Growth of High-Quality GaAs on Ge by Controlling the Thickness and Growth Temperature of Buffer Layer

NASA Astrophysics Data System (ADS)

Zhou, Xu-Liang; Pan, Jiao-Qing; Yu, Hong-Yan; Li, Shi-Yan; Wang, Bao-Jun; Bian, Jing; Wang, Wei

2014-12-01

High-quality GaAs thin films grown on miscut Ge substrates are crucial for GaAs-based devices on silicon. We investigate the effect of different thicknesses and temperatures of GaAs buffer layers on the crystal quality and surface morphology of GaAs on Ge by metal-organic chemical vapor deposition. Through high resolution x-ray diffraction measurements, it is demonstrated that the full width at half maximum for the GaAs epilayer (Ge substrate) peak could achieve 19.3 (11.0) arcsec. The value of etch pit density could be 4×104 cm-2. At the same time, GaAs surfaces with no pyramid-shaped pits are obtained when the buffer layer growth temperature is lower than 360°C, due to effective inhibition of initial nucleation at terraces of the Ge surface. In addition, it is shown that large island formation at the initial stage of epitaxial growth is a significant factor for the final rough surface and that this initial stage should be carefully controlled when a device quality GaAs surface is desired.

Some wear studies on aircraft brake systems

NASA Technical Reports Server (NTRS)

Ho, T. L.

1975-01-01

An initial investigation of worn surfaces in friction pads and steel rotors used in current aircraft brakes was carried out using electron microprobe and X-ray diffraction analysis. It consists of the topographical study and the analysis of chemical element distribution. Based upon this initial examination, two approaches, microscopic and macroscopic have been conducted to interpret and formulate the wear mechanism of the aircraft brake materials. Microscopically, the wear particles were examined. The initiation and growth of surface cracks and the oxidation were emphasized in this investigation. Macroscopically, it has been found that, for the current copper based brake material sliding against 17-22 AS steel in a caliper brake, the surface temperature raised due to frictional heat is nonlinearly proportional to the load applied and slide time with speed at 1750 rpm. The wear of brake materials is then proportional to this temperature and is also a function of the melting temperature for copper.

Multi-model assessment of the impact of soil moisture initialization on mid-latitude summer predictability

NASA Astrophysics Data System (ADS)

Ardilouze, Constantin; Batté, L.; Bunzel, F.; Decremer, D.; Déqué, M.; Doblas-Reyes, F. J.; Douville, H.; Fereday, D.; Guemas, V.; MacLachlan, C.; Müller, W.; Prodhomme, C.

2017-12-01

Land surface initial conditions have been recognized as a potential source of predictability in sub-seasonal to seasonal forecast systems, at least for near-surface air temperature prediction over the mid-latitude continents. Yet, few studies have systematically explored such an influence over a sufficient hindcast period and in a multi-model framework to produce a robust quantitative assessment. Here, a dedicated set of twin experiments has been carried out with boreal summer retrospective forecasts over the 1992-2010 period performed by five different global coupled ocean-atmosphere models. The impact of a realistic versus climatological soil moisture initialization is assessed in two regions with high potential previously identified as hotspots of land-atmosphere coupling, namely the North American Great Plains and South-Eastern Europe. Over the latter region, temperature predictions show a significant improvement, especially over the Balkans. Forecast systems better simulate the warmest summers if they follow pronounced dry initial anomalies. It is hypothesized that models manage to capture a positive feedback between high temperature and low soil moisture content prone to dominate over other processes during the warmest summers in this region. Over the Great Plains, however, improving the soil moisture initialization does not lead to any robust gain of forecast quality for near-surface temperature. It is suggested that models biases prevent the forecast systems from making the most of the improved initial conditions.

Surface design of antibody-immobilized thermoresponsive cell culture dishes for recovering intact cells by low-temperature treatment.

PubMed

Kobayashi, Jun; Hayashi, Masaki; Ohno, Takahiro; Nishi, Masanori; Arisaka, Yoshinori; Matsubara, Yoshinori; Kakidachi, Hiroshi; Akiyama, Yoshikatsu; Yamato, Masayuki; Horii, Akihiro; Okano, Teruo

2014-11-01

Antibody-immobilized thermoresponsive poly(N-isopropylacrylamide-co-2-carboxyisopropylacrylamide) [poly(IPAAm-co-CIPAAm)]-grafted cell culture surfaces were designed to enhance both the initial adhesion of weakly adhering cells and the ability of cells to detach in response to low temperature through the regulation of affinity binding between immobilized antibodies and antigens on the cellular surface. Ty-82 cells and neonatal normal human dermal fibroblasts (NHDFs), which express CD90 on the cell surface, adhered to anti-CD90 antibody-immobilized thermoresponsive surfaces at 37°C, a condition at which the grafted thermoresponsive polymer chains shrank. Adherent Ty-82 cells were detached from the surfaces by lowering the temperature to 20°C and applying external forces, such as pipetting, whereas cultured NHDF sheets spontaneously detached themselves from the surface in response to reduced temperature alone. When the temperature was decreased to 20°C, the swelling of grafted thermoresponsive polymer chains weakened the affinity binding between immobilized antibody and antigen on the cells due to the increasing steric hindrance of the polymer chains around the antigen-recognition site of the immobilized antibodies. No contamination was detected on cells harvested from covalently immobilized antibodies on the culture surfaces by low-temperature treatment, whereas a carryover of the antibody and avidin from the avidin-biotin binding surface was observed. Furthermore, the initial adhesion of adipose tissue-derived cells, which adhere weakly to PIPAAm-grafted surfaces, was enhanced on the antibody-immobilized thermoresponsive surfaces. © 2013 Wiley Periodicals, Inc.

Improving Numerical Weather Predictions of Summertime Precipitation Over the Southeastern U.S. Through a High-Resolution Initialization of the Surface State

NASA Technical Reports Server (NTRS)

Case, Jonathan L.; Kumar, Sujay V.; Krikishen, Jayanthi; Jedlovec, Gary J.

2011-01-01

It is hypothesized that high-resolution, accurate representations of surface properties such as soil moisture and sea surface temperature are necessary to improve simulations of summertime pulse-type convective precipitation in high resolution models. This paper presents model verification results of a case study period from June-August 2008 over the Southeastern U.S. using the Weather Research and Forecasting numerical weather prediction model. Experimental simulations initialized with high-resolution land surface fields from the NASA Land Information System (LIS) and sea surface temperature (SST) derived from the Moderate Resolution Imaging Spectroradiometer (MODIS) are compared to a set of control simulations initialized with interpolated fields from the National Centers for Environmental Prediction 12-km North American Mesoscale model. The LIS land surface and MODIS SSTs provide a more detailed surface initialization at a resolution comparable to the 4-km model grid spacing. Soil moisture from the LIS spin-up run is shown to respond better to the extreme rainfall of Tropical Storm Fay in August 2008 over the Florida peninsula. The LIS has slightly lower errors and higher anomaly correlations in the top soil layer, but exhibits a stronger dry bias in the root zone. The model sensitivity to the alternative surface initial conditions is examined for a sample case, showing that the LIS/MODIS data substantially impact surface and boundary layer properties.

Towards the use of HYCOM in Coupled ENSO Prediction: Assessment of ENSO Skill in Forced Global HYCOM

DTIC Science & Technology

2016-08-10

CICE spun-up state forced with climatological surface atmospheric fluxes. This run was initialized from Generalized Digital Environmental Model4...GDEM4) climatological temperature and salinity. It was configured with 41layers. 2. Global 0.72° HYCOM/CICE forced with NOGAPS for 2003-2012. The same...surface temperature, sea-ice concentration, and precipitation products. It was initialized from Levitus-PHC2 climatology . It was configured with 32 layers

Surface oxidation of GaN(0001): Nitrogen plasma-assisted cleaning for ultrahigh vacuum applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gangopadhyay, Subhashis; Schmidt, Thomas, E-mail: tschmidt@ifp.uni-bremen.de; Kruse, Carsten

The cleaning of metal-organic vapor-phase epitaxial GaN(0001) template layers grown on sapphire has been investigated. Different procedures, performed under ultrahigh vacuum conditions, including degassing and exposure to active nitrogen from a radio frequency nitrogen plasma source have been compared. For this purpose, x-ray photoelectron spectroscopy, reflection high-energy electron diffraction, and scanning tunneling microscopy have been employed in order to assess chemical as well as structural and morphological surface properties. Initial degassing at 600 °C under ultrahigh vacuum conditions only partially eliminates the surface contaminants. In contrast to plasma assisted nitrogen cleaning at temperatures as low as 300 °C, active-nitrogen exposure at temperaturesmore » as high as 700 °C removes the majority of oxide species from the surface. However, extended high-temperature active-nitrogen cleaning leads to severe surface roughening. Optimum results regarding both the removal of surface oxides as well as the surface structural and morphological quality have been achieved for a combination of initial low-temperature plasma-assisted cleaning, followed by a rapid nitrogen plasma-assisted cleaning at high temperature.« less

Estimation of Initial and Response Times of Laser Dew-Point Hygrometer by Measurement Simulation

NASA Astrophysics Data System (ADS)

Matsumoto, Sigeaki; Toyooka, Satoru

1995-10-01

The initial and the response times of the laser dew-point hygrometer were evaluated by measurement simulation. The simulation was based on loop computations of the surface temperature of a plate with dew deposition, the quantity of dew deposited and the intensity of scattered light from the surface at each short interval of measurement. The initial time was defined as the time necessary for the hygrometer to reach a temperature within ±0.5° C of the measured dew point from the start time of measurement, and the response time was also defined for stepwise dew-point changes of +5° C and -5° C. The simulation results are in approximate agreement with the recorded temperature and intensity of scattered light of the hygrometer. The evaluated initial time ranged from 0.3 min to 5 min in the temperature range from 0° C to 60° C, and the response time was also evaluated to be from 0.2 min to 3 min.

Simultaneous droplet impingement dynamics and heat transfer on nano-structured surfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shen, Jian; Graber, Christof; Liburdy, James

This study examines the hydrodynamics and temperature characteristics of distilled deionized water droplets impinging on smooth and nano-structured surfaces using high speed (HS) and infrared (IR) imaging at We = 23.6 and Re = 1593, both based on initial drop impingement parameters. Results for a smooth and nano-structured surface for a range of surface temperatures are compared. Droplet impact velocity, transient spreading diameter and dynamic contact angle are measured. The near surface average droplet fluid temperatures are evaluated for conditions of evaporative cooling and boiling. Also included are surface temperature results using a gold layered IR opaque surface on silicon.more » Four stages of the impingement process are identified: impact, boiling, near constant surface diameter evaporation, and final dry-out. For the boiling conditions there is initial nucleation followed by severe boiling, then near constant diameter evaporation resulting in shrinking of the droplet height. When a critical contact angle is reached during evaporation the droplet rapidly retracts to a smaller diameter reducing the contact area with the surface. This continues as a sequence of retractions until final dry out. The basic trends are the same for all surfaces, but the nano-structured surface has a lower dissipated energy during impact and enhances the heat transfer for evaporative cooling with a 20% shorter time to achieve final dry out. (author)« less

Radical Initiated Hydrosilylation on Silicon Nanocrystal Surfaces: An Evaluation of Functional Group Tolerance and Mechanistic Study.

PubMed

Yang, Zhenyu; Gonzalez, Christina M; Purkait, Tapas K; Iqbal, Muhammad; Meldrum, Al; Veinot, Jonathan G C

2015-09-29

Hydrosilylation is among the most common methods used for modifying silicon surface chemistry. It provides a wide range of surface functionalities and effective passivation of surface sites. Herein, we report a systematic study of radical initiated hydrosilylation of silicon nanocrystal (SiNC) surfaces using two common radical initiators (i.e., 2,2'-azobis(2-methylpropionitrile) and benzoyl peroxide). Compared to other widely applied hydrosilylation methods (e.g., thermal, photochemical, and catalytic), the radical initiator based approach is particle size independent, requires comparatively low reaction temperatures, and yields monolayer surface passivation after short reaction times. The effects of differing functional groups (i.e., alkene, alkyne, carboxylic acid, and ester) on the radical initiated hydrosilylation are also explored. The results indicate functionalization occurs and results in the formation of monolayer passivated surfaces.

Effects of High-Temperature Exposures on the Fatigue Life of Superalloy Udimet(Registered Trademark) 720

NASA Technical Reports Server (NTRS)

Gabb, Timothy P.; Telesman, Jack; Kantzos, Peter T.; Sweeney, Joseph W.; Browning, Paul F.

2002-01-01

The purpose of this study was to examine the effects of extended exposures on the near-surface fatigue resistance of a disk superalloy. Powder metallurgy processed, supersolvus heat-treated Udimet 720 (U720) fatigue specimens were exposed in air at temperatures from 650 to 705 C for 100 hr to over 1000 hr. They were then tested using conventional fatigue tests at 650 C to determine the effects of exposure on fatigue resistance. The exposures reduced life by up to 70% and increased the scatter in life, compared to unexposed levels. Fractographic evaluations indicated the failure mode was shifted by the exposures from internal to surface crack initiations. The increased scatter in life was related to the competition between internal crack initiations at inclusions or large grains producing longer lives, and surface crack initiations at an environmentally affected surface layer producing shorter lives.

Investigation of atomic oxygen-surface interactions related to measurements with dual air density explorer satellites

NASA Technical Reports Server (NTRS)

Wood, B. J.; Ablow, C. M.; Wise, H.

1973-01-01

For a number of candidate materials of construction for the dual air density explorer satellites the rate of oxygen atom loss by adsorption, surface reaction, and recombination was determined as a function of surface and temperature. Plain aluminum and anodized aluminum surfaces exhibit a collisional atom loss probability alpha .01 in the temperature range 140 - 360 K, and an initial sticking probability. For SiO coated aluminum in the same temperature range, alpha .001 and So .001. Atom-loss on gold is relatively rapid alpha .01. The So for gold varies between 0.25 and unity in the temperature range 360 - 140 K.

Molecular beam epitaxial growth and structural characterization of ZnS on (001) GaAs

NASA Technical Reports Server (NTRS)

Benz, R. G., II; Huang, P. C.; Stock, S. R.; Summers, C. J.

1988-01-01

The effect of surface nucleation processes on the quality of ZnS layers grown on (001) GaAs substrates by molecular beam epitaxy is reported. Reflection high energy electron diffraction indicated that nucleation at high temperatures produced more planar surfaces than nucleation at low temperatures, but the crystalline quality as assessed by X-ray double crystal diffractometry is relatively independent of nucleation temperature. A critical factor in layer quality was the initial roughness of the GaAs surfaces.

Experimental evidence for modifying the current physical model for ice accretion on aircraft surfaces

NASA Technical Reports Server (NTRS)

Olsen, W.; Walker, E.

1986-01-01

Closeup movies, still photographs, and other experimental data suggest that the current physical model for ice accretion needs significant modification. At aircraft airspeeds there was no flow of liquid over the surface of the ice after a short initial flow, even at barely subfreezing temperatures. Instead, there were very large stationary drops on the ice surface that lose water from their bottoms by freezing and replenish their liquid by catching the microscopic cloud droplets. This observation disagrees with the existing physical model, which assumes there is a thin liquid film continuously flowing over the ice surface. With no such flow, the freezing-fraction concept of the model fails when a mass balance is performed on the surface water. Rime ice does, as the model predicts, form when the air temperature is low enough to cause the cloud droplets to freeze almost immediately on impact. However, the characteristic shapes of horn-glaze ice or rime ice are primarily caused by the ice shape affecting the airflow locally and consequently the droplet catch and the resulting ice shape. Ice roughness greatly increases the heat transfer coefficient, stops the movement of drops along the surface, and may also affect the airflow initially and thereby the droplet catch. At high subreezing temperatures the initial flow and shedding of surface drops have a large effect on the ice shape. At the incipient freezing limit, no ice forms.

Physical and electrical characterizations of AlGaN/GaN MOS gate stacks with AlGaN surface oxidation treatment

NASA Astrophysics Data System (ADS)

Yamada, Takahiro; Watanabe, Kenta; Nozaki, Mikito; Shih, Hong-An; Nakazawa, Satoshi; Anda, Yoshiharu; Ueda, Tetsuzo; Yoshigoe, Akitaka; Hosoi, Takuji; Shimura, Takayoshi; Watanabe, Heiji

2018-06-01

The impacts of inserting ultrathin oxides into insulator/AlGaN interfaces on their electrical properties were investigated to develop advanced AlGaN/GaN metal–oxide–semiconductor (MOS) gate stacks. For this purpose, the initial thermal oxidation of AlGaN surfaces in oxygen ambient was systematically studied by synchrotron radiation X-ray photoelectron spectroscopy (SR-XPS) and atomic force microscopy (AFM). Our physical characterizations revealed that, when compared with GaN surfaces, aluminum addition promotes the initial oxidation of AlGaN surfaces at temperatures of around 400 °C, followed by smaller grain growth above 850 °C. Electrical measurements of AlGaN/GaN MOS capacitors also showed that, although excessive oxidation treatment of AlGaN surfaces over around 700 °C has an adverse effect, interface passivation with the initial oxidation of the AlGaN surfaces at temperatures ranging from 400 to 500 °C was proven to be beneficial for fabricating high-quality AlGaN/GaN MOS gate stacks.

Molecular dynamics simulation of temperature effects on low energy near-surface cascades and surface damage in Cu

NASA Astrophysics Data System (ADS)

Zhu, Guo; Sun, Jiangping; Guo, Xiongxiong; Zou, Xixi; Zhang, Libin; Gan, Zhiyin

2017-06-01

The temperature effects on near-surface cascades and surface damage in Cu(0 0 1) surface under 500 eV argon ion bombardment were studied using molecular dynamics (MD) method. In present MD model, substrate system was fully relaxed for 1 ns and a read-restart scheme was introduced to save total computation time. The temperature dependence of damage production was calculated. The evolution of near-surface cascades and spatial distribution of adatoms at varying temperature were analyzed and compared. It was found that near-surface vacancies increased with temperature, which was mainly due to the fact that more atoms initially located in top two layers became adatoms with the decrease of surface binding energy. Moreover, with the increase of temperature, displacement cascades altered from channeling-like structure to branching structure, and the length of collision sequence decreased gradually, because a larger portion of energy of primary knock-on atom (PKA) was scattered out of focused chain. Furthermore, increasing temperature reduced the anisotropy of distribution of adatoms, which can be ascribed to that regular registry of surface lattice atoms was changed with the increase of thermal vibration amplitude of surface atoms.

Precursor state of oxygen molecules on the Si(001) surface during the initial room-temperature adsorption

NASA Astrophysics Data System (ADS)

Hwang, Eunkyung; Chang, Yun Hee; Kim, Yong-Sung; Koo, Ja-Yong; Kim, Hanchul

2012-10-01

The initial adsorption of oxygen molecules on Si(001) is investigated at room temperature. The scanning tunneling microscopy images reveal a unique bright O2-induced feature. The very initial sticking coefficient of O2 below 0.04 Langmuir is measured to be ˜0.16. Upon thermal annealing at 250-600 °C, the bright O2-induced feature is destroyed, and the Si(001) surface is covered with dark depressions that seem to be oxidized structures with -Si-O-Si- bonds. This suggests that the observed bright O2-induced feature is an intermediate precursor state that may be either a silanone species or a molecular adsorption structure.

Polymer-Based Protein Engineering: Synthesis and Characterization of Armored, High Graft Density Polymer-Protein Conjugates.

PubMed

Carmali, Sheiliza; Murata, Hironobu; Cummings, Chad; Matyjaszewski, Krzysztof; Russell, Alan J

2017-01-01

Atom transfer radical polymerization (ATRP) from the surface of a protein can generate remarkably dense polymer shells that serve as armor and rationally tune protein function. Using straightforward chemistry, it is possible to covalently couple or display multiple small molecule initiators onto a protein surface. The chemistry is fine-tuned to be sequence specific (if one desires a single targeted site) at controlled density. Once the initiator is anchored on the protein surface, ATRP is used to grow polymers on protein surface, in situ. The technique is so powerful that a single-protein polymer conjugate molecule can contain more than 90% polymer coating by weight. If desired, stimuli-responsive polymers can be "grown" from the initiated sites to prepare enzyme conjugates that respond to external triggers such as temperature or pH, while still maintaining enzyme activity and stability. Herein, we focus mainly on the synthesis of chymotrypsin-polymer conjugates. Control of the number of covalently coupled initiator sites by changing the stoichiometric ratio between enzyme and the initiator during the synthesis of protein-initiator complexes allowed fine-tuning of the grafting density. For example, very high grafting density chymotrypsin conjugates were prepared from protein-initiator complexes to grow the temperature-responsive polymers, poly(N-isopropylacrylamide), and poly[N,N'-dimethyl(methacryloyloxyethyl) ammonium propane sulfonate]. Controlled growth of polymers from protein surfaces enables one to predictably manipulate enzyme kinetics and stability without the need for molecular biology-dependent mutagenesis. © 2017 Elsevier Inc. All rights reserved.

A Modeling and Verification Study of Summer Precipitation Systems Using NASA Surface Initialization Datasets

NASA Technical Reports Server (NTRS)

Jonathan L. Case; Kumar, Sujay V.; Srikishen, Jayanthi; Jedlovec, Gary J.

2010-01-01

One of the most challenging weather forecast problems in the southeastern U.S. is daily summertime pulse-type convection. During the summer, atmospheric flow and forcing are generally weak in this region; thus, convection typically initiates in response to local forcing along sea/lake breezes, and other discontinuities often related to horizontal gradients in surface heating rates. Numerical simulations of pulse convection usually have low skill, even in local predictions at high resolution, due to the inherent chaotic nature of these precipitation systems. Forecast errors can arise from assumptions within parameterization schemes, model resolution limitations, and uncertainties in both the initial state of the atmosphere and land surface variables such as soil moisture and temperature. For this study, it is hypothesized that high-resolution, consistent representations of surface properties such as soil moisture, soil temperature, and sea surface temperature (SST) are necessary to better simulate the interactions between the surface and atmosphere, and ultimately improve predictions of summertime pulse convection. This paper describes a sensitivity experiment using the Weather Research and Forecasting (WRF) model. Interpolated land and ocean surface fields from a large-scale model are replaced with high-resolution datasets provided by unique NASA assets in an experimental simulation: the Land Information System (LIS) and Moderate Resolution Imaging Spectroradiometer (MODIS) SSTs. The LIS is run in an offline mode for several years at the same grid resolution as the WRF model to provide compatible land surface initial conditions in an equilibrium state. The MODIS SSTs provide detailed analyses of SSTs over the oceans and large lakes compared to current operational products. The WRF model runs initialized with the LIS+MODIS datasets result in a reduction in the overprediction of rainfall areas; however, the skill is almost equally as low in both experiments using traditional verification methodologies. Output from object-based verification within NCAR s Meteorological Evaluation Tools reveals that the WRF runs initialized with LIS+MODIS data consistently generated precipitation objects that better matched observed precipitation objects, especially at higher precipitation intensities. The LIS+MODIS runs produced on average a 4% increase in matched precipitation areas and a simultaneous 4% decrease in unmatched areas during three months of daily simulations.

Heat-transfer dynamics during cryogen spray cooling of substrate at different initial temperatures.

PubMed

Jia, Wangcun; Aguilar, Guillermo; Wang, Guo-Xiang; Nelson, J Stuart

2004-12-07

Cryogen spray cooling (CSC) is used to minimize the risk of epidermal damage during laser dermatologic therapy. However, the dominant mechanisms of heat transfer during the transient cooling process are incompletely understood. The objective of this study is to elucidate the physics of CSC by measuring the effect of initial substrate temperature (T0) on cooling dynamics. Cryogen was delivered by a straight-tube nozzle onto a skin phantom. A fast-response thermocouple was used to record the phantom temperature changes before, during and after the cryogen spray. Surface heat fluxes (q") and heat-transfer coefficients (h) were computed using an inverse heat conduction algorithm. The maximum surface heat flux (q"max) was observed to increase with T0. The surface temperature corresponding to q"max also increased with T0 but the latter has no significant effect on h. It is concluded that heat transfer between the cryogen spray and skin phantom remains in the nucleate boiling region even if T0 is 80 degrees C.

Shape-Persistent, Thermoresponsive Polypeptide Brushes Prepared by Vapor Deposition Surface-Initiated Ring-Opening Polymerization of α-Amino Acid N -Carboxyanhydrides

DOE PAGES

Shen, Yong; Desseaux, Solenne; Aden, Bethany; ...

2015-04-20

We report that surface-grafting thermoresponsive polymers allows the preparation of thin polymer brush coatings with surface properties that can be manipulated by variation of temperature. In most instances, thermoresponsive polymer brushes are produced using polymers that dehydrate and collapse above a certain temperature. This report presents the preparation and properties of polymer brushes that show thermoresponsive surface properties, yet are shape-persistent in that they do not undergo main chain collapse. The polymer brushes presented here are obtained via vapor deposition surface-initiated ring-opening polymerization (SI-ROP) of γ-di- or tri(ethylene glycol)-modified glutamic acid N-carboxyanhydrides. Vapor deposition SI-ROP of γ-di- or tri(ethylene glycol)-modifiedmore » L- or D-glutamic acid N-carboxyanhydrides affords helical surface-tethered polymer chains that do not show any changes in secondary structure between 10 and 70 °C. QCM-D experiments, however, revealed significant dehydration of poly(γ-(2-(2-methoxyethoxy)ethyl)-l-glutamate) (poly(L-EG 2-Glu)) brushes upon heating from 10 to 40 °C. At the same time, AFM and ellipsometry studies did not reveal significant variations in film thickness over this temperature range, which is consistent with the shape-persistent nature of these polypeptide brushes and indicates that the thermoresponsiveness of the films is primarily due to hydration and dehydration of the oligo(ethylene glycol) side chains. The results we present here illustrate the potential of surface-initiated NCA ring-opening polymerization to generate densely grafted assemblies of polymer chains that possess well-defined secondary structures and tunable surface properties. These polypeptide brushes complement their conformationally unordered counterparts that can be generated via surface-initiated polymerization of vinyl-type monomers and represent another step forward to biomimetic surfaces and interfaces.« less

Effects of High Temperature Exposures on Fatigue Life of Disk Superalloys

NASA Technical Reports Server (NTRS)

Gabb, Tim P.; Telesman, Jack; Kantzos, Pete T.; Smith, James W.; Browning, Paul F.

2004-01-01

The effects on fatigue life of high temperature exposures simulating service conditions were considered for two disk superalloys. Powder metallurgy processed, supersolvus heat treated Udimet (trademark) 720 and ME3 fatigue specimens were exposed in air at temperatures of 650 to 704 C, for times of 100 h to over 1000 h. They were then tested using conventional fatigue tests at 650 and 704 C, to determine the effects of exposure on fatigue resistance. Cyclic dwell verification tests were also performed to contrast the effects of intermixed exposures and fatigue cycles. The prior exposures reduced life by up to 70% and increased the scatter in life, compared to unexposed levels. Cyclic dwell tests reduced lives even more. Fractographic evaluations indicated the failure mode was shifted by the exposures and cyclic dwells from predominantly internal to often surface crack initiations. The increased scatter in life was related to the competition between internal crack initiations at inclusions or large grains producing longer lives, and surface crack initiations at an environmentally affected surface layer producing shorter lives.

Adhesive Viscoelastic Response to Surfaces with Tailored Surface Chemistry

DTIC Science & Technology

2008-12-01

represents the minimum energy where failure occurs. This term (measured at low rates and high temperatures to minimize viscoelastic effects ) is...temperature effects described by Williams-Landel-Ferry (WLF) behavior. In this work, we present initial attempts to correlate interfacial bonding and...either 3-methacryloxypropyltrimethoxysilane 97% (MPS, Avocado Research Chemicals Ltd) or n- propyltrimethoxysilane (PTMO, Degussa Corporation). Each

Laser ablation based fuel ignition

DOEpatents

Early, J.W.; Lester, C.S.

1998-06-23

There is provided a method of fuel/oxidizer ignition comprising: (a) application of laser light to a material surface which is absorptive to the laser radiation; (b) heating of the material surface with the laser light to produce a high temperature ablation plume which emanates from the heated surface as an intensely hot cloud of vaporized surface material; and (c) contacting the fuel/oxidizer mixture with the hot ablation cloud at or near the surface of the material in order to heat the fuel to a temperature sufficient to initiate fuel ignition. 3 figs.

Laser ablation based fuel ignition

DOEpatents

Early, James W.; Lester, Charles S.

1998-01-01

There is provided a method of fuel/oxidizer ignition comprising: (a) application of laser light to a material surface which is absorptive to the laser radiation; (b) heating of the material surface with the laser light to produce a high temperature ablation plume which emanates from the heated surface as an intensely hot cloud of vaporized surface material; and (c) contacting the fuel/oxidizer mixture with the hot ablation cloud at or near the surface of the material in order to heat the fuel to a temperature sufficient to initiate fuel ignition.

Initial fuel temperature effects on burning rate of pool fire.

PubMed

Chen, Bing; Lu, Shou-Xiang; Li, Chang-Hai; Kang, Quan-Sheng; Lecoustre, Vivien

2011-04-15

The influence of the initial fuel temperature on the burning behavior of n-heptane pool fire was experimentally studied at the State Key Laboratory of Fire Science (SKLFS) large test hall. Circular pool fires with diameters of 100mm, 141 mm, and 200 mm were considered with initial fuel temperatures ranging from 290 K to 363 K. Burning rate and temperature distributions in fuel and vessel wall were recorded during the combustion. The burning rate exhibited five typical stages: initial development, steady burning, transition, bulk boiling burning, and decay. The burning rate during the steady burning stage was observed to be relatively independent of the initial fuel temperature. In contrast, the burning rate of the bulk boiling burning stage increases with increased initial fuel temperature. It was also observed that increased initial fuel temperature decreases the duration of steady burning stage. When the initial temperature approaches the boiling point, the steady burning stage nearly disappears and the burning rate moves directly from the initial development stage to the transition stage. The fuel surface temperature increases to its boiling point at the steady burning stage, shortly after ignition, and the bulk liquid reaches boiling temperature at the bulk boiling burning stage. No distinguished cold zone is formed in the fuel bed. However, boiling zone is observed and the thickness increases to its maximum value when the bulk boiling phenomena occurs. Copyright © 2011 Elsevier B.V. All rights reserved.

The influence of initial and surface boundary conditions on a model-generated January climatology

NASA Technical Reports Server (NTRS)

Wu, K. F.; Spar, J.

1981-01-01

The influence on a model-generated January climate of various surface boundary conditions, as well as initial conditions, was studied by using the GISS coarse-mesh climate model. Four experiments - two with water planets, one with flat continents, and one with mountains - were used to investigate the effects of initial conditions, and the thermal and dynamical effects of the surface on the model generated-climate. However, climatological mean zonal-symmetric sea surface temperature is used in all four runs over the model oceans. Moreover, zero ground wetness and uniform ground albedo except for snow are used in the last experiments.

Method for solving the problem of nonlinear heating a cylindrical body with unknown initial temperature

NASA Astrophysics Data System (ADS)

Yaparova, N.

2017-10-01

We consider the problem of heating a cylindrical body with an internal thermal source when the main characteristics of the material such as specific heat, thermal conductivity and material density depend on the temperature at each point of the body. We can control the surface temperature and the heat flow from the surface inside the cylinder, but it is impossible to measure the temperature on axis and the initial temperature in the entire body. This problem is associated with the temperature measurement challenge and appears in non-destructive testing, in thermal monitoring of heat treatment and technical diagnostics of operating equipment. The mathematical model of heating is represented as nonlinear parabolic PDE with the unknown initial condition. In this problem, both the Dirichlet and Neumann boundary conditions are given and it is required to calculate the temperature values at the internal points of the body. To solve this problem, we propose the numerical method based on using of finite-difference equations and a regularization technique. The computational scheme involves solving the problem at each spatial step. As a result, we obtain the temperature function at each internal point of the cylinder beginning from the surface down to the axis. The application of the regularization technique ensures the stability of the scheme and allows us to significantly simplify the computational procedure. We investigate the stability of the computational scheme and prove the dependence of the stability on the discretization steps and error level of the measurement results. To obtain the experimental temperature error estimates, computational experiments were carried out. The computational results are consistent with the theoretical error estimates and confirm the efficiency and reliability of the proposed computational scheme.

Plasma Assisted Ignition and Combustion at Low Initial Gas Temperatures: Development of Kinetic Mechanism

DTIC Science & Technology

2016-10-05

describes physics of a nanosecond surface dielectric barrier discharge (SDBD) at ambient gas temperature and high pressures (1-6 bar) in air. Details about...the ignition by a nanosecond discharge. Chapter 7 presents the high pressure high temperature reactor built recently at Laboratory for Plasma Physics ...livelink.ebs.afrl.af.mil/livelink/llisapi.dll Laboratory for Physics of Plasma, Ecole Polytechnique Plasma Assisted Ignition and Combustion at Low Initial Gas

Atmospheric response to anomalous autumn surface forcing in the Arctic Basin

NASA Astrophysics Data System (ADS)

Cassano, Elizabeth N.; Cassano, John J.

2017-09-01

Data from four reanalyses are analyzed to evaluate the downstream atmospheric response both spatially and temporally to anomalous autumn surface forcing in the Arctic Basin. Running weekly mean skin temperature anomalies were classified using the self-organizing map algorithm. The resulting classes were used to both composite the initial atmospheric state and determine how the atmosphere evolves from this state. The strongest response was to anomalous forcing—positive skin temperature and total surface energy flux anomalies and reduced sea ice concentration—in the Barents and Kara Seas. Analysis of the evolution of the atmospheric state for 12 weeks after the initial forcing showed a persistence in the anomalies in this area which led to a buildup of heat in the atmosphere. This resulted in positive 1000-500 hPa thickness and high-pressure circulation anomalies in this area which were associated with cold air advection and temperatures over much of central and northern Asia. Evaluation of days with the opposite forcing (i.e., negative skin temperature anomalies and increased sea ice concentration in the Barents and Kara Seas) showed a mirrored, opposite downstream atmospheric response. Other patterns with positive skin temperature anomalies in the Arctic Basin did not show the same response most likely because the anomalies were not as strong nor did they persist for as many weeks following the initial forcing.

Toward Improved Land Surface Initialization in Support of Regional WRF Forecasts at the Kenya Meteorological Service (KMS)

NASA Technical Reports Server (NTRS)

Case, Jonathan L.; Mungai, John; Sakwa, Vincent; Kabuchanga, Eric; Zavodsky, Bradley T.; Limaye, Ashutosh S.

2014-01-01

SPoRT/SERVIR/RCMRD/KMS Collaboration: Builds off strengths of each organization. SPoRT: Transition of satellite, modeling and verification capabilities; SERVIR-Africa/RCMRD: International capacity-building expertise; KMS: Operational organization with regional weather forecasting expertise in East Africa. Hypothesis: Improved land-surface initialization over Eastern Africa can lead to better temperature, moisture, and ultimately precipitation forecasts in NWP models. KMS currently initializes Weather Research and Forecasting (WRF) model with NCEP/Global Forecast System (GFS) model 0.5-deg initial / boundary condition data. LIS will provide much higher-resolution land-surface data at a scale more representative to regional WRF configuration. Future implementation of real-time NESDIS/VIIRS vegetation fraction to further improve land surface representativeness.

Nucleation and initial radius of self-catalyzed III-V nanowires

NASA Astrophysics Data System (ADS)

Dubrovskii, V. G.; Borie, S.; Dagnet, T.; Reynes, L.; André, Y.; Gil, E.

2017-02-01

We treat theoretically the initial nucleation step of self-catalyzed III-V nanowires under simultaneously deposited group III and V vapor fluxes and with surface diffusion of a group III element. Our model is capable of describing the droplet size at which the very first nanowire monolayer nucleates depending on the element fluxes and surface temperature. This size determines the initial nanowire radius in growth techniques without pre-deposition of gallium. We show that useful self-catalyzed III-V nanowires can form only under the appropriately balanced V/III flux ratios and temperatures. Such balance is required to obtain nucleation from reasonably sized droplets that are neither too small under excessive arsenic flux nor too large in the arsenic-poor conditions.

Linear dependence of surface expansion speed on initial plasma temperature in warm dense matter

DOE PAGES

Bang, Woosuk; Albright, Brian James; Bradley, Paul Andrew; ...

2016-07-12

Recent progress in laser-driven quasi-monoenergetic ion beams enabled the production of uniformly heated warm dense matter. Matter heated rapidly with this technique is under extreme temperatures and pressures, and promptly expands outward. While the expansion speed of an ideal plasma is known to have a square-root dependence on temperature, computer simulations presented here show a linear dependence of expansion speed on initial plasma temperature in the warm dense matter regime. The expansion of uniformly heated 1–100 eV solid density gold foils was modeled with the RAGE radiation-hydrodynamics code, and the average surface expansion speed was found to increase linearly withmore » temperature. The origin of this linear dependence is explained by comparing predictions from the SESAME equation-of-state tables with those from the ideal gas equation-of-state. In conclusion, these simulations offer useful insight into the expansion of warm dense matter and motivate the application of optical shadowgraphy for temperature measurement.« less

The effects of temperature on the surface resistivity of polyvinyl alcohol (PVA) thin films doped with silver nanoparticles and multi-walled carbon-nanotubes for optoelectronic and sensor applications

NASA Astrophysics Data System (ADS)

Polius, Jemilia R.

This thesis reports measurements of the temperature-dependent surface resistivity of multi-wall carbon nanotube doped polyvinyl alcohol (PVA) thin films. In the temperature range from 22°C to 40°C in a humidity controlled environment, it was found that the surface resistivity decreased initially but raised as the temperature continued to increase. I report surface resistivity measurements as a function of temperature of both multiwall and single-wall carbon nanotube doped PVA thin films, with comparison of the similarities and differences between the two types of film types. This research was conducted using the combined instrumentation of the KEITHLEY Model 6517 Electrometer and the KEITHLEY Model 8009 resistivity test fixture using both commercial and in-house produced organic thin films.

[Properties of maize stalk biochar produced under different pyrolysis temperatures and its sorption capability to naphthalene].

PubMed

Huang, Hua; Wang, Ya-Xiong; Tang, Jing-Chun; Tang, Jing-Chun; Zhu, Wen-Ying

2014-05-01

Biochar was made from maize stalk under three different temperatures of 300, 500 and 700 degreeC. The elemental composition of biochar was measured by elemental analyzer. Scanning electron microscope (SEM) was used to measure the surface morphology. Sorption of naphthalene to biochar was researched by batch sorption experiments. Results showed that, with the increase of temperature, C content increased from 66. 79% to 76. 30% , H and O contents decreased from 4.92% and 19. 25% to 3. 18% and 9.53%, respectively; H/C, O/C, (O + N)/C, aromaticity and hydrophobicity increased, and polarity decreased. SEM results showed that maize stalk biochar was platy particles, and its roughness of surface increased with increasing temperature. The sorption of naphthalene on biochar followed the Lagergren pseudo-second order dynamic sorption model. Initial sorption rate and equilibrium sorption capacity increased as preparation temperatures increased at the same initial concentration of naphthalene. The isotherm sorption behavior can be described by the Freundlich model, which indicated that, as pyrolysis temperature increased, the sorption capacity of biochar increased, and nonlinearity increased first and then decreased. Biochar derived from maize stalk had distinct features when compared with other feedstocks, and its elemental composition, surface features and sorption behaviors were significantly influenced by pyrolysis temperature.

Initialization of Cloud and Radiation in the Florida State University Global Spectral Model

DTIC Science & Technology

1990-01-01

come home." My son will soon learn to throw the football farther and harder. My daughter will have one more guest at her tea parties. I love you all very... Peruvian Current keep the sea surface temperatures cool in this area. The Andes Mountain chain also has cool surface temperatures due to its high

Development of measurement simulation of the laser dew-point hygrometer using an optical fiber cable

NASA Astrophysics Data System (ADS)

Matsumoto, Shigeaki

2005-02-01

In order to improve the initial and the response times of the Laser Dew-Point Hygrometer (LDH), the measurement simulation was developed on the basis of the loop computation of the surface temperature of a gold plate for dew depostition, the quantity of deposited dew and the intensity of scattered light from the surface of the plate at time interval of 5 sec during measurement. A more detailed relationship between the surface temperature of the plate and the cooling current, and the time constant of the integrator in the control circuit of the LDH were introduced in the simulation program as a function of atmospheric temperature. The simulation was more close to the actual measurement by the LDH. The simulation results indicated the possibility of improving both the times of teh LDH by the increase of the sensitivity of dew and that of the mass transfer coefficient of dew deposited on the plate surface. It was concluded that the initial and the response times could be improved to below 100sec and 120 sec, respectively in the dew-point range at room temperature, that are almost half of the those times of the original LDH.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shen, Yong; Desseaux, Solenne; Aden, Bethany

We report that surface-grafting thermoresponsive polymers allows the preparation of thin polymer brush coatings with surface properties that can be manipulated by variation of temperature. In most instances, thermoresponsive polymer brushes are produced using polymers that dehydrate and collapse above a certain temperature. This report presents the preparation and properties of polymer brushes that show thermoresponsive surface properties, yet are shape-persistent in that they do not undergo main chain collapse. The polymer brushes presented here are obtained via vapor deposition surface-initiated ring-opening polymerization (SI-ROP) of γ-di- or tri(ethylene glycol)-modified glutamic acid N-carboxyanhydrides. Vapor deposition SI-ROP of γ-di- or tri(ethylene glycol)-modifiedmore » L- or D-glutamic acid N-carboxyanhydrides affords helical surface-tethered polymer chains that do not show any changes in secondary structure between 10 and 70 °C. QCM-D experiments, however, revealed significant dehydration of poly(γ-(2-(2-methoxyethoxy)ethyl)-l-glutamate) (poly(L-EG 2-Glu)) brushes upon heating from 10 to 40 °C. At the same time, AFM and ellipsometry studies did not reveal significant variations in film thickness over this temperature range, which is consistent with the shape-persistent nature of these polypeptide brushes and indicates that the thermoresponsiveness of the films is primarily due to hydration and dehydration of the oligo(ethylene glycol) side chains. The results we present here illustrate the potential of surface-initiated NCA ring-opening polymerization to generate densely grafted assemblies of polymer chains that possess well-defined secondary structures and tunable surface properties. These polypeptide brushes complement their conformationally unordered counterparts that can be generated via surface-initiated polymerization of vinyl-type monomers and represent another step forward to biomimetic surfaces and interfaces.« less

Mississippi Sound remote sensing study. [NASA Earth Resources Laboratory seasonal experiments

NASA Technical Reports Server (NTRS)

Atwell, B. H.; Thomann, G. C.

1973-01-01

A study of the Mississippi Sound was initiated in early 1971 by personnel of NASA Earth Resources Laboratory. Four separate seasonal experiments consisting of quasi-synoptic remote and surface measurements over the entire area were planned. Approximately 80 stations distributed throughout Mississippi Sound were occupied. Surface water temperature and secchi extinction depth were measured at each station and water samples were collected for water quality analyses. The surface distribution of three water parameters of interest from a remote sensing standpoint - temperature, salinity and chlorophyll content - are displayed in map form. Areal variations in these parameters are related to tides and winds. A brief discussion of the general problem of radiative measurements of water temperature is followed by a comparison of remotely measured temperatures (PRT-5) to surface vessel measurements.

Exact analytical solution to a transient conjugate heat-transfer problem

NASA Technical Reports Server (NTRS)

Sucec, J.

1973-01-01

An exact analytical solution is found for laminar, constant-property, slug flow over a thin plate which is also convectively cooled from below. The solution is found by means of two successive Laplace transformations when a transient in the plate and the fluid is initiated by a step change in the fluid inlet temperature. The exact solution yields the transient fluid temperature, surface heat flux, and surface temperature distributions. The results of the exact transient solution for the surface heat flux are compared to the quasi-steady values, and a criterion for the validity of the quasi-steady results is found. Also the effect of the plate coupling parameter on the surface heat flux are investigated.

The Effects of Hot Corrosion Pits on the Fatigue Resistance of a Disk Superalloy

NASA Technical Reports Server (NTRS)

Gabb, Timothy P.; Telesman, Jack; Hazel, Brian; Mourer, David P.

2009-01-01

The effects of hot corrosion pits on low cycle fatigue life and failure modes of the disk superalloy ME3 were investigated. Low cycle fatigue specimens were subjected to hot corrosion exposures producing pits, then tested at low and high temperatures. Fatigue lives and failure initiation points were compared to those of specimens without corrosion pits. Several tests were interrupted to estimate the fraction of fatigue life that fatigue cracks initiated at pits. Corrosion pits significantly reduced fatigue life by 60 to 98 percent. Fatigue cracks initiated at a very small fraction of life for high temperature tests, but initiated at higher fractions in tests at low temperature. Critical pit sizes required to promote fatigue cracking were estimated, based on measurements of pits initiating cracks on fracture surfaces.

Potential Environmental Factors Affecting Oil-Degrading Bacterial Populations in Deep and Surface Waters of the Northern Gulf of Mexico

PubMed Central

Liu, Jiqing; Bacosa, Hernando P.; Liu, Zhanfei

2017-01-01

Understanding bacterial community dynamics as a result of an oil spill is important for predicting the fate of oil released to the environment and developing bioremediation strategies in the Gulf of Mexico. In this study, we aimed to elucidate the roles of temperature, water chemistry (nutrients), and initial bacterial community in selecting oil degraders through a series of incubation experiments. Surface (2 m) and bottom (1537 m) waters, collected near the Deepwater Horizon site, were amended with 200 ppm light Louisiana sweet crude oil and bacterial inoculums from surface or bottom water, and incubated at 4 or 24°C for 50 days. Bacterial community and residual oil were analyzed by pyrosequencing and gas chromatography-mass spectrometry (GC-MS), respectively. The results showed that temperature played a key role in selecting oil-degrading bacteria. Incubation at 4°C favored the development of Cycloclasticus, Pseudoalteromonas, Sulfitobacter, and Reinekea, while 24°C incubations enhanced Oleibacter, Thalassobius, Phaeobacter, and Roseobacter. Water chemistry and the initial community also had potential roles in the development of hydrocarbon-degrading bacterial communities. Pseudoalteromonas, Oleibacter, and Winogradskyella developed well in the nutrient-enriched bottom water, while Reinekea and Thalassobius were favored by low-nutrient surface water. We revealed that the combination of 4°C, crude oil and bottom inoculum was a key factor for the growth of Cycloclasticus, while the combination of surface inoculum and bottom water chemistry was important for the growth of Pseudoalteromonas. Moreover, regardless of the source of inoculum, bottom water at 24°C was a favorable condition for Oleibacter. Redundancy analysis further showed that temperature and initial community explained 57 and 19% of the variation observed, while oil and water chemistry contributed 14 and 10%, respectively. Overall, this study revealed the relative roles of temperature, water chemistry, and initial bacterial community in selecting oil degraders and regulating their evolution in the northern Gulf of Mexico. PMID:28119669

Potential Environmental Factors Affecting Oil-Degrading Bacterial Populations in Deep and Surface Waters of the Northern Gulf of Mexico.

PubMed

Liu, Jiqing; Bacosa, Hernando P; Liu, Zhanfei

2016-01-01

Understanding bacterial community dynamics as a result of an oil spill is important for predicting the fate of oil released to the environment and developing bioremediation strategies in the Gulf of Mexico. In this study, we aimed to elucidate the roles of temperature, water chemistry (nutrients), and initial bacterial community in selecting oil degraders through a series of incubation experiments. Surface (2 m) and bottom (1537 m) waters, collected near the Deepwater Horizon site, were amended with 200 ppm light Louisiana sweet crude oil and bacterial inoculums from surface or bottom water, and incubated at 4 or 24°C for 50 days. Bacterial community and residual oil were analyzed by pyrosequencing and gas chromatography-mass spectrometry (GC-MS), respectively. The results showed that temperature played a key role in selecting oil-degrading bacteria. Incubation at 4°C favored the development of Cycloclasticus, Pseudoalteromonas , Sulfitobacter , and Reinekea , while 24°C incubations enhanced Oleibacter, Thalassobius, Phaeobacter, and Roseobacter. Water chemistry and the initial community also had potential roles in the development of hydrocarbon-degrading bacterial communities. Pseudoalteromonas , Oleibacter , and Winogradskyella developed well in the nutrient-enriched bottom water, while Reinekea and Thalassobius were favored by low-nutrient surface water. We revealed that the combination of 4°C, crude oil and bottom inoculum was a key factor for the growth of Cycloclasticus , while the combination of surface inoculum and bottom water chemistry was important for the growth of Pseudoalteromonas . Moreover, regardless of the source of inoculum, bottom water at 24°C was a favorable condition for Oleibacter. Redundancy analysis further showed that temperature and initial community explained 57 and 19% of the variation observed, while oil and water chemistry contributed 14 and 10%, respectively. Overall, this study revealed the relative roles of temperature, water chemistry, and initial bacterial community in selecting oil degraders and regulating their evolution in the northern Gulf of Mexico.

Influence of anomalous temperature dependence of water density on convection at lateral heating

NASA Astrophysics Data System (ADS)

Bukreev, V. I.; Gusev, A. V.

2012-12-01

The article provides results of experimental investigation of a fresh water motion in a flume with limited dimensions at lateral heating. The initial water temperature in the flume ranged from 0 to 22 °C. It is shown that there are qualitative changes of the motion picture in the vicinity of initial temperature in the flume equal to the one at which water has maximal density (approximately 4 °C). At an initial temperature in the flume exceeding or equal to 4 °C, the heated water propagates in the form of a relatively thin surface jet, and at jet reflection from the flume end walls the heated water is accumulated only in the upper layer. When the initial temperature in the flume is below 4 °C the convective instability develops. A part of the heated water sinks to the bottom. The paper provides respective illustrations and quantitative data on the distribution of temperature and velocity.

Competition between surface adsorption and folding of fibril-forming polypeptides

NASA Astrophysics Data System (ADS)

Ni, Ran; Kleijn, J. Mieke; Abeln, Sanne; Cohen Stuart, Martien A.; Bolhuis, Peter G.

2015-02-01

Self-assembly of polypeptides into fibrillar structures can be initiated by planar surfaces that interact favorably with certain residues. Using a coarse-grained model, we systematically studied the folding and adsorption behavior of a β -roll forming polypeptide. We find that there are two different folding pathways depending on the temperature: (i) at low temperature, the polypeptide folds in solution into a β -roll before adsorbing onto the attractive surface; (ii) at higher temperature, the polypeptide first adsorbs in a disordered state and folds while on the surface. The folding temperature increases with increasing attraction as the folded β -roll is stabilized by the surface. Surprisingly, further increasing the attraction lowers the folding temperature again, as strong attraction also stabilizes the adsorbed disordered state, which competes with folding of the polypeptide. Our results suggest that to enhance the folding, one should use a weakly attractive surface. They also explain the recent experimental observation of the nonmonotonic effect of charge on the fibril formation on an oppositely charged surface [C. Charbonneau et al., ACS Nano 8, 2328 (2014), 10.1021/nn405799t].

Optimization of conditions for thermal smoothing GaAs surfaces

NASA Astrophysics Data System (ADS)

Akhundov, I. O.; Kazantsev, D. M.; Kozhuhov, A. S.; Alperovich, V. L.

2018-03-01

GaAs thermal smoothing by annealing in conditions which are close to equilibrium between the surface and vapors of As and Ga was earlier proved to be effective for the step-terraced surface formation on epi-ready substrates with a small root-mean-square roughness (Rq ≤ 0.15 nm). In the present study, this technique is further developed in order to reduce the annealing duration and to smooth GaAs samples with a larger initial roughness. To this end, we proposed a two-stage anneal with the first high-temperature stage aimed at smoothing "coarse" relief features and the second stage focused on "fine" smoothing at a lower temperature. The optimal temperatures and durations of two-stage annealing are found by Monte Carlo simulations and adjusted after experimentation. It is proved that the temperature and duration of the first high-temperature stage are restricted by the surface roughening, which occurs due to deviations from equilibrium conditions.

Imaging of high-amylose starch tablets. 3. Initial diffusion and temperature effects.

PubMed

Thérien-Aubin, Héloïse; Baille, Wilms E; Zhu, Xiao Xia; Marchessault, Robert H

2005-01-01

The penetration of water into cross-linked high amylose starch tablets was studied at different temperatures by nuclear magnetic resonance (NMR) imaging, which follows the changes occurring at the surface and inside the starch tablets during swelling. It was found that the swelling was anisotropic, whereas water diffusion was almost isotropic. The water proton image profiles at the initial stage of water penetration were used to calculate the initial diffusion coefficient. The swelling and water concentration gradients in this controlled release system show significant temperature dependence. Diffusion behavior changed from Fickian to Case II diffusion with increasing temperature. The observed phenomena are attributed to the gelatinization of starch and the pseudo-cross-linking effect of double helix formation.

Deriving a sea surface temperature record suitable for climate change research from the along-track scanning radiometers

NASA Astrophysics Data System (ADS)

Merchant, C. J.; Llewellyn-Jones, D.; Saunders, R. W.; Rayner, N. A.; Kent, E. C.; Old, C. P.; Berry, D.; Birks, A. R.; Blackmore, T.; Corlett, G. K.; Embury, O.; Jay, V. L.; Kennedy, J.; Mutlow, C. T.; Nightingale, T. J.; O'Carroll, A. G.; Pritchard, M. J.; Remedios, J. J.; Tett, S.

We describe the approach to be adopted for a major new initiative to derive a homogeneous record of sea surface temperature for 1991 2007 from the observations of the series of three along-track scanning radiometers (ATSRs). This initiative is called (A)RC: (Advanced) ATSR Re-analysis for Climate. The main objectives are to reduce regional biases in retrieved sea surface temperature (SST) to less than 0.1 K for all global oceans, while creating a very homogenous record that is stable in time to within 0.05 K decade-1, with maximum independence of the record from existing analyses of SST used in climate change research. If these stringent targets are achieved, this record will enable significantly improved estimates of surface temperature trends and variability of sufficient quality to advance questions of climate change attribution, climate sensitivity and historical reconstruction of surface temperature changes. The approach includes development of new, consistent estimators for SST for each of the ATSRs, and detailed analysis of overlap periods. Novel aspects of the approach include generation of multiple versions of the record using alternative channel sets and cloud detection techniques, to assess for the first time the effect of such choices. There will be extensive effort in quality control, validation and analysis of the impact on climate SST data sets. Evidence for the plausibility of the 0.1 K target for systematic error is reviewed, as is the need for alternative cloud screening methods in this context.

HYTHIRM Radiance Modeling and Image Analyses in Support of STS-119, STS-125 and STS-128 Space Shuttle Hypersonic Re-entries

NASA Technical Reports Server (NTRS)

Gibson, David M.; Spisz, Thomas S.; Taylor, Jeff C.; Zalameda, Joseph N.; Horvath, Thomas J.; Tomek, Deborah M.; Tietjen, Alan B.; Tack, Steve; Bush, Brett C.

2010-01-01

We provide the first geometrically accurate (i.e., 3-D) temperature maps of the entire windward surface of the Space Shuttle during hypersonic reentry. To accomplish this task we began with estimated surface temperatures derived from CFD models at integral high Mach numbers and used them, the Shuttle's surface properties and reasonable estimates of the sensor-to-target geometry to predict the emitted spectral radiance from the surface (in units of W sr-1 m-2 nm-1). These data were converted to sensor counts using properties of the sensor (e.g. aperture, spectral band, and various efficiencies), the expected background, and the atmosphere transmission to inform the optimal settings for the near-infrared and midwave IR cameras on the Cast Glance aircraft. Once these data were collected, calibrated, edited, registered and co-added we formed both 2-D maps of the scene in the above units and 3-D maps of the bottom surface in temperature that could be compared with not only the initial inputs but also thermocouple data from the Shuttle itself. The 3-D temperature mapping process was based on the initial radiance modeling process. Here temperatures were guessed for each node in a well-resolved 3-D framework, a radiance model was produced and compared to the processed imagery, and corrections to the temperature were estimated until the iterative process converged. This process did very well in characterizing the temperature structure of the large asymmetric boundary layer transition the covered much of the starboard bottom surface of STS-119 Discovery. Both internally estimated accuracies and differences with CFD models and thermocouple measurements are at most a few percent. The technique did less well characterizing the temperature structure of the turbulent wedge behind the trip due to limitations in understanding the true sensor resolution. (Note: Those less inclined to read the entire paper are encouraged to read an Executive Summary provided at the end.)

A Limited Comparison of the Thermal Durability of Polyimide Candidate Matrix Polymers with PMR-15

NASA Technical Reports Server (NTRS)

Bowles, Kenneth J.; Papadopoulos, Demetrios S.; Scheiman, Daniel A.; Inghram, Linda L.; McCorkle, Linda S.; Klans, Ojars V.

2003-01-01

Studies were conducted with six different candidate high-temperature neat matrix resin specimens of varied geometric shapes to investigate the mechanisms involved in the thermal degradation of polyimides like PMR-15. The metrics for assessing the quality of these candidates were chosen to be glass transition temperature (T(sub g)), thermo-oxidative stability, dynamic mechanical properties, microstructural changes, and dimensional stability. The processing and mechanical properties were not investigated in the study reported herein. The dimensional changes and surface layer growth were measured and recorded. The data were in agreement with earlier published data. An initial weight increase reaction was observed to be dominating at the lower temperatures. However, at the more elevated temperatures, the weight loss reactions were prevalent and probably masked the weight gain reaction. These data confirmed the findings of the existence of an initial weight gain reaction previously reported. Surface- and core-dependent weight losses were shown to control the polymer degradation at the higher temperatures.

Temperatures of the Ocular Surface, Lid, and Periorbital Regions of Sjögren's, Evaporative, and Aqueous-Deficient Dry Eyes Relative to Normals.

PubMed

Abreau, Kerstin; Callan, Christine; Kottaiyan, Ranjini; Zhang, Aizhong; Yoon, Geunyoung; Aquavella, James V; Zavislan, James; Hindman, Holly B

2016-01-01

To compare the temperatures of the ocular surface, eyelid, and periorbital skin in normal eyes with Sjögren's syndrome (SS) eyes, evaporative dry eyes (EDE), and aqueous deficient dry eyes (ADDE). 10 eyes were analyzed in each age-matched group (normal, SS, EDE, and ADDE). A noninvasive infrared thermal camera captured two-dimensional images in three regions of interest (ROI) in each of three areas: the ocular surface, the upper eyelid, and the periorbital skin within a controlled environmental chamber. Mean temperatures in each ROI were calculated from the videos. Ocular surface time-segmented cooling rates were calculated over a 5-s blink interval. Relative to normal eyes, dry eyes had lower initial central OSTs (SS -0.71°C, EDE -0.55°C, ADDE -0.95°C, KW P<.0001) and lower central upper lid temperatures (SS -0.24°C, ADDE -0.51°C, and EDE -0.54°C, KW P<.0001). ADDE eyes had the lowest initial central OST (P<.0001), while EDE eyes had the lowest central lid temperature and lower periorbital temperatures (P<.0001). Over the 5-s interblink interval, the greatest rate of temperature loss occurred following eyelid opening, but varied by group (normals -0.52, SS -0.73, EDE -0.63, and ADDE -0.75°C/s). The ADDE group also had the most substantial heat loss over the 5-s interblink interval (-0.97°C). Differences in OST may be related to thermal differences in lids and periorbita along with an altered tear film. Thermography of the ocular surface, lids, and surrounding tissues may help to differentiate between different etiologies of dry eye. Copyright © 2016 Elsevier Inc. All rights reserved.

Ocean heat budget analysis on sea surface temperature anomaly in western Indian Ocean during strong-weak Asian summer monsoon

NASA Astrophysics Data System (ADS)

Fathrio, Ibnu; Manda, Atsuyoshi; Iizuka, Satoshi; Kodama, Yasu-Masa; Ishida, Sachinobu

2018-05-01

This study presents ocean heat budget analysis on seas surface temperature (SST) anomalies during strong-weak Asian summer monsoon (southwest monsoon). As discussed by previous studies, there was close relationship between variations of Asian summer monsoon and SST anomaly in western Indian Ocean. In this study we utilized ocean heat budget analysis to elucidate the dominant mechanism that is responsible for generating SST anomaly during weak-strong boreal summer monsoon. Our results showed ocean advection plays more important role to initate SST anomaly than the atmospheric prcess (surface heat flux). Scatterplot analysis showed that vertical advection initiated SST anomaly in western Arabian Sea and southwestern Indian Ocean, while zonal advection initiated SST anomaly in western equatorial Indian Ocean.

Assimilation and High Resolution Forecasts of Surface and Near Surface Conditions for the 2010 Vancouver Winter Olympic and Paralympic Games

NASA Astrophysics Data System (ADS)

Bernier, Natacha B.; Bélair, Stéphane; Bilodeau, Bernard; Tong, Linying

2014-01-01

A dynamical model was experimentally implemented to provide high resolution forecasts at points of interests in the 2010 Vancouver Olympics and Paralympics Region. In a first experiment, GEM-Surf, the near surface and land surface modeling system, is driven by operational atmospheric forecasts and used to refine the surface forecasts according to local surface conditions such as elevation and vegetation type. In this simple form, temperature and snow depth forecasts are improved mainly as a result of the better representation of real elevation. In a second experiment, screen level observations and operational atmospheric forecasts are blended to drive a continuous cycle of near surface and land surface hindcasts. Hindcasts of the previous day conditions are then regarded as today's optimized initial conditions. Hence, in this experiment, given observations are available, observation driven hindcasts continuously ensure that daily forecasts are issued from improved initial conditions. GEM-Surf forecasts obtained from improved short-range hindcasts produced using these better conditions result in improved snow depth forecasts. In a third experiment, assimilation of snow depth data is applied to further optimize GEM-Surf's initial conditions, in addition to the use of blended observations and forecasts for forcing. Results show that snow depth and summer temperature forecasts are further improved by the addition of snow depth data assimilation.

Forced synchronization of large-scale circulation to increase predictability of surface states

NASA Astrophysics Data System (ADS)

Shen, Mao-Lin; Keenlyside, Noel; Selten, Frank; Wiegerinck, Wim; Duane, Gregory

2016-04-01

Numerical models are key tools in the projection of the future climate change. The lack of perfect initial condition and perfect knowledge of the laws of physics, as well as inherent chaotic behavior limit predictions. Conceptually, the atmospheric variables can be decomposed into a predictable component (signal) and an unpredictable component (noise). In ensemble prediction the anomaly of ensemble mean is regarded as the signal and the ensemble spread the noise. Naturally the prediction skill will be higher if the signal-to-noise ratio (SNR) is larger in the initial conditions. We run two ensemble experiments in order to explore a way to reduce the SNR of surface winds and temperature. One ensemble experiment is AGCM with prescribing sea surface temperature (SST); the other is AGCM with both prescribing SST and nudging the high-level temperature and winds to ERA-Interim. Each ensemble has 30 members. Larger SNR is expected and found over the tropical ocean in the first experiment because the tropical circulation is associated with the convection and the associated surface wind convergence as these are to a large extent driven by the SST. However, small SNR is found over high latitude ocean and land surface due to the chaotic and non-synchronized atmosphere states. In the second experiment the higher level temperature and winds are forced to be synchronized (nudged to reanalysis) and hence a larger SNR of surface winds and temperature is expected. Furthermore, different nudging coefficients are also tested in order to understand the limitation of both synchronization of large-scale circulation and the surface states. These experiments will be useful for the developing strategies to synchronize the 3-D states of atmospheric models that can be later used to build a super model.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alkhaldi, H. S.; Department of Physics in Jubail Education college, Dammam University, Dammam 1982; Kremer, F.

The development of porosity in single-crystal germanium and silicon-germanium alloys (c-Si{sub 1−x} Ge{sub x}) of (100) orientation was studied under bombardment with 140 keV Ge{sup −} ions over a wide range of temperatures (−180 to 400 °C) and ion fluences up to 1 × 10{sup 18} ions/cm{sup 2}. The surface swelling and morphology were investigated using multi-characterization techniques including optical profilometry, transmission electron microscopy, and scanning electron microscopy. The initiation of porosity and the evolution of the near-surface microstructure strongly depend on the ion fluence, the irradiation temperature, and the stoichiometry of the substrate. Significant results and new findings include: (i) the fact that,more » over the entire temperature and stoichiometry range, porosity is only developed once the substrate is rendered amorphous; (ii) with increasing Si content in the alloy, the onset of porosity is pushed to higher fluences; (iii) porosity is observed for Si contents in the alloy up to 23% but not higher under the irradiation conditions used; and (iv) in all cases the initiation of porosity was observed to occur at the surface of the amorphous alloy above a threshold fluence. This last result strongly suggests that the mechanism for initiation of porosity is via preferential vacancy segregation and clustering at the surface of the amorphous alloy. Particularly at elevated temperatures, preferential sputtering of the Si-Ge atomic species in the alloy also plays an important role in developing the surface topography and porosity in alloys. Such effects are discussed along with the implications of our results for mechanisms of porosity in Ge and its alloys.« less

A High-Latitude Winter Continental Low Cloud Feedback Suppresses Arctic Air Formation in Warmer Climates

NASA Astrophysics Data System (ADS)

Cronin, T.; Tziperman, E.; Li, H.

2015-12-01

High latitude continents have warmed much more rapidly in recent decades than the rest of the globe, especially in winter, and the maintenance of warm, frost-free conditions in continental interiors in winter has been a long-standing problem of past equable climates. It has also been found that the high-latitude lapse rate feedback plays an important role in Arctic amplification of climate change in climate model simulations, but we have little understanding of why lapse rates at high latitudes change so strongly with warming. To better understand these problems, we study Arctic air formation - the process by which a high-latitude maritime air mass is advected over a continent during polar night, cooled at the surface by radiation, and transformed into a much colder continental polar air mass - and its sensitivity to climate warming. We use a single-column version of the WRF model to conduct two-week simulations of the cooling process across a wide range of initial temperature profiles and microphysics schemes, and find that a low cloud feedback suppresses Arctic air formation in warmer climates. This cloud feedback consists of an increase in low cloud amount with warming, which shields the surface from radiative cooling, and increases the continental surface air temperature by roughly two degrees for each degree increase of the initial maritime surface air temperature. The time it takes for the surface air temperature to drop below freezing increases nonlinearly to ~10 days for initial maritime surface air temperatures of 20 oC. Given that this is about the time it takes an air mass starting over the Pacific to traverse the north American continent, this suggests that optically thick stratus cloud decks could help to maintain frost-free winter continental interiors in equable climates. We find that CMIP5 climate model runs show large increases in cloud water path and surface cloud longwave forcing in warmer climates, consistent with the proposed low-cloud feedback. The suppression of Arctic air formation with warming may act as a significant amplifier of climate change at high latitudes, and offers a mechanistic perspective on the high-latitude "lapse rate feedback" diagnosed in climate models.

Transient nature of Arctic spring systems driven by subglacial meltwater

NASA Astrophysics Data System (ADS)

Scheidegger, J. M.; Bense, V. F.; Grasby, S. E.

2012-06-01

In the High Arctic, supra- and proglacial springs occur at Borup Fiord Pass, Ellesmere Island. Spring waters are sulfur bearing and isotope analysis suggests springs are fed by deeply circulating glacial meltwater. However, the mechanism maintaining spring flow is unclear in these areas of thick permafrost which would hamper the discharge of deep groundwater to the surface. It has been hypothesized that fracture zones along faults focus groundwater which discharges initially underneath wet-based parts of the ice. With thinning ice, the spring head is exposed to surface temperatures, tens of degrees lower than temperatures of pressure melting, and permafrost starts to develop. Numerical modeling of coupled heat and fluid flow suggest that focused groundwater discharge should eventually be cut off by permafrost encroaching into the feeding channel of the spring. Nevertheless, our model simulations show that these springs can remain flowing for millennia depending on the initial flow rate and ambient surface temperature. These systems might provide a terrestrial analog for the possible occurrence of Martian springs recharged by polar ice caps.

Multiscale crack initiator promoted super-low ice adhesion surfaces.

PubMed

He, Zhiwei; Xiao, Senbo; Gao, Huajian; He, Jianying; Zhang, Zhiliang

2017-09-27

Preventing icing on exposed surfaces is important for life and technology. While suppressing ice nucleation by surface structuring and local confinement is highly desirable and yet to be achieved, a realistic roadmap of icephobicity is to live with ice, but with lowest possible ice adhesion. According to fracture mechanics, the key to lower ice adhesion is to maximize crack driving forces at the ice-substrate interface. Herein, we present a novel integrated macro-crack initiator mechanism combining nano-crack and micro-crack initiators, and demonstrate a new approach to designing super-low ice adhesion surfaces by introducing sub-structures into smooth polydimethylsiloxane coatings. Our design promotes the initiation of macro-cracks and enables the reduction of ice adhesion by at least ∼50% regardless of the curing temperature, weight ratio and size of internal holes, reaching a lowest ice adhesion of 5.7 kPa. The multiscale crack initiator mechanisms provide an unprecedented and versatile strategy towards designing super-low ice adhesion surfaces.

Determination of the surface charge density and temperature dependence of purple membrane by electric force microscopy.

PubMed

Du, Huiwen; Li, Denghua; Wang, Yibing; Wang, Chenxuan; Zhang, Dongdong; Yang, Yan-lian; Wang, Chen

2013-08-29

We report here the measurement of the temperature-dependent surface charge density of purple membrane (PM) by using electrostatic force microscopy (EFM). The surface charge density was measured to be 3.4 × 10(5) e/cm(2) at room temperature and reaches the minimum at around 52 °C. The initial decrease of the surface charge density could be attributed to the reduced dipole alignment because of the thermally induced protein mobility in PM. The increase of charge density at higher temperature could be ascribed to the weakened interaction between proteins and the lipids, which leads to the exposure of the charged amino acids. This work could be a benefit to the direct assessment of the structural stability and electric properties of biological membranes at the nanoscale.

An improved hindcast approach for evaluation and diagnosis of physical processes in global climate models

DOE PAGES

Ma, H. -Y.; Chuang, C. C.; Klein, S. A.; ...

2015-11-06

Here, we present an improved procedure of generating initial conditions (ICs) for climate model hindcast experiments with specified sea surface temperature and sea ice. The motivation is to minimize errors in the ICs and lead to a better evaluation of atmospheric parameterizations' performance in the hindcast mode. We apply state variables (horizontal velocities, temperature and specific humidity) from the operational analysis/reanalysis for the atmospheric initial states. Without a data assimilation system, we apply a two-step process to obtain other necessary variables to initialize both the atmospheric (e.g., aerosols and clouds) and land models (e.g., soil moisture). First, we nudge onlymore » the model horizontal velocities towards operational analysis/reanalysis values, given a 6-hour relaxation time scale, to obtain all necessary variables. Compared to the original strategy in which horizontal velocities, temperature and specific humidity are nudged, the revised approach produces a better representation of initial aerosols and cloud fields which are more consistent and closer to observations and model's preferred climatology. Second, we obtain land ICs from an offline land model simulation forced with observed precipitation, winds, and surface fluxes. This approach produces more realistic soil moisture in the land ICs. With this refined procedure, the simulated precipitation, clouds, radiation, and surface air temperature over land are improved in the Day 2 mean hindcasts. Following this procedure, we propose a “Core” integration suite which provides an easily repeatable test allowing model developers to rapidly assess the impacts of various parameterization changes on the fidelity of modelled cloud-associated processes relative to observations.« less

An improved hindcast approach for evaluation and diagnosis of physical processes in global climate models

NASA Astrophysics Data System (ADS)

Ma, H.-Y.; Chuang, C. C.; Klein, S. A.; Lo, M.-H.; Zhang, Y.; Xie, S.; Zheng, X.; Ma, P.-L.; Zhang, Y.; Phillips, T. J.

2015-12-01

We present an improved procedure of generating initial conditions (ICs) for climate model hindcast experiments with specified sea surface temperature and sea ice. The motivation is to minimize errors in the ICs and lead to a better evaluation of atmospheric parameterizations' performance in the hindcast mode. We apply state variables (horizontal velocities, temperature, and specific humidity) from the operational analysis/reanalysis for the atmospheric initial states. Without a data assimilation system, we apply a two-step process to obtain other necessary variables to initialize both the atmospheric (e.g., aerosols and clouds) and land models (e.g., soil moisture). First, we nudge only the model horizontal velocities toward operational analysis/reanalysis values, given a 6 h relaxation time scale, to obtain all necessary variables. Compared to the original strategy in which horizontal velocities, temperature, and specific humidity are nudged, the revised approach produces a better representation of initial aerosols and cloud fields which are more consistent and closer to observations and model's preferred climatology. Second, we obtain land ICs from an off-line land model simulation forced with observed precipitation, winds, and surface fluxes. This approach produces more realistic soil moisture in the land ICs. With this refined procedure, the simulated precipitation, clouds, radiation, and surface air temperature over land are improved in the Day 2 mean hindcasts. Following this procedure, we propose a "Core" integration suite which provides an easily repeatable test allowing model developers to rapidly assess the impacts of various parameterization changes on the fidelity of modeled cloud-associated processes relative to observations.

Recent High Heat Flux Tests on W-Rod-Armored Mockups

DOE Office of Scientific and Technical Information (OSTI.GOV)

NYGREN,RICHARD E.; YOUCHISON,DENNIS L.; MCDONALD,JIMMIE M.

2000-07-18

In the authors initial high heat flux tests on small mockups armored with W rods, done in the small electron beam facility (EBTS) at Sandia National Laboratories, the mockups exhibited excellent thermal performance. However, to reach high heat fluxes, they reduced the heated area to only a portion ({approximately}25%) of the sample. They have now begun tests in their larger electron beam facility, EB 1200, where the available power (1.2 MW) is more than enough to heat the entire surface area of the small mockups. The initial results indicate that, at a given power, the surface temperatures of rods inmore » the EB 1200 tests is somewhat higher than was observed in the EBTS tests. Also, it appears that one mockup (PW-10) has higher surface temperatures than other mockups with similar height (10mm) W rods, and that the previously reported values of absorbed heat flux on this mockup were too high. In the tests in EB 1200 of a second mockup, PW-4, absorbed heat fluxes of {approximately}22MW/m{sup 2} were reached but the corresponding surface temperatures were somewhat higher than in EBTS. A further conclusion is that the simple 1-D model initially used in evaluating some of the results from the EBTS testing was not adequate, and 3-D thermal modeling will be needed to interpret the results.« less

Moderate temperature-dependent surface and volume resistivity and low-frequency dielectric constant measurements of pure and multi-walled carbon nanotube (MWCNT) doped polyvinyl alcohol thin films

NASA Astrophysics Data System (ADS)

Edwards, Matthew; Guggilla, Padmaja; Reedy, Angela; Ijaz, Quratulann; Janen, Afef; Uba, Samuel; Curley, Michael

2017-08-01

Previously, we have reported measurements of temperature-dependent surface resistivity of pure and multi-walled carbon nanotube (MWNCT) doped amorphous Polyvinyl Alcohol (PVA) thin films. In the temperature range from 22 °C to 40 °C with humidity-controlled environment, we found the surface resistivity to decrease initially, but to rise steadily as the temperature continued to increase. Moreover, electric surface current density (Js) was measured on the surface of pure and MWCNT doped PVA thin films. In this regard, the surface current density and electric field relationship follow Ohm's law at low electric fields. Unlike Ohmic conduction in metals where free electrons exist, selected captive electrons are freed or provided from impurities and dopants to become conduction electrons from increased thermal vibration of constituent atoms in amorphous thin films. Additionally, a mechanism exists that seemingly decreases the surface resistivity at higher temperatures, suggesting a blocking effect for conducting electrons. Volume resistivity measurements also follow Ohm's law at low voltages (low electric fields), and they continue to decrease as temperatures increase in this temperature range, differing from surface resistivity behavior. Moreover, we report measurements of dielectric constant and dielectric loss as a function of temperature and frequency. Both the dielectric constant and dielectric loss were observed to be highest for MWCNT doped PVA compared to pure PVA and commercial paper, and with frequency and temperature for all samples.

Full-coverage film cooling. I - Comparison of heat transfer data for three injection angles

NASA Technical Reports Server (NTRS)

Crawford, M. E.; Kays, W. M.; Moffat, R. J.

1980-01-01

Wind tunnel experiments were carried out at Stanford between 1971 and 1977 to study the heat transfer characteristics of full-coverage film cooled surfaces with three geometries; normal-, 30 deg slant-, and 30 deg x 45 deg compound-angled injection. A flat full-coverage section and downstream recovery section comprised the heat transfer system. The experimental objectives were to determine, for each geometry, the effects on surface heat flux of injection blowing ratio, injection temperature ratio, and upstream initial conditions. Spanwise-averaged Stanton numbers were measured for blowing ratios from 0 to 1.3, and for two values of injection temperature at each blowing ratio. The heat transfer coefficient was defined on the basis of a mainstream-to-wall temperature difference. Initial momentum and enthalpy thickness Reynolds numbers were varied from 500 to about 3000.

Evolution of the Specific Surface Area of Snow in a High Temperature Gradient Metamorphism

NASA Astrophysics Data System (ADS)

Wang, X.; Baker, I.

2014-12-01

The structural evolution of low-density snow under a high temperature gradient over a short period usually takes place in the surface layers during diurnal recrystallization or on a clear, cold night. To relate snow microstructures with their thermal properties, we combined X-ray computed microtomography (micro-CT) observations with numerical simulations. Different types of snow were tested over a large range of TGs (100 K m-1- 500 K m-1). The Specific Surface Area (SSA) was used to characterize the temperature gradient metamorphism (TGM). The magnitude of the temperature gradient and the initial snow type both influence the evolution of SSA. The SSA evolution under TGM was dominated by grain growth and the formation of complex surfaces. Fresh snow experienced a logarithmic decrease of SSA with time, a feature been observed previously by others [Calonne et al., 2014; Schneebeli and Sokratov, 2004; Taillandier et al., 2007]. However, for initial rounded and connected snow structures, the SSA will increase during TGM. Understanding the SSA increase is important in order to predict the enhanced uptake of chemical species by snow or increase in snow albedo. Calonne, N., F. Flin, C. Geindreau, B. Lesaffre, and S. Rolland du Roscoat (2014), Study of a temperature gradient metamorphism of snow from 3-D images: time evolution of microstructures, physical properties and their associated anisotropy, The Cryosphere Discussions, 8, 1407-1451, doi:10.5194/tcd-8-1407-2014. Schneebeli, M., and S. A. Sokratov (2004), Tomography of temperature gradient metamorphism of snow and associated changes in heat conductivity, Hydrological Processes, 18(18), 3655-3665, doi:10.1002/hyp.5800. Taillandier, A. S., F. Domine, W. R. Simpson, M. Sturm, and T. A. Douglas (2007), Rate of decrease of the specific surface area of dry snow: Isothermal and temperature gradient conditions, Journal of Geophysical Research: Earth Surface (2003-2012), 112(F3), doi: 10.1029/2006JF000514.

Impact of atmosphere and land surface initial conditions on seasonal forecast of global surface temperature

NASA Astrophysics Data System (ADS)

Materia, Stefano; Borrelli, Andrea; Bellucci, Alessio; Alessandri, Andrea; Di Pietro, Pierluigi; Athanasiadis, Panagiotis; Navarra, Antonio; Gualdi, Silvio

2014-05-01

The impact of land surface and atmosphere initialization on the forecast skill of a seasonal prediction system is investigated, and an effort to disentangle the role played by the individual components to the global predictability is done, via a hierarchy of seasonal forecast experiments performed under different initialization strategies. A realistic atmospheric initial state allows an improved equilibrium between the ocean and overlying atmosphere, mitigating the coupling shock and possibly increasing the model predictive skill in the ocean. In fact, in a few regions characterized by strong air-sea coupling, the atmosphere initial condition affects the forecast skill for several months. In particular, the ENSO region, the eastern tropical Atlantic and the North Pacific benefit significantly from the atmosphere initialization. On mainland, the impact of atmospheric initial conditions is detected in the early phase of the forecast, while the quality of land surface initialization affects the forecast skill in the following lead seasons. The winter forecast in the high latitude plains of Siberia and Canada benefit from the snow initialization, while the impact of soil moisture initial state is particularly effective in the Mediterranean region, in central Asia and Australia. However, initialization through land surface reanalysis does not systematically guarantee an enhancement of the predictive skill: the quality of the forecast is sometimes higher for the non-constrained model. Overall, the introduction of a realistic initialization of land surface and atmosphere substantially increases skill and accuracy. However, further developments in the operating procedure for land surface initialization are required for more accurate seasonal forecasts.

Thermal and UV Hydrosilylation of Alcohol-Based Bifunctional Alkynes on Si (111) surfaces: How surface radicals influence surface bond formation.

PubMed

Khung, Y L; Ngalim, S H; Scaccabarozi, A; Narducci, D

2015-06-12

Using two different hydrosilylation methods, low temperature thermal and UV initiation, silicon (111) hydrogenated surfaces were functionalized in presence of an OH-terminated alkyne, a CF3-terminated alkyne and a mixed equimolar ratio of the two alkynes. XPS studies revealed that in the absence of premeditated surface radical through low temperature hydrosilylation, the surface grafting proceeded to form a Si-O-C linkage via nucleophilic reaction through the OH group of the alkyne. This led to a small increase in surface roughness as well as an increase in hydrophobicity and this effect was attributed to the surficial etching of silicon to form nanosize pores (~1-3 nm) by residual water/oxygen as a result of changes to surface polarity from the grafting. Furthermore in the radical-free thermal environment, a mix in equimolar of these two short alkynes can achieve a high contact angle of ~102°, comparable to long alkyl chains grafting reported in literature although surface roughness was relatively mild (rms = ~1 nm). On the other hand, UV initiation on silicon totally reversed the chemical linkages to predominantly Si-C without further compromising the surface roughness, highlighting the importance of surface radicals determining the reactivity of the silicon surface to the selected alkynes.

Fatigue life assessment of 316L stainless steel and DIN-1.4914 martensitic steel before and after TEXTOR exposure

NASA Astrophysics Data System (ADS)

Shakib, J. I.; Ullmaier, H.; Little, E. A.; Schmitz, W.; Faulkner, R. G.; Chung, T. E.

1992-09-01

The effects of plasma exposure in the TEXTOR tokomak on elevated temperature fatigue lifetime and failure micromechanisms of 316L austenitic stainless steel and DIN 1.4914 martensitic steel (NET reference heats) have been evaluated. Fatigue tests were carried out in vacuum in the temperature range 150°-450°C and compared with data from reference specimens.Plasma-induced surface modifications lead to significant deterioration in fatigue life of 316L steel, whereas the lifetime of 1.4914 steel is unaffected. Fatigue in the 1.4914 steel is surface-initiated only at high stresses. At low stress amplitudes internal fatigue initiation at inclusions was observed.

Characterizing the Diurnal Cycle of Land Surface Temperature and Evapotranspiration at High Spatial Resolution Using Thermal Observations from sUAS.

NASA Astrophysics Data System (ADS)

Dutta, D.; Drewry, D.; Johnson, W. R.

2017-12-01

The surface temperature of plant canopies is an important indicator of the stomatal regulation of plant water use and the associated water flux from plants to atmosphere (evapotranspiration (ET)). Remotely sensed thermal observations using compact, low-cost, lightweight sensors from small unmanned aerial systems (sUAS) have the potential to provide surface temperature (ST) and ET estimates at unprecedented spatial and temporal resolutions, allowing us to characterize the intra-field diurnal variations in canopy ST and ET for a variety of vegetation systems. However, major challenges exist for obtaining accurate surface temperature estimates from low-cost uncooled microbolometer-type sensors. Here we describe the development of calibration methods using thermal chamber experiments, taking into account the ambient optics and sensor temperatures, and applying simple models of spatial non-uniformity correction to the sensor focal-plane-array. We present a framework that can be used to derive accurate surface temperatures using radiometric observations from low-cost sensors, and demonstrate this framework using a sUAS-mounted sensor across a diverse set of calibration and vegetation targets. Further, we demonstrate the use of the Surface Temperature Initiated Closure (STIC) model for computing spatially explicit, high spatial resolution ET estimates across several well-monitored agricultural systems, as driven by sUAS acquired surface temperatures. STIC provides a physically-based surface energy balance framework for the simultaneous retrieval of the surface and atmospheric vapor conductances and surface energy fluxes, by physically integrating radiometric surface temperature information into the Penman-Monteith equation. Results of our analysis over agricultural systems in Ames, IA and Davis, CA demonstrate the power of this approach for quantifying the intra-field spatial variability in the diurnal cycle of plant water use at sub-meter resolutions.

Biogenic isoprene emissions driven by regional weather predictions using different initialization methods: case studies during the SEAC4RS and DISCOVER-AQ airborne campaigns

NASA Astrophysics Data System (ADS)

Huang, Min; Carmichael, Gregory R.; Crawford, James H.; Wisthaler, Armin; Zhan, Xiwu; Hain, Christopher R.; Lee, Pius; Guenther, Alex B.

2017-08-01

Land and atmospheric initial conditions of the Weather Research and Forecasting (WRF) model are often interpolated from a different model output. We perform case studies during NASA's SEAC4RS and DISCOVER-AQ Houston airborne campaigns, demonstrating that using land initial conditions directly downscaled from a coarser resolution dataset led to significant positive biases in the coupled NASA-Unified WRF (NUWRF, version 7) surface and near-surface air temperature and planetary boundary layer height (PBLH) around the Missouri Ozarks and Houston, Texas, as well as poorly partitioned latent and sensible heat fluxes. Replacing land initial conditions with the output from a long-term offline Land Information System (LIS) simulation can effectively reduce the positive biases in NUWRF surface air temperature by ˜ 2 °C. We also show that the LIS land initialization can modify surface air temperature errors almost 10 times as effectively as applying a different atmospheric initialization method. The LIS-NUWRF-based isoprene emission calculations by the Model of Emissions of Gases and Aerosols from Nature (MEGAN, version 2.1) are at least 20 % lower than those computed using the coarser resolution data-initialized NUWRF run, and are closer to aircraft-observation-derived emissions. Higher resolution MEGAN calculations are prone to amplified discrepancies with aircraft-observation-derived emissions on small scales. This is possibly a result of some limitations of MEGAN's parameterization and uncertainty in its inputs on small scales, as well as the representation error and the neglect of horizontal transport in deriving emissions from aircraft data. This study emphasizes the importance of proper land initialization to the coupled atmospheric weather modeling and the follow-on emission modeling. We anticipate it to also be critical to accurately representing other processes included in air quality modeling and chemical data assimilation. Having more confidence in the weather inputs is also beneficial for determining and quantifying the other sources of uncertainties (e.g., parameterization, other input data) of the models that they drive.

Oxidation behavior of a thermal barrier coating

NASA Technical Reports Server (NTRS)

Miller, R. A.

1984-01-01

Thermal barrier coatings, consisting of a plasma sprayed calcium silicate ceramic layer and a CoCrAlY or NiCrAlY bond coat, were applied on B-1900 coupons and cycled hourly in air in a rapid-response furnace to maximum temperatures of 1030, 1100, or 1160 C. Eight specimens were tested for each of the six conditions of bond-coat composition and temperature. Specimens were removed from test at the onset of failure, which was taken to be the formation of a fine surface crack visible at 10X magnification. Specimens were weighed periodically, and plots of weight gain vs time indicate that weight is gained at a parabolic rate after an initial period where weight was gained at a much greater rate. The high initial oxidation rate is thought to arise from the initially high surface area in the porous bond coat. Specimen life (time to first crack) was found to be a strong function of temperature. However, while test lives varied greatly with time, the weight gain at the time of specimen failure was quite insensitive to temperature. This indicates that there is a critical weight gain at which the coating fails when subjected to this test.

Jet array impingement flow distributions and heat transfer characteristics. Effects of initial crossflow and nonuniform array geometry. [gas turbine engine component cooling

NASA Technical Reports Server (NTRS)

Florschuetz, L. W.; Metzger, D. E.; Su, C. C.; Isoda, Y.; Tseng, H. H.

1982-01-01

Two-dimensional arrays of circular air jets impinging on a heat transfer surface parallel to the jet orifice plate are considered. The jet flow, after impingement, is constrained to exit in a single direction along the channel formed by the jet orifice plate and the heat transfer surface. The configurations considered are intended to model those of interest in current and contemplated gas turbine airfoil midchord cooling applications. The effects of an initial crossflow which approaches the array through an upstream extension of the channel are considered. Flow distributions as well as heat transfer coefficients and adiabatic wall temperatures resolved to one streamwise hole spacing were measured as a function of the initial crossflow rate and temperature relative to the jet flow rate and temperature. Both Nusselt number profiles and dimensionless adiabatic wall temperature (effectiveness) profiles are presented and discussed. Special test results which show a significant reduction of jet orifice discharge coefficients owing to the effect of a confined crossflow are also presented, along with a flow distribution model which incorporates those effects. A nonuniform array flow distribution model is developed and validated.

Automated thermal mapping techniques using chromatic image analysis

NASA Technical Reports Server (NTRS)

Buck, Gregory M.

1989-01-01

Thermal imaging techniques are introduced using a chromatic image analysis system and temperature sensitive coatings. These techniques are used for thermal mapping and surface heat transfer measurements on aerothermodynamic test models in hypersonic wind tunnels. Measurements are made on complex vehicle configurations in a timely manner and at minimal expense. The image analysis system uses separate wavelength filtered images to analyze surface spectral intensity data. The system was initially developed for quantitative surface temperature mapping using two-color thermographic phosphors but was found useful in interpreting phase change paint and liquid crystal data as well.

New Phenomena in High Temperature Nanofriction on Nonmelting Surfaces: NaCl(100)

NASA Astrophysics Data System (ADS)

Zykova-Timan, Tatyana; Ceresoli, Davide; Tosatti, Erio

2006-03-01

High temperature nanofriction is a difficult and so far unexplored area whwere we made an initial attack by means of simulation. Alkali halide (100) surfaces were chosen as they would not automatically liquefy under a sliding tip, even at temperatures very close to the melting point. We conducted sliding friction molecular dynamics simulations of hard tips on NaCl(100),both in the heavy ploughing, wear-dominated regime, and in the light grazing, wearless regime. Ploughing friction shows for increasing temperature a strong frictional drop near the melting point. Here the tip can be characterized as ``skating'' over the hot solid, its apex surrounded by a local liquid halo, which moves along with the tip as it ploughs on. At the opposite extreme, we find that grazing friction of a lightly pressed flat-ended tip behaves just the other way around. Starting with an initially very weak low temperature frictional force, there is a surge of friction just near the melting point, where the surface is still solid, but not too far from a vibrational instability. This frictional rise can be envisaged as an analog of the celebrated ``peak effect'' found close to Hc2 in the mixed state critical current of type II superconductors.

Impacts of Initial Soil Moisture and Vegetation on the Diurnal Temperature Range in Arid and Semiarid Regions in China

NASA Astrophysics Data System (ADS)

Yuan, Guanghui; Zhang, Lei; Liang, Jiening; Cao, Xianjie; Guo, Qi; Yang, Zhaohong

2017-11-01

To assess the impacts of initial soil moisture (SMOIS) and the vegetation fraction (Fg) on the diurnal temperature range (DTR) in arid and semiarid regions in China, three simulations using the weather research and forecasting (WRF) model are conducted by modifying the SMOIS, surface emissivity and Fg. SMOIS affects the daily maximum temperature (Tmax) and daily minimum temperature (Tmin) by altering the distribution of available energy between sensible and latent heat fluxes during the day and by altering the surface emissivity at night. Reduced soil wetness can increase both the Tmax and Tmin, but the effect on the DTR is determined by the relative strength of the effects on Tmax and Tmin. Observational data from the Semi-Arid Climate and Environment Observatory of Lanzhou University (SACOL) and the Shapotou Desert Research and Experimental Station (SPD) suggest that the magnitude of the SMOIS effect on the distribution of available energy during the day is larger than that on surface emissivity at night. In other words, SMOIS has a negative effect on the DTR. Changes in Fg modify the surface radiation and the energy budget. Due to the depth of the daytime convective boundary layer, the temperature in daytime is affected less than in nighttime by the radiation and energy budget. Increases in surface emissivity and decreases in soil heating resulting from increased Fg mainly decrease Tmin, thereby increasing the DTR. The effects of SMOIS and Fg on both Tmax and Tmin are the same, but the effects on DTR are the opposite.

Sensitivities of Modeled Tropical Cyclones to Surface Friction and the Coriolis Parameter

NASA Technical Reports Server (NTRS)

Chao, Winston C.; Chen, Baode; Tao, Wei-Kuo; Lau, William K. M. (Technical Monitor)

2002-01-01

In this investigation the sensitivities of a 2-D tropical cyclone (TC) model to surface frictional coefficient and the Coriolis parameter are studied and their implication is discussed. The model used is an axisymmetric version of the latest version of the Goddard cloud ensemble model. The model has stretched vertical grids with 33 levels varying from 30 m near the bottom to 1140 m near the top. The vertical domain is about 21 km. The horizontal domain covers a radius of 962 km (770 grids) with a grid size of 1.25 km. The time step is 10 seconds. An open lateral boundary condition is used. The sea surface temperature is specified at 29C. Unless specified otherwise, the Coriolis parameter is set at its value at 15 deg N. The Newtonian cooling is used with a time scale of 12 hours. The reference vertical temperature profile used in the Newtonian cooling is that of Jordan. The Newtonian cooling models not only the effect of radiative processes but also the effect of processes with scale larger than that of TC. Our experiments showed that if the Newtonian cooling is replaced by a radiation package, the simulated TC is much weaker. The initial condition has a temperature uniform in the radial direction and its vertical profile is that of Jordan. The initial winds are a weak Rankin vortex in the tangential winds superimposed on a resting atmosphere. The initial sea level pressure is set at 1015 hPa everywhere. Since there is no surface pressure perturbation, the initial condition is not in gradient balance. This initial condition is enough to lead to cyclogenesis, but the initial stage (say, the first 24 hrs) is not considered to resemble anything observed. The control experiment reaches quasi-equilibration after about 10 days with an eye wall extending from 15 to 25 km radius, reasonable comparing with the observations. The maximum surface wind of more than 70 m/s is located at about 18 km radius. The minimum sea level pressure on day 10 is about 886 hPa. Thus the overall simulation is considered successful and the model is considered adequate for our investigation.

Senstitivity analysis of horizontal heat and vapor transfer coefficients for a cloud-topped marine boundary layer during cold-air outbreaks. M.S. Thesis

NASA Technical Reports Server (NTRS)

Chang, Y. V.

1986-01-01

The effects of external parameters on the surface heat and vapor fluxes into the marine atmospheric boundary layer (MABL) during cold-air outbreaks are investigated using the numerical model of Stage and Businger (1981a). These fluxes are nondimensionalized using the horizontal heat (g1) and vapor (g2) transfer coefficient method first suggested by Chou and Atlas (1982) and further formulated by Stage (1983a). In order to simplify the problem, the boundary layer is assumed to be well mixed and horizontally homogeneous, and to have linear shoreline soundings of equivalent potential temperature and mixing ratio. Modifications of initial surface flux estimates, time step limitation, and termination conditions are made to the MABL model to obtain accurate computations. The dependence of g1 and g2 in the cloud topped boundary layer on the external parameters (wind speed, divergence, sea surface temperature, radiative sky temperature, cloud top radiation cooling, and initial shoreline soundings of temperature, and mixing ratio) is studied by a sensitivity analysis, which shows that the uncertainties of horizontal transfer coefficients caused by changes in the parameters are reasonably small.

Titan's surface from the Cassini RADAR radiometry data during SAR mode

USGS Publications Warehouse

Paganelli, F.; Janssen, M.A.; Lopes, R.M.; Stofan, E.; Wall, S.D.; Lorenz, R.D.; Lunine, J.I.; Kirk, R.L.; Roth, L.; Elachi, C.

2008-01-01

We present initial results on the calibration and interpretation of the high-resolution radiometry data acquired during the Synthetic Aperture Radar (SAR) mode (SAR-radiometry) of the Cassini Radar Mapper during its first five flybys of Saturn's moon Titan. We construct maps of the brightness temperature at the 2-cm wavelength coincident with SAR swath imaging. A preliminary radiometry calibration shows that brightness temperature in these maps varies from 64 to 89 K. Surface features and physical properties derived from the SAR-radiometry maps and SAR imaging are strongly correlated; in general, we find that surface features with high radar reflectivity are associated with radiometrically cold regions, while surface features with low radar reflectivity correlate with radiometrically warm regions. We examined scatterplots of the normalized radar cross-section ??0 versus brightness temperature, outlining signatures that characterize various terrains and surface features. The results indicate that volume scattering is important in many areas of Titan's surface, particularly Xanadu, while other areas exhibit complex brightness temperature variations consistent with variable slopes or surface material and compositional properties. ?? 2007.

Linking the Local Climate Zones and Land Surface Temperature to Investigate the Surface Urban Heat Island, a Case Study of San Antonio, Texas, U.S.

NASA Astrophysics Data System (ADS)

Zhao, Chunhong

2018-04-01

The Local Climate Zones (LCZs) concept was initiated in 2012 to improve the documentation of Urban Heat Island (UHI) observations. Despite the indispensable role and initial aim of LCZs concept in metadata reporting for atmospheric UHI research, its role in surface UHI investigation also needs to be emphasized. This study incorporated LCZs concept to study surface UHI effect for San Antonio, Texas. LCZ map was developed by a GIS-based LCZs classification scheme with the aid of airborne Lidar dataset and other freely available GIS data. Then, the summer LST was calculated based Landsat imagery, which was used to analyse the relations between LST and LCZs and the statistical significance of the differences of LST among the typical LCZs, in order to test if LCZs are able to efficiently facilitate SUHI investigation. The linkage of LCZs and land surface temperature (LST) indicated that the LCZs mapping can be used to compare and investigate the SUHI. Most of the pairs of LCZs illustrated significant differences in average LSTs with considerable significance. The intra-urban temperature comparison among different urban classes contributes to investigate the influence of heterogeneous urban morphology on local climate formation.

Improved fluid dynamics similarity, analysis and verification. Part 5: Analytical and experimental studies of thermal stratification phenomena

NASA Technical Reports Server (NTRS)

Winter, E. R. F.; Schoenhals, R. J.; Haug, R. I.; Libby, T. L.; Nelson, R. N.; Stevenson, W. H.

1968-01-01

The stratification behavior of a contained fluid subjected to transient free convection heat transfer was studied. A rectangular vessel was employed with heat transfer from two opposite walls of the vessel to the fluid. The wall temperature was increased suddenly to initiate the process and was then maintained constant throughout the transient stratification period. Thermocouples were positioned on a post at the center of the vessel. They were adjusted so that temperatures could be measured at the fluid surface and at specific depths beneath the surface. The predicted values of the surface temperature and the stratified layer thickness were found to agree reasonably well with the experimental measurements. The experiments also provided information on the transient centerline temperature distribution and the transient flow distribution.

Determination of Yield and Flow Surfaces for Inconel 718 Under Axial-Torsional Loading at Temperatures Up to 649 C

NASA Technical Reports Server (NTRS)

Gil, Christopher M.

1998-01-01

An experimental program to determine flow surfaces has been established and implemented for solution annealed and aged IN718. The procedure involved subjecting tubular specimens to various ratios of axial-torsional stress at temperatures between 23 and 649 C and measuring strain with a biaxial extensometer. Each stress probe corresponds to a different direction in stress space, and unloading occurs when a 30 microstrain (1 micro eplison = 10(exp -6) mm/mm) offset is detected. This technique was used to map out yield loci in axial-torsional stress space. Flow surfaces were determined by post-processing the experimental data to determine the inelastic strain rate components. Surfaces of constant inelastic strain rate (SCISRS) and surfaces of constant inelastic power (SCIPS) were mapped out in the axial-shear stress plane. The von Mises yield criterion appeared to closely fit the initial loci for solutioned IN718 at 23 C. However, the initial loci for solutioned IN718 at 371 and 454 C, and all of the initial loci for aged IN718 were offset in the compression direction. Subsequent loci showed translation, distortion, and for the case of solutioned IN718, a slight cross effect. Aged IN718 showed significantly more hardening behavior than solutioned IN718.

Scanning tunneling microscope-quartz crystal microbalance study of temperature gradients at an asperity contact.

PubMed

Pan, L; Krim, J

2013-01-01

Investigations of atomic-scale friction frequently involve setups where a tip and substrate are initially at different temperatures. The temperature of the sliding interface upon contact has thus become a topic of interest. A method for detecting initial tip-sample temperature differences at an asperity contact is described, which consists of a scanning tunneling microscope (STM) tip in contact with the surface electrode of a quartz crystal microbalance (QCM). The technique makes use of the fact that a QCM is extremely sensitive to abrupt changes in temperature. In order to demonstrate the technique's capabilities, QCM frequency shifts were recorded for varying initial tip-substrate temperature differences as an STM tip was brought into and out of contact. The results are interpreted within the context of a recent model for thermal heat conduction at an asperity contact, and it is concluded that the transient frequency response is attributable to small changes in temperature close to the region of contact rather than a change in the overall temperature of the QCM itself. For the assumed model parameters, the results moreover reveal substantial temperature discontinuities at the boundary between the tip and the sample, for example, on the order of 10-15 °C for initial temperature differences of 20 °C.

Scanning tunneling microscope-quartz crystal microbalance study of temperature gradients at an asperity contact

NASA Astrophysics Data System (ADS)

Pan, L.; Krim, J.

2013-01-01

Investigations of atomic-scale friction frequently involve setups where a tip and substrate are initially at different temperatures. The temperature of the sliding interface upon contact has thus become a topic of interest. A method for detecting initial tip-sample temperature differences at an asperity contact is described, which consists of a scanning tunneling microscope (STM) tip in contact with the surface electrode of a quartz crystal microbalance (QCM). The technique makes use of the fact that a QCM is extremely sensitive to abrupt changes in temperature. In order to demonstrate the technique's capabilities, QCM frequency shifts were recorded for varying initial tip-substrate temperature differences as an STM tip was brought into and out of contact. The results are interpreted within the context of a recent model for thermal heat conduction at an asperity contact, and it is concluded that the transient frequency response is attributable to small changes in temperature close to the region of contact rather than a change in the overall temperature of the QCM itself. For the assumed model parameters, the results moreover reveal substantial temperature discontinuities at the boundary between the tip and the sample, for example, on the order of 10-15 °C for initial temperature differences of 20 °C.

Computationally derived rules for persistence of C60 nanowires on recumbent pentacene bilayers.

PubMed

Cantrell, Rebecca A; James, Christine; Clancy, Paulette

2011-08-16

The tendency for C(60) nanowires to persist on two monolayers of recumbent pentacene is studied using molecular dynamics (MD) simulations. A review of existing experimental literature for the tilt angle adopted by pentacene on noble metal surfaces shows that studies cover a limited range from 55° to 90°, motivating simulation studies of essentially the entire range of tilt angles (10°-90°) to predict the optimum surface tilt angle for C(60) nanowire formation. The persistence of a 1D nanowire depends sensitively on this tilt angle, the amount of initial tensile strain, and the presence of surface step edges. At room temperature, C(60) nanowires oriented along the pentacene short axes persist for several nanoseconds and are more likely to occur if they reside between, or within, pentacene rows for ϕ ≤ ∼60°. The likelihood of this persistence increases the smaller the tilt angle. Nanowires oriented along the long axes of pentacene molecules are unlikely to form. The limit of stability of nanowires was tested by raising the temperature to 400 K. Nanowires located between pentacene rows survived this temperature rise, but those located initially within pentacene rows are only stable in the range ϕ(1) = 30°-50°. Flatter pentacene surfaces, that is, tilt angles above about 60°, are subject to disorder caused by C(60) molecules "burrowing" into the pentacene surface. An initial strain of 5% applied to the C(60) nanowires significantly decreases the likelihood of nanowire persistence. In contrast, any appreciable surface roughness, even by half a monolayer in height of a third pentacene monolayer, strongly enhances the likelihood of nanowire formation due to the strong binding energy of C(60) molecules to step edges.

Improved Decadal Climate Prediction in the North Atlantic using EnOI-Assimilated Initial Condition

NASA Astrophysics Data System (ADS)

Li, Q.; Xin, X.; Wei, M.; Zhou, W.

2017-12-01

Decadal prediction experiments of Beijing Climate Center climate system model version 1.1(BCC-CSM1.1) participated in Coupled Model Intercomparison Project Phase 5 (CMIP5) had poor skill in extratropics of the North Atlantic, the initialization of which was done by relaxing modeled ocean temperature to the Simple Ocean Data Assimilation (SODA) reanalysis data. This study aims to improve the prediction skill of this model by using the assimilation technique in the initialization. New ocean data are firstly generated by assimilating the sea surface temperature (SST) of the Hadley Centre Sea Ice and Sea Surface Temperature (HadISST) dataset to the ocean model of BCC-CSM1.1 via Ensemble Optimum Interpolation (EnOI). Then a suite of decadal re-forecasts launched annually over the period 1961-2005 is carried out with simulated ocean temperature restored to the assimilated ocean data. Comparisons between the re-forecasts and previous CMIP5 forecasts show that the re-forecasts are more skillful in mid-to-high latitude SST of the North Atlantic. Improved prediction skill is also found for the Atlantic multi-decadal Oscillation (AMO), which is consistent with the better skill of Atlantic meridional overturning circulation (AMOC) predicted by the re-forecasts. We conclude that the EnOI assimilation generates better ocean data than the SODA reanalysis for initializing decadal climate prediction of BCC-CSM1.1 model.

Response surface methodological approach for the decolorization of simulated dye effluent using Aspergillus fumigatus fresenius.

PubMed

Sharma, Praveen; Singh, Lakhvinder; Dilbaghi, Neeraj

2009-01-30

The aim of our research was to study, effect of temperature, pH and initial dye concentration on decolorization of diazo dye Acid Red 151 (AR 151) from simulated dye solution using a fungal isolate Aspergillus fumigatus fresenius have been investigated. The central composite design matrix and response surface methodology (RSM) have been applied to design the experiments to evaluate the interactive effects of three most important operating variables: temperature (25-35 degrees C), pH (4.0-7.0), and initial dye concentration (100-200 mg/L) on the biodegradation of AR 151. The total 20 experiments were conducted in the present study towards the construction of a quadratic model. Very high regression coefficient between the variables and the response (R(2)=0.9934) indicated excellent evaluation of experimental data by second-order polynomial regression model. The RSM indicated that initial dye concentration of 150 mg/L, pH 5.5 and a temperature of 30 degrees C were optimal for maximum % decolorization of AR 151 in simulated dye solution, and 84.8% decolorization of AR 151 was observed at optimum growth conditions.

Exploring the effect of Al2O3 ALD coating on a high gradient ILC single-cell cavity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grigory Eremeev, Anne-Marie Valente, Andy Wu, Diefeng Gu

2012-07-01

Encouraged by work at Argonne National Lab, we investigated atomic layer deposition technique (ALD) for high gradient superconducting RF cavities at JLab with an ALD coating system of Old Dominion University located on the JLab site. The goal of this study was to look into the possibility of coating a dielectric layer on top of RF niobium surface at a lower temperature of 120 C as compared to ANL coatings at 200 C to preserve niobium pentoxide on niobium surface. The initial coatings showed complete, but non-uniform coatings of the surface with several areas exhibiting discoloration, which was probably duemore » to the temperature variation across the cavity surface. The initial coating showed a high RF losses, which were improved after discolored areas on the beam tubes were removed with HF rinse of the beam tubes only. The best result was 2 109 low field Q0 and Eacc = 18 MV/m limited by available power.« less

Geostatistical Analysis of Surface Temperature and In-Situ Soil Moisture Using LST Time-Series from Modis

NASA Astrophysics Data System (ADS)

Sohrabinia, M.; Rack, W.; Zawar-Reza, P.

2012-07-01

The objective of this analysis is to provide a quantitative estimate of the fluctuations of land surface temperature (LST) with varying near surface soil moisture (SM) on different land-cover (LC) types. The study area is located in the Canterbury Plains in the South Island of New Zealand. Time series of LST from the MODerate resolution Imaging Spectro-radiometer (MODIS) have been analysed statistically to study the relationship between the surface skin temperature and near-surface SM. In-situ measurements of the skin temperature and surface SM with a quasi-experimental design over multiple LC types are used for validation. Correlations between MODIS LST and in-situ SM, as well as in-situ surface temperature and SM are calculated. The in-situ measurements and MODIS data are collected from various LC types. Pearson's r correlation coefficient and linear regression are used to fit the MODIS LST and surface skin temperature with near-surface SM. There was no significant correlation between time-series of MODIS LST and near-surface SM from the initial analysis, however, careful analysis of the data showed significant correlation between the two parameters. Night-time series of the in-situ surface temperature and SM from a 12 hour period over Irrigated-Crop, Mixed-Grass, Forest, Barren and Open- Grass showed inverse correlations of -0.47, -0.68, -0.74, -0.88 and -0.93, respectively. These results indicated that the relationship between near-surface SM and LST in short-terms (12 to 24 hours) is strong, however, remotely sensed LST with higher temporal resolution is required to establish this relationship in such time-scales. This method can be used to study near-surface SM using more frequent LST observations from a geostationary satellite over the study area.

Greenland ice sheet surface temperature, melt and mass loss: 2000-06

USGS Publications Warehouse

Hall, D.K.; Williams, R.S.; Luthcke, S.B.; DiGirolamo, N.E.

2008-01-01

A daily time series of 'clear-sky' surface temperature has been compiled of the Greenland ice sheet (GIS) using 1 km resolution moderate-resolution imaging spectroradiometer (MODIS) land-surface temperature (LST) maps from 2000 to 2006. We also used mass-concentration data from the Gravity Recovery and Climate Experiment (GRACE) to study mass change in relationship to surface melt from 2003 to 2006. The mean LST of the GIS increased during the study period by ???0.27??Ca-1. The increase was especially notable in the northern half of the ice sheet during the winter months. Melt-season length and timing were also studied in each of the six major drainage basins. Rapid (<15 days) and sustained mass loss below 2000 m elevation was triggered in 2004 and 2005 as recorded by GRACE when surface melt begins. Initiation of large-scale surface melt was followed rapidly by mass loss. This indicates that surface meltwater is flowing rapidly to the base of the ice sheet, causing acceleration of outlet glaciers, thus highlighting the metastability of parts of the GIS and the vulnerability of the ice sheet to air-temperature increases. If air temperatures continue to rise over Greenland, increased surface melt will play a large role in ice-sheet mass loss.

Influence of High Cycle Thermal Loads on Thermal Fatigue Behavior of Thick Thermal Barrier Coatings

NASA Technical Reports Server (NTRS)

Zhu, Dongming; Miller, Robert A.

1997-01-01

Thick thermal barrier coating systems in a diesel engine experience severe thermal Low Cycle Fatigue (LCF) and High Cycle Fatigue (HCF) during engine operation. In the present study, the mechanisms of fatigue crack initiation and propagation, as well as of coating failure, under thermal loads which simulate engine conditions, are investigated using a high power CO2 laser. In general, surface vertical cracks initiate early and grow continuously under LCF and HCF cyclic stresses. It is found that in the absence of interfacial oxidation, the failure associated with LCF is closely related to coating sintering and creep at high temperatures, which induce tensile stresses in the coating after cooling. Experiments show that the HCF cycles are very damaging to the coating systems. The combined LCF and HCF tests produced more severe coating surface cracking, microspallation and accelerated crack growth, as compared to the pure LCF test. It is suggested that the HCF component cannot only accelerate the surface crack initiation, but also interact with the LCF by contributing to the crack growth at high temperatures. The increased LCF stress intensity at the crack tip due to the HCF component enhances the subsequent LCF crack growth. Conversely, since a faster HCF crack growth rate will be expected with lower effective compressive stresses in the coating, the LCF cycles also facilitate the HCF crack growth at high temperatures by stress relaxation process. A surface wedging model has been proposed to account for the HCF crack growth in the coating system. This mechanism predicts that HCF damage effect increases with increasing temperature swing, the thermal expansion coefficient and the elastic modulus of the ceramic coating, as well as the HCF interacting depth. A good agreement has been found between the analysis and experimental evidence.

Monthly mean forecast experiments with the GISS model

NASA Technical Reports Server (NTRS)

Spar, J.; Atlas, R. M.; Kuo, E.

1976-01-01

The GISS general circulation model was used to compute global monthly mean forecasts for January 1973, 1974, and 1975 from initial conditions on the first day of each month and constant sea surface temperatures. Forecasts were evaluated in terms of global and hemispheric energetics, zonally averaged meridional and vertical profiles, forecast error statistics, and monthly mean synoptic fields. Although it generated a realistic mean meridional structure, the model did not adequately reproduce the observed interannual variations in the large scale monthly mean energetics and zonally averaged circulation. The monthly mean sea level pressure field was not predicted satisfactorily, but annual changes in the Icelandic low were simulated. The impact of temporal sea surface temperature variations on the forecasts was investigated by comparing two parallel forecasts for January 1974, one using climatological ocean temperatures and the other observed daily ocean temperatures. The use of daily updated sea surface temperatures produced no discernible beneficial effect.

Modeling physical vapor deposition of energetic materials

DOE PAGES

Shirvan, Koroush; Forrest, Eric C.

2018-03-28

Morphology and microstructure of organic explosive films formed using physical vapor deposition (PVD) processes strongly depends on local surface temperature during deposition. Currently, there is no accurate means of quantifying the local surface temperature during PVD processes in the deposition chambers. This study focuses on using a multiphysics computational fluid dynamics tool, STARCCM+, to simulate pentaerythritol tetranitrate (PETN) deposition. The PETN vapor and solid phase were simulated using the volume of fluid method and its deposition in the vacuum chamber on spinning silicon wafers was modeled. The model also included the spinning copper cooling block where the wafers are placedmore » along with the chiller operating with forced convection refrigerant. Implicit time-dependent simulations in two- and three-dimensional were performed to derive insights in the governing physics for PETN thin film formation. PETN is deposited at the rate of 14 nm/s at 142.9 °C on a wafer with an initial temperature of 22 °C. The deposition of PETN on the wafers was calculated at an assumed heat transfer coefficient (HTC) of 400 W/m 2 K. This HTC proved to be the most sensitive parameter in determining the local surface temperature during deposition. Previous experimental work found noticeable microstructural changes with 0.5 mm fused silica wafers in place of silicon during the PETN deposition. This work showed that fused silica slows initial wafer cool down and results in ~10 °C difference for the surface temperature at 500 μm PETN film thickness. It was also found that the deposition surface temperature is insensitive to the cooling power of the copper block due to the copper block's very large heat capacity and thermal conductivity relative to the heat input from the PVD process. Future work should incorporate the addition of local stress during PETN deposition. Lastly, based on simulation results, it is also recommended to investigate the impact of wafer surface energy on the PETN microstructure and morphology formation.« less

Modeling physical vapor deposition of energetic materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shirvan, Koroush; Forrest, Eric C.

Morphology and microstructure of organic explosive films formed using physical vapor deposition (PVD) processes strongly depends on local surface temperature during deposition. Currently, there is no accurate means of quantifying the local surface temperature during PVD processes in the deposition chambers. This study focuses on using a multiphysics computational fluid dynamics tool, STARCCM+, to simulate pentaerythritol tetranitrate (PETN) deposition. The PETN vapor and solid phase were simulated using the volume of fluid method and its deposition in the vacuum chamber on spinning silicon wafers was modeled. The model also included the spinning copper cooling block where the wafers are placedmore » along with the chiller operating with forced convection refrigerant. Implicit time-dependent simulations in two- and three-dimensional were performed to derive insights in the governing physics for PETN thin film formation. PETN is deposited at the rate of 14 nm/s at 142.9 °C on a wafer with an initial temperature of 22 °C. The deposition of PETN on the wafers was calculated at an assumed heat transfer coefficient (HTC) of 400 W/m 2 K. This HTC proved to be the most sensitive parameter in determining the local surface temperature during deposition. Previous experimental work found noticeable microstructural changes with 0.5 mm fused silica wafers in place of silicon during the PETN deposition. This work showed that fused silica slows initial wafer cool down and results in ~10 °C difference for the surface temperature at 500 μm PETN film thickness. It was also found that the deposition surface temperature is insensitive to the cooling power of the copper block due to the copper block's very large heat capacity and thermal conductivity relative to the heat input from the PVD process. Future work should incorporate the addition of local stress during PETN deposition. Lastly, based on simulation results, it is also recommended to investigate the impact of wafer surface energy on the PETN microstructure and morphology formation.« less

Rewetting of monogroove heat pipe in Space Station radiators

NASA Technical Reports Server (NTRS)

Chan, S. H.

1994-01-01

This annual report summarizes the work accomplished on rewetting of monogroove heat pipe in space station. Specifically, theoretical and experimental investigations of the rewetting characteristics of thin liquid films over unheated and heated capillary grooved plates were performed. To investigate the effect of gravity on rewetting, the grooved surface was placed in upward and downward facing positions. Profound gravitational effects were observed as the rewetting velocity was found to be higher in the upward than in the downward facing orientation. The difference was even greater with higher initial plate temperatures. With either orientation, it was found that the rewetting velocity increased with the initial plate temperature. But when the temperature was raised above a rewetting temperature, the rewetting velocity decreased with the initial plate temperature. Hydrodynamically controlled and heat conduction controlled rewetting models were then presented to explain and to predict the rewetting characteristics in these two distinct regions. The predicted rewetting velocities were found to be in good agreement with experimental data with elevated plate temperatures.

Towards adjoint-based inversion of time-dependent mantle convection with nonlinear viscosity

NASA Astrophysics Data System (ADS)

Li, Dunzhu; Gurnis, Michael; Stadler, Georg

2017-04-01

We develop and study an adjoint-based inversion method for the simultaneous recovery of initial temperature conditions and viscosity parameters in time-dependent mantle convection from the current mantle temperature and historic plate motion. Based on a realistic rheological model with temperature-dependent and strain-rate-dependent viscosity, we formulate the inversion as a PDE-constrained optimization problem. The objective functional includes the misfit of surface velocity (plate motion) history, the misfit of the current mantle temperature, and a regularization for the uncertain initial condition. The gradient of this functional with respect to the initial temperature and the uncertain viscosity parameters is computed by solving the adjoint of the mantle convection equations. This gradient is used in a pre-conditioned quasi-Newton minimization algorithm. We study the prospects and limitations of the inversion, as well as the computational performance of the method using two synthetic problems, a sinking cylinder and a realistic subduction model. The subduction model is characterized by the migration of a ridge toward a trench whereby both plate motions and subduction evolve. The results demonstrate: (1) for known viscosity parameters, the initial temperature can be well recovered, as in previous initial condition-only inversions where the effective viscosity was given; (2) for known initial temperature, viscosity parameters can be recovered accurately, despite the existence of trade-offs due to ill-conditioning; (3) for the joint inversion of initial condition and viscosity parameters, initial condition and effective viscosity can be reasonably recovered, but the high dimension of the parameter space and the resulting ill-posedness may limit recovery of viscosity parameters.

Experimental study on water content detection of traditional masonry based on infrared thermal image

NASA Astrophysics Data System (ADS)

Zhang, Baoqing; Lei, Zukang

2017-10-01

Based on infrared thermal imaging technology for seepage test of two kinds of brick masonry, find out the relationship between the distribution of one-dimensional two brick surface temperature distribution and one-dimensional surface moisture content were determined after seepage brick masonry minimum temperature zone and water content determination method of the highest point of the regression equation, the relationship between temperature and moisture content of the brick masonry reflected the quantitative and establish the initial wet masonry building disease analysis method, then the infrared technology is applied to the protection of historic buildings in.

Surface Power Radiative Cooling Tests

NASA Astrophysics Data System (ADS)

Vaughn, Jason; Schneider, Todd

2006-01-01

Terrestrial nuclear power plants typically maintain their temperature through convective cooling, such as water and forced air. However, the space environment is a vacuum environment, typically 10-8 Torr pressure, therefore in proposed missions to the lunar surface, power plants would have to rely on radiative cooling to remove waste heat. Also, the Martian surface has a very tenuous atmosphere (e.g. ~5 Torr CO2), therefore, the main heat transfer method on the Martian surface is also radiative. Because of the lack of atmosphere on the Moon and the tenuous atmosphere on Mars, surface power systems on both the Lunar and Martian surface must rely heavily on radiative heat transfer. Because of the large temperature swings on both the lunar and the Martian surfaces, trying to radiate heat is inefficient. In order to increase power system efficiency, an effort is underway to test various combinations of materials with high emissivities to demonstrate their ability to survive these degrading atmospheres to maintain a constant radiator temperature improving surface power plant efficiency. An important part of this effort is the development of a unique capability that would allow the determination of a materials emissivity at high temperatures. A description of the test capability as well as initial data is presented.

Thermal and UV Hydrosilylation of Alcohol-Based Bifunctional Alkynes on Si (111) surfaces: How surface radicals influence surface bond formation

PubMed Central

Khung, Y. L.; Ngalim, S. H.; Scaccabarozi, A.; Narducci, D.

2015-01-01

Using two different hydrosilylation methods, low temperature thermal and UV initiation, silicon (111) hydrogenated surfaces were functionalized in presence of an OH-terminated alkyne, a CF3-terminated alkyne and a mixed equimolar ratio of the two alkynes. XPS studies revealed that in the absence of premeditated surface radical through low temperature hydrosilylation, the surface grafting proceeded to form a Si-O-C linkage via nucleophilic reaction through the OH group of the alkyne. This led to a small increase in surface roughness as well as an increase in hydrophobicity and this effect was attributed to the surficial etching of silicon to form nanosize pores (~1–3 nm) by residual water/oxygen as a result of changes to surface polarity from the grafting. Furthermore in the radical-free thermal environment, a mix in equimolar of these two short alkynes can achieve a high contact angle of ~102°, comparable to long alkyl chains grafting reported in literature although surface roughness was relatively mild (rms = ~1 nm). On the other hand, UV initiation on silicon totally reversed the chemical linkages to predominantly Si-C without further compromising the surface roughness, highlighting the importance of surface radicals determining the reactivity of the silicon surface to the selected alkynes. PMID:26067470

A fundamental study of nucleate pool boiling under microgravity

NASA Technical Reports Server (NTRS)

Ervin, Jamie S.; Merte, Herman, Jr.

1991-01-01

An experimental study of incipient boiling in short-term microgravity and with a/g = +/- 1 for pool boiling was performed. Calibrated thin gold films sputtered on a smoothly polished quartz surface were used simultaneously for thermal resistance measurements and heating of the boiling surface. The gold films were used for both transient and quasi-steady heating surface temperature measurements. Two test vessels were constructed for precise measurement and control of fluid temperature and pressure: a laboratory pool boiling vessel for the a/g = +/- experiments and a pool boiling vessel designed for the 131 m free-fall in the NASA Lewis Research Center Microgravity Research Facility for the microgravity tests. Measurements included the heater surface temperature, the pressure near the heating surface, and the bulk liquid temperatures. High speed photography was used in the experiments. With high quality microgravity and the measured initial temperature of the quiescent test fluid, R113, the temperature distribution in the liquid at the moment of boiling inception resulting from an imposed step in heat flux is known with a certainty not possible previously. The types of boiling propagation across the large flat heating surface are categorized; the conditions necessary for their occurrence are described. Explosive boiling propagation with a striking pattern of small scale protuberances over the entire vapor mass periphery not observed previously at low heat flux levels is described. For the heater surface with a/g = -1, a step in the heater surface temperature of short duration was imposed. The resulting liquid temperature distribution at the moment of boiling inception was different from that obtained with a step in heat flux.

Improving the Accuracy of Satellite Sea Surface Temperature Measurements by Explicitly Accounting for the Bulk-Skin Temperature Difference

NASA Technical Reports Server (NTRS)

Castro, Sandra L.; Emery, William J.

2002-01-01

The focus of this research was to determine whether the accuracy of satellite measurements of sea surface temperature (SST) could be improved by explicitly accounting for the complex temperature gradients at the surface of the ocean associated with the cool skin and diurnal warm layers. To achieve this goal, work centered on the development and deployment of low-cost infrared radiometers to enable the direct validation of satellite measurements of skin temperature. During this one year grant, design and construction of an improved infrared radiometer was completed and testing was initiated. In addition, development of an improved parametric model for the bulk-skin temperature difference was completed using data from the previous version of the radiometer. This model will comprise a key component of an improved procedure for estimating the bulk SST from satellites. The results comprised a significant portion of the Ph.D. thesis completed by one graduate student and they are currently being converted into a journal publication.

Dissolution of minerals with rough surfaces

NASA Astrophysics Data System (ADS)

de Assis, Thiago A.; Aarão Reis, Fábio D. A.

2018-05-01

We study dissolution of minerals with initial rough surfaces using kinetic Monte Carlo simulations and a scaling approach. We consider a simple cubic lattice structure, a thermally activated rate of detachment of a molecule (site), and rough surface configurations produced by fractional Brownian motion algorithm. First we revisit the problem of dissolution of initial flat surfaces, in which the dissolution rate rF reaches an approximately constant value at short times and is controlled by detachment of step edge sites. For initial rough surfaces, the dissolution rate r at short times is much larger than rF ; after dissolution of some hundreds of molecular layers, r decreases by some orders of magnitude across several time decades. Meanwhile, the surface evolves through configurations of decreasing energy, beginning with dissolution of isolated sites, then formation of terraces with disordered boundaries, their growth, and final smoothing. A crossover time to a smooth configuration is defined when r = 1.5rF ; the surface retreat at the crossover is approximately 3 times the initial roughness and is temperature-independent, while the crossover time is proportional to the initial roughness and is controlled by step-edge site detachment. The initial dissolution process is described by the so-called rough rates, which are measured for fixed ratios between the surface retreat and the initial roughness. The temperature dependence of the rough rates indicates control by kink site detachment; in general, it suggests that rough rates are controlled by the weakest microscopic bonds during the nucleation and formation of the lowest energy configurations of the crystalline surface. Our results are related to recent laboratory studies which show enhanced dissolution in polished calcite surfaces. In the application to calcite dissolution in alkaline environment, the minimal values of recently measured dissolution rate spectra give rF ∼10-9 mol/(m2 s), and the calculated rate laws of our model give rough rates in the range 10-6 -10-5 mol/(m2 s). This estimate is consistent with the range of calcite dissolution rates obtained in a recent work after treatment of literature data, which suggests the universal control of kink site dissolution in short term laboratory works. The weak effects of lattice size on our results also suggest that smoothing of mineral grain surfaces across geological times may be a microscopic explanation for the difference of chemical weathering rate of silicate minerals in laboratory and in the environment.

How does whole ecosystem warming of a peatland affect methane production and consumption?

NASA Astrophysics Data System (ADS)

Hopple, A.; Brunik, K.; Keller, J.; Pfeifer-Meister, L.; Woerndle, G.; Zalman, C.; Hanson, P.; Bridgham, S. D.

2017-12-01

Peatlands are among Earth's most important terrestrial ecosystems due to their massive soil carbon (C) stores and significant release of methane (CH4) into the atmosphere. Methane has a sustained-flux global warming potential 45-times greater than carbon dioxide (CO2), and the accuracy of Earth system model projections relies on our mechanistic understanding of peatland CH4 cycling in the context of environmental change. The objective of this study was to determine, under in situ conditions, how heating of the peat profile affects ecosystem-level anaerobic C cycling. We assessed the response of CO2 and CH4 production, as well as the anaerobic oxidation of CH4 (AOM), in a boreal peatland following 13 months of deep peat heating (DPH) and 16 months of subsequent whole-ecosystem warming (surface and deep heating; WEW) as part of the Spruce and Peatland Responses Under Changing Environments (SPRUCE) project in northern Minnesota, USA. The study uses a regression-based experimental design including 5 temperature treatments that warmed the entire 2 m peat profile from 0 to +9 °C above ambient temperature. Soil cores were collected at multiple depths (25-200 cm) from each experimental chamber at the SPRUCE site and anaerobically incubated at in situ temperatures for 1-2 weeks. Methane and CO2 production in surface peat were positively correlated with elevated temperature, but no consistent temperature response was found at depth (75-200 cm) following DPH. However, during WEW, we observed significant increases in both surface and deep peat methanogenesis with increasing temperature. Surface peat had greater CH4 production rates than deeper peat, implying that the increased CH4 emissions observed in the field were largely driven by surface peat warming. The CO2:CH4 ratio was inversely correlated with temperature across all depths following 16 months of WEW, indicating that the entire peat profile is becoming more methanogenic with warming. We also observed AOM throughout the whole peat profile, with the highest rates observed at the surface and initial data suggesting a positive correlation with increasing temperature. While SPRUCE will continue for many years, our initial results suggest that the vast C stores at depth in peatlands are minimally responsive to warming and any response will be driven largely by surface peat.

Heat Transfer in a Superelliptic Transition Duct

NASA Technical Reports Server (NTRS)

Poinsatte, Philip; Thurman, Douglas; Hippensteele, Steven

2008-01-01

Local heat transfer measurements were experimentally mapped using a transient liquid-crystal heat transfer technique on the surface of a circular-to-rectangular transition duct. The transition duct had a length-to-diameter ratio of 1.5 and an exit-plane aspect ratio of 3. The crosssectional geometry was defined by the equation of a superellipse. The cross-sectional area was the same at the inlet and exit but varied up to 15 percent higher through the transition. The duct was preheated to a uniform temperature (nominally 64 C) before allowing room temperature air to be suddenly drawn through it. As the surface cooled, the resulting isothermal contours on the duct surface were revealed using a surface coating of thermochromic liquid crystals that display distinctive colors at particular temperatures. A video record was made of the surface temperature and time data for all points on the duct surfaces during each test. Using this surface temperature-time data together with the temperature of the air flowing through the model and the initial temperature of the model wall, the heat transfer coefficient was calculated by employing the classic one-dimensional, semi-infinite wall heat transfer conduction model. Test results are reported for inlet diameter-based Reynolds numbers ranging from 0.4x106 to 2.4x106 and two grid-generated freestream turbulence intensities of about 1 percent, which is typical of wind tunnels, and up to 16 percent, which may be more typical of real engine conditions.

Skin Temperature Analysis and Bias Correction in a Coupled Land-Atmosphere Data Assimilation System

NASA Technical Reports Server (NTRS)

Bosilovich, Michael G.; Radakovich, Jon D.; daSilva, Arlindo; Todling, Ricardo; Verter, Frances

2006-01-01

In an initial investigation, remotely sensed surface temperature is assimilated into a coupled atmosphere/land global data assimilation system, with explicit accounting for biases in the model state. In this scheme, an incremental bias correction term is introduced in the model's surface energy budget. In its simplest form, the algorithm estimates and corrects a constant time mean bias for each gridpoint; additional benefits are attained with a refined version of the algorithm which allows for a correction of the mean diurnal cycle. The method is validated against the assimilated observations, as well as independent near-surface air temperature observations. In many regions, not accounting for the diurnal cycle of bias caused degradation of the diurnal amplitude of background model air temperature. Energy fluxes collected through the Coordinated Enhanced Observing Period (CEOP) are used to more closely inspect the surface energy budget. In general, sensible heat flux is improved with the surface temperature assimilation, and two stations show a reduction of bias by as much as 30 Wm(sup -2) Rondonia station in Amazonia, the Bowen ratio changes direction in an improvement related to the temperature assimilation. However, at many stations the monthly latent heat flux bias is slightly increased. These results show the impact of univariate assimilation of surface temperature observations on the surface energy budget, and suggest the need for multivariate land data assimilation. The results also show the need for independent validation data, especially flux stations in varied climate regimes.

Auger electron spectroscopy study of initial stages of oxidation in a copper - 19.6-atomic-percent-aluminum alloy

NASA Technical Reports Server (NTRS)

Ferrante, J.

1973-01-01

Auger electron spectroscopy was used to examine the initial stages of oxidation of a polycrystalline copper - 19.6 a/o-aluminum alloy. The growth of the 55-eV aluminum oxide peak and the decay of the 59-, 62-, and 937-eV copper peaks were examined as functions of temperature, exposure, and pressure. Pressures ranged from 1x10 to the minus 7th power to 0.0005 torr of O2. Temperatures ranged from room temperature to 700 C. A completely aluminum oxide surface layer was obtained in all cases. Complete disappearance of the underlying 937-eV copper peak was obtained by heating at 700 C in O2 at 0.0005 torr for 1 hr. Temperature studies indicated that thermally activated diffusion was important to the oxidation studies. The initial stages of oxidation followed a logarithmic growth curve.

Initial stage oxidation on nano-trenched Si(1 0 0) surface

NASA Astrophysics Data System (ADS)

Sun, Yu; Liu, Yi-Lun; Izumi, Satoshi; Chen, Xue-Feng; Zhai, Zhi; Tian, Shao-Hua

2018-01-01

As the size of an electronic element shrinks to nanoscale, trench design of Si strongly influences the performance of related semiconductor devices. By reactive force field molecular dynamics (ReaxFF MD) simulation, the initial stage oxidation on nano-trenched Si(1 0 0) angled 60°, 90°, 120°, 150° under temperatures from 300 K to 1200 K has been studied. Inhomogeneous oxidation at the convex-concave corners of the Si surface was observed. In general, the initial oxidation process on the Si surface was that, firstly, the O atoms ballistically transported into surface, then a high O concentration induced compressive stress at the surface layers, which prevented further oxidation. Compared to the concave corner, the convex one contacted a larger volume of oxygen at the very beginning stage, leading an anisotropic absorption of O atoms. Afterwards, a critical compression was produced at both the convex and concave corners to limit the oxidation. As a result, an inhomogeneous oxide film grew on nano-trenched Si. Meanwhile, due to enhanced O transport and compression relaxation by increasing temperature, the inhomogeneous oxidation was more obvious under 1200 K. These present results explained the observed experimental phenomena on the oxidation of non-planar Si and provided an aspect on the design of nano-trenched electronic components in the semiconductor field.

Improved Modeling of Land-Atmosphere Interactions using a Coupled Version of WRF with the Land Information System

NASA Technical Reports Server (NTRS)

Case, Jonathan L.; LaCasse, Katherine M.; Santanello, Joseph A., Jr.; Lapenta, William M.; Petars-Lidard, Christa D.

2007-01-01

The exchange of energy and moisture between the Earth's surface and the atmospheric boundary layer plays a critical role in many hydrometeorological processes. Accurate and high-resolution representations of surface properties such as sea-surface temperature (SST), vegetation, soil temperature and moisture content, and ground fluxes are necessary to better understand the Earth-atmosphere interactions and improve numerical predictions of weather and climate phenomena. The NASA/NWS Short-term Prediction Research and Transition (SPORT) Center is currently investigating the potential benefits of assimilating high-resolution datasets derived from the NASA moderate resolution imaging spectroradiometer (MODIS) instruments using the Weather Research and Forecasting (WRF) model and the Goddard Space Flight Center Land Information System (LIS). The LIS is a software framework that integrates satellite and ground-based observational and modeled data along with multiple land surface models (LSMs) and advanced computing tools to accurately characterize land surface states and fluxes. The LIS can be run uncoupled to provide a high-resolution land surface initial condition, and can also be run in a coupled mode with WRF to integrate surface and soil quantities using any of the LSMs available in LIS. The LIS also includes the ability to optimize the initialization of surface and soil variables by tuning the spin-up time period and atmospheric forcing parameters, which cannot be done in the standard WRF. Among the datasets available from MODIS, a leaf-area index field and composite SST analysis are used to improve the lower boundary and initial conditions to the LIS/WRF coupled model over both land and water. Experiments will be conducted to measure the potential benefits from using the coupled LIS/WRF model over the Florida peninsula during May 2004. This month experienced relatively benign weather conditions, which will allow the experiments to focus on the local and mesoscale impacts of the high-resolution MODIS datasets and optimized soil and surface initial conditions. Follow-on experiments will examine the utility of such an optimized WRF configuration for more complex weather scenarios such as convective initiation. This paper will provide an overview of the experiment design and present preliminary results from selected cases in May 2004.

Effects of high-temperature gas dealkalization on surface mechanical properties of float glass

NASA Astrophysics Data System (ADS)

Senturk, Ufuk

The surface topography, and the near-surface structure and mechanical property changes on float glass, that was treated in atmospheres containing SOsb2, HCl, and 1,1 difluoroethane (DFE) gases, at temperatures in the glass transition region, were studied. Structure was investigated using surface sensitive infrared spectroscopy techniques (attenuated total reflectance (ATR) and diffuse reflectance (DRIFT)) and the topography was evaluated using atomic force microscopy (AFM). The results obtained from the two FTIR methods were in agreement with each other. Mechanical property characteristics of the surface were determined by measuring microhardness using a recording microindentation set-up. A simple analysis performed on the three hardness calculation methods-LVH, LVHsb2, and Lsb2VH-indicated that LVH and LVHsb2 are less effected by measurement errors and are better suited for the calculation of hardness. Contact damage characteristics of the treated glass was also studied by monitoring the crack initiation behavior during indentation, using acoustic emission. The results of the studies, aiming for the understanding of the structure, topography, and hardness property changes indicate that the treatment parameters-temperature, time, and treatment atmosphere conditions-are significant factors influencing these properties. The analysis of these results suggest a relation to exist between the three properties. This relation is used in understanding the surface mechanical properties of the treated float glasses. The difference in the thermal expansion coefficients between the dealkalized surface and bulk, the nature of surface structure changes, structural relaxation, surface water content, and glass transformation temperature are identified as the major factors having an influence on the properties. A model connecting these features is suggested. A difference in the structure, hardness, and topography on the air and tin sides of float glass is also shown to exist. The contact damage behavior of the treated surfaces is shown to differ from those of untreated surfaces, for SOsb2-treated float glass, where the crack initiation characteristics indicate crack formation from the surface and the indenter tip, different than the expected anomalous deformation. This behavior resembles that of a silica glass deformation on the surface, which is in agreement with the other foundations in this study.

Initial oxidation of pure and K doped NiTi shape memory alloys

NASA Astrophysics Data System (ADS)

Tollefsen, H.; Raaen, S.

2009-06-01

Initial oxidation of pure and K doped nitinol has been studied by photoelectron spectroscopy. The composition of the TiOx layer that forms on the surface is found to depend on the temperature during oxidation. The oxidation at high temperatures results in enhanced formation of lower oxides, whereas TiO2 predominates for oxidation at lower temperatures, e.g., 70 °C. Submonolayer coverage of K on NiTi enhances the formation of TiO2 on the expense of lower oxides, which is of consequence for formation of a protective oxide layer and biocompatibility. Oxidation in the martensitic phase was found to be independent of temperature for temperatures between -40 and 10 °C, whereas in the austenitic phase the oxide growth is thermally activated.

A comparison of thermocouple and infrared thermographic analysis of temperature rise on the root surface during the continuous wave of condensation technique.

PubMed

Mc Cullagh, J J; Setchell, D J; Gulabivala, K; Hussey, D L; Biagioni, P; Lamey, P J; Bailey, G

2000-07-01

This study was designed to use two methods of temperature measurement to analyse and quantify the in vitro root surface temperature changes during the initial stage of the continuous wave technique of obturation of 17 single-rooted premolar teeth with standard canal preparations. A model was designed to allow simultaneous temperature measurement with both thermocouples and an infrared thermal imaging system. Two thermocouples were placed on the root surface, one coronally and the other near the root apex. A series of thermal images were recorded by an infrared thermal imaging camera during the downpack procedure. The mean temperature rises on the root surface, as measured by the two thermocouples, averaged 13.9 degrees C over the period of study, whilst the infrared thermal imaging system measured an average rise of 28.4 degrees C at the same sites. Temperatures at the more apical point were higher than those measured coronally. After the first wave of condensation, the second activation of the plugger in the canal prior to its removal always resulted in a secondary rise in temperature. The thermal imaging system detected areas of greater temperature change distant from the two selected thermocouple sites. The continuous wave technique of obturation may result in high temperatures on the external root surface. Infrared thermography is a useful device for mapping patterns of temperature change over a large area.

Facile Synthesis of Thick Films of Poly(methyl methacrylate), Poly(styrene), and Poly(vinyl pyridine) from Au Surfaces

PubMed Central

Saha, Sampa

2011-01-01

Atom transfer radical polymerization (ATRP) is commonly used to grow polymer brushes from Au surfaces, but the resulting film thicknesses are usually significantly less than with ATRP from SiO2 substrates. On Au, growth of poly(methyl methacrylate) (PMMA) blocks from poly(tert-butyl acrylate) brushes occurs more rapidly than growth of PMMA from initiator monolayers, suggesting that the disparity between growth rates from Au and SiO2 stems from the Au surface. Radical quenching by electron transfer from Au is probably not the termination mechanism because polymerization from thin, cross-linked initiators gives film thicknesses that are essentially the same as the thicknesses of films grown from SiO2 under the same polymerization conditions. However, this result is consistent with termination through desorption of thiols from non-cross-linked films, and reaction of these thiols with growing polymer chains. The enhanced stability of cross-linked initiators allows ATRP at temperatures up to ~100 °C and enables the growth of thick films of PMMA (350 nm), polystyrene (120 nm) and poly(vinyl pyridine) (200 nm) from Au surfaces in 1 hour. At temperatures >100 °C, the polymer brush layers delaminate as large area films. PMID:21728374

Effect of hot extrusion, other constituents, and temperature on the strength and fracture of polycrystalline MgO

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rice, R.W.

Improved agreement was confirmed between the Petch intercept and single-crystal yield stresses at 22 C. Hot-extruded MgO crystal specimens stressed parallel with the resultant axial texture (1) gave the highest and least-scattered strength-grain size results at 22 C, (2) showed direct fractographic evidence of microplastic initiated fracture at 22 C and showed macroscopic yield at 1,315 and especially 1,540 C, and (3) fractured entirely via transgranular cleavage, except for intergranular failure initiation from one or a few grain boundary surfaces exposed on the subsequent fracture surface, mainly at 1,540 C. Hot-extruded, hot-pressed MgO billets gave comparable strength when fracture initiatedmore » transgranularly, but lower strength when fracture initiated from one or especially a few grain boundary surfaces exposed on the fracture. The extent and frequency of such boundary fracture increased with test temperature. While oxide additions of [<=] 5% or impurities in hot-pressed or hot-extruded MgO can make limited strength increases at larger grain sizes, those having limited solubility can limit strength at finer grain sizes, as can coarser surface finish. Overall, MgO strength is seen as a balance between flaw and microplastic controlled failure, with several parameters shifting the balance.« less

The relative contributions of tropical Pacific sea surface temperatures and atmospheric internal variability to the recent global warming hiatus

NASA Astrophysics Data System (ADS)

Deser, Clara; Guo, Ruixia; Lehner, Flavio

2017-08-01

The recent slowdown in global mean surface temperature (GMST) warming during boreal winter is examined from a regional perspective using 10-member initial-condition ensembles with two global coupled climate models in which observed tropical Pacific sea surface temperature anomalies (TPAC SSTAs) and radiative forcings are specified. Both models show considerable diversity in their surface air temperature (SAT) trend patterns across the members, attesting to the importance of internal variability beyond the tropical Pacific that is superimposed upon the response to TPAC SSTA and radiative forcing. Only one model shows a close relationship between the realism of its simulated GMST trends and SAT trend patterns. In this model, Eurasian cooling plays a dominant role in determining the GMST trend amplitude, just as in nature. In the most realistic member, intrinsic atmospheric dynamics and teleconnections forced by TPAC SSTA cause cooling over Eurasia (and North America), and contribute equally to its GMST trend.

Our contaminated atmosphere: The danger of climate change, phases 1 and 2. [effect of atmospheric particulate matter on surface temperature and earth's radiation budget

NASA Technical Reports Server (NTRS)

Cimorelli, A. J.; House, F. B.

1974-01-01

The effects of increased concentrations of atmospheric particulate matter on average surface temperature and on the components of the earth's radiation budget are studied. An atmospheric model which couples particulate loading to surface temperature and to changes in the earth's radiation budget was used. A determination of the feasibility of using satellites to monitor the effect of increased atmospheric particulate concentrations is performed. It was found that: (1) a change in man-made particulate loading of a factor of 4 is sufficient to initiate an ice age; (2) variations in the global and hemispheric weighted averages of surface temperature, reflected radiant fluz and emitted radiant flux are nonlinear functions of particulate loading; and (3) a black satellite sphere meets the requirement of night time measurement sensitivity, but not the required day time sensitivity. A nonblack, spherical radiometer whose external optical properties are sensitive to either the reflected radiant fluz or the emitted radiant flux meets the observational sensitivity requirements.

Low-Temperature Desorption of N2O from NO on Rutile TiO2(110)-1x1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Boseong; Li, Zhenjun; Kay, Bruce D.

2014-05-08

We find that NO dosed on rutile TiO2(110)-1×1 at substrate temperatures as low as 50 K readily reacts to produce N2O which desorbs promptly from the surface leaving an oxygen adatom behind. The desorption rate of N2O reaches a maximum value after 1 – 2 sec at an NO flux of 1.2 ×1014 NO/cm2∙sec and then decreases rapidly as the initially clean, reduced TiO2(110) surface with ~5% oxygen vacancies (VO’s) becomes covered with oxygen adatoms and unreacted NO. The maximum desorption rate is also found to increase as the substrate temperature is raised up to about 100 K. Interestingly, themore » N2O desorption during the low-temperature (LT) NO dose is strongly suppressed when molecular oxygen is predosed, whereas it persists on the surface with VO’s passivated by surface hydroxyls. Our results show that the surface charge, not the VO sites, plays a dominant role in the LT N2O desorption induced by a facile NO reduction at such low temperatures.« less

Modeling of surface temperature effects on mixed material migration in NSTX-U

NASA Astrophysics Data System (ADS)

Nichols, J. H.; Jaworski, M. A.; Schmid, K.

2016-10-01

NSTX-U will initially operate with graphite walls, periodically coated with thin lithium films to improve plasma performance. However, the spatial and temporal evolution of these films during and after plasma exposure is poorly understood. The WallDYN global mixed-material surface evolution model has recently been applied to the NSTX-U geometry to simulate the evolution of poloidally inhomogenous mixed C/Li/O plasma-facing surfaces. The WallDYN model couples local erosion and deposition processes with plasma impurity transport in a non-iterative, self-consistent manner that maintains overall material balance. Temperature-dependent sputtering of lithium has been added to WallDYN, utilizing an adatom sputtering model developed from test stand experimental data. Additionally, a simplified temperature-dependent diffusion model has been added to WallDYN so as to capture the intercalation of lithium into a graphite bulk matrix. The sensitivity of global lithium migration patterns to changes in surface temperature magnitude and distribution will be examined. The effect of intra-discharge increases in surface temperature due to plasma heating, such as those observed during NSTX Liquid Lithium Divertor experiments, will also be examined. Work supported by US DOE contract DE-AC02-09CH11466.

Evolution of Ge nanoislands on Si(110)-'16 × 2' surface under thermal annealing studied using STM

NASA Astrophysics Data System (ADS)

Gangopadhyay, Subhashis; Yoshimura, Masamichi; Ueda, Kazuyuki

2009-11-01

The initial nucleation of Ge nanoclusters on Si(110) at room temperature (RT), annealing-induced surface roughening and the evolution of three-dimensional Ge nanoislands have been investigated using scanning tunneling microscopy (STM). A few monolayers (ML) of Ge deposited at room temperature lead to the formation of Ge clusters which are homogeneously distributed across the surface. The stripe-like patterns, characteristic of the Si(110)-'16 × 2' surface reconstruction are also retained. Increasing annealing temperatures, however, lead to significant surface diffusion and thus, disruption of the underlying '16 × 2' reconstruction. The annealing-induced removal of the stripe structures (originated from '16 × 2' reconstruction) starts at approximately 300 °C, whereas the terrace structures of Si(110) are thermally stable up to 500 °C. At approximately 650 °C, shallow Ge islands of pyramidal shape with (15,17,1) side facets start to form. Annealing at even higher temperatures enhances Ge island formation. Our findings are explained in terms of partial dewetting of the metastable Ge wetting layer (WL) (formed at room temperature) as well as partial relaxation of lattice strain through three-dimensional (3D) island growth.

Re-emerging ocean temperature anomalies in late-2010 associated with a repeat negative NAO

NASA Astrophysics Data System (ADS)

Taws, Sarah L.; Marsh, Robert; Wells, Neil C.; Hirschi, Joël

2011-10-01

Northern Europe was influenced by consecutive episodes of extreme winter weather at the start and end of the 2010 calendar year. A tripole pattern in North Atlantic sea surface temperature anomalies (SSTAs), associated with an exceptionally negative phase of the North Atlantic Oscillation (NAO), characterized both winter periods. This pattern was largely absent at the surface during the 2010 summer season; however equivalent sub-surface temperature anomalies were preserved within the seasonal thermocline throughout the year. Here, we present evidence for the re-emergence of late-winter 2009/10 SSTAs during the following early winter season of 2010/11. The observed re-emergence contributes toward the winter-to-winter persistence of the anomalous tripole pattern. Considering the active influence of the oceans upon leading modes of atmospheric circulation over seasonal timescales, associated with the memory of large-scale sea surface temperature anomaly patterns, the re-emergence of remnant temperature anomalies may have also contributed toward the persistence of a negative winter NAO, and the recurrence of extreme wintry conditions over the initial 2010/11 winter season.

Photosynthetically active radiation (PAR) x ultraviolet radiation (UV) interact to initiate solar injury in apple

USDA-ARS?s Scientific Manuscript database

Sunburn or solar injury (SI) in apple is associated with high temperature, high visible light and ultraviolet radiation (UV). Fruit surface temperature (FST) thresholds for SI related disorders have been developed but there are no thresholds established for solar radiation. The objectives of the s...

Coverage-dependent adsorption and desorption of oxygen on Pd(100)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dunnen, Angela den; Jacobse, Leon; Wiegman, Sandra

2016-06-28

We have studied the adsorption and desorption of O{sub 2} on Pd(100) by supersonic molecular beam techniques and thermal desorption spectroscopy. Adsorption measurements on the bare surface confirm that O{sub 2} initially dissociates for all kinetic energies between 56 and 380 meV and surface temperatures between 100 and 600 K via a direct mechanism. At and below 150 K, continued adsorption leads to a combined O/O{sub 2} overlayer. Dissociation of molecularly bound O{sub 2} during a subsequent temperature ramp leads to unexpected high atomic oxygen coverages, which are also obtained at high incident energy and high surface temperature. At intermediatemore » temperatures and energies, these high final coverages are not obtained. Our results show that kinetic energy of the gas phase reactant and reaction energy dissipated during O{sub 2} dissociation on the cold surface both enable activated nucleation of high-coverage surface structures. We suggest that excitation of local substrate phonons may play a crucial role in oxygen dissociation at any coverage.« less

Recent Upgrades to NASA SPoRT Initialization Datasets for the Environmental Modeling System

NASA Technical Reports Server (NTRS)

Case, Jonathan L.; Lafontaine, Frank J.; Molthan, Andrew L.; Zavodsky, Bradley T.; Rozumalski, Robert A.

2012-01-01

The NASA Short-term Prediction Research and Transition (SPoRT) Center has developed several products for its NOAA/National Weather Service (NWS) partners that can initialize specific fields for local model runs within the NOAA/NWS Science and Training Resource Center Environmental Modeling System (EMS). The suite of SPoRT products for use in the EMS consists of a Sea Surface Temperature (SST) composite that includes a Lake Surface Temperature (LST) analysis over the Great Lakes, a Great Lakes sea-ice extent within the SST composite, a real-time Green Vegetation Fraction (GVF) composite, and NASA Land Information System (LIS) gridded output. This paper and companion poster describe each dataset and provide recent upgrades made to the SST, Great Lakes LST, GVF composites, and the real-time LIS runs.

Viscous relaxation of the Moho under large lunar basins

NASA Technical Reports Server (NTRS)

Brown, C. David; Grimm, Robert E.

1993-01-01

Viscously relaxed topography on the Moon is evidence of a period in lunar history of higher internal temperatures and greater surface activity. Previous work has demonstrated the viscous relaxation of the Tranquilitatis basin surface. Profiles of the lunar Moho under nine basins were constructed from an inversion of lunar gravity data. These profiles show a pattern of increasingly subdued relief with age, for which two explanations have been proposed. First, ancient basins may have initially had extreme Moho relief like that of younger basins like Orientale, but, due to higher internal temperatures in early lunar history, this relief viscously relaxed to that observed today. Second, ductile flow in the crust immediately after basin formation resulted in an initially shallow basin and subdued mantle uplift. The intent is to test the first hypothesis.

Examining the Impacts of High-Resolution Land Surface Initialization on Model Predictions of Convection in the Southeastern U.S.

NASA Technical Reports Server (NTRS)

Case, Jonathan L.; Kumar, Sujay V.; Santos, Pablo; Medlin, Jeffrey M.; Jedlovec, Gary J.

2009-01-01

One of the most challenging weather forecast problems in the southeastern U.S. is daily summertime pulse convection. During the summer, atmospheric flow and forcing are generally weak in this region; thus, convection typically initiates in response to local forcing along sea/lake breezes, and other discontinuities often related to horizontal gradients in surface heating rates. Numerical simulations of pulse convection usually have low skill, even in local predictions at high resolution, due to the inherent chaotic nature of these precipitation systems. Forecast errors can arise from assumptions within physics parameterizations, model resolution limitations, as well as uncertainties in both the initial state of the atmosphere and land surface variables such as soil moisture and temperature. For this study, it is hypothesized that high-resolution, consistent representations of surface properties such as soil moisture and temperature, ground fluxes, and vegetation are necessary to better simulate the interactions between the land surface and atmosphere, and ultimately improve predictions of local circulations and summertime pulse convection. The NASA Short-term Prediction Research and Transition (SPORT) Center has been conducting studies to examine the impacts of high-resolution land surface initialization data generated by offline simulations of the NASA Land Informatiot System (LIS) on subsequent numerical forecasts using the Weather Research and Forecasting (WRF) model (Case et al. 2008, to appear in the Journal of Hydrometeorology). Case et al. presents improvements to simulated sea breezes and surface verification statistics over Florida by initializing WRF with land surface variables from an offline LIS spin-up run, conducted on the exact WRF domain and resolution. The current project extends the previous work over Florida, focusing on selected case studies of typical pulse convection over the southeastern U.S., with an emphasis on improving local short-term WRF simulations over the Mobile, AL and Miami, FL NWS county warning areas. Future efforts may involve examining the impacts of assimilating remotely-sensed soil moisture data, and/or introducing weekly greenness vegetation fraction composites (as opposed to monthly climatologies) into ol'fline NASA LIS runs. Based on positive impacts, the offline LIS runs could be transitioned into an operational mode, providing land surface initialization data to NWS forecast offices in real time.

Opposed-Flow Flame Spread Across Propanol Pools: Effect of Liquid Fuel Depth

NASA Technical Reports Server (NTRS)

Kim, Inchul; Sirignano, William A.

1999-01-01

This computational study examines the effect of liquid fuel depth on flame spread across propanol pools with and without forced, opposed air flow. The initial pool temperature is below its closed- cup flash point temperature T(sub cc); so the liquid fuel must be heated sufficiently to create a combustible mixture of fuel vapor before ignition and flame spread can occur. Furthermore, in order for the flame to spread, an approximate rule is that the liquid fuel surface temperature ahead of the flame must be heated above T(sub cc) so that a flammable mixture just above the lean limit exists ahead of the flame. The depth of a liquid fuel pool would affect the heating of the liquid fuel pool and thus the liquid fuel surface temperature ahead of the flame. It has been observed experimentally and numerically that, at normal gravity without forced gas-phase flow and with the initial pool temperature T(sub 0) in a range well below T(sub cc), the flame periodically accelerates and decelerates (pulsates) as it propagates. The depth of a liquid fuel pool would change this range of T(sub 0) since it would affect the heating of the pool.

A Fundamental Study of Nucleate Pool Boiling Under Microgravity

NASA Technical Reports Server (NTRS)

Ervin, Jamie S.; Merte, Herman, Jr.

1996-01-01

An experimental study of incipient boiling in short-term microgravity and with a/g = +/- 1 for pool boiling was performed. Calibrated thin gold films sputtered on a smoothly polished quartz surface were used simultaneously for thermal-resistance measurements and heating of the boiling surface. The gold films were used for both transient and quasi-steady heating surface temperature measurements. Two test vessels were constructed for precise measurement and control of fluid temperature and pressure: a laboratory pool boiling vessel for the a/g = +/- 1 experiments and a pool boiling vessel designed for the 131 m free-fall in the NASA Lewis Research Center Microgravity Research Facility for the microgravity tests. Measurements included the heater surface temperature, the pressure near the heating surface, the bulk liquid temperatures. High speed photography (up to 1,000 frames per second) was used in the experiments. With high quality microgravity and the measured initial temperature of the quiescent test fluid, R113, the temperature distribution in the liquid at the moment of boiling inception resulting from an imposed step in heat flux is known with a certainty not possible previously. The types of boiling propagation across the large flat heating surface, some observed here for the first time, are categorized; the conditions necessary for their occurrence are described. Explosive boiling propagation with a striking pattern of small scale protuberances over the entire vapor mass periphery not observed previously at low heat flux levels (on the order of 5 W/cm(exp 2)) is described. For the heater surface with a/g = -1, a step in the heater surface temperature of short duration was imposed. The resulting liquid temperature distribution at the moment of boiling inception was different from that obtained with a step in heat flux.

Fabrication method for a room temperature hydrogen sensor

NASA Technical Reports Server (NTRS)

Shukla, Satyajit V. (Inventor); Cho, Hyoung (Inventor); Seal, Sudipta (Inventor); Ludwig, Lawrence (Inventor)

2011-01-01

A sensor for selectively determining the presence and measuring the amount of hydrogen in the vicinity of the sensor. The sensor comprises a MEMS device coated with a nanostructured thin film of indium oxide doped tin oxide with an over layer of nanostructured barium cerate with platinum catalyst nanoparticles. Initial exposure to a UV light source, at room temperature, causes burning of organic residues present on the sensor surface and provides a clean surface for sensing hydrogen at room temperature. A giant room temperature hydrogen sensitivity is observed after making the UV source off. The hydrogen sensor of the invention can be usefully employed for the detection of hydrogen in an environment susceptible to the incursion or generation of hydrogen and may be conveniently used at room temperature.

Liquid cooled plate heat exchanger for battery cooling of an electric vehicle (EV)

NASA Astrophysics Data System (ADS)

Rahman, M. M.; Rahman, H. Y.; Mahlia, T. M. I.; Sheng, J. L. Y.

2016-03-01

A liquid cooled plate heat exchanger was designed to improve the battery life of an electric vehicle which suffers from premature aging or degradation due to the heat generation during discharging and charging period. Computational fluid dynamics (CFD) was used as a tool to analyse the temperature distribution when a constant surface heat flux was set at the bottom surface of the battery. Several initial and boundary conditions were set based on the past studies on the plate heat exchanger in the simulation software. The design of the plate heat exchanger was based on the Nissan Leaf battery pack to analyse the temperature patterns. Water at different mass flow rates was used as heat transfer fluid. The analysis revealed the designed plate heat exchanger could maintain the surface temperature within the range of 20 to 40°C which is within the safe operating temperature of the battery.

Real-time photoelectron spectroscopy study of the oxidation reaction kinetics on p-type and n-type Si (001) surfaces

NASA Astrophysics Data System (ADS)

Yu, Zhou

Silicon oxides thermally grown on Si surface are the core gate materials of metal-oxide-semiconductor field effect transistor (MOSFET). This thin oxide layer insulates the gate terminals and the transistors substrate which make MOSFET has certain advantages over those conventional junctions, such as field-effect transistor (FET) and junction field effect transistor (JFET). With an oxide insulating layer, MOSFET is able to sustain higher input impedance and the corresponding gate leakage current can be minimized. Today, though the oxidation process on Si substrate is popular in industry, there are still some uncertainties about its oxidation kinetics. On a path to clarify and modeling the oxidation kinetics, a study of initial oxidation kinetics on Si (001) surface has attracted attentions due to having a relatively low surface electron density and few adsorption channels compared with other Si surface direction. Based on previous studies, there are two oxidation models of Si (001) that extensively accepted, which are dual oxide species mode and autocatalytic reaction model. These models suggest the oxidation kinetics on Si (001) mainly relies on the metastable oxygen atom on the surface and the kinetic is temperature dependent. Professor Yuji Takakuwa's group, Surface Physics laboratory, Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, observed surface strain existed during the oxidation kinetics on Si (001) and this is the first time that strain was discovered during Si oxidation. Therefore, it is necessary to explain where the strain comes from since none of previous model research included the surface strain (defects generation) into considerations. Moreover, recent developing of complementary metal-oxide-semiconductor (CMOS) requires a simultaneous oxidation process on p- and n-type Si substrate. However, none of those previous models included the dopant factor into the oxidation kinetic modeling. All of these points that further work is necessary to update and modify the traditional Si (001) oxidation models that had been accepted for several decades. To update and complement the Si (001) oxidation kinetics, an understanding of the temperature and dopant factor during initial oxidation kinetics on Si (001) is our first step. In this study, real-time photoelectron spectroscopy is applied to characterize the oxidized (001) surface and surface information was collected by ultraviolet photoelectron spectroscopy technique. By analyzing parameters such as O 2p spectra uptake, change of work function and the surface state in respect of p- and n- type Si (001) substrate under different temperature, the oxygen adsorption structure and the dopant factor can be determined. In this study, experiments with temperature gradients on p-type Si (001) were conducted and this aims to clarify the temperature dependent characteristic of Si (001) surface oxidation. A comparison of the O 2p uptake, change of work function and surface state between p-and n-type Si (001) is made under a normal temperature and these provides with the data to explain how the dopant factor impacts the oxygen adsorption structure on the surface. In the future, the study of the oxygen adsorption structure will lead to an explanation of the surface strain that discovered; therefore, fundamental of the initial oxidation on Si (001) would be updated and complemented, which would contribute to the future gate technology in MOSFET and CMOS.

Novel Phenylethynyl Imide Silanes as Coupling Agents for Titanium Alloy

NASA Technical Reports Server (NTRS)

Park, C.; Lowther, S. E.; Smith, J. G., Jr.; Conell, J. W.; Hergenrother, P. M.; SaintClair, T. L.

2004-01-01

The durability of titanium (Ti) alloys bonded with high temperature adhesives such as polyimides has failed to attain the level of performance required for many applications. The problem to a large part is attributed to the instability of the surface treatment on the Ti substrate. Although Ti alloy adhesive specimens with surface treatments such as chromic acid anodization, Pasa-Jell, Turco, etc. have provided high initial mechanical properties, these properties have decreased as a function of aging at ambient temperature and faster, when aged at elevated temperatures or in a hot-wet environment. As part of the High Speed Civil Transport program where Ti honeycomb sandwich structure must perform for 60,000 hours at 177 C, work was directed to the development of environmentally safe, durable Ti alloy surface treatments.

A Two-Dimensional Manganese Gallium Nitride Surface Structure Showing Ferromagnetism at Room Temperature.

PubMed

Ma, Yingqiao; Chinchore, Abhijit V; Smith, Arthur R; Barral, María Andrea; Ferrari, Valeria

2018-01-10

Practical applications of semiconductor spintronic devices necessitate ferromagnetic behavior at or above room temperature. In this paper, we demonstrate a two-dimensional manganese gallium nitride surface structure (MnGaN-2D) which is atomically thin and shows ferromagnetic domain structure at room temperature as measured by spin-resolved scanning tunneling microscopy and spectroscopy. Application of small magnetic fields proves that the observed magnetic domains follow a hysteretic behavior. Two initially oppositely oriented MnGaN-2D domains are rotated into alignment with only 120 mT and remain mostly in alignment at remanence. The measurements are further supported by first-principles theoretical calculations which reveal highly spin-polarized and spin-split surface states with spin polarization of up to 95% for manganese local density of states.

Auger electron spectroscopy and depth profile study of oxidation of modified 440C steel

NASA Technical Reports Server (NTRS)

Ferrante, J.

1974-01-01

Auger electron spectroscopy (AES) and sputtering were used to study selective oxidation of modified 440C steel. The sample was polycrystalline. Oxidation was performed on initially clean surfaces for pressures ranging from 1 x 10 to the minus 7th power to 1 x 10 to the minus 5th power torr and temperatures ranging from room temperature to 800 C. AES traces were taken during oxidation. In situ sputtering depth profiles are also obtained. A transition temperature is observed in the range 600 to 700 C for which the composition of the outer surface oxide changed from iron oxide to chromium oxide. Heating in vacuum about 5 x 10 to the minus 10 power torr to 700 C causes conversion of the iron oxide surface to chromium oxide.

Mechanisms of deep benzene oxidation on the Pt(1 1 1) surface using temperature-programmed reaction methods

NASA Astrophysics Data System (ADS)

Marsh, Anderson L.; Gland, John L.

2003-06-01

The catalytic oxidation of benzene on the Pt(1 1 1) surface has been characterized using temperature-programmed reaction spectroscopy (TPRS) over a wide range of benzene and oxygen coverages. Coadsorbed atomic oxygen and benzene are the primary reactants on the surface during the initial oxidation step. Benzene is oxidized over the 300-500 K range to produce carbon dioxide and water. Carbon-hydrogen and carbon-carbon bond activation are clearly rate-limiting steps for these reactions. Preferential oxidation causes depletion of bridge-bonded benzene, suggesting enhanced reactivity in this bonding configuration. When oxygen is in excess on the surface, all of the surface carbon and hydrogen is oxidized. When benzene is in excess on the surface, hydrogen produced by dehydrogenation is desorbed after all of the surface oxygen has been consumed. Repulsive interactions between benzene and molecular oxygen dominate at low temperatures. Preadsorption of oxygen inhibits adsorption of less reactive benzene in threefold hollow sites. The desorption temperature of this non-reactive chemisorbed benzene decreases and overlaps with the multilayer desorption peak with increasing oxygen exposure. The results presented here provide a clear picture of rate-limiting steps during deep oxidation of benzene on the Pt(1 1 1) surface.

The size prediction of potential inclusions embedded in the sub-surface of fused silica by damage morphology

NASA Astrophysics Data System (ADS)

Gao, Xiang; Qiu, Rong; Wang, Kunpeng; Zhang, Jiangmei; Zhou, Guorui; Yao, Ke; Jiang, Yong; Zhou, Qiang

2017-04-01

A model for predicting the size ranges of different potential inclusions initiating damage on the surface of fused silica has been presented. This accounts for the heating of nanometric inclusions whose absorptivity is described based on Mie Theory. The depth profile of impurities has been measured by ICP-OES. By the measured temporal pulse profile on the surface of fused silica, the temperature and thermal stress has been calculated. Furthermore, considering the limit conditions of temperature and thermal stress strength for different damage morphologies, the size range of potential inclusions for fused silica is discussed.

Quantum tunneling of oxygen atoms on very cold surfaces.

PubMed

Minissale, M; Congiu, E; Baouche, S; Chaabouni, H; Moudens, A; Dulieu, F; Accolla, M; Cazaux, S; Manicó, G; Pirronello, V

2013-08-02

Any evolving system can change state via thermal mechanisms (hopping a barrier) or via quantum tunneling. Most of the time, efficient classical mechanisms dominate at high temperatures. This is why an increase of the temperature can initiate the chemistry. We present here an experimental investigation of O-atom diffusion and reactivity on water ice. We explore the 6-25 K temperature range at submonolayer surface coverages. We derive the diffusion temperature law and observe the transition from quantum to classical diffusion. Despite the high mass of O, quantum tunneling is efficient even at 6 K. As a consequence, the solid-state astrochemistry of cold regions should be reconsidered and should include the possibility of forming larger organic molecules than previously expected.

Crystallization of copper metaphosphate glass

NASA Technical Reports Server (NTRS)

Bae, Byeong-Soo; Weinberg, Michael C.

1993-01-01

The effect of the valence state of copper in copper metaphosphate glass on the crystallization behavior and glass transition temperature has been investigated. The crystallization of copper metaphosphate is initiated from the surface and its main crystalline phase is copper metaphosphate (Cu(PO)3),independent of the (Cu sup 2+)/(Cu(total)). However, the crystal morphology, the relative crystallization rates, and their temperature dependences are affected by the (Cu sup 2+)/(Cu (total)) ratio in the glass. On the other hand, the totally oxidized glass crystallizes from all over the surface. The relative crystallization rate of the reduced glass to the totally oxidized glass is large at low temperature, but small at high temperature. The glass transition temperature of the glass increases as the (Cu sup 2+)/(Cu(total)) ratio is raised. It is also found that the atmosphere used during heat treatment does not influence the crystallization of the reduced glass, except for the formation of a very thin CuO surface layer when heated in air.

Short communication: using infrared thermography as an in situ measure of core body temperature in lot-fed Angus steers

NASA Astrophysics Data System (ADS)

Lees, Angela M.; Lees, J. C.; Sejian, V.; Wallage, A. L.; Gaughan, J. B.

2018-01-01

Thirty-six Black Angus steers were used in a replicated study; three replicates of 12 steers/replicate. Steers had an initial non-fasted BW of 392.3 ± 5.1, 427.5 ± 6.3, and 392.7 ± 3.7 kg for each replicate, respectively. Steers were housed outside in individual animal pens (10 m × 3.4 m). Each replicate was conducted over a 6-day period where infrared thermography (IRT) images were collected at 3-h intervals, commencing at 0600 h on day 1 and concluding at 0600 h on day 6. Rumen temperatures ( T RUM) were measured at 10-min intervals for the duration of each replicate using a radio-frequency identification (RFID) rumen bolus. These data were used to determine the relationship with surface temperature of the cattle, which was determined using IRT. Individual T RUM were converted to an hourly average. The relationship between T RUM and surface temperature was determined using Pearson's correlation coefficient. There were no linear trends between mean hourly T RUM and mean surface temperature. Pearson's correlation coefficient indicated that there were weak associations ( r ≤ 0.1; P < 0.003) between T RUM and body surface temperature. These data suggest that there was little relationship between the surface temperature and T RUM.

Triton's surface-atmosphere energy balance

USGS Publications Warehouse

Stansberry, J.A.; Yelle, R.V.; Lunine, J.I.; McEwen, A.S.

1992-01-01

We explore the energetics of Triton's surface-atmosphere system using a model that includes the turbulent transfer of sensible heat as well as insolation, reradiation, and latent heat transport. The model relies on a 1?? by 1?? resolution hemispheric bolometric albedo map of Triton for determining the atmospheric temperature, the N2 frost emissivity, and the temperatures of unfrosted portions of the surface consistent with a frost temperature of ???38 K. For a physically plausible range of heat transfer coefficients, we find that the atmospheric temperature roughly 1 km above the surface is approximately 1 to 3 K hotter than the surface. Atmospheric temperatures of 48 K suggested by early analysis of radio occultation data cannot be obtained for plausible values of the heat transfer coefficients. Our calculations indicate that Triton's N2 frosts must have an emissivity well below unity in order to have a temperature of ???38 K, consistent with previous results. We also find that convection over small hot spots does not significantly cool them off, so they may be able to act as continous sources of buoyancy for convective plumes, but have not explored whether the convection is vigorous enough to entrain particulate matter thereby forming a dust devil. Our elevated atmospheric temperatures make geyser driven plumes with initial upward velocities ???10 m s-1 stagnate in the lower atmosphere. These "wimpy" plumes provide a possible explanation for Triton's "wind streaks.". ?? 1992.

Initialized decadal prediction for transition to positive phase of the Interdecadal Pacific Oscillation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meehl, Gerald A.; Hu, Aixue; Teng, Haiyan

The negative phase of the Interdecadal Pacific Oscillation (IPO), a dominant mode of multi-decadal variability of sea surface temperatures (SSTs) in the Pacific, contributed to the reduced rate of global surface temperature warming in the early 2000s. Here, a proposed mechanism for IPO multidecadal variability indicates that the presence of decadal timescale upper ocean heat content in the off-equatorial western tropical Pacific can provide conditions for an interannual El Nino/Southern Oscillation event to trigger a transition of tropical Pacific SSTs to the opposite IPO phase. Here we show that a decadal prediction initialized in 2013 simulates predicted Nino3.4 SSTs thatmore » have qualitatively tracked the observations through 2015. The year three to seven average prediction (2015-2019) from the 2013 initial state shows a transition to the positive phase of the IPO from the previous negative phase and a resumption of larger rates of global warming over the 2013-2022 period consistent with a positive IPO phase.« less

Initialized decadal prediction for transition to positive phase of the Interdecadal Pacific Oscillation

DOE PAGES

Meehl, Gerald A.; Hu, Aixue; Teng, Haiyan

2016-06-02

The negative phase of the Interdecadal Pacific Oscillation (IPO), a dominant mode of multi-decadal variability of sea surface temperatures (SSTs) in the Pacific, contributed to the reduced rate of global surface temperature warming in the early 2000s. Here, a proposed mechanism for IPO multidecadal variability indicates that the presence of decadal timescale upper ocean heat content in the off-equatorial western tropical Pacific can provide conditions for an interannual El Nino/Southern Oscillation event to trigger a transition of tropical Pacific SSTs to the opposite IPO phase. Here we show that a decadal prediction initialized in 2013 simulates predicted Nino3.4 SSTs thatmore » have qualitatively tracked the observations through 2015. The year three to seven average prediction (2015-2019) from the 2013 initial state shows a transition to the positive phase of the IPO from the previous negative phase and a resumption of larger rates of global warming over the 2013-2022 period consistent with a positive IPO phase.« less

High-Resolution Specification of the Land and Ocean Surface for Improving Regional Mesoscale Model Predictions

NASA Technical Reports Server (NTRS)

Case, Jonathan L.; Lazarus, Steven M.; Splitt, Michael E.; Crosson, William L.; Lapenta, William M.; Jedlovec, Gary J.; Peters-Lidard, Christa D.

2008-01-01

The exchange of energy and moisture between the Earth's surface and the atmospheric boundary layer plays a critical role in many meteorological processes. High-resolution, accurate representations of surface properties such as sea-surface temperature (SST), soil temperature and moisture content, ground fluxes, and vegetation are necessary to better understand the Earth-atmosphere interactions and improve numerical predictions of sensible weather. The NASA Short-term Prediction Research and Transition (SPoRT) Center has been conducting separate studies to examine the impacts of high-resolution land-surface initialization data from the Goddard Space Flight Center Land Information System (LIS) on subsequent WRF forecasts, as well as the influence of initializing WRF with SST composites derived from the MODIS instrument. This current project addresses the combined impacts of using high-resolution lower boundary data over both land (LIS data) and water (MODIS SSTs) on the subsequent daily WRF forecasts over Florida during May 2004. For this experiment, the WRF model is configured to run on a nested domain with 9- km and 3-kin grid spacing, centered on the Florida peninsula and adjacent coastal waters of the Gulf of Mexico and Atlantic Ocean. A control configuration of WRF is established to take all initial condition data from the NCEP Eta model. Meanwhile, two WRF experimental runs are configured to use high-resolution initialization data from (1) LIS land-surface data only, and (2) a combination of LIS data and high-resolution MODIS SST composites. The experiment involves running 24-hour simulations of the control WRF configuration, the MS-initialized WRF, and the LIS+MODIS-initialized WRF daily for the entire month of May 2004. All atmospheric data for initial and boundary conditions for the Control, LIS, and LIS+MODIS runs come from the NCEP Eta model on a 40-km grid. Verification statistics are generated at land surface observation sites and buoys, and the impacts of the high-resolution lower boundary data on the development and evolution of mesoscale circulations such as sea and land breezes are examined, This paper will present the results of these WRF modeling experiments using LIS and MODIS lower boundary datasets over the Florida peninsula during May 2004.

Constraining storm-scale forecasts of deep convective initiation with surface weather observations

NASA Astrophysics Data System (ADS)

Madaus, Luke

Successfully forecasting when and where individual convective storms will form remains an elusive goal for short-term numerical weather prediction. In this dissertation, the convective initiation (CI) challenge is considered as a problem of insufficiently resolved initial conditions and dense surface weather observations are explored as a possible solution. To better quantify convective-scale surface variability in numerical simulations of discrete convective initiation, idealized ensemble simulations of a variety of environments where CI occurs in response to boundary-layer processes are examined. Coherent features 1-2 hours prior to CI are found in all surface fields examined. While some features were broadly expected, such as positive temperature anomalies and convergent winds, negative temperature anomalies due to cloud shadowing are the largest surface anomaly seen prior to CI. Based on these simulations, several hypotheses about the required characteristics of a surface observing network to constrain CI forecasts are developed. Principally, these suggest that observation spacings of less than 4---5 km would be required, based on correlation length scales. Furthermore, it is anticipated that 2-m temperature and 10-m wind observations would likely be more relevant for effectively constraining variability than surface pressure or 2-m moisture observations based on the magnitudes of observed anomalies relative to observation error. These hypotheses are tested with a series of observing system simulation experiments (OSSEs) using a single CI-capable environment. The OSSE results largely confirm the hypotheses, and with 4-km and particularly 1-km surface observation spacing, skillful forecasts of CI are possible, but only within two hours of CI time. Several facets of convective-scale assimilation, including the need for properly-calibrated localization and problems from non-Gaussian ensemble estimates of the cloud field are discussed. Finally, the characteristics of one candidate dense surface observing network are examined: smartphone pressure observations. Available smartphone pressure observations (and 1-hr pressure tendency observations) are tested by assimilating them into convective-allowing ensemble forecasts for a three-day active convective period in the eastern United States. Although smartphone observations contain noise and internal disagreement, they are effective at reducing short-term forecast errors in surface pressure, wind and precipitation. The results suggest that smartphone pressure observations could become a viable mesoscale observation platform, but more work is needed to enhance their density and reduce error. This work concludes by reviewing and suggesting other novel candidate observation platforms with a potential to improve convective-scale forecasts of CI.

Thermonuclear runaways in nova outbursts. 2: Effect of strong, instantaneous, local fluctuations

NASA Technical Reports Server (NTRS)

Shankar, Anurag; Arnett, David

1994-01-01

In an attempt to understand the manner in which nova outbursts are initiated on the surface of a white dwarf, we investigate the effects fluctuations have on the evolution of a thermonuclear runaway. Fluctuations in temperature density, or the composition of material in the burning shell may arise due to the chaotic flow field generated by convection when it occurs, or by the accretion process itself. With the aid of two-dimensional reactive flow calculations, we consider cases where a strong fluctutation in temperature arises during the early, quiescent accretion phase or during the later, more dynamic, explosion phase. In all cases we find that an instantaneous, local temperature fluctuation causes the affected material to become Rayleigh-Taylor unstable. The rapid rise and subsequent expansion of matter immediately cools the hot blob, which prevents the lateral propagation of burning. This suggests that local temperature fluctuations do not play a significant role in directly initiating the runaway, especially during the early stages. However, they may provide an efficient mechanism of mixing core material into the envelope (thereby pre-enriching the fuel for subsequent episodes of explosive hydrogen burning) and of mixing substantial amounts of the radioactive nucleus N-13 into the surface layers, making novae potential gamma-ray sources. This suggests that it is the global not the local, evolution of the core-envelope interface to high temperatures which dominates the development of the runaway. We also present a possible new scenario for the initiation of nova outbursts based on our results.

The international surface temperature initiative

NASA Astrophysics Data System (ADS)

Thorne, P. W.; Lawrimore, J. H.; Willett, K. M.; Allan, R.; Chandler, R. E.; Mhanda, A.; de Podesta, M.; Possolo, A.; Revadekar, J.; Rusticucci, M.; Stott, P. A.; Strouse, G. F.; Trewin, B.; Wang, X. L.; Yatagai, A.; Merchant, C.; Merlone, A.; Peterson, T. C.; Scott, E. M.

2013-09-01

The aim of International Surface Temperature Initiative is to create an end-to-end process for analysis of air temperature data taken over the land surface of the Earth. The foundation of any analysis is the source data. Land surface air temperature records have traditionally been stored in local, organizational, national and international holdings, some of which have been available digitally but many of which are available solely on paper or as imaged files. Further, economic and geopolitical realities have often precluded open sharing of these data. The necessary first step therefore is to collate readily available holdings and augment these over time either through gaining access to previously unavailable digital data or through data rescue and digitization activities. Next, it must be recognized that these historical measurements were made primarily in support of real-time weather applications where timeliness and coverage are key. At almost every long-term station it is virtually certain that changes in instrumentation, siting or observing practices have occurred. Because none of the historical measures were made in a metrologically traceable manner there is no unambiguous way to retrieve the true climate evolution from the heterogeneous raw data holdings. Therefore it is desirable for multiple independent groups to produce adjusted data sets (so-called homogenized data) to adequately understand the data characteristics and estimate uncertainties. Then it is necessary to benchmark the performance of the contributed algorithms (equivalent to metrological software validation) through development of realistic benchmark datasets. In support of this, a series of successive benchmarking and assessment cycles are envisaged, allowing continual improvement while avoiding over-tuning of algorithms. Finally, a portal is proposed giving access to related data-products, utilizing the assessment results to provide guidance to end-users on which product is the most suited to their needs. Recognizing that the expertise of the metrological community has been under-utilized historically in such climate data analysis problems, the governance of the Initiative includes significant representation from the metrological community. We actively welcome contributions from interested parties to any relevant aspects of the Initiative work.

Investigating the Impacts of Surface Temperature Anomalies due to Burned Area Albedo in Northern sub-Saharan Africa

NASA Astrophysics Data System (ADS)

Gabbert, T.; Matsui, T.; Capehart, W. J.; Ichoku, C. M.; Gatebe, C. K.

2015-12-01

The northern Sub-Saharan African region (NSSA) is an area of intense focus due to periodic severe droughts that have dire consequences on the growing population, which relies mostly on rain fed agriculture for its food supply. This region's weather and hydrologic cycle are very complex and are dependent on the West African Monsoon. Different regional processes affect the West African Monsoon cycle and variability. One of the areas of current investigation is the water cycle response to the variability of land surface characteristics. Land surface characteristics are often altered in NSSA due to agricultural practices, grazing, and the fires that occur during the dry season. To better understand the effects of biomass burning on the hydrologic cycle of the sub-Saharan environment, an interdisciplinary team sponsored by NASA is analyzing potential feedback mechanisms due to the fires. As part of this research, this study focuses on the effects of land surface changes, particularly albedo and skin temperature, that are influenced by biomass burning. Surface temperature anomalies can influence the initiation of convective rainfall and surface albedo is linked to the absorption of solar radiation. To capture the effects of fire perturbations on the land surface, NASA's Unified Weather and Research Forecasting (NU-WRF) model coupled with NASA's Land Information System (LIS) is being used to simulate burned area surface albedo inducing surface temperature anomalies and other potential effects to environmental processes. Preliminary sensitivity results suggest an altered surface radiation budget, regional warming of the surface temperature, slight increase in average rainfall, and a change in precipitation locations.

Nucleation and growth of oxide islands during the initial-stage oxidation of (100)Cu-Pt alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Luo, Langli; Zhou, Guangwen, E-mail: gzhou@binghamton.edu; Kang, Yihong

2015-02-14

The initial-stage oxidation of (100) Cu-Pt alloys has been examined by in situ environmental transmission electron microscopy and ex situ atomic force microscopy (AFM). It is shown that the oxidation proceeds via the nucleation and growth of Cu{sub 2}O islands that show dependence on the alloy composition and oxidation temperature. The kinetic measurements on the oxide nucleation reveal that both the nucleation density and surface coverage of Cu{sub 2}O islands can be promoted by alloying more Pt in the Cu-Pt alloys. Increasing the oxidation temperature above 700 °C results in the growth of large Cu{sub 2}O islands that transits to amore » dendritic growth morphology. The ex situ AFM studies reveal that the nucleation of oxide islands can occur on surface terraces and the subsequent oxide growth depletes local terrace Cu atoms that results in the formation of surface pits.« less

Simulation of hydrodynamics, temperature, and dissolved oxygen in Beaver Lake, Arkansas, 1994-1995

USGS Publications Warehouse

Haggard, Brian; Green, W. Reed

2002-01-01

The tailwaters of Beaver Lake and other White River reservoirs support a cold-water trout fishery of significant economic yield in northwestern Arkansas. The Arkansas Game and Fish Commission has requested an increase in existing minimum flows through the Beaver Lake dam to increase the amount of fishable waters downstream. Information is needed to assess the impact of additional minimum flows on temperature and dissolved-oxygen qualities of reservoir water above the dam and the release water. A two-dimensional, laterally averaged hydrodynamic, thermal and dissolved-oxygen model was developed and calibrated for Beaver Lake, Arkansas. The model simulates surface-water elevation, currents, heat transport and dissolved-oxygen dynamics. The model was developed to assess the impacts of proposed increases in minimum flows from 1.76 cubic meters per second (the existing minimum flow) to 3.85 cubic meters per second (the additional minimum flow). Simulations included assessing (1) the impact of additional minimum flows on tailwater temperature and dissolved-oxygen quality and (2) increasing initial water-surface elevation 0.5 meter and assessing the impact of additional minimum flow on tailwater temperatures and dissolved-oxygen concentrations. The additional minimum flow simulation (without increasing initial pool elevation) appeared to increase the water temperature (<0.9 degrees Celsius) and decrease dissolved oxygen concentration (<2.2 milligrams per liter) in the outflow discharge. Conversely, the additional minimum flow plus initial increase in pool elevation (0.5 meter) simulation appeared to decrease outflow water temperature (0.5 degrees Celsius) and increase dissolved oxygen concentration (<1.2 milligrams per liter) through time. However, results from both minimum flow scenarios for both water temperature and dissolved oxygen concentration were within the boundaries or similar to the error between measured and simulated water column profile values.

Initialization shock in decadal hindcasts due to errors in wind stress over the tropical Pacific

NASA Astrophysics Data System (ADS)

Pohlmann, Holger; Kröger, Jürgen; Greatbatch, Richard J.; Müller, Wolfgang A.

2017-10-01

Low prediction skill in the tropical Pacific is a common problem in decadal prediction systems, especially for lead years 2-5 which, in many systems, is lower than in uninitialized experiments. On the other hand, the tropical Pacific is of almost worldwide climate relevance through its teleconnections with other tropical and extratropical regions and also of importance for global mean temperature. Understanding the causes of the reduced prediction skill is thus of major interest for decadal climate predictions. We look into the problem of reduced prediction skill by analyzing the Max Planck Institute Earth System Model (MPI-ESM) decadal hindcasts for the fifth phase of the Climate Model Intercomparison Project and performing a sensitivity experiment in which hindcasts are initialized from a model run forced only by surface wind stress. In both systems, sea surface temperature variability in the tropical Pacific is successfully initialized, but most skill is lost at lead years 2-5. Utilizing the sensitivity experiment enables us to pin down the reason for the reduced prediction skill in MPI-ESM to errors in wind stress used for the initialization. A spurious trend in the wind stress forcing displaces the equatorial thermocline in MPI-ESM unrealistically. When the climate model is then switched into its forecast mode, the recovery process triggers artificial El Niño and La Niña events at the surface. Our results demonstrate the importance of realistic wind stress products for the initialization of decadal predictions.

Sink property of metallic glass free surfaces

DOE PAGES

Shao, Lin; Fu, Engang; Price, Lloyd; ...

2015-03-16

When heated to a temperature close to glass transition temperature, metallic glasses (MGs) begin to crystallize. Under deformation or particle irradiation, crystallization occurs at even lower temperatures. Hence, phase instability represents an application limit for MGs. Here, we report that MG membranes of a few nanometers thickness exhibit properties different from their bulk MG counterparts. The study uses in situ transmission electron microscopy with concurrent heavy ion irradiation and annealing to observe crystallization behaviors of MGs. For relatively thick membranes, ion irradiations introduce excessive free volumes and thus induce nanocrystal formation at a temperature linearly decreasing with increasing ion fluences.more » For ultra-thin membranes, however, the critical temperature to initiate crystallization is about 100 K higher than the bulk glass transition temperature. Molecular dynamics simulations indicate that this effect is due to the sink property of the surfaces which can effectively remove excessive free volumes. These findings suggest that nanostructured MGs having a higher surface to volume ratio are expected to have higher crystallization resistance, which could pave new paths for materials applications in harsh environments requiring higher stabilities.« less

The effect of physiological conditions on the surface structure of proteins: Setting the scene for human digestion of emulsions

NASA Astrophysics Data System (ADS)

Maldonado-Valderrama, J.; Gunning, A. P.; Ridout, M. J.; Wilde, P. J.; Morris, V. J.

2009-10-01

Understanding and manipulating the interfacial mechanisms that control human digestion of food emulsions is a crucial step towards improved control of dietary intake. This article reports initial studies on the effects of the physiological conditions within the stomach on the properties of the film formed by the milk protein ( β -lactoglobulin) at the air-water interface. Atomic force microscopy (AFM), surface tension and surface rheology techniques were used to visualize and examine the effect of gastric conditions on the network structure. The effects of changes in temperature, pH and ionic strength on a pre-formed interfacial structure were characterized in order to simulate the actual digestion process. Changes in ionic strength had little effect on the surface properties. In isolation, acidification reduced both the dilatational and the surface shear modulus, mainly due to strong repulsive electrostatic interactions within the surface layer and raising the temperature to body temperature accelerated the rearrangements within the surface layer, resulting in a decrease of the dilatational response and an increase of surface pressure. Together pH and temperature display an unexpected synergism, independent of the ionic strength. Thus, exposure of a pre-formed interfacial β -lactoglobulin film to simulated gastric conditions reduced the surface dilatational modulus and surface shear moduli. This is attributed to a weakening of the surface network in which the surface rearrangements of the protein prior to exposure to gastric conditions might play a crucial role.

Geodynamic Modeling of Planetary Ice-Oceans: Evolution of Ice-Shell Thickness in Convecting Two-Phase Systems

NASA Astrophysics Data System (ADS)

Allu Peddinti, D.; McNamara, A. K.

2016-12-01

Along with the newly unveiled icy surface of Pluto, several icy planetary bodies show indications of an active surface perhaps underlain by liquid oceans of some size. This augments the interest to explore the evolution of an ice-ocean system and its surface implications. The geologically young surface of the Jovian moon Europa lends much speculation to variations in ice-shell thickness over time. Along with the observed surface features, it suggests the possibility of episodic convection and conduction within the ice-shell as it evolved. What factors would control the growth of the ice-shell as it forms? If and how would those factors determine the thickness of the ice-shell and consequently the heat transfer? Would parameters such as tidal heating or initial temperature affect how the ice-shell grows and to what significance? We perform numerical experiments using geodynamical models of the two-phase ice-water system to study the evolution of planetary ice-oceans such as that of Europa. The models evolve self-consistently from an initial liquid ocean as it cools with time. The effects of presence, absence and magnitude of tidal heating on ice-shell thickness are studied in different models. The vigor of convection changes as the ice-shell continues to thicken. Initial modeling results track changes in the growth rate of the ice-shell as the vigor of the convection changes. The magnitude and temporal location of the rate change varies with different properties of tidal heating and values of initial temperature. A comparative study of models is presented to demonstrate how as the ice-shell is forming, its growth rate and convection are affected by processes such as tidal heating.

Diffusion dynamics of the Li+ ion on a model surface of amorphous carbon: a direct molecular orbital dynamics study.

PubMed

Tachikawa, Hiroto; Shimizu, Akira

2005-07-14

Diffusion processes of the Li+ ion on a model surface of amorphous carbon (Li+C96H24 system) have been investigated by means of the direct molecular orbital (MO) dynamics method at the semiempirical AM1 level. The total energy and energy gradient on the full-dimensional AM1 potential energy surface were calculated at each time step in the dynamics calculation. The optimized structure, where Li+ is located in the center of the cluster, was used as the initial structure at time zero. The dynamics calculation was carried out in the temperature range 100-1000 K. The calculations showed that the Li+ ion vibrates around the equilibrium point below 200 K, while the Li+ ion moves on the surface above 250 K. At intermediate temperatures (300 K < T < 400 K), the ion moves on the surface and falls in the edge regions of the cluster. At higher temperatures (600 K < T), the Li+ ion transfers freely on the surface and edge regions. The diffusion pathway of the Li+ ion was discussed on the basis of theoretical results.

Climate Response to Negative Greenhouse Gas Radiative Forcing in Polar Winter

NASA Astrophysics Data System (ADS)

Flanner, M. G.; Huang, X.; Chen, X.; Krinner, G.

2018-02-01

Greenhouse gas (GHG) additions to Earth's atmosphere initially reduce global outgoing longwave radiation, thereby warming the planet. In select environments with temperature inversions, however, increased GHG concentrations can actually increase local outgoing longwave radiation. Negative top of atmosphere and effective radiative forcing (ERF) from this situation give the impression that local surface temperatures could cool in response to GHG increases. Here we consider an extreme scenario in which GHG concentrations are increased only within the warmest layers of winter near-surface inversions of the Arctic and Antarctic. We find, using a fully coupled Earth system model, that the underlying surface warms despite the GHG addition exerting negative ERF and cooling the troposphere in the vicinity of the GHG increase. This unique radiative forcing and thermal response is facilitated by the high stability of the polar winter atmosphere, which inhibit thermal mixing and amplify the impact of surface radiative forcing on surface temperature. These findings also suggest that strategies to exploit negative ERF via injections of short-lived GHGs into inversion layers would likely be unsuccessful in cooling the planetary surface.

WRF Simulation over the Eastern Africa by use of Land Surface Initialization

NASA Astrophysics Data System (ADS)

Sakwa, V. N.; Case, J.; Limaye, A. S.; Zavodsky, B.; Kabuchanga, E. S.; Mungai, J.

2014-12-01

The East Africa region experiences severe weather events associated with hazards of varying magnitude. It receives heavy precipitation which leads to wide spread flooding and lack of sufficient rainfall in some parts results into drought. Cases of flooding and drought are two key forecasting challenges for the Kenya Meteorological Service (KMS). The source of heat and moisture depends on the state of the land surface which interacts with the boundary layer of the atmosphere to produce excessive precipitation or lack of it that leads to severe drought. The development and evolution of precipitation systems are affected by heat and moisture fluxes from the land surface within weakly-sheared environments, such as in the tropics and sub-tropics. These heat and moisture fluxes during the day can be strongly influenced by land cover, vegetation, and soil moisture content. Therefore, it is important to represent the land surface state as accurately as possible in numerical weather prediction models. Improved modeling capabilities within the region have the potential to enhance forecast guidance in support of daily operations and high-impact weather over East Africa. KMS currently runs a configuration of the Weather Research and Forecasting (WRF) model in real time to support its daily forecasting operations, invoking the Non-hydrostatic Mesoscale Model (NMM) dynamical core. They make use of the National Oceanic and Atmospheric Administration / National Weather Service Science and Training Resource Center's Environmental Modeling System (EMS) to manage and produce the WRF-NMM model runs on a 7-km regional grid over Eastern Africa.SPoRT and SERVIR provide land surface initialization datasets and model verification tool. The NASA Land Information System (LIS) provide real-time, daily soil initialization data in place of interpolated Global Forecast System soil moisture and temperature data. Model verification is done using the Model Evaluation Tools (MET) package, in order to quantify possible improvements in simulated temperature, moisture and precipitation resulting from the experimental land surface initialization. These MET tools enable KMS to monitor model forecast accuracy in near real time. This study highlights verification results of WRF runs over East Africa using the LIS land surface initialization.

Exchange of Groundwater and Surface-Water Mediated by Permafrost Response to Seasonal and Long Term Air Temperature Variation

USGS Publications Warehouse

Ge, Shemin; McKenzie, Jeffrey; Voss, Clifford; Wu, Qingbai

2011-01-01

Permafrost dynamics impact hydrologic cycle processes by promoting or impeding groundwater and surface water exchange. Under seasonal and decadal air temperature variations, permafrost temperature changes control the exchanges between groundwater and surface water. A coupled heat transport and groundwater flow model, SUTRA, was modified to simulate groundwater flow and heat transport in the subsurface containing permafrost. The northern central Tibet Plateau was used as an example of model application. Modeling results show that in a yearly cycle, groundwater flow occurs in the active layer from May to October. Maximum groundwater discharge to the surface lags the maximum subsurface temperature by two months. Under an increasing air temperature scenario of 3?C per 100 years, over the initial 40-year period, the active layer thickness can increase by three-fold. Annual groundwater discharge to the surface can experience a similar three-fold increase in the same period. An implication of these modeling results is that with increased warming there will be more groundwater flow in the active layer and therefore increased groundwater discharge to rivers. However, this finding only holds if sufficient upgradient water is available to replenish the increased discharge. Otherwise, there will be an overall lowering of the water table in the recharge portion of the catchment.

Optimizing pentacene thin-film transistor performance: Temperature and surface condition induced layer growth modification.

PubMed

Lassnig, R; Hollerer, M; Striedinger, B; Fian, A; Stadlober, B; Winkler, A

2015-11-01

In this work we present in situ electrical and surface analytical, as well as ex situ atomic force microscopy (AFM) studies on temperature and surface condition induced pentacene layer growth modifications, leading to the selection of optimized deposition conditions and entailing performance improvements. We prepared p ++ -silicon/silicon dioxide bottom-gate, gold bottom-contact transistor samples and evaluated the pentacene layer growth for three different surface conditions (sputtered, sputtered + carbon and unsputtered + carbon) at sample temperatures during deposition of 200 K, 300 K and 350 K. The AFM investigations focused on the gold contacts, the silicon dioxide channel region and the highly critical transition area. Evaluations of coverage dependent saturation mobilities, threshold voltages and corresponding AFM analysis were able to confirm that the first 3-4 full monolayers contribute to the majority of charge transport within the channel region. At high temperatures and on sputtered surfaces uniform layer formation in the contact-channel transition area is limited by dewetting, leading to the formation of trenches and the partial development of double layer islands within the channel region instead of full wetting layers. By combining the advantages of an initial high temperature deposition (well-ordered islands in the channel) and a subsequent low temperature deposition (continuous film formation for low contact resistance) we were able to prepare very thin (8 ML) pentacene transistors of comparably high mobility.

Optimizing pentacene thin-film transistor performance: Temperature and surface condition induced layer growth modification

PubMed Central

Lassnig, R.; Hollerer, M.; Striedinger, B.; Fian, A.; Stadlober, B.; Winkler, A.

2015-01-01

In this work we present in situ electrical and surface analytical, as well as ex situ atomic force microscopy (AFM) studies on temperature and surface condition induced pentacene layer growth modifications, leading to the selection of optimized deposition conditions and entailing performance improvements. We prepared p++-silicon/silicon dioxide bottom-gate, gold bottom-contact transistor samples and evaluated the pentacene layer growth for three different surface conditions (sputtered, sputtered + carbon and unsputtered + carbon) at sample temperatures during deposition of 200 K, 300 K and 350 K. The AFM investigations focused on the gold contacts, the silicon dioxide channel region and the highly critical transition area. Evaluations of coverage dependent saturation mobilities, threshold voltages and corresponding AFM analysis were able to confirm that the first 3–4 full monolayers contribute to the majority of charge transport within the channel region. At high temperatures and on sputtered surfaces uniform layer formation in the contact–channel transition area is limited by dewetting, leading to the formation of trenches and the partial development of double layer islands within the channel region instead of full wetting layers. By combining the advantages of an initial high temperature deposition (well-ordered islands in the channel) and a subsequent low temperature deposition (continuous film formation for low contact resistance) we were able to prepare very thin (8 ML) pentacene transistors of comparably high mobility. PMID:26543442

America's Urban Forests: Keeping Our Cities Cool

NASA Technical Reports Server (NTRS)

Luvall, Jeffrey C.; Quattrochi, Dale A.

1997-01-01

The additional heating of the air over the city is the result of the replacement of naturally vegetated surfaces with those composed of asphalt, concrete, rooftops and other man-made materials. The temperatures of these artificial surfaces can be 20 to 40 C higher than vegetated surfaces. Materials such as asphalt store much of the sun's energy and remains hot long after sunset. This produces a dome of elevated air temperatures 5 to 8 C greater over the city, compared to the air temperatures over adjacent rural areas. This effect is called the "urban heat island". Tree canopies can reduce the urban heat island effect by dissipating the solar energy received by transpiring water from leaf surfaces which cools the air by taking "heat" from the air to evaporate the water and by shading surfaces like asphalt, roofs, and concrete parking lots which prevents initial heating and storage of heat. It is difficult to take enough temperature measurements over a large city area to characterize the surface temperature variability and quantify the temperature reduction effects of tree canopies. However, the use of remotely sensed thermal data from airborne scanners are ideal for the task. In a study funded by NASA, a series of flights over Huntsville AL were performed in September 1994 and over Atlanta in May 1997. In this article we will examine the techniques of analyzing remotely sensed data for measuring the effect of tree canopies in reducing the urban heat island effect.

Ocular surface temperature in patients with evaporative and aqueous-deficient dry eyes: a thermographic approach.

PubMed

Matteoli, S; Favuzza, E; Mazzantini, L; Aragona, P; Cappelli, S; Corvi, A; Mencucci, R

2017-07-26

In recent decades infrared thermography (IRT) has facilitated accurate quantitative measurements of the ocular surface temperature (OST), applying a non-invasive procedure. The objective of this work was to develop a procedure based on IRT, which allows characterizing of the cooling of the ocular surface of patients suffering from dry eye syndrome, and distinguishing among patients suffering from aqueous deficient dry eye (ADDE) and evaporative dry eyes (EDE). All patients examined (34 females and 4 males, 23-84 years) were divided into two groups according to their Schirmer I result (⩽ 7 mm for ADDE and  >  7 mm for EDE), and the OST was recorded for 7 s at 30 Hz. For each acquisition, the temperatures of the central cornea (CC) as well as those of both temporal and nasal canthi were investigated. Findings showed that the maximum temperature variation (up to 0.75  ±  0.29 °C) was at the CC for both groups. Furthermore, patients suffering from EDE tended to have a higher initial OST than those with ADDE, explained by the greater quantity of the tear film, evenly distributed over the entire ocular surface, keeping the OST higher initially. Results also showed that EDE patients had an average cooling rate higher than those suffering from ADDE, confirming the excessive evaporation of the tear film. Ocular thermography paves the way to become an effective tool for differentiating between the two different etiologies of dry eye syndrome.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dong, B.; Valdes, P.J.

The U.K. University Global Atmospheric Modeling Programme GCM is used to investigate whether the growth of Northern Hemisphere ice sheets could have been initiated by changes of orbital parameters and sea surface temperatures. Two different orbital configurations, corresponding to the present day and 115 kyr BP are used. The reduced summer solar insolation in the Northern Hemisphere results in a decrease of the surface temperature by 4{degrees} to 10{degrees}C in the northern continents and to perennial snow in some high-latitude regions. Therefore, the model results support the hypothesis that a deficit of summer insolation can create conditions favorable for initiationmore » of ice sheet growth in the Northern Hemisphere. A decreased sea surface temperature northward of 65{degrees}N during the Northern Hemisphere summer may contribute to the maintenance of ice sheets. A simple mixed-layer ocean model coupled to the GCM indicates that the changes of sea surface temperature and extension of sea ice due to insolation changes play an important role in inception of the Fennoscandian, Laurentide, and Cordilleran ice sheets. The model results suggest that the regions of greatest sensitivity for ice initiation are the Canadian Archipelago, Baffin Island, Tibetan Plateau, Scandinavia, Siberia, Alaska, and Keewatin, where changing orbital parameters to 115 kyr BP results in the snow cover remaining throughout the warmer summer, leading to long-term snow accumulation. The model results are in general agreement with geological evidence and are the first time that a GCM coupled with a mixed layer ocean has reproduced the inception of the Northern Hemisphere ice sheets. 69 refs., 21 figs., 3 tabs.« less

Clouds not important for control of short-term surface temperatures

NASA Astrophysics Data System (ADS)

Schultz, Colin

2012-01-01

In two recent papers, R. W. Spencer and W. D. Braswell (Remote Sens., 3(8), 1603- 1613, doi:10.3390/rs3081603, 2011) (SB) and R. S. Lindzen and Y.-S. Choi (Asia Pac. J. Atmos. Sci., 47(4), 377-390, doi:10.1007/s13143-011-0023-x, 2011) (LC) argue that clouds act as a primary initiator of surface temperature changes in Earth's climate system. The two sets of authors reached this conclusion by developing a method that tries to determine the Earth's surface temperature by calculating how much energy is stored in the ocean's upper layers, how much of this heat is transferred to the rest of the climate system, how clouds affect the rate at which energy escapes Earth's atmosphere, and how the surface's energy flux changes with temperature. Both studies spurred substantial debate within the media and the public, with the research by SB causing the editor of the journal in which it was published to resign, claiming it should not have been accepted by the journal. Assessing the two studies, Dessler found what he suggests are a number of methodological errors.

Temperature-responsive chromatography for the separation of biomolecules.

PubMed

Kanazawa, Hideko; Okano, Teruo

2011-12-09

Temperature-responsive chromatography for the separation of biomolecules utilizing poly(N-isopropylacrylamide) (PNIPAAm) and its copolymer-modified stationary phase is performed with an aqueous mobile phase without using organic solvent. The surface properties and function of the stationary phase are controlled by external temperature changes without changing the mobile-phase composition. This analytical system is based on nonspecific adsorption by the reversible transition of a hydrophilic-hydrophobic PNIPAAm-grafted surface. The driving force for retention is hydrophobic interaction between the solute molecules and the hydrophobized polymer chains on the stationary phase surface. The separation of the biomolecules, such as nucleotides and proteins was achieved by a dual temperature- and pH-responsive chromatography system. The electrostatic and hydrophobic interactions could be modulated simultaneously with the temperature in an aqueous mobile phase, thus the separation system would have potential applications in the separation of biomolecules. Additionally, chromatographic matrices prepared by a surface-initiated atom transfer radical polymerization (ATRP) exhibit a strong interaction with analytes, because the polymerization procedure forms a densely packed polymer, called a polymer brush, on the surfaces. The copolymer brush grafted surfaces prepared by ATRP was an effective tool for separating basic biomolecules by modulating the electrostatic and hydrophobic interactions. Applications of thermally responsive columns for the separations of biomolecules are reviewed here. Copyright © 2011 Elsevier B.V. All rights reserved.

Surface temperature determination in surface analytic systems by infrared optical pyrometry

NASA Technical Reports Server (NTRS)

Wheeler, Donald R.; Jones, William R., Jr.; Pepper, Stephen V.

1988-01-01

An IR pyrometric technique for measuring the surface temperatures of metal specimens in an ultrahigh-vacuum analytic chamber is described and demonstrated. The experimental setup comprises a commercial IR microscope with a long-working-distance right-angle objective (focal spot diameter 1 mm at 53 cm), a metal-coated glass vacuum chamber with a Ta-mesh-covered quartz viewport, an Mo specimen stub with an internal heating element, and a Ta disk test specimen with a flat side coated with a high-emissivity graphite film. The results of an initial calibration test are presented graphically and briefly characterized. The measurement error at 450 C is found to be less than 10 C.

The SeaFlux Turbulent Flux Dataset Version 1.0 Documentation

NASA Technical Reports Server (NTRS)

Clayson, Carol Anne; Roberts, J. Brent; Bogdanoff, Alec S.

2012-01-01

Under the auspices of the World Climate Research Programme (WCRP) Global Energy and Water cycle EXperiment (GEWEX) Data and Assessment Panel (GDAP), the SeaFlux Project was created to investigate producing a high-resolution satellite-based dataset of surface turbulent fluxes over the global oceans. The most current release of the SeaFlux product is Version 1.0; this represents the initial release of turbulent surface heat fluxes, associated near-surface variables including a diurnally varying sea surface temperature.

A first-principles study of methyl lactate adsorption on the chiral Cu (643) surface

NASA Astrophysics Data System (ADS)

Yuk, Simuck F.; Asthagiri, Aravind

2014-11-01

We used dispersion-corrected density function theory (DFT) to investigate the enantiospecific adsorption of R- and S-methyl lactate on the chiral Cu (643)R surface. Initial study of methyl lactate adsorbed on the Cu (111) surface revealed that the most strongly bound states are associated with interaction of the hydroxyl and alkoxide group with the surface. Using dispersion-corrected DFT-derived pre-factors and desorption energies within the Redhead analysis predicts peak temperatures that are in relatively good agreement with experimental values for molecular methyl lactate desorption from both the Cu (111) and Cu (643)R surface. The global minimum of S-methyl lactate is more firmly bound by 9.5 kJ/mol over its enantiomer on the Cu (643)R surface, with a peak temperature difference of 25 K versus an experimental value of 12 K.

Rewetting of Monogroove Heat Pipe in Space Station Radiators

NASA Technical Reports Server (NTRS)

Chan, S. H.; Shen, Ting Rong; Blake, John

1996-01-01

Experimental investigation of the rewetting characteristics of a uniformly heated grooved surface was performed, the results of which are presented in this work. It was found that, for a rewetting fluid of 2-propanol, the rewetting temperature was approx. 93-96 C for the upward-facing case and about 2 C lower for the downwardfacing case. When the initial plate temperature was higher than the rewetting temperature, the rewetting speed decreased with the initial plate temperature. The rewetting speed is also faster in the upward-facing case than in the downward-facing case for the same initial plate temperatures, which indicates a gravitational effect on rewetting. This trend is found to be consistent with the previously investigated end heating condition. The rewetting distance that is predicted by the conduction controlled model is found to be in fair agreement with the experimental data. Also, an apparatus that enables experiments to be performed in a reduced gravitational environment has been built and experiments are currently being performed. The design of this apparatus is presented along with preliminary data.

Optimization of γ-aminobutyric acid production by Lactobacillus plantarum Taj-Apis362 from honeybees.

PubMed

Tajabadi, Naser; Ebrahimpour, Afshin; Baradaran, Ali; Rahim, Raha Abdul; Mahyudin, Nor Ainy; Manap, Mohd Yazid Abdul; Bakar, Fatimah Abu; Saari, Nazamid

2015-04-15

Dominant strains of lactic acid bacteria (LAB) isolated from honey bees were evaluated for their γ-aminobutyric acid (GABA)-producing ability. Out of 24 strains, strain Taj-Apis362 showed the highest GABA-producing ability (1.76 mM) in MRS broth containing 50 mM initial glutamic acid cultured for 60 h. Effects of fermentation parameters, including initial glutamic acid level, culture temperature, initial pH and incubation time on GABA production were investigated via a single parameter optimization strategy. The optimal fermentation condition for GABA production was modeled using response surface methodology (RSM). The results showed that the culture temperature was the most significant factor for GABA production. The optimum conditions for maximum GABA production by Lactobacillus plantarum Taj-Apis362 were an initial glutamic acid concentration of 497.97 mM, culture temperature of 36 °C, initial pH of 5.31 and incubation time of 60 h, which produced 7.15 mM of GABA. The value is comparable with the predicted value of 7.21 mM.

Crystalline TiO 2 grafted with poly(2-methacryloyloxyethyl phosphorylcholine) via surface-initiated atom-transfer radical polymerization

NASA Astrophysics Data System (ADS)

Zhao, Yuancong; Tu, Qiufen; Wang, Jin; Huang, Qiongjian; Huang, Nan

2010-12-01

Crystalline TiO 2 films were prepared by unbalanced magnetron sputtering and the structure was confirmed by XRD. An organic layer of 11-hydroxyundecylphosphonic acid (HUPA) was prepared on the TiO 2 films by self-assembling, and the HUPA on TiO 2 films was confirmed by FTIR analysis. Simultaneously, hydroxyl groups were introduced in the phosphonic acid molecules to provide a functionality for further chemical modification. 2-Methacryloyloxyethyl phosphorylcholine (MPC), a biomimetic monomer, was chemically grafted on the HUPA surfaces at room temperature by surface-initiated atom-transfer radical polymerization. The surface characters of TiO 2 films modified by poly-MPC were confirmed by FTIR, XPS and SEM analysis. Platelet adhesion experiment revealed that poly-MPC modified surface was effective to inhibit platelet adhesion in vitro.

On the habitability of a stagnant-lid Earth

NASA Astrophysics Data System (ADS)

Tosi, Nicola; Stracke, Barbara; Godolt, Mareike; Ruedas, Thomas; Grenfell, John Lee; Höning, Dennis; Nikolaou, Athanasia; Plesa, Ana-Catalina; Breuer, Doris; Spohn, Tilman

2016-04-01

Whether plate tectonics is a recurrent feature of terrestrial bodies orbiting other stars or is unique to the Earth is unknown. The stagnant-lid may rather be the most common tectonic mode through which terrestrial bodies operate. Here we model the thermal history of the mantle, the outgassing evolution of H2O and CO2, and the resulting climate of a hypothetical planet with the same mass, radius, and composition as the Earth, but lacking plate tectonics. We employ a 1-D model of parameterized stagnant-lid convection to simulate the evolution of melt generation, crust production, and volatile extraction over a timespan of 4.5 Gyr, focusing on the effects of three key mantle parameters: the initial temperature, which controls the overall volume of partial melt produced; the initial water content, which affects the mantle rheology and solidus temperature; and the oxygen fugacity, which is employed in a model of redox melting to determine the amount of carbon stored in partial melts. We assume that the planet lost its primordial atmosphere and use the H2O and CO2 outgassed from the interior to build up a secondary atmosphere over time. Furthermore, we assume that the planet may possess an Earth-like ocean. We calculate the atmospheric pressure based on the solubility of H2O and CO2 in basaltic magmas at the evolving surface pressure conditions. We then employ a 1-D radiative-convective, cloud-free stationary atmospheric model to calculate the resulting atmospheric temperature, pressure and water content, and the corresponding boundaries of the habitable zone (HZ) accounting for the evolution of the Sun's luminosity with time but neglecting escape processes. The interior evolution is characterized by a large initial production of partial melt accompanied by the formation of crust that rapidly grows until its thickness matches that of the stagnant lid so that the convecting sublithospheric mantle prevents further crustal growth. Even for initial water concentrations in excess of thousands of ppm, the high solubility of water in surface magmas limits the maximal partial pressure of atmospheric H2O to a few tens of bars, which places de facto an upper bound on the amount of water that can be delivered to the surface and atmosphere from the interior. The relatively low solubility of CO2 causes instead most of the carbon contained in surface melts to be outgassed. As a consequence, the partial pressure of atmospheric CO2 is largely controlled by the redox state of the mantle, with values that range from a few up to tens of bars for oxygen fugacities between the iron-wüstite buffer and one log-unit above it. At 1 AU and for most cases, liquid water on the surface is possible, hence the planets considered would be regarded as habitable although the atmospheric temperature may be well above the temperature limits for terrestrial life. The inner edge of the HZ depends on the amount of outgassed H2O and is located further away from the star if no initial water ocean is assumed. The outer edge of the HZ is controlled by the amount of outgassed CO2, hence by the assumed redox state of the mantle and its initial temperature.

Performance and Structural Evolution of Nano-Scale Infiltrated Solid Oxide Fuel Cell Cathodes

NASA Astrophysics Data System (ADS)

Call, Ann Virginia

Nano-structured mixed ionic and electronic conducting (MIEC) materials have garnered intense interest in electrode development for solid oxide fuel cells due to their high surface areas which allow for effective catalytic activity and low polarization resistances. In particular, composite solid oxide fuel cell (SOFC) cathodes consisting of ionic conducting scaffolds infiltrated with MIEC nanoparticles have exhibited some of the lowest reported polarization resistances. In order for cells utilizing nanostructured moRPhologies to be viable for commercial implementation, more information on their initial performance and long term stability is necessary. In this study, symmetric cell cathodes were prepared via wet infiltration of Sr0.5Sm 0.5CoO3 (SSC) nano-particles via a nitrate process into porous Ce0.9Gd0.1O1.95 (GDC) scaffolds to be used as a model system to investigate performance and structural evolution. Detailed analysis of the cells and cathodes was carried out using electrochemical impedance spectroscopy (EIS). Initial polarization resistances (RP) as low as 0.11 O cm2 at 600ºC were obtained for these SSC-GDC cathodes, making them an ideal candidate for studying high performance nano-structured electrodes. The present results show that the infiltrated cathode microstructure has a direct impact on the initial performance of the cell. Small initial particle sizes and high infiltration loadings (up to 30 vol% SSC) improved initial RP. A simple microstructure-based electrochemical model successfully explained these trends in RP. Further understanding of electrode performance was gleaned from fitting EIS data gathered under varying temperatures and oxygen partial pressures to equivalent circuit models. Both RQ and Gerischer impedance elements provided good fits to the main response in the EIS data, which was associated with the combination of oxygen surface exchange and oxygen diffusion in the electrode. A gas diffusion response was also observed at relatively low pO2. The cells were subjected to life testing at temperatures between 650°C and 800°C for as long as 1500 h. EIS measurements, carried out periodically during the life tests, were done in air at 600°C, a typical expected intermediate-temperature SOFC operating temperature. These were accelerated tests because the aging temperatures > 600ºC should accelerate most degradation processes such as nano-particle coarsening. Long-term RP versus time data was fitted to a combined surface resistance and coarsening kinetics model, and a t0.25 power law coarsening model was found to provide the best fits to the data, suggesting that surface diffusion is the dominant mass transport pathway in SSC-GDC infiltrated cathodes. That is, cathode degradation was due primarily to the coarsening-induced decrease in active SSC surface area. Scanning electron microscopy (SEM) performed after electrochemical life testing confirmed the extent of coarsening of the SSC nanoparticles. The model is used to make predictions regarding long-term stability of infiltrated SSC electrodes, and is also compared with prior results on a similar perovskite MIEC electrode, LSCF. An important new finding is that increasing infiltration loadings yields a marked decrease in the long term degradation rate. Predictions based on accelerated life tests found the lowest possible operating temperature while achieving a degradation rate of 0.5% per kh is 595°C, corresponding to an initial particle size of 40 nm.

46 CFR 164.008-4 - Test requirements.

Code of Federal Regulations, 2011 CFR

2011-10-01

... thermocouples on the unexposed surface described in § 164.008-3(f)(2) will not rise more than 139 °C. (250 °F..., rise more than 225 °C. (405 °F.) above the initial temperature at the end of 15 minutes. When failure is due to excessive temperature rise on the joint, consideration will be given to alternate joint...

46 CFR 164.008-4 - Test requirements.

Code of Federal Regulations, 2010 CFR

2010-10-01

... thermocouples on the unexposed surface described in § 164.008-3(f)(2) will not rise more than 139 °C. (250 °F..., rise more than 225 °C. (405 °F.) above the initial temperature at the end of 15 minutes. When failure is due to excessive temperature rise on the joint, consideration will be given to alternate joint...

The effects of Venus' thermal structure on buoyant magma ascent

NASA Technical Reports Server (NTRS)

Sakimoto, S. E. H.; Zuber, M. T.

1992-01-01

The recent Magellan images have revealed a broad spatial distribution of surface volcanism on Venus. Previous work in modeling the ascent of magma on both Venus and Earth has indicated that the planetary thermal structure significantly influences the magmatic cooling rates and thus the amount of magma that can be transported to the surface before solidification. In order to understand which aspects of the thermal structure have the greatest influence on the cooling of ascending magma, we have constructed magma cooling curves for both plutonic and crack buoyant ascent mechanisms, and evaluated the curves for variations in the planetary mantle temperature, thermal gradient curvature with depth, surface temperature gradient, and surface temperature. The planetary thermal structure is modeled as T/T(sub 0) = 1-tau(1-Z/Z(sub 0)(exp n), where T is the temperature, T(sub 0) is the source depth temperature, tau = 1-(T(sub s)/T(sub 0)) where T(sub s) is the planetary surface temperature, Z is the depth, Z(sub 0) is the source depth, and n is a constant that controls thermal gradient curvature with depth. The equation is used both for mathematical convenience and flexibility, as well as its fit to the thermal gradients predicted by the cooling half-space models. We assume a constant velocity buoyant ascent, body-averaged magma temperatures and properties, an initially crystal-free magma, and the same liquidus and solidus for both Venus and Earth.

Thermoelastic Stress Analysis: An NDE Tool for the Residual Stress Assessment of Metallic Alloys

NASA Technical Reports Server (NTRS)

Gyekenyesi, Andrew L.; Baaklini, George Y.

2000-01-01

During manufacturing, certain propulsion components that will be used in a cyclic fatigue environment are fabricated to contain compressive residual stresses on their surfaces because these stresses inhibit the nucleation of cracks. Overloads and elevated temperature excursions cause the induced residual stresses to dissipate while the component is still in service, lowering its resistance to crack initiation. Research at the NASA Glenn Research Center at Lewis Field has focused on employing the Thermoelastic Stress Analysis technique (TSA, also recognized as SPATE: Stress Pattern Analysis by Thermal Emission) as a tool for monitoring the residual stress state of propulsion components. TSA is based on the fact that materials experience small temperature changes when they are compressed or expanded. When a structure is cyclically loaded (i.e., cyclically compressed and expanded), the resulting surface-temperature profile correlates to the stress state of the structure s surface. The surface-temperature variations resulting from a cyclic load are measured with an infrared camera. Traditionally, the temperature amplitude of a TSA signal has been theoretically defined to be linearly dependent on the cyclic stress amplitude. As a result, the temperature amplitude resulting from an applied cyclic stress was assumed to be independent of the cyclic mean stress.

An experimental study on the thermal characteristics and heating effect of arc-fault from Cu core in residential electrical wiring fires

PubMed Central

Du, Jian-Hua; Zeng, Yi; Pan, Leng; Zhang, Ren-Cheng

2017-01-01

The characteristics of a series direct current (DC) arc-fault including both electrical and thermal parameters were investigated based on an arc-fault simulator to provide references for multi-parameter electrical fire detection method. Tests on arc fault behavior with three different initial circuit voltages, resistances and arc gaps were conducted, respectively. The influences of circuit conditions on arc dynamic image, voltage, current or power were interpreted. Also, the temperature rises of electrode surface and ambient air were studied. The results showed that, first, significant variations of arc structure and light emitting were observed under different conditions. A thin outer burning layer of vapor generated from electrodes with orange light was found due to the extremely high arc temperature. Second, with the increasing electrode gap in discharging, the arc power was shown to have a non monotonic relationship with arc length for constant initial circuit voltage and resistance. Finally, the temperature rises of electrode surface caused by heat transfer from arc were found to be not sensitive with increasing arc length due to special heat transfer mechanism. In addition, temperature of ambient air showed a large gradient in radial direction of arc. PMID:28797055

An experimental study on the thermal characteristics and heating effect of arc-fault from Cu core in residential electrical wiring fires.

PubMed

Du, Jian-Hua; Tu, Ran; Zeng, Yi; Pan, Leng; Zhang, Ren-Cheng

2017-01-01

The characteristics of a series direct current (DC) arc-fault including both electrical and thermal parameters were investigated based on an arc-fault simulator to provide references for multi-parameter electrical fire detection method. Tests on arc fault behavior with three different initial circuit voltages, resistances and arc gaps were conducted, respectively. The influences of circuit conditions on arc dynamic image, voltage, current or power were interpreted. Also, the temperature rises of electrode surface and ambient air were studied. The results showed that, first, significant variations of arc structure and light emitting were observed under different conditions. A thin outer burning layer of vapor generated from electrodes with orange light was found due to the extremely high arc temperature. Second, with the increasing electrode gap in discharging, the arc power was shown to have a non monotonic relationship with arc length for constant initial circuit voltage and resistance. Finally, the temperature rises of electrode surface caused by heat transfer from arc were found to be not sensitive with increasing arc length due to special heat transfer mechanism. In addition, temperature of ambient air showed a large gradient in radial direction of arc.

Use of Ocean Remote Sensing Data to Enhance Predictions with a Coupled General Circulation Model

NASA Technical Reports Server (NTRS)

Rienecker, Michele M.

1999-01-01

Surface height, sea surface temperature and surface wind observations from satellites have given a detailed time sequence of the initiation and evolution of the 1997/98 El Nino. The data have beet complementary to the subsurface TAO moored data in their spatial resolution and extent. The impact of satellite observations on seasonal prediction in the tropical Pacific using a coupled ocean-atmosphere general circulation model will be presented.

Optimizing Surface Winds using QuikSCAT Measurements in the Mediterranean Sea During 2000-2006

DTIC Science & Technology

2009-02-28

Temperature and salinity from the 1/4° Generalized Digital Envi- ronmental Model ( GDEM ) monthly climatology developed at the Naval Oceanographic...monthly GDEM climatology was also used for relaxation of the sea-surface salinity (SSS) to keep the surface salinity balance on track. The net heat...salinity from the GDEM clima- tology are used to initialize themodel. There is a relaxation tomonthly mean SSS fromGDEM. The referencemixed-layer

Initialization of a mesoscale model for April 10, 1979, using alternative data sources

NASA Technical Reports Server (NTRS)

Kalb, M. W.

1984-01-01

A 35 km grid limited area mesoscale model was initialized with high density SESAME radiosonde data and high density TIROS-N satellite temperature profiles for April 10, 1979. These data sources were used individually and with low level wind fields constructed from surface wind observations. The primary objective was to examine the use of satellite temperature data for initializing a mesoscale model by comparing the forecast results with similar experiments employing radiosonde data. The impact of observed low level winds on the model forecasts was also investigated with experiments varying the method of insertion. All forecasts were compared with each other and with mesoscale observations for precipitation, mass and wind structure. Several forecasts produced convective precipitation systems with characteristics satisfying criteria for a mesoscale convective complex. High density satellite temperature data and balanced winds can be used in a mesoscale model to produce forecasts which verify favorably with observations.

A physically based model of global freshwater surface temperature

NASA Astrophysics Data System (ADS)

Beek, Ludovicus P. H.; Eikelboom, Tessa; Vliet, Michelle T. H.; Bierkens, Marc F. P.

2012-09-01

Temperature determines a range of physical properties of water and exerts a strong control on surface water biogeochemistry. Thus, in freshwater ecosystems the thermal regime directly affects the geographical distribution of aquatic species through their growth and metabolism and indirectly through their tolerance to parasites and diseases. Models used to predict surface water temperature range between physically based deterministic models and statistical approaches. Here we present the initial results of a physically based deterministic model of global freshwater surface temperature. The model adds a surface water energy balance to river discharge modeled by the global hydrological model PCR-GLOBWB. In addition to advection of energy from direct precipitation, runoff, and lateral exchange along the drainage network, energy is exchanged between the water body and the atmosphere by shortwave and longwave radiation and sensible and latent heat fluxes. Also included are ice formation and its effect on heat storage and river hydraulics. We use the coupled surface water and energy balance model to simulate global freshwater surface temperature at daily time steps with a spatial resolution of 0.5° on a regular grid for the period 1976-2000. We opt to parameterize the model with globally available data and apply it without calibration in order to preserve its physical basis with the outlook of evaluating the effects of atmospheric warming on freshwater surface temperature. We validate our simulation results with daily temperature data from rivers and lakes (U.S. Geological Survey (USGS), limited to the USA) and compare mean monthly temperatures with those recorded in the Global Environment Monitoring System (GEMS) data set. Results show that the model is able to capture the mean monthly surface temperature for the majority of the GEMS stations, while the interannual variability as derived from the USGS and NOAA data was captured reasonably well. Results are poorest for the Arctic rivers because the timing of ice breakup is predicted too late in the year due to the lack of including a mechanical breakup mechanism. Moreover, surface water temperatures for tropical rivers were overestimated, most likely due to an overestimation of rainfall temperature and incoming shortwave radiation. The spatiotemporal variation of water temperature reveals large temperature differences between water and atmosphere for the higher latitudes, while considerable lateral transport of heat can be observed for rivers crossing hydroclimatic zones, such as the Nile, the Mississippi, and the large rivers flowing to the Arctic. Overall, our model results show promise for future projection of global surface freshwater temperature under global change.

Impact of Soil Moisture Initialization on Seasonal Weather Prediction

NASA Technical Reports Server (NTRS)

Koster, Randal D.; Suarez, Max J.; Houser, Paul (Technical Monitor)

2002-01-01

The potential role of soil moisture initialization in seasonal forecasting is illustrated through ensembles of simulations with the NASA Seasonal-to-Interannual Prediction Project (NSIPP) model. For each boreal summer during 1997-2001, we generated two 16-member ensembles of 3-month simulations. The first, "AMIP-style" ensemble establishes the degree to which a perfect prediction of SSTs would contribute to the seasonal prediction of precipitation and temperature over continents. The second ensemble is identical to the first, except that the land surface is also initialized with "realistic" soil moisture contents through the continuous prior application (within GCM simulations leading up to the start of the forecast period) of a daily observational precipitation data set and the associated avoidance of model drift through the scaling of all surface prognostic variables. A comparison of the two ensembles shows that soil moisture initialization has a statistically significant impact on summertime precipitation and temperature over only a handful of continental regions. These regions agree, to first order, with regions that satisfy three conditions: (1) a tendency toward large initial soil moisture anomalies, (2) a strong sensitivity of evaporation to soil moisture, and (3) a strong sensitivity of precipitation to evaporation. The degree to which the initialization improves forecasts relative to observations is mixed, reflecting a critical need for the continued development of model parameterizations and data analysis strategies.

Design and test of a compact optics system for the pool boiling experiment

NASA Technical Reports Server (NTRS)

Ling, Jerri S.; Laubenthal, James R.

1990-01-01

The experiment described seeks to improve the understanding of the fundamental mechanisms that constitute nucleate pool boiling. The vehicle for accomplishing this is an investigation, including tests to be conducted in microgravity and coupled with appropriate analyses, of the heat transfer and vapor bubble dynamics associated with nucleation, bubble growth/collapse and subsequent motion, considering the interrelations between buoyancy, momentum and surface tension which will govern the motion of the vapor and surrounding liquid, as a function of the heating rate at the heat transfer surface and the temperature level and distribution in the bulk liquid. The experiment is designed to be contained within the confines of a Get-Away-Special Canister (GAS Can) installed in the bay of the space shuttle. When the shuttle reaches orbit, the experiment will be turned on and testing will proceed automatically. In the proposed Pool Boiling Experiment a pool of liquid, initially at a precisely defined pressure and temperature, will be subjected to a step imposed heat flux from a semitransparent thin-film heater forming part of one wall of the container such that boiling is initiated and maintained for a defined period of time at a constant pressure level. Transient measurements of the heater surface and fluid temperatures near the surface will be made, noting especially the conditions at the onset of boiling, along with motion photography of the boiling process in two simultaneous views, from beneath the heating surface and from the side. The conduct of the experiment and the data acquisition will be completely automated and self-contained. For the initial flight, a total of nine tests are proposed, with three levels of heat flux and three levels of subcooling. The design process used in the development and check-out of the compact photographic/optics system for the Pool Boiling Experiment is documented.

Response of the Vegetation-Climate System to High Temperature (Invited)

NASA Astrophysics Data System (ADS)

Berry, J. A.

2009-12-01

High temperature extremes may lead to inhibition of photosynthesis and stomatal closure at the leaf scale. When these responses occur over regional scales, they can initiate a positive feedback loop in the coupled vegetation-climate system. The fraction of net radiation that is used by the land surface to evaporate water decreases leading to deeper, drier boundary layers, fewer clouds, increased solar radiation reaching the surface, and possibility reduced precipitation. These interactions within the vegetation-climate system may amplify natural (or greenhouse gas forced) variations in temperature and further stress the vegetation. Properly modeling of this system depends, among other things, on getting the plant responses to high temperature correct. I will review the current state of this problem and present some studies of rain forest trees to high temperature and drought conducted in the Biosphere 2 enclosure that illustrate how experiments in controlled systems can contribute to our understanding of complex systems to extreme events.

Formation mechanism and mechanics of dip-pen nanolithography using molecular dynamics.

PubMed

Wu, Cheng-Da; Fang, Te-Hua; Lin, Jen-Fin

2010-03-02

Molecular dynamics simulations are used to investigate the mechanisms of molecular transference, pattern formation, and mechanical behavior in the dip-pen nanolithography (DPN) process. The effects of deposition temperature were studied using molecular trajectories, the meniscus characteristic, surface absorbed energy, and pattern formation analysis. At the first transferred stage (at the initial indentation depth), the conformation of SAM molecules lies almost on the substrate surface. The molecules start to stand on the substrate due to the pull and drag forces at the second transferred stage (after the tip is pulled up). According to the absorbed energy behavior, the second transferred stage has larger transferred amounts and the transfer rate is strongly related to temperature. When molecules were deposited at low temperature (e.g., room temperature), the pattern shape was more highly concentrated. The pattern shape at high temperatures expanded and the area increased because of good molecular diffusion.

Predicting the Dominant Patterns of Subseasonal Variability of Wintertime Surface Air Temperature in Extratropical Northern Hemisphere

NASA Astrophysics Data System (ADS)

Lin, Hai

2018-05-01

Skillfully predicting persistent extreme temperature anomalies more than 10 days in advance remains a challenge although it is of great value to the society. Here the two leading modes of subseasonal variability of surface air temperature over the extratropical Northern Hemisphere in boreal winter are identified with pentad (5 days) averaged data. They are well separated geographically, dominating temperature variability in North America and Eurasia, respectively. There exists a two-pentad lagged correlation between these two modes, implying an intercontinental link of temperature variability. Forecast skill of these two modes is evaluated based on three operational subseasonal prediction models. The results show that useful forecasts of the Eurasian mode (EOF2) can be achieved four pentads in advance, which is more skillful than the North American mode (EOF1). EOF2 is found to benefit from the Madden-Julian Oscillation signal in the initial condition.

Application of Reflected Global Navigation Satellite System (GNSS-R) Signals in the Estimation of Sea Roughness Effects in Microwave Radiometry

NASA Technical Reports Server (NTRS)

Voo, Justin K.; Garrison, James L.; Yueh, Simon H.; Grant, Michael S.; Fore, Alexander G.; Haase, Jennifer S.; Clauss, Bryan

2010-01-01

In February-March 2009 NASA JPL conducted an airborne field campaign using the Passive Active L-band System (PALS) and the Ku-band Polarimetric Scatterometer (PolSCAT) collecting measurements of brightness temperature and near surface wind speeds. Flights were conducted over a region of expected high-speed winds in the Atlantic Ocean, for the purposes of algorithm development for salinity retrievals. Wind speeds encountered were in the range of 5 to 25 m/s during the two weeks deployment. The NASA-Langley GPS delay-mapping receiver (DMR) was also flown to collect GPS signals reflected from the ocean surface and generate post-correlation power vs. delay measurements. This data was used to estimate ocean surface roughness and a strong correlation with brightness temperature was found. Initial results suggest that reflected GPS signals, using small low-power instruments, will provide an additional source of data for correcting brightness temperature measurements for the purpose of sea surface salinity retrievals.

Infrared Thermography Flight Experimentation

NASA Technical Reports Server (NTRS)

Blanchard, Robert C.; Carter, Matthew L.; Kirsch, Michael

2003-01-01

Analysis was done on IR data collected by DFRC on May 8, 2002. This includes the generation of a movie to initially examine the IR flight data. The production of the movie was challenged by the volume of data that needed to be processed, namely 40,500 images with each image (256 x 252) containing over 264 million points (pixel depth 4096). It was also observed during the initial analysis that the RTD surface coating has a different emissivity than the surroundings. This fact added unexpected complexity in obtaining a correlation between RTD data and IR data. A scheme was devised to generate IR data near the RTD location which is not affected by the surface coating This scheme is valid as long as the surface temperature as measured does not change too much over a few pixel distances from the RTD location. After obtaining IR data near the RTD location, it is possible to make a direct comparison with the temperature as measured during the flight after adjusting for the camera s auto scaling. The IR data seems to correlate well to the flight temperature data at three of the four RID locations. The maximum count intensity occurs closely to the maximum temperature as measured during flight. At one location (RTD #3), there is poor correlation and this must be investigated before any further progress is possible. However, with successful comparisons at three locations, it seems there is great potential to be able to find a calibration curve for the data. Moreover, as such it will be possible to measure temperature directly from the IR data in the near future.

On the Evolution of Terrestrial Planets: Implications of Evolutionary Paths and Evolving Lid-States

NASA Astrophysics Data System (ADS)

Weller, M. B.; Lenardic, A.

2015-12-01

Growing geodynamic and geochemical evidence suggests that plate tectonics may not have operated on the early Earth, with both the timing of its onset and the length of its activity far from certain [e.g., 1, 2, and references therein]. Accordingly, information from current observations and processes have the potential of sampling portions of the Earth that has both formed under and been modified by differing tectonic regimes. Here we use coupled 3D mantle convection and planetary tectonics simulations to explore evolutionary paths and planetary tectonic regimes. Early in the geologic lifetime of a terrestrial planet, high mantle temperatures favour stagnant-lids. As radiogenics decay, an initial stagnant-lid may yield into a high temperature mobile-lid state. The transition from an initial stagnant-lid is a function of yield strength, in addition to both internal and surface temperatures. Each lid-state has specific diagnostics and implications for internal parameters, and consequently planetary evolution. The implication within this framework is that a system with a different thermal evolution has the potential to migrate through tectonic regimes at the same 'thermal time' (e.g. temperature), but very different 'temporal times'. This indicate that multiple modes of convection and surface tectonics can potentially operate on a single planetary body at different times in its evolution, as consequence of changing internal parameters, surface temperatures, and differing thermal histories. We will discuss the implications of terrestrial worlds that can alternate, and be offset between multiple tectonic states over giga-year timescales. [1] O'Neill et. al. (2013b) Geol. Soc. London; [2] Weller et al. (2015) EPSL

High temperature measurement of water vapor absorption

NASA Technical Reports Server (NTRS)

Keefer, Dennis; Lewis, J. W. L.; Eskridge, Richard

1985-01-01

An investigation was undertaken to measure the absorption coefficient, at a wavelength of 10.6 microns, for mixtures of water vapor and a diluent gas at high temperature and pressure. The experimental concept was to create the desired conditions of temperature and pressure in a laser absorption wave, similar to that which would be created in a laser propulsion system. A simplified numerical model was developed to predict the characteristics of the absorption wave and to estimate the laser intensity threshold for initiation. A non-intrusive method for temperature measurement utilizing optical laser-beam deflection (OLD) and optical spark breakdown produced by an excimer laser, was thoroughly investigated and found suitable for the non-equilibrium conditions expected in the wave. Experiments were performed to verify the temperature measurement technique, to screen possible materials for surface initiation of the laser absorption wave and to attempt to initiate an absorption wave using the 1.5 kW carbon dioxide laser. The OLD technique was proven for air and for argon, but spark breakdown could not be produced in helium. It was not possible to initiate a laser absorption wave in mixtures of water and helium or water and argon using the 1.5 kW laser, a result which was consistent with the model prediction.

Effects of Refractive Index and Diffuse or Specular Boundaries on a Radiating Isothermal Layer

NASA Technical Reports Server (NTRS)

Siegel, R.; Spuckler, C. M.

1994-01-01

Equilibrium temperatures of an absorbing-emitting layer were obtained for exposure to incident radiation and with the layer boundaries either specular or diffuse. For high refractive indices the surface condition can influence the radiative heat balance if the layer optical thickness is small. Hence for a spectrally varying absorption coefficient the layer temperature is affected if there is significant radiative energy in the spectral range with a small absorption coefficient. Similar behavior was obtained for transient radiative cooling of a layer where the results are affected by the initial temperature and hence the fraction of energy radiated in the short wavelength region where the absorption coefficient is small. The results are a layer without internal scattering. If internal scattering is significant, the radiation reaching the internal surface of a boundary is diffused and the effect of the two different surface conditions would become small.

Thermal-mechanical coupling effect on initial stage oxidation of Si(100) surface

NASA Astrophysics Data System (ADS)

Sun, Yu; Liu, Yilun; Chen, Xuefeng; Zhai, Zhi; Izumi, Satoshi

2018-04-01

The initial stage oxidation of biaxially strained Si(100) at temperatures ranging from 300 K to 1200 K has been investigated by Reactive Force Field Molecular Dynamics simulations. We reported that the oxidation process involving the reaction rate and the amount of absorbed O atoms could be enhanced by the coupling effect of higher temperatures and larger external tension. By fitting the simulation results, the relationship between absorbed oxygen and the coupling of temperature and strain was obtained. In probing the mechanism, we observed that there was a ballistic transport of O atoms, displaying an enhancement of inward penetration by external tension. Since such an inward transport was favored by thermal actuation, more O atoms penetrated into deeper layers when the 9% strained Si oxidized at 1200 K. Moreover, the evolution of stress in the surface region during the oxidation process was discussed, as well as the related oxide structure and the film quality. These present results may provide a way to understand the thermally-mechanically coupled chemical reactions and propose an effective approach to optimize microscale component processing in the electronic field.

The GEOS-iODAS: Description and Evaluation

NASA Technical Reports Server (NTRS)

Vernieres, Guillaume; Rienecker, Michele M.; Kovach, Robin; Keppenne, Christian L.

2012-01-01

This report documents the GMAO's Goddard Earth Observing System sea ice and ocean data assimilation systems (GEOS iODAS) and their evolution from the first reanalysis test, through the implementation that was used to initialize the GMAO decadal forecasts, and to the current system that is used to initialize the GMAO seasonal forecasts. The iODAS assimilates a wide range of observations into the ocean and sea ice components: in-situ temperature and salinity profiles, sea level anomalies from satellite altimetry, analyzed SST, and sea-ice concentration. The climatological sea surface salinity is used to constrain the surface salinity prior to the Argo years. Climatological temperature and salinity gridded data sets from the 2009 version of the World Ocean Atlas (WOA09) are used to help constrain the analysis in data sparse areas. The latest analysis, GEOS ODAS5.2, is diagnosed through detailed studies of the statistics of the innovations and analysis departures, comparisons with independent data, and integrated values such as volume transport. Finally, the climatologies of temperature and salinity fields from the Argo era, 2002-2011, are presented and compared with the WOA09.

Tracking Internal Temperature and Structural Dynamics during Nail Penetration of Lithium-Ion Cells

DOE PAGES

Finegan, Donal P.; Tjaden, Bernhard; M. M. Heenan, Thomas; ...

2017-10-31

Mechanical abuse of lithium-ion batteries is widely used during testing to induce thermal runaway, characterize associated risks, and expose cell and module vulnerabilities. But, the repeatability of puncture or 'nail penetration' tests is a key issue as there is often a high degree of variability in the resulting thermal runaway process. Here, the failure mechanisms of 18650 cells punctured at different locations and orientations are characterized with respect to their internal structural degradation, and both their internal and surface temperature, all of which are monitored in real time. The initiation and propagation of thermal runaway is visualized via high-speed synchrotronmore » X-ray radiography at 2000 frames per second, and the surface and internal temperatures are recorded via infrared imaging and a thermocouple embedded in the tip of the penetrating nail, respectively. The influence of the nail, as well as how and where it penetrates the cell, on the initiation and propagation of thermal runaway is described and the suitability of this test method for representing in-field failures is discussed.« less

A revised approach for an exact analytical solution for thermal response in biological tissues significant in therapeutic treatments.

PubMed

Dutta, Jaideep; Kundu, Balaram

2017-05-01

The genesis of the present research paper is to develop a revised exact analytical solution of thermal profile of 1-D Pennes' bioheat equation (PBHE) for living tissues influenced in thermal therapeutic treatments. In order to illustrate the temperature distribution in living tissue both Fourier and non-Fourier model of 1-D PBHE has been solved by 'Separation of variables' technique. Till date most of the research works have been carried out with the constant initial steady temperature of tissue which is not at all relevant for the biological body due to its nonhomogeneous living cells. There should be a temperature variation in the body before the therapeutic treatment. Therefore, a coupled heat transfer in skin surface before therapeutic heating must be taken account for establishment of exact temperature propagation. This approach has not yet been considered in any research work. In this work, an initial condition for solving governing differential equation of heat conduction in biological tissues has been represented as a function of spatial coordinate. In a few research work, initial temperature distribution with PBHE has been coupled in such a way that it eliminates metabolic heat generation. The study has been devoted to establish the comparison of thermal profile between present approach and published theoretical approach for particular initial and boundary conditions inflicted in this investigation. It has been studied that maximum temperature difference of existing approach for Fourier temperature distribution is 19.6% while in case of non-Fourier, it is 52.8%. We have validated our present analysis with experimental results and it has been observed that the temperature response based on the spatial dependent variable initial condition matches more accurately than other approaches. Copyright © 2017 Elsevier Ltd. All rights reserved.

Isotherm and thermodynamic studies of Zn (II) adsorption on lignite and coconut shell-based activated carbon fiber.

PubMed

Shrestha, Sohan; Son, Guntae; Lee, Seung Hwan; Lee, Tae Gwan

2013-08-01

The Zn (II) adsorption capacity of lignite and coconut shell-based activated carbon fiber (ACF) was evaluated as a function of initial Zn (II) concentration, temperature and contact time in batch adsorption process in this study. Adsorption uptake increased with initial Zn (II) concentration and temperature. Optimal contact time for the adsorption of Zn (II) ions onto lignite and coconut shell-based ACF was found to be 50 min. Removal percentage decreased from 88.0% to 78.54% with the increment in initial Zn (II) concentration from 5 to 50 mg L(-1). Equilibrium data fit well with Langmuir-I isotherm indicating homogeneous monolayer coverage of Zn (II) ions on the adsorbent surface. Maximum monolayer adsorption capacity of Zn (II) ions on ACF was found to be 9.43 mg g(-1). Surface morphology and functionality of ACF prior to and after adsorption were characterized by electron microscopy and infrared spectroscopy. Various thermodynamic parameters such as standard Gibbs free energy (ΔG°), standard enthalpy (ΔH°), and standard entropy (ΔS°) were evaluated. Copyright © 2013 Elsevier Ltd. All rights reserved.

Remote measurement of soil moisture over vegetation using infrared temperature measurements

NASA Technical Reports Server (NTRS)

Carlson, Toby N.

1991-01-01

Better methods for remote sensing of surface evapotranspiration, soil moisture, and fractional vegetation cover were developed. The objectives were to: (1) further develop a model of water movement through the soil/plant/atmosphere system; (2) use this model, in conjunction with measurements of infrared surface temperature and vegetation fraction; (3) determine the magnitude of radiometric temperature response to water stress in vegetation; (4) show at what point one can detect that sensitivity to water stress; and (5) determine the practical limits of the methods. A hydrological model that can be used to calculate soil water content versus depth given conventional meteorological records and observations of vegetation cover was developed. An outline of the results of these initiatives is presented.

Analysis of flame spread over multicomponent combustibles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ohtani, H.; Sato, J.

1985-01-01

A theoretical model of volatile component diffusion in the condensed phase is carried out in order to form a basis for predicting the flame spread rate in thermally thick multicomponent combustibles in a non-fluid condensed phase. The fuels could be, e.g., crude oil, heavy oil, or light oil. Mass transfer occurs only by diffusion so the gas phase volatile concentration at the surface is estimated from the condensed phase volatile concentration and the surface temperature, which increases close to the leading flame edge. The flame spread rate is assumed steady. The velocity of the flame spread is shown to bemore » a function of the initial condensed phase temperature and the temperature at the leading flame edge.« less

The dynamics of nucleation and growth of a particle in the ternary alloy melt with anisotropic surface tension.

PubMed

Chen, Ming-Wen; Li, Lin-Yan; Guo, Hui-Min

2017-08-28

The dynamics of nucleation and growth of a particle affected by anisotropic surface tension in the ternary alloy melt is studied. The uniformly valid asymptotic solution for temperature field, concentration field, and interface evolution of nucleation and particle growth is obtained by means of the multiple variable expansion method. The asymptotic solution reveals the critical radius of nucleation in the ternary alloy melt and an inward melting mechanism of the particle induced by the anisotropic effect of surface tension. The critical radius of nucleation is dependent on isotropic surface tension, temperature undercooling, and constitutional undercooling in the ternary alloy melt, and the solute diffusion melt decreases the critical radius of nucleation. Immediately after a nucleus forms in the initial stage of solidification, the anisotropic effect of surface tension makes some parts of its interface grow inward while some parts grow outward. Until the inward melting attains a certain distance (which is defined as "the melting depth"), these parts of interface start to grow outward with other parts. The interface of the particle evolves into an ear-like deformation, whose inner diameter may be less than two times the critical radius of nucleation within a short time in the initial stage of solidification. The solute diffusion in the ternary alloy melt decreases the effect of anisotropic surface tension on the interface deformation.

Seasonal and Interannual Variations of Ice Sheet Surface Elevation at the Summit of Greenland: Observed and Modeled

NASA Technical Reports Server (NTRS)

Zwally, H. Jay; Jun, Li; Koblinsky, Chester J. (Technical Monitor)

2001-01-01

Observed seasonal and interannual variations in the surface elevation over the summit of the Greenland ice sheet are modeled using a new temperature-dependent formulation of firn-densification and observed accumulation variations. The observed elevation variations are derived from ERS (European Remote Sensing)-1 and ERS-2 radar altimeter data for the period between April 1992 and April 1999. A multivariate linear/sine function is fitted to an elevation time series constructed from elevation differences measured by radar altimetry at orbital crossovers. The amplitude of the seasonal elevation cycle is 0.25 m peak-to-peak, with a maximum in winter and a minimum in summer. Inter-annually, the elevation decreases to a minimum in 1995, followed by an increase to 1999, with an overall average increase of 4.2 cm a(exp -1) for 1992 to 1999. Our densification formulation uses an initial field-density profile, the AWS (automatic weather station) surface temperature record, and a temperature-dependent constitutive relation for the densification that is based on laboratory measurements of crystal growth rates. The rate constant and the activation energy commonly used in the Arrhenius-type constitutive relation for firn densification are also temperature dependent, giving a stronger temperature and seasonal amplitudes about 10 times greater than previous densification formulations. Summer temperatures are most important, because of the strong non-linear dependence on temperature. Much of firn densification and consequent surface lowering occurs within about three months of the summer season, followed by a surface build-up from snow accumulation until spring. Modeled interannual changes of the surface elevation, using the AWS measurements of surface temperature and accumulation and results of atmospheric modeling of precipitation variations, are in good agreement with the altimeter observations. In the model, the surface elevation decreases about 20 cm over the seven years due to more compaction driven by increasing summer temperatures. The minimum elevation in 1995 is driven mainly by a temporary accumulation decrease and secondarily by warmer temperatures. However, the overall elevation increase over the seven years is dominated by the accumulation increase in the later years.

Improvement in surface hydrophilicity and resistance to deformation of natural leather through O2/H2O low-temperature plasma treatment

NASA Astrophysics Data System (ADS)

You, Xuewei; Gou, Li; Tong, Xingye

2016-01-01

The natural leather was modified through O2/H2O low-temperature plasma treatment. Surface morphology was characterized by scanning electron microscopy (SEM) and the results showed that the pores on the leather surface became deeper and larger with enhanced permeability of water and vapor. XPS and FTIR-ATR was performed to determine the chemical composition of natural leather surface. Oxygen-containing groups were successfully grafted onto the surface of natural leather and oxygen content increased with longer treatment time. After O2/H2O plasma treatment, initial water contact angle was about 21° and water contact angles were not beyond 55° after being stored for 3 days. Furthermore, the tensile test indicated that the resistance to deformation had a prominent transform without sacrificing the tensile strength.

Factors affecting the simulated trajectory and intensification of Tropical Cyclone Yasi (2011)

NASA Astrophysics Data System (ADS)

Parker, Chelsea L.; Lynch, Amanda H.; Mooney, Priscilla A.

2017-09-01

This study investigates the sensitivity of the simulated trajectory, intensification, and forward speed of Tropical Cyclone Yasi to initial conditions, physical parameterizations, and sea surface temperatures. Yasi was a category 5 storm that made landfall in Queensland, Australia in February 2011. A series of simulations were performed using WRF-ARW v3.4.1 driven by ERA-Interim data at the lateral boundaries. To assess these simulations, a new simple skill score is devised to summarize the deviation from observed conditions at landfall. The results demonstrate the sensitivity to initial condition resolution and the need for a new initialization dataset. Ensemble testing of physics parameterizations revealed strong sensitivity to cumulus schemes, with a trade-off between trajectory and intensity accuracy. The Tiedtke scheme produces an accurate trajectory evolution and landfall location. The Kain Fritch scheme is associated with larger errors in trajectory due to a less active shallow convection over the ocean, leading to warmer temperatures at the 700 mb level and a stronger, more poleward steering flow. However, the Kain Fritsch scheme produces more accurate intensities and translation speeds. Tiedtke-derived intensities were weaker due to suppression of deep convection by active shallow convection. Accurate representation of the sea surface temperature through correcting a newly discovered SST lag in reanalysis data or increasing resolution of SST data can improve the simulation. Higher resolution increases relative vorticity and intensity. However, the sea surface boundary had a more pronounced effect on the simulation with the Tiedtke scheme due to its moisture convergence trigger and active shallow convection over the tropical ocean.

Verification of Experimental Techniques for Flow Surface Determination

NASA Technical Reports Server (NTRS)

Lissenden, Cliff J.; Lerch, Bradley A.; Ellis, John R.; Robinson, David N.

1996-01-01

The concept of a yield surface is central to the mathematical formulation of a classical plasticity theory. However, at elevated temperatures, material response can be highly time-dependent, which is beyond the realm of classical plasticity. Viscoplastic theories have been developed for just such conditions. In viscoplastic theories, the flow law is given in terms of inelastic strain rate rather than the inelastic strain increment used in time-independent plasticity. Thus, surfaces of constant inelastic strain rate or flow surfaces are to viscoplastic theories what yield surfaces are to classical plasticity. The purpose of the work reported herein was to validate experimental procedures for determining flow surfaces at elevated temperatures. Since experimental procedures for determining yield surfaces in axial/torsional stress space are well established, they were employed -- except inelastic strain rates were used rather than total inelastic strains. In yield-surface determinations, the use of small-offset definitions of yield minimizes the change of material state and allows multiple loadings to be applied to a single specimen. The key to the experiments reported here was precise, decoupled measurement of axial and torsional strain. With this requirement in mind, the performance of a high-temperature multi-axial extensometer was evaluated by comparing its results with strain gauge results at room temperature. Both the extensometer and strain gauges gave nearly identical yield surfaces (both initial and subsequent) for type 316 stainless steel (316 SS). The extensometer also successfully determined flow surfaces for 316 SS at 650 C. Furthermore, to judge the applicability of the technique for composite materials, yield surfaces were determined for unidirectional tungsten/Kanthal (Fe-Cr-Al).

Trapping dynamics of xenon on Pt(111)

NASA Astrophysics Data System (ADS)

Arumainayagam, Christopher R.; Madix, Robert J.; Mcmaster, Mark C.; Suzawa, Valerie M.; Tully, John C.

1990-02-01

The dynamics of Xe trapping on Pt(111) was studied using supersonic atomic beam techniques. Initial trapping probabilities ( S0) were measured directly as a function of incident translational energy ( EinT) and angle of incidence (θ i) at a surface temperature ( Tins) 95 K. The initial trapping probability decreases smoothly with increasing ET cosθ i;, rather than ET cos 2θ i, suggesting participation of parallel momentum in the trapping process. Accordingly, the measured initial trapping probability falls off more slowly with increasing incident translational energy than predicted by one-dimensional theories. This finding is in near agreement with previous mean translational energy measurements for Xe desorbing near the Pt(111) surface normal, assuming detailed balance applies. Three-dimensional stochastic classical trajectory calculations presented herein also exhibit the importance of tangential momentum in trapping and satisfactorily reproduce the experimental initial trapping probabilities.

Design of a global soil moisture initialization procedure for the simple biosphere model

NASA Technical Reports Server (NTRS)

Liston, G. E.; Sud, Y. C.; Walker, G. K.

1993-01-01

Global soil moisture and land-surface evapotranspiration fields are computed using an analysis scheme based on the Simple Biosphere (SiB) soil-vegetation-atmosphere interaction model. The scheme is driven with observed precipitation, and potential evapotranspiration, where the potential evapotranspiration is computed following the surface air temperature-potential evapotranspiration regression of Thomthwaite (1948). The observed surface air temperature is corrected to reflect potential (zero soil moisture stress) conditions by letting the ratio of actual transpiration to potential transpiration be a function of normalized difference vegetation index (NDVI). Soil moisture, evapotranspiration, and runoff data are generated on a daily basis for a 10-year period, January 1979 through December 1988, using observed precipitation gridded at a 4 deg by 5 deg resolution.

Exchange of groundwater and surface-water mediated by permafrost response to seasonal and long term air temperature variation

USGS Publications Warehouse

Ge, S.; McKenzie, J.; Voss, C.; Wu, Q.

2011-01-01

Permafrost dynamics impact hydrologic cycle processes by promoting or impeding groundwater and surface water exchange. Under seasonal and decadal air temperature variations, permafrost temperature changes control the exchanges between groundwater and surface water. A coupled heat transport and groundwater flow model, SUTRA, was modified to simulate groundwater flow and heat transport in the subsurface containing permafrost. The northern central Tibet Plateau was used as an example of model application. Modeling results show that in a yearly cycle, groundwater flow occurs in the active layer from May to October. Maximum groundwater discharge to the surface lags the maximum subsurface temperature by two months. Under an increasing air temperature scenario of 3C per 100 years, over the initial 40-year period, the active layer thickness can increase by three-fold. Annual groundwater discharge to the surface can experience a similar three-fold increase in the same period. An implication of these modeling results is that with increased warming there will be more groundwater flow in the active layer and therefore increased groundwater discharge to rivers. However, this finding only holds if sufficient upgradient water is available to replenish the increased discharge. Otherwise, there will be an overall lowering of the water table in the recharge portion of the catchment. Copyright 2011 by the American Geophysical Union.

Method of assembling and sealing an alkali metal battery

DOEpatents

Elkins, Perry E.; Bell, Jerry E.; Harlow, Richard A.; Chase, Gordon G.

1983-01-01

A method of initially assembling and then subsequently hermetically sealing a container portion of an alkali metal battery to a ceramic portion of such a battery is disclosed. Sealing surfaces are formed respectively on a container portion and a ceramic portion of an alkali metal battery. These sealing surfaces are brought into juxtaposition and a material is interposed therebetween. This interposed material is one which will diffuse into sealing relationship with both the container portion and the ceramic portion of the alkali metal battery at operational temperatures of such a battery. A pressure is applied between these sealing surfaces to cause the interposed material to be brought into intimate physical contact with such juxtaposed surfaces. A temporary sealing material which will provide a seal against a flow of alkali metal battery reactants therethrough at room temperatures and is applied over the juxtaposed sealing surfaces and material interposed therebetween. The entire assembly is heated to an operational temperature so that the interposed material diffuses into the container portion and the ceramic portion to form a hermetic seal therebetween. The pressure applied to the juxtaposed sealing surfaces is maintained in order to ensure the continuation of the hermetic seal.

Method of assembling and sealing an alkali metal battery

DOEpatents

Elkins, P.E.; Bell, J.E.; Harlow, R.A.; Chase, G.G.

1983-03-01

A method of initially assembling and then subsequently hermetically sealing a container portion of an alkali metal battery to a ceramic portion of such a battery is disclosed. Sealing surfaces are formed respectively on a container portion and a ceramic portion of an alkali metal battery. These sealing surfaces are brought into juxtaposition and a material is interposed there between. This interposed material is one which will diffuse into sealing relationship with both the container portion and the ceramic portion of the alkali metal battery at operational temperatures of such a battery. A pressure is applied between these sealing surfaces to cause the interposed material to be brought into intimate physical contact with such juxtaposed surfaces. A temporary sealing material which will provide a seal against a flow of alkali metal battery reactants there through at room temperatures and is applied over the juxtaposed sealing surfaces and material interposed there between. The entire assembly is heated to an operational temperature so that the interposed material diffuses into the container portion and the ceramic portion to form a hermetic seal there between. The pressure applied to the juxtaposed sealing surfaces is maintained in order to ensure the continuation of the hermetic seal. 4 figs.

Surface slope characteristics from Thermal Emission Spectrometer emission phase function observations

NASA Astrophysics Data System (ADS)

Edwards, C. S.; Bandfield, J. L.; Christensen, P. R.

2006-12-01

It is possible to obtain surface roughness characteristics, by measuring a single surface from multiple emission angles and azimuths in the thermal infrared. Surfaces will have different temperatures depending on their orientation relative to the sun. A different proportion of sunlit versus shaded surfaces will be in the field of view based on the viewing orientation, resulting in apparent temperature differences. This difference in temperature can be utilized to calculate the slope characteristics for the observed area. This technique can be useful for determining surface slope characteristics not resolvable by orbital imagery. There are two main components to this model, a surface DEM, in this case a synthetic, two dimensional sine wave surface, and a thermal model (provided by H. Kieffer). Using albedo, solar longitude, slope, azimuth, along with several other parameters, the temperature for each cell of the DEM is calculated using the thermal model. A temperature is then predicted using the same observation geometries as the Thermal Emission Spectrometer (TES) observations. A temperature difference is calculated for the two complementary viewing azimuths and emission angles from the DEM. These values are then compared to the observed temperature difference to determine the surface slope. This method has been applied to TES Emission Phase Function (EPF) observations for both the spectrometer and bolometer data, with a footprint size of 10s of kilometers. These specialized types of TES observations measure nearly the same surface from several angles. Accurate surface kinetic temperatures are obtained after the application of an atmospheric correction for the TES bolometer and/or spectrometer. Initial results include an application to the northern circumpolar dunes. An average maximum slope of ~33 degrees has been obtained, which makes physical sense since this is near the angle of repose for sand sized particles. There is some scatter in the data from separate observations, which may be due to the large footprint size. This technique can be better understood and characterized by correlation with high resolution imagery. Several different surface maps will also be tested in addition to the two dimensional sine wave surface. Finally, by modeling the thermal effects on different particle sizes and land forms, we can further interpret the scale of these slopes.

ALMA observation of Ceres' Surface Temperature.

NASA Astrophysics Data System (ADS)

Titus, T. N.; Li, J. Y.; Sykes, M. V.; Ip, W. H.; Lai, I.; Moullet, A.

2016-12-01

Ceres, the largest object in the main asteroid belt, has been mapped by the Dawn spacecraft. The mapping includes measuring surface temperatures using the Visible and Infrared (VIR) spectrometer at high spatial resolution. However, the VIR instrument has a long wavelength cutoff at 5 μm, which prevents the accurate measurement of surface temperatures below 180 K. This restricts temperature determinations to low and mid-latitudes at mid-day. Observations from the Atacama Large Millimeter/submillimeter Array (ALMA) [1], while having lower spatial resolution, are sensitive to the full range of surface temperatures that are expected at Ceres. Forty reconstructed images at 75 km/beam resolution were acquired of Ceres that were consistent with a low thermal inertia surface. The diurnal temperature profiles were compared to the KRC thermal model [2, 3], which has been extensively used for Mars [e.g. 4, 5]. Variations in temperature as a function of local time are observed and are compared to predictions from the KRC model. The model temperatures are converted to radiance (Jy/Steradian) and are corrected for near-surface thermal gradients and limb effects for comparison to observations. Initial analysis is consistent with the presence of near-surface water ice in the north polar region. The edge of the ice table is between 50° and 70° North Latitude, consistent with the enhanced detection of hydrogen by the Dawn GRaND instrument [6]. Further analysis will be presented. This work is supported by the NASA Solar System Observations Program. References: [1] Wootten A. et al. (2015) IAU General Assembly, Meeting #29, #2237199 [2] Kieffer, H. H., et al. (1977) JGR, 82, 4249-4291. [3] Kieffer, Hugh H., (2013) Journal of Geophysical Research: Planets, 118(3), 451-470. [4] Titus, T. N., H. H. Kieffer, and P. N. Christensen (2003) Science, 299, 1048-1051. [5] Fergason, R. L. et al. (2012) Space Sci. Rev, 170, 739-773[6] Prettyman, T. et al. (2016) LPSC 47, #2228.

Solid and liquid Equation of state for initially porous aluminum where specific heat is constant

NASA Astrophysics Data System (ADS)

Forbes, Jerry W.; Lemar, E. R.; Brown, Mary

2011-06-01

A porous solid's initial state is off the thermodynamic surface of the non-porous solid to start with but when pressure is high enough to cause total pore collapse or crush up, then the final states are on the condensed matter thermodynamic surfaces. The Hugoniot for the fully compacted solid is above the Principle Hugoniot with pressure, temperature and internal energy increased at a given v. There are a number of ways to define this hotter Hugoniot, which can be referenced to other thermodynamic paths on this thermodynamic surface. The choice here was to use the Vinet isotherm to define a consistent thermodynamic surface for the solid and melt phase of 6061 aluminum where specific heat is constant for the P-v-T space of interest. Analytical equations are developed for PH and TH.

Deuterium desorption from ion-irradiated tantalum and effects on surface morphology

NASA Astrophysics Data System (ADS)

Novakowski, T. J.; Sundaram, A.; Tripathi, J. K.; Gonderman, S.; Hassanein, A.

2018-06-01

Compared to tungsten (W), tantalum (Ta) has shown superior resistance to helium (He)-induced surface morphology changes under fusion-relevant irradiation conditions. However, Ta is also expected to have a stronger interaction with hydrogen isotopes, potentially limiting its use as a plasma-facing material. Despite these concerns, detailed investigations on hydrogen irradiation effects on Ta are scarce. In this study, pristine and fuzzy (He+ ion-irradiated) Ta samples are irradiated with 120 eV deuterium (D) ions at various temperatures and examined with a combination of thermal desorption spectroscopy (TDS), scanning electron microscopy (SEM), and optical reflectivity. TDS reveals discrete D desorption temperatures at 660 and 760 K, corresponding to trapping energies of 1.82 and 2.11 eV, respectively. Although D is retained in Ta both in higher quantities and at higher temperatures compared to W, extreme surface temperatures expected in tokamak divertors may exceed these desorption temperatures and counteract retention. Furthermore, this study indicates that Ta is relatively resistant to adverse surface structuring under D+ ion irradiation. In fact, D+ is shown to prevent and suppress Ta fuzz formation in sequential D+/He+ ion irradiation experiments. While further investigations are needed to elucidate this behavior, these initial investigations show a strong potential for the use of Ta as a PFC material.

Influence law of structural characteristics on the surface roughness of a magnetorheological-finished KDP crystal.

PubMed

Chen, Shaoshan; Li, Shengyi; Hu, Hao; Li, Qi; Tie, Guipeng

2014-11-01

A new nonaqueous and abrasive-free magnetorheological finishing (MRF) method is adopted for processing potassium dihydrogen phosphate (KDP) crystal due to its low hardness, high brittleness, temperature sensitivity, and water solubility. This paper researches the influence of structural characteristics on the surface roughness of MRF-finished KDP crystal. The material removal by dissolution is uniform layer by layer when the polishing parameters are stable. The angle between the direction of the polishing wheel's linear velocity and the initial turning lines will affect the surface roughness. If the direction is perpendicular to the initial turning lines, the polishing can remove the lines. If the direction is parallel to the initial turning lines, the polishing can achieve better surface roughness. The structural characteristic of KDP crystal is related to its internal chemical bonds due to its anisotropy. During the MRF finishing process, surface roughness will be improved if the structural characteristics of the KDP crystal are the same on both sides of the wheel. The processing results of (001) plane crystal show we can get the best surface roughness (RMS of 0.809 nm) if the directions of cutting and MRF polishing are along the (110) direction.

Reintroducing radiometric surface temperature into the Penman-Monteith formulation

NASA Astrophysics Data System (ADS)

Mallick, Kaniska; Boegh, Eva; Trebs, Ivonne; Alfieri, Joseph G.; Kustas, William P.; Prueger, John H.; Niyogi, Dev; Das, Narendra; Drewry, Darren T.; Hoffmann, Lucien; Jarvis, Andrew J.

2015-08-01

Here we demonstrate a novel method to physically integrate radiometric surface temperature (TR) into the Penman-Monteith (PM) formulation for estimating the terrestrial sensible and latent heat fluxes (H and λE) in the framework of a modified Surface Temperature Initiated Closure (STIC). It combines TR data with standard energy balance closure models for deriving a hybrid scheme that does not require parameterization of the surface (or stomatal) and aerodynamic conductances (gS and gB). STIC is formed by the simultaneous solution of four state equations and it uses TR as an additional data source for retrieving the "near surface" moisture availability (M) and the Priestley-Taylor coefficient (α). The performance of STIC is tested using high-temporal resolution TR observations collected from different international surface energy flux experiments in conjunction with corresponding net radiation (RN), ground heat flux (G), air temperature (TA), and relative humidity (RH) measurements. A comparison of the STIC outputs with the eddy covariance measurements of λE and H revealed RMSDs of 7-16% and 40-74% in half-hourly λE and H estimates. These statistics were 5-13% and 10-44% in daily λE and H. The errors and uncertainties in both surface fluxes are comparable to the models that typically use land surface parameterizations for determining the unobserved components (gS and gB) of the surface energy balance models. However, the scheme is simpler, has the capabilities for generating spatially explicit surface energy fluxes and independent of submodels for boundary layer developments. This article was corrected on 27 AUG 2015. See the end of the full text for details.

Reduction of the Livestock Ammonia Emission under the Changing Temperature during the Initial Manure Nitrogen Biomineralization

PubMed Central

Bagdonienė, Indrė; Baležentienė, Ligita

2013-01-01

Experimental data were applied for the modelling optimal cowshed temperature environment in laboratory test bench by a mass-flow method. The principal factor affecting exponent growth of ammonia emission was increasing air and manure surface temperature. With the manure temperature increasing from 4°C to 30°C, growth in the ammonia emission grew fourfold, that is, from 102 to 430 mg m−2h−1. Especial risk emerges when temperature exceeds 20°C: an increase in temperature of 1°C contributes to the intensity of ammonia emission by 17 mg m−2h−1. The temperatures of air and manure surface as well as those of its layers are important when analysing emission processes from manure. Indeed, it affects the processes occurring on the manure surface, namely, dehydration and crust formation. To reduce ammonia emission from cowshed, it is important to optimize the inner temperature control and to manage air circulation, especially at higher temperatures, preventing the warm ambient air from blowing direct to manure. Decrease in mean annual temperature of 1°C would reduce the annual ammonia emission by some 5.0%. The air temperature range varied between −15°C and 30°C in barns. The highest mean annual temperature (14.6°C) and ammonia emission (218 mg m−2h−1) were observed in the semideep cowshed. PMID:24453912

Super Clausius-Clapeyron scaling of extreme hourly precipitation and its relation to large-scale atmospheric conditions

NASA Astrophysics Data System (ADS)

Lenderink, Geert; Barbero, Renaud; Loriaux, Jessica; Fowler, Hayley

2017-04-01

Present-day precipitation-temperature scaling relations indicate that hourly precipitation extremes may have a response to warming exceeding the Clausius-Clapeyron (CC) relation; for The Netherlands the dependency on surface dew point temperature follows two times the CC relation corresponding to 14 % per degree. Our hypothesis - as supported by a simple physical argument presented here - is that this 2CC behaviour arises from the physics of convective clouds. So, we think that this response is due to local feedbacks related to the convective activity, while other large scale atmospheric forcing conditions remain similar except for the higher temperature (approximately uniform warming with height) and absolute humidity (corresponding to the assumption of unchanged relative humidity). To test this hypothesis, we analysed the large-scale atmospheric conditions accompanying summertime afternoon precipitation events using surface observations combined with a regional re-analysis for the data in The Netherlands. Events are precipitation measurements clustered in time and space derived from approximately 30 automatic weather stations. The hourly peak intensities of these events again reveal a 2CC scaling with the surface dew point temperature. The temperature excess of moist updrafts initialized at the surface and the maximum cloud depth are clear functions of surface dew point temperature, confirming the key role of surface humidity on convective activity. Almost no differences in relative humidity and the dry temperature lapse rate were found across the dew point temperature range, supporting our theory that 2CC scaling is mainly due to the response of convection to increases in near surface humidity, while other atmospheric conditions remain similar. Additionally, hourly precipitation extremes are on average accompanied by substantial large-scale upward motions and therefore large-scale moisture convergence, which appears to accelerate with surface dew point. This increase in large-scale moisture convergence appears to be consequence of latent heat release due to the convective activity as estimated from the quasi-geostrophic omega equation. Consequently, most hourly extremes occur in precipitation events with considerable spatial extent. Importantly, this event size appears to increase rapidly at the highest dew point temperature range, suggesting potentially strong impacts of climatic warming.

Photothermal waves for two temperature with a semiconducting medium under using a dual-phase-lag model and hydrostatic initial stress

NASA Astrophysics Data System (ADS)

Lotfy, Kh.

2017-07-01

The dual-phase-lag (DPL) model with two different time translations and Lord-Shulman (LS) theory with one relaxation time are applied to study the effect of hydrostatic initial stress on medium under the influence of two temperature parameter(a new model will be introduced using two temperature theory) and photothermal theory. We solved the thermal loading at the free surface in the semi-infinite semiconducting medium-coupled plasma waves with the effect of mechanical force during a photothermal process. The exact expressions of the considered variables are obtained using normal mode analysis also the two temperature coefficient ratios were obtained analytically. Numerical results for the field quantities are given in the physical domain and illustrated graphically under the effects of several parameters. Comparisons are made between the results of the two different models with and without two temperature parameter, and for two different values of the hydrostatic initial stress. A comparison is carried out between the considered variables as calculated from the generalized thermoelasticity based on the DPL model and the LS theory in the absence and presence of the thermoelastic and thermoelectric coupling parameters.

Determination of Yield in Inconel 718 for Axial-Torsional Loading at Temperatures up to 649 C

NASA Technical Reports Server (NTRS)

Gil, Christopher M.; Lissenden, Cliff J.; Lerch, Bradley A.

1998-01-01

An experimental program has been implemented to determine small offset yield loci under axial-torsional loading at elevated temperatures. The nickel-base superalloy Inconel 718 (IN718) was chosen for study due to its common use in aeropropulsion applications. Initial and subsequent yield loci were determined for solutioned IN718 at 23, 371, and 454 C and for aged (precipitation hardened) IN718 at 23 and 649 C. The shape of the initial yield loci for solutioned and aged IN718 agreed well with the von Mises prediction. However, in general, the centers of initial yield loci were eccentric to the origin due to a strength-differential (S-D) effect that increased with temperature. Subsequent yield loci exhibited anisotropic hardening in the form of translation and distortion of the locus. This work shows that it is possible to determine yield surfaces for metallic materials at temperatures up to at least 649 C using multiple probes of a single specimen. The experimental data is first-of-its-kind for a superalloy at these very high temperatures and will facilitate a better understanding of multiaxial material response, eventually leading to improved design tools for engine designers.

Nano ZSM-5 type ferrisilicates as novel catalysts for ethylbenzene dehydrogenation in the presence of N 2O

NASA Astrophysics Data System (ADS)

Khatamian, M.; Khandar, A. A.; Haghighi, M.; Ghadiri, M.

2011-11-01

Nanosized ZSM-5 type ferrisilicates were successfully prepared using hydrothermal process. Several parameters including gel initiative compositions (Na+ or K+ alkali system), SiO2/Fe2O3 molar ratios and hydrothermal temperature were systematically investigated. The samples were characterized by XRD, TEM, SEM-EDS, BET surface area and ICP techniques. It was found that surface areas and the total pore volume increase with increasing in the SiO2/Fe2O3 molar ratio at Na-FZ ferrisilicates. The catalytic performance of the synthesized catalysts was evaluated in ethylbenzene dehydrogenation to styrene in the presence of N2O or steam at temperatures ranging from 400 °C to 660 °C under atmospheric pressure. The effects of gel initiative compositions, SiO2/Fe2O3 molar ratio as well as the hydrothermal synthesis temperature on the catalytic performance of these catalysts have been addressed. It was shown that styrene yield significantly influenced by altering in the SiO2/Fe2O3 ratio but was not greatly influenced by changes in hydrothermal synthesis temperatures. The comparison between performance of potassium and sodium containing catalysts was shown that the one with potassium has higher yield and selectivity toward styrene production at an optimum temperature of 610 °C.

Magnetic susceptibility well-logging unit with single power supply thermoregulation system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seeley, R. L.

1985-11-05

The magnetic susceptibility well-logging unit with single power supply thermoregulation system provides power from a single surface power supply over a well-logging cable to an integrated circuit voltage regulator system downhole. This voltage regulator system supplies regulated voltages to a temperature control system and also to a Maxwell bridge sensing unit which includes the solenoid of a magnetic susceptibility probe. The temperature control system is provided with power from the voltage regulator system and operates to permit one of several predetermined temperatures to be chosen, and then operates to maintain the solenoid of a magnetic susceptibility probe at this chosenmore » temperature. The temperature control system responds to a temperature sensor mounted upon the probe solenoid to cause resistance heaters concentrically spaced from the probe solenoid to maintain the chosen temperature. A second temperature sensor on the probe solenoid provides a temperature signal to a temperature transmitting unit, which initially converts the sensed temperature to a representative voltage. This voltage is then converted to a representative current signal which is transmitted by current telemetry over the well logging cable to a surface electronic unit which then reconverts the current signal to a voltage signal.« less

High Resolution Land Surface Modeling with the next generation Land Data Assimilation Systems

NASA Astrophysics Data System (ADS)

Kumar, S. V.; Eylander, J.; Peters-Lidard, C.

2005-12-01

Knowledge of land surface processes is important to many real-world applications such as agricultural production, water resources management, and flood predication. The Air Force Weather Agency (AFWA) has provided the USDA and other customers global soil moisture and temperature data for the past 30 years using the agrometeorological data assimilation model (now called AGRMET), merging atmospheric data. Further, accurate initialization of land surface conditions has been shown to greatly influence and improve weather forecast model and seasonal-to-interannual climate predictions. The AFWA AGRMET model exploits real time precipitation observations and analyses, global forecast model and satellite data to generate global estimates of soil moisture, soil temperature and other land surface states at 48km spatial resolution. However, to truly address the land surface initialization and climate prediction problem, and to mitigate the errors introduced by the differences in spatial scales of models, representations of land surface conditions need to be developed at the same fine scales such as that of cloud resolving models. NASA's Goddard Space Flight Center has developed an offline land data assimilation system known as the Land Information System (LIS) capable of modeling land atmosphere interactions at spatial resolutions as fine as 1km. LIS provides a software architecture that integrates the use of the state of the art land surface models, data assimilation techniques, and high performance computing and data management tools. LIS also employs many high resolution surface parameters such as the NASA Earth Observing System (EOS)-era products. In this study we describe the development of a next generation high resolution land surface modeling and data assimilation system, combining the capabilities of LIS and AGRMET. We investigate the influence of high resolution land surface data and observations on the land surface conditions by comparing with the operational AGRMET outputs.

Segregation effects during solidification in weightless melts

NASA Technical Reports Server (NTRS)

Li, C.; Gershinsky, M.

1974-01-01

The generalized problem of determining the temperature and solute concentration profiles during directional solidification of binary alloys with surface evaporation was mathematically formulated. Realistic initial and boundary conditions were defined, and a computer program was developed and checked out. The programs computes the positions of two moving boundaries, evaporation and solidification, and their velocities. Temperature and solute concentration profiles in the semiinfinite material body at selected instances of time are also computed.

A thermo-elastoplastic model for soft rocks considering structure

NASA Astrophysics Data System (ADS)

He, Zuoyue; Zhang, Sheng; Teng, Jidong; Xiong, Yonglin

2017-11-01

In the fields of nuclear waste geological deposit, geothermy and deep mining, the effects of temperature on the mechanical behaviors of soft rocks cannot be neglected. Experimental data in the literature also showed that the structure of soft rocks cannot be ignored. Based on the superloading yield surface and the concept of temperature-deduced equivalent stress, a thermo-elastoplastic model for soft rocks is proposed considering the structure. Compared to the superloading yield surface, only one parameter is added, i.e. the linear thermal expansion coefficient. The predicted results and the comparisons with experimental data in the literature show that the proposed model is capable of simultaneously describing heat increase and heat decrease of soft rocks. A stronger initial structure leads to a greater strength of the soft rocks. Heat increase and heat decrease can be converted between each other due to the change of the initial structure of soft rocks. Furthermore, regardless of the heat increase or heat decrease, a larger linear thermal expansion coefficient or a greater temperature always leads to a much rapider degradation of the structure. The degradation trend will be more obvious for the coupled greater values of linear thermal expansion coefficient and temperature. Lastly, compared to heat decrease, the structure will degrade more easily in the case of heat increase.

Numerical modeling of ultrasonic cavitation in ionic liquids

NASA Astrophysics Data System (ADS)

Calvisi, Michael L.; Elder, Ross M.

2017-11-01

Ionic liquids have favorable properties for sonochemistry applications in which the high temperatures and pressures achieved by cavitation bubbles are important drivers of chemical processes. Two different numerical models are presented to simulate ultrasonic cavitation in ionic liquids, each with different capabilities and physical assumptions. A model based on a compressible form of the Rayleigh-Plesset equation (RPE) simulates ultrasonic cavitation of a spherical bubble with a homogeneous interior, incorporating evaporation and condensation at the bubble surface, and temperature-varying thermodynamic properties in the interior. A second, more computationally intensive model of a spherical bubble uses the finite element method (FEM) and accounts for spatial variations in pressure and temperature throughout the flow domain. This model provides insight into heat transfer across the bubble surface and throughout the bubble interior and exterior. Parametric studies are presented for sonochemistry applications involving ionic liquids as a solvent, examining a range of realistic ionic liquid properties and initial conditions to determine their effect on temperature and pressure. Results from the two models are presented for parametric variations including viscosity, thermal conductivity, water content of the ionic liquid solvent, acoustic frequency, and initial bubble pressure. An additional study performed with the FEM model examines thermal penetration into the surrounding ionic liquid during bubble oscillation. The results suggest the prospect of tuning ionic liquid properties for specific applications.

High-Performance Simulations of the Diffusion Characteristics of a Pentacene Derivative on Gold Surfaces

NASA Astrophysics Data System (ADS)

Miller, Ryan; Larson, Amanda; Pohl, Karsten

Pentacene serves as a backbone for several molecules that provide attractive qualities for organic photovoltaic devices. One of these pentacene derivatives is 5 6,7-trithiapentacene-13-one (TTPO), which is unique in that it achieves its lowest energy configuration on Au(1 1 1) surfaces with the thiol group angled down towards the surface, allowing many molecules to pack closely together and form molecular nanowires. However, TTPO diffuses on flat surfaces, making it difficult for the self-assembly process to be initiated. With the help of the low-energy sites in surface defects and Au(7 8 8) step edges, TTPO molecules can be anchored in place on surfaces, allowing for chain formation to begin. By using high-performance Density Functional Theory based molecular dynamics calculations, the molecules can be shown to stay localized to these bonding sites and serve as a basis for chain formation. In addition, by simulating various temperatures with a Nose-Hoover thermostat, we can analyze how temperature affects anchoring ability and diffusion properties.

Understanding the Role of Temperature and Cathode Composition on Interface and Bulk: Optimizing Aluminum Oxide Coatings for Li-Ion Cathodes.

PubMed

Han, Binghong; Paulauskas, Tadas; Key, Baris; Peebles, Cameron; Park, Joong Sun; Klie, Robert F; Vaughey, John T; Dogan, Fulya

2017-05-03

Surface coating of cathode materials with Al 2 O 3 has been shown to be a promising method for cathode stabilization and improved cycling performance at high operating voltages. However, a detailed understanding on how coating process and cathode composition change the chemical composition, morphology, and distribution of coating within the cathode interface and bulk lattice is still missing. In this study, we use a wet-chemical method to synthesize a series of Al 2 O 3 -coated LiNi 0.5 Co 0.2 Mn 0.3 O 2 and LiCoO 2 cathodes treated under various annealing temperatures and a combination of structural characterization techniques to understand the composition, homogeneity, and morphology of the coating layer and the bulk cathode. Nuclear magnetic resonance and electron microscopy results reveal that the nature of the interface is highly dependent on the annealing temperature and cathode composition. For Al 2 O 3 -coated LiNi 0.5 Co 0.2 Mn 0.3 O 2 , higher annealing temperature leads to more homogeneous and more closely attached coating on cathode materials, corresponding to better electrochemical performance. Lower Al 2 O 3 coating content is found to be helpful to further improve the initial capacity and cyclability, which can greatly outperform the pristine cathode material. For Al 2 O 3 -coated LiCoO 2 , the incorporation of Al into the cathode lattice is observed after annealing at high temperatures, implying the transformation from "surface coatings" to "dopants", which is not observed for LiNi 0.5 Co 0.2 Mn 0.3 O 2 . As a result, Al 2 O 3 -coated LiCoO 2 annealed at higher temperature shows similar initial capacity but lower retention compared to that annealed at a lower temperature, due to the intercalation of surface alumina into the bulk layered structure forming a solid solution.

Understanding the Role of Temperature and Cathode Composition on Interface and Bulk: Optimizing Aluminum Oxide Coatings for Li-Ion Cathodes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Han, Binghong; Paulauskas, Tadas; Key, Baris

Here, surface coating of cathode materials with Al 2O 3 has been shown to be a promising method for cathode stabilization and improved cycling performance at high operating voltages. However, a detailed understanding on how coating process and cathode composition changes the chemical composition, morphology and distribution of coating within cathode interface and bulk lattice, is still missing. In this study, we use a wet-chemical method to synthesize a series of Al 2O 3-coated LiNi 0.5Co 0.2Mn 0.3O 2 and LiCoO 2 cathodes treated under various annealing temperatures and a combination of structural characterization techniques to understand the composition, homogeneitymore » and morphology of coating layer and the bulk cathode. Nuclear magnetic resonance and electron microscopy results reveal that the nature of the interface is highly depended on the annealing temperature and cathode composition. For Al 2O 3-coated LiNi 0.5Co 0.2Mn 0.3O 2, higher annealing temperature leads to more homogeneous and more closely attached coating on cathode materials, corresponding to better electrochemical performance. Lower Al 2O 3 coating content is found to be helpful to further improve the initial capacity and cyclability, which can greatly outperform the pristine cathode material. For Al 2O 3-coated LiCoO 2, the incorporation of Al into the cathode lattice is observed after annealing at high temperatures, implying the transformation from “surface coatings” to “dopants”, which is not observed for LiNi 0.5Co 0.2Mn 0.3O 2. As a result, Al 2O 3-coated LiCoO 2 annealed at higher temperature shows similar initial capacity but lower retention compared to that annealed at a lower temperature, due to the intercalation of surface alumina into the bulk layered structure forming a solid solution.« less

Understanding the Role of Temperature and Cathode Composition on Interface and Bulk: Optimizing Aluminum Oxide Coatings for Li-Ion Cathodes

DOE PAGES

Han, Binghong; Paulauskas, Tadas; Key, Baris; ...

2017-04-07

Here, surface coating of cathode materials with Al 2O 3 has been shown to be a promising method for cathode stabilization and improved cycling performance at high operating voltages. However, a detailed understanding on how coating process and cathode composition changes the chemical composition, morphology and distribution of coating within cathode interface and bulk lattice, is still missing. In this study, we use a wet-chemical method to synthesize a series of Al 2O 3-coated LiNi 0.5Co 0.2Mn 0.3O 2 and LiCoO 2 cathodes treated under various annealing temperatures and a combination of structural characterization techniques to understand the composition, homogeneitymore » and morphology of coating layer and the bulk cathode. Nuclear magnetic resonance and electron microscopy results reveal that the nature of the interface is highly depended on the annealing temperature and cathode composition. For Al 2O 3-coated LiNi 0.5Co 0.2Mn 0.3O 2, higher annealing temperature leads to more homogeneous and more closely attached coating on cathode materials, corresponding to better electrochemical performance. Lower Al 2O 3 coating content is found to be helpful to further improve the initial capacity and cyclability, which can greatly outperform the pristine cathode material. For Al 2O 3-coated LiCoO 2, the incorporation of Al into the cathode lattice is observed after annealing at high temperatures, implying the transformation from “surface coatings” to “dopants”, which is not observed for LiNi 0.5Co 0.2Mn 0.3O 2. As a result, Al 2O 3-coated LiCoO 2 annealed at higher temperature shows similar initial capacity but lower retention compared to that annealed at a lower temperature, due to the intercalation of surface alumina into the bulk layered structure forming a solid solution.« less

Effect of Slag-Steel Reaction on the Initial Solidification of Molten Steel during Continuous Casting

NASA Astrophysics Data System (ADS)

Wang, Wanlin; Lou, Zhican; Zhang, Haihui

2018-03-01

With the mold simulator technique, the effect of slag-steel reaction on the initial shell solidification as well as the heat transfer and lubrication behavior of the infiltrated mold/shell slag film was studied in this article. The results showed that the Al2O3 content, the CaO/SiO2 ratio, and the viscosity of mold flux were increased with the progress of the slag-steel reaction during casting. The slag-steel reaction has two major effects on the initial shell solidification: one is increasing the mold heat flux and shell thickness by the decrease of slag film thickness. The other is the reduction of mold heat flux by the increase of crystal fraction in slag film. Mold flux with a lower basicity, viscosity, and crystallization temperature would result in a larger liquid slag consumption and the uneven infiltration of slag into the mold and shell gap that eventually leads to the irregular solidification of initial shell with a poor surface quality, such as slag entrapment and depressions as well as glaciation marks. Conversely, mold flux with a higher viscosity, basicity, and crystallization temperature would result in a smaller liquid slag consumption, which would cause the poor mold lubrication, the longitudinal shell surface defects, and drag marks.

Effect of Slag-Steel Reaction on the Initial Solidification of Molten Steel during Continuous Casting

NASA Astrophysics Data System (ADS)

Wang, Wanlin; Lou, Zhican; Zhang, Haihui

2018-06-01

With the mold simulator technique, the effect of slag-steel reaction on the initial shell solidification as well as the heat transfer and lubrication behavior of the infiltrated mold/shell slag film was studied in this article. The results showed that the Al2O3 content, the CaO/SiO2 ratio, and the viscosity of mold flux were increased with the progress of the slag-steel reaction during casting. The slag-steel reaction has two major effects on the initial shell solidification: one is increasing the mold heat flux and shell thickness by the decrease of slag film thickness. The other is the reduction of mold heat flux by the increase of crystal fraction in slag film. Mold flux with a lower basicity, viscosity, and crystallization temperature would result in a larger liquid slag consumption and the uneven infiltration of slag into the mold and shell gap that eventually leads to the irregular solidification of initial shell with a poor surface quality, such as slag entrapment and depressions as well as glaciation marks. Conversely, mold flux with a higher viscosity, basicity, and crystallization temperature would result in a smaller liquid slag consumption, which would cause the poor mold lubrication, the longitudinal shell surface defects, and drag marks.

Improved prediction of severe thunderstorms over the Indian Monsoon region using high-resolution soil moisture and temperature initialization

PubMed Central

Osuri, K. K.; Nadimpalli, R.; Mohanty, U. C.; Chen, F.; Rajeevan, M.; Niyogi, D.

2017-01-01

The hypothesis that realistic land conditions such as soil moisture/soil temperature (SM/ST) can significantly improve the modeling of mesoscale deep convection is tested over the Indian monsoon region (IMR). A high resolution (3 km foot print) SM/ST dataset prepared from a land data assimilation system, as part of a national monsoon mission project, showed close agreement with observations. Experiments are conducted with (LDAS) and without (CNTL) initialization of SM/ST dataset. Results highlight the significance of realistic land surface conditions on numerical prediction of initiation, movement and timing of severe thunderstorms as compared to that currently being initialized by climatological fields in CNTL run. Realistic land conditions improved mass flux, convective updrafts and diabatic heating in the boundary layer that contributed to low level positive potential vorticity. The LDAS run reproduced reflectivity echoes and associated rainfall bands more efficiently. Improper representation of surface conditions in CNTL run limit the evolution boundary layer processes and thereby failed to simulate convection at right time and place. These findings thus provide strong support to the role land conditions play in impacting the deep convection over the IMR. These findings also have direct implications for improving heavy rain forecasting over the IMR, by developing realistic land conditions. PMID:28128293

On the appropriate definition of soil profile configuration and initial conditions for land surface-hydrology models in cold regions

NASA Astrophysics Data System (ADS)

Sapriza-Azuri, Gonzalo; Gamazo, Pablo; Razavi, Saman; Wheater, Howard S.

2018-06-01

Arctic and subarctic regions are amongst the most susceptible regions on Earth to global warming and climate change. Understanding and predicting the impact of climate change in these regions require a proper process representation of the interactions between climate, carbon cycle, and hydrology in Earth system models. This study focuses on land surface models (LSMs) that represent the lower boundary condition of general circulation models (GCMs) and regional climate models (RCMs), which simulate climate change evolution at the global and regional scales, respectively. LSMs typically utilize a standard soil configuration with a depth of no more than 4 m, whereas for cold, permafrost regions, field experiments show that attention to deep soil profiles is needed to understand and close the water and energy balances, which are tightly coupled through the phase change. To address this gap, we design and run a series of model experiments with a one-dimensional LSM, called CLASS (Canadian Land Surface Scheme), as embedded in the MESH (Modélisation Environmentale Communautaire - Surface and Hydrology) modelling system, to (1) characterize the effect of soil profile depth under different climate conditions and in the presence of parameter uncertainty; (2) assess the effect of including or excluding the geothermal flux in the LSM at the bottom of the soil column; and (3) develop a methodology for temperature profile initialization in permafrost regions, where the system has an extended memory, by the use of paleo-records and bootstrapping. Our study area is in Norman Wells, Northwest Territories of Canada, where measurements of soil temperature profiles and historical reconstructed climate data are available. Our results demonstrate a dominant role for parameter uncertainty, that is often neglected in LSMs. Considering such high sensitivity to parameter values and dependency on the climate condition, we show that a minimum depth of 20 m is essential to adequately represent the temperature dynamics. We further show that our proposed initialization procedure is effective and robust to uncertainty in paleo-climate reconstructions and that more than 300 years of reconstructed climate time series are needed for proper model initialization.

Oxidation and the Effects of High Temperature Exposures on Notched Fatigue Life of an Advanced Powder Metallurgy Disk Superalloy

NASA Technical Reports Server (NTRS)

Sudbrack, Chantal K.; Draper, Susan L.; Gorman, Timothy T.; Telesman, Jack; Gab, Timothy P.; Hull, David R.

2012-01-01

Oxidation and the effects of high temperature exposures on notched fatigue life were considered for a powder metallurgy processed supersolvus heat-treated ME3 disk superalloy. The isothermal static oxidation response at 704 C, 760 C, and 815 C was consistent with other chromia forming nickel-based superalloys: a TiO2-Cr2O3 external oxide formed with a branched Al2O3 internal subscale that extended into a recrystallized - dissolution layer. These surface changes can potentially impact disk durability, making layer growth rates important. Growth of the external scales and dissolution layers followed a cubic rate law, while Al2O3 subscales followed a parabolic rate law. Cr- rich M23C6 carbides at the grain boundaries dissolved to help sustain Cr2O3 growth to depths about 12 times thicker than the scale. The effect of prior exposures was examined through notched low cycle fatigue tests performed to failure in air at 704 C. Prior exposures led to pronounced debits of up to 99 % in fatigue life, where fatigue life decreased inversely with exposure time. Exposures that produced roughly equivalent 1 m thick external scales at the various isotherms showed statistically equivalent fatigue lives, establishing that surface damage drives fatigue debit, not exposure temperature. Fractographic evaluation indicated the failure mode for the pre-exposed specimens involved surface crack initiations that shifted with exposure from predominately single intergranular initiations with transgranular propagation to multi-initiations from the cracked external oxide with intergranular propagation. Weakened grain boundaries at the surface resulting from the M23C6 carbide dissolution are partially responsible for the intergranular cracking. Removing the scale and subscale while leaving a layer where M23C6 carbides were dissolved did not lead to a significant fatigue life improvement, however, also removing the M23C6 carbide dissolution layer led to nearly full recovery of life, with a transgranular initiation typical to that observed in unexposed specimens.

Penetrator Coring Apparatus for Cometary Surfaces

NASA Technical Reports Server (NTRS)

Braun, David F.; Heinrich, Michael; Ai, Huirong Anita; Ahrens, Thomas J.

2004-01-01

Touch and go impact coring is an attractive technique for sampling cometary nuclei and asteroidal surface on account of the uncertain strength properties and low surface gravities of these objects. Initial coring experiments in low temperature (approx. 153K polycrystalline ice) and porous rock demonstrate that simultaneous with impact coring, measurements of both the penetration strength and constraints on the frictional properties of surface materials can be obtained upon core penetration and core sample extraction. The method of sampling an asteroid, to be deployed, on the now launched MUSES-C mission, employs a small gun device that fires into the asteroid and the resulted impact ejecta is collected for return to Earth. This technique is well suited for initial sampling in a very low gravity environment and deployment depends little on asteroid surface mechanical properties. Since both asteroids and comets are believed to have altered surface properties a simple sampling apparatus that preserves stratigraphic information, such as impact coring is an attractive alternate to impact ejecta collection.

Engineering live cell surfaces with functional polymers via cytocompatible controlled radical polymerization

NASA Astrophysics Data System (ADS)

Niu, Jia; Lunn, David J.; Pusuluri, Anusha; Yoo, Justin I.; O'Malley, Michelle A.; Mitragotri, Samir; Soh, H. Tom; Hawker, Craig J.

2017-06-01

The capability to graft synthetic polymers onto the surfaces of live cells offers the potential to manipulate and control their phenotype and underlying cellular processes. Conventional grafting-to strategies for conjugating preformed polymers to cell surfaces are limited by low polymer grafting efficiency. Here we report an alternative grafting-from strategy for directly engineering the surfaces of live yeast and mammalian cells through cell surface-initiated controlled radical polymerization. By developing cytocompatible PET-RAFT (photoinduced electron transfer-reversible addition-fragmentation chain-transfer polymerization), synthetic polymers with narrow polydispersity (Mw/Mn < 1.3) could be obtained at room temperature in 5 minutes. This polymerization strategy enables chain growth to be initiated directly from chain-transfer agents anchored on the surface of live cells using either covalent attachment or non-covalent insertion, while maintaining high cell viability. Compared with conventional grafting-to approaches, these methods significantly improve the efficiency of grafting polymer chains and enable the active manipulation of cellular phenotypes.

The 2014-2015 warming anomaly in the Southern California Current System observed by underwater gliders

NASA Astrophysics Data System (ADS)

Zaba, Katherine D.; Rudnick, Daniel L.

2016-02-01

Large-scale patterns of positive temperature anomalies persisted throughout the surface waters of the North Pacific Ocean during 2014-2015. In the Southern California Current System, measurements by our sustained network of underwater gliders reveal the coastal effects of the recent warming. Regional upper ocean temperature anomalies were greatest since the initiation of the glider network in 2006. Additional observed physical anomalies included a depressed thermocline, high stratification, and freshening; induced biological consequences included changes in the vertical distribution of chlorophyll fluorescence. Contemporaneous surface heat flux and wind strength perturbations suggest that local anomalous atmospheric forcing caused the unusual oceanic conditions.

Sequence- and Temperature-Dependent Properties of Unfolded and Disordered Proteins from Atomistic Simulations.

PubMed

Zerze, Gül H; Best, Robert B; Mittal, Jeetain

2015-11-19

We use all-atom molecular simulation with explicit solvent to study the properties of selected intrinsically disordered proteins and unfolded states of foldable proteins, which include chain dimensions and shape, secondary structure propensity, solvent accessible surface area, and contact formation. We find that the qualitative scaling behavior of the chains matches expectations from theory under ambient conditions. In particular, unfolded globular proteins tend to be more collapsed under the same conditions than charged disordered sequences of the same length. However, inclusion of explicit solvent in addition naturally captures temperature-dependent solvation effects, which results in an initial collapse of the chains as temperature is increased, in qualitative agreement with experiment. There is a universal origin to the collapse, revealed in the change of hydration of individual residues as a function of temperature: namely, that the initial collapse is driven by unfavorable solvation free energy of individual residues, which in turn has a strong temperature dependence. We also observe that in unfolded globular proteins, increased temperature also initially favors formation of native-like (rather than non-native-like) structure. Our results help to establish how sequence encodes the degree of intrinsic disorder or order as well as its response to changes in environmental conditions.

Measurement of elastic precursor decay in pre-heated aluminum films under ultra-fast laser generated shocks

DOE PAGES

Zuanetti, Bryan; McGrane, Shawn David; Bolme, Cynthia Anne; ...

2018-05-18

Here, this article presents results from laser-driven shock compression experiments performed on pre-heated pure aluminum films at temperatures ranging from 23 to 400 °C. The samples were vapor deposited on the surface of a 500 μm thick sapphire substrate and mounted onto a custom holder with an integrated ring-heater to enable variable initial temperature conditions. A chirped pulse amplified laser was used to generate a pulse for both shocking the films and for probing the free surface velocity using Ultrafast Dynamic Ellipsometry. The particle velocity traces measured at the free surface clearly show elastic and plastic wave separation, which wasmore » used to estimate the decay of the elastic precursor amplitude over propagation distances ranging from 0.278 to 4.595 μm. Elastic precursors (which also correspond to dynamic material strength under uniaxial strain) of increasing amplitudes were observed with increasing initial sample temperatures for all propagation distances, which is consistent with expectations for aluminum in a deformation regime where phonon drag limits the mobility of dislocations. The experimental results show peak elastic amplitudes corresponding to axial stresses of over 7.5 GPa; estimates for plastic strain-rates in the samples are of the order 10 9/s. The measured elastic amplitudes at the micron length scales are compared with those at the millimeter length-scales using a two-parameter model and used to correlate the rate sensitivity of the dynamic strength at strain-rates ranging from 10 3 to 10 9/s and elevated temperature conditions. The overall trend, as inferred from the experimental data, indicates that the temperature-strengthening effect decreases with increasing plastic strain-rates.« less

Measurement of elastic precursor decay in pre-heated aluminum films under ultra-fast laser generated shocks

NASA Astrophysics Data System (ADS)

Zuanetti, Bryan; McGrane, Shawn D.; Bolme, Cynthia A.; Prakash, Vikas

2018-05-01

This article presents results from laser-driven shock compression experiments performed on pre-heated pure aluminum films at temperatures ranging from 23 to 400 °C. The samples were vapor deposited on the surface of a 500 μm thick sapphire substrate and mounted onto a custom holder with an integrated ring-heater to enable variable initial temperature conditions. A chirped pulse amplified laser was used to generate a pulse for both shocking the films and for probing the free surface velocity using Ultrafast Dynamic Ellipsometry. The particle velocity traces measured at the free surface clearly show elastic and plastic wave separation, which was used to estimate the decay of the elastic precursor amplitude over propagation distances ranging from 0.278 to 4.595 μm. Elastic precursors (which also correspond to dynamic material strength under uniaxial strain) of increasing amplitudes were observed with increasing initial sample temperatures for all propagation distances, which is consistent with expectations for aluminum in a deformation regime where phonon drag limits the mobility of dislocations. The experimental results show peak elastic amplitudes corresponding to axial stresses of over 7.5 GPa; estimates for plastic strain-rates in the samples are of the order 109/s. The measured elastic amplitudes at the micron length scales are compared with those at the millimeter length-scales using a two-parameter model and used to correlate the rate sensitivity of the dynamic strength at strain-rates ranging from 103 to 109/s and elevated temperature conditions. The overall trend, as inferred from the experimental data, indicates that the temperature-strengthening effect decreases with increasing plastic strain-rates.

Measurement of elastic precursor decay in pre-heated aluminum films under ultra-fast laser generated shocks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zuanetti, Bryan; McGrane, Shawn David; Bolme, Cynthia Anne

Here, this article presents results from laser-driven shock compression experiments performed on pre-heated pure aluminum films at temperatures ranging from 23 to 400 °C. The samples were vapor deposited on the surface of a 500 μm thick sapphire substrate and mounted onto a custom holder with an integrated ring-heater to enable variable initial temperature conditions. A chirped pulse amplified laser was used to generate a pulse for both shocking the films and for probing the free surface velocity using Ultrafast Dynamic Ellipsometry. The particle velocity traces measured at the free surface clearly show elastic and plastic wave separation, which wasmore » used to estimate the decay of the elastic precursor amplitude over propagation distances ranging from 0.278 to 4.595 μm. Elastic precursors (which also correspond to dynamic material strength under uniaxial strain) of increasing amplitudes were observed with increasing initial sample temperatures for all propagation distances, which is consistent with expectations for aluminum in a deformation regime where phonon drag limits the mobility of dislocations. The experimental results show peak elastic amplitudes corresponding to axial stresses of over 7.5 GPa; estimates for plastic strain-rates in the samples are of the order 10 9/s. The measured elastic amplitudes at the micron length scales are compared with those at the millimeter length-scales using a two-parameter model and used to correlate the rate sensitivity of the dynamic strength at strain-rates ranging from 10 3 to 10 9/s and elevated temperature conditions. The overall trend, as inferred from the experimental data, indicates that the temperature-strengthening effect decreases with increasing plastic strain-rates.« less

Oxidation of Inconel 625 superalloy upon treatment with oxygen or hydrogen plasma at high temperature

NASA Astrophysics Data System (ADS)

Vesel, Alenka; Drenik, Aleksander; Elersic, Kristina; Mozetic, Miran; Kovac, Janez; Gyergyek, Tomaz; Stockel, Jan; Varju, Jozef; Panek, Radomir; Balat-Pichelin, Marianne

2014-06-01

Initial stages of Inconel 625 superalloy (Ni60Cr30Mo10Ni4Nb1) oxidation upon short treatment with gaseous plasma at different temperatures up to about 1600 K were studied. Samples were treated for different periods up to a minute by oxygen or hydrogen plasma created with a microwave discharge in the standing-wave mode at a pressure of 40 Pa and a power 500 W. Simultaneous heating of the samples was realized by focusing concentrated solar radiation from a 5 kW solar furnace directly onto the samples. The morphological changes upon treatment were monitored using scanning electron microscopy, compositional depth profiling was performed using Auger electron spectroscopy, while structural changes were determined by X-ray diffraction. The treatment in oxygen plasma caused formation of metal oxide clusters of three dimensional crystallites initially rich in nickel oxide with the increasing chromium oxide content as the temperature was increasing. At about 1100 K iron and niobium oxides prevailed on the surface causing a drop of the material emissivity at 5 μm. Simultaneously the NiCr2O4 compound started growing at the interface between the oxide film and bulk alloy and the compound persisted up to temperatures close to the Inconel melting point. Intensive migration of minority alloying elements such as Fe and Ti was observed at 1600 K forming mixed surface oxides of sub-micrometer dimensions. The treatment in hydrogen plasma with small admixture of water vapor did not cause much modification unless the temperature was close to the melting point. At such conditions aluminum segregated on the surface and formed well-defined Al2O3 crystals.

Deposition of tantalum carbide coatings on graphite by laser interactions

NASA Technical Reports Server (NTRS)

Veligdan, James; Branch, D.; Vanier, P. E.; Barietta, R. E.

1994-01-01

Graphite surfaces can be hardened and protected from erosion by hydrogen at high temperatures by refractory metal carbide coatings, which are usually prepared by chemical vapor deposition (CVD) or chemical vapor reaction (CVR) methods. These techniques rely on heating the substrate to a temperature where a volatile metal halide decomposes and reacts with either a hydrocarbon gas or with carbon from the substrate. For CVR techniques, deposition temperatures must be in excess of 2000 C in order to achieve favorable deposition kinetics. In an effort to lower the bulk substrate deposition temperature, the use of laser interactions with both the substrate and the metal halide deposition gas has been employed. Initial testing involved the use of a CO2 laser to heat the surface of a graphite substrate and a KrF excimer laser to accomplish a photodecomposition of TaCl5 gas near the substrate. The results of preliminary experiments using these techniques are described.

Two-layer thermal barrier coating for turbine airfoils - furnace and burner rig test results

NASA Technical Reports Server (NTRS)

Stecura, S.

1976-01-01

A simple, two-layer plasma-sprayed thermal barrier coating system was developed which has the potential for protecting high temperature air-cooled gas turbine components. Of those coatings initially examined, the most promising system consisted of a Ni-16Cr-6Al-0.6Y (in wt%) thermal barrier coating (about 0.005 to 0.010 cm thick) and a ZrO2-12Y2O3 (in wt%) thermal barrier coating (about 0.025 to 0.064 cm thick). This thermal barrier substantially lowered the metal temperature of an air-cooled airfoil. The coating withstood 3,200 cycles (80 sec at 1,280 C surface temperature) and 275 cycles (1 hr at 1,490 C surface temperature) without cracking or spalling. No separation of the thermal barrier from the bond coating or the bond coating from the substrate was observed.

Assessing impacts of PBL and surface layer schemes in simulating the surface–atmosphere interactions and precipitation over the tropical ocean using observations from AMIE/DYNAMO

DOE PAGES

Qian, Yun; Yan, Huiping; Berg, Larry K.; ...

2016-10-28

Accuracy of turbulence parameterization in representing Planetary Boundary Layer (PBL) processes in climate models is critical for predicting the initiation and development of clouds, air quality issues, and underlying surface-atmosphere-cloud interactions. In this study, we 1) evaluate WRF model-simulated spatial patterns of precipitation and surface fluxes, as well as vertical profiles of potential temperature, humidity, moist static energy and moisture tendency terms as simulated by WRF at various spatial resolutions and with PBL, surface layer and shallow convection schemes against measurements, 2) identify model biases by examining the moisture tendency terms contributed by PBL and convection processes through nudging experiments,more » and 3) evaluate the dependence of modeled surface latent heat (LH) fluxes onPBL and surface layer schemes over the tropical ocean. The results show that PBL and surface parameterizations have surprisingly large impacts on precipitation, convection initiation and surface moisture fluxes over tropical oceans. All of the parameterizations tested tend to overpredict moisture in PBL and free atmosphere, and consequently result in larger moist static energy and precipitation. Moisture nudging tends to suppress the initiation of convection and reduces the excess precipitation. The reduction in precipitation bias in turn reduces the surface wind and LH flux biases, which suggests that the model drifts at least partly because of a positive feedback between precipitation and surface fluxes. The updated shallow convection scheme KF-CuP tends to suppress the initiation and development of deep convection, consequently decreasing precipitation. The Eta surface layer scheme predicts more reasonable LH fluxes and the LH-Wind Speed relationship than the MM5 scheme, especially when coupled with the MYJ scheme. By examining various parameterization schemes in WRF, we identify sources of biases and weaknesses of current PBL, surface layer and shallow convection schemes in reproducing PBL processes, the initiation of convection and intra-seasonal variability of precipitation.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dai, X.; Antal, M.J. Jr.

Macadamia nut shell charcoal was heated in an inert environment to temperatures above 1000 K (carbonized), reacted with oxygen (Po{sub 2} = 2.68--11.3 kPa) at temperatures between 525 and 586 K (oxygenated), and heated again in an inert environment to temperatures above 1000 K (activated) to produce an activated carbon. Carbons produced by this process possess surface areas and iodine numbers in the range of 400--550. Overall yields of these carbons (based on the dry, raw macadamia nut shell feed) ranged from 24 to 30 wt %. Under the conditions employed in this work, the rates of chemisorption and gasificationmore » were not mass transfer limited. Initially, the gasification reaction was first-order with respect to oxygen concentration but became independent of oxygen concentration as the surface sites of the carbon became saturated with oxygen.« less

Colloidal nanocrystals and method of making

DOEpatents

Kahen, Keith

2015-10-06

A tight confinement nanocrystal comprises a homogeneous center region having a first composition and a smoothly varying region having a second composition wherein a confining potential barrier monotonically increases and then monotonically decreases as the smoothly varying region extends from the surface of the homogeneous center region to an outer surface of the nanocrystal. A method of producing the nanocrystal comprises forming a first solution by combining a solvent and at most two nanocrystal precursors; heating the first solution to a nucleation temperature; adding to the first solution, a second solution having a solvent, at least one additional and different precursor to form the homogeneous center region and at most an initial portion of the smoothly varying region; and lowering the solution temperature to a growth temperature to complete growth of the smoothly varying region.

The evolution of rotating very massive stars with LMC composition

NASA Astrophysics Data System (ADS)

Köhler, K.; Langer, N.; de Koter, A.; de Mink, S. E.; Crowther, P. A.; Evans, C. J.; Gräfener, G.; Sana, H.; Sanyal, D.; Schneider, F. R. N.; Vink, J. S.

2015-01-01

Context. With growing evidence for the existence of very massive stars at subsolar metallicity, there is an increased need for corresponding stellar evolution models. Aims: We present a dense model grid with a tailored input chemical composition appropriate for the Large Magellanic Cloud (LMC). Methods: We use a one-dimensional hydrodynamic stellar evolution code, which accounts for rotation, transport of angular momentum by magnetic fields, and stellar wind mass loss to compute our detailed models. We calculate stellar evolution models with initial masses from 70 to 500 M⊙ and with initial surface rotational velocities from 0 to 550 km s-1, covering the core-hydrogen burning phase of evolution. Results: We find our rapid rotators to be strongly influenced by rotationally induced mixing of helium, with quasi-chemically homogeneous evolution occurring for the fastest rotating models. Above 160 M⊙, homogeneous evolution is also established through mass loss, producing pure helium stars at core hydrogen exhaustion independent of the initial rotation rate. Surface nitrogen enrichment is also found for slower rotators, even for stars that lose only a small fraction of their initial mass. For models above ~150 M⊙ at zero age, and for models in the whole considered mass range later on, we find a considerable envelope inflation due to the proximity of these models to their Eddington limit. This leads to a maximum ZAMS surface temperature of ~56 000 K, at ~180 M⊙, and to an evolution of stars in the mass range 50 M⊙...100 M⊙ to the regime of luminous blue variables in the Hertzsprung-Russell diagram with high internal Eddington factors. Inflation also leads to decreasing surface temperatures during the chemically homogeneous evolution of stars above ~180 M⊙. Conclusions: The cool surface temperatures due to the envelope inflation in our models lead to an enhanced mass loss, which prevents stars at LMC metallicity from evolving into pair-instability supernovae. The corresponding spin-down will also prevent very massive LMC stars to produce long-duration gamma-ray bursts, which might, however, originate from lower masses. The dataset of the presented stellar evolution models is only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/573/A71Appendices are available in electronic form at http://www.aanda.org

An improved empirical dynamic control system model of global mean sea level rise and surface temperature change

NASA Astrophysics Data System (ADS)

Wu, Qing; Luu, Quang-Hung; Tkalich, Pavel; Chen, Ge

2018-04-01

Having great impacts on human lives, global warming and associated sea level rise are believed to be strongly linked to anthropogenic causes. Statistical approach offers a simple and yet conceptually verifiable combination of remotely connected climate variables and indices, including sea level and surface temperature. We propose an improved statistical reconstruction model based on the empirical dynamic control system by taking into account the climate variability and deriving parameters from Monte Carlo cross-validation random experiments. For the historic data from 1880 to 2001, we yielded higher correlation results compared to those from other dynamic empirical models. The averaged root mean square errors are reduced in both reconstructed fields, namely, the global mean surface temperature (by 24-37%) and the global mean sea level (by 5-25%). Our model is also more robust as it notably diminished the unstable problem associated with varying initial values. Such results suggest that the model not only enhances significantly the global mean reconstructions of temperature and sea level but also may have a potential to improve future projections.

Thermal transfer in extracted incisors during thermal pulp sensitivity testing.

PubMed

Linsuwanont, P; Palamara, J E; Messer, H H

2008-03-01

To measure the temperature distribution within tooth structure during and after application of thermal stimuli used during pulp sensitivity testing. Extracted intact human maxillary anterior teeth were investigated for temperature changes at the labial enamel, the dentino-enamel junction (DEJ) and pulpal surface during and after a 5-s application of six different thermal stimuli: hot water (80 degrees C), heated gutta-percha (140 degrees C), carbon dioxide dry ice (-72 degrees C), refrigerant spray (-50 degrees C), ice stick (0 degrees C) and cold water (2 degrees C). J-type thermocouples and heat conduction paste were used to detect temperature changes, together with a data acquisition system (Labview). Data were analysed using analysis of variance, with a confidence level of P < 0.05. Temperature change was detected more quickly at the DEJ and pulpal surface with the application of hot water, heated gutta-percha and refrigerant spray than with carbon dioxide dry ice and ice (P < 0.05). Cold water and refrigerant spray were in the same range in terms of time to detect temperature change at both the DEJ and pulpal surface. Thermal stimuli with greater temperature difference from tooth temperature created a greater thermal gradient initially, followed by a greater temperature change at the DEJ and the pulpal surface. In this regard, ice and cold water were weaker stimuli than others (P < 0.05). Thermal stimuli used in pulp testing are highly variable in terms of temperature of the stimulus, rate of thermal transfer to the tooth and extent of temperature change within tooth structure. Overall, dry ice and refrigerant spray provide the most consistent stimuli, whereas heated gutta-percha and hot water were highly variable. Ice was a weak stimulus.

Characteristics and mechanism of laser-induced surface damage initiated by metal contaminants

NASA Astrophysics Data System (ADS)

Shi, Shuang; Sun, Mingying; Shi, Shuaixu; Li, Zhaoyan; Zhang, Ya-nan; Liu, Zhigang

2015-08-01

In high power laser facility, contaminants on optics surfaces reduce damage resistance of optical elements and then decrease their lifetime. By damage test experiments, laser damage induced by typical metal particles such as stainless steel 304 is studied. Optics samples with metal particles of different sizes on surfaces are prepared artificially based on the file and sieve. Damage test is implemented in air using a 1-on-1 mode. Results show that damage morphology and mechanism caused by particulate contamination on the incident and exit surfaces are quite different. Contaminants on the incident surface absorb laser energy and generate high temperature plasma during laser irradiation which can ablate optical surface. Metal particles melt and then the molten nano-particles redeposit around the initial particles. Central region of the damaged area bears the same outline as the initial particle because of the shielding effect. However, particles on the exit surface absorb a mass of energy, generate plasma and splash lots of smaller particles, only a few of them redeposit at the particle coverage area on the exit surface. Most of the laser energy is deposited at the interface of the metal particle and the sample surface, and thus damage size on the exit surface is larger than that on the incident surface. The areas covered by the metal particle are strongly damaged. And the damage sites are more serious than that on the incident surface. Besides damage phenomenon also depends on coating and substrate materials.

Interactive initialization of heat flux parameters for numerical models using satellite temperature measurements

NASA Technical Reports Server (NTRS)

Carlson, T. N. (Principal Investigator)

1981-01-01

Efforts were made (1) to bring the image processing and boundary layer model operation into a completely interactive mode and (2) to test a method for determining the surface energy budget and surface moisture availability and thermal inertia on a scale appreciably larger than that of the city. A region a few hundred kilometers on a side centered over southern Indiana was examined.

In situ REM and ex situ SPM studies of silicon (111) surface

NASA Astrophysics Data System (ADS)

Aseev, A. L.; Kosolobov, S. S.; Latyshev, A. V.; Song, Se Ahn; Saranin, A. A.; Zotov, A. V.; Lifshits, V. G.

2005-09-01

Combination of experimental methods, including ultrahigh vacuum in situ reflection electron microscopy, scanning tunnelling microscopy and atomic force microscopy, has been applied for analysis of surface structure and dynamic processes on silicon (111) surfaces during sublimation, rapid temperature cooling, oxygen reactions and metal-silicon surface phase formation. From analysis of triangular negative islands, 0.08 nm in depth, which were forming during quenching, it was deduced the effective activation energy of the island generation is equalled to 0.35 eV and made conclusion that the (1 × 1) (7 × 7) phase transition on Si(111) assumes to be responsible for the negative island nucleation. On the base of the in situ REM study, the dependence of step motion, initiated by surface vacancies generation during oxygen-silicon interaction, on the terrace width was measured. Peculiarities of the initial stages of silicon surface oxidation at low pressures were considered. From precision measurements, the top silicon atom density was determined for the metal-silicon surface phase formed during Na, Ca, Mg and Ag deposition on clean silicon (111) surface.

Subsurface temperature signature of a large Pleistocene - Holocene surface warming in the North Alberta, Canada

NASA Astrophysics Data System (ADS)

Majorowicz, J.; Šafanda, J.; Gosnold, W.; Unsworth, M.

2012-04-01

Recent results from a 2.3km deep temperature log in northern Alberta, Canada acquired as part of the University of Alberta Helmholtz-Alberta Initiative (HAI) geothermal energy project in 2010-2011shows that there is a significant increase in thermal gradient in the granites. Inversion of the measured T-z profile between 550 - 2320 m indicates a temperature increase of 9.6 ± 0.3 °C, at 13.0 ± 0.6 ka and that the glacial base surface temperature was - 4.4± 0.3 °C. This inversion computation accounted for granite heat production of 3 µW/m3. This is the largest amplitude of Pleistocene - Holocene surface warming in Canada inferred from borehole temperature logs, and is compatible with the results of similar studies in Eurasia (KTB, Outokumpu, Torun-1 etc.) reported previously. Reference: Majorowicz, J., Unsworth, M., Chacko, T., Gray, A., Heaman L., Potter, D., Schmitt, D., and Babadagli, T., 2011. Geothermal energy as a source of heat for oilsands processing in northern Alberta, Canada, in: Hein, F. J., Leckie, D., Suter , J., and Larter, S., (Eds), Heavy Oil/Bitumen Petroleum Systems in Alberta and beyond, AAPG Mem., in press.

Surface functionalization of 3D-printed plastics via initiated chemical vapor deposition

PubMed Central

Cheng, Christine

2017-01-01

3D printing is a useful fabrication technique because it offers design flexibility and rapid prototyping. The ability to functionalize the surfaces of 3D-printed objects allows the bulk properties, such as material strength or printability, to be chosen separately from surface properties, which is critical to expanding the breadth of 3D printing applications. In this work, we studied the ability of the initiated chemical vapor deposition (iCVD) process to coat 3D-printed shapes composed of poly(lactic acid) and acrylonitrile butadiene styrene. The thermally insulating properties of 3D-printed plastics pose a challenge to the iCVD process due to large thermal gradients along the structures during processing. In this study, processing parameters such as the substrate temperature and the filament temperature were systematically varied to understand how these parameters affect the uniformity of the coatings along the 3D-printed objects. The 3D-printed objects were coated with both hydrophobic and hydrophilic polymers. Contact angle goniometry and X-ray photoelectron spectroscopy were used to characterize the functionalized surfaces. Our results can enable the use of iCVD to functionalize 3D-printed materials for a range of applications such as tissue scaffolds and microfluidics. PMID:28875099

Development and Test Evaluations for Ni-DOBDC Metal Organic Framework (MOF) Engineered Forms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Troy G. Garn; Mitchell Greenhalgh

2013-07-01

A joint effort to prepare engineered forms of a Ni-DOBDC metal organic framework (MOF) was completed with contributions from PNNL, SNL and the INL. Two independent methods were used at INL and SNL to prepare engineered form (EF) sorbents from Ni-DOBDC MOF powder developed and prepared at PNNL. Xe and Kr capacity test evaluations were performed at ambient temperature with the cryostat experimental setup at INL. The initial INL EF MOF test results indicated a Xe capacity of 1.6 mmol/kg sorbent and no Kr capacity. A large loss of surface area also occurred during minimal testing rendering the INL EFmore » MOF unusable. Four capacity tests were completed using the SNL EF MOF at ambient temperature and resulted in Xe capacities of 1.4, 4.2, 5.0 and 3.8 mmol/kg sorbent with no Kr capacity observed in any ambient temperature tests. Two additional capacity tests were performed at 240 K to further evaluate SNL EF MOF performance. Xe capacities of 50.7 and 49.3 mmol/kg of sorbent and Kr capacities of 0.77 and 0.69 mmol/kg of sorbent were obtained, respectively. Following the adsorption evaluations, the SNL EF MOF material had lost about 40 % of the initial mass and 40 % of the initial surface area. In general, the Xe capacity results at ambient temperature for the INL and SNL EF Ni-DOBDC MOF’s were lower than 9.8 mmol Xe/kg sorbent test results reported by INL in FY-12 using PNNL’s inital EF supplied material.« less

The role of surface generated radicals in catalytic combustion

NASA Technical Reports Server (NTRS)

Santavicca, D. A.; Stein, Y.; Royce, B. S. H.

1985-01-01

Experiments were conducted to better understand the role of catalytic surface reactions in determining the ignition characteristics of practical catalytic combustors. Hydrocarbon concentrations, carbon monoxide and carbon dioxide concentrations, hydroxyl radical concentrations, and gas temperature were measured at the exit of a platinum coated, stacked plate, catalytic combustor during the ignition of lean propane-air mixtures. The substrate temperature profile was also measured during the ignition transient. Ignition was initiated by suddenly turning on the fuel and the time to reach steady state was of the order of 10 minutes. The gas phase reaction, showed no pronounced effect due to the catalytic surface reactions, except the absence of a hydroxyl radical overshoot. It is found that the transient ignition measurements are valuable in understanding the steady state performance characteristics.

Room-temperature processing of CdSe quantum dots with tunable sizes

NASA Astrophysics Data System (ADS)

Joo, So-Yeong; Jeong, Da-Woon; Lee, Chan-Gi; Kim, Bum-Sung; Park, Hyun-Su; Kim, Woo-Byoung

2017-06-01

In this work, CdSe quantum dots (QDs) with tunable sizes have been fabricated via photo-induced chemical etching at room temperature, and the related reaction mechanism was investigated. The surface of QDs was oxidized by the holes generated through photon irradiation of oxygen species, and the obtained oxide layer was dissolved in an aqueous solution of 3-amino-1-propanol (APOL) with an APOL:H2O volume ratio of 5:1. The generated electrons promoted QD surface interactions with amino groups, which ultimately passivated surface defects. The absorption and photoluminescence emission peaks of the produced QDs were clearly blue-shifted about 26 nm with increasing time, and the resulting quantum yield for an 8 h etched sample was increased from 20% to 26%, as compared to the initial sample.

Effects of Variable Surface Temperatures on the Dynamics of Convection within Enceladus' Ice Shell

NASA Astrophysics Data System (ADS)

Weller, M. B.; Fuchs, L.; Becker, T. W.; Soderlund, K. M.

2017-12-01

Despite Enceladus' relatively small size, observations reveal it as one of the more geologically active bodies in the solar system. Its surface is heavily deformed, including ridges, grooves, grabens, rifts, and folds that cover a significant fraction of the planet. Perhaps most notably, there is evidence of a hemispheric dichotomy between the south (the South Polar Terrain - SPT), and the remainder of the satellite. While the origin of the SPT has spurred much debate, ranging from oceans and tides to impacts, its existence suggests some form of localization process. Here, we use the mantle convection code CitcomS with temperature-dependent viscosity to address the effects of latitudinally variable surface temperature (due to differences in solar heating) for a range of internal heating rates (as proxy for tidal heating)on the convective vigor and planform within Enceladus' ice shell. Heterogeneous surface temperatures can produce a large, degree-1 upwelling with the other hemisphere fully dominated by a slower, colder downwelling. As internal heating decreases, the degree-1 upwelling forms and localizes, resulting in larger strain rates that arerestricted to 5-20% of the satellite. The remaining 80-95% of the surface remains cold and relatively quiescent, in general agreement with observations of Enceladus and the SPT today. These results show the initial degree-1 structure forms at a polar latitude, the region of greatest radial temperature contrast. This configuration is unstable, however, with the plume structure migrating towards a stable orientation at equatorial latitudes, the region of the highest absolute surface temperature. While an equatorial configuration is currently not witnessed on Enceladus,such a large and persistent dynamic structure could lead to reorientation of the satellite.

Development of Advanced Thermal and Environmental Barrier Coatings Using a High-Heat-Flux Testing Approach

NASA Technical Reports Server (NTRS)

Zhu, Dongming; Miller, Robert A.

2003-01-01

The development of low conductivity, robust thermal and environmental barrier coatings requires advanced testing techniques that can accurately and effectively evaluate coating thermal conductivity and cyclic resistance at very high surface temperatures (up to 1700 C) under large thermal gradients. In this study, a laser high-heat-flux test approach is established for evaluating advanced low conductivity, high temperature capability thermal and environmental barrier coatings under the NASA Ultra Efficient Engine Technology (UEET) program. The test approach emphasizes the real-time monitoring and assessment of the coating thermal conductivity, which initially rises under the steady-state high temperature thermal gradient test due to coating sintering, and later drops under the cyclic thermal gradient test due to coating cracking/delamination. The coating system is then evaluated based on damage accumulation and failure after the combined steady-state and cyclic thermal gradient tests. The lattice and radiation thermal conductivity of advanced ceramic coatings can also be evaluated using laser heat-flux techniques. The external radiation resistance of the coating is assessed based on the measured specimen temperature response under a laser- heated intense radiation-flux source. The coating internal radiation contribution is investigated based on the measured apparent coating conductivity increases with the coating surface test temperature under large thermal gradient test conditions. Since an increased radiation contribution is observed at these very high surface test temperatures, by varying the laser heat-flux and coating average test temperature, the complex relation between the lattice and radiation conductivity as a function of surface and interface test temperature may be derived.

Altimetric lagrangian advection to reconstruct Pacific Ocean fine scale surface tracer fields

NASA Astrophysics Data System (ADS)

Rogé, Marine; Morrow, Rosemary; Dencausse, Guillaume

2015-04-01

In past studies, lagrangian stirring of surface tracer fields by altimetric surface geostrophic currents has been performed in different mid to high-latitude regions, showing good results in reconstructing finer-scale tracer patterns. Here we apply the technique to three different regions in the eastern and western tropical Pacific, and in the subtropical southwest Pacific. Initial conditions are derived from weekly gridded temperature and salinity fields, based on hydrographic data and Argo. Validation of the improved fine-scale surface tracer fields is performed using satellite AMSRE SST data, and high-resolution ship thermosalinograph data. We test two kinds of lagrangian advection. The standard one-way advection is shown to introduce an increased tracer bias as the advection time increases. Indeed, since we only use passive stirring, a bias is introduced from the missing physics, such as air-sea fluxes or mixing. A second "backward-forward" advection technique is shown to reduce the seasonal bias, but more data is lost around coasts and islands, a strong handicap in the tropical Pacific with many small islands. In the subtropical Pacific Ocean, the mesoscale temperature and salinity fronts are well represented by the one-way advection over a 10-day advection time, including westward propagating features not apparent in the initial fields. In the tropics, the results are less clear. The validation is hampered by the complex vertical stratification, and the technique is limited by the lack of accurate surface currents for the stirring - the gridded altimetric fields poorly represent the meridional currents, and are not detecting the fast tropical instability waves, nor the wind-driven circulation. We suggest that the passive lateral stirring technique is efficient in regions with moderate the high mesoscale energy and correlated mesoscale surface temperature and surface height. In other regions, more complex dynamical processes may need to be included.

Assessing the Regional/Diurnal Bias between Satellite Retrievals and GEOS-5/MERRA Model Estimates of Land Surface Temperature

NASA Astrophysics Data System (ADS)

Scarino, B. R.; Smith, W. L., Jr.; Minnis, P.; Bedka, K. M.

2017-12-01

Atmospheric models rely on high-accuracy, high-resolution initial radiometric and surface conditions for better short-term meteorological forecasts, as well as improved evaluation of global climate models. Continuous remote sensing of the Earth's energy budget, as conducted by the Clouds and Earth's Radiant Energy System (CERES) project, allows for near-realtime evaluation of cloud and surface radiation properties. It is unfortunately common for there to be bias between atmospheric/surface radiation models and Earth-observations. For example, satellite-observed surface skin temperature (Ts), an important parameter for characterizing the energy exchange at the ground/water-atmosphere interface, can be biased due to atmospheric adjustment assumptions and anisotropy effects. Similarly, models are potentially biased by errors in initial conditions and regional forcing assumptions, which can be mitigated through assimilation with true measurements. As such, when frequent, broad-coverage, and accurate retrievals of satellite Ts are available, important insights into model estimates of Ts can be gained. The Satellite ClOud and Radiation Property retrieval System (SatCORPS) employs a single-channel thermal-infrared method to produce anisotropy-corrected Ts over clear-sky land and ocean surfaces from data taken by geostationary Earth orbit (GEO) satellite imagers. Regional and diurnal changes in model land surface temperature (LST) performance can be assessed owing to the somewhat continuous measurements of the LST offered by GEO satellites - measurements which are accurate to within 0.2 K. A seasonal, hourly comparison of satellite-observed LST with the NASA Goddard Earth Observing System Version 5 (GEOS-5) and the Modern-Era Retrospective Analysis for Research and Applications (MERRA) LST estimates is conducted to reveal regional and diurnal biases. This assessment is an important first step for evaluating the effectiveness of Ts assimilation, as well for determining the impact anisotropy correction has on observation - model bias, and is of critical importance for CERES.

Surface spectroscopy studies of the oxidation behavior of uranium

NASA Astrophysics Data System (ADS)

Bloch, J.; Atzmony, U.; Dariel, M. P.; Mintz, M. H.; Shamir, N.

1982-02-01

Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS) techniques were utilized to study the oxidation behavior of clean uranium surfaces, at very low pressures of various atmospheres (UHV, H 2, O 2, and CO 2), at room temperature. Both for O 2 and CO 2, a precursor chemisorbed oxygen species has been identified at the very initial stage of the oxidation reaction. This chemisorbed oxygen transforms to the oxide form at a rate which depends on the pressure of the oxidizing atmosphere. Residual gaseous carbon compounds which are present even under UHV conditions result in the simultaneous formation of surface carbide which accompanies the initial stage of oxidation. This carbide however decomposes later as oxidation proceeds. Adventitious hydrocarbon adsorption occurs on the formed oxide layer.

Ion beam microtexturing of surfaces

NASA Technical Reports Server (NTRS)

Robinson, R. S.

1981-01-01

Some recent work in surface microtecturing by ion beam sputtering is described. The texturing is accomplished by deposition of an impurity onto a substrate while simultaneously bombarding it with an ion beam. A summary of the theory regarding surface diffusion of impurities and the initiation of cone formation is provided. A detailed experimental study of the time-development of individual sputter cones is described. A quasi-liquid coating was observed that apparently reduces the sputter rate of the body of a cone compared to the bulk material. Experimental measurements of surface diffusion activation energies are presented for a variety of substrate-seed combinations and range from about 0.3 eV to 1.2 eV. Observations of apparent crystal structure in sputter cones are discussed. Measurements of the critical temperature for cone formation are also given along with a correlation of critical temperature with substrate sputter rate.

Rewetting of hot vertical rod during jet impingement surface cooling

NASA Astrophysics Data System (ADS)

Agrawal, Chitranjan; Kumar, Ravi; Gupta, Akhilesh; Chatterjee, Barun

2016-06-01

A stainless steel (SS-316) vertical rod of 12 mm diameter at 800 ± 10 °C initial temperature was cooled by normal impinging round water jet. The surface rewetting phenomenon was investigated for a range of jet diameter 2.5-4.8 mm and jet Reynolds number 5000-24,000 using a straight tube type nozzle. The investigation were made from the stagnation point to maximum 40 mm downstream locations, simultaneously for both upside and downside directions. The cooling performance of the vertical rod was evaluated on the basis of rewetting parameters i.e. rewetting temperature, wetting delay, rewetting velocity and the maximum surface heat flux. Two separate Correlations have been proposed for the dimensionless rewetting velocity in terms of rewetting number and the maximum surface heat flux that predicts the experimental data within an error band of ±20 and ±15 % respectively.

Effects of Medium Temperature and Industrial By-Products on the Key Hardened Properties of High Performance Concrete.

PubMed

Safiuddin, Md; Raman, Sudharshan N; Zain, Muhammad Fauzi Mohd

2015-12-10

The aim of the work reported in this article was to investigate the effects of medium temperature and industrial by-products on the key hardened properties of high performance concrete. Four concrete mixes were prepared based on a water-to-binder ratio of 0.35. Two industrial by-products, silica fume and Class F fly ash, were used separately and together with normal portland cement to produce three concrete mixes in addition to the control mix. The properties of both fresh and hardened concretes were examined in the laboratory. The freshly mixed concrete mixes were tested for slump, slump flow, and V-funnel flow. The hardened concretes were tested for compressive strength and dynamic modulus of elasticity after exposing to 20, 35 and 50 °C. In addition, the initial surface absorption and the rate of moisture movement into the concretes were determined at 20 °C. The performance of the concretes in the fresh state was excellent due to their superior deformability and good segregation resistance. In their hardened state, the highest levels of compressive strength and dynamic modulus of elasticity were produced by silica fume concrete. In addition, silica fume concrete showed the lowest level of initial surface absorption and the lowest rate of moisture movement into the interior of concrete. In comparison, the compressive strength, dynamic modulus of elasticity, initial surface absorption, and moisture movement rate of silica fume-fly ash concrete were close to those of silica fume concrete. Moreover, all concretes provided relatively low compressive strength and dynamic modulus of elasticity when they were exposed to 50 °C. However, the effect of increased temperature was less detrimental for silica fume and silica fume-fly ash concretes in comparison with the control concrete.

Thermomechanical Fatigue Damage/Failure Mechanisms in SCS-6/Timetal 21S [0/90](Sub S) Composite

NASA Technical Reports Server (NTRS)

Castelli, Michael G.

1994-01-01

The thermomechanical fatigue (TMF) deformation, damage, and life behaviors of SCS6/Timetal 21S (0/90)s were investigated under zero-tension conditions. In-phase (IP) and out-of-phase (OP) loadings were investigated with a temperature cycle from 150 to 650 deg C. An advanced TMF test technique was used to quantify mechanically damage progression. The technique incorporated explicit measurements of the macroscopic (1) isothermal static moduli at the temperature extremes of the TMF cycle and (2) coefficient of thermal expansion (CTE) as functions of the TMF cycles. The importance of thermal property degradation and its relevance to accurate post-test data analysis and interpretation is briefly addressed. Extensive fractography and metallography were conducted on specimens from failed and interrupted tests to characterize the extent of damage at the microstructure level. Fatigue life results indicated trends analogous to those established for similar unidirectional(0) reinforced titanium matrix composite systems. High stress IP and mid to low stress OP loading conditions were life-limiting in comparison to maximum temperature isothermal conditions. Dominant damage mechanisms changed with cycle type. Damage resulting from IP TMF conditions produced measurable decreases in static moduli but only minimal changes in the CTE. Metallography on interrupted and failed specimens revealed extensive (0) fiber cracking with sparse matrix damage. No surface initiated matrix cracks were present. Comparable OP TMF conditions initiated environment enhanced surface cracking and matrix cracking initiated at (90) fiber/matrix (F/M) interfaces. Notable static moduli and CTE degradations were measured. Fractography and metallography revealed that the transverse cracks originating from the surface and (90) F/M interfaces tended to converge and coalesce at the (0) fibers.

Thermal Conductivity and Elastic Modulus Evolution of Thermal Barrier Coatings under High Heat Flux Conditions

NASA Technical Reports Server (NTRS)

Zhu, Dongming; Miller, Robert A.

1999-01-01

Laser high heat flux test approaches have been established to obtain critical properties of ceramic thermal barrier coatings (TBCs) under near-realistic temperature and thermal gradients that may he encountered in advanced engine systems. Thermal conductivity change kinetics of a thin ceramic coating were continuously monitored in real time at various test temperatures. A significant thermal conductivity increase was observed during the laser simulated engine heat flux tests. For a 0.25 mm thick ZrO2-8%Y2O3 coating system, the overall thermal conductivity increased from the initial value of 1.0 W/m-K to 1. 15 W/m-K, 1. 19 W/m-K and 1.5 W/m-K after 30 hour testing at surface temperatures of 990C, 1100C, and 1320C. respectively. Hardness and modulus gradients across a 1.5 mm thick TBC system were also determined as a function of laser testing time using the laser sintering/creep and micro-indentation techniques. The coating Knoop hardness values increased from the initial hardness value of 4 GPa to 5 GPa near the ceramic/bond coat interface, and to 7.5 GPa at the ceramic coating surface after 120 hour testing. The ceramic surface modulus increased from an initial value of about 70 GPa to a final value of 125 GPa. The increase in thermal conductivity and the evolution of significant hardness and modulus gradients in the TBC systems are attributed to sintering-induced micro-porosity gradients under the laser-imposed high thermal gradient conditions. The test techniques provide a viable means for obtaining coating data for use in design, development, stress modeling, and life prediction for various thermal barrier coating applications.

Effects of Medium Temperature and Industrial By-Products on the Key Hardened Properties of High Performance Concrete

PubMed Central

Safiuddin, Md.; Raman, Sudharshan N.; Zain, Muhammad Fauzi Mohd.

2015-01-01

The aim of the work reported in this article was to investigate the effects of medium temperature and industrial by-products on the key hardened properties of high performance concrete. Four concrete mixes were prepared based on a water-to-binder ratio of 0.35. Two industrial by-products, silica fume and Class F fly ash, were used separately and together with normal portland cement to produce three concrete mixes in addition to the control mix. The properties of both fresh and hardened concretes were examined in the laboratory. The freshly mixed concrete mixes were tested for slump, slump flow, and V-funnel flow. The hardened concretes were tested for compressive strength and dynamic modulus of elasticity after exposing to 20, 35 and 50 °C. In addition, the initial surface absorption and the rate of moisture movement into the concretes were determined at 20 °C. The performance of the concretes in the fresh state was excellent due to their superior deformability and good segregation resistance. In their hardened state, the highest levels of compressive strength and dynamic modulus of elasticity were produced by silica fume concrete. In addition, silica fume concrete showed the lowest level of initial surface absorption and the lowest rate of moisture movement into the interior of concrete. In comparison, the compressive strength, dynamic modulus of elasticity, initial surface absorption, and moisture movement rate of silica fume-fly ash concrete were close to those of silica fume concrete. Moreover, all concretes provided relatively low compressive strength and dynamic modulus of elasticity when they were exposed to 50 °C. However, the effect of increased temperature was less detrimental for silica fume and silica fume-fly ash concretes in comparison with the control concrete. PMID:28793732

Predictive Finite Rate Model for Oxygen-Carbon Interactions at High Temperature

NASA Astrophysics Data System (ADS)

Poovathingal, Savio

An oxidation model for carbon surfaces is developed to predict ablation rates for carbon heat shields used in hypersonic vehicles. Unlike existing empirical models, the approach used here was to probe gas-surface interactions individually and then based on an understanding of the relevant fundamental processes, build a predictive model that would be accurate over a wide range of pressures and temperatures, and even microstructures. Initially, molecular dynamics was used to understand the oxidation processes on the surface. The molecular dynamics simulations were compared to molecular beam experiments and good qualitative agreement was observed. The simulations reproduced cylindrical pitting observed in the experiments where oxidation was rapid and primarily occurred around a defect. However, the studies were limited to small systems at low temperatures and could simulate time scales only of the order of nanoseconds. Molecular beam experiments at high surface temperature indicated that a majority of surface reaction products were produced through thermal mechanisms. Since the reactions were thermal, they occurred over long time scales which were computationally prohibitive for molecular dynamics to simulate. The experiments provided detailed dynamical data on the scattering of O, O2, CO, and CO2 and it was found that the data from molecular beam experiments could be used directly to build a model. The data was initially used to deduce surface reaction probabilities at 800 K. The reaction probabilities were then incorporated into the direct simulation Monte Carlo (DSMC) method. Simulations were performed where the microstructure was resolved and dissociated oxygen convected and diffused towards it. For a gas-surface temperature of 800 K, it was found that despite CO being the dominant surface reaction product, a gas-phase reaction forms significant CO2 within the microstructure region. It was also found that surface area did not play any role in concentration of reaction products because the reaction probabilities were in the diffusion dominant regime. The molecular beam data at different surface temperatures was then used to build a finite rate model. Each reaction mechanism and all rate parameters of the new model were determined individually based on the molecular beam data. Despite the experiments being performed at near vacuum conditions, the finite rate model developed using the data could be used at pressures and temperatures relevant to hypersonic conditions. The new model was implemented in a computational fluid dynamics (CFD) solver and flow over a hypersonic vehicle was simulated. The new model predicted similar overall mass loss rates compared to existing models, however, the individual species production rates were completely different. The most notable difference was that the new model (based on molecular beam data) predicts CO as the oxidation reaction product with virtually no CO2 production, whereas existing models predict the exact opposite trend. CO being the dominant oxidation product is consistent with recent high enthalpy wind tunnel experiments. The discovery that measurements taken in molecular beam facilities are able to determine individual reaction mechanisms, including dependence on surface coverage, opens up an entirely new way of constructing ablation models.

Silicon Carbide Etching Using Chlorine Trifluoride Gas

NASA Astrophysics Data System (ADS)

Habuka, Hitoshi; Oda, Satoko; Fukai, Yasushi; Fukae, Katsuya; Takeuchi, Takashi; Aihara, Masahiko

2005-03-01

The etch rate, chemical reactions and etched surface of β-silicon carbide are studied in detail using chlorine trifluoride gas. The etch rate is greater than 10 μm min-1 at 723 K with a flow rate of 0.1 \\ell min-1 at atmospheric pressure in a horizontal reactor. The maximum etch rate at a substrate temperature of 773 K is 40 μm min-1 with a flow rate of 0.25 \\ell min-1. The step-like pattern that initially exists on the β-silicon carbide surface tends to be smoothed; the root-mean-square surface roughness decreases from its initial value of 5 μm to 1 μm within 15 min; this minimum value is maintained for more than 15 min. Therefore, chlorine trifluoride gas is considered to have a large etch rate for β-silicon carbide associated with making a rough surface smooth.

Estimation of state and material properties during heat-curing molding of composite materials using data assimilation: A numerical study.

PubMed

Matsuzaki, Ryosuke; Tachikawa, Takeshi; Ishizuka, Junya

2018-03-01

Accurate simulations of carbon fiber-reinforced plastic (CFRP) molding are vital for the development of high-quality products. However, such simulations are challenging and previous attempts to improve the accuracy of simulations by incorporating the data acquired from mold monitoring have not been completely successful. Therefore, in the present study, we developed a method to accurately predict various CFRP thermoset molding characteristics based on data assimilation, a process that combines theoretical and experimental values. The degree of cure as well as temperature and thermal conductivity distributions during the molding process were estimated using both temperature data and numerical simulations. An initial numerical experiment demonstrated that the internal mold state could be determined solely from the surface temperature values. A subsequent numerical experiment to validate this method showed that estimations based on surface temperatures were highly accurate in the case of degree of cure and internal temperature, although predictions of thermal conductivity were more difficult.

Global temperature change

PubMed Central

Hansen, James; Sato, Makiko; Ruedy, Reto; Lo, Ken; Lea, David W.; Medina-Elizade, Martin

2006-01-01

Global surface temperature has increased ≈0.2°C per decade in the past 30 years, similar to the warming rate predicted in the 1980s in initial global climate model simulations with transient greenhouse gas changes. Warming is larger in the Western Equatorial Pacific than in the Eastern Equatorial Pacific over the past century, and we suggest that the increased West–East temperature gradient may have increased the likelihood of strong El Niños, such as those of 1983 and 1998. Comparison of measured sea surface temperatures in the Western Pacific with paleoclimate data suggests that this critical ocean region, and probably the planet as a whole, is approximately as warm now as at the Holocene maximum and within ≈1°C of the maximum temperature of the past million years. We conclude that global warming of more than ≈1°C, relative to 2000, will constitute “dangerous” climate change as judged from likely effects on sea level and extermination of species. PMID:17001018

Alloying Elements Transition Into the Weld Metal When Using an Inventor Power Source

NASA Astrophysics Data System (ADS)

Mamadaliev, R. A.; Kuskov, V. N.; Popova, A. A.; Valuev, D. V.

2016-04-01

The temperature distribution over the surface of the welded 12Kh18N10T steel plates using the inventor power source ARC-200 has been calculated. In order to imitate multipass welding when conducting the thermal analysis the initial temperature was changed from 298K up to 798K in 100K increments. It has been determined that alloying elements transition into the weld metal depends on temperature. Using an inventor power source facilitates a uniform distribution of alloying elements along the length and height of the weld seam.

Recording Rapidly Changing Cylinder-wall Temperatures

NASA Technical Reports Server (NTRS)

Meier, Adolph

1942-01-01

The present report deals with the design and testing of a measuring plug suggested by H. Pfriem for recording quasi-stationary cylinder wall temperatures. The new device is a resistance thermometer, the temperature-susceptible part of which consists of a gold coating applied by evaporation under high vacuum and electrolytically strengthened. After overcoming initial difficulties, calibration of plugs up to and beyond 400 degrees C was possible. The measurements were made on high-speed internal combustion engines. The increasing effect of carbon deposit at the wall surface with increasing operating period is indicated by means of charts.

The prediction of surface temperature in the new seasonal prediction system based on the MPI-ESM coupled climate model

NASA Astrophysics Data System (ADS)

Baehr, J.; Fröhlich, K.; Botzet, M.; Domeisen, D. I. V.; Kornblueh, L.; Notz, D.; Piontek, R.; Pohlmann, H.; Tietsche, S.; Müller, W. A.

2015-05-01

A seasonal forecast system is presented, based on the global coupled climate model MPI-ESM as used for CMIP5 simulations. We describe the initialisation of the system and analyse its predictive skill for surface temperature. The presented system is initialised in the atmospheric, oceanic, and sea ice component of the model from reanalysis/observations with full field nudging in all three components. For the initialisation of the ensemble, bred vectors with a vertically varying norm are implemented in the ocean component to generate initial perturbations. In a set of ensemble hindcast simulations, starting each May and November between 1982 and 2010, we analyse the predictive skill. Bias-corrected ensemble forecasts for each start date reproduce the observed surface temperature anomalies at 2-4 months lead time, particularly in the tropics. Niño3.4 sea surface temperature anomalies show a small root-mean-square error and predictive skill up to 6 months. Away from the tropics, predictive skill is mostly limited to the ocean, and to regions which are strongly influenced by ENSO teleconnections. In summary, the presented seasonal prediction system based on a coupled climate model shows predictive skill for surface temperature at seasonal time scales comparable to other seasonal prediction systems using different underlying models and initialisation strategies. As the same model underlying our seasonal prediction system—with a different initialisation—is presently also used for decadal predictions, this is an important step towards seamless seasonal-to-decadal climate predictions.

Field-calibrated model of melt, refreezing, and runoff for polar ice caps: Application to Devon Ice Cap

NASA Astrophysics Data System (ADS)

Morris, Richard M.; Mair, Douglas W. F.; Nienow, Peter W.; Bell, Christina; Burgess, David O.; Wright, Andrew P.

2014-09-01

Understanding the controls on the amount of surface meltwater that refreezes, rather than becoming runoff, over polar ice masses is necessary for modeling their surface mass balance and ultimately for predicting their future contributions to global sea level change. We present a modified version of a physically based model that includes an energy balance routine and explicit calculation of near-surface meltwater refreezing capacity, to simulate the evolution of near-surface density and temperature profiles across Devon Ice Cap in Arctic Canada. Uniquely, our model is initiated and calibrated using high spatial resolution measurements of snow and firn densities across almost the entire elevation range of the ice cap for the summer of 2004 and subsequently validated with the same type of measurements obtained during the very different meteorological conditions of summer 2006. The model captures the spatial variability across the transect in bulk snowpack properties although it slightly underestimates the flow of meltwater into the firn of previous years. The percentage of meltwater that becomes runoff is similar in both years; however, the spatial pattern of this melt-runoff relationship is different in the 2 years. The model is found to be insensitive to variation in the depth of impermeable layers within the firn but is very sensitive to variation in air temperature, since the refreezing capacity of firn decreases with increasing temperature. We highlight that the sensitivity of the ice cap's surface mass balance to air temperature is itself dependent on air temperature.

Modeled Seasonal Variations of Firn Density Induced by Steady State Surface Air Temperature Cycle

NASA Technical Reports Server (NTRS)

Jun, Li; Zwally, H. Jay; Koblinsky, Chester J. (Technical Monitor)

2001-01-01

Seasonal variations of firn density in ice-sheet firn layers have been attributed to variations in deposition processes or other processes within the upper firn. A recent high-resolution (mm scale) density profile, measured along a 181 m core from Antarctica, showed small-scale density variations with a clear seasonal cycle that apparently was not-related to seasonal variations in deposition or known near-surface processes (Gerland and others 1999). A recent model of surface elevation changes (Zwally and Li, submitted) produced a seasonal variation in firn densification, and explained the seasonal surface elevation changes observed by satellite radar altimeters. In this study, we apply our 1-D time-dependent numerical model of firn densification that includes a temperature-dependent formulation of firn densification based on laboratory measurements of grain growth. The model is driven by a steady-state seasonal surface temperature and a constant accumulation rate appropriate for the measured Antarctic ice core. The modeled seasonal variations in firn density show that the layers of snow deposited during spring to mid-summer with the highest temperature history compress to the highest density, and the layers deposited during later summer to autumn with the lowest temperature history compress to the lowest density. The initial amplitude of the seasonal difference of about 0.13 reduces to about 0.09 in five years and asymptotically to 0.92 at depth, which is consistent with the core measurements.

Assimilation of GOES Land Surface Data Within a Rapid Update Cycle Format: Impact on MM5 Warm Season QPF

NASA Technical Reports Server (NTRS)

Lapenta, William M.; Suggs, Ron; Jedlovec, Gary; McNider, Richard T.; Dembek, Scott; Arnold, James E. (Technical Monitor)

2001-01-01

A technique has been developed for assimilating GOES-derived skin temperature tendencies and insolation into the surface energy budget equation of a mesoscale model so that the simulated rate of temperature change closely agrees with the satellite observations. A critical assumption of the technique is that the availability of moisture (either from the soil or vegetation) is the least known term in the model's surface energy budget. Therefore, the simulated latent heat flux, which is a function of surface moisture availability, is adjusted based upon differences between the modeled and satellite-observed skin temperature tendencies. An advantage of this technique is that satellite temperature tendencies are assimilated in an energetically consistent manner that avoids energy imbalances and surface stability problems that arise from direct assimilation of surface shelter temperatures. The fact that the rate of change of the satellite skin temperature is used rather than the absolute temperature means that sensor calibration is not as critical. The focus of this paper is to examine how the satellite assimilation technique impacts simulations of near-surface meteorology on the 0-to 12-hour time scale when implemented within a local rapid update cycle (LRUC) format. The PSU/NCAR MM5 V34 is used and configured with a 36-km CONUS domain and a 12-km nest centered over the southeastern US. The LRUC format consists of a sequence of 12-hour forecasts initialized every hour between 12 and 18 UTC seven days a week. GOES skin temperature tendencies and solar insolation are assimilated in a 1-hour period prior to the start of each twelve-hour forecast. A unique aspect of the LRUC is the satellite assimilation and the continuous recycling of the adjusted moisture availability field from one forecast cycle to the next. Preliminary results for a seven-day trial period indicate that hourly LST tendencies assimilated in a 1 hour LRUC showed improved simulated air and dewpoint temperatures for all cycles on each day. The LRUC will be used during the 2001 summer months to identify the impact of the assimilation on warm season QPF Results will be presented at the meeting.

Distribution law of temperature changes during methane adsorption and desorption in coal using infrared thermography technology

NASA Astrophysics Data System (ADS)

Zhao, Dong; Chen, Hao; An, Jiangfei; Zhou, Dong; Feng, Zengchao

2018-05-01

Gas adsorption and desorption is a thermodynamic process that takes place within coal as temperature changes and that is related to methane (CH4) storage. As infrared thermographic technology has been applied in this context to measure surface temperature changes, the aim of this research was to further elucidate the distribution law underlying this process as well as the thermal effects induced by heat adsorption and desorption in coal. Specimens of two different coal ranks were used in this study, and the surface temperature changes seen in the latter were detected. A contour line map was then drawn on the basis of initial results enabling a distribution law of temperature changes for samples. The results show that different regions of coal sample surfaces exhibit different heating rates during the adsorption process, but they all depends on gas storage capacity to a certain extent. It proposes a correlation coefficient that expresses the relationship between temperature change and gas adsorption capacity that could also be used to evaluate the feasibility of coalbed CH4 extraction in the field. And finally, this study is deduced a method to reveal the actual adsorption capacity of coal or CH4 reservoirs in in situ coal seams.

Initiated chemical vapor deposition of thermoresponsive poly(N-vinylcaprolactam) thin films for cell sheet engineering.

PubMed

Lee, Bora; Jiao, Alex; Yu, Seungjung; You, Jae Bem; Kim, Deok-Ho; Im, Sung Gap

2013-08-01

Poly(N-vinylcaprolactam) (PNVCL) is a thermoresponsive polymer known to be nontoxic, water soluble and biocompatible. Here, PNVCL homopolymer was successfully synthesized for the first time by use of a one-step vapor-phase process, termed initiated chemical vapor deposition (iCVD). Fourier transform infrared spectroscopy results showed that radical polymerization took place from N-vinylcaprolactam monomers without damaging the functional caprolactam ring. A sharp lower critical solution temperature transition was observed at 31°C from the iCVD poly(N-vinylcaprolactam) (PNVCL) film. The thermoresponsive PNVCL surface exhibited a hydrophilic/hydrophobic alteration with external temperature change, which enabled the thermally modulated attachment and detachment of cells. The conformal coverage of PNVCL film on various substrates with complex topography, including fabrics and nanopatterns, was successfully demonstrated, which can further be utilized to fabricate cell sheets with aligned cell morphology. The advantage of this system is that cells cultured on such thermoresponsive surfaces could be recovered as an intact cell sheet by simply lowering the temperature, eliminating the need for conventional enzymatic treatments. Copyright © 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Temperature-responsive peptide-mimetic coating based on poly(N-methacryloyl-l-leucine): properties, protein adsorption and cell growth.

PubMed

Raczkowska, Joanna; Ohar, Mariya; Stetsyshyn, Yurij; Zemła, Joanna; Awsiuk, Kamil; Rysz, Jakub; Fornal, Katarzyna; Bernasik, Andrzej; Ohar, Halyna; Fedorova, Svitlana; Shtapenko, Oksana; Polovkovych, Svyatoslav; Novikov, Volodymyr; Budkowski, Andrzej

2014-06-01

Poly(N-methacryloyl-l-leucine) (PNML) coatings were successfully fabricated via polymerization from peroxide initiator grafted to premodified glass substrate. Chemical composition and thickness of PNML coatings were determined using time of flight-secondary ion mass spectrometry (TOF- SIMS) and ellipsometry, respectively. PNML coatings exhibit thermal response of the wettability, between 4 and 28°C, which indicates a transition between hydrated loose coils and hydrophobic collapsed chains. Morphology of the PNML coating was observed with the AFM, transforming with increasing temperature from initially relatively smooth surface to rough and more structured surface. Protein adsorption observed by fluorescence microscopy for model proteins (bovine serum albumin and lentil lectin labeled with fluorescein isothiocyanate) at transition from 5 to 25°C, showed high affinity of PNML coating to proteins at all investigated temperatures and pH. Thus, PNML coating have significant potential for medical and biotechnological applications as protein capture agents or functional replacements of antibodies ("plastic antibodies"). The high proliferation growth of the human embryonic kidney cell (HEK 293) onto PNML coating was demonstrated, indicating its excellent cytocompatibility. Copyright © 2014 Elsevier B.V. All rights reserved.

Plasma Thruster Development: Magnetoplasmadynamic Propulsion, Status and Basic Problems.

DTIC Science & Technology

1986-02-01

34 9 Sublimation Rates vs. Temperature for Typical Electrode Materials 65 10 Time to Reach Melting vs. Surface Heat Load (One-Dimensional, Large Area...Approx.) for Different Electrode Materials and Initial Temperatures 75 V LIST OF TABLES TABLE PAGE I Models of Thruster Types (with approximation (1...much higher specific impulse values than the minimum must be achieved in order to obtain acceptable effi- Sciencies , e.g. for 30% efficiency with argon

Microstructural Features Controlling the Variability in Low-Cycle Fatigue Properties of Alloy Inconel 718DA at Intermediate Temperature

NASA Astrophysics Data System (ADS)

Texier, Damien; Gómez, Ana Casanova; Pierret, Stéphane; Franchet, Jean-Michel; Pollock, Tresa M.; Villechaise, Patrick; Cormier, Jonathan

2016-03-01

The low-cycle fatigue behavior of two direct-aged versions of the nickel-based superalloy Inconel 718 (IN718DA) was examined in the low-strain amplitude regime at intermediate temperature. High variability in fatigue life was observed, and abnormally short lifetimes were systematically observed to be due to crack initiation at (sub)-surface non-metallic inclusions. However, crack initiation within (sub)-surface non-metallic inclusions did not necessarily lead to short fatigue life. The macro- to micro-mechanical mechanisms of deformation and damage have been examined by means of detailed microstructural characterization, tensile and fatigue mechanical tests, and in situ tensile testing. The initial stages of crack micro-propagation from cracked non-metallic particles into the surrounding metallic matrix occupies a large fraction of the fatigue life and requires extensive local plastic straining in the matrix adjacent to the cracked inclusions. Differences in microstructure that influence local plastic straining, i.e., the δ-phase content and the grain size, coupled with the presence of non-metallic inclusions at the high end of the size distribution contribute strongly to the fatigue life variability.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Finegan, Donal P.; Tjaden, Bernhard; M. M. Heenan, Thomas

Mechanical abuse of lithium-ion batteries is widely used during testing to induce thermal runaway, characterize associated risks, and expose cell and module vulnerabilities. But, the repeatability of puncture or 'nail penetration' tests is a key issue as there is often a high degree of variability in the resulting thermal runaway process. Here, the failure mechanisms of 18650 cells punctured at different locations and orientations are characterized with respect to their internal structural degradation, and both their internal and surface temperature, all of which are monitored in real time. The initiation and propagation of thermal runaway is visualized via high-speed synchrotronmore » X-ray radiography at 2000 frames per second, and the surface and internal temperatures are recorded via infrared imaging and a thermocouple embedded in the tip of the penetrating nail, respectively. The influence of the nail, as well as how and where it penetrates the cell, on the initiation and propagation of thermal runaway is described and the suitability of this test method for representing in-field failures is discussed.« less

Phase diagram of Ag-Pd bimetallic nanoclusters by molecular dynamics simulations: solid-to-liquid transition and size-dependent behavior.

PubMed

Kim, Da Hye; Kim, Hyun You; Ryu, Ji Hoon; Lee, Hyuck Mo

2009-07-07

This report on the solid-to-liquid transition region of an Ag-Pd bimetallic nanocluster is based on a constant energy microcanonical ensemble molecular dynamics simulation combined with a collision method. By varying the size and composition of an Ag-Pd bimetallic cluster, we obtained a complete solid-solution type of binary phase diagram of the Ag-Pd system. Irrespective of the size and composition of the cluster, the melting temperature of Ag-Pd bimetallic clusters is lower than that of the bulk state and rises as the cluster size and the Pd composition increase. Additionally, the slope of the phase boundaries (even though not exactly linear) is lowered when the cluster size is reduced on account of the complex relations of the surface tension, the bulk melting temperature, and the heat of fusion. The melting of the cluster initially starts at the surface layer. The initiation and propagation of a five-fold icosahedron symmetry is related to the sequential melting of the cluster.

Statistical analysis and isotherm study of uranium biosorption by Padina sp. algae biomass.

PubMed

Khani, Mohammad Hassan

2011-06-01

The application of response surface methodology is presented for optimizing the removal of U ions from aqueous solutions using Padina sp., a brown marine algal biomass. Box-Wilson central composite design was employed to assess individual and interactive effects of the four main parameters (pH and initial uranium concentration in solutions, contact time and temperature) on uranium uptake. Response surface analysis showed that the data were adequately fitted to second-order polynomial model. Analysis of variance showed a high coefficient of determination value (R (2)=0.9746) and satisfactory second-order regression model was derived. The optimum pH and initial uranium concentration in solutions, contact time and temperature were found to be 4.07, 778.48 mg/l, 74.31 min, and 37.47°C, respectively. Maximized uranium uptake was predicted and experimentally validated. The equilibrium data for biosorption of U onto the Padina sp. were well represented by the Langmuir isotherm, giving maximum monolayer adsorption capacity as high as 376.73 mg/g.

Graphical Procedure for Comparing Thermal Death of Bacillus stearothermophilus Spores in Saturated and Superheated Steam

PubMed Central

Shull, James J.; Ernst, Robert R.

1962-01-01

The thermal death curve of dried spores of Bacillus stearothermophilus in saturated steam was characterized by three phases: (i) a sharp initial rise in viable count; (ii) a low rate of death which gradually increased; and (iii) logarithmic death at maximal rate. The first phase was a reflection of inadequate heat activation of the spore population. The second and third phases represented the characteristic thermal death curve of the spores in saturated steam. A jacketed steam sterilizer, equipped with a system for initial evacuation of the chamber, was examined for superheat during normal operation. Measurements of spore inactivation and temperature revealed superheat in surface layers of fabrics being processed in steam at 121 C. The high temperature of the fabric surfaces was attributed to absorption of excess heat energy from superheated steam. The superheated steam was produced at the beginning of the normal sterilizing cycle by transfer of heat from the steam-heated jacket to saturated steam entering the vessel. PMID:13988774

Optimization of the functional domain of flat plate collectors

NASA Astrophysics Data System (ADS)

Ritoux, G.; Irigaray, J.-L.

1981-12-01

The variations of the extracted heat flux as function of the temperature of the heat transfer fluid in black and selective surface solar collectors are examined. The heat flux is calculated based on the difference of the initial to the stage of thermal equilibrium of the fluid. A nonlinear system of equations is developed and solved by a fast, iterative method to obtain the equilibrium temperatures. It is found that more flux can be extracted from the solar heat by a collector with only one glass cover than with more than one cover. The captured flux is proportional to the coefficient of transmission of the glass coverings, to the coefficient of absorption of the collector, and to the incident flux. Black painted surfaces were more absorbent than selective surfaces, and highest collection efficiencies were displayed by low temperature collectors. Charts of effective uses of the respective types of collectors for heating swimming pools, hot water, home heat, and for refrigeration and air-conditioning are provided.

Size-Dependent Melting Behavior of Colloidal In, Sn, and Bi Nanocrystals

PubMed Central

Liu, Minglu; Wang, Robert Y.

2015-01-01

Colloidal nanocrystals are a technologically important class of nanostructures whose phase change properties have been largely unexplored. Here we report on the melting behavior of In, Sn, and Bi nanocrystals dispersed in a polymer matrix. This polymer matrix prevents the nanocrystals from coalescing with one another and enables previously unaccessed observations on the melting behavior of colloidal nanocrystals. We measure the melting temperature, melting enthalpy, and melting entropy of colloidal nanocrystals with diameters of approximately 10 to 20 nm. All of these properties decrease as nanocrystal size decreases, although the depression rate for melting temperature is comparatively slower than that of melting enthalpy and melting entropy. We also observe an elevated melting temperature during the initial melt-freeze cycle that we attribute to surface stabilization from the organic ligands on the nanocrystal surface. Broad endothermic melting valleys and very large supercoolings in our calorimetry data suggest that colloidal nanocrystals exhibit a significant amount of surface pre-melting and low heterogeneous nucleation probabilities during freezing. PMID:26573146

Fusion of vesicles with the air-water interface: the influence of polar head group, salt concentration, and vesicle size.

PubMed

Gugliotti, M; Chaimovich, H; Politi, M J

2000-02-15

Fusion of vesicles with the air-water interface and consequent monolayer formation has been studied as a function of temperature. Unilamellar vesicles of DMPC, DPPC, and DODAX (X=Cl(-), Br(-)) were injected into a subphase containing NaCl, and the surface pressure (tension) was recorded on a Langmuir Balance (Tensiometer) using the Wilhelmy plate (Ring) method. For the zwitterionic vesicles, plots of the initial surface pressure increase rate (surface tension decrease rate) as a function of temperature show a peak at the phase transition temperature (T(m)) of the vesicles, whereas for ionic ones they show a sharp rise. At high concentrations of NaCl, ionic DODA(Cl) vesicles seem to behave like zwitterionic ones, and the rate of fusion is higher at the T(m). The influence of size was studied comparing large DODA(Cl) vesicles with small sonicated ones, and no significant changes were found regarding the rate of fusion with the air-water interface.

Atomic Beam Scattering Methods to Study Overlayer Structures and H-Surface Interaction Relevant to Astrophysics

NASA Astrophysics Data System (ADS)

Lin, Jingsu

In this thesis we present results of experimental methods for studying surface structures of ultra-thin films and describe a new apparatus to study the recombination of atomic hydrogen on well characterized low temperature surface using atomic and molecular beam methods. We have used atomic beam scattering (ABS) to characterize the growth of mercury and lead overlayers on Cu(001) surface. The structures of ordered phases have been identified using ABS and low-energy electron diffraction (LEED). A model to analyze diffraction data from these phases is presented. The new apparatus we are going to describe includes a high performance atomic hydrogen source using radio-frequency (RF) dissociation. The dissociation efficiency can be as high as 90% in the optimized pressure range. An atomic hydrogen beam line has been added to our ultra-high vacuum (UHV) scattering apparatus. We have also designed and constructed a low temperature sample manipulator for experiments at liquid helium temperatures. The manipulator has one degree of freedom of rotation and the capability of heating the sample to 700K and cooling down to 12K. The first sample studied was a single graphite surface. We have used a He beam to characterize the sample surface and to monitor deposition of H on the sample surface in real time. A series of "adsorption curves" have been obtained at different temperature and doses. We found that at temperatures below 16K, both H and H_2 have formed a partial layer on the surface. From adsorption curve, we deduce that the initial sticking coefficient for H is about 0.06 when surface at 16K. When the H beam is interrupted, the He specularly reflected beam recovers partially, indicating that hydrogen atoms desorb, while others remain on the surface. The residual coverage of H is estimated to be about 2% of a monolayer.

Combined Homogeneous Surface Diffusion Model - Design of experiments approach to optimize dye adsorption considering both equilibrium and kinetic aspects.

PubMed

Muthukkumaran, A; Aravamudan, K

2017-12-15

Adsorption, a popular technique for removing azo dyes from aqueous streams, is influenced by several factors such as pH, initial dye concentration, temperature and adsorbent dosage. Any strategy that seeks to identify optimal conditions involving these factors, should take into account both kinetic and equilibrium aspects since they influence rate and extent of removal by adsorption. Hence rigorous kinetics and accurate equilibrium models are required. In this work, the experimental investigations pertaining to adsorption of acid orange 10 dye (AO10) on activated carbon were carried out using Central Composite Design (CCD) strategy. The significant factors that affected adsorption were identified to be solution temperature, solution pH, adsorbent dosage and initial solution concentration. Thermodynamic analysis showed the endothermic nature of the dye adsorption process. The kinetics of adsorption has been rigorously modeled using the Homogeneous Surface Diffusion Model (HSDM) after incorporating the non-linear Freundlich adsorption isotherm. Optimization was performed for kinetic parameters (color removal time and surface diffusion coefficient) as well as the equilibrium affected response viz. percentage removal. Finally, the optimum conditions predicted were experimentally validated. Copyright © 2017 Elsevier Ltd. All rights reserved.

Room temperature deposition of gold onto the diffuse and sharp diffraction spot Si(111)-( 3 × 3) R30° Au surfaces

NASA Astrophysics Data System (ADS)

Plass, Richard; Marks, Laurence D.

1996-06-01

Room temperature gold depositions onto Si(111)-( 3 × 3) R30° Au surfaces with diffuse and sharp diffraction spots [Surf. Sci. 242 (1991) 73] (diffuse and sharp 3 × 3 Au hereafter) under UHV conditions has been monitored using transmission electron diffraction (TED). Both systems display an increase in surface structure diffraction spot intensities up to the completion of 1.0 monolayer (ML) after which the surface beams display an exponential decrease in intensity with coverage. The exponential decay rate decreases after roughly 1.33 ML. These results can be attributed to gold initially diffusing to and filling 3 × 3 Au gold trimer sites in vacancy type surface domain walls [Surf. Sci. 342 (1995) 233], then filling one of three possible sites on the 3 × 3 Au structure with essentially no surface diffusion, disrupting nearby gold trimers. Gold deposition onto the diffuse type structure caused the formation and expansion of satellite arcs around the strongest 3 × 3 beams similar to those seen by others [Surf. Sci. 242 (1991) 73; Jpn. J. Appl. Phys. 16 (1977) 891; J. Vac. Sci. Technol. A 10 (1992) 3486] at elevated temperatures while the sharp structure displayed only a modest shoulder formation near the strongest 3 × 3 beams.

Toward Improved Land Surface Initialization in Support of Regional WRF Forecasts at the Kenya Meteorological Department

NASA Technical Reports Server (NTRS)

Case. Jonathan; Mungai, John; Sakwa, Vincent; Kabuchanga, Eric; Zavodsky, Bradley T.; Limaye, Ashutosh S.

2014-01-01

Flooding and drought are two key forecasting challenges for the Kenya Meteorological Department (KMD). Atmospheric processes leading to excessive precipitation and/or prolonged drought can be quite sensitive to the state of the land surface, which interacts with the boundary layer of the atmosphere providing a source of heat and moisture. The development and evolution of precipitation systems are affected by heat and moisture fluxes from the land surface within weakly-sheared environments, such as in the tropics and sub-tropics. These heat and moisture fluxes during the day can be strongly influenced by land cover, vegetation, and soil moisture content. Therefore, it is important to represent the land surface state as accurately as possible in numerical weather prediction models. Enhanced regional modeling capabilities have the potential to improve forecast guidance in support of daily operations and high-end events over east Africa. KMD currently runs a configuration of the Weather Research and Forecasting (WRF) model in real time to support its daily forecasting operations, invoking the Nonhydrostatic Mesoscale Model (NMM) dynamical core. They make use of the National Oceanic and Atmospheric Administration / National Weather Service Science and Training Resource Center's Environmental Modeling System (EMS) to manage and produce the WRF-NMM model runs on a 7-km regional grid over eastern Africa. Two organizations at the National Aeronautics and Space Administration Marshall Space Flight Center in Huntsville, AL, SERVIR and the Short-term Prediction Research and Transition (SPoRT) Center, have established a working partnership with KMD for enhancing its regional modeling capabilities. To accomplish this goal, SPoRT and SERVIR will provide experimental land surface initialization datasets and model verification capabilities to KMD. To produce a land-surface initialization more consistent with the resolution of the KMD-WRF runs, the NASA Land Information System (LIS) will be run at a comparable resolution to provide real-time, daily soil initialization data in place of interpolated Global Forecast System soil moisture and temperature data. Additionally, real-time green vegetation fraction data from the Visible Infrared Imaging Radiometer Suite will be incorporated into the KMD-WRF runs, once it becomes publicly available from the National Environmental Satellite Data and Information Service. Finally, model verification capabilities will be transitioned to KMD using the Model Evaluation Tools (MET) package, in order to quantify possible improvements in simulated temperature, moisture and precipitation resulting from the experimental land surface initialization. The transition of these MET tools will enable KMD to monitor model forecast accuracy in near real time. This presentation will highlight preliminary verification results of WRF runs over east Africa using the LIS land surface initialization.

Soil Moisture and Snow Cover: Active or Passive Elements of Climate?

NASA Technical Reports Server (NTRS)

Oglesby, Robert J.; Marshall, Susan; Erickson, David J., III; Robertson, Franklin R.; Roads, John O.; Arnold, James E. (Technical Monitor)

2002-01-01

A key question in the study of the hydrologic cycle is the extent to which surface effects such as soil moisture and snow cover are simply passive elements or whether they can affect the evolution of climate on seasonal and longer time scales. We have constructed ensembles of predictability studies using the NCAR CCM3 in which we compared the relative roles of initial surface and atmospheric conditions over the central and western U.S. in determining the subsequent evolution of soil moisture and of snow cover. We have also made sensitivity studies with exaggerated soil moisture and snow cover anomalies in order to determine the physical processes that may be important. Results from simulations with realistic soil moisture anomalies indicate that internal climate variability may be the strongest factor, with some indication that the initial atmospheric state is also important. The initial state of soil moisture does not appear important, a result that held whether simulations were started in late winter or late spring. Model runs with exaggerated soil moisture reductions (near-desert conditions) showed a much larger effect, with warmer surface temperatures, reduced precipitation, and lower surface pressures; the latter indicating a response of the atmospheric circulation. These results suggest the possibility of a threshold effect in soil moisture, whereby an anomaly must be of a sufficient size before it can have a significant impact on the atmospheric circulation and hence climate. Results from simulations with realistic snow cover anomalies indicate that the time of year can be crucial. When introduced in late winter, these anomalies strongly affected the subsequent evolution of snow cover. When introduced in early winter, however, little or no effect is seen on the subsequent snow cover. Runs with greatly exaggerated initial snow cover indicate that the high reflectively of snow is the most important process by which snow cover cart impact climate, through lower surface temperatures and increased surface pressures. In early winter, the amount of solar radiation is very small and so this albedo effect is inconsequential while in late winter, with the sun higher in the sky and period of daylight longer, the effect is much stronger.

Ultrasonic hydrometer

DOEpatents

Swoboda, Carl A.

1984-01-01

The disclosed ultrasonic hydrometer determines the specific gravity (density) of the electrolyte of a wet battery, such as a lead-acid battery. The hydrometer utilizes a transducer that when excited emits an ultrasonic impulse that traverses through the electrolyte back and forth between spaced sonic surfaces. The transducer detects the returning impulse, and means measures the time "t" between the initial and returning impulses. Considering the distance "d" between the spaced sonic surfaces and the measured time "t", the sonic velocity "V" is calculated with the equation "V=2d/t". The hydrometer also utilizes a thermocouple to measure the electrolyte temperature. A hydrometer database correlates three variable parameters including sonic velocity in and temperature and specific gravity of the electrolyte, for temperature values between 0.degree. and 40.degree. C. and for specific gravity values between 1.05 and 1.30. Upon knowing two parameters (the calculated sonic velocity and the measured temperature), the third parameter (specific gravity) can be uniquely found in the database. The hydrometer utilizes a microprocessor for data storage and manipulation. The disclosed modified battery has a hollow spacer nub on the battery side wall, the sonic surfaces being on the inside of the nub and the electrolyte filling between the surfaces to the exclusion of intervening structure. An accessible pad exposed on the nub wall opposite one sonic surface allows the reliable placement thereagainst of the transducer.

Thermal management of metallic surfaces: evaporation of sessile water droplets on polished and patterned stainless steel

NASA Astrophysics Data System (ADS)

Czerwiec, T.; Tsareva, S.; Andrieux, A.; Bortolini, G. A.; Bolzan, P. H.; Castanet, G.; Gradeck, M.; Marcos, G.

2017-10-01

This communication focus on the evaporation of sessile water droplets on different states of austenitic stainless steel surfaces: mirror polished, mirror polished and aged and patterned by sputtering. The evolution of the contact angle and of the droplet diameter is presented as a function of time at room temperature. For all the surface states, a constant diameter regime (CCR) is observed. An important aging effect on the contact angle is measured on polished surfaces due to atmospheric contamination. The experimental observations are compared to a quasi-static evaporation model assuming spherical caps. The evolution of the droplet volume as a function of time is almost linear with the evaporation time for all the observed surfaces. This is in accordance with the model prediction for the CCR mode for small initial contact angles. In our experiments, the evaporation time is found to be linearly dependent on the initial contact angle. This dependence is not correctly described by the evaporation model

Comprehensive Adsorption Studies of Doxycycline and Ciprofloxacin Antibiotics by Biochars Prepared at Different Temperatures

PubMed Central

Zeng, Zhi-wei; Tan, Xiao-fei; Liu, Yun-guo; Tian, Si-rong; Zeng, Guang-ming; Jiang, Lu-hua; Liu, Shao-bo; Li, Jiang; Liu, Ni; Yin, Zhi-hong

2018-01-01

This paper comparatively investigated the removal efficiency and mechanisms of rice straw biochars prepared under three pyrolytic temperatures for two kinds of tetracycline and quinolone antibiotics (doxycycline and ciprofloxacin). The influencing factors of antibiotic adsorption (including biochar dosage, pH, background electrolytes, humic acid, initial antibiotics concentration, contact time, and temperature) were comprehensively studied. The results suggest that biochars produced at high-temperature [i.e., 700°C (BC700)], have higher adsorption capacity for the two antibiotics than low-temperature (i.e., 300–500°C) biochars (BC300 and BC500). Higher surface area gives rise to greater volume of micropores and mesopores, and higher graphitic surfaces of the BC700 contributed to its higher functionality. The maximum adsorption capacity was found to be in the following order: DOX > CIP. The π-π EDA interaction and hydrogen bonding might be the predominant adsorption mechanisms. Findings in this study highlight the important roles of high-temperature biochars in controlling the contamination of tetracycline and quinolone antibiotics in the environment. PMID:29637067

Comprehensive adsorption studies of doxycycline and ciprofloxacin antibiotics by biochars prepared at different temperatures

NASA Astrophysics Data System (ADS)

Zeng, Zhi-wei; Tan, Xiao-fei; Liu, Yun-guo; Tian, Si-rong; Zeng, Guang-ming; Jiang, Lu-hua; Liu, Shao-bo; Li, Jiang; Liu, Ni; Yin, Zhi-hong

2018-03-01

This paper comparatively investigated the removal efficiency and mechanisms of rice straw biochars prepared under three pyrolytic temperatures for two kinds of tetracycline and quinolone antibiotics (doxycycline and ciprofloxacin). The influencing factors of antibiotic adsorption (including biochar dosage, pH, background electrolytes, humic acid, initial antibiotics concentration, contact time, and temperature) were comprehensively studied. The results suggest that biochars produced at high-temperature (i.e., 700°C (BC700)), have higher adsorption capacity for the two antibiotics than low-temperature (i.e., 300-500°C) biochars (BC300 and BC500). Higher surface area gives rise to greater volume of micropores and mesopores, and higher graphitic surfaces of the BC700 contributed to its higher functionality. The maximum adsorption capacity was found to be in the following order: DOX > CIP. The π-π EDA interaction and hydrogen bonding might be the predominant adsorption mechanisms. Findings in this study highlight the important roles of high-temperature biochars in controlling the contamination of tetracycline and quinolone antibiotics in the environment.

Two-phase working fluids for the temperature range of 50 to 350 deg, phase 2

NASA Technical Reports Server (NTRS)

Saaski, E. W.; Hartl, J. H.

1980-01-01

Several two phase heat transfer fluids were tested in aluminum and carbon steel reflux capsules for over 25,000 hours at temperatures up to 300 C. Several fluids showed very good stability and would be useful for long duration heat transfer applications over the range 100 to 350 C. Instrumentation for the measurement of surface tension and viscosity were constructed for use with heat transfer fluids over the temperature range 0 to 300 C and with pressures from 0 to 10 atmospheres. The surface tension measuring device constructed requires less than a 1.0 cc sample and displays an accuracy of about 5 percent in preliminary tests, while the viscometer constructed for this program requires a 0.05 cc sample and shows an accuracy of about 5 percent in initial tests.

Steel bonded dense silicon nitride compositions and method for their fabrication

DOEpatents

Landingham, R.L.; Shell, T.E.

1985-05-20

A two-stage bonding technique for bonding high density silicon nitride and other ceramic materials to stainless steel and other hard metals, and multilayered ceramic-metal composites prepared by the technique are disclosed. The technique involves initially slurry coating a surface of the ceramic material at about 1500/sup 0/C in a vacuum with a refractory material and the stainless steel is then pressure bonded to the metallic coated surface by brazing it with nickel-copper-silver or nickel-copper-manganese alloys at a temperature in the range of about 850/sup 0/ to 950/sup 0/C in a vacuum. The two-stage bonding technique minimizes the temperature-expansion mismatch between the dissimilar materials.

Steel bonded dense silicon nitride compositions and method for their fabrication

DOEpatents

Landingham, Richard L.; Shell, Thomas E.

1987-01-01

A two-stage bonding technique for bonding high density silicon nitride and other ceramic materials to stainless steel and other hard metals, and multilayered ceramic-metal composites prepared by the technique are disclosed. The technique involves initially slurry coating a surface of the ceramic material at about 1500.degree. C. in a vacuum with a refractory material and the stainless steel is then pressure bonded to the metallic coated surface by brazing it with nickel-copper-silver or nickel-copper-manganese alloys at a temperature in the range of about 850.degree. to 950.degree. C. in a vacuum. The two-stage bonding technique minimizes the temperature-expansion mismatch between the dissimilar materials.

Metal/silicon Interfaces and Their Oxidation Behavior - Photoemission Spectroscopy Analysis.

NASA Astrophysics Data System (ADS)

Yeh, Jyh-Jye

Synchrotron radiation photoemission spectroscopy was used to study Ni/Si and Au/Si interface properties on the atomic scale at room temperature, after high temperature annealing and after oxygen exposures. Room temperature studies of metal/Si interfaces provide background for an understanding of the interface structure after elevated temperature annealing. Oxidation studies of Si surfaces covered with metal overlayers yield insight about the effect of metal atoms in the Si oxidation mechanisms and are useful in the identification of subtle differences in bonding relations between atoms at the metal/Si interfaces. Core level and valence band spectra with variable surface sensitivities were used to study the interactions between metal, Si, and oxygen for metal coverages and oxide thickness in the monolayer region. Interface morphology at the initial stage of metal/Si interface formation and after oxidation was modeled on the basis of the evolutions of metal and Si signals at different probing depths in the photoemission experiment. Both Ni/Si and Au/Si interfaces formed at room temperature have a diffusive region at the interface. This is composed of a layer of metal-Si alloy, formed by Si outdiffusion into the metal overlayer, above a layer of interstitial metal atoms in the Si substrate. Different atomic structures of these two regions at Ni/Si interface can account for the two different growth orientations of epitaxial Ni disilicides on the Si(111) surface after thermal annealing. Annealing the Au/Si interface at high temperature depletes all the Au atoms except for one monolayer of Au on the Si(111) surface. These phenomena are attributed to differences in the metal-Si chemical bonding relations associated with specific atomic structures. After oxygen exposures, both the Ni disilicide surface and Au covered Si surfaces (with different coverages and surface orderings) show silicon in higher oxidation states, in comparison to oxidized silicon on a clean surface. Preferential Si dioxide growth on the Au/Si surface is related to the strong distortion of the Si lattice when Au-Si bonds are formed. In comparison, a monolayer of Ni on a Si surface, with its weaker Ni-Si bond, does not enhance oxide formation.

Hydrogen desorption from hydrogen fluoride and remote hydrogen plasma cleaned silicon carbide (0001) surfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

King, Sean W., E-mail: sean.king@intel.com; Tanaka, Satoru; Davis, Robert F.

2015-09-15

Due to the extreme chemical inertness of silicon carbide (SiC), in-situ thermal desorption is commonly utilized as a means to remove surface contamination prior to initiating critical semiconductor processing steps such as epitaxy, gate dielectric formation, and contact metallization. In-situ thermal desorption and silicon sublimation has also recently become a popular method for epitaxial growth of mono and few layer graphene. Accordingly, numerous thermal desorption experiments of various processed silicon carbide surfaces have been performed, but have ignored the presence of hydrogen, which is ubiquitous throughout semiconductor processing. In this regard, the authors have performed a combined temperature programmed desorptionmore » (TPD) and x-ray photoelectron spectroscopy (XPS) investigation of the desorption of molecular hydrogen (H{sub 2}) and various other oxygen, carbon, and fluorine related species from ex-situ aqueous hydrogen fluoride (HF) and in-situ remote hydrogen plasma cleaned 6H-SiC (0001) surfaces. Using XPS, the authors observed that temperatures on the order of 700–1000 °C are needed to fully desorb C-H, C-O and Si-O species from these surfaces. However, using TPD, the authors observed H{sub 2} desorption at both lower temperatures (200–550 °C) as well as higher temperatures (>700 °C). The low temperature H{sub 2} desorption was deconvoluted into multiple desorption states that, based on similarities to H{sub 2} desorption from Si (111), were attributed to silicon mono, di, and trihydride surface species as well as hydrogen trapped by subsurface defects, steps, or dopants. The higher temperature H{sub 2} desorption was similarly attributed to H{sub 2} evolved from surface O-H groups at ∼750 °C as well as the liberation of H{sub 2} during Si-O desorption at temperatures >800 °C. These results indicate that while ex-situ aqueous HF processed 6H-SiC (0001) surfaces annealed at <700 °C remain terminated by some surface C–O and Si–O bonding, they may still exhibit significant chemical reactivity due to the creation of surface dangling bonds resulting from H{sub 2} desorption from previously undetected silicon hydride and surface hydroxide species.« less

Thermal Ignition

NASA Astrophysics Data System (ADS)

Boettcher, Philipp Andreas

Accidental ignition of flammable gases is a critical safety concern in many industrial applications. Particularly in the aviation industry, the main areas of concern on an aircraft are the fuel tank and adjoining regions, where spilled fuel has a high likelihood of creating a flammable mixture. To this end, a fundamental understanding of the ignition phenomenon is necessary in order to develop more accurate test methods and standards as a means of designing safer air vehicles. The focus of this work is thermal ignition, particularly auto-ignition with emphasis on the effect of heating rate, hot surface ignition and flame propagation, and puffing flames. Combustion of hydrocarbon fuels is traditionally separated into slow reaction, cool flame, and ignition regimes based on pressure and temperature. Standard tests, such as the ASTM E659, are used to determine the lowest temperature required to ignite a specific fuel mixed with air at atmospheric pressure. It is expected that the initial pressure and the rate at which the mixture is heated also influences the limiting temperature and the type of combustion. This study investigates the effect of heating rate, between 4 and 15 K/min, and initial pressure, in the range of 25 to 100 kPa, on ignition of n-hexane air mixtures. Mixtures with equivalence ratio ranging from 0.6 to 1.2 were investigated. The problem is also modeled computationally using an extension of Semenov's classical auto-ignition theory with a detailed chemical mechanism. Experiments and simulations both show that in the same reactor either a slow reaction or an ignition event can take place depending on the heating rate. Analysis of the detailed chemistry demonstrates that a mixture which approaches the ignition region slowly undergoes a significant modification of its composition. This change in composition induces a progressive shift of the explosion limit until the mixture is no longer flammable. A mixture that approaches the ignition region sufficiently rapidly undergoes only a moderate amount of thermal decomposition and explodes quite violently. This behavior can also be captured and analyzed using a one-step reaction model, where the heat release is in competition with the depletion of reactants. Hot surface ignition is examined using a glow plug or heated nickel element in a series of premixed n-hexane air mixtures. High-speed schlieren photography, a thermocouple, and a fast response pressure transducer are used to record flame characteristics such as ignition temperature, flame speed, pressure rises, and combustion mode. The ignition event is captured by considering the dominant balance of diffusion and chemical reaction that occurs near a hot surface. Experiments and models show a dependence of ignition temperature on mixture composition, initial pressure, and hot surface size. The mixtures exhibit the known lower flammability limit where the maximum temperature of the hot surface was insufficient at igniting the mixture. Away from the lower flammability limit, the ignition temperature drops to an almost constant value over a wide range of equivalence ratios (0.7 to 2.8) with large variations as the upper flammability limit is approached. Variations in the initial pressure and equivalence ratio also give rise to different modes of combustion: single flame, re-ignition, and puffing flames. These results are successfully compared to computational results obtained using a flamelet model and a detailed chemical mechanism for n-heptane. These different regimes can be delineated by considering the competition between inertia, i.e., flame propagation, and buoyancy, which can be expressed in the Richardson number. In experiments of hot surface ignition and subsequent flame propagation a 10 Hz puffing flame instability is visible in mixtures that are stagnant and premixed prior to the ignition sequence. By varying the size of the hot surface, power input, and combustion vessel volume, we determined that the instability is a function of the interaction of the flame with the fluid flow induced by the combustion products rather than the initial plume established by the hot surface. The phenomenon is accurately reproduced in numerical simulations and a detailed flow field analysis revealed a competition between the inflow velocity at the base of the flame and the flame propagation speed. The increasing inflow velocity, which exceeds the flame propagation speed, is ultimately responsible for creating a puff. The puff is then accelerated upward, allowing for the creation of the subsequent instabilities. The frequency of the puffing is proportional to the gravitational acceleration and inversely proportional to the flame speed. We propose a relation describing the dependence of the frequency on gravitational acceleration, hot surface diameter, and flame speed. This relation shows good agreement for lean and rich n-hexane-air as well as lean hydrogen-air flames.

Fast surface crystallization of amorphous griseofulvin below T g.

PubMed

Zhu, Lei; Jona, Janan; Nagapudi, Karthik; Wu, Tian

2010-08-01

To study crystal growth rates of amorphous griseofulvin (GSF) below its glass transition temperature (T (g)) and the effect of surface crystallization on the overall crystallization kinetics of amorphous GSF. Amorphous GSF was generated by melt quenching. Surface and bulk crystal growth rates were determined using polarized light microscope. X-ray powder diffraction (XRPD) and Raman microscopy were used to identify the polymorph of the crystals. Crystallization kinetics of amorphous GSF powder stored at 40 degrees C (T (g)-48 degrees C) and room temperature (T (g)-66 degrees C) was monitored using XRPD. Crystal growth at the surface of amorphous GSF is 10- to 100-fold faster than that in the bulk. The surface crystal growth can be suppressed by an ultrathin gold coating. Below T (g), the crystallization of amorphous GSF powder was biphasic with a rapid initial crystallization stage dominated by the surface crystallization and a slow or suspended late stage controlled by the bulk crystallization. GSF exhibits the fastest surface crystallization kinetics among the known amorphous pharmaceutical solids. Well below T (g), surface crystallization dominated the overall crystallization kinetics of amorphous GSF powder. Thus, surface crystallization should be distinguished from bulk crystallization in studying, modeling and controlling the crystallization of amorphous solids.

The initiation of boiling during pressure transients. [water boiling on metal surfaces

NASA Technical Reports Server (NTRS)

Weisman, J.; Bussell, G.; Jashnani, I. L.; Hsieh, T.

1973-01-01

The initiation of boiling of water on metal surfaces during pressure transients has been investigated. The data were obtained by a new technique in which light beam fluctuations and a pressure signal were simultaneously recorded on a dual beam oscilloscope. The results obtained agreed with those obtained using high speed photography. It was found that, for water temperatures between 90-150 C, the wall superheat required to initiate boiling during a rapid pressure transient was significantly higher than required when the pressure was slowly reduced. This result is explained by assuming that a finite time is necessary for vapor to fill the cavity at which the bubble originates. Experimental measurements of this time are in reasonably good agreement with calculations based on the proposed theory. The theory includes a new procedure for estimating the coefficient of vaporization.

Late-Time Mixing Sensitivity to Initial Broadband Surface Roughness in High-Energy-Density Shear Layers

DOE PAGES

Flippo, K. A.; Doss, F. W.; Kline, J. L.; ...

2016-11-23

While using a large volume high-energy-density fluid shear experiment ( 8.5 cm 3 ) at the National Ignition Facility, we have demonstrated for the first time the ability to significantly alter the evolution of a supersonic sheared mixing layer by controlling the initial conditions of that layer. Furthermore, by altering the initial surface roughness of the tracer foil, we demonstrate the ability to transition the shear mixing layer from a highly ordered system of coherent structures to a randomly ordered system with a faster growing mix layer, indicative of strong mixing in the layer at a temperature of severalmore » tens of electron volts and at near solid density. Moreover, simulations using a turbulent-mix model show good agreement with the experimental results and poor agreement without turbulent mix.« less

Temperature-dependent residual shear strength characteristics of smectite-rich landslide soils

NASA Astrophysics Data System (ADS)

Shibasaki, Tatsuya; Matsuura, Sumio; Okamoto, Takashi

2015-04-01

On gentle clayey slopes in weathered argillaceous rock areas, there exist many landslides which repeatedly reactivate with slow movement. The slip surface soils of these landslides are sometimes composed dominantly of swelling clay mineral (smectite) which is well known to show extremely low residual friction angle. From field data monitored at landslide sites in Japan, it has become clear that some landslides with relatively shallow slip surface begin to move and become active in late autumn or early winter every year. In such cases, the triggering mechanisms of landslides have not been understood well enough, because landslide initiation and movement are not always clearly linked with rises in pore water pressures (ground water levels). In this study, we focus on the influence of seasonal variation in ground temperature on slope stability and have investigated the effect of temperature on the shear strength of slip surface soils. Undisturbed soil samples were collected by boring from the Busuno landslide in Japan. We performed box shear experiments on undisturbed slip surface soils at low temperature ranges (approximately 5-25 °C). XRD analysis revealed that these soils contain high fraction of smectite. Slickensided slip surface within test specimen was coincided with the shearing plane of the shear box and shear displacement was applied precisely along the localized slip surface. Experiments were performed under slow shearing rate condition (0.005mm/min) and the results showed that shear strength decreased with decreasing temperature. Temperature effect was rather significant on frictional angle than on cohesion. Ring shear experiments were also performed on normally-consolidated remoulded samples. Under residual strength condition, temperature-change experiments (cooling-event tests) ranging approximately from 5 to 25 °C were performed on smectite-rich landslide soils and commercial bentonites. As well as the results by box shear test, shear weakening behaviors were also recognized during cooling-event tests. Shear stress fluctuations, which were obtained by 1 Hz data sampling, showed that shear behavior characteristically changed in response to temperature conditions. Stick-slip behavior prevailed under room temperature conditions, whereas shear behavior gradually changed into stable sliding behavior as temperature decreased. SEM (Scanning Electric Microscope) observation on shear surfaces indicated that silt- and sand-size asperities in the vicinity of the shear surface influence the occurrence of stick-slip behavior. It is also characteristically noted that rod-shaped smectitic clays, here called "roll", developed on shear surfaces and are arrayed densely perpendicular to the shearing direction in a micrometer scale. We assume that these rolls are probably rotating slowly within shear zone and acting as a lubricant which affects the temperature-dependent frictional properties of the shearing plane. These experimental results show that residual strength characteristics of smectite-rich soils are sensitive to temperature conditions. Our findings imply that if slip surface soils contain a high fraction of smectite, a decrease in ground temperature can lead to lowered shear resistance of the slip surface and triggering of slow landslide movement.

Comparing Geophysical Methods for Determining the Thickness of Arctic Sea Ice: Is There a Correlation Between Thickness and Surface Temperature?

NASA Astrophysics Data System (ADS)

Robertson, R.; Bowman, T.; Eagle, J. L.; Fisher, L.; Mankowski, K.; McGrady, N.; Schrecongost, N.; Voll, H.; Zulfiqar, A.; Herman, R. B.

2016-12-01

Several small geophysical surveys were conducted on the Chukchi Sea ice just offshore from the Naval Arctic Research Laboratory near Barrow, Alaska, in March, 2016. The goal was to investigate a possible correlation between the surface temperature and the thickness of the sea ice, as well as to test a potential new method for more accurately determining ice thickness. Surveys were conducted using a capacitively coupled resistivity array, a custom built thermal sensor array sled, ground penetrating radar (GPR), and an ice drill. The thermal sensor array was based on an Arduino microcontroller. It used an infrared (IR) sensor to determine surface temperature, and thermistor-based sensors to determine vertical air temperatures at 6 evenly spaced heights up to a maximum of 1.5 meters. Surface temperature (IR) data show possible correlations with ice drill, resistivity, and GPR data. The vertical air sensors showed almost no variation for any survey line which we postulate is due to the constant wind during each survey. Ice drill data show ice thickness along one 200 meter line varied from 79-95 cm, with an average of 87 cm. The thickness appears to be inversely correlated to surface temperatures. Resistivity and IR data both showed abrupt changes when crossing from the shore to the sea ice along a 400 meter line. GPR and IR data showed similar changes along a separate 900 meter line, suggesting that surface temperature and subsurface composition are related. Resistivity data were obtained in two locations by using the array in an expanding dipole-dipole configuration with 2.5 meter dipoles. The depth to the ice/water boundary was calculated using a "cumulative resistivity" plot and matched the depths obtained via the ice drill to within 2%. This has initiated work to develop a microcontroller-based resistivity array specialized for thickness measurements of thin ice.

Photon-induced selenium migration in TiSe 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lioi, David B.; Gosztola, David J.; Wiederrecht, Gary P.

2017-02-20

TiSe 2 is a member of the transition metal dichalcogenide family of layered van der Waals materials which exhibits some distinct electronic and optical properties. Here, we perform Raman spectroscopy and microscopy studies on single crystal TiSe 2 to investigate thermal and photon-induced defects associated with diffusion of selenium to the surface. Additional phonon peaks near 250 cm -1 are observed in the laser- irradiated regions that are consistent with formation of amorphous and nanocrys- talline selenium on the surface. Temperature dependent studies of the threshold temperature and laser intensity necessary to initiate selenium migration to the surface show anmore » activation barrier for the process of 1.55 eV. The impact of these results on the properties of strongly correlated electron states in TiSe 2 are discussed« less

A rolling-sliding bench test for investigating rear axle lubrication

DOE PAGES

Stump, Benjamin C.; Zhou, Yan; Viola, Michael B.; ...

2018-02-07

An automotive rear axle is composed of a set of hypoid gears, whose contact surfaces experience a complex combination of rolling contact fatigue damage and sliding wear. Full-scale rear axle dynamometer tests are used in the industry for efficiency and durability assessment. Here, this study developed a bench-scale rolling-sliding test protocol by simulating the contact pressure, oil temperature, and lubrication regime experienced in a dynamometer duty cycle test. Initial bench results have demonstrated the ability of generating both rolling contact-induced micropitting and sliding wear and the feasibility of investigating the impact of slide-to-roll ratio, surface roughness, test duration, and oilmore » temperature on the friction behavior, vibration noise, and surface damage. Finally, this bench test will allow studying candidate rear axle lubricants and materials under relevant conditions.« less

A rolling-sliding bench test for investigating rear axle lubrication

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stump, Benjamin C.; Zhou, Yan; Viola, Michael B.

An automotive rear axle is composed of a set of hypoid gears, whose contact surfaces experience a complex combination of rolling contact fatigue damage and sliding wear. Full-scale rear axle dynamometer tests are used in the industry for efficiency and durability assessment. Here, this study developed a bench-scale rolling-sliding test protocol by simulating the contact pressure, oil temperature, and lubrication regime experienced in a dynamometer duty cycle test. Initial bench results have demonstrated the ability of generating both rolling contact-induced micropitting and sliding wear and the feasibility of investigating the impact of slide-to-roll ratio, surface roughness, test duration, and oilmore » temperature on the friction behavior, vibration noise, and surface damage. Finally, this bench test will allow studying candidate rear axle lubricants and materials under relevant conditions.« less

Characteristics code for shock initiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Partom, Y.

1986-10-01

We developed SHIN, a characteristics code for shock initiation studies. We describe in detail the equations of state, reaction model, rate equations, and numerical difference equations that SHIN incorporates. SHIN uses the previously developed surface burning reaction model which better represents the shock initiation process in TATB, than do bulk reaction models. A large number of computed simulations prove the code is a reliable and efficient tool for shock initiation studies. A parametric study shows the effect on build-up and run distance to detonation of (1) type of boundary condtion, (2) burning velocity curve, (3) shock duration, (4) rise timemore » in ramp loading, (5) initial density (or porosity) of the explosive, (6) initial temperature, and (7) grain size. 29 refs., 65 figs.« less

An Active Englacial Hydrological System in a Cold Glacier: Blood Falls, Taylor Glacier, Antarctica

NASA Astrophysics Data System (ADS)

Carr, C. G.; Pettit, E. C.; Carmichael, J.; Badgeley, J.; Tulaczyk, S. M.; Lyons, W. B.; Mikucki, J.

2016-12-01

Blood Falls is a supraglacial hydrological feature formed by episodic release of iron-rich subglacial brine derived from an extensive aquifer beneath the cold, polar, Taylor Glacier. While fluid transport in non-temperate ice typically occurs through meltwater delivery from the glacier surface to the bed (hydrofracturing, supraglacial lake drainage), Blood Falls represents the opposite situation: brine moves from a subglacial source to the glacier surface. Here, we present the first complete conceptual model for brine transport and release, as well as the first direct evidence of a wintertime brine release at Blood Falls obtained through year-round time-lapse photography. Related analyses show that brine pools subglacially underneath the northern terminus of Taylor Glacier, rather than flowing directly into proglacial Lake Bonney because ice-cored moraines and channelized surface topography provide hydraulic barriers. This pooled brine is pressurized by hydraulic head from the upglacier brine source region. Based on seismic data, we propose that episodic supraglacial release is initiated by high strain rates coupled with pressurized subglacial brine that drive intermittent subglacial and englacial fracturing. Ultimately, brine-filled basal crevasses propagate upward to link with surface crevasses, allowing brine to flow from the bed to the surface. The observation of wintertime brine release indicates that surface-generated meltwater is not necessary to trigger crack propagation or to maintain the conduit as previously suggested. The liquid brine persists beneath and within the cold ice (-17°C) despite ambient ice/brine temperature differences of as high as 10°C through both locally depressed brine freezing temperatures through cryoconcentration of salts and increased ice temperatures through release of latent heat during partial freezing of brine. The existence of an englacial hydrological system initiated by basal crevassing extends to polar glaciers a process thought limited to temperate glaciers and confirms that supraglacial, englacial, and subglacial hydrological systems act in concert to provide critical forcing on glacier dynamics, even in cold polar ice.

Soil Moisture and Snow Cover: Active or Passive Elements of Climate

NASA Technical Reports Server (NTRS)

Oglesby, Robert J.; Marshall, Susan; Erickson, David J., III; Robertson, Franklin R.; Roads, John O.; Arnold, James E. (Technical Monitor)

2002-01-01

A key question is the extent to which surface effects such as soil moisture and snow cover are simply passive elements or whether they can affect the evolution of climate on seasonal and longer time scales. We have constructed ensembles of predictability studies using the NCAR CCM3 in which we compared the relative roles of initial surface and atmospheric conditions over the central and western U.S. in determining the subsequent evolution of soil moisture and of snow cover. Results from simulations with realistic soil moisture anomalies indicate that internal climate variability may be the strongest factor, with some indication that the initial atmospheric state is also important. Model runs with exaggerated soil moisture reductions (near-desert conditions) showed a much larger effect, with warmer surface temperatures, reduced precipitation, and lower surface pressures; the latter indicating a response of the atmospheric circulation. These results suggest the possibility of a threshold effect in soil moisture, whereby an anomaly must be of a sufficient size before it can have a significant impact on the atmospheric circulation and climate. Results from simulations with realistic snow cover anomalies indicate that the time of year can be crucial. When introduced in late winter, these anomalies strongly affected the subsequent evolution of snow cover. When introduced in early winter, however, little or no effect is seen on the subsequent snow cover. Runs with greatly exaggerated initial snow cover indicate that the high reflectivity of snow is the most important process by which snow cover can impact climate, through lower surface temperatures and increased surface pressures. The results to date were obtained for model runs with present-day conditions. We are currently analyzing runs made with projected forcings for the 21st century to see if these results are modified in any way under likely scenarios of future climate change. An intriguing new statistical technique involving 'clustering' is developed to assist in this analysis.

Influence of Substrate Temperature on the Transformation Front Velocities That Determine Thermal Stability of Vapor-Deposited Glasses

DOE PAGES

Dalal, Shakeel S.; Ediger, M. D.

2015-02-09

Stable organic glasses prepared by physical vapor deposition transform into the supercooled liquid via propagating fronts of molecular mobility, a mechanism different from that exhibited by glasses prepared by cooling the liquid. In this paper, we show that spectroscopic ellipsometry can directly observe this front-based mechanism in real time and explore how the velocity of the front depends upon the substrate temperature during deposition. For the model glass former indomethacin, we detect surface-initiated mobility fronts in glasses formed at substrate temperatures between 0.68T g and 0.94T g. At each of two annealing temperatures, the substrate temperature during deposition can changemore » the transformation front velocity by a factor of 6, and these changes are imperfectly correlated with the density of the glass. We also observe substrate-initiated fronts at some substrate temperatures. By connecting with theoretical work, we are able to infer the relative mobilities of stable glasses prepared at different substrate temperatures. Finally, an understanding of the transformation behavior of vapor-deposited glasses may be relevant for extending the lifetime of organic semiconducting devices.« less

Measuring the rebound resilience of a bouncing ball

NASA Astrophysics Data System (ADS)

Wadhwa, Ajay

2012-09-01

Some balls which are made of high-quality rubber (an elastomeric) material, such as tennis or squash balls, could be used for the determination of an important property of such materials called resilience. Since a bouncing ball involves a single impact we call this property 'rebound resilience' and express it as the ratio of the rebound height to the initial drop height of the ball. We determine the rebound resilience for three different types of ball by calculating the coefficient of restitution of the ball-surface combination from the experimentally measurable physical quantities, such as initial drop height and time interval between successive bounces. Using these we also determine the contact time of balls with the surface of impact. For measurements we have used audio, motion and surface-temperature sensors that were interfaced through a USB port with a computer.

Bioleaching of arsenic from highly contaminated mine tailings using Acidithiobacillus thiooxidans.

PubMed

Lee, Eunseong; Han, Yosep; Park, Jeonghyun; Hong, Jeongsik; Silva, Rene A; Kim, Seungkon; Kim, Hyunjung

2015-01-01

The behavior of arsenic (As) bioleaching from mine tailings containing high amount of As (ca. 34,000 mg/kg) was investigated using Acidithiobacillus thiooxidans to get an insight on the optimal conditions that would be applied to practical heap and/or tank bioleaching tests. Initial pH (1.8-2.2), temperature (25-40 °C), and solid concentration (0.5-4.0%) were employed as experimental parameters. Complementary characterization experiments (e.g., XRD, SEM-EDS, electrophoretic mobility, cell density, and sulfate production) were also carried out to better understand the mechanism of As bioleaching. The results showed that final As leaching efficiency was similar regardless of initial pH. However, greater initial As leaching rate was observed at initial pH 1.8 than other conditions, which could be attributed to greater initial cell attachment to mine tailings. Unlike the trend observed when varying the initial pH, the final As leaching efficiency varied with the changes in temperature and solid concentration. Specifically, As leaching efficiency tended to decrease with increasing temperature due to the decrease in the bacterial growth rate at higher temperature. Meanwhile, As leaching efficiency tended to increase with decreasing solid concentration. The results for jarosite contents in mine tailings residue after bioleaching revealed that much greater amount of the jarosite was formed during the bioleaching reaction at higher solid concentration, suggesting that the coverage of the surface of the mine tailings by jarosite and/or the co-precipitation of the leached As with jarosite could be a dominant factor reducing As leaching efficiency. Copyright © 2014 Elsevier Ltd. All rights reserved.

Transitioning Enhanced Land Surface Initialization and Model Verification Capabilities to the Kenya Meteorological Department (KMD)

NASA Technical Reports Server (NTRS)

Case, Jonathan L.; Mungai, John; Sakwa, Vincent; Zavodsky, Bradley T.; Srikishen, Jayanthi; Limaye, Ashutosh; Blankenship, Clay B.

2016-01-01

Flooding, severe weather, and drought are key forecasting challenges for the Kenya Meteorological Department (KMD), based in Nairobi, Kenya. Atmospheric processes leading to convection, excessive precipitation and/or prolonged drought can be strongly influenced by land cover, vegetation, and soil moisture content, especially during anomalous conditions and dry/wet seasonal transitions. It is thus important to represent accurately land surface state variables (green vegetation fraction, soil moisture, and soil temperature) in Numerical Weather Prediction (NWP) models. The NASA SERVIR and the Short-term Prediction Research and Transition (SPoRT) programs in Huntsville, AL have established a working partnership with KMD to enhance its regional modeling capabilities. SPoRT and SERVIR are providing experimental land surface initialization datasets and model verification capabilities for capacity building at KMD. To support its forecasting operations, KMD is running experimental configurations of the Weather Research and Forecasting (WRF; Skamarock et al. 2008) model on a 12-km/4-km nested regional domain over eastern Africa, incorporating the land surface datasets provided by NASA SPoRT and SERVIR. SPoRT, SERVIR, and KMD participated in two training sessions in March 2014 and June 2015 to foster the collaboration and use of unique land surface datasets and model verification capabilities. Enhanced regional modeling capabilities have the potential to improve guidance in support of daily operations and high-impact weather and climate outlooks over Eastern Africa. For enhanced land-surface initialization, the NASA Land Information System (LIS) is run over Eastern Africa at 3-km resolution, providing real-time land surface initialization data in place of interpolated global model soil moisture and temperature data available at coarser resolutions. Additionally, real-time green vegetation fraction (GVF) composites from the Suomi-NPP VIIRS instrument is being incorporated into the KMD-WRF runs, using the product generated by NOAA/NESDIS. Model verification capabilities are also being transitioned to KMD using NCAR's Model *Corresponding author address: Jonathan Case, ENSCO, Inc., 320 Sparkman Dr., Room 3008, Huntsville, AL, 35805. Email: Jonathan.Case-1@nasa.gov Evaluation Tools (MET; Brown et al. 2009) software in conjunction with a SPoRT-developed scripting package, in order to quantify and compare errors in simulated temperature, moisture and precipitation in the experimental WRF model simulations. This extended abstract and accompanying presentation summarizes the efforts and training done to date to support this unique regional modeling initiative at KMD. To honor the memory of Dr. Peter J. Lamb and his extensive efforts in bolstering weather and climate science and capacity-building in Africa, we offer this contribution to the special Peter J. Lamb symposium. The remainder of this extended abstract is organized as follows. The collaborating international organizations involved in the project are presented in Section 2. Background information on the unique land surface input datasets is presented in Section 3. The hands-on training sessions from March 2014 and June 2015 are described in Section 4. Sample experimental WRF output and verification from the June 2015 training are given in Section 5. A summary is given in Section 6, followed by Acknowledgements and References.

Numerical Simulations and Observations of Surface Wave Fields Under an Extreme Tropical Cyclone

DTIC Science & Technology

2009-09-01

the initial condition is first generated using the Gener- alized Digital Environmental Model ( GDEM ) monthly ocean temperature and salinity climatology...soscale eddies in the Gulf of Mexico, but no real-time data assimilation is done in the Caribbean Sea. Instead, the GDEM monthly climatology data are used... GDEM monthly climatology to initialize the 3D tem- perature and current fields in our ocean model. Since the climatology data smooth out most of the

The role of the sea-surface temperature distribution on numerically simulated cyclogenesis during ERICA

NASA Technical Reports Server (NTRS)

Lapenta, William M.; Perkey, Donald J.; Kreitzberg, Carl W.; Robertson, Franklin R.

1991-01-01

The goal was to quantify the extent to which a sea surface temperature (SST) front can influence cyclogenesis. The approach was to use the Drexel Limited-Area Mesoscale Prediction System (LAMPS) dynamical model to simulate cyclogenesis over various SST fields. Research during the past year focused on the development and testing of a four dimensional data assimilation (FDDA) technique within LAMPS. The technique is a continuous dynamical assimilation where forcing terms are added to the governing model equations to gradually nudge the model solution toward a gridded analysis. Here, the nudging is used as a dynamic initialization tool during a 12 hour preforecast to generate model balanced initial conditions for a subsequent 24 hour numerical prediction. Tests were performed to determine which variables to nudge and how to specify the four dimensional weighting function used to scale the nudging terms. To date, optimal results were obtained by nudging the u and v components of the wind along with the potential temperature. The weighting function ranged from 0 to 1 and varies in time as a quadratic polynomial. It was initialized at 0, reached its maximum at 9 hours into the preforecast, and fell back at 0 to 12 hours. The nudging terms are included in the model equations for all grid points except those within the model predicted oceanic boundary layer. This design attempts to confine changes imposed by the specified SST field to the oceanic boundary layer during the preforecast period.

Improved atmosphere-ocean coupled modeling in the tropics for climate prediction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Minghua

2015-01-01

We investigated the initial development of the double ITCZ in the Community Climate System Model (CCSM Version 3) in the central Pacific. Starting from a resting initial condition of the ocean in January, the model developed a warm bias of sea-surface temperature (SST) in the central Pacific from 5oS to 10oS in the first three months. We found this initial bias to be caused by excessive surface shortwave radiation that is also present in the standalone atmospheric model. The initial bias is further amplified by biases in both surface latent heat flux and horizontal heat transport in the upper ocean.more » These biases are caused by the responses of surface winds to SST bias and the thermocline structure to surface wind curls. We also showed that the warming biases in surface solar radiation and latent heat fluxes are seasonally offset by cooling biases from reduced solar radiation after the austral summer due to cloud responses and in the austral fall due to enhanced evaporation when the maximum SST is closest to the equator. The warming biases from the dynamic heat transport by ocean currents however stay throughout all seasons once they are developed, which are eventually balanced by enhanced energy exchange and penetration of solar radiation below the mixed layer. Our results also showed that the equatorial cold tongue develops after the warm biases in the south central Pacific, and the overestimation of surface shortwave radiation recurs in the austral summer in each year.« less

Depth-Penetrating Temperature Measurements of Thermal Barrier Coatings Incorporating Thermographic Phosphors

NASA Technical Reports Server (NTRS)

Eldridge, Jeffrey I.; Bencic, Timothy J..; Allison, Stephen W.; Beshears, David L.

2003-01-01

Thermographic phosphors have been previously demonstrated to provide effective non-contact, emissivity-independent surface temperature measurements. Because of the translucent nature of thermal barrier coatings (TBCs), thermographic phosphor-based temperature measurements can be extended beyond the surface to provide depth-selective temperature measurements by incorporating the thermographic phosphor layer at the depth where the temperature measurement is desired. In this paper, thermographic phosphor (Y2O3:Eu) fluorescence decay time measurements are demonstrated to provide through-the-coating thickness temperature readings up to 1100 C with the phosphor layer residing beneath a 100 micron thick TBC (plasma-sprayed 8wt% yttria-stabilized zirconia). With an appropriately chosen excitation wavelength and detection configuration, it is shown that sufficient phosphor emission is generated to provide effective temperature measurements, despite the attenuation of both the excitation and emission intensities by the overlying TBC. This depth-penetrating temperature measurement capability should prove particularly useful for TBC diagnostics where a large thermal gradient is typically present across the TBC thickness. The fluorescence decay from the Y2O3:Eu layer exhibited both an initial short-term exponential rise and a longer-term exponential decay. The rise time constant was demonstrated to provide better temperature indication below 500 C while the decay time constant was a better indicator at higher temperatures.

The Contribution of Soil Moisture Information to Forecast Skill: Two Studies

NASA Technical Reports Server (NTRS)

Koster, Randal

2010-01-01

This talk briefly describes two recent studies on the impact of soil moisture information on hydrological and meteorological prediction. While the studies utilize soil moisture derived from the integration of large-scale land surface models with observations-based meteorological data, the results directly illustrate the potential usefulness of satellite-derived soil moisture information (e.g., from SMOS and SMAP) for applications in prediction. The first study, the GEWEX- and ClIVAR-sponsored GLACE-2 project, quantifies the contribution of realistic soil moisture initialization to skill in subseasonal forecasts of precipitation and air temperature (out to two months). The multi-model study shows that soil moisture information does indeed contribute skill to the forecasts, particularly for air temperature, and particularly when the initial local soil moisture anomaly is large. Furthermore, the skill contributions tend to be larger where the soil moisture initialization is more accurate, as measured by the density of the observational network contributing to the initialization. The second study focuses on streamflow prediction. The relative contributions of snow and soil moisture initialization to skill in streamflow prediction at seasonal lead, in the absence of knowledge of meteorological anomalies during the forecast period, were quantified with several land surface models using uniquely designed numerical experiments and naturalized streamflow data covering mUltiple decades over the western United States. In several basins, accurate soil moisture initialization is found to contribute significant levels of predictive skill. Depending on the date of forecast issue, the contributions can be significant out to leads of six months. Both studies suggest that improvements in soil moisture initialization would lead to increases in predictive skill. The relevance of SMOS and SMAP satellite-based soil moisture information to prediction are discussed in the context of these studies.

The oxidation of aluminum at high temperature studied by Thermogravimetric Analysis and Differential Scanning Calorimetry.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Coker, Eric Nicholas

2013-10-01

The oxidation in air of high-purity Al foil was studied as a function of temperature using Thermogravimetric Analysis with Differential Scanning Calorimetry (TGA/DSC). The rate and/or extent of oxidation was found to be a non-linear function of the temperature. Between 650 and 750 ÀC very little oxidation took place; at 850 ÀC oxidation occurred after an induction period, while at 950 ÀC oxidation occurred without an induction period. At oxidation temperatures between 1050 and 1150 ÀC rapid passivation of the surface of the aluminum foil occurred, while at 1250 ÀC and above, an initial rapid mass increase was observed, followedmore » by a more gradual increase in mass. The initial rapid increase was accompanied by a significant exotherm. Cross-sections of oxidized specimens were characterized by scanning electron microscopy (SEM); the observed alumina skin thicknesses correlated qualitatively with the observed mass increases.« less

Melting in Superheated Silicon Films Under Pulsed-Laser Irradiation

NASA Astrophysics Data System (ADS)

Wang, Jin Jimmy

This thesis examines melting in superheated silicon films in contact with SiO2 under pulsed laser irradiation. An excimer-laser pulse was employed to induce heating of the film by irradiating the film through the transparent fused-quartz substrate such that most of the beam energy was deposited near the bottom Si-SiO2 interface. Melting dynamics were probed via in situ transient reflectance measurements. The temperature profile was estimated computationally by incorporating temperature- and phase-dependent physical parameters and the time-dependent intensity profile of the incident excimer-laser beam obtained from the experiments. The results indicate that a significant degree of superheating occurred in the subsurface region of the film. Surface-initiated melting was observed in spite of the internal heating scheme, which resulted in the film being substantially hotter at and near the bottom Si-SiO2 interface. By considering that the surface melts at the equilibrium melting point, the solid-phase-only heat-flow analysis estimates that the bottom Si-SiO2 interface can be superheated by at least 220 K during excimer-laser irradiation. It was found that at higher laser fluences (i.e., at higher temperatures), melting can be triggered internally. At heating rates of 1010 K/s, melting was observed to initiate at or near the (100)-oriented Si-SiO2 interface at temperatures estimated to be over 300 K above the equilibrium melting point. Based on theoretical considerations, it was deduced that melting in the superheated solid initiated via a nucleation and growth process. Nucleation rates were estimated from the experimental data using Johnson-Mehl-Avrami-Kolmogorov (JMAK) analysis. Interpretation of the results using classical nucleation theory suggests that nucleation of the liquid phase occurred via the heterogeneous mechanism along the Si-SiO2 interface.

Preparation and Antioxidant Activity of Purple Potato Wine

PubMed Central

Zhong-hua, Liu; Jie, Guo

2015-01-01

Purple potatoes were used as raw material to study the purple potato wine production process and antioxidant activity. This paper analyzed different fermentation time, fermentation temperature, yeast inoculum, initial pH, the initial sugar content on alcohol and anthocyanin contents of purple potato wine by single factor experiments and response surface methodology(RSM). The results showed that the optimum fermentation conditions of purple potato wine were as follows: fermentation temperature was 26oC, yeast inoculum was 0.15%, fermentation time was 7 d, initial pH was 3.0 and initial sugar content was 11 %. Under these conditions the alcohol and anthocyanin contents of purple potato wine could reach 10.55%/Vol and 6.42 μg/mL, respectively. The purple potato wine was purple, bright in colour, pleasant fragrance and pure taste. Prepared purple potato wine had the ability of reducing Fe3+ and scavenging superoxide anion radicals, which meant that purple potato wine had certain antioxidant activity. PMID:26998173

Study of variability of permittivity and its mapping over lunar surface and subsurface using multisensors datasets

NASA Astrophysics Data System (ADS)

Calla, O. P. N.; Mathur, Shubhra; Gadri, Kishan Lal; Jangid, Monika

2016-12-01

In the present paper, permittivity maps of equatorial lunar surface are generated using brightness temperature (TB) data obtained from Microwave Radiometer (MRM) of Chang'e-1 and physical temperature (TP) data obtained from Diviner of Lunar Reconnaissance Orbiter (LRO). Here, permittivity mapping is not carried out above 60° latitudes towards the lunar poles due to large anomaly in the physical temperature obtained from the Diviner. Microwave frequencies, which are used to generate these maps are 3 GHz, 7.8 GHz, 19.35 GHz and 37 GHz. Permittivity values are simulated using TB values at these four frequencies. Here, weighted average of physical temperature obtained from Diviner are used to compute permittivity at each microwave frequencies. Longer wavelengths of microwave signals give information of more deeper layers of the lunar surface as compared to smaller wavelength. Initially, microwave emissivity is estimated using TB values from MRM and physical temperature (TP) from Diviner. From estimated emissivity the real part of permittivity (ε), is calculated using Fresnel equations. The permittivity maps of equatorial lunar surface is generated. The simulated permittivity values are normalized with respect to density for easy comparison of simulated permittivity values with the permittivity values of Apollo samples as well as with the permittivity values of Terrestrial Analogue of Lunar Soil (TALS) JSC-1A. Lower value of dielectric constant (ε‧) indicates that the corresponding lunar surface is smooth and doesn't have rough rocky terrain. Thus a future lunar astronaut can use these data to decide proper landing site for future lunar missions. The results of this paper will serve as input to future exploration of lunar surface.

SINTERING OF NASCENT CALCIUM OXIDE

EPA Science Inventory

The paper discusses the measurement of the sintering rate of CaO in a nitrogen atmosphere at temperatures of 700-1100 C. CaO prepared from ultrapure CaCO3 was compared with an impure CaO derived from limestone. Both materials yielded an initial surface area of 104 sq m/g. The rat...

40 CFR 63.1386 - Notification, recordkeeping, and reporting requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... temperature above the molten glass in an uncontrolled cold top electric furnace, including any period when the... glass surface, the date and time of the exceedance, when corrective actions were initiated, the cause of... was corrected; (iv) Uncontrolled glass-melting furnace (that is not a cold top electric furnace...

40 CFR 63.1386 - Notification, recordkeeping, and reporting requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... temperature above the molten glass in an uncontrolled cold top electric furnace, including any period when the... glass surface, the date and time of the exceedance, when corrective actions were initiated, the cause of... was corrected; (iv) Uncontrolled glass-melting furnace (that is not a cold top electric furnace...

40 CFR 63.1386 - Notification, recordkeeping, and reporting requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... temperature above the molten glass in an uncontrolled cold top electric furnace, including any period when the... glass surface, the date and time of the exceedance, when corrective actions were initiated, the cause of... was corrected; (iv) Uncontrolled glass-melting furnace (that is not a cold top electric furnace...

40 CFR 63.1386 - Notification, recordkeeping, and reporting requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... temperature above the molten glass in an uncontrolled cold top electric furnace, including any period when the... glass surface, the date and time of the exceedance, when corrective actions were initiated, the cause of... was corrected; (iv) Uncontrolled glass-melting furnace (that is not a cold top electric furnace...

Transient nucleate pool boiling in microgravity: Some initial results

NASA Technical Reports Server (NTRS)

Merte, Herman, Jr.; Lee, H. S.; Ervin, J. S.

1994-01-01

Variable gravity provides an opportunity to test the understanding of phenomena which are considered to depend on buoyancy, such as nucleate pool boiling. The active fundamental research in nucleate boiling has sought to determine the mechanisms or physical processes responsible for its high effectiveness, manifested by the high heat flux levels possible with relatively low temperature differences. Earlier research on nucleate pool boiling at high gravity levels under steady conditions demonstrated quantitatively that the heat transfer is degraded as the buoyancy normal to the heater surfaced increases. Correspondingly, it was later shown, qualitatively for short periods of time only, that nucleate boiling heat transfer is enhanced as the buoyancy normal to the heater surface is reduced. It can be deduced that nucleate pool boiling can be sustained as a quasi-steady process provided that some means is available to remove the vapor generated from the immediate vicinity of the heater surface. One of the objectives of the research, the initial results of which are presented here, is to quantify the heat transfer associated with boiling in microgravity. Some quantitative results of nucleate pool boiling in high quality microgravity (a/g approximately 10(exp -5)) of 5s duration, obtained in an evacuated drop tower, are presented here. These experiments were conducted as precursors of longer term space experiments. A transient heating technique is used, in which the heater surface is a transparent gold film sputtered on a qua rtz substrate, simultaneously providing the mean surface temperature from resistance thermometry and viewing of the boiling process both from beneath and across the surface. The measurement of the transient mean heater surface temperature permits the computation, by numerical means, of the transient mean heat transfer coefficient. The preliminary data obtained demonstrates that a quasi-steady boiling process can occur in microgravity if the bulk liquid subcooling is sufficiently high and if the imposed heat flux is sufficiently low. This is attributed to suface tension effects at the liquid-vapor-solid junction causing rewetting to take place, sustaining the nucleate boiling. Otherwise, dryout at the heater surface will occur, as observed.

SAMOS - A Decade of High-Quality, Underway Meteorological and Oceanographic Data from Research Vessels

NASA Astrophysics Data System (ADS)

Smith, S. R.; Rolph, J.; Briggs, K.; Elya, J. L.; Bourassa, M. A.

2016-02-01

The authors will describe the successes and lessons learned from the Shipboard Automated Meteorological and Oceanographic System (SAMOS) initiative. Over the past decade, SAMOS has acquired, quality controlled, and distributed underway surface meteorological and oceanographic observations from nearly 40 oceanographic research vessels. Research vessels provide underway observations at high-temporal frequency (1-minute sampling interval) that include navigational (position, course, heading, and speed), meteorological (air temperature, humidity, wind, surface pressure, radiation, rainfall), and oceanographic (surface sea temperature and salinity) samples. Vessels recruited to the SAMOS initiative collect a high concentration of data within the U.S. continental shelf, around Hawaii and the islands of the tropical Pacific, and frequently operate well outside routine shipping lanes, capturing observations in extreme ocean environments (Southern, Arctic, South Atlantic, and South Pacific oceans) desired by the air-sea exchange, modeling, and satellite remote sensing communities. The presentation will highlight the data stewardship practices of the SAMOS initiative. Activities include routine automated and visual data quality evaluation, feedback to vessel technicians and operators regarding instrumentation errors, best practices for instrument siting and exposure on research vessels, and professional development activities for research vessel technicians. Best practices for data, metadata, and quality evaluation will be presented. We will discuss ongoing efforts to expand data services to enhance interoperability between marine data centers. Data access and archival protocols will also be presented, including how these data may be referenced and accessed via NCEI.

Development of a Response Surface Thermal Model for Orion Mated to the International Space Station

NASA Technical Reports Server (NTRS)

Miller, Stephen W.; Meier, Eric J.

2010-01-01

A study was performed to determine if a Design of Experiments (DOE)/Response Surface Methodology could be applied to on-orbit thermal analysis and produce a set of Response Surface Equations (RSE) that accurately predict vehicle temperatures. The study used an integrated thermal model of the International Space Station and the Orion Outer mold line model. Five separate factors were identified for study: yaw, pitch, roll, beta angle, and the environmental parameters. Twenty external Orion temperatures were selected as the responses. A DOE case matrix of 110 runs was developed. The data from these cases were analyzed to produce an RSE for each of the temperature responses. The initial agreement between the engineering data and the RSE predictions was encouraging, although many RSEs had large uncertainties on their predictions. Fourteen verification cases were developed to test the predictive powers of the RSEs. The verification showed mixed results with some RSE predicting temperatures matching the engineering data within the uncertainty bands, while others had very large errors. While this study to not irrefutably prove that the DOE/RSM approach can be applied to on-orbit thermal analysis, it does demonstrate that technique has the potential to predict temperatures. Additional work is needed to better identify the cases needed to produce the RSEs

Cleavage fracture in pearlitic eutectoid steel

NASA Astrophysics Data System (ADS)

Alexander, D. J.; Bernstein, I. M.

1989-11-01

The effect of microstructure on flow and fracture properties of fully pearlitic steel has been studied by independently varying the prior austenite grain size and the pearlite interlamellar spacing through appropriate heat treatments. The yield strength is independent of the prior austenite grain size but increases as the interlamellar spacing or the temperature decreases. The microstructural dependence can be explained by using a model which assumes that yielding is controlled by dislocation motion in the ferrite lamellae. The critical tensile stress for cleavage fracture is found to be independent of prior austenite grain size, increasing as the interlamellar spacing decreases. The cleavage fracture stress is independent of temperature for fine pearlite but increases as the temperature decreases for coarse pearlite. The associated fracture in blunt notch specimens initiates at inclusions beneath notch surface near the location of maximum tensile stress. From the size of such inclusions, the effective surface energy for cleavage fracture can be directly calculated and is found to be independent of temperature and prior austenite grain size but to increase as the interlamellar spacing decreases, from about 5 to 13 J/m2 for the range of microstructures and temperatures used in this study. Additional measurements of the effective surface energy and further theoretical analyses of the cleavage process are needed.

Surface microstructure and high temperature corrosion resistance of arc-sprayed FeCrAl coating irradiated by high current pulsed electron beam

NASA Astrophysics Data System (ADS)

Hao, Shengzhi; Zhao, Limin; He, Dongyun

2013-10-01

The surface microstructure of arc-sprayed FeCrAl coating irradiated by high current pulsed electron beam (HCPEB) with long pulse duration of 200 μs was characterized by using optical microscopy, scanning electron microscopy and X-ray diffractometry. The distribution of chemical composition in modified surface layer was measured with electron probe micro-analyzer. The high temperature corrosion resistance of FeCrAl coating was tested in a saturated Na2SO4 and K2SO4 solution at 650 °C. After HCPEB irradiation, the coarse surface of arc-sprayed coating was changed as discrete bulged nodules with smooth and compact appearance. When using low energy density of 20 J/cm2, the surface modified layer was continuous entirely with an average melting depth of ˜30 μm. In the surface remelted layer, Fe and Cr elements gave a uniform distribution, while Al and O elements agglomerated particularly at the concave part between nodule structures to form α-Al2O3 phase. After high temperature corrosion tests, the FeCrAl coating treated with HCPEB of 20 J/cm2 remained a glossy surface with weight increment of ˜51 mg/cm2, decreased by 20% as compared to the initial sample. With the increasing energy density of HCPEB irradiation, the integrity of surface modified layer got segmented due to the formation of larger bulged nodules and cracks at the concave parts. For the HCPEB irradiation of 40 J/cm2, the high temperature corrosion resistance of FeCrAl coating was deteriorated drastically.

The effects of internal heating and large scale climate variations on tectonic bi-stability in terrestrial planets

NASA Astrophysics Data System (ADS)

Weller, M. B.; Lenardic, A.; O'Neill, C.

2015-06-01

We use 3D mantle convection and planetary tectonics models to explore the links between tectonic regimes and the level of internal heating within the mantle of a planet (a proxy for thermal age), planetary surface temperature, and lithosphere strength. At both high and low values of internal heating, for moderate to high lithospheric yield strength, hot and cold stagnant-lid (single plate planet) states prevail. For intermediate values of internal heating, multiple stable tectonic states can exist. In these regions of parameter space, the specific evolutionary path of the system has a dominant role in determining its tectonic state. For low to moderate lithospheric yield strength, mobile-lid behavior (a plate tectonic-like mode of convection) is attainable for high degrees of internal heating (i.e., early in a planet's thermal evolution). However, this state is sensitive to climate driven changes in surface temperatures. Relatively small increases in surface temperature can be sufficient to usher in a transition from a mobile- to a stagnant-lid regime. Once a stagnant-lid mode is initiated, a return to mobile-lid is not attainable by a reduction of surface temperatures alone. For lower levels of internal heating, the tectonic regime becomes less sensitive to surface temperature changes. Collectively our results indicate that terrestrial planets can alternate between multiple tectonic states over giga-year timescales. Within parameter space regions that allow for bi-stable behavior, any model-based prediction as to the current mode of tectonics is inherently non-unique in the absence of constraints on the geologic and climatic histories of a planet.

Molecular dynamics simulation study of nanoscale passive oxide growth on Ni-Al alloy surfaces at low temperatures

NASA Astrophysics Data System (ADS)

Sankaranarayanan, Subramanian K. R. S.; Ramanathan, Shriram

2008-08-01

Oxidation kinetics of Ni-Al (100) alloy surface is investigated at low temperatures (300-600 K) and at different gas pressures using molecular dynamics (MD) simulations with dynamic charge transfer between atoms. Monte Carlo simulations employing the bond order simulation model are used to generate the surface segregated minimum energy initial alloy configurations for use in the MD simulations. In the simulated temperature-pressure-composition regime for Ni-Al alloys, we find that the oxide growth curves follow a logarithmic law beyond an initial transient regime. The oxidation rates for Ni-Al alloys were found to decrease with increasing Ni composition. Structure and dynamical correlations in the metal/oxide/gas environments are used to gain insights into the evolution and morphology of the growing oxide film. Oxidation of Ni-Al alloys is characterized by the absence of Ni-O bond formation. Oxide films formed on the various simulated metal surfaces are amorphous in nature and have a limiting thickness ranging from ˜1.7nm for pure Al to 1.1 nm for 15% Ni-Al surfaces. Oxide scale analysis indicates significant charge transfer as well as variation in the morphology and structure of the oxide film formed on pure Al and 5% Ni-Al alloy. For oxide scales thicker than 1 nm, the oxide structure in case of pure Al exhibits a mixed tetrahedral (AlO4˜37%) and octahedral (AlO6˜19%) environment, whereas the oxide scale on Ni-Al alloy surface is almost entirely composed of tetrahedral environment (AlO4˜60%) with very little AlO6 (<1%) . The oxide growth kinetic curves are fitted to Arrhenius-type plots to get an estimate of the activation energy barriers for metal oxidation. The activation energy barrier for oxidation on pure Al was found to be 0.3 eV lower than that on 5% Ni-Al surface. Atomistic observations as well as calculated dynamical correlation functions indicate a layer by layer growth on pure Al, whereas a transition from an initial island growth mode (<75ps) to a layer by layer mode (>100ps) occurs in case of 5% Ni-Al alloy. The oxide growth on both pure Al and Ni-Al alloy surfaces occurs by inward anion and outward cation diffusions. The cation diffusion in both the cases is similar, whereas the anion diffusion in case of 5% Ni-Al is 25% lower than pure Al, thereby resulting in reduced self-limiting thickness of oxide scale on the alloy surface. The simulation findings agree well with previously reported experimental observations of oxidation on Ni-Al alloy surface.

Using the ``blue spike'' to characterize biomass-burning sites during Southern African Regional Science Initiative (SAFARI) 2000

NASA Astrophysics Data System (ADS)

McCourt, M. L.; McMillan, W. W.; Ackerman, S.; Holz, R.; Revercomb, H. E.; Tobin, D.

2004-10-01

During several flights of the ER-2 while participating in the Southern African Regional Science Initiative (SAFARI 2000), the University of Wisconsin-Madison's Scanning High Resolution Interferometer Sounder (S-HIS) obtained spectra containing isolated fires within its field of view (FOV). These fire-laden FOVs contain a spectral feature caused by rotational hot band transitions of CO2 near 2400 cm-1. Because of its location on the blue side of the 4.3 μm band of CO2, this feature is commonly referred to as the "blue spike." Using this feature, we detected fires on four flights: 24 and 27 August and 6 and 7 September 2000. Fire locations are further verified by the ER-2 pilot's flight logs and elevated brightness temperatures in the thermal detectors of the MODIS Airborne Simulator (MAS) also on board the ER-2. Using line-by-line radiative transfer calculations (Genln2) with corrections for a fire's extreme high temperatures (HiTemp), we model S-HIS spectra for various scenes: background (cool surface and cool atmosphere), smoldering (warm surface and cool atmosphere), hot gas layer (cool surface and warm atmosphere), and fire (hot surface and hot atmosphere) cases. Using the controlled burn in the Timbavati Game Reserve on 7 September 2000 as a test case, we spectrally modeled the blue spike feature seen in the spectra obtained by S-HIS while the ER-2 flew over the fire. For this case, we found that ˜4.12 ± 0.05% of the FOV contained the hot gas layer while ˜0.23 ± 0.05% was actively burning. Originally viewed as a straightforward task of using the blue spike to characterize the fire temperature and size (fraction of S-HIS FOV), our analysis shows that numerous variables, including amount of carbon dioxide, amount of water vapor, and the temperature near the fire, play significant roles in the blue spike's shape and spectral position.

Effects of selected process parameters in extrusion of yam flour (Dioscorea rotundata) on physicochemical properties of the extrudates.

PubMed

Sebio, L; Chang, Y K

2000-04-01

Raw yam (Dioscorea rotundata) flour was cooked and extruded in a Brabender single-screw laboratory scale extruder. Response surface methodology using an incomplete factorial design was applied with various combinations of barrel temperature [100, 125, 150 degrees C], feed moisture content [18, 22, 26%] and screw speed [100, 150, 200 rpm]. Initial viscosity at 30 degrees C, water solubility index, expansion and hardness were determined. The highest values of initial viscosity were at the highest barrel temperatures and the highest moisture contents. At high feed moisture content and high barrel temperatures the yam extrudate flour showed the greatest values of water solubility index. The physical properties of the extruded product showed that at high temperature the lower the moisture content the greater the expansion index. Hardness was influenced directly by moisture content and inversely by extrusion temperature. The extrusion of yam flour led to the production of snacks and pre-gelatinized flours of diverse properties. Also extruded yam flour can be successfully used in the preparation of 'futu' (pre-cooked compact dough), a yam-based food, popular in Western Africa.

Buckybomb: Reactive Molecular Dynamics Simulation

DOE PAGES

Chaban, Vitaly V.; Fileti, Eudes Eterno; Prezhdo, Oleg V.

2015-02-24

Energetic materials, such as explosives, propellants, and pyrotechnics, are widely used in civilian and military applications. Nanoscale explosives represent a special group because of the high density of energetic covalent bonds. The reactive molecular dynamics (ReaxFF) study of nitrofullerene decomposition reported here provides a detailed chemical mechanism of explosion of a nanoscale carbon material. Upon initial heating, C 60(NO 2) 12 disintegrates, increasing temperature and pressure by thousands of Kelvins and bars within tens of picoseconds. The explosion starts with NO 2 group isomerization into C-O-N-O, followed by emission of NO molecules and formation of CO groups on the buckyballmore » surface. NO oxidizes into NO 2, and C 60 falls apart, liberating CO 2. At the highest temperatures, CO 2 gives rise to diatomic carbon. Lastly, the study shows that the initiation temperature and released energy depend strongly on the chemical composition and density of the material.« less

A one-dimensional nonlinear problem of thermoelasticity in extended thermodynamics

NASA Astrophysics Data System (ADS)

Rawy, E. K.

2018-06-01

We solve a nonlinear, one-dimensional initial boundary-value problem of thermoelasticity in generalized thermodynamics. A Cattaneo-type evolution equation for the heat flux is used, which differs from the one used extensively in the literature. The hyperbolic nature of the associated linear system is clarified through a study of the characteristic curves. Progressive wave solutions with two finite speeds are noted. A numerical treatment is presented for the nonlinear system using a three-step, quasi-linearization, iterative finite-difference scheme for which the linear system of equations is the initial step in the iteration. The obtained results are discussed in detail. They clearly show the hyperbolic nature of the system, and may be of interest in investigating thermoelastic materials, not only at low temperatures, but also during high temperature processes involving rapid changes in temperature as in laser treatment of surfaces.

Applying Central Composite Design and Response Surface Methodology to Optimize Growth and Biomass Production of Haemophilus influenzae Type b.

PubMed

Momen, Seyed Bahman; Siadat, Seyed Davar; Akbari, Neda; Ranjbar, Bijan; Khajeh, Khosro

2016-06-01

Haemophilus influenzae type b (Hib) is the leading cause of bacterial meningitis, otitis media, pneumonia, cellulitis, bacteremia, and septic arthritis in infants and young children. The Hib capsule contains the major virulence factor, and is composed of polyribosyl ribitol phosphate (PRP) that can induce immune system response. Vaccines consisting of Hib capsular polysaccharide (PRP) conjugated to a carrier protein are effective in the prevention of the infections. However, due to costly processes in PRP production, these vaccines are too expensive. To enhance biomass, in this research we focused on optimizing Hib growth with respect to physical factors such as pH, temperature, and agitation by using a response surface methodology (RSM). We employed a central composite design (CCD) and a response surface methodology to determine the optimum cultivation conditions for growth and biomass production of H. influenzae type b. The treatment factors investigated were initial pH, agitation, and temperature, using shaking flasks. After Hib cultivation and determination of dry biomass, analysis of experimental data was performed by the RSM-CCD. The model showed that temperature and pH had an interactive effect on Hib biomass production. The dry biomass produced in shaking flasks was about 5470 mg/L, which was under an initial pH of 8.5, at 250 rpm and 35° C. We found CCD and RSM very effective in optimizing Hib culture conditions, and Hib biomass production was greatly influenced by pH and incubation temperature. Therefore, optimization of the growth factors to maximize Hib production can lead to 1) an increase in bacterial biomass and PRP productions, 2) lower vaccine prices, 3) vaccination of more susceptible populations, and 4) lower risk of Hib infections.

Measurement of the properties of lossy materials inside a finite conducting cylinder

NASA Technical Reports Server (NTRS)

Dominek, A.; Park, A.; Caldecott, R.

1988-01-01

Broadband, swept frequency measurement techniques were investigated for the evaluation of the electrical performance of thin, high temperature material coatings. Reflections and transmission measurements using an HP8510B Network Analyzer were developed for an existing high temperature test rig at NASA Lewis Research Center. Reflection measurements will be the initial approach used due to fixture simplicity even though surface wave transmission measurements would be more sensitive. The minimum goal is to monitor the electrical change of the material's performance as a function of temperature. If possible, the materials constitutive parameters, epsilon and muon will be found.

Process for introducing electrical conductivity into high-temperature polymeric materials

DOEpatents

Liepins, R.; Jorgensen, B.S.; Liepins, L.Z.

1993-12-21

High-temperature electrically conducting polymers are described. The in situ reactions: AgNO[sub 3] + RCHO [yields] Ag + RCOOH and R[sub 3]M [yields] M + 3R, where M=Au or Pt have been found to introduce either substantial bulk or surface conductivity in high-temperature polymers. The reactions involving the R[sub 3]M were caused to proceed thermally suggesting the possibility of using laser means for initiating such reactions in selected areas or volumes of the polymeric materials. The polymers successfully investigated to date are polyphenylquinoxaline, polytolylquinoxaline, polyquinoline, polythiazole, and pyrone.

Process for introducing electrical conductivity into high-temperature polymeric materials

DOEpatents

Liepins, Raimond; Jorgensen, Betty S.; Liepins, Leila Z.

1993-01-01

High-temperature electrically conducting polymers. The in situ reactions: AgNO.sub.3 +RCHO.fwdarw.Ag.degree.+RCOOH and R.sub.3 M.fwdarw.M.degree.+3R, where M=Au or Pt have been found to introduce either substantial bulk or surface conductivity in high-temperature polymers. The reactions involving the R.sub.3 M were caused to proceed thermally suggesting the possibility of using laser means for initiating such reactions in selected areas or volumes of the polymeric materials. The polymers successfully investigated to date are polyphenylquinoxaline, polytolylquinoxaline, polyquinoline, polythiazole, and pyrrone.

Process for introducing electrical conductivity into high-temperature polymeric materials

DOEpatents

Liepins, Raimond; Jorgensen, Betty S.; Liepins, Leila Z.

1989-01-01

High-temperature electrically conducting polymers. The in situ reactions: AgNO.sub.3 +RCHO.fwdarw.AG.sup.0 +RCOOH and R.sub.3 M.fwdarw.M.sup.0 3R, where M=Au or Pt have been found to introduce either substantial bulk or surface conductivity in high-temperature polymers. The reactions involving the R.sub.3 M were caused to proceed thermally suggesting the possibility of using laser means for initiating such reactions in selected areas or volumes of the polymeric materials. The polymers successfully investigated to date are polyphenylquinoxaline, polytolylquinoxaline, polyquinoline, polythiazole, and pyrrone.

Process for introducing electrical conductivity into high-temperature polymeric materials

DOEpatents

Liepins, R.; Jorgensen, B.S.; Liepins, L.Z.

1987-08-27

High-temperature electrically conducting polymers. The in situ reactions: AgNO/sub 3/ + RCHO ..-->.. Ag/sup 0/ + RCOOH and R/sub 3/M ..-->.. M/sup 0/ + 3R, where M = Au or Pt have been found to introduce either substantial bulk or surface conductivity in high- temperature polymers. The reactions involving the R/sub 3/M were caused to proceed thermally suggesting the possibility of using laser means for initiating such reactions in selected areas or volumes of the polymeric materials. The polymers successfully investigated to date are polyphenylquinoxaline, polytolylquinoxaline, polyquinoline, polythiazole, and pyrrone. 3 tabs.

Positive ion temperature effect on the plasma-wall transition

NASA Astrophysics Data System (ADS)

Morales Crespo, R.

2018-06-01

This paper analyses the plasma-wall interaction of a plasma in contact with a conducting planar surface when the positive-ion temperature is not negligible compared with the electron one. The electric potential from the plasma to the wall is obtained by the appropriate formulation of the model as an initial-value problem as well as some features useful for experimental applications, such as the positive current-to-voltage characteristics, the saturation current density, the floating potential or an estimation of the sheath thickness. Finally, it is analysed how all these quantities depend on the ionization degree and the positive-ion temperature.

The Effect of High Temperature Corrosion on Mechanical Behavior of a GAMMA-TiAl Alloy

NASA Astrophysics Data System (ADS)

Zhao, Wenyue; Ma, Yue; Gong, Shengkai

The mechanical properties of Ti-48Al-2Cr-2Nb alloy were discussed after the high temperature corrosion tests carried out with salt mixture of 75wt. % Na2SO4 and 25wt. % NaCl at 800°C. The microstructure of the alloy after corrosion was observed by SEM and the fracture behavior of the corroded and uncorroded alloys was investigated by means of the three-point bending tests. It has been shown that the corrosion path was mainly along the lamellar structure and rough surface with a large number of corrosion pits formed during the high temperature corrosion. The experimental results also indicated that the bearing capacity of bending fracture descended evidently due to the molten salt corrosion at high temperature, which only had remarkable effects on the surface state of the alloy. The microcracks inside the alloy always propagated along the phase interfaces and grain boundaries while the corrosion pits on salt-deposited surface became the main crack initiation location in corroded alloy. The stress concentration caused by corrosion was considered as the essential reason of the property reduction, which decreased the energy barrier of crack nucleation and shortened the incubation period.

High-resolution heat-transfer-coefficient maps applicable to compound-curve surfaces using liquid crystals in a transient wind tunnel

NASA Technical Reports Server (NTRS)

Jones, Terry V.; Hippensteele, Steven A.

1988-01-01

Tests were performed in a transient heat transfer tunnel in which the model under test was preheated prior to allowing room temperature air to be suddenly drawn over the model. The resulting movement of isothermal contours on the model is revealed using a surface coating of thermochromic liquid crystals that display distinctive colors at particular temperatures. A video record is obtained of a temperature and time data pair for all points on the model during a single test. Experiments on a duct model are reported in which the model was preheated using a hot air stream. A manner in which initial model temperature nonuniformities could be taken into account was investigated. The duct model was also tested with a steady-state measurement technique and results were compared with the transient measurements, but recognizing that differences existed between the upstream thermal boundary conditions. The steady-state and transient measurements were shown to be consistent with predicted values. The main advantage of this transient heat transfer technique using liquid crystals is that since the test model need not be actively heated, high-resolution measurements on surfaces with complex shapes may be obtained.

Mechanism study on the sulfidation of ZnO with sulfur and iron oxide at high temperature

NASA Astrophysics Data System (ADS)

Han, Junwei; Liu, Wei; Zhang, Tianfu; Xue, Kai; Li, Wenhua; Jiao, Fen; Qin, Wenqing

2017-02-01

The mechanism of ZnO sulfidation with sulfur and iron oxide at high temperatures was studied. The thermodynamic analysis, sulfidation behavior of zinc, phase transformations, morphology changes, and surface properties were investigated by HSC 5.0 combined with FactSage 7.0, ICP, XRD, optical microscopy coupled with SEM-EDS, and XPS. The results indicate that increasing temperature and adding iron oxide can not only improve the sulfidation of ZnO but also promote the formation and growth of ZnS crystals. Fe2O3 captured the sulfur in the initial sulfidation process as iron sulfides, which then acted as the sulfurizing agent in the late period, thus reducing sulfur escape at high temperatures. The addition of carbon can not only enhance the sulfidation but increase sulfur utilization rate and eliminate the generation of SO2. The surfaces of marmatite and synthetic zinc sulfides contain high oxygen due to oxidation and oxygen adsorption. Hydroxyl easily absorbs on the surface of iron-bearing zinc sulfide (Zn1-xFexS). The oxidation of synthetic Zn1-xFexS is easier than marmatite in air.

Mechanism study on the sulfidation of ZnO with sulfur and iron oxide at high temperature

PubMed Central

Han, Junwei; Liu, Wei; Zhang, Tianfu; Xue, Kai; Li, Wenhua; Jiao, Fen; Qin, Wenqing

2017-01-01

The mechanism of ZnO sulfidation with sulfur and iron oxide at high temperatures was studied. The thermodynamic analysis, sulfidation behavior of zinc, phase transformations, morphology changes, and surface properties were investigated by HSC 5.0 combined with FactSage 7.0, ICP, XRD, optical microscopy coupled with SEM-EDS, and XPS. The results indicate that increasing temperature and adding iron oxide can not only improve the sulfidation of ZnO but also promote the formation and growth of ZnS crystals. Fe2O3 captured the sulfur in the initial sulfidation process as iron sulfides, which then acted as the sulfurizing agent in the late period, thus reducing sulfur escape at high temperatures. The addition of carbon can not only enhance the sulfidation but increase sulfur utilization rate and eliminate the generation of SO2. The surfaces of marmatite and synthetic zinc sulfides contain high oxygen due to oxidation and oxygen adsorption. Hydroxyl easily absorbs on the surface of iron-bearing zinc sulfide (Zn1−xFexS). The oxidation of synthetic Zn1−xFexS is easier than marmatite in air. PMID:28186156

Effect of surface modification on hydration kinetics of carbamazepine anhydrate using isothermal microcalorimetry.

PubMed

Otsuka, Makoto; Ishii, Mika; Matsuda, Yoshihisa

2003-01-01

The purpose of this research was to improve the stability of carbamazepine (CBZ) bulk powder under high humidity by surface modification. The surface-modified anhydrates of CBZ were obtained in a specially designed surface modification apparatus at 60 degrees C via the adsorption of n-butanol, and powder x-ray diffraction, Fourier-Transformed Infrared spectra, and differential scanning calorimetry were used to determine the crystalline characteristics of the samples. The hydration process of intact and surface-modified CBZ anhydrate at 97% relative humidity (RH) and 40 +/-C 1 degrees C was automatically monitored by using isothermal microcalorimetry (IMC). The dissolution test for surface-modified samples (20 mg) was performed in 900 mL of distilled water at 37 +/-C 0.5 degrees C with stirring by a paddle at 100 rpm as in the Japanese Pharmacopoeia XIII. The heat flow profiles of hydration of intact and surface-modified CBZ anhydrates at 97% RH by using IMC profiles showed a maximum peak at around 10 hours and 45 hours after 0 and 10 hours of induction, respectively. The result indicated that hydration of CBZ anhydrate was completely inhibited at the initial stage by surface modification of n-butanol and thereafter transformed into dihydrate. The hydration of surface-modified samples followed a 2-dimensional phase boundary process with an induction period (IP). The IP of intact and surface-modified samples decreased with increase of the reaction temperature, and the hydration rate constant (k) increased with increase of the temperature. The crystal growth rate constants of nuclei of the intact sample were significantly larger than the surface-modified sample's at each temperature. The activation energy (E) of nuclei formation and crystal growth process for hydration of surface-modified CBZ anhydrate were evaluated to be 20.1 and 32.5 kJ/mol, respectively, from Arrhenius plots, but the Es of intact anhydrate were 56.3 and 26.8 kJ/mol, respectively. The dissolution profiles showed that the surface-modified sample dissolved faster than the intact sample at the initial stage. The dissolution kinetics were analyzed based on the Hixon-Crowell equation, and the dissolution rate constants for intact and surface-modified anhydrates were found to be 0.0102 +/-C 0.008 mg(1/3) x min(-1) and 0.1442 +/-C 0.0482 mg(1/3) x min(-1). The surface-modified anhydrate powders were more stable than the nonmodified samples under high humidity and showed resistance against moisture. However, surface modification induced rapid dissolution in water compared to the control.

Creep fatigue life prediction for engine hot section materials (isotropic)

NASA Technical Reports Server (NTRS)

Moreno, V.

1983-01-01

The Hot Section Technology (HOST) program, creep fatigue life prediction for engine hot section materials (isotropic), is reviewed. The program is aimed at improving the high temperature crack initiation life prediction technology for gas turbine hot section components. Significant results include: (1) cast B1900 and wrought IN 718 selected as the base and alternative materials respectively; (2) fatigue test specimens indicated that measurable surface cracks appear early in the specimen lives, i.e., 15% of total life at 871 C and 50% of life at 538 c; (3) observed crack initiation sites are all surface initiated and are associated with either grain boundary carbides or local porosity, transgrannular cracking is observed at the initiation site for all conditions tested; and (4) an initial evaluation of two life prediction models, representative of macroscopic (Coffin-Mason) and more microscopic (damage rate) approaches, was conducted using limited data generated at 871 C and 538 C. It is found that the microscopic approach provides a more accurate regression of the data used to determine crack initiation model constants, but overpredicts the effect of strain rate on crack initiation life for the conditions tested.

Effects of ocean initial perturbation on developing phase of ENSO in a coupled seasonal prediction model

NASA Astrophysics Data System (ADS)

Lee, Hyun-Chul; Kumar, Arun; Wang, Wanqiu

2018-03-01

Coupled prediction systems for seasonal and inter-annual variability in the tropical Pacific are initialized from ocean analyses. In ocean initial states, small scale perturbations are inevitably smoothed or distorted by the observational limits and data assimilation procedures, which tends to induce potential ocean initial errors for the El Nino-Southern Oscillation (ENSO) prediction. Here, the evolution and effects of ocean initial errors from the small scale perturbation on the developing phase of ENSO are investigated by an ensemble of coupled model predictions. Results show that the ocean initial errors at the thermocline in the western tropical Pacific grow rapidly to project on the first mode of equatorial Kelvin wave and propagate to the east along the thermocline. In boreal spring when the surface buoyancy flux weakens in the eastern tropical Pacific, the subsurface errors influence sea surface temperature variability and would account for the seasonal dependence of prediction skill in the NINO3 region. It is concluded that the ENSO prediction in the eastern tropical Pacific after boreal spring can be improved by increasing the observational accuracy of subsurface ocean initial states in the western tropical Pacific.

Comparison of surface temperature in 13-lined ground squirrel (Spermophilus tridecimlineatus) and yellow-bellied marmot (Marmota flaviventris) during arousal from hibernation.

PubMed

Phillips, P K; Heath, J E

2004-08-01

Surface temperatures (Ts) of eight 13-lined ground squirrels and seven yellow-bellied marmots were measured during arousal from hibernation using infrared thermography (IRT) and recorded on videotape. Animals aroused normally in 5 degrees C cold rooms. Body temperatures were recorded during arousal using both cheek pouch and interscapular temperature probes. Warming rate in arousal was exponential. Mean mass specific warming rates show the squirrels warm faster (69.76 degrees C/h/kg) than the marmots (4.49 degrees C/h/kg). Surface temperatures (Ts) for 11 regions were measured every few minutes during arousal. The smaller ground squirrel shows the ability to perfuse distal regions without compromising rise in deep body temperature (Tb). All squirrel Ts's remained low as Tb rose to 18 degrees C, at which point, eyes opened, squirrels became more active and all Ts's rose parallel to Tb. Marmot Ts remained low as Tb rose initially. Each marmot showed a plateau phase where Tb remained constant (mean Tb 20.3+/-1.0 degrees C, duration 9.4+/-4.1 min) during which time all Ts's rose, and then remained relatively constant as Tb again began to rise. An anterior to posterior Ts gradient was evident in the ground squirrel, both body and feet. This gradient was only evident in the feet of the marmots.

Ultrasonic hydrometer. [Specific gravity of electrolyte

DOEpatents

Swoboda, C.A.

1982-03-09

The disclosed ultrasonic hydrometer determines the specific gravity (density) of the electrolyte of a wet battery, such as a lead-acid battery. The hydrometer utilizes a transducer that when excited emits an ultrasonic impulse that traverses through the electrolyte back and forth between spaced sonic surfaces. The transducer detects the returning impulse, and means measures the time t between the initial and returning impulses. Considering the distance d between the spaced sonic surfaces and the measured time t, the sonic velocity V is calculated with the equation V = 2d/t. The hydrometer also utilizes a thermocouple to measure the electrolyte temperature. A hydrometer database correlates three variable parameters including sonic velocity in and temperature and specific gravity of the electrolyte, for temperature values between 0 and 40/sup 0/C and for specific gravity values between 1.05 and 1.30. Upon knowing two parameters (the calculated sonic velocity and the measured temperature), the third parameter (specific gravity) can be uniquely found in the database. The hydrometer utilizes a microprocessor for data storage and manipulation.

Thermal Vacuum Facility for Testing Thermal Protection Systems

NASA Technical Reports Server (NTRS)

Daryabeigi, Kamran; Knutson, Jeffrey R.; Sikora, Joseph G.

2002-01-01

A thermal vacuum facility for testing launch vehicle thermal protection systems by subjecting them to transient thermal conditions simulating re-entry aerodynamic heating is described. Re-entry heating is simulated by controlling the test specimen surface temperature and the environmental pressure in the chamber. Design requirements for simulating re-entry conditions are briefly described. A description of the thermal vacuum facility, the quartz lamp array and the control system is provided. The facility was evaluated by subjecting an 18 by 36 in. Inconel honeycomb panel to a typical re-entry pressure and surface temperature profile. For most of the test duration, the average difference between the measured and desired pressures was 1.6% of reading with a standard deviation of +/- 7.4%, while the average difference between measured and desired temperatures was 7.6% of reading with a standard deviation of +/- 6.5%. The temperature non-uniformity across the panel was 12% during the initial heating phase (t less than 500 sec.), and less than 2% during the remainder of the test.

The Effect of Composition on the Surface Finish of PS400: A New High Temperature Solid Lubricant Coating

NASA Technical Reports Server (NTRS)

DellaCorte, Christopher; Stanford, malcolm K.; Thomas, Fransua; Edmonds, Brian J.

2010-01-01

A new composite, multi-constituent, solid lubricant coating, NASA PS400, developed for high temperature tribological applications, exhibits a smoother surface finish after grinding and polishing than its predecessors PS200 and PS300. In this paper, the baseline composition of PS400 is modified to investigate each individual constituent s role on the achievable surface finish through a series of coating deposition, grinding, and polishing experiments. Furthermore, to explore the limits of compositional tailoring for improved tribological performance, several PS400 coatings were doped with additional solid lubricants (graphite, MoS2 and BN) and tribologically tested. The test results clearly showed that, compared to PS300 coatings, PS400 achieves a smoother surface finish via a reduced lubricant content. Coatings prepared with higher than the baseline level (10 wt%) of lubricants exhibited higher final surface roughness than the earlier generation PS300 coatings. Reducing or eliminating the one or both lubricants (fluorides or silver) did not further improve the surface finish suggesting that the current composition of PS400 is near optimal with respect to surface finish. Lastly, attempts to improve the poor initial room temperature tribological behavior of PS400 via the addition of traditional solid lubricants were unsuccessful. Based upon this work and earlier results it is expected that future research will concentrate on developing methods to produce a lubricious glaze on the rubbing surface during break in to ensure that low friction and wear are rapidly achieved.

Influence of surface nudging on climatological mean and ENSO feedbacks in a coupled model

NASA Astrophysics Data System (ADS)

Zhu, Jieshun; Kumar, Arun

2018-01-01

Studies have suggested that surface nudging could be an efficient way to reconstruct the subsurface ocean variability, and thus a useful method for initializing climate predictions (e.g., seasonal and decadal predictions). Surface nudging is also the basis for climate models with flux adjustments. In this study, however, some negative aspects of surface nudging on climate simulations in a coupled model are identified. Specifically, a low-resolution version of the NCEP Climate Forecast System, version 2 (CFSv2L) is used to examine the influence of nudging on simulations of climatological mean and on the coupled feedbacks during ENSO. The effect on ENSO feedbacks is diagnosed following a heat budget analysis of mixed layer temperature anomalies. Diagnostics of the climatological mean state indicates that, even though SST biases in all ocean basins, as expected, are eliminated, the fidelity of climatological precipitation, surface winds and subsurface temperature (or the thermocline depth) could be highly ocean basin dependent. This is exemplified by improvements in the climatology of these variables in the tropical Atlantic, but degradations in the tropical Pacific. Furthermore, surface nudging also distorts the dynamical feedbacks during ENSO. For example, while the thermocline feedback played a critical role during the evolution of ENSO in a free simulation, it only played a minor role in the nudged simulation. These results imply that, even though the simulation of surface temperature could be improved in a climate model with surface nudging, the physics behind might be unrealistic.

Direct observation of electrothermal instability structures on intensely Ohmically heated aluminum with current flowing in a surface skin layer

NASA Astrophysics Data System (ADS)

Awe, Thomas

2017-10-01

Implosions on the Z Facility assemble high-energy-density plasmas for radiation effects and ICF experiments, but achievable stagnation pressures and temperatures are degraded by the Magneto-Rayleigh-Taylor (MRT) instability. While the beryllium liners (tubes) used in Magnetized Liner Inertial Fusion (MagLIF) experiments are astonishingly smooth (10 to 50 nm RMS roughness), they also contain distributed micron-scale resistive inclusions, and large MRT amplitudes are observed. Early in the implosion, an electrothermal instability (ETI) may provide a perturbation which greatly exceeds the initial surface roughness of the liner. Resistive inhomogeneities drive nonuniform current density and Joule heating, resulting in locally higher temperature, and thus still higher resistivity. Such unstable temperature and pressure growth produce density perturbations which seed MRT. For MagLIF liners, ETI seeding of MRT has been inferred by evaluating late-time MRT, but a direct observation of ETI is not made. ETI is directly observed on the surface of 1.0-mm-diameter solid Al rods pulsed to 1 MA in 100 ns via high resolution gated optical imaging (2 ns temporal and 3 micron spatial resolution). Aluminum 6061 alloy rods, with micron-scale resistive inclusions, consistently first demonstrate overheating from distinct, 10-micron-scale, sub-eV spots, which 5-10 ns later merge into azimuthally stretched elliptical spots and discrete strata (40-100 microns wide by 10 microns tall). Axial plasma filaments form shortly thereafter. Surface plasma can be suppressed for rods coated with dielectric, enabling extended study of the evolution of stratified ETI structures, and experimental inference of ETI growth rates. This fundamentally new and highly 3-dimensional dataset informs ETI physics, including when the ETI seed of MRT may be initiated.

Wetting Transition of Nonpolar Neutral Molecule System on a Neutral and Atomic Length Scale Roughness Substrate

NASA Astrophysics Data System (ADS)

Zhou, Shiqi

2018-03-01

One recently proposed new method for accurately determining wetting temperature is applied to the wetting transition occurring in a single component nonpolar neutral molecule system near a neutral planar substrate with roughness produced by cosinusoidal modulation(s). New observations are summarized into five points: (i) for a planar substrate superimposed with one cosinusoidal modulation, with increasing of the periodicity length or the surface attraction force field, or decreasing of the amplitude, wetting temperature T_W drops accordingly and the three parameters show multiplication effect; moreover, both the periodicity length and amplitude effect curves display pole phenomena and saturation phenomena, and the T_W saturation occurs at small (for case of large amplitude) or large (for case of small amplitude) periodicity length side, respectively. (ii) In the case of the planar substrate superimposed with two cosinusoidal modulations with equal periodicity length, the initial phase difference is critical issue that influences the T_W, which decreases with the initial phase difference. (iii) In the case of the planar substrate superimposed with two cosinusoidal modulations with zero phase difference, change of the T_W with one periodicity length under the condition of another periodicity length unchanged is non-monotonous. (iv) When the parameters are chosen such that the T_W draws ever closer to the bulk critical temperature, wetting transition on the roughness substrate eventually does not occur. (v) The present microscopic calculation challenges traditional macroscopic theory by confirming that the atomic length scale roughness always renders the surface less hydrophilic and whereas the mesoscopical roughness renders the surface more hydrophilic. All of these observations summarized can be reasonably explained by the relative strength of the attraction actually enjoyed by the surface gas molecules to the attraction the gas molecules can get when in bulk.

EXPERIMENTAL EVALUATION OF THE THERMAL PERFORMANCE OF A WATER SHIELD FOR A SURFACE POWER REACTOR

DOE Office of Scientific and Technical Information (OSTI.GOV)

REID, ROBERT S.; PEARSON, J. BOSIE; STEWART, ERIC T.

2007-01-16

Water based reactor shielding is being investigated for use on initial lunar surface power systems. A water shield may lower overall cost (as compared to development cost for other materials) and simplify operations in the setup and handling. The thermal hydraulic performance of the shield is of significant interest. The mechanism for transferring heat through the shield is natural convection. Natural convection in a 100 kWt lunar surface reactor shield design is evaluated with 2 kW power input to the water in the Water Shield Testbed (WST) at the NASA Marshall Space Flight Center. The experimental data from the WSTmore » is used to validate a CFD model. Performance of the water shield on the lunar surface is then predicted with a CFD model anchored to test data. The experiment had a maximum water temperature of 75 C. The CFD model with 1/6-g predicts a maximum water temperature of 88 C with the same heat load and external boundary conditions. This difference in maximum temperature does not greatly affect the structural design of the shield, and demonstrates that it may be possible to use water for a lunar reactor shield.« less

Recurring slope lineae in equatorial regions of Mars

USGS Publications Warehouse

McEwen, Alfred S.; Dundas, Colin M.; Mattson, Sarah S.; Toigo, Anthony D.; Ojha, Lujendra; Wray, James J.; Chojnacki, Matthew; Byrne, Shane; Murchie, Scott L.; Thomas, Nicolas

2014-01-01

The presence of liquid water is a requirement of habitability on a planet. Possible indicators of liquid surface water on Mars include intermittent flow-like features observed on sloping terrains. These recurring slope lineae are narrow, dark markings on steep slopes that appear and incrementally lengthen during warm seasons on low-albedo surfaces. The lineae fade in cooler seasons and recur over multiple Mars years. Recurring slope lineae were initially reported to appear and lengthen at mid-latitudes in the late southern spring and summer and are more common on equator-facing slopes where and when the peak surface temperatures are higher. Here we report extensive activity of recurring slope lineae in equatorial regions of Mars, particularly in the deep canyons of Valles Marineris, from analysis of data acquired by the Mars Reconnaissance Orbiter. We observe the lineae to be most active in seasons when the slopes often face the sun. Expected peak temperatures suggest that activity may not depend solely on temperature. Although the origin of the recurring slope lineae remains an open question, our observations are consistent with intermittent flow of briny water. Such an origin suggests surprisingly abundant liquid water in some near-surface equatorial regions of Mars.

Thermal Desorption Analysis of Effective Specific Soil Surface Area

NASA Astrophysics Data System (ADS)

Smagin, A. V.; Bashina, A. S.; Klyueva, V. V.; Kubareva, A. V.

2017-12-01

A new method of assessing the effective specific surface area based on the successive thermal desorption of water vapor at different temperature stages of sample drying is analyzed in comparison with the conventional static adsorption method using a representative set of soil samples of different genesis and degree of dispersion. The theory of the method uses the fundamental relationship between the thermodynamic water potential (Ψ) and the absolute temperature of drying ( T): Ψ = Q - aT, where Q is the specific heat of vaporization, and a is the physically based parameter related to the initial temperature and relative humidity of the air in the external thermodynamic reservoir (laboratory). From gravimetric data on the mass fraction of water ( W) and the Ψ value, Polyanyi potential curves ( W(Ψ)) for the studied samples are plotted. Water sorption isotherms are then calculated, from which the capacity of monolayer and the target effective specific surface area are determined using the BET theory. Comparative analysis shows that the new method well agrees with the conventional estimation of the degree of dispersion by the BET and Kutilek methods in a wide range of specific surface area values between 10 and 250 m2/g.

Observing the Vertical Dimensions of Singapore's Urban Heat Island

NASA Astrophysics Data System (ADS)

Chow, W. T. L.; Ho, D. X. Q.

2015-12-01

In numerous cities, measurements of urban warmth in most urban heat island (UHI) studies are generally constrained towards surface or near-surface (<2 m above ground) levels across horizontal variations in land use and land cover. However, there has been hitherto limited attention towards the measurement of vertical temperature profiles extending from the urban surface through to the urban boundary layer. Knowledge of these profiles, through how they vary over different local urban morphologies, and develop with respect to synoptic meteorological conditions, are important towards several aspects of UHI research; these include validating modelling urban canopy lapse rate profiles or estimating the growth of urban plumes. In this study, we utilised temperature sensors attached onto remote controlled aerial quadcopter platforms to measure urban temperature and humidity profiles in Singapore, which is a rapidly urbanizing major tropical metropolis. These profiles were measured from the surface to ~100 m above ground level, a height which includes all of the urban canopy and parts of the urban boundary layer. Initial results indicate significant variations in stability measured over different land uses (e.g. urban park, high-rise residential, commercial); these profiles are also temporally dynamic, depending on the time of day and larger-scale weather conditions.

Transient boiling heat transfer in saturated liquid nitrogen and F113 at standard and zero gravity

NASA Technical Reports Server (NTRS)

Oker, E.; Merte, H., Jr.

1973-01-01

Transient and steady state nucleate boiling in saturated LN2 and F113 at standard and near zero gravity conditions were investigated for the horizontal up, vertical and horizontal down orientations of the heating surface. Two distinct regimes of heat transfer mechanisms were observed during the interval from the step increase of power input to the onset of nucleate boiling: the conduction and convection dominated regimes. The time duration in each regime was considerably shorter with LN2 than with F113, and decreased as heat flux increased, as gravity was reduced, and as the orientation was changed from horizontal up to horizontal down. In transient boiling, boiling initiates at a single point following the step increase in power, and then spreads over the surface. The delay time for the inception of boiling at the first site, and the velocity of spread of boiling varies depending upon the heat flux, orientation, body force, surface roughness and liquid properties, and are a consequence of changes in boundary layer temperature levels associated with changes in natural convection. Following the step increase in power input, surface temperature overshoot and undershoot occur before the steady state boiling temperature level is established.

Effective micro-spray cooling for light-emitting diode with graphene nanoporous layers

NASA Astrophysics Data System (ADS)

Keong Lay, Kok; Yew Cheong, Brian Mun; Li Tong, Wei; Tan, Ming Kwang; Hung, Yew Mun

2017-04-01

A graphene nanoplatelet (GNP) coating is utilized as a functionalized surface in enhancing the evaporation rate of micro-spray cooling for light-emitting diodes (LEDs). In micro-spray cooling, water is atomized into micro-sized droplets to reduce the surface energy and to increase the surface area for evaporation. The GNP coating facilitates the effective filmwise evaporation through the attribute of fast water permeation. The oxygenated functional groups of GNPs provide the driving force that initiates the intercalation of water molecules through the carbon nanostructure. The water molecules slip through the frictionless passages between the hydrophobic carbon walls, resulting an effective filmwise evaporation. The enhancement of evaporation leads to an enormous temperature reduction of 61.3 °C. The performance of the LED is greatly enhanced: a maximum increase in illuminance of 25% and an extension of power rating from 9 W to 12 W can be achieved. With the application of GNP coating, the high-temperature region is eliminated while maintaining the LED surface temperature for optimal operation. This study paves the way for employing the effective hybrid spray-evaporation-nanostructure technique in the development of a compact, low-power-consumption cooling system.

Development of ultralow energy (1–10 eV) ion scattering spectrometry coupled with reflection absorption infrared spectroscopy and temperature programmed desorption for the investigation of molecular solids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bag, Soumabha; Bhuin, Radha Gobinda; Methikkalam, Rabin Rajan J.

2014-01-15

Extremely surface specific information, limited to the first atomic layer of molecular surfaces, is essential to understand the chemistry and physics in upper atmospheric and interstellar environments. Ultra low energy ion scattering in the 1–10 eV window with mass selected ions can reveal extremely surface specific information which when coupled with reflection absorption infrared (RAIR) and temperature programmed desorption (TPD) spectroscopies, diverse chemical and physical properties of molecular species at surfaces could be derived. These experiments have to be performed at cryogenic temperatures and at ultra high vacuum conditions without the possibility of collisions of neutrals and background deposition inmore » view of the poor ion intensities and consequent need for longer exposure times. Here we combine a highly optimized low energy ion optical system designed for such studies coupled with RAIR and TPD and its initial characterization. Despite the ultralow collision energies and long ion path lengths employed, the ion intensities at 1 eV have been significant to collect a scattered ion spectrum of 1000 counts/s for mass selected CH{sub 2}{sup +}.« less

Performance Evaluation of an Actuator Dust Seal for Lunar Operation

NASA Technical Reports Server (NTRS)

Delgado, Irebert R.; Gaier, James R.; Handschuh, Michael; Panko, Scott; Sechkar, Ed

2013-01-01

Exploration of extraterrestrial surfaces (e.g. moon, Mars, asteroid) will require durable space mechanisms that will survive potentially dusty surface conditions in addition to the hard vacuum and extreme temperatures of space. Baseline tests with lunar simulant were recently completed at NASA GRC on a new Low-Temperature Mechanism (LTM) dust seal for space actuator application. Following are top-level findings of the tests completed to date in vacuum using NU-LHT-2M lunar-highlands simulant. A complete set of findings are found in the conclusions section.Tests were run at approximately 10-7 torr with unidirectional rotational speed of 39 RPM.Initial break-in runs were performed at atmospheric conditions with no simulant. During the break-in runs, the maximum torque observed was 16.7 lbf-in. while the maximum seal outer diameter temperature was 103F. Only 0.4 milligrams of NU-LHT-2M simulant passed through the sealshaft interface in the first 511,000 cycles while under vacuum despite a chip on the secondary sealing surface.Approximately 650,000 of a planned 1,000,000 cycles were completed in vacuum with NU-LHT-2M simulant.Upon test disassembly NU-LHT-2M was found on the secondary sealing surface.

CFD simulation of simultaneous monotonic cooling and surface heat transfer coefficient

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mihálka, Peter, E-mail: usarmipe@savba.sk; Matiašovský, Peter, E-mail: usarmat@savba.sk

The monotonic heating regime method for determination of thermal diffusivity is based on the analysis of an unsteady-state (stabilised) thermal process characterised by an independence of the space-time temperature distribution on initial conditions. At the first kind of the monotonic regime a sample of simple geometry is heated / cooled at constant ambient temperature. The determination of thermal diffusivity requires the determination rate of a temperature change and simultaneous determination of the first eigenvalue. According to a characteristic equation the first eigenvalue is a function of the Biot number defined by a surface heat transfer coefficient and thermal conductivity ofmore » an analysed material. Knowing the surface heat transfer coefficient and the first eigenvalue the thermal conductivity can be determined. The surface heat transport coefficient during the monotonic regime can be determined by the continuous measurement of long-wave radiation heat flow and the photoelectric measurement of the air refractive index gradient in a boundary layer. CFD simulation of the cooling process was carried out to analyse local convective and radiative heat transfer coefficients more in detail. Influence of ambient air flow was analysed. The obtained eigenvalues and corresponding surface heat transfer coefficient values enable to determine thermal conductivity of the analysed specimen together with its thermal diffusivity during a monotonic heating regime.« less

Thermal effects on domain orientation of tetragonal piezoelectrics

NASA Astrophysics Data System (ADS)

Chang, Wonyoung

Thermal effects on electrical poling or mechanical grinding induced texture in tetragonal lead zirconate titanate (PZT) and lead titanate (PT) have been investigated using ex situ and in situ X-ray diffraction (XRD) with an area detector. According to previous results using ex situ XRD, domain configurations of poled samples after heat-treatment at or higher than the Curie temperature (TC) are similar to that of unpoled samples showing random domain distributions. The texture parameter called multiples of a random distribution (MRD) gradually decreases with increasing depoling temperature. On the other hand, using in situ XRD measurements, it was found that the MRD maximum for soft PZT initially increases with temperature up to approximately 100°C and then falls to unity at temperatures approaching the TC, whereas the MRD of hard PZT and PT initially undergoes a smaller increase or no change. Mechanical strain energy has an apparent effect on domain wall mobility. In contrast with previous results on electrical poling, mechanically-ground PT and soft PZT materials retained strong ferroelastic textures during thermal cycling, even after excursions to temperatures slightly above the TC . For the ground PT, it was found that repeated cycling above T C results in changes in both peak intensity and peak position, whereas the ground soft PZT undergoes the decrease in intensity of the (002) reflection after the first cycle of heating. Residual stresses in the surface region from grinding resulted in domain wall motion and the retention of textures in annealed samples. The research in this thesis demonstrates that the magnitude of loading applied to the sample surface, the speed used for grinding, or the grit size, can greatly affect the grinding induced damage zone and the depoling behavior of piezoelectric ceramics. Among the possible effects of grinding conditions on surface textures, one of particular interest is the effect of mechanical stresses produced during grinding on the texture intensity in the ground surface region. Inhibited depoling of ground PT materials under different loading conditions investigated by in situ texture measurements between room temperature and approximately 100°C above the Curie temperature demonstrates the effects of residual stresses. For all the ground PT and soft PZT samples, there was little or no evidence of time dependence for domain reorientation at the whole annealing temperature range. In addition, both ground PT and soft PZT materials under lower loading conditions showed a gradual depoling behavior with increasing heat treatment temperature, whereas ground materials under higher loading conditions retained relatively strong ferroelastic texture up to temperatures around their respective TC, and then underwent a drastic change in MRD at temperatures above TC. Compared to the ground soft PZT materials, all the ground PT samples still maintained high MRD values after heat treatment above TC.

Biosorption of Cr(VI) by Ceratocystis paradoxa MSR2 Using Isotherm Modelling, Kinetic Study and Optimization of Batch Parameters Using Response Surface Methodology

PubMed Central

Ramalingam, Chidambaram

2015-01-01

This study is focused on the possible use of Ceratocystis paradoxa MSR2 native biomass for Cr(VI) biosorption. The influence of experimental parameters such as initial pH, temperature, biomass dosage, initial Cr(VI) concentration and contact time were optimized using batch systems as well as response surface methodology (RSM). Maximum Cr(VI) removal of 68.72% was achieved, at an optimal condition of biomass dosage 2g L−1, initial Cr(VI) concentration of 62.5 mg L−1 and contact time of 60 min. The closeness of the experimental and the predicted values exhibit the success of RSM. The biosorption mechanism of MSR2 biosorbent was well described by Langmuir isotherm and a pseudo second order kinetic model, with a high regression coefficient. The thermodynamic study also revealed the spontaneity and exothermic nature of the process. The surface characterization using FT-IR analysis revealed the involvement of amine, carbonyl and carboxyl groups in the biosorption process. Additionally, desorption efficiency of 92% was found with 0.1 M HNO3. The Cr(VI) removal efficiency, increased with increase in metal ion concentration, biomass concentration, temperature but with a decrease in pH. The size of the MSR2 biosorbent material was found to be 80 μm using particle size analyzer. Atomic force microscopy (AFM) visualizes the distribution of Cr(VI) on the biosorbent binding sites with alterations in the MSR2 surface structure. The SEM-EDAX analysis was also used to evaluate the binding characteristics of MSR2 strain with Cr(VI) metals. The mechanism of Cr(VI) removal of MSR2 biomass has also been proposed. PMID:25822726

Initial stages of Lutetium growth on Si (111)-7 × 7 probed by STM and core-level photoelectron spectroscopy

NASA Astrophysics Data System (ADS)

Smykalla, Lars; Shukrynau, Pavel; Hietschold, Michael

2017-09-01

The interaction of small amounts of Lutetium with the Si (111)-7 × 7 reconstructed surface was investigated in detail using a combination of Scanning Tunneling Microscopy (STM) and Photoelectron Spectroscopy (XPS and UPS). Various immobile and also fastly moving atoms and nanocluster were found in the initial growth of the Lu/Si interface. Density functional theory calculations and photoelectron spectroscopy results suggest that the most attractive adsorption sites for the Lu atoms are basins around Si rest-atoms and there is no strong interaction between Lu and Si at the initial steps of film growth. However Lu nanocluster could also be found on other adsorption sites which results in a different voltage dependence in STM. Coverage-dependent STM images reveal the growth of a closed Lu metal overlayer by joining of the clusters. The existence of a stoichiometric Lu silicide compound was not detected on the surface in the initial growth for deposition at room temperature.

An Automatic Cloud Mask Algorithm Based on Time Series of MODIS Measurements

NASA Technical Reports Server (NTRS)

Lyapustin, Alexei; Wang, Yujie; Frey, R.

2008-01-01

Quality of aerosol retrievals and atmospheric correction depends strongly on accuracy of the cloud mask (CM) algorithm. The heritage CM algorithms developed for AVHRR and MODIS use the latest sensor measurements of spectral reflectance and brightness temperature and perform processing at the pixel level. The algorithms are threshold-based and empirically tuned. They don't explicitly address the classical problem of cloud search, wherein the baseline clear-skies scene is defined for comparison. Here, we report on a new CM algorithm which explicitly builds and maintains a reference clear-skies image of the surface (refcm) using a time series of MODIS measurements. The new algorithm, developed as part of the Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm for MODIS, relies on fact that clear-skies images of the same surface area have a common textural pattern, defined by the surface topography, boundaries of rivers and lakes, distribution of soils and vegetation etc. This pattern changes slowly given the daily rate of global Earth observations, whereas clouds introduce high-frequency random disturbances. Under clear skies, consecutive gridded images of the same surface area have a high covariance, whereas in presence of clouds covariance is usually low. This idea is central to initialization of refcm which is used to derive cloud mask in combination with spectral and brightness temperature tests. The refcm is continuously updated with the latest clear-skies MODIS measurements, thus adapting to seasonal and rapid surface changes. The algorithm is enhanced by an internal dynamic land-water-snow classification coupled with a surface change mask. An initial comparison shows that the new algorithm offers the potential to perform better than the MODIS MOD35 cloud mask in situations where the land surface is changing rapidly, and over Earth regions covered by snow and ice.

Impervious surfaces and sewer pipe effects on stormwater runoff temperature

NASA Astrophysics Data System (ADS)

Sabouri, F.; Gharabaghi, B.; Mahboubi, A. A.; McBean, E. A.

2013-10-01

The warming effect of the impervious surfaces in urban catchment areas and the cooling effect of underground storm sewer pipes on stormwater runoff temperature are assessed. Four urban residential catchment areas in the Cities of Guelph and Kitchener, Ontario, Canada were evaluated using a combination of runoff monitoring and modelling. The stormwater level and water temperature were monitored at 10 min interval at the inlet of the stormwater management ponds for three summers 2009, 2010 and 2011. The warming effect of the ponds is also studied, however discussed in detail in a separate paper. An artificial neural network (ANN) model for stormwater temperature was trained and validated using monitoring data. Stormwater runoff temperature was most sensitive to event mean temperature of the rainfall (EMTR) with a normalized sensitivity coefficient (Sn) of 1.257. Subsequent levels of sensitivity corresponded to the longest sewer pipe length (LPL), maximum rainfall intensity (MI), percent impervious cover (IMP), rainfall depth (R), initial asphalt temperature (AspT), pipe network density (PND), and rainfall duration (D), respectively. Percent impervious cover of the catchment area (IMP) was the key parameter that represented the warming effect of the paved surfaces; sensitivity analysis showed IMP increase from 20% to 50% resulted in runoff temperature increase by 3 °C. The longest storm sewer pipe length (LPL) and the storm sewer pipe network density (PND) are the two key parameters that control the cooling effect of the underground sewer system; sensitivity analysis showed LPL increase from 345 to 966 m, resulted in runoff temperature drop by 2.5 °C.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wereszczak, A.A.; Ferber, M.K.; Kirkland, T.P.

Several yttria-fluxed, hot-isostatically pressed (HIPed) silicon nitrides have been tensile creep tested at temperatures representative of gas turbine engines. Creep and oxidation assisted damage mechanisms concurrently evolve when these materials are tested at high temperatures and low stresses (i.e., long exposure times at temperature). Atmospheric creep testing results in creation of oxygen and yttrium gradients across the radial dimension. High concentrations of oxygen and yttrium coincide with dense populations of lenticular-shaped cavities near the surface of crept specimens. The center of the tensile specimens was devoid of oxygen or yttrium; in addition, lenticular cavities were rare. The gradient in lenticular-cavitymore » concentration is coincident with the oxygen and yttrium gradients. Stress corrosion cracking (SCC) also occurs in these HIPed silicon nitrides when they are subjected to stress at high temperatures in ambient air. The size of this damage zone increases when the temperature is higher and/or the applied stress is lower. Stress-corrosion cracking initiates at the surface of the tensile specimen and advances radially inwards. What nucleates SCC has not yet been identified, but it is believed to result from a stress-concentrator (e.g., machining damage) at the surface and its growth is a result of coalescence of microcracks and cavities. The higher concentration of oxygen and yttrium in the grain boundaries near the specimen`s surface lessens the local high temperature mechanical integrity; this is believed to be associated with the growth of the SCC zone. This SCC zone continues to grow in size during tensile loading until it reaches a critical size which causes fracture.« less

Atmospheric model development in support of SEASAT. Volume 2: Analysis models

NASA Technical Reports Server (NTRS)

Langland, R. A.

1977-01-01

As part of the SEASAT program of NASA, two sets of analysis programs were developed for the Jet Propulsion Laboratory. One set of programs produce 63 x 63 horizontal mesh analyses on a polar stereographic grid. The other set produces 187 x 187 third mesh analyses. The parameters analyzed include sea surface temperature, sea level pressure and twelve levels of upper air temperature, height and wind analyses. The analysis output is used to initialize the primitive equation forecast models.

The validation of AIRS retrievals

NASA Technical Reports Server (NTRS)

Fetzer, Eric J.; Olsen, Edward T.; Chen, Luke L.; Hagan, Denise E.; Fishbein, Evan; McMillin, Larry; Zhou, Jiang; McMillan, Wallace W.

2003-01-01

The initial validation of Atmospheric Infrared Sounder (SIRS) experiment retrievals were completed in August 2003 as part of public release of version 3.0 data. The associated analyses are reported at http://daac.gsfc.nasa.gov/atmodyn/airs/, where data may be accessed. Here we describe some of those analyses, with an emphasis on cloud cleared radiances, atmospheric temperature profiles, sea surface temperature, total water vapor and atmospheric water vapor profiles. The results are applicable over ocean in the latitude band +/-40 degrees.

Analysis of a Radioisotope Thermal Rocket Engine

NASA Technical Reports Server (NTRS)

Machado-Rodriguez, Jonathan P.; Landis, Geoffrey A.

2017-01-01

The Triton Hopper is a concept for a vehicle to explore the surface of Neptunes moon Triton, which uses a radioisotope heated rocket engine and in-situ propellant acquisition. The initial Triton Hopper conceptual design stores pressurized Nitrogen in a spherical tank to be used as the propellant. The aim of the research was to investigate the benefits of storing propellant at ambient temperature and heating it through a thermal block during engine operation, as opposed to storing gas at a high temperature.

The New Horizons Radio Science Experiment: Performance and Measurements of Pluto's Atmospheric Structure, Surface Pressure, and Surface Temperature

NASA Astrophysics Data System (ADS)

Linscott, I.; Hinson, D. P.; Bird, M. K.; Stern, A.; Weaver, H. A., Jr.; Olkin, C.; Young, L. A.; Ennico Smith, K.

2015-12-01

The New Horizons (NH) spacecraft payload contained the Radio Science Experiment (REX) for determining key characteristics of Pluto and Charon during the July 14, 2015, flyby of the Pluto/Charon system. The REX flight equipment augments the NH X-band radio transceiver by providing a high precision, narrow band recording of high power uplink transmissions from Earth stations, as well as a record of broadband radiometric power. This presentation will review the performance and initial results of two high- priority observations. First, REX received two pair of 20-kW signals, one pair per polarization, transmitted from the DSN at 4.2-cm wavelength during a diametric radio occultation by Pluto. REX recorded these uplink signals and determined precise measurement of the surface pressure, the temperature structure of the lower atmosphere, and the surface radius of Pluto. The ingress portion of one polarization was played back from the spacecraft in July and processed to obtain the pressure and temperature structure of Pluto's atmosphere. Second, REX measured the thermal emission from Pluto at 4.2- cm wavelength during two linear scans across the disk at close range when both the dayside and the night side are visible. Both scans extend from limb to limb with a resolution of one-tenth Pluto's disk and temperature resolution of 0.1 K. Occultation and radiometric temperature results presented here will encompass additional data scheduled for playback in September.

Fractography of the high temperature hydrogen attack of a medium carbon steel

NASA Technical Reports Server (NTRS)

Melson, H. G.; Moorhead, R. D.

1975-01-01

Microscopic fracture processes were studied which are associated with hydrogen attack of a medium carbon steel in a well-controlled, high-temperature, high-purity hydrogen environment. Exposure to a hydrogen pressure and temperature of 3.5 MN/m2 and 575 C was found to degrade room temperature tensile properties with increasing exposure time. After 408 hr, yield and ultimate strengths were reduced by more than 40 percent and elongation was reduced to less than 2 percent. Initial fissure formation was found to be associated with manganese rich particles, most probably manganese oxide, aligned in the microstructure during the rolling operation. Fissure growth was found to be associated with a reduction in carbide content of the microstructure and was inhibited by the depletion of carbon. The interior surfaces of sectioned fissures or bubbles exhibit both primary and secondary cracking by intergranular separation. The grain surfaces were rough and rounded, suggesting a diffusion-associated separation process. Specimens that failed at room temperature after exposure to hydrogen were found to exhibit mixed mode fracture having varying amounts of intergranular separation, dimple formation, and cleavage, depending on exposure time.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaRue, Jerry; Krejci, Ondrej; Yu, Liang

Here, the direct elucidation of the reaction pathways in heterogeneous catalysis has been challenging due the short-lived nature of reaction intermediates. Here, we directly measured on ultrafast timescales the initial hydrogenation steps of adsorbed CO on a Ru catalyst surface, which is known as the bottleneck reaction in syngas and CO 2 reforming processes. We initiated the hydrogenation of CO with an ultrafast laser temperature jump and probed transient changes in the electronic structure using real-time x-ray spectroscopy. In combination with theoretical simulations, we verified the formation of CHO during CO hydrogenation.

Methylene migration and coupling on a non-reducible metal oxide: The reaction of dichloromethane on stoichiometric α-Cr 2O 3(0001)

DOE PAGES

Dong, Yujung; Brooks, John D.; Chen, Tsung-Liang; ...

2014-09-17

The reaction of CH 2Cl 2 over the nearly-stoichiometric α-Cr 2O 3(0001) surface produces gas phase ethylene, methane and surface chlorine adatoms. The reaction is initiated by the decomposition of CH 2Cl 2 into surface methylene and chlorine. Photoemission indicates that surface cations are the preferred binding sites for both methylene and chlorine adatoms. Two reaction channels are observed for methylene coupling to ethylene in temperature-programmed desorption (TPD). A desorption-limited, low-temperature route is attributed to two methylenes bound at a single site. The majority of ethylene is produced by a reaction-limited process involving surface migration (diffusion) of methylene as themore » rate-limiting step. DFT calculations indicate the surface diffusion mechanism is mediated by surface oxygen anions. The source of hydrogen for methane formation is adsorbed background water. Chlorine adatoms produced by the dissociation of CH 2Cl 2 deactivate the surface by simple site-blocking of surface Cr 3+ sites. Finally, a comparison of experiment and theory shows that DFT provides a better description of the surface chemistry of the carbene intermediate than DFT+U using reported parameters for a best representation of the bulk electronic properties of α-Cr 2O 3.« less

Decadal climate simulations using the Climate Forecast System (CFS) coupled to the SSiB2 land surface model

NASA Astrophysics Data System (ADS)

De Sales, F.; Xue, Y.; Marx, L.; Ek, M. B.

2016-12-01

The Simplified Simple Biophysical version 2 (SSiB2) model was implemented in the NCEP Climate Forecast System (CFS) for two 30-yr simulations. One simulation was initialized from CFS reanalysis data (EXP1), and the other from a 10-yr spin-up run (EXP2), in which the ocean model was allowed to run freely while the atmosphere and land surface were maintained constant to adjust inconsistencies in the initial conditions. EXP2 also includes an update in the SSiB2's average soil water potential calculation. The material presented highlights the model's performance in predicting spatial and temporal variability of monthly precipitation and surface temperature and aims at determining the optimum configuration for longer simulations. In general, the model is able to reproduce the main features of large-scale precipitation, with spatial correlation (scorr) and RMSE of 0.8 and 1.4 mm day-1, respectively. A split ITCZ pattern is observed in the Pacific and Indian oceans, which results in dry biases along the equator and wet-bias bands to its north and south. Positive biases are also observed in the Atlantic ITCZ. The model generates consistent surface temperature climatology (scorr > 0.9, RMSE= 2.3°C). Warm biases are observed especially over southern Asia during summer. Both experiments produce similar precipitation climatology patterns with similar biases. EXP2, however, improves the temperature simulation by reducing the global bias by 48% and 26% during boreal winter and summer, respectively; and improves the temperature decadal variability for many areas. Moreover, EXP2 generates a better continental surface air warming trend. In the attempt to improve the precipitation decadal variability in the simulations, remotely-sensed LAI and vegetation cover fraction have been implemented in the CFS/SSiB2 to substitute the look-up table originally used in EXP1 and 2. The satellite vegetation data has been processed into global monthly maps which are continuous updated throughout the simulation. Results from this experiment will also be presented.

Strain Evolution of Annealed Hydrogen-Implanted (0001) Sapphire

NASA Astrophysics Data System (ADS)

Wong, Christine Megan

Exfoliation is a technique used to remove a thin, uniform layer of material from the bulk that involves the annealing of hydrogen ion-implanted materials in order to initiate defect nucleation and growth leading to guided crack propagation. This study presents an investigation into the annealing process required to initiate blistering (an essential precursor to exfoliation) in (0001) sapphire implanted at room temperature with hydrogen ions. Triple axis x-ray diffraction was used to characterize the evolution of the implanted layer for single crystal (0001) sapphire substrates implanted at room temperature at 360 keV with either a 5x1016 cm -2 or 8x1016 cm-2 dose of hydrogen ions. A simulation of the ion distribution in TRIM estimated that the projected range and thickness of the implanted layer for both doses was approximately 2.2 mum. Following implantation, the implanted sapphire was annealed using a two-step annealing procedure. The first step was performed at a lower temperature, ideally to nucleate and coarsen defects. Temperatures investigated ranged from 550 - 650 °C. The second step was performed at a higher temperature (800 °C) to induce further defect coarsening and surface blistering. After all annealing steps, triple axis o/2theta and o scans were taken to observe any changes in the diffraction profile - namely, any reduction in the amplitude and shift in the location of the fringes associated with strain in the crystal - which would correlate with defect growth and nucleation. It was found that significant strain fringe reduction first occurred after annealing at 650 °C for 8 hours for both doses; however, it was not clear whether or not this strain reduction was due primarily to hydrogen diffusion or to recovery of other defects induced during the ion implantation. The o/2theta curves were then fit using Bede RADS in order to quantify the strain within the crystal and confirm the reduction of the strained layer within the crystal. Finally, Nomarski optical images of the sample surfaces were taken after each step to observe any visual changes or blistering that might have occurred. These optical images showed that the strain reduction observed using XRD did not correlate to blistering, as no blisters were observed in any of the optical images. Experimental results showed that at temperatures below 650 °C, no significant strain reduction occurs in hydrogen ion implanted (0001) sapphire. It has also been determined that for (0001) sapphire implanted at room temperature, it was not possible to produce surface blistering after a two-step annealing process at 650 °C and 800 °C, although significant strain reduction did occur, and ? scans showed peak broadening with subsequent annealing, indicating increasing mosaicity and potential defect nucleation. This was in contrast to previous findings that asserted that for sapphire annealed at 650 °C, surface blistering was observable. As previous findings were based on sapphire implanted at elevated temperatures, this may imply that the sapphire substrate reaches a higher temperature than expected during such implantation processes, which may account for the capability for surface blistering at a lower temperature. Conversely, for room temperature ion implantation, temperatures greater than 800 °C may be necessary to first nucleate hydrogen platelet defects and then produce surface blistering.

Hugoniot temperatures and melting of tantalum under shock compression determined by optical pyrometry

NASA Astrophysics Data System (ADS)

Dai, Chengda; Hu, Jianbo; Tan, Hua

2009-08-01

LiF single crystal was used as transparent window (anvil) to tamp the shock-induced free surface expansion of Ta specimen, and the Ta/LiF interface temperature was measured under shock compression using optical pyrometry technique. The shock temperatures and/or melting temperatures of Ta up to ˜400 GPa were extracted from the observed interface temperatures based on the Tan-Ahrens' model for one-dimensional heat conduction across metal/window ideal interface in which initial melting and subsequent solidification were considered under shock loading. The obtained data within the experimental uncertainties are consistent with the results from high-pressure sound velocity measurements. The temperature of the partial melting on Ta Hugoniot is estimated to be ˜9700 K at 300 GPa, supported by available results from theoretical calculations.

Phlogopite Decomposition, Water, and Venus

NASA Technical Reports Server (NTRS)

Johnson, N. M.; Fegley, B., Jr.

2005-01-01

Venus is a hot and dry planet with a surface temperature of 660 to 740 K and 30 parts per million by volume (ppmv) water vapor in its lower atmosphere. In contrast Earth has an average surface temperature of 288 K and 1-4% water vapor in its troposphere. The hot and dry conditions on Venus led many to speculate that hydrous minerals on the surface of Venus would not be there today even though they might have formed in a potentially wetter past. Thermodynamic calculations predict that many hydrous minerals are unstable under current Venusian conditions. Thermodynamics predicts whether a particular mineral is stable or not, but we need experimental data on the decomposition rate of hydrous minerals to determine if they survive on Venus today. Previously, we determined the decomposition rate of the amphibole tremolite, and found that it could exist for billions of years at current surface conditions. Here, we present our initial results on the decomposition of phlogopite mica, another common hydrous mineral on Earth.

Condensation on Highly Superheated Surfaces: Unstable Thin Films in a Wickless Heat Pipe

NASA Astrophysics Data System (ADS)

Kundan, Akshay; Nguyen, Thao T. T.; Plawsky, Joel L.; Wayner, Peter C.; Chao, David F.; Sicker, Ronald J.

2017-03-01

A wickless heat pipe was operated on the International Space Station to provide a better understanding of how the microgravity environment might alter the physical and interfacial forces driving evaporation and condensation. Traditional heat pipes are divided into three zones: evaporation at the heated end, condensation at the cooled end, and intermediate or adiabatic in between. The microgravity experiments reported herein show that the situation may be dramatically more complicated. Beyond a threshold heat input, there was a transition from evaporation at the heated end to large-scale condensation, even as surface temperatures exceeded the boiling point by 160 K. The hotter the surface, the more vapor was condensed onto it. The condensation process at the heated end is initiated by thickness and temperature disturbances in the thin liquid film that wet the solid surface. Those disturbances effectively leave the vapor "superheated" in that region. Condensation is amplified and sustained by the high Marangoni stresses that exist near the heater and that drive liquid to cooler regions of the device.

Development of a laser-induced heat flux technique for measurement of convective heat transfer coefficients in a supersonic flowfield

NASA Technical Reports Server (NTRS)

Porro, A. Robert; Keith, Theo G., Jr.; Hingst, Warren R.; Chriss, Randall M.; Seablom, Kirk D.

1991-01-01

A technique is developed to measure the local convective heat transfer coefficient on a model surface in a supersonic flow field. The technique uses a laser to apply a discrete local heat flux at the model test surface, and an infrared camera system determines the local temperature distribution due to heating. From this temperature distribution and an analysis of the heating process, a local convective heat transfer coefficient is determined. The technique was used to measure the load surface convective heat transfer coefficient distribution on a flat plate at nominal Mach numbers of 2.5, 3.0, 3.5, and 4.0. The flat plate boundary layer initially was laminar and became transitional in the measurement region. The experimental results agreed reasonably well with theoretical predictions of convective heat transfer of flat plate laminar boundary layers. The results indicate that this non-intrusive optical measurement technique has the potential to obtain high quality surface convective heat transfer measurements in high speed flowfields.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Donald, Scott B.; Siekhaus, Wigbert J.; Nelson, Art J.

X-ray photoelectron spectroscopy in combination with secondary ion mass spectrometry depth profiling were used to investigate the surface and interfacial chemistry of C + ion implanted polycrystalline uranium subsequently oxidized in air for over 10 years at ambient temperature. The original implantation of 33 keV C + ions into U 238 with a dose of 4.3 × 10 17 cm –3 produced a physically and chemically modified surface layer that was characterized and shown to initially prevent air oxidation and corrosion of the uranium after 1 year in air at ambient temperature. The aging of the surface and interfacial layersmore » were examined by using the chemical shift of the U 4f, C 1s, and O 1s photoelectron lines. In addition, valence band spectra were used to explore the electronic structure of the aged carbide surface and interface layer. Moreover, the time-of-flight secondary ion mass spectrometry depth profiling results for the aged sample confirmed an oxidized uranium carbide layer over the carbide layer/U metal interface.« less

A laser-induced heat flux technique for convective heat transfer measurements in high speed flows

NASA Technical Reports Server (NTRS)

Porro, A. R.; Keith, T. G., Jr.; Hingst, W. R.

1991-01-01

A technique is developed to measure the local convective heat transfer coefficient on a model surface in a supersonic flow field. The technique uses a laser to apply a discrete local heat flux at the model test surface, and an infrared camera system determines the local temperature distribution due to the heating. From this temperature distribution and an analysis of the heating process, a local convective heat transfer coefficient is determined. The technique was used to measure the local surface convective heat transfer coefficient distribution on a flat plate at nominal Mach numbers of 2.5, 3.0, 3.5, and 4.0. The flat plate boundary layer initially was laminar and became transitional in the measurement region. The experimentally determined convective heat transfer coefficients were generally higher than the theoretical predictions for flat plate laminar boundary layers. However, the results indicate that this nonintrusive optical measurement technique has the potential to measure surface convective heat transfer coefficients in high speed flow fields.

A laser-induced heat flux technique for convective heat transfer measurements in high speed flows

NASA Technical Reports Server (NTRS)

Porro, A. R.; Keith, T. G., Jr.; Hingst, W. R.

1991-01-01

A technique is developed to measure the local convective heat transfer coefficient on a model surface in a supersonic flow field. The technique uses a laser to apply a discrete local heat flux at the model test surface, and an infrared camera system determines the local temperature distribution due to the heating. From this temperature distribution and an analysis of the heating process, a local convective heat transfer coefficient is determined. The technique was used to measure the local surface convective heat transfer coefficient distribution on a flat plate at nominal Mach numbers of 2.5, 3.0, 3.5, and 4.0. The flat plate boundary layer initially was laminar and became transitional in the measurement region. The experimentally determined convective heat transfer coefficients were generally higher than the theoretical predictions for flat plate laminar boundary layers. However, the results indicate that this nonintrusive optical measurement technique has the potential to measure surface convective heat transfer coefficients in high-speed flowfields.

Laser-heated rotating specimen autoignition test

NASA Technical Reports Server (NTRS)

Au, A. C.

1988-01-01

Specimens of 440 C steel were rotated in a chamber pressurized with oxygen gas and heated with a 5-kW CO2 laser to determine the temperature required for autoignition to occur. Tests included exposures of static and rotating (25,000 rpm) specimens in oxygen pressurized to 5.51 MPa, and with focused laser fluences of more than 3.5 billion W/sq m. Specimen surface temperatures were monitored with a scanning infrared camera. Temperature measurement difficulties were experienced due to a problem with internal reflection inside the test chamber; however, posttest specimen examinations confirmed that surface melt (1371 C) was achieved in several tests. No sustained combustion was initiated in any rotating specimen. One static specimen was ignited. Results indicated that conditions necessary for autoignition of 440 C steel are more dependent on specimen geometry and available heat removal mechanisms. Sustained combustion occurred in the ignited static specimen with an estimated 130 C/sec cooling rate due to conduction. The rotating specimens could not sustain combustion due to a greater conductive/convective cooling rate of about 4000 C/sec and ejection of molten material. These results were applied to the Space Shuttle Main Engine (SSME) oxygen turbopump bearings to conclude that the LOX-cooled 440 C steel bearings cannot sustain combustion initiated by skidding friction.

Hydroxide ion-mediated synthesis of monodisperse dopamine-melanin nanospheres.

PubMed

Cho, Soojeong; Kim, Shin-Hyun

2015-11-15

Dopamine-melanin nanospheres are promising materials for photoprotection, structural coloration, and thermoregulation due to their unusual optical and chemical properties. Here, we report the experimental parameters which influence size of dopamine-melanin nanospheres and uniformity. Dopamine precursors are oxidatively polymerized in basic aqueous medium. Therefore, concentration of hydroxide ions significantly influences reaction rate and size of nanospheres. To investigate the effect of hydroxide ions, we adjust three different parameters which affect pH of medium: concentration of sodium hydroxide and dopamine hydrochloride, and reaction temperature. At constant temperature, concentration of hydroxide ions is linearly proportional to initial reaction rates which determine the number of nuclei for nanosphere growth. Temperature alters not only initial reaction rate but also diffusivity of molecules, leading to deviation from the relation between the reaction rate and the number of nuclei. The diameter of dopamine-melanin nanospheres can be readily controlled in a range of 80-490nm through adjusting concentration of dopamine precursor, while maintaining uniform-size distribution and dispersion stability. The synthesized nanospheres are analyzed to confirm the chemical structure, which is composed of approximately 6 indole units. Moreover, surface and chemical properties of the nanospheres are characterized to provide valuable information for surface modification and application. Copyright © 2015 Elsevier Inc. All rights reserved.

Tectonic predictions with mantle convection models

NASA Astrophysics Data System (ADS)

Coltice, Nicolas; Shephard, Grace E.

2018-04-01

Over the past 15 yr, numerical models of convection in Earth's mantle have made a leap forward: they can now produce self-consistent plate-like behaviour at the surface together with deep mantle circulation. These digital tools provide a new window into the intimate connections between plate tectonics and mantle dynamics, and can therefore be used for tectonic predictions, in principle. This contribution explores this assumption. First, initial conditions at 30, 20, 10 and 0 Ma are generated by driving a convective flow with imposed plate velocities at the surface. We then compute instantaneous mantle flows in response to the guessed temperature fields without imposing any boundary conditions. Plate boundaries self-consistently emerge at correct locations with respect to reconstructions, except for small plates close to subduction zones. As already observed for other types of instantaneous flow calculations, the structure of the top boundary layer and upper-mantle slab is the dominant character that leads to accurate predictions of surface velocities. Perturbations of the rheological parameters have little impact on the resulting surface velocities. We then compute fully dynamic model evolution from 30 and 10 to 0 Ma, without imposing plate boundaries or plate velocities. Contrary to instantaneous calculations, errors in kinematic predictions are substantial, although the plate layout and kinematics in several areas remain consistent with the expectations for the Earth. For these calculations, varying the rheological parameters makes a difference for plate boundary evolution. Also, identified errors in initial conditions contribute to first-order kinematic errors. This experiment shows that the tectonic predictions of dynamic models over 10 My are highly sensitive to uncertainties of rheological parameters and initial temperature field in comparison to instantaneous flow calculations. Indeed, the initial conditions and the rheological parameters can be good enough for an accurate prediction of instantaneous flow, but not for a prediction after 10 My of evolution. Therefore, inverse methods (sequential or data assimilation methods) using short-term fully dynamic evolution that predict surface kinematics are promising tools for a better understanding of the state of the Earth's mantle.

A systematic study of atmospheric pressure chemical vapor deposition growth of large-area monolayer graphene.

PubMed

Liu, Lixin; Zhou, Hailong; Cheng, Rui; Chen, Yu; Lin, Yung-Chen; Qu, Yongquan; Bai, Jingwei; Ivanov, Ivan A; Liu, Gang; Huang, Yu; Duan, Xiangfeng

2012-01-28

Graphene has attracted considerable interest as a potential material for future electronics. Although mechanical peel is known to produce high quality graphene flakes, practical applications require continuous graphene layers over a large area. The catalyst-assisted chemical vapor deposition (CVD) is a promising synthetic method to deliver wafer-sized graphene. Here we present a systematic study on the nucleation and growth of crystallized graphene domains in an atmospheric pressure chemical vapor deposition (APCVD) process. Parametric studies show that the mean size of the graphene domains increases with increasing growth temperature and CH 4 partial pressure, while the density of domains decreases with increasing growth temperature and is independent of the CH 4 partial pressure. Our studies show that nucleation of graphene domains on copper substrate is highly dependent on the initial annealing temperature. A two-step synthetic process with higher initial annealing temperature but lower growth temperature is developed to reduce domain density and achieve high quality full-surface coverage of monolayer graphene films. Electrical transport measurements demonstrate that the resulting graphene exhibits a high carrier mobility of up to 3000 cm 2 V -1 s -1 at room temperature.

Rapid warming of the world's lakes: Interdecadal variability and long-term trends from 1910-2009 using in situ and remotely sensed data

NASA Astrophysics Data System (ADS)

Lenters, J. D.; Read, J. S.; Sharma, S.; O'Reilly, C.; Hampton, S. E.; Gray, D.; McIntyre, P. B.; Hook, S. J.; Schneider, P.; Soylu, M. E.; Barabás, N.; Lofton, D. D.

2014-12-01

Global and regional changes in climate have important implications for terrestrial and aquatic ecosystems. Recent studies, for example, have revealed significant warming of inland water bodies throughout the world. To better understand the global patterns, physical mechanisms, and ecological implications of lake warming, an initiative known as the "Global Lake Temperature Collaboration" (GLTC) was started in 2010, with the objective of compiling and analyzing lake temperature data from numerous satellite and in situ records dating back at least 20-30 years. The GLTC project has now assembled data from over 300 lakes, with some in situ records extending back more than 100 years. Here, we present an analysis of the long-term warming trends, interdecadal variability, and a direct comparison between in situ and remotely sensed lake surface temperature for the 3-month summer period July-September (January-March for some lakes). The overall results show consistent, long-term trends of increasing summer-mean lake surface temperature across most but not all sites. Lakes with especially long records show accelerated warming in the most recent two to three decades, with almost half of the lakes warming at rates in excess of 0.5 °C per decade during the period 1985-2009, and a few even exceeding 1.0 °C per decade. Both satellite and in situ data show a similar distribution of warming trends, and a direct comparison at lake sites that have both types of data reveals a close correspondence in mean summer water temperature, interannual variability, and long-term trends. Finally, we examine standardized lake surface temperature anomalies across the full 100-year period (1910-2009), and in conjunction with similar timeseries of air temperature. The results reveal a close correspondence between summer air temperature and lake surface temperature on interannual and interdecadal timescales, but with many lakes warming more rapidly than the ambient air temperature over 25- to 100-year periods.

Updated global soil map for the Weather Research and Forecasting model and soil moisture initialization for the Noah land surface model

NASA Astrophysics Data System (ADS)

DY, C. Y.; Fung, J. C. H.

2016-08-01

A meteorological model requires accurate initial conditions and boundary conditions to obtain realistic numerical weather predictions. The land surface controls the surface heat and moisture exchanges, which can be determined by the physical properties of the soil and soil state variables, subsequently exerting an effect on the boundary layer meteorology. The initial and boundary conditions of soil moisture are currently obtained via National Centers for Environmental Prediction FNL (Final) Operational Global Analysis data, which are collected operationally in 1° by 1° resolutions every 6 h. Another input to the model is the soil map generated by the Food and Agriculture Organization of the United Nations - United Nations Educational, Scientific and Cultural Organization (FAO-UNESCO) soil database, which combines several soil surveys from around the world. Both soil moisture from the FNL analysis data and the default soil map lack accuracy and feature coarse resolutions, particularly for certain areas of China. In this study, we update the global soil map with data from Beijing Normal University in 1 km by 1 km grids and propose an alternative method of soil moisture initialization. Simulations of the Weather Research and Forecasting model show that spinning-up the soil moisture improves near-surface temperature and relative humidity prediction using different types of soil moisture initialization. Explanations of that improvement and improvement of the planetary boundary layer height in performing process analysis are provided.

Plane wave density functional molecular dynamics study of exothermic reactions of Al/CuO thermites

NASA Astrophysics Data System (ADS)

Oloriegbe, Suleiman; Sewell, Thomas; Chen, Zhen; Jiang, Shan; Gan, Yong

2014-03-01

Exothermic reactions between nanosize aluminum (Al) and copper oxide (CuO) structures are of current interest because of their high reaction enthalpy and energy density which exceed those of traditional monomolecular energetic compounds such as TNT, RDX, and HMX. In this work, molecular dynamics simulations with forces obtained from plane wave density functional theory are used to investigate the atomic-scale and electronic processes that occur during the fast thermite reactions between Al and CuO nanostructures under adiabatic conditions. Aluminum surfaces in contact with O-exposed and Cu-exposed CuO surfaces are studied. Starting from initial temperature T = 800 K, we have observed: faster chemical reaction at the oxygen-rich interface during the initial 0.5 ps, linear temperature rise, and fast oxygen diffusion into the Al region with the rate 1.87 X 10-3 cm2/s. The density-derived electrostatic and chemical method is used to evaluate the net atomic charges and charge transfer during the important redox processes. High charge density around the oxygen-exposed interface may be responsible for the faster initial reactions at that interface. The overall reaction rate, determined using the time evolution of Cu-O charge orbital overlap population, is approximately first order.

On retrodictions of global mantle flow with assimilated surface velocities

NASA Astrophysics Data System (ADS)

Colli, Lorenzo; Bunge, Hans-Peter; Schuberth, Bernhard S. A.

2016-04-01

Modeling past states of Earth's mantle and relating them to geologic observations such as continental-scale uplift and subsidence is an effective method for testing mantle convection models. However, mantle convection is chaotic and two identical mantle models initialized with slightly different temperature fields diverge exponentially in time until they become uncorrelated, thus limiting retrodictions (i.e., reconstructions of past states of Earth's mantle obtained using present information) to the recent past. We show with 3-D spherical mantle convection models that retrodictions of mantle flow can be extended significantly if knowledge of the surface velocity field is available. Assimilating surface velocities produces in some cases negative Lyapunov times (i.e., e-folding times), implying that even a severely perturbed initial condition may evolve toward the reference state. A history of the surface velocity field for Earth can be obtained from past plate motion reconstructions for time periods of a mantle overturn, suggesting that mantle flow can be reconstructed over comparable times.

On retrodictions of global mantle flow with assimilated surface velocities

NASA Astrophysics Data System (ADS)

Colli, Lorenzo; Bunge, Hans-Peter; Schuberth, Bernhard S. A.

2015-10-01

Modeling past states of Earth's mantle and relating them to geologic observations such as continental-scale uplift and subsidence is an effective method for testing mantle convection models. However, mantle convection is chaotic and two identical mantle models initialized with slightly different temperature fields diverge exponentially in time until they become uncorrelated, thus limiting retrodictions (i.e., reconstructions of past states of Earth's mantle obtained using present information) to the recent past. We show with 3-D spherical mantle convection models that retrodictions of mantle flow can be extended significantly if knowledge of the surface velocity field is available. Assimilating surface velocities produces in some cases negative Lyapunov times (i.e., e-folding times), implying that even a severely perturbed initial condition may evolve toward the reference state. A history of the surface velocity field for Earth can be obtained from past plate motion reconstructions for time periods of a mantle overturn, suggesting that mantle flow can be reconstructed over comparable times.

Activated recombinative desorption: A potential component in mechanisms of spacecraft glow

NASA Technical Reports Server (NTRS)

Cross, J. B.

1985-01-01

The concept of activated recombination of atomic species on surfaces can explain the production of vibrationally and translationally excited desorbed molecular species. Equilibrium statistical mechanics predicts that the molecular quantum state distributions of desorbing molecules is a function of surface temperature only when the adsorption probability is unity and independent of initial collision conditions. In most cases, the adsorption probability is dependent upon initial conditions such as collision energy or internal quantum state distribution of impinging molecules. From detailed balance, such dynamical behavior is reflected in the internal quantum state distribution of the desorbing molecule. This concept, activated recombinative desorption, may offer a common thread in proposed mechanisms of spacecraft glow. Using molecular beam techniques and equipment available at Los Alamos, which includes a high translational energy 0-atom beam source, mass spectrometric detection of desorbed species, chemiluminescence/laser induced fluorescence detection of electronic and vibrationally excited reaction products, and Auger detection of surface adsorbed reaction products, a fundamental study of the gas surface chemistry underlying the glow process is proposed.

Synthesis of surface-anchored DNA-polymer bioconjugates using reversible addition-fragmentation chain transfer polymerization.

PubMed

He, Peng; He, Lin

2009-07-13

We report here an approach to grafting DNA-polymer bioconjugates on a planar solid support using reversible addition-fragmentation chain transfer (RAFT) polymerization. In particular, a trithiocarbonate compound as the RAFT chain transfer agent (CTA) is attached to the distal point of a surface-immobilized oligonucleotide. Initiation of RAFT polymerization leads to controlled growth of polymers atop DNA molecules on the surface. Growth kinetics of poly(monomethoxy-capped oligo(ethylene glycol) methacrylate) atop DNA molecules is investigated by monitoring the change of polymer film thickness as a function of reaction time. The reaction conditions, including the polymerization temperature, the initiator concentration, the CTA surface density, and the selection of monomers, are varied to examine their impacts on the grafting efficiency of DNA-polymer conjugates. Comparing to polymer growth atop small molecules, the experimental results suggest that DNA molecules significantly accelerate polymer growth, which is speculated as a result of the presence of highly charged DNA backbones and purine/pyrimidine moieties surrounding the reaction sites.

Anomalous behavior in temporal evolution of ripple wavelength under medium energy Ar{sup +}-ion bombardment on Si: A case of initial wavelength selection

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garg, Sandeep Kumar; Inter-University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi 110 067; Cuerno, Rodolfo

We have studied the early stage dynamics of ripple patterns on Si surfaces, in the fluence range of 1–3 × 10{sup 18} ions cm{sup −2}, as induced by medium energy Ar{sup +}-ion irradiation at room temperature. Under our experimental conditions, the ripple evolution is found to be in the linear regime, while a clear decreasing trend in the ripple wavelength is observed up to a certain time (fluence). Numerical simulations of a continuum model of ion-sputtered surfaces suggest that this anomalous behavior is due to the relaxation of the surface features of the experimental pristine surface during the initial stage of patternmore » formation. The observation of this hitherto unobserved behavior of the ripple wavelength seems to have been enabled by the use of medium energy ions, where the ripple wavelengths are found to be order(s) of magnitude larger than those at lower ion energies.« less

Attractive interaction between Mn atoms on the GaAs(110) surface observed by scanning tunneling microscopy.

PubMed

Taninaka, Atsushi; Yoshida, Shoji; Kanazawa, Ken; Hayaki, Eiko; Takeuchi, Osamu; Shigekawa, Hidemi

2016-06-16

Scanning tunneling microscopy/spectroscopy (STM/STS) was carried out to investigate the structures of Mn atoms deposited on a GaAs(110) surface at room temperature to directly observe the characteristics of interactions between Mn atoms in GaAs. Mn atoms were paired with a probability higher than the random distribution, indicating an attractive interaction between them. In fact, re-pairing of unpaired Mn atoms was observed during STS measurement. The pair initially had a new structure, which was transformed during STS measurement into one of those formed by atom manipulation at 4 K. Mn atoms in pairs and trimers were aligned in the <110> direction, which is theoretically predicted to produce a high Curie temperature.

Glycine's radiolytic destruction in ices: first in situ laboratory measurements for Mars.

PubMed

Gerakines, Perry A; Hudson, Reggie L

2013-07-01

We report new laboratory studies of the radiation-induced destruction of glycine-containing ices for a range of temperatures and compositions that allow extrapolation to martian conditions. In situ infrared spectroscopy was used to study glycine decay rates as a function of temperature (from 15 to 280 K) and initial glycine concentrations in six mixtures whose compositions ranged from dry glycine to H2O+glycine (300:1). Results are presented in several systems of units, with cautions concerning their use. The half-life of glycine under the surface of Mars is estimated as an extrapolation of this data set to martian conditions, and trends in decay rates are described as are applications to Mars' near-surface chemistry.

Understanding Mesoscale Land-Atmosphere Interactions in Arctic Region

NASA Astrophysics Data System (ADS)

Hong, X.; Wang, S.; Nachamkin, J. E.

2017-12-01

Land-atmosphere interactions in Arctic region are examined using the U.S. Navy Coupled Ocean/Atmosphere Mesoscale Prediction System (COAMPS©*) with the Noah Land Surface Model (LSM). Initial land surface variables in COAMPS are interpolated from the real-time NASA Land Information System (LIS). The model simulations are configured for three nest grids with 27-9-3 km horizontal resolutions. The simulation period is set for October 2015 with 12-h data assimilation update cycle and 24-h integration length. The results are compared with those simulated without using LSM and evaluated with observations from ONR Sea State R/V Sikuliaq cruise and the North Slope of Alaska (NSA). There are complex soil and vegetation types over the surface for simulation with LSM, compared to without LSM simulation. The results show substantial differences in surface heat fluxes between bulk surface scheme and LSM, which may have an important impact on the sea ice evolution over the Arctic region. Evaluations from station data show surface air temperature and relative humidity have smaller biases for simulation using LSM. Diurnal variation of land surface temperature, which is necessary for physical processes of land-atmosphere, is also better captured than without LSM.

Evolution of surface structure in laser-preheated, perturbed materials

DOE PAGES

Di Stefano, Carlos; Merritt, Elizabeth Catherine; Doss, Forrest William; ...

2017-02-03

Here, we report an experimental and computational study investigating the effects of laser preheat on the hydrodynamic behavior of a material layer. In particular, we find that perturbation of the surface of the layer results in a complex interaction, in which the bulk of the layer develops density, pressure, and temperature structure and in which the surface experiences instability-like behavior, including mode coupling. A uniform one-temperature preheat model is used to reproduce the experimentally observed behavior, and we find that this model can be used to capture the evolution of the layer, while also providing evidence of complexities in themore » preheat behavior. Lastly, this result has important consequences for inertially confined fusion plasmas, which can be difficult to diagnose in detail, as well as for laser hydrodynamics experiments, which generally depend on assumptions about initial conditions in order to interpret their results.« less

Description and testing of three moisture sensors for measuring surface wetness on carbonate building stones

USGS Publications Warehouse

See, R.B.; Reddy, M.M.; Martin, R.G.

1988-01-01

Three moisture sensors were tested as a means for determining the surface wetness on carbonate building stones exposed to conditions that produce deposition of moisture. A relative-humidity probe, a gypsum-coated circuit grid, and a limestone-block resistor were tested as sensors for determining surface wetness. Sensors were tested under laboratory conditions of constant relative humidity and temperature and also under on-site conditions of variable relative humidity and temperature for eight weeks at Newcomb, NY. Laboratory tests indicated that relative humidity alone did not cause sensors to become saturated with water. However, the rates of drying indicated by the sensors after an initial saturation were inversely related to the relative humidity. On-site testing of the relative-humidity probe and the gypsum-coated ciruit grid indicated that they respond to a diurnal wetting and drying cycle; the limestone-block resistor responded only to rainfall.

Influence of Soil Heterogeneity on Mesoscale Land Surface Fluxes During Washita '92

NASA Technical Reports Server (NTRS)

Jasinski, Michael F.; Jin, Hao

1998-01-01

The influence of soil heterogeneity on the partitioning of mesoscale land surface energy fluxes at diurnal time scales is investigated over a 10(exp 6) sq km domain centered on the Little Washita Basin, Oklahoma, for the period June 10 - 18, 1992. The sensitivity study is carried out using MM5/PLACE, the Penn State/NCAR MM5 model enhanced with the Parameterization for Land-Atmosphere-Cloud Exchange or PLACE. PLACE is a one-dimensional land surface model possessing detailed plant and soil water physics algorithms, multiple soil layers, and the capacity to model subgrid heterogeneity. A series of 12-hour simulations were conducted with identical atmospheric initialization and land surface characterization but with different initial soil moisture and texture. A comparison then was made of the simulated land surface energy flux fields, the partitioning of net radiation into latent and sensible heat, and the soil moisture fields. Results indicate that heterogeneity in both soil moisture and texture affects the spatial distribution and partitioning of mesoscale energy balance. Spatial averaging results in an overprediction of latent heat flux, and an underestimation of sensible heat flux. In addition to the primary focus on the partitioning of the land surface energy, the modeling effort provided an opportunity to examine the issue of initializing the soil moisture fields for coupled three-dimensional models. For the present case, the initial soil moisture and temperature were determined from off-line modeling using PLACE at each grid box, driven with a combination of observed and assimilated data fields.

Peripheral temperature drop in response to anticipation and consumption of a signaled palatable reward in laying hens (Gallus domesticus).

PubMed

Moe, Randi Oppermann; Stubsjøen, Solveig Marie; Bohlin, Jon; Flø, Andreas; Bakken, Morten

2012-06-25

The present study describes effects of anticipation and consumption of a palatable reward on comb surface temperature. The purpose was to investigate temperature responses as a potential physiological indicator of positive emotional states in laying hens. A rise in body temperature in response to stimuli predictive of or during exposure to unpleasant events has been interpreted as evidence of emotions in mammals and avians. However, this phenomenon has so far only been studied during anticipation of or exposure to negative events; i.e., emotions of a negative valence. Infrared thermography was used to record potential alterations in comb surface temperature to a conditioned cue signaling a reward (mealworms) and during reward delivery. On average, comb temperature dropped 1.5 °C (95% CI: +/-1.2 °C) after exposure to CS and consumption of reward (p~0.0014) when initial comb temperature was above 30 °C. Such temperature drop indicates a peripheral vasoconstriction and has clear resemblances to emotional fever as seen during negative emotional states. Thus, we propose that a drop in peripheral temperature reflects emotional arousal more than emotional valence. Substantial temperature responses due to diet-induced thermogenesis were found, further emphasizing a cautious interpretation of altered comb temperature in studies of animal welfare. Copyright © 2012 Elsevier Inc. All rights reserved.

Forced convection in the wakes of impacting and sliding bubbles

NASA Astrophysics Data System (ADS)

O'Reilly Meehan, R.; Williams, N. P.; Donnelly, B.; Persoons, T.; Nolan, K.; Murray, D. B.

2017-09-01

Both vapour and gas bubbles are known to significantly increase heat transfer rates between a heated surface and the surrounding fluid, even with no phase change. The cooling structures observed are highly temporal, intricate and complex, with a full description of the surface cooling phenomena not yet available. The current study uses high speed infrared thermography to measure the surface temperature and determine the convective heat flux enhancement associated with the interaction of a single air bubble with a heated, inclined surface. This process can be discretised into the initial impact, in which enhancement levels in excess of 20 times natural convection are observed, and the subsequent sliding behaviour, with more moderate maximum enhancement levels of 8 times natural convection. In both cases, localised regions of suppressed heat transfer are also observed due to the recirculation of warm fluid displaced from the thermal boundary layer with the surface. The cooling patterns observed herein are consistent with the interaction between an undulating wake containing multiple hairpin vortex loops and the thermal boundary layer that exists under the surface, with the initial nature of this enhancement and suppression dependent on the particular point on its rising path at which the bubble impacts the surface.

Interaction of gases with lunar materials. [analysis of lunar samples from Apollo 17 flight

NASA Technical Reports Server (NTRS)

Holmes, H. F.; Fuller, E. L., Jr.; Gammage, R. B.

1974-01-01

The surface chemistry of Apollo 17 lunar fines samples 74220 (the orange soil) and 74241 (the gray control soil) has been studied by measuring the adsorption of nitrogen, argon, and oxygen (all at 77 K) and also water vapor (at 20 or 22 C). In agreement with results for samples from other missions, both samples had low initial specific surface areas, consisted of nonporous particles, and were attacked by water vapor at high relative pressure to give an increased specific surface area and create a pore system which gave rise to a capillary condensation hysteresis loop in the adsorption isotherms. In contrast to previous samples, both of the Apollo 17 soils were partially hydrophobic in their initial interaction with water vapor (both samples were completely hydrophilic after the reaction with water). The results are consistent with formation at high temperatures without subsequent exposure to significant amounts of water.

Reduction of initial shock in decadal predictions using a new initialization strategy

NASA Astrophysics Data System (ADS)

He, Yujun; Wang, Bin

2017-04-01

Initial shock is a well-known problem occurring in the early years of a decadal prediction when assimilating full-field observations into a coupled model, which directly affects the prediction skill. For the purpose to alleviate this problem, we propose a novel full-field initialization method based on dimension-reduced projection four-dimensional variational data assimilation (DRP-4DVar). Different from the available solution strategies including anomaly assimilation and bias correction, it substantially reduces the initial shock through generating more consistent initial conditions for the coupled model, which, along with the model trajectory in one-month windows, best fit the monthly mean analysis data of oceanic temperature and salinity. We evaluate the performance of initialized hindcast experiments according to three proposed indices to measure the intensity of the initial shock. The results indicate that this strategy can obviously reduce the initial shock in decadal predictions by FGOALS-g2 (the Flexible Global Ocean-Atmosphere-Land System model, Grid-point Version 2) compared with the commonly-used nudging full-field initialization for the same model as well as the different full-field initialization strategies for other CMIP5 (the fifth phase of the Coupled Model Intercomparison Project) models whose decadal prediction results are available. It is also comparable to or even better than the anomaly initialization methods. Better hindcasts of global mean surface air temperature anomaly are obtained due to the reduction of initial shock by the new initialization scheme.

[Optimization of prokaryotic expression conditions of Leptospira interrogans trigeminy genus-specific protein antigen based on surface response analysis].

PubMed

Wang, Jiang; Luo, Dongjiao; Sun, Aihua; Yan, Jie

2008-07-01

Lipoproteins LipL32 and LipL21 and transmembrane protein OMPL1 have been confirmed as the superficial genus-specific antigens of Leptospira interrogans, which can be used as antigens for developing a universal genetic engineering vaccine. In order to obtain high expression of an artificial fusion gene lipL32/1-lipL21-ompL1/2, we optimized prokaryotic expression conditions. We used surface response analysis based on the central composite design to optimize culture conditions of a new antigen protein by recombinant Escherichia coli DE3.The culture conditions included initial pH, induction start time, post-induction time, Isopropyl beta-D-thiogalactopyranoside (IPTG) concentration, and temperature. The maximal production of antigen protein was 37.78 mg/l. The optimal culture conditions for high recombinant fusion protein was determined: initial pH 7.9, induction start time 2.5 h, a post-induction time of 5.38 h, 0.20 mM IPTG, and a post-induction temperature of 31 degrees C. Surface response analysis based on CCD increased the target production. This statistical method reduced the number of experiments required for optimization and enabled rapid identification and integration of the key culture condition parameters for optimizing recombinant protein expression.

Studies on adsorption, reaction mechanisms and kinetics for photocatalytic degradation of CHD, a pharmaceutical waste.

PubMed

Sarkar, Santanu; Bhattacharjee, Chiranjib; Curcio, Stefano

2015-11-01

The photocatalytic degradation of chlorhexidine digluconate (CHD), a disinfectant and topical antiseptic and adsorption of CHD catalyst surface in dark condition has been studied. Moreover, the value of kinetic parameters has been measured and the effect of adsorption on photocatalysis has been investigated here. Substantial removal was observed during the photocatalysis process, whereas 40% removal was possible through the adsorption route on TiO2 surface. The parametric variation has shown that alkaline pH, ambient temperature, low initial substrate concentration, high TiO2 loading were favourable, though at a certain concentration of TiO2 loading, photocatalytic degradation efficiency was found to be maximum. The adsorption study has shown good confirmation with Langmuir isotherm and during the reaction at initial stage, it followed pseudo-first-order reaction, after that Langmuir Hinshelwood model was found to be appropriate in describing the system. The present study also confirmed that there is a significant effect of adsorption on photocatalytic degradation. The possible mechanism for adsorption and photocatalysis has been shown here and process controlling step has been identified. The influences of pH and temperature have been explained with the help of surface charge distribution of reacting particles and thermodynamic point of view respectively. Copyright © 2015 Elsevier Inc. All rights reserved.

The Impact of Sea Surface Temperature on Organized Convective Storms Crossing over Coastlines

NASA Astrophysics Data System (ADS)

Lombardo, K.

2016-02-01

As organized coastal convective storms develop over land and move over the coastal ocean, their storm-scale structures, intensity, and associated weather threats evolve. This study aims to quantify the impact of sea surface temperature on the fundamental mechanisms controlling the evolution of coastal quasi-linear convective systems (QLCSs) as they move offshore. Results from this work will contribute to the improved predictability of these coastal, potentially severe warm season storms. The current work systematically studies the interaction between QLCSs and marine atmospheric boundary layers (MABLs) associated with the coastal ocean in an idealized numerical framework. The initial simulations are run in 2-dimensions, with a 250 m horizontal resolution and a vertical resolution ranging from 100 m in the lowest 3000 m stretched to 250 m at the top of the 20 km domain. To create a numerical environment representative of a coastal region, the western half of the 800 km domain is configured to represent a land surface, while the eastern half represents a water surface. A series of sensitivity experiments are conducted to explore the influence of sea surface temperature and the overlying MABL on coastal QLCSs. Sea surface temperature values are selected to represent values observed within the Mid-Atlantic Bight coastal waters, including 5oC (min SST - January), 14oC (early summer), and 23oC (late summer). The numerical MABL is allowed to develop through surface heat fluxes. Preliminary simulations indicate that SST influences storm structure, with the stratiform precipitation shield becoming progressively wider as SST increases. SST also impacts propagation speed; once the storms are over the water, the early and late summer QLCSs move more quickly than the min SST storm. The physical mechanisms contributing to these and other differences will be discussed.

Reduction of Trapped-Ion Anomalous Heating by in situ Surface Plasma Cleaning

DTIC Science & Technology

2015-04-29

the trap chip temperature. To load ions, we initially cool 88Sr atoms into a remotely-located magneto - optical trap (MOT), then use a resonant push beam... trap heating rates [10]. Furthermore, some previous experiments have shown an improvement in the heating rates of surface-electrode ion traps after...rate when the trap chip is held at 4 K is not significantly improved by the plasma cleaning. While the observed frequency scaling is not the same in

Fatigue flaw growth and NDI evaluation for preventing through cracks in spacecraft tankage structures

NASA Technical Reports Server (NTRS)

Pettit, D. E.; Hoeppner, D. W.

1972-01-01

A program was conducted to determine the fatigue-crack propagation behavior of parent and welded 2219-T87 aluminum alloy sheet under controlled cyclic stress conditions in room temperature air and 300 F air. Specimens possessing an initial surface defect of controlled dimensions were cycled under constant load amplitude until the propagating fatigue crack penetrated the back surface of the specimen. A series of precracked specimens were prepared to determine optimum penetrant, X-ray, ultrasonic, and eddy current nondestructive inspection procedures.

Eastern Pacific cooling and Atlantic overturning circulation during the last deglaciation.

PubMed

Kienast, Markus; Kienast, Stephanie S; Calvert, Stephen E; Eglinton, Timothy I; Mollenhauer, Gesine; François, Roger; Mix, Alan C

2006-10-19

Surface ocean conditions in the equatorial Pacific Ocean could hold the clue to whether millennial-scale global climate change during glacial times was initiated through tropical ocean-atmosphere feedbacks or by changes in the Atlantic thermohaline circulation. North Atlantic cold periods during Heinrich events and millennial-scale cold events (stadials) have been linked with climatic changes in the tropical Atlantic Ocean and South America, as well as the Indian and East Asian monsoon systems, but not with tropical Pacific sea surface temperatures. Here we present a high-resolution record of sea surface temperatures in the eastern tropical Pacific derived from alkenone unsaturation measurements. Our data show a temperature drop of approximately 1 degrees C, synchronous (within dating uncertainties) with the shutdown of the Atlantic meridional overturning circulation during Heinrich event 1, and a smaller temperature drop of approximately 0.5 degrees C synchronous with the smaller reduction in the overturning circulation during the Younger Dryas event. Both cold events coincide with maxima in surface ocean productivity as inferred from 230Th-normalized carbon burial fluxes, suggesting increased upwelling at the time. From the concurrence of equatorial Pacific cooling with the two North Atlantic cold periods during deglaciation, we conclude that these millennial-scale climate changes were probably driven by a reorganization of the oceans' thermohaline circulation, although possibly amplified by tropical ocean-atmosphere interaction as suggested before.

Deterministic and Probabilistic Metrics of Surface Air Temperature and Precipitation in the MiKlip Decadal Prediction System

NASA Astrophysics Data System (ADS)

Kadow, Christopher; Illing, Sebastian; Kunst, Oliver; Pohlmann, Holger; Müller, Wolfgang; Cubasch, Ulrich

2014-05-01

Decadal forecasting of climate variability is a growing need for different parts of society, industry and economy. The German initiative MiKlip (www.fona-miklip.de) focuses on the ongoing processes of medium-term climate prediction. The scientific major project funded by the Federal Ministry of Education and Research in Germany (BMBF) develops a forecast system, that aims for reliable predictions on decadal timescales. Using a single earth system model from the Max-Planck institute (MPI-ESM) and moving from the uninitialized runs on to the first initialized 'Coupled Model Intercomparison Project Phase 5' (CMIP5) hindcast experiments identified possibilities and open scientific tasks. The MiKlip decadal prediction system was improved on different aspects through new initialization techniques and datasets of the ocean and atmosphere. To accompany and emphasize such an improvement of a forecast system, a standardized evaluation system designed by the MiKlip sub-project 'Integrated data and evaluation system for decadal scale prediction' (INTEGRATION) analyzes every step of its evolution. This study aims at combining deterministic and probabilistic skill scores of this prediction system from its unitialized state to anomaly and then full-field oceanic initialization. The improved forecast skill in these different decadal hindcast experiments of surface air temperature and precipitation in the Pacific region and the complex area of the North Atlantic illustrate potential sources of skill. A standardized evaluation leads prediction systems depending on development to find its way to produce reliable forecasts. Different aspects of these research dependencies, e.g. ensemble size, resolution, initializations, etc. will be discussed.

Modeling Surface Growth of Escherichia coli on Agar Plates

PubMed Central

Fujikawa, Hiroshi; Morozumi, Satoshi

2005-01-01

Surface growth of Escherichia coli cells on a membrane filter placed on a nutrient agar plate under various conditions was studied with a mathematical model. The surface growth of bacterial cells showed a sigmoidal curve with time on a semilogarithmic plot. To describe it, a new logistic model that we presented earlier (H. Fujikawa et al., Food Microbiol. 21:501-509, 2004) was modified. Growth curves at various constant temperatures (10 to 34°C) were successfully described with the modified model (model III). Model III gave better predictions of the rate constant of growth and the lag period than a modified Gompertz model and the Baranyi model. Using the parameter values of model III at the constant temperatures, surface growth at various temperatures was successfully predicted. Surface growth curves at various initial cell numbers were also sigmoidal and converged to the same maximum cell numbers at the stationary phase. Surface growth curves at various nutrient levels were also sigmoidal. The maximum cell number and the rate of growth were lower as the nutrient level decreased. The surface growth curve was the same as that in a liquid, except for the large curvature at the deceleration period. These curves were also well described with model III. The pattern of increase in the ATP content of cells grown on a surface was sigmoidal, similar to that for cell growth. We discovered several characteristics of the surface growth of bacterial cells under various growth conditions and examined the applicability of our model to describe these growth curves. PMID:16332768

Factors associated with initial mortality of Walleye and Sauger caught in live-release tournaments

USGS Publications Warehouse

Schramm, Harold L.; Vondracek, Bruce C.; French, William E.; Gerard, Patrick D.

2010-01-01

We measured the initial mortality (fish judged nonreleasable at weigh-in), prerelease mortality (fish judged nonreleasable 1–2 h after weigh-in [which includes initial mortality]), and postrelease mortality (fish that died during a 5-d retention in net-pens) in 14 live-release tournaments for walleye Sander vitreus conducted in April–October 2006 and April–July 2007 in lakes and rivers in Michigan, Minnesota, North Dakota, South Dakota, and Wisconsin. Among the 14 events, initial mortality was 0–28%, prerelease mortality was 3–54%, and postrelease mortality was 0–100%; the mortality of reference fish (walleyes ≥31 cm long that were captured by electrofishing and held in net-pens with tournament-caught walleyes to measure postrelease mortality) was 0–97%. Mortality was generally low in events conducted when water temperatures were below 14°C but substantially higher in events when water temperatures were above 18°C. The mortality of reference fish suggests that capture by electrofishing and minimal handling when the water temperature exceeds 19°C results in high mortality of walleyes that is largely the result of the thermal conditions immediately after capture. Mortality was not related to the size of the tournaments (number of boats), the total number or weight of walleyes weighed in, or the mean number or weight of walleyes weighed in per boat. Mortality was positively related to the depth at which walleyes were caught and the live-well temperature and negatively related to the live-well dissolved oxygen concentration. Surface water temperature was the best predictor of mortality, and models were developed to predict the probability of prerelease and postrelease mortality of 10, 20, and 30% or less of tournament-caught walleyes due to water temperature.

USSR and Eastern Europe Scientific Abstracts. Geophysics, Astronomy and Space, Number 387

DTIC Science & Technology

1976-12-30

gives basis for assuming that the " greenhouse " effect hypothesis was completely confirmed. During the descent of the vehicle in the atmosphere the...conditions at the surface? On Venus the greenhouse effect was intensified in the initial stages of its geological evolution: an increase in temperature led

Effect of Si Content on Oxide Formation on Surface of Molten Fe-Cr-C Alloy Bath During Oxygen Top Blowing

NASA Astrophysics Data System (ADS)

Mihara, Ryosuke; Gao, Xu; Kim, Sun-joong; Ueda, Shigeru; Shibata, Hiroyuki; Seok, Min Oh; Kitamura, Shin-ya

2018-02-01

Using a direct observation experimental method, the oxide formation behavior on the surface of Fe-Cr-5 mass pct C-Si alloy baths during decarburization by a top-blown Ar-O2 mixture was studied. The effects of the initial Si and Cr content of the alloy, temperature, and oxygen feed ratio on oxide formation were investigated. The results showed that, for alloys without Si, oxide particles, unstable oxide films, and stable oxide films formed sequentially. The presence of Si in the alloy changed the formation behavior of stable oxide film, and increased the crucial C content when stable oxide film started to form. Increasing the temperature, decreasing the initial Cr content, and increasing the ratio of the diluting gas decreased the critical C content at which a stable oxide film started to form. In addition, the P CO and a_{{{Cr}2 {O}3 }} values at which oxides started to form were estimated using Hilty's equation and the equilibrium relation to understand the formation conditions and the role of each parameter in oxide formation.

Application of the double paddle oscillator for quantifying environmental, surface mass variation

NASA Astrophysics Data System (ADS)

Wei, Haoyan; Pomeroy, Joshua

2016-04-01

Sub-monolayer sensitivity to controlled gas adsorption and desorption is demonstrated using a double paddle oscillator (DPO) installed within an ultra-high vacuum (UHV) environmental chamber equipped with in situ film deposition, (multi)gas admission and temperature control. This effort is intended to establish a robust framework for quantitatively comparing mass changes due to gas loading and unloading on different materials systems selected or considered for use as mass artefacts. Our apparatus is composed of a UHV chamber with gas introduction and temperature control and in situ materials deposition for future materials testing enabling in situ preparation of virgin surfaces that can be monitored during initial exposure to gasses of interest. These tools are designed to allow us to comparatively evaluate how different materials gain or lose mass due to precisely controlled environmental excursions, with a long term goal of measuring changes in absolute mass. Herein, we provide a detailed experimental description of the apparatus, an evaluation of the initial performance, and demonstration measurements using nitrogen adsorption and desorption directly on the DPO.

Application of the double paddle oscillator for quantifying environmental, surface mass variation

PubMed Central

Wei, Haoyan; Pomeroy, Joshua

2016-01-01

Sub-monolayer sensitivity to controlled gas adsorption and desorption is demonstrated using a double paddle oscillator (DPO) installed within an UHV (ultra-high vacuum) environmental chamber equipped with in situ film deposition, (multi)gas admission and temperature control. This effort is intended to establish a robust framework for quantitatively comparing mass changes due to gas loading and unloading on different materials systems selected or considered for use as mass artifacts. Our apparatus is composed of a UHV chamber with gas introduction and temperature control and in-situ materials deposition for future materials testing enabling in situ preparation of virgin surfaces that can be monitored during initial exposure to gasses of interest. These tools are designed to allow us to comparatively evaluate how different materials gain or lose mass due to precisely controlled environmental excursions, with a long term goal of measuring changes in absolute mass. Herein, we provide a detailed experimental description of the apparatus, an evaluation of the initial performance, and demonstration measurements using nitrogen adsorption and desorption directly on the DPO. PMID:27212736

Quantitative Restoration of the Evolution of Mantle Structures Using Data Assimilation

NASA Astrophysics Data System (ADS)

Ismail-Zadeh, A.; Schubert, G.; Tsepelev, I.

2008-12-01

Rapid progress in imaging deep Earth structures and in studies of physical and chemical properties of mantle rocks facilitates research in assimilation of data related to mantle dynamics. We present a quantitative approach to assimilation of geophysical and geodetic data, which allows for incorporating observations and unknown initial conditions for mantle temperature and flow into a three-dimensional dynamic model in order to determine the initial conditions in the geological past. Once the conditions are determined the evolution of mantle structures can be restore backward in time. We apply data assimilation techniques to model the evolution of mantle plumes and lithospheric slabs. We show that the geometry of the mantle structures changes with time diminishing the degree of surface curvature of the structures, because the heat conduction smoothes the complex thermal surfaces of mantle bodies with time. Present seismic tomography images of mantle structures do not allow definition of the sharp shapes of these structures. Assimilation of mantle temperature and flow to the geological past instead provides a quantitative tool to restore thermal shapes of prominent structures in the past from their diffusive shapes at present.

Chemical and valence reconstruction at the surface of SmB6 revealed by means of resonant soft x-ray reflectometry

NASA Astrophysics Data System (ADS)

Zabolotnyy, V. B.; Fürsich, K.; Green, R. J.; Lutz, P.; Treiber, K.; Min, Chul-Hee; Dukhnenko, A. V.; Shitsevalova, N. Y.; Filipov, V. B.; Kang, B. Y.; Cho, B. K.; Sutarto, R.; He, Feizhou; Reinert, F.; Inosov, D. S.; Hinkov, V.

2018-05-01

Samarium hexaboride (SmB6), a Kondo insulator with mixed valence, has recently attracted much attention as a possible host for correlated topological surface states. Here, we use a combination of x-ray absorption and reflectometry techniques, backed up with a theoretical model for the resonant M4 ,5 absorption edge of Sm and photoemission data, to establish laterally averaged chemical and valence depth profiles at the surface of SmB6. We show that upon cleaving, the highly polar (001) surface of SmB6 undergoes substantial chemical and valence reconstruction, resulting in boron termination and a Sm3 + dominated subsurface region. Whereas at room temperature, the reconstruction occurs on a timescale of less than 2 h, it takes about 24 h below 50 K. The boron termination is eventually established, irrespective of the initial termination. Our findings reconcile earlier depth resolved photoemission and scanning tunneling spectroscopy studies performed at different temperatures and are important for better control of surface states in this system.

XPS and SIMS study of the surface and interface of aged C + implanted uranium

DOE PAGES

Donald, Scott B.; Siekhaus, Wigbert J.; Nelson, Art J.

2016-09-08

X-ray photoelectron spectroscopy in combination with secondary ion mass spectrometry depth profiling were used to investigate the surface and interfacial chemistry of C + ion implanted polycrystalline uranium subsequently oxidized in air for over 10 years at ambient temperature. The original implantation of 33 keV C + ions into U 238 with a dose of 4.3 × 10 17 cm –3 produced a physically and chemically modified surface layer that was characterized and shown to initially prevent air oxidation and corrosion of the uranium after 1 year in air at ambient temperature. The aging of the surface and interfacial layersmore » were examined by using the chemical shift of the U 4f, C 1s, and O 1s photoelectron lines. In addition, valence band spectra were used to explore the electronic structure of the aged carbide surface and interface layer. Moreover, the time-of-flight secondary ion mass spectrometry depth profiling results for the aged sample confirmed an oxidized uranium carbide layer over the carbide layer/U metal interface.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Swarctz, Christopher; Alijallis, Elias; Hunter, Scott Robert

In this study, a closed loop low-temperature wind tunnel was custom-built and uniquely used to investigate the anti-icing mechanism of superhydrophobic surfaces in regulated flow velocities, temperatures, humidity, and water moisture particle sizes. Silica nanoparticle-based hydrophobic coatings were tested as superhydrophobic surface models. During tests, images of ice formation were captured by a camera and used for analysis of ice morphology. Prior to and after wind tunnel testing, apparent contact angles of water sessile droplets on samples were measured by a contact angle meter to check degradation of surface superhydrophobicity. A simple peel test was also performed to estimate adhesionmore » of ice on the surfaces. When compared to an untreated sample, superhydrophobic surfaces inhibited initial ice formation. After a period of time, random droplet strikes attached to the superhydrophobic surfaces and started to coalesce with previously deposited ice droplets. These sites appear as mounds of accreted ice across the surface. The appearance of the ice formations on the superhydrophobic samples is white rather than transparent, and is due to trapped air. These ice formations resemble soft rime ice rather than the transparent glaze ice seen on the untreated sample. Compared to untreated surfaces, the icing film formed on superhydrophobic surfaces was easy to peel off by shear flows.« less

Carbon Cycle Model of a Hawaiian Barrier Reef under Rising Ocean Acidification and Temperature Conditions of the Anthropocene

NASA Astrophysics Data System (ADS)

Drupp, P. S.; Mackenzie, F. T.; De Carlo, E. H.; Guidry, M.

2015-12-01

A CO2-carbonic acid system biogeochemical box model (CRESCAM, Coral Reef and Sediment Carbonate Model) of the barrier reef flat in Kaneohe Bay, Hawai'i was developed to determine how increasing temperature and dissolved inorganic carbon (DIC) content of open ocean source waters, resulting from rising anthropogenic CO2 emissions and ocean acidification, affect the CaCO3budget of coral reef ecosystems. CRESCAM consists of 17 reservoirs and 59 fluxes, including a surface water column domain, a two-layer permeable sediment domain, and a coral framework domain. Physical, chemical, and biological processes such as advection, carbonate precipitation/dissolution, and net ecosystem production and calcification were modeled. The initial model parameters were constrained by experimental and field data from previous coral reef studies, mostly in Kaneohe Bay over the past 50 years. The field studies include data collected by our research group for both the water column and sediment-porewater system.The model system, initially in a quasi-steady state condition estimated for the early 21st century, was perturbed using future projections to the year 2100 of the Anthropocene of atmospheric CO2 ­concentrations, temperature, and source water DIC. These perturbations were derived from the most recent (2013) IPCC's Representative Concentration Pathway (RCP) scenarios, which predict CO2 atmospheric concentrations and temperature anomalies out to 2100. A series of model case studies were also performed whereby one or more parameters (e.g., coral calcification response to declining surface water pH) were altered to investigate potential future outcomes. Our model simulations predict that although the Kaneohe Bay barrier reef will likely see a significant decline in NEC over the coming century, it is unlikely to reach a state of net erosion - a result contrary to several global coral reef model projections. In addition, we show that depending on the future response of NEP and NEC to OA and rising temperatures, the surface waters could switch from being a present-day source of CO2 to the atmosphere to a future sink. This ecosystem specific model can be applied to any reef system where data are available to constrain the initial model state and is a powerful tool for examining future changes in coral reef carbon budgets.

Introduction to CAUSES: Description of Weather and Climate Models and Their Near-Surface Temperature Errors in 5 day Hindcasts Near the Southern Great Plains

DOE Office of Scientific and Technical Information (OSTI.GOV)

Morcrette, C. J.; Van Weverberg, K.; Ma, H. -Y.

The Clouds Above the United States and Errors at the Surface (CAUSES) project is aimed at gaining a better understanding of the physical processes that are leading to the creation of warm screen-temperature biases over the American Midwest, which are seen in many numerical models. Here in Part 1, a series of 5-day hindcasts, each initialised from re-analyses and performed by 11 different models, are evaluated against screen-temperature observations. All the models have a warm bias over parts of the Midwest. Several ways of quantifying the impact of the initial conditions on the evolution of the simulations are presented, showingmore » that within a day or so all models have produced a warm bias that is representative of their bias after 5 days, and not closely tied to the conditions at the initial time. Although the surface temperature biases sometimes coincide with locations where the re-analyses themselves have a bias, there are many regions in each of the models where biases grow over the course of 5 days or are larger than the biases present in the reanalyses. At the Southern Great Plains site, the model biases are shown to not be confined to the surface, but extend several kilometres into the atmosphere. In most of the models, there is a strong diurnal cycle in the screen-temperature bias and in some models the biases are largest around midday, while in the others it is largest during the night. While the different physical processes that are contributing to a given model having a screen-temperature error will be discussed in more detail in the companion papers (Parts 2 and 3) the fact that there is a spatial coherence in the phase of the diurnal cycle of the error across wide regions and that there are numerous locations across the Midwest where the diurnal cycle of the error is highly correlated with the diurnal cycle of the error at SGP suggest that the detailed evaluations of the role of different processes in contributing to errors at SGP will be representative of errors that are prevalent over a much larger spatial scale.« less

Introduction to CAUSES: Description of weather and climate models and their near-surface temperature errors in 5-day hindcasts near the Southern Great Plains

DOE Office of Scientific and Technical Information (OSTI.GOV)

Morcrette, Cyril J.; Van Weverberg, Kwinten; Ma, H

2018-02-16

The Clouds Above the United States and Errors at the Surface (CAUSES) project is aimed at gaining a better understanding of the physical processes that are leading to the creation of warm screen-temperature biases over the American Midwest, which are seen in many numerical models. Here in Part 1, a series of 5-day hindcasts, each initialised from re-analyses and performed by 11 different models, are evaluated against screen-temperature observations. All the models have a warm bias over parts of the Midwest. Several ways of quantifying the impact of the initial conditions on the evolution of the simulations are presented, showingmore » that within a day or so all models have produced a warm bias that is representative of their bias after 5 days, and not closely tied to the conditions at the initial time. Although the surface temperature biases sometimes coincide with locations where the re-analyses themselves have a bias, there are many regions in each of the models where biases grow over the course of 5 days or are larger than the biases present in the reanalyses. At the Southern Great Plains site, the model biases are shown to not be confined to the surface, but extend several kilometres into the atmosphere. In most of the models, there is a strong diurnal cycle in the screen-temperature bias and in some models the biases are largest around midday, while in the others it is largest during the night. While the different physical processes that are contributing to a given model having a screen-temperature error will be discussed in more detail in the companion papers (Parts 2 and 3) the fact that there is a spatial coherence in the phase of the diurnal cycle of the error across wide regions and that there are numerous locations across the Midwest where the diurnal cycle of the error is highly correlated with the diurnal cycle of the error at SGP suggest that the detailed evaluations of the role of different processes in contributing to errors at SGP will be representative of errors that are prevalent over a much larger spatial scale.« less

Spontaneous jumping, bouncing and trampolining of hydrogel drops on a heated plate.

PubMed

Pham, Jonathan T; Paven, Maxime; Wooh, Sanghyuk; Kajiya, Tadashi; Butt, Hans-Jürgen; Vollmer, Doris

2017-10-13

The contact between liquid drops and hot solid surfaces is of practical importance for industrial processes, such as thermal spraying and spray cooling. The contact and bouncing of solid spheres is also an important event encountered in ball milling, powder processing, and everyday activities, such as ball sports. Using high speed video microscopy, we demonstrate that hydrogel drops, initially at rest on a surface, spontaneously jump upon rapid heating and continue to bounce with increasing amplitudes. Jumping is governed by the surface wettability, surface temperature, hydrogel elasticity, and adhesion. A combination of low-adhesion impact behavior and fast water vapor formation supports continuous bouncing and trampolining. Our results illustrate how the interplay between solid and liquid characteristics of hydrogels results in intriguing dynamics, as reflected by spontaneous jumping, bouncing, trampolining, and extremely short contact times.Drops of liquid on a hot surface can exhibit fascinating behaviour such as the Leidenfrost effect in which drops hover on a vapour layer. Here Pham et al. show that when hydrogel drops are placed on a rapidly heated plate they bounce to increasing heights even if they were initially at rest.

Research Vessel Meteorological and Oceanographic Systems Support Satellite and Model Validation Studies

NASA Astrophysics Data System (ADS)

Smith, S. R.; Lopez, N.; Bourassa, M. A.; Rolph, J.; Briggs, K.

2012-12-01

The research vessel data center at the Florida State University routinely acquires, quality controls, and distributes underway surface meteorological and oceanographic observations from vessels. The activities of the center are coordinated by the Shipboard Automated Meteorological and Oceanographic System (SAMOS) initiative in partnership with the Rolling Deck to Repository (R2R) project. The data center evaluates the quality of the observations, collects essential metadata, provides data quality feedback to vessel operators, and ensures the long-term data preservation at the National Oceanographic Data Center. A description of the SAMOS data stewardship protocols will be provided, including dynamic web tools that ensure users can select the highest quality observations from over 30 vessels presently recruited to the SAMOS initiative. Research vessels provide underway observations at high-temporal frequency (1 min. sampling interval) that include navigational (position, course, heading, and speed), meteorological (air temperature, humidity, wind, surface pressure, radiation, rainfall), and oceanographic (surface sea temperature and salinity) samples. Recruited vessels collect a high concentration of data within the U.S. continental shelf and also frequently operate well outside routine shipping lanes, capturing observations in extreme ocean environments (Southern Ocean, Arctic, South Atlantic and Pacific). The unique quality and sampling locations of research vessel observations and there independence from many models and products (RV data are rarely distributed via normal marine weather reports) makes them ideal for validation studies. We will present comparisons between research vessel observations and model estimates of the sea surface temperature and salinity in the Gulf of Mexico. The analysis reveals an underestimation of the freshwater input to the Gulf from rivers, resulting in an overestimation of near coastal salinity in the model. Additional comparisons between surface atmospheric products derived from satellite observations and the underway research vessel observations will be shown. The strengths and limitations of research observations for validation studies will be highlighted through these case studies.

A new temperature and humidity dependent surface site density approach for deposition ice nucleation

NASA Astrophysics Data System (ADS)

Steinke, I.; Hoose, C.; Möhler, O.; Connolly, P.; Leisner, T.

2014-07-01

Deposition nucleation experiments with Arizona Test Dust (ATD) as a surrogate for mineral dusts were conducted at the AIDA cloud chamber at temperatures between 220 and 250 K. The influence of the aerosol size distribution and the cooling rate on the ice nucleation efficiencies was investigated. Ice nucleation active surface site (INAS) densities were calculated to quantify the ice nucleation efficiency as a function of temperature, humidity and the aerosol surface area concentration. Additionally, a contact angle parameterization according to classical nucleation theory was fitted to the experimental data in order to relate the ice nucleation efficiencies to contact angle distributions. From this study it can be concluded that the INAS density formulation is a very useful tool to decribe the temperature and humidity dependent ice nucleation efficiency of ATD particles. Deposition nucleation on ATD particles can be described by a temperature and relative humidity dependent INAS density function ns(T, Sice) with ns(xtherm) = 1.88 × 105 \\centerdot exp(0.2659 \\centerdot xtherm) [m-2] (1) where the thermodynamic variable xtherm is defined as xtherm = -(T - 273.2) + (Sice-1) × 100 (2) with Sice>1 and within a temperature range between 226 and 250 K. For lower temperatures, xtherm deviates from a linear behavior with temperature and relative humidity over ice. Two different approaches for describing the time dependence of deposition nucleation initiated by ATD particles are proposed. Box model estimates suggest that the time dependent contribution is only relevant for small cooling rates and low number fractions of ice-active particles.

A new experimental apparatus for emissivity measurements of steel and the application of multi-wavelength thermometry to continuous casting billets

NASA Astrophysics Data System (ADS)

Wang, Peng; Hu, Zhenwei; Xie, Zhi; Yan, Ming

2018-05-01

An experimental apparatus has been designed for measuring the emissivity of a steel surface in both vacuum and oxidation atmosphere. The sample is heated with the method of electromagnetic induction in order to ensure the temperature uniformity. The radiance emitted from a sample is measured using a fiber-optic Fourier transform infrared spectrometer. Using this unique apparatus, we investigated the spectral (2-6 μm) and directional (0°-86°) emissivity of stainless steel 304 with different degrees of surface oxidation at temperatures ranging from 800 to 1100 °C. The experimental results show that the emissivity increases slightly with increasing temperature, which accords with the Hagen-Rubens relation. The emissivity increases rapidly at the initial stage of oxidation, but gradually reaches to a constant value after 20 min. In addition, the directional emissivity has a maximum value at the measuring angle of about 75°. The maximum uncertainty of emissivity is only 3.0% over all the measuring ranges, indicating that this experimental apparatus has a high reliability. In order to measure the surface temperature of casting billets based on multi-wavelength thermometry, the bivariate emissivity function with the two variables, wavelength and temperature, is determined. Temperature measurement results based on our technique are compared with those from common dual-wavelength radiation thermometry. Our approach reduces the measured temperature fluctuation from ±20.7 °C to ±2.8 °C and reflects the temperature variation with the changes of production parameters in real time.

Synthesis of cobalt stearate as oxidant additive for oxo-biodegradable polyethylene

NASA Astrophysics Data System (ADS)

Asriza, Ristika O.; Arcana, I. Made

2015-09-01

Cobalt stearate is an oxidant additives that can initiate a process of degradation in high density polyethylene (HDPE). To determine the effect of cobalt stearate in HDPE, oxo-biodegradable polyethylene film was given an irradiation with UV light or heating at various temperature. After given a heating, the FTIR spectra showed a new absorption peak at wave number 1712 cm-1 indicating the presence of carbonyl groups in polymers, whereas after irradiation with UV light is not visible the presence of this absorption peak. The increase concentration of cobalt stearate added in HDPE and the higher heating temperature, the intensity of the absorption peak of the carbonyl group increased. The increasing intensity of the carbonyl group absorption is caused the presence of damage in the film surface after heating, and this result is supported by analysis the surface properties of the film with using SEM. Biodegradation tests were performed on oxo-biodegradable polyethylene film which has been given heating or UV light with using activated sludge under optimal conditions the growth of microorganisms. After biodegradation, the maximum weight decreased by 23% in the oxo-biodegradable polyethylene film with a cobalt stearate concentration of 0.2% and after heating at a temperature of 75 °C for 10 days, and only 0.69% in the same film after irradiation UV light for 10 days. Based on the results above, cobalt stearate additive is more effective to initiate the oxidative degradation of HDPE when it is initiated by heating compared to irradiation with UV light.

Impact of Assimilation of Conventional and Satellite Radiance GTS Observations on Simulation of Mesoscale Convective System Over Southeast India Using WRF-3DVar

NASA Astrophysics Data System (ADS)

Madhulatha, A.; Rajeevan, M.; Bhowmik, S. K. Roy; Das, A. K.

2018-01-01

The primary goal of present study is to investigate the impact of assimilation of conventional and satellite radiance observations in simulating the mesoscale convective system (MCS) formed over south east India. An assimilation methodology based on Weather Research and Forecasting model three dimensional variational data assimilation is considered. Few numerical experiments are carried out to examine the individual and combined impact of conventional and non-conventional (satellite radiance) observations. After the successful inclusion of additional observations, strong analysis increments of temperature and moisture fields are noticed and contributed to significant improvement in model's initial fields. The resulting model simulations are able to successfully reproduce the prominent synoptic features responsible for the initiation of MCS. Among all the experiments, the final experiment in which both conventional and satellite radiance observations assimilated has showed considerable impact on the prediction of MCS. The location, genesis, intensity, propagation and development of rain bands associated with the MCS are simulated reasonably well. The biases of simulated temperature, moisture and wind fields at surface and different pressure levels are reduced. Thermodynamic, dynamic and vertical structure of convective cells associated with the passage of MCS are well captured. Spatial distribution of rainfall is fairly reproduced and comparable to TRMM observations. It is demonstrated that incorporation of conventional and satellite radiance observations improved the local and synoptic representation of temperature, moisture fields from surface to different levels of atmosphere. This study highlights the importance of assimilation of conventional and satellite radiances in improving the models initial conditions and simulation of MCS.

Synthesis of cobalt stearate as oxidant additive for oxo-biodegradable polyethylene

DOE Office of Scientific and Technical Information (OSTI.GOV)

Asriza, Ristika O.; Arcana, I Made, E-mail: arcana@chem.itb.ac.id

Cobalt stearate is an oxidant additives that can initiate a process of degradation in high density polyethylene (HDPE). To determine the effect of cobalt stearate in HDPE, oxo-biodegradable polyethylene film was given an irradiation with UV light or heating at various temperature. After given a heating, the FTIR spectra showed a new absorption peak at wave number 1712 cm{sup −1} indicating the presence of carbonyl groups in polymers, whereas after irradiation with UV light is not visible the presence of this absorption peak. The increase concentration of cobalt stearate added in HDPE and the higher heating temperature, the intensity of themore » absorption peak of the carbonyl group increased. The increasing intensity of the carbonyl group absorption is caused the presence of damage in the film surface after heating, and this result is supported by analysis the surface properties of the film with using SEM. Biodegradation tests were performed on oxo-biodegradable polyethylene film which has been given heating or UV light with using activated sludge under optimal conditions the growth of microorganisms. After biodegradation, the maximum weight decreased by 23% in the oxo-biodegradable polyethylene film with a cobalt stearate concentration of 0.2% and after heating at a temperature of 75 °C for 10 days, and only 0.69% in the same film after irradiation UV light for 10 days. Based on the results above, cobalt stearate additive is more effective to initiate the oxidative degradation of HDPE when it is initiated by heating compared to irradiation with UV light.« less

Effects of water vapor pretreatment time and reaction temperature on CO(2) capture characteristics of a sodium-based solid sorbent in a bubbling fluidized-bed reactor.

PubMed

Seo, Yongwon; Jo, Sung-Ho; Ryu, Chong Kul; Yi, Chang-Keun

2007-10-01

CO(2) capture from flue gas using a sodium-based solid sorbent was investigated in a bubbling fluidized-bed reactor. Carbonation and regeneration temperature on CO(2) removal was determined. The extent of the chemical reactivity after carbonation or regeneration was characterized via (13)C NMR. In addition, the physical properties of the sorbent such as pore size, pore volume, and surface area after carbonation or regeneration were measured by gas adsorption method (BET). With water vapor pretreatment, near complete CO(2) removal was initially achieved and maintained for about 1-2min at 50 degrees C with 2s gas residence time, while without proper water vapor pretreatment CO(2) removal abruptly decreased from the beginning. Carbonation was effective at the lower temperature over the 50-70 degrees C temperature range, while regeneration more effective at the higher temperature over the 135-300 degrees C temperature range. To maintain the initial 90% CO(2) removal, it would be necessary to keep the regeneration temperature higher than about 135 degrees C. The results obtained in this study can be used as basic data for designing and operating a large scale CO(2) capture process with two fluidized-bed reactors.

Moon (Form-Origin)

NASA Astrophysics Data System (ADS)

Tsiapas, Elias

2016-04-01

When the Earth was formed, it was in a state of burning heat. As time went by, temperature on the planet's surface was falling due to radiation and heat transfer, and various components (crusts) began taking solid form at the Earth's poles. The formation of crusts took place at the Earth's poles, because the stirring of burning and fluid masses on the surface of the Earth was significantly slighter there than it was on the equator. Due to centrifugal force and Coriolis Effect, these solid masses headed towards the equator; those originating from the North Pole followed a south-western course, while those originating from the South Pole followed a north-western course and there they rotated from west to east at a lower speed than the underlying burning and liquid earth, because of their lower initial linear velocity, their solid state and inertia. Because inertia is proportional to mass, the initially larger solid body swept all new solid ones, incorporating them to its western side. The density of the new solid masses was higher, because the components on the surface would freeze and solidify first, before the underlying thicker components. As a result, the western side of the initial islet of solid rocks submerged, while the east side elevated. . As a result of the above, this initial islet began to spin in reverse, and after taking on the shape of a sphere, it formed the "heart" of the Moon. The Moon-sphere, rolling on the equator, would sink the solid rocks that continued to descend from the Earth's poles. The sinking rocks partially melted because of higher temperatures in the greater depths that the Moon descended to, while part of the rocks' mass bonded with the Moon and also served as a heat-insulating material, preventing the descended side of the sphere from melting. Combined with the Earth's liquid mass that covered its emerging eastern surface, new sphere-shaped shells were created, with increased density and very powerful structural cohesion. During the above mentioned process, the thick clouds surrounding Earth-Moon were causing heavy storms and on the outer surface of the rolling Moon, wherever small cavities - or pockets - existed, these would fill up with water. Then, due to the Moon's changing tilt, these pockets were sealed by sediments and as a result, small water tanks are scattered on the successive layers of the Moon, from its centre to its surface. . As this sphere (the Moon) continued to grow, the Earth-Moon system was displaying a double-planet image. The Moon's reverse rolling velocity increased according to the increase of its mass and volume. As the temperature on the surface of the Earth continued to fall, a larger number of bigger sized solid masses were descending from the poles towards the equator, and the Moon could no longer aggregate them. The gathering and interference of solid rocks of great mass acted as the catapult on which the Moon bounced off the Earth and was put into orbit around it.

Moon (Form-Origin)

NASA Astrophysics Data System (ADS)

Tsiapas, Elias; Soumelidou, Despina; Tsiapas, Christos

2017-04-01

When the Earth was formed, it was in a state of burning heat. As time went by, temperature on the planet's surface was falling due to radiation and heat transfer, and various components (crusts) began taking solid form at the Earth's poles. The formation of crusts took place at the Earth's poles, because the stirring of burning and fluid masses on the surface of the Earth was significantly slighter there than it was on the equator. Due to centrifugal force and Coriolis Effect, these solid masses headed towards the equator; those originating from the North Pole followed a south-western course, while those originating from the South Pole followed a north-western course and there they rotated from west to east at a lower speed than the underlying burning and liquid earth, because of their lower initial linear velocity, their solid state and inertia. Because inertia is proportional to mass, the initially larger solid body swept all new solid ones, incorporating them to its western side. The density of the new solid masses was higher, because the components on the surface would freeze and solidify first, before the underlying thicker components. As a result, the western side of the initial islet of solid rocks submerged, while the east side elevated. . As a result of the above, this initial islet began to spin in reverse, and after taking on the shape of a sphere, it formed the "heart" of the Moon. The Moon-sphere, rolling on the equator, would sink the solid rocks that continued to descend from the Earth's poles. The sinking rocks partially melted because of higher temperatures in the greater depths that the Moon descended to, while part of the rocks' mass bonded with the Moon and also served as a heat-insulating material, preventing the descended side of the sphere from melting. Combined with the Earth's liquid mass that covered its emerging eastern surface, new sphere-shaped shells were created, with increased density and very powerful structural cohesion. During the above mentioned process, the thick clouds surrounding Earth-Moon were causing heavy storms and on the outer surface of the rolling Moon, wherever small cavities - or pockets - existed, these would fill up with water. Then, due to the Moon's changing tilt, these pockets were sealed by sediments and as a result, small water tanks are scattered on the successive layers of the Moon, from its centre to its surface. . As this sphere (the Moon) continued to grow, the Earth-Moon system was displaying a double-planet image. The Moon's reverse rolling velocity increased according to the increase of its mass and volume. As the temperature on the surface of the Earth continued to fall, a larger number of bigger sized solid masses were descending from the poles towards the equator, and the Moon could no longer aggregate them. The gathering and interference of solid rocks of great mass acted as the catapult on which the Moon bounced off the Earth and was put into orbit around it.

Moon (Form-Origin)

NASA Astrophysics Data System (ADS)

Tsiapas, Elias

2015-04-01

When the Earth was formed, it was in a state of burning heat. As time went by, temperature on the planet's surface was falling due to radiation and heat transfer, and various components (crusts) began taking solid form at the Earth's poles. The formation of crusts took place at the Earth's poles, because the stirring of burning and fluid masses on the surface of the Earth was significantly slighter there than it was on the equator. Due to centrifugal force and Coriolis Effect, these solid masses headed towards the equator; those originating from the North Pole followed a south-western course, while those originating from the South Pole followed a north-western course and there they rotated from west to east at a lower speed than the underlying burning and liquid earth, because of their lower initial linear velocity, their solid state and inertia. Because inertia is proportional to mass, the initially larger solid body swept all new solid ones, incorporating them to its western side. The density of the new solid masses was higher, because the components on the surface would freeze and solidify first, before the underlying thicker components. As a result, the western side of the initial islet of solid rocks submerged, while the east side elevated. . As a result of the above, this initial islet began to spin in reverse, and after taking on the shape of a sphere, it formed the "heart" of the Moon. The Moon-sphere, rolling on the equator, would sink the solid rocks that continued to descend from the Earth's poles. The sinking rocks partially melted because of higher temperatures in the greater depths that the Moon descended to, while part of the rocks' mass bonded with the Moon and also served as a heat-insulating material, preventing the descended side of the sphere from melting. Combined with the Earth's liquid mass that covered its emerging eastern surface, new sphere-shaped shells were created, with increased density and very powerful structural cohesion. During the above mentioned process, the thick clouds surrounding Earth-Moon were causing heavy storms and on the outer surface of the rolling Moon, wherever small cavities - or pockets - existed, these would fill up with water. Then, due to the Moon's changing tilt, these pockets were sealed by sediments and as a result, small water tanks are scattered on the successive layers of the Moon, from its centre to its surface. . As this sphere (the Moon) continued to grow, the Earth-Moon system was displaying a double-planet image. The Moon's reverse rolling velocity increased according to the increase of its mass and volume. As the temperature on the surface of the Earth continued to fall, a larger number of bigger sized solid masses were descending from the poles towards the equator, and the Moon could no longer aggregate them. The gathering and interference of solid rocks of great mass acted as the catapult on which the Moon bounced off the Earth and was put into orbit around it.

Moon (Form-Origin)

NASA Astrophysics Data System (ADS)

Tsiapas, Elias

2014-05-01

When the Earth was formed, it was in a state of burning heat. As time went by, temperature on the planet's surface was falling due to radiation and heat transfer, and various components (crusts) began taking solid form at the Earth's poles. The formation of crusts took place at the Earth's poles, because the stirring of burning and fluid masses on the surface of the Earth was significantly slighter there than it was on the equator. Due to centrifugal force and Coriolis Effect, these solid masses headed towards the equator; those originating from the North Pole followed a south-western course, while those originating from the South Pole followed a north-western course and there they rotated from west to east at a lower speed than the underlying burning and liquid earth, because of their lower initial linear velocity, their solid state and inertia. Because inertia is proportional to mass, the initially larger solid body swept all new solid ones, incorporating them to its western side. The density of the new solid masses was higher, because the components on the surface would freeze and solidify first, before the underlying thicker components. As a result, the western side of the initial islet of solid rocks submerged, while the east side elevated. . As a result of the above, this initial islet began to spin in reverse, and after taking on the shape of a sphere, it formed the "heart" of the Moon. The Moon-sphere, rolling on the equator, would sink the solid rocks that continued to descend from the Earth's poles. The sinking rocks partially melted because of higher temperatures in the greater depths that the Moon descended to, while part of the rocks' mass bonded with the Moon and also served as a heat-insulating material, preventing the descended side of the sphere from melting. Combined with the Earth's liquid mass that covered its emerging eastern surface, new sphere-shaped shells were created, with increased density and very powerful structural cohesion. During the above mentioned process, the thick clouds surrounding Earth-Moon were causing heavy storms and on the outer surface of the rolling Moon, wherever small cavities - or pockets - existed, these would fill up with water. Then, due to the Moon's changing tilt, these pockets were sealed by sediments and as a result, small water tanks are scattered on the successive layers of the Moon, from its centre to its surface. . As this sphere (the Moon) continued to grow, the Earth-Moon system was displaying a double-planet image. The Moon's reverse rolling velocity increased according to the increase of its mass and volume. As the temperature on the surface of the Earth continued to fall, a larger number of bigger sized solid masses were descending from the poles towards the equator, and the Moon could no longer aggregate them. The gathering and interference of solid rocks of great mass acted as the catapult on which the Moon bounced off the Earth and was put into orbit around it..

Nanoscale oxidation and complex oxide growth on single crystal iron surfaces and external electric field effects.

PubMed

Jeon, Byoungseon; Van Overmeere, Quentin; van Duin, Adri C T; Ramanathan, Shriram

2013-02-14

Oxidation of iron surfaces and oxide growth mechanisms have been studied using reactive molecular dynamics. Oxide growth kinetics on Fe(100), (110), and (111) surface orientations has been investigated at various temperatures and/or an external electric field. The oxide growth kinetics decreases in the order of (110), (111), and (100) surfaces at 300 K over 1 ns timescale while higher temperature increases the oxidation rate. The oxidation rate shows a transition after an initial high rate, implying that the oxide formation mechanism evolves, with iron cation re-ordering. In early stages of surface oxide growth, oxygen transport through iron interstitial sites is dominant, yielding non-stoichiometric wüstite characteristics. The dominant oxygen inward transport decreases as the oxide thickens, evolving into more stoichiometric oxide phases such as wüstite or hematite. This also suggests that cation outward transport increases correspondingly. In addition to oxidation kinetics simulations, formed oxide layers have been relaxed in the range of 600-1500 K to investigate diffusion characteristics, fitting these results into an Arrhenius relation. The activation energy of oxygen diffusion in oxide layers formed on Fe(100), (110), and (111) surfaces was estimated to be 0.32, 0.26, and 0.28 eV, respectively. Comparison between our modeling results and literature data is then discussed. An external electric field (10 MV cm(-1)) facilitates initial oxidation kinetics by promoting oxygen transport through iron lattice interstitial sites, but reaches self-limiting thickness, showing that similar oxide formation stages are maintained when cation transport increases. The effect of the external electric field on iron oxide structure, composition, and oxide activation energy is found to be minimal, whereas cation outward migration is slightly promoted.

Evaluating the influence of antecedent soil moisture on variability of the North American Monsoon precipitation in the coupled MM5/VIC modeling system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhu, Chunmei; Leung, Lai R.; Gochis, David

2009-11-29

The influence of antecedent soil moisture on North American monsoon system (NAMS) precipitation variability was explored using the MM5 mesoscale model coupled with the Variable Infiltration Capacity (VIC) land surface model. Sensitivity experiments were performed with extreme wet and dry initial soil moisture conditions for both the 1984 wet monsoon year and the 1989 dry year. The MM5-VIC model reproduced the key features of NAMS in 1984 and 1989 especially over northwestern Mexico. Our modeling results indicate that the land surface has memory of the initial soil wetness prescribed at the onset of the monsoon that persists over most ofmore » the region well into the monsoon season (e.g. until August). However, in contrast to the classical thermal contrast concept, where wetter soils lead to cooler surface temperatures, less land-sea thermal contrast, weaker monsoon circulations and less precipitation, the coupled model consistently demonstrated a positive soil moisture – precipitation feedback. Specifically, anomalously wet premonsoon soil moisture always lead to enhanced monsoon precipitation, and the reverse was also true. The surface temperature changes induced by differences in surface energy flux partitioning associated with pre-monsoon soil moisture anomalies changed the surface pressure and consequently the flow field in the coupled model, which in turn changed moisture convergence and, accordingly, precipitation patterns. Both the largescale circulation change and local land-atmospheric interactions in response to premonsoon soil moisture anomalies play important roles in the coupled model’s positive soil moisture monsoon precipitation feedback. However, the former may be sensitive to the strength and location of the thermal anomalies, thus leaving open the possibility of both positive and negative soil moisture precipitation feedbacks.« less

Uncertainty quantification methodologies development for stress corrosion cracking of canister welds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dingreville, Remi Philippe Michel; Bryan, Charles R.

2016-09-30

This letter report presents a probabilistic performance assessment model to evaluate the probability of canister failure (through-wall penetration) by SCC. The model first assesses whether environmental conditions for SCC – the presence of an aqueous film – are present at canister weld locations (where tensile stresses are likely to occur) on the canister surface. Geometry-specific storage system thermal models and weather data sets representative of U.S. spent nuclear fuel (SNF) storage sites are implemented to evaluate location-specific canister surface temperature and relative humidity (RH). As the canister cools and aqueous conditions become possible, the occurrence of corrosion is evaluated. Corrosionmore » is modeled as a two-step process: first, pitting is initiated, and the extent and depth of pitting is a function of the chloride surface load and the environmental conditions (temperature and RH). Second, as corrosion penetration increases, the pit eventually transitions to a SCC crack, with crack initiation becoming more likely with increasing pit depth. Once pits convert to cracks, a crack growth model is implemented. The SCC growth model includes rate dependencies on both temperature and crack tip stress intensity factor, and crack growth only occurs in time steps when aqueous conditions are predicted. The model suggests that SCC is likely to occur over potential SNF interim storage intervals; however, this result is based on many modeling assumptions. Sensitivity analyses provide information on the model assumptions and parameter values that have the greatest impact on predicted storage canister performance, and provide guidance for further research to reduce uncertainties.« less

NASA SPoRT Initialization Datasets for Local Model Runs in the Environmental Modeling System

NASA Technical Reports Server (NTRS)

Case, Jonathan L.; LaFontaine, Frank J.; Molthan, Andrew L.; Carcione, Brian; Wood, Lance; Maloney, Joseph; Estupinan, Jeral; Medlin, Jeffrey M.; Blottman, Peter; Rozumalski, Robert A.

2011-01-01

The NASA Short-term Prediction Research and Transition (SPoRT) Center has developed several products for its National Weather Service (NWS) partners that can be used to initialize local model runs within the Weather Research and Forecasting (WRF) Environmental Modeling System (EMS). These real-time datasets consist of surface-based information updated at least once per day, and produced in a composite or gridded product that is easily incorporated into the WRF EMS. The primary goal for making these NASA datasets available to the WRF EMS community is to provide timely and high-quality information at a spatial resolution comparable to that used in the local model configurations (i.e., convection-allowing scales). The current suite of SPoRT products supported in the WRF EMS include a Sea Surface Temperature (SST) composite, a Great Lakes sea-ice extent, a Greenness Vegetation Fraction (GVF) composite, and Land Information System (LIS) gridded output. The SPoRT SST composite is a blend of primarily the Moderate Resolution Imaging Spectroradiometer (MODIS) infrared and Advanced Microwave Scanning Radiometer for Earth Observing System data for non-precipitation coverage over the oceans at 2-km resolution. The composite includes a special lake surface temperature analysis over the Great Lakes using contributions from the Remote Sensing Systems temperature data. The Great Lakes Environmental Research Laboratory Ice Percentage product is used to create a sea-ice mask in the SPoRT SST composite. The sea-ice mask is produced daily (in-season) at 1.8-km resolution and identifies ice percentage from 0 100% in 10% increments, with values above 90% flagged as ice.

III-V compound semiconductor growth on silicon via germanium buffer and surface passivation for CMOS technology

NASA Astrophysics Data System (ADS)

Choi, Donghun

Integration of III-V compound semiconductors on silicon substrates has recently received much attention for the development of optoelectronic and high speed electronic devices. However, it is well known that there are some key challenges for the realization of III-V device fabrication on Si substrates: (i) the large lattice mismatch (in case of GaAs: 4.1%), and (ii) the formation of antiphase domain (APD) due to the polar compound semiconductor growth on non-polar elemental structure. Besides these growth issues, the lack of a useful surface passivation technology for compound semiconductors has precluded development of metal-oxide-semiconductor (MOS) devices and causes high surface recombination parasitics in scaled devices. This work demonstrates the growth of high quality III-V materials on Si via an intermediate Ge buffer layer and some surface passivation methods to reduce interface defect density for the fabrication of MOS devices. The initial goal was to achieve both low threading dislocation density (TDD) and low surface roughness on Ge-on-Si heterostructure growth. This was achieved by repeating a deposition-annealing cycle consisting of low temperature deposition + high temperature-high rate deposition + high temperature hydrogen annealing, using reduced-pressure chemical-vapor deposition (CVD). We then grew III-V materials on the Ge/Si virtual substrates using molecular-beam epitaxy (MBE). The relationship between initial Ge surface configuration and antiphase boundary formation was investigated using surface reflection high-energy electron diffraction (RHEED) patterns and atomic force microscopy (AFM) image analysis. In addition, some MBE growth techniques, such as migration enhanced epitaxy (MEE) and low temperature GaAs growth, were adopted to improve surface roughness and solve the Ge self-doping problem. Finally, an Al2O3 gate oxide layer was deposited using atomic-layer-deposition (ALD) system after HCl native oxide etching and ALD in-situ pre-annealing at 400 °C. A 100 nm thick aluminum layer was deposited to form the gate contact for a MOS device fabrication. C-V measurement results show very small frequency dispersion and 200-300 mV hysteresis, comparable to our best results for InGaAs/GaAs MOS structures on GaAs substrate. Most notably, the quasi-static C-V curve demonstrates clear inversion layer formation. I-V curves show a reasonable leakage current level. The inferred midgap interface state density, Dit, of 2.4 x 1012 eV-1cm-2 was calculated by combined high-low frequency capacitance method. In addition, we investigated the interface properties of amorphous LaAlO 3/GaAs MOS capacitors fabricated on GaAs substrate. The surface was protected during sample transfer between III-V and oxide molecular beam deposition (MBD) chambers by a thick arsenic-capping layer. An annealing method, a low temperature-short time RTA followed by a high temperature RTA, was developed, yielding extremely small hysteresis (˜ 30 mV), frequency dispersion (˜ 60 mV), and interface trap density (mid 1010 eV-1cm -2). We used capacitance-voltage (C-V) and current-voltage (I-V) measurements for electrical characterization of MOS devices, tapping-mode AFM for surface morphology analysis, X-ray photoelectron spectroscopy (XPS) for chemical elements analysis of interface, cross section transmission-electron microscopy (TEM), X-ray diffraction (XRD), secondary ion mass spectrometry (SIMS), and photoluminescence (PL) measurement for film quality characterization. This successful growth and appropriate surface treatments of III-V materials provides a first step for the fabrication of III-V optical and electrical devices on the same Si-based electronic circuits.

Verification and transfer of thermal pollution model. Volume 4: User's manual for three-dimensional rigid-lid model

NASA Technical Reports Server (NTRS)

Lee, S. S.; Nwadike, E. V.; Sinha, S. E.

1982-01-01

The theory of a three dimensional (3-D) mathematical thermal discharge model and a related one dimensional (1-D) model are described. Model verification at two sites, a separate user's manual for each model are included. The 3-D model has two forms: free surface and rigid lid. The former allows a free air/water interface and is suited for significant surface wave heights compared to mean water depth, estuaries and coastal regions. The latter is suited for small surface wave heights compared to depth because surface elevation was removed as a parameter. These models allow computation of time dependent velocity and temperature fields for given initial conditions and time-varying boundary conditions. The free surface model also provides surface height variations with time.

Power-law Magnetic Field Decay and Constant Core Temperatures of Magnetars, Normal and Millisecond Pulsars

NASA Astrophysics Data System (ADS)

Xie, Y.; Zhang, S.

2011-12-01

The observed correlations, between the characteristic ages and dipole surface magnetic field strengths of all pulsars, can be well explained by magnetic field decay with core temperatures of 2×108 K, ˜2×107 K, and ˜105 K, for magnetars, normal radio pulsars, and millisecond pulsars, respectively; assuming that their characteristic ages are about two orders of magnitude larger than their true ages, the required core temperatures may be reduced by about a factor of 10. The magnetic decay follows a power-law and is dominated by the solenoidal component of the ambipolar diffusion mode. In this model, all NSs are assumed to have the same initial magnetic field strength, but different core temperature which does not change as the magnetic field decays. This suggests that the key distinguishing property between magnetars and normal pulsars is that magnetars were born much hotter than normal pulsars, and thus have much longer magnetic field decay time scales, resulting in higher surface magnetic field strength even with the same ages of normal pulsars. The above conclusion agrees well with the observed correlations between the surface temperatures of magnetars and other young NSs, which do not agree with the cooling dominated evolution of neutron stars. This suggests a possible scenario that heating, perhaps due to magnetic field decay, balances neutron star cooling for observed pulsars.

Initiation of clement surface conditions on the earliest Earth

PubMed Central

Sleep, N. H.; Zahnle, K.; Neuhoff, P. S.

2001-01-01

In the beginning the surface of the Earth was extremely hot, because the Earth as we know it is the product of a collision between two planets, a collision that also created the Moon. Most of the heat within the very young Earth was lost quickly to space while the surface was still quite hot. As it cooled, the Earth's surface passed monotonically through every temperature regime between silicate vapor to liquid water and perhaps even to ice, eventually reaching an equilibrium with sunlight. Inevitably the surface passed through a time when the temperature was around 100°C at which modern thermophile organisms live. How long this warm epoch lasted depends on how long a thick greenhouse atmosphere can be maintained by heat flow from the Earth's interior, either directly as a supplement to insolation, or indirectly through its influence on the nascent carbonate cycle. In both cases, the duration of the warm epoch would have been controlled by processes within the Earth's interior where buffering by surface conditions played little part. A potentially evolutionarily significant warm period of between 105 and 107 years seems likely, which nonetheless was brief compared to the vast expanse of geological time. PMID:11259665

Initiation of clement surface conditions on the earliest Earth.

PubMed

Sleep, N H; Zahnle, K; Neuhoff, P S

2001-03-27

In the beginning the surface of the Earth was extremely hot, because the Earth as we know it is the product of a collision between two planets, a collision that also created the Moon. Most of the heat within the very young Earth was lost quickly to space while the surface was still quite hot. As it cooled, the Earth's surface passed monotonically through every temperature regime between silicate vapor to liquid water and perhaps even to ice, eventually reaching an equilibrium with sunlight. Inevitably the surface passed through a time when the temperature was around 100 degrees C at which modern thermophile organisms live. How long this warm epoch lasted depends on how long a thick greenhouse atmosphere can be maintained by heat flow from the Earth's interior, either directly as a supplement to insolation, or indirectly through its influence on the nascent carbonate cycle. In both cases, the duration of the warm epoch would have been controlled by processes within the Earth's interior where buffering by surface conditions played little part. A potentially evolutionarily significant warm period of between 10(5) and 10(7) years seems likely, which nonetheless was brief compared to the vast expanse of geological time.

Formation and characterization of perpendicular mode Si ripples by glancing angle O{sub 2}{sup +} sputtering at room temperature

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mollick, S. A.; Ghose, D.

Off-normal low energy ion beam sputtering of solid surfaces often leads to morphological instabilities resulting in the spontaneous formation of ripple structures in nanometer length scales. In the case of Si surfaces at ambient temperature, ripple formation is found to take place normally at lower incident angles with the wave vector parallel to the ion beam direction. The absence of ripple pattern on Si surface at larger angles is due to the dominance of ion beam polishing effect. We have shown that a gentle chemical roughening of the starting surface morphology can initiate ripple pattern under grazing incidence ion beammore » sputtering (theta>64 deg. with respect to the surface normal), where the ripple wave vector is perpendicular to the ion beam direction. The characteristics of the perpendicular mode ripples are studied as a function of pristine surface roughness (2-30 nm) and projectile fluence (5x10{sup 16}-1.5x10{sup 18} O atoms cm{sup -2}). The quality of the morphological structure is assessed from the analysis of ion induced topological defects.« less

Effect of flaw size and temperature on the matrix cracking behavior of a brittle ceramic matrix composite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anandakumar, U.; Webb, J.E.; Singh, R.N.

The matrix cracking behavior of a zircon matrix - uniaxial SCS 6 fiber composite was studied as a function of initial flaw size and temperature. The composites were fabricated by a tape casting and hot pressing technique. Surface flaws of controlled size were introduced using a vicker`s indenter. The composite samples were tested in three point flexure at three different temperatures to study the non steady state and steady state matrix cracking behavior. The composite samples exhibited steady state and non steady matrix cracking behavior at all temperatures. The steady state matrix cracking stress and steady state crack size increasedmore » with increasing temperature. The results of the study correlated well with the results predicted by the matrix cracking models.« less

A new temperature- and humidity-dependent surface site density approach for deposition ice nucleation

NASA Astrophysics Data System (ADS)

Steinke, I.; Hoose, C.; Möhler, O.; Connolly, P.; Leisner, T.

2015-04-01

Deposition nucleation experiments with Arizona Test Dust (ATD) as a surrogate for mineral dusts were conducted at the AIDA cloud chamber at temperatures between 220 and 250 K. The influence of the aerosol size distribution and the cooling rate on the ice nucleation efficiencies was investigated. Ice nucleation active surface site (INAS) densities were calculated to quantify the ice nucleation efficiency as a function of temperature, humidity and the aerosol surface area concentration. Additionally, a contact angle parameterization according to classical nucleation theory was fitted to the experimental data in order to relate the ice nucleation efficiencies to contact angle distributions. From this study it can be concluded that the INAS density formulation is a very useful tool to describe the temperature- and humidity-dependent ice nucleation efficiency of ATD particles. Deposition nucleation on ATD particles can be described by a temperature- and relative-humidity-dependent INAS density function ns(T, Sice) with ns(xtherm) = 1.88 ×105 · exp(0.2659 · xtherm) [m-2] , (1) where the temperature- and saturation-dependent function xtherm is defined as xtherm = -(T-273.2)+(Sice-1) ×100, (2) with the saturation ratio with respect to ice Sice >1 and within a temperature range between 226 and 250 K. For lower temperatures, xtherm deviates from a linear behavior with temperature and relative humidity over ice. Also, two different approaches for describing the time dependence of deposition nucleation initiated by ATD particles are proposed. Box model estimates suggest that the time-dependent contribution is only relevant for small cooling rates and low number fractions of ice-active particles.

Toward Improved Land Surface Initialization in Support of Regional WRF Forecasts at the Kenya Meteorological Service (KMS)

NASA Technical Reports Server (NTRS)

Case, Johnathan L.; Mungai, John; Sakwa, Vincent; Kabuchanga, Eric; Zavodsky, Bradley T.; Limaye, Ashutosh S.

2014-01-01

Flooding and drought are two key forecasting challenges for the Kenya Meteorological Service (KMS). Atmospheric processes leading to excessive precipitation and/or prolonged drought can be quite sensitive to the state of the land surface, which interacts with the planetary boundary layer (PBL) of the atmosphere providing a source of heat and moisture. The development and evolution of precipitation systems are affected by heat and moisture fluxes from the land surface, particularly within weakly-sheared environments such as in the tropics and sub-tropics. These heat and moisture fluxes during the day can be strongly influenced by land cover, vegetation, and soil moisture content. Therefore, it is important to represent the land surface state as accurately as possible in land surface and numerical weather prediction (NWP) models. Enhanced regional modeling capabilities have the potential to improve forecast guidance in support of daily operations and high-impact weather over eastern Africa. KMS currently runs a configuration of the Weather Research and Forecasting (WRF) NWP model in real time to support its daily forecasting operations, making use of the NOAA/National Weather Service (NWS) Science and Training Resource Center's Environmental Modeling System (EMS) to manage and produce the KMS-WRF runs on a regional grid over eastern Africa. Two organizations at the NASA Marshall Space Flight Center in Huntsville, AL, SERVIR and the Shortterm Prediction Research and Transition (SPoRT) Center, have established a working partnership with KMS for enhancing its regional modeling capabilities through new datasets and tools. To accomplish this goal, SPoRT and SERVIR is providing enhanced, experimental land surface initialization datasets and model verification capabilities to KMS as part of this collaboration. To produce a land-surface initialization more consistent with the resolution of the KMS-WRF runs, the NASA Land Information System (LIS) is run at a comparable resolution to provide real-time, daily soil initialization data in place of data interpolated from the National Centers for Environmental Prediction (NCEP) Global Forecast System (GFS) model soil moisture and temperature fields. Additionally, realtime green vegetation fraction (GVF) data from the Visible Infrared Imaging Radiometer Suite (VIIRS) on the Suomi National Polar-orbiting Partnership (Suomi- NPP) satellite will be incorporated into the KMS-WRF runs, once it becomes publicly available from the National Environmental Satellite Data and Information Service (NESDIS). Finally, model verification capabilities will be transitioned to KMS using the Model Evaluation Tools (MET; Brown et al. 2009) package in conjunction with a dynamic scripting package developed by SPoRT (Zavodsky et al. 2014), to help quantify possible improvements in simulated temperature, moisture and precipitation resulting from the experimental land surface initialization. Furthermore, the transition of these MET tools will enable KMS to monitor model forecast accuracy in near real time. This paper presents preliminary efforts to improve land surface model initialization over eastern Africa in support of operations at KMS. The remainder of this extended abstract is organized as follows: The collaborating organizations involved in the project are described in Section 2; background information on LIS and the configuration for eastern Africa is presented in Section 3; the WRF configuration used in this modeling experiment is described in Section 4; sample experimental WRF output with and without LIS initialization data are given in Section 5; a summary is given in Section 6 followed by acknowledgements and references.

Experimental Study of the Stability of Aircraft Fuels at Elevated Temperatures

NASA Technical Reports Server (NTRS)

Vranos, A.; Marteney, P. J.

1980-01-01

An experimental study of fuel stability was conducted in an apparatus which simulated an aircraft gas turbine fuel system. Two fuels were tested: Jet A and Number 2 Home Heating oil. Jet A is an aircraft gas turbine fuel currently in wide use. No. 2HH was selected to represent the properties of future turbine fuels, particularly experimental Reference Broad Specification, which, under NASA sponsorship, was considered as a possible next-generation fuel. Tests were conducted with varying fuel flow rates, delivery pressures and fuel pretreatments (including preheating and deoxygenation). Simulator wall temperatures were varied between 422K and 672K at fuel flows of 0.022 to 0.22 Kg/sec. Coking rate was determined at four equally-spaced locations along the length of the simulator. Fuel samples were collected for infrared analysis. The dependence of coking rate in Jet A may be correlated with surface temperature via an activation energy of 9 to 10 kcal/mole, although the results indicate that both bulk fluid and surface temperature affect the rate of decomposition. As a consequence, flow rate, which controls bulk temperature, must also be considered. Taken together, these results suggest that the decomposition reactions are initiated on the surface and continue in the bulk fluid. The coking rate data for No. 2 HH oil are very highly temperature dependent above approximately 533K. This suggests that bulk phase reactions can become controlling in the formation of coke.

Dissociative chemisorption of methane on metal surfaces: Tests of dynamical assumptions using quantum models and ab initio molecular dynamics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jackson, Bret, E-mail: jackson@chem.umass.edu; Nattino, Francesco; Kroes, Geert-Jan

The dissociative chemisorption of methane on metal surfaces is of great practical and fundamental importance. Not only is it the rate-limiting step in the steam reforming of natural gas, the reaction exhibits interesting mode-selective behavior and a strong dependence on the temperature of the metal. We present a quantum model for this reaction on Ni(100) and Ni(111) surfaces based on the reaction path Hamiltonian. The dissociative sticking probabilities computed using this model agree well with available experimental data with regard to variation with incident energy, substrate temperature, and the vibrational state of the incident molecule. We significantly expand the vibrationalmore » basis set relative to earlier studies, which allows reaction probabilities to be calculated for doubly excited initial vibrational states, though it does not lead to appreciable changes in the reaction probabilities for singly excited initial states. Sudden models used to treat the center of mass motion parallel to the surface are compared with results from ab initio molecular dynamics and found to be reasonable. Similar comparisons for molecular rotation suggest that our rotationally adiabatic model is incorrect, and that sudden behavior is closer to reality. Such a model is proposed and tested. A model for predicting mode-selective behavior is tested, with mixed results, though we find it is consistent with experimental studies of normal vs. total (kinetic) energy scaling. Models for energy transfer into lattice vibrations are also examined.« less

Spinal cord, hypothalamic, and air temperature: interaction with arousal states in the marmot.

PubMed

Miller, V M; South, F E

1979-01-01

Yellow-bellied marmots, Marmota flaviventris, prepared with U-shaped thermodes in the epidural space of the thoracic vertebral canal, a thermode in the preoptic hypothalamus, and cortical surface and hippocampal electrodes, were used to investigate the interaction of arousal states with temperature regulation. It was found that arousal state of the animal influences the thermoregulatory responses initiated in either the spinal cord or hypothalamus. Further, changes in ambient temperature affected both the gain and the threshold of these responses. The interaction of the hypothalamus and spinal cord was not an additive function, however the threshold for shivering of each could be altered by temperature manipulation of the other. Future studies in modeling of temperature regulation should consider the contributions of temperature receptors of the spinal cord and the arousal state of the animal during the stimulation period.

Thermal testing results of an electroformed nickel secondary (M2) mirror

NASA Astrophysics Data System (ADS)

Smith, David R.; Gale, David M.; Cabrera Cuevas, Lizeth; Lucero Álvarez, Maribel; Castro Santos, David; Olmos Tapia, Arak

2016-07-01

To support higher-frequency operation, the Large Millimeter Telescope/Gran Telescopio Milimetrico (or LMT/GTM) is replacing its existing monolithic aluminum secondary mirror (M2). The new mirror is a segmented design based on the same electroformed nickel reflector panel technology that is already in use for the primary reflector segments. While the new M2 is lighter and has better surface accuracy than the original mirror, the electroformed panels are more sensitive to high temperatures. During the design phase, concerns were raised over the level of temperature increase that could occur at M2 during daytime observations. Although the panel surface is designed to scatter visible light, the LMT primary mirror is large enough to cause substantial solar heating, even at significant angular separation from the Sun. To address these concerns, the project conducted a series of field tests, within the constraint of having minimum impact on night time observations. The supplier sent two coupon samples of a reflector panel prepared identically to their proposed M2 surface. Temperature sensors were mounted on the samples and they were temporarily secured to the existing M2 mirror at different distances from the center. The goal was to obtain direct monitoring of the surface temperature under site thermal conditions and the concentration effects from the primary reflector. With the sensors installed, the telescope was then commanded to track the Sun with an elevation offset. Initially, elevation offsets from as far as 40 degrees to as close as 6 degrees were tested. The 6 degree separation test quickly passed the target maximum temperature and the telescope was returned to a safer separation. Based on these initial results, a second set of tests was performed using elevation separations from 30 degrees to 8 degrees. To account for the variability of site conditions, the temperature data were analyzed using multiple metrics. These metrics included maximum temperature, final time average temperature, and an curve fit for heating/ cooling. The results indicate that a solar separation angle of 20 degrees should be suitable for full performance operation of the LMT/GTM. This separation not only is sufficient to avoid high temperatures at the mirror, but also provides time to respond to any emergency conditions that could occur (e.g., switching to a generator after a power failure) for observations that are ahead of the motion of the Sun. Additionally, even approaches of 10 to 15 degrees of angular separation on the sky may be achievable for longer wavelength observations, though these would likely be limited to positions that are behind the position of the Sun along its motion.

Regional evapotranspiration from an image-based implementation of the Surface Temperature Initiated Closure (STIC1.2) model and its validation across an aridity gradient in the conterminous US

NASA Astrophysics Data System (ADS)

Bhattarai, Nishan; Mallick, Kaniska; Brunsell, Nathaniel A.; Sun, Ge; Jain, Meha

2018-04-01

Recent studies have highlighted the need for improved characterizations of aerodynamic conductance and temperature (gA and T0) in thermal remote-sensing-based surface energy balance (SEB) models to reduce uncertainties in regional-scale evapotranspiration (ET) mapping. By integrating radiometric surface temperature (TR) into the Penman-Monteith (PM) equation and finding analytical solutions of gA and T0, this need was recently addressed by the Surface Temperature Initiated Closure (STIC) model. However, previous implementations of STIC were confined to the ecosystem-scale using flux tower observations of infrared temperature. This study demonstrates the first regional-scale implementation of the most recent version of the STIC model (STIC1.2) that integrates the Moderate Resolution Imaging Spectroradiometer (MODIS) derived TR and ancillary land surface variables in conjunction with NLDAS (North American Land Data Assimilation System) atmospheric variables into a combined structure of the PM and Shuttleworth-Wallace (SW) framework for estimating ET at 1 km × 1 km spatial resolution. Evaluation of STIC1.2 at 13 core AmeriFlux sites covering a broad spectrum of climates and biomes across an aridity gradient in the conterminous US suggests that STIC1.2 can provide spatially explicit ET maps with reliable accuracies from dry to wet extremes. When observed ET from one wet, one dry, and one normal precipitation year from all sites were combined, STIC1.2 explained 66 % of the variability in observed 8-day cumulative ET with a root mean square error (RMSE) of 7.4 mm/8-day, mean absolute error (MAE) of 5 mm/8-day, and percent bias (PBIAS) of -4 %. These error statistics showed relatively better accuracies than a widely used but previous version of the SEB-based Surface Energy Balance System (SEBS) model, which utilized a simple NDVI-based parameterization of surface roughness (zOM), and the PM-based MOD16 ET. SEBS was found to overestimate (PBIAS = 28 %) and MOD16 was found to underestimate ET (PBIAS = -26 %). The performance of STIC1.2 was better in forest and grassland ecosystems as compared to cropland (20 % underestimation) and woody savanna (40 % overestimation). Model inter-comparison suggested that ET differences between the models are robustly correlated with gA and associated roughness length estimation uncertainties which are intrinsically connected to TR uncertainties, vapor pressure deficit (DA), and vegetation cover. A consistent performance of STIC1.2 in a broad range of hydrological and biome categories, as well as the capacity to capture spatio-temporal ET signatures across an aridity gradient, points to the potential for this simplified analytical model for near-real-time ET mapping from regional to continental scales.

Evidence for a Southern Pattern of Deglacial Surface Warming in the Eastern Equatorial Pacific

NASA Astrophysics Data System (ADS)

Spero, H. J.; Schmidt, M. W.; Lea, D. W.; Lavagnino, L.

2009-12-01

The timing of both Southern and Northern hemisphere warming patterns has been used to explain tropical Pacific warming at the end of the last glacial period. Despite the importance of resolving this deglacial tropical-polar connection, the controversy is still ongoing (Koutavas & Sachs, 2008; Lea et al., 2000, 2006). For instance, the initiation of eastern equatorial Pacific (EEP) surface warming, derived from Mg/Ca analyses of the surface-dwelling foraminifera Globigerinoides ruber, shows a clear correlation with the Southern hemisphere. In contrast, alkenone-derived temperatures from the EEP indicate tropical warming occurred at least 3 kyr later than that implied from Mg/Ca data, thereby suggesting a Northern hemisphere link to initial SST rise. Here, we use a multispecies, multiproxy approach that is based on fundamental foraminifera biology to resolve this controversy. Laboratory experiments demonstrate the final shell size of symbiont-bearing foraminifera varies primarily as a function of the light level (=symbiont photosynthetic rate) that an individual grew under. Because light decreases exponentially in the water column, and the EEP is highly stratified with a shallow mixed layer and cold thermocline, we hypothesize that symbiotic foraminifera with a broad habitat range such as Globigerinoides sacculifer, should produce smaller shells in the more dimly lit cold thermocline than individuals growing in the more illuminated mixed layer. Moreover, these larger shells should contain a temperature signal that is similar to G. ruber, which is constrained to the shallow mixed layer. Mg/Ca and δ18O analyses conducted on 350-400 μm and >650 μm sized G. sacculifer from EEP core TR163-19 (2N, 91W, 2348) demonstrate large specimens yield Mg/Ca and δ18O that are similar to data published previously for mixed layer dwelling G. ruber. In contrast, small G. sacculifer record significantly higher δ18O and lower Mg/Ca temperatures that are consistent with a shallow thermocline habitat. More important, the timing of warming for the large G. sacculifer is similar to that of G. ruber, whereas thermocline temperatures recorded by small G. sacculifer increase nearly 3 kyr later, in close agreement with alkenone temperature change. These results link EEP surface warming to the Southern hemisphere and suggest that 1) early deglacial alkenone data are recording thermocline rather than mixed layer temperatures and 2) EEP thermocline temperature increase is more closely linked to Northern, rather than Southern hemisphere dynamics.

Evolution of Morphology and Crystallinity of Silica Minerals Under Hydrothermal Conditions

NASA Astrophysics Data System (ADS)

Isobe, H.

2011-12-01

Silica minerals are quite common mineral species in surface environment of the terrestrial planets. They are good indicator of terrestrial processes including hydrothermal alteration, diagenesis and soil formation. Hydrothermal quartz, metastable low temperature cristobalite and amorphous silica show characteristic morphology and crystallinity depending on their formation processes and kinetics under wide range of temperature, pressure, acidity and thermal history. In this study, silica minerals produced by acidic hydrothermal alteration related to volcanic activities and hydrothermal crystallization experiments from diatom sediment are examined with crystallographic analysis and morphologic observations. Low temperature form of cistobalite is a metastable phase and a common alteration product occured in highly acidic hydrothermal environment around fumaroles in geothermal / volcanic areas. XRD analysis revealed that the alteration degree of whole rock is represented by abundance of cristobalite. Detailed powder XRD analysis show that the primary diffraction peak of cristobalite composed with two or three phases with different d-spacing and FWHM by peak profile fitting analysis. Shorter d-spacing and narrower FWHM cristobalite crystallize from precursor materials with less-crystallized, longer d-spacing and wider FWHM cristobalite. Textures of hydrothermal cristobalite in altered rock shows remnant of porphylitic texture of the host rock, pyroxene-amphibole andesite. Diatom has amorphous silica shell and makes diatomite sediment. Diatomite found in less diagenetic Quarternary formation keeps amorphous silica diatom shells. Hydrothermal alteration experiments of amorphous silica diatomite sediment are carried out from 300 °C to 550 °C. Mineral composition of run products shows crystallization of cristobalite and quartz progress depending on temperature and run durations. Initial crystallization product, cristobalite grains occur as characteristic lepispheres and granules with various surface structures. At the very initial stage of cristobalite crystallization within 2 days run duration, cristobalite shows lepispheres a few micron meters in diameter with irregular, submicron scale ridges and grooves on the surface. With the run duration up to 7 days, lepispheres change to granules with smooth surface remaining a few micron meters in diameter. Crystallinity of cristobalite lepispheres and granules corresponds to opal-CT. Euhedral quartz crystals grow with dissolution of cristobalite grains. Growth rate of cristobalite and quartz is controlled by crystallization kinetics with induction period strongly depending on temperature. Induction period of cristobalite crystallization from amorphous silica may exceed several million years at temperature below 100 °C. Crystallinity, morphology and growth rate of silica minerals occurred in various terrestrial and planetary processes are controlled by temperature and acidity of hydrothermal fluid and nucleation and growth kinetics of silica minerals.

Ultrasonic Attenuation of Surface Acoustic Waves in Thin Films of High Transition Temperature Superconducting Niobium-Tin and Niobium-Nitride

NASA Astrophysics Data System (ADS)

Fredricksen, Hans Peter

The ultrasonic attenuation of 600-700 MHz surface acoustic waves by two high T(,c), cubic crystal structure, superconducting thin films has been investigated. The films studied were two, 0.5 (mu) thin, Nb(,3)Sn samples, electron-beam codeposited on LiNbO(,3) and Quartz, and eleven NbN samples from 3 x 10('3) (ANGSTROM) to <(, )200 (ANGSTROM) thin, sputter deposited on LiNbO(,3). The Nb(,3)Sn (Al5 structure) film on Quartz was difficult to measure due to defects in the Quartz caused by the high deposition temperature ((DBLTURN)700(DEGREES)C) used to make the high T(,c) form of the compound. The Nb(,3)Sn film on LiNbO(,3), however, provided information about the transition temperature and energy gap at T = 0 K when the attenuation was measured as a function of temperature in zero magnetic field. A theory is developed to predict the electron-phonon produced normal state attenuation of surface acoustic waves by a thin, loss producing film on a nonattenuating substrate. Using a viscous drag model for the attenuation, the predictions of the theory are compared to the measured normal state attenuation to find the electron mean-free-path for the Nb(,3)Sn film on LiNbO(,3). The attenuation measured for this film as a function of applied magnetic field for four temperatures below T(,c) showed the sample to be an impurity rich type II superconductor with H(,c(,2)) (T = 0 K) = 85 KG, having GLAG theory constants: (kappa)(,2)(t=1) = 28.5 and (kappa)(t=1) = 29.2. The attenuation curves of the nine thickest NbN samples were non-BCS-like and very similar. Measured as a function of temperature only, because we could not reach the high critical fields of the samples, the attenuation showed an initial drop at T(,c) of about 1-2 dB which then leveled off until the temperature was below 0.5 T(,c), where the rate of decrease was much slower than the initial drop. A qualitative description of this behavior is derived from the Kosterlitz-Thouless vortex-antivortex theory. Although the thinnest NbN film did not show an attenuation change at T(,c), the next thinnest did. In this case, the measured decrease of nearly 40 dB is explained by the change in boundary condition when the substrate surface changes from "open" to "shortened" when the film becomes superconducting.

Grafting methyl acrylic onto carbon fiber via Diels-Alder reaction for excellent mechanical and tribological properties of phenolic composites

NASA Astrophysics Data System (ADS)

Fei, Jie; Duan, Xiao; Luo, Lan; Zhang, Chao; Qi, Ying; Li, Hejun; Feng, Yongqiang; Huang, Jianfeng

2018-03-01

Carbon fibers (CFs) were grafted with methyl acrylic via Diels-Alder reaction at the different oil bath temperature effectively creating a carboxyl functionalized surface. The effect of grafting temperature on the surface morphology and functional groups of carbon fibers were investigated by FTIR, Raman spectroscopy, XPS and SEM respectively. The results showed that the optimal grafting temperature was 80 °C, and the relative surface coverage by carboxylic acid groups increased from an initial 5.16% up to 19.30% significantly improved the chemical activity without damaging the skin and core region of the carbon fibers. Mechanical property tests indicated that the shear and tensile strength of the sample with the grafting temperature of 80 °C (CFRP-3) increased obviously by 90.3% and 78.7%, respectively, compared with the pristine carbon fibers reinforced composite. Further, the sample CFRP-3 exhibited higher and more stable friction coefficient and improved wear resistance, while the wear rate decreased 52.7%, from 10.8 × 10-6 to 5.1 × 10-6 mm3/N m. The present work shows that grafting methyl acrylic via Diels-Alder reaction could be a highly efficient and facile method to functionalize carbon fibers for advanced composites.

Linking Satellite Derived Land Surface Temperature with Cholera: A Case Study for South Sudan

NASA Astrophysics Data System (ADS)

Aldaach, H. S. V.; Jutla, A.; Akanda, A. S.; Colwell, R. R.

2014-12-01

A sudden onset of cholera in South Sudan, in April 2014 in Northern Bari in Juba town resulted in more than 400 cholera cases after four weeks of initial outbreak with a case of fatality rate of CFR 5.4%. The total number of reported cholera cases for the period of April to July, 2014 were 5,141 including 114 deaths. With the limited efficacy of cholera vaccines, it is necessary to develop mechanisms to predict cholera occurrence and thereafter devise intervention strategies for mitigating impacts of the disease. Hydroclimatic processes, primarily precipitation and air temperature are related to epidemic and episodic outbreak of cholera. However, due to coarse resolution of both datasets, it is not possible to precisely locate the geographical location of disease. Here, using Land Surface Temperature (LST) from MODIS sensors, we have developed an algorithm to identify regions susceptible for cholera. Conditions for occurrence of cholera were detectable at least one month in advance in South Sudan and were statistically sensitive to hydroclimatic anomalies of land surface and air temperature, and precipitation. Our results indicate significant spatial and temporal averaging required to infer usable information from LST over South Sudan. Preliminary results that geographically location of cholera outbreak was identifiable within 1km resolution of the LST data.

The Nanoconfined Free Radical Polymerization: Reaction Kinetics and Thermodynamics

NASA Astrophysics Data System (ADS)

Zhao, Haoyu; Simon, Sindee

The reaction kinetics and thermodynamics of nanoconfined free radical polymerizations are investigated for methyl methacrylate (MMA) and ethyl methacrylate (EMA) monomers using differential scanning calorimetry. Controlled pore glass is used as the confinement medium with pore diameters as small as 7.5 nm; the influence of both hydrophobic (silanized such that trimethylsilyl groups cover the surface) and hydrophilic (native silanol) surfaces is investigated. Propagation rates increase when monomers are reacted in the hydrophilic pores presumably due to the specific interactions between the carbonyl and silanol groups; however, the more flexible EMA monomer shows weaker effects. On the other hand, initial rates of polymerization in hydrophobic pores are unchanged from the bulk. In both pores, the onset of autoacceleration occurs earlier due to the reduced diffusivity of confined chains, which may be compensated at high temperatures. In addition to changes in kinetics, the reaction thermodynamics can be affected under nanoconfinement. Specifically, the ceiling temperature (Tc) is shifted to lower temperatures in nanopores, with pore surface chemistry showing no significant effects; the equilibrium conversion is also reduced at high temperatures below Tc. These observations are attributed to a larger negative change in entropy on propagation for the confined system, with the MMA system again showing greater effects. Funding from ACS PRF is gratefully acknowledged.

Epitaxial GaN layers formed on langasite substrates by the plasma-assisted MBE method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lobanov, D. N., E-mail: dima@ipmras.ru; Novikov, A. V.; Yunin, P. A.

2016-11-15

In this publication, the results of development of the technology of the epitaxial growth of GaN on single-crystal langasite substrates La{sub 3}Ga{sub 5}SiO{sub 14} (0001) by the plasma-assisted molecular-beam epitaxy (PA MBE) method are reported. An investigation of the effect of the growth temperature at the initial stage of deposition on the crystal quality and morphology of the obtained GaN layer is performed. It is demonstrated that the optimal temperature for deposition of the initial GaN layer onto the langasite substrate is about ~520°C. A decrease in the growth temperature to this value allows the suppression of oxygen diffusion frommore » langasite into the growing layer and a decrease in the dislocation density in the main GaN layer upon its subsequent high-temperature deposition (~700°C). Further lowering of the growth temperature of the nucleation layer leads to sharp degradation of the GaN/LGS layer crystal quality. As a result of the performed research, an epitaxial GaN/LGS layer with a dislocation density of ~10{sup 11} cm{sup –2} and low surface roughness (<2 nm) is obtained.« less

Cost/performance of solar reflective surfaces for parabolic dish concentrators

NASA Technical Reports Server (NTRS)

Bouquet, F.

1980-01-01

Materials for highly reflective surfaces for use in parabolic dish solar concentrators are discussed. Some important factors concerning performance of the mirrors are summarized, and typical costs are treated briefly. Capital investment cost/performance ratios for various materials are computed specifically for the double curvature parabolic concentrators using a mathematical model. The results are given in terms of initial investment cost for reflective surfaces per thermal kilowatt delivered to the receiver cavity for various operating temperatures from 400 to 1400 C. Although second surface glass mirrors are emphasized, first surface, chemically brightened and anodized aluminum surfaces as well as second surface, metallized polymeric films are treated. Conventional glass mirrors have the lowest cost/performance ratios, followed closely by aluminum reflectors. Ranges in the data due to uncertainties in cost and mirror reflectance factors are given.

Oxidation behavior of multiwall carbon nanotubes with different diameters and morphology

NASA Astrophysics Data System (ADS)

Mazov, Ilya; Kuznetsov, Vladimir L.; Simonova, Irina A.; Stadnichenko, Andrey I.; Ishchenko, Arkady V.; Romanenko, Anatoly I.; Tkachev, Evgeniy N.; Anikeeva, Olga B.

2012-06-01

Multiwall carbon nanotubes (MWNT) with three medium diameters (20-22, 9-13, and 6-8 nm) and different morphology were chemically oxidized using concentrated nitric acid, mixture of nitric and sulfuric acids ("mélange" solution) and mixture of sulfuric acid and hydrogen peroxide ("piranha" solution). Influence of MWNT type and structure as well as type of oxidizer on the surface composition and structure of nanotubes after oxidation was investigated. Acid-base titration, X-ray photoelectron spectroscopy and thermal gravimetric analysis were used for quantitative and qualitative investigation of surface group composition of initial and oxidized nanotubes. Amount of oxygen-containing groups on the surface of oxidized MWNT depends on the type of initial MWNT. It was found that ratio of different oxygen containing groups is less dependent on the type of oxidizer. Electrophysical properties of initial and oxidized nanotubes were investigated in temperature range 4-293 K and main types of electrical conductivity were determined. It was shown that oxidation results in decrease in electrical conductivity of all samples with simultaneous change in the conductivity mechanism. Dispersive behavior of initial and oxidized nanotubes in different commonly used solvents was investigated. It was shown that oxidation leads to the improvement of sedimentation stability of MWNT in polar solvents.

Surface Variability of Short-wavelength Radiation and Temperature on Exoplanets around M Dwarfs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Xin; Tian, Feng; Wang, Yuwei

2017-03-10

It is a common practice to use 3D General Circulation Models (GCM) with spatial resolution of a few hundred kilometers to simulate the climate of Earth-like exoplanets. The enhanced albedo effect of clouds is especially important for exoplanets in the habitable zones around M dwarfs that likely have fixed substellar regions and substantial cloud coverage. Here, we carry out mesoscale model simulations with 3 km spatial resolution driven by the initial and boundary conditions in a 3D GCM and find that it could significantly underestimate the spatial variability of both the incident short-wavelength radiation and the temperature at planet surface.more » Our findings suggest that mesoscale models with cloud-resolving capability be considered for future studies of exoplanet climate.« less

SSME main combustion chamber life prediction

NASA Technical Reports Server (NTRS)

Cook, R. T.; Fryk, E. E.; Newell, J. F.

1983-01-01

Typically, low cycle fatigue life is a function of the cyclic strain range, the material properties, and the operating temperature. The reusable life is normally defined by the number of strain cycles that can be accrued before severe material degradation occurs. Reusable life is normally signified by the initiation or propagation of surface cracks. Hot-fire testing of channel wall combustors has shown significant mid-channel wall thinning or deformation during accrued cyclic testing. This phenomenon is termed cyclic-creep and appears to be significantly accelerated at elevated surface temperatures. This failure mode was analytically modelled. The cyclic life of the baseline SSME-MCC based on measured calorimeter heat transfer data, and the life sensitivity of local hot spots caused by injector effects were determined. Four life enhanced designs were assessed.

Fire performances of foam core particleboards continuously produced in a one-step process

Treesearch

Ali Shalbafan; Mark A. Dietenberger; Johannes Welling

2013-01-01

For further progress of novel foam core particleboards, their fire performance was examined with cone calorimetry tests (ASTM E 1354-11a). Specimens with varying surface layer thicknesses, foam densities (polystyrene foam), and processing temperatures were tested. Using the initially recommended cone irradiance of 35 kW/m2, different flammability...

Raman spectra of adsorbed layers on space shuttle and AOTV thermal protection system surface

NASA Technical Reports Server (NTRS)

Willey, Ronald J.

1987-01-01

Surfaces of interest to space vehicle heat shield design were struck by a 2 W argon ion laser line while subjected to supersonic arc jet flow conditions. Emission spectra were taken at 90 deg to the angle of laser incidence on the test object. Results showed possible weak Raman shifts which could not be directly tied to any particular parameter such as surface temperature or gas composition. The investigation must be considered exploratory in terms of findings. Many undesirable effects were found and corrected as the project progressed. For instance, initial spectra settings led to ghosts which were eliminated by closing the intermediate of filter slit of the Spex from 8 to 3 mm. Further, under certain conditions, plasma lines from the laser were observed. Several materials were also investigated at room temperature for Raman shifts. Results showed Raman shifts for RCC and TEOS coated materials. The HRSI materials showed only weak Raman shifts, however, substantial efforts were made in studying these materials. Baseline materials showed the technique to be sound. The original goal was to find a Raman shift for the High-temperature Reusable Surface Insulation (HRSI) Reaction Cured borosilicate Glass (RCG) coated material and tie the amplitude of this peak to Arc jet conditions. Weak Raman shifts may be present, however, time limitations prevented confirmation.