Science.gov

Sample records for industrial scale coal

  1. Statistical modeling of spontaneous combustion in industrial-scale coal stockpiles

    SciTech Connect

    Ozdeniz, H

    2009-07-01

    Companies consuming large amounts of coal should work with coal stocks in order to not face problems due to production delays. The industrial-scale stockpiles formed for the aforementioned reasons cause environmental problems and economic losses for the companies. This study was performed in a coal stock area of a large company in Konya, which uses large amounts of coal in its manufacturing units. The coal stockpile with 5 m width, 10 m length, 3 m height, and having 120 tons of weight was formed in the coal stock area of the company. The inner temperature data of the stockpile was recorded by 17 temperature sensors placed inside the stockpile at certain points. Additionally, the data relating to the air temperature, air humidity, atmospheric pressure, wind velocity, and wind direction that are the parameters affecting the coal stockpile were also recorded. A statistical model applicable for a spontaneous combustion event was developed during this study after applying multi-regression analyses to the data recorded in the stockpile during the spontaneous combustion event. The correlation coefficients obtained by the developed statistical model were measured approximately at a 0.95 level. Thus, the prediction of temperature variations influential in the spontaneous combustion event of the industrial-scale coal stockpiles will be possible.

  2. Coal industry annual 1997

    SciTech Connect

    1998-12-01

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  3. Coal Industry Annual 1995

    SciTech Connect

    1996-10-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  4. Coal industry annual 1996

    SciTech Connect

    1997-11-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  5. Coal industry annual 1993

    SciTech Connect

    Not Available

    1994-12-06

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

  6. Development and Testing of Industrial Scale Coal Fired Combustion System, Phase 3

    SciTech Connect

    Bert Zauderer

    1998-09-30

    Coal Tech Corp's mission is to develop, license & sell innovative, lowest cost, solid fuel fired power systems & total emission control processes using proprietary and patented technology for domestic and international markets. The present project 'DEVELOPMENT & TESTING OF INDUSTRIAL SCALE, COAL FIRED COMBUSTION SYSTEM, PHASE 3' on DOE Contract DE-AC22-91PC91162 was a key element in achieving this objective. The project consisted of five tasks that were divided into three phases. The first phase, 'Optimization of First Generation 20 MMBtu/hr Air-Cooled Slagging Coal Tech Combustor', consisted of three tasks, which are detailed in Appendix 'A' of this report. They were implemented in 1992 and 1993 at the first generation, 20 MMBtu/hour, combustor-boiler test site in Williamsport, PA. It consisted of substantial combustor modifications and coal-fired tests designed to improve the combustor's wall cooling, slag and ash management, automating of its operation, and correcting severe deficiencies in the coal feeding to the combustor. The need for these changes was indicated during the prior 900-hour test effort on this combustor that was conducted as part of the DOE Clean Coal Program. A combination of combustor changes, auxiliary equipment changes, sophisticated multi-dimensional combustion analysis, computer controlled automation, and series of single and double day shift tests totaling about 300 hours, either resolved these operational issues or indicated that further corrective changes were needed in the combustor design. The key result from both analyses and tests was that the combustor must be substantially lengthened to maximize combustion efficiency and sharply increase slag retention in the combustor. A measure of the success of these modifications was realized in the third phase of this project, consisting of task 5 entitled: 'Site Demonstration with the Second Generation 20 MMBtu/hr Air-Cooled Slagging Coal Tech Combustor'. The details of the task 5 effort are

  7. Artificial neural network modeling of the spontaneous combustion occurring in the industrial-scale coal stockpiles with 10-18 mm coal grain sizes

    SciTech Connect

    Ozdeniz, A.H.; Yilmaz, N.

    2009-07-01

    Companies consuming large amounts of coal should work with coal stocks in order to not face problems due to production delays. The industrial-scale stockpiles formed for the aforementioned reasons cause environmental problems and economic losses for the companies. This study was performed in a coal stock area of a large company in Konya, which uses large amounts of coal in its manufacturing units. The coal stockpile with 5 m width, 10 m length, 3 m height, and having 120 tons of weight was formed in the coal stock area of the company. The inner temperature data of the stockpile was recorded by 17 temperature sensors placed inside the stockpile at certain points. In order to achieve this goal, the electrical signal conversion of temperatures sensed by 17 temperature sensors placed in certain points inside the coal stockpile, the transfer of these electrical signals into computer media by using analog-digital conversion unit after applying necessary filtration and upgrading processes, and the record of these information into a database in particular time intervals are provided. Additionally, the data relating to the air temperature, air humidity, atmospheric pressure, wind velocity, and wind direction that are the parameters affecting the coal stockpile were also recorded. Afterwards, these measurement values were used for training and testing of an artificial neural network model. Comparison of the experimental and artificial neural network results, accuracy rates of training and testing were found to be 99.5% and 99.17%, respectively. It is shown that possible coal stockpile behavior with this artificial neural network model is powerfully estimated.

  8. Baseload, industrial-scale wind power: An alternative to coal in China

    SciTech Connect

    Lew, D.J.; Williams, R.H.; Xie Shaoxiong; Zhang Shihui

    1996-12-31

    This report presents a novel strategy for developing wind power on an industrial-scale in China. Oversized wind farms, large-scale electrical storage and long-distance transmission lines are integrated to deliver {open_quotes}baseload wind power{close_quotes} to distant electricity demand centers. The prospective costs for this approach to developing wind power are illustrated by modeling an oversized wind farm at Huitengxile, Inner Mongolia. Although storage adds to the total capital investment, it does not necessarily increase the cost of the delivered electricity. Storage makes it possible to increase the capacity factor of the electric transmission system, so that the unit cost for long-distance transmission is reduced. Moreover, baseload wind power is typically more valuable to the electric utility than intermittent wind power, so that storage can be economically attractive even in instances where the cost per kWh is somewhat higher than without storage. 9 refs., 3 figs., 2 tabs.

  9. Development and testing of industrial scale, coal fired combustion system, Phase 3

    SciTech Connect

    Zauderer, B.

    1993-02-15

    A major part of the work in this quarter was on the combustor tests in task 2. Three of the six planned tests in this task were completed. The first two were parametric tests of nominal one shift, (8 hour) duration on coal. Due to failure of the UV detector in the first test only several hours of coal fired operation were completed. In the second test, coal fired operation continued for the planned one shift until the 4 ton coal bin was empty. After reviewing this work with DOE, it was decided to focus the remaining test on longer duration operation with each test at one optimum condition. The third test was planned for two shift coal fired operation. Due to a problem with the pilot gas ignitor, combustion was delayed by 5 hours from 7 AM to Noon. As a result coal fired operation was limited to one shift between 3 PM and 11 PM. Throughout this period the combustor remained at one fixed condition with the use of computer control. Results for these three tests are presented in this report. Most of the work on the task 4 design and cost of a 20 MW combined gas-steam turbine power plant using the air cooled combustor was completed in the previous quarter. The results obtained by the A/E subcontractor on the installation desip and cost were evaluated in the present quarter and they are summarized in this report.

  10. Development & testing of industrial scale, coal fired combustion system, Phase 3. Eleventh quarterly technical progress report, July 1, 1994--September 30, 1994

    SciTech Connect

    Zauderer, B.

    1994-11-15

    The primary objective of the present effort is to perform the final testing, at a 20Mmbtu/hr commercial scale, of an air cooled, slagging coal combustor for application to industrial steam boilers and power plants. The focus of the test effort is on combustor durability, automatic control of the combustor`s operation, and optimal environmental control of emissions inside the combustor.

  11. DEVELOPMENT AND TESTING OF INDUSTRIAL SCALE, COAL FIRED COMBUSTION SYSTEM, PHASE 3

    SciTech Connect

    Dr. Bert Zauderer

    1999-03-11

    In the second half of calendar year 1998, no work was performed on the present project. The 20 MMBtu/hr combustor-boiler facility was operated for 11 tests, primarily with Coal Tech resources on biomass combustion and gasification. The total test days on the Philadelphia facility to the end of August 1998 was 119. Of these, 36 tests were part of another DOE project on sulfur retention is slag, and 8 were on an in-house biomass combustion effort. The test days on the other project are listed here because they demonstrate the durability of the combustor, which is one of the objectives of the present project. Also, the test work of 1998 revealed for the first time the major potential of this combustor for biomass combustion. These tests are double the 63 tests in the original plan for this project. All key project objectives have been exceeded including combustor durability, automated combustor operation, NO{sub x} emissions as low as 0.07 lb/MMBtu and SO{sub 2} emissions as low as 0.2 lb/MMBtu. In addition, a novel post-combustion NOx control process has been tested on a 37 MW and 100 MW utility boiler. The only effort remaining on this project is facility disassembly and Final Report. However, as part of the commercialization effort for this combustor technology, Coal Tech is planning to maintain the combustor facility in an operational mode at least through 2001. Coal Tech is focusing on utilizing the combustor with biomass fuels in very low cost, small (1 MW nominal) steam power plants. Worldwide application of this technology would have a major impact in reduction of greenhouse gas emissions because the energy content of agricultural biomass is equal to the energy content of the USA's annual coal production.

  12. Development and Testing of Industrial Scale Coal-Fired Combustion System, Phase 3

    SciTech Connect

    Zauderer, Bert

    1997-02-27

    In the fourth quarter of calendar year 1996, 15 days of combust-boiler tests were performed, including 10 days of tests on a parallel DOE sponsored project on sulfur retention in a slagging combustor. Between tests, modifications and improvements that were indicated by these tests were implemented. This brings the total number of test days to the end of December in the task 5 effort to 57, increased to 65 as of the date of this Report, 1/27/97. This compares with a total of 63 test days needed to complete the task 5 test effort, and it completes the number of tests days required to meet the task 5 project plan. The key project objectives of the areas of combustor performance and environmental performance have been exceeded. With sorbent injection in the combustion gas train, NOX emissions as low as 0.07 lb/MMBtu and S02 emissions as low as 0.2 lb/MMBtu have been measured in tests in this quarter. Work in the next quarter will focus on even greater reductions in environmental emissions. Also tests are planned with coals other than the Eastern US bituminous coals tested in this project. For example, it is planned to tests Indian coals whose ash concentration is in the 40 {approx} 0 range.

  13. Development and Testing of Industrial Scale, Coal-Fired Combustion System: Phase 3.

    SciTech Connect

    Zauderer, B.

    1997-04-21

    In the first quarter of calendar year 1997, 17 days of combustor- boiler tests were performed, including one day of tests on a parallel DOE sponsored project on sulfur retention in a slagging combustor. Between tests, modifications and improvements that were indicated by these tests were implemented. This brings the total number of test days required to meet the task 5 project plan. The key project objectives in the areas of combustor performance and environmental performance have been exceeded. With sorbent injection in the combustion gas train, NO{sub x} emissions as low as 0.07 lb/MMBtu and SO{sub 2} emissions as low as 0.2 lb/MMBtu have been measured in tests in this quarter. Tests in the present quarter have resulted in further optimizing the sorbent injection and NO{sub x} control processes. A very important milestone in this quarter was two successful combustor tests on a very high ash (37%) Indian coal. Work in the next quarter will focus on commercialization of the combustor- boiler system. In addition, further tests of the NO{sub x} and SO{sub 2} control process and on the Indian coal will be performed.

  14. DEVELOPMENT AND TESTING OF INDUSTRIAL SCALE, COAL FIRED COMBUSTION SYSTEM, PHASE 3

    SciTech Connect

    Dr. Bert Zauderer

    1998-07-08

    In the second quarter of calendar year 1998, no work was performed on the present project. The 20 MMBtu/hr combustor-boiler facility was not operated during this period. The total test days on the Philadelphia facility to the end of June 1998 remained at 108 as in the previous quarter. Of these, 34 tests were part of the other DOE project. The test days on the other project are listed here because they demonstrate the durability of the combustor, which is one of the objectives of the present project. As noted previously, this exceeds the planned 63 test days for this project. All key project objectives have been exceeded including combustor durability, automated combustor operation, NO{sub x} emissions as low as 0.07 lb/MMBtu and SO{sub 2} emissions as low as 0.2 lb/MMBtu. In addition, a novel post-combustion NO{sub x} control process has been tested on a 37 MW and 100 MW utility boiler. Any further tests will depend on the results of evaluations of current and prior tests. The only effort remaining on this project is facility disassembly and Final Report. Also, as part of the commercialization effort for this combustor technology, Coal Tech is developing alternative designs of the combustor that allow its fabrication as substantially reduced costs from the present unit.

  15. Development and testing of industrial scale, coal-fire combustion system: phase 3

    SciTech Connect

    Zauderer, Dr. Bert

    1997-08-15

    In the second quarter of calendar year 1997, 9 days of combustor- boiler tests were performed, including 3 days of tests on a parallel DOE sponsored project on sulfur retention in a slagging combustor. Between tests, modifications and improvements that were indicated by these tests were implemented. This brings the total number of test days to the end of June 1997 in the task 5 effort to 83 days. This compares with a total of 63 test days needed to complete the task 5 test effort, and the number of tests days required to meet the task 5 project plan have been completed. The key project objectives in the areas of combustor performance and environmental performance have been exceeded. With sorbent injection in the combustion gas train, NO{sub x} emissions as low as 0.07 lb/MMBtu and SO{sub 2} emissions as low as 0.2 lb/MMBtu have been measured in tests in the previous quarter. The emphasis of tests in the present quarter have been on further optimizing post-combustion sorbent injection for SO{sub 2} and NO{sub x} control processes, with most of the test effort focused on the NO{sub x} control process. Many factors which control the NO{sub x} reduction were identified in tests on the 20 MMBtu/hr combustor-boiler. Another very important milestone in this quarter was the successful test of this Coal Tech post combustion NO{sub x} control process on a 100 MW utility boiler, where in a preliminary test 25% NO{sub x} reduction was measured.

  16. Coal conversion products Industrial applications

    NASA Technical Reports Server (NTRS)

    Warren, D.; Dunkin, J.

    1980-01-01

    The synfuels economic evaluation model was utilized to analyze cost and product economics of the TVA coal conversion facilities. It is concluded that; (1) moderate yearly future escalations ( 6%) in current natural gas prices will result in medium-Btu gas becoming competitive with natural gas at the plant boundary; (2) utilizing DRI price projections, the alternate synfuel products, except for electricity, will be competitive with their counterparts; (3) central site fuel cell generation of electricity, utilizing MBG, is economically less attractive than the other synthetic fuels, given projected price rises in electricity produced by other means; and (4) because of estimated northern Alabama synfuels market demands, existing conventional fuels, infrastructure and industrial synfuels retrofit problems, a diversity of transportable synfuels products should be produced by the conversion facility.

  17. Development & testing of industrial scale, coal fired combustion system, phase 3. Eighth quarterly technical progress report, 1 October, 1993--31 December, 1993

    SciTech Connect

    Zauderer, B.

    1994-01-31

    The primary objective of the present Phase 3 effort is to perform the final testing at a 20 MMBtu/hr commercial scale of an air cooled, slagging coal combustor for application to industrial steam boilers and power plants. The focus of the test effort will be on combustor durability, automatic control of the combustor`s operation, and optimum environmental control of emissions inside the combustor. In connection with the latter, the goal is to achieve 0.4 lb/MMBtu of SO{sub 2} emissions, 0.2 lb/MMBtu of NO{sub x} emissions, and 0.02 lb particulates/MMBtu. Meeting the particulate goal will require the use of a baghouse or electrostatic precipitator to augment the nominal slag retention in the combustor. The NO{sub x} emission goal will require a modest improvement over maximum reduction achieved to date in the combustor to a level of 0.26 lb/MMBtu. To reach the SO{sub 2} emissions goal may require a combination of sorbent injection inside the combustor and sorbent injection inside the boiler, especially in high (>3.5%) sulfur coals. Prior to the initiation of the project, SO{sub 2} levels as low as 0.6 lb/MMBtu, equal to 81% reduction in 2% sulfur coals, were measured with boiler injection of calcium hydrate. The final objective is to define suitable commercial power or steam generating systems to which the use of the air cooled combustor offers significant technical and economic benefits. In implementing this objective both simple steam generation and combined gas turbine-steam generation systems will be considered.

  18. Industrial unionism and the Oklahoma coal industry, 1870-1935

    SciTech Connect

    Sewall, S.L.

    1992-01-01

    This study traces the development of industrial unionism in Oklahoma's coal industry from the beginnings of the industry in 1870 to its decline in 1935. Chapter topics include the early years of the coal industry, life in the coal towns, and the series of strikes that occurred from 1894 to 1932. The study draws from both labor and management materials, but also from primary sources that reflect the role of both the state and federal governments during strikes. The study also utilizes the newspapers of the coal towns. They are a bountiful source on life in Oklahoma's coal towns. Study concludes that Oklahoma's coal towns were a perfect breeding ground for industrial unionism. Working in the most dangerous mines in the United States, the miners of Oklahoma turned to unionism in their efforts to improve working conditions and to secure a living wage. Above ground, the miners battled to break the company towns system. There the union achieved success in eliminating the company store and company housing, the two principal components of the company town system. At the same time, the miners created a union culture under which miners of all nationalities were welcome.

  19. Commercial scale gasification test with Kentucky coal

    SciTech Connect

    Roeger, A.; Jones, J.E.

    1984-03-01

    The paper describes in some detail the coal testing programme carried out by Tri-State Synfuels. One of the major elements in the programme was a commercial-scale gasification test with Kentucky 9 coal in a Lurgi dry-bottom gasifier. This was carried out at the Sasol One plant in Sasolburg, S. Africa, in 1981. Other parts of the programme included coal selection, characterisation, stockpile weatherability, corrosion testing, by-product characterisation and waste water treatability.

  20. Research on the competitiveness and development strategy of china's modern coal chemical industry

    NASA Astrophysics Data System (ADS)

    Wang, Q.; Han, Y. J.; Yu, Z. F.

    2016-08-01

    China's modern coal chemical industry has grown into a certain scale after over a decade of development, and remarkable progress has been made in key technologies. But as oil price collapsed since 2015, the economic benefit of the industry also slumped, with loud controversies in China over the necessity of modern coal chemical industry. The research believes that the modern coal chemical industry plays a positive role in the clean and sustainable exploitation of coal in China. It makes profit when oil price is no lower than 60/bbl, and outperforms petrochemical in terms of cost effectiveness when the price is between 60/bbl and 80/bbl. Given the low oil price and challenges posed by environmental protection and water restraints, we suggest that the state announce a guideline quickly, with adjusted tax policies and an encouragement to technological innovation, so that the modern coal chemical industry in China can grow sound and stable.

  1. Development and testing of an industrial scale coal fired slagging combustion system, Phase 3. Task 2.1, Preliminary systems test plan

    SciTech Connect

    Not Available

    1992-09-11

    The planned effort for the task 2 tests has four major objectives. They are computer controlled combustor operation, optimization of SO2 reduction, combustor materials durability, and testing focused on application to industrial coal fired boilers. Several major advances in the combustor development have occurred since this original plan was proposed in 1991. Some of these advances occurred in tests performed in a project that was completed in June 1992, while others occurred during the design and shakedown tests of equipment that was installed in task I of this project. Therefore, the present test plan is based on the current status of the combustor technology, and it differs somewhat from the preliminary test plan that was prepared in April 1992. Depending on the results in the early tests in this task, further test plan modifications may be required. However, the general objectives will most probably remain unchanged.

  2. Laboratory scale separation of coal macerals

    SciTech Connect

    Dyrkacz, G.R.; Bloomquist, C.A.A.; Horwitz, E.P.

    1981-01-01

    A laboratory scale procedure for separation of the maceral constituents of coal has been developed. This procedure is a modification and scale-up of our earlier density gradient centrifugation method. The technique enables us to separate larger quantities and to obtain higher density resoltuions of individual coal macerals than was previously possible. The procedure involves an intiial sink-float separation on finely ground chemically demineralized coal using a high speed centrifuge to obtain large quantities of single maceral groups (i.e., exinite, vitrinite, or inertinite). The maceral concentrate, 15 to 20 g in quantity, rather than the entire coal serves as the feed for the DGC separation. Efforts to apply continuous centrifugation techniques as an alternative to the sink-float separation to concentrate maceral groups were only partially sucessful. 8 figures, 3 tables.

  3. Development and testing of industrial scale, coal fired combustion system, Phase 3. Fifth quarterly technical progress report, January 1, 1993--March 31, 1993

    SciTech Connect

    Zauderer, B.

    1993-05-17

    In the present reporting period, the first quarter of calendar year 1993, the effort was divided between Task 2. ``Pre Systems Tests`` and Task 4 ``Economics and Commercialization Plan.`` A major part of the task 2 effort was devoted converting the nozzle from adiabatic to air cooted operation. This conversion will allow immediate implementation of the longer duration task 3.2 tests after the completion of the task 2 tests. Therefore, a significant pan of the exit nozzle conversion effort is also part of task 3.1, ``Combustor Refurbishment.`` In task 1 the only activity remaining is to receive the results of the BYU combustion modeling. The results are anticipated this Spring. One of the three remaining tests in task 2 was implemented in late January under freezing weather and snow conditions. Ice plugged the coal feed lines and stack scrubber water outlet and ice jammed and damaged the coal metering auger. While these lines were thawed, the combustor was fired with oil. The coal used in this test contained fine fibrous tramp material which passed through the two tramp material retaining screens and eventually plugged several of the coal feed lines to the combustor. This cut the planned coal feed rate in half. As a result it was decided for the next test to increase the number of coal injection ports by 50% in order to provide excess capacity in the pneumatic feed feed. This will allow continued operation even in the presence of fine tramp material in the coal.

  4. Elevation (typical EBT Coal Hopper Car) with scale. 3 Bay ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Elevation (typical EBT Coal Hopper Car) with scale. 3 Bay Steel Hopper Car with side extensions raising coal carrying capacity to 80,000 pounds. Note cars on either side lack extensions limiting their coal capacity to 70,000 pounds - East Broad Top Railroad & Coal Company, State Route 994, West of U.S. Route 522, Rockhill Furnace, Huntingdon County, PA

  5. Advanced coal-fueled industrial cogeneration gas turbine system

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; When, C.S.

    1992-06-01

    This report covers the activity during the period from 2 June 1991 to 1 June 1992. The major areas of work include: the combustor sub-scale and full size testing, cleanup, coal fuel specification and processing, the Hot End Simulation rig and design of the engine parts required for use with the coal-fueled combustor island. To date Solar has demonstrated: Stable and efficient combustion burning coal-water mixtures using the Two Stage Slagging Combustor; Molten slag removal of over 97% using the slagging primary and the particulate removal impact separator; and on-site preparation of CWM is feasible. During the past year the following tasks were completed: The feasibility of on-site CWM preparation was demonstrated on the subscale TSSC. A water-cooled impactor was evaluated on the subscale TSSC; three tests were completed on the full size TSSC, the last one incorporating the PRIS; a total of 27 hours of operation on CWM at design temperature were accumulated using candle filters supplied by Refraction through Industrial Pump Filter; a target fuel specification was established and a fuel cost model developed which can identify sensitivities of specification parameters; analyses of the effects of slag on refractory materials were conducted; and modifications continued on the Hot End Simulation Rig to allow extended test times.

  6. Development and testing of industrial scale, coal fired combustion system, Phase 3. Fourth quarterly technical progress report, October 1, 1992--December 31, 1992

    SciTech Connect

    Zauderer, B.

    1993-02-15

    A major part of the work in this quarter was on the combustor tests in task 2. Three of the six planned tests in this task were completed. The first two were parametric tests of nominal one shift, (8 hour) duration on coal. Due to failure of the UV detector in the first test only several hours of coal fired operation were completed. In the second test, coal fired operation continued for the planned one shift until the 4 ton coal bin was empty. After reviewing this work with DOE, it was decided to focus the remaining test on longer duration operation with each test at one optimum condition. The third test was planned for two shift coal fired operation. Due to a problem with the pilot gas ignitor, combustion was delayed by 5 hours from 7 AM to Noon. As a result coal fired operation was limited to one shift between 3 PM and 11 PM. Throughout this period the combustor remained at one fixed condition with the use of computer control. Results for these three tests are presented in this report. Most of the work on the task 4 design and cost of a 20 MW combined gas-steam turbine power plant using the air cooled combustor was completed in the previous quarter. The results obtained by the A/E subcontractor on the installation desip and cost were evaluated in the present quarter and they are summarized in this report.

  7. Burlington industries' program proves worth of shift to coal

    SciTech Connect

    Schwieger, R.G.; O'Keefe, W.

    1981-11-01

    It is shown how reduction in both fuel cost and energy consumption comes from corporate planning, local initiative, skilled operation, and constant followup. Phased conversion to solid fuel has paid off for the company. Burlington Industries energy-management objectives, diversification of the corporation, and return to coal in three phases are described. Coal sampling, coal handling, steam generation, pollution control, and the training program are described.

  8. Environmental and industrial policy study on converting coal into city gas in China

    SciTech Connect

    Qu, D.; Chen, Y.; Teng, T.

    1994-12-31

    Because coal firing directly causes serious pollution, developing city gas has become inevitable trend in China. In this paper, large scale city gas projected and revamping medium and small scale ammonia plants are evaluated and the principle of environmental and industrial policy are proposed through typical technical and economic analysis.

  9. Development and testing of industrial scale coal fired combustion systems, Phase 3. Sixth quarterly technical progress report, April 1, 1993--June 30, 1993

    SciTech Connect

    Zauderer, B.

    1993-09-22

    The most significant effort in the quarter was the completion of the conversion of the exit nozzle from adiabatic operation to air cooled operation. This conversion was implemented midway in the task 2 test effort, and the final two tests in task 2 were with the cooled nozzle. It performed as per design. The second significant result was the successful implementation of a computer controlled combustor wall cooling procedure. The hot side combustor liner temperature can now be maintained within a narrow range of less than 5OF at the nominal wall temperature of 2000F. This is an essential requirement for long term durability of the combustor wall. The first tests with the computer control system were implemented in June 1993. A third development in this period was the decision to replace the coal feeder that had been in use since coal fired operation began in late 1987. Since that time, this commercial device has been modified numerous times in order to achieve uniform coal feed. Uniform feed was achieved in 1991. However, the feeder operation was not sufficiently reliable for commercial use. The new feeder has the same design as the sorbent feeders that have been successfully used since 1987. This design has much better speed control and it can be rapidly restarted when the feed auger becomes jammed with tramp material. The last task 2 test was a long duration coal fired test with almost 12 hours of coal fired operation until the 4 ton coal bin was empty. It was the longest coal firing period of the task 2 tests. The exit nozzle cooling maintained the wall temperature in the desired operating range.

  10. [Occupational fitness of workers in coal mining industry].

    PubMed

    Ismailova, A A; Musina, A A

    2006-01-01

    Specified criteria of occupational fitness are adequate for optimizing material expenses within the system "human-machine" and during occupational training for work in extreme conditions of coal industry.

  11. Full-scale and bench-scale testing of a coal-fueled gas turbine system

    SciTech Connect

    Roberts, P.B.; LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1992-01-01

    Components for a coal-fueled industrial gas turbine were developed and tested at both benchscale and full-scale. The components included a two stage slagging combustor, a particulate rejection impact separator (PRIS), and a secondary particulate filter. The Integrated Bench Scale Test Facility (IBSTF) was used for the filter tests ana some of the PRIS testing. Full-scale combustor testing has been carried-out both with and without the PRIS. Bench-scale testing has included evaluating the feasibility of on-site CWM preparation, developing a water-cooled impactor and an extended run with new secondary candle filters.

  12. Full-scale and bench-scale testing of a coal-fueled gas turbine system

    SciTech Connect

    Roberts, P.B.; LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1992-12-31

    Components for a coal-fueled industrial gas turbine were developed and tested at both benchscale and full-scale. The components included a two stage slagging combustor, a particulate rejection impact separator (PRIS), and a secondary particulate filter. The Integrated Bench Scale Test Facility (IBSTF) was used for the filter tests ana some of the PRIS testing. Full-scale combustor testing has been carried-out both with and without the PRIS. Bench-scale testing has included evaluating the feasibility of on-site CWM preparation, developing a water-cooled impactor and an extended run with new secondary candle filters.

  13. Development and Testing of Industrial Scale, Coal Fired Combustion System, Phase 3: Twentieth quarterly technical progress report, October 1-December 31, 1996

    SciTech Connect

    Zauderer, Bert

    1997-02-27

    In the fourth quarter of calendar year 1996, 15 days of combust boiler tests were performed, including 10 days of tests on a parallel DOE sponsored project on sulfur retention in a slagging combustor. Between tests, modifications and improvements that were indicated by these tests were implemented. This brings the total number of test days to the end of December in the task 5 effort to 57, increased to 65 as of the date of this Report, 1/27/97. This compares with a total of 63 test days needed to complete the task 5 test effort, and it completes the number of tests days required to meet the task 5 project plan. The key project objectives of the areas of combustor performance and environmental performance have been exceeded. With sorbent injection in the combustion gas train, NO{sub x} emissions as low as 0.07 lb/MMBtu and SO{sub 2} emissions as low as 0.2 lb/MMBtu have been measured in tests in this quarter. Work in the next quarter will focus on even greater reductions in environmental emissions. Also tests are planned with coals other than the Eastern U.S. bituminous coals tested in this project. For example, it is planned to tests Indian coals whose ash concentration is in the 40% range.

  14. Preliminary assessment of coal-based industrial energy systems

    SciTech Connect

    Not Available

    1980-01-01

    This report presents the results of a study, performed by Mittelhauser Corp. and Resource Engineering, Inc. to identify the potential economic, environmental, and energy impacts of possible New Source Performance Standards for industrial steam generators on the use of coal and coal-derived fuels. A systems-level approach was used to take mine-mouth coal and produce a given quantity of heat input to a new boiler at an existing Chicago industrial-plant site. The technologies studied included post-combustion clean-up, atmospheric fluidized-bed combustion, solvent-refined coal liquids, substitute natural gas, and low-Btu gas. Capital and operating costs were prepared on a mid-1985 basis from a consistent set of economic guidelines. The cases studied were evaluated using three levels of air emission controls, two coals, two boiler sizes, and two operating factors. Only those combinations considered likely to make a significant impact on the 1985 boiler population were considered. The conclusions drawn in the report are that the most attractive applications of coal technology are atmospheric fluidized-bed combustion and post-combustion clean-up. Solvent-refined coal and probably substitute natural gas become competitive for the smaller boiler applications. Coal-derived low-Btu gas was found not to be a competitive boiler fuel at the sizes studied. It is recommended that more cases be studied to broaden the applicability of these results.

  15. Commissioning an Engineering Scale Coal Gasifier

    SciTech Connect

    Reid, Douglas J.; Bearden, Mark D.; Cabe, James E.

    2010-07-01

    This report explains the development, commissioning, and testing of an engineering scale slagging coal gasifier at PNNL. The initial objective of this project was to commission the gasifier with zero safety incidents. The commissioning work was primarily an empirical study that required an engineering design approach. After bringing the gasifier on-line, tests were conducted to assess the impact of various operating parameters on the synthesis gas (syngas) product composition. The long-term intent of this project is to produce syngas product for use by internal Pacific Northwest National Laboratory (PNNL) researchers in catalyst, materials, and instrumentation development. Future work on the project will focus on improving the reliability and performance of the gasifier, with a goal of continuous operation for greater than 4 hours using coal feedstock. In addition, alternate designs that allow for increased flexibility regarding the fuel sources that can be used for syngas production is desired. Continued modifications to the fuel feed system will be pursued to address these goals. Alternative feed mechanisms such as a coal/methanol slurry are being considered.

  16. Digging Deeper: Crisis Management in the Coal Industry

    ERIC Educational Resources Information Center

    Miller, Barbara M.; Horsley, J. Suzanne

    2009-01-01

    This study explores crisis management/communication practices within the coal industry through the lens of high reliability organization (HRO) concepts and sensemaking theory. In-depth interviews with industry executives and an analysis of an emergency procedures manual were used to provide an exploratory examination of the status of crisis…

  17. Development and testing of industrial scale, coal fired combustion system, Phase 3. Second quarterly technical progress report, April 1, 1992--June 30, 1992

    SciTech Connect

    Zauderer, B.

    1992-07-10

    In the second quarter of calendar year 1992, work continued on Task 1.1. ``DESIGN MODIFICATIONS TO THE 20 MMBTU/HR AIR COOLED COMBUSTOR AND BOILER COMPONENTS``. This consisted of specifying and designing the changes needed to prepare the 20 MMBtu/hr air cooled combustor at the Tampella boiler house site in Williamsport, PA. In depth review of the technical status of the combustor showed that no major design changes were necessary in order to implement the effort of task 2 testing and part of the task 3 testing. Among the major planned changes eliminated were replacement of the inlet swirl air flow section of the combustor. The major changes undertaken were to improve the coal and sorbent injection into the combustor; refurbishing various components and controls systems such as the stack particle scrubber and temperature probes; automating key elements of the combustor, such as the slag tap, upgrading the computer control and automatic data acquisition; and upgrading the long duration capability of the exit nozzle. To support this effort advanced analytical modeling was used to provide guidance for the design changes. A multi-dimensional computer code was used to analyze the combustor performance for different combustor stoichiometries and geometry. A heat transfer analysis of the exit nozzle was performed to determine the best method of adding cooling capacity to the exit nozzle to allow its use for multi-day, round-the-clock coal testing.

  18. Development and testing of industrial scale, coal fired combustion system, Phase 3. Sixteenth quarterly technical progress report, October 1--December 31, 1995

    SciTech Connect

    Zauderer, B.

    1996-01-03

    In the fourth quarter of calendar year 1995 the installation and checkout of the 20 MMBtu/hr combustor and auxiliary equipment in Philadelphia was completed. The task 5, Site Demonstration Testing, combustor-boiler tests on gas, oil, and coal were initiated. The task 5 effort involves testing the combustor over extended periods under conditions that fully simulate commercial operation and that meet the combustion and environmental specifications for this project. To meet this project objective within the current work scope requires up to 500 hours of testing. The focus of this testing will be on the component and environmental performance of combustor, boiler, coal preparation and feeding, and the stack gas equipment. The facility can be converted to a 500 kW power plant by the addition of a steam turbine, condenser, and cooling tower. However, this added effort is beyond the current work scope and its implementation will depend on recovering the added costs by placing the steam production from the boiler to beneficial use. During the present quarterly reporting period, all the components needed to implement the initial 100 hours of testing under task 5 were installed at the test site, and checkout of this equipment was performed. Since the present installation contained substantial improvements and simplifications to all sub-systems that had been used in the Williamsport facility, each component and sub-system had to be tested individually.

  19. Coal industry taxes: state-by-state guide

    SciTech Connect

    Sammons, D.

    1981-01-01

    This book describes the taxes levied on coal mining industries by each of the 26 coal-producing states in the US. Described are severance taxes, charter fees, permit fees, franchise taxes, income taxes, property taxes, sales taxes, use taxes, unemployment compensations, workmens compensation, utility taxes, inspection fees, motor fuel taxes, motor vehicle use taxes, message tax, local taxes, etc. The appendices contain the results of a study to translate the tax burden imposed by 21 states into a per-ton figure and a reprint of the US Supreme Court decision upholding Montana's 30% severance tax on coal. (CKK)

  20. Coal.

    ERIC Educational Resources Information Center

    Brant, Russell A.; Glass, Gary B.

    1983-01-01

    Principle work of 23 state geological surveys is summarized. Work includes mapping/estimating coal resources, centralizing data in National Coal Resources Data System through cooperative programs, exploration drilling, and others. Comments on U.S. Geological Survey activities, coal-related conferences/meetings, and industry research activities are…

  1. Respirable dust from lignite coal in the Victorian power industry

    SciTech Connect

    Lazarus, R.

    1983-01-01

    The results from a 12-month program of static sampling for respirable dust in various work sites of the Victorian power industry are presented. Lignite coal is the major source of dust in this industry. The data appear to be nearly lognormal in distribution and are similar in magnitude to levels reported from North American surface mines and surface work sites. Average 8-hour, time-weighted-average dust concentrations of 0.3 mg/m/sup 3/ (SD = 0.3) were found in open areas. In enclosed coal handling areas, average concentrations of 0.7 mg/m/sup 3/ (SD = 0.6) were found.

  2. Development and testing of industrial scale, coal-fired combustion system, Phase 3. Seventeenth quarterly technical progress report, January 1, 1996--March 31, 1996

    SciTech Connect

    Zauderer, B.

    1996-04-07

    In the first quarter of calendar year 1996, 9 days of combust-boiler tests were performed. Between these tests, modifications and improvements that were indicated by these tests were implemented. In January and early February, the modifications and installations indicated by the 6 days of testing in December 1995 were implemented. This was followed by 6 additional consecutive test days in mid- February. This was in turn followed by additional modifications, followed by a series of 3 one day, coal fired tests at end of March. These latter tests were the first ones in which slagging conditions were achieved in the combustor. The maximum thermal input was 13 MMBtu/hr, which equals two-thirds of the rated boiler heat input. The measured thermal, combustion, and slagging performance achieved in the combustor was superior to that achieved in the final series of tests conducted in Williamsport in 1993. The combustor-boiler facility is now ready for implementation of the task 5 site demonstration.

  3. Development and testing of industrial scale, coal fired combustion system, Phase 3. Thirteenth quarterly technical progress report, January 1, 1995--March 31, 1995

    SciTech Connect

    Zauderer, B.

    1995-04-18

    The present report is a summary of the activities in February and March 1995. The primary activities during these two months was to monitor the fabricator of the combustor extension in order to assure completion of the work according to the design, to procure the additional components needed to install the combustor-boiler system at the Arsenal test site, and on initial installation of auxiliary components at the site. Welding of the combustor extension major sections began in mid-January. However, the quality of the welds was poor and a number of non-critical flanges were warped during welding. As a result the fabricator replaced the welders and the quality assurance personnel in early February. To assure that the welded sections would properly mate with the existing combustor, Coal Tech personnel regularly visited the fabricator until the end of March. The combustor extension section was completed and delivered to the Arsenal at the end of March. To meet the Philadelphia particulate emission standard of 0.06 lb/MMBtu a baghouse was procured in February. Competitive procurement of the stack ducting from the boiler to the baghouse and to the atmosphere was initiated. Pneumatically controlled valves for the combustor extension section`s air cooling sub-system were ordered and delivered.

  4. Development and Testing of Industrial Scale, Coal-Fired Combustin System, Phase 3. Twenty second technical progress report, April 1-June 30, 1997

    SciTech Connect

    Zauderer, B., Dr.

    1997-09-30

    In the second quarter of calendar year 1997, 9 days of combustor- boiler tests were performed, including 3 days of tests on a parallel DOE sponsored project on sulfur retention in a slagging combustor. Between tests, modifications and improvements that were indicated by these tests were implemented. This brings the total number of test days to the end of June 1997 in the task 5 effort to 83 days. This compares with a total of 63 test days needed to complete the task 5 test effort, and the number of tests days required to meet the task 5 project plan have been completed. The key project objectives in the areas of combustor performance and environmental performance have been exceeded. With sorbent injection in the combustion gas train, NO{sub x} emissions as low as 0.07 lb/MMBtu and S0{sub 2} emissions as low as 0.lb/MBtu have been measured in tests in the previous quarter. The emphasis of tests in the present quarter have been on further optimizing post-combustion sorbent injection for S0{sub 2} and NO{sub x} control processes, with most of the test effort focused on the NO{sub x} control process. Many factors which control the NO{sub x} reduction were identified in tests on the 20 MMBtu/hr combustor-boiler. Another very important milestone in this quarter was the successful test of this Coal Tech post combustion NO{sub x} control process on a 100 MAR utility boiler, where in a preliminary test 25% NO{sub x} reduction was measured.

  5. Development and testing of industrial scale, coal fired combustion system, Phase 3. Third quarterly technical progress report, July 1, 1992--September 30, 1992

    SciTech Connect

    Zauderer, B.

    1992-10-17

    In the third quarter of calendar year 1992, work continued on Task l. ``Design, Installation, and Shakedown of the Modifications to the 20 MMBtu/hr Air Cooled Combustor and Boiler Components``. Task 2. ``Preliminary Systems Tests`` and Task 4 ``Economics and Commercialization Plan``. In task 1, the design of the planned modifications were mostly completed. The equipment to implement these modifications was procured, and most of the installation of this equipment was completed. Finally, a series of two shakedown tests was performed to test the operability of these modifications. As previously reported, no modifications to the combustor were made. All the changes were improvements in overall combustor-boiler operation, maintenance and repair of components, and addition of diagnostics. In addition, during shakedown tests of these modifications the need for additional improvements or modifications became apparent, and these were or a-re being implemented. The major improvements focused on coal and sorbent storage, transport, and combustor injection, real time control of ash deposition in the boiler, unproved combustor wall cooling, expanded computer control and diagnostics, and refurbishment of the scrubber and combustor temperature measurements. AD this work has been described in a detailed topical report on task 1, which was recently submitted to DOE, and it will not be repeated here. Instead the focus of this report will be on the analysis of the test results obtained in the two shakedown tests. This work was partly reported in the 7th 8th and 9th monthly reports. An important result of these tests has been the observation of high (over 85%) SO{sub 2} reduction obtained with sorbent injection in the combustor.

  6. Efficient, large scale separation of coal macerals

    SciTech Connect

    Dyrkacz, G.R.; Bloomquist, C.A.A.

    1988-01-01

    The authors believe that the separation of macerals by continuous flow centrifugation offers a simple technique for the large scale separation of macerals. With relatively little cost (/approximately/ $10K), it provides an opportunity for obtaining quite pure maceral fractions. Although they have not completely worked out all the nuances of this separation system, they believe that the problems they have indicated can be minimized to pose only minor inconvenience. It cannot be said that this system completely bypasses the disagreeable tedium or time involved in separating macerals, nor will it by itself overcome the mental inertia required to make maceral separation an accepted necessary fact in fundamental coal science. However, they find their particular brand of continuous flow centrifugation is considerably faster than sink/float separation, can provide a good quality product with even one separation cycle, and permits the handling of more material than a conventional sink/float centrifuge separation.

  7. Managing Scarce Water Resources in China's Coal Power Industry

    NASA Astrophysics Data System (ADS)

    Zhang, Chao; Zhong, Lijin; Fu, Xiaotian; Zhao, Zhongnan

    2016-06-01

    Coal power generation capacity is expanding rapidly in the arid northwest regions in China. Its impact on water resources is attracting growing concerns from policy-makers, researchers, as well as mass media. This paper briefly describes the situation of electricity-water conflict in China and provides a comprehensive review on a variety of water resources management policies in China's coal power industry. These policies range from mandatory regulations to incentive-based instruments, covering water withdrawal standards, technological requirements on water saving, unconventional water resources utilization (such as reclaimed municipal wastewater, seawater, and mine water), water resources fee, and water permit transfer. Implementing these policies jointly is of crucial importance for alleviating the water stress from the expanding coal power industry in China.

  8. Industry Wage Survey: Bituminous Coal, January 1976-March 1981.

    ERIC Educational Resources Information Center

    Bush, Joseph C.

    Production and related workers in the nation's bituminous coal mines averaged $6.94 an hour in January 1976, which represents an increase of 110% since the Bureau of Labor Statistics' 1967 survey in the industry. Over the same period, the Hourly Earnings Index rose by 84% for private nonagricultural workers. Earnings for most of the 128,390…

  9. New petrochemical compositions for use in the coal industry

    SciTech Connect

    D.O. Safieva; E.V. Surov; O.G. Safiev

    2008-12-15

    Various aspects of the use of antifreezing agents in the coal industry are considered. It has been found that, unlike previously proposed compositions, these agents can be prepared based on the products of a single process, the vacuum distillation of fuel oil.

  10. Early opportunities of CO₂ geological storage deployment in coal chemical industry in China

    DOE PAGES

    Wei, Ning; Li, Xiaochun; Liu, Shengnan; ...

    2014-12-31

    Carbon dioxide capture and geological storage (CCS) is regarded as a promising option for climate change mitigation; however, the high capture cost is the major barrier to large-scale deployment of CCS technologies. High-purity CO₂ emission sources can reduce or even avoid the capture requirements and costs. Among these high-purity CO₂ sources, certain coal chemical industry processes are very important, especially in China. In this paper, the basic characteristics of coal chemical industries in China is investigated and analyzed. As of 2013 there were more than 100 coal chemical plants in operation. These emission sources together emit 430 million tons CO₂more » per year, of which about 30% are emit high-purity and pure CO₂ (CO₂ concentration >80% and >98.5% respectively). Four typical source-sink pairs are chosen for techno-economic evaluation, including site screening and selection, source-sink matching, concept design, and economic evaluation. The technical-economic evaluation shows that the levelized cost of a CO₂ capture and aquifer storage project in the coal chemistry industry ranges from 14 USD/t to 17 USD/t CO₂. When a 15USD/t CO₂ tax and 20USD/t for CO₂ sold to EOR are considered, the levelized cost of CCS project are negative, which suggests a benefit from some of these CCS projects. This might provide China early opportunities to deploy and scale-up CCS projects in the near future.« less

  11. Early opportunities of CO₂ geological storage deployment in coal chemical industry in China

    SciTech Connect

    Wei, Ning; Li, Xiaochun; Liu, Shengnan; Dahowski, R. T.; Davidson, C. L.

    2014-12-31

    Carbon dioxide capture and geological storage (CCS) is regarded as a promising option for climate change mitigation; however, the high capture cost is the major barrier to large-scale deployment of CCS technologies. High-purity CO₂ emission sources can reduce or even avoid the capture requirements and costs. Among these high-purity CO₂ sources, certain coal chemical industry processes are very important, especially in China. In this paper, the basic characteristics of coal chemical industries in China is investigated and analyzed. As of 2013 there were more than 100 coal chemical plants in operation. These emission sources together emit 430 million tons CO₂ per year, of which about 30% are emit high-purity and pure CO₂ (CO₂ concentration >80% and >98.5% respectively). Four typical source-sink pairs are chosen for techno-economic evaluation, including site screening and selection, source-sink matching, concept design, and economic evaluation. The technical-economic evaluation shows that the levelized cost of a CO₂ capture and aquifer storage project in the coal chemistry industry ranges from 14 USD/t to 17 USD/t CO₂. When a 15USD/t CO₂ tax and 20USD/t for CO₂ sold to EOR are considered, the levelized cost of CCS project are negative, which suggests a benefit from some of these CCS projects. This might provide China early opportunities to deploy and scale-up CCS projects in the near future.

  12. Development program to support industrial coal gasification. Quarterly report 1

    SciTech Connect

    1982-01-15

    The Development Program to Support Industrial Coal Gasification is on schedule. The efforts have centered on collecting background information and data, planning, and getting the experimental program underway. The three principal objectives in Task I-A were accomplished. The technical literature was reviewed, the coals and binders to be employed were selected, and tests and testing equipment to be used in evaluating agglomerates were developed. The entire Erie Mining facility design was reviewed and a large portion of the fluidized-bed coal gasification plant design was completed. Much of the work in Task I will be experimental. Wafer-briquette and roll-briquette screening tests will be performed. In Task II, work on the fluidized-bed gasification plant design will be completed and work on a plant design involving entrained-flow gasifiers will be initiated.

  13. Coal myths and environmental realities: Industrial fuel-use decisions in a time of change

    SciTech Connect

    Alm, A.L.

    1984-01-01

    This book deals with two inconsistent myths that persistently surround industrial use of coal. The first myth is that the Clean Air Act effectively precludes use of coal; the second, that industrial use of coal will expand rapidly. Through analysing fuel-use decisions actually made by industry, Mr. Alm concludes that environmental quality standards have played a minor role in industrial choice of fuel. Historically, natural gas and oil have been both less costly and more convenient fuels for industry to use.

  14. The coal industry and its industrial relations. Some union/nonunion comparisons

    SciTech Connect

    Hannah, R.; Mangum, G.

    1985-01-01

    This book addresses the following questions: how do product markets and labor markets interact in a labor intensive industry; how can a union whose members once mined 90 percent of the coal and now mines 40 percent, still dominate the industrial relations system of the industry, bargaining for member, nonmember, miners and management; how did a union which came into being to take wages out of competition eventually come to shield prices from competition as well and what is causing the erosion of that power; how can the environmental threats of an industry be compromised with its essential resource role; with all of its traditional markets dead or dying, how coal has survived through electric power generation; and what is the future of the industry.

  15. Continuous bench-scale slurry catalyst testing direct coal liquefaction rawhide sub-bituminous coal

    SciTech Connect

    Bauman, R.F.; Coless, L.A.; Davis, S.M.

    1995-12-31

    In 1992, the Department of Energy (DOE) sponsored research to demonstrate a dispersed catalyst system using a combination of molybdenum and iron precursors for direct coal liquefaction. This dispersed catalyst system was successfully demonstrated using Black Thunder sub-bituminous coal at Wilsonville, Alabama by Southern Electric International, Inc. The DOE sponsored research continues at Exxon Research and Development Laboratories (ERDL). A six month continuous bench-scale program using ERDL`s Recycle Coal Liquefaction Unit (RCLU) is planned, three months in 1994 and three months in 1995. The initial conditions in RCLU reflect experience gained from the Wilsonville facility in their Test Run 263. Rawhide sub-bituminous coal which is similar to the Black Thunder coal tested at Wilsonville was used as the feed coal. A slate of five dispersed catalysts for direct coal liquefaction of Rawhide sub-bituminous coal has been tested. Throughout the experiments, the molybdenum addition rate was held constant at 100 wppm while the iron oxide addition rate was varied from 0.25 to 1.0 weight percent (dry coal basis). This report covers the 1994 operations and accomplishments.

  16. Economics of the coal industry east of the Mississippi, 1973-1982

    USGS Publications Warehouse

    Bhagwat, S.B.

    1987-01-01

    Government regulations on health, safety and environment have been poppular blamed for the declining productivity in U.S. coal mines since 1970. The stagnation in the coal industry east of the Mississippi is alleged to have been caused by this declining productivity and by the growth of cheaper and cleaner coal production west of the Mississippi. Economic evidence suggests, however, that productivity declines were more due to a relative lowering of labor costs in comparison with coal prices and due to work stoppages. The development of western coals fields was spurred by growth in local demand and had only a relatively small impact on coal production east of the Mississippi. Problems of the eastern coal industry are rooted mainly in slow economic growth in eastern U.S. which must be addressed in the long-term interests of the eastern coal industry. ?? 1987.

  17. Respirable dust from lignite coal in the Victorian power industry

    SciTech Connect

    Lazarus, R.

    1983-04-01

    The results of a 12-month programme of static sampling for respirable dust at various work sites of the Victorian power industry are presented. Lignite is the major source of dust. The data appear to be nearly lognormal in distribution and are similar in magnitude to levels reported from North American surface mines and surface work sites. Average 8-hour, time-weighted-average dust concentrations of 0.3 mg/m/sup 3/ were found in open areas. In enclosed coal-handling areas, average concentrations of 0.7 mg/m/sup 3/ were found.

  18. Early opportunities of CO2 geological storage deployment in coal chemical industry in China

    SciTech Connect

    Wei, Ning; Li, Xiaochun; Liu, Shengnan; Dahowski, Robert T.; Davidson, Casie L.

    2014-11-12

    Abstract: Carbon dioxide capture and geological storage (CCS) is regarded as a promising option for climate change mitigation; however, the high capture cost is the major barrier to large-scale deployment of CCS technologies. High-purity CO2 emission sources can reduce or even avoid the capture requirements and costs. Among these high-purity CO2 sources, certain coal chemical industry processes are very important, especially in China. In this paper, the basic characteristics of coal chemical industries in China is investigated and analyzed. As of 2013 there were more than 100 coal chemical plants in operation or in late planning stages. These emission sources together emit 430 million tons CO2 per year, of which about 30% are emit high-purity and pure CO2 (CO2 concentration >80% and >99% respectively).Four typical source-sink pairs are studied by a techno-economic evaluation, including site screening and selection, source-sink matching, concept design, and experienced economic evaluation. The technical-economic evaluation shows that the levelized cost of a CO2 capture and aquifer storage project in the coal chemistry industry ranges from 14 USD/t to 17 USD/t CO2. When a 15USD/t CO2 tax and 15USD/t for CO2 sold to EOR are considered, the levelized cost of CCS project are negative, which suggests a net economic benefit from some of these CCS projects. This might provide China early opportunities to deploy and scale-up CCS projects in the near future.

  19. Microfine coal firing results from a retrofit gas/oil-designed industrial boiler

    SciTech Connect

    Patel, R.; Borio, R.W.; Liljedahl, G.

    1995-11-01

    Under US Department of Energy, Pittsburgh Energy Technology Center (PETC) support, the development of a High Efficiency Advanced Coal Combustor (HEACC) has been in progress since 1987 at the ABB Power Plant Laboratories. The initial work on this concept produced an advanced coal firing system that was capable of firing both water-based and dry pulverized coal in an industrial boiler environment.

  20. Strategy for large scale solubilization of coal-characterization of neurospora protein and gene

    SciTech Connect

    Patel, A.; Chen, Y.P.; Mishra, N.C.

    1995-12-31

    Coal represents an important source of energy. Its utilization for generating energy has been offset by environmental problem that it creates by the release of SOx and NOx, which are major causes of acid rain and deforestation. Some of these problems can be tackled by the use of industrial scrubbers. However, a biotechnological approach to these problems may prove more efficient and environment friendly. We have employed certain genetically characterized fungi for the biosolubilization of coal in order to yield chemicals that can be converted into utilizable energy and can be rendered free of SOx and NOx at the source. Here we describe the purification of a protein which is responsible for the biodegradation of low rank coal both in vivo and in vitro. We also report the characterization of the biochemical nature of the coal derived products obtained after the biosolubilization of coal by this protein in vivo and in, vitro. Identification and characterization of this fungal protein is expected to help the cloning of the gene encoding this protein which is needed to construct a super strain of Neurospora capable of large scale solubilization of coal.

  1. Non traditional uses of coal ash: Steel industry applications

    SciTech Connect

    Hauke, D.

    1997-09-01

    Coal fly ash is used by the steel industry as an insulating cover to retain heat in ladles of molten steel and as a slag foamer in electric arc furnaces (EAFs) to prolong the life of consumable components and to aid extraction of impurities from the molten steel. The fly ashes that are used in the steel industry are generated from stoker boilers and have a relatively wide particle-size distribution. The powder-type materials used by steel mills to insulate ladles of molten metal include rice hull ash, a heat treated montmorillonite clay mineral (calcined clay), a fly ash from a stoker boiler called LadleJacket, and coke breeze. These ladle insulators should be flowable, coarse, and have a wide particle-size distribution. A study to compare the insulating characteristics of ladle insulators, conducted by the American Foundrymen`s Society Cast Metals Institute, indicated that the ladle insulated with LadleJacket exhibited a lower rate of heat loss than either the rice hull ash or calcined clay. To prolong the life of carbon electrodes and refractory in EAFs and to promote extraction of contaminants from the steel, carbon-based ingredients are injected into the slag to cause it to foam. Typically, high-carbon products such as coke breeze (coke fines) are used as slag foamers. A new product called Carbon Plus, which is a coarse, high-carbon fly ash from a coal-fired stoker boiler, is now being used as a slag foamer in the steel industry.

  2. Some Problems of Industrial Scale-Up.

    ERIC Educational Resources Information Center

    Jackson, A. T.

    1985-01-01

    Scientific ideas of the biological laboratory are turned into economic realities in industry only after several problems are solved. Economics of scale, agitation, heat transfer, sterilization of medium and air, product recovery, waste disposal, and future developments are discussed using aerobic respiration as the example in the scale-up…

  3. Development of Affordable, Low-Carbon Hydrogen Supplies at an Industrial Scale

    ERIC Educational Resources Information Center

    Roddy, Dermot J.

    2008-01-01

    An existing industrial hydrogen generation and distribution infrastructure is described, and a number of large-scale investment projects are outlined. All of these projects have the potential to generate significant volumes of low-cost, low-carbon hydrogen. The technologies concerned range from gasification of coal with carbon capture and storage…

  4. Burlington Industries' program proves worth of shift to coal

    SciTech Connect

    Schwieger, R.G.; O'Keefe, W.

    1981-11-01

    This US textile manufacturer started to convert its factories to coal in 1973. Boilers with spreader stokers and travelling grates burn low-sulphur, low-ash coal. Coal delivery and handling, the boilers, and the removal of fly ash from the flue gas are described.

  5. Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1991--June 1992

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; When, C.S.

    1992-06-01

    This report covers the activity during the period from 2 June 1991 to 1 June 1992. The major areas of work include: the combustor sub-scale and full size testing, cleanup, coal fuel specification and processing, the Hot End Simulation rig and design of the engine parts required for use with the coal-fueled combustor island. To date Solar has demonstrated: Stable and efficient combustion burning coal-water mixtures using the Two Stage Slagging Combustor; Molten slag removal of over 97% using the slagging primary and the particulate removal impact separator; and on-site preparation of CWM is feasible. During the past year the following tasks were completed: The feasibility of on-site CWM preparation was demonstrated on the subscale TSSC. A water-cooled impactor was evaluated on the subscale TSSC; three tests were completed on the full size TSSC, the last one incorporating the PRIS; a total of 27 hours of operation on CWM at design temperature were accumulated using candle filters supplied by Refraction through Industrial Pump & Filter; a target fuel specification was established and a fuel cost model developed which can identify sensitivities of specification parameters; analyses of the effects of slag on refractory materials were conducted; and modifications continued on the Hot End Simulation Rig to allow extended test times.

  6. Productivity, job satisfaction, and health and safety in the coal industry: the participatory alternative

    SciTech Connect

    Not Available

    1982-01-01

    This is a conference which presents results and ideas on workplace participation in the coal industry. It discusses the theory of the quality circle groups for developing their own production rates and design goals. It presents the results of different coal company participation in this idea and how to implement this option. Individual topics are entered into the Data Base as separate items.

  7. Effective Communication and Training. A Guide for Workplace Trainers in the Australian Coal Industry.

    ERIC Educational Resources Information Center

    Lukin, Annabelle

    This guide is designed to help workplace trainers in Australia's coal industry improve coal miners' operator and general communication skills through a curriculum that integrates training in language, literacy, and numeracy. The following topics are discussed in the guide's seven sections: the changing workplace (changing work environment;…

  8. Upgrading selected Czech coals for home and industrial heating

    SciTech Connect

    Musich, M.A.; Young, B.C.

    1995-12-31

    The Czech Republic has large coal reserves, particularly brown coal and lignite, and to a lesser extent, bituminous coal. Concurrent with the recent political changes, there has been a reassessment of the role of coal for electrical and heating energy in the future economy, owing to the large dependence on brown coal and lignite and the implementation of more stringent environmental regulations. These coals have a relatively high sulfur content, typically 1-3 wt%, and ash content, leading to significant SO{sub 2} and other gaseous and particulate emissions. Some of the bituminous coals also exhibit high ash content. Against this background, the Energy & Environmental Research Center, on behalf of the U.S. Agency for International Development and the U.S. Department of Energy Office of Fossil Energy, undertook a project on upgrading Czech coals to achieve desired fuel properties. The purpose of the project was to assist the city of Usti nad Labem in Northern Bohemia in developing cost-effective alternatives for reducing environmental emissions from district and home heating systems.

  9. Coal face and stockpile ash analyser for the coal mining industry.

    PubMed

    Borsaru, M; Dixon, R; Rojc, A; Stehle, R; Jecny, Z

    2001-09-01

    A portable nucleonic instrument was developed for the determination of coal ash on the coal face or the surface of coal stockpiles. The instrument employs the backscattered gamma-gamma technique. There are two gamma-ray sources used in this instrument: a 1.1 MBq 133Ba source as the primary source of radiation and a 37 kBq 137Cs for gain stabilization. The instrument is commercially available.

  10. Combustion characterization of coals for industrial applications. Final technical report, January 1, 1981-May 29, 1985

    SciTech Connect

    Nsakala, N.; Patel, R.L.; Lao, T.C.

    1985-03-01

    In-depth fundamental information was obtained from a two-inch inner diameter laminar flow reactor referred to as the Drop Tube Furnace System (DTFS). This information consists of the following: (1) pyrolysis kinetic characteristics of four coals of various rank (Texas lignite, Montana subbituminous, Alabama high volatile bituminous, and Pennsylvania anthracite); and (2) combustion kinetic studies of chars produced from the foregoing parent coals. A number of standard ASTM and special in-house bench scale tests were also performed on the coals and chars prepared therefrom to characterize their physicochemical properties. The pilot scale (500,000 Btu/hr) Controlled Mixing History Furnace (CMHF) was used to determine the effect of staged combustion on NO/sub x/ emissions control from an overall combustion performance of the Alabama high volatile bituminous coal. The quantitative fundamental data developed from this study indicate significant differences in coal/char chemical, physical, and reactivity characteristics, which should be useful to those interested in modeling coal combustion and pyrolysis processes. These results underscore the fact that coal selection is one of the keys governing a successful coal conversion/utilization process. The combustion kinetic information obtained on the high volatile bituminous coal has been used in conjunction with combustion engineering's proprietary mathematical models to predict the combustion performance of this coal in the Controlled Mixing History Furnace. Comparison of the predicted data with the experimental results shows a virtually one-to-one scale-up from the DTFS to the CMHF. These data should provide vital information to designers in the area of carbon burnout and NO/sub x/ reduction for large scale coal utilization applications. 31 refs., 28 figs., 17 tabs.

  11. Ash characterization in laboratory-scale oxy-coal combustor

    EPA Science Inventory

    Oxygen enriched coal (oxy-coal) combustion is a developing technology. During oxy-coal combustion, combustion air is separated and the coal is burned in a mixture of oxygen and recycled flue gas. The resulting effluent must be further processed before the C02 can be compressed, t...

  12. Advanced coal-fueled industrial cogeneration gas turbine system

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  13. Coal combustion: Science and technology of industrial and utility applications

    SciTech Connect

    Junkai, F.

    1988-01-01

    This reference source offers material on theoretical research (including mathematical modeling, low NO/sub x/ combustion, and studies of sulfur), applications of the newest technologies, and actual experience of low-grade coal combustion.

  14. Do coal consumption and industrial development increase environmental degradation in China and India?

    PubMed

    Shahbaz, Muhammad; Farhani, Sahbi; Ozturk, Ilhan

    2015-03-01

    The present study is aimed to explore the relationship between coal consumption, industrial production, and CO2 emissions in China and India for the period of 1971-2011. The structural break unit root test and cointegrating approach have been applied. The direction of causal relationship between the variables is investigated by applying the VECM Granger causality test. Our results validate the presence of cointegration among the series in both countries. Our results also validate the existence of inverted U-shaped curve between industrial production and CO2 emissions for India, but for China, it is a U-shaped relationship. Coal consumption adds in CO2 emissions. The causality analysis reveals that industrial production and coal consumption Granger cause CO2 emissions in India. In the case of China, the feedback effect exists between coal consumption and CO2 emissions. Due to the importance of coal in China and India, any reduction in coal consumption will negatively affect their industrial value added as well as economic growth.

  15. Estimates and Predictions of Coal Workers’ Pneumoconiosis Cases among Redeployed Coal Workers of the Fuxin Mining Industry Group in China: A Historical Cohort Study

    PubMed Central

    Han, Bing; Liu, Hongbo; Zhai, Guojiang; Wang, Qun; Liang, Jie; Zhang, Mengcang; Cui, Kai; Shen, Fuhai; Yi, Hongbo; Li, Yuting; Zhai, Yuhan; Sheng, Yang; Chen, Jie

    2016-01-01

    This research was aimed at estimating possible Coal workers’ pneumoconiosis (CWP) cases as of 2012, and predicting future CWP cases among redeployed coal workers from the Fuxin Mining Industry Group. This study provided the scientific basis for regulations on CWP screening and diagnosis and labor insurance policies for redeployed coal workers of resource-exhausted mines. The study cohort included 19,116 coal workers. The cumulative incidence of CWP was calculated by the life-table method. Possible CWP cases by occupational category were estimated through the average annual incidence rate of CWP and males’ life expectancy. It was estimated that 141 redeployed coal workers might have suffered from CWP as of 2012, and 221 redeployed coal workers could suffer from CWP in the future. It is crucial to establish a set of feasible and affordable regulations on CWP screening and diagnosis as well as labor insurance policies for redeployed coal workers of resource-exhausted coal mines in China. PMID:26845337

  16. Estimates and Predictions of Coal Workers' Pneumoconiosis Cases among Redeployed Coal Workers of the Fuxin Mining Industry Group in China: A Historical Cohort Study.

    PubMed

    Han, Bing; Liu, Hongbo; Zhai, Guojiang; Wang, Qun; Liang, Jie; Zhang, Mengcang; Cui, Kai; Shen, Fuhai; Yi, Hongbo; Li, Yuting; Zhai, Yuhan; Sheng, Yang; Chen, Jie

    2016-01-01

    This research was aimed at estimating possible Coal workers' pneumoconiosis (CWP) cases as of 2012, and predicting future CWP cases among redeployed coal workers from the Fuxin Mining Industry Group. This study provided the scientific basis for regulations on CWP screening and diagnosis and labor insurance policies for redeployed coal workers of resource-exhausted mines. The study cohort included 19,116 coal workers. The cumulative incidence of CWP was calculated by the life-table method. Possible CWP cases by occupational category were estimated through the average annual incidence rate of CWP and males' life expectancy. It was estimated that 141 redeployed coal workers might have suffered from CWP as of 2012, and 221 redeployed coal workers could suffer from CWP in the future. It is crucial to establish a set of feasible and affordable regulations on CWP screening and diagnosis as well as labor insurance policies for redeployed coal workers of resource-exhausted coal mines in China.

  17. Markets for small-scale, advanced coal-combustion technologies

    SciTech Connect

    Placet, M.; Kenkeremath, L.D.; Streets, D.G.; Dials, G.E.; Kern, D.M.; Nehring, J.L.; Szpunar, C.B.

    1988-12-01

    This report examines the potential of using US-developed advanced coal technologies (ACTs) for small combustors in foreign markets; in particular, the market potentials of the member countries of the Organization of Economic Co-operation and Development (OECD) were determined. First, the United States and those OECD countries with very low energy demands were eliminated. The remaining 15 countries were characterized on the basis of eight factors that would influence their decision to use US ACTs: energy plan and situation, dependence on oil and gas imports, experience with coal, residential/commercial energy demand, industrial energy demand, trade relationship with the United States, level of domestic competition with US ACT manufacturers, and environmental pressure to use advanced technology. Each country was rated high, medium-high, low-medium, or low on each factor, based on statistical and other data. The ratings were then used to group the countries in terms of their relative market potential (good, good but with impediments, or limited). The best potential markets appear to be Spain, Italy, turkey, Greece, and Canada. 25 refs., 1 fig., 37 tabs.

  18. The development of a coal-fired combustion system for industrial process heating applications

    SciTech Connect

    Not Available

    1992-07-16

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation's Coal-Fired Combustion System for Industrial Process Heating Applications has been selected for Phase III development under contract DE-AC22-91PC91161. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting, recycling, and refining processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase HI research effort is being focused on the development of a process heater system to be used for producing glass frits and wool fiber from boiler and incinerator ashes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. The economic evaluation of commercial scale CMS processes has begun. In order to accurately estimate the cost of the primary process vessels, preliminary designs for 25, 50, and 100 ton/day systems have been started under Task 1. This data will serve as input data for life cycle cost analysis performed as part of techno-economic evaluations. The economic evaluations of commercial CMS systems will be an integral part of the commercialization plan.

  19. POC-SCALE TESTING OF AN ADVANCED FINE COAL DEWATERING EQUIPMENT/TECHNIQUE

    SciTech Connect

    B.K. PAREKH; D. TAO; J.G. GROPPO

    1998-02-03

    The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the UKCAER will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean-coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high-sulfur and low-sulfur clean coal. The Mayflower Plant processes coals from five different seams, thus the dewatering studies results could be generalized for most of the bituminous coals.

  20. Laboratory-scale study of the suppression of PCDD/F emission during coal and MSW co-incineration.

    PubMed

    Lu, Sheng-yong; Yan, Jian-hua; Li, Xiao-dong; Ni, Ming-jiang; Cen, Ke-fa

    2007-01-01

    The experimental test of co-incinerating Chinese raw municipal solid waste (MSW) and coal in a laboratory-scale tubular reactor was first reported in present study, and the emission of normal gas components and the effects of the S/C1 molar ratio or coal mixing percentages on polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDDs/Fs) emission were investigated and discussed. The results indicated that OCDD was the only PCDD homologues since others like TCDD-HpCDD was hardly detected, while as the categories of PCDF homologues were comparatively much more general. The amount of PCDD was much larger than that of PCDF in all operating conditions. Since sigma PCDF/sigma PCDD<1, the dominant role of the precursor formation was proven in our experimental conductions. With increasing the coal addition to MSW (from 0 to 16%), PCDD and PCDF were reduced considerably. Coal and MSW may suppress the PCDD/F emissions efficiently (over 95%) during the MSW incineration process. The PCDD/F suppression results of the present study could be helpful guidance to the industrial application of Chinese MSW and auxiliary coal co-incineration processes. The PCDD/F stack emission data of two industrial incinerators using co-incineration technology in China seem to have a great positive reduction of PCDDs/Fs.

  1. Coal gasification via the Lurgi process: Topical report: Volume 2, Production of IFG (industrial fuel gas)

    SciTech Connect

    Zahnstecher, L.W.

    1984-12-01

    A Lurgi baseline study was requested by the DOE/GRI Operating Committee of the Joint Coal Gasification Program for the purpose of updating the economics of earlier Lurgi coal gasification plant studies for the production of industrial fuel gas (IFG) based on commercially advanced technologies. The current study incorporates the recent experience with large size Lurgi plants in an effort to improve capital and operating costs of earlier plant designs. The present coal gasification study is based upon a plant producing 73.3 billion Btu (HHV) per day of IFG using the Lurgi dry bottom coal gasification technology. A Western subbituminous coal was designated as the plant feed, obtained from the Rosebud seam at Colstrip, Montana. This study presents the detailed description of an integrated facility which utilizes coal, air, and water to produce 73.3 billion Btu (HHV) per day of industrial fuel gas. The plant consists of coal handling and preparation, seven Lurgi dry bottom gasifiers, acid gas removal, sulfur recovery, phenol and ammonia recovery, as well as necessary support facilities. The plant is a grass roots facility located in the area of Minneapolis, Minnesota. The Lurgi Corporation assisted in this study, under subcontract to Foster Wheeler, by supplying the heat and material balances, flow sheets, utilities, catalysts and chemical requirements, and cost data for Lurgi designed process sections. Details of material supplied by Lurgi Corporation are presented in Appendix A. 39 refs., 33 figs., 50 tabs.

  2. Review of China's Low-Carbon City Initiative and Developments in the Coal Industry

    SciTech Connect

    Fridley, David; Khanna, Nina Zheng; Hong, Lixuan

    2012-09-01

    As China continues its double-digit economic growth, coal remains the principal fuel for the country’s primary energy consumption and electricity generation. China’s dependence on coal in coming years makes its carbon emission intensity reduction targets more difficult to achieve, particularly given rising electricity demand from a growing number of Chinese cities. This paradox has led the government to pursue cleaner and more efficient development of the coal industry on the supply side and “low carbon” development of cities on the demand side. To understand and assess how China may be able to meet its energy and carbon intensity reduction targets, this report looks at the recent development of low carbon cities as well as new developments and trends in the coal industry. Specifically, we review low-carbon city and related eco-city development in China before delving into a comparison of eight pilot lowcarbon city plans to highlight their strengths and weaknesses in helping achieve national energy and carbon targets. We then provide insights into the future outlook for China’s coal industry by evaluating new and emerging trends in coal production, consumption, transport, trade and economic performance.

  3. POC-SCALE TESTING OF OIL AGGLOMERATION TECHNIQUES AND EQUIPMENT FOR FINE COAL PROCESSING

    SciTech Connect

    1998-01-01

    This report covers the technical progress achieved from July 01, 1997 to September 30, 1997 on the POC-Scale Testing Agglomeration Techniques and Equipment for Fine Coal Processing project. Experimental procedures and test data for recovery of fine coal from coal fines streams generated at a commercial coal preparation plant are described. Two coal fines streams, namely Sieve Bend Effluent and Cyclone Overflow were investigated. The test results showed that ash was reduced by more than 50% at combustible matter recovery levels exceeding 95%.

  4. The Safety Attitudes of Senior Managers in the Chinese Coal Industry.

    PubMed

    Zhang, Jiangshi; Chen, Na; Fu, Gui; Yan, Mingwei; Kim, Young-Chan

    2016-11-17

    Introduction: Senior managers' attitudes towards safety are very important regarding the safety practices in an organization. The study is to describe the current situation of senior managers' attitudes towards safety in the Chinese coal industry. Method: We evaluated the changing trends as well as the reasons for these changes in the Chinese coal industry in 2009 and in 2014 with 168 senior manager samples from large Chinese state-owned coal enterprises. Evaluations of 15 safety concepts were performed by means of a questionnaire. Results and Conclusions: Results indicate that, in 2014, three concepts were at a very high level (mean > 4.5), and six were at a relatively high level (4.5 > mean > 4.0). Analyses of changing trends revealed that nine concepts improved significantly, while four greatly declined in 2014 compared to those in 2009. The data reported here suggest that the reasons for the significant improvement with respect to the nine concepts include the improvement in social and legal environments, the improvement of the culture of social safety, workers' safety demands being met, and scientific and technical advances in the coal industry. The decline of the four concepts seemed to be caused by a poor awareness of managers in the coal industry that safety creates economic benefits, insufficient information on safety, inadequate attention to the development of a safety culture and safety management methods, and safety organizations and workers' unions not playing their role effectively. Practical Applications: We therefore recommend strengthening the evidence that safety creates economic benefits, providing incentives for employees to encourage their participation in safety management, and paying more attention to the prevention of accidents in coal mines via safety organizations and unions. These results can provide guidelines for workers, industrialists, and government regarding occupational safety in the whole coal industry.

  5. The Safety Attitudes of Senior Managers in the Chinese Coal Industry

    PubMed Central

    Zhang, Jiangshi; Chen, Na; Fu, Gui; Yan, Mingwei; Kim, Young-Chan

    2016-01-01

    Introduction: Senior managers’ attitudes towards safety are very important regarding the safety practices in an organization. The study is to describe the current situation of senior managers′ attitudes towards safety in the Chinese coal industry. Method: We evaluated the changing trends as well as the reasons for these changes in the Chinese coal industry in 2009 and in 2014 with 168 senior manager samples from large Chinese state-owned coal enterprises. Evaluations of 15 safety concepts were performed by means of a questionnaire. Results and Conclusions: Results indicate that, in 2014, three concepts were at a very high level (mean > 4.5), and six were at a relatively high level (4.5 > mean > 4.0). Analyses of changing trends revealed that nine concepts improved significantly, while four greatly declined in 2014 compared to those in 2009. The data reported here suggest that the reasons for the significant improvement with respect to the nine concepts include the improvement in social and legal environments, the improvement of the culture of social safety, workers′ safety demands being met, and scientific and technical advances in the coal industry. The decline of the four concepts seemed to be caused by a poor awareness of managers in the coal industry that safety creates economic benefits, insufficient information on safety, inadequate attention to the development of a safety culture and safety management methods, and safety organizations and workers′ unions not playing their role effectively. Practical Applications: We therefore recommend strengthening the evidence that safety creates economic benefits, providing incentives for employees to encourage their participation in safety management, and paying more attention to the prevention of accidents in coal mines via safety organizations and unions. These results can provide guidelines for workers, industrialists, and government regarding occupational safety in the whole coal industry. PMID:27869654

  6. Corrosion performance of alumina scales in coal gasification environments

    SciTech Connect

    Natesan, K.

    1997-02-01

    Corrosion of metallic structural materials in complex gas environments of coal gasification is a potential problem. The corrosion process is dictated by concentrations of two key constituents: sulfur as H{sub 2}S and Cl as HCl. This paper examines the corrosion performance of alumina scales that are thermally grown on Fe-base alloys during exposure to O/S mixed-gas environments. The results are compared with the performance of chromia-forming alloys in similar environments. The paper also discusses the available information on corrosion performance of alloys whose surfaces were enriched with Al by the pack-diffusion process, by the electrospark deposition process, or by weld overlay techniques.

  7. Abandoned coal mining sites: using ecotoxicological tests to support an industrial organic sludge amendment.

    PubMed

    Chiochetta, Claudete G; Radetski, Marilice R; Corrêa, Albertina X R; Tischer, Vinícius; Tiepo, Erasmo N; Radetski, Claudemir M

    2013-11-01

    The different stages involved in coal mining-related activities result in a degraded landscape and sites associated with large amounts of dumped waste material. Remediation of these contaminated soils can be carried out by application of industrial organic sludge if the concerns regarding the potential negative environmental impacts of this experimental practice are properly addressed. In this context, the objective of this study was to use ecotoxicological tests to determine the quantity of organic industrial sludge that is required as a soil amendment to restore soil production while avoiding environmental impact. Chemical analysis of the solids (industrial sludge and soil) and their leachates was carried out as well as a battery of ecotoxicity tests on enzymes (hydrolytic activity), bacteria, algae, daphnids, earthworms, and higher plants, according to standardized methodologies. Solid and leachate samples of coal-contaminated soil were more toxic than those of industrial sludge towards enzyme activity, bacteria, algae, daphnids, and earthworms. In the case of the higher plants (lettuce, corn, wild cabbage, and Surinam cherry) the industrial sludge was more toxic than the coal-contaminated soil, and a soil/sludge mixture (66:34% dry weight basis) had a stimulatory effect on the Surinam cherry biomass. The ecotoxicological assessment of the coal-contaminated soil remediation using sludge as an amendment is very important to determine application rates that could promote a stimulatory effect on agronomic species without negatively affecting the environment.

  8. POC-scale testing of an advanced fine coal dewatering equipment/technique

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.; Rawls, P.

    1995-11-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. As the contract title suggests, the main focus of the program is on proof-of-concept testing of a dewatering technique for a fine clean coal product. The coal industry is reluctant to use the advanced fine coal recovery technology due to the non-availability of an economical dewatering process. in fact, in a recent survey conducted by U.S. DOE and Battelle, dewatering of fine clean coal was identified as the number one priority for the coal industry. This project will attempt to demonstrate an efficient and economic fine clean coal slurry dewatering process.

  9. The changing structure of the US coal industry: An update, July 1993

    SciTech Connect

    Not Available

    1993-07-29

    Section 205(a)(2) of the Department of Energy Organization Act of 1977 requires the Administrator of the Energy Information Administration (EIA) to carry out a central, comprehensive, and unified energy data and information program that will collect, evaluate, assemble, analyze, and disseminate data and information relevant to energy resources, reserves, production, demand, technology, and related economic and statistical information. The purpose of this report is to provide a comprehensive overview of changes in the structure of the US coal industry between 1976 and 1991. The structural elements examined include the number of mines, average mine size, the size distribution of mines, and the size distribution of coal firms. The report measures changes in the market shares of the largest coal producers at the national level and in various regions. The Central Appalachian low-sulfur coal market is given special attention, and the market for coal reserves is examined. A history of mergers in the coal industry is presented, and changes in the proportions of US coal output that are produced by various types of companies, including foreign-controlled firms, are described. Finally, the impact of post-1991 mergers on the structure of the industry is estimated. The legislation that created the EIA vested the organization with an element of statutory independence. The EIA does not take positions on policy questions. The EIA`s responsibility is to provide timely, high-quality information and to perform objective, credible analyses in support of deliberations by both public and private decisionmakers. Accordingly, this report does not purport to represent the policy positions of the US Department of Energy or the Administration.

  10. Evaluation of the Impact of Chlorine on Mercury Oxidation in a Pilot-Scale Coal Combustor--The Effect of Coal Blending

    EPA Science Inventory

    A study has been undertaken to investigate the effect of blending PRB coal with an Eastern bituminous coal on the speciation of Hg across an SCR catalyst. In this project, a pilot-scale (1.2 MWt) coal combustor equipped with an SCR reactor for NOx control was used for evaluating ...

  11. From Mining to Post-Mining: The Sustainable Development Strategy of the German Hard Coal Mining Industry

    NASA Astrophysics Data System (ADS)

    Kretschmann, J.; Efremenkov, A. B.; Khoreshok, A. A.

    2017-01-01

    By the end of the 1950s, the German coal mining industry produced 150 million tons of hard coal per year in 170 collieries with 600,000 employees. At that time, 70% of the primary energy demand of the Federal Republic of Germany was covered by domestic coal. Since the advance of oil, later of natural gas, in the world energy market and with the growth of world coal trade, domestic coal stood under a long-term restructuring pressure. This decision required a new strategy for the coal mining industry. Now German coal mining will be strictly finalized and will be prepared for the post-mining era. Within a sustainability strategy the long-term impacts of mining activities before and after the mine closures concerning the environmental, economic and social dimensions will be analyzed systematically and forward-looking.

  12. APPLICATION OF REBURNING TO COAL-FIRED INDUSTRIAL BOILERS IN TAIWAN

    EPA Science Inventory

    The paper gives an overview of the characteristics of coal-fired industrial boilers in Taiwan and projections of the cost and performance data for retrofitting several boilers with reburning. The impacts of reburning fuel type on the reburning system design and cost effectivenes...

  13. The Coal Employment Project--How Women Can Make Breakthroughs into Nontraditional Industries.

    ERIC Educational Resources Information Center

    Women's Bureau (DOL), Washington, DC.

    Based on a project carried out by the Women's Bureau of the U.S. Department of Labor, this program guide provides a plan for helping women gain entrance into nontraditional industries. The guide uses as background and examples in the planning process the coal employment project that began in 1977 to make intensive efforts to help women get jobs in…

  14. Liquid Fuels from Coal: From R&D to an Industry

    ERIC Educational Resources Information Center

    Swabb, L. E., Jr.

    1978-01-01

    Government support of coal liquefaction Research and Development has created the conditions that make possible the development of needed technology. With the proper government incentives, pioneer plants will lead to lower costs, and this, plus rising prices, will create the conditions necessary to develop a multi-plant industry. (Author/MA)

  15. Catalytic multi-stage liquefaction of coal at HTI: Bench-scale studies in coal/waste plastics coprocessing

    SciTech Connect

    Pradhan, V.R.; Lee, L.K.; Stalzer, R.H.

    1995-12-31

    The development of Catalytic Multi-Stage Liquefaction (CMSL) at HTI has focused on both bituminous and sub-bituminous coals using laboratory, bench and PDU scale operations. The crude oil equivalent cost of liquid fuels from coal has been curtailed to about $30 per barrel, thus achieving over 30% reduction in the price that was evaluated for the liquefaction technologies demonstrated in the late seventies and early eighties. Contrary to the common belief, the new generation of catalytic multistage coal liquefaction process is environmentally very benign and can produce clean, premium distillates with a very low (<10ppm) heteroatoms content. The HTI Staff has been involved over the years in process development and has made significant improvements in the CMSL processing of coals. A 24 month program (extended to September 30, 1995) to study novel concepts, using a continuous bench scale Catalytic Multi-Stage unit (30kg coal/day), has been initiated since December, 1992. This program consists of ten bench-scale operations supported by Laboratory Studies, Modelling, Process Simulation and Economic Assessments. The Catalytic Multi-Stage Liquefaction is a continuation of the second generation yields using a low/high temperature approach. This paper covers work performed between October 1994- August 1995, especially results obtained from the microautoclave support activities and the bench-scale operations for runs CMSL-08 and CMSL-09, during which, coal and the plastic components for municipal solid wastes (MSW) such as high density polyethylene (HDPE)m, polypropylene (PP), polystyrene (PS), and polythylene terphthlate (PET) were coprocessed.

  16. Co-combustion of coal and solid waste (municipal and industrial solid wastes)

    SciTech Connect

    Ketlogetswe, C.

    1996-12-31

    This work determines the thermal characteristics of various mixtures of carpet waste as an illustrative solid waste. Generally the results revealed that combustion of a mixture of coal with carpet waste yields high fuel bed temperature, in comparison with the combustion of pure solid waste. High fuel bed temperatures of 1,340 C to 1,520 C obtained during the combustion of a mixture of coal with PVC carpet waste would be ideal for energy recovery. The fuel bed temperature of 1,290 C obtained during the combustion of 100% PVC carpet waste suggests that the combustion of general industrial solid waste may be expected to yield a fuel bed temperature of about 1,400 C which would be suitable for energy recovery in the form of power generation or steam generation for general use. The results also revealed that combustion of a mixture of coal and municipal solid waste may require 30% to 35% coal to achieve a fuel bed temperature of about 1,300 C. From economical viewpoint, the % of coal must be kept to a minimum, at least 20% coal or less.

  17. Bench-scale testing of a micronized magnetite, fine-coal cleaning process

    SciTech Connect

    Suardini, P.J.

    1995-11-01

    Custom Coals, International has installed and is presently testing a 500 lb/hr. micronized-magnetite, fine-coal cleaning circuit at PETC`s Process Research Facility (PRF). The cost-shared project was awarded as part of the Coal Preparation Program`s, High Efficiency Preparation Subprogram. The project includes design, construction, testing, and decommissioning of a fully-integrated, bench-scale circuit, complete with feed coal classification to remove the minus 30 micron slimes, dense medium cycloning of the 300 by 30 micron feed coal using a nominal minus 10 micron size magnetite medium, and medium recovery using drain and rinse screens and various stages and types of magnetic separators. This paper describes the project circuit and goals, including a description of the current project status and the sources of coal and magnetite which are being tested.

  18. Microfine coal firing results from a retrofit gas/oil-designed industrial boiler

    SciTech Connect

    Patel, R.; Borio, R.W.; Liljedahl, G.; Miller, B.G.; Scaroni, A.W.; McGowan, J.G.

    1995-12-31

    The development of a High Efficiency Advanced Coal Combustor (HEACC) has been in progress since 1987 and the ABB Power Plant Laboratories. The initial work on this concept produced an advanced coal firing system that was capable of firing both water-based and dry pulverized coal in an industrial boiler environment. Economics may one day dictate that it makes sense to replace oil or natural gas with coal in boilers that were originally designed to burn these fuels. The objective of the current program is to demonstrate the technical and economic feasibility of retrofitting a gas/oil designed boiler to burn micronized coal. In support of this overall objective, the following specific areas were targeted: A coal handling/preparation system that can meet the technical requirements for retrofitting microfine coal on a boiler designed for burning oil or natural gas; Maintaining boiler thermal performance in accordance with specifications when burning oil or natural gas; Maintaining NOx emissions at or below 0.6 lb/MBtu; Achieving combustion efficiencies of 98% or higher; and Calculating economic payback periods as a function of key variables. The overall program has consisted of five major tasks: (1) A review of current state-of-the-art coal firing system components; (2) Design and experimental testing of a prototype HEACC burner; (3) Installation and testing of a HEACC system in a commercial retrofit application; (4) Economic evaluation of the HEACC concept for retrofit applications; and (5) Long term demonstration under commercial user demand conditions. This paper will summarize the latest key experimental results (Task 3) and the economic evaluation (Task 4) of the HEACC concept for retrofit applications. 28 figs., 6 tabs.

  19. Sources and Distribution of Trace Elements in Soils Near Coal-Related Industries.

    PubMed

    Shangguan, Yuxian; Wei, Yuan; Wang, Linquan; Hou, Hong

    2016-04-01

    The degree of contamination of soil and the potential ecological risks associated with five different coal-burning industries were assessed in Shanxi Province, China. Results showed that the trace element concentrations in soil close to the coal industries were higher than those in the background soils, and the enrichment factors were >1. The potential ecological risk indexes ranged from 99 to 328 for the five coal-related industries. Results also illustrated that the trace elements were transported through the atmosphere. Concentrations of B, Hg, Mo, Pb, Se, Cr, Cu, Ni, V, Zn, and Mn were high in the area around the steel plant. Principal component analysis and redundancy analysis indicated that the sources of Se, Mo, Hg, Cd, As, Cr, B, Ni, and Cu were mainly anthropogenic, whereas Pb, V, Cu, Zn, and Mn were from natural sources. The soil Hg and Se contents were simulated by an artificial neural network model, which showed that Hg and Se in soils were from atmospheric deposits and their spatial distributions were related to the dominant wind direction. The potential ecological risk from Hg was much higher (one order of magnitude) than that from the other trace elements, which highlights the fact that it deserves urgent attention. Control of emissions from the burning of coal and other raw materials (such as iron and phosphate ores) should also be prioritized.

  20. The mine management professions in the twentieth-century Scottish coal mining industry

    SciTech Connect

    Perchard, A.

    2007-07-01

    This book seeks to redress the exclusion of colliery managers and other mining professionals from the history of British, and particularly Scottish, coal industries. This is accomplished by examining these groups within the most crucial period of their ascendancy in the Scottish coal mining industry, 1930-1966. This work seeks to place such persons within their context and to examine their roles, statuses and behaviours through their relationships with employees and the execution of their functions, also examining their terms and conditions of employment, the outlook of their professional associations, and that of their union. Through all this, Dr. Perchard illustrates how this growing consciousness amongst managerial employees in the industry was accompanied by an intense public discussion, within the mining professions, over their future shape, principles and occupational standards.

  1. Solid by-products of coal combustion: Fly ash as a source of industrial minerals

    SciTech Connect

    Bhagwat, S.B.; Rapp, D.M.; Bukowski, J.M.

    1996-12-31

    Fly ash is one of the most important by-products of coal combustion. It is a complex mix of cenospheres, reactive glasses, magnetite and carbon, in addition to minor quantities of other minerals. Fly ash components are determined by the type of coal, the combustion technology, material collection system and the temperature of combustion. The changing mix of coal burned in power plants is increasingly making the fly ash characteristics independent of the locally mined coal. Fly ash is thus becoming a raw material independent of the existence of a local coal mining industry. Currently, about 65 million tons of fly ash are generated annually in the United States. This is equivalent to the crushed stone production of such highly industrialized states as Illinois. Only about twenty percent of the total fly ash are currently used, mostly in low value applications such as road building materials and concrete additions. The fly ash currently represents an environmental and financial liability to electric utilities. The increasingly competitive and boundaryless electricity market in the US increases the incentive to look at fly ash in terms of its individual components and recognize their potential as industrial minerals in the production of value added materials. For example, zeolites and other adsorbents could be produced from reactive glasses, magnetite could be used in pigments and ferrite manufacture, activated carbon could serve in pollution control and cenospheres could be used to make lightweight ceramics. If one begins to look at fly ash as a source of industrial minerals and not as a waste product, this change in perspective could turn a financial and environmental liability into an economic opportunity.

  2. The production of high load coal-water mixtures on the base of Kansk-Achinsk Coal Basin

    SciTech Connect

    Demidov, Y.; Bruer, G.; Kolesnikova, S.

    1995-12-01

    The results of the {open_quotes}KATEKNIIugol{close_quotes} work on the problems of high load coal-water mixtures are given in this article. General principles of the mixture production, short characteristics of Kansk-Achinsk coals, the experimental results of the coal mixture production on a test-industrial scale, the suspension preparation on the base of coal mixtures, technical-economical indexes of tested coal pipeline variants based on Kansk-Achinsk coals are described.

  3. POC-scale testing of oil agglomeration techniques and equipment for fine coal processing

    SciTech Connect

    W. Pawlak; K. Szymocha

    1998-04-01

    This report covers the technical progress achieved from January 1, 1998 to April 31, 1998 on the POC-Scale Testing of Oil Agglomeration Techniques and Equipment for Fine Coal Processing. Experimental work was carried out with two coal fines. One sample originated from pond (Drummond Pond Fines) while the second was pulverized Luscar Mine coal. Both samples were tested at the laboratory batch-scale while only Luscar Mine Coal was processed on the 250 kg/h continuous system. Significant progress was made on optimization of process conditions for Pond Fines. The test results showed that ash could be reduced by about 42% at combustible recovery exiting 94%. It was also found that pond fines required significantly longer conditioning time than freshly pulverized run of mine coal. Continuous bench-scale testing carried out with Luscar Mine coal included rod mill calibration, plant equipment and instrumentation check-up, and parametric studies. Compared with batch-scale tests, the continuous bench-scale process required more bridging oil to achieve similar process performance. During the current reporting period work has been commenced on the final engineering and preparation of design package of 3t/h POC-scale unit.

  4. [Emission characteristics of PM10 from coal-fired industrial boiler].

    PubMed

    Li, Chao; Li, Xing-Hua; Duan, Lei; Zhao, Meng; Duan, Jing-Chun; Hao, Ji-Ming

    2009-03-15

    Through ELPI (electrical low-pressure impactor) based dilution sampling system, the emission characteristics of PM10 and PM2.5 was studied experimentally at the inlet and outlet of dust catchers at eight different coal-fired industrial boilers. Results showed that a peak existed at around 0.12-0.20 microm of particle size for both number size distribution and mass size distribution of PM10 emitted from most of the boilers. Chemical composition analysis indicated that PM2.5 was largely composed of organic carbon, elementary carbon, and sulfate, with mass fraction of 3.7%-21.4%, 4.2%-24.6%, and 1.5%-55.2% respectively. Emission factors of PM10 and PM2.5 measured were 0.13-0.65 kg x t(-1) and 0.08-0.49 kg x t(-1) respectively for grate boiler using raw coal, and 0.24 kg x t(-1) and 0.22 kg x t(-1) for chain-grate boiler using briquette. In comparison, the PM2.5 emission factor of fluidized bed boiler is 1.14 kg x t(-1), much her than that of grate boiler. Due to high coal consumption and low efficiency of dust separator, coal-fired industrial boiler may become the most important source of PM10, and should be preferentially controlled in China.

  5. 77 FR 74473 - Notice of Filing of Self-Certification of Coal Capability Under the Powerplant and Industrial...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-12-14

    ... coal or another alternate fuel as a primary energy source. Pursuant to FUA in order to meet the... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Notice of Filing of Self-Certification of Coal Capability Under the Powerplant and Industrial Fuel Use...

  6. 78 FR 26337 - Notice of Filing of Self-Certification of Coal Capability Under the Powerplant and Industrial...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-05-06

    ... of Filing of Self-Certification of Coal Capability Under the Powerplant and Industrial Fuel Use Act... a coal capability self- certification to the Department of Energy (DOE) pursuant to Sec. 201(d) of... 501.60, 61. FUA and regulations thereunder require DOE to publish a notice of filing of...

  7. Partners in health: Injury prevention and the coal mining industry

    SciTech Connect

    Hoerner, E.F.

    1996-12-31

    It is necessary to solve many of the work-related problems and areas of concern that are present in the mining industry. An overview of concerns and how to attack the problems is discussed. Some of the worker`s injury problems, such as back pain syndromes, are by no means unique to the industry. However, other problems such as bolter shoulder syndrome problems, are job specific and need biomechanical investigation to determine specific causal relation of job task to injury. The goal would be defined as twofold. The primary goal is to identify the specific job contribution to high risk occupations, and secondly, to implement a total work force injury prevention program. These goals are discussed.

  8. An explanation of large-scale coal and gas outbursts in underground coal mines: the effect of low-permeability zones on abnormally abundant gas

    NASA Astrophysics Data System (ADS)

    An, F. H.; Cheng, Y. P.

    2013-09-01

    Large-scale coal and gas outbursts post a risk of fatal disasters in underground mines. Large-scale outbursts (outburst of coal and rock greater than 500 t) in recent years in China indicate that there is abundant gas in areas of outbursts containing large amounts of potential energy. The adequate sealing properties of the roof and floor of a coal seam are required for local abundant gas around the site of an outburst, but an annular low-permeability zone in a coal seam, which prevents the loss by gas migration through the coal seam itself, is also required. The distribution of coal gas with this annular zone of low permeability is described, and it is proposed that the annular zone of low permeability creates conditions for confining the coal gas. The effect of this low-permeability zone on the gas distribution is analyzed after allowing for simplifications in the model. The results show that the permeability and length of the low-permeability zone have a great impact on the gas distribution. A steep gradient of gas pressure in the low-permeability zone and the high gas pressure in the abundant zone of gas can promote coal mass failure and coal wall deformation, thereby accelerating the coal and gas outburst. The high pressure gas in abundant zone of gas will lead to a large-scale outburst if an outburst occurs.

  9. Strategy for large scale solubilization of coal - characterization of Neurospora protein and gene

    SciTech Connect

    Patel, A.; Chen, Y.P.; Mishra, N.C.

    1995-12-31

    Low grade coal placed on mycelial mat of Neurospora crassa growing on Petri plate was found to be solubilized by this fungus. A heat stable protein has been purified to near homogeneity which can solubilize low grade coal in in vitro. The biochemical properties of the Neurospora protein will be presented. The nature of the product obtained after solubilization of coal by Neurospora protein in vivo and in vitro will also be presented. The N-terminus sequence of the amino acids of this protein will be used to design primer for possible cloning of gene for Neurospora protein capable of solubilization of coal in order to develop methodology for coal solubilization on a large scale.

  10. Modeling of hydrodynamics of large scale atmospheric circulating fluidized bed coal combustors

    SciTech Connect

    Leretaille, P.Y.; Werther, J.; Briand, P.; Montat, D.

    1999-07-01

    A model for evaluation of the hydrodynamics of gas-solid flow in the riser of a circulating fluidized bed coal boiler is proposed. The 3D fields of the gas and solid velocities and of the solid concentration in the riser are estimated from measured data of the vertical pressure profile. The model includes semi-empirical laws developed on the basis of a set of experimental data on six industrial boilers ranging from 12 MWth to 700 MWth. Its relevance for laboratory scale risers was not tested. The estimation of flow of solids near the walls was fulfilled with a special care due to the influence of this flow on heat transfer. For the validation of the model, measurements of solid concentration with guarded capacitance probes were performed in the 250 MWe Stein Industrie-Lurgi type CFB boiler in Gardanne, France. Finally, an attempt to predict the vertical pressure profile on the riser, starting from the operating conditions (and based on an empirical evaluation of the variation of the downward flow of solid from local conditions) is presented and compared to experimental data.

  11. POC-scale testing of a dry triboelectrostatic separator for fine coal cleaning

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.; Adel, G.T.

    1995-11-01

    Numerous advanced coal cleaning processes have been developed in recent years that are capable of substantially reducing both the ash and sulfur contents of run-of-mine coals. The extent of cleaning depends on the liberation characteristics of the coal, which generally improve with reducing particle size. however, since most of the advanced technologies are wet processes, the clean coal product must be dewatered before it can be transported and burned in conventional boilers. This additional treatment step significantly increases the processing cost and makes the industrial applicability of these advanced technologies much less attractive. In order to avoid problems associated with fine coal dewatering, researchers at the Pittsburgh Energy Technology Center (PETC) developed a novel triboelectrostatic separation (TES) process that can remove mineral matter from dry coal. In this technique, finely pulverized coal is brought into contact with a material (such as copper) having a work function intermediate to that of the carbonaceous material and associated mineral matter. Carbonaceous particles having a relatively low work function become positively charged, while particles of mineral matter having significantly higher work functions become negatively charged. once the particles become selectively charged, a separation can be achieved by passing the particle stream through an electrically charged field. Details related to the triboelectrostatic charging phenomenon have been discussed elsewhere (Inculet, 1984).

  12. Source profiles of particulate matter emissions from a pilot-scale boiler burning North American coal blends.

    PubMed

    Lee, S W

    2001-11-01

    Recent awareness of suspected adverse health effects from ambient particulate matter (PM) emission has prompted publication of new standards for fine PM with aerodynamic diameter less than 2.5 microm (PM2.5). However, scientific data on fine PM emissions from various point sources and their characteristics are very limited. Source apportionment methods are applied to identify contributions of individual regional sources to tropospheric particulate concentrations. The existing industrial database developed using traditional source measurement techniques provides total emission rates only, with no details on chemical nature or size characteristics of particulates. This database is inadequate, in current form, to address source-receptor relationships. A source dilution system was developed for sampling and characterization of total PM, PM2.5, and PM10 (i.e., PM with aerodynamic diameter less than 10 pm) from residual oil and coal combustion. This new system has automatic control capabilities for key parameters, such as relative humidity (RH), temperature, and sample dilution. During optimization of the prototype equipment, three North American coal blends were burned using a 0.7-megawatt thermal (MWt) pulverized coal-fired, pilot-scale boiler. Characteristic emission profiles, including PM2.5 and total PM soluble acids, and elemental and carbon concentrations for three coal blends are presented. Preliminary results indicate that volatile trace elements such as Pb, Zn, Ti, and Se are preferentially enriched in PM2.5. PM2.5 is also more concentrated in soluble sulfates relative to total PM. Coal fly ash collected at the outlet of the electrostatic precipitator (ESP) contains about 85-90% PM10 and 30-50% PM2.5. Particles contain the highest elemental concentrations of Si and Al while Ca, Fe, Na, Ba, and K also exist as major elements. Approximately 4-12% of the materials exists as soluble sulfates in fly ash generated by coal blends containing 0.2-0.8% sulfur by mass

  13. The efficient, large scale separation of coal macerals

    SciTech Connect

    Dyrkacz, G.R.; Bloomquist, C.A.A.

    1988-01-01

    In our continuing efforts in the area of maceral separation, we have recognized the need for a process to supply relatively large amounts of macerals as rapidly as possible. Earlier we reported some initial work using combined sink/float and density gradient centrifugation (DGC) or continuous flow centrifugation and DGC. There are several notable advantages in using continuous flow centrifugation for maceral separation. First, the coal particles can be in a highly dilute suspension, which reduces particle-particle interactions. Second, large amounts of material can be separated; the major limitation being the capacity of the rotor. Third, the separation efficiency is higher. Unlike batch sink/float centrifuge operations, there are less cross-contamination problems with removal of the light and heavy particles, since the light phase is continuously removed. Lastly, the separation is fast. To produce an equivalent amount of purified coal material, much less manipulation is necessary to achieve separation compared to batch sink/float. With all of these advantages in mind, we have again turned our investigations to continuous flow centrifugation for maceral separations. However, this time we are using a centrifuge specifically designed for such work. We report our initial investigations on the separation of the maceral groups from Lewiston-Stockton coal from the Argonne Premium Coal Sample Program (APCS-7). 5 refs., 4 figs., 1 tab.

  14. Industry perspectives on increasing the efficiency of coal-fired power generation

    SciTech Connect

    Torrens, I.M.; Stenzel, W.C.

    1997-12-31

    Independent power producers will build a substantial fraction of expected new coal-fired power generation in developing countries over the coming decades. To reduce perceived risk and obtain financing for their projects, they are currently building and plan to continue to build subcritical coal-fired plants with generating efficiency below 40%. Up-to-date engineering assessment leads to the conclusion that supercritical generating technology, capable of efficiencies of up to 45%, can produce electricity at a lower total cost than conventional plants. If such plants were built in Asia over the coming decades, the savings in carbon dioxide emissions over their lifetime would be measured in billions of tons. IPPs perceive supercritical technology as riskier and higher cost than conventional technology. The truth needs to be confirmed by discussions with additional experienced power engineering companies. Better communication among the interested parties could help to overcome the IPP perception issue. Governments working together with industry might be able to identify creative financing arrangements which can encourage the use of more efficient pulverized clean coal technologies, while awaiting the commercialization of advanced clean coal technologies like gasification combined cycle and pressurized fluidized bed combustion.

  15. Use of sorbents of hot-contact coal carbonization in the power industry

    SciTech Connect

    A.I. Blokhin; F.E. Keneman; A.V. Sklyarov; B.S. Fedoseev

    2003-11-15

    The many years of experience in the use of sorbents of hot-contact coal carbonization (HCCC) in the power industry is used for substantiation of their prospects for solving problems of power and materials saving and improving the reliability and safety of operation of power equipment. Results of tests of sorbents in systems of water conditioning of thermal power plants, cleaning of return condensates, mazut- and oil-contaminated process wastewaters, makeup water in heat networks, and biosorption cleaning of sewerage are presented. The sorption methods of cleaning are shown to have many advantages, to save expensive ion-exchange resins and reagents, to decrease the cost of desalinated water, and to prolong the service of power equipment. Comparative data are presented for basic commercial kinds of activated carbon and HCCC (sorbents activated crushed brown-coal coke (ABD)). The technical characteristics of sorbents of hot-contact coal carbonization are shown to be at the level of commercial sorbents or be higher at a much lower cost (by a factor of 2.5 - 3). It is shown that the creation of several HCCC installations with an output of 25 - 30 thousand tons of sorbents a year at coal-fired power plants will solve many water-cleaning problems of the 'EES Rossii' Co. ('The United Power Systems of Russia') and make it a monopolistic producer of activated carbon in the Russian market.

  16. Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development

    SciTech Connect

    Stephenson, M.

    1994-03-01

    Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because of the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.

  17. Partitioning behavior of trace elements during pilot-scale combustion of pulverized coal and coal-water slurry fuel

    PubMed

    Nodelman; Pisupati; Miller; Scaroni

    2000-05-29

    Release pathways for inorganic hazardous air pollutants (IHAPs) from a pilot-scale, down-fired combustor (DFC) when firing pulverized coal (PC) and coal-water slurry fuel (CWSF) were identified and quantified to demonstrate the effect of fuel form on IHAP partitioning, enrichment and emissions. The baghouse capturing efficiency for each element was calculated to determine the effectiveness of IHAP emission control. Most of the IHAPs were enriched in the fly ash and depleted in the bottom ash. Mercury was found to be enriched in the flue gas, and preferentially emitted in the vapor phase. When firing CWSF, more IHAPs were partitioned in the bottom ash than when firing PC. Significant reduction of Hg emissions during CWSF combustion was also observed.

  18. Conceptual design study of a coal gasification combined-cycle powerplant for industrial cogeneration

    NASA Astrophysics Data System (ADS)

    Bloomfield, H. S.; Nelson, S. G.; Straight, H. F.; Subramaniam, T. K.; Winklepleck, R. G.

    1981-03-01

    A conceptual design study was conducted to assess technical feasibility, environmental characteristics, and economics of coal gasification. The feasibility of a coal gasification combined cycle cogeneration powerplant was examined in response to energy needs and to national policy aimed at decreasing dependence on oil and natural gas. The powerplant provides the steam heating and baseload electrical requirements while serving as a prototype for industrial cogeneration and a modular building block for utility applications. The following topics are discussed: (1) screening of candidate gasification, sulfur removal and power conversion components; (2) definition of a reference system; (3) quantification of plant emissions and waste streams; (4) estimates of capital and operating costs; and (5) a procurement and construction schedule. It is concluded that the proposed powerplant is technically feasible and environmentally superior.

  19. Conceptual design study of a coal gasification combined-cycle powerplant for industrial cogeneration

    NASA Technical Reports Server (NTRS)

    Bloomfield, H. S.; Nelson, S. G.; Straight, H. F.; Subramaniam, T. K.; Winklepleck, R. G.

    1981-01-01

    A conceptual design study was conducted to assess technical feasibility, environmental characteristics, and economics of coal gasification. The feasibility of a coal gasification combined cycle cogeneration powerplant was examined in response to energy needs and to national policy aimed at decreasing dependence on oil and natural gas. The powerplant provides the steam heating and baseload electrical requirements while serving as a prototype for industrial cogeneration and a modular building block for utility applications. The following topics are discussed: (1) screening of candidate gasification, sulfur removal and power conversion components; (2) definition of a reference system; (3) quantification of plant emissions and waste streams; (4) estimates of capital and operating costs; and (5) a procurement and construction schedule. It is concluded that the proposed powerplant is technically feasible and environmentally superior.

  20. FTIR monitoring of industrial scale CVD processes

    NASA Astrophysics Data System (ADS)

    Hopfe, V.; Mosebach, H.; Meyer, M.; Sheel, D.; Grählert, W.; Throl, O.; Dresler, B.

    1998-06-01

    The goal is to improve chemical vapour deposition (CVD) and infiltration (CVI) process control by a multipurpose, knowledge based feedback system. For monitoring the CVD/CVI process in-situ FTIR spectroscopic data has been identified as input information. In the presentation, three commonly used, and distinctly different, types of industrial CVD/CVI processes are taken as test cases: (i) a thermal high capacity CVI batch process for manufacturing carbon fibre reinforced SiC composites for high temperature applications, (ii) a continuously driven CVD thermal process for coating float glass for energy protection, and (iii) a laser stimulated CVD process for continuously coating bundles of thin ceramic fibers. The feasibility of the concept with FTIR in-situ monitoring as a core technology has been demonstrated. FTIR monitoring sensibly reflects process conditions.

  1. POC-scale testing of a dry triboelectrostatic separator for fine coal cleaning

    SciTech Connect

    Yoon, R.-H.; Yan, E.S.; Luttrell, G.H.; Adel, G.T.

    1996-12-31

    It is the objective of the present project to further develop the triboelectrostatic separation (TES) process developed at the Federal Energy Technology Center and test the process at a proof-of-concept (POC) scale. This process has a distinct advantage over other coal cleaning processes in that it does not entail costly steps of dewatering. The POC-scale unit is to developed based on (1) the charge characteristics of coal and mineral matter that can be determined using the novel online tribocharge measuring device developed at Virginia Tech, and (2) the results obtained from bench-scale TES tests conducted on three different coals. At present, the project is at the stage of engineering design, which has three subtasks, Charger Tests, Separator Tests, and Final POC Design. Work accomplished during the current reporting period pertains to the first two subtasks.

  2. Temporal trends and spatial variation characteristics of primary air pollutants emissions from coal-fired industrial boilers in Beijing, China.

    PubMed

    Xue, Yifeng; Tian, Hezhong; Yan, Jing; Zhou, Zhen; Wang, Junling; Nie, Lei; Pan, Tao; Zhou, Junrui; Hua, Shenbing; Wang, Yong; Wu, Xiaoqing

    2016-06-01

    Coal-fired combustion is recognized as a significant anthropogenic source of atmospheric compounds in Beijing, causing heavy air pollution events and associated deterioration in visibility. Obtaining an accurate understanding of the temporal trends and spatial variation characteristics of emissions from coal-fired industrial combustion is essential for predicting air quality changes and evaluating the effectiveness of current control measures. In this study, an integrated emission inventory of primary air pollutants emitted from coal-fired industrial boilers in Beijing is developed for the period of 2007-2013 using a technology-based approach. Future emission trends are projected through 2030 based on current energy-related and emission control policies. Our analysis shows that there is a general downward trend in primary air pollutants emissions because of the implementation of stricter local emission standards and the promotion by the Beijing municipal government of converting from coal-fired industrial boilers to gas-fired boilers. However, the ratio of coal consumed by industrial boilers to total coal consumption has been increasing, raising concerns about the further improvement of air quality in Beijing. Our estimates indicate that the total emissions of PM10, PM2.5, SO2, NOx, CO and VOCs from coal-fired industrial boilers in Beijing in 2013 are approximately 19,242 t, 13,345 t, 26,615 t, 22,965 t, 63,779 t and 1406 t, respectively. Under the current environmental policies and relevant energy savings and emission control plans, it may be possible to reduce NOx and other air pollutant emissions by 94% and 90% by 2030, respectively, if advanced flue gas purification technologies are implemented and coal is replaced with natural gas in the majority of existing boilers.

  3. An explanation of large-scale coal and gas outbursts in underground coal mines: the effect of low-permeability zones on abnormally abundant gas

    NASA Astrophysics Data System (ADS)

    An, F. H.; Cheng, Y. P.

    2014-08-01

    Large-scale coal and gas outbursts pose a risk of fatal disasters in underground mines. Large-scale outbursts (outburst of coal and rock greater than 500 t) in recent years in China indicate that there is abundant gas in areas of outbursts containing large amounts of potential energy. The adequate sealing properties of the roof and floor of a coal seam are required for local abundant gas around the site of an outburst, but an annular low-permeability zone in a coal seam, which prevents the loss by gas migration through the coal seam itself, is also required. The distribution of coal gas with this annular zone of low permeability is described, and it is proposed that the annular zone of low permeability creates conditions for confining the coal gas. The effect of this low-permeability zone on the gas distribution is analyzed after allowing for simplifications in the model. The results show that the permeability and length of the low-permeability zone have a great impact on the gas distribution, and the permeability is required to be several orders of magnitude less than that of normal coal and enough length is also in demand. A steep gradient of gas pressure in the low-permeability zone and the high-pressure gas in the abundant zone of gas can promote coal mass failure and coal wall deformation, thereby accelerating the coal and gas outburst. The high-pressure gas in abundant zone of gas will lead to a large-scale outburst if an outburst occurs.

  4. Managing produced water from coal seam gas projects: implications for an emerging industry in Australia.

    PubMed

    Davies, Peter J; Gore, Damian B; Khan, Stuart J

    2015-07-01

    This paper reviews the environmental problems, impacts and risks associated with the generation and disposal of produced water by the emerging coal seam gas (CSG) industry and how it may be relevant to Australia and similar physical settings. With only limited independent research on the potential environmental impacts of produced water, is it necessary for industry and government policy makers and regulators to draw upon the experiences of related endeavours such as mining and groundwater extraction accepting that the conclusions may not always be directly transferrable. CSG is widely touted in Australia as having the potential to provide significant economic and energy security benefits, yet the environmental and health policies and the planning and regulatory setting are yet to mature and are continuing to evolve amidst ongoing social and environmental concerns and political indecision. In this review, produced water has been defined as water that is brought to the land surface during the process of recovering methane gas from coal seams and includes water sourced from CSG wells as well as flowback water associated with drilling, hydraulic fracturing and gas extraction. A brief overview of produced water generation, its characteristics and environmental issues is provided. A review of past lessons and identification of potential risks, including disposal options, is included to assist in planning and management of this industry.

  5. Pilot scale single stage fine coal dewatering and briquetting process. Technical report, September 1--November 30, 1995

    SciTech Connect

    Wilson, J.W.; Ding, Y.; Honaker, R.Q.

    1995-12-31

    The primary goal of the current coal preparation research is to reduce the ash and sulfur content from coal, using fine grinding and various coal cleaning processes to separate finely disseminated mineral matter and pyrite from coal. Small coal particles are produced by the grinding operation, thus the ultrafine coal becomes very difficult to dewater. In addition, the ultrafine coal also creates problems during its transportation, storage and handling at utility plants. The current research is seeking to combine ultrafine coal dewatering and briquetting processes into a single stage operation, using hydrophobic binders as coal dewatering and binding reagents with the help of a compaction device. From previous tests, it has been found that coal pellets with a moisture content of less than 15% and good wear and water resistance can be successfully fabricated at pressures of less than 6,000 psi using a lab scale ram extruder. The primary objective of the research described in this quarter has been to extend the lab scale ultrafine coal dewatering and briquetting process into a pilot scale operation, based on the test data obtained from earlier research. A standard roller briquetting machine was used to dewater fine coal-binder mixtures during the briquetting process. The operating parameters, including moisture content of feed, feed rate, and roller speed, were evaluated on the basis of the performance of the briquettes. Briquettes fabricated at rates of up to 108 pellets per minute exhibited satisfactory water and wear resistance, i.e., less than 7.5% cured moisture and less than 8.3% weight loss after 6 min. of tumbling. Also, coal-binder samples with moisture contents of 40 percent have been successfully dewatered and briquetted. Briquetting of fine coal was possible under current feeding conditions, however, a better feeding system must be designed to further improve the quality of dewatered coal briquettes.

  6. POC-SCALE TESTING OF AN ADVANCED FINE COAL DEWATERING EQUIPMENT/TECHNIQUE

    SciTech Connect

    X.H. Wang; J. Wiseman; D.J. Sung; D. McLean; William Peters; Jim Mullins; John Hugh; G. Evans; Vince Hamilton; Kenneth Robinette; Tim Krim; Michael Fleet

    1999-08-01

    Dewatering of ultra-fine (minus 150 {micro}m) coal slurry to less than 20% moisture is difficult using the conventional dewatering techniques. The main objective of the project was to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions and surfactants in combination for the dewatering of ultra-fine clean-coal slurries using various dewatering techniques on a proof-of-concept (POC) scale of 0.5 to 2 tons per hour. The addition of conventional reagents and the application of coal surface modification technique were evaluated using vacuum filtration, hyperbaric (pressure) filtration, ceramic plate filtration and screen-bowl centrifuge techniques. The laboratory and pilot-scale dewatering studies were conducted using the fine-size, clean-coal slurry produced in the column flotation circuit at the Powell Mountain Coal Company, St. Charles, VA. The pilot-scale studies were conducted at the Mayflower preparation plant in St. Charles, VA. The program consisted of nine tasks, namely, Task 1--Project Work Planning, Task 2--Laboratory Testing, Task 3--Engineering Design, Task 4--Procurement and Fabrication, Task 5--Installation and Shakedown, Task 6--System Operation, Task 7--Process Evaluation, Task 8--Equipment Removal, and Task 9--Reporting.

  7. POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING

    SciTech Connect

    R.H. Yoon; G.H. Luttrell; E.S. Yan; A.D. Walters

    2001-04-30

    Numerous advanced coal cleaning processes have been developed in recent years that are capable of substantially reducing both ash- and sulfur-forming minerals from coal. However, most of the processes involve fine grinding and use water as the cleaning medium; therefore, the clean coal products must be dewatered before they can be transported and burned. Unfortunately, dewatering fine coal is costly, which makes it difficult to deploy advanced coal cleaning processes for commercial applications. As a means of avoiding problems associated with the fine coal dewatering, the National Energy Technology Laboratory (NETL) developed a dry coal cleaning process in which mineral matter is separated from coal without using water. In this process, pulverized coal is subjected to triboelectrification before being placed in an electric field for electrostatic separation. The triboelectrification is accomplished by passing a pulverized coal through an in-line mixer made of copper. Copper has a work function that lies between that of carbonaceous material (coal) and mineral matter. Thus, coal particles impinging on the copper wall lose electrons to the metal thereby acquiring positive charges, while mineral matter impinging on the wall gain electrons to acquire negative charges. The charged particles then pass through an electric field where they are separated according to their charges into two or more products depending on the configuration of the separator. The results obtained at NETL showed that it is capable of removing more than 90% of the pyritic sulfur and 70% of the ash-forming minerals from a number of eastern U.S. coals. However, the BTU recoveries were less than desirable. The laboratory-scale batch triboelectrostatic separator (TES) used by NETL relied on adhering charged particles on parallel electrode surfaces and scraping them off. Therefore, its throughput will be proportional to the electrode surface area. If this laboratory device is scaled-up as is, it would

  8. Water-carbon trade-off in China's coal power industry.

    PubMed

    Zhang, Chao; Anadon, Laura Diaz; Mo, Hongpin; Zhao, Zhongnan; Liu, Zhu

    2014-10-07

    The energy sector is increasingly facing water scarcity constraints in many regions around the globe, especially in China, where the unprecedented large-scale construction of coal-fired thermal power plants is taking place in its extremely arid northwest regions. As a response to water scarcity, air-cooled coal power plants have experienced dramatic diffusion in China since the middle 2000s. By the end of 2012, air-cooled coal-fired thermal power plants in China amounted to 112 GW, making up 14% of China's thermal power generation capacity. But the water conservation benefit of air-cooled units is achieved at the cost of lower thermal efficiency and consequently higher carbon emission intensity. We estimate that in 2012 the deployment of air-cooled units contributed an additional 24.3-31.9 million tonnes of CO2 emissions (equivalent to 0.7-1.0% of the total CO2 emissions by China's electric power sector), while saving 832-942 million m(3) of consumptive water use (about 60% of the total annual water use of Beijing) when compared to a scenario with water-cooled plants. Additional CO2 emissions from air-cooled plants largely offset the CO2 emissions reduction benefits from Chinese policies of retiring small and outdated coal plants. This water-carbon trade-off is poised to become even more significant by 2020, as air-cooled units are expected to grow by a factor of 2-260 GW, accounting for 22% of China's total coal-fired power generation capacity.

  9. Synthesis of hydroxy sodalite from coal fly ash using waste industrial brine solution.

    PubMed

    Musyoka, Nicholas M; Petrik, Leslie F; Balfour, Gillian; Gitari, Wilson M; Hums, Eric

    2011-01-01

    The effect of using industrial waste brine solution instead of ultra pure water was investigated during the synthesis of zeolites using three South African coal fly ashes as Si feedstock. The high halide brine was obtained from the retentate effluent of a reverse osmosis mine water treatment plant. Synthesis conditions applied were; ageing of fly ash was at 47 ° C for 48 hours, and while the hydrothermal treatment temperature was set at 140 ° C for 48 hours. The use of brine as a solvent resulted in the formation of hydroxy sodalite zeolite although unconverted mullite and hematite from the fly ash feedstock was also found in the synthesis product.

  10. Cost-effectiveness Analysis on Measures to Improve China's Coal-fired Industrial Boiler

    DOE PAGES

    Liu, Manzhi; Shen, Bo; Han, Yafeng; ...

    2015-08-01

    Tackling coal-burning industrial boiler is becoming one of the key programs to solve the environmental problem in China. Assessing the economics of various options to address coal-fired boiler is essential to identify cost-effective solutions. This paper discusses our work in conducting a cost-effectiveness analysis on various types of improvement measures ranging from energy efficiency retrofits to switch from coal to other fuels in China. Sensitivity analysis was also performed in order to understand the impacts of some economic factors such as discount rate and energy price on the economics of boiler improvement options. The results show that nine out ofmore » 14 solutions are cost-effective, and a lower discount rate and higher energy price will result in more energy efficiency measures being cost-effective. Both monetary and non-monetary barriers to energy-efficiency improvement are discussed and policies to tackle these barriers are recommended. Our research aims at providing a methodology to assess cost-effective solutions to boiler problems.« less

  11. Cost-effectiveness Analysis on Measures to Improve China's Coal-fired Industrial Boiler

    SciTech Connect

    Liu, Manzhi; Shen, Bo; Han, Yafeng; Price, Lynn; Xu, Mingchao

    2015-08-01

    Tackling coal-burning industrial boiler is becoming one of the key programs to solve the environmental problem in China. Assessing the economics of various options to address coal-fired boiler is essential to identify cost-effective solutions. This paper discusses our work in conducting a cost-effectiveness analysis on various types of improvement measures ranging from energy efficiency retrofits to switch from coal to other fuels in China. Sensitivity analysis was also performed in order to understand the impacts of some economic factors such as discount rate and energy price on the economics of boiler improvement options. The results show that nine out of 14 solutions are cost-effective, and a lower discount rate and higher energy price will result in more energy efficiency measures being cost-effective. Both monetary and non-monetary barriers to energy-efficiency improvement are discussed and policies to tackle these barriers are recommended. Our research aims at providing a methodology to assess cost-effective solutions to boiler problems.

  12. Use of Sorbents of Hot-Contact Coal Carbonization in the Power Industry

    SciTech Connect

    Blokhin, A. I.; Keneman, F. E.; Sklyarov, A. V.; Fedoseev, B. S.

    2003-11-15

    The many years of experience in the use of sorbents of hot-contact coal carbonization in the power industry is used for substantiation of their prospects for solving problems of power and materials saving and improving the reliability and safety of operation of power equipment. Results of tests of sorbents in systems of water conditioning of thermal power plants, cleaning of return condensates, mazut- and oil-contaminated process wastewaters, makeup water in heat networks, and biosorption cleaning of sewerage are presented. The sorption methods of cleaning are shown to have many advantages, to save expensive ion-exchange resins and reagents, to decrease the cost of desalinated water, and to prolong the service of power equipment. Comparative data are presented for basic commercial kinds of activated carbon and HCCC sorbents (ABD). The technical characteristics of sorbents of hot-contact coal carbonization are shown to be at the level of commercial sorbents or be higher at a much lower cost (by a factor of 2.5 - 3). It is shown that the creation of several HCCC installations with an output of 25 - 30 thousand tons of sorbents a year at coal-fired power plants will solve many water-cleaning problems of the 'EES Rossii' Co. ('The United Power Systems of Russia') and make it a monopolistic producer of activated carbon in the Russian market.

  13. Study of application of ERTS-A imagery to fracture-related mine safety hazards in the coal mining industry

    NASA Technical Reports Server (NTRS)

    Wier, C. E.; Wobber, F. J. (Principal Investigator); Russell, O. R.; Amato, R. V.; Leshendok, T. V.

    1974-01-01

    The author has identified the following significant results. The mine refuse inventory maps were prepared in response to a need by both the State and the coal industry. The lack of information on the scope of the problem handicapped all people concerned in drafting realistic legislation for a severance tax on coal production to raise funds for restoration of refuse sites. The inventory was conducted rapidly and economically, and demonstrated the benefits which can be derived through remote sensing methods.

  14. POC-SCALE TESTING OF OIL AGGLOMERATION TECHNIQUES AND EQUIPMENT FOR FINE COAL PROCESSING

    SciTech Connect

    1998-01-01

    This report covers the technical progress achieved from October 1, 1997 to December 31, 1997 on the POC-Scale Testing of Oil Agglomeration Techniques and Equipment for Fine Coal Processing project. Experimental test procedures and the results related to the processing of coal fines originating from process streams generated at the Shoal Creek Mine preparation plant, owned and operated by the Drummond Company Inc. of Alabama, are described. Two samples of coal fines, namely Cyclone Overflow and Pond Fines were investigated. The batch test results showed that by applying the Aglofloat technology a significant ash removal might be achieved at a very high combustible matter recovery: · for the Cyclone Overflow sample the ash reduction was in the range 50 to 55% at combustible matter recovery about 98% · for the Pond Fines sample the ash reduction was up to 48% at combustible matter recovery up to 85%. Additional tests were carried out with the Alberta origin Luscar Mine coal, which will be used for the parametric studies of agglomeration equipment at the 250 kg/h pilot plant. The Luscar coal is very similar to the Mary Lee Coal Group (processed at Shoal Creek Mine preparation plant) in terms of rank and chemical composition.

  15. Capital and the state in regional economic development: the case of the coal industry in central Appalachia

    SciTech Connect

    Duncan, C.L.

    1985-01-01

    This study examines theories of development policy to assess their relevance for the problems of persistently poor regions within advanced capitalist societies. The central premises of three sets of theories are explored using a multi-method approach that combines quantitative analysis of the impact of growth in the coal industry in rural Kentucky between 1960 and 1980, and qualitative analysis of the perspectives of coal industry executives on development in the coal fields. Theories are categorized into neoclassical, redistributionist and critical paradigms because this typology clarifies the differences in the role of capital and the state in development strategies. Results of analyses of economic and social change in rural Kentucky challenge neoclassical development theory. Greater economic growth in coal counties did not bring greater social progress. The analysis supports the redistributionist and critical theorists' thesis that widespread distribution of economic benefits is important to development. Counties with better distribution of income and work had better conditions in 1980, and coal counties have the greatest economic inequality. Comments of coal industry executives confirm the critical theorists' argument that capital resists State policies to redistribute economic surplus for investment in development.

  16. Microalgae bulk growth model with application to industrial scale systems.

    PubMed

    Quinn, Jason; de Winter, Lenneke; Bradley, Thomas

    2011-04-01

    The scalability of microalgae growth systems is a primary research topic in anticipation of the commercialization of microalgae-based biofuels. To date, there is little published data on the productivity of microalgae in growth systems that are scalable to commercially viable footprints. To inform the development of more detailed assessments of industrial-scale microalgae biofuel processes, this paper presents the construction and validation of a model of microalgae biomass and lipid accumulation in an outdoor, industrial-scale photobioreactor. The model incorporates a time-resolved simulation of microalgae growth and lipid accumulation based on solar irradiation, species specific characteristics, and photobioreactor geometry. The model is validated with 9 weeks of growth data from an industrially-scaled outdoor photobioreactor. Discussion focuses on the sensitivity of the model input parameters, a comparison of predicted microalgae productivity to the literature, and an analysis of the implications of this more detailed growth model on microalgae biofuels lifecycle assessment studies.

  17. Tri-State Synfuels Project Commercial Scale Coal Test: Volume 1. Selection of camp 1 coal. [Proposed Henderson, Kentucky coal to gasoline plant; selection and testing of coal supplies

    SciTech Connect

    Not Available

    1982-06-01

    This report focuses on the rationale for selecting Camp 1 coal for a commercial scale gasification test conducted at the Sasol One Plant. The initial coal quality evaluation consisted primarily of The Pennsylvania State University coal data from Illinois Basin Counties. In November 1980, a preliminary collection of Illinois Basin coal quality data was developed to support the selection of coals for potential plant supply and full scale commercial testing. The total sample and coarse and fine fractions were analyzed. Lurgi and Sasol examined the list and gave their reasons for selection but they had not examined the samples in their laboratories. In December 1980, the list of potential source mines for the 22,000 short ton sample of raw coal for the test was narrowed to three. The mines were Camp 1, Ken and Providence. The reasons for this selection are given. The three candidate mines were again sampled and representative splits of the run-of-mine samples were flown to Lurgi and to Sasol for examination. The Lurgi laboratory report indicated that both Camp 1 and Ken mine samples would qualify as suitable gasifier feed coals. Sasol concluded from an examination of the November report data that Camp 1 and Ken mine samples would be preferable since the free swelling indices are not excessive. Paul Weir Company examined the data and recommended Camp 1 mine since it operates in the seams contiguous to other potential candidate reserve sites and has the ability to transport the mine sample by belt to a barge loading facility to limit production of fines. The final selection of the Camp 1 mine for the test shipment resulted from considerations given in the report.

  18. A coal-fired combustion system for industrial process heating applications

    SciTech Connect

    Not Available

    1992-09-03

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation's Phase III development contract DE-AC22-91PC91161 for a Coal-Fired Combustion System for Industrial Process Heating Applications'' is project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelling and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the current reporting period, approval of Vortec's Environmental Assessment (EA) required under the National Environmental Policy Act (NEPA) was approved. The EA approval cycle took approximately 9 months. The preliminary test program which was being held in abeyance pending approval of the EA was initiated. Six preliminary test runs were successfully competed during the period. Engineering and design activities in support of the Phase III proof of concept are continuing, and modifications to the existing test system configuration to allow performance of the preliminary tests were completed.

  19. Integrated process control for recirculating cooling water treatment in the coal chemical industry.

    PubMed

    Pei, Y S; Guo, W; Yang, Z F

    2011-01-01

    This work focused on the integrated process of the recirculating cooling water (RCW) treatment to achieve approximate zero emission in the coal chemical industry. The benefits of fractional and comprehensive RCW treatment were quantified and qualified by using a water and mass balance approach. Limits of cycle of concentrations and some encountered bottlenecks were used to ascertain set target limits for different water sources. Makeup water was mixed with water produced from reverse osmosis (RO) in the proportion of 6:4, which notably reduced salts discharge. Side infiltration, which settled down suspended solids, can reduce energy consumption by over 40%. An automated on-line monitoring organic phosphorus inhibitor feed maintains the RCW system stability in comparison to the manual feed. Two-step electrosorb technology (EST) instead of an acid feed can lead cycle of concentration of water to reach 7.0. The wastewater from RO, EST and filter was transferred into a concentration treatment system where metallic ions were adsorbed by permanent magnetic materials. Separation of water and salts was completed by using a magnetic disc separator. Applying the integrated process in a coal chemical industry, a benefit of 1.60 million Yuan annually in 2 years was gained and approximate zero emission was achieved. Moreover, both technical and economic feasibility were demonstrated in detail.

  20. Employment conditions of blacks in the coal industry, 1900 to 1930

    SciTech Connect

    Fishback, P.V.M.

    1983-01-01

    Economic historians recently have analyzed black economic welfare mostly in agriculture. The thesis contributes to knowledge of black welfare in nonagricultural employment by analyzing their status in bituminous-coal mining, an industry in which black employment rose throughout the handloading era ending in 1930. Employmen conditions of blacks are compared with those of native whites and immigrants. Using a model of Schumpeterian competition in an environment of racial hostility, the study analyzes the multiple facets of employment packages, as well as differences in the individuals' initial endowments of wealth and skills, acquisition of human capital, and mobility. Discrimination is found to have been a minor factor in the West Virginia coal industry. Piece-rate wages, about which information was relatively easy to gather, were the same for all ethnic groups. The evidence is consistent with the hypothesis that blacks did not receive unequal treatment via assignments in the mine that affected their safety. Lack of managment positions for blacks was the primary form of job segregation.

  1. POC-scale testing of oil agglomeration techniques and equipment for fine coal processing

    SciTech Connect

    W. Pawlak; K. Szymocha

    1998-08-01

    This report covers the technical progress achieved from April 1, 1998 to June 30, 1998 on the POC-Scale Testing of Oil Agglomeration Techniques and Equipment for Fine Coal Processing. Continuous bench-scale runs were carried out with Luscar Mine coal. The main objectives were to optimize process conditions for a proposed jet processor and to compare its performance with a standard high-shear mixer. A total of three runs consisted of 15 testing periods was carried out. Both conditioning devices performed very well with combustible matter recovery exceeding 96%. Slightly higher coal recovery was observed for high-shear mixer, while lower ash contents were achieved when jet processor was used for coal conditioning. During the current reporting period work has been continued and completed on the engineering and design package of a 3 t/h POC-scale agglomeration unit. Preliminary design package prepared by Thermo Design Engineering, a subcontractor to this project, was submitted to DOE for revision and approval.

  2. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 2

    SciTech Connect

    Miller, Bruce; Winton, Shea

    2010-12-31

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or ~28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to the

  3. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 3

    SciTech Connect

    Miller, Bruce; Shea, Winton

    2010-12-31

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or ~28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to the

  4. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 4

    SciTech Connect

    Miller, Bruce; Shea, Winton

    2010-12-31

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or {approx}28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to

  5. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 5

    SciTech Connect

    Miller, Bruce; Shea, Winton

    2010-12-31

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or {approx}28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to

  6. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 1

    SciTech Connect

    Miller, Bruce; Winton, Shea

    2010-12-31

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or ~28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to the

  7. Corrosivities in a pilot-scale combustor of a British and two Illinois coals with varying chlorine contents

    USGS Publications Warehouse

    Chou, I.-Ming; Lytle, J.M.; Kung, S.C.; Ho, K.K.

    2000-01-01

    Many US boiler manufacturers have recommended limits on the chlorine (Cl) content (< 0.25% or < 0.3%) of coals to be used in their boilers. These limits were based primarily on extrapolation of British coal data to predict the probable corrosion behavior of US coals. Even though Cl-related boiler corrosion has not been reported by US utilities burning high-Cl Illinois coals, the manufacturer's limits affect the marketability of high-Cl Illinois coals. This study measured the relative rates of corrosion caused by two high-Cl coals (British and Illinois) and one low-Cl Illinois baseline coal under identical pilot-scale combustion conditions for about 1000 h which gave reliable comparisons. Temperatures used reflected conditions in boiler superheaters. The corrosion probes were fabricated from commercial alloy 304SS frequently used at the hottest superheater section of utility boilers. The results showed no evidence of direct correlation between the coal chlorine content and rate of corrosion. A correlation between the rate of corrosion and the metal temperature was obvious. The results suggested that the different field histories of corrosivity from burning high-Cl Illinois coal and high-Cl British coal occurred because of different metal temperatures operated in US and UK utility boilers. The results of this study can be combined into a database, which could be used for lifting the limits on chlorine contents of coals burned in utility boilers in the US.

  8. Ever-shifting ground: work and labor relations in the anthracite coal industry, 1968-1903

    SciTech Connect

    Blatz, P.K.

    1987-01-01

    This dissertation traces the work experience of the mine workers of the anthracite coal industry of northeastern Pennsylvania from the final three decades of the nineteenth century, during which several attempts to unionize the mines failed, to the industry-wide anthracite strikes of 1900 and 1902, which brought to a successful conclusion the United Mine Workers' drive for unionization. The correspondence of corporate executives shows that a pervasive philosophy of antiunionism characterized management's approach to labor relations. During the nonunion era, the state, rather than any labor organization, served as the most effective counterpoise to corporate power through its enactment of an extensive code of mining regulation. Nevertheless, mine workers still confronted a perilous workplace which, along with chronic underemployment and an utterly unsystematized congeries of work rules, combined to create a work experience fraught with insecurity. The United Mine Workers proposed an industry-wide contract as the means to solve these problems, and effective organization as the prod to force the corporations to negotiate such a contract. However, the union succeeded in its organizing only in the wake of numerous wildcat strikes protesting the many manifestations of the paternalistic, individualized style of labor relations which had always characterized the industry.

  9. Impending impacts of Title III and Title V of the Clean Air Act Amendments of 1990 on the coal industry

    SciTech Connect

    Kerch, R.L.

    1994-12-31

    The coal industry has already begun to feel the affects of the acid deposition title, particularly in Illinois. Two challenges to the producers and sellers of coal; i.e., (1) Title III, Hazardous Air Pollutants and what is in store for customers, and (2) Title V, Operating Permits, which may affect production facilities are discussed. The utilities are temporarily exempted from Title III. The Great Waters report suggests that mercury will be regulated, and it looks like risk assessments will be based on coal analysis rather than on actual emission measurements. Stack sampling is difficult, expensive and slow. Coal cleaning is important in reducing trace elements. Electrostatic precipitators also remove trace elements. ESPs are less effective for mercury and selenium because they are emitted in the gas phase. FGD can remove hazardous air pollutants, but it is not well documented.

  10. Mercury emissions control in coal combustion systems using potassium iodide: bench-scale and pilot-scale studies

    SciTech Connect

    Ying Li; Michael Daukoru; Achariya Suriyawong; Pratim Biswas

    2009-01-15

    Bench- and pilot-scale experiments were conducted using potassium iodide (KI) for capture and removal of Hg in air and coal combustion exhaust. Two bench-scale reactor systems were used: (1) a packed-bed reactor (PBR) packed with granular or powder KI and (2) an aerosol flow reactor (AFR) with injection of KI particles. It was found that a higher temperature, a higher concentration of KI, and a longer gas residence time resulted in a higher Hg removal efficiency. A 100% Hg removal was achieved in the PBR above 300{sup o}C using 0.5 g of powder KI and in the AFR above 500{sup o}C with a KI/Hg molar ratio of 600 at a 5.8 s residence time. The low KI injection ratio relative to Hg indicated that KI is highly effective for Hg removal in air. Formation of I{sub 2} vapor by the oxidation of KI by O{sub 2} at high temperatures, which then reacts with Hg to produce HgI{sub 2}, was identified as the pathway for removal. The pilot-scale experiments were conducted in a 160 kW pulverized coal combustor. KI was introduced in two ways: as a powder mixed with coal and by spraying KI solution droplets into the flue gas. In both cases the Hg removal efficiency increased with an increase in the feed rate of KI. Mixing KI powder with coal was found to be more effective than spraying KI into the flue gas. The Hg removal by KI was less efficient in the pilot-scale tests than in the bench-scale tests probably due to certain flue gas components reacting with KI or I{sub 2}. Hg speciation measurements in both bench- and pilot-scale experiments indicated no oxidized mercury in the gas phase upon introduction of KI, indicating that the oxidation product HgI2 was captured in the particulate phase. This is very beneficial in coal-fired power plants equipped with electrostatic precipitators where particulate-bound Hg can be efficiently removed. 27 refs., 8 figs., 4 tabs.

  11. POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING

    SciTech Connect

    R.-H. Yoon; G.H. Luttrell; B. Luvsansambuu; A.D. Walters

    2000-10-01

    Work continued during the past quarter to improve the performance of the POC-scale unit. For the charging system, a more robust ''turbocharger'' has been fabricated and installed. All of the internal components of the charger have been constructed from the same material (i.e., Plexiglas) to prevent particles from contacting surfaces with different work functions. For the electrode system, a new set of vinyl-coated electrodes have been constructed and tested. The coated electrodes (i) allow higher field strengths to be tested without of risk of arcing and (ii) minimize the likelihood of charge reversal caused by particles colliding with the conducting surfaces of the uncoated electrodes. Tests are underway to evaluate these modifications. Several different coal samples were collected for testing during this reporting period. These samples included (i) a ''reject'' material that was collected from the pyrite trap of a pulverizer at a coal-fired power plant, (ii) an ''intermediate'' product that was selectively withdrawn from the grinding chamber of a pulverizer at a power plant, and (iii) a run-of-mine feed coal from an operating coal preparation plant. Tests were conducted with these samples to investigate the effects of several key parameters (e.g., particle size, charger type, sample history, electrode coatings, etc.) on the performance of the bench-scale separator.

  12. Evaluation of water resources around Barapukuria coal mine industrial area, Dinajpur, Bangladesh

    NASA Astrophysics Data System (ADS)

    Howladar, M. Farhad; Deb, Pulok Kanti; Muzemder, A. T. M. Shahidul Huqe; Ahmed, Mushfique

    2014-09-01

    Water is a very important natural resource which can be utilized in renewable or non-renewable forms but before utilizing, the evaluation of the quality of this resource is crucial for a particular use. However, the problems of water quality are more severe in areas where the mining and mineral processes' industries are present. In mining processes, several classes of wastes are produced which may turn into ultimately the sources of water quality and environmental degradation. In consequences, the evaluations of water quality for livestock, drinking, irrigation purposes and environmental implications have been carried out around the Barapukuria Coal Mining Industry under different methods and techniques such as primarily the field investigation; secondly the laboratory chemical analysis and thirdly justified the suitability of the laboratory analysis with statistical representation and correlation matrix, Schoeller plot, Piper's Trilinear diagram, Expanded Durov diagram, Wilcox diagram, US salinity diagram, Doneen's chart and others. The results of all surface and ground water samples analysis show that the characteristics and concentrations of all the major physical and chemical parameters such as pH, EC, TDS, Na+, K+, Ca2+, Mg2+, Fetotal, Cl-, HCO3 -, CO3 2- and SO4 2- are varied from one sample to other but well analogous with the WHO and EQS standard limit for all purposes in the area where the abundance of the major ions is as follows: Ca2+ > Na+ > Mg2+ > K+ > Fetotal = HCO3 - > SO4 2- > Cl- > CO3 2-. The graphical exposition of analytical data demonstrates two major hydrochemical facies for example: calcium-bicarbonate (Ca2+- HCO3 -) and magnesium-bicarbonate (Mg2+- HCO3 -) type facies which directly support the shallow recently recharged alkaline water around the industry. The calculated values for the evaluation classification of water based on TDS, Na%, EC, SAR, PI, RSC, MH, and TH replicate good to excellent use of water for livestock, drinking and

  13. Large scale solubilization of coal and bioconversion to utilizable energy. Quarterly technical progress report, January-March 1994

    SciTech Connect

    Mishra, N.C.

    1994-06-01

    In order to develop a system for large scale coal solubilization and its bioconversion to utilizable fuel, the authors plan to clone the genes encoding Neurospora protein that facilitate depolymerization of coal. They also plan to use desulfurizing bacteria to remove the sulfur in situ and use other microorganisms to convert biosolubilized coal into utilizable energy following an approach utilizing several microorganisms (Faison). In addition the product of coal solubilized by fungus will be characterized to determine their chemical nature and the mechanism of reaction catalyzed by fungal product during in vivo and in vitro solubilization by the fungus or purified fungal protein.

  14. Large scale solubilization of coal and bioconversion to utilizable energy. Fifth quarterly technical report, January 1, 1995--March 31, 1995

    SciTech Connect

    Mishra, N.C.

    1995-12-01

    In order to develop a system for a large scale coal solubilization and its bioconversion to utilizable fuel, we plan to clone the genes encoding Neurospora protein that facilitate depolymerization of coal. We also plan to use desulfurizing bacteria to remove the sulfur in situ and use other microorganisms to convert biosolubilized coal into utilizable energy following an approach utilizing several microorganisms. In addition the product of coal solubilized by fungus will be characterized to determine their chemical nature and the mechanism of reaction catalyzed by fungal product during in vivo and in vitro solubilization by the fungus or purified fungal protein.

  15. Development of a coal quality expert

    SciTech Connect

    Not Available

    1991-01-09

    Four companies and seven host utilities have teamed with CQ Inc. and C-E to perform the work on this project. The 42-month project will provide the utility industry with a PC expert system to confidently and inexpensively evaluate the potential for coal cleaning, blending, and switching options to reduce emissions while producing lowest cost electricity. Specifically, this project will: enhance the existing Coal Quality Information System (CQIS) database and Coal Quality Impact Model (CQIM) to allow confident assessment of the effects of cleaning on specific boiler cost and performance; and develop and validate a methodology, Coal Quality Expert (CQE) which allows accurate and detailed predictions of coal quality impacts on total power plant capital cost, operating cost, and performance based upon inputs from inexpensive bench-scale tests. During the past quarter, coal cleanability characterization and utility boiler field tests were conducted. Coal characterization studies were performed with the Croweburg Seam coal, obtained from Peabody Coal Company's Rogers County No. 2 Mine located in northeastern Oklahoma. This coal is burned as part of a blend at Public Service Oklahoma's Northeastern Unit 4 (PSO-NE4), a 450-MW unit located at Oologah, Oklahoma. Full-scale combustion tests were initiated at PSO-NE4. Three coal feed scenarios will be evaluated at this site: (1) 100 percent Wyoming Coal (baseline), (2) 90/10 blend of Wyoming and Oklahoma coals, and (3) 70/30 blend of Wyoming and Oklahoma coals. Results to date are given. 3 figs., 5 tabs.

  16. POC-Scale Testing of Oil Agglomeration Techniques and Equipment for Fine Coal Processing

    SciTech Connect

    1998-11-12

    The objective of this project is to develop and demonstrate a Proof-of-Concept (POC) scale oil agglomeration technology capable of increasing the recovery and improving the quality of fine coal strearrts. Two distinct agglomeration devices will be tested, namely, a conventional high shear mixer and a jet processor. To meet the overall objective an eleven task work plan has been designed. The work ranges from batch and continuous bench-scale testing through the design, commissioning and field testing of POC-scale agglomeration equipment.

  17. EVALUATION OF THE IMPACT OF CHLORINE ON MERCURY OXIDATION IN A PILOT-SCALE COAL COMBUSTION--THE EFFECT OF COAL BLENDING

    EPA Science Inventory

    Coal-fired power plants are a major source of mercury (Hg) released into the environment and the utility industry is currently investigating options to reduce Hg emissions. The EPA Clean Air Mercury Rule (CAMR) depends heavily on the co-benefit of mercury removal by existing and ...

  18. Fields of Coal: An analysis of industry and sedimentology in Dolores, Texas

    NASA Astrophysics Data System (ADS)

    Oaden, A.; Besonen, M. R.

    2013-12-01

    characterize the sediments is underway. Basic conclusions indicate the present environment to be minimally affected by the coal operations and resulting tipple pile, but with a large variance over time in mineralogy and composition of sediment, with further research necessary to determine the full effects of industry in the area.

  19. New cleaning technologies advance coal

    SciTech Connect

    Onursal, B.

    1984-05-01

    Alternative options are discussed for reducing sulfur dioxide emissions from coal burning utility and industrial sources. Test results indicate that it may be most advantageous to use the AED Process after coal preparation or on coals that do not need much ash removal. However, the developer claims that research efforts after 1981 have led to process improvements for producing clean coals containing 1.5% to 3% ash. This paper describes the test facility where a full-scale test of the AED Process is underway.

  20. Physicochemical characterizations and desulfurization properties in coal combustion of three calcium and sodium industrial wastes

    SciTech Connect

    Jun Cheng; Junhu Zhou; Jianzhong Liu; Xinyu Cao; Kefa Cen

    2009-05-15

    To recycle industrial wastes and reduce SO{sub 2} pollutant emission in coal combustion, the mineralogical compositions, porosity structures, surface morphologies, and desulfurization properties of three calcium and sodium industrial wastes were investigated via X-ray diffraction (XRD), porosimeter, scanning electron microscopy (SEM), and a fixed-bed reactor. (1) White lime mud (WLM) mainly composed of CaCO{sub 3} with Na{sub 2}O and K{sub 2}O impurities has smaller CaCO{sub 3} particles and a higher surface area than limestone. But calcined WLM has larger CaO particles and a lower surface area than limestone calcined at 1200{sup o}C for 300 s. (2) Calcium carbide residue (CCR) mainly composed of Ca(OH)2, has the highest surface area and smaller Ca(OH){sub 2} particles than the CaCO{sub 3} particles in WLM. Its surface area monotonously and dramatically decreases at 1200{sup o}C for 300 s, but the sintered CaO particles are still smaller than those in the limestone. (3) When brine sludge (BS), mainly composed of NaCl and CaCO{sub 3}, is heated at 1200{sup o}C for 300 s, the NaCl/CaO eutectic solvent facilitates the aggregation of some complex composites to form many larger particles. (4) WLM gives the highest desulfurization efficiency of 80.4% at 1000{sup o}C and 65.0% at 1100{sup o}C in coal combustion. Combined CCR and limestone give a synergistic desulfurization efficiency of 45.8% at 1200{sup o}C. BS with a molar ratio of Na/Ca at 1:15 effectively promotes the synergistic desulfurization efficiency of combined CCR and limestone to a peak of 54.9% at 1200{sup o}C. 23 refs., 10 figs., 3 tabs.

  1. Advanced coal-fueled industrial cogeneration gas turbine system -- combustion development

    SciTech Connect

    LeCren, R.T.

    1994-06-01

    This topical report summarizes the combustor development work accomplished under the subject contract. The objective was to develop a combustion system for the Solar 4MW Type H Centaur gas turbine generator set which was to be used to demonstrate the economic, technical and environmental feasibility of a direct coal-fueled gas turbine in a 100 hour proof-of-concept test. This program started with a design configuration derived during the CSC program. The design went through the following evolution: CSC design which had some known shortcomings, redesigned CSC now designated as the Two Stage Slagging Combustor (TSSC), improved TSSC with the PRIS evaluated in the IBSTF, and full scale design. Supporting and complimentary activities included computer modelling, flow visualization, slag removal, SO{sub x} removal, fuel injector development and fuel properties evaluation. Three combustor rigs were utilized: the TSSC, the IBSTF and the full scale rig at Peoria. The TSSC rig, which was 1/10th scale of the proposed system, consisted of a primary and secondary zone and was used to develop the primary zone performance and to evaluate SO{sub x} and slag removal and fuel properties variations. The IBSTF rig which included all the components of the proposed system was also 1/10th scale except for the particulate removal system which was about 1/30th scale. This rig was used to verify combustor performance data obtained on the TSSC and to develop the PRIS and the particulate removal system. The full scale rig initially included the primary and secondary zones and was later modified to incorporate the PRIS. The purpose of the full scale testing was to verify the scale up calculations and to provide a combustion system for the proof-of-concept engine test that was initially planned in the program.

  2. Development and testing of commercial-scale, coal-fired combustion systems, Phase 3

    SciTech Connect

    Not Available

    1990-01-01

    The US Department of Energy's Pittsburgh Energy Technology Center (PETC) is actively pursuing the development and testing of coal-fired combustion systems for residential, commercial, and industrial market sectors. In response, MTCI initiated the development of a new combustor technology based on the principle of pulse combustion under the sponsorship of PETC (Contract No. AC22-83PC60419). The initial pulse combustor development program was conducted in three phases (MTCI, Development of a Pulsed Coal Combustor Fired with CWM, Phase III Final Report, DOE Contract No. AC22-83PC60419, November 1986). Phase I included a review of the prior art in the area of pulse combustion and the development of pulse combustor design concepts. It led to the conclusion that pulse combustors offer technical and base-of-operation advantages over conventional burners and also indicated favorable economics for replacement of oil- and gas-fired equipment.

  3. Development of a coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, January--March 1994

    SciTech Connect

    Not Available

    1994-04-30

    This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system, controls, and then test the complete system in order to evaluate its potential marketability. The past quarter began with a two-day test performed in January to determine the cause of pulsations in the batch feed system observed during pilot-scale testing of surrogate TSCA incinerator ash performed in December of 1993. Two different batch feedstocks were used during this test: flyash and cullet. The cause of the pulsations was traced to a worn part in the feeder located at the bottom of the batch feed tank. The problem was corrected by replacing the wom part with the corresponding part on the existing coal feed tank. A new feeder for the existing coal tank, which had previously been ordered as part of the new coal handling system, was procured and installed. The data from the pilot-scale tests performed on surrogate TSCA incinerator ash during December of 1993 was collected and analyzed. All of the glass produced during the test passed both the Toxicity characteristics Leach Procedure (TCLP) and the Product Consistency Test (PCT) by approximately two orders of magnitude.

  4. [Industrial pulverized coal low NO{sub x} burner, Phase I] technical progress report, April 1, 1992--June 30, 1992

    SciTech Connect

    Not Available

    1992-09-01

    Market evaluation of industrial pulverized coal usage, and of typical industries and applications where the low-NO{sub x}, burner may be sold, was partially completed at the end of this reporting period. The study identified three coals that may adequately meet the requirements of the low-NO{sub x} burner modeling study, and of the intended industrial applications. These were: (a) Pittsburgh Seam Bituminous, (b) Pittsburgh No. 8, and (c) Utah Bituminous. The first burner design, for modeling studies, was developed for a nominal output of 5.0 million Btu/hr. All input and process parameters, and all major dimensions of the burner have been determined. Burner design sketch was developed. Standard jet pump geometry of the fuel-rich burner flow path (US Patents No. 4,445,842 and No. 3,990,831), has been modified for use with pulverized coal. Staged air was added. Staged air, in conjunction with recirculated flue gas, has been found by ADL, MIT and other researchers to be effective in NO{sub x}, reduction. No attempt has been made to achieve compactness of design. The primary and seconder, air inlets and flow passages are separate, although in the industrial burner they will be combined. Flue gas may be drawn into the burner either from the hot furnace chamber, or from the flue stack after recuperation. However, to satisfy the energy requirements for volatilizing the coal, flue gas temperature above 2000{degrees}F may be needed. With the preliminary burner design completed, and suitable coals for the modeling study selected, type project is ready to proceed to the kinetic modeling tasks at MIT.

  5. [Industrial pulverized coal low NO[sub x] burner, Phase I] technical progress report, April 1, 1992--June 30, 1992

    SciTech Connect

    Not Available

    1992-09-01

    Market evaluation of industrial pulverized coal usage, and of typical industries and applications where the low-NO[sub x], burner may be sold, was partially completed at the end of this reporting period. The study identified three coals that may adequately meet the requirements of the low-NO[sub x] burner modeling study, and of the intended industrial applications. These were: (a) Pittsburgh Seam Bituminous, (b) Pittsburgh No. 8, and (c) Utah Bituminous. The first burner design, for modeling studies, was developed for a nominal output of 5.0 million Btu/hr. All input and process parameters, and all major dimensions of the burner have been determined. Burner design sketch was developed. Standard jet pump geometry of the fuel-rich burner flow path (US Patents No. 4,445,842 and No. 3,990,831), has been modified for use with pulverized coal. Staged air was added. Staged air, in conjunction with recirculated flue gas, has been found by ADL, MIT and other researchers to be effective in NO[sub x], reduction. No attempt has been made to achieve compactness of design. The primary and seconder, air inlets and flow passages are separate, although in the industrial burner they will be combined. Flue gas may be drawn into the burner either from the hot furnace chamber, or from the flue stack after recuperation. However, to satisfy the energy requirements for volatilizing the coal, flue gas temperature above 2000[degrees]F may be needed. With the preliminary burner design completed, and suitable coals for the modeling study selected, type project is ready to proceed to the kinetic modeling tasks at MIT.

  6. Polycyclic aromatic hydrocarbons (PAHs) around tea processing industries using high-sulfur coals.

    PubMed

    Saikia, Jyotilima; Khare, Puja; Saikia, Prasenjit; Saikia, Binoy K

    2016-09-27

    In the present investigation, the concentrations of polycyclic aromatic hydrocarbons (PAHs) associated with PM2.5, PM10 and dust particles emitted from two tea processing industrial units were studied that uses high-sulfur coal as their energy source. A total of 16 PAHs (viz. naphthalene (Nap), acenaphthene (Ace), acenaphthylene (Acen), phenanthrene (Phe), fluorene (Flu), anthracene (Ant), fluoranthene (Fluo), pyrene (Pyr), benz[a]anthracene (BaA), chrysene (Chry), benzo[b]fluoranthene (BbF), benzo[k]fluoranthene (BkF), benzo[a]pyrene (BaP), dibenz[a,h]anthracene (DBahA), indeno[1,2,3-cd]pyrene (IP) and benzo[ghi]perylene (BghiP) were measured. The total PAH concentration was found to be 94.7 ng/m(3) (∑4 PAHs) in the PM10 particle, 32.5 (∑12 PAHs) in PM2.5 and 1.08 ng/m(3) (∑6 PAHs) in the dust sample from site A. In site B, the sum of the PAHs in the PM2.5, PM10 and dust samples are found to be 154.4 ng/m(3) (∑7 PAHs), 165 ng/m(3) (∑3 PAHs) and 1.27 ng/m(3) (∑6 PAHs), respectively. Hybrid Single Particle Lagrangian Integrated Trajectory model study revealed the contribution of local or long-range transport of aerosol sources. Along with the coal combustion activities in the study sites, other sources such as biomass burning and vehicular emission may contribute to the PAHs in the aerosol samples.

  7. Identifying Catchment-Scale Predictors of Coal Mining Impacts on New Zealand Stream Communities.

    PubMed

    Clapcott, Joanne E; Goodwin, Eric O; Harding, Jon S

    2016-03-01

    Coal mining activities can have severe and long-term impacts on freshwater ecosystems. At the individual stream scale, these impacts have been well studied; however, few attempts have been made to determine the predictors of mine impacts at a regional scale. We investigated whether catchment-scale measures of mining impacts could be used to predict biological responses. We collated data from multiple studies and analyzed algae, benthic invertebrate, and fish community data from 186 stream sites, including un-mined streams, and those associated with 620 mines on the West Coast of the South Island, New Zealand. Algal, invertebrate, and fish richness responded to mine impacts and were significantly higher in un-mined compared to mine-impacted streams. Changes in community composition toward more acid- and metal-tolerant species were evident for algae and invertebrates, whereas changes in fish communities were significant and driven by a loss of nonmigratory native species. Consistent catchment-scale predictors of mining activities affecting biota included the time post mining (years), mining density (the number of mines upstream per catchment area), and mining intensity (tons of coal production per catchment area). Mining was associated with a decline in stream biodiversity irrespective of catchment size, and recovery was not evident until at least 30 years after mining activities have ceased. These catchment-scale predictors can provide managers and regulators with practical metrics to focus on management and remediation decisions.

  8. Identifying Catchment-Scale Predictors of Coal Mining Impacts on New Zealand Stream Communities

    NASA Astrophysics Data System (ADS)

    Clapcott, Joanne E.; Goodwin, Eric O.; Harding, Jon S.

    2016-03-01

    Coal mining activities can have severe and long-term impacts on freshwater ecosystems. At the individual stream scale, these impacts have been well studied; however, few attempts have been made to determine the predictors of mine impacts at a regional scale. We investigated whether catchment-scale measures of mining impacts could be used to predict biological responses. We collated data from multiple studies and analyzed algae, benthic invertebrate, and fish community data from 186 stream sites, including un-mined streams, and those associated with 620 mines on the West Coast of the South Island, New Zealand. Algal, invertebrate, and fish richness responded to mine impacts and were significantly higher in un-mined compared to mine-impacted streams. Changes in community composition toward more acid- and metal-tolerant species were evident for algae and invertebrates, whereas changes in fish communities were significant and driven by a loss of nonmigratory native species. Consistent catchment-scale predictors of mining activities affecting biota included the time post mining (years), mining density (the number of mines upstream per catchment area), and mining intensity (tons of coal production per catchment area). Mining was associated with a decline in stream biodiversity irrespective of catchment size, and recovery was not evident until at least 30 years after mining activities have ceased. These catchment-scale predictors can provide managers and regulators with practical metrics to focus on management and remediation decisions.

  9. Industrial experiments for the application of ultrasound on scale control in the Chinese sugar industry.

    PubMed

    Hu, Aijun; Zheng, Jie; Qiu, Taiqiu

    2006-05-01

    The industrialized application of a technique of scale control by ultrasound was investigated in this paper. The results indicated that not only the viscosity of sugar solution was reduced, but also the heat transfer coefficient and evaporation intensity of the evaporation system were improved by 42.4% and 15.2% respectively, and the scale was removed remarkably with no significant effects on white sugar quality. In addition, chemical detergent was not necessary, so no chemical contamination existed and labour intensity was reduced in this technique. Furthermore, the ultrasonic equipment is easy to operate and has good performance in terms of high continuity and automisation.

  10. Novel sensing techniques for industrial scale bio-digesters

    NASA Astrophysics Data System (ADS)

    Rallis, Ilias; Deakin, Anthony; Spencer, J. W.; Jones, G. R.

    2005-05-01

    The monitoring of a complex industrial scale process is a challenging task, particularly when such a process is a large (100m3) industrial organic waste anaerobic digestion (AD) system. This paper describes the deployment of fibre optic based sensors for monitoring an AD process. To enable this complex process to proceed, a number of critical conditions must be set (e.g. temperature, pH etc.).Two novel fibre optic sensors have been developed for monitoring temperature and pH. These operate in a zone zero environment (highly explosive) and need to withstand vibrations and microbial activity and to operate over extended periods of time (months) with no or little servicing.

  11. "Rule of Thumb Methods No Longer Suffice": Development of British Coal Industry Education and Training 1900-circa 1970 and Lessons for Present-Day Education Policy-Makers

    ERIC Educational Resources Information Center

    Walker, Martyn A.

    2015-01-01

    This paper traces the origins and development of coal mining education and training in Britain from 1900 to the 1970s, by which time the coal industry had substantially declined. It looks at the progress from working-class self-help to national policy in support of education and training. The research makes use of college prospectuses and…

  12. Industrial-Scale Processes For Stabilizing Radioactively Contaminated Mercury Wastes

    SciTech Connect

    Broderick, T. E.; Grondin, R.

    2003-02-24

    This paper describes two industrial-scaled processes now being used to treat two problematic mercury waste categories: elemental mercury contaminated with radionuclides and radioactive solid wastes containing greater than 260-ppm mercury. The stabilization processes were developed by ADA Technologies, Inc., an environmental control and process development company in Littleton, Colorado. Perma-Fix Environmental Services has licensed the liquid elemental mercury stabilization process to treat radioactive mercury from Los Alamos National Laboratory and other DOE sites. ADA and Perma-Fix also cooperated to apply the >260-ppm mercury treatment technology to a storm sewer sediment waste collected from the Y-12 complex in Oak Ridge, TN.

  13. China's Coal: Demand, Constraints, and Externalities

    SciTech Connect

    Aden, Nathaniel; Fridley, David; Zheng, Nina

    2009-07-01

    likely to come from the burgeoning coal-liquefaction and chemicals industries. If coal to chemicals capacity reaches 70 million tonnes and coal-to-liquids capacity reaches 60 million tonnes, coal feedstock requirements would add an additional 450 million tonnes by 2025. Even with more efficient growth among these drivers, China's annual coal demand is expected to reach 3.9 to 4.3 billion tonnes by 2025. Central government support for nuclear and renewable energy has not reversed China's growing dependence on coal for primary energy. Substitution is a matter of scale: offsetting one year of recent coal demand growth of 200 million tonnes would require 107 billion cubic meters of natural gas (compared to 2007 growth of 13 BCM), 48 GW of nuclear (compared to 2007 growth of 2 GW), or 86 GW of hydropower capacity (compared to 2007 growth of 16 GW). Ongoing dependence on coal reduces China's ability to mitigate carbon dioxide emissions growth. If coal demand remains on a high growth path, carbon dioxide emissions from coal combustion alone would exceed total US energy-related carbon emissions by 2010. Within China's coal-dominated energy system, domestic transportation has emerged as the largest bottleneck for coal industry growth and is likely to remain a constraint to further expansion. China has a low proportion of high-quality reserves, but is producing its best coal first. Declining quality will further strain production and transport capacity. Furthermore, transporting coal to users has overloaded the train system and dramatically increased truck use, raising transportation oil demand. Growing international imports have helped to offset domestic transport bottlenecks. In the long term, import demand is likely to exceed 200 million tonnes by 2025, significantly impacting regional markets.

  14. Production cost and air emissions impacts of coal cycling in power systems with large-scale wind penetration

    NASA Astrophysics Data System (ADS)

    Oates, David Luke; Jaramillo, Paulina

    2013-06-01

    Wind power introduces variability into electric power systems. Due to the physical characteristics of wind, most of this variability occurs at inter-hour time-scales and coal units are therefore technically capable of balancing wind. Operators of coal-fired units have raised concerns that additional cycling will be prohibitively costly. Using PJM bid-data, we observe that coal operators are likely systematically under-bidding their startup costs. We then consider the effects of a 20% wind penetration scenario in the coal-heavy PJM West area, both when coal units bid business as usual startup costs, and when they bid costs accounting for the elevated wear and tear that occurs during cycling. We conclude that while 20% wind leads to increased coal cycling and reduced coal capacity factors under business as usual startup costs, including full startup costs shifts the burden of balancing wind onto more flexible units. This shift has benefits for CO2, NOX, and SO2 emissions as well as for the profitability of coal plants, as calculated by our dispatch model.

  15. [Cardiac deaths in hard coal-mining industry as an indicator of efficiency of occupational medicine services].

    PubMed

    Skowronek, Rafał; Chowaniec, Czesław; Kowalska, Anna

    2011-01-01

    Deaths in hard-coal mining industry can be divided into: accidental (usually of a single character) and non-accidental-intentional (homicide, suicide) and natural (with a pathological background, 'without external factors'). The main cause of natural deaths is myocardial infarction (MI). Its risk is increased by environmental factors in working place, unhealthy life style, cigarette smoking and alcohol drinking, which is often an attempt at coping with chronic stress, so proper prevention, qualification and periodic examination of workers is indispensable. The aim of the study is to analyze cases of miners' cardiac deaths investigated in Department of Forensic Medicine in Katowice and the number of natural deaths in hard-coal mines in the years 1999-2010. There were 298 accidental and 122 natural deaths, the latter showing an increasing tendency in the years 2002-2004, 2006, 2008 and 2010. Natural deaths--in 95% sudden cardiac deaths--constituted 29% of all deaths in hard-coal mining industry. Autopsies supplemented by histopathological investigations often revealed advanced atherosclerosis and coronary heart disease, which should disqualify a candidate from working underground. A high number of natural deaths in hard-coal mining industry and morphological post mortem assessment of victims indicate insufficiency of occupational medicine services. We propose an improvement of its quality and a higher frequency of periodic examinations of workers (especially in groups with the highest risk of MI), as well as courses of Basic Life Support (BLS). Forensic medicine may be socially useful in assessing the efficiency of occupational medicine services in mining industry.

  16. The effect of unionization and firm structure on health and safety in the bituminous coal industry

    SciTech Connect

    Reardon, J.E.

    1991-01-01

    The increase in the number of conglomerate mergers during the 1980's has prompted renewed debate on the effects of such mergers. This study investigates the effect of the conglomerate firm on the ability of the labor union to achieve safe working conditions in the bituminous coal industry. An index of union strength is constructed to replace the dummy union variable, traditionally included in econometric models to indicate whether or not the work place is unionized. The index is able to differentiate between situations in which the union has the ability to achieve a desired result from situations in which it does not. The principal data set constructed consists of 2,748 injuries in 270 mines from the states of: West Virginia, Pennsylvania, Virginia, Illinois, Kentucky, and Colorado for the year 1988. One finding was that the index of union strength has a negative but insignificant effect on the injury rate and the severity of the injury. Another principal finding was that conglomerate firms reduce the severity of the injury, but not the injury frequency rate. It was also found that conglomerate firms have a higher incidence of occupational illness than independent firms.

  17. Large-Scale Digital Geologic Map Databases and Reports of the North Coal District in Afghanistan

    USGS Publications Warehouse

    Hare, Trent M.; Davis, Philip A.; Nigh, Devon; Skinner, James A.; SanFilipo, John R.; Bolm, Karen S.; Fortezzo, Corey M.; Galuszka, Donna; Stettner, William R.; Sultani, Shafiqullah; Nader, Billal

    2008-01-01

    members of the coal team: Engineer Saifuddin Aminy (Team Leader); Engineer Gul Pacha Azizi; Engineer Abdul Haq Barakati; Engineer Abdul Basir; Engineer Mohammad Daoud; Engineer Abdullah Ebadi; Engineer Abdul Ahad Omaid; Engineer Spozmy; and Engineer Shapary Tokhi. The ongoing efforts of Engineer Mir M. Atiq Kazimi (Team leader); Engineer M. Anwar Housinzada; and Engineer Shereen Agha of the AGS Records Department to organize and catalogue the AGS material were invaluable in locating and preserving these data. The efforts of the entire AGS staff to personally preserve these data during war time, in the absence of virtually any supporting infrastructure, was truly remarkable. The efforts by the British Geological Survey (BGS) to assist the AGS in archiving these data, and the personal assistance provided by BGS (notably Robert McIntosh), to the USGS teams were also appreciated. The logistical support provided by the U.S. Embassy in Kabul, particularly the Afghanistan Reconstruction Group, was critical to the success of the USGS teams while in Afghanistan. Finally, the efforts of the Minister of the Ministry of Mines and Industries (M. Ibrahim Adel) to support the USGS coal resource assessment in Afghanistan, in both his current and former role as President of the Mines Affairs Department was vital to this effort.

  18. Development and testing of a commercial-scale coal-fired combustion system, Phase 3

    SciTech Connect

    Litka, A.F.; Breault, R.W.

    1991-10-01

    Within the commercial sector, oil and natural gas are the predominant fuels used to meet the space-heating needs of schools, office buildings, apartment complexes, and other similar structures. In general, these buildings require firing rates of 1 to 10 million Btu/hr. The objective of this program is to demonstrate the technical and economic viability of a coal-fired combustion system for this sector. The commercial-scale coal-water slurry (CWS)-fired space heating system will be a scale-up of a CWS-fired residential warm-air heating system developed by Tecogen under contract to the Department of Energy, Pittsburgh Energy Technology Center. This system included a patented nonslagging combustor known as IRIS, for Inertial Reactor with Internal Separation. This combustion technology, which has demonstrated high combustion efficiency using CWS fuels at input rates of 100,000 Btu/hr, will be scaled to operate at 2 to 5 millon Btu/hr. Along with the necessary fuel storage and delivery, heat recovery, and control equipment, the system will include pollution control devices to meet targeted values of NO{sub x}, S0{sub 2}, and particulate emissions. In general, the system will be designed to match the reliability, safety, turndown, and ignition performance of gas or oil-fired systems.

  19. Development and testing of a commercial-scale coal-fired combustion system, Phase 3

    SciTech Connect

    Litka, A.F.; Breault, R.W.

    1991-07-01

    Within the commercial sector, oil and natural gas are the predominant fuels used to meet the space-heating needs of schools, office buildings, apartment complexes, and other similar structures. In general, these buildings require firing rates of 1 to 10 million Btu/hr. The objective of this program is to demonstrate the technical and economic viability of a coal-fired combustion system for this sector. The commercial-scale coal-water slurry (CWS)-fired space heating system will be a scale-up of a CWS-fired residential warm-air heating system developed by Tecogen under contract to the Department of Energy, Pittsburgh Energy Technology Center. This system included a patented nonslagging combustor known as IRIS, for Inertial Reactor with Internal Separation. This combustion technology, which has demonstrated high combustion efficiency using CWS fuels at input rates of 100,000 Btu/hr, will be scaled to operate at 2 to 5 millon Btu/hr. Along with the necessary fuel storage and delivery, heat recovery, and control equipment, the system will include pollution control devices to meet targeted values of NO{sub x}, S0{sub 2}, and particulate emissions. In general, the system will be designed to match the reliability, safety, turndown, and ignition performance of gas or oil-fired systems.

  20. Bench-scale treatment of Lurgi gasifier and H-coal wastewaters by the PACT system

    SciTech Connect

    Randall, T.L.

    1984-11-01

    Laboratory and pilot scale studies were carried out on the feasibility of applying the PACT system (involving addition of powdered activated carbon to the aeration tanks in the activated sludge process, and wet-air oxidation of the sludge to recover carbon) to the treatment of wastewaters from the Lurgi/Mobil M process, which produces synthesis gas, and a coal liquefaction process. The PACT system provided continuous, reliable treatment. A 2-stage process gave the best overall removal of COD and DOC. Both single and 2-stage systems achieved consistent nitrification of the wastewaters, producing effluents containing < 1 mg NH/sub 3//l.

  1. Industrial Large Scale Applications of Superconductivity -- Current and Future Trends

    NASA Astrophysics Data System (ADS)

    Amm, Kathleen

    2011-03-01

    Since the initial development of NbTi and Nb3Sn superconducting wires in the early 1960's, superconductivity has developed a broad range of industrial applications in research, medicine and energy. Superconductivity has been used extensively in NMR low field and high field spectrometers and MRI systems, and has been demonstrated in many power applications, including power cables, transformers, fault current limiters, and motors and generators. To date, the most commercially successful application for superconductivity has been the high field magnets required for magnetic resonance imaging (MRI), with a global market well in excess of 4 billion excluding the service industry. The unique ability of superconductors to carry large currents with no losses enabled high field MRI and its unique clinical capabilities in imaging soft tissue. The rapid adoption of high field MRI with superconducting magnets was because superconductivity was a key enabler for high field magnets with their high field uniformity and image quality. With over 30 years of developing MRI systems and applications, MRI has become a robust clinical tool that is ever expanding into new and developing markets. Continued innovation in system design is continuing to address these market needs. One of the key questions that innovators in industrial superconducting magnet design must consider today is what application of superconductivity may lead to a market on the scale of MRI? What are the key considerations for where superconductivity can provide a unique solution as it did in the case of MRI? Many companies in the superconducting industry today are investigating possible technologies that may be the next large market like MRI.

  2. A comparison study of ash formation during pilot-scale combustion of pulverized coal and coal-water slurry fuels

    SciTech Connect

    Miller, S.F.

    1992-01-01

    The objective of this study was to investigate the effect of fuel form. specifically pulverized coal and coal-water slurry fuel (CWSF), on the particle size distribution (PSD) and inorganic composition of the ash formed during combustion. Three areas of primary interest were fuel particle and droplet size distribution, mineral matter PSD, and the composition and occurrence of inorganics in the fuel. The reactions of pyrite, silicates, aluminosilicates, and alkali and alkaline earth elements during combustion are traced. Two coals, a West Virginia Elk Creek high volatile A bituminous coal and the North Dakota Beulah lignite, were fired as a standard utility grind pulverized fuel and a CWSF at 316.2 MJ/h at 20% excess air in the Penn State Combustion Laboratory down-fired combustor. Fuel PSD and droplet size distribution of the pulverized coal and CWSF are important in determining the PSD of the respective ash when the PSD of the mineral matter and the composition and occurrence of the inorganics in the two fuels are similar, as in the case of the Elk Creek fuels. The mechanism for ash formation in both Elk Creek fuels was coalescence and agglomeration of the inorganics in the coal. The Elk Creek CWSF ash was coarser than the pulverized coal ash due to the larger CWSF char size formed during atomization. The average diameter of the inorganic particles identified in the pulverized coal ash was 2.6 times smaller than those identified in the fuel. The mechanism for ash formation in the Beulah CWSF was coalescence and agglomeration of inherent mineral matter. The average diameter of the inorganic particles identified in the CWSF ash was 3.3 times larger than those identified in the fuel.

  3. Industrial innovations for tomorrow: Advances in industrial energy-efficiency technologies. Commercial power plant tests blend of refuse-derived fuel and coal to generate electricity

    SciTech Connect

    Not Available

    1993-11-01

    MSW can be converted to energy in two ways. One involves the direct burning of MSW to produce steam and electricity. The second converts MSW into refuse-derived fuel (RDF) by reducing the size of the MSW and separating metals, glass, and other inorganic materials. RDF can be densified or mixed with binders to form fuel pellets. As part of a program sponsored by DOE`s Office of Industrial Technologies, the National Renewable Energy Laboratory participated in a cooperative research and development agreement to examine combustion of binder-enhanced, densified refuse-derived fuel (b-d RDF) pellets with coal. Pelletized b-d RDF has been burned in coal combustors, but only in quantities of less than 3% in large utility systems. The DOE project involved the use of b-d RDF in quantities up to 20%. A major goal was to quantify the pollutants released during combustion and measure combustion performance.

  4. Recovery Act: Oxy-Combustion Techology Development for Industrial-Scale Boiler Applications

    SciTech Connect

    Levasseur, Armand

    2014-04-30

    Alstom Power Inc. (Alstom), under U.S. DOE/NETL Cooperative Agreement No. DE-NT0005290, is conducting a development program to generate detailed technical information needed for application of oxy-combustion technology. The program is designed to provide the necessary information and understanding for the next step of large-scale commercial demonstration of oxy combustion in tangentially fired boilers and to accelerate the commercialization of this technology. The main project objectives include: • Design and develop an innovative oxyfuel system for existing tangentially-fired boiler units that minimizes overall capital investment and operating costs. • Evaluate performance of oxyfuel tangentially fired boiler systems in pilot scale tests at Alstom’s 15 MWth tangentially fired Boiler Simulation Facility (BSF). • Address technical gaps for the design of oxyfuel commercial utility boilers by focused testing and improvement of engineering and simulation tools. • Develop the design, performance and costs for a demonstration scale oxyfuel boiler and auxiliary systems. • Develop the design and costs for both industrial and utility commercial scale reference oxyfuel boilers and auxiliary systems that are optimized for overall plant performance and cost. • Define key design considerations and develop general guidelines for application of results to utility and different industrial applications. The project was initiated in October 2008 and the scope extended in 2010 under an ARRA award. The project completion date was April 30, 2014. Central to the project is 15 MWth testing in the BSF, which provided in-depth understanding of oxy-combustion under boiler conditions, detailed data for improvement of design tools, and key information for application to commercial scale oxy-fired boiler design. Eight comprehensive 15 MWth oxy-fired test campaigns were performed with different coals, providing detailed data on combustion, emissions, and thermal behavior over a

  5. Novel approach for extinguishing large-scale coal fires using gas-liquid foams in open pit mines.

    PubMed

    Lu, Xinxiao; Wang, Deming; Qin, Botao; Tian, Fuchao; Shi, Guangyi; Dong, Shuaijun

    2015-12-01

    Coal fires are a serious threat to the workers' security and safe production in open pit mines. The coal fire source is hidden and innumerable, and the large-area cavity is prevalent in the coal seam after the coal burned, causing the conventional extinguishment technology difficult to work. Foams are considered as an efficient means of fire extinguishment in these large-scale workplaces. A noble foam preparation method is introduced, and an original design of cavitation jet device is proposed to add foaming agent stably. The jet cavitation occurs when the water flow rate and pressure ratio reach specified values. Through self-building foaming system, the high performance foams are produced and then infused into the blast drilling holes at a large flow. Without complicated operation, this system is found to be very suitable for extinguishing large-scale coal fires. Field application shows that foam generation adopting the proposed key technology makes a good fire extinguishment effect. The temperature reduction using foams is 6-7 times higher than water, and CO concentration is reduced from 9.43 to 0.092‰ in the drilling hole. The coal fires are controlled successfully in open pit mines, ensuring the normal production as well as the security of personnel and equipment.

  6. Development of a retrofit coal combustor for industrial applications, (Phase 1-A)

    SciTech Connect

    Not Available

    1988-10-01

    During this past quarter, two tandem-fired pulse combustors were designed to fire at a nominal rate of 3.5 to 5.5 MMBtu/hr under continuation of Phase I work on DOE project DE-AC22-87PC79654. In prior work, MTCI demonstrated the operation of a 1--2 MMBtu/h coal-fired tandem pulse combustor that is intended for small industrial applications. These component tests emphasized verification of key design issues such as combustor coupling, slag rejection, and staged air addition. The current work, which represents an extension of the Phase I effort, focuses on integrated testing of the tandem pulse combustor with a fire-tube boiler, and the addition of a slag quench vessel. A tandem-fired pulse combustion unit designed to fire at a nominal rate of 3.5-5 MMBtu/hr was designed and fabricated. The configuration includes two combustion chambers cast in a single monolith, tailpipes cast separately with annular air preheating capability, and a cyclonic decoupler. Design analysis and evaluations were performed to optimize the system with respect to minimizing heat losses, size, and cost. Heat losses from the combustor and decoupler walls are predicted to be approximately 3 percent. The final designs for the ancillary items (slag quench, tertiary air addition, scrubber and sampling system) were completed and fabrication and installation initiated. A Cleaver-Brooks 150 hp-4 pass boiler was delivered and installed and modifications for interfacing with the retrofit pulse combustor unit completed. A below-ground slag collection pit was excavated to permit direct in-line coupling of the combustor to the boiler and to reduce head-room requirements. The pit is 30 inches deep and lined with waterproof and fireproof siding.

  7. Large scale solubilization of coal and bioconversion to utilizable energy. Technical progress report, January 1--March 31, 1996

    SciTech Connect

    Mishra, N.C.

    1996-05-01

    In order develop a system for a large scale coal solubilization and its bioconversion to utilizable fuel, the authors plan to clone the genes encoding Neurospora protein that facilitates depolymerization of coal. They also plan to use desulfurizing bacteria to remove the sulfur in situ and use other microorganisms to convert biosolubilized coal into utilizable energy following an approach utilizing several microorganisms. In addition the products of coal solubilized by fungus will be characterized to determine their chemical nature and the mechanism of reaction catalyzed by fungal product during in vivo and in vitro solubilization by the fungus or purified fungal protein. Results are presented for the cloning of genes for Neurospora CSA-protein.

  8. Estimation of Scale Deposition in the Water Walls of an Operating Indian Coal Fired Boiler: Predictive Modeling Approach Using Artificial Neural Networks

    NASA Astrophysics Data System (ADS)

    Kumari, Amrita; Das, Suchandan Kumar; Srivastava, Prem Kumar

    2016-04-01

    Application of computational intelligence for predicting industrial processes has been in extensive use in various industrial sectors including power sector industry. An ANN model using multi-layer perceptron philosophy has been proposed in this paper to predict the deposition behaviors of oxide scale on waterwall tubes of a coal fired boiler. The input parameters comprises of boiler water chemistry and associated operating parameters, such as, pH, alkalinity, total dissolved solids, specific conductivity, iron and dissolved oxygen concentration of the feed water and local heat flux on boiler tube. An efficient gradient based network optimization algorithm has been employed to minimize neural predictions errors. Effects of heat flux, iron content, pH and the concentrations of total dissolved solids in feed water and other operating variables on the scale deposition behavior have been studied. It has been observed that heat flux, iron content and pH of the feed water have a relatively prime influence on the rate of oxide scale deposition in water walls of an Indian boiler. Reasonably good agreement between ANN model predictions and the measured values of oxide scale deposition rate has been observed which is corroborated by the regression fit between these values.

  9. Metabolic engineering of strains: from industrial-scale to lab-scale chemical production.

    PubMed

    Sun, Jie; Alper, Hal S

    2015-03-01

    A plethora of successful metabolic engineering case studies have been published over the past several decades. Here, we highlight a collection of microbially produced chemicals using a historical framework, starting with titers ranging from industrial scale (more than 50 g/L), to medium-scale (5-50 g/L), and lab-scale (0-5 g/L). Although engineered Escherichia coli and Saccharomyces cerevisiae emerge as prominent hosts in the literature as a result of well-developed genetic engineering tools, several novel native-producing strains are gaining attention. This review catalogs the current progress of metabolic engineering towards production of compounds such as acids, alcohols, amino acids, natural organic compounds, and others.

  10. Chlor-Alkali Industry: A Laboratory Scale Approach

    ERIC Educational Resources Information Center

    Sanchez-Sanchez, C. M.; Exposito, E.; Frias-Ferrer, A.; Gonzalez-Garaia, J.; Monthiel, V.; Aldaz, A.

    2004-01-01

    A laboratory experiment for students in the last year of degree program in chemical engineering, chemistry, or industrial chemistry is presented. It models the chlor-alkali process, one of the most important industrial applications of electrochemical technology and the second largest industrial consumer of electricity after aluminium industry.

  11. Outlook and Challenges for Chinese Coal

    SciTech Connect

    Aden, Nathaniel T.; Fridley, David G.; Zheng, Nina

    2008-06-20

    China has been, is, and will continue to be a coal-powered economy. The rapid growth of coal demand since 2001 has created deepening strains and bottlenecks that raise questions about supply security. Although China's coal is 'plentiful,' published academic and policy analyses indicate that peak production will likely occur between 2016 and 2029. Given the current economic growth trajectory, domestic production constraints will lead to a coal gap that is not likely to be filled with imports. Urbanization, heavy industry growth, and increasing per-capita consumption are the primary drivers of rising coal usage. In 2006, the power sector, iron and steel, and cement accounted for 71% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units could save only 14% of projected 2025 coal demand. If China follows Japan, steel production would peak by 2015; cement is likely to follow a similar trajectory. A fourth wedge of future coal consumption is likely to come from the burgeoning coal-liquefaction and chemicals industries. New demand from coal-to-liquids and coal-to-chemicals may add 450 million tonnes of coal demand by 2025. Efficient growth among these drivers indicates that China's annual coal demand will reach 4.2 to 4.7 billion tonnes by 2025. Central government support for nuclear and renewable energy has not been able to reduce China's growing dependence on coal for primary energy. Few substitution options exist: offsetting one year of recent coal demand growth would require over 107 billion cubic meters of natural gas, 48 GW of nuclear, or 86 GW of hydropower capacity. While these alternatives will continue to grow, the scale of development using existing technologies will be insufficient to substitute significant coal demand before 2025. The central role of heavy industry in GDP growth and the difficulty of substituting other fuels suggest that coal consumption is inextricably entwined with

  12. Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1990--June 1991

    SciTech Connect

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  13. Old Dominion, industrial commonwealth: coal, politics, and economy in Antebellum America

    SciTech Connect

    Adams, S.P.

    2005-05-15

    The political economies of coal in Virginia and Pennsylvania from the late eighteenth century through the Civil War are compared, and the divergent paths these two states took in developing their ample coal reserves during a critical period of American industrialisation are examined. State economic policies played a major role. Virginia's failure to exploit the rich coal fields in the western part of the state can be traced to the legislature's over riding concern to protect and promote the interests of the agrarian, slaveholding elite of eastern Virginia. Pennsylvania's more fractious legislature enthusiastically embraced a policy of economic growth that resulted in the construction of an extensive transportation network, a statewide geological survey, and support for private investment in its coal fields.

  14. Pilot scale single stage fine coal dewatering and briquetting process. Final technical report, September 1, 1995--August 31, 1996

    SciTech Connect

    Wilson, J.W.; Honaker, R.Q.; Ding, Y.

    1997-05-01

    The primary goal of the ongoing ICCI coal preparation research project is to reduce ash and sulfur content in coal by using fine grinding and other coal cleaning processes. The ultrafine coal particles that result from the grinding and cleaning operations are difficult to dewater, and create problems in their storage, handling and transportation. The objective of this research is to combine the dewatering and briquetting processes of fine coal preparation into a single stage operation, thereby enhancing the economic viability of utilizing fine coal. A bitumen based emulsion, Orimulsion, has proven to be an effective hydrophobic binder, which helps not only with the briquetting process but also in the expulsion of water from the coal. Encouraging results from the use of a ram extruder briquetting device led to experimentation in the production of briquettes using a lab scale roll briquetting device. In the first quarter of this reporting year, a commercially available lab scale roll briquetting machine was employed (Komarek B-100). Further testing was conducted for the rest of the year with the use of a pilot scale model (Komarek B220-A). Briquettes were produced and evaluated by comparing results developed by adjusting various parameters of the briquetting machines and feed material. Results further substantiate previous findings that curing time dictates both moisture content and strengths of briquettes, and slower roll speeds produce more robust briquettes. A statistical model was set up to determine the optimal range of operating parameters. The statistical model generated from these results provided basic relationships between the roll speed and briquette form pressure.

  15. A new partnership to enhance international competitiveness for coal-related industries

    SciTech Connect

    Schobert, H.H.; Mitchell, G.D.; Finkelman, R.B.

    1999-07-01

    Conducting business in countries with significant indigenous coal supplies and expected economic growth (China, Indonesia, India, Russia, Ukraine, South Africa, Columbia, Brazil, and Venezuela) is extremely difficult, not only from a socio-economic/cultural standpoint, but because little reliable information is available on the properties and quality of raw materials. The question is how to compete and create opportunities in these countries when little or nothing is known about the properties of the indigenous raw materials. To address this concern the Penn State University and the U.S. Geological Survey (USGS) are partnering to develop an integrated database and sample bank of international coal and limestone samples of commercial value to power generation. The purpose of this partnership is to provide a reliable database linked to a convenient sample bank that would aid in resource evaluation and testing with regard to coal utilization including, but not limited to, combustion and combustion engineering, coke making, liquefaction, gasification, coalbed methane recovery, coal preparation, and mining. The Penn State-USGS-Private Sector partnership offers unique potential to provide this valuable service. The Penn State Energy Institute maintains a wide variety of analytical and testing equipment and expertise in coal-related engineering, chemistry and geology and has access to much more throughout the University system. For several decades the Institute has successfully maintained a large domestic coal sample bank. The USGS maintains a state-of-the-art analytical facility and a comprehensive domestic coal quality database. The USGS is actively working in about thirty countries to develop a reliable international coal quality database. Private sector will bring insights into the issues of competitiveness, certain knowledge of the marketplace and financial support.

  16. POC-scale testing of oil agglomeration techniques and equipment for fine coal processing. Quarterly report, July 1--September 30, 1997

    SciTech Connect

    Ignasiak, B.; Pawlak, W.; Szymocha, K.

    1997-12-31

    This report covers the technical progress achieved from July 1, 1997 to September 30, 1997 on the POC-Scale Testing Agglomeration Techniques and Equipment for Fine Coal Processing project. Experimental procedures and test data for recovery of fine coal from coal fines streams generated at a commercial coal preparation plant are described. Two coal fines streams, namely Sieve Bend Effluent and Cyclone Overflow were investigated. The test results showed that ash was reduced by more than 50% at combustible matter recovery levels exceeding 95%.

  17. Clean coal technology: The new coal era

    SciTech Connect

    Not Available

    1994-01-01

    The Clean Coal Technology Program is a government and industry cofunded effort to demonstrate a new generation of innovative coal processes in a series of full-scale showcase`` facilities built across the country. Begun in 1986 and expanded in 1987, the program is expected to finance more than $6.8 billion of projects. Nearly two-thirds of the funding will come from the private sector, well above the 50 percent industry co-funding expected when the program began. The original recommendation for a multi-billion dollar clean coal demonstration program came from the US and Canadian Special Envoys on Acid Rain. In January 1986, Special Envoys Lewis and Davis presented their recommendations. Included was the call for a 5-year, $5-billion program in the US to demonstrate, at commercial scale, innovative clean coal technologies that were beginning to emerge from research programs both in the US and elsewhere in the world. As the Envoys said: if the menu of control options was expanded, and if the new options were significantly cheaper, yet highly efficient, it would be easier to formulate an acid rain control plan that would have broader public appeal.

  18. Small-Scale Coal-Biomass to Liquids Production Using Highly Selective Fischer-Tropsch Synthesis

    SciTech Connect

    Gangwal, Santosh K.; McCabe, Kevin

    2015-04-30

    The research project advanced coal-to-liquids (CTL) and coal-biomass to liquids (CBTL) processes by testing and validating Chevron’s highly selective and active cobalt-zeolite hybrid Fischer-Tropsch (FT) catalyst to convert gasifier syngas predominantly to gasoline, jet fuel and diesel range hydrocarbon liquids, thereby eliminating expensive wax upgrading operations The National Carbon Capture Center (NCCC) operated by Southern Company (SC) at Wilsonville, Alabama served as the host site for the gasifier slip-stream testing/demonstration. Southern Research designed, installed and commissioned a bench scale skid mounted FT reactor system (SR-CBTL test rig) that was fully integrated with a slip stream from SC/NCCC’s transport integrated gasifier (TRIGTM). The test-rig was designed to receive up to 5 lb/h raw syngas augmented with bottled syngas to adjust the H2/CO molar ratio to 2, clean it to cobalt FT catalyst specifications, and produce liquid FT products at the design capacity of 2 to 4 L/day. It employed a 2-inch diameter boiling water jacketed fixed-bed heat-exchange FT reactor incorporating Chevron’s catalyst in Intramicron’s high thermal conductivity micro-fibrous entrapped catalyst (MFEC) packing to efficiently remove heat produced by the highly exothermic FT reaction.

  19. Selenium and arsenic speciation in fly ash from full-scale coal-burning utility plants.

    PubMed

    Huggins, Frank E; Senior, Constance L; Chu, Paul; Ladwig, Ken; Huffman, Gerald P

    2007-05-01

    X-ray absorption fine structure spectroscopy has been used to determine directly the oxidation states and speciation of selenium and arsenic in 10 fly ash samples collected from full-scale utility plants. Such information is needed to assess the health risk posed by these elements in fly ash and to understand their behavior during combustion and in fly ash disposal options, such as sequestration in tailings ponds. Selenium is found predominantly as Se(IV) in selenite (SeO3(2-)) species, whereas arsenic is found predominantly as As(V) in arsenate (AsO4(3-)) species. Two distinct types of selenite and arsenate spectra were observed depending upon whether the fly ash was derived from eastern U.S. bituminous (Fe-rich) coals or from western subbituminous or lignite (Ca-rich) coals. Similar spectral details were observed for both arsenic and selenium in the two different types of fly ash, suggesting that the postcombustion behavior and capture of both of these elements are likely controlled by the same dominant element or phase in each type of fly ash.

  20. The development of a coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, January 1992--March 1992

    SciTech Connect

    Not Available

    1992-07-16

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Coal-Fired Combustion System for Industrial Process Heating Applications has been selected for Phase III development under contract DE-AC22-91PC91161. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting, recycling, and refining processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase HI research effort is being focused on the development of a process heater system to be used for producing glass frits and wool fiber from boiler and incinerator ashes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. The economic evaluation of commercial scale CMS processes has begun. In order to accurately estimate the cost of the primary process vessels, preliminary designs for 25, 50, and 100 ton/day systems have been started under Task 1. This data will serve as input data for life cycle cost analysis performed as part of techno-economic evaluations. The economic evaluations of commercial CMS systems will be an integral part of the commercialization plan.

  1. POC-scale testing of a dry triboelectrostatic separator for fine coal cleaning. Quarterly technical progress report, 1996

    SciTech Connect

    Yoon, R.-H.; Yan, E.S.; Luttrell, G.H.; Adel, G.T.

    1996-12-31

    The Pittsburgh Energy Technology Center (PETC) developed a triboelectrostatic separation (TES) process which is capable of removing mineral matter from coal without using water. A distinct advantage of this dry coal cleaning process is that it does not entail costly steps of dewatering which is a common problem associated with conventional fine coal cleaning processes. It is the objective of this project to conduct a series of proof-of-concept (POC) scale tests at a throughput of 200-250 kg/hr and obtain scale-up information. Prior to the POC testing, bench-scale test work will be conducted with the objective of increasing the separation efficiency and throughput, for which changes in the basic designs for the charger and the separator may be necessary. The bench- and POC-scale test work will be carried out to evaluate various operating parameters and establish a reliable scale-up procedure. The scale-up data will be used to analyze the economic merits of the TES process. At present, the project is at the stage of engineering design (Task 3). Work accomplished during this reporting period are summarized as follows: (i) An on-line tribocharge analyzer has been developed to study triboelectrification. (ii) The effects of aeration rate, feed rate and particle size on the tribocbarging mechanisms using the on-line tribocharge analyzer. (iii) A continuous bench-scale tnboelectrostatic separator has been constructed. (iv) Shakedown testing of the bench-scale triboelectrostatic separator is on-going.

  2. Scaled multisensor inspection of extended surfaces for industrial quality control

    NASA Astrophysics Data System (ADS)

    Kayser, Daniel; Bothe, Thorsten; Osten, Wolfgang

    2002-06-01

    Reliable real-time surface inspection of extended surfaces with high resolution is needed in several industrial applications. With respect to an efficient application to extended technical components such as aircraft or automotive parts, the inspection system has to perform a robust measurement with a ratio of less then 10-6 between depth resolution and lateral extension. This ratio is at least one order beyond the solutions that are offered by existing technologies. The concept of scaled topometry consists of arranging different optical measurement techniques with overlapping ranges of resolution systematically in order to receive characteristic surface information with the required accuracy. In such a surface inspection system, an active algorithm combines measurements on several scales of resolution and distinguishes between local fault indicating structures with different extensions and global geometric properties. The first part of this active algorithm finds indications of critical surface areas in the data of every measurement and separates them into different categories. The second part analyses the detected structures in the data with respect to their resolution and decides whether a further local measurement with a higher resolution has to be performed. The third part positions the sensors and starts the refined measurements. The fourth part finally integrates the measured local data set into the overall data mesh. We have constructed a laboratory setup capable of measuring surfaces with extensions up to 1500mm x 1000mm x 500mm (in x-, y- and z-direction respectively). Using this measurement system we will be able to separate the fault indicating structures on the surface from the global shape and to classify the detected structures according to their extensions and characteristic shapes simultaneously. The level of fault detection probability will be applicable by input parameter control.

  3. Pilot Scale Single Stage Fine Coal Dewatering and Briquetting Process. Technical report, March 1, 1996 - May 31, 1996

    SciTech Connect

    Wilson, J.W.; Honaker, R.Q.; Ding, Y.; Ho, K.

    1996-12-31

    The primary goal for this ICCI coal research project is to effectively liberate coal from fnely disseminated minerals for Illinois Basin coal by using fine grinding and cleaning processes. However, because of the large surface area generated during the cleaning processes, it is difficult and uneconomic for conventional techniques to dewater the coal fines. In addition, these coal fine pose transportation, storage and handling problems at cleaning and utility facilities. The objective of this research is to combine dewatering and briquetting processes into a single stage operation that will solve the problems mentioned above. To build on the promising results obtained from the previous studies, a pilot scale commercial briquetting machine was used to evaluate this technique. The primary objective of the research in this reporting period is to determine the effectiveness of a single stage dewatering and briquetting technique using a commercial briquetting device. Two types of samples were prepared and the results of the -28 x 100 mesh samples are presented in this report. Modifications were made to the machine in an attempt to solve the back drainage problem. A total of six experiments were conducted and the results indicate that water resistance of coal briquettes increased as curing time increased. However, due to a deficiency of fine particles to bridge the gaps between the coarse particles, the wear resistance of the products declined. Also, at high roll speeds and compaction pressures, the coal briquettes produced tended to have higher moisture content and lower strength. On the other hand, at high feed rates, because of the screw extrusion effect, coal briquettes were produced with lower moisture content and higher strengths.

  4. Development of a coal quality expert

    SciTech Connect

    Not Available

    1991-04-03

    This 42-month project will provide the utility industry with a PC expert system to confidently and inexpensively evaluate the potential for coal cleaning, blending, and switching options to reduce emissions while producing lowest cost electricity. The project consists of the following seven tasks: (Task 1) Project management, (Task 2) Coal cleanability characterization, (Task 3) Pilot-scale combustion testing, (Task 4) Utility boiler field testing, (Task 5) CQIM completion and development of CQE specification (Task 6) Develop CQE, and (Task 7) CQE workstation testing and validation. During the past quarter, coal cleanability characterization, pilot-scale combustion, and utility boiler field tests were conducted. Coal characterization studies were performed at CQ Inc. with the Croweburg Seam coal (alternate coal at Public Service Oklahoma's Northeastern Unit 4) and Western Kentucky No. 11 Seam coal (alternate coal at Mississippi Power Company's Plant Watson Unit 4). Pilot-scale combustion testing was initiated at Combustion Engineering's Fireside Performance Test Facility (FPTF) with evaluations of two of the four PSO test coals. Full-scale combustion tests were completed at the first two utility test sites: Public Service Oklahoma's Northeastern Unit 4 (PSO-NE4) and Mississippi Power Company's Plant Watson Unit 4 (MPC-W4). 3 figs., 7 tabs.

  5. Investigation of flow behaviour of coal particles in a pilot-scale fluidized bed gasifier (FBG) using radiotracer technique.

    PubMed

    Pant, H J; Sharma, V K; Kamudu, M Vidya; Prakash, S G; Krishanamoorthy, S; Anandam, G; Rao, P Seshubabu; Ramani, N V S; Singh, Gursharan; Sonde, R R

    2009-09-01

    Knowledge of residence time distribution (RTD), mean residence time (MRT) and degree of axial mixing of solid phase is required for efficient operation of coal gasification process. Radiotracer technique was used to measure the RTD of coal particles in a pilot-scale fluidized bed gasifier (FBG). Two different radiotracers i.e. lanthanum-140 and gold-198 labeled coal particles (100 gm) were independently used as radiotracers. The radiotracer was instantaneously injected into the coal feed line and monitored at the ash extraction line at the bottom and gas outlet at the top of the gasifier using collimated scintillation detectors. The measured RTD data were treated and MRTs of coal/ash particles were determined. The treated data were simulated using tanks-in-series model. The simulation of RTD data indicated good degree of mixing with small fraction of the feed material bypassing/short-circuiting from the bottom of the gasifier. The results of the investigation were found useful for optimizing the design and operation of the FBG, and scale-up of the gasification process.

  6. Production of Jet Fuels from Coal Derived Liquids. Volume 9. Results of Bench-Scale and Pilot Plant Testing

    DTIC Science & Technology

    1989-06-01

    Amoco Oil Company has conducted bench- and pilot plant-scale experiments to produce jet fuels from the tar oil from the Great Plains Coal ... Gasification Plant in Beulah, North Dakota. Experiments show that the hydroprocessing conditions recommended in Task I are not severe enough to saturate the

  7. Mathematical and experimental pilot-scale study of coal reburning for NO sub x control in cyclone boilers

    SciTech Connect

    Farzan, H.; Wessel, R.A.

    1991-06-01

    The purpose of this pilot-scale study was to examine the effectiveness of reburning for NO{sub x} reduction and to assess the potential side effects. In addition, the potential of a high-sulfur Illinois coal for cyclone reburning application was evaluated. (VC)

  8. Advanced coal-fueled industrial cogeneration gas turbine system: Hot End Simulation Rig

    SciTech Connect

    Galica, M.A.

    1994-02-01

    This Hot End Simulation Rig (HESR) was an integral part of the overall Solar/METC program chartered to prove the technical, economic, an environmental feasibility of a coal-fueled gas turbine, for cogeneration applications. The program was to culminate in a test of a Solar Centaur Type H engine system operated on coal slurry fuel throughput the engine design operating range. This particular activity was designed to verify the performance of the Centaur Type H engine hot section materials in a coal-fired environment varying the amounts of alkali, ash, and sulfur in the coal to assess the material corrosion. Success in the program was dependent upon the satisfactory resolution of several key issues. Included was the control of hot end corrosion and erosion, necessary to ensure adequate operating life. The Hot End Simulation Rig addressed this important issue by exposing currently used hot section turbine alloys, alternate alloys, and commercially available advanced protective coating systems to a representative coal-fueled environment at turbine inlet temperatures typical of Solar`s Centaur Type H. Turbine hot end components which would experience material degradation include the transition duct from the combustor outlet to the turbine inlet, the shroud, nozzles, and blades. A ceramic candle filter vessel was included in the system as the particulate removal device for the HESR. In addition to turbine material testing, the candle material was exposed and evaluated. Long-term testing was intended to sufficiently characterize the performance of these materials for the turbine.

  9. Development and testing of a high efficiency advanced coal combustor: Phase 3, industrial boiler retrofit. Quarterly technical progress report number 12, July 1, 1994--September 30, 1994

    SciTech Connect

    Patel, R.L.; Borio, R.; McGowan, J.G.

    1994-11-18

    The objective of this project is to retrofit the previously developed High Efficiency Advanced Coal Combustor (HEACC) to a standard gas/oil designed industrial boiler to assess the technical and economic viability of displacing premium fuels with microfine coal. During this reporting period, data reduction/evaluation and interpretation from the long term four hundred hours Proof-of-Concept System Test under Task 3 were completed. Cumulatively, a total of approximately 563 hours of coal testing was performed with 160 hrs on 100% coal and over 400 hours with co-firing coal and gas. The primary objectives of this testing were to: (1) obtain steady state operation consistently on 100% coal; (2) increase carbon conversion efficiency from 95% to the project goal of 98%; and (3) maintain NOx emissions at or below 0.6 lbs/MBtu. The following specific conclusions are based on results of coal-fired testing at Penn State and the initial economic evaluation of the HEACC system: a coal handling/preparation system can be designed to meet the technical requirements for retrofitting microfine coal combustion to a gas/oil-designed boiler; the boiler thermal performance requirements were met; the NOx emission target of was met; combustion efficiencies of 95% could be met on a daily average basis, somewhat below the target of 98%; the economic playback is very sensitive to fuel differential cost, unit size, and annual operating hours; continuous long term demonstration is needed to quantify ash effects and how to best handle ashes. The following modifications are recommended prior to the 1,000 hour demonstration phase testing: (1) coal feeding improvements--improved raw coal/storage and transport, installation of gravimetric feeder, and redesign/installation of surge bin bottom; (2) burner modification--minor modification to the tip of the existing HEACC burner to prevent change of flame shapes for no apparent reason.

  10. Continuous pilot-scale testing of column flotation for recovery of fine coal

    SciTech Connect

    Groppo, J.G.; Parekh, B.K. . Center for Applied Energy Research)

    1990-10-01

    A series of performance studies were conducted using countercurrent column flotation to recover a marketable clean coal product from existing preparation plant fine waste streams. The test work was conducted at several preparation plant sites in Kentucky and Virginia using a 150-mm (6-in.) inside diameter column that was 5.8 m (19 ft) high. Both thickener feed and classifying cyclone overflow with a typical size distribution of 150{mu}m (100 mesh) {times} 0 were tested. The percent solids of the column flotation feed varied from 1.5% to 15% while the ash content ranged from about 30% to 60%. The concentrates produced contained 2% to 10% ash with Btu recoveries of nearly 90% using 0.12 to 1.25 kg/t (0.25 to 2.5 lbs per st) fuel oil and 0.12 kg/t (0.25 lbs per st) MIBC. These results were consistent with or better than results obtained in preliminary laboratory scale column flotation evaluation. Test results from seven different seams are discussed as well as scale-up relationships used to design a full-scale installation presently in operation.

  11. Environmental impact of coal industry and thermal power plants in India.

    PubMed

    Mishra, U C

    2004-01-01

    Coal is the only natural resource and fossil fuel available in abundance in India. Consequently, it is used widely as a thermal energy source and also as fuel for thermal power plants producing electricity. India has about 90,000 MW installed capacity for electricity generation, of which more than 70% is produced by coal-based thermal power plants. Hydro-electricity contributes about 25%, and the remaining is mostly from nuclear power plants (NPPs). The problems associated with the use of coal are low calorific value and very high ash content. The ash content is as high as 55-60%, with an average value of about 35-40%. Further, most of the coal is located in the eastern parts of the country and requires transportation over long distances, mostly by trains, which run on diesel. About 70% oil is imported and is a big drain on India's hard currency. In the foreseeable future, there is no other option likely to be available, as the nuclear power programme envisages installing 20,000 MWe by the year 2020, when it will still be around 5% of the installed capacity. Hence, attempts are being made to reduce the adverse environmental and ecological impact of coal-fired power plants. The installed electricity generating capacity has to increase very rapidly (at present around 8-10% per annum), as India has one of the lowest per capita electricity consumptions. Therefore, the problems for the future are formidable from ecological, radio-ecological and pollution viewpoints. A similar situation exists in many developing countries of the region, including the People's Republic of China, where coal is used extensively. The paper highlights some of these problems with the data generated in the author's laboratory and gives a brief description of the solutions being attempted. The extent of global warming in this century will be determined by how developing countries like India manage their energy generation plans. Some of the recommendations have been implemented for new plants

  12. Baseline Industrial Hygiene Survey at the Coal Fired Heating Plant, Malmstrom AFB, Montana.

    DTIC Science & Technology

    1987-12-01

    entrance and maintenance (i.e., bag changing every 4-5 years), ash exposure and heat stress can create health hazards. c. Periodically, the waste ash...a neutralizing adsorbent called "mi]. klime .ŕ MilklimP is an alkaline reed slairry made by mixing q-uiklime (calciu.n oxide), ash and water. In a...USAFOEHL Report (2). b. Any of’ the thrpa (coal, ash, or combined) silica content percentages can change when new coal is delivered during the course of

  13. Pilot-scale fluidized-bed combustor testing cofiring animal-tissue biomass with coal as a carcass disposal option

    SciTech Connect

    Bruce G. Miller; Sharon Falcone Miller; Elizabeth M. Fedorowicz; David W. Harlan; Linda A. Detwiler; Michelle L. Rossman

    2006-10-15

    This study was performed to demonstrate the technical viability of cofiring animal-tissue biomass (ATB) in a coal-fired fluidized-bed combustor (FBC) as an option for disposing of specified risk materials (SRMs) and carcasses. The purpose of this study was to assess the technical issues of feeding/combusting ATB and not to investigate prion deactivation/pathogen destruction. Overall, the project successfully demonstrated that carcasses and SRMs can be cofired with coal in a bubbling FBC. Feeding ATB into the FBC did, however, present several challenges. Specifically, handling/feeding issues resulting from the small scale of the equipment and the extremely heterogeneous nature of the ATB were encountered during the testing. Feeder modifications and an overbed firing system were necessary. Through statistical analysis, it was shown that the ATB feed location had a greater effect on CO emissions, which were used as an indication of combustion performance, than the fuel type due to the feeding difficulties. Baseline coal tests and tests cofiring ATB into the bed were statistically indistinguishable. Fuel feeding issues would not be expected at the full scale since full-scale units routinely handle low-quality fuels. In a full-scale unit, the disproportionate ratio of feed line size to unit diameter would be eliminated thereby eliminating feed slugging. Also, the ATB would either be injected into the bed, thereby ensuring uniform mixing and complete combustion, or be injected directly above the bed with overfire air ports used to ensure complete combustion. Therefore, it is anticipated that a demonstration at the full scale, which is the next activity in demonstrating this concept, should be successful. As the statistical analysis shows, emissions cofiring ATB with coal would be expected to be similar to that when firing coal only. 14 refs., 5 figs., 6 tabs.

  14. The Contribution of Individual, Social and Work Characteristics to Employee Mental Health in a Coal Mining Industry Population

    PubMed Central

    James, Carole; Wiggers, John; Lewin, Terry; Inder, Kerry; Perkins, David; Handley, Tonelle

    2017-01-01

    Background Evidence regarding the extent of mental health problems and the associated characteristics within an employee population is necessary to inform appropriate and tailored workplace mental health programs. Mental health within male dominated industries (such as mining) has received recent public attention, chiefly through observations regarding suicide in such populations in Australia and internationally. Currently there is limited empirical evidence regarding the mental health needs in the mining industry as an exemplar of a male dominated workforce, and the relative contribution to such problems of individual, socio-economic and workplace factors. This study aimed to investigate the mental health and associated characteristics among employees in the Australian coal mining industry with a specific focus on identifying modifiable work characteristics. Methods A cross-sectional study was conducted among employees (n = 1457) across eight coal mines stratified by key mine characteristics (state, mine type and employee commute arrangements). Participants completed measures of psychological distress (K10+) and key variables across four categories (socio-demographic characteristics, health history, current health behaviours, work attitudes and characteristics). Results Psychological distress levels within this sample were significantly higher in comparison with a community sample of employed Australians. The following factors contributed significantly to levels of psychological distress using hierarchical linear regression analysis: lower social networks; a past history of depression, anxiety or drug/alcohol problems; high recent alcohol use; work role (managers) and a set of work characteristics (level of satisfaction with work, financial factors and job insecurity; perception of lower workplace support for people with mental health problems. Conclusion This is the first study to examine the characteristics associated with mental health problems in the

  15. Multi-scale radiographic applications in microelectronic industry

    NASA Astrophysics Data System (ADS)

    Gluch, J.; Löffler, M.; Meyendorf, N.; Oppermann, M.; Röllig, M.; Sättler, P.; Wolter, K. J.; Zschech, E.

    2016-02-01

    New concepts in assembly technology boost our daily life in an unknown way. High end semiconductor industry today deals with functional structures down to a few nanometers. ITRS roadmap predicts an ongoing decrease of the "DRAM half pitch" over the next decade. Packaging of course is not intended to realize pitches at the nanometer scale, but has to face the challenges of integrating such semiconductor devices with smallest pitch and high pin counts into systems. System integration (SiP, SoP, Hetero System Integration etc.) into the third dimension is the only way to reduce the gap between semiconductor level and packaging level interconnection. The described development is mainly driven by communication technology but also other branches like power electronics benefit from the vast progress in integration and assembly technology. The challenge of advanced packaging requires new nondestructive evaluation (NDE) techniques for technology development and production control. In power electronics production the condition monitoring receives a lot of interest to avoid electrical shortcuts, dead solder joints and interface cracking. It is also desired to detect and characterize very small defects like transportation phenomenon or Kirkendall voids. For this purpose imaging technologies with resolutions in the sub-micron range are required. Our presentation discusses the potentials and the limits of X-ray NDE techniques, illustrated by crack observation in solder joints, evaluation of micro vias in PCBs and interposers and the investigation of solder material composition and other aftermaths of electro migration in solder joints. Applied radiographic methods are X-ray through transmission, multi-energy techniques, laminography, CT and nano-CT.

  16. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, April 1992--June 1992

    SciTech Connect

    Not Available

    1992-09-03

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a ``Coal-Fired Combustion System for Industrial Process Heating Applications`` is project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelling and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the current reporting period, approval of Vortec`s Environmental Assessment (EA) required under the National Environmental Policy Act (NEPA) was approved. The EA approval cycle took approximately 9 months. The preliminary test program which was being held in abeyance pending approval of the EA was initiated. Six preliminary test runs were successfully competed during the period. Engineering and design activities in support of the Phase III proof of concept are continuing, and modifications to the existing test system configuration to allow performance of the preliminary tests were completed.

  17. Coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, April 1995--June 1995

    SciTech Connect

    1995-08-01

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. This includes new installations and those existing installations that were originally designed for oil or gas firing. The data generated by these projects must be sufficient for private-sector decisions on the feasibility of using coal as the fuel of choice. This work should also provide incentives for the private sector to continue and expand the development, demonstration, and application of these combustion systems. Vortec Corporation`s Coal-Fired Combustion System for Industrial Process Heating Applications is being developed under contract DE-AC22-91PC91161 as part of this DOE development program. The current contract represents the third phase of a three-phase development program. Phase I of the program addressed the technical and economic feasibility of the process, and was initiated in 1987 and completed 1989. Phase II was initiated in 1989 and completed in 1990. During Phase II of the development, design improvements were made to critical components and the test program addressed the performance of the process using several different feedstocks. Phase III of the program was initiated September 1991 and is scheduled for completion in 1994. The Phase III research effort is being focused on the development of a process heater system to be used for producing value-added vitrified glass products from boiler/incinerator ashes and selected industrial wastes.

  18. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, April 1993--June 1993

    SciTech Connect

    Not Available

    1993-07-30

    Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a ``Coal-Fired Combustion System for Industrial Process Heating Applications`` is project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the past quarter, the designs of the remaining major components of the integrated system were completed and the equipment was ordered. DOE has elected to modify the scope of the existing R&D program being conducted under this contract to include testing of a simulated TSCA incinerator ash. The modification will be in the form of an additional Task (Task 8 -- TSCA Ash Testing) to the original Statement of Work.

  19. Study of application of ERTS-A imagery to fracture related mine safety hazards in the coal mining industry

    NASA Technical Reports Server (NTRS)

    Wier, C. E.; Wobber, F. J. (Principal Investigator); Russell, O. R.; Amato, R. V.

    1973-01-01

    The author has identified the following significant results. The 70mm black and white infrared photography acquired in March 1973 at an approximate scale of 1:115,000 permits the identification of areas of mine subsidence not readily evident on other films. This is largely due to the high contrast rendition of water and land by this film and the excessive surface moisture conditions prevalent in the area at the time of photography. Subsided areas consist of shallow depressions which have impounded water. Patterns with a regularity indicative of the room and pillar configuration used in subsurface coal mining are evident.

  20. Scale-free phenomenon in industries in China

    NASA Astrophysics Data System (ADS)

    Tang, Da-Hai; Chen, Bo-Kui; Gao, Ya-Chun; Wang, Bing-Hong

    2013-12-01

    In this paper, we investigate the data of industries in China and find that the frequency distributions of fixed assets and fixed-assets’ investment of industries obey power laws. We show that these power-law modes can be explained by the rules of the Simon Model, rather than the existing investment theories such as the classical investment theory or acceleration principle. Moreover, the mechanism of the investment distribution may be similar to the forest-fire model of self-organizing criticality. By introducing the complex system methods, this research changes the traditional opinion of the investment and gains some meaningful understanding in the dynamics of industries and the economic cycle.

  1. Development and testing of a high efficiency advanced coal combustor Phase III industrial boiler retrofit. Quarterly technical progress report, July 1, 1995--September 30, 1995 No. 16

    SciTech Connect

    Borio, R.W.

    1995-12-15

    The objective of this project is to retrofit a burner, capable of firing microfine coal, to a standard gas/oil designed industrial boiler to assess the technical and economic viability of displacing premium fuels with microfine coal. This report documents the technical aspects of this project during the sixteenth quarter (July `95 through September `95) of the program. The overall program has consisted of five major tasks: (1) A review of current state-of-the-art coal firing system components. (2) Design and experimental testing of a prototype HEACC (High Efficiency Advanced Coal Combustor) burner. (3) Installation and testing of a prototype HEACC system in a commercial retrofit application. (4) Economics evaluation of the HEACC concept for retrofit applications. (5) Long term demonstration under commercial user demand conditions.

  2. Large scale solubilization of coal and bioconversion to utilizable energy. Eighth quarterly technical progress report, July 1, 1995--September 30, 1995

    SciTech Connect

    Mishra, N.C.

    1996-02-01

    In order to develop a system for a large scale coal solubilization and its bioconversion to utilizable fuel, we plan to clone the genes encoding Neurospora protein that facilitate depolymerization of coal. We also plan to use desulfurizing bacteria to remove the sulfur in situ and use other microorganisms to convert biosolubilized coal into utilizable energy following an approach utilizing several microorganisms. In addition the product of coal solubilized by fungus will be characterized to determine their chemical nature and the mechanism of reaction catalyzed by fungal product during in vivo and in vitro solubilization by the fungus or purified fungal protein.

  3. Large scale solubilization of coal and bioconversion to utilizable energy. Seventh quarterly technical progress report, April 1, 1995--June 30, 1995

    SciTech Connect

    Mishra, N.C.

    1995-12-01

    In order to develop a system for a large scale coal solubilization and its bioconversion to utilizable fuel, we plan to clone the genes encoding Neurospora protein that facilitate depolymerization of coal. We also plan to use desulfurizing bacteria to remove the sulfur in situ and use other microorganisms to convert biosolubilized coal into utilizable energy following an approach utilizing several microorganisms. In addition the product of coal solubilized by fungus will be characterized to determine their chemical nature and the mechanism of reaction catalyzed by fungal product during in vivo and in vitro solubilization by the fungus or purified fungal protein.

  4. Regional-scale geomechanical impact assessment of underground coal gasification by coupled 3D thermo-mechanical modeling

    NASA Astrophysics Data System (ADS)

    Otto, Christopher; Kempka, Thomas; Kapusta, Krzysztof; Stańczyk, Krzysztof

    2016-04-01

    Underground coal gasification (UCG) has the potential to increase the world-wide coal reserves by utilization of coal deposits not mineable by conventional methods. The UCG process involves combusting coal in situ to produce a high-calorific synthesis gas, which can be applied for electricity generation or chemical feedstock production. Apart from its high economic potentials, UCG may induce site-specific environmental impacts such as fault reactivation, induced seismicity and ground subsidence, potentially inducing groundwater pollution. Changes overburden hydraulic conductivity resulting from thermo-mechanical effects may introduce migration pathways for UCG contaminants. Due to the financial efforts associated with UCG field trials, numerical modeling has been an important methodology to study coupled processes considering UCG performance. Almost all previous UCG studies applied 1D or 2D models for that purpose, that do not allow to predict the performance of a commercial-scale UCG operation. Considering our previous findings, demonstrating that far-field models can be run at a higher computational efficiency by using temperature-independent thermo-mechanical parameters, representative coupled simulations based on complex 3D regional-scale models were employed in the present study. For that purpose, a coupled thermo-mechanical 3D model has been developed to investigate the environmental impacts of UCG based on a regional-scale of the Polish Wieczorek mine located in the Upper Silesian Coal Basin. The model size is 10 km × 10 km × 5 km with ten dipping lithological layers, a double fault and 25 UCG reactors. Six different numerical simulation scenarios were investigated, considering the transpressive stress regime present in that part of the Upper Silesian Coal Basin. Our simulation results demonstrate that the minimum distance between the UCG reactors is about the six-fold of the coal seam thickness to avoid hydraulic communication between the single UCG

  5. Large scale solubilization of coal and bioconversion to utilizable energy. Third quarterly technical progress report, April 1, 1994--June 30, 1994

    SciTech Connect

    Mishra, N.C.

    1994-08-01

    In order to develop a system for a large scale coal solubilization and its bioconversion to utilizable fuel, the investigators plan to clone the genes encoding Neurospora protein that facilitate depolymerization of coal. They also plan to use desulfurizing bacteria to remove the sulfur in situ and use other microorganisms to convert biosolubilized coal into utilizable energy following an approach utilizing several microorganisms. In addition the product of coal solubilized by fungus will be characterized to determine their chemical nature and the mechanism of reaction catalyzed by fungal product during in vivo and in vitro solubilization by the fungus or purified fungal protein. Main objectives are: (1) cloning of Neurospora gene for coal depolymerization protein controlling solubilization in different host cells, utilizing Neurospora plasmid and other vector(s); (2) (a) development of a large scale electrophoretic separation of coal drived products obtained after microbial solubilization; (b) identification of the coal derived products obtained after biosolubilization by Neurospora cultures or obtained after Neurospora enzyme catalyzed reaction in in vitro by the wildtype and mutant enzymes; (3) bioconversion of coal drived products into utilizable fuel; and (4) characterization of Neurospora wildtype and mutant CSA protein(s) involved in solubilization of coal in order to assess the nature of the mechanism of solubilization and the role of Neurospora proteins in this process.

  6. TENORM: Coal Combustion Residuals

    EPA Pesticide Factsheets

    Burning coal in boilers to create steam for power generation and industrial applications produces a number of combustion residuals. Naturally radioactive materials that were in the coal mostly end up in fly ash, bottom ash and boiler slag.

  7. Indonesian coal mining

    SciTech Connect

    2008-11-15

    The article examines the opportunities and challenges facing the Indonesian coal mining industry and how the coal producers, government and wider Indonesian society are working to overcome them. 2 figs., 1 tab.

  8. Annual Coal Report

    EIA Publications

    2016-01-01

    Provides information about U.S. coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves to a wide audience, including Congress, federal and state agencies, the coal industry, and the general public.

  9. Industrial Scale Energy Systems Integration; NREL (National Renewable Energy Laboratory)

    SciTech Connect

    Ruth, Mark

    2015-07-28

    The industrial sector consumes 25% of the total energy in the U.S. and produces 18% of the greenhouse gas (GHG) emissions. Energy Systems Integration (ESI) opportunities can reduce those values and increase the profitability of that sector. This presentation outlines several options. Combined heat and power (CHP) is an option that is available today for many applications. In some cases, it can be extended to trigeneration by adding absorbtion cooling. Demand response is another option in use by the industrial sector - in 2012, industry provided 47% of demand response capacity. A longer term option that combines the benefits of CHP with those of demand response is hybrid energy systems (HESs). Two possible HESs are described and development implications discussed. extended to trigeneration by adding absorbtion cooling. Demand response is another option in use by the industrial sector - in 2012, industry provided 47% of demand response capacity. A longer term option that combines the benefits of CHP with those of demand response is hybrid energy systems (HESs). Two possible HESs are described and development implications discussed.

  10. O absorption measurements in an engineering-scale high-pressure coal gasifier

    NASA Astrophysics Data System (ADS)

    Sun, Kai; Sur, Ritobrata; Jeffries, Jay B.; Hanson, Ronald K.; Clark, Tommy; Anthony, Justin; Machovec, Scott; Northington, John

    2014-10-01

    A real-time, in situ water vapor (H2O) sensor using a tunable diode laser near 1,352 nm was developed to continuously monitor water vapor in the synthesis gas of an engineering-scale high-pressure coal gasifier. Wavelength-scanned wavelength-modulation spectroscopy with second harmonic detection (WMS-2 f) was used to determine the absorption magnitude. The 1 f-normalized, WMS-2 f signal (WMS-2 f/1 f) was insensitive to non-absorption transmission losses including beam steering and light scattering by the particulate in the synthesis gas. A fitting strategy was used to simultaneously determine the water vapor mole fraction and the collisional-broadening width of the transition from the scanned 1 f-normalized WMS-2 f waveform at pressures up to 15 atm, which can be used for large absorbance values. This strategy is analogous to the fitting strategy for wavelength-scanned direct absorption measurements. In a test campaign at the US National Carbon Capture Center, the sensor demonstrated a water vapor detection limit of ~800 ppm (25 Hz bandwidth) at conditions with more than 99.99 % non-absorption transmission losses. Successful unattended monitoring was demonstrated over a 435 h period. Strong correlations between the sensor measurements and transient gasifier operation conditions were observed, demonstrating the capability of laser absorption to monitor the gasification process.

  11. Froude Scaling of Buried Structures Using Coal and Coal/Leas as Simulants for Sand. Volume 1. Study Results

    DTIC Science & Technology

    1993-06-01

    set of test data is the friction angle. For the materials that met the scale factor and stiffness criteria, a series of triaxial compression tests were...search was made of a two plastics databases (References 4 and 5). Since the prototype material properties and the desired scale factors were known...to have even higher density and lower modulus, resulting in scale factors of the order of 1150. Unfortunately, the low coefficient of friction of PTFE

  12. Surface runoff from full-scale coal combustion product pavements during accelerated loading

    SciTech Connect

    Cheng, C.M.; Taerakul, P.; Tu, W.; Zand, B.; Butalia, T.; Wolfe, W.; Walker, H.

    2008-08-15

    In this study, the release of metals and metalloids from full-scale portland cement concrete pavements containing coal combustion products (CCPs) was evaluated by laboratory leaching tests and accelerated loading of full-scale pavement sections under well-controlled conditions. An equivalent of 20 years of highway traffic loading was simulated at the OSU/OU Accelerated Pavement Load Facility (APLF). Three types of portland cement concrete driving surface layers were tested, including a control section (i.e., ordinary portland cement (PC) concrete) containing no fly ash and two sections in which fly ash was substituted for a fraction of the cement; i.e., 30% fly ash (FA30) and 50% fly ash (FA50). In general, the concentrations of minor and trace elements were higher in the toxicity characteristic leaching procedure (TCLP) leachates than in the leachates obtained from synthetic precipitation leaching procedure and ASTM leaching procedures. Importantly, none of the leachate concentrations exceeded the TCLP limits or primary drinking water standards. Surface runoff monitoring results showed the highest release rates of inorganic elements from the FA50 concrete pavement, whereas there were little differences in release rates between PC and FA30 concretes. The release of elements generally decreased with increasing pavement loading. Except for Cr, elements were released as particulates (>0.45 {mu} m) rather than dissolved constituents. The incorporation of fly ash in the PC cement concrete pavements examined in this study resulted in little or no deleterious environmental impact from the leaching of inorganic elements over the lifetime of the pavement system.

  13. Community Economic Identity: The Coal Industry and Ideology Construction in West Virginia

    ERIC Educational Resources Information Center

    Bell, Shannon Elizabeth; York, Richard

    2010-01-01

    Economic changes and the machinations of the treadmill of production have dramatically reduced the number of jobs provided by extractive industries, such as mining and timber, in the United States and other affluent nations in the post-World War II era. As the importance of these industries to national, regional, and local economies wanes,…

  14. Optical and chemical characterization of aerosols emitted from coal, heavy and light fuel oil, and small-scale wood combustion.

    PubMed

    Frey, Anna K; Saarnio, Karri; Lamberg, Heikki; Mylläri, Fanni; Karjalainen, Panu; Teinilä, Kimmo; Carbone, Samara; Tissari, Jarkko; Niemelä, Ville; Häyrinen, Anna; Rautiainen, Jani; Kytömäki, Jorma; Artaxo, Paulo; Virkkula, Aki; Pirjola, Liisa; Rönkkö, Topi; Keskinen, Jorma; Jokiniemi, Jorma; Hillamo, Risto

    2014-01-01

    Particle emissions affect radiative forcing in the atmosphere. Therefore, it is essential to know the physical and chemical characteristics of them. This work studied the chemical, physical, and optical characteristics of particle emissions from small-scale wood combustion, coal combustion of a heating and power plant, as well as heavy and light fuel oil combustion at a district heating station. Fine particle (PM1) emissions were the highest in wood combustion with a high fraction of absorbing material. The emissions were lowest from coal combustion mostly because of efficient cleaning techniques used at the power plant. The chemical composition of aerosols from coal and oil combustion included mostly ions and trace elements with a rather low fraction of absorbing material. The single scattering albedo and aerosol forcing efficiency showed that primary particles emitted from wood combustion and some cases of oil combustion would have a clear climate warming effect even over dark earth surfaces. Instead, coal combustion particle emissions had a cooling effect. Secondary processes in the atmosphere will further change the radiative properties of these emissions but are not considered in this study.

  15. Integrated low emissions cleanup system for coal fueled turbines Phase III bench-scale testing and evaluation

    SciTech Connect

    Newby, R.A.; Alvin, M.A.; Bachovchin, D.M.

    1995-08-01

    The United States Department of Energy, Morgantown Energy Research Center (DOE/METC), is sponsoring the development of coal-fired turbine technologies such as Pressurized Fluidized Bed Combustion (PFBC), coal Gasification Combined Cycles (GCC), and Direct Coal-Fired Turbines (DCFT). A major technical development challenge remaining for coal-fired turbine systems is high-temperature gas cleaning to meet environmental emissions standards, as well as to ensure acceptable turbine life. The Westinghouse Electric Corporation, Science & Technology Center, has evaluated an Integrated Low Emissions Cleanup (ILEC) concept that has been configured to meet this technical challenge. This ceramic hot gas filter (HGF), ILEC concept controls particulate emissions, while simultaneously contributing to the control of sulfur and alkali vapor contaminants in high-temperature, high-pressure, fuel gases or combustion gases. This document reports on the results of Phase III of the ILEC evaluation program, the final phase of the program. In Phase III, a bench-scale ILEC facility has been tested to (1) confirm the feasibility of the ILEC concept, and (2) to resolve some major filter cake behavior issues identified in PFBC, HGF applications.

  16. Coal-Based Oxy-Fuel System Evaluation and Combustor Development; Oxy-Fuel Turbomachinery Development for Energy Intensive Industrial Applications

    SciTech Connect

    Hollis, Rebecca

    2013-03-31

    Clean Energy Systems, Inc. (CES) partnered with the U.S. Department of Energy’s National Energy Technology Laboratory in 2005 to study and develop a competing technology for use in future fossil-fueled power generation facilities that could operate with near zero emissions. CES’s background in oxy-fuel (O-F) rocket technology lead to the award of Cooperative Agreement DE-FC26-05NT42645, “Coal-Based Oxy-Fuel System Evaluation and Combustor Development,” where CES was to first evaluate the potential of these O-F power cycles, then develop the detailed design of a commercial-scale O-F combustor for use in these clean burning fossil-fueled plants. Throughout the studies, CES found that in order to operate at competitive cycle efficiencies a high-temperature intermediate pressure turbine was required. This led to an extension of the Agreement for, “Oxy-Fuel Turbomachinery Development for Energy Intensive Industrial Applications” where CES was to also develop an intermediate-pressure O-F turbine (OFT) that could be deployed in O-F industrial plants that capture and sequester >99% of produced CO2, at competitive cycle efficiencies using diverse fuels. The following report details CES’ activities from October 2005 through March 2013, to evaluate O-F power cycles, develop and validate detailed designs of O-F combustors (main and reheat), and to design, manufacture, and test a commercial-scale OFT, under the three-phase Cooperative Agreement.

  17. POC-Scale Testing of an Advanced Fine Coal Dewatering Equipment/Technique

    SciTech Connect

    Karekh, B K; Tao, D; Groppo, J G

    1998-08-28

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 mm) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy's program to show that ultra-clean coal could be effectively dewatered to 20% or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 45 months beginning September 30, 1994. This report discusses technical progress made during the quarter from January 1 - March 31, 1998.

  18. DEVELOPMENT AND DEMONSTRATION OF A PILOT SCALE FACILITY FOR FABRICATION AND MARKETING OF LIGHTWEIGHT-COAL COMBUSTION BYPRODUCTS-BASED SUPPORTS AND MINE VENTILATION BLOCKS FOR UNDERGROUND MINES

    SciTech Connect

    Yoginder P. Chugh

    2002-10-01

    The overall goal of this program was to develop a pilot scale facility, and design, fabricate, and market CCBs-based lightweight blocks for mine ventilation control devices, and engineered crib elements and posts for use as artificial supports in underground mines to replace similar wooden elements. This specific project was undertaken to (1) design a pilot scale facility to develop and demonstrate commercial production techniques, and (2) provide technical and marketing support to Fly Lite, Inc to operate the pilot scale facility. Fly Lite, Inc is a joint venture company of the three industrial cooperators who were involved in research into the development of CCBs-based structural materials. The Fly-Lite pilot scale facility is located in McLeansboro, Illinois. Lightweight blocks for use in ventilation stoppings in underground mines have been successfully produced and marketed by the pilot-scale facility. To date, over 16,000 lightweight blocks (30-40 pcf) have been sold to the mining industry. Additionally, a smaller width (6-inch) full-density block was developed in August-September 2002 at the request of a mining company. An application has been submitted to Mine Safety and Health Administration for the developed block approval for use in mines. Commercialization of cribs and posts has also been accomplished. Two generations of cribs have been developed and demonstrated in the field. MSHA designated them suitable for use in mines. To date, over 2,000 crib elements have been sold to mines in Illinois. Two generations of posts were also demonstrated in the field and designated as suitable for use in mines by MSHA. Negotiations are currently underway with a mine in Illinois to market about 1,000 posts per year based on a field demonstration in their mine. It is estimated that 4-5 million tons CCBs (F-fly ash or FBC fly ash) may be utilized if the developed products can be commercially implemented in U.S. coal and non-coal mines.

  19. Pilot-Scale Demonstration of ALTA for NOx Control in Pulverized Coal-Fired Boilers

    SciTech Connect

    Andrew Fry; Devin Davis; Marc Cremer; Bradley Adams

    2008-04-30

    This report describes computational fluid dynamics (CFD) modeling and pilot-scale testing conducted to demonstrate the ability of the Advanced Layered Technology Approach (ALTA) to reduce NO{sub x} emissions in a pulverized coal (PC) boiler. Testing specifically focused on characterizing NO{sub x} behavior with deep burner staging combined with Rich Reagent Injection (RRI). Tests were performed in a 4 MBtu/hr pilot-scale furnace at the University of Utah. Reaction Engineering International (REI) led the project team which included the University of Utah and Combustion Components Associates (CCA). Deep burner staging and RRI, combined with selective non-catalytic reduction (SNCR), make up the Advanced Layered Technology Approach (ALTA) for NO{sub x} reduction. The application of ALTA in a PC environment requires homogenization and rapid reaction of post-burner combustion gases and has not been successfully demonstrated in the past. Operation of the existing low-NO{sub x} burner and design and operation of an application specific ALTA burner was guided by CFD modeling conducted by REI. Parametric pilot-scale testing proved the chemistry of RRI in a PC environment with a NOx reduction of 79% at long residence times and high baseline NOx rate. At representative particle residence times, typical operation of the dual-register low-NO{sub x} burner provided an environment that was unsuitable for NO{sub x} reduction by RRI, showing no NOx reduction. With RRI, the ALTA burner was able to produce NO{sub x} emissions 20% lower than the low-NO{sub x} burner, 76 ppmv vs. 94 ppmv, at a burner stoichiometric ratio (BSR) of 0.7 and a normalized stoichiometric ratio (NSR) of 2.0. CFD modeling was used to investigate the application of RRI for NO{sub x} control on a 180 MW{sub e} wall-fired, PC boiler. A NO{sub x} reduction of 37% from baseline (normal operation) was predicted using ALTA burners with RRI to produce a NO{sub x} emission rate of 0.185 lb/MBtu at the horizontal nose of

  20. (Performance evaluation of fabric bag filters on a bench-scale coal gasifier)

    SciTech Connect

    Not Available

    1986-01-15

    The objective of the proposed work is to demonstrate the operational and economic feasibility of using high-temperature ceramic filters for particulate control in a variety of coal gasification power generating systems.

  1. (Performance evaluation of fabric bag filters on a bench-scale coal gasifier)

    SciTech Connect

    Chang, R.; Sawyer, J.; Lips, H.

    1985-07-15

    The objective of the proposed work is to demonstrate the operational and economic feasibility of using high-temperature ceramic filters for particulate control in a variety of coal gasification power generating systems.

  2. (Performance evaluation of fabric bug filters on a bench-scale coal gasifier)

    SciTech Connect

    Not Available

    1986-04-15

    The objective of this proposed work is to demonstrate the operational and economic feasibility of using high-temperature ceramic filters for particulate control in a variety of coal gasification power generating systems.

  3. Industrial-scale radio frequency treatments for insect control in lentils

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Radio frequency (RF) treatments are considered as a potential postharvest technology for disinfesting legumes. After treatment protocols are validated to control postharvest insects without significant quality degradation, it is important to scale-up laboratory RF treatments to industrial applicatio...

  4. Pilot Scale Water Gas Shift - Membrane Device for Hydrogen from Coal

    SciTech Connect

    Barton, Tom

    2013-06-30

    The objectives of the project were to build pilot scale hydrogen separation systems for use in a gasification product stream. This device would demonstrate fabrication and manufacturing techniques for producing commercially ready facilities. The design was a 2 lb/day hydrogen device which included composite hydrogen separation membranes, a water gas shift monolith catalyst, and stainless steel structural components. Synkera Technologies was to prepare hydrogen separation membranes with metallic rims, and to adjust the alloy composition in their membranes to a palladium-gold composition which is sulfur resistant. Chart was to confirm their brazing technology for bonding the metallic rims of the composite membranes to their structural components and design and build the 2 lbs/day device incorporating membranes and catalysts. WRI prepared the catalysts and completed the testing of the membranes and devices on coal derived syngas. The reactor incorporated eighteen 2'' by 7'' composite palladium alloy membranes. These membranes were assembled with three stacks of three paired membranes. Initial vacuum testing and visual inspection indicated that some membranes were cracked, either in transportation or in testing. During replacement of the failed membranes, while pulling a vacuum on the back side of the membranes, folds were formed in the flexible composite membranes. In some instances these folds led to cracks, primarily at the interface between the alumina and the aluminum rim. The design of the 2 lb/day device was compromised by the lack of any membrane isolation. A leak in any membrane failed the entire device. A large number of tests were undertaken to bring the full 2 lb per day hydrogen capacity on line, but no single test lasted more than 48 hours. Subsequent tests to replace the mechanical seals with brazing have been promising, but the technology remains promising but not proven.

  5. The Economics of Rural and Urban Small-Scale Industries in Sierra Leone. African Rural Economy Paper No. 14.

    ERIC Educational Resources Information Center

    Liedholm, Carl; Chuta, Enyinna

    Small-scale industry in Sierra Leone, Africa was examined in terms of: labor intensity; output generated per unit of capital; generation of positive economic profits by small-scale industry groups/processes; and seasonal and locational variations. Key analytical issues were the nature of small-scale industry supply and demand processes. Data were…

  6. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, July 1993--September 1993

    SciTech Connect

    Not Available

    1993-10-30

    This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase 3 research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase 3 project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the past quarter, the major effort was completing some of the system modification installation designs, completing industry funded testing, developing a surrogate TSCA ash composition, and completing the TSCA ash Test Plan. The installation designs will be used for the equipment modifications planned for the end of CY 93. The industry funded testing consisted of vitrifying Spent Aluminum Potliner (SPL) which is a listed hazardous waste. This testing has verified that SPL can be vitrified into a safe, recyclable glass product. Some results from this testing are provided in Section 2.2.1. The surrogate TSCA ash composition was developed with input from various DOE laboratories and subcontractors. The surrogate ash consists of a mixture of MSW fly ash and bottom ash spiked with heavy metal contaminants. The levels of metal additives are sufficient to ascertain the partitioning of the contaminants between the glass and effluent flow streams. Details of the surrogate composition and the planned testing is provided in Section 4.2.2.

  7. Playing the Scales: Regional Transformations and the Differentiation of Rural Space in the Chilean Wine Industry

    ERIC Educational Resources Information Center

    Overton, John; Murray, Warwick E.

    2011-01-01

    Globalization and industrial restructuring transform rural places in complex and often contradictory ways. These involve both quantitative changes, increasing the size and scope of operation to achieve economies of scale, and qualitative shifts, sometimes leading to a shift up the quality/price scale, towards finer spatial resolution and…

  8. Experimental characterization of an industrial pulverized coal-fired furnace under deep staging conditions

    SciTech Connect

    Costa, M.; Azevedo, J.L.T.

    2007-07-01

    Measurements have been performed in a 300 MWe, front-wall-fired, pulverized-coal, utility boiler. This boiler was retrofitted with boosted over fire air injectors that allowed the operation of the furnace under deeper staging conditions. New data are reported for local mean gas species concentration of O{sub 2}, CO, CO{sub 2}, NOx, gas temperatures and char burnout measured at several ports in the boiler including those in the main combustion and staged air regions. Comparisons of the present data with our previous measurements in this boiler, prior to the retrofitting with the new over fire system, show lower O{sub 2} and higher CO concentrations for the new situation as a consequence of the lower stoichiometry in the main combustion zone associated with the present boiler operating condition. Consistently, the measured mean NOx concentrations in the main combustion zone are now lower than those obtained previously, yielding emissions below 500 mg/Nm{sup 3}at 6% O{sub 2}. Finally, the measured values of particle burnout at the furnace exit are acceptable being those measured in the main combustion zone comparable with those obtained with the conventional over fire system.

  9. Development of the industrial scale Ag/Bi-2223 tape

    NASA Astrophysics Data System (ADS)

    Fujikami, J.; Kaneko, T.; Ayai, N.; Kobayashi, S.; Hayashi, K.; Takei, H.; Sato, K.

    2002-10-01

    Tape shaped silver-sheathed Bi-2223 superconducting wire (Bi-2223 tape) technologies are reported. The operations of superconducting apparatus at liquid nitrogen temperature or at 20-30 K are expectable by using Bi-2223-tapes. The reduction of AC loss at 77 K is critical for power cable application, such as electric transmission cable and transformer prototypes. Thinning of the tape thickness and twisting of the tapes are the main techniques for the reduction of AC loss. For the power transformer application, coating technology is investigated to have good electrical insulation. The refrigerator-cooled magnet for industrial use is another example of the superconducting apparatus operating at 20-30 K. It is important to know the critical current density dependence on the applied magnetic field ( Jc- B dependence) for the magnet design. It was confirmed that Jc of the Bi-2223 tape, which shows Jc=30 kA/cm 2 at 77 K in self-magnetic field, exceeds 100 kA/cm 2 at 20 K, and 1 T.

  10. POC-scale testing of an advanced fine coal dewatering equipment/technique

    SciTech Connect

    1998-09-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 pm) clean coal. Economical dewatering of an ultra-fine clean-coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20% or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from July 1 - September 30, 1997.

  11. Coal production 1989

    SciTech Connect

    Not Available

    1990-11-29

    Coal Production 1989 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, reserves, and stocks to a wide audience including Congress, federal and state agencies, the coal industry, and the general public. 7 figs., 43 tabs.

  12. Technology, managerial, and policy initiatives for improving environmental performance in small-scale gold mining industry.

    PubMed

    Hilson, Gavin; Van der Vorst, Rita

    2002-12-01

    This paper reviews a series of strategies for improving environmental performance in the small-scale gold mining industry. Although conditions vary regionally, few regulations and policies exist specifically for small-scale gold mining activity. Furthermore, because environmental awareness is low in most developing countries, sites typically feature rudimentary technologies and poor management practices. A combination of policy-, managerial- and technology-related initiatives is needed to facilitate environmental improvement in the industry. Following a broad overview of these initiatives, a recommended strategy is put forth for governments keen on improving the environmental conditions of resident small-scale gold mines.

  13. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report No. 5, October--December, 1995

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.

    1996-02-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74{mu}m) clean coal. Economical dewatering of an ultrafine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the the University of Kentucky Center for Applied Energy Research will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high sulfur and low sulfur clean coal. Accomplishments for the past quarter are described.

  14. In Developping a Bench-Scale Circulating Fluidized Bed Combustor to Burn High Ash Brazilian Coal-Dolomites Mixtures

    NASA Astrophysics Data System (ADS)

    Ramírez Behainne, Jhon Jairo; Hory, Rogério Ishikawa; Goldstein, Leonardo; Bernárdez Pécora, Araí Augusta

    This work considers some of the questions in burning high ash Brazilian coal-dolomite mixtures in a bench-scale circulating fluidized bed combustor (CFBC). Experimental tests were performed with the CE4500 coal from Santa Catarina State, in southern Brazil, with a Sauter mean diameter d p =43 μm. The coal particles were mixed with dolomite particles of d p = 111 μm and this fuel mixture was fed into the circulating fluidized reactor, previously loaded with quartz sand particles of d p =353 μm. This inert material was previously heated by the combustion of liquefied petroleum gas up to the ignition temperature of the fuel mixture. The CFBC unit has a 100mm internal diameter riser, 4.0m high, as well as a 62.8mm internal diameter downcomer. The loop has a cyclone, a sampling valve to collect particles and a 62.8mm internal diameter L-valve to recirculate the particles in the loop. A screw feeder with a rotation control system was used to feed the fuel mixture to the reactor. The operational conditions were monitored by pressure taps and thermocouples installed along the loop. A data acquisition system showed the main operational conditions to control. Experimental tests performed put in evidence the problems found during bed operation, with special attention to the solids feed device, to the L-valve operation, to particle size, solids inventory, fluidized gas velocity, fuel mixture and recirculated solids feeding positions.

  15. Numerical simulation of ash vaporization during pulverized coal combustion in the laboratory-scale single-burner furnace

    SciTech Connect

    Jiancai Sui; Minghou Xu; Jihua Qiu; Yu Qiao; Yun Yu; Xiaowei Liu; Xiangpeng Gao

    2005-08-01

    CFD tools have been developed to effectively simulate complex, reacting, multiphase flows that exist in utility boilers. In this paper, a model of ash vaporization was established and integrated into a self-developed CFD code to predict ash vaporization in the coal combustion process. Experimental data from a single-particle combustion was used to validate the above model. The calibrated model was then applied to simulate the ash vaporization in a 92.9 kW laboratory-scale single-burner furnace. The effects of different combustion conditions, including air staging, on the ash vaporization were investigated. The results showed that the fraction of ash vaporization is mostly sensitive to coal particle temperature. Ash vaporization primarily occurred after a short interval along the coal particle trajectories when the particle temperatures increased to 1800 K. Air staging influenced the ash vaporization by changing the gas temperature distribution in the furnace. The simulation results showed that the more extreme the staging condition, the lower the overall peak temperature, and hence the lower the amount of ash vaporization. 26 refs., 9 figs.

  16. Bench-scale solid phase biotreatment: Benfield Industries Superfund site

    SciTech Connect

    Marlowe, M.W.; Harper, T.R.; Semenak, R.K.

    1995-12-31

    The Benfield Industries, Inc. Superfund site located in Hazelwood, North Carolina has been found to have approximately 15,000 cubic yards of polycyclic aromatic hydrocarbon (PAH) contaminated soil. Risk based clean up goals were specified at the site for eight target PAH compounds including benzo(a)anthracene, benzo(a)pyrene, benzo(b)fluoranthene, benzo(k)fluoranthene, chrysene, indeno(1,2,3-cd)pyrene, naphthalene, and pentachlorophenol. Treatability studies were performed to evaluate solid phase bioremediation, which includes ex-situ and in-situ land treatment processes, for treatment of the site soil. All treatments were conducted using only indigenous microorganisms maintained under aerobic conditions. Two soil samples with different levels of PAH contamination were collected from the site for use in the treatability evaluations. The two soil samples were contaminated with total PAHs at concentrations of approximately 30 milligrams per kilogram (mg/kg) and 6,000 mg/kg, respectively. Three solid phase bioremediation studies were conducted over a one and one half year period using starting concentrations of total PAHs of approximately 30; 600; and 6,000 mg/kg. The objectives of the studies included determining (1) if clean up goals could be achieved, (2) the approximate biodegradation rate of PAHs in the site soils, and (3) the optimum environmental conditions for biodegradation of the PAHs. Some of the environmental parameters which were varied during the testing included moisture levels, soil conditioners, nutrients and pH. The results of the testing indicated that total and target PAHs can be reduced by up to 90 percent in less than 50 days, depending on environmental conditions maintained in the reactors. Clean up goals for all of the target compounds were achieved at some point during the study.

  17. Emissions from carpet combustion in a pilot-scale rotary kiln: comparison with coal and particle-board combustion

    SciTech Connect

    Stephanie Lucero Konopa; James A. Mulholland; Matthew J. Realff; Paul M. Lemieux

    2008-08-15

    The use of post-consumer carpet as a potential fuel substitute in cement kilns and other high-temperature processes is being considered to address the problem of huge volumes of carpet waste and the opportunity of waste-to-energy recovery. Carpet represents a high volume waste stream, provides high energy value, and contains other recoverable materials for the production of cement. This research studied the emission characteristics of burning 0.46-kg charges of chopped nylon carpet squares, pulverized coal, and particle-board pellets in a pilot-scale natural gas-fired rotary kiln. Carpet was tested with different amounts of water added. Emissions of oxygen, carbon dioxide, nitric oxide (NO), sulfur dioxide (SO{sub 2}), carbon monoxide (CO), and total hydrocarbons and temperatures were continuously monitored. It was found that carpet burned faster and more completely than coal and particle board, with a rapid volatile release that resulted in large and variable transient emission peaks. NO emissions from carpet combustion ranged from 0.06 to 0.15 g/MJ and were inversely related to CO emissions. Carpet combustion yielded higher NO emissions than coal and particleboard combustion, consistent with its higher nitrogen content. S{sub 2} emissions were highest for coal combustion, consistent with its higher sulfur content than carpet or particle board. Adding water to carpet slowed its burn time and reduced variability in the emission transients, reducing the CO peak but increasing NO emissions. Results of this study indicate that carpet waste can be used as an effective alternative fuel, with the caveats that it might be necessary to wet carpet or chop it finely to avoid excessive transient puff emissions due to its high volatility compared with other solid fuels, and that controlled mixing of combustion air might be used to control NO emissions from nylon carpet. 13 refs., 5 figs., 1 tab.

  18. Emissions from carpet combustion in a pilot-scale rotary kiln: comparison with coal and particle-board combustion.

    PubMed

    Konopa, Stephanie Lucero; Mulholland, James A; Realff, Matthew J; Lemieux, Paul M

    2008-08-01

    The use of post-consumer carpet as a potential fuel substitute in cement kilns and other high-temperature processes is being considered to address the problem of huge volumes of carpet waste and the opportunity of waste-to-energy recovery. Carpet represents a high volume waste stream, provides high energy value, and contains other recoverable materials for the production of cement. This research studied the emission characteristics of burning 0.46-kg charges of chopped nylon carpet squares, pulverized coal, and particle-board pellets in a pilot-scale natural gas-fired rotary kiln. Carpet was tested with different amounts of water added. Emissions of oxygen, carbon dioxide, nitric oxide (NO), sulfur dioxide (SO2), carbon monoxide (CO), and total hydrocarbons and temperatures were continuously monitored. It was found that carpet burned faster and more completely than coal and particle board, with a rapid volatile release that resulted in large and variable transient emission peaks. NO emissions from carpet combustion ranged from 0.06 to 0.15 g/MJ and were inversely related to CO emissions. Carpet combustion yielded higher NO emissions than coal and particle-board combustion, consistent with its higher nitrogen content. SO2 emissions were highest for coal combustion, consistent with its higher sulfur content than carpet or particle board. Adding water to carpet slowed its burn time and reduced variability in the emission transients, reducing the CO peak but increasing NO emissions. Results of this study indicate that carpet waste can be used as an effective alternative fuel, with the caveats that it might be necessary to wet carpet or chop it finely to avoid excessive transient puff emissions due to its high volatility compared with other solid fuels, and that controlled mixing of combustion air might be used to control NO emissions from nylon carpet.

  19. Electrostatic precipitation of particulate emissions from the combustion of coal-oil-water and coal-water-slurry in an industrial packaged boiler. Final report

    SciTech Connect

    Noll, C.G.; Dooher, J.R.

    1984-12-01

    The report discusses the results of a research project designed to determine electrostatic-precipitation performance in collecting particulate emissions from coal-oil-water or coal-water slurry fuels. Measurements made on a mobile electrostatic precipitator (ESP) showed that New Source Performance Standards (NSPS) could be met by appropriate design and operation. Coal-oil-water fuels required a specific collection area (SCA) of 340 sq ft/1,000 ACFM flue gas, while coal-water slurry fuel needed 500 sq ft/ACFM flue gas to comply with NSPS. Specific electrode power densities were 200 watts/1,000 ACFM flue gas. The mobile ESP accepted flue gas from a packaged fire-tube boiler converted to coal-slurry firing. The fully instrumented boiler produced a fly-ash high-in carbon content, especially when burning CWS fuel. The high carbon content influenced fly-ash resistivity vs. temperature curves and must be taken into account in designing an ESP for this kind of service.

  20. PROTOTYPE SCALE TESTING OF LIMB TECHNOLOGY FOR A PULVERIZED-COAL-FIRED BOILER

    EPA Science Inventory

    The report summarizes results of an evaluation of furnace sorbent injection (FSI) to control sulfur dioxide (SO2) emissions from coal-fired utility boilers. (NOTE: FSI of calcium-based sorbents has shown promise as a moderate SO2 removal technology.) The Electric Power Research I...

  1. Coal production and transportation

    SciTech Connect

    Not Available

    1981-01-01

    Sixteen papers covering a wide variety of topics relevant to today's coal industry and a panel discussion on railroad deregulation and coal unit train rates were presented at the Seventh Annual PLM Coal Conference on Coal Production and Transportation. This volume contains all of these papers, which cover the topics ranging from acid rain to project financing, from slurry pipelines to barge and railroad transportation, as well as the panel discussion. All papers have been abstracted and indexed.

  2. Coal Extraction - Environmental Prediction

    USGS Publications Warehouse

    Cecil, C. Blaine; Tewalt, Susan J.

    2002-01-01

    Coal from the Appalachian region has supplied energy to the Nation for more than 200 years. Appalachian coal fueled America through a civil war and helped win two world wars. Appalachian coal has also provided fuel for keeping America warm in the winter and cool in the summer and has served as the basis for the steel, automobile, organic chemicals, chlorine, and aluminum industries. These benefits have not come without environmental costs, however. Coal extraction and utilization have had significant environmental impacts.

  3. POC-scale testing of an advanced fine coal dewatering equipment/technique: Quarterly technical progress report No. 9, October 1996--December 1996

    SciTech Connect

    Tao, D.; Groppo, J.G.; Parekh, B.K.

    1997-01-21

    The advanced fine-coal cleaning techniques such as column flotation, recovers a low-ash ultra-fine size clean-coal product. However, economical dewatering of the clean coal product to less than 20 percent moisture using conventional technology is difficult. This research program objective is to evaluate a novel coal surface modification technique developed at the University of Kentucky Center for Applied Energy Research in conjunction with conventional and advanced dewatering technique at a pilot scale at the Powell Mountain Coal Company`s Mayflower preparation plant located in St. Charles, VA. During this quarter in the laboratory dewatering studies were conducted using copper and aluminum ions showed that for the low sulfur clean coal slurry addition of 0.1 Kg/t of copper ions was effective in lowering the filter cake moisture from 29 percent to 26.3 percent. Addition of 0.3 Kg/t of aluminum ions provided filter cake with 28 percent moisture. For the high sulfur clean coal slurry 0.5 Kg/t of copper and 0.1 Kg/t of aluminum ions reduced cake moisture from 30.5 percent to 28 percent respectively. Combined addition of anionic (10 g/t) and cationic (10 g/t) flocculants was effective in providing a filter cake with 29.8 percent moisture. Addition of flocculants was not effective in centrifuge dewatering. In pilot scale screen bowl centrifuge dewatering studies it was found that the clean coal slurry feed rate of 30 gpm was optimum to the centrifuge, which provided 65 percent solids capture. Addition of anionic or cationic flocculants was not effective in lowering of filter cake moisture, which remained close to 30 percent for both clean coal slurries.

  4. Coal Activities for Secondary Students.

    ERIC Educational Resources Information Center

    American Coal Foundation, Washington, DC.

    This collection of lesson plans designed for teachers of 4th- through 12th-grade students utilizes an assortment of teaching strategies for topics related to coal and the coal industry. Activities cover the following topics: coal formation; coal identification; "the geologist's dilemma" (a supply and demand activity); geologic time and…

  5. Coal market momentum converts skeptics

    SciTech Connect

    Fiscor, S.

    2006-01-15

    Tight supplies, soaring natural gas prices and an improving economy bode well for coal. Coal Age presents it 'Forecast 2006' a survey of 200 US coal industry executives. Questions asked included predicted production levels, attitudes, expenditure on coal mining, and rating of factors of importance. 7 figs.

  6. POC-scale testing of a dry triboelectrostatic separator for fine coal cleaning. First quarterly technical progress report, September 27, 1995--December 31, 1995

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.; Adel, G.T.

    1995-12-31

    The Pittsburgh Energy Technology Center (PETC) developed a triboelectrostatic separation (TES) process which is capable of removing mineral matter from coal without using water. A distinct advantage of this dry coal cleaning process is that it does not entail costly steps of dewatering which is a common problem associated with conventional fine coal cleaning processes. It is the objective of this project to conduct a series of proof-of-concept (POC) scale tests at a throughput of 200--250 kg/hr and obtain scale- up information. Prior to the POC testing, bench-scale test work will be conducted with the objective of increasing the separation efficiency and throughput, for which changes in the basic designs for the charger and the separator may be necessary. The bench- and POC- scale test work will be carried out to evaluate various operating parameters and establish a reliable scale-up procedure. The scale-up data will be used to analyze the economic merits of the TES process. During the past quarter, a number of project tasks have been initiated. All documents required for project startup (i.e., work plans, management plans, etc.) have been submitted to DOE for approval. A bench-scale TES unit and an apparatus for studying tribocharging mechanisms have been designed and are currently being fabricated. One of the three coal samples to be used for bench-scale testing has been acquired.

  7. Accomplishments in genome-scale in silico modeling for industrial and medical biotechnology

    PubMed Central

    Milne, Caroline B.; Kim, Pan-Jun; Eddy, James A.; Price, Nathan D.

    2011-01-01

    Driven by advancements in high-throughput biological technologies and the growing number of sequenced genomes, the construction of in silico models at the genome scale has provided powerful tools to investigate a vast array of biological systems and applications. Here, we review comprehensively the uses of such models in industrial and medical biotechnology, including biofuel generation, food production, and drug development. While the use of in silico models is still in its early stages for delivering to industry, significant initial successes have been achieved. For the cases presented here, genome-scale models predict engineering strategies to enhance properties of interest in an organism or to inhibit harmful mechanisms of pathogens or in disease. Going forward, genome-scale in silico models promise to extend their application and analysis scope to become a transformative tool in biotechnology. As such, genome-scale models can provide a basis for rational genome-scale engineering and synthetic biology. PMID:19946878

  8. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal, Annual Progress Report, October 1, 2003 through September 30, 2004

    SciTech Connect

    Andresen, John; Schobert, Harold; Miller, Bruce G

    2006-03-01

    Since 1998, The Pennsylvania State University (PSU) has been successfully operating the Consortium for Premium Carbon Products from Coal (CPCPC), which is a vehicle for industry-driven research on the promotion, development, and transfer of innovative technology on premium carbon produces from coal to the U.S. industry. The CPCPC is an initiative being led by PSU, its co-charter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provides the base funding for the program, with PSU responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity has continued under the present cooperative agreement, No. DE-FC26-03NT41874, which started October 1, 2003. The objective of the second agreement is to continue the successful operation of the CPCPC. The CPCPC has enjoyed tremendous success with its organizational structure, that includes PSU and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC is its industry-led council that selects proposals submitted by CPCPC members to ensure CPCPC target areas have strong industrial support. A second contract was executed with DOE NETL starting in October 2003 to continue the activities of CPCPC. An annual funding meeting was held in October 2003 and the council selected 10 projects for funding. Base funding for the projects is provided by NETL with matching funds from industry. Subcontracts were let from Penn State to the various subcontractors on March 1, 2004.

  9. Allergen sanitation in the food industry: a systematic industrial scale approach to reduce hazelnut cross-contamination of cookies.

    PubMed

    Röder, Martin; Baltruweit, Iris; Gruyters, Helwig; Ibach, Anja; Mücke, Ingo; Matissek, Reinhard; Vieths, Stefan; Holzhauser, Thomas

    2010-09-01

    Recently, we investigated the impact of shared equipment on cross-contamination of cookies at a pilot plant scale. Based on those findings, this study investigated the extent and subsequent sanitation of hazelnut cross-contamination (HNCC) of cookies at the industrial scale. Similarly, a product change from cookies with hazelnut ingredient to cookies without hazelnut was performed on standard equipment. HNCC in the hazelnut-free follow-up product was quantified by enzyme-linked immunosorbent assay for each production device and the applied cleaning procedure. All experiments were repeated in duplicate. The highest HNCC was found in concordance with previous studies after mere mechanical scraping: more than 1,000 mg of hazelnut protein per kg was quantified in the follow-up product after processing by a cookie machine. Additional cleaning with hot water decreased the HNCC irrespective of the processing device to levels at or below 1 mg of hazelnut protein per kg. Furthermore, raw materials for cookie production were monitored over a period of 24 months for unwanted preloads of hazelnut and peanut: hazelnut was quantified in 16% of the investigated raw materials as being between 0.26 and 90 mg/kg. Further critical control points at the industrial scale, where cross-contamination might occur, were identified but did not display noteworthy sources of cross-contamination. In conclusion, the quantitative monitoring of the cleaning efficiency at the industrial scale confirmed the procedure of manual scraping plus wet cleaning as a qualified sanitation procedure to effectively reduce the hazelnut protein cross-contamination down to a level at which severe hazelnut-related allergic reactions are unlikely to occur.

  10. Catalytic Two-Stage Liquefaction (CTSL{trademark}) process bench studies and PDU scale-up with sub-bituminous coal. Final report

    SciTech Connect

    Comolli, A.G.; Johanson, E.S.; Karolkiewicz, W.F.; Lee, L.K.T.; Stalzer, R.H.; Smith, T.O.

    1993-03-01

    Reported are the details and results of Laboratory and Bench-Scale experiments using sub-bituminous coal conducted at Hydrocarbon Research, Inc., under DOE Contract No. DE-AC22-88PC88818 during the period October 1, 1988 to December 31, 1992. The work described is primarily concerned with testing of the baseline Catalytic Two-Stage Liquefaction (CTSL{trademark}) process with comparisons with other two stage process configurations, catalyst evaluations and unit operations such as solid separation, pretreatments, on-line hydrotreating, and an examination of new concepts. In the overall program, three coals were evaluated, bituminous Illinois No. 6, Burning Star and sub-bituminous Wyoming Black Thunder and New Mexico McKinley Mine seams. The results from a total of 16 bench-scale runs are reported and analyzed in detail. The runs (experiments) concern process variables, variable reactor volumes, catalysts (both supported, dispersed and rejuvenated), coal cleaned by agglomeration, hot slurry treatments, reactor sequence, on-line hydrotreating, dispersed catalyst with pretreatment reactors and CO{sub 2}/coal effects. The tests involving the Wyoming and New Mexico Coals are reported herein, and the tests involving the Illinois coal are described in Topical Report No. 2. On a laboratory scale, microautoclave tests evaluating coal, start-up oils, catalysts, thermal treatment, CO{sub 2} addition and sulfur compound effects were conducted and reported in Topical Report No. 3. Other microautoclave tests are described in the Bench Run sections to which they refer such as: rejuvenated catalyst, coker liquids and cleaned coals. The microautoclave tests conducted for modelling the CTSL{trademark} process are described in the CTSL{trademark} Modelling section of Topical Report No. 3 under this contract.

  11. Total population study of factors affecting chronic bronchitis prevalence in the coal mining industry of New South Wales, Australia.

    PubMed Central

    Leigh, J; Wiles, A N; Glick, M

    1986-01-01

    The period prevalence of simple chronic bronchitis (SCB) (mucus hypersecretion), defined as chronic cough and sputum production by the MRC respiratory symptom questionnaire administered by occupational physicians and of obstructive chronic bronchitis (OCB) (airflow obstruction) (defined as SCB plus FEV1 less than 80% predicted) have been measured over the period 30 June 1977-30 June 1980 in the entire work force aged between 21 and 60 of the coal industry of New South Wales, Australia (12 357 men). Four dimensional contingency table analysis by a logistic transform method showed highly significant (p less than 0.001) additive affects of age (exposure duration), site of work, smoking, and alcohol consumption on development of overall chronic bronchitis (SCB + OCB). Odds ratios were face work:surface work = 1.78:1, smoker:non-smoker = 4.23:1, alcohol greater than 300 g/wk:alcohol less than 300 g/wk = 2.13:1. There was no evidence for synergistic effects of these factors on the development of mucus hypersecretion. When OCB was analysed separately, the effect of site of work, although in the same direction, was not statistically significant and this was assumed to be due to a "healthy worker" effect or a "swamping" effect of smoking. Age, smoking, and alcohol effects were highly significant (p less than 0.0001) and there was a sharp increase in prevalence of OCB in the age groups 41-50 and 51-60. Odds ratios were face work:surface work = 1.11:1, smoker:non-smoker = 2.66:1, alcohol greater than 300 g/wk:alcohol less than 300 g/wk = 2.91:1. There was no evidence of synergistic effects. These results are consistent with a hypothesis of additive effects of smoking, alcohol, and coal mine dust and fumes on the development of chronic mucus hypersecretion leading to airflow obstruction or a hypothesis of similar additive effects on the development of two separate conditions--mucus hypersecretion with airflow obstruction and mucus hypersecretion without airflow obstruction

  12. Development & Testing of Industrial Scale, Coal Fired Combustion System, Phase 3

    SciTech Connect

    Bert Lauderer

    1998-01-17

    In the fourth quarter of calendar year 1997, 11 days of tests on the 20 MMBtu/hr combustor-boiler facility were performed as part of a parallel project on sulfur capture in slag. No work was performed on the present project in this quarter. The total test days on the Philadelphia facility to the end of December 1997 was 103, of which 30 tests were part of the other DOE project. This exceeds the planned 63 test days for this project. All key project objectives have been exceeded including combustor durability, automated combustor operation, NO emissions as x low as 0.07 lb/MMBtu and SO emissions as low as 0.2 lb/MMBtu. In addition, a novel post- 2 combustion NOx control process has been tested on a 37 MW and 100 MW utility boiler. Any further tests will depend on the results of evaluations of current and prior tests. The only effort remaining on this project is facility disassembly and Final Report. This report also contains clarification of project results reported in the 22 Quarterly Technical Report in response to nd comments by DOE.

  13. Development & Testing of Industrial Scale, Coal Fired Combustion System, Phase 3

    SciTech Connect

    Bert Lauderer

    1998-04-01

    In the first quarter of calendar year 1998, 4 days of tests on the 20 MMBtu/hr combustor-boiler facility were performed as part of a parallel project on sulfur capture in slag. No work was performed on the present project in this quarter. The total test days on the Philadelphia facility to the end of March 1998 was 108, of which 34 tests were part of the other DOE project. This exceeds the planned 63 test days for this project. All key project objectives have been exceeded including combustor durability, automated combustor operation, NOx emissions as low as 0.07 lb/MMBtu and SO2 emissions as low as 0.2 lb/MMBtu. In addition, a novel post-combustion NOx control process has been tested on a 37 MW and 100 MW utility boiler. Any further tests will depend on the results of evaluations of current and prior tests. The only effort remaining on this project is facility disassembly and Final Report. Almost all of the effort in the present quarter focussed on applying the results of this project and the parallel sulfur capture in slag project on new applications of this technology. Several very promising areas were identified and a number of proposals to implement them were prepared.

  14. Cyclone reburn using coal-water fuel: Pilot-scale development and testing

    SciTech Connect

    Eckhart, C.F.; DeVault, R.F.

    1991-10-01

    There is an ongoing effort to develop retrofit technologies capable of converting oil- and/or gas-fired boilers to coal combustion. The objective of this project is to demonstrate the technical feasibility of an improved portion of a previously developed retrofit system designed for the purpose of converting oil/gas boilers. This improvement would almost entirely eliminate the use of premium fuels, thereby significantly increasing the economical attractiveness of the system. Specifically, the goals in this program were to replace natural gas as a reburning fuel with coal-water fuel (CWF). The advantages of such a system include: (1) increased return on investment (ROI) for conversions; (2) nearly complete elimination of premium oil or gas fuel; (3) a more integrated approach to the conversion of oil- or gas-designed boilers to CWF.

  15. Cyclone reburn using coal-water fuel: Pilot-scale development and testing. Final report

    SciTech Connect

    Eckhart, C.F.; DeVault, R.F.

    1991-10-01

    There is an ongoing effort to develop retrofit technologies capable of converting oil- and/or gas-fired boilers to coal combustion. The objective of this project is to demonstrate the technical feasibility of an improved portion of a previously developed retrofit system designed for the purpose of converting oil/gas boilers. This improvement would almost entirely eliminate the use of premium fuels, thereby significantly increasing the economical attractiveness of the system. Specifically, the goals in this program were to replace natural gas as a reburning fuel with coal-water fuel (CWF). The advantages of such a system include: (1) increased return on investment (ROI) for conversions; (2) nearly complete elimination of premium oil or gas fuel; (3) a more integrated approach to the conversion of oil- or gas-designed boilers to CWF.

  16. Recovery Act: Oxy-Combustion Technology Development for Industrial-Scale Boiler Applications

    SciTech Connect

    Levasseur, Armand

    2014-01-01

    This Topical Report outlines guidelines and key considerations for design and operation of pulverized coal-fired boilers for oxy-combustion. The scope addressed includes only the boiler island, not the entire oxy-fired CO{sub 2} capture plant. These guidelines are primarily developed for tangential-fired boilers and focus on designs capable of dual air and oxy-fired operation. The guidelines and considerations discussed are applicable to both new units and existing boiler retrofits. These guidelines are largely based on the findings from the extensive 15 MW{sub th} pilot testing and design efforts conducted under this project. A summary level description is provided for each major aspect of boiler design impacted by oxy-combustion, and key considerations are discussed for broader application to different utility and industrial designs. Guidelines address the boiler system arrangement, firing system, boiler thermal design, ducting, materials, control system, and other key systems.

  17. Development of pressurized coal partial combustor

    SciTech Connect

    Yoshida, K.; Ino, T.; Yamamoto, T.; Kimura, N.

    1995-12-31

    The integrated gasification combined cycle (IGCC), an environment-friendly power generation system of high thermal efficiency, is being developed via various approaches around the world. The oxygen-blown entrained flow gasification process is a relatively simple method of producing medium calorie coal gas suitable for application to gas turbines. Various systems for this process have been developed to a demonstration level in Europe and America. Japan has actively been developing the air-blown process. However, taking stable molten slag discharge into consideration, coal must be supplied at two stages to raise the combustor temperature in ash molten part. Only two reports have been presented regarding two-stage coal supply. One is the report on an experiment with the Hycol gasifier, in which air feed ratio is varied, with coal feed fixed. The other is report on a simulation study with various gasifier coal feed ratios, conducted at Central Research Institute of Electric Power Industry. It seems that the appropriate feed ratio has not yet been established. Through this activity, a unique furnace construction has been established, and these influences of stoichiometric air ratio, of oxygen enrichment, of char recycling and of coal types on performance have been clarified. The purpose of the present study is to apply this developed CPC techniques to a Pressurized CPC (PCPC), thereby improving the IGCC technology. For the present study, we conducted systematic experiments on the air-blown process with a two stage dry feed system, using a 7 t/d-coal bench scale PCPC test facility, operated at the pressure of 0.4 MPa, and clarified the influence of coal feed ratio on coal gasification performance. This report describes the above-mentioned bench scale test procedures and results, and also some informations about a plan of a 25 t/d-coal pilot test system.

  18. Advanced coal-fueled gas turbine systems

    SciTech Connect

    Wenglarz, R.A.

    1994-08-01

    Several technology advances since the early coal-fueled turbine programs that address technical issues of coal as a turbine fuel have been developed in the early 1980s: Coal-water suspensions as fuel form, improved methods for removing ash and contaminants from coal, staged combustion for reducing NO{sub x} emissions from fuel-bound nitrogen, and greater understanding of deposition/erosion/corrosion and their control. Several Advanced Coal-Fueled Gas Turbine Systems programs were awarded to gas turbine manufacturers for for components development and proof of concept tests; one of these was Allison. Tests were conducted in a subscale coal combustion facility and a full-scale facility operating a coal combustor sized to the Allison Model 501-K industrial turbine. A rich-quench-lean (RQL), low nitrogen oxide combustor design incorporating hot gas cleanup was developed for coal fuels; this should also be applicable to biomass, etc. The combustor tests showed NO{sub x} and CO emissions {le} levels for turbines operating with natural gas. Water washing of vanes from the turbine removed the deposits. Systems and economic evaluations identified two possible applications for RQL turbines: Cogeneration plants based on Allison 501-K turbine (output 3.7 MW(e), 23,000 lbs/hr steam) and combined cycle power plants based on 50 MW or larger gas turbines. Coal-fueled cogeneration plant configurations were defined and evaluated for site specific factors. A coal-fueled turbine combined cycle plant design was identified which is simple, compact, and results in lower capital cost, with comparable efficiency and low emissions relative to other coal technologies (gasification, advanced PFBC).

  19. Study of application of ERTS-A imagery to fracture-related mine safety hazards in the coal mining industry

    NASA Technical Reports Server (NTRS)

    Wier, C. E.; Wobber, F. J.; Russell, O. R.; Martin, K. R. (Principal Investigator)

    1973-01-01

    The author has identified the following significant results. Mined land reclamation analysis procedures developed within the Indiana portion of the Illinois Coal Basin were independently tested in Ohio utilizing 1:80,000 scale enlargements of ERTS-1 image 1029-15361-7 (dated August 21, 1972). An area in Belmont County was selected for analysis due to the extensive surface mining and the different degrees of reclamation occurring in this area. Contour mining in this area provided the opportunity to extend techniques developed for analysis of relatively flat mining areas in Indiana to areas of rolling topography in Ohio. The analysts had no previous experience in the area. Field investigations largely confirmed office analysis results although in a few areas estimates of vegetation percentages were found to be too high. In one area this error approximated 25%. These results suggest that systematic ERTS-1 analysis in combination with selective field sampling can provide reliable vegetation percentage estimates in excess of 25% accuracy with minimum equipment investment and training. The utility of ERTS-1 for practical and reasonably reliable update of mined lands information for groups with budget limitations is suggested. Many states can benefit from low cost updates using ERTS-1 imagery from public sources.

  20. [The role, objectives and usefulness of medico-legal determinations in post-accidental procedures in traumatic deaths in hard coal-mining industry].

    PubMed

    Skowronek, Rafał; Chowaniec, Czesław

    2009-01-01

    The underground hard coal-mining sector demonstrates one of the highest rates of fatal accidents, in spite of a decline in coal-mining over the last few years. Post-accidental investigations, including forensic medical expertise, continue to present a significant problem. The objective of the research was to evaluate the role, tasks and usefulness of medico-legal determinations in post-accidental procedures in traumatic deaths in hard coal-mining industry. The study was carried out retrospectively by investigating files and autopsy reports, with attention focusing on the scope of necessary activities and medico-legal examinations in order to determine the cause and manner of death, and on identification of fatalities, especially in the cases of collective occupational accidents. Complex medico-legal determinations (identification, autopsy), supplemented by additional investigations (toxicology, histopathology and hemogenetics) provide a valuable source of evidence for legal authorities and post-accidental commissions. Mutual cooperation of the experts representing various branches of science is the basis of executing appropriate procedures after a traumatic death in the coal mine.

  1. Modeling industrial centrifugation of mammalian cell culture using a capillary based scale-down system.

    PubMed

    Westoby, Matthew; Rogers, Jameson K; Haverstock, Ryan; Romero, Jonathan; Pieracci, John

    2011-05-01

    Continuous-flow centrifugation is widely utilized as the primary clarification step in the recovery of biopharmaceuticals from cell culture. However, it is a challenging operation to develop and characterize due to the lack of easy to use, small-scale, systems that can be used to model industrial processes. As a result, pilot-scale continuous centrifugation is typically employed to model large-scale systems requiring a significant amount of resources. In an effort to reduce resource requirements and create a system which is easy to construct and utilize, a capillary shear device, capable of producing energy dissipation rates equivalent to those present in the feed zones of industrial disk stack centrifuges, was developed and evaluated. When coupled to a bench-top, batch centrifuge, the capillary device reduced centrate turbidity prediction error from 37% to 4% compared to using a bench-top centrifuge alone. Laboratory-scale parameters that are analogous to those routinely varied during industrial-scale continuous centrifugation were identified and evaluated for their utility in emulating disk stack centrifuge performance. The resulting relationships enable bench-scale process modeling of continuous disk stack centrifuges using an easily constructed, scalable, capillary shear device coupled to a typical bench-top centrifuge.

  2. Nano-Scale Interpenetrating Phase Composites (IPC S) for Industrial and Vehicle Applications

    SciTech Connect

    Hemrick, James Gordon; Hu, Michael Z.

    2010-06-01

    A one-year project was completed at Oak Ridge National Laboratory (ORNL) to explore the technical and economic feasibility of producing nano-scale Interpenetrating Phase Composite (IPC) components of a usable size for actual testing/implementation in a real applications such as high wear/corrosion resistant refractory shapes for industrial applications, lightweight vehicle braking system components, or lower cost/higher performance military body and vehicle armor. Nano-scale IPC s with improved mechanical, electrical, and thermal properties have previously been demonstrated at the lab scale, but have been limited in size. The work performed under this project was focused on investigating the ability to take the current traditional lab scale processes to a manufacturing scale through scaling of these processes or through the utilization of an alternative high-temperature process.

  3. Development of a coal-fired combustion system for industrial process heating applications. Phase 3 final report, November 1992--December 1994

    SciTech Connect

    1995-09-26

    A three phase research and development program has resulted in the development and commercialization of a Cyclone Melting System (CMS{trademark}), capable of being fueled by pulverized coal, natural gas, and other solid, gaseous, or liquid fuels, for the vitrification of industrial wastes. The Phase 3 research effort focused on the development of a process heater system to be used for producing value added glass products from the vitrification of boiler/incinerator ashes and industrial wastes. The primary objective of the Phase 3 project was to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential for successful commercialization. The demonstration test consisted of one test run with a duration of 105 hours, approximately one-half (46 hours) performed with coal as the primary fuel source (70% to 100%), the other half with natural gas. Approximately 50 hours of melting operation were performed vitrifying approximately 50,000 lbs of coal-fired utility boiler flyash/dolomite mixture, producing a fully-reacted vitrified product.

  4. Development of a coal-fired combustion system for industrial processing heating applications: Appendix A. Phase 3 final report, November 1992--December 1994

    SciTech Connect

    1995-09-26

    A three phase research and development program has resulted in the development and commercialization of a Cyclone Melting System (CMS{trademark}), capable of being fueled by pulverized coal, natural gas, and other solid, gaseous, or liquid fuels, for the vitrification of industrial wastes. The Phase 3 research effort focused on the development of a process heater system to be used for producing value added glass products from the vitrification of boiler/incinerator ashes and industrial wastes. The primary objective of the Phase 3 project was to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential for successful commercialization. The demonstration test consisted of one test run with a duration of 105 hours, approximately one-half (46 hours) performed with coal as the primary fuel source (70% to 100%), the other half with natural gas. Approximately 50 hours of melting operation were performed vitrifying approximately 50,000 lbs of coal-fired utility boiler flyash/dolomite mixture, producing a fully-reacted vitrified product. Appendix A contains 89 figures containing the data from the demonstration tests undertaken under Phase 3.

  5. Computer Aided Design of Advanced Turbine Airfoil Alloys for Industrial Gas Turbines in Coal Fired Environments

    SciTech Connect

    G.E. Fuchs

    2007-12-31

    Recent initiatives for fuel flexibility, increased efficiency and decreased emissions in power generating industrial gas turbines (IGT's), have highlighted the need for the development of techniques to produce large single crystal or columnar grained, directionally solidified Ni-base superalloy turbine blades and vanes. In order to address the technical difficulties of producing large single crystal components, a program has been initiated to, using computational materials science, better understand how alloy composition in potential IGT alloys and solidification conditions during processing, effect castability, defect formation and environmental resistance. This program will help to identify potential routes for the development of high strength, corrosion resistant airfoil/vane alloys, which would be a benefit to all IGT's, including small IGT's and even aerospace gas turbines. During the first year, collaboration with Siemens Power Corporation (SPC), Rolls-Royce, Howmet and Solar Turbines has identified and evaluated about 50 alloy compositions that are of interest for this potential application. In addition, alloy modifications to an existing alloy (CMSX-4) were also evaluated. Collaborating with SPC and using computational software at SPC to evaluate about 50 alloy compositions identified 5 candidate alloys for experimental evaluation. The results obtained from the experimentally determined phase transformation temperatures did not compare well to the calculated values in many cases. The effects of small additions of boundary strengtheners (i.e., C, B and N) to CMSX-4 were also examined. The calculated phase transformation temperatures were somewhat closer to the experimentally determined values than for the 5 candidate alloys, discussed above. The calculated partitioning coefficients were similar for all of the CMSX-4 alloys, similar to the experimentally determined segregation behavior. In general, it appears that computational materials science has become a

  6. Development of a retrofit coal combustor for industrial applications, (Phase 1-A). Technical progress report, July--September 1988

    SciTech Connect

    Not Available

    1988-10-01

    During this past quarter, two tandem-fired pulse combustors were designed to fire at a nominal rate of 3.5 to 5.5 MMBtu/hr under continuation of Phase I work on DOE project DE-AC22-87PC79654. In prior work, MTCI demonstrated the operation of a 1--2 MMBtu/h coal-fired tandem pulse combustor that is intended for small industrial applications. These component tests emphasized verification of key design issues such as combustor coupling, slag rejection, and staged air addition. The current work, which represents an extension of the Phase I effort, focuses on integrated testing of the tandem pulse combustor with a fire-tube boiler, and the addition of a slag quench vessel. A tandem-fired pulse combustion unit designed to fire at a nominal rate of 3.5-5 MMBtu/hr was designed and fabricated. The configuration includes two combustion chambers cast in a single monolith, tailpipes cast separately with annular air preheating capability, and a cyclonic decoupler. Design analysis and evaluations were performed to optimize the system with respect to minimizing heat losses, size, and cost. Heat losses from the combustor and decoupler walls are predicted to be approximately 3 percent. The final designs for the ancillary items (slag quench, tertiary air addition, scrubber and sampling system) were completed and fabrication and installation initiated. A Cleaver-Brooks 150 hp-4 pass boiler was delivered and installed and modifications for interfacing with the retrofit pulse combustor unit completed. A below-ground slag collection pit was excavated to permit direct in-line coupling of the combustor to the boiler and to reduce head-room requirements. The pit is 30 inches deep and lined with waterproof and fireproof siding.

  7. A two-scale system to identify environmental risk of chemical industry clusters.

    PubMed

    Huang, Lei; Wan, Wenbo; Li, Fengying; Li, Bing; Yang, Jie; Bi, Jun

    2011-02-15

    Recent reform policies in China have spurred rapid industrial development. This has led to a large increase in chemical accidents, which may have catastrophic impacts on the local population and environment. As industrial facilities become more complex, it becomes more difficult to control and mitigate the risks associated with chemical accidents. In this study, we propose a two-scale system for assessing the environmental risk level of chemical industry clusters. A series of risk early warning indices for both the plant-specific level and regional clusters level are used in this system. Firstly, at the enterprise scale, a risk early warning index is constructed using inputs such as the presence of hazardous materials, the operation of critical plant equipment and the efficiency of extant management techniques. Secondly, an index for quantifying risks on regional scales depends on environmental, economic, and social conditions as well as the specific enterprises' components. As an illustration, the system is applied to a case study involving a five-plant chemical industry cluster in Jiangsu province, China. A geographical information system-based methodology is used to obtain a composite index score for each mesh of the five plants. The results prove that the proposed two-scale early warning system can efficiently identify environmental risk and help guide emergency responses at both the enterprise and cluster level.

  8. Software sensor design considering oscillating conditions as present in industrial scale fed-batch cultivations.

    PubMed

    Lyubenova, V; Junne, S; Ignatova, M; Neubauer, P

    2013-07-01

    Investigations of inhomogeneous dynamics in industrial-scale bioreactors can be realized in laboratory simulators. Such studies will be improved by on line observation of the growth of microorganisms and their product synthesis at oscillating substrate availability which represents the conditions in industrial-scale fed-batch cultivations. A method for the kinetic monitoring of such processes, supported by on line measurements accessible in industrial practice, is proposed. It consists of a software sensor (SS) system composed of a cascade structure. Process kinetics are simulated in models with a structure including time-varying yield coefficients. SSs for measured variable kinetics have classical structures. The SS design of unmeasured variables is realized after a linear transformation using a logarithmic function. For these software sensors, a tuning procedure is proposed, at which an arbitrary choice of one tuning parameter value that guarantees stability of the monitoring system allows the calculation of the optimal values of six parameters. The effectiveness of the proposed monitoring approach is demonstrated with experimental data from a glucose-limited fed-batch process of Bacillus subtilis in a laboratory two-compartment scale down reactor which tries to mimic the conditions present in industrial scale nutrient-limited fed-batch cultivations.

  9. China's post-coal growth

    NASA Astrophysics Data System (ADS)

    Qi, Ye; Stern, Nicholas; Wu, Tong; Lu, Jiaqi; Green, Fergus

    2016-08-01

    Slowing GDP growth, a structural shift away from heavy industry, and more proactive policies on air pollution and clean energy have caused China's coal use to peak. It seems that economic growth has decoupled from growth in coal consumption.

  10. Scale-up of stirring as foam disruption (SAFD) to industrial scale.

    PubMed

    Hoeks, Frans W J M M; Boon, Lotte A; Studer, Fabian; Wolff, Menno O; van der Schot, Freija; Vrabél, Peter; van der Lans, Rob G J M; Bujalski, Waldemar; Manelius, Asa; Blomsten, Gustav; Hjorth, Sven; Prada, Giovanna; Luyben, Karel Ch A M; Nienow, Alvin W

    2003-02-01

    Foam disruption by agitation-the stirring as foam disruption (SAFD) technique-was scaled up to pilot and production scale using Rushton turbines and an up-pumping hydrofoil impeller, the Scaba 3SHP1. The dominating mechanism behind SAFD-foam entrainment-was also demonstrated at production scale. The mechanistic model for SAFD defines a fictitious liquid velocity generated by the (upper) impeller near the dispersion surface, which is correlated with complete foam disruption. This model proved to be scalable, thus enabling the model to be used for the design of SAFD applications. Axial upward pumping impellers appeared to be more effective with respect to SAFD than Rushton turbines, as demonstrated by retrofitting a 12,000 l bioreactor, i.e. the triple Rushton configuration was compared with a mixed impeller configuration from Scaba with a 20% lower ungassed power draw. The retrofitted impeller configuration allowed 10% more broth without risking excessive foaming. In this way a substantial increase in the volumetric productivity of the bioreactor was achieved. Design recommendations for the application of SAFD are given in this paper. Using these recommendations for the design of a 30,000 l scale bioreactor, almost foamless Escherichia coli fermentations were realised.

  11. Industrialization of lipid nanoparticles: From laboratory-scale to large-scale production line.

    PubMed

    Hu, Caibiao; Qian, Airui; Wang, Qiang; Xu, Feng; He, Yi; Xu, Jing; Xia, Yongchang; Xia, Qiang

    2016-12-01

    This work aimed at developing a large-scale modular production line, which referred to coenzyme Q10 loaded-NLC as well as its continuous and scalable emulsification and homogenization process. The production line exhibited good control over the emulsification and homogenization process and enabled the particle size of NLC below 210nm at a throughput of 25kg/h (for lipid solution at a flow rate of 0.4kg/min). Among the several process parameters investigated, the size of the NLC was mainly influenced by the pre-emulsification temperature, homogenization pressure and homogenization. Suitable emulsification temperature (70°C), homogenization pressure (600, 800bar), and homogenization cycle (3, 4cycles) resulted in relatively smaller particles. These results proved that coenzyme Q10, a model active, had been successfully loaded into the NLC. Meanwhile, the large-scale production line can be effectively applied for continuous and modular production of NLC. The line had modern networking features-essential in the Internet age-and a modular design that was easily modified and upgraded. In addition, the long-term stability over 6month was monitored at 30°C and at 40°C to assess a potential effect of the laboratory scale and large scale on stability. All batches at room temperature and below were stable, and only a negligible increase in size was observed.

  12. Coal Production 1992

    SciTech Connect

    Not Available

    1993-10-29

    Coal Production 1992 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, productive capacity, and recoverable reserves to a wide audience including Congress, Federal and State agencies, the coal industry, and the general public. In 1992, there were 3,439 active coal mining operations made up of all mines, preparation plants, and refuse operations. The data in Table 1 cover the 2,746 mines that produced coal, regardless of the amount of production, except for bituminous refuse mines. Tables 2 through 33 include data from the 2,852 mining operations that produced, processed, or prepared 10 thousand or more short tons of coal during the period, except for bituminous refuse, and includes preparation plants with 5 thousand or more employee hours. These mining operations accounted for over 99 percent of total US coal production and represented 83 percent of all US coal mining operations in 1992.

  13. Farewell, king coal!

    PubMed

    Seaton, Anthony

    2016-04-01

    Coal mining provided the power for the industrial development of the West, at great cost to the health of the workforce and, from industrial pollution, of the population. Medical appreciation of the diseases of miners was slow to develop and has been marked by controversy relating to the roles of coal and quartz and the causation of emphysema. Research by the MRC and the British coal industry resolved these issues as the industry itself declined. However, from the research has come an understanding of the influence of inhalation of different inhaled pollutants on human health that has been applied to predicting and preventing possible hazards of developing nanotechnologies.

  14. Coal-water slurry fuel combustion testing in an oil-fired industrial boiler. Semiannual technical progress report, February 15, 1994--August 15, 1994

    SciTech Connect

    Miller, B.G.; Scaroni, A.W.

    1994-11-30

    The Pennsylvania State University is conducting a coal-water slurry fuel (CWSF) program for the United States Department of Energy (DOE) and the Commonwealth of Pennsylvania with the objective of determining the viability of firing CWSF in an industrial boiler designed for heavy fuel oil. The project will also provide information to help in the design of new system specifically configured to fire these clean coal-based fuels. The project consists of four phases: (1) design, permitting, and test planning, (2) construction and start up, (3) demonstration and evaluation (1,000-hour demonstration), and (4) expanded demonstration and evaluation (installing a CWSF preparation circuit, conducting an additional 1,000 hours of testing, and installing an advanced flue gas treatment system). The boiler testing and evaluation will determine if the CWSF combustion characteristics, heat release rate, fouling and slagging behavior, corrosion and erosion tendencies, and fuel transport, storage, and handling characteristics can be accommodated in a boiler system designed to fire heavy fuel oil. In addition, the proof-of-concept demonstration will generate data to determine how the properties of a CWSF and its parent coal affect boiler performance. The economic factors associated with retrofitting boilers will also be evaluated. During this reporting period, the construction of the CWSF preparation circuit (as well as a dry, micronized coal circuit) continued. The CWSF preparation circuit will be completed by November 1,1994. Additional activities included receiving a coal-designed burner and installing it on the demonstration boiler, and working with DOE in selecting pollution control systems to install on the boiler.

  15. Accomplishments in genome-scale in silico modeling for industrial and medical biotechnology.

    PubMed

    Milne, Caroline B; Kim, Pan-Jun; Eddy, James A; Price, Nathan D

    2009-12-01

    Driven by advancements in high-throughput biological technologies and the growing number of sequenced genomes, the construction of in silico models at the genome scale has provided powerful tools to investigate a vast array of biological systems and applications. Here, we review comprehensively the uses of such models in industrial and medical biotechnology, including biofuel generation, food production, and drug development. While the use of in silico models is still in its early stages for delivering to industry, significant initial successes have been achieved. For the cases presented here, genome-scale models predict engineering strategies to enhance properties of interest in an organism or to inhibit harmful mechanisms of pathogens. Going forward, genome-scale in silico models promise to extend their application and analysis scope to become a trans-formative tool in biotechnology.

  16. Evaluation of multiple-scale 3D characterization for coal physical structure with DCM method and synchrotron X-ray CT.

    PubMed

    Wang, Haipeng; Yang, Yushuang; Yang, Jianli; Nie, Yihang; Jia, Jing; Wang, Yudan

    2015-01-01

    Multiscale nondestructive characterization of coal microscopic physical structure can provide important information for coal conversion and coal-bed methane extraction. In this study, the physical structure of a coal sample was investigated by synchrotron-based multiple-energy X-ray CT at three beam energies and two different spatial resolutions. A data-constrained modeling (DCM) approach was used to quantitatively characterize the multiscale compositional distributions at the two resolutions. The volume fractions of each voxel for four different composition groups were obtained at the two resolutions. Between the two resolutions, the difference for DCM computed volume fractions of coal matrix and pores is less than 0.3%, and the difference for mineral composition groups is less than 0.17%. This demonstrates that the DCM approach can account for compositions beyond the X-ray CT imaging resolution with adequate accuracy. By using DCM, it is possible to characterize a relatively large coal sample at a relatively low spatial resolution with minimal loss of the effect due to subpixel fine length scale structures.

  17. Elastic and optical anisotropy of the single-coal monolithic high-temperature (HT) carbonization products obtained on a laboratory scale

    SciTech Connect

    Marta Krzesinska; Slawomira Pusz; Andrzej Koszorek

    2005-10-01

    The aim of the present study was to investigate the directional dependences of the elastic and optical properties of monolithic single-coal high-temperature (HT) carbonization products obtained on a laboratory scale (with very slow heating rate) from coals of different caking propensity. Sixteen monolithic HT carbonization products, mainly cokes, were produced in the Jenkner retort furnace using 16 various types of coals of varying rank (from 83.1 wt % carbon to 98.3 wt % carbon) with a Roga index (RI) in the range of 0-76. Coals were carbonized in the form of monolithic blocks. The physical parameters such as true density, porosity, ultrasonic velocity, and dynamic elastic moduli, as well as optical reflectance parameters (R{sub max}, R{sub min}, R{sub am}), were determined for the resultant products. The elastic and optical properties of the HT carbonization products were related to their porosity and the rank of the parent coals. It was determined that the HT carbonization products exhibit the different directional properties of the studied parameters, and they can be divided into three groups, with respect to the observed differences. The properties of these groups were related to the parent coal rank and the caking propensity (i.e., to the RI value). Anisotropy of the coke matrix structure was determined to be important for discussion about the anisotropic properties of cokes. 50 refs., 9 figs., 4 tabs.

  18. Healy Clean Coal Project: Healy coal firing at TRW Cleveland Test Facility. Final report

    SciTech Connect

    Koyama, T.; Petrill, E.; Sheppard, D.

    1991-08-01

    A test burn of two Alaskan coals was conducted at TRW`s Cleveland test facility in support of the Healy Clean Coal Project, as part of Clean Coal Technology III Program in which a new power plant will be constructed using a TRW Coal Combustion System. This system features ash slagging technology combined with NO{sub x} and SO{sub x} control. The tests, funded by the Alaska Industrial Development and Export Authority (AIDEA) and TRW, were conducted to verify that the candidate Healy station coals could be successfully fired in the TRW coal combustor, to provide data required for scale-up to the utility project size requirements, and to produce sufficient flash-calcined material (FCM) for spray dryer tests to be conducted by Joy/NIRO. The tests demonstrated that both coals are viable candidates for the project, provided the data required for scale-up, and produced the FCM material. This report describes the modifications to the test facility which were required for the test burn, the tests run, and the results of the tests.

  19. Healy Clean Coal Project: Healy coal firing at TRW Cleveland Test Facility

    SciTech Connect

    Koyama, T.; Petrill, E.; Sheppard, D.

    1991-08-01

    A test burn of two Alaskan coals was conducted at TRW's Cleveland test facility in support of the Healy Clean Coal Project, as part of Clean Coal Technology III Program in which a new power plant will be constructed using a TRW Coal Combustion System. This system features ash slagging technology combined with NO{sub x} and SO{sub x} control. The tests, funded by the Alaska Industrial Development and Export Authority (AIDEA) and TRW, were conducted to verify that the candidate Healy station coals could be successfully fired in the TRW coal combustor, to provide data required for scale-up to the utility project size requirements, and to produce sufficient flash-calcined material (FCM) for spray dryer tests to be conducted by Joy/NIRO. The tests demonstrated that both coals are viable candidates for the project, provided the data required for scale-up, and produced the FCM material. This report describes the modifications to the test facility which were required for the test burn, the tests run, and the results of the tests.

  20. Potential for improved radiation thermometry measurement uncertainty through implementing a primary scale in an industrial laboratory

    NASA Astrophysics Data System (ADS)

    Willmott, Jon R.; Lowe, David; Broughton, Mick; White, Ben S.; Machin, Graham

    2016-09-01

    A primary temperature scale requires realising a unit in terms of its definition. For high temperature radiation thermometry in terms of the International Temperature Scale of 1990 this means extrapolating from the signal measured at the freezing temperature of gold, silver or copper using Planck’s radiation law. The difficulty in doing this means that primary scales above 1000 °C require specialist equipment and careful characterisation in order to achieve the extrapolation with sufficient accuracy. As such, maintenance of the scale at high temperatures is usually only practicable for National Metrology Institutes, and calibration laboratories have to rely on a scale calibrated against transfer standards. At lower temperatures it is practicable for an industrial calibration laboratory to have its own primary temperature scale, which reduces the number of steps between the primary scale and end user. Proposed changes to the SI that will introduce internationally accepted high temperature reference standards might make it practicable to have a primary high temperature scale in a calibration laboratory. In this study such a scale was established by calibrating radiation thermometers directly to high temperature reference standards. The possible reduction in uncertainty to an end user as a result of the reduced calibration chain was evaluated.

  1. POC-scale testing of a dry triboelectrostatic separator for fine coal cleaning. Third quarterly technical progress report, April 1996--June 30, 1996

    SciTech Connect

    Yoon, R.-H.; Mesenyashin, A.; Yan, E.S.; Luttrell, G.H.; Adel, G.T.

    1996-10-01

    The Pittsburgh Energy Technology Center (PETC) developed a triboelectrostatic separation (TES) process which is capable of removing mineral matter from coal without using water. A distinct advantage of this dry coal cleaning process is that it does not entail costly steps of dewatering which is a common problem associated with conventional fine coal cleaning processes. It is the objective of this project to conduct a series of proof-of-concept (POC) scale tests at a throughput of 200--250 kg/hr and obtain scale- up information. Prior to the POC testing, bench-scale test work will be conducted with the objective of increasing the separation efficiency and throughput, for which changes in the basic designs for the charger and the separator may be necessary. The bench- and POC- scale test work will be carried out to evaluate various operating parameters and establish a reliable scale-up procedure. The scale-up data will be used to analyze the economic merits of the TES process. At present, the project is at the stage of engineering design (Task 3). Work accomplished during this reporting period include the construction of a Faraday Cage for measurement of particle charges (Subtask 3.1), construction of a bench-scale triboelectrostatic separator (Subtask 3.2) and development of a theoretical model for predicting motion of charged particles in a non-uniform electrostatic field (Subtask 3.2). This model will be useful for designing the POC module.

  2. Environmental justice implications of industrial hazardous waste generation in India: a national scale analysis

    NASA Astrophysics Data System (ADS)

    Basu, Pratyusha; Chakraborty, Jayajit

    2016-12-01

    While rising air and water pollution have become issues of widespread public concern in India, the relationship between spatial distribution of environmental pollution and social disadvantage has received less attention. This lack of attention becomes particularly relevant in the context of industrial pollution, as India continues to pursue industrial development policies without sufficient regard to its adverse social impacts. This letter examines industrial pollution in India from an environmental justice (EJ) perspective by presenting a national scale study of social inequities in the distribution of industrial hazardous waste generation. Our analysis connects district-level data from the 2009 National Inventory of Hazardous Waste Generating Industries with variables representing urbanization, social disadvantage, and socioeconomic status from the 2011 Census of India. Our results indicate that more urbanized and densely populated districts with a higher proportion of socially and economically disadvantaged residents are significantly more likely to generate hazardous waste. The quantity of hazardous waste generated is significantly higher in more urbanized but sparsely populated districts with a higher proportion of economically disadvantaged households, after accounting for other relevant explanatory factors such as literacy and social disadvantage. These findings underscore the growing need to incorporate EJ considerations in future industrial development and waste management in India.

  3. A Proven, Industrial Magnetron Sputtering System With Excellent Expansion And Scale-Up Capabilities

    NASA Astrophysics Data System (ADS)

    Griffin, D.

    1987-11-01

    Airco Solar Products began as a business unit of Airco Temescal in the early 1970's. The first large area magnetron sputtering deposition occurred in 1974, and the first large area magnetron sputtering system was built and operated under contract to Guardian Industries in Carleton, Michigan in 1977, and was later sold to Guardian. This system continues in three-shift production today. A smaller development system, designed for use in the architectural glass coating industry, was introduced in parallel with the large area coaters. There are now over seventeen of these systems, called the ILS-1600, in use or on order throughout the world. This is a proven, industrial-style development sputter deposition system and has an excellent field record in the areas of versatility and low maintenance requirements. Airco Solar Products has recently begun to market this system into other applications such as the photovoltaics industry, the flat panel display industry and other specialty industries. The features of this system such as overall design, expandability, process scale-up and available options will be discussed. Expanded versions of this system currently in the field will be reviewed, and future applications will be discussed.

  4. ELECTROKINETIC DENSIFICATION OF COAL FINES IN WASTE PONDS

    SciTech Connect

    E. James Davis

    1996-04-01

    The objective of this research is to apply electrokinetics to remove colloidal coal and mineral particles from coal washing ponds without the addition of chemical additives. Colloidal particles do not settle gravitationally, but because their surfaces are charged one can produce settling by applying an external electric field. Of specific interest is a lake near Centralia, Washington used to wash coal prior to combustion in an electrical power generation facility. Laboratory experiments have demonstrated that electrokinetic treatment is feasible, so this project is examining how to scale up laboratory results to an industrial level. Electrode configurations, power requirements, and system properties are being studied.

  5. Coal devolatilization and char combustion study using FTIR spectroscopy

    SciTech Connect

    Raines, T.S.; Brown, R.C.

    1995-12-31

    The goal of this research is to characterize coals during the normal operation of an industrial-scale circulating fluidized bed (CFB) boiler. The method determines coal properties based on the analysis of transient CO and CO{sub 2} emissions from the boiler. Fourier Transform Infrared (FTIR) spectroscopy is used to qualitatively and quantitatively analyze the gaseous products of combustion. The method is non-intrusive and is performed under realistic combustion conditions. Preliminary data suggest that coal devolatilization is complete before char combustion commences in a circulating fluidized bed boiler.

  6. POC-scale testing of oil agglomeration techniques and equipment for fine coal processing: technical progress report no. 3--January 1, 1996-March 31, 1996

    SciTech Connect

    1996-10-01

    The objective of this project is to develop and demonstrate a Proof-of-Concept (POC) scale oil agglomeration technology capable of increasing the recovery and improving the quality of fine coal streams. Two distinct agglomeration devices will be tested, namely, a conventional high shear mixer and a tubular (jet) processor. To meet the overall objective an 11 task work plan has been designed. The work will range from batch and continuous bench-scale testing through the design, commissioning and field testing of POC-scale agglomeration equipment. During the reporting period there were activities under the following tasks: project planning and management; host site selection and plan formulation; preliminary engineering and design of POC equipment; coal characterization and laboratory (batch) and bench-scale testing; and process evaluation. The work on the remaining tasks is scheduled for the next months.

  7. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal, Annual Progress Report, October 1, 2005 through September 30, 2006

    SciTech Connect

    Miller, Bruce G

    2006-09-29

    Since 1998, The Pennsylvania State University has been successfully managing the Consortium for Premium Carbon Products from Coal (CPCPC), which is a vehicle for industry-driven research on the promotion, development, and transfer of innovative technology on premium carbon produces from coal to the U.S. industry. The CPCPC is an initiative being led by Penn State, its co-charter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provides the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity has continued under the present cooperative agreement, No. DE-FC26-03NT41874, which started October 1, 2003. The objective of the second agreement is to continue the successful operation of the CPCPC. The CPCPC has enjoyed tremendous success with its organizational structure, that includes Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC is its industry-led council that selects proposals submitted by CPCPC members to ensure CPCPC target areas have strong industrial support. Base funding for the selected projects is provided by NETL with matching funds from industry. At the annual funding meeting held in October 2003, ten projects were selected for funding. Subcontracts were let from Penn State to the subcontractors on March 1, 2004. Nine of the ten 2004 projects were completed during the previous annual reporting period and their final reports were submitted with the previous annual report (i.e., 10/01/04-09/30/05). The final report for the remaining project, which was submitted during this reporting

  8. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal, Annual Progress Report, October 1, 2004 through September 30, 2005

    SciTech Connect

    Miller, Bruce G

    2006-03-01

    Since 1998, The Pennsylvania State University (PSU) has been successfully operating the Consortium for Premium Carbon Products from Coal (CPCPC), which is a vehicle for industry-driven research on the promotion, development, and transfer of innovative technology on premium carbon produces from coal to the U.S. industry. The CPCPC is an initiative being led by PSU, its co-charter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provides the base funding for the program, with PSU responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity has continued under the present cooperative agreement, No. DE-FC26-03NT41874, which started October 1, 2003. The objective of the second agreement is to continue the successful operation of the CPCPC. The CPCPC has enjoyed tremendous success with its organizational structure, that includes PSU and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC is its industry-led council that selects proposals submitted by CPCPC members to ensure CPCPC target areas have strong industrial support. A second contract was executed with DOE NETL starting in October 2003 to continue the activities of CPCPC. An annual funding meeting was held in October 2003 and the council selected ten projects for funding. Base funding for the projects is provided by NETL with matching funds from industry. Subcontracts were let from Penn State to the subcontractors on March 1, 2004. Nine of the ten projects have been completed and the final reports for these 2004 projects are attached. An annual funding meeting was held in November 2004 and the council selected

  9. State coal profiles, January 1994

    SciTech Connect

    Not Available

    1994-02-02

    The purpose of State Coal Profiles is to provide basic information about the deposits, production, and use of coal in each of the 27 States with coal production in 1992. Although considerable information on coal has been published on a national level, there is a lack of a uniform overview for the individual States. This report is intended to help fill that gap and also to serve as a framework for more detailed studies. While focusing on coal output, State Coal Profiles shows that the coal-producing States are major users of coal, together accounting for about three-fourths of total US coal consumption in 1992. Each coal-producing State is profiled with a description of its coal deposits and a discussion of the development of its coal industry. Estimates of coal reserves in 1992 are categorized by mining method and sulfur content. Trends, patterns, and other information concerning production, number of mines, miners, productivity, mine price of coal, disposition, and consumption of coal are detailed in statistical tables for selected years from 1980 through 1992. In addition, coal`s contribution to the State`s estimated total energy consumption is given for 1991, the latest year for which data are available. A US summary of all data is provided for comparing individual States with the Nation as a whole. Sources of information are given at the end of the tables.

  10. Particle physics and polyedra proximity calculation for hazard simulations in large-scale industrial plants

    NASA Astrophysics Data System (ADS)

    Plebe, Alice; Grasso, Giorgio

    2016-12-01

    This paper describes a system developed for the simulation of flames inside an open-source 3D computer graphic software, Blender, with the aim of analyzing in virtual reality scenarios of hazards in large-scale industrial plants. The advantages of Blender are of rendering at high resolution the very complex structure of large industrial plants, and of embedding a physical engine based on smoothed particle hydrodynamics. This particle system is used to evolve a simulated fire. The interaction of this fire with the components of the plant is computed using polyhedron separation distance, adopting a Voronoi-based strategy that optimizes the number of feature distance computations. Results on a real oil and gas refining industry are presented.

  11. Premium carbon products from coal

    SciTech Connect

    Rusinko, F. Jr.; Morrison, J.L.

    2000-07-01

    The face of the US coal industry and its markets are changing. Environmental concerns over global warming and plant emissions are two factors that will continue to gain national attention and consequently will challenge the use of coal in the US within its traditional markets. The decline of coke production in the US has lead to high quality metallurgical-grade coal being used to generate electricity. One could argue this is a waste of a limited valuable resource. The debate over global warming and the generation of greenhouse gases, particularly CO{sub 2}, will undoubtedly negatively impact the use of coal in newly constructed power plants. What is the future of the US coal industry and the industries that benefit from coal? This paper will review the use of coal and coal-derived materials in new, non-fuel markets. It will review a new industrial consortium that has recently been formed to stimulate the use of coal in value-added carbon markets. One of the questions the reader should ask when reading this paper is: Is coal more valuable for its carbon content or its BTU content? Carbon materials such as carbon fibers, carbon-carbon composites, specialty and mechanical graphite, activated carbon, carbon black, and carbon foams may provide new markets for the coal industry. These markets are expanding and some of these markets are in their infancy. These new material applications offer an exciting, but little recognized, opportunity for the expanded use of coal.

  12. Treatment of aqueous streams containing strong oxidants using bituminous coal

    SciTech Connect

    Doyle, F.M.; Bodine, D.L.

    1995-12-31

    Certain oxidizing contaminants, notably Cr(VI) and Mn(VII), are attenuated by reduction and sorption on organic matter in soils. Coals have some chemical similarity with this organic matter, and might be used on an industrial scale to treat effluents. We have studied the ability of acidic KMnO{sub 4} to oxidize Upper Freeport, bituminous coal with concurrent sorption of the resulting Mn(IV) and Mn(II). The oxidizing ability of Cr(VI) was briefly investigated. The ability of the oxidized coal to sorb Cu{sup 2+} and Cd{sup 2+} was then studied, and compared with coal oxidized by hydrogen peroxide. The effect of oxidation treatment, metal ion concentration, and solution pH on metal uptake kinetics and coal loading was investigated. Potential applications for treating effluents containing oxidizing ions are discussed.

  13. Anaerobic Digestion of Laminaria japonica Waste from Industrial Production Residues in Laboratory- and Pilot-Scale

    PubMed Central

    Barbot, Yann Nicolas; Thomsen, Claudia; Thomsen, Laurenz; Benz, Roland

    2015-01-01

    The cultivation of macroalgae to supply the biofuel, pharmaceutical or food industries generates a considerable amount of organic residue, which represents a potential substrate for biomethanation. Its use optimizes the total resource exploitation by the simultaneous disposal of waste biomaterials. In this study, we explored the biochemical methane potential (BMP) and biomethane recovery of industrial Laminaria japonica waste (LJW) in batch, continuous laboratory and pilot-scale trials. Thermo-acidic pretreatment with industry-grade HCl or industrial flue gas condensate (FGC), as well as a co-digestion approach with maize silage (MS) did not improve the biomethane recovery. BMPs between 172 mL and 214 mL g−1 volatile solids (VS) were recorded. We proved the feasibility of long-term continuous anaerobic digestion with LJW as sole feedstock showing a steady biomethane production rate of 173 mL g−1 VS. The quality of fermentation residue was sufficient to serve as biofertilizer, with enriched amounts of potassium, sulfur and iron. We further demonstrated the upscaling feasibility of the process in a pilot-scale system where a CH4 recovery of 189 L kg−1 VS was achieved and a biogas composition of 55% CH4 and 38% CO2 was recorded. PMID:26393620

  14. Anaerobic Digestion of Laminaria japonica Waste from Industrial Production Residues in Laboratory- and Pilot-Scale.

    PubMed

    Barbot, Yann Nicolas; Thomsen, Claudia; Thomsen, Laurenz; Benz, Roland

    2015-09-18

    The cultivation of macroalgae to supply the biofuel, pharmaceutical or food industries generates a considerable amount of organic residue, which represents a potential substrate for biomethanation. Its use optimizes the total resource exploitation by the simultaneous disposal of waste biomaterials. In this study, we explored the biochemical methane potential (BMP) and biomethane recovery of industrial Laminaria japonica waste (LJW) in batch, continuous laboratory and pilot-scale trials. Thermo-acidic pretreatment with industry-grade HCl or industrial flue gas condensate (FGC), as well as a co-digestion approach with maize silage (MS) did not improve the biomethane recovery. BMPs between 172 mL and 214 mL g(-1) volatile solids (VS) were recorded. We proved the feasibility of long-term continuous anaerobic digestion with LJW as sole feedstock showing a steady biomethane production rate of 173 mL g(-1) VS. The quality of fermentation residue was sufficient to serve as biofertilizer, with enriched amounts of potassium, sulfur and iron. We further demonstrated the upscaling feasibility of the process in a pilot-scale system where a CH₄ recovery of 189 L kg(-1) VS was achieved and a biogas composition of 55% CH₄ and 38% CO₂ was recorded.

  15. The development of an industrial-scale fed-batch fermentation simulation.

    PubMed

    Goldrick, Stephen; Ştefan, Andrei; Lovett, David; Montague, Gary; Lennox, Barry

    2015-01-10

    This paper describes a simulation of an industrial-scale fed-batch fermentation that can be used as a benchmark in process systems analysis and control studies. The simulation was developed using a mechanistic model and validated using historical data collected from an industrial-scale penicillin fermentation process. Each batch was carried out in a 100,000 L bioreactor that used an industrial strain of Penicillium chrysogenum. The manipulated variables recorded during each batch were used as inputs to the simulator and the predicted outputs were then compared with the on-line and off-line measurements recorded in the real process. The simulator adapted a previously published structured model to describe the penicillin fermentation and extended it to include the main environmental effects of dissolved oxygen, viscosity, temperature, pH and dissolved carbon dioxide. In addition the effects of nitrogen and phenylacetic acid concentrations on the biomass and penicillin production rates were also included. The simulated model predictions of all the on-line and off-line process measurements, including the off-gas analysis, were in good agreement with the batch records. The simulator and industrial process data are available to download at www.industrialpenicillinsimulation.com and can be used to evaluate, study and improve on the current control strategy implemented on this facility.

  16. Energy saving membrane treatment of high organic load industrial effluents: from lab to pilot scale.

    PubMed

    Lopes, Mafalda Pessoa; Xin, Gang; Crespo, João G

    2013-12-15

    In this study, a nanofiltration unit was implemented at an industrial site, for the treatment of industrial wastewater generated during rubber tubing extrusion. The aim was to reduce the energy input required, while assuring a final effluent quality that meets the requirements of environmental legislation. In a first stage, two membrane process treatments, ultrafiltration and nanofiltration, were evaluated at laboratory scale in order to assess the rejection of pollutants and maximise permeate throughput. Permeate generated from nanofiltration using either an NF90 or an NF270 membrane were shown to meet the effluent discharge requirements (<2000 mg COD/l). The less restrictive membrane, NF270, was chosen for study in a pilot plant at the industrial site, due to its higher membrane permeability. The pilot nanofiltration unit was integrated into the treatment plant operation aiming at optimising the process in terms of the efficiency of pollutant removal with minimal energy input. A feasibility study was performed for this case-study and it was concluded that the energy expenditure of the new process represents only 62% of the current energy consumption of the treatment plant. The proposed solution in this work may be retrofitted to full scale wastewater treatment processes, and may be applicable to industries that employ similar manufacturing processes, and face similar difficulties.

  17. Bioprocess development for kefiran production by Lactobacillus kefiranofaciens in semi industrial scale bioreactor.

    PubMed

    Dailin, Daniel Joe; Elsayed, Elsayed Ahmed; Othman, Nor Zalina; Malek, Roslinda; Phin, Hiew Siaw; Aziz, Ramlan; Wadaan, Mohamad; El Enshasy, Hesham Ali

    2016-07-01

    Lactobacillus kefiranofaciens is non-pathogenic gram positive bacteria isolated from kefir grains and able to produce extracellular exopolysaccharides named kefiran. This polysaccharide contains approximately equal amounts of glucose and galactose. Kefiran has wide applications in pharmaceutical industries. Therefore, an approach has been extensively studied to increase kefiran production for pharmaceutical application in industrial scale. The present work aims to maximize kefiran production through the optimization of medium composition and production in semi industrial scale bioreactor. The composition of the optimal medium for kefiran production contained sucrose, yeast extract and K2HPO4 at 20.0, 6.0, 0.25 g L(-1), respectively. The optimized medium significantly increased both cell growth and kefiran production by about 170.56% and 58.02%, respectively, in comparison with the unoptimized medium. Furthermore, the kinetics of cell growth and kefiran production in batch culture of L. kefiranofaciens was investigated under un-controlled pH conditions in 16-L scale bioreactor. The maximal cell mass in bioreactor culture reached 2.76 g L(-1) concomitant with kefiran production of 1.91 g L(-1).

  18. Size distribution of rare earth elements in coal ash

    USGS Publications Warehouse

    Scott, Clinton T.; Deonarine, Amrika; Kolker, Allan; Adams, Monique; Holland, James F.

    2015-01-01

    Rare earth elements (REEs) are utilized in various applications that are vital to the automotive, petrochemical, medical, and information technology industries. As world demand for REEs increases, critical shortages are expected. Due to the retention of REEs during coal combustion, coal fly ash is increasingly considered a potential resource. Previous studies have demonstrated that coal fly ash is variably enriched in REEs relative to feed coal (e.g, Seredin and Dai, 2012) and that enrichment increases with decreasing size fractions (Blissett et al., 2014). In order to further explore the REE resource potential of coal ash, and determine the partitioning behavior of REE as a function of grain size, we studied whole coal and fly ash size-fractions collected from three U.S commercial-scale coal-fired generating stations burning Appalachian or Powder River Basin coal. Whole fly ash was separated into , 5 um, to 5 to 10 um and 10 to 100 um particle size fractions by mechanical shaking using trace-metal clean procedures. In these samples REE enrichments in whole fly ash ranges 5.6 to 18.5 times that of feedcoals. Partitioning results for size separates relative to whole coal and whole fly ash will also be reported. 

  19. Investigation of the relationship between particulate-bound mercury and properties of fly ash in a full-scale 100 MWe pulverized coal combustion boiler

    SciTech Connect

    Sen Li; Chin-Min Cheng; Bobby Chen; Yan Cao; Jacob Vervynckt; Amanda Adebambo; Wei-Ping Pan

    2007-12-15

    The properties of fly ash in coal-fired boilers influence the emission of mercury from power plants into the environment. In this study, seven different bituminous coals were burned in a full-scale 100 MWe pulverized coal combustion boiler and the derived fly ash samples were collected from a mechanical hopper (MH) and an electrostatic precipitator hopper (ESP). The mercury content, specific surface area (SSA), unburned carbon, and elemental composition of the fly ash samples were analyzed to evaluate the correlation between the concentration of particulate-bound mercury and the properties of coal and fly ash. For a given coal, it was found that the mercury content in the fly ash collected from the ESP was greater than in the fly ash samples collected from the MHP. This phenomenon may be due to a lower temperature of flue gas at the ESP (about 135{sup o}C) compared to the temperature at the air preheater (about 350{sup o}C). Also, a significantly lower SSA observed in MH ash might also contribute to the observation. A comparison of the fly ash samples generated from seven different coals using statistical methods indicates that the mercury adsorbed on ESP fly ashes has a highly positive correlation with the unburned carbon content, manganese content, and SSA of the fly ash. Sulfur content in coal showed a significant negative correlation with the Hg adsorption. Manganese in fly ash is believed to participate in oxidizing volatile elemental mercury (Hg{sup 0}) to ionic mercury (Hg{sup 2+}). The oxidized mercury in flue gas can form a complex with the fly ash and then get removed before the flue gas leaves the stack of the boiler.

  20. Characteristics of fly ashes from full-scale coal-fired power plants and their relationship to mercury adsorption

    USGS Publications Warehouse

    Lu, Y.; Rostam-Abadi, M.; Chang, R.; Richardson, C.; Paradis, J.

    2007-01-01

    Nine fly ash samples were collected from the particulate collection devices (baghouse or electrostatic precipitator) of four full-scale pulverized coal (PC) utility boilers burning eastern bituminous coals (EB-PC ashes) and three cyclone utility boilers burning either Powder River Basin (PRB) coals or PRB blends,(PRB-CYC ashes). As-received fly ash samples were mechanically sieved to obtain six size fractions. Unburned carbon (UBC) content, mercury content, and Brunauer-Emmett-Teller (BET)-N2 surface areas of as-received fly ashes and their size fractions were measured. In addition, UBC particles were examined by scanning electron microscopy, high-resolution transmission microscopy, and thermogravimetry to obtain information on their surface morphology, structure, and oxidation reactivity. It was found that the UBC particles contained amorphous carbon, ribbon-shaped graphitic carbon, and highly ordered graphite structures. The mercury contents of the UBCs (Hg/UBC, in ppm) in raw ash samples were comparable to those of the UBC-enriched samples, indicating that mercury was mainly adsorbed on the UBC in fly ash. The UBC content decreased with a decreasing particle size range for all nine ashes. There was no correlation between the mercury and UBC contents of different size fractions of as-received ashes. The mercury content of the UBCs in each size fraction, however, generally increased with a decreasing particle size for the nine ashes. The mercury contents and surface areas of the UBCs in the PRB-CYC ashes were about 8 and 3 times higher than UBCs in the EB-PC ashes, respectively. It appeared that both the particle size and surface area of UBC could contribute to mercury capture. The particle size of the UBC in PRB-CYC ash and thus the external mass transfer was found to be the major factor impacting the mercury adsorption. Both the particle size and surface reactivity of the UBC in EB-PC ash, which generally had a lower carbon oxidation reactivity than the PRB

  1. Coal-water slurry fuel combustion testing in an oil-fired industrial boiler. Semiannual technical progress report, August 15, 1993--February 15, 1994

    SciTech Connect

    Miller, B.G.; Morrison, J.L.; Poe, R.L.; Scaroni, A.W.

    1994-11-30

    The Pennsylvania State University is conducting a coal-water slurry fuel (CWSF) program with the objective of determining the viability of firing CWSF in an industrial boiler designed for heavy fuel oil. The project will also provide information to help in the design of new systems specifically configured to fire these clean coal-based fuels. The project consists of four phases: (1) design, permitting, and test planning, (2) construction and start up, (3) demonstration and evaluation (1,000-hour demonstration), and (4) expanded demonstration and evaluation (installing a CWSF preparation circuit, conducting an additional 1,000 hours of testing, and installing an advanced flue gas treatment system). The boiler testing and evaluation will determine if the CWSF combustion characteristics, heat release rate, fouling and slagging behavior, corrosion and erosion tendencies, and fuel transport, storage, and handling characteristics can be accommodated in a boiler system designed to fire heavy fuel oil. In addition, the proof-of-concept demonstration will generate data to determine how the properties of a CWSF and its parent coal affect boiler performance. The economic factors associated with retrofitting boilers will also be evaluated. The first demonstrations been completed and the combustion performance of the burner that was provided with the boiler has been determined to be unacceptable. Consequently, the first demonstration has been concluded at 500 hours. The second demonstration will be conducted after a proven CWSF-designed burner is installed on the boiler. During this reporting period, the construction of the fuel preparation facility that will contain the CWSF circuit (as well as a dry, micronized coal circuit) was completed. Proposals from potential suppliers of the flue gas treatment systems were reviewed by Penn State and DOE.

  2. Preliminary draft industrial siting administration permit application: Socioeconomic factors technical report. Final technical report, November 1980-May 1982. [Proposed WyCoalGas project in Converse County, Wyoming

    SciTech Connect

    Not Available

    1982-01-01

    Under the with-project scenario, WyCoalGas is projected to make a difference in the long-range future of Converse County. Because of the size of the proposed construction and operations work forces, the projected changes in employment, income, labor force, and population will alter Converse County's economic role in the region. Specifically, as growth occurs, Converse County will begin to satisfy a larger portion of its own higher-ordered demands, those that are currently being satisfied by the economy of Casper. Business-serving and household-serving activities, currently absent, will find the larger income and population base forecast to occur with the WyCoalGas project desirable. Converse County's economy will begin to mature, moving away from strict dependence on extractive industries to a more sophisticated structure that could eventually appeal to national, and certainly, regional markets. The technical demand of the WyCoalGas plant will mean a significant influx of varying occupations and skills. The creation of basic manufacturing, advanced trade and service sectors, and concomitant finance and transportation firms will make Converse County more economically autonomous. The county will also begin to serve market center functions for the smaller counties of eastern Wyoming that currently rely on Casper, Cheyenne or other distant market centers. The projected conditions expected to exist in the absence of the WyCoalGas project, the socioeconomic conditions that would accompany the project, and the differences between the two scenarios are considered. The analysis is keyed to the linkages between Converse County and Natrona County.

  3. Polycyclic aromatic hydrocarbons (PAHs) in atmospheric PM2.5 and PM10 at a coal-based industrial city: Implication for PAH control at industrial agglomeration regions, China

    NASA Astrophysics Data System (ADS)

    Wu, Di; Wang, Zongshuang; Chen, Jianhua; Kong, Shaofei; Fu, Xiao; Deng, Hongbing; Shao, Guofan; Wu, Gang

    2014-11-01

    Eighteen polycyclic aromatic hydrocarbons (PAHs) in PM2.5 and PM10 are identified and quantified at five sites of E'erduosi in 2005 by GC-MS. Total PAH concentrations in PM2.5 and PM10 are in the ranges of 0.58-145.01 ng m- 3 and 5.80-180.32 ng m- 3 for the five sites, decreasing as coal-chemical base site (ZGE) > heavy industrial site (QPJ) > residential site with heavy traffic (DS) > suburban site surrounded by grassland (HJQ) > background site (QGN) for both PM2.5 and PM10. PAH concentrations in the coal-chemical base site are 250 and 31.1 times of those in the background site. Flu, Pyr, Chr, BbF, BeP, IND and BghiP are abundant for the coal-chemical base site, totally accounting for 75% of the PAH concentrations. 4, 5 and 6 rings PAHs are dominant, accounting for 88.9-94.2% and 90.5-94.1% of PAHs in PM2.5 and PM10, respectively. Combustion-derived PAH concentrations cover 42%-84% and 75%-82% of PAHs in PM2.5 and PM10, indicating large amounts of combustion sources existed for them in E'erduosi. PAH compositions between PM2.5 and PM10 are quite different from each other for sites with few human activities (HJQ and QGN) by coefficient of divergence analysis. Results obtained from principal component analysis and diagnostic ratios indicate that coal combustion, vehicle emission, wood combustion and industrial processes are the main sources for PAHs in E'erduosi. According to BaP equivalent concentration, the potential health risk of PAHs in PM2.5 at the two industrial sites ZGE and QPJ are 537 and 460 times of those for the background site. And they are 4.3 and 3.7 times of those for the residential site. The potential PAH pollution in particles at other industrial agglomeration regions that occurred in China in recent years should be paid attention by the local government.

  4. Regional scale selenium loading associated with surface coal mining, Elk Valley, British Columbia, Canada.

    PubMed

    Wellen, Christopher C; Shatilla, Nadine J; Carey, Sean K

    2015-11-01

    Selenium (Se) concentrations in surface water downstream of surface mining operations have been reported at levels in excess of water quality guidelines for the protection of wildlife. Previous research in surface mining environments has focused on downstream water quality impacts, yet little is known about the fundamental controls on Se loading. This study investigated the relationship between mining practices, stream flows and Se concentrations using a SPAtially Referenced Regression On Watershed attributes (SPARROW) model. This work is part of a R&D program examining the influence of surface coal mining on hydrological and water quality responses in the Elk Valley, British Columbia, Canada, aimed at informing effective management responses. Results indicate that waste rock volume, a product of mining activity, accounted for roughly 80% of the Se load from the Elk Valley, while background sources accounted for roughly 13%. Wet years were characterized by more than twice the Se load of dry years. A number of variables regarding placement of waste rock within the catchments, length of buried streams, and the construction of rock drains did not significantly influence the Se load. The age of the waste rock, the proportion of waste rock surface reclaimed, and the ratio of waste rock pile side area to top area all varied inversely with the Se load from watersheds containing waste rock. These results suggest operational practices that are likely to reduce the release of Se to surface waters.

  5. Laboratory-scale controlled-atmosphere chamber for use with premium coal samples

    NASA Astrophysics Data System (ADS)

    Filla, B. James; Callanan, Jane E.

    1985-04-01

    The recent availability of premium coal samples makes it desirable to have the capability for working with these materials, in one's own laboratory, in an atmosphere which can be controlled. A controlled-atmosphere chamber, large enough to allow for processing samples yet small enough to fit easily in an ordinary laboratory, has been designed and fabricated. The overall cost of this controlled-atmosphere chamber was competitive with commercially available systems. The major advantages of this specific system include: convenient size and reversible design for use in a limited work space; incorporation of a full vacuum antechamber that minimizes loss of the working chamber purified atmosphere; and a recirculating system with a bypass valve arrangement allowing separate or combined operation of oxygen and moisture removal systems. The design features were combined to create a unique apparatus capable of both the specific use for which it was intended and general controlled-atmosphere chamber applications. Compatible modular-design work chambers could have been purchased from commercial vendors; however, it still would have been necessary to custom fabricate both the antechamber and recirculation system to meet the requirements of the anticipated experimental work.

  6. National Occupational Health Service policies and programs for workers in small-scale industries in China.

    PubMed

    Zhi, S; Sheng, W; Levine, S P

    2000-01-01

    Over the 14 years since economic reform began, and the restructuring of the economy to encourage international trade, a large number of township enterprises have been developed and put into operation in the Peoples Republic of China. From 1978 to 1991, the number of enterprises has increased 11.5 times; the number of employees has increased 2.4 times; the fixed assets have increased 13.7 times; and the value of the total output has increased 22.5 times. In this article, a report is given on a sample survey in 30 counties in 1990, which showed that 82.69% of rural industrial enterprises had at least one type of occupational hazard in their work environments. Workers engaged in at least one type of hazardous working environment accounted for 33.91% of the blue-collar workers. Physical examinations were performed for seven types of occupational diseases: silicosis, coal worker's pneumoconiosis, asbestosis, chronic lead poisoning, benzene analogs poisoning, chronic chromium poisoning, and noise-induced hearing loss. The total detectable rate of the seven types of occupational diseases was 4.4% among those workers. In addition, 11% had illnesses suspected of being (though not proven to be) caused by occupational exposures. Most township enterprises do not provide basic occupational health services. The coverage of five routine occupational health service activities provided for township enterprises were very limited, from 1.4 to 36%.

  7. POC-scale testing of oil agglomeration techniques and equipment for fine coal processing. Technical report number 2, October 1--December 31, 1995

    SciTech Connect

    1996-07-01

    The objective of this project is to develop and demonstrate a Proof-of-Concept (POC) scale oil agglomeration technology capable of increasing the recovery and improving the quality of fine coal streams. Two distinct agglomeration devices will be tested, namely, a conventional high shear mixer and a tubular (jet) processor. To meet the overall objective an 11 task work plan has been designed. The work will range from batch and continuous bench-scale testing through the design, commissioning and field testing of POC-scale agglomeration equipment. The project includes the following tasks: Project planning and management; host site selection and plan formulation; preliminary engineering and design of POC equipment; coal characterization and laboratory (batch) and bench-scale testing; final engineering and design of POC equipment; proof-of-concept (POC) equipment procurement and fabrication; POC equipment inspection; POC equipment installation, shakedown and operation; process evaluation; dismantling of the system; final report. Accomplishments to date are described on the site selection, a work plan for bench-scale testing, preliminary engineering and design of POC equipment, and coal characterization.

  8. Minimizing Waste from the Oil Industry: Scale Treatment and Scrap Recycling

    SciTech Connect

    Lindberg, M.

    2002-02-26

    Naturally occurring radioactive material is technologically concentrated in the piping in systems in the oil and gas industry, especially in the offshore facilities. The activity, mainly Ra-226, in the scales in the systems are often at levels classified as low level radioactive waste (LSA) in the industry. When the components and pipes are descaled for maintenance or recycling purposes, usually by high-pressure water jetting, the LSA scales arising constitute a significant quantity of radioactive waste for disposal. A new process is under development for the treatment of scales, where the radioactive solids are separated from the inactive. This would result in a much smaller fraction to be deposited as radioactive waste. The radioactive part recovered from the scales will be reduced to a stable non-metallic salt and because the volume is significantly smaller then the original material, will minimize the cost for disposal. The pipes, that have been cleaned by high pressure water jetting can either be reused or free released by scrapping and melting for recycling.

  9. Utilization of artificial recharged effluent as makeup water for industrial cooling system: corrosion and scaling.

    PubMed

    Wei, Liangliang; Qin, Kena; Zhao, Qingliang; Noguera, Daniel R; Xin, Ming; Liu, Chengcai; Keene, Natalie; Wang, Kun; Cui, Fuyi

    2016-01-01

    The secondary effluent from wastewater treatment plants was reused for industrial cooling water after pre-treatment with a laboratory-scale soil aquifer treatment (SAT) system. Up to a 95.3% removal efficiency for suspended solids (SS), 51.4% for chemical oxygen demand (COD), 32.1% for Cl(-) and 30.0% SO4(2-) were observed for the recharged secondary effluent after the SAT operation, which is essential for controlling scaling and corrosion during the cooling process. As compared to the secondary effluent, the reuse of the 1.5 m depth SAT effluent decreased the corrosion by 75.0%, in addition to a 55.1% decline of the scales/biofouling formation (with a compacted structure). The experimental results can satisfy the Chinese criterion of Design Criterion of the Industrial Circulating Cooling Water Treatment (GB 50050-95), and was more efficient than tertiary effluent which coagulated with ferric chloride. In addition, chemical structure of the scales/biofouling obtained from the cooling system was analyzed.

  10. Advanced techniques for energy-efficient industrial-scale continuous chromatography

    SciTech Connect

    DeCarli, J.P. II ); Carta, G. . Dept. of Chemical Engineering); Byers, C.H. )

    1989-11-01

    Continuous annular chromatography (CAC) is a developing technology that allows truly continuous chromatographic separations. Previous work has demonstrated the utility of this technology for the separation of various materials by isocratic elution on a bench scale. Novel applications and improved operation of the process were studied in this work, demonstrating that CAC is a versatile apparatus which is capable of separations at high throughput. Three specific separation systems were investigated. Pilot-scale separations at high loadings were performed using an industrial sugar mixture as an example of scale-up for isocratic separations. Bench-scale experiments of a low concentration metal ion mixture were performed to demonstrate stepwise elution, a chromatographic technique which decreases dilution and increases sorbent capacity. Finally, the separation of mixtures of amino acids by ion exchange was investigated to demonstrate the use of displacement development on the CAC. This technique, which perhaps has the most potential, when applied to the CAC allowed simultaneous separation and concentration of multicomponent mixtures on a continuous basis. Mathematical models were developed to describe the CAC performance and optimize the operating conditions. For all the systems investigated, the continuous separation performance of the CAC was found to be very nearly the same as the batchwise performance of conventional chromatography. the technology appears, thus, to be very promising for industrial applications. 43 figs., 9 tabs.

  11. Status of health and environmental research relative to coal gasification 1976 to the present

    SciTech Connect

    Wilzbach, K.E.; Reilly, C.A. Jr.

    1982-10-01

    Health and environmental research relative to coal gasification conducted by Argonne National Laboratory, the Inhalation Toxicology Research Institute, and Oak Ridge National Laboratory under DOE sponsorship is summarized. The studies have focused on the chemical and toxicological characterization of materials from a range of process streams in five bench-scale, pilot-plant and industrial gasifiers. They also address ecological effects, industrial hygiene, environmental control technology performance, and risk assessment. Following an overview of coal gasification technology and related environmental concerns, integrated summaries of the studies and results in each area are presented and conclusions are drawn. Needed health and environmental research relative to coal gasification is identified.

  12. THE DEVELOPMENT OF COAL-BASED TECHNOLOGIES FOR DEPARTMENT OF DEFENSE FACILITIES

    SciTech Connect

    Bruce G. Miller; Sharon Falcone Miller; Sarma V. Pisupati; Chunshan Song; Ronald S. Wasco; Ronald T. Wincek; Xiaochun Xu; Alan W. Scaroni; Richard Hogg; Subhash Chander; M. Thaddeus Ityokumbul; Mark S. Klima; Peter T. Luckie; Adam Rose; Richard L. Gordon; Jeffrey Lazo; A. Michael Schaal

    2004-01-30

    The third phase of a three-phase project investigating the development of coal-based technologies for US Department of Defense (DOD) facilities was completed. The objectives of the project were to: decrease DOD's dependence on foreign oil and increase its use of coal; promote public and private sector deployment of technologies for utilizing coal-based fuels in oil-designed combustion equipment; and provide a continuing environment for research and development of coal-based fuel technologies for small-scale applications at a time when market conditions in the US are not favorable for the introduction of coal-fired equipment in the commercial and industrial capacity ranges. The Phase III activities were focused on evaluating deeply-cleaned coals as fuels for industrial boilers and investigating emissions control strategies for providing ultra-low emissions when firing coal-based fuels. This was addressed by performing coal beneficiation and preparation studies, and bench- to demonstration-scale emissions reduction studies. In addition, economic studies were conducted focused on determining cost and market penetration, selection of incentives, and regional economic impacts of coal-based technologies.

  13. 76 FR 48833 - Notice of Filings of Self-Certifications of Coal Capability Under the Powerplant and Industrial...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-09

    ... coal or another alternate fuel as a primary energy source. Pursuant to FUA section 201(d), in order to... natural gas or petroleum as its primary energy source shall certify to the Secretary of Energy (Secretary... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY...

  14. 78 FR 54879 - Notice of Filing of Self-Certification of Coal Capability Under the Powerplant and Industrial...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-09-06

    ... operated without the capability to use coal or another alternate fuel as a primary energy source. Pursuant... proposing to use natural gas or petroleum as its primary energy source shall certify to the Secretary of... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY...

  15. Effects of agricultural and industrial by-products on restoration quality of reclaimed coal mine soil in Mississippi

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The generally low level of organic C in reclaimed coal mine soils may limit microbial activity. The oxidized material used as substitute soil for upland restoration at a surface mine in Mississippi contains a mixture of topsoil plus oxidized subsoils that provide for biota reestablishment. By incre...

  16. Clean coal reference plants: Pulverized coal boiler with flue gas desulfurization. Topical report

    SciTech Connect

    1995-09-01

    The Clean Coal Technology Demonstration Program (CCT) is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of full-scale facilities. The goal of the program is to provide the U.S. energy marketplace with a number of advanced, more efficient, and environmentally responsive coal-using technologies. To achieve this goal, a multiphased effort consisting of five separate solicitations has been completed. The Morgantown Energy Technology Center (METC) has the responsibility for monitoring the CCT Projects within certain technology categories, which, in general, correspond to the center`s areas of technology development. Primarily the categories of METC CCT projects are: atmospheric fluid bed combustion, pressurized fluidized bed combustion, integrated gasification combined cycle, mild gasification, and industrial applications.

  17. Quality by design: scale-up of freeze-drying cycles in pharmaceutical industry.

    PubMed

    Pisano, Roberto; Fissore, Davide; Barresi, Antonello A; Rastelli, Massimo

    2013-09-01

    This paper shows the application of mathematical modeling to scale-up a cycle developed with lab-scale equipment on two different production units. The above method is based on a simplified model of the process parameterized with experimentally determined heat and mass transfer coefficients. In this study, the overall heat transfer coefficient between product and shelf was determined by using the gravimetric procedure, while the dried product resistance to vapor flow was determined through the pressure rise test technique. Once model parameters were determined, the freeze-drying cycle of a parenteral product was developed via dynamic design space for a lab-scale unit. Then, mathematical modeling was used to scale-up the above cycle in the production equipment. In this way, appropriate values were determined for processing conditions, which allow the replication, in the industrial unit, of the product dynamics observed in the small scale freeze-dryer. This study also showed how inter-vial variability, as well as model parameter uncertainty, can be taken into account during scale-up calculations.

  18. Rheology of coal-water slurries prepared by the HP roll mill grinding of coal

    SciTech Connect

    Fuerstenau, D.W.

    1992-12-01

    The objective of the research is the development of improved technology for the preparation of coal-water slurries, which have potential for replacing fuel oil in direct combustion. The fine grinding of coal is a crucial step in the manufacture of coal-water slurries. In this context, currently available grinding mills exhibit poor energy efficiency for size reduction and non-optimum packing characteristics of the ground coal. The first increases the cost of manufacture of coal-water slurries and the second adversely affects their rheological properties. The newly invented choke-fed, high-pressure roll mill is up to 50% more energy efficient and, moreover, there are reasons to believe that it produces a size distribution of ground particles which is closer to the dense packing composition. The high-pressure roll mill (which is perhaps the only really significant innovation in industrial comminution in this century) has lower capital cost, occupies less floor space, shows negligible wear rate, accepts feed with a wide range of moisture contents and, of particular importance, it can be scaled up to grind hundreds of tons of solids per hour. The high-pressure roll mill provides a unique opportunity to develop an improved technology for preparing coal-water slurries. Our research group in the University of California at Berkeley not only has a fully instrumented, laboratory-scale, choke-fed. high-pressure roll mill (the only one of its kind in the United States) but also fully instrumented laboratory ball mills for comparative fine coal preparation purposes. In this research program, our plans are to systematically investigate comminution energy consumption, deagglomeration procedures, and the stability and rheology of coal-water slurry fuel prepared with high-pressure roll mill, and to compare the results with slurry prepared with ball-milled coal.

  19. Coal char fragmentation during pulverized coal combustion

    SciTech Connect

    Baxter, L.L.

    1995-07-01

    A series of investigations of coal and char fragmentation during pulverized coal combustion is reported for a suite of coals ranging in rank from lignite to low-volatile (lv) bituminous coal under combustion conditions similar to those found in commercial-scale boilers. Experimental measurements are described that utilize identical particle sizing characteristics to determine initial and final size distributions. Mechanistic interpretation of the data suggest that coal fragmentation is an insignificant event and that char fragmentation is controlled by char structure. Chars forming cenospheres fragment more extensively than solid chars. Among the chars that fragment, large particles produce more fine material than small particles. In all cases, coal and char fragmentation are seen to be sufficiently minor as to be relatively insignificant factors influencing fly ash size distribution, particle loading, and char burnout.

  20. 78 FR 19495 - Draft Guidance for Industry on Scale-Up and Post-Approval Changes: Manufacturing Equipment...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-04-01

    ... HUMAN SERVICES Food and Drug Administration Draft Guidance for Industry on Scale-Up and Post-Approval...: Notice. SUMMARY: The Food and Drug Administration (FDA) is announcing the availability of a scale-up and... Oral Dosage Forms--Scale-Up and Post-Approval Changes: Chemistry, Manufacturing and Controls, In...

  1. The large-scale process of microbial carbonate precipitation for nickel remediation from an industrial soil.

    PubMed

    Zhu, Xuejiao; Li, Weila; Zhan, Lu; Huang, Minsheng; Zhang, Qiuzhuo; Achal, Varenyam

    2016-12-01

    Microbial carbonate precipitation is known as an efficient process for the remediation of heavy metals from contaminated soils. In the present study, a urease positive bacterial isolate, identified as Bacillus cereus NS4 through 16S rDNA sequencing, was utilized on a large scale to remove nickel from industrial soil contaminated by the battery industry. The soil was highly contaminated with an initial total nickel concentration of approximately 900 mg kg(-1). The soluble-exchangeable fraction was reduced to 38 mg kg(-1) after treatment. The primary objective of metal stabilization was achieved by reducing the bioavailability through immobilizing the nickel in the urease-driven carbonate precipitation. The nickel removal in the soils contributed to the transformation of nickel from mobile species into stable biominerals identified as calcite, vaterite, aragonite and nickelous carbonate when analyzed under XRD. It was proven that during precipitation of calcite, Ni(2+) with an ion radius close to Ca(2+) was incorporated into the CaCO3 crystal. The biominerals were also characterized by using SEM-EDS to observe the crystal shape and Raman-FTIR spectroscopy to predict responsible bonding during bioremediation with respect to Ni immobilization. The electronic structure and chemical-state information of the detected elements during MICP bioremediation process was studied by XPS. This is the first study in which microbial carbonate precipitation was used for the large-scale remediation of metal-contaminated industrial soil.

  2. Probing Rubber Cross-Linking Generation of Industrial Polymer Networks at Nanometer Scale.

    PubMed

    Gabrielle, Brice; Gomez, Emmanuel; Korb, Jean-Pierre

    2016-06-23

    We present improved analyses of rheometric torque measurements as well as (1)H double-quantum (DQ) nuclear magnetic resonance (NMR) buildup data on polymer networks of industrial compounds. This latter DQ NMR analysis allows finding the distribution of an orientation order parameter (Dres) resulting from the noncomplete averaging of proton dipole-dipole couplings within the cross-linked polymer chains. We investigate the influence of the formulation (filler and vulcanization systems) as well as the process (curing temperature) ending to the final polymer network. We show that DQ NMR follows the generation of the polymer network during the vulcanization process from a heterogeneous network to a very homogeneous one. The time variations of microscopic Dres and macroscopic rheometric torques present power-law behaviors above a threshold time scale with characteristic exponents of the percolation theory. We observe also a very good linear correlation between the kinetics of Dres and rheometric data routinely performed in industry. All these observations confirm the description of the polymer network generation as a critical phenomenon. On the basis of all these results, we believe that DQ NMR could become a valuable tool for investigating in situ the cross-linking of industrial polymer networks at the nanometer scale.

  3. Partial Oxidation Gas Turbine for Power and Hydrogen Co-Production from Coal-Derived Fuel in Industrial Applications

    SciTech Connect

    Joseph Rabovitser

    2009-06-30

    , pressures, and volumetric flows practically identical. In POGT mode, the turbine specific power (turbine net power per lb mass flow from expander exhaust) is twice the value of the onventional turbine. POGT based IGCC plant conceptual design was developed and major components have been identified. Fuel flexible fluid bed gasifier, and novel POGT unit are the key components of the 100 MW IGCC plant for co producing electricity, hydrogen and/or yngas. Plant performances were calculated for bituminous coal and oxygen blown versions. Various POGT based, natural gas fueled systems for production of electricity only, coproduction of electricity and hydrogen, and co production of electricity and syngas for gas to liquid and hemical processes were developed and evaluated. Performance calculations for several versions of these systems were conducted. 64.6 % LHV efficiency for fuel to electricity in combined cycle was achieved. Such a high efficiency arise from using of syngas from POGT exhaust s a fuel that can provide required temperature level for superheated steam generation in HRSG, as well as combustion air preheating. Studies of POGT materials and combustion instabilities in POR were conducted and results reported. Preliminary market assessment was performed, and recommendations for POGT systems applications in oil industry were defined. POGT technology is ready to proceed to the engineering prototype stage, which is recommended.

  4. Anaerobic sequencing batch reactor in pilot scale for treatment of tofu industry wastewater

    SciTech Connect

    Rahayu, Suparni Setyowati; Purwanto, Budiyono

    2015-12-29

    The small industry of tofu production process releases the waste water without being processed first, and the wastewater is directly discharged into water. In this study, Anaerobic Sequencing Batch Reactor in Pilot Scale for Treatment of Tofu Industry was developed through an anaerobic process to produce biogas as one kind of environmentally friendly renewable energy which can be developed into the countryside. The purpose of this study was to examine the fundamental characteristics of organic matter elimination of industrial wastewater with small tofu effective method and utilize anaerobic active sludge with Anaerobic Sequencing Bath Reactor (ASBR) to get rural biogas as an energy source. The first factor is the amount of the active sludge concentration which functions as the decomposers of organic matter and controlling selectivity allowance to degrade organic matter. The second factor is that HRT is the average period required substrate to react with the bacteria in the Anaerobic Sequencing Bath Reactor (ASBR).The results of processing the waste of tofu production industry using ASBR reactor with active sludge additions as starter generates cumulative volume of 5814.4 mL at HRT 5 days so that in this study it is obtained the conversion 0.16 L of CH{sub 4}/g COD and produce biogas containing of CH{sub 4}: 81.23% and CO{sub 2}: 16.12%. The wastewater treatment of tofu production using ASBR reactor is able to produce renewable energy that has economic value as well as environmentally friendly by nature.

  5. Anaerobic sequencing batch reactor in pilot scale for treatment of tofu industry wastewater

    NASA Astrophysics Data System (ADS)

    Rahayu, Suparni Setyowati; Purwanto, Budiyono

    2015-12-01

    The small industry of tofu production process releases the waste water without being processed first, and the wastewater is directly discharged into water. In this study, Anaerobic Sequencing Batch Reactor in Pilot Scale for Treatment of Tofu Industry was developed through an anaerobic process to produce biogas as one kind of environmentally friendly renewable energy which can be developed into the countryside. The purpose of this study was to examine the fundamental characteristics of organic matter elimination of industrial wastewater with small tofu effective method and utilize anaerobic active sludge with Anaerobic Sequencing Bath Reactor (ASBR) to get rural biogas as an energy source. The first factor is the amount of the active sludge concentration which functions as the decomposers of organic matter and controlling selectivity allowance to degrade organic matter. The second factor is that HRT is the average period required substrate to react with the bacteria in the Anaerobic Sequencing Bath Reactor (ASBR).The results of processing the waste of tofu production industry using ASBR reactor with active sludge additions as starter generates cumulative volume of 5814.4 mL at HRT 5 days so that in this study it is obtained the conversion 0.16 L of CH4/g COD and produce biogas containing of CH4: 81.23% and CO2: 16.12%. The wastewater treatment of tofu production using ASBR reactor is able to produce renewable energy that has economic value as well as environmentally friendly by nature.

  6. Use of a moss biomonitoring method to compile emission inventories for small-scale industries.

    PubMed

    Varela, Z; Aboal, J R; Carballeira, A; Real, C; Fernández, J A

    2014-06-30

    We used a method of detecting small-scale pollution sources (DSSP) that involves measurement of the concentrations of elements in moss tissues, with the following aims: (i) to determine any common qualitative patterns of contaminant emissions for individual industrial sectors, (ii) to compare any such patterns with previously described patterns, and (iii) to compile an inventory of the metals and metalloids emitted by the industries considered. Cluster analysis revealed that there were no common patterns of emission associated with the industrial sectors, probably because of differences in production processes and in the types of fuel and raw materials. However, when these variables were shared by different factories, the concentrations of the elements in moss tissues enabled the factories to be grouped according to their emissions. We compiled a list of the metals and metalloids emitted by the factories under study and found that the DSSP method was satisfactory for this purpose in most cases (53 of 56). The method appears to be a useful tool for compiling contaminant inventories; it may also be useful for determining the efficacy of technical improvements aimed at reducing the industrial emission of contaminants and could be incorporated in environmental monitoring and control programmes.

  7. Fluidized bed coal desulfurization

    NASA Technical Reports Server (NTRS)

    Ravindram, M.

    1983-01-01

    Laboratory scale experiments were conducted on two high volatile bituminous coals in a bench scale batch fluidized bed reactor. Chemical pretreatment and posttreatment of coals were tried as a means of enhancing desulfurization. Sequential chlorination and dechlorination cum hydrodesulfurization under modest conditions relative to the water slurry process were found to result in substantial sulfur reductions of about 80%. Sulfur forms as well as proximate and ultimate analyses of the processed coals are included. These studies indicate that a fluidized bed reactor process has considerable potential for being developed into a simple and economic process for coal desulfurization.

  8. Coal: the new black

    SciTech Connect

    Tullo, A.H.; Tremblay, J.-F.

    2008-03-15

    Long eclipsed by oil and natural gas as a raw material for high-volume chemicals, coal is making a comeback, with oil priced at more than $100 per barrel. It is relatively cheap feedstock for chemicals such as methanol and China is building plants to convert coal to polyolefins on a large scale and interest is spreading worldwide. Over the years several companies in the US and China have made fertilizers via the gasification of coal. Eastman in Tennessee gasifies coal to make methanol which is then converted to acetic acid, acetic anhydride and acetate fiber. The future vision is to convert methanol to olefins. UOP and Lurgi are the major vendors of this technology. These companies are the respective chemical engineering arms of Honeywell and Air Liquide. The article reports developments in China, USA and India on coal-to-chemicals via coal gasification or coal liquefaction. 2 figs., 2 photo.

  9. Coal supply for California

    NASA Technical Reports Server (NTRS)

    Yancik, J. J.

    1978-01-01

    The potential sources and qualities of coals available for major utility and industrial consumers in California are examined and analyzed with respect to those factors that would affect the reliability of supplies. Other considerations, such as the requirements and assurances needed by the coal producers to enter into long-term contracts and dedicate large reserves of coal to these contracts are also discussed. Present and potential future mining contraints on coal mine operators are identified and analyzed with respect to their effect on availability of supply.

  10. Application of ERTS-1 imagery to fracture related mine safety hazards in the coal mining industry. [Indiana

    NASA Technical Reports Server (NTRS)

    Wier, C. E.; Wobber, F. J. (Principal Investigator); Russell, O. R.; Amato, R. V.; Leshendok, T. V.

    1974-01-01

    The author has identified the following significant results. New fracture detail of Indiana has been observed and mapped from ERTS-1 imagery. Studies so far indicate a close relationship between the directions of fracture traces mapped from the imagery, fractures measured on bedrock outcrops, and fractures measured in the underground mines. First hand observations and discussions with underground mine operators indicate good correlation of mine hazard maps prepared from ERTS-1/aircraft imagery and actual roof falls. The inventory of refuse piles/slurry ponds of the coal field of Indiana has identified over 225 such sites from past mining operations. These data will serve the State Legislature in making tax decisions on coal mining which take on increased importance because of the energy crisis.

  11. Enhanced Combustion Low NOx Pulverized Coal Burner

    SciTech Connect

    David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost

    2007-06-30

    evaluation and commercial application. During the project performance period, Alstom performed computational fluid dynamics (CFD) modeling and large pilot scale combustion testing in its Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut in support of these objectives. The NOx reduction approach was to optimize near-field combustion to ensure that minimum NOx emissions are achieved with minimal impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down. Several iterations of CFD and combustion testing on a Midwest coal led to an optimized design, which was extensively combustion tested on a range of coals. The data from these tests were then used to validate system costs and benefits versus SCR. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive subbituminous coal to a moderately reactive Western bituminous coal to a much less reactive Midwest bituminous coal. Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis. Bench-scale characterization of the three test coals showed that both NOx emissions and combustion performance are a strong function of coal properties. The more reactive coals evolved more of their fuel bound nitrogen in the substoichiometric main burner zone than less reactive coal, resulting in the potential for lower NOx emissions. From a combustion point of view, the more reactive coals also showed lower carbon in ash and CO values than the less reactive coal at any given main burner zone stoichiometry. According to bench-scale results, the subbituminous coal was found to be the most amenable to both low NOx, and acceptably low combustibles in the flue gas, in an air staged low NOx system. The Midwest bituminous coal, by contrast, was predicted to

  12. Directory of coal production ownership, 1979

    SciTech Connect

    Thompson, B.

    1981-10-01

    Ownership patterns in the coal industry are highly complex. Many producers are diversified into other lines of activity. The pattern and extent of this diversification has varied through time. In the past, steel and nonferrous metals companies had major coal industry involvement. This is still true today. However, other types of enterprises have entered the industry de novo or through merger. Those of greatest significance in recent times have involved petroleum and particularly public utility companies. This report attempts to identify, as accurately as possible, production ownership patterns in the coal industry. The audience for this Directory is anyone who is interested in accurately tracing the ownership of coal companies to parent companies, or who is concerned about the structure of ownership in the US coal industry. This audience includes coal industry specialists, coal industry policy analysts, economists, financial analysts, and members of the investment community.

  13. An analysis of markets for small-scale, advanced coal-combustion technology in Spain, Italy, and Turkey

    SciTech Connect

    Placet, M.; Gerry, P.A.; Kenski, D.M.; Kern, D.M.; Nehring, J.L.; Szpunar, C.B.

    1989-09-01

    This report discusses the examination of potential overseas markets for using small-scale, US-developed, advanced coal-combustion technologies (ACTs). In previous work, member countries of the Organization for Economic Cooperation and Development (OECD) were rated on their potential for using ACTs through a comprehensive screening methodology. The three most promising OECD markets were found to be Spain, Italy, and Turkey. This report provides in-depth analyses of these three selected countries. First, it addresses changes in the European Community with particular reference to the 1992 restructuring and its potential effect on the energy situation in Europe, specifically in the three subject countries. It presents individual country studies that examine demographics, economics, building infrastructures, and energy-related factors. Potential niches for ACTs are explored for each country through regional analyses. Marketing channels, strategies, and the trading environments in each country are also discussed. The information gathered indicates that Turkey is a most promising market, Spain is a fairly promising market, and Italy appears to be a somewhat limited market for US ACTs. 76 refs., 16 figs., 14 tabs.

  14. Experimental investigation of mobile small-scale liquefier for 10000 NM3/D of coal bed methane gas

    NASA Astrophysics Data System (ADS)

    Sun, Zhaohu; Wu, J. F.; Gong, Maoqiong; Guo, Ping

    2012-06-01

    There is a growing recognition that unconventional sources of gas, such as shale gas, coal bed methane (CBM) and deep tight gas will contribute a significant component of future gas supplies as technologies evolve. In recent years, the interest in such source of gas utilization technologies based on small-scale LNG production has been rising steeply. In this paper, a mobile liquefier prototype for 10000 Nm3/d of CBM has been designed, constructed and tested. It has two cascade refrigeration systems. The high-temperature refrigeration system will pre-cool the resource gas to 5oC, and the low-temperature refrigeration system will continue to cool the resource gas to the liquefied point with a Mixed Refrigerant Cycle (MRC). The kernel compressor is a conventional oil-lubricated air-conditioning compressor with the discharge pressure of 2.0 MPa. The main heat exchanger is plate-fin heat exchanger with four passages. A series of experiments have been done on the prototype liquefier at different resource gas pressures and environmental temperatures. It is less than one hour from the start of the equipment to the existence of LNG. The maximum production of LNG is about 20 m3/d when a stream of about 12500 Nm3/d of pure CBM at a process pressure of 1.3 MPa is liquefied. The energy consumption of liquefying 1 Nm3 methane is 0.612 kWh.

  15. Do we have to consider temperature-dependent material properties in large-scale environmental impact assessments of underground coal gasification?

    NASA Astrophysics Data System (ADS)

    Otto, Christopher; Kempka, Thomas

    2015-04-01

    Underground coal gasification (UCG) can increase the world-wide coal reserves by utilization of coal deposits not mineable by conventional methods. The UCG process involves combusting coal in situ to produce a high-calorific synthesis gas which can be applied for electricity generation or chemical feedstock production. Apart from its high economic potentials, UCG may induce environmental impacts such as ground subsidence associated with groundwater pollution due to generation of hydraulic connectivities between the UCG reactor and adjacent aquifers. These changes overburden conductivity may introduce potential migration pathways for UCG contaminants such as organic (phenols, benzene, PAHs and heterocyclics) and inorganic (ammonia, sulphates, cyanides, and heavy metals) pollutants. Mitigation of potential environmental UCG impacts can be achieved by improving the understanding of coupled thermo-hydro-mechanical processes in the rocks surrounding the UCG reactor. In the present study, a coupled thermo-mechanical model has been developed to carry out a parameter sensitivity analysis and assess permeability changes derived from volumetric strain increments in the UCG reactor overburden. Our simulation results demonstrate that thermo-mechanical rock behavior is mainly influenced by the thermal expansion coefficient, tensile strength and elastic modulus of the surrounding rock. A comparison of temperature-dependent and temperature-independent simulation results indicates high variations in the distribution of total displacements in the UCG reactor vicinity related to thermal stress, but only negligible differences in permeability changes. Hence, temperature-dependent thermo-mechanical parameters have to be considered in the assessment of near-field UCG impacts, while far-field models can achieve a higher computational efficiency by using temperature-independent thermo-mechanical parameters. Considering the findings of the present study in the large-scale assessment of

  16. Industrial scale microwave processing of tomato juice using a novel continuous microwave system.

    PubMed

    Stratakos, Alexandros Ch; Delgado-Pando, Gonzalo; Linton, Mark; Patterson, Margaret F; Koidis, Anastasios

    2016-01-01

    This study evaluated the effect of an industrial scale continuous flow microwave volumetric heating system in comparison to conventional commercial scale pasteurisation for the processing of tomato juice in terms of physicochemical properties, microbial characteristics and antioxidant capacity. The effect against oxidative stress in Caco-2 cells, after in vitro digestion was also investigated. Physicochemical and colour characteristics of juices were very similar between technologies and during storage. Both conventional and microwave pasteurisation inactivated microorganisms and kept them in low levels throughout storage. ABTS[Symbol: see text](+) values, but not ORAC, were higher for the microwave pasteurised juice at day 0 however no significant differences between juices were observed during storage. Juice processed with the microwave system showed an increased cytoprotective effect against H2O2 induced oxidation in Caco-2 cells. Organoleptic analysis revealed that the two tomato juices were very similar. The continuous microwave volumetric heating system appears to be a viable alternative to conventional pasteurisation.

  17. Development and testing of commercial-scale, coal-fired combustion systems, Phase 3. Technical progress report, October 1990--December 1990

    SciTech Connect

    Not Available

    1990-12-31

    The US Department of Energy`s Pittsburgh Energy Technology Center (PETC) is actively pursuing the development and testing of coal-fired combustion systems for residential, commercial, and industrial market sectors. In response, MTCI initiated the development of a new combustor technology based on the principle of pulse combustion under the sponsorship of PETC (Contract No. AC22-83PC60419). The initial pulse combustor development program was conducted in three phases (MTCI, Development of a Pulsed Coal Combustor Fired with CWM, Phase III Final Report, DOE Contract No. AC22-83PC60419, November 1986). Phase I included a review of the prior art in the area of pulse combustion and the development of pulse combustor design concepts. It led to the conclusion that pulse combustors offer technical and base-of-operation advantages over conventional burners and also indicated favorable economics for replacement of oil- and gas-fired equipment.

  18. POC-scale testing of a dry triboelectrostatic separator for fine coal cleaning. Second quarterly technical progress report, January 1, 1996--March 31, 1996

    SciTech Connect

    Yoon, R.-H.; Luttrell, G.H.; Adel, G.T.

    1996-08-01

    The Pittsburgh Energy Technology Center (PETC) developed a triboelectrostatic separation (TES) process which is capable of removing mineral matter from coal without using water. A distinct advantage of this dry coal cleaning process is that it does not entail costly steps of dewatering which is a common problem associated with conventional fine coal cleaning processes. It is the objective of this project to conduct a series of proof-of-concept (POC) scale tests at a throughput of 200--250 kg/hr and obtain scale- up information. Prior to the POC testing, bench-scale test work will be conducted with the objective of increasing the separation efficiency and throughput, for which changes in the basic designs for the charger and the separator may be necessary. The bench- and POC- scale test work will be carried out to evaluate various operating parameters and establish a reliable scale-up procedure. The scale-up data will be used to analyze the economic merits of the TES process. All required documents associated with project planning were completed and submitted to DOE for approval during the second quarter of this project. Approval of the project work plan is still pending at this time subject to additional review by DOE of requested modifications to the statement of work. Accomplishments during this reporting period include the set-up of an apparatus for assessing tribocharger performance, continued construction of the bench-scale (1 kg/hr) triboelectrostatic separator and initial development of a fundamental model for predicting the motion of charged particles in a non-uniform electrostatic field.

  19. Metabolic Profiling of Geobacter sulfurreducens during Industrial Bioprocess Scale-Up.

    PubMed

    Muhamadali, Howbeer; Xu, Yun; Ellis, David I; Allwood, J William; Rattray, Nicholas J W; Correa, Elon; Alrabiah, Haitham; Lloyd, Jonathan R; Goodacre, Royston

    2015-05-15

    During the industrial scale-up of bioprocesses it is important to establish that the biological system has not changed significantly when moving from small laboratory-scale shake flasks or culturing bottles to an industrially relevant production level. Therefore, during upscaling of biomass production for a range of metal transformations, including the production of biogenic magnetite nanoparticles by Geobacter sulfurreducens, from 100-ml bench-scale to 5-liter fermentors, we applied Fourier transform infrared (FTIR) spectroscopy as a metabolic fingerprinting approach followed by the analysis of bacterial cell extracts by gas chromatography-mass spectrometry (GC-MS) for metabolic profiling. FTIR results clearly differentiated between the phenotypic changes associated with different growth phases as well as the two culturing conditions. Furthermore, the clustering patterns displayed by multivariate analysis were in agreement with the turbidimetric measurements, which displayed an extended lag phase for cells grown in a 5-liter bioreactor (24 h) compared to those grown in 100-ml serum bottles (6 h). GC-MS analysis of the cell extracts demonstrated an overall accumulation of fumarate during the lag phase under both culturing conditions, coinciding with the detected concentrations of oxaloacetate, pyruvate, nicotinamide, and glycerol-3-phosphate being at their lowest levels compared to other growth phases. These metabolites were overlaid onto a metabolic network of G. sulfurreducens, and taking into account the levels of these metabolites throughout the fermentation process, the limited availability of oxaloacetate and nicotinamide would seem to be the main metabolic bottleneck resulting from this scale-up process. Additional metabolite-feeding experiments were carried out to validate the above hypothesis. Nicotinamide supplementation (1 mM) did not display any significant effects on the lag phase of G. sulfurreducens cells grown in the 100-ml serum bottles. However

  20. Education, Training and Employment in Small-Scale Enterprises: Three Industries in Sao Paulo, Brazil. IIEP Research Report No. 63.

    ERIC Educational Resources Information Center

    Leite, Elenice M.; Caillods, Francoise

    Despite the prophecies forecasting their probable disappearance or annihilation, small-scale enterprises have persisted in the Brazilian industrial structure since 1950. To account for the survival of small firms in Brazil, specifically in the state of Sao Paulo, a study examined 100 small firms in three industrial sectors: clothing, mechanical…

  1. Microbial desulfurization of coal

    NASA Technical Reports Server (NTRS)

    Dastoor, M. N.; Kalvinskas, J. J.

    1978-01-01

    Experiments indicate that several sulfur-oxidizing bacteria strains have been very efficient in desulfurizing coal. Process occurs at room temperature and does not require large capital investments of high energy inputs. Process may expand use of abundant reserves of high-sulfur bituminous coal, which is currently restricted due to environmental pollution. On practical scale, process may be integrated with modern coal-slurry transportation lines.

  2. GIS Representation of Coal-Bearing Areas in Africa

    USGS Publications Warehouse

    Merrill, Matthew D.; Tewalt, Susan J.

    2008-01-01

    The African continent contains approximately 5 percent of the world's proven recoverable reserves of coal (World Energy Council, 2007). Energy consumption in Africa is projected to grow at an annual rate of 2.3 percent from 2004 through 2030, while average consumption in first-world nations is expected to rise at 1.4 percent annually (Energy Information Administration, 2007). Coal reserves will undoubtedly continue to be part of Africa's energy portfolio as it grows in the future. A review of academic and industrial literature indicates that 27 nations in Africa contain coal-bearing rock. South Africa accounts for 96 percent of Africa's total proven recoverable coal reserves, ranking it sixth in the world. This report is a digital compilation of information on Africa's coal-bearing geology found in the literature and is intended to be used in small scale spatial investigations in a Geographic Information System (GIS) and as a visual aid for the discussion of Africa's coal resources. Many maps of African coal resources often include points for mine locations or regional scale polygons with generalized borders depicting basin edges. Point locations are detailed but provide no information regarding extent, and generalized polygons do not have sufficient detail. In this dataset, the polygons are representative of the actual coal-bearing lithology both in location and regional extent. Existing U.S. Geological Survey (USGS) digital geology datasets provide the majority of the base geologic polygons. Polygons for the coal-bearing localities were clipped from the base geology that represented the age and extent of the coal deposit as indicated in the literature. Where the 1:5,000,000-scale geology base layer's ages conflicted with those in the publications, polygons were generated directly from the regional African coal maps (1:500,000 scale, approximately) in the published material. In these cases, coal-bearing polygons were clipped to the literature's indicated coal

  3. Evaluation of a new annular capacitance probe for biomass monitoring in industrial pilot-scale fermentations.

    PubMed

    Ferreira, Ana P; Vieira, Luís M; Cardoso, Joaquim P; Menezes, José C

    2005-04-06

    The four-pin electrode capacitance probe has already shown to be a valuable tool for on-line monitoring viable biomass concentration in industrial-type fermentations. A new prototype annular probe was developed and its performance in real-time monitoring the concentration of viable cells during industrial pilot-scale fermentation for the production of an Active Pharmaceutical Ingredient (API) was investigated and compared to the four-pin probe. A set of 14 fermentations was monitored on-line: four of them with the four-pin probe, the remaining with the annular probe. The performance of both the annular and the four-pin electrode probe were compared against each other and against off-line measurements (viscosity and packed mycelial volume). The prototype annular probe showed to have higher signal intensity and sensitivity than the standard four-pin probe, with higher signal-to-noise ratio. Furthermore, its new design and construction proved to be easier to handle in an industrial environment.

  4. Exergy analysis of an industrial-scale ultrafiltrated (UF) cheese production plant: a detailed survey

    NASA Astrophysics Data System (ADS)

    Nasiri, Farshid; Aghbashlo, Mortaza; Rafiee, Shahin

    2017-02-01

    In this study, a detailed exergy analysis of an industrial-scale ultrafiltrated (UF) cheese production plant was conducted based on actual operational data in order to provide more comprehensive insights into the performance of the whole plant and its main subcomponents. The plant included four main subsystems, i.e., steam generator (I), above-zero refrigeration system (II), Bactocatch-assisted pasteurization line (III), and UF cheese production line (IV). In addition, this analysis was aimed at quantifying the exergy destroyed in processing a known quantity of the UF cheese using the mass allocation method. The specific exergy destruction of the UF cheese production was determined at 2330.42 kJ/kg. The contributions of the subsystems I, II, III, and IV to the specific exergy destruction of the UF cheese production were computed as 1337.67, 386.18, 283.05, and 323.51 kJ/kg, respectively. Additionally, it was observed through the analysis that the steam generation system had the largest contribution to the thermodynamic inefficiency of the UF cheese production, accounting for 57.40 % of the specific exergy destruction. Generally, the outcomes of this survey further manifested the benefits of applying exergy analysis for design, analysis, and optimization of industrial-scale dairy processing plants to achieve the most cost-effective and environmentally-benign production strategies.

  5. Exergy analysis of an industrial-scale ultrafiltrated (UF) cheese production plant: a detailed survey

    NASA Astrophysics Data System (ADS)

    Nasiri, Farshid; Aghbashlo, Mortaza; Rafiee, Shahin

    2016-05-01

    In this study, a detailed exergy analysis of an industrial-scale ultrafiltrated (UF) cheese production plant was conducted based on actual operational data in order to provide more comprehensive insights into the performance of the whole plant and its main subcomponents. The plant included four main subsystems, i.e., steam generator (I), above-zero refrigeration system (II), Bactocatch-assisted pasteurization line (III), and UF cheese production line (IV). In addition, this analysis was aimed at quantifying the exergy destroyed in processing a known quantity of the UF cheese using the mass allocation method. The specific exergy destruction of the UF cheese production was determined at 2330.42 kJ/kg. The contributions of the subsystems I, II, III, and IV to the specific exergy destruction of the UF cheese production were computed as 1337.67, 386.18, 283.05, and 323.51 kJ/kg, respectively. Additionally, it was observed through the analysis that the steam generation system had the largest contribution to the thermodynamic inefficiency of the UF cheese production, accounting for 57.40 % of the specific exergy destruction. Generally, the outcomes of this survey further manifested the benefits of applying exergy analysis for design, analysis, and optimization of industrial-scale dairy processing plants to achieve the most cost-effective and environmentally-benign production strategies.

  6. The Clean Coal Technology Program: Lessons learned

    SciTech Connect

    Not Available

    1994-07-01

    The Clean Coal Technology (CCT) Program is a unique partnership between the federal government and industry that has as its primary goal the successful introduction of new clean coal utilization technologies into the energy marketplace. Clean coal technologies being demonstrated under the CCT Program are establishing a technology base that will enable the nation to meet more stringent energy and environmental goals. Most of the, demonstrations are being conducted at commercial scale, in actual user environments, and under circumstances typical of commercial operations. These features allow the potential of the technologies to be evaluated in their intended commercial applications. Each application addresses one of the following four market sectors: advanced electric power generation; environmental control devices; coal processing for clean fuels; and industrial applications. The purpose of this report is fourfold: Explain the CCT program as a model for successful joint government industry partnership for selecting and demonstrating technologies that have promise for adaptation to the energy marketplace; set forth the process by which the process has been implemented and the changes that have been made to improve that process; outline efforts employed to inform potential users and other interested parties about the technologies being developed; and examine some of the questions which must be considered in determining if the CCT Program model can be applied to other programs.

  7. Technological Change and Its Labor Impact in Five Energy Industries. Coal Mining/Oil and Gas Extraction/Petroleum Refining/Petroleum Pipeline Transportation/Electric and Gas Utilities.

    ERIC Educational Resources Information Center

    Bureau of Labor Statistics (DOL), Washington, DC.

    This bulletin appraises major technological changes emerging in five American industries (coal mining, oil and gas extraction, petroleum refining, petroleum pipeline transportation, and electric and gas utilities) and discusses the impact of these changes on productivity and occupations over the next five to ten years. Its separate reports on each…

  8. Mercury speciation and emissions from coal combustion in Guiyang, Southwest China.

    PubMed

    Tang, Shunlin; Feng, Xinbin; Qiu, Jianrong; Yin, Guoxun; Yang, Zaichan

    2007-10-01

    Although China has been regarded as one of the largest anthropogenic mercury emission source with coal combustion, so far the actual measurements of Hg species and Hg emissions from the combustion and the capture of Hg in Chinese emission control devices were very limited. Aiming at Hg mercury species measurements in Guiyang, the capital city of Guizhou province in Southwest China, we studied flue gases of medium-to-small-sized industrial steam coal-firing boiler (10-30 t/h) with no control devices, medium-to-small-sized industrial steam coal-firing boiler with WFGD and large-scale coal combustion with ESPs using Ontario Hytro method. We obtained mercury emission factors of the three representative coal combustion and estimated mercury emissions in Guiyang in 2003, as well as the whole province from 1986 to 2002. Coal combustion in Guiyang emitted 1898 kg mercury to the atmosphere, of which 36% Hg is released from power plants, 41% from industrial coal combustion, and 23% from domestic users, and 267 kg is Hg(p), 813 kg is Hg(2+) and 817 kg is Hg0. Mercury emission in Guizhou province increased sharply from 5.8 t in 1986 to 16.4 t in 2002. With the implementation of national economic strategy of China's Western Development, the annual mercury emission from coal combustion in the province is estimated to be about 32 t in 2015.

  9. Mercury speciation and emissions from coal combustion in Guiyang, southwest China

    SciTech Connect

    Tang, S.L.; Feng, X.B.; Qiu, H.R.; Yin, G.X.; Yang, Z.C.

    2007-10-15

    Although China has been regarded as one of the largest anthropogenic mercury emission source with coal combustion, so far the actual measurements of Hg species and Hg emissions from the combustion and the capture of Hg in Chinese emission control devices were very limited. Aiming at Hg mercury species measurements in Guiyang, the capital city of Guizhou province in Southwest China, we studied flue gases of medium-to-small-sized industrial steam coal-firing boiler (10-30 t/h) with no control devices, medium-to-small-sized industrial steam coal-firing boiler with WFGD and large-scale coal combustion with ESPs using Ontario Hytro method. We obtained mercury emission factors of the three representative coal combustion and estimated mercury emissions in Guiyang in 2003, as well as the whole province from 1986 to 2002. Coal combustion in Guiyang emitted 1898 kg mercury to the atmosphere, of which 36% Hg is released from power plants, 41% from industrial coal combustion, and 23% from domestic users, and 267 kg is Hg{sup P}, 813 kg is Hg{sup 2+} and 817 kg is Hg{sup 0}. Mercury emission in Guizhou province increased sharply from 5.8 t in 1986 to 16.4 t in 2002. With the implementation of national economic strategy of China's Western Development, the annual mercury emission from coal combustion in the province is estimated to be about 32 t in 2015.

  10. Tri-State Synfuels Project Commercial Scale Coal Test: Volume 3A. Gasification test at Sasolburg, overview. [Proposed Henderson, Kentucky coal to gasoline plant; Sasolburg test of Illinois Basin coals in Lurgi Mark IV

    SciTech Connect

    Not Available

    1982-06-01

    The SASOL test was conducted in order to confirm the operability of the Lurgi process with Western Kentucky coal and determine the preliminary design basis for the Tri-State Synfuels Project. The test plan was structured to optimize design parameters of both the gasification and associated plants and their component units by: demonstrating the need for additional gasifiers over the 36 estimated in the feasibility study; determining the steam requirement, which was about 6% higher than for the feasibility study; confirming the oxygen requirement estimated for the feasibility study; confirming design and performance of the distributor/stirrer to be satisfactory for Illinois Basin type coal; confirming that moderately swelling and strongly caking Illinois Basin coals can be gasified in a Mark IV gasifier fitted with a distributor/stirrer when using a non-caking coal for start-up; determining coal handling and preparation should provide a proper size and minimize fines generation and reject rock material to provide a constant specific gravity coal to gasifier. Confirming that dusty tar injection is feasible up to certain limits and that all the tar injected is gasified; determining that no oil is produced directly from the gasifier; determining that no shift unit is required to adjust the hydrogen-to-carbon monoxide ratio to that required for the input to the Fischer-Tropsch Synthol Units; determining a required increase in frequency of monitoring and quality control measures; and determining that direct use of stripped gas liquor for plant cooling purposes is not practical nor economical due to the excessively high chloride levels.

  11. Safety analysis of the CSTR-1 bench-scale coal liquefaction unit

    SciTech Connect

    Hulburt, D.A.

    1981-05-01

    The objective of the program reported herein was to provide a Safety Analysis of the CSTR-1 bench scale unit located in Building 167 at the Pittsburgh Energy Technology Center. It was apparent that considerable effort was expended in the design and construction of the unit, and in the development of operating procedures, with regard to safety. Exhaust ventilation, H/sub 2/ and H/sub 2/S monitoring, overpressure protection, overtemperature protection, and interlock systems have been provided. Present settings on the pressure and temperature safety systems are too high, however, to insure prevention of vessel deformation or damage in all cases. While the occurrence of catastrophic rupture of a system pressure vessel (e.g., reactor, high pressure separators) is unlikely, the potential consequences to personnel are severe. Feasibility of providing shielding for these components should be considered. A more probable mode of vessel failure in the event of overpressure or overtemperature and failure of the safety system is yielding of the closure bolts followed by high pressure flow across the mating surfaces. As a minimum, shielding should be designed to restrict travel of resultant spray. The requirements for personal protective equipment are presently stated in rather broad and general terms in the operating procedures. Safe practices and procedures would be more assured if specific requirements were stated and included for each operational step. Recommendations were developed for all hazards triggered by the guidelines.

  12. Hydrometallurgical recovery of germanium from coal gasification fly ash: pilot plant scale evaluation

    SciTech Connect

    Arroyo, F.; Fernandez-Pereira, C.; Olivares, J.; Coca, P.

    2009-04-15

    In this article, a hydrometallurgical method for the selective recovery of germanium from fly ash (FA) has been tested at pilot plant scale. The pilot plant flowsheet comprised a first stage of water leaching of FA, and a subsequent selective recovery of the germanium from the leachate by solvent extraction method. The solvent extraction method was based on Ge complexation with catechol in an aqueous solution followed by the extraction of the Ge-catechol complex (Ge(C{sub 6}H{sub 4}O{sub 2}){sub 3}{sup 2-}) with an extracting organic reagent (trioctylamine) diluted in an organic solvent (kerosene), followed by the subsequent stripping of the organic extract. The process has been tested on a FA generated in an integrated gasification with combined cycle (IGCC) process. The paper describes the designed 5 kg/h pilot plant and the tests performed on it. Under the operational conditions tested, approximately 50% of germanium could be recovered from FA after a water extraction at room temperature. Regarding the solvent extraction method, the best operational conditions for obtaining a concentrated germanium-bearing solution practically free of impurities were as follows: extraction time equal to 20 min; aqueous phase/organic phase volumetric ratio equal to 5; stripping with 1 M NaOH, stripping time equal to 30 min, and stripping phase/organic phase volumetric ratio equal to 5. 95% of germanium were recovered from water leachates using those conditions.

  13. Bench-scale demonstration of biological production of ethanol from coal synthesis gas

    SciTech Connect

    Not Available

    1992-01-01

    Culture isolation and selection studies are being performed in order to select the best biological system for bench-scale studies in producing ethanol from syngas components. Three isolates have been found which produce more than 2 g/L ethanol from CO and C0[sub 2]/H[sub 2] in batch culture. These low concentrations are actually quite promising since Clostridium ljungdahlii, strain PETC, performs well in continuous culture but produces only small concentrations of ethanol in batch culture after several weeks of incubation. Two of the isolates have been utilized in the CSTR, where 90 percent CO conversions have been noted, while producing up to 2 g/L ethanol, in preliminary studies. CSTR studies will continue until steady state is reached. An anaerobic bacterium has been isolated from natural sources that converts the components of synthesis gas (CO, H[sub 2],C0[sub 2]) into ethanol. This organism, the only one known at that time to produce ethanol from synthesis gas, has been identified as a new clostridial strain and has been named Clostridium ljungdahlii, strain PETC.

  14. Bench-Scale and Pilot-Scale Treatment Technologies for the Removal of Total Dissolved Solids from Coal Mine Water: A Review

    EPA Science Inventory

    Coal mine water (CMW) is typically treated to remove suspended solids, acidity, and soluble metals, but high concentrations of total dissolved solids (TDS) have been reported to impact the environment at several CMW discharge points. Consequently, various states have establishe...

  15. Comparison of lab, pilot, and industrial scale low consistency mechanical refining for improvements in enzymatic digestibility of pretreated hardwood.

    PubMed

    Jones, Brandon W; Venditti, Richard; Park, Sunkyu; Jameel, Hasan

    2014-09-01

    Mechanical refining has been shown to improve biomass enzymatic digestibility. In this study industrial high-yield sodium carbonate hardwood pulp was subjected to lab, pilot and industrial refining to determine if the mechanical refining improves the enzymatic hydrolysis sugar conversion efficiency differently at different refining scales. Lab, pilot and industrial refining increased the biomass digestibility for lignocellulosic biomass relative to the unrefined material. The sugar conversion was increased from 36% to 65% at 5 FPU/g of biomass with industrial refining at 67.0 kWh/t, which was more energy efficient than lab and pilot scale refining. There is a maximum in the sugar conversion with respect to the amount of refining energy. Water retention value is a good predictor of improvements in sugar conversion for a given fiber source and composition. Improvements in biomass digestibility with refining due to lab, pilot plant and industrial refining were similar with respect to water retention value.

  16. Vertical profile, source apportionment, and toxicity of PAHs in sediment cores of a wharf near the coal-based steel refining industrial zone in Kaohsiung, Taiwan.

    PubMed

    Chen, Chih-Feng; Chen, Chiu-Wen; Ju, Yun-Ru; Dong, Cheng-Di

    2016-03-01

    Three sediment cores were collected from a wharf near a coal-based steel refining industrial zone in Kaohsiung, Taiwan. Analyses for 16 polycyclic aromatic hydrocarbons (PAHs) of the US Environmental Protection Agency priority list in the core sediment samples were conducted using gas chromatography-mass spectrometry. The vertical profiles of PAHs in the core sediments were assessed, possible sources and apportionment were identified, and the toxicity risk of the core sediments was determined. The results from the sediment analyses showed that total concentrations of the 16 PAHs varied from 11774 ± 4244 to 16755 ± 4593 ng/g dry weight (dw). Generally, the vertical profiles of the PAHs in the sediment cores exhibited a decreasing trend from the top to the lower levels of the S1 core and an increasing trend of PAHs from the top to the lower levels of the S2 and S3 cores. Among the core sediment samples, the five- and six-ring PAHs were predominantly in the S1 core, ranging from 42 to 54 %, whereas the composition of the PAHs in the S2 and S3 cores were distributed equally across three groups: two- and three-ring, four-ring, and five- and six-ring PAHs. The results indicated that PAH contamination at the site of the S1 core had a different source. The molecular indices and principal component analyses with multivariate linear regression were used to determine the source contributions, with the results showing that the contributions of coal, oil-related, and vehicle sources were 38.6, 35.9, and 25.5 %, respectively. A PAH toxicity assessment using the mean effect range-median quotient (m-ERM-q, 0.59-0.79), benzo[a]pyrene toxicity equivalent (TEQ(carc), 1466-1954 ng TEQ/g dw), and dioxin toxicity equivalent (TEQ(fish), 3036-4174 pg TEQ/g dw) identified the wharf as the most affected area. The results can be used for regular monitoring, and future pollution prevention and management should target the coal-based industries in this region for pollution reduction.

  17. Create a Consortium and Develop Premium Carbon Products from Coal

    SciTech Connect

    Frank Rusinko; John Andresen; Jennifer E. Hill; Harold H. Schobert; Bruce G. Miller

    2006-01-01

    The objective of these projects was to investigate alternative technologies for non-fuel uses of coal. Special emphasis was placed on developing premium carbon products from coal-derived feedstocks. A total of 14 projects, which are the 2003 Research Projects, are reported herein. These projects were categorized into three overall objectives. They are: (1) To explore new applications for the use of anthracite in order to improve its marketability; (2) To effectively minimize environmental damage caused by mercury emissions, CO{sub 2} emissions, and coal impounds; and (3) To continue to increase our understanding of coal properties and establish coal usage in non-fuel industries. Research was completed in laboratories throughout the United States. Most research was performed on a bench-scale level with the intent of scaling up if preliminary tests proved successful. These projects resulted in many potential applications for coal-derived feedstocks. These include: (1) Use of anthracite as a sorbent to capture CO{sub 2} emissions; (2) Use of anthracite-based carbon as a catalyst; (3) Use of processed anthracite in carbon electrodes and carbon black; (4) Use of raw coal refuse for producing activated carbon; (5) Reusable PACs to recycle captured mercury; (6) Use of combustion and gasification chars to capture mercury from coal-fired power plants; (7) Development of a synthetic coal tar enamel; (8) Use of alternative binder pitches in aluminum anodes; (9) Use of Solvent Extracted Carbon Ore (SECO) to fuel a carbon fuel cell; (10) Production of a low cost coal-derived turbostratic carbon powder for structural applications; (11) Production of high-value carbon fibers and foams via the co-processing of a low-cost coal extract pitch with well-dispersed carbon nanotubes; (12) Use of carbon from fly ash as metallurgical carbon; (13) Production of bulk carbon fiber for concrete reinforcement; and (14) Characterizing coal solvent extraction processes. Although some of the

  18. Industrial-scale demonstration of a new sorbent reactivation technology for fluidized bed combustors.

    PubMed

    Anthony, Edward J; McCleave, Robert; Gandolfi, Eduardo; Wang, Jinsheng

    2003-10-01

    To minimize the disposal of highly reactive spent sorbent from a fluidized bed combustor, a new method for reactivation has been developed. The method consists of grinding the spent ash in a rotary mill, hydrating the ash with an excess of water, and mixing the wet ground ash with dry solids to absorb the excess water. The mixing process eliminates the formation of a concrete-like product that normally results as wet fluidized bed combustor ash ages. Pilot-scale combustion trials proved to be successful, and the process was scaled up using a 35MWt utility boiler at Purdue University. The test lasted for 3 days and resulted in net reduction of limestone sorbent use of 18%. The results generated in this work have been used to develop an economic evaluation for a 165MWe circulating fluidized bed (CFB) boiler, which projects significant savings due to reduction of limestone supply and ash disposal costs. The evaluation also suggests that the process is cost competitive with other processes, albeit that those processes have not been demonstrated at industrial scale. Furthermore, it also has the potential to make a small net reduction in CO(2) emissions, due to reduced limestone usage.

  19. The development of coal-based technologies for Department of Defense facilities: Phase 1 final report. Volume 1: Technical report

    SciTech Connect

    Miller, B.G.; Morrison, J.L.; Pisupati, S.V.

    1997-01-31

    The first phase of a three-phase project investigating the development of coal-based technologies for Department of Defense facilities has been completed. The objectives of the project are to: decrease DOD`s dependence on foreign oil and increase its use of coal; promote public and private sector deployment of technologies for utilizing coal-based fuels in oil-designed combustion equipment; and provide a continuing environment for research and development of coal-based fuel technologies for small-scale applications at a time when market conditions in the US are not favorable for the introduction of coal-fired equipment in the commercial and industrial capacity ranges. The Phase 1 activities were focused on developing clean, coal-based combustion technologies for the utilization of both micronized coal-water mixtures (MCWMs) and dry, micronized coal (DMC) in fuel oil-designed industrial boilers. The specific objective in Phase 1 was to deliver fully engineered retrofit options for a fuel oil-designed watertube boiler located on a DOD installation to fire either MCWM or DMC. This was achieved through a project consisting of fundamental, pilot-sale, and demonstration-scale activities investigating coal beneficiation and preparation, and MCWM and DMC combustion performance. In addition, detailed engineering designs and an economic analysis were conducted for a boiler located at the Naval Surface Warfare Center, near Crane, Indiana. Results are reported on MCWM and DMC combustion performance evaluation; engineering design; and cost/economic analysis.

  20. Industry

    SciTech Connect

    Bernstein, Lenny; Roy, Joyashree; Delhotal, K. Casey; Harnisch, Jochen; Matsuhashi, Ryuji; Price, Lynn; Tanaka, Kanako; Worrell, Ernst; Yamba, Francis; Fengqi, Zhou; de la Rue du Can, Stephane; Gielen, Dolf; Joosen, Suzanne; Konar, Manaswita; Matysek, Anna; Miner, Reid; Okazaki, Teruo; Sanders, Johan; Sheinbaum Parado, Claudia

    2007-12-01

    This chapter addresses past, ongoing, and short (to 2010) and medium-term (to 2030) future actions that can be taken to mitigate GHG emissions from the manufacturing and process industries. Globally, and in most countries, CO{sub 2} accounts for more than 90% of CO{sub 2}-eq GHG emissions from the industrial sector (Price et al., 2006; US EPA, 2006b). These CO{sub 2} emissions arise from three sources: (1) the use of fossil fuels for energy, either directly by industry for heat and power generation or indirectly in the generation of purchased electricity and steam; (2) non-energy uses of fossil fuels in chemical processing and metal smelting; and (3) non-fossil fuel sources, for example cement and lime manufacture. Industrial processes also emit other GHGs, e.g.: (1) Nitrous oxide (N{sub 2}O) is emitted as a byproduct of adipic acid, nitric acid and caprolactam production; (2) HFC-23 is emitted as a byproduct of HCFC-22 production, a refrigerant, and also used in fluoroplastics manufacture; (3) Perfluorocarbons (PFCs) are emitted as byproducts of aluminium smelting and in semiconductor manufacture; (4) Sulphur hexafluoride (SF{sub 6}) is emitted in the manufacture, use and, decommissioning of gas insulated electrical switchgear, during the production of flat screen panels and semiconductors, from magnesium die casting and other industrial applications; (5) Methane (CH{sub 4}) is emitted as a byproduct of some chemical processes; and (6) CH{sub 4} and N{sub 2}O can be emitted by food industry waste streams. Many GHG emission mitigation options have been developed for the industrial sector. They fall into three categories: operating procedures, sector-wide technologies and process-specific technologies. A sampling of these options is discussed in Sections 7.2-7.4. The short- and medium-term potential for and cost of all classes of options are discussed in Section 7.5, barriers to the application of these options are addressed in Section 7.6 and the implication of

  1. Tri-State Synfuels Project Commercial Scale Coal Test: Volume 2B. Collection and shipment analytical testwork. [Proposed Henderson, Kentucky coal to gasoline plant; West Kentucky No. 9 seam coal characterization and testing

    SciTech Connect

    Not Available

    1982-06-01

    This report covers the detailed analytical testwork conducted for control purposes during the collection and shipment phase as well as the results obtained by Lurgi and other parties on the composite barge sample. These tests were conducted to ensure quality control at every step during the shipment, obtain fines generation data during rehandling and establish a chemical and physical characterization of the coal for testing and design purposes. Lurgi concluded from the laboratory results that the Camp 1 coal is suitable feedstock for the Lurgi pressure gasification process. This confirms their early statements during the selection phase as reported in Volume 1. Lurgi reported that the ash melting characteristics under oxidizing conditions indicated a short ash which means that the steam/oxygen ratio will have to be controlled carefully. The chlorine content is significantly higher than most coals and the gasifier, but not the downstream equipment, must be fited with protective cladding. The Kentucky Department of Energy coal shipment examination report provides a confirmation of the ASTM standard data; in addition, analyses for macerals, microlithotypes, reflectances and anisotropy are given. The crushed, run-of-mine, oversize material which required more operating attention at Sasolburg was investigated as to source and characteristics. Specimens collected at Sasolburg and from the Kentucky stockpile were examined as reported in Section 7.2.

  2. Coal distribution, January--June 1990

    SciTech Connect

    Not Available

    1990-10-17

    The Coal Distribution report provides information on coal production, distribution, and stocks in the United States to a wide audience including Congress, federal and state agencies, the coal industry, and the general public. This issue presents information for January through June 1990. Coal distribution data are shown (in tables 1--34) by coal-producing state of origin, consumer use, method of transportation, and state of destination. 6 figs., 34 tabs.

  3. Zero Emission Coal

    NASA Astrophysics Data System (ADS)

    Ziock, H.; Guthrie, G. D.; Lackner, K. S.; Harrison, D. P.; Johnson, A. A.

    2002-05-01

    Unless the economic development of the majority of the world's population is prohibited, thereby forcing thereby forcing them to remain in poverty, world energy consumption and therefore carbon dioxide greenhouse gas emission rates could easily increase by an order of magnitude during this century. Given that we have already increased global atmospheric concentrations by 30% compared to their pre-industrial age level, without massive intervention, we will completely overwhelm Nature's ability to cope. In order to stabilize atmospheric CO2 levels, while allowing desired world economic development, the future allowable US per capita CO2 emissions are only 3 % of today's value. This is effectively zero, and thus what is required is the development of technologies that aim for emission of zero CO2 as well as other pollutants. If we continue to rely on our lowest cost, readily available, and dominant energy source, this will involve both a separation of the energy from the fossil fuel carbon followed by a permanent disposal of the CO2. To set the scale, today's yearly global emissions are approaching 25 cubic kilometers of CO2 at liquid densities, and these could grow by an order of magnitude by the end of the century. We describe a zero emission coal technology that would be able to deal with both the scope of the problem and the emission goal. The energy production process is a chemical conversion of coal to electricity or hydrogen, which involves no combustion and thus no smoke stack. The process provides a pure stream of CO2 for disposal while simultaneously achieving fuel to electricity conversion efficiencies that are two times better than today's value. This high efficiency by itself extends cuts pollutant production by a factor of two while also extending the lifetime of our fossil fuel reserves by a factor of two to many hundreds of years. By concentrating on coal, we also lay the groundwork for energy security and complete independence for the US, given the

  4. Industrial scale garage-type dry fermentation of municipal solid waste to biogas.

    PubMed

    Qian, M Y; Li, R H; Li, J; Wedwitschka, H; Nelles, M; Stinner, W; Zhou, H J

    2016-10-01

    The objectives of this study was to through monitoring the 1st industrial scale garage-type dry fermentation (GTDF) MSW biogas plant in Bin County, Harbin City, Heilongjiang Province, China, to investigate its anaerobic digestion (AD) performance and the stability of process. After a monitoring period of 180days, the results showed that the volumetric biogas production of the digesters and percolate tank was 0.72 and 2.22m(3) (m(3)d)(-1), respectively, and the specific biogas yield of the feedstock was about 270m(3)CH4tVS(-1), which indicated that the GTDF is appropriate for the Chinese MSW. This paper also raised some problems aimed at improving the process stability and AD efficiency.

  5. Functionality Enhancement of Industrialized Optical Fiber Sensors and System Developed for Full-Scale Pavement Monitoring

    PubMed Central

    Wang, Huaping; Liu, Wanqiu; He, Jianping; Xing, Xiaoying; Cao, Dandan; Gao, Xipeng; Hao, Xiaowei; Cheng, Hongwei; Zhou, Zhi

    2014-01-01

    Pavements always play a predominant role in transportation. Health monitoring of pavements is becoming more and more significant, as frequently suffering from cracks, rutting, and slippage renders them prematurely out of service. Effective and reliable sensing elements are thus in high demand to make prognosis on the mechanical properties and occurrence of damage to pavements. Therefore, in this paper, various types of functionality enhancement of industrialized optical fiber sensors for pavement monitoring are developed, with the corresponding operational principles clarified in theory and the performance double checked by basic experiments. Furthermore, a self-healing optical fiber sensing network system is adopted to accomplish full-scale monitoring of pavements. The application of optical fiber sensors assembly and self-healing network system in pavement has been carried out to validate the feasibility. It has been proved that the research in this article provides a valuable method and meaningful guidance for the integrity monitoring of civil structures, especially pavements. PMID:24854060

  6. Torrefaction of cedarwood in a pilot scale rotary kiln and the influence of industrial flue gas.

    PubMed

    Mei, Yanyang; Liu, Rujie; Yang, Qing; Yang, Haiping; Shao, Jingai; Draper, Christopher; Zhang, Shihong; Chen, Hanping

    2015-02-01

    Torrefaction of cedarwood was performed in a pilot-scale rotary kiln at various temperatures (200, 230, 260 and 290°C). The torrefaction properties, the influence on the grindability and hydroscopicity of the torrefied biomass were investigated in detail as well as the combustion performance. It turned out that, compared with raw biomass, the grindability and the hydrophobicity of the torrefied biomass were significantly improved, and the increasing torrefaction temperature resulted in a decrease in grinding energy consumption and an increase in the proportion of smaller-sized particles. The use of industrial flue gas had a significant influence on the behavior of cedarwood during torrefaction and the properties of the resultant solid products. To optimize the energy density and energy yield, the temperature of torrefaction using flue gas should be controlled within 260°C. Additionally, the combustion of torrefied samples was mainly the combustion of chars, with similar combustion characteristics to lignite.

  7. Drivers and barriers to e-invoicing adoption in Greek large scale manufacturing industries

    SciTech Connect

    Marinagi, Catherine E-mail: ptrivel@yahoo.com Trivellas, Panagiotis E-mail: ptrivel@yahoo.com Reklitis, Panagiotis E-mail: ptrivel@yahoo.com; Skourlas, Christos

    2015-02-09

    This paper attempts to investigate the drivers and barriers that large-scale Greek manufacturing industries experience in adopting electronic invoices (e-invoices), based on three case studies with organizations having international presence in many countries. The study focuses on the drivers that may affect the increase of the adoption and use of e-invoicing, including the customers demand for e-invoices, and sufficient know-how and adoption of e-invoicing in organizations. In addition, the study reveals important barriers that prevent the expansion of e-invoicing, such as suppliers’ reluctance to implement e-invoicing, and IT infrastructures incompatibilities. Other issues examined by this study include the observed benefits from e-invoicing implementation, and the financial priorities of the organizations assumed to be supported by e-invoicing.

  8. Drivers and barriers to e-invoicing adoption in Greek large scale manufacturing industries

    NASA Astrophysics Data System (ADS)

    Marinagi, Catherine; Trivellas, Panagiotis; Reklitis, Panagiotis; Skourlas, Christos

    2015-02-01

    This paper attempts to investigate the drivers and barriers that large-scale Greek manufacturing industries experience in adopting electronic invoices (e-invoices), based on three case studies with organizations having international presence in many countries. The study focuses on the drivers that may affect the increase of the adoption and use of e-invoicing, including the customers demand for e-invoices, and sufficient know-how and adoption of e-invoicing in organizations. In addition, the study reveals important barriers that prevent the expansion of e-invoicing, such as suppliers' reluctance to implement e-invoicing, and IT infrastructures incompatibilities. Other issues examined by this study include the observed benefits from e-invoicing implementation, and the financial priorities of the organizations assumed to be supported by e-invoicing.

  9. Clean coal

    SciTech Connect

    Liang-Shih Fan; Fanxing Li

    2006-07-15

    The article describes the physics-based techniques that are helping in clean coal conversion processes. The major challenge is to find a cost- effective way to remove carbon dioxide from the flue gas of power plants. One industrially proven method is to dissolve CO{sub 2} in the solvent monoethanolamine (MEA) at a temperature of 38{sup o}C and then release it from the solvent in another unit when heated to 150{sup o}C. This produces CO{sub 2} ready for sequestration. Research is in progress with alternative solvents that require less energy. Another technique is to use enriched oxygen in place of air in the combustion process which produces CO{sub 2} ready for sequestration. A process that is more attractive from an energy management viewpoint is to gasify coal so that it is partially oxidized, producing a fuel while consuming significantly less oxygen. Several IGCC schemes are in operation which produce syngas for use as a feedstock, in addition to electricity and hydrogen. These schemes are costly as they require an air separation unit. Novel approaches to coal gasification based on 'membrane separation' or chemical looping could reduce the costs significantly while effectively capturing carbon dioxide. 1 ref., 2 figs., 1 photo.

  10. Processes for non-destructive transfer of graphene: widening the bottleneck for industrial scale production.

    PubMed

    Zaretski, Aliaksandr V; Lipomi, Darren J

    2015-06-14

    The exceptional charge-transport, mechanical, and barrier properties of graphene are well known. High-quality films of single-layer graphene produced over large areas, however, are extremely expensive. The high cost of graphene precludes its use in industries-such as transparent electrodes and flexible packaging-that might take full advantage of its properties. This minireview presents several strategies for the transfer of graphene from the substrates used for growth to substrates used for the final application. Each strategy shares the characteristic of being non-destructive: that is, the growth substrate remains reusable for further synthesis of new graphene. These processes have the potential to lower significantly the costs of manufacturing graphene, to increase production yields, and to minimize environmental impact. This article is divided into sections on (i) the synthesis of high-quality single-layer graphene and (ii) its non-destructive transfer to a host substrate. Section (ii) is further divided according to the substrate from which graphene is transferred: single-crystalline wafers or flexible copper foils. We also comment, wherever possible, on defects produced as a result of the transfer, and potential strategies to mitigate these defects. We conclude that several methods for the green synthesis and transfer of graphene have several of the right characteristics to be useful in industrial scale production.

  11. Full-scale Daramend{trademark} bioremediation of industrial soils containing chlorinated phenols and PAHs

    SciTech Connect

    Seech, A.G.; Bucens, P.G.; Bergeron, D.

    1994-12-31

    Daramend{trademark} bioremediation was developed under the sponsorship of, and is owned by, the Government of Canada. Grace Dearborn Inc. has acquired the license for worldwide application of this technology; which has been successfully used at full-scale to remediate soils containing chlorophenols, polynuclear aromatic hydrocarbons (PAHS) and petroleum hydrocarbons. Over the course of four years (1991--1994), soil was treated under a variety of conditions. During ex-situ treatment, the mean total chlorophenol concentration in excavated soil was reduced from 702 mg/kg to less than the criterion established by the Canadian Council of Ministers of the Environment (CCME) for industrial soil (5 mg/kg). In the same soil the total PAH concentration was reduced from 1.442 me/kg to 35 mg/kg. and the concentrations of all PAH isomers were reduced to less than the CCME criteria for industrial soil (i.e. 10 mg/kg for carcinogenic isomers). Standard toxicological tests, including earthworm mortality and seed germination, were performed on soil taken from the treated area and the control area after completion of the bioremediation. The tests indicated that Daramend treatment had reduced or eliminated the soil`s toxicity.

  12. Environmentally conscious coal combustion

    SciTech Connect

    Hickmott, D.D.; Brown, L.F.; Currier, R.P.

    1997-08-01

    This is the final report of a one-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The objective of this project was to evaluate the environmental impacts of home-scale coal combustion on the Navajo Reservation and develop strategies to reduce adverse health effects associated with home-scale coal combustion. Principal accomplishments of this project were: (1) determination of the metal and gaseous emissions of a representative stove on the Navajo Reservation; (2) recognition of cyclic gaseous emissions in combustion in home-scale combustors; (3) `back of the envelope` calculation that home-scale coal combustion may impact Navajo health; and (4) identification that improved coal stoves require the ability to burn diverse feedstocks (coal, wood, biomass). Ultimately the results of Navajo home-scale coal combustion studies will be extended to the Developing World, particularly China, where a significant number (> 150 million) of households continue to heat their homes with low-grade coal.

  13. Volatilization behavior of Cd and Zn based on continuous emission measurement of flue gas from laboratory-scale coal combustion.

    PubMed

    Liu, J; Falcoz, Q; Gauthier, D; Flamant, G; Zheng, C Z

    2010-06-01

    The accumulation of toxic metals generated by coal-fired power stations presents a serious threat to the environment. The volatilization behavior of two representative metals (Cd and Zn), and the influence of temperature were investigated during coal combustion. An inductively coupled plasma atomic emission spectrometric (ICP-AES) method was developed to continuously measure the heavy metal concentrations quantitatively in flue gas under combustion conditions in order to track the metal release process. This continuous heavy metal analysis system was implemented by coupling it to two types of high temperature reactors: a bubbling fluidized bed reactor and a fixed bed reactor with diameter of 0.1 m and 0.08 m respectively. For the two metals considered in this study (Cd and Zn), the experimental setup was successfully used to continuously monitor the metal vaporization process during coal combustion independent of reactor design, and at different temperatures. Cd is more easily vaporized than Zn during coal combustion. Temperature significantly influences the metal vaporization process. In general, the higher the temperature, the higher the metal vaporization, although the vaporization is not proportional to temperature. In addition to the experimental study, a thermodynamic calculation was carried out to simulate the heavy metal speciation during coal combustion process. The theoretical volatilization tendency is consistent with the experiment. The thermodynamic calculation identified the formation of binary oxides retarding heavy metal vaporization.

  14. Review of a Proposed Quarterly Coal Publication

    SciTech Connect

    Not Available

    1981-01-01

    This Review of a Proposed Quartery Coal Publication contains findings and recommendations regarding the content of a new summary Energy Information Administration (EIA) coal and coke publication entitled The Quarterly Coal Review (QCR). It is divided into five sections: results of interviews with selected EIA data users; identification of major functions of the coal and coke industries; analysis of coal and coke data collection activities; evaluation of issues conerning data presentation including recommendations for the content of the proposed QCR; and comparison of the proposed QCR with other EIA publications. Major findings and recommendations are as follows: (1) User interviews indicate a definite need for a compehensive publication that would support analyses and examine economic, supply and demand trends in the coal industry; (2) the organization of the publication should reflect the natural order of activities of the coal and coke industries. Based on an analysis of the industries, these functions are: production, stocks, imports, exports, distribution, and consumption; (3) current EIA coal and coke surveys collect sufficient data to provide a summary of the coal and coke industries on a quarterly basis; (4) coal and coke data should be presented separately. Coke data could be presented as an appendix; (5) three geographic aggregations are recommended in the QCR. These are: US total, coal producing districts, and state; (6) coal consumption data should be consolidated into four major consumer categories: electric utilities, coke plants, other industrial, and residential commercial; (7) several EIA publications could be eliminated by the proposed QCR.

  15. Bench-scale testing of DOE/PETC`s GranuFlow Process for fine coal dewatering and handling. 1: Results using a high-gravity solid-bowl centrifuge

    SciTech Connect

    Wen, W.W.; Killmeyer, R.P.; Lowman, R.H.; Elstrodt, R.

    1995-12-31

    Most advanced fine-coal cleaning processes involve the use of water. Utility companies are concerned not only with the lower Btu content of the resulting wet, cleaned coal, but more importantly with its handleability problems. Solutions to these problems would enhance the utilization of fine-coal cleaning processes in the utility industry. This paper describes testing of the GranuFlow Process, developed and patented by the Pittsburgh Energy Technology Center (PETC) of the US Department of Energy, using a high-gravity solid bowl centrifuge for dewatering and reconstitution of fine-cleaned-coal slurry at 300 lb per hour in PETC`s Coal Preparation Process Research Facility. Fine-cleaned-coal slurry was treated with a bitumen emulsion before dewatering in a high-gravity solid-bowl centrifuge. The treated products appeared to be dry and in a free-flowing granular form, while the untreated products were wet, lumpy, sticky, and difficult to handle. Specifically, test results indicated that the moisture content, handleability, and dust reduction of the dewatered coal product improved as the addition of emulsion increased from 2% to 8%. The improvement in handleability was most visible for the 200 mesh (75 micron) x 0 coal, when compared with 150 mesh (106 micron) x 0, 65 mesh (212 micron) x 0 or 28 mesh (600 micron) x 0 coals. Test results also showed that the moisture content was dramatically reduced (26--37% reduction) for the four different sizes of coals at 6 or 8% emulsion addition. Because of the moisture reduction and the granular form of the product, the freezing problem was also alleviated.

  16. Iron and zinc fortification of corn tortilla made either at the household or at industrial scale.

    PubMed

    Tovar, Luis Raul; Larios-Saldaña, Alfredo

    2005-03-01

    Fe and Zn deficiencies among the Mexican population are widespread, and one-third of children and women of childbearing age are anemic. Since diets that are Fe-deficient are most probably also Zn-deficient, a proprietary process was developed to fortify corn tortilla with these trace elements at the first stage of treatment with lime. Phytic acid (PA), Ca, Fe, and Zn content were determined, as well as the molar ratios of phytate/Fe, phytate/Zn, and Ca x phytate to Zn in traditional and fortified tortillas; the Student's t-test was used to detect differences between the treatments (p < 0.001). Contents of Fe and Zn in the fortified tortilla relative to the traditional tortilla were 1.9 and 3.4 times greater than the latter, whereas PA contents showed the opposite result, i.e. traditional tortillas had 1.65 times more PA than the fortified tortilla. Consequently the calculated molar ratios were statistically more favorable for fortified than for traditional tortillas (p < 0.001). The process developed allows making iron- and zinc-fortified tortillas by lime-treating or nixtamalizing corn either at the household, at small-scale tortilla shops, or at industrial scale by using lime fortified with both trace elements. The cost of this fortification is negligible.

  17. Recovery Act: Oxy-Combustion Technology Development for Industrial-Scale Boiler Applications. Task 4 - Testing in Alstom's 15 MWth Boiler Simulation Facility

    SciTech Connect

    Levasseur, Armand

    2014-04-30

    Alstom Power Inc. (Alstom), under U.S. DOE/NETL Cooperative Agreement No. DE-NT0005290, is conducting a development program to generate detailed technical information needed for application of oxy-combustion technology. The program is designed to provide the necessary information and understanding for the next step of large-scale commercial demonstration of oxy combustion in tangentially fired boilers and to accelerate the commercialization of this technology. The main project objectives include: Design and develop an innovative oxyfuel system for existing tangentially-fired boiler units that minimizes overall capital investment and operating costs; Evaluate performance of oxyfuel tangentially fired boiler systems in pilot scale tests at Alstom’s 15 MWth tangentially fired Boiler Simulation Facility (BSF); Address technical gaps for the design of oxyfuel commercial utility boilers by focused testing and improvement of engineering and simulation tools; Develop the design, performance and costs for a demonstration scale oxyfuel boiler and auxiliary systems; Develop the design and costs for both industrial and utility commercial scale reference oxyfuel boilers and auxiliary systems that are optimized for overall plant performance and cost; and, Define key design considerations and develop general guidelines for application of results to utility and different industrial applications. The project was initiated in October 2008 and the scope extended in 2010 under an ARRA award. The project is scheduled for completion by April 30, 2014. Central to the project is 15 MWth testing in the BSF, which provided in-depth understanding of oxy-combustion under boiler conditions, detailed data for improvement of design tools, and key information for application to commercial scale oxy-fired boiler design. Eight comprehensive 15 MWth oxy-fired test campaigns were performed with different coals, providing detailed data on combustion, emissions, and thermal behavior over a matrix of

  18. Modeling and full-scale tests of vortex plasma-fuel systems for igniting high-ash power plant coal

    NASA Astrophysics Data System (ADS)

    Messerle, V. E.; Ustimenko, A. B.; Karpenko, Yu. E.; Chernetskiy, M. Yu.; Dekterev, A. A.; Filimonov, S. A.

    2015-06-01

    The processes of supplying pulverized-coal fuel into a boiler equipped with plasma-fuel systems and its combustion in the furnace of this boiler are investigated. The results obtained from 3D modeling of conventional coal combustion processes and its firing with plasma-assisted activation of combustion in the furnace space are presented. The plasma-fuel system with air mixture supplied through a scroll is numerically investigated. The dependence of the swirled air mixture flow trajectory in the vortex plasma-fuel system on the scroll rotation angle is revealed, and the optimal rotation angle at which stable plasma-assisted ignition of pulverized coal flame is achieved is determined.

  19. Development of an Ultra-fine Coal Dewatering Technology and an Integrated Flotation-Dewatering System for Coal Preparation Plants

    SciTech Connect

    Wu Zhang; David Yang; Amar Amarnath; Iftikhar Huq; Scott O'Brien; Jim Williams

    2006-12-22

    The project proposal was approved for only the phase I period. The goal for this Phase I project was to develop an industrial model that can perform continuous and efficient dewatering of fine coal slurries of the previous flotation process to fine coal cake of {approx}15% water content from 50-70%. The feasibility of this model should be demonstrated experimentally using a lab scale setup. The Phase I project was originally for one year, from May 2005 to May 2006. With DOE approval, the project was extended to Dec. 2006 without additional cost from DOE to accomplish the work. Water has been used in mining for a number of purposes such as a carrier, washing liquid, dust-catching media, fire-retardation media, temperature-control media, and solvent. When coal is cleaned in wet-processing circuits, waste streams containing water, fine coal, and noncombustible particles (ash-forming minerals) are produced. In many coal preparation plants, the fine waste stream is fed into a series of selection processes where fine coal particles are recovered from the mixture to form diluted coal fine slurries. A dewatering process is then needed to reduce the water content to about 15%-20% so that the product is marketable. However, in the dewatering process currently used in coal preparation plants, coal fines smaller than 45 micrometers are lost, and in many other plants, coal fines up to 100 micrometers are also wasted. These not-recovered coal fines are mixed with water and mineral particles of the similar particle size range and discharged to impoundment. The wasted water from coal preparation plants containing unrecoverable coal fine and mineral particles are called tailings. With time the amount of wastewater accumulates occupying vast land space while it appears as threat to the environment. This project developed a special extruder and demonstrated its application in solid-liquid separation of coal slurry, tailings containing coal fines mostly less than 50 micron. The

  20. A large scale investigation into changes in coal quality caused by dolerite dykes in Secunda, South Africa-implications for the use of proximate analysis on a working mine

    NASA Astrophysics Data System (ADS)

    Bussio, John P.; Roberts, James R.

    2016-05-01

    The coalfields of South Africa contain numerous dolerite intrusions, which affected the quality of the surrounding coal through thermal processes, commonly believed to be controlled by the size of the magmatic body. Data gathered from a working coalfield in Secunda, South Africa, suggest that the relationship between intrusive sills and coal is complex and factors other than intrusion width must be considered in relation to the contact metamorphic effect. The study area contains multiple dolerite intrusions of Karoo age, of which three intrusions occur as sills intruded close to the main coal seam of the. A large database (>8000 boreholes) of coal quality data was used to investigate the presence or absence of a change in coal quality relative to dolerite proximity. Reduction in coal quality was defined using three proximate analysis values, namely the ash, volatile content and dry ash free volatile (DAFV) as defined in the coal industry. The resultant investigation showed no correlation between the position and thickness of the dolerites, and changes in coal quality as measured by proximate analysis. In the absence of a linear relationship between coal quality and dolerite proximity, two processes are proposed to explain the absence of the contact metamorphic effects expected from previous studies. Firstly dolerite emplacement dynamics may influence the size of the metamorphic aureole produced by an intrusion, invalidating intrusion size as a measure of thermal output. Secondly, hydrothermal fluids mobilised by the dolerite intrusions, either from the country rock or the intrusion itself may percolate through the coal and act as the metamorphic agent responsible for changing coal quality, by dissolving the volatile and semi-volatile components of the coal and transporting them to other locations. These two processes are sufficient to explain the lack of a clear "metamorphic effect" related to the dolerite intrusions. However, the perceived lack of a clear

  1. The Full Scale Seal Experiment - A Seal Industrial Prototype for Cigeo - 13106

    SciTech Connect

    Lebon, P.; Bosgiraud, J.M.; Foin, R.; Armand, G.

    2013-07-01

    The Full Scale Seal (FSS) Experiment is one of various experiments implemented by Andra, within the frame of the Cigeo (the French Deep Geological Repository) Project development, to demonstrate the technical construction feasibility and performance of seals to be constructed, at time of Repository components (shafts, ramps, drifts, disposal vaults) progressive closure. FSS is built inside a drift model fabricated on surface for the purpose. Prior to the scale 1:1 seal construction test, various design tasks are scheduled. They include the engineering work on the drift model to make it fit with the experimental needs, on the various work sequences anticipated for the swelling clay core emplacement and the concrete containment plugs construction, on the specialized handling tools (and installation equipment) manufactured and delivered for the purpose, and of course on the various swelling clay materials and low pH (below 11) concrete formulations developed for the application. The engineering of the 'seal-as-built' commissioning means (tools and methodology) must also be dealt with. The FSS construction experiment is a technological demonstrator, thus it is not focused on the phenomenological survey (and by consequence, on the performance and behaviour forecast). As such, no hydration (forced or natural) is planned. However, the FSS implementation (in particular via the construction and commissioning activities carried out) is a key milestone in view of comforting phenomenological extrapolation in time and scale. The FSS experiment also allows for qualifying the commissioning methods of a real sealing system in the Repository, as built, at time of industrial operations. (authors)

  2. Coal-fueled diesels for modular power generation

    NASA Astrophysics Data System (ADS)

    Wilson, R. P.; Rao, A. K.; Smith, W. C.

    1993-11-01

    Interest in coal-fueled heat engines revived after the sharp increase in the prices of natural gas and petroleum in the 1970's. Based on the success of micronized coal water slurry combustion tests in an engine in the 1980's, Morgantown Energy Technology Center (METC) of the US Department of Energy initiated several programs for the development of advanced coal-fueled diesel and gas turbine engines for use in cogeneration, small utilities, industrial applications and transportation. Cooper-Bessemer and Arthur D. Little have been developing technology since 1985, under the sponsor of METC, to enable coal water slurry (CWS) to be utilized in large bore, medium-speed diesel engines. Modular power generation applications in the 10-100 MW size (each plant typically using from two to eight engines) are the target applications for the late 1990's and beyond when, according to the US DOE and other projections, oil and natural gas prices are expected to escalate much more rapidly compared to the price of coal. As part of this program over 7.50 hours of prototype engine operation has been achieved on coal water slurry (CWS), including over 100 hours operation of a six-cylinder full scale engine with Integrated Emissions Control System in 1993. In this paper, the authors described the project cost of the CWS fuel used, the heat rate of the engine operating on CWS, the projected maintenance cost for various engine components, and the demonstrated low emissions characteristics of the coal diesel system.

  3. Coal-fueled diesels for modular power generation

    SciTech Connect

    Wilson, R.P.; Rao, A.K.; Smith, W.C.

    1993-11-01

    Interest in coal-fueled heat engines revived after the sharp increase in the prices of natural gas and petroleum in the 1970`s. Based on the success of micronized coal water slurry combustion tests in an engine in the 1980`s, Morgantown Energy Technology Center (METC) of the US Department of Energy. initiated several programs for the development of advanced coal-fueled diesel and gas turbine engines for use in cogeneration, small utilities, industrial applications and transportation. Cooper-Bessemer and Arthur D. Little have been developing technology since 1985, under the sponsor of METC, to enable coal water slurry (CWS) to be utilized in large bore, medium-speed diesel engines. Modular power generation applications in the 10--100 MW size (each plant typically using from two to eight engines) are the target applications for the late 1990`s and beyond when, according to the US DOE and other projections, oil and natural gas prices are expected to escalate much more rapidly compared to the price of coal. As part of this program over 7.50 hours of prototype engine operation has been achieved on coal water slurry (CWS), including over 100 hours operation of a six-cylinder full scale engine with Integrated Emissions Control System in 1993. In this paper, the authors described the project cost of the CWS fuel used, the heat rate of the engine operating on CWS, the projected maintenance cost for various engine components, and the demonstrated low emissions characteristics of the coal diesel system.

  4. Environmental studies of materials from the H-coal liquefaction process development unit

    SciTech Connect

    Cada, G.F.

    1982-12-01

    H-coal is a process for the direct liquefaction of coal to produce synthetic fuels. Its development has progressed from bench-scale testing through operation of a 2.7 Mg/d (3 ton/d) Process Development Unit. A large-scale H-Coal pilot plant is presently operating at Catlettsburg, Kentucky, and there are plans for the construction of a commercial H-Coal liquefaction facility by the end of the decade. Two of the environmental concerns of the developing direct coal liquefaction industry are accidental spills of synthetic oils and treatment/storage of solid wastes. As a means of obtaining preliminary information on the severity of these potential impacts well in advance of commercialization, samples of product oils and solid wastes were obtained from the H-Coal Process Development Unit (PDU). These samples were subjected to a battery of rapid screening tests, including chemical characterization and bioassays with a variety of aquatic and terrestrial organisms. Water-soluble fraction (WSFs) of H-Coal PDU oils had considerably higher concentrations of phenols and anilines and were commonly one to two orders of magnitude more toxic to aquatic organisms than WSFs of analogous petroleum crude oil. Whole H-Coal PDU oils were also more toxic to the cricket than petroleum-based oils, and some H-Coal samples showed evidence of teratogenicity. Leachates from H-Coal PDU solid wastes, on the other hand, had relatively low concentrations of selected elements and had essentially no acute toxicity to a variety of aquatic and terrestrial species. These studies indicate that environmental effects of product oil spills from a commercial H-Coal liquefaction plant are likely to be more severe than those of conventional petroleum spills. Product upgrading or special transportation and storage techniques may be needed to ensure environmentally sound commercialization of the H-Coal process.

  5. Development and testing of a commercial-scale coal-fired combustion system: Phase 2, Quarterly technical progress report No. 7, April 1, 1992--June 20, 1992

    SciTech Connect

    Litka, A.F.; Breault, R.W.

    1992-08-01

    The objective of this program is to demonstrate the technical and economic viability of a coal-fired combustion system for the commercial sector. The commercial-scale coal-water slurry (CWS) fired space heating system will be a scale-up of a CWS-fired residential warm-air heating system developed by Tecogen Inc. under contract to the Department of Energy (DOE), Pittsburgh Energy Technology Center. This system included a patented nonslagging combustor known as IRIS, for Inertial Reactor with Internal Separation. This combustion technology, which has demonstrated high combustion efficiency using CWS fuels at input rates of 100,000 Btu/hr. will be scaled to operate at 2 to 5 million Btu/hr. Along with the necessary fuel storage and delivery, heat recovery, and control equipment, the system will include pollution control devices to meet targeted values of NO{sub x}, SO{sub 2}, and particulate emissions. In general, the system will be designed to match the reliability, safety, turndown, and ignition performance of gas or oil-fired systems. This report documents the work carried out in the seventh quarter of the program. During this period, proof-of-concept tests aimed at eliminating ash accumulation in the combustor and boiler were conducted. A compressed air soot blower system was installed on the boiler and combustor design changes implemented to reduced direct impingement of slurry on the upper chamber partition. As part of this testing, emission performance goals using Kentucky Hazard Prince Mine coal water slurry were met. Also, during this period the automatic control system for the system was installed and operation with this system was implemented.

  6. Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems

    SciTech Connect

    Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan

    2009-09-15

    A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

  7. [An investigation of the formation of] polycyclic aromatic hydrocarbon (PAH) emissions when firing pulverized coal in a bench-scale drop tube reactor

    SciTech Connect

    Pisupati, S.V.; Wasco, R.S.; Scaroni, A.W.

    1998-12-31

    The Clean Air Act Amendments (CAAA) of 1990 contain provisions which will set standards for the allowable emissions of 188 analytes designated as hazardous air pollutants (HAPs). This list of HAPs was used to establish an initial list of source categories for which EPA would be required to establish technology-based emission standards, which would result in regulated sources sharply reducing routine emissions of toxic air pollutants. Polycyclic organic matter (POM) has also been referred to as polynuclear or polycyclic aromatic compounds (PACs). Nine major categories of POM have been defined by EPA. The study of organic compounds from coal combustion is complex and the results obtained so far are inconclusive with respect to emission factors. The most common organic compounds in the flue gas of coal-fired power plants are polycyclic aromatic hydrocarbons (PAHs). Furthermore, EPA has specified 16 PAH compounds as priority pollutants. These are naphthalene, acenaphthylene, acenaphthene, fluorene, phenanthrene, anthracene, fluoranthene, pyrene, chrysene, benz[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, benzo[a]pyrene, indeno[1,2,3-cd]pyrene, benzo[ghi]perylene, and dibenz[ah]anthracene. Penn State`s Combustion Laboratory is equipped to collect and analyze the HAPs in the flue gas from fossil fuels combustion. The overall objective of this study was to examine the effect of unit temperature on PAH emissions. A Modified Method 5 sampling train was used to isokinetically collect samples at desired locations in flue gas streams. The collected sample can be separated into solid, condensed liquid and gaseous phases. The PAHs of interest are extracted from the collected sample, concentrated, then separated and quantified by gas chromatography/mass spectrometry (GC/MS). This study was conducted using a bench-scale drop-tube reactor (DTR). The fuel selected for this study was a Middle Kittanning seam coal pulverized to 80% passing US Standard 200 mesh (commonly

  8. Development and testing of a commercial-scale coal-fired combustion system, Phase 3. Quarterly technical progress report No. 3, April 1, 1991--June 30, 1991

    SciTech Connect

    Litka, A.F.; Breault, R.W.

    1991-10-01

    Within the commercial sector, oil and natural gas are the predominant fuels used to meet the space-heating needs of schools, office buildings, apartment complexes, and other similar structures. In general, these buildings require firing rates of 1 to 10 million Btu/hr. The objective of this program is to demonstrate the technical and economic viability of a coal-fired combustion system for this sector. The commercial-scale coal-water slurry (CWS)-fired space heating system will be a scale-up of a CWS-fired residential warm-air heating system developed by Tecogen under contract to the Department of Energy, Pittsburgh Energy Technology Center. This system included a patented nonslagging combustor known as IRIS, for Inertial Reactor with Internal Separation. This combustion technology, which has demonstrated high combustion efficiency using CWS fuels at input rates of 100,000 Btu/hr, will be scaled to operate at 2 to 5 millon Btu/hr. Along with the necessary fuel storage and delivery, heat recovery, and control equipment, the system will include pollution control devices to meet targeted values of NO{sub x}, S0{sub 2}, and particulate emissions. In general, the system will be designed to match the reliability, safety, turndown, and ignition performance of gas or oil-fired systems.

  9. Development and testing of a commercial-scale coal-fired combustion system, Phase 3. Quarterly technical progress report No. 2, January 1, 1991--March 31, 1991

    SciTech Connect

    Litka, A.F.; Breault, R.W.

    1991-07-01

    Within the commercial sector, oil and natural gas are the predominant fuels used to meet the space-heating needs of schools, office buildings, apartment complexes, and other similar structures. In general, these buildings require firing rates of 1 to 10 million Btu/hr. The objective of this program is to demonstrate the technical and economic viability of a coal-fired combustion system for this sector. The commercial-scale coal-water slurry (CWS)-fired space heating system will be a scale-up of a CWS-fired residential warm-air heating system developed by Tecogen under contract to the Department of Energy, Pittsburgh Energy Technology Center. This system included a patented nonslagging combustor known as IRIS, for Inertial Reactor with Internal Separation. This combustion technology, which has demonstrated high combustion efficiency using CWS fuels at input rates of 100,000 Btu/hr, will be scaled to operate at 2 to 5 millon Btu/hr. Along with the necessary fuel storage and delivery, heat recovery, and control equipment, the system will include pollution control devices to meet targeted values of NO{sub x}, S0{sub 2}, and particulate emissions. In general, the system will be designed to match the reliability, safety, turndown, and ignition performance of gas or oil-fired systems.

  10. Bench-scale demonstration of biological production of ethanol from coal synthesis gas. Quarterly report, January 1, 1994--March 31, 1994

    SciTech Connect

    Not Available

    1994-06-01

    This report presents results from the solvent selection, fermentation, and product recovery studies performed thus far in the development of a bench scale unit for the production of ethanol from coal-derived synthesis gas. Several additional solvents have been compared for their ability to extract ethanol from aqueous solutions of ethanol in water and fermentation permeate. The solvent 2,6-dimethyl-4-heptanol still appears to be the solvent of choice. Liquid-liquid equilibrium data have been collected for ethanol and 2,6-dimethyl-4-heptanol.

  11. Impact of the addition of chicken litter on mercury speciation and emissions from coal combustion in a laboratory-scale fluidized bed combustor

    SciTech Connect

    Songgeng Li; Shuang Deng; Andy Wu; Wei-ping Pan

    2008-07-15

    Co-combustion of chicken litter with coal was performed in a laboratory-scale fluidized bed combustor to investigate the effect of chicken litter addition on the partitioning behavior of mercury. Gaseous total and elemental mercury concentrations in the flue gas were measured online, and ash was analyzed for particle-bound mercury along with other elemental and surface properties. The mercury mass balance was between 85 and 105%. The experimental results show that co-combustion of chicken litter decreases the amount of elemental and total mercury in the gas phase. Mercury content in fly ash increases with an increasing chicken litter share. 22 refs., 6 figs., 5 tabs.

  12. Application of ERTS-A imagery to fracture related mine safety hazards in the coal mining industry

    NASA Technical Reports Server (NTRS)

    Wier, C. E.; Wobber, F. J. (Principal Investigator)

    1973-01-01

    The author has identified the following significant results. The most important result to date is the demonstration of the special value of repetitive ERTS-1 multiband coverage for detecting previously unknown fracture lineaments despite the presence of a deep glacial overburden. The Illinois Basin is largely covered with glacial drift and few rock outcrops are present. A contribution to the geological understanding of Illinois and Indiana has been made. Analysis of ERTS-1 imagery has provided useful information to the State of Indiana concerning the surface mined lands. The contrast between healthy vegetation and bare ground as imaged by Band 7 is sharp and substantial detail can be obtained concerning the extent of disturbed lands, associated water bodies, large haul roads, and extent of mined lands revegetation. Preliminary results of analysis suggest a reasonable correlation between image-detected fractures and mine roof fall accidents for a few areas investigated. ERTS-1 applications to surface mining operations appear probable, but further investigations are required. The likelihood of applying ERTS-1 derived fracture data to improve coal mine safety in the entire Illinois Basin is suggested from studies conducted in Indiana.

  13. Co-firing of oil sludge with coal-water slurry in an industrial internal circulating fluidized bed boiler.

    PubMed

    Liu, Jianguo; Jiang, Xiumin; Zhou, Lingsheng; Wang, Hui; Han, Xiangxin

    2009-08-15

    Incineration has been proven to be an alternative for disposal of sludge with its unique characteristics to minimize the volume and recover energy. In this paper, a new fluidized bed (FB) incineration system for treating oil sludge is presented. Co-firing of oil sludge with coal-water slurry (CWS) was investigated in the new incineration system to study combustion characteristics, gaseous pollutant emissions and ash management. The study results show the co-firing of oil sludge with CWS in FB has good operating characteristic. CWS as an auxiliary fuel can flexibly control the dense bed temperatures by adjusting its feeding rate. All emissions met the local environmental requirements. The CO emission was less than 1 ppm or essentially zero; the emissions of SO(2) and NO(x) were 120-220 and 120-160 mg/Nm(3), respectively. The heavy metal analyses of the bottom ash and the fly ash by ICP/AES show that the combustion ashes could be recycled as soil for farming.

  14. Early Implementation of Large Scale Carbon Dioxide Removal Projects through the Cement Industry

    NASA Astrophysics Data System (ADS)

    Zeman, F. S.

    2014-12-01

    The development of large-scale carbon dioxide reduction projects requires high purity CO2and a reactive cation source. A project seeking to provide both of these requirements will likely face cost barriers with current carbon prices. The cement industry is a suitable early implementation site for such projects by virtue of the properties of its exhaust gases and those of waste concrete. Cement plants are the second largest source of industrial CO2 emissions, globally. It is also the second largest commodity after water, has no ready substitute and is literally the foundation of society. Finally, half of the CO2 emissions originate from process reactions rather than fossil fuel combustion resulting in higher flue gas CO2concentrations. These properties, with the co-benefits of oxygen combustion, create a favorable environment for spatially suitable projects. Oxygen combustion involves substituting produced oxygen for air in a combustion reaction. The absence of gaseous N2 necessitates the recirculation of exhaust gases to maintain kiln temperatures, which increase the CO2 concentrations from 28% to 80% or more. Gas exit temperatures are also elevated (>300oC) and can reach higher temperatures if the multi stage pre-heater towers, that recover heat, are re-designed in light of FGR. A ready source of cations can be found in waste concrete, a by-product of construction and demolition activities. These wastes can be processed to remove cations and then reacted with atmospheric CO2 to produce carbonate minerals. While not carbon negative, they represent a demonstration opportunity for binding atmospheric CO2while producing a saleable product (precipitated calcium carbonate). This paper will present experimental results on PCC production from waste concrete along with modeling results for oxygen combustion at cement facilities. The results will be presented with a view to mineral sequestration process design and implementation.

  15. Macrophyte growth in a pilot-scale constructed wetland for industrial wastewater treatment.

    PubMed

    Hadad, H R; Maine, M A; Bonetto, C A

    2006-06-01

    A pilot-scale wetland was constructed to assess the feasibility of treating the wastewater from a tool industry in Santo Tomé, Santa Fe, Argentina. The wastewater had high conductivity and pH, and contained Cr, Ni and Zn. This paper describes the growth of vegetation in the experimental wetland and the nutrient and metal removal. The wetland was 6 x 3 x 0.4 m. Water discharge was 1000 l d(-1) and residence time was 7d. After the wetland was rendered impermeable, macrophytes from Middle Paraná River floodplain were transplanted. Influent and effluent quality was analyzed every 15 d. TP, Cr, Ni and Zn concentrations in leaves, roots and sediment (inlet and outlet) were measured monthly. Cover and biomass of predominant species were estimated. Also, greenhouse experiments were carried out to measure the effects of conductivity and pH on floating species. The variables measured in the influent were significantly higher than those in the effluent, except for HCO(3)(-) and NH(4)(+). TP and metal concentrations in sediment at the inlet were significantly higher than those at the outlet. Conductivity and pH of the incoming wastewater were toxic for the floating species. Typha domingensis displaced the other species and reached positive relative cover rate and biomass greater than those at the undisturbed natural environment. T. domingensis proved to be highly efficient for the treatment of wastewater. For that reason, it is the advisable species for the treatment of wastewater of high conductivity and pH enriched with metals, characteristic of many industrial processes.

  16. Effect of processing techniques at industrial scale on orange juice antioxidant and beneficial health compounds.

    PubMed

    Gil-Izquierdo, Angel; Gil, Maria I; Ferreres, Federico

    2002-08-28

    Phenolic compounds, vitamin C (L-ascorbic acid and L-dehydroascorbic acid), and antioxidant capacity were evaluated in orange juices manufactured by different techniques. Five processes at industrial scale (squeezing, mild pasteurization, standard pasteurization, concentration, and freezing) used in commercial orange juice manufacturing were studied. In addition, domestic squeezing (a hand processing technique) was compared with commercial squeezing (an industrial FMC single-strength extraction) to evaluate their influences on health components of orange juice. Whole orange juice was divided into soluble and cloud fractions after centrifugation. Total and individual phenolics were analyzed in both fractions by HPLC. Commercial squeezing extracted 22% more phenolics than hand squeezing. The freezing process caused a dramatic decrease in phenolics, whereas the concentration process caused a mild precipitation of these compounds to the juice cloud. In pulp, pasteurization led to degradation of several phenolic compounds, that is, caffeic acid derivatives, vicenin 2 (apigenin 6,8-di-C-glucoside), and narirutin (5,7,4'-trihydroxyflavanone-7-rutinoside) with losses of 34.5, 30.7, and 28%, respectively. Regarding vitamin C, orange juice produced by commercial squeezing contained 25% more of this compound than domestic squeezing. Mild and standard pasteurization slightly increased the total vitamin C content as the contribution from the orange solids parts, whereas concentration and freezing did not show significant changes. The content of L-ascorbic acid provided 77-96% of the total antioxidant capacity of orange juice. Mild pasteurization, standard pasteurization, concentration, and freezing did not affect the total antioxidant capacity of juice, but they did, however, in pulp, where it was reduced by 47%.

  17. Occupational risk factors for prostate cancer in an area of former coal, iron, and steel industries in Germany. Part 1: Results from a study performed in the 1980s.

    PubMed

    Dickhut, Silvia; Urfer, Wolfgang; Reich, Susanne; Bandel, Tiemo; Bremicker, Karl-Dieter; Neugebauer, Wolfgang; Sökeland, Jürgen; Bolt, Hermann M; Golka, Klaus

    2016-01-01

    Prostate cancer is the most frequent occurring malignancy in men in many Western countries. Unfortunately, only a few studies on occupational risk factors have been published. Thus, the aim of this study was to investigate possible occupational risk factors in a former center of coal, iron, and steel industries the greater Dortmund area, located in the western part of Germany. In three local departments of urology, a total of 238 prostate cancer cases and 414 patients with benign prostatic hyperplasia as controls were requested to provide information for all jobs ever performed for 6 mo or longer. Jobs performed less than 10 yr prior to diagnosis were excluded from the analysis due to the latency of prostate cancer. In addition, data on smoking habits and age were obtained. Analysis of data was performed by means of logistic regression. Hard coal miners and, based on fewer cases, painters, stratified by age, showed a significantly elevated prostate cancer risk. Smoking history did not influence prostate cancer risk. The causes of the observed increased prostate cancer risk in hard coal miners cannot be explained by merely the risk factor "male sexual hormones." In former decades, underground hard coal miners were exposed to high concentrations of dust and different xenobiotics such as hydraulic oils. Surprisingly, in a study performed about a decade later in the same area, prostate cancer risk in underground hard coal miners was found to be reduced. However, exposure to colorants was associated with an increased prostate cancer risk.

  18. Dry sorbent injection of trona to control acid gases from a pilot-scale coal-fired combustion facility

    EPA Science Inventory

    Gaseous and particulate emissions from the combustion of coal have been associated with adverse effects on human and environmental health, and have for that reason been subject to regulation by federal and state governments. Recent regulations by the United States Environmental ...

  19. EMISSION OF ORGANIC HAZARDOUS AIR POLLUTANTS FROM THE COMBUSION OF PULVERIZED COAL IN A SMALL-SCALE COMBUSTOR

    EPA Science Inventory

    The emissions of hazardous air pollutants (HAPs) from the combustion of pulverized coal have become an important issue in light of the requirements of Title I11 of the 1990 Clean Air Act Amendments, which impose emission limits on 189 compounds and compound classes. Although pre...

  20. Development of an advanced high efficiency coal combustor for boiler retrofit

    SciTech Connect

    LaFlesh, R.C.; Rini, M.J.; McGowan, J.G.

    1989-10-01

    The overall objective of this program is to develop a high efficiency advanced coal combustor (HEACC) for coal-based fuels capable of being retrofitted to industrial boilers originally designed for firing natural gas, distillate, and/or residual oil. The HEACC system is to be capable of firing microfine coal water fuel (MCWF), MCWF with alkali sorbent (for SO{sub 2} reduction), and dry microfine coal. Design priorities for the system are that it be simple to operate and will offer significant reductions in NO{sub x}, SO{sub x}, and particulate emissions as compared with current coal fired combustor technology. The specific objective of this report is to document the work carried out under Task 1.0 of this contract, Cold Flow Burner Development''. As are detailed in the report, key elements of this work included primary air swirler development, burner register geometry design, cold flow burner model testing, and development of burner scale up criteria.

  1. Coal trade means shipbuilders' goldmine

    SciTech Connect

    Ridgeway, J.

    1980-03-01

    Nowhere is the advent of a new international trade in coal more important than in the shipping industry. Since the middle of the last decade the world shipping industry has been in the doldrums. As the world switches slowly away from oil, the trade in coal probably will increase dramatically. As it does, the structure of the trade will change. Much of the coal will be shipped by water. During the past decade, US influence declined as the energy crisis changed the nature of the trade away from metallurgical coals to thermal coals. Shipping experts predict the dry bulk carriers that are used for coal, grain, and iron ore (a commodity whose trade is expected to increase) will replace the oil tankers as the most-important class of ships on the high seas by the year 2000.

  2. LIBS Analysis for Coal

    NASA Astrophysics Data System (ADS)

    E. Romero, Carlos; De Saro, Robert

    Coal is a non-uniform material with large inherent variability in composition, and other important properties, such as calorific value and ash fusion temperature. This quality variability is very important when coal is used as fuel in steam generators, since it affects boiler operation and control, maintenance and availability, and the extent and treatment of environmental pollution associated with coal combustion. On-line/in situ monitoring of coal before is fed into a boiler is a necessity. A very few analytical techniques like X-ray fluorescence and prompt gamma neutron activation analysis are available commercially with enough speed and sophistication of data collection for continuous coal monitoring. However, there is still a need for a better on-line/in situ technique that has higher selectivity, sensitivity, accuracy and precision, and that is safer and has a lower installation and operating costs than the other options. Laser induced breakdown spectroscopy (LIBS) is ideal for coal monitoring in boiler applications as it need no sample preparation, it is accurate and precise it is fast, and it can detect all of the elements of concern to the coal-fired boiler industry. LIBS data can also be adapted with advanced data processing techniques to provide real-time information required by boiler operators nowadays. This chapter summarizes development of LIBS for on-line/in situ coal applications in utility boilers.

  3. Coals of the Brazil Formation (Pennsylvanian) in Indiana: Observations of correlation inconsistencies and their implications

    USGS Publications Warehouse

    Mastalerz, Maria; Ames, P.R.; Padgett, P.L.

    2003-01-01

    The coals of the upper part of the Mansfield, Brazil, and the lower part of the Staunton Formations (Atokan and Desmoinesian, Pennsylvanian) in Indiana (Illinois Basin) are characteristically thin and discontinuous. As a result, problems with correlation and identification of the seams have persisted for both researchers and industry. These discrepancies affect coal exploration, mine planning, and subsequently coal-fired utilities. This study presents exploration and operational examples demonstrating some of the correlation problems associated with the coals of the Brazil Formation, and the Upper Block and Lower Block, in particular, and the surrounding upper part of the Mansfield Formation and lower part of the Staunton Formations. Based on exploration boreholes, mine scale observations, and coal quality and petrographic data, this study suggests that (1) the coal mapped as the Upper Block Coal Member of Clay County may, in fact, be the same seam as the Lower Block Coal Member of Daviess County; and (2) the Lower Block coal of Clay County is not present south of the Switz City area of central Greene County, IN. ?? 2003 Elsevier Science B.V. All rights reserved.

  4. Bioelements and mineral matter in human livers from the highly industrialized region of the Upper Silesia Coal Basin (Poland).

    PubMed

    Lewińska-Preis, Lucyna; Jabłońska, Mariola; Fabiańska, Monika J; Kita, Andrzej

    2011-12-01

    Contents of mineral substance, silica, and a range of bioelements and toxic elements (Mg, Na, K, Ca, Ba, Zn, Cr, P Al, Cd, Mn Cu, Ni, Pb, Sr, Fe) in 38 livers of donors from the Upper Silesia Coal Basin (southern Poland) are presented. Elements were determined by inductively coupled plasma-atomic emission spectrometry (ICP-AES) with the exception of silica that was estimated colorimetrically. Concentrations, concentration variability, and correlations between selected liver components determined for the total population are related to donor age, gender, and lesion occurrence. Correlations between particular elements were found using correlation coefficient values and the Fisher transformation. Mineral substance in the livers lies in the range 0.40-5.03 wt%. With increasing donor age, mineral-matter content decreases to a minimum for the 40-60 years of age range. Microbioelement contents show a similar tendency, while microbioelements and toxic elements reach maximum contents in donors aged 60-80 years. All elements show content decreases in livers from the oldest group (>80 years). Silica contents increase with age. Variability of element contents is lowest in the older subpopulations. Livers with lesions show lower element contents and variability. The results are compared to literature data for regions of Poland assumed to be of low pollution and to data from comparable regions in Japan and Hungary. Up to our knowledge, this paper is the first work describing the total contents, as distinct from contents of selected elements, of mineral substance in human livers.

  5. Design and analysis of small wind turbine blades with wakes similar to those of industrial scale turbines

    NASA Astrophysics Data System (ADS)

    Hassanzadeh, Arash; Naughton, Jonathan

    2016-11-01

    A new design approach has been developed for wind turbine blades to be used in wind tunnel experiments that study wind turbine wakes. The approach allows wakes of small scale (2 m diameter) wind turbine rotors to simulate the important physics of wakes generated by a "parent" industrial scale wind turbine rotor despite the difference in size. The design approach forces the normalized normal and tangential force distributions of the small scale wind turbine blades to match those of the "parent" industrial scale wind turbine blades. The wake arises from the interaction between the flow and the blade, which imparts a momentum deficit and rotation to the flow due to the forces created by the blade on the flow. In addition, the wake dynamics and stability are affected by the load distribution across the blade. Thus, it is expected that matching normalized force distributions should result in similar wake structure. To independently assess the blades designed using this approach, the "parent" industrial scale and small scale wind turbine rotors are modeled using a free vortex wake method to study the generation and evolution of the two wakes. This work was supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, under Award # DE-SC0012671.

  6. Alaska low-rank coal-water fuel -- Diesel demonstration Phase 2: Construction

    SciTech Connect

    Wilson, W.; Benson, C.; Wilson, R.; Krier, G.; Ruckhaus, M.; Walsh, D.; Ward, C.

    1998-07-01

    The technical feasibility of producing and utilizing a premium low-rank coal-water fuel (LRCWF) made from ultra-low sulfur Alaskan subbituminous coal following hydrothermal treatment (HT) has been demonstrated in pilot plants in Australia, Japan and the US. Preliminary process economics suggest that LRCWF produced from subbituminous coal from the Beluga coal field near Anchorage, Alaska, with measured coal reserves approaching 2 billion tons, would be competitive with heavy oil priced above about $18 per barrel in Japan. Consequently, a consortium led by Usibelli Coal Mine, Inc. (UCM), the University of Alaska Fairbanks (UAF) and Coal-Water Fuel Services (CWFS) was formed to seek funding for a commercial-scale demonstration project to be built at UAF. Arthur D. Little, Inc. (ADL), with support from the US Department of Energy (DOE), led a team that demonstrated the feasibility of using CWFs in medium speed diesel engines. They were awarded funding in DOE's fifth and final Clean Coal Technology Program solicitation to demonstrate the technology at commercial scale in a Maryland utility. Due to reduced power demands, the utility withdrew and project developers sought a new location. ADL was familiar with the potential synergism with the proposed Alaskan LRCWF project and have joined with the Alaskan team to formulate the LRCWF-Diesel Demonstration Project to be located at UAF. Coltec Industries, Fairbanks Morse Engine Division, will provide commercial CWF diesel technology.

  7. Advantages of city-scale emission inventory for urban air quality research and policy: the case of Nanjing, a typical industrial city in the Yangtze River Delta, China

    NASA Astrophysics Data System (ADS)

    Zhao, Y.; Qiu, L.; Xu, R.; Xie, F.; Zhang, Q.; Yu, Y.; Nielsen, C. P.; Qin, H.; Wang, H.; Wu, X.; Li, W.; Zhang, J.

    2015-07-01

    With most eastern Chinese cities facing major air quality challenges, there is a strong need for city-scale emission inventories for use in both chemical transport modeling and the development of pollution control policies. In this paper, a high-resolution emission inventory of air pollutants and CO2 for Nanjing, a typical large city in the Yangtze River Delta, is developed incorporating the best available information on local sources. Emission factors and activity data at the unit or facility level are collected and compiled using a thorough onsite survey of major sources. Over 900 individual plants, which account for 97 % of the city's total coal consumption, are identified as point sources, and all of the emission-related parameters including combustion technology, fuel quality, and removal efficiency of air pollution control devices (APCD) are analyzed. New data-collection approaches including continuous emission monitoring systems and real-time monitoring of traffic flows are employed to improve spatiotemporal distribution of emissions. Despite fast growth of energy consumption between 2010 and 2012, relatively small inter-annual changes in emissions are found for most air pollutants during this period, attributed mainly to benefits of growing APCD deployment and the comparatively strong and improving regulatory oversight of the large point sources that dominate the levels and spatial distributions of Nanjing emissions overall. The improvement of this city-level emission inventory is indicated by comparisons with observations and other inventories at larger spatial scale. Relatively good spatial correlations are found for SO2, NOx, and CO between the city-scale emission estimates and concentrations at 9 state-opertated monitoring sites (R = 0.58, 0.46, and 0.61, respectively). The emission ratios of specific pollutants including BC to CO, OC to EC, and CO2 to CO compare well to top-down constraints from ground observations. The inter-annual variability and

  8. Impacts of detrital nano- and micro-scale particles (dNP) on contaminant dynamics in a coal mine AMD treatment system.

    PubMed

    Lefticariu, Liliana; Sutton, Stephen R; Bender, Kelly S; Lefticariu, Mihai; Pentrak, Martin; Stucki, Joseph W

    2017-01-01

    Pollutants in acid mine drainage (AMD) are usually sequestered in neoformed nano- and micro-scale particles (nNP) through precipitation, co-precipitation, and sorption. Subsequent biogeochemical processes may control nNP stability and thus long-term contaminant immobilization. Mineralogical, chemical, and microbiological data collected from sediments accumulated over a six-year period in a coal-mine AMD treatment system were used to identify the pathways of contaminant dynamics. We present evidence that detrital nano- and micron-scale particles (dNP), composed mostly of clay minerals originating from the partial weathering of coal-mine waste, mediated biogeochemical processes that catalyzed AMD contaminant (1) immobilization by facilitating heterogeneous nucleation and growth of nNP in oxic zones, and (2) remobilization by promoting phase transformation and reductive dissolution of nNP in anoxic zones. We found that dNP were relatively stable under acidic conditions and estimated a dNP content of ~0.1g/L in the influent AMD. In the AMD sediments, the initial nNP precipitates were schwertmannite and poorly crystalline goethite, which transformed to well-crystallized goethite, the primary nNP repository. Subsequent reductive dissolution of nNP resulted in the remobilization of up to 98% of S and 95% of Fe accompanied by the formation of a compact dNP layer. Effective treatment of pollutants could be enhanced by better understanding the complex, dynamic role dNP play in mediating biogeochemical processes and contaminant dynamics at coal-mine impacted sites.

  9. Zero Discharge Performance of an Industrial Pilot-Scale Plant Treating Palm Oil Mill Effluent

    PubMed Central

    Mahmood, Qaisar; Qiu, Jiang-Ping; Li, Yin-Sheng; Chang, Yoon-Seong; Chi, Li-Na; Li, Xu-Dong

    2015-01-01

    Palm oil is one of the most important agroindustries in Malaysia. Huge quantities of palm oil mill effluent (POME) pose a great threat to aqueous environment due to its very high COD. To make full use of discharged wastes, the integrated “zero discharge” pilot-scale industrial plant comprising “pretreatment-anaerobic and aerobic process-membrane separation” was continuously operated for 1 year. After pretreatment in the oil separator tank, 55.6% of waste oil in raw POME could be recovered and sold and anaerobically digested through 2 AnaEG reactors followed by a dissolved air flotation (DAF); average COD reduced to about 3587 mg/L, and biogas production was 27.65 times POME injection which was used to generate electricity. The aerobic effluent was settled for 3 h or/and treated in MBR which could remove BOD3 (30°C) to less than 20 mg/L as required by Department of Environment of Malaysia. After filtration by UF and RO membrane, all organic compounds and most of the salts were removed; RO permeate could be reused as the boiler feed water. RO concentrate combined with anaerobic surplus sludge could be used as biofertilizer. PMID:25685798

  10. Characteristics of a multicomponent Nb-Ti-Al alloy via industrial-scale practice

    SciTech Connect

    Sikka, V.K.; Loria, E.A.

    1997-05-01

    Within the spectrum of advanced intermetallic materials, an alloy containing 44Nb-35Ti-6Al-5Cr-8V-1W-0.5Mo-0.3Hf (at. %) was investigated in the industrial-scale produced condition. The alloy was tensile tested in air from room temperature to 1,000 C and in vacuum at 750 and 850 C. Results of this study have shown that the alloy can be commercially produced and has adequate ductility for its secondary processing even at an oxygen level of 1,160 wppm. The alloy has room temperature ductility of 16% and superplastic elongation of 244% at 1,000 C. This alloy shows low intermediate temperature (600--850 C) ductility when tested in air. The vacuum testing revealed that the low ductility is associated within oxygen embrittlement phenomenon. It is expected that such an embrittlement can be taken care of by an oxidation resistant coating. The alloy also possesses superior strength to similar alloys in this class. Results of this investigation suggest a strong potential for consideration of this alloy to exceed the useful temperature range of nickel-base superalloys.

  11. Chlorine inactivation of coliphage MS2 on strawberries by industrial-scale water washing units.

    PubMed

    Casteel, Michael J; Schmidt, Charles E; Sobsey, Mark D

    2009-06-01

    Fruits and vegetables (produce) intended for minimal processing are often rinsed or washed in water. Chlorine and other sanitizers are used during washing to inactivate produce spoilage microbes, but such procedures may also inactivate pathogens epidemiologically linked to produce, such as hepatitis A virus (HAV). However, no information exists on the efficacy of chlorinated wash water to inactivate HAV and other viruses on produce in actual practice, because of obvious safety concerns. In contrast, coliphage MS2 (a bacterial virus) is commonly used as a surrogate for some pathogenic viruses and may be safely used in field studies. In the present investigation, strawberries seeded with MS2 were passed through industrial-scale water washing units operated with or without added sodium hypochlorite. MS2 on strawberries was inactivated by 68%, 92% and 96% at free chlorine (FC) concentrations of < or = 2, 20 and 200 ppm in wash water, respectively. MS2 was detected in wash water containing < or = 2 ppm FC in one trial, but was not detected in water containing 20 or 200 ppm FC. The presence and absence of MS2 in wash water containing various levels of FC highlight the importance of controlling sanitizer levels to prevent viral cross contamination of strawberries.

  12. Economics of recombinant antibody production processes at various scales: Industry-standard compared to continuous precipitation.

    PubMed

    Hammerschmidt, Nikolaus; Tscheliessnig, Anne; Sommer, Ralf; Helk, Bernhard; Jungbauer, Alois

    2014-06-01

    Standard industry processes for recombinant antibody production employ protein A affinity chromatography in combination with other chromatography steps and ultra-/diafiltration. This study compares a generic antibody production process with a recently developed purification process based on a series of selective precipitation steps. The new process makes two of the usual three chromatographic steps obsolete and can be performed in a continuous fashion. Cost of Goods (CoGs) analyses were done for: (i) a generic chromatography-based antibody standard purification; (ii) the continuous precipitation-based purification process coupled to a continuous perfusion production system; and (iii) a hybrid process, coupling the continuous purification process to an upstream batch process. The results of this economic analysis show that the precipitation-based process offers cost reductions at all stages of the life cycle of a therapeutic antibody, (i.e. clinical phase I, II and III, as well as full commercial production). The savings in clinical phase production are largely attributed to the fact that expensive chromatographic resins are omitted. These economic analyses will help to determine the strategies that are best suited for small-scale production in parallel fashion, which is of importance for antibody production in non-privileged countries and for personalized medicine.

  13. A full-scale biological treatment system application in the treated wastewater of pharmaceutical industrial park.

    PubMed

    Lei, Ge; Ren, Hongqiang; Ding, Lili; Wang, Feifei; Zhang, Xingsong

    2010-08-01

    A full-scale combined biological system is used for the treatment of treated wastewater discharged from a pharmaceutical industrial park. This treated water is rich in NH(4)(+)-N (average in 86.4 mg/L), low in COD/NH(4)(+)-N (average in 3.4) and low in BOD(5)/COD ratio (average in 0.24) with pH varying from 7.16 to 7.78. The final effluent of the combined treatment process was stably below 100mg/L COD and 20mg/L NH(4)(+)-N, separately, with organic loading rate of 4954 kg COD/d and 92.5 kg NH(4)(+)-N/d. It is found that the BOD(5)/COD ratio could be raised from 0.24 to 0.35, and the production of total VFAs account for 9.57% of the total COD via the treatment of hydrolysis/acidification. MBBR and oxidation ditch represent 35.4% and 60.7% of NH(4)(+)-N removal, 30.2% and 61.5% of COD removal, separately, of the total treatment process. PCR-DGGE is used for microbial community analysis of MBBR and oxidation ditch.

  14. Monitoring of cotton dust and health risk assessment in small-scale weaving industry.

    PubMed

    Tahir, Muhammad Wajid; Mumtaz, Muhammad Waseem; Tauseef, Shanza; Sajjad, Muqadas; Nazeer, Awais; Farheen, Nazish; Iqbal, Muddsar

    2012-08-01

    The present study describes the estimation of particulate matter (cotton dust) with different sizes, i.e., PM(1.0), PM(2.5), PM(4.0), and PM(10.0 μm) in small-scale weaving industry (power looms) situated in district Hafizabad, Punjab, Pakistan, and the assessment of health problems of workers associated with these pollutants. A significant difference was found in PM(1.0), PM(2.5), PM(4.0), and PM(10.0) with reference to nine different sampling stations with p values <0.05. Multiple comparisons of particulate matter with respect to size, i.e. PM(1.0), PM(2.5), PM(4.0), and PM(10.0), depict that PM(1.0) differs significantly from PM(2.5), PM(4.0), and PM(10.0), with p values <0.05 and that PM(2.5) differs significantly from PM(1.0) and PM(10.0), with p values <0.05, whereas PM(2.5) differs non-significantly from PM(4.0), with a p value >0.05 in defined sampling stations on an average basis. Majority of the workers were facing several diseases due to interaction with particulate matter (cotton dust) during working hours. Flue, cough, eye, and skin infections were the most common diseases among workers caused by particulate matter (cotton dust).

  15. Zero discharge performance of an industrial pilot-scale plant treating palm oil mill effluent.

    PubMed

    Wang, Jin; Mahmood, Qaisar; Qiu, Jiang-Ping; Li, Yin-Sheng; Chang, Yoon-Seong; Chi, Li-Na; Li, Xu-Dong

    2015-01-01

    Palm oil is one of the most important agroindustries in Malaysia. Huge quantities of palm oil mill effluent (POME) pose a great threat to aqueous environment due to its very high COD. To make full use of discharged wastes, the integrated "zero discharge" pilot-scale industrial plant comprising "pretreatment-anaerobic and aerobic process-membrane separation" was continuously operated for 1 year. After pretreatment in the oil separator tank, 55.6% of waste oil in raw POME could be recovered and sold and anaerobically digested through 2 AnaEG reactors followed by a dissolved air flotation (DAF); average COD reduced to about 3587 mg/L, and biogas production was 27.65 times POME injection which was used to generate electricity. The aerobic effluent was settled for 3 h or/and treated in MBR which could remove BOD3 (30°C) to less than 20 mg/L as required by Department of Environment of Malaysia. After filtration by UF and RO membrane, all organic compounds and most of the salts were removed; RO permeate could be reused as the boiler feed water. RO concentrate combined with anaerobic surplus sludge could be used as biofertilizer.

  16. Gaseous Oxidized Mercury Flux from Substrates Associated with Industrial Scale Gold Mining in Nevada, USA

    NASA Astrophysics Data System (ADS)

    Miller, M. B.

    2015-12-01

    Gaseous elemental and oxidized mercury (Hg) fluxes were measured in a laboratory setting from substrate materials derived from industrial-scale open pit gold mining operations in Nevada, USA. Mercury is present in these substrates at a range of concentrations (10 - 40000 ng g-1), predominantly of local geogenic origin in association with the mineralized gold ores, but altered and redistributed to a varying degree by subsequent ore extraction and processing operations, including deposition of Hg recently emitted to the atmosphere from large point sources on the mines. Waste rock, heap leach, and tailings material usually comprise the most extensive and Hg emission relevant substrate surfaces. All three of these material types were collected from active Nevada mine sites in 2010 for previous research, and have since been stored undisturbed at the University of Nevada, Reno. Gaseous elemental Hg (GEM) flux was previously measured from these materials under a variety of conditions, and was re-measured in this study, using Teflon® flux chambers and Tekran® 2537A automated ambient air analyzers. GEM flux from dry undisturbed materials was comparable between the two measurement periods. Gaseous oxidized Hg (GOM) flux from these materials was quantified using an active filter sampling method that consisted of polysulfone cation-exchange membranes deployed in conjunction with the GEM flux apparatus. Initial measurements conducted within greenhouse laboratory space indicate that in dry conditions GOM is deposited to relatively low Hg cap and leach materials, but may be emitted from the much higher Hg concentration tailings material.

  17. Interconnected, microporous hollow fibers for tissue engineering: commercially relevant, industry standard scale-up manufacturing.

    PubMed

    Tuin, Stephen A; Pourdeyhimi, Behnam; Loboa, Elizabeth G

    2014-09-01

    Significant progress has been achieved in the field of tissue engineering to create functional tissue using biomimetic three-dimensional scaffolds that support cell growth, proliferation, and extracellular matrix production. However, many of these constructs are severely limited by poor nutrient diffusion throughout the tissue-engineered construct, resulting in cell death and tissue necrosis at the core. Nutrient transport can be improved by creation and use of scaffolds with hollow and microporous fibers, significantly improving permeability and nutrient diffusion. The purpose of this review is to highlight current technological advances in the fabrication of hollow fibers with interconnected pores throughout the fiber walls, with specific emphasis on developing hollow porous nonwoven fabrics for use as tissue engineering constructs via industry standard processing technologies: Spunbond processing and polymer melt extrusion. We outline current methodologies to create hollow and microporous scaffolds with the aim of translating that knowledge to the production of such fibers into nonwoven tissue engineering scaffolds via spunbond technology, a commercially relevant and viable melt extrusion manufacturing approach that allows for facile scale-up.

  18. Real-time monitoring of emissions from monoethanolamine-based industrial scale carbon capture facilities.

    PubMed

    Zhu, Liang; Schade, Gunnar Wolfgang; Nielsen, Claus Jørgen

    2013-12-17

    We demonstrate the capabilities and properties of using Proton Transfer Reaction time-of-flight mass spectrometry (PTR-ToF-MS) to real-time monitor gaseous emissions from industrial scale amine-based carbon capture processes. The benchmark monoethanolamine (MEA) was used as an example of amines needing to be monitored from carbon capture facilities, and to describe how the measurements may be influenced by potentially interfering species in CO2 absorber stack discharges. On the basis of known or expected emission compositions, we investigated the PTR-ToF-MS MEA response as a function of sample flow humidity, ammonia, and CO2 abundances, and show that all can exhibit interferences, thus making accurate amine measurements difficult. This warrants a proper sample pretreatment, and we show an example using a dilution with bottled zero air of 1:20 to 1:10 to monitor stack gas concentrations at the CO2 Technology Center Mongstad (TCM), Norway. Observed emissions included many expected chemical species, dominantly ammonia and acetaldehyde, but also two new species previously not reported but emitted in significant quantities. With respect to concerns regarding amine emissions, we show that accurate amine quantifications in the presence of water vapor, ammonia, and CO2 become feasible after proper sample dilution, thus making PTR-ToF-MS a viable technique to monitor future carbon capture facility emissions, without conventional laborious sample pretreatment.

  19. Large-Scale Selection and Breeding To Generate Industrial Yeasts with Superior Aroma Production

    PubMed Central

    Steensels, Jan; Meersman, Esther; Snoek, Tim; Saels, Veerle

    2014-01-01

    The concentrations and relative ratios of various aroma compounds produced by fermenting yeast cells are essential for the sensory quality of many fermented foods, including beer, bread, wine, and sake. Since the production of these aroma-active compounds varies highly among different yeast strains, careful selection of variants with optimal aromatic profiles is of crucial importance for a high-quality end product. This study evaluates the production of different aroma-active compounds in 301 different Saccharomyces cerevisiae, Saccharomyces paradoxus, and Saccharomyces pastorianus yeast strains. Our results show that the production of key aroma compounds like isoamyl acetate and ethyl acetate varies by an order of magnitude between natural yeasts, with the concentrations of some compounds showing significant positive correlation, whereas others vary independently. Targeted hybridization of some of the best aroma-producing strains yielded 46 intraspecific hybrids, of which some show a distinct heterosis (hybrid vigor) effect and produce up to 45% more isoamyl acetate than the best parental strains while retaining their overall fermentation performance. Together, our results demonstrate the potential of large-scale outbreeding to obtain superior industrial yeasts that are directly applicable for commercial use. PMID:25192996

  20. Pilot-scale study of efficient vermicomposting of agro-industrial wastes.

    PubMed

    Kumar, Vaidyanathan Vinoth; Shanmugaprakash, M; Aravind, J; Namasivayam, S Karthick Raja

    2012-01-01

    Pilot-scale vermicomposting was explored using Eudrilus eugeniae for 90 days with 45 days preliminary decomposition using different agro-industrial wastes as substrates. Spent wash and pressmud were mixed together (referred to as PS) and then combined with cow dung (CD) at five different ratios of PS:CD, namely, 25:75 (T1), 50:50 (T2), 75:25 (T3), 85:15 (T4) and 100 (T5), with two replicates for each treatment. All vermibeds expressed a significant decrease in pH (11.4-14.8%), organic carbon (4.2-30.5%) and an increase in total nitrogen (6-29%), AP (5-29%), exchangeable potash (6-21%) and turnover rate (52-66%). Maximum mortality (18.10%) of worms was recorded in T5 treatment. A high manurial value and a matured product was achieved in T3 treatment. The data reveal that pressmud mixed with spent wash can be decomposed through vermicomposting and can help to enhance the quality of vermicompost.

  1. An industry-scale mass marking technique for tracing farmed fish escapees.

    PubMed

    Warren-Myers, Fletcher; Dempster, Tim; Fjelldal, Per Gunnar; Hansen, Tom; Swearer, Stephen E

    2015-01-01

    Farmed fish escape and enter the environment with subsequent effects on wild populations. Reducing escapes requires the ability to trace individuals back to the point of escape, so that escape causes can be identified and technical standards improved. Here, we tested if stable isotope otolith fingerprint marks delivered during routine vaccination could be an accurate, feasible and cost effective marking method, suitable for industrial-scale application. We tested seven stable isotopes, (134)Ba, (135)Ba, (136)Ba, (137)Ba, (86)Sr, (87)Sr and (26)Mg, on farmed Atlantic salmon reared in freshwater, in experimental conditions designed to reflect commercial practice. Marking was 100% successful with individual Ba isotopes at concentrations as low as 0.001 µg. g-1 fish and for Sr isotopes at 1 µg. g-1 fish. Our results suggest that 63 unique fingerprint marks can be made at low cost using Ba (0.0002 - 0.02 $US per mark) and Sr (0.46 - 0.82 $US per mark) isotopes. Stable isotope fingerprinting during vaccination is feasible for commercial application if applied at a company level within the world's largest salmon producing nations. Introducing a mass marking scheme would enable tracing of escapees back to point of origin, which could drive greater compliance, better farm design and improved management practices to reduce escapes.

  2. Coal-to-liquids: Potential impact on U.S. coal reserves

    USGS Publications Warehouse

    Milici, R.C.

    2009-01-01

    The production of liquid fuels from coal will very likely become an important part of the hydrocarbon energy mix of the future, provided that technical and environmental obstacles are overcome economically. The coal industry should be able to handle a coal-to-liquids (CTL) industry of modest size, using 60-70 million short tons or 54-64 million metric tonnes of coal per annum, without premature depletion of the country's coal reserves. However, attempts to use CTL technology to replace all petroleum imports would deplete the nation's coal reserves by the end of the century. ?? 2009 U.S. Government.

  3. Industrial Scale Isolation, Structural and Spectroscopic Characterization of Epiisopiloturine from Pilocarpus microphyllus Stapf Leaves: A Promising Alkaloid against Schistosomiasis

    PubMed Central

    Véras, Leiz M. C.; Cunha, Vanessa R. R.; Lima, Filipe C. D. A.; Guimarães, Maria A.; Vieira, Marianne M.; Campelo, Yuri D. M.; Sakai, Vanessa Y.; Lima, David F.; Carvalho Jr, Paulo S.; Ellena, Javier A.; Silva, Paulo R. P.; Vasconcelos, Luciene C.; Godejohann, Markus; Petrilli, Helena M.; Constantino, Vera R. L.; Mascarenhas, Yvonne P.; de Souza de Almeida Leite, José Roberto

    2013-01-01

    This paper presents an industrial scale process for extraction, purification, and isolation of epiisopiloturine (EPI) (2(3H)-Furanone,dihydro-3-(hydroxyphenylmethyl)-4-[(1-methyl-1H-imidazol-4-yl)methyl]-, [3S-[3a(R*),4b

  4. Study of application of ERTS-A imagery to fracture related mine safety hazards in the coal mining industry

    NASA Technical Reports Server (NTRS)

    Wier, C. E.; Wobber, F. J. (Principal Investigator); Russell, O. R.; Amato, R. V.

    1973-01-01

    The author has identified the following significant results. The utility of ERTS-1/high altitude aircraft imagery to detect underground mine hazards is strongly suggested. A 1:250,000 scale mined lands map of the Vincennes Quadrangle, Indiana has been prepared. This map is a prototype for a national mined lands inventory and will be distributed to State and Federal offices.

  5. Clean Coal Technology Demonstration Program. Program update 1994

    SciTech Connect

    1995-04-01

    The Clean Coal Technology Demonstration Program (CCT Program) is a $7.14 billion cost-shared industry/government technology development effort. The program is to demonstrate a new generation of advanced coal-based technologies, with the most promising technologies being moved into the domestic and international marketplace. Clean coal technologies being demonstrated under the CCT program are creating the technology base that allows the nation to meet its energy and environmental goals efficiently and reliably. The fact that most of the demonstrations are being conducted at commercial scale, in actual user environments, and under conditions typical of commercial operations allows the potential of the technologies to be evaluated in their intended commercial applications. The technologies are categorized into four market sectors: advanced electric power generation systems; environmental control devices; coal processing equipment for clean fuels; and industrial technologies. Sections of this report describe the following: Role of the Program; Program implementation; Funding and costs; The road to commercial realization; Results from completed projects; Results and accomplishments from ongoing projects; and Project fact sheets. Projects include fluidized-bed combustion, integrated gasification combined-cycle power plants, advanced combustion and heat engines, nitrogen oxide control technologies, sulfur dioxide control technologies, combined SO{sub 2} and NO{sub x} technologies, coal preparation techniques, mild gasification, and indirect liquefaction. Industrial applications include injection systems for blast furnaces, coke oven gas cleaning systems, power generation from coal/ore reduction, a cyclone combustor with S, N, and ash control, cement kiln flue gas scrubber, and pulse combustion for steam coal gasification.

  6. Coal Research

    NASA Technical Reports Server (NTRS)

    1986-01-01

    Coal slurries are "clean" pulverized coal mixed with oil or water. Significant fuel savings can be realized when using coal slurries. Advanced Fuels Technology (AFT) utilized a COSMIC program, (Calculation of Complex Chemical Equilibrium Compositions), which provides specific capabilities for determining combustion products. The company has developed a cleaning process that removes much of the mineral sulphur and ash from the coals.

  7. ULTRA LOW NOx INTEGRATED SYSTEM FOR NOx EMISSION CONTROL FROM COAL-FIRED BOILERS

    SciTech Connect

    Galen H. Richards; Charles Q. Maney; Richard W. Borio; Robert D. Lewis

    2002-12-30

    ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important, enabling step in keeping coal as a viable part of the national energy mix in this century, and beyond. Presently 57% of U.S. electrical generation is coal based, and the Energy Information Agency projects that coal will maintain a lead in U.S. power generation over all other fuel sources for decades (EIA 1998 Energy Forecast). Yet, coal-based power is being strongly challenged by society's ever-increasing desire for an improved environment and the resultant improvement in health and safety. The needs of the electric-utility industry are to improve environmental performance, while simultaneously improving overall plant economics. This means that emissions control technology is needed with very low capital and operating costs. This project has responded to the industry's need for low NOx emissions by evaluating ideas that can be adapted to present pulverized coal fired systems, be they conventional or low NOx firing systems. The TFS 2000{trademark} firing system has been the ALSTOM Power Inc. commercial offering producing the lowest NOx emission levels. In this project, the TFS 2000{trademark} firing system served as a basis for comparison to other low NOx systems evaluated and was the foundation upon which refinements were made to further improve NOx emissions and

  8. TVA coal-gasification plant conceptual design. Volume 1. Plant based on Executive overview (Summary). Final report

    SciTech Connect

    Not Available

    1980-11-01

    TVA plans to build a coal gasification plant to demonstrate the operation of a commercial scale coal gasification facility producing a clean medium Btu gas (MBG) for use in various industrial applications in the TVA region. In the Phase I efforts, Foster Wheeler Energy Corporation prepared conceptual designs, cost estimates, and trade-off studies of the following gasification systems: Lurgi Dry Bottom, Koppers-Totzek, Babcock and Wilcox, British Gas Slagger, and Texaco.

  9. The ENCOAL Mild Coal Gasification Project, A DOE Assessment

    SciTech Connect

    National Energy Technology Laboratory

    2002-03-15

    This report is a post-project assessment of the ENCOAL{reg_sign} Mild Coal Gasification Project, which was selected under Round III of the U.S. Department of Energy (DOE) Clean Coal Technology (CCT) Demonstration Program. The CCT Demonstration Program is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of commercial-scale facilities. The ENCOAL{reg_sign} Corporation, a wholly-owned subsidiary of Bluegrass Coal Development Company (formerly SMC Mining Company), which is a subsidiary of Ziegler Coal Holding Company, submitted an application to the DOE in August 1989, soliciting joint funding of the project in the third round of the CCT Program. The project was selected by DOE in December 1989, and the Cooperative Agreement (CA) was approved in September 1990. Construction, commissioning, and start-up of the ENCOAL{reg_sign} mild coal gasification facility was completed in June 1992. In October 1994, ENCOAL{reg_sign} was granted a two-year extension of the CA with the DOE, that carried through to September 17, 1996. ENCOAL{reg_sign} was then granted a six-month, no-cost extension through March 17, 1997. Overall, DOE provided 50 percent of the total project cost of $90,664,000. ENCOAL{reg_sign} operated the 1,000-ton-per-day mild gasification demonstration plant at Triton Coal Company's Buckskin Mine near Gillette, Wyoming, for over four years. The process, using Liquids From Coal (LFC{trademark}) technology originally developed by SMC Mining Company and SGI International, utilizes low-sulfur Powder River Basin (PRB) coal to produce two new fuels, Process-Derived Fuel (PDF{trademark}) and Coal-Derived Liquids (CDL{trademark}). The products, as alternative fuel sources, are capable of significantly lowering current sulfur emissions at industrial and utility boiler sites throughout the nation thus reducing pollutants causing acid rain. In support of this overall objective

  10. Connect the Spheres with the Coal Cycle

    ERIC Educational Resources Information Center

    Clary, Renee; Wandersee, James

    2010-01-01

    Coal fueled the Industrial Revolution and, as a result, changed the course of human history. However, the geologic history of coal is much, much longer than that which is recorded by humans. In your classroom, the coal cycle can be used to trace the formation of this important economic resource from its plant origins, through its lithification, or…

  11. Coal mine directory: United States and Canada

    SciTech Connect

    2004-07-01

    The directory gives a state-by-state listing of all US and Canadian coal producers. It contains contact information as well as the type of mine, production statistics, coal composition, transportation methods etc. A statistical section provides general information about the US coal industry, preparation plants, and longwall mining operations.

  12. Coal combustion byproducts and environmental issues

    SciTech Connect

    Sajwan, K.S.; Twardowska, I.; Punshon, T.; Alva, A.K.

    2006-07-01

    The book addresses the major implications and critical issues surrounding coal combustion products and their impact upon the environment. It provides essential information for scientists conducting research on coal and coal combustion products, but also serves as a valuable reference for a wide variety of researchers and other professionals in the energy industry and in the fields of public health, engineering, and environmental sciences.

  13. National Coal Quality Inventory (NACQI)

    SciTech Connect

    Robert Finkelman

    2005-09-30

    The U.S. Geological Survey (USGS) conducted the National Coal Quality Inventory (NaCQI) between 1999 and 2005 to address a need for quality information on coals that will be mined during the next 20-30 years. Collaboration between the USGS, State geological surveys, universities, coal burning utilities, and the coal mining industry plus funding support from the Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE) permitted collection and submittal of coal samples for analysis. The chemical data (proximate and ultimate analyses; major, minor and trace element concentrations) for 729 samples of raw or prepared coal, coal associated shale, and coal combustion products (fly ash, hopper ash, bottom ash and gypsum) from nine coal producing States are included. In addition, the project identified a new coal reference analytical standard, to be designated CWE-1 (West Elk Mine, Gunnison County, Colorado) that is a high-volatile-B or high-volatile-A bituminous coal with low contents of ash yield and sulfur, and very low, but detectable contents of chlorine, mercury and other trace elements.

  14. Colombia: why coal won't wait

    SciTech Connect

    Not Available

    1983-05-11

    Colombia's coal production target is 68-million tons by the year 2000, with hopes to export 10% of world thermal-coal demand. Colombia's economic commitment to coal marketing is not an option, but an imperative. There are indications that coal production in the US - bogged down by complex transportation, environmental, and other disputes - will be revitalized, partly because Colombia will be added to the list of international coal-market competitors. Some coal-industry analysts recognize that the Colombian factor could, through stimulating price competition, encourage world coal consumption. Despite monumental infrastructure requirements that will turn the area between El Cerrejon and the Caribbean Sea into one integrated complex, the government is throwing itself heart and soul back into the coal age. This issue has the Energy Detente fuel price/tax series and the principal industrial fuel prices for May 1983 for countries of the Eastern Hemisphere.

  15. Non-contact multi-frequency magnetic induction spectroscopy system for industrial-scale bio-impedance measurement

    NASA Astrophysics Data System (ADS)

    O'Toole, M. D.; Marsh, L. A.; Davidson, J. L.; Tan, Y. M.; Armitage, D. W.; Peyton, A. J.

    2015-03-01

    Biological tissues have a complex impedance, or bio-impedance, profile which changes with respect to frequency. This is caused by dispersion mechanisms which govern how the electromagnetic field interacts with the tissue at the cellular and molecular level. Measuring the bio-impedance spectra of a biological sample can potentially provide insight into the sample’s properties and its cellular structure. This has obvious applications in the medical, pharmaceutical and food-based industrial domains. However, measuring the bio-impedance spectra non-destructively and in a way which is practical at an industrial scale presents substantial challenges. The low conductivity of the sample requires a highly sensitive instrument, while the demands of industrial-scale operation require a fast high-throughput sensor of rugged design. In this paper, we describe a multi-frequency magnetic induction spectroscopy (MIS) system suitable for industrial-scale, non-contact, spectroscopic bio-impedance measurement over a bandwidth of 156 kHz-2.5 MHz. The system sensitivity and performance are investigated using calibration and known reference samples. It is shown to yield rapid and consistently sensitive results with good long-term stability. The system is then used to obtain conductivity spectra of a number of biological test samples, including yeast suspensions of varying concentration and a range of agricultural produce, such as apples, pears, nectarines, kiwis, potatoes, oranges and tomatoes.

  16. Application of Pulse Spark Discharges for Scale Prevention and Continuous Filtration Methods in Coal-Fired Power Plant

    SciTech Connect

    Cho, Young; Fridman, Alexander

    2012-06-30

    The overall objective of the present work was to develop a new scale-prevention technology by continuously precipitating and removing dissolved mineral ions (such as calcium and magnesium) in cooling water while the COC could be doubled from the present standard value of 3.5. The hypothesis of the present study was that if we could successfully precipitate and remove the excess calcium ions in cooling water, we could prevent condenser-tube fouling and at the same time double the COC. The approach in the study was to utilize pulse spark discharges directly in water to precipitate dissolved mineral ions in recirculating cooling water into relatively large suspended particles, which could be removed by a self-cleaning filter. The present study began with a basic scientific research to better understand the mechanism of pulse spark discharges in water and conducted a series of validation experiments using hard water in a laboratory cooling tower. Task 1 of the present work was to demonstrate if the spark discharge could precipitate the mineral ions in water. Task 2 was to demonstrate if the selfcleaning filter could continuously remove these precipitated calcium particles such that the blowdown could be eliminated or significantly reduced. Task 3 was to demonstrate if the scale could be prevented or minimized at condenser tubes with a COC of 8 or (almost) zero blowdown. In Task 1, we successfully completed the validation study that confirmed the precipitation of dissolved calcium ions in cooling water with the supporting data of calcium hardness over time as measured by a calcium ion probe. In Task 2, we confirmed through experimental tests that the self-cleaning filter could continuously remove precipitated calcium particles in a simulated laboratory cooling tower such that the blowdown could be eliminated or significantly reduced. In addition, chemical water analysis data were obtained which were used to confirm the COC calculation. In Task 3, we conducted a series

  17. Designing Clothing for Coal Miners

    ERIC Educational Resources Information Center

    Watkins, Susan M.

    1977-01-01

    Describes procedures taken by apparel design students, working in an industrial setting, in designing functional clothing for coal miners as part of the Armco Steel Corporation's Student Design Program. (TA)

  18. Mercury emissions during cofiring of sub-bituminous coal and biomass (chicken waste, wood, coffee residue, and tobacco stalk) in a laboratory-scale fluidized bed combustor

    SciTech Connect

    Yan Cao; Hongcang Zhou; Junjie Fan; Houyin Zhao; Tuo Zhou; Pauline Hack; Chia-Chun Chan; Jian-Chang Liou; Wei-ping Pan

    2008-12-15

    Four types of biomass (chicken waste, wood pellets, coffee residue, and tobacco stalks) were cofired at 30 wt % with a U.S. sub-bituminous coal (Powder River Basin Coal) in a laboratory-scale fluidized bed combustor. A cyclone, followed by a quartz filter, was used for fly ash removal during tests. The temperatures of the cyclone and filter were controlled at 250 and 150{sup o}C, respectively. Mercury speciation and emissions during cofiring were investigated using a semicontinuous mercury monitor, which was certified using ASTM standard Ontario Hydra Method. Test results indicated mercury emissions were strongly correlative to the gaseous chlorine concentrations, but not necessarily correlative to the chlorine contents in cofiring fuels. Mercury emissions could be reduced by 35% during firing of sub-bituminous coal using only a quartz filter. Cofiring high-chlorine fuel, such as chicken waste (Cl = 22340 wppm), could largely reduce mercury emissions by over 80%. When low-chlorine biomass, such as wood pellets (Cl = 132 wppm) and coffee residue (Cl = 134 wppm), is cofired, mercury emissions could only be reduced by about 50%. Cofiring tobacco stalks with higher chlorine content (Cl = 4237 wppm) did not significantly reduce mercury emissions. Gaseous speciated mercury in flue gas after a quartz filter indicated the occurrence of about 50% of total gaseous mercury to be the elemental mercury for cofiring chicken waste, but occurrence of above 90% of the elemental mercury for all other cases. Both the higher content of alkali metal oxides or alkali earth metal oxides in tested biomass and the occurrence of temperatures lower than 650{sup o}C in the upper part of the fluidized bed combustor seemed to be responsible for the reduction of gaseous chlorine and, consequently, limited mercury emissions reduction during cofiring. 36 refs., 3 figs. 1 tab.

  19. Quarterly coal report

    SciTech Connect

    Young, P.

    1996-05-01

    The Quarterly Coal Report (QCR) provides comprehensive information about U.S. coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for October through December 1995 and aggregated quarterly historical data for 1987 through the third quarter of 1995. Appendix A displays, from 1987 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  20. Liquefaction of calcium-containing subbituminous coals and coals of lower rank

    DOEpatents

    Brunson, Roy J.

    1979-01-01

    An improved process for the treatment of a calcium-containing subbituminous coal and coals of lower rank to form insoluble, thermally stable calcium salts which remain within the solids portions of the residue on liquefaction of the coal, thereby suppressing the formation of scale, made up largely of calcium carbonate which normally forms within the coal liquefaction reactor (i.e., coal liquefaction zone), e.g., on reactor surfaces, lines, auxiliary equipment and the like. An oxide of sulfur, in liquid phase, is contacted with a coal feed sufficient to impregnate the pores of the coal. The impregnated coal, in particulate form, can thereafter be liquefied in a coal liquefaction reactor (reaction zone) at coal liquefaction conditions without significant formation of scale.

  1. Effect of alkalinity on nitrite accumulation in treatment of coal chemical industry wastewater using moving bed biofilm reactor.

    PubMed

    Hou, Baolin; Han, Hongjun; Jia, Shengyong; Zhuang, Haifeng; Zhao, Qian; Xu, Peng

    2014-05-01

    Nitrogen removal via nitrite (the nitrite pathway) is more suitable for carbon-limited industrial wastewater. Partial nitrification to nitrite is the primary step to achieve nitrogen removal via nitrite. The effect of alkalinity on nitrite accumulation in a continuous process was investigated by progressively increasing the alkalinity dosage ratio (amount of alkalinity to ammonia ratio, mol/mol). There is a close relationship among alkalinity, pH and the state of matter present in aqueous solution. When alkalinity was insufficient (compared to the theoretical alkalinity amount), ammonia removal efficiency increased first and then decreased at each alkalinity dosage ratio, with an abrupt removal efficiency peak. Generally, ammonia removal efficiency rose with increasing alkalinity dosage ratio. Ammonia removal efficiency reached to 88% from 23% when alkalinity addition was sufficient. Nitrite accumulation could be achieved by inhibiting nitrite oxidizing bacteria (NOB) by free ammonia (FA) in the early period and free nitrous acid in the later period of nitrification when alkalinity was not adequate. Only FA worked to inhibit the activity of NOB when alkalinity addition was sufficient.

  2. Fieldston coal transportation manual, 1991

    SciTech Connect

    Not Available

    1991-01-01

    This book reports on coal production and movements contains up-to-day statistics and analysis of the coal transportation industry. It contains railroad rates and tonnages hauled, along with the contracting point. Rail systems and mine origin maps for traffic analysis are also included. The book also covers coal transfer points on inland waterways, transfer capabilities, coal hauling barge lines in 1988, 1989, and 1990, spot barge rates and key contacts. Details of US and Canadian ports, Great Lakes docks and foreign ocean docks are listed. Port loading statistics, ocean shipping rates, port authorities and listings are given along with regional maps of rail lines and schematic drawings of loading facilities.

  3. Villacidro solar demo plant: Integration of small-scale CSP and biogas power plants in an industrial microgrid

    NASA Astrophysics Data System (ADS)

    Camerada, M.; Cau, G.; Cocco, D.; Damiano, A.; Demontis, V.; Melis, T.; Musio, M.

    2016-05-01

    The integration of small scale concentrating solar power (CSP) in an industrial district, in order to develop a microgrid fully supplied by renewable energy sources, is presented in this paper. The plant aims to assess in real operating conditions, the performance, the effectiveness and the reliability of small-scale concentrating solar power technologies in the field of distributed generation. In particular, the potentiality of small scale CSP with thermal storage to supply dispatchable electricity to an industrial microgrid will be investigated. The microgrid will be realized in the municipal waste treatment plant of the Industrial Consortium of Villacidro, in southern Sardinia (Italy), which already includes a biogas power plant. In order to achieve the microgrid instantaneous energy balance, the analysis of the time evolution of the waste treatment plant demand and of the generation in the existing power systems has been carried out. This has allowed the design of a suitable CSP plant with thermal storage and an electrochemical storage system for supporting the proposed microgrid. At the aim of obtaining the expected energy autonomy, a specific Energy Management Strategy, which takes into account the different dynamic performances and characteristics of the demand and the generation, has been designed. In this paper, the configuration of the proposed small scale concentrating solar power (CSP) and of its thermal energy storage, based on thermocline principle, is initially described. Finally, a simulation study of the entire power system, imposing scheduled profiles based on weather forecasts, is presented.

  4. DETERMINATION OF THE FORMS OF NITROGEN RELEASED IN COAL TAR DURING RAPID DEVOLATILIZATION

    SciTech Connect

    1998-10-30

    The primary objective of this work is to determine the forms of nitrogen in coal that lead to nitrogen release during devolatilization. Experiments are to be performed in two existing laminar flow reactors available at Brigham Young University, which are both capable of temperatures (up to 2000 K), particle heating rates (10 4 to 10 5 K/s), and residence times (up to 500 ms) relevant to conditions commonly encountered in industrial pulverized coal combustors. The forms of nitrogen in coal, char, and tar samples are analyzed using state-of-the-art techniques, including nuclear magnetic resonance (NMR), X-Ray photoelectron spectroscopy (XPS), and high resolution nitrogen-specific chromatography. These sophisticated analysis techniques are being performed in collaboration with other researchers at BYU, the University of Utah, and industrial organizations. Coals have been obtained as a function of rank, including eight coals from the University of Utah that are to be used in pilot scale tests in support of the DOE Coal-2000 HiPPS (High Performance Power Systems) and LEBS (Low-Emission Boiler Systems) programs. Results from the proposed research are (a) nitrogen release parameters during devolatilization for specific coals pertinent to the HiPPS and LEBS projects, (b) better fundamental understanding of the chemistry of nitrogen release, and (c) a nitrogen release submodel based on fundamental chemistry that may be more widely applicable than existing empirical relationships.

  5. Novel single stripper with side-draw to remove ammonia and sour gas simultaneously for coal-gasification wastewater treatment and the industrial implementation

    SciTech Connect

    Feng, D.C.; Yu, Z.J.; Chen, Y.; Qian, Y.

    2009-06-15

    A large amount of wastewater is produced in the Lurgi coal-gasification process with the complex compounds carbon dioxide, ammonia, phenol, etc., which cause a serious environmental problem. In this paper, a novel stripper operated at elevated pressure is designed to improve the pretreatment process. In this technology, two noticeable improvements were established. First, the carbon dioxide and ammonia were removed simultaneously in a single stripper where sour gas (mainly carbon dioxide) is removed from the tower top and the ammonia vapor is drawn from the side and recovered by partial condensation. Second, the ammonia is removed before the phenol recovery to reduce the pH value of the subsequent extraction units, so as the phenol removal performance of the extraction is greatly improved. To ensure the operational efficiency, some key operational parameters are analyzed and optimized though simulation. It is shown that when the top temperature is kept at 40 C and the weight ratio of the side draw to the feed is above 9%, the elevated pressures can ensure the removal efficiency of NH{sub 3} and carbon dioxide and the desired purified water as the bottom product of the unit is obtained. A real industrial application demonstrates the attractiveness of the new technique: it removes 99.9% CO{sub 2} and 99.6% ammonia, compared to known techniques which remove 66.5% and 94.4%, respectively. As a result, the pH value of the wastewater is reduced from above 9 to below 7. This ensures that the phenol removal ratio is above 93% in the following extraction units. The operating cost is lower than that of known techniques, and the operation is simplified.

  6. Small-scale spatial heterogeneity in Pennsylvanian-age vegetation from the roof shale of the Springfield coal (Illinois Basin)

    SciTech Connect

    DiMichele, W.A. ); Nelson, W.J. )

    1989-06-01

    An underground mine in southern Illinois exposes the spatial composition of the final forest of the Springfield (No. 5) Coal swamp. The area studied is within 600 m of the Galatia channel, contemporaneous deposits that mark the course of a river that periodically flooded the surface of the adjacent peat-forming forest. A nearly pure stand of Sigillaria mamillaris is flanked on the south, the side farthest from the channel, by a pteridosperm-calamite vegetation from which Sigillaria is absent. The ecotonal contact of these two assemblages may be as narrow as 2 m wide. On the north end, the side closest to the channel, the Sigillaria stand grades over a 40 m wide ecotone into a mixed lycopod-calamite vegetation with minor pteridosperms. Tree ferns and ground cover are nearly absent from all assemblages. This exposure provides a rare look at the short-term spatial heterogeneity of a Pennsylvanian-age peat-forming forest, and reveals an unexpected degree of patchiness, which is not demonstrable from most outcrop or coal-ball exposures.

  7. Reconstruction and analysis of the industrial strain Bacillus megaterium WSH002 genome-scale in silico metabolic model.

    PubMed

    Zou, Wei; Zhou, Maoda; Liu, Liming; Chen, Jian

    2013-04-15

    A genome-scale metabolic model of Bacillus megaterium WSH002, an industrial bacterium widely used in the vitamin C industry, was reconstructed on the basis of the genome annotation and data from the literature and biochemical databases. It comprises 1112 reactions, 993 metabolites, and 1055 genes, including 43 new annotated genes. This model was able to predict qualitatively and quantitatively the growth of B. megaterium on a range of carbon and nitrogen sources, and the results agreed well with experimental data. A gene essentiality analysis predicted a core metabolic essential gene set of 57 genes on three different media. Furthermore, constraint-based analysis revealed that B. megaterium WSH002 is capable of producing and exporting several key metabolites, which could promote the growth of Ketogulonicigenium vulgare and 2-keto-l-gulonic acid (2-KLG) production. Here, the model represents a helpful tool for understanding and exploring this important industrial organism.

  8. Curbing variations in packaging process through Six Sigma way in a large-scale food-processing industry

    NASA Astrophysics Data System (ADS)

    Desai, Darshak A.; Kotadiya, Parth; Makwana, Nikheel; Patel, Sonalinkumar

    2015-08-01

    Indian industries need overall operational excellence for sustainable profitability and growth in the present age of global competitiveness. Among different quality and productivity improvement techniques, Six Sigma has emerged as one of the most effective breakthrough improvement strategies. Though Indian industries are exploring this improvement methodology to their advantage and reaping the benefits, not much has been presented and published regarding experience of Six Sigma in the food-processing industries. This paper is an effort to exemplify the application of Six Sigma quality improvement drive to one of the large-scale food-processing sectors in India. The paper discusses the phase wiz implementation of define, measure, analyze, improve, and control (DMAIC) on one of the chronic problems, variations in the weight of milk powder pouch. The paper wraps up with the improvements achieved and projected bottom-line gain to the unit by application of Six Sigma methodology.

  9. Comparing Antonovsky's sense of coherence scale across three UK post-industrial cities

    PubMed Central

    Walsh, David; McCartney, Gerry; McCullough, Sarah; Buchanan, Duncan; Jones, Russell

    2014-01-01

    Objectives High levels of ‘excess’ mortality (ie, that seemingly not explained by deprivation) have been shown for Scotland compared to England and Wales and, especially, for its largest city, Glasgow, compared to the similarly deprived English cities of Liverpool and Manchester. It has been suggested that this excess may be related to differences in ‘Sense of Coherence’ (SoC) between the populations. The aim of this study was to ascertain whether levels of SoC differed between these cities and whether, therefore, this could be a plausible explanation for the ‘excess’. Setting Three post-industrial UK cities: Glasgow, Liverpool and Manchester. Participants A representative sample of more than 3700 adults (over 1200 in each city). Primary and secondary outcome measures SoC was measured using Antonovsky's 13-item scale (SOC-13). Multivariate linear regression was used to compare SoC between the cities while controlling for characteristics (age, gender, SES etc) of the samples. Additional modelling explored whether differences in SoC moderated city differences in levels of self-assessed health (SAH). Results SoC was higher, not lower, among the Glasgow sample. Fully adjusted mean SoC scores for residents of Liverpool and Manchester were, respectively, 5.1 (−5.1 (95% CI −6.0 to −4.1)) and 8.1 (−8.1 (−9.1 to −7.2)) lower than those in Glasgow. The additional modelling confirmed the relationship between SoC and SAH: a 1 unit increase in SoC predicted approximately 3% lower likelihood of reporting bad/very bad health (OR=0.97 (95% CI 0.96 to 0.98)): given the slightly worse SAH in Glasgow, this resulted in slightly lower odds of reporting bad/very bad health for the Liverpool and Manchester samples compared to Glasgow. Conclusions The reasons for the high levels of ‘excess’ mortality seen in Scotland and particularly Glasgow remain unclear. However, on the basis of these analyses, it appears unlikely that a low SoC provides any explanation

  10. Innovative clean coal technology (ICCT): demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emission from high-sulfur, coal-fired boilers - economic evaluation of commercial-scale SCR applications for utility boilers

    SciTech Connect

    Healy, E.C.; Maxwell, J.D.; Hinton, W.S.

    1996-09-01

    This report presents the results of an economic evaluation produced as part of the Innovative Clean Coal Technology project, which demonstrated selective catalytic reduction (SCR) technology for reduction of NO{sub x} emissions from utility boilers burning U.S. high-sulfur coal. The document includes a commercial-scale capital and O&M cost evaluation of SCR technology applied to a new facility, coal-fired boiler utilizing high-sulfur U.S. coal. The base case presented herein determines the total capital requirement, fixed and variable operating costs, and levelized costs for a new 250-MW pulverized coal utility boiler operating with a 60-percent NO{sub x} removal. Sensitivity evaluations are included to demonstrate the variation in cost due to changes in process variables and assumptions. This report also presents the results of a study completed by SCS to determine the cost and technical feasibility of retrofitting SCR technology to selected coal-fired generating units within the Southern electric system.

  11. Combustion and fuel characterization of coal-water fuels

    SciTech Connect

    Not Available

    1989-07-01

    Pittsburgh Energy Technology Center (PETC) of the Department of Energy initiated a comprehensive effort in 1982 to develop the necessary performance and cost data and to assess the commercial viability of coal water fuels (CWFs) as applied to representative utility and industrial units. The effort comprised six tasks beginning with coal resource evaluation and culminating in the assessment of the technical and economic consequences of switching representative commercial units from oil to state-of-the-art CWF firing. Extensive bench, pilot and commercial-scale tests were performed to develop necessary CWF combustion and fireside performance data for the subsequent boiler performance analyses and retrofit cost estimates. This report (Volume 2) provides a review of the fuel selection and procurement activities. Included is a discussion on coal washability, transport of the slurry, and characterization. 20 figs., 26 tabs.

  12. Clean coal technology demonstration program: Program update 1996-97

    SciTech Connect

    1997-10-01

    The Clean Coal Technology Demonstration Program (known as the CCT Program) reached a significant milestone in 1996 with the completion of 20 of the 39 active projects. The CCT Program is responding to a need to demonstrate and deploy a portfolio of technologies that will assure the U.S. recoverable coal reserves of 297 billion tons could continue to supply the nation`s energy needs economically and in a manner that meets the nation`s environmental objectives. This portfolio of technologies includes environmental control devices that contributed to meeting the accords on transboundary air pollution recommended by the Special Envoys on Acid Rain in 1986. Operational, technical, environmental, and economic performance information and data are now flowing from highly efficient, low-emission, advanced power generation technologies that will enable coal to retain its prominent role into the next millennium. Further, advanced technologies are emerging that will enhance the competitive use of coal in the industrial sector, such as in steelmaking. Coal processing technologies will enable the entire coal resource base to be used while complying with environmental requirements. These technologies are producing products used by utilities and industrial processes. The capability to coproduce products, such as liquid and solid fuels, electricity, and chemicals, is being demonstrated at a commercial scale by projects in the CCT Program. In summary, this portfolio of technologies is satisfying the national need to maintain a multifuel energy mix in which coal is a key component because of its low-cost, availability, and abundant supply within the nation`s borders.

  13. Production of Illinois base compliance coal using enhanced gravity separation. [Quarterly] technical report, September 1--November 30, 1993

    SciTech Connect

    Paul, B.C.; Honaker, R.Q.; Ho, K.

    1993-12-31

    Illinois Basin coal often contains a significant portion of finely dispersed pyrite. Most of the free pyrite particles exist in the fine size fractions, which are generally treated using froth flotation. An inherent problem of the froth flotation process is the inefficient treatment of middling particles containing a small amount of coal on their surface. On the other hand, gravity-based processes can effectively remove middling particles containing only a small amount of coal. Falcon Concentrators Inc. and Knelson Gold Concentrators Inc. have developed full-scale, enhanced gravity separators for the treatment of heavy minerals. This project will evaluate the potential of using these concentrators to de-ash and de-sulfurize Illinois coal fines, thus, producing coal products that meet the requirements for Phase I of the Clean Air Act. Since both continuous separators are commercially available, the results obtained in this investigation should be applicable to industrial operations.

  14. Development of an advanced high efficiency coal combustor for boiler retrofit. Task 1, Cold flow burner development: Final report

    SciTech Connect

    LaFlesh, R.C.; Rini, M.J.; McGowan, J.G.

    1989-10-01

    The overall objective of this program is to develop a high efficiency advanced coal combustor (HEACC) for coal-based fuels capable of being retrofitted to industrial boilers originally designed for firing natural gas, distillate, and/or residual oil. The HEACC system is to be capable of firing microfine coal water fuel (MCWF), MCWF with alkali sorbent (for SO{sub 2} reduction), and dry microfine coal. Design priorities for the system are that it be simple to operate and will offer significant reductions in NO{sub x}, SO{sub x}, and particulate emissions as compared with current coal fired combustor technology. The specific objective of this report is to document the work carried out under Task 1.0 of this contract, ``Cold Flow Burner Development``. As are detailed in the report, key elements of this work included primary air swirler development, burner register geometry design, cold flow burner model testing, and development of burner scale up criteria.

  15. W versus Co-Al as Gate Fill-Metal for Aggressively Scaled Replacement High-k/Metal Gate Devices for (Sub-)22 nm Technology Nodes

    NASA Astrophysics Data System (ADS)

    Veloso, Anabela; Aik Chew, Soon; Schram, Tom; Dekkers, Harold; Van Ammel, Annemie; Witters, Thomas; Tielens, Hilde; Heylen, Nancy; Devriendt, Katia; Sebaai, Farid; Brus, Stephan; Ragnarsson, Lars-Åke; Pantisano, Luigi; Eneman, Geert; Carbonell, Laure; Richard, Olivier; Favia, Paola; Geypen, Jef; Bender, Hugo; Higuchi, Yuichi; Phatak, Anup; Thean, Aaron; Horiguchi, Naoto

    2013-04-01

    In this work we provide a comprehensive evaluation of a novel, low-resistance Co-Al alloy vs W to fill aggressively scaled gates with high aspect-ratios [gate height (Hgate) ˜50-60 nm, gate length (Lgate) ≥20-25 nm]. We demonstrate that, with careful liner/barrier materials selection and tuning, well-behaved devices are obtained, showing: tight gate resistance (Rgate) distributions down to Lgate˜20 nm, low threshold voltage (VT) values, comparable DC and bias temperature instability (BTI) behavior, and improved RF response. The impact of fill-metals intrinsic stress, including the presence of occasional voids in narrow W-gates, on devices fabrication and performance is also explored.

  16. Coal pump

    DOEpatents

    Bonin, John H.; Meyer, John W.; Daniel, Jr., Arnold D.

    1983-01-01

    A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

  17. Analysis of brokerage feasibility for unit coal train shipments to the Midwest. [Unit train shipment and local distribution

    SciTech Connect

    Knorr, R.; Vezeris, S.; Wilkie, K.

    1980-01-01

    The purpose of this study is to determine the feasibility of aggregating industry and utility demand for coal and serving the demand through a local brokerage operation to reduce transportation cost. This cost saving is associated with the economy of scale of unit train shipments. The delivered price of western coal is calculated for local users in a given midwest subregion based on present utility and industrial coal demand. The broker operation would consist of unit train hauls from western mines, a receiving and storage terminal, local truck or rail transportation from the terminal to each user, and possible transshipment to distant waterfront users. The research focuses on the Green Bay, Wisconsin area. Applicability of this brokerage concept to other areas receiving western coal shipments is also discussed.

  18. Development of a simple measurement scale to evaluate the severity of non-specific low back pain for industrial ergonomics.

    PubMed

    Higuchi, Yoshiyuki; Izumi, Hiroyuki; Kumashiro, Mashaharu

    2010-06-01

    This study developed an assessment scale that hierarchically classifies degrees of low back pain severity. This assessment scale consists of two subscales: 1) pain intensity; 2) pain interference. First, the assessment scale devised by the authors was used to administer a self-administered questionnaire to 773 male workers in the car manufacturing industry. Subsequently, the validity of the measurement items was examined and some of them were revised. Next, the corrected low back pain scale was used in a self-administered questionnaire, the subjects of which were 5053 ordinary workers. The hierarchical validity between the measurement items was checked based on the results of Mokken Scale analysis. Finally, a low back pain assessment scale consisting of seven items was perfected. Quantitative assessment is made possible by scoring the items and low back pain severity can be classified into four hierarchical levels: none; mild; moderate; severe. STATEMENT OF RELEVANCE: The use of this scale devised by the authors allows a more detailed assessment of the degree of risk factor effect and also should prove useful both in selecting remedial measures for occupational low back pain and evaluating their efficacy.

  19. Technical analysis of advanced wastewater-treatment systems for coal-gasification plants

    SciTech Connect

    Not Available

    1981-03-31

    This analysis of advanced wastewater treatment systems for coal gasification plants highlights the three coal gasification demonstration plants proposed by the US Department of Energy: The Memphis Light, Gas and Water Division Industrial Fuel Gas Demonstration Plant, the Illinois Coal Gasification Group Pipeline Gas Demonstration Plant, and the CONOCO Pipeline Gas Demonstration Plant. Technical risks exist for coal gasification wastewater treatment systems, in general, and for the three DOE demonstration plants (as designed), in particular, because of key data gaps. The quantities and compositions of coal gasification wastewaters are not well known; the treatability of coal gasification wastewaters by various technologies has not been adequately studied; the dynamic interactions of sequential wastewater treatment processes and upstream wastewater sources has not been tested at demonstration scale. This report identifies key data gaps and recommends that demonstration-size and commercial-size plants be used for coal gasification wastewater treatment data base development. While certain advanced treatment technologies can benefit from additional bench-scale studies, bench-scale and pilot plant scale operations are not representative of commercial-size facility operation. It is recommended that coal gasification demonstration plants, and other commercial-size facilities that generate similar wastewaters, be used to test advanced wastewater treatment technologies during operation by using sidestreams or collected wastewater samples in addition to the plant's own primary treatment system. Advanced wastewater treatment processes are needed to degrade refractory organics and to concentrate and remove dissolved solids to allow for wastewater reuse. Further study of reverse osmosis, evaporation, electrodialysis, ozonation, activated carbon, and ultrafiltration should take place at bench-scale.

  20. Coal desulfurization

    NASA Technical Reports Server (NTRS)

    Corcoran, William H. (Inventor); Vasilakos, Nicholas P. (Inventor); Lawson, Daniel D. (Inventor)

    1982-01-01

    A method for enhancing solubilizing mass transport of reactive agents into and out of carbonaceous materials, such as coal. Solubility parameters of mass transfer and solvent media are matched to individual peaks in the solubility parameter spectrum of coals to enhance swelling and/or dissolution. Methanol containing reactive agent carriers are found particularly effective for removing organic sulfur from coals by chlorinolysis.

  1. Study of application of ERTS-A imagery to fracture-related mine safety hazards in the coal mining industry. [Indiana

    NASA Technical Reports Server (NTRS)

    Wier, C. E.; Wobber, F. J. (Principal Investigator); Russell, O. R.; Amato, R. V.; Leshendok, T.

    1973-01-01

    The author has identified the following significant results. The Mined Land Inventory map of Pike, Gibson, and Warrick Counties, Indiana, prepared from ERTS-1 imagery, was included in the 1973 Annual Report of the President's Council on Environmental Quality as an example of ERTS applications to mined lands. Increasing numbers of inquiries have been received from coal producing states and coal companies interested in the Indiana Program.

  2. Semiconductor Nanocrystal Quantum Dot Synthesis Approaches Towards Large-Scale Industrial Production for Energy Applications

    NASA Astrophysics Data System (ADS)

    Hu, Michael Z.; Zhu, Ting

    2015-12-01

    This paper reviews the experimental synthesis and engineering developments that focused on various green approaches and large-scale process production routes for quantum dots. Fundamental process engineering principles were illustrated. In relation to the small-scale hot injection method, our discussions focus on the non-injection route that could be scaled up with engineering stir-tank reactors. In addition, applications that demand to utilize quantum dots as "commodity" chemicals are discussed, including solar cells and solid-state lightings.

  3. Semiconductor nanocrystal quantum dot synthesis approaches towards large-scale industrial production for energy applications

    SciTech Connect

    Hu, Michael Z.; Zhu, Ting

    2015-12-04

    This study reviews the experimental synthesis and engineering developments that focused on various green approaches and large-scale process production routes for quantum dots. Fundamental process engineering principles were illustrated. In relation to the small-scale hot injection method, our discussions focus on the non-injection route that could be scaled up with engineering stir-tank reactors. In addition, applications that demand to utilize quantum dots as "commodity" chemicals are discussed, including solar cells and solid-state lightings.

  4. Preventable H5N1 avian influenza epidemics in the British poultry industry network exhibit characteristic scales.

    PubMed

    Jonkers, A R T; Sharkey, K J; Christley, R M

    2010-04-06

    Epidemics are frequently simulated on redundantly wired contact networks, which have many more links between sites than are minimally required to connect all. Consequently, the modelled pathogen can travel numerous alternative routes, complicating effective containment strategies. These networks have moreover been found to exhibit 'scale-free' properties and percolation, suggesting resilience to damage. However, realistic H5N1 avian influenza transmission probabilities and containment strategies, here modelled on the British poultry industry network, show that infection dynamics can additionally express characteristic scales. These system-preferred scales constitute small areas within an observed power law distribution that exhibit a lesser slope than the power law itself, indicating a slightly increased relative likelihood. These characteristic scales are here produced by a network-pervading intranet of so-called hotspot sites that propagate large epidemics below the percolation threshold. This intranet is, however, extremely vulnerable; targeted inoculation of a mere 3-6% (depending on incorporated biosecurity measures) of the British poultry industry network prevents large and moderate H5N1 outbreaks completely, offering an order of magnitude improvement over previously advocated strategies affecting the most highly connected 'hub' sites. In other words, hotspots and hubs are separate functional entities that do not necessarily coincide, and hotspots can make more effective inoculation targets. Given the ubiquity and relevance of networks (epidemics, Internet, power grids, protein interaction), recognition of this spreading regime elsewhere would suggest a similar disproportionate sensitivity to such surgical interventions.

  5. Measuring Interdependency among Industrial Chains with Financial Data

    NASA Astrophysics Data System (ADS)

    Sun, Jingchun; Fang, Ye; Luo, Jing

    Industrial chains exhibit strong interdependency within a large-scale resource-based enterprise group. When analyzing the independency effect in industrial chains, the interdependency of financial index is often ignored. In this paper, we will mainly focus on measuring the long-term interdependency effect by historical simulation and cointegration tests with financial data. A large-scale coal-mining group is studied empirically as a case to explain the framework of independency analysis among the industrial chains. The results show that high degree of independency appears in production costs and marketing costs, and low degree appears in revenues and profits.

  6. Inventory compilation and distribution of heavy metals in wastewater from small-scale industrial areas of Delhi, India.

    PubMed

    Rawat, Manju; Moturi, Mechah Charles Zuriels; Subramanian, Vaidyanathan

    2003-12-01

    Delhi has the highest cluster of small-scale industries (SSI) in India. There are generally less stringent rules for the treatment of waste in SSI due to less waste generation within each individual industry. This results in SSI disposing of their wastewater untreated into drains and subsequently into the river Yamuna, which is a major source of potable water in Delhi, thus posing a potential health and environmental risk to the people living in Delhi and downstream. To study the quantity, quality and distribution of heavy metals in liquid waste from industrial areas, wastewater, suspended materials and bed sediments were collected from industrial areas and from the river Yamuna in Delhi. This study has also focused on the efficiency of production processes in small-scale industries in India. Heavy metals such as Fe, Mn, Cu, Zn, Ni, Cr, Cd, Co and Pb were detected using a GBC 902 atomic absorption spectrometer. The concentration of heavy metals observed was as follows: Fe 2-212, Mn 0.3-39, Cu 0.2-20, Zn 0.2-5, Ni 0.6-6, Cr 0.2-53, Cd 0.08-0.2, Co 0.013-0.55, Pb 0.3-0.7 mg L(-1) in wastewater; Fe 5842-78 000, Mn 585-10 889, Cu 206-7201, Zn 406-9000, Ni 22-3621, Cr 178-10 533, Co 17-114, Cd 13-141, Pb 67-50 171 mg kg(-1) in suspended material; and Fe 3000-84000, Mn 479-1230, Cu 378-8127, Zn 647-4010, Ni 164-1582, Cr 139-3281, Co 20-54, Cd 37-65, Pb 228-293 mg kg(-1) in bed residues. This indicates that SSI could be one of the point sources of metals pollution in the river system.

  7. Rheology of coal-water slurries prepared by the HP roll mill grinding of coal. Quarterly technical progress report No. 1, September 1--November 30, 1992

    SciTech Connect

    Fuerstenau, D.W.

    1992-12-01

    The objective of the research is the development of improved technology for the preparation of coal-water slurries, which have potential for replacing fuel oil in direct combustion. The fine grinding of coal is a crucial step in the manufacture of coal-water slurries. In this context, currently available grinding mills exhibit poor energy efficiency for size reduction and non-optimum packing characteristics of the ground coal. The first increases the cost of manufacture of coal-water slurries and the second adversely affects their rheological properties. The newly invented choke-fed, high-pressure roll mill is up to 50% more energy efficient and, moreover, there are reasons to believe that it produces a size distribution of ground particles which is closer to the dense packing composition. The high-pressure roll mill (which is perhaps the only really significant innovation in industrial comminution in this century) has lower capital cost, occupies less floor space, shows negligible wear rate, accepts feed with a wide range of moisture contents and, of particular importance, it can be scaled up to grind hundreds of tons of solids per hour. The high-pressure roll mill provides a unique opportunity to develop an improved technology for preparing coal-water slurries. Our research group in the University of California at Berkeley not only has a fully instrumented, laboratory-scale, choke-fed. high-pressure roll mill (the only one of its kind in the United States) but also fully instrumented laboratory ball mills for comparative fine coal preparation purposes. In this research program, our plans are to systematically investigate comminution energy consumption, deagglomeration procedures, and the stability and rheology of coal-water slurry fuel prepared with high-pressure roll mill, and to compare the results with slurry prepared with ball-milled coal.

  8. Eleventh annual international Pittsburgh coal conference proceedings: Volume 2

    SciTech Connect

    Chiang, S.H.

    1994-12-31

    The conference presented over 300 papers in 39 separate sessions. These presentations are grouped into five topical areas: the technologies in pre- and post-utilization of coal; research and development in coal conversion; advanced coal combustion; environmental control technologies, and environmental policy issues related to coal use. The program has expanded its coverage in non-fuel use of coal. This is reflected in the three sessions on use of coal in the steel industry, and a sessions on carbon products and non-fuel coal applications. Volume 2 includes the following topics: Environmental systems and technologies/Environmental policy; Coal drying, dewatering and reconstitution; Coal cleaning technology; Slurry bed technology; Coal syngas, methanol, DME, olefins and oxygenates; Environmental issues in energy conversion technology; Applied coal geology; Use of coal in the steel industry; Recent developments in coal preparation; International coal gasification projects; Progress on Clean Coal projects; Retrofit air quality control technologies;Fluidized bed combustion; Commercialization of coal preparation technologies; Integrated gasification combined cycle program; the US Department of Energy`s Combustion 2000 program; and Environmental issues in coal utilization. All papers have been processed separately for inclusion on the data base.

  9. Geographic information system for the management of industrial risks at the subregional scale

    SciTech Connect

    Dusserre, G.; Touraud, E.; Le Cloirec, P.; Citeau, J.M.

    1995-12-31

    Risk assessment and environmental issues are among the most important subjects of research today. In an evaluation process, all sources, vectors and receptors are taken into account in order to achieve a description of territorial risk (infrastructural networks, transportation of hazardous materials, etc.) factors influencing the general evaluation framework. This validated integrated information system allows evaluations of the possible consequences of industrial disasters or spills regarding: new plants and installations, relocation of existing production activities; infrastructural modifications; and general planning activities by using specific models. The system which can be developed from this project would supply information services at several levels: to authorities charged with the control and the management of industrial risk; to managers of hazardous industries; and the information to the population.

  10. A Synergistic Combination of Advanced Separation and Chemical Scale Inhibitor Technologies for Efficient Use of Imparied Water As Cooling Water in Coal-based Power Plants

    SciTech Connect

    Jasbir Gill

    2010-08-30

    Nalco Company is partnering with Argonne National Laboratory (ANL) in this project to jointly develop advanced scale control technologies that will provide cost-effective solutions for coal-based power plants to operate recirculating cooling water systems at high cycles using impaired waters. The overall approach is to use combinations of novel membrane separations and scale inhibitor technologies that will work synergistically, with membrane separations reducing the scaling potential of the cooling water and scale inhibitors extending the safe operating range of the cooling water system. The project started on March 31, 2006 and ended in August 30, 2010. The project was a multiyear, multi-phase project with laboratory research and development as well as a small pilot-scale field demonstration. In Phase 1 (Technical Targets and Proof of Concept), the objectives were to establish quantitative technical targets and develop calcite and silica scale inhibitor chemistries for high stress conditions. Additional Phase I work included bench-scale testing to determine the feasibility of two membrane separation technologies (electrodialysis ED and electrode-ionization EDI) for scale minimization. In Phase 2 (Technology Development and Integration), the objectives were to develop additional novel scale inhibitor chemistries, develop selected separation processes, and optimize the integration of the technology components at the laboratory scale. Phase 3 (Technology Validation) validated the integrated system's performance with a pilot-scale demonstration. During Phase 1, Initial evaluations of impaired water characteristics focused on produced waters and reclaimed municipal wastewater effluents. Literature and new data were collected and evaluated. Characteristics of produced waters vary significantly from one site to another, whereas reclaimed municipal wastewater effluents have relatively more uniform characteristics. Assessment to date confirmed that calcite and silica

  11. Geomorphology of coal seam fires

    NASA Astrophysics Data System (ADS)

    Kuenzer, Claudia; Stracher, Glenn B.

    2012-02-01

    Coal fires occur in underground natural coal seams, in exposed surface seams, and in coal storage or waste piles. The fires ignite through spontaneous combustion or natural or anthropogenic causes. They are reported from China, India, USA, South Africa, Australia, and Russia, as well as many other countries. Coal fires lead to loss of a valuable resource (coal), the emission of greenhouse-relevant and toxic gases, and vegetation deterioration. A dangerous aspect of the fires is the threat to local mines, industries, and settlements through the volume loss underground. Surface collapse in coal fire areas is common. Thus, coal fires are significantly affecting the evolution of the landscape. Based on more than a decade of experience with in situ mapping of coal fire areas worldwide, a general classification system for coal fires is presented. Furthermore, coal seam fire geomorphology is explained in detail. The major landforms associated with, and induced by, these fires are presented. The landforms include manifestations resulting from bedrock surface fracturing, such as fissures, cracks, funnels, vents, and sponges. Further manifestations resulting from surface bedrock subsidence include sinkholes, trenches, depressions, partial surface subsidence, large surface subsidence, and slides. Additional geomorphologic coal fire manifestations include exposed ash layers, pyrometamorphic rocks, and fumarolic minerals. The origin, evolution, and possible future development of these features are explained, and examples from in situ surveys, as well as from high-resolution satellite data analyses, are presented. The geomorphology of coal fires has not been presented in a systematic manner. Knowledge of coal fire geomorphology enables the detection of underground coal fires based on distinct surface manifestations. Furthermore, it allows judgments about the safety of coal fire-affected terrain. Additionally, geomorphologic features are indicators of the burning stage of fires

  12. The development of coal-based technologies for Department of Defense facilities. Semi-annual report, March 28, 1996--September 27, 1996

    SciTech Connect

    Miller, B.G.; Pisupati, S.V.; Scarone, A.W.

    1996-12-13

    The U.S. Department of Defense (DOD), through an Interagency Agreement with the U.S. Department of Energy (DOE), has initiated a three-phase program with the Consortium for Coal-Water Fuel Technology, with the aim of decreasing DOD`s reliance on imported oil by increasing its use of coal. The program is being conducted as a cooperative agreement between the Consortium and DOE. Activities this reporting period are summarized by phase. Phase I was completed on November 1, 1995. Work on Phase II focused on emissions reductions, coal beneficiation/preparation studies, and economic analyses of coal use. Emissions reductions investigations included continuing bench-scale tests to identify an NO{sub x} reduction catalyst which is appropriate for industrial boiler applications. In addition, installation of a ceramic filtering device on the demonstration boiler started. Also, a sodium bicarbonate duct injection system was procured for installation on the demonstration boiler. Work related to coal preparation and utilization, and the economic analysis was primarily focused on preparing the final report. Work in Phase III focused on coal preparation studies and economic analyses of coal use. Coal preparation studies were focused on continuing activities on particle size control, physical separations,surface-based separation processes, and dry processing. The economic study focused on community sensitivity to coal usage, regional/national economic impacts of new coal utilization technologies, and constructing a national energy portfolio.

  13. Pelletization of fine coals. Final report

    SciTech Connect

    Sastry, K.V.S.

    1995-12-31

    Coal is one of the most abundant energy resources in the US with nearly 800 million tons of it being mined annually. Process and environmental demands for low-ash, low-sulfur coals and economic constraints for high productivity are leading the coal industry to use such modern mining methods as longwall mining and such newer coal processing techniques as froth flotation, oil agglomeration, chemical cleaning and synthetic fuel production. All these processes are faced with one common problem area--fine coals. Dealing effectively with these fine coals during handling, storage, transportation, and/or processing continues to be a challenge facing the industry. Agglomeration by the unit operation of pelletization consists of tumbling moist fines in drums or discs. Past experimental work and limited commercial practice have shown that pelletization can alleviate the problems associated with fine coals. However, it was recognized that there exists a serious need for delineating the fundamental principles of fine coal pelletization. Accordingly, a research program has been carried involving four specific topics: (i) experimental investigation of coal pelletization kinetics, (ii) understanding the surface principles of coal pelletization, (iii) modeling of coal pelletization processes, and (iv) simulation of fine coal pelletization circuits. This report summarizes the major findings and provides relevant details of the research effort.

  14. Coal desulfurization by chlorinolysis production and combustion test evaluation of product coals

    NASA Technical Reports Server (NTRS)

    Kalvinskas, J. J.; Daly, D.

    1982-01-01

    Laboratory-scale screening tests were carried out on coal from Harrison County, Ohio to establish chlorination and hydrodesulfurization conditions for the batch reactor production of chlorinolysis and chlorinolysis-hydrodesulfurized coals. In addition, three bituminous coals, were treated on the lab scale by the chlorinolysis process to provide 39 to 62% desulfurization. Two bituminous coals and one subbituminous coal were then produced in 11 to 15 pound lots as chlorinolysis and hydrodesulfurized coals. The chlorinolysis coals had a desulfurization of 29-69%, reductions in voltatiles and hydrogen. Hydrodesulfurization provided a much greater desulfurization (56-86%), reductions in volatiles and hydrogen. The three coals were combustion tested in the Penn State ""plane flame furnace'' to determine ignition and burning characteristics. All three coals burned well to completion as: raw coals, chlorinolysis processed coals, and hydrodesulfurized coals. The hydrodesulfurized coals experienced greater ignition delays and reduced burning rates than the other coals because of the reduced volatile content. It is thought that the increased open pore volume in the desulfurized-devolatilized coals compensates in part for the decreased volatiles effect on ignition and burning.

  15. American coal imports 2015

    SciTech Connect

    Frank Kolojeski

    2007-09-15

    As 2007 ends, the US coal industry passes two major milestones - the ending of the Synfuel tax break, affecting over 100M st annually, and the imposition of tighter and much more expensive safety measures, particularly in deep mines. Both of these issues, arriving at a time of wretched steam coal price levels, promise to result in a major shake up in the Central Appalachian mining sector. The report utilizes a microeconomic regional approach to determine whether either of these two schools of thought have any validity. Transport, infrastructure, competing fuels and regional issues are examined in detail and this forecasts estimates coal demand and imports on a region by region basis for the years 2010 and 2015. Some of the major highlights of the forecast are: Import growth will be driven by steam coal demand in the eastern and southern US; Transport will continue to be the key driver - we believe that inland rail rates will deter imports from being railed far inland and that the great majority of imports will be delivered directly by vessel, barge or truck to end users; Colombian coal will be the overwhelmingly dominant supply source and possesses a costs structure to enable it to compete with US-produced coal in any market conditions; Most of the growth will come from existing power plants - increasing capacity utilization at existing import facilities and other plants making investments to add imports to the supply portfolio - the growth is not dependent upon a lot of new coal fired capacity being built. Contents of the report are: Key US market dynamics; International supply dynamics; Structure of the US coal import market; and Geographic analysis.

  16. The directory of US coal and technology export resources

    SciTech Connect

    Not Available

    1990-10-01

    The purpose of The Directory remains focused on offering a consolidated resource to potential buyers of US coal, coal technology, and expertise. This is consistent with the US policy on coal and coal technology trade, which continues to emphasize export market strategy implementation. Within this context, DOE will continue to support the teaming'' approach to marketing; i.e., vertically integrated large project teams to include multiple industry sectors, such as coal producers, engineering and construction firms, equipment manufacturers, financing and service organizations.

  17. A landscape-scale approach to examining the fate of atmospherically derived industrial metals in the surficial environment.

    PubMed

    Stromsoe, Nicola; Marx, Samuel K; McGowan, Hamish A; Callow, Nikolaus; Heijnis, Henk; Zawadzki, Atun

    2015-02-01

    Industrial metals are now ubiquitous within the atmosphere and their deposition represents a potential source of contamination to surficial environments. Few studies, however, have examined the environmental fate of atmospheric industrial metals within different surface environments. In this study, patterns of accumulation of atmospherically transported industrial metals were investigated within the surface environments of the Snowy Mountains, Australia. Metals, including Pb, Sb, Cr and Mo, were enriched in aerosols collected in the Snowy Mountains by 3.5-50 times pre-industrial concentrations. In sedimentary environments (soils, lakes and reservoirs) metals showed varying degrees of enrichment. Differences were attributed to the relative degree of atmospheric input, metal sensitivity to enrichment, catchment area and metal behaviour following deposition. In settings where atmospheric deposition dominated (ombrotrophic peat mires in the upper parts of catchments), metal enrichment patterns most closely resembled those in collected aerosols. However, even in these environments significant dilution (by 5-7 times) occurred. The most sensitive industrial metals (those with the lowest natural concentration; Cd, Ag, Sb and Mo) were enriched throughout the studied environments. However, in alpine tarn-lakes no other metals were enriched, due to the dilution of pollutant-metals by catchment derived sediment. In reservoirs, which were located lower within catchments, industrial metals exhibited more complex patterns. Particle reactive metals (e.g. Pb) displayed little enrichment, implying that they were retained up catchment, whereas more soluble metals (e.g., Cu and Zn) showed evidence of concentration. These same metals (Cu and Zn) were depleted in soils, implying that they are preferentially transported through catchments. Enrichment of other metals (e.g. Cd) varied between reservoirs as a function of contributing catchment area. Overall this study showed that the fate

  18. Cost evaluation of cellulase enzyme for industrial-scale cellulosic ethanol production based on rigorous Aspen Plus modeling.

    PubMed

    Liu, Gang; Zhang, Jian; Bao, Jie

    2016-01-01

    Cost reduction on cellulase enzyme usage has been the central effort in the commercialization of fuel ethanol production from lignocellulose biomass. Therefore, establishing an accurate evaluation method on cellulase enzyme cost is crucially important to support the health development of the future biorefinery industry. Currently, the cellulase cost evaluation methods were complicated and various controversial or even conflict results were presented. To give a reliable evaluation on this important topic, a rigorous analysis based on the Aspen Plus flowsheet simulation in the commercial scale ethanol plant was proposed in this study. The minimum ethanol selling price (MESP) was used as the indicator to show the impacts of varying enzyme supply modes, enzyme prices, process parameters, as well as enzyme loading on the enzyme cost. The results reveal that the enzyme cost drives the cellulosic ethanol price below the minimum profit point when the enzyme is purchased from the current industrial enzyme market. An innovative production of cellulase enzyme such as on-site enzyme production should be explored and tested in the industrial scale to yield an economically sound enzyme supply for the future cellulosic ethanol production.

  19. The Zambian Wildlife Ranching Industry: Scale, Associated Benefits, and Limitations Affecting Its Development

    PubMed Central

    Lindsey, Peter A.; Barnes, Jonathan; Nyirenda, Vincent; Pumfrett, Belinda; Tambling, Craig J.; Taylor, W. Andrew; Rolfes, Michael t’Sas

    2013-01-01

    The number and area of wildlife ranches in Zambia increased from 30 and 1,420 km2 in 1997 to 177 and ∼6,000 km2 by 2012. Wild ungulate populations on wildlife ranches increased from 21,000 individuals in 1997 to ∼91,000 in 2012, while those in state protected areas declined steeply. Wildlife ranching and crocodile farming have a turnover of ∼USD15.7 million per annum, compared to USD16 million from the public game management areas which encompass an area 29 times larger. The wildlife ranching industry employs 1,200 people (excluding jobs created in support industries), with a further ∼1,000 individuals employed through crocodile farming. Wildlife ranches generate significant quantities of meat (295,000 kg/annum), of which 30,000 kg of meat accrues to local communities and 36,000 kg to staff. Projected economic returns from wildlife ranching ventures are high, with an estimated 20-year economic rate of return of 28%, indicating a strong case for government support for the sector. There is enormous scope for wildlife ranching in Zambia due to the availability of land, high diversity of wildlife and low potential for commercial livestock production. However, the Zambian wildlife ranching industry is small and following completion of field work for this study, there was evidence of a significant proportion of ranchers dropping out. The industry is performing poorly, due to inter alia: rampant commercial bushmeat poaching; failure of government to allocate outright ownership of wildlife to landowners; bureaucratic hurdles; perceived historical lack of support from the Zambia Wildlife Authority and government; a lack of a clear policy on wildlife ranching; and a ban on hunting on unfenced lands including game ranches. For the wildlife ranching industry to develop, these limitations need to be addressed decisively. These findings are likely to apply to other savanna countries with large areas of marginal land potentially suited to wildlife ranching. PMID:24367493

  20. The Zambian wildlife ranching industry: scale, associated benefits, and limitations affecting its development.

    PubMed

    Lindsey, Peter A; Barnes, Jonathan; Nyirenda, Vincent; Pumfrett, Belinda; Tambling, Craig J; Taylor, W Andrew; t'Sas Rolfes, Michael

    2013-01-01

    The number and area of wildlife ranches in Zambia increased from 30 and 1,420 km(2) in 1997 to 177 and ∼6,000 km(2) by 2012. Wild ungulate populations on wildlife ranches increased from 21,000 individuals in 1997 to ∼91,000 in 2012, while those in state protected areas declined steeply. Wildlife ranching and crocodile farming have a turnover of ∼USD15.7 million per annum, compared to USD16 million from the public game management areas which encompass an area 29 times larger. The wildlife ranching industry employs 1,200 people (excluding jobs created in support industries), with a further ∼1,000 individuals employed through crocodile farming. Wildlife ranches generate significant quantities of meat (295,000 kg/annum), of which 30,000 kg of meat accrues to local communities and 36,000 kg to staff. Projected economic returns from wildlife ranching ventures are high, with an estimated 20-year economic rate of return of 28%, indicating a strong case for government support for the sector. There is enormous scope for wildlife ranching in Zambia due to the availability of land, high diversity of wildlife and low potential for commercial livestock production. However, the Zambian wildlife ranching industry is small and following completion of field work for this study, there was evidence of a significant proportion of ranchers dropping out. The industry is performing poorly, due to inter alia: rampant commercial bushmeat poaching; failure of government to allocate outright ownership of wildlife to landowners; bureaucratic hurdles; perceived historical lack of support from the Zambia Wildlife Authority and government; a lack of a clear policy on wildlife ranching; and a