Sample records for intermediate range downwind

  1. Meteorological modeling of arrival and deposition of fallout at intermediate distances downwind of the Nevada Test Site.

    PubMed

    Cederwall, R T; Peterson, K R

    1990-11-01

    A three-dimensional atmospheric transport and diffusion model is used to calculate the arrival and deposition of fallout from 13 selected nuclear tests at the Nevada Test Site (NTS) in the 1950s. Results are used to extend NTS fallout patterns to intermediate downwind distances (300 to 1200 km). The radioactive cloud is represented in the model by a population of Lagrangian marker particles, with concentrations calculated on an Eulerian grid. Use of marker particles, with fall velocities dependent on particle size, provides a realistic simulation of fallout as the debris cloud travels downwind. The three-dimensional wind field is derived from observed data, adjusted for mass consistency. Terrain is represented in the grid, which extends up to 1200 km downwind of NTS and has 32-km horizontal resolution and 1-km vertical resolution. Ground deposition is calculated by a deposition-velocity approach. Source terms and relationships between deposition and exposure rate are based on work by Hicks. Uncertainty in particle size and vertical distributions within the debris cloud (and stem) allow for some model "tuning" to better match measured ground-deposition values. Particle trajectories representing different sizes and starting heights above ground zero are used to guide source specification. An hourly time history of the modeled fallout pattern as the debris cloud moves downwind provides estimates of fallout arrival times. Results for event HARRY illustrate the methodology. The composite deposition pattern for all 13 tests is characterized by two lobes extending out to the north-northeast and east-northeast, respectively, at intermediate distances from NTS. Arrival estimates, along with modeled deposition values, augment measured deposition data in the development of data bases at the county level; these data bases are used for estimating radiation exposure at intermediate distances downwind of NTS. Results from a study of event TRINITY are also presented.

  2. Persistent organic contaminants in Saharan dust air masses in West Africa, Cape Verde and the eastern Caribbean

    USGS Publications Warehouse

    Garrison, Virginia H.; Majewski, Michael S.; Foreman, William T.; Genualdi, Susan A.; Mohammed, Azad; Massey Simonich, Stacy L.

    2014-01-01

    Anthropogenic semivolatile organic compounds (SOCs) that persist in the environment, bioaccumulate, are toxic at low concentrations, and undergo long-range atmospheric transport (LRT) were identified and quantified in the atmosphere of a Saharan dust source region (Mali) and during Saharan dust incursions at downwind sites in the eastern Caribbean (U.S. Virgin Islands, Trinidad and Tobago) and Cape Verde. More organochlorine and organophosphate pesticides (OCPPs), polycyclic aromatic hydrocarbons (PAHs), and polychlorinated biphenyl (PCB) congeners were detected in the Saharan dust region than at downwind sites. Seven of the 13 OCPPs detected occurred at all sites: chlordanes, chlorpyrifos, dacthal, dieldrin, endosulfans, hexachlorobenzene (HCB), and trifluralin. Total SOCs ranged from 1.9–126 ng/m3 (mean = 25 ± 34) at source and 0.05–0.71 ng/m3 (mean = 0.24 ± 0.18) at downwind sites during dust conditions. Most SOC concentrations were 1–3 orders of magnitude higher in source than downwind sites. A Saharan source was confirmed for sampled air masses at downwind sites based on dust particle elemental composition and rare earth ratios, atmospheric back trajectory models, and field observations. SOC concentrations were considerably below existing occupational and/or regulatory limits; however, few regulatory limits exist for these persistent organic compounds. Long-term effects of chronic exposure to low concentrations of SOCs are unknown, as are possible additive or synergistic effects of mixtures of SOCs, biologically active trace metals, and mineral dust particles transported together in Saharan dust air masses.

  3. Measurement of the temperature dependent partitioning of semi-volatile organics onto aerosol near roadways

    NASA Astrophysics Data System (ADS)

    Wentzell, J. J.; Liggio, J.; Li, S.; Brook, J.; Staebler, R. M.; Evans, G. J.; Jeong, C.; Sheppard, A.; Lu, G.; Gordon, M.; Mihele, C.

    2010-12-01

    The volatility of the organic aerosol fraction has received a great deal of attention recently in light of new volatility-based modelling approaches and due to the inability of current models to fully account for secondary organic aerosol (SOA). In this regard, evaporation of primary organic aerosol species and their subsequent oxidation may contribute significantly to SOA downwind of sources. This implies that moderate ambient temperature fluctuations can significantly increase or decrease the aerosol bound fraction of semi-volatile and intermediate volatility (SVOC + IVOC) compounds. In order to examine the importance of these more volatile organic components, a temperature controlled inlet was developed with the ability to heat and cool the aerosol in 2 C increments to 15 C above or below ambient temperature. The inlet was coupled to an Aerodyne High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS) and deployed on a mobile platform upwind and downwind of a major Southern Ontario highway as part of the Fast Evolution of Vehicle Emissions near Roadways (FEVER 2010) campaign. Preliminary results suggest that changes in temperature of 5-10 C can alter the partitioning of volatile organic aerosol components by up to 30%. Although the largest affect was observed 10-13 meters downwind of the vehicle emissions, a measurable affect was observed beyond 500 m and in aerosol upwind of the highway. These results suggest that a significant pool of semi-volatile organics exist, which can condense onto particles at slightly lower temperatures or evaporate to the gas phase and be further oxidized. The nature of these organic species at locations upwind and downwind of vehicle emissions will be discussed.

  4. Noise radiation characteristics of the Westinghouse WWG-0600 (600kW) wind turbine generator

    NASA Technical Reports Server (NTRS)

    Shepherd, Kevin P.; Hubbard, Harvey H.

    1989-01-01

    Acoustic data are presented from five different WWG-0600 machines for the wind speed range 6.7 to 13.4 m/s, for a power output range of 51 to 600 kW and for upwind, downwind and crosswind locations. Both broadband and narrowband data are presented and are compared with calculations and with similar data from other machines. Predicted broadband spectra are in good agreement with measurements at high power and underestimate them at low power. Discrete frequency rotational noise components are present in all measurements and are believed due to terrain induced wind gradients. Predictions are in general agreement with measurements upwind and downwind but underestimate them in the crosswind direction.

  5. Radon emissions from natural gas power plants at The Pennsylvania State University.

    PubMed

    Stidworthy, Alison G; Davis, Kenneth J; Leavey, Jeff

    2016-11-01

    Burning natural gas in power plants may emit radon ( 222 Rn) into the atmosphere. On the University Park campus of The Pennsylvania State University, atmospheric radon enhancements were measured and modeled in the vicinity of their two power plants. The three-part study first involved measuring ambient outdoor radon concentrations from August 2014 through January 2015 at four sites upwind and downwind of the power plants at distances ranging from 80 m to 310 m. For each plant, one site served as a background site, while three other sites measured radon concentration enhancements downwind. Second, the radon content of natural gas flowing into the power plant was measured, and third, a plume dispersion model was used to predict the radon concentrations downwind of the power plants. These predictions are compared to the measured downwind enhancements in radon to determine whether the observed radon concentration enhancements could be attributed to the power plants' emissions. Atmospheric radon concentrations were consistently low as compared to the EPA action level of 148 Bq m -3 , averaging 34.5 ± 2.7 Bq m -3 around the East Campus Steam Plant (ECSP) and 31.6 ± 2.7 Bq m -3 around the West Campus Steam Plant (WCSP). Significant concentrations of radon, ranging from 516 to 1,240 Bq m -3 , were detected in the natural gas. The measured enhancements downwind of the ECSP averaged 6.2 Bq m -3 compared to modeled enhancements of 0.08 Bq m -3 . Measured enhancements around the WCSP averaged -0.2 Bq m -3 compared to the modeled enhancements of 0.05 Bq m -3 , which were not significant compared to observational error. The comparison of the measured to modeled downwind radon enhancements shows no correlation over time. The measurements of radon levels in the vicinity of the power plants appear to be unaffected by the emissions from the power plants. Radon measurements at sites surrounding power plants that utilize natural gas did not indicate that the radon concentrations originated from the plants' emissions. There were elevated radon concentrations in the natural gas supply flowing into the power plants, but combustion dilution puts the concentration below EPA action levels coming out of the stack, so no hazardous levels were expected downwind. Power plant combustion of natural gas is not likely to pose a radiation health hazard unless very different gas radon concentrations or combustion dilution ratios are encountered.

  6. Morphing Downwind-Aligned Rotor Concept Based on a 13-MW Wind Turbine

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ichter, Brian; Steele, Adam; Loth, Eric

    To alleviate the mass-scaling issues associated with conventional upwind rotors of extreme-scale wind turbines (>/=10 MW), a morphing downwind-aligned rotor (MoDaR) concept is proposed herein. The concept employs a downwind rotor with blades whose elements are stiff (no intentional flexibility) but with hub-joints that can be unlocked to allow for moment-free downwind alignment. Aligning the combination of gravitational, centrifugal and thrust forces along the blade path reduces downwind cantilever loads, resulting in primarily tensile loading. For control simplicity, the blade curvature can be fixed with a single morphing degree of freedom using a near-hub joint for coning angle: 22 degreesmore » at rated conditions. The conventional baseline was set as the 13.2-MW Sandia 100-m all glass blade in a three-bladed upwind configuration. To quantify potential mass savings, a downwind load-aligning, two-bladed rotor was designed. Because of the reduced number of blades, the MoDaR concept had a favorable 33% mass reduction. The blade reduction and coning led to a reduction in rated power, but morphing increased energy capture at lower speeds such that both the MoDaR and conventional rotors have the same average power: 5.4 MW. A finite element analysis showed that quasi-steady structural stresses could be reduced, over a range of operating wind speeds and azimuthal angles, despite the increases in loading per blade. However, the concept feasibility requires additional investigation of the mass, cost and complexity of the morphing hinge, the impact of unsteady aeroelastic influence because of turbulence and off-design conditions, along with system-level Levelized Cost of Energy analysis.« less

  7. The Downwind Hemisphere of the Heliosphere as Observed with IBEX-Lo from 2009 to 2015

    NASA Astrophysics Data System (ADS)

    Wurz, P.; Galli, A.; Schwadron, N.; Kucharek, H.; Moebius, E.; Bzowski, M.; Sokol, J. M.; Kubiak, M. A.; Funsten, H. O.; Fuselier, S. A.; McComas, D. J.

    2017-12-01

    The topic of this study is the vast region towards the tail of the heliosphere. To this end, we comprehensively analyzed energetic neutral hydrogen atoms (ENAs) of energies 10 eV to 2.5 keV from the downwind hemisphere of the heliosheath measured during the first 7 years of the IBEX (Interstellar Boundary Explorer) mission. Neutralized ions from the heliosheath (the region of slow solar wind plasma between termination shock and heliopause) can be remotely observed as ENAs down to 10 eV with the IBEX-Lo sensor onboard IBEX. This sensor covers those energies of the ion spectrum that dominate the total plasma pressure in the downwind region. So far, this region of the heliosphere has never been explored in-situ. Converting observations obtained near Earth orbit at these low energies to the original ion distributions in the heliocentric rest frame at 100 AU is very challenging, making the assessment of uncertainties and implicit assumptions crucial. From the maps of observed ENAs from the heliosheath and their uncertainties we derive observational constraints on heliospheric models for the downwind hemisphere. These constraints limit the possible range of 1) the distance of the termination shock, 2) the total plasma pressure across the termination shock, 3) the radial flow velocity of the heliosheath plasma, 4) the extinction length of said plasma, and finally 5) the dimension of the heliosheath in downwind directions. Because these parameters are coupled and because of observational limitations, we also need to characterize the degeneracy, i.e., the fact that different sets of parameters may reproduce the observations.

  8. Systematic Satellite Observations of the Impact of Aerosols from Passive Volcanic Degassing on Local Cloud Properties

    NASA Technical Reports Server (NTRS)

    Ebmeier, S.K.; Sayer, Andrew M.; Grainger, R. G.; Mather, T. A.; Carboni, E.

    2014-01-01

    The impact of volcanic emissions, especially from passive degassing and minor explosions, is a source of uncertainty in estimations of aerosol indirect effects. Observations of the impact of volcanic aerosol on clouds contribute to our understanding of both present-day atmospheric properties and of the pre-industrial baseline necessary to assess aerosol radiative forcing. We present systematic measurements over several years at multiple active and inactive volcanic islands in regions of low present-day aerosol burden. The timeaveraged indirect aerosol effects within 200 kilometers downwind of island volcanoes are observed using Moderate Resolution Imaging Spectroradiometer (MODIS, 2002-2013) and Advanced Along-Track Scanning Radiometer (AATSR, 2002- 2008) data. Retrievals of aerosol and cloud properties at Kilauea (Hawaii), Yasur (Vanuatu) and Piton de la Fournaise (la Reunion) are rotated about the volcanic vent to be parallel to wind direction, so that upwind and downwind retrievals can be compared. The emissions from all three volcanoes - including those from passive degassing, Strombolian activity and minor explosions - lead to measurably increased aerosol optical depth downwind of the active vent. Average cloud droplet effective radius is lower downwind of the volcano in all cases, with the peak difference ranging from 2 - 8 micrometers at the different volcanoes in different seasons. Estimations of the difference in Top of Atmosphere upward Short Wave flux upwind and downwind of the active volcanoes from NASA's Clouds and the Earth's Radiant Energy System (CERES) suggest a downwind elevation of between 10 and 45 Watts per square meter at distances of 150 - 400 kilometers from the volcano, with much greater local (less than 80 kilometers) effects. Comparison of these observations with cloud properties at isolated islands without degassing or erupting volcanoes suggests that these patterns are not purely orographic in origin. Our observations of unpolluted, isolated marine settings may capture processes similar to those in the pre-industrial marine atmosphere.

  9. Global and Regional Modeling of Long-Range Transport and Intercontinental Source-Receptor Linkages (presentation)

    EPA Science Inventory

    Because long-range transport has been shown to affect air quality in downwind continents, there is a growing realization that these effects may need to be considered in air quality management efforts by distinguishing between the contributions of local and regional emission sourc...

  10. Evaluation of Uncertainties in Measuring Particulate Matter Emission Factors from Atmospheric Fugitive Sources Using Optical Remote Sensing

    NASA Astrophysics Data System (ADS)

    Yuen, W.; Ma, Q.; Du, K.; Koloutsou-Vakakis, S.; Rood, M. J.

    2015-12-01

    Measurements of particulate matter (PM) emissions generated from fugitive sources are of interest in air pollution studies, since such emissions vary widely both spatially and temporally. This research focuses on determining the uncertainties in quantifying fugitive PM emission factors (EFs) generated from mobile vehicles using a vertical scanning micro-pulse lidar (MPL). The goal of this research is to identify the greatest sources of uncertainty of the applied lidar technique in determining fugitive PM EFs, and to recommend methods to reduce the uncertainties in this measurement. The MPL detects the PM plume generated by mobile fugitive sources that are carried downwind to the MPL's vertical scanning plane. Range-resolved MPL signals are measured, corrected, and converted to light extinction coefficients, through inversion of the lidar equation and calculation of the lidar ratio. In this research, both the near-end and far-end lidar equation inversion methods are considered. Range-resolved PM mass concentrations are then determined from the extinction coefficient measurements using the measured mass extinction efficiency (MEE) value, which is an intensive PM property. MEE is determined by collocated PM mass concentration and light extinction measurements, provided respectively by a DustTrak and an open-path laser transmissometer. These PM mass concentrations are then integrated with wind information, duration of plume event, and vehicle distance travelled to obtain fugitive PM EFs. To obtain the uncertainty of PM EFs, uncertainties in MPL signals, lidar ratio, MEE, and wind variation are considered. Error propagation method is applied to each of the above intermediate steps to aggregate uncertainty sources. Results include determination of uncertainties in each intermediate step, and comparison of uncertainties between the use of near-end and far-end lidar equation inversion methods.

  11. Integrated Design of Downwind Land-Based Wind Turbines using Analytic Gradients

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ning, Andrew; Petch, Derek

    2016-12-01

    Wind turbines are complex systems where component-level changes can have significant system-level effects. Effective wind turbine optimization generally requires an integrated analysis approach with a large number of design variables. Optimizing across large variable sets is orders of magnitude more efficient with gradient-based methods as compared with gradient-free method, particularly when using exact gradients. We have developed a wind turbine analysis set of over 100 components where 90% of the models provide numerically exact gradients through symbolic differentiation, automatic differentiation, and adjoint methods. This framework is applied to a specific design study focused on downwind land-based wind turbines. Downwind machinesmore » are of potential interest for large wind turbines where the blades are often constrained by the stiffness required to prevent a tower strike. The mass of these rotor blades may be reduced by utilizing a downwind configuration where the constraints on tower strike are less restrictive. The large turbines of this study range in power rating from 5-7MW and in diameter from 105m to 175m. The changes in blade mass and power production have important effects on the rest of the system, and thus the nacelle and tower systems are also optimized. For high-speed wind sites, downwind configurations do not appear advantageous. The decrease in blade mass (10%) is offset by increases in tower mass caused by the bending moment from the rotor-nacelle-assembly. For low-wind speed sites, the decrease in blade mass is more significant (25-30%) and shows potential for modest decreases in overall cost of energy (around 1-2%).« less

  12. Ozone Transport Aloft Drives Surface Ozone Maxima Across the Mojave Desert

    NASA Astrophysics Data System (ADS)

    VanCuren, R. A.

    2014-12-01

    A persistent layer of polluted air in the lower free troposphere over the Mojave Desert (California and Nevada) drives spring and summer surface ozone maxima as deep afternoon mixing delivers ozone and ozone precursors to surface measurement sites 200 km or more downwind of the mountains that separate the deserts from the heavily populated coastal areas of California. Pollutants in this elevated layer derive from California source regions (the Los Angeles megacity region and the intensive agricultural region of the San Joaquin Valley), and from long-range transport from Asia. Recognition of this poorly studied persistent layer explains and expands the significance of previously published reports of ozone and other pollutants observed in and over the Mojave Desert, resolves an apparent paradox in the timing of ozone peaks due to transport from the upwind basins, and provides a new perspective on the long-range downwind impacts of megacity pollution plumes.

  13. Zone trends for three metropolitan statistical areas in North Carolina

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Oommen, R.G.; Aneja, V.P.; Riordan, A.J.

    1996-12-31

    As part of an effort by the state of North Carolina to develop a State Implementation Plan (SIP) for ozone control, a network of ozone stations was established to monitor ozone concentrations across the state. Approximately twenty-five ozone stations made continuous measurements surrounding the three major Metropolitan Statistical Areas (MSAs) between 1993-1995: Raleigh/Durham (RDU), Charlotte/Mecklenburg (CLT), and Greensboro/Winston-Salem/High Point (GSO). Statistical Averages on the ozone data were performed at each MSA to study trends and/or relationships on high ozone days. It was found that the three MSAs were not significantly different to each other, indicating they fall under the samemore » synoptic weather patterns, Transport and local production of biogenic sources of VOCs and NO{sub x} appear to play an important role for high ozone downwind at RDU, while mobile sources of these precursor gases contribute to the high ozone downwind of CLT and GSO. A {delta}(O{sub 3}) analysis (difference between the O{sub 3} measured at an upwind and downwind site) suggested that long-range transport of the precursors was a significant contribution for ozone problems at the three MSAs. 15 refs., 2 figs., 2 tabs.« less

  14. Airborne endotoxin concentrations at a large open-lot dairy in southern idaho.

    PubMed

    Dungan, Robert S; Leytem, April B

    2009-01-01

    Endotoxins are derived from gram-negative bacteria and are a potential respiratory health risk for animals and humans. To determine the potential for endotoxin transport from a large open-lot dairy, total airborne endotoxin concentrations were determined at an upwind location (background) and five downwind locations on three separate days. The downwind locations were situated at of the edge of the lot, 200 and 1390 m downwind from the lot, and downwind from a manure composting area and wastewater holding pond. When the wind was predominantly from the west, the average endotoxin concentration at the upwind location was 24 endotoxin units (EU) m(-3), whereas at the edge of the lot on the downwind side it was 259 EU m(-3). At 200 and 1390 m downwind from the edge of the lot, the average endotoxin concentrations were 168 and 49 EU m(-3), respectively. Average airborne endotoxin concentrations downwind from the composting site (36 EU m(-3)) and wastewater holding pond (89 EU m(-3)) and 1390 m from the edge of the lot were not significantly different from the upwind location. There were no significant correlations between ambient weather data collected and endotoxin concentrations over the experimental period. The downwind data show that the airborne endotoxin concentrations decreased exponentially with distance from the lot edge. Decreasing an individual's proximity to the dairy should lower their risk of airborne endotoxin exposure and associated health effects.

  15. Systematic Satellite Observations of the Impact of Aerosols from Passive Volcanic Degassing on Local Cloud Properties

    NASA Technical Reports Server (NTRS)

    Ebmeier, S. K.; Sayer, A. M.; Grainger, R. G.; Mather, T. A.; Carboni, E.

    2014-01-01

    The impact of volcanic emissions is a significant source of uncertainty in estimations of aerosol indirect radiative forcing, especially with respect to emissions from passive de-gassing and minor explosions. Understanding the impact of volcanic emissions on indirect radiative forcing is important assessing present day atmospheric properties and also to define the pre-industrial baseline to assess anthropogenic perturbations. We present observations of the time-averaged indirect aerosol effect within 200 km downwind of isolated island volcanoes in regions of low present-day aerosol burden using MODIS and AATSR data. Retrievals of aerosol and cloud properties at Kilauea (Hawaii), Yasur (Vanuatu) and Piton de la Fournaise (Reunion) are rotated about the volcanic vent according to wind direction, so that retrievals downwind of the volcano can be averaged to improve signal to noise ratio. The emissions from all three volcanoes, including those from passive degassing, strombolian activity and minor explosions lead to measurably increased aerosol optical depth downwind of the active vent. Average cloud droplet effective radius is lower downwind of the volcano in all cases, with the peak difference in effective radius ranging from 48 microns at the different volcanoes. A comparison of these observations with cloud properties at isolated islands with no significant source of aerosol suggests that these patterns are not purely orographic in origin. This approach sets out a first step for the systematic measurement of the effects of present day low altitude volcanic emissions on cloud properties, and our observations of unpolluted, isolated marine settings may capture processes similar to those in the preindustrial marine atmosphere.

  16. Long-range pollution transport during the MILAGRO-2006 campaign: a case study of a major Mexico City outflow event using free-floating altitude-controlled balloons

    NASA Astrophysics Data System (ADS)

    Voss, P. B.; Zaveri, R. A.; Flocke, F. M.; Mao, H.; Hartley, T. P.; Deamicis, P.; Deonandan, I.; Contreras-Jiménez, G.; Martínez-Antonio, O.; Figueroa Estrada, M.; Greenberg, D.; Campos, T. L.; Weinheimer, A. J.; Knapp, D. J.; Montzka, D. D.; Crounse, J. D.; Wennberg, P. O.; Apel, E.; Madronich, S.; de Foy, B.

    2010-02-01

    One of the major objectives of the Megacities Initiative: Local And Global Research Observations (MILAGRO-2006) campaign was to investigate the long-range transport of polluted Mexico City Metropolitan Area (MCMA) outflow and determine its downwind impacts on air quality and climate. Six research aircraft, including the National Center for Atmospheric Research (NCAR) C-130, made extensive chemical, aerosol, and radiation measurements above MCMA and more than 1000 km downwind in order to characterize the evolution of the outflow as it aged and dispersed over the Mesa Alta and Gulf of Mexico. As part of this effort, free-floating Controlled-Meteorological (CMET) balloons, commanded to change altitude via satellite, made repeated profile measurements of winds and state variables within the advecting outflow. In this paper, we present an analysis based on the data from two CMET balloons that were launched near Mexico City on the afternoon of 18 March 2006 and floated downwind with the MCMA pollution for nearly 30 h. The repeating profile measurements show the evolving structure of the outflow in considerable detail: its stability and stratification, interaction with other air masses, mixing episodes, and dispersion into the regional background. Air parcel trajectories, computed directly from the balloon wind profiles, show three different transport pathways on 18-19 March: (a) high-altitude advection of the top of the MCMA mixed layer, (b) mid-level outflow over the Sierra Madre Oriental followed by decoupling and isolated transport over the Gulf, and (c) low-altitude outflow with entrainment into a cleaner westerly jet below the plateau. The C-130 aircraft intercepted the balloon-based trajectories three times on 19 March, once along each of these pathways. In all three cases, distinct peaks in the urban tracer signatures and LIDAR backscatter imagery were consistent with MCMA pollution. The coherence of the high-altitude outflow was well preserved after one day whereas that lower in the atmosphere was more widely dispersed over the same time period. Other C-130 intercepts of polluted air are shown to have likely originated outside of MCMA. These findings, and the aircraft intercepts in particular, should prove useful in answering a range of scientific questions pertaining to the transport, transformation, and downwind impacts of megacity air pollution.

  17. Numerical investigations on the aerodynamic performance of wind turbine: Downwind versus upwind configuration

    NASA Astrophysics Data System (ADS)

    Zhou, Hu; Wan, Decheng

    2015-03-01

    Although the upwind configuration is more popular in the field of wind energy, the downwind one is a promising type for the offshore wind energy due to its special advantages. Different configurations have different aerodynamic performance and it is important to predict the performance of both downwind and upwind configurations accurately for designing and developing more reliable wind turbines. In this paper, a numerical investigation on the aerodynamic performance of National Renewable Energy Laboratory (NREL) phase VI wind turbine in downwind and upwind configurations is presented. The open source toolbox OpenFOAM coupled with arbitrary mesh interface (AMI) method is applied to tackle rotating problems of wind turbines. Two 3D numerical models of NREL phase VI wind turbine with downwind and upwind configurations under four typical working conditions of incoming wind velocities are set up for the study of different unsteady characteristics of the downwind and upwind configurations, respectively. Numerical results of wake vortex structure, time histories of thrust, pressure distribution on the blade and limiting streamlines which can be used to identify points of separation in a 3D flow are presented. It can be concluded that thrust reduction due to blade-tower interaction is small for upwind wind turbines but relatively large for downwind wind turbines and attention should be paid to the vibration at a certain frequency induced by the cyclic reduction for both configurations. The results and conclusions are helpful to analyze the different aerodynamic performance of wind turbines between downwind and upwind configurations, providing useful references for practical design of wind turbine.

  18. Source-Receptor Relationship Analysis of the Atmospheric Deposition of PAHs Subject to Long-Range Transport in Northeast Asia.

    PubMed

    Inomata, Yayoi; Kajino, Mizuo; Sato, Keiichi; Kurokawa, Junichi; Tang, Ning; Ohara, Toshimasa; Hayakawa, Kazuichi; Ueda, Hiromasa

    2017-07-18

    The source-receptor relationship analysis of PAH deposition in Northeast Asia was investigated using an Eulerian regional-scale aerosol chemical transport model. Dry deposition (DD) of PAH was controlled by wind flow patterns, whereas wet deposition (WD) depended on precipitation in addition to wind flow patterns. The contribution of WD was approximately 50-90% of the total deposition, except during winter in Northern China (NCHN) and Eastern Russia (ERUS) because of the low amount of precipitation. The amount of PAH deposition showed clear seasonal variation and was high in winter and low in summer in downwind (South Korea, Japan) and oceanic-receptor regions. In the downwind region, the contributions from NCHN (WD 28-52%; DD 54-55%) and Central China (CCHN) (WD 43-65%; DD 33-38%) were large in winter, whereas self-contributions (WD 20-51%; DD 79-81%) were relatively high in summer. In the oceanic-receptor region, the deposition amount decreased with distance from the Asian continent. The amount of DD was strongly influenced by emissions from neighboring domains. The contributions of WD from NCHN (16-20%) and CCHN (28-35%) were large. The large contributions from China in summer to the downwind region were linked to vertical transport of PAHs over the Asian continent associated with convection.

  19. Physics-based agent to simulant correlations for vapor phase mass transport.

    PubMed

    Willis, Matthew P; Varady, Mark J; Pearl, Thomas P; Fouse, Janet C; Riley, Patrick C; Mantooth, Brent A; Lalain, Teri A

    2013-12-15

    Chemical warfare agent simulants are often used as an agent surrogate to perform environmental testing, mitigating exposure hazards. This work specifically addresses the assessment of downwind agent vapor concentration resulting from an evaporating simulant droplet. A previously developed methodology was used to estimate the mass diffusivities of the chemical warfare agent simulants methyl salicylate, 2-chloroethyl ethyl sulfide, di-ethyl malonate, and chloroethyl phenyl sulfide. Along with the diffusivity of the chemical warfare agent bis(2-chloroethyl) sulfide, the simulant diffusivities were used in an advection-diffusion model to predict the vapor concentrations downwind from an evaporating droplet of each chemical at various wind velocities and temperatures. The results demonstrate that the simulant-to-agent concentration ratio and the corresponding vapor pressure ratio are equivalent under certain conditions. Specifically, the relationship is valid within ranges of measurement locations relative to the evaporating droplet and observation times. The valid ranges depend on the relative transport properties of the agent and simulant, and whether vapor transport is diffusion or advection dominant. Published by Elsevier B.V.

  20. Thermoregulatory demands of elite professional America's Cup yacht racing.

    PubMed

    Neville, V; Gant, N; Folland, J P

    2010-06-01

    America's Cup yacht racing predominantly occurs during the summer months under hot and humid conditions, with athletes exposed to the environment for prolonged periods, and yet the thermoregulatory responses to competitive sailing are largely unappreciated. This study aimed to assess the thermoregulatory responses to elite professional big-boat yacht racing, according to crew position and upwind and downwind sailing. Intestinal (T(core)) and skin temperature, fluid balance and regional sweat compositions were measured in two America's Cup crews (n=32) during 100 min of racing. The environmental conditions were as follows: 32 degrees C, 52% RH and 5 m/s wind speed. Subjective race intensity was moderate. Bowmen recorded the greatest elevation in the heart rate (184 +/- 10 beats/min) and T(core) (39.2 degrees C, P<0.01). Both heart rate and T(core) were higher during downwind sailing (P<0.001). Regional skin temperatures were significantly different according to site (P=0.05), with tibia being the lowest (33.3 +/- 1.2 degrees C). The mean sweat loss during racing was 1.34 +/- 0.58 L/h (range: 0.44-2.40 L/h), with bowmen experiencing the greatest loss of sweat (3.7 +/- 0.9% of body mass). The mean fluid intake was highly correlated to sweat loss (r=0.74, P<0.001), with 72 +/- 41% of sweat losses replaced. The mean sodium concentration of sweat was 27.2 +/- 9.2 mmol/L (range: 12.0-43.5 mmol/L) and the total NaCl loss during sailing was 3.8 +/- 2.4 g (range 0.7-10.0 g). America's Cup sailing is a demanding sport that presents considerable challenges to thermoregulation, fluid and electrolyte balance. Certain crew roles (bowmen) present an increased risk of developing exertional heat illness, and for the majority of crew downwind sailing results in greater thermal strain than upwind sailing - which may have implications for clothing selection and boat design.

  1. Long-range pollution transport during the MILAGRO-2006 campaign: a case study of a major Mexico City outflow event using free-floating altitude-controlled balloons

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Voss, Paul B.; Zaveri, Rahul A.; Flocke, Frank M.

    2010-08-04

    One of the major objectives of the Megacities Initiative: Local And Global Research 3 Observations (MILAGRO 2006) campaign was to investigate the long-range transport of 4 Mexico City Metropolitan Area (MCMA) pollution outflow and its downwind impacts on air 5 quality and climate. Four aircraft (DOE G-1, NSF/NCAR C-130, NASA-J31, and NASA 6 DC-8) made extensive chemical, aerosol, and radiation measurements above MCMA and over 7 1000 km downwind in order to characterize the evolution of MCMA pollution as it aged and 8 dispersed over the central Mexican plateau and the Gulf of Mexico. As part of this effort, 9more » free-floating Controlled-Meteorological (CMET) balloons, capable of changing altitude on 10 command via satellite, characterized the MCMA outflow by performing repeated soundings 11 during the transit. In this paper, we present an analysis based on the data from two CMET 12 balloons that were launched near Mexico City on the afternoon of 18 March 2006 and floated 13 downwind with the outflow for nearly 30 hours. Continuous profile measurements made by 14 the balloons show the evolving structure of the MCMA outflow in considerable detail: its 15 stability and stratification, interaction with other air masses, mixing episodes, and dispersion 16 into the regional background. Air parcel trajectories, computed directly from the balloon 17 wind profiles, show three different transport pathways for Mexico City outflow on 18-19 18 March: (a) high-altitude advection of the top of the MCMA mixed layer, (b) low-altitude flow 19 over the Sierra Madre Oriental followed by decoupling and isolated transport over the Gulf, 20 and (c) the same decoupling scenario with entrainment into a cleaner westerly jet below the 21 plateau. The C-130 intercepted the balloon-based trajectories three times on 19 March, once 22 along each transport pathway. In all three cases, distinct peaks in the urban tracer signature 23 and LIDAR backscatter imagery provided evidence for Mexico City air. The coherence of the 24 high-altitude outflow was well preserved after 25 hours whereas that lower in the atmosphere 25 was more widely dispersed over the same time period. Other C-130 intercepts, previously 26 thought to be from Mexico City, are shown to have likely originated elsewhere. These 27 findings address key questions about the long-range transport of Mexico City pollution and its 28 impact on the regional background. The particular intercepts identified should prove useful in 29 answering a wide range scientific questions pertaining to the transport, transformation, and 30 downwind impacts of megacity air pollution. 31 32« less

  2. Impact of natural gas development in the Marcellus and Utica shales on regional ozone and fine particulate matter levels

    NASA Astrophysics Data System (ADS)

    Roohani, Yusuf H.; Roy, Anirban A.; Heo, Jinhyok; Robinson, Allen L.; Adams, Peter J.

    2017-04-01

    The Marcellus and Utica shale formations have recently been the focus of intense natural gas development and production, increasing regional air pollutant emissions. Here we examine the effects of these emissions on regional ozone and fine particulate matter (PM2.5) levels using the chemical transport model, CAMx, and estimate the public health costs with BenMAP. Simulations were performed for three emissions scenarios for the year 2020 that span a range potential development storylines. In areas with the most gas development, the 'Medium Emissions' scenario, which corresponds to an intermediate level of development and widespread adoption of new equipment with lower emissions, is predicted to increase 8-hourly ozone design values by up to 2.5 ppbv and average annual PM2.5 concentrations by as much as 0.27 μg/m3. These impacts could range from as much as a factor of two higher to a factor of three lower depending on the level of development and the adoption of emission controls. Smaller impacts (e.g. 0.1-0.5 ppbv of ozone, depending on the emissions scenario) are predicted for non-attainment areas located downwind of the Marcellus region such as New York City, Philadelphia and Washington, DC. Premature deaths for the 'Medium Emissions' scenario are predicted to increase by 200-460 annually. The health impacts as well as the changes in ozone and PM2.5 were all driven primarily by NOx emissions.

  3. International Airport Impacts to Air Quality: Size and Related Properties of Large Increases in Ultrafine Particle Number Concentrations.

    PubMed

    Hudda, N; Fruin, S A

    2016-04-05

    We measured particle size distributions and spatial patterns of particle number (PN) and particle surface area concentrations downwind from the Los Angeles International Airport (LAX) where large increases (over local background) in PN concentrations routinely extended 18 km downwind. These elevations were mostly comprised of ultrafine particles smaller than 40 nm. For a given downwind distance, the greatest increases in PN concentrations, along with the smallest mean sizes, were detected at locations under the landing jet trajectories. The smaller size of particles in the impacted area, as compared to the ambient urban aerosol, increased calculated lung deposition fractions to 0.7-0.8 from 0.5-0.7. A diffusion charging instrument (DiSCMini), that simulates alveolar lung deposition, measured a fivefold increase in alveolar-lung deposited surface area concentrations 2-3 km downwind from the airport (over local background), decreasing steadily to a twofold increase 18 km downwind. These ratios (elevated lung-deposited surface area over background) were lower than the corresponding ratios for elevated PN concentrations, which decreased from tenfold to twofold over the same distance, but the spatial patterns of elevated concentrations were similar. It appears that PN concentration can serve as a nonlinear proxy for lung deposited surface area downwind of major airports.

  4. Assessment for the impact of dust events on measles incidence in western China

    NASA Astrophysics Data System (ADS)

    Ma, Yuxia; Zhou, Jianding; Yang, Sixu; Zhao, Yuxin; Zheng, Xiaodong

    2017-05-01

    Dust events affect human health in both drylands and downwind environments. In this study, we used county-level data during the period of 1965-2005 to assess the impact of dust events on measles incidence in Gansu province in Western China. We used Fast Fourier Transform (FFT) to set up the cyclical regression model; in particular, we set the model to downwind direction for the typical cities in the Hexi Corridor as well as the capital city Lanzhou. The results showed that Spring measles incidence was the highest in the Hexi Corridor, where dust events occur the most frequently over Gansu province. Measles incidence declined on the pathway of dust storms from west to east due to the weakening of both intensity and duration in dust storms. Measles incidence was positively correlated with monthly wind speed and negatively correlated with rainfall amount, relative humidity, and air pressure. Measles incidence was significantly (p ≤ 0.01) positively correlated with daily coarse particles, e.g., TSP and PM10. According to the cyclical regression model, average monthly excess measles that is related to dust events was 39.1 (ranging from 17.3 to 87.6), 149.9 (ranging from 7.1 to 413.4), and 31.3 (ranging from 20.6 to 63.5) in Zhangye, Lanzhou, and Jiuquan, respectively.

  5. Intercontinental transport of aerosols and photochemical oxidants from Asia and its consequences.

    PubMed

    Wuebbles, Donald J; Lei, Hang; Lin, Jintai

    2007-11-01

    The intercontinental transport of aerosols and photochemical oxidants from Asia is a crucial issue for air quality concerns in countries downwind of the significant emissions and concentrations of pollutants occurring in this important region of the world. Since the lifetimes of some important pollutants are long enough to be transported over long distance in the troposphere, regional control strategies for air pollution in downwind countries might be ineffective without considering the effects of long-range transport of pollutants from Asia. Field campaigns provide strong evidence for the intercontinental transport of Asian pollutants. They, together with ground-based observations and model simulations, show that the air quality over parts of North America is being affected by the pollutants transported from Asia. This paper examines the current understanding of the intercontinental transport of gases and aerosols from Asia and resulting effects on air quality, and on the regional and global climate system.

  6. Characterization and Impact of Low Frequency Wind Turbine Noise Emissions

    NASA Astrophysics Data System (ADS)

    Finch, James

    Wind turbine noise is a complex issue that requires due diligence to minimize any potential impact on quality of life. This study enhances existing knowledge of wind turbine noise through focused analyses of downwind sound propagation, directionality, and the low frequency component of the noise. Measurements were conducted at four wind speeds according to a design of experiments at incremental distances and angles. Wind turbine noise is shown to be highly directional, while downwind sound propagation is spherical with limited ground absorption. The noise is found to have a significant low frequency component that is largely independent of wind speed over the 20-250 Hz range. The generated low frequency noise is shown to be audible above 40 Hz at the MOE setback distance of 550 m. Infrasound levels exhibit higher dependency on wind speed, but remain below audible levels up to 15 m/s.

  7. Contribution of regional-scale fire events to ozone and PM2.5 ...

    EPA Pesticide Factsheets

    Two specific fires from 2011 are tracked for local to regional scale contribution to ozone (O3) and fine particulate matter (PM2.5) using a freely available regulatory modeling system that includes the BlueSky wildland fire emissions tool, Spare Matrix Operator Kernel Emissions (SMOKE) model, Weather and Research Forecasting (WRF) meteorological model, and Community Multiscale Air Quality (CMAQ) photochemical grid model. The modeling system was applied to track the contribution from a wildfire (Wallow) and prescribed fire (Flint Hills) using both source sensitivity and source apportionment approaches. The model estimated fire contribution to primary and secondary pollutants are comparable using source sensitivity (brute-force zero out) and source apportionment (Integrated Source Apportionment Method) approaches. Model estimated O3 enhancement relative to CO is similar to values reported in literature indicating the modeling system captures the range of O3 inhibition possible near fires and O3 production both near the fire and downwind. O3 and peroxyacetyl nitrate (PAN) are formed in the fire plume and transported downwind along with highly reactive VOC species such as formaldehyde and acetaldehyde that are both emitted by the fire and rapidly produced in the fire plume by VOC oxidation reactions. PAN and aldehydes contribute to continued downwind O3 production. The transport and thermal decomposition of PAN to nitrogen oxides (NOX) enables O3 production in areas

  8. Aspergillus fumigatus and mesophilic moulds in air in the surrounding environment downwind of non-hazardous waste landfill sites.

    PubMed

    Schlosser, Olivier; Robert, Samuel; Debeaupuis, Catherine

    2016-05-01

    Non-hazardous waste landfilling has the potential to release biological agents into the air, notably mould spores. Some species, such as Aspergillus fumigatus, may be a cause of concern for at-risk nearby residents. However, air concentration in the surrounding environment of non-hazardous waste landfill sites is poorly documented. An extensive sampling programme was designed to investigate the relationship between culturable mesophilic moulds and A. fumigatus concentrations in air and distance downwind of non-hazardous waste landfill sites. On-site and off-site repeated measurements were performed at four landfill sites during cold and warm seasons. A high-flow air-sampler device was selected so as to allow peak concentration measurement. Linear mixed-effects models were used to explain variability in the concentrations in air over time and across sites, seasons, instantaneous meteorological conditions and discharged waste tonnage. Concentrations of mesophilic moulds and A. fumigatus at off-site upwind sampling locations were compared with concentrations at each of the downwind sampling locations. At the tipping face location, peak concentration reached 480,000CFUm(-3) for mesophilic moulds and 9300CFUm(-3) for A. fumigatus. Compared with upwind background levels, these concentrations were, on average, approximately 20 and 40 times higher respectively. A steep decline in the concentration of both mesophilic moulds and A. fumigatus was observed between the tipping face location and the downwind property boundary (reduction by 77% and 84% respectively), followed by a low decline leading to a 90% and 94% reduction in concentration at 200m from the property boundary and beyond. With the 200m and 500m downwind sampling point values added together, the 97.5th percentile of concentration was 6013CFUm(-3) and 87CFUm(-3) for mesophilic moulds and A. fumigatus, respectively. Other determining factors were the discharged waste tonnage, the season, instantaneous temperature and wind velocity for mesophilic mould, and instantaneous temperature for A. fumigatus. At 200m and 500 downwind from the property boundary, mesophilic moulds and A. fumigatus concentrations were still higher than the local background level. However, whilst statistically significant, this increase does not suggest an excess risk to nearby residents' health when compared with the wide range of outdoor background levels reported in literature. These findings suggest that moulds and A. fumigatus may be transported beyond 200m from the property boundary in concentrations above those found locally upwind of the landfill site. Nevertheless, for exposure assessment purposes, comparison should also be made with background levels in wider areas which are either residential or through which people travel to work for example. Copyright © 2016 Elsevier GmbH. All rights reserved.

  9. Aircraft emission impacts in a neighborhood adjacent to a general aviation airport in southern California.

    PubMed

    Hu, Shishan; Fruin, Scott; Kozawa, Kathleen; Mara, Steve; Winer, Arthur M; Paulson, Suzanne E

    2009-11-01

    Real time air pollutant concentrations were measured downwind of Santa Monica Airport (SMA), using an electric vehicle mobile platform equipped with fast response instruments in spring and summer of 2008. SMA is a general aviation airport operated for private aircraft and corporate jets in Los Angeles County, California. An impact area of elevated ultrafine particle (UFP) concentrations was observed extending beyond 660 m downwind and 250 m perpendicular to the wind on the downwind side of SMA. Aircraft operations resulted in average UFP concentrations elevated by factors of 10 and 2.5 at 100 and 660 m downwind, respectively, over background levels. The long downwind impact distance (i.e., compared to nearby freeways at the same time of day) is likely primarily due to the large volumes of aircraft emissions containing higher initial concentrations of UFP than on-road vehicles. Aircraft did not appreciably elevate average levels of black carbon (BC), particle-bound polycyclic aromatic hydrocarbons (PB-PAH), although spikes in concentration of these pollutants were observed associated with jet takeoffs. Jet departures resulted in peak 60-s average concentrations of up to 2.2 x 10(6) cm(-3), 440 ng m(-3), and 30 microg m(-3) for UFP, PB-PAH, and BC, respectively, 100 m downwind of the takeoff area. These peak levels were elevated by factors of 440, 90, and 100 compared to background concentrations. Peak UFP concentrations were reasonably correlated (r(2) = 0.62) with fuel consumption rates associated with aircraft departures, estimated from aircraft weights and acceleration rates. UFP concentrations remained elevated for extended periods associated particularly with jet departures, but also with jet taxi and idle, and operations of propeller aircraft. UFP measured downwind of SMA had a median mode of about 11 nm (electric mobility diameter), which was about half of the 22 nm median mode associated with UFP from heavy duty diesel trucks. The observation of highly elevated ultrafine particle concentrations in a large residential area downwind of this local airport has potential health implications for persons living near general aviation airports.

  10. Antibiotics, Bacteria, and Antibiotic Resistance Genes: Aerial Transport from Cattle Feed Yards via Particulate Matter

    PubMed Central

    McEachran, Andrew D.; Blackwell, Brett R.; Hanson, J. Delton; Wooten, Kimberly J.; Mayer, Gregory D.; Cox, Stephen B.

    2015-01-01

    Background: Emergence and spread of antibiotic resistance has become a global health threat and is often linked with overuse and misuse of clinical and veterinary chemotherapeutic agents. Modern industrial-scale animal feeding operations rely extensively on veterinary pharmaceuticals, including antibiotics, to augment animal growth. Following excretion, antibiotics are transported through the environment via runoff, leaching, and land application of manure; however, airborne transport from feed yards has not been characterized. Objectives: The goal of this study was to determine the extent to which antibiotics, antibiotic resistance genes (ARG), and ruminant-associated microbes are aerially dispersed via particulate matter (PM) derived from large-scale beef cattle feed yards. Methods: PM was collected downwind and upwind of 10 beef cattle feed yards. After extraction from PM, five veterinary antibiotics were quantified via high-performance liquid chromatography with tandem mass spectrometry, ARG were quantified via targeted quantitative polymerase chain reaction, and microbial community diversity was analyzed via 16S rRNA amplification and sequencing. Results: Airborne PM derived from feed yards facilitated dispersal of several veterinary antibiotics, as well as microbial communities containing ARG. Concentrations of several antibiotics in airborne PM immediately downwind of feed yards ranged from 0.5 to 4.6 μg/g of PM. Microbial communities of PM collected downwind of feed yards were enriched with ruminant-associated taxa and were distinct when compared to upwind PM assemblages. Furthermore, genes encoding resistance to tetracycline antibiotics were significantly more abundant in PM collected downwind of feed yards as compared to upwind. Conclusions: Wind-dispersed PM from feed yards harbors antibiotics, bacteria, and ARGs. Citation: McEachran AD, Blackwell BR, Hanson JD, Wooten KJ, Mayer GD, Cox SB, Smith PN. 2015. Antibiotics, bacteria, and antibiotic resistance genes: aerial transport from cattle feed yards via particulate matter. Environ Health Perspect 123:337–343; http://dx.doi.org/10.1289/ehp.1408555 PMID:25633846

  11. Computational Aerodynamic Analysis of Offshore Upwind and Downwind Turbines

    DOE PAGES

    Zhao, Qiuying; Sheng, Chunhua; Afjeh, Abdollah

    2014-01-01

    Aerodynamic interactions of the model NREL 5 MW offshore horizontal axis wind turbines (HAWT) are investigated using a high-fidelity computational fluid dynamics (CFD) analysis. Four wind turbine configurations are considered; three-bladed upwind and downwind and two-bladed upwind and downwind configurations, which operate at two different rotor speeds of 12.1 and 16 RPM. In the present study, both steady and unsteady aerodynamic loads, such as the rotor torque, blade hub bending moment, and base the tower bending moment of the tower, are evaluated in detail to provide overall assessment of different wind turbine configurations. Aerodynamic interactions between the rotor and tower are analyzed,more » including the rotor wake development downstream. The computational analysis provides insight into aerodynamic performance of the upwind and downwind, two- and three-bladed horizontal axis wind turbines.« less

  12. Emissions from an international airport increase particle number concentrations 4-fold at 10 km downwind.

    PubMed

    Hudda, Neelakshi; Gould, Tim; Hartin, Kris; Larson, Timothy V; Fruin, Scott A

    2014-06-17

    We measured the spatial pattern of particle number (PN) concentrations downwind from the Los Angeles International Airport (LAX) with an instrumented vehicle that enabled us to cover larger areas than allowed by traditional stationary measurements. LAX emissions adversely impacted air quality much farther than reported in previous airport studies. We measured at least a 2-fold increase in PN concentrations over unimpacted baseline PN concentrations during most hours of the day in an area of about 60 km(2) that extended to 16 km (10 miles) downwind and a 4- to 5-fold increase to 8-10 km (5-6 miles) downwind. Locations of maximum PN concentrations were aligned to eastern, downwind jet trajectories during prevailing westerly winds and to 8 km downwind concentrations exceeded 75 000 particles/cm(3), more than the average freeway PN concentration in Los Angeles. During infrequent northerly winds, the impact area remained large but shifted to south of the airport. The freeway length that would cause an impact equivalent to that measured in this study (i.e., PN concentration increases weighted by the area impacted) was estimated to be 280-790 km. The total freeway length in Los Angeles is 1500 km. These results suggest that airport emissions are a major source of PN in Los Angeles that are of the same general magnitude as the entire urban freeway network. They also indicate that the air quality impact areas of major airports may have been seriously underestimated.

  13. The effect of chemical weapons incineration on the survival rates of Red-tailed Tropicbirds

    USGS Publications Warehouse

    Schreiber, E.A.; Schenk, G.A.; Doherty, P.F.

    2001-01-01

    In 1992, the Johnston Atoll Chemical Agent Disposal System (JACADS) began incinerating U.S. chemical weapons stockpiles on Johnston Atoll (Pacific Ocean) where about 500,000 seabirds breed, including Red-tailed Tropicbirds (Phaethon rubricauda). We hypothesized that survival rates of birds were lower in those nesting downwind of the incinerator smokestack compared to those upwind, and that birds might move away from the area. From 1992 - 2000 we monitored survival and movements between areas upwind and downwind from the JACADS facility. We used a multi-strata mark recapture approach to model survival, probability of recapture and movement. Probability of recapture was significantly higher for birds in downwind areas (owing to greater recapture effort) and thus was an important 'nuisance' parameter to take into account in modeling. We found no differences in survival between birds nesting upwind ( 0.8588) and downwind (0.8550). There was no consistent difference in movement rates between upwind or downwind areas from year to year: differences found may be attributed to differing vegetation growth and human activities between the areas. Our results suggest that JACADS has had no documentable influence on the survival and year to year movement of Red-tailed Tropicbirds.

  14. Simulating the moderating effect of a lake on downwind temperatures

    NASA Technical Reports Server (NTRS)

    Bill, R. G., Jr.; Chen, E.; Sutherland, R. A.; Bartholic, J. F.

    1979-01-01

    A steady-state, two-dimensional numerical model is used to simulate air temperatures and humidity downwind of a lake at night. Thermal effects of the lake were modelled for the case of moderate and low surface winds under the cold-air advective conditions that occur following the passage of a cold front. Surface temperatures were found to be in good agreement with observations. A comparison of model results with thermal imagery indicated the model successfully predicts the downwind distance for which thermal effects due to the lake are significant.

  15. Optimization of Darrieus turbines with an upwind and downwind momentum model

    NASA Astrophysics Data System (ADS)

    Loth, J. L.; McCoy, H.

    1983-08-01

    This paper presents a theoretical aerodynamic performance optimization for two dimensional vertical axis wind turbines. A momentum type wake model is introduced with separate cosine type interference coefficients for the up and downwind half of the rotor. The cosine type loading permits the rotor blades to become unloaded near the junction of the upwind and downwind rotor halves. Both the optimum and the off design magnitude of the interference coefficients are obtained by equating the drag on each of the rotor halves to that on each of two cosine loaded actuator discs in series. The values for the optimum rotor efficiency, solidity and corresponding interference coefficients have been obtained in a closed form analytic solution by maximizing the power extracted from the downwind rotor half as well as from the entire rotor. A numerical solution was required when viscous effects were incorporated in the rotor optimization.

  16. Using Atmosphere-Forest Measurements To Examine The Potential For Reduced Downwind Dose

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Viner, B.

    2015-10-13

    A 2-D dispersion model was developed to address how airborne plumes interact with the forest at Savannah River Site. Parameters describing turbulence and mixing of the atmosphere within and just above the forest were estimated using measurements of water vapor or carbon dioxide concentration made at the Aiken AmeriFlux tower for a range of stability and seasonal conditions. Stability periods when the greatest amount of mixing of an airborne plume into the forest were found for 1) very unstable environments, when atmospheric turbulence is usually at a maximum, and 2) very stable environments, when the plume concentration at the forestmore » top is at a maximum and small amounts of turbulent mixing can move a substantial portion of the plume into the forest. Plume interactions with the forest during stable periods are of particular importance because these conditions are usually considered the worst-case scenario for downwind effects from a plume. The pattern of plume mixing into the forest was similar during the year except during summer when the amount of plume mixed into the forest was nearly negligible for all but stable periods. If the model results indicating increased deposition into the forest during stable conditions can be confirmed, it would allow for a reduction in the limitations that restrict facility operations while maintaining conservative estimates for downwind effects. Continuing work is planned to confirm these results as well as estimate specific deposition velocity values for use in toolbox models used in regulatory roles.« less

  17. Modeling emergent large-scale structures of barchan dune fields

    NASA Astrophysics Data System (ADS)

    Worman, S. L.; Murray, A.; Littlewood, R. C.; Andreotti, B.; Claudin, P.

    2013-12-01

    In nature, barchan dunes typically exist as members of larger fields that display striking, enigmatic structures that cannot be readily explained by examining the dynamics at the scale of single dunes, or by appealing to patterns in external forcing. To explore the possibility that observed structures emerge spontaneously as a collective result of many dunes interacting with each other, we built a numerical model that treats barchans as discrete entities that interact with one another according to simplified rules derived from theoretical and numerical work, and from field observations: Dunes exchange sand through the fluxes that leak from the downwind side of each dune and are captured on their upstream sides; when dunes become sufficiently large, small dunes are born on their downwind sides ('calving'); and when dunes collide directly enough, they merge. Results show that these relatively simple interactions provide potential explanations for a range of field-scale phenomena including isolated patches of dunes and heterogeneous arrangements of similarly sized dunes in denser fields. The results also suggest that (1) dune field characteristics depend on the sand flux fed into the upwind boundary, although (2) moving downwind, the system approaches a common attracting state in which the memory of the upwind conditions vanishes. This work supports the hypothesis that calving exerts a first order control on field-scale phenomena; it prevents individual dunes from growing without bound, as single-dune analyses suggest, and allows the formation of roughly realistic, persistent dune field patterns.

  18. The Characteristics of Long-range Transboundary Inorganic Secondary Aerosols in Northeast Asia

    NASA Astrophysics Data System (ADS)

    Kim, Y. J.; Carmichael, G. R.; Woo, J. H.; Qiang, Z.

    2014-12-01

    Recurrent particle matter episodes greatly influence air quality in Northeast Asia. According to many studies, a major reason is long-range transport of air pollutant. Large amount of emission of chemical compounds aggravate air pollution in the region. Emitted air pollutants mainly come from industrialized regions along the East China coast. It can be transported over downwind region by the prevailing westerlies. The long-rang transported fine particle certainly attributes to air quality in downwind region, but there are many unknowns on the quantity, transport pattern, and secondary aerosol production mechanism despite the fact with many studies have been performed. Major contributors of PM2.5 are inorganic secondary aerosols, sulfate, nitrate and ammonium, in Korea. Especially high relative contributions of inorganic secondary aerosols appear for westerly wind cases. The main pathway of production of inorganic secondary aerosols is produced by converting from SO2 and NOx during the long-range transport but the contribution varies dramatically depending on season and wind pattern. Sulfate is consistently the primary contributor of PM2.5 still now but we should more concern nitrate because that NOx emissions of China is increasing steeply since 2000 by leading powerplant, industry, and transport, despite downward trend of SO2. In order to better understand regional air quality modeling of the long-range transport, international study, MICS-Asia phase III, has been initiated with many researchers. We will present chemical characteristics of PM2.5 long-range transport during westerly wind cases focused on secondary aerosol, tracking their transport pattern, and production pathway. Results using CMAQ with the modeling domain covering Northeast and Southeast China, Korea, and Japan with 15km resolution will be discussed.

  19. Pu isotopes in soils collected downwind from Lop Nor: regional fallout vs. global fallout.

    PubMed

    Bu, Wenting; Ni, Youyi; Guo, Qiuju; Zheng, Jian; Uchida, Shigeo

    2015-07-17

    For the first time, soil core samples from the Jiuquan region have been analyzed for Pu isotopes for radioactive source identification and radiological assessment. The Jiuquan region is in downwind from the Lop Nor Chinese nuclear test (CNT) site. The high Pu inventories (13 to 546 Bq/m(2)) in most of the sampling locations revealed that this region was heterogeneously contaminated by the regional fallout Pu from the CNTs. The contributions of the CNTs to the total Pu in soils were estimated to be more than 40% in most cases. The (240)Pu/(239)Pu atom ratios in the soils ranged from 0.059 to 0.186 with an inventory-weighted average of 0.158, slightly lower than that of global fallout. This atom ratio could be considered as a mixed fingerprint of Pu from the CNTs. In addition, Pu in soils of Jiuquan region had a faster downward migration rate compared with other investigated places in China.

  20. Pu isotopes in soils collected downwind from Lop Nor: regional fallout vs. global fallout

    PubMed Central

    Bu, Wenting; Ni, Youyi; Guo, Qiuju; Zheng, Jian; Uchida, Shigeo

    2015-01-01

    For the first time, soil core samples from the Jiuquan region have been analyzed for Pu isotopes for radioactive source identification and radiological assessment. The Jiuquan region is in downwind from the Lop Nor Chinese nuclear test (CNT) site. The high Pu inventories (13 to 546 Bq/m2) in most of the sampling locations revealed that this region was heterogeneously contaminated by the regional fallout Pu from the CNTs. The contributions of the CNTs to the total Pu in soils were estimated to be more than 40% in most cases. The 240Pu/239Pu atom ratios in the soils ranged from 0.059 to 0.186 with an inventory-weighted average of 0.158, slightly lower than that of global fallout. This atom ratio could be considered as a mixed fingerprint of Pu from the CNTs. In addition, Pu in soils of Jiuquan region had a faster downward migration rate compared with other investigated places in China. PMID:26184740

  1. The Downwind Hemisphere of the Heliosphere: Eight Years of IBEX-Lo Observations

    NASA Astrophysics Data System (ADS)

    Galli, A.; Wurz, P.; Schwadron, N. A.; Kucharek, H.; Möbius, E.; Bzowski, M.; Sokół, J. M.; Kubiak, M. A.; Fuselier, S. A.; Funsten, H. O.; McComas, D. J.

    2017-12-01

    We present a comprehensive study of energetic neutral atoms (ENAs) of 10 eV to 2.5 keV from the downwind hemisphere of the heliosphere. These ENAs are believed to originate mostly from pickup protons and solar-wind protons in the inner heliosheath. This study includes all low-energy observations made with the Interstellar Boundary Explorer over the first eight years. Because the protons around 0.1 keV dominate the plasma pressure within the inner heliosheath in downwind direction, these ENA observations offer the unique opportunity to constrain the plasma properties and dimensions of the heliosheath where no in situ observations are available. We first derive energy spectra of ENA intensities averaged over time for 49 macropixels covering the entire downwind hemisphere. The results confirm previous studies regarding integral intensities and the roll-over around 0.1 keV energy. With the expanded data set, we now find that ENA intensities at 0.2 and 0.1 keV seem to anti-correlate with solar activity. We then derive the product of total plasma pressure and emission thickness of protons in the heliosheath to estimate lower limits on the thickness of the inner heliosheath. The temporally averaged ENA intensities support a rather spherical shape of the termination shock and a heliosheath thickness between 150 and 210 au for most regions of the downwind hemisphere. Around the nominal downwind direction of 76° ecliptic longitude, the heliosheath is at least 280 au thick. There, the neutral hydrogen density seems to be depleted compared to upwind directions by roughly a factor of 2.

  2. The Downwind Hemisphere of the Heliosphere: Eight Years of IBEX -Lo Observations

    DOE PAGES

    Galli, A.; Wurz, P.; Schwadron, N. A.; ...

    2017-12-05

    We present a comprehensive study of energetic neutral atoms (ENAs) of 10 eV to 2.5 keV from the downwind hemisphere of the heliosphere. These ENAs are believed to originate mostly from pickup protons and solar wind protons in the inner heliosheath. This study includes all low-energy observations made with the Interstellar Boundary Explorer over the first 8 years. Since the protons around 0.1 keV dominate the plasma pressure in the inner heliosheath in downwind direction, these ENA observations offer the unique opportunity to constrain the plasma properties and dimensions of the heliosheath where no in-situ observations are available. We firstmore » derive energy spectra of ENA intensities averaged over time for 49 macropixels covering the entire downwind hemisphere. The results confirm previous studies regarding integral intensities and the roll-over around 0.1 keV energy. With the expanded dataset we now find that ENA intensities at 0.2 and 0.1 keV seem to anti-correlate with solar activity. We then derive the product of total plasma pressure and emission thickness of protons in the heliosheath to estimate lower limits on the thickness of the inner heliosheath. The temporally averaged ENA intensities support a rather spherical shape of the termination shock and a heliosheath thickness between 150 and 210 au for most regions of the downwind hemisphere. Around the nominal downwind direction of 76° ecliptic longitude, the heliosheath is at least 280 au thick. There, the neutral hydrogen density seems to be depleted compared to upwind directions by roughly a factor of 2.« less

  3. The Downwind Hemisphere of the Heliosphere: Eight Years of IBEX -Lo Observations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Galli, A.; Wurz, P.; Schwadron, N. A.

    We present a comprehensive study of energetic neutral atoms (ENAs) of 10 eV to 2.5 keV from the downwind hemisphere of the heliosphere. These ENAs are believed to originate mostly from pickup protons and solar wind protons in the inner heliosheath. This study includes all low-energy observations made with the Interstellar Boundary Explorer over the first 8 years. Since the protons around 0.1 keV dominate the plasma pressure in the inner heliosheath in downwind direction, these ENA observations offer the unique opportunity to constrain the plasma properties and dimensions of the heliosheath where no in-situ observations are available. We firstmore » derive energy spectra of ENA intensities averaged over time for 49 macropixels covering the entire downwind hemisphere. The results confirm previous studies regarding integral intensities and the roll-over around 0.1 keV energy. With the expanded dataset we now find that ENA intensities at 0.2 and 0.1 keV seem to anti-correlate with solar activity. We then derive the product of total plasma pressure and emission thickness of protons in the heliosheath to estimate lower limits on the thickness of the inner heliosheath. The temporally averaged ENA intensities support a rather spherical shape of the termination shock and a heliosheath thickness between 150 and 210 au for most regions of the downwind hemisphere. Around the nominal downwind direction of 76° ecliptic longitude, the heliosheath is at least 280 au thick. There, the neutral hydrogen density seems to be depleted compared to upwind directions by roughly a factor of 2.« less

  4. Emissions from an International Airport Increase Particle Number Concentrations 4-fold at 10 km Downwind

    PubMed Central

    2014-01-01

    We measured the spatial pattern of particle number (PN) concentrations downwind from the Los Angeles International Airport (LAX) with an instrumented vehicle that enabled us to cover larger areas than allowed by traditional stationary measurements. LAX emissions adversely impacted air quality much farther than reported in previous airport studies. We measured at least a 2-fold increase in PN concentrations over unimpacted baseline PN concentrations during most hours of the day in an area of about 60 km2 that extended to 16 km (10 miles) downwind and a 4- to 5-fold increase to 8–10 km (5–6 miles) downwind. Locations of maximum PN concentrations were aligned to eastern, downwind jet trajectories during prevailing westerly winds and to 8 km downwind concentrations exceeded 75 000 particles/cm3, more than the average freeway PN concentration in Los Angeles. During infrequent northerly winds, the impact area remained large but shifted to south of the airport. The freeway length that would cause an impact equivalent to that measured in this study (i.e., PN concentration increases weighted by the area impacted) was estimated to be 280–790 km. The total freeway length in Los Angeles is 1500 km. These results suggest that airport emissions are a major source of PN in Los Angeles that are of the same general magnitude as the entire urban freeway network. They also indicate that the air quality impact areas of major airports may have been seriously underestimated. PMID:24871496

  5. Polychlorinated biphenyls in two salt marsh sediments of the Venice Lagoon.

    PubMed

    Mugnai, Cristian; Giuliani, Silvia; Bellucci, Luca G; Carraro, Claudio; Favotto, Maurizio; Frignani, Mauro

    2011-10-01

    Polychlorinated biphenyls (PCBs) were measured in two dated salt marsh cores of the Venice Lagoon to assess their input chronology and to evaluate the importance of atmospheric deposition as a source. Sampling sites were chosen in order to evidence the differences between areas located leeward and windward with respect to inputs originating in both the city of Venice and the industrial area. Concentrations of PCB indicators (0.13-15.6 ng g⁻¹) increased gradually from the 1930s, reached maxima from the 1950s to the late 1970s, and then decreased. PCB loadings to marshes are driven by both the atmospheric deposition and the resuspension of subtidal sediments, this latter being more important for heavier congeners. The downwind marsh recorded higher fluxes (0.06-9.72 ng cm⁻² year⁻¹) than the upwind one (0.01-0.53 ng cm⁻² year⁻¹). Recent fluxes are rather consistent with bulk deposition measurements. A higher contribution of CB-101 and CB-118 was detected in the intermediate layers of the downwind site, suggesting a different PCB source for the corresponding time interval. In the other marsh, PCBs showed a rather constant composition at all levels (mostly CB-153, CB-138 and CB-180), accounting for a regional influence. Deep layers showed an enrichment of higher chlorinated congeners at both sites, whereas recent samples conserve the patterns typical of surficial and subsurficial subtidal sediments. The scientific approach adopted in this research can be considered as a sort of methodological procedure for the determination of fluxes and pathways of PCBs through the study of marsh cores.

  6. Size distribution and coating thickness of black carbon from the Canadian oil sands operations

    NASA Astrophysics Data System (ADS)

    Cheng, Yuan; Li, Shao-Meng; Gordon, Mark; Liu, Peter

    2018-02-01

    Black carbon (BC) plays an important role in the Earth's climate system. However, parameterizations of BC size and mixing state have not been well addressed in aerosol-climate models, introducing substantial uncertainties into the estimation of radiative forcing by BC. In this study, we focused on BC emissions from the oil sands (OS) surface mining activities in northern Alberta, based on an aircraft campaign conducted over the Athabasca OS region in 2013. A total of 14 flights were made over the OS source area, in which the aircraft was typically flown in a four- or five-sided polygon pattern along flight tracks encircling an OS facility. Another 3 flights were performed downwind of the OS source area, each of which involved at least three intercepting locations where the well-mixed OS plume was measured along flight tracks perpendicular to the wind direction. Comparable size distributions were observed for refractory black carbon (rBC) over and downwind of the OS facilities, with rBC mass median diameters (MMDs) between ˜ 135 and 145 nm that were characteristic of fresh urban emissions. This MMD range corresponded to rBC number median diameters (NMDs) of ˜ 60-70 nm, approximately 100 % higher than the NMD settings in some aerosol-climate models. The typical in- and out-of-plume segments of a flight, which had different rBC concentrations and photochemical ages, showed consistent rBC size distributions in terms of MMD, NMD and the corresponding distribution widths. Moreover, rBC size distributions remained unchanged at different downwind distances from the source area, suggesting that atmospheric aging would not necessarily change rBC size distribution. However, aging indeed influenced rBC mixing state. Coating thickness for rBC cores in the diameter range of 130-160 nm was nearly doubled (from ˜ 20 to 40 nm) within 3 h when the OS plume was transported over a distance of 90 km from the source area.

  7. Evaluation of eight short-term long-range transport models using field data

    NASA Astrophysics Data System (ADS)

    Carhart, R. A.; Policastro, A. J.; Wastag, M.; Coke, L.

    Eight short-term long-range transport models (MESOPUFF, MESOPLUME, MSPUFF, MESOPUFF II, MTDDIS, ARRPA, RADM and RTM-II) have been tested with field data from two data bases involving tracer releases. The Oklahoma data base involved two separate experiments with measurements taken at 100 and 600 km arcs downwind of a 3-h perfluorocarbon release. The Savannah River Plant data base encompassed 15 experiments with measurements taken over 2-5 days at distances of 28-144 km downwind from a 62 m stack release of Kr-85 gas. Application of the American Meteorological Society statistics to the model/data comparisons showed that six of the eight models predicted within a factor of two of the observed concentrations for all of the following: points paired in space and time, points paired in space only, and for points unpaired in space and time. However, the ratio of the standard deviation of residuals to the average observed value showed improvement as more unpairing was done in the comparison of the models with the data. The statistical comparisons reveal a definite tendency of the models to overpredict plume concentrations. Supplemental graphical comparisons showed that plume concentration overprediction is accompanied with an underprediction of plume spreading, and that a definite time lag is often observed between the time of arrival of the observed plume and the time of arrival of the predicted plume. The causes of model/data discrepancies can be largely traced to inadequate wind field modeling that leads to an incorrect temporal and spatial positioning of the plume, and the use of the Turner [Workbook of atmospheric dispersion estimates. U.S. Dept of H.E.W. Publication 999-AP-26 (1970)] curves to downwind distances beyond which they can accurately represent the scales of atmospheric turbulence. The use of multilayer wind field models and the use of the Heffter [ J. appl. Met.4, 153-156 (1965)] formula for lateral plume dispersion close to the source appear to improve model accuracies.

  8. Tar balls are processed, weakly absorbing, primary aerosol particles formed downwind of boreal forest fires

    NASA Astrophysics Data System (ADS)

    Sedlacek, A. J., III; Buseck, P. R.; Adachi, K.; Kleinman, L. I.; Onasch, T. B.; Springston, S. R.

    2017-12-01

    Biomass burning is a major source of light-absorbing black and brown carbonaceous aerosols Brown carbon is a poorly characterized mixture that includes tar balls (TBs), a type of carbonaceous particle unique to biomass burning. Here we describe the first atmospheric observations of the formation and evolution of TBs Aerosol particles were collected on TEM grids during individual aircraft transects at varying downwind distances from the Colockum Tarp wildland fire. The TEM images show primary particles transforming from viscous, impact-deformed particles to spherical TBs. The number fraction of TBs in the wildfire smoke plume increased from less than 5% in samples collected close to the emission source to greater than 40% after 3 hours of aging, with little change in downwind TB diameters. The TB mass fraction increased from 2% near the fire to 23±9% downwind. Single-scatter albedo determined from scattering and absorption measurements increased slightly with downwind distance. Mie calculations show this observation is consistent with weak light absorbance by TBs (m=1.56 - 0.02i) but not consistent with order-of-magnitude stronger absorption observed in different settings. The field-derived TB mass fractions reported here indicate that this particle type should be accounted for in biomass-burn emission inventories.

  9. Remeasured FIA plots reveal tree-level diameter growth and tree mortality impacts of nitrogen deposition on California’s forests

    Treesearch

    Mark E. Fenn; Jeremy S. Fried; Haiganoush K. Preisler; Andrzej Bytnerowicz; Susan Schilling; Sarah Jovan; Olaf Kuegler

    2015-01-01

    The air in California’s forests spans a broad range of purity, from virtually no locally generated pollutants to highly elevated levels of pollutants in forests downwind of urban and agricultural source areas. Ten-year remeasurement data from Forest Inventory and Analysis (FIA) plots in California were used in combination with modelled atmospheric nitrogen (N)...

  10. Nitrogen emissions, deposition, and monitoring in the western United States

    Treesearch

    Mark E. Fenn; Richard Haeuber; Gail S. Tonnesen; Jill S. Baron; Susanne Grossman-Clarke; Diane Hope; Daniel A. Jaffe; Scott Copeland; Linda Geiser; Heather M. Rueth; James O. Sickman

    2003-01-01

    Nitrogen (N) deposition in the western United States ranges from 1 to 4 kilograms (kg) per hectare (ha) per year over much of the region to as high as 30 to 90 kg per ha per year downwind of major urban and agricultural areas. Primary N emissions sources are transportation, agriculture, and industry. Emissions of N as ammonia are about 50% as great as emissions of N as...

  11. An Analysis of Unique Aerial Photographs of Atmospheric Eddies in Marine Stratocumulus Clouds Downwind of Complex Terrain Along the California Coast

    NASA Astrophysics Data System (ADS)

    Muller, B. M.; Herbster, C. G.; Mosher, F. R.

    2013-12-01

    Unique aerial photographs of atmospheric eddies in marine stratocumulus clouds downwind of complex terrain along the California coast are presented and analyzed. While satellite imagery of similar eddies have appeared in the scientific literature since the 1960's, it is believed that these are the first close-up photographs of such eddies, taken from an airplane, to appear in publication. Two photographs by a commercial pilot, flying California coastal routes, are presented: one from July 16, 2006 downwind of Santa Cruz Island, a 740 m peak bordering the Santa Barbara Channel off the California coast; and one from September 12, 2006 near Grover Beach, California, downwind of a headland containing the San Luis Range, a region of complex terrain near San Luis Obispo, California, with ridges ranging approximately from 240 to 550 m elevation. Both eddies occurred in the lee of inversion-penetrating terrain, and were marked by a cyclonic vortex in the clouds with a striking cloud-free 'eye' feature roughly 3 km in diameter. The Santa Cruz Island eddy was 25 km in length and 9-10 km in width, while the Grover Beach eddy was 17 km in length and had a width of 9 km, placing it in the meso-gamma scale of atmospheric features. GOES (Geostationary Operational Environmental Satellite) imagery for both cases was obtained and help to define the lifecycle and motions of the eddies captured in the snapshots. Relevant meteorological observations for the Santa Cruz Island eddy were not located, but in-situ observations from the Diablo Canyon Nuclear Power Plant, California Polytechnic State University (Cal Poly) pier, and the San Luis Obispo County Air Pollution Control District, made possible a more detailed examination of the Grover Beach eddy and its structure. Additionally, we offer speculation on an eddy formation mechanism consistent with the satellite and in-situ observations described in this presentation, and hypotheses from the literature on low Froude number, continuously stratified flow. Attempting to analyze and understand the very small scale meteorological features in this case brings to light a variety of issues of increasing importance to modern meteorology and modeling of atmospheric flows near complex terrain. Fig. 1 Aerial photograph of stratocumulus cloud vortex just north of Santa Cruz Island on July 16, 2006 at 11:26 PDT (18:26 UTC), viewing toward the southwest. Photo by 'KB' courtesy of Capt. Peter Weiss of SkyWest Airlines.

  12. Measured Aerodynamic Interaction of Two Tiltrotors

    NASA Technical Reports Server (NTRS)

    Yamauchi, Gloria K.; Wadcock, Alan J.; Derby, Michael R.

    2003-01-01

    The aerodynamic interaction of two model tilrotors in helicopter-mode formation flight is investigated. Three cenarios representing tandem level flight, tandem operations near the ground, and a single tiltrotor operating above thc ground for varying winds are examined. The effect of aircraft separation distance on the thrust and rolling moment of the trailing aircraft with and without the presence of a ground plane are quantified. Without a ground plane, the downwind aircraft experiences a peak rolling moment when the right (left) roto- of the upwind aircraft is laterally aligned with the left (right) rotor of the downwind aircraft. The presence of the ground plane causes the peak rolling moment on the downwind aircraft to occur when the upwind aircraft is further outboard of the downwind aircraft. Ground plane surface flow visualization images obtained using rufts and oil are used to understand mutual interaction between the two aircraft. These data provide guidance in determining tiltrotor flight formations which minimize disturbance to the trailing aircraft.

  13. Size-resolved chemistry of aerosols produced by Halema'uma'u eruption 2008-2009, Kilauea Volcano, Hawai'i

    NASA Astrophysics Data System (ADS)

    Ilyinskaya, E.; Martin, R.; Edmonds, M.; Sutton, A. J.; Elias, T.; Werner, C. A.

    2009-12-01

    A dense quiescent plume has been emitted continuously from the 2008 eruptive vent in Halema'uma'u crater since March 2008. Aerosol particles were sampled near-source in the young plume (<30 s old) in May 2008 and April 2009, and at 10 km downwind (April 2009 only). We also sampled the plume from Pu'u O'o vent both near-source and 8-10 km downwind (2007 to 2009). Sampling was performed using filter packs and a cascade impactor that collects and segregates PM10 (particle matter <10 μm) into 14 size fractions. The collected PM was analysed for SO42-, F-, Cl-, Na+, K+, Ca2+ and Mg2+. Our results show a distinctive peak of sulphate abundance at ~0.3-0.5 μm in the 2008 and 2009 summit samples. The total SO42- mass concentration collected in each sampling run correlates well with that of metals but poorly with Cl- and F-. Downwind measurements of PM from Halema'uma'u and Pu'u O'o show SO42- in the same narrow size bin (0.3-0.5 μm) with concentrations similar to, or higher than at source. It is noteworthy that the particles appear not to have grown when the plume has drifted 5-10 km downwind. However, a 1 μm size mode of SO42- seen at Pu'u O'o crater rim (not seen at Halema'uma'u) is absent from the downwind plume. This result leads us to believe that the particles grow rapidly after emission but get scavenged efficiently once they reach a certain size (>0.5 μm). The formation of aerosol measured downwind is dominated by oxidation of SO2 to SO42- in the plume. The ratio of Cl-/SO42- is higher downwind than at the source in both Halema'uma'u and Pu'u O'o plumes, and increases further during rainfall; we propose that the Cl--bearing aerosol is formed by dissolution of HCl gas into water droplets in the plume.

  14. Geochemical evidence for an Eolian sand dam across the North and South Platte rivers in Nebraska

    USGS Publications Warehouse

    Muhs, Daniel R.; Swinehart, James B.; Loope, David B.; Been, Josh; Mahan, Shannon; Bush, Charles A.

    2000-01-01

    Geochemical and geomorphic data from dune fields in southwestern Nebraska provide new evidence that the Nebraska Sand Hills once migrated across the North and South Platte rivers and dammed the largest tributary system to the Missouri River. The Lincoln County and Imperial dune fields, which lie downwind of the South Platte River, have compositions intermediate between the Nebraska Sand Hills (quartz-rich) and northeastern Colorado dunes (K-feldspar-rich). The most likely explanation for the intermediate composition is that the Lincoln County and Imperial dunes are derived in part from the Nebraska Sand Hills and in part from the South Platte River. The only mechanism by which the Nebraska Sand Hills could have migrated this far south is by complete infilling of what were probably perennially dry North Platte and South Platte river valleys. Such a series of events would have required an extended drought, both for activation of eolian sand and decreased discharges in the Platte River system. A nearby major tributary of the North Platte River is postulated to have been blocked by eolian sand about 12,000 14C yr B.P. We propose that an eolian sand dam across the Plattes was constructed at about this same time.

  15. Environmental Factors Affecting Asthma and Allergies: Predicting and Simulating Downwind Exposure to Airborne Pollen

    NASA Technical Reports Server (NTRS)

    Luvall, Jeffrey; Estes, Sue; Sprigg, William A.; Nickovic, Slobodan; Huete, Alfredo; Solano, Ramon; Ratana, Piyachat; Jiang, Zhangyan; Flowers, Len; Zelicoff, Alan

    2009-01-01

    This slide presentation reviews the environmental factors that affect asthma and allergies and work to predict and simulate the downwind exposure to airborne pollen. Using a modification of Dust REgional Atmosphere Model (DREAM) that incorporates phenology (i.e. PREAM) the aim was to predict concentrations of pollen in time and space. The strategy for using the model to simulate downwind pollen dispersal, and evaluate the results. Using MODerate-resolution Imaging Spectroradiometer (MODIS), to get seasonal sampling of Juniper, the pollen chosen for the study, land cover on a near daily basis. The results of the model are reviewed.

  16. Aircraft in situ and remote sensing measurements of emissions from Etna volcano, Sicily

    NASA Astrophysics Data System (ADS)

    Vogel, A.; Weber, K.; Fischer, C.; Prata, A. J.; Durant, A. J.

    2012-04-01

    Volcanoes emit particles (silicates and sulphate aerosol) and gases (e.g., water and sulphur dioxide) which influence the radiative balance of the atmosphere. The rate at which sulphur dioxide oxidises to sulphate aerosol is poorly constrained and measurements of downwind abundance are required to quantify the rate at which this process occurs. During July and November 2011, a series of measurements were performed in emissions from Etna Volcano, Sicily, using the University of Applied Sciences (Dusseldorf) research aircraft. Both in situ and remote sensing instrumentation was simultaneously deployed to quantify the down-wind characteristics of gases and particles in the plume emitted by the volcano. In situ particle characteristics were measured using a Grimm 1.109 optical particle counter (microparticles 0.25-32 microns) and Grimm 1320 diffusion electrometer (nanoparticles 25-300 nanometers). Column abundance of sulphur dioxide was measured using a vertically-pointing differential optical absorption spectrometer (DOAS). These measurements were compared to horizontal pathlength-integrated measurements of sulphur dioxide from the Airborne Volcanic Imaging Object Detector (AVOID). Down-wind plume dispersion was discriminated through a series of aircraft transects below and through the volcanic plume. The emissions contained large amounts of nanoparticles relative to microparticles, which reflects gas-phase nucleation of sulphate aerosol. The AVOID system discriminated horizontal layering of volcanic aerosol at altitudes of up to 12,000 ft from a detection range of >50 km. Plume boundaries were discriminated using a combination of the in situ and DOAS measurements in order to compare to the pathlength-integrated measurements from AVOID.

  17. Assessment of the long-term impacts of PM10 and PM2.5 particles from construction works on surrounding areas.

    PubMed

    Azarmi, Farhad; Kumar, Prashant; Marsh, Daniel; Fuller, Gary

    2016-02-01

    Construction activities are common across cities; however, the studies assessing their contribution to airborne PM10 (≤10 μm) and PM2.5 (≤2.5 μm) particles on the surrounding air quality are limited. Herein, we assessed the impact of PM10 and PM2.5 arising from construction works in and around London. Measurements were carried out at 17 different monitoring stations around three construction sites between January 2002 and December 2013. Tapered element oscillating microbalance (TEOM 1400) and OSIRIS (2315) particle monitors were used to measure the PM10 and PM2.5 fractions in the 0.1-10 μm size range along with the ambient meteorological data. The data was analysed using bivariate concentration polar plots and k-means clustering techniques. Daily mean concentrations of PM10 were found to exceed the European Union target limit value of 50 μg m(-3) at 11 monitoring stations but remained within the allowable 35 exceedences per year, except at two monitoring stations. In general, construction works were found to influence the downwind concentrations of PM10 relatively more than PM2.5. Splitting of the data between working (0800-1800 h; local time) and non-working (1800-0800 h) periods showed about 2.2-fold higher concentrations of PM10 during working hours when compared with non-working hours. However, these observations did not allow to conclude that this increase was from the construction site emissions. Together, the polar concentration plots and the k-means cluster analysis applied to a pair of monitoring stations across the construction sites (i.e. one in upwind and the other in downwind) confirmed the contribution of construction sources on the measured concentrations. Furthermore, pairing the monitoring stations downwind of the construction sites showed a logarithmic decrease (with R(2) about 0.9) in the PM10 and PM2.5 concentration with distance. Our findings clearly indicate an impact of construction activities on the nearby downwind areas and a need for developing mitigation measures to limit their escape from the construction sites.

  18. Assessing Model Characterization of Single Source ...

    EPA Pesticide Factsheets

    Aircraft measurements made downwind from specific coal fired power plants during the 2013 Southeast Nexus field campaign provide a unique opportunity to evaluate single source photochemical model predictions of both O3 and secondary PM2.5 species. The model did well at predicting downwind plume placement. The model shows similar patterns of an increasing fraction of PM2.5 sulfate ion to the sum of SO2 and PM2.5 sulfate ion by distance from the source compared with ambient based estimates. The model was less consistent in capturing downwind ambient based trends in conversion of NOX to NOY from these sources. Source sensitivity approaches capture near-source O3 titration by fresh NO emissions, in particular subgrid plume treatment. However, capturing this near-source chemical feature did not translate into better downwind peak estimates of single source O3 impacts. The model estimated O3 production from these sources but often was lower than ambient based source production. The downwind transect ambient measurements, in particular secondary PM2.5 and O3, have some level of contribution from other sources which makes direct comparison with model source contribution challenging. Model source attribution results suggest contribution to secondary pollutants from multiple sources even where primary pollutants indicate the presence of a single source. The National Exposure Research Laboratory (NERL) Computational Exposure Division (CED) develops and evaluates data, deci

  19. Transport of Aerosols: Regional and Global Implications for Climate, Weather, and Air Quality

    NASA Technical Reports Server (NTRS)

    Chin, Mian; Diehl, Thomas; Yu, Hongbin; Bian, Huisheng; Remer, Lorraine; Kahn, Ralph

    2008-01-01

    Long-range transport of atmospheric aerosols can have a significant impact on global climate, regional weather, and local air quality. In this study, we use a global model GOCART together with satellite data and ground-based measurements to assess the emission and transport of pollution, dust, biomass burning, and volcanic aerosols and their implications. In particular, we will show the impact of emissions and long-range transport of aerosols from major pollution and dust source regions to (1) the surface air quality, (2) the atmospheric heating rates, and (3) surface radiation change near the source and downwind regions.

  20. Modeling of ammonia dry deposition downwind of a large poultry facility

    EPA Science Inventory

    This report describes a study investigating dry deposition of ammonia downwind of a poultry facility located on the southern perimeter of the Pocosin Lakes National Wildlife Refuge. This work is a component of a larger project conducted by the U.S. Fish and Wildlife Service: "Imp...

  1. TERRA: a computer code for simulating the transport of environmentally released radionuclides through agriculture

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Baes, C.F. III; Sharp, R.D.; Sjoreen, A.L.

    1984-11-01

    TERRA is a computer code which calculates concentrations of radionuclides and ingrowing daughters in surface and root-zone soil, produce and feed, beef, and milk from a given deposition rate at any location in the conterminous United States. The code is fully integrated with seven other computer codes which together comprise a Computerized Radiological Risk Investigation System, CRRIS. Output from either the long range (> 100 km) atmospheric dispersion code RETADD-II or the short range (<80 km) atmospheric dispersion code ANEMOS, in the form of radionuclide air concentrations and ground deposition rates by downwind location, serves as input to TERRA. User-definedmore » deposition rates and air concentrations may also be provided as input to TERRA through use of the PRIMUS computer code. The environmental concentrations of radionuclides predicted by TERRA serve as input to the ANDROS computer code which calculates population and individual intakes, exposures, doses, and risks. TERRA incorporates models to calculate uptake from soil and atmospheric deposition on four groups of produce for human consumption and four groups of livestock feeds. During the environmental transport simulation, intermediate calculations of interception fraction for leafy vegetables, produce directly exposed to atmospherically depositing material, pasture, hay, and silage are made based on location-specific estimates of standing crop biomass. Pasture productivity is estimated by a model which considers the number and types of cattle and sheep, pasture area, and annual production of other forages (hay and silage) at a given location. Calculations are made of the fraction of grain imported from outside the assessment area. TERRA output includes the above calculations and estimated radionuclide concentrations in plant produce, milk, and a beef composite by location.« less

  2. Explicit modeling of organic chemistry and secondary organic aerosol partitioning for Mexico City and its outflow plume

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lee-Taylor, J.; Madronich, Sasha; Aumont, B.

    2011-12-21

    The evolution of organic aerosols (OA) in Mexico City and its outflow is investigated with the nearly explicit gas phase photochemistry model GECKO-A (Generator of Explicit Chemistry and Kinetics of Organics in the Atmosphere), wherein precursor hydrocarbons are oxidized to numerous intermediate species for which vapor pressures are computed and used to determine gas/particle partitioning in a chemical box model. Precursor emissions included observed C3-10 alkanes, alkenes, and light aromatics, as well as larger n-alkanes (up to C25) not directly observed but estimated by scaling to particulate emissions according to their volatility. Conditions were selected for comparison with observations mademore » in March 2006 (MILAGRO). The model successfully reproduces the magnitude and diurnal shape for both primary (POA) and secondary (SOA) organic aerosols, with POA peaking in the early morning at 15-20 ug m-3, and SOA peaking at 10-15 μg m-3 during mid-day. The majority (> 75%) of the model SOA stems from the large n-alkanes, with the remainder mostly from the light aromatics. Simulated OA elemental composition reproduces observed H/C and O/C ratios reasonably well, although modeled ratios develop more slowly than observations suggest. SOA chemical composition is initially dominated by *- hydroxy ketones and nitrates from the large alkanes, with contributions from peroxy acyl nitrates and, at later times when NOx is lower, organic hydroperoxides. The simulated plume-integrated OA mass continues to increase for several days downwind despite dilution-induced particle evaporation, since oxidation chemistry leading to SOA formation remains strong. In this model, the plume SOA burden several days downwind exceeds that leaving the city by a factor of >3. These results suggest significant regional radiative impacts of SOA.« less

  3. Holocene loess deposition and soil formation as competing processes, Matanuska Valley, southern Alaska

    USGS Publications Warehouse

    Muhs, D.R.; McGeehin, J.P.; Beann, J.; Fisher, E.

    2004-01-01

    Although loess-paleosol sequences are among the most important records of Quaternary climate change and past dust deposition cycles, few modern examples of such sedimentation systems have been studied. Stratigraphic studies and 22 new accelerator mass spectrometry radiocarbon ages from the Matanuska Valley in southern Alaska show that loess deposition there began sometime after ???6500 14C yr B.P. and has continued to the present. The silts are produced through grinding by the Matanuska and Knik glaciers, deposited as outwash, entrained by strong winds, and redeposited as loess. Over a downwind distance of ???40 km, loess thickness, sand content, and sand-plus-coarse-silt content decrease, whereas fine-silt content increases. Loess deposition was episodic, as shown by the presence of paleosols, at distances >10 km from the outwash plain loess source. Stratigraphic complexity is at a maximum (i.e., the greatest number of loesses and paleosols) at intermediate (10-25 km) distances from the loess source. Surface soils increase in degree of development with distance downwind from the source, where sedimentation rates are lower. Proximal soils are Entisols or Inceptisols, whereas distal soils are Spodosols. Ratios of mobile CaO, K2O, and Fe2O3 to immobile TiO2 show decreases in surface horizons with distance from the source. Thus, as in China, where loess deposition also takes place today, eolian sedimentation and soil formation are competing processes. Study of loess and paleosols in southern Alaska shows that particle size can vary over short distances, loess deposition can be episodic over limited time intervals, and soils developed in stabilized loess can show considerable variability under the same vegetation. ?? 2004 University of Washington. All rights reserved.

  4. Air pollution from future giant jetports

    NASA Technical Reports Server (NTRS)

    Fay, J. A.

    1970-01-01

    Because aircraft arrive and depart in a generally upwind direction, the pollutants are deposited in a narrow corridor extending downwind of the airport. Vertical mixing in the turbulent atmosphere will not dilute such a trail, since the pollutants are distributed vertically during the landing and take-off operations. As a consequence, airport pollution may persist twenty to forty miles downwind without much attenuation. Based on this simple meteorological model, calculations of the ambient levels of nitric oxide and particulates to be expected downwind of a giant jetport show them to be about equal to those in present urban environments. These calculations are based on measured emission rates from jet engines and estimates of aircraft performance and traffic for future jetports.

  5. Long-range pollution transport during the MILAGRO-2006 campaign: a case study of a major Mexico City outflow event using free-floating altitude-controlled balloons

    NASA Astrophysics Data System (ADS)

    Voss, P. B.; Zaveri, R. A.; Flocke, F. M.; Mao, H.; Hartley, T. P.; Deamicis, P.; Deonandan, I.; Contreras-Jiménez, G.; Martínez-Antonio, O.; Figueroa Estrada, M.; Greenberg, D.; Campos, T. L.; Weinheimer, A. J.; Knapp, D. J.; Montzka, D. D.; Crounse, J. D.; Wennberg, P. O.; Apel, E.; Madronich, S.; de Foy, B.

    2010-08-01

    One of the major objectives of the Megacities Initiative: Local And Global Research Observations (MILAGRO-2006) campaign was to investigate the long-range transport of polluted Mexico City Metropolitan Area (MCMA) outflow and determine its downwind impacts on air quality and climate. Six research aircraft, including the National Center for Atmospheric Research (NCAR) C-130, made extensive chemical, aerosol, and radiation measurements above MCMA and more than 1000 km downwind in order to characterize the evolution of the outflow as it aged and dispersed over the Mesa Alta, Sierra Madre Oriental, Coastal Plain, and Gulf of Mexico. As part of this effort, free-floating Controlled-Meteorological (CMET) balloons, commanded to change altitude via satellite, made repeated profile measurements of winds and state variables within the advecting outflow. In this paper, we present an analysis of the data from two CMET balloons that were launched near Mexico City on the afternoon of 18 March 2006 and floated downwind with the MCMA pollution for nearly 30 h. The repeating profile measurements show the evolving structure of the outflow in considerable detail: its stability and stratification, interaction with other air masses, mixing episodes, and dispersion into the regional background. Air parcel trajectories, computed directly from the balloon wind profiles, show three transport pathways on 18-19 March: (a) high-altitude advection of the top of the MCMA mixed layer, (b) mid-level outflow over the Sierra Madre Oriental followed by decoupling and isolated transport over the Gulf of Mexico, and (c) low-level outflow with entrainment into a cleaner northwesterly jet above the Coastal Plain. The C-130 aircraft intercepted the balloon-based trajectories three times on 19 March, once along each of these pathways; in all three cases, peaks in urban tracer concentrations and LIDAR backscatter are consistent with MCMA pollution. In comparison with the transport models used in the campaign, the balloon-based trajectories appear to shear the outflow far more uniformly and decouple it from the surface, thus forming a thin but expansive polluted layer over the Gulf of Mexico that is well aligned with the aircraft observations. These results provide critical context for the extensive aircraft measurements made during the 18-19 March MCMA outflow event and may have broader implications for modelling and understanding long-range transport.

  6. Airborne Detection of H5N8 Highly Pathogenic Avian Influenza Virus Genome in Poultry Farms, France.

    PubMed

    Scoizec, Axelle; Niqueux, Eric; Thomas, Rodolphe; Daniel, Patrick; Schmitz, Audrey; Le Bouquin, Sophie

    2018-01-01

    In southwestern France, during the winter of 2016-2017, the rapid spread of highly pathogenic avian influenza H5N8 outbreaks despite the implementation of routine control measures, raised the question about the potential role of airborne transmission in viral spread. As a first step to investigate the plausibility of that transmission, air samples were collected inside, outside and downwind from infected duck and chicken facilities. H5 avian influenza virus RNA was detected in all samples collected inside poultry houses, at external exhaust fans and at 5 m distance from poultry houses. For three of the five flocks studied, in the sample collected at 50-110 m distance, viral genomic RNA was detected. The measured viral air concentrations ranged between 4.3 and 6.4 log 10 RNA copies per m 3 , and their geometric mean decreased from external exhaust fans to the downwind measurement point. These findings are in accordance with the possibility of airborne transmission and question the procedures for outbreak depopulation.

  7. Airborne Detection of H5N8 Highly Pathogenic Avian Influenza Virus Genome in Poultry Farms, France

    PubMed Central

    Scoizec, Axelle; Niqueux, Eric; Thomas, Rodolphe; Daniel, Patrick; Schmitz, Audrey; Le Bouquin, Sophie

    2018-01-01

    In southwestern France, during the winter of 2016–2017, the rapid spread of highly pathogenic avian influenza H5N8 outbreaks despite the implementation of routine control measures, raised the question about the potential role of airborne transmission in viral spread. As a first step to investigate the plausibility of that transmission, air samples were collected inside, outside and downwind from infected duck and chicken facilities. H5 avian influenza virus RNA was detected in all samples collected inside poultry houses, at external exhaust fans and at 5 m distance from poultry houses. For three of the five flocks studied, in the sample collected at 50–110 m distance, viral genomic RNA was detected. The measured viral air concentrations ranged between 4.3 and 6.4 log10 RNA copies per m3, and their geometric mean decreased from external exhaust fans to the downwind measurement point. These findings are in accordance with the possibility of airborne transmission and question the procedures for outbreak depopulation. PMID:29487857

  8. Pollution transport from North America to Greenland during summer 2008

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Thomas, J. L.; Raut, Jean-Christophe; Law, K. S.

    2013-04-10

    Ozone pollution transported to the Arctic is a significant concern because of the rapid, enhanced warming in high northern latitudes, which is caused, in part, by short lived climate forcers, such as ozone. Long range transport of pollution contributes to background and episodic ozone levels in the Arctic. However, the extent to which plumes are photochemically active during transport, particularly during the summer, is uncertain. Regional chemical transport model simulations are used to examine photochemical production 8 of ozone in air masses originating from boreal fire and anthropogenic emissions over North America and during their transport toward the Arctic duringmore » early July 2008. Model results shows good agreement with aircraft data collected over boreal fire source regions in Canada and several days down-wind over Greenland during the study period. Pollutant plumes were transported east and north towards the Arctic and show significant ozone enhancements downwind of source regions. Anthropogenic plumes were more photochemically active than fire plumes. Together, both sources made an important contribution to ozone in pollution plumes transported to the Arctic.« less

  9. Pollution Transport From North America to Greenland During Summer 2008

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Thomas, J. L.; Raut, Jean-Christophe; Law, K. S.

    2013-04-10

    Ozone pollution transported to the Arctic is a significant concern because of the rapid, enhanced warming in high northern latitudes, which is caused, in part, by short lived climate forcers, such as ozone. Long range transport of pollution contributes to background and episodic ozone levels in the Arctic. However, the extent to which plumes are photochemically active during transport, particularly during the summer, is uncertain. Regional chemical transport model simulations are used to examine photochemical production of ozone in air masses originating from boreal fire and anthropogenic emissions over North America and during their transport toward the Arctic during earlymore » July 2008. Model results shows good agreement with aircraft data collected over boreal fire source regions in Canada and several days downwind over Greenland during the study period. Pollutant plumes were transported east and north towards the Arctic and show significant ozone enhancements downwind of source regions. Anthropogenic plumes were more photochemically active than fire plumes. Together, both sources made an important contribution to ozone in pollution plumes transported to the Arctic.« less

  10. Reduction of Air Pollution Levels Downwind of a Road with an Upwind Noise Barrier

    EPA Science Inventory

    We propose a dispersion model to characterize the impact of an upwind solid noise barrier next to a highway on air pollution concentrations downwind of the road. The model is based on data from wind tunnel experiments conducted by Heist et al. (2009). The model assumes that the...

  11. Bayesian Estimation of Fugitive Methane Point Source Emission Rates from a SingleDownwind High-Frequency Gas Sensor

    EPA Science Inventory

    Bayesian Estimation of Fugitive Methane Point Source Emission Rates from a Single Downwind High-Frequency Gas Sensor With the tremendous advances in onshore oil and gas exploration and production (E&P) capability comes the realization that new tools are needed to support env...

  12. 76 FR 48207 - Federal Implementation Plans: Interstate Transport of Fine Particulate Matter and Ozone and...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-08

    ... Problems and NAAQS Addressed 1. Air Quality Problems and NAAQS Addressed 2. FIP Authority for Each State... resolve nonattainment or maintenance problems at downwind state receptors. Downwind states also have... are fossil fuel-fired boilers and turbines producing electricity for sale, as detailed in section VII...

  13. Modeling of Ammonia Dry Deposition to a Pocosin Landscape Downwind of a Large Poultry Facility

    EPA Science Inventory

    A semi-empirical bi-directional flux modeling approach is used to estimate NH3 air concentrations and dry deposition fluxes to a portion of the Pocosin Lakes National Wildlife Refuge (PLNWR) downwind of a large poultry facility. Meteorological patterns at PLNWR are such that som...

  14. Detection of Legionella spp. by a nested-PCR assay in air samples of a wastewater treatment plant and downwind distances in Isfahan

    PubMed Central

    Mirzaee, Seyyed Abbas; Nikaeen, Mahnaz; Hajizadeh, Yaghob; Nabavi, BiBi Fatemeh; Hassanzadeh, Akbar

    2015-01-01

    Background: Wastewater contains a variety of pathogens and bio -aerosols generated during the wastewater treatment process, which could be a potential health risk for exposed individuals. This study was carried out to detect Legionella spp. in the bio -aerosols generated from different processes of a wastewater treatment plant (WWTP) in Isfahan, Iran, and the downwind distances. Materials and Methods: A total of 54 air samples were collected and analyzed for the presence of Legionella spp. by a nested- polymerase chain reaction (PCR) assay. A liquid impingement biosampler was used to capture bio -aerosols. The weather conditions were also recorded. Results: Legionella were detected in 6% of the samples, including air samples above the aeration tank (1/9), belt filter press (1/9), and 250 m downwind (1/9). Conclusion: The result of this study revealed the presence of Legionella spp. in air samples of a WWTP and downwind distance, which consequently represent a potential health risk to the exposed individuals. PMID:25802817

  15. Downwind evolution of the volatility and mixing state of near-road aerosols near a US interstate highway

    NASA Astrophysics Data System (ADS)

    Saha, Provat K.; Khlystov, Andrey; Grieshop, Andrew P.

    2018-02-01

    We present spatial measurements of particle volatility and mixing state at a site near a North Carolina interstate highway (I-40) applying several heating (thermodenuder; TD) experimental approaches. Measurements were conducted in summer 2015 and winter 2016 in a roadside trailer (10 m from road edge) and during downwind transects at different distances from the highway under favorable wind conditions using a mobile platform. Results show that the relative abundance of semi-volatile species (SVOCs) in ultrafine particles decreases with downwind distance, which is consistent with the dilution and mixing of traffic-sourced particles with background air and evaporation of semi-volatile species during downwind transport. An evaporation kinetics model was used to derive particle volatility distributions by fitting TD data. While the TD-derived distribution apportions about 20-30 % of particle mass as semi-volatile (SVOCs; effective saturation concentration, C∗ ≥ 1µm-3) at 10 m from the road edge, approximately 10 % of particle mass is attributed to SVOCs at 220 m, showing that the particle-phase semi-volatile fraction decreases with downwind distance. The relative abundance of semi-volatile material in the particle phase increased during winter. Downwind spatial gradients of the less volatile particle fraction (that remaining after heating at 180 °C) were strongly correlated with black carbon (BC). BC size distribution and mixing state measured using a single-particle soot photometer (SP2) at the roadside trailer showed that a large fraction (70-80 %) of BC particles were externally mixed. Heating experiments with a volatility tandem differential mobility analyzer (V-TDMA) also showed that the nonvolatile fraction in roadside aerosols is mostly externally mixed. V-TDMA measurements at different distances downwind from the highway indicate that the mixing state of roadside aerosols does not change significantly (e.g., BC mostly remains externally mixed) within a few hundred meters from the highway. Our analysis indicates that a superposition of volatility distributions measured in laboratory vehicle tests and of background aerosol can be used to represent the observed partitioning of near-road particles. The results from this study show that exposures and impacts of BC and semi-volatile organics-containing particles in a roadside microenvironment may differ across seasons and under changing ambient conditions.

  16. The impact of photovoltaic (PV) installations on downwind particulate matter concentrations: Results from field observations at a 550-MWAC utility-scale PV plant.

    PubMed

    Ravikumar, Dwarakanath; Sinha, Parikhit

    2017-10-01

    With utility-scale photovoltaic (PV) projects increasingly developed in dry and dust-prone geographies with high solar insolation, there is a critical need to analyze the impacts of PV installations on the resulting particulate matter (PM) concentrations, which have environmental and health impacts. This study is the first to quantify the impact of a utility-scale PV plant on PM concentrations downwind of the project site. Background, construction, and post-construction PM 2.5 and PM 10 (PM with aerodynamic diameters <2.5 and <10 μm, respectively) concentration data were collected from four beta attenuation monitor (BAM) stations over 3 yr. Based on these data, the authors evaluate the hypothesis that PM emissions from land occupied by a utility-scale PV installation are reduced after project construction through a wind-shielding effect. The results show that the (1) confidence intervals of the mean PM concentrations during construction overlap with or are lower than background concentrations for three of the four BAM stations; and (2) post-construction PM 2.5 and PM 10 concentrations downwind of the PV installation are significantly lower than the background concentrations at three of the four BAM stations. At the fourth BAM station, downwind post-construction PM 2.5 and PM 10 concentrations increased marginally by 5.7% and 2.6% of the 24-hr ambient air quality standards defined by the U.S. Environmental Protection Agency, respectively, when compared with background concentrations, with the PM 2.5 increase being statistically insignificant. This increase may be due to vehicular emissions from an access road near the southwest corner of the site or a drainage berm near the south station. The findings demonstrate the overall environmental benefit of downwind PM emission abatement from a utility-scale PV installation in desert conditions due to wind shielding. With PM emission reductions observed within 10 months of completion of construction, post-construction monitoring of downwind PM levels may be reduced to a 1-yr period for other projects with similar soil and weather conditions. This study is the first to analyze impact of a utility photovoltaic (PV) project on downwind particulate matter (PM) concentration in desert conditions. The PM data were collected at four beta attenuation monitor stations over a 3-yr period. The post-construction PM concentrations are lower than background concentrations at three of four stations, therefore supporting the hypothesis of post-construction wind shielding from PV installations. With PM emission reductions observed within 10 months of completion of construction, postconstruction monitoring of downwind PM levels may be reduced to a 1-yr period for other PV projects with similar soil and weather conditions.

  17. Quantifying atmospheric nitrogen outflow from the Front Range of Colorado

    NASA Astrophysics Data System (ADS)

    Neuman, J. A.; Eilerman, S. J.; Brock, C. A.; Brown, S. S.; Dube, W. P.; Herndon, S. C.; Holloway, J. S.; Nowak, J. B.; Roscioli, J. R.; Ryerson, T. B.; Sjostedt, S. J.; Thompson, C. R.; Trainer, M.; Veres, P. R.; Wild, R. J.

    2015-12-01

    Reactive nitrogen emitted to the atmosphere from urban, industrial, and agricultural sources can be transported and deposited far from the source regions, affecting vegetation, soils, and water of sensitive ecosystems. Mitigation of atmospheric nitrogen deposition requires emissions characterization and quantification. Ammonia (NH3), a full suite of gas-phase oxidized nitrogen compounds, and particulate matter were measured from an aircraft that flew downwind from concentrated animal feeding operations, oil and gas extraction facilities, and urban areas along the Colorado Front Range in March and April 2015, as part of the Shale Oil and Natural Gas Nexus (SONGNEX) field study. Additionally, NH3 measurements from a fully instrumented aircraft that flew over the same region in July and August 2014 as part of the Front Range Air Pollution and Photochemistry Experiment (FRAPPE) are used to examine atmospheric nitrogen emission and transport. Cross-wind plume transects and altitude profiles were performed over the source regions and 60-240 km downwind. Plumes were transported in the boundary layer with large NH3 mixing ratios (typically 20-100 ppbv) and were tens of km wide. The NH3 in these plumes provided an atmospheric nitrogen burden greater than 0.2 kg N/ha. Nitrogen oxides and their oxidation products and particulate matter were also enhanced in the plumes, but with concentrations substantially less than NH3. With efficient transport followed by wet deposition, these plumes have the potential to provide a large nitrogen input to the neighboring Rocky Mountain National Park, where nitrogen deposition currently exceeds the ecological critical load of 1.5 kg N/ha/yr.

  18. Longitudinal Study of the Contamination of Air and of Soil Surfaces in the Vicinity of Pig Barns by Livestock-Associated Methicillin-Resistant Staphylococcus aureus

    PubMed Central

    Friese, Anika; Klees, Sylvia; Tenhagen, Bernd A.; Fetsch, Alexandra; Rösler, Uwe; Hartung, Jörg

    2012-01-01

    During 1 year, samples were taken on 4 days, one sample in each season, from pigs, the floor, and the air inside pig barns and from the ambient air and soil at different distances outside six commercial livestock-associated methicillin-resistant Staphylococcus aureus (LA-MRSA)-positive pig barns in the north and east of Germany. LA-MRSA was isolated from animals, floor, and air samples in the barn, showing a range of airborne LA-MRSA between 6 and 3,619 CFU/m3 (median, 151 CFU/m3). Downwind of the barns, LA-MRSA was detected in low concentrations (11 to 14 CFU/m3) at distances of 50 and 150 m; all upwind air samples were negative. In contrast, LA-MRSA was found on soil surfaces at distances of 50, 150, and 300 m downwind from all barns, but no statistical differences could be observed between the proportions of positive soil surface samples at the three different distances. Upwind of the barns, positive soil surface samples were found only sporadically. Significantly more positive LA-MRSA samples were found in summer than in the other seasons both in air and soil samples upwind and downwind of the pig barns. spa typing was used to confirm the identity of LA-MRSA types found inside and outside the barns. The results show that there is regular airborne LA-MRSA transmission and deposition, which are strongly influenced by wind direction and season, of up to at least 300 m around positive pig barns. The described boot sampling method seems suitable to characterize the contamination of the vicinity of LA-MRSA-positive pig barns by the airborne route. PMID:22685139

  19. Longitudinal study of the contamination of air and of soil surfaces in the vicinity of pig barns by livestock-associated methicillin-resistant Staphylococcus aureus.

    PubMed

    Schulz, Jochen; Friese, Anika; Klees, Sylvia; Tenhagen, Bernd A; Fetsch, Alexandra; Rösler, Uwe; Hartung, Jörg

    2012-08-01

    During 1 year, samples were taken on 4 days, one sample in each season, from pigs, the floor, and the air inside pig barns and from the ambient air and soil at different distances outside six commercial livestock-associated methicillin-resistant Staphylococcus aureus (LA-MRSA)-positive pig barns in the north and east of Germany. LA-MRSA was isolated from animals, floor, and air samples in the barn, showing a range of airborne LA-MRSA between 6 and 3,619 CFU/m(3) (median, 151 CFU/m(3)). Downwind of the barns, LA-MRSA was detected in low concentrations (11 to 14 CFU/m(3)) at distances of 50 and 150 m; all upwind air samples were negative. In contrast, LA-MRSA was found on soil surfaces at distances of 50, 150, and 300 m downwind from all barns, but no statistical differences could be observed between the proportions of positive soil surface samples at the three different distances. Upwind of the barns, positive soil surface samples were found only sporadically. Significantly more positive LA-MRSA samples were found in summer than in the other seasons both in air and soil samples upwind and downwind of the pig barns. spa typing was used to confirm the identity of LA-MRSA types found inside and outside the barns. The results show that there is regular airborne LA-MRSA transmission and deposition, which are strongly influenced by wind direction and season, of up to at least 300 m around positive pig barns. The described boot sampling method seems suitable to characterize the contamination of the vicinity of LA-MRSA-positive pig barns by the airborne route.

  20. Spatial variations in soil and plant nitrogen levels caused by ammonia deposition near a cattle feedlot

    NASA Astrophysics Data System (ADS)

    Shen, Jianlin; Chen, Deli; Bai, Mei; Sun, Jianlei; Lam, Shu Kee; Mosier, Arvin; Liu, Xinliang; Li, Yong

    2018-03-01

    Cattle feedlots are significant ammonia (NH3) emission sources, and cause high NH3 deposition. This study was conducted to investigate the responses of soil mineral nitrogen (N), percent cover of plant species, leaf N content, and leaf δ15N to NH3 deposition around a 17,500-head cattle feedlot in Victoria, Australia. Soil samples were collected in May 2015 at 100-m intervals along eight downwind transects, and plant samples were collected in June 2015 from five sites at 50- to 300-m intervals along a grassland transect within 1 km downwind of the feedlot. NH3 deposition was also monitored at five sites within 1 km downwind of the feedlot. The estimated NH3-N deposition rates ranged from 2.9 kg N ha-1 yr-1 at 1 km from the feedlot to 203 kg N ha-1 yr-1 at 100 m from the feedlot. The soil mineral N content was high (22-98 mg kg-1, mainly nitrate), significantly decreased with increasing distance from the feedlot, and significantly increased with increasing NH3-N deposition. With increasing NH3-N deposition, the percent cover of the herb species Cymbonotus lawsonianus increased significantly, but that of the grass species Microlaena stipoides decreased significantly. The leaf total N contents of the grass and herb species were high (>4%), and were linearly, positively correlated with the NH3-N deposition rate. Leaf δ15N values were linearly, negatively correlated with the N deposition rate. These results indicate that the leaf N contents and δ15N values of C. lawsonianus and M. stipoides may be bioindicators of N deposition.

  1. Russian Compliance with the Intermediate Range Nuclear Forces (INF) Treaty: Background and Issues for Congress

    DTIC Science & Technology

    2017-01-27

    Russian Compliance with the Intermediate Range Nuclear Forces (INF) Treaty: Background and Issues for Congress Amy F. Woolf Specialist in... Nuclear Weapons Policy January 27, 2017 Congressional Research Service 7-5700 www.crs.gov R43832 Russian Compliance with the Intermediate Range... Nuclear Forces (INF) Treaty Congressional Research Service Summary The United States and Soviet Union signed the Intermediate-Range Nuclear Forces

  2. Comparison of measured and calculated sound pressure levels around a large horizontal axis wind turbine generator

    NASA Technical Reports Server (NTRS)

    Shepherd, Kevin P.; Willshire, William L., Jr.; Hubbard, Harvey H.

    1989-01-01

    Results are reported from a large number of simultaneous acoustic measurements around a large horizontal axis downwind configuration wind turbine generator. In addition, comparisons are made between measurements and calculations of both the discrete frequency rotational harmonics and the broad band noise components. Sound pressure time histories and noise radiation patterns as well as narrow band and broadband noise spectra are presented for a range of operating conditions. The data are useful for purposes of environmental impact assessment.

  3. Consequence Assessment Methods for Incidents Involving Releases From Liquefied Natural Gas Carriers

    DTIC Science & Technology

    2004-05-13

    the downwind direction. The Thomas (1965) correlation is used to calculate flame length . Flame tilt is estimated using an empirical correlation from...follows: From TNO (1997) • Thomas (1963) correlation for flame length • For an experimental LNG pool fire of 16.8-m diameter, a mass burning flux of...m, flame length ranged from 50 to 78 m, and tilt angle from 27 to 35 degrees From Rew (1996) • Work included a review of recent developments in

  4. Fugitive dust from vehicles traveling on unpaved roads

    Treesearch

    Thomas A. Cuscino; Robert Jennings Heinsohn; Clotworthy, Jr. Birnie

    1977-01-01

    A model has been developed for estimating concentrations of fugitive dust downwind of an unpaved road within a factor of 2 for most cases. The model allows for winds oblique to the road and also for extraction of fugitive dust from the plume as it diffuses to the ground. Experiments were performed to determine the accuracy of the model in estimating downwind...

  5. THE USE OF MODELED ATMOSPHERIC WIND TRAJECTORIES TO DETERMINE POTENTIAL DOWNWIND GENE FLOW; A CASE STUDY USING GM-BENTGRASS

    EPA Science Inventory

    The down-wind dispersal of pollen and the airborne spread of seed are affected by the size, shape and weight of the particles and by the strength, buoyancy and direction of surface winds. An atmospheric model (HYSPLIT model: www.arl.noaa.gov\\ready.html) was used to reconstruct w...

  6. Comparison of upwind and downwind rotor operation of the DOE/NASA 100-kW MOD-0 wind turbine

    NASA Technical Reports Server (NTRS)

    Glasgow, J. C.; Miller, D. R.; Corrigan, R. D.

    1981-01-01

    Tests were conducted on a 38m diameter horizontal axis wind turbine, which had first a rotor downwind of the supporting truss tower and then upwind of the tower. Aside from the placement of the rotor and the direction of rotation of the drive train, the wind turbine was identical for both tests. Three aspects of the test results are compared: rotor blade bending loads, rotor teeter response, and nacelle yaw moments. As a result of the tests, it is shown that while mean flatwise bending moments were unaffected by the placement of the rotor, cyclic flatwise bending tended to increase with wind speed for the downwind rotor while remaining somewhat uniform with wind speed for the upwind rotor, reflecting the effects of increased flow disturbance for downwind rotor. Rotor teeter response was not significantly affected by the rotor location relative to the tower, but appears to reflect reduced teeter stability near rated wind speed for both configurations. Teeter stability appears to return above rated wind speed, however. Nacelle yaw moments are higher for the upwind rotor but do not indicate significant design problems for either configuration.

  7. Exploring the Sandy Province of Herschel Crater

    NASA Image and Video Library

    2017-09-04

    This view from NASA's Mars Reconnaissance Orbiter shows the downwind stretches of a sand sheet in central part of the much larger Herschel Crater. This sandy province began kilometers upwind in a string of barchan sand dunes. As the north-to-south blowing wind weakened downwind, it could no longer fashion the sand into dunes but rather into amorphously-shaped sand sheets. While perhaps not awe-inspiringly beautiful, sand sheets can tell us about Mars' current and past environmental conditions as a piece of the puzzle for understanding habitability. Having dunes upwind of sheets is the opposite situation Earth has, where upwind sand sheets evolve downwind into sand dunes. This mystery is receiving ongoing research to to understand these sandy differences between Earth and Mars. https://photojournal.jpl.nasa.gov/catalog/PIA21933

  8. Some experiments on Yaw stability of wind turbines with various coning angles

    NASA Technical Reports Server (NTRS)

    Bundas, D.; Dugundji, J.

    1981-01-01

    A horizontal axis wind turbine was constructed to study the effect of coning angle on the yawing moments produced. Coning angles of 0 deg, +10 deg and -10 deg were studied in the upwind and downwind cases. Moment and rotational frequency of the blades at each yaw angle setting were taken. It was found that as the coning angle increased from -10 deg to +10 deg in either the upwind or downwind case the stability decreased. The downwind case was slightly more stable for all coning angles than was the upwind case. It is found that all the previous cases were stable for high rotation speeds, but at lower rotation speeds, they were all unstable and could not self start unless held in the wind.

  9. Surface greenhouse gas fluxes downwind of a penguin colony in the maritime sub-Antarctic

    NASA Astrophysics Data System (ADS)

    Drewer, Julia; Braban, Christine F.; Tang, Y. Sim; Anderson, Margaret; Skiba, Ute M.; Dragosits, Ulrike; Trathan, Phil

    2015-12-01

    The relationship between ammonia (NH3) concentrations downwind from a penguin colony and local surface greenhouse gas (GHG) fluxes was investigated on the remote sub-Antarctic Bird Island (54°00‧S, 38°03‧W) during summer 2010 (November and December). A Macaroni penguin (Eudyptes chrysolophus) colony (40,000 pairs) at Goldcrest Point is a large point source of NH3 on the island and a measurement transect of 23 m, 36 m, 70 m, 143 m and 338 m was set up downwind from the colony. Atmospheric NH3 concentrations measured by passive diffusion samplers declined from 23 μg m-3 close to the colony to less than 1 μg m-3 338 m downwind. As increased nitrogen (N) deposition can affect soil carbon (C) and N cycling, it can therefore potentially influence GHG and nitric oxide (NO) emission rates. However, in this study, a clear correlation between surface GHG fluxes and atmospheric NH3 concentrations could not be established. Average fluxes for nitrous oxide (N2O), methane (CH4) and carbon dioxide (CO2) over the entire transect and the eight week study period ranged from 7 to 23 μg N2O-N m-2 h-1, -5.5-245 μg CH4 m-2 h-1, and CO2 respiration rates averaged 2.2 μmol m-2 s-1. Laboratory studies using intact soil cores from the transect also did not show any significant correlation between atmospheric NH3 concentrations and N2O, NO, CH4 emissions or CO2 respiration rates. Overall, fluxes measured in the laboratory study reflected the high variability measured in the field. Large changes in soil depth along the transect, due to the topography of the island, possibly influenced fluxes more than NH3 concentration and seabirds appeared to have a more localised input (e.g. ground nesting birds). However, warmer temperatures might have a large potential to increase GHG fluxes in this ecosystem. This study confirms that GHG fluxes do occur in these ornithogenic ecosystems, however, the scale of the impact remains largely unquantified due to high uncertainties and high spatial variability.

  10. 30 CFR 75.1103-4 - Automatic fire sensor and warning device systems; installation; minimum requirements.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... downwind of each belt drive unit, each tailpiece transfer point, and each belt take-up. If the belt drive, tailpiece, and/or take-up for a single transfer point are installed together in the same air course, and the... downwind of each belt drive unit, each tailpiece transfer point, and each belt take-up; (ii) Not more than...

  11. 30 CFR 75.1103-4 - Automatic fire sensor and warning device systems; installation; minimum requirements.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... downwind of each belt drive unit, each tailpiece transfer point, and each belt take-up. If the belt drive, tailpiece, and/or take-up for a single transfer point are installed together in the same air course, and the... downwind of each belt drive unit, each tailpiece transfer point, and each belt take-up; (ii) Not more than...

  12. 30 CFR 75.1103-4 - Automatic fire sensor and warning device systems; installation; minimum requirements.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... downwind of each belt drive unit, each tailpiece transfer point, and each belt take-up. If the belt drive, tailpiece, and/or take-up for a single transfer point are installed together in the same air course, and the... downwind of each belt drive unit, each tailpiece transfer point, and each belt take-up; (ii) Not more than...

  13. Shelter effect efficacy of sand fences: A comparison of systems in a wind tunnel

    NASA Astrophysics Data System (ADS)

    Wang, Tao; Qu, Jianjun; Ling, Yuquan; Liu, Benli; Xiao, Jianhua

    2018-02-01

    The Lanzhou-Xinjiang High-speed Railway runs through an expansive wind area in the Gobi Desert and blown-sand disasters are a critical issue affecting its operation. To strengthen the blown-sand disaster shelter systems along the railway, the shelter effects of punching plate and wire mesh fences with approximately equal porosity (48%) were simulated in a wind tunnel. The experimental results showed that the wind velocity was reduced to a higher extent by the punching plate fence than by the wire mesh fence. When a single row of sand fencing was used, the wind velocity reduction coefficient (Rcz) values downwind of the punching plate fence and wire mesh fence reached 71.77% and 39.37%, respectively. When double rows of sand fencing were used, the Rcz values downwind of the punching plate and wire mesh fences were approximately 87.48% and 60.81%, respectively. For the flow field structure on the leeward side of the fencing, the deceleration zone behind the punching plate fence was more pronounced than that behind the wire mesh fence. The vortex zone was not obvious and the reverse flow disappeared for both types of fences, which indicates that the turbulent intensity was small. The sand-trapping efficiency of the wire mesh fence was close to that of punching plate fence. When a single row of sand fencing was set up, the total mass flux density decreased, on average, by 65.85% downwind of the wire mesh fence, and 75.06% downwind of the punching plate fence; when double rows of sand fencing were present, the total mass flux density decreased, on average, by 84.53% downwind of the wire mesh fence and 84.51% downwind of the punching plate fence. In addition, the wind-proof efficiency and the sand-proof efficiency of the punching plate fence and the wire mesh fence decreased with increasing wind velocities. Consequently, punching plate and wire mesh fences may effectively control the sand hazard in the expansive wind area of the Gobi Desert.

  14. Canopy wake measurements using multiple scanning wind LiDARs

    NASA Astrophysics Data System (ADS)

    Markfort, C. D.; Carbajo Fuertes, F.; Iungo, V.; Stefan, H. G.; Porte-Agel, F.

    2014-12-01

    Canopy wakes have been shown, in controlled wind tunnel experiments, to significantly affect the fluxes of momentum, heat and other scalars at the land and water surface over distances of ˜O(1 km), see Markfort et al. (EFM, 2013). However, there are currently no measurements of the velocity field downwind of a full-scale forest canopy. Point-based anemometer measurements of wake turbulence provide limited insight into the extent and details of the wake structure, whereas scanning Doppler wind LiDARs can provide information on how the wake evolves in space and varies over time. For the first time, we present measurements of the velocity field in the wake of a tall patch of forest canopy. The patch consists of two uniform rows of 40-meter tall deciduous, plane trees, which border either side of the Allée de Dorigny, near the EPFL campus. The canopy is approximately 250 m long, and it is approximately 40 m wide, along the direction of the wind. A challenge faced while making field measurements is that the wind rarely intersects a canopy normal to the edge. The resulting wake flow may be deflected relative to the mean inflow. Using multiple LiDARs, we measure the evolution of the wake due to an oblique wind blowing over the canopy. One LiDAR is positioned directly downwind of the canopy to measure the flow along the mean wind direction and the other is positioned near the canopy to evaluate the transversal component of the wind and how it varies with downwind distance from the canopy. Preliminary results show that the open trunk space near the base of the canopy results in a surface jet that can be detected just downwind of the canopy and farther downwind dissipates as it mixes with the wake flow above. A time-varying recirculation zone can be detected by the periodic reversal of the velocity near the surface, downwind of the canopy. The implications of canopy wakes for measurement and modeling of surface fluxes will be discussed.

  15. Canopy wake measurements using multiple scanning wind LiDARs

    NASA Astrophysics Data System (ADS)

    Markfort, Corey D.; Carbajo Fuertes, Fernando; Valerio Iungo, Giacomo; Stefan, Heinz; Porté-Agel, Fernando

    2014-05-01

    Canopy wakes have been shown, in controlled wind tunnel experiments, to significantly affect the fluxes of momentum, heat and other scalars at the land and water surface over distances of ~O(1 km), see Markfort et al. (EFM, 2013). However, there are currently no measurements of the velocity field downwind of a full-scale forest canopy. Point-based anemometer measurements of wake turbulence provide limited insight into the extent and details of the wake structure, whereas scanning Doppler wind LiDARs can provide information on how the wake evolves in space and varies over time. For the first time, we present measurements of the velocity field in the wake of a tall patch of forest canopy. The patch consists of two uniform rows of 35-meter tall deciduous, plane trees, which border either side of the Allée de Dorigny, near the EPFL campus. The canopy is approximately 250 m long, and it is 35 m wide, along the direction of the wind. A challenge faced while making field measurements is that the wind rarely intersects a canopy normal to the edge. The resulting wake flow may be deflected relative to the mean inflow. Using multiple LiDARs, we measure the evolution of the wake due to an oblique wind blowing over the canopy. One LiDAR is positioned directly downwind of the canopy to measure the flow along the mean wind direction and the other is positioned near the canopy to evaluate the transversal component of the wind and how it varies with downwind distance from the canopy. Preliminary results show that the open trunk space near the base of the canopy results in a surface jet that can be detected just downwind of the canopy and farther downwind dissipates as it mixes with the wake flow above. A time-varying recirculation zone can be detected by the periodic reversal of the velocity vector near the surface, downwind of the canopy. The implications of canopy wakes for measurement and modeling of surface fluxes will be discussed.

  16. Yardangs in the Qaidam Basin, northwestern China: Distribution and morphology

    NASA Astrophysics Data System (ADS)

    Li, Jiyan; Dong, Zhibao; Qian, Guangqiang; Zhang, Zhengcai; Luo, Wanyin; Lu, Junfeng; Wang, Meng

    2016-03-01

    The northwestern Qaidam Basin exposes one of the largest and highest elevation yardang fields on Earth. The aim of the present study was to describe the distribution and morphology of these yardangs, and analyze the factors responsible for the distribution pattern of these aeolian landforms. The yardang fields are bounded by piedmont alluvial-diluvial fans from the mountain ranges surrounding the basin, except in the south, where they are bounded by dune fields, dry salt flats, lakes, and rivers. This distribution pattern can be attributed to regional tectogenesis and its corresponding environmental impacts. The morphology of the yardangs varies considerably in response to the diverse factors that control their formation and evolution. Long-ridge yardangs are mainly located in the northernmost part of the yardang field, and the long ridges are gradually dissected into smaller ridges in the downwind direction. Further downwind, the convergence of northerly and northwesterly winds and the effects of temporary runoff cause the ridges to gradually transition into mesa yardangs. Saw-toothed crests, and conical and pyramidal yardangs, occur in groups on folded brachyanticlinal structures. Typical whaleback yardangs are found in the southeast, at the northern margin of Dabuxun Lake. Morphological parameters vary among the yardang types. The orientation of the yardangs in the northernmost area is nearly N-S, with a transition towards NW-SE in the southernmost area in response to a change in the dominant wind direction that results from the orientations and positions of the mountain ranges that surround the basin.

  17. Aeolian Sediment Transport Pathways and Aerodynamics at Troughs on Mars

    NASA Technical Reports Server (NTRS)

    Bourke, Mary C.; Bullard, Joanna E.; Barnouin-Jha, Olivier S.

    2004-01-01

    Interaction between wind regimes and topography can give rise to complex suites of aeolian landforms. This paper considers aeolian sediment associated wit11 troughs on Mars and identifies a wider range of deposit types than has previously been documented. These include wind streaks, falling dunes, "lateral" dunes, barchan dunes, linear dunes, transverse ridges, sand ramps, climbing dunes, sand streamers, and sand patches. The sediment incorporated into these deposits is supplied by wind streaks and ambient Planitia sources as well as originating within the trough itself, notably from the trough walls and floor. There is also transmission of sediment between dneTsh. e flow dynamics which account for the distribution of aeolian sediment have been modeled using two-dimensional computational fluid dynamics. The model predicts flow separation on the upwind side of the trough followed by reattachment and acceleration at the downwind margin. The inferred patterns of sediment transport compare well with the distribution of aeolian forms. Model data indicate an increase of wind velocity by approx. 30 % at the downwind trough margin. This suggests that the threshold wind speed necessary for sand mobilization on Mars will be more freqentmlye t in these inclined locations.

  18. Atmospheric Fate and Transport of Agricultural Dust and Ammonia

    NASA Astrophysics Data System (ADS)

    Hiranuma, N.; Brooks, S. D.; Thornton, D. C.; Auvermann, B. W.; Fitz, D. R.

    2008-12-01

    Agricultural fugitive dust and odor are significant sources of localized air pollution in the semi-arid southern Great Plains. Daily episodes of ground-level fugitive dust emissions from the cattle feedlots associated with increased cattle activity in the early evenings are routinely observed, while consistently high ammonia is observed throughout the day. Here we present measurements of aerosol size distributions and concentrations of gas and particulate phase ammonia species collected at a feedlot in Texas during summers of 2006, 2007 and 2008. A GRIMM sequential mobility particle sizer and GRIMM 1.108 aerosol spectrometer were used to determine aerosol size distributions in the range of 10 nm to 20 µm aerodynamic diameter at the downwind and upwind edges of the facility. Using aqueous scrubbers, simultaneous measurements of both gas phase and total ammonia species present in the gas and particle phases were also collected. In addition to the continuous measurements at the edges of the facility, coincident aerosol and ammonia measurements were obtain at an additional site further downwind (~3.5 km). Taken together our measurements will be used to quantify aerosol and ammonia dispersion and transport. Relationships between the fate and transport of the aerosols and ammonia will be discussed.

  19. Halite depositional facies in a solar salt pond: A key to interpreting physical energy and water depth in ancient deposits?

    NASA Astrophysics Data System (ADS)

    Robertson Handford, C.

    1990-08-01

    Subaqueous deposits of aragonite, gypsum, and halite are accumulating in shallow solar salt ponds constructed in the Pekelmeer, a sea-level sauna on Bonaire, Netherlands Antilles. Several halite facies are deposited in the crystallizer ponds in response to differences in water depth and wave energy. Cumulate halite, which originates as floating rafts, is present only along the protected, upwind margins of ponds where low-energy conditions foster their formation and preservation. Cornet crystals with peculiar mushroom- and mortarboard-shaped caps precipitate in centimetre-deep brine sheets within a couple of metres of the upwind or low-energy margins. Downwind from these margins, cornet and chevron halite precipitate on the pond floors in water depths ranging from a few centimetres to ˜60 cm. Halite pisoids with radial-concentric structure are precipitated in the swash zone along downwind high-energy shorelines where they form pebbly beaches. This study suggests that primary halite facies are energy and/or depth dependent and that some primary features, if preserved in ancient halite deposits, can be used to infer physical energy conditions, subenvironments such as low- to high-energy shorelines, and extremely shallow water depths in ancient evaporite basins.

  20. Analytic model for washout of HCl(g) from dispersing rocket exhaust clouds

    NASA Technical Reports Server (NTRS)

    Pellett, G. L.

    1981-01-01

    The potential is investigated that precipitation scavenging of HCl from large solid rocket exhaust clouds may result in unacceptably acidic rain in the Cape Canaveral, Florida, area before atmospheric dispersion reduces HCl concentrations to safe limits. Several analytic expressions for HCl(g) and HCl(g + aq) washout are derived; a geometric mean washout coefficient is recommended. A previous HCl washout model is refined and applied to a space shuttle case (70 t HCl exhausted up to 4 km) and eight Titan 3 (60 percent less exhaust) dispersion cases. The vertical column density (sigma) decays were deduced by application of a multilayer Gaussian diffusion model to seven standard meteorological regimes for overland advection. The Titan 3 decays of sigma and initial rain pH differed greatly among regimes; e.g., a range of 2 pH units was spanned at x 100 km downwind and t = 2 hr. Environmentally significant pH's .5 for infrequent exposures were shown possible at X = 50 km and t 5 hr for the two least dispersive Titan 3 cases. Representative examples of downwind rainwater pH and G(X) are analyzed. Factors affecting the validity of the results are discussed.

  1. Horizontal wind powered reaction turbine electrical generator

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    de Geus, A.M.

    1980-05-27

    A horizontal wind powered electrical generator is disclosed in which a horizontal reaction turbine is disposed within an augmentor cowling which extends downwind of the turbine. First stage curved stator blades interconnect the augmentor with the turbine cowling, and secondary stator blades are spaced downwind from said primary stator blades to extend inwardly from the augmentor to terminate short of the turbine cowling. These secondary stator blades have a greater angle of departure than the primary stator blades to increase the rotational velocity of the air at the expense of its axial velocity while permitting the axial velocity of themore » air moving inwardly of the secondary stator blades to be undiminished. A venturi-structured diffusor is carried by said augmentor in a downwind position to lower the pressure generally and assist the action of the secondary stator blades.« less

  2. Hypothyrodisim and spontaneous abortions among Hanford, Washington, downwinders

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Grossman, C.M.; Morton, W.E.; Nussbaum, R.H.

    1996-05-01

    Spontaneous abortions occurred more than twice as frequently in hypothyroid women, compared with nonhypothyroid women. Both groups of women had lived in the same environment during the same period of time. The high incidence of hypothyroidism in a cohort of several hundred women who lived downwind of the Hanford, Washington, nuclear installation was likely associated with environmental contamination from deliberate releases of radioactive iodine from the facility. 8 refs.

  3. Analysis of In-Canyon Flow Characterisitcs in step-up street canyons

    NASA Astrophysics Data System (ADS)

    PARK, S.; Kim, J.; Choi, W.; Pardyjak, E.

    2017-12-01

    Flow characteristics in strep-up street canyons were investigated focusing on in-canyon region. To see the effects of the building geometry, two building height ratios [ratio of the upwind (Hu) to downwind building heights (Hd) = 0.33, 0.6] were considered and eight building length ratios [ratio of the cross-wind building length (L) to street-canyon width (S) from 0.5 to 4 with the increment of 0.5] were systematically changed. For the model validation, the simulated results were compared with the wind- tunnel data measured for Hu/Hd = 0.33, 0.6 and L/S = 1, 2, 3, and 4. In the CFD model simulations, the corner vortices at the downwind side near the ground level and the recirculation zones above the downwind buildings had the relatively small extents, compared with those in the wind-tunnel experiments. However, the CFD model reproduced the main flow features such as the street-canyon vortices, circulations above the building roof, and the positions of the stagnation points on the downwind building walls in the wind-tunnel experiments reasonably well. By further analyzing the three-dimensional flow structures based on the numerical results simulated in the step-up street canyons, we schematically suggested the flow characteristics with different building-height and building-length ratios.

  4. Downwind pre-aligned rotors for extreme-scale wind turbines

    DOE PAGES

    Loth, Eric; Steele, Adam; Qin, Chao; ...

    2017-03-08

    Downwind force angles are small for current turbines systems (1-5 MW) such that they may be readily accommodated by conventional upwind configurations. However, analysis indicates that extreme-scale systems (10-20 MW) will have larger angles that may benefit from downwind-aligned configurations. To examine potential rotor mass reduction, the pre-alignment concept was investigated a two-bladed configuration by keeping the structural and aerodynamic characteristics of each blade fixed (to avoids a complete blade re-design). Simulations for a 13.2 MW rated rotor at steady-state conditions show that this concept-level two-bladed design may yield 25% rotor mass savings while also reducing average blade stress overmore » all wind speeds. These results employed a pre-alignment on the basis of a wind speed of 1.25 times the rated wind speed. The downwind pre-aligned concept may also reduce damage equivalent loads on the blades by 60% for steady rated wind conditions. Even higher mass and damage equivalent load savings (relative to conventional upwind designs) may be possible for larger systems (15-20 MW) for which load-alignment angles become even larger. Furthermore, much more work is needed to determine whether this concept can be translated into a practical design that must meet a wide myriad of other criteria.« less

  5. A wind-tunnel investigation of wind-turbine wakes in different yawed and loading conditions

    NASA Astrophysics Data System (ADS)

    Bastankhah, Majid; Porté-Agel, Fernando

    2015-04-01

    Wind-turbine wakes have negative effects on wind-farm performance. They are associated with: (a) the velocity deficit, which reduces the generated power of downwind turbines; and (b) the turbulence level, which increases the fatigue loads on downwind turbines. Controlling the yaw angle of turbines can potentially improve the performance of wind farms by deflecting the wake away from downwind turbines. However, except for few studies, wakes of yawed turbines still suffer from the lack of systematic research. To fill this research gap, we performed wind-tunnel experiments in the recirculating boundary-layer wind tunnel at the WIRE Laboratory of EPFL to better understand the wakes of yawed turbines. High-resolution stereoscopic particle image-velocimetry (S-PIV) was used to measure three velocity components in a horizontal plane located downwind of a horizontal-axis, three-blade model turbine. A servo-controller was connected to the DC generator of the turbine, which allowed us to apply different loadings. The power and thrust coefficients of the turbine were also measured for each case. These power and thrust measurements together with the highly-resolved flow measurements enabled us to study different wake characteristics such as the energy entrainment from the outer flow into the wake, the wake deflection and the helicoidal tip vortices for yawed turbines.

  6. Downwind pre-aligned rotors for extreme-scale wind turbines

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Loth, Eric; Steele, Adam; Qin, Chao

    Downwind force angles are small for current turbines systems (1-5 MW) such that they may be readily accommodated by conventional upwind configurations. However, analysis indicates that extreme-scale systems (10-20 MW) will have larger angles that may benefit from downwind-aligned configurations. To examine potential rotor mass reduction, the pre-alignment concept was investigated a two-bladed configuration by keeping the structural and aerodynamic characteristics of each blade fixed (to avoids a complete blade re-design). Simulations for a 13.2 MW rated rotor at steady-state conditions show that this concept-level two-bladed design may yield 25% rotor mass savings while also reducing average blade stress overmore » all wind speeds. These results employed a pre-alignment on the basis of a wind speed of 1.25 times the rated wind speed. The downwind pre-aligned concept may also reduce damage equivalent loads on the blades by 60% for steady rated wind conditions. Even higher mass and damage equivalent load savings (relative to conventional upwind designs) may be possible for larger systems (15-20 MW) for which load-alignment angles become even larger. Furthermore, much more work is needed to determine whether this concept can be translated into a practical design that must meet a wide myriad of other criteria.« less

  7. A simulation of Asian dust events observed from 20 to 29 December 2009 in Korea by using ADAM2

    NASA Astrophysics Data System (ADS)

    Park, Soon-Ung; Choe, Anna; Park, Moon-Soo

    2013-01-01

    The Asian dust Aerosol Model 2 (ADAM2) with the MM5 meteorological model has been employed to study long-range transport process of Asian dust and to estimate dust emission, deposition (wet and dry) and concentration over the Asian dust source region and the downwind regions for dust events observed in Korea during the period of 20-29 December 2009, which is one of the dust events chosen by the 3rd Meeting of Working Group for Joint Research on Dust Sand Storm among Mongolia, China, Japan and Korea to study intensively for the development of an early warning system in Asia. It is found that the model simulates quite well the starting and ending times of dust events and the peak dust concentrations with their occurrence times both in the source region and downwind regions. The dust emission in the dust source region is found to be associated with a developing synoptic weather system accompanied with strong surface winds over the source region that usually travels east to southeastward across the source region and then turns to move northeastward toward the north western Pacific Ocean. The dust emitted in the source region is found to be split into two parts: one is transported southeastward to the East China Sea in front of the surface high pressure system and experiencing enhanced deposition due to the sinking motion induced by the southeastward traveling the surface high pressure system whereas, the other moves northeastward toward the surface low pressure system and then lifted upward to form a upper-level high dust concentration layer that results in a favorable condition for the long-range transport of dust. It is also found that the maximum ten-day total dust emission of about 23 t km-2 occurs in the domain Northwestern China (NWC). However, the maximum ten-day total dust deposition of 21 t km-2 with the maximum mean surface concentration of 555 μg m-3 and the column integrated mean concentration of 2.9 g m-2 occurs in the domain Central-northern China (CNC). The column-integrated PM10 concentration is found to increase toward northeastward especially in the domain North northeastern China (NNEC) due to the upper-level transported high PM10 concentration. The ten-day total dust deposition, mean surface PM10 and column integrated PM10 concentrations in the downwind domains are found to decrease away from the source region from 2.44 t km-2, 112 μg m-3 and 1.68 g m-2, respectively in the domain YES to 0.06 t km-2, 2.1 μg m-3 and 0.4 g m-2, respectively in the domain Northwestern Pacific 1 (NWP1). Much of the total dust deposition is largely contributed by wet deposition in the far downwind region of the seas while that is contributed by dry deposition in the source region.

  8. Wind tunnel tests of a free yawing downwind wind turbine

    NASA Astrophysics Data System (ADS)

    Verelst, D. R. S.; Larsen, T. J.; van Wingerden, J. W.

    2014-12-01

    This research paper presents preliminary results on a behavioural study of a free yawing downwind wind turbine. A series of wind tunnel tests was performed at the TU Delft Open Jet Facility with a three bladed downwind wind turbine and a rotor radius of 0.8 meters. The setup includes an off the shelf three bladed hub, nacelle and generator on which relatively flexible blades are mounted. The tower support structure has free yawing capabilities provided at the base. A short overview on the technical details of the experiment is given as well as a brief summary of the design process. The discussed test cases show that the turbine is stable while operating in free yawing conditions. Further, the effect of the tower shadow passage on the blade flapwise strain measurement is evaluated. Finally, data from the experiment is compared with preliminary simulations using DTU Wind Energy's aeroelastic simulation program HAWC2.

  9. Mercury deposition in snow near an industrial emission source in the western U.S. and comparison to ISC3 model predictions

    USGS Publications Warehouse

    Abbott, M.L.; Susong, D.D.; Krabbenhoft, D.P.; Rood, A.S.

    2002-01-01

    Mercury (total and methyl) was evaluated in snow samples collected near a major mercury emission source on the Idaho National Engineering and Environmental Laboratory (INEEL) in southeastern Idaho and 160 km downwind in Teton Range in western Wyoming. The sampling was done to assess near-field (<12 km) deposition rates around the source, compare them to those measured in a relatively remote, pristine downwind location, and to use the measurements to develop improved, site-specific model input parameters for precipitation scavenging coefficient and the fraction of Hg emissions deposited locally. Measured snow water concentrations (ng L-1) were converted to deposition (ug m-2) using the sample location snow water equivalent. The deposition was then compared to that predicted using the ISC3 air dispersion/deposition model which was run with a range of particle and vapor scavenging coefficient input values. Accepted model statistical performance measures (fractional bias and normalized mean square error) were calculated for the different modeling runs, and the best model performance was selected. Measured concentrations close to the source (average = 5.3 ng L-1) were about twice those measured in the Teton Range (average = 2.7 ng L-1) which were within the expected range of values for remote background areas. For most of the sampling locations, the ISC3 model predicted within a factor of two of the observed deposition. The best modeling performance was obtained using a scavenging coefficient value for 0.25 ??m diameter particulate and the assumption that all of the mercury is reactive Hg(II) and subject to local deposition. A 0.1 ??m particle assumption provided conservative overprediction of the data, while a vapor assumption resulted in highly variable predictions. Partitioning a fraction of the Hg emissions to elemental Hg(0) (a U.S. EPA default assumption for combustion facility risk assessments) would have underpredicted the observed fallout.

  10. Transport aloft drives peak ozone in the Mojave Desert

    NASA Astrophysics Data System (ADS)

    VanCuren, Richard

    2015-05-01

    Transport of anthropogenic pollution eastward out of the Los Angeles megacity region in California has been periodically observed to reach the Colorado River and the Colorado Plateau region beyond. In the 1980s, anthropogenic halocarbon tracers measured in and near the Las Angeles urban area and at a mountain-top site near the Colorado River, 400 km downwind, were shown to have a correlated seven-day cycle explainable by transport from the urban area with a time lag of 1-2 days. Recent short term springtime intensive studies using aircraft observations and regional modeling of long range transport of ozone from the Southern California megacity region showed frequent and persistent ozone impacts at surface sites across the Colorado Plateau and Southern Rocky Mountain region, at distances up to 1500 km, also with time lags of 1-2 days. However, the timing of ozone peaks at low altitude monitoring sites within the Mojave Desert, at distances from 100 to 400 km from the South Coast and San Joaquin Valley ozone source regions, does not show the expected time-lag behavior seen in the larger transport studies. This discrepancy is explained by recognizing ozone transport across the Mojave Desert to occur in a persistent layer of polluted air in the lower free troposphere with a base level at approximately 1 km MSL. This layer impacts elevated downwind sites directly, but only influences low altitude surface ozone maxima through deep afternoon mixing. Pollutants in this elevated layer derive from California source regions (the Los Angeles megacity region and the intensive agricultural region of the San Joaquin Valley), from long-range transport from Asia, and stratospheric down-mixing. Recognition of the role of afternoon mixing during spring and summer over the Mojave explains and expands the significance of previously published reports of ozone and other pollutants observed in and over the Mojave Desert, and resolves an apparent paradox in the timing of ozone peaks due to short-range and long-range transport from the upwind basins.

  11. Did municipal solid waste landfill have obvious influence on polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) in ambient air: A case study in East China.

    PubMed

    Li, Jiafu; Wang, Chong; Du, Lei; Lv, Zhiwei; Li, Xiaonan; Hu, Xuepeng; Niu, Zhiguang; Zhang, Ying

    2017-04-01

    Municipal solid waste (MSW) landfill was a main way to disposal of MSW and almost 95% of MSW was disposed by landfills in the world. In order to understand the influence of MSW landfill on polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) in surrounding atmosphere, 42 ambient air samples were collected and analyzed from surrounding sites, background site, upwind site and downwind site of a MSW landfill in East China. The results of present study were summarized as follows. (1) The total concentrations of PCDD/Fs (∑PCDD/Fs) in ambient air from surrounding sites, background site, upwind site and downwind site were 2.215±1.004, 2.058±0.458, 2.617±1.092 and 1.822±0.566pgNm -3 , respectively. (2) The toxic equivalent concentrations (TEQ) of PCDD/Fs in ambient air from surrounding sites, background site, upwind site and downwind site were 0.103±0.017, 0.096±0.015, 0.120±0.024 and 0.108±0.014pg I-TEQNm -3 , respectively. (3) The congener profiles, ∑PCDD/Fs and TEQ between background atmosphere and surrounding atmosphere of landfill did not show statistically significant difference. (4) The ∑PCDD/Fs and TEQ in ambient air of downwind site were not higher than that of upwind site, suggesting that studied landfill did not have obvious influence on PCDD/Fs in ambient air from downwind site. (5) The 95th percentile carcinogenic risk (CR) of PCDD/Fs in ambient air from surrounding sites, background site, upwind site and downwind site were 8.03×10 -9 , 7.57×10 -9 , 9.69×10 -9 and 8.15×10 -9 , respectively, which were much lower than the threshold value of CR (10 -6 ), suggesting that studied landfill did not influence the CR of PCDD/Fs in surrounding atmosphere and negligible cancer risk occurred. (6) The non-carcinogenic risk (non-CR) analysis indicated that landfill did not have influence on the non-CR of PCDD/Fs in surrounding atmosphere and no obvious non-carcinogenic effects developed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. 3D Volumetric Analysis of Wind Turbine Wake Properties in the Atmosphere Using High-Resolution Doppler Lidar

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Banta, Robert M.; Pichugina, Yelena L.; Brewer, W. Alan

    Wind turbine wakes in the atmosphere are three-dimensional (3D) and time dependent. An important question is how best to measure atmospheric wake properties, both for characterizing these properties observationally and for verification of numerical, conceptual, and physical (e.g., wind tunnel) models of wakes. Here a scanning, pulsed, coherent Doppler lidar is used to sample a turbine wake using 3D volume scan patterns that envelop the wake and simultaneously measure the inflow profile. The volume data are analyzed for quantities of interest, such as peak velocity deficit, downwind variability of the deficit, and downwind extent of the wake, in a mannermore » that preserves the measured data. For the case study presented here, in which the wake was well defined in the lidar data, peak deficits of up to 80% were measured 0.6-2 rotor diameters (D) downwind of the turbine, and the wakes extended more than 11D downwind. Temporal wake variability over periods of minutes and the effects of atmospheric gusts and lulls in the inflow are demonstrated in the analysis. Lidar scanning trade-offs important to ensuring that the wake quantities of interest are adequately sampled by the scan pattern, including scan coverage, number of scans per volume, data resolution, and scan-cycle repeat interval, are discussed.« less

  13. Optical and chemical properties of wildland biomass burning particles measured downwind during the BBOP study

    NASA Astrophysics Data System (ADS)

    Onasch, Timothy; Wormhoudt, Jody; Sedlacek, Arthur; Chand, Duli; Freedman, Andrew

    2017-04-01

    Rapid physical, chemical and optical changes in biomass burning particles were measured downwind (< 3 hours temporally) from wildland fires. The Biomass Burning Observation Project (BBOP), sponsored by the U.S. Department of Energy (DOE), involved the measurement of emissions from wildland fires in the Pacific Northwest and agricultural burns in the Central Southeastern United States observed from the DOE Gulfstream-1 airborne platform over a four month period in 2013. Optical instrumentation included a CAPS PMex particle extinction monitor operating at 630 nm (Aerodyne Research), a photothermal interferometer (Brookhaven National Laboratory) measuring particle absorption at 632 nm and a 3 wavelength nephelometer (TSI). Information about the chemical evolution of the plumes was obtained primarily using a SP-AMS (Aerodyne Research) and a Single Particle Soot Photometer (SP2, Droplet Measurements). The chemical composition of the particulate emissions were characterized in the context of the fire location, combustion conditions, and optical property measurements, including extinction and single scattering albedos. The chemical composition of organic aerosol was found to be rapidly changing as a function of downwind location, with oxygen to carbon ratios increasing as a results of atmospheric aging processes (e.g., dilution, photochemistry). The single scattering albedo, (SSA) of plume aerosols increases downwind as the ratio of total particle extinction to carbon monoxide concentration (a marker for the plume dilution) increases, a finding that is related to changes in organic aerosol chemistry.

  14. Evaluation of the surface roughness effect on suspended particle deposition near unpaved roads

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zhu, Dongzi; Gillies, J. A.; Etyemezian, V.

    2015-11-11

    The downwind transport and deposition of suspended dust raised by a vehicle driving on unpaved roads was studied for four differently vegetated surfaces in the USA states of Kansas and Washington, and one barren surface in Nevada. A 10 m high tower adjacent to the source (z10 m downwind) and an array of multi-channel optical particle counters at three positions downwind of the source measured the flux of particles and the particle size distribution in the advecting dust plumes in the horizontal and vertical directions. Aerodynamic parameters such as friction velocity (u*) and surface roughness length (z0) were calculated frommore » wind speed measurements made on the tower. Particle number concentration, PM10 mass exhibited an exponential decay along the direction of transport. Coarse particles accounted for z95% of the PM10 mass, at least to a downwind distance of 200 m from the source. PM10 removed by deposition was found to increase with increasing particle size and increasing surface roughness under similar moderate wind speed conditions. The surface of dense, long grass (1.2 m high and complete surface cover) had the greatest reduction of PM10 among the five surfaces tested due to deposition induced by turbulence effects created by the rougher surface and by enhanced particle impaction/ interception effects to the grass blades.« less

  15. Airborne detection and quantification of swine influenza a virus in air samples collected inside, outside and downwind from swine barns.

    PubMed

    Corzo, Cesar A; Culhane, Marie; Dee, Scott; Morrison, Robert B; Torremorell, Montserrat

    2013-01-01

    Airborne transmission of influenza A virus (IAV) in swine is speculated to be an important route of virus dissemination, but data are scarce. This study attempted to detect and quantify airborne IAV by virus isolation and RRT-PCR in air samples collected under field conditions. This was accomplished by collecting air samples from four acutely infected pig farms and locating air samplers inside the barns, at the external exhaust fans and downwind from the farms at distances up to 2.1 km. IAV was detected in air samples collected in 3 out of 4 farms included in the study. Isolation of IAV was possible from air samples collected inside the barn at two of the farms and in one farm from the exhausted air. Between 13% and 100% of samples collected inside the barns tested RRT-PCR positive with an average viral load of 3.20E+05 IAV RNA copies/m³ of air. Percentage of exhaust positive air samples also ranged between 13% and 100% with an average viral load of 1.79E+04 RNA copies/m³ of air. Influenza virus RNA was detected in air samples collected between 1.5 and 2.1 Km away from the farms with viral levels significantly lower at 4.65E+03 RNA copies/m³. H1N1, H1N2 and H3N2 subtypes were detected in the air samples and the hemagglutinin gene sequences identified in the swine samples matched those in aerosols providing evidence that the viruses detected in the aerosols originated from the pigs in the farms under study. Overall our results indicate that pigs can be a source of IAV infectious aerosols and that these aerosols can be exhausted from pig barns and be transported downwind. The results from this study provide evidence of the risk of aerosol transmission in pigs under field conditions.

  16. How do Humans interact with the Biotic Pump of South America?

    NASA Astrophysics Data System (ADS)

    Sharma, Ajar; Pande, Saket; Renata Cordeiro Ortigara, Angela; Uhlenbrook, Stefan

    2017-04-01

    The negative effects of the deforestation have been both advertised and down played. However, the effects are far more tangible than what they seem to be. It has been shown that the change in forest cover causes the rainfall patterns to change as the forests work as so-called Biotic Pumps. This changes the water availability in the area by modifying the water balance. Local water balances affect the changes that may take longer to be visible on the larger scales. The Amazon rain forest, one of the most bio-diverse areas worldwide, is an essential part of the biosphere of South America. However, there are clear links between deforestation carried out for agricultural purposes, specifically, Soybean and Sugarcane and the variability in global food prices. Here we analyse the anthropogenic actions that may influence the biotic pump. Variables such as volatility in commodity prices, risk taking capacities, land availability, government subsidies are used to drive the decision making of farmers. These variables are embedded in a lumped biotic pump model made for Brazil, utilizing data from different sources including MODIS, Centro de Previsão do Tempo e Estudos Climáticos (CPTEC), European Centre for Medium-Range Weather Forecasts (ECMWF). The biotic pump model essentially transports atmospheric moisture downwind, part of which falls as rain. The atmospheric moisture 'upwind' accounts for evaporation, incorporating land cover changes in response to land use decisions made by farmers and rainfall. The model is run for scenarios to demonstrate how rain downwind is affected by upwind land cover and provides first insights in to how much rain and productivity (agriculture) downwind is caused by the Amazonian rain forest upwind We then discuss the value of environmental conservation based on marginal productivity analysis, i.e., finding harmony between the conservation of rainforest and the economic growth of the country.

  17. Short-term risk of hospitalization for asthma or bronchiolitis in children living near an aluminum smelter.

    PubMed

    Lewin, Antoine; Buteau, Stéphane; Brand, Allan; Kosatsky, Tom; Smargiassi, Audrey

    2013-01-01

    Few studies have measured the effect of short-term exposure to industrial emissions on the respiratory health of children. Here we estimate the risk of hospitalization for asthma and bronchiolitis in young children associated with their recent exposure to emissions from an aluminum smelter. We used a case-crossover design to assess the risk of hospitalization, February 1999-December 2008, in relation to short-term variation in levels of exposure among children 0-4 years old living less than 7.5 km from the smelter. The percentage of hours per day that the residence of a hospitalized child was in the shadow of winds crossing the smelter was used to estimate the effect of wind-borne emissions on case and crossover days. Community-wide pollutant exposure was estimated through daily mean and daily maximum SO2 and PM2.5 concentrations measured at a fixed monitoring site near the smelter. Odds ratios (OR) were estimated using conditional logistic regressions. The risk of same-day hospitalization for asthma or bronchiolitis increased with the percentage of hours in a day that a child's residence was downwind of the smelter. For children aged 2-4 years, the OR was 1.27 (95% CI=1.03-1.56; n=103 hospitalizations), for an interquartile range (IQR) of 21% of hours being downwind. In this age group, the OR with PM2.5 daily mean levels was slightly smaller than with the hours downwind (OR: 1.22 for an IQR of 15.7 μg/m(3), 95% CI=1.03-1.44; n=94 hospitalizations). Trends were observed between hospitalizations and levels of SO2 for children 2-4 years old. Increasing short-term exposure to emissions from a Quebec aluminum smelter was associated with an increased risk of hospitalization for asthma and bronchiolitis in young children who live nearby. Estimating exposure through records of wind direction allows for the integration of exposure to all pollutants carried from the smelter stack.

  18. Airborne Detection and Quantification of Swine Influenza A Virus in Air Samples Collected Inside, Outside and Downwind from Swine Barns

    PubMed Central

    Corzo, Cesar A.; Culhane, Marie; Dee, Scott; Morrison, Robert B.; Torremorell, Montserrat

    2013-01-01

    Airborne transmission of influenza A virus (IAV) in swine is speculated to be an important route of virus dissemination, but data are scarce. This study attempted to detect and quantify airborne IAV by virus isolation and RRT-PCR in air samples collected under field conditions. This was accomplished by collecting air samples from four acutely infected pig farms and locating air samplers inside the barns, at the external exhaust fans and downwind from the farms at distances up to 2.1 km. IAV was detected in air samples collected in 3 out of 4 farms included in the study. Isolation of IAV was possible from air samples collected inside the barn at two of the farms and in one farm from the exhausted air. Between 13% and 100% of samples collected inside the barns tested RRT-PCR positive with an average viral load of 3.20E+05 IAV RNA copies/m3 of air. Percentage of exhaust positive air samples also ranged between 13% and 100% with an average viral load of 1.79E+04 RNA copies/m3 of air. Influenza virus RNA was detected in air samples collected between 1.5 and 2.1 Km away from the farms with viral levels significantly lower at 4.65E+03 RNA copies/m3. H1N1, H1N2 and H3N2 subtypes were detected in the air samples and the hemagglutinin gene sequences identified in the swine samples matched those in aerosols providing evidence that the viruses detected in the aerosols originated from the pigs in the farms under study. Overall our results indicate that pigs can be a source of IAV infectious aerosols and that these aerosols can be exhausted from pig barns and be transported downwind. The results from this study provide evidence of the risk of aerosol transmission in pigs under field conditions. PMID:23951164

  19. Guidelines for reducing dynamic loads in two-bladed teetering-hub downwind wind turbines

    NASA Astrophysics Data System (ADS)

    Wright, A. D.; Bir, G. S.; Butterfield, C. D.

    1995-06-01

    A major goal of the federal Wind Energy Program is the rapid development and validation of structural models to determine loads and response for a wide variety of different wind turbine configurations operating under extreme conditions. Such codes are crucial to the successful design of future advanced wind turbines. In previous papers the authors described steps they took to develop a model of a two-bladed teetering-hub downwind wind turbine using ADAMS (Automatic Dynamic Analysis of Mechanical Systems), as well as comparison of model predictions to test data. In this paper they show the use of this analytical model to study the influence of various turbine parameters on predicted system loads. They concentrate their study on turbine response in the frequency range of six to ten times the rotor rotational frequency (6P to 10P). Their goal is to identify the most important parameters which influence the response of this type of machine in this frequency range and give turbine designers some general design guidelines for designing two-bladed teetering-hub machines to be less susceptible to vibration. They study the effects of such parameters as blade edgewise and flapwise stiffness, tower top stiffness, blade tip-brake mass, low-speed shaft stiffness, nacelle mass momenta of inertia, and rotor speed. They show which parameters can be varied in order to make the turbine less responsive to such atmospheric inputs as wind shear and tower shadow. They then give designers a set of design guidelines in order to show how these machines can be designed to be less responsive to these inputs.

  20. Examples of the Influence of Turbine Wakes on Downwind Power Output, Surface Wind Speed, Turbulence and Flow Convergence in Large Wind Farms

    NASA Astrophysics Data System (ADS)

    Takle, E. S.; Rajewski, D. A.; Lundquist, J. K.; Doorenbos, R. K.

    2014-12-01

    We have analyzed turbine power and concurrent wind speed, direction and turbulence data from surface 10-m flux towers in a large wind farm for experiments during four summer periods as part of the Crop Wind Energy Experiment (CWEX). We use these data to analyze surface differences for a near-wake (within 2.5 D of the turbine line), far wake (17 D downwind of the turbine line), and double wake (impacted by two lines of turbines about 34 D downwind of the first turbine line) locations. Composites are categorized by10 degree directional intervals and three ambient stability categories as defined by Rajewski et al. (2013): neutral (|z/L|<0.05), stable (z/L>0.05) and unstable (z/L<-0.05), where z is the height of the measurement and L is the Monin-Obhukov length. The dominant influence of the turbines is under stably stratified conditions (i. e., mostly at night). A 25% to 40% increase in mean wind speed occurs when turbine wakes are moving over the downwind station at a distance of 2.8 D and 5.4 D (D = fan diameter). For the double wake condition (flux station leeward of two lines of turbines) we find a daytime (unstable conditions) speed reduction of 20% for southerly wind, but for nighttime (stable conditions) the surface speeds are enhancedby 40-60% for SSW-SW winds. The speedup is reduced as wind directions shift to the west. We interpret these speed variations as due to the rotation of the wake and interaction (or not) with higher speed air above the rotor layer in highly sheared nocturnal low-level jet conditions. From a cluster of flux stations and three profiling lidars deployed within and around a cluster of turbines in 2013 (CWEX-13) we found evidence of mesoscale influences. In particular, surface convergence (wind direction deflection of 10-20 degrees) was observed during periods of low nighttime winds (hub-height winds of 4-6 m/s) with power reduction of 50-75%. This is consistent with a similar range of deflection observed from a line of turbines in CWEX-11, In the mid to late afternoon hours when hub-height wind speeds are between 5-10 m/s convergence periods have been observed, with power enhancements of 20-40% at several locations around the farm.

  1. The Importance of Tree Size and Fecundity for Wind Dispersal of Big-Leaf Mahogany

    PubMed Central

    Norghauer, Julian M.; Nock, Charles A.; Grogan, James

    2011-01-01

    Seed dispersal by wind is a critical yet poorly understood process in tropical forest trees. How tree size and fecundity affect this process at the population level remains largely unknown because of insufficient replication across adults. We measured seed dispersal by the endangered neotropical timber species big-leaf mahogany (Swietenia macrophylla King, Meliaceae) in the Brazilian Amazon at 25 relatively isolated trees using multiple 1-m wide belt transects extended 100 m downwind. Tree diameter and fecundity correlated positively with increased seed shadow extent; but in combination large, high fecundity trees contributed disproportionately to longer-distance dispersal events (>60 m). Among three empirical models fitted to seed density vs. distance in one dimension, the Student-t (2Dt) generally fit best (compared to the negative exponential and inverse power). When seedfall downwind was modelled in two dimensions using a normalised sample, it peaked furthest downwind (c. 25 m) for large, high-fecundity trees; with the inverse Gaussian and Weibull functions providing comparable fits that were slightly better than the lognormal. Although most seeds fell within 30 m of parent trees, relatively few juveniles were found within this distance, resulting in juvenile-to-seed ratios peaking at c. 35–45 m. Using the 2Dt model fits to predict seed densities downwind, coupled with known fecundity data for 2000–2009, we evaluated potential Swietenia regeneration near adults (≤30 m dispersal) and beyond 30 m. Mean seed arrival into canopy gaps >30 m downwind was more than 3× greater for large, high fecundity trees than small, high-fecundity trees. Tree seed production did not necessarily scale up proportionately with diameter, and was not consistent across years, and this resulting intraspecific variation can have important consequences for local patterns of dispersal in forests. Our results have important implications for management and conservation of big-leaf mahogany populations, and may apply to other threatened wind-dispersed Meliaceae trees. PMID:21408184

  2. Effects of emission reductions at the Hayden powerplant on precipitation, snowpack, and surface-water chemistry in the Mount Zirkel Wilderness Area, Colorado, 1995-2003

    USGS Publications Warehouse

    Mast, M. Alisa; Campbell, Donald H.; Ingersoll, George P.

    2005-01-01

    Precipitation, snowpack, and surface-water samples collected during 1995-2003 were analyzed to evaluate the effects of emission reductions at the Hayden powerplant on water chemistry in the Mount Zirkel Wilderness Area. The Hayden powerplant, one of two large coal-fired powerplants in the Yampa Valley, was retrofitted with control systems during late 1998 and 1999 to reduce emissions of sulfur dioxide and nitrogen oxide--the primary precursors of haze and acidic precipitation. The U.S. Geological Survey, in cooperation with the Colorado Department of Public Health and Environment, evaluated three water-chemistry data sets: wet-only precipitation chemistry from the National Atmospheric Deposition Program, snowpack chemistry from the Rocky Mountain snowpack network, and surface-water chemistry from a U.S. Geological Survey long-term lakes monitoring program. Concentrations and deposition rates of selected constituents were compared for the periods before and after emission reductions at the Hayden powerplant. Data collected during 1995-98 were used to represent the pre-control period, and data collected during 2000-2003 were used to represent the post-control period. Ten stations in the National Atmospheric Deposition Program were evaluated including two that were directly downwind from the Hayden powerplant (Dry Lake and Buffalo Pass) and eight that were upwind or more distant (more than 100 kilometers) from the powerplant. Precipitation amount at all 10 precipitation stations was lower in the post-control period than the pre-control period as a result of a regional drought that persisted during the post-control period. In contrast to precipitation amount, there was no consistent pattern of change in sulfate concentrations between periods, indicating that the drought did not have a concentrating effect on sulfate or that trends in regional sulfur dioxide emissions masked its influence. Sulfate concentrations increased at three stations between periods, remained the same at three stations, and decreased at four stations. The largest change in average annual sulfate concentrations occurred at the two precipitation stations downwind from the Hayden powerplant, decreasing by 3.3 microequivalents per liter at Dry Lake and by 2.2 microequivalents per liter at Buffalo Pass. Declines in annual sulfate deposition also were greater at Dry Lake (3.4 kilograms per hectare) and Buffalo Pass (3.3 kilograms per hectare) than at the other stations, which ranged from 0.2 to 1.7 kilograms per hectare. These results indicate that emission reductions at the Hayden powerplant have been a factor in declines in atmospheric deposition of sulfate downwind from the powerplant. Nitrate, ammonium, and base-cation concentrations, in contrast to sulfate, were higher in the post-control period than the pre-control period at all 10 stations, most likely due to a concentrating effect of the drought. Twenty-two snowpack sites in the Rocky Mountain snowpack network were evaluated including 4 sites that were located directly downwind from the Hayden powerplant and 18 sites that were upwind or more distant (as much as 200 kilometers) from the powerplant. The water content of the snowpack at maximum accumulation was lower in the post-control period than the pre-control period, reflecting the regional drought. Although there were small declines in snowpack sulfate concentrations at the downwind stations between the pre- and post-control periods, the difference was not statistically significant, indicating emission reductions had a weaker effect on snowpack chemistry than precipitation chemistry. Sulfate deposition decreased at all four downwind sites in the post-control period, primarily reflecting both lower water content and concentrations in the snowpack. As observed at the precipitation stations, nitrate, ammonium, and base-cation concentrations at all 22 sites were significantly higher in the post-control period than the pre-control period, reflecting d

  3. Modeling the oxidative capacity of the atmosphere of the south coast air basin of California. 1. Ozone formation metrics.

    PubMed

    Griffin, Robert J; Revelle, Meghan K; Dabdub, Donald

    2004-02-01

    Metrics associated with ozone (O3) formation are investigated using the California Institute of Technology (CIT) three-dimensional air-quality model. Variables investigated include the O3 production rate (P(O3)), O3 production efficiency (OPE), and total reactivity (the sum of the reactivity of carbon monoxide (CO) and all organic gases that react with the hydroxyl radical). Calculations are spatially and temporally resolved; surface-level and vertically averaged results are shown for September 9, 1993 for three Southern California locations: Central Los Angeles, Azusa, and Riverside. Predictions indicate increasing surface-level O3 concentrations with distance downwind, in line with observations. Surface-level and vertically averaged P(O3) values peak during midday and are highest downwind; surface P(O3) values are greater than vertically averaged values. Surface OPEs generally are highest downwind and peak during midday in downwind locations. In contrast, peaks occur in early morning and late afternoon in the vertically averaged case. Vertically averaged OPEs tend to be greater than those for the surface. Total reactivities are highest in upwind surface locations and peak during rush hours; vertically averaged reactivities are smaller and tend to be more uniform temporally and spatially. Total reactivity has large contributions from CO, alkanes, alkenes, aldehydes, unsubstituted monoaromatics, and secondary organics. Calculations using estimated emissions for 2010 result in decreases in P(O3) values and reactivities but increases in OPEs.

  4. Contribution of Vegetation to the Microbial Composition of Nearby Outdoor Air

    PubMed Central

    Adams, Rachel I.

    2016-01-01

    ABSTRACT Given that epiphytic microbes are often found in large population sizes on plants, we tested the hypothesis that plants are quantitatively important local sources of airborne microorganisms. The abundance of microbial communities, determined by quantifying bacterial 16S RNA genes and the fungal internal transcribed spacer (ITS) region, in air collected directly above vegetation was 2- to 10-fold higher than that in air collected simultaneously in an adjacent nonvegetated area 50 m upwind. Nonmetric multidimensional scaling revealed that the composition of airborne bacteria in upwind air samples grouped separately from that of downwind air samples, while communities on plants and downwind air could not be distinguished. In contrast, fungal taxa in air samples were more similar to each other than to the fungal epiphytes. A source-tracking algorithm revealed that up to 50% of airborne bacteria in downwind air samples were presumably of local plant origin. The difference in the proportional abundances of a given operational taxonomic unit (OTU) between downwind and upwind air when regressed against the proportional representation of this OTU on the plant yielded a positive slope for both bacteria and fungi, indicating that those taxa that were most abundant on plants proportionally contributed more to downwind air. Epiphytic fungi were less of a determinant of the microbiological distinctiveness of downwind air and upwind air than epiphytic bacteria. Emigration of epiphytic bacteria and, to a lesser extent, fungi, from plants can thus influence the microbial composition of nearby air, a finding that has important implications for surrounding ecosystems, including the built environment into which outdoor air can penetrate. IMPORTANCE This paper addresses the poorly understood role of bacterial and fungal epiphytes, the inhabitants of the aboveground plant parts, in the composition of airborne microbes in outdoor air. It is widely held that epiphytes contribute to atmospheric microbial assemblages, but much of what we know is limited to qualitative assessments. Elucidating the sources of microbes in outdoor air can inform basic biological processes seen in airborne communities (e.g., dispersal and biogeographical patterns). Furthermore, given the considerable contribution of outdoor air to microbial communities found within indoor environments, the understanding of plants as sources of airborne microbes in outdoor air might contribute to our understanding of indoor air quality. With an experimental design developed to minimize the likelihood of other-than-local plant sources contributing to the composition of airborne microbes, we provide direct evidence that plants are quantitatively important local sources of airborne microorganisms, with implications for the surrounding ecosystems. PMID:27107117

  5. Contribution of Vegetation to the Microbial Composition of Nearby Outdoor Air.

    PubMed

    Lymperopoulou, Despoina S; Adams, Rachel I; Lindow, Steven E

    2016-07-01

    Given that epiphytic microbes are often found in large population sizes on plants, we tested the hypothesis that plants are quantitatively important local sources of airborne microorganisms. The abundance of microbial communities, determined by quantifying bacterial 16S RNA genes and the fungal internal transcribed spacer (ITS) region, in air collected directly above vegetation was 2- to 10-fold higher than that in air collected simultaneously in an adjacent nonvegetated area 50 m upwind. Nonmetric multidimensional scaling revealed that the composition of airborne bacteria in upwind air samples grouped separately from that of downwind air samples, while communities on plants and downwind air could not be distinguished. In contrast, fungal taxa in air samples were more similar to each other than to the fungal epiphytes. A source-tracking algorithm revealed that up to 50% of airborne bacteria in downwind air samples were presumably of local plant origin. The difference in the proportional abundances of a given operational taxonomic unit (OTU) between downwind and upwind air when regressed against the proportional representation of this OTU on the plant yielded a positive slope for both bacteria and fungi, indicating that those taxa that were most abundant on plants proportionally contributed more to downwind air. Epiphytic fungi were less of a determinant of the microbiological distinctiveness of downwind air and upwind air than epiphytic bacteria. Emigration of epiphytic bacteria and, to a lesser extent, fungi, from plants can thus influence the microbial composition of nearby air, a finding that has important implications for surrounding ecosystems, including the built environment into which outdoor air can penetrate. This paper addresses the poorly understood role of bacterial and fungal epiphytes, the inhabitants of the aboveground plant parts, in the composition of airborne microbes in outdoor air. It is widely held that epiphytes contribute to atmospheric microbial assemblages, but much of what we know is limited to qualitative assessments. Elucidating the sources of microbes in outdoor air can inform basic biological processes seen in airborne communities (e.g., dispersal and biogeographical patterns). Furthermore, given the considerable contribution of outdoor air to microbial communities found within indoor environments, the understanding of plants as sources of airborne microbes in outdoor air might contribute to our understanding of indoor air quality. With an experimental design developed to minimize the likelihood of other-than-local plant sources contributing to the composition of airborne microbes, we provide direct evidence that plants are quantitatively important local sources of airborne microorganisms, with implications for the surrounding ecosystems. Copyright © 2016 Lymperopoulou et al.

  6. Large-scale carbon fiber tests

    NASA Technical Reports Server (NTRS)

    Pride, R. A.

    1980-01-01

    A realistic release of carbon fibers was established by burning a minimum of 45 kg of carbon fiber composite aircraft structural components in each of five large scale, outdoor aviation jet fuel fire tests. This release was quantified by several independent assessments with various instruments developed specifically for these tests. The most likely values for the mass of single carbon fibers released ranged from 0.2 percent of the initial mass of carbon fiber for the source tests (zero wind velocity) to a maximum of 0.6 percent of the initial carbon fiber mass for dissemination tests (5 to 6 m/s wind velocity). Mean fiber lengths for fibers greater than 1 mm in length ranged from 2.5 to 3.5 mm. Mean diameters ranged from 3.6 to 5.3 micrometers which was indicative of significant oxidation. Footprints of downwind dissemination of the fire released fibers were measured to 19.1 km from the fire.

  7. Aeolian Features of Scandia Cavi

    NASA Image and Video Library

    2015-09-30

    This image from NASA Mars Reconnaissance Orbiter spacecraft shows modified barchan dunes with shapes that resemble raptor claws. The unusual morphology of these dunes suggests a limited supply of windblown sand. Winds likely blew from the northeast resulting in elongate dunes with an asymmetric downwind point. The transverse crests of the smaller ripples/mega-ripple bed-forms surrounding the dune, echo the dominant downwind direction towards the southwest. This locality is in the Northern Lowlands directly east of Dokka Crater in Scandia Cavi. http://photojournal.jpl.nasa.gov/catalog/PIA19962

  8. Observed chlorine concentrations during Jack Rabbit I and Lyme Bay field experiments

    NASA Astrophysics Data System (ADS)

    Hanna, Steven; Chang, Joseph; Huq, Pablo

    2016-01-01

    As part of planning for a series of field experiments where large quantities (up to 20 tons) of pressurized liquefied chlorine will be released, observations from previous chlorine field experiments are analyzed to estimate the ranges of chlorine concentrations expected at various downwind distances. In five field experiment days during the summer 2010 Jack Rabbit I (JR I) field trials, up to two tons of chlorine were released and concentrations were observed at distances, x, from 25 to 500 m. In the 1927 Lyme Bay (LB) experiments, there were four days of trials, where 3-10 tons of chlorine were released in about 15 min from the back of a ship. Concentrations were sampled at LB from four ships sailing across the cloud path at downwind distances in the range from about 350 to 3000 m. Thus, the distances from which JR I concentrations were available slightly overlapped the LB distances. One-minute arc-maximum chlorine concentrations, C (g/m3), were analyzed from four JR I trials and two LB trials. Normalized concentrations (Cu/Q) were plotted versus x (m), where u (m/s) is measured wind speed at heights of 2-10 m and Q (g/s) is continuous mass release rate. It is found that the JR I and LB Cu/Q observations smoothly merge with each other and fall along a line with approximate slope of -2 at distances beyond about 200 m (i.e., Cu/Q is proportional to x-2). At x < 200 m, where dense gas effects are more important, the slope is less (about -1.5). Most of the data points are within a factor of two of the "best-fit" line.

  9. Wind speed and sediment transport recovery in the lee of a vegetated and denuded nebkha within a nebkha dune field

    NASA Astrophysics Data System (ADS)

    Gillies, John A.; Nield, Joanna M.; Nickling, William G.

    2014-03-01

    Field observations of scaled wind speed and sand transport recovery in the lee of a nebka within a field of nebkhas and then subsequently for the nebkha denuded of its vegetation cover were collected. The measurements of wind speed at 0.4 times the element height indicate that for both conditions wind speed recovery in the lee is exponential. The porous vegetation cover influences the rate of this recovery being more gradual for the vegetated form. The return to equilibrium wind speed occurs in both cases at approximately eight element heights. For either case the recovery of shear stress and the return to a constant value occurs much closer to the bluff body form than has been described for porous fences. The recovery of sand transport in the lee appears to be more rapid for the un-vegetated condition, which corresponds to the observed faster rate of wind speed increase. The observations did not show a continual increase in saltation flux with increasing downwind distance due to the increasing shear stress downwind and the increase that may be expected due to the fetch effect. The change in saltation flux with downwind distance was controlled by the sediment supply, which diminished with downwind distance. The interaction of a changing shear stress and the zone of influence created by the wind as it interacts with the roughness dimensions, along with the distribution of sediment available for transport bring increased complexity to modeling sand flux for this type of environment over different temporal scales.

  10. Aerosol and Urban Land Use Effect on Rainfall Around Cities in Indo-Gangetic Basin From Observations and Cloud Resolving Model Simulations

    NASA Astrophysics Data System (ADS)

    Sarangi, Chandan; Tripathi, S. N.; Qian, Yun; Kumar, Shailendra; Ruby Leung, L.

    2018-04-01

    Coupling of urban land use land cover (LULC) and aerosol loading on rainfall around cities in the Gangetic Basin (GB) is examined here. Long-term observations illustrate more rainfall at urban core and climatological downwind regions compared to the upwind regions of Kanpur, a metropolitan area located in central GB. In addition, analysis of a 15 day cloud resolving simulation using the Weather Research and Forecasting model also illustrated similar rainfall pattern around other major cities in the GB. Interestingly, the enhancement of downwind rainfall was greater than that over urban regions, and it was positively associated with both the urban area of the city and ambient aerosol loading during the propagating storm. Further, to gain a process-level understanding, a typical storm that propagated northwestward across Kanpur was simulated using Weather Research and Forecasting under three different scenarios. Case 1 has realistic LULC representation of Kanpur, while the grids representing the Kanpur urban region were replaced by cropland LULC pattern in Case 2. Comparison illustrated that urban heat island effect caused convergence of winds and moisture in the lower troposphere, which enhances convection over urban region and induced more rainfall over the urban core compared to upwind regions. Case 3 is similar to Case 1 but lower aerosol concentration (by a factor of 100) over the storm region. Analysis shows that aerosol-induced microphysical changes delay the initiation of warm rain (over the upwind region) but enhance ice phase particle formation in latter stages (over the urban and downwind regions) resulting in increase in downwind rainfall.

  11. Continental Tele-connections of ET and Precipitation: Tractable Models, Viable Management, and Potential Monitoring.

    NASA Astrophysics Data System (ADS)

    Selker, J. S.; Higgins, C. W.; Tai, L. C. M.

    2014-12-01

    The linkage between large-scale manipulation of land cover and resulting patterns of precipitation has been a long-standing problem. For example, what is the impact of the Columbia River project's 2,700 km^2 irrigated area (applying approximately 300 m^3/s) on the down-wind continental rainfall in North America? Similarly, can we identify places on earth where planting large-scale runoff-reducing forests might increase down-wind precipitation, thus leading to magnified carbon capture? In this talk we present an analytical Lagrangian framework for the prediction of incremental increases in down-wind precipitation due to land surface evaporation and transpiration. We compare these predictions to recently published rainfall recycling values from the literature. Focus is on the Columbia basin (Pacific Northwest of hte USA), with extensions to East Africa. We further explore the monitoring requirements for verification of any such impact, and see if the planned TAHMO African Observatory (TAHMO.org) has the potential to document any such processes over the 25-year and 1,000 km scales.

  12. Formation and evolution of Tar Balls from Northwestern US wildfires

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sedlacek III, Arthur J.; Buseck, Peter R.; Adachi, Kouji

    Biomass burning is a major source of light-absorbing black and brown carbonaceous particles. Brown carbon is a poorly characterized mixture that includes tar balls (TBs), a type of carbonaceous particle apparently unique to biomass burning. Here we describe the first atmospheric observations of the formation and evolution of TBs from forest fires. Aerosol particles were collected on TEM grids during aircraft transects at various downwind distances from the Colockum Tarp wildland fire. TB mass fractions, derived from TEM and in-situ measurements, increased from < 1 % near the fire to 31–45 % downwind, with little change in TB diameter. Single-scatteringmore » albedo determined from scattering and absorption measurements increased slightly with downwind distance. Similar TEM and SSA results were observed sampling multiple wildfires. Mie calculations are consistent with weak light absorbance by TBs (m = 1.56–0.02i) but not consistent with order-of-magnitude stronger absorption observed in different settings. The field-derived TB mass fractions reported here indicate that this particle type should be accounted for in biomass-burn emission inventories.« less

  13. Use of Remote Sensing and Dust Modelling to Evaluate Ecosystem Phenology and Pollen Dispersal

    NASA Technical Reports Server (NTRS)

    Luvall, Jeffrey C.; Sprigg, William A.; Watts, Carol; Shaw, Patrick

    2007-01-01

    The impact of pollen release and downwind concentrations can be evaluated utilizing remote sensing. Previous NASA studies have addressed airborne dust prediction systems PHAiRS (Public Health Applications in Remote Sensing) which have determined that pollen forecasts and simulations are possible. By adapting the deterministic dust model (as an in-line system with the National Weather Service operational forecast model) used in PHAiRS to simulate downwind dispersal of pollen, initializing the model with pollen source regions from MODIS, assessing the results a rapid prototype concept can be produced. We will present the results of our effort to develop a deterministic model for predicting and simulating pollen emission and downwind concentration to study details or phenology and meteorology and their dependencies, and the promise of a credible real time forecast system to support public health and agricultural science and service. Previous studies have been done with PHAiRS research, the use of NASA data, the dust model and the PHAiRS potential to improve public health and environmental services long into the future.

  14. Formation and evolution of Tar Balls from Northwestern US wildfires

    DOE PAGES

    Sedlacek III, Arthur J.; Buseck, Peter R.; Adachi, Kouji; ...

    2018-01-30

    Biomass burning is a major source of light-absorbing black and brown carbonaceous particles. Brown carbon is a poorly characterized mixture that includes tar balls (TBs), a type of carbonaceous particle apparently unique to biomass burning. Here we describe the first atmospheric observations of the formation and evolution of TBs from forest fires. Aerosol particles were collected on TEM grids during aircraft transects at various downwind distances from the Colockum Tarp wildland fire. TB mass fractions, derived from TEM and in-situ measurements, increased from < 1 % near the fire to 31–45 % downwind, with little change in TB diameter. Single-scatteringmore » albedo determined from scattering and absorption measurements increased slightly with downwind distance. Similar TEM and SSA results were observed sampling multiple wildfires. Mie calculations are consistent with weak light absorbance by TBs (m = 1.56–0.02i) but not consistent with order-of-magnitude stronger absorption observed in different settings. The field-derived TB mass fractions reported here indicate that this particle type should be accounted for in biomass-burn emission inventories.« less

  15. Multiple origins of linear dunes on Earth and Titan

    USGS Publications Warehouse

    Rubin, David M.; Hesp, Patrick A.

    2009-01-01

    Dunes with relatively long and parallel crests are classified as linear dunes. On Earth, they form in at least two environmental settings: where winds of bimodal direction blow across loose sand, and also where single-direction winds blow over sediment that is locally stabilized, be it through vegetation, sediment cohesion or topographic shelter from the winds. Linear dunes have also been identified on Titan, where they are thought to form in loose sand. Here we present evidence that in the Qaidam Basin, China, linear dunes are found downwind of transverse dunes owing to higher cohesiveness in the downwind sediments, which contain larger amounts of salt and mud. We also present a compilation of other settings where sediment stabilization has been reported to produce linear dunes. We suggest that in this dune-forming process, loose sediment accumulates on the dunes and is stabilized; the stable dune then functions as a topographic shelter, which induces the deposition of sediments downwind. We conclude that a model in which Titan's dunes formed similarly in cohesive sediments cannot be ruled out by the existing data.

  16. Comparison of aerosol volume size distributions between column and surface measurements downwind of Seoul, Korea

    NASA Astrophysics Data System (ADS)

    Park, J. S.; Choi, Y.; Ghim, Y. S.

    2015-12-01

    The aerosol volume size distribution is one of the most important parameters in retrieving aerosol optical properties and studying radiative forcing. The column-integrated aerosol volume size distribution for AERONET was obtained from inversion product level 1.5 (22 bins between 0.1 and 30 μm in diameter) from the measurements of CIMEL sunphotometer (CE-318); that for SKYNET was obtained using skyrad.pack V5 (20 bins, 0.02-33 μm) from the measurements of PREDE skyradiometer (POM-02). The aerosol volume size distribution at the surface was measured using a wide range aerosol spectrometer system consisting of a scanning mobility particle scanner (Grimm, Model 5.419; 89 bins, 0.005-0.35 μm) and an optical particle counter (Grimm, Model 1.109; 31 bins, 0.27-34 μm). The measurement was conducted in Yongin, downwind of Seoul, Korea, from April 30 to June 27, 2015. The measurement site is located on the rooftop of a five-story building on the hill (37.34°N, 127.27°E, 167 m above sea level) in the global campus of Hankuk University of Foreign Studies. To investigate the discrepancy in effective diameter and fine mode volume fraction, we compared the volume size distributions when the measurement time coincided within 5 minutes because the measurement intervals were different between instruments.

  17. Boundary Layer Temporal Evolution Observed by Doppler LiDAR Upwind of a Lake-Effect Snow Event

    NASA Astrophysics Data System (ADS)

    King, D.; Kristovich, D.

    2017-12-01

    Lake-effect snow (LES) annually affects the Great Lakes region. It can impact communities economically, recreationally and perhaps result in fatalities. Previous studies have shown that the upwind shore of a LES system tends to be a region for mesoscale downdrafts. This study intends to show how the depth of the boundary (BL) on the upwind shore and how it could influence a LES event downstream. From December 7-10, 2016, we deployed a Halo-Photonics Streamline pulsed Doppler LiDAR at Illinois Beach State Park in Zion, Illinois, to observe the evolving BL wind structure and depth upwind of the growing LES over eastern Lake Michigan. The LiDAR scans included vertical stare, velocity-azimuth display (VAD), and range height indicator (RHI) modes to display the BL depth as well as LES cloud band structure. The BL depth was observed by turbulent velocities and backscatter profiles from the LiDAR. The BL was found to be approximately one kilometer during the day, and reduced to near surface at night. The BL depth, overall, increased from the 8th to the 9th, while snowfall rate decreased on the downwind shore. This suggests that local BL dynamics have less influence on downwind convection and snow production than originally anticipated. The larger scale environment appears to play a larger role in the multi-day BL evolution.

  18. Atmospheric transport of mold spores in clouds of desert dust

    USGS Publications Warehouse

    Shinn, E.A.; Griffin, Dale W.; Seba, D.B.

    2003-01-01

    Fungal spores can be transported globally in clouds of desert dust. Many species of fungi (commonly known as molds) and bacteria--including some that are human pathogens--have characteristics suited to long-range atmospheric transport. Dust from the African desert can affect air quality in Africa, Europe, the Middle East, and the Americas. Asian desert dust can affect air quality in Asia, the Arctic, North America, and Europe. Atmospheric exposure to mold-carrying desert dust may affect human health directly through allergic induction of respiratory stress. In addition, mold spores within these dust clouds may seed downwind ecosystems in both outdoor and indoor environments.

  19. Prediction of engine exhaust concentrations downwind from the Delta-Thor Telsat-A launch of 9 November 1972

    NASA Technical Reports Server (NTRS)

    Kaufman, J. W.; Susko, M.; Hill, C. K.

    1973-01-01

    Results are presented of the downwind concentrations of engine exhaust by-products from the Delta-Thor Telsat-A vehicle launched from Cape Kennedy, Florida on November 9, 1972 (2014 EST). The meteorological conditions which existed are identified as well as the exhaust cloud rise and the results from the MSFC Multilayer Diffusion Model calculations. These predictions are compared to exhaust cloud sampled data acquired by the Langley Research Center personnel. Values of the surface level concentrations show that very little hydrochloric acid, carbon monoxide, or aluminum oxide reached the ground.

  20. The Effect of Wind-Turbine Wakes on Summertime US Midwest Atmospheric Wind Profiles as Observed with Ground-Based Doppler Lidar

    NASA Astrophysics Data System (ADS)

    Rhodes, Michael E.; Lundquist, Julie K.

    2013-07-01

    We examine the influence of a modern multi-megawatt wind turbine on wind and turbulence profiles three rotor diameters (D) downwind of the turbine. Light detection and ranging (lidar) wind-profile observations were collected during summer 2011 in an operating wind farm in central Iowa at 20-m vertical intervals from 40 to 220 m above the surface. After a calibration period during which two lidars were operated next to each other, one lidar was located approximately 2D directly south of a wind turbine; the other lidar was moved approximately 3D north of the same wind turbine. Data from the two lidars during southerly flow conditions enabled the simultaneous capture of inflow and wake conditions. The inflow wind and turbulence profiles exhibit strong variability with atmospheric stability: daytime profiles are well-mixed with little shear and strong turbulence, while nighttime profiles exhibit minimal turbulence and considerable shear across the rotor disk region and above. Consistent with the observations available from other studies and with wind-tunnel and large-eddy simulation studies, measurable reductions in wake wind-speeds occur at heights spanning the wind turbine rotor (43-117 m), and turbulent quantities increase in the wake. In generalizing these results as a function of inflow wind speed, we find the wind-speed deficit in the wake is largest at hub height or just above, and the maximum deficit occurs when wind speeds are below the rated speed for the turbine. Similarly, the maximum enhancement of turbulence kinetic energy and turbulence intensity occurs at hub height, although observations at the top of the rotor disk do not allow assessment of turbulence in that region. The wind shear below turbine hub height (quantified here with the power-law coefficient) is found to be a useful parameter to identify whether a downwind lidar observes turbine wake or free-flow conditions. These field observations provide data for validating turbine-wake models and wind-tunnel observations, and for guiding assessments of the impacts of wakes on surface turbulent fluxes or surface temperatures downwind of turbines.

  1. High levels of hair manganese in children living in the vicinity of a ferro-manganese alloy production plant.

    PubMed

    Menezes-Filho, José A; Paes, Ciro R; Pontes, Angela M de C; Moreira, Josino C; Sarcinelli, Paula N; Mergler, Donna

    2009-11-01

    Manganese (Mn) is an essential element, but an effective toxic at high concentrations. While there is an extensive literature on occupational exposure, few studies have examined adults and children living near important sources of airborne Mn. The objective of this study was to analyze hair Mn of children living in the vicinity of a ferro-manganese alloy production plant in the Great Salvador region, State of Bahia, Brazil and examine factors that influence this bioindicator of exposure. We examined 109 children in the age range of 1-10 years, living near the plant. Four separate housing areas were identified a priori on the bases of proximity to the emission sources and downwind location. A non-exposed group (n=43) of similar socio-economic status was also evaluated. Mn hair (MnH) concentration was measured by graphite atomic absorption spectrometry (GFAAS). Possible confounding hematological parameters were also assessed. Mean MnH concentration was 15.20 microg/g (1.10-95.50 microg/g) for the exposed children and 1.37 microg/g (0.39-5.58 microg/g) for the non-exposed. For the former, MnH concentrations were 7.95+/-1.40 microg/g (farthest from the plant), 11.81+/-1.11 microg/g (mid-region), 34.43+/-8.66 microg/g (closest to the plant) and 34.22+/-9.15 microg/g (directly downwind). Multiple regression analysis on log transformed MnH concentrations for the exposed children derived a model that explained 36.8% of the variability. In order of importance, area of children's residence, gender (girls>boys) and time of mother's residence in the area at the birth of the child, were significantly associated with MnH. Post hoc analyses indicated two groupings for exposure areas, with those living closest to and downwind of the plant displaying higher MnH concentrations compared to the others. The contribution of the time the mother lived in the community prior to the child's birth to the children's current MnH suggests that in utero exposure may play a role. A study of neurobehavioral performance with respect to Mn exposure in these children is currently underway.

  2. Automated source term and wind parameter estimation for atmospheric transport and dispersion applications

    NASA Astrophysics Data System (ADS)

    Bieringer, Paul E.; Rodriguez, Luna M.; Vandenberghe, Francois; Hurst, Jonathan G.; Bieberbach, George; Sykes, Ian; Hannan, John R.; Zaragoza, Jake; Fry, Richard N.

    2015-12-01

    Accurate simulations of the atmospheric transport and dispersion (AT&D) of hazardous airborne materials rely heavily on the source term parameters necessary to characterize the initial release and meteorological conditions that drive the downwind dispersion. In many cases the source parameters are not known and consequently based on rudimentary assumptions. This is particularly true of accidental releases and the intentional releases associated with terrorist incidents. When available, meteorological observations are often not representative of the conditions at the location of the release and the use of these non-representative meteorological conditions can result in significant errors in the hazard assessments downwind of the sensors, even when the other source parameters are accurately characterized. Here, we describe a computationally efficient methodology to characterize both the release source parameters and the low-level winds (eg. winds near the surface) required to produce a refined downwind hazard. This methodology, known as the Variational Iterative Refinement Source Term Estimation (STE) Algorithm (VIRSA), consists of a combination of modeling systems. These systems include a back-trajectory based source inversion method, a forward Gaussian puff dispersion model, a variational refinement algorithm that uses both a simple forward AT&D model that is a surrogate for the more complex Gaussian puff model and a formal adjoint of this surrogate model. The back-trajectory based method is used to calculate a ;first guess; source estimate based on the available observations of the airborne contaminant plume and atmospheric conditions. The variational refinement algorithm is then used to iteratively refine the first guess STE parameters and meteorological variables. The algorithm has been evaluated across a wide range of scenarios of varying complexity. It has been shown to improve the source parameters for location by several hundred percent (normalized by the distance from source to the closest sampler), and improve mass estimates by several orders of magnitude. Furthermore, it also has the ability to operate in scenarios with inconsistencies between the wind and airborne contaminant sensor observations and adjust the wind to provide a better match between the hazard prediction and the observations.

  3. Short-term risk of hospitalization for asthma or bronchiolitis in children living near an aluminum smelter

    PubMed Central

    Lewin, Antoine; Buteau, Stéphane; Brand, Allan; Kosatsky, Tom; Smargiassi, Audrey

    2013-01-01

    Few studies have measured the effect of short-term exposure to industrial emissions on the respiratory health of children. Here we estimate the risk of hospitalization for asthma and bronchiolitis in young children associated with their recent exposure to emissions from an aluminum smelter. We used a case–crossover design to assess the risk of hospitalization, February 1999–December 2008, in relation to short-term variation in levels of exposure among children 0–4 years old living less than 7.5 km from the smelter. The percentage of hours per day that the residence of a hospitalized child was in the shadow of winds crossing the smelter was used to estimate the effect of wind-borne emissions on case and crossover days. Community-wide pollutant exposure was estimated through daily mean and daily maximum SO2 and PM2.5 concentrations measured at a fixed monitoring site near the smelter. Odds ratios (OR) were estimated using conditional logistic regressions. The risk of same-day hospitalization for asthma or bronchiolitis increased with the percentage of hours in a day that a child's residence was downwind of the smelter. For children aged 2–4 years, the OR was 1.27 (95% CI=1.03–1.56; n=103 hospitalizations), for an interquartile range (IQR) of 21% of hours being downwind. In this age group, the OR with PM2.5 daily mean levels was slightly smaller than with the hours downwind (OR: 1.22 for an IQR of 15.7 μg/m3, 95% CI=1.03–1.44; n=94 hospitalizations). Trends were observed between hospitalizations and levels of SO2 for children 2–4 years old. Increasing short-term exposure to emissions from a Quebec aluminum smelter was associated with an increased risk of hospitalization for asthma and bronchiolitis in young children who live nearby. Estimating exposure through records of wind direction allows for the integration of exposure to all pollutants carried from the smelter stack. PMID:23695491

  4. Spatial and temporal characterization of traffic emissions in urban microenvironments with a mobile laboratory

    NASA Astrophysics Data System (ADS)

    Pirjola, L.; Lähde, T.; Niemi, J. V.; Kousa, A.; Rönkkö, T.; Karjalainen, P.; Keskinen, J.; Frey, A.; Hillamo, R.

    2012-12-01

    A measurement campaign by a mobile laboratory van was performed in urban microenvironments bounded by a busy street Mannerheimintie in the city center of Helsinki, Finland. The characteristics of spatiotemporally high-resolution pollutant concentrations were studied such as ultrafine particles in the size range of 3-414 nm, black carbon BC, fine particle mass PM2.5, as well as nitrogen oxides NO and NO2. In addition, the effects of street geometry and roadside structure on the local dispersion of traffic emissions were analyzed as well. Meteorological conditions stayed stable and the wind direction was perpendicular to Mannerheimintie during the campaign. The highest particle concentrations were ˜8 × 105 cm-3, of which around 94% was smaller than 40 nm. At the pavement, the average concentration was in maximum 5 × 104 cm-3; around 80% of the particles was smaller than 40 nm. The volatility fraction was 75% by number. Due to the street canyon effect by the surrounding buildings, the downwind concentrations were around 24% of the upwind concentrations for particle number, 28% of NO, 39% of BC and 70% of NO2 concentrations. Furthermore, the upwind concentrations were higher than the simultaneously measured concentrations within the traffic flow. In fact, the particle count was around 3-fold, BC 2.5-fold, PM2.5 and NO2 1.5-fold compared to the concentrations while driving. Thus, for this measurement site and under these meteorological conditions, the exposure to pedestrians and cyclist on the upwind pavement is even higher than the driver's exposure. If the downwind buildings were parallel to Mannerheimintie, the concentrations dropped significantly at the pavement and continued decreasing slightly in the courtyards. When the downwind buildings were perpendicular to Mannerheimintie, a gradual reduction in the concentrations between the buildings was observed. However, at a distance of approximately a hundred meters a parallel side street which was a street canyon, started to affect the concentrations resulting in an increased exposure risk for pedestrians and cyclists. Understanding the local transport and the dispersion of traffic emissions are important for city planning and air quality assessment.

  5. The abundance and diversity of antibiotic resistance genes in the atmospheric environment of composting plants.

    PubMed

    Gao, Min; Qiu, Tianlei; Sun, Yanmei; Wang, Xuming

    2018-07-01

    Composting is considered to reduce the introduction of antimicrobial resistance genes (ARGs) into the environment through land application of manure; however, the possible pollution of ARGs in the atmospheric environment of composting plants is unknown. In this study, 29 air samples including up- and downwind, composting, packaging, and office areas from 4 composting plants were collected. Dynamic concentrations of 22 subtypes of ARGs, class 1 integron (intl1), and 2 potential human pathogenic bacteria (HPB), and bacterial communities were investigated using droplet digital PCR and 16S rRNA gene sequencing, respectively. In this study, intl1 and 22 subtypes of ARGs (except tetQ) were detected in air of composting, packaging, office, and downwind areas. The highest concentration of 15 out of 22 subtypes of ARGs was detected in the packaging areas, and intl1 also had the maximum average concentration of 10 4  copies/m 3 , with up to (1.78 ± 0.49) × 10 -2 copies/16S rRNA copy. Non-metric multi-dimensional scaling of ARGs, potential HPBs, and bacterial components all indicated that the bioaerosol pollutant pattern in packaging areas was most similar to that in composting areas, followed by office, downwind, and upwind areas. The co-occurrence between ARGs and bacterial taxa assessed by Procrustes test, mantel test, and network analysis implied that aerosolized ARG fragments from composting and packaging areas contributed to the compositions of ARG aerosols in office and downwind areas. The results presented here show that atmoshperic environments of composting plants harbor abundant and diverse ARGs, which highlight the urgent need for comprehensive evaluation of potential human health and ecological risks of composts during both production as well as land application. Copyright © 2018 Elsevier Ltd. All rights reserved.

  6. Low-frequency coherent motions within the spruce canopy on the upwind vs. downwind side of a forested ridge

    NASA Astrophysics Data System (ADS)

    Potužníková, K.; Sedlák, P.; Šauli, P.

    2009-09-01

    Airflow and turbulence within and above the forest canopy determine the forest - atmosphere exchange of atmospheric constituents and pollutants. Our investigation is related to the existence of large-scale intermittent coherent structures, which have been detected in turbulence time series measured at the Experimental Ecological Study Site Bílý Kříž (800-900 m a.s.l.) in the Czech Republic. The site is situated on a steep (13°) SSW-faced slope near the top of a mountain ridge forested by a young Norway spruce plantation. Flow directions across the ridge (along the slope) strongly prevail at the site. Results based on a recent study reveal significant differences between the cases when the site is on the upwind vs. downwind side of the ridge. Typical downwind cases are characterized by a low wind speed above the canopy and by relatively higher friction velocity than in the upwind cases. This is explained by the flow retardation by the upslope-directed hydrodynamic pressure gradient and by the large wind shear in the upper part of the wake behind the ridge top. This contribution concentrates on the vertical coherency of the turbulent flow within the forest canopy. Analysed variables include the high-frequency wind velocity components and sonic temperature measured during periods of neutral thermal stratification at two different levels. Wavelet analysis was used for detection of characteristic temporal scale of coherent structures, their persistence and effectivity parameter. Special attention is paid to the differences between the upwind and downwind cases. Acknowledgements: The study is supported by the grant IAA300420803 and IAA300420704 from Grant Agency of Academy of Sciences of the Czech Republic.

  7. A numerical study on the evolution of the wind-driven circulation in the Yellow Sea in winter

    NASA Astrophysics Data System (ADS)

    Tak, Y. J.; Cho, Y. K.

    2016-02-01

    The Yellow Sea is a semi-enclosed marginal sea and its circulation in winter is affected by the winter monsoon. In previous studies, it was found that the circulation of the Yellow Sea in winter consists of downwind and upwind currents. Downwind currents consisting of the Korean Coast Current (KCC) and the Chinese Coast Current (CCC) flow along the boundary of the Yellow Sea, whereas an upwind current consisting of the Yellow Sea Warm Current (YSWC) flows along the central trough of the Yellow Sea. Although some characteristics of such currents and the driving forces of the circulation have been studied by many scientists, the evolution of these currents has received little attention. So, the wind-driven circulation in the Yellow Sea was simulated to explain the changing pattern of these currents in winter and their evolutions were explored by the time-lagged correlation for winter season. According to the lagged correlation, downwind currents occurred in surface layer without a time lag. These downwind currents were more sensitive in the Chinese coast than that in the Korean coast. There is one day time-lag between the wind and the upwind flow developing in the Yellow Sea trough. The YSWC was shifted to the west of the trough after two days and then the KCC strengthened at the same time. It implied the westward shift of the YSWC and the clockwise circulation is developed, two days after the wind blows. The clockwise circulation was one of the reasons that the KCC was stronger than the CCC although the CCC was more sensitive to the wind than the KCC. The clockwise circulation also made the YSWC stronger in the inner YS than it at the entrance of the YS.

  8. Analysis of gaseous SO2, CO2 and halogen species in volcanic plumes using a multirotor Unmanned Aerial Vehicle (UAV).

    NASA Astrophysics Data System (ADS)

    Rüdiger, J.; de Moor, M. J.; Tirpitz, L.; Bobrowski, N.; Gutmann, A.; Hoffmann, T.

    2016-12-01

    Volcanoes are a large source for several reactive atmospheric trace gases including sulfur and halogen containing species. The detailed understanding of volcanic plume chemistry is needed to draw information from gas measurements on subsurface processes. This knowledge is essential for using gas measurements as a monitoring tool for volcanic activity. The reactive bromine species bromine monoxide (BrO) is of particular interest, because BrO as well as SO2 are readily measurable from safe distance by spectroscopic remote sensing techniques. BrO is not directly emitted, but is formed in the plume by a multiphase reaction mechanism. The abundance of BrO changes as a function of the distance from the vent as well as the spatial position in the plume. The precursor substance for the formation of BrO is HBr with Br2 as an intermediate product. In this study we present the application of a UAV as a carrier for a remote-controlled sampling system for halogen species (Br2, HBr, BrCl, etc), based on the gas diffusion denuder technique, which allows speciation and enrichment by selective organic reactions. For the analysis of gaseous SO2 and CO2 an in-situ gas monitoring system was additionally mounted. This setup was deployed into the gas plumes of Stromboli Volcano (Italy) and Masaya Volcano (Nicaragua) in 2016, to investigate the halogen chemistry at distant locations in the plume further downwind to the emission source, which are in most cases not accessible by other approaches. The used quadrocopter (0.75 m in diameter) weighs 2.45 kg and lifts a payload of 1.3 kg. Flights into the plume were conducted with ascents of up to 900 m, starting at 500 to 800 m altitude. From telemetrically transmitted SO2 mixing ratios, areas of dense plume were localized to keep the UAV stationary for up to 10 minutes of sampling time. Herein we will present time and spatial resolved gas mixing ratio data for SO2, CO2 and halogen species for a downwind plume age of about 3 to 5 minutes.

  9. Intermediate visual acuity of presbyopic individuals with and without distance and bifocal lens corrections.

    DOT National Transportation Integrated Search

    1977-03-01

    Visual acuity was determined at the intermediate range for older individuals with various combinations of ocular refractive error (nine subcategories) and accommodative power (three subcategories). Subjects (N=249) read numerals ranging in size to me...

  10. Observations of the microclimate of a lake under cold air advective conditions

    NASA Technical Reports Server (NTRS)

    Bill, R. G., Jr.; Sutherland, R. A.; Bartholic, J. F.

    1977-01-01

    The moderating effects of Lake Apopka, Florida, on downwind surface temperatures were evaluated under cold air advective conditions. Point temperature measurements north and south of the lake and data obtained from the NOAA satellite and a thermal scanner flown at 1.6 km, indicate that, under conditions of moderate winds (approximately 4m/sec), surface temperatures directly downwind may be higher than surrounding surface temperatures by as much as 5 C. With surface wind speed less than 1m/sec, no substantial temperature effects were observed. Results of this study are being used in land use planning, lake level control and in agriculture for selecting planting sites.

  11. Synergistic Effects of Turbine Wakes and Atmospheric Stability on Power Production at an Onshore Wind Farm

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wharton, S; Lundquist, J K; Marjanovic, N

    This report examines the complex interactions between atmospheric stability and turbine-induced wakes on downwind turbine wind speed and power production at a West Coast North American multi-MW wind farm. Wakes are generated when the upwind flow field is distorted by the mechanical movement of the wind turbine blades. This has two consequences for downwind turbines: (1) the downwind turbine encounters wind flows with reduced velocity and (2) the downwind turbine encounters increased turbulence across multiple length scales via mechanical turbulence production by the upwind turbine. This increase in turbulence on top of ambient levels may increase aerodynamic fatigue loads onmore » the blades and reduce the lifetime of turbine component parts. Furthermore, ambient atmospheric conditions, including atmospheric stability, i.e., thermal stratification in the lower boundary layer, play an important role in wake dissipation. Higher levels of ambient turbulence (i.e., a convective or unstable boundary layer) lead to higher turbulent mixing in the wake and a faster recovery in the velocity flow field downwind of a turbine. Lower levels of ambient turbulence, as in a stable boundary layer, will lead to more persistent wakes. The wake of a wind turbine can be divided into two regions: the near wake and far wake, as illustrated in Figure 1. The near wake is formed when the turbine structure alters the shape of the flow field and usually persists one rotor diameter (D) downstream. The difference between the air inside and outside of the near wake results in a shear layer. This shear layer thickens as it moves downstream and forms turbulent eddies of multiple length scales. As the wake travels downstream, it expands depending on the level of ambient turbulence and meanders (i.e., travels in non-uniform path). Schepers estimates that the wake is fully expanded at a distance of 2.25 D and the far wake region begins at 2-5 D downstream. The actual distance traveled before the wake recovers to its inflow velocity is dependent on the amount ambient turbulence, the amount of wind shear, and topographical and structural effects. The maximum velocity deficit is estimated to occur at 1-2 D but can be longer under low levels of ambient turbulence. Our understanding of turbine wakes comes from wind tunnel experiments, field experiments, numerical simulations, and from studies utilizing both experimental and modeling methods. It is well documented that downwind turbines in multi-Megawatt wind farms often produce less power than upwind turbine rows. These wake-induced power losses have been estimated from 5% to up to 40% depending on the turbine operating settings (e.g., thrust coefficient), number of turbine rows, turbine size (e.g., rotor diameter and hub-height), wind farm terrain, and atmospheric flow conditions (e.g., ambient wind speed, turbulence, and atmospheric stability). Early work by Elliott and Cadogan suggested that power data for different turbulent conditions be segregated to distinguish the effects of turbulence on wind farm power production. This may be especially important for downwind turbines within wind farms, as chaotic and turbulent wake flows increase stress on downstream turbines. Impacts of stability on turbine wakes and power production have been examined for a flat terrain, moderate size (43 turbines) wind farm in Minnesota and for an offshore, 80 turbine wind farm off the coast of Denmark. Conzemius found it difficult to distinguish wakes (i.e., downwind velocity deficits) when the atmosphere was convective as large amounts of scatter were present in the turbine nacelle wind speed data. This suggested that high levels of turbulence broke-up the wake via large buoyancy effects, which are generally on the order of 1 km in size. On the other hand, they found pronounced wake effects when the atmosphere was very stable and turbulence was either suppressed or the length scale was reduced as turbulence in this case was mechanically produced (i.e., friction forces). This led to larger reductions at downwind turbines and maximum velocity (power) deficits reached up to 50% (70%) during strongly stable conditions. At an offshore Danish wind farm, Hansen et al. found a strong negative correlation between power deficit and ambient turbulence intensity (i.e., atmospheric stability). Under convective conditions, when turbulence levels were relatively high, smallest power deficits were observed. Power deficits approaching 35 to 40% were found inside the wind farm during stable conditions.« less

  12. Hydrogeology of the surficial and intermediate aquifer systems in Sarasota and adjacent counties, Florida

    USGS Publications Warehouse

    Barr, G.L.

    1996-01-01

    From 1991 to 1995, the hydrogeology of the surficial aquifer system and the major permeable zones and confining units of the intermediate aquifer system in southwest Florida was studied. The study area is a 1,400-square-mile area that includes Sarasota County and parts of Manatee, De Soto, Charlotte, and Lee Counties. Lithologic, geophysical, hydraulic property, and water-level data were used to correlate the hydrogeology and map the extent of the aquifer systems. Water chemistry was evaluated in southwest Sarasota County to determine salinity of the surficial and intermediate aquifer systems. The surficial aquifer is an unconfined aquifer system that overlies the intermediate aquifer system and ranges from a few feet to over 60 feet in thickness in the study area. Hydraulic properties of the surficial aquifer system determined from aquifer and laboratory tests, and model simulations vary considerably across the study area. The intermediate aquifer system, a confined aquifer system that lies between the surficial and the Upper Floridan aquifers, is composed of alternating confining units and permeable zones. The intermediate aquifer system has three major permeable zones that exhibit a wide range of hydraulic properties. Horizontal flow in the intermediate aquifer system is northeast to southwest. Most of the study area is in a discharge area of the intermediate aquifer system. Water ranges naturally from fresh in the surficial aquifer system and upper permeable zones of the intermediate aquifer system to moderately saline in the lower permeable zone. Water-quality data collected in coastal southwest Sarasota County indicate that ground-water withdrawals from major pumping centers have resulted in lateral seawater intrusion and upconing into the surficial and intermediate aquifer systems.

  13. Projecting non-diffracting waves with intermediate-plane holography.

    PubMed

    Mondal, Argha; Yevick, Aaron; Blackburn, Lauren C; Kanellakopoulos, Nikitas; Grier, David G

    2018-02-19

    We introduce intermediate-plane holography, which substantially improves the ability of holographic trapping systems to project propagation-invariant modes of light using phase-only diffractive optical elements. Translating the mode-forming hologram to an intermediate plane in the optical train can reduce the need to encode amplitude variations in the field, and therefore complements well-established techniques for encoding complex-valued transfer functions into phase-only holograms. Compared to standard holographic trapping implementations, intermediate-plane holograms greatly improve diffraction efficiency and mode purity of propagation-invariant modes, and so increase their useful non-diffracting range. We demonstrate this technique through experimental realizations of accelerating modes and long-range tractor beams.

  14. Atmospheric characterization through fused mobile airborne and surface in situ surveys: methane emissions quantification from a producing oil field

    NASA Astrophysics Data System (ADS)

    Leifer, Ira; Melton, Christopher; Fischer, Marc L.; Fladeland, Matthew; Frash, Jason; Gore, Warren; Iraci, Laura T.; Marrero, Josette E.; Ryoo, Ju-Mee; Tanaka, Tomoaki; Yates, Emma L.

    2018-03-01

    Methane (CH4) inventory uncertainties are large, requiring robust emission derivation approaches. We report on a fused airborne-surface data collection approach to derive emissions from an active oil field near Bakersfield, central California. The approach characterizes the atmosphere from the surface to above the planetary boundary layer (PBL) and combines downwind trace gas concentration anomaly (plume) above background with normal winds to derive flux. This approach does not require a well-mixed PBL; allows explicit, data-based, uncertainty evaluation; and was applied to complex topography and wind flows. In situ airborne (collected by AJAX - the Alpha Jet Atmospheric eXperiment) and mobile surface (collected by AMOG - the AutoMObile trace Gas - Surveyor) data were collected on 19 August 2015 to assess source strength. Data included an AMOG and AJAX intercomparison transect profiling from the San Joaquin Valley (SJV) floor into the Sierra Nevada (0.1-2.2 km altitude), validating a novel surface approach for atmospheric profiling by leveraging topography. The profile intercomparison found good agreement in multiple parameters for the overlapping altitude range from 500 to 1500 m for the upper 5 % of surface winds, which accounts for wind-impeding structures, i.e., terrain, trees, buildings, etc. Annualized emissions from the active oil fields were 31.3 ± 16 Gg methane and 2.4 ± 1.2 Tg carbon dioxide. Data showed the PBL was not well mixed at distances of 10-20 km downwind, highlighting the importance of the experimental design.

  15. Understanding Anthropogenic Impacts on Air Quality at Rural Locations Using High Time Resolution Particle Composition Measurements

    NASA Astrophysics Data System (ADS)

    Collett, J. L.; Lee, T.; Yu, X.; Sullivan, A.; Kreidenweis, S. M.; Malm, W.

    2006-12-01

    Many of our nation's National Parks, wilderness areas and other visually protected environments are located in regions where urban, agricultural, and other anthropogenic emissions periodically exert strong impacts on local air quality. In this presentation we will use high time resolution (15 min) measurements of particle composition to examine the frequency and magnitude of these impacts and to elucidate changes in aerosol chemistry occurring during transitions between periods of strong anthropogenic impact and periods when atmospheric composition is more strongly influenced by natural emissions and/or regional air quality. Highlights will be drawn from a series of field campaigns at locations around the U.S., including Yosemite National Park (downwind of the Central Valley of California), San Gorgonio Wilderness Area (downwind of the Los Angeles basin), Bondville, Illinois (a rural Midwestern site), Great Smoky Mountains National Park (a rural, mountain location in the polluted southeast U.S.), Brigantine National Wildlife Refuge, New Jersey (a coastal site on the U.S. eastern seaboard), and Rocky Mountain National Park, Colorado (located in the mountains west of the Colorado Front Range urban corridor). Particle composition measurements were made using a Particle Into Liquid Sampler (PILS) coupled to two on-line ion chromatographs. We will demonstrate how air quality at these locations is strongly influenced by local and regional transport phenomena and illustrate the influence of anthropogenic emissions on both fine and coarse particle concentrations and speciation.

  16. Impact Assessment of Biomass Burning on Air Quality in Southeast and East Asia During BASE-ASIA

    NASA Technical Reports Server (NTRS)

    Huang, Kan; Fu, Joshua S.; Hsu, N. Christina; Gao, Yang; Dong, Xinyi; Tsay, Si-Chee; Lam, Yun Fat

    2013-01-01

    A synergy of numerical simulation, ground-based measurement and satellite observation was applied to evaluate the impact of biomass burning originating from Southeast Asia (SE Asia) within the framework of NASA's 2006 Biomass burning Aerosols in Southeast Asia: Smoke Impact Assessment (BASE-ASIA). Biomass burning emissions in the spring of 2006 peaked in MarcheApril when most intense biomass burning occurred in Myanmar, northern Thailand, Laos, and parts of Vietnam and Cambodia. Model performances were reasonably validated by comparing to both satellite and ground-based observations despite overestimation or underestimation occurring in specific regions due to high uncertainties of biomass burning emission. Chemical tracers of particulate K(+), OC concentrations, and OC/EC ratios showed distinct regional characteristics, suggesting biomass burning and local emission dominated the aerosol chemistry. CMAQ modeled aerosol chemical components were underestimated at most circumstances and the converted AOD values from CMAQ were biased low at about a factor of 2, probably due to the underestimation of biomass emissions. Scenario simulation indicated that the impact of biomass burning to the downwind regions spread over a large area via the Asian spring monsoon, which included Southern China, South China Sea, and Taiwan Strait. Comparison of AERONET aerosol optical properties with simulation at multi-sites clearly demonstrated the biomass burning impact via longrange transport. In the source region, the contribution from biomass burning to AOD was estimated to be over 56%. While in the downwind regions, the contribution was still significant within the range of 26%-62%.

  17. Monthly and diurnal variations in aerosol size distributions, downwind of the Seoul metropolitan area

    NASA Astrophysics Data System (ADS)

    Kim, B. S.; Choi, Y.; Ghim, Y. S.

    2014-12-01

    The size distribution of aerosols is a physical property. However, since major aerosol types such as mineral dust, secondary inorganic ions, and carbonaceous aerosols are typically in specific size ranges, we can estimate the chemical composition of aerosols from the size distribution. We measured the mass size distribution of aerosols using an optical particle counter (Grimm Model 1.109) for a year from February 2013 to February 2014 at intervals of 10 minutes. The optical particle counter measures number concentrations between 0.25 and 32 μm in 31 bins and converts them into mass concentrations assuming a sphere and densities of aerosols in urban environment which originate from traffic and other combustion sources and are secondarily formed from photochemical reactions. The measurement site is at the rooftop of the five-story building on the hill (37.34 °N, 127.27 °E, 167 m above sea level), about 35 km southeast of downtown Seoul, the downwind area of which is affected by prevailing northwesterlies. There are no major emission sources nearby except a 4-lane road running about 1.4 km to the west. We tried to characterize the bimodal property of the mass size distribution, consisting of fine and coarse modes, in terms of mass concentration and mean diameter. Monthly and diurnal variations in mass concentration and mean diameter of each mode were investigated to estimate major aerosol types as well as major factors causing those variations.

  18. Dependence of the Normalized Radar Cross Section of Water Waves on Bragg Wavelength-Wind Speed Sensitivity

    NASA Technical Reports Server (NTRS)

    Long, David G.; Collyer, R. Scott; Reed, Ryan; Arnold, David V.

    1996-01-01

    Measurements of the normalized radar cross section (sigma(sup o)) made by the YSCAT ultrawideband scatterometer during an extended deployment on the Canada Centre for Inland Waters(CCIW) Research Tower located at Lake Ontario are analyzed and compared with anemometer wind measurements to study the sensitivity of (sigma(sup o)) to the wind speed as a function of the Bragg wavelength. This paper concentrates on upwind and downwind azimuth angles in the wind speed range of 4.5-12 m/s. While YSCAT collected measurements of sigma(sup o) at a variety of frequencies and incidence angles, this paper focuses on frequencies of 2.0, 3.05, 5.30, 10.02, and 14.0 GHz and incidence angles within the Bragg regime, 30-50 deg. Adopting a power law model to describe the relationship between sigma(sup o) and wind speed, both wind speed exponents and upwind/downwind (u/d) ratios of sigma(sup o) are found using least squares linear regression. The analysis of the wind speed exponents and u/d ratios show that shorter Bragg wavelengths (Lambda less than 4 cm) are the most sensitive to wind speed and direction. Additionally, vertical polarization (V-pol) sigma(sup o) is shown to be more sensitive to wind speed than horizontal polarization (H-pol) sigma(sup o), while the H-pol u/d ratio is larger than the V-pol u/d ratio.

  19. Navigation errors encountered using weather-mapping radar for helicopter IFR guidance to oil rigs

    NASA Technical Reports Server (NTRS)

    Phillips, J. D.; Bull, J. S.; Hegarty, D. M.; Dugan, D. C.

    1980-01-01

    In 1978 a joint NASA-FAA helicopter flight test was conducted to examine the use of weather-mapping radar for IFR guidance during landing approaches to oil rig helipads. The following navigation errors were measured: total system error, radar-range error, radar-bearing error, and flight technical error. Three problem areas were identified: (1) operational problems leading to pilot blunders, (2) poor navigation to the downwind final approach point, and (3) pure homing on final approach. Analysis of these problem areas suggests improvement in the radar equipment, approach procedure, and pilot training, and gives valuable insight into the development of future navigation aids to serve the off-shore oil industry.

  20. High Resolution Image From Viking Lander 1

    NASA Image and Video Library

    1996-12-12

    NASA's Viking 1 took this high-resolution picture today, its third day on Mars. Distance from the camera to the nearfield (bottom) is about 4 meters (13 feet); to the horizon, about 3 kilometers (1.8 miles). The photo shows numerous angular blocks ranging in size from a few centimeters to several meters. The surface between the blocks is composed of fine-grained material. Accumulation of some fine-grained material behind blocks indicates wind deposition of dust and sand downwind of obstacles. The large block on the horizon is about 4 meters (13 feet) wide. Distance across the horizon is about 34 meters (110 feet). http://photojournal.jpl.nasa.gov/catalog/PIA00385

  1. Evaluation of the feasibility of scale modeling to quantify wind and terrain effects on low-angle sound propagation

    NASA Technical Reports Server (NTRS)

    Anderson, G. S.; Hayden, R. E.; Thompson, A. R.; Madden, R.

    1985-01-01

    The feasibility of acoustical scale modeling techniques for modeling wind effects on long range, low frequency outdoor sound propagation was evaluated. Upwind and downwind propagation was studied in 1/100 scale for flat ground and simple hills with both rigid and finite ground impedance over a full scale frequency range from 20 to 500 Hz. Results are presented as 1/3-octave frequency spectra of differences in propagation loss between the case studied and a free-field condition. Selected sets of these results were compared with validated analytical models for propagation loss, when such models were available. When they were not, results were compared with predictions from approximate models developed. Comparisons were encouraging in many cases considering the approximations involved in both the physical modeling and analysis methods. Of particular importance was the favorable comparison between theory and experiment for propagation over soft ground.

  2. Contribution of regional-scale fire events to ozone and PM2.5 air quality estimated by photochemical modeling approaches

    NASA Astrophysics Data System (ADS)

    Baker, K. R.; Woody, M. C.; Tonnesen, G. S.; Hutzell, W.; Pye, H. O. T.; Beaver, M. R.; Pouliot, G.; Pierce, T.

    2016-09-01

    Two specific fires from 2011 are tracked for local to regional scale contribution to ozone (O3) and fine particulate matter (PM2.5) using a freely available regulatory modeling system that includes the BlueSky wildland fire emissions tool, Spare Matrix Operator Kernel Emissions (SMOKE) model, Weather and Research Forecasting (WRF) meteorological model, and Community Multiscale Air Quality (CMAQ) photochemical grid model. The modeling system was applied to track the contribution from a wildfire (Wallow) and prescribed fire (Flint Hills) using both source sensitivity and source apportionment approaches. The model estimated fire contribution to primary and secondary pollutants are comparable using source sensitivity (brute-force zero out) and source apportionment (Integrated Source Apportionment Method) approaches. Model estimated O3 enhancement relative to CO is similar to values reported in literature indicating the modeling system captures the range of O3 inhibition possible near fires and O3 production both near the fire and downwind. O3 and peroxyacetyl nitrate (PAN) are formed in the fire plume and transported downwind along with highly reactive VOC species such as formaldehyde and acetaldehyde that are both emitted by the fire and rapidly produced in the fire plume by VOC oxidation reactions. PAN and aldehydes contribute to continued downwind O3 production. The transport and thermal decomposition of PAN to nitrogen oxides (NOX) enables O3 production in areas limited by NOX availability and the photolysis of aldehydes to produce free radicals (HOX) causes increased O3 production in NOX rich areas. The modeling system tends to overestimate hourly surface O3 at routine rural monitors in close proximity to the fires when the model predicts elevated fire impacts on O3 and Hazard Mapping System (HMS) data indicates possible fire impact. A sensitivity simulation in which solar radiation and photolysis rates were more aggressively attenuated by aerosol in the plume reduced model O3 but does not eliminate this bias. A comparison of model predicted daily average speciated PM2.5 at surface rural routine network sites when the model predicts fire impacts from either of these fires shows a tendency toward overestimation of PM2.5 organic aerosol in close proximity to these fires. The standard version of the CMAQ treats primarily emitted organic aerosol as non-volatile. An alternative approach for treating organic aerosol as semi-volatile resulted in lower PM2.5 organic aerosol from these fires but does not eliminate the bias. Future work should focus on modeling specific fire events that are well characterized in terms of size, emissions, and have extensive measurements taken near the fire and downwind to better constrain model representation of important physical and chemical processes (e.g. aerosol photolysis attenuation and organic aerosol treatment) related to wild and prescribed fires.

  3. Ammonia emissions, transport, and deposition downwind of agricultural areas at local to regional scales

    NASA Astrophysics Data System (ADS)

    Zondlo, Mark; Pan, Da; Golston, Levi; Sun, Kang; Tao, Lei

    2016-04-01

    Ammonia (NH3) emissions from agricultural areas show extreme spatiotemporal variations, yet agricultural emissions dominate the global NH3 budget and ammoniated aerosols are a dominant component of unhealthy fine particulate matter. The emissions of NH3 and their deposition near and downwind of agricultural areas is complex. As part of a multi-year field intensive along the Colorado Front Range (including the NASA DISCOVER-AQ and NSF FRAPPE field experiments), we have examined temporal emissions of NH3 from feedlots, regional transport of ammonia and ammoniated aerosols from the plains to relatively pristine regions in Rocky Mountain National Park, and dry deposition and re-emission of grassland NH3 in the park. Eddy covariance measurements at feedlots and natural grasslands in the mountains were conducted with newly-developed open-path, eddy covariance laser-based sensors for NH3 (0.7 ng NH3/m2/s detection limit at 10 Hz). These measurements were coupled with other NH3/NHx measurements from mobile laboratories, aircraft, and satellite to examine the transport of NH3 from agricultural areas to cleaner regions downwind. At the farm level, eddy covariance NH3 fluxes showed a strong diurnal component correlated with temperature regardless of the season but with higher absolute emissions in summer than winter. While farm-to-farm variability (N=62 feedlots) was high, similar diurnal trends were observed at all sites regardless of individual farm type (dairy, beef, sheep, poultry, pig). Deposition at scales of several km showed relatively small deposition (10% loss) based upon NH3/CH4 tracer correlations, though the NH3 concentrations were so elevated (up to ppmv) that these losses should not be neglected when considering near-farm deposition. Ammonia was efficiently transported at least 150 km during upslope events to the Colorado Front Range (ele. 3000-4000 m) based upon aircraft, mobile laboratory, and model measurements. The gas phase lifetime of NH3 was estimated to be at least 12 hours. Eddy covariance measurements in the mountains showed deposition of 3.2 ng N/m2/s during upslope events from the agricultural areas. In contrast, during downslope events when clean, free tropospheric air was at the site, re-emission of NH3 to the atmosphere of a similar magnitude was observed. The strong correlations with wind direction, coupled to back trajectories and measurements, suggest that agricultural NH3 emissions are playing an important role in nitrogen deposition at Rocky Mountain National Park. These results will be compared to similar measurements by our group in the San Joaquin Valley in California and via TES/IASI satellite measurements elsewhere in the US.

  4. Wind flow characteristics in the wakes of large wind turbines. Volume 1: Analytical model development

    NASA Technical Reports Server (NTRS)

    Eberle, W. R.

    1981-01-01

    A computer program to calculate the wake downwind of a wind turbine was developed. Turbine wake characteristics are useful for determining optimum arrays for wind turbine farms. The analytical model is based on the characteristics of a turbulent coflowing jet with modification for the effects of atmospheric turbulence. The program calculates overall wake characteristics, wind profiles, and power recovery for a wind turbine directly in the wake of another turbine, as functions of distance downwind of the turbine. The calculation procedure is described in detail, and sample results are presented to illustrate the general behavior of the wake and the effects of principal input parameters.

  5. Winds and the distribution of nearshore phytoplankton in a stratified lake.

    PubMed

    Cyr, Hélène

    2017-10-01

    The distribution of phytoplankton in lakes is notoriously patchy and dynamic, but wind-driven currents and algal buoyancy/motility are thought to determine where algae accumulate. In this study, nearshore phytoplankton were sampled from different parts of a lake basin twice a day for 4-5 consecutive days, in the spring and in late summer, to test whether short-term changes in phytoplankton biomass and community composition can be predicted from wind-driven currents. On windy days, phytoplankton biomass was higher at downwind than at upwind nearshore sites, and the magnitude of this difference increased linearly with increasing wind speed. However, contrary to the generally assumed downwind phytoplankton aggregations, these differences were mostly due to upwelling activity and the dilution of phytoplankton at upwind nearshore sites. The distribution of individual taxa was also related to wind speed, but only during late stratification (except for cryptophytes), and these relationships were consistent with the buoyancy and motility of each group. On windy days, large diatoms and cyanobacteria concentrated upwind, neutrally buoyant taxa (green algae, small diatoms) were homogeneously distributed, and motile taxa (cryptophytes, chrysophytes, dinoflagellates) concentrated downwind. Predictable differences in the biomass and composition of phytoplankton communities could affect the efficiency of trophic transfers in nearshore areas. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. Evaluation of the wind farm parameterization in the Weather Research and Forecasting model (version 3.8.1) with meteorological and turbine power data

    NASA Astrophysics Data System (ADS)

    Lee, Joseph C. Y.; Lundquist, Julie K.

    2017-11-01

    Forecasts of wind-power production are necessary to facilitate the integration of wind energy into power grids, and these forecasts should incorporate the impact of wind-turbine wakes. This paper focuses on a case study of four diurnal cycles with significant power production, and assesses the skill of the wind farm parameterization (WFP) distributed with the Weather Research and Forecasting (WRF) model version 3.8.1, as well as its sensitivity to model configuration. After validating the simulated ambient flow with observations, we quantify the value of the WFP as it accounts for wake impacts on power production of downwind turbines. We also illustrate with statistical significance that a vertical grid with approximately 12 m vertical resolution is necessary for reproducing the observed power production. Further, the WFP overestimates wake effects and hence underestimates downwind power production during high wind speed, highly stable, and low turbulence conditions. We also find the WFP performance is independent of the number of wind turbines per model grid cell and the upwind-downwind position of turbines. Rather, the ability of the WFP to predict power production is most dependent on the skill of the WRF model in simulating the ambient wind speed.

  7. Trace-metal concentrations in African dust: effects of long-distance transport and implications for human health

    USGS Publications Warehouse

    Garrison, Virginia; Lamothe, Paul; Morman, Suzette; Plumlee, Geoffrey S.; Gilkes, Robert; Prakongkep, Nattaporn

    2010-01-01

    The Sahara and Sahel lose billions of tons of eroded mineral soils annually to the Americas and Caribbean, Europe and Asia via atmospheric transport. African dust was collected from a dust source region (Mali, West Africa) and from downwind sites in the Caribbean [Trinidad-Tobago (TT) and U.S. Virgin Islands (VI)] and analysed for 32 trace-elements. Elemental composition of African dust samples was similar to that of average upper continental crust (UCC), with some enrichment or depletion of specific trace-elements. Pb enrichment was observed only in dust and dry deposition samples from the source region and was most likely from local use of leaded gasoline. Dust particles transported long-distances (VI and TT) exhibited increased enrichment of Mo and minor depletion of other elements relative to source region samples. This suggests that processes occurring during long-distance transport of dust produce enrichment/depletion of specific elements. Bioaccessibility of trace-metals in samples was tested in simulated human fluids (gastric and lung) and was found to be greater in downwind than source region samples, for some metals (e.g., As). The large surface to volume ratio of the dust particles (<2.5 µm) at downwind sites may be a factor.

  8. Evaluation of the wind farm parameterization in the Weather Research and Forecasting model (version 3.8.1) with meteorological and turbine power data

    DOE PAGES

    Lee, Joseph C. Y.; Lundquist, Julie K.

    2017-11-23

    Forecasts of wind-power production are necessary to facilitate the integration of wind energy into power grids, and these forecasts should incorporate the impact of wind-turbine wakes. Our paper focuses on a case study of four diurnal cycles with significant power production, and assesses the skill of the wind farm parameterization (WFP) distributed with the Weather Research and Forecasting (WRF) model version 3.8.1, as well as its sensitivity to model configuration. After validating the simulated ambient flow with observations, we quantify the value of the WFP as it accounts for wake impacts on power production of downwind turbines. We also illustratemore » with statistical significance that a vertical grid with approximately 12 m vertical resolution is necessary for reproducing the observed power production. Further, the WFP overestimates wake effects and hence underestimates downwind power production during high wind speed, highly stable, and low turbulence conditions. We also find the WFP performance is independent of the number of wind turbines per model grid cell and the upwind–downwind position of turbines. Rather, the ability of the WFP to predict power production is most dependent on the skill of the WRF model in simulating the ambient wind speed.« less

  9. Application of ray theory to propagation of low frequency noise from wind turbines

    NASA Technical Reports Server (NTRS)

    Hawkins, James A.

    1987-01-01

    Ray theory is used to explain data from two experiments (1985 and 1985) on the propagation of low frequency sound generated by the WTS-4 wind turbine. Emphasis is on downwind data, but some upwind measurements taken during the 1985 experiment are also considered. General ray theory for a moving medium is reviewed and ray equations obtained. Restrictions are introduced simplifying the equations and permitting the use of a ray theory program MEDUSA, the computed propagation loss curve of which is compared to the measurements. Good qualitative agreement is obtained with 1984 downwind data. The results indicate that the downwind sound field is that of a near-ground sound channel. Although more scatter is seen in the 1985 data, agreement between theory and data is also good. In particular, the position and magnitude of the jump in the sound levels associated with the beginning of the sound channel is correctly predicted. The theoretical explanation of the upwind data is less successful. Ray theory calculations indicate the formation of a shadow zone that, in fact, does not occur. While no sharp shadow zone is apparent in the data, the general expectation (based on ray theory) that sound levels should be much reduced upwind is confirmed by the data.

  10. Evaluation of the wind farm parameterization in the Weather Research and Forecasting model (version 3.8.1) with meteorological and turbine power data

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lee, Joseph C. Y.; Lundquist, Julie K.

    Forecasts of wind-power production are necessary to facilitate the integration of wind energy into power grids, and these forecasts should incorporate the impact of wind-turbine wakes. Our paper focuses on a case study of four diurnal cycles with significant power production, and assesses the skill of the wind farm parameterization (WFP) distributed with the Weather Research and Forecasting (WRF) model version 3.8.1, as well as its sensitivity to model configuration. After validating the simulated ambient flow with observations, we quantify the value of the WFP as it accounts for wake impacts on power production of downwind turbines. We also illustratemore » with statistical significance that a vertical grid with approximately 12 m vertical resolution is necessary for reproducing the observed power production. Further, the WFP overestimates wake effects and hence underestimates downwind power production during high wind speed, highly stable, and low turbulence conditions. We also find the WFP performance is independent of the number of wind turbines per model grid cell and the upwind–downwind position of turbines. Rather, the ability of the WFP to predict power production is most dependent on the skill of the WRF model in simulating the ambient wind speed.« less

  11. The Impact of Prenatal Exposure to Power Plant Emissions on Birth Weight: Evidence from a Pennsylvania Power Plant Located Upwind of New Jersey.

    PubMed

    Yang, Muzhe; Bhatta, Rhea A; Chou, Shin-Yi; Hsieh, Cheng-I

    To examine the infant health impact of prenatal exposure to power plant emissions, we draw scientific evidence on the impacted region downwind of a large polluter, a coal-fired power plant located on the border of two states and proven to be the sole contributor to the violation of air quality standards of the impacted region. Our results show that among all live singleton births that occurred during 1990 through 2006, those born to mothers living as far as 20 to 30 miles away downwind from the power plant (which is also an affluent region) during pregnancy are at greater risks of low birth weight (LBW) and very low birth weight (VLBW): the likelihoods of LBW and VLBW could increase approximately by 6.50 and 17.12 percent, respectively. In light of the continual efforts of The U.S. Environmental Protection Agency in reducing cross-state air pollution caused by transboundary power plant emissions, our study is aimed at broadening the scope of cross-border pollution impact analysis by taking into account adverse infant health effects of upwind polluters, which can impose disproportionate burdens of health risks on downwind states due to air pollutants transported by wind.

  12. Rainfall Modification by Major Urban Areas: Observations from Spaceborne Rain Radar on the TRMM Satellite.

    NASA Astrophysics Data System (ADS)

    Shepherd, J. Marshall; Pierce, Harold; Negri, Andrew J.

    2002-07-01

    Data from the Tropical Rainfall Measuring Mission (TRMM) satellite's precipitation radar (PR) were employed to identify warm-season rainfall (1998-2000) patterns around Atlanta, Georgia; Montgomery, Alabama; Nashville, Tennessee; and San Antonio, Waco, and Dallas, Texas. Results reveal an average increase of about 28% in monthly rainfall rates within 30-60 km downwind of the metropolis, with a modest increase of 5.6% over the metropolis. Portions of the downwind area exhibit increases as high as 51%. The percentage changes are relative to an upwind control area. It was also found that maximum rainfall rates in the downwind impact area exceeded the mean value in the upwind control area by 48%-116%. The maximum value was generally found at an average distance of 39 km from the edge of the urban center or 64 km from the center of the city. Results are consistent with the Metropolitan Meteorological Experiment (METROMEX) studies of St. Louis, Missouri, almost two decades ago and with more recent studies near Atlanta. The study establishes the possibility of utilizing satellite-based rainfall estimates for examining rainfall modification by urban areas on global scales and over longer time periods. Such research has implications for weather forecasting, urban planning, water resource management, and understanding human impact on the environment and climate.

  13. Nighttime Chemistry and Morning Isoprene Can Drive Urban Ozone Downwind of a Major Deciduous Forest.

    PubMed

    Millet, Dylan B; Baasandorj, Munkhbayar; Hu, Lu; Mitroo, Dhruv; Turner, Jay; Williams, Brent J

    2016-04-19

    Isoprene is the predominant non-methane volatile organic compound emitted to the atmosphere and shapes tropospheric composition and biogeochemistry through its effects on ozone, other oxidants, aerosols, and the nitrogen cycle. Isoprene is emitted naturally by vegetation during daytime, when its photo-oxidation is rapid, and in the presence of nitrogen oxides (NOx) produces ozone and degrades air quality in polluted regions. Here, we show for a city downwind of an isoprene-emitting forest (St. Louis, MO) that isoprene actually peaks at night; ambient levels then endure, owing to low nighttime OH radical concentrations. Nocturnal chemistry controls the fate of that isoprene and the likelihood of a high-ozone episode the following day. When nitrate (NO3) radicals are suppressed, high isoprene persists through the night, providing photochemical fuel upon daybreak and leading to a dramatic late-morning ozone peak. On nights with significant NO3, isoprene is removed before dawn; days with low morning isoprene then have lower ozone with a more typical afternoon peak. This biogenic-anthropogenic coupling expands the daily high-ozone window and likely has an opposite O3-NOx response to what would otherwise be expected, with implications for exposure and air-quality management in cities that, like St. Louis, are downwind of major isoprene-emitting forests.

  14. Air ion mobility spectra and concentrations upwind and downwind of overhead AC high voltage power lines

    NASA Astrophysics Data System (ADS)

    Wright, Matthew D.; Buckley, Alison J.; Matthews, James C.; Shallcross, Dudley E.; Henshaw, Denis L.

    2014-10-01

    Corona ions produced by high-voltage power lines (HVPLs) can alter the nearby electrical environment, potentially increasing aerosol charge levels downwind. However, there is a lack of knowledge concerning the concentration and mobility of ions from AC HVPLs and their dispersion away from the line. We present ion concentration and mobility measurements made near AC HVPLs in South-West England. Examples of typical mobility spectra are shown highlighting features commonly observed. Corona was observed during 33 of 46 measurements, at 9 of 11 sites, with positive or ‘bipolar' (both polarities) ion production commonly seen. Ion production usually increases atmospheric concentrations by only a modest amount, but extreme cases can enhance concentration by an order of magnitude or more. A polarity imbalance is required to increase aerosol charge via ion attachment; this was observed on 15 of 24 days when positive corona was observed, but was not seen for negative ions. Ion mobility was higher downwind compared with upwind for both ion polarities, but the increase was not statistically significant. Future work should focus on identifying and characterising ‘heavy-producing' HVPLs, and obtaining results in conditions which may favour negative ion production e.g. high humidity, inclement weather or during nighttime.

  15. Radiation sensitivity and EPR dosimetric potential of gallic acid and its esters

    NASA Astrophysics Data System (ADS)

    Tuner, Hasan; Oktay Bal, M.; Polat, Mustafa

    2015-02-01

    In the preset work the radiation sensitivities of Gallic Acid anhydrous and monohydrate, Octyl, Lauryl, and Ethyl Gallate (GA, GAm, OG, LG, and EG) were investigated in the intermediate (0.5-20 kGy) and low radiation (<10 Gy) dose range using Electron Paramagnetic Resonance (EPR) spectroscopy. While OG, LG, and EG are presented a singlet EPR spectra, their radiation sensitivity found to be very different in the intermediate dose range. At low radiation dose range (<10 Gy) only LG is found to be present a signal that easily distinguished from the noise signals. The intermediate and low dose range radiation sensitivities are compared using well known EPR dosimeter alanine. The radiation yields (G) of the interested material were found to be 1.34×10-2, 1.48×10-2, 4.14×10-2, and 6.03×10-2, 9.44×10-2 for EG, GA, GAm, OG, and LG, respectively at the intermediate dose range. It is found that the simple EPR spectra and the noticeable EPR signal of LG make it a promising dosimetric material to be used below 10 Gy of radiation dose.

  16. Characterization of air pollutant concentrations, fleet emission factors, and dispersion near a North Carolina interstate freeway across two seasons

    NASA Astrophysics Data System (ADS)

    Saha, Provat K.; Khlystov, Andrey; Snyder, Michelle G.; Grieshop, Andrew P.

    2018-03-01

    We present field measurement data and modeling of multiple traffic-related air pollutants during two seasons at a site adjoining Interstate 40, near Durham, North Carolina. We analyze spatial-temporal and seasonal trends and fleet-average pollutant emission factors and use our data to evaluate a line source dispersion model. Month-long measurement campaigns were performed in summer 2015 and winter 2016. Data were collected at a fixed near-road site located within 10 m from the highway edge, an upwind background site and, under favorable meteorological conditions, along downwind perpendicular transects. Measurements included the size distribution, chemical composition, and volatility of submicron particles, black carbon (BC), nitrogen oxides (NOx), meteorological conditions and traffic activity data. Results show strong seasonal and diurnal differences in spatial distribution of traffic sourced pollutants. A strong signature of vehicle emissions was observed within 100-150 m from the highway edge with significantly higher concentrations during morning. Substantially higher concentrations and less-sharp near-road gradients were observed in winter for many species. Season-specific fleet-average fuel-based emission factors for NO, NOx, BC, and particle number (PN) were derived based on up- and down-wind roadside measurements. The campaign-average NOx and PN emission factors were 20% and 300% higher in winter than summer, respectively. These results suggest that the combined effect of higher emissions and their slower downwind dispersion in winter dictate the observed higher downwind concentrations and wider highway influence zone in winter for several species. Finally, measurements of traffic data, emission factors, and pollutant concentrations were integrated to evaluate a line source dispersion model (R-LINE). The dispersion model captured the general trends in the spatial and temporal patterns in near-road concentrations. However, there was a tendency for the model to under-predict concentrations near the road in the mornings and over-predict concentrations in the evenings.

  17. The Influence of Atmospheric Stability on Wind Drift from Ultra-Low-volume Aerial Forest Spray Applications.

    NASA Astrophysics Data System (ADS)

    Crabbe, R. S.; McCooeye, M.; Mickle, R. E.

    1994-04-01

    Measurements of drift cloud mass from 11 cases selected from a study of wind-borne droplet drift from ultra low-volume aerial spray applications over northern Ontario forests are presented as a function of atmospheric stability. Six swaths were overlaid onto a flight line in 30 min to obtain ensemble-averaged data from rotary atomizer emissions from an agricultural spray plane flying at about 21 and 26 m above ground level. The estimated volume median diameters of the spray were 100 µm for the 21-m height and 70 µm for the 26-m height. The mass of spray material in the drift cloud was measured at 400, 1200, and 2200 m downwind of the (crosswind) flight line using Rotorods' suspended from tethered blimps. Wind speed at aircraft height varied from 2 to 5 m s1 and meteorological conditions varied from moderately stable to moderately unstable.Analysis of the data revealed that 35% more drift occurred in stable than in unstable conditions. The lowest drift was measured when the aircraft was flown in the morning mixing layer beneath a low capping inversion. Under thee conditions, only 18% of the emission drifted put 400 m downwind and 10% past 1200 m. The highest drift occurred in moderately stable flow, 71% past 400 m and 50% past 2200 m in 3 m s1 wind speeds and, in slightly stable flow, 77% past 400 m and 27% past 2200 m in 5 m s1 wind speeds.Within experimental error, little difference was observed between wind drift of the 100-µm-diameter droplets and the 70-µm-diameter droplets past 400 m downwind although farther downwind, drift from the larger-droplet emission was less. This difference is discussed in terms of the descent rate of the aircraft vortex wake in stable conditions.

  18. ANEMOS: A computer code to estimate air concentrations and ground deposition rates for atmospheric nuclides emitted from multiple operating sources

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Miller, C.W.; Sjoreen, A.L.; Begovich, C.L.

    This code estimates concentrations in air and ground deposition rates for Atmospheric Nuclides Emitted from Multiple Operating Sources. ANEMOS is one component of an integrated Computerized Radiological Risk Investigation System (CRRIS) developed for the US Environmental Protection Agency (EPA) for use in performing radiological assessments and in developing radiation standards. The concentrations and deposition rates calculated by ANEMOS are used in subsequent portions of the CRRIS for estimating doses and risks to man. The calculations made in ANEMOS are based on the use of a straight-line Gaussian plume atmospheric dispersion model with both dry and wet deposition parameter options. Themore » code will accommodate a ground-level or elevated point and area source or windblown source. Adjustments may be made during the calculations for surface roughness, building wake effects, terrain height, wind speed at the height of release, the variation in plume rise as a function of downwind distance, and the in-growth and decay of daughter products in the plume as it travels downwind. ANEMOS can also accommodate multiple particle sizes and clearance classes, and it may be used to calculate the dose from a finite plume of gamma-ray-emitting radionuclides passing overhead. The output of this code is presented for 16 sectors of a circular grid. ANEMOS can calculate both the sector-average concentrations and deposition rates at a given set of downwind distances in each sector and the average of these quantities over an area within each sector bounded by two successive downwind distances. ANEMOS is designed to be used primarily for continuous, long-term radionuclide releases. This report describes the models used in the code, their computer implementation, the uncertainty associated with their use, and the use of ANEMOS in conjunction with other codes in the CRRIS. A listing of the code is included in Appendix C.« less

  19. Accuracy of vertical radial plume mapping technique in measuring lagoon gas emissions.

    PubMed

    Viguria, Maialen; Ro, Kyoung S; Stone, Kenneth C; Johnson, Melvin H

    2015-04-01

    Recently, the U.S. Environmental Protection Agency (EPA) posted a ground-based optical remote sensing method on its Web site called Other Test Method (OTM) 10 for measuring fugitive gas emission flux from area sources such as closed landfills. The OTM 10 utilizes the vertical radial plume mapping (VRPM) technique to calculate fugitive gas emission mass rates based on measured wind speed profiles and path-integrated gas concentrations (PICs). This study evaluates the accuracy of the VRPM technique in measuring gas emission from animal waste treatment lagoons. A field trial was designed to evaluate the accuracy of the VRPM technique. Control releases of methane (CH4) were made from a 45 m×45 m floating perforated pipe network located on an irrigation pond that resembled typical treatment lagoon environments. The accuracy of the VRPM technique was expressed by the ratio of the calculated emission rates (QVRPM) to actual emission rates (Q). Under an ideal condition of having mean wind directions mostly normal to a downwind vertical plane, the average VRPM accuracy was 0.77±0.32. However, when mean wind direction was mostly not normal to the downwind vertical plane, the emission plume was not adequately captured resulting in lower accuracies. The accuracies of these nonideal wind conditions could be significantly improved if we relaxed the VRPM wind direction criteria and combined the emission rates determined from two adjacent downwind vertical planes surrounding the lagoon. With this modification, the VRPM accuracy improved to 0.97±0.44, whereas the number of valid data sets also increased from 113 to 186. The need for developing accurate and feasible measuring techniques for fugitive gas emission from animal waste lagoons is vital for livestock gas inventories and implementation of mitigation strategies. This field lagoon gas emission study demonstrated that the EPA's vertical radial plume mapping (VRPM) technique can be used to accurately measure lagoon gas emission with two downwind vertical concentration planes surrounding the lagoon.

  20. Water-based condensation particle counters comparison near a major freeway with significant heavy-duty diesel traffic

    NASA Astrophysics Data System (ADS)

    Lee, Eon S.; Polidori, Andrea; Koch, Michael; Fine, Philip M.; Mehadi, Ahmed; Hammond, Donald; Wright, Jeffery N.; Miguel, Antonio. H.; Ayala, Alberto; Zhu, Yifang

    2013-04-01

    This study compares the instrumental performance of three TSI water-based condensation particle counter (WCPC) models measuring particle number concentrations in close proximity (15 m) to a major freeway that has a significant level of heavy-duty diesel traffic. The study focuses on examining instrument biases and performance differences by different WCPC models under realistic field operational conditions. Three TSI models (3781, 3783, and 3785) were operated for one month in triplicate (nine units in total) in parallel with two sets of Scanning Mobility Particle Sizer (SMPS) spectrometers for the concurrent measurement of particle size distributions. Inter-model bias under different wind directions were first evaluated using 1-min raw data. Although all three WCPC models agreed well in upwind conditions (lower particle number concentrations, in the range of 103-104 particles cm-3), the three models' responses were significantly different under downwind conditions (higher particle number concentrations, above 104 particles cm-3). In an effort to increase inter-model linear correlations, we evaluated the results of using longer averaging time intervals. An averaging time of at least 15 min was found to achieve R2 values of 0.96 or higher when comparing all three models. Similar results were observed for intra-model comparisons for each of the three models. This strong linear relationship helped identify instrument bias related to particle number concentrations and particle size distributions. The TSI 3783 produced the highest particle counts, followed by TSI 3785, which reported 11% lower during downwind conditions than TSI 3783. TSI 3781 recorded particle number concentrations that were 24% lower than those observed by TSI 3783 during downwind condition. We found that TSI 3781 underestimated particles with a count median diameter less than 45 nm. Although the particle size dependency of instrument performance was found the most significant in TSI 3781, both models 3783 and 3785 showed somewhat size dependency. In addition, within each tested WCPC model, one unit was found to count significantly different and be more sensitive to particle size than the other two. Finally, exponential regression analysis was used to numerically quantify instrumental inter-model bias. Correction equations are proposed to adjust the TSI 3781 and 3785 data to the most recent model TSI 3783.

  1. A Downscaling Analysis of the Urban Influence on Rainfall: TRMM Satellite Component AMS Conference on Satellite Meteorology and Oceanography

    NASA Technical Reports Server (NTRS)

    Shepherd, J. Marshall; Burian, Steven J.

    2002-01-01

    A recent publication by Shepherd et al. (2002) demonstrated the feasibility of using TRMM precipitation radar (PR) estimates to identify precipitation anomalies caused by urbanization. The approach is particularly useful for investigating this global process because TRMM data span large portions of the globe and comprise an extended temporal dataset. Recent literature suggests that urbanized regions of Houston, Texas may be influencing lightning and precipitation formation over and downwind of the city. Possible mechanisms include: (1) enhanced convergence through interactions between the sea breeze, Galveston bay breeze, and urban heat island circulations, (2) enhanced convergence due to increased surface roughness over the city and/or destabilization of the boundary layer by the UHI, or (3) enhanced cloud condensation nuclei due to urban and industrial aerosol sources. In this study, a downscaling analysis of spatial and temporal trends in rainfall around the Houston Area is being conducted. The downscaling analysis concept involves identifying and quantifying urban rainfall anomalies at progressively smaller spatial and temporal scales using the TRMM satellite, ground-based radar, and a dense network of rain gauges. The goal is to test the hypothesis that the Houston urban district and regions in the climatological downwind region of the city exhibit enhanced rainfall amounts relative to the climatological upwind regions. TRMM was launched in 1997 and currently operates in a low-inclination (35 deg), non-sun-synchronous orbit at an altitude of 402 km (350 km prior to August 2001). The satellite analysis follows the methodologies described in Shepherd et al. (2002). Nearly five years of TRMM PR-derived mean monthly rainfall estimates are utilized to produce annual and warm season isohyetal analyses around Houston. Early results indicate that rainfall rates (mm/h) for the entire period are largest within 100 km northeast and east of Houston (e.g. the "hypothesized downwind region"). The mean rainfall rate over the Houston urban center is 30.5% larger than the upwind control region. The mean rainfall rate in the downwind region is 34.4% larger than the upwind region. An analysis of a parameter called the urban rainfall ratio (URR) illustrates that 65% (88%) of the satellite-derived rainfall rates in the downwind (upwind control) region are greater (less) than the mean background rainfall rate of the entire study region. When the data is stratified by summer months from 1998 to 2001 (June-August), even greater influence over and downwind of the urban area is observed in the statistics. This result is consistent with published reports of urban-generated rainfall being more prevalent in the warm season. The research demonstrates that the evolving TRMM satellite climatology is a credible way to detect mesoscale precipitation signatures that may be linked to urbanization. Early results also corroborate recent findings on Houston-induced convection/drainfall anomalies. Burian and Shepherd will report on other aspects of the downscaling analysis in future forums, but early rain gauge results are consistent with the satellite-based observations.

  2. Intermediate Temperature Water Heat Pipe Tests

    NASA Technical Reports Server (NTRS)

    Devarakonda, Angirasa; Xiong, Da-Xi; Beach, Duane E.

    2005-01-01

    Heat pipes are among the most promising technologies for space radiator systems. Water heat pipes are explored in the intermediate temperature range of 400 to above 500 K. The thermodynamic and thermo-physical properties of water are reviewed in this temperature range. Test data are reported for a copper-water heat pipe. The heat pipe was tested under different orientations. Water heat pipes show promise in this temperature range. Fabrication and testing issues are being addressed.

  3. Making windpower an important part of a national energy plan

    NASA Astrophysics Data System (ADS)

    Finlayson, A. N.

    1981-01-01

    The design characteristics of the Finlayson Windcatcher wind turbine are outlined. The unit geometry consists of two vertical axis cylindrical vane arrays mounted very close to each other and rotating in opposite directions. The two rotors are supported top and bottom by anti-friction bearings mounted at the ends of arms which are attached to a single support pillar. Because the rotor axes are downwind of the support pillar axis, they are free to swing in the horizontal plane, remaining automatically downwind without the need for a separate guide vane. There is not gyroscopic effect of the rotors to hinder rotation in wind direction. A 1-2 kW net electrical output in a 30 mph wind is estimated.

  4. Modeling the CAPTEX Vertical Tracer Concentration Profiles.

    NASA Astrophysics Data System (ADS)

    Draxler, Roland R.; Stunder, Barbara J. B.

    1988-05-01

    Perfluorocarbon tracer concentration profiles measured by aircraft 600-900 km downwind of the release locations during CAPTEX are discussed and compared with some model results. In general, the concentrations decreased with height in the upper half of the boundary layer where the aircraft measurements were made. The results of a model sensitivity study suggested that the shape of the profile was primarily due to winds increasing with height and relative position of the sampling with respect to the upwind and downwind edge of the plume. Further modeling studies showed that relatively simple vertical mixing parameterizations could account for the complex vertical plume structure when the model had sufficient vertical resolution. In general, the model performed better with slower winds and corresponding longer transport times.

  5. Mastcam Telephoto of a Martian Dune Downwind Face

    NASA Image and Video Library

    2016-01-04

    This view combines multiple images from the telephoto-lens camera of the Mast Camera (Mastcam) on NASA's Curiosity Mars rover to reveal fine details of the downwind face of "Namib Dune." The site is part of the dark-sand "Bagnold Dunes" field along the northwestern flank of Mount Sharp. Images taken from orbit have shown that dunes in the Bagnold field move as much as about 3 feet (1 meter) per Earth year. Sand on this face of Namib Dune has cascaded down a slope of about 26 to 28 degrees. The top of the face is about 13 to 17 feet (4 to 5 meters) above the rocky ground at its base. http://photojournal.jpl.nasa.gov/catalog/PIA20283

  6. Cumulus cloud venting of mixed layer ozone

    NASA Technical Reports Server (NTRS)

    Ching, J. K. S.; Shipley, S. T.; Browell, E. V.; Brewer, D. A.

    1985-01-01

    Observations are presented which substantiate the hypothesis that significant vertical exchange of ozone and aerosols occurs between the mixed layer and the free troposphere during cumulus cloud convective activity. The experiments utilized the airborne Ultra-Violet Differential Absorption Lidar (UV-DIAL) system. This system provides simultaneous range resolved ozone concentration and aerosol backscatter profiles with high spatial resolution. Evening transects were obtained in the downwind area where the air mass had been advected. Space-height analyses for the evening flight show the cloud debris as patterns of ozone typically in excess of the ambient free tropospheric background. This ozone excess was approximately the value of the concentration difference between the mixed layer and free troposphere determined from independent vertical soundings made by another aircraft in the afternoon.

  7. Aerobiology and the global transport of desert dust

    USGS Publications Warehouse

    Kellogg, Christina A.; Griffin, Dale W.

    2006-01-01

    Desert winds aerosolize several billion tons of soil-derived dust each year, including concentrated seasonal pulses from Africa and Asia. These transoceanic and transcontinental dust events inject a large pulse of microorganisms and pollen into the atmosphere and could therefore have a role in transporting pathogens or expanding the biogeographical range of some organisms by facilitating long-distance dispersal events. As we discuss here, whether such dispersal events are occurring is only now beginning to be investigated. Huge dust events create an atmospheric bridge over land and sea, and the microbiota contained within them could impact downwind ecosystems. Such dispersal is of interest because of the possible health effects of allergens and pathogens that might be carried with the dust.

  8. INF (Intermediate Range Nuclear Forces) Treaty and flexible response. Research report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lewis, J.W.

    1988-03-01

    This paper examines how the Intermediate Range Nuclear Forces (INF) Treaty affects NATO's military strategy of flexible response. A discussion of flexible response strategy is provided as background for the reader. Then, relevant terms of the INF treaty are addressed followed by an assessment of the treaty's impact on the military strategy of the alliance.

  9. Lidar characterization of crystalline silica generation and transport from a sand and gravel plant.

    PubMed

    Trzepla-Nabaglo, Krystyna; Shiraki, Ryoji; Holmén, Britt A

    2006-04-30

    Light detection and ranging (Lidar) remote sensing two-dimensional vertical and horizontal scans collected downwind of a sand and gravel plant were used to evaluate the generation and transport of geologic fugitive dust emitted by quarry operations. The lidar data give unsurpassed spatial resolution of the emitted dust, but lack quantitative particulate matter (PM) mass concentration data. Estimates of the airborne PM10 and crystalline silica concentrations were determined using linear relationships between point monitor PM10 and quartz content data with the lidar backscatter signal collected from the point monitor location. Lidar vertical profiles at different distances downwind from the plant were used to quantify the PM10 and quartz horizontal fluxes at 2-m vertical resolution as well as off-site emission factors. Emission factors on the order of 65-110 kg of PM10 (10-30 kg quartz) per daily truck activity or 2-4 kg/t product shipped (0.5-1 kg quartz/t) were quantified for this facility. The lidar results identify numerous elevated plumes at heights >30 m and maximum plume heights of 100 m that cannot be practically sampled by conventional point sampler arrays. The PM10 and quartz mass flux was greatest at 10-25 m height and decreased with distance from the main operation. Measures of facility activity were useful for explaining differences in mass flux and emission rates between days. The study results highlight the capabilities of lidar remote sensing for determining the spatial distribution of fugitive dust emitted by area sources with intermittent and spatially diverse dust generation rates.

  10. The Influence of Aerosol Hygroscopicity on Precipitation Intensity During a Mesoscale Convective Event

    NASA Astrophysics Data System (ADS)

    Kawecki, Stacey; Steiner, Allison L.

    2018-01-01

    We examine how aerosol composition affects precipitation intensity using the Weather and Research Forecasting Model with Chemistry (version 3.6). By changing the prescribed default hygroscopicity values to updated values from laboratory studies, we test model assumptions about individual component hygroscopicity values of ammonium, sulfate, nitrate, and organic species. We compare a baseline simulation (BASE, using default hygroscopicity values) with four sensitivity simulations (SULF, increasing the sulfate hygroscopicity; ORG, decreasing organic hygroscopicity; SWITCH, using a concentration-dependent hygroscopicity value for ammonium; and ALL, including all three changes) to understand the role of aerosol composition on precipitation during a mesoscale convective system (MCS). Overall, the hygroscopicity changes influence the spatial patterns of precipitation and the intensity. Focusing on the maximum precipitation in the model domain downwind of an urban area, we find that changing the individual component hygroscopicities leads to bulk hygroscopicity changes, especially in the ORG simulation. Reducing bulk hygroscopicity (e.g., ORG simulation) initially causes fewer activated drops, weakened updrafts in the midtroposphere, and increased precipitation from larger hydrometeors. Increasing bulk hygroscopicity (e.g., SULF simulation) simulates more numerous and smaller cloud drops and increases precipitation. In the ALL simulation, a stronger cold pool and downdrafts lead to precipitation suppression later in the MCS evolution. In this downwind region, the combined changes in hygroscopicity (ALL) reduces the overprediction of intense events (>70 mm d-1) and better captures the range of moderate intensity (30-60 mm d-1) events. The results of this single MCS analysis suggest that aerosol composition can play an important role in simulating high-intensity precipitation events.

  11. An Investigation of the Influence of Urban Areas on Rainfall Using a Cloud-Mesoscale Model and TRMM Satellite

    NASA Technical Reports Server (NTRS)

    Shepherd, J. Marshall; Starr, David OC (Technical Monitor)

    2002-01-01

    The urban heat island (UHI) has become a widely acknowledged, observed, and researched phenomena because of its broad implications. It is estimated that by the year 2025, 80% of the world's population will live in cities (UNFP, 1999). The UHI has been documented in the literature to affect local and regional temperature distributions, wind patterns and air quality. The UHI can also impact the development of clouds and precipitation in and around cities. This paper will focus primarily on the UHI's impact on precipitation. In the past 30 years, several observational and climatological studies have theorized that the UHI can have a significant influence on mesoscale circulations and resulting precipitation (see Shepherd et al. 2002 for a thorough review). More recent studies have continued to validate and extend the findings from pre and post-METROMEX investigations. Shepherd et al. (2002) was one of the first (and possibly the first) attempts to identify rainfall modification by urban areas using satellite-based rainfall measurements. Using a 15-month (spanning three years) analysis of mean rainfall rates, the cities of Atlanta, Montgomery, Dallas, Waco, and San Antonio were examined. Shepherd et al. (2002) found that the average percentage increase in mean rainfall rate in a hypothesized "downwind maximum impact area" over an "upwind control area" was 28.4% with a range of 14.6 to 51%. The typical distance of the downwind rainfall rate anomaly from the urban center was 30-60 km, consistent with earlier studies. This fact provides confidence that UHI-rainfall effects are real and detectable by TRMM satellite estimates.

  12. Evaluation of Noise Exposure Secondary to Wind Noise in Cyclists.

    PubMed

    Seidman, Michael D; Wertz, Anna G; Smith, Matthew M; Jacob, Steve; Ahsan, Syed F

    2017-11-01

    Objective Determine if the noise levels of wind exposure experienced by cyclists reach levels that could contribute to noise-induced hearing loss. Study Design Industrial lab research. Setting Industrial wind tunnel. Subjects and Methods A commercial-grade electric wind tunnel was used to simulate different speeds encountered by a cyclist. A single cyclist was used during the simulation for audiometric measurements. Microphones attached near the ears of the cyclist were used to measure the sound (dB sound pressure level) experienced by the cyclist. Loudness levels were measured with the head positioned at 15-degree increments from 0 degrees to 180 degrees relative to the oncoming wind at different speeds (10-60 mph). Results Wind noise ranged from 84.9 dB at 10 mph and increased proportionally with speed to a maximum of 120.3 dB at 60 mph. The maximum of 120.3 dB was measured at the downwind ear when the ear was 90 degrees away from the wind. Conclusions Wind noise experienced by a cyclist is proportional to the speed and the directionality of the wind current. Turbulent air flow patterns are observed that contribute to increased sound exposure in the downwind ear. Consideration of ear deflection equipment without compromising sound awareness for cyclists during prolonged rides is advised to avoid potential noise trauma. Future research is warranted and can include long-term studies including dosimetry measures of the sound and yearly pre- and postexposure audiograms of cyclists to detect if any hearing loss occurs with long-term cycling.

  13. Observed trends in ground-level O3 in Monterrey, Mexico, during 1993-2014: comparison with Mexico City and Guadalajara

    NASA Astrophysics Data System (ADS)

    Hernández Paniagua, Iván Y.; Clemitshaw, Kevin C.; Mendoza, Alberto

    2017-07-01

    Here, we present an assessment of long-term trends in O3 and odd oxygen (O3 + NO2) at the industrial Monterrey metropolitan area (MMA) in NE Mexico. Diurnal amplitudes in Ox (AVd) are used as a proxy for net O3 production, which is influenced by the NO2 photolysis rate. No significant differences in the AVd are observed between weekends and weekdays, although the largest AVd values are observed at sites downwind of industrial areas. The highest O3 mixing ratios are observed in spring, with minimum values in winter. The largest annual variations in O3 are typically observed downwind of the MMA, with the lowest variations generally recorded in highly populated areas and close to industrial areas. A wind sector analysis of mixing ratios of O3 precursors revealed that the dominant sources of emissions are located in the industrial regions within the MMA and surrounding area. Significant increasing trends in O3 in spring, summer, and autumn are observed depending on site location, with trends in annual averages ranging between 0.19 and 0.33 ppb yr-1. Overall, from 1993 to 2014, within the MMA, O3 has increased at an average rate of 0.22 ppb yr-1 (p < 0. 01), which is in marked contrast with the decline of 1.15 ppb yr-1 (p < 0. 001) observed in the Mexico City metropolitan area (MCMA) for the same period. No clear trend is observed from 1996 to 2014 within the Guadalajara metropolitan area (GMA).

  14. Plant/soil concentration ratios of SSWRa for contrasting sites around an active U mine-mill

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ibrahim, S.A.; Whicker, F.W.

    Concentrations of 226Ra were determined in native vegetation and underlying substrate (soil and tailings) at various sites around a conventional open-pit, acid leach U production operation in Wyoming. Plant/soil concentration ratios (CRs) for 226Ra were estimated for various sites, including weathered tailings; a tailings impoundment shoreline; downwind from exposed tailings; a mine overburden reclamation area; and several background locations. Radium-226 concentrations for vegetation and substrate and CR values from the perturbed sites were elevated above background. The highest vegetation concentration (1.3 Bq g-1) was found in a grass which had invaded exposed, weathered tailings. Levels of 226Ra in soil andmore » vegetation and CR values decreased with distance from the tailings impoundment edge. CR values varied significantly among sites, but few differences were found between plant species groups. The observed CR values ranged from 0.07 at the background and reclamation areas to 0.4 downwind from the tailings area. Average CR values for plants growing on exposed tailings and within one meter from the impoundment edge were 0.15 and 0.3, respectively. CR values of 226Ra for plants on tailings substrates were comparatively low in contrast to other radionuclides in the U chain. We speculate that in the case of sulfuric acid leached tailings-derived material, 226Ra is sequestered as sulfate, which is highly insoluble relative to the sulfates of the other elements (e.g., U and Th) resulting in reduced availability for plant uptake.« less

  15. Constraints on oceanic methane emissions west of Svalbard from atmospheric in situ measurements and Lagrangian transport modeling

    NASA Astrophysics Data System (ADS)

    Pisso, Ignacio; Myhre, Cathrine Lund; Platt, Stephen Matthew; Eckhardt, Sabine; Hermansen, Ove; Schmidbauer, Norbert; Mienert, Jurgen; Vadakkepuliyambatta, Sunil; Bauguitte, Stephane; Pitt, Joseph; Allen, Grant; Bower, Keith; O'Shea, Sebastian; Gallagher, Martin; Percival, Carl; Pyle, John; Cain, Michelle; Stohl, Andreas

    2017-04-01

    Methane stored in seabed reservoirs such as methane hydrates can reach the atmosphere in the form of bubbles or dissolved in water. Hydrates could destabilize with rising temperature further increasing greenhouse gas emissions in a warming climate. To assess the impact of oceanic emissions from the area west of Svalbard, where methane hydrates are abundant, we used measurements collected with a research aircraft (FAAM) and a ship (Helmer Hansen) during the Summer 2014, and for Zeppelin Observatory for the full year. We present a model-supported analysis of the atmospheric CH4 mixing ratios measured by the different platforms. To address uncertainty about where CH4 emissions actually occur, we explored three scenarios: areas with known seeps, a hydrate stability model and an ocean depth criterion. We then used a budget analysis and a Lagrangian particle dispersion model to compare measurements taken upwind and downwind of the potential CH4 emission areas. We found small differences between the CH4 mixing ratios measured upwind and downwind of the potential emission areas during the campaign. By taking into account measurement and sampling uncertainties and by determining the sensitivity of the measured mixing ratios to potential oceanic emissions, we provide upper limits for the CH4 fluxes. The CH4 flux during the campaign was small, with an upper limit of 2.5 nmol / m s in the stability model scenario. The Zeppelin Observatory data for 2014 suggests CH4 fluxes from the Svalbard continental platform below 0.2 Tg/yr . All estimates are in the lower range of values previously reported.

  16. Alternative Significant Contribution Approaches Evaluated

    EPA Pesticide Factsheets

    This Technical Support Document (TSD) discusses alternative approaches that EPA evaluated for defining emissions that constitute each upwind state’s significant contribution to nonattainment and interference with maintenance downwind.

  17. Other Remedy Options Evaluated

    EPA Pesticide Factsheets

    EPA considered several remedy options for reducing emissions from electric generating units (EGUs) that contribute significantly to nonattainment or interfere with maintenance of the air quality standards by downwind states.

  18. Fog composition at Baengnyeong Island in the Eastern Yellow Sea: detecting markers of aqueous atmospheric oxidations

    NASA Astrophysics Data System (ADS)

    Boris, A. J.; Lee, T.; Park, T.; Choi, J.; Seo, S.; Collett, J. L., Jr.

    2015-09-01

    Samples of fog water were collected at Baengnyeong Island (BYI) in the Yellow Sea during the summer of 2014. The most abundant chemical species in the fog water were NH4+ (mean of 2220 μM), NO3- (1260 μM), SO4-2 (730 μM), and Na+ (551 μM), with substantial contributions from other ions consistent with marine and biomass burning influence on some dates. The pH of the samples ranged between 3.48 and 5.00, with a mean of 3.94, intermediate within pH values of fog/cloud water reported previously in Southeast Asia. Back trajectories (72 h) showed that high relative humidity (> 80 %) was encountered upwind of the sampling site by all but one of the sampled air masses, and that the fog composition at BYI can be impacted by several different source regions, including the Sea of Japan, Northeastern China, and the East China Sea. Sulfur in the collected fog was highly oxidized: low S(IV) concentrations were measured (mean of 2.36 μM) in contrast to SO4-2 and in contrast to fog/cloud S(IV) concentrations from pollutant source regions; organosulfate species were also observed and were most likely formed through aging of mainly biogenic volatile organic compounds. Low molecular mass organic acids were major contributors to total organic carbon (TOC; 36-69 %), comprising a fraction of TOC at the upper end of that seen in fogs and clouds in other polluted environments. Large contributions were observed from not only acetic and formic acids, but also oxalic, succinic, maleic, and other organic acids that can be produced in aqueous atmospheric organic processing (AAOP) reactions. These samples of East Asian fog water containing highly oxidized components represent fog downwind of pollutant sources and can provide new insight into the fate of regional emissions. In particular, these samples demonstrate the result of extensive photochemical aging during multiday transport, including oxidation within wet aerosols and fogs.

  19. Factor analysis of submicron particle size distributions near a major United States-Canada trade bridge.

    PubMed

    Ogulei, David; Hopke, Philip K; Ferro, Andrea R; Jaques, Peter A

    2007-02-01

    A factor analytic model has been applied to resolve and apportion particles based on submicron particle size distributions downwind of a United States-Canada bridge in Buffalo, NY. The sites chosen for this study were located at gradually increasing distances downwind of the bridge complex. Seven independent factors were resolved, including four factors that were common to all of the five sites considered. The common factors were generally characterized by the existence of two or more number and surface area modes. The seven factors resolved were identified as follows: fresh tail-pipe diesel exhaust, local/street diesel traffic, aged/evolved diesel particles, spark-ignition gasoline emissions, background urban emissions, heavy-duty diesel agglomerates, and secondary/transported material. Submicron (<0.5 microm) and ultrafine (<0.1 microm) particle emissions downwind of the bridge were dominated by commercial diesel truck emissions. Thus, this study obtained size distinction between fresh versus aged vehicle exhaust and spark-ignition versus diesel emissions based on the measured high time-resolution particle number concentrations. Because this study mainly used particles <300 nm in diameter, some sources that would usually exhibit number modes >100 nm were not resolved. Also, the resolved profiles suggested that the major number mode for fresh tailpipe diesel exhaust might exist below the detection limit of the spectrometer used. The average particle number contributions from the resolved factors were highest closest to the bridge.

  20. Rainfall Modification by Urban Areas: New Perspectives from TRMM

    NASA Technical Reports Server (NTRS)

    Shepherd, J. Marshall; Pierce, Harold F.; Negri, Andrew

    2002-01-01

    Data from the Tropical Rainfall Measuring Mission's (TRMM) Precipitation Radar (PR) were employed to identify warm season rainfall (1998-2000) patterns around Atlanta, Montgomery, Nashville, San Antonio, Waco, and Dallas. Results reveal an average increase of -28% in monthly rainfall rates within 30-60 kilometers downwind of the metropolis with a modest increase of 5.6% over the metropolis. Portions of the downwind area exhibit increases as high as 51%. The percentage changes are relative to an upwind control area. It was also found that maximum rainfall rates in the downwind impact area exceeded the mean value in the upwind control area by 48% - 116%. The maximum value was generally found at an average distance of 39 km from the edge of the urban center or 64 km from the center of the city. Results are consistent with METROMEX studies of St. Louis almost two decades ago and with more recent studies near Atlanta. Future work is extending the investigation to Phoenix, Arizona, an arid U.S. city, and several international cities like Mexico City, Johannesburg, and Brasilia. The study establishes the possibility of utilizing satellite-based rainfall estimates for examining rainfall modification by urban areas on global scales and over longer time periods. Such research has implications for weather forecasting, urban planning, water resource management, and understanding human impact on the environment and climate.

  1. Formation and Growth of New Organic Aerosol Particles over the Deepwater Horizon Oil Spill

    NASA Astrophysics Data System (ADS)

    Brock, C. A.; Murphy, D. M.; Bahreini, R.; Middlebrook, A. M.; De Gouw, J. A.

    2011-12-01

    Aerosol size distributions were measured in June 2010 downwind of the surface oil slick produced by the Deepwater Horizon oil spill in the Gulf of Mexico. Rapid condensation of partially oxidized hydrocarbons was responsible for formation of a plume of secondary organic aerosol downwind of the spill region. New particles were nucleated upwind of the freshest surface oil but downwind of oil that surfaced less than 100 hours previously. These new particles grew by condensation at rates of ~20 nm hr-1; preexisting accumulation mode particles grew by ~10 nm hr-1. The gas-phase concentration of a condensing species necessary to support the observed growth rate assuming irreversible adsorption with unit accommodation coefficient is estimated to be ~0.04-0.09 μg m-3 (~3-8 pptv). The ratio of growth rates for newly formed particles to accumulation mode particles was consistent within error limits with irreversible condensation. Because new particle formation did not occur in areas away from the <100 hr-old oil slick, these results indicate that the oxidation products of VOC species, probably C14-C16 compounds, were directly involved in the growth of the new particles. While a unique and extreme environment, the oil spill plume provides insight into similar processes that may occur in urban and industrial areas where petrochemical products are produced and consumed.

  2. Characterisation of airborne particulate pollution in the Cu smelter and former mining town of Karabash, South Ural Mountains of Russia.

    PubMed

    Williamson, B J; Udachin, V; Purvis, O W; Spiro, B; Cressey, G; Jones, G C

    2004-11-01

    Airborne total suspended particulates (TSP), dusts from smelter blast furnace and converter stacks, and filtrates of snow melt waters have been characterised in the Cu smelter and former mining town of Karabash, Russia. TSP was collected at sites up- and downwind of the smelter and large waste and tailings dumps (Oct. 2000 and July 2001). Methods for particle size, mineralogical and elemental determinations have been tested and described, and a new PSD-MicroSOURCE XRD technique developed for the mineralogical analysis of microsamples on filter substrates. TSP in downwind samples has a mean equivalent spherical diameter of 0.5 microm (s.d. = 0.2) and was found to be 100% respirable. The main element of human health/environmental concern, above Russian maximum permitted levels (1 microg m(-3), average over any time period), was Pb which was measured at 16-30 microg m(-3) in downwind samples. Individual particulates mainly consisted of complex mixtures of anglesite (PbSO4), Zn2SnO4 and poorly ordered Zn sulphates. From experimental and theoretical considerations, a high proportion of contained Pb, Zn, Cd and As in this material is considered to be in a readily bioavailable form. Chemical and mineralogical differences between the TSP, stack dusts and snow samples are discussed, as well as the implications for human and regional environmental health.

  3. Chemical element concentrations in four lichens on a transect entering Voyageurs National Park

    USGS Publications Warehouse

    Bennett, J.; Wetmore, C.M.

    1997-01-01

    A three factor transect study was conducted to test the hypothesis that chemical elements from air emissions in the vicinity of International Falls, Minnesota could not be detected in lichens along a 24 km transect reaching into Voyageurs National Park. It was hypothesized that element concentrations in lichens would decline exponentially downwind and would reach background values at a distance before the park boundary. Four species (Cladina rangiferina, Evernia mesomorpha, Hypogymnia physodes, and Parmelia sulcata) were sampled at ten sites for 3 years and 17 chemical elements were measured. The most notable result was a curvilinear geographic trend for many elements, which decreased from International Falls and then increased towards the park. This trend was significant for many anthropogenic elements, including S, Hg, Cd, and Cr, and for all four species. This type of distribution pattern has been observed in Hypogymnia physodes in other studies downwind of a steel mill and an oil refinery. Cladina, a ground-dwelling lichen, generally had lower tissue concentrations of the elements than the three epiphytic species. Tissue concentrations over the 3 years of sampling declined an average of 12%. Sufficient evidence exists to conclude that lichen tissue element concentrations in the vicinity of International Falls may be related to local air emissions, and that an exponential decline of element concentrations downwind of the sources does not apply to this situation.

  4. Range-gated field disturbance sensor with range-sensitivity compensation

    DOEpatents

    McEwan, T.E.

    1996-05-28

    A field disturbance sensor operates with relatively low power, provides an adjustable operating range, is not hypersensitive at close range, allows co-location of multiple sensors, and is inexpensive to manufacture. The sensor includes a transmitter that transmits a sequence of transmitted bursts of electromagnetic energy. The transmitter frequency is modulated at an intermediate frequency. The sequence of bursts has a burst repetition rate, and each burst has a burst width and comprises a number of cycles at a transmitter frequency. The sensor includes a receiver which receives electromagnetic energy at the transmitter frequency, and includes a mixer which mixes a transmitted burst with reflections of the same transmitted burst to produce an intermediate frequency signal. Circuitry, responsive to the intermediate frequency signal indicates disturbances in the sensor field. Because the mixer mixes the transmitted burst with reflections of the transmitted burst, the burst width defines the sensor range. The burst repetition rate is randomly or pseudorandomly modulated so that bursts in the sequence of bursts have a phase which varies. 8 figs.

  5. Range-gated field disturbance sensor with range-sensitivity compensation

    DOEpatents

    McEwan, Thomas E.

    1996-01-01

    A field disturbance sensor operates with relatively low power, provides an adjustable operating range, is not hypersensitive at close range, allows co-location of multiple sensors, and is inexpensive to manufacture. The sensor includes a transmitter that transmits a sequence of transmitted bursts of electromagnetic energy. The transmitter frequency is modulated at an intermediate frequency. The sequence of bursts has a burst repetition rate, and each burst has a burst width and comprises a number of cycles at a transmitter frequency. The sensor includes a receiver which receives electromagnetic energy at the transmitter frequency, and includes a mixer which mixes a transmitted burst with reflections of the same transmitted burst to produce an intermediate frequency signal. Circuitry, responsive to the intermediate frequency signal indicates disturbances in the sensor field. Because the mixer mixes the transmitted burst with reflections of the transmitted burst, the burst width defines the sensor range. The burst repetition rate is randomly or pseudorandomly modulated so that bursts in the sequence of bursts have a phase which varies.

  6. CAUGHT IN THE ACT: STRONG, ACTIVE RAM PRESSURE STRIPPING IN VIRGO CLUSTER SPIRAL NGC 4330

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Abramson, Anne; Kenney, Jeffrey D. P.; Crowl, Hugh H.

    We present a multi-wavelength study of NGC 4330, a highly inclined spiral galaxy in the Virgo Cluster which is a clear example of strong, ongoing intracluster medium-interstellar medium (ICM-ISM) ram pressure stripping. The H I has been removed from well within the undisturbed old stellar disk, to 50%-65% of R{sub 25}. Multi-wavelength data (WIYN BVR-H{alpha}, Very Large Array 21 cm H I and radio continuum, and Galaxy Evolution Explorer NUV and FUV) reveal several one-sided extraplanar features likely caused by ram pressure at an intermediate disk-wind angle. At the leading edge of the interaction, the H{alpha} and dust extinction curvemore » sharply out of the disk in a remarkable and distinctive 'upturn' feature that may be generally useful as a diagnostic indicator of active ram pressure. On the trailing side, the ISM is stretched out in a long tail which contains 10% of the galaxy's total H I emission, 6%-9% of its NUV-FUV emission, but only 2% of the H{alpha}. The centroid of the H I tail is downwind of the UV/H{alpha} tail, suggesting that the ICM wind has shifted most of the ISM downwind over the course of the past 10-300 Myr. Along the major axis, the disk is highly asymmetric in the UV, but more symmetric in H{alpha} and H I, also implying recent changes in the distributions of gas and star formation. The UV-optical colors indicate very different star formation histories for the leading and trailing sides of the galaxy. On the leading side, a strong gradient in the UV-optical colors of the gas-stripped disk suggests that it has taken 200-400 Myr to strip the gas from a radius of >8 to 5 kpc, but on the trailing side there is no age gradient. All our data suggest a scenario in which NGC 4330 is falling into the cluster center for the first time and has experienced a significant increase in ram pressure over the last 200-400 Myr. Many of the UV-bright stars that form outside the thin disk due to ram pressure will ultimately produce stellar thick disk and halo components with characteristic morphologies and age distributions distinct from those produced by gravitational interactions.« less

  7. Compositional variation in aging volcanic plumes - Analysis of gaseous SO2, CO2 and halogen species in volcanic emissions using an Unmanned Aerial Vehicle (UAV).

    NASA Astrophysics Data System (ADS)

    Rüdiger, Julian; Lukas, Tirpitz; Bobrowski, Nicole; Gutmann, Alexandra; Liotta, Marcello; de Moor, Maarten; Hoffmann, Thorsten

    2017-04-01

    Volcanoes are a large source for several reactive atmospheric trace gases including sulfur and halogen containing species. The detailed understanding of volcanic plume chemistry is needed to draw information from gas measurements on subsurface processes. This knowledge is essential for using gas measurements as a monitoring tool for volcanic activity. The reactive bromine species bromine monoxide (BrO) is of particular interest, because BrO as well as SO2 are readily measurable from safe distance by spectroscopic remote sensing techniques. BrO is not directly emitted, but is formed in the plume by a multiphase reaction mechanism. The abundance of BrO changes as a function of the distance from the vent as well as the spatial position in the plume. The precursor substance for the formation of BrO is HBr with Br2as an intermediate product. In this study we present the application of a UAV as a carrier for a remote-controlled sampling system for halogen species (Br2, HBr, BrCl, etc), based on the gas diffusion denuder technique, which allows speciation and enrichment by selective organic reactions. For the analysis of gaseous SO2 and CO2 an in-situ gas monitoring system was additionally mounted. This setup was deployed into the gas plumes of Stromboli Volcano (Italy), Masaya Volcano (Nicaragua) and Turrialba Volcano (Costa Rica) in 2016, to investigate the halogen chemistry at distant locations in the plume further downwind to the emission source, which are in most cases not accessible by other approaches. Flights into the plume were conducted with ascents of up to 1000 m. From telemetrically transmitted SO2 mixing ratios, areas of dense plume where localized to keep the UAV stationary for up to 10 minutes of sampling time. Additionally, ground based samples were taken at the crater rim (at Masaya and Turrialba) using alkaline traps, denuder and gas sensors for comparison with airborne-collected data. Herein we will present time and spatial resolved gas mixing ratio data for SO2, CO2 and halogen species for crater rim sites and a downwind plume age of about 3 to 5 minutes.

  8. Hydrogeology of the surficial and intermediate aquifers of central Sarasota County, Florida

    USGS Publications Warehouse

    Duerr, A.D.; Wolansky, R.M.

    1986-01-01

    The geohydrologic units underlying a 300 sq mi area in central Sarasota County, Florida, consist of the surficial aquifer, intermediate aquifers (Tamiami-upper Hawthorn and lower Hawthorn-upper Tampa aquifers) and confining units, the Floridan aquifer system, and the sub-Floridan confining unit. The saturated thickness of the surficial aquifer ranges from about 40 to 75 ft and the water table is generally within 5 ft of land surface. The Tamiami-upper Hawthorn is the uppermost intermediate aquifer. The top of the aquifer ranges from about 50 ft to about 75 below sea level and has an average thickness of about 100 ft. The lower Hawthorne-upper Tampa aquifer is the lowermost intermediate aquifer. The top of the aquifer ranges from about 190 to about 220 ft below sea level and its thickness ranges from about 200 to 250 ft. The quality of water in the surficial and the two intermediate aquifers is acceptable for potable use except near the coast. Water from the Floridan aquifer system is used primarily for agricultural purposes because it is too mineralized for most other uses; therefore, the surficial and intermediate aquifers are developed for water supply. The artesian pressure of the various aquifers generally increases with depth. A more detailed geohydrologic description is presented for the Ringling-MacArthur Reserve, a 51 sq mi area in the central part of the county that may be used by Sarasota County as a future water supply. Average annual rainfall is 56 inches and evapotranspiration is about 42 in at the Reserve. The area has a high water table, many sloughs and swamps, and undeveloped land, making it an attractive site as a potential source of water. (Author 's abstract)

  9. Observations of the convective plume of a lake under cold-air advective conditions

    NASA Technical Reports Server (NTRS)

    Bill, R. G., Jr.; Sutherland, R. A.; Bartholic, J. F.; Chen, E.

    1978-01-01

    Moderating effects of Lake Apopka, Florida, on downwind surface temperatures were evaluated under cold-air advective conditions. Point temperature measurements north and south of the lake and data obtained from a thermal scanner flown at 1.6 km indicate that surface temperatures directly downwind may be higher than surrounding surface temperatures by as much as 5 C under conditions of moderate winds (about 4 m/s). No substantial temperature effects were observed with surface wind speed less than 1 m/s. Fluxes of sensible and latent heat from Lake Apopka were calculated from measurements of lake temperature, net radiation, relative humidity, and air temperature above the lake. Bulk transfer coefficients and the Bowen ratio were calculated and found to be in agreement with reported data for nonadvective conditions.

  10. Far Field Modeling Methods For Characterizing Surface Detonations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Garrett, A.

    2015-10-08

    Savannah River National Laboratory (SRNL) analyzed particle samples collected during experiments that were designed to replicate tests of nuclear weapons components that involve detonation of high explosives (HE). SRNL collected the particle samples in the HE debris cloud using innovative rocket propelled samplers. SRNL used scanning electronic microscopy to determine the elemental constituents of the particles and their size distributions. Depleted uranium composed about 7% of the particle contents. SRNL used the particle size distributions and elemental composition to perform transport calculations that indicate in many terrains and atmospheric conditions the uranium bearing particles will be transported long distances downwind.more » This research established that HE tests specific to nuclear proliferation should be detectable at long downwind distances by sampling airborne particles created by the test detonations.« less

  11. View of atmospheric wave patterns by effect of island on wind currents

    NASA Image and Video Library

    1973-12-14

    SL4-137-3632 (February 1974) --- A photograph taken from the Skylab space station in Earth orbit illustrating an atmospheric wave pattern by the affect of a small mountainous island on wind currents. Various patterns can be seen downwind of small islands. Often a Von Karmon vortex can be seen which appears as a spiral pattern. Multiple vortices have been photographed on previous missions. This photograph illustrates a "bow wave" pattern which extends for hundreds of miles downwind from the island. The island itself is often clear when a wave pattern is formed downstream. This particular pattern is very symmetrical. These wave patterns are most common in the South Pacific. This picture was taken by a Skylab 4 crewmen using a hand-held 70mm Hasselblad camera. Photo credit: NASA

  12. Multi-model evaluation of short-lived pollutant distributions over east Asia during summer 2008

    NASA Astrophysics Data System (ADS)

    Quennehen, B.; Raut, J.-C.; Law, K. S.; Daskalakis, N.; Ancellet, G.; Clerbaux, C.; Kim, S.-W.; Lund, M. T.; Myhre, G.; Olivié, D. J. L.; Safieddine, S.; Skeie, R. B.; Thomas, J. L.; Tsyro, S.; Bazureau, A.; Bellouin, N.; Hu, M.; Kanakidou, M.; Klimont, Z.; Kupiainen, K.; Myriokefalitakis, S.; Quaas, J.; Rumbold, S. T.; Schulz, M.; Cherian, R.; Shimizu, A.; Wang, J.; Yoon, S.-C.; Zhu, T.

    2016-08-01

    The ability of seven state-of-the-art chemistry-aerosol models to reproduce distributions of tropospheric ozone and its precursors, as well as aerosols over eastern Asia in summer 2008, is evaluated. The study focuses on the performance of models used to assess impacts of pollutants on climate and air quality as part of the EU ECLIPSE project. Models, run using the same ECLIPSE emissions, are compared over different spatial scales to in situ surface, vertical profiles and satellite data. Several rather clear biases are found between model results and observations, including overestimation of ozone at rural locations downwind of the main emission regions in China, as well as downwind over the Pacific. Several models produce too much ozone over polluted regions, which is then transported downwind. Analysis points to different factors related to the ability of models to simulate VOC-limited regimes over polluted regions and NOx limited regimes downwind. This may also be linked to biases compared to satellite NO2, indicating overestimation of NO2 over and to the north of the northern China Plain emission region. On the other hand, model NO2 is too low to the south and west of this region and over South Korea/Japan. Overestimation of ozone is linked to systematic underestimation of CO particularly at rural sites and downwind of the main Chinese emission regions. This is likely to be due to enhanced destruction of CO by OH. Overestimation of Asian ozone and its transport downwind implies that radiative forcing from this source may be overestimated. Model-observation discrepancies over Beijing do not appear to be due to emission controls linked to the Olympic Games in summer 2008.With regard to aerosols, most models reproduce the satellite-derived AOD patterns over eastern China. Our study nevertheless reveals an overestimation of ECLIPSE model mean surface BC and sulphate aerosols in urban China in summer 2008. The effect of the short-term emission mitigation in Beijing is too weak to explain the differences between the models. Our results rather point to an overestimation of SO2 emissions, in particular, close to the surface in Chinese urban areas. However, we also identify a clear underestimation of aerosol concentrations over northern India, suggesting that the rapid recent growth of emissions in India, as well as their spatial extension, is underestimated in emission inventories. Model deficiencies in the representation of pollution accumulation due to the Indian monsoon may also be playing a role. Comparison with vertical aerosol lidar measurements highlights a general underestimation of scattering aerosols in the boundary layer associated with overestimation in the free troposphere pointing to modelled aerosol lifetimes that are too long. This is likely linked to too strong vertical transport and/or insufficient deposition efficiency during transport or export from the boundary layer, rather than chemical processing (in the case of sulphate aerosols). Underestimation of sulphate in the boundary layer implies potentially large errors in simulated aerosol-cloud interactions, via impacts on boundary-layer clouds.This evaluation has important implications for accurate assessment of air pollutants on regional air quality and global climate based on global model calculations. Ideally, models should be run at higher resolution over source regions to better simulate urban-rural pollutant gradients and/or chemical regimes, and also to better resolve pollutant processing and loss by wet deposition as well as vertical transport. Discrepancies in vertical distributions require further quantification and improvement since these are a key factor in the determination of radiative forcing from short-lived pollutants.

  13. Temporal and spatial variations of polycyclic aromatic hydrocarbon concentrations around a coke oven plant.

    PubMed

    Stella, Anna; Piccardo, Maria Teresa; Pala, Mauro; Balducci, Daniele; Cipolla, Massimo; Ceppi, Marcello; Valerio, Federico

    2012-09-01

    From 1995 to 2004, in Genoa, Italy, daily concentrations of twelve polycyclic aromatic hydrocarbons (PAHs) were measured in particulate phase (PM10), around a coke oven plant in operation from the 1950s and closed in 2002. The study permitted to identify the coke oven as the main PAH source in Genoa, causing constant exceeding of benzo(a)pyrene (BaP) air quality target (1.0 ng/m3) in the urban area till 1,900 meters distance downwind the plant. For this reason the plant was closed. Distance and daily hours downwind the coke plant were the main sources of variability of toxic BaP equivalent (BaPeq) concentrations and equations that best fitted these variables were experimentally obtained. During full plant activity, annual average BaPeq concentrations, measured in the three sampling sites aligned downwind to the summer prevalent winds, were: 85 ng/m3 at 40 m (site 2, industrial area), 13.2 ng/m3 at 300 m (site 3, residential area) and 5.6 ng/m3 at 575 m (site 4, residential area). Soon after the coke oven's closure (February 2002) BaPeq concentrations (annual average) measured in residential area, decreased drastically: 0.2 ng/m3 at site 3, 0.4 ng/m3 at site 4. Comparing 1998 and 2003 data, BaPeq concentrations decreased 97.6% in site 3 and 92.8% in site 4. Samples collected at site 3, during the longest downwind conditions, provided a reliable PAH profile of fugitive coke oven emissions. This profile was significantly different from the PAH profile, contemporary found at site 5, near the traffic flow. This study demonstrates that risk assessment based only on distance of residences from a coke plant can be heavily inaccurate and confirmed that seasonal variability of BaPeq concentrations and high variability of fugitive emissions of PAHs during coke oven activities require at least one year of frequent and constant monitoring (10-15 samples each month). Around a coking plant, polycyclic aromatic hydrocarbons (PAHs), concentrations depend mainly on downwind hours and distance. Equations that best fit these variables were experimentally calculated. Fugitive emissions of an old coke oven did not comply with the threshold BAP air concentration proposed by the World Health Organization (WHO), up to 1,900 m distance. The study identified the PAH profile of fugitive emissions of a coke oven, statistically different from the profile of traffic emissions. During its activity, in the Genoa residential area, 575 m away from the plant, 92.8% of found PAHs was due to coke oven emission only.

  14. Oil Spill Field Trial at Sea: Measurements of Benzene Exposure.

    PubMed

    Gjesteland, Ingrid; Hollund, Bjørg Eli; Kirkeleit, Jorunn; Daling, Per; Bråtveit, Magne

    2017-07-01

    Characterize personal exposure to airborne hydrocarbons, particularly carcinogenic benzene, during spill of two different fresh crude oils at sea. The study included 22 participants taking part in an «oil on water» field trial in the North Sea. Two types of fresh crude oils (light and heavy) were released six times over two consecutive days followed by different oil spill response methods. The participants were distributed on five boats; three open sampling boats (A, B, and C), one release ship (RS), and one oil recovery (OR) vessel. Assumed personal exposure was assessed a priori, assuming high exposure downwind and close to the oil slick (sampling boats), low exposure further downwind (100-200 m) and upwind from the oil slick (main deck of RS and OR vessel), and background exposure indoors (bridge of RS/OR vessel). Continuous measurements of total volatile organic compounds in isobutylene equivalents were performed with photoionization detectors placed in all five boats. Full-shift personal exposure to benzene, toluene, ethylbenzene, xylenes, naphthalene, and n-hexane was measured with passive thermal desorption tubes. Personal measurements of benzene, averaged over the respective sample duration, on Day 1 showed that participants in the sampling boats (A, B, and C) located downwind and close to the oil slick were highest exposed (0.14-0.59 ppm), followed by participants on the RS main deck (0.02-0.10 ppm) and on the bridge (0.004-0.03 ppm). On Day 2, participants in sampling boat A had high benzene exposure (0.87-1.52 ppm) compared to participants in sampling boat B (0.01-0.02 ppm), on the ships (0.06-0.10 ppm), and on the bridge (0.004-0.01 ppm). Overall, the participants in the sampling boats had the highest exposure to all of the compounds measured. The light crude oil yielded a five times higher concentration of total volatile organic compounds in air in the sampling boats (max 510 ppm) than the heavy crude oil (max 100 ppm) but rapidly declined to <20 ppm within 24 min after release of oil, indicating short periods of exposure. The personal exposure to benzene downwind and close to the oil slick during spills of light crude oil was relatively high, with concentration levels approaching the occupational exposure limits for several participants. For bulk spill scenarios like in this study, cleanup should not be initiated the first 30-60 min to allow for evaporation, while appropriate personal protective equipment should be used in continuous spills when working downwind and close to the oil slick. © The Author 2017. Published by Oxford University Press on behalf of the British Occupational Hygiene Society.

  15. The investigation of order–disorder transition process of ZSM-5 induced by spark plasma sintering

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wang, Liang; Wang, Lianjun, E-mail: wanglj@dhu.edu.cn; Jiang, Wan

    2014-04-01

    Based on the amorphization of zeolites, an order–disorder transition method was used to prepare silica glass via Spark Plasma Sintering (SPS). In order to get a better understanding about the mechanism of amorphization induced by SPS, the intermediate products in this process were prepared and characterized by different characterization techniques. X-ray diffraction and High-energy synchrotron X-ray scattering show a gradual transformation from ordered crystal to glass. Local structural changes in glass network including Si–O bond length, O–Si–O bond angle, size of rings, coordination were detected by Infrared spectroscopy and {sup 29}Si magic-angle spinning nuclear magnetic resonance (NMR) spectroscopy. Topologically ordered,more » amorphous material with a different intermediate-range structure can be obtained by precise control of intermediate process which can be expected to optimize and design material. - Graphical abstract: Low-density, ordered zeolites collapse to the rigid amorphous glass through spark plasma sintering. The intermediate-range structure formed in the process of order–disorder transition may give rise to specific property. - Highlights: • Order–disorder transition process of ZSM-5 induced by spark plasma sintering was investigated using several methods including XRD, High-energy synchrotron X-ray scattering, SAXS, IR, NMR, ect. • Order–disorder transition induced by SPS was compared with TIA and PIA. • Three stages has been divided during the whole process. • The collapse temperature range which may give rise to intermediate-range structure has been located.« less

  16. Photochemical model estimated fire impacts on ozone and aerosol evaluated with field studies and routine data sources

    NASA Astrophysics Data System (ADS)

    Baker, K. R.

    2017-12-01

    Highly instrumented field studies provide a unique opportunity to evaluate multiple aspects of photochemical grid model representation of fire emissions, dispersion, and chemical evolution. Fuel information and burn area for a specific fire coupled with near-fire and downwind chemical measurements provides information needed to constrain model predicted fire plume transport and chemical evolution of important pollutants such as ozone and particulate matter (PM2.5) that have deleterious health effects. Most local to regional scale field campaigns to date have made relatively few transects through plumes from fires with well characterized fuel type and consumption. While more comprehensive field studies are being planned for 2018 and beyond (WE-CAN, FIREX, FIRE-CHEM, and FASMEE), existing measurement data from multiple field campaigns including 2013 SEAC4RS, satellite data, and routine surface networks are used to assess how a regulatory modeling system captures fire impacts on local to regional scale ozone and PM2.5. Key aspects of the regulatory modeling system include fire location and burn area from SMARTFIRE2, emissions from BlueSky framework, and predictions of ambient O3 and PM2.5 from the Community Multiscale Air Quality (CMAQ) photochemical transport model. A comparison of model estimated O3 from specific fires with routine surface measurements at rural locations in proximity to the 2013 Rim fire, 2011 Wallow fire, and 2011 Flint Hills fires suggest the modeling system over-estimates smoke impacts on hourly ozone. Sensitivity simulations where solar radiation and photolysis rates are more aggressively attenuated by smoke reduced O3 predictions but did not ameliorate the over prediction bias. PM2.5 organic carbon tends to be overpredicted at rural surface sites downwind from the 2011 Flint Hills prescribed fires while results were mixed at rural sites downwind of the 2013 Rim fire and 2011 Wallow fire suggesting differences in fuel characterization (e.g., emission factors, emissions speciation, burn period, etc.) between these areas may contribute to differences in model prediction. Aircraft plume transects made downwind of the 2013 Rim fire and satellite information suggest the model does well at regional scale plume transport.

  17. An Elevated Reservoir of Air Pollutants over the Mid-Atlantic States During the 2011 DISCOVER-AQ Campaign: Airborne Measurements and Numerical Simulations

    NASA Technical Reports Server (NTRS)

    He, Hao; Loughner, Christopher P.; Stehr, Jeffrey W.; Arkinson, Heather L.; Brent, Lacey C.; Follette-Cook, Melanie B.; Tzortziou, Maria A.; Pickering, Kenneth E.; Thompson, Anne M.; Martins, Douglas K.; hide

    2013-01-01

    During a classic heat wave with record high temperatures and poor air quality from July 18 to 23, 2011, an elevated reservoir of air pollutants was observed over and downwind of Baltimore, MD, with relatively clean conditions near the surface. Aircraft and ozonesonde measurements detected approximately 120 parts per billion by volume ozone at 800 meters altitude, but approximately 80 parts per billion by volume ozone near the surface. High concentrations of other pollutants were also observed around the ozone peak: approximately 300 parts per billion by volume CO at 1200 meters, approximately 2 parts per billion by volume NO2 at 800 meters, approximately 5 parts per billion by volume SO2 at 600 meters, and strong aerosol optical scattering (2 x 10 (sup 4) per meter) at 600 meters. These results suggest that the elevated reservoir is a mixture of automobile exhaust (high concentrations of O3, CO, and NO2) and power plant emissions (high SO2 and aerosols). Back trajectory calculations show a local stagnation event before the formation of this elevated reservoir. Forward trajectories suggest an influence on downwind air quality, supported by surface ozone observations on the next day over the downwind PA, NJ and NY area. Meteorological observations from aircraft and ozonesondes show a dramatic veering of wind direction from south to north within the lowest 5000 meters, implying that the development of the elevated reservoir was caused in part by the Chesapeake Bay breeze. Based on in situ observations, Community Air Quality Multi-scale Model (CMAQ) forecast simulations with 12 kilometers resolution overestimated surface ozone concentrations and failed to predict this elevated reservoir; however, CMAQ research simulations with 4 kilometers and 1.33 kilometers resolution more successfully reproduced this event. These results show that high resolution is essential for resolving coastal effects and predicting air quality for cities near major bodies of water such as Baltimore on the Chesapeake Bay and downwind areas in the Northeast.

  18. Gravity Waves in the Presence of Shear during DEEPWAVE

    NASA Astrophysics Data System (ADS)

    Doyle, J. D.; Jiang, Q.; Reinecke, P. A.; Reynolds, C. A.; Eckermann, S. D.; Fritts, D. C.; Smith, R. B.; Taylor, M. J.; Dörnbrack, A.

    2016-12-01

    The DEEP propagating gravity WAVE program (DEEPWAVE) is a comprehensive, airborne and ground-based measurement and modeling program centered on New Zealand and focused on providing a new understanding of gravity wave dynamics and impacts from the troposphere through the mesosphere and lower thermosphere. This program employed the NSF/NCAR GV (NGV) research aircraft from a base in New Zealand in a 6-week field measurement campaign in June-July 2014. During the field phase, the NGV was equipped with new Rayleigh and sodium resonance lidars and an advanced mesospheric temperature mapper (AMTM), a microwave temperature profiler (MTP), as well as dropwindsondes and flight level instruments providing measurements spanning altitudes from immediately above the NGV flight altitude ( 13 km) to 100 km. In this study, we utilize the DEEPWAVE observations and the nonhydrostatic COAMPS configured at high resolution (2 km) with a deep domain (60-80 km) to explore the effects of horizontal wind shear on gravity wave propagation and wave characteristics. Real-data simulations have been conducted for several DEEPWAVE cases. The results suggest that horizontal shear associated with the stratospheric polar night jet refracts the gravity waves and leads to propagation of waves significantly downwind of the South Island. These waves have been referred to as "trailing gravity waves", since they are found predominantly downwind of the orography of the South Island and the wave crests rotate nearly normal to the mountain crest. Observations from the G-V, remote sensing instruments, and the AIRS satellite confirm the presence of gravity waves downwind of the orography in numerous events. The horizontal propagation in the stratosphere can be explained by group velocity arguments for gravity waves in which the wave energy is advected downwind by the component of the flow normal to the horizontal wavevector. We explore the impact of the shear on gravity wave propagation in COAMPS configured in an idealized mode initialized with a zonally balanced stratospheric jet. The idealized results confirm the importance of horizontal wind shear for the refraction of the waves. The zonal momentum flux minimum is shown to bend or refract into the jet in the stratosphere as a consequence of the wind shear.

  19. Exploring Evidence of Land Surface Dynamics of River Basin Development in East Africa

    NASA Astrophysics Data System (ADS)

    Eluwa, C.; Brown, C.

    2017-12-01

    Improving the productivity of agricultural lands in Africa in the face of climate variability and change is vital to achieving food security. A variety of possible approaches exist, many of which focus on the development and expansion of irrigation - at times associated with dam construction to provide co-benefits of hydropower and water supply. Optimal development of river basin infrastructure such as this has long been a topic of interest in water resources systems analysis. Recent advances have focused on addressing the uncertainty associated with climate change in the development of river basin plans. However, such studies rarely consider either the uncertainty from changing local surface-atmosphere interactions via basin development or the attendant effects on local ecosystems, precipitation, evapotranspiration and consequently the availability of water for the proposed projects. Some numerical experiments have described and reproduced the mechanisms via which river basin infrastructure influences local climatology in Sahelian Africa. However, no studies have explored available data for evidence of land-atmosphere interactions associated with actual development projects. This study explores the correlation of seasonal soil moisture and latent heat flux over currently dammed/irrigated areas on downwind precipitation in the East Africa region (bounded by 0N, -15N, 25E, 40E) at the mesoscale (30km - 100km) to unearth evidence of local climatological effects of river basin development (irrigation schemes). The adopted process is (1) use reanalysis data to derive mean wind directions at 800hPa for selected regions (2) use mean wind directions (and orthogonal directions) to locate high (and low) impact areas 30 -100km downwind (3) extract precipitation time series for downwind locations from three different gridded products (CRU, GCPC, PRINCETON) (4) compare precipitation time series across datasets in high/low impact areas and correlate with upwind latent heat flux and soil moisture (5) perform Pettit change point tests on downwind precipitation and compare with dates of infrastructure development. Evidence from this investigation will supply missing empiricism to hitherto theoretical results and strengthen the basis for much needed improved river basin planning on the continent

  20. Changes in the physico-chemical properties of Amazonian aerosols from background conditions due to urban impacts in Central Amazonia.

    NASA Astrophysics Data System (ADS)

    Artaxo, P.; Barbosa, H. M.; Brito, J.; Carbone, S.; Fiorese, C.; Andre, B.; Rizzo, L. V.; Ditas, F.; Pöhlker, C.; Pöhlker, M. L.; Saturno, J.; Holanda, B. A.; Wang, J.; Souza, R. A. F. D.; Machado, L.; Andreae, M. O.; Martin, S. T.

    2016-12-01

    The GoAmazon 2014/15 experiment (Observations and Modeling of the Green Ocean Amazon) was a great opportunity to study how urbanization can change aerosol properties under pristine conditions in a tropical rain forest. The experiment took place from January 2014 to December 2015 in the vicinity of Manaus, Brazil, where several sampling stations were operated. Natural biogenic aerosol properties were studied in 3 sampling stations upwind of Manaus (ATTO (T0a), ZF2 (T0z) and EMBRAPA (T0e)). Urban impacted aerosols were analysed in two downwind sampling stations at Tiwa (T2) and Manacapuru (T3). Properties analysed were size distribution, scattering and absorption, composition, vertical profiles and others. Remote sensing measurements were done using AERONET and MODIS, while extensive ground based measurements were done in all sampling stations. Remote sensing measurements shows important changes in aerosol optical depth (AOD), especially in the aerosol absorption component. It was also observed a reduction in cloud droplet size downwind of Manaus for liquid phase clouds. Changes in particle number and size were also very significant, that reflected in changes in the aerosol radiative forcing (RF) before and after Manaus plume. In the dry season, an average RF of -24 w/m² was observed upwind, while -17 w/m² was observed downwind, due to large scale biomass burning aerosols. Single scattering albedo (SSA) at 550 nm changed from a high value of 0.96 upwind to 0.84 downwind due to the increase in absorbing aerosols in the wet season. In the dry season, SSA at 550nm changed from 0.95 to 0.87. Aerosol composition showed a large dominance of organic aerosols for all sites, accounting for 65-75% of PM1 non refractory aerosol. Most of these were secondary organic aerosol (SOA), with very low sulfate and nitrate concentrations. The influence of the Manaus plume on aerosol properties was more intense during the wet season, because in the dry season a significant amount of large scale biomass burning aerosol was observed for all GoAmazon 2014/15 sites.

  1. An Investigation of the Influence of Urban Areas on Rainfall Using the TRMM Satellite and a Cloud-Mesoscale Model

    NASA Technical Reports Server (NTRS)

    Shepherd, J. Marshall; OCStarr, David (Technical Monitor)

    2002-01-01

    A recent paper by Shepherd and Pierce (in press at Journal of Applied Meteorology) used rainfall data from the Precipitation Radar on NASA's Tropical Rainfall Measuring Mission's (TRMM) satellite to identify warm season rainfall anomalies downwind of major urban areas. Data (PR) were employed to identify warm season rainfall (1998-2000) patterns around Atlanta, Montgomery, Nashville, San Antonio, Waco, and Dallas. Results reveal an average increase of approx. 28% in monthly rainfall rates within 30-60 kilometers downwind of the metropolis with a modest increase of 5.6% over the metropolis. Portions of the downwind area exhibit increases as high as 51%. The percentage changes are relative to an upwind control area. It was also found that maximum rainfall rates in the downwind impact area exceeded the mean value in the upwind control area by 48%-116%. The maximum value was generally found at an average distance of 39 km from the edge of the urban center or 64 km from the center of the city. Results are consistent with METROMEX studies of St. Louis almost two decades ago and with more recent studies near Atlanta. A convective-mesoscale model with extensive land-surface processes is currently being employed to (a) determine if an urban heat island (UHI) thermal perturbation can induce a dynamic response to affect rainfall processes and (b) quantify the impact of the following three factors on the evolution of rainfall: (1) urban surface roughness, (2) magnitude of the UHI temperature anomaly, and (3) physical size of the UHI temperature anomaly. The sensitivity experiments are achieved by inserting a slab of land with urban properties (e.g. roughness length, albedo, thermal character) within a rural surface environment and varying the appropriate lower boundary condition parameters. The study will discuss the feasibility of utilizing satellite-based rainfall estimates for examining rainfall modification by urban areas on global scales and over longer time periods. The talk also introduces very preliminary results from the modeling component of the study. Such research has implications for weather forecasting, urban planning, water resource management, and understanding human impact on the environment and climate.

  2. Transport of Cs-137 from Boreal Biomass Burning in Summer of 2010

    NASA Technical Reports Server (NTRS)

    Strode, Sarah; Ott, Lesley; Nielsen, Eric; Pawson, Steven

    2010-01-01

    The summer of 2010 was a severe fire season in western Russia. Wildfires were detected in the Bryansk region, raising concerns that radionuclide contamination from the Chernobyl accident could be resuspended in the atmosphere. We simulate the transport of passive and particulate tracers of biomass burning from this region using the GEOS5 GOCART model driven by assimilated meteorology. Biomass burning emissions are based on MODIS fire detections. We validate the model against aerosol optical depth from MODIS. Using a range of estimates for Cs-137 emissions during wildfires, we estimate the downwind concentration and deposition of Cs-137 based on the emission ratios of Cs-137 to the simulated tracers. We discuss the sensitivity of our results to the location of the fires and the fraction of Cs-137 resuspended.

  3. Venus: Atmospheric motion and structure from Mariner 10 pictures

    USGS Publications Warehouse

    Murray, B.C.; Belton, M.J.S.; Danielson, G. Edward; Davies, M.E.; Gault, D.; Hapke, B.; O'Leary, B.; Strom, R.G.; Suomi, V.; Trask, N.

    1974-01-01

    The Mariner 10 television cameras imaged the planet Venus in the visible and near ultraviolet for a period of 8 days at resolutions ranging from 100 meters to 130 kilometers. The general pattern of the atmospheric circulation in the upper tropospheric/lower stratospheric region is displayed in the pictures. Atmospheric flow is symmetrical between north and south hemispheres. The equatorial motions are zonal (east-west) at approximately 100 meters per second, consistent with the previously inferred 4-day retrograde rotation. Angular velocity increases with latitude. The subsolar region, and the region downwind from it, show evidence of large-scale convection that persists in spite of the main zonal motion. Dynamical interaction between the zonal motion and the relatively stationary region of convection is evidenced by bowlike waves.

  4. ARC-1990-AC91-2014

    NASA Image and Video Library

    1990-02-14

    Range : 1.7 million miles This photo of Venus was taken by the Galileo spacecraft's Solid State Imaging System. A high-pass spatial filter has been applied in order to emphasize the smaller-scale cloud features, and the rendition has been colorized to a bluish hue in order to emphasize the subtle contrasts in the cloud markings and to indicate how it was taken through a violet filter. The sulfuric acid clouds indicate considerable convective activity, in the equatorial regions of the planet to the left and downwind of the subsolar point (afternoon on Venus), They are analogous to 'fair weather clouds' on Earth. The filamentary dark features visible in the colorized image are here revealed to be composed of several dark nodules, like strings on a bead, each about 60 miles across.

  5. Evaluating the influences of biomass burning during 2006 BASE-ASIA: a regional chemical transport modeling

    NASA Astrophysics Data System (ADS)

    Fu, J. S.; Hsu, N. C.; Gao, Y.; Huang, K.; Li, C.; Lin, N.-H.; Tsay, S.-C.

    2011-12-01

    To evaluate the impact of biomass burning from Southeast Asia to East Asia, this study conducted numerical simulations during NASA's 2006 Biomass-burning Aerosols in South-East Asia: Smoke Impact Assessment (BASE-ASIA). Two typical episode periods (27-28 March and 13-14 April) were examined. Two emission inventories, FLAMBE and GFED, were used in the simulations. The influences during two episodes in the source region (Southeast Asia) contributed to the surface CO, O3 and PM2.5 concentrations as high as 400 ppbv, 20 ppbv and 80 μg m-3, respectively. The perturbations with and without biomass burning of the above three species during the intense episodes were in the range of 10 to 60%, 10 to 20% and 30 to 70%, respectively. The impact due to long-range transport could spread over the southeastern parts of East Asia and could reach about 160 to 360 ppbv, 8 to 18 ppbv and 8 to 64 μg m-3 on CO, O3 and PM2.5, respectively; the percentage impact could reach 20 to 50% on CO, 10 to 30% on O3, and as high as 70% on PM2.5. In March, the impact of biomass burning was mainly concentrated in Southeast Asia and Southern China, while in April the impact becomes slightly broader, potentially including the Yangtze River Delta region. Two cross-sections at 15° N and 20° N were used to compare the vertical flux of biomass burning. In the source region (Southeast Asia), CO, O3 and PM2.5 concentrations had a strong upward transport from surface to high altitudes. The eastward transport becomes strong from 2 to 8 km in the free troposphere. The subsidence process during the long-range transport contributed 60 to 70%, 20 to 50%, and 80% to CO, O3 and PM2.5, respectively to surface in the downwind area. The study reveals the significant impact of Southeastern Asia biomass burning on the air quality in both local and downwind areas, particularly during biomass burning episodes. This modeling study might provide lower limit constraints. An additional study is underway for an active biomass burning year to obtain an upper limit and climate effects.

  6. Evaluating the influences of biomass burning during 2006 BASE-ASIA: a regional chemical transport modeling

    NASA Astrophysics Data System (ADS)

    Fu, J. S.; Hsu, N. C.; Gao, Y.; Huang, K.; Li, C.; Lin, N.-H.; Tsay, S.-C.

    2012-05-01

    To evaluate the impact of biomass burning from Southeast Asia to East Asia, this study conducted numerical simulations during NASA's 2006 Biomass-burning Aerosols in South-East Asia: Smoke Impact Assessment (BASE-ASIA). Two typical episode periods (27-28 March and 13-14 April) were examined. Two emission inventories, FLAMBE and GFED, were used in the simulations. The influences during two episodes in the source region (Southeast Asia) contributed to the surface CO, O3 and PM2.5 concentrations as high as 400 ppbv, 20 ppbv and 80 μg m-3, respectively. The perturbations with and without biomass burning of the above three species during the intense episodes were in the range of 10 to 60%, 10 to 20% and 30 to 70%, respectively. The impact due to long-range transport could spread over the southeastern parts of East Asia and could reach about 160 to 360 ppbv, 8 to 18 ppbv and 8 to 64 μg m-3 on CO, O3 and PM2.5, respectively; the percentage impact could reach 20 to 50% on CO, 10 to 30% on O3, and as high as 70% on PM2.5. In March, the impact of biomass burning mainly concentrated in Southeast Asia and southern China, while in April the impact becomes slightly broader and even could go up to the Yangtze River Delta region. Two cross-sections at 15° N and 20° N were used to compare the vertical flux of biomass burning. In the source region (Southeast Asia), CO, O3 and PM2.5 concentrations had a strong upward transport from surface to high altitudes. The eastward transport becomes strong from 2 to 8 km in the free troposphere. The subsidence process during the long-range transport contributed 60 to 70%, 20 to 50%, and 80% on CO, O3 and PM2.5, respectively to surface in the downwind area. The study reveals the significant impact of Southeastern Asia biomass burning on the air quality in both local and downwind areas, particularly during biomass burning episodes. This modeling study might provide constraints of lower limit. An additional study is underway for an active biomass burning year to obtain an upper limit and climate effects.

  7. Mercury contamination and potential impacts from municipal waste incinerator on Samui Island, Thailand.

    PubMed

    Muenhor, Dudsadee; Satayavivad, Jutamaad; Limpaseni, Wongpun; Parkpian, Preeda; Delaune, R D; Gambrell, R P; Jugsujinda, Aroon

    2009-03-01

    In recent years, mercury (Hg) pollution generated by municipal waste incinerators (MWIs) has become the subject of serious public concern. On Samui Island, Thailand, a large-scale municipal waste incinerator has been in operation for over 7 years with a capacity of 140 tons/day for meeting the growing demand for municipal waste disposal. This research assessed Hg contamination in environmental matrices adjacent to the waste incinerating plant. Total Hg concentrations were determined in municipal solid waste, soil and sediment within a distance of 100 m to 5 km from the incinerator operation in both wet and dry seasons. Hg analyses conducted in municipal solid waste showed low levels of Hg ranging between 0.15-0.56 mg/kg. The low level was due to the type of waste incinerator. Waste such as electrical appliances, motors and spare parts, rubber tires and hospital wastes are not allowed to feed into the plant. As a result, low Hg levels were also found in fly and bottom ashes (0.1-0.4 mg/kg and

  8. Evidence for a Shared Mechanism in the Formation of Urea-Induced Kinetic and Equilibrium Intermediates of Horse Apomyoglobin from Ultrarapid Mixing Experiments.

    PubMed

    Mizukami, Takuya; Abe, Yukiko; Maki, Kosuke

    2015-01-01

    In this study, the equivalence of the kinetic mechanisms of the formation of urea-induced kinetic folding intermediates and non-native equilibrium states was investigated in apomyoglobin. Despite having similar structural properties, equilibrium and kinetic intermediates accumulate under different conditions and via different mechanisms, and it remains unknown whether their formation involves shared or distinct kinetic mechanisms. To investigate the potential mechanisms of formation, the refolding and unfolding kinetics of horse apomyoglobin were measured by continuous- and stopped-flow fluorescence over a time range from approximately 100 μs to 10 s, along with equilibrium unfolding transitions, as a function of urea concentration at pH 6.0 and 8°C. The formation of a kinetic intermediate was observed over a wider range of urea concentrations (0-2.2 M) than the formation of the native state (0-1.6 M). Additionally, the kinetic intermediate remained populated as the predominant equilibrium state under conditions where the native and unfolded states were unstable (at ~0.7-2 M urea). A continuous shift from the kinetic to the equilibrium intermediate was observed as urea concentrations increased from 0 M to ~2 M, which indicates that these states share a common kinetic folding mechanism. This finding supports the conclusion that these intermediates are equivalent. Our results in turn suggest that the regions of the protein that resist denaturant perturbations form during the earlier stages of folding, which further supports the structural equivalence of transient and equilibrium intermediates. An additional folding intermediate accumulated within ~140 μs of refolding and an unfolding intermediate accumulated in <1 ms of unfolding. Finally, by using quantitative modeling, we showed that a five-state sequential scheme appropriately describes the folding mechanism of horse apomyoglobin.

  9. Analysis to Quantify Significant Contribution

    EPA Pesticide Factsheets

    This Technical Support Document provides information that supports EPA’s analysis to quantify upwind state emissions that significantly contribute to nonattainment or interfere with maintenance of National Ambient Air Quality Standards in downwind states.

  10. Patterns of LGM precipitation in the U.S. Rocky Mountains: results from regional application of a glacier mass/energy balance and flow model

    NASA Astrophysics Data System (ADS)

    Leonard, E. M.; Laabs, B. J.; Refsnider, K. A.; Plummer, M. A.; Jacobsen, R. E.; Wollenberg, J. A.

    2010-12-01

    Global climate model (GCM) simulations of the last glacial maximum (LGM) in the western United States predict changes in atmospheric circulation and storm tracks that would have resulted in significantly less-than-modern precipitation in the Northwest and northern Rockies, and significantly more-than-modern precipitation in the Southwest and southern Rockies. Model simulations also suggest that late Pleistocene pluvial lakes in the intermontane West may have modified local moisture regimes in areas immediately downwind. In this study, we present results of the application of a coupled energy/mass balance and glacier-flow model (Plummer and Phillips, 2003) to reconstructed paleoglaciers in Rocky Mountains of Utah, New Mexico, Colorado, and Wyoming to assess the changes from modern climate that would have been necessary to sustain each glacier in mass-balance equilibrium at its LGM extent. Results demonstrate that strong west-to-east and north-to-south gradients in LGM precipitation, relative to present, would be required if a uniform LGM temperature depression with respect to modern is assumed across the region. At an assumed 7oC temperature depression, approximately modern precipitation would have been necessary to support LGM glaciation in the Colorado Front Range, significantly less than modern precipitation to support glaciation in the Teton Range, and almost twice modern precipitation to sustain glaciers in the Wasatch and Uinta ranges of Utah and the New Mexico Sangre de Cristo Range. The observed west-to-east (Utah-to-Colorado) LGM moisture gradient is consistent with precipitation enhancement from pluvial Lake Bonneville, decreasing with distance downwind from the lake. The north-to-south (Wyoming-to-New Mexico) LGM moisture gradient is consistent with a southward LGM displacement of the mean winter storm track associated with the winter position of the Pacific Jet Stream across the western U.S. Our analysis of paleoglacier extents in the Rocky Mountain region supports the results of GCM simulations of western U.S. precipitation distribution during the LGM, and suggests that this approach provides a practical means of testing such hypotheses about large-scale paleoclimate patterns. Finally, we note that most GCM results indicate greater LGM temperature depression in the northern and eastern portions of the study region than in its southern and western portions - which would necessitate LGM precipitation differences even greater than those determined based on an assumed uniform temperature depression.

  11. Intermediate- and short-range order in phosphorus-selenium glasses

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bytchkov, Aleksei; Hennet, Louis; Price, David L.

    2011-04-01

    State-of-the-art neutron and x-ray diffraction measurements have been performed to provide a definitive picture of the intermediate- and short-range structures of P{sub x}Se{sub 1-x} glasses spanning two glass regions, x 0.025-0.54 and 0.64-0.84. Liquid P{sub 4}Se{sub 3} and amorphous red P and Se were also measured. Detailed information was obtained about the development with increasing phosphorous concentration of intermediate-range order on the length scale {approx}6 A ring , based on the behavior of the first sharp diffraction peak. Attention is also paid to the feature in the structure factor at 7.5 A ring {sup -1}, identified in earlier numerical simulations,more » provides further evidence of the existence of molecular units. The real-space transforms yield a reliable statistical picture of the changing short-range order as x increases, using the information about types and concentrations of local structural units provided by previous NMR measurements to interpret the trends observed.« less

  12. Near-source mobile methane emission estimates using EPA Method33a and a novel probabilistic approach as a basis for leak quantification in urban areas

    NASA Astrophysics Data System (ADS)

    Albertson, J. D.

    2015-12-01

    Methane emissions from underground pipeline leaks remain an ongoing issue in the development of accurate methane emission inventories for the natural gas supply chain. Application of mobile methods during routine street surveys would help address this issue, but there are large uncertainties in current approaches. In this paper, we describe results from a series of near-source (< 30 m) controlled methane releases where an instrumented van was used to measure methane concentrations during both fixed location sampling and during mobile traverses immediately downwind of the source. The measurements were used to evaluate the application of EPA Method 33A for estimating methane emissions downwind of a source and also to test the application of a new probabilistic approach for estimating emission rates from mobile traverse data.

  13. Field investigation of a wake structure downwind of a VANT (Vertical-Axis Wind Turbine) in a wind farm array

    NASA Astrophysics Data System (ADS)

    Liu, H. T.; Buck, J. W.; Germain, A. C.; Hinchee, M. E.; Solt, T. S.; Leroy, G. M.; Srnsky, R. A.

    1988-09-01

    The effects of upwind turbine wakes on the performance of a FloWind 17-m vertical-axis wind turbine (VAWT) were investigated through a series of field experiments conducted at the FloWind wind farm on Cameron Ridge, Tehachapi, California. From the field measurements, we derived the velocity and power/energy deficits under various turbine on/off configurations. Much information was provided to characterize the structure of VAWT wakes and to assess their effects on the performance of downwind turbines. A method to estimate the energy deficit was developed based on the measured power deficit and the wind speed distributions. This method may be adopted for other turbine types and sites. Recommendations are made for optimizing wind farm design and operations, as well as for wind energy management.

  14. On Rainfall Modification by Major Urban Areas. Part 1; Observations from Space-borne Rain Radar on TRMM

    NASA Technical Reports Server (NTRS)

    Shepherd, J. Marshall; Pierce, Harold; Starr, David OC. (Technical Monitor)

    2001-01-01

    This study represents one of the first published attempts to identify rainfall modification by urban areas using satellite-based rainfall measurements. Data from the first space-based rain-radar, the Tropical Rainfall Measuring Mission's (TRMM) Precipitation Radar, are employed. Analysis of the data enables identification of rainfall patterns around Atlanta, Montgomery, Nashville, San Antonio, Waco, and Dallas during the warm season. Results reveal an average increase of -28% in monthly rainfall rates within 30-60 kilometers downwind of the metropolis with a modest increase of 5.6% over the metropolis. Portions of the downwind area exhibit increases as high as 51%. The percentage chances are relative to an upwind CONTROL area. It was also found that maximum rainfall rates in the downwind impact area can exceed the mean value in the upwind CONTROL area by 48%-116%. The maximum value was generally found at an average distance of 39 km from the edge of the urban center or 64 km from the center of the city. These results are consistent with METROMEX studies of St. Louis almost two decades ago and more recent studies near Atlanta. Future work will investi(yate hypothesized factors causing rainfall modification by urban areas. Additional work is also needed to provide more robust validation of space-based rain estimates near major urban areas. Such research has implications for urban planning, water resource management, and understanding human impact on the environment.

  15. Global ERS 1 and 2 and NSCAT observations: Upwind/crosswind and upwind/downwind measurements

    NASA Astrophysics Data System (ADS)

    Quilfen, Y.; Chapron, B.; Bentamy, A.; Gourrion, J.; El Fouhaily, T.; Vandemark, D.

    1999-05-01

    This paper presents an analysis of the wind speed dependence of upwind/downwind asymmetry (UDA) and upwind-crosswind anisotropy (UCA) as derived from global C band VV-polarized ERS 1 and 2 and Ku band VV- and HH-polarized NASA scatterometer (NSCAT) data. Interpretation of the results relies on identifying relationships between the differing frequencies and incidence angles that are consistent with Bragg scattering theory from gravity-capillary waves. It is shown that globally derived parameters characterizing UDA and UCA hold information on the wind dependence of short gravity and gravity-capillary wave growth and dissipation. In particular, the UCA behavior is found quadratic for both the C and Ku band, peaking at moderate wind speeds. In addition, the dual-frequency results appear to map out the expected, more rapid adjustment of centimeter-scale (Ku band) waves to the wind direction at light winds. However, as wind increases, the directionality associated with these shorter waves saturates at a lower speed than for the slightly longer waves inferred at C band. It is suggested that this observed phenomenon may be related to increasing wave-drift interactions that can potentially inhibit short-scale surface wave growth along the wind direction. Concerning UDA properties, our present analysis reveals that the NSCAT and ERS 1 and 2 scatterometers give quite different results. Our preliminary interpretation is that C band measurements may be easier to interpret using composite Bragg scattering theory and that upwind/downwind contrasts are mainly supported by short gravity waves.

  16. Self-similarity and flow characteristics of vertical-axis wind turbine wakes: an LES study

    NASA Astrophysics Data System (ADS)

    Abkar, Mahdi; Dabiri, John O.

    2017-04-01

    Large eddy simulation (LES) is coupled with a turbine model to study the structure of the wake behind a vertical-axis wind turbine (VAWT). In the simulations, a tuning-free anisotropic minimum dissipation model is used to parameterise the subfilter stress tensor, while the turbine-induced forces are modelled with an actuator line technique. The LES framework is first validated in the simulation of the wake behind a model straight-bladed VAWT placed in the water channel and then used to study the wake structure downwind of a full-scale VAWT sited in the atmospheric boundary layer. In particular, the self-similarity of the wake is examined, and it is found that the wake velocity deficit can be well characterised by a two-dimensional multivariate Gaussian distribution. By assuming a self-similar Gaussian distribution of the velocity deficit, and applying mass and momentum conservation, an analytical model is developed and tested to predict the maximum velocity deficit downwind of the turbine. Also, a simple parameterisation of VAWTs for LES with very coarse grid resolutions is proposed, in which the turbine is modelled as a rectangular porous plate with the same thrust coefficient. The simulation results show that, after some downwind distance (x/D ≈ 6), both actuator line and rectangular porous plate models have similar predictions for the mean velocity deficit. These results are of particular importance in simulations of large wind farms where, due to the coarse spatial resolution, the flow around individual VAWTs is not resolved.

  17. Atmospheric ammonia mixing ratios at an open-air cattle feeding facility.

    PubMed

    Hiranuma, Naruki; Brooks, Sarah D; Thornton, Daniel C O; Auvermann, Brent W

    2010-02-01

    Mixing ratios of total and gaseous ammonia were measured at an open-air cattle feeding facility in the Texas Panhandle in the summers of 2007 and 2008. Samples were collected at the nominally upwind and downwind edges of the facility. In 2008, a series of far-field samples was also collected 3.5 km north of the facility. Ammonium concentrations were determined by two complementary laboratory methods, a novel application of visible spectrophotometry and standard ion chromatography (IC). Results of the two techniques agreed very well, and spectrophotometry is faster, easier, and cheaper than chromatography. Ammonia mixing ratios measured at the immediate downwind site were drastically higher (approximately 2900 parts per billion by volume [ppbv]) than thos measured at the upwind site (< or = 200 ppbv). In contrast, at 3.5 km away from the facility, ammonia mixing ratios were reduced to levels similar to the upwind site (< or = 200 ppbv). In addition, PM10 (particulate matter < 10 microm in optical diameter) concentrations obtained at each sampling location using Grimm portable aerosol spectrometers are reported. Time-averaged (1-hr) volume concentrations of PM10 approached 5 x 10(12) nm3 cm(-3). Emitted ammonia remained largely in the gas phase at the downwind and far-field locations. No clear correlation between concentrations of ammonia and particles was observed. Overall, this study provides a better understanding of ammonia emissions from open-air animal feeding operations, especially under the hot and dry conditions present during these measurements.

  18. Three-dimensional structure of wind turbine wakes as measured by scanning lidar

    NASA Astrophysics Data System (ADS)

    Bodini, Nicola; Zardi, Dino; Lundquist, Julie K.

    2017-08-01

    The lower wind speeds and increased turbulence that are characteristic of turbine wakes have considerable consequences on large wind farms: turbines located downwind generate less power and experience increased turbulent loads. The structures of wakes and their downwind impacts are sensitive to wind speed and atmospheric variability. Wake characterization can provide important insights for turbine layout optimization in view of decreasing the cost of wind energy. The CWEX-13 field campaign, which took place between June and September 2013 in a wind farm in Iowa, was designed to explore the interaction of multiple wakes in a range of atmospheric stability conditions. Based on lidar wind measurements, we extend, present, and apply a quantitative algorithm to assess wake parameters such as the velocity deficits, the size of the wake boundaries, and the location of the wake centerlines. We focus on wakes from a row of four turbines at the leading edge of the wind farm to explore variations between wakes from the edge of the row (outer wakes) and those from turbines in the center of the row (inner wakes). Using multiple horizontal scans at different elevations, a three-dimensional structure of wakes from the row of turbines can be created. Wakes erode very quickly during unstable conditions and can in fact be detected primarily in stable conditions in the conditions measured here. During stable conditions, important differences emerge between the wakes of inner turbines and the wakes of outer turbines. Further, the strong wind veer associated with stable conditions results in a stretching of the wake structures, and this stretching manifests differently for inner and outer wakes. These insights can be incorporated into low-order wake models for wind farm layout optimization or for wind power forecasting.

  19. Effects of wind direction on coarse and fine particulate matter concentrations in southeast Kansas.

    PubMed

    Guerra, Sergio A; Lane, Dennis D; Marotz, Glen A; Carter, Ray E; Hohl, Carrie M; Baldauf, Richard W

    2006-11-01

    Field data for coarse particulate matter ([PM] PM10) and fine particulate matter (PM2.5) were collected at selected sites in Southeast Kansas from March 1999 to October 2000, using portable MiniVol particulate samplers. The purpose was to assess the influence on air quality of four industrial facilities that burn hazardous waste in the area located in the communities of Chanute, Independence, Fredonia, and Coffeyville. Both spatial and temporal variation were observed in the data. Variation because of sampling site was found to be statistically significant for PM10 but not for PM2.5. PM10 concentrations were typically slightly higher at sites located within the four study communities than at background sites. Sampling sites were located north and south of the four targeted sources to provide upwind and downwind monitoring pairs. No statistically significant differences were found between upwind and downwind samples for either PM10 or PM2.5, indicating that the targeted sources did not contribute significantly to PM concentrations. Wind direction can frequently contribute to temporal variation in air pollutant concentrations and was investigated in this study. Sampling days were divided into four classifications: predominantly south winds, predominantly north winds, calm/variable winds, and winds from other directions. The effect of wind direction was found to be statistically significant for both PM10 and PM2.5. For both size ranges, PM concentrations were typically highest on days with predominantly south winds; days with calm/variable winds generally produced higher concentrations than did those with predominantly north winds or those with winds from "other" directions. The significant effect of wind direction suggests that regional sources may exert a large influence on PM concentrations in the area.

  20. Three-dimensional structure of wind turbine wakes as measured by scanning lidar

    DOE PAGES

    Bodini, Nicola; Zardi, Dino; Lundquist, Julie K.

    2017-08-14

    The lower wind speeds and increased turbulence that are characteristic of turbine wakes have considerable consequences on large wind farms: turbines located downwind generate less power and experience increased turbulent loads. The structures of wakes and their downwind impacts are sensitive to wind speed and atmospheric variability. Wake characterization can provide important insights for turbine layout optimization in view of decreasing the cost of wind energy. The CWEX-13 field campaign, which took place between June and September 2013 in a wind farm in Iowa, was designed to explore the interaction of multiple wakes in a range of atmospheric stability conditions.more » Based on lidar wind measurements, we extend, present, and apply a quantitative algorithm to assess wake parameters such as the velocity deficits, the size of the wake boundaries, and the location of the wake centerlines. We focus on wakes from a row of four turbines at the leading edge of the wind farm to explore variations between wakes from the edge of the row (outer wakes) and those from turbines in the center of the row (inner wakes). Using multiple horizontal scans at different elevations, a three-dimensional structure of wakes from the row of turbines can be created. Wakes erode very quickly during unstable conditions and can in fact be detected primarily in stable conditions in the conditions measured here. During stable conditions, important differences emerge between the wakes of inner turbines and the wakes of outer turbines. Further, the strong wind veer associated with stable conditions results in a stretching of the wake structures, and this stretching manifests differently for inner and outer wakes. As a result, these insights can be incorporated into low-order wake models for wind farm layout optimization or for wind power forecasting.« less

  1. Modeling regional/urban ozone and particulate matter in Beijing, China.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Fu, J.S.; Streets, D.G.; Jang, C.J.

    2009-01-15

    This paper examines Beijing air quality in the winter and summer of 2001 using an integrated air quality modeling system (Fifth Generation Mesoscale Meteorological Model (MM5)/Community Multiscale Air Quality (CMAQ)) in nested mode. The National Aeronautics and Space Administration (NASA) Transport and Chemical Evolution over the Pacific (TRACE-P) emission inventory is used in the 36- (East Asia), 12- (East China), and 4-km (greater Beijing area) domains. Furthermore, we develop a local Beijing emission inventory that is used in the 4-km domain. We also construct a corroborated mapping of chemical species between the TRACE-P inventory and the Carbon Bond IV (CB-IV)more » chemical mechanism before the integrated modeling system is applied to study ozone (O{sub 3}) and particulate matter (PM) in Beijing. Meteorological data for the integrated modeling runs are extracted from MM5. Model results show O{sub 3} hourly concentrations in the range of 80-159 parts per billion (ppb) during summer in the urban areas and up to 189 ppb downwind of the city. High fine PM (PM2.5) concentrations (monthly average of 75 {mu}g.m{sup -3} in summer and 150 {mu}g.m{sup -3} in winter) are simulated over the metropolitan and down-wind areas with significant secondary constituents. Major sources of particulates were biomass burning, coal combustion and industry. A comparison against available O{sub 3} and PM measurement data in Beijing is described. We recommend refinements to the developed local Beijing emission inventory to improve the simulation of Beijing's air quality. The 4-km modeling configuration is also recommended for the development of air pollution control strategies. 31 refs., 5 figs., 3 tabs.« less

  2. Measurements of Methane Emissions and Volatile Organic Compounds from Shale Gas Operations in the Marcellus Shale

    NASA Astrophysics Data System (ADS)

    Omara, M.; Subramanian, R.; Sullivan, M.; Robinson, A. L.; Presto, A. A.

    2014-12-01

    The Marcellus Shale is the most expansive shale gas reserve in play in the United States, representing an estimated 17 to 29 % of the total domestic shale gas reserves. The rapid and extensive development of this shale gas reserve in the past decade has stimulated significant interest and debate over the climate and environmental impacts associated with fugitive releases of methane and other pollutants, including volatile organic compounds. However, the nature and magnitude of these pollutant emissions remain poorly characterized. This study utilizes the tracer release technique to characterize total fugitive methane release rates from natural gas facilities in southwestern Pennsylvania and West Virginia that are at different stages of development, including well completion flowbacks and active production. Real-time downwind concentrations of methane and two tracer gases (acetylene and nitrous oxide) released onsite at known flow rates were measured using a quantum cascade tunable infrared laser differential absorption spectrometer (QC-TILDAS, Aerodyne, Billerica, MA) and a cavity ring down spectrometer (Model G2203, Picarro, Santa Clara, CA). Evacuated Silonite canisters were used to sample ambient air during downwind transects of methane and tracer plumes to assess volatile organic compounds (VOCs). A gas chromatograph with a flame ionization detector was used to quantify VOCs following the EPA Method TO-14A. A preliminary assessment of fugitive emissions from actively producing sites indicated that methane leak rates ranged from approximately 1.8 to 6.2 SCFM, possibly reflecting differences in facility age and installed emissions control technology. A detailed comparison of methane leak rates and VOCs emissions with recent published literature for other US shale gas plays will also be discussed.

  3. Urban emissions of water vapor in winter

    NASA Astrophysics Data System (ADS)

    Salmon, Olivia E.; Shepson, Paul B.; Ren, Xinrong; Marquardt Collow, Allison B.; Miller, Mark A.; Carlton, Annmarie G.; Cambaliza, Maria O. L.; Heimburger, Alexie; Morgan, Kristan L.; Fuentes, Jose D.; Stirm, Brian H.; Grundman, Robert; Dickerson, Russell R.

    2017-09-01

    Elevated water vapor (H2Ov) mole fractions were occasionally observed downwind of Indianapolis, IN, and the Washington, D.C.-Baltimore, MD, area during airborne mass balance experiments conducted during winter months between 2012 and 2015. On days when an urban H2Ov excess signal was observed, H2Ov emission estimates range between 1.6 × 104 and 1.7 × 105 kg s-1 and account for up to 8.4% of the total (background + urban excess) advected flow of atmospheric boundary layer H2Ov from the urban study sites. Estimates of H2Ov emissions from combustion sources and electricity generation facility cooling towers are 1-2 orders of magnitude smaller than the urban H2Ov emission rates estimated from observations. Instances of urban H2Ov enhancement could be a result of differences in snowmelt and evaporation rates within the urban area, due in part to larger wintertime anthropogenic heat flux and land cover differences, relative to surrounding rural areas. More study is needed to understand why the urban H2Ov excess signal is observed on some days, and not others. Radiative transfer modeling indicates that the observed urban enhancements in H2Ov and other greenhouse gas mole fractions contribute only 0.1°C d-1 to the urban heat island at the surface. This integrated warming through the boundary layer is offset by longwave cooling by H2Ov at the top of the boundary layer. While the radiative impacts of urban H2Ov emissions do not meaningfully influence urban heat island intensity, urban H2Ov emissions may have the potential to alter downwind aerosol and cloud properties.

  4. Spatial clustering of toxic trace elements in adolescents around the Torreón, Mexico lead-zinc smelter.

    PubMed

    Garcia-Vargas, Gonzalo G; Rothenberg, Stephen J; Silbergeld, Ellen K; Weaver, Virginia; Zamoiski, Rachel; Resnick, Carol; Rubio-Andrade, Marisela; Parsons, Patrick J; Steuerwald, Amy J; Navas-Acién, Ana; Guallar, Eliseo

    2014-11-01

    High blood lead (BPb) levels in children and elevated soil and dust arsenic, cadmium, and lead were previously found in Torreón, northern Mexico, host to the world's fourth largest lead-zinc metal smelter. The objectives of this study were to determine spatial distributions of adolescents with higher BPb and creatinine-corrected urine total arsenic, cadmium, molybdenum, thallium, and uranium around the smelter. Cross-sectional study of 512 male and female subjects 12-15 years of age was conducted. We measured BPb by graphite furnace atomic absorption spectrometry and urine trace elements by inductively coupled plasma-mass spectrometry, with dynamic reaction cell mode for arsenic. We constructed multiple regression models including sociodemographic variables and adjusted for subject residence spatial correlation with spatial lag or error terms. We applied local indicators of spatial association statistics to model residuals to identify hot spots of significant spatial clusters of subjects with higher trace elements. We found spatial clusters of subjects with elevated BPb (range 3.6-14.7 μg/dl) and urine cadmium (0.18-1.14 μg/g creatinine) adjacent to and downwind of the smelter and elevated urine thallium (0.28-0.93 μg/g creatinine) and uranium (0.07-0.13 μg/g creatinine) near ore transport routes, former waste, and industrial discharge sites. The conclusion derived from this study was that spatial clustering of adolescents with high BPb and urine cadmium adjacent to and downwind of the smelter and residual waste pile, areas identified over a decade ago with high lead and cadmium in soil and dust, suggests that past and/or present plant operations continue to present health risks to children in those neighborhoods.

  5. Three-dimensional structure of wind turbine wakes as measured by scanning lidar

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bodini, Nicola; Zardi, Dino; Lundquist, Julie K.

    The lower wind speeds and increased turbulence that are characteristic of turbine wakes have considerable consequences on large wind farms: turbines located downwind generate less power and experience increased turbulent loads. The structures of wakes and their downwind impacts are sensitive to wind speed and atmospheric variability. Wake characterization can provide important insights for turbine layout optimization in view of decreasing the cost of wind energy. The CWEX-13 field campaign, which took place between June and September 2013 in a wind farm in Iowa, was designed to explore the interaction of multiple wakes in a range of atmospheric stability conditions.more » Based on lidar wind measurements, we extend, present, and apply a quantitative algorithm to assess wake parameters such as the velocity deficits, the size of the wake boundaries, and the location of the wake centerlines. We focus on wakes from a row of four turbines at the leading edge of the wind farm to explore variations between wakes from the edge of the row (outer wakes) and those from turbines in the center of the row (inner wakes). Using multiple horizontal scans at different elevations, a three-dimensional structure of wakes from the row of turbines can be created. Wakes erode very quickly during unstable conditions and can in fact be detected primarily in stable conditions in the conditions measured here. During stable conditions, important differences emerge between the wakes of inner turbines and the wakes of outer turbines. Further, the strong wind veer associated with stable conditions results in a stretching of the wake structures, and this stretching manifests differently for inner and outer wakes. As a result, these insights can be incorporated into low-order wake models for wind farm layout optimization or for wind power forecasting.« less

  6. Time Dependence of Aerosol Light Scattering Downwind of Forest Fires

    NASA Astrophysics Data System (ADS)

    Kleinman, L. I.; Sedlacek, A. J., III; Wang, J.; Lewis, E. R.; Springston, S. R.; Chand, D.; Shilling, J.; Arnott, W. P.; Freedman, A.; Onasch, T. B.; Fortner, E.; Zhang, Q.; Yokelson, R. J.; Adachi, K.; Buseck, P. R.

    2017-12-01

    In the first phase of BBOP (Biomass Burn Observation Project), a Department of Energy (DOE) sponsored study, wildland fires in the Pacific Northwest were sampled from the G-1 aircraft via sequences of transects that encountered emission whose age (time since emission) ranged from approximately 15 minutes to four hours. Comparisons between transects allowed us to determine the near-field time evolution of trace gases, aerosol particles, and optical properties. The fractional increase in aerosol concentration with plume age was typically less than a third of the fractional increase in light scattering. In some fires the increase in light scattering exceeded a factor of two. Two possible causes for the discrepancy between scattering and aerosol mass are i) the downwind formation of refractory tar balls that are not detected by the AMS and therefore contribute to scattering but not to aerosol mass and ii) changes to the aerosol size distribution. Both possibilities are considered. Our information on tar balls comes from an analysis of TEM grids. A direct determination of size changes is complicated by extremely high aerosol number concentrations that caused coincidence problems for the PCASP and UHSAS probes. We instead construct a set of plausible log normal size distributions and for each member of the set do Mie calculations to determine mass scattering efficiency (MSE), angstrom exponents, and backscatter ratios. Best fit size distributions are selected by comparison with observed data derived from multi-wavelength scattering measurements, an extrapolated FIMS size distribution, and mass measurements from an SP-AMS. MSE at 550 nm varies from a typical near source value of 2-3 to about 4 in aged air.

  7. Herbicide sorption to fine particulate matter suspended downwind of agricultural operations: field and laboratory investigations.

    PubMed

    Clymo, Amelia S; Shin, Jin Young; Holmen, Britt A

    2005-01-15

    Tillage-induced erosion of herbicides bound to airborne soil particles has not been quantified as a mechanism for offsite herbicide transport. This study quantifies the release of two preemergent herbicides, metolachlor and pendimethalin, to the atmosphere as gas- and particle-phase species during soil incorporation operations. Fine particulate matter (PM2.5) and gas-phase samples were collected at three sampling heights during herbicide disking into the soil in Davis, CA, in May 2000 and May 2001 using filter/PUF sampling. Quartz fiber filters (QFFs) were used in May 2000, and Teflon membrane filters (TMFs) were used in May 2001. The field data were combined with laboratory filter/PUF partitioning experiments to account for adsorption to the filter surfaces and quantify the mass of PM2.5-bound herbicides in the field samples. Laboratory results indicate a significant adsorption of metolachlor, but not pendimethalin, to the quartz filter surfaces. Metolachlor partitioning to PM2.5 collected on TMF filters resulted in corrected PM2.5 field partition coefficient values, Kp,corr = Cp/Cg, of approximately 10(-3.5) m3/microg, indicating its preference for the gas phase. Pendimethalin exhibited more semivolatile behavior,with Kp,corr values that ranged from 10(-3) to 10(-1) m3/ microg and increased with sampling height and distance downwind of the operation. An increase in pendimethalin enrichment at a height of 5 m suggests winnowing of finer, more sorptive soil components with corresponding higher transport potential. Pendimethalin was enriched in the PM2.5 samples by up to a factor of 250 compared to the field soil, indicating thatfurther research on the processes controlling the generation of PM-bound herbicides during agricultural operations is warranted to enable prediction of off-site mass fluxes by this mechanism.

  8. Urban Emissions of Water Vapor in Winter.

    PubMed

    Salmon, Olivia E; Shepson, Paul B; Ren, Xinrong; Marquardt Collow, Allison B; Miller, Mark A; Carlton, Annmarie G; Cambaliza, Maria O L; Heimburger, Alexie; Morgan, Kristan L; Fuentes, Jose D; Stirm, Brian H; Grundman, Robert; Dickerson, Russell R

    2017-09-16

    Elevated water vapor (H 2 O v ) mole fractions were occassionally observed downwind of Indianapolis, IN, and the Washington, D.C.-Baltimore, MD, area during airborne mass balance experiments conducted during winter months between 2012 and 2015. On days when an urban H 2 O v excess signal was observed, H 2 O v emissions estimates range between 1.6 × 10 4 and 1.7 × 10 5 kg s -1 , and account for up to 8.4% of the total (background + urban excess) advected flow of atmospheric boundary layer H 2 O v from the urban study sites. Estimates of H 2 O v emissions from combustion sources and electricity generation facility cooling towers are 1-2 orders of magnitude smaller than the urban H 2 O v emission rates estimated from observations. Instances of urban H 2 O v enhancement could be a result of differences in snowmelt and evaporation rates within the urban area, due in part to larger wintertime anthropogenic heat flux and land cover differences, relative to surrounding rural areas. More study is needed to understand why the urban H 2 O v excess signal is observed on some days, and not others. Radiative transfer modeling indicates that the observed urban enhancements in H 2 O v and other greenhouse gas mole fractions contribute only 0.1°C day -1 to the urban heat island at the surface. This integrated warming through the boundary layer is offset by longwave cooling by H 2 O v at the top of the boundary layer. While the radiative impacts of urban H 2 O v emissions do not meaningfully influence urban heat island intensity, urban H 2 O v emissions may have the potential to alter downwind aerosol and cloud properties.

  9. Spatial clustering of toxic trace elements in adolescents around the Torreón, Mexico lead–zinc smelter

    PubMed Central

    Garcia-Vargas, Gonzalo G.; Rothenberg, Stephen J.; Silbergeld, Ellen K.; Weaver, Virginia; Zamoiski, Rachel; Resnick, Carol; Rubio-Andrade, Marisela; Parsons, Patrick J.; Steuerwald, Amy J.; Navas-Acién, Ana; Guallar, Eliseo

    2016-01-01

    High blood lead (BPb) levels in children and elevated soil and dust arsenic, cadmium, and lead were previously found in Torreón, northern Mexico, host to the world’s fourth largest lead–zinc metal smelter. The objectives of this study were to determine spatial distributions of adolescents with higher BPb and creatinine-corrected urine total arsenic, cadmium, molybdenum, thallium, and uranium around the smelter. Cross-sectional study of 512 male and female subjects 12–15 years of age was conducted. We measured BPb by graphite furnace atomic absorption spectrometry and urine trace elements by inductively coupled plasma-mass spectrometry, with dynamic reaction cell mode for arsenic. We constructed multiple regression models including sociodemographic variables and adjusted for subject residence spatial correlation with spatial lag or error terms. We applied local indicators of spatial association statistics to model residuals to identify hot spots of significant spatial clusters of subjects with higher trace elements. We found spatial clusters of subjects with elevated BPb (range 3.6–14.7 µg/dl) and urine cadmium (0.18–1.14 µg/g creatinine) adjacent to and downwind of the smelter and elevated urine thallium (0.28–0.93 µg/g creatinine) and uranium (0.07–0.13 µg/g creatinine) near ore transport routes, former waste, and industrial discharge sites. The conclusion derived from this study was that spatial clustering of adolescents with high BPb and urine cadmium adjacent to and downwind of the smelter and residual waste pile, areas identified over a decade ago with high lead and cadmium in soil and dust, suggests that past and/or present plant operations continue to present health risks to children in those neighborhoods. PMID:24549228

  10. Constraints on oceanic methane emissions west of Svalbard from atmospheric in situ measurements and Lagrangian transport modeling.

    PubMed

    Pisso, I; Myhre, C Lund; Platt, S M; Eckhardt, S; Hermansen, O; Schmidbauer, N; Mienert, J; Vadakkepuliyambatta, S; Bauguitte, S; Pitt, J; Allen, G; Bower, K N; O'Shea, S; Gallagher, M W; Percival, C J; Pyle, J; Cain, M; Stohl, A

    2016-12-16

    Methane stored in seabed reservoirs such as methane hydrates can reach the atmosphere in the form of bubbles or dissolved in water. Hydrates could destabilize with rising temperature further increasing greenhouse gas emissions in a warming climate. To assess the impact of oceanic emissions from the area west of Svalbard, where methane hydrates are abundant, we used measurements collected with a research aircraft (Facility for Airborne Atmospheric Measurements) and a ship (Helmer Hansen) during the Summer 2014 and for Zeppelin Observatory for the full year. We present a model-supported analysis of the atmospheric CH 4 mixing ratios measured by the different platforms. To address uncertainty about where CH 4 emissions actually occur, we explored three scenarios: areas with known seeps, a hydrate stability model, and an ocean depth criterion. We then used a budget analysis and a Lagrangian particle dispersion model to compare measurements taken upwind and downwind of the potential CH 4 emission areas. We found small differences between the CH 4 mixing ratios measured upwind and downwind of the potential emission areas during the campaign. By taking into account measurement and sampling uncertainties and by determining the sensitivity of the measured mixing ratios to potential oceanic emissions, we provide upper limits for the CH 4 fluxes. The CH 4 flux during the campaign was small, with an upper limit of 2.5 nmol m -2  s -1 in the stability model scenario. The Zeppelin Observatory data for 2014 suggest CH 4 fluxes from the Svalbard continental platform below 0.2 Tg yr -1 . All estimates are in the lower range of values previously reported.

  11. The National Environmental Respiratory Center (NERC) experiment in multi-pollutant air quality health research: II. Comparison of responses to diesel and gasoline engine exhausts, hardwood smoke and simulated downwind coal emissions.

    PubMed

    Mauderly, J L; Barrett, E G; Day, K C; Gigliotti, A P; McDonald, J D; Harrod, K S; Lund, A K; Reed, M D; Seagrave, J C; Campen, M J; Seilkop, S K

    2014-09-01

    The NERC Program conducted identically designed exposure-response studies of the respiratory and cardiovascular responses of rodents exposed by inhalation for up to 6 months to diesel and gasoline exhausts (DE, GE), wood smoke (WS) and simulated downwind coal emissions (CE). Concentrations of the four combustion-derived mixtures ranged from near upper bound plausible to common occupational and environmental hotspot levels. An "exposure effect" statistic was created to compare the strengths of exposure-response relationships and adjustments were made to minimize false positives among the large number of comparisons. All four exposures caused statistically significant effects. No exposure caused overt illness, neutrophilic lung inflammation, increased circulating micronuclei or histopathology of major organs visible by light microscopy. DE and GE caused the greatest lung cytotoxicity. WS elicited the most responses in lung lavage fluid. All exposures reduced oxidant production by unstimulated alveolar macrophages, but only GE suppressed stimulated macrophages. Only DE retarded clearance of bacteria from the lung. DE before antigen challenge suppressed responses of allergic mice. CE tended to amplify allergic responses regardless of exposure order. GE and DE induced oxidant stress and pro-atherosclerotic responses in aorta; WS and CE had no such effects. No overall ranking of toxicity was plausible. The ranking of exposures by number of significant responses varied among the response models, with each of the four causing the most responses for at least one model. Each exposure could also be deemed most or least toxic depending on the exposure metric used for comparison. The database is available for additional analyses.

  12. Effects of Large-Scale Solar Installations on Dust Mobilization and Air Quality

    NASA Astrophysics Data System (ADS)

    Pratt, J. T.; Singh, D.; Diffenbaugh, N. S.

    2012-12-01

    Large-scale solar projects are increasingly being developed worldwide and many of these installations are located in arid, desert regions. To examine the effects of these projects on regional dust mobilization and air quality, we analyze aerosol product data from NASA's Multi-angle Imaging Spectroradiometer (MISR) at annual and seasonal time intervals near fifteen photovoltaic and solar thermal stations ranging from 5-200 MW (12-4,942 acres) in size. The stations are distributed over eight different countries and were chosen based on size, location and installation date; most of the installations are large-scale, took place in desert climates and were installed between 2006 and 2010. We also consider air quality measurements of particulate matter between 2.5 and 10 micrometers (PM10) from the Environmental Protection Agency (EPA) monitoring sites near and downwind from the project installations in the U.S. We use monthly wind data from the NOAA's National Center for Atmospheric Prediction (NCEP) Global Reanalysis to select the stations downwind from the installations, and then perform statistical analysis on the data to identify any significant changes in these quantities. We find that fourteen of the fifteen regions have lower aerosol product after the start of the installations as well as all six PM10 monitoring stations showing lower particulate matter measurements after construction commenced. Results fail to show any statistically significant differences in aerosol optical index or PM10 measurements before and after the large-scale solar installations. However, many of the large installations are very recent, and there is insufficient data to fully understand the long-term effects on air quality. More data and higher resolution analysis is necessary to better understand the relationship between large-scale solar, dust and air quality.

  13. Dimensional and chemical characterization of particles at a downwind receptor site of a waste-to-energy plant

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Buonanno, G., E-mail: buonanno@unicas.i; Stabile, L.; Avino, P.

    2010-07-15

    In the last years numerous epidemiological studies were carried out to evaluate the effects of particulate matter on human health. In industrialized areas, anthropogenic activities highly contribute to the fine and ultrafine particle concentrations. Then, it is important to characterize the evolution of particle size distribution and chemical composition near these emission points. Waste incineration represents a favorable technique for reducing the waste volume. However, in the past, municipal waste incinerators (MWIs) had a bad reputation due to the emission of toxic combustion byproducts. Consequently, the risk perception of the people living near MWIs is very high even if inmore » Western countries waste incineration has nowadays to be considered a relatively clean process from a technical point of view. The study here presented has an exemplary meaning for developing appropriate management and control strategies for air quality in the surrounding of MWIs and to perform exposure assessment for populations involved. Environment particles were continuously measured through a SMPS/APS system over 12 months. The monitoring site represents a downwind receptor of a typical MWI. Furthermore, elements and organic fractions were measured by means of the Instrumental Neutron Activation Analysis and using dichotomous and high volume samplers. Annual mean values of 8.6 x 10{sup 3} +- 3.7 x 10{sup 2} part. cm{sup -3} and 31.1 +- 9.0 mug m{sup -3} were found for number and mass concentration, typical of a rural site. Most of the elements can be attributed to long-range transport from other natural and/or anthropogenic sources. Finally, the Polycyclic Aromatic Hydrocarbons present low concentrations with a mean value of 24.6 ng m{sup -3}.« less

  14. Influence of solid noise barriers on near-road and on-road air quality

    NASA Astrophysics Data System (ADS)

    Baldauf, Richard W.; Isakov, Vlad; Deshmukh, Parikshit; Venkatram, Akula; Yang, Bo; Zhang, K. Max

    2016-03-01

    Public health concerns regarding adverse health effects for populations spending significant amounts of time near high traffic roadways has increased substantially in recent years. Roadside features, including solid noise barriers, have been investigated as potential methods that can be implemented in a relatively short time period to reduce air pollution exposures from nearby traffic. A field study was conducted to determine the influence of noise barriers on both on-road and downwind pollutant concentrations near a large highway in Phoenix, Arizona, USA. Concentrations of nitrogen dioxide, carbon monoxide, ultrafine particles, and black carbon were measured using a mobile platform and fixed sites along two limited-access stretches of highway that contained a section of noise barrier and a section with no noise barrier at-grade with the surrounding terrain. Results of the study showed that pollutant concentrations behind the roadside barriers were significantly lower relative to those measured in the absence of barriers. The reductions ranged from 50% within 50 m from the barrier to about 30% as far as 300 m from the barrier. Reductions in pollutant concentrations generally began within the first 50 m of the barrier edge; however, concentrations were highly variable due to vehicle activity behind the barrier and along nearby urban arterial roadways. The concentrations on the highway, upwind of the barrier, varied depending on wind direction. Overall, the on-road concentrations in front of the noise barrier were similar to those measured in the absence of the barrier, contradicting previous modeling results that suggested roadside barriers increase pollutant levels on the road. Thus, this study suggests that noise barriers do reduce potential pollutant exposures for populations downwind of the road, and do not likely increase exposures to traffic-related pollutants for vehicle passengers on the highway.

  15. Constraints on oceanic methane emissions west of Svalbard from atmospheric in situ measurements and Lagrangian transport modeling

    PubMed Central

    Myhre, C. Lund; Platt, S. M.; Eckhardt, S.; Hermansen, O.; Schmidbauer, N.; Mienert, J.; Vadakkepuliyambatta, S.; Bauguitte, S.; Pitt, J.; Allen, G.; Bower, K. N.; O'Shea, S.; Gallagher, M. W.; Percival, C. J.; Pyle, J.; Cain, M.; Stohl, A.

    2016-01-01

    Abstract Methane stored in seabed reservoirs such as methane hydrates can reach the atmosphere in the form of bubbles or dissolved in water. Hydrates could destabilize with rising temperature further increasing greenhouse gas emissions in a warming climate. To assess the impact of oceanic emissions from the area west of Svalbard, where methane hydrates are abundant, we used measurements collected with a research aircraft (Facility for Airborne Atmospheric Measurements) and a ship (Helmer Hansen) during the Summer 2014 and for Zeppelin Observatory for the full year. We present a model‐supported analysis of the atmospheric CH4 mixing ratios measured by the different platforms. To address uncertainty about where CH4 emissions actually occur, we explored three scenarios: areas with known seeps, a hydrate stability model, and an ocean depth criterion. We then used a budget analysis and a Lagrangian particle dispersion model to compare measurements taken upwind and downwind of the potential CH4 emission areas. We found small differences between the CH4 mixing ratios measured upwind and downwind of the potential emission areas during the campaign. By taking into account measurement and sampling uncertainties and by determining the sensitivity of the measured mixing ratios to potential oceanic emissions, we provide upper limits for the CH4 fluxes. The CH4 flux during the campaign was small, with an upper limit of 2.5 nmol m−2 s−1 in the stability model scenario. The Zeppelin Observatory data for 2014 suggest CH4 fluxes from the Svalbard continental platform below 0.2 Tg yr−1. All estimates are in the lower range of values previously reported. PMID:28261536

  16. Constraints on oceanic methane emissions west of Svalbard from atmospheric in situ measurements and Lagrangian transport modeling

    NASA Astrophysics Data System (ADS)

    Pisso, I.; Myhre, C. Lund; Platt, S. M.; Eckhardt, S.; Hermansen, O.; Schmidbauer, N.; Mienert, J.; Vadakkepuliyambatta, S.; Bauguitte, S.; Pitt, J.; Allen, G.; Bower, K. N.; O'Shea, S.; Gallagher, M. W.; Percival, C. J.; Pyle, J.; Cain, M.; Stohl, A.

    2016-12-01

    Methane stored in seabed reservoirs such as methane hydrates can reach the atmosphere in the form of bubbles or dissolved in water. Hydrates could destabilize with rising temperature further increasing greenhouse gas emissions in a warming climate. To assess the impact of oceanic emissions from the area west of Svalbard, where methane hydrates are abundant, we used measurements collected with a research aircraft (Facility for Airborne Atmospheric Measurements) and a ship (Helmer Hansen) during the Summer 2014 and for Zeppelin Observatory for the full year. We present a model-supported analysis of the atmospheric CH4 mixing ratios measured by the different platforms. To address uncertainty about where CH4 emissions actually occur, we explored three scenarios: areas with known seeps, a hydrate stability model, and an ocean depth criterion. We then used a budget analysis and a Lagrangian particle dispersion model to compare measurements taken upwind and downwind of the potential CH4 emission areas. We found small differences between the CH4 mixing ratios measured upwind and downwind of the potential emission areas during the campaign. By taking into account measurement and sampling uncertainties and by determining the sensitivity of the measured mixing ratios to potential oceanic emissions, we provide upper limits for the CH4 fluxes. The CH4 flux during the campaign was small, with an upper limit of 2.5 nmol m-2 s-1 in the stability model scenario. The Zeppelin Observatory data for 2014 suggest CH4 fluxes from the Svalbard continental platform below 0.2 Tg yr-1. All estimates are in the lower range of values previously reported.

  17. A new algorithm quantifies the roles of wind and midge flight activity in the bluetongue epizootic in northwest Europe

    PubMed Central

    Sedda, Luigi; Brown, Heidi E.; Purse, Bethan V.; Burgin, Laura; Gloster, John; Rogers, David J.

    2012-01-01

    The 2006 bluetongue (BT) outbreak in northwestern Europe had devastating effects on cattle and sheep in that intensively farmed area. The role of wind in disease spread, through its effect on Culicoides dispersal, is still uncertain, and remains unquantified. We examine here the relationship between farm-level infection dates and wind speed and direction within the framework of a novel model involving both mechanistic and stochastic steps. We consider wind as both a carrier of host semio-chemicals, to which midges might respond by upwind flight, and as a transporter of the midges themselves, in a more or less downwind direction. For completeness, we also consider midge movement independent of wind and various combinations of upwind, downwind and random movements. Using stochastic simulation, we are able to explain infection onset at 94 per cent of the 2025 affected farms. We conclude that 54 per cent of outbreaks occurred through (presumably midge) movement of infections over distances of no more than 5 km, 92 per cent over distances of no more than 31 km and only 2 per cent over any greater distances. The modal value for all infections combined is less than 1 km. Our analysis suggests that previous claims for a higher frequency of long-distance infections are unfounded. We suggest that many apparent long-distance infections resulted from sequences of shorter-range infections; a ‘stepping stone’ effect. Our analysis also found that downwind movement (the only sort so far considered in explanations of BT epidemics) is responsible for only 39 per cent of all infections, and highlights the effective contribution to disease spread of upwind midge movement, which accounted for 38 per cent of all infections. The importance of midge flight speed is also investigated. Within the same model framework, lower midge active flight speed (of 0.13 rather than 0.5 m s−1) reduced virtually to zero the role of upwind movement, mainly because modelled wind speeds in the area concerned were usually greater than such flight speed. Our analysis, therefore, highlights the need to improve our knowledge of midge flight speed in field situations, which is still very poorly understood. Finally, the model returned an intrinsic incubation period of 8 days, in accordance with the values reported in the literature. We argue that better understanding of the movement of infected insect vectors is an important ingredient in the management of future outbreaks of BT in Europe, and other devastating vector-borne diseases elsewhere. PMID:22319128

  18. Quantifying error of lidar and sodar Doppler beam swinging measurements of wind turbine wakes using computational fluid dynamics

    DOE PAGES

    Lundquist, J. K.; Churchfield, M. J.; Lee, S.; ...

    2015-02-23

    Wind-profiling lidars are now regularly used in boundary-layer meteorology and in applications such as wind energy and air quality. Lidar wind profilers exploit the Doppler shift of laser light backscattered from particulates carried by the wind to measure a line-of-sight (LOS) velocity. The Doppler beam swinging (DBS) technique, used by many commercial systems, considers measurements of this LOS velocity in multiple radial directions in order to estimate horizontal and vertical winds. The method relies on the assumption of homogeneous flow across the region sampled by the beams. Using such a system in inhomogeneous flow, such as wind turbine wakes ormore » complex terrain, will result in errors. To quantify the errors expected from such violation of the assumption of horizontal homogeneity, we simulate inhomogeneous flow in the atmospheric boundary layer, notably stably stratified flow past a wind turbine, with a mean wind speed of 6.5 m s -1 at the turbine hub-height of 80 m. This slightly stable case results in 15° of wind direction change across the turbine rotor disk. The resulting flow field is sampled in the same fashion that a lidar samples the atmosphere with the DBS approach, including the lidar range weighting function, enabling quantification of the error in the DBS observations. The observations from the instruments located upwind have small errors, which are ameliorated with time averaging. However, the downwind observations, particularly within the first two rotor diameters downwind from the wind turbine, suffer from errors due to the heterogeneity of the wind turbine wake. Errors in the stream-wise component of the flow approach 30% of the hub-height inflow wind speed close to the rotor disk. Errors in the cross-stream and vertical velocity components are also significant: cross-stream component errors are on the order of 15% of the hub-height inflow wind speed (1.0 m s −1) and errors in the vertical velocity measurement exceed the actual vertical velocity. By three rotor diameters downwind, DBS-based assessments of wake wind speed deficits based on the stream-wise velocity can be relied on even within the near wake within 1.0 s -1 (or 15% of the hub-height inflow wind speed), and the cross-stream velocity error is reduced to 8% while vertical velocity estimates are compromised. Furthermore, measurements of inhomogeneous flow such as wind turbine wakes are susceptible to these errors, and interpretations of field observations should account for this uncertainty.« less

  19. Quantifying error of lidar and sodar Doppler beam swinging measurements of wind turbine wakes using computational fluid dynamics

    NASA Astrophysics Data System (ADS)

    Lundquist, J. K.; Churchfield, M. J.; Lee, S.; Clifton, A.

    2015-02-01

    Wind-profiling lidars are now regularly used in boundary-layer meteorology and in applications such as wind energy and air quality. Lidar wind profilers exploit the Doppler shift of laser light backscattered from particulates carried by the wind to measure a line-of-sight (LOS) velocity. The Doppler beam swinging (DBS) technique, used by many commercial systems, considers measurements of this LOS velocity in multiple radial directions in order to estimate horizontal and vertical winds. The method relies on the assumption of homogeneous flow across the region sampled by the beams. Using such a system in inhomogeneous flow, such as wind turbine wakes or complex terrain, will result in errors. To quantify the errors expected from such violation of the assumption of horizontal homogeneity, we simulate inhomogeneous flow in the atmospheric boundary layer, notably stably stratified flow past a wind turbine, with a mean wind speed of 6.5 m s-1 at the turbine hub-height of 80 m. This slightly stable case results in 15° of wind direction change across the turbine rotor disk. The resulting flow field is sampled in the same fashion that a lidar samples the atmosphere with the DBS approach, including the lidar range weighting function, enabling quantification of the error in the DBS observations. The observations from the instruments located upwind have small errors, which are ameliorated with time averaging. However, the downwind observations, particularly within the first two rotor diameters downwind from the wind turbine, suffer from errors due to the heterogeneity of the wind turbine wake. Errors in the stream-wise component of the flow approach 30% of the hub-height inflow wind speed close to the rotor disk. Errors in the cross-stream and vertical velocity components are also significant: cross-stream component errors are on the order of 15% of the hub-height inflow wind speed (1.0 m s-1) and errors in the vertical velocity measurement exceed the actual vertical velocity. By three rotor diameters downwind, DBS-based assessments of wake wind speed deficits based on the stream-wise velocity can be relied on even within the near wake within 1.0 m s-1 (or 15% of the hub-height inflow wind speed), and the cross-stream velocity error is reduced to 8% while vertical velocity estimates are compromised. Measurements of inhomogeneous flow such as wind turbine wakes are susceptible to these errors, and interpretations of field observations should account for this uncertainty.

  20. Atmospheric nitrogen deposition to the northwestern Pacific: seasonal variation and source attribution

    NASA Astrophysics Data System (ADS)

    Zhao, Y.; Zhang, L.; Pan, Y.; Wang, Y.; Paulot, F.; Henze, D. K.

    2015-09-01

    Rapid Asian industrialization has led to increased downwind atmospheric nitrogen deposition threatening the marine environment. We present an analysis of the sources and processes controlling atmospheric nitrogen deposition to the northwestern Pacific, using the GEOS-Chem global chemistry model and its adjoint model at 1/2° × 2/3° horizontal resolution over East Asia and its adjacent oceans. We focus our analyses on the marginal seas: the Yellow Sea and the South China Sea. Asian nitrogen emissions in the model are 28.6 Tg N a-1 as NH3 and 15.7 Tg N a-1 as NOx. China has the largest sources with 12.8 Tg N a-1 as NH3 and 7.9 Tg N a-1 as NOx; the high-NH3 emissions reflect its intensive agricultural activities. We find Asian NH3 emissions are a factor of 3 higher in summer than winter. The model simulation for 2008-2010 is evaluated with NH3 and NO2 column observations from satellite instruments, and wet deposition flux measurements from surface monitoring sites. Simulated atmospheric nitrogen deposition to the northwestern Pacific ranges 0.8-20 kg N ha-1 a-1, decreasing rapidly downwind of the Asian continent. Deposition fluxes average 11.9 kg N ha-1 a-1 (5.0 as reduced nitrogen NHx and 6.9 as oxidized nitrogen NOy) to the Yellow Sea, and 5.6 kg N ha-1 a-1 (2.5 as NHx and 3.1 as NOy) to the South China Sea. Nitrogen sources over the ocean (ship NOx and oceanic NH3) have little contribution to deposition over the Yellow Sea, about 7 % over the South China Sea, and become important (greater than 30 %) further downwind. We find that the seasonality of nitrogen deposition to the northwestern Pacific is determined by variations in meteorology largely controlled by the East Asian monsoon and in nitrogen emissions. The model adjoint further estimates that nitrogen deposition to the Yellow Sea originates from sources over China (92 % contribution) and the Korean peninsula (7 %), and by sectors from fertilizer use (24 %), power plants (22 %), and transportation (18 %). Deposition to the South China Sea shows source contribution from mainland China (66 %), Taiwan (20 %), and the rest (14 %) from the southeast Asian countries and oceanic NH3 emissions. The adjoint analyses also indicate that reducing Asian NH3 emissions would increase NOy dry deposition to the Yellow Sea (28 % offset annually), limiting the effectiveness of NH3 emission controls on reducing nitrogen deposition to the Yellow Sea.

  1. Atmospheric nitrogen deposition to the northwestern Pacific: seasonal variation and source attribution

    NASA Astrophysics Data System (ADS)

    Zhao, Yuanhong; Zhang, Lin; Pan, Yuepeng; Wang, Yuesi; Paulot, Fabien; Henze, Daven

    2016-04-01

    Rapid Asian industrialization has lead to increased atmospheric nitrogen deposition downwind threatening the marine environment. We present an analysis of the sources and processes controlling atmospheric nitrogen deposition to the northwestern Pacific, using the GEOS-Chem global chemistry model and its adjoint model at 1/2°× 2/3° horizontal resolution over the East Asia and its adjacent oceans. We focus our analyses on the marginal seas: the Yellow Sea and the South China Sea. Asian nitrogen emissions in the model are 28.6 Tg N a-1 as NH3 and 15.7 Tg N a-1 as NOx. China has the largest sources with 12.8 Tg N a-1 as NH3 and 7.9 Tg N a-1 as NOx; the much higher NH3 emissions reflect its intensive agricultural activities. We improve the seasonality of Asian NH3 emissions; emissions are a factor of 3 higher in summer than winter. The model simulation for 2008-2010 is evaluated with NH3 and NO2 column observations from satellite instruments, and wet deposition flux measurements from surface monitoring sites. Simulated atmospheric nitrogen deposition to the northwestern Pacific ranges 0.8-20 kg N ha-1 a-1, decreasing rapidly downwind the Asian continent. Deposition fluxes average 11.9 kg N ha-1 a-1 (5.0 as reduced nitrogen NHx and 6.9 as oxidized nitrogen NOy) to the Yellow Sea, and 5.6 kg N ha-1 a-1 (2.5 as NHx and 3.1 as NOy) to the South China Sea. Nitrogen sources over the ocean (ship NOx and oceanic NH3) have little contribution to deposition over the Yellow Sea, about 7% over the South China Sea, and become important (greater than 30%) further downwind. We find that the seasonality of nitrogen deposition to the northwestern Pacific is determined by variations in meteorology largely controlled by the East Asian Monsoon and in nitrogen emissions. The model adjoint further points out that nitrogen deposition to the Yellow Sea originates from sources over China (92% contribution) and the Korean peninsula (7%), and by sectors from fertilizer use (24%), power plants (22%), and transportation (18%). Deposition to the South China Sea shows source contribution from Mainland China (64%), Taiwan (21%), and the rest 15% from the Southeast Asian countries and oceanic NH3 emissions. The adjoint analyses also indicate that reducing Asian NH3 emissions would increase NOy dry deposition to the Yellow Sea (28% offset annually), limiting the effectiveness of NH3 emission controls.

  2. A regional chemical transport modeling to identify the influences of biomass burning during 2006 BASE-ASIA

    NASA Astrophysics Data System (ADS)

    Fu, J. S.; Hsu, N. C.; Gao, Y.; Huang, K.; Li, C.; Lin, N.-H.; Tsay, S.-C.

    2011-01-01

    To evaluate the impact of biomass burning from Southeast Asia to East Asia, this study conducted numerical simulations during NASA's 2006 Biomass-burning Aerosols in South-East Asia: Smoke Impact Assessment (BASE-ASIA). Two typical episode periods (27-28 March and 13-14 April) were examined. Two emission inventories, FLAMBE and GFED, were used in the simulations. The influences during two episodes in the source region (Southeast Asia) contributed to CO, O3 and PM2.5 concentrations as high as 400 ppbv, 20 ppbv and 80 μg/m3, respectively. The perturbations with and without biomass burning of the above three species were in the range of 10 to 60%, 10 to 20% and 30 to 70%, respectively. The impact due to long-range transport could spread over the southeastern parts of East Asia and could reach about 160 to 360 ppbv, 8 to 18 ppbv and 8 to 64 μg/m3 on CO, O3 and PM2.5, respectively; the percentage impact could reach 20 to 50% on CO, 10 to 30% on O3, and as high as 70% on PM2.5. An impact pattern can be found in April, while the impact becomes slightly broader and goes up to Yangtze River Delta. Two cross-sections at 15° N and 20° N were used to compare the vertical flux of biomass burning. In the source region (Southeast Asia), CO, O3 and PM2.5 concentrations had a strong upward tendency from surface to high altitudes. The eastward transport becomes strong from 2 to 8 km in the free troposphere. The subsidence contributed 60 to 70%, 20 to 50%, and 80% on CO, O3 and PM2.5, respectively to surface in the downwind area. The study reveals the significant impact of Southeastern Asia biomass burning on the air quality in both local and downwind areas, particularly during biomass burning episodes. This modeling study might provide constraints of lower limit. An additional study is underway for an active biomass burning year to obtain an upper limit and climate effects.

  3. Areal distribution, thickness, mass, volume, and grain size of tephra-fall deposits from the 1992 eruptions of Crater Peak vent, Mt. Spurr Volcano, Alaska

    USGS Publications Warehouse

    McGimsey, Robert G.; Neal, Christina A.; Riley, Colleen M.

    2001-01-01

    The Crater Peak flank vent of Mount Spurr volcano erupted June 27, August 18, and September 16-17, 1992. The three eruptions were similar in intensity (vulcanian to subplinian eruption columns reaching up to 14 km Above Sea Level) and duration (3.5 to 4.0 hours) and produced tephra-fall deposits (12, 14, 15 x 106 m3 Dense Rock Equivalent [DRE]) discernible up to 1,000 km downwind. The June 27 ash cloud traveled north over the rugged, ice- and snow-covered Alaska Range. The August 18 ash cloud was carried southeastward over Anchorage, across Prince William Sound, and down the southeastern shoreline of the Gulf of Alaska. The September 16-17 ash plume was directed eastward over the Talkeetna and Wrangell mountains and into the Yukon Territory of Canada. Over 50 mass-per-unit-area (MPUA) samples were collected for each of the latter two fall deposits at distances ranging from about 2 km to 370 km downwind from the volcano. Only 10 (mostly proximal) samples were collected for the June fall deposit due to inaccessible terrain and funding constraints. MPUA data were plotted and contoured (isomass lines) to graphically display the distribution of each fall deposit. For the August and September eruptions, fallout was concentrated along a narrow (30 to 50 km wide) belt. The fallout was most concentrated (100,000 to greater than 250,000 g/m2) within about 80 km of the volcano. Secondary maxima occur at 200 km (2,620 g/m2) and 300 km (4,659 g/m2), respectively, down axis for the August and September deposits. The maxima contain bimodal grain size distributions (with peaks at 88.4 and 22.1 microns) indicating aggregation within the ash cloud. Combined tephra-volume for the 1992 Mount Spurr eruptions (41 x 106 m3 DRE) is comparable to that (tephra-fall only) of the 1989-90 eruptions of nearby Redoubt volcano (31-49 x 106 m3 DRE).

  4. Trajectory optimization study of a lifting body re-entry vehicle for medium to intermediate range applications

    NASA Astrophysics Data System (ADS)

    Rizvi, S. Tauqeer ul Islam; Linshu, He; ur Rehman, Tawfiq; Rafique, Amer Farhan

    2012-11-01

    A numerical optimization study of lifting body re-entry vehicles is presented for nominal as well as shallow entry conditions for Medium and Intermediate Range applications. Due to the stringent requirement of a high degree of accuracy for conventional vehicles, lifting re-entry can be used to attain the impact at the desired terminal flight path angle and speed and thus can potentially improve accuracy of the re-entry vehicle. The re-entry of a medium range and intermediate range vehicles is characterized by very high negative flight path angle and low re-entry speed as compared to a maneuverable re-entry vehicle or a common aero vehicle intended for an intercontinental range. Highly negative flight path angles at the re-entry impose high dynamic pressure as well as heat loads on the vehicle. The trajectory studies are carried out to maximize the cross range of the re-entry vehicle while imposing a maximum dynamic pressure constraint of 350 KPa with a 3 MW/m2 heat rate limit. The maximum normal acceleration and the total heat load experienced by the vehicle at the stagnation point during the maneuver have been computed for the vehicle for possible future conceptual design studies. It has been found that cross range capability of up to 35 km can be achieved with a lifting-body design within the heat rate and the dynamic pressure boundary at normal entry conditions. For shallow entry angle of -20 degree and intermediate ranges a cross range capability of up to 250 km can be attained for a lifting body design with less than 10 percent loss in overall range. The normal acceleration also remains within limits. The lifting-body results have also been compared with wing-body results at shallow entry condition. An hp-adaptive pseudo-spectral method has been used for constrained trajectory optimization.

  5. JPRS Report, China

    DTIC Science & Technology

    1987-12-31

    inconsistent with Japan’s declared policy of opening up her markets. JPRS-CAR-87-061 31 December 1987 28 ECONOMIC 2. The "three lows "— low oil prices, the...intermediate- range warheads in Soviet Asia and the United States, respectively. But the United States and some Western European nations soon demanded...Union insisted on keeping 100 intermediate- range guided missiles in Asia while balking at the U.S. demand that it be allowed to deploy an equal

  6. Quantification of greenhouse gas (GHG) emissions from wastewater treatment plants using a ground-based remote sensing approach

    NASA Astrophysics Data System (ADS)

    Delre, Antonio; Mønster, Jacob; Scheutz, Charlotte

    2016-04-01

    The direct release of nitrous oxide (N2O) and methane (CH4) from wastewater treatment plants (WWTP) is important because it contributes to the global greenhouse gases (GHGs) release and strongly effects the WWTP carbon footprint. Biological nitrogen removal technologies could increase the direct emission of N2O (IPCC, 2006), while CH4 losses are of environmental, economic and safety concern. Currently, reporting of N2O and CH4 emissions from WWTPs are performed mainly using methods suggested by IPCC which are not site specific (IPCC, 2006). The dynamic tracer dispersion method (TDM), a ground based remote sensing approach implemented at DTU Environment, was demonstrated to be a novel and successful tool for full-scale CH4 and N2O quantification from WWTPs. The method combines a controlled release of tracer gas from the facility with concentration measurements downwind of the plant (Mønster et al., 2014; Yoshida et al., 2014). TDM in general is based on the assumption that a tracer gas released at an emission source, in this case a WWTP, disperses into the atmosphere in the same way as the GHG emitted from process units. Since the ratio of their concentrations remains constant along their atmospheric dispersion, the GHG emission rate can be calculated using the following expression when the tracer gas release rate is known: EGHG=Qtr*(CGHG/Ctr)*(MWGHG/MWtr) EGHG is the GHG emission in mass per time, Qtr is the tracer release in mass per time, CGHG and Ctr are the concentrations measured downwind in parts per billion subtracted of their background values and integrated over the whole plume, and MWGHG and MWtr are the molar weights of GHG and tracer gas respectively (Mønster et al. 2014). In this study, acetylene (C2H2) was used as tracer. Downwind plume concentrations were measured driving along transects with two cavity ring down spectrometers (Yoshida et al., 2014). TDM was successfully applied in different seasons at several Scandinavian WWTPs characterized by different capacity, process unit technologies and locations. The method was applied at plants with different combination of nitrogen removal technologies and sewage sludge treatment. According to the plant capacity and technologies, quantified emissions ranged in the following intervals: from 0.7 to 3.4 kg N2O/h and from 1.1 to 17.6 kg CH4/h. In addition to quantifying the whole emission from the facilities, main sources in the plants were identified. While CH4 was generally emitted from sludge treatment areas, N2O was detected from nitrogen removal technologies both in the main stream and in the side treatment. Process units like biosolids storage and aeration tanks were the only units releasing both GHGs, although in different magnitude. References IPCC, 2006. Guidelines for National Greenhouse Gas Inventories, Volume 5 - Waste. Mønster, J., Samuelsson, J., Kjeldsen, P., Rella, C.W., Scheutz, C., 2014. Quantifying methane emission from fugitive sources by combining tracer release and downwind measurements - a sensitivity analysis based on multiple field surveys. Waste Manag. 34, 1416-28. doi:10.1016/j.wasman.2014.03.025 Yoshida, H., Mønster, J., Scheutz, C., 2014. Plant-integrated measurement of greenhouse gas emissions from a municipal wastewater treatment plant. Water Res. 1, 108-118. doi:10.1016/j.watres.2014.05.014

  7. Propylene oxidation mechanisms and intermediates using in situ soft X-ray fluorescence methods on the Pt(111) surface

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gabelnick, A.M.; Capitano, A.T.; Kane, S.M.

    2000-01-12

    The oxidation of propylene preabsorbed on the Pt(111) surface has been characterized in oxygen pressures up to 0.02 Torr using fluorescence yield near-edge spectroscopy (FYNES) and temperature-programmed fluorescence yield near-edge spectroscopy (TP-FYNES) above the carbon K edge. During oxidation of adsorbed propylene, a stable intermediate was observed and characterized using these soft X-ray methods. A general in situ method for determining the stoichiometry of carbon-containing reaction intermediate species has been developed and demonstrated for the first time. Total carbon concentration measured during temperature-programmed reaction studies clearly indicates a reaction intermediate is formed in the 300 K temperature range with amore » surface concentration of 0.55 x 10{sup 15} carbon atoms/cm{sup 2}. By comparing the intensity of the C-H {sigma}* resonance at the magic angle with the intensity in the carbon continuum, the stoichiometry of this intermediate can be determined unambiguously. Based on calibration with molecular propylene (C{sub 3}H{sub 6}) and propylidyne (C{sub 3}H{sub 5}), the intermediate has a C{sub 3}H{sub 5} stoichiometry for oxygen pressures up to 0.02 Torr. A set of normal and glancing angle FYNES spectra above the carbon K edge was used to characterize the bonding and structure of this intermediate. Spectra of known coverages of adsorbed propylene and propylidyne served as standards. The spectra of di-{sigma} propylene, propylidyne, and the intermediate were curve fit as a group with consistent energies and widths of all primary features. Based on this procedure, the intermediate is 1,1,2-tri-{sigma} 1-methylvinyl. The stoichiometry and temperature stability range of the 1-methylvinyl intermediate formed in oxygen pressures up to 0.02 Torr is identical with the stoichiometry and stability of the same intermediate formed during oxidation of preadsorbed propylene by excess coadsorbed atomic oxygen.« less

  8. Does the range of IMF affect rise and fall trend in fragmentation?

    NASA Astrophysics Data System (ADS)

    Sharma, Sakshi; Kumar, Rohit; Puri, Rajeev K.

    2018-05-01

    We study the rise and fall behavior in the multiplicity of intermediate mass fragments produced in the asymmetric reactions of 36S+ 198Pt using isospin-dependent quantum molecular dynamics model. We use different definitions of intermediate mass fragments according to various experimental studies. We find that the use of one or the other definition of intermediate mass fragments does not alter results significantly.

  9. The INF (Intermediate-Range Nuclear Forces) Controversy: A Confluence of Foreign and Domestic Interests.

    DTIC Science & Technology

    1986-09-01

    AD-R175 303 THE INF (INTERMEDIRTE-RANSE NUCLEAR FORCES) 1/2 CONTROVERSY: A CONFLUENCE OF FOREIGN AND DOMESTIC INTERESTS(U) NAVAL POSTGRADUATE SCHOOL...on reverse if necessary and identify by block number) F:ELD I GROUP SUB-GROUP INF (Intermediate-Range Nuclear Forces, NATO, European Nuclear Capability...the United Kingdom, and several non- nuclear members of 14ATO are examined and analyzed. The analysis is concerned with alliance and transnational

  10. Respirable dust measured downwind during rock dust application.

    PubMed

    Harris, M L; Organiscak, J; Klima, S; Perera, I E

    2017-05-01

    The Pittsburgh Mining Research Division of the U.S. National Institute for Occupational Safety and Health (NIOSH) conducted underground evaluations in an attempt to quantify respirable rock dust generation when using untreated rock dust and rock dust treated with an anticaking additive. Using personal dust monitors, these evaluations measured respirable rock dust levels arising from a flinger-type application of rock dust on rib and roof surfaces. Rock dust with a majority of the respirable component removed was also applied in NIOSH's Bruceton Experimental Mine using a bantam duster. The respirable dust measurements obtained downwind from both of these tests are presented and discussed. This testing did not measure miners' exposure to respirable coal mine dust under acceptable mining practices, but indicates the need for effective continuous administrative controls to be exercised when rock dusting to minimize the measured amount of rock dust in the sampling device.

  11. Downwind effects on an arid dunefield from an evolving urbanised area

    NASA Astrophysics Data System (ADS)

    Hernández-Calvento, L.; Jackson, D. W. T.; Medina, R.; Hernández-Cordero, A. I.; Cruz, N.; Requejo, S.

    2014-12-01

    The impacts of urbanised zones on aeolian dynamics are little understood, particularly within arid areas. This study examines the large-scale influence of a growing tourist resort in Gran Canaria Island, Spain, on the sedimentary dynamics of an arid dunefield. Direct downwind effects from the urban area on the dune field surface are modelled for pre-growth and post-growth phases of the urban development. The geomorphological changes observed in the area stretching from the shoreline to the inland transgressive dune field were documented through aerial photographic and LiDAR evidence. Impacts of the urban growth on airflow, as well as those induced by tourists in the upper beach zone (de-vegetation), are examined through analysis of topographic changes. These impacts on the system are shown to have been synergistic in driving the development of a composite dune ridge, formed by the coalescence of smaller dunes into a distinctive aeolian accumulation ridge.

  12. Slip Face on Downwind Side of Namib Sand Dune on Mars

    NASA Image and Video Library

    2016-01-04

    This view from NASA's Curiosity Mars Rover shows the downwind side of "Namib Dune," which stands about 13 feet (4 meters) high. The site is part of Bagnold Dunes, a band of dark sand dunes along the northwestern flank of Mars' Mount Sharp. The component images stitched together into this scene were taken with Curiosity's Navigation Camera (Navcam) on Dec. 17, 2015, during the 1,196th Martian day, or sol, of the rover's work on Mars. In late 2015 and early 2016, Curiosity is conducting the first up-close studies ever made of active sand dunes anywhere but on Earth. Under the influence of Martian wind, the Bagnold Dunes are migrating up to about one yard or meter per Earth year. The view spans from westward on the left to east-southeastward on the right. It is presented as a cylindrical perspective projection. http://photojournal.jpl.nasa.gov/catalog/PIA20281

  13. Downwind Side of Namib Sand Dune on Mars, Stereo

    NASA Image and Video Library

    2016-01-04

    This stereo view from NASA's Curiosity Mars Rover shows the downwind side of "Namib Dune," which stands about 13 feet (4 meters) high. The image appears three-dimensional when viewed through red-blue glasses with the red lens on the left. The site is part of Bagnold Dunes, a band of dark sand dunes along the northwestern flank of Mars' Mount Sharp. The component images stitched together into this scene were taken with Curiosity's Navigation Camera (Navcam) on Dec. 17, 2015, during the 1,196th Martian day, or sol, of the rover's work on Mars. In late 2015 and early 2016, Curiosity is conducting the first up-close studies ever made of active sand dunes anywhere but on Earth. Under the influence of Martian wind, the Bagnold Dunes are migrating up to about one yard or meter per Earth year. http://photojournal.jpl.nasa.gov/catalog/PIA20282

  14. Dynamic calibration of fast-response probes in low-pressure shock tubes

    NASA Astrophysics Data System (ADS)

    Persico, G.; Gaetani, P.; Guardone, A.

    2005-09-01

    Shock tube flows resulting from the incomplete burst of the diaphragm are investigated in connection with the dynamic calibration of fast-response pressure probes. As a result of the partial opening of the diaphragm, pressure disturbances are observed past the shock wave and the measured total pressure profile deviates from the envisaged step signal required by the calibration process. Pressure oscillations are generated as the initially normal shock wave diffracts from the diaphragm's orifice and reflects on the shock tube walls, with the lowest local frequency roughly equal to the ratio of the sound speed in the perturbed region to the shock tube diameter. The energy integral of the perturbations decreases with increasing distance from the diaphragm, as the diffracted leading shock and downwind reflections coalesce into a single normal shock. A procedure is proposed to calibrate fast-response pressure probes downwind of a partially opened shock tube diaphragm.

  15. Wake Vortex Transport in Proximity to the Ground

    NASA Technical Reports Server (NTRS)

    Hamilton, David W.; Proctor, Fred H.

    2000-01-01

    A sensitivity study for aircraft wake vortex transport has been conducted using a validated large eddy simulation (LES) model. The study assumes neutrally stratified and nonturbulent environments and includes the consequences of the ground. The numerical results show that the nondimensional lateral transport is primarily influenced by the magnitude of the ambient crosswind and is insensitive to aircraft type. In most of the simulations, the ground effect extends the lateral position of the downwind vortex about one initial vortex spacing (b(sub o)) in the downstream direction. Further extension by as much as one b(sub o) occurs when the downwind vortex remains 'in ground effect' (IGE) for relatively long periods of time. Results also show that a layer-averaged ambient wind velocity can be used to bound the time for lateral transport of wake vortices to insure safe operations on a parallel runway.

  16. Estimating the volcanic emission rate and atmospheric lifetime of SO2 from space: a case study for Kīlauea volcano, Hawai'i

    USGS Publications Warehouse

    Beirle, Steffen; Hörmann, Christoph; Penning de Vries, Malouse; Dörner, Stefan; Kern, Christoph; Wagner, Thomas

    2014-01-01

    We present an analysis of SO2 column densities derived from GOME-2 satellite measurements for the Kīlauea volcano (Hawai`i) for 2007–2012. During a period of enhanced degassing activity in March–November 2008, monthly mean SO2 emission rates and effective SO2 lifetimes are determined simultaneously from the observed downwind plume evolution and meteorological wind fields, without further model input. Kīlauea is particularly suited for quantitative investigations from satellite observations owing to the absence of interfering sources, the clearly defined downwind plumes caused by steady trade winds, and generally low cloud fractions. For March–November 2008, the effective SO2 lifetime is 1–2 days, and Kīlauea SO2 emission rates are 9–21 kt day−1, which is about 3 times higher than initially reported from ground-based monitoring systems.

  17. Particle size distribution of airborne Aspergillus fumigatus spores emitted from compost using membrane filtration

    NASA Astrophysics Data System (ADS)

    Deacon, L. J.; Pankhurst, L. J.; Drew, G. H.; Hayes, E. T.; Jackson, S.; Longhurst, P. J.; Longhurst, J. W. S.; Liu, J.; Pollard, S. J. T.; Tyrrel, S. F.

    Information on the particle size distribution of bioaerosols emitted from open air composting operations is valuable in evaluating potential health impacts and is a requirement for improved dispersion simulation modelling. The membrane filter method was used to study the particle size distribution of Aspergillus fumigatus spores in air 50 m downwind of a green waste compost screening operation at a commercial facility. The highest concentrations (approximately 8 × 10 4 CFU m -3) of culturable spores were found on filters with pore diameters in the range 1-2 μm which suggests that the majority of spores are emitted as single cells. The findings were compared to published data collected using an Andersen sampler. Results were significantly correlated ( p < 0.01) indicating that the two methods are directly comparable across all particles sizes for Aspergillus spores.

  18. Pulse homodyne field disturbance sensor

    DOEpatents

    McEwan, Thomas E.

    1997-01-01

    A field disturbance sensor operates with relatively low power, provides an adjustable operating range, is not hypersensitive at close range, allows co-location of multiple sensors, and is inexpensive to manufacture. The sensor includes a transmitter that transmits a sequence of transmitted bursts of electromagnetic energy. The transmitter frequency is modulated at an intermediate frequency. The sequence of bursts has a burst repetition rate, and each burst has a burst width and comprises a number of cycles at a transmitter frequency. The sensor includes a receiver which receives electromagnetic energy at the transmitter frequency, and includes a mixer which mixes a transmitted burst with reflections of the same transmitted burst to produce an intermediate frequency signal. Circuitry, responsive to the intermediate frequency signal indicates disturbances in the sensor field. Because the mixer mixes the transmitted burst with reflections of the transmitted burst, the burst width defines the sensor range. The burst repetition rate is randomly or pseudo-randomly modulated so that bursts in the sequence of bursts have a phase which varies. A second range-defining mode transmits two radio frequency bursts, where the time spacing between the bursts defines the maximum range divided by two.

  19. Pulse homodyne field disturbance sensor

    DOEpatents

    McEwan, T.E.

    1997-10-28

    A field disturbance sensor operates with relatively low power, provides an adjustable operating range, is not hypersensitive at close range, allows co-location of multiple sensors, and is inexpensive to manufacture. The sensor includes a transmitter that transmits a sequence of transmitted bursts of electromagnetic energy. The transmitter frequency is modulated at an intermediate frequency. The sequence of bursts has a burst repetition rate, and each burst has a burst width and comprises a number of cycles at a transmitter frequency. The sensor includes a receiver which receives electromagnetic energy at the transmitter frequency, and includes a mixer which mixes a transmitted burst with reflections of the same transmitted burst to produce an intermediate frequency signal. Circuitry, responsive to the intermediate frequency signal indicates disturbances in the sensor field. Because the mixer mixes the transmitted burst with reflections of the transmitted burst, the burst width defines the sensor range. The burst repetition rate is randomly or pseudo-randomly modulated so that bursts in the sequence of bursts have a phase which varies. A second range-defining mode transmits two radio frequency bursts, where the time spacing between the bursts defines the maximum range divided by two. 12 figs.

  20. The changing relationship between HbA1c and FPG according to different FPG ranges.

    PubMed

    Guan, X; Zheng, L; Sun, G; Guo, X; Li, Y; Song, H; Tian, F; Sun, Y

    2016-05-01

    Since the American Diabetes Association included hemoglobin A1c (HbA1c) in the diagnostic criteria for diabetes in 2010, the clinical use of HbA1c has remained controversial. We explored the use of HbA1c for diagnosing diabetes and intermediate hyperglycemia in comparison with fasting plasma glucose (FPG). We screened 3710 adult subjects (mean age = 55.24 years) comprising 1704 males and 2006 females. We drew an receiver operating characteristic (ROC) curve to evaluate the ability of HbA1c to diagnose diabetes and intermediate hyperglycemia according to FPG. We used Kappa coefficient and Pearson's correlation coefficient to evaluate the relationship between HbA1c and FPG in different FPG ranges. The areas under ROC curve to diagnose diabetes and intermediate hyperglycemia were 0.859 (95 % CI 0.827-0.892) and 0.633 (95 % CI 0.615-0.651). The kappa coefficients between FPG and HbA1c for diagnosis of diabetes and intermediate hyperglycemia were 0.601 (P < 0.001) and 0.104 (P < 0.001). The Pearson's correlation coefficient of FPG and HbA1c was 0.640 (P < 0.001), but when we classified FPG as normal, intermediate hyperglycemia and diabetes, the coefficients became 0.07 (P = 0.002), 0.185 (P < 0.001) and 0.760 (P < 0.001), respectively. The relationship between HbA1c and FPG changed according to the different FPG ranges. When FPG was higher, the relationship was stronger. HbA1c and FPG were highly consistent in diagnosing diabetes, but they were not in predicting intermediate hyperglycemia.

  1. Intermediate selectivity in the oxidation of phenols using plasmonic Au/ZnO photocatalysts

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lin, Feng; Cojocaru, Bogdan E.; Williams, Luke S.

    Tunable reaction selectivity on a single catalyst is a continual goal in chemical syntheses. Herein, we report an unexpected light-directed intermediate selectivity using well-known plasmonic photocatalysts. We observed distinct intermediate selectivity behaviors between using UV and visible light irradiations. Chemical computations and quenching experiments suggest that the radicals generated by the plasmonic excitation govern the light-directed selectivity. As a result, the broader impact of this work ranges from selective yield of desirable intermediates for subsequent syntheses without tedious separation procedures, to arousing interest in examining new opportunities for plasmonic photocatalysts.

  2. Intermediate selectivity in the oxidation of phenols using plasmonic Au/ZnO photocatalysts

    DOE PAGES

    Lin, Feng; Cojocaru, Bogdan E.; Williams, Luke S.; ...

    2017-06-20

    Tunable reaction selectivity on a single catalyst is a continual goal in chemical syntheses. Herein, we report an unexpected light-directed intermediate selectivity using well-known plasmonic photocatalysts. We observed distinct intermediate selectivity behaviors between using UV and visible light irradiations. Chemical computations and quenching experiments suggest that the radicals generated by the plasmonic excitation govern the light-directed selectivity. As a result, the broader impact of this work ranges from selective yield of desirable intermediates for subsequent syntheses without tedious separation procedures, to arousing interest in examining new opportunities for plasmonic photocatalysts.

  3. Evidence for a Shared Mechanism in the Formation of Urea-Induced Kinetic and Equilibrium Intermediates of Horse Apomyoglobin from Ultrarapid Mixing Experiments

    PubMed Central

    Mizukami, Takuya; Abe, Yukiko; Maki, Kosuke

    2015-01-01

    In this study, the equivalence of the kinetic mechanisms of the formation of urea-induced kinetic folding intermediates and non-native equilibrium states was investigated in apomyoglobin. Despite having similar structural properties, equilibrium and kinetic intermediates accumulate under different conditions and via different mechanisms, and it remains unknown whether their formation involves shared or distinct kinetic mechanisms. To investigate the potential mechanisms of formation, the refolding and unfolding kinetics of horse apomyoglobin were measured by continuous- and stopped-flow fluorescence over a time range from approximately 100 μs to 10 s, along with equilibrium unfolding transitions, as a function of urea concentration at pH 6.0 and 8°C. The formation of a kinetic intermediate was observed over a wider range of urea concentrations (0–2.2 M) than the formation of the native state (0–1.6 M). Additionally, the kinetic intermediate remained populated as the predominant equilibrium state under conditions where the native and unfolded states were unstable (at ~0.7–2 M urea). A continuous shift from the kinetic to the equilibrium intermediate was observed as urea concentrations increased from 0 M to ~2 M, which indicates that these states share a common kinetic folding mechanism. This finding supports the conclusion that these intermediates are equivalent. Our results in turn suggest that the regions of the protein that resist denaturant perturbations form during the earlier stages of folding, which further supports the structural equivalence of transient and equilibrium intermediates. An additional folding intermediate accumulated within ~140 μs of refolding and an unfolding intermediate accumulated in <1 ms of unfolding. Finally, by using quantitative modeling, we showed that a five-state sequential scheme appropriately describes the folding mechanism of horse apomyoglobin. PMID:26244984

  4. Method for ambiguity resolution in range-Doppler measurements

    NASA Technical Reports Server (NTRS)

    Heymsfield, Gerald M. (Inventor); Miller, Lee S. (Inventor)

    1994-01-01

    A method for resolving range and Doppler target ambiguities when the target has substantial range or has a high relative velocity in which a first signal is generated and a second signal is also generated which is coherent with the first signal but at a slightly different frequency such that there exists a difference in frequency between these two signals of Delta f(sub t). The first and second signals are converted into a dual-frequency pulsed signal, amplified, and the dual-frequency pulsed signal is transmitted towards a target. A reflected dual-frequency signal is received from the target, amplified, and changed to an intermediate dual-frequency signal. The intermediate dual-frequency signal is amplified, with extracting of a shifted difference frequency Delta f(sub r) from the amplified intermediate dual-frequency signal done by a nonlinear detector. The final step is generating two quadrature signals from the difference frequency Delta f(sub t) and the shifted difference frequency Delta f(sub r) and processing the two quadrature signals to determine range and Doppler information of the target.

  5. The Composite Effect of Transgenic Plant Volatiles for Acquired Immunity to Herbivory Caused by Inter-Plant Communications

    PubMed Central

    Muroi, Atsushi; Ramadan, Abdelaziz; Nishihara, Masahiro; Yamamoto, Masaki; Ozawa, Rika; Takabayashi, Junji; Arimura, Gen-ichiro

    2011-01-01

    A blend of volatile organic compounds (VOCs) emitted from plants induced by herbivory enables the priming of defensive responses in neighboring plants. These effects may provide insights useful for pest control achieved with transgenic-plant-emitted volatiles. We therefore investigated, under both laboratory and greenhouse conditions, the priming of defense responses in plants (lima bean and corn) by exposing them to transgenic-plant-volatiles (VOCos) including (E)-β-ocimene, emitted from transgenic tobacco plants (NtOS2) that were constitutively overexpressing (E)-β-ocimene synthase. When lima bean plants that had previously been placed downwind of NtOS2 in an open-flow tunnel were infested by spider mites, they were more defensive to spider mites and more attractive to predatory mites, in comparison to the infested plants that had been placed downwind of wild-type tobacco plants. This was similarly observed when the NtOS2-downwind maize plants were infested with Mythimna separata larvae, resulting in reduced larval growth and greater attraction of parasitic wasps (Cotesia kariyai). In a greenhouse experiment, we also found that lima bean plants (VOCos-receiver plants) placed near NtOS2 were more attractive when damaged by spider mites, in comparison to the infested plants that had been placed near the wild-type plants. More intriguingly, VOCs emitted from infested VOCos-receiver plants affected their conspecific neighboring plants to prime indirect defenses in response to herbivory. Altogether, these data suggest that transgenic-plant-emitted volatiles can enhance the ability to prime indirect defenses via both plant-plant and plant-plant-plant communications. PMID:22022359

  6. The composite effect of transgenic plant volatiles for acquired immunity to herbivory caused by inter-plant communications.

    PubMed

    Muroi, Atsushi; Ramadan, Abdelaziz; Nishihara, Masahiro; Yamamoto, Masaki; Ozawa, Rika; Takabayashi, Junji; Arimura, Gen-ichiro

    2011-01-01

    A blend of volatile organic compounds (VOCs) emitted from plants induced by herbivory enables the priming of defensive responses in neighboring plants. These effects may provide insights useful for pest control achieved with transgenic-plant-emitted volatiles. We therefore investigated, under both laboratory and greenhouse conditions, the priming of defense responses in plants (lima bean and corn) by exposing them to transgenic-plant-volatiles (VOCos) including (E)-β-ocimene, emitted from transgenic tobacco plants (NtOS2) that were constitutively overexpressing (E)-β-ocimene synthase. When lima bean plants that had previously been placed downwind of NtOS2 in an open-flow tunnel were infested by spider mites, they were more defensive to spider mites and more attractive to predatory mites, in comparison to the infested plants that had been placed downwind of wild-type tobacco plants. This was similarly observed when the NtOS2-downwind maize plants were infested with Mythimna separata larvae, resulting in reduced larval growth and greater attraction of parasitic wasps (Cotesia kariyai). In a greenhouse experiment, we also found that lima bean plants (VOCos-receiver plants) placed near NtOS2 were more attractive when damaged by spider mites, in comparison to the infested plants that had been placed near the wild-type plants. More intriguingly, VOCs emitted from infested VOCos-receiver plants affected their conspecific neighboring plants to prime indirect defenses in response to herbivory. Altogether, these data suggest that transgenic-plant-emitted volatiles can enhance the ability to prime indirect defenses via both plant-plant and plant-plant-plant communications.

  7. Sensitivity of two dispersion models (AERMOD and ISCST3) to input parameters for a rural ground-level area source.

    PubMed

    Faulkner, William B; Shaw, Bryan W; Grosch, Tom

    2008-10-01

    As of December 2006, the American Meteorological Society/U.S. Environmental Protection Agency (EPA) Regulatory Model with Plume Rise Model Enhancements (AERMOD-PRIME; hereafter AERMOD) replaced the Industrial Source Complex Short Term Version 3 (ISCST3) as the EPA-preferred regulatory model. The change from ISCST3 to AERMOD will affect Prevention of Significant Deterioration (PSD) increment consumption as well as permit compliance in states where regulatory agencies limit property line concentrations using modeling analysis. Because of differences in model formulation and the treatment of terrain features, one cannot predict a priori whether ISCST3 or AERMOD will predict higher or lower pollutant concentrations downwind of a source. The objectives of this paper were to determine the sensitivity of AERMOD to various inputs and compare the highest downwind concentrations from a ground-level area source (GLAS) predicted by AERMOD to those predicted by ISCST3. Concentrations predicted using ISCST3 were sensitive to changes in wind speed, temperature, solar radiation (as it affects stability class), and mixing heights below 160 m. Surface roughness also affected downwind concentrations predicted by ISCST3. AERMOD was sensitive to changes in albedo, surface roughness, wind speed, temperature, and cloud cover. Bowen ratio did not affect the results from AERMOD. These results demonstrate AERMOD's sensitivity to small changes in wind speed and surface roughness. When AERMOD is used to determine property line concentrations, small changes in these variables may affect the distance within which concentration limits are exceeded by several hundred meters.

  8. On Rainfall Modification by Major Urban Areas. Part 1; Observations from Space-borne Rain Radar Aboard TRMM

    NASA Technical Reports Server (NTRS)

    Shepherd, J. Marshell; Starr, David OC. (Technical Monitor)

    2001-01-01

    A novel approach is introduced to correlating urbanization and rainfall modification. This study represents one of the first published attempts (possibly the first) to identify and quantify rainfall modification by urban areas using satellite-based rainfall measurements. Previous investigations successfully used rain gauge networks and around-based radar to investigate this phenomenon but still encountered difficulties due to limited, specialized measurements and separation of topographic and other influences. Three years of mean monthly rainfall rates derived from the first space-based rainfall radar, Tropical Rainfall Measuring Mission's (TRMM) Precipitation Radar, are employed. Analysis of data at half-degree latitude resolution enables identification of rainfall patterns around major metropolitan areas of Atlanta, Montgomery, Nashville, San Antonio, Waco, and Dallas during the warm season. Preliminary results reveal an average increase of 5.6% in monthly rainfall rates (relative to a mean upwind CONTROL area) over the metropolis but an average increase of approx. 28%, in monthly rainfall rates within 30-60 kilometers downwind of the metropolis. Some portions of the downwind area exhibit increases as high as 51%. It was also found that maximum rainfall rates found in the downwind impact area exceeded the mean value in the upwind CONTROL area by 48%-116% and were generally found at an average distance of 39 km from the edge of the urban center or 64 km from the center of the city. These results are quite consistent studies of St. Louis (e.g' METROMEX) and Chicago almost two decades ago and more recent studies in the Atlanta and Mexico City areas.

  9. Effects of NOx control and plume mixing on nighttime chemical processing of plumes from coal-fired power plants

    NASA Astrophysics Data System (ADS)

    Brown, Steven S.; Dubé, William P.; Karamchandani, Prakash; Yarwood, Greg; Peischl, Jeff; Ryerson, Thomas B.; Neuman, J. Andrew; Nowak, John B.; Holloway, John S.; Washenfelder, Rebecca A.; Brock, Charles A.; Frost, Gregory J.; Trainer, Michael; Parrish, David D.; Fehsenfeld, Frederick C.; Ravishankara, A. R.

    2012-04-01

    Coal-fired electric power plants produce a large fraction of total U.S. NOx emissions, but NOx from this sector has been declining in the last decade owing to installation of control technology. Nighttime aircraft intercepts of plumes from two different Texas power plants (Oklaunion near Wichita Falls and W. A. Parish near Houston) with different control technologies demonstrate the effect of these reductions on nighttime NOxoxidation rates. The analysis shows that the spatial extent of nighttime-emitted plumes to be quite limited and that mixing of highly concentrated plume NOx with ambient ozone is a determining factor for its nighttime oxidation. The plume from the uncontrolled plant had full titration of ozone through 74 km/2.4 h of downwind transport that suppressed nighttime oxidation of NO2 to higher oxides of nitrogen across the majority of the plume. The plume from the controlled plant did not have sufficient NOx to titrate background ozone, which led to rapid nighttime oxidation of NO2 during downwind transport. A plume model that includes horizontal mixing and nighttime chemistry reproduces the observed structures of the nitrogen species in the plumes from the two plants. The model shows that NOx controls not only reduce the emissions directly but also lead to an additional overnight NOx loss of 36-44% on average. The maximum reduction for 12 h of transport in darkness was 73%. The results imply that power plant NOxemissions controls may produce a larger than linear reduction in next-day, downwind ozone production following nighttime transport.

  10. Chemical composition of wildland and agricultural biomass burning particles measured downwind during the BBOP study

    NASA Astrophysics Data System (ADS)

    Onasch, T. B.; Shilling, J. E.; Wormhoudt, J.; Sedlacek, A. J., III; Fortner, E.; Pekour, M. S.; Chand, D.; Zhou, S.; Collier, S.; Zhang, Q.; Kleinman, L. I.; Lewis, E. R.; Yokelson, R. J.; Adachi, K.; Buseck, P. R.; Freedman, A.; Williams, L. R.

    2017-12-01

    The Biomass Burning Observation Project (BBOP), a Department of Energy (DOE) sponsored study, measured emissions from wildland fires in the Pacific Northwest and agricultural burns in the Central Southeastern US from the DOE Gulfstream-1 airborne platform over a four month period in 2013. Rapid physical, chemical and optical changes in biomass burning particles were measured downwind (< 3 hours temporally) from wildland fires. The chemical composition of the particulate emissions was characterized using an Aerodyne Soot Particle Aerosol Mass Spectrometer (SP-AMS) and a Single Particle Soot Photometer (SP2) and the measurement results will be presented in the context of the fire location, combustion conditions, and optical property measurements, including extinction and single scattering albedos. The SP-AMS was operated with both laser and resistively heated tungsten vaporizers, alternating between laser on and off. With the laser vaporizer off, the instrument operated as a standard high resolution AMS. Under these sampling conditions, the non-refractory chemical composition, including the level of oxidation (i.e., O:C, H:C, and organic mass/organic carbon ratios, OM:OC), of the biomass burning particles was characterized as a function of the fuel type burned, modified combustion efficiency, and degree of oxidation during downwind transport. With the laser vaporizer on, the SP-AMS was also sensitive to the refractory black carbon (rBC) content, in addition to the non-refractory components. The chemical measurements will be correlated with simultaneous optical measurements. We will also present preliminary results from laboratory studies on tar balls and SP-AMS OA quantification while operating with both laser and tungsten vaporizers.

  11. Air toxics exposure from vehicle emissions at a U.S. border crossing: Buffalo Peace Bridge Study.

    PubMed

    Spengler, John; Lwebuga-Mukasa, Jamson; Vallarino, Jose; Melly, Steve; Chillrud, Steve; Baker, Joel; Minegishi, Taeko

    2011-07-01

    The Peace Bridge in Buffalo, New York, which spans the Niagara River at the east end of Lake Erie, is one of the busiest U.S. border crossings. The Peace Bridge plaza on the U.S. side is a complex of roads, customs inspection areas, passport control areas, and duty-free shops. On average 5000 heavy-duty diesel trucks and 20,000 passenger cars traverse the border daily, making the plaza area a potential "hot spot" for emissions from mobile sources. In a series of winter and summer field campaigns, we measured air pollutants, including many compounds considered by the U.S. Environmental Protection Agency (EPA*) as mobile-source air toxics (MSATs), at three fixed sampling sites: on the shore of Lake Erie, approximately 500 m upwind (under predominant wind conditions) of the Peace Bridge plaza; immediately downwind of (adjacent to) the plaza; and 500 m farther downwind, into the community of west Buffalo. Pollutants sampled were particulate matter (PM) < or = 10 microm (PM10) and < or = 2.5 microm (PM2.5) in aerodynamic diameter, elemental carbon (EC), 28 elements, 25 volatile organic compounds (VOCs) including 3 carbonyls, 52 polycyclic aromatic hydrocarbons (PAHs), and 29 nitrogenated polycyclic aromatic hydrocarbons (NPAHs). Spatial patterns of counts of ultrafine particles (UFPs, particles < 0.1 microm in aerodynamic diameter) and of particle-bound PAH (pPAH) concentrations were assessed by mobile monitoring in the neighborhood adjacent to the Peace Bridge plaza using portable instruments and Global Positioning System (GPS) tracking. The study was designed to assess differences in upwind and downwind concentrations of MSATs, in areas near the Peace Bridge plaza on the U.S. side of the border. The Buffalo Peace Bridge Study featured good access to monitoring locations proximate to the plaza and in the community, which are downwind with the dominant winds from the direction of Lake Erie and southern Ontario. Samples from the lakeside Great Lakes Center (GLC), which is upwind of the plaza with dominant winds, were used to characterize contaminants in regional air masses. On-site meteorologic measurements and hourly truck and car counts were used to assess the role of traffic on UFP counts and pPAH concentrations. The array of parallel and perpendicular residential streets adjacent to the plaza provided a grid on which to plot the spatial patterns of UFP counts and pPAH concentrations to determine the extent to which traffic emissions from the Peace Bridge plaza might extend into the neighboring community. For lake-wind conditions (southwest to northwest) 12-hour integrated daytime samples showed clear evidence that vehicle-related emissions at the Peace Bridge plaza were responsible for elevated downwind concentrations of PM2.5, EC, and benzene, toluene, ethylbenzene, and xylenes (BTEX), as well as 1,3-butadiene and styrene. The chlorinated VOCs and aldehydes were not differentially higher at the downwind site. Several metals (aluminum, calcium, iron, copper, and antimony) were two times higher at the site adjacent to the plaza as they were at the upwind GLC site on lake-wind sampling days. Other metals (beryllium, sodium, magnesium, potassium, titanium, manganese, cobalt, strontium, tin, cesium, and lanthanum) showed significant increases downwind as well. Sulfur, arsenic, selenium, and a few other elements appeared to be markers for regional transport as their upwind and downwind concentrations were correlated, with ratios near unity. Using positive matrix factorization (PMF), we identified the sources for PAHs at the three fixed sampling sites as regional, diesel, general vehicle, and asphalt volatilization. Diesel exhaust at the Peace Bridge plaza accounted for approximately 30% of the PAHs. The NPAH sources were identified as nitrate (NO3) radical reactions, diesel, and mixed sources. Diesel exhaust at the Peace Bridge plaza accounted for 18% of the NPAHs. Further evidence for the impact of the Peace Bridge plaza on local air quality was found when the differences in 10-minute average UFP counts and pPAH concentrations were calculated between pairs of sites and displayed by wind direction. With winds from approximately 160 degrees through 220 degrees, UFP counts adjacent to the plaza were 10,000 to 20,000 particles/cm3 higher than those upwind of the plaza. A similar pattern was displayed for pPAH concentrations adjacent to the plaza, which were between 10 and 20 ng/m3 higher than those at the upwind GLC site. Regression models showed better correlation with traffic variables for pPAHs than for UFPs. For pPAHs, truck counts and car counts had significant positive correlations, with similar magnitudes for the effects of trucks and cars, despite lower truck counts. Examining all traffic variables, including traffic counts and counts divided by wind speed, the multivariate regression analysis had an adjusted coefficient of determination (R2) of 0.34 for pPAHs, with all terms significant at P < 0.002. Study staff members traversed established routes in the neighborhood while carrying instruments to record continuous UFP and pPAH values. They also carried a GPS, which was used to provide location-specific time-stamped data. Analyses using a geographic information system (GIS) demonstrated that emissions at the Peace Bridge plaza, at times, affected ambient air quality over several blocks (a few hundred meters). Under lake-wind conditions, overall spatial patterns in UFP and pPAH levels were similar for summer and winter and for morning and afternoon sampling sessions. The Buffalo Peace Bridge Study demonstrated that a concentration of motor vehicles resulted in elevated levels of mobile-source-related emissions downwind, to distances of 300 m to 600 m. The study provides a unique data set to assess interrelationships among MSATs and to ascertain the impact of heavy-duty diesel vehicles on air quality.

  12. DFVLR rotorcraft: Construction and engineering

    NASA Technical Reports Server (NTRS)

    Langer, H. J.

    1984-01-01

    A helicopter rotor test stand is described. Full scale helicopter components can be tested such as hingeless fiberglass rotors and two blade rotor with flapping hinge, or a hybrid system. The facility is used to test stability, rotor components and downwind components.

  13. Proposed Cross-State Air Pollution Rule (75 FR 45210)

    EPA Pesticide Factsheets

    EPA proposes identifying and limiting emissions within 32 states in the eastern United States that affect the ability of downwind states to attain and maintain compliance with fine particulate matter and ozone national ambient air quality standards.

  14. Geophysical Tests for Intermediate-Range Forces

    DTIC Science & Technology

    1993-11-01

    34Feeble intermediate-range Gravitation, 1989, 154. Topics: AG,T, A forces from higher dimensions", Physical Review 60. Bell J. S., Perring J. K., ൝r...M., 134 Bell J. S., 60, 61 Coleman R., 389 Beltran-Lopez V., 359 Cabibbo N., 64 Coleman R. A ., 135 Bender P. L., 540 Calafiura P., 106 Cook A . H...of Zh. Eksp. Teor. Fiz., Selen M. A ., Shoemaker F. C., Smith A . J. S., 1985,88, 1946-1949.] Topics: SD,E,+ Blackmore E. W., Bryman D. A ., Felawka L

  15. Using stable isotopes of hydrogen to quantify biogenic and thermogenic atmospheric methane sources: A case study from the Colorado Front Range

    NASA Astrophysics Data System (ADS)

    Townsend-Small, Amy; Botner, E. Claire; Jimenez, Kristine L.; Schroeder, Jason R.; Blake, Nicola J.; Meinardi, Simone; Blake, Donald R.; Sive, Barkley C.; Bon, Daniel; Crawford, James H.; Pfister, Gabriele; Flocke, Frank M.

    2016-11-01

    Global atmospheric concentrations of methane (CH4), a powerful greenhouse gas, are increasing, but because there are many natural and anthropogenic sources of CH4, it is difficult to assess which sources may be increasing in magnitude. Here we present a data set of δ2H-CH4 measurements of individual sources and air in the Colorado Front Range, USA. We show that δ2H-CH4, but not δ13C, signatures are consistent in air sampled downwind of landfills, cattle feedlots, and oil and gas wells in the region. Applying these source signatures to air in ground and aircraft samples indicates that at least 50% of CH4 emitted in the region is biogenic, perhaps because regulatory restrictions on leaking oil and natural gas wells are helping to reduce this source of CH4. Source apportionment tracers such as δ2H may help close the gap between CH4 observations and inventories, which may underestimate biogenic as well as thermogenic sources.

  16. Nitrogen emissions, deposition, and monitoring in the Western United States

    USGS Publications Warehouse

    Fenn, M.E.; Haeuber, R.; Tonnesen, G.S.; Baron, Jill S.; Grossman-Clarke, S.; Hope, D.; Jaffe, D.A.; Copeland, S.; Geiser, L.; Rueth, H.M.; Sickman, J.O.

    2003-01-01

    Nitrogen (N) deposition in the western United States ranges from 1 to 4 kilograms (kg) per hectare (ha) per year over much of the region to as high as 30 to 90 kg per ha per year downwind of major urban and agricultural areas. Primary N emissions sources are transportation, agriculture, and industry. Emissions of N as ammonia are about 50% as great as emissions of N as nitrogen oxides. An unknown amount of N deposition to the West Coast originates from Asia. Nitrogen deposition has increased in the West because of rapid increases in urbanization, population, distance driven, and large concentrated animal feeding operations. Studies of ecological effects suggest that emissions reductions are needed to protect sensitive ecosystem components. Deposition rates are unknown for most areas in the West, although reasonable estimates are available for sites in California, the Colorado Front Range, and central Arizona. National monitoring networks provide long-term wet deposition data and, more recently, estimated dry deposition data at remote sites. However, there is little information for many areas near emissions sources.

  17. Potential contribution of semi-volatile and intermediate volatility primary organic compounds to secondary organic aerosol in the Mexico City region

    NASA Astrophysics Data System (ADS)

    Hodzic, A.; Jimenez, J. L.; Madronich, S.; Canagaratna, M. R.; Decarlo, P. F.; Kleinman, L.; Fast, J.

    2010-01-01

    It has been established that observed local and regional levels of secondary organic aerosols (SOA) in polluted areas cannot be explained by the oxidation and partitioning of anthropogenic and biogenic VOC precursors, at least using current mechanisms and parameterizations. In this study, the 3-D regional air quality model CHIMERE is applied to quantify the contribution to SOA formation of recently identified semi-volatile and intermediate volatility organic vapors (S/IVOC) in and around Mexico City for the MILAGRO field experiment during March 2006. The model has been updated to include explicitly the volatility distribution of primary organic aerosols (POA), their gas-particle partitioning and the gas-phase oxidation of the vapors. Two recently proposed parameterizations, those of Robinson et al. (2007) ("ROB") and Grieshop et al. (2009) ("GRI") are compared and evaluated against surface and aircraft measurements. The 3-D model results are assessed by comparing with the concentrations of OA components from Positive Matrix Factorization of Aerosol Mass Spectrometer (AMS) data, and for the first time also with oxygen-to-carbon ratios derived from high-resolution AMS measurements. The results show a substantial enhancement in predicted SOA concentrations (3-6 times) with respect to the previously published base case without S/IVOCs (Hodzic et al., 2009), both within and downwind of the city leading to much reduced discrepancies with the total OA measurements. The predicted anthropogenic POA levels are found to agree within 20% with the observed HOA concentrations for both the ROB and GRI simulations, consistent with the interpretation of the emissions inventory by previous studies. The impact of biomass burning POA within the city is underestimated in comparison to the AMS BBOA, presumably due to insufficient nighttime smoldering emissions. Model improvements in OA predictions are associated with the better-captured SOA magnitude and diurnal variability. The predicted production from anthropogenic and biomass burning S/IVOC represents 40-60% of the total SOA at the surface during the day and is somewhat larger than that from aromatics, especially at the T1 site at the edge of the city. The SOA production from the continued multi-generation S/IVOC oxidation products continues actively downwind. Similar to aircraft observations, the predicted OA/ΔCO ratio for the ROB case increases from 20-30 μg sm-3 ppm-1 up to 60-70 μg sm-3 ppm-1 between a fresh and 1-day aged air mass, while the GRI case produces a 30-40% higher OA growth than observed. The predicted average O/C ratio of total OA for the ROB case is 0.16 at T0, substantially below observed value of 0.5. A much better agreement for O/C ratios and temporal variability (R2=0.63) is achieved with the updated GRI treatment. Both treatments show a deficiency in regard to POA evolution with a tendency to over-evaporate POA upon dilution of the urban plume suggesting that atmospheric HOA may be less volatile than assumed in these parameterizations. This study highlights the important potential role of S/IVOC chemistry in the SOA budget in this region, and highlights the need for improvements in current parameterizations. We note that our simulations did not include other proposed pathways of SOA formation such as formation from very volatile species like glyoxal, which can also contribute SOA mass and especially increase the O/C ratio.

  18. Modeling organic aerosols in a megacity: potential contribution of semi-volatile and intermediate volatility primary organic compounds to secondary organic aerosol formation

    NASA Astrophysics Data System (ADS)

    Hodzic, A.; Jimenez, J. L.; Madronich, S.; Canagaratna, M. R.; Decarlo, P. F.; Kleinman, L.; Fast, J.

    2010-06-01

    It has been established that observed local and regional levels of secondary organic aerosols (SOA) in polluted areas cannot be explained by the oxidation and partitioning of anthropogenic and biogenic VOC precursors, at least using current mechanisms and parameterizations. In this study, the 3-D regional air quality model CHIMERE is applied to estimate the potential contribution to SOA formation of recently identified semi-volatile and intermediate volatility organic precursors (S/IVOC) in and around Mexico City for the MILAGRO field experiment during March 2006. The model has been updated to include explicitly the volatility distribution of primary organic aerosols (POA), their gas-particle partitioning and the gas-phase oxidation of the vapors. Two recently proposed parameterizations, those of Robinson et al. (2007) ("ROB") and Grieshop et al. (2009) ("GRI") are compared and evaluated against surface and aircraft measurements. The 3-D model results are assessed by comparing with the concentrations of OA components from Positive Matrix Factorization of Aerosol Mass Spectrometer (AMS) data, and for the first time also with oxygen-to-carbon ratios derived from high-resolution AMS measurements. The results show a substantial enhancement in predicted SOA concentrations (2-4 times) with respect to the previously published base case without S/IVOCs (Hodzic et al., 2009), both within and downwind of the city leading to much reduced discrepancies with the total OA measurements. Model improvements in OA predictions are associated with the better-captured SOA magnitude and diurnal variability. The predicted production from anthropogenic and biomass burning S/IVOC represents 40-60% of the total measured SOA at the surface during the day and is somewhat larger than that from commonly measured aromatic VOCs, especially at the T1 site at the edge of the city. The SOA production from the continued multi-generation S/IVOC oxidation products continues actively downwind. Similar to aircraft observations, the predicted OA/ΔCO ratio for the ROB case increases from 20-30 μg sm-3 ppm-1 up to 60-70 μg sm-3 ppm-1 between a fresh and 1-day aged air mass, while the GRI case produces a 30% higher OA growth than observed. The predicted average O/C ratio of total OA for the ROB case is 0.16 at T0, substantially below observed value of 0.5. A much better agreement for O/C ratios and temporal variability (R2=0.63) is achieved with the updated GRI treatment. Both treatments show a deficiency in regard to POA ageing with a tendency to over-evaporate POA upon dilution of the urban plume suggesting that atmospheric HOA may be less volatile than assumed in these parameterizations. This study highlights the important potential role of S/IVOC chemistry in the SOA budget in this region, and highlights the need for further improvements in available parameterizations. The agreement observed in this study is not sufficient evidence to conclude that S/IVOC are the major missing SOA source in megacity environments. The model is still very underconstrained, and other possible pathways such as formation from very volatile species like glyoxal may explain some of the mass and especially increase the O/C ratio.

  19. Cytoplasmic peptidoglycan intermediate levels in Staphylococcus aureus.

    PubMed

    Vemula, Harika; Ayon, Navid J; Gutheil, William G

    2016-02-01

    Intracellular cytoplasmic peptidoglycan (PG) intermediate levels were determined in Staphylococcus aureus during log-phase growth in enriched media. Levels of UDP-linked intermediates were quantitatively determined using ion pairing LC-MS/MS in negative mode, and amine intermediates were quantitatively determined stereospecifically as their Marfey's reagent derivatives in positive mode. Levels of UDP-linked intermediates in S. aureus varied from 1.4 μM for UDP-GlcNAc-Enolpyruvyate to 1200 μM for UDP-MurNAc. Levels of amine intermediates (L-Ala, D-Ala, D-Ala-D-Ala, L-Glu, D-Glu, and L-Lys) varied over a range of from 860 μM for D-Ala-D-Ala to 30-260 mM for the others. Total PG was determined from the D-Glu content of isolated PG, and used to estimate the rate of PG synthesis (in terms of cytoplasmic metabolite flux) as 690 μM/min. The total UDP-linked intermediates pool (2490 μM) is therefore sufficient to sustain growth for 3.6 min. Comparison of UDP-linked metabolite levels with published pathway enzyme characteristics demonstrates that enzymes on the UDP-branch range from >80% saturation for MurA, Z, and C, to <5% saturation for MurB. Metabolite levels were compared with literature values for Escherichia coli, with the major difference in UDP-intermediates being the level of UDP-MurNAc, which was high in S. aureus (1200 μM) and low in E. coli (45 μM). Copyright © 2015 Elsevier B.V. and Société Française de Biochimie et Biologie Moléculaire (SFBBM). All rights reserved.

  20. 40 CFR 141.66 - Maximum contaminant levels for radionuclides.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... quality range andconsiderations. 1 1. Ion exchange (IE) (a) Intermediate All ground waters. 2. Point of.... Lime softening (d) Advanced All waters. 6. Green sand filtration (e) Basic. 7. Co-precipitation with Barium sulfate (f) Intermediate to Advanced Ground waters with suitable water quality. 8. Electrodialysis...

  1. Elevated temperature tensile properties of P9 steel towards ferritic steel wrapper development for sodium cooled fast reactors

    NASA Astrophysics Data System (ADS)

    Choudhary, B. K.; Mathew, M. D.; Isaac Samuel, E.; Christopher, J.; Jayakumar, T.

    2013-11-01

    Tensile deformation and fracture behaviour of the three developmental heats of P9 steel for wrapper applications containing varying silicon in the range 0.24-0.60% have been examined in the temperature range 300-873 K. Yield and ultimate tensile strengths in all the three heats exhibited gradual decrease with increase in temperature from room to intermediate temperatures followed by rapid decrease at high temperatures. A gradual decrease in ductility to a minimum at intermediate temperatures followed by an increase at high temperatures has been observed. The fracture mode remained transgranular ductile. The steel displayed signatures of dynamic strain ageing at intermediate temperatures and dominance of recovery at high temperatures. No significant difference in the strength and ductility values was observed for varying silicon in the range 0.24-0.60% in P9 steel. P9 steel for wrapper application displayed strength and ductility values comparable to those reported in the literature.

  2. Secondary organic aerosol (SOA) derived from isoprene epoxydiols: Insights into formation, aging and distribution over the continental US from the DC3 and SEAC4RS campaigns

    NASA Astrophysics Data System (ADS)

    Campuzano Jost, P.; Palm, B. B.; Day, D. A.; Hu, W.; Ortega, A. M.; Jimenez, J. L.; Liao, J.; Froyd, K. D.; Pollack, I. B.; Peischl, J.; Ryerson, T. B.; St Clair, J. M.; Crounse, J.; Wennberg, P. O.; Mikoviny, T.; Wisthaler, A.; Ziemba, L. D.; Anderson, B. E.

    2014-12-01

    Isoprene-derived SOA formation has been studied extensively in the laboratory. However, it is still unclear to what extent isoprene contributes to the overall SOA burden over the southeastern US, an area with both strong isoprene emissions as well as large discrepancies between modeled and observed aerosol optical depth. For the low-NO isoprene oxidation pathway, the key gas-phase intermediate is believed to be isoprene epoxide (IEPOX), which can be incorporated into the aerosol phase by either sulfate ester formation (IEPOX sulfate) or direct hydrolysis. As first suggested by Robinson et al, the SOA formed by this mechanism (IEPOX-SOA) has a characteristic fragmentation pattern when analyzed by an Aerodyne Aerosol Mass Spectrometer (AMS) with enhanced relative abundances of the C5H6O+ ion (fC5H6O). Based on data from previous ground campaigns and chamber studies, we have developed a empirical method to quantify IEPOX-SOA and have applied it to the data from the DC3 and SEAC4RS aircraft campaigns that sampled the SE US during the Spring of 2012 and the Summer of 2013. We used Positive Matrix Factorization (PMF) to extract IEPOX-SOA factors that show good correlation with inside or downwind of high isoprene emitting areas and in general agree well with the IEPOX-SOA mass predicted by the empirical expression. According to this analysis, the empirical method performs well regardless of (at times very strong) BBOA or urban OA influences. On average 17% of SOA in the SE US boundary layer was IEPOX-SOA. Overall, the highest concentrations of IEPOX-SOA were typically found around 1-2 km AGL, several hours downwind of the isoprene source areas with high gas-phase IEPOX present. IEPOX-SOA was also detected up to altitudes of 6 km, with a clear trend towards more aged aerosol at altitude, likely a combination of chemical aging and physical airmass mixing. The unique instrument package aboard the NASA-DC8 allows us to examine the influence of multiple factors (aerosol acidity, aerosol water content, sulfate mass fraction, isoprene and terpene source strength) to the relative and absolute contribution of IEPOX-SOA to the total OA burden. In particular, the IEPOX-sulfate measurement from the PALMS instrument was used to estimate the relative contribution of the organosulfate channel to the IEPOX-SOA formation.

  3. Significant Contribution Assessment of Proposed Revisions Technical Support Document (TSD)

    EPA Pesticide Factsheets

    This TSD demonstrates EPA’s analysis to quantify the SO2 emissions that significantly contribute to nonattainment or interfere with maintenance of the National Ambient Air Quality Standards in downwind states for the Revisions to the Transport Rule.

  4. EMISSION OF PESTICIDES INTO THE AIR

    EPA Science Inventory

    During and after the application of pesticide in agriculture, a substantial fraction of the dosage may enter the atmosphere and be transported over varying distances downwind of the target. The rate and extent of the emission during application depends primarily on the applicat...

  5. Intermediality and the Child Performer

    ERIC Educational Resources Information Center

    Budd, Natasha

    2016-01-01

    This report details examples of praxis in the creation and presentation of "Joy Fear and Poetry": an intermedial theatre performance in which children aged 7-12 years generated aesthetic gestures using a range of new media forms. The impetus for the work's development was a desire to make an intervention into habituated patterns of…

  6. Intermediate load-center photovoltaic application experiments

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Burgess, E. L.

    1980-01-01

    A total of nine intermediate load-center photovoltaic systems were carried into the construction phase this year. These nine systems range in size from 20 to 225 kW/sub p/ electrical output and total almost 1 MW/sub p/. They are being installed in a diverse set of applications and locations and represent the bulk of the photovoltaic initial system evaluation experiments (ISEE) for the intermediate load-center sector. Each of these experiments are briefly described and the status of the construction phase is given for each project.

  7. Remote sensing of volcanic CO2, HF, HCl, SO2, and BrO in the downwind plume of Mt. Etna

    NASA Astrophysics Data System (ADS)

    Butz, André; Solvejg Dinger, Anna; Bobrowski, Nicole; Kostinek, Julian; Fieber, Lukas; Fischerkeller, Constanze; Giuffrida, Giovanni Bruno; Hase, Frank; Klappenbach, Friedrich; Kuhn, Jonas; Lübcke, Peter; Tirpitz, Lukas; Tu, Qiansi

    2017-01-01

    Remote sensing of the gaseous composition of non-eruptive, passively degassing volcanic plumes can be a tool to gain insight into volcano interior processes. Here, we report on a field study in September 2015 that demonstrates the feasibility of remotely measuring the volcanic enhancements of carbon dioxide (CO2), hydrogen fluoride (HF), hydrogen chloride (HCl), sulfur dioxide (SO2), and bromine monoxide (BrO) in the downwind plume of Mt. Etna using portable and rugged spectroscopic instrumentation. To this end, we operated the Fourier transform spectrometer EM27/SUN for the shortwave-infrared (SWIR) spectral range together with a co-mounted UV spectrometer on a mobile platform in direct-sun view at 5 to 10 km distance from the summit craters. The 3 days reported here cover several plume traverses and a sunrise measurement. For all days, intra-plume HF, HCl, SO2, and BrO vertical column densities (VCDs) were reliably measured exceeding 5 × 1016, 2 × 1017, 5 × 1017, and 1 × 1014 molec cm-2, with an estimated precision of 2.2 × 1015, 1.3 × 1016, 3.6 × 1016, and 1.3 × 1013 molec cm-2, respectively. Given that CO2, unlike the other measured gases, has a large and well-mixed atmospheric background, derivation of volcanic CO2 VCD enhancements (ΔCO2) required compensating for changes in altitude of the observing platform and for background concentration variability. The first challenge was met by simultaneously measuring the overhead oxygen (O2) columns and assuming covariation of O2 and CO2 with altitude. The atmospheric CO2 background was found by identifying background soundings via the co-emitted volcanic gases. The inferred ΔCO2 occasionally exceeded 2 × 1019 molec cm-2 with an estimated precision of 3.7 × 1018 molec cm-2 given typical atmospheric background VCDs of 7 to 8 × 1021 molec cm-2. While the correlations of ΔCO2 with the other measured volcanic gases confirm the detection of volcanic CO2 enhancements, correlations were found of variable significance (R2 ranging between 0.88 and 0.00). The intra-plume VCD ratios ΔCO2 / SO2, SO2 / HF, SO2 / HCl, and SO2 / BrO were in the range 7.1 to 35.4, 5.02 to 21.2, 1.54 to 3.43, and 2.9 × 103 to 12.5 × 103, respectively, showing pronounced day-to-day and intra-day variability.

  8. Effects of Air Pollutants on Lichens of the Idaho National Engineering Laboratory National Environmental Research Park

    NASA Astrophysics Data System (ADS)

    Marty, R. C.; Forman, A.; Crawford, R.; Tyler, T.

    2001-12-01

    The Idaho National Engineering and Environmental Laboratory is a (2300 square km) National Environmental Research Park that has been used for research and operational support of nuclear power. The Park includes scattered industrial operations and provides an ideal setting to study effects of industry on semi-arid environments. One of the facilities on the Research Park is the Idaho Nuclear Technology Center (INTEC). This facility reprocessed spent nuclear fuel from the US Navy, and its operations included heating acidic solutions to convert wastes to a solid form. The conversion released nitrogen oxides, low levels of other gases (including HF), and small amounts of solid particles through a facility stack. A fossil-fuel power plant also contributed airborne contaminants including sulfur dioxide. A 1985 study identified the effects of INTEC operations on the health of lichens Xanthoria polycarpa (quantified using electrolyte leakage), on levels of trace metals in the lichens X. polycarpa and Rhizoplaca melanophthalma, and on the levels of trace metals in higher plants and soils. The study concluded that operations impacted the physiological health of X. polycarpa southwest of the plant, and that lead was significantly higher downwind of the plant relative to other locations. Effects of the plant were re-examined in 1999 as part of an Environmental Impact Statement to evaluate the environmental effects of measures available to deal with radioactive waste at INTEC. Sulfur dioxide emissions from the facility decreased from approximately 375 tonsyear to approximately 10 tonsyear between the two studies. The re-examination of lichens showed that the measure of physiological health used in the previous study (conductivity of rinsates collected from lichen thalli) correlated well to the levels of potassium measured in rinsates collected from thalli. There, however, was no correlation between the levels of potassium/conductivity of such rinsates and the levels of total potassium in lichens or between levels of potassium/conductivity and macroscopic vigor of the lichens or between levels of potassium/conductivity in rinsates and chlorophyll ratios (another common indicator of the physiological health of lichens). This suggests that potassium levels in rinsates may not be a good indicator of physiological stress. X. polycarpa abundance varied with direction from the facility. The species was lacking from background locations at Craters of the Moon National monument. Cover on dead Artemisia tridentata twigs varied between 2 and 5% downwind and crosswind for the predominant wind direction, but approached 75% to the north and northeast (downwind) of the facility. This differential cover is striking but was not noted in the previous study and probably reflects increased abundance of the nitrogen loving X. polycarpa downwind from the facility between the two studies. Calcium levels in R. melanophthalma around INTEC were significantly higher than calcium levels in lichens from the background location at Craters of the Moon. This may reflect migration of the species to more buffered calcium carbonate substrates in response to acidified precipitation. Levels of calcium in R. melanophthalma fell between the two studies, possibly reflecting less substrate acidification during the later period. Lead was not significantly elevated during the second study, but mercury may be elevated downwind of the facility.

  9. Estimation of Downwind Concentration of Airborne Effluents Discharged in the Neighbourhood of Buildings.

    ERIC Educational Resources Information Center

    Barry, P. J.

    Air flow in the neighborhood of buildings is briefly described and compared with that assumed for the usual atmospheric diffusion equations. The literature is reviewed and empirical formulae which have been proposed are listed and compared. (RH)

  10. A Windmill's Theoretical Maximum Extraction of Power from the Wind.

    ERIC Educational Resources Information Center

    Inglis, David Rittenhouse

    1979-01-01

    Explains that the efficiency and the useful power available from a windmill turbine, of a laminar-flow model, will vary due to rotational kinetic energy of the downwind stream and turbulent mixing from outside the boundaries of the idealized stream. (GA)

  11. Commercial aircraft engine emissions characterization of in-use aircraft at Hartsfield-Jackson Atlanta International Airport

    DOT National Transportation Integrated Search

    2008-01-31

    The emissions from in-use commercial aircraft engines have been analyzed for selected gas-phase species and particulate characteristics using continuous extractive sampling 1-2 min downwind from operational taxi- and runways at Hartsfield-Jackson Atl...

  12. Footprint of recycled water subsidies downwind of Lake Michigan

    USDA-ARS?s Scientific Manuscript database

    Continental evaporation is a significant and dynamic flux within the atmospheric water budget, but few methods provide robust observational constraints on the large-scale hydroclimatological and hydroecological impacts of this ‘recycled-water’ flux. We demonstrate a geospatial analysis that provides...

  13. Pasture-scale methane emissions of grazing cattle

    USDA-ARS?s Scientific Manuscript database

    Grazing cattle are mobile point sources of methane and present challenges to quantify emissions using noninterfering micrometeorological methods. Stocking density is low and cattle can bunch up or disperse over a wide area, so knowing cattle locations is critical. The methane concentration downwind ...

  14. POTENTIAL AIR TOXICS HOT SPOTS IN TRUCK TERMINALS AND CABS

    EPA Science Inventory

    All three types of testing sites — upwind and downwind traffic — met the established definition for a hot spot by having periods with concentrations of pollutants that exceeded the EPA’s screening values. Most frequently, the pollutants with concentrations...

  15. An informational transition in conditioned Markov chains: Applied to genetics and evolution.

    PubMed

    Zhao, Lei; Lascoux, Martin; Waxman, David

    2016-08-07

    In this work we assume that we have some knowledge about the state of a population at two known times, when the dynamics is governed by a Markov chain such as a Wright-Fisher model. Such knowledge could be obtained, for example, from observations made on ancient and contemporary DNA, or during laboratory experiments involving long term evolution. A natural assumption is that the behaviour of the population, between observations, is related to (or constrained by) what was actually observed. The present work shows that this assumption has limited validity. When the time interval between observations is larger than a characteristic value, which is a property of the population under consideration, there is a range of intermediate times where the behaviour of the population has reduced or no dependence on what was observed and an equilibrium-like distribution applies. Thus, for example, if the frequency of an allele is observed at two different times, then for a large enough time interval between observations, the population has reduced or no dependence on the two observed frequencies for a range of intermediate times. Given observations of a population at two times, we provide a general theoretical analysis of the behaviour of the population at all intermediate times, and determine an expression for the characteristic time interval, beyond which the observations do not constrain the population's behaviour over a range of intermediate times. The findings of this work relate to what can be meaningfully inferred about a population at intermediate times, given knowledge of terminal states. Copyright © 2016 Elsevier Ltd. All rights reserved.

  16. Full-Scale Field Test of Wake Steering

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Fleming, Paul; Annoni, Jennifer; Scholbrock, Andrew

    Wind farm control, in which turbine controllers are coordinated to improve farmwide performance, is an active field of research. One form of wind farm control is wake steering, in which a turbine is yawed to the inflow to redirect its wake away from downstream turbines. Wake steering has been studied in depth in simulations as well as in wind tunnels and scaled test facilities. This work performs a field test of wake steering on a full-scale turbine. In the campaign, the yaw controller of the turbine has been set to track different yaw misalignment set points while a nacelle-mounted lidarmore » scans the wake at several ranges downwind. The lidar measurements are combined with turbine data, as well as measurements of the inflow made by a highly instrumented meteorological mast. In conclusion, these measurements are then compared to the predictions of a wind farm control-oriented model of wakes.« less

  17. Theoretical and experimental studies of the waveforms associated with stratospheric infrasonic returns

    NASA Astrophysics Data System (ADS)

    Waxler, R.; Talmadge, C. L.; Blom, P.

    2009-12-01

    Theory predicts that for ground to ground infrasound propagation along paths which travel downwind, relative to the stratospheric jet, there is a shadow zone which ends about 200 km from the source where the first return from the stratosphere strikes the earth. With increasing range the single stratospheric arrival splits into two distinct arrivals, a fast arrival with the trace velocity of the effective sound speed at the stratopause, and a slower arrival with the trace velocity of the sound speed on the ground. To test the theory we have deployed eight infrasound arrays along an approximate line directly west of the site of the US Navy's Trident Missile rocket motor eliminations. The arrays were deployed during the summer of 2009 spaced roughly 10 km apart along a segment from 180 to 260 km west of the site. Comparisons between the theoretical predictions and the received data will be presented.

  18. The acoustic field of a point source in a uniform boundary layer over an impedance plane

    NASA Technical Reports Server (NTRS)

    Zorumski, W. E.; Willshire, W. L., Jr.

    1986-01-01

    The acoustic field of a point source in a boundary layer above an impedance plane is investigated anatytically using Obukhov quasi-potential functions, extending the normal-mode theory of Chunchuzov (1984) to account for the effects of finite ground-plane impedance and source height. The solution is found to be asymptotic to the surface-wave term studies by Wenzel (1974) in the limit of vanishing wind speed, suggesting that normal-mode theory can be used to model the effects of an atmospheric boundary layer on infrasonic sound radiation. Model predictions are derived for noise-generation data obtained by Willshire (1985) at the Medicine Bow wind-turbine facility. Long-range downwind propagation is found to behave as a cylindrical wave, with attention proportional to the wind speed, the boundary-layer displacement thickness, the real part of the ground admittance, and the square of the frequency.

  19. On the Global Character of Overlap Between Low and High Clouds

    NASA Technical Reports Server (NTRS)

    Yuan, Tianle; Oreopoulos, Lazaros

    2013-01-01

    The global character of overlap between low and high clouds is examined using active satellite sensors. Low-cloud fraction has a strong land-ocean contrast with oceanic values double those over land. Major low-cloud regimes include not only the eastern ocean boundary stratocumulus and shallow cumulus but also those associated with cold air outbreaks downwind of wintertime continents and land stratus over particular geographic areas. Globally, about 30% of low clouds are overlapped by high clouds. The overlap rate exhibits strong spatial variability ranging from higher than 90% in the tropics to less than 5% in subsidence areas and is anticorrelated with subsidence rate and low-cloud fraction. The zonal mean of vertical separation between cloud layers is never smaller than 5 km and its zonal variation closely follows that of tropopause height, implying a tight connection with tropopause dynamics. Possible impacts of cloud overlap on low clouds are discussed.

  20. [Death by avalanche in the minor mountain range].

    PubMed

    Geisenberger, Dorothee; Kramer, Lena; Pircher, Rebecca; Pollak, Stefan

    2015-01-01

    On 30 Jan 2015, two avalanche accidents happened in the Black Forest (at the foot of the 1493 m high Feldberg and the Herzogenhorn situated next to it), in which experienced ski tourers--a 58-year-old woman and a 20-year-old man--were completely buried by snow masses. Both victims were recovered dead after nearly 2 hours under the snow. The avalanches were promoted by strong snowfalls, snowdrift by the wind and steep downwind slopes. One of the victims, the 20-year-old man, underwent a forensic autopsy. The findings suggested death by protracted asphyxiation with agonal hypothermia. A mechanical traumatization with internal injuries suspected by the emergency doctor at the scene could not be confirmed at autopsy. The possible causes of death in the avalanche are discussed using the reported case as an example and in reference to the relevant literature.

  1. Full-Scale Field Test of Wake Steering

    DOE PAGES

    Fleming, Paul; Annoni, Jennifer; Scholbrock, Andrew; ...

    2017-06-13

    Wind farm control, in which turbine controllers are coordinated to improve farmwide performance, is an active field of research. One form of wind farm control is wake steering, in which a turbine is yawed to the inflow to redirect its wake away from downstream turbines. Wake steering has been studied in depth in simulations as well as in wind tunnels and scaled test facilities. This work performs a field test of wake steering on a full-scale turbine. In the campaign, the yaw controller of the turbine has been set to track different yaw misalignment set points while a nacelle-mounted lidarmore » scans the wake at several ranges downwind. The lidar measurements are combined with turbine data, as well as measurements of the inflow made by a highly instrumented meteorological mast. In conclusion, these measurements are then compared to the predictions of a wind farm control-oriented model of wakes.« less

  2. Use of external cavity quantum cascade laser compliance voltage in real-time trace gas sensing of multiple chemicals

    NASA Astrophysics Data System (ADS)

    Phillips, Mark C.; Taubman, Matthew S.; Kriesel, Jason

    2015-01-01

    We describe a prototype trace gas sensor designed for real-time detection of multiple chemicals. The sensor uses an external cavity quantum cascade laser (ECQCL) swept over its tuning range of 940-1075 cm-1 (9.30-10.7 μm) at a 10 Hz repetition rate. The sensor was designed for operation in multiple modes, including gas sensing within a multi-pass Heriott cell and intracavity absorption sensing using the ECQCL compliance voltage. In addition, the ECQCL compliance voltage was used to reduce effects of long-term drifts in the ECQCL output power. The sensor was characterized for noise, drift, and detection of chemicals including ammonia, methanol, ethanol, isopropanol, Freon- 134a, Freon-152a, and diisopropyl methylphosphonate (DIMP). We also present use of the sensor for mobile detection of ammonia downwind of cattle facilities, in which concentrations were recorded at 1-s intervals.

  3. A method for defining down-wind evacuation areas for transportation accidents involving toxic propellant spills

    NASA Technical Reports Server (NTRS)

    Siewert, R. D.

    1972-01-01

    Evacuation areas for accidental spills of toxic propellants along rail and highway shipping routes are defined to help local authorities reduce risks to people from excessive vapor concentrations. These criteria along with other emergency information are shown in propellant spill cards. The evacuation areas are based on current best estimates of propellant evaporation rates from various areas of spill puddles. These rates are used together with a continuous point-source, bi-normal model of plume dispersion. The rate at which the toxic plume disperses is based on a neutral atmospheric condition. This condition, which results in slow plume dispersion, represents the widest range of weather parameters which could occur during the day and nighttime periods. Evacuation areas are defined by the ground level boundaries of the plume within which the concentrations exceed the toxic Threshold Limit Value (TLV) or in some cases the Emergency Exposure Limit (EEL).

  4. The nature of intermediate-range order in Ge-As-S glasses : results from reverse Monte Carlo modeling.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Soyer-Uzun, S.; Benmore, C. J.; Siewenie, J. E.

    2010-01-01

    The experimental neutron and x-ray diffraction data for stoichiometric and S-deficient Ge{sub x}As{sub x}S{sub 100-2x} glasses with x = 18.2, 25.0, and 33.3 at.% have been modeled simultaneously using the reverse Monte Carlo (RMC) technique. Nearest-neighbor coordination environments, as obtained in previous x-ray absorption spectroscopy and diffraction experiments, have been employed as short-range order constraints in these simulations. The large scale three-dimensional structural models thus obtained from RMC simulation are used to investigate the nature and compositional evolution of intermediate-range structural order in these ternary glasses. The intermediate-range structural order is controlled by (1) a corner-shared three-dimensional network of AsS{submore » 3} pyramids and GeS{sub 4} tetrahedra in the stoichiometric Ge{sub 18.2}As{sub 18.2}S{sub 63.6} glass, (2) a heterogeneous structure that consists of homopolar bonded As-rich regions coexisting with a GeS{sub 2} network in the S-deficient Ge{sub 25}As{sub 25}S{sub 50} glass, and (3) a homogeneous structure resulting from the disruption of the topological continuity of the GeS{sub 2} network and As-rich clusters regions due to the formation of Ge-As bonds in the most S-deficient Ge{sub 33.3}As{sub 33.3}S{sub 33.3} glass. This scenario of the compositional evolution of intermediate-range structural order is consistent with and provides an atomistic explanation of the corresponding evolution in the position, width and intensity of the first sharp diffraction peak and the magnitude of small angle scattering in these glasses.« less

  5. Flow and sediment transport dynamics in a slot and cauldron blowout and over a foredune, Mason Bay, Stewart Island (Rakiura), NZ

    NASA Astrophysics Data System (ADS)

    Hesp, Patrick A.; Hilton, Michael; Konlecher, Teresa

    2017-10-01

    This study is the first to simultaneously compare flow and sediment transport through a blowout and over an adjacent foredune, and the first study of flow within a highly sinuous, slot and cauldron blowout. Flow across the foredune transect is similar to that observed in other studies and is primarily modulated by across-dune vegetation density differences. Flow within the blowout is highly complex and exhibits pronounced accelerations and jet flow. It is characterised by marked helicoidal coherent vortices in the mid-regions, and topographically vertically forced flow out of the cauldron portion of the blowout. Instantaneous sediment transport within the blowout is significant compared to transport onto and/or over the adjacent foredune stoss slope and ridge, with the blowout providing a conduit for suspended sediment to reach the downwind foredune upper stoss slope and crest. Medium term (4 months) aeolian sedimentation data indicates sand is accumulating in the blowout entrance while erosion is taking place throughout the majority of the slot, and deposition is occurring downwind of the cauldron on the foredune ridge. The adjacent lower stoss slope of the foredune is accreting while the upper stoss slope is slightly erosional. Longer term (16 months) pot trap data shows that the majority of foredune upper stoss slope and crest accretion occurs via suspended sediment delivery from the blowout, whereas the majority of the suspended sediment arriving to the well-vegetated foredune stoss slope is deposited on the mid-stoss slope. The results of this study indicate one mechanism of how marked alongshore foredune morphological variability evolves due to the role of blowouts in topographically accelerating flow, and delivering significant aeolian sediment downwind to relatively discrete sections of the foredune.

  6. Aeolian Rat Tails (ARTs): A New Morphological Indicator of Abrasion Direction

    NASA Astrophysics Data System (ADS)

    Favaro, E. A.; Hugenholtz, C.; Barchyn, T.

    2016-12-01

    Aeolian rat tails (ARTs) are a previously undocumented aeolian abrasion feature observed on ignimbrite surfaces in the Puna Plateau of Northwest Argentina and bare morphological similarity to small-scale features on Mars. We describe the terrestrial features and present an evolutionary sequence from inception to demise. ARTs are regionally-ubiquitous and characterized by a windward abrasion-resistant lithic clast and a downwind-tapering tail. The size of ARTs is controlled by the diameter of the windward lithic clast, observed on the sub-decimeter to meter scale. Their distribution throughout the Campo de Piedra Pómez, and adjacent regions is determined by the ignimbrite clast content. ARTs develop under a uni-modal abrasion direction when lithic clasts are eroded out of the ignimbrite matrix, protrude from the surface, and shelter material directly behind the clast. As the surrounding material is eroded away, a downwind-tapered tail develops. Continued erosion of the adjacent surface leads to the undercutting of clasts, liberating them from the feature where, if small enough, the clasts can be transported downwind, leading to the destruction of the tail and ultimately the feature. This evolutionary sequence accounts not only for the morphology of the feature, but also the presence of loose clasts on the ignimbrite surface, which plays a role in the development of other enigmatic landforms in the area, such as periodic bedrock ridges, yardangs, and megaripples. The significance of the identification of ARTs is due to the necessity of uni-modal abrasion direction for their development, thereby making their orientation a diagnostic indicator of long-term aeolian abrasion direction. ARTs are likely analogs of features identified by MSL Curiosity Rover on Mars, possibly providing information on past and present wind regimes.

  7. Juvenile hypothyroidism among two populations exposed to radioiodine.

    PubMed Central

    Goldsmith, J R; Grossman, C M; Morton, W E; Nussbaum, R H; Kordysh, E A; Quastel, M R; Sobel, R B; Nussbaum, F D

    1999-01-01

    We found an epidemic of juvenile hypothyroidism among a population of self-defined "downwinders" living near the Hanford nuclear facility located in southeast Washington State. The episode followed massive releases of 131I. Self-reported data on 60 cases of juvenile hypothyroidism (<20 years of age) among a group of 801 Hanford downwinders are presented, as well as data concerning the thyroid status of approximately 160,000 children exposed to radioiodine before 10 years of age as a result of the 26 April 1986 Chernobyl explosion in the former Soviet Union. These children were residents of five regions near Chernobyl. They were examined by standardized screening protocols over a period of 5 years from 1991 to 1996. They are a well-defined group of 10 samples. Fifty-six cases of hypothyroidism were found among boys and 92 among girls. Body burdens of 137Cs have been correlated with hypothyroidism prevalence rates. On the other hand, the group of juvenile (<20 years of age) Hanford downwinders is not a representative sample. Most of the 77 cases of juvenile hypothyroidism in the Hanford group were diagnosed from 1945 to 1970. However, the ratio of reported cases to the county population under 20 years of age is roughly correlated with officially estimated mean levels of cumulative thyroid 131I uptake in these counties, providing evidence that juvenile hypothyroidism was associated with radioiodine exposures. Because even subtle hypothyroidism may be of clinical significance in childhood and can be treated, it may be useful to screen for the condition in populations exposed to radioiodine fallout. Although radiation exposure is associated with hypothyroidism, its excess among fallout-exposed children has not been previously quantified. Images Figure 1 Figure 2 Figure 3 Figure 4 Figure 5 Figure 6 PMID:10090710

  8. Particle and Gas Emissions from an In Situ Burn of Crude Oil on the Ocean.

    PubMed

    Hobbs, John L Ross Ronald J Ferek And Peter V

    1996-03-01

    Burning is a very effective way of removing oil spills from the ocean; the tradeoff is the potential for significant air pollution. Airborne measurements are described for particles and gases from two test burns of crude oil offshore of St. Johns, Newfoundland during the Newfoundland Offshore Burn Experiment (NOBE). The smoke plumes from the burns initially rose 200-400 m into the air and then continued to rise and disperse laterally downwind. The concentrations of accumulation-mode particles in the smoke were ~45,000 cm -3 at 1.5 km from the fires, and they remained as high as ~4,000 cm -3 after an hour or more of travel time downwind. Total particle mass loadings in the plumes were over 1000 µg m -3 near the fires, but decreased to ~100 µg m -3 at 25 km downwind. For each kilogram of fuel consumed, ~770 g of carbon was released in the form of CO2, ~13 g of carbon as CO, -5 g as volatile organic compounds (VOCs), and -87 g as particles with diameters <3.5 µm, of which ~66 g was elemental carbon and ~7 g condensed organic carbon. Also, ~3 g of SO2 was released per kilogram of fuel burned. A relatively low combustion efficiency was indicated by the average molar ratio of the concentration of CO to excess CO2 of 0.017. The molar ratio of NOX to excess CO2 typically varied from 0.3 x 10 -3 to 0.4 x 10 -3 , implying little fixation of atmospheric nitrogen and low concentrations of NOX. For comparison, the total smoke particle production rate in the NOBE burns was about the same as that for a nineacre slash burn.

  9. Evaluation of Space-Based Constraints on Global Nitrogen Oxide Emissions with Regional Aircraft Measurements over and Downwind of Eastern North America

    NASA Technical Reports Server (NTRS)

    Martin, Randall V.; Sioris, Christopher E.; Chance, Kelly; Ryerson, Thomas B.; Flocke, Frank M.; Bertram, Timothy H.; Wooldridge, Paul J.; Cohen, Ronald C.; Neuman, J. Andy; Swanson, Aaron

    2006-01-01

    We retrieve tropospheric nitrogen dioxide (NO 2) columns for May 2004 to April 2005 from the SCIAMACHY satellite instrument to derive top-down emissions of nitrogen oxides (NO(x) = NO + NO2) via inverse modeling with a global chemical transport model (GEOS-Chem). Simulated NO 2 vertical profiles used in the retrieval are evaluated with airborne measurements over and downwind of North America (ICARTT); a northern midlatitude lightning source of 1.6 Tg N/yr minimizes bias in the retrieval. Retrieved NO2 columns are validated (r2 = 0.60, slope = 0.82) with coincident airborne in situ measurements. The top-down emissions are combined with a priori information from a bottom-up emission inventory with error weighting to achieve an improved a posteriori estimate of the global distribution of surface NOx emissions. Our a posteriori NOx emission inventory for land surface NOx emissions (46.1 Tg N/yr) is 22% larger than the GEIA-based a priori bottom-up inventory for 1998, a difference that reflects rising anthropogenic emissions, especially from East Asia A posteriori NOx emissions for East Asia (9.8 Tg N/yr) exceed those from other continents. The a posteriori inventory improves the GEOS-Chem simulation of NOx, peroxyacetylnitrate, and nitric acid with respect to airborne in situ measurements over and downwind of New York City. The a posteriori is 7% larger than the EDGAR 3.2FT2000 global inventory, 3% larger than the NEI99 inventory for the United States, and 68% larger than a regional inventory for 2000 for eastern Asia. SCIAMACHY NO2 columns over the North Atlantic show a weak plume from lightning NO(x).

  10. Ozone and alkyl nitrate formation from the Deepwater Horizon oil spill atmospheric emissions

    NASA Astrophysics Data System (ADS)

    Neuman, J. A.; Aikin, K. C.; Atlas, E. L.; Blake, D. R.; Holloway, J. S.; Meinardi, S.; Nowak, J. B.; Parrish, D. D.; Peischl, J.; Perring, A. E.; Pollack, I. B.; Roberts, J. M.; Ryerson, T. B.; Trainer, M.

    2012-05-01

    Ozone (O3), alkyl nitrates (RONO2), and other photochemical products were formed in the atmosphere downwind from the Deepwater Horizon (DWH) oil spill by photochemical reactions of evaporating hydrocarbons with NOx (=NO + NO2) emissions from spill response activities. Reactive nitrogen species and volatile organic compounds (VOCs) were measured from an instrumented aircraft during daytime flights in the marine boundary layer downwind from the area of surfacing oil. A unique VOC mixture, where alkanes dominated the hydroxyl radical (OH) loss rate, was emitted into a clean marine environment, enabling a focused examination of O3 and RONO2 formation processes. In the atmospheric plume from DWH, the OH loss rate, an indicator of potential O3 formation, was large and dominated by alkanes with between 5 and 10 carbons per molecule (C5-C10). Observations showed that NOx was oxidized very rapidly with a 0.8 h lifetime, producing primarily C6-C10 RONO2 that accounted for 78% of the reactive nitrogen enhancements in the atmospheric plume 2.5 h downwind from DWH. Both observations and calculations of RONO2 and O3 production rates show that alkane oxidation dominated O3 formation chemistry in the plume. Rapid and nearly complete oxidation of NOx to RONO2 effectively terminated O3 production, with O3 formation yields of 6.0 ± 0.5 ppbv O3 per ppbv of NOx oxidized. VOC mixing ratios were in large excess of NOx, and additional NOx would have formed additional O3 in this plume. Analysis of measurements of VOCs, O3, and reactive nitrogen species and calculations of O3 and RONO2 production rates demonstrate that NOx-VOC chemistry in the DWH plume is explained by known mechanisms.

  11. Bio-inspired energy-harvesting mechanisms and patterns of dynamic soaring.

    PubMed

    Liu, Duo-Neng; Hou, Zhong-Xi; Guo, Zheng; Yang, Xi-Xiang; Gao, Xian-Zhong

    2017-01-30

    Albatrosses can make use of the dynamic soaring technique extracting energy from the wind field to achieve large-scale movement without a flap, which stimulates interest in effortless flight with small unmanned aerial vehicles (UAVs). However, mechanisms of energy harvesting in terms of the energy transfer from the wind to the flyer (albatross or UAV) are still indeterminate and controversial when using different reference frames in previous studies. In this paper, the classical four-phase Rayleigh cycle, includes sequentially upwind climb, downwind turn, downwind dive and upwind turn, is introduced in analyses of energy gain with the albatross's equation of motions and the simulated trajectory in dynamic soaring. Analytical and numerical results indicate that the energy gain in the air-relative frame mostly originates from large wind gradients at lower part of the climb and dive, while the energy gain in the inertial frame comes from the lift vector inclined to the wind speed direction during the climb, dive and downwind turn at higher altitude. These two energy-gain mechanisms are not equivalent in terms of energy sources and reference frames but have to be simultaneously satisfied in terms of the energy-neutral dynamic soaring cycle. For each reference frame, energy-loss phases are necessary to connect energy-gain ones. Based on these four essential phases in dynamic soaring and the albatrosses' flight trajectory, different dynamic soaring patterns are schematically depicted and corresponding optimal trajectories are computed. The optimal dynamic soaring trajectories are classified into two closed patterns including 'O' shape and '8' shape, and four travelling patterns including 'Ω' shape, 'α' shape, 'C' shape and 'S' shape. The correlation among these patterns are analysed and discussed. The completeness of the classification for different patterns is confirmed by listing and summarising dynamic soaring trajectories shown in studies over the past decades.

  12. Assessment of uncertainties of an aircraft-based mass balance approach for quantifying urban greenhouse gas emissions

    NASA Astrophysics Data System (ADS)

    Cambaliza, M. O. L.; Shepson, P. B.; Caulton, D. R.; Stirm, B.; Samarov, D.; Gurney, K. R.; Turnbull, J.; Davis, K. J.; Possolo, A.; Karion, A.; Sweeney, C.; Moser, B.; Hendricks, A.; Lauvaux, T.; Mays, K.; Whetstone, J.; Huang, J.; Razlivanov, I.; Miles, N. L.; Richardson, S. J.

    2014-09-01

    Urban environments are the primary contributors to global anthropogenic carbon emissions. Because much of the growth in CO2 emissions will originate from cities, there is a need to develop, assess, and improve measurement and modeling strategies for quantifying and monitoring greenhouse gas emissions from large urban centers. In this study the uncertainties in an aircraft-based mass balance approach for quantifying carbon dioxide and methane emissions from an urban environment, focusing on Indianapolis, IN, USA, are described. The relatively level terrain of Indianapolis facilitated the application of mean wind fields in the mass balance approach. We investigate the uncertainties in our aircraft-based mass balance approach by (1) assessing the sensitivity of the measured flux to important measurement and analysis parameters including wind speed, background CO2 and CH4, boundary layer depth, and interpolation technique, and (2) determining the flux at two or more downwind distances from a point or area source (with relatively large source strengths such as solid waste facilities and a power generating station) in rapid succession, assuming that the emission flux is constant. When we quantify the precision in the approach by comparing the estimated emissions derived from measurements at two or more downwind distances from an area or point source, we find that the minimum and maximum repeatability were 12 and 52%, with an average of 31%. We suggest that improvements in the experimental design can be achieved by careful determination of the background concentration, monitoring the evolution of the boundary layer through the measurement period, and increasing the number of downwind horizontal transect measurements at multiple altitudes within the boundary layer.

  13. The potential near-source ozone impacts of upstream oil and gas industry emissions.

    PubMed

    Olaguer, Eduardo P

    2012-08-01

    Increased drilling in urban areas overlying shale formations and its potential impact on human health through decreased air quality make it important to estimate the contribution of oil and gas activities to photochemical smog. Flares and compressor engines used in natural gas operations, for example, are large sources not only of NOx but also offormaldehyde, a hazardous air pollutant and powerful ozone precursor We used a neighborhood scale (200 m horizontal resolution) three-dimensional (3D) air dispersion model with an appropriate chemical mechanism to simulate ozone formation in the vicinity ofa hypothetical natural gas processing facility, based on accepted estimates of both regular and nonroutine emissions. The model predicts that, under average midday conditions in June, regular emissions mostly associated with compressor engines may increase ambient ozone in the Barnett Shale by more than 3 ppb beginning at about 2 km downwind of the facility, assuming there are no other major sources of ozone precursors. Flare volumes of 100,000 cubic meters per hour ofnatural gas over a period of 2 hr can also add over 3 ppb to peak 1-hr ozone somewhatfurther (>8 km) downwind, once dilution overcomes ozone titration and inhibition by large flare emissions of NOx. The additional peak ozone from the hypothetical flare can briefly exceed 10 ppb about 16 km downwind. The enhancements of ambient ozone predicted by the model are significant, given that ozone control strategy widths are of the order of a few parts per billion. Degrading the horizontal resolution of the model to 1 km spuriously enhances the simulated ozone increases by reducing the effectiveness of ozone inhibition and titration due to artificial plume dilution.

  14. Power-dependent speciation of volatile organic compounds in aircraft exhaust

    NASA Astrophysics Data System (ADS)

    Beyersdorf, Andreas J.; Thornhill, K. Lee; Winstead, Edward L.; Ziemba, Luke D.; Blake, Donald R.; Timko, Michael T.; Anderson, Bruce E.

    2012-12-01

    As part of the third NASA Aircraft Particle Emissions Experiment (APEX-3, November 2005), whole air samples were collected to determine the emission rates of volatile organic compounds (VOCs) from aircraft equipped with three different gas-turbine engines (an Allison Engine 3007-A1E, a Pratt-Whitney 4158, and a Rolls-Royce RB211-535E4B). Samples were collected 1 m behind the engine exhaust plane of the engines while they were operated at powers ranging from idle up to 30% of maximum rated thrust. Exhaust emission indices (mass emitted per kilogram of fuel used) for CO and non-methane hydrocarbons (NMHCs) were calculated based on enhancements over background relative to CO2. Emissions of all NMHCs were greatest at low power with values decreasing by an order of magnitude with increasing power. Previous studies have shown that scaling idle hydrocarbon emissions to formaldehyde or ethene (which are typically emitted at a ratio of 1-to-1 at idle) reduces variability amongst engine types. NMHC emissions were found to scale at low power, with alkenes contributing over 50% of measured NMHCs. However, as the power increases hydrocarbon emissions no longer scale to ethene, as the aromatics become the dominant species emitted. This may be due in part to a shift in combustion processes from thermal cracking (producing predominantly alkenes) to production of new molecules (producing proportionally more aromatics) as power increases. The formation of these aromatics is an intermediate step in the production of soot, which also increases with increasing power. The increase in aromatics relative to alkenes additionally results in a decrease in the hydroxyl radical reactivity and ozone formation potential of aircraft exhaust. Samples collected 30 m downwind of the engine were also analyzed for NMHCs and carbonyl compounds (acetone, 2-butanone and C1-C9 aldehydes). Formaldehyde was the predominant carbonyl emitted; however, the ratio of ethene-to-formaldehyde varied between the aircraft, possibly due to the sampling of transient emissions such as engine start-up and power changes. A large portion of the measured emissions (27-42% by mass) in the plume samples was made up of hazardous air pollutants (HAPs) with oxygenated compounds being most significant.

  15. Spatial and temporal variability of particulate polycyclic aromatic hydrocarbons in Mexico City

    NASA Astrophysics Data System (ADS)

    Thornhill, D. A.; de Foy, B.; Herndon, S. C.; Onasch, T. B.; Wood, E. C.; Zavala, M.; Molina, L. T.; Gaffney, J. S.; Marley, N. A.; Marr, L. C.

    2008-06-01

    As part of the Megacities Initiative: Local and Global Research Observations (MILAGRO) study in the Mexico City Metropolitan Area in March 2006, we measured particulate polycyclic aromatic hydrocarbons (PAHs) and other gaseous species and particulate properties, including light absorbing carbon or effective black carbon (BC), at six locations throughout the city. The measurements were intended to support the following objectives: to describe spatial and temporal patterns in PAH concentrations, to gain insight into sources and transformations of PAHs and BC, and to quantify the relationships between PAHs and other pollutants. Total particulate PAHs at the Instituto Mexicano del Petróleo (T0 supersite) located near downtown averaged 50 ng m-3, and aerosol active surface area averaged 80 mm2 m-3. PAHs were also measured on board the Aerodyne Mobile Laboratory, which visited six sites encompassing a mixture of different land uses and a range of ages of air parcels transported from the city core. A combination of analyses of time series, back trajectories, concentration fields, pollutant ratios, and correlation coefficients supports the concept of T0 as an urban source site, T1 as a receptor site with strong local sources, Pedregal and PEMEX as intermediate sites, Pico Tres Padres as a vertical receptor site, and Santa Ana as a downwind receptor site. Weak intersite correlations suggest that local sources are important and variable and that exposure to PAHs and BC cannot be represented by a single regional-scale value. The relationships between PAHs and other pollutants suggest that a variety of sources and ages of particles are present. Among carbon monoxide, nitrogen oxides (NOx), and carbon dioxide, particulate PAHs are most strongly correlated with NOx. Mexico City's PAH/BC mass ratio of 0.01 is similar to that found on a freeway loop in the Los Angeles area and approximately 8 30 times higher than that found in other cities. Evidence also suggests that primary combustion particles are rapidly coated by secondary aerosol in Mexico City. If so, their optical properties may change, and the lifetime of PAHs may be prolonged if the coating protects them against photodegradation or heterogeneous reactions.

  16. Fog composition at Baengnyeong Island in the eastern Yellow Sea: detecting markers of aqueous atmospheric oxidations

    NASA Astrophysics Data System (ADS)

    Boris, A. J.; Lee, T.; Park, T.; Choi, J.; Seo, S. J.; Collett, J. L., Jr.

    2016-01-01

    Samples of fog water were collected at Baengnyeong Island (BYI) in the Yellow Sea during the summer of 2014. The most abundant chemical species in the fog water were NH4+ (mean of 2220 µM), NO3- (1260 µM), SO4-2 (730 µM), and Na+ (551 µM), with substantial contributions from other species consistent with marine and biomass burning influence on some dates. The pH of the samples ranged between 3.48 and 5.00, with a mean of 3.94, intermediate within pH values of fog/cloud water reported previously in Southeast Asia. Back trajectories (72 h) showed that high relative humidity ( > 80 %) was encountered upwind of the sampling site by all but one of the sampled air masses, and that the fog composition at BYI can be impacted by several different source regions, including the Sea of Japan, southeastern China, northeastern China, and the East China Sea. Sulfur in the collected fog was highly oxidized: low S(IV) concentrations were measured (mean of 2.36 µM) in contrast to SO4-2 and in contrast to fog/cloud S(IV) concentrations from pollutant source regions; organosulfate species were also observed and were most likely formed through aging of mainly biogenic volatile organic compounds. Low-molecular-mass organic acids were major contributors to total organic carbon (TOC; 36-69 %), comprising a fraction of TOC at the upper end of that seen in fogs and clouds in other polluted environments. Large contributions were observed from not only acetic and formic acids but also oxalic, succinic, maleic, and other organic acids that can be produced in aqueous atmospheric organic processing (AAOP) reactions. These samples of East Asian fog water containing highly oxidized components represent fog downwind of pollutant sources and can provide new insight into the fate of regional emissions. In particular, these samples demonstrate the result of extensive photochemical aging during multiday transport, including oxidation within wet aerosols and fogs.

  17. Solar tracking system

    NASA Technical Reports Server (NTRS)

    White, P. R.; Scott, D. R. (Inventor)

    1981-01-01

    A solar tracker for a solar collector is described in detail. The collector is angularly oriented by a motor wherein the outputs of two side-by-side photodetectors are discriminated as to three ranges: a first corresponding to a low light or darkness condition; a second corresponding to light intensity lying in an intermediate range; and a third corresponding to light above an intermediate range, direct sunlight. The first output drives the motor to a selected maximum easterly angular position; the second enables the motor to be driven westerly at the Earth rotational rate; and the third output, the separate outputs of the two photodetectors, differentially controls the direction of rotation of the motor to effect actual tracking of the Sun.

  18. Cross sections for electron scattering by carbon disulfide in the low- and intermediate-energy range

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Brescansin, L. M.; Iga, I.; Lee, M.-T.

    2010-01-15

    In this work, we report a theoretical study on e{sup -}-CS{sub 2} collisions in the low- and intermediate-energy ranges. Elastic differential, integral, and momentum-transfer cross sections, as well as grand total (elastic + inelastic) and absorption cross sections, are reported in the 1-1000 eV range. A recently proposed complex optical potential composed of static, exchange, and correlation-polarization plus absorption contributions is used to describe the electron-molecule interaction. The Schwinger variational iterative method combined with the distorted-wave approximation is applied to calculate the scattering amplitudes. The comparison between our calculated results and the existing experimental and/or theoretical results is encouraging.

  19. 40 CFR 142.65 - Variances and exemptions from the maximum contaminant levels for radionuclides.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Raw water quality range &considerations 1 1. Ion exchange (IE) (a) Intermediate All ground waters. 2...-filtration. 5. Lime softening (d) Advanced All waters. 6. Green sand filtration (e) Basic. 7. Co-precipitation with barium sulfate (f) Intermediate to Advanced Ground waters with suitable water quality. 8...

  20. Mechanisms of deterioration of intermediate moisture food systems

    NASA Technical Reports Server (NTRS)

    Labuza, T. P.

    1972-01-01

    A study of shelf stability in intermediate moisture foods was made. Major efforts were made to control lipid oxidation and nonenzymatic browning. In order to determine means of preventing these reactions, model systems were developed having the same water activity content relationship of intermediate moisture foods. Models were based on a cellulose-lipid and protein-lipid system with glycerol added as the humectant. Experiments with both systems indicate that lipid oxidation is promoted significantly in the intermediate moisture range. The effect appeared to be related to increased mobility of either reactants or catalysts, since when the amount of water in the system reached a level where capillary condensation occurred and thus free water was present, the rates of oxidation increased. With added glycerol, which is water soluble and thus increases the amount of mobile phase, the increase in oxidation rate occurs at a lower relative humidity. The rates of oxidation were maximized at 61% RH and decreased again at 75% RH probably due to dilution. No significant non-enzymatic browning occurred in the protein-lipid systems. Prevention of oxidation by the use of metal chelating agents was enhanced in the cellulose system, whereas, with protein present, the lipid soluble chain terminating antioxidants (such as BHA) worked equally as well. Preliminary studies of foods adjusted to the intermediate moisture range bear out the results of oxidation in model systems. It can be concluded that for most fat containing intermediate moisture foods, rancidity will be the reaction most limiting stability.

  1. Tunable in-line fiber optic comb filter using a side-polished single-mode fiber coupler with LiNbO 3 overlay and intermediate coupling layer

    NASA Astrophysics Data System (ADS)

    Sohn, Kyung-Rak; Song, Jae-Won

    2002-03-01

    Using a side-polished single-mode fiber covered with a polished LiNbO 3 overlay and an intermediate coupling layer, tunable fiber-optic comb filters are demonstrated. The device behaviors based on the modal properties of the fiber and the planar LiNbO 3 waveguide are analyzed by two dimensional beam propagation methods (2-D BPM) and discussed the role of an intermediate coupling layer in terms of coupling efficiency. We also show that the thermo-optic effects of this layer can be utilized to tune the comb filter. When the polished x-cut LiNbO 3 with 200 μm thickness is used as a multimode overlay waveguide, the comb output spectra with free spectral range of 4 nm are measured in 1550 nm wavelength range. The tuning rate as a function of the refractive index of an intermediate coupling layer, Δλ/ Δnb, is about -0.129 nm/-0.001. The experimental results are in good agreement with the calculated results.

  2. Modeling the impact of solid noise barriers on near road air quality

    EPA Science Inventory

    Studies based on field measurements, wind tunnel experiments, and controlled tracer gas releases indicate that solid, roadside noise barriers can lead to reductions in downwind near-road air pollutant concentrations. A tracer gas study showed that a solid barrier reduced pollutan...

  3. Roadside vegetation design characteristics that can improve local, near-road air quality

    EPA Science Inventory

    Roadside vegetation has been shown to impact downwind, near-road air quality, leading to both reductions and increases in pollutant concentrations which has led to confusion regarding the capability of vegetative barriers to mitigate near-road air pollution. These roadside veget...

  4. An LES study of vertical-axis wind turbine wakes aerodynamics

    NASA Astrophysics Data System (ADS)

    Abkar, Mahdi; Dabiri, John O.

    2016-11-01

    In this study, large-eddy simulation (LES) combined with a turbine model is used to investigate the structure of the wake behind a vertical-axis wind turbine (VAWT). In the simulations, a recently developed minimum dissipation model is used to parameterize the subgrid-scale stress tensor, while the turbine-induced forces are modeled with an actuator-line technique. The LES framework is first tested in the simulation of the wake behind a model straight-bladed VAWT placed in the water channel, and then used to study the wake structure downwind of a full-scale VAWT sited in the atmospheric boundary layer. In particular, the self-similarity of the wake is examined, and it is found that the wake velocity deficit is well characterized by a two-dimensional elliptical Gaussian distribution. By assuming a self-similar Gaussian distribution of the velocity deficit, and applying mass and momentum conservation, an analytical model is developed and tested to predict the maximum velocity deficit downwind of the turbine.

  5. PM2.5 and Carbon Emissions from Prescribed Fire in a Longleaf Pine Ecosystem

    NASA Astrophysics Data System (ADS)

    Strenfel, S. J.; Clements, C. B.; Hiers, J. K.; Kiefer, C. M.

    2008-12-01

    Prescribed fires are a frequently utilized land-management tool in the Southeastern US. In order to better characterize emissions and impacts from prescribed fire in longleaf pine ecosystems, in situ data were obtained within the burn perimeter using a 10-m instrumented flux tower. Turbulence and temperature data at 10-m were sampled at 10 Hz using a sonic anemometer and fine-wire thermocouples respectively. Measurements of PM2.5, CO and CO2 emissions were sampled at 10-m within the burn perimeter and PM2.5 and Black Carbon PM2.5 were sampled 0.5 km downwind of the fire front using a 2-m instrumented tripod. Preliminary results indicate PM2.5 and carbon emissions significantly increased during the fire-front passage, and downwind PM concentrations were amplified beyond pre-fire ambient concentrations. In addition, the considerable amount a heat release and flux data gathered from these prescribed fires suggests that near surface atmospheric conditions were directly impacted by increased turbulence generation.

  6. Using Atmospheric Dispersion Theory to Inform the Design of a Short-lived Radioactive Particle Release Experiment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rishel, Jeremy P.; Keillor, Martin E.; Arrigo, Leah M.

    2016-01-01

    Atmospheric dispersion theory can be used to predict ground deposition of particulates downwind of a radionuclide release. This paper utilizes standard formulations found in Gaussian plume models to inform the design of an experimental release of short-lived radioactive particles into the atmosphere. Specifically, a source depletion algorithm is used to determine the optimum particle size and release height that maximizes the near-field deposition while minimizing the both the required source activity and the fraction of activity lost to long-distance transport. The purpose of the release is to provide a realistic deposition pattern that might be observed downwind of a small-scalemore » vent from an underground nuclear explosion. The deposition field will be used, in part, to investigate several techniques of gamma radiation survey and spectrometry that could be utilized by an On-Site Inspection team under the verification regime of the Comprehensive Nuclear-Test-Ban Treaty.« less

  7. Barchan Pac-Man

    NASA Image and Video Library

    2018-05-14

    This image from NASA's Mars Reconnaissance Orbiter shows barchan sand dunes, common on Mars and often forming vast dune fields within very large (tens to hundreds of kilometers) impact basins. The regions upwind of barchans are usually devoid of sandy bedforms, so if you were walking in a downwind direction, then the barchans would seem to appear out of nowhere. As you walk downwind, you would notice the barchans link up ("joining arms") and eventually slope into featureless sand sheets. We call this progression of dunes a "Herschel-type dune field" named after the first place this sequence was described: Herschel Crater. But here is something interesting: a barchan dune filling the upwind portion of a small impact crater in a Pac-Man-like shape. This "dune-in-a-crater" is nearly at the highest extent of the field. It is also probably a rare configuration, and over the next few tens of thousands of years the sand will be blown out of the crater. https://photojournal.jpl.nasa.gov/catalog/PIA22456

  8. Femoral curvature variability in modern humans using three-dimensional quadric surface fitting.

    PubMed

    Chapman, Tara; Sholukha, Victor; Semal, Patrick; Louryan, Stéphane; Rooze, Marcel; Van Sint Jan, Serge

    2015-12-01

    This study analysed femoral curvature in a population from Belgium in conjunction with other morphological characteristics by the use of three-dimensional (3D) quadric surfaces (QS) modelled from the bone surface. 3D models were created from computed tomography data of 75 femoral modern human bones. Anatomical landmarks (ALs) were palpated in specific bony areas of the femur (shaft, condyles, neck and head). QS were then created from the surface vertices which enclose these ALs. The diaphyseal shaft was divided into five QS shapes to analyse curvature in different parts of the shaft. Femoral bending differs in different parts of the diaphyseal shaft. The greatest degree of curvature was found in the distal shaft (mean 4.5° range 0.2°-10°) followed by the proximal (mean 4.4° range 1.5°-10.2°), proximal intermediate (mean 3.7° range 0.9°-7.9°) and distal intermediate (mean 1.8° range 0.2°-5.6°) shaft sections. The proximal and distal angles were significantly more bowed than the intermediate proximal and the intermediate distal angle. There was no significant difference between the proximal and distal angle. No significant correlations were found between morphological characteristics and femoral curvature. An extremely large variability of femoral curvature with several bones displaying very high or low degrees of femoral curvature was also found. 3D QS fitting enables the creation of accurate models which can discriminate between different patterns in similar curvatures and demonstrates there is a clear difference between curvature in different parts of the shaft.

  9. CCN Activity of Organic Aerosols Observed Downwind of Urban Emissions during CARES

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mei, Fan; Setyan, Ari; Zhang, Qi

    2013-12-17

    During the Carbonaceous Aerosols and Radiative Effects Study (CARES), activation fraction of size-resolved aerosol particles and aerosol chemical composition were characterized at the T1 site (~60 km downwind of Sacramento, California) from 10 June to 28 June 2010. The hygroscopicity of CCN-active particles (K CCN) with diameter from 100 to 170 nm, derived from the size-resolved activated fraction, varied from 0.10 to 0.21, with an average of 0.15, which was substantially lower than that proposed for continental sites in earlier studies. The low K CCN value was due to the high organic volume fraction, averaged over 80% at the T1more » site. The derived K CCN exhibited little diurnal variation, consistent with the relatively constant organic volume fraction observed. At any time, over 90% of the size selected particles with diameter between 100 and 171nm were CCN active, suggesting most particles within this size range were aged background particles. Due to the large organic volume fraction, organic hygroscopicity (K org) strongly impacted particle hygroscopicity and therefore calculated CCN concentration. For vast majority of the cases, an increase of K org from 0.03 to 0.18, which are within the typical range, doubled the calculated CCN concentration. Organic hygroscopicity was derived from K CCN and aerosol chemical composition, and its variations with the fraction of total organic mass spectral signal at m/z 44 (f 44) and O:C were compared to results from previous studies. Overall, the relationships between K org and f 44 are quite consistent for organic aerosol (OA) observed during field studies and those formed in smog chamber. Compared to the relationship between K org and f 44, the relationship between K org and O:C exhibits more significant differences among different studies, suggesting korg may be better parameterized using f 44. A least squares fit yielded K org = 2.10 (±0.07) × f 44 -0.11 (±0.01) with the Pearson R 2 value of 0.71. One possible explanation for the stronger correlation between K org and f 44 is that the m/z 44 signal (mostly contributed by the CO 2 + ion) is more closely related to organic acids, which may dominate the overall korg due to their relatively high water solubility and hygroscopicity.« less

  10. Application of a combined measurement and modeling method to quantify windblown dust emissions from the exposed playa at Mono Lake, California.

    PubMed

    Ono, Duane; Kiddoo, Phill; Howard, Christopher; Davis, Guy; Richmond, Kenneth

    2011-10-01

    Particulate matter < or =10 microm (PM10) emissions due to wind erosion can vary dramatically with changing surface conditions. Crust formation, mechanical disturbance, soil texture, moisture, and chemical content of the soil can affect the amount of dust emitted during a wind event. A refined method of quantifying windblown dust emissions was applied at Mono Lake, CA, to account for changing surface conditions. This method used a combination of real-time sand flux monitoring, ambient PM10 monitoring, and dispersion modeling to estimate dust emissions and their downwind impact. The method identified periods with high emissions and periods when the surface was stable (no sand flux), even though winds may have been high. A network of 25 Cox sand catchers (CSCs) was used to measure the mass of saltating particles to estimate sand flux rates across a 2-km2 area. Two electronic sensors (Sensits) were used to time-resolve the CSC sand mass to estimate hourly sand flux rates, and a perimeter tapered element oscillating microbalance (TEOM) monitor measured hourly PM10 concentrations. Hourly sand flux rates were related by dispersion modeling to hourly PM10 concentrations to back-calculate the ratio of vertical PM10 flux to horizontal sand flux (K-factors). Geometric mean K-factor values (K(f)) were found to change seasonally, ranging from 1.3 x 10(-5) to 5.1 x 10(-5) for sand flux measured at 15 cm above the surface (q15). Hourly PM10 emissions, F, were calculated by applying seasonal K-factors to sand flux measurements (F = K(f) x q15). The maximum hourly PM10 emission rate from the study area was 76 g/m2 x hr (10-m wind speed = 23.5 m/sec). Maximum daily PM10 emissions were estimated at 450 g/m2 x day, and annual emissions at 1095 g/m2 x yr. Hourly PM10 emissions were used by the U.S. Environmental Protection Agency (EPA) guideline AERMOD dispersion model to estimate downwind ambient impacts. Model predictions compared well with monitor concentrations, with hourly PM10 ranging from 16 to over 60,000 microg/m3 (slope = 0.89, R2 = 0.77).

  11. Vegetative environmental buffers for reducing downwind odor and VOCs from tunnel-ventilated swine barn

    USDA-ARS?s Scientific Manuscript database

    Scientists have investigated methods for reducing odor emissions from livestock buildings for decades, yet few technologies have proven effective. Vegetative Environmental Buffers (VEBs), which are specially designed combinations of trees, shrubs and grasses, have shown promise in recent years for ...

  12. Federal Implementation Plans: Interstate Transport of Fine Particulate Matter and Ozone and Correction of SIP Approvals (76 FR 48208)

    EPA Pesticide Factsheets

    In this action, EPA limits the interstate transport of emissions of nitrogen oxides (NOX) and sulfur dioxide (SO2) that contribute to harmful levels of fine particle matter (PM2.5) and ozone in downwind states.

  13. Atmospheric stability determination at different time intervals for determination of aerial application timing

    USDA-ARS?s Scientific Manuscript database

    Determination of atmospheric conditions for proper timing of spray application is important to prevent off-target movement of crop protection materials. Susceptible crops can be injured downwind if proper application procedure is not followed. In our previous study, hourly data indicated unfavorable...

  14. Model evaluation of roadside barrier impact on near-road air pollution

    EPA Science Inventory

    Roadside noise barriers are common features along major highways in urban regions and are anticipated to have important effects on near-road air pollution – the occurrence of elevated air pollutant concentrations for several hundred meters downwind of a major roadway. A 3-dimens...

  15. Dispersion model studies for Space Shuttle environmental effects activities

    NASA Technical Reports Server (NTRS)

    1981-01-01

    The NASA/MSFC REED computer code was developed for predicting concentrations, dosage, and deposition downwind from rocket vehicle launches. The calculation procedures and results of nine studies using the code are presented. Topics include plume expansion, hydrazine concentrations, and hazard calculations for postulated fuel spills.

  16. Using Smart Planning to Mitigate Drought in Urban Areas: A Seasonal Simulation of the Impact of Urbanization on Precipitation in the Indianapolis Region

    NASA Astrophysics Data System (ADS)

    Schmid, P. E.; Niyogi, D.

    2012-12-01

    The Indianapolis region exhibits a precipitation distribution indicative of urban weather modification: negative bias upwind and positive bias downwind. The causes for such a distribution within an urban area arise from a combination of land-surface heterogeneity and urban aerosol-cloud interaction. This study investigates the causes of the precipitation distribution with a 120-day simulation using the Regional Atmospheric Modeling System (RAMS) coupled with the Town Energy Budget (TEB) model. Using a nested grid with a maximum resolution of 500m, a seasonal simulation of May through August, 2008 is conducted. Land surface conditions are varied, removing, expanding, and intensifying the Indianapolis urban area. Aerosol conditions are scaled by a three-dimensional combination of MODIS and CALIPSO observations, and varied in concentration and plume extent. Results from the study demonstrate the paradigm of urban precipitation modification on a seasonal time scale. The boundary between the rural and urban land surfaces weakens approaching systems upwind, decreasing precipitation in the city center. A larger urban extent diminishes the systems further. The aerosol plume downwind increases cloud lifetimes via cloud-nucleating aerosol, then invigorates precipitation via large drizzle-invigorating aerosols. The overall effect reproduces the observed negative precipitation bias upwind and positive bias downwind of the urban center. A lower concentration of aerosols leads to a higher proportion of stratiform rain over a larger area, whereas a higher concentration of aerosols leads to more convective rain and heavy rain events. This manifests in a weekly cycle of precipitation with rain most likely on weekends, and with less frequent but heavier rain events most likely during midweek, when aerosol concentrations are the highest. More intense urbanization, via both land surface and aerosol effects, creates more frequent heavy rainfall events and exacerbates dry-periods, potentially leading to premature drought onset. The wetter than average May, June, and July received more total rainfall from the heavy rainfall events, while the dry August became drier due to lack of stratiform precipitation. Smart planning solutions can partially mitigate the urban precipitation problem. In a simulation where a more intense urban Indianapolis is surrounded by a greenbelt and green roofs are implemented in the city, the urban precipitation bias becomes less significant. Upwind, the greenbelt provides surface moisture and mitigates how much precipitation systems weaken. Downwind, the greenbelt slows the transport of drizzle-invigorating aerosol, reducing the heavy rain events. The green roofs reduce the urban-rural gradient and slow the initial weakening of systems.

  17. Dynamics of skimming flow in the wake of a vegetation patch

    NASA Astrophysics Data System (ADS)

    Mayaud, Jerome R.; Wiggs, Giles F. S.; Bailey, Richard M.

    2016-09-01

    Dryland vegetation is often spatially patchy, and so affects wind flow in complex ways. Theoretical models and wind tunnel testing have shown that skimming flow develops above vegetation patches at high plant densities, resulting in little or no wind erosion in these zones. Understanding the dynamics of skimming flow is therefore important for predicting sediment transport and bedform development in dryland areas. However, no field-based data are available describing turbulent airflow dynamics in the wake of vegetation patches. In this study, turbulent wind flow was examined using high-frequency (10 Hz) sonic anemometry at four measurement heights (0.30 m, 0.55 m, 1.10 m and 1.65 m) along a transect in the lee of an extensive patch of shrubs (z = 1.10 m height) in Namibia. Spatial variations in mean wind velocity, horizontal Reynolds stresses and coherent turbulent structures were analysed. We found that wind velocity in the wake of the patch effectively recovered over ∼12 patch heights (h) downwind, which is 2-5 h longer than previously reported recovery lengths for individual vegetation elements and two-dimensional wind fences. This longer recovery can be attributed to a lack of flow moving around the obstacle in the patch case. The step-change in roughness between the patch canopy and the bare surface in its wake resulted in an initial peak in resultant horizontal shear stress (τr) followed by significant decrease downwind. In contrast to τr , horizontal normal Reynolds stress (u‧2 ‾) progressively increased along the patch wake. A separation of the upper shear layer at the leeside edge of the patch was observed, and a convergence of τr curves implies the formation of a constant stress layer by ∼20 h downwind. The use of τr at multiple heights is found to be a useful tool for identifying flow equilibration in complex aerodynamic regimes. Quadrant analysis revealed elevated frequencies of Q2 (ejection) and Q4 (sweep) events in the immediate lee of the patch, which contributed to the observed high levels of shear stress. The increasing downwind contribution of Q1 (outward interaction) events, which coincides with greater u‧2 ‾ and wind velocity, suggests that sediment transport potential increases with greater distance from the patch edge. Determining realistic, field-derived constraints on turbulent airflow dynamics in the wakes of vegetation patches is crucial for accurately parameterising sediment transport potential in larger-scale dryland landscape models. This will help to improve our understanding of how semi-vegetated desert surfaces might react to future environmental and anthropogenic stresses.

  18. Microbial Ecology of a Crewed Rover Traverse in the Arctic: Low Microbial Dispersal and Implications for Planetary Protection on Human Mars Missions.

    PubMed

    Schuerger, Andrew C; Lee, Pascal

    2015-06-01

    Between April 2009 and July 2011, the NASA Haughton-Mars Project (HMP) led the Northwest Passage Drive Expedition (NWPDX), a multi-staged long-distance crewed rover traverse along the Northwest Passage in the Arctic. In April 2009, the HMP Okarian rover was driven 496 km over sea ice along the Northwest Passage, from Kugluktuk to Cambridge Bay, Nunavut, Canada. During the traverse, crew members collected samples from within the rover and from undisturbed snow-covered surfaces around the rover at three locations. The rover samples and snow samples were stored at subzero conditions (-20°C to -1°C) until processed for microbial diversity in labs at the NASA Kennedy Space Center, Florida. The objective was to determine the extent of microbial dispersal away from the rover and onto undisturbed snow. Interior surfaces of the rover were found to be associated with a wide range of bacteria (69 unique taxa) and fungi (16 unique taxa). In contrast, snow samples from the upwind, downwind, uptrack, and downtrack sample sites exterior to the rover were negative for both bacteria and fungi except for two colony-forming units (cfus) recovered from one downwind (1 cfu; site A4) and one uptrack (1 cfu; site B6) sample location. The fungus, Aspergillus fumigatus (GenBank JX517279), and closely related bacteria in the genus Brevibacillus were recovered from both snow (B. agri, GenBank JX517278) and interior rover surfaces. However, it is unknown whether the microorganisms were deposited onto snow surfaces at the time of sample collection (i.e., from the clothing or skin of the human operator) or via airborne dispersal from the rover during the 12-18 h layovers at the sites prior to collection. Results support the conclusion that a crewed rover traveling over previously undisturbed terrain may not significantly contaminate the local terrain via airborne dispersal of propagules from the vehicle.

  19. Investigating the Impacts of Wildfires on Air Quality in the Western US

    NASA Astrophysics Data System (ADS)

    Yates, E. L.; Iraci, L. T.; Singh, H. B.; Ambrosia, V. G.; Clements, C. B.; Gore, W.; Lareau, N.; Quayle, B.; Ryoo, J. M.; Schroeder, W.; Tanaka, T.

    2015-12-01

    Wildfire emissions are an important source of a wide range of trace gases and particles that can impact local, regional and global air quality, climate forcing, biogeochemical cycles and human health. In the western US, wildfires dominate over prescribed fires. However, limited sampling of wildfire emissions means western US emission estimates rely largely on data from prescribed fires, which may not be a suitable proxy for wildfire emissions. Further, interactions of wildfire emissions with urban pollution, commonly the case with California wildfires, are complex and poorly understood. The Alpha Jet Atmospheric eXperiment (AJAX) sampled a variety of Californian wildfire plumes during 2013 and 2014. In addition to wildfire plumes, flights sample upwind, background conditions allowing for an assessment of enhancement ratios of trace gas species (carbon dioxide, methane and ozone). This paper presents airborne measurements of multiple trace constituents downwind of a variety of Californian wildfires, with a focus on the exceptionally large Yosemite Rim wildfire during summer 2013. During its intense burning phases, the Rim wildfire was sampled by AJAX on 29 August as well as by the NASA DC-8, as part of its SEAC4RS mission, on 26 and 27 August. AJAX revisited the wildfire on 10 September when it had reached its smoldering phase. The more extensive payload of the DC-8 helped to bridge key measurements that were not available as part of the AJAX payload (e. g. carbon monoxide). The emission ratios (ER), emission factors (EF) and combustion efficiency are compared with previous wildfire studies. Integration of AJAX data with other available datasets, such as SEAC4RS, Lidar data from the California State University Mobile Atmospheric Profiling System (CSU-MAPS), MODIS/VIIRS Fire Radiative Power (FRP) and surface ozone and meteorology measurements is explored to assess the impacts of wildfires on downwind air quality including the densely populated California central valley.

  20. Wind-mediated horseweed (Conyza canadensis) gene flow: pollen emission, dispersion, and deposition.

    PubMed

    Huang, Haiyan; Ye, Rongjian; Qi, Meilan; Li, Xiangzhen; Miller, David R; Stewart, Charles Neal; DuBois, David W; Wang, Junming

    2015-07-01

    Horseweed (Conyza canadensis) is a problem weed in crop production because of its evolved resistance to glyphosate and other herbicides. Although horseweed is mainly self-pollinating, glyphosate-resistant (GR) horseweed can pollinate glyphosate-susceptible (GS) horseweed. To the best of our knowledge, however, there are no available data on horseweed pollen production, dispersion, and deposition relative to gene flow and the evolution of resistance. To help fill this knowledge gap, a 43-day field study was performed in Champaign, Illinois, USA in 2013 to characterize horseweed atmospheric pollen emission, dispersion, and deposition. Pollen concentration and deposition, coupled with atmospheric data, were measured in a source field (180 m by 46 m) and its surrounding areas up to 1 km downwind horizontally and up to 100 m vertically. The source strength (emission rate) ranged from 0 to 140 pollen grains per plant per second (1170 to 2.1×10(6) per plant per day). For the life of the study, the estimated number of pollen grains generated from this source field was 10.5×10(10) (2.3×10(6) per plant). The release of horseweed pollen was not strongly correlated to meteorological data and may be mainly determined by horseweed physiology. Horseweed pollen reached heights of 80 to100 m, making long-distance transport possible. Normalized (by source data) pollen deposition with distance followed a negative-power exponential curve. Normalized pollen deposition was 2.5% even at 480 m downwind from the source edge. Correlation analysis showed that close to or inside the source field at lower heights (≤3 m) vertical transport was related to vertical wind speed, while horizontal pollen transport was related to horizontal wind speed. High relative humidity prevented pollen transport at greater heights (3-100 m) and longer distances (0-1000 m) from the source. This study can contribute to the understanding of how herbicide-resistance weeds or invasive plants affect ecology through wind-mediated pollination and invasion.

  1. Trends in Gypsiferous Aerosol Downwind of White Sands, New Mexico

    NASA Astrophysics Data System (ADS)

    White, W. H.; Trzepla, K.; Yatkin, S.; Gill, T. E.; Jin, L.

    2013-12-01

    White Sands is a known 'hotspot' of dust emissions in southwestern North America where an active gypsum dunefield abuts erodible playa sediments. Aerosols entrained from White Sands are sometimes visible on satellite images as distinct, light-colored plumes crossing the Sacramento Mountains to the northeast. The U.S. Forest Service operates an aerosol sampler at White Mountain in the lee of the Sacramento range as part of the IMPROVE network (Interagency Monitoring of PROtected Visual Environments). In recent years a spring pulse of sulfate aerosol has appeared at White Mountain, eclipsing the regional summer peak attributed to atmospheric reactions of sulfur dioxide emissions. A significant fraction of this spring sulfate is contributed by gypsum and other salts from White Sands, with clearly increased concentrations of calcium, strontium, and chloride. The increase in these species coincides with a drought following a period of above-average precipitation. White Sands and White Mountain thus provide an unusually well-defined natural laboratory: a climatically sensitive dust source that is both well characterized and chemically distinct from its surroundings, with a signature that remains identifiably distinct at a long-term observatory ~100 km downwind. This paper examines the routine PM2.5 (fine-particle, Dp < 2.5 um) composition data available from White Mountain and other regional IMPROVE sites (e.g. Bosque del Apache), supplemented by some elemental analysis of collocated PM10 samples. The ambient data are compared with chemical analyses of surface samples from White Sands, bulk dry dustfall and soil surface composition at White Mountain, satellite observations of dust plumes, and available meteorological records. Together, the observations document significant, episodic aeolian transport of gypsum and other salts across the Sacramento Mountains. Figure 1. Left: Monthly average concentrations of every-third-day 24h samples. Top right: MODIS image, 2/28/2012, http://earthobservatory.nasa.gov/NaturalHazards/view.php?id=77294). Bottom right: Correlation (r) matrix for 2011 daily elemental data from White Mountain (n = 105).

  2. Wind-Related Orientation Patterns in Diurnal, Crepuscular and Nocturnal High-Altitude Insect Migrants

    PubMed Central

    Hu, Gao; Lim, Ka Sing; Reynolds, Don R.; Reynolds, Andy M.; Chapman, Jason W.

    2016-01-01

    Most insect migrants fly at considerable altitudes (hundreds of meters above the ground) where they utilize fast-flowing winds to achieve rapid and comparatively long-distance transport. The nocturnal aerial migrant fauna has been well studied with entomological radars, and many studies have demonstrated that flight orientations are frequently grouped around a common direction in a range of nocturnal insect migrants. Common orientation typically occurs close to the downwind direction (thus ensuring that a large component of the insects’ self-powered speed is directed downstream), and in nocturnal insects at least, the downwind headings are seemingly maintained by direct detection of wind-related turbulent cues. Despite being far more abundant and speciose, the day-flying windborne migrant fauna has been much less studied by radar; thus the frequency of wind-related common orientation patterns and the sensory mechanisms involved in their formation remain to be established. Here, we analyze a large dataset of >600,000 radar-detected “medium-sized” windborne insect migrants (body mass from 10 to 70 mg), flying hundreds of meters above southern UK, during the afternoon, in the period around sunset, and in the middle of the night. We found that wind-related common orientation was almost ubiquitous during the day (present in 97% of all “migration events” analyzed), and was also frequent at sunset (85%) and at night (81%). Headings were systematically offset to the right of the flow at night-time (as predicted from the use of turbulence cues for flow assessment), but there was no directional bias in the offsets during the day or at sunset. Orientation “performance” significantly increased with increasing flight altitude throughout the day and night. We conclude by discussing sensory mechanisms which most likely play a role in the selection and maintenance of wind-related flight headings. PMID:26973481

  3. Quantitative Microbial Risk Assessment for Spray Irrigation of Dairy Manure Based on an Empirical Fate and Transport Model

    PubMed Central

    Burch, Tucker R.; Spencer, Susan K.; Stokdyk, Joel P.; Kieke, Burney A.; Larson, Rebecca A.; Firnstahl, Aaron D.; Rule, Ana M.

    2017-01-01

    Background: Spray irrigation for land-applying livestock manure is increasing in the United States as farms become larger and economies of scale make manure irrigation affordable. Human health risks from exposure to zoonotic pathogens aerosolized during manure irrigation are not well understood. Objectives: We aimed to a) estimate human health risks due to aerosolized zoonotic pathogens downwind of spray-irrigated dairy manure; and b) determine which factors (e.g., distance, weather conditions) have the greatest influence on risk estimates. Methods: We sampled downwind air concentrations of manure-borne fecal indicators and zoonotic pathogens during 21 full-scale dairy manure irrigation events at three farms. We fit these data to hierarchical empirical models and used model outputs in a quantitative microbial risk assessment (QMRA) to estimate risk [probability of acute gastrointestinal illness (AGI)] for individuals exposed to spray-irrigated dairy manure containing Campylobacter jejuni, enterohemorrhagic Escherichia coli (EHEC), or Salmonella spp. Results: Median risk estimates from Monte Carlo simulations ranged from 10−5 to 10−2 and decreased with distance from the source. Risk estimates for Salmonella or EHEC-related AGI were most sensitive to the assumed level of pathogen prevalence in dairy manure, while risk estimates for C. jejuni were not sensitive to any single variable. Airborne microbe concentrations were negatively associated with distance and positively associated with wind speed, both of which were retained in models as a significant predictor more often than relative humidity, solar irradiation, or temperature. Conclusions: Our model-based estimates suggest that reducing pathogen prevalence and concentration in source manure would reduce the risk of AGI from exposure to manure irrigation, and that increasing the distance from irrigated manure (i.e., setbacks) and limiting irrigation to times of low wind speed may also reduce risk. https://doi.org/10.1289/EHP283 PMID:28885976

  4. Aircraft trace gas measurements during the London 2012 Olympics: Air quality and emission fluxes derived from sampling upwind and downwind of a megacity

    NASA Astrophysics Data System (ADS)

    Allen, G.; O'Shea, S.; Muller, J.; Jones, B.; O'Sullivan, D.; Lee, J. D.; Bauguitte, S.; Gallagher, M. W.; Percival, C.; Barratt, B.; McQuaid, J. B.; Illingworth, S.

    2013-12-01

    This study presents airborne in situ and remote sensing measurements recorded during July and August 2012, across the period of the London 2012 Summer Olympics and simultaneous with the Clear air for London (ClearfLo) ground-based measurement and modelling campaign. Through long-term (2-year) and intensive observation periods (Winter 2011 and Summer 2012), the ClearfLo programme aims to better understand emissions, as well as the chemical, dynamical and micro-meteorological processes which modulate air quality in the London urban environment - an important risk factor for both acute and chronic health effects. The work presented here focuses on two contrasting case studies within the summer ClearfLo period: 30 July 2012 and 9 August 2012, representing relatively clean background and polluted background cases, respectively, and characterised by well-mixed Atlantic westerly maritime inflow in the former and stagnant air (high pressure) in the latter. Measurements of CO, CO2, CH4, N2O, O3, HCN, and other gases measured on board the UK Facility for Airborne Atmospheric Measurement (FAAM) BAe-146 aircraft will be presented and interpreted, with emphasis on observed concentration gradients and tracer-tracer correlations as well as airmass vertical structure and airmass history upwind and downwind of central London in each case. By applying a simple advective model and making use of vertically resolved thermodynamic and composition data, we are able to derive emission strengths for these gases that are representative of the total enclosed surface area. Example emissions for these two cases range between 6x105 kg(C)/hr and 9x105 kg(C)/hr for CO2, and ~0.6x105 kg(C)/hr for CH4. This airborne sampling methodology highlights the unique utility of aircraft measurements to routinely and climatologically characterise emissions from area sources such as cities, and points to future missions to target localised hotspots and distributed point sources.

  5. Structure of the airflow above surface waves

    NASA Astrophysics Data System (ADS)

    Buckley, Marc; Veron, Fabrice

    2016-04-01

    Weather, climate and upper ocean patterns are controlled by the exchanges of momentum, heat, mass, and energy across the ocean surface. These fluxes are, in turn, influenced by the small-scale physics at the wavy air-sea interface. We present laboratory measurements of the fine-scale airflow structure above waves, achieved in over 15 different wind-wave conditions, with wave ages Cp/u* ranging from 1.4 to 66.7 (where Cp is the peak phase speed of the waves, and u* the air friction velocity). The experiments were performed in the large (42-m long) wind-wave-current tank at University of Delaware's Air-Sea Interaction laboratory (USA). A combined Particle Image Velocimetry and Laser Induced Fluorescence system was specifically developed for this study, and provided two-dimensional airflow velocity measurement as low as 100 um above the air-water interface. Starting at very low wind speeds (U10~2m/s), we directly observe coherent turbulent structures within the buffer and logarithmic layers of the airflow above the air-water interface, whereby low horizontal velocity air is ejected away from the surface, and higher velocity fluid is swept downward. Wave phase coherent quadrant analysis shows that such turbulent momentum flux events are wave-phase dependent. Airflow separation events are directly observed over young wind waves (Cp/u*<3.7) and counted using measured vorticity and surface viscous stress criteria. Detached high spanwise vorticity layers cause intense wave-coherent turbulence downwind of wave crests, as shown by wave-phase averaging of turbulent momentum fluxes. Mean wave-coherent airflow motions and fluxes also show strong phase-locked patterns, including a sheltering effect, upwind of wave crests over old mechanically generated swells (Cp/u*=31.7), and downwind of crests over young wind waves (Cp/u*=3.7). Over slightly older wind waves (Cp/u* = 6.5), the measured wave-induced airflow perturbations are qualitatively consistent with linear critical layer theory.

  6. Quantitative microbial risk assessment for spray irrigation of dairy manure based on an empirical fate and transport model

    USGS Publications Warehouse

    Burch, Tucker R; Spencer, Susan K.; Stokdyk, Joel; Kieke, Burney A; Larson, Rebecca A; Firnstahl, Aaron; Rule, Ana M; Borchardt, Mark A.

    2017-01-01

    BACKGROUND: Spray irrigation for land-applying livestock manure is increasing in the United States as farms become larger and economies of scale make manure irrigation affordable. Human health risks from exposure to zoonotic pathogens aerosolized during manure irrigation are not well understood. OBJECTIVES: We aimed to a) estimate human health risks due to aerosolized zoonotic pathogens downwind of spray-irrigated dairy manure; and b) determine which factors (e.g., distance, weather conditions) have the greatest influence on risk estimates. METHODS: We sampled downwind air concentrations of manure-borne fecal indicators and zoonotic pathogens during 21 full-scale dairy manure irri- gation events at three farms. We fit these data to hierarchical empirical models and used model outputs in a quantitative microbial risk assessment (QMRA) to estimate risk [probability of acute gastrointestinal illness (AGI)] for individuals exposed to spray-irrigated dairy manure containing Campylobacter jejuni, enterohemorrhagic Escherichia coli (EHEC), or Salmonella spp. RESULTS: Median risk estimates from Monte Carlo simulations ranged from 10−5 to 10−2 and decreased with distance from the source. Risk estimates for Salmonella or EHEC-related AGI were most sensitive to the assumed level of pathogen prevalence in dairy manure, while risk estimates for C. jejuni were not sensitive to any single variable. Airborne microbe concentrations were negatively associated with distance and positively associated with wind speed, both of which were retained in models as a significant predictor more often than relative humidity, solar irradiation, or temperature. CONCLUSIONS: Our model-based estimates suggest that reducing pathogen prevalence and concentration in source manure would reduce the risk of AGI from exposure to manure irrigation, and that increasing the distance from irrigated manure (i.e., setbacks) and limiting irrigation to times of low wind speed may also reduce risk.

  7. Pedagogical Values of Mobile-Assisted Task-Based Activities to Enhance Speaking Skill

    ERIC Educational Resources Information Center

    Mohammadi, Mojtaba; Safdari, Nastaran

    2015-01-01

    The purpose of the present study was to examine the impact of online mobile-assisted task-based activities on improving Iranian intermediate English as a Foreign Language (EFL) learners' speaking skills. To achieve the purpose of the study, 90 intermediate language learners were selected ranging between 13 to 16 years old and divided into three…

  8. Aldehydes and ketones form intermediate π complexes with the Gilman reagent, Me2CuLi, at low temperatures in tetrahydrofuran.

    PubMed

    Bertz, Steven H; Hardin, Richard A; Ogle, Craig A

    2013-07-03

    Typical aldehydes and ketones form π complexes with Me2CuLi at low temperatures in tetrahydrofuran. They range in stability from fleeting intermediates at -100 °C to entities that persist up to -20 °C. Three subsequent reaction pathways have been identified.

  9. Short, intermediate and long range order in amorphous ices

    NASA Astrophysics Data System (ADS)

    Martelli, Fausto; Torquato, Salvatore; Giovanbattista, Nicolas; Car, Roberto

    Water exhibits polyamorphism, i.e., it exists in more than one amorphous state. The most common forms of glassy water are the low-density amorphous (LDA) and the high-density amorphous (HDA) ices. LDA, the most abundant form of ice in the Universe, transforms into HDA upon isothermal compression. We model the transformation of LDA into HDA under isothermal compression with classical molecular dynamics simulations. We analyze the molecular structures with a recently introduced scalar order metric to measure short and intermediate range order. In addition, we rank the structures by their degree of hyperuniformity, i.e.,the extent to which long range density fluctuations are suppressed. F.M. and R.C. acknowledge support from the Department of Energy (DOE) under Grant No. DE-SC0008626.

  10. Effective sampling range of a synthetic protein-based attractant for Ceratitis capitata (Diptera: Tephritidae).

    PubMed

    Epsky, Nancy D; Espinoza, Hernán R; Kendra, Paul E; Abernathy, Robert; Midgarden, David; Heath, Robert R

    2010-10-01

    Studies were conducted in Honduras to determine effective sampling range of a female-targeted protein-based synthetic attractant for the Mediterranean fruit fly, Ceratitis capitata (Wiedemann) (Diptera: Tephritidae). Multilure traps were baited with ammonium acetate, putrescine, and trimethylamine lures (three-component attractant) and sampled over eight consecutive weeks. Field design consisted of 38 traps (over 0.5 ha) placed in a combination of standard and high-density grids to facilitate geostatistical analysis, and tests were conducted in coffee (Coffea arabica L.),mango (Mangifera indica L.),and orthanique (Citrus sinensis X Citrus reticulata). Effective sampling range, as determined from the range parameter obtained from experimental variograms that fit a spherical model, was approximately 30 m for flies captured in tests in coffee or mango and approximately 40 m for flies captured in orthanique. For comparison, a release-recapture study was conducted in mango using wild (field-collected) mixed sex C. capitata and an array of 20 baited traps spaced 10-50 m from the release point. Contour analysis was used to document spatial distribution of fly recaptures and to estimate effective sampling range, defined by the area that encompassed 90% of the recaptures. With this approach, effective range of the three-component attractant was estimated to be approximately 28 m, similar to results obtained from variogram analysis. Contour maps indicated that wind direction had a strong influence on sampling range, which was approximately 15 m greater upwind compared with downwind from the release point. Geostatistical analysis of field-captured insects in appropriately designed trapping grids may provide a supplement or alternative to release-recapture studies to estimate sampling ranges for semiochemical-based trapping systems.

  11. Vegetative environmental buffers and exhaust fan deflectors for reducing downwind odor and VOCs from tunnel-ventilated swine barns

    USDA-ARS?s Scientific Manuscript database

    Scientists have investigated methods for reducing odor emissions from livestock buildings for decades, yet few technologies have proven effective. Vegetative Environmental Buffers (VEB), which are specially designed combinations of trees, shrubs and grasses, have shown promise in recent years for r...

  12. Differential Effects of Particulate Matter Upwind and Downwind of an Urban Freeway in an Allergic Mouse Model

    EPA Science Inventory

    Near-road exposure to air pollutants has been associated with decreased lung function and other adverse health effects in susceptible populations. This study was designed to investigate whether different types of near-road particulate matter (PM) contribute to exacerbation of all...

  13. Federal Implementation Plans for Iowa, Kansas, Michigan, Missouri, Oklahoma, and Wisconsin To Reduce Interstate Transport of Ozone (76 FR 40662)

    EPA Pesticide Factsheets

    EPA provides an opportunity for public comment on our conclusion that emissions from six states significantly contribute to downwind nonattainment or interfere with maintenance of the 1997 ozone National Ambient Air Quality Standards in other states.

  14. The Reduction of Partitioned Wind and Water Erosion by Conservation Agriculture

    USDA-ARS?s Scientific Manuscript database

    Soil loss due to wind and water erosion degrades the soil and results in environmental problems downstream and downwind of the source field. Wind and water erosion may both occur to varying extents particularly in semi-arid environments. Soil conservation strategies require information about the p...

  15. Design and evaluation of a low-volume total suspended particulate sampler

    USDA-ARS?s Scientific Manuscript database

    The regulation of particulate matter (PM) emitted by agricultural sources, e.g., cotton gins, feed mills, and concentrated animal feeding operations (CAFOs), is based on downwind concentrations of particulate matter less than 10 and 2.5 'm (PM10 and PM2.5) aerodynamic equivalent diameter (AED). Both...

  16. Federal Implementation Plans for Iowa, Michigan, Missouri, Oklahoma, and Wisconsin and Determination for Kansas Regarding Interstate Transport of Ozone (76 FR 80760)

    EPA Pesticide Factsheets

    EPA concludes that emissions from Iowa, Kansas, Michigan, Missouri, Oklahoma, and Wisconsin significantly contribute to downwind nonattainment or interfere with maintenance of the 1997 ozone National Ambient Air Quality Standards (NAAQS) in other states.

  17. Emission of volatile organic compounds after land application of cattle manure

    USDA-ARS?s Scientific Manuscript database

    Beef cattle manure can serve as a valuable source of nutrients for crop production. However, emissions of volatile organic compounds (VOCs) following land application may pose an odor nuisance to downwind populations. This study was conducted to evaluate the effects of application method, diet, so...

  18. Assessing Model Characterization of Single Source Secondary Pollutant Impacts Using 2013 SENEX Field Study Measurements

    EPA Science Inventory

    Aircraft measurements made downwind from specific coal fired power plants during the 2013 Southeast Nexus field campaign provide a unique opportunity to evaluate single source photochemical model predictions of both O3 and secondary PM2.5 species. The model did well at predicting...

  19. Concentrations of airborne endotoxin and microorganisms at a 10,000 cow open-freestall dairy

    USDA-ARS?s Scientific Manuscript database

    Confined animal production systems produce elevated bioaerosol concentrations, which are a potential respiratory health risk to individuals on site and downwind. In this study, airborne endotoxin and microorganisms were collected during the spring, summer, and fall at a large open-freestall dairy i...

  20. Regional pollution potential in the northwestern United States.

    Treesearch

    Sue A. Ferguson; Miriam L. Rorig

    2003-01-01

    The potential for air pollution from industrial sources to reach wilderness areas throughout the Northwestern United States is approximated from monthly mean emissions, along with wind speeds and directions. A simple index is derived to estimate downwind concentration. Maps of pollution potential were generated for each pollution component (particulates, sulfur oxides...

  1. 14 CFR 25.415 - Ground gust conditions.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Ground gust conditions. 25.415 Section 25... AIRWORTHINESS STANDARDS: TRANSPORT CATEGORY AIRPLANES Structure Control Surface and System Loads § 25.415 Ground... ground gusts and taxiing downwind: (1) The control system between the stops nearest the surfaces and the...

  2. 14 CFR 25.415 - Ground gust conditions.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 1 2011-01-01 2011-01-01 false Ground gust conditions. 25.415 Section 25... AIRWORTHINESS STANDARDS: TRANSPORT CATEGORY AIRPLANES Structure Control Surface and System Loads § 25.415 Ground... ground gusts and taxiing downwind: (1) The control system between the stops nearest the surfaces and the...

  3. 30 CFR 250.1613 - Diverter systems.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) downstream of the spool outlet flange, and the radius of curvature of turns shall be as large as practicable... following shall apply: (1) If the diverter system utilizes only one spool outlet, branch lines shall be installed to provide downwind diversion capability, and (2) No spool outlet or diverter line internal...

  4. 30 CFR 250.1613 - Diverter systems.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... number of turns in the vent line(s) downstream of the spool outlet flange, and the radius of curvature of... utilizes only one spool outlet, branch lines shall be installed to provide downwind diversion capability, and (2) No spool outlet or diverter line internal diameter shall be less than 10 inches, except that...

  5. 30 CFR 250.1613 - Diverter systems.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... a minimum number of turns in the vent line(s) downstream of the spool outlet flange, and the radius... system utilizes only one spool outlet, branch lines shall be installed to provide downwind diversion capability, and (2) No spool outlet or diverter line internal diameter shall be less than 10 inches, except...

  6. 30 CFR 250.1613 - Diverter systems.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... number of turns in the vent line(s) downstream of the spool outlet flange, and the radius of curvature of... utilizes only one spool outlet, branch lines shall be installed to provide downwind diversion capability, and (2) No spool outlet or diverter line internal diameter shall be less than 10 inches, except that...

  7. 30 CFR 250.1613 - Diverter systems.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... number of turns in the vent line(s) downstream of the spool outlet flange, and the radius of curvature of... utilizes only one spool outlet, branch lines shall be installed to provide downwind diversion capability, and (2) No spool outlet or diverter line internal diameter shall be less than 10 inches, except that...

  8. SPATIAL VARIATION OF THE EVOLUTION AND STRUCTURE OF THE URBAN BOUNDARY LAYER

    EPA Science Inventory

    The spatial variation of the nocturnal urban boundary layer structure and the time variation of the mixing height, the nocturnal inversion top and strength after sunrise are presented for urban sites located upwind, downwind, and near the center of the heat island and for upwind ...

  9. 14 CFR 25.479 - Level landing conditions.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    .... (a) In the level attitude, the airplane is assumed to contact the ground at forward velocity... if approval of downwind landings exceeding 10 knots is requested. (b) For the level landing attitude...) For the level landing attitude for airplanes with nose wheels, shown in Figure 2 of Appendix A of this...

  10. Secondary organic aerosol formation from ambient air in an oxidation flow reactor in central Amazonia

    DOE PAGES

    Palm, Brett B.; de Sá, Suzane S.; Day, Douglas A.; ...

    2018-01-17

    Secondary organic aerosol (SOA) formation from ambient air was studied using an oxidation flow reactor (OFR) coupled to an aerosol mass spectrometer (AMS) during both the wet and dry seasons at the Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) field campaign. Measurements were made at two sites downwind of the city of Manaus, Brazil. Ambient air was oxidized in the OFR using variable concentrations of either OH or O 3, over ranges from hours to days (O 3) or weeks (OH) of equivalent atmospheric aging. The amount of SOA formed in the OFR ranged from 0 to asmore » much as 10 μg m -3, depending on the amount of SOA precursor gases in ambient air. Typically, more SOA was formed during nighttime than daytime, and more from OH than from O 3 oxidation. SOA yields of individual organic precursors under OFR conditions were measured by standard addition into ambient air, and confirmed to be consistent with published environmental chamber-derived SOA yields. Positive matrix factorization of organic aerosol (OA) after OH oxidation showed formation of typical oxidized OA factors and a loss of primary OA factors as OH aging increased. After OH oxidation in the OFR, the hygroscopicity of the OA increased with increasing elemental O : C up to O : C ~ 1.0, and then decreased as O : C increased further. Some possible reasons for this decrease are discussed. The measured SOA formation was compared to the amount predicted from the concentrations of measured ambient SOA precursors and their SOA yields. And while measured ambient precursors were sufficient to explain the amount of SOA formed from O 3, they could only explain 10–50 % of the SOA formed from OH. This is consistent with previous OFR studies which showed that typically unmeasured semivolatile and intermediate volatility gases (that tend to lack C = C bonds) are present in ambient air and can explain such additional SOA formation. To investigate the sources of the unmeasured SOA-forming gases during this campaign, multilinear regression analysis was performed between measured SOA formation and the concentration of gas-phase tracers representing different precursor sources. The majority of SOA-forming gases present during both seasons were of biogenic origin. Urban sources also contributed substantially in both seasons, while biomass burning sources were more important during the dry season. Our study enables a better understanding of SOA formation in environments with diverse emission sources.« less

  11. Secondary organic aerosol formation from ambient air in an oxidation flow reactor in central Amazonia

    NASA Astrophysics Data System (ADS)

    Palm, Brett B.; de Sá, Suzane S.; Day, Douglas A.; Campuzano-Jost, Pedro; Hu, Weiwei; Seco, Roger; Sjostedt, Steven J.; Park, Jeong-Hoo; Guenther, Alex B.; Kim, Saewung; Brito, Joel; Wurm, Florian; Artaxo, Paulo; Thalman, Ryan; Wang, Jian; Yee, Lindsay D.; Wernis, Rebecca; Isaacman-VanWertz, Gabriel; Goldstein, Allen H.; Liu, Yingjun; Springston, Stephen R.; Souza, Rodrigo; Newburn, Matt K.; Lizabeth Alexander, M.; Martin, Scot T.; Jimenez, Jose L.

    2018-01-01

    Secondary organic aerosol (SOA) formation from ambient air was studied using an oxidation flow reactor (OFR) coupled to an aerosol mass spectrometer (AMS) during both the wet and dry seasons at the Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) field campaign. Measurements were made at two sites downwind of the city of Manaus, Brazil. Ambient air was oxidized in the OFR using variable concentrations of either OH or O3, over ranges from hours to days (O3) or weeks (OH) of equivalent atmospheric aging. The amount of SOA formed in the OFR ranged from 0 to as much as 10 µg m-3, depending on the amount of SOA precursor gases in ambient air. Typically, more SOA was formed during nighttime than daytime, and more from OH than from O3 oxidation. SOA yields of individual organic precursors under OFR conditions were measured by standard addition into ambient air and were confirmed to be consistent with published environmental chamber-derived SOA yields. Positive matrix factorization of organic aerosol (OA) after OH oxidation showed formation of typical oxidized OA factors and a loss of primary OA factors as OH aging increased. After OH oxidation in the OFR, the hygroscopicity of the OA increased with increasing elemental O : C up to O : C ˜ 1.0, and then decreased as O : C increased further. Possible reasons for this decrease are discussed. The measured SOA formation was compared to the amount predicted from the concentrations of measured ambient SOA precursors and their SOA yields. While measured ambient precursors were sufficient to explain the amount of SOA formed from O3, they could only explain 10-50 % of the SOA formed from OH. This is consistent with previous OFR studies, which showed that typically unmeasured semivolatile and intermediate volatility gases (that tend to lack C = C bonds) are present in ambient air and can explain such additional SOA formation. To investigate the sources of the unmeasured SOA-forming gases during this campaign, multilinear regression analysis was performed between measured SOA formation and the concentration of gas-phase tracers representing different precursor sources. The majority of SOA-forming gases present during both seasons were of biogenic origin. Urban sources also contributed substantially in both seasons, while biomass burning sources were more important during the dry season. This study enables a better understanding of SOA formation in environments with diverse emission sources.

  12. Secondary organic aerosol formation from ambient air in an oxidation flow reactor in central Amazonia

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Palm, Brett B.; de Sá, Suzane S.; Day, Douglas A.

    Secondary organic aerosol (SOA) formation from ambient air was studied using an oxidation flow reactor (OFR) coupled to an aerosol mass spectrometer (AMS) during both the wet and dry seasons at the Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) field campaign. Measurements were made at two sites downwind of the city of Manaus, Brazil. Ambient air was oxidized in the OFR using variable concentrations of either OH or O 3, over ranges from hours to days (O 3) or weeks (OH) of equivalent atmospheric aging. The amount of SOA formed in the OFR ranged from 0 to asmore » much as 10 μg m -3, depending on the amount of SOA precursor gases in ambient air. Typically, more SOA was formed during nighttime than daytime, and more from OH than from O 3 oxidation. SOA yields of individual organic precursors under OFR conditions were measured by standard addition into ambient air, and confirmed to be consistent with published environmental chamber-derived SOA yields. Positive matrix factorization of organic aerosol (OA) after OH oxidation showed formation of typical oxidized OA factors and a loss of primary OA factors as OH aging increased. After OH oxidation in the OFR, the hygroscopicity of the OA increased with increasing elemental O : C up to O : C ~ 1.0, and then decreased as O : C increased further. Some possible reasons for this decrease are discussed. The measured SOA formation was compared to the amount predicted from the concentrations of measured ambient SOA precursors and their SOA yields. And while measured ambient precursors were sufficient to explain the amount of SOA formed from O 3, they could only explain 10–50 % of the SOA formed from OH. This is consistent with previous OFR studies which showed that typically unmeasured semivolatile and intermediate volatility gases (that tend to lack C = C bonds) are present in ambient air and can explain such additional SOA formation. To investigate the sources of the unmeasured SOA-forming gases during this campaign, multilinear regression analysis was performed between measured SOA formation and the concentration of gas-phase tracers representing different precursor sources. The majority of SOA-forming gases present during both seasons were of biogenic origin. Urban sources also contributed substantially in both seasons, while biomass burning sources were more important during the dry season. Our study enables a better understanding of SOA formation in environments with diverse emission sources.« less

  13. Secondary organic aerosol formation from ambient air in an oxidation flow reactor in central Amazonia

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Palm, Brett B.; de Sá, Suzane S.; Day, Douglas A.

    Secondary organic aerosol (SOA) formation from ambient air was studied using an oxidation flow reactor (OFR) coupled to an aerosol mass spectrometer (AMS) during both the wet and dry seasons at the Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) field campaign. Measurements were made at two sites downwind of the city of Manaus, Brazil. Ambient air was oxidized in the OFR using variable concentrations of either OH or O 3, over ranges from hours to days (O 3) or weeks (OH) of equivalent atmospheric aging. The amount of SOA formed in the OFR ranged from 0 to asmore » much as 10 µg m −3, depending on the amount of SOA precursor gases in ambient air. Typically, more SOA was formed during nighttime than daytime, and more from OH than from O 3 oxidation. SOA yields of individual organic precursors under OFR conditions were measured by standard addition into ambient air and were confirmed to be consistent with published environmental chamber-derived SOA yields. Positive matrix factorization of organic aerosol (OA) after OH oxidation showed formation of typical oxidized OA factors and a loss of primary OA factors as OH aging increased. After OH oxidation in the OFR, the hygroscopicity of the OA increased with increasing elemental O : C up to O : C ∼ 1.0, and then decreased as O : C increased further. Possible reasons for this decrease are discussed. The measured SOA formation was compared to the amount predicted from the concentrations of measured ambient SOA precursors and their SOA yields. While measured ambient precursors were sufficient to explain the amount of SOA formed from O 3, they could only explain 10–50 % of the SOA formed from OH. This is consistent with previous OFR studies, which showed that typically unmeasured semivolatile and intermediate volatility gases (that tend to lack C = C bonds) are present in ambient air and can explain such additional SOA formation. To investigate the sources of the unmeasured SOA-forming gases during this campaign, multilinear regression analysis was performed between measured SOA formation and the concentration of gas-phase tracers representing different precursor sources. The majority of SOA-forming gases present during both seasons were of biogenic origin. Urban sources also contributed substantially in both seasons, while biomass burning sources were more important during the dry season. This study enables a better understanding of SOA formation in environments with diverse emission sources.« less

  14. The costs and service implications of substituting intermediate care for acute hospital care.

    PubMed

    Mayhew, Leslie; Lawrence, David

    2006-05-01

    Intermediate care is part of a package of initiatives introduced by the UK Government mainly to relieve pressure on acute hospital beds and reduce delayed discharge (bed blocking). Intermediate care involves caring for patients in a range of settings, such as in the home or community or in nursing and residential homes. This paper considers the scope of intermediate care and its role in relation to acute hospital services. In particular, it develops a framework that can be used to inform decisions about the most cost-effective care pathways for given clinical situations, and also for wider planning purposes. It does this by providing a model for evaluating the costs of intermediate care services provided by different agencies and techniques for calibrating the model locally. It finds that consistent application of the techniques over a period of time, coupled with sound planning and accounting, should result in savings to the health economy.

  15. Characterization of a transient +2 sulfur oxidation state intermediate from the oxidation of aqueous sulfide

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Vairavmurthy, M.A.; Zhou, Weiqing

    1995-04-01

    The oxidation H{sub 2}S to sulfate involves a net transfer of eight electrons and occurs through the formation of several partially oxidized intermediates with oxidation states ranging from {minus}1 to +5. Known intermediates include elemental sulfur (oxidation state 0), polysulfides (outer sulfur: {minus}1, inner sulfur: 0), sulfite (+4) and thiosulfate (outer sulfur: {minus}1, inner sulfur: +5). A noticeable gap in this series of intermediates is that of a +2 sulfur oxidation state oxoacid/oxoanion species, which was never detected experimentally. Here, we present evidence of the transient existence of +2 oxidation state intermediate in the Ni(II)-catalyzed oxidation of aqueous sulfide. X-raymore » absorption near-edge structure (XANES) spectroscopy and Fourier-transform-infrared (FT-IR) spectroscopy were used to characterize this species; they suggest that it has a sulfoxylate ion (SO{sub 2}{sup 2{minus}}) structure.« less

  16. Lower tropospheric ozone and aerosol measurements at a coastal mountain site in Northern California

    NASA Astrophysics Data System (ADS)

    Post, A.; Conley, S. A.; Zhao, Y.; Cliff, S. S.; Faloona, I. C.; Wexler, A. S.; Lighthall, D.

    2012-12-01

    Increasing concern over the impacts of exogenous air pollution in California's Central Valley have prompted the establishment of a coastal, high altitude monitoring site at the Chews Ridge Observatory (1550 m) approximately 30 km east of Point Sur in Monterey County. Six months of ozone and aerosol measurements are presented in the context of long-range transport and its potential impact on surface air quality in the southern San Joaquin Valley. Moreover, approximately monthly ozone surveys are conducted by aircraft upwind, over the Pacific Ocean, and downwind, over the Central Valley, to characterize horizontal and vertical transport across the coastal mountains. The measurements exhibit no systematic diurnal variations of ozone or water vapor, an indication that the site primarily samples lower free tropospheric air which has not been significantly influenced by either local emissions or convective coupling to the surface. Aerosol size is measured with a scanning mobility particle sizer and composition is analyzed with an 8-stage rotating drum impactor whose substrates are characterized by X-ray fluorescence. Various elemental ratios and back trajectory calculations are used to infer the temporal patterns of influence that long range transport has on California air quality.

  17. Regional transport of a chemically distinctive dust: Gypsum from White Sands, New Mexico (USA)

    NASA Astrophysics Data System (ADS)

    White, Warren H.; Hyslop, Nicole P.; Trzepla, Krystyna; Yatkin, Sinan; Rarig, Randy S.; Gill, Thomas E.; Jin, Lixin

    2015-03-01

    The White Sands complex, a National Monument and adjoining Missile Range in southern New Mexico, occupies the dry bed of an ice-age lake where an active gypsum dunefield abuts erodible playa sediments. Aerosols entrained from White Sands are sometimes visible on satellite images as distinct, light-colored plumes crossing the Sacramento Mountains to the east and northeast. The IMPROVE network (Interagency Monitoring of PROtected Visual Environments) operates long-term aerosol samplers at two sites east of the Sacramento range. In recent years a spring pulse of sulfate aerosol has appeared at these sites, eclipsing the regional summer peak resulting from atmospheric reactions of sulfur dioxide emissions. A significant fraction of this spring sulfate is contributed by gypsum and other salts from White Sands, with much of the sulfur in coarse particles and concentrations of calcium and strontium above regional levels. The increase in these gypsiferous species coincides with a drought following a period of above-average precipitation. White Sands and the IMPROVE samplers together provide a natural laboratory: a climatically sensitive dust source that is both well characterized and chemically distinct from its surroundings, with a signature that remains identifiable at long-term observatories 100-200 km downwind.

  18. Analytical framework for modeling of long-range transport of fungal plant epidemics

    NASA Astrophysics Data System (ADS)

    Kogan, Oleg; O'Keeffe, Kevin; Schneider, David; Myers, Christopher; Analytical FrameworksInfectious Disease Dynamics Team

    2015-03-01

    A new framework for the study of long-range transport of fungal plant epidemics is proposed. The null nonlinear model includes advective transport through the free atmosphere, spore production on the ground, and transfer of spores between the ground and the advective atmospheric layer. The competition between the growth wave on the ground and the effect of the wind is most strongly reflected in upwind fronts, which can propagate into the wind for exponential initial conditions. If the rate of spore transfer into the advective layer is below critical, this happens for initital conditions with arbitrary steepness. Upwind fronts from localized initial conditions will propagate in the direction of the wind above this critical parameter, and will not propagate below it. On the other hand, the speed of the downwind front does not have a strong dependence on the rate of spore transfer between the advective layer and the ground. Thus, even vanishingly small, but finite transfer rates result in a substantial epidemic wave in the direction of the wind. We also consider the effect of an additional, random-walk like mechanism of transport through the near-ground atmospheric boundary layer, and attempt to understand which route dominates the transport over long distances.

  19. Damped spin waves in the intermediate ordered phases in Ni 3V 2O 8

    DOE PAGES

    Ehlers, Georg; Podlesnyak, Andrey A.; Frontzek, Matthias D.; ...

    2015-06-09

    Here, spin dynamics in the intermediate ordered phases (between 4 and 9 K) in Ni 3V 2O 8 have been studied with inelastic neutron scattering. It is found that the spin waves are very diffuse, indicative of short lived correlations and the coexistence of paramagnetic moments with the long-range ordered state.

  20. High-lying intermediate excitations in the nuclear effective interaction with a super-soft-core potential

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Goode, P.R.; Barrett, B.R.; Portilho, O.

    1979-02-01

    The earlier calculations of Goode and Barrett are repeated using the super-soft-core potential of Gogny, Pires, and de Tourreil. The particular third-order folded diagram which they calculated now converges in its intermediate-state energy summation, because of the suppression of the strong short-range repulsive effects present in earlier calculations.

  1. The thermally reversing window in ternary GexPxS1-2x glasses

    NASA Astrophysics Data System (ADS)

    Vempati, U.; Boolchand, P.

    2004-11-01

    GexPxS1-2x glasses in the compositional range 0.05 \\le x \\le 0.19 have been synthesized and examined in temperature modulated differential scanning calorimetry (MDSC) and Raman scattering experiments. Trends in the non-reversing enthalpy ΔHnr(x) near Tg show the term to almost vanish in the 0.090(5)0.135. In analogy to previous results on chalcogenide glasses, we identify compositions at x<0.09 to be elastically floppy, those in the 0.0900.135 to be stressed rigid. MDSC results also show that the ΔHnr term ages in the stressed-rigid and floppy phases but not in the intermediate phase. The intermediate phase is viewed to be a self-organized phase of a disordered network. It consists of at least four isostatically rigid local structures: corner-sharing GeS4, edge-sharing GeS2, pyramidal P(S1/2)3 and quasi-tetrahedral S = P(S1/2)3 units for which evidence comes from Raman scattering. The latter method also shows the existence of P4S7 and P4S10 molecules in the glasses segregated from the backbone. These aspects of structure contribute to an intermediate phase that is significantly narrower in width than in the corresponding selenide glasses.

  2. Experimental study on the performance of the vapor injection refrigeration system with an economizer for intermediate pressures

    NASA Astrophysics Data System (ADS)

    Moon, Chang-Uk; Choi, Kwang-Hwan; Yoon, Jung-In; Kim, Young-Bok; Son, Chang-Hyo; Ha, Soo-Jung; Jeon, Min-Ju; An, Sang-Young; Lee, Joon-Hyuk

    2018-04-01

    In this study, to investigate the performance characteristics of vapor injection refrigeration system with an economizer at an intermediate pressure, the vapor injection refrigeration system was analyzed under various experiment conditions. As a result, the optimum design data of the vapor injection refrigeration system with an economizer were obtained. The findings from this study can be summarized as follows. The mass flow rate through the compressor increases with intermediate pressure. The compression power input showed an increasing trend under all the test conditions. The evaporation capacity increased and then decreased at the intermediate pressure, and as such, it became maximum at the given intermediate pressure. The increased mass flow rate of the by-passed refrigerant enhanced the evaporation capacity at the low medium pressure range, but the increased saturation temperature limited the subcooling degree of the liquid refrigerant after the application of the economizer when the intermediate pressure kept rising, and degenerated the evaporation capacity. The coefficient of performance (COP) increased and then decreased with respect to the intermediate pressures under all the experiment conditions. Nevertheless, there was an optimum intermediate pressure for the maximum COP under each experiment condition. Therefore, the optimum intermediate pressure in this study was found at -99.08 kPa, which is the theoretical standard medium pressure under all the test conditions.

  3. Variations in airborne bacterial communities at high altitudes over the Noto Peninsula (Japan) in response to Asian dust events

    NASA Astrophysics Data System (ADS)

    Maki, Teruya; Hara, Kazutaka; Iwata, Ayumu; Lee, Kevin C.; Kawai, Kei; Kai, Kenji; Kobayashi, Fumihisa; Pointing, Stephen B.; Archer, Stephen; Hasegawa, Hiroshi; Iwasaka, Yasunobu

    2017-10-01

    Aerosol particles, including airborne microorganisms, are transported through the free troposphere from the Asian continental area to the downwind area in East Asia and can influence climate changes, ecosystem dynamics, and human health. However, the variations present in airborne bacterial communities in the free troposphere over downwind areas are poorly understood, and there are few studies that provide an in-depth examination of the effects of long-range transport of aerosols (natural and anthropogenic particles) on bacterial variations. In this study, the vertical distributions of airborne bacterial communities at high altitudes were investigated and the bacterial variations were compared between dust events and non-dust events.Aerosols were collected at three altitudes from ground level to the free troposphere (upper level: 3000 or 2500 m; middle level: 1200 or 500 m; and low level: 10 m) during Asian dust events and non-dust events over the Noto Peninsula, Japan, where westerly winds carry aerosols from the Asian continental areas. During Asian dust events, air masses at high altitudes were transported from the Asian continental area by westerly winds, and laser imaging detection and ranging (lidar) data indicated high concentrations of non-spherical particles, suggesting that dust-sand particles were transported from the central desert regions of Asia. The air samples collected during the dust events contained 10-100 times higher concentrations of microscopic fluorescent particles and optical particle counter (OPC) measured particles than in non-dust events. The air masses of non-dust events contained lower amounts of dust-sand particles. Additionally, some air samples showed relatively high levels of black carbon, which were likely transported from the Asian continental coasts. Moreover, during the dust events, microbial particles at altitudes of > 1200 m increased to the concentrations ranging from 1. 2 × 106 to 6. 6 × 106 particles m-3. In contrast, when dust events disappeared, the microbial particles at > 1200 m decreased slightly to microbial-particle concentrations ranging from 6. 4 × 104 to 8. 9 × 105 particles m-3.High-throughput sequencing technology targeting 16S rRNA genes (16S rDNA) revealed that the bacterial communities collected at high altitudes (from 500 to 3000 m) during dust events exhibited higher diversities and were predominantly composed of natural-sand/terrestrial bacteria, such as Bacillus members. During non-dust periods, airborne bacteria at high altitudes were mainly composed of anthropogenic/terrestrial bacteria (Actinobacteria), marine bacteria (Cyanobacteria and Alphaproteobacteria), and plant-associated bacteria (Gammaproteobacteria), which shifted in composition in correspondence with the origins of the air masses and the meteorological conditions. The airborne bacterial structures at high altitudes suggested remarkable changes in response to air mass sources, which contributed to the increases in community richness and to the domination of a few bacterial taxa.

  4. Design and Performance Analysis of an Intrinsically Safe Ultrasonic Ranging Sensor

    PubMed Central

    Zhang, Hongjuan; Wang, Yu; Zhang, Xu; Wang, Dong; Jin, Baoquan

    2016-01-01

    In flammable or explosive environments, an ultrasonic sensor for distance measurement poses an important engineering safety challenge, because the driving circuit uses an intermediate frequency transformer as an impedance transformation element, in which the produced heat or spark is available for ignition. In this paper, an intrinsically safe ultrasonic ranging sensor is designed and implemented. The waterproof piezoelectric transducer with integrated transceiver is chosen as an energy transducing element. Then a novel transducer driving circuit is designed based on an impedance matching method considering safety spark parameters to replace an intermediate frequency transformer. Then, an energy limiting circuit is developed to achieve dual levels of over-voltage and over-current protection. The detail calculation and evaluation are executed and the electrical characteristics are analyzed to verify the intrinsic safety of the driving circuit. Finally, an experimental platform of the ultrasonic ranging sensor system is constructed, which involves short-circuit protection. Experimental results show that the proposed ultrasonic ranging sensor is excellent in both ranging performance and intrinsic safety. PMID:27304958

  5. Design and Performance Analysis of an Intrinsically Safe Ultrasonic Ranging Sensor.

    PubMed

    Zhang, Hongjuan; Wang, Yu; Zhang, Xu; Wang, Dong; Jin, Baoquan

    2016-06-13

    In flammable or explosive environments, an ultrasonic sensor for distance measurement poses an important engineering safety challenge, because the driving circuit uses an intermediate frequency transformer as an impedance transformation element, in which the produced heat or spark is available for ignition. In this paper, an intrinsically safe ultrasonic ranging sensor is designed and implemented. The waterproof piezoelectric transducer with integrated transceiver is chosen as an energy transducing element. Then a novel transducer driving circuit is designed based on an impedance matching method considering safety spark parameters to replace an intermediate frequency transformer. Then, an energy limiting circuit is developed to achieve dual levels of over-voltage and over-current protection. The detail calculation and evaluation are executed and the electrical characteristics are analyzed to verify the intrinsic safety of the driving circuit. Finally, an experimental platform of the ultrasonic ranging sensor system is constructed, which involves short-circuit protection. Experimental results show that the proposed ultrasonic ranging sensor is excellent in both ranging performance and intrinsic safety.

  6. Correlation and nuclear distortion effects of Cr-substituted ZnSe.

    PubMed

    Tablero, C

    2007-04-28

    There is a great deal of interest in the effect of the correlation and effect of the atomic distortion in materials with a metallic intermediate band. This band, situated within the semiconductor band gaps, would be split, thus creating two bands, a full one below the Fermi energy and an empty one above it, i.e., a metal-insulator transition. This basic electronic band structure corresponds to intermediate band materials and is characteristic of transparent-conducting oxides, up and down converters, and intermediate band solar cells. A sufficiently high density of Cr in ZnSe substituting the Zn atoms leads to a microscopic intermediate band, in which these effects will be analyzed. A Hubbard term has been included to improve the description of the many-body effect. This term modifies the bandwidth of the intermediate band, the Fermi energy, and breaks the orbital-occupation degeneracy. From the results, the intermediate band is not split within the range of Hubbard term values analyzed and for Cr substituting Zn from 0.463% to 3.125% of Cr atomic concentration.

  7. 49 CFR 193.2059 - Flammable vapor-gas dispersion protection.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... Dispersion Model.” Alternatively, in order to account for additional cloud dilution which may be caused by..., subject to the Administrator's approval. (b) The following dispersion parameters must be used in computing... if it can be shown that the terrain both upwind and downwind of the vapor cloud has dense vegetation...

  8. 49 CFR 193.2059 - Flammable vapor-gas dispersion protection.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... Dispersion Model.” Alternatively, in order to account for additional cloud dilution which may be caused by..., subject to the Administrator's approval. (b) The following dispersion parameters must be used in computing... if it can be shown that the terrain both upwind and downwind of the vapor cloud has dense vegetation...

  9. 49 CFR 193.2059 - Flammable vapor-gas dispersion protection.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... Dispersion Model.” Alternatively, in order to account for additional cloud dilution which may be caused by..., subject to the Administrator's approval. (b) The following dispersion parameters must be used in computing... if it can be shown that the terrain both upwind and downwind of the vapor cloud has dense vegetation...

  10. Catalog of Wargaming and Military Simulation Models

    DTIC Science & Technology

    1992-02-07

    C-107 D2PC - Downwind Chemical Hazard ........... ................... . D-1 DAMS - Division Ammunition Management Simulator...Communications, and Intelligence Simulation .... ............. T-83 TMS - Target Management System ............ .................. T-85 TNP - Tactical...Documentation: User’s Manual for Aircraft Inter-Antenna Propagation with Graphics (AAPG) Computer Program, Version 09, Hussar, Dr. Paul E. and Klocko, William

  11. 30 CFR 250.431 - What are the diverter design and installation requirements?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... OFFSHORE OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER CONTINENTAL SHELF Oil and Gas Drilling Operations... floating drilling operations; (b) Use dual diverter lines arranged to provide for downwind diversion capability; (c) Use at least two diverter control stations. One station must be on the drilling floor. The...

  12. A field and modeling study to assess the potential mitigation of near-road pollution by vegetative and structural barriers

    EPA Science Inventory

    Recent modeling and field studies have demonstrated that roadside structures such as noise barriers or tree stands, may significantly affect the local-scale transport of on-road emissions to areas located adjacent to major roadways. When directly downwind of a major roadway, conc...

  13. 77 FR 34400 - Agency Information Collection Activities: Comment Request

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-06-11

    ... warnings and notification to the public of volcanic activity in the U.S. in order to reduce the loss of... eruptions will be directed towards a web form allowing them to fill in ash fall information and submit the... track eruption clouds and associated fallout downwind. These reports from the public will also give...

  14. Ultrafine particles near a major roadway in Raleigh, North Carolina: downwind attenuation and correlation with traffic-related pollutants

    EPA Science Inventory

    Ultrafine particles (UFPs, diameter <100 run) emitted by traffic are a potential direct health threat to nearby populations and may additionally act as a tracer for co-emitted pollutants. During summertime in Raleigh, North Carolina, UFPs were simultaneously measured upwind and d...

  15. 14 CFR 23.415 - Ground gust conditions.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 1 2011-01-01 2011-01-01 false Ground gust conditions. 23.415 Section 23... and System Loads § 23.415 Ground gust conditions. (a) The control system must be investigated as follows for control surface loads due to ground gusts and taxiing downwind: (1) If an investigation of the...

  16. A simulated approach to estimating PM10 and PM2.5 concentrations downwind from cotton gins

    USDA-ARS?s Scientific Manuscript database

    Cotton gins are required to obtain operating permits from state air pollution regulatory agencies (SAPRA), which regulate the amount of particulate matter that can be emitted. Industrial Source Complex Short Term version 3 (ISCST3) is the Gaussian dispersion model currently used by some SAPRAs to pr...

  17. Estimation of point source fugitive emission rates from a single sensor time series: a conditionally-sampled Gaussian plume reconstruction

    EPA Science Inventory

    This paper presents a technique for determining the trace gas emission rate from a point source. The technique was tested using data from controlled methane release experiments and from measurement downwind of a natural gas production facility in Wyoming. Concentration measuremen...

  18. Ecological effects of nitrogen deposition in the western United States

    Treesearch

    Mark E. Fenn; Jill S. Baron; Edith B. Allen; Heather M. Rueth; Koren R. Nydick; Linda Geiser; William D. Bowman; James O. Sickman; Thomas Meixner; Dale W. Johnson; Peter Neitlich

    2003-01-01

    In the western United States vast acreages of land are exposed to low levels of atmospheric nitrogen (N) deposition, with interspersed hotspots of elevated N deposition downwind of large, expanding metropolitan centers or large agricultural operations. Biological response studies in western North America demonstrate that some aquatic and terrestrial plant and microbial...

  19. In situ observations of the influence of a large onshore wind farm on near-surface temperature, turbulence intensity and wind speed profiles

    NASA Astrophysics Data System (ADS)

    Smith, Craig M.; Barthelmie, R. J.; Pryor, S. C.

    2013-09-01

    Observations of wakes from individual wind turbines and a multi-megawatt wind energy installation in the Midwestern US indicate that directly downstream of a turbine (at a distance of 190 m, or 2.4 rotor diameters (D)), there is a clear impact on wind speed and turbulence intensity (TI) throughout the rotor swept area. However, at a downwind distance of 2.1 km (26 D downstream of the closest wind turbine) the wake of the whole wind farm is not evident. There is no significant reduction of hub-height wind speed or increase in TI especially during daytime. Thus, in high turbulence regimes even very large wind installations may have only a modest impact on downstream flow fields. No impact is observable in daytime vertical potential temperature gradients at downwind distances of >2 km, but at night the presence of the wind farm does significantly decrease the vertical gradients of potential temperature (though the profile remains stably stratified), largely by increasing the temperature at 2 m.

  20. Radon measurements in the lower tropical stratosphere - Evidence for rapid vertical transport and dehydration of tropospheric air

    NASA Technical Reports Server (NTRS)

    Kritz, Mark A.; Rosner, Stefan W.; Kelly, Kenneth K.; Loewenstein, Max; Chan, K. R.

    1993-01-01

    During the tropical experiment of NASA's Stratosphere-Troposphere Exchange Program (STEP), in situ radon and other trace constituent measurements were made aboard a NASA ER-2 high-altitude research aircraft to investigate the mechanisms of irreversible transfers from the troposphere into the tropical stratosphere. Observations made in and downwind of the cirrus shields of three large tropical cyclones and downwind of the cirrus anvil of a large cumulonimbus cloud cluster showed several clear instances of elevated radon activity occurring simultaneously with low total water mixing ratios. These observations are unambiguous evidence of an effective dehydration process, capable of reducing total water vapor mixing ratios to less than 2.5 ppmv, occurring in conjunction with troposphere-to-stratosphere transport and indicate that rapid localized convection, rather than slow regional mean motions, was responsible for the observed transports and associated with the accompanying dehydration. Radon activities measured in regions of active or recent troposphere-to-stratosphere transport were consistent with the 17 pCi/scm mean value needed to support the observed abundance of stratospheric 210 Pb.

  1. Floating wind turbine system

    NASA Technical Reports Server (NTRS)

    Viterna, Larry A. (Inventor)

    2009-01-01

    A floating wind turbine system with a tower structure that includes at least one stability arm extending therefrom and that is anchored to the sea floor with a rotatable position retention device that facilitates deep water installations. Variable buoyancy for the wind turbine system is provided by buoyancy chambers that are integral to the tower itself as well as the stability arm. Pumps are included for adjusting the buoyancy as an aid in system transport, installation, repair and removal. The wind turbine rotor is located downwind of the tower structure to allow the wind turbine to follow the wind direction without an active yaw drive system. The support tower and stability arm structure is designed to balance tension in the tether with buoyancy, gravity and wind forces in such a way that the top of the support tower leans downwind, providing a large clearance between the support tower and the rotor blade tips. This large clearance facilitates the use of articulated rotor hubs to reduced damaging structural dynamic loads. Major components of the turbine can be assembled at the shore and transported to an offshore installation site.

  2. Data reduction and analysis of graphite fiber release experiments

    NASA Technical Reports Server (NTRS)

    Lieberman, P.; Chovit, A. R.; Sussholz, B.; Korman, H. F.

    1979-01-01

    The burn and burn/explode effects on aircraft structures were examined in a series of fifteen outdoor tests conducted to verify the results obtained in previous burn and explode tests of carbon/graphite composite samples conducted in a closed chamber, and to simulate aircraft accident scenarios in which carbon/graphite fibers would be released. The primary effects that were to be investigaged in these tests were the amount and size distribution of the conductive fibers released from the composite structures, and how these various sizes of fibers transported downwind. The structures included plates, barrels, aircraft spoilers and a cockpit. The heat sources included a propane gas burner and 20 ft by 20 ft and 40 ft by 60 ft JP-5 pool fires. The larger pool fire was selected to simulate an aircraft accident incident. The passive instrumentation included sticky paper and sticky bridal veil over an area 6000 ft downwind and 3000 ft crosswind. The active instrumentation included instrumented meteorological towers, movies, infrared imaging cameras, LADAR, high voltage ball gages, light emitting diode gages, microwave gages and flame velocimeter.

  3. Complementary Pu Resuspension Study at Palomares, Spain

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shinn, J

    2002-10-01

    Soil in an area near Palomares, Spain, was contaminated with plutonium as a result of a mid-air collision of U.S. military aircraft in January 1966. The assessment for potential inhalation dose can be found in Iranzo et al., (1987). Long-term monitoring has been used to evaluate remedial actions (Iranzo et al., 1988) and there are many supporting studies of the Pu contamination at Palomares that have been carried out by the Centro de Investigaciones Energeticas, Medioambientales y Tecnologicas (CIEMAT) in Madrid. The purpose of this study is to evaluate the resuspension of Pu from the soil in terms of Pu-concentrationsmore » in air and resuspension rates in a complementary investigation to those of CIEMAT but in an intensive short-term field effort. This study complements the resuspension studies of CIEMAT at Palomares with additional information, and with confirmation of their previous studies. Observed mass loadings (M) were an average of 70 mg/m{sup 3} with peaks in the daytime of 130 mg/m{sup 3} and low values at night below 30 {micro}g/m{sup 3}. The Pu-activity of aerosols (A) downwind of plot 2-1 was 0.12 Bq/g and the enhancement factor (E{sub f}) had a value of 0.3, which is low but similar to a typical value of 0.7 for other undisturbed sites. This E{sub f} value may increase further away from ground zero. The particle size distribution of the Pu in air measured by cascade impactors was approximately lognormal with a median aerodynamic diameter of 3.7 {micro}m and a geometric standard deviation of 3.5 in the respirable range. This peak midway between 1 ? m and 10 {micro}m in the respirable range is commonly observed. Daily fluctuations in the Pu concentration in air (C) detected by the UHV were lognormally distributed with a geometric standard deviation of 4.9 indicating that the 98th percentile would be 24 times as high as the median. Downwind of plot 2-1 the mean Pu concentration in air, C, was 8.5 {micro}Bq/m{sup 3}. The resuspension factor (Sf) was 2.4 x 10{sup -10} m{sup -1} and agrees very well with the values between 10{sup -10} m{sup -1} and 10{sup -9} m{sup -1} previously reported. We observed a mean Pu/Am ratio of 7.1 with a relative variation of 30%, which compares well with a mean value of 6.5 for nearby plot 2-2. The resuspension rate (R) was in the middle of the range, 10{sup -11} s{sup -1} to 10{sup -12} s{sup -1} as observed in other stable sites, and indicates low potential for Pu redistribution.« less

  4. An Effective Method to Detect Volatile Intermediates Generated in the Bioconversion of Coal to Methane by Gas Chromatography-Mass Spectrometry after In-Situ Extraction Using Headspace Solid-Phase Micro-Extraction under Strict Anaerobic Conditions.

    PubMed

    Liu, Jianmin; Wang, Baoyu; Tai, Chao; Wu, Li; Zhao, Han; Guan, Jiadong; Chen, Linyong

    2016-01-01

    Bioconversion of coal to methane has gained increased attention in recent decades because of its economic and environmental advantages. However, the mechanism of this process is difficult to study in depth, partly because of difficulties associated with the analysis of intermediates generated in coal bioconversion. In this investigation, we report on an effective method to analyze volatile intermediates generated in the bioconversion of coal under strict anaerobic conditions. We conduct in-situ extraction of intermediates using headspace solid-phase micro-extraction followed by detection by gas chromatography-mass spectrometry. Bioconversion simulation equipment was modified and combined with a solid-phase micro-extraction device. In-situ extraction could be achieved by using the combined units, to avoid a breakdown in anaerobic conditions and to maintain the experiment continuity. More than 30 intermediates were identified qualitatively in the conversion process, and the variation in trends of some typical intermediates has been discussed. Volatile organic acids (C2-C7) were chosen for a quantitative study of the intermediates because of their importance during coal bioconversion to methane. Fiber coating, extraction time, and solution acidity were optimized in the solid-phase micro-extraction procedure. The pressure was enhanced during the bioconversion process to investigate the influence of headspace pressure on analyte extraction. The detection limits of the method ranged from 0.0006 to 0.02 mmol/L for the volatile organic acids and the relative standard deviations were between 4.6% and 11.5%. The volatile organic acids (C2-C7) generated in the bioconversion process were 0.01-1.15 mmol/L with a recovery range from 80% to 105%. The developed method is useful for further in-depth research on the bioconversion of coal to methane.

  5. An Effective Method to Detect Volatile Intermediates Generated in the Bioconversion of Coal to Methane by Gas Chromatography-Mass Spectrometry after In-Situ Extraction Using Headspace Solid-Phase Micro-Extraction under Strict Anaerobic Conditions

    PubMed Central

    Liu, Jianmin; Wang, Baoyu; Tai, Chao; Wu, Li; Zhao, Han; Guan, Jiadong; Chen, Linyong

    2016-01-01

    Bioconversion of coal to methane has gained increased attention in recent decades because of its economic and environmental advantages. However, the mechanism of this process is difficult to study in depth, partly because of difficulties associated with the analysis of intermediates generated in coal bioconversion. In this investigation, we report on an effective method to analyze volatile intermediates generated in the bioconversion of coal under strict anaerobic conditions. We conduct in-situ extraction of intermediates using headspace solid-phase micro-extraction followed by detection by gas chromatography-mass spectrometry. Bioconversion simulation equipment was modified and combined with a solid-phase micro-extraction device. In-situ extraction could be achieved by using the combined units, to avoid a breakdown in anaerobic conditions and to maintain the experiment continuity. More than 30 intermediates were identified qualitatively in the conversion process, and the variation in trends of some typical intermediates has been discussed. Volatile organic acids (C2–C7) were chosen for a quantitative study of the intermediates because of their importance during coal bioconversion to methane. Fiber coating, extraction time, and solution acidity were optimized in the solid-phase micro-extraction procedure. The pressure was enhanced during the bioconversion process to investigate the influence of headspace pressure on analyte extraction. The detection limits of the method ranged from 0.0006 to 0.02 mmol/L for the volatile organic acids and the relative standard deviations were between 4.6% and 11.5%. The volatile organic acids (C2–C7) generated in the bioconversion process were 0.01–1.15 mmol/L with a recovery range from 80% to 105%. The developed method is useful for further in-depth research on the bioconversion of coal to methane. PMID:27695055

  6. Intense Mixing and Recirculations of Intermediate and Deep Water in the Northwest Argentine Basin

    NASA Astrophysics Data System (ADS)

    Valla, D.; Piola, A. R.

    2016-02-01

    The sources of the South Atlantic upper and intermediate waters that form the upper layer flow needed to maintain mass balance due the export of North Atlantic Deep Water from the North Atlantic are still under debate. The "cold path" scheme postulates that intermediate waters are injected into the South Atlantic from the Pacific through the Drake Passage, advected north by the Malvinas Current up to the Brazil/Malvinas Confluence (BMC) and circulated around the basin following the path of the subtropical gyre. We report high-quality hydrographic observations collected in the South Atlantic western boundary at 34.5 °S during 7 hydrographic cruises as part of the SAMOC project. We focus on the flow and characteristics of Antarctic Intermediate Water (AAIW) and Upper Circumpolar Deep Water (UCDW). The water mass analysis indicates the presence of "young" (fresh and highly oxygenated) varieties of AAIW (S<34.2, O2>6 ml·l-1) which must be derived from south of the SAMOC array. This suggests an alternative pathway for intermediate waters that involves a short circuit beneath the BMC. Simultaneous full-depth velocity measurements using lowered acoustic Doppler current profilers confirm this hypothesis. The flow direction across the SAMOC array in the UCDW range inferred from dissolved oxygen measurements also indicate the presence of UCDW (O2<4.2 ml·l-1) derived from farther south. However, the wider range of oxygen concentrations suggests strong recirculations of both water masses within the northwestern Argentine Basin.

  7. Profiler Support for Operations at Space Launch Ranges

    NASA Technical Reports Server (NTRS)

    Merceret, Francis; Wilfong, Timothy; Lambert, Winifred; Short, David; Decker, Ryan; Ward, Jennifer

    2006-01-01

    Accurate vertical wind profiles are essential to successful launch or landing. Wind changes can make it impossible to fly a desired trajectory or avoid dangerous vehicle loads, possibly resulting in loss of mission. Balloons take an hour to generate a profile up to 20 km, but major wind changes can occur in 20 minutes. Wind profilers have the temporal response to detect such last minute hazards. They also measure the winds directly overhead while balloons blow downwind. At the Eastern Range (ER), altitudes from 2 to 20 km are sampled by a 50-MHz profiler every 4 minutes. The surface to 3 km is sampled by five 915-MHz profilers every 15 minutes. The Range Safety office assesses the risk of potential toxic chemical dispersion. They use observational data and model output to estimate the spatial extent and concentration of substances dispersed within the boundary layer. The ER uses 915-MHz profilers as both a real time observation system and as input to dispersion models. The WR has similar plans. Wind profilers support engineering analyses for the Space Shuttle. The 50-IVl11z profiler was used recently to analyze changes in the low frequency wind and low vertical wavenumber content of wind profiles in the 3 to 15 km region of the atmosphere. The 915-MHz profiler network was used to study temporal wind change within the boundary layer.

  8. Hydrology of the Goat Lake watershed, Snohomish County, Washington, 1982-87

    USGS Publications Warehouse

    Dion, N.P.; Ebbert, J.C.; Poole, J.E.; Peck, B.S.

    1989-01-01

    The Goat Lake watershed in Snohomish County, Washington, functions as an ' experimental watershed ' for long-term studies to determine the effects of acidic precipitation on water resources. Data have been collected there by the U.S. Geological Survey since 1982. The watershed is in a wilderness area of the Cascade Range and is downwind of an industrial and urban area that produces chemical compounds found in acidic precipitation. The lake is considered sensitive to acidic inputs from atmospheric deposition and streamflow. The mean annual discharge of the Goat Lake outflow is 35 cu ft/sec; precipitation on the watershed is calculated to be about 170 in/yr. The inflow to Goat Lake is sufficient to replace the entire contents of the lake basin on an average every 21.5 days, or 17 times/year. Water in Goat Lake, and that of the inlet and outlet, is of low ionic strength and of calcium-bicarbonate type. The lake, although considered oligotrophic, is sufficiently deep to stratify thermally, and summer dissolved-oxygen concentrations in the hypolimnion are depressed. Even though alkalinity and specific conductance at Goat Lake are in the range considered sensitive to acidic inputs , the pH of water in the lake has consistently ranged from 6.1 to 7.2, indicating that the lake is not acidified at this time. (USGS)

  9. Deposition of aerially applied BT in an oak forest and its prediction with the FSCBG model

    USGS Publications Warehouse

    Anderson, Dean E.; Miller, David R.; Wang, Yansen; Yendol, William G.; Mierzejewski, Karl; McManus, Michael L.

    1992-01-01

    Data are provided from 17 single-swath aerial spray trials that were conducted over a fully leafed, 16-m tall, mixed oak forest. The distribution of cross-swath spray deposits was sampled at the top of the canopy and below the canopy. Micrometeorological conditions were measured above and within the canopy during the spray trials. The USDA Forest Service FSCBG (Forest Service-Cramer-Barry-Grim) model was run to predict the target sampler catch for each trial using forest stand, airplane-application-equipment configuration, and micrometeorological conditions as inputs. Observations showed an average cross-swath deposition of 100 IU cm−2 with large run-to-run variability in deposition patterns, magnitudes, and drift. Eleven percent of the spray material that reached the top of the canopy penetrated through the tree canopy to the forest floor.The FSCBG predictions of the ensemble-averaged deposition were within 17% of the measured deposition at the canopy top and within 8% on the ground beneath the canopy. Run-to-run deposit predictions by FSCBG were considerably less variable than the measured deposits. Individual run predictions were much less accurate than the ensemble-averaged predictions as demonstrated by an average root-mean-square-error (rmse) of 27.9 IU CM−2 at the top of the canopy. Comparisons of the differences between predicted and observed deposits indicated that the model accuracy was sensitive to atmospheric stability conditions. In neutral and stable conditions, a regular pattern of error was indicated by overprediction of the canopy-top deposit at distances from 0 to 20 m downwind from the flight line and underprediction of the deposit both farther downwind than 20 m and upwind of the flight line. In unstable conditions the model generally underpredicted the deposit downwind from the flight line, but showed no regular pattern of error.

  10. Comprehensive Evaluation of Fast-Response, Reynolds-Averaged Navier–Stokes, and Large-Eddy Simulation Methods Against High-Spatial-Resolution Wind-Tunnel Data in Step-Down Street Canyons

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hayati, Arash Nemati; Stoll, Rob; Kim, J. J.

    Three computational fluid dynamics (CFD) methods with different levels of flow-physics modelling are comprehensively evaluated against high-spatial-resolution wind-tunnel velocity data from step-down street canyons (i.e., a short building downwind of a tall building). The first method is a semi-empirical fast-response approach using the Quick Urban Industrial Complex (QUIC-URB) model. The second method solves the Reynolds-averaged Navier–Stokes (RANS) equations, and the third one utilizes a fully-coupled fluid-structure interaction large-eddy simulation (LES) model with a grid-turbulence inflow generator. Unlike typical point-by-point evaluation comparisons, here the entire two-dimensional wind-tunnel dataset is used to evaluate the dynamics of dominant flow topological features in themore » street canyon. Each CFD method is scrutinized for several geometric configurations by varying the downwind-to-upwind building-height ratio (H d/H u) and street canyon-width to building-width aspect ratio (S / W) for inflow winds perpendicular to the upwind building front face. Disparities between the numerical results and experimental data are quantified in terms of their ability to capture flow topological features for different geometric configurations. Ultimately, all three methods qualitatively predict the primary flow topological features, including a saddle point and a primary vortex. But, the secondary flow topological features, namely an in-canyon separation point and secondary vortices, are only well represented by the LES method despite its failure for taller downwind building cases. Misrepresentation of flow-regime transitions, exaggeration of the coherence of recirculation zones and wake fields, and overestimation of downwards vertical velocity into the canyon are the main defects in QUIC-URB, RANS and LES results, respectively. All three methods underestimate the updrafts and, surprisingly, QUIC-URB outperforms RANS for the streamwise velocity component, while RANS is superior to QUIC-URB for the vertical velocity component in the street canyon.« less

  11. Comprehensive Evaluation of Fast-Response, Reynolds-Averaged Navier–Stokes, and Large-Eddy Simulation Methods Against High-Spatial-Resolution Wind-Tunnel Data in Step-Down Street Canyons

    DOE PAGES

    Hayati, Arash Nemati; Stoll, Rob; Kim, J. J.; ...

    2017-05-18

    Three computational fluid dynamics (CFD) methods with different levels of flow-physics modelling are comprehensively evaluated against high-spatial-resolution wind-tunnel velocity data from step-down street canyons (i.e., a short building downwind of a tall building). The first method is a semi-empirical fast-response approach using the Quick Urban Industrial Complex (QUIC-URB) model. The second method solves the Reynolds-averaged Navier–Stokes (RANS) equations, and the third one utilizes a fully-coupled fluid-structure interaction large-eddy simulation (LES) model with a grid-turbulence inflow generator. Unlike typical point-by-point evaluation comparisons, here the entire two-dimensional wind-tunnel dataset is used to evaluate the dynamics of dominant flow topological features in themore » street canyon. Each CFD method is scrutinized for several geometric configurations by varying the downwind-to-upwind building-height ratio (H d/H u) and street canyon-width to building-width aspect ratio (S / W) for inflow winds perpendicular to the upwind building front face. Disparities between the numerical results and experimental data are quantified in terms of their ability to capture flow topological features for different geometric configurations. Ultimately, all three methods qualitatively predict the primary flow topological features, including a saddle point and a primary vortex. But, the secondary flow topological features, namely an in-canyon separation point and secondary vortices, are only well represented by the LES method despite its failure for taller downwind building cases. Misrepresentation of flow-regime transitions, exaggeration of the coherence of recirculation zones and wake fields, and overestimation of downwards vertical velocity into the canyon are the main defects in QUIC-URB, RANS and LES results, respectively. All three methods underestimate the updrafts and, surprisingly, QUIC-URB outperforms RANS for the streamwise velocity component, while RANS is superior to QUIC-URB for the vertical velocity component in the street canyon.« less

  12. Size-distributed metallic elements in submicronic and ultrafine atmospheric particles from urban and industrial areas in northern France

    NASA Astrophysics Data System (ADS)

    Mbengue, Saliou; Alleman, Laurent Y.; Flament, Pascal

    2014-01-01

    To determine the size distribution of potentially toxic trace metals (TM) in atmospheric particulate matter (PM), sampling experiments were performed in the urban-industrial area of Dunkirk (North of France) during winter 2012. Total mass concentrations are in accordance with typical values obtained at European urban background sites but lower than the concentrations reported for some Asian industrial countries. Considering the local wind directions, mass concentrations are higher downwind of urban influences than downwind of industrial emissions. The mean PM10 mass concentration (25-30 μg/m3) is less than the European Union and US EPA limit values (40-50 μg/m3) but greater than the WHO guidelines (20 μg/m3). The calculated TM crustal enrichment factors (EFCrust) suggest the anthropogenic origins of most of the studied TM (Sb, Cd, As, Mo, Pb, Zn, Cu, Ni, Cr, Mn and V). The highest TM concentrations were obtained for Zn and Mn (> 50 ng/m3) under industrial influence, but the finest particle (< 0.29 μm) concentrations were higher for the urban sector than for the industrial sector. This enrichment may be attributed to local urban traffic. In contrast, trace metals are more abundant in the coarser fraction (> 0.29 μm) downwind of industrial emissions. Moreover, mechanical operations associated with industrial processes (excavating, crushing, and sintering), as well as the resuspension of industrial soils, likely represent some significant TM source-terms in the supermicronic fraction. The EFCrust comparison between the two prevailing sectors demonstrates the importance of steelworks and smelting emissions in the abundance of some TM (As, Cd, Fe, Mn, Mo, Pb, Rb and Zn). In contrast, the Cr and Co concentrations seem to be more related to coal combustion emissions, Cu and Sb to automotive traffic, and V, La and Ni to petrochemical activities.

  13. Comprehensive Evaluation of Fast-Response, Reynolds-Averaged Navier-Stokes, and Large-Eddy Simulation Methods Against High-Spatial-Resolution Wind-Tunnel Data in Step-Down Street Canyons

    NASA Astrophysics Data System (ADS)

    Hayati, Arash Nemati; Stoll, Rob; Kim, J. J.; Harman, Todd; Nelson, Matthew A.; Brown, Michael J.; Pardyjak, Eric R.

    2017-08-01

    Three computational fluid dynamics (CFD) methods with different levels of flow-physics modelling are comprehensively evaluated against high-spatial-resolution wind-tunnel velocity data from step-down street canyons (i.e., a short building downwind of a tall building). The first method is a semi-empirical fast-response approach using the Quick Urban Industrial Complex (QUIC-URB) model. The second method solves the Reynolds-averaged Navier-Stokes (RANS) equations, and the third one utilizes a fully-coupled fluid-structure interaction large-eddy simulation (LES) model with a grid-turbulence inflow generator. Unlike typical point-by-point evaluation comparisons, here the entire two-dimensional wind-tunnel dataset is used to evaluate the dynamics of dominant flow topological features in the street canyon. Each CFD method is scrutinized for several geometric configurations by varying the downwind-to-upwind building-height ratio (H_d/H_u) and street canyon-width to building-width aspect ratio ( S / W) for inflow winds perpendicular to the upwind building front face. Disparities between the numerical results and experimental data are quantified in terms of their ability to capture flow topological features for different geometric configurations. Overall, all three methods qualitatively predict the primary flow topological features, including a saddle point and a primary vortex. However, the secondary flow topological features, namely an in-canyon separation point and secondary vortices, are only well represented by the LES method despite its failure for taller downwind building cases. Misrepresentation of flow-regime transitions, exaggeration of the coherence of recirculation zones and wake fields, and overestimation of downwards vertical velocity into the canyon are the main defects in QUIC-URB, RANS and LES results, respectively. All three methods underestimate the updrafts and, surprisingly, QUIC-URB outperforms RANS for the streamwise velocity component, while RANS is superior to QUIC-URB for the vertical velocity component in the street canyon.

  14. Effects of natural factors on the spatial distribution of heavy metals in soils surrounding mining regions.

    PubMed

    Ding, Qian; Cheng, Gong; Wang, Yong; Zhuang, Dafang

    2017-02-01

    Various studies have shown that soils surrounding mining areas are seriously polluted with heavy metals. Determining the effects of natural factors on spatial distribution of heavy metals is important for determining the distribution characteristics of heavy metals in soils. In this study, an 8km buffer zone surrounding a typical non-ferrous metal mine in Suxian District of Hunan Province, China, was selected as the study area, and statistical, spatial autocorrelation and spatial interpolation analyses were used to obtain descriptive statistics and spatial autocorrelation characteristics of As, Pb, Cu, and Zn in soil. Additionally, the distributions of soil heavy metals under the influences of natural factors, including terrain (elevation and slope), wind direction and distance from a river, were determined. Layout of sampling sites, spatial changes of heavy metal contents at high elevations and concentration differences between upwind and downwind directions were then evaluated. The following results were obtained: (1) At low elevations, heavy metal concentrations decreased slightly, then increased considerably with increasing elevation. At high elevations, heavy metal concentrations first decreased, then increased, then decreased with increasing elevation. As the slope increased, heavy metal contents increased then decreased. (2) Heavy metal contents changed consistently in the upwind and downwind directions. Heavy metal contents were highest in 1km buffer zone and decreased with increasing distance from the mining area. The largest decrease in heavy metal concentrations was in 2km buffer zone. Perennial wind promotes the transport of heavy metals in downwind direction. (3) The spatial extent of the influence of the river on Pb, Zn and Cu in the soil was 800m. (4) The influence of the terrain on the heavy metal concentrations was greater than that of the wind. These results provide a scientific basis for preventing and mitigating heavy metal soil pollution in areas surrounding mines. Copyright © 2016 Elsevier B.V. All rights reserved.

  15. Ammonia and Methane Dairy Emission Plumes in the San Joaquin Valley of California from Individual Feedlot to Regional Scales

    NASA Technical Reports Server (NTRS)

    Miller, David J.; Sun, Kang; Pan, Da; Zondlo, Mark A.; Nowak, John B.; Liu, Zhen; Diskin, Glenn; Sachse, Glen; Beyersdorf, Andreas; Ferrare, Richard; hide

    2015-01-01

    Agricultural ammonia (NH3) emissions are highly uncertain, with high spatiotemporal variability and a lack of widespread in situ measurements. Regional NH3 emission estimates using mass balance or emission ratio approaches are uncertain due to variable NH3 sources and sinks as well as unknown plume correlations with other dairy source tracers. We characterize the spatial distributions of NH3 and methane (CH4) dairy plumes using in situ surface and airborne measurements in the Tulare dairy feedlot region of the San Joaquin Valley, California, during the NASA Deriving Information on Surface conditions from Column and Vertically Resolved Observations Relevant to Air Quality 2013 field campaign. Surface NH3 and CH4 mixing ratios exhibit large variability with maxima localized downwind of individual dairy feedlots. The geometric mean NH3:CH4 enhancement ratio derived from surface measurements is 0.15 +/- 0.03 ppmv ppmv-1. Individual dairy feedlots with spatially distinct NH3 and CH4 source pathways led to statistically significant correlations between NH3 and CH4 in 68% of the 69 downwind plumes sampled. At longer sampling distances, the NH3:CH4 enhancement ratio decreases 20-30%, suggesting the potential for NH3 deposition as a loss term for plumes within a few kilometers downwind of feedlots. Aircraft boundary layer transect measurements directly above surface mobile measurements in the dairy region show comparable gradients and geometric mean enhancement ratios within measurement uncertainties, even when including NH3 partitioning to submicron particles. Individual NH3 and CH4 plumes sampled at close proximity where losses are minimal are not necessarily correlated due to lack of mixing and distinct source pathways. Our analyses have important implications for constraining NH3 sink and plume variability influences on regional NH3 emission estimates and for improving NH3 emission inventory spatial allocations.

  16. Earth Observations taken by the Expedition 18 Crew

    NASA Image and Video Library

    2008-12-20

    ISS018-E-014770 (20 Dec. 2008) --- Sand dunes in the Marzuq Sand Sea, southwest Libya are featured in this image photographed by an Expedition 18 crewmember on the International Space Station. This detailed view, taken from low Earth orbit, shows classic large and small sand masses of the Central Sahara where wind is a more powerful land-forming agent than water. ?Draa? dunes (from the Arabic for ?arm?) are very large masses of sand and appear here as the broad network of yellow-orange sand masses (the image covers a region approximately 9.4 kilometers wide), with smooth-floored, almost sand-free basins between them. These sand masses lie in the western part of Libya?s vast Marzuq Sand Sea (greater than 60,000 square kilometers, centered at 24.5N 12W). Geologists think that the draa of the Marzuq have probably been formed by winds different from the dominant north/northeast winds of today. Numerous smaller dunes can be seen developed on the backs of the draa. Three distinct dune types can be identified: longitudinal dunes (formed essentially parallel with formative winds from the north); transverse dunes, usually more curved, formed at right angles to the formative wind; and star dunes, in which several linear arms converge towards a single peak. The upwind side of the sand masses appears smoother than the more rippled downwind side. Wind is moving sand grains almost all the time. This means that the draa and the dunes are all moving -- as sand is added on the upwind side and blown off the downwind side. It is well known that small sand masses move much faster than large sand masses. This means that the draa are almost stationary, but that the smaller dunes are moving relatively quickly across their backs. When the dunes reach the downwind side of the draa they are obliterated, their sand being blown across the basins as individual grains.

  17. Ammonia and methane dairy emissions in the San Joaquin Valley of California from individual feedlot to regional scale

    DOE PAGES

    Miller, David J.; Sun, Kang; Tao, Lei; ...

    2015-09-27

    Agricultural ammonia (NH 3) emissions are highly uncertain, with high spatiotemporal variability and a lack of widespread in situ measurements. Regional NH 3 emission estimates using mass balance or emission ratio approaches are uncertain due to variable NH 3 sources and sinks as well as unknown plume correlations with other dairy source tracers. We characterize the spatial distributions of NH 3 and methane (CH 4) dairy plumes using in situ surface and airborne measurements in the Tulare dairy feedlot region of the San Joaquin Valley, California, during the NASA Deriving Information on Surface conditions from Column and Vertically Resolved Observationsmore » Relevant to Air Quality 2013 field campaign. Surface NH 3 and CH 4 mixing ratios exhibit large variability with maxima localized downwind of individual dairy feedlots. The geometric mean NH 3:CH 4 enhancement ratio derived from surface measurements is 0.15 ± 0.03 ppmv ppmv –1. Individual dairy feedlots with spatially distinct NH 3 and CH 4 source pathways led to statistically significant correlations between NH 3 and CH 4 in 68% of the 69 downwind plumes sampled. At longer sampling distances, the NH 3:CH 4 enhancement ratio decreases 20–30%, suggesting the potential for NH 3 deposition as a loss term for plumes within a few kilometers downwind of feedlots. Aircraft boundary layer transect measurements directly above surface mobile measurements in the dairy region show comparable gradients and geometric mean enhancement ratios within measurement uncertainties, even when including NH 3 partitioning to submicron particles. Individual NH 3 and CH 4 plumes sampled at close proximity where losses are minimal are not necessarily correlated due to lack of mixing and distinct source pathways. As a result, our analyses have important implications for constraining NH 3 sink and plume variability influences on regional NH 3 emission estimates and for improving NH 3 emission inventory spatial allocations.« less

  18. Indexing method for assessment of pollution potential of leachate from non-engineered landfill sites and its effect on ground water quality.

    PubMed

    Rana, Rishi; Ganguly, Rajiv; Gupta, Ashok Kumar

    2017-12-26

    Dumping of solid waste in a non-engineered landfill site often leads to contamination of ground water due to leachate percolation into ground water. The present paper assesses the pollution potential of leachate generated from three non-engineered landfill sites located in the Tricity region (one each in cities of Chandigarh, Mohali and Panchkula) of Northern India and its possible effects of contamination of groundwater. Analysis of physico-chemical properties of leachate from all the three landfill sites and the surrounding groundwater samples from five different downwind distances from each of the landfill sites were collected and tested to determine the leachate pollution index (LPI) and the water quality index (WQI). The Leachate Pollution Index values of 26.1, 27 and 27.8 respectively for landfill sites of Chandigarh (CHD), Mohali (MOH) and Panchkula (PKL) cities showed that the leachate generated are contaminated. The average pH values of the leachate samples over the sampling period (9.2 for CHD, 8.97 for MOH and 8.9 for PKL) show an alkaline nature indicating that all the three landfill sites could be classified as mature to old stage. The WQI calculated over the different downwind distances from the contamination sites showed that the quality of the groundwater improved with an increase in the downwind distance. Principal component analysis (PCA) carried out established major components mainly from natural and anthropogenic sources with cumulative variance of 88% for Chandigarh, 87.1% for Mohali and 87.8% for Panchkula. Hierarchical cluster analysis (HCA) identifies three distinct cluster types for the groundwater samples. These clusters corresponds to a relatively low pollution, moderate pollution and high pollution regions. It is suggested that all the three non-engineered landfill sites be converted to engineered landfill sites to prevent groundwater contamination and also new sites be considered for construction of these engineered landfill sites as the present dumpsites are nearing the end of their lifespan capacity.

  19. The primary volcanic aerosol emission from Mt Etna: Size-resolved particles with SO2 and role in plume reactive halogen chemistry

    NASA Astrophysics Data System (ADS)

    Roberts, T. J.; Vignelles, D.; Liuzzo, M.; Giudice, G.; Aiuppa, A.; Coltelli, M.; Salerno, G.; Chartier, M.; Couté, B.; Berthet, G.; Lurton, T.; Dulac, F.; Renard, J.-B.

    2018-02-01

    Volcanoes are an important source of aerosols to the troposphere. Within minutes after emission, volcanic plume aerosol catalyses conversion of co-emitted HBr, HCl into highly reactive halogens (e.g. BrO, OClO) through chemical cycles that cause substantial ozone depletion in the dispersing downwind plume. This study quantifies the sub-to-supramicron primary volcanic aerosol emission (0.2-5 μm diameter) and its role in this process. An in-situ ground-based study at Mt Etna (Italy) during passive degassing co-deployed an optical particle counter and Multi-Gas SO2 sensors at high time resolution (0.1 Hz) enabling to characterise the aerosol number, size-distribution and emission flux. A tri-modal volcanic aerosol size distribution was found, to which lognormal distributions are fitted. Total particle volume correlates to SO2 (as a plume tracer). The measured particle volume:SO2 ratio equates to a sulfate:SO2 ratio of 1-2% at the observed meteorological conditions (40% Relative Humidity). A particle mass flux of 0.7 kg s-1 is calculated for the measured Mt Etna SO2 flux of 1950 tonnes/day. A numerical plume atmospheric chemistry model is used to simulate the role of the hygroscopic primary aerosol surface area and its humidity dependence on volcanic plume BrO and OClO chemistry. As well as predicting volcanic BrO formation and O3 depletion, the model achieves OClO/SO2 in broad quantitative agreement with recently reported Mt Etna observations, with a predicted maximum a few minutes downwind. In addition to humidity - that enhances aerosols surface area for halogen cycling - background ozone is predicted to be an important control on OClO/SO2. Dependence of BrO/SO2 on ambient humidity is rather low near-to-source but increases further downwind. The model plume chemistry also exhibits strong across-plume spatial variations between plume edge and centre.

  20. Using models to interpret the impact of roadside barriers on near-road air quality

    NASA Astrophysics Data System (ADS)

    Amini, Seyedmorteza; Ahangar, Faraz Enayati; Schulte, Nico; Venkatram, Akula

    2016-08-01

    The question this paper addresses is whether semi-empirical dispersion models based on data from controlled wind tunnel and tracer experiments can describe data collected downwind of a sound barrier next to a real-world urban highway. Both models are based on the mixed wake model described in Schulte et al. (2014). The first neglects the effects of stability on dispersion, and the second accounts for reduced entrainment into the wake of the barrier under unstable conditions. The models were evaluated with data collected downwind of a kilometer-long barrier next to the I-215 freeway running next to the University of California campus in Riverside. The data included measurements of 1) ultrafine particle (UFP) concentrations at several distances from the barrier, 2) micrometeorological variables upwind and downwind of the barrier, and 3) traffic flow separated by automobiles and trucks. Because the emission factor for UFP is highly uncertain, we treated it as a model parameter whose value is obtained by fitting model estimates to observations of UFP concentrations measured at distances where the barrier impact is not dominant. Both models provide adequate descriptions of both the magnitude and the spatial variation of observed concentrations. The good performance of the models reinforces the conclusion from Schulte et al. (2014) that the presence of the barrier is equivalent to shifting the line sources on the road upwind by a distance of about HU/u∗ where H is the barrier height, U is the wind velocity at half of the barrier height, and u∗ is the friction velocity. The models predict that a 4 m barrier results in a 35% reduction in average concentration within 40 m (10 times the barrier height) of the barrier, relative to the no-barrier site. This concentration reduction is 55% if the barrier height is doubled.

  1. Explaining intermediate filament accumulation in giant axonal neuropathy

    PubMed Central

    Opal, Puneet; Goldman, Robert D.

    2013-01-01

    Giant axonal neuropathy (GAN)1 is a rare autosomal recessive neurological disorder caused by mutations in the GAN gene that encodes gigaxonin, a member of the BTB/Kelch family of E3 ligase adaptor proteins.1 This disease is characterized by the aggregation of Intermediate Filaments (IF)—cytoskeletal elements that play important roles in cell physiology including the regulation of cell shape, motility, mechanics and intra-cellular signaling. Although a range of cell types are affected in GAN, neurons display the most severe pathology, with neuronal intermediate filament accumulation and aggregation; this in turn causes axonal swellings or “giant axons.” A mechanistic understanding of GAN IF pathology has eluded researchers for many years. In a recent study1 we demonstrate that the normal function of gigaxonin is to regulate the degradation of IF proteins via the proteasome. Our findings present the first direct link between GAN mutations and IF pathology; moreover, given the importance of IF aggregations in a wide range of disease conditions, our findings could have wider ramifications. PMID:25003002

  2. Glutamatergic drive along the septo-temporal axis of hippocampus boosts prelimbic oscillations in the neonatal mouse

    PubMed Central

    Ahlbeck, Joachim; Song, Lingzhen; Chini, Mattia; Bitzenhofer, Sebastian H

    2018-01-01

    The long-range coupling within prefrontal-hippocampal networks that account for cognitive performance emerges early in life. The discontinuous hippocampal theta bursts have been proposed to drive the generation of neonatal prefrontal oscillations, yet the cellular substrate of these early interactions is still unresolved. Here, we selectively target optogenetic manipulation of glutamatergic projection neurons in the CA1 area of either dorsal or intermediate/ventral hippocampus at neonatal age to elucidate their contribution to the emergence of prefrontal oscillatory entrainment. We show that despite stronger theta and ripples power in dorsal hippocampus, the prefrontal cortex is mainly coupled with intermediate/ventral hippocampus by phase-locking of neuronal firing via dense direct axonal projections. Theta band-confined activation by light of pyramidal neurons in intermediate/ventral but not dorsal CA1 that were transfected by in utero electroporation with high-efficiency channelrhodopsin boosts prefrontal oscillations. Our data causally elucidate the cellular origin of the long-range coupling in the developing brain. PMID:29631696

  3. Isothermal decay studies of intermediate energy levels in quartz.

    PubMed

    Veronese, I; Giussani, A; Göksu, H Y; Martini, M

    2004-05-01

    The recent interest in the thermoluminescence of quartz extracted from unfired building materials, such as mortar and concrete for dose reconstruction applications, led to the requirement of an accurate determination of the lifetime of the intermediate glow peaks in this mineral. The prediction of the lifetimes of these peaks is helpful in establishing the likely time range within which retrospective measurements can be carried out. These peaks, corresponding to intermediate energy levels, occur in the glow curve in the temperature range 150-250 degrees C (heating rate 2 degrees C/s). Lifetimes of 720+/-70 days and 580+/-70 years (at a temperature of 15 degrees C) were derived for the two main peaks placed in the glow curve at approximately 150 degrees C and 200 degrees C, respectively, using the isothermal decay technique. These results as well as the estimated values of the trap parameters (thermal activation energy and frequency factor) have been compared with the data already available in the literature.

  4. Compound hydraulic shear-modulated vortex amplifiers

    NASA Technical Reports Server (NTRS)

    Goldschmied, F. R.

    1977-01-01

    A novel two-stage shear-modulated hydraulic vortex amplifier (U.S. patent 3,520,317) has been fabricated and put through preliminary steady-state testing at the 1000 psi supply pressure level with flows up to 15 gpm. The invention comprises a conventional fluidic vortex power stage and a shear-modulated pilot stage. In the absence of any mechanical moving parts, water may be used as the hydraulic medium thus opening the way to many underseas applications. At blocked load, a control input from 0 to 150 psi was required to achieve an output from 0 to 900 psi; at wide-open load, a control input of 0 to 120 psi was needed to achieve an output from 0 to 15 gpm. The power stage has been found unsuitable for the proportional control mode because of its nonlinear performance in the intermediate load range and because of strong pressure fluctuations (plus or minus 150 psi) in the intermediate control range. The addition of the shear-modulated pilot stage improves intermediate load linearity.

  5. IRAS 23385 & 6053: A Prototype Massive Class O Object

    NASA Technical Reports Server (NTRS)

    Molinari, S.; Testi, L.; Brand, J.; Cesaroni, R.; Palla, F.

    1998-01-01

    The last few years have seen a rapid growth in observations aimed at identifying intermediate and high-mass star forming sites in a wide range of evolutionary stages ranging from Hot Cores to ultracompact regions, to proto-Ae/Be stars.

  6. Advanced Offshore Wind Turbine/Foundation Concept for the Great Lakes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Afjeh, Abdollah A.; Windpower, Nautica; Marrone, Joseph

    2013-08-29

    This project investigated a conceptual 2-bladed rotor wind turbine design and assessed its feasibility for installation in the Great Lakes. The levelized cost of energy was used for this purpose. A location in Lake Erie near the coast of Cleveland, Ohio was selected as the application site. The loading environment was defined using wind and wave data collected at a weather station in Lake Erie near Cleveland. In addition, the probability distributions of the annual significant wave height and wind speed were determined. A model of the dependence of the above two quantities was also developed and used in themore » study of wind turbine system loads. Loads from ice floes and ridges were also included.The NREL 5 MW 3-bladed rotor wind turbine concept was used as the baseline design. The proposed turbine design employs variable pitch blade control with tip-brakes and a teeter mechanism. The rotor diameter, rated power and the tower dimensions were selected to closely match those of the NREL 5 MW wind turbine.A semi-floating gravity base foundation was designed for this project primarily to adapt to regional logistical constraints to transport and install the gravity base foundation. This foundation consists of, from bottom to top, a base plate, a buoyancy chamber, a taper zone, a column (with ice cone), and a service platform. A compound upward-downward ice cone was selected to secure the foundation from moving because of ice impact.The turbine loads analysis was based on International ElectroTechnical Committee (IEC) Standard 61400-1, Class III winds. The NREL software FAST was the primary computational tool used in this study to determine all design load cases. An initial set of studies of the dynamics of wind turbines using Automatic Dynamic Analysis of Mechanical Systems (ADAMS) demonstrated that FAST and ADAMS load predictions were comparable. Because of its relative simplicity and short run times, FAST was selected for this study. For ice load calculations, a method was developed and implemented in FAST to extend its capability for ice load modeling.Both upwind and downwind 2-bladed rotor wind turbine designs were developed and studied. The new rotor blade uses a new twist angle distribution design and a new pitch control algorithm compared with the baseline model. The coning and tilt angles were selected for both the upwind and downwind configurations to maximize the annual energy production. The risk of blade-tower impact is greater for the downwind design, particularly under a power grid fault; however, this risk was effectively reduced by adjusting the tilt angle for the downwind configuration.« less

  7. Quantitative analysis of autophagic flux by confocal pH-imaging of autophagic intermediates

    PubMed Central

    Maulucci, Giuseppe; Chiarpotto, Michela; Papi, Massimiliano; Samengo, Daniela; Pani, Giovambattista; De Spirito, Marco

    2015-01-01

    Although numerous techniques have been developed to monitor autophagy and to probe its cellular functions, these methods cannot evaluate in sufficient detail the autophagy process, and suffer limitations from complex experimental setups and/or systematic errors. Here we developed a method to image, contextually, the number and pH of autophagic intermediates by using the probe mRFP-GFP-LC3B as a ratiometric pH sensor. This information is expressed functionally by AIPD, the pH distribution of the number of autophagic intermediates per cell. AIPD analysis reveals how intermediates are characterized by a continuous pH distribution, in the range 4.5–6.5, and therefore can be described by a more complex set of states rather than the usual biphasic one (autophagosomes and autolysosomes). AIPD shape and amplitude are sensitive to alterations in the autophagy pathway induced by drugs or environmental states, and allow a quantitative estimation of autophagic flux by retrieving the concentrations of autophagic intermediates. PMID:26506895

  8. Generalized thickness and configuration of the top of the intermediate aquifer, west-central Florida

    USGS Publications Warehouse

    Corral, Miguel A.; Wolansky, Richard M.

    1984-01-01

    Generalized map show the thickness and top of the intermediate aquifer in west-central Florida within the boundaries of the Southwest Florida Water Management District. The intermediate aquifer consists of a series of water-bearing units and confining beds between the surficial aquifer (water table) and the Floridan aquifer. This aquifer contains from one to several water-bearing units in west-central Florida. The aquifer and confining beds consist of the Tamiami and Hawthorn Formations of late and middle Miocene age and parts of the Tampa Limestone of early Miocene age. The top of the intermediate aquifer is about 100 feet above sea level in the north and slopes to about 100 feet below sea level in the south. The thickness ranges from zero in the north to more than 600 feet in the south. Despite the high mineral content of the water in some areas, the intermediate aquifer offers the best source of ground water to the coastal and southern areas of west-central Florida. (USGS)

  9. Noise measurements for single and multiple operation of 50 kw wind turbine generators

    NASA Technical Reports Server (NTRS)

    Hubbard, H. H.; Shepherd, K. P.

    1982-01-01

    The noise characteristics of the U.S. Windpower Inc., 50 kw wind turbine generator were measured at various distances from 30 m to 1100 m and for a range of output power. The generated noise is affected by the aerodynamic wakes of the tower legs at frequencies below about 120 Hz and the blade trailing edge thickness at frequencies of about 2 kHz. Rope strakes and airfoil fairings on the legs did not result in substantial noise reductions. Sharpening the blade trailing edges near the tip was effective in reducing broad band noise near 2 kHz. For multiple machines the sound fields are superposed. A three-fold increase in number of machines (from 1 to 3) results in a predicted increase in he sound pressure level of about 5 dB. The detection threshold for 14 machines operating in a 13 - 20 mph wind is observed to be at approximately 1160 m in the downwind direction.

  10. Assessing the regional impact of Indonesian biomass burning emissions based on organic molecular tracers and chemical mass balance modeling

    NASA Astrophysics Data System (ADS)

    Engling, G.; He, J.; Betha, R.; Balasubramanian, R.

    2014-01-01

    Biomass burning activities commonly occur in Southeast Asia (SEA), and are particularly intense in Indonesia during dry seasons. The effect of biomass smoke emissions on air quality in the city state of Singapore was investigated during a haze episode in October 2006. Substantially increased levels of airborne particulate matter (PM) and associated chemical species were observed during the haze period. Specifically, the enhancement in the concentration of molecular tracers for biomass combustion such as levoglucosan by as much as two orders of magnitude and diagnostic ratios of individual organic compounds indicated that biomass burning emissions caused a regional smoke haze episode due to their long-range transport by prevailing winds. With the aid of air mass back trajectories and chemical mass balance modeling, large-scale forest and peat fires in Sumatra and Kalimantan were identified as the sources of the smoke aerosol, exerting a significant impact on air quality in downwind areas, such as Singapore.

  11. Assessing the regional impact of indonesian biomass burning emissions based on organic molecular tracers and chemical mass balance modeling

    NASA Astrophysics Data System (ADS)

    Engling, G.; He, J.; Betha, R.; Balasubramanian, R.

    2014-08-01

    Biomass burning activities commonly occur in Southeast Asia (SEA), and are particularly intense in Indonesia during the dry seasons. The effect of biomass smoke emissions on air quality in the city state of Singapore was investigated during a haze episode in October 2006. Substantially increased levels of airborne particulate matter (PM) and associated chemical species were observed during the haze period. Specifically, the enhancement in the concentration of molecular tracers for biomass combustion such as levoglucosan by as much as two orders of magnitude and the diagnostic ratios of individual organic compounds indicated that biomass burning emissions caused a regional smoke haze episode due to their long-range transport by prevailing winds. With the aid of air mass backward trajectories and chemical mass balance modeling, large-scale forest and peat fires in Sumatra and Kalimantan were identified as the sources of the smoke aerosol, exerting a significant impact on air quality in downwind areas, such as Singapore.

  12. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kuang, C; Artaxo, P; Martin, S

    Aerosol nucleation and initial growth were investigated during the Green Ocean Amazon (GoAmazon) 2014/15 campaign. Aerosol sampling occurred during the wet and dry seasons of 2014, and took place at the T3 measurement site, downwind of the city of Manaus, Brazil. Characterization of the aerosol size distribution from 10 to 500 nm was accomplished through the deployment of a conventional Scanning Mobility Particle Spectrometer (SMPS) and a fine condensation particle counter (> 10 nm). In order to directly measure aerosol nucleation and initial growth, a Nano SMPS (1.5-20 nm) was also deployed, consisting of a condensation particle counter-based electrical mobilitymore » spectrometer that was modified for the detection of sub-3 nm aerosol. Measurements of the aerosol size distribution from 1.5 nm to 10 nm were obtained during the first observational period, and from 3 nm to 15 nm during the second observational period. Routine, stable measurement in this size range was complicated due to persistent water condensation in the Nano SMPS and diffusional transport losses« less

  13. Characterization studies and indicated remediation methods for plutonium contaminated soils at the Nevada Test Site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Murarik, T.M.; Wenstrand, T.K.; Rogers, L.A.

    An initial soil characterization study was conducted to help identify possible remediation methods to remove plutonium from the Nevada Test Site and Tonapah Test Range surface soils. Results from soil samples collected across various isopleths at five sites indicate that the size-fraction distribution patterns of plutonium remain similar to findings from the Nevada Applied Ecology Group (NAEG) (1970's). The plutonium remains in the upper 10--15 cm of soils, as indicated in previous studies. Distribution of fine particles downwind'' of ground zero at each site is suggested. Whether this pattern was established immediately after each explosion or this resulted from post-shotmore » wind movement of deposited material is unclear. Several possible soil treatment scenarios are presented. Removal of plutonium from certain size fractions of the soils would alleviate the sites of much of the plutonium burden. However, the nature of association of plutonium with soil components will determine which remediation methods will most likely succeed.« less

  14. Characterization studies and indicated remediation methods for plutonium contaminated soils at the Nevada Test Site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Murarik, T.M.; Wenstrand, T.K.; Rogers, L.A.

    An initial soil characterization study was conducted to help identify possible remediation methods to remove plutonium from the Nevada Test Site and Tonapah Test Range surface soils. Results from soil samples collected across various isopleths at five sites indicate that the size-fraction distribution patterns of plutonium remain similar to findings from the Nevada Applied Ecology Group (NAEG) (1970`s). The plutonium remains in the upper 10--15 cm of soils, as indicated in previous studies. Distribution of fine particles ``downwind`` of ground zero at each site is suggested. Whether this pattern was established immediately after each explosion or this resulted from post-shotmore » wind movement of deposited material is unclear. Several possible soil treatment scenarios are presented. Removal of plutonium from certain size fractions of the soils would alleviate the sites of much of the plutonium burden. However, the nature of association of plutonium with soil components will determine which remediation methods will most likely succeed.« less

  15. Mercury accumulation in transplanted Hypogymnia physodes lichens downwind of Wisconsin chlor-alkali plant

    USGS Publications Warehouse

    Makholm, M.M.; Bennett, J.P.

    1998-01-01

    Emissions of mercury from a chlor-alkali plant in central Wisconsin have raised concern about possible effects on biota in the area. Samples of the lichen Hypogymnia physodes, which no longer grows in the area, were transplanted from a site in northeastern Wisconsin and positioned on plastic stands at varying distances up to 1250 m from the plant and sampled for Hg quarterly for one year to test the hypothesis that Hg would be taken up by the lichens and would decline with distance. Average tissue concentrations were elevated when first sampled at three months and continued to increase at the nearest sites until the study ended after one year. Average concentrations after a year of exposure ranged from 4418 ppb at 250 m from the plant to 403 ppb at 1250 m from the plant. The decrease over distance followed a negative exponential pattern. Background concentrations at a control site in northern Wisconsin averaged 155 ppb.

  16. Diluted thrombin time reliably measures low to intermediate plasma dabigatran concentrations.

    PubMed

    Božič-Mijovski, Mojca; Malmström, Rickard E; Malovrh, Petra; Antovic, Jovan P; Vene, Nina; Šinigoj, Petra; Mavri, Alenka

    2016-07-01

    Direct oral anticoagulant dabigatran was first introduced as a fixed-dose drug without routine coagulation monitoring, but current recommendations suggest that diluted thrombin time can be used to estimate plasma drug level. The aim of this study was to assess a diluted thrombin time assay based on the same thrombin reagent already used for traditional thrombin time measurements that reliably measure low to intermediate plasma dabigatran levels. We included 44 patients with atrial fibrillation who started treatment with dabigatran 150 mg (23 patients) or 110 mg (21 patients) twice a day. Blood samples were collected at baseline (no dabigatran) and 2-4 weeks after the beginning of dabigatran therapy at trough and at peak. Plasma dabigatran levels were measured with diluted thrombin time and compared to liquid chromatography with tandem mass spectrometry as the reference method. The performance of the diluted thrombin time was compared to Hemoclot® Thrombin Inhibitor and Ecarin Chromogenic Assay. In ex vivo plasma samples, diluted thrombin time highly correlated with the liquid chromatography with tandem mass spectrometry (Pearson's R = 0.9799). In the low to intermediate range (dabigatran concentration ≤ 100 µg/L) diluted thrombin time correlated significantly more closely to the liquid chromatography with tandem mass spectrometry (R = 0.964) than Hemoclot® Thrombin Inhibitor (R = 0.935, p = 0.05) or Ecarin Chromogenic Assay (R = 0.915, p < 0.01). It was also the only functional assay without any significant bias in the low to intermediate range. Both trough and peak diluted thrombin time values were similar to liquid chromatography with tandem mass spectrometry. We conclude that the diluted thrombin time assay presented in this study reliably detects dabigatran and that it is superior to the Hemoclot® Thrombin Inhibitor assay in the low to intermediate range. © The Author(s) 2015.

  17. Magnetic fields of intermediate mass T Tauri stars

    NASA Astrophysics Data System (ADS)

    Lavail, A.; Kochukhov, O.; Hussain, G. A. J.; Alecian, E.; Herczeg, G. J.; Johns-Krull, C.

    2017-12-01

    Aims: In this paper, we aim to measure the strength of the surface magnetic fields for a sample of five intermediate mass T Tauri stars and one low mass T Tauri star from late-F to mid-K spectral types. While magnetic fields of T Tauri stars at the low mass range have been extensively characterized, our work complements previous studies towards the intermediate mass range; this complementary study is key to evaluate how magnetic fields evolve during the transition from a convective to a radiative core. Methods: We studied the Zeeman broadening of magnetically sensitive spectral lines in the H-band spectra obtained with the CRIRES high-resolution near-infrared spectrometer. These data are modelled using magnetic spectral synthesis and model atmospheres. Additional constraints on non-magnetic line broadening mechanisms are obtained from modelling molecular lines in the K band or atomic lines in the optical wavelength region. Results: We detect and measure mean surface magnetic fields for five of the six stars in our sample: CHXR 28, COUP 107, V2062 Oph, V1149 Sco, and Par 2441. Magnetic field strengths inferred from the most magnetically sensitive diagnostic line range from 0.8 to 1.8 kG. We also estimate a magnetic field strength of 1.9 kG for COUP 107 from an alternative diagnostic. The magnetic field on YLW 19 is the weakest in our sample and is marginally detected, with a strength of 0.8 kG. Conclusions: We populate an uncharted area of the pre-main-sequence HR diagram with mean magnetic field measurements from high-resolution near-infrared spectra. Our sample of intermediate mass T Tauri stars in general exhibits weaker magnetic fields than their lower mass counterparts. Our measurements will be used in combination with other spectropolarimetric studies of intermediate mass and lower mass T Tauri stars to provide input into pre-main-sequence stellar evolutionary models.

  18. Large-scale determinants of intestinal schistosomiasis and intermediate host snail distribution across Africa: does climate matter?

    PubMed

    Stensgaard, Anna-Sofie; Utzinger, Jürg; Vounatsou, Penelope; Hürlimann, Eveline; Schur, Nadine; Saarnak, Christopher F L; Simoonga, Christopher; Mubita, Patricia; Kabatereine, Narcis B; Tchuem Tchuenté, Louis-Albert; Rahbek, Carsten; Kristensen, Thomas K

    2013-11-01

    The geographical ranges of most species, including many infectious disease agents and their vectors and intermediate hosts, are assumed to be constrained by climatic tolerances, mainly temperature. It has been suggested that global warming will cause an expansion of the areas potentially suitable for infectious disease transmission. However, the transmission of infectious diseases is governed by a myriad of ecological, economic, evolutionary and social factors. Hence, a deeper understanding of the total disease system (pathogens, vectors and hosts) and its drivers is important for predicting responses to climate change. Here, we combine a growing degree day model for Schistosoma mansoni with species distribution models for the intermediate host snail (Biomphalaria spp.) to investigate large-scale environmental determinants of the distribution of the African S. mansoni-Biomphalaria system and potential impacts of climatic changes. Snail species distribution models included several combinations of climatic and habitat-related predictors; the latter divided into "natural" and "human-impacted" habitat variables to measure anthropogenic influence. The predictive performance of the combined snail-parasite model was evaluated against a comprehensive compilation of historical S. mansoni parasitological survey records, and then examined for two climate change scenarios of increasing severity for 2080. Future projections indicate that while the potential S. mansoni transmission area expands, the snail ranges are more likely to contract and/or move into cooler areas in the south and east. Importantly, we also note that even though climate per se matters, the impact of humans on habitat play a crucial role in determining the distribution of the intermediate host snails in Africa. Thus, a future contraction in the geographical range size of the intermediate host snails caused by climatic changes does not necessarily translate into a decrease or zero-sum change in human schistosomiasis prevalence. Copyright © 2011 Elsevier B.V. All rights reserved.

  19. Catalytic Cyclization of o-Alkynyl Phenethylamines via Osmacyclopropene Intermediates: Direct Access to Dopaminergic 3-Benzazepines.

    PubMed

    Álvarez-Pérez, Andrea; González-Rodríguez, Carlos; García-Yebra, Cristina; Varela, Jesús A; Oñate, Enrique; Esteruelas, Miguel A; Saá, Carlos

    2015-11-02

    A novel osmium-catalyzed cyclization of o-alkynyl phenethylamines to give 3-benzazepines is reported. The procedure allows the straightforward preparation of a broad range of dopaminergic 3-benzazepine derivatives. Mechanistic investigations revealed that the process takes place via osmacyclopropene intermediates, which were isolated and characterized by X-ray crystallography. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Using Massive Star Clusters in Merger Remnants To Provide Reference Colors of Intermediate-Age Stellar Populations

    NASA Astrophysics Data System (ADS)

    Goudfrooij, Paul

    2009-07-01

    Much current research in cosmology and galaxy formation relies on an accurate interpretation of colors of galaxies in terms of their evolutionary state, i.e., in terms of ages and metallicities. One particularly important topic is the ability to identify early-type galaxies at "intermediate" ages { 500 Myr - 5 Gyr}, i.e., the period between the end of star formation and half the age of the universe. Currently, integrated-light studies must rely on population synthesis models which rest upon spectral libraries of stars in the solar neighborhood. These models have a difficult time correctly incorporating short-lived evolutionary phases such as thermally pulsing AGB stars, which produce up to 80% of the flux in the near-IR in this age range. Furthermore, intermediate-age star clusters in the Local Group do not represent proper templates against which to calibrate population synthesis models in this age range, because their masses are too low to render the effect of stochastic fluctuations due to the number of bright RGB and AGB stars negligible. As a consequence, current population synthesis models have trouble reconciling the evolutionary state of high-redshift galaxies from optical versus near-IR colors. We propose a simple and effective solution to this issue, namely obtaining high-quality EMPIRICAL colors of massive globular clusters in galaxy merger remnants which span this important age range. These colors should serve as relevant references, both to identify intermediate-age objects in the local and distant universe and as calibrators for population synthesis modellers.

  1. Topological Ordering and Viscosity in the Glassy Ge-Se System: The Search for a Structural or Dynamical Signature of the Intermediate Phase

    NASA Astrophysics Data System (ADS)

    Zeidler, Anita; Salmon, Philip S.; Whittaker, Dean A. J.; Pizzey, Keiron J.; Hannon, Alex C.

    2017-11-01

    The topological ordering of the network structure in vitreous Ge_xSe_{1-x} was investigated across most of the glass-forming region (0 ≤ x ≤ 0.4) by using high-resolution neutron diffraction to measure the Bhatia-Thornton number-number partial structure factor. This approach gives access to the composition dependence of the mean coordination number \\bar{n} and correlation lengths associated with the network ordering. The thermal properties of the samples were also measured by using temperature-modulated differential scanning calorimetry. The results do not point to a structural origin of the so-called intermediate phase, which in our work is indicated for the composition range 0.175(8) ≤ x ≤ 0.235(8) by a vanishingly-small non-reversing enthalpy near the glass transition. The midpoint of this range coincides with the mean-field expectation of a floppy-to-rigid transition at x = 0.20. The composition dependence of the liquid viscosity, as taken from the literature, was also investigated to look for a dynamical origin of the intermediate phase, using the Mauro-Yue-Ellison-Gupta-Allan (MYEGA) model to estimate the viscosity at the liquidus temperature. The evidence points to a maximum in the viscosity at the liquidus temperature, and a minimum in the fragility index, for the range 0.20 ≤ x ≤ 0.22. The utility of the intermediate phase as a predictor of the material properties in network glass-forming systems is discussed.

  2. Intermediate term follow-up of calcaneal osteotomy and flexor digitorum longus transfer for treatment of posterior tibial tendon dysfunction.

    PubMed

    Fayazi, Amir H; Nguyen, Hoan-Vu; Juliano, Paul J

    2002-12-01

    Twenty-three patients with stage II posterior tibial tendon dysfunction who had failed non-surgical therapy were treated with flexor digitorum longus transfer and calcaneal osteotomy. At latest follow-up averaging 35 +/- 7 months (range, 24 to 51 months), 22 patients (96%) were subjectively "better" or "much better." No patient had difficulty with shoe wear; however, four patients (17%) required routine orthotic use consisting of a molded shoe insert. AOFAS scores were available on 21 patients and improved from a preoperative mean of 50 +/- 14 (range, 27 to 85) to a postoperative mean of 89 +/- 10 (range, 70 to 100). Our experience, at an intermediate date follow-up is that calcaneal osteotomy and flexor digitorum longus transfer is a safe and effective form of treatment for stage II posterior tibial tendon dysfunction.

  3. Interactive effects of O3 exposure on California black oak (Quercus kelloggii Newb.) seedlings with and without N amendment

    Treesearch

    T. Handley; Nancy Grulke

    2008-01-01

    We examined the short-term separate and combined effects of simulated nitrogen (N) deposition (fertilization) and ozone (O3) exposure on California black oak seedlings (Quercus kelloggii Newb.), an ecologically important tree of the San Bernardino Mountains downwind of Los Angeles. Realistic concentrations of O3...

  4. Ozone distribution in remote ecologically vulnerable terrain of the southern Sierra Nevada, CA

    Treesearch

    Jeanne Panek; David Saah; Annie Esperanza; Andrzej Bytnerowicz; Witold Fraczek; Ricardo Cisneros

    2013-01-01

    Ozone concentration spatial patterns remain largely uncharacterized across the extensive wilderness areas of the Sierra Nevada, CA, despite being downwind of major pollution sources. These natural areas, including four national parks and four national forests, contain forest species that are susceptible to ozone injury. Forests stressed by ozone are also more...

  5. Particulate Matter in the Vicinity of an Egg Production Facility: Concentrations, Statistical Distributions, and Upwind and Downwind Comparison

    EPA Science Inventory

    Animal feeding operations (AFOs) satisfy the demand for meat, dairy, and eggs; however, they may negatively impact air quality. In this study, the concentrations of PM2.5 and PM10 were simultaneously monitored at four ambient locations in the vicinity of a commercial egg producti...

  6. Satellite detection of smoke plumes and inadvertant weather modification

    Treesearch

    Wayne A. Pettyjohn; John B. McKeon

    1976-01-01

    Satellite imagery provides a convenient and inexpensive means for monitoring smoke plumes and evaluating inadvertant weather modification. Visual examination of LANDSAT-1 imagery for two sites in east-central Ohio indicates that, at times, a plume may extend nearly 48 km downwind and reach a width of six km. Density slicing techniques provide clues as to the...

  7. Aligning smoke management with ecological and public health goals

    Treesearch

    Jonathan W. Long; Leland W. Tarnay; Malcolm P. North

    2017-01-01

    Past and current forest management affects wildland fire smoke impacts on downwind human populations. However, mismatches between the scale of benefits and risks make it difficult to proactively manage wildland fires to promote both ecological and public health. Building on recent literature and advances in modeling smoke and health effects, we outline a framework to...

  8. Investigation of excitation control for wind-turbine generator stability

    NASA Technical Reports Server (NTRS)

    Gebben, V. D.

    1977-01-01

    High speed horizontal axis wind turbine generators with blades on the downwind side of the support tower require special design considerations to handle disturbances introduced by the flow wake behind the tower. Experiments and analytical analyses were made to determine benefits that might be obtained by using the generator exciter to provide system damping for reducing power fluctuations.

  9. Wind speed effects on the quantity of Xanthomonas citri subsp. citri dispersed downwind from canopies of grapefruit trees infected with citrus canker

    USDA-ARS?s Scientific Manuscript database

    The epidemic of citrus canker (Xanthomonas citri subsp. citri, Xcc) in Florida continues to expand since termination of the eradication program in 2006. Storms are known to be associated with disease spread, but little information exists on the interaction of fundamental physical and biological proc...

  10. Mesoscale features of urban rainfall enhancement

    Treesearch

    F. A. Huff

    1977-01-01

    Analyses of data from the first 4 years of a 5-year research project at St. Louis indicate a substantial enhancement of summer rainfall downwind of the urban-industrial complex. This anomaly appears to be caused primarily by the intensification of naturally occurring storm systems through the addition of heat and raindrop nuclei from the urban area. Most of the...

  11. Measurements of smoke from chipped and unchipped plots

    Treesearch

    Gary L. Achtemeier; Jeff Glitzenstein; Luke P. Naeher

    2006-01-01

    Smoke data were collected from two instrumented plots located on the Francis Marion National Forest in South Carolina during prescribed burns on Feb. 12, 2003. One of the plots had been subjected to mechanical chipping. Particulate matter (PM2.5) data analyzed by gravimetric methods were collected at nine locations on the downwind sides of each plot. In addition,...

  12. Air tankers in Southern California Fires...effectiveness in delivering retardants rated

    Treesearch

    Theodore G. Storey; Leon W. Cooley

    1967-01-01

    Eleven air attack experts were asked to rate 12 models of fixed-wing tankers and light helitankers for effectiveness ill delivering chemical fire retardants under 21 typical situations. They rated fixed-wing tankers as more effective in strong wind crosswinds, and downwind approaches, but helitankers as more effective in narrow canyons and on steep slopes. Certain...

  13. Program VSMOKE--Users Manual

    Treesearch

    Leonidas G. Lavdas

    1996-01-01

    This is a users manual for VSMOKE, a computer porgram for predicting the smoke and dry weather visibility impact of a singel prescvribed fire at several downwind locations. VSMOKE is a FORTRAN 77 program that depends on the input in file VSMOKE.IPT to generate output in file compatible with those used by the U.S. Environmental Protection Agency. VSMOKE is uniquely...

  14. Optimal symmetric flight with an intermediate vehicle model

    NASA Technical Reports Server (NTRS)

    Menon, P. K. A.; Kelley, H. J.; Cliff, E. M.

    1983-01-01

    Optimal flight in the vertical plane with a vehicle model intermediate in complexity between the point-mass and energy models is studied. Flight-path angle takes on the role of a control variable. Range-open problems feature subarcs of vertical flight and singular subarcs. The class of altitude-speed-range-time optimization problems with fuel expenditure unspecified is investigated and some interesting phenomena uncovered. The maximum-lift-to-drag glide appears as part of the family, final-time-open, with appropriate initial and terminal transient exceeding level-flight drag, some members exhibiting oscillations. Oscillatory paths generally fail the Jacobi test for durations exceeding a period and furnish a minimum only for short-duration problems.

  15. Visual outcomes of patients bilaterally implanted with the extended range of vision intraocular lens: A prospective study

    PubMed Central

    Sachdev, Gitansha Shreyas; Ramamurthy, Shreyas; Sharma, Umesh; Dandapani, Ramamurthy

    2018-01-01

    Purpose: The aim of this study was to analyze the objective and subjective visual outcomes of patients bilaterally implanted with the extended range of vision intraocular lens (EROV IOL), the Tecnis Symfony. Methods: This was a prospective interventional case series conducted at a tertiary eye care hospital in South India. The study included patients with bilateral implantation of EROV IOLs. The uncorrected and corrected visual acuity for distance, intermediate, and near vision was recorded at 6 weeks and 6 months’ postoperative visit. A subjective questionnaire was administered to assess spectacle independence, photic phenomenon, and overall satisfaction. All data were recorded using Microsoft Excel worksheet. The analyses were performed using SPSS for windows software. Results: Our study included fifty patients with bilateral implantation of EROV IOLs. The mean age was 59.84 ± 11.68 years. The mean uncorrected binocular distance, intermediate, and near visual acuity (in standard decimal equivalent) was 0.89,0.99 and 0.99 respectively, at 6 months’ postoperative visit. Ninety-six percent of the patients did not require spectacles for distance and 98% of the patients were free from spectacles for intermediate and near vision. 94% of our patients perceived no or minimal photic phenomena such as glare and halos. The mean subjective patient satisfaction score (out of 10) for distance, intermediate, and near was 9, 10, and 9, respectively. Conclusion: The EROV IOLs demonstrated high levels of spectacle independence for distance, intermediate, and near vision. The incidence of photic phenomena observed was minimal with a high level of patient satisfaction. PMID:29480252

  16. Rehabilitation of Understocked Loblolly-Shortleaf Pine Stands - II. Development of Intermediate and Suppressed Trees Following Release in Natural Stands

    Treesearch

    James B. Baker; Michael G. Shelton

    1998-01-01

    Development of 86 intermediate and suppressed loblolly pine (Pinus taeda L.) trees, that had been recently released from overtopping pines and hardwoods, was monitored over a 15 year period. The trees were growing in natural stands on good sites (site index = 90 ft at 50 years) that had been recently cut to stocking levels ranging from 10 to 50 percent. At time of...

  17. Volcán Quizapu, Chilean Andes

    USGS Publications Warehouse

    Hildreth, Wes; Drake, Robert E.

    1992-01-01

    Quizapu is a flank vent of the basalt-to-rhyodacite Holocene stratocone, Cerro Azul, and lies at the focus of a complex Quaternary volcanic field on the Andean volcanic front. The Quizapu vent originated in 1846 when 5 km3 of hornblende-dacite magma erupted effusively with little accompanying tephra. Between ∼ 1907 and 1932, phreatic and strombolian activity reamed out a deep crater, from which 4 km3 of dacite magma identical to that of 1846 fed the great plinian event of 10–11 April 1932. Although a total of >9 km3 of magma was thus released in 86 years, there is no discernible subsidence. As the pre-plinian crater was lined by massive lavas, 1932 enlargement was limited and the total plinian deposit contains only ∼ 0.4 wt % lithics. Areas of 5-cm and 1-cm isopachs for compacted 1932 fallout are about half of those estimated in the 1930's, yielding a revised ejecta volume of ∼9.5 km3. A strong inflection near the 10-cm isopach (downwind ∼110 km) on a plot of log Thickness vs Area1/2 reflects slow settling of fine plinian ash — not of coignimbrite ash, as the volume of pyroclastic flows was trivial (<0.01 km3). About 17 vol.% of the fallout lies beyond the 1-cm isopach, and ∼ 82 wt% of the ejecta are finer than 1 mm. A least 18 hours of steady plinian activity produced an exceptionally uniform fall deposit. Observed column height (27–30 km) and average mass eruption rate (1.5x108 kg/s) compare well with values for height and peak intensity calculated from published eruption models. The progressive “aeolian fractionation” of downwind ash (for which Quizapu is widely cited) is complicated by the large compositional range of 1932 juvenile pumice (52–70% SiO2). The eruption began with andesitic scoria and ended with basaltic scoria, but >95% of the ejecta are dacitic pumice (67–68% SiO2); minor andesitic scoria and frothier rhyodacite pumice (70% SiO2) accompanied the dominant dacite. Phenocrysts (pl>hb∼opx>mt>ilm∼cpx) are similar in both abundance and composition in the 1846 (effusive) and 1932 (plinian) dacites. Despite the contrast in mode of eruption, bulk compositions are also indistinguishable. The only difference so far identified is a lower range of δ D values for 1846 hornblende, consistent with pre-eruptive degassing of the effusive batch.

  18. On the structure of the disordered Bi 2Te 4O 11 phase

    NASA Astrophysics Data System (ADS)

    Masson, O.; Thomas, P.; Durand, O.; Hansen, T.; Champarnaud, J. C.; Mercurio, D.

    2004-06-01

    The structure of the disordered metastable Bi 2Te 4O 11 phase has been investigated using both neutron powder diffraction and reverse Monte Carlo (RMC) modelling. The average structure, of fluorite-type (space group Fm 3¯m ), is characterized by very high Debye-Waller parameters, especially for oxygen. Whereas the cations form a fairly well-defined FCC lattice, the oxygen sublattice is very disordered. It is shown that the local order is similar to that present in the stable monoclinic Bi 2Te 4O 11 phase. Clear differences are observed for the intermediate range order. The present phase is analogous to the "anti-glass" phases reported by Trömel in other tellurium-based mixed oxides. However, whereas Trömel defines anti-glass as having long range order but no short range order, it is shown here that this phase is best described as an intermediate state between the amorphous and crystalline states, i.e. having short and medium range order similar to that of tellurite glasses and a premise of long range order with the cations only.

  19. Comparative techno-economic analysis and process design for indirect liquefaction pathways to distillate-range fuels via biomass-derived oxygenated intermediates upgrading: Liquid Transportation Fuel Production via Biomass-derived Oxygenated Intermediates Upgrading

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tan, Eric C. D.; Snowden-Swan, Lesley J.; Talmadge, Michael

    This paper presents a comparative techno-economic analysis (TEA) of five conversion pathways from biomass to gasoline-, jet-, and diesel-range hydrocarbons via indirect liquefaction with specific focus on pathways utilizing oxygenated intermediates. The four emerging pathways of interest are compared with one conventional pathway (Fischer-Tropsch) for the production of the hydrocarbon blendstocks. The processing steps of the four emerging pathways include: biomass to syngas via indirect gasification, gas cleanup, conversion of syngas to alcohols/oxygenates followed by conversion of alcohols/oxygenates to hydrocarbon blendstocks via dehydration, oligomerization, and hydrogenation. Conversion of biomass-derived syngas to oxygenated intermediates occurs via three different pathways, producing: 1)more » mixed alcohols over a MoS2 catalyst, 2) mixed oxygenates (a mixture of C2+ oxygenated compounds, predominantly ethanol, acetic acid, acetaldehyde, ethyl acetate) using an Rh-based catalyst, and 3) ethanol from syngas fermentation. This is followed by the conversion of oxygenates/alcohols to fuel-range olefins in two approaches: 1) mixed alcohols/ethanol to 1-butanol rich mixture via Guerbet reaction, followed by alcohol dehydration, oligomerization, and hydrogenation, and 2) mixed oxygenates/ethanol to isobutene rich mixture and followed by oligomerization and hydrogenation. The design features a processing capacity of 2,000 tonnes/day (2,205 short tons) of dry biomass. The minimum fuel selling prices (MFSPs) for the four developing pathways range from $3.40 to $5.04 per gasoline-gallon equivalent (GGE), in 2011 US dollars. Sensitivity studies show that MFSPs can be improved with co-product credits and are comparable to the commercial Fischer-Tropsch benchmark ($3.58/GGE). Overall, this comparative TEA study documents potential economics for the developmental biofuel pathways via mixed oxygenates.« less

  20. Interferon versus methotrexate in intermediate uveitis with macular edema: results of a randomized controlled clinical trial.

    PubMed

    Mackensen, Friederike; Jakob, Eva; Springer, Christina; Dobner, Bianca C; Wiehler, Ute; Weimer, Petra; Rohrschneider, Klaus; Fiehn, Christoph; Max, Regina; Storch-Hagenlocher, Brigitte; Becker, Matthias D

    2013-09-01

    To compare interferon (IFN) beta with methotrexate (MTX) in the treatment of intermediate uveitis with macular edema. Monocentric, prospective, randomized, controlled clinical trial. Specialized uveitis center at the University of Heidelberg. PATIENT OR STUDY POPULATION: Patients with either primary intermediate uveitis or uveitis associated with multiple sclerosis. MAIN INCLUSION CRITERIA: Visual acuity of 20/30 or worse (0.2 logarithm of the minimal angle of resolution) and macular edema of more than 250 μm (central 1-mm in optical coherence tomography; Stratus). Randomization into either IFN beta 44 μg subcutaneously 3 times weekly or 20 mg MTX subcutaneously once weekly. At 3 months, the primary outcome parameter of mean change in visual acuity was evaluated and efficacy was determined. Secondary parameters were macular edema by optical coherence tomography, inflammatory activity, and retinal sensitivity by microperimetry (MP-1; Nidek). In case of treatment failure, switching to the other treatment arm was possible. Nineteen patients were included. Ten were randomized to MTX, and 9 were randomized to IFN beta. At 3 months, visual acuity improved a mean 0.31 logarithm of the minimal angle of resolution (range, -0.02 to -0.96, 15.6 letters on the Early Treatment Diabetic Retinopathy Study chart) in the IFN beta group versus a mean 0.09 logarithm of the minimal angle of resolution (range, 0.12 to -0.38, 4.7 letters) in the MTX arm (P = .0435, Mann-Whitney U test). Macular thickness decreased by a mean of 206 μm (range, -41 to -416 μm) in the IFN arm, but increased by 47 μm (range, 108 to -28 μm) in the MTX group (P < .0001). Although the sample size is small, results of the trial support superiority of IFN beta over MTX in the treatment of macular edema in the setting of intermediate uveitis. Copyright © 2013 Elsevier Inc. All rights reserved.

  1. Coherent vector meson photoproduction from deuterium at intermediate energies

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rogers, T.C.; Strikman, M.I.; Sargsian, M.M.

    2006-04-15

    We analyze the cross section for vector meson photoproduction off a deuteron for the intermediate range of photon energies starting at a few giga-electron-volts above the threshold and higher. We reproduce the steps in the derivation of the conventional nonrelativistic Glauber expression based on an effective diagrammatic method while making corrections for Fermi motion and intermediate-energy kinematic effects. We show that, for intermediate-energy vector meson production, the usual Glauber factorization breaks down, and we derive corrections to the usual Glauber method to linear order in longitudinal nucleon momentum. The purpose of our analysis is to establish methods for probing interestingmore » physics in the production mechanism for {phi} mesons and heavier vector mesons. We demonstrate how neglecting the breakdown of Glauber factorization can lead to errors in measurements of basic cross sections extracted from nuclear data.« less

  2. A new method of intermediate orbit determination based on range and range rate measurements at three times. (Russian Title: Новый метод определения промежуточной орбиты по измерениям дальности и скорости ее изменения в три момента времени)

    NASA Astrophysics Data System (ADS)

    Shefer, V. A.

    2013-12-01

    A new method is proposed for computing the preliminary orbit of a small celestial body from three pairs of range and range rate observations. The method is based on using the superosculating intermediate orbit with a fourth-order tangency that we previously constructed. This intermediate orbit allows for most of the perturbations in the motion of the body under study. The methodical error of orbit determination by the proposed method is three orders smaller than the corresponding error of the commonly used approach based on the construction of the unperturbed Keplerian orbit. Using the examples of finding the orbits of artificial Earth satellites, the results obtained by the procedure implementing the traditional approach and the new method are compared. The comparison shows that the new method is a highly efficient means for studying perturbed motion.

  3. Estimating Emissions of Toxic Hydrocarbons from Natural Gas Production Sites in the Barnett Shale Region of Northern Texas.

    PubMed

    Marrero, Josette E; Townsend-Small, Amy; Lyon, David R; Tsai, Tracy R; Meinardi, Simone; Blake, Donald R

    2016-10-04

    Oil and natural gas operations have continued to expand and move closer to densely populated areas, contributing to growing public concerns regarding exposure to hazardous air pollutants. During the Barnett Shale Coordinated Campaign in October, 2013, ground-based whole air samples collected downwind of oil and gas sites revealed enhancements in several potentially toxic volatile organic compounds (VOCs) when compared to background values. Molar emissions ratios relative to methane were determined for hexane, benzene, toluene, ethylbenzene, and xylene (BTEX compounds). Using methane leak rates measured from the Picarro mobile flux plane (MFP) system and a Barnett Shale regional methane emissions inventory, the rates of emission of these toxic gases were calculated. Benzene emissions ranged between 51 ± 4 and 60 ± 4 kg h -1 . Hexane, the most abundantly emitted pollutant, ranged from 642 ± 45 to 1070 ± 340 kg h -1 . While observed hydrocarbon enhancements fall below federal workplace standards, results may indicate a link between emissions from oil and natural gas operations and concerns about exposure to hazardous air pollutants. The larger public health risks associated with the production and distribution of natural gas are of particular importance and warrant further investigation, particularly as the use of natural gas increases in the United States and internationally.

  4. Measurements of methane emissions from natural gas gathering facilities and processing plants: measurement methods

    DOE PAGES

    Roscioli, J. R.; Yacovitch, T. I.; Floerchinger, C.; ...

    2015-05-07

    Increased natural gas production in recent years has spurred intense interest in methane (CH 4) emissions associated with its production, gathering, processing, transmission, and distribution. Gathering and processing facilities (G&P facilities) are unique in that the wide range of gas sources (shale, coal-bed, tight gas, conventional, etc.) results in a wide range of gas compositions, which in turn requires an array of technologies to prepare the gas for pipeline transmission and distribution. We present an overview and detailed description of the measurement method and analysis approach used during a 20-week field campaign studying CH 4 emissions from the natural gasmore » G&P facilities between October 2013 and April 2014. Dual-tracer flux measurements and on-site observations were used to address the magnitude and origins of CH 4 emissions from these facilities. The use of a second tracer as an internal standard revealed plume-specific uncertainties in the measured emission rates of 20–47%, depending upon plume classification. Furthermore, combining downwind methane, ethane (C 2H 6), carbon monoxide (CO), carbon dioxide (CO 2), and tracer gas measurements with on-site tracer gas release allows for quantification of facility emissions and in some cases a more detailed picture of source locations.« less

  5. Intercontinental dispersal of bacteria and archaea by transpacific winds

    USGS Publications Warehouse

    D. Smith,; H. Timonen,; D. Jaffe,; Griffin, Dale W.; M. Birmele,; Perry, K.D.; Ward, P.D.; M. Roberts,

    2013-01-01

    Microorganisms are abundant in the upper atmosphere, particularly downwind of arid regions, where winds can mobilize large amounts of topsoil and dust. However, the challenge of collecting samples from the upper atmosphere and reliance upon culture-based characterization methods have prevented a comprehensive understanding of globally dispersed airborne microbes. In spring 2011 at the Mt. Bachelor Observatory in North America (2.8 km above sea level), we captured enough microbial biomass in two transpacific air plumes to permit a microarray analysis using 16S rRNA genes. Thousands of distinct bacterial taxa spanning a wide range of phyla and surface environments were detected before, during, and after each Asian long-range transport event. Interestingly, the transpacific plumes delivered higher concentrations of taxa already in the background air (particularly Proteobacteria, Actinobacteria, and Firmicutes). While some bacterial families and a few marine archaea appeared for the first and only time during the plumes, the microbial community compositions were similar, despite the unique transport histories of the air masses. It seems plausible, when coupled with atmospheric modeling and chemical analysis, that microbial biogeography can be used to pinpoint the source of intercontinental dust plumes. Given the degree of richness measured in our study, the overall contribution of Asian aerosols to microbial species in North American air warrants additional investigation.

  6. Overview of NASA's Observations for Global Air Quality

    NASA Astrophysics Data System (ADS)

    Kaye, J. A.

    2015-12-01

    Observations of pollutants are central to the study of air quality. Much focus has been placed on local-scale observations that can help specific geographic areas document their air quality issues, plan abatement strategies, and understand potential impacts. In addition, long-range atmospheric transport of pollutants can cause downwind regions to not meet attainment standards. Satellite observations have shed significant light on air quality from local to regional to global scales, especially for pollutants such as ozone, aerosols, carbon monoxide, sulfur dioxide, and nitrogen dioxide. These observations have made use of multiple techniques and in some cases multiple satellite sensors. The satellite observations are complemented by surface observations, as well as atmospheric (in situ) observations typically made as part of focused airborne field campaigns. The synergy between satellite observations and field campaigns has been an important theme for recent and upcoming activities and plans. In this talk, a review of NASA's investments in observations relevant to global air quality will be presented, with examples given for a range of pollutants and measurement approaches covering the last twenty-five years. These investments have helped build national and international collaborations such that the global satellite community is now preparing to deploy a constellation of satellites that together will provide fundamental advances in global observations for air quality.

  7. Hydrocarbon emissions from in-use commercial aircraft during airport operations.

    PubMed

    Herndon, Scott C; Rogers, Todd; Dunlea, Edward J; Jayne, John T; Miake-Lye, Richard; Knighton, Berk

    2006-07-15

    The emissions of selected hydrocarbons from in-use commercial aircraft at a major airport in the United States were characterized using proton-transfer reaction mass spectrometry (PTR-MS) and tunable infrared differential absorption spectroscopy (TILDAS) to probe the composition of diluted exhaust plumes downwind. The emission indices for formaldehyde, acetaldehyde, benzene, and toluene, as well as other hydrocarbon species, were determined through analysis of 45 intercepted plumes identified as being associated with specific aircraft. As would have been predicted for high bypass turbine engines, the hydrocarbon emission index was greater in idle and taxiway acceleration plumes relative to approach and takeoff plumes. The opposite was seen in total NOy emission index, which increased from idle to takeoff. Within the idle plumes sampled in this study, the median emission index for formaldehyde was 1.1 g of HCHO per kg of fuel. For the subset of hydrocarbons measured in this work, the idle emissions levels relative to formaldehyde agree well with those of previous studies. The projected total unburned hydrocarbons (UHC) deduced from the range of in-use idle plumes analyzed in this work is greater than a plausible range of engine types using the defined idle condition (7% of rated engine thrust) in the International Civil Aviation Organization (ICAO) databank reference.

  8. Intercontinental Dispersal of Bacteria and Archaea by Transpacific Winds

    PubMed Central

    Timonen, Hilkka J.; Jaffe, Daniel A.; Griffin, Dale W.; Birmele, Michele N.; Perry, Kevin D.; Ward, Peter D.; Roberts, Michael S.

    2013-01-01

    Microorganisms are abundant in the upper atmosphere, particularly downwind of arid regions, where winds can mobilize large amounts of topsoil and dust. However, the challenge of collecting samples from the upper atmosphere and reliance upon culture-based characterization methods have prevented a comprehensive understanding of globally dispersed airborne microbes. In spring 2011 at the Mt. Bachelor Observatory in North America (2.8 km above sea level), we captured enough microbial biomass in two transpacific air plumes to permit a microarray analysis using 16S rRNA genes. Thousands of distinct bacterial taxa spanning a wide range of phyla and surface environments were detected before, during, and after each Asian long-range transport event. Interestingly, the transpacific plumes delivered higher concentrations of taxa already in the background air (particularly Proteobacteria, Actinobacteria, and Firmicutes). While some bacterial families and a few marine archaea appeared for the first and only time during the plumes, the microbial community compositions were similar, despite the unique transport histories of the air masses. It seems plausible, when coupled with atmospheric modeling and chemical analysis, that microbial biogeography can be used to pinpoint the source of intercontinental dust plumes. Given the degree of richness measured in our study, the overall contribution of Asian aerosols to microbial species in North American air warrants additional investigation. PMID:23220959

  9. Constraining the intermediate-mass range of the Initial Mass Function using Galactic Cepheids

    NASA Astrophysics Data System (ADS)

    Mor, R.; Figueras, F.; Robin, A. C.; Lemasle, B.

    2015-05-01

    Aims. To use the Besançon Galaxy Model (Robin A.C. et al., 2003) and the most complete observational catalogues of Galactic Cepheids to constrain the intermediate-mass range of the Initial Mass Function (IMF) in the Milky Way Galactic thin disc. Methods. We have optimized the flexibility of the new Besançon Galaxy Model (Czekaj et al., 2014) to simulate magnitude and distance complete samples of young intermediate mass stars assuming different IMFs and Star Formation Histories (SFH). Comparing the simulated synthetic catalogues with the observational data, we studied which IMF reproduces better the observational number of Cepheids in the Galactic thin disc. We analysed three different IMFs: (1) Salpeter, (2) Kroupa-Haywood and (3) Haywood-Robin, all of them with a decreasing SFH from Aumer and Binney, 2009. Results. For the first time the Besançon Galaxy Model is used to characterize the Galactic Cepheids. We find that for most of the cases the Salpeter IMF overestimates the number of observed Cepheids and Haywood-Robin IMF underestimates it. The Kroupa-Haywood IMF, with a slope α=3.2, is the one that best reproduces the observed Cepheids. From the comparison of the predicted and observed number of Cepheids up to V=12, we point that the model might underestimate the scale-height of the young population. The effects of the variation of the model ingredients need to be quantified. Conclusions. In agreement with Kroupa and Weidner (2003), our study shows that the Salpeter IMF (α=2.35) overestimates the star counts in the range 4 ≤ M/M_{⊙} ≤ 10 and supports the idea that the slope of the intermediate and massive stars IMF is steeper than the Salpeter IMF.

  10. Development of a modified cortisol extraction procedure for intermediately sized fish not amenable to whole-body or plasma extraction methods.

    PubMed

    Guest, Taylor W; Blaylock, Reginald B; Evans, Andrew N

    2016-02-01

    The corticosteroid hormone cortisol is the central mediator of the teleost stress response. Therefore, the accurate quantification of cortisol in teleost fishes is a vital tool for addressing fundamental questions about an animal's physiological response to environmental stressors. Conventional steroid extraction methods using plasma or whole-body homogenates, however, are inefficient within an intermediate size range of fish that are too small for phlebotomy and too large for whole-body steroid extractions. To assess the potential effects of hatchery-induced stress on survival of fingerling hatchery-reared Spotted Seatrout (Cynoscion nebulosus), we developed a novel extraction procedure for measuring cortisol in intermediately sized fish (50-100 mm in length) that are not amenable to standard cortisol extraction methods. By excising a standardized portion of the caudal peduncle, this tissue extraction procedure allows for a small portion of a larger fish to be sampled for cortisol, while minimizing the potential interference from lipids that may be extracted using whole-body homogenization procedures. Assay precision was comparable to published plasma and whole-body extraction procedures, and cortisol quantification over a wide range of sample dilutions displayed parallelism versus assay standards. Intra-assay %CV was 8.54%, and average recovery of spiked samples was 102%. Also, tissue cortisol levels quantified using this method increase 30 min after handling stress and are significantly correlated with blood values. We conclude that this modified cortisol extraction procedure provides an excellent alternative to plasma and whole-body extraction procedures for intermediately sized fish, and will facilitate the efficient assessment of cortisol in a variety of situations ranging from basic laboratory research to industrial and field-based environmental health applications.

  11. Wind energy converter GROWIAN 2

    NASA Astrophysics Data System (ADS)

    Braun, D.; Kloeppel, V.; Marsch, G.; Meggle, R.; Mehlhose, R.; Schoebe, B.; Wennekers, R.

    1984-04-01

    Multi MW wind energy conversion systems in the rotor class of 135 m diam are described. A variable-speed horizontal-axis downwind machine with a one-bladed teetering rotor and a guyed soft steel tower was investigated and a 1 to 3 scaled demonstrator with a rotor diameter of 48 m was built. The demonstrator will undergo a 2 year verification test program.

  12. California black oak response to nitrogen amendment at a high O3, nitrogen-saturated site

    Treesearch

    Nancy Grulke; W. Dobrowolski; P. Mingus; M.E. Fenn

    2005-01-01

    In a nitrogen (N) saturated forest downwind from Los Angeles, California, the cumulative response to long-term background-N and N-amendment on black oak (Quercus kelloggii) was described in a below-average and average precipitation year. Monthly measurements of leaf and branch growth, gas exchange, and canopy health attributes were conducted. The...

  13. Using fire risk and species loss to set critical loads for nitrogen deposition in southern California shrublands

    Treesearch

    E.B. Allen; L.E. Rao; G. Tonnesen; R.F. Johnson; M.E. Fenn; A. Bytnerowicz

    2014-01-01

    Southern California deserts and coastal sage scrub (CSS) are undergoing vegetation-type conversion to exotic annual grassland, especially in regions downwind of urban areas that receive high nitrogen (N), primarily as dry deposition. To determine critical loads (CLs) of N that cause negative impacts, we measured plant and soil responses along N deposition gradients,...

  14. The Effects of Nitrogen Deposition, Ambient Ozone, and Climate Change on Forests in the Western U.S.

    Treesearch

    M. E. Fenn

    2006-01-01

    Nitrogen (N) deposition in the western United States is most severe near major urban areas or downwind of agricultural regions, particularly in areas where confined animal feeding operations such as dairies or feedlots are located. Nitrogen saturated ecosystems are predominantly found in hotspots located within 60 km of urban or agricultural emissions source areas,...

  15. Fuels planning: science synthesis and integration; environmental consequences fact sheet 11: Smoke Impact Spreadsheet (SIS) model

    Treesearch

    Trent Wickman; Ann Acheson

    2005-01-01

    The Smoke Impact Spreadsheet (SIS) is a simple-to-use planning model for calculating particulate matter (PM) emissions and concentrations downwind of wildland fires. This fact sheet identifies the intended users and uses, required inputs, what the model does and does not do, and tells the user how to obtain the model.

  16. Wood borers attracted to turpentine in windthrown timber in northern California

    Treesearch

    Boyd E. Wickman

    1969-01-01

    The attraction of turpentine to wood borers under natural conditions was observed by setting up three types of traps in a stand of windthrown timber. The traps were made of hardware cloth, plywood, or pane glass Several species of wood borers and their predators were caught more consistently in downwind traps than in upwind traps. Circumstantial evidence suggests the...

  17. PREPARING TO MEASURE THE EFFECTS OF THE NOX SIP CALL - METHODS FOR AMBIENT AIR MONITORING OF NO, NO2, NOY AND INDIVIDUAL NOZ SPECIES

    EPA Science Inventory

    The capping of stationary source emissions of NOx in 22 states and the District of Columbia is federally mandated by the NOx SIP Call legislation with the intended purpose of reducing downwind ozone concentrations. Monitors for NO, NO2, and the reactive oxides of nitrogen into ...

  18. Hydrogen ion input to the Hubbard Brook Experimental Forest, New Hampshire, during the last decade

    Treesearch

    Gene E. Likens; F. Herbert Bormann; John S. Eaton; Robert S. Pierce; Noye M. Johnson

    1976-01-01

    Being downwind of eastern and midwestern industrial centers, the Hubbard Brook Experimental Forest offers a prime location to monitor long-term trends in atmospheric chemistry. Continuous measurements of precipitation chemistry during the last 10 years provide a measure of recent changes in precipitation inputs of hydrogen ion. The weighted average pH of precipitation...

  19. Impacts of atmospheric nitrogen deposition on vegetation and soils in Joshua Tree National Park

    Treesearch

    E.B. Allen; L. Rao; R.J. Steers; A. Bytnerowicz; M.E. Fenn

    2009-01-01

    The western Mojave Desert is downwind of nitrogen emissions from coastal and inland urban sources, especially automobiles. The objectives of this research were to measure reactive nitrogen (N) in the atmosphere and soils along a N-deposition gradient at Joshua Tree National Park and to examine its effects on invasive and native plant species. Atmospheric nitric acid (...

  20. A theoretically based determination of bowen-ratio fetch requirements

    USGS Publications Warehouse

    Stannard, D.I.

    1997-01-01

    Determination of fetch requirements for accurate Bowen-ratio measurements of latent- and sensible-heat fluxes is more involved than for eddy-correlation measurements because Bowen-ratio sensors are located at two heights, rather than just one. A simple solution to the diffusion equation is used to derive an expression for Bowen-ratio fetch requirements, downwind of a step change in surface fluxes. These requirements are then compared to eddy-correlation fetch requirements based on the same diffusion equation solution. When the eddy-correlation and upper Bowen-ratio sensor heights are equal, and the available energy upwind and downwind of the step change is constant, the Bowen-ratio method requires less fetch than does eddy correlation. Differences in fetch requirements between the two methods are greatest over relatively smooth surfaces. Bowen-ratio fetch can be reduced significantly by lowering the lower sensor, as well as the upper sensor. The Bowen-ratio fetch model was tested using data from a field experiment where multiple Bowen-ratio systems were deployed simultaneously at various fetches and heights above a field of bermudagrass. Initial comparisons were poor, but improved greatly when the model was modified (and operated numerically) to account for the large roughness of the upwind cotton field.

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