2014-05-01

Climate response to anthropogenic land cover change happens more locally and occurs on a shorter time scale than the global warming due to increased GHGs. Over the second half of last Century, peatlands were vastly drained in Finland to stimulate forest growth for timber production. In this study, we investigate the biophysical effects of peatland forestation on near-surface climate conditions in Finland. For this, the regional climate model REMO, developed in Max Plank Institute (currently in Climate Service Center, Germany), provides an effective way. Two sets of 15-year climate simulations were done by REMO, using the historic (1920s; The 1st Finnish National Forest Inventory) and present-day (2000s; the 10th Finnish National Forest Inventory) land cover maps, respectively. The simulated surface air temperature and precipitation were then analyzed. In the most intensive peatland forestation area in Finland, the differences in monthly averaged daily mean surface air temperature show a warming effect around 0.2 to 0.3 K in February and March and reach to 0.5 K in April, whereas a slight cooling effect, less than 0.2 K, is found from May till October. Consequently, the selected snow clearance dates in model gridboxes over that area are advanced 0.5 to 4 days in the mean of 15 years. The monthly averaged precipitation only shows small differences, less than 10 mm/month, in a varied pattern in Finland from April to September. Furthermore, a more detailed analysis was conducted on the peatland forestation area with a 23% decrease in peatland and a 15% increase in forest types. 11 day running means of simulated temperature and energy balance terms, as well as snow depth were averaged over 15 years. Results show a positive feedback induced by peatland forestation between the surface air temperature and snow depth in snow melting period. This is because the warmer temperature caused by lower surface albedo due to more forest in snow cover period leads to a quicker and earlier snow melting. Meanwhile, surface albedo is reduced and consequently surface air temperature is increased. Additionally, the maximum difference from individual gridboxes in this area over 15 years of 11 day running means of daily mean surface air temperature reaches 2 K, which is four times as much as the maximum difference of 15-year regional average of that. This illustrates that the spring warming effect from peatland forestation in Finland is highly heterogeneous spatially and temporally.

Comparing goblet cell densities in patients wearing disposable hydrogel contact lenses versus silicone hydrogel contact lenses in an extended-wear modality.

PubMed

Lievens, Christopher W; Connor, Charles G; Murphy, Heather

2003-10-01

The current study evaluates the response of the ocular surface to extended contact lens wear by comparing a new silicone hydrogel lens to an ACUVUE 2 lens. Twenty subjects with an average age of 28 years were randomly assigned to a fitting with ACUVUE 2 or PureVision lenses. Ocular surface assessment by impression cytology was performed at baseline and for the 6 months after initiation of lens wear. Although goblet cell density significantly increased with wear time, no statistically significant difference was observed between the contact lens groups. The average baseline goblet cell percentages were as follows: ACUVUE 2 group, 1.44; PureVision group, 1.11. The 6-month averages were as follows: ACUVUE 2 group, 3.16; PureVision group, 2.22. It appears that silicone hydrogel lenses may be slightly less irritating to the ocular surface than lenses not containing silicone. This could be a promising indicator for successful 30-day continuous wear.

Radiative Forcing and Temperature Response to Changes in Urban Albedos and Associated CO2 Offsets

NASA Technical Reports Server (NTRS)

Menon, Surabi; Akbari, Hashem; Mahanama, Sarith; Sednev, Igor; Levinson, Ronnen

2009-01-01

The two main forcings that can counteract to some extent the positive forcings from greenhouse gases from pre-industrial times to present-day are the aerosol and related aerosol-cloud forcings, and the radiative response to changes in surface albedo. Here, we quantify the change in radiative forcing and surface temperature that may be obtained by increasing the albedos of roofs and pavements in urban areas in temperate and tropical regions of the globe. Using the catchment land surface model (the land model coupled to the GEOS-5 Atmospheric General Circulation Model), we quantify the response of the total outgoing (outgoing shortwave+longwave) radiation to urban albedo changes. Globally, the total outgoing radiation increased by 0.5 W/square m and temperature decreased by -0.008 K for an average 0.003 increase in albedo. For the U.S. the total outgoing total radiation increased by 2.3 W/square meter, and temperature decreased by approximately 0.03 K for an average 0.01 increase in albedo. These values are for the boreal summer (Tune-July-August). Based on these forcings, the expected emitted CO2 offset for a plausible 0.25 and 0.15 increase in albedos of roofs and pavements, respectively, for all global urban areas, was found to be approximately 57 Gt CO2 . A more meaningful evaluation of the impacts of urban albedo increases on climate and the expected CO2 offsets would require simulations which better characterizes urban surfaces and represents the full annual cycle.

An overview of mainland China temperature change research

NASA Astrophysics Data System (ADS)

Ren, Guoyu; Ding, Yihui; Tang, Guoli

2017-02-01

There has been significant effort devoted to investigating long-term trends in land surface air temperature over mainland China by Chinese scientists over the past 50 years, and much progress has been made in understanding dynamics of the changes. This review highlights research conducted by early Chinese climatologists, and particularly Professor Shaowu Wang from Peking University, with special focus on systematic work that has been conducted since the mid to late 1970s. We also discuss major issues that remain unresolved in past and current studies. The most recent analyses indicate that the country-average annual mean surface air temperature rose by 1.12°C over the past 115 years (1901-2015), with a rate of increase of about 0.10°C decade-1. Temperatures have risen more rapidly since the 1950s, with the rate of increase of more than 0.25°C decade-1. However, the recent increase in temperatures is in large part due to contamination by systematically biased data. These data are influenced by unprecedented urbanization in China, with a contribution of urbanization to the overall increase of annual mean temperatures in mainland China of about one third over the past half a century. If the bias is corrected, the rate of increase for the country-average annual mean surface air temperature is 0.17°C decade-1 over the last 50-60 years, which is approximately the same as global and Northern Hemispheric averages in recent decades. Future efforts should be focused towards the recovery and digitization of early-year observational records, the homogenization of observational data, the evaluation and adjustment of urbanization bias in temperature data series from urban stations, the analysis of extreme temperatures over longer periods including the first half of the 20th century, and the investigation of the observed surface air temperature change mechanisms in mainland China.

Investigation of the influence of irradiation with Fe+7 ions on structural properties of AlN ceramics

NASA Astrophysics Data System (ADS)

Kozlovskiy, A.; Dukenbayev, K.; Ivanov, I.; Kozin, S.; Aleksandrenko, V.; Kurakhmedov, A.; Sambaev, E.; Kenzhina, I.; Tosi, D.; Loginov, V.; Zdorovets, M.

2018-06-01

The paper presents the results of investigation of defect formation in AlN ceramics under Fe+7 ion irradiation with a fluence from 1 × 1011 to 1 × 1014 ion cm‑2. The change in the main crystallographic characteristics, the decrease in the magnitude of Griffiths criterion, and the increase in the average voltage as a result of irradiation are caused by the appearance of additional defects in the structure and their further evolution leading to a change in the degree of crystallinity. For samples irradiated with Fe+7 ions to a dose of 1 × 1011 ion cm‑2, the formation of pyramidal hillocks is observed on the surface, whose average height is 17–20 nm. An increase in the irradiation dose leads to an increase in chillocks size and their density. At the same time, at large irradiation doses, the formation of conglomerates of chyllocks and grooves on the samples surface is observed. The change in surface morphology, the formation of chyllocks on the ceramic surface, and the dependence of the change in crystallographic characteristics during irradiation make it possible to unambiguously associate the formation of radiation defects in the structure of the ceramic with energy losses in elastic and inelastic interactions of iron ions with lattice atoms.

Gloss measurements and rugometric inspection in dental biomaterials

NASA Astrophysics Data System (ADS)

Fernández-Oliveras, Alicia; Costa, Manuel F. M.; Yebra, Ana; Rubiño, Manuel; Pérez, María. M.

2013-11-01

In dental applications, optimizing appearance is desirable and increasingly demanded by patients. The specular gloss is among the major appearance properties of dental biomaterials, and its relationship with surface roughness has been reported. Roughness and gloss are key surface aspects that complement each other. We have experimentally analyzed the specular gloss and surface roughness of two different types of dental-resin composites and pre-sintered and sintered zirconia ceramics. We have studied two shades of both composite types and two sintered zirconia ceramics: colored and uncolored. Moreover, a surface treatment was applied to one specimen of each dental resin. Gloss measurements were performed with a standardized reflectometer and the corresponding gloss percentages were calculated. All the samples were submitted to rugometric non-invasive inspection with the MICROTOP.06.MFC laser microtopographer in order to determine meaningful statistical parameters such as the average roughness (Ra) and the root-mean-square deviation (Rq). For a comparison of the different biomaterials, the uncertainties associated to the measure of the surface gloss and roughness were also determined. The differences between the two shades of both kinds of composites proved significant in the case of the roughness parameters but not for the specular gloss. The surface treatment applied to the dental-resin composites increased the average roughness but the changes in the specular gloss were significant only for the A2 enamel nano-composite. For the zirconia ceramic the sintered process resulted in an increase in the surface roughness with a decrease of the specular gloss, corroborating that the relationship between the gloss and the roughness shows the expected behavior.

DOE Office of Scientific and Technical Information (OSTI.GOV)

MacDonald, I. R.; Garcia-Pineda, O.; Beet, A.

When wind speeds are 2–10 m s -1, reflective contrasts in the ocean surface make oil slicks visible to synthetic aperture radar (SAR) under all sky conditions. Neural network analysis of satellite SAR images quantified the magnitude and distribution of surface oil in the Gulf of Mexico from persistent,natural seeps and from the Deep water Horizon (DWH) discharge. This analysis identified 914 natural oil seep zones across the entire Gulf of Mexico in pre-2010 data. Their ~0.1 mm slicks covered an aggregated average of 775 km 2. Assuming an average volume of 77.5 m 3 over an 8–24 h lifespanmore » per oil slick, the floating oil indicates a surface flux of 2.5–9.4 X 10 4 m 3 yr -1. Oil from natural slicks was regionally concentrated: 68%, 25%, 7%, and <1% of the total was observed in the NW, SW, NE, and SE Gulf, respectively. This reflects differences in basin history and hydrocarbon generation. SAR images from 2010 showed that the 87 day DWH discharge produced a surface-oil footprint fundamentally different from background seepage, with an average ocean area of 11,200 km 2(SD 5028) and a volume of 22,600 m 3(SD 5411). Peak magnitudes of oil were detected during equivalent, ~14 day intervals around 23 May and 18 June, when wind speeds remained <5ms -1. Over this interval, aggregated volume of floating oil decreased by 21%; area covered increased by 49% (p < 0.1), potentially altering its ecological impact. Furthermore, the most likely causes were increased applications of dispersant and surface burning operations.« less

A Study of Aerosol Direct Radiative Effect and Its Impacts on Global Terrestrial Ecosystem Cycles

NASA Astrophysics Data System (ADS)

Zhang, J.; Shao, S.; Zhou, L.

2017-12-01

Aerosols can absorb and scatter solar radiation, thus cause the total solar radiation reaching the surface to drop and the fraction of diffuse radiation to increase, which influence the surface radiation budget. The global surface radiation with and without consideration of aerosols are calculated by the Fu-Liou atmospheric radiative transfer model based on the MODIS aerosol products, CERES cloud products and other remote sensing data. The aerosol direct radiative effect is calculated based on the two scenarios of aerosols. Our calculation showed that in 2007, aerosols decreased the global total radiation by 9.16 W m-2 on average. Large decrease generally occurred in places with high AOD. As for the diffuse radiation, aerosol-induced changes were either positive or negative. Large increase generally occurred in places with high surface albedo, while large decrease generally occurred in places with high cloud fraction. The global aerosol-induced diffuse radiation change averaged 8.17 W m-2 in 2007. The aerosol direct radiative effect causes the photosynthetic active radiation to increase, and its influences on the global carbon cycle of terrestrial ecosystem are studied by using the Community Land Model (CLM). Calculations show that the aerosol direct radiative effects caused the global averages of terrestrial gross primary productivity (GPP), net primary productivity (NPP), heterotrophic respiration (RH), autotrophic respiration (RA), and net ecosystem productivity (Reco) to increase in 2007, with significant spatial variations however. The global average changes of GPP, NPP, NEP, RA, RH and Reco in 2007 were +6.47 gC m-2, +2.23 gC m-2, +0.34 gC m-2, +4.24 gC m-2, +1.89 gC m-2, +6.13 gC m-2, respectively. Examinations of the carbon fluxes show that the aerosol direct radiative effects influence the terrestrial ecosystem carbon cycles via the following two approaches: First, the diffuse fertilization effect, i.e. more diffuse radiation absorbed by vegetation shade leaves (photosynthetic active radiation, PAR) results in higher photosynthetic rates; Second, the radiation changes lead to changes in temperature and humidity, thereby changing the rates of the plant biophysical and chemical processes.

Film condensation in a horizontal rectangular duct

NASA Technical Reports Server (NTRS)

Lu, Qing; Suryanarayana, N. V.

1992-01-01

Condensation heat transfer in an annular flow regime with and without interfacial waves was experimentally investigated. The study included measurements of heat transfer rate with condensation of vapor flowing inside a horizontal rectangular duct and experiments on the initiation of interfacial waves in condensation, and adiabatic air-liquid flow. An analytical model for the condensation was developed to predict condensate film thickness and heat transfer coefficients. Some conclusions drawn from the study are that the condensate film thickness was very thin (less than 0.6 mm). The average heat transfer coefficient increased with increasing the inlet vapor velocity. The local heat transfer coefficient decreased with the axial distance of the condensing surface, with the largest change at the leading edge of the test section. The interfacial shear stress, which consisted of the momentum shear stress and the adiabatic shear stress, appeared to have a significant effect on the heat transfer coefficients. In the experiment, the condensate flow along the condensing surface experienced a smooth flow, a two-dimensional wavy flow, and a three-dimensional wavy flow. In the condensation experiment, the local wave length decreased with the axial distance of the condensing surface and the average wave length decreased with increasing inlet vapor velocity, while the wave speed increased with increasing vapor velocity. The heat transfer measurements are reliable. And, the ultrasonic technique was effective for measuring the condensate film thickness when the surface was smooth or had waves of small amplitude.

Thermal Energy Exchange Model and Water Loss of a Barrel Cactus, Ferocactus acanthodes1

PubMed Central

Lewis, Donald A.; Nobel, Park S.

1977-01-01

The influences of various diurnal stomatal opening patterns, spines, and ribs on the stem surface temperature and water economy of a CAM succulent, the barrel cactus Ferocactus acanthodes, were examined using an energy budget model. To incorporate energy exchanges by shortwave and longwave irradiation, latent heat, conduction, and convection as well as the heat storage in the massive stem, the plant was subdivided into over 100 internal and external regions in the model. This enabled the average surface temperature to be predicted within 1 C of the measured temperature for both winter and summer days. Reducing the stem water vapor conductance from the values observed in the field to zero caused the average daily stem surface temperature to increase only 0.7 C for a winter day and 0.3 C for a summer day. Thus, latent heat loss does not substantially reduce stem temperature. Although the surface temperatures averaged 18 C warmer for the summer day than for the winter day for a plant 41 cm tall, the temperature dependence of stomatal opening caused the simulated nighttime water loss rates to be about the same for the 2 days. Spines moderated the amplitude of the diurnal temperature changes of the stem surface, since the daily variation was 17 C for the winter day and 25 C for the summer day with spines compared with 23 C and 41 C, respectively, in their simulated absence. Ribs reduced the daytime temperature rise by providing 54% more area for convective heat loss than for a smooth circumscribing surface. In a simulation where both spines and ribs were eliminated, the daytime average surface temperature rose by 5 C. PMID:16660148

Nanotextured PDMS Substrates for Enhanced Roughness and Aptamer Immobilization for Cancer Cell Capture

NASA Astrophysics Data System (ADS)

Islam, Muhymin; Mahmood, Arif; Bellah, Md.; Kim, Young-Tae; Iqbal, Samir

2014-03-01

Detection of circulating tumor cells (CTCs) in the early stages of cancer is requires very sensitive approach. Nanotextured polydimethylsiloxane (PDMS) substrates were fabricated by micro reactive ion etching (Micro-RIE) to have better control on surface morphology and to improve the affinity of PDMS surfaces to capture cancer cells using surface immobilized aptamers. The aptamers were specific to epidermal growth factor receptors (EGFR) present in cell membranes, and overexpressed in tumor cells. We also investigated the effect of nano-scale features on cell capturing by implementing various surfaces of different roughnesses. Three different recipes were used to prepare nanotextured PDMS by micro-RIE using oxygen (O2) and carbon tetrafluoride (CF4). The measured average roughness of three nanotextured PDMS surfaces were found to impact average densities of captured cells. In all cases, nanotextured PDMS facilitated cell capturing possibly due to increased effective surface area of roughened substrates at nanoscale. It was also observed that cell capture efficiency was higher for higher surface roughness. The nanotextured PDMS substrates are thus useful for cancer cytology devices.

RCCM2-BATS model over tropical South America: Applications to tropical deforestation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hahmann, A.N.; Dickinson, R.E.

A multiyear simulation of the global climate uses a revised version of the National Center for Atmospheric Research (NCAR) Community Climate Model Version 2 (CCM2) coupled to the Biosphere-Atmosphere Transfer Scheme (BATS). It is compared with global and rain gauge precipitation climatologies to evaluate precipitation fields and European Centre for Medium-Range Forecasts analyses to evaluate the atmospheric circulation. The near-surface climate is compared with data from Amazonian field campaigns. The model simulation of the South American climate agrees closely with the observational record and is much improved from past simulations with previous versions of the NCAR Community Climate model overmore » this portion of the Tropics. The model is then used to study the local and regional response to tropical deforestation over Amazonia. In addition to the standard deforestation forcing, consisting mainly of increased albedo and decreased roughness length, two additional sensitivity experiments were conducted to assess the individual contributions from these forcings to the deforestation changes. The standard deforestation simulation shows slight increases in annually averaged surface temperature (+1{degrees}C) and reductions in annually averaged precipitation and evaporation (-363 and -149 mm yr{sup -1}, respectively). As expected, increases in surface albedo over Amazonia produce a reduction in net downward solar radiation at the surface and consequently a reduction in net surface radiation and surface latent heat flux. The roughness decrease, on the other hand, reduces the surface latent heat fluxes through decreases in the surface drag coefficient. The regional changes in moisture convergence and precipitation during the Amazonian wet season display a shift in the area of maximum precipitation rather than an overall decrease over the deforested area. 45 refs., 16 figs., 4 tabs.« less

A study of variation characteristics of Gobi broadband emissivity based on field observational experiments in northwestern China

NASA Astrophysics Data System (ADS)

Zheng, Zhi-yuan; Wei, Zhi-gang; Wen, Zhi-ping; Dong, Wen-jie; Li, Zhen-chao; Wen, Xiao-hang; Zhu, Xian; Chen, Chen; Hu, Shan-shan

2018-02-01

Land surface emissivity is a significant variable in energy budgets, land cover assessments, and environment and climate studies. However, the assumption of an emissivity constant is being used in Gobi broadband emissivity (GbBE) parameterization scheme in numerical models because of limited knowledge surrounding the spatiotemporal variation characteristics of GbBE. To address this issue, we analyzed the variation characteristics of GbBE and possible impact factor-surface soil moisture based on long-term continuous and high temporal resolution field observational experiments over a typical Gobi underlying surface in arid and semiarid areas in northwestern China. The results indicate that GbBE has obvious daily and diurnal variation features, especially diurnal cycle characteristics. The multi-year average of the daily average of GbBE is in the range of 0.932 to 0.970 with an average of 0.951 ± 0.008, and the average diurnal GbBE is in the range of 0.880 to 0.940 with an average of 0.906 ± 0.018. GbBE varies with surface soil moisture content. We observed a slight decrease in GbBE with an increase in soil moisture, although this change was not very obvious because of the low soil moisture in this area. Nevertheless, we think that soil moisture must be one of the most significant impact factors on GbBE in arid and semiarid areas. Soil moisture must be taken into account into the parameterization schemes of bare soil broadband emissivity in land surface models. Additional field experiments and studies should be carried out in order to clarify this issue.

A rotary drum dryer for palm sterilization: preliminary study of flow and heat transfer using CFD

NASA Astrophysics Data System (ADS)

Hanifarianty, S.; Legwiriyakul, A.; Alimalbari, A.; Nuntadusit, C.; Theppaya, T.; Wae-Hayee, M.

2018-01-01

Preliminary study in this article, the flow and the heat transfer of rotary drum dryer were simulated by using Computational Fluid Dynamics (CFD). A 3D modelling of rotary drum dryer including ambient air was created by considering transient simulation. The temperature distributions on rotary drum dryer surfaces of experimental setup during heating detected by using infrared camera were given to be boundary conditions of modelling. The average temperature at the surface of the drum lids was 80°C, and the average temperature on the heated surface of the drum was 130°C. The results showed that the internal temperature of air in drum modelling was increased relating on time dependent. The final air temperature inside the drum modelling was similar to the measurement results.

More than carbon sequestration: Biophysical climate benefits of restored savanna woodlands.

PubMed

Syktus, Jozef I; McAlpine, Clive A

2016-07-04

Deforestation and climate change are interconnected and represent major environmental challenges. Here, we explore the capacity of regional-scale restoration of marginal agricultural lands to savanna woodlands in Australia to reduce warming and drying resulting from increased concentration of greenhouse gases. We show that restoration triggers a positive feedback loop between the land surface and the atmosphere, characterised by increased evaporative fraction, eddy dissipation and turbulent mixing in the boundary-layer resulting in enhanced cloud formation and precipitation over the restored regions. The increased evapotranspiration results from the capacity deep-rooted woody vegetation to access soil moisture. As a consequence, the increase in precipitation provides additional moisture to soil and trees, thus reinforcing the positive feedback loop. Restoration reduced the rate of warming and drying under the transient increase in the radiative forcing of greenhouse gas emissions (RCP8.5). At the continental scale, average summer warming for all land areas was reduced by 0.18 (o)C from 4.1 (o)C for the period 2056-2075 compared to 1986-2005. For the restored regions (representing 20% of Australia), the averaged surface temperature increase was 3.2 °C which is 0.82 °C cooler compared to agricultural landscapes. Further, there was reduction of 12% in the summer drying of the near-surface soil for the restored regions.

Public-supply water use in Kansas, 1990-2012

USGS Publications Warehouse

Kenny, Joan F.

2014-01-01

This fact sheet describes water-use data collection and quantities of surface water and groundwater diverted for public supply in Kansas for the years 1990 through 2012. Data used in this fact sheet are from the Kansas Department of Agriculture’s Division of Water Resources and the Kansas Water Office. Water used for public supply represents about 10 percent of all reported water withdrawals in Kansas. Between 1990 and 2012, annual withdrawals for public supply ranged from a low of 121 billion gallons in 1993 to a high of 159 billion gallons in 2012. Differences in annual withdrawals were associated primarily with climatic fluctuations. Six suppliers distributed about one-half of the total water withdrawn for public supply, and nearly three-quarters of the surface water. Surface water represented between 52 and 61 percent of total annual withdrawals for public supply. The proportion of surface water obtained through contracts from Federal reservoirs increased from less than 5 percent in the 1990s to 8 percent in 2011 and 2012. More than 99 percent of the reported water withdrawn for public supply in Kansas in 2012 was metered, which was an increase from 92 percent in 1990. State population increased steadily from 2.5 million people in 1990 to 2.9 million in 2012. Recent estimates indicate that about 95 percent of the total population was served by public water supply; the remainder obtained water from other sources such as private wells. Average per capita water use as calculated for State conservation planning purposes varied by region of the State. The smallest regional average water use for the years 1990–2012 was 98 gallons per person per day in easternmost Kansas, and the largest regional average water use was 274 gallons per person per day in westernmost Kansas.

Modification of polycarbonate surface in oxidizing plasma

NASA Astrophysics Data System (ADS)

Ovtsyn, A. A.; Smirnov, S. A.; Shikova, T. G.; Kholodkov, I. V.

2017-11-01

The properties of the surface of the film polycarbonate Lexan 8010 were experimentally studied after treatment in a DC discharge plasma in oxygen and air at pressures of 50-300 Pa and a discharge current of 80 mA. The contact angles of wetting and surface energies are measured. The topography of the surface was investigated by atomic force microscopy. The chemical composition of the surface was determined from the FT-IR spectroscopy data in the variant of total internal reflection, as well as X-ray photoelectron spectroscopy. Treatment in the oxidizing plasma leads to a change in morphology (average roughness increases), an increase in the surface energy, and the concentration of oxygen-containing groups (hydroxyl groups, carbonyl groups in ketones or aldehydes and in oxyketones) on the surface of the polymer. Possible reasons for the difference in surface properties of polymer under the action of oxygen and air plasma on it are discussed.

A 10 Year Climatology of Arctic Cloud Fraction and Radiative Forcing at Barrow, Alaska

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dong, Xiquan; Xi, Baike; Crosby, Kathryn

2010-09-15

A 10-yr record of Arctic cloud fraction and surface radiation budget has been generated using data collected from June 1998 to May 2008 at the Atmospheric Radiation Measurement (ARM) North Slope of Alaska (NSA) site and the nearby NOAA Barrow Observatory (BRW). The record includes the seasonal variations of cloud fraction (CF), cloud liquid water path (LWP), precipitable water vapor (PWV), surface albedo, shortwave (SW) and longwave (LW) fluxes and cloud radative forcings (CRFs), as well as their decadal variations. Values of CF derived from different instruments and methods agree well, having an annual average of ~0.74. Cloudiness increases frommore » March to May, remains high (~0.8-0.9) from May to October, and then decreases over winter. More clouds and higher LWP and PWV occurred during the warm season (May-October) than the cold season (November-April). These results are strongly associated with southerly flow which transports warm, moist air masses to Barrow from the North Pacific and over area of Alaska already free of snow during the warm season and with a dipole pattern of pressure in which a high is centered over the Beaufort Sea and low over the Aleutians during the cold season. The monthly means of estimated clear-sky and measured allsky SW-down and LW-down fluxes at the two facilities are almost identical with the annual mean differences less than 1.6 W m-2. The downwelling and upwelling LW fluxes remain almost constant from January to March, then increase from March and peak during July-August. SW-down fluxes are primarily determined by seasonal changes in the intensity and duration of insolation over Northern Alaska, and are also strongly dependent on cloud fraction and optical depth, and surface albedo. The monthly variations of NET CRF generally follow the cycle of SW CRF, modulated by LW effects. On annual average, the negative SW CRF and positive LW CRF tend to cancel, resulting in annual average NET CRF of 2-4.5 Wm-2. Arctic clouds have a 3 net warming effect on the surface throughout the year, with exception of the snow-free period from middle June to middle September when there tends to be a cooling effect. The daily average surface albedos agree well at the two sites remaining high (>0.8) until late May, dropping below 0.2 after the snow melts around June and increasing during autumn once snow begins to accumulate. On the basis of long-term regression analyses CF has decreased by about 0.048 while temperature has risen by ≈1.1 K over the 10-yr period, which can be characterized by tendencies of warming mainly during December and April. With regard to the 2007 record minimum Arctic ice extent, this study provides additional empirical evidence that decreased cloud cover and increased SW-down flux during summer contributed to anomalous ice melt in the region north of Barrow. At Barrow, average June-August CF decreased by 0.062 in 2007 from the 10-yr mean, while SW-down and NET fluxes increased by 28.4 Wm-2 and 11.3 Wm-2, respectively. The increase in the NET radiative flux during summer 2007 most likely contributed to an increase in surface air temperature of 1.6 K.« less

Chemical weathering rates of a soil chronosequence on granitic alluvium: I. Quantification of mineralogical and surface area changes and calculation of primary silicate reaction rates

USGS Publications Warehouse

White, A.F.; Blum, A.E.; Schulz, M.S.; Bullen, T.D.; Harden, J.W.; Peterson, M.L.

1996-01-01

Mineral weathering rates are determined for a series of soils ranging in age from 0.2-3000 Ky developed on alluvial terraces near Merced in the Central Valley of California. Mineralogical and elemental abundances exhibit time-dependent trends documenting the chemical evolution of granitic sand to residual kaolinite and quartz. Mineral losses with time occur in the order: hornblende > plagioclase > K-feldspar. Maximum volume decreases of >50% occur in the older soils. BET surface areas of the bulk soils increase with age, as do specific surface areas of aluminosilicate mineral fractions such as plagioclase, which increases from 0.4-1.5 m2 g-1 over 600 Ky. Quartz surface areas are lower and change less with time (0.11-0.23 m2 g-1). BET surface areas correspond to increasing external surface roughness (?? = 10-600) and relatively constant internal surface area (??? 1.3 m2 g-1). SEM observations confirm both surface pitting and development of internal porosity. A numerical model describes aluminosilicate dissolution rates as a function of changes in residual mineral abundance, grain size distributions, and mineral surface areas with time. A simple geometric treatment, assuming spherical grains and no surface roughness, predicts average dissolution rates (plagioclase, 10-17.4; K-feldspar, 10-17.8; and hornblende, 10-17.5 mol cm-1 s-1) that are constant with time and comparable to previous estimates of soil weathering. Average rates, based on BET surface area measurements and variable surface roughnesses, are much slower (plagioclase, 10-19.9; K-feldspar, 10-20.5; and hornblende 10-20.1 mol cm-2 s-1). Rates for individual soil horizons decrease by a factor of 101.5 over 3000 Ky indicating that the surface reactivities of minerals decrease as the physical surface areas increase. Rate constants based on BET estimates for the Merced soils are factors of 103-104 slower than reported experimental dissolution rates determined from freshly prepared silicates with low surface roughness (?? <10). This study demonstrates that the utility of experimental rate constants to predict weathering in soils is limited without consideration of variable surface areas and processes that control the evolution of surface reactivity with time.

Low reservoir ages for the surface ocean from mid-Holocene Florida corals

USGS Publications Warehouse

Druffel, E.R.M.; Robinson, L.F.; Griffin, S.; Halley, R.B.; Southon, J.R.; Adkins, J.F.

2008-01-01

The 14C reservoir age of the surface ocean was determined for two Holocene periods (4908-4955 and 3008-3066 calendar (cal) B.P.) using U/Th-dated corals from Biscayne National Park, Florida, United States. We found that the average reservoir ages for these two time periods (294 ?? 33 and 291 ?? 27 years, respectively) were lower than the average value between A.D. 1600 and 1900 (390 ?? 60 years) from corals. It appears that the surface ocean was closer to isotopic equilibrium with CO2 in the atmosphere during these two time periods than it was during recent times. Seasonal ??18O measurements from the younger coral are similar to modern values, suggesting that mixing with open ocean waters was indeed occurring during this coral's lifetime. Likely explanations for the lower reservoir age include increased stratification of the surface ocean or increased ??14C values of subsurface waters that mix into the surface. Our results imply that a more correct reservoir age correction for radiocarbon measurements of marine samples in this location from the time periods ???3040 and ???4930 cal years B.P. is ???292 ?? 30 years, less than the canonical value of 404 ?? 20 years. Copyright 2008 by the American Geophysical Union.

Changes in the firn structure of the western Greenland Ice Sheet caused by recent warming

DOE PAGES

de la Peña, S.; Howat, I. M.; Nienow, P. W.; ...

2015-06-11

Atmospheric warming over the Greenland Ice Sheet during the last 2 decades has increased the amount of surface meltwater production, resulting in the migration of melt and percolation regimes to higher altitudes and an increase in the amount of ice content from refrozen meltwater found in the firn above the superimposed ice zone. Here we present field and airborne radar observations of buried ice layers within the near-surface (0–20 m) firn in western Greenland, obtained from campaigns between 1998 and 2014. We find a sharp increase in firn-ice content in the form of thick widespread layers in the percolation zone,more » which decreases the capacity of the firn to store meltwater. The estimated total annual ice content retained in the near-surface firn in areas with positive surface mass balance west of the ice divide in Greenland reached a maximum of 74 ± 25 Gt in 2012, when compared to the 1958–1999 average of 13 ± 2 Gt, while the percolation zone area more than doubled between 2003 and 2012. Increased melt and column densification resulted in surface lowering averaging -0.80 ± 0.39 m yr -1 between 1800 and 2800 m in the accumulation zone of western Greenland. Since 2007, modeled annual melt and refreezing rates in the percolation zone at elevations below 2100 m surpass the annual snowfall from the previous year, implying that mass gain in the region is retained after melt in the form of refrozen meltwater. Furthermore, if current melt trends over high elevation regions continue, subsequent changes in firn structure will have implications for the hydrology of the ice sheet and related abrupt seasonal densification could become increasingly significant for altimetry-derived ice sheet mass balance estimates.« less

Rugometric and microtopographic non-invasive inspection in dental-resin composites and zirconia ceramics

NASA Astrophysics Data System (ADS)

Fernández-Oliveras, Alicia; Costa, Manuel F. M.; Pecho, Oscar E.; Rubiño, Manuel; Pérez, María. M.

2013-11-01

Surface properties are essential for a complete characterization of biomaterials. In restorative dentistry, the study of the surface properties of materials meant to replace dental tissues in an irreversibly diseased tooth is important to avoid harmful changes in future treatments. We have experimentally analyzed the surface characterization parameters of two different types of dental-resin composites and pre-sintered and sintered zirconia ceramics. We studied two shades of both composite types and two sintered zirconia ceramics: colored and uncolored. Moreover, a surface treatment was applied to one specimen of each dental-resin. All the samples were submitted to rugometric and microtopographic non-invasive inspection with the MICROTOP.06.MFC laser microtopographer in order to gather meaningful statistical parameters such as the average roughness (Ra), the root-mean-square deviation (Rq), the skewness (Rsk), and the kurtosis of the surface height distribution (Rku). For a comparison of the different biomaterials, the uncertainties associated to the surface parameters were also determined. With respect to Ra and Rq, significant differences between the composite shades were found. Among the dental resins, the nanocomposite presented the highest values and, for the zirconia ceramics, the pre-sintered sample registered the lowest ones. The composite performance may have been due to cluster-formation variations. Except for the composites with the surface treatment, the sample surfaces had approximately a normal distribution of heights. The surface treatment applied to the composites increased the average roughness and moved the height distribution farther away from the normal distribution. The zirconia-sintering process resulted in higher average roughness without affecting the height distribution.

Laser shock peening studies on SS316LN plate with various sacrificial layers

NASA Astrophysics Data System (ADS)

Yella, Pardhu; Venkateswarlu, P.; Buddu, Ramesh K.; Vidyasagar, D. V.; Sankara Rao, K. Bhanu; Kiran, P. Prem; Rajulapati, Koteswararao V.

2018-03-01

Laser shock peening (LSP) has been utilized to modify the surface characteristics of SS316LN plates of 6 mm thickness. Laser pulse widths employed are 30 ps and 7 ns and the laser energy was varied in the range 5-90 mJ. Peening was performed in direct ablation mode as well as with various sacrificial layers such as black paint, transparent adhesive tape and absorbing adhesive tape. The surface characteristics were greatly influenced by the type of sacrificial layer employed. The average surface roughness values are about 0.4 μm when the black paint and transparent adhesive tape were used as sacrificial layers. In contrast to this, using absorbent adhesive tape as a sacrificial layer has resulted in an average surface roughness of about 0.04 μm. Irrespective of pulse durations (30 ps or 7 ns), absorbent adhesive tape has always resulted in compressive residual stresses whereas other layers appear to be not that effective. In case of 30 ps pulse, as the laser energy was increased from 5 mJ to 25 mJ, there was a texture observed in (111) reflection of X-ray diffractograms and the center of the peak has also gradually shifted to left. X-ray line profile analysis suggests that with the increase in laser energy, lattice microstrain also has increased. This lattice microstrain appears to be resulting from the increased dislocation density in the peened sample as evidenced during transmission electron microscopic investigations. Cross-sectional scanning electron microscopy performed on peened samples suggests that absorbing adhesive tape brings no surface damage to the samples whereas other sacrificial layers have resulted in some surface damage. Based on all these structural and microstructural details, it is recommended that absorbent tape could be used as a sacrificial layer during LSP process which induces surface residual stresses with no damage to the sample surface.

Behavior of aircraft antiskid breaking systems on dry and wet runway surfaces: A slip-ratio-controlled system with ground speed reference from unbraked nose wheel

NASA Technical Reports Server (NTRS)

Tanner, J. A.; Stubbs, S. M.

1977-01-01

An experimental investigation was conducted at the Langley aircraft landing loads and traction facility to study the braking and cornering response of a slip ratio controlled aircraft antiskid braking system with ground speed reference derived from an unbraked nose wheel. The investigation, conducted on dry and wet runway surfaces, utilized one main gear wheel, brake, and tire assembly of a DC-9 series 10 airplane. During maximum braking, the average ratio of the drag force friction coefficient developed by the antiskid system to the maximum drag force friction coefficient available was higher on the dry surface than on damp and flooded surfaces, and was reduced with lighter vertical loads, higher yaw angles, and when new tire treads were replaced by worn treads. Similarly, the average ratio of side force friction coefficient developed by the tire under antiskid control to the maximum side force friction coefficient available to a freely rolling yawed tire decreased with increasing yaw angle, generally increased with ground speed, and decreased when tires with new treads were replaced by those with worn treads.

Self-organized nanostructure formation on the graphite surface induced by helium ion irradiation

NASA Astrophysics Data System (ADS)

Dutta, N. J.; Mohanty, S. R.; Buzarbaruah, N.; Ranjan, M.; Rawat, R. S.

2018-06-01

The effects of helium ion irradiation on the graphite surface are studied by employing a plasma focus device. The device emits helium ion pulse having energies in the range of a few keV to a few MeV and flux on the order of 1025 m-2 s-1 at 60 mm axial position from the anode tip. The field emission scanning electron microscopy confirms the formation of multi-modal spherical and elongated agglomerated structures on irradiated samples surface with increase in agglomerate size with increasing number of irradiation shots. The transient annealing in each irradiation was not enough to cause the Oswald ripening or sintering of particles into bigger particle or crystal size but only resulted in clustering. The atomic force micrographs reveal an increase in average surface roughness with increasing ion irradiation. The Raman study demonstrates increase in disordered D peak along with reduced crystallite size (La) with increasing number of irradiation shots.

Acoustic Effects in Classical Nucleation Theory

NASA Technical Reports Server (NTRS)

Baird, J. K.; Su, C.-H.

2017-01-01

The effect of sound wave oscillations on the rate of nucleation in a parent phase can be calculated by expanding the free energy of formation of a nucleus of the second phase in powers of the acoustic pressure. Since the period of sound wave oscillation is much shorter than the time scale for nucleation, the acoustic effect can be calculated as a time average of the free energy of formation of the nucleus. The leading non-zero term in the time average of the free energy is proportional to the square of the acoustic pressure. The Young-Laplace equation for the surface tension of the nucleus can be used to link the time average of the square of the pressure in the parent phase to its time average in the nucleus of the second phase. Due to the surface tension, the pressure in the nuclear phase is higher than the pressure in the parent phase. The effect is to lower the free energy of formation of the nucleus and increase the rate of nucleation.

Field application of farmstead runoff to vegetated filter strips: surface and subsurface water quality assessment.

PubMed

Larson, Rebecca A; Safferman, Steven I

2012-01-01

Farmstead runoff poses significant environmental impacts to ground and surface waters. Three vegetated filter strips were assessed for the treatment of dairy farmstead runoff at the soil surface and subsurface at 0.3- or 0. 46-m and 0. 76-m depths for numerous storm events. A medium-sized Michigan dairy was retrofitted with two filter strips on sandy loam soil and a third filter strip was implemented on a small Michigan dairy with sandy soil to collect and treat runoff from feed storage, manure storage, and other impervious farmstead areas. All filter strips were able to eliminate surface runoff via infiltration for all storm events over the duration of the study, eliminating pollutant contributions to surface water. Subsurface effluent was monitored to determine the contributing groundwater concentrations of numerous pollutants including chemical oxygen demand (COD), metals, and nitrates. Subsurface samples have an average reduction of COD concentrations of 20, 11, and 85% for the medium dairy Filter Strip 1 (FS1), medium dairy Filter Strip 2 (FS2), and the small Michigan dairy respectively, resulting in average subsurface concentrations of 355, 3960, and 718 mg L COD. Similar reductions were noted for ammonia and total Kjeldahl nitrogen (TKN) in the subsurface effluent. The small Michigan dairy was able to reduce the pollutant leachate concentrations of COD, TKN, and ammonia over a range of influent concentrations. Increased influent concentrations in the medium Michigan dairy filter strips resulted in an increase in COD, TKN, and ammonia concentrations in the leachate. Manganese was leached from the native soils at all filter strips as evidenced by the increase in manganese concentrations in the leachate. Nitrate concentrations were above standard drinking water limits (10 mg L), averaging subsurface concentrations of 11, 45, and 25 mg L NO-N for FS1, FS2, and the small Michigan dairy, respectively. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Memory of irrigation effects on hydroclimate and its modeling challenge

NASA Astrophysics Data System (ADS)

Chen, Fei; Xu, Xiaoyu; Barlage, Michael; Rasmussen, Roy; Shen, Shuanghe; Miao, Shiguang; Zhou, Guangsheng

2018-06-01

Irrigation modifies land-surface water and energy budgets, and also influences weather and climate. However, current earth-system models, used for weather prediction and climate projection, are still in their infancy stage to consider irrigation effects. This study used long-term data collected from two contrasting (irrigated and rainfed) nearby maize-soybean rotation fields, to study the effects of irrigation memory on local hydroclimate. For a 12 year average, irrigation decreases summer surface-air temperature by less than 1 °C and increases surface humidity by 0.52 g kg‑1. The irrigation cooling effect is more pronounced and longer lasting for maize than for soybean. Irrigation reduces maximum, minimum, and averaged temperature over maize by more than 0.5 °C for the first six days after irrigation, but its temperature effect over soybean is mixed and negligible two or three days after irrigation. Irrigation increases near-surface humidity over maize by about 1 g kg‑1 up to ten days and increases surface humidity over soybean (~ 0.8 g kg‑1) with a similar memory. These differing effects of irrigation memory on temperature and humidity are associated with respective changes in the surface sensible and latent heat fluxes for maize and soybean. These findings highlight great need and challenges for earth-system models to realistically simulate how irrigation effects vary with crop species and with crop growth stages, and to capture complex interactions between agricultural management and water-system components (crop transpiration, precipitation, river, reservoirs, lakes, groundwater, etc.) at various spatial and temporal scales.

Retinotopic Maps, Spatial Tuning, and Locations of Human Visual Areas in Surface Coordinates Characterized with Multifocal and Blocked fMRI Designs

PubMed Central

Henriksson, Linda; Karvonen, Juha; Salminen-Vaparanta, Niina; Railo, Henry; Vanni, Simo

2012-01-01

The localization of visual areas in the human cortex is typically based on mapping the retinotopic organization with functional magnetic resonance imaging (fMRI). The most common approach is to encode the response phase for a slowly moving visual stimulus and to present the result on an individual's reconstructed cortical surface. The main aims of this study were to develop complementary general linear model (GLM)-based retinotopic mapping methods and to characterize the inter-individual variability of the visual area positions on the cortical surface. We studied 15 subjects with two methods: a 24-region multifocal checkerboard stimulus and a blocked presentation of object stimuli at different visual field locations. The retinotopic maps were based on weighted averaging of the GLM parameter estimates for the stimulus regions. In addition to localizing visual areas, both methods could be used to localize multiple retinotopic regions-of-interest. The two methods yielded consistent retinotopic maps in the visual areas V1, V2, V3, hV4, and V3AB. In the higher-level areas IPS0, VO1, LO1, LO2, TO1, and TO2, retinotopy could only be mapped with the blocked stimulus presentation. The gradual widening of spatial tuning and an increase in the responses to stimuli in the ipsilateral visual field along the hierarchy of visual areas likely reflected the increase in the average receptive field size. Finally, after registration to Freesurfer's surface-based atlas of the human cerebral cortex, we calculated the mean and variability of the visual area positions in the spherical surface-based coordinate system and generated probability maps of the visual areas on the average cortical surface. The inter-individual variability in the area locations decreased when the midpoints were calculated along the spherical cortical surface compared with volumetric coordinates. These results can facilitate both analysis of individual functional anatomy and comparisons of visual cortex topology across studies. PMID:22590626

The Impact of In Vitro Accelerated Aging, Approximating 30 and 60 Years In Vivo, on Commercially Available Zirconia Dental Implants.

PubMed

Monzavi, Mona; Noumbissi, Sammy; Nowzari, Hessam

2017-04-01

Despite increased popularity of Zirconia dental implants, concerns have been raised regarding low temperature degradation (LTD) and its effect on micro-structural integrity. This study evaluated the effect of LTD on four types of Zirconia dental implants at 0, 30, and 60 years of artificial aging. The impact of aging on t-m transformation and micro crack formation was measured. Accelerated aging at 15 and 30 hours, approximating 30 and 60 years in vivo, aged 36 Zirconia dental implants: Z systems ® (A), Straumann ® (B), Ceraroot ® (C), and Zeramex ® (D). Focused ion beam-scanning electron microscopic analysis determined the micro structural features, phase transformation, and the formation of micro cracks. At 15 hours, type A implant presented with micro cracks and t-m transformation of 0.9 µm and 3.1 µm, respectively. At 30 hours, micro cracks remained shallow (1 µm). At 15 hours, type B implant presented micro cracks (0.7 µm) and grain transformation (1.2 µm). At 30 hours, these features remained superficial at 0.6 and 1.5 µm, respectively. Type C implant presented surface micro cracks of 0.3 µm at 15 hours. The depth of t-m transformation slightly increased to 1.4 µm. At 30 hours, number of micro cracks increased at the surface to an average depth of 1.5 µm. Depth of t-m transformation increased to an average of 2.5 µm. At 15 hours, micro cracks remained superficial (0.8 µm) for type D implant and depth of t-m transformation increased to 2.3 µm. At 30 hours, the depth of micro cracks increased to an average of 1.3 µm followed by increased t-m transformation to a depth of 4.1 µm. Depth of grain transformation remained within 1-4 µm from the surface. The effect of aging was minimal for all Zirconia implants. © 2016 Wiley Periodicals, Inc.

Measuring Skew in Average Surface Roughness as a Function of Surface Preparation

NASA Technical Reports Server (NTRS)

Stahl, Mark

2015-01-01

Characterizing surface roughness is important for predicting optical performance. Better measurement of surface roughness reduces polishing time, saves money and allows the science requirements to be better defined. This study characterized statistics of average surface roughness as a function of polishing time. Average surface roughness was measured at 81 locations using a Zygo white light interferometer at regular intervals during the polishing process. Each data set was fit to a normal and Largest Extreme Value (LEV) distribution; then tested for goodness of fit. We show that the skew in the average data changes as a function of polishing time.

Laser surface modification of 316 L stainless steel with bioactive hydroxyapatite.

PubMed

Balla, Vamsi Krishna; Das, Mitun; Bose, Sreyashree; Ram, G D Janaki; Manna, Indranil

2013-12-01

Laser-engineered net shaping (LENS™), a commercial additive manufacturing process, was used to modify the surfaces of 316 L stainless steel with bioactive hydroxyapatite (HAP). The modified surfaces were characterized in terms of their microstructure, hardness and apatite forming ability. The results showed that with increase in laser energy input from 32 J/mm(2) to 59 J/mm(2) the thickness of the modified surface increased from 222±12 μm to 355±6 μm, while the average surface hardness decreased marginally from 403±18 HV0.3 to 372±8 HV0.3. Microstructural studies showed that the modified surface consisted of austenite dendrites with HAP and some reaction products primarily occurring in the inter-dendritic regions. Finally, the surface-modified 316 L samples immersed in simulated body fluids showed significantly higher apatite precipitation compared to unmodified 316 L samples. © 2013.

Heterogeneity in horse ferritins. A comparative study of surface charge, iron content and kinetics of iron uptake.

PubMed Central

Russell, S M; Harrison, P M

1978-01-01

Horse ferritins from different organs show heterogeneity on electrofocusing in Ampholine gradients. Both ferritin and apoferritin from liver and spleen could be fractionated with respect to surface charge by serial precipitation with (NH4)2SO4. In the ferritin fractions, increasing iron content parallels increasing isoelectric point. After removal of their iron, those fractions which originally contained most iron accumulated added iron at the fastest rates. When unfractionated ferritins from different organs were compared the average isoelectric point increased in order spleen less than liver less than kidney less than heart. The order of initial rates of iron uptake by the apoferritins was spleen greater than kidney greater than heart and initial average iron contents also followed this order. The relatively low rates of iron accumulation by iron-poor molecules may have been due to structural alteration, to degradation, to activation of the iron-rich molecules or to other factors. Images Fig. 1. Fig. 2. PMID:736908

Natural and unnatural oil slicks in the Gulf of Mexico

USGS Publications Warehouse

MacDonald, Ian R.; O. Garcia-Pineda,; A. Beet,; S. Daneshgar Asl,; L. Feng,; D. G. Graettinger,; D. French-McCay,; J. Holmes,; C. Hu,; F. Huffer,; I. Leifer,; F. Mueller-Karger,; A. Solow,; M. Silva,; Swayze, Gregg A.

2015-01-01

When wind speeds are 2 – 10 m s−1, reflective contrasts in the ocean surface make oil slicks visible to synthetic aperture radar (SAR) under all sky conditions. Neural network analysis of satellite SAR images quantified the magnitude and distribution of surface oil in the Gulf of Mexico from persistent, natural seeps and from the Deepwater Horizon (DWH) discharge. This analysis identified 914 natural oil seep zones across the entire Gulf of Mexico in pre-2010 data. Their ∼0.1 µm slicks covered an aggregated average of 775 km2. Assuming an average volume of 77.5 m3over an 8 – 24 h lifespan per oil slick, the floating oil indicates a surface flux of 2.5 – 9.4 × 104 m3 y−1. Oil from natural slicks was regionally concentrated: 68%, 25%, 7%, and <1% of the total was observed in the NW, SW, NE and SE Gulf, respectively. This reflects differences in basin history and hydrocarbon generation. SAR images from 2010 showed that the 87-day DWH discharge produced a surface-oil footprint fundamentally different from background seepage, with an average ocean area of 11,200 km2 (SD 5,028) and a volume of 22,600 m3 (SD 5,411). Peak magnitudes of oil were detected during equivalent, ∼14-day intervals around 23 May and 18 June, when wind speeds remained <5 m s−1. Over this interval, aggregated volume of floating oil decreased by 21%; area covered increased by 49% (p < .1), potentially altering its ecological impact. The most likely causes were increased applications of dispersant and surface burning operations.

Natural and unnatural oil slicks in the Gulf of Mexico

DOE PAGES

MacDonald, I. R.; Garcia-Pineda, O.; Beet, A.; ...

2015-12-28

When wind speeds are 2–10 m s -1, reflective contrasts in the ocean surface make oil slicks visible to synthetic aperture radar (SAR) under all sky conditions. Neural network analysis of satellite SAR images quantified the magnitude and distribution of surface oil in the Gulf of Mexico from persistent,natural seeps and from the Deep water Horizon (DWH) discharge. This analysis identified 914 natural oil seep zones across the entire Gulf of Mexico in pre-2010 data. Their ~0.1 mm slicks covered an aggregated average of 775 km 2. Assuming an average volume of 77.5 m 3 over an 8–24 h lifespanmore » per oil slick, the floating oil indicates a surface flux of 2.5–9.4 X 10 4 m 3 yr -1. Oil from natural slicks was regionally concentrated: 68%, 25%, 7%, and <1% of the total was observed in the NW, SW, NE, and SE Gulf, respectively. This reflects differences in basin history and hydrocarbon generation. SAR images from 2010 showed that the 87 day DWH discharge produced a surface-oil footprint fundamentally different from background seepage, with an average ocean area of 11,200 km 2(SD 5028) and a volume of 22,600 m 3(SD 5411). Peak magnitudes of oil were detected during equivalent, ~14 day intervals around 23 May and 18 June, when wind speeds remained <5ms -1. Over this interval, aggregated volume of floating oil decreased by 21%; area covered increased by 49% (p < 0.1), potentially altering its ecological impact. Furthermore, the most likely causes were increased applications of dispersant and surface burning operations.« less

Impacts of vehicles on natural terrain at seven sites in the San Francisco Bay area

USGS Publications Warehouse

Wilshire, H.G.; Nakata, J.K.; Shipley, S.; Prestegaard, K.

1978-01-01

The impacts of off-road vehicles on vegetation and soil were investigated at seven representative sites in the San Francisco Bay area. Plant cover of grass and chaparral (with shrubs to 4 m tall) have been stripped by the two- and four-wheel vehicles in use. Impacts on loamy soils include increased surface strength (as much as 275 bars), increased bulk density (averaging 18%) to depths of 90 cm or more, reduction of soil moisture by an average 43% to 30 cm depths, greatly reduced infiltration, extension of the diurnal temperature range by as much as 12??C, and reduction of organic carbon by an average 33% in exposed soils. Very sandy soils respond similarly to vehicular use except that moisture is increased and surface strength of beach sand is decreased. These physical and chemical impacts reduce the land's capability of restoring its vegetative cover, which in turn adversely affects animal populations. Both the loss of plant cover and the physical changes caused by vehicles promote erosion. Measured soil and substrate losses from vehicular use zones range from 7 to 1180 kg/m2. The estimated erosion rate of the Chabot Park site exceeds the rate of erosion considered a serious problem by a factor 30, it exceeds United States Soil Conservation Service tolerance values by a factor of 46, and it exceeds average San Francisco Bay area erosion rates by a factor of 17. The resulting soil losses are effectively permanent. Neither the increased sediment yield nor the increased runoff is accomodated on the sites of use, and both are causing adverse effects to neighboring properties. ?? 1978 Springer-Verlag New York Inc.

Interactions between aerosol absorption, thermodynamics, dynamics, and microphysics and their impacts on a multiple-cloud system

NASA Astrophysics Data System (ADS)

Lee, Seoung Soo; Li, Zhanqing; Mok, Jungbin; Ahn, Myoung-Hwan; Kim, Byung-Gon; Choi, Yong-Sang; Jung, Chang-Hoon; Yoo, Hye Lim

2017-12-01

This study investigates how the increasing concentration of black carbon aerosols, which act as radiation absorbers as well as agents for the cloud-particle nucleation, affects stability, dynamics and microphysics in a multiple-cloud system using simulations. Simulations show that despite increases in stability due to increasing concentrations of black carbon aerosols, there are increases in the averaged updraft mass fluxes (over the whole simulation domain and period). This is because aerosol-enhanced evaporative cooling intensifies convergence near the surface. This increase in the intensity of convergence induces an increase in the frequency of updrafts with the low range of speeds, leading to the increase in the averaged updraft mass fluxes. The increase in the frequency of updrafts induces that in the number of condensation entities and this leads to more condensation and cloud liquid that acts to be a source of the accretion of cloud liquid by precipitation. Hence, eventually, there is more accretion that offsets suppressed autoconversion, which results in negligible changes in cumulative precipitation as aerosol concentrations increase. The increase in the frequency of updrafts with the low range of speeds alters the cloud-system organization (represented by cloud-depth spatiotemporal distributions and cloud-cell population) by supporting more low-depth clouds. The altered organization in turn alters precipitation spatiotemporal distributions by generating more weak precipitation events. Aerosol-induced reduction in solar radiation that reaches the surface induces more occurrences of small-value surface heat fluxes, which in turn supports the more low-depth clouds and weak precipitation together with the greater occurrence of low-speed updrafts.

A bone marrow toxicity model for 223Ra alpha-emitter radiopharmaceutical therapy

NASA Astrophysics Data System (ADS)

Hobbs, Robert F.; Song, Hong; Watchman, Christopher J.; Bolch, Wesley E.; Aksnes, Anne-Kirsti; Ramdahl, Thomas; Flux, Glenn D.; Sgouros, George

2012-05-01

Ra-223, an α-particle emitting bone-seeking radionuclide, has recently been used in clinical trials for osseous metastases of prostate cancer. We investigated the relationship between absorbed fraction-based red marrow dosimetry and cell level-dosimetry using a model that accounts for the expected localization of this agent relative to marrow cavity architecture. We show that cell level-based dosimetry is essential to understanding potential marrow toxicity. The GEANT4 software package was used to create simple spheres representing marrow cavities. Ra-223 was positioned on the trabecular bone surface or in the endosteal layer and simulated for decay, along with the descendants. The interior of the sphere was divided into cell-size voxels and the energy was collected in each voxel and interpreted as dose cell histograms. The average absorbed dose values and absorbed fractions were also calculated in order to compare those results with previously published values. The absorbed dose was predominantly deposited near the trabecular surface. The dose cell histogram results were used to plot the percentage of cells that received a potentially toxic absorbed dose (2 or 4 Gy) as a function of the average absorbed dose over the marrow cavity. The results show (1) a heterogeneous distribution of cellular absorbed dose, strongly dependent on the position of the cell within the marrow cavity; and (2) that increasing the average marrow cavity absorbed dose, or equivalently, increasing the administered activity resulted in only a small increase in potential marrow toxicity (i.e. the number of cells receiving more than 4 or 2 Gy), for a range of average marrow cavity absorbed doses from 1 to 20 Gy. The results from the trabecular model differ markedly from a standard absorbed fraction method while presenting comparable average dose values. These suggest that increasing the amount of radioactivity may not substantially increase the risk of toxicity, a result unavailable to the absorbed fraction method of dose calculation.

Speckle phase near random surfaces

NASA Astrophysics Data System (ADS)

Chen, Xiaoyi; Cheng, Chuanfu; An, Guoqiang; Han, Yujing; Rong, Zhenyu; Zhang, Li; Zhang, Meina

2018-03-01

Based on Kirchhoff approximation theory, the speckle phase near random surfaces with different roughness is numerically simulated. As expected, the properties of the speckle phase near the random surfaces are different from that in far field. In addition, as scattering distances and roughness increase, the average fluctuations of the speckle phase become larger. Unusually, the speckle phase is somewhat similar to the corresponding surface topography. We have performed experiments to verify the theoretical simulation results. Studies in this paper contribute to understanding the evolution of speckle phase near a random surface and provide a possible way to identify a random surface structure based on its speckle phase.

Performance of Inductors Attached to a Galvanizing Bath

NASA Astrophysics Data System (ADS)

Zhou, Xinping; Yuan, Shuo; Liu, Chi; Yang, Peng; Qian, Chaoqun; Song, Bao

2013-12-01

By taking a galvanizing bath with inductors from an Iron and Steel Co., Ltd as an example, the distributions of Lorentz force and generated heat in the inductor are simulated. As a result, the zinc flow and the temperature distribution driven by the Lorentz force and the generated heat in the inductor of a galvanizing bath are simulated numerically, and their characteristics are analyzed. The relationship of the surface-weighted average velocity at the outlet and the temperature difference between the inlet and the outlet and the effective power for the inductor is studied. Results show that with an increase in effective power for the inductor, the surface-weighted average velocity at the outlet and the temperature difference between the inlet and the outlet increase gradually. We envisage this work to lay a foundation for the study of the performance of the galvanizing bath in future.

Mass balance, meteorological, ice motion, surface altitude, runoff, and ice thickness data at Gulkana Glacier, Alaska, 1995 balance year

USGS Publications Warehouse

March, Rod S.

2000-01-01

The 1995 measured winter snow, maximum winter snow, net, and annual balances in the Gulkana Glacier basin were evaluated on the basis of meteorological, hydrological, and glaciological data obtained in the basin. Averaged over the glacier, the measured winter snow balance was 0.94 meter on April 19, 1995, 0.6 standard deviation below the long-term average; the maximum winter snow balance, 0.94 meter, was reached on April 25, 1995; the net balance (from September 18, 1994 to August 29, 1995) was -0.70 meter, 0.76 standard deviation below the long-term average. The annual balance (October 1, 1994, to September 30, 1995) was -0.86 meter. Ice-surface motion and altitude changes measured at three index sites document seasonal ice speed and glacier-thickness changes. Annual stream runoff was 2.05 meters averaged over the basin, approximately equal to the long-term average. The 1976 ice-thickness data are reported from a single site near the highest measurement site (180 meters thick) and from two glacier cross profiles near the mid-glacier (270 meters thick on centerline) and low glacier (150 meters thick on centerline) measurement sites. A new area-altitude distribution determined from 1993 photogrammetry is reported. Area-averaged balances are reported from both the 1967 and 1993 area-altitude distribution so the reader may directly see the effect of the update. Briefly, loss of ablation area between 1967 and 1993 results in a larger weighting being applied to data from the upper glacier site and hence, increases calculated area-averaged balances. The balance increase is of the order of 15 percent for net balance.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yadav, Praveen Kumar, E-mail: praveenyadav@rrcat.gov.in; Nayak, Maheswar; Rai, Sanjay Kumar

The authors report the effect of argon ion to molybdenum atom ratio (r) on the microstructure of low energy (70 eV) argon ion assisted electron beam evaporated Mo thin films. Surface roughness, morphology, and crystallinity of Mo films are found to strongly depend on “r.” Increase of “r” from 0 to 100 induces gradual loss in crystallinity, reduction in surface roughness and systematic increase in density of the film. For “r” ∼ 100, average atomic density of the film approaches the bulk value (97%) with lowest surface roughness. Further, increasing “r” up to 170 reduces the atomic density, increases roughness, and increase inmore » crystallinity induced by low energy Ar ion beam. The observed surface roughness and grain size determined by x-ray reflectivity and glancing incidence x-ray diffraction correlate well with atomic force microscopy measurements. This study demonstrates that for r = 100 one gets lowest roughness Mo film with highest density and nearly amorphous microstructure. The growth model is discussed by structural zone model.« less

Measuring skew in average surface roughness as a function of surface preparation

NASA Astrophysics Data System (ADS)

Stahl, Mark T.

2015-08-01

Characterizing surface roughness is important for predicting optical performance. Better measurement of surface roughness reduces polishing time, saves money and allows the science requirements to be better defined. This study characterized statistics of average surface roughness as a function of polishing time. Average surface roughness was measured at 81 locations using a Zygo® white light interferometer at regular intervals during the polishing process. Each data set was fit to a normal and Largest Extreme Value (LEV) distribution; then tested for goodness of fit. We show that the skew in the average data changes as a function of polishing time.

Impact of anthropogenic aerosols from global, East Asian, and non-East Asian sources on East Asian summer monsoon system

NASA Astrophysics Data System (ADS)

Wang, Qiuyan; Wang, Zhili; Zhang, Hua

2017-01-01

The impact of the total effects due to anthropogenic aerosols from global, East Asian, and non-East Asian sources on East Asian summer monsoon (EASM) system is studied using an aerosol-climate online model BCC_AGCM2.0.1_CUACE/Aero. The results show that the summer mean net all-sky shortwave fluxes averaged over East Asian monsoon region (EAMR) at the top of the atmosphere (TOA) and surface reduce by 4.8 and 5.0 W m- 2, respectively, due to the increases of global aerosol emissions in 2000 relative to 1850. Changes in radiations and their resulting changes in heat and water transport and cloud fraction contribute together to the surface cooling over EAMR in summer. The increases in global anthropogenic aerosols lead to a decrease of 2.1 K in summer mean surface temperature and an increase of 0.4 hPa in summer mean surface pressure averaged over EAMR, respectively. It is shown that the changes in surface temperature and pressure are significantly larger over land than ocean, thus decreasing the contrast of land-sea surface temperature and pressure. This results in the marked anomalies of north and northeast winds over eastern and southern China and the surrounding oceans in summer, thereby weakening the EASM. The summer mean precipitation averaged over the EAMR reduces by 12%. The changes in non-East Asian aerosol emissions play a more important role in inducing the changes of local temperature and pressure, and thus significantly exacerbate the weakness of the EASM circulation due to local aerosol changes. The weakening of circulation due to both is comparable, and even the effect of non-local aerosols is larger in individual regions. The changes of local and non-local aerosols contribute comparably to the reductions in precipitation over oceans, whereas cause opposite changes over eastern China. Our results highlight the importance of aerosol changes outside East Asia in the impact of the changes of anthropogenic aerosols on EASM.

[Adsorption of heavy metals on the surface of birnessite relationship with its Mn average oxidation state and adsorption sites].

PubMed

Wang, Yan; Tan, Wen-Feng; Feng, Xiong-Han; Qiu, Guo-Hong; Liu, Fan

2011-10-01

Adsorption characteristics of mineral surface for heavy metal ions are largely determined by the type and amount of surface adsorption sites. However, the effects of substructure variance in manganese oxide on the adsorption sites and adsorption characteristics remain unclear. Adsorption experiments and powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) were combined to examine the adsorption characteristics of Pb2+, Cu2+, Zn2+ and Cd2+ sequestration by birnessites with different Mn average oxidation state (AOS), and the Mn AOS dependent adsorption sites and adsorption characteristics. The results show that the maximum adsorption capacity of Pb2+, Cu2+, Zn2+ and Cd2+ increased with increasing birnessite Mn AOS. The adsorption capacity followed the order of Pb2+ > Cu2+ > Zn2+ > Cd2+. The observations suggest that there exist two sites on the surface of birnessite, i. e., high-binding-energy site (HBE site) and low-binding-energy site (LBE site). With the increase of Mn AOS for birnessites, the amount of HBE sites for heavy metal ions adsorption remarkably increased. On the other hand, variation in the amount of LBE sites was insignificant. The amount of LBE sites is much more than those of HBE sites on the surface of birnessite with low Mn AOS. Nevertheless, both amounts on the surface of birnessite with high Mn AOS are very close to each other. Therefore, the heavy metal ions adsorption capacity on birnessite is largely determined by the amount of HBE sites. On birnessite surface, adsorption of Cu2+, Zn2+, and Cd2+ mostly occurred at HBE sites. In comparison with Zn2+ and Cd2+, more Cu2+ adsorbed on the LBW sites. Pb2+ adsorption maybe occupy at both LBE sites and HBE sites simultaneously.

Surface topography, nano-mechanics and secondary structure of wheat gluten pretreated by alternate dual-frequency ultrasound and the correlation to enzymolysis.

PubMed

Zhang, Yanyan; Wang, Bei; Zhou, Cunshan; Atungulu, Griffiths G; Xu, Kangkang; Ma, Haile; Ye, Xiaofei; Abdualrahman, Mohammed A Y

2016-07-01

The effects of alternate dual-frequency ultrasound (ADFU) pretreatment on the degree of hydrolysis (DH) of wheat gluten (WG) and angiotensin I-converting enzyme (ACE) inhibitory activity were investigated in this research. The surface topography, nano-mechanics and secondary structure of WG were also determined using atomic force microscope (AFM) and circular dichroism (CD). The correlations of ACE inhibitory activity and DH with surface topography, nano-mechanics and secondary structure of WG were determined using Pearson's correlation analysis. The results showed that with an increase in either pretreatment duration or power, the ACE inhibitory activity of the hydrolysate also increases, reaching maximum at 10 min and 150 W/L, respectively, and then decreases thereafter. Similarly, AFM analysis showed that as the pretreatment duration or power increases, the surface roughness also increase and again a decrease occurs thereafter. As the pretreatment duration or power increased, the Young's modulus and adhesion of WG also increased and then declined. Young's modulus and adhesions average values were compared with ACE inhibitory activity reversely. The result of the CD spectra analysis exhibited losses in the relative percentage of α-helix of WG. Pearson's correlation analysis showed that the average values of Young's modulus and the relative percentage of α-helix correlated with ACE inhibitory activity of the hydrolysates linearly and significantly (P<0.05); the relative percentage of β-sheet correlated linearly with DH of WG significantly (P<0.05). In conclusion, ADFU pretreatment is an efficient method in proteolysis due to its physical and chemical effect on the Young's modulus, α-helix and β-sheet of WG. Copyright © 2015 Elsevier B.V. All rights reserved.

Surface roughness effects in elastohydrodynamic contacts

NASA Technical Reports Server (NTRS)

Tripp, J. H.; Hamrock, B. J.

1985-01-01

Surface roughness effects in full-film EHL contacts were studied. A flow factor modification to the Reynolds equation was applied to piezoviscous-elastic line contacts. Results for ensemble-averaged film shape, pressure distribution, and other mechanical quantities were obtained. Asperities elongated in the flow direction by a factor exceeding two decreased both film shape and pressure extrema at constant load; isotropic or transverse asperities increased these extrema. The largest effects are displayed by traction, which increased by over 5% for isotropic or transverse asperities and by slightly less for longitudinal roughness.

Multi-Decadal Aerosol Variations from 1980 to 2009: A Perspective from Observations and a Global Model

NASA Technical Reports Server (NTRS)

Chin, Mian; Diehl, T.; Tan, Q.; Prospero, J. M.; Kahn, R. A.; Remer, L. A.; Yu, H.; Sayer, A. M.; Bian, H.; Geogdzhayev, I. V.;

Infrared thermal imaging as a method to evaluate heat loss in newborn lambs.

PubMed

Labeur, L; Villiers, G; Small, A H; Hinch, G N; Schmoelzl, S

2017-12-01

Thermal imaging technology has been identified as a potential method for non-invasive study of thermogenesis in the neonatal lamb. In comparison to measurement of the core body temperature, infrared thermography may observe thermal loss and thermogenesis linked to subcutaneous brown fat depots. This study aimed to identify a suitable method to measure heat loss in the neonatal lamb under a cold challenge. During late pregnancy (day 125), ewes were subjected to either shearing (n=15) or mock handling (sham-shorn for 2min mimicking the shearing movements) (n=15). Previous studies have shown an increase in brown adipose tissue deposition in lambs born to ewes shorn during pregnancy and we hypothesized that the shearing treatment would impact thermoregulatory capacities in newborn lambs. Lambs born to control ewes (n=14; CONTROL) and shorn ewes (n=13; SHORN) were subjected to a cold challenge of 1h duration at 4h after birth. During the cold challenge, thermography images were taken every 10min, from above, at a fixed distance from the dorsal midline. On each image, four fixed-size areas were identified (shoulder, mid loin, hips and rump) and the average and maximum temperatures of each recorded. In all lambs, body surface temperature decreased over time. Overall the SHORN lambs appeared to maintain body surface temperature better than CONTROL lambs, while CONTROL lambs appeared to have higher core temperature. At 30min post cold challenge SHORN lambs tended to have higher body surface temperatures than lambs (P=0.0474). Both average and maximum temperatures were highest at the hips. Average temperature was lowest at the shoulder (P<0.05), while maximum temperatures were lowest at both shoulder and rump (P<0.005). These results indicate that lambs born to shorn ewes maintained their radiated body surface temperature better than CONTROL lambs. In conjunction with core temperature changes under cold challenge, this insight will allow us to understand whether increased body surface temperature contributes to increased overall heat loss or whether increased body surface temperature is indeed a mechanism contributing to maintenance of core body temperature under cold challenge conditions. This study has confirmed the utility of infrared thermography images to capture and identify different levels of thermoregulatory capacity in newborn lambs. Copyright © 2017 Elsevier Ltd. All rights reserved.

Global Increase in UV Irradiance during the Past 30 Years (1979-2008) Estimated from Satellite Data

NASA Technical Reports Server (NTRS)

Herman, Jay R.

2010-01-01

Zonal average ultraviolet irradiance (flux ultraviolet, F(sub uv)) reaching the Earth's surface has significantly increased since 1979 at all latitudes except the equatorial zone. Changes are estimated in zonal average F(sub uv) caused by ozone and cloud plus aerosol reflectivity using an approach based on Beer's law for monochromatic and action spectrum weighted irradiances. For four different cases, it is shown that Beer's Law leads to a power law form similar to that applied to erythemal action spectrum weighted irradiances. Zonal and annual average increases in F(sub uv) were caused by decreases in ozone amount from 1979 to 1998. After 1998, midlatitude annual average ozone amounts and UV irradiance levels have been approximately constant. In the Southern Hemisphere, zonal and annual average UV increase is partially offset by tropospheric cloud and aerosol transmission decreases (hemispherical dimming), and to a lesser extent in the Northern Hemisphere. Ozone and 340 nm reflectivity changes have been obtained from multiple joined satellite time series from 1978 to 2008. The largest zonal average increases in F(sub uv) have occurred in the Southern Hemisphere. For clear-sky conditions at 50 S, zonal average F(sub uv) changes are estimated (305 nm, 23%; erythemal, 8.5%; 310 nm, 10%; vitamin D production, 12%). These are larger than at 50 N (305 nm, 9%; erythemal, 4%; 310 nm, 4%; vitamin D production, 6%). At the latitude of Buenos Aires, Argentina (34.6 S), the clear-sky Fuv increases are comparable to the increases near Washington, D. C. (38.9 N): 305 nm, 9% and 7%; erythemal, 6% and 4%; and vitamin D production, 7% and 5%, respectively.

Small nanoparticles, surface geometry and contact forces.

PubMed

Takato, Yoichi; Benson, Michael E; Sen, Surajit

2018-03-01

In this molecular dynamics study, we examine the local surface geometric effects of the normal impact force between two approximately spherical nanoparticles that collide in a vacuum. Three types of surface geometries-(i) crystal facets, (ii) sharp edges, and (iii) amorphous surfaces of small nanoparticles with radii R <10 nm-are considered. The impact forces are compared with their macroscopic counterparts described by nonlinear contact forces based on Hertz contact mechanics. In our simulations, edge and amorphous surface contacts with weak surface energy reveal that the average impact forces are in excellent agreement with the Hertz contact force. On the other hand, facet collisions show a linearly increasing force with increasing compression. Our results suggest that the nearly spherical nanoparticles are likely to enable some nonlinear dynamic phenomena, such as breathers and solitary waves observed in granular materials, both originating from the nonlinear contact force.

The average chemical composition of the lunar surface

NASA Technical Reports Server (NTRS)

Turkevich, A. L.

1973-01-01

The available analytical data from twelve locations on the moon are used to estimate the average amounts of the principal chemical elements (O, Na, Mg, Al, Si, Ca, Ti, and Fe) in the mare, the terra, and the average lunar surface regolith. These chemical elements comprise about 99% of the atoms on the lunar surface. The relatively small variability in the amounts of these elements at different mare (or terra) sites, and the evidence from the orbital measurements of Apollo 15 and 16, suggest that the lunar surface is much more homogeneous than the surface of the earth. The average chemical composition of the lunar surface may now be known as well as, if not better than, that of the solid part of the earth's surface.

Impacts of river segmentation strategies on reach-averaged product uncertainties for the upcoming Surface Water and Ocean Topography (SWOT) mission

NASA Astrophysics Data System (ADS)

Frasson, R. P. M.; Wei, R.; Minear, J. T.; Tuozzolo, S.; Domeneghetti, A.; Durand, M. T.

2016-12-01

Averaging is a powerful method to reduce measurement noise associated with remote sensing observation of water surfaces. However, when dealing with river measurements, the choice of which points are averaged may affect the quality of the products. We examine the effectiveness of three fully automated reach definition strategies: In the first, we break up reaches at regular intervals measured along the rivers' centerlines. The second strategy consists of identifying hydraulic controls by searching for inflection points on water surface profiles. The third strategy takes into consideration river planform features, breaking up reaches according to channel sinuosity. We employed the Jet Propulsion Laboratory's (JPL) SWOT hydrology simulator to generate 9 synthetic SWOT observations of the Sacramento River in California, USA and 14 overpasses of the Po River in northern Italy. In order to create the synthetic SWOT data, the simulator requires the true water digital elevation model (DEM), which we constructed from hydraulic models of both rivers, and the terrain DEM, which we built from LiDAR data of both basins. We processed the simulated pixel clouds using the JPL's RiverObs package, which traces the river centerline and estimates water surface height and river width on equally spaced nodes located along the centerline. Subsequently, we applied the three reach definition methodologies to the nodes and to the hydraulic models' outputs to generate simulated reach-averaged observations and the reach-averaged truth respectively. Our results generally indicate that height, width, slope, and discharge errors decrease with increasing reach length, with most of the accuracy gains occurring when reach length increases to up to 15 km for both the narrow (Sacramento) and the wide (Po) rivers. The "smart" methods led to smaller slope, width, and discharge errors for the Sacramento River when compared to arbitrary reaches of similar length whereas, for the for the Po River all methods had comparable performance. Our results suggest that river segmentation strategies that take into consideration the hydraulic characteristics of rivers may lead to more meaningful reach boundaries and to better products especially for narrower and more complex rivers.

Hydrogeology and analysis of ground-water withdrawal from the Catahoula aquifer system in the Natchez area, Adams County, Mississippi

USGS Publications Warehouse

Strom, E.W.; Burt, D.E.; Oakley, W.T.

1995-01-01

The city of Natchez, located in Adams County, Mississippi, relies on ground water for public supply and industrial needs. Most public supply and industrial wells are developed in Catahoula Formation sands of Miocene age. In 1991, an investigation began to describe the hydrogeology, analyze the effects of ground-water withdrawal from currently pumped wells, and project the possible effects of increased ground-water withdrawals on water levels in the Catahoula aquifer system within the Natchez area. The study area covers about 80 square miles in Adams County, southwestern Mississippi. The study area contains several aquifers; however, the most important aquifers in terms of water supply are the Mississippi River alluvial aquifer and the Catahoula aquifer system. In the Natchez area, the Catahoula aquifer system consists of three main sand intervals that form the upper, middle, and lower Catahoula aquifers. Ground-water withdrawal from the Catahoula aquifer system in the study area currently (March 1995) is from 24 wells screened in the three aquifers. The current daily rate of withdrawal is about 9.2 million gallons of water per day. Analysis of the effect of ground-water withdrawal from these wells was made using the Theis nonequilibrium equation and applying the principle of superposition. The calculated drawdown surfaces under current conditions indicate cones of depression surrounding the principal wells. In the upper Catahoula sand, most of the drawdown is concentrated about 1 mile east of the downtown Natchez area, where a maximum drawdown of 95x11 feet was calculated. Most of the drawdown in the middle Catahoula sand occurred in the same general vicinity as in the upper sand, with a maximum calculated drawdown of about 113 feet. Drawdown in the lower Catahoula sand was concentrated about 4x11 miles northeast of downtown Natchez, with a maximum calculated drawdown of about 31 feet. Drawdown-surface maps were made using calculations based on current pumping rates for 10 years and 20 years beyond March 1995. Planned changes in the pumping configuration were incorporated into these analyses. The drawdown surface calculated for 10 years beyond March 1995 indicates an average total increase in drawdown of about 7.3 feet for the upper Catahoula sand, with a maximum increase of about 28 feet. An average total increase in drawdown of only 1.2 feet was calculated for the middle Catahoula sand due to the planned discontinued pumping of many of the wells. An average total increase in drawdown of about 19 feet was calculated for the lower Catahoula sand, with a maximum increase of about 41 feet. The drawdown surface calculated for 20 years beyond March 1995 indicates an average total additional increase in drawdown over the 10 year drawdown surface of about 1.9, 0.6, and 2.7 feet for the upper, middle, and lower Catahoula sands, respectively.

Distribution of Mercury Concentrations in Tree Rings and Surface Soils Adjacent to a Phosphate Fertilizer Plant in Southern Korea.

PubMed

Jung, Raae; Ahn, Young Sang

2017-08-01

This study aimed to determine mercury concentrations in tree rings and surface soils at distances of 4, 26 and 40 km from a fertilizer plant located in Yeosu City, Korea. Mercury concentrations in all tree rings were low prior to the establishment of the plant in 1977 and became elevated thereafter. The highest average mercury concentration in the tree rings was 11.96 ng g -1 at the Yeosu site located nearest to the plant, with the lowest average mercury concentration of 4.45 ng g -1 at the Suncheon site furthest away from the plant. In addition, the highest mercury content in the surface soil was 108.51 ng cm -3 at the Yeosu site, whereas the lowest mercury content in the surface soil was 31.47 ng cm -3 at the Suncheon site. The mercury levels decreased gradually with increasing distance from the plant.

Increased cortical curvature reflects white matter atrophy in individual patients with early multiple sclerosis

PubMed Central

Deppe, Michael; Marinell, Jasmin; Krämer, Julia; Duning, Thomas; Ruck, Tobias; Simon, Ole J.; Zipp, Frauke; Wiendl, Heinz; Meuth, Sven G.

2014-01-01

Objective White matter atrophy occurs independently of lesions in multiple sclerosis. In contrast to lesion detection, the quantitative assessment of white matter atrophy in individual patients has been regarded as a major challenge. We therefore tested the hypothesis that white matter atrophy (WMA) is present at the very beginning of multiple sclerosis (MS) and in virtually each individual patient. To find a new sensitive and robust marker for WMA we investigated the relationship between cortical surface area, white matter volume (WMV), and whole-brain-surface-averaged rectified cortical extrinsic curvature. Based on geometrical considerations we hypothesized that cortical curvature increases if WMV decreases and the cortical surface area remains constant. Methods In total, 95 participants were enrolled: 30 patients with early and advanced relapsing–remitting MS; 30 age-matched control subjects; 30 patients with Alzheimer's disease (AD) and 5 patients with clinically isolated syndrome (CIS). Results 29/30 MS and 5/5 CIS patients showed lower WMV than expected from their intracranial volume (average reduction 13.0%, P < 10− 10), while the cortical surface area showed no significant differences compared with controls. The estimated WMV reductions were correlated with an increase in cortical curvature (R = 0.62, P = 0.000001). Discriminant analysis revealed that the curvature increase was highly specific for the MS and CIS groups (96.7% correct assignments between MS and control groups) and was significantly correlated with reduction of white matter fractional anisotropy, as determined by diffusion tensor imaging and the Expanded Disability Status Scale. As expected by the predominant gray and WM degeneration in AD, no systematic curvature increase was observed in AD. Conclusion Whole-brain-averaged cortical extrinsic curvature appears to be a specific and quantitative marker for a WMV–cortex disproportionality and allows us to assess “pure” WMA without being confounded by intracranial volume. WMA seems to be a characteristic symptom in early MS and can already occur in patients with CIS and should thus be considered in future MS research and clinical studies. PMID:25610761

Impacts of Aerosols on Seasonal Precipitation and Snowpack in California Based on Convection-Permitting WRF-Chem Simulations

NASA Astrophysics Data System (ADS)

Gu, Y.; Wu, L.; Jiang, J. H.; Su, H.; Yu, N.; Zhao, C.; Qian, Y.; Zhao, B.; Liou, K. N.; Choi, Y. S.

2017-12-01

A version of the WRF-Chem model with fully coupled aerosol-meteorology-snowpack is employed to investigate the impacts of various aerosol sources on precipitation and snowpack in California. In particular, the impacts of locally emitted anthropogenic and dust aerosols, and aerosols transported from outside of California are studied. We differentiate three pathways of aerosol effects including aerosol-radiation interaction (ARI), aerosol-snow interaction (ASI), and aerosol-cloud interaction (ACI). The convection-permitting model simulations show that precipitation, snow water equivalent (SWE), and surface air temperature averaged over the whole domain (34-42°N, 117-124°W, not including ocean points) are reduced when aerosols are included, therefore reducing the high model biases of these variables when aerosol effects are not considered. Aerosols affect California water resources through the warming of mountain tops and anomalously low precipitation, however, different aerosol sources play different roles in changing surface temperature, precipitation and snowpack in California by means of various weights of the three pathways. ARI by all aerosols mainly cools the surface, leading to slightly increased SWE over the mountains. Locally emitted dust aerosols warm the surface of mountain tops through ASI, in which the reduced snow albedo associated with dirty snow leads to more surface absorption of solar radiation and reduced SWE. Transported and local anthropogenic aerosols play a dominant role in increasing cloud water amount but reducing precipitation through ACI, leading to reduced SWE and runoff over the Sierra Nevada, as well as the warming of mountain tops associated with decreased SWE and hence lower surface albedo. The average changes in surface temperature from October to June are about -0.19 K and 0.22 K for the whole domain and over mountain tops, respectively. Overall, the averaged reduction during October to June is about 7% for precipitation, 3% for SWE, and 7% for surface runoff for the whole domain, while the corresponding numbers are 12%, 10%, and 10% for mountain tops. The reduction in SWE is more significant in a dry year, with 9% for the whole domain and 16% for mountain tops.

Averaged head phantoms from magnetic resonance images of Korean children and young adults

NASA Astrophysics Data System (ADS)

Han, Miran; Lee, Ae-Kyoung; Choi, Hyung-Do; Jung, Yong Wook; Park, Jin Seo

2018-02-01

Increased use of mobile phones raises concerns about the health risks of electromagnetic radiation. Phantom heads are routinely used for radiofrequency dosimetry simulations, and the purpose of this study was to construct averaged phantom heads for children and young adults. Using magnetic resonance images (MRI), sectioned cadaver images, and a hybrid approach, we initially built template phantoms representing 6-, 9-, 12-, 15-year-old children and young adults. Our subsequent approach revised the template phantoms using 29 averaged items that were identified by averaging the MRI data from 500 children and young adults. In females, the brain size and cranium thickness peaked in the early teens and then decreased. This is contrary to what was observed in males, where brain size and cranium thicknesses either plateaued or grew continuously. The overall shape of brains was spherical in children and became ellipsoidal by adulthood. In this study, we devised a method to build averaged phantom heads by constructing surface and voxel models. The surface model could be used for phantom manipulation, whereas the voxel model could be used for compliance test of specific absorption rate (SAR) for users of mobile phones or other electronic devices.

Surface rupture and slip distribution of the Denali and Totschunda faults in the 3 November 2002 M 7.9 earthquake, Alaska

USGS Publications Warehouse

Haeussler, Peter J.; Schwartz, David P.; Dawson, Timothy E.; Stenner, Heidi D.; Lienkaemper, James J.; Sherrod, Brian; Cinti, Francesca R.; Montone, Paola; Craw, Patricia; Crone, Anthony J.; Personius, Stephen F.

2004-01-01

The 3 November 2002 Denali fault, Alaska, earthquake resulted in 341 km of surface rupture on the Susitna Glacier, Denali, and Totschunda faults. The rupture proceeded from west to east and began with a 48-km-long break on the previously unknown Susitna Glacier thrust fault. Slip on this thrust averaged about 4 m (Crone et al., 2004). Next came the principal surface break, along 226 km of the Denali fault, with average right-lateral offsets of 4.5–5.1 m and a maximum offset of 8.8 m near its eastern end. The Denali fault trace is commonly left stepping and north side up. About 99 km of the fault ruptured through glacier ice, where the trace orientation was commonly influenced by local ice fabric. Finally, slip transferred southeastward onto the Totschunda fault and continued for another 66 km where dextral offsets average 1.6–1.8 m. The transition from the Denali fault to the Totschunda fault occurs over a complex 25-km-long transfer zone of right-slip and normal fault traces. Three methods of calculating average surface slip all yield a moment magnitude of Mw 7.8, in very good agreement with the seismologically determined magnitude of M 7.9. A comparison of strong-motion inversions for moment release with our slip distribution shows they have a similar pattern. The locations of the two largest pulses of moment release correlate with the locations of increasing steps in the average values of observed slip. This suggests that slip-distribution data can be used to infer moment release along other active fault traces.

Synthesis, characterization and properties of L-arginine-passivated silver nanocolloids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sunatkari, A. L., E-mail: ashok.sunatkari@rediffmail.com; Talwatkar, S. S.; Tamgadge, Y. S.

2016-05-06

We investigate the effect of L-arginine-surface passivation on localised surface plasmon resonance (LSPR), size and stability of colloidal Silver Nanoparticles (AgNPs) synthesized by chemical reduction method. The surface Plasmon resonance absorption peak of AgNPs shows blue shift with the increase in L-arginine concentration. Transmission electron microscopy (TEM) analysis confirmed that the average size of AgNPs reduces from 10 nm to 6 nm as the concentration of L-Arginine increased from 1 to 5 mM. The X-ray diffraction study (XRD) confirmed the formation face-centred cubic (fcc) structured AgNPs. FT-IR studies revealed strong bonding between L-arginine functional groups and AgNPs.

On Averaging Timescales for the Surface Energy Budget Closure Problem

NASA Astrophysics Data System (ADS)

Grachev, A. A.; Fairall, C. W.; Persson, O. P. G.; Uttal, T.; Blomquist, B.; McCaffrey, K.

2017-12-01

An accurate determination of the surface energy budget (SEB) and all SEB components at the air-surface interface is of obvious relevance for the numerical modelling of the coupled atmosphere-land/ocean/snow system over different spatial and temporal scales, including climate modelling, weather forecasting, environmental impact studies, and many other applications. This study analyzes and discusses comprehensive measurements of the SEB and the surface energy fluxes (turbulent, radiative, and ground heat) made over different underlying surfaces based on the data collected during several field campaigns. Hourly-averaged, multiyear data sets collected at two terrestrial long-term research observatories located near the coast of the Arctic Ocean at Eureka (Canadian Archipelago) and Tiksi (East Siberia) and half-hourly averaged fluxes collected during a year-long field campaign (Wind Forecast Improvement Project 2, WFIP 2) at the Columbia River Gorge (Oregon) in areas of complex terrain. Our direct measurements of energy balance show that the sum of the turbulent sensible and latent heat fluxes systematically underestimate the available energy at half-hourly and hourly time scales by around 20-30% at these sites. This imbalance of the surface energy budget is comparable to other terrestrial sites. Surface energy balance closure is a formulation of the conservation of energy principle (the first law of thermodynamics). The lack of energy balance closure at hourly time scales is a fundamental and pervasive problem in micrometeorology and may be caused by inaccurate estimates of the energy storage terms in soils, air and biomass in the layer below the measurement height and above the heat flux plates. However, the residual energy imbalance is significantly reduced at daily and monthly timescales. Increasing the averaging time to daily scales substantially reduces the storage terms because energy locally entering the soil, air column, and vegetation in the morning is released in the afternoon and evening.

Pattern Analysis of El Nino and La Nina Phenomenon Based on Sea Surface Temperature (SST) and Rainfall Intensity using Oceanic Nino Index (ONI) in West Java Area

NASA Astrophysics Data System (ADS)

Prasetyo, Yudo; Nabilah, Farras

2017-12-01

Climate change occurs in 1998-2016 brings significant alteration in the earth surface. It is affects an extremely anomaly temperature such as El Nino and La Nina or mostly known as ENSO (El Nino Southern Oscillation). West Java is one of the regions in Indonesia that encounters the impact of this phenomenon. Climate change due to ENSO also affects food production and other commodities. In this research, processing data method is conducted using programming language to process SST data and rainfall data from 1998 to 2016. The data are sea surface temperature from NOAA satellite, SST Reynolds (Sea Surface Temperature) and daily rainfall temperature from TRMM satellite. Data examination is done using analysis of rainfall spatial pattern and sea surface temperature (SST) where is affected by El Nino and La Nina phenomenon. This research results distribution map of SST and rainfall for each season to find out the impacts of El Nino and La Nina around West Java. El Nino and La Nina in Java Sea are occurring every August to February. During El Nino, sea surface temperature is between 27°C - 28°C with average temperature on 27.71°C. Rainfall intensity is 1.0 mm/day - 2.0 mm/day and the average are 1.63 mm/day. During La Nina, sea surface temperature is between 29°C - 30°C with average temperature on 29.06°C. Rainfall intensity is 9.0 mm/day - 10 mm/day, and the average is 9.74 mm/day. The correlation between rainfall and SST is 0,413 which is expresses a fairly strong correlation between parameters. The conclusion is, during La Nina SST and rainfall increase. While during El Nino SST and rainfall decrease. Hopefully this research could be a guideline to plan disaster mitigation in West Java region that is related extreme climate change.

Stream denitrification across biomes and its response to anthropogenic nitrate loading

Treesearch

Patrick J Mulholland; Ashely M. Helton; Geoffrey C. Poole; Robert O. Hall; Stephen K. Hamilton; Bruce J. Peterson; Jennifer L. Tank; Linda R. Ashkenas; Lee W. Cooper; Clifford N. Dahm; Walter K. Dodds; Stuart E.G. Findlay; Stanley V. Gregory; Nancy B. Grimm; Sherri L. Johnson; William H. McDowell; Judy L. Meyer; H. Maurice Valett; Jackson R. Webster; Clay P. Arango; Jake J. Beaulieu; Melody J. Bernot; Amy J. Burgin; Chelsea L. Crenshaw; Laura T. Johnson; B.R. Niederlehner; Jonathan M. O' Brien; Jody D. Potter; Richard W. Sheibley; Daniel J. Sobota; Suzanne M. Thomas

2008-01-01

Anthropogenic addition of bioavailable nitrogen to the biosphere is increasing, and terrestrial ecosystems are becoming increasingly nitrogen-saturated, causing more bioavailable nitrogen to enter groundwater and surface waters. Large-scale nitrogen budgets show that an average of about 20 to 25 percent of the nitrogen added to the biosphere is exported from rivers to...

Teachers and Students Knowledge about Global Warming: A Study in Smoke Disaster Area of Indonesia

ERIC Educational Resources Information Center

Rosidin, Undang; Suyatna, Agus

2017-01-01

The average temperature on the Earth's surface has globally increased. This issue was generally caused by the increasing of greenhouse gases concentrations due to human activities. Therefore, the knowledge about global warming becomes major topics for students and educators. This research aimed to investigate how the teachers and students…

The impact of boreal forest fire on climate warming

USGS Publications Warehouse

Randerson, J.T.; Liu, H.; Flanner, M.G.; Chambers, S.D.; Jin, Y.; Hess, P.G.; Pfister, G.; Mack, M.C.; Treseder, K.K.; Welp, L.R.; Chapin, F.S.; Harden, J.W.; Goulden, M.L.; Lyons, E.; Neff, J.C.; Schuur, E.A.G.; Zender, C.S.

2006-01-01

We report measurements and analysis of a boreal forest fire, integrating the effects of greenhouse gases, aerosols, black carbon deposition on snow and sea ice, and postfire changes in surface albedo. The net effect of all agents was to increase radiative forcing during the first year (34 ?? 31 Watts per square meter of burned area), but to decrease radiative forcing when averaged over an 80-year fire cycle (-2.3 ?? 2.2 Watts per square meter) because multidecadal increases in surface albedo had a larger impact than fire-emitted greenhouse gases. This result implies that future increases in boreal fire may not accelerate climate warming.

The impact of boreal forest fire on climate warming.

PubMed

Randerson, J T; Liu, H; Flanner, M G; Chambers, S D; Jin, Y; Hess, P G; Pfister, G; Mack, M C; Treseder, K K; Welp, L R; Chapin, F S; Harden, J W; Goulden, M L; Lyons, E; Neff, J C; Schuur, E A G; Zender, C S

2006-11-17

We report measurements and analysis of a boreal forest fire, integrating the effects of greenhouse gases, aerosols, black carbon deposition on snow and sea ice, and postfire changes in surface albedo. The net effect of all agents was to increase radiative forcing during the first year (34 +/- 31 Watts per square meter of burned area), but to decrease radiative forcing when averaged over an 80-year fire cycle (-2.3 +/- 2.2 Watts per square meter) because multidecadal increases in surface albedo had a larger impact than fire-emitted greenhouse gases. This result implies that future increases in boreal fire may not accelerate climate warming.

European Science Notes Information Bulletin. Report on Current European and Middle Eastern Science

DTIC Science & Technology

1992-10-01

oceanographers. This has occurred at a time of current radar systems . The independent develop- rapidly increasing government interest in and fund...over each area in which surface current is ment of the waves (some motions caused by wave determined (for HF systems , averaging time spans action and...Ocean Observing System ; high-resolution model capabilities; ocean- atmosphere interface; Surface Density Depression Pool; forecasting INTRODUCTION tion

A multiresolution hierarchical classification algorithm for filtering airborne LiDAR data

NASA Astrophysics Data System (ADS)

Chen, Chuanfa; Li, Yanyan; Li, Wei; Dai, Honglei

2013-08-01

We presented a multiresolution hierarchical classification (MHC) algorithm for differentiating ground from non-ground LiDAR point cloud based on point residuals from the interpolated raster surface. MHC includes three levels of hierarchy, with the simultaneous increase of cell resolution and residual threshold from the low to the high level of the hierarchy. At each level, the surface is iteratively interpolated towards the ground using thin plate spline (TPS) until no ground points are classified, and the classified ground points are used to update the surface in the next iteration. 15 groups of benchmark dataset, provided by the International Society for Photogrammetry and Remote Sensing (ISPRS) commission, were used to compare the performance of MHC with those of the 17 other publicized filtering methods. Results indicated that MHC with the average total error and average Cohen’s kappa coefficient of 4.11% and 86.27% performs better than all other filtering methods.

Optimal Extraction of Tropospheric Ozone Column by Simultaneous Use of OMI and TES Data and the Surface Temperature

NASA Astrophysics Data System (ADS)

Mobasheri, M. R.; Shirazi, H.

2015-12-01

This article aims to increase the accuracy of Ozone data from tropospheric column (TOC) of the OMI and TES satellite instruments. To validate the estimated amount of satellite data, Ozonesonde data is used. The vertical resolution in both instruments in the tropospheric atmosphere decreases so that the degree of freedom signals (DOFS) on the average for TES is reduced to 2 and for OMI is reduced to1. But this decline in accuracy in estimation of tropospheric ozone is more obvious in urban areas so that estimated ozone in both instruments alone in non-urban areas show a high correlation with Ozonesonde. But in urban areas this correlation is significantly reduced, due to the ozone pre-structures and consequently an increase on surface-level ozone in urban areas. In order to improve the accuracy of satellite data, the average tropospheric ozone data from the two instruments were used. The aim is to increase the vertical resolution of ozone profile and the results clearly indicate an increase in correlations, but nevertheless the satellite data have a positive bias towards the earth data. To reduce the bias, with the solar flux and nitrogen dioxide values and surface temperatures are calculated as factors of ozone production on the earth's surface and formation of mathematical equations based on coefficients for each of the mentioned values and multiplication of these coefficients by satellite data and repeated comparison with the values of Ozonesonde, the results showed that bias in urban areas is greatly reduced.

Daily mean temperature estimate at the US SUFRAD stations as an average of the maximum and minimum temperatures

DOE PAGES

Chylek, Petr; Augustine, John A.; Klett, James D.; ...

2017-09-30

At thousands of stations worldwide, the mean daily surface air temperature is estimated as a mean of the daily maximum (T max) and minimum (T min) temperatures. In this paper, we use the NOAA Surface Radiation Budget Network (SURFRAD) of seven US stations with surface air temperature recorded each minute to assess the accuracy of the mean daily temperature estimate as an average of the daily maximum and minimum temperatures and to investigate how the accuracy of the estimate increases with an increasing number of daily temperature observations. We find the average difference between the estimate based on an averagemore » of the maximum and minimum temperatures and the average of 1440 1-min daily observations to be - 0.05 ± 1.56 °C, based on analyses of a sample of 238 days of temperature observations. Considering determination of the daily mean temperature based on 3, 4, 6, 12, or 24 daily temperature observations, we find that 2, 4, or 6 daily observations do not reduce significantly the uncertainty of the daily mean temperature. The bias reduction in a statistically significant manner (95% confidence level) occurs only with 12 or 24 daily observations. The daily mean temperature determination based on 24 hourly observations reduces the sample daily temperature uncertainty to - 0.01 ± 0.20 °C. Finally, estimating the parameters of population of all SURFRAD observations, the 95% confidence intervals based on 24 hourly measurements is from - 0.025 to 0.004 °C, compared to a confidence interval from - 0.15 to 0.05 °C based on the mean of T max and T min.« less

Daily mean temperature estimate at the US SUFRAD stations as an average of the maximum and minimum temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chylek, Petr; Augustine, John A.; Klett, James D.

At thousands of stations worldwide, the mean daily surface air temperature is estimated as a mean of the daily maximum (T max) and minimum (T min) temperatures. In this paper, we use the NOAA Surface Radiation Budget Network (SURFRAD) of seven US stations with surface air temperature recorded each minute to assess the accuracy of the mean daily temperature estimate as an average of the daily maximum and minimum temperatures and to investigate how the accuracy of the estimate increases with an increasing number of daily temperature observations. We find the average difference between the estimate based on an averagemore » of the maximum and minimum temperatures and the average of 1440 1-min daily observations to be - 0.05 ± 1.56 °C, based on analyses of a sample of 238 days of temperature observations. Considering determination of the daily mean temperature based on 3, 4, 6, 12, or 24 daily temperature observations, we find that 2, 4, or 6 daily observations do not reduce significantly the uncertainty of the daily mean temperature. The bias reduction in a statistically significant manner (95% confidence level) occurs only with 12 or 24 daily observations. The daily mean temperature determination based on 24 hourly observations reduces the sample daily temperature uncertainty to - 0.01 ± 0.20 °C. Finally, estimating the parameters of population of all SURFRAD observations, the 95% confidence intervals based on 24 hourly measurements is from - 0.025 to 0.004 °C, compared to a confidence interval from - 0.15 to 0.05 °C based on the mean of T max and T min.« less

The effect of concentration ratio and type of functional group on synthesis of CNT-ZnO hybrid nanomaterial by an in situ sol-gel process

NASA Astrophysics Data System (ADS)

Hosseini Largani, Sekineh; Akbarzadeh Pasha, Mohammad

2017-12-01

In this research, MWCNT-ZnO hybrid nanomaterials were synthesized by a simple sol-gel process using Zn(CH3COO)2·2H2O and functionalized MWCNT with carboxyl(COOH) and hydroxyl(OH) groups. Three different mass ratios of MWCNT:ZnO = 3:1, 1:1 and 1:3 were examined. The prepared nanomaterials were characterized by field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX) and Fourier transform infrared spectroscopy (FTIR). Successful growth of MWCNT-ZnO hybrids for both COOH and OH functional groups and all the three mass ratios were obtained. The ZnO nanoparticles attached on the surfaces of CNTs have rather spherical shapes and hexagonal crystal structure. By increasing the concentration of ZnO, the number and average size of ZnO nanoparticles decorated the body of CNTs in hybrid structures increase. By increasing the ZnO precursor, the distribution of ZnO nanoparticles that appeared on the surface of CNTs becomes more uniform. The SEM observation beside EDX analysis revealed that at the same concentration ratio the amount of ZnO loading on the surface of MWCNT-COOH is more than MWCNT-OH. Moreover, the average size of ZnO nanoparticles attached on the surface of COOH functionalized CNTs is relatively smaller than that of OH functionalized ones.

Influence of Sub-Surface Irrigation on Soil Conditions and Water Irrigation Efficiency in a Cherry Orchard in a Hilly Semi-Arid Area of Northern China

PubMed Central

Peng, Gao; Bing, Wang; Guangcan, Zhang

2013-01-01

Sub-surface irrigation (SUI) is a new water-saving irrigation technology. To explore the influence of SUI on soil conditions in a cherry orchard and its water-saving efficiency, experiments were conducted from 2009 to 2010 using both SUI and flood irrigation (FLI) and different SUI quotas in hilly semi-arid area of northern China. The results demonstrated the following: 1) The bulk density of the soil under SUI was 6.8% lower than that of soil under FLI (P<0.01). The total soil porosity, capillary porosity and non-capillary porosity of soils using SUI were 11.7% (P<0.01), 8.7% (P<0.01) and 43.8% (P<0.01) higher than for soils using FLI. 2) The average soil temperatures at 0, 5, 10, 15 and 20 cm of soil depth using SUI were 1.7, 1.1, 0.7, 0.4 and 0.3°C higher than those for FLI, specifically, the differences between the surface soil layers were more significant. 3) Compared with FLI, the average water-saving efficiency of SUI was 55.6%, and SUI increased the irrigation productivity by 7.9-12.3 kg m-3 ha-1. 4) The soil moisture of different soil layers using SUI increased with increases in the irrigation quotas, and the soil moisture contents under SUI were significantly higher in the 0-20 cm layer and in the 21-50 cm layer than those under FLI (P<0.01). 5) The average yields of cherries under SUI with irrigation quotas of 80-320 m3 ha-1 were 8.7%-34.9% higher than those in soil with no irrigation (CK2). The average yields of cherries from soils using SUI were 4.5%-12.2% higher than using FLI. It is appropriate to irrigate 2-3 times with 230 m3 ha-1 per application using SUI in a year with normal rainfall. Our findings indicated that SUI could maintain the physical properties, greatly improve irrigation water use efficiency, and significantly increase fruit yields in hilly semi-arid areas of northern China. PMID:24039986

Study on the surface sulfidization behavior of smithsonite at high temperature

NASA Astrophysics Data System (ADS)

Lv, Jin-fang; Tong, Xiong; Zheng, Yong-xing; Xie, Xian; Wang, Cong-bing

2018-04-01

Surface sulfidization behavior of smithsonite at high temperature was investigated by X-ray powder diffractometer (XRD) along with thermodynamic calculation, X-ray photoelectron spectroscopy (XPS) and electron probe microanalysis (EPMA). The XRD and thermodynamic analyses indicated that the smithsonite was decomposed into zincite at high temperatures. After introducing a small amount of pyrite, artificial sulfides were formed at surface of the obtained zincite. The XPS analyses revealed that the sulfide species including zinc sulfide and zinc disulfide were generated at the zincite surface. The EPMA analyses demonstrated that the film of sulfides was unevenly distributed at the zincite surface. The average concentration of elemental sulfur at the sample surface increased with increasing of pyrite dosage. A suitable mole ratio of FeS2 to ZnCO3 for the surface thermal modification was determined to be about 0.3. These findings can provide theoretical support for improving the process during which the zinc recovery from refractory zinc oxide ores is achieved by xanthate flotation.

Effects of stratospheric ozone recovery on photochemistry and ozone air quality in the troposphere

NASA Astrophysics Data System (ADS)

Zhang, H.; Wu, S.; Huang, Y.; Wang, Y.

2014-04-01

There has been significant stratospheric ozone depletion since the late 1970s due to ozone-depleting substances (ODSs). With the implementation of the Montreal Protocol and its amendments and adjustments, stratospheric ozone is expected to recover towards its pre-1980 level in the coming decades. In this study, we examine the implications of stratospheric ozone recovery for the tropospheric chemistry and ozone air quality with a global chemical transport model (GEOS-Chem). With a full recovery of the stratospheric ozone, the projected increases in ozone column range from 1% over the low latitudes to more than 10% over the polar regions. The sensitivity factor of troposphere ozone photolysis rate, defined as the percentage changes in surface ozone photolysis rate for 1% increase in stratospheric ozone column, shows significant seasonal variation but is always negative with absolute value larger than one. The expected stratospheric ozone recovery is found to affect the tropospheric ozone destruction rates much more than the ozone production rates. Significant decreases in surface ozone photolysis rates due to stratospheric ozone recovery are simulated. The global average tropospheric OH decreases by 1.7%, and the global average lifetime of tropospheric ozone increases by 1.5%. The perturbations to tropospheric ozone and surface ozone show large seasonal and spatial variations. General increases in surface ozone are calculated for each season, with increases by up to 0.8 ppbv in the remote areas. Increases in ozone lifetime by up to 13% are found in the troposphere. The increased lifetimes of tropospheric ozone in response to stratospheric ozone recovery enhance the intercontinental transport of ozone and global pollution, in particular for the summertime. The global background ozone attributable to Asian emissions is calculated to increase by up to 15% or 0.3 ppbv in the Northern Hemisphere in response to the projected stratospheric ozone recovery.

Comparing daily temperature averaging methods: the role of surface and atmosphere variables in determining spatial and seasonal variability

NASA Astrophysics Data System (ADS)

Bernhardt, Jase; Carleton, Andrew M.

2018-05-01

The two main methods for determining the average daily near-surface air temperature, twice-daily averaging (i.e., [Tmax+Tmin]/2) and hourly averaging (i.e., the average of 24 hourly temperature measurements), typically show differences associated with the asymmetry of the daily temperature curve. To quantify the relative influence of several land surface and atmosphere variables on the two temperature averaging methods, we correlate data for 215 weather stations across the Contiguous United States (CONUS) for the period 1981-2010 with the differences between the two temperature-averaging methods. The variables are land use-land cover (LULC) type, soil moisture, snow cover, cloud cover, atmospheric moisture (i.e., specific humidity, dew point temperature), and precipitation. Multiple linear regression models explain the spatial and monthly variations in the difference between the two temperature-averaging methods. We find statistically significant correlations between both the land surface and atmosphere variables studied with the difference between temperature-averaging methods, especially for the extreme (i.e., summer, winter) seasons (adjusted R2 > 0.50). Models considering stations with certain LULC types, particularly forest and developed land, have adjusted R2 values > 0.70, indicating that both surface and atmosphere variables control the daily temperature curve and its asymmetry. This study improves our understanding of the role of surface and near-surface conditions in modifying thermal climates of the CONUS for a wide range of environments, and their likely importance as anthropogenic forcings—notably LULC changes and greenhouse gas emissions—continues.

An experimental study of the flow boiling of refrigerant-based nanofluids

NASA Astrophysics Data System (ADS)

Kolekar, Rahul Dadasaheb

The use of nanofluids for various heat transfer applications has been a topic of intense research over the last decade. A number of studies to evaluate the thermophysical properties and single-phase heat transfer behavior of nanofluids have been reported. The current study is focused on the use of nanofluids in flow boiling applications, with CO2 and R134a used as the base refrigerants. CuO nanoparticles 40nm in size, and TiO2 nanoparticles 200nm in size are used to create partially stable CO2-based nanofluids. Stable nanofluids are created in R134a by mixing it with dispersions of surface-treated nanoparticles in polyolester (POE) oil (RL22H and RL68H). The particles (Al 2O3, ZnO, CuO, and ATO) at particle mass fractions from 0.08% to 1.34%, with particle sizes of 20nm and 40nm are coated with polar and non-polar surface treatments. The thermal properties of R134a-based nanofluids are measured. Thermal conductivity shows limited improvements; the largest increase of 13% is observed with CuO nanoparticles. Significant increases in viscosity, as high as 2147%, are observed due to CuO nanoparticles. Only the ATO nanofluid exhibited a decrease in the measured viscosity. Heat transfer coefficients during flow boiling of nanofluids are measured over a range of mass flux from 100 to 1000 kg/m2s, with a heat flux from 5 to 25kW/m2, and vapor quality up to 1. The test section is a smooth copper tube, 6.23mm in diameter and 1.8m in length. Average decreases of 5% and 28% are observed in heat transfer coefficients during flow boiling of CuO/CO2 and TiO2/CO2 nanofluids, respectively. For the R134a-based nanofluids, average decreases in heat transfer during flow boiling at the highest particle mass fraction are 15% and 22% for Al2O3 and ZnO nanoparticles, respectively. CuO nanoparticles exhibit an average decrease of 7% for particle mass fraction of 0.08%. An average increase of 10% is observed with ATO nanoparticles at a 0.22% mass fraction. Heat transfer performance deteriorates with increase in viscosity and particle number density. The performance is also worse for partially stable nanofluids that modify the test section surface. Modifications to the thermophysical properties is the primary mechanism that affects heat transfer performance during flow boiling of nanofluids; increased thermal conductivity enhances while increased viscosity and surface tension reduce heat transfer in nucleate boiling-dominated flows. A secondary mechanism of nanoparticles filling up the micro-cavities on test surface is also responsible for decreased heat transfer and is a strong function of particle number density.

Surface modification of Monel K-500 as a means of reducing friction and wear in high-pressure oxygen

NASA Technical Reports Server (NTRS)

Gunaji, Mohan; Stoltzfus, Joel M.; Schoenman, Leonard; Kazaroff, John

1989-01-01

A study is conducted of the tribological characteristics of Monel K-500 during rubbing in a high pressure oxygen atmosphere, upon surface treatment by ion-implanted oxygen, chromium, lead, and silver, as well as electrolyzed chromium and an electroless nickel/SiC composite. The electrolyzed chromium dramatically increased total sample wear, while other surface treatments affected sample wear only moderately. Although the ion-implant treatments reduced the average coefficient of friction at low contact pressure, higher contact pressures eliminated this improvement.

Impact of elevated temperatures on specific leaf weight, stomatal density, photosynthesis and chlorophyll fluorescence in soybean.

PubMed

Jumrani, Kanchan; Bhatia, Virender Singh; Pandey, Govind Prakash

2017-03-01

High-temperature stress is a major environmental stress and there are limited studies elucidating its impact on soybean (Glycine max L. Merril.). The objectives of present study were to quantify the effect of high temperature on changes in leaf thickness, number of stomata on adaxial and abaxial leaf surfaces, gas exchange, chlorophyll fluorescence parameters and seed yield in soybean. Twelve soybean genotypes were grown at day/night temperatures of 30/22, 34/24, 38/26 and 42/28 °C with an average temperature of 26, 29, 32 and 35 °C, respectively, under greenhouse conditions. One set was also grown under ambient temperature conditions where crop season average maximum, minimum and mean temperatures were 28.0, 22.4 and 25.2 °C, respectively. Significant negative effect of temperature was observed on specific leaf weight (SLW) and leaf thickness. Rate of photosynthesis, stomatal conductance and water use efficiency declined as the growing temperatures increased; whereas, intercellular CO 2 and transpiration rate were increased. With the increase in temperature chlorophyll fluorescence parameters such as Fv/Fm, qP and PhiPSII declined while there was increase in qN. Number of stomata on both abaxial and adaxial surface of leaf increased significantly with increase in temperatures. The rate of photosynthesis, PhiPSII, qP and SPAD values were positively associated with leaf thickness and SLW. This indicated that reduction in photosynthesis and associated parameters appears to be due to structural changes observed at higher temperatures. The average seed yield was maximum (13.2 g/pl) in plants grown under ambient temperature condition and declined by 8, 14, 51 and 65% as the temperature was increased to 30/22, 34/24, 38/26 and 42/28 °C, respectively.

Impact of Tropospheric Ozone on Summer Climate in China

NASA Astrophysics Data System (ADS)

Li, Shu; Wang, Tijian; Zanis, Prodromos; Melas, Dimitris; Zhuang, Bingliang

2018-04-01

The spatial distribution, radiative forcing, and climatic effects of tropospheric ozone in China during summer were investigated by using the regional climate model RegCM4. The results revealed that the tropospheric ozone column concentration was high in East China, Central China, North China, and the Sichuan basin during summer. The increase in tropospheric ozone levels since the industrialization era produced clear-sky shortwave and clear-sky longwave radiative forcing of 0.18 and 0.71 W m-2, respectively, which increased the average surface air temperature by 0.06 K and the average precipitation by 0.22 mm day-1 over eastern China during summer. In addition, tropospheric ozone increased the land-sea thermal contrast, leading to an enhancement of East Asian summer monsoon circulation over southern China and a weakening over northern China. The notable increase in surface air temperature in northwestern China, East China, and North China could be attributed to the absorption of longwave radiation by ozone, negative cloud amount anomaly, and corresponding positive shortwave radiation anomaly. There was a substantial increase in precipitation in the middle and lower reaches of the Yangtze River. It was related to the enhanced upward motion and the increased water vapor brought by strengthened southerly winds in the lower troposphere.

Impact of the ongoing Amazonian deforestation on local precipitation: A GCM simulation study

NASA Technical Reports Server (NTRS)

Walker, G. K.; Sud, Y. C.; Atlas, R.

1995-01-01

Numerical simulation experiments were conducted to delineate the influence of in situ deforestation data on episodic rainfall by comparing two ensembles of five 5-day integrations performed with a recent version of the Goddard Laboratory for Atmospheres General Circulation Model (GCM) that has a simple biosphere model (SiB). The first set, called control cases, used the standard SiB vegetation cover (comprising 12 biomes) and assumed a fully forested Amazonia, while the second set, called deforestation cases, distinguished the partially deforested regions of Amazonia as savanna. Except for this difference, all other initial and prescribed boundary conditions were kept identical in both sets of integrations. The differential analyses of these five cases show the following local effects of deforestation. (1) A discernible decrease in evapotranspiration of about 0.80 mm/d (roughly 18%) that is quite robust in the averages for 1-, 2-, and 5-day forecasts. (2) A decrease in precipitation of about 1.18 mm/d (roughly 8%) that begins to emerge even in 1-2 day averages and exhibits complex evolution that extends downstream with the winds. (3) A significant decrease in the surface drag force (as a consequence of reduced surface roughness of deforested regions) that, in turn, affects the dynamical structure of moisture convergence and circulation. The surface winds increase significantly during the first day, and thereafter the increase is well maintained even in the 2- and 5-day averages.

Natural and unnatural oil slicks in the Gulf of Mexico

PubMed Central

Garcia‐Pineda, O.; Beet, A.; Daneshgar Asl, S.; Feng, L.; Graettinger, G.; French‐McCay, D.; Holmes, J.; Hu, C.; Huffer, F.; Leifer, I.; Muller‐Karger, F.; Solow, A.; Silva, M.; Swayze, G.

2015-01-01

Abstract When wind speeds are 2–10 m s−1, reflective contrasts in the ocean surface make oil slicks visible to synthetic aperture radar (SAR) under all sky conditions. Neural network analysis of satellite SAR images quantified the magnitude and distribution of surface oil in the Gulf of Mexico from persistent, natural seeps and from the Deepwater Horizon (DWH) discharge. This analysis identified 914 natural oil seep zones across the entire Gulf of Mexico in pre‐2010 data. Their ∼0.1 µm slicks covered an aggregated average of 775 km2. Assuming an average volume of 77.5 m3 over an 8–24 h lifespan per oil slick, the floating oil indicates a surface flux of 2.5–9.4 × 104 m3 yr−1. Oil from natural slicks was regionally concentrated: 68%, 25%, 7%, and <1% of the total was observed in the NW, SW, NE, and SE Gulf, respectively. This reflects differences in basin history and hydrocarbon generation. SAR images from 2010 showed that the 87 day DWH discharge produced a surface‐oil footprint fundamentally different from background seepage, with an average ocean area of 11,200 km2 (SD 5028) and a volume of 22,600 m3 (SD 5411). Peak magnitudes of oil were detected during equivalent, ∼14 day intervals around 23 May and 18 June, when wind speeds remained <5 m s−1. Over this interval, aggregated volume of floating oil decreased by 21%; area covered increased by 49% (p < 0.1), potentially altering its ecological impact. The most likely causes were increased applications of dispersant and surface burning operations. PMID:27774370

Modeled effect of warming on ecosystem carbon and water dynamics within grassland/old-field ecosystems along a moisture gradient

USDA-ARS?s Scientific Manuscript database

As a consequence of steadily increasing concentrations of greenhouse gases in Earth’s atmosphere, average world-wide surface temperature is expected to increase 1.5-6.4°C by the end of the 21st Century. Results from manipulative field experiments and ecosystem modeling indicate that plants and soil...

Climatological Data For Clouds Over the Globe From Surface Observations, 1982-1991: The Total Cloud Edition (1994) (NDP-026a)

DOE Data Explorer

Hahn, Carole J. [Univ. of Colorado, Boulder, CO (United States). Cooperative Inst. for Research in Environmental Sciences (CIRES); Warren, Stephen G. [Department of Atmospheric Sciences, University of Colorado, Boulder, CO; London, Julius [Department of Astrophysical, Planetary, and Atmospheric Sciences, University of Colorado, Boulder, CO

1994-01-01

Routine, synoptic surface weather reports from ships and land stations over the entire globe, for the10-year period December 1981 through November 1991, were processed for total cloud cover and the frequencies of occurrence of clear sky, sky-obscured due to precipitation, and sky-obscured due to fog. Archived data, consisting of various annual, seasonal and monthly averages, are provided in grid boxes that are typically 2.5° × 2.5° for land and 5° × 5° for ocean. Day and nighttime averages are also given separately for each season. Several derived quantities, such as interannual variations and annual and diurnal harmonics, are provided as well. This data set incorporates an improved representation of nighttime cloudiness by utilizing only those nighttime observations for which the illuminance due to moonlight exceeds a specified threshold. This reduction in the night-detection bias increases the computed global average total cloud cover by about 2%. The impact on computed diurnal cycles is even greater, particularly over the oceans where it is found (in contrast to previous surface-based climatologies), that cloudiness is often greater at night than during the day.

Experimental investigation of time and repeated cycles in nucleate pool boiling of alumina/water nanofluid on polished and machined surfaces

NASA Astrophysics Data System (ADS)

Rajabzadeh Dareh, F.; Haghshenasfard, M.; Nasr Esfahany, M.; Salimi Jazi, H.

2018-06-01

Pool boiling heat transfer of pure water and nanofluids on a copper block has been studied experimentally. Nanofluids with various concentrations of 0.0025, 0.005 and 0.01 vol.% are employed and two simple surfaces (polished and machined copper surface) are used as the heating surfaces. The results indicated that the critical heat flux (CHF) in boiling of fluids on the polished surface is 7% higher than CHF on the machined surface. In the case of machined surface, the heat transfer coefficient (HTC) of 0.01 vol.% nanofluid is about 37% higher than HTC of base fluid, while in the polished surface the average HTC of 0.01% nanofluid is about 19% lower than HTC of the pure water. The results also showed that the boiling time and boiling cycles on the polished surface changes the heat transfer performance. By increasing the boiling time from 5 to 10 min, the roughness enhances about 150%, but by increasing the boiling time to 15 min, the roughness enhancement is only 8%.

Effect of metal surface topography on mechanical bonding at simulated total hip stem-cement interfaces.

PubMed

Chen, C Q; Scott, W; Barker, T M

1999-01-01

Bonding and loosening mechanisms between bone cement and joint prostheses have not been well identified. In this study, the effects of simulated hip stem surface topography on the interfacial shear strength were examined. Six different surface topographies were used. They were described by several surface characterization parameters that may directly relate to the interfacial bonding strength: average surface roughness R(a), root mean square slope R(Deltaq), correlation length beta, and fluid retention index R(ri). The shear strengths between Palacos E bone cement and stainless steel rods were measured using an Instron materials testing machine. We found that cement can "flow" into the surface microtopography and establish good contact with the metal surface. The results show that the interfacial strength increases monotonically with the increase of R(Deltaq) instead of with R(a). The relationship between interfacial strength and surface parameters shows that a metal stem with an isotropic surface texture, higher R(Deltaq), and greater R(ri) gives a higher interfacial strength. Copyright 1999 John Wiley & Sons, Inc.

Influence of Idealized Heterogeneity on Wet and Dry Planetary Boundary Layers Coupled to the Land Surface. 2; Phase-Averages

NASA Technical Reports Server (NTRS)

Houser, Paul (Technical Monitor); Patton, Edward G.; Sullivan, Peter P.; Moeng, Chin-Hoh

2003-01-01

We examine the influence of surface heterogeneity on boundary layers using a large-eddy simulation coupled to a land-surface model. Heterogeneity, imposed in strips varying from 2-30 km (1 less than lambda/z(sub i) less than 18), is found to dramatically alter the structure of the free convective boundary layer by inducing significant organized circulations. A conditional sampling technique, based on the scale of the surface heterogeneity (phase averaging), is used to identify and quantify the organized surface fluxes and motions in the atmospheric boundary layer. The impact of the organized motions on turbulent transport depends critically on the scale of the heterogeneity lambda, the boundary layer height zi and the initial moisture state of the boundary layer. Dynamical and scalar fields respond differently as the scale of the heterogeneity varies. Surface heterogeneity of scale 4 less than lamba/z(sub i) less than 9 induces the strongest organized flow fields (up, wp) while heterogeneity with smaller or larger lambda/z(sub i) induces little organized motion. However, the organized components of the scalar fields (virtual potential temperature and mixing ratio) grow continuously in magnitude and horizontal scale, as lambda/z(sub i) increases. For some cases, the organized motions can contribute nearly 100% of the total vertical moisture flux. Patch-induced fluxes are shown to dramatically impact point measurements that assume the time-average vertical velocity to be zero. The magnitude and sign of this impact depends on the location of the measurement within the region of heterogeneity.

English and Spanish oral cancer information on the internet: a pilot surface quality and content evaluation of oral cancer web sites.

PubMed

Irwin, Jeannie Y; Thyvalikakath, Thankam; Spallek, Heiko; Wali, Teena; Kerr, Alexander Ross; Schleyer, Titus

2011-01-01

Oral and pharyngeal cancers are responsible for over 7600 deaths each year in the United States. Given the significance of the disease and the fact that many individuals increasingly rely on health information on the Internet, it is important that patients and others can access clear and accurate oral cancer information on the Web. The objective of this study was threefold: (a) develop an initial method to evaluate surface and content quality of selected English- and Spanish-language oral cancer Web sites; (b) conduct a pilot evaluation; and (c) discuss implications of our findings for dental public health. We developed a search strategy to find oral cancer sites frequented by the public using Medline Plus, Google, and Yahoo in English and Spanish. We adapted the Information Quality Tool (IQT) to perform a surface evaluation and developed a novel tool to evaluate site content for 24 sites each in English and Spanish. English-language sites had an average IQT score of 76.6 (out of 100) and an average content score of 52.1 (out of 100). Spanish-language sites had an average IQT score of 50.3 and an average content score of 25.6. The study produced a quality assessment of oral cancer Web sites useful for clinicians and patients. Sites provided more information on clinical presentation, and etiology, and risk factors, than other aspects of oral cancer. The surface and quality of Spanish-language sites was low, possibly putting Hispanic populations at a disadvantage regarding oral cancer information on the Web.

An Assessment of Hydrogen as a Means to Implement the United States Navy’s Renewable Energy Initiative

DTIC Science & Technology

2014-09-01

pH of Household Items and Associated Effect on Fish , after [5] 5 As the world’s average surface temperature increases and continues to negatively... Effect on Fish , after [5] ........... 4  Figure 4.  Historical and Predicted Sea Level Change, after [10] ......................... 6  Figure 5...IPCC states in a 2014 climate change report [4] that, “[t]he global average consumption of fish and other products from fisheries and aquaculture in

Rapid fluctuations in flow and water-column properties in Asan Bay, Guam: implications for selective resilience of coral reefs in warming seas

USGS Publications Warehouse

Storlazzi, Curt D.; Field, Michael E.; Cheriton, Olivia M.; Presto, M.K.; Logan, J.B.

2013-01-01

Hydrodynamics and water-column properties were investigated off west-central Guam from July 2007 through January 2008. Rapid fluctuations, on time scales of 10s of min, in currents, temperature, salinity, and acoustic backscatter were observed to occur on sub-diurnal frequencies along more than 2 km of the fore reef but not at the reef crest. During periods characterized by higher sea-surface temperatures (SSTs), weaker wind forcing, smaller ocean surface waves, and greater thermal stratification, rapid decreases in temperature and concurrent rapid increases in salinity and acoustic backscatter coincided with onshore-directed near-bed currents and offshore-directed near-surface currents. During the study, these cool-water events, on average, lasted 2.3 h and decreased the water temperature 0.57 °C, increased the salinity 0.25 PSU, and were two orders of magnitude more prevalent during the summer season than the winter. During the summer season when the average satellite-derived SST anomaly was +0.63 °C, these cooling events, on average, lowered the temperature 1.14 °C along the fore reef but only 0.11 °C along the reef crest. The rapid shifts appear to be the result of internal tidal bores pumping cooler, more saline, higher-backscatter oceanic water from depths >50 m over cross-shore distances of 100 s of m into the warmer, less saline waters at depths of 20 m and shallower. Such internal bores appear to have the potential to buffer shallow coral reefs from predicted increases in SSTs by bringing cool, offshore water to shallow coral environments. These cooling internal bores may also provide additional benefits to offset stress such as supplying food to thermally stressed corals, reducing stress due to ultraviolet radiation and/or low salinity, and delivering coral larvae from deeper reefs not impacted by surface thermal stress. Thus, the presence of internal bores might be an important factor locally in the resilience of select coral reefs facing increased thermal stress.

Rapid fluctuations in flow and water-column properties in Asan Bay, Guam: implications for selective resilience of coral reefs in warming seas

NASA Astrophysics Data System (ADS)

Storlazzi, C. D.; Field, M. E.; Cheriton, O. M.; Presto, M. K.; Logan, J. B.

2013-12-01

Hydrodynamics and water-column properties were investigated off west-central Guam from July 2007 through January 2008. Rapid fluctuations, on time scales of 10s of min, in currents, temperature, salinity, and acoustic backscatter were observed to occur on sub-diurnal frequencies along more than 2 km of the fore reef but not at the reef crest. During periods characterized by higher sea-surface temperatures (SSTs), weaker wind forcing, smaller ocean surface waves, and greater thermal stratification, rapid decreases in temperature and concurrent rapid increases in salinity and acoustic backscatter coincided with onshore-directed near-bed currents and offshore-directed near-surface currents. During the study, these cool-water events, on average, lasted 2.3 h and decreased the water temperature 0.57 °C, increased the salinity 0.25 PSU, and were two orders of magnitude more prevalent during the summer season than the winter. During the summer season when the average satellite-derived SST anomaly was +0.63 °C, these cooling events, on average, lowered the temperature 1.14 °C along the fore reef but only 0.11 °C along the reef crest. The rapid shifts appear to be the result of internal tidal bores pumping cooler, more saline, higher-backscatter oceanic water from depths >50 m over cross-shore distances of 100 s of m into the warmer, less saline waters at depths of 20 m and shallower. Such internal bores appear to have the potential to buffer shallow coral reefs from predicted increases in SSTs by bringing cool, offshore water to shallow coral environments. These cooling internal bores may also provide additional benefits to offset stress such as supplying food to thermally stressed corals, reducing stress due to ultraviolet radiation and/or low salinity, and delivering coral larvae from deeper reefs not impacted by surface thermal stress. Thus, the presence of internal bores might be an important factor locally in the resilience of select coral reefs facing increased thermal stress.

Temporal Changes in the Observed Relationship between Cloud Cover and Surface Air Temperature.

NASA Astrophysics Data System (ADS)

Sun, Bomin; Groisman, Pavel Ya.; Bradley, Raymond S.; Keimig, Frank T.

2000-12-01

The relationship between cloud cover and near-surface air temperature and its decadal changes are examined using the hourly synoptic data for the past four to six decades from five regions of the Northern Hemisphere: Canada, the United States, the former Soviet Union, China, and tropical islands of the western Pacific. The authors define the normalized cloud cover-surface air temperature relationship, NOCET or dT/dCL, as a temperature anomaly with a unit (one-tenth) deviation of total cloud cover from its average value. Then mean monthly NOCET time series (night- and daytime, separately) are area-averaged and parameterized as functions of surface air humidity and snow cover. The day- and nighttime NOCET variations are strongly anticorrelated with changes in surface humidity. Furthermore, the daytime NOCET changes are positively correlated to changes in snow cover extent. The regionally averaged nighttime NOCET varies from 0.05 K tenth1 in the wet Tropics to 1.0 K tenth1 at midlatitudes in winter. The daytime regional NOCET ranges from 0.4 K tenth1 in the Tropics to 0.7 K tenth1 at midlatitudes in winter.The authors found a general strengthening of a daytime surface cooling during the post-World War II period associated with cloud cover over the United States and China, but a minor reduction of this cooling in higher latitudes. Furthermore, since the 1970s, a prominent increase in atmospheric humidity has significantly weakened the effectiveness of the surface warming (best seen at nighttime) associated with cloud cover.The authors apportion the spatiotemporal field of interactions between total cloud cover and surface air temperature into a bivariate relationship (described by two equations, one for daytime and one for nighttime) with surface air humidity and snow cover and two constant factors. These factors are invariant in space and time domains. It is speculated that they may represent empirical estimates of the overall cloud cover effect on the surface air temperature.

Dynamic Development of Regional Cortical Thickness and Surface Area in Early Childhood.

PubMed

Lyall, Amanda E; Shi, Feng; Geng, Xiujuan; Woolson, Sandra; Li, Gang; Wang, Li; Hamer, Robert M; Shen, Dinggang; Gilmore, John H

2015-08-01

Cortical thickness (CT) and surface area (SA) are altered in many neuropsychiatric disorders and are correlated with cognitive functioning. Little is known about how these components of cortical gray matter develop in the first years of life. We studied the longitudinal development of regional CT and SA expansion in healthy infants from birth to 2 years. CT and SA have distinct and heterogeneous patterns of development that are exceptionally dynamic; overall CT increases by an average of 36.1%, while cortical SA increases 114.6%. By age 2, CT is on average 97% of adult values, compared with SA, which is 69%. This suggests that early identification, prevention, and intervention strategies for neuropsychiatric illness need to be targeted to this period of rapid postnatal brain development, and that SA expansion is the principal driving factor in cortical volume after 2 years of age. © The Author 2014. Published by Oxford University Press. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com.

Surface Roughness Investigation of Ultrafine-Grained Aluminum Alloy Subjected to High-Speed Erosion

NASA Astrophysics Data System (ADS)

Kazarinov, N. A.; Evstifeev, A. D.; Petrov, Y. V.; Atroshenko, S. A.; Lashkov, V. A.; Valiev, R. Z.; Bondarenko, A. S.

2016-09-01

This study is the first attempt to investigate the influence of severe plastic deformation (SPD) treatment on material surface behavior under intensive erosive conditions. Samples of aluminum alloy 1235 (99.3 Al) before and after high-pressure torsion (HPT) were subjected to intensive erosion by corundum particles accelerated via air flow in a small-scale wind tunnel. Velocity of particles varied from 40 to 200 m/s, while particle average diameter was around 100 μm. Surface roughness measurements provided possibility to compare surface properties of both materials after erosion tests. Moreover, SPD processing appeared to increase noticeably the threshold velocity of the surface damaging process. Additionally, structural analysis of the fracture surfaces of the tested samples was carried out.

Modelling radiative transfer through ponded first-year Arctic sea ice with a plane-parallel model

NASA Astrophysics Data System (ADS)

Taskjelle, Torbjørn; Hudson, Stephen R.; Granskog, Mats A.; Hamre, Børge

2017-09-01

Under-ice irradiance measurements were done on ponded first-year pack ice along three transects during the ICE12 expedition north of Svalbard. Bulk transmittances (400-900 nm) were found to be on average 0.15-0.20 under bare ice, and 0.39-0.46 under ponded ice. Radiative transfer modelling was done with a plane-parallel model. While simulated transmittances deviate significantly from measured transmittances close to the edge of ponds, spatially averaged bulk transmittances agree well. That is, transect-average bulk transmittances, calculated using typical simulated transmittances for ponded and bare ice weighted by the fractional coverage of the two surface types, are in good agreement with the measured values. Radiative heating rates calculated from model output indicates that about 20 % of the incident solar energy is absorbed in bare ice, and 50 % in ponded ice (35 % in pond itself, 15 % in the underlying ice). This large difference is due to the highly scattering surface scattering layer (SSL) increasing the albedo of the bare ice.

Characterization of nanoporous shales with gas sorption

NASA Astrophysics Data System (ADS)

Joewondo, N.; Prasad, M.

2017-12-01

The understanding of the fluid flow in porous media requires the knowledge of the pore system involved. Fluid flow in fine grained shales falls under different regime than transport regime in conventional reservoir due to the different average pore sizes in the two materials; the average pore diameter of conventional sandstones is on the micrometer scale, while of shales can be as small as several nanometers. Mercury intrusion porosimetry is normally used to characterize the pores of conventional reservoir, however with increasingly small pores, the injection pressure required to imbibe the pores becomes infinitely large due to surface tension. Characterization of pores can be expressed by a pore size distribution (PSD) plot, which reflects distribution of pore volume or surface area with respect to pore size. For the case of nanoporous materials, the surface area, which serves as the interface between the rock matrix and fluid, becomes increasingly large and important. Physisorption of gas has been extensively studied as a method of nanoporous solid characterization (particularly for the application of catalysis, metal organic frameworks, etc). The PSD is obtained by matching the experimental result to the calculated theoretical result (using Density Functional Theory (DFT), a quantum mechanics based modelling method for molecular scale interactions). We present the challenges and experimental result of Nitrogen and CO2 gas sorption on shales with various mineralogy and the interpreted PSD obtained by DFT method. Our result shows significant surface area contributed by the nanopores of shales, hence the importance of surface area measurements for the characterization of shales.

Activation Pattern of Lower Leg Muscles in Running on Asphalt, Gravel and Grass.

PubMed

Dolenec, Aleš; Štirn, Igor; Strojnik, Vojko

2015-07-01

Running is performed on different natural surfaces (outdoor) and artificial surfaces (indoor). Different surface characteristics cause modification of the lower leg muscle activation pattern to adopt ankle stiffness to these characteristics. So the purpose of our investigation was to study changes of lower leg muscles activation pattern in running on different natural running surfaces. Six male and two female runners participated. The participants ran at a freely chosen velocity in trials on asphalt while in trials on gravel, and grass surfaces they were attempting to reach similar velocities as in the trials on asphalt. Muscle activation of the peroneus brevis, tibialis anterior, soleus, and gastrocnemius medialis of the right leg was recorded. Running on asphalt increased average EMG amplitude of the m. tibialis anterior in the pre-activation phase and the m. gastrocnemius medialis in the entire contact phase compared to running on grass from 0.222 ± 0.113 V to 0.276 ± 0.136 V and from 0.214 ± 0.084 V to 0.238 ± 0.088 V, respectively. The average EMG of m. peroneus brevis in pre-activation phase increased from 0.156 ± 0.026 V to 0.184 ± 0.455 V in running on grass in comparison to running on gravel. Running on different surfaces is connected with different activation patterns of lower leg muscles. Running on asphalt requires stiff ankle joints, running on gravel requires greater stability in ankle joints, while running on grass is the least demanding on lower leg muscles.

Corrosion of Nickel-Titanium Orthodontic Archwires in Saliva and Oral Probiotic Supplements

PubMed Central

Turco, Gianluca; Contardo, Luca; Serdarević, Nikolina Leona; Otmačić, Helena; Ćurković; Špalj, Stjepan

2017-01-01

Objectives The aim of the study was to examine how probiotic supplements affect the corrosion stability of orthodontic archwires made of nickel-titanium alloy (NiTi). Materials and Methods NiTi archwires (0.508x0.508 and having the length of 2.5 cm) were tested. The archwires (composition Ni=50.4%, Ti=49.6%) were uncoated, nitrified and rhodium coated. Surface microgeometry was observed by using scanning electron microscope and surface roughness was measured by profilometer through these variables: roughness average, maximum height and maximum roughness depth. Corrosion was examined by electrochemical method of cyclic polarisation. Results Rhodium coated alloy in saliva has significantly higher general corrosion in saliva than nitrified alloy and uncoated alloy, with large effect size (p=0.027; η2=0.700). In the presence of probiotics, the result was even more pronounced (p<0.001; η2=0.936). Probiotic supplement increases general and localised corrosion of rhodium coated archwire and slightly decreases general corrosion and increases localised corrosion in uncoated archwire, while in the case of nitrified archwire the probability of corrosion is very low. The differences in surface roughness between NiTi wires before corrosion are not significant. Exposure to saliva decreases roughness average in rhodium coated wire (p=0.015; η2=0.501). Media do not significantly influence surface microgeometry in nitrified and uncoated wires. Conclusion Probiotic supplement affects corrosion depending on the type of coating of the NiTi archwire. It increases general corrosion of rhodium coated wire and causes localised corrosion of uncoated and rhodium coated archwire. Probiotic supplement does not have greater influence on surface roughness compared to that of saliva. PMID:29872237

Exploring Statistical Characterizations of Morphologic Change and Variability: Fire Island, New York

NASA Astrophysics Data System (ADS)

Lentz, E. E.; Hapke, C. J.

2012-12-01

A comprehensive understanding of coastal barrier behavior requires high-resolution observations that capture a wide range of morphological changes occurring over a range of spatial and temporal scales. Fire Island National Seashore, located along the coast of Long Island, New York, is a well studied barrier island coast where understanding how morphological changes contribute to barrier island vulnerability have important implications for coastal land management. Previous work has shown that morphologic differences in eastern and western reaches are attributable to the underlying geology and variations sediment transport in the system. In this study, we further explore western and eastern differences and variability with lidar-derived topographic surfaces to provide a unique and comprehensive investigation of dune-beach change at Fire Island, New York. Continuous topographic surfaces generated from 12 lidar surveys collected between 1998 and 2011 are used to examine the three-dimensional variability over a range of time periods over the 50 km long island. Because surveys were collected over a range of seasons and in response to a number of storm events, we explore morphologic configurations reflecting the seasonality, post-storm configuration, and replenishment response to the system through the generation of a representative or average surface. These averaged surfaces provide the context for what would be an expected or typical coastal configuration under certain conditions, and through comparison with an individual event, can be used to derive an event-specific spatial-change signature. To investigate anthropogenic influences, differences in morphology between a survey collected after a substantial beach replenishment project and a typical fair-weather configuration averaged from six surveys are determined. Storm response variations are also explored by assessing differences between Tropical Storm Irene (2011), Nor'Ida (2009), and a typical post-storm configuration averaged from five post-storm surveys. In addition to averaged surfaces, surveys are combined to generate a new raster surface reflecting cell by cell standard deviations over a defined period. Standard deviation surfaces are generated to highlight 1) where areas of highest and lowest morphologic variation are located over the entire period, and 2) whether spatial similarities exist in variability between storm and non-storm morphologies. Results show there are distinct and variable responses in eastern and western reaches attributable to wave climate, profile gradient, and offshore bathymetry, as well as to a general along-coast increase in sediment availability.

Effects of temporal averaging on short-term irradiance variability under mixed sky conditions

NASA Astrophysics Data System (ADS)

Lohmann, Gerald M.; Monahan, Adam H.

2018-05-01

Characterizations of short-term variability in solar radiation are required to successfully integrate large numbers of photovoltaic power systems into the electrical grid. Previous studies have used ground-based irradiance observations with a range of different temporal resolutions and a systematic analysis of the effects of temporal averaging on the representation of variability is lacking. Using high-resolution surface irradiance data with original temporal resolutions between 0.01 and 1 s from six different locations in the Northern Hemisphere, we characterize the changes in representation of temporal variability resulting from time averaging. In this analysis, we condition all data to states of mixed skies, which are the most potentially problematic in terms of local PV power volatility. Statistics of clear-sky index k* and its increments Δk*τ (i.e., normalized surface irradiance and changes therein over specified intervals of time) are considered separately. Our results indicate that a temporal averaging time scale of around 1 s marks a transition in representing single-point irradiance variability, such that longer averages result in substantial underestimates of variability. Higher-resolution data increase the complexity of data management and quality control without appreciably improving the representation of variability. The results do not show any substantial discrepancies between locations or seasons.

Quantifying Sulfur-Containing Compounds Over the Santa Barbara Channel

NASA Astrophysics Data System (ADS)

Black, J.; Hughes, S.; Blake, D. R.

2016-12-01

Carbonyl sulfide (OCS) is emitted to the atmosphere through the outgassing of ocean surface waters. OCS is also the primary source of sulfur-containing compounds in the stratosphere and contributes to the formation of the stratospheric sulfate layer. During the 2016 Student Airborne Research Program (SARP), whole air samples were collected on the NASA DC-8 aircraft over the Santa Barbara Channel. Five additional surface samples were taken at various locations along the Santa Barbara Channel. The samples were analyzed using gas chromatography in the Rowland-Blake lab at UC Irvine, and compounds such as OCS, dimethyl sulfide (DMS), carbon disulfide (CS2), bromoform (CHBr3), and methyl iodide (CH3I) associated with ocean emissions and stratospheric aerosols were analyzed. These marine sourced compounds, excluding OCS, showed expected trends of dilution with increasing altitude. The surface samples from the Santa Barbara Channel all exhibited elevated concentrations of OCS in comparison to samples taken from the aircraft, with an average of 666 ± 12 pptv, whereas the average background concentration of OCS was 587 ± 19 pptv. SARP flights from 2009-2015 over the Santa Barbara Channel saw an average OCS concentration of 548 ± 26 pptv. Elevated levels of OCS have never been detected from the aircraft during SARP flights, indicating that OCS emissions must be measured using surface sampling if emission estimates from the ocean are to be evaluated.

Comparison between AVHRR surface temperature data and in-situ weather station temperatures over the Greenland Ice Sheet

NASA Astrophysics Data System (ADS)

Rezvanbehbahani, S.; Csatho, B. M.; Comiso, J. C.; Babonis, G. S.

2011-12-01

Advanced Very-High Resolution Radiometer (AVHRR) images have been exhaustively used to measure surface temperature time series of the Greenland Ice sheet. The purpose of this study is to assess the accuracy of monthly average ice sheet surface temperatures, derived from thermal infrared AVHRR satellite imagery on a 6.25 km grid. In-situ temperature data sets are from the Greenland Collection Network (GC-Net). GC-Net stations comprise sensors monitoring air temperature at 1 and 2 meter above the snow surface, gathered at every 60 seconds and monthly averaged to match the AVHRR temporal resolution. Our preliminary results confirm the good agreement between satellite and in-situ temperature measurements reported by previous studies. However, some large discrepancies still exist. While AVHRR provides ice surface temperature, in-situ stations measure air temperatures at different elevations above the snow surface. Since most in-situ data on ice sheets are collected by Automatic Weather Station (AWS) instruments, it is important to characterize the difference between surface and air temperatures. Therefore, we compared and analyzed average monthly AVHRR ice surface temperatures using data collected in 2002. Differences between these temperatures correlate with in-situ temperatures and GC-Net station elevations, with increasing differences at lower elevations and higher temperatures. The Summit Station (3199 m above sea level) and the Swiss Camp (1176 m above sea level) results were compared as high altitude and low altitude stations for 2002, respectively. Our results show that AVHRR derived temperatures were 0.5°K warmer than AWS temperature at the Summit Station, while this difference was 2.8°K in the opposite direction for the Swiss Camp with surface temperatures being lower than air temperatures. The positive bias of 0.5°K at the high altitude Summit Station (surface warmer than air) is within the retrieval error of AVHRR temperatures and might be in part due to atmospheric inversion. The large negative bias of 2.8°K at the low altitude Swiss Camp (surface colder than the air) could be caused by a combination of different factors including local effects such as more windy circumstances above the snow surface and biases introduced by the cloud-masking applied on the AVHRR images. Usually only satellite images acquired in clear-sky conditions are used for deriving monthly AVHRR average temperatures. Since cloud-free days are usually warmer, satellite derived temperatures tend to underestimate the real average temperatures, especially regions with frequent cloud cover, such as Swiss Camp. Therefore, cautions must be exercised while using ice surface temperatures derived from satellite imagery for glaciological applications. Eliminating the cloudy day's' temperature from the in-situ data prior to the comparison with AVHRR derived temperatures will provide a better assessment of AVHRR surface temperature measurement accuracy.

Increasing runoff and sediment load from the Greenland ice sheet at kangerlussuaq (Sonder Stromfjord) in a 30-year perspective, 1979-2008

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mernild, Sebastian Haugard; Liston, Glen; Hasholt, Bent

2009-01-01

This observation and modeling study provides insights into runoff and sediment load exiting the Watson River drainage basin, Kangerlussuaq, West Greenland during a 30 year period (1978/79-2007/08) when the climate experienced increasing temperatures and precipitation. The 30-year simulations quantify the terrestrial freshwater and sediment output from part of the Greenland Ice Sheet (GrIS) and the land between the GrIS and the ocean, in the context of global warming and increasing GrIS surface melt. We used a snow-evolution modeling system (SnowModel) to simulate the winter accumulation and summer ablation processes, including runoff and surface mass balance (SMB), of the Greenland icemore » sheet. Observed sediment concentrations were related to observed runoff, producing a sediment-load time series. To a large extent, the SMB fluctuations could be explained by changes in net precipitation (precipitation minus evaporation and sublimation), with 8 out of 30 years having negative SMB, mainly because of relatively low annual net precipitation. The overall trend in net precipitation and runoff increased significantly, while 5MB increased insignificantly throughout the simulation period, leading to enhanced precipitation of 0.59 km{sup 3} w.eq. (or 60%), runoff of 0.43 km{sup 3} w.eq (or 54%), and SMB of 0.16 km3 w.eq. (or 86%). Runoff rose on average from 0.80 km{sup 3} w.eq. in 1978/79 to 1.23 km{sup 3} w.eq. in 2007/08. The percentage of catchment oudet runoff explained by runoff from the GrIS decreased on average {approx} 10%, indicating that catchment runoff throughout the simulation period was influenced more by precipitation and snowmelt events, and less by runoff from the GrIS. Average variations in the increasing Kangerlussuaq runoff from 1978/79 through 2007/08 seem to follow the overall variations in satellite-derived GrIS surface melt, where 64% of the variations in simulated runoff were explained by regional melt conditions on the GrIS. Throughout the simulation period, the sediment load varied from a minimum of 0.96 x 10{sup 6} t y{sup -1} in 1991/92 to a maximum of 3.52 x 10{sup 6} t y{sup -1} in 2006/07, showing an average increase of sediment load of 9.42 x 10{sup 5} t (or 72%) throughout the period.« less

An adjoint method for gradient-based optimization of stellarator coil shapes

NASA Astrophysics Data System (ADS)

Paul, E. J.; Landreman, M.; Bader, A.; Dorland, W.

2018-07-01

We present a method for stellarator coil design via gradient-based optimization of the coil-winding surface. The REGCOIL (Landreman 2017 Nucl. Fusion 57 046003) approach is used to obtain the coil shapes on the winding surface using a continuous current potential. We apply the adjoint method to calculate derivatives of the objective function, allowing for efficient computation of analytic gradients while eliminating the numerical noise of approximate derivatives. We are able to improve engineering properties of the coils by targeting the root-mean-squared current density in the objective function. We obtain winding surfaces for W7-X and HSX which simultaneously decrease the normal magnetic field on the plasma surface and increase the surface-averaged distance between the coils and the plasma in comparison with the actual winding surfaces. The coils computed on the optimized surfaces feature a smaller toroidal extent and curvature and increased inter-coil spacing. A technique for computation of the local sensitivity of figures of merit to normal displacements of the winding surface is presented, with potential applications for understanding engineering tolerances.

Deep and surface learning in problem-based learning: a review of the literature.

PubMed

Dolmans, Diana H J M; Loyens, Sofie M M; Marcq, Hélène; Gijbels, David

2016-12-01

In problem-based learning (PBL), implemented worldwide, students learn by discussing professionally relevant problems enhancing application and integration of knowledge, which is assumed to encourage students towards a deep learning approach in which students are intrinsically interested and try to understand what is being studied. This review investigates: (1) the effects of PBL on students' deep and surface approaches to learning, (2) whether and why these effects do differ across (a) the context of the learning environment (single vs. curriculum wide implementation), and (b) study quality. Studies were searched dealing with PBL and students' approaches to learning. Twenty-one studies were included. The results indicate that PBL does enhance deep learning with a small positive average effect size of .11 and a positive effect in eleven of the 21 studies. Four studies show a decrease in deep learning and six studies show no effect. PBL does not seem to have an effect on surface learning as indicated by a very small average effect size (.08) and eleven studies showing no increase in the surface approach. Six studies demonstrate a decrease and four an increase in surface learning. It is concluded that PBL does seem to enhance deep learning and has little effect on surface learning, although more longitudinal research using high quality measurement instruments is needed to support this conclusion with stronger evidence. Differences cannot be explained by the study quality but a curriculum wide implementation of PBL has a more positive impact on the deep approach (effect size .18) compared to an implementation within a single course (effect size of -.05). PBL is assumed to enhance active learning and students' intrinsic motivation, which enhances deep learning. A high perceived workload and assessment that is perceived as not rewarding deep learning are assumed to enhance surface learning.

Aquatic burst locomotion by hydroplaning and paddling in common eiders (Somateria mollissima).

PubMed

Gough, William T; Farina, Stacy C; Fish, Frank E

2015-06-01

Common eiders (Somateria mollissima) are heavy sea-ducks that spend a large portion of their time swimming at the water surface. Surface swimming generates a bow and hull wave that can constructively interfere and produce wave drag. The speed at which the wavelengths of these waves equal the waterline length of the swimming animal is the hull speed. To increase surface swimming speed beyond the hull speed, an animal must overtake the bow wave. This study found two distinct behaviors that eider ducks used to exceed the hull speed: (1) 'steaming', which involved rapid oaring with the wings to propel the duck along the surface of the water, and (2) 'paddle-assisted flying', during which the ducks lifted their bodies out of the water and used their feet to paddle against the surface while flapping their wings in the air. An average hull speed (0.732±0.046 m s(-1)) was calculated for S. mollissima by measuring maximum waterline length from museum specimens. On average, steaming ducks swam 5.5 times faster and paddle-assisted flying ducks moved 6.8 times faster than the hull speed. During steaming, ducks exceeded the hull speed by increasing their body angle and generating dynamic lift to overcome wave drag and hydroplane along the water surface. During paddle-assisted flying, ducks kept their bodies out of the water, thereby avoiding the limitations of wave drag altogether. Both behaviors provided alternatives to flight for these ducks by allowing them to exceed the hull speed while staying at or near the water surface. © 2015. Published by The Company of Biologists Ltd.

Investigation of the relationship between CO2 reservoir rock property change and the surface roughness change originating from the supercritical CO2-sandstone-groundwater geochemical reaction at CO2 sequestration condition

NASA Astrophysics Data System (ADS)

Lee, Minhee; Wang, Sookyun; Kim, Seyoon; Park, Jinyoung

2015-04-01

Lab scale experiments were performed to investigate the property changes of sandstone slabs and cores, resulting from the scCO2-rock-groundwater reaction for 180 days under CO2 sequestration conditions (100 bar and 50 °C). The geochemical reactions, including the surface roughness change of minerals in the slab, resulted from the dissolution and the secondary mineral precipitation for the sandstone reservoir of the Gyeongsang basin, Korea were reproduced in laboratory scale experiments and the relationship between the geochemical reaction and the physical rock property change was derived, for the consideration of successful subsurface CO2 sequestration. The use of the surface roughness value (SRrms) change rate and the physical property change rate to quantify scCO2-rock-groundwater reaction is the novel approach on the study area for CO2 sequestration in the subsurface. From the results of SPM (Scanning Probe Microscope) analyses, the SRrms for each sandstone slab was calculated at different reaction time. The average SRrms increased more than 3.5 times during early 90 days reaction and it continued to be steady after 90 days, suggesting that the surface weathering process of sandstone occurred in the early reaction time after CO2 injection into the subsurface reservoir. The average porosity of sandstone cores increased by 8.8 % and the average density decreased by 0.5 % during 90 days reaction and these values slightly changed after 90 days. The average P and S wave velocities of sandstone cores also decreased by 10 % during 90 days reaction. The trend of physical rock property change during the geochemical reaction showed in a logarithmic manner and it was also correlated to the logarithmic increase in SRrms, suggesting that the physical property change of reservoir rocks originated from scCO2 injection directly comes from the geochemical reaction process. Results suggested that the long-term estimation of the physical property change for reservoir rocks in CO2 injection site could be possible from the extrapolation process of SRrms and rocks property change rates, acquired from laboratory scale experiments. It will be aslo useful to determine the favorite CO2 injection site from the viewpoint of the safety.

Plasma-material interaction in electrothermal and electromagnetic launchers

NASA Astrophysics Data System (ADS)

Bourham, M. A.; Gilligan, J. G.; Hankins, O. E.

1993-07-01

Various material surfaces have been exposed to high heat fluxes from 2 to 80 GW/sq m over 100 microsec duration using the electrothermal launcher, SIRENS. The vapor shield is effective in reducing the heat to the ablating surface, and the energy transmission factor through the vapor shield decreases as the incident heat flux increases. Results show good agreement with code predictions. Visible light emission spectra have been observed both in-bore and from the muzzle flash of the barrel, and from the flash of the source. Measurements of visible emission from the source indicate time averaged temperatures of 1 to 3 eV, and about 1 to 2 eV along the axis of the device, which agree with the theory and experimental measurements of the average heat flux and plasma conductivity.

Impact of Te and ne on edge current density profiles in ELM mitigated regimes on ASDEX Upgrade

NASA Astrophysics Data System (ADS)

Dunne, M. G.; Rathgeber, S.; Burckhart, A.; Fischer, R.; Giannone, L.; McCarthy, P. J.; Schneider, P. A.; Wolfrum, E.; the ASDEX Upgrade Team

2015-01-01

ELM resolved edge current density profiles are reconstructed using the CLISTE equilibrium code. As input, highly spatially and temporally resolved edge electron temperature and density profiles are used in addition to data from the extensive set of external poloidal field measurements available at ASDEX Upgrade, flux loop difference measurements, and current measurements in the scrape-off layer. Both the local and flux surface averaged current density profiles are analysed for several ELM mitigation regimes. The focus throughout is on the impact of altered temperature and density profiles on the current density. In particular, many ELM mitigation regimes rely on operation at high density. Two reference plasmas with type-I ELMs are analysed, one with a deuterium gas puff and one without, in order to provide a reference for the behaviour in type-II ELMy regimes and high density ELM mitigation with external magnetic perturbations at ASDEX Upgrade. For type-II ELMs it is found that while a similar pedestal top pressure is sustained at the higher density, the temperature gradient decreases in the pedestal. This results in lower local and flux surface averaged current densities in these phases, which reduces the drive for the peeling mode. No significant differences between the current density measured in the type-I phase and ELM mitigated phase is seen when external perturbations are applied, though the pedestal top density was increased. Finally, ELMs during the nitrogen seeded phase of a high performance discharge are analysed and compared to ELMs in the reference phase. An increased pedestal pressure gradient, which is the source of confinement improvement in impurity seeded discharges, causes a local current density increase. However, the increased Zeff in the pedestal acts to reduce the flux surface averaged current density. This dichotomy, which is not observed in other mitigation regimes, could act to stabilize both the ballooning mode and the peeling mode at the same time.

Modeling The Urban Impact On Semiarid Surface Climate: A Case Study In Marrakesh, Morocco

NASA Technical Reports Server (NTRS)

Lachir, Asia; Bounoua, Lahouari; Zhang, Ping; Thome, Kurtis; Messouli, Mohamed

2016-01-01

We combine Landsat and MODIS data in the Simple Biosphere Model to assess the impact of urbanization on surface climate in a semiarid city in North Africa. The model simulates highest temperatures in urban class, with spring average maximum temperature differences to other land cover classes ranging between 1.6 C and 6.0 C. During summer, these maximum temperature differences are smallest (0.5 C) with barelands and highest (8.3 C) with irrigated lawns. This excess heating is simulated above and beyond a seasonal temperature average of about 30 C during spring and 44 C during summer. On annual mean, a full urbanization scenario decreases the carbon fixation by 0.13 MtC and increases the daytime mean surface temperature by 1.3 C. This may boost the city energy consumption by 5.72%. Under a 'smart growth' scenario, whereby the city expands on barelands to cover 50% of the study region and all remaining barelands converted to orchards, the carbon fixation is enhanced by 0.04 MtC with a small daytime temperature increase of 0.2 C. Our results indicate that vegetation can mitigate the urban heating. The hydrological cycle indicates that highest ratio of surface runoff to precipitation (43.8%) occurs in urban areas, versus only 16.7 % for all cover types combined.

Modeling the Urban Impact on Semiarid Surface Climate: A Case Study in Marrakech, Morocco

NASA Technical Reports Server (NTRS)

Lachir, Asia; Bounoua, Lahouari; Zhang, Ping; Thome, Kurtis; Moussouli, Mohamed

2016-01-01

We combine Landsat and MODIS data in the Simple Biosphere Model to assess the impact of urbanization on surface climate in a semiarid city in North Africa. The model simulates highest temperatures in urban class, with spring average maximum temperature differences to other land cover classes ranging between 1.6 C and 6.0 C. During summer, these maximum temperature differences are smallest (0.5 C) with barelands and highest (8.3 C) with irrigated lawns. This excess heating is simulated above and beyond a seasonal temperature average of about 30 C during spring and 44 C during summer. On annual mean, a full urbanization scenario decreases the carbon fixation by 0.13 MtC and increases the daytime mean surface temperature by 1.3 C. This may boost the city energy consumption by 5.72%. Under a 'smart growth' scenario, whereby the city expands on barelands to cover 50% of the study region and all remaining barelands converted to orchards, the carbon fixation is enhanced by 0.04 MtC with a small daytime temperature increase of 0.2 C. Our results indicate that vegetation can mitigate the urban heating. The hydrological cycle indicates that highest ratio of surface runoff to precipitation (43.8%) occurs in urban areas, versus only 16.7 % for all cover types combined.

The use and effects of studded tires in Oregon.

DOT National Transportation Integrated Search

1974-12-01

During the past 11 years the use of studded tires has increased from a novelty to anestimated average of 20 percent for the Northern States in which snow and ice is expected. An alarming amount of surface wear in the wheel paths of the highway paveme...

Climate Impacts of CALIPSO-Guided Corrections to Black Carbon Aerosol Vertical Distributions in a Global Climate Model

NASA Astrophysics Data System (ADS)

Kovilakam, Mahesh; Mahajan, Salil; Saravanan, R.; Chang, Ping

2017-10-01

We alleviate the bias in the tropospheric vertical distribution of black carbon aerosols (BC) in the Community Atmosphere Model (CAM4) using the Cloud-Aerosol and Infrared Pathfinder Satellite Observations (CALIPSO)-derived vertical profiles. A suite of sensitivity experiments are conducted with 1x, 5x, and 10x the present-day model estimated BC concentration climatology, with (corrected, CC) and without (uncorrected, UC) CALIPSO-corrected BC vertical distribution. The globally averaged top of the atmosphere radiative flux perturbation of CC experiments is ˜8-50% smaller compared to uncorrected (UC) BC experiments largely due to an increase in low-level clouds. The global average surface temperature increases, the global average precipitation decreases, and the ITCZ moves northward with the increase in BC radiative forcing, irrespective of the vertical distribution of BC. Further, tropical expansion metrics for the poleward extent of the Northern Hemisphere Hadley cell (HC) indicate that simulated HC expansion is not sensitive to existing model biases in BC vertical distribution.

Stream denitrification across biomes and its response to anthropogenic nitrate loading

Treesearch

Patrick J. Mulholland; Ashley M. Helton; Geoffrey C. Poole; Robert O. Hall; Stephen K. Hamilton; et al

2008-01-01

Anthropogenic addition of bioavailable nitrogen to the biosphere is increasing1, 2 and terrestrial ecosystems are becoming increasingly nitrogen-saturated3, causing more bioavailable nitrogen to enter groundwater and surface waters4, 5, 6. Large-scale nitrogen budgets show that an average of about 20–25 per cent of the nitrogen added to the biosphere is exported from...

Latitudinal and Longitudinal Basin-scale Surface Salinity Contrasts and Freshwater Transport by Ocean Thermohaline Circulation

NASA Astrophysics Data System (ADS)

Seidov, D.; Haupt, B. J.

2003-12-01

The role of sea surface salinity (SSS) contrasts in maintaining vigorous global ocean thermohaline circulation (THC) is revisited. Relative importance of different generalizations of sea surface conditions in climate studies is explored. In numerical experiments using an ocean general circulation model, we have aggregated the observed sea surface temperature (SST) and SSS in several different ways: we used observed unchanged SST with SSS taken as constant (34.25 psu) everywhere; SST unchanged, and SSS zonally averaged globally, i.e., in the whole World Ocean; SST averaged globally, and SSS unchanged; SST zonally averaged globally and SSS zonally averaged basin-wide in individual basins, i.e., in the Atlantic, Indian, Pacific, and Southern Oceans separately; and, finally, both SST and SSS zonally averaged in individual basins. Global zonal averaging removes all longitudinal differences in sea surface climatology among ocean basins. However, latitudinal profiles of zonally averaged parameters preserve the main character of large-scale equator-to-pole sea surface variability. Basin-wide zonal averaging does an even better job of preserving latitudinal distributions within each basin. The results of the experiments could hardly be anticipated a priory. Surprisingly, SST could be used as a 2-D field, or as a zonally-averaged field without much difference in the THC dynamics. Moreover, SST could be averaged either globally, or basin-wide, and it also did not change the overall character of THC. At the same time, THC responded vigorously to how the SSS has been changed. It appeared that the THC structure with the globally averaged SST and basin-wide averaged SSS was very close to the one obtained in the control run (control run operates with 2-D observed SST and SSS). Our main conclusion is that ocean-wide inter-basin sea surface salinity contrasts serve as the major controlling element in global thermohaline circulation. Thermal inter-basin contrasts, as well as longitudinal variation in SSS, are less important than latitudinal thermal gradients and inter-basin salinity contrasts. Details of SSS also decrease in importance as soon as its inter-basin contrasts are retained. This is especially important for paleoclimate and future climate simulations, as only the large-scale inter-basin contrasts of the sea surface conditions really matter.

Estimated use of water in the United States, 1965

USGS Publications Warehouse

Murray, Charles Richard

1968-01-01

Estimates of water use in the United States for 1965 indicate that an average of about 310 bgd (billion gallons per day) were withdrawn for public-supply, rural domestic and livestock, irrigation, and industrial (including thermoelectric power)uses--that is, about 1,600 gallons per capita per day. This represents an increase of 15 percent over the withdrawal of 270 bgd reported for 1960. Fresh water withdrawals for thermoelectric power generation increased nearly 25 percent during the 5 years, and saline water withdrawals increased 33 percent. An additional 2,300 bgd was used for hydroelectric power generation (waterpower), which also represented a 15-percent increase in 5 years. The quantity of water consumed-that is, water made unavailable for further possible withdrawal because of evaporation, incorporation in manufactured products, and other causes - was estimated to average 78 bgd for 1965, an increase of about 28 percent since 1960.Estimates made of the quantities of water withdrawn from surface and ground-water sources indicate withdrawals of 61 bgd of ground water, of which nearly 0.5 bgd was saline, and 250 bgd of surface water, of which 44 bgd was saline. The estimated amount of saline water used by industry increased 36 percent from 1960 to 1965. In addition to surface and ground water sources, reclaimed sewage supplied two-thirds of a billion gallons per day, mainly to irrigation and industry.The average annual streamflow in the United States is approximately 1,200 bgd, about four times the amount withdrawn for all purposes (except hydroelectric power) in 1965, and more than 15 times the estimated quantity of water consumed. However, comparisons of supply and demand in many river basins show that repeated use of the water is made, and at times in some basins all the available supply is consumed.In addition to tabulations of water-use data by States and by the water-use regions previously used, water-use tables are also given for the regions recently defined by the Water Resources Council for its national assessment.

Effects of turbulence-induced collision enhancement on heavy precipitation: The 21 September 2010 case over the Korean Peninsula

NASA Astrophysics Data System (ADS)

Lee, Hyunho; Baik, Jong-Jin

2016-10-01

The effects of turbulence-induced collision enhancement (TICE) on a heavy precipitation event that occurred on 21 September 2010 over the middle Korean Peninsula are examined. For this purpose, an updated bin microphysics scheme incorporating TICE for drop-drop and drop-graupel collisions is implemented into the Weather Research and Forecasting (WRF) model. The numerical simulation shows some differences in the strong precipitation system compared to the observations but generally captures well the important features of observed synoptic conditions, surface precipitation, and radar reflectivity. While the change in domain-averaged surface precipitation amount due to TICE is small and similar to that due to small initial perturbations, the spatial distribution of surface precipitation amount is somewhat altered due to TICE. The surface precipitation amount is increased due to TICE in the area where the largest surface precipitation occurred, but the effects of different flow realizations also contribute to the changes. TICE accelerates the coalescence between small cloud droplets, which induces a decrease in condensation and an increase in excess water vapor transported upward. This causes an increase in relative humidity with respect to ice at high altitudes, hence increasing the depositional growth of ice particles. Therefore, the ice mass increases due to TICE, and this increase induces the increases in riming and melting of ice particles. A series of these microphysical changes due to TICE are regarded as partially contributing to the increase in surface precipitation amount in some areas, hence inducing alterations in the spatial distribution of surface precipitation amount.

Correlation of gravestone decay and air quality 1960-2010

NASA Astrophysics Data System (ADS)

Mooers, H. D.; Carlson, M. J.; Harrison, R. M.; Inkpen, R. J.; Loeffler, S.

2017-03-01

Evaluation of spatial and temporal variability in surface recession of lead-lettered Carrara marble gravestones provides a quantitative measure of acid flux to the stone surfaces and is closely related to local land use and air quality. Correlation of stone decay, land use, and air quality for the period after 1960 when reliable estimates of atmospheric pollution are available is evaluated. Gravestone decay and SO2 measurements are interpolated spatially using deterministic and geostatistical techniques. A general lack of spatial correlation was identified and therefore a land-use-based technique for correlation of stone decay and air quality is employed. Decadally averaged stone decay is highly correlated with land use averaged spatially over an optimum radius of ≈7 km even though air quality, determined by records from the UK monitoring network, is not highly correlated with gravestone decay. The relationships among stone decay, air-quality, and land use is complicated by the relatively low spatial density of both gravestone decay and air quality data and the fact that air quality data is available only as annual averages and therefore seasonal dependence cannot be evaluated. However, acid deposition calculated from gravestone decay suggests that the deposition efficiency of SO2 has increased appreciably since 1980 indicating an increase in the SO2 oxidation process possibly related to reactions with ammonia.

Localized stress fluctuations drive shear thickening in dense suspensions

NASA Astrophysics Data System (ADS)

Rathee, Vikram; Blair, Daniel L.; Urbach, Jeffrey S.

2017-08-01

Dense particulate suspensions exhibit a dramatic increase in average viscosity above a critical, material-dependent shear stress. This thickening changes from continuous to discontinuous as the concentration is increased. Using direct measurements of spatially resolved surface stresses in the continuous thickening regime, we report the existence of clearly defined dynamic localized regions of substantially increased stress that appear intermittently at stresses above the critical stress. With increasing applied stress, these regions occupy an increasing fraction of the system, and the increase accounts quantitatively for the observed shear thickening. The regions represent high-viscosity fluid phases, with a size determined by the distance between the shearing surfaces and a viscosity that is nearly independent of shear rate but that increases rapidly with concentration. Thus, we find that continuous shear thickening arises from increasingly frequent localized discontinuous transitions between distinct fluid phases with widely differing viscosities.

Mass-velocity and size-velocity distributions of ejecta cloud from shock-loaded tin surface using large scale molecular dynamics simulations

NASA Astrophysics Data System (ADS)

Durand, Olivier; Soulard, Laurent

2015-06-01

The mass (volume and areal densities) versus velocity as well as the size versus velocity distributions of a shock-induced cloud of particles are investigated using large scale molecular dynamics (MD) simulations. A generic 3D tin crystal with a sinusoidal free surface roughness is set in contact with vacuum and shock-loaded so that it melts directly on shock. At the reflection of the shock wave onto the perturbations of the free surface, 2D sheets/jets of liquid metal are ejected. The simulations show that the distributions may be described by an analytical model based on the propagation of a fragmentation zone, from the tip of the sheets to the free surface, within which the kinetic energy of the atoms decreases as this zone comes closer to the free surface on late times. As this kinetic energy drives (i) the (self-similar) expansion of the zone once it has broken away from the sheet and (ii) the average size of the particles which result from fragmentation in the zone, the ejected mass and the average size of the particles progressively increase in the cloud as fragmentation occurs closer to the free surface. Though relative to nanometric scales, our model reproduces quantitatively experimental profiles and may help in their analysis.

Structure zone diagram and particle incorporation of nickel brush plated composite coatings

PubMed Central

Isern, L.; Impey, S.; Almond, H.; Clouser, S. J.; Endrino, J. L.

2017-01-01

This work studies the deposition of aluminium-incorporated nickel coatings by brush electroplating, focusing on the electroplating setup and processing parameters. The setup was optimised in order to increase the volume of particle incorporation. The optimised design focused on increasing the plating solution flow to avoid sedimentation, and as a result the particle transport experienced a three-fold increase when compared with the traditional setup. The influence of bath load, current density and the brush material used was investigated. Both current density and brush material have a significant impact on the morphology and composition of the coatings. Higher current densities and non-abrasive brushes produce rough, particle-rich samples. Different combinations of these two parameters influence the surface characteristics differently, as illustrated in a Structure Zone Diagram. Finally, surfaces featuring crevices and peaks incorporate between 3.5 and 20 times more particles than smoother coatings. The presence of such features has been quantified using average surface roughness Ra and Abbott-Firestone curves. The combination of optimised setup and rough surface increased the particle content of the composite to 28 at.%. PMID:28300159

Structure zone diagram and particle incorporation of nickel brush plated composite coatings

NASA Astrophysics Data System (ADS)

Isern, L.; Impey, S.; Almond, H.; Clouser, S. J.; Endrino, J. L.

2017-03-01

This work studies the deposition of aluminium-incorporated nickel coatings by brush electroplating, focusing on the electroplating setup and processing parameters. The setup was optimised in order to increase the volume of particle incorporation. The optimised design focused on increasing the plating solution flow to avoid sedimentation, and as a result the particle transport experienced a three-fold increase when compared with the traditional setup. The influence of bath load, current density and the brush material used was investigated. Both current density and brush material have a significant impact on the morphology and composition of the coatings. Higher current densities and non-abrasive brushes produce rough, particle-rich samples. Different combinations of these two parameters influence the surface characteristics differently, as illustrated in a Structure Zone Diagram. Finally, surfaces featuring crevices and peaks incorporate between 3.5 and 20 times more particles than smoother coatings. The presence of such features has been quantified using average surface roughness Ra and Abbott-Firestone curves. The combination of optimised setup and rough surface increased the particle content of the composite to 28 at.%.

Structure zone diagram and particle incorporation of nickel brush plated composite coatings.

PubMed

Isern, L; Impey, S; Almond, H; Clouser, S J; Endrino, J L

2017-03-16

This work studies the deposition of aluminium-incorporated nickel coatings by brush electroplating, focusing on the electroplating setup and processing parameters. The setup was optimised in order to increase the volume of particle incorporation. The optimised design focused on increasing the plating solution flow to avoid sedimentation, and as a result the particle transport experienced a three-fold increase when compared with the traditional setup. The influence of bath load, current density and the brush material used was investigated. Both current density and brush material have a significant impact on the morphology and composition of the coatings. Higher current densities and non-abrasive brushes produce rough, particle-rich samples. Different combinations of these two parameters influence the surface characteristics differently, as illustrated in a Structure Zone Diagram. Finally, surfaces featuring crevices and peaks incorporate between 3.5 and 20 times more particles than smoother coatings. The presence of such features has been quantified using average surface roughness Ra and Abbott-Firestone curves. The combination of optimised setup and rough surface increased the particle content of the composite to 28 at.%.

Ground-motion prediction equations for the average horizontal component of PGA, PGV, and 5%-damped PSA at spectral periods between 0.01 s and 10.0 s

USGS Publications Warehouse

Boore, D.M.; Atkinson, G.M.

2008-01-01

This paper contains ground-motion prediction equations (GMPEs) for average horizontal-component ground motions as a function of earthquake magnitude, distance from source to site, local average shear-wave velocity, and fault type. Our equations are for peak ground acceleration (PGA), peak ground velocity (PGV), and 5%-damped pseudo-absolute-acceleration spectra (PSA) at periods between 0.01 s and 10 s. They were derived by empirical regression of an extensive strong-motion database compiled by the 'PEER NGA' (Pacific Earthquake Engineering Research Center's Next Generation Attenuation) project. For periods less than 1 s, the analysis used 1,574 records from 58 mainshocks in the distance range from 0 km to 400 km (the number of available data decreased as period increased). The primary predictor variables are moment magnitude (M), closest horizontal distance to the surface projection of the fault plane (RJB), and the time-averaged shear-wave velocity from the surface to 30 m (VS30). The equations are applicable for M=5-8, RJB<200 km, and VS30= 180-1300 m/s. ?? 2008, Earthquake Engineering Research Institute.

A new parameterization for surface ocean light attenuation in Earth System Models: assessing the impact of light absorption by colored detrital material

NASA Astrophysics Data System (ADS)

Kim, G. E.; Pradal, M.-A.; Gnanadesikan, A.

2015-03-01

Light limitation can affect the distribution of biota and nutrients in the ocean. Light absorption by colored detrital material (CDM) was included in a fully coupled Earth System Model using a new parameterization for shortwave attenuation. Two model runs were conducted, with and without light attenuation by CDM. In a global average sense, greater light limitation associated with CDM increased surface chlorophyll, biomass and nutrients together. These changes can be attributed to the movement of biological productivity higher up the water column, which increased surface chlorophyll and biomass while simultaneously decreasing total biomass. Meanwhile, the reduction in biomass resulted in greater nutrient availability throughout the water column. Similar results were found on a regional scale in an analysis of the oceans by biome. In coastal regions, surface chlorophyll increased by 35% while total integrated phytoplankton biomass diminished by 18%. The largest relative increases in modeled surface chlorophyll and biomass in the open ocean were found in the equatorial biomes, while largest decreases in depth-integrated biomass and chlorophyll were found in the subpolar and polar biomes. This mismatch of surface and subsurface trends and their regional dependence was analyzed by comparing the competing factors of diminished light availability and increased nutrient availability on phytoplankton growth in the upper 200 m. Overall, increases in surface biomass were expected to accompany greater nutrient uptake and therefore diminish surface nutrients, but changes in light limitation decoupled trends between these two variables. Understanding changes in biological productivity requires both surface and depth-resolved information. Surface trends may be minimal or of the opposite sign to depth-integrated amounts, depending on the vertical structure of phytoplankton abundance.

Composite foam structures

NASA Technical Reports Server (NTRS)

Williams, Brian E. (Inventor); Brockmeyer, Jerry (Inventor); Tuffias, Robert H. (Inventor)

2005-01-01

A composite rigid foam structure that has a skin or coating on at least one of its surfaces. The skin is formed in situ by thermal spray techniques. The skin is bonded substantially throughout the surface of the porous substrate to the peripheries of the pores. The skin on the average does not penetrate the surface of the substrate by more than the depth of about 2 to 5 pores. Thus, thermal spraying the skin onto the rigid foam produces a composite that is tightly and uniformly bonded together without unduly increasing the weight of the composite structure. Both thermal conductivity and bonding are excellent.

Sensitivity of Climate Simulations to Land-Surface and Atmospheric Boundary-Layer Treatments-A Review.

NASA Astrophysics Data System (ADS)

Garratt, J. R.

1993-03-01

Aspects of the land-surface and boundary-layer treatments in some 20 or so atmospheric general circulation models (GCMS) are summarized. In only a small fraction of these have significant sensitivity studies been carried out and published. Predominantly, the sensitivity studies focus upon the parameterization of land-surface processes and specification of land-surface properties-the most important of these include albedo, roughness length, soil moisture status, and vegetation density. The impacts of surface albedo and soil moisture upon the climate simulated in GCMs with bare-soil land surfaces are well known. Continental evaporation and precipitation tend to decrease with increased albedo and decreased soil moisture availability. For example, results from numerous studies give an average decrease in continental precipitation of 1 mm day1 in response to an average albedo increase of 0.13. Few conclusive studies have been carried out on the impact of a gross roughness-length change-the primary study included an important statistical assessment of the impact upon the mean July climate around the globe of a decreased continental roughness (by three orders of magnitude). For example, such a decrease reduced the precipitation over Amazonia by 1 to 2 mm day1.The inclusion of a canopy scheme in a GCM ensures the combined impacts of roughness (canopies tend to be rougher than bare soil), albedo (canopies tend to be less reflective than bare soil), and soil-moisture availability (canopies prevent the near-surface soil region from drying out and can access the deep soil moisture) upon the simulated climate. The most revealing studies to date involve the regional impact of Amazonian deforestation. The results of four such studies show that replacing tropical forest with a degraded pasture results in decreased evaporation ( 1 mm day1) and precipitation (1-2 mm day1), and increased near-surface air temperatures (2 K).Sensitivity studies as a whole suggest the need for a realistic surface representation in general circulation models of the atmosphere. It is not yet clear how detailed this representation needs to be, but even allowing for the importance of surface processes, the parameterization of boundary-layer and convective clouds probably represents a greater challenge to improved climate simulations. This is illustrated in the case of surface net radiation for Aniazonia, which is not well simulated and tends to be overestimated, leading to evaporation rates that are too large. Underestimates in cloudiness, cloud albedo, and clear-sky shortwave absorption, rather than in surface albedo, appear to be the main culprits.There are three major tasks that confront the researcher so far as the development and validation of atmospheric boundary-layer (ABL) and surface schemes in GCMs are concerned:(i) There is a need to as' critically the impact of `improved' parameterization schemes on WM simulations, taking into account the problem of natural variability and hence the statistical significance of the induced changes.(ii) There is a need to compare GCM simulations of surface and ABL behavior (particularly regarding the diurnal cycle of surface fluxes, air temperature, and ABL depth) with observations over a range of surface types (vegetation, desert, ocean). In this context, area-average values of surface fluxes will be required to calibrate directly the ABL/land-surface scheme in the GCM.(iii) There is a need for intercomparisons of ABL and land-surface schemes used in GCMS, both for one- dimensional stand-alone models and for GCMs that incorporate the respective schemes.

Electrospun polyvinylpyrrolidone (PVP)/green tea extract composite nanofiber mats and their antioxidant activities

NASA Astrophysics Data System (ADS)

Pusporini, Pusporini; Edikresnha, Dhewa; Sriyanti, Ida; Suciati, Tri; Miftahul Munir, Muhammad; Khairurrijal, Khairurrijal

2018-05-01

Electrospinning was employed to make PVP (polyvinylpyrrolidone)/GTE (green tea extract) composite nanofiber mats. The electrospun PVP nanofiber mat as well as the PVP/GTE nanofiber mats were uniform. The average fiber diameter of PVP/GTE composite nanofiber mat decreased with increasing the GTE weight fraction (or decreasing the PVP weight fraction) in the PVP/GTE solution because the PVP/GTE solution concentration decreased. Then, the broad FTIR peak representing the stretching vibrations of O–H in hydroxyl groups of phenols and the stretching of N–H in amine groups of the GTE paste shifted to higher wavenumbers in the PVP/GTE composite nanofiber mats. These peak shifts implied that PVP and catechins of GTE in the PVP/GTE composite nanofiber mats had intermolecular interactions via hydrogen bonds between carbonyl groups of PVP and hydroxyl groups of catechins in GTE. Lastly, the antioxidant activity of the PVP/GTE composite nanofiber mat increased with reducing the average fiber diameter because the amount of catechins in the composite nanofiber mat increased with the increase of surface area due to the reduction of the average fiber diameter.

Droplet sliding on inclined superhydrophobic surfaces: the effect of anisotropic contact line

NASA Astrophysics Data System (ADS)

Jiang, Youhua; Cao, Lile; Guo, Zongqi; Choi, Chang-Hwan

2017-11-01

Although the effects of solid structures on droplet retention on superhydrophobic surfaces have been studied extensively, the investigation has been restricted to the sessile droplets on horizontal surfaces where the contact line motions are axisymmetric or isotropic (either advancing or receding). In the droplet retention on inclined surfaces, the contact line motions are asymmetric or anisotropic; the advancing and receding motions coexist. In this study, we investigate the correlation between the droplet boundary pinning and the surface morphology on inclined superhydrophobic surfaces. The evolution of the droplet contact angle and width show contrary behaviors between pillar- and pore-structured surfaces due to the distinctive microscopic contact line motions. Therefore, the visualizations of the contact line motions at different locations of the boundary on inclined superhydrophobic surfaces are performed and the averaged contact line density of the boundary is quantified. The result shows that the droplet retentive force monotonously increase with the increase in contact line density, regardless of the surface morphological types, dimensions, or the direction of contact line motion (advancing, receding, or both). The result indicates that the droplet retentive force on superhydrophobic surfaces is mainly determined by the contact line density, regardless of the isotropy of the contact line.

Formation of diamond nanoparticle thin films by electrophoretic deposition

NASA Astrophysics Data System (ADS)

Goto, Yosuke; Ohishi, Fujio; Tanaka, Kuniaki; Usui, Hiroaki

2016-03-01

Thin films of diamond nanoparticles were prepared by electrophoretic deposition (EPD) using 0.5 wt % dispersions in water, ethanol, and 2-propanol. The film growth rate increased with increasing voltage applied to the electrodes. However, an excessive increase in voltage caused the degradation of film morphology. The optimum voltage was 4 V with an electrode separation of 5 mm. The film growth rate was higher in organic solvents than in water. The deposited film had a smooth surface with an average surface roughness comparable to the size of primary particles of the source material. It is notable that the EPD films had a considerably higher physical stability than spin-coated and cast films. The stability was further improved by thermally annealing the films. IR analysis revealed that the diamond nanoparticles have carboxy and amino groups on their surfaces. It is considered that the stability of the EPD films originate from a chemical reaction between these functional groups.

Water budgets for selected watersheds in the Delaware River basin, eastern Pennsylvania and western New Jersey

USGS Publications Warehouse

Sloto, Ronald A.; Buxton, Debra E.

2005-01-01

This pilot study, done by the U.S. Geological Survey in cooperation with the Delaware River Basin Commission, developed annual water budgets using available data for five watersheds in the Delaware River Basin with different degrees of urbanization and different geological settings. A basin water budget and a water-use budget were developed for each watershed. The basin water budget describes inputs to the watershed (precipitation and imported water), outputs of water from the watershed (streamflow, exported water, leakage, consumed water, and evapotranspiration), and changes in ground-water and surface-water storage. The water-use budget describes water withdrawals in the watershed (ground-water and surface-water withdrawals), discharges of water in the watershed (discharge to surface water and ground water), and movement of water of water into and out of the watershed (imports, exports, and consumed water). The water-budget equations developed for this study can be applied to any watershed in the Delaware River Basin. Data used to develop the water budgets were obtained from available long-term meteorological and hydrological data-collection stations and from water-use data collected by regulatory agencies. In the Coastal Plain watersheds, net ground-water loss from unconfined to confined aquifers was determined by using ground-water-flow-model simulations. Error in the water-budget terms is caused by missing data, poor or incomplete measurements, overestimated or underestimated quantities, measurement or reporting errors, and the use of point measurements, such as precipitation and water levels, to estimate an areal quantity, particularly if the watershed is hydrologically or geologically complex or the data-collection station is outside the watershed. The complexity of the water budgets increases with increasing watershed urbanization and interbasin transfer of water. In the Wissahickon Creek watershed, for example, some ground water is discharged to streams in the watershed, some is exported as wastewater, and some is exported for public supply. In addition, ground water withdrawn outside the watershed is imported for public supply or imported as wastewater for treatment and discharge in the watershed. A GIS analysis was necessary to quantify many of the water-budget components. The 89.9-square mile East Branch Brandywine Creek watershed in Pennsylvania is a rural watershed with reservoir storage that is underlain by fractured rock. Water budgets were developed for 1977-2001. Average annual precipitation, streamflow, and evapotranspiration were 46.89, 21.58, and 25.88 inches, respectively. Some water was imported (average of 0.68 inches) into the watershed for public-water supply and as wastewater for treatment and discharge; these imports resulted in a net gain of water to the watershed. More water was discharged to East Branch Brandywine Creek than was withdrawn from it; the net discharge resulted in an increase in streamflow. Most ground water was withdrawn (average of 0.25 inches) for public-water supply. Surface water was withdrawn (average of 0.58 inches) for public-water and industrial supply. Discharge of water by sewage-treatment plants and industries (average of 1.22 inches) and regulation by Marsh Creek Reservoir caused base flow to appear an average of 7.2 percent higher than it would have been without these additional sources. On average, 67 percent of the difference was caused by sewage-treatment-plant and industrial discharges, and 33 percent was caused by regulation of the Marsh Creek Reservoir. Water imports, withdrawals, and discharges have been increasing as the watershed becomes increasingly urbanized. The 64-square mile Wissahickon Creek watershed in Pennsylvania is an urban watershed underlain by fractured rock. Water budgets were developed for 1987-98. Average annual precipitation, streamflow, and evapotranspiration were 47.23, 22.24, and 23.12 inches, respectively. The watershed is highly u

Electron Scattering at Surfaces of Epitaxial Metal Layers

NASA Astrophysics Data System (ADS)

Chawla, Jasmeet Singh

In the field of electron transport in metal films and wires, the 'size effect' refers to the increase in the resistivity of the films and wires as their critical dimensions (thickness of film, width and height of wires) approach or become less than the electron mean free path lambda, which is, for example, 39 nm for bulk copper at room temperature. This size-effect is currently of great concern to the semiconductor industry because the continued downscaling of feature sizes has already lead to Cu interconnect wires in this size effect regime, with a reported 2.5 times higher resistivity for 40 nm wide Cu wires than for bulk Cu. Silver is a possible alternate material for interconnect wires and titanium nitride is proposed as a gate metal in novel field-effect-transistors. Therefore, it is important to develop an understanding of how the growth, the surface morphology, and the microstructure of ultrathin (few nanometers) Cu, Ag and TiN layers affect their electrical properties. This dissertation aims to advance the scientific knowledge of electron scattering at surfaces (external surfaces and grain boundaries), that are, the primary reasons for the size-effect in metal conductors. The effect of surface and grain boundary scattering on the resistivity of Cu thin films and nanowires is separately quantified using (i) in situ transport measurements on single-crystal, atomically smooth Cu(001) layers, (ii) textured polycrystalline Cu(111) layers and patterned wires with independently varying grain size, thickness and line width, and (iii) in situ grown interfaces including Cu-Ta, Cu-MgO, Cu-vacuum and Cu-oxygen. In addition, the electron surface scattering is also measured in situ for single-crystal Ag(001), (111) twinned epitaxial Ag(001), and single-crystal TiN(001) layers. Cu(001), Ag(001), and TiN(001) layers with a minimum continuous thickness of 4, 3.5 and 1.8 nm, respectively, are grown by ultra-high vacuum magnetron sputter deposition on MgO(001) substrates with and without thin epitaxial TiN(001) wetting layers and are studied for structure, crystalline quality, surface morphology, density and composition by a combination of x-ray diffraction theta-2theta scans, o-rocking curves, pole figures, reciprocal space mapping, Rutherford backscattering, x-ray reflectometry and transmission electron microscopy. The TiN(001) surface suppresses Cu and Ag dewetting, yielding lower defect density, no twinning, and smaller surface roughness than if grown on MgO(001). Textured polycrystalline Cu(111) layers 25-50-nm-thick are deposited on a stack of 7.5-nm-Ta on SiO2/Si(001), and subsequent in situ annealing at 350°C followed by sputter etching in Ar plasma yields Cu layers with independently variable thickness and grain size. Cu nanowires, 75 to 350 nm wide, are fabricated from Cu layers with different average grain size using a subtractive patterning process. In situ electron transport measurements at room temperature in vacuum and at 77 K in liquid nitrogen for single-crystal Cu and Ag layers is consistent with the Fuchs-Sondheimer (FS) model and indicates specular scattering at the metal-vacuum boundary with an average specularity parameter p = 0.8 and 0.6, respectively. In contrast, layers measured ex situ show diffuse surface scattering due to sub-monolayer oxidation. Also, addition of Ta atoms on Cu(001) surface perturbs the smooth interface potential and results in completely diffuse scattering at the Cu-Ta interface, and in turn, a higher resistivity of single-crystal Cu layers. In situ exposure of Cu(001) layers to O2 between 10 -3 and 105 Pa-s results in a sequential increase, decrease and increase of the electrical resistance which is attributed to specular surface scattering for clean Cu(001) and for surfaces with a complete adsorbed monolayer, but diffuse scattering at partial coverage and after chemical oxidation. Electron transport measurements for polycrystalline Cu layers and wires show a 10-15% and 7-9% decrease in resistivity, respectively, when increasing the average lateral grain size by a factor of 1.8. The maximum resistivity decrease that can be achieved by increasing the grain size of polycrystalline Cu layers with an average grain size approximately ˜2.5x the layer thickness is 20-26%.

The Climate Science Special Report: Arctic Changes and their Effect on Alaska and the Rest of the United States

NASA Astrophysics Data System (ADS)

Taylor, P. C.

2017-12-01

Rapid and visible climate change is happening across the Arctic, outpacing global change. Annual average near-surface air temperatures across the Arctic are increasing at more than twice the rate of global average surface temperature. In addition to surface temperature, all components of the Arctic climate system are responding in kind, including sea ice, mountain glaciers and the Greenland Ice sheet, snow cover, and permafrost. Many of these changes with a discernable anthropogenic imprint. While Arctic climate change may seem physically remote to those living in other regions of the planet, Arctic climate change can affect the global climate influencing sea level, the carbon cycle, and potentially atmospheric and oceanic circulation patterns. As an Arctic nation, United States' adaptation, mitigation, and policy decisions depend on projections of future Alaskan and Arctic climate. This chapter of the Climate Science Special Report documents significant scientific progress and knowledge about how the Alaskan and Arctic climate has changed and will continue to change.

Reducing dissolved inorganic nitrogen in surface runoff water from sugarcane production systems.

PubMed

Webster, A J; Bartley, R; Armour, J D; Brodie, J E; Thorburn, P J

2012-01-01

Nitrogen (N) lost from farms, especially as the highly bioavailable dissolved inorganic form, may be damaging Australia's Great Barrier Reef (GBR). As sugarcane is the dominant cropping system in GBR catchments, its N management practises are coming under increasing scrutiny. This study measured dissolved inorganic N lost in surface runoff water and sugarcane productivity over 3 years. The experiment compared the conventional fertiliser N application rate to sugarcane (average 180kg N/ha/year) and a rate based on replacing N exported in the previous crop (average 94kg N/ha/year). Dissolved inorganic N losses in surface water were 72%, 48% and 66% lower in the three monitored years in the reduced N fertiliser treatment. There was no significant difference in sugarcane yield between the two fertiliser N treatments, nor any treatment difference in soil mineral N - both of these results are indicators of the sustainability of the lower fertiliser N applications. Copyright © 2012 Elsevier Ltd. All rights reserved.

A study on tensile deformation at room temperature and 650 °C in the directional solidified Ni-base superalloy GTD-111

NASA Astrophysics Data System (ADS)

Pauzi, AA; Ghaffar, MH Abdul; Chang, SY; Ng, GP; Husin, S.

2017-10-01

GTD-111 DS generally used for gas turbine blades is a high performance Ni-base superalloy. This alloy, with high volume of γ’ phase, has excellent tensile properties at high temperature. The effect of temperature on the tensile deformation of GTD-111 DS was investigated by using tensile test and microstructure evaluation of the fractured specimens. The tensile behaviour of GTD-111 DS was studied in the room temperature (RT) and 650 °C. From the yield strength results, the yield strength decreases from the average of 702.72 MPa to the average of 645.62 MPa with the increase of temperature from RT to 650 °C. The scanning electron microscope (SEM) results on fractured specimens confirmed that the tensile behaviour affected by deformation of the surface at 650 °C compared to fractured surface at RT. Based on the laboratory testing results, the correlation between tensile deformation of fractured surface and yield strength were discussed.

Importance of length and sequence order on magnesium binding to surface-bound oligonucleotides studied by second harmonic generation and atomic force microscopy.

PubMed

Holland, Joseph G; Geiger, Franz M

2012-06-07

The binding of magnesium ions to surface-bound single-stranded oligonucleotides was studied under aqueous conditions using second harmonic generation (SHG) and atomic force microscopy (AFM). The effect of strand length on the number of Mg(II) ions bound and their free binding energy was examined for 5-, 10-, 15-, and 20-mers of adenine and guanine at pH 7, 298 K, and 10 mM NaCl. The binding free energies for adenine and guanine sequences were calculated to be -32.1(4) and -35.6(2) kJ/mol, respectively, and invariant with strand length. Furthermore, the ion density for adenine oligonucleotides did not change as strand length increased, with an average value of 2(1) ions/strand. In sharp contrast, guanine oligonucleotides displayed a linear relationship between strand length and ion density, suggesting that cooperativity is important. This data gives predictive capabilities for mixed strands of various lengths, which we exploit for 20-mers of adenines and guanines. In addition, the role sequence order plays in strands of hetero-oligonucleotides was examined for 5'-A(10)G(10)-3', 5'-(AG)(10)-3', and 5'-G(10)A(10)-3' (here the -3' end is chemically modified to bind to the surface). Although the free energy of binding is the same for these three strands (averaged to be -33.3(4) kJ/mol), the total ion density increases when several guanine residues are close to the 3' end (and thus close to the solid support substrate). To further understand these results, we analyzed the height profiles of the functionalized surfaces with tapping-mode atomic force microscopy (AFM). When comparing the average surface height profiles of the oligonucleotide surfaces pre- and post- Mg(II) binding, a positive correlation was found between ion density and the subsequent height decrease following Mg(II) binding, which we attribute to reductions in Coulomb repulsion and strand collapse once a critical number of Mg(II) ions are bound to the strand.

Validation of a mixture-averaged thermal diffusion model for premixed lean hydrogen flames

NASA Astrophysics Data System (ADS)

Schlup, Jason; Blanquart, Guillaume

2018-03-01

The mixture-averaged thermal diffusion model originally proposed by Chapman and Cowling is validated using multiple flame configurations. Simulations using detailed hydrogen chemistry are done on one-, two-, and three-dimensional flames. The analysis spans flat and stretched, steady and unsteady, and laminar and turbulent flames. Quantitative and qualitative results using the thermal diffusion model compare very well with the more complex multicomponent diffusion model. Comparisons are made using flame speeds, surface areas, species profiles, and chemical source terms. Once validated, this model is applied to three-dimensional laminar and turbulent flames. For these cases, thermal diffusion causes an increase in the propagation speed of the flames as well as increased product chemical source terms in regions of high positive curvature. The results illustrate the necessity for including thermal diffusion, and the accuracy and computational efficiency of the mixture-averaged thermal diffusion model.

Altering surface fluctuations by blending tethered and untethered chains

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, J. K.; Akgun, B.; Jiang, Z.

"Partially tethering" a thin film of a polymer melt by covalently attaching to the substrate a fraction of the chains in an unentangled melt dramatically increases the relaxation time of the surface height fluctuations. This phenomenon is observed even when the film thickness, h, is 20 times the unperturbed chain radius, R g,tethered, of the tethered chains, indicating that partial tethering is more influential than any physical attraction with the substrate. Furthermore, a partially tethered layer of a low average molecular weight of 5k showed much slower surface fluctuations than did a reference layer of pure untethered chains of muchmore » greater molecular weight (48k), so the partial tethering effect is stronger than the effects of entanglement and increase in glass transition temperature, Tg, with molecular weight. Partial tethering offers a means of tailoring these fluctuations which influence wetting, adhesion, and tribology of the surface.« less

Altering surface fluctuations by blending tethered and untethered chains

DOE PAGES

Lee, J. K.; Akgun, B.; Jiang, Z.; ...

2017-10-16

"Partially tethering" a thin film of a polymer melt by covalently attaching to the substrate a fraction of the chains in an unentangled melt dramatically increases the relaxation time of the surface height fluctuations. This phenomenon is observed even when the film thickness, h, is 20 times the unperturbed chain radius, R g,tethered, of the tethered chains, indicating that partial tethering is more influential than any physical attraction with the substrate. Furthermore, a partially tethered layer of a low average molecular weight of 5k showed much slower surface fluctuations than did a reference layer of pure untethered chains of muchmore » greater molecular weight (48k), so the partial tethering effect is stronger than the effects of entanglement and increase in glass transition temperature, Tg, with molecular weight. Partial tethering offers a means of tailoring these fluctuations which influence wetting, adhesion, and tribology of the surface.« less

Method of burning sulfur-containing fuels in a fluidized bed boiler

DOEpatents

Jones, Brian C.

1982-01-01

A method of burning a sulfur-containing fuel in a fluidized bed of sulfur oxide sorbent wherein the overall utilization of sulfur oxide sorbent is increased by comminuting the bed drain solids to a smaller average particle size, preferably on the order of 50 microns, and reinjecting the comminuted bed drain solids into the bed. In comminuting the bed drain solids, particles of spent sulfur sorbent contained therein are fractured thereby exposing unreacted sorbent surface. Upon reinjecting the comminuted bed drain solids into the bed, the newly-exposed unreacted sorbent surface is available for sulfur oxide sorption, thereby increasing overall sorbent utilization.

Surface tension estimation of high temperature melts of the binary alloys Ag-Au

NASA Astrophysics Data System (ADS)

Dogan, Ali; Arslan, Hüseyin

2017-11-01

Surface tension calculation of the binary alloys Ag-Au at the temperature of 1381 K, where Ag and Au have similar electronic structures and their atomic radii are comparable, are carried out in this study using several equations over entire composition range of Au. Apparently, the deviations from ideality of the bulk solutions, such as activities of Ag and Au are small and the maximum excess Gibbs free energy of mixing of the liquid phase is for instance -4500 J/mol at XAu = 0.5. Besides, the results obtained in Ag-Au alloys that at a constant temperature the surface tension increases with increasing composition while the surface tension decreases as the temperature increases for entire composition range of Au. Although data about surface tension of the Ag-Au alloy are limited, it was possible to make a comparison for the calculated results for the surface tension in this study with the available experimental data. Taken together, the average standard error analysis that especially the improved Guggenheim model in the other models gives the best agreement along with the experimental results at temperature 1383 K although almost all models are mutually in agreement with the other one.

Biogeochemical patterns of intermittent streams over space and time as surface flows decrease

NASA Astrophysics Data System (ADS)

MacNeille, R. B.; Lohse, K. A.; Godsey, S.; McCorkle, E. P.; Parsons, S.; Baxter, C.

2016-12-01

Climate change in the western United States is projected to lead to earlier snowmelt, increasing fire risk and potentially transitioning perennial streams to intermittent ones. Differences between perennial and intermittent streams, especially the temporal and spatial patterns of carbon and nutrient dynamics during periods of drying, are understudied. We examined spatial and temporal patterns in surface water biogeochemistry in southwest Idaho and hypothesized that as streams dry, carbon concentrations would increase due to evapoconcentration and/or increased in-stream production. Furthermore, we expected that biogeochemical patterns of streams would become increasingly spatially heterogeneous with drying. Finally, we expected that these patterns would vary in response to fire. To test these hypotheses, we collected water samples every 50 meters from two intermittent streams, one burned and one unburned, in April, May and June, 2016 to determine surface water biogeochemistry. Results showed average concentrations of dissolved inorganic carbon (DIC) and dissolved organic carbon (DOC) increased 3-fold from April to June in the burned site compared to the unburned site where concentrations remained relatively constant. Interestingly, average concentrations of total nitrogen (TN) dropped substantially for the burned site over these three months, but only decreased slightly for the unburned site over the same time period. We also assessed changes in spatial correlation between the burned and unburned site: carbon concentrations were less spatially correlated at the unburned site than at the burned site. Scatterplot matrices of DIC values indicated that at a lag distance of 300 m in April and June, the unburned site had r-values of 0.7416 and 0.5975, respectively, while the burned site had r-values of 0.9468 and 0.8783, respectively. These initial findings support our hypotheses that carbon concentrations and spatial heterogeneity increased over time.

Changes in anthropogenic carbon storage in the Northeast Pacific in the last decade

NASA Astrophysics Data System (ADS)

Chu, Sophie N.; Wang, Zhaohui Aleck; Doney, Scott C.; Lawson, Gareth L.; Hoering, Katherine A.

2016-07-01

In order to understand the ocean's role as a sink for anthropogenic carbon dioxide (CO2), it is important to quantify changes in the amount of anthropogenic CO2 stored in the ocean interior over time. From August to September 2012, an ocean acidification cruise was conducted along a portion of the P17N transect (50°N 150°W to 33.5°N 135°W) in the Northeast Pacific. These measurements are compared with data from the previous occupation of this transect in 2001 to estimate the change in the anthropogenic CO2 inventory in the Northeast Pacific using an extended multiple linear regression (eMLR) approach. Maximum increases in the surface waters were 11 µmol kg-1 over 11 years near 50°N. Here, the penetration depth of anthropogenic CO2 only reached ˜300 m depth, whereas at 33.5°N, penetration depth reached ˜600 m. The average increase of the depth-integrated anthropogenic carbon inventory was 0.41 ± 0.12 mol m-2 yr-1 across the transect. Lower values down to 0.20 mol m-2 yr-1 were observed in the northern part of the transect near 50°N and increased up to 0.55 mol m-2 yr-1 toward 33.5°N. This increase in anthropogenic carbon in the upper ocean resulted in an average pH decrease of 0.002 ± 0.0003 pH units yr-1 and a 1.8 ± 0.4 m yr-1 shoaling rate of the aragonite saturation horizon. An average increase in apparent oxygen utilization of 13.4 ± 15.5 µmol kg-1 centered on isopycnal surface 26.6 kg m-3 from 2001 to 2012 was also observed.

Enhanced electrohydrodynamic force generation in a two-stroke cycle dielectric-barrier-discharge plasma actuator

NASA Astrophysics Data System (ADS)

Sato, Shintaro; Takahashi, Masayuki; Ohnishi, Naofumi

2017-05-01

An approach for electrohydrodynamic (EHD) force production is proposed with a focus on a charge cycle on a dielectric surface. The cycle, consisting of positive-charging and neutralizing strokes, is completely different from the conventional methodology, which involves a negative-charging stroke, in that the dielectric surface charge is constantly positive. The two-stroke charge cycle is realized by applying a DC voltage combined with repetitive pulses. Simulation results indicate that the negative pulse eliminates the surface charge accumulated during constant voltage phase, resulting in repetitive EHD force generation. The time-averaged EHD force increases almost linearly with increasing repetitive pulse frequency and becomes one order of magnitude larger than that driven by the sinusoidal voltage, which has the same peak-to-peak voltage.

Satellite observations of rainfall effect on sea surface salinity in the waters adjacent to Taiwan

NASA Astrophysics Data System (ADS)

Ho, Chung-Ru; Hsu, Po-Chun; Lin, Chen-Chih; Huang, Shih-Jen

2017-10-01

Changes of oceanic salinity are highly related to the variations of evaporation and precipitation. To understand the influence of rainfall on the sea surface salinity (SSS) in the waters adjacent to Taiwan, satellite remote sensing data from the year of 2012 to 2014 are employed in this study. The daily rain rate data obtained from Special Sensor Microwave Imager (SSM/I), Tropical Rainfall Measuring Mission's Microwave Imager (TRMM/TMI), Advanced Microwave Scanning Radiometer (AMSR), and WindSat Polarimetric Radiometer. The SSS data was derived from the measurements of radiometer instruments onboard the Aquarius satellite. The results show the average values of SSS in east of Taiwan, east of Luzon and South China Sea are 33.83 psu, 34.05 psu, and 32.84 psu, respectively, in the condition of daily rain rate higher than 1 mm/hr. In contrast to the rainfall condition, the average values of SSS are 34.07 psu, 34.26 psu, and 33.09 psu in the three areas, respectively at no rain condition (rain rate less than 1 mm/hr). During the cases of heavy rainfall caused by spiral rain bands of typhoon, the SSS is diluted with an average value of -0.78 psu when the average rain rate is higher than 4 mm/hr. However, the SSS was increased after temporarily decreased during the typhoon cases. A possible reason to explain this phenomenon is that the heavy rainfall caused by the spiral rain bands of typhoon may dilute the sea surface water, but the strong winds can uplift the higher salinity of subsurface water to the sea surface.

Impacts of aerosols on seasonal precipitation and snowpack in California based on convection-permitting WRF-Chem simulations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, Longtao; Gu, Yu; Jiang, Jonathan H.

Here, a version of the WRF-Chem model with fully coupled aerosol–meteorology–snowpack is employed to investigate the impacts of various aerosol sources on precipitation and snowpack in California. In particular, the impacts of locally emitted anthropogenic and dust aerosols, and aerosols transported from outside California are studied. We differentiate three pathways of aerosol effects: aerosol–radiation interaction (ARI), aerosol–snow interaction (ASI), and aerosol–cloud interaction (ACI). The convection-permitting model simulations show that precipitation, snow water equivalent (SWE), and surface air temperature averaged over the whole domain (34–42° N, 117–124° W, not including ocean points) are reduced when aerosols are included, therefore reducing largemore » biases in these variables due to the absence of aerosol effects in the model. Aerosols affect California water resources through the warming of mountaintops and the reduction of precipitation; however, different aerosol sources play different roles in changing surface temperature, precipitation, and snowpack in California by means of various weights of the three pathways. ARI by all aerosols mainly cools the surface, leading to slightly increased SWE over the mountains. Locally emitted dust aerosols warm the surface of mountaintops through ASI, in which the reduced snow albedo associated with dusty snow leads to more surface absorption of solar radiation and reduced SWE. Transported aerosols and local anthropogenic aerosols play a dominant role in increasing nonprecipitating clouds but reducing precipitation through ACI, leading to reduced SWE and runoff on the Sierra Nevada, as well as the warming of mountaintops associated with decreased SWE and hence lower surface albedo. The average changes in surface temperature from October 2012 to June 2013 are about –0.19 and 0.22 K for the whole domain and over mountaintops, respectively. Overall, the averaged reduction during October to June is about 7 % for precipitation, 3 % for SWE, and 7 % for surface runoff for the whole domain, while the corresponding numbers are 12, 10, and 10 % for the mountaintops. The reduction in SWE is more significant in a dry year, with 9 % for the whole domain and 16 % for the mountaintops. The maximum reduction of ~20 % in precipitation occurs in May and is associated with the maximum aerosol loading, leading to the largest decrease in SWE and surface runoff over that period. It is also found that dust aerosols can cause early snowmelt on the mountaintops and reduced surface runoff after April.« less

Impacts of aerosols on seasonal precipitation and snowpack in California based on convection-permitting WRF-Chem simulations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, Longtao; Gu, Yu; Jiang, Jonathan H.

A version of the WRF-Chem model with fully coupled aerosol–meteorology–snowpack is employed to investigate the impacts of various aerosol sources on precipitation and snowpack in California. In particular, the impacts of locally emitted anthropogenic and dust aerosols, and aerosols transported from outside California are studied. We differentiate three pathways of aerosol effects: aerosol–radiation interaction (ARI), aerosol–snow interaction (ASI), and aerosol–cloud interaction (ACI). The convection-permitting model simulations show that precipitation, snow water equivalent (SWE), and surface air temperature averaged over the whole domain (34–42° N, 117–124° W, not including ocean points) are reduced when aerosols are included, therefore reducing large biasesmore » in these variables due to the absence of aerosol effects in the model. Aerosols affect California water resources through the warming of mountaintops and the reduction of precipitation; however, different aerosol sources play different roles in changing surface temperature, precipitation, and snowpack in California by means of various weights of the three pathways. ARI by all aerosols mainly cools the surface, leading to slightly increased SWE over the mountains. Locally emitted dust aerosols warm the surface of mountaintops through ASI, in which the reduced snow albedo associated with dusty snow leads to more surface absorption of solar radiation and reduced SWE. Transported aerosols and local anthropogenic aerosols play a dominant role in increasing nonprecipitating clouds but reducing precipitation through ACI, leading to reduced SWE and runoff on the Sierra Nevada, as well as the warming of mountaintops associated with decreased SWE and hence lower surface albedo. The average changes in surface temperature from October 2012 to June 2013 are about -0.19 and 0.22 K for the whole domain and over mountaintops, respectively. Overall, the averaged reduction during October to June is about 7% for precipitation, 3% for SWE, and 7% for surface runoff for the whole domain, while the corresponding numbers are 12, 10, and 10% for the mountaintops. The reduction in SWE is more significant in a dry year, with 9% for the whole domain and 16% for the mountaintops. The maximum reduction of -20% in precipitation occurs in May and is associated with the maximum aerosol loading, leading to the largest decrease in SWE and surface runoff over that period. It is also found that dust aerosols can cause early snowmelt on the mountaintops and reduced surface runoff after April.« less

Impacts of aerosols on seasonal precipitation and snowpack in California based on convection-permitting WRF-Chem simulations

NASA Astrophysics Data System (ADS)

Wu, Longtao; Gu, Yu; Jiang, Jonathan H.; Su, Hui; Yu, Nanpeng; Zhao, Chun; Qian, Yun; Zhao, Bin; Liou, Kuo-Nan; Choi, Yong-Sang

2018-04-01

A version of the WRF-Chem model with fully coupled aerosol-meteorology-snowpack is employed to investigate the impacts of various aerosol sources on precipitation and snowpack in California. In particular, the impacts of locally emitted anthropogenic and dust aerosols, and aerosols transported from outside California are studied. We differentiate three pathways of aerosol effects: aerosol-radiation interaction (ARI), aerosol-snow interaction (ASI), and aerosol-cloud interaction (ACI). The convection-permitting model simulations show that precipitation, snow water equivalent (SWE), and surface air temperature averaged over the whole domain (34-42° N, 117-124° W, not including ocean points) are reduced when aerosols are included, therefore reducing large biases in these variables due to the absence of aerosol effects in the model. Aerosols affect California water resources through the warming of mountaintops and the reduction of precipitation; however, different aerosol sources play different roles in changing surface temperature, precipitation, and snowpack in California by means of various weights of the three pathways. ARI by all aerosols mainly cools the surface, leading to slightly increased SWE over the mountains. Locally emitted dust aerosols warm the surface of mountaintops through ASI, in which the reduced snow albedo associated with dusty snow leads to more surface absorption of solar radiation and reduced SWE. Transported aerosols and local anthropogenic aerosols play a dominant role in increasing nonprecipitating clouds but reducing precipitation through ACI, leading to reduced SWE and runoff on the Sierra Nevada, as well as the warming of mountaintops associated with decreased SWE and hence lower surface albedo. The average changes in surface temperature from October 2012 to June 2013 are about -0.19 and 0.22 K for the whole domain and over mountaintops, respectively. Overall, the averaged reduction during October to June is about 7 % for precipitation, 3 % for SWE, and 7 % for surface runoff for the whole domain, while the corresponding numbers are 12, 10, and 10 % for the mountaintops. The reduction in SWE is more significant in a dry year, with 9 % for the whole domain and 16 % for the mountaintops. The maximum reduction of ˜ 20 % in precipitation occurs in May and is associated with the maximum aerosol loading, leading to the largest decrease in SWE and surface runoff over that period. It is also found that dust aerosols can cause early snowmelt on the mountaintops and reduced surface runoff after April.

Impacts of aerosols on seasonal precipitation and snowpack in California based on convection-permitting WRF-Chem simulations

DOE PAGES

Wu, Longtao; Gu, Yu; Jiang, Jonathan H.; ...

2018-04-23

Here, a version of the WRF-Chem model with fully coupled aerosol–meteorology–snowpack is employed to investigate the impacts of various aerosol sources on precipitation and snowpack in California. In particular, the impacts of locally emitted anthropogenic and dust aerosols, and aerosols transported from outside California are studied. We differentiate three pathways of aerosol effects: aerosol–radiation interaction (ARI), aerosol–snow interaction (ASI), and aerosol–cloud interaction (ACI). The convection-permitting model simulations show that precipitation, snow water equivalent (SWE), and surface air temperature averaged over the whole domain (34–42° N, 117–124° W, not including ocean points) are reduced when aerosols are included, therefore reducing largemore » biases in these variables due to the absence of aerosol effects in the model. Aerosols affect California water resources through the warming of mountaintops and the reduction of precipitation; however, different aerosol sources play different roles in changing surface temperature, precipitation, and snowpack in California by means of various weights of the three pathways. ARI by all aerosols mainly cools the surface, leading to slightly increased SWE over the mountains. Locally emitted dust aerosols warm the surface of mountaintops through ASI, in which the reduced snow albedo associated with dusty snow leads to more surface absorption of solar radiation and reduced SWE. Transported aerosols and local anthropogenic aerosols play a dominant role in increasing nonprecipitating clouds but reducing precipitation through ACI, leading to reduced SWE and runoff on the Sierra Nevada, as well as the warming of mountaintops associated with decreased SWE and hence lower surface albedo. The average changes in surface temperature from October 2012 to June 2013 are about –0.19 and 0.22 K for the whole domain and over mountaintops, respectively. Overall, the averaged reduction during October to June is about 7 % for precipitation, 3 % for SWE, and 7 % for surface runoff for the whole domain, while the corresponding numbers are 12, 10, and 10 % for the mountaintops. The reduction in SWE is more significant in a dry year, with 9 % for the whole domain and 16 % for the mountaintops. The maximum reduction of ~20 % in precipitation occurs in May and is associated with the maximum aerosol loading, leading to the largest decrease in SWE and surface runoff over that period. It is also found that dust aerosols can cause early snowmelt on the mountaintops and reduced surface runoff after April.« less

Tribological properties of fish scale inspired underwater superoleophobic hierarchical structure in aqueous environment

NASA Astrophysics Data System (ADS)

Lian, Zhongxu; Xu, Jinkai; Wan, Yanling; Li, Yiquan; Yu, Zhanjiang; Liu, Qimeng; Yu, Huadong

2017-10-01

Underwater superoleophobic surfaces are becoming increasingly important in regard to self-cleaning, anti-fouling, oil droplet transportation and water/oil separation. Although a great number of underwater superoleophobic surfaces have been demonstrated, their tribological properties remain impractical for the purposes of real-life applications. Herein, a two-step method of high speed wire electrical discharge machining and boiling water treatment was adopted to fabricate fish scale inspired underwater oil repellent hierarchical structure on an aluminum (Al) alloy 5083 surface. The hierarchical roughness and hydroxyl groups were obtained on the surface, and the surface exhibited the ability to prevent contact with organic fluids when submerged in water. Moreover, the tribological properties of underwater superoleophobic Al surfaces in aqueous environments were analyzed. The average friction coefficient of underwater superoleophobic surfaces was decreased compared with the polished Al surface. We believe that this research will contribute to the engineering application of underwater superoleophobic surfaces in the future.

Areal-Averaged Spectral Surface Albedo in an Atlantic Coastal Area: Estimation from Ground-Based Transmission

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kassianov, Evgueni; Barnard, James; Flynn, Connor

Tower-based data combined with high-resolution satellite products have been used to produce surface albedo at various spatial scales over land. Because tower-based albedo data are available at only a few sites, surface albedos using these combined data are spatially limited. Moreover, tower-based albedo data are not representative of highly heterogeneous regions. To produce areal-averaged and spectrally-resolved surface albedo for regions with various degrees of surface heterogeneity, we have developed a transmission-based retrieval and demonstrated its feasibility for relatively homogeneous land surfaces. Here we demonstrate its feasibility for a highly heterogeneous coastal region. We use the atmospheric transmission measured during amore » 19-month period (June 2009 – December 2010) by a ground-based Multi-Filter Rotating Shadowband Radiometer (MFRSR) at five wavelengths (0.415, 0.5, 0.615, 0.673 and 0.87 µm) at the Department of Energy’s Atmospheric Radiation Measurement (ARM) Mobile Facility (AMF) site located on Graciosa Island. We compare the MFRSR-retrieved areal-averaged surface albedo with albedo derived from Moderate Resolution Imaging Spectroradiometer (MODIS) observations, and also a composite-based albedo. Lastly, we demonstrate that these three methods produce similar spectral signatures of surface albedo; however, the MFRSR-retrieved albedo, is higher on average (≤0.04) than the MODIS-based areal-averaged surface albedo and the largest difference occurs in winter.« less

Areal-Averaged Spectral Surface Albedo in an Atlantic Coastal Area: Estimation from Ground-Based Transmission

DOE PAGES

Kassianov, Evgueni; Barnard, James; Flynn, Connor; ...

2017-07-12

Tower-based data combined with high-resolution satellite products have been used to produce surface albedo at various spatial scales over land. Because tower-based albedo data are available at only a few sites, surface albedos using these combined data are spatially limited. Moreover, tower-based albedo data are not representative of highly heterogeneous regions. To produce areal-averaged and spectrally-resolved surface albedo for regions with various degrees of surface heterogeneity, we have developed a transmission-based retrieval and demonstrated its feasibility for relatively homogeneous land surfaces. Here we demonstrate its feasibility for a highly heterogeneous coastal region. We use the atmospheric transmission measured during amore » 19-month period (June 2009 – December 2010) by a ground-based Multi-Filter Rotating Shadowband Radiometer (MFRSR) at five wavelengths (0.415, 0.5, 0.615, 0.673 and 0.87 µm) at the Department of Energy’s Atmospheric Radiation Measurement (ARM) Mobile Facility (AMF) site located on Graciosa Island. We compare the MFRSR-retrieved areal-averaged surface albedo with albedo derived from Moderate Resolution Imaging Spectroradiometer (MODIS) observations, and also a composite-based albedo. Lastly, we demonstrate that these three methods produce similar spectral signatures of surface albedo; however, the MFRSR-retrieved albedo, is higher on average (≤0.04) than the MODIS-based areal-averaged surface albedo and the largest difference occurs in winter.« less

Irrigation as an Historical Climate Forcing

NASA Technical Reports Server (NTRS)

Cook, Benjamin I.; Shukla, Sonali P.; Puma, Michael J.; Nazarenko, Larissa S.

2014-01-01

Irrigation is the single largest anthropogenic water use, a modification of the land surface that significantly affects surface energy budgets, the water cycle, and climate. Irrigation, however, is typically not included in standard historical general circulation model (GCM) simulations along with other anthropogenic and natural forcings. To investigate the importance of irrigation as an anthropogenic climate forcing, we conduct two 5-member ensemble GCM experiments. Both are setup identical to the historical forced (anthropogenic plus natural) scenario used in version 5 of the Coupled Model Intercomparison Project, but in one experiment we also add water to the land surface using a dataset of historically estimated irrigation rates. Irrigation has a negligible effect on the global average radiative balance at the top of the atmosphere, but causes significant cooling of global average surface air temperatures over land and dampens regional warming trends. This cooling is regionally focused and is especially strong in Western North America, the Mediterranean, the Middle East, and Asia. Irrigation enhances cloud cover and precipitation in these same regions, except for summer in parts of Monsoon Asia, where irrigation causes a reduction in monsoon season precipitation. Irrigation cools the surface, reducing upward fluxes of longwave radiation (increasing net longwave), and increases cloud cover, enhancing shortwave reflection (reducing net shortwave). The relative magnitude of these two processes causes regional increases (northern India) or decreases (Central Asia, China) in energy availability at the surface and top of the atmosphere. Despite these changes in net radiation, however, climate responses are due primarily to larger magnitude shifts in the Bowen ratio from sensible to latent heating. Irrigation impacts on temperature, precipitation, and other climate variables are regionally significant, even while other anthropogenic forcings (anthropogenic aerosols, greenhouse gases, etc.) dominate the long term climate evolution in the simulations. To better constrain the magnitude and uncertainties of irrigation-forced climate anomalies, irrigation should therefore be considered as another important anthropogenic climate forcing in the next generation of historical climate simulations and multimodel assessments.

The effect of welding parameters on surface quality of AA6351 aluminium alloy

NASA Astrophysics Data System (ADS)

Yacob, S.; MAli, M. A.; Ahsan, Q.; Ariffin, N.; Ali, R.; Arshad, A.; Wahab, M. I. A.; Ismail, S. A.; Roji, NS M.; Din, W. B. W.; Zakaria, M. H.; Abdullah, A.; Yusof, M. I.; Kamarulzaman, K. Z.; Mahyuddin, A.; Hamzah, M. N.; Roslan, R.

2015-12-01

In the present work, the effects of gas metal arc welding-cold metal transfer (GMAW-CMT) parameters on surface roughness are experimentally assessed. The purpose of this study is to develop a better understanding of the effects of welding speed, material thickness and contact tip to work distance on the surface roughness. Experiments are conducted using single pass gas metal arc welding-cold metal transfer (GMAW-CMT) welding technique to join the material. The material used in this experiment was AA6351 aluminum alloy with the thickness of 5mm and 6mm. A Mahr Marsuft XR 20 machine was used to measure the average roughness (Ra) of AA6351 joints. The main and interaction effect analysis was carried out to identify process parameters that affect the surface roughness. The results show that all the input process parameters affect the surface roughness of AA6351 joints. Additionally, the average roughness (Ra) results also show a decreasing trend with increased of welding speed. It is proven that gas metal arc welding-cold metal transfer (GMAW-CMT)welding process has been successful in term of providing weld joint of good surface quality for AA6351 based on the low value surface roughness condition obtained in this setup. The outcome of this experimental shall be valuable for future fabrication process in order to obtained high good quality weld.

Preparation of enhanced hydrophobic poly(L-lactide-co-ɛ-caprolactone) films surface and its blood compatibility

NASA Astrophysics Data System (ADS)

Kim, Seung Il; Lim, Jin Ik; Jung, Youngmee; Mun, Cho Hay; Kim, Ji Heung; Kim, Soo Hyun

2013-07-01

Hydrophobicity-enhanced poly(L-lactide-co-ɛ-caprolactone) (PLCL) (50:50) films were cast by using the solvent-nonsolvent casting method. PLCL (50:50) was synthesized by the well-known random copolymerization process and confirmed by 1H NMR analysis. The molecular weight of the synthesized PLCL was measured by gel permeation chromatography (GPC). Number-average (Mn), weight-average (Mw) molecular weights and polydispersity (Mw/Mn) were 7 × 104, 1.2 × 105, and 1.7, respectively. PLCL films were cast in vacuum condition with various nonsolvents and nonsolvent ratios. Tetrahydrofuran (THF) was used as the solvent and three different alcohols were used as the nonsolvent: methanol, ethanol, and isopropyl alcohol (IPA). Surface hydrophobicity was confirmed by water contact angle. The water contact angle was increased from 81° ± 2° to 107° ± 2°. Water contact angle was influenced by surface porosity and topography. The prepared film surfaces were characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The change of crystalline property was characterized by X-ray diffraction (XRD). Platelet adhesion tests on the modified PLCL film surfaces were evaluated by platelet-rich plasma (PRP). The modified film surface exhibited enhanced hydrophobicity and reduced platelet adhesion ratio depending on the surface topography. One of the candidate products proposed as a potential blood compatible material showed a markedly reduced platelet adhesion property.

Cosmic rays and other rpace phenomena influenced on the Earth's climate

NASA Astrophysics Data System (ADS)

Lev, Dorman

2016-07-01

We consider effects of cosmic rays (CR) and some other space phenomena on the Earth's climate change. It is well known that the system of internal and external factors formatting the Earth's climate is very unstable: decreasing of planetary average annual temperature leads to an increase of planetary snow surface, and decreasing of the total annual solar energy input into the system decreases the planetary temperature even more. And inverse: increasing planetary temperature leads to an decrease of snow surface, and increasing of the total solar energy input into the system increases the planetary temperature even more. From this follows that even energetically small factors acted long time in one direction may have a big influence on climate change. In our opinion, the most important of these factors are CR (mostly through its influence on planetary cloudiness) and space dust (SD) through their influence on the flux of solar irradiation and on formation of clouds (these actions are in one direction). It is important that CR and SD influenced on global climate change in the same direction. Increasing of CR planetary intensity leads to increasing of formation clouds (especially low clouds on altitudes smaller than 3 km), increasing annual average of raining and decreasing of annual average planetary temperature. Increasing of SD decreases of solar irradiation and increases cloudiness what leads also to decreasing of annual average planetary temperature. Moreover, interactions of CR particles with dust granules decreases their dimensions what increased effectiveness of their actions on clouds. We consider data great variations of planetary temperature much before the beginning of the Earth's technological civilization (mostly caused by moving of the solar system around our Galaxy centre and collisions with molecular-dust clouds). We consider in details not only situation during the last hundred years, but also situation in the last one thousand years (and especially situation during Maunder minimum of solar activity), during many thousand and many millions years. It is shown that very big changes in climate were caused also by some rarely phenomena as impacts of asteroids and nearby supernova explosions with great influence on biosphere. We discuss also the problem on forecasting of global climate change what is especially important for saving present civilization from great climate catastrophes.

Influence of Surface Roughness on Strong Light-Matter Interaction of a Quantum Emitter-Metallic Nanoparticle System.

PubMed

Lu, Yu-Wei; Li, Ling-Yan; Liu, Jing-Feng

2018-05-08

We investigate the quantum optical properties of strong light-matter interaction between a quantum emitter and a metallic nanoparticle beyond idealized structures with a smooth surface. Based on the local coupling strength and macroscopic Green's function, we derived an exact quantum optics approach to obtain the field enhancement and light-emission spectrum of a quantum emitter. Numerical simulations show that the surface roughness has a greater effect on the near-field than on the far-field, and slightly increases the vacuum Rabi splitting on average. Further, we verified that the near-field enhancement is mainly determined by the surface features of hot-spot area.

Effects of El Niño on summertime ozone air quality in the eastern United States

NASA Astrophysics Data System (ADS)

Shen, L.; Mickley, L. J.

2017-12-01

We investigate the effect of El Nino on maximum daily 8-hour average (MDA8) surface ozone over the eastern United States in summer (June-August, JJA) from 1980 to 2016. El Nino can influence the extra-tropical climate through the propagation of stationary waves, leading to (1) a low-pressure anomaly in the western Atlantic, which reduces transport of moist, clean air from the ocean into the mid- and southern Atlantic states, and (2) intensified southerly flow in the South Central states, which conversely enhances flux of moist, clean air into this region. El Nino can also trigger greater subsidence, reduced precipitation, and increased surface solar radiation in the mid- and southern Atlantic States. As a result, every standard deviation increase in the Nino 1+2 index is associated with an increase of 1-2 ppbv ozone in the Atlantic States and a decrease of 0.5-2 ppbv ozone in the South Central states. On average, models participating in the Atmospheric Model Intercomparison Project have difficulties capturing the El Nino influence on summertime weather in the eastern United States, implying that the freely running chemistry-climate models also cannot simulate the ozone variability related to El Nino.

Nutrient transport in surface runoff and interflow from an aspen-birch forest

Treesearch

D.R. Timmons; E.S. Verry; R.E. Burwell; R.F. Holt

1977-01-01

Nutrients transported in surface runoff and interflow from an undisturbed aspen-birch (Populus tremuloides Michx., and Betula papyrifera Marsh.) forest (6.48 ha) in northern Minnesota were measured for 3 years. Surface runoff from snowmelt accounted for 97% of the average annual surface runoff and for 57% of the average annual...

Surface Fatigue Lives of Case-Carburized Gears With an Improved Surface Finish

NASA Technical Reports Server (NTRS)

Krantz, T. L.; Alanou, M. P.; Evans, H. P.; Snidle, R. W.; Krantz, T. L. (Technical Monitor)

2000-01-01

Previous research provides qualitative evidence that an improved surface finish can increase the surface fatigue lives of gears. To quantify the influence of surface roughness on life, a set of AISI 93 10 steel gears was provided with a nearmirror finish by superfinishing. The effects of the superfinishing on the quality of the gear tooth surfaces were determined using data from metrology, profilometry, and interferometric microscope inspections. The superfinishing reduced the roughness average by about a factor of 5. The superfinished gears were subjected to surface fatigue testing at 1.71 -GPa (248-ksi) Hertz contact stress, and the data were compared with the NASA Glenn gear fatigue data base. The lives of gears with superfinished teeth were about four times greater compared with the lives of gears with ground teeth but with otherwise similar quality.

Molecular dynamics study of oil adsorption on the rock surface in presence of silica nanoparticles

NASA Astrophysics Data System (ADS)

Salehzadeh, Jamal; Tohidi, Zahra; Jafari, Arezou

2018-01-01

Despite the increasing applications of nanoparticles in enhanced oil recovery (EOR), there is not enough information about the mechanisms and microscopic aspects of nanoparticles' effects. Therefore, in this research, molecular dynamics simulation is used to provide the molecular-scale insight for investigation of the silica nanoparticles effects on the oil adsorption on calcite surface for the first time. The surface interacts with the mixture of heptane and decane as the oil phase with mole ratio of 1/2 and silica nanoparticles are dispersed in distilled water with concentration of 7000 ppm. Based on the simulation results, by using nanoparticles surface adsorption behavior have been changed to hydrophilic and the oil molecules departed from the calcite. This result is based on the oil-calcite binding energy calculation which is decreased from 5224 kcal/mol to 3278 kcal/mol by using silica nanoparticles. In addition, calculation of radial distribution functions showed that after adding silica nanoparticles, the picks fall which means increasing in average distance between oil and calcite surface.

Characterization of water quality and biological communities, Fish Creek, Teton County, Wyoming, 2007-08

USGS Publications Warehouse

Eddy-Miller, Cheryl A.; Peterson, David A.; Wheeler, Jerrod D.; Leemon, Daniel J.

2010-01-01

Fish Creek, a tributary to the Snake River, is about 25 river kilometers long and is located in Teton County in western Wyoming near the town of Wilson. Public concern about nuisance growths of aquatic plants in Fish Creek have been increasing in recent years. To address this concern, the U.S. Geological Survey conducted a study in cooperation with the Teton Conservation District to characterize the water quality and biological communities in Fish Creek. Water-quality samples were collected for analyses of physical properties and water chemistry (nutrients, nitrate isotopes, and wastewater chemicals) between March 2007 and October 2008 from seven surface-water sites and three groundwater wells. During this same period, aquatic plant and macroinvertebrate samples were collected and habitat characteristics were measured at the surface-water sites. The main objectives of this study were to (1) evaluate nutrient concentrations (that influence biological indicators of eutrophication) and potential sources of nutrients by using stable isotope analysis and other indicator chemicals (such as caffeine and disinfectants) that could provide evidence of anthropogenic sources, such as wastewater or septic tank contamination in Fish Creek and adjacent groundwater, and (2) characterize the algal, macrophyte, and macroinvertebrate communities and habitat of Fish Creek. Nitrate was the dominant species of dissolved nitrogen present in all samples and was the only bioavailable species detected at concentrations greater than the laboratory reporting level in all surface-water samples. Average concentrations of dissolved nitrate in surface water were largest in samples collected from the two sites with seasonal flow near Teton Village and decreased downstream; the smallest concentration was at downstream site A-Wck. Concentrations of dissolved nitrate in groundwater were consistently greater than concentrations in corresponding surface-water sites during the same sampling event. Orthophosphate was the primary dissolved species of phosphorus present in all surface-water and groundwater samples. The average concentration of dissolved orthophosphate in surface water was largest in samples collected from near Teton Village; samples from all other sites had similar average concentrations. Concentrations of dissolved orthophosphate in groundwater also were typically greater than concentrations in corresponding surface-water sites during the same sampling event. The aquatic plant communities in Fish Creek typically were composed of a mixture of macrophytes, macroalgae, microalgae, and moss. The composition of the aquatic plant community in Fish Creek appeared to shift in the downstream direction in 2007. On average, the proportion of macrophytes ranged from about 1 percent at site A-R1U, the most upstream site, to 54 percent of the plant community at site A-R6D, the farthest downstream site sampled during 2007. The downstream increase in macrophytes was accompanied by a downstream decrease in microalgae. The average proportion of microalgae ranged from 80 percent at site A-R1U to 24 percent at site A-R6D. The proportion of the macroalgae Cladophora in the aquatic plant community was relatively high at sites A-Wck and A-R3D in both 2007 and 2008.

[Practice of engineering management and its effect on schistosomiasis control in Hankou marshland, Wuhan City].

PubMed

Zhi-Qing, Deng; Xiao-Dong, Tan; Shi-Bo, Kong; Kai, Wu; Ming-Xing, Xu; Hua-Tang, Luo

2017-01-06

To investigate the Oncomelania hupensis snail control effect of schistosomiasis control engineering in marshland within Wuhan City. The engineering measures including surface barrier removal, molluscicide, flatting surface, topsoil stripping, topsoil covering and ditch renovation were applied to transform Hankou marshland. Then the corresponding technical parameters of engineering measures were put forward. The situation of snails was analyzed before and after the transform project. The total length and area of the project were 6 015 m and 87.21 hm 2 , respectively, including 17.44 hm 2 of topsoil landfill, 52.08 hm 2 of topsoil covering and 23 new ditches. After the transformation, the average length of the new groove, the groove top width, groove depth, height difference, and the average values of slopes and ditch bottom slope were all increased, while the average values of the width and height of the ditch were decreased. At the same time, the marshland beach surface had a new slope that the embankment was higher than the river and no living O. hupensis snails were found then. The snail breeding environment in Hankou marshland has been effectively changed by the project. However, the constant monitoring and engineering management are still needed to consolidate the effect.

Experimental and ecosystem model approach to assessing the sensitivity of High arctic deep permafrost to changes in surface temperature and precipitation

NASA Astrophysics Data System (ADS)

Rasmussen, L. H.; Zhang, W.; Elberling, B.; Cable, S.

2016-12-01

Permafrost affected areas in Greenland are expected to experience large temperature increases within the 21st century. Most previous studies on permafrost consider near-surface soil, where changes will happen first. However, how sensitive the deep permafrost temperature is to near-surface conditions through changes in soil thermal properties, snow depth and soil moisture, is not known. In this study, we measured the sensitivity of thermal conductivity (TC) to gravimetric water content (GWC) in frozen and thawed deep permafrost sediments from deltaic, alluvial and fluvial depositional environments in the Zackenberg valley, NE Greenland. We also calibrated a coupled heat and water transfer model, the "CoupModel", for the two closely situated deltaic sites, one with average snow depth and the other with topographic snow accumulation. With the calibrated model, we simulated deep permafrost thermal dynamics in four scenarios with changes in surface forcing: a. 3 °C warming and 20 % increase in precipitation; b. 3 °C warming and 100 % increase in precipitation; c. 6 °C warming and 20 % increase in precipitation; d. 6 °C warming and 100 % increase in precipitation.Our results indicated that frozen sediments had higher TC than thawed sediments. All sediments showed a positive linear relation between TC and soil moisture when frozen, and a logarithmic one when thawed. Fluvial sediments had high sensitivity, but never reached above 12 % GWC, indicating a field effect of water retention capacity. Alluvial sediments were less sensitive to soil moisture than deltaic and fluvial sediments, indicating the importance of unfrozen water in frozen sediment. The deltaic site with snow accumulation had 1 °C higher annual mean ground temperature than the average snow site. The soil temperature at the depth of 18 m increased with 1.5 °C and 3.5 °C in the scenarios with 3 °C and 6 °C warming, respectively. Precipitation had no significant additional effect to warming. We conclude that below-ground sediment properties affect the sensitivity of TC to GWC, that surface temperature changes can significantly affect the deep permafrost within a short period, and that differences in snow depth affect surface temperatures. Geology, pedology and precipitation should thus be considered if estimating future High arctic deep permafrost sensitivity.

Juvenile Chinook Salmon abundance in the northern Bering Sea: Implications for future returns and fisheries in the Yukon River

NASA Astrophysics Data System (ADS)

Murphy, James M.; Howard, Kathrine G.; Gann, Jeanette C.; Cieciel, Kristin C.; Templin, William D.; Guthrie, Charles M.

2017-01-01

Juvenile Chinook Salmon (Oncorhynchus tshawytscha) abundance in the northern Bering Sea is used to provide insight into future returns and fisheries in the Yukon River. The status of Yukon River Chinook Salmon is of concern due to recent production declines and subsequent closures of commercial, sport, and personal use fisheries, and severe restrictions on subsistence fisheries in the Yukon River. Surface trawl catch data, mixed layer depth adjustments, and genetic stock mixtures are used to estimate juvenile abundance for the Canadian-origin stock group from the Yukon River. Abundance ranged from a low of 0.62 million in 2012 to a high of 2.58 million in 2013 with an overall average of 1.5 million from 2003 to 2015. Although abundance estimates indicate that average survival is relatively low (average of 5.2%), juvenile abundance was significantly correlated (r=0.87, p=0.005) with adult returns, indicating that much of the variability in survival occurs during early life-history stages (freshwater and initial marine). Juvenile abundance in the northern Bering Sea has increased since 2013 due to an increase in early life-history survival (average juveniles-per-spawner increased from 29 to 59). The increase in juvenile abundance is projected to produce larger runs and increased subsistence fishing opportunities for Chinook Salmon in the Yukon River as early as 2016.

Clouds Aerosols Internal Affaires: Increasing Cloud Fraction and Enhancing the Convection

NASA Technical Reports Server (NTRS)

Koren, Ilan; Kaufman, Yoram; Remer, Lorraine; Rosenfeld, Danny; Rudich, Yinon

2004-01-01

Clouds developing in a polluted environment have more numerous, smaller cloud droplets that can increase the cloud lifetime and liquid water content. Such changes in the cloud droplet properties may suppress low precipitation allowing development of a stronger convection and higher freezing level. Delaying the washout of the cloud water (and aerosol), and the stronger convection will result in higher clouds with longer life time and larger anvils. We show these effects by using large statistics of the new, 1km resolution data from MODIS on the Terra satellite. We isolate the aerosol effects from meteorology by regression and showing that aerosol microphysical effects increases cloud fraction by average of 30 presents for all cloud types and increases convective cloud top pressure by average of 35mb. We analyze the aerosol cloud interaction separately for high pressure trade wind cloud systems and separately for deep convective cloud systems. The resultant aerosol radiative effect on climate for the high pressure cloud system is: -10 to -13 W/sq m at the top of the atmosphere (TOA) and -11 to -14 W/sq m at the surface. For deeper convective clouds the forcing is: -4 to -5 W/sq m at the TOA and -6 to -7 W/sq m at the surface.

Optical and morphological properties of sol gel derived titanium dioxide films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sharma, A. B.; Sharma, S. K.; M, Vishwas

2015-08-28

Titanium oxide (Titania) thin films were synthesized on different substrates via the sol-gel dip-coating method using alkoxide solution. Some selected samples were also prepared with different percentage of Lead (Pb). The influence of Pb addition in precursor sol on the optical properties of titanium dioxide thin films was studied. The optical transmittance in the visible region has increased with increase in weight percentage of lead. The refractive index was slightly decreased with Pb addition. Crystallization of these coatings was achieved through thermal annealing at temperatures above 400 °C. The structural properties and surface morphology of the crystallized coatings were studiedmore » by Scanning Electron Microscopy. Increase in average grain size from 250 nm to 350 nm with increase in Pb concentration is observed. Films were appeared to more coarse with increase in Pb addition. An increase in Pb addition resulted increase in average roughness from 12 nm to 25 nm.« less

[Evolution pattern of impervious surface in the Yuqiao Reservoir Watershed, Tianjin, China during the process of urbanization.

PubMed

Xie, Hui Jun; Li, Chong Wei; Zhang, Ya Juan; Song, Ai Yun

2016-04-22

Imperviousness in watershed is a key index to measure urbanization status which exerts an important impact on both eco-hydrological process and spatio-temporal pattern. Taking Yuqiao Reservoir Watershed as a case study area, based on the ENVI 5.1 software, the basic impervious surface information was extracted from remote sensing images taken in 1984, 1994, 2004 and 2013. The linear spectral mixture analysis (LSMA) model was applied to extract the impervious surface area (ISA) in nine coverage classes of watershed in order to analyze its spatio-temporal varying trend in terms of the landscape pattern metrics. Results showed that the RMSE and IS pixel accuracy of all samples were 0.005 and 85.4% respectively, which indicated that the method of extracting impervious surface on a basin scale was feasible. The average of ISA showed a linear growth, from 0.16 to 0.23, the impervious surface area increased by 4.9% in the whole watershed, and the total impervious surface area increased by 1 time. In the sub-basin road network, the impervious surface area increased gradually with the density of the road network, and its expansion pattern was of infilling growth. The patch shape of the middle coverage degree was irregular, and its fragmentation degree was the highest. The fragmentation degree and diversity of the landscape in the whole river basin increased year by year due to increasing human disturbance.

Electronic cigarettes are a source of thirdhand exposure to nicotine.

PubMed

Goniewicz, Maciej L; Lee, Lily

2015-02-01

Substances remaining on the surfaces in areas where people have smoked contribute to thirdhand exposure. Nicotine from tobacco smoke has been shown to react with oxidizing chemicals in the air to form secondary pollutants, such as carcinogenic nitrosamines. While previous studies have demonstrated thirdhand exposure to nicotine from tobacco smoke, none have investigated whether nicotine from electronic cigarettes (e-cigarettes) can also be deposited on various surfaces. Three brands of e-cigarettes were refilled with varying nicotine concentrations. We released 100 puffs from each product directly into an exposure chamber. Surface wipe samples were taken from 5 indoor 100 cm(2) surfaces (window, walls, floor, wood, and metal) pre- and post-release of vapors. Nicotine was extracted from the wipes and was analyzed using gas chromatography. Three of the 4 experiments showed significant increases in the amount of nicotine on all five surfaces. The floor and glass windows had the greatest increases in nicotine, on average by a factor of 47 and 6, respectively (p < .05). The average amount of nicotine deposited on a floor during each experiment was 205 μg/m(2) and varied from limit of quantitation to 550 μg/m(2). This study indicates that there is a risk for thirdhand exposure to nicotine from e-cigarettes. Thirdhand exposure levels differ depending on the surface and the e-cigarette brand. Future research should explore the potential risks of thirdhand exposure to carcinogens formed from the nicotine that is released from e-cigarettes. © The Author 2014. Published by Oxford University Press on behalf of the Society for Research on Nicotine and Tobacco. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

The Carbon Cycle Response to Two El Nino Types: Observational Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chylek, Petr; Tans, Pieter; Christy, John

Here, we analyze monthly tropical near surface air temperature and Mauna Loa Observatory carbon dioxide (CO 2) data within 1960-2016 to identify different carbon cycle responses for two El Nino types: El Ninos originating in the central tropical Pacific (CP El Nino) and El Ninos originating in the eastern tropical Pacific (EP El Nino). We find significant differences between the two types of El Nino events with respect to time delay of the CO 2 rise rate that follows the increase in tropical near surface air temperatures caused by El Nino events. The average time lag of the CP Elmore » Nino is 4.0±1.7 months, while the mean time lag of EP El Nino is found to be 8.5±2.3 months. The average lag of all considered 1960-2016 El Ninos is 5.2±2.7 months. In contrast the sensitivity of CO2 growth rate to tropical near surface air temperature increase is determined to be about the same for both El Nino types equal to 2.8±0.9 ppmyr -1K -1 (or 5.9±1.9 GtCyr -1K -1). Our results should be useful for the understanding of the carbon cycle and constraining it in climate models.« less

Satellite chlorophyll off the British Columbia Coast, 1997-2010

NASA Astrophysics Data System (ADS)

Jackson, Jennifer M.; Thomson, Richard E.; Brown, Leslie N.; Willis, Peter G.; Borstad, Gary A.

2015-07-01

We examine the spatial and temporal variability of satellite-sensed sea surface chlorophyll off the west coast of North America from 1997 to 2010, with focus on coastal British Columbia. The variability in surface chlorophyll is complex. Whereas the spring bloom generates the highest phytoplankton concentration for coastal Alaska, the north and east coasts of Haida Gwaii, Queen Charlotte Sound, the Strait of Georgia, and coastal Oregon and California, it is the fall bloom that normally generates the highest concentration for the west coast of Vancouver Island, Juan de Fuca Strait, and the west coast of Washington. The highest satellite-sensed chlorophyll concentrations occur in the Strait of Georgia, where mean values are at least 2 times higher than elsewhere in the northeast Pacific. Moreover, the annual average surface chlorophyll concentration increased significantly in the Strait of Georgia during this period, with highest concentration observed during the near neutral ENSO conditions of the spring of 2007. The next highest concentrations occur off southwest Vancouver Island but have no statistically significant trend. The lowest average peak chlorophyll concentration is observed off Southern California. The timing of the highest chlorophyll concentration is latest off the coast of Washington and earliest off the coast of Southern California. Small increasing concentration trends are observed off the Washington and California coasts.

The Carbon Cycle Response to Two El Nino Types: Observational Study

DOE PAGES

Chylek, Petr; Tans, Pieter; Christy, John; ...

2017-11-22

Here, we analyze monthly tropical near surface air temperature and Mauna Loa Observatory carbon dioxide (CO 2) data within 1960-2016 to identify different carbon cycle responses for two El Nino types: El Ninos originating in the central tropical Pacific (CP El Nino) and El Ninos originating in the eastern tropical Pacific (EP El Nino). We find significant differences between the two types of El Nino events with respect to time delay of the CO 2 rise rate that follows the increase in tropical near surface air temperatures caused by El Nino events. The average time lag of the CP Elmore » Nino is 4.0±1.7 months, while the mean time lag of EP El Nino is found to be 8.5±2.3 months. The average lag of all considered 1960-2016 El Ninos is 5.2±2.7 months. In contrast the sensitivity of CO2 growth rate to tropical near surface air temperature increase is determined to be about the same for both El Nino types equal to 2.8±0.9 ppmyr -1K -1 (or 5.9±1.9 GtCyr -1K -1). Our results should be useful for the understanding of the carbon cycle and constraining it in climate models.« less

SOLINS- SOLAR INSOLATION MODEL FOR COMPUTING AVAILABLE SOLAR ENERGY TO A SURFACE OF ARBITRARY ORIENTATION

NASA Technical Reports Server (NTRS)

Smith, J. H.

1994-01-01

This computer program, SOLINS, was developed to aid engineers and solar system designers in the accurate modeling of the average hourly solar insolation on a surface of arbitrary orientation. The program can be used to study insolation problems specific to residential and commercial applications where the amount of space available for solar collectors is limited by shadowing problems, energy output requirements, and costs. For tandem rack arrays, SOLINS will accommodate the use of augmentation reflectors built into the support structure to increase insolation values at the collector surface. As the use of flat plate solar collectors becomes more prevalent in the building industry, the engineer and designer must have the capability to conduct extensive sensitivity analyses on the orientation and location of solar collectors. SOLINS should prove to be a valuable aid in this area of engineering. SOLINS uses a modified version of the National Bureau of Standards model to calculate the direct, diffuse, and reflected components of total insolation on a tilted surface with a given azimuthal orientation. The model is based on the work of Liu and Jordan with corrections by Kusuda and Ishii to account for early morning and late afternoon errors. The model uses a parametric description of the average day solar climate to generate monthly average day profiles by hour of the insolation level on the collector surface. The model includes accommodation of user specified ground and landscape reflectivities at the collector site. For roof or ground mounted, tilted arrays, SOLINS will calculate insolation including the effects of shadowing and augmentation reflectors. The user provides SOLINS with data describing the array design, array orientation, the month, the solar climate parameter, the ground reflectance, and printout control specifications. For the specified array and environmental conditions, SOLINS outputs the hourly insolation the array will receive during an average day during the month specified, along with the total insolation the collector surface will receive over an average 24-hour period. This program is written in FORTRAN IV for batch execution and has been implemented on an IBM 370 computer with a central memory requirement of approximately 46K of 8 bit bytes. The SOLINS routines were developed in 1979.

Remote Sensing of the Urban Heat Island Effect Across Biomes in the Continental USA

NASA Technical Reports Server (NTRS)

Imhoff, Marc L.; Zhang, Ping; Wolfe, Robert E.; Bounoua, Lahouari

2010-01-01

Impervious surface area (ISA) from the Landsat TM-based NLCD 2001 dataset and land surface temperature (LST) from MODIS averaged over three annual cycles (2003-2005) are used in a spatial analysis to assess the urban heat island (UHI) skin temperature amplitude and its relationship to development intensity, size, and ecological setting for 38 of the most populous cities in the continental United States. Development intensity zones based on %ISA are defined for each urban area emanating outward from the urban core to the nonurban rural areas nearby and used to stratify sampling for land surface temperatures and NDVI. Sampling is further constrained by biome and elevation to insure objective intercomparisons between zones and between cities in different biomes permitting the definition of hierarchically ordered zones that are consistent across urban areas in different ecological setting and across scales. We find that ecological context significantly influences the amplitude of summer daytime UHI (urban-rural temperature difference) the largest (8 C average) observed for cities built in biomes dominated by temperate broadleaf and mixed forest. For all cities combined, ISA is the primary driver for increase in temperature explaining 70% of the total variance in LST. On a yearly average, urban areas are substantially warmer than the non-urban fringe by 2.9 C, except for urban areas in biomes with arid and semiarid climates. The average amplitude of the UHI is remarkably asymmetric with a 4.3 C temperature difference in summer and only 1.3 C in winter. In desert environments, the LST's response to ISA presents an uncharacteristic "U-shaped" horizontal gradient decreasing from the urban core to the outskirts of the city and then increasing again in the suburban to the rural zones. UHI's calculated for these cities point to a possible heat sink effect. These observational results show that the urban heat island amplitude both increases with city size and is seasonally asymmetric for a large number of cities across most biomes. The implications are that for urban areas developed within forested ecosystems the summertime UHI can be quite high relative to the wintertime UHI suggesting that the residential energy consumption required for summer cooling is likely to increase with urban growth within those biomes.

Pyrite Stability Under Venus Surface Conditions

NASA Astrophysics Data System (ADS)

Kohler, E.; Craig, P.; Port, S.; Chevrier, V.; Johnson, N.

2015-12-01

Radar mapping of the surface of Venus shows areas of high reflectivity in the Venusian highlands, increasing to 0.35 ± 0.04 to 0.43 ± 0.05 in the highlands from the planetary average of 0.14 ± 0.03. Iron sulfides, specifically pyrite (FeS2), can explain the observed high reflectivity. However, several studies suggest that pyrite is not stable under Venusian conditions and is destroyed on geologic timescales. To test the stability of pyrite on the Venusian surface, pyrite was heated in the Venus simulation chamber at NASA Goddard Space Flight Center to average Venusian surface conditions, and separately to highland conditions under an atmosphere of pure CO2 and separately under an atmosphere of 96.5% CO2, 3.5% N2 and 150 ppm SO2. After each run, the samples were weighed and analyzed using X-Ray Diffraction (XRD) to identify possible phase changes and determine the stability of pyrite under Venusian surface conditions. Under a pure CO2 atmosphere, the Fe in pyrite oxidizes to form hematite which is more stable at higher temperatures corresponding to the Venusian lowlands. Magnetite is the primary iron oxide that forms at lower temperatures corresponding to the radar-bright highlands. Our experiments also showed that the presence of atmospheric SO2 inhibits the oxidation of pyrite, increasing its stability under Venusian conditions, especially those corresponding to the highlands. This indicates that the relatively high level of SO2 in the Venusian atmosphere is key to the stability of pyrite, making it a possible candidate for the bright radar signal in the Venusian highlands.

Estimation of the average exchanges in momentum and latent heat between the atmosphere and the oceans with Seasat observations

NASA Technical Reports Server (NTRS)

Liu, W. T.

1983-01-01

Ocean-surface momentum flux and latent heat flux are determined from Seasat-A data from 1978 and compared with ship observations. Momentum flux was measured using the Seasat-A scatterometer system (SASS) heat flux, with the scanning multichannel MW radiometer (SMMR). Ship measurements were quality selected and averaged to increase their reliability. The fluxes were computed using a bulk parameterization technique. It is found that although SASS effectively measures momentum flux, variations in atmospheric stability and sea-surface temperature cause deviations which are not accounted for by the present data-processing algorithm. The SMMR-latent-heat-flux algorithm, while needing refinement, is shown to given estimations to within 35 W/sq m in its present form, which removes systematic error and uses an empirically determined transfer coefficient.

Formation of grafted surface layers on silicon dioxide particles and their investigation by means of thermoprogrammed oxidation

NASA Astrophysics Data System (ADS)

Aleksandrova, E. O.; Novichkov, R. V.; Olenin, A. Yu.; Zuev, B. K.

2017-03-01

Silica nanoparticles are obtained according to the Stober-Fink-Bohn method, and their surfaces are chemically modified with 1H,1H,2H,2H-perfluorodecyltriethoxysilane. It is estimated that sols of porous silica nanoparticles (average sizes, 50-200 nm) form during primary chemical process; the average size of the particles can be increased to 400-500 nm by consecutive growth. Oxythermography (thermoprogrammed oxidation) measurements reveal a stepped dependence between the content of organic substance of nanoparticles and the duration of chemical modification reaction exists. It is concluded that this could be due to the formation of dense shell (or shells) as a result of sols aging between the cycles of growth; such shells impose diffusive restrictions when molecules penetrate into the pores of the internal volume of the particles.

Average focal length and power of a section of any defined surface.

PubMed

Kaye, Stephen B

2010-04-01

To provide a method to allow calculation of the average focal length and power of a lens through a specified meridian of any defined surface, not limited to the paraxial approximations. University of Liverpool, Liverpool, United Kingdom. Functions were derived to model back-vertex focal length and representative power through a meridian containing any defined surface. Average back-vertex focal length was based on the definition of the average of a function, using the angle of incidence as an independent variable. Univariate functions allowed determination of average focal length and power through a section of any defined or topographically measured surface of a known refractive index. These functions incorporated aberrations confined to the section. The proposed method closely approximates the average focal length, and by inference power, of a section (meridian) of a surface to a single or scalar value. It is not dependent on the paraxial and other nonconstant approximations and includes aberrations confined to that meridian. A generalization of this method to include all orthogonal and oblique meridians is needed before a comparison with measured wavefront values can be made. Copyright (c) 2010 ASCRS and ESCRS. Published by Elsevier Inc. All rights reserved.

Natural convection of Al2O3-water nanofluid in a wavy enclosure

NASA Astrophysics Data System (ADS)

Leonard, Mitchell; Mozumder, Aloke K.; Mahmud, Shohel; Das, Prodip K.

2017-06-01

Natural convection heat transfer and fluid flow inside enclosures filled with fluids, such as air, water or oil, have been extensively analysed for thermal enhancement and optimisation due to their applications in many engineering problems, including solar collectors, electronic cooling, lubrication technologies, food processing and nuclear reactors. In comparison, little effort has been given to the problem of natural convection inside enclosures filled with nanofluids, while the addition of nanoparticles into a fluid base to alter thermal properties can be a feasible solution for many heat transfer problems. In this study, the problem of natural convection heat transfer and fluid flow inside a wavy enclosure filled with Al2O3-water nanofluid is investigated numerically using ANSYS-FLUENT. The effects of surface waviness and aspect ratio of the wavy enclosure on the heat transfer and fluid flow are analysed for various concentrations of Al2O3 nanoparticles in water. Flow fields and temperature fields are investigated and heat transfer rate is examined for different values of Rayleigh number. Results show that heat transfer within the enclosure can be enhanced by increasing surface waviness, aspect ratio or nanoparticles volume fraction. Changes in surface waviness have little effect on the heat transfer rate at low Rayleigh numbers, but when Ra ≥ 105 heat transfer increases with the increase of surface waviness from zero to higher values. Increasing the aspect ratio causes an increase in heat transfer rate, as the Rayleigh number increases the effect of changing aspect ratio is more apparent with the greatest heat transfer enhancement seen at higher Rayleigh numbers. Nanoparticles volume fraction has a little effect on the average Nusselt number at lower Rayleigh numbers when Ra ≥ 105 average Nusselt number increases with the increase of volume fraction. These findings provide insight into the heat transfer effects of using Al2O3-water nanofluid as a heat transfer medium and the effects of changing geometrical parameters, which will help in developing novel geometries with enhanced and controlled heat-transfer for solar collectors, electronic cooling, and food processing industries.

Dairy heifer manure management, dietary phosphorus, and soil test P effects on runoff phosphorus.

PubMed

Jokela, William E; Coblentz, Wayne K; Hoffman, Patrick C

2012-01-01

Manure application to cropland can contribute to runoff losses of P and eutrophication of surface waters. We conducted a series of three rainfall simulation experiments to assess the effects of dairy heifer dietary P, manure application method, application rate, and soil test P on runoff P losses from two successive simulated rainfall events. Bedded manure (18-21% solids) from dairy heifers fed diets with or without supplemental P was applied on a silt loam soil packed into 1- by 0.2-m sheet metal pans. Manure was either surface-applied or incorporated (Experiment 1) or surface-applied at two rates (Experiment 2) to supply 26 to 63 kg P ha. Experiment 3 evaluated runoff P from four similar nonmanured soils with average Bray P1-extractable P levels of 11, 29, 51, and 75 mg kg. We measured runoff quantity, total P (TP), dissolved reactive P (DRP), and total and volatile solids in runoff collected for 30 min after runoff initiation from two simulated rain events (70 mm h) 3 or 4 d apart. Manure incorporation reduced TP and DRP concentrations and load by 85 to 90% compared with surface application. Doubling the manure rate increased runoff DRP and TP concentrations an average of 36%. In the same experiment, P diet supplementation increased water-extractable P in manure by 100% and increased runoff DRP concentration threefold. Concentrations of solids, TP, and DRP in runoff from Rain 2 were 25 to 75% lower than from Rain 1 in Experiments 1 and 2. Runoff DRP from nonmanured soils increased quadratically with increasing soil test P. These results show that large reductions in P runoff losses can be achieved by incorporation of manure, avoiding unnecessary diet P supplementation, limiting manure application rate, and managing soils to prevent excessive soil test P levels. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Modeling electrochemical resistance with coal surface properties in a direct carbon fuel cell based on molten carbonate

NASA Astrophysics Data System (ADS)

Eom, Seongyong; Ahn, Seongyool; Kang, Kijoong; Choi, Gyungmin

2017-12-01

In this study, a numerical model of activation and ohmic polarization is modified, taking into account the correlation function between surface properties and inner resistance. To investigate the correlation function, the surface properties of coal are changed by acid treatment, and the correlations between the inner resistance measured by half-cell tests and the surface characteristics are analyzed. A comparison between the model and experimental results demonstrates that the absolute average deviations for each fuel are less than 10%. The numerical results show that the sensitivities of the coal surface properties affecting polarization losses change depending on the operating temperature. The surface oxygen concentrations affect the activation polarization and the sensitivity decreased with increasing temperature. The surface ash of coal is an additional index to be considered along with ohmic polarization and it has the greatest effect on the surface properties at 973 K.

Impact of Surface Type, Wheelchair Weight, and Axle Position on Wheelchair Propulsion by Novice Older Adults

PubMed Central

Cowan, Rachel E.; Nash, Mark S.; Collinger, Jennifer L.; Koontz, Alicia M.; Boninger, Michael L.

2009-01-01

Objective To examine the impact of surface type, wheelchair weight, and rear axle position on older adult propulsion biomechanics. Design Crossover trial. Setting Biomechanics laboratory. Participants Convenience sample of 53 ambulatory older adults with minimal wheelchair experience (65−87y); men = 20, women = 33. Intervention Participants propelled 4 different wheelchair configurations over 4 surfaces; tile, low carpet, high carpet, and an 8% grade ramp (surface, chair order randomized). Chair configurations included: (1) unweighted chair with an anterior axle position, (2) 9.05kg weighted chair with an anterior axle position, (3) unweighted chair with a posterior axle position (Δ0.08m), and (4) 9.05kg weighted chair with a posterior axle position (Δ0.08m). Weight was added to a titanium folding chair, simulating the weight difference between very light and depot wheelchairs. Instrumented wheels measured propulsion kinetics. Main Outcome Measures Average self-selected velocity, push-frequency, stroke length, peak resultant and tangential force. Results Velocity decreased as surface rolling resistance or chair weight increased. Peak resultant and tangential forces increased as chair weight increased, surface resistance increased, and with a posterior axle position. The effect of a posterior axle position was greater on high carpet and the ramp. The effect of weight was constant, but more easily observed on high carpet and ramp. The effects of axle position and weight were independent of one another. Conclusion Increased surface resistance decreases self-selected velocity and increases peak forces. Increased weight decreases self-selected velocity and increases forces. Anterior axle positions decrease forces, more so on high carpet. Effects of weight and axle position are independent. Greatest reductions in peak forces occur in lighter chairs with anterior axle positions. PMID:19577019

Meteorological influence on predicting surface SO2 concentration from satellite remote sensing in Shanghai, China.

PubMed

Xue, Dan; Yin, Jingyuan

2014-05-01

In this study, we explored the potential applications of the Ozone Monitoring Instrument (OMI) satellite sensor in air pollution research. The OMI planetary boundary layer sulfur dioxide (SO2_PBL) column density and daily average surface SO2 concentration of Shanghai from 2004 to 2012 were analyzed. After several consecutive years of increase, the surface SO2 concentration finally declined in 2007. It was higher in winter than in other seasons. The coefficient between daily average surface SO2 concentration and SO2_PBL was only 0.316. But SO2_PBL was found to be a highly significant predictor of the surface SO2 concentration using the simple regression model. Five meteorological factors were considered in this study, among them, temperature, dew point, relative humidity, and wind speed were negatively correlated with surface SO2 concentration, while pressure was positively correlated. Furthermore, it was found that dew point was a more effective predictor than temperature. When these meteorological factors were used in multiple regression, the determination coefficient reached 0.379. The relationship of the surface SO2 concentration and meteorological factors was seasonally dependent. In summer and autumn, the regression model performed better than in spring and winter. The surface SO2 concentration predicting method proposed in this study can be easily adapted for other regions, especially most useful for those having no operational air pollution forecasting services or having sparse ground monitoring networks.

Measuring melittin uptake into hydrogel nanoparticles with near-infrared single nanoparticle surface plasmon resonance microscopy.

PubMed

Cho, Kyunghee; Fasoli, Jennifer B; Yoshimatsu, Keiichi; Shea, Kenneth J; Corn, Robert M

2015-01-01

This paper describes how changes in the refractive index of single hydrogel nanoparticles (HNPs) detected with near-infrared surface plasmon resonance microscopy (SPRM) can be used to monitor the uptake of therapeutic compounds for potential drug delivery applications. As a first example, SPRM is used to measure the specific uptake of the bioactive peptide melittin into N-isopropylacrylamide (NIPAm)-based HNPs. Point diffraction patterns in sequential real-time SPRM differential reflectivity images are counted to create digital adsorption binding curves of single 220 nm HNPs from picomolar nanoparticle solutions onto hydrophobic alkanethiol-modified gold surfaces. For each digital adsorption binding curve, the average single nanoparticle SPRM reflectivity response, ⟨Δ%RNP⟩, was measured. The value of ⟨Δ%RNP⟩ increased linearly from 1.04 ± 0.04 to 2.10 ± 0.10% when the melittin concentration in the HNP solution varied from zero to 2.5 μM. No change in the average HNP size in the presence of melittin is observed with dynamic light scattering measurements, and no increase in ⟨Δ%RNP⟩ is observed in the presence of either FLAG octapeptide or bovine serum albumin. Additional bulk fluorescence measurements of melittin uptake into HNPs are used to estimate that a 1% increase in ⟨Δ%RNP⟩ observed in SPRM corresponds to the incorporation of approximately 65000 molecules into each 220 nm HNP, corresponding to roughly 4% of its volume. The lowest detected amount of melittin loading into the 220 nm HNPs was an increase in ⟨Δ%RNP⟩ of 0.15%, corresponding to the absorption of 10000 molecules.

Effects of ambient conditions on the risk of pressure injuries in bedridden patients-multi-physics modelling of microclimate.

PubMed

Zeevi, Tal; Levy, Ayelet; Brauner, Neima; Gefen, Amit

2018-06-01

Scientific evidence regarding microclimate and its effects on the risk of pressure ulcers (PU) remains sparse. It is known that elevated skin temperatures and moisture may affect metabolic demand as well as the mechanical behaviour of the tissue. In this study, we incorporated these microclimate factors into a novel, 3-dimensional multi-physics coupled model of the human buttocks, which simultaneously determines the biothermal and biomechanical behaviours of the buttocks in supine lying on different support surfaces. We compared 3 simulated thermally controlled mattresses with 2 reference foam mattresses. A tissue damage score was numerically calculated in a relevant volume of the model, and the cooling effect of each 1°C decrease of tissue temperature was deduced. Damage scores of tissues were substantially lower for the non-foam mattresses compared with the foams. The percentage tissue volume at risk within the volume of interest was found to grow exponentially as the average tissue temperature increased. The resultant average sacral skin temperature was concluded to be a good predictor for an increased risk of PU/injuries. Each 1°C increase contributes approximately 14 times as much to the risk with respect to an increase of 1 mmHg of pressure. These findings highlight the advantages of using thermally controlled support surfaces as well as the need to further assess the potential damage that may be caused by uncontrolled microclimate conditions on inadequate support surfaces in at-risk patients. © 2017 Medicalhelplines.com Inc and John Wiley & Sons Ltd.

Design and characterization of textured surfaces for applications in the food industry

NASA Astrophysics Data System (ADS)

Lazzini, G.; Romoli, L.; Blunt, L.; Gemini, L.

2017-12-01

The aim of this work is to design, manufacture and characterize surface morphologies on AISI 316L stainless steel produced by a custom designed laser-texturing strategy. Surface textures were characterized at a micrometric dimension in terms of areal parameters compliant with ISO 25178, and correlations between these parameters and processing parameters (e.g. laser energy dose supplied to the material, repetition rate of the laser pulses and scanning velocity) were investigated. Preliminary efforts were devoted to the research of special requirements for surface morphology that, according to the commonly accepted research on the influence of surface roughness on cellular adhesion on surfaces, should discourage the formation of biofilms. The topographical characterization of the surfaces was performed with a coherence scanning interferometer. This approach showed that increasing doses of energy to the surfaces increased the global level of roughness as well as the surface complexity. Moreover, the behavior of the parameters S pk, S vk also indicates that, due to the ablation process, an increase in the energy dose causes an average increase in the height of the highest peaks and in the depth of the deepest dales. The study of the density of peaks S pd showed that none of the surfaces analyzed here seem to perfectly match the conditions dictated by the theories on cellular adhesion to confer anti-biofouling properties. However, this result seems to be mainly due to the limits of the resolving power of coherence scanning interferometry, which does not allow the resolution of sub-micrometric features which could be crucial in the prevention of cellular attachment.

The importance of particle size in porous titanium and nonporous counterparts for surface energy and its impact on apatite formation.

PubMed

Chen, Xiao-Bo; Li, Yun-Cang; Hodgson, Peter D; Wen, Cuie

2009-07-01

The importance of particle size in titanium (Ti) fabricated by powder metallurgy for the surface energy and its impact on the apatite formation was investigated. Four sorts of Ti powders of different mean particle size were realized through 20min, 2h, 5h and 8h of ball milling, respectively. Each sort of Ti powder was used to fabricate porous Ti and its nonporous counterparts sharing similar surface morphology, grain size and chemical composition, and then alkali-heat treatment was conducted on them. Surface energy was measured on the surfaces of the nonporous Ti counterparts due to the difficulty in measuring the porous surfaces directly. The surface energy increase on the alkali-heat-treated porous and nonporous Ti was observed due to the decrease in the particle size of the Ti powders and the presence of Ti-OH groups brought by the alkali-heat treatment. The apatite-inducing ability of the alkali-heat-treated porous and nonporous Ti with different surface energy values was evaluated in modified simulated body fluid and results indicated that there was a strong correlation between the apatite-inducing ability and the surface energy. The alkali-heat-treated porous and nonporous Ti discs prepared from the powders with an average particle size of 5.89+/-0.76microm possessed the highest surface energy and the best apatite-inducing ability when compared to the samples produced from the powders with the average particle size varying from 19.79+/-0.31 to 10.25+/-0.39microm.

43 CFR 418.36 - Incentives for additional long term conservation.

Code of Federal Regulations, 2014 CFR

2014-10-01

... be reduced by the incremental amount of evaporation which occurs as a result of the increased surface area of the reservoir due to the additional storage. The evaporation rate used will be either the net evaporation measured or the net historical average after precipitation is taken into account. The method of...

43 CFR 418.36 - Incentives for additional long term conservation.

Code of Federal Regulations, 2013 CFR

2013-10-01

... be reduced by the incremental amount of evaporation which occurs as a result of the increased surface area of the reservoir due to the additional storage. The evaporation rate used will be either the net evaporation measured or the net historical average after precipitation is taken into account. The method of...

43 CFR 418.36 - Incentives for additional long term conservation.

Code of Federal Regulations, 2012 CFR

2012-10-01

... be reduced by the incremental amount of evaporation which occurs as a result of the increased surface area of the reservoir due to the additional storage. The evaporation rate used will be either the net evaporation measured or the net historical average after precipitation is taken into account. The method of...

Global Warming: If You Can't Stand the Heat

ERIC Educational Resources Information Center

Baird, Stephen L.

2005-01-01

Global warming is the progressive, gradual rise of the earth's average surface temperature, thought to be caused in part by increased concentrations of "greenhouse" gases (GHGs) in the atmosphere. According to the National Academy of Sciences, the Earth's temperature has risen by about one degree Fahrenheit in the past century, with accelerated…

Utilization of point soil moisture measurements for field scale soil moisture averages and variances in agricultural landscapes

USDA-ARS?s Scientific Manuscript database

Soil moisture is a key variable in understanding the hydrologic processes and energy fluxes at the land surface. In spite of new technologies for in-situ soil moisture measurements and increased availability of remotely sensed soil moisture data, scaling issues between soil moisture observations and...

Changes of the phytoplankton community as symptoms of deterioration of water quality in a shallow lake.

PubMed

Dembowska, Ewa Anna; Mieszczankin, Tomasz; Napiórkowski, Paweł

2018-01-25

Covering more than 60% of the lake surface, macrophytes determined the taxonomic composition of phytoplankton. We have found numerous indications of ecological deterioration and an increased trophic level year to year: an increased total number of taxa; a significantly increased number of species of Chlorophyta, Bacillariophyceae and Cyanoprokaryota; a decreased number of Chrysophyceae; increased Nygaard index, and high diversity and variability of phytoplankton functional groups. Within 2 years (2002 and 2003) algal biomass doubled: from 3.616 to 7.968 mg l -1 . An increased contribution of Chlorococcales and Cyanoprokaryota indicates progressive eutrophication of the lake. The average size of planktonic algae increased, particularly Cyanoprokaryota, where small-celled decreased dramatically and were replaced by large colonies. Cyanoprokaryota remained the dominant group of phytoplankton after 10 years, and the ecosystem of the lake remained in the turbid state. This group of algae had the average biomass 9.734 mg l -1 , which constituted almost 92% of the total biomass.

Heat transfer from high-temperature surfaces to fluids II : correlation of heat-transfer and friction data for air flowing in inconel tube with rounded entrance

NASA Technical Reports Server (NTRS)

Lowdermilk, Warren H; Grele, Milton D

1949-01-01

A heat transfer investigation, which was an extension of a previously reported NACA investigation, was conducted with air flowing through an electrically heated inconel tube with a rounded entrance,an inside diameter of 0.402 inch, and a length of 24 inches over a range of conditions, which included Reynolds numbers up to 500,000, average surface temperatures up to 2050 degrees R, and heat-flux densities up to 150,000 Btu per hour per square foot. Conventional methods of correlating heat-transfer data wherein properties of the air were evaluated at the average bulk, film, and surface temperatures resulted in reductions of Nusselt number of about 38, 46, and 53 percent, respectively, for an increase in surface temperature from 605 degrees to 2050 degrees R at constant Reynolds number. A modified correlation method in which the properties of air were based on the surface temperature and the Reynolds number was modified by substituting the product of the density at the inside tube wall and the bulk velocity for the conventional mass flow per unit cross-sectional area, resulted in a satisfactory correlation of the data for the extended ranges of conditions investigated.

Combined Effects of Deforestation and Doubled Atmospheric CO2 Concentrations on the Climate of Amazonia.

NASA Astrophysics Data System (ADS)

Costa, Marcos Heil; Foley, Jonathan A.

2000-01-01

It is generally expected that the Amazon basin will experience at least two major environmental changes during the next few decades and centuries: 1) increasing areas of forest will be converted to pasture and cropland, and 2) concentrations of atmospheric CO2 will continue to rise. In this study, the authors use the National Center for Atmospheric Research GENESIS atmospheric general circulation model, coupled to the Integrated Biosphere Simulator, to determine the combined effects of large-scale deforestation and increased CO2 concentrations (including both physiological and radiative effects) on Amazonian climate.In these simulations, deforestation decreases basin-average precipitation by 0.73 mm day1 over the basin, as a consequence of the general reduction in vertical motion above the deforested area (although there are some small regions with increased vertical motion). The overall effect of doubled CO2 concentrations in Amazonia is an increase in basin-average precipitation of 0.28 mm day1. The combined effect of deforestation and doubled CO2, including the interactions among the processes, is a decrease in the basin-average precipitation of 0.42 mm day1. While the effects of deforestation and increasing CO2 concentrations on precipitation tend to counteract one another, both processes work to warm the Amazon basin. The effect of deforestation and increasing CO2 concentrations both tend to increase surface temperature, mainly because of decreases in evapotranspiration and the radiative effect of CO2. The combined effect of deforestation and doubled CO2, including the interactions among the processes, increases the basin-average temperature by roughly 3.5°C.

Comparison of high-voltage ac and pulsed operation of a surface dielectric barrier discharge

NASA Astrophysics Data System (ADS)

Williamson, James M.; Trump, Darryl D.; Bletzinger, Peter; Ganguly, Biswa N.

2006-10-01

A surface dielectric barrier discharge (DBD) in atmospheric pressure air was excited either by low frequency (0.3-2 kHz) high-voltage ac or by short, high-voltage pulses at repetition rates from 50 to 600 pulses s-1. The short-pulse excited discharge was more diffuse and did not have the pronounced bright multiple cathode spots observed in the ac excited discharge. The discharge voltage, current and average power deposited into the discharge were calculated for both types of excitation. As a measure of plasma-chemical efficiency, the ozone number density was measured by UV absorption as a function of average deposited power. The density of ozone produced by ac excitation did not increase so rapidly as that produced by short-pulse excitation as a function of average power, with a maximum measured density of ~3 × 1015 cm-3 at 25 W. The maximum ozone production achieved by short-pulse excitation was ~8.5 × 1015 cm-3 at 20 W, which was four times greater than that achieved by ac excitation at the same power level.

Luminescent properties of YVO4:Eu/SiO2 core-shell composite particles

NASA Astrophysics Data System (ADS)

Bao, Amurisana; Lai, Hua; Yang, Yuming; Liu, Zhilong; Tao, Chunyan; Yang, Hua

2010-02-01

We report an efficient process for preparing monodisperse SiO2@Y0.95Eu0.05VO4 core-shell phosphors using a simple citrate sol-gel method and without the use of surface-coupling silane agents or large stabilizers. X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and photoluminescence (PL) spectra were used to characterize the resulting SiO2@Y0.95Eu0.05VO4 core-shell phosphors. The XRD results demonstrate that the Y0.95Eu0.05VO4 particles crystallization on the surface of SiO2 annealing at 800 °C is perfectly and the crystallinity increases with raising the annealing temperature. The obtained core-shell phosphors have a near perfect spherical shape with narrow size distribution (average size ca. 500 nm and an average thickness of 50 nm), are not agglomerated, and have a smooth surface. The thickness of the YVO4:Eu3+ shells on the SiO2 cores could be easily tailored by changing the mass ratio of shell to core ( W = [YVO4]/[SiO2]) ( 50 nm for W = 30%). The Eu3+ shows a strong PL luminescence (dominated by 5D0 - 7F2 red emission at 618 nm) under the excitation of 320 nm UV light. The PL intensity of Eu3+ increases with increasing the annealing temperature and the values of W.

Foraging patterns and prey selection in an increasing and expanding sea otter population

USGS Publications Warehouse

Laidre, K.L.; Jameson, R.J.

2006-01-01

Focal observations of sea otter (Enhydra lutris kenyoni) foraging patterns and prey selection were collected in coastal Washington between 1993 and 1999. Records consisted of 13,847 individual dives from 841 feeding bouts ranging from 1 min to >4 h. Average dive time was 55 s ?? 0.9 SE and average surface time was 45 s ?? 2.3 SE, irrespective of dive success. At least 77% of all dives (n = 10,636) were successful prey captures (dives in low light or of undetermined success were excluded). Prey capture success was significantly lower for subadults (63% ?? 5 SE) than adults (82% ?? 1 SE; P 60% red urchins (Strongylocentrotus franciscanus), with only 2 other prey species comprising >10% of their diet. Prey size and prey category were dominant predictor variables in generalized linear models of dive duration and postdive surface duration on successful dives. Significant increases in areal extent of surface canopy of giant kelp (Macrocystis integrifolia) and bull kelp (Nereocystis leutkeana) were found both in the outer coast and the Strait of Juan de Fuca (0.4-0.5 km2 per year, P < 0.05) and suggest increasing suitable habitat for a growing population. The growth and expansion of a small and isolated sea otter population provides a unique opportunity to examine the relationship between dietary diversity and population status and explore similarities and differences between trophic paradigms established for sea otter populations at other localities. ?? 2006 American Society of Mammalogists.

Reconnaissance of Surface-Water Quality and Possible Sources of Nutrients and Bacteria in the Turkey Creek Watershed, Northwest Oklahoma, 2002-2003

USGS Publications Warehouse

Becker, Carol J.

2004-01-01

The U.S. Geological Survey in cooperation with the Oklahoma Department of Environmental Quality and the U.S. Environmental Protection Agency investigated the distribution of surface-water quality and possible sources of nutrients and Escherichia coli bacteria to surface water in Turkey Creek, which flows about 70 miles through mostly rural agricultural areas in northwest Oklahoma. Results show that discharge on the main stem of Turkey Creek increased during low-flow conditions from an average of 5.4 cubic feet per second at the upper most site to 39 cubic feet per second at the lower most site in the watershed, indicating that Turkey Creek gains water from ground-water discharge. A portion of the increase in stream discharge may be from discharges of treated effluent from city sewage lagoons. However, the volume and frequency of discharges are unknown. Surface-water-quality samples show that specific conductance ranged from 1,180 to 1,740 microsiemens per centimeter at 25 degrees Celsius during low-flow conditions and in general, decreased downstream with site 1 or site 2 having the largest measurement and site 5 having the lowest. The pH values were slightly alkaline and ranged from 6.8 to 8.5 with a median of 8.2. Dissolved oxygen ranged from 9.3 to 15.9 milligrams per liter in samples collected in the months of November, February, and March and ranged from 5.3 to 13.9 milligrams per liter in samples collected in the months of June, July, and August. Surface-water-quality samples show that the median concentrations of nitrite plus nitrate as nitrogen (1.16 milligrams per liter) and total phosphorus (0.275 milligram per liter) are larger than the average median concentrations of 0.35 and 0.083 milligram per liter, respectively, calculated from water-quality sites in Oklahoma and part of Arkansas (excluding sites in the Ozark Highland and the Ouachita Mountains ecoregions) having similar stream orders and stream slopes. Concentrations of nitrite plus nitrate as nitrogen increased slightly in the winter months and decreased in the summer months, whereas, concentrations of total phosphorus and orthophosphate as phosphorus tended to increase during the summer months and decrease in the winter months. During high-flow conditions total phosphorus increased 7.7 times above the average concentration of 0.261 milligram per liter in low-flow samples. Orthophosphate concentrations increased 3.5 to 4 times during high-flow conditions. Almost all low-flow samples showed 15N values between 4 and 10 parts per thousand, above the range for atmospheric nitrogen and synthetic fertilizer and below the range for animal waste. These samples may represent a mixture of nitrate from these two sources and other sources enriched with 15N, such as soils and plants. Results of the bacterial source tracking indicated that the two source groups having the greatest number of ribopattern matches with surface-water isolates were the cattle group, 53 isolates or 23.5 percent, and the human group, 41 isolates or 18.2 percent. Fewer surface-water isolates matched the deer and horse groups, 8.0 percent and 3.5 percent, respectively. About 43 percent or 96 surface-water isolates were not matched to any source group.

The timescales of global surface-ocean connectivity.

PubMed

Jönsson, Bror F; Watson, James R

2016-04-19

Planktonic communities are shaped through a balance of local evolutionary adaptation and ecological succession driven in large part by migration. The timescales over which these processes operate are still largely unresolved. Here we use Lagrangian particle tracking and network theory to quantify the timescale over which surface currents connect different regions of the global ocean. We find that the fastest path between two patches--each randomly located anywhere in the surface ocean--is, on average, less than a decade. These results suggest that marine planktonic communities may keep pace with climate change--increasing temperatures, ocean acidification and changes in stratification over decadal timescales--through the advection of resilient types.

The timescales of global surface-ocean connectivity

PubMed Central

Jönsson, Bror F.; Watson, James R.

2016-01-01

Planktonic communities are shaped through a balance of local evolutionary adaptation and ecological succession driven in large part by migration. The timescales over which these processes operate are still largely unresolved. Here we use Lagrangian particle tracking and network theory to quantify the timescale over which surface currents connect different regions of the global ocean. We find that the fastest path between two patches—each randomly located anywhere in the surface ocean—is, on average, less than a decade. These results suggest that marine planktonic communities may keep pace with climate change—increasing temperatures, ocean acidification and changes in stratification over decadal timescales—through the advection of resilient types. PMID:27093522

Shot-Peening Effect on High Cycling Fatigue of Al-Cu Alloy

NASA Astrophysics Data System (ADS)

Fouad, Yasser; Metwally, Mostafa El

2013-12-01

The present work was aimed at evaluating the effects of shot-peening on the high cycle fatigue performance of the age-hardening aircraft alloy Al 2024 at different almen intensities. Shot-peening to full coverage (100 pct) was performed using spherically conditioned cut wire (SCCW 14) with an average shot size of 0.36 mm and at almen intensities of 0.1, 0.2, and 0.3 mmA. After applying the various mechanical surface treatments, the changes in the surface and near-surface layer properties such as microhardness, residual stress-depth profiles, and surface roughness were determined. The microhardness, surface roughness, and the residual stresses increased proportionally with the almen intensity. Electropolitically polished conditions were used as reference in the mechanically surface treated specimens. A significant improvement was seen in the fatigue performance of the 0.1 mmA.

Porcelain-metal bonding: part I. Effects of repeated baking process.

PubMed

Nagasawa, S; Yoshida, T; Mizoguchi, H; Ito, M; Oshida, Y

2001-01-01

A plurality of repeated porcelain-baking procedures are normally practiced in order to achieve the final adjustment metal-porcelain restorations. By increasing the number of baking cycles, the undesired internal strain would be built-up, causing the reduction of mechanical properties and deterioration of color characteristics. However the extensive studies on such deterioration have not been done. In this study, effects of numbers (up to 10 times) of repeated baking cycles on baking shrinkage, surface roughness, bend strength, color changes and internal microstructure were investigated when opaque, body and enamel was individually applied or when a triple-player comprising of these three porcelains was repeatedly applied. It was concluded that (1) the bend strengths increased by increasing baking cycles, (2) the average surface roughness decreased by increasing number of baking procedures, (3) changes in color characteristics was very small in the Vintage halo porcelain system, and (4) since the pores entrapped in the porcelain remained even by increasing baking cycles, it is recommended to remove the surface pores before forming the next layer when handling the high viscous opaque porcelain.

Examination of the effect of blowing on the near-surface flow structure over a dimpled surface

NASA Astrophysics Data System (ADS)

Borchetta, C. G.; Martin, A.; Bailey, S. C. C.

2018-03-01

The near surface flow over a dimpled surface with flow injection through it was documented using time-resolved particle image velocimetry. The instantaneous flow structure, time-averaged statistics, and results from snapshot proper orthogonal decomposition were used to examine the coherent structures forming near the dimpled surface. In particular, the modifications made to the flow structures by the addition of flow injection through the surface were studied. It was observed that without flow injection, inclined flow structures with alternating vorticity from neighboring dimples are generated by the dimples and advect downstream. This behavior is coupled with fluid becoming entrained inside the dimples, recirculating and ejecting away from the surface. When flow injection was introduced through the surface, the flow structures became more disorganized, but some of the features of the semi-periodic structures observed without flow injection were preserved. The structures with flow injection appear in multiple wall-normal layers, formed from vortical structures shed from upstream dimples, with a corresponding increase in the size of the advecting structures. As a result of the more complex flow field observed with flow injection, there was an increase in turbulent kinetic energy and Reynolds shear stress, with the Reynolds shear stress representing an increase in vertical transport of momentum by sweeping and ejecting motions that were not present without flow injection.

NE Forests 2100: A synthesis of climate change impacts on forests of the northeastern US and eastern Canada

Treesearch

Lindsey Rustad; John Campbell; Roger Cox; Jeffrey Dukes; T.G. Huntington; Allison Magill; Andrew Richardson; Jacqueline Mohan; Jennifer Pontius; N.R. Rodenhouse; M.R. Watson

2009-01-01

Human activities such as the combustion of fossil fuels and changes in land use are increasing atmospheric concentrations of carbon dioxide and other greenhouse gases (e.g., nitrous oxide, methane, halocarbons). Climate models indicate that these heat-trapping gases are likely to increase the Earth’s average surface air temperature by 1.1 to 6.4 °C by the end...

Local Mass and Heat Transfer on a Turbine Blade Tip

DOE PAGES

Jin, P.; Goldstein, R. J.

2003-01-01

Locmore » al mass and heat transfer measurements on a simulated high-pressure turbine blade-tip surface are conducted in a linear cascade with a nonmoving tip endwall, using a naphthalene sublimation technique. The effects of tip clearance (0.86–6.90% of chord) are investigated at various exit Reynolds numbers (4–7 × 10 5 ) and turbulence intensities (0.2 and 12.0%). The mass transfer on the tip surface is significant along its pressure edge at the smallest tip clearance. At the two largest tip clearances, the separation bubble on the tip surface can cover the whole width of the tip on the second half of the tip surface. The average mass-transfer rate is highest at a tip clearance of 1.72% of chord. The average mass-transfer rate on the tip surface is four and six times as high as on the suction and the pressure surface, respectively. A high mainstream turbulence level of 12.0% reduces average mass-transfer rates on the tip surface, while the higher mainstream Reynolds number generates higher local and average mass-transfer rates on the tip surface.« less

Improving the surface metrology accuracy of optical profilers by using multiple measurements

NASA Astrophysics Data System (ADS)

Xu, Xudong; Huang, Qiushi; Shen, Zhengxiang; Wang, Zhanshan

2016-10-01

The performance of high-resolution optical systems is affected by small angle scattering at the mid-spatial-frequency irregularities of the optical surface. Characterizing these irregularities is, therefore, important. However, surface measurements obtained with optical profilers are influenced by additive white noise, as indicated by the heavy-tail effect observable on their power spectral density (PSD). A multiple-measurement method is used to reduce the effects of white noise by averaging individual measurements. The intensity of white noise is determined using a model based on the theoretical PSD of fractal surface measurements with additive white noise. The intensity of white noise decreases as the number of times of multiple measurements increases. Using multiple measurements also increases the highest observed spatial frequency; this increase is derived and calculated. Additionally, the accuracy obtained using multiple measurements is carefully studied, with the analysis of both the residual reference error after calibration, and the random errors appearing in the range of measured spatial frequencies. The resulting insights on the effects of white noise in optical profiler measurements and the methods to mitigate them may prove invaluable to improve the quality of surface metrology with optical profilers.

Impacts of temperature increase and acidification on thickness of the surface mucopolysaccharide layer of the Caribbean coral Diploria spp.

NASA Astrophysics Data System (ADS)

Pratte, Zoe A.; Richardson, Laurie L.

2014-06-01

Coral mechanisms of resilience and resistance to stressors such as increasing sea surface temperature and ocean acidification must first be understood in order to facilitate the survival of coral reefs as we know them. One such mechanism is production of the protective surface mucopolysaccharide layer (SML). In this study, we investigated changes in the thickness of the SML in response to increasing temperature and acidification for the three Caribbean scleractinian coral species of the genus Diploria, which have been shown to exhibit differential resilience to disease and bleaching. Among the three species, Diploria strigosa is known to have a higher susceptibility to disease, Diploria labyrinthiformis is known to bleach more quickly, and Diploria clivosa is relatively unstudied. When temperature was increased from 25 to 31 °C over a 1- or 6-week period, the overall thickness of the SML decreased from 33 to 55 % for all three species. Average SML thickness at 25 °C for all three species ranged from 106 to 156 μm, while average thickness at 31 °C ranged from 64 to 86 μm. SML thickness was significantly different among species at 25 °C, but not at 31 °C. D. labyrinthiformis demonstrated lower fragment mortality due to thermal stress when compared to the other Diploria species. Acidification from pH 8.2 to 7.7 over 5 weeks had no effect on SML thickness for any species. The observed decrease in SML thickness in response to increased temperature might be attributed to a decrease in the production of mucus or an increase in the viscosity of the SML. These findings may help to explain the increased prevalence of coral disease during the warmer months, since increased temperature compromises an important aspect of coral innate immunity, as well as differences in disease and bleaching susceptibilities between Diploria species.

Understanding recent climate change.

PubMed

Serreze, Mark C

2010-02-01

The Earth's atmosphere has a natural greenhouse effect, without which the global mean surface temperature would be about 33 degrees C lower and life would not be possible. Human activities have increased atmospheric concentrations of carbon dioxide, methane, and other gases in trace amounts. This has enhanced the greenhouse effect, resulting in surface warming. Were it not for the partly offsetting effects of increased aerosol concentrations, the increase in global mean surface temperature over the past 100 years would be larger than observed. Continued surface warming through the 21st century is inevitable and will likely have widespread ecological impacts. The magnitude and rate of warming for the global average will be largely dictated by the strength and direction of climate feedbacks, thermal inertia of the oceans, the rate of greenhouse gas emissions, and aerosol concentrations. Because of regional expressions of climate feedbacks, changes in atmospheric circulation, and a suite of other factors, the magnitude and rate of warming and changes in other key climate elements, such as precipitation, will not be uniform across the planet. For example, due to loss of its floating sea-ice cover, the Arctic will warm the most.

Tool life and surface integrity aspects when drilling nickel alloy

NASA Astrophysics Data System (ADS)

Kannan, S.; Pervaiz, S.; Vincent, S.; Karthikeyan, R.

2018-04-01

Nickel based super alloys manufactured through powder metallurgy (PM) route are required to increase the operational efficiency of gas turbine engines. They are material of choice for high pressure components due to their superior high temperature strength, excellent corrosion, oxidation and creep resistance. This unique combination of mechanical and thermal properties makes them even more difficult-to-machine. In this paper, the hole making process using coated carbide inserts by drilling and plunge milling for a nickel-based powder metallurgy super alloy has been investigated. Tool life and process capability studies were conducted using optimized process parameters using high pressure coolants. The experimental trials were directed towards an assessment of the tendency for surface malformations and detrimental residual stress profiles. Residual stresses in both the radial and circumferential directions have been evaluated as a function of depth from the machined surface using the target strain gauge / center hole drilling method. Circumferential stresses near workpiece surface and at depth of 512 µm in the starting material was primarily circumferential compression which was measured to be average of –404 MPa. However, the radial stresses near workpiece surface was tensile and transformed to be compressive in nature at depth of 512 µm in the starting material (average: -87 Mpa). The magnitude and the depth below the machined surface in both radial and circumferential directions were primarily tensile in nature which increased with hole number due to a rise of temperature at the tool–workpiece interface with increasing tool wear. These profiles are of critical importance for the selection of cutting strategies to ensure avoidance/minimization of tensile residual stresses that can be detrimental to the fatigue performance of the components. These results clearly show a tendency for the circumferential stresses to be more tensile than the radial stresses. Overall the results indicate that the effect of drilling and milling parameters is most marked in terms of surface quality in the circumferential direction. Material removal rates and tool flank wear must be maintained within the control limits to maintain hole integrity.

Stick-Jump (SJ) Evaporation of Strongly Pinned Nanoliter Volume Sessile Water Droplets on Quick Drying, Micropatterned Surfaces.

PubMed

Debuisson, Damien; Merlen, Alain; Senez, Vincent; Arscott, Steve

2016-03-22

We present an experimental study of stick-jump (SJ) evaporation of strongly pinned nanoliter volume sessile water droplets drying on micropatterned surfaces. The evaporation is studied on surfaces composed of photolithographically micropatterned negative photoresist (SU-8). The micropatterning of the SU-8 enables circular, smooth, trough-like features to be formed which causes a very strong pinning of the three phase (liquid-vapor-solid) contact line of an evaporating droplet. This is ideal for studying SJ evaporation as it contains sequential constant contact radius (CCR) evaporation phases during droplet evaporation. The evaporation was studied in nonconfined conditions, and forced convection was not used. Micropatterned concentric circles were defined having an initial radius of 1000 μm decreasing by a spacing ranging from 500 to 50 μm. The droplet evaporates, successively pinning and depinning from circle to circle. For each pinning radius, the droplet contact angle and volume are observed to decrease quasi-linearly with time. The experimental average evaporation rates were found to decrease with decreasing pining radii. In contrast, the experimental average evaporation flux is found to increase with decreasing droplet radii. The data also demonstrate the influence of the initial contact angle on evaporation rate and flux. The data indicate that the total evaporation time of a droplet depends on the specific micropattern spacing and that the total evaporation time on micropatterned surfaces is always less than on flat, homogeneous surfaces. Although the surface patterning is observed to have little effect on the average droplet flux-indicating that the underlying evaporation physics is not significantly changed by the patterning-the total evaporation time is considerably modified by patterning, up to a factor or almost 2 compared to evaporation on a flat, homogeneous surface. The closely spaced concentric circle pinning maintains a large droplet radius and small contact angle from jump to jump; the result is a large evaporation rate leading to faster evaporation.

Variations and controls on crustal thermal regimes in Southeastern Australia

NASA Astrophysics Data System (ADS)

Mather, Ben; McLaren, Sandra; Taylor, David; Roy, Sukanta; Moresi, Louis

2018-01-01

The surface heat flow field in Australia has for many years been poorly constrained compared to continental regions elsewhere. 182 recent heat flow determinations and 66 new heat production measurements for Southeastern Australia significantly increase our understanding of local and regional lithospheric thermal regimes and allow for detailed thermal modelling. The new data give a mean surface heat flow for Victoria of 71 ± 15 mW m- 2 which fits within the 61-77 mW m- 2 range reported for Phanerozoic-aged crust globally. These data reveal three new thermally and compositionally distinct heat flow sub-provinces within the previously defined Eastern Heat Flow Province: the Delamerian heat flow sub-province (average surface heat flow 60 ± 9 mW m- 2); the Lachlan heat flow sub-province (average surface heat flow 74 ± 13 mW m- 2); and the Newer Volcanics heat flow sub-province (average surface heat flow 72 ± 16 mW m- 2) which includes extreme values that locally exceed 100 mW m- 2. Inversions of reduced heat flow and crustal differentiation find that the Delamerian sub-province has experienced significant crustal reworking compared to the Lachlan and Newer Volcanics sub-provinces. The latter has experienced volcanism within the last 8 Ma and the degree of variability observed in surface heat flow points (up to 8 mW m- 2 per kilometre laterally) cannot be replicated with steady-state thermal models through this sub-province. In the absence of a strong palaeoclimate signal, aquifer disturbances, or highly enriched granites, we suggest that this high variability arises from localised transient perturbations to the upper crust associated with recent intraplate volcanism. This is supported by a strong spatial correlation of high surface heat flow and known eruption points within the Newer Volcanics heat flow sub-province.

Effect of treatment temperature on the microstructure of asphalt binders: insights on the development of dispersed domains.

PubMed

Menapace, I; Masad, E; Bhasin, A

2016-04-01

This paper offers important insights on the development of the microstructure in asphalt binders as a function of the treatment temperature. Different treatment temperatures are useful to understand how dispersed domains form when different driving energies for the mobility of molecular species are provided. Small and flat dispersed domains, with average diameter between 0.02 and 0.70 μm, were detected on the surface of two binders at room temperature, and these domains were observed to grow with an increase in treatment temperature (up to over 2 μm). Bee-like structures started to appear after treatment at or above 100°C. Moreover, the effect of the binder thickness on its microstructure at room temperature and at higher treatment temperatures was investigated and is discussed in this paper. At room temperature, the average size of the dispersed domains increased as the binder thickness decreased. A hypothesis that conciliates current theories on the origin and development of dispersed domains is proposed. Small dispersed domains (average diameter around 0.02 μm) are present in the bulk of the binder, whereas larger domains and bee-like structures develop on the surface, following heat treatment or mechanical disturbance that reduces the film thickness. Molecular mobility and association are the key factors in the development of binder microstructure. © 2015 The Authors Journal of Microscopy © 2015 Royal Microscopical Society.

Poly- and perfluoroalkylated substances (PFASs) in water, sediment and fish muscle tissue from Lake Tana, Ethiopia and implications for human exposure.

PubMed

Ahrens, Lutz; Gashaw, Habiba; Sjöholm, Margareta; Gebrehiwot, Solomon Gebreyohannis; Getahun, Abebe; Derbe, Ermias; Bishop, Kevin; Åkerblom, Staffan

2016-12-01

Lake Tana is Ethiopia's largest lake and there are plans to increase the harvest of fish from the lake. The objective of this study was to assess the levels of poly- and perfluoroalkyl substances (PFASs) in different compartments of the lake (water, sediment, and fish muscle tissue), and its implications for human exposure. The results showed higher PFAS concentrations in piscivorous fish species (Labeobarbus megastoma and Labeobarbus gorguari) than non-piscivorous species (Labeobarbus intermedius, Oreochromis niloticus and Clarias gariepinus) and also spatial distribution similarities. The ∑PFAS concentrations ranged from 0.073 to 5.6 ng L -1 (on average, 2.9 ng L -1 ) in surface water, 0.22-0.55 ng g -1 dry weight (dw) (on average, 0.30 ng g -1 dw) in surface sediment, and non-detected to 5.8 ng g -1 wet weight (ww) (on average, 1.2 ng g -1 ww) in all fish species. The relative risk (RR) indicates that the consumption of fish contaminated with perfluorooctane sulfonate (PFOS) will likely not cause any harmful effects for the Ethiopian fish eating population. However, mixture toxicity of the sum of PFASs, individual fish consumption patterns and increasing fish consumption are important factors to consider in future risk assessments. Copyright © 2016 Elsevier Ltd. All rights reserved.

Methane flux from Minnesota Peatlands

NASA Astrophysics Data System (ADS)

Crill, P. M.; Bartlett, K. B.; Harriss, R. C.; Gorham, E.; Verry, E. S.; Sebacher, D. I.; Madzar, L.; Sanner, W.

1988-12-01

Northern (>40°N) wetlands have been suggested as the largest natural source of methane (CH4) to the troposphere. To refine our estimates of source strengths from this region and to investigate climatic controls on the process, fluxes were measured from a variety of Minnesota peatlands during May, June, and August 1986. Sites included forested and unforested ombrotrophic bogs and minerotrophic fens in and near the U.S. Department of Agriculture Marcell Experimental Forest and the Red Lake peatlands. Late spring and summer fluxes ranged from 11 to 866 mg CH4 m-2 d-1, averaging 207 mg CH4 m-2 d-1 overall. At Marcell Forest, forested bogs and fen sites had lower fluxes (averages of 77 ± 21 mg CH4 m-2 d-1 and 142 ± 19 mg CH4 m-2 d-1) than open bogs (average of 294 ± 30 mg CH4 m-2 d-1). In the Red Lake peatland, circumneutral fens, with standing water above the peat surface, produced more methane than acid bog sites in which the water table was beneath the moss surface (325 ± 31 and 102 ± 13 mg CH4 m-2 d-1, respectively). Peat temperature was an important control. Methane flux increased in response to increasing soil temperature. For example, the open bog in the Marcell Forest with the highest CH4 flux exhibited a 74-fold increase in flux over a three-fold increase in temperature. We estimate that the methane flux from all peatlands north of 40° may be on the order of 70 to 90 Tg/yr though estimates of this sort are plagued by uncertainties in the areal extent of peatlands, length of the CH4 producing season, and the spatial and temporal variability of the flux.

Surface modification of protein enhances encapsulation in chitosan nanoparticles

NASA Astrophysics Data System (ADS)

Koyani, Rina D.; Andrade, Mariana; Quester, Katrin; Gaytán, Paul; Huerta-Saquero, Alejandro; Vazquez-Duhalt, Rafael

2018-04-01

Chitosan nanoparticles have a huge potential as nanocarriers for environmental and biomedical purposes. Protein encapsulation in nano-sized chitosan provides protection against inactivation, proteolysis, and other alterations due to environmental conditions, as well as the possibility to be targeted to specific tissues by ligand functionalization. In this work, we demonstrate that the chemical modification of the protein surface enhances the protein loading in chitosan nanocarriers. Encapsulation of green fluorescent protein and the cytochrome P450 was studied. The increase of electrostatic interactions between the free amino groups of chitosan and the increased number of free carboxylic groups in the protein surface enhance the protein loading, protein retention, and, thus, the enzymatic activity of chitosan nanoparticles. The chemical modification of protein surface with malonic acid moieties reduced drastically the protein isoelectric point increasing the protein interaction with the polycationic biomaterial and chitosan. The chemical modification of protein does not alter the morphology of chitosan nanoparticles that showed an average diameter of 18 nm, spheroidal in shape, and smooth surfaced. The strategy of chemical modification of protein surface, shown here, is a simple and efficient technique to enhance the protein loading in chitosan nanoparticles. This technique could be used for other nanoparticles based on polycationic or polyanionic materials. The increase of protein loading improves, doubtless, the performance of protein-loaded chitosan nanoparticles for biotechnological and biomedical applications.

Climate Impacts of CALIPSO-Guided Corrections to Black Carbon Aerosol Vertical Distributions in a Global Climate Model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kovilakam, Mahesh; Mahajan, Salil; Saravanan, R.

Here, we alleviate the bias in the tropospheric vertical distribution of black carbon aerosols (BC) in the Community Atmosphere Model (CAM4) using the Cloud-Aerosol and Infrared Pathfinder Satellite Observations (CALIPSO)-derived vertical profiles. A suite of sensitivity experiments are conducted with 1x, 5x, and 10x the present-day model estimated BC concentration climatology, with (corrected, CC) and without (uncorrected, UC) CALIPSO-corrected BC vertical distribution. The globally averaged top of the atmosphere radiative flux perturbation of CC experiments is ~8–50% smaller compared to uncorrected (UC) BC experiments largely due to an increase in low-level clouds. The global average surface temperature increases, the globalmore » average precipitation decreases, and the ITCZ moves northward with the increase in BC radiative forcing, irrespective of the vertical distribution of BC. Further, tropical expansion metrics for the poleward extent of the Northern Hemisphere Hadley cell (HC) indicate that simulated HC expansion is not sensitive to existing model biases in BC vertical distribution.« less

Climate Impacts of CALIPSO-Guided Corrections to Black Carbon Aerosol Vertical Distributions in a Global Climate Model

DOE PAGES

Kovilakam, Mahesh; Mahajan, Salil; Saravanan, R.; ...

2017-09-13

Here, we alleviate the bias in the tropospheric vertical distribution of black carbon aerosols (BC) in the Community Atmosphere Model (CAM4) using the Cloud-Aerosol and Infrared Pathfinder Satellite Observations (CALIPSO)-derived vertical profiles. A suite of sensitivity experiments are conducted with 1x, 5x, and 10x the present-day model estimated BC concentration climatology, with (corrected, CC) and without (uncorrected, UC) CALIPSO-corrected BC vertical distribution. The globally averaged top of the atmosphere radiative flux perturbation of CC experiments is ~8–50% smaller compared to uncorrected (UC) BC experiments largely due to an increase in low-level clouds. The global average surface temperature increases, the globalmore » average precipitation decreases, and the ITCZ moves northward with the increase in BC radiative forcing, irrespective of the vertical distribution of BC. Further, tropical expansion metrics for the poleward extent of the Northern Hemisphere Hadley cell (HC) indicate that simulated HC expansion is not sensitive to existing model biases in BC vertical distribution.« less

Thermal regimes of Rocky Mountain lakes warm with climate change

PubMed Central

Roberts, James J.

2017-01-01

Anthropogenic climate change is causing a wide range of stresses in aquatic ecosystems, primarily through warming thermal conditions. Lakes, in response to these changes, are experiencing increases in both summer temperatures and ice-free days. We used continuous records of lake surface temperature and air temperature to create statistical models of daily mean lake surface temperature to assess thermal changes in mountain lakes. These models were combined with downscaled climate projections to predict future thermal conditions for 27 high-elevation lakes in the southern Rocky Mountains. The models predict a 0.25°C·decade-1 increase in mean annual lake surface temperature through the 2080s, which is greater than warming rates of streams in this region. Most striking is that on average, ice-free days are predicted to increase by 5.9 days ·decade-1, and summer mean lake surface temperature is predicted to increase by 0.47°C·decade-1. Both could profoundly alter the length of the growing season and potentially change the structure and function of mountain lake ecosystems. These results highlight the changes expected of mountain lakes and stress the importance of incorporating climate-related adaptive strategies in the development of resource management plans. PMID:28683083

Thermal regimes of Rocky Mountain lakes warm with climate change

USGS Publications Warehouse

Roberts, James J.; Fausch, Kurt D.; Schmidt, Travis S.; Walters, David M.

2017-01-01

Anthropogenic climate change is causing a wide range of stresses in aquatic ecosystems, primarily through warming thermal conditions. Lakes, in response to these changes, are experiencing increases in both summer temperatures and ice-free days. We used continuous records of lake surface temperature and air temperature to create statistical models of daily mean lake surface temperature to assess thermal changes in mountain lakes. These models were combined with downscaled climate projections to predict future thermal conditions for 27 high-elevation lakes in the southern Rocky Mountains. The models predict a 0.25°C·decade-1increase in mean annual lake surface temperature through the 2080s, which is greater than warming rates of streams in this region. Most striking is that on average, ice-free days are predicted to increase by 5.9 days ·decade-1, and summer mean lake surface temperature is predicted to increase by 0.47°C·decade-1. Both could profoundly alter the length of the growing season and potentially change the structure and function of mountain lake ecosystems. These results highlight the changes expected of mountain lakes and stress the importance of incorporating climate-related adaptive strategies in the development of resource management plans.

Thermal regimes of Rocky Mountain lakes warm with climate change.

PubMed

Roberts, James J; Fausch, Kurt D; Schmidt, Travis S; Walters, David M

2017-01-01

Anthropogenic climate change is causing a wide range of stresses in aquatic ecosystems, primarily through warming thermal conditions. Lakes, in response to these changes, are experiencing increases in both summer temperatures and ice-free days. We used continuous records of lake surface temperature and air temperature to create statistical models of daily mean lake surface temperature to assess thermal changes in mountain lakes. These models were combined with downscaled climate projections to predict future thermal conditions for 27 high-elevation lakes in the southern Rocky Mountains. The models predict a 0.25°C·decade-1 increase in mean annual lake surface temperature through the 2080s, which is greater than warming rates of streams in this region. Most striking is that on average, ice-free days are predicted to increase by 5.9 days ·decade-1, and summer mean lake surface temperature is predicted to increase by 0.47°C·decade-1. Both could profoundly alter the length of the growing season and potentially change the structure and function of mountain lake ecosystems. These results highlight the changes expected of mountain lakes and stress the importance of incorporating climate-related adaptive strategies in the development of resource management plans.

Simulating 3-D radiative transfer effects over the Sierra Nevada Mountains using WRF

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gu, Y.; Liou, K. N.; Lee, W. -L.

2012-01-01

A surface solar radiation parameterization based on deviations between 3-D and conventional plane-parallel radiative transfer models has been incorporated into the Weather Research and Forecasting (WRF) model to understand the solar insolation over mountain/snow areas and to investigate the impact of the spatial and temporal distribution and variation of surface solar fluxes on land-surface processes. Using the Sierra-Nevada in the western United States as a testbed, we show that mountain effect could produce up to -50 to + 50 W m -2 deviations in the surface solar fluxes over the mountain areas, resulting in a temperature increase of up tomore » 1 °C on the sunny side. Upward surface sensible and latent heat fluxes are modulated accordingly to compensate for the change in surface solar fluxes. Snow water equivalent and surface albedo both show decreases on the sunny side of the mountains, indicating more snowmelt and hence reduced snow albedo associated with more solar insolation due to mountain effect. Soil moisture increases on the sunny side of the mountains due to enhanced snowmelt, while decreases on the shaded side. Substantial differences are found in the morning hours from 8–10 a.m. and in the afternoon around 3–5 p.m., while differences around noon and in the early morning and late afternoon are comparatively smaller. Variation in the surface energy balance can also affect atmospheric processes, such as cloud fields, through the modulation of vertical thermal structure. Negative changes of up to -40 g m -2 are found in the cloud water path, associated with reductions in the surface insolation over the cloud region. The day-averaged deviations in the surface solar flux are positive over the mountain areas and negative in the valleys, with a range between -12~12 W m -2. Changes in sensible and latent heat fluxes and surface skin temperature follow the solar insolation pattern. Differences in the domain-averaged diurnal variation over the Sierras show that the mountain area receives more solar insolation during early morning and late afternoon, resulting in enhanced upward sensible heat and latent heat fluxes from the surface and a corresponding increase in surface skin temperature. During the middle of the day, however, the surface insolation and heat fluxes show negative changes, indicating a cooling effect. Hence overall, the diurnal variations of surface temperature and surface fluxes in the Sierra-Nevada are reduced through the interactions of radiative transfer and mountains. Finally, the hourly differences of the surface solar insolation in higher elevated regions, however, show smaller magnitude in negative changes during the middle of the day and possibly more solar fluxes received during the whole day.« less

Injectable and porous PLGA microspheres that form highly porous scaffolds at body temperature.

PubMed

Qutachi, Omar; Vetsch, Jolanda R; Gill, Daniel; Cox, Helen; Scurr, David J; Hofmann, Sandra; Müller, Ralph; Quirk, Robin A; Shakesheff, Kevin M; Rahman, Cheryl V

2014-12-01

Injectable scaffolds are of interest in the field of regenerative medicine because of their minimally invasive mode of delivery. For tissue repair applications, it is essential that such scaffolds have the mechanical properties, porosity and pore diameter to support the formation of new tissue. In the current study, porous poly(dl-lactic acid-co-glycolic acid) (PLGA) microspheres were fabricated with an average size of 84±24μm for use as injectable cell carriers. Treatment with ethanolic sodium hydroxide for 2min was observed to increase surface porosity without causing the microsphere structure to disintegrate. This surface treatment also enabled the microspheres to fuse together at 37°C to form scaffold structures. The average compressive strength of the scaffolds after 24h at 37°C was 0.9±0.1MPa, and the average Young's modulus was 9.4±1.2MPa. Scaffold porosity levels were 81.6% on average, with a mean pore diameter of 54±38μm. This study demonstrates a method for fabricating porous PLGA microspheres that form solid porous scaffolds at body temperature, creating an injectable system capable of supporting NIH-3T3 cell attachment and proliferation in vitro. Copyright © 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Efficacy of 3 different artificial tears for the treatment of dry eye in frequent computer users and/or contact lens users.

PubMed

Calvão-Santos, Gil; Borges, Cristina; Nunes, Sandrina; Salgado-Borges, José; Duarte, Lilianne

2011-01-01

To compare the efficacy of 3 different artificial tears (AT) acting primarily in one of the 3 tear film layers (Tears Again®, lipidic; Opticol®, aqueous; Optive®, mucin) in recovering the tear film changes in patients with dry eye symptoms due to external causes. A total of 27 patients, with dry eye symptoms associated with extra hours of computer or contact lenses use, were randomized to 4 treatment groups: A received Tears Again®; B received Optive®; C received Opticol®; D received no treatment (control). Patients were observed in 3 visits: day 0, day 7, and day 30. Tear break-up time (TBUT) and Schirmer tests and the Ocular Surface Disease Index were performed. Data analysis was performed. There were no significant differences between the groups. From day 0 to day 30, there was a decrease in the number of eyes with abnormal TBUT (not significant) and Schirmer (significant in A, B, D; p<0.031). There was an increase in the average TBUT for all groups (significant in A, C; p<0.001) and a decrease in the average Schirmer value in groups B, C, and D (not significant) and an increase in group A (p = 0.002). There was a decrease in the average Ocular Surface Disease Index value in all groups (p<0.045). All AT were efficient at recovering the tear film, but those acting primarily on the internal and intermediate layer led to a mild decline on lachrymal production. An association of different kinds of AT acting on each layer can be the best treatment for corneal surface diseases affecting eye lubrication.

Impact of the ongoing Amazonian deforestation on local precipitation: A GCM simulation study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Walker, G.K.; Sud, Y.C.; Atlas, R.

1995-03-01

Numerical simulation experiments were conducted to delineate the influence of in situ deforestation data on episodic rainfall by comparing two ensembles of five 5-day integrations performed with a recent version of the Goddard Laboratory for Atmospheres GCM that has a simple biosphere model (SiB). The first set, called control cases, used the standard SiB vegetation cover (comprising 12 biomes) and assumed a fully forested Amazonia, while the second set, called deforestation cases, distinguished the partially deforested regions of Amazonia as savanna. Except for this difference, all other initial and prescribed boundary conditions were kept identical in both sets of integrations.more » The differential analyses of these five cases show the following local effects of deforestation. (1) A discernible decrease in evapotranspiration of about 0.80 mm d{sup {minus}1} (roughly 18%) that is quite robust in the averages for 1-, 2-, and 5-day forecasts. (2) A decrease in precipitation of about 1.18 mm d{sup {minus}1} (roughly 8%) that begins to emerge even in 1-2-day averages and exhibits complex evolution that extends downstream with the winds. A larger decrease in precipitation as compared to evapotranspiration produces some drying and warming. The precipitation differences are consistent with the decrease in atmospheric moisture flux convergence and are consistent with earlier simulation studies of local climate change due to large-scale deforestation. (3) A significant decrease in the surface drag force (as a consequence of reduced surface roughness of deforested regions) that, in turn, affects the dynamical structure of moisture convergence and circulation. The surface winds increase significantly during the first day, and thereafter the increase is well maintained even in the 2- and 5-day averages. 34 refs., 9 figs., 2 tabs.« less

Synthesis and characterization of Ni doped ZnO nanoparticles

NASA Astrophysics Data System (ADS)

Tamgadge, Y. S.; Gedam, P. P.; Ganorkar, R. P.; Mahure, M. A.; Pahurkar, V. G.; Muley, G. G.

2018-05-01

In this paper, we present synthesis of L-valine assisted surface modification of Ni doped ZnO nanoparticles (NPs) using chemical precipitation method. Samples were calcined at 500oC for 2h. Uncalcined and calcined samples were characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM) and ultraviolet-visible (UV-vis) spectroscopy. Ni doped ZnO NPs with average particle size of 8 nm have been successfully obtained using L-valine as surface modifying agent. Increase in the particle size was observed after the calcination. XRD and TEM studies confirmed the purity, surface morphology and hexagonal wurtzite crystal structure of ZnO NPs. UV-vis spectroscopy indicated the blue shift of excitons absorption wavelength and surface modification by L-valine.

Characteristic CT Findings After Percutaneous Cryoablation Treatment of Malignant Lung Nodules

PubMed Central

Chaudhry, Ammar; Grechushkin, Vadim; Hoshmand, Mahsa; Kim, Choo Won; Pena, Andres; Huston, Brett; Chaya, Yair; Bilfinger, Thomas; Moore, William

2015-01-01

Abstract Assess computed tomography (CT) imaging characteristics after percutaneous cryotherapy for lung cancer. A retrospective IRB-approved analysis of 40 patients who underwent nonsurgical treatment for primary stage 1 lung cancer performed from January 2007 to March 2011 was included in this study. All procedures were performed using general anesthesia and CT guidance. Follow-up imaging with CT of the chest was obtained at 1 month, 3 months, 6 months, and 12 months postprocedure to evaluate the ablated lung nodule. Nodule surface area, density (in Hounsfield units), and presence or absence of cavitations were recorded. In addition, the degree of nodule enhancement was also recorded. Patients who were unable to obtain the aforementioned follow-up were excluded from the study. Thirty-six patients underwent percutaneous cryoablation with men to women ratio of 75% with mean age for men 74.6 and mean age for women 74.3 years of age. The average nodule surface area preablation and postcryoablation at 1-, 3-, 6-, and 12-month follow-ups were 2.99, 7.86, 3.89, 3.18 and 3.07�cm2, respectively. The average precontrast nodule density before cryoablation was 8.9 and average precontrast nodule density postprocedure at 1, 3, 6, and 12 months follow-ups were 8.5, −5.9, −9.4, and −3.8 HU, respectively. There is increased attenuation of lung nodules over time with an average postcontrast enhancement of 11.4, 18.5, 16.1, and 25.7 HU at the aforementioned time intervals. Cavitations occurred in the cryoablation zone in 53% (19/36) of patients. 80.6% (29/36) of the cavitations in the cryoablation zone resolved within 12 months. Four patients (11%) had recurrence of tumor at the site of cryoablation and none of the patients had satellite or distant metastasis. Our study shows that patients who underwent cryotherapy for lung nodules treatment had characteristic changes on follow-up CT including. The surface area of the nodule increases at the 1-month follow-up with subsequent gradual decrease in the surface area. Decreased nodule density (Hounsfield units) at each interval follow-up is associated with complete ablation of the lung cancer whereas increasing nodule density was suggestive of recurrence. Cavity formation within the region of the ablated nodule, most of which typically resolved within the first 3 to 6 months. Nodule enhancement is difficult to assess because of the limited data sets that are available. PMID:26496275

Characteristic CT Findings After Percutaneous Cryoablation Treatment of Malignant Lung Nodules.

PubMed

Chaudhry, Ammar; Grechushkin, Vadim; Hoshmand, Mahsa; Kim, Choo Won; Pena, Andres; Huston, Brett; Chaya, Yair; Bilfinger, Thomas; Moore, William

2015-10-01

Assess computed tomography (CT) imaging characteristics after percutaneous cryotherapy for lung cancer.A retrospective IRB-approved analysis of 40 patients who underwent nonsurgical treatment for primary stage 1 lung cancer performed from January 2007 to March 2011 was included in this study. All procedures were performed using general anesthesia and CT guidance. Follow-up imaging with CT of the chest was obtained at 1 month, 3 months, 6 months, and 12 months postprocedure to evaluate the ablated lung nodule. Nodule surface area, density (in Hounsfield units), and presence or absence of cavitations were recorded. In addition, the degree of nodule enhancement was also recorded. Patients who were unable to obtain the aforementioned follow-up were excluded from the study.Thirty-six patients underwent percutaneous cryoablation with men to women ratio of 75% with mean age for men 74.6 and mean age for women 74.3 years of age. The average nodule surface area preablation and postcryoablation at 1-, 3-, 6-, and 12-month follow-ups were 2.99, 7.86, 3.89, 3.18 and 3.07[REPLACEMENT CHARACTER]cm, respectively. The average precontrast nodule density before cryoablation was 8.9 and average precontrast nodule density postprocedure at 1, 3, 6, and 12 months follow-ups were 8.5, -5.9, -9.4, and -3.8 HU, respectively. There is increased attenuation of lung nodules over time with an average postcontrast enhancement of 11.4, 18.5, 16.1, and 25.7 HU at the aforementioned time intervals. Cavitations occurred in the cryoablation zone in 53% (19/36) of patients. 80.6% (29/36) of the cavitations in the cryoablation zone resolved within 12 months. Four patients (11%) had recurrence of tumor at the site of cryoablation and none of the patients had satellite or distant metastasis.Our study shows that patients who underwent cryotherapy for lung nodules treatment had characteristic changes on follow-up CT including. The surface area of the nodule increases at the 1-month follow-up with subsequent gradual decrease in the surface area. Decreased nodule density (Hounsfield units) at each interval follow-up is associated with complete ablation of the lung cancer whereas increasing nodule density was suggestive of recurrence. Cavity formation within the region of the ablated nodule, most of which typically resolved within the first 3 to 6 months. Nodule enhancement is difficult to assess because of the limited data sets that are available.

Controllable preparation of a nano-hydroxyapatite coating on carbon fibers by electrochemical deposition and chemical treatment.

PubMed

Wang, Xudong; Zhao, Xueni; Wang, Wanying; Zhang, Jing; Zhang, Li; He, Fuzhen; Yang, Jianjun

2016-06-01

A nano-hydroxyapatite (HA) coating with appropriate thickness and morphology similar to that of human bone tissue was directly prepared onto the surfaces of carbon fibers (CFs). A mixed solution of nitric acid, hydrochloric acid, sulfuric acid, and hydrogen peroxide (NHSH) was used in the preparation process. The coating was fabricated by combining NHSH treatment and electrochemical deposition (ECD). NHSH treatment is easy to operate, produces rapid reaction, and highly effective. This method was first used to induce the nucleation and growth of HA crystals on the CF surfaces. Numerous O-containing functional groups, such as hydroxyl (-OH) and carboxyl (-COOH) groups, were grafted onto the CF surfaces by NHSH treatment (NHSH-CFs); as such, the amounts of these groups on the functionalized CFs increased by nearly 8- and 12-fold, respectively, compared with those on untreated CFs. After treatment, the NHSH-CFs not only acquired larger specific surface areas but retained surfaces free from serious corrosion or breakage. Hence, NHSH-CFs are ideal depositional substrates of HA coating during ECD. ECD was successfully used to prepare a nano-rod-like HA coating on the NHSH-CF surfaces. The elemental composition, structure, and morphology of the HA coating were effectively controlled by adjusting various technological parameters, such as the current density, deposition time, and temperature. The average central diameter of HA crystals and the coating density increased with increasing deposition time. The average central diameter of most HA crystals on the NHSH-CFs varied from approximately 60 nm to 210 nm as the deposition time increased from 60 min to 180 min. Further studies on a possible deposition mechanism revealed that numerous O-containing functional groups on the NHSH-CF surfaces could associate with electrolyte ions (Ca(2+)) to form special chemical bonds. These bonds can induce HA coating deposition and improve the interfacial bonding strength between the HA coating and NHCH-CFs. The results of this study and the proposed preparation of uniform and dense nano-HA coating provide theoretical and practical guidance for future investigations of active HA coatings on fiber materials for medical products and implants. This work also lays the foundation for the wider use of HA-coated CFs/HA composite implants in clinical application. Copyright © 2016 Elsevier B.V. All rights reserved.

Role of SiO2 coating in multiferroic CoCr2O4 nanoparticles

NASA Astrophysics Data System (ADS)

Kamran, M.; Ullah, Asmat; Mehmood, Y.; Nadeem, K.; Krenn, H.

2017-02-01

Effect of silica (SiO2) coating concentration on structural and magnetic properties of multiferroic cobalt chromite (CoCr2O4) nanoparticles have been studied. The nanoparticles with average crystallite size in the range 19 to 28 nm were synthesised by sol-gel method. X-ray diffraction (XRD) analysis has verified the composition of single-phase cubic normal spinel structure of CoCr2O4 nanoparticles. The average crystallite size and cell parameter decreased with increasing SiO2 concentration. TEM image revealed that the shape of nanoparticles was non-spherical. Zero field cooled/field cooled (ZFC/FC) curves revealed that nanoparticles underwent a transition from paramagnetic (PM) state to collinear short-range ferrimagnetic (FiM) state, and this PM-FiM transition temperature decreased from 101 to 95 K with increasing SiO2 concentration or decreasing crystallite size. A conical spin state at Ts = 27 K was also observed for all the samples which decreased with decreasing average crystallite size. Low temperature lock-in transition was also observed in these nanoparticles at 12 K for uncoated nanoparticles which slightly shifted towards low temperature with decreasing average crystallite size. Saturation magnetization (Ms) showed decreasing trend with increasing SiO2 concentration, which was due to decrease in average crystallite size of nanoparticles and enhanced surface disorder in smaller nanoparticles. The temperature dependent AC-susceptibility also showed the decrease in the transition temperature (Tc), broadening of the Tc peak and decrease in magnetization with increasing SiO2 concentration or decreasing average crystallite size. In summary, the concentration of SiO2 has significantly affected the structural and magnetic properties of CoCr2O4 nanoparticles.

Numerical investigation of roughness effects in aircraft icing calculations

NASA Astrophysics Data System (ADS)

Matheis, Brian Daniel

2008-10-01

Icing codes are playing a role of increasing significance in the design and certification of ice protected aircraft surfaces. However, in the interest of computational efficiency certain small scale physics of the icing problem are grossly approximated by the codes. One such small scale phenomena is the effect of ice roughness on the development of the surface water film and on the convective heat transfer. This study uses computational methods to study the potential effect of ice roughness on both of these small scale phenomena. First, a two-dimensional condensed layer code is used to examine the effect of roughness on surface water development. It is found that the Couette approximation within the film breaks down as the wall shear goes to zero, depending on the film thickness. Roughness elements with initial flow separation in the air induce flow separation in the water layer at steady state, causing a trapping of the film. The amount of trapping for different roughness configurations is examined. Second, a three-dimensional incompressible Navier-Stokes code is developed to examine large scale ice roughness on the leading edge. The effect on the convective heat transfer and potential effect on the surface water dynamics is examined for a number of distributed roughness parameters including Reynolds number, roughness height, streamwise extent, roughness spacing and roughness shape. In most cases the roughness field increases the net average convective heat transfer on the leading edge while narrowing surface shear lines, indicating a choking of the surface water flow. Both effects show significant variation on the scale of the ice roughness. Both the change in heat transfer as well as the potential change in surface water dynamics are presented in terms of the development of singularities in the surface shear pattern. Of particular interest is the effect of the smooth zone upstream of the roughness which shows both a relatively large increase in convective heat transfer as well as excessive choking of the surface shear lines at the upstream end of the roughness field. A summary of the heat transfer results is presented for both the averaged heat transfer as well as the maximum heat transfer over each roughness element, indicating that the roughness Reynolds number is the primary parameter which characterizes the behavior of the roughness for the problem of interest.

Assessing the Urban Heat Island Effect Across Biomes in the Continental USA Using Landsat and MODIS

NASA Technical Reports Server (NTRS)

Imhoff, Marc L.; Bounoua, L.; Zhang, Ping; Wolfe, Robert

2011-01-01

Impervious surface area (ISA) from the Landsat TM and land surface temperature (LST) from MODIS averaged over three annual cycles (2003-2005) are used in a spatial analysis to assess the urban heat island (UHI) skin temperature amplitude and its relationship to development intensity, size, and ecological setting for 38 of the most populous cities in the continental United States. Development intensity zones based on %ISA are defined across urban gradients and used to stratify sampling of LST and NDVI. We find that ecological context significantly influences the amplitude of summer daytime UHI (urban - rural temperature difference) with the largest 8 C (average) for cities built in mixed forest biomes. For all cities ISA is the primary driver for increase in temperature explaining 70% of the total variance. Annually, urban areas are warmer than the non-urban fringe by 2.9 C, except in biomes with arid and semiarid climates. The average amplitude of the UHI is asymmetric with a 4.3 C difference in summer and 1.3 C in winter. In desert environments, UHI's point to a possible heat sink effect. Results show that the urban heat island amplitude increases with city size and is seasonally asymmetric for a large number of cities across most biomes. The implications are that for urban areas developed within forested ecosystems the summertime UHI can be quite high relative to the wintertime UHI suggesting that the residential energy consumption required for summer cooling is likely to increase with urban growth within those biomes.

Polaron-mediated surface reconstruction in the reduced Rutile TiO2 (110) surface

NASA Astrophysics Data System (ADS)

Reticcioli, Michele; Setvin, Martin; Hao, Xianfeng; Diebold, Ulrike; Franchini, Cesare

The role of polarons is of key importance for the understanding of the fundamental properties and functionalities of TiO2. We use density functional theory with an on-site Coulomb interaction and molecular dynamics to study the formation and dynamics of small polarons in the reduced rutile (110) surface. We show that excess electrons donated by oxygen-vacancies (VO) form mobile small polarons that hop easily in subsurface and surface Ti-sites. The polaron formation becomes more favorable by increasing the VO concentration level (up to 20%) due to the progressively lower energy cost needed to distort the lattice. However, at higher VO concentration the shortening of the averaged polaron-polaron distance leads to an increased Coulomb repulsion among the trapped charges at the Ti-sites, which weakens this trend. This instability is overtaken by means of a structural 1 × 2 surface reconstruction, characterized by a distinctively more favorable polaron distribution. The calculations are validated by a direct comparison with experimental AFM and STM data. Our study identifies a fundamentally novel mechanism to drive surface reconstructions and resolves a long standing issue on the origin of the reconstruction in rutile (110) surface.

An Assessment of Ground Level and Free Tropospheric Ozone Over California and Nevada

NASA Astrophysics Data System (ADS)

Yates, E. L.; Johnson, M. S.; Iraci, L. T.; Ryoo, J.-M.; Pierce, R. B.; Cullis, P. D.; Gore, W.; Ives, M. A.; Johnson, B. J.; Leblanc, T.; Marrero, J. E.; Sterling, C. W.; Tanaka, T.

2017-09-01

Increasing free tropospheric ozone (O3), combined with the high elevation and often deep boundary layers at western U.S. surface stations, poses challenges in attaining the more stringent 70 ppb O3 National Ambient Air Quality Standard. As such, use of observational data to identify sources and mechanisms that contribute to surface O3 is increasingly important. This work analyzes surface and vertical O3 observations over California and Nevada from 1995 to 2015. Over this period, the number of high O3 events (95th percentile) at the U.S. Environmental Protection Agency Clean Air Status and Trends Network (CASTNET) sites has decreased during summer, as a result of decreasing U.S. emissions. In contrast, an increase in springtime 5th percentile O3 indicates a general increase of baseline O3. During 2012 there was a peak in exceedances and in the average spring-summer O3 mixing ratios at CASTNET sites. Goddard Earth Observing System-Chem results show that the surface O3 attributable to transport from the upper troposphere and stratosphere was increased in 2013 compared to 2012, highlighting the importance of measurements aloft. Vertical O3 measurements from aircraft, ozonesondes, and lidar show distinct seasonal trends, with a high percentage of elevated O3 laminae (O3 > 70 ppb, 3-8 km) during spring and summer. Analysis of the timing of high O3 surface events and correlation between surface and vertical O3 data is used to discuss varying sources of western U.S. surface O3.

Determinants of aerosol lung-deposited surface area variation in an urban environment.

PubMed

Reche, Cristina; Viana, Mar; Brines, Mariola; Pérez, Noemí; Beddows, David; Alastuey, Andrés; Querol, Xavier

2015-06-01

Ultrafine particles are characterized by a high surface area per mass. Particle surface has been reported to play a significant role in determining the toxicological activity of ultrafine particles. In light of this potential role, the time variation of lung deposited surface area (LDSA) concentrations in the alveolar region was studied at the urban background environment of Barcelona (Spain), aiming to asses which processes and sources govern this parameter. Simultaneous data on Black Carbon (BC), total particle number (N) and particle number size distribution were correlated with LDSA. Average LDSA concentrations in Barcelona were 37 ± 26 μm(2)cm(-3), levels which seem to be characteristic for urban environments under traffic influence across Europe. Results confirm the comparability between LDSA data provided by the online monitor and those calculated based on particle size distributions (by SMPS), and reveal that LDSA concentrations are mainly influenced by particles in the size range 50-200 nm. A set of representative daily cycles for LDSA concentrations was obtained by means of a k-means cluster technique. The contribution of traffic emissions to daily patterns was evidenced in all the clusters, but was quantitatively different. Traffic events under stable atmospheric conditions increased mean hourly background LDSA concentrations up to 6 times, attaining levels higher than 200 μm(2)cm(-3). However, under warm and relatively clean atmospheric conditions, the traffic rush hour contribution to the daily LDSA mean appeared to be lower and the contribution of new urban particle formation events (by photochemically induced nucleation) was detected. These nucleation events were calculated to increase average background LDSA concentrations by 15-35% (maximum LDSA levels=45-50 μm(2)cm(-3)). Thereby, it may be concluded that in the urban background of Barcelona road traffic is the main source increasing the aerosol surface area which can deposit on critical regions of the human lung, followed by nucleation episodes. Copyright © 2015 Elsevier B.V. All rights reserved.

Atomic Oxygen (ATOX) simulation of Teflon FEP and Kapton H surfaces using a high intensity, low energy, mass selected, ion beam facility

NASA Technical Reports Server (NTRS)

Vered, R.; Grossman, E.; Lempert, G. D.; Lifshitz, Y.

1994-01-01

A high intensity (greater than 10(exp 15) ions/sq cm) low energy (down to 5 eV) mass selected ion beam (MSIB) facility was used to study the effects of ATOX on two polymers commonly used for space applications (Kapton H and Teflon FEP). The polymers were exposed to O(+) and Ne(+) fluences on 10(exp 15) - 10(exp 19) ions/sq cm, using 30eV ions. A variety of analytical methods were used to analyze the eroded surfaces including: (1) atomic force microscopy (AFM) for morphology measurements; (2) total mass loss measurements using a microbalance; (3) surface chemical composition using x-ray photoelectron spectroscopy (XPS), and (4) residual gas analysis (RGA) of the released gases during bombardment. The relative significance of the collisional and chemical degradation processes was evaluated by comparing the effects of Ne(+) and O(+) bombardment. For 30 eV ions it was found that the Kapton is eroded via chemical mechanisms while Teflon FEP is eroded via collisional mechanisms. AFM analysis was found very powerful in revealing the evolution of the damage from its initial atomic scale (roughness of approx. 1 nm) to its final microscopic scale (roughness greater than 1 micron). Both the surface morphology and the average roughness of the bombarded surfaces (averaged over 1 micron x 1 micron images by the system's computer) were determined for each sample. For 30 eV a non linear increase of the Kapton roughness with the O(+) fluence was discovered (a slow increase rate for fluences phi less than 5 x 10(exp 17) O(+)/sq cm, and a rapid increase rate for phi greater than 5 x 10(exp 17) O(+)/sq cm). Comparative studies on the same materials exposed to RF and DC oxygen plasmas indicate that the specific details of the erosion depend on the simulation facility emphasizing the advantages of the ion beam facility.

Thermal conductance of and heat generation in tire-pavement interface and effect on aircraft braking

NASA Technical Reports Server (NTRS)

Miller, C. D.

1976-01-01

A finite-difference analysis was performed on temperature records obtained from a free rolling automotive tire and from pavement surface. A high thermal contact conductance between tire and asphalt was found on a statistical basis. Average slip due to squirming between tire and asphalt was about 1.5 mm. Consequent friction heat was estimated as 64 percent of total power absorbed by bias-ply, belted tire. Extrapolation of results to aircraft tire indicates potential braking improvement by even moderate increase of heat absorbing capacity of runway surface.

Transient heat transfer behavior of water spray evaporative cooling on a stainless steel cylinder with structured surface for safety design application in high temperature scenario

NASA Astrophysics Data System (ADS)

Aamir, Muhammad; Liao, Qiang; Hong, Wang; Xun, Zhu; Song, Sihong; Sajid, Muhammad

2017-02-01

High heat transfer performance of spray cooling on structured surface might be an additional measure to increase the safety of an installation against any threat caused by rapid increase in the temperature. The purpose of present experimental study is to explore heat transfer performance of structured surface under different spray conditions and surface temperatures. Two cylindrical stainless steel samples were used, one with pyramid pins structured surface and other with smooth surface. Surface heat flux of 3.60, 3.46, 3.93 and 4.91 MW/m2 are estimated for sample initial average temperature of 600, 700, 800 and 900 °C, respectively for an inlet pressure of 1.0 MPa. A maximum cooling rate of 507 °C/s was estimated for an inlet pressure of 0.7 MPa at 900 °C for structured surface while for smooth surface maximum cooling rate of 356 °C/s was attained at 1.0 MPa for 700 °C. Structured surface performed better to exchange heat during spray cooling at initial sample temperature of 900 °C with a relative increase in surface heat flux by factor of 1.9, 1.56, 1.66 and 1.74 relative to smooth surface, for inlet pressure of 0.4, 0.7, 1.0 and 1.3 MPa, respectively. For smooth surface, a decreasing trend in estimated heat flux is observed, when initial sample temperature was increased from 600 to 900 °C. Temperature-based function specification method was utilized to estimate surface heat flux and surface temperature. Limited published work is available about the application of structured surface spray cooling techniques for safety of stainless steel structures at very high temperature scenario such as nuclear safety vessel and liquid natural gas storage tanks.

Improved Satellite Retrievals of NO2 and SO2 over the Canadian Oil Sands and Comparisons with Surface Measurements

NASA Technical Reports Server (NTRS)

McLinden, C. A.; Fioletov, V.; Boersma, K. F.; Kharol, S. K.; Krotkov, N.; Lamsal, L.; Makar, P. A.; Martin, R. V.; Veefkind, J. P.; Yang, K.

2014-01-01

Satellite remote sensing is increasingly being used to monitor air quality over localized sources such as the Canadian oil sands. Following an initial study, significantly low biases have been identified in current NO2 and SO2 retrieval products from the Ozone Monitoring Instrument (OMI) satellite sensor over this location resulting from a combination of its rapid development and small spatial scale. Air mass factors (AMFs) used to convert line-of-sight "slant" columns to vertical columns were re-calculated for this region based on updated and higher resolution input information including absorber profiles from a regional-scale (15 km × 15 km resolution) air quality model, higher spatial and temporal resolution surface reflectivity, and an improved treatment of snow. The overall impact of these new Environment Canada (EC) AMFs led to substantial increases in the peak NO2 and SO2 average vertical column density (VCD), occurring over an area of intensive surface mining, by factors of 2 and 1.4, respectively, relative to estimates made with previous AMFs. Comparisons are made with long-term averages of NO2 and SO2 (2005-2011) from in situ surface monitors by using the air quality model to map the OMI VCDs to surface concentrations. This new OMI-EC product is able to capture the spatial distribution of the in situ instruments (slopes of 0.65 to 1.0, correlation coefficients of greater than 0.9). The concentration absolute values from surface network observations were in reasonable agreement, with OMI-EC NO2 and SO2 biased low by roughly 30%. Several complications were addressed including correction for the interference effect in the surface NO2 instruments and smoothing and clear-sky biases in the OMI measurements. Overall these results highlight the importance of using input information that accounts for the spatial and temporal variability of the location of interest when performing retrievals.

Surface Characteristics of Green Island Wakes from Satellite Imagery

NASA Astrophysics Data System (ADS)

Cheng, Kai-Ho; Hsu, Po-Chun; Ho, Chung-Ru

2017-04-01

Characteristics of an island wake induced by the Kuroshio Current flows pass by Green Island, a small island 40 km off southeast of Taiwan is investigated by the Moderate Resolution Imaging Spectroradiometer (MODIS) satellite imagery. The MODIS sea surface temperature (SST) and chlorophyll-a (chl-a) imagery is produced at 250-meter resolution from 2014 to 2015 using the SeaDAS software package which is developed by the National Aeronautics and Space Administration. The wake occurrence is 59% observed from SST images during the data span. The average cooling area is 190 km2, but the area is significantly changed with wind directions. The wake area is increased during southerly winds and is reduced during northerly winds. Besides, the average cooling SST was about 2.1 oC between the front and rear island. Comparing the temperature difference between the wake and its left side, the difference is 1.96 oC. In addition, the wakes have 1 3 times higher than normal in chlorophyll concentration. The results indicate the island mass effect makes the surface water of Green island wake colder and chl-a higher.

The impact of the fast ion fluxes and thermal plasma loads on the design of the ITER fast ion loss detector

NASA Astrophysics Data System (ADS)

Kocan, M.; Garcia-Munoz, M.; Ayllon-Guerola, J.; Bertalot, L.; Bonnet, Y.; Casal, N.; Galdon, J.; Garcia-Lopez, J.; Giacomin, T.; Gonzalez-Martin, J.; Gunn, J. P.; Rodriguez-Ramos, M.; Reichle, R.; Rivero-Rodriguez, J. F.; Sanchis-Sanchez, L.; Vayakis, G.; Veshchev, E.; Vorpahl, C.; Walsh, M.; Walton, R.

2017-12-01

Thermal plasma loads to the ITER Fast Ion Loss Detector are studied for QDT = 10 burning plasma equilibrium using the 3D field line tracing. The simulations are performed for a FILD insertion 9-13 cm past the port plasma facing surface, optimized for fast ion measurements, and include the worst-case perturbation of the plasma boundary and the error in the magnetic reconstruction. The FILD head is exposed to superimposed time-averaged ELM heat load, static inter-ELM heat flux and plasma radiation. The study includes the estimate of the instantaneous temperature rise due to individual 0.6 MJ controlled ELMs. The maximum time-averaged surface heat load is lesssim 12 MW/m2 and will lead to increase of the FILD surface temperature well below the melting temperature of the materials considered here, for the FILD insertion time of 0.2 s. The worst-case instantaneous temperature rise during controlled 0.6 MJ ELMs is also significantly smaller than the melting temperature of e.g. Tungsten or Molybdenum, foreseen for the FILD housing.

[Plankton dynamics in the South of California Current].

PubMed

Hernández Trujillo, S; Gómez Ochoa, F; Verdugo Díaz, G

2001-03-01

We analyzed zooplankton biomass, micro- and nannophytoplankton abundance, Calanus pacificus Brodsky 1948 abundance, and sea surface temperature along the west coast of Baja California between February 1983 and September 1991. The zooplankton biovolume abundance decreased from spring to autumn. The average abundance of nannophytoplankton (< 20 microns) was generally higher than microphytoplankton (> 20 microns). Both increased 3.5 times in abundance after 1986. Seasonally, both fractions (NP and MP) were least abundant in winter and most abundant in summer and autumn. Calanus pacificus abundance was variable, but especially high in May of some years. Abundance was lowest in winter and highest in spring, dropping in summer and autumn. Sea surface temperatures averaged 21.5 degrees C, with highest in autumn (24.2 degrees C) and the lowest in spring (17.9 degrees C). C. pacificus abundance and sea surface temperature were inversely related by cruise, season, and latitude. The phytoplankton abundance and zooplankton biomass and C. pacificus abundance showed low and high abundance patterns coincident with warming and cooling events (El Niño-La Niña).

The Influence of depth and surface waves on marine current turbine performance

NASA Astrophysics Data System (ADS)

Lust, Ethan; Flack, Karen; Luznik, Luksa; van Benthem, Max; Walker, Jessica

2013-11-01

Performance characteristics are presented for a 1/25th scale marine current turbine operating in calm conditions and in the presence of intermediate and deep water waves. The two-bladed turbine has radius of 0.4 m and a maximum blade pitch of 17°. The hydrofoil is a NACA63-618 which was selected to be Reynolds number independent for lift in the operational range (ReC = 2 - 4 × 105) . The experiments were performed in the 116 m tow-tank at the United States Naval Academy at depths of 0.8D and 1.75D measured from the blade tip to the mean free surface. Overall average values for power and thrust coefficient were found to be insensitive to wave form and weakly sensitive to turbine depth. Waves yield a small increase in turbine performance which can be explained by Stokes drift. Variations on performance parameters are on the same order of magnitude as the average value especially near the mean free surface and in the presence of high energy waves. Office of Naval Research.

The Impact of Transported Pollution on Arctic Climate

NASA Astrophysics Data System (ADS)

Quinn, P.; Stohl, A.; Arneth, A.; Berntsen, T.; Burkhart, J. F.; Flanner, M. G.; Kupiainen, K.; Shepherd, M.; Shevchenko, V. P.; Skov, H.; Vestreng, V.

2011-12-01

Arctic temperatures have increased at almost twice the global average rate over the past 100 years. Warming in the Arctic has been accompanied by an earlier onset of spring melt, a lengthening of the melt season, changes in the mass balance of the Greenland ice sheet, and a decrease in sea ice extent. Short-lived, climate warming pollutants such as black carbon (BC) have recently gained attention as a target for immediate mitigation of Arctic warming in addition to reductions in long lived greenhouse gases. Model calculations indicate that BC increases surface temperatures within the Arctic primarily through deposition on snow and ice surfaces with a resulting decrease in surface albedo and increase in absorbed solar radiation. In 2009, the Arctic Monitoring and Assessment Program (AMAP) established an Expert Group on BC with the goal of identifying source regions and energy sectors that have the largest impact on Arctic climate. Here we present the results of this work and investigate links between mid-latitude pollutants and Arctic climate.

How Well Can We Estimate Areal-Averaged Spectral Surface Albedo from Ground-Based Transmission in an Atlantic Coastal Area?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kassianov, Evgueni I.; Barnard, James C.; Flynn, Connor J.

Areal-averaged albedos are particularly difficult to measure in coastal regions, because the surface is not homogenous, consisting of a sharp demarcation between land and water. With this difficulty in mind, we evaluate a simple retrieval of areal-averaged surface albedo using ground-based measurements of atmospheric transmission alone under fully overcast conditions. To illustrate the performance of our retrieval, we find the areal-averaged albedo using measurements from the Multi-Filter Rotating Shadowband Radiometer (MFRSR) at five wavelengths (415, 500, 615, 673, and 870 nm). These MFRSR data are collected at a coastal site in Graciosa Island, Azores supported by the U.S. Department ofmore » Energy’s (DOE’s) Atmospheric Radiation Measurement (ARM) Program. The areal-averaged albedos obtained from the MFRSR are compared with collocated and coincident Moderate Resolution Imaging Spectroradiometer (MODIS) white-sky albedo at four nominal wavelengths (470, 560, 670 and 860 nm). These comparisons are made during a 19-month period (June 2009 - December 2010). We also calculate composite-based spectral values of surface albedo by a weighted-average approach using estimated fractions of major surface types observed in an area surrounding this coastal site. Taken as a whole, these three methods of finding albedo show spectral and temporal similarities, and suggest that our simple, transmission-based technique holds promise, but with estimated errors of about ±0.03. Additional work is needed to reduce this uncertainty in areas with inhomogeneous surfaces.« less

Stable near-surface ocean salinity stratifications due to evaporation observed during STRASSE

NASA Astrophysics Data System (ADS)

Asher, William E.; Jessup, Andrew T.; Clark, Dan

2014-05-01

Under conditions with a large solar flux and low wind speed, a stably stratified warm layer forms at the ocean surface. Evaporation can then lead to an increase in salinity in the warm layer. A large temperature gradient will decrease density enough to counter the density increase caused by the salinity increase, forming a stable positive salinity anomaly at the surface. If these positive salinity anomalies are large in terms of the change in salinity from surface to the base of the gradient, if their areal coverage is a significant fraction of the satellite footprint, and if they persist long enough to be in the satellite field of view, they could be relevant for calibration and validation of L-band microwave salinity measurements. A towed, surface-following profiler was deployed from the N/O Thalassa during the Subtropical Atlantic Surface Salinity Experiment (STRASSE). The profiler measured temperature and conductivity in the surface ocean at depths of 10, 50, and 100 cm. The measurements show that positive salinity anomalies are common at the ocean surface for wind speeds less than 4 m s-1 when the average daily insolation is >300 W m-2 and the sea-to-air latent heat flux is greater than zero. A semiempirical model predicts the observed dependence of measured anomalies on environmental conditions. However, the model results and the field data suggest that these ocean surface salinity anomalies are not large enough in terms of the salinity difference to significantly affect microwave radiometric measurements of salinity.

Changes in pore structure of coal caused by coal-to-gas bioconversion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Rui; Liu, Shimin; Bahadur, Jitendra

Microbial enhanced coalbed methane (ME-CBM) recovery is critically examined as a viable technology for natural gas recovery from coalbed methane (CBM) reservoirs. Since the majority of gas-in-place (GIP) is stored as an adsorbed phase in fine pores of coal matrix, the nano-pore structure directly influences gas storage and transport properties. Only limited studies have quantified the alteration of the nano-pore structure due to ME-CBM treatment. This study examines the evolution of the pore structure using a combination of small angle X-ray scattering (SAXS), low-pressure N 2 and CO 2 adsorption (LPGA) and high-pressure methane adsorption methods. The results show thatmore » the surface fractal dimension decreases for the two bioconverted coals compared to the untreated coal. After bio-treatment, the mesopore surface area and pore volume decrease with the average pore diameter increases, while the micropore surface area increases with pore volume decreases. Both inaccessible meso-/micropore size distributions decrease after bioconversion, while the accessible micropore size distribution increases, making a portion of closed micropore network accessible. In addition, the methane adsorption capacities increase after bio-treatment, which is confirmed by the increase of micropore surface area. A conceptual physical model of methanogenesis is proposed based on the evolution of the pore structure.« less

Changes in pore structure of coal caused by coal-to-gas bioconversion

DOE PAGES

Zhang, Rui; Liu, Shimin; Bahadur, Jitendra; ...

2017-06-19

Microbial enhanced coalbed methane (ME-CBM) recovery is critically examined as a viable technology for natural gas recovery from coalbed methane (CBM) reservoirs. Since the majority of gas-in-place (GIP) is stored as an adsorbed phase in fine pores of coal matrix, the nano-pore structure directly influences gas storage and transport properties. Only limited studies have quantified the alteration of the nano-pore structure due to ME-CBM treatment. This study examines the evolution of the pore structure using a combination of small angle X-ray scattering (SAXS), low-pressure N 2 and CO 2 adsorption (LPGA) and high-pressure methane adsorption methods. The results show thatmore » the surface fractal dimension decreases for the two bioconverted coals compared to the untreated coal. After bio-treatment, the mesopore surface area and pore volume decrease with the average pore diameter increases, while the micropore surface area increases with pore volume decreases. Both inaccessible meso-/micropore size distributions decrease after bioconversion, while the accessible micropore size distribution increases, making a portion of closed micropore network accessible. In addition, the methane adsorption capacities increase after bio-treatment, which is confirmed by the increase of micropore surface area. A conceptual physical model of methanogenesis is proposed based on the evolution of the pore structure.« less

Linkages Between Global Vegetation and Climate: An Analysis Based on NOAA Advanced Very High Resolution Radiometer Data. Degree awarded by Vrije Universiteit, Amsterdam, Netherlands

NASA Technical Reports Server (NTRS)

Los, Sietse Oene

1998-01-01

A monthly global 1 degree by 1 degree data set from 1982 until 1990 was derived from data collected by the Advanced Very High Resolution Radiometer on board the NOAA 7, 9, and 11 satellites. This data set was used to study the interactions between variations in climate and variations in the "greenness" of vegetation. Studies with the Colorado State University atmospheric general circulation model coupled to the Simple Biosphere model showed a large sensitivity of the hydrological balance to changes in vegetation at low latitudes. The depletion of soil moisture as a result of increased vegetation density provided a negative feedback in an otherwise positive association between increased vegetation, increased evaporation, and increased precipitation proposed by Charney and coworkers. Analysis of climate data showed, at temperate to high latitudes, a positive association between variation in land surface temperature, sea surface temperature and vegetation greenness. At low latitudes the data indicated a positive association between variations in sea surface temperature, rainfall and vegetation greenness. The variations in mid- to high latitude temperatures affected the global average greenness and this could provide an explanation for the increased carbon uptake by the terrestrial surface over the past couple of decades.

Radar characteristics of Viking 1 landing sites

USGS Publications Warehouse

Tyler, G.L.; Campbell, D.B.; Downs, G.S.; Green, R.R.; Moore, H.J.

1976-01-01

Radar observations of Mars at centimeter wavelengths in May, June, and July 1976 provided estimates of surface roughness and reflectivity in three potential landing areas for Viking 1. Surface roughness is characterized by the distribution of surface landing slopes or tilts on lateral scales of the order of 1 to 10 meters; measurements of surface reflectivity are indicators of bulk surface density in the uppermost few centimeters. By these measures, the Viking 1 landing site at 47.5??W, 22.4??N is rougher than the martian average, although it may be near the martian average for elevations accessible to Viking, and is estimated to be near the Mars average in reflectivity. The AINW site at the center of Chryse Planitia, 43.5??W, 23.4??N, may be an area of anomalous radar characteristics, indicative of extreme, small-scale roughness, very low surface density, or a combination of these two characteristics. Low signal-to-noise ratio observations of the original Chryse site at 34??W, 19.5??N indicate that that area is at least twice as rough as the Mars average.

Generation of hierarchical pore systems in the titanosilicate ETS-10 by hydrogen peroxide treatment under microwave irradiation.

PubMed

Pavel, Claudiu C; Schmidt, Wolfgang

2006-02-28

Supermicropores and well-defined mesopores with an average size of 10 nm were created in ETS-10 structure by post-synthesis treatment with H2O2 under microwave irradiation. Macropores were also formed and the external surface area of the material was increased during the treatment.

The pore structure and fractal characteristics of shales with low thermal maturity from the Yuqia Coalfield, northern Qaidam Basin, northwestern China

NASA Astrophysics Data System (ADS)

Hou, Haihai; Shao, Longyi; Li, Yonghong; Li, Zhen; Zhang, Wenlong; Wen, Huaijun

2018-03-01

The continental shales from the Middle Jurassic Shimengou Formation of the northern Qaidam Basin, northwestern China, have been investigated in recent years because of their shale gas potential. In this study, a total of twenty-two shale samples were collected from the YQ-1 borehole in the Yuqia Coalfield, northern Qaidam Basin. The total organic carbon (TOC) contents, pore structure parameters, and fractal characteristics of the samples were investigated using TOC analysis, low-temperature nitrogen adsorption experiments, and fractal analysis. The results show that the average pore size of the Shimengou shales varied from 8.149 nm to 20.635 nm with a mean value of 10.74 nm, which is considered mesopore-sized. The pores of the shales are mainly inkbottle- and slit-shaped. The sedimentary environment plays an essential role in controlling the TOC contents of the low maturity shales, with the TOC values of shales from deep to semi-deep lake facies (mean: 5.23%) being notably higher than those of the shore-shallow lake facies (mean: 0.65%). The fractal dimensions range from 2.4639 to 2.6857 with a mean of 2.6122, higher than those of marine shales, which indicates that the pore surface was rougher and the pore structure more complex in these continental shales. The fractal dimensions increase with increasing total pore volume and total specific surface area, and with decreasing average pore size. With increasing TOC contents in shales, the fractal dimensions increase first and then decrease, with the highest value occurring at 2% of TOC content, which is in accordance with the trends between the TOC and both total specific surface area and total pore volume. The pore structure complexity and pore surface roughness of these low-maturity shales would be controlled by the combined effects of both sedimentary environments and the TOC contents.

Using an implicitly-coupled hydrologic and river-operations models to investigate the trade-offs of artificial recharge in agricultural areas

NASA Astrophysics Data System (ADS)

Morway, E. D.; Niswonger, R. G.; Triana, E.

2016-12-01

In irrigated agricultural regions supplied by both surface-water and groundwater, increased reliance on groundwater during sustained drought leads to long-term water table drawdown and subsequent surface-water losses. This, in turn, may threaten the sustainability of the irrigation project. To help offset groundwater resource losses and restore water supply reliability, an alternative management strategy commonly referred to as managed aquifer recharge (MAR) in agricultural regions helps mitigate long-term aquifer drawdown and provides additional water for subsequent withdraw. Sources of MAR in this investigation are limited to late winter runoff in years with above average precipitation (i.e., above average snowpack). However, where winter MAR results in an elevated water table, non-beneficial consumptive use may increase from evapotranspiration in adjacent and down-gradient fallow and naturally vegetated lands. To rigorously explore this trade-off, the recently published MODSIM-MODFLOW model was applied to quantify both the benefits and unintended consequences of MAR. MODSIM-MODFLOW is a generalized modeling tool capable of exploring the effects of altered river operations within an integrated groundwater and surface-water (GW-SW) model. Thus, the MODSIM-MODFLOW model provides a modeling platform capable of simulating MAR in amounts and duration consistent with other senior water rights in the river system (e.g., minimum in-stream flow requirements). Increases in non-beneficial consumptive use resulting from winter MAR are evaluated for a hypothetical model patterned after alluvial aquifers common in arid and semi-arid areas of the western United States. Study results highlight (1) the benefit of an implicitly-coupled river operations and hydrologic modeling tool, (2) the balance between winter MAR and the potential increase in non-beneficial consumptive use, and (3) conditions where MAR may or may not be an appropriate management option, such as the availability of surface-water storage.

Pressure and heat-transfer distributions in a simulated wing-elevon cove with variable leakage at a free-stream Mach number of 6.9

NASA Technical Reports Server (NTRS)

Deveikis, W. D.; Bartlett, W.

1978-01-01

An experimental aerodynamic heating investigation was conducted to determine effects of hot boundary-layer ingestion into the cove on the windward surface between a wing and elevon for cove seal leak areas nominally between 0 and 100 percent of cove entrance area. Pressure and heating-rate distributions were obtained on the wing and elevon surfaces and on the cove walls of a full-scale model that represented a section of the cove region on the space shuttle orbiter. Data were obtained for both attached and separated turbulent boundary layers upstream of the unswept cove entrance. Average free-stream Mach number was 6.9, average free-stream unit Reynolds numbers were 1.31 x 10 to the 6th power and 4.40 x 10 to the 6th power per meter (0.40 x 10 to the 6th power and 1.34 x 10 to the 6th power per foot), and average total temperature was 1888 K (3400 R). Cove pressures and heating rates varied as a function of seal leak area independent of leak aspect ratio. Although cove heating rates for attached flow did not appear intolerable, it was postulated that convective heating in the cove may increase with time. For separated flow, the cove environment was considered too severe for unprotected interior structures of control surfaces.

[Macrocephalic spermatozoa. What would be the impact on reproduction?].

PubMed

Guichaoua, M-R; Mercier, G; Geoffroy-Siraudin, C; Paulmyer-Lacroix, O; Lanteaume, A; Metzler-Guillemin, C; Perrin, J; Achard, V

2009-09-01

We want to highlight the risk of infertility and failure of Assisted Reproductive Technologies due to the presence of macrocephalic spermatozoa (MS) in the sperm at rate equalling or superior to 20% in at least one semen analysis. We did a retrospective analysis of 19 infertile patients presenting MS at average rate between 14.3 and 49.7%. For each patient, at least one semen analysis showed a MS rate equal or superior to 20%. We did an automated analysis of the spermatozoa surface for 13 patients and a detailed analysis of the MS morphology in 18 patients. Thirteen couples benefited of one or more IVF with or without ICSI. The semen analysis shows an impairment of one or more parameter of the sperm in all patients. Three morphological aspects for MS were highlighted: MS with irregular head, MS with regular head, and MS with multiple heads, with a dominance of irregular heads. The spermatozoa surface analysis shows a significant increase of the average surface and of the standard deviation (p<0.0001). The average rate of pregnancies by transfer is decreased compared to usual rates in our laboratories (13% versus 28%). We want to sensitize biologist and clinical doctors to the existence of partial forms of this syndrome, which could be related to infertility with impaired sperm parameters and low pregnancy rates after FIV or ICSI.

On the role of atmosphere-ocean interactions in the expected long-term changes of the Earth's ozone layer caused by greenhouse gases

NASA Astrophysics Data System (ADS)

Zadorozhny, Alexander; Dyominov, Igor

It is well known that anthropogenic emissions of greenhouse gases into the atmosphere produce a global warming of the troposphere and a global cooling of the stratosphere. The expected stratospheric cooling essentially influences the ozone layer via increased polar stratospheric cloud formation and via temperature dependences of the gas phase reaction rates. One more mechanism of how greenhouse gases influences the ozone layer is enhanced water evaporation from the oceans into the atmosphere because of increasing temperatures of the ocean surface due to greenhouse effect. The subject of this paper is a study of the influence of anthropogenic pollution of the atmosphere by the greenhouse gases CO2, CH4, N2O and ozone-depleting chlorine and bromine compounds on the expected long-term changes of the ozone layer with taking into account an increase of water vapour content in the atmosphere due to greenhouse effect. The study based on 2-D zonally averaged interactive dynamical radiative-photochemical model of the troposphere and stratosphere. The model allows to self-consistently calculating diabatic circulation, temperature, gaseous composition of the troposphere and stratosphere at latitudes from the South to North Poles, as well as distribution of sulphate aerosol particles and polar stratospheric clouds of two types. It was supposed in the model that an increase of the ocean surface temperature caused by greenhouse effect is similar to calculated increase of atmospheric surface temperature. Evaporation rate from the ocean surface was computed in dependence of latitude. The model time-dependent runs were made for the period from 1975 to 2100 using two IPCC scenarios depicting maximum and average expected increases of greenhouse gases in the atmosphere. The model calculations show that anthropogenic increasing of water vapour abundance in the atmosphere due to heating of the ocean surface caused by greenhouse effect gives a sensible contribution to the expected ozone changes. The enhanced evaporation from the ocean increases noticeably a water vapour abundance in the stratosphere that decreases global total ozone and retards the expected recovery of the ozone layer. In polar latitudes, additional stratospheric water vapour increase due to greenhouse effect noticeably strengthens the impact of anthropogenic greenhouse gases on ozone through modification of polar stratospheric clouds and retards the expected recovery of the ozone, too. In the Northern hemisphere, the delay of the ozone recovery is about 5 years, in the Southern hemisphere the delay is about 2 years.

Impact of fire on global land surface air temperature and energy budget for the 20th century due to changes within ecosystems

NASA Astrophysics Data System (ADS)

Li, Fang; Lawrence, David M.; Bond-Lamberty, Ben

2017-04-01

Fire is a global phenomenon and tightly interacts with the biosphere and climate. This study provides the first quantitative assessment and understanding of fire’s influence on the global annual land surface air temperature and energy budget through its impact on terrestrial ecosystems. Fire impacts are quantified by comparing fire-on and fire-off simulations with the Community Earth System Model (CESM). Results show that, for the 20th century average, fire-induced changes in terrestrial ecosystems significantly increase global land annual mean surface air temperature by 0.18 °C, decrease surface net radiation and latent heat flux by 1.08 W m-2 and 0.99 W m-2, respectively, and have limited influence on sensible heat flux (-0.11 W m-2) and ground heat flux (+0.02 W m-2). Fire impacts are most clearly seen in the tropical savannas. Our analyses suggest that fire increases surface air temperature predominantly by reducing latent heat flux, mainly due to fire-induced damage to the vegetation canopy, and decreases net radiation primarily because fire-induced surface warming significantly increases upward surface longwave radiation. This study provides an integrated estimate of fire and induced changes in ecosystems, climate, and energy budget at a global scale, and emphasizes the importance of a consistent and integrated understanding of fire effects.

A thickness-weighted average perspective of force balance in an idealized circumpolar current

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ringler, Todd Darwin; Saenz, Juan Antonio; Wolfram, Jr., Phillip Justin

The exact, three-dimensional thickness-weighted averaged (TWA) Boussinesq equations are used to diagnose eddy-mean flow interaction in an idealized circumpolar current (ICC). The force exerted by mesoscale eddies on the TWA velocity is expressed as the divergence of the Eliassen-Palm flux tensor. Consistent with previous findings, the analysis indicates that the dynamically relevant definition of the ocean surface layer is comprised of the set of buoyancy coordinates that ever reside at the ocean surface at a given horizontal position. The surface layer is found to be a physically distinct object with a diabatic- and force-balance that is largely isolated from themore » underlying adiabatic region in the interior. Within the ICC surface layer, the TWA meridional velocity is southward/northward in the top/bottom half, and has a value near zero at the bottom. In the top half of the surface layer, the zonal forces due to wind stress and meridional advection of potential vorticity act to accelerate the TWA zonal velocity; equilibrium is obtained by eddies decelerating the zonal flow via a downward flux of eastward momentum that increases with depth. In the bottom half of the surface layer, the accelerating force of the wind stress is balanced by the eddy force and meridional advection of potential vorticity. The bottom of the surface layer coincides with the location where the zonal eddy force, meridional advection of potential vorticity and zonal wind stress force are all zero. The net meridional transport, S f, within the surface layer is a small residual of its southward and northward TWA meridional flows. Furthermore, the mean meridional gradient of surface-layer buoyancy is advected by S f to balance the surface buoyancy fluxs.« less

A thickness-weighted average perspective of force balance in an idealized circumpolar current

DOE PAGES

Ringler, Todd Darwin; Saenz, Juan Antonio; Wolfram, Jr., Phillip Justin; ...

2016-11-22

The exact, three-dimensional thickness-weighted averaged (TWA) Boussinesq equations are used to diagnose eddy-mean flow interaction in an idealized circumpolar current (ICC). The force exerted by mesoscale eddies on the TWA velocity is expressed as the divergence of the Eliassen-Palm flux tensor. Consistent with previous findings, the analysis indicates that the dynamically relevant definition of the ocean surface layer is comprised of the set of buoyancy coordinates that ever reside at the ocean surface at a given horizontal position. The surface layer is found to be a physically distinct object with a diabatic- and force-balance that is largely isolated from themore » underlying adiabatic region in the interior. Within the ICC surface layer, the TWA meridional velocity is southward/northward in the top/bottom half, and has a value near zero at the bottom. In the top half of the surface layer, the zonal forces due to wind stress and meridional advection of potential vorticity act to accelerate the TWA zonal velocity; equilibrium is obtained by eddies decelerating the zonal flow via a downward flux of eastward momentum that increases with depth. In the bottom half of the surface layer, the accelerating force of the wind stress is balanced by the eddy force and meridional advection of potential vorticity. The bottom of the surface layer coincides with the location where the zonal eddy force, meridional advection of potential vorticity and zonal wind stress force are all zero. The net meridional transport, S f, within the surface layer is a small residual of its southward and northward TWA meridional flows. Furthermore, the mean meridional gradient of surface-layer buoyancy is advected by S f to balance the surface buoyancy fluxs.« less

Reduction of Crosshatch Roughness and Threading Dislocation Density in Metamorphic GaInP Buffers and GaInAs Solar Cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

France, R. M.; Geisz, J. F.; Steiner, M. A.

Surface crosshatch roughness typically develops during the growth of lattice-mismatched compositionally graded buffers and can limit misfit dislocation glide. In this study, the crosshatch roughness during growth of a compressive GaInP/GaAs graded buffer is reduced by increasing the phosphine partial pressure throughout the metamorphic growth. Changes in the average misfit dislocation length are qualitatively determined by characterizing the threading defect density and residual strain. The decrease of crosshatch roughness leads to an increase in the average misfit dislocation glide length, indicating that the surface roughness is limiting dislocation glide. Growth rate is also analyzed as a method to reduce surfacemore » crosshatch roughness and increase glide length, but has a more complicated relationship with glide kinetics. Using knowledge gained from these experiments, high quality inverted GaInAs 1 eV solar cells are grown on a GaInP compositionally graded buffer with reduced roughness and threading dislocation density. The open circuit voltage is only 0.38 V lower than the bandgap potential at a short circuit current density of 15 mA/cm{sup 2}, suggesting that there is very little loss due to the lattice mismatch.« less

Surface morphology of vacuum-evaporated pentacene film on Si substrate studied by in situ grazing-incidence small-angle X-ray scattering: I. The initial stage of formation of pentacene film

NASA Astrophysics Data System (ADS)

Hirosawa, Ichiro; Watanabe, Takeshi; Koganezawa, Tomoyuki; Kikuchi, Mamoru; Yoshimoto, Noriyuki

2018-03-01

The progress of the surface morphology of a growing sub-monolayered pentacene film on a Si substrate was studied by in situ grazing-incidence small angle X-ray scattering (GISAXS). The observed GISAXS profiles did not show sizes of pentacene islands but mainly protuberances on the boundaries around pentacene film. Scattering of X-ray by residual pits in the pentacene film was also detected in the GISAXS profiles of an almost fully covered film. The average radius of pentacene protuberances increased from 13 to 24 nm as the coverage increased to 0.83 monolayer, and the most frequent radius was almost constant at approximately 9 nm. This result suggests that the population of larger protuberances increase with increasing lengths of boundaries of the pentacene film. It can also be considered that the detected protuberances were crystallites of pentacene, since the average size of protuberances was nearly equal to crystallite sizes of pentacene films. The almost constant characteristic distance of 610 nm and amplitudes of pair correlation functions at low coverages suggest that the growth of pentacene films obeyed the diffusion-limited aggregation (DLA) model, as previously reported. It is also considered that the sites of islands show a triangular distribution for small variations of estimated correlation distances.

Increasing Wastage of the Bering and Malaspina Glacier Systems, Alaska-Yukon, 1972 to 2006

NASA Astrophysics Data System (ADS)

Muskett, R. R.; Lingle, C. S.; Sauber, J. M.; Tangborn, W. V.; Rabus, B. T.; Echelmeyer, K. A.

2007-12-01

Ice dynamics are integral to the net mass balances of the huge Bagley-Bering and Seward-Malaspina Glacier systems of south-central Alaska. Quasi-periodic surging of the main trunks and some large tributaries of these exceptionally active glacier systems are important contributors to their increasing volume losses in the present rapidly-warming climate, because surges rapidly transport ice from higher elevations, where it is "safe," to lower elevations where it subject to increased ablation. New estimates of mass losses from the Bering and Malaspina Glacier systems during 1972-2006 were derived from analysis of (i) digital elevation models (DEMs) synthesized from airborne and spaceborne interferometric synthetic aperture radar (InSAR); (ii) small-aircraft laser altimetry; and (iii) spaceborne laser altimetry acquired by ICESat. Adjustments for estimated seasonal snow accumulation were applied to datasets acquired at times subsequent to late summer. Adjustments for systematic DEM biases were also applied. The area-average lowering rate on the main-trunk of the Bering Glacier system from 1972 to 1995 was 0.9 ± 0.1 m/yr. The major 1993 to '95 surge moved ice rapidly from the surge reservoir into the piedmont lobe where rapid surface melting was facilitated by the heavily crevassed surface. The lowering rate accelerated to 3.0 ± 0.1 m/yr during 1995 to 2000, then moderated to 1.4 ± 0.1 m/yr during 2000 to 2003. On the Malaspina Glacier system, the area-average rate of surface lowering was 1.4 ± 0.1 m/yr during 1972 to 1999. It then increased by 30% to 1.8 ± 0.1 m/yr during 1999 to 2002. Near-concurrent surges of Agassiz Glacier (a west piedmont lobe tributary), lower Seward Glacier (main source for the central Seward lobe), and Marvine Glacier (a detached former tributary of the eastern piedmont lobe) were observed during this 3-year time span of increased surface lowering. Recent ICESat-derived elevation changes from 2003 to 2006 indicate increasing wastage on the Malaspina piedmont lobe. By contrast, its main accumulation area, upper Seward Glacier, which was drawn down by the 1999-2002 surge, is showing recovery with increasing surface elevations. Concurrently, elevations on Bagley Ice Valley are also increasing in preparation, evidently, for the next surge of the Bering Glacier system. For both of these large glacier systems we estimate a combined volume loss of 254.0 ± 16.5 km3 (water equivalent) over an area of 7734 km2 during 1972 to 2003, representing over 80% and 70% of the areas of the Bering and Malaspina Glacier systems, respectively. This is equivalent to a mean surface lowering of 31 to 35 meters. These glaciers are making an increasing contribution to globally-rising sea-level.

Giant dipole resonance and shape transitions in hot and rotating 88Mo

NASA Astrophysics Data System (ADS)

Rhine Kumar, A. K.; Arumugam, P.; Dang, N. Dinh; Mazumdar, I.

2017-08-01

The giant dipole resonance (GDR) observables are calculated within the thermal shape fluctuation model by considering the probability distributions of different angular momentum (I ) and temperature (T ) values estimated recently in the deexcitation process of the compound nucleus 88Mo. These results are found to be very similar to the results obtained with the average T (Tave) and average I (Iave) corresponding to those distributions. The shape transitions in 88Mo at different T and I are also studied through the free energy surfaces calculated within the microscopic-macroscopic approach. The deformation of 88Mo is found to increase considerably with T and I , leading to the Jacobi shape transition at I ˜50 ℏ . The combined effect of increasing deformation, larger fluctuations at higher T , and larger Coriolis splitting of GDR components at higher I , leads to a rapid increase in the GDR width.

Accuracy of computer-assisted navigation: significant augmentation by facial recognition software.

PubMed

Glicksman, Jordan T; Reger, Christine; Parasher, Arjun K; Kennedy, David W

2017-09-01

Over the past 20 years, image guidance navigation has been used with increasing frequency as an adjunct during sinus and skull base surgery. These devices commonly utilize surface registration, where varying pressure of the registration probe and loss of contact with the face during the skin tracing process can lead to registration inaccuracies, and the number of registration points incorporated is necessarily limited. The aim of this study was to evaluate the use of novel facial recognition software for image guidance registration. Consecutive adults undergoing endoscopic sinus surgery (ESS) were prospectively studied. Patients underwent image guidance registration via both conventional surface registration and facial recognition software. The accuracy of both registration processes were measured at the head of the middle turbinate (MTH), middle turbinate axilla (MTA), anterior wall of sphenoid sinus (SS), and nasal tip (NT). Forty-five patients were included in this investigation. Facial recognition was accurate to within a mean of 0.47 mm at the MTH, 0.33 mm at the MTA, 0.39 mm at the SS, and 0.36 mm at the NT. Facial recognition was more accurate than surface registration at the MTH by an average of 0.43 mm (p = 0.002), at the MTA by an average of 0.44 mm (p < 0.001), and at the SS by an average of 0.40 mm (p < 0.001). The integration of facial recognition software did not adversely affect registration time. In this prospective study, automated facial recognition software significantly improved the accuracy of image guidance registration when compared to conventional surface registration. © 2017 ARS-AAOA, LLC.

Negating Tissue Contracture Improves Volume Maintenance and Longevity of In Vivo Engineered Tissues.

PubMed

Lytle, Ian F; Kozlow, Jeffrey H; Zhang, Wen X; Buffington, Deborah A; Humes, H David; Brown, David L

2015-10-01

Engineering large, complex tissues in vivo requires robust vascularization to optimize survival, growth, and function. Previously, the authors used a "chamber" model that promotes intense angiogenesis in vivo as a platform for functional three-dimensional muscle and renal engineering. A silicone membrane used to define the structure and to contain the constructs is successful in the short term. However, over time, generated tissues contract and decrease in size in a manner similar to capsular contracture seen around many commonly used surgical implants. The authors hypothesized that modification of the chamber structure or internal surface would promote tissue adherence and maintain construct volume. Three chamber configurations were tested against volume maintenance. Previously studied, smooth silicone surfaces were compared to chambers modified for improved tissue adherence, with multiple transmembrane perforations or lined with a commercially available textured surface. Tissues were allowed to mature long term in a rat model, before analysis. On explantation, average tissue masses were 49, 102, and 122 mg; average volumes were 74, 158 and 176 μl; and average cross-sectional areas were 1.6, 6.7, and 8.7 mm for the smooth, perforated, and textured groups, respectively. Both perforated and textured designs demonstrated significantly greater measures than the smooth-surfaced constructs in all respects. By modifying the design of chambers supporting vascularized, three-dimensional, in vivo tissue engineering constructs, generated tissue mass, volume, and area can be maintained over a long time course. Successful progress in the scale-up of construct size should follow, leading to improved potential for development of increasingly complex engineered tissues.

Application and Analysis of Measurement Model for Calibrating Spatial Shear Surface in Triaxial Test

NASA Astrophysics Data System (ADS)

Zhang, Zhihua; Qiu, Hongsheng; Zhang, Xiedong; Zhang, Hang

2017-12-01

Discrete element method has great advantages in simulating the contacts, fractures, large displacement and deformation between particles. In order to analyze the spatial distribution of the shear surface in the three-dimensional triaxial test, a measurement model is inserted in the numerical triaxial model which is generated by weighted average assembling method. Due to the non-visibility of internal shear surface in laboratory, it is largely insufficient to judge the trend of internal shear surface only based on the superficial cracks of sheared sample, therefore, the measurement model is introduced. The trend of the internal shear zone is analyzed according to the variations of porosity, coordination number and volumetric strain in each layer. It shows that as a case study on confining stress of 0.8 MPa, the spatial shear surface is calibrated with the results of the rotated particle distribution and the theoretical value with the specific characteristics of the increase of porosity, the decrease of coordination number, and the increase of volumetric strain, which represents the measurement model used in three-dimensional model is applicable.

Nanopolishing by colloidal nanodiamond in elastohydrodynamic lubrication

NASA Astrophysics Data System (ADS)

Shirvani, Khosro A.; Mosleh, Mohsen; Smith, Sonya T.

2016-08-01

In this paper, the feasibility of using explosion synthesized diamond nanoparticles with an average particle size (APS) of 3-5 nm with a concentration of 1 % by weight for improving lubrication and friction in elastohydrodynamic lubrication (EHL) was investigated. Owing to the orders of magnitude increase in the viscosity of the lubricant in the EHL contact zone, diamond nanoparticles in the lubricant polish the surfaces at the nanoscale which decreases the composite roughness of contacting surfaces. The reduced composite roughness results in an increased film thickness ratio which yields lower friction. In the numerical analysis, governing equations of lubricant flow in the full elastohydrodynamic lubrication were solved, and the shear stress distribution over the fluid film was calculated. Using an abrasion model and the shear stress distribution profile, the material removal by the nanofluid containing nanoparticles and the resultant surface roughness were determined. The numerical analysis showed that in full EHL regime, the nanolubricant can reduce the composite roughness of moving surfaces. Experimental results from prior studies which exhibited surface polishing by such nanolubricants in boundary, mixed, and full elastohydrodynamic lubrication were used for comparison to the numerical model.

Surface properties tuning of welding electrode-deposited hardfacings by laser heat treatment

NASA Astrophysics Data System (ADS)

Oláh, Arthur; Croitoru, Catalin; Tierean, Mircea Horia

2018-04-01

In this paper, several Cr-Mn-rich hardfacings have been open-arc deposited on S275JR carbon quality structural steel and further submitted to laser treatment at different powers. An overall increase with 34-98% in the average microhardness and wear resistance of the coatings has been obtained, due to the formation of martensite, silicides, as well as simple and complex carbides on the surface of the hardfacings, in comparison with the reference, not submitted to laser thermal treatment. Surface laser treatment of electrode-deposited hardfacings improves their chemical resistance under corrosive saline environments, as determined by the 43% lower amount of leached iron and respectively, 28% lower amount of manganese ions leached in a 10% wt. NaCl aqueous solution, comparing with the reference hardfacings. Laser heat treatment also promotes better compatibility of the hardfacings with water-based paints and oil-based paints and primers, through the relative increasing in the polar component of the surface energy (with up to 65%) which aids both water and filler spreading on the metallic surface.

Surface transport processes in charged porous media

DOE PAGES

Gabitto, Jorge; Tsouris, Costas

2017-03-03

Surface transport processes are important in chemistry, colloidal sciences, engineering, biology, and geophysics. Natural or externally produced charges on surfaces create electrical double layers (EDLs) at the solid-liquid interface. The existence of the EDLs produces several complex processes including bulk and surface transport of ions. In this work, a model is presented to simulate bulk and transport processes in homogeneous porous media comprising big pores. It is based on a theory for capacitive charging by ideally polarizable porous electrodes without Faradaic reactions or specific adsorption of ions. A volume averaging technique is used to derive the averaged transport equations inmore » the limit of thin electrical double layers. Description of the EDL between the electrolyte solution and the charged wall is accomplished using the Gouy-Chapman-Stern (GCS) model. The surface transport terms enter into the average equations due to the use of boundary conditions for diffuse interfaces. Two extra surface transports terms appear in the closed average equations. One is a surface diffusion term equivalent to the transport process in non-charged porous media. The second surface transport term is a migration term unique to charged porous media. The effective bulk and transport parameters for isotropic porous media are calculated solving the corresponding closure problems.« less

Surface transport processes in charged porous media

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gabitto, Jorge; Tsouris, Costas

Surface transport processes are important in chemistry, colloidal sciences, engineering, biology, and geophysics. Natural or externally produced charges on surfaces create electrical double layers (EDLs) at the solid-liquid interface. The existence of the EDLs produces several complex processes including bulk and surface transport of ions. In this work, a model is presented to simulate bulk and transport processes in homogeneous porous media comprising big pores. It is based on a theory for capacitive charging by ideally polarizable porous electrodes without Faradaic reactions or specific adsorption of ions. A volume averaging technique is used to derive the averaged transport equations inmore » the limit of thin electrical double layers. Description of the EDL between the electrolyte solution and the charged wall is accomplished using the Gouy-Chapman-Stern (GCS) model. The surface transport terms enter into the average equations due to the use of boundary conditions for diffuse interfaces. Two extra surface transports terms appear in the closed average equations. One is a surface diffusion term equivalent to the transport process in non-charged porous media. The second surface transport term is a migration term unique to charged porous media. The effective bulk and transport parameters for isotropic porous media are calculated solving the corresponding closure problems.« less

Atomic force microscopy and nanoindentation investigation of polydimethylsiloxane elastomeric substrate compliancy for various sputtered thin film morphologies.

PubMed

Maji, Debashis; Das, Soumen

2018-03-01

Crack free electrically continuous metal thin films over soft elastomeric substrates play an integral part in realization of modern day flexible bioelectronics and biosensors. Under nonoptimized deposition conditions, delamination, and/or cracking of the top film as well as the underlying soft substrate hinders optimal performance of these devices. Hence it is very important to understand and control not only the various deposition factors like power, time, or deposition pressure but also investigate the various interfacial physics playing a critical role in assuring thin film adhesion and substrate compliancy. In the present study, various nanomechanical information of the underlying substrate, namely, crack profile, average roughness, Young's modulus, and adhesion force were studied for uncracked and cracked polydimethylsiloxane (PDMS) surfaces along with pristine and conventional plasma treated PDMS samples as control. Quantification of the above parameters were done using three-dimensional surface profiler, scanning electron microscopy, nanoindentation, and atomic force microscopy techniques to elucidate the modulus range, average roughness, and adhesion force. Comparative analysis with control revealed remarkable similarity between increased modulus values, increased surface roughness, and reduced adhesion force accounting for reduced substrate compliancy and resulting in film cracking or buckling which are critical for development of various bioflexible devices. © 2017 Wiley Periodicals, Inc. J Biomed Mater Res Part A: 106A: 725-737, 2018. © 2017 Wiley Periodicals, Inc.

Effects of random aspects of cutting tool wear on surface roughness and tool life

NASA Astrophysics Data System (ADS)

Nabil, Ben Fredj; Mabrouk, Mohamed

2006-10-01

The effects of random aspects of cutting tool flank wear on surface roughness and on tool lifetime, when turning the AISI 1045 carbon steel, were studied in this investigation. It was found that standard deviations corresponding to tool flank wear and to the surface roughness increase exponentially with cutting time. Under cutting conditions that correspond to finishing operations, no significant differences were found between the calculated values of the capability index C p at the steady-state region of the tool flank wear, using the best-fit method or the Box-Cox transformation, or by making the assumption that the surface roughness data are normally distributed. Hence, a method to establish cutting tool lifetime could be established that simultaneously respects the desired average of surface roughness and the required capability index.

Distribution of organic matrix in calcium oxalate renal calculi.

PubMed

Warpehoski, M A; Buscemi, P J; Osborn, D C; Finlayson, B; Goldberg, E P

1981-01-01

The quantity of protein and carbohydrate comprising the matrix of calcium oxalate monohydrate (COM) renal stones was found to decrease with distance from the surface of the stone. The average organic concentration of stones 3 to 30 mm in diameter ranged from 5.7% at the surface to 2.7% at the core. This concentration gradient suggests matrix involvement in a "growth front" on stone surfaces with migration of organic material from the "older" interior. The matrix distribution was not readily correlated with density variations or with the presence of hydroxyapatite or calcium oxalate dihydrate. Surface matrix concentrations were greater than amounts predicted by physical adsorption. Electron microscopy confirmed the presence of the organic-rich surface layer and also suggested that increase in stone size occurs predominantly by crystal growth with microcrystal aggregates as growth centers.

Marine Cloud Brightening: regional applications to the weakening of hurricanes and reduction in coral bleaching

NASA Astrophysics Data System (ADS)

Gadian, A.; Hauser, R.; Kleypas, J. A.; Latham, J.; Parkes, B.; Salter, S.

2013-12-01

This study examines the potential to cool ocean surface waters in regions of hurricane genesis and early development. This would be achieved by seeding, with copious quantities of seawater cloud condensation nuclei (CCN), low-level maritime stratocumulus clouds covering these regions or those at the source of incoming currents. Higher cloud droplet density would increase these clouds' reflectivity to incoming sunlight, and possibly their longevity. This approach is a more localized application of the Marine Cloud Brightening (MCB) geoengineering technique promoting global cooling. By utilizing a climate ocean/atmosphere coupled model, HadGEM1, and by judicious seeding of maritime stratocumulus clouds, we demonstrate that we may be able to significantly reduce sea surface temperatures (SSTs) in hurricane development regions. Thus artificial seeding may reduce hurricane intensity; but how well the magnitude of this effect is yet to be determined. Increases in coral bleaching events over the last few decades have been largely caused by rising SSTs, and continued warming is expected to cause even greater increases through this century. Using thr same Global Climate Model to examine the potential of MCB to cool oceanic surface waters in three coral reef provinces. Our simulations indicate that under doubled CO2 conditions, the substantial increases in coral bleaching conditions from current values in three reef regions (Caribbean, French Polynesia, and the Great Barrier Reef) were eliminated when MCB was applied, which reduced the SSTs at these sites roughly to their original values. In this study we also illustrate how even regional application of MCB can affect the planetary meridional heat flux and the reduction in poleward heat transfer. (a) Change in annual average sea surface temperature, Celsius, between the 2xCO2 and CONTROL simulations. (b) Change in annual average sea surface temperature, Celsius, between the CONTROL and 2xCO2+MCB simulations. The dashed black boxes in both panels represent the three coral reef regions. In the Southern north Atlantic, the warmer SSTs in (a) is reduced to the current "control" temperatures, weakening hurricane formation.

Apparent late Quaternary fault slip rate increase in the southwestern Lower Rhine Graben, central Europe

USGS Publications Warehouse

Gold, Ryan D.; Friedrich, Anke M.; Kubler, Simon; Salamon, Martin

2017-01-01

In regions of low strain, long earthquake recurrence intervals (104–106  yrs) and erosive processes limit preservation of Quaternary markers suitable for distinguishing whether faults slip at uniform or secularly varying rates. The Lower Rhine graben in the border region of Germany, The Netherlands, and Belgium provides a unique opportunity to explore Quaternary slip‐rate variations in a region of low strain using the basal (2.29±0.29  Ma) and surface (700±80  ka) contacts of the regionally extensive main terrace (“Hauptterrasse”), deposited by the Rhine and Maas Rivers. These surfaces are vertically offset 3–140 m and 0–68 m, respectively, across individual fault strands within a distributed network of northwest‐trending, slow‐slipping (<0.1  mm/yr) normal faults. In this investigation, we construct Quaternary slip histories for the southern Lower Rhine graben faults using new main terrace surface vertical offset measurements made from light detection and ranging (lidar)‐derived bare‐earth digital terrain models, which we synthesize with existing constraints on the offset basal contact of this fluvial deposit (n=91 collocated sites with displacement constraints). We find that >80% of the sites record an apparent increase in slip rate for the more recent interval from 700 ka to present, which corresponds to a period of increased uplift of the nearby Rhenish Massif and regional volcanism. However, the apparent increase in slip rate could result, in part, from erosion of the footwall surface below the main terrace, leading to an apparent displacement that is smaller than the total vertical offset since the start of the Quaternary. Prior work focused on characterization of these faults as seismic sources in the Lower Rhine graben has preferentially relied on the average fault‐slip rate constrained using the base of the main terrace. We suggest that average fault‐slip rates calculated using the ∼700  ka main terrace surface are subjected to fewer uncertainties and sample a time interval that is more relevant for seismic‐hazard analysis.

Simulation and assessment of urbanization impacts on runoff metrics: insights from landuse changes

NASA Astrophysics Data System (ADS)

Zhang, Yongyong; Xia, Jun; Yu, Jingjie; Randall, Mark; Zhang, Yichi; Zhao, Tongtiegang; Pan, Xingyao; Zhai, Xiaoyan; Shao, Quanxi

2018-05-01

Urbanization-induced landuse changes alter runoff regimes in complex ways. In this study, a detailed investigation of the urbanization impacts on runoff regimes is provided by using multiple runoff metrics and with consideration of landuse dynamics. A catchment hydrological model is modified by coupling a simplified flow routing module of the urban drainage system and landuse dynamics to improve long-term urban runoff simulations. Moreover, multivariate statistical approach is adopted to mine the spatial variations of runoff metrics so as to further identify critical impact factors of landuse changes. The Qing River catchment as a peri-urban catchment in the Beijing metropolitan area is selected as our study region. Results show that: (1) the dryland agriculture is decreased from 13.9% to 1.5% of the total catchment area in the years 2000-2015, while the percentages of impervious surface, forest and grass are increased from 63.5% to 72.4%, 13.5% to 16.6% and 5.1% to 6.5%, respectively. The most dramatic landuse changes occur in the middle and downstream regions; (2) The combined landuse changes do not alter the average flow metrics obviously at the catchment outlet, but slightly increase the high flow metrics, particularly the extreme high flows; (3) The impacts on runoff metrics in the sub-catchments are more obvious than those at the catchment outlet. For the average flow metrics, the most impacted metric is the runoff depth in the dry season (October ∼ May) with a relative change from -10.9% to 11.6%, and the critical impact factors are the impervious surface and grass. For the high flow metrics, the extreme high flow depth is increased most significantly with a relative change from -0.6% to 10.5%, and the critical impact factors are the impervious surface and dryland agriculture; (4) The runoff depth metrics in the sub-catchments are increased because of the landuse changes from dryland agriculture to impervious surface, but are decreased because of the landuse changes from dryland agriculture or impervious surface to grass or forest. The results of this study provide useful information for urban planning such as Sponge City design.

Effects of Rotor Blade Scaling on High-Pressure Turbine Unsteady Loading

NASA Astrophysics Data System (ADS)

Lastiwka, Derek; Chang, Dongil; Tavoularis, Stavros

2013-03-01

The present work is a study of the effects of rotor blade scaling of a single-stage high pressure turbine on the time-averaged turbine performance and on parameters that influence vibratory stresses on the rotor blades and stator vanes. Three configurations have been considered: a reference case with 36 rotor blades and 24 stator vanes, a case with blades upscaled by 12.5%, and a case with blades downscaled by 10%. The present results demonstrate that blade scaling effects were essentially negligible on the time-averaged turbine performance, but measurable on the unsteady surface pressure fluctuations, which were intensified as blade size was increased. In contrast, blade torque fluctuations increased significantly as blade size decreased. Blade scaling effects were also measurable on the vanes.

Combined effects of deforestation and doubled atmospheric CO{sub 2} concentrations on the climate of Amazonia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Costa, M.H.; Foley, J.A.

2000-01-01

It is generally expected that the Amazon basin will experience at least two major environmental changes during the next few decades and centuries: (1) increasing areas of forest will be converted to pasture and cropland, and (2) concentrations of atmospheric CO{sub 2} will continue to rise. In this study, the authors use the National Center for Atmospheric Research GENESIS atmospheric general circulation model, coupled to the Integrated Biosphere Simulator, to determine the combined effects of large-scale deforestation and increased CO{sub 2} concentrations (including both physiological and radiative effects) on Amazonian climate. In these simulations, deforestation decreases basin-average precipitation by 0.73more » mm day{sup {minus}1} over the basin, as a consequence of the general reduction in vertical motion above the deforested area (although there are some small regions with increased vertical motion). The overall effect of doubled CO{sub 2} concentrations in Amazonia is an increase in basin-average precipitation of 0.28 mm day{sup {minus}1}. The combined effect of deforestation and doubled CO{sub 2}, including the interactions among the processes, is a decrease in the basin-average precipitation of 0.42 mm day{sup {minus}1}. While the effects of deforestation and increasing CO{sub 2} concentrations on precipitation tend to counteract one another, both processes work to warm the Amazon basin. The effect of deforestation and increasing CO{sub 2} concentrations both tent to increase surface temperature, mainly because of decreases in evapotranspiration and the radiative effect of CO{sub 2}. The combined effect of deforestation and doubled CO{sub 2}, including the interactions among the processes, increases the basin-average temperature by roughly 3.5 C.« less

Understanding self ion damage in FCC Ni-Cr-Fe based alloy using X-ray diffraction techniques

NASA Astrophysics Data System (ADS)

Halder Banerjee, R.; Sengupta, P.; Chatterjee, A.; Mishra, S. C.; Bhukta, A.; Satyam, P. V.; Samajdar, I.; Dey, G. K.

2018-04-01

Using X-ray diffraction line profile analysis (XRDLPA) approach the radiation response of FCC Ni-Cr-Fe based alloy 690 to 1.5 and 3 MeV Ni2+ ion damage was quantified in terms of its microstructural parameters. These microstructural parameters viz. average domain size, microstrain and dislocation density were found to vary anisotropically with fluence. The anisotropic behaviour is mainly attributable to presence of twins in pre-irradiated microstructure. After irradiation, surface roughness increases as a function of fluence attributable to change in surface and sub-surface morphology caused by displacement cascade, defects and sputtered atoms created by incident energetic ion. The radiation hardening in case of 1.5 MeV Ni2+ irradiated specimens too is a consequence of the increase in dislocation density formed by interaction of radiation induced defects with pre-existing dislocations. At highest fluence there is an initiation of saturation.

Effect of Ga Addition on Morphology and Recovery of Primary Si During Al-Si Alloy Solidification Refining

NASA Astrophysics Data System (ADS)

Li, Jingwei; Bai, Xiaolong; Li, Yanlei; Ban, Boyuan; Chen, Jian

2015-12-01

The effect of Ga addition on alloy macrostructure, morphology and recovery rate of primary Si during the Al-Si-Ga alloy solvent refining process of silicon was studied in this work. The addition of Ga to Al-Si alloy could change the morphology of the primary Si. The average plate thickness of the primary Si increases with increase of Ga content. With the increase of Ga content, the average plate length of the primary Si crystals becomes larger when the Ga content is less than 5% in the Al-30%Si-xGa alloy, but becomes smaller when the Ga content exceeds 5%. Al-Si-Ga alloys consist of three types, primary Si, GaxAl1-x, (α-Al+Si+β-Ga) eutectic. (111) is the preferred growth surface of the plate-like primary Si. The recovery rate of the primary Si increases with the increase of Ga content. When the Ga content increased to 20% in Al-30%Si-xGa alloy, the relative recovery rate of the primary Si increased to 50.41% than that in Al-30%Si alloy.

Bend strengths of reaction bonded silicon nitride prepared from dry attrition milled silicon powder

NASA Technical Reports Server (NTRS)

Herbell, T. P.; Glasgow, T. K.

1979-01-01

Dry attrition milled silicon powder was compacted, sintered in helium, and reaction bonded in nitrogen-4 volume percent hydrogen. Bend strengths of bars with as-nitrided surfaces averaged as high as 210 MPa at room temperature and 220 MPa at 1400 C. Bars prepared from the milled powder were stronger than those prepared from as-received powder at both room temperature and at 1400 C. Room temperature strength decreased with increased milling time and 1400 C strength increased with increased milling time.

Quantifying the biological impact of surface ocean light attenuation by colored detrital matter in an ESM using a new optical parameterization

NASA Astrophysics Data System (ADS)

Kim, G. E.; Pradal, M.-A.; Gnanadesikan, A.

2015-08-01

Light attenuation by colored detrital material (CDM) was included in a fully coupled Earth system model (ESM). This study presents a modified parameterization for shortwave attenuation, which is an empirical relationship between 244 concurrent measurements of the diffuse attenuation coefficient for downwelling irradiance, chlorophyll concentration and light absorption by CDM. Two ESM model runs using this parameterization were conducted, with and without light absorption by CDM. The light absorption coefficient for CDM was prescribed as the average of annual composite MODIS Aqua satellite data from 2002 to 2013. Comparing results from the two model runs shows that changes in light limitation associated with the inclusion of CDM decoupled trends between surface biomass and nutrients. Increases in surface biomass were expected to accompany greater nutrient uptake and therefore diminish surface nutrients. Instead, surface chlorophyll, biomass and nutrients increased together. These changes can be attributed to the different impact of light limitation on surface productivity versus total productivity. Chlorophyll and biomass increased near the surface but decreased at greater depths when CDM was included. The net effect over the euphotic zone was less total biomass leading to higher nutrient concentrations. Similar results were found in a regional analysis of the oceans by biome, investigating the spatial variability of response to changes in light limitation using a single parameterization for the surface ocean. In coastal regions, surface chlorophyll increased by 35 % while total integrated phytoplankton biomass diminished by 18 %. The largest relative increases in modeled surface chlorophyll and biomass in the open ocean were found in the equatorial biomes, while the largest decreases in depth-integrated biomass and chlorophyll were found in the subpolar and polar biomes. This mismatch of surface and subsurface trends and their regional dependence was analyzed by comparing the competing factors of diminished light availability and increased nutrient availability on phytoplankton growth in the upper 200 m. Understanding changes in biological productivity requires both surface and depth-resolved information. Surface trends may be minimal or of the opposite sign than depth-integrated amounts, depending on the vertical structure of phytoplankton abundance.

An experimental assessment of the size effects on the strength and ductility of freestanding copper films under macroscopically homogenous deformation

NASA Astrophysics Data System (ADS)

Chauhan, Shakti Singh

Metallic interconnects and circuitry has been experiencing excessive deformation beyond their elastic limits in many applications, ranging from micro-electromechanical systems (MEMS) to flexible electronics. These broad applications are creating needs to understand the extent of strength and ductility of freestanding metallic films at scales approaching the micron and sub micron range. This work aims to elucidate the effects of microstructural constraint as well as geometric dimensional constraint on the strength and ductility of freestanding Cu films under uniaxial tension. Two types of films are tested (i) high purity rolled films of 12.5-100microm thickness and average grain sizes of 11-47microm and (ii) electroplated films of 2-50 microm thickness and average grain sizes of 1.8-5microm. Several experimental tools including residual electrical resistivity measurements, surface strain measurements and surface roughness measurements are employed to highlight the underlying deformation mechanisms leading to the observed size effects. With respect to the strength of the specimens, we find that the nature and magnitude of thickness effects is very sensitive to the average grain size. In all cases, coupled thickness and grain size effects were observed. This study shows that this observed coupling, unique to the case of freestanding specimen, arises because the observed size effects are an outcome of the size dependence of two fundamental microstructural parameters i.e. volume fraction of surface grains and grain boundary area per unit specimen volume. For films having thickness and grain sizes greater than 5microm, thickness dependent weakening is observed for a constant grain size. Reducing thickness results in an increase in the volume fraction of grains exposed to the free surface as well as a reduction in the grain boundary area per unit specimen volume. The former effect leads to a reduction in the effective microstructural constraint on the intragranular dislocation activity in individual grains. This free surface related effect is the origin of a weakening contribution to the overall specimen strength with reducing thickness. For specimens with grain sizes ˜ O (10-50microm), this effect was found to be dominating i.e. reducing thickness resulted in reducing strength. A phenomenological model employing the flow strength of surface and bulk grains is proposed to model the observed trends. For films having thickness and grain sizes smaller than 5microm, size dependent strengthening is observed for a constant grain size. At this scale, grain boundary dislocations dominate. As a consequence, thickness effects arise because grain boundary dislocation source density per unit specimen volume reduces with reducing specimen thickness. This statistical reduction in dislocation source density leads to increasing specimen strength via source starvation strengthening. Our results show that such increasing specimen strength with reducing thickness, which has only been observed previously for nanocrystalline thin films, first appears at average grain size of ˜5microm or xx smaller. The measurements showed a characteristic length scale of about 5microm, which defines the size dependent strengthening or weakening of the film. With respect to the thickness effects on ductility, it was found that both thickness and average grain size affect ductility. While prominent thickness effects persist at larger grain sizes, for specimens with grain size approaching 1microm, the loss of strain hardening ability at such fine microstructures dominates and a limiting ductility of ˜2% is seen irrespective of the thickness. The observed thickness effects on ductility were investigated via surface roughness measurements that allow the characterization of initiation and evolution of deformation heterogeneities. It was found that thickness has a strong influence on the characteristic heterogeneity of deformation. At small specimen thicknesses, the deformation was found to be highly localized i.e. widely spaced regions showing substantial thickness reduction, hence increasing the vulnerability to the onset of plastic instabilities. At larger thicknesses, however, the increasing microstructural constraint delocalizes the strain and thereby precludes the early onset of instability, leading to enhanced ductility.

Estimation of open water evaporation using land-based meteorological data

NASA Astrophysics Data System (ADS)

Li, Fawen; Zhao, Yong

2017-10-01

Water surface evaporation is an important process in the hydrologic and energy cycles. Accurate simulation of water evaporation is important for the evaluation of water resources. In this paper, using meteorological data from the Aixinzhuang reservoir, the main factors affecting water surface evaporation were determined by the principal component analysis method. To illustrate the influence of these factors on water surface evaporation, the paper first adopted the Dalton model to simulate water surface evaporation. The results showed that the simulation precision was poor for the peak value zone. To improve the model simulation's precision, a modified Dalton model considering relative humidity was proposed. The results show that the 10-day average relative error is 17.2%, assessed as qualified; the monthly average relative error is 12.5%, assessed as qualified; and the yearly average relative error is 3.4%, assessed as excellent. To validate its applicability, the meteorological data of Kuancheng station in the Luan River basin were selected to test the modified model. The results show that the 10-day average relative error is 15.4%, assessed as qualified; the monthly average relative error is 13.3%, assessed as qualified; and the yearly average relative error is 6.0%, assessed as good. These results showed that the modified model had good applicability and versatility. The research results can provide technical support for the calculation of water surface evaporation in northern China or similar regions.

Description and recognition of faces from 3D data

NASA Astrophysics Data System (ADS)

Coombes, Anne M.; Richards, Robin; Linney, Alfred D.; Bruce, Vicki; Fright, Rick

1992-12-01

A method based on differential geometry, is presented for mathematically describing the shape of the facial surface. Three-dimensional data for the face are collected by optical surface scanning. The method allows the segmentation of the face into regions of a particular `surface type,' according to the surface curvature. Eight different surface types are produced which all have perceptually meaningful interpretations. The correspondence of the surface type regions to the facial features are easily visualized, allowing a qualitative assessment of the face. A quantitative description of the face in terms of the surface type regions can be produced and the variation of the description between faces is demonstrated. A set of optical surface scans can be registered together and averages to produce an average male and average female face. Thus an assessment of how individuals vary from the average can be made as well as a general statement about the differences between male and female faces. This method will enable an investigation to be made as to how reliably faces can be individuated by their surface shape which, if feasible, may be the basis of an automatic system for recognizing faces. It also has applications in physical anthropology, for classification of the face, facial reconstructive surgery, to quantify the changes in a face altered by reconstructive surgery and growth, and in visual perception, to assess the recognizability of faces. Examples of some of these applications are presented.

Thermodynamics of manganese oxides: Sodium, potassium, and calcium birnessite and cryptomelane

PubMed Central

Birkner, Nancy; Navrotsky, Alexandra

2017-01-01

Manganese oxides with layer and tunnel structures occur widely in nature and inspire technological applications. Having variable compositions, these structures often are found as small particles (nanophases). This study explores, using experimental thermochemistry, the role of composition, oxidation state, structure, and surface energy in the their thermodynamic stability. The measured surface energies of cryptomelane, sodium birnessite, potassium birnessite and calcium birnessite are all significantly lower than those of binary manganese oxides (Mn3O4, Mn2O3, and MnO2), consistent with added stabilization of the layer and tunnel structures at the nanoscale. Surface energies generally decrease with decreasing average manganese oxidation state. A stabilizing enthalpy contribution arises from increasing counter-cation content. The formation of cryptomelane from birnessite in contact with aqueous solution is favored by the removal of ions from the layered phase. At large surface area, surface-energy differences make cryptomelane formation thermodynamically less favorable than birnessite formation. In contrast, at small to moderate surface areas, bulk thermodynamics and the energetics of the aqueous phase drive cryptomelane formation from birnessite, perhaps aided by oxidation-state differences. Transformation among birnessite phases of increasing surface area favors compositions with lower surface energy. These quantitative thermodynamic findings explain and support qualitative observations of phase-transformation patterns gathered from natural and synthetic manganese oxides. PMID:28130549

δ2H isotopic flux partitioning of evapotranspiration over a grass field following a water pulse and subsequent dry down

NASA Astrophysics Data System (ADS)

Good, Stephen P.; Soderberg, Keir; Guan, Kaiyu; King, Elizabeth G.; Scanlon, Todd M.; Caylor, Kelly K.

2014-02-01

The partitioning of surface vapor flux (FET) into evaporation (FE) and transpiration (FT) is theoretically possible because of distinct differences in end-member stable isotope composition. In this study, we combine high-frequency laser spectroscopy with eddy covariance techniques to critically evaluate isotope flux partitioning of FET over a grass field during a 15 day experiment. Following the application of a 30 mm water pulse, green grass coverage at the study site increased from 0 to 10% of ground surface area after 6 days and then began to senesce. Using isotope flux partitioning, transpiration increased as a fraction of total vapor flux from 0% to 40% during the green-up phase, after which this ratio decreased while exhibiting hysteresis with respect to green grass coverage. Daily daytime leaf-level gas exchange measurements compare well with daily isotope flux partitioning averages (RMSE = 0.0018 g m-2 s-1). Overall the average ratio of FT to FET was 29%, where uncertainties in Keeling plot intercepts and transpiration composition resulted in an average of uncertainty of ˜5% in our isotopic partitioning of FET. Flux-variance similarity partitioning was partially consistent with the isotope-based approach, with divergence occurring after rainfall and when the grass was stressed. Over the average diurnal cycle, local meteorological conditions, particularly net radiation and relative humidity, are shown to control partitioning. At longer time scales, green leaf area and available soil water control FT/FET. Finally, we demonstrate the feasibility of combining isotope flux partitioning and flux-variance similarity theory to estimate water use efficiency at the landscape scale.

Projected near-future levels of temperature and pCO2 reduce coral fertilization success.

PubMed

Albright, Rebecca; Mason, Benjamin

2013-01-01

Increases in atmospheric carbon dioxide (pCO2) are projected to contribute to a 1.1-6.4°C rise in global average surface temperatures and a 0.14-0.35 reduction in the average pH of the global surface ocean by 2100. If realized, these changes are expected to have negative consequences for reef-building corals including increased frequency and severity of coral bleaching and reduced rates of calcification and reef accretion. Much less is known regarding the independent and combined effects of temperature and pCO2 on critical early life history processes such as fertilization. Here we show that increases in temperature (+3°C) and pCO2 (+400 µatm) projected for this century negatively impact fertilization success of a common Indo-Pacific coral species, Acropora tenuis. While maximum fertilization did not differ among treatments, the sperm concentration required to obtain 50% of maximum fertilization increased 6- to 8- fold with the addition of a single factor (temperature or CO2) and nearly 50- fold when both factors interact. Our results indicate that near-future changes in temperature and pCO2 narrow the range of sperm concentrations that are capable of yielding high fertilization success in A. tenuis. Increased sperm limitation, in conjunction with adult population decline, may have severe consequences for coral reproductive success. Impaired sexual reproduction will further challenge corals by inhibiting population recovery and adaptation potential.

Projected Near-Future Levels of Temperature and pCO2 Reduce Coral Fertilization Success

PubMed Central

Albright, Rebecca; Mason, Benjamin

2013-01-01

Increases in atmospheric carbon dioxide (pCO2) are projected to contribute to a 1.1–6.4°C rise in global average surface temperatures and a 0.14–0.35 reduction in the average pH of the global surface ocean by 2100. If realized, these changes are expected to have negative consequences for reef-building corals including increased frequency and severity of coral bleaching and reduced rates of calcification and reef accretion. Much less is known regarding the independent and combined effects of temperature and pCO2 on critical early life history processes such as fertilization. Here we show that increases in temperature (+3°C) and pCO2 (+400 µatm) projected for this century negatively impact fertilization success of a common Indo-Pacific coral species, Acropora tenuis. While maximum fertilization did not differ among treatments, the sperm concentration required to obtain 50% of maximum fertilization increased 6- to 8- fold with the addition of a single factor (temperature or CO2) and nearly 50- fold when both factors interact. Our results indicate that near-future changes in temperature and pCO2 narrow the range of sperm concentrations that are capable of yielding high fertilization success in A. tenuis. Increased sperm limitation, in conjunction with adult population decline, may have severe consequences for coral reproductive success. Impaired sexual reproduction will further challenge corals by inhibiting population recovery and adaptation potential. PMID:23457572

The mean and turbulent flow structure of a weak hydraulic jump

NASA Astrophysics Data System (ADS)

Misra, S. K.; Kirby, J. T.; Brocchini, M.; Veron, F.; Thomas, M.; Kambhamettu, C.

2008-03-01

The turbulent air-water interface and flow structure of a weak, turbulent hydraulic jump are analyzed in detail using particle image velocimetry measurements. The study is motivated by the need to understand the detailed dynamics of turbulence generated in steady spilling breakers and the relative importance of the reverse-flow and breaker shear layer regions with attention to their topology, mean flow, and turbulence structure. The intermittency factor derived from turbulent fluctuations of the air-water interface in the breaker region is found to fit theoretical distributions of turbulent interfaces well. A conditional averaging technique is used to calculate ensemble-averaged properties of the flow. The computed mean velocity field accurately satisfies mass conservation. A thin, curved shear layer oriented parallel to the surface is responsible for most of the turbulence production with the turbulence intensity decaying rapidly away from the toe of the breaker (location of largest surface curvature) with both increasing depth and downstream distance. The reverse-flow region, localized about the ensemble-averaged free surface, is characterized by a weak downslope mean flow and entrainment of water from below. The Reynolds shear stress is negative in the breaker shear layer, which shows that momentum diffuses upward into the shear layer from the flow underneath, and it is positive just below the mean surface indicating a downward flux of momentum from the reverse-flow region into the shear layer. The turbulence structure of the breaker shear layer resembles that of a mixing layer originating from the toe of the breaker, and the streamwise variations of the length scale and growth rate are found to be in good agreement with observed values in typical mixing layers. All evidence suggests that breaking is driven by a surface-parallel adverse pressure gradient and a streamwise flow deceleration at the toe of the breaker. Both effects force the shear layer to thicken rapidly, thereby inducing a sharp free surface curvature change at the toe.

Research on effect of rough surface on FMCW laser radar range accuracy

NASA Astrophysics Data System (ADS)

Tao, Huirong

2018-03-01

The non-cooperative targets large scale measurement system based on frequency-modulated continuous-wave (FMCW) laser detection and ranging technology has broad application prospects. It is easy to automate measurement without cooperative targets. However, the complexity and diversity of the surface characteristics of the measured surface directly affects the measurement accuracy. First, the theoretical analysis of range accuracy for a FMCW laser radar was studied, the relationship between surface reflectivity and accuracy was obtained. Then, to verify the effect of surface reflectance for ranging accuracy, a standard tool ball and three standard roughness samples were measured within 7 m to 24 m. The uncertainty of each target was obtained. The results show that the measurement accuracy is found to increase as the surface reflectivity gets larger. Good agreements were obtained between theoretical analysis and measurements from rough surfaces. Otherwise, when the laser spot diameter is smaller than the surface correlation length, a multi-point averaged measurement can reduce the measurement uncertainty. The experimental results show that this method is feasible.

Interactions between soil texture and placement of dairy slurry application: II. Leaching of phosphorus forms.

PubMed

Glaesner, Nadia; Kjaergaard, Charlotte; Rubaek, Gitte H; Magid, Jakob

2011-01-01

Managing phosphorus (P) losses in soil leachate folllowing land application of manure is key to curbing eutrophication in many regions. We compared P leaching from columns of variably textured, intact soils (20 cm diam., 20 cm high) subjected to surface application or injection of dairy cattle (Bos taurus L.) manure slurry. Surface application of slurry increased P leaching losses relative to baseline losses, but losses declined with increasing active flow volume. After elution of one pore volume, leaching averaged 0.54 kg P ha(-1) from the loam, 0.38 kg P ha(-1) from the sandy loam, and 0.22 kg P ha(-1) from the loamy sand following surface application. Injection decreased leaching of all P forms compared with surface application by an average of 0.26 kg P ha(-1) in loam and 0.23 kg P ha(-1) in sandy loam, but only by 0.03 kg P ha(-1) in loamy sand. Lower leaching losses were attributed to physical retention of particulate P and dissolved organic P, caused by placing slurry away from active flow paths in the fine-textured soil columns, as well as to chemical retention of dissolved inorganic P, caused by better contact between slurry P and soil adsorption sites. Dissolved organic P was less retained in soil after slurry application than other P forms. On these soils with low to intermediate P status, slurry injection lowered P leaching losses from clay-rich soil, but not from the sandy soils, highlighting the importance of soil texture in manageing P losses following slurry application.

Study on glacier changes from multi-source remote sensing data in the mountainous areas of the upper reaches of Shule River Basin

NASA Astrophysics Data System (ADS)

Zhang, S.; Li, H.

2017-12-01

The changes of glacier area, ice surface elevation and ice storage in the upper reaches of the Shule River Basin were investigated by the Landsat TM series SRTM and stereo image pairs of Third Resources Satellite (ZY-3)from 2000 to 2015. There are 510 glaciers with areas large than 0.01 km2 in 2015, and the glacier area is 435 km2 in the upper reach of Shule River basin. 96 glaciers were disappeared from 2000 to 2015, and the total glacier area decreased by 57.6±2.68km2 (11.7 %). After correcting the elevation difference between ZY-3 DEM and SRTM and aspect, we found that the average ice surface elevation of glaciers reduced by 2.58±0.6m from 2000 to 2015 , with average reduction 0.172 ±0.04m a-1, and the ice storage reduced by 1.277±0.311km3. Elevation variation of ice surface in different sub-regions reflects the complexity of glacier change. The ice storage change calculated from the sum of single glacier area-volume relationship is glacier 1.46 times higher than that estimated from ice surface elevation change, indicating that the global ice storage change estimated from glacier area-volume change probably overestimated. The shrinkage of glacier increased glacier runoff, and led the significant increase of river runoff. The accuracy of projecting the potential glacier change, glacier runoff and river runoff is the key issues of delicacy water resource management in Shule River Basin.

To Analyse the Erosive Potential of Commercially Available Drinks on Dental Enamel and Various Tooth Coloured Restorative Materials - An In-vitro Study.

PubMed

Karda, Babita; Jindal, Ritu; Mahajan, Sandeep; Sandhu, Sanam; Sharma, Sunila; Kaur, Rajwinder

2016-05-01

With the enormous change in life style pattern of a common man through the past few decades, there has been proportional variation in the amount and frequency of consumption of drinks. An increased consumption of these drinks will concurrently increase enamel surface roughness by demineralization, resulting in hypersensitivity and elevated caries risk. The present study was designed to evaluate the erosive potential of commercially available drinks on tooth enamel and various tooth coloured restorative materials. Extracted human teeth were taken and divided into four groups i.e. tooth enamel, glass ionomer cement, composite and compomer. Four commercially available drinks were chosen these were Coca -Cola, Nimbooz, Frooti and Yakult. The pH of each drink was measured. Each group was immersed in various experimental drinks for a period of 14 days. The erosive potential of each drink was measured by calculating the change in average surface roughness of these groups after the immersion protocol in various drinks. The data analysis was done by One Way Anova, Post-Hoc Bonferroni, and paired t -test. Group II-GIC showed highest values for mean of change in average surface roughness and the values were statistically significant (p<0.001) with tooth enamel, composite and compomer (p=0.002). Coca-cola showed the highest erosive potential and Yakult showed the lowest, there was no statistical significant difference between the results shown by Yakult and Frooti. Characteristics which may promote erosion of enamel and tooth coloured restorative materials were surface texture of the material and pH of the drinks.

Assessment of land surface temperature and heat fluxes over Delhi using remote sensing data.

PubMed

Chakraborty, Surya Deb; Kant, Yogesh; Mitra, Debashis

2015-01-15

Surface energy processes has an essential role in urban weather, climate and hydrosphere cycles, as well in urban heat redistribution. The research was undertaken to analyze the potential of Landsat and MODIS data in retrieving biophysical parameters in estimating land surface temperature & heat fluxes diurnally in summer and winter seasons of years 2000 and 2010 and understanding its effect on anthropogenic heat disturbance over Delhi and surrounding region. Results show that during years 2000-2010, settlement and industrial area increased from 5.66 to 11.74% and 4.92 to 11.87% respectively which in turn has direct effect on land surface temperature (LST) and heat fluxes including anthropogenic heat flux. Based on the energy balance model for land surface, a method to estimate the increase in anthropogenic heat flux (Has) has been proposed. The settlement and industrial areas has higher amounts of energy consumed and has high values of Has in all seasons. The comparison of satellite derived LST with that of field measured values show that Landsat estimated values are in close agreement within error of ±2 °C than MODIS with an error of ±3 °C. It was observed that, during 2000 and 2010, the average change in surface temperature using Landsat over settlement & industrial areas of both seasons is 1.4 °C & for MODIS data is 3.7 °C. The seasonal average change in anthropogenic heat flux (Has) estimated using Landsat & MODIS is up by around 38 W/m(2) and 62 W/m(2) respectively while higher change is observed over settlement and concrete structures. The study reveals that the dynamic range of Has values has increased in the 10 year period due to the strong anthropogenic influence over the area. The study showed that anthropogenic heat flux is an indicator of the strength of urban heat island effect, and can be used to quantify the magnitude of the urban heat island effect. Copyright © 2013 Elsevier Ltd. All rights reserved.

Improved vegetation parameterization for hydrological model and assessment of land cover change impacts on flow regime of the Upper Bhima basin, India

NASA Astrophysics Data System (ADS)

Mohaideen, M. M. Diwan; Varija, K.

2018-05-01

This study investigates the potential and applicability of variable infiltration capacity (VIC) hydrological model to simulate different hydrological components of the Upper Bhima basin under two different Land Use Land Cover (LULC) (the year 2000 and 2010) conditions. The total drainage area of the basin was discretized into 1694 grids of about 5.5 km by 5.5 km: accordingly the model parameters were calibrated at each grid level. Vegetation parameters for the model were prepared using temporal profile of Leaf Area Index (LAI) from Moderate-Resolution Imaging Spectroradiometer and LULC. This practice provides a methodological framework for the improved vegetation parameterization along with region-specific condition for the model simulation. The calibrated and validated model was run using the two LULC conditions separately with the same observed meteorological forcing (1996-2001) and soil data. The change in LULC has resulted to an increase in the average annual evapotranspiration over the basin by 7.8%, while the average annual surface runoff and baseflow decreased by 18.86 and 5.83%, respectively. The variability in hydrological components and the spatial variation of each component attributed to LULC were assessed at the basin grid level. It was observed that 80% of the basin grids showed an increase in evapotranspiration (ET) (maximum of 292 mm). While the majority of the grids showed a decrease in surface runoff and baseflow, some of the grids showed an increase (i.e. 21 and 15% of total grids—surface runoff and baseflow, respectively).

Assessing recent air-sea freshwater flux changes using a surface temperature-salinity space framework

NASA Astrophysics Data System (ADS)

Grist, Jeremy P.; Josey, Simon A.; Zika, Jan D.; Evans, Dafydd Gwyn; Skliris, Nikolaos

2016-12-01

A novel assessment of recent changes in air-sea freshwater fluxes has been conducted using a surface temperature-salinity framework applied to four atmospheric reanalyses. Viewed in the T-S space of the ocean surface, the complex pattern of the longitude-latitude space mean global Precipitation minus Evaporation (PME) reduces to three distinct regions. The analysis is conducted for the period 1979-2007 for which there is most evidence for a broadening of the (atmospheric) tropical belt. All four of the reanalyses display an increase in strength of the water cycle. The range of increase is between 2% and 30% over the period analyzed, with an average of 14%. Considering the average across the reanalyses, the water cycle changes are dominated by changes in tropical as opposed to mid-high latitude precipitation. The increases in the water cycle strength, are consistent in sign, but larger than in a 1% greenhouse gas run of the HadGEM3 climate model. In the model a shift of the precipitation/evaporation cells to higher temperatures is more evident, due to the much stronger global warming signal. The observed changes in freshwater fluxes appear to be reflected in changes in the T-S distribution of the Global Ocean. Specifically, across the diverse range of atmospheric reanalyses considered here, there was an acceleration of the hydrological cycle during 1979-2007 which led to a broadening of the ocean's salinity distribution. Finally, although the reanalyses indicate that the warm temperature tropical precipitation dominated water cycle change, ocean observations suggest that ocean processes redistributed the freshening to lower ocean temperatures.

Sea Ice, Clouds, Sunlight, and Albedo: The Umbrella Versus the Blanket

NASA Astrophysics Data System (ADS)

Perovich, D. K.

2017-12-01

The Arctic sea ice cover has undergone a major decline in recent years, with reductions in ice extent, ice thickness, and ice age. Understanding the feedbacks and forcing driving these changes is critical in improving predictions. The surface radiation budget plays a central role in summer ice melt and is governed by clouds and surface albedo. Clouds act as an umbrella reducing the downwelling shortwave, but also serve as a blanket increasing the downwelling longwave, with the surface albedo also determining the net balance. Using field observations from the SHEBA program, pairs of clear and cloudy days were selected for each month from May through September and the net radiation flux was calculated for different surface conditions and albedos. To explore the impact of albedo we calculated a break even albedo, where the net radiation for cloudy skies is the same as clear skies. For albedos larger than the break-even value the net radiation flux is smaller under clear skies compared to cloudy skies. Break-even albedos ranged from 0.30 in September to 0.58 in July. For snow covered or bare ice, clear skies always resulted in less radiative heat input. In contrast, leads always had, and ponds usually had, more radiative heat input under clear skies than cloudy skies. Snow covered ice had a net radiation flux that was negative or near zero under clear skies resulting in radiative cooling. We combined the albedo of individual ice types with the area of those ice types to calculate albedos averaged over a 50 km x 50 km area. The July case had the smallest areally averaged albedo of 0.50. This was less than the breakeven albedo, so cloudy skies had a smaller net radiation flux than clear skies. For the cases from the other four months, the areally averaged albedo was greater than the break-even albedo. The areally averaged net radiation flux was negative under clear skies for the May and September cases.

Metal-boride phase formation on tungsten carbide (WC-Co) during microwave plasma chemical vapor deposition

NASA Astrophysics Data System (ADS)

Johnston, Jamin M.; Catledge, Shane A.

2016-02-01

Strengthening of cemented tungsten carbide by boriding is used to improve the wear resistance and lifetime of carbide tools; however, many conventional boriding techniques render the bulk carbide too brittle for extreme conditions, such as hard rock drilling. This research explored the variation in metal-boride phase formation during the microwave plasma enhanced chemical vapor deposition process at surface temperatures from 700 to 1100 °C. We showed several well-adhered metal-boride surface layers consisting of WCoB, CoB and/or W2CoB2 with average hardness from 23 to 27 GPa and average elastic modulus of 600-730 GPa. The metal-boride interlayer was shown to be an effective diffusion barrier against elemental cobalt; migration of elemental cobalt to the surface of the interlayer was significantly reduced. A combination of glancing angle X-ray diffraction, electron dispersive spectroscopy, nanoindentation and scratch testing was used to evaluate the surface composition and material properties. An evaluation of the material properties shows that plasma enhanced chemical vapor deposited borides formed at substrate temperatures of 800 °C, 850 °C, 900 °C and 1000 °C strengthen the material by increasing the hardness and elastic modulus of cemented tungsten carbide. Additionally, these boride surface layers may offer potential for adhesion of ultra-hard carbon coatings.

A Community Terrain-Following Ocean Modeling System (ROMS)

DTIC Science & Technology

2015-09-30

funded NOPP project titled: Toward the Development of a Coupled COAMPS-ROMS Ensemble Kalman filter and adjoint with a focus on the Indian Ocean and the...surface temperature and surface salinity daily averages for 31-Jan-2014. Similarly, Figure 3 shows the sea surface height averaged solution for 31-Jan... temperature (upper panel; Celsius) and surface salinity (lower panel) for 31-Jan-2014. The refined solution for the Hudson Canyon grid is overlaid on

Comparison of land-atmosphere interaction at different surface types in the mid- to lower Yangzi River Valley

NASA Astrophysics Data System (ADS)

Guo, Weidong; Wang, Xueqian; Sun, Jianning; Ding, Aijun; Zou, Jun

2016-04-01

The mid- to lower Yangzi River Valley is located within the typical monsoon zone. Rapid urbanization, industrialization, and development of agriculture have led to fast and complicated land use and land cover changes in this region. To investigate land-atmosphere interaction in this region where human activities and monsoon climate are highly interactive with each other, micro-meteorological elements over four different surface types, i.e. urban surface represented by the observational site at Communist Party School in Nanjing (hereafter DX), suburban surface represented by the ground site at Xianling (XL), and grassland and farmland represented by field sites at Lishui County (LS-grass and LS-crop), are analyzed and their differences are revealed. Impacts of different surface parameters applied for different surface types on the radiation budget and surface-atmosphere heat, water, and mass exchanges are investigated. Results indicate that (1) the largest differences in daily average surface air temperature (Ta), surface skin temperature (Ts), and relative humidity (RH) , which are found during the dry periods between DX and LS-crop, can be up to 3.21°C, 7.26°C, and 22.79% respectively. During the growing season, the diurnal ranges of the above three elements are the smallest at DX and the largest at LS-grass, XL and LS-crop; (2) differences in radiative fluxes are mainly reflected in upward shortwave radiation (USR) that is related to surface albedo and upward longwave radiation (ULR) that is related to Ts. USR is the smallest and ULR is the largest at DX. During the growing season, the average difference in ULR between the DX site and other sites with vegetation cover can be up to 20Wm-2. The USR variability is the largest at LS-crop, while the diurnal variation of ULR is the same as that of Ts at all the four sites; (3) the differences in daily average sensible heat (H) and latent heat (LE) between DX and LS-crop are larger than 45 and 95Wm-2, respectively. The proportion of latent heat flux in the net radiation (LE/Rn) keeps increasing with the change of season from the spring to summer. XL site demonstrates a distinct forest feature; (4) surface albedo is small while the Bowen ratio is large at DX (an urban site). The urban heat island effect results in higher Ta and Ts at DX site that is 2°C higher than that at other sites in the nighttime. It is found that surface albedo and roughness length variability both increase at LS-crop during the harvest season and straw burning periods. LE is dominant due to irrigation. Negative H is observed since evaporative cooling leads to low Ts. Daily variability of Ts and Ta is the lowest at LS-crop while RH is the largest. In the summer, the grassland albedo at XL site gradually becomes larger than that at the sites in Lishui. Since the forest-like effects becomes more distinct at XL, LE/Rn increases rapidly. Thereby, although Ts is higher at XL than that at LS-grass , there is no large difference in Ta between the two sites.

Fallow land effects on land-atmosphere interactions in California drought

NASA Astrophysics Data System (ADS)

Lu, Y.; Melton, F. S.; Kueppers, L. M.

2015-12-01

The recent drought in California increased the area of fallow land, which is cropland not planted or irrigated per normal agricultural practice. The effects of fallow land on land-atmosphere interactions in drought years are not well studied, but theoretically should alter local energy balance and surface climate relative to normal years, which in turn could affect neighboring cropland. We examined these effects using a regional climate model (Weather Research and Forecasting model) coupled with a dynamic crop growth model (Community Land Model) that has an irrigation scheme to study the effects of fallow land in 2014, an extreme drought year in California. In our study, we used satellite-derived maps of cultivated and fallowed acreage, and defined summer fallow land in 2014 as the reduced percentage of cultivated land for each grid cell relative to the 2011 cultivated area (2011 was the most recent year following a winter with average or above average precipitation). Using a sensitivity experiment that kept large-scale climate boundary conditions constant, we found that fallow land resulted in even dryer and warmer weather that worsened the drought impact. Fallow land increased 2-meter air temperature by 0.1- 4 °C with 0-80% fallow land, mainly due to an increase in nighttime temperature. Fallow land warmed the atmosphere up to 850hpa during the day, and after sunset, the warmed atmosphere emitted downward longwave radiation that prevented the surface from rapidly cooling, and therefore resulted in warmer nights. Fallow land reduced near surface relative humidity by 5-30% and increased vapor pressure deficit by 0.5-2 kPa. These drier conditions increased the irrigation water demand in the nearby cropland: crops required 1-25% more irrigation with 10-80% fallow land within the same 10km grid cell. Our study suggests that fallow land has large impacts on land-atmosphere interactions and increases irrigation requirements in nearby cropland.

Front gardens to car parks: changes in garden permeability and effects on flood regulation.

PubMed

Warhurst, Jennifer R; Parks, Katherine E; McCulloch, Lindsay; Hudson, Malcolm D

2014-07-01

This study addresses the consequences of widespread conversion of permeable front gardens to hard standing car parking surfaces, and the potential consequences in high-risk urban flooding hotspots, in the city of Southampton. The last two decades has seen a trend for domestic front gardens in urban areas to be converted for parking, driven by the lack of space and increased car ownership. Despite media and political attention, the effects of this change are unknown, but increased and more intense rainfall, potentially linked to climate change, could generate negative consequences as runoff from impermeable surfaces increases. Information is limited on garden permeability change, despite the consequences for ecosystem services, especially flood regulation. We focused on eight flooding hotspots identified by the local council as part of a wider urban flooding policy response. Aerial photographs from 1991, 2004 and 2011 were used to estimate changes in surface cover and to analyse permeability change within a digital surface model in a GIS environment. The 1, 30 and 100 year required attenuation storage volumes were estimated, which are the temporary storage required to reduce the peak flow rate given surface permeability. Within our study areas, impermeable cover in domestic front gardens increased by 22.47% over the 20-year study period (1991-2011) and required attenuation storage volumes increased by 26.23% on average. These increases suggest that a consequence of the conversion of gardens to parking areas will be a potential increase in flooding frequency and severity - a situation which is likely to occur in urban locations worldwide. Copyright © 2014 Elsevier B.V. All rights reserved.

Effect of surface nano/micro-structuring on the early formation of microbial anodes with Geobacter sulfurreducens: Experimental and theoretical approaches.

PubMed

Champigneux, Pierre; Renault-Sentenac, Cyril; Bourrier, David; Rossi, Carole; Delia, Marie-Line; Bergel, Alain

2018-06-01

Smooth and nano-rough flat gold electrodes were manufactured with controlled Ra of 0.8 and 4.5nm, respectively. Further nano-rough surfaces (Ra 4.5nm) were patterned with arrays of micro-pillars 500μm high. All these electrodes were implemented in pure cultures of Geobacter sulfurreducens, under a constant potential of 0.1V/SCE and with a single addition of acetate 10mM to check the early formation of microbial anodes. The flat smooth electrodes produced an average current density of 0.9A·m -2 . The flat nano-rough electrodes reached 2.5A·m -2 on average, but with a large experimental deviation of ±2.0A·m -2 . This large deviation was due to the erratic colonization of the surface but, when settled on the surface, the cells displayed current density that was directly correlated to the biofilm coverage ratio. The micro-pillars considerably improved the experimental reproducibility by offering the cells a quieter environment, facilitating biofilm development. Current densities of up to 8.5A·m -2 (per projected surface area) were thus reached, in spite of rate limitation due to the mass transport of the buffering species, as demonstrated by numerical modelling. Nano-roughness combined with micro-structuring increased current density by a factor close to 10 with respect to the smooth flat surface. Copyright © 2018 Elsevier B.V. All rights reserved.

Bacterial Adhesion on the Titanium and Stainless-Steel Surfaces Undergone Two Different Treatment Methods: Polishing and Ultrafast Laser Treatment

NASA Astrophysics Data System (ADS)

Chik, N.; Zain, W. S. Wan Md; Mohamad, A. J.; Sidek, M. Z.; Ibrahim, W. H. Wan; Reif, A.; Rakebrandt, J. H.; Pfleging, W.; Liu, X.

2018-05-01

Bacterial adhesion has become a significant problem in many industries causing billions of dollars for its complicated removal treatment and maintenance. In this study, metal surfaces undergone treatment with ultrafast laser with varies power. The microstructure produced on its original surfaces were expected to prevent the adhesion of Escherichia coli (E. coli) ATCC 8739 and Staphylococcus aureus (S. aureus) ATCC 6838. The laser treatment was performed at 380 fs pulse duration, 515 µm central wavelength and a repetition rate of 200 kHz. Stainless steel AISI 316L was treated with an average laser power of 0.04 W (SS-0.04) and 0.11 W (SS-0.11), while Grade 5 titanium alloy was tested with high laser power 0.11 W (T-0.11). The adhesion was observed after 16 hours and the number of adhering bacteria was counted per cm2. The result achieved shows that, increasing the average laser power is leading to an enhanced S. aureus adhesion while E. coli adhesion is reduced which is due to the hydrophobicity interaction and difference in surface texture. Meanwhile, the laser treatment showed significant reduction of the bacterial adhesion on its surface compared to the polished surfaces. Thus, ultrafast laser texturing can be suggested as a promising method to reduce the bacterial adhesion, which reduced the adhesion of >80% for E. coli and >20% for S. aureus.

The effects of aircraft on climate and pollution. Part II: 20-year impacts of exhaust from all commercial aircraft worldwide treated individually at the subgrid scale.

PubMed

Jacobson, M Z; Wilkerson, J T; Naiman, A D; Lele, S K

2013-01-01

This study examines the 20-year impacts of emissions from all commercial aircraft flights worldwide on climate, cloudiness, and atmospheric composition. Aircraft emissions from each individual flight worldwide were modeled to evolve from the subgrid to grid scale with the global model described and evaluated in Part I of this study. Simulations with and without aircraft emissions were run for 20 years. Aircraft emissions were found to be responsible for -6% of Arctic surface global warming to date, -1.3% of total surface global warming, and -4% of global upper tropospheric warming. Arctic warming due to aircraft slightly decreased Arctic sea ice area. Longer simulations should result in more warming due to the further increase in CO2. Aircraft increased atmospheric stability below cruise altitude and decreased it above cruise altitude. The increase in stability decreased cumulus convection in favor of increased stratiform cloudiness. Aircraft increased total cloud fraction on average. Aircraft increased surface and upper tropospheric ozone by -0.4% and -2.5%, respectively and surface and upper-tropospheric peroxyacetyl nitrate (PAN) by -0.1% and -5%, respectively. Aircraft emissions increased tropospheric OH, decreasing column CO and CH4 by -1.7% and -0.9%, respectively. Aircraft emissions increased human mortality worldwide by -620 (-240 to 4770) deaths per year, with half due to ozone and the rest to particulate matter less than 2.5 micrometers in diameter (PM2.5).

Recent trends (2003-2013) of land surface heat fluxes on the southern side of the central Himalayas, Nepal

NASA Astrophysics Data System (ADS)

Amatya, Pukar Man; Ma, Yaoming; Han, Cunbo; Wang, Binbin; Devkota, Lochan Prasad

2015-12-01

Novice efforts have been made in order to study the regional distribution of land surface heat fluxes on the southern side of the central Himalayas utilizing high-resolution remotely sensed products, but these have been on instantaneous scale. In this study the Surface Energy Balance System model is used to obtain annual averaged maps of the land surface heat fluxes for 11 years (2003-2013) and study their annual trends on the central Himalayan region. The maps were derived at 5 km resolution using monthly input products ranging from satellite derived to Global Land Data Assimilation System meteorological data. It was found that the net radiation flux is increasing as a result of decreasing precipitation (drier environment). The sensible heat flux did not change much except for the northwestern High Himalaya and High Mountains. In northwestern High Himalaya sensible heat flux is decreasing because of decrease in wind speed, ground-air temperature difference, and increase in winter precipitation, whereas in High Mountains it is increasing due to increase in ground-air temperature difference and high rate of deforestation. The latent heat flux has an overall increasing trend with increase more pronounced in the lower regions compared to high elevated regions. It has been reported that precipitation is decreasing with altitude in this region. Therefore, the increasing trend in latent heat flux can be attributed to increase in net radiation flux under persistent forest cover and irrigation land used for agriculture.

Is the Surface Potential Integral of a Dipole in a Volume Conductor Always Zero? A Cloud Over the Average Reference of EEG and ERP.

PubMed

Yao, Dezhong

2017-03-01

Currently, average reference is one of the most widely adopted references in EEG and ERP studies. The theoretical assumption is the surface potential integral of a volume conductor being zero, thus the average of scalp potential recordings might be an approximation of the theoretically desired zero reference. However, such a zero integral assumption has been proved only for a spherical surface. In this short communication, three counter-examples are given to show that the potential integral over the surface of a dipole in a volume conductor may not be zero. It depends on the shape of the conductor and the orientation of the dipole. This fact on one side means that average reference is not a theoretical 'gold standard' reference, and on the other side reminds us that the practical accuracy of average reference is not only determined by the well-known electrode array density and its coverage but also intrinsically by the head shape. It means that reference selection still is a fundamental problem to be fixed in various EEG and ERP studies.

Crowdsourcing for error detection in cortical surface delineations.

PubMed

Ganz, Melanie; Kondermann, Daniel; Andrulis, Jonas; Knudsen, Gitte Moos; Maier-Hein, Lena

2017-01-01

With the recent trend toward big data analysis, neuroimaging datasets have grown substantially in the past years. While larger datasets potentially offer important insights for medical research, one major bottleneck is the requirement for resources of medical experts needed to validate automatic processing results. To address this issue, the goal of this paper was to assess whether anonymous nonexperts from an online community can perform quality control of MR-based cortical surface delineations derived by an automatic algorithm. So-called knowledge workers from an online crowdsourcing platform were asked to annotate errors in automatic cortical surface delineations on 100 central, coronal slices of MR images. On average, annotations for 100 images were obtained in less than an hour. When using expert annotations as reference, the crowd on average achieves a sensitivity of 82 % and a precision of 42 %. Merging multiple annotations per image significantly improves the sensitivity of the crowd (up to 95 %), but leads to a decrease in precision (as low as 22 %). Our experiments show that the detection of errors in automatic cortical surface delineations generated by anonymous untrained workers is feasible. Future work will focus on increasing the sensitivity of our method further, such that the error detection tasks can be handled exclusively by the crowd and expert resources can be focused on error correction.

Potential Impacts of Future Warming and Land Use Changes on Intra-Urban Heat Exposure in Houston, Texas

PubMed Central

Conlon, Kathryn; Monaghan, Andrew; Hayden, Mary; Wilhelmi, Olga

2016-01-01

Extreme heat events in the United States are projected to become more frequent and intense as a result of climate change. We investigated the individual and combined effects of land use and warming on the spatial and temporal distribution of daily minimum temperature (Tmin) and daily maximum heat index (HImax) during summer in Houston, Texas. Present-day (2010) and near-future (2040) parcel-level land use scenarios were embedded within 1-km resolution land surface model (LSM) simulations. For each land use scenario, LSM simulations were conducted for climatic scenarios representative of both the present-day and near-future periods. LSM simulations assuming present-day climate but 2040 land use patterns led to spatially heterogeneous temperature changes characterized by warmer conditions over most areas, with summer average increases of up to 1.5°C (Tmin) and 7.3°C (HImax) in some newly developed suburban areas compared to simulations using 2010 land use patterns. LSM simulations assuming present-day land use but a 1°C temperature increase above the urban canopy (consistent with warming projections for 2040) yielded more spatially homogeneous metropolitan-wide average increases of about 1°C (Tmin) and 2.5°C (HImax), respectively. LSM simulations assuming both land use and warming for 2040 led to summer average increases of up to 2.5°C (Tmin) and 8.3°C (HImax), with the largest increases in areas projected to be converted to residential, industrial and mixed-use types. Our results suggest that urbanization and climate change may significantly increase the average number of summer days that exceed current threshold temperatures for initiating a heat advisory for metropolitan Houston, potentially increasing population exposure to extreme heat. PMID:26863298

Role of Acoustoelectric Interaction in the Formation of Nanoscale Periodic Structures of Adsorbed Atoms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peleshchak, R. M., E-mail: peleshchak@rambler.ru; Lazurchak, I. I.; Kuzyk, O. V.

The role of acoustoelectric effects in the formation of nanoscale structures of adatoms, resulting from the self-consistent interaction of adatoms with a surface acoustic wave and the electronic subsystem, is studied for the case of charged and uncharged adatoms. It is shown that an increase in the doping level of a semiconductor with donor impurities at a fixed average adatom concentration results in an increase in the critical temperature below which self-organization processes occur.

Changes in stem quality of young thinned hardwoods

Treesearch

David L. Sonderman; David L. Sonderman

1986-01-01

Describes changes in limb-related defects on 18-year-old, even-aged hardwoods 6 years after thinning. Stocking levels of 30, 45, and 60 percent were studied. There were fewer defects per square foot of surface area in the higher stocking plots than in the lower stocking plots. The average number of live limbs decreased 83 percent in the unthinned plots and increased...

Corrosion behaviour and mechanical properties of functionally gradient materials developed for possible hard-tissue applications.

PubMed

Becker, B S; Bolton, J D

1997-12-01

Artificial hip joints have an average lifetime of 10 years due to aseptic loosening of the femoral stem attributed to polymeric wear debris; however, there is a steadily increasing demand from younger osteoarthritis patients aged between 15 and 40 year for a longer lasting joint of 25 years or more. Compliant layers incorporated into the acetabular cup generate elastohydrodynamic lubrication conditions between the bearing surfaces, reduce joint friction coefficients and wear debris production and could increase the average life of total hip replacements, and other human load-bearing joint replacements, i.e. total knee replacements. Poor adhesion between a fully dense substrate and the compliant layer has so far prevented any further exploitation. This work investigated the possibility of producing porous metallic, functionally gradient type acetabular cups using powder metallurgy techniques - where a porous surface was supported by a denser core - into which the compliant layers could be incorporated. The corrosion behaviour and mechanical properties of three biomedically approved alloys containing two levels of total porosity (>30% and <10%) were established, resulting in Ti-6Al-4V being identified as the most promising biocompatible functionally graded material, not only for this application but for other hard-tissue implants.

Insights into the effect of dilute acid, hot water or alkaline pretreatment on cellulose accessible surface area and the overall porosity of Populus

DOE PAGES

Meng, Xianzhi; Wells, Tyrone; Sun, Qining; ...

2015-06-19

Pretreatment is known to render biomass more reactive to cellulase by altering the chemical compositions as well as physical structures of biomass. Simons stain technique along with mercury porosimetry were applied on the acid, neutral, and alkaline pretreated materials to measure the accessible surface area of cellulose and pore size distribution of Populus. Results indicated that acid pretreatment is much more effective than water and alkaline pretreatment in terms of cellulose accessibility increase. Further investigation suggests that lignin does not dictate cellulose accessibility to the extent that hemicellulose does, but it does restrict xylan accessibility which in turn controls themore » access of cellulase to cellulose. The most interesting finding is that severe acid pretreatment significantly decreases the average pore size, i.e., 90% average size decrease could be observed after 60 min dilute acid pretreatment at 160 °C; moreover, the nano-pore space formed between coated microfibrils is increased after pretreatment, especially for the acid pretreatment, suggesting this particular type of biomass porosity is probably the most fundamental barrier to effective enzymatic hydrolysis.« less

Calcium dependent formation of tubular assemblies by recombinant S-layer proteins in vivo and in vitro

NASA Astrophysics Data System (ADS)

Korkmaz, Nuriye; Ostermann, Kai; Rödel, Gerhard

2011-03-01

Surface layer proteins have the appealing property to self-assemble in nanosized arrays in solution and on solid substrates. In this work, we characterize the formation of assembly structures of the recombinant surface layer protein SbsC of Geobacillus stearothermophilus ATTC 12980, which was tagged with enhanced green fluorescent protein and expressed in the yeast Saccharomyces cerevisiae. The tubular structures formed by the protein in vivo are retained upon bursting the cells by osmotic shock; however, their average length is decreased. During dialysis, monomers obtained by treatment with chaotropic chemicals recrystallize again to form tube-like structures. This process is strictly dependent on calcium (Ca2 + ) ions, with an optimal concentration of 10 mM. Further increase of the Ca2 + concentration results in multiple non-productive nucleation points. We further show that the lengths of the S-layer assemblies increase with time and can be controlled by pH. After 48 h, the average length at pH 9.0 is 4.13 µm compared to 2.69 µm at pH 5.5. Successful chemical deposition of platinum indicates the potential of recrystallized mSbsC-eGFP structures for nanobiotechnological applications.

Regional warming of hot extremes accelerated by surface energy fluxes consistent with drying soils

NASA Astrophysics Data System (ADS)

Donat, M.; Pitman, A.; Seneviratne, S. I.

2017-12-01

Strong regional differences exist in how hot temperature extremes increase under global warming. Using an ensemble of coupled climate models, we examine the regional warming rates of hot extremes relative to annual average warming rates in the same regions. We identify hotspots of accelerated warming of model-simulated hot extremes in Europe, North America, South America and Southeast China. These hotspots indicate where the warm tail of a distribution of temperatures increases faster than the average and are robust across most CMIP5 models. Exploring the conditions on the specific day the hot extreme occurs demonstrates the hotspots are explained by changes in the surface energy fluxes consistent with drying soils. Furthermore, in these hotspot regions we find a relationship between the temperature - heat flux correlation under current climate conditions and the magnitude of future projected changes in hot extremes, pointing to a potential emergent constraint for simulations of future hot extremes. However, the model-simulated accelerated warming of hot extremes appears inconsistent with observations of the past 60 years, except over Europe. The simulated acceleration of hot extremes may therefore be unreliable, a result that necessitates a re-evaluation of how climate models resolve the relevant terrestrial processes.

Microwave remote sensing and its application to soil moisture detection

NASA Technical Reports Server (NTRS)

Newton, R. W. (Principal Investigator)

1977-01-01

The author has identified the following significant results. Experimental measurements were utilized to demonstrate a procedure for estimating soil moisture, using a passive microwave sensor. The investigation showed that 1.4 GHz and 10.6 GHz can be used to estimate the average soil moisture within two depths; however, it appeared that a frequency less than 10.6 GHz would be preferable for the surface measurement. Average soil moisture within two depths would provide information on the slope of the soil moisture gradient near the surface. Measurements showed that a uniform surface roughness similar to flat tilled fields reduced the sensitivity of the microwave emission to soil moisture changes. Assuming that the surface roughness was known, the approximate soil moisture estimation accuracy at 1.4 GHz calculated for a 25% average soil moisture and an 80% degree of confidence, was +3% and -6% for a smooth bare surface, +4% and -5% for a medium rough surface, and +5.5% and -6% for a rough surface.

Future heat waves and surface ozone

NASA Astrophysics Data System (ADS)

Meehl, Gerald A.; Tebaldi, Claudia; Tilmes, Simone; Lamarque, Jean-Francois; Bates, Susan; Pendergrass, Angeline; Lombardozzi, Danica

2018-06-01

A global Earth system model is used to study the relationship between heat waves and surface ozone levels over land areas around the world that could experience either large decreases or little change in future ozone precursor emissions. The model is driven by emissions of greenhouse gases and ozone precursors from a medium-high emission scenario (Representative Concentration Pathway 6.0–RCP6.0) and is compared to an experiment with anthropogenic ozone precursor emissions fixed at 2005 levels. With ongoing increases in greenhouse gases and corresponding increases in average temperature in both experiments, heat waves are projected to become more intense over most global land areas (greater maximum temperatures during heat waves). However, surface ozone concentrations on future heat wave days decrease proportionately more than on non-heat wave days in areas where ozone precursors are prescribed to decrease in RCP6.0 (e.g. most of North America and Europe), while surface ozone concentrations in heat waves increase in areas where ozone precursors either increase or have little change (e.g. central Asia, the Mideast, northern Africa). In the stabilized ozone precursor experiment, surface ozone concentrations increase on future heat wave days compared to non-heat wave days in most regions except in areas where there is ozone suppression that contributes to decreases in ozone in future heat waves. This is likely associated with effects of changes in isoprene emissions at high temperatures (e.g. west coast and southeastern North America, eastern Europe).

Tensile Strength and Microstructural Characterization of Uncoated and Coated HPZ Ceramic Fibers

NASA Technical Reports Server (NTRS)

Bansal, Narottam P.; Wheeler, Donald R.; Dickerson, Robert M.

1996-01-01

Tensile strengths of as-received HPZ fiber and those surface coated with BN, BN/SiC, and BN/Si3N4 have been determined at room temperature using a two-parameter Weibull distribution. Nominally approx. 0.4 micron BN and 0.2 micron SiC or Si3N4 coatings were deposited on the fibers by chemical vapor deposition using a continuous reactor. The average tensile strength of uncoated HPZ fiber was 2.0 +/- 0.56 GPa (290 +/- 81 ksi) with a Weibull modulus of 4.1. For the BN coated fibers, the average strength and the Weibull modulus increased to 2.39 +/- 0.44 GPa (346 +/- 64 ksi) and 6.5, respectively. The HPZ/BN/SiC fibers showed an average strength of 2.0 +/- 0.32 GPa (290 +/- 47 ksi) and Weibull modulus of 7.3. Average strength of the fibers having a dual BN/Si3N4 surface coating degraded to 1.15 +/- 0.26 GPa (166 +/- 38 ksi) with a Weibull modulus of 5.3. The chemical composition and thickness of the fiber coatings were determined using scanning Auger analysis. Microstructural analysis of the fibers and the coatings was carried out by scanning electron microscopy and transmission electron microscopy. A microporous silica-rich layer approx. 200 nm thick is present on the as-received HPZ fiber surface. The BN coatings on the fibers are amorphous to partly turbostratic and contaminated with carbon and oxygen. Silicon carbide coating was crystalline whereas the silicon nitride coating was amorphous. The silicon carbide and silicon nitride coatings are non-stoichiometric, non-uniform, and granular. Within a fiber tow, the fibers on the outside had thicker and more granular coatings than those on the inside.

Bio-Optical Properties and Ocean Color Algorithms for Coastal Waters Influenced by the Mississippi River During a Cold Front Passage

NASA Technical Reports Server (NTRS)

D'Sa Eurico J.; Miller, Richard L.; DelCastillo, Carlos

2006-01-01

During the passage of a cold front in March 2002, bio-optical properties examined in coastal waters impacted by the Mississippi River indicated westward advective flows and increasing river discharge containing a larger nonalgal particle content contributed significantly to surface optical variability. A comparison of seasonal data from three cruises indicated spectral models of absorption and scattering to be generally consistent with other coastal environments, while their parameterization in terms of chlorophyll a concentration (Chl) showed seasonal variability. The exponential slope of the colored dissolved organic matter (CDOM) averaged 0.0161 plus or minus 0.00054 per nanometer, and for nonalgal absorption it averaged 0.011 per nanometer with deviations from general trends observed due to anomalous water properties. Although the phytoplankton specific absorption coefficients varied over a wide range (0.02 to 0.1 square meters (mg Chl) sup -1)) being higher in offshore surface waters, values of phytoplankton absorption spectra at the SeaWiFS wavebands were highly correlated to modeled values. The normalized scattering spectral shapes and the mean spectrum were in agreement to observations in other coastal waters, while the backscattering ratios were on average lower in phytoplankton dominated surface waters (0.0101 plus or minus 0.002) and higher in near-bottom waters (0.0191 plus or minus 0.0045) with low Chl. Average percent differences in remote sensing reflectance R (sub rs) derived form modeled and in-eater radiometric measurements were highest in the blue wavebands (52%) and at sampling stations with a ore stratified water column. Estimates of Chl and CDOM absorption derived from SeaWiFS images generated using regional empirical algorithms were highly correlated to in situ data.

Interfacial spreading effects on one-dimensional organic liquid imbibition in water-wetted porous media

NASA Astrophysics Data System (ADS)

McBride, J. F.; Simmons, C. S.; Cary, J. W.

1992-10-01

The spreading coefficient, Csp, determines whether an organic immiscible liquid, OIL, will form a lens ( Csp < 0) or will spread spontaneously ( Csp > 0) on a water surface. An OIL that forms a lens does not perfectly wet the water surface and therefore has a contact angle greater than 0°. The one-dimensional rate at which an OIL spreads spontaneously on a water surface is proportional to the square root of Csp. Of the OIL's that pose a contaminant threat to the subsurface, the majority has a non-zero Csp. To test the influence of such interfacial spreading phenomena on OIL infiltration in a pristine vadose zone, upward OIL and water imbibition infiltration experiments were performed in glass-bead columns, moistened with water, by using OIL's with different Csp. An analytical model for saturated liquid front rise was used to inversely estimate the effective capillary pressure head at the front and the average liquid conductivity. A nonspreading OIL ( Csp ≪ 0) exhibited a reduced capillary pressure head in the water-wetted glass beads. A spontaneously spreading OIL ( Csp ≫0) manifested an enhanced capillary pressure head. Reduced capillary pressure head was associated with an increase in average conductivity, and enhanced capillary pressure head was associated with a decrease in average conductivity when compared to the average water conductivity during water imbibition. The employed experimental method and mathematical analysis of dynamic flow, subject to interfacial spreading phenomena, are practical for quantifying parameters for use in sharp-front OIL infiltration models, but more research is needed to determine how to incorporate the spreading coefficient in numerical multiphase flow models.

Characteristics of Nitrogen Loss through Surface-Subsurface Flow on Red Soil Slopes of Southeast China

NASA Astrophysics Data System (ADS)

Zheng, Haijin; Liu, Zhao; Zuo, Jichao; Wang, Lingyun; Nie, Xiaofei

2017-12-01

Soil nitrogen (N) loss related to surface flow and subsurface flow (including interflow and groundwater flow) from slope lands is a global issue. A lysimetric experiment with three types of land cover (grass cover, GC; litter cover, LC; and bare land, BL) were carried out on a red soil slope land in southeast China. Total Nitrogen (TN) loss through surface flow, interflow and groundwater flow was observed under 28 natural precipitation events from 2015 to 2016. TN concentrations from subsurface flow on BL and LC plots were, on average, 2.7-8.2 and 1.5-4.4 times greater than TN concentrations from surface flow, respectively; the average concentration of TN from subsurface flow on GC was about 36-56% of that recorded from surface flow. Surface flow, interflow and groundwater flow contributed 0-15, 2-9 and 76-96%, respectively, of loss load of TN. Compared with BL, GC and LC intercepted 83-86% of TN loss through surface runoff; GC intercepted 95% of TN loss through subsurface flow while TN loss through subsurface flow on LC is 2.3 times larger than that on BL. In conclusion, subsurface flow especially groundwater flow is the dominant hydrological rout for N loss that is usually underestimated. Grass cover has the high retention of N runoff loss while litter mulch will increase N leaching loss. These findings provide scientific support to control N runoff loss from the red soil slope lands by using suitable vegetation cover and mulching techniques.

Disk-averaged synthetic spectra of Mars

NASA Technical Reports Server (NTRS)

Tinetti, Giovanna; Meadows, Victoria S.; Crisp, David; Fong, William; Velusamy, Thangasamy; Snively, Heather

2005-01-01

The principal goal of the NASA Terrestrial Planet Finder (TPF) and European Space Agency's Darwin mission concepts is to directly detect and characterize extrasolar terrestrial (Earthsized) planets. This first generation of instruments is expected to provide disk-averaged spectra with modest spectral resolution and signal-to-noise. Here we use a spatially and spectrally resolved model of a Mars-like planet to study the detectability of a planet's surface and atmospheric properties from disk-averaged spectra. We explore the detectability as a function of spectral resolution and wavelength range, for both the proposed visible coronograph (TPFC) and mid-infrared interferometer (TPF-I/Darwin) architectures. At the core of our model is a spectrum-resolving (line-by-line) atmospheric/surface radiative transfer model. This model uses observational data as input to generate a database of spatially resolved synthetic spectra for a range of illumination conditions and viewing geometries. The model was validated against spectra recorded by the Mars Global Surveyor-Thermal Emission Spectrometer and the Mariner 9-Infrared Interferometer Spectrometer. Results presented here include disk-averaged synthetic spectra, light curves, and the spectral variability at visible and mid-infrared wavelengths for Mars as a function of viewing angle, illumination, and season. We also considered the differences in the spectral appearance of an increasingly ice-covered Mars, as a function of spectral resolution, signal-to-noise and integration time for both TPF-C and TPFI/ Darwin.

Disk-averaged synthetic spectra of Mars.

PubMed

Tinetti, Giovanna; Meadows, Victoria S; Crisp, David; Fong, William; Velusamy, Thangasamy; Snively, Heather

2005-08-01

The principal goal of the NASA Terrestrial Planet Finder (TPF) and European Space Agency's Darwin mission concepts is to directly detect and characterize extrasolar terrestrial (Earthsized) planets. This first generation of instruments is expected to provide disk-averaged spectra with modest spectral resolution and signal-to-noise. Here we use a spatially and spectrally resolved model of a Mars-like planet to study the detectability of a planet's surface and atmospheric properties from disk-averaged spectra. We explore the detectability as a function of spectral resolution and wavelength range, for both the proposed visible coronograph (TPFC) and mid-infrared interferometer (TPF-I/Darwin) architectures. At the core of our model is a spectrum-resolving (line-by-line) atmospheric/surface radiative transfer model. This model uses observational data as input to generate a database of spatially resolved synthetic spectra for a range of illumination conditions and viewing geometries. The model was validated against spectra recorded by the Mars Global Surveyor-Thermal Emission Spectrometer and the Mariner 9-Infrared Interferometer Spectrometer. Results presented here include disk-averaged synthetic spectra, light curves, and the spectral variability at visible and mid-infrared wavelengths for Mars as a function of viewing angle, illumination, and season. We also considered the differences in the spectral appearance of an increasingly ice-covered Mars, as a function of spectral resolution, signal-to-noise and integration time for both TPF-C and TPFI/ Darwin.

Injectable and porous PLGA microspheres that form highly porous scaffolds at body temperature

PubMed Central

Qutachi, Omar; Vetsch, Jolanda R.; Gill, Daniel; Cox, Helen; Scurr, David J.; Hofmann, Sandra; Müller, Ralph; Quirk, Robin A.; Shakesheff, Kevin M.; Rahman, Cheryl V.

2014-01-01

Injectable scaffolds are of interest in the field of regenerative medicine because of their minimally invasive mode of delivery. For tissue repair applications, it is essential that such scaffolds have the mechanical properties, porosity and pore diameter to support the formation of new tissue. In the current study, porous poly(dl-lactic acid-co-glycolic acid) (PLGA) microspheres were fabricated with an average size of 84 ± 24 μm for use as injectable cell carriers. Treatment with ethanolic sodium hydroxide for 2 min was observed to increase surface porosity without causing the microsphere structure to disintegrate. This surface treatment also enabled the microspheres to fuse together at 37 °C to form scaffold structures. The average compressive strength of the scaffolds after 24 h at 37 °C was 0.9 ± 0.1 MPa, and the average Young’s modulus was 9.4 ± 1.2 MPa. Scaffold porosity levels were 81.6% on average, with a mean pore diameter of 54 ± 38 μm. This study demonstrates a method for fabricating porous PLGA microspheres that form solid porous scaffolds at body temperature, creating an injectable system capable of supporting NIH-3T3 cell attachment and proliferation in vitro. PMID:25152354

Photochemistry on ultrathin metal films: Strongly enhanced cross sections for NO2 on Ag /Si(100)

NASA Astrophysics Data System (ADS)

Wesenberg, Claudia; Autzen, Olaf; Hasselbrink, Eckart

2006-12-01

The surface photochemistry of NO2 on ultrathin Ag(111) films (5-60nm ) on Si(100) substrates has been studied. NO2, forming N2O4 on the surface, dissociates to release NO and NO2 into the gas phase with translational energies exceeding the equivalent of the sample temperature. An increase of the photodesorption cross section is observed for 266nm light when the film thickness is decreased below 30nm despite the fact that the optical absorptivity decreases. For 4.4nm film thickness this increase is about threefold. The data are consistent with a similar effect for 355nm light. The reduced film thickness has no significant influence on the average translation energy of the desorbing molecules or the branching into the different channels. The increased photodesorption cross section is interpreted to result from photon absorption in the Si substrate producing electrons with no or little momenta parallel to the surface at energies where this is not allowed in Ag. It is suggested that these electrons penetrate through the Ag film despite the gap in the surface projected band structure.

Shear velocity profiles in the crust and lithospheric mantle across Tibet

NASA Astrophysics Data System (ADS)

Agius, M. R.; Lebedev, S.

2010-12-01

We constrain variations in the crustal and lithospheric structure across Tibet, using phase velocities of seismic surface waves. The data are seismograms recorded by broadband instruments of permanent and temporary networks within and around the plateau. Phase-velocity measurements are performed in broad period ranges using an elaborate recent implementation of the 2-station method. A combination of the cross-correlation and multimode-waveform-inversion measurements using tens to hundreds of seismograms per station pair produces robust, accurate phase-velocity curves for Rayleigh and Love waves. We use our new measurements to infer phase-velocity variations and to constrain S-velocity profiles in different parts of the plateau, including radial anisotropy and depths of lithospheric discontinuities. We observe a mid-crustal low-velocity zone (LVZ) in the 20-45 km depth range across the plateau, with S-velocities within a 3.2-3.5 km/s range. This LVZ coincides with a low-resistivity layer inferred from magnetotelluric studies, interpreted as evidence for partial melting in the middle crust. Surface-wave data are also consistent with radial anisotropy in this layer, indicative of horizontal flow. At the north-eastern boundary of the plateau, past the Kunlun Fault, the mid-crustal LVZ, in the sense of an S-velocity decrease with depth in the 15-25 km depth range, is not required by the surface-wave data although the velocity is still relatively low. The mantle-lithosphere structure shows a pronounced contrast between the south-western and central-northern parts of the plateau. The south-west is underlain by a thick, high-velocity, craton-like lithospheric mantle. Below central Lhasa the uppermost mantle appears to be close to global average with an increase in velocity between 150 - 250 km depth. Beneath central and northern Tibet, the average S velocity between the Moho and 200 km depth is close to the global continental average (4.5 km/s). In order to investigate the finer detail of the lithosphere in the North we perform an extensive series of test inversions. We find that surface-wave dispersion measurements alone are consistent both with models that have low S velocity just beneath the Moho, increasing with depth below, and with models that display a thin high-velocity mantle lid underlain by a low-velocity zone (asthenosphere). To resolve this non-uniqueness from the inversion model, we combine our surface-wave measurements in the Qiangtang Block with receiver-function constraints on the Moho depth, and Sn constraints on the uppermost mantle S velocities. We show that the data is matched significantly better with models that contain a thin, high-velocity lithosphere (up to 90 km thick) underlain by a low-velocity zone than by models with no wave-speed decrease between the Moho and ~100 km depth. In the deeper upper mantle (below ~150 km depth), S velocity increases and is likely to exceed the global average value.

Stream structure at low flow: biogeochemical patterns in intermittent streams over space and time

NASA Astrophysics Data System (ADS)

MacNeille, R. B.; Lohse, K. A.; Godsey, S.; McCorkle, E. P.; Parsons, S.; Baxter, C.

2017-12-01

Climate change in the western United States is projected to lead to earlier snowmelt, increasing fire risk and potentially transitioning perennial streams to intermittent ones. Differences between perennial and intermittent streams, especially the temporal and spatial patterns of carbon and nutrient dynamics during periods of drying, are understudied. We examined spatial and temporal patterns in surface water biogeochemistry during a dry (2016) and a wet (2017) water year in southwest Idaho. We hypothesized that as streams dry, carbon concentrations would increase due to evapoconcentration and/or increased in-stream production, and that the heterogeneity of constituents within each stream would increase. We expected these patterns to differ in a high water year compared to a low water year due to algae scour. Finally, we expected that the spatial heterogeneity of biogeochemistry would decrease with time following fire. To test these hypotheses, in 2016 we collected surface water samples at 50 meter intervals from two intermittent headwater streams over 2,500 meter reaches in April, May, and June. One stream is burned and one remains unburned. In 2017, we collected surface water at the 50, 25 and 10 meter intervals from each stream once during low flow. 2016 results showed average concentrations of dissolved inorganic carbon (DIC) and dissolved organic carbon (DOC) increased 3-fold from April to June in the burned site compared to the unburned site. Interestingly, average concentrations of total nitrogen (TN) dropped substantially for the burned site over these three months, but only decreased slightly for the unburned site over the same time period. Between wet and dry water years, we observed a decrease in the spatial heterogeneity as measured by the standard deviation (SD) in conductivity at 50 meter intervals; the burned stream had a SD of 23.08 in 2016 and 11.40 in 2017 whereas the unburned stream had similar SDs. We conclude that the burned stream experienced more inter and intra-annual surface water change in chemistry patterns than did the unburned stream.

Favorable Influence of Hydrophobic Surfaces on Protein Structure in Porous Organically-modified Silica Glasses

PubMed Central

Menaa, Bouzid; Herrero, Mar; Rives, Vicente; Lavrenko, Mayya; Eggers, Daryl K.

2008-01-01

Organically-modified siloxanes were used as host materials to examine the influence of surface chemistry on protein conformation in a crowded environment. The sol-gel materials were prepared from tetramethoxysilane and a series of monosubstituted alkoxysilanes, RSi(OR′)3, featuring alkyl groups of increasing chain length in the R-position. Using circular dichroism spectroscopy in the far-UV region, apomyoglobin was found to transit from an unfolded state to a native-like helical state as the content of the hydrophobic precursor increased from 0–15%. At a fixed molar content of 5% RSi(OR’)3, the helical structure of apomyoglobin increased with the chain length of the R-group, i.e. methyl < ethyl < n-propyl < n-butyl < n-hexyl. This trend also was observed for the tertiary structure of ribonuclease A, suggesting that protein folding and biological activity are sensitive to the hydrophilic/hydrophobic balance of neighboring surfaces. The observed changes in protein structure did not correlate with total surface area or the average pore size of the modified glasses, but scanning electron microscopy images revealed an interesting relationship between surface morphology and alkyl chain length. The unexpected benefit of incorporating a low content of hydrophobic groups into a hydrophilic surface may lead to materials with improved biocompatibility for use in biosensors and implanted devices. PMID:18359512

Fabrication of a nano-cone array on a p-GaN surface for enhanced light extraction efficiency from GaN-based tunable wavelength LEDs.

PubMed

Soh, C B; Wang, B; Chua, S J; Lin, Vivian K X; Tan, Rayson J N; Tripathy, S

2008-10-08

We report on the fabrication of a nano-cone structured p-GaN surface for enhanced light extraction from tunable wavelength light emitting diodes (LEDs). Prior to p-contact metallization, self-assembled colloidal particles are deposited and used as a mask for plasma etching to create nano-cone structures on the p-GaN layer of LEDs. A well-defined periodic nano-cone array, with an average cone diameter of 300 nm and height of 150 nm, is generated on the p-GaN surface. The photoluminescence emission intensity recorded from the regions with the nano-cone array is increased by two times as compared to LEDs without surface patterning. The light output power from the LEDs with surface nano-cones shows significantly higher electroluminescence intensity at an injection current of 70 mA. This is due to the internal multiple scattering of light from the nano-cone sidewalls. Furthermore, we have shown that with an incorporation of InGaN nanostructures in the quantum well, the wavelength of these surface-patterned LEDs can be tuned from 517 to 488 nm with an increase in the injection current. This methodology may serve as a practical approach to increase the light extraction efficiency from wavelength tunable LEDs.

Impact of Future Emissions and Climate Change on Surface Ozone over China

NASA Astrophysics Data System (ADS)

Ma, C. T.; Westervelt, D. M.; Fiore, A. M.; Rieder, H. E.; Kinney, P.; Wang, S.; Correa, G. J. P.

2017-12-01

China's immense ambient air pollution problem and world-leading greenhouse gas emissions place it at the forefront of global efforts to address these related environmental concerns. Here, we analyze the impact of ECLIPSE (Evaluating the Climate and Air Quality Impacts of Short-Lived Pollutants) future emissions scenarios representative of current legislation (CLE) and maximum technically feasible emissions reductions (MFR) on surface ozone (O3) concentrations over China in the 2030s and 2050s, in the context of a changing climate. We use a suite of simulations performed with the NOAA Geophysical Fluid Dynamics Laboratory's AM3 global chemistry-climate model. To estimate the impact of climate change in isolation on Chinese air quality, we hold emissions of air pollutants including O3 precursors fixed at 2015 levels but allow climate (global sea surface temperatures and sea ice cover) to change according to decadal averages for the years 2026-2035 and 2046-2055 from a three-member ensemble of GFDL-CM3 simulations under the RCP8.5 high warming scenario. Evaluation of the present-day simulation (2015 CLE) with observations from 1497 chiefly urban air quality monitoring stations shows that simulated surface O3 is positively biased by 26 ppb on average over the domain of China. Previous studies, however, have shown that the modeled ozone response to changes in NOx emissions over the Eastern United States mirrors the magnitude and structure of observed changes in maximum daily average 8-hour (MDA8) O3 distributions. Therefore, we use the model's simulated changes for the 2030s and 2050s to project changes in policy-relevant MDA8 O3 concentrations. We find an overall increase in MDA8 O3 for CLE scenarios in which emissions of NOx precursors are projected to increase, and under MFR scenarios, an overall decrease, with the highest changes occurring in summertime for both 2030 and 2050 MFR. Under climate change alone, the model simulates a mean summertime decrease of 1.3 ppb and wintertime increase of 3.3 ppb by 2050. Adjustment of the observed site-level MDA8 O3 distribution to reflect regionally interpolated projected changes from AM3 allows us to examine changes in the number of days in exceedance of MDA8 O3 Level I (50 ppb) and Level II (80 ppb) Chinese national ambient air quality standards.

Salivary bisphenol A levels and their association with composite resin restoration.

PubMed

Lee, Jung-Ha; Yi, Seung-Kyoo; Kim, Se-Yeon; Kim, Ji-Soo; Son, Sung-Ae; Jeong, Seung-Hwa; Kim, Jin-Bom

2017-04-01

Composite resin has been increasingly used in an effort to remove minimal amount of tooth structure and are used for restoring not just carious cavities but also cervical abrasion. To synthesize composite resin, bisphenol A (BPA) is used. The aim of the study was to measure the changes in salivary BPA level related with composite resin restoration. ELISA was used to examine the BPA levels in the saliva collected from 30 volunteers whose teeth were filled with composite resin. Salivary samples were collected immediately before filling and 5 min and 7 d after filling. Wilcoxon signed-ranks test and linear regression were performed to test the significant differences of the changes in BPA levels in saliva. Before a new composite resin filling, there was no significant difference between with and without existing filling of composite resin and BPA level in the saliva was not correlated to the number of filled surfaces with composite resin. However, BPA level in the saliva increased to average 3.64 μg/L from average 0.15 μg/L after filling 5 min. BPA level increased in proportion with the number of filled surfaces. BPA level decreased to average 0.59 after filling 7 d. However it was higher than the BPA level before a new composite resin filling. Considering 50 μg/kg/day as the Tolerable Daily Intake of BPA suggested by European Food Safety Authority, the amount of BPA eluted in saliva after the composite resin filling is considered a safe level that is not a hazard to health at all. Copyright © 2016 Elsevier Ltd. All rights reserved.

Changes in future air quality, deposition, and aerosol-cloud interactions under future climate and emission scenarios

NASA Astrophysics Data System (ADS)

Glotfelty, Timothy; Zhang, Yang; Karamchandani, Prakash; Streets, David G.

2016-08-01

The prospect of global climate change will have wide scale impacts, such as ecological stress and human health hazards. One aspect of concern is future changes in air quality that will result from changes in both meteorological forcing and air pollutant emissions. In this study, the GU-WRF/Chem model is employed to simulate the impact of changing climate and emissions following the IPCC AR4 SRES A1B scenario. An average of 4 future years (2020, 2030, 2040, and 2050) is compared against an average of 2 current years (2001 and 2010). Under this scenario, by the Mid-21st century global air quality is projected to degrade with a global average increase of 2.5 ppb in the maximum 8-hr O3 level and of 0.3 μg m-3 in 24-hr average PM2.5. However, PM2.5 changes are more regional due to regional variations in primary aerosol emissions and emissions of gaseous precursor for secondary PM2.5. Increasing NOx emissions in this scenario combines with a wetter climate elevating levels of OH, HO2, H2O2, and the nitrate radical and increasing the atmosphere's near surface oxidation state. This differs from findings under the RCP scenarios that experience declines in OH from reduced NOx emissions, stratospheric recovery of O3, and increases in CH4 and VOCs. Increasing NOx and O3 levels enhances the nitrogen and O3 deposition, indicating potentially enhanced crop damage and ecosystem stress under this scenario. The enhanced global aerosol level results in enhancements in aerosol optical depth, cloud droplet number concentration, and cloud optical thickness. This leads to dimming at the Earth's surface with a global average reduction in shortwave radiation of 1.2 W m-2. This enhanced dimming leads to a more moderate warming trend and different trends in radiation than those found in NCAR's CCSM simulation, which does not include the advanced chemistry and aerosol treatment of GU-WRF/Chem and cannot simulate the impacts of changing climate and emissions with the same level of detailed treatments. This study indicates that effective climate mitigation and emission control strategies are needed to prevent future health impact and ecosystem stress. Further, studies that are used to develop these strategies should use fully coupled models with sophisticated chemical and aerosol-interaction treatments that can provide a more realistic representation of the atmosphere.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Glotfelty, Timothy; Zhang, Yang; Karamchandani, Prakash

The prospect of global climate change will have wide scale impacts, such as ecological stress and human health hazards. One aspect of concern is future changes in air quality that will result from changes in both meteorological forcing and air pollutant emissions. In this study, the GU-WRF/Chem model is employed to simulate the impact of changing climate and emissions following the IPCC AR4 SRES A1B scenario. An average of 4 future years (2020, 2030, 2040, and 2050) is compared against an average of 2 current years (2001 and 2010). Under this scenario, by the Mid-21st century global air quality ismore » projected to degrade with a global average increase of 2.5 ppb in the maximum 8-hr O 3 level and of 0.3 mg m 3 in 24-hr average PM2.5. However, PM2.5 changes are more regional due to regional variations in primary aerosol emissions and emissions of gaseous precursor for secondary PM2.5. Increasing NOx emissions in this scenario combines with a wetter climate elevating levels of OH, HO 2, H 2O 2, and the nitrate radical and increasing the atmosphere’s near surface oxidation state. This differs from findings under the RCP scenarios that experience declines in OH from reduced NOx emissions, stratospheric recovery of O 3, and increases in CH 4 and VOCs. Increasing NO x and O 3 levels enhances the nitrogen and O 3 deposition, indicating potentially enhanced crop damage and ecosystem stress under this scenario. The enhanced global aerosol level results in enhancements in aerosol optical depth, cloud droplet number concentration, and cloud optical thickness. This leads to dimming at the Earth’s surface with a global average reduction in shortwave radiation of 1.2 W m 2 . This enhanced dimming leads to a more moderate warming trend and different trends in radiation than those found in NCAR’s CCSM simulation, which does not include the advanced chemistry and aerosol treatment of GU-WRF/Chem and cannot simulate the impacts of changing climate and emissions with the same level of detailed treatments. This study indicates that effective climate mitigation and emission control strategies are needed to prevent future health impact and ecosystem stress. Further, studies that are used to develop these strategies should use fully coupled models with sophisticated chemical and aerosol-interaction treatments that can provide a more realistic representation of the atmosphere.« less

A low-cost, high-efficiency and high-flexibility surface modification technology for a black bisphenol A polycarbonate board

NASA Astrophysics Data System (ADS)

Wang, Suhuan; Liu, Jianguo; Lv, Ming; Zeng, Xiaoyan

2014-09-01

In this paper, a low-cost, high-efficiency and high-flexibility surface modification technology for polymer materials was achieved at high laser scanning speeds (600-1000 mm s-1) and using an all-solid state, Q-switched, high-average power, and nanosecond pulse ultraviolet (355 nm wavelength) laser. During the surface modification of a very important engineering plastic, i.e., black bisphenol A polycarbonate (BAPC) board, it was found that different laser parameters (e.g., laser fluence and pulse frequency) were able to result in different surface microstructures (e.g., many tiny protuberances or a porous microstructure with periodical V-type grooves). After the modification, although the total relative content of the oxygen-containing groups (e.g., Csbnd O and COO-) on the BAPC surface increased, however, the special microstructures played a deciding role in the surface properties (e.g., contact angle and surface energy) of the BAPC. The change trend of the water contact angle on the BAPC surface was with an obvious increase, that of the diiodomethane contact angle was with a most decrease, and that of the ethylene glycol contact angle was between the above two. It showed that the wetting properties of the three liquids on the modified BAPC surface were different. Basing on the measurements of the contact angles of the three liquids, and according to the Young equation and the Lifshitz van der Waals and Lewis acid-base theory, the BAPC surface energy after the modification was calculated. The results were that, in a broad range of laser fluences, pulse frequencies and scanning speeds, the surface energy had a significant increase (e.g., from the original of about 44 mJ m-2 to the maximum of about 70 mJ m-2), and the higher the laser pulse frequency, the more significant the increase. This would be very advantageous to fabricate the high-quality micro-devices and micro-systems on the modified surface.

The effect of aluminium nanocoating and water pH value on the wettability behavior of an aluminium surface

NASA Astrophysics Data System (ADS)

Ali, Naser; Teixeira, Joao A.; Addali, Abdulmajid; Al-Zubi, Feras; Shaban, Ehab; Behbehani, Ismail

2018-06-01

Experimental investigation was performed to highlight the influence of ionic bounding and surface roughness effects on the surface wettability. Nanocoating technique via e-beam physical vapor deposition process was used to fabricate aluminium (Al) film of 50, 100, and 150 nm on the surface of an Al substrate. Microstructures of the samples before and after deposition were observed using an atomic force microscopy. A goniometer device was later on used to examine the influence of surface topography on deionised water of pH 4, 7 and 9 droplets at a temperature ranging from 10 °C to 60 °C through their contact angles with the substrate surface, for both coated and uncoated samples. It was found that, although the coated layer has reduced the mean surface roughness of the sample from 10.7 nm to 4.23 nm, by filling part of the microstructure gaps with Al nanoparticles, the wettability is believed to be effected by the ionic bounds between the surface and the free anions in the fluid. As the deionised water of pH 4, and 9 gave an increase in the average contact angles with the increase of the coated layer thickness. On the other hand, the deionised water of pH 7 has showed a negative relation with the film thickness, where the contact angle reduced as the thickness of the coated layer was increased. The results from the aforementioned approach had showed that nanocoating can endorse the hydrophobicity (unwitting) nature of the surface when associated with free ions hosted by the liquid.

Switchgrass potential on reclaimed surface mines for biofuel production in West Virginia

NASA Astrophysics Data System (ADS)

Marra, Michael A.

The high cost and environmental risks associated with non-renewable energy sources has caused an increased interest in, and development of renewable biofuels. Switchgrass (Panicum virgatum L.), a warm season perennial grass, has been investigated as a source of biofuel feedstock due to its high biomass production on marginal soils, its tolerance of harsh growing conditions, and its ability to provide habitat for wildlife and soil conservation cover. West Virginia contains vast expanses of reclaimed surface mine lands and could potentially benefit from the production of switchgrass as a biofuel feedstock. Furthermore, switchgrass production could satisfy Surface Mining Reclamation and Control Act of 1977 (SMCRA) requirements for reclamation bond release to mine operators. Three separate studies will be discussed in this thesis to determine if switchgrass grown on reclaimed surface mines can produce yields similar to yields from stands grown under normal agronomic conditions and what common surface mining reclamation practices may be most appropriate for growing switchgrass. The first study examined yield production of three commercially-available, upland switchgrass varieties grown on two reclaimed surface mines in production years two, three and four. The Hampshire Hill mine site, which was reclaimed in the late 1990s using top soil and treated municipal sludge, averaged 5,800 kg (ha-yr)-1 of switchgrass compared to 803 kg (ha-yr)-1 at the Hobet 21 site which was reclaimed with crushed, unweathered rock over compacted overburden. Site and variety interacted with Cave-in-Rock as the top performer at the more fertile Hampshire Hill site and Shawnee produced the highest yields at Hobet 21 (7,853 kg ha-1 and 1,086 kg ha-1 averaged across years, respectively). Switchgrass yields increased from 2009 to 2010, but declined from 2010 to 2011. Switchgrass yields from farmlands in this region averaged about 15000 kg (ha-yr)-1 in the research literature, so switchgrass grown on reclaimed lands appears to be about 50% lower. A second study to determine optimal nitrogen and mulch rates for switchgrass establishment began in June 2011 on two newly-reclaimed surface mines. Both sites were seeded at a rate of 11.2 kg pure live seed (PLS) ha-1 of Cave-in-Rock on replicated treatments of 0, 33.6 and 67.0 kg N ha-1, and high and low mulch rates of mulch applied as hydromulch. Switchgrass cover, frequency and yield improved with the addition of any amount of N fertilizer compared to no N application. There was no significant difference in yield associated with high and low levels of N. We also observed that yields were not affected by application of additional mulch. The final study compared a one- and two-harvest system in the fourth year of production at the Hampshire Hill and Hobet 21 sites. There was no increase in yield production utilizing a two-harvest system (2922 kg (ha-yr)-1, averaged across site) compared to a one-harvest system (3029 kg (ha-yr)-1). The data also showed that re-growth collected from July to October in the two-harvest system added negligible yield and that yield collected in July was comparable in one- and two-harvest systems.

The contact heat transfer between the heating plate and granular materials in rotary heat exchanger under overloaded condition

NASA Astrophysics Data System (ADS)

Duan, Luanfang; Qi, Chonggang; Ling, Xiang; Peng, Hao

2018-03-01

In the present work, the contact heat transfer between the granular materials and heating plates inside plate rotary heat exchanger (PRHE) was investigated. The heat transfer coefficient is dominated by the contact heat transfer coefficient at hot wall surface of the heating plates and the heat penetration inside the solid bed. A plot scale PRHE with a diameter of Do = 273 mm and a length of L = 1000 mm has been established. Quartz sand with dp = 2 mm was employed as the experimental material. The operational parameters were in the range of ω = 1 - 8 rpm, and F = 15, 20, 25, 30%, and the effect of these parameters on the time-average contact heat transfer coefficient was analyzed. The time-average contact heat transfer coefficient increases with the increase of rotary speed, but decreases with the increase of the filling degree. The measured data of time-average heat transfer coefficients were compared with theoretical calculations from Schlünder's model, a good agreement between the measurements and the model could be achieved, especially at a lower rotary speed and filling degree level. The maximum deviation between the calculated data and the experimental data is approximate 10%.

Photometric Mapping of Two Kepler Eclipsing Binaries: KIC11560447 and KIC8868650

NASA Astrophysics Data System (ADS)

Senavci, Hakan Volkan; Özavci, I.; Isik, E.; Hussain, G. A. J.; O'Neal, D. O.; Yilmaz, M.; Selam, S. O.

2018-04-01

We present the surface maps of two eclipsing binary systems KIC11560447 and KIC8868650, using the Kepler light curves covering approximately 4 years. We use the code DoTS, which is based on maximum entropy method in order to reconstruct the surface maps. We also perform numerical tests of DoTS to check the ability of the code in terms of tracking phase migration of spot clusters. The resulting latitudinally averaged maps of KIC11560447 show that spots drift towards increasing orbital longitudes, while the overall behaviour of spots on KIC8868650 drifts towards decreasing latitudes.

UV sensitivity of planktonic net community production in ocean surface waters

NASA Astrophysics Data System (ADS)

Regaudie-de-Gioux, Aurore; Agustí, Susana; Duarte, Carlos M.

2014-05-01

The net plankton community metabolism of oceanic surface waters is particularly important as it more directly affects the partial pressure of CO2 in surface waters and thus the air-sea fluxes of CO2. Plankton communities in surface waters are exposed to high irradiance that includes significant ultraviolet blue (UVB, 280-315 nm) radiation. UVB radiation affects both photosynthetic and respiration rates, increase plankton mortality rates, and other metabolic and chemical processes. Here we test the sensitivity of net community production (NCP) to UVB of planktonic communities in surface waters across contrasting regions of the ocean. We observed here that UVB radiation affects net plankton community production at the ocean surface, imposing a shift in NCP by, on average, 50% relative to the values measured when excluding partly UVB. Our results show that under full solar radiation, the metabolic balance shows the prevalence of net heterotrophic community production. The demonstration of an important effect of UVB radiation on NCP in surface waters presented here is of particular relevance in relation to the increased UVB radiation derived from the erosion of the stratospheric ozone layer. Our results encourage design future research to further our understanding of UVB effects on the metabolic balance of plankton communities.

Calculation of a solid/liquid surface tension: A methodological study

NASA Astrophysics Data System (ADS)

Dreher, T.; Lemarchand, C.; Soulard, L.; Bourasseau, E.; Malfreyt, P.; Pineau, N.

2018-01-01

The surface tension of a model solid/liquid interface constituted of a graphene sheet surrounded by liquid methane has been computed using molecular dynamics in the Kirkwood-Buff formalism. We show that contrary to the fluid/fluid case, the solid/liquid case can lead to different structurations of the first fluid layer, leading to significantly different values of surface tension. Therefore we present a statistical approach that consists in running a series of molecular simulations of similar systems with different initial conditions, leading to a distribution of surface tensions from which an average value and uncertainty can be extracted. Our results suggest that these distributions converge as the system size increases. Besides we show that surface tension is not particularly sensitive to the choice of the potential energy cutoff and that long-range corrections can be neglected contrary to what we observed in the liquid/vapour interfaces. We have not observed the previously reported commensurability effect.

Natural convection with evaporation in a vertical cylindrical cavity under the effect of temperature-dependent surface tension

NASA Astrophysics Data System (ADS)

Kozhevnikov, Danil A.; Sheremet, Mikhail A.

2018-01-01

The effect of surface tension on laminar natural convection in a vertical cylindrical cavity filled with a weak evaporating liquid has been analyzed numerically. The cylindrical enclosure is insulated at the bottom, heated by a constant heat flux from the side, and cooled by a non-uniform evaporative heat flux from the top free surface having temperature-dependent surface tension. Governing equations with corresponding boundary conditions formulated in dimensionless stream function, vorticity, and temperature have been solved by finite difference method of the second-order accuracy. The influence of Rayleigh number, Marangoni number, and aspect ratio on the liquid flow and heat transfer has been studied. Obtained results have revealed that the heat transfer rate at free surface decreases with Marangoni number and increases with Rayleigh number, while the average temperature inside the cavity has an opposite behavior; namely, it growths with Marangoni number and reduces with Rayleigh number.

Diel Surface Temperature Range Scales with Lake Size

PubMed Central

Woolway, R. Iestyn; Jones, Ian D.; Maberly, Stephen C.; French, Jon R.; Livingstone, David M.; Monteith, Donald T.; Simpson, Gavin L.; Thackeray, Stephen J.; Andersen, Mikkel R.; Battarbee, Richard W.; DeGasperi, Curtis L.; Evans, Christopher D.; de Eyto, Elvira; Feuchtmayr, Heidrun; Hamilton, David P.; Kernan, Martin; Krokowski, Jan; Rimmer, Alon; Rose, Kevin C.; Rusak, James A.; Ryves, David B.; Scott, Daniel R.; Shilland, Ewan M.; Smyth, Robyn L.; Staehr, Peter A.; Thomas, Rhian; Waldron, Susan; Weyhenmeyer, Gesa A.

2016-01-01

Ecological and biogeochemical processes in lakes are strongly dependent upon water temperature. Long-term surface warming of many lakes is unequivocal, but little is known about the comparative magnitude of temperature variation at diel timescales, due to a lack of appropriately resolved data. Here we quantify the pattern and magnitude of diel temperature variability of surface waters using high-frequency data from 100 lakes. We show that the near-surface diel temperature range can be substantial in summer relative to long-term change and, for lakes smaller than 3 km2, increases sharply and predictably with decreasing lake area. Most small lakes included in this study experience average summer diel ranges in their near-surface temperatures of between 4 and 7°C. Large diel temperature fluctuations in the majority of lakes undoubtedly influence their structure, function and role in biogeochemical cycles, but the full implications remain largely unexplored. PMID:27023200

Climate warming due to increasing atmospheric CO2 - Simulations with a multilayer coupled atmosphere-ocean seasonal energy balance model

NASA Technical Reports Server (NTRS)

Li, Peng; Chou, Ming-Dah; Arking, Albert

1987-01-01

The transient response of the climate to increasing CO2 is studied using a modified version of the multilayer energy balance model of Peng et al. (1982). The main characteristics of the model are described. Latitudinal and seasonal distributions of planetary albedo, latitude-time distributions of zonal mean temperatures, and latitudinal distributions of evaporation, water vapor transport, and snow cover generated from the model and derived from actual observations are analyzed and compared. It is observed that in response to an atmospheric doubling of CO2, the model reaches within 1/e of the equilibrium response of global mean surface temperature in 9-35 years for the probable range of vertical heat diffusivity in the ocean. For CO2 increases projected by the National Research Council (1983), the model's transient response in annually and globally averaged surface temperatures is 60-75 percent of the corresponding equilibrium response, and the disequilibrium increases with increasing heat diffusivity of the ocean.

Origins of the Kuroshio and Mindanao Currents

DTIC Science & Technology

2016-03-30

REPORT DOCUMENTATION PAGE Form Approved OMB No. 0704-0188 The public reporting burden for this collection of information is estimated to average 1...Objectively napped time- averaged sea surface hieght (right) and surface geostrophic current (left). The mapped fields are estimated by objectively mapping

40 CFR 192.12 - Standards.

Code of Federal Regulations, 2013 CFR

2013-07-01

... level by more than— (1) 5 pCi/g, averaged over the first 15 cm of soil below the surface, and (2) 15 pCi/g, averaged over 15 cm thick layers of soil more than 15 cm below the surface. (b) In any occupied...

40 CFR 192.12 - Standards.

Code of Federal Regulations, 2011 CFR

2011-07-01

... level by more than— (1) 5 pCi/g, averaged over the first 15 cm of soil below the surface, and (2) 15 pCi/g, averaged over 15 cm thick layers of soil more than 15 cm below the surface. (b) In any occupied...

40 CFR 192.12 - Standards.

Code of Federal Regulations, 2012 CFR

2012-07-01

... level by more than— (1) 5 pCi/g, averaged over the first 15 cm of soil below the surface, and (2) 15 pCi/g, averaged over 15 cm thick layers of soil more than 15 cm below the surface. (b) In any occupied...

40 CFR 192.12 - Standards.

Code of Federal Regulations, 2014 CFR

2014-07-01

... level by more than— (1) 5 pCi/g, averaged over the first 15 cm of soil below the surface, and (2) 15 pCi/g, averaged over 15 cm thick layers of soil more than 15 cm below the surface. (b) In any occupied...

40 CFR 192.12 - Standards.

Code of Federal Regulations, 2010 CFR

2010-07-01

... level by more than— (1) 5 pCi/g, averaged over the first 15 cm of soil below the surface, and (2) 15 pCi/g, averaged over 15 cm thick layers of soil more than 15 cm below the surface. (b) In any occupied...

Factors Controlling Summertime Surface Ozone In The Western U.S

NASA Astrophysics Data System (ADS)

Gao, Mei

In this dissertation we investigate different factors controlling summertime surface ozone (O3) in the western U.S., including the impacts from increased wildfire emissions, the modulation by North American summer monsoon as well as long-range transport of O3 and its precursors from outside of North America. We first analyze the surface ozone observations from the Clean Air Status and Trend Network (CASTNet) using a global chemical transport model (GEOS-Chem) to investigate the impact of biomass burning on surface O3 in the western U.S. (WUS) mountain ranges during the June--October fire season of 2007, one of the stronger fire years in the WUS in the past decade. GEOS-Chem O3 captures the observed seasonal, synoptic and daily variations. Model daily afternoon average surface O3 concentrations at the CASTNet sites are within 2 ppb of the observations, with correlation coefficients of 0.51--0.83 and Taylor scores of 0.64--0.92. Observed maximum daily 8-hour (MAD8) surface O3 concentrations are 37--8 ppb at the sites, while the corresponding model results are higher by 6 ppb on average. Model results show July--September maximum surface O3 enhancement of ~9 ppb on average because of biomass burning. Peaks in fire-contributed surface O3 correspond broadly with high levels of potassium (K), reaffirming a strong fire influence. We find a policy relevant background (PRB) O3 of 45.6 ppb on average during July--September. Fire-contributed O3 accounts for up to 30% of the PRB O3, highest in the intense fire region (Montana, Idaho, and Wyoming) with maxima in August and September. We also examine an unexpected summertime surface O3 minimum (~30--5 ppb) in July--August 2007 observed throughout the Southwestern U.S. (SWUS) by interpreting observations of O3 and rainfall from the Clean Air Status and Trends Network (CASTNet) with a global chemical transport model. The O3 minimum reflects competing chemical and dynamic factors as well as anthropogenic and natural influences. Its reoccurrence annually in 2000--11 corresponds to the seasonal rainfall maximum during the North American summer monsoon (NASM) (negative O3 and positive rainfall anomalies at the CASTNet sites, (r = -0.5 to -0.7, p < 0.05). Relative to June 15--July 15, 2007 (pre-onset of the NASM), increased cloudiness in July 15--August 15 (post-onset) weakens photochemistry, reduces O3 production from anthropogenic emissions, thereby depresses O3 throughout the lower troposphere and at the surface (-5 ppb at Chiricahua, AZ and -3 ppb on average across the SWUS). The resulting changes are largest at rainfall maxima, particularly in the core of the Great Plains low-level jet. Enhanced lightning NOx emissions post-onset augments O3 production in the middle troposphere followed by downward mixing in convective downdrafts, thereby increases O3 significantly throughout the tropospheric column and non-negligibly at the surface (+2 ppb at Chiricahua and +1 ppb averaged over the SWUS). The resulting DeltaO 3 changes is largest (+8 ppb) in the middle troposphere in the anti-cyclonic circulation associated with the reoccurring summertime high over the Southern U.S. Weaker photochemistry post-onset dominates the overall DeltaO 3 change near the surface, while enhanced lightning dominates in much of the free troposphere. Additionally, we find that transport leads to a net export of O3 throughout the tropospheric column and the influence from stratospheric intrusion is vanishingly small. These competing effects suppress O3 in the lower troposphere (DeltaO3 change up to -5 ppb) while enhance O3 at higher altitudes (DeltaO 3 change up to +7 ppb) across the SWUS during the monsoon. Better understanding of these effects is critical to estimate present and predict future background O3 in the U.S. Southwest as the NASM changes under a changing climate. Lastly we use the GEOS-Chem 3-D global tropospheric chemical transport model and its adjoint to quantify the source contributions to O3 pollution observed at Mt. Bachelor Observatory (MBO) during the summer of 2008. We found that MBO experienced distinct O3 pollution episodes from Siberia wildfire emissions. We also used the adjoint of GEOS-Chem to show the model O3 at MBO is largely sensitive to NOx emissions from biomass burning sources in Siberia and northern California, lightning sources over southwestern U.S. and Mexico, and anthropogenic sources in western U.S. and eastern Asia. For the CO emissions, the largest O 3 sensitivity is to the biomass burning sources in northern California and Siberia. The peak sensitivity to biomass burning CO emissions is comparable to the peak O3 sensitivity to anthropogenic NOx emissions. (Abstract shortened by UMI.).

Influence of growth temperature on bulk and surface defects in hybrid lead halide perovskite films

NASA Astrophysics Data System (ADS)

Peng, Weina; Anand, Benoy; Liu, Lihong; Sampat, Siddharth; Bearden, Brandon E.; Malko, Anton V.; Chabal, Yves J.

2016-01-01

The rapid development of perovskite solar cells has focused its attention on defects in perovskites, which are gradually realized to strongly control the device performance. A fundamental understanding is therefore needed for further improvement in this field. Recent efforts have mainly focused on minimizing the surface defects and grain boundaries in thin films. Using time-resolved photoluminescence spectroscopy, we show that bulk defects in perovskite samples prepared using vapor assisted solution process (VASP) play a key role in addition to surface and grain boundary defects. The defect state density of samples prepared at 150 °C (~1017 cm-3) increases by 5 fold at 175 °C even though the average grains size increases slightly, ruling out grain boundary defects as the main mechanism for the observed differences in PL properties upon annealing. Upon surface passivation using water molecules, the PL intensity and lifetime of samples prepared at 200 °C are only partially improved, remaining significantly lower than those prepared at 150 °C. Thus, the present study indicates that the majority of these defect states observed at elevated growth temperatures originates from bulk defects and underscores the importance to control the formation of bulk defects together with grain boundary and surface defects to further improve the optoelectronic properties of perovskites.The rapid development of perovskite solar cells has focused its attention on defects in perovskites, which are gradually realized to strongly control the device performance. A fundamental understanding is therefore needed for further improvement in this field. Recent efforts have mainly focused on minimizing the surface defects and grain boundaries in thin films. Using time-resolved photoluminescence spectroscopy, we show that bulk defects in perovskite samples prepared using vapor assisted solution process (VASP) play a key role in addition to surface and grain boundary defects. The defect state density of samples prepared at 150 °C (~1017 cm-3) increases by 5 fold at 175 °C even though the average grains size increases slightly, ruling out grain boundary defects as the main mechanism for the observed differences in PL properties upon annealing. Upon surface passivation using water molecules, the PL intensity and lifetime of samples prepared at 200 °C are only partially improved, remaining significantly lower than those prepared at 150 °C. Thus, the present study indicates that the majority of these defect states observed at elevated growth temperatures originates from bulk defects and underscores the importance to control the formation of bulk defects together with grain boundary and surface defects to further improve the optoelectronic properties of perovskites. Electronic supplementary information (ESI) available. See DOI: 10.1039/c5nr06222e

The Impact of Sea Ice Concentration Accuracies on Climate Model Simulations with the GISS GCM

NASA Technical Reports Server (NTRS)

Parkinson, Claire L.; Rind, David; Healy, Richard J.; Martinson, Douglas G.; Zukor, Dorothy J. (Technical Monitor)

2000-01-01

The Goddard Institute for Space Studies global climate model (GISS GCM) is used to examine the sensitivity of the simulated climate to sea ice concentration specifications in the type of simulation done in the Atmospheric Modeling Intercomparison Project (AMIP), with specified oceanic boundary conditions. Results show that sea ice concentration uncertainties of +/- 7% can affect simulated regional temperatures by more than 6 C, and biases in sea ice concentrations of +7% and -7% alter simulated annually averaged global surface air temperatures by -0.10 C and +0.17 C, respectively, over those in the control simulation. The resulting 0.27 C difference in simulated annual global surface air temperatures is reduced by a third, to 0.18 C, when considering instead biases of +4% and -4%. More broadly, least-squares fits through the temperature results of 17 simulations with ice concentration input changes ranging from increases of 50% versus the control simulation to decreases of 50% yield a yearly average global impact of 0.0107 C warming for every 1% ice concentration decrease, i.e., 1.07 C warming for the full +50% to -50% range. Regionally and on a monthly average basis, the differences can be far greater, especially in the polar regions, where wintertime contrasts between the +50% and -50% cases can exceed 30 C. However, few statistically significant effects are found outside the polar latitudes, and temperature effects over the non-polar oceans tend to be under 1 C, due in part to the specification of an unvarying annual cycle of sea surface temperatures. The +/- 7% and 14% results provide bounds on the impact (on GISS GCM simulations making use of satellite data) of satellite-derived ice concentration inaccuracies, +/- 7% being the current estimated average accuracy of satellite retrievals and +/- 4% being the anticipated improved average accuracy for upcoming satellite instruments. Results show that the impact on simulated temperatures of imposed ice concentration changes is least in summer, encouragingly the same season in which the satellite accuracies are thought to be worst. Hence the impact of satellite inaccuracies is probably less than the use of an annually averaged satellite inaccuracy would suggest.

Fenton-treated functionalized diamond nanoparticles as gene delivery system.

PubMed

Martín, Roberto; Alvaro, Mercedes; Herance, José Raúl; García, Hermenegildo

2010-01-26

When raw diamond nanoparticles (Dnp, 7 nm average particle size) obtained from detonation are submitted to harsh Fenton-treatment, the resulting material becomes free of amorphous soot matter and the process maintains the crystallinity, reduces the particle size (4 nm average particle size), increases the surface OH population, and increases water solubility. All these changes are beneficial for subsequent Dnp covalent functionalization and for the ability of Dnp to cross cell membranes. Fenton-treated Dnps have been functionalized with thionine and the resulting sample has been observed in HeLa cell nuclei. A triethylammonium-functionalized Dnp pairs electrostatically with a plasmid having the green fluorescent protein gene and acts as gene delivery system permitting the plasmid to cross HeLa cell membrane, something that does not occur for the plasmid alone without assistance of polycationic Dnp.

Average chemical composition of the lunar surface

NASA Technical Reports Server (NTRS)

Turkevich, A. L.

1973-01-01

The available data on the chemical composition of the lunar surface at eleven sites (3 Surveyor, 5 Apollo and 3 Luna) are used to estimate the amounts of principal chemical elements (those present in more than about 0.5% by atom) in average lunar surface material. The terrae of the moon differ from the maria in having much less iron and titanium and appreciably more aluminum and calcium.

Preliminary evaluation of magnitude and frequency of floods in selected small drainage basins in Ohio

USGS Publications Warehouse

Kolva, J.R.

1985-01-01

A previous study of flood magitudes and frequencies in Ohio concluded that existing regionalized flood equations may not be adequate for estimating peak flows in small basins that are heavily forested, surface mined, or located in northwestern Ohio. In order to provide a large data base for improving estimation of flood peaks in these basins, 30 crest-stage gages were installed in 1977, in cooperation with the Ohio Department of Transportation, to provide a 10-year record of flood data The study area consists of two distinct parts: Northwestern Ohio, which contains 8 sites, and southern and eastern Ohio, which contains 22 sites in small forested or surface-mined drainage basins. Basin characteristics were determined for all 30 sites for 1978 conditions. Annual peaks were recorded or estimated for all 30 sites for water years 1978-82; an additional year of peak discharges was available at four sites. The 2-year (Q2) and 5-year (Q5) flood peaks were determined from these annual peaks.Q2 and Q5 values also were calculated using published regionalized regression equations for Ohio. The ratios of the observed to predicted 2-year (R2) and 5-year (R5) values were then calculated. This study found that observed flood peaks aree lower than estimated peaks by a significant amount in surface-mined basins. The average ratios of observed to predicted R2 values are 0.51 for basins with more than 40 percent surface-minded land, and 0.68 for sites with any surface-mined land. The average R5 value is 0.55 for sites with more than 40 percent surface-minded land, and 0.61 for sites with any surface-mined land. Estimated flood peaks from forested basins agree with the observed values fairly well. R2 values average 0.87 for sites with 20 percent or more forested land, but no surface-mined land, and R5 values average 0.96. If all sites with more than 20 percent forested land and some surface-mined land are considered, R2 the values average 0.86, and the R5 values average 0.82.

The Special Sensor Microwave Imager Wind Dataset: A Source of Quantitative Information for the Ocean-to-Land Advection

NASA Technical Reports Server (NTRS)

Otterman, J.; Ardizzone, J.; Atlas, R.; Demaree, G.; Huth, R.; Jaagus, J.; Koslowsky, D.; Przybylak, R.; Wos, A.; Atlas, Robert (Technical Monitor)

1999-01-01

It is well recognized that advection from the North Atlantic has a profound effect on the climatic conditions in central Europe. A new dataset of the ocean-surface winds, derived from the Special Sensor Microwave Imager, SSM/1, is now available. This satellite instrument measures the wind speed, but not the direction. However, variational analysis developed at the Data Assimilation Office, NASA Goddard Space Flight Center, by combining the SSM/I measurements with wind vectors measured from ships, etc., produced global maps of the ocean surface winds suitable for climate analysis. From this SSM/I dataset, a specific index I(sub na) of the North Atlantic surface winds has been developed, which pertinently quantifies the low-level advection into central Europe. For a selected time-period, the index I(sub na) reports the average of the amplitude of the wind, averaging only the speed when the direction is from the southwest (when the wind is from another direction, the contribution counts to the average as zero speed). Strong correlations were found between February I(sub na) and the surface air temperatures in Europe 50-60 deg N. In the present study, we present the correlations between I(sub na) and temperature I(sub s), and also the sensitivity of T(sub s), to an increase in I(sub na), in various seasons and various regions. We specifically analyze the flow of maritime-air from the North Atlantic that produced two extraordinary warm periods: February 1990, and early-winter 2000/2001. The very cold December 2001 was clearly due to a northerly flow. Our conclusion is that the SSM/I dataset is very useful for providing insight to the forcing of climatic fluctuations in Europe.

Understanding gas-surface interactions from direct force measurements using a specialized torsion balance

NASA Technical Reports Server (NTRS)

Cook, S. R.; Hoffbauer, M. A.

1996-01-01

The first comprehensive measurements of the magnitude and direction of the forces exerted on surfaces by molecular beams are discussed and used to obtain information about the microscopic properties of the gas-surface interactions. This unique approach is not based on microscopic measurements of the scattered molecules. The reduced force coefficients are introduced as a new set of parameters that completely describe the macroscopic average momentum transfer to a surface by an incident molecular beam. By using a specialized torsion balance and molecular beams of N2, CO, CO2, and H2, the reduced force coefficients are determined from direct measurements of the force components exerted on surface of a solar panel array material, Kapton, SiO2-coated Kapton, and Z-93 as a function of the angle of incidence ranging from 0 degrees to 85 degrees. The absolute flux densities of the molecular beams were measured using a different torsion balance with a beam-stop that nullified the force of the scattered molecules. Standard time-of-flight techniques were used to determine the flux-weighted average velocities of the various molecular beams ranging from 1600 m/s to 4600 m/s. The reduced force coefficients can be used to directly obtain macroscopic average properties of the scattered molecules, such as the flux-weighted average velocity and translational energy, that can then be used to determine microscopic details concerning gas-surface interactions without the complications associated with averaging microscopic measurements.

Clouds and the Earth's Radiant Energy System (CERES) algorithm theoretical basis document. volume 4; Determination of surface and atmosphere fluxes and temporally and spatially averaged products (subsystems 5-12); Determination of surface and atmosphere fluxes and temporally and spatially averaged products

NASA Technical Reports Server (NTRS)

Wielicki, Bruce A. (Principal Investigator); Barkstrom, Bruce R. (Principal Investigator); Baum, Bryan A.; Charlock, Thomas P.; Green, Richard N.; Lee, Robert B., III; Minnis, Patrick; Smith, G. Louis; Coakley, J. A.; Randall, David R.

1995-01-01

The theoretical bases for the Release 1 algorithms that will be used to process satellite data for investigation of the Clouds and the Earth's Radiant Energy System (CERES) are described. The architecture for software implementation of the methodologies is outlined. Volume 4 details the advanced CERES techniques for computing surface and atmospheric radiative fluxes (using the coincident CERES cloud property and top-of-the-atmosphere (TOA) flux products) and for averaging the cloud properties and TOA, atmospheric, and surface radiative fluxes over various temporal and spatial scales. CERES attempts to match the observed TOA fluxes with radiative transfer calculations that use as input the CERES cloud products and NOAA National Meteorological Center analyses of temperature and humidity. Slight adjustments in the cloud products are made to obtain agreement of the calculated and observed TOA fluxes. The computed products include shortwave and longwave fluxes from the surface to the TOA. The CERES instantaneous products are averaged on a 1.25-deg latitude-longitude grid, then interpolated to produce global, synoptic maps to TOA fluxes and cloud properties by using 3-hourly, normalized radiances from geostationary meteorological satellites. Surface and atmospheric fluxes are computed by using these interpolated quantities. Clear-sky and total fluxes and cloud properties are then averaged over various scales.

Effects of Surface Roughness on Conical Squeeze Film Bearings with Micropolar fluid

NASA Astrophysics Data System (ADS)

Rajani, C. B.; Hanumagowda, B. N.; Shigehalli, Vijayalaxmi S.

2018-04-01

In the current paper, a hypothetical analysis of the impact of surface roughness on squeeze film lubrication of rough conical bearing using Micropolar fluid is examined using Eringen’sMicropolar fluid model. The generalized averaged Reynolds type equation for roughness has been determined analytically using the Christensen’s stochastic theory of roughness effects and the closed form expressions are obtained for the fluid film pressure, load carrying capacity and squeezing time. Further, the impacts of surface roughness using micropolar fluids on the squeeze film lubrication of rough conical bearings has been discussed and according to the outcomes arrived, pressure, load carrying capacity and squeezing time increases for azimuthal roughness pattern and decreases for radial roughness patterns comparatively to the smooth case.

Cohesive zone modelling of wafer bonding and fracture: effect of patterning and toughness variations

NASA Astrophysics Data System (ADS)

Kubair, D. V.; Spearing, S. M.

2006-03-01

Direct wafer bonding has increasingly become popular in the manufacture of microelectromechanical systems and semiconductor microelectronics components. The success of the bonding process is controlled by variables such as wafer flatness and surface preparation. In order to understand the effects of these variables, spontaneous planar crack propagation simulations were performed using the spectral scheme in conjunction with a cohesive zone model. The fracture-toughness on the bond interface is varied to simulate the effect of surface roughness (nanotopography) and patterning. Our analysis indicated that the energetics of crack propagation is sensitive to the local surface property variations. The patterned wafers are tougher (well bonded) than the unpatterned ones of the same average fracture-toughness.

Space-time interpolation of satellite winds in the tropics

NASA Astrophysics Data System (ADS)

Patoux, Jérôme; Levy, Gad

2013-09-01

A space-time interpolator for creating average geophysical fields from satellite measurements is presented and tested. It is designed for optimal spatiotemporal averaging of heterogeneous data. While it is illustrated with satellite surface wind measurements in the tropics, the methodology can be useful for interpolating, analyzing, and merging a wide variety of heterogeneous and satellite data in the atmosphere and ocean over the entire globe. The spatial and temporal ranges of the interpolator are determined by averaging satellite and in situ measurements over increasingly larger space and time windows and matching the corresponding variability at each scale. This matching provides a relationship between temporal and spatial ranges, but does not provide a unique pair of ranges as a solution to all averaging problems. The pair of ranges most appropriate for a given application can be determined by performing a spectral analysis of the interpolated fields and choosing the smallest values that remove any or most of the aliasing due to the uneven sampling by the satellite. The methodology is illustrated with the computation of average divergence fields over the equatorial Pacific Ocean from SeaWinds-on-QuikSCAT surface wind measurements, for which 72 h and 510 km are suggested as optimal interpolation windows. It is found that the wind variability is reduced over the cold tongue and enhanced over the Pacific warm pool, consistent with the notion that the unstably stratified boundary layer has generally more variable winds and more gustiness than the stably stratified boundary layer. It is suggested that the spectral analysis optimization can be used for any process where time-space correspondence can be assumed.

The impact of an extreme case of irrigation on the southeastern United States climate

NASA Astrophysics Data System (ADS)

Selman, Christopher; Misra, Vasubandhu

2017-02-01

The impacts of irrigation on southeast United States diurnal climate are investigated using simulations from a regional climate model. An extreme case is assumed, wherein irrigation is set to 100 % of field capacity over the growing season of May through October. Irrigation is applied to the root zone layers of 10-40 and 40-100 cm soil layers only. It is found that in this regime there is a pronounced decrease in monthly averaged temperatures in irrigated regions across all months. In non-irrigated areas a slight warming is simulated. Diurnal maximum temperatures in irrigated areas warm, while diurnal minimum temperatures cool. The daytime warming is attributed to an increase in shortwave flux at the surface owing to diminished low cloud cover. Nighttime and daily mean cooling result as a consequence repartitioning of energy into latent heat flux over sensible heat flux, and of a higher net downward ground heat flux. Excess heat is transported into the deep soil layer, preventing a rapidly intensifying positive feedback loop. Both diurnal and monthly average precipitations are reduced over irrigated areas at a magnitude and spatial pattern similar to one another. Due to the excess moisture availability, evaporation is seen to increase, but this is nearly balanced by a corresponding reduction in sensible heat flux. Concomitant with additional moisture availability is an increase in both transient and stationary moisture flux convergences. However, despite the increase, there is a large-scale stabilization of the atmosphere stemming from a cooled surface.

HOW UNIVERSAL IS THE {Sigma}{sub SFR}-{Sigma}{sub H{sub 2}} RELATION?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Feldmann, R.; Gnedin, N. Y.; Kravtsov, A. V., E-mail: feldmann@fnal.gov

It is a well-established empirical fact that the surface density of the star formation rate, {Sigma}{sub SFR}, strongly correlates with the surface density of molecular hydrogen, {Sigma}{sub H{sub 2}}, at least when averaged over large ({approx}kpc) scales. Much less is known, however, about whether (and how) the {Sigma}{sub SFR}-{Sigma}{sub H{sub 2}} relation depends on environmental parameters, such as the metallicity or the UV radiation field in the interstellar medium (ISM). Furthermore, observations indicate that the scatter in the {Sigma}{sub SFR}-{Sigma}{sub H{sub 2}} relation increases rapidly with decreasing averaging scale. How the scale-dependent scatter is generated and how one recovers amore » tight {approx} kpc scale {Sigma}{sub SFR}-{Sigma}{sub 2} relation in the first place is still largely debated. Here, these questions are explored with hydrodynamical simulations that follow the formation and destruction of H{sub 2}, include radiative transfer of UV radiation, and resolve the ISM on {approx}60 pc scales. We find that within the considered range of H{sub 2} surface densities (10-100 M{sub sun} pc{sup -2}), the {Sigma}{sub SFR}-{Sigma}{sub H{sub 2}} relation is steeper in environments of low-metallicity and/or high-radiation fields (compared to the Galaxy), that the star formation rate (SFR) at a given H{sub 2} surface density is larger, and the scatter is increased. Deviations from a 'universal' {Sigma}{sub SFR}-{Sigma}{sub H{sub 2}} relation should be particularly relevant for high-redshift galaxies or for low-metallicity dwarfs at z {approx} 0. We also find that the use of time-averaged SFRs produces a large, scale-dependent scatter in the {Sigma}{sub SFR}-{Sigma}{sub H{sub 2}} relation. Given the plethora of observational data expected from upcoming surveys such as ALMA, the scale-scatter relation may indeed become a valuable tool for determining the physical mechanisms connecting star formation and H{sub 2} formation.« less

Evaluation of entrance surface air kerma in pediatric chest radiography

NASA Astrophysics Data System (ADS)

Porto, L.; Lunelli, N.; Paschuk, S.; Oliveira, A.; Ferreira, J. L.; Schelin, H.; Miguel, C.; Denyak, V.; Kmiecik, C.; Tilly, J.; Khoury, H.

2014-11-01

The objective of this study was to evaluate the entrance surface air kerma in pediatric chest radiography. An evaluation of 301 radiographical examinations in anterior-posterior (AP) and posterior-anterior (PA) (166 examinations) and lateral (LAT) (135 examinations) projections was performed. The analyses were performed on patients grouped by age; the groups included ages 0-1 y, 1-5 y, 5-10 y, and 10-15 y. The entrance surface air kerma was determined with DoseCal software (Radiological Protection Center of Saint George's Hospital, London) and thermoluminescent dosimeters. Two different exposure techniques were compared. The doses received by patients who had undergone LAT examinations were 40% higher, on average, those in AP/PA examinations because of the difference in tube voltage. A large high-dose “tail” was observed for children up to 5 y old. An increase in tube potential and corresponding decrease in current lead to a significant dose reduction. The difference between the average dose values for different age ranges was not practically observed, implying that the exposure techniques are still not optimal. Exposure doses received using the higher tube voltage and lower current-time product correspond to the international diagnostic reference levels.

Wind-driven angular momentum loss in binary systems. I - Ballistic case

NASA Technical Reports Server (NTRS)

Brookshaw, Leigh; Tavani, Marco

1993-01-01

We study numerically the average loss of specific angular momentum from binary systems due to mass outflow from one of the two stars for a variety of initial injection geometries and wind velocities. We present results of ballistic calculations in three dimensions for initial mass ratios q of the mass-losing star to primary star in the range q between 10 exp -5 and 10. We consider injection surfaces close to the Roche lobe equipotential surface of the mass-losing star, and also cases with the mass-losing star underfilling its Roche lobe. We obtain that the orbital period is expected to have a negative time derivative for wind-driven secular evolution of binaries with q greater than about 3 and with the mass-losing star near filling its Roche lobe. We also study the effect of the presence of an absorbing surface approximating an accretion disk on the average final value of the specific angular momentum loss. We find that the effect of an accretion disk is to increase the wind-driven angular momentum loss. Our results are relevant for evolutionary models of high-mass binaries and low-mass X-ray binaries.

Surface Modification and Damage of MeV-Energy Heavy Ion Irradiation on Gold Nanowires.

PubMed

Cheng, Yaxiong; Yao, Huijun; Duan, Jinglai; Xu, Lijun; Zhai, Pengfei; Lyu, Shuangbao; Chen, Yonghui; Maaz, Khan; Mo, Dan; Sun, Youmei; Liu, Jie

2017-05-15

Gold nanowires with diameters ranging from 20 to 90 nm were fabricated by the electrochemical deposition technique in etched ion track polycarbonate templates and were then irradiated by Xe and Kr ions with the energy in MeV range. The surface modification of nanowires was studied by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) characterizations. Different craters with and without protrusion on the gold nanowires were analyzed, and the two corresponding formation mechanisms, i.e., plastic flow and micro-explosion, were investigated. In addition, the sputtered gold nanoparticles caused by ion irradiation were studied and it was confirmed that the surface damage produced in gold nanowires was increased as the diameter of the nanowires decreased. It was also found that heavy ion irradiation can also create stacking fault tetrahedrons (SFTs) in gold nanowires and three different SFTs were confirmed in irradiated nanowires. A statistical analysis of the size distribution of SFTs in gold nanowires proved that the average size distribution of SFT was positively related to the nuclear stopping power of incident ions, i.e., the higher nuclear stopping power of incident ions could generate SFT with a larger average size in gold nanowires.

Surface Modification and Damage of MeV-Energy Heavy Ion Irradiation on Gold Nanowires

PubMed Central

Cheng, Yaxiong; Yao, Huijun; Duan, Jinglai; Xu, Lijun; Zhai, Pengfei; Lyu, Shuangbao; Chen, Yonghui; Maaz, Khan; Mo, Dan; Sun, Youmei; Liu, Jie

2017-01-01

Gold nanowires with diameters ranging from 20 to 90 nm were fabricated by the electrochemical deposition technique in etched ion track polycarbonate templates and were then irradiated by Xe and Kr ions with the energy in MeV range. The surface modification of nanowires was studied by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) characterizations. Different craters with and without protrusion on the gold nanowires were analyzed, and the two corresponding formation mechanisms, i.e., plastic flow and micro-explosion, were investigated. In addition, the sputtered gold nanoparticles caused by ion irradiation were studied and it was confirmed that the surface damage produced in gold nanowires was increased as the diameter of the nanowires decreased. It was also found that heavy ion irradiation can also create stacking fault tetrahedrons (SFTs) in gold nanowires and three different SFTs were confirmed in irradiated nanowires. A statistical analysis of the size distribution of SFTs in gold nanowires proved that the average size distribution of SFT was positively related to the nuclear stopping power of incident ions, i.e., the higher nuclear stopping power of incident ions could generate SFT with a larger average size in gold nanowires. PMID:28505116

Age-related changes in human posture control: Sensory organization tests

NASA Technical Reports Server (NTRS)

Peterka, R. J.; Black, F. O.

1989-01-01

Postural control was measured in 214 human subjects ranging in age from 7 to 81 years. Sensory organization tests measured the magnitude of anterior-posterior body sway during six 21 s trials in which visual and somatosensory orientation cues were altered (by rotating the visual surround and support surface in proportion to the subject's sway) or vision eliminated (eyes closed) in various combinations. No age-related increase in postural sway was found for subjects standing on a fixed support surface with eyes open or closed. However, age-related increases in sway were found for conditions involving altered visual or somatosensory cues. Subjects older than about 55 years showed the largest sway increases. Subjects younger than about 15 years were also sensitive to alteration of sensory cues. On average, the older subjects were more affected by altered visual cues whereas younger subjects had more difficulty with altered somatosensory cues.

Influence of non-adiabatic wall conditions on the cross-flow around a circular cylinder

DOE Office of Scientific and Technical Information (OSTI.GOV)

Macha, J.M.; Shafa, K.S.

1984-02-01

The drag and heat transfer of a finite length circular cylinder in a cross-flow have been investigated in a wind tunnel at surface-to-freestream temperature ratios from 1.0 to 2.1 for freestream Reynolds numbers of 2.2 x 10/sup 5/ and 4.4 x 10/sup 5/. The measured surface pressures were integrated to determine the effect of cylinder temperature on the drag coefficient, and the average Nusselt number was calculated from the electrical power required to heat the cylinder. For the freestream Reynolds number of 4.4 x 10/sup 5/, the experimental data show that increasing the cylinder temperature caused a reverse-transition from supercriticalmore » to subcritical flow. As a result of the increased size of the low-velocity wake region, C /SUB D/ increased by 21 percent and Nu /SUB d/ decreased by 26 percent.« less

Seasonal and Vegetational Variation in Albedo Measured During CERES Ground-Validation Pilot Study

NASA Technical Reports Server (NTRS)

Schuster, G. L.; Whitlock, C. H.; Plant, J. V.; Wheeler, R. J.; Moats, C. D.; Larman, K. T.; Ayers, J. K.; Feldl, E. K.

1997-01-01

The Clouds and the Earth's Radiant Energy System (CERES) satellite is scheduled for launch in the Fall of 1997 aboard the Tropical Rainfall Measuring Mission (TRMM). A surface measurement pilot study has been initiated in a 37-km region near Richmond, VA, for comparison with the CERES surface flux retrievals. Two-minute averaged upwelling and downwelling surface fluxes over a mostly deciduous forest have been recorded daily for the past two years, and show a broadband, shortwave daily albedo increase during the summer months. Evidence is presented that indicates vegetational changes in the forest as the overriding mechanism for this change. Upwelling flux measured over the entire region by helicopter-mounted instrumentation has been processed for four solar seasons. Future plans include the installation of four more albedo surface sites over various types of vegetation throughout the region.

Trends in 1970-2010 southern California surface maximum temperatures: extremes and heat waves

NASA Astrophysics Data System (ADS)

Ghebreegziabher, Amanuel T.

Daily maximum temperatures from 1970-2010 were obtained from the National Climatic Data Center (NCDC) for 28 South Coast Air Basin (SoCAB) Cooperative Network (COOP) sites. Analyses were carried out on the entire data set, as well as on the 1970-1974 and 2006-2010 sub-periods, including construction of spatial distributions and time-series trends of both summer-average and annual-maximum values and of the frequency of two and four consecutive "daytime" heat wave events. Spatial patterns of average and extreme values showed three areas consistent with climatological SoCAB flow patterns: cold coastal, warm inland low-elevation, and cool further-inland mountain top. Difference (2006-2010 minus 1970-1974) distributions of both average and extreme-value trends were consistent with the shorter period (1970-2005) study of previous study, as they showed the expected inland regional warming and a "reverse-reaction" cooling in low elevation coastal and inland areas open to increasing sea breeze flows. Annual-extreme trends generally showed cooling at sites below 600 m and warming at higher elevations. As the warming trends of the extremes were larger than those of the averages, regional warming thus impacts extremes more than averages. Spatial distributions of hot-day frequencies showed expected maximum at inland low-elevation sites. Regional warming again thus induced increases at both elevated-coastal areas, but low-elevation areas showed reverse-reaction decreases.

Biochar characteristics produced from food-processing products and their sorptive capacity for mercury and phenanthrene

NASA Astrophysics Data System (ADS)

Fotopoulou, Kalliopi N.; Karapanagioti, Hrissi K.; Manariotis, Ioannis D.

2015-04-01

Various organic-rich wastes including wood chips, animal manure, and crop residues have been used for biochar production. Biochar is used as an additive to soils to sequester carbon and improve soil fertility but its use as a sorbent for environmental remediation processes is gaining increased attention. Surface properties such as point of zero charge, surface area and pore volume, surface topography, surface functional groups and acid-base behavior are important factors, which affect sorption efficiency. Understanding the surface alteration of biochars increases our understanding of the pollutant-sorbent interaction. The scope of the present work was to evaluate the effect of key characteristics of biochars on their sorptive properties. Raw materials for biochar production were evaluated including byproducts from brewering, coffee, wine, and olive oil industry. The charring process was performed at different temperatures under limited-oxygen conditions using specialized containers. The surface area, the pore volume, and the average pore size of the biochars were determined. Open surface area and micropore volume were determined using t-plot method and Harkins & Jura equation. Raw food-processing waste demonstrates low surface area that increases by 1 order of magnitude by thermal treatment up to 750oC. At temperatures from 750 up to 900oC, pyrolysis results to biochars with surface areas 210-700 m2/g. For the same temperature range, a high percentage (46 to73%) of the pore volume of the biochars is due to micropores. Positive results were obtained when high surface area biochars were tested for their ability to remove organic (i.e. phenanthrene) and inorganic (i.e. mercury) compounds from aqueous solutions. All these properties point to new materials that can effectively be used for environmental remediation.

Numerical simulation of groundwater flow in the Columbia Plateau Regional Aquifer System, Idaho, Oregon, and Washington

USGS Publications Warehouse

Ely, D. Matthew; Burns, Erick R.; Morgan, David S.; Vaccaro, John J.

2014-01-01

Groundwater pumping has increased substantially over the past 40–50 years; this increase resulted in declining water levels at depth and decreased base flows over much of the study area. The effects of pumping are mitigated somewhat by the increase of surface-water irrigation, especially in the shallow Overburden unit, and commingling wells in some areas. During dry to average years, groundwater pumping causes a net loss of groundwater in storage and current condition (2000–2007) groundwater pumping exceeds recharge in all but the wettest of years.

Analysis of radiation-induced small Cu particle cluster formation in aqueous CuCl2

USGS Publications Warehouse

Jayanetti, Sumedha; Mayanovic, Robert A.; Anderson, Alan J.; Bassett, William A.; Chou, I.-Ming

2001-01-01

Radition-induced small Cu particle cluster formation in aqueous CuCl2 was analyzed. It was noticed that nearest neighbor distance increased with the increase in the time of irradiation. This showed that the clusters approached the lattice dimension of bulk copper. As the average cluster size approached its bulk dimensions, an increase in the nearest neighbor coordination number was found with the decrease in the surface to volume ratio. Radiolysis of water by incident x-ray beam led to the reduction of copper ions in the solution to themetallic state.

Surface-pattern geometry, topography, and chemical modifications during KrF excimer laser micro-drilling of p-type Si (111) wafers in ambient environment of HCl fumes in air

NASA Astrophysics Data System (ADS)

Zakria Butt, Muhammad; Saher, Sobia; Waqas Khaliq, Muhammad; Siraj, Khurram

2016-11-01

Eight mirror-like polished p-type Si (111) wafers were irradiated with 100, 200, 300, 400, 800, 1200, 1600, and 2000 KrF excimer laser pulses in ambient environment of HCl fumes in air. The laser parameters were: wavelength = 248 nm, pulse width = 20 ns, pulse energy = 20 mJ, and repetition rate = 20 Hz. For each set of laser pulses, characterization of the rectangular etched patterns formed on target surface was done by optical/scanning electron microscopy, XRD, and EDX techniques. The average etched depth increased with the increase in number of laser pulses from 100 to 2000 in accord with Sigmoidal (Boltzmann) function, whereas the average etch rate followed an exponential decay with the increase in number of laser pulses. However, the etched area, maximum etched depth, and maximum etch rate were found to increase linearly with the number of laser pulses, but the rate of increase was faster for 100-400 laser pulses (region I) than that for 800-2000 laser pulses (region II). The elemental composition for each etched-pattern determined by EDX shows that both O and Cl contents increase progressively with the increase in the number of laser shots in region I. However, in region II both O and Cl contents attain saturation values of about 39.33 wt.% and 0.14 wt.%, respectively. Perforation of Si wafers was achieved on irradiation with 1200-2000 laser pulses. XRD analysis confirmed the formation of SiO2, SiCl2 and SiCl4 phases in Si (111) wafers due to chemical reaction of silicon with both HCl fumes and oxygen in air.

The effects of atmospheric processes on tehran smog forming.

PubMed

Mohammadi, H; Cohen, D; Babazadeh, M; Rokni, L

2012-01-01

Air pollution is one of the most important problems in urban areas that always threaten citizen's health. Photochemical smog is one of the main factors of air pollution in large cities like Tehran. Usually smog is not only a part of nature, but is being analyzed as an independent matter, which highly affects on the nature. It has been used as relationship between atmospheric elements such as temperature, pressure, relative humidity, wind speed with inversion in the time of smog forming and weather map in 500 Hpa level during 9 years descriptive static by using correlation coefficient in this analyze. Results show that there is a meaningful correlation between atmospheric elements and smog forming. This relation is seen between monthly average of these elements and monthly average of smog forming. However, when temperature decreases, corresponding pressure will increase and result of this will be smog forming. Usually smog increases in cold months of year due to enter cold high pressure air masses in Iran during December and January that is simultaneous with decreasing temperature and air pressure increases and inversion height distance decreases from the earth surface which cause to integrate air pollution under its surface, will cause to form smog in Tehran. It shows a meaningful and strong relation, based on resultant relations by correlation coefficient from inversion height and smog forming, so that obtained figure is more than 60% .

Leading edge film cooling effects on turbine blade heat transfer

NASA Technical Reports Server (NTRS)

Garg, Vijay K.; Gaugler, Raymond E.

1995-01-01

An existing three dimensional Navier-Stokes code, modified to include film cooling considerations, has been used to study the effect of spanwise pitch of shower-head holes and coolant to mainstream mass flow ratio on the adiabatic effectiveness and heat transfer coefficient on a film-cooled turbine vane. The mainstream is akin to that under real engine conditions with stagnation temperature = 1900 K and stagnation pressure = 3 MPa. It is found that with the coolant to mainstream mass flow ratio fixed, reducing P, the spanwise pitch for shower-head holes, from 7.5 d to 3.0 d, where d is the hole diameter, increases the average effectiveness considerably over the blade surface. However, when P/d= 7.5, increasing the coolant mass flow increases the effectiveness on the pressure surface but reduces it on the suction surface due to coolant jet lift-off. For P/d = 4.5 or 3.0, such an anomaly does not occur within the range of coolant to mainstream mass flow ratios analyzed. In all cases, adiabatic effectiveness and heat transfer coefficient are highly three-dimensional.

Lubricin Surface Modification Improves Tendon Gliding After Tendon Repair in a Canine Model in Vitro

PubMed Central

Taguchi, Manabu; Sun, Yu-Long; Zhao, Chunfeng; Zobitz, Mark E.; Cha, Chung-Ja; Jay, Gregory D.; An, Kai-Nan; Amadio, Peter C.

2011-01-01

This study investigated the effects of lubricin on the gliding of repaired flexor digitorum profundus (FDP) tendons in vitro. Canine FDP tendons were completely lacerated, repaired with a modified Pennington technique, and treated with one of the following solutions: saline, carbodiimide derivatized gelatin/hyaluronic acid (cd-HA-gelatin), carbodiimide derivatized gelatin to which lubricin was added in a second step (cd-gelatin + lubricin), or carbodiimide derivatized gelatin/HA + lubricin (cd-HA-gelatin + lubricin). After treatment, gliding resistance was measured up to 1,000 cycles of simulated flexion/extension motion. The increase in average and peak gliding resistance in cd-HA-gelatin, cd-gelatin + lubricin, and cd-HA-gelatin + lubricin tendons was less than the control tendons after 1,000 cycles (p < 0.05). The increase in average gliding resistance of cd-HA-gelatin + lubricin treated tendons was also less than that of the cd-HA-gelatin treated tendons (p < 0.05). The surfaces of the repaired tendons and associated pulleys were assessed qualitatively with scanning electron microscopy and appeared smooth after 1,000 cycles of tendon motion for the cd-HA-gelatin, cd-gelatin + lubricin, and cd-HA-gelatin + lubricin treated tendons, while that of the saline control appeared roughened. These results suggest that tendon surface modification can improve tendon gliding ability, with a trend suggesting that lubricin fixed on the repaired tendon may provide additional improvement over that provided by HA and gelatin alone. PMID:18683890

Prevalence and distribution of dental restorative materials in US Air Force veterans.

PubMed

Albertini, T F; Kingman, A; Brown, L J

1997-01-01

Millions of restorative procedures are performed annually in the United States, yet very little is known about their distribution in the general population. With increasing concern about potential adverse health effects of some restorative materials, a better understanding of the extent of exposure to these materials in the population is important. The purpose of this study is to report the prevalence, patterns, and distribution of dental restorative materials in a population of male veterans. This collaborative study with the US Air Force examined 1,166 male veterans to assess exposure to dental amalgam and other restorative materials. An inventory of dental materials in the study population was obtained through oral examinations. Dental materials were classified into five categories: (1) amalgam; (2) resin; (3) porcelain, cement, or temporary, including ionomer (PCT); (4) cast gold alloys/direct filling gold; and (5) other metals (OM). The mean age of the study participants was 52.9 years. Over 94 percent of the study participants were dentate. The study participants averaged 45.8 restored/replaced surfaces. Restored/replaced surfaces increased with age while the number of teeth decreased with age. The most frequently used restorative material was amalgam, averaging 19.89 surfaces per subject, followed by PCT (9.38), resins (8.99), OM (5.52), and gold (4.91). The distributions of restorative materials varied by age, arch type, and location in the mouth. The study population experienced substantial exposure to dental materials.

Meltwater flux and runoff modeling in the abalation area of jakobshavn Isbrae, West Greenland

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mernild, Sebastian Haugard; Chylek, Petr; Liston, Glen

2009-01-01

The temporal variability in surface snow and glacier melt flux and runoff were investigated for the ablation area of lakobshavn Isbrae, West Greenland. High-resolution meteorological observations both on and outside the Greenland Ice Sheet (GrIS) were used as model input. Realistic descriptions of snow accumulation, snow and glacier-ice melt, and runoff are essential to understand trends in ice sheet surface properties and processes. SnowModel, a physically based, spatially distributed meteorological and snow-evolution modeling system was used to simulate the temporal variability of lakobshavn Isbrre accumulation and ablation processes for 2000/01-2006/07. Winter snow-depth observations and MODIS satellite-derived summer melt observations weremore » used for model validation of accumulation and ablation. Simulations agreed well with observed values. Simulated annual surface melt varied from as low as 3.83 x 10{sup 9} m{sup 3} (2001/02) to as high as 8.64 x 10{sup 9} m{sup 3} (2004/05). Modeled surface melt occurred at elevations reaching 1,870 m a.s.l. for 2004/05, while the equilibrium line altitude (ELA) fluctuated from 990 to 1,210 m a.s.l. during the simulation period. The SnowModel meltwater retention and refreezing routines considerably reduce the amount of meltwater available as ice sheet runoff; without these routines the lakobshavn surface runoff would be overestimated by an average of 80%. From September/October through May/June no runoff events were simulated. The modeled interannual runoff variability varied from 1.81 x 10{sup 9} m{sup 3} (2001/02) to 5.21 x 10{sup 9} m{sup 3} (2004/05), yielding a cumulative runoff at the Jakobshavn glacier terminus of {approx}2.25 m w.eq. to {approx}4.5 m w.eq., respectively. The average modeled lakobshavn runoff of {approx}3.4 km{sup 3} y{sup -1} was merged with previous estimates of Jakobshavn ice discharge to quantify the freshwater flux to Illulissat Icefiord. For both runoff and ice discharge the average trends are similar, indicating increasing (insignificant) influx of freshwater to the Illulissat Icefiord for the period 2000/01-2006/07. This study suggests that surface runoff forms a minor part of the overall Jakobshavn freshwater flux to the fiord: around 7% ({approx}3.4 km{sup 3} y{sup -1}) of the average annual freshwater flux of {approx}51.0 km{sup 3} y{sup -1} originates from the surface runoff.« less

A feasibility analysis of the employment of satellite imagery to monitor and inspect surface mining operations in western Kentucky, volume 1

NASA Technical Reports Server (NTRS)

Fish, B. R. (Principal Investigator)

1977-01-01

The author has identified the following significant results. Surface mining violation estimates were scaled by scores assigned by ten inspectors from western Kentucky to each violation. A sensitivity analysis was made by varying the violation costs; costs were varied by using three different average durations. These durations were: (1) best estimated duration; (2) longest possible duration as restricted by the one year permit renewal and bond release regulations, and (3) shortest possible duration when inspections were made. If a social cost cannot be reduced, then the value of the social cost is irrelevant. Indications from the increased inspection rate of 1975 were that the total amount of fines collected per year remains constant independent of the increased detection rate.

Effects of Zr on microstructure and mechanical properties of Al-Cu base ribbons spun by planar flow casting

NASA Astrophysics Data System (ADS)

Lee, S. M.; Hong, C. P.

1998-04-01

The effects of the Zr addition on the solidification behavior and mechanical properties of the AI-Cu alloy ribbon have been investigated. Zr addition reduced the average grain size of the ribbon at the wheel-side surface, and promoted the microstructural transition into cellular/dendritic structure. Another noteworthy effect of Zr was the homogenization of the microstructure. The addition of Zr up to 0.5 wt.% in the /U-4.3 wt.% Cu ribbon resulted in a considerable increase in hardness at both the wheel-side and the air-side surfaces. The yield strength increased with the addition of Zr due to the grain refincment and more homogeneous distribution of ZrAI, particles. despite no noticeable improvement of the ductility.

A comparison of cellulosic fuel yields and separated soil-surface CO2 fluxes in maize and prairie biofuel cropping systems

NASA Astrophysics Data System (ADS)

Nichols, Virginia A.

It has been suggested that strategic incorporation of perennial vegetation into agricultural landscapes could provide ecosystem services while maintaining agricultural productivity. To evaluate potential use of prairie as a Midwestern cellulosic feedstock, we investigated theoretical cellulosic fuel yields, as well as soil-surface carbon dioxide emissions of prairie-based biofuel systems as compared to maize-based systems on fertile soils in Boone County, IA, USA. Investigated systems were: a maize-soybean rotation grown for grain only, continuous maize grown for grain and stover both with and without a winter rye cover crop, and a 31-species reconstructed prairie grown with and without spring nitrogen fertilization for fall-harvested biomass. From 2009-2013, the highest producing system was N-fertilized prairie, averaging 10.4 Mg ha -1 yr-1 above-ground biomass with average harvest removals of 7.8 Mg ha-1 yr-1. The unfertilized prairie produced 7.4 Mg ha-1 yr-1, averaging harvests of 5.3 Mg ha-1 yr-1. Lowest cellulosic biomass harvests were realized from continuous maize systems, averaging 3.5 Mg ha -1 yr-1 when grown with, and 3.7 Mg ha-1 yr-1 when grown without a winter rye cover crop, respectively. Un-fertilized prairie biomass and maize stover had equivalent dietary conversion ratios at 330 g ethanol kg-1 dry biomass, but N-fertilized prairie was lower at 315. Over four years prairie systems averaged 1287 L cellulosic ethanol ha-1 yr-1 more than maize systems, with fertilization increasing prairie ethanol production by 865 L ha-1 yr-1. Harvested biomass accounted for >90% of ethanol yield variation. A major hurdle in carbon cycling studies is the separation of the soil-surface CO2 flux into its respective components. From 2012-2013 we used a shading method to separate soil-surface CO2 resulting from oxidation of soil organic matter and CO2 derived from live-root activity in three systems: unfertilized prairie, N-fertilized prairie, and continuous maize. Contrary to our hypothesis, total growing-season root CO2 flux was not proportional to end-of-season root biomass of cropping systems; unfertilized prairie contained nearly twice the root biomass of N-fertilized prairie, but the two systems' total root CO2 fluxes were not significantly different in either year. We found that the total growing-season flux of both root- and organic matter-derived CO 2 was higher in the prairie systems compared to the maize system. However, on a percentage basis, the prairies' soil-surface CO2 flux from May-September averaged 29% root-derived while from mid-June through September the maize averaged 22% root-derived. The percentage of the total CO2 flux that was root-derived in a given system varied from year to year, indicating there is no set relationship for a given cropping system.

Properties of Diamond and Diamond-Like Clusters in Nanometric Dimensions

NASA Technical Reports Server (NTRS)

Halicioglu, Timur; Langhoff, Stephen R. (Technical Monitor)

1996-01-01

Variations in materials properties of small clusters of nanometric dimensions were investigated. Investigations were carried out for diamond and diamond-like particles in spherical shapes. Calculations were performed for clusters containing over 1000 carbon atoms. Results indicate that as the cluster size diminishes, (i) the average cohesive energy becomes weaker, (ii) the excess surface energy increases, and (iii) the value for stiffness decreases.

Time series study of weather, water quality, and acute gastroenteritis at Water Safety Plan implementation sites in France and Spain

PubMed Central

Setty, Karen E.; Enault, Jerome; Loret, Jean-Francois; Serra, Claudia Puigdomenech; Martin-Alonso, Jordi; Bartram, Jamie

2018-01-01

Water Safety Plans (WSPs), recommended by the World Health Organization since 2004, can help drinking water suppliers to proactively identify potential risks and implement preventive barriers that improve safety. Few studies have investigated long-term impacts of WSPs, such as changes in drinking water quality or public health; however, some evidence from high-income countries associates WSP implementation with a reduction in diarrheal disease. To validate the previously observed linkages between WSPs and health outcomes, this time series study examined site-specific relationships between water-related exposures and acute gastroenteritis rates at three locations in France and Spain, including the role of WSP status. Relationships between control or exposure variables and health outcomes were tested using Poisson regression within generalized additive models. Controls included suspected temporal trends in disease reporting. Exposures included temperature, precipitation, raw water quality, and finished water quality (e.g., turbidity, free chlorine). In France, daily acute gastroenteritis cases were tracked using prescription reimbursements; Spanish data aggregated monthly acute gastroenteritis hospital visits. The models identified several significant relationships between indicators of exposure and acute gastroenteritis. Lag times of 6–9 days (including transit time) were most relevant for hydrological indicators (related to precipitation, runoff, and flow) at the two French sites, indicative of viral pathogens. Flush events (defined as surface runoff after a two-week antecedent dry period) linked to nonpoint source pollution were associated with a 10% increase in acute gastroenteritis rates at one location supplied by surface water. Acute gastroenteritis rates were positively associated with elevated turbidity average or maximum values in finished water at locations supplied by both surface and groundwater, by about 4% per 1-NTU increase in the two-week moving average of daily maxima or about 10% per 0.1 NTU increase in the prior month’s average value. In some cases, risk appeared to be mitigated by WSP-related treatment interventions. Our results suggest drinking water exposure is associated with some potentially preventable gastrointestinal illness risk in high-income regions. PMID:29678324

Degradation of orthodontic wires under simulated cariogenic and erosive conditions.

PubMed

Jaber, Laura Cavalcante Lima; Rodrigues, José Augusto; Amaral, Flávia Lucisano Botelho; França, Fabiana Mantovani Gomes; Basting, Roberta Tarkany; Turssi, Cecilia Pedroso

2014-01-01

This study examined the effect of cariogenic and erosive challenges (CCs and ECs, respectively) on the degradation of copper-nickel-titanium (CuNiTi) orthodontic wires. Sixty wire segments were divided into four treatment groups and exposed to CCs, ECs, artificial saliva, or dry storage (no-treatment control). CC and EC were simulated using a demineralizing solution (pH 4.3) and a citric acid solution (pH 2.3), respectively. Following treatment, the average surface roughness (Ra) of the wires was assessed, and friction between the wires and a passive self-ligating bracket was measured. CuNiTi wires subjected to ECs exhibited significantly higher Ra values than did those that were stored in artificial saliva. In contrast, surface roughness was not affected by CCs. Finally, friction between the treated wires and brackets was not affected by ECs or CCs. Our results indicate that CuNiTi orthodontic wires may suffer degradation within the oral cavity, as ECs increased the surface roughness of these wires. However, rougher surfaces did not increase friction between the wire and the passive self-ligating bracket.

Water on the surface of the Moon as seen by the Moon Mineralogy Mapper: Distribution, abundance, and origins

PubMed Central

Li, Shuai; Milliken, Ralph E.

2017-01-01

A new thermal correction model and experimentally validated relationships between absorption strength and water content have been used to construct the first global quantitative maps of lunar surface water derived from the Moon Mineralogy Mapper near-infrared reflectance data. We find that OH abundance increases as a function of latitude, approaching values of ~500 to 750 parts per million (ppm). Water content also increases with the degree of space weathering, consistent with the preferential retention of water originating from solar wind implantation during agglutinate formation. Anomalously high water contents indicative of interior magmatic sources are observed in several locations, but there is no global correlation between surface composition and water content. Surface water abundance can vary by ~200 ppm over a lunar day, and the upper meter of regolith may contain a total of ~1.2 × 1014 g of water averaged over the globe. Formation and migration of water toward cold traps may thus be a continuous process on the Moon and other airless bodies. PMID:28924612

Second-surface silvered glass solar mirrors of very high reflectance

NASA Astrophysics Data System (ADS)

Butel, Guillaume P.; Coughenour, Blake M.; Macleod, H. Angus; Kennedy, Cheryl E.; Olbert, Blain H.; Angel, J. Roger P.

2011-10-01

This paper reports methods developed to maximize the overall reflectance second-surface silvered glass. The reflectance at shorter wavelengths is increased with the aid of a dielectric enhancing layer between the silver and the glass, while at longer wavelengths it is enhanced by use of glass with negligible iron content. The calculated enhancement of reflectance, compared to unenhanced silver on standard low-iron float glass, corresponds to a 4.4% increase in reflectance averaged across the full solar spectrum, appropriate for CSP, and 2.7% for CPV systems using triple junction cells. An experimental reflector incorporating these improvements, of drawn crown glass and a silvered second-surface with dielectric boost, was measured at NREL to have 95.4% solar weighted reflectance. For comparison, non-enhanced, wetsilvered reflectors of the same 4 mm thickness show reflectance ranging from 91.6 - 94.6%, depending on iron content. A potential drawback of using iron-free drawn glass is reduced concentration in high concentration systems because of the inherent surface errors. This effect is largely mitigated for glass shaped by slumping into a concave mold, rather than by bending.

Geographic patterns of fishes and jellyfish in Puget Sound surface waters

USGS Publications Warehouse

Rice, Casimir A.; Duda, Jeffrey J.; Greene, Correigh M.; Karr, James R.

2012-01-01

We explored patterns of small pelagic fish assemblages and biomass of gelatinous zooplankton (jellyfish) in surface waters across four oceanographic subbasins of greater Puget Sound. Our study is the first to collect data documenting biomass of small pelagic fishes and jellyfish throughout Puget Sound; sampling was conducted opportunistically as part of a juvenile salmon survey of daytime monthly surface trawls at 52 sites during May–August 2003. Biomass composition differed spatially and temporally, but spatial differences were more distinct. Fish dominated in the two northern basins of Puget Sound, whereas jellyfish dominated in the two southern basins. Absolute and relative abundance of jellyfish, hatchery Chinook salmon Oncorhynchus tshawytscha, and chum salmon O. keta decreased with increasing latitude, whereas the absolute and relative abundance of most fish species and the average fish species richness increased with latitude. The abiotic factors with the strongest relationship to biomass composition were latitude, water clarity, and sampling date. Further study is needed to understand the spatial and temporal heterogeneity in the taxonomic composition we observed in Puget Sound surface waters, especially as they relate to natural and anthropogenic influences.

Incorporation of multiple cloud layers for ultraviolet radiation modeling studies

NASA Technical Reports Server (NTRS)

Charache, Darryl H.; Abreu, Vincent J.; Kuhn, William R.; Skinner, Wilbert R.

1994-01-01

Cloud data sets compiled from surface observations were used to develop an algorithm for incorporating multiple cloud layers into a multiple-scattering radiative transfer model. Aerosol extinction and ozone data sets were also incorporated to estimate the seasonally averaged ultraviolet (UV) flux reaching the surface of the Earth in the Detroit, Michigan, region for the years 1979-1991, corresponding to Total Ozone Mapping Spectrometer (TOMS) version 6 ozone observations. The calculated UV spectrum was convolved with an erythema action spectrum to estimate the effective biological exposure for erythema. Calculations show that decreasing the total column density of ozone by 1% leads to an increase in erythemal exposure by approximately 1.1-1.3%, in good agreement with previous studies. A comparison of the UV radiation budget at the surface between a single cloud layer method and a multiple cloud layer method presented here is discussed, along with limitations of each technique. With improved parameterization of cloud properties, and as knowledge of biological effects of UV exposure increase, inclusion of multiple cloud layers may be important in accurately determining the biologically effective UV budget at the surface of the Earth.

Changes in Land Surface Water Dynamics since the 1990s and Relation to Population Pressure

NASA Technical Reports Server (NTRS)

Prigent, C.; Papa, F.; Aires, F.; Jimenez, C.; Rossow, W. B.; Matthews, E.

2012-01-01

We developed a remote sensing approach based on multi-satellite observations, which provides an unprecedented estimate of monthly distribution and area of land-surface open water over the whole globe. Results for 1993 to 2007 exhibit a large seasonal and inter-annual variability of the inundation extent with an overall decline in global average maximum inundated area of 6% during the fifteen-year period, primarily in tropical and subtropical South America and South Asia. The largest declines of open water are found where large increases in population have occurred over the last two decades, suggesting a global scale effect of human activities on continental surface freshwater: denser population can impact local hydrology by reducing freshwater extent, by draining marshes and wetlands, and by increasing water withdrawals. Citation: Prigent, C., F. Papa, F. Aires, C. Jimenez, W. B. Rossow, and E. Matthews (2012), Changes in land surface water dynamics since the 1990s and relation to population pressure, in section 4, insisting on the potential applications of the wetland dataset.

Measurements of Heat-Transfer and Friction Coefficients for Helium Flowing in a Tube at Surface Temperatures up to 5900 Deg R

NASA Technical Reports Server (NTRS)

Taylor, Maynard F.; Kirchgessner, Thomas A.

1959-01-01

Measurements of average heat transfer and friction coefficients and local heat transfer coefficients were made with helium flowing through electrically heated smooth tubes with length-diameter ratios of 60 and 92 for the following range of conditions: Average surface temperature from 1457 to 4533 R, Reynolds numbe r from 3230 to 60,000, heat flux up to 583,200 Btu per hr per ft2 of heat transfer area, and exit Mach numbe r up to 1.0. The results indicate that, in the turbulent range of Reynolds number, good correlation of the local heat transfer coefficients is obtained when the physical properties and density of helium are evaluated at the surface temperature. The average heat transfer coefficients are best correlated on the basis that the coefficient varies with [1 + (L/D))(sup -0,7)] and that the physical properties and density are evaluated at the surface temperature. The average friction coefficients for the tests with no heat addition are in complete agreement with the Karman-Nikuradse line. The average friction coefficients for heat addition are in poor agreement with the accepted line.

Direct and semi-direct aerosol radiative effect on the Mediterranean climate variability using a coupled regional climate system model

NASA Astrophysics Data System (ADS)

Nabat, Pierre; Somot, Samuel; Mallet, Marc; Sevault, Florence; Chiacchio, Marc; Wild, Martin

2015-02-01

A fully coupled regional climate system model (CNRM-RCSM4) has been used over the Mediterranean region to investigate the direct and semi-direct effects of aerosols, but also their role in the radiation-atmosphere-ocean interactions through multi-annual ensemble simulations (2003-2009) with and without aerosols and ocean-atmosphere coupling. Aerosols have been taken into account in CNRM-RCSM4 through realistic interannual monthly AOD climatologies. An evaluation of the model has been achieved, against various observations for meteorological parameters, and has shown the ability of CNRM-RCSM4 to reproduce the main patterns of the Mediterranean climate despite some biases in sea surface temperature (SST), radiation and cloud cover. The results concerning the aerosol radiative effects show a negative surface forcing on average because of the absorption and scattering of the incident radiation. The SW surface direct effect is on average -20.9 Wm-2 over the Mediterranean Sea, -14.7 Wm-2 over Europe and -19.7 Wm-2 over northern Africa. The LW surface direct effect is weaker as only dust aerosols contribute (+4.8 Wm-2 over northern Africa). This direct effect is partly counterbalanced by a positive semi-direct radiative effect over the Mediterranean Sea (+5.7 Wm-2 on average) and Europe (+5.0 Wm-2) due to changes in cloud cover and atmospheric circulation. The total aerosol effect is consequently negative at the surface and responsible for a decrease in land (on average -0.4 °C over Europe, and -0.5 °C over northern Africa) and sea surface temperature (on average -0.5 °C for the Mediterranean SST). In addition, the latent heat loss is shown to be weaker (-11.0 Wm-2) in the presence of aerosols, resulting in a decrease in specific humidity in the lower troposphere, and a reduction in cloud cover and precipitation. Simulations also indicate that dust aerosols warm the troposphere by absorbing solar radiation, and prevent radiation from reaching the surface, thus stabilizing the troposphere. The comparison with the model response in atmosphere-only simulations shows that these feedbacks are attenuated if SST cannot be modified by aerosols, highlighting the importance of using coupled regional models over the Mediterranean. Oceanic convection is also strengthened by aerosols, which tends to reinforce the Mediterranean thermohaline circulation. In parallel, two case studies are presented to illustrate positive feedbacks between dust aerosols and regional climate. First, the eastern Mediterranean was subject to high dust aerosol loads in June 2007 which reduce land and sea surface temperature, as well as air-sea humidity fluxes. Because of northern wind over the eastern Mediterranean, drier and cooler air has been consequently advected from the sea to the African continent, reinforcing the direct dust effect over land. On the contrary, during the western European heat wave in June 2006, dust aerosols have contributed to reinforcing an important ridge responsible for dry and warm air advection over western Europe, and thus to increasing lower troposphere (+0.8 °C) and surface temperature (+0.5 °C), namely about 15 % of this heat wave.

Quantification of evaporation induced error in atom probe tomography using molecular dynamics simulation.

PubMed

Chen, Shu Jian; Yao, Xupei; Zheng, Changxi; Duan, Wen Hui

2017-11-01

Non-equilibrium molecular dynamics was used to simulate the dynamics of atoms at the atom probe surface and five objective functions were used to quantify errors. The results suggested that before ionization, thermal vibration and collision caused the atoms to displace up to 1Å and 25Å respectively. The average atom displacements were found to vary between 0.2 and 0.5Å. About 9 to 17% of the atoms were affected by collision. Due to the effects of collision and ion-ion repulsion, the back-calculated positions were on average 0.3-0.5Å different from the pre-ionized positions of the atoms when the number of ions generated per pulse was minimal. This difference could increase up to 8-10Å when 1.5ion/nm 2 were evaporated per pulse. On the basis of the results, surface ion density was considered an important factor that needed to be controlled to minimize error in the evaporation process. Copyright © 2017. Published by Elsevier B.V.

Plastic pollution in the South Pacific subtropical gyre.

PubMed

Eriksen, Marcus; Maximenko, Nikolai; Thiel, Martin; Cummins, Anna; Lattin, Gwen; Wilson, Stiv; Hafner, Jan; Zellers, Ann; Rifman, Samuel

2013-03-15

Plastic marine pollution in the open ocean of the southern hemisphere is largely undocumented. Here, we report the result of a (4489 km) 2424 nautical mile transect through the South Pacific subtropical gyre, carried out in March-April 2011. Neuston samples were collected at 48 sites, averaging 50 nautical miles apart, using a manta trawl lined with a 333 μm mesh. The transect bisected a predicted accumulation zone associated with the convergence of surface currents, driven by local winds. The results show an increase in surface abundance of plastic pollution as we neared the center and decrease as we moved away, verifying the presence of a garbage patch. The average abundance and mass was 26,898 particles km(-2) and 70.96 g km(-2), respectively. 88.8% of the plastic pollution was found in the middle third of the samples with the highest value of 396,342 particles km(-2) occurring near the center of the predicted accumulation zone. Copyright © 2013 Elsevier Ltd. All rights reserved.

[Responses of rice growth and development to elevated near-surface layer ozone (O3) concentration: a review].

PubMed

Yang, Lian-xin; Wang, Yu-long; Shi, Guang-yao; Wang, Yun-xia; Zhu, Jian-guo

2008-04-01

Ozone (O3) is recognized as one of the most important air pollutants. At present, the worldwide average tropospheric O3 concentration has been increased from an estimated pre-industrial level of 38 nl L(-1) (25-45 nl L(-1), 8-h summer seasonal average) to approximately 50 nl L(-1) in 2000, and to 80 nl L(-1) by 2100 based on most pessimistic projections. Oryza sativa L. (rice) is the most important grain crop in the world, and thus, to correctly evaluate how the elevated near-surface layer O3 concentration will affect the growth and development of rice is of great significance. This paper reviewed the chamber (including closed and open top chamber)-based studies about the effects of atmospheric ozone enrichment on the rice visible injury symptoms, photosynthesis, water relationship, phenology, dry matter production and allocation, leaf membrane protective system, and grain yield and its components. Further research directions in this field were discussed.

Lunar near-surface shear wave velocities at the Apollo landing sites as inferred from spectral amplitude ratios

NASA Technical Reports Server (NTRS)

Horvath, P.; Latham, G. V.; Nakamura, Y.; Dorman, H. J.

1980-01-01

The horizontal-to-vertical amplitude ratios of the long-period seismograms are reexamined to determine the shear wave velocity distributions at the Apollo 12, 14, 15, and 16 lunar landing sites. Average spectral ratios, computed from a number of impact signals, were compared with spectral ratios calculated for the fundamental mode Rayleigh waves in media consisting of homogeneous, isotropic, horizontal layers. The shear velocities of the best fitting models at the different sites resemble each other and differ from the average for all sites by not more than 20% except for the bottom layer at station 14. The shear velocities increase from 40 m/s at the surface to about 400 m/s at depths between 95 and 160 m at the various sites. Within this depth range the velocity-depth functions are well represented by two piecewise linear segments, although the presence of first-order discontinuities cannot be ruled out.

Influence of atmospheric energy transport on amplification of winter warming in the Arctic

NASA Astrophysics Data System (ADS)

Alekseev, Genrikh; Kuzmina, Svetlana; Urazgildeeva, Aleksandra; Bobylev, Leonid

2016-04-01

The study was performed on base reanalysis ERA/Interim to discover the link between amplified warming in the high Arctic and the atmospheric transport of heat and water vapor through the 70 ° N. The partitioning transports across the Atlantic and Pacific "gates" is established the link between variations of atmospheric flux through the "gates" and a larger part of the variability of the average surface air temperature, water vapor content and its trends in the winter 1980-2014. Influence of winter (December-February) atmospheric transport across the Atlantic "gate" at the 1000 hPa on variability of average for January-February surface air temperature to north 70° N is estimated correlation coefficient 0.75 and contribution to the temperature trend 40%. These results for the first time denote the leading role of increasing atmospheric transport on the amplification of winter warming in the high Arctic. The investigation is supported with RFBR project 15-05-03512.

The Diamond Window with Boron-Doped Layers for the Output of Microwave Radiation at High Peak and Average Power Levels

NASA Astrophysics Data System (ADS)

Ivanov, O. A.; Kuzikov, S. V.; Vikharev, A. A.; Vikharev, A. L.; Lobaev, M. A.

2017-10-01

We propose a novel design of the barrier window for the output of microwave radiation at high peak and average power levels. A window based on a plate of polycrystalline CVD diamond with thin (nanometer-thick) boron-doped layers with increased conductivity is considered. Such a window, which retains the low radiation loss due to the small total thickness of the conductive layers and the high thermal conductivity inherent in diamond, prevents accumulation of a static charge on its surface, on the one hand, and allows one to produce a static electric field on the surface of the doped layer, which impedes the development of a multipactor discharge, on the other hand. In this case, a high level of the power of the transmitted radiation and a large passband width are ensured by choosing the configuration of the field in the form of a traveling wave inside the window.

More frequent showers and thunderstorm days under a warming climate: evidence observed over Northern Eurasia from 1966 to 2000

NASA Astrophysics Data System (ADS)

Ye, Hengchun; Fetzer, Eric J.; Wong, Sun; Lambrigtsen, Bjorn H.; Wang, Tao; Chen, Luke; Dang, Van

2017-09-01

This study uses 3-hourly synoptic observations at 547 stations to examine changes in convective and non-convective precipitation days and their associations with surface air temperature and specific humidity over Northern Eurasia. We found that convective days (showers and those associated with thunder and lightning) have become more frequent possibly at the expense of non-convective ones for all seasons during the study period of 1966-2000. The mean trends for convective day fraction (total convective precipitation events divided by all precipitation events for each season) are very similar among all four seasons at around 0.61-0.76% per year averaged over the study region. The temperature and humidity associated with convective events are on average 2.4-5.6 °C and 0.4-0.9 g/kg higher than those of non-convective events, respectively. This study suggests that surface warming and moistening lead to increased tropospheric static instability, contributing to the observed trends.

Vertical coherence of deformation in lithosphere in the eastern Himalayan syntaxis using GPS, Quaternary fault slip rates, and shear wave splitting data

NASA Astrophysics Data System (ADS)

Chang, Lijun; Flesch, Lucy M.; Wang, Chun-Yung; Ding, Zhifeng

2015-07-01

We present 59 new SKS/SKKS and combine them with 69 previously published data to infer the mantle deformation field in SE Tibet. The dense set of anisotropy measurements in the eastern Himalayan syntaxis (EHS) are oriented along a NE-SW azimuth and rotate clockwise in the surround regions. We use GPS measurements and geologic data to determine a continuous surface deformation field that is then used to predict shear wave spitting directions at each station. Comparison of splitting observations with predictions yields an average misfit of 11.7° illustrating that deformation is vertically coherent, consistent with previous studies. Within the central EHS in areas directly surrounding the Namche-Barwa metamorphic massif, the average misfit of 11 stations increases to 60.8°, and vertical coherence is no longer present. The complexity of the mantle anisotropy and surface observations argues for local alteration of the strain fields here associated with recent rapid exhumation of the Indian crust.

Effective dilution of surfactants due to thinning of the soap film

NASA Astrophysics Data System (ADS)

Sane, Aakash; Mandre, Shreyas; Kim, Ildoo

2017-11-01

A flowing soap film is a system whose hydrodynamic properties can be affected by its thickness. Despite abundant experiments performed using soap films, few have examined the dependence of its physical as well as chemical properties with respect to its thickness. We investigate one such property - surface tension of the flowing film and delineate its dependence on the concentration of the soap solution and flow rate per unit width i.e. thickness of the soap film. Using our proposed method to measure the average surface tension in-situ over the whole soap film, we show that the surface tension increases by reducing the thickness of the film and by reducing the concentration of the soap solution. Our data suggests that thinning of the soap film is effectively diluting the solution. Thinning increases the adsorption of surfactants to the surfaces, but it decreases the total number of molecules per unit area. Our work brings new insight into the physics of soap films and we believe that this effective dilution due to thinning is a signature of the flowing soap films, whose surface concentration of surfactants is affected by the thickness.

Multi-temporal AirSWOT elevations on the Willamette river: error characterization and algorithm testing

NASA Astrophysics Data System (ADS)

Tuozzolo, S.; Frasson, R. P. M.; Durand, M. T.

2017-12-01

We analyze a multi-temporal dataset of in-situ and airborne water surface measurements from the March 2015 AirSWOT field campaign on the Willamette River in Western Oregon, which included six days of AirSWOT flights over a 75km stretch of the river. We examine systematic errors associated with dark water and layover effects in the AirSWOT dataset, and test the efficacies of different filtering and spatial averaging techniques at reconstructing the water surface profile. Finally, we generate a spatially-averaged time-series of water surface elevation and water surface slope. These AirSWOT-derived reach-averaged values are ingested in a prospective SWOT discharge algorithm to assess its performance on SWOT-like data collected from a borderline SWOT-measurable river (mean width = 90m).

To Analyse the Erosive Potential of Commercially Available Drinks on Dental Enamel and Various Tooth Coloured Restorative Materials – An In-vitro Study

PubMed Central

Jindal, Ritu; Mahajan, Sandeep; Sandhu, Sanam; Sharma, Sunila; Kaur, Rajwinder

2016-01-01

Introduction With the enormous change in life style pattern of a common man through the past few decades, there has been proportional variation in the amount and frequency of consumption of drinks. An increased consumption of these drinks will concurrently increase enamel surface roughness by demineralization, resulting in hypersensitivity and elevated caries risk. Aim The present study was designed to evaluate the erosive potential of commercially available drinks on tooth enamel and various tooth coloured restorative materials. Materials and Methods Extracted human teeth were taken and divided into four groups i.e. tooth enamel, glass ionomer cement, composite and compomer. Four commercially available drinks were chosen these were Coca -Cola, Nimbooz, Frooti and Yakult. The pH of each drink was measured. Each group was immersed in various experimental drinks for a period of 14 days. The erosive potential of each drink was measured by calculating the change in average surface roughness of these groups after the immersion protocol in various drinks. The data analysis was done by One Way Anova, Post-Hoc Bonferroni, and paired t –test. Results Group II-GIC showed highest values for mean of change in average surface roughness and the values were statistically significant (p<0.001) with tooth enamel, composite and compomer (p=0.002). Coca-cola showed the highest erosive potential and Yakult showed the lowest, there was no statistical significant difference between the results shown by Yakult and Frooti. Conclusion Characteristics which may promote erosion of enamel and tooth coloured restorative materials were surface texture of the material and pH of the drinks. PMID:27437343

Tailoring Silica-alumina Supported Pt-Pd As Poison Tolerant Catalyst For Aromatics Hydrogenation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yu, Yanzhe; Gutierrez, Oliver Y.; Haller, Gary L.

2013-08-01

The tailoring of the physicochemical and catalytic properties of mono- and bimetallic Pt-Pd catalysts supported on amorphous silica-alumina is studied. Electron energy loss spectroscopy and extended X-ray absorption fine structure analyses indicated that bimetallic Pt-Pd and relatively large monometallic Pd particles were formed, whereas the X-ray absorption near edge structure provided direct evidence for the electronic deficiency of the Pt atoms. The heterogeneous distribution of metal particles was also shown by high resolution transmission electron microscopy. The average structure of the bimetallic particles (Pt-rich core and Pd-rich shell) and the presence of Pd particles led to surface Pd enrichment, whichmore » was independently shown by IR spectra of adsorbed CO. The specific metal distribution, average size, and surface composition of the Pt-Pd particles depend to a large extent on the metal precursors. In the presence of NH3 ligands, Pt-Pd particles with a fairly homogeneous bulk and surface metal distribution were formed. Also high Lewis acid site concentration of the carrier leads to more homogeneous bimetallic particles. All catalysts were active for the hydrogenation of tetralin in the absence and presence of quinoline and dibenzothiophene (DBT). Monometallic Pt catalysts had the highest hydrogenation activity in poison-free and quinoline-containing feed. When DBT was present, bimetallic Pt-Pd catalysts with the most homogenous metal distribution showed the highest activity. The higher resistance of bimetallic catalysts towards sulfur poisoning compared to their monometallic Pt counterparts results from the weakened metal-sulfur bond on the electron deficient Pt atoms. Thus, increasing the fraction of electron deficient Pt on the surface of the bimetallic particles increases the efficiency of the catalyst in the presence of sulfur.« less

Effect of Pd Surface Roughness on the Bonding Process and High Temperature Reliability of Au Ball Bonds

NASA Astrophysics Data System (ADS)

Huang, Y.; Kim, H. J.; McCracken, M.; Viswanathan, G.; Pon, F.; Mayer, M.; Zhou, Y. N.

2011-06-01

A 0.3- μm-thick electrolytic Pd layer was plated on 1 μm of electroless Ni on 1 mm-thick polished and roughened Cu substrates with roughness values ( R a) of 0.08 μm and 0.5 μm, respectively. The rough substrates were produced with sand-blasting. Au wire bonding on the Ni/Pd surface was optimized, and the electrical reliability was investigated under a high temperature storage test (HTST) during 800 h at 250°C by measuring the ball bond contact resistance, R c. The average value of R c of optimized ball bonds on the rough substrate was 1.96 mΩ which was about 40.0% higher than that on the smooth substrate. The initial bondability increased for the rougher surface, so that only half of the original ultrasonic level was required, but the reliability was not affected by surface roughness. For both substrate types, HTST caused bond healing, reducing the average R c by about 21% and 27%, respectively. Au diffusion into the Pd layer was observed in scanning transmission electron microscopy/ energy dispersive spectroscopy (STEM-EDS) line-scan analysis after HTST. It is considered that diffusion of Au or interdiffusion between Au and Pd can provide chemically strong bonding during HTST. This is supported by the R c decrease measured as the aging time increased. Cu migration was indicated in the STEM-EDS analysis, but its effect on reliability can be ignored. Au and Pd tend to form a complete solid solution at the interface and can provide reliable interconnection for high temperature (250°C) applications.

Optimal size for heating efficiency of superparamagnetic dextran-coated magnetite nanoparticles for application in magnetic fluid hyperthermia

NASA Astrophysics Data System (ADS)

Shaterabadi, Zhila; Nabiyouni, Gholamreza; Soleymani, Meysam

2018-06-01

Dextran-coated magnetite (Fe3O4) nanoparticles with average particle sizes of 4 and 19 nm were synthesized through in situ and semi-two-step co-precipitation methods, respectively. The experimental results confirm the formation of pure phase of magnetite as well as the presence of dextran layer on the surface of modified magnetite nanoparticles. The results also reveal that both samples have the superparamagnetic behavior. Furthermore, calorimetric measurements show that the dextran-coated Fe3O4 nanoparticles with an average size of 4 nm cannot produce any appreciable heat under a biologically safe alternating magnetic field used in hyperthermia therapy; whereas, the larger ones (average size of 19 nm) are able to increase the temperature of their surrounding medium up to above therapeutic range. In addition, measured specific absorption rate (SAR) values confirm that magnetite nanoparticles with an average size of 19 nm are very excellent candidates for application in magnetic hyperthermia therapy.

Hydrodynamic instability experiments with three-dimensional modulations at the National Ignition Facility

DOE PAGES

Smalyuk, V. A.; Weber, S. V.; Casey, D. T.; ...

2015-06-18

The first hydrodynamic instability growth measurements with three-dimensional (3D) surface-roughness modulations were performed on CH shell spherical implosions at the National Ignition Facility (NIF) [G. H. Miller, E. I. Moses, and C. R. Wuest, Opt. Eng. 43, 2841 (2004)]. The initial capsule outer-surface amplitudes were increased approximately four times, compared with the standard specifications, to increase the signal-to-noise ratio, helping to qualify a technique for measuring small 3D modulations. The instability growth measurements were performed using x-ray through-foil radiography based on time-resolved pinhole imaging. Averaging over 15 similar images significantly increased the signal-to-noise ratio, making possible a comparison with 3Dmore » simulations. At a convergence ratio of ~2.4, the measured modulation levels were ~3 times larger than those simulated based on the growth of the known imposed initial surface modulations. Several hypotheses are discussed, including increased instability growth due to modulations of the oxygen content in the bulk of the capsule. In conclusion, future experiments will be focused on measurements with standard 3D ‘native-roughness’ capsules as well as with deliberately imposed oxygen modulations.« less

Surface modification of carbon fibers by a polyether sulfone emulsion sizing for increased interfacial adhesion with polyether sulfone

NASA Astrophysics Data System (ADS)

Yuan, Haojie; Zhang, Shouchun; Lu, Chunxiang

2014-10-01

Interests on carbon fiber-reinforced thermoplastic composites are growing rapidly, but the challenges with poor interfacial adhesion have slowed their adoption. In this work, a polyether sulfone (PES) emulsion sizing was prepared successfully for increased interfacial adhesion of carbon fiber/PES composites. To obtain a high-quality PES emulsion sizing, the key factor, emulsifier concentration, was studied by dynamic light scattering technique. The results demonstrated that the suitable weight ratio of PES to emulsifier was 8:3, and the resulting PES emulsion sizing had an average particle diameter of 117 nm and Zeta potential of -52.6 mV. After sizing, the surface oxygen-containing functional groups, free energy and wettability of carbon fibers increased significantly, which were advantageous to promote molecular-level contact between carbon fiber and PES. Finally, short beam shear tests were performed to evaluate the interfacial adhesion of carbon fiber/PES composites. The results indicated that PES emulsion sizing played a critical role for the enhanced interfacial adhesion in carbon fiber/PES composites, and a 26% increase of interlaminar shear strength was achieved, because of the improved fiber surface wettability and interfacial compatibility between carbon fiber and PES.

The impact of urbanization on wind speed and surface aerodynamic characteristics in Beijing during 1991-2011

NASA Astrophysics Data System (ADS)

Liu, Junkai; Gao, Zhiqiu; Wang, Linlin; Li, Yubin; Gao, Chloe Y.

2018-06-01

Urbanization has a significant influence on climate and meteorological conditions through altering surface aerodynamic characteristics. Based on observational data collected at 15 levels on a 325 m meteorological tower in Beijing during 1991-2011, changes in wind speed, vertical profile, aerodynamic roughness length (z0), and zero-plane displacement height (zd) were analyzed. Decreasing trends were observed predominantly during this period, especially for levels between 65 and 140 m where the largest decreasing rates often occur. The annual and seasonal (spring, summer, autumn, and winter) mean wind speeds at 15 levels all present decreasing trends with average rates of 0.029, 0.024, 0.023, 0.040, and 0.019 m s-1 a-1, respectively. The decreases in strong wind categories contribute most to the reduction of mean wind speed. Furthermore, in 2005-2011, the diurnal maximum wind speeds at lower levels tend to appear earlier as compared to those in 1991-1997, while the patterns of diurnal cycle between different levels become more similar in these periods. Besides, the phenomena of "kink" in wind profiles are visible in various atmospheric stabilities, and the average height of a kink has increased from about 40 m to nearly 80 m associated with urbanization during 1991-2011. In addition, the results of z0 and zd calculated using the wind profile method vary with wind directions due to surface heterogeneity and that larger values often occur along with southerly winds. Both z0 and zd show increasing trends in different sectors during 1991-2011, and the annual mean z0 and zd have increased from less than 1 m to greater than 2 m, and from less than 10 m to greater than 20 m, respectively.

Blowing momentum and duty cycle effect on aerodynamic performance of flap by pulsed blowing

NASA Astrophysics Data System (ADS)

Zhou, Ping; Wang, Yankui; Wang, Jinjun; Sha, Yongxiang

2017-04-01

Control surface, which is often located in the trailing edge of wings, is important in the attitude control of an aircraft. However, the efficiency of the control surface declines severely under the high deflect angle of the control surface because of the flow separation. To improve the efficiency of control surface, this study discusses a flow-control technique aimed at suppressing the flow separation by pulsed blowing at the leading edge of the control surface. Results indicated that flow separation over the control surface can be suppressed by pulsed blowing, and the maximum average lift coefficient of the control surface can be 95% times higher than that of without blowing when average blowing momentum coefficient is 0.03 relative to that of without blowing. Finally, this study shows that the average blowing momentum coefficient and non-dimensional frequency of pulsed blowing are two of the key parameters of the pulsed blowing control technique. Otherwise, duty cycle also has influence on the effect of pulsed blowing. Numerical simulation is used in this study.

Cellulose and lignin colocalization at the plant cell wall surface limits microbial hydrolysis of Populus biomass

DOE PAGES

Dumitrache, Alexandru; Tolbert, Allison; Natzke, Jace; ...

2017-04-20

Biorefining of plant feedstocks into fuels and specialty chemicals, using biological conversion, requires the solubilization of lignocellulosics into simpler oligomeric compounds. However, non-pretreated woody biomass has shown high resistance to hydrolysis by cellulolytic microbes or purified cellulases. We investigate the limited solubilization of Populus deltoides by the cellulolytic thermophile Clostridium thermocellum in the absence of solute inhibitors. Compared to control samples, fermented poplar revealed that the hydrolysis of carbohydrates in secondary cell walls ceased prematurely as lignin presence increased at the surface. In quantitative fluorescence colocalization analysis by confocal laser scanning microscopy, the Manders’ coefficient of fractional overlap between ligninmore » and cellulose signals increased from an average of 0.67 to a near-maximum 0.92 in fermented tissue. Chemical imaging by time-of-flight secondary ion mass spectrometry revealed a 49% decline in surface cellulose and a compensatory 30% and 11% increase in surface S- and G- lignin, respectively. Although 72% of the initial glucan was still present in the lignocellulose matrix of this feedstock, subsequent treatments with cell-free purified cellulases did not significantly restore hydrolysis. This confirmed that biomass surfaces had become non-productive for the C. thermocellum hydrolytic exoproteome. This study provides direct evidence for an explicit definition of feedstock recalcitrance, whereby depletion of surface carbohydrate increases lignin exposure which leads to inhibition of enzyme activity, while the bulk residual biomass retains significant undigested carbohydrate content. The analysis presented here establishes a novel method for the quantitation of lignocellulose recalcitrance.« less

Cellulose and lignin colocalization at the plant cell wall surface limits microbial hydrolysis of Populus biomass

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dumitrache, Alexandru; Tolbert, Allison; Natzke, Jace

Biorefining of plant feedstocks into fuels and specialty chemicals, using biological conversion, requires the solubilization of lignocellulosics into simpler oligomeric compounds. However, non-pretreated woody biomass has shown high resistance to hydrolysis by cellulolytic microbes or purified cellulases. We investigate the limited solubilization of Populus deltoides by the cellulolytic thermophile Clostridium thermocellum in the absence of solute inhibitors. Compared to control samples, fermented poplar revealed that the hydrolysis of carbohydrates in secondary cell walls ceased prematurely as lignin presence increased at the surface. In quantitative fluorescence colocalization analysis by confocal laser scanning microscopy, the Manders’ coefficient of fractional overlap between ligninmore » and cellulose signals increased from an average of 0.67 to a near-maximum 0.92 in fermented tissue. Chemical imaging by time-of-flight secondary ion mass spectrometry revealed a 49% decline in surface cellulose and a compensatory 30% and 11% increase in surface S- and G- lignin, respectively. Although 72% of the initial glucan was still present in the lignocellulose matrix of this feedstock, subsequent treatments with cell-free purified cellulases did not significantly restore hydrolysis. This confirmed that biomass surfaces had become non-productive for the C. thermocellum hydrolytic exoproteome. This study provides direct evidence for an explicit definition of feedstock recalcitrance, whereby depletion of surface carbohydrate increases lignin exposure which leads to inhibition of enzyme activity, while the bulk residual biomass retains significant undigested carbohydrate content. The analysis presented here establishes a novel method for the quantitation of lignocellulose recalcitrance.« less

Relationships between surface free energy, surface texture parameters and controlled drug release in hydrophilic matrices.

PubMed

Saurí, J; Suñé-Negre, J M; Díaz-Marcos, J; Vilana, J; Millán, D; Ticó, J R; Miñarro, M; Pérez-Lozano, P; García-Montoya, E

2015-01-15

The study of controlled release and drug release devices has been dominated by considerations of the bulk or average properties of material or devices. Yet the outermost surface atoms play a central role in their performance. The objective of this article has been to characterize the surface of hydrophilic matrix tablets using the contact angle (CA) method to ascertain the surface free energy, and atomic force microscopy (AFM) and confocal microscopy (CM) for the physical characterization of the surface of the hydrophilic matrix. The surface free energy results obtained show that hydroxypropylmethylcellulose K15M hinders the spreading of water on the surface of the tablet, such that the concentration of HPMC K15M increases the reaction rate of the hydrophobic interactions between the chains of HPMC K15M which increases with respect to the rate of penetration of water into the tablet. In this study, we developed a new method to characterize the swelling of the tablets and established a relationship between the new method based on microswelling and the swelling ratio parameter. The surface texture parameters have been determined and the morphology of the tablets of the different formulations and the evolution of the surface morphology after interacting with the water, swelling and forming a gel layer were characterized. This work represents significant progress in the characterization of matrix tablets. Copyright © 2014 Elsevier B.V. All rights reserved.

Enhancing the electrochemical performance of Li-rich layered oxide Li1.13Ni0.3Mn0.57O2 via WO3 doping and accompanying spontaneous surface phase formation

NASA Astrophysics Data System (ADS)

Huang, Jiajia; Liu, Haodong; Hu, Tao; Meng, Ying Shirley; Luo, Jian

2018-01-01

WO3 doping and accompanying spontaneous formation of a surface phase can substantially improve the discharge capacity, rate capability, and cycling stability of Co-free Li-rich layered oxide Li1.13Ni0.3Mn0.57O2 cathode material. X-ray photoelectron spectroscopy, in conjunction with ion sputtering, shows that W segregates to the particle surfaces, decreases the surface Ni/Mn ratio, and changes the surface valence state. High-resolution transmission electron microscopy further suggests that W segregation increases surface structural disorder. The spontaneous and simultaneous changes in the surface structure, composition, and valence state represent the formation of a surface phase (complexion) as the preferred surface thermodynamic state. Consequently, the averaged discharge capacity is increased by ∼13% from 251 to 284 mAh g-1 at a low rate of C/20 and by ∼200% from 30 to 90 mAh g-1 at a high rate of 40C, in comparison with an undoped specimen processed under identical conditions. Moreover, after 100 cycles at a charge/discharge rate of 1C, the WO3 doped specimen retained a discharge capacity of 188 mAh g-1, being 27% higher than that of the undoped specimen. In a broader context, this work exemplifies an opportunity of utilizing spontaneously-formed surface phases as a scalable and cost-effective method to improve materials properties.

Automotive System for Remote Surface Classification.

PubMed

Bystrov, Aleksandr; Hoare, Edward; Tran, Thuy-Yung; Clarke, Nigel; Gashinova, Marina; Cherniakov, Mikhail

2017-04-01

In this paper we shall discuss a novel approach to road surface recognition, based on the analysis of backscattered microwave and ultrasonic signals. The novelty of our method is sonar and polarimetric radar data fusion, extraction of features for separate swathes of illuminated surface (segmentation), and using of multi-stage artificial neural network for surface classification. The developed system consists of 24 GHz radar and 40 kHz ultrasonic sensor. The features are extracted from backscattered signals and then the procedures of principal component analysis and supervised classification are applied to feature data. The special attention is paid to multi-stage artificial neural network which allows an overall increase in classification accuracy. The proposed technique was tested for recognition of a large number of real surfaces in different weather conditions with the average accuracy of correct classification of 95%. The obtained results thereby demonstrate that the use of proposed system architecture and statistical methods allow for reliable discrimination of various road surfaces in real conditions.

Effect of intrinsic surface roughness on the efficiency of intermodal phase matching in silica optical nanofibers.

PubMed

Khudus, Muhammad I M Abdul; Lee, Timothy; Horak, Peter; Brambilla, Gilberto

2015-04-01

We investigate the effect of intrinsic surface roughness associated to frozen thermal oscillations from the fiber fabrication process on the efficiency of third-harmonic generation via intermodal phase matching in silica nanofibers. Already a periodic wave with roughness of 0.2 nm reduces the efficiency by roughly 50% in a 1-mm optical nanofiber, with the divergence growing quadratically with distance. The surface wave period does not exhibit a large impact on the efficiency, due to averaging effects. However, both the location of the surface waves with respect to the phase matching radius as well as the surface wave amplitude have substantial effect on the efficiency, with the former presenting the possibility of transferring the power back to the pump wavelength. Simulations with a realistic superposition of random surface waves indicate that the conversion efficiency increases only for a few mm of propagation and reaches a maximum of less than 1%.

Automotive System for Remote Surface Classification

PubMed Central

Bystrov, Aleksandr; Hoare, Edward; Tran, Thuy-Yung; Clarke, Nigel; Gashinova, Marina; Cherniakov, Mikhail

2017-01-01

In this paper we shall discuss a novel approach to road surface recognition, based on the analysis of backscattered microwave and ultrasonic signals. The novelty of our method is sonar and polarimetric radar data fusion, extraction of features for separate swathes of illuminated surface (segmentation), and using of multi-stage artificial neural network for surface classification. The developed system consists of 24 GHz radar and 40 kHz ultrasonic sensor. The features are extracted from backscattered signals and then the procedures of principal component analysis and supervised classification are applied to feature data. The special attention is paid to multi-stage artificial neural network which allows an overall increase in classification accuracy. The proposed technique was tested for recognition of a large number of real surfaces in different weather conditions with the average accuracy of correct classification of 95%. The obtained results thereby demonstrate that the use of proposed system architecture and statistical methods allow for reliable discrimination of various road surfaces in real conditions. PMID:28368297

Non-fouling surfaces produced by gas phase pulsed plasma polymerization of an ultra low molecular weight ethylene oxide containing monomer.

PubMed

Wu; Timmons; Jen; Molock

2000-10-01

The pulsed plasma polymerization of low molecular weight molecules containing only one (ethylene oxide vinyl ether) and two (diethylene oxide vinyl ether) ethylene oxide units were investigated. The surface density of EO units retained in the polymer films increases sharply with decreasing average power input during deposition, particularly at very low plasma duty cycles. The protein adsorption properties of these plasma synthesized polymer were investigated using 125I-labeled albumin and fibrinogen. Surprisingly effective, non-fouling surfaces were observed with films synthesized from the monomer containing two ethylene oxide units; however, the monomer containing only one EO unit gave surfaces that were not particularly effective in preventing protein adsorptions. The results obtained show that ultra short chain length PEO modified surfaces can be biologically non-fouling. This, in turn, has interesting consequences in terms of trying to identify the basic reason for the effectiveness of EO units in preventing biomolecule adsorptions on surfaces.

Analysis of linear electrode array EMG for assessment of hemiparetic biceps brachii muscles.

PubMed

Yao, Bo; Zhang, Xu; Li, Sheng; Li, Xiaoyan; Chen, Xiang; Klein, Cliff S; Zhou, Ping

2015-01-01

This study presents a frequency analysis of surface electromyogram (EMG) signals acquired by a linear electrode array from the biceps brachii muscles bilaterally in 14 hemiparetic stroke subjects. For different levels of isometric contraction ranging from 10 to 80% of the maximum voluntary contraction (MVC), the power spectra of 19 bipolar surface EMG channels arranged proximally to distally along the muscle fibers were examined in both paretic and contralateral muscles. It was found that across all stroke subjects, the median frequency (MF) and the mean power frequency (MPF), averaged from different surface EMG channels, were significantly smaller in the paretic muscle compared to the contralateral muscle at each of the matched percent MVC contractions. The muscle fiber conduction velocity (MFCV) was significantly slower in the paretic muscle than in the contralateral muscle. No significant correlation between the averaged MF, MPF, or MFCV vs. torque was found in both paretic and contralateral muscles. However, there was a significant positive correlation between the global MFCV and MF. Examination of individual EMG channels showed that electrodes closest to the estimated muscle innervation zones produced surface EMG signals with significantly higher MF and MPF than more proximal or distal locations in both paretic and contralateral sides. These findings suggest complex central and peripheral neuromuscular alterations (such as selective loss of large motor units, disordered control of motor units, increased motor unit synchronization, and atrophy of muscle fibers, etc.) which can collectively influence the surface EMG signals. The frequency difference with regard to the innervation zone also confirms the relevance of electrode position in surface EMG analysis.

ESTIMATION OF EFFECTIVE SHEAR STRESS WORKING ON FLAT SHEET MEMBRANE USING FLUIDIZED MEDIA IN MBRs

NASA Astrophysics Data System (ADS)

Zaw, Hlwan Moe; Li, Tairi; Nagaoka, Hiroshi; Mishima, Iori

This study was aimed at estimating effective shear stress working on flat sheet membrane by the addition of fluidized media in MBRs. In both of laboratory-scale aeration tanks with and without fluidized media, shear stress variations on membrane surface and water phase velocity variations were measured and MBR operation was conducted. For the evaluation of the effective shear stress working on membrane surface to mitigate membrane surface, simulation of trans-membrane pressure increase was conducted. It was shown that the time-averaged absolute value of shear stress was smaller in the reactor with fluidized media than without fluidized media. However, due to strong turbulence in the reactor with fluidized media caused by interaction between water-phase and media and also due to the direct interaction between membrane surface and fluidized media, standard deviation of shear stress on membrane surface was larger in the reactor with fluidized media than without media. Histograms of shear stress variation data were fitted well to normal distribution curves and mean plus three times of standard deviation was defined to be a maximum shear stress value. By applying the defined maximum shear stress to a membrane fouling model, trans-membrane pressure curve in the MBR experiment was simulated well by the fouling model indicting that the maximum shear stress, not time-averaged shear stress, can be regarded as an effective shear stress to prevent membrane fouling in submerged flat-sheet MBRs.

Near-surface Salinity and Temperature Structure Observed with Dual-Sensor Drifters in the Subtropical South Pacific

NASA Astrophysics Data System (ADS)

Dong, Shenfu; Goni, Gustavo; Volkov, Denis; Lumpkin, Rick; Foltz, Gregory

2017-04-01

Three surface drifters equipped with temperature and salinity sensors at 0.2 m and 5 m depths were deployed in April/May 2015 in the subtropical South Pacific Ocean with the objective of measuring near-surface salinity differences seen by satellite and in situ sensors and examining the causes of the differences. Measurements from these drifters indicate that, on average, water at a depth of 0.2 m is about 0.013 psu fresher than at 5 m and about 0.024°C warmer. Events with large temperature and salinity differences between the two depths often occur when surface winds are weak. In addition to the expected surface freshening and cooling during rainfall events, surface salinification occurs under weak wind conditions when there is strong surface warming that enhances evaporation and upper ocean stratification. Further examination of the drifter measurements demonstrate that (i) the amount of surface freshening and vertical salinity gradient heavily depend on wind speed during rain events, (ii) salinity differences between 0.2 m and 5 m are positively correlated with the corresponding temperature differences, and (iii) temperature exhibits a diurnal cycle at both depths, whereas the diurnal cycle of salinity is observed only at 0.2 m when the wind speed is less than 4 m/s. Its phase is consistent with diurnal changes in surface temperature-induced evaporation. Below a wind speed of 6 m/s, the amplitudes of the diurnal cycles of temperature at both depths decrease with increasing wind speed. Wind speed also affects the phasing of the diurnal cycle of T5m with the time of maximum T5m increasing gradually with decreasing wind speed. Wind speed does not affect the phasing of the diurnal cycle of T0.2m. At 0.2 m and 5 m, the diurnal cycle of temperature also depends on surface solar radiation, with the amplitude and time of diurnal maximum increasing as solar radiation increases.

Characterizing the seasonal cycle and vertical structure of ozone in Paris, France using four years of ground based LIDAR measurements in the lowermost troposphere

NASA Astrophysics Data System (ADS)

Klein, Amélie; Ancellet, Gérard; Ravetta, François; Thomas, Jennie L.; Pazmino, Andrea

2017-10-01

Systematic ozone LIDAR measurements were completed during a 4 year period (2011-2014) in Paris, France to study the seasonal variability of the vertical structure of ozone in the urban boundary layer. In addition, we use in-situ measurements from the surface air quality network that is located in Paris (AIRPARIF). Specifically, we use ozone and NO2 measurements made at two urban stations: Paris13 (60 m ASL) and the Eiffel Tower (310 m ASL) to validate and interpret the LIDAR profiles. Remote sensed tropospheric NO2 integrated columns from the SAOZ instrument located in Paris are also used to interpret ozone measurements. Comparison between ozone LIDAR measurements averaged from 250 m to 500 m and the Eiffel Tower in-situ measurements shows that the accuracy of the LIDAR (originally ±14 μg·m-3) is significantly improved (±7 μg·m-3) when a small telescope with a wide angular aperture is used. Results for the seasonal cycle of the ozone vertical gradient are found to be similar using two methods: (1) measured differences between AIRPARIF stations with measurements at 60 m ASL and 310 m ASL and (2) using LIDAR profiles from 300 m to the top of the Planetary Boundary Layer (PBL). Ozone concentrations measured by the LIDAR increase with altitude within the PBL, with a steeper gradient in winter (60 μg·m-3·km-1) and a less strong gradient in summer (20 μg·m-3·km-1). Results show that in winter, there is a sharp positive gradient of ozone at the surface, which is explained by ozone titration by NO combined with increased atmospheric stability in winter. In the afternoon during summer, photochemistry and vertical mixing are large enough to compensate for ozone titration near the surface, where NOx is emitted, and there is no gradient in ozone observed. In contrast, in the summer during the morning, ozone has a sharper positive vertical gradient similar to the winter values. Comparison of the vertically averaged ozone concentrations up to (0-3 km) and urban layer (0-310 m) ozone concentrations shows that the ratio between these two quantities is the largest in summer (86%) and the lowest in winter (49%). We conclude that satellite measurements that represent the 0-3 km integrated ozone column are not necessarily a good proxy for surface ozone and may lead to incorrect conclusions about the surface ozone seasonal variability. The ratio between the urban layer NO2 average concentration and the boundary layer NO2 average concentration obtained from SAOZ NO2 tropospheric columns is always less than 50%, meaning NO2 does not decrease linearly in the PBL, but with a sharper decrease close to the surface.

Impact of fire on global land carbon, water, and energy budgets and climate during the 20th century through changing ecosystems

NASA Astrophysics Data System (ADS)

Li, F.; Lawrence, D. M.; Bond-Lamberty, B. P.; Levis, S.

2016-12-01

Fire is an integral Earth system process and the primary form of terrestrial ecosystem disturbance on a global scale. Here we provide the first quantitative assessment and understanding on fire's impact on global land carbon, water, and energy budgets and climate through changing ecosystems. This is done by quantifying the difference between 20th century fire-on and fire-off simulations using the Community Earth System Model (CESM1.2). Results show that fire decreases the net carbon gain of global terrestrial ecosystems by 1.0 Pg C/yr averaged across the 20th century, as a result of biomass and peat burning (1.9 Pg C/yr) partly offset by changing gross primary productivity, respiration, and land-use carbon loss (-0.9 Pg C/yr). In addition, fire's effect on global carbon budget intensifies with time. Fire significantly reduces land evapotranspiration (ET) by 600 km3/yr and increases runoff, but has limited impact on precipitation. The impact on ET and runoff is most clearly seen in the tropical savannas, African rainforest, and some boreal and Southern Asian forests mainly due to fire-induced reduction in the vegetation canopy. It also weakens both the significant upward trend in global land ET prior to the 1950s and the downward trend from 1950 to 1985 by 35%. Fire-induced changes in land ecosystems affects global energy budgets by significantly reducing latent heating and surface net radiation. Fire changes surface radiative budget dominantly by raising surface upward longwave radiation and net longwave radiation. It also increases the global land average surface air temperature (Tas) by 0.04°C, and significantly increases wind speed and decreases surface relative humidity. The fire-induced change in wind speed, Tas, and relative humidity implies a positive feedback loop between fire and climate. Moreover, fire-induced changes in land ecosystems contribute 20% of strong global land warming during 1910-1940, which provides a new mechanism for the early 20th century global land warming. The results emphasize the importance of fire disturbance in the Earth's carbon, water, and energy cycles and climate by changing terrestrial ecosystems.

The Effects of Increasing Ocular Surface Stimulation on Blinking and Tear Secretion

PubMed Central

Wu, Ziwei; Begley, Carolyn G.; Port, Nicholas; Bradley, Arthur; Braun, Richard; King-Smith, Ewen

2015-01-01

Purpose. To investigate the effect of varying levels of ocular surface stimulation on the timing and amplitude of the blink and tear secretion. Methods. Following instillation of fluorescein dye, increasing levels of air flow were directed toward the central corneas of 10 healthy subjects. Interblink interval (IBI), tear meniscus height (TMH), and fluorescence intensity were measured simultaneously. Because blinking can obscure changes in TMH, we developed novel measures of tear secretion by calculating tear meniscus fluorescein concentration (TMFC) from intensity using a mathematical model. The change of TMH and TMFC over trials and the slope of the TMFC within each IBI (IBI-TTR) were further calculated. Results. The mean IBI was decreased by 8.08 ± 8.54 seconds from baseline to maximum air stimulation. The TMH increase was highly variable (0.41 ± 0.39 mm) among subjects, compared to the fluorescence tear turnover metrics: decrease in TMFC of 2.84 ± 0.98 natural logarithm or ln(%) and IBI-TTR of 0.065 ± 0.032 ln(%)/sec. Ocular surface stimulation was highly correlated with the TMFC and IBI-TTR, but less so with TMH (Pearson's r = 0.71, 0.69, and 0.40, P < 0.01, respectively). Blinking and tearing were significantly correlated with each other (Pearson's r = 0.56, P < 0.01), but tearing lagged behind by an average of 6.54 ± 4.07 seconds. Conclusions. Blinking and tearing share a common origin with sensory stimulation at the ocular surface. Both showed a dose–response increase with surface stimulation and were correlated with each other. These methods can potentially be used to understand alterations in ocular surface sensory function and associated protective responses in dry eye and other disorders of the ocular surface. PMID:26132780

The Effects of Increasing Ocular Surface Stimulation on Blinking and Tear Secretion.

PubMed

Wu, Ziwei; Begley, Carolyn G; Port, Nicholas; Bradley, Arthur; Braun, Richard; King-Smith, Ewen

2015-07-01

To investigate the effect of varying levels of ocular surface stimulation on the timing and amplitude of the blink and tear secretion. Following instillation of fluorescein dye, increasing levels of air flow were directed toward the central corneas of 10 healthy subjects. Interblink interval (IBI), tear meniscus height (TMH), and fluorescence intensity were measured simultaneously. Because blinking can obscure changes in TMH, we developed novel measures of tear secretion by calculating tear meniscus fluorescein concentration (TMFC) from intensity using a mathematical model. The change of TMH and TMFC over trials and the slope of the TMFC within each IBI (IBI-TTR) were further calculated. The mean IBI was decreased by 8.08 ± 8.54 seconds from baseline to maximum air stimulation. The TMH increase was highly variable (0.41 ± 0.39 mm) among subjects, compared to the fluorescence tear turnover metrics: decrease in TMFC of 2.84 ± 0.98 natural logarithm or ln(%) and IBI-TTR of 0.065 ± 0.032 ln(%)/sec. Ocular surface stimulation was highly correlated with the TMFC and IBI-TTR, but less so with TMH (Pearson's r = 0.71, 0.69, and 0.40, P < 0.01, respectively). Blinking and tearing were significantly correlated with each other (Pearson's r = 0.56, P < 0.01), but tearing lagged behind by an average of 6.54 ± 4.07 seconds. Blinking and tearing share a common origin with sensory stimulation at the ocular surface. Both showed a dose-response increase with surface stimulation and were correlated with each other. These methods can potentially be used to understand alterations in ocular surface sensory function and associated protective responses in dry eye and other disorders of the ocular surface.

Surface roughness control by extreme ultraviolet (EUV) radiation

NASA Astrophysics Data System (ADS)

Ahad, Inam Ul; Obeidi, Muhannad Ahmed; Budner, Bogusław; Bartnik, Andrzej; Fiedorowicz, Henryk; Brabazon, Dermot

2017-10-01

Surface roughness control of polymeric materials is often desirable in various biomedical engineering applications related to biocompatibility control, separation science and surface wettability control. In this study, Polyethylene terephthalate (PET) polymer films were irradiated with Extreme ultraviolet (EUV) photons in nitrogen environment and investigations were performed on surface roughness modification via EUV exposure. The samples were irradiated at 3 mm and 4 mm distance from the focal spot to investigate the effect of EUV fluence on topography. The topography of the EUV treated PET samples were studied by AFM. The detailed scanning was also performed on the sample irradiated at 3 mm. It was observed that the average surface roughness of PET samples was increased from 9 nm (pristine sample) to 280 nm and 253 nm for EUV irradiated samples. Detailed AFM studies confirmed the presence of 1.8 mm wide period U-shaped channels in EUV exposed PET samples. The walls of the channels were having FWHM of about 0.4 mm. The channels were created due to translatory movements of the sample in horizontal and transverse directions during the EUV exposure. The increased surface roughness is useful for many applications. The nanoscale channels fabricated by EUV exposure could be interesting for microfluidic applications based on lab-on-a-chip (LOC) devices.

Markedly Enhanced Surface Hydroxyl Groups of TiO2 Nanoparticles with Superior Water-Dispersibility for Photocatalysis

PubMed Central

Wu, Chung-Yi; Tu, Kuan-Ju; Deng, Jin-Pei; Lo, Yu-Shiu; Wu, Chien-Hou

2017-01-01

The benefits of increasing the number of surface hydroxyls on TiO2 nanoparticles (NPs) are known for environmental and energy applications; however, the roles of the hydroxyl groups have not been characterized and distinguished. Herein, TiO2 NPs with abundant surface hydroxyl groups were prepared using commercial titanium dioxide (ST-01) powder pretreated with alkaline hydrogen peroxide. Through this simple treatment, the pure anatase phase was retained with an average crystallite size of 5 nm and the surface hydroxyl group density was enhanced to 12.0 OH/nm2, estimated by thermogravimetric analysis, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. Especially, this treatment increased the amounts of terminal hydroxyls five- to six-fold, which could raise the isoelectric point and the positive charges on the TiO2 surface in water. The photocatalytic efficiency of the obtained TiO2 NPs was investigated by the photodegradation of sulforhodamine B under visible light irradiation as a function of TiO2 content, pH of solution, and initial dye concentration. The high surface hydroxyl group density of TiO2 NPs can not only enhance water-dispersibility but also promote dye sensitization by generating more hydroxyl radicals. PMID:28772926

[Characteristics of nutrient loss by runoff in sloping arable land of yellow-brown under different rainfall intensities].

PubMed

Chen, Ling; Liu, De-Fu; Song, Lin-Xu; Cui, Yu-Jie; Zhang, Gei

2013-06-01

In order to investigate the loss characteristics of N and P through surface flow and interflow under different rainfall intensities, a field experiment was conducted on the sloping arable land covered by typical yellow-brown soils inXiangxi River watershed by artificial rainfall. The results showed that the discharge of surface flow, total runoff and sediment increased with the increase of rain intensity, while the interflow was negatively correlated with rain intensity under the same total rainfall. TN, DN and DP were all flushed at the very beginning in surface flow underdifferent rainfall intensities; TP fluctuated and kept consistent in surface flow without obvious downtrend. While TN, DN and DP in interflow kept relatively stable in the whole runoff process, TP was high at the early stage, then rapidly decreased with time and kept steady finally. P was directly influenced by rainfall intensity, its concentration in the runoff increased with the increase of the rainfall intensity, the average concentration of N and P both exceeded the threshold of eutrophication of freshwater. The higher the amount of P loss was, the higher the rain intensity. The change of N loss was the opposite. The contribution rate of TN loss carried by surface flow increased from 36.5% to 57.6% with the increase of rainfall intensity, but surface flow was the primary form of P loss which contributed above 90.0%. Thus, it is crucial to control interflow in order to reduce N loss. In addition, measures should be taken to effectively manage soil erosion to mitigate P loss. The proportion of dissolved nitrogen in surface flow elevated with the decrease of rainfall intensity, but in interflow, dissolved form was predominant. P was exported mainly in the form of particulate under different rainfall intensities and runoff conditions.

Transition of surface energy budget in the Gobi Desert between spring and summer seasons

NASA Technical Reports Server (NTRS)

Smith, Eric A.; Reiter, Elmar R.; Gao, Youxi

1986-01-01

The surface energetics of the southwest Gobi Desert, including the temporal variations and diurnally averaged properties of the surface energy budget components, was investigated. The field program was conducted during the spring and summer of 1984, with the measurement system designed to monitor radiative exchange, heat/moisture storage in the soil, and sensible and latent heat exhange between the ground and the atmosphere. Results of the analysis reveal a seasonal transition feature not expected of a midlatitude desert. Namely, the differences in both surface radiation exchange and the distibution of sensible and latent heat transfer arise within a radiatively forced environment that barely deviates from spring to summer in terms of available solar energy at the surface. Both similarities and differences in the spring and summer surface energy budgets arise from differences imparted to the system by an increase in the summertime atmospheric moisture content. Changes in the near-surface mixing ratio are shown to alter the effectiveness of the desert surface in absorbing radiative energy and redistibuting it to the lower atmosphere through sensible and latent heat exchange.

Duplex stainless steel fracture surface analysis using X-ray fractography

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rajanna, K.; Pathiraj, B.; Kolster, B.H.

1997-02-01

The fatigue fracture surface of a duplex stainless steel was analyzed using x-ray fractography. A lower than average austenite content was observed at the fracture surface due to the transformation of austenite into deformation-induced martensite. The influence of fatigue cycling on the transformation was confined to a depth of about 30 {micro}m below the fracture surface. X-ray analyses of both the ferrite-martensite and the austenite phases indicated residual stresses ({sigma}{sub r}) increasing with depth from the fracture surface and reaching a maximum some tens of microns below the fracture surface. The lower {sigma}{sub r} observed at the fracture surface hasmore » been attributed to the stress relaxation effects caused by the new fracture surfaces created in the crack growth process. The observed decrease in full width at half maximum (FWHM) in the ferrite-martensite phase was presumed to be due to the dynamic recovery effect that was likely to occur within the material close to the crack tip as a consequence of fatigue cycling.« less

Effects of human activities and climate variability on water resources in the Saveh plain, Iran.

PubMed

Mohammadi Ghaleni, M; Ebrahimi, K

2015-02-01

Quantity and quality distribution of surface water and groundwater are changing under the impacts of both climate variability and human activities. The main goal of this paper is to evaluate the abovementioned impacts on the water resources in the Saveh plain, central Iran. To achieve this aim, spatial and temporal changes of the surface and groundwater quality and quantity have been analyzed, using hydrometric and meteorological data. The nonparametric Mann-Kendall test was used to identify trends and change points in the annual rainfall and runoff for the period of 1946 to 2011. In order to analyze the impacts of the Saveh Dam on runoff, the dam operation year, 1994, was considered as a change point. Mann-Kendall test results show that rainfall time series was divided into two parts, namely, 1966-1989 and 1990-2007, and averages of annual rainfall in five stations increase from 10 to 21 %. Also, runoff time series was divided into two parts, namely, 1946-1995 and 1996-2007 and averages of annual runoff in four stations decrease from 8 to 83 %. Results show that rainfall changes in Shahabasi, Razin, Jalayer, Emamabad, and Ahmadabad stations increased from 9 to 33 % before and after 1994. Nevertheless, runoff decreased from 24 to 81 %. The results indicate that the greatest lack of runoff between stations is at Shahabasi station and one important reason for the severe lack is operation of the Saveh Dam in 1994. Highest groundwater level decline, about 168.67 cm, occurred in 1994 that is the operation year of the Saveh Dam. Trend analysis of surface water quality show that electrical conductivity increased 957.34 μmho/cm before and after 1994. Also, the Wilcox water quality classification method has been reduced from C3-S1 to C4-S2. Average groundwater electrical conductivity (EC) during 1999-2003 and 2004-2009 increased to 89.6 μmho/cm. Also, the groundwater quality indices for agricultural usages are classified in four classes including, C4-S2 16, C4-S1 46, C3-S1 30, and C2-S1 8 % of the total aquifer area. In conclusion, in order to have a sustainable development, the effects of water projects on environment and water resources need to be predicted very carefully.

New perspectives on the Li isotopic composition of the upper continental crust and its weathering signature

NASA Astrophysics Data System (ADS)

Sauzéat, Lucie; Rudnick, Roberta L.; Chauvel, Catherine; Garçon, Marion; Tang, Ming

2015-10-01

Lithium isotopes are increasingly used to trace both present-day and past weathering processes at the surface of the Earth, and could potentially be used to evaluate the average degree of past weathering recorded by the upper continental crust (UCC). Yet the previous estimate of average δ7Li of the UCC has a rather large uncertainty, hindering the use of Li isotopes for this purpose. New δ7Li for desert and periglacial loess deposits (windblown dust) from several parts of the world (Europe, Argentina, China and Tajikistan) demonstrate that the former are more homogeneous than the latter, and may therefore serve as excellent proxies of the average composition of large tracts of the UCC. The Li isotopic compositions and concentrations of desert loess samples are controlled by eolian sorting that can be quantified by a binary mixing between a weathered, fine-grained end-member, dominated by phyllosilicates and having low δ7Li, and an unweathered, coarse-grained end-member, that is a mixture of quartz and plagioclase having higher δ7Li. We use correlations between insoluble elements (REE, Nd/Hf and Fe2O3/SiO2), Li concentrations (henceforth referred as [Li]), and δ7Li to estimate a new, more precise, average Li isotopic composition and concentration for the UCC: [ Li ] = 30.5 ± 3.6 (2 σ) ppm, and δ7Li = + 0.6 ± 0.6 (2 σ). The δ7Li for desert loess deposits is anti-correlated with the chemical index of alteration (CIA). Using this relationship, along with our average δ7Li, we infer that (1) the present-day CIA of the average UCC is 61-2+4 (2 σ), higher than the common reference value of 53, and (2) the average proportion of chemically weathered components is as high as 37-10+17 (2 σ)% at the surface of the Earth.

Potentiometric Surface of the Upper Floridan Aquifer in the St. Johns River Water Management District and Vicinity, May 2008

USGS Publications Warehouse

Kinnaman, Sandra L.; Dixon, Joann F.

2008-01-01

This map depicts the potentiometric surface of the Upper Floridan aquifer in the St. Johns River Water Management District and vicinity for May 2008. Potentiometric contours are based on water-level measurements collected at 567 wells during the period May 6-May 27, near the end of the dry season. Some contours are inferred from previous potentiometric-surface maps with larger well networks. The potentiometric surface of the carbonate Upper Floridan aquifer responds mainly to rainfall, and more locally, to ground-water withdrawals and spring flow. Potentiometric-surface highs generally correspond to topographic highs where the aquifer is recharged. Springs and areas of diffuse upward leakage naturally discharge water from the aquifer and are most prevalent along the St. Johns River. Areas of discharge are reflected by depressions in the potentiometric surface. Ground-water withdrawals locally have lowered the potentiometric surface. Ground water in the Upper Floridan aquifer generally flows from potentiometric highs to potentiometric lows in a direction perpendicular to the contours. Measured values of the potentiometric surface ranged from 7 feet below NGVD29 near Fernandina Beach, Florida, to 124 feet above NGVD29 in Polk County, Florida. The average water level of the network in May 2008 was about 1 foot lower than the average in September 2007 following below-average rainfall during the dry season of 2007-08. Seasonal differences in network average water levels generally range from 4 to 6 feet. For 457 wells with previous measurements, May 2008 levels ranged from about 19 feet below to about 11 feet above September 2007 water levels. The average water level of the network in May 2008 was about 1 foot higher than the average in May 2007. For 544 wells with previous measurements, May 2008 levels ranged from about 8 feet below to about 13 feet above May 2007 water levels. Long-term hydrographs of ground-water levels for continuous and periodic wells are available at internet site: http://waterdata.usgs.gov/fl/nwis/gw

Processing vertical size disparities in distinct depth planes.

PubMed

Duke, Philip A; Howard, Ian P

2012-08-17

A textured surface appears slanted about a vertical axis when the image in one eye is horizontally enlarged relative to the image in the other eye. The surface appears slanted in the opposite direction when the same image is vertically enlarged. Two superimposed textured surfaces with different horizontal size disparities appear as two surfaces that differ in slant. Superimposed textured surfaces with equal and opposite vertical size disparities appear as a single frontal surface. The vertical disparities are averaged. We investigated whether vertical size disparities are averaged across two superimposed textured surfaces in different depth planes or whether they induce distinct slants in the two depth planes. In Experiment 1, two superimposed textured surfaces with different vertical size disparities were presented in two depth planes defined by horizontal disparity. The surfaces induced distinct slants when the horizontal disparity was more than ±5 arcmin. Thus, vertical size disparities are not averaged over surfaces with different horizontal disparities. In Experiment 2 we confirmed that vertical size disparities are processed in surfaces away from the horopter, so the results of Experiment 1 cannot be explained by the processing of vertical size disparities in a fixated surface only. Together, these results show that vertical size disparities are processed separately in distinct depth planes. The results also suggest that vertical size disparities are not used to register slant globally by their effect on the registration of binocular direction of gaze.

Estimates of water use and trends in the Colorado River Basin, Southwestern United States, 1985–2010

USGS Publications Warehouse

Maupin, Molly A.; Ivahnenko, Tamara I.; Bruce, Breton

2018-06-26

The Colorado River Basin (CRB) drains 246,000 square miles and includes parts of California, Colorado, Nevada, New Mexico, Utah, and Wyoming, and all of Arizona (Basin States). This report contains water-use estimates by category of use for drainage basins (Hydrologic Unit Code 8; HUC‑8) within the CRB from 1985 to 2010, at 5-year intervals. Estimates for public supply, domestic, commercial, industrial, irrigation, livestock, mining, aquaculture, hydroelectric and thermoelectric power, and wastewater returns are tabulated as (1) water withdrawals from groundwater or surface‑water sources of fresh or saline quality, (2) water delivered for domestic use, (3) wastewater returns and instream use (hydroelectric), and (4) consumptive use, or water that is consumed (USGS definition) and not available for immediate reuse. Water transported outside of the CRB (interbasin transfers) is not included as part of withdrawals and are not accounted for in any category of use within the CRB.Total withdrawals in the CRB (excluding interbasin transfers) averaged about 17 million acre-feet (maf) from 1985 to 2010, peaked at about 17.76 maf in 2000, and reached their lowest levels of 16.43 maf in 1990. Interbasin transfers to serve mostly public-supply and irrigation needs outside of the CRB are reported for 2000, 2005, and 2010 only, and averaged 5.40 maf. More surface water was used in the CRB than groundwater, averaging about 78 percent of total withdrawals, and its use increased less than 2 percent from 1985 to 2010, while groundwater withdrawals decreased about 12 percent. From 1985 to 2010, surface water averaged 98 percent of withdrawals in the upper CRB, and about 59 percent in the lower CRB. Nearly all withdrawals were freshwater, but some saline groundwater was used for mining and self-supplied industrial.Interbasin transfers have a large effect on flows in the Colorado River and are listed in this report separately with no explanation of how the water is used outside of the CRB. There are 34 interbasin transfers that conveyed an estimated 5.83, 5.20, and 5.18 maf out of the CRB in 2000, 2005, and 2010, respectively. The largest interbasin transfers are in the lower CRB and convey surface water (Colorado River water) to southern California; these accounted for 80 to 84 percent of total interbasin transfers in the CRB from 2000 to 2010. Intrabasin transfers are conveyances of surface water that cross drainage basin or State boundaries in the CRB, but the water does not leave the CRB. There are many intrabasin transfers in the CRB, but this report lists 11 that are mostly in the State of Colorado. The largest is the Central Arizona Project (CAP), through which more than 1.00 maf of water was provided to irrigate nearly 1 million acres in Maricopa, Pinal, and Pima Counties, as well as provide municipal water for Phoenix and Tucson, Arizona, during 2000, 2005, and 2010. In 2010, interbasin and intrabasin transfers accounted for 24 and 11 percent of the total water withdrawals in CRB, respectively, with the larger volumes being conveyed out of the lower CRB.Total population in the CRB increased from 4.56 to 9.44 million people from 1985 to 2010. Most of those people were in the lower CRB, with 86 percent of the total in 1985, and 90 percent of the total in 2010. Total public-supply withdrawals in the CRB provided most people with their potable water, and averaged about 1.63 maf from 1985 to 2010, ranging from about 1.07 maf in 1985 to about 2.10 maf in 2010, when it peaked. Most of public-supply withdrawals occurred in the lower CRB, ranging from 87 to 91 percent of total public-supply withdrawals in the CRB over the 25 years. Total domestic use, comprised of public-supply deliveries and self-supply domestic withdrawals, increased more than 90 percent from 1985 to 2010, from about 0.80 maf to about 1.54 maf. Domestic daily per-capita use rates in the CRB ranged from about 144 (1985) to about 121 (2000) gallons (gal) per‑capita between 1985 and 2010. When comparing domestic daily per-capita rates for the upper and lower CRB, people in the lower CRB, on average, used less water for domestic purposes at 128 gal per-capita daily (1985–2010), while those in the upper CRB for the same time period averaged 133 gal per-capita daily. The trend in daily per-capita use rates for the entire CRB fluctuated between the reporting years, but decreased overall, indicating that more people used less water in 2010 than in 1985, likely due to improved infrastructure, conservation, and improvements to water using appliances in homes and businesses.Irrigation accounted for most total withdrawals in the CRB, excluding instream use for hydroelectric power and interbasin transfers, averaging 85 percent from 1985 to 2010. Far more surface water than groundwater was used for irrigation in both the upper and lower CRB, but in the upper CRB, it accounted for an average of more than 98 percent of the total withdrawals (1985–2010), whereas in the lower CRB, surface-water withdrawals for irrigation averaged 61 percent of total withdrawals. On average, the upper CRB accounted for 56 percent of total irrigated acres, and the irrigation systems in the upper CRB trended towards more efficient sprinkler systems from 1985 to 2010. Long-term drought in the CRB substantially decreased the amount of streamflow available for irrigation. Increases in micro-irrigation acres, which can have efficiencies that exceed 90 percent and require 20–50 percent less water than sprinkler systems, likely contributed to reduced withdrawals in the lower CRB.For thermoelectric power, total withdrawals, including the use of reclaimed wastewater, were greater in the upper CRB from 1985 through 2005. In 2010, the lower CRB exceeded the upper by only 11,000 acre-feet. On average, thermoelectric consumptive use accounted for about 80 percent of the total withdrawals; however, consumptive-use data in the upper CRB was incomplete. Surface water was the primary source in the upper CRB and groundwater was the primary source in the lower CRB. In the CRB overall, water withdrawals for thermoelectric generation has decreased since 2000, except for groundwater withdrawals in the lower CRB. Power generation at thermoelectric plants was greater in the upper CRB from 1985 to 2000, and after 2005 the difference in power generation was small; however, the upper CRB continued to have more power generation. In both the upper and lower CRB, power generation increased from 1985 to 2005.

Potential biases in evapotranspiration estimates from Earth system models due to spatial heterogeneity and lateral moisture redistribution

NASA Astrophysics Data System (ADS)

Rouholahnejad, E.; Kirchner, J. W.

2016-12-01

Evapotranspiration (ET) is a key process in land-climate interactions and affects the dynamics of the atmosphere at local and regional scales. In estimating ET, most earth system models average over considerable sub-grid heterogeneity in land surface properties, precipitation (P), and potential evapotranspiration (PET). This spatial averaging could potentially bias ET estimates, due to the nonlinearities in the underlying relationships. In addition, most earth system models ignore lateral redistribution of water within and between grid cells, which could potentially alter both local and regional ET. Here we present a first attempt to quantify the effects of spatial heterogeneity and lateral redistribution on grid-cell-averaged ET as seen from the atmosphere over heterogeneous landscapes. Using a Budyko framework to express ET as a function of P and PET, we quantify how sub-grid heterogeneity affects average ET at the scale of typical earth system model grid cells. We show that averaging over sub-grid heterogeneity in P and PET, as typical earth system models do, leads to overestimates of average ET. We use a similar approach to quantify how lateral redistribution of water could affect average ET, as seen from the atmosphere. We show that where the aridity index P/PET increases with altitude, gravitationally driven lateral redistribution will increase average ET, implying that models that neglect lateral moisture redistribution will underestimate average ET. In contrast, where the aridity index P/PET decreases with altitude, gravitationally driven lateral redistribution will decrease average ET. This approach yields a simple conceptual framework and mathematical expressions for determining whether, and how much, spatial heterogeneity and lateral redistribution can affect regional ET fluxes as seen from the atmosphere. This analysis provides the basis for quantifying heterogeneity and redistribution effects on ET at regional and continental scales, which will be the focus of future work.

Effects of surface-water and groundwater inflows and outflows on the hydrology of the Tsala Apopka Lake Basin in Citrus County, Florida

USGS Publications Warehouse

Sepúlveda, Nicasio; Fulkerson, Mark; Basso, Ron; Ryan, Patrick J.

2018-05-21

The U.S. Geological Survey, in cooperation with the Southwest Florida Water Management District, initiated a study to quantify the inflows and outflows in the Floral City, Inverness, and Hernando pools of the Tsala Apopka Lake Basin in Citrus County, Florida. This study assesses hydrologic changes in pool stages, groundwater levels, spring flows, and streamflows caused by the diversion of streamflow from the Withlacoochee River to the Tsala Apopka Lake Basin through water-control structures. A surface-water/groundwater flow model was developed using hydraulic parameters for lakes, streams, the unsaturated zone, and the underlying surficial and Upper Floridan aquifers estimated using an inverse modeling calibration technique. After calibration, the model was used to assess the relation between inflows and outflows in the Tsala Apopka Lake Basin and changes in pool stages.Simulation results using the calibrated surface-water/groundwater flow model showed that leakage rates from the pools to the Upper Floridan aquifer were largest at the deep lake cells and that these leakage rates to the Upper Floridan aquifer were the highest in the model area. Downward leakage to the Upper Floridan aquifer occurred beneath most of the extent of the Floral City, Inverness, and Hernando pools. These leakage rates depended on the lakebed leakance and the difference between lake stages and heads in the Upper Floridan aquifer. Leakage rates were higher for the Floral City pool than for the Inverness pool, and higher for the Inverness pool than for the Hernando pool. Lakebed leakance was higher for the Floral City pool than for the Hernando pool, and higher for the Hernando pool than for the Inverness pool.Simulation results showed that the average recharge rate to the surficial aquifer was 10.3 inches per year for the 2004 to 2012 simulation period. Areas that recharge the surficial aquifer covered about 86 percent of the model area. Simulations identified areas along segments of the Withlacoochee River and within land-surface depressions that receive water from the surficial aquifer. Recharge rates were largest in physiographic regions having a deep water table. Simulated heads in the Upper Floridan aquifer indicated the general flow directions in the active flow model area were from the northeast toward the southwest and then westward toward the coast, and from the southeast toward the northwest and then westward toward the coast, consistent with flow directions inferred from the estimated potentiometric surface map for May 2010. The largest inflow in the water budget of the Upper Floridan aquifer was downward leakage from the overlying hydrogeologic unit. The largest outflow in the water budget of the Upper Floridan aquifer was spring flow.The calibrated surface-water and groundwater flow model was used to simulate hydrologic scenarios that included changes in rainfall rates, projected increases in groundwater pumping rates for 2025 and 2035, no flow for the 2004–12 period through the eight water-control structures in the Tsala Apopka Lake Basin, and the removal of the Inglis Dam and the Inglis Bypass Spillway on Lake Rousseau. Scenario simulation results were compared to annual average calibrated water levels and flows from 2004 to 2012. Simulated declines in the Tsala Apopka Lake pool stages under the 10-percent lower rainfall scenario were about 0.8, 0.3, and 1.3 feet (ft) for the Floral City, Inverness, and Hernando pools, respectively. Simulated groundwater levels under the same scenario declined up to 5.4 ft in the surficial aquifer and up to 2.9 ft in the Upper Floridan aquifer. Under the projected increases in groundwater pumping rates for 2035 that represented an increase of 36 percent from average 2004 to 2012 pumping rates, the simulated declines in the Floral City, Inverness, and Hernando pool stages were, in downstream order, 0.02, 0.06, and 0.04 ft. The largest drawdown under the projected increases in groundwater pumping rates for 2035 was 2.1 ft in the surficial aquifer and about 1.8 ft in the Upper Floridan aquifer. A scenario of decreased rainfall by 10 percent caused greater declines in water levels and pool stages than projected increases in groundwater pumping rates. The simulation with no flow through the eight Tsala Apopka Lake water-control structures resulted in simulated declines in average pool stage of 1.8, 1.9, and 0.5 ft in the Floral City, Inverness, and Hernando pools, respectively. The simulated removal of the two water-control structures in Lake Rousseau caused flow to increase at Rainbow Springs by 28 cubic feet per second, an increase of 4.7 percent from the average calibrated flow for 2004 to 2012.