CTEPP STANDARD OPERATING PROCEDURE FOR PREPARATION OF SURROGATE RECOVERY STANDARD AND INTERNAL STANDARD SOLUTIONS FOR NEUTRAL TARGET ANALYTES (SOP-5.25)

EPA Science Inventory

This standard operating procedure describes the method used for preparing internal standard, surrogate recovery standard and calibration standard solutions for neutral analytes used for gas chromatography/mass spectrometry analysis.

Validation of a Chinese Version of the Geriatric Anxiety Scale Among Community-Dwelling Older Adults in Mainland China.

PubMed

Lin, Xiao-Ling; Lu, Da-Li; Gottschling, Juliana; Segal, Daniel L; Tang, Si-Yuan

2017-03-01

The Geriatric Anxiety Scale (GAS) was developed as an international screening instrument for anxiety in older adults. The aims of the present study were to translate the GAS into Chinese and to subsequently evaluate the preliminary psychometric properties of the Chinese version of the GAS (GAS-C) among community-dwelling Chinese older adults. The translation of the GAS into Chinese was developed through a translation and back translation process. A sample of 206 community-dwelling older adults (51.9 % men, Mean age = 70.70 years, SD = 8.15 years) completed the GAS-C, the Beck Anxiety Inventory (BAI), the Geriatric Depression Scale (GDS) and the Pittsburgh Sleep Quality Index (PSQI). A confirmatory factor analysis was conducted to examine the factor structure of the GAS-C. Internal consistency and convergent validity were used to evaluate the psychometric properties of the translated measure. The factor analyses were in support of a unidimensional factor model of the GAS-C in this Chinese sample, and the item-total correlations for all 25 items ranged from 0.40 to 0.83. The internal consistency for the GAS-C total score was excellent (α = 0.92). The GAS-C total score were significantly and strongly correlated with the BAI (r = 0.86), the GDS (r = 0.78) and the PSQI (r = 0.63), which indicated good convergent validity of the GAS-C. The GAS-C appears to be a reliable and valid screening instrument to assess anxiety symptoms among community-dwelling older adults in mainland China.

[The use of the deuterated internal standard for morphine quantitation for the purpose of doping control by gas chromatography with mass-selective detection].

PubMed

Savel'eva, N B; Bykovskaia, N Iu; Dikunets, M A; Bolotov, S L; Rodchenkov, G M

2010-01-01

The objective of this study was to demonstrate the possibility to use deuterated compounds as internal standards for the quantitative analysis of morphine by gas chromatography with mass-selective detection for the purpose of doping control. The paper is focused on the problems associated with the use of deuterated morphine-D3 as the internal standard. Quantitative characteristics of the calibration dependence thus documented are presented along with uncertainty values obtained in the measurements with the use of deuterated morphine-D6. An approach to the assessment of method bias associated with the application of morphine-D6 as the deuterated internal standard is described.

The Impact of Measurement Noise in GPA Diagnostic Analysis of a Gas Turbine Engine

NASA Astrophysics Data System (ADS)

Ntantis, Efstratios L.; Li, Y. G.

2013-12-01

The performance diagnostic analysis of a gas turbine is accomplished by estimating a set of internal engine health parameters from available sensor measurements. No physical measuring instruments however can ever completely eliminate the presence of measurement uncertainties. Sensor measurements are often distorted by noise and bias leading to inaccurate estimation results. This paper explores the impact of measurement noise on Gas Turbine GPA analysis. The analysis is demonstrated with a test case where gas turbine performance simulation and diagnostics code TURBOMATCH is used to build a performance model of a model engine similar to Rolls-Royce Trent 500 turbofan engine, and carry out the diagnostic analysis with the presence of different levels of measurement noise. Conclusively, to improve the reliability of the diagnostic results, a statistical analysis of the data scattering caused by sensor uncertainties is made. The diagnostic tool used to deal with the statistical analysis of measurement noise impact is a model-based method utilizing a non-linear GPA.

An investigation of the matrix sensitivity of refinery gas analysis using gas chromatography with flame ionisation detection.

PubMed

Ferracci, Valerio; Brown, Andrew S; Harris, Peter M; Brown, Richard J C

2015-02-27

The response of a flame ionisation detector (FID) on a gas chromatograph to methane, ethane, propane, i-butane and n-butane in a series of multi-component refinery gas standards was investigated to assess the matrix sensitivity of the instrument. High-accuracy synthetic gas standards, traceable to the International System of Units, were used to minimise uncertainties. The instrument response exhibited a small dependence on the component amount fraction: this behaviour, consistent with that of another FID, was thoroughly characterised over a wide range of component amount fractions and was shown to introduce a negligible bias in the analysis of refinery gas samples, provided a suitable reference standard is employed. No significant effects of the molar volume, density and viscosity of the gas mixtures on the instrument response were observed, indicating that the FID is suitable for the analysis of refinery gas mixtures over a wide range of component amount fractions provided that appropriate drift-correction procedures are employed. Copyright © 2015 Elsevier B.V. All rights reserved.

Assay of potency of the proposed Fifth International Standard for Gas-Gangrene Antitoxin (Perfringens)

PubMed Central

Prigge, R.; Micke, H.; Krüger, J.

1963-01-01

As part of a collaborative assay of the proposed Fifth International Standard for Gas-Gangrene Antitoxin (Perfringens), five ampoules of the proposed replacement material were assayed in the authors' laboratory against the then current Fourth International Standard. Both in vitro and in vivo methods were used. This paper presents the results and their statistical analysis. The two methods yielded different results which were not likely to have been due to chance, but exact statistical comparison is not possible. It is thought, however, that the differences may be due, at least in part, to differences in the relative proportions of zeta-antitoxin and alpha-antitoxin in the Fourth and Fifth International Standards and the consequent different reactions with the test toxin that was used for titration. PMID:14107746

Bangladesh Country Analysis Brief

EIA Publications

2015-01-01

Natural gas and solid biomass and waste account for the majority of Bangladesh’s total primary energy consumption with the remainder being oil, coal, and hydro. In 2012, Bangladesh’s primary energy consumption was an estimated 55% natural gas, 27% traditional biomass and waste, 15% oil, 3% coal, and less than 1% hydropower and solar, according to the International Energy Agency.

A methodology for thermodynamic simulation of high temperature, internal reforming fuel cell systems

NASA Astrophysics Data System (ADS)

Matelli, José Alexandre; Bazzo, Edson

This work presents a methodology for simulation of fuel cells to be used in power production in small on-site power/cogeneration plants that use natural gas as fuel. The methodology contemplates thermodynamics and electrochemical aspects related to molten carbonate and solid oxide fuel cells (MCFC and SOFC, respectively). Internal steam reforming of the natural gas hydrocarbons is considered for hydrogen production. From inputs as cell potential, cell power, number of cell in the stack, ancillary systems power consumption, reformed natural gas composition and hydrogen utilization factor, the simulation gives the natural gas consumption, anode and cathode stream gases temperature and composition, and thermodynamic, electrochemical and practical efficiencies. Both energetic and exergetic methods are considered for performance analysis. The results obtained from natural gas reforming thermodynamics simulation show that the hydrogen production is maximum around 700 °C, for a steam/carbon ratio equal to 3. As shown in the literature, the found results indicate that the SOFC is more efficient than MCFC.

CTEPP STANDARD OPERATING PROCEDURE FOR PREPARATION OF SURROGATE RECOVERY STANDARD AND INTERNAL STANDARD SOLUTIONS FOR POLAR TARGET ANALYTES (SOP-5.26)

EPA Science Inventory

This SOP describes the method used for preparing surrogate recovery standard and internal standard solutions for the analysis of polar target analytes. It also describes the method for preparing calibration standard solutions for polar analytes used for gas chromatography/mass sp...

Impact of cutting meat intake on hidden greenhouse gas emissions in an import-reliant city

NASA Astrophysics Data System (ADS)

Yau, Y. Y.; Thibodeau, B.; Not, C.

2018-06-01

Greenhouse gas emissions embodied in trade is a growing concern for the international community. Multiple studies have highlighted drawbacks in the territorial and production-based accounting of greenhouse gas emissions because it neglects emissions from the consumption of goods in trade. This creates weak carbon leakage and complicates international agreements on emissions regulations. Therefore, we estimated consumption-based emissions using input-output analysis and life cycle assessment to calculate the greenhouse gas emissions hidden in meat and dairy products in Hong Kong, a city predominately reliant on imports. We found that emissions solely from meat and dairy consumption were higher than the city’s total greenhouse gas emissions using conventional production-based calculation. This implies that government reports underestimate more than half of the emissions, as 62% of emissions are embodied in international trade. The discrepancy emphasizes the need of transitioning climate targets and policy to consumption-based accounting. Furthermore, we have shown that dietary change from a meat-heavy diet to a diet in accordance with governmental nutrition guidelines could achieve a 67% reduction in livestock-related emissions, allowing Hong Kong to achieve the Paris Agreement targets for 2030. Consequently, we concluded that consumption-based accounting for greenhouse gas emissions is crucial to target the areas where emissions reduction is realistically achievable, especially for import-reliant cities like Hong Kong.

Internal Acoustics of a Pintle Valve with Supercritical Helium Flow

NASA Technical Reports Server (NTRS)

Fishbach, Sean R.; Davis, R. Benjamin

2010-01-01

Large amplitude flow unsteadiness is a common phenomenon within the high flow rate ducts and valves associated with propulsion systems. Boundary layer noise, shear layers and vortex shedding are a few of the many sources of flow oscillations. The presence of lightly damped acoustic modes can organize and amplify these sources of flow perturbation, causing undesirable loading of internal parts. The present study investigates the self-induced acoustic environment within a pintle valve subject to high Reynolds Number flow of helium gas. Experiments were conducted to measure the internal pressure oscillations of the Ares I Launch Abort System (LAS) Attitude Control Motor (ACM) valve. The AGM consists of a solid propellant gas generator with eight pintle valves attached to the aft end. The pintle valve is designed to deliver variable upstream conditions to an attache( converging diverging nozzle. In order to investigate the full range of operating conditions 28 separate tests were conducted with varying pintle position and upstream pressure. Helium gas was utilized in order to closely mimic the speed of sound of the gas generator exhaust, minimizing required scaling during data analysis. The recordec pressure measurements were interrogated to multiple ends. The development of root mean square (RMS) value! versus Reynolds Number and Pintle position are important to creating bounding unsteady load curves for valve internal parts. Spectral analysis was also performed, helping to identify power spectral densities (PSD) of acoustic natural frequencies and boundary layer noise. An interesting and unexpected result was the identification of an acoustic mode within the valve which does not respond until the valve was over 60% open. Further, the response amplitude around this mode can be as large or larger than those associated with lower frequency modes.

Development of a Feedstock-to-Product Chain Model for Densified Biomass Pellets

NASA Astrophysics Data System (ADS)

McPherrin, Daniel

The Q’Pellet is a spherical, torrefied biomass pellet currently under development. It aims to improve on the shortcomings of commercially available cylindrical white and torrefied pellets. A spreadsheet-based model was developed to allow for techno-economic analysis and simplified life cycle analysis of Q’Pellets, torrefied pellets and white pellets. A case study was developed to compare the production of white, torrefied and Q’Pellet production based on their internal rates of return and life cycle greenhouse gas emissions. The case study was based on a commercial scale plant built in Williams Lake BC with product delivery in Rotterdam, Netherlands. Q’Pellets had the highest modelled internal rate of return, at 12.7%, with white pellets at 11.1% and torrefied pellets at 8.0%. The simplified life cycle analysis showed that Q’Pellets had the lowest life cycle greenhouse gas emissions of the three products, 6.96 kgCO2eq/GJ, compared to 21.50 kgCO2eq/GJ for white pellets and 10.08 kgCO2eq/GJ for torrefied pellets. At these levels of life cycle greenhouse gas emissions, white pellets are above the maximum life cycle emissions to be considered sustainable under EU regulations. Sensitivity analysis was performed on the model by modifying input variables, and showed that white pellets are more sensitive to uncontrollable market variables, especially pellet sale prices, raw biomass prices and transportation costs. Monte Carlo analysis was also performed, which showed that white pellet production is less predictable and more likely to lead to a negative internal rate of return compared to Q’Pellet production.

Online gas analysis and diagnosis for RPC detectors in the ATLAS experiment

NASA Astrophysics Data System (ADS)

de Asmundis, Riccardo

2007-03-01

Resistive Plate Counters (RPC) detectors need a very strict control of gas parameters: motivations for this statement come from both the request of stability in the detector working point, and chemical consideration concerning potentially aggressive materials generated during the ionization processes into the sensitive gap; the latter point can be relevant because of a possible damage to the internal surface of the detector that has to be avoided in order to ensure an high detection efficiency of the RPC during their ten years or more of operation in ATLAS. In order to understand these aspects, detailed studies on gas behavior have been carried on at the GIF-X5 at CERN (2002-2005), based on Gas Chromatographic and spectroscopy techniques. Main results of these analysis are presented here, together with the design of the online analyzer to be installed on ATLAS conceived to keep control of gas quality and to trigger maintenance interventions on the gas system, in particular on the purification subsystem.

Preliminary studies of using preheated carrier gas for on-line membrane extraction of semivolatile organic compounds.

PubMed

Liu, Xinyu; Pawliszyn, Janusz

2007-04-01

In this paper, we present results for the on-line determination of semivolatile organic compounds (SVOCs) in air using membrane extraction with a sorbent interface-ion mobility spectrometry (MESI-IMS) system with a preheated carrier (stripping) gas. The mechanism of the mass transfer of SVOCs across a membrane was initially studied. In comparison with the extraction of volatile analytes, the mass transfer resistance that originated from the slow desorption from the internal membrane surface during the SVOC extraction processes should be taken into account. A preheated carrier gas system was therefore built to facilitate desorption of analytes from the internal membrane surface. With the benefit of a temperature gradient existing between the internal and external membrane surfaces, an increase in the desorption rate of a specific analyte at the internal surface and the diffusion coefficient within the membrane could be achieved while avoiding a decrease of the distribution constant on the external membrane interface. This technique improved both the extraction rate and response times of the MESI-IMS system for the analysis of SVOCs. Finally, the MESI-IMS system was shown to be capable of on-site measurement by monitoring selected polynuclear aromatic hydrocarbons emitted from cigarette smoke.

77 FR 47427 - Accreditation and Approval of Chem Gas International LLC, as a Commercial Gauger and Laboratory

Federal Register 2010, 2011, 2012, 2013, 2014

2012-08-08

... Chem Gas International LLC, as a Commercial Gauger and Laboratory AGENCY: U.S. Customs and Border Protection, Department of Homeland Security. ACTION: Notice of accreditation and approval of Chem Gas... Gas International LLC, as commercial gauger and laboratory became effective on October 19, 2011. The...

Equatorial Guinea Country Analysis Brief

EIA Publications

2015-01-01

Equatorial Guinea's economy is heavily reliant on its oil and natural gas industry, which accounted for almost 95% of its gross domestic product (GDP) and 99% of its export earnings in 2011, according to the latest estimates from the International Monetary Fund. Equatorial Guinea’s declining oil and natural gas production, coupled with a decline in global oil prices, is adversely affecting its economy, and has resulted in lower, and at times negative, GDP growth. Emphasis on the oil and natural gas industries has also led to the lack of development in non-hydrocarbon sectors.

International Permafrost Field Courses in Siberia: the Synthesis of Research and Education

NASA Astrophysics Data System (ADS)

Ablyazina, D.; Boitsov, A.; Grebenets, V.; Kaverin, D.; Klene, A.; Kurchatova, A.; Pfeiffer, E. M.; Zschocke, A.; Shiklomanov, N.; Streletskiy, D.

2009-04-01

During summers of 2007 and 2008 a series of International University Courses on Permafrost (IUCP) were conducted in West Siberia, Russia. Courses were organized as part of the International Permafrost Association (IPA) International Polar Year activities. The North of West Siberia region was selected to represent diverse permafrost, climatic and landscape conditions. The courses were jointly organized by the Moscow State University (MSU) and the Tumen' Oil and Gas University (TOGU) with the help from German and U.S. institutions. The program attracted undergraduate and graduate students with diverse interests and backgrounds from Germany, Russia and the U.S. and involved instructors specializing in different aspects of permafrost research. Courses were designed to address three major topics of permafrost-related research: a) permafrost environments characteristic of the discontinuous and continuous zones; b) field instrumentation and techniques; c) permafrost engineering and problems of development in permafrost regions. Methodologically, courses consisted of systematic permafrost investigations at long-term monitoring sites and survey-type expeditions. Systematic, process-based investigations were conducted at a network of sites which constitute the TEPO established by TOGU in collaboration with the gas company NadymGasProm. The observation complex includes an array of 30-m deep boreholes equipped with automatic data collection systems and representing characteristic permafrost landscapes of West Siberia. Boreholes are complemented by sites for snow cover, vegetation, soil, ground ice, and geomorphologic investigations. As part of student research activities, four new Circumpolar Active Layer Monitoring (CALM) sites were established in proximity to boreholes for monitoring spatial distribution and long-term dynamic of the active layer. New sites represent diverse landscapes characteristic of the West Siberian previously underrepresented in the CALM network. Specific emphasis was made on the study of permafrost soils. Throughout the course students were exposed to a wide range of field techniques, including surveying, coring, geothermal monitoring, thaw-depth measurements, landscape characterization, geomorphologic investigations, soil description and classification according to International, Russian, German, and U.S. classification schemes, and hydrologic and botanical field investigations. Significant portion of the course curriculum was devoted to problems of industrial development in permafrost regions. Pipelines, material sites, operating gas wells, processing plants, pump stations, and permafrost engineering testing facilities associated with three major gas fields (Yamburg, Yubileinoe, and Zapolyarnoe) were visited as part of the field excursions. Several meetings with Russian gas industry executives and workers were arranged to openly discuss economic and political issues associated with GasProm activities in West Siberia. The field work was complemented by daily lectures prepared by instructors and students, covering a wide range of topics. Students also participated in active permafrost research through daily data collection and analysis activities. Analysis of the diverse data sets obtained during the course was conducted at Moscow State University, presented in a series of detailed reports. The data collected by students were contributed to the international IPY permafrost monitoring programmes. Several students have presented results of their research at the Ninth International Conference on Permafrost and other national and international scientific meetings. This presentation describes research and educational activities of the IUCP, provides results of student research, and outlines the plan for the future.

A method for direct, semi-quantitative analysis of gas phase samples using gas chromatography-inductively coupled plasma-mass spectrometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carter, Kimberly E; Gerdes, Kirk

2013-07-01

A new and complete GC–ICP-MS method is described for direct analysis of trace metals in a gas phase process stream. The proposed method is derived from standard analytical procedures developed for ICP-MS, which are regularly exercised in standard ICP-MS laboratories. In order to implement the method, a series of empirical factors were generated to calibrate detector response with respect to a known concentration of an internal standard analyte. Calibrated responses are ultimately used to determine the concentration of metal analytes in a gas stream using a semi-quantitative algorithm. The method was verified using a traditional gas injection from a GCmore » sampling valve and a standard gas mixture containing either a 1 ppm Xe + Kr mix with helium balance or 100 ppm Xe with helium balance. Data collected for Xe and Kr gas analytes revealed that agreement of 6–20% with the actual concentration can be expected for various experimental conditions. To demonstrate the method using a relevant “unknown” gas mixture, experiments were performed for continuous 4 and 7 hour periods using a Hg-containing sample gas that was co-introduced into the GC sample loop with the xenon gas standard. System performance and detector response to the dilute concentration of the internal standard were pre-determined, which allowed semi-quantitative evaluation of the analyte. The calculated analyte concentrations varied during the course of the 4 hour experiment, particularly during the first hour of the analysis where the actual Hg concentration was under predicted by up to 72%. Calculated concentration improved to within 30–60% for data collected after the first hour of the experiment. Similar results were seen during the 7 hour test with the deviation from the actual concentration being 11–81% during the first hour and then decreasing for the remaining period. The method detection limit (MDL) was determined for the mercury by injecting the sample gas into the system following a period of equilibration. The MDL for Hg was calculated as 6.8 μg · m -3. This work describes the first complete GC–ICP-MS method to directly analyze gas phase samples, and detailed sample calculations and comparisons to conventional ICP-MS methods are provided.« less

[Rapid determination of volatile organic compounds in workplace air by protable gas chromatography-mass spectrometer].

PubMed

Zhu, H B; Su, C J; Tang, H F; Ruan, Z; Liu, D H; Wang, H; Qian, Y L

2017-10-20

Objective: To establish a method for rapid determination of 47 volatile organic compounds in the air of workplace using portable gas chromatography - mass spectrometer(GC - MS). Methods: The mixed standard gas with different concentration levels was made by using the static gas distribution method with the high purity nitrogen as dilution gas. The samples were injected into the GC - MS by a hand - held probe. Retention time and characteristic ion were used for qualitative analysis,and the internal standard method was usd for quantitation. Results: The 47 poisonous substances were separated and determined well. The linear range of this method was 0.2 - 16.0 mg/m(3),and the relative standard deviation of 45 volatile ovganic compounds was 3.8% - 15.8%. The average recovery was 79.3% - 119.0%. Conclusion: The method is simple,accurate,sensitive,has good separation effect,short analysis period, can be used for qualitative and quantitative analysis of volatile organic compounds in the workplace, and also supports the rapid identification and detection of occupational hazards.

Argon gas analysis to predict water leakage into the W88

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gillen, K.T.

1990-08-01

Analyses of the internal argon gas concentrations monitored on surveillance units of the W84 indicates that field aging of this weapon for times up to {approximately}4 years does not lead to important increases in the rate at which water leaks into the interior of the weapon. This implies that the EPDM environmental seals used on the W84 do not age significantly over this time period. By comparing the percentages of oxygen and argon in the internal atmosphere, an estimate of the oxygen consumption rate is made for a typical W84 unit. The argon gas analysis approach is then applied tomore » the W88, which is sealed with a new EPDM material. Predictive expressions are derived which relate the anticipated argon gas concentrations of future, field-returned units to their water leakage rates. The predictions are summarized in convenient plots, which can be immediately and easily applied to surveillance data as reported. Since the argon approach is sensitive enough to be useful over the entire lifetime of the W88, it can be used to point out leaking units and to determine whether long-term aging has any significant effect on the new EPDM material. 11 refs., 10 figs., 3 tabs.« less

On the Stratospheric Aerosol and Gas Experiment III on the International Space Station

NASA Technical Reports Server (NTRS)

Hernandez, Gloria; Zawodny, Joseph M.; Cisewski, Michael S.; Thornton, Brooke M.; Panetta, Andrew D,; Roell, Marilee M.; Vernier, Jean-Paul

2014-01-01

The Stratospheric Aerosol and Gas Experiment III on International Space Station (SAGE3/ISS) is anticipated to be delivered to Cape Canaveral in the spring of 2015. This is the fourth generation, fifth instrument, of visible/near-IR solar occultation instruments operated by the National Aeronautics and Space Agency (NASA) to investigate the Earth's upper atmosphere. The instrument is a moderate resolution spectrometer covering wavelengths from 290 nm to 1550 nm. The nominal science products include vertical profiles of trace gases, such as ozone, nitrogen dioxide and water vapor, along with multi-wavelength aerosol extinction. The SAGE3/ISS validation program will be based upon internal consistency of the measurements, detailed analysis of the retrieval algorithm, and comparisons with independent correlative measurements. The Instrument Payload (IP), mission architecture, and major challenges are also discussed.

Aero-Thermo-Structural Design Optimization of Internally Cooled Turbine Blades

NASA Technical Reports Server (NTRS)

Dulikravich, G. S.; Martin, T. J.; Dennis, B. H.; Lee, E.; Han, Z.-X.

1999-01-01

A set of robust and computationally affordable inverse shape design and automatic constrained optimization tools have been developed for the improved performance of internally cooled gas turbine blades. The design methods are applicable to the aerodynamics, heat transfer, and thermoelasticity aspects of the turbine blade. Maximum use of the existing proven disciplinary analysis codes is possible with this design approach. Preliminary computational results demonstrate possibilities to design blades with minimized total pressure loss and maximized aerodynamic loading. At the same time, these blades are capable of sustaining significantly higher inlet hot gas temperatures while requiring remarkably lower coolant mass flow rates. These results suggest that it is possible to design internally cooled turbine blades that will cost less to manufacture, will have longer life span, and will perform as good, if not better than, film cooled turbine blades.

Sonar surveys used in gas-storage cavern analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Crossley, N.G.

1998-05-04

Natural-gas storage cavern internal configuration, inspection information, and cavern integrity data can be obtained during high-pressure operations with specialized gas-sonar survey logging techniques. TransGas Ltd., Regina, Sask., has successfully performed these operations on several of its deepest and highest pressurized caverns. The data can determine gas-in-place inventory and assess changes in spatial volumes. These changes can result from cavern creep, shrinkage, or closure or from various downhole abnormalities such as fluid infill or collapse of the sidewall or roof. The paper discusses conventional surveys with sonar, running surveys in pressurized caverns, accuracy of the sonar survey, initial development of Cavernmore » 5, a roof fall, Cavern 4 development, and a damaged string.« less

Parallel synthesis: a new approach for developing analytical internal standards. Application to the analysis of patulin by gas chromatography-mass spectrometry.

PubMed

Llovera, Montserrat; Balcells, Mercè; Torres, Mercè; Canela, Ramon

2005-08-24

The polymer-assisted reaction of 4-(hydroxymethyl)furan-2(5H)-one (4HM2F) with 21 carboxylic acids using polystyrene-carbodiimide (PS-carbodiimide) yielded an ester library. Four of the esters, (5-oxo-2,5-dihydrofuran-3-yl)methyl acetate (IS-1), (5-oxo-2,5-dihydrofuran-3-yl)methyl butyrate (IS-2), (5-oxo-2,5-dihydrofuran-3-yl)methyl 2-methylpropanoate (IS-3), and (5-oxo-2,5-dihydrofuran-3-yl)methyl chloroacetate (IS-4), were tested as internal standards for the quantification of patulin in apple juice by gas chromatography-mass spectrometry in the selected ion monitoring mode (GC-MS-SIM). The developed method combines an AOAC official extractive step and a GC-MS-SIM analysis. Using a chromatographic column containing trifluoropropylmethylpolysiloxane as the stationary phase and IS-1 as the internal standard, it was possible to perform an accurate and precise quantification of underivatizated patulin in apple juice at concentrations down to 6 microg/L. A detection limit of 1 microg/L was established.

Confluence of climate change policies and international trade

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vickery, R.E. Jr.

1997-12-31

The paper summarizes market information on energy conservation and renewable energy industries in the U.S., and highlights activities of the International Trade Administration. International treaties agreements on environmental issues are examined with respect to their influence on U.S. trade promotion and job creation. A sectoral analysis of the economic impact of greenhouse gas emissions reductions on industries is very briefly summarized. Finally, the need for a climate change treaty in spite of possible adverse impacts is discussed. 1 tab.

Non-diffusive ignition of a gaseous reactive mixture following time-resolved, spatially distributed energy deposition

NASA Astrophysics Data System (ADS)

Kassoy, D. R.

2014-01-01

Systematic asymptotic methods are applied to the compressible conservation and state equations for a reactive gas, including transport terms, to develop a rational thermomechanical formulation for the ignition of a chemical reaction following time-resolved, spatially distributed thermal energy addition from an external source into a finite volume of gas. A multi-parameter asymptotic analysis is developed for a wide range of energy deposition levels relative to the initial internal energy in the volume when the heating timescale is short compared to the characteristic acoustic timescale of the volume. Below a quantitatively defined threshold for energy addition, a nearly constant volume heating process occurs, with a small but finite internal gas expansion Mach number. Very little added thermal energy is converted to kinetic energy. The gas expelled from the boundary of the hot, high-pressure spot is the source of mechanical disturbances (acoustic and shock waves) that propagate away into the neighbouring unheated gas. When the energy addition reaches the threshold value, the heating process is fully compressible with a substantial internal gas expansion Mach number, the source of blast waves propagating into the unheated environmental gas. This case corresponds to an extremely large non-dimensional hot-spot temperature and pressure. If the former is sufficiently large, a high activation energy chemical reaction is initiated on the short heating timescale. This phenomenon is in contrast to that for more modest levels of energy addition, where a thermal explosion occurs only after the familiar extended ignition delay period for a classical high activation reaction. Transport effects, modulated by an asymptotically small Knudsen number, are shown to be negligible unless a local gradient in temperature, concentration or velocity is exceptionally large.

Using Passive Polyethylene Samplers to Evaluate Chemical Activities Controlling Fluxes and Bioaccumulation of Organic Contaminants in Bed Sediments

DTIC Science & Technology

2010-11-01

carbon flipid fraction lipid foc fraction organic carbon fprotein fraction protein GCMS Gas Chromatography -Mass Spectrometry HP Hunter’s...Internal standards were added to the extracts before gas chromatography -mass spectrometry (GCMS) analysis. GCMS was done using a JEOL GCmate...min. The MS was operated in selected ion monitoring (SIM) and EI+ modes. Calibration standards 6 containing at least 25 aromatic compounds

Thermal engine driven heat pump for recovery of volatile organic compounds

DOEpatents

Drake, Richard L.

1991-01-01

The present invention relates to a method and apparatus for separating volatile organic compounds from a stream of process gas. An internal combustion engine drives a plurality of refrigeration systems, an electrical generator and an air compressor. The exhaust of the internal combustion engine drives an inert gas subsystem and a heater for the gas. A water jacket captures waste heat from the internal combustion engine and drives a second heater for the gas and possibly an additional refrigeration system for the supply of chilled water. The refrigeration systems mechanically driven by the internal combustion engine effect the precipitation of volatile organic compounds from the stream of gas.

Study on Gas-liquid Falling Film Flow in Internal Heat Integrated Distillation Column

NASA Astrophysics Data System (ADS)

Liu, Chong

2017-10-01

Gas-liquid internally heat integrated distillation column falling film flow with nonlinear characteristics, study on gas liquid falling film flow regulation control law, can reduce emissions of the distillation column, and it can improve the quality of products. According to the distribution of gas-liquid mass balance internally heat integrated distillation column independent region, distribution model of heat transfer coefficient of building internal heat integrated distillation tower is obtained liquid distillation falling film flow in the saturated vapour pressure of liquid water balance, using heat transfer equation and energy equation to balance the relationship between the circulating iterative gas-liquid falling film flow area, flow parameter information, at a given temperature, pressure conditions, gas-liquid flow falling film theory makes the optimal parameters to achieve the best fitting value with the measured values. The results show that the geometric gas-liquid internally heat integrated distillation column falling film flow heat exchange area and import column thermostat, the average temperature has significant. The positive correlation between the heat exchanger tube entrance due to temperature difference between inside and outside, the heat flux is larger, with the increase of internal heat integrated distillation column temperature, the slope decreases its temperature rise, which accurately describes the internal gas-liquid heat integrated distillation tower falling film flow regularity, take appropriate measures to promote the enhancement of heat transfer. It can enhance the overall efficiency of the heat exchanger.

Economic aspects of advanced coal-fired gas turbine locomotives

NASA Technical Reports Server (NTRS)

Liddle, S. G.; Bonzo, B. B.; Houser, B. C.

1983-01-01

Increases in the price of such conventional fuels as Diesel No. 2, as well as advancements in turbine technology, have prompted the present economic assessment of coal-fired gas turbine locomotive engines. A regenerative open cycle internal combustion gas turbine engine may be used, given the development of ceramic hot section components. Otherwise, an external combustion gas turbine engine appears attractive, since although its thermal efficiency is lower than that of a Diesel engine, its fuel is far less expensive. Attention is given to such a powerplant which will use a fluidized bed coal combustor. A life cycle cost analysis yields figures that are approximately half those typical of present locomotive engines.

Polarized internal target apparatus

DOEpatents

Holt, Roy J.

1986-01-01

A polarized internal target apparatus with a polarized gas target of improved polarization and density achieved by mixing target gas atoms with a small amount of alkali metal gas atoms, and passing a high intensity polarized light source into the mixture to cause the alkali metal gas atoms to become polarized which interact in spin exchange collisions with target gas atoms yielding polarized target gas atoms.

New method for stock-tank oil compositional analysis.

PubMed

McAndrews, Kristine; Nighswander, John; Kotzakoulakis, Konstantin; Ross, Paul; Schroeder, Helmut

2009-01-01

A new method for accurately determining stock-tank oil composition to normal pentatriacontane using gas chromatography is developed and validated. The new method addresses the potential errors associated with the traditional equipment and technique employed for extended hydrocarbon gas chromatography outside a controlled laboratory environment, such as on an offshore oil platform. In particular, the experimental measurement of stock-tank oil molecular weight with the freezing point depression technique and the use of an internal standard to find the unrecovered sample fraction are replaced with correlations for estimating these properties. The use of correlations reduces the number of necessary experimental steps in completing the required sample preparation and analysis, resulting in reduced uncertainty in the analysis.

Technical, economic, and environmental impact study of converting Uzbekistan transportation fleets to natural gas operation. Export trade information

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1997-04-30

This study, conducted by Radian International, was funded by the U.S. Trade and Development Agency. The report assesses the feasibility (technical, economic and environmental) of converting the Uzbek transportation fleets to natural gas operation. The study focuses on the conversion of high fuel use vehicles and locomotives to liquefied natural gas (LNG) and the conversion of moderate fuel use veicles to compressed natural gas (CNG). The report is divided into the following sections: Executive Summary; (1.0) Introduction; (2.0) Country Background; (3.0) Characterization of Uzbek Transportation Fuels; (4.0) Uzbek Vehicle and Locomotive Fleet Characterization; (5.0) Uzbek Natural Gas Vehicle Conversion Shops;more » (6.0) Uzbek Natural Gas Infrastructure; (7.0) Liquefied Natural Gas (LNG) for Vehicular Fuel in Uzbekistan; (8.0) Economic Feasibility Study; (9.0) Environmental Impact Analysis; References; Appendices A - S.« less

Approach for Self-Calibrating CO2 Measurements with Linear Membrane-Based Gas Sensors

PubMed Central

Lazik, Detlef; Sood, Pramit

2016-01-01

Linear membrane-based gas sensors that can be advantageously applied for the measurement of a single gas component in large heterogeneous systems, e.g., for representative determination of CO2 in the subsurface, can be designed depending on the properties of the observation object. A resulting disadvantage is that the permeation-based sensor response depends on operating conditions, the individual site-adapted sensor geometry, the membrane material, and the target gas component. Therefore, calibration is needed, especially of the slope, which could change over several orders of magnitude. A calibration-free approach based on an internal gas standard is developed to overcome the multi-criterial slope dependency. This results in a normalization of sensor response and enables the sensor to assess the significance of measurement. The approach was proofed on the example of CO2 analysis in dry air with tubular PDMS membranes for various CO2 concentrations of an internal standard. Negligible temperature dependency was found within an 18 K range. The transformation behavior of the measurement signal and the influence of concentration variations of the internal standard on the measurement signal were shown. Offsets that were adjusted based on the stated theory for the given measurement conditions and material data from the literature were in agreement with the experimentally determined offsets. A measurement comparison with an NDIR reference sensor shows an unexpectedly low bias (<1%) of the non-calibrated sensor response, and comparable statistical uncertainty. PMID:27869656

Recent Operational Experience with the Internal Thermal Control System Dual-Membrane Gas Trap

NASA Technical Reports Server (NTRS)

Leimkuehler, Thomas O.; Lukens, Clark; Reeves, Daniel R.; Holt, James M.

2004-01-01

A dual-membrane gas trap is currently used to remove gas bubbles from the Internal Thermal Control System (ITCS) coolant on board the International Space Station. The gas trap consists of concentric tube membrane pairs, comprised of outer hydrophilic tubes and inner hydrophobic fibers. Liquid coolant passes through the outer hydrophilic membrane, which traps the gas bubbles. The inner hydrophobic fiber allows the trapped gas bubbles to pass through and vent to the ambient atmosphere in the cabin. The gas removal performance and operational lifetime of the gas trap have been affected by contamination in the ITCS coolant. However, the gas trap has performed flawlessly with regard to its purpose of preventing gas bubbles from causing depriming, overspeed, and shutdown of the ITCS pump. This paper discusses on-orbit events over the course of the last year related to the performance and functioning of the gas trap.

Williams works with the GASMAP section of the HRF rack in the U.S. Laboratory during Expedition 13

NASA Image and Video Library

2006-06-17

ISS013-E-38343 (17 June 2006) --- Astronaut Jeffrey N. Williams, Expedition 13 NASA space station science officer and flight engineer, works with the Gas Analysis System for Metabolic Analysis of Physiology (GASMAP) section of the Human Research Facility (HRF) in the Destiny laboratory of the International Space Station.

Sampling and analysis of natural gas trace constituents

DOE Office of Scientific and Technical Information (OSTI.GOV)

Attari, A.; Chao, S.

1993-09-01

Major and minor components of natural gas are routinely analyzed by gas chromatography (GC), using a thermal conductivity (TC). The best results obtained by these methods can report no better than 0.01 mole percent of each measured component. Even the extended method of analysis by flame ionization detector (FID) can only improve on the detection limit of hydrocarbons. The gas industry needs better information on all trace constituents of natural gas, whether native or inadvertently added during gas processing that may adversely influence the operation of equipment or the safety of the consumer. The presence of arsenic and mercury inmore » some gas deposits have now been documented in international literature as causing not only human toxicity but also damaging to the field equipment. Yet, no standard methods of sampling and analysis exist to provide this much needed information. In this paper the authors report the results of a three-year program to develop an extensive array of sampling and analysis methods for speciation and measurement of trace constituents of natural gas. A cryogenic sampler operating at near 200 K ({minus}99 F) and at pipeline pressures up to 12.4 {times} 10{sup 6}Pa (1800 psig) has been developed to preconcentrate and recover all trace constituents with boiling points above butanes. Specific analytical methods have been developed for speciating and measurement of many trace components (corresponding to US EPA air toxics) by GC-AED and GC-MS, and for determining various target compounds by other techniques. Moisture, oxygen and sulfur contents are measured on site using dedicated field instruments. Arsenic, mercury and radon are sampled by specific solid sorbents for subsequent laboratory analysis.« less

Validation of an analytical method for nitrous oxide (N2O) laughing gas by headspace gas chromatography coupled to mass spectrometry (HS-GC-MS): forensic application to a lethal intoxication.

PubMed

Giuliani, N; Beyer, J; Augsburger, M; Varlet, V

2015-03-01

Drug abuse is a widespread problem affecting both teenagers and adults. Nitrous oxide is becoming increasingly popular as an inhalation drug, causing harmful neurological and hematological effects. Some gas chromatography-mass spectrometry (GC-MS) methods for nitrous oxide measurement have been previously described. The main drawbacks of these methods include a lack of sensitivity for forensic applications; including an inability to quantitatively determine the concentration of gas present. The following study provides a validated method using HS-GC-MS which incorporates hydrogen sulfide as a suitable internal standard allowing the quantification of nitrous oxide. Upon analysis, sample and internal standard have similar retention times and are eluted quickly from the molecular sieve 5Å PLOT capillary column and the Porabond Q column therefore providing rapid data collection whilst preserving well defined peaks. After validation, the method has been applied to a real case of N2O intoxication indicating concentrations in a mono-intoxication. Copyright © 2015 Elsevier B.V. All rights reserved.

How will greenhouse gas observations meet changing requirements, laws, and demands?

NASA Astrophysics Data System (ADS)

Butler, J. H.; Tans, P. P.; Sweeney, C.; Andrews, A. E.; Miller, J. B.; Montzka, S. A.

2010-12-01

Recent efforts to develop a global greenhouse gas information system (GHGIS) have been driven by an anticipated need to support future national emission reduction policies or international treaties with observations. Such an effort would be similar to that done in support of the Montreal Protocol on Substances that Deplete Ozone, but more complex. However, greenhouse gas emissions are much more difficult to manage and may not be controlled by international agreement. The Kyoto Protocol has been fraught with political and practical difficulties, not the least of which is the absence of an independent observation and analysis requirement. Nevertheless, no unifying agreement was reached at the much heralded 2009 Conference of Parties (COP-15) in Copenhagen. Thus, it is quite possible (likely?) that greenhouse gas emissions may be reduced owing to other, uncoordinated policies that have their own merits, e.g., energy efficiency, alternative energy development, air quality improvement, forest development, agricultural practices, etc. If this is the future, then what observations and observation system design are needed and to what end? This presentation will discuss those needs in light of critical observations, analytical approaches, and evolving, disparate policies.

International comparison Euramet.QM-K111—propane in nitrogen

NASA Astrophysics Data System (ADS)

Wouter van der Hout, J.; van der Veen, Adriaan M. H.; Ziel, Paul R.; Kipphardt, Heinrich; Tuma, Dirk; Maiwald, Michael; Fernández, Teresa E.; Gómez, Concepción; Cieciora, Dariusz; Ochman, Grzegorz; Dias, Florbela; Silvino, Victor; Macé, Tatiana; Sutour, Christophe; Marioni, Fabrice; Ackermann, Andreas; Niederhauser, Bernhard; Fükő, Judit; Büki, Tamás; Nagyné Szilágyi, Zsófia; Tarhan, Tanıl; Engin, Erinç

2017-01-01

This key comparison aims to assess the core capabilities of the participants in gas analysis. Such competences include, among others, the capabilities to prepare Primary Standard gas Mixtures (PSMs), perform the necessary purity analysis on the materials used in the gas mixture preparation, the verification of the composition of newly prepared PSMs against existing ones, and the capability of calibrating the composition of a gas mixture. According to the Strategy for Key Comparisons of the Gas Analysis Working Group, this key comparison is classified as an RMO track A key comparison. The artefacts were binary mixtures of propane in nitrogen at a nominal amount-of-substance fraction level of 1000 μmol/mol. The values and uncertainties from the gravimetric gas mixture preparation were used as key comparison reference values (KCRVs). Each transfer standard had its own KCRV. The results are generally good. All results are within +/- 1 % of the KCRV. Main text To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/. The final report has been peer-reviewed and approved for publication by the CCQM, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).

Polarized internal target apparatus

DOEpatents

Holt, R.J.

1984-10-10

A polarized internal target apparatus with a polarized gas target of improved polarization and density (achieved by mixing target gas atoms with a small amount of alkali metal gas atoms, and passing a high intensity polarized light source into the mixture to cause the alkali metal gas atoms to become polarized which interact in spin exchange collisions with target gas atoms yielding polarized target gas atoms) is described.

Nitrogen enriched combustion of a natural gas internal combustion engine to reduce NO.sub.x emissions

DOEpatents

Biruduganti, Munidhar S.; Gupta, Sreenath Borra; Sekar, R. Raj; McConnell, Steven S.

2008-11-25

A method and system for reducing nitrous oxide emissions from an internal combustion engine. An input gas stream of natural gas includes a nitrogen gas enrichment which reduces nitrous oxide emissions. In addition ignition timing for gas combustion is advanced to improve FCE while maintaining lower nitrous oxide emissions.

Forecasting of natural gas consumption with neural network and neuro fuzzy system

NASA Astrophysics Data System (ADS)

Kaynar, Oguz; Yilmaz, Isik; Demirkoparan, Ferhan

2010-05-01

The prediction of natural gas consumption is crucial for Turkey which follows foreign-dependent policy in point of providing natural gas and whose stock capacity is only 5% of internal total consumption. Prediction accuracy of demand is one of the elements which has an influence on sectored investments and agreements about obtaining natural gas, so on development of sector. In recent years, new techniques, such as artificial neural networks and fuzzy inference systems, have been widely used in natural gas consumption prediction in addition to classical time series analysis. In this study, weekly natural gas consumption of Turkey has been predicted by means of three different approaches. The first one is Autoregressive Integrated Moving Average (ARIMA), which is classical time series analysis method. The second approach is the Artificial Neural Network. Two different ANN models, which are Multi Layer Perceptron (MLP) and Radial Basis Function Network (RBFN), are employed to predict natural gas consumption. The last is Adaptive Neuro Fuzzy Inference System (ANFIS), which combines ANN and Fuzzy Inference System. Different prediction models have been constructed and one model, which has the best forecasting performance, is determined for each method. Then predictions are made by using these models and results are compared. Keywords: ANN, ANFIS, ARIMA, Natural Gas, Forecasting

Internal Stress and Microstructure of Zinc Oxide Films Sputter-Deposited with Carbon Dioxide Gas

NASA Astrophysics Data System (ADS)

Toru Ashida,; Kazuhiro Kato,; Hideo Omoto,; Atsushi Takamatsu,

2010-06-01

The internal stress and microstructure of ZnO films were investigated as a function of carbon dioxide (CO2) gas flow ratio [CO2/(O2+CO2)] during sputter deposition. The internal stress of the ZnO films decreased with increasing CO2 gas flow ratio. The carbon concentration in the films deposited using CO2 gas increased by up to 4.0 at. %. Furthermore, the ZnO films deposited without CO2 gas exhibited a preferred orientation of (002); however, the C-doped ZnO films exhibited random orientations. These findings suggest that the C atoms incorporated in the ZnO crystal lattice induce this random orientation, thereby relaxing the internal stress of C-doped ZnO films.

Radioisotope Stirling Engine Powered Airship for Low Altitude Operation on Venus

NASA Technical Reports Server (NTRS)

Colozza, Anthony J.

2012-01-01

The feasibility of a Stirling engine powered airship for the near surface exploration of Venus was evaluated. The heat source for the Stirling engine was limited to 10 general purpose heat source (GPHS) blocks. The baseline airship utilized hydrogen as the lifting gas and the electronics and payload were enclosed in a cooled insulated pressure vessel to maintain the internal temperature at 320 K and 1 Bar pressure. The propulsion system consisted of an electric motor driving a propeller. An analysis was set up to size the airship that could operate near the Venus surface based on the available thermal power. The atmospheric conditions on Venus were modeled and used in the analysis. The analysis was an iterative process between sizing the airship to carry a specified payload and the power required to operate the electronics, payload and cooling system as well as provide power to the propulsion system to overcome the drag on the airship. A baseline configuration was determined that could meet the power requirements and operate near the Venus surface. From this baseline design additional trades were made to see how other factors affected the design such as the internal temperature of the payload chamber and the flight altitude. In addition other lifting methods were evaluated such as an evacuated chamber, heated atmospheric gas and augmented heated lifting gas. However none of these methods proved viable.

Hypersonic ramjet experiment project. Phase 1: Computer program description, ramjet and scramjet cycle performance

NASA Technical Reports Server (NTRS)

Jackson, R. J.; Wang, T. T.

1974-01-01

A computer program was developed to describe the performance of ramjet and scramjet cycles. The program performs one dimensional calculations of the equilibrium, real-gas internal flow properties of the engine. The program can be used for the following: (1) preliminary design calculation and (2) design analysis of internal flow properties corresponding to stipulated flow areas. Only the combustion of hydrogen in air is considered in this case.

Effects of Surfactant Contamination on the Next Generation Gas Trap for the ISS Internal Thermal Control System

NASA Technical Reports Server (NTRS)

Leimkuehler, Thomas O.; Lukens, Clark; Reeves, Daniel R.; Holt, James M.

2004-01-01

The current dual-membrane gas trap is designed to remove non-condensed gas bubbles from the Internal Thermal Control System (ITCS) coolant on board the International Space Station (ISS). To date it has successfully served its purpose of preventing gas bubbles from causing depriming, overspeed, and shutdown of the ITCS pump. However, contamination in the ITCS coolant has adversely affected the gas venting rate and lifetime of the gas trap, warranting a development effort for a next-generation gas trap. Previous testing has shown that a hydrophobic-only design is capable of performing even better than the current dual-membrane design for both steady-state gas removal and gas slug removal in clean deionized water. This paper presents results of testing to evaluate the effects of surfactant contamination on the steady-state performance of the hydrophobic-only design.

Brunei Country Analysis Brief

EIA Publications

2017-01-01

Brunei's small, wealthy economy is based heavily upon proceeds from exports of crude oil and natural gas. Brunei relies on hydrocarbon revenues for about 60% of its gross domestic product and about 90% of its merchandise exports and government revenues. Lower international oil prices since late 2014 have dampened the country’s export revenues. However, the government intends to bolster investment in its oil and gas sector and diversify the country’s economic base by promoting growth in other industries over the long term.

The use of gas chromatographic-mass spectrometric-computer systems in pharmacokinetic studies.

PubMed

Horning, M G; Nowlin, J; Stafford, M; Lertratanangkoon, K; Sommer, K R; Hill, R M; Stillwell, R N

1975-10-29

Pharmacokinetic studies involving plasma, urine, breast milk, saliva and liver homogenates have been carried out by selective ion detection with a gas chromatographic-mass spectrometric-computer system operated in the chemical ionization mode. Stable isotope labeled drugs were used as internal standards for quantification. The half-lives, the concentration at zero time, the slope (regression coefficient), the maximum velocity of the reaction and the apparent Michaelis constant of the reaction were determined by regression analysis, and also by graphic means.

Green's function solution to heat transfer of a transparent gas through a tube

NASA Technical Reports Server (NTRS)

Frankel, J. I.

1989-01-01

A heat transfer analysis of a transparent gas flowing through a circular tube of finite thickness is presented. This study includes the effects of wall conduction, internal radiative exchange, and convective heat transfer. The natural mathematical formulation produces a nonlinear, integrodifferential equation governing the wall temperature and an ordinary differential equation describing the gas temperature. This investigation proposes to convert the original system of equations into an equivalent system of integral equations. The Green's function method permits the conversion of an integrodifferential equation into a pure integral equation. The proposed integral formulation and subsequent computational procedure are shown to be stable and accurate.

Analysis of benzo(a)pyrene in airborne particulates by gas chromatography

NASA Technical Reports Server (NTRS)

Luedecke, E.

1976-01-01

A routine method was developed to measure benzo(a)pyrene in airborne particulates. Samples were collected on a filter and the organic portion was extracted with cyclohexane. The polynuclear hydrocarbon (PNHC) fraction was separated from the aliphatics by column chromatography. An internal standard was added to the extract and a portion of it was injected into a gas chromatograph. Although the gas chromatographic method has often been reported in the literature, satisfactory separation of benzo(a)pyrene and benzo(e)pyrene has not been achieved. With the introduction of a nematic liquid crystal as the stationary phase good separation is now possible.

Numerical Analysis of the Trailblazer Inlet Flowfield for Hypersonic Mach Numbers

NASA Technical Reports Server (NTRS)

Steffen, C. J., Jr.; DeBonis, J. R.

1999-01-01

A study of the Trailblazer vehicle inlet was conducted using the Global Air Sampling Program (GASP) code for flight Mach numbers ranging from 4-12. Both perfect gas and finite rate chemical analysis were performed with the intention of making detailed comparisons between the two results. Inlet performance was assessed using total pressure recovery and kinetic energy efficiency. These assessments were based upon a one-dimensional stream-thrust-average of the axisymmetric flowfield. Flow visualization utilized to examine the detailed shock structures internal to this mixed-compression inlet. Kinetic energy efficiency appeared to be the least sensitive to differences between the perfect gas and finite rate chemistry results. Total pressure recovery appeared to be the most sensitive discriminator between the perfect gas and finite rate chemistry results for flight Mach numbers above Mach 6. Adiabatic wall temperature was consistently overpredicted by the perfect gas model for flight Mach numbers above Mach 4. The predicted shock structures were noticeably different for Mach numbers from 6-12. At Mach 4, the perfect gas and finite rate chemistry models collapse to the same result.

75 FR 82040 - Notice of Public Meeting on the International Maritime Organization Guidelines for Exhaust Gas...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-29

... on the International Maritime Organization Guidelines for Exhaust Gas Cleaning Systems for Marine... Organization guidelines for exhaust gas cleaning systems for marine engines in Washington, DC. The purpose of... exhaust gas cleaning systems for marine engines to remove sulphur oxide emissions in order to comply with...

Filler bar heating due to stepped tiles in the shuttle orbiter thermal protection system

NASA Technical Reports Server (NTRS)

Petley, D. H.; Smith, D. M.; Edwards, C. L. W.; Patten, A. B.; Hamilton, H. H., II

1983-01-01

An analytical study was performed to investigate the excessive heating in the tile to tile gaps of the Shuttle Orbiter Thermal Protection System due to stepped tiles. The excessive heating was evidence by visible discoloration and charring of the filler bar and strain isolation pad that is used in the attachment of tiles to the aluminum substrate. Two tile locations on the Shuttle orbiter were considered, one on the lower surface of the fuselage and one on the lower surface of the wing. The gap heating analysis involved the calculation of external and internal gas pressures and temperatures, internal mass flow rates, and the transient thermal response of the thermal protection system. The results of the analysis are presented for the fuselage and wing location for several step heights. The results of a study to determine the effectiveness of a half height ceramic fiber gap filler in preventing hot gas flow in the tile gaps are also presented.

Gas monitoring onboard ISS using FTIR spectroscopy

NASA Astrophysics Data System (ADS)

Gisi, Michael; Stettner, Armin; Seurig, Roland; Honne, Atle; Witt, Johannes; Rebeyre, Pierre

2017-06-01

In the confined, enclosed environment of a spacecraft, the air quality must be monitored continuously in order to safeguard the crew's health. For this reason, OHB builds the ANITA2 (Analysing Interferometer for Ambient Air) technology demonstrator for trace gas monitoring onboard the International Space Station (ISS). The measurement principle of ANITA2 is based on the Fourier Transform Infrared (FTIR) technology with dedicated gas analysis software from the Norwegian partner SINTEF. This combination proved to provide high sensitivity, accuracy and precision for parallel measurements of 33 trace gases simultaneously onboard ISS by the precursor instrument ANITA1. The paper gives a technical overview about the opto-mechanical components of ANITA2, such as the interferometer, the reference Laser, the infrared source and the gas cell design and a quick overview about the gas analysis. ANITA2 is very well suited for measuring gas concentrations specifically but not limited to usage onboard spacecraft, as no consumables are required and measurements are performed autonomously. ANITA2 is a programme under the contract of the European Space Agency, and the air quality monitoring system is a stepping stone into the future, as a precursor system for manned exploration missions.

Psychometric evaluation of the adolescent and parent versions of the Gaming Addiction Identification Test (GAIT).

PubMed

Vadlin, Sofia; Åslund, Cecilia; Rehn, Mattias; Nilsson, Kent W

2015-12-01

The objective of the study is to evaluate the psychometric properties of the Gaming Addiction Identification Test (GAIT) and its parent version (GAIT-P), in a representative community sample of adolescents and parents in Västmanland, Sweden. Self-rated and parent-rated gaming addictive symptoms identified by GAIT and GAIT-P were analyzed for frequency of endorsement, internal consistency, concordance, factor structure, prevalence of Internet gaming disorder (IGD), concurrence with the Gaming Addiction Scale for Adolescents, 7-item version (GAS) and the parent version of GAS (GAS-P), and for sex differences. The 12-month prevalence of IGD was found to be 1.3% with GAIT and 2.4% with GAIT-P. Results also indicate promising psychometric results within this population, with high internal consistency, and high concurrent validity with GAS and GAS-P. Concordance between adolescents and parents ratings was high, although moderate in girls. Although exploratory factor analysis indicated poor model fit, it also indicated unidimensionality and high factor loadings in all analyses. GAIT and GAIT-P are suitable for continued use in measuring gaming addiction in adolescents, and, with the additional two items, they now cover all nine IGD criteria. © 2015 Scandinavian Psychological Associations and John Wiley & Sons Ltd.

Operational Experience with the Internal Thermal Control System Dual-Membrane Gas Trap

NASA Technical Reports Server (NTRS)

Leimkuehler, Thomas O.; Lukens, Clark; Reeves, Daniel R.; Holt, James M.

2003-01-01

A dual-membrane gas trap is currently used to remove non-condensed gases (NCG) from the Internal Thermal Control System (ITCS) coolant on board the International Space Station. The gas trap consists of concentric tube membrane pairs, comprised of outer hydrophilic tubes and inner hydrophobic fibers. Liquid coolant passes through the outer hydrophilic membrane, which traps the NCG. The inner hydrophobic fiber allows the trapped NCG to pass through and vent to the ambient atmosphere in the cabin. The purpose of the gas trap is to prevent gas bubbles from causing depriming, overspeed, and shutdown of the ITCS pump, and the current gas trap has performed flawlessly in this regard. However, because of actual operational conditions on-orbit, its gas removal performance and operational lifetime have been affected. This paper discusses experiences with several of these dual- membrane gas traps, including on-orbit gas venting rate, effects due to the presence of nickel in the ITCS coolant, and subsequent refurbishing to remove the nickel from the gas trap.

A Novel Repair Technique for the Internal Thermal Control System Dual-Membrane Gas Trap

NASA Technical Reports Server (NTRS)

Leimkuehler, Thomas O.; Patel, Vipul; Reeves, Daniel R.; Holt, James M.

2005-01-01

A dual-membrane gas trap is currently used to remove gas bubbles from the Internal Thermal Control System (ITCS) coolant on board the International Space Station (ISS). The gas trap consists of concentric tube membrane pairs, comprised of outer hydrophilic tubes and inner hydrophobic fibers. Liquid coolant passes through the outer hydrophilic membrane, which traps the gas bubbles. The inner hydrophobic fiber allows the trapped gas bubbles to pass through and vent to the ambient atmosphere in the cabin. The gas trap was designed to last for the entire lifetime of the ISS, and therefore was not designed to be repaired. However, repair of these gas traps is now a necessity due to contamination from the on-orbit ITCS fluid and other sources on the ground as well as a limited supply of flight gas traps. This paper describes a novel repair technique that has been developed that will allow the refurbishment of contaminated gas traps and their return to flight use.

Deformation of Cases in High Capacitance Value Wet Tantalum Capacitors under Environmental Stresses

NASA Technical Reports Server (NTRS)

Teverovsky, Alexander

2016-01-01

Internal gas pressure in hermetic wet tantalum capacitors is created by air, electrolyte vapor, and gas generated by electrochemical reactions at the electrodes. This pressure increases substantially with temperature and time of operation due to excessive leakage currents. Deformation of the case occurs when the internal pressure exceeds pressure of the environments and can raise significantly when a part operates in space. Contrary to the cylinder case wet tantalum capacitors that have external sealing by welding and internal sealing provided by the Teflon bushing and crimping of the case, no reliable internal sealing exists in the button case capacitors. Single seal design capacitors are used for high capacitance value wet tantalum capacitors manufactured per DLA L&M drawings #04003, 04005, and 10011, and require additional analysis to assure their reliable application in space systems. In this work, leakage currents and case deformation of button case capacitors were measured during different environmental test conditions. Recommendations for derating, screening and qualification testing are given. This work is a continuation of a series of NEPP reports related to quality and reliability of wet tantalum capacitors.

Internal standards for use in the comprehensive analysis of polychlorinated aromatic hydrocarbons using gas chromatography combined with multiphoton ionization mass spectrometry.

PubMed

Li, Adan; Imasaka, Totaro

2016-10-28

To decrease health-risks to humans, non-toxic compounds were evaluated for use as internal standards for calibrating data obtained by gas chromatography/multiphoton ionization mass spectrometry (GC-MPI-MS) using an ultraviolet femtosecond laser as the ionization source. The retention time in the mass chromatogram was calibrated using a retention index, in which a series of n-alkanes was employed as internal standards for evaluating the retention times for polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), and polychlorinated biphenyls (PCBs). To compensate for changes in signal intensity in MPI-MS, the dependence of signal intensity on the laser pulse energy was investigated for the dioxin-like compounds, in addition to five non-toxic aromatic hydrocarbons, that were used as internal standards. Based on their similar behavior,the non-toxic PCDD/PCDF, its 13 C-isotope, and pentachlorobenzene behave similarly, we conclude that they can be used for calibrating the signal intensities in MPI-MS. Copyright © 2016 Elsevier B.V. All rights reserved.

Wellsite, laboratory, and mathematical techniques for determining sorbed gas content of coals and gas shales utilizing well cuttings

USGS Publications Warehouse

Newell, K.D.

2007-01-01

Drill cuttings can be used for desorption analyses but with more uncertainty than desorption analyses done with cores. Drill cuttings are not recommended to take the place of core, but in some circumstances, desorption work with cuttings can provide a timely and economic supplement to that of cores. The mixed lithologic nature of drill cuttings is primarily the source of uncertainty in their analysis for gas content, for it is unclear how to apportion the gas generated from both the coal and the dark-colored shale that is mixed in usually with the coal. In the Western Interior Basin Coal Basin in eastern Kansas (Pennsylvanian-age coals), dark-colored shales with normal (??? 100 API units) gamma-ray levels seem to give off minimal amounts of gas on the order of less than five standard cubic feet per ton (scf/ton). In some cuttings analyses this rule of thumb for gas content of the shale is adequate for inferring the gas content of coals, but shales with high-gamma-ray values (>150 API units) may yield several times this amount of gas. The uncertainty in desorption analysis of drill cuttings can be depicted graphically on a diagram identified as a "lithologic component sensitivity analysis diagram." Comparison of cuttings desorption results from nearby wells on this diagram, can sometimes yield an unique solution for the gas content of both a dark shale and coal mixed in a cuttings sample. A mathematical solution, based on equating the dry, ash-free gas-contents of the admixed coal and dark-colored shale, also yields results that are correlative to data from nearby cores. ?? 2007 International Association for Mathematical Geology.

BASIN-CENTERED GAS SYSTEMS OF THE U.S.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marin A. Popov; Vito F. Nuccio; Thaddeus S. Dyman

2000-11-01

The USGS is re-evaluating the resource potential of basin-centered gas accumulations in the U.S. because of changing perceptions of the geology of these accumulations, and the availability of new data since the USGS 1995 National Assessment of United States oil and gas resources (Gautier et al., 1996). To attain these objectives, this project used knowledge of basin-centered gas systems and procedures such as stratigraphic analysis, organic geochemistry, modeling of basin thermal dynamics, reservoir characterization, and pressure analysis. This project proceeded in two phases which had the following objectives: Phase I (4/1998 through 5/1999): Identify and describe the geologic and geographicmore » distribution of potential basin-centered gas systems, and Phase II (6/1999 through 11/2000): For selected systems, estimate the location of those basin-centered gas resources that are likely to be produced over the next 30 years. In Phase I, we characterize thirty-three (33) potential basin-centered gas systems (or accumulations) based on information published in the literature or acquired from internal computerized well and reservoir data files. These newly defined potential accumulations vary from low to high risk and may or may not survive the rigorous geologic scrutiny leading towards full assessment by the USGS. For logistical reasons, not all basins received the level of detail desired or required.« less

Life cycle assessment integrated with thermodynamic analysis of bio-fuel options for solid oxide fuel cells.

PubMed

Lin, Jiefeng; Babbitt, Callie W; Trabold, Thomas A

2013-01-01

A methodology that integrates life cycle assessment (LCA) with thermodynamic analysis is developed and applied to evaluate the environmental impacts of producing biofuels from waste biomass, including biodiesel from waste cooking oil, ethanol from corn stover, and compressed natural gas from municipal solid wastes. Solid oxide fuel cell-based auxiliary power units using bio-fuel as the hydrogen precursor enable generation of auxiliary electricity for idling heavy-duty trucks. Thermodynamic analysis is applied to evaluate the fuel conversion efficiency and determine the amount of fuel feedstock needed to generate a unit of electrical power. These inputs feed into an LCA that compares energy consumption and greenhouse gas emissions of different fuel pathways. Results show that compressed natural gas from municipal solid wastes is an optimal bio-fuel option for SOFC-APU applications in New York State. However, this methodology can be regionalized within the U.S. or internationally to account for different fuel feedstock options. Copyright © 2012 Elsevier Ltd. All rights reserved.

Versatile, ultra-low sample volume gas analyzer using a rapid, broad-tuning ECQCL and a hollow fiber gas cell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kriesel, Jason M.; Makarem, Camille N.; Phillips, Mark C.

We describe a versatile mid-infrared (Mid-IR) spectroscopy system developed to measure the concentration of a wide range of gases with an ultra-low sample size. The system combines a rapidly-swept external cavity quantum cascade laser (ECQCL) with a hollow fiber gas cell. The ECQCL has sufficient spectral resolution and reproducibility to measure gases with narrow features (e.g., water, methane, ammonia, etc.), and also the spectral tuning range needed to measure volatile organic compounds (VOCs), (e.g., aldehydes, ketones, hydrocarbons), sulfur compounds, chlorine compounds, etc. The hollow fiber is a capillary tube having an internal reflective coating optimized for transmitting the Mid-IR lasermore » beam to a detector. Sample gas introduced into the fiber (e.g., internal volume = 0.6 ml) interacts strongly with the laser beam, and despite relatively modest path lengths (e.g., L ~ 3 m), the requisite quantity of sample needed for sensitive measurements can be significantly less than what is required using conventional IR laser spectroscopy systems. Example measurements are presented including quantification of VOCs relevant for human breath analysis with a sensitivity of ~2 picomoles at a 1 Hz data rate.« less

Versatile, ultra-low sample volume gas analyzer using a rapid, broad-tuning ECQCL and a hollow fiber gas cell

NASA Astrophysics Data System (ADS)

Kriesel, Jason M.; Makarem, Camille N.; Phillips, Mark C.; Moran, James J.; Coleman, Max L.; Christensen, Lance E.; Kelly, James F.

2017-05-01

We describe a versatile mid-infrared (Mid-IR) spectroscopy system developed to measure the concentration of a wide range of gases with an ultra-low sample size. The system combines a rapidly-swept external cavity quantum cascade laser (ECQCL) with a hollow fiber gas cell. The ECQCL has sufficient spectral resolution and reproducibility to measure gases with narrow features (e.g., water, methane, ammonia, etc.), and also the spectral tuning range needed to measure volatile organic compounds (VOCs), (e.g., aldehydes, ketones, hydrocarbons), sulfur compounds, chlorine compounds, etc. The hollow fiber is a capillary tube having an internal reflective coating optimized for transmitting the Mid-IR laser beam to a detector. Sample gas introduced into the fiber (e.g., internal volume = 0.6 ml) interacts strongly with the laser beam, and despite relatively modest path lengths (e.g., L 3 m), the requisite quantity of sample needed for sensitive measurements can be significantly less than what is required using conventional IR laser spectroscopy systems. Example measurements are presented including quantification of VOCs relevant for human breath analysis with a sensitivity of 2 picomoles at a 1 Hz data rate.

Surface Composition Influence on Internal Gas Flow at Large Knudsen Numbers

DTIC Science & Technology

2000-07-09

situated in an ultra high vacuum system . The system is supplied with means of gas phase, surface CP585, Rarefied Gas Dynamics: 22nd International...control and gas flow measuring system . The experimental procedure consists in a few stages. The first stage includes surface preparation process at...solid body system , Proceedings 20-th Int. Symp. Rarefied Gas Dynamics, Peking University Press, Beijing, China, 1997, pp. 387-391. 3. Lord, R.G

One-dimensional analysis of supersonic two-stage HVOF process

NASA Astrophysics Data System (ADS)

Katanoda, Hiroshi; Hagi, Junichi; Fukuhara, Minoru

2009-12-01

The one-dimensional calculation of the gas/particle flows of a supersonic two-stage high-velocity oxy-fuel (HVOF) thermal spray process was performed. The internal gas flow was solved by numerically integrating the equations of the quasi-one-dimensional flow including the effects of pipe friction and heat transfer. As for the supersonic jet flow, semi-empirical equations were used to obtain the gas velocity and temperature along the center line. The velocity and temperature of the particle were obtained by an one-way coupling method. The material of the spray particle selected in this study is ultra high molecular weight polyethylene (UHMWPE). The temperature distributions in the spherical UHMWPE particles of 50 and 150µm accelerated and heated by the supersonic gas flow was clarified.

Evaluation of the quality of sandalwood essential oils by gas chromatography-mass spectrometry.

PubMed

Howes, Melanie-Jayne R; Simmonds, Monique S J; Kite, Geoffrey C

2004-03-05

Trade and historic oils from 'sandalwoods', labelled as Amyris balsamifera, Eremophila mitchelli, Fusanus acuminatus (= Santalum acuminatum), Santalum album, S. austrocaledonicum, S. latifolium, S. spicatum and S. yasi, were assessed using gas chromatography-mass spectrometry (GC-MS). Using GC-MS, none of the oils assessed complied with the internationally recognised standard of a 90% santalol content, and only about half of the trade sandalwood oils met with recent International Organisation for Standardisation standards. The majority of trade oils, reportedly from S. album, contained approximately 50-70% santalols (Z-alpha and Z-beta). Thus, the internationally recognised specification (90% santalols) for S. album requires re-evaluation by more efficient analysis methods. In view of the issues associated with the quality of sandalwood oils being traded, specifications of > or = 43% Z-alpha-santalol and > or = 18% Z-beta-santalol for S. album oil estimated by GC-MS are suggested. GC-MS are recommended as it assists with authentication and quality control issues associated with sandalwood oils.

Ecological policy in oil-gas complexes, HSE MS implementation in oil and gas company

NASA Astrophysics Data System (ADS)

Kochetkova, O. P.; Glyzina, T. S.; Vazim, A. A.; Tugutova, S. S.

2016-09-01

The paper considers the following issues: HSE MS international standard implementation in oil and gas industry, taking into account international practices; implementation of standards in oil and gas companies; policy in the field of environmental protection and occupational health and safety; achievement of planned indicators and targets in environmental protection and occupational health and safety.

Modeling and Simulation of a Nuclear Fuel Element Test Section

NASA Technical Reports Server (NTRS)

Moran, Robert P.; Emrich, William

2011-01-01

"The Nuclear Thermal Rocket Element Environmental Simulator" test section closely simulates the internal operating conditions of a thermal nuclear rocket. The purpose of testing is to determine the ideal fuel rod characteristics for optimum thermal heat transfer to their hydrogen cooling/working fluid while still maintaining fuel rod structural integrity. Working fluid exhaust temperatures of up to 5,000 degrees Fahrenheit can be encountered. The exhaust gas is rendered inert and massively reduced in temperature for analysis using a combination of water cooling channels and cool N2 gas injectors in the H2-N2 mixer portion of the test section. An extensive thermal fluid analysis was performed in support of the engineering design of the H2-N2 mixer in order to determine the maximum "mass flow rate"-"operating temperature" curve of the fuel elements hydrogen exhaust gas based on the test facilities available cooling N2 mass flow rate as the limiting factor.

Effect of layerwise structural inhomogeneity on stress- corrosion cracking of steel tubes

NASA Astrophysics Data System (ADS)

Perlovich, Yu A.; Krymskaya, O. A.; Isaenkova, M. G.; Morozov, N. S.; Fesenko, V. A.; Ryakhovskikh, I. V.; Esiev, T. S.

2016-04-01

Based on X-ray texture and structure analysis data of the material of main gas pipelines it was shown that the layerwise inhomogeneity of tubes is formed during their manufacturing. The degree of this inhomogeneity affects on the tendency of tubes to stress- corrosion cracking under exploitation. Samples of tubes were cut out from gas pipelines located under various operating conditions. Herewith the study was conducted both for sections with detected stress-corrosion defects and without them. Distributions along tube wall thickness for lattice parameters and half-width of X-ray lines were constructed. Crystallographic texture analysis of external and internal tube layers was also carried out. Obtained data testifies about considerable layerwise inhomogeneity of all samples. Despite the different nature of the texture inhomogeneity of gas pipeline tubes, the more inhomogeneous distribution of texture or structure features causes the increasing of resistance to stress- corrosion. The observed effect can be explained by saturation with interstitial impurities of the surface layer of the hot-rolled sheet and obtained therefrom tube. This results in rising of lattice parameters in the external layer of tube as compared to those in underlying metal. Thus, internal layers have a compressive effect on external layers in the rolling plane that prevents cracks opening at the tube surface. Moreover, the high mutual misorientation of grains within external and internal layers of tube results in the necessity to change the moving crack plane, so that the crack growth can be inhibited when reaching the layer with a modified texture.

Numerical analysis of the transient response of an axisymmetric ablative char layer considering internal flow effects

NASA Technical Reports Server (NTRS)

Pittman, C. M.; Howser, L. M.

1972-01-01

The differential equations governing the transient response of the char layer of an ablating axisymmetric body, internal pyrolysis gas flow effects being considered, have been derived. These equations have been expanded into finite difference form and programed for numerical solution on a digital computer. Numerical results compare favorably with simplified exact solutions. The complete numerical analysis was used to obtain solutions for two representative body shapes subjected to a typical entry heating environment. Pronounced effects of the lateral flow of pyrolysis gases on the mass flow field within the char layer and the associated surface and pyrolysis interface recession rates are shown.

Analysis of selected volatile organic compounds at background level in South Africa.

NASA Astrophysics Data System (ADS)

Ntsasa, Napo; Tshilongo, James; Lekoto, Goitsemang

2017-04-01

Volatile organic compounds (VOC) are measured globally at urban air pollution monitoring and background level at specific locations such as the Cape Point station. The urban pollution monitoring is legislated at government level; however, the background levels are scientific outputs of the World Meteorological Organisation Global Atmospheric Watch program (WMO/GAW). The Cape Point is a key station in the Southern Hemisphere which monitors greenhouse gases and halocarbons, with reported for over the past decade. The Cape Point station does not have the measurement capability VOC's currently. A joint research between the Cape Point station and the National Metrology Institute of South Africa (NMISA) objective is to perform qualitative and quantitative analysis of volatile organic compounds listed in the GAW program. NMISA is responsible for development, maintain and disseminate primary reference gas mixtures which are directly traceable to the International System of Units (SI) The results of some volatile organic compounds which where sampled in high pressure gas cylinders will be presented. The analysis of samples was performed on the gas chromatography with flame ionisation detector and mass selective detector (GC-FID/MSD) with a dedicate cryogenic pre-concentrator system. Keywords: volatile organic compounds, gas chromatography, pre-concentrator

Exhaust gas recirculation system for an internal combustion engine

DOEpatents

Wu, Ko-Jen

2013-05-21

An exhaust gas recirculation system for an internal combustion engine comprises an exhaust driven turbocharger having a low pressure turbine outlet in fluid communication with an exhaust gas conduit. The turbocharger also includes a low pressure compressor intake and a high pressure compressor outlet in communication with an intake air conduit. An exhaust gas recirculation conduit fluidly communicates with the exhaust gas conduit to divert a portion of exhaust gas to a low pressure exhaust gas recirculation branch extending between the exhaust gas recirculation conduit and an engine intake system for delivery of exhaust gas thereto. A high pressure exhaust gas recirculation branch extends between the exhaust gas recirculation conduit and the compressor intake and delivers exhaust gas to the compressor for mixing with a compressed intake charge for delivery to the intake system.

Thermal Management as a Force Multiplier within the Research, Development, and Engineering Command (RDECOM)

DTIC Science & Technology

2012-08-01

pp. 4–9. 46. Ye, Liang; Tong, Ming Wei; Zeng, Xin Design and Analysis of Multiple Parallel-pass Condensers. International Journal of Refrigeration...we mean energy that has low availability to do work (low exergy ). The closer a system is to the condition of its surroundings in terms of...vehicle with a gasoline internal combustion engine loses 40% of its fuel energy through the exhaust gas, which is still at a relatively high

Instrumentation for Aerosol and Gas Speciation

NASA Technical Reports Server (NTRS)

Coggiola, Michael J.

1998-01-01

Using support from NASA Grant No. NAG 2-963, SRI International successfully completed the project, entitled, 'Instrumentation for Aerosol and Gas Speciation.' This effort (SRI Project 7383) covered the design, fabrication, testing, and deployment of a real-time aerosol speciation instrument in NASA's DC-8 aircraft during the Spring 1996 SUbsonic aircraft: Contrail and Cloud Effects Special Study (SUCCESS) mission. This final technical report describes the pertinent details of the instrument design, its abilities, its deployment during SUCCESS and the data acquired from the mission, and the post-mission calibration, data reduction, and analysis.

Burma (Myanmar) Country Analysis Brief

EIA Publications

2016-01-01

Burma (Myanmar) is an important natural gas producer in Southeast Asia, although its upstream hydrocarbons sector is severely underdeveloped. Financial constraints by Burma’s national oil company, a lack of technical capacity, opaque regulatory policy, insufficient investment by foreign firms, and international sanctions have significantly impeded the country’s efforts to realize its oil and natural gas production potential. These factors have also severely hampered the development of necessary energy infrastructure. However, U.S. and European Union sanctions were eased or suspended in 2012 and 2013 in response to political and economic reforms in Burma.

21ST International Symposium on Rarefied Gas Dynamics, Marseille (France) 26-31 July 1998. Book of Abstracts, Volume II: Poster Sessions.

DTIC Science & Technology

1998-07-30

for normal oxidation. other surfaces exposed to the fast 0 beam. These results and others clearly show that stoichiomet- nic layers of TeO2 are...to pos- However a detailed analysis shows that results both sibilities for reduction of aerodynamic friction for metal and glass channels with the...P.E., The effect of t e surf ce compos - accommodation coefficient for glass and metal (Ti tion on a free molecular gas flow in a cylin- or Mo) reachs

Insight into the molecular basis of pathogen abundance: group A Streptococcus inhibitor of complement inhibits bacterial adherence and internalization into human cells.

PubMed

Hoe, Nancy P; Ireland, Robin M; DeLeo, Frank R; Gowen, Brian B; Dorward, David W; Voyich, Jovanka M; Liu, Mengyao; Burns, Eugene H; Culnan, Derek M; Bretscher, Anthony; Musser, James M

2002-05-28

Streptococcal inhibitor of complement (Sic) is a secreted protein made predominantly by serotype M1 Group A Streptococcus (GAS), which contributes to persistence in the mammalian upper respiratory tract and epidemics of human disease. Unexpectedly, an isogenic sic-negative mutant adhered to human epithelial cells significantly better than the wild-type parental strain. Purified Sic inhibited the adherence of a sic negative serotype M1 mutant and of non-Sic-producing GAS strains to human epithelial cells. Sic was rapidly internalized by human epithelial cells, inducing cell flattening and loss of microvilli. Ezrin and moesin, human proteins that functionally link the cytoskeleton to the plasma membrane, were identified as Sic-binding proteins by affinity chromatography and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry analysis. Sic colocalized with ezrin inside epithelial cells and bound to the F-actin-binding site region located in the carboxyl terminus of ezrin and moesin. Synthetic peptides corresponding to two regions of Sic had GAS adherence-inhibitory activity equivalent to mature Sic and inhibited binding of Sic to ezrin. In addition, the sic mutant was phagocytosed and killed by human polymorphonuclear leukocytes significantly better than the wild-type strain, and Sic colocalized with ezrin in discrete regions of polymorphonuclear leukocytes. The data suggest that binding of Sic to ezrin alters cellular processes critical for efficient GAS contact, internalization, and killing. Sic enhances bacterial survival by enabling the pathogen to avoid the intracellular environment. This process contributes to the abundance of M1 GAS in human infections and their ability to cause epidemics.

International Space Station Major Constituent Analyzer On-Orbit Performance

NASA Technical Reports Server (NTRS)

Gardner, Ben D.; Erwin, Philip M.; Thoresen, Souzan; Granahan, John; Matty, Chris

2010-01-01

The Major Constituent Analyzer is a mass spectrometer based system that measures the major atmospheric constituents on the International Space Station. A number of limited-life components require periodic changeout, including the analyzer (ORU 02) and the verification gas assembly (ORU 08). The longest lasting ORU 02 was recently replaced after a record service length of 1033 days. The comparatively high performance duration may be attributable to a reduced inlet flow rate into the analyzer, resulting in increased ion pump lifetime; however, there may be other factors as well. A recent schedule slip for delivery of replacement verification gas led to a demonstration that the calibration interval could be extended on a short-term basis. An analysis of ORU 08 performance characteristics indicates that it is possible to temporarily extend the calibration interval from 6 weeks to 12 weeks if necessary.

Internal ballistics of the detonation products of a blast-hole charge

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mangush, S.K.; Garbunov, V.A.

1986-07-01

The authors investigate the gasdynamic flow of the detonation products of a blast-hole charge (the expansion of the detonation products in the blast hole and the gas outflow and propagation of shock airwaves into the face space). The problem is solved by means of a numerical program for integration of partial differential equations of one-dimensional gas-dynamics. A numerical model of the internal ballistics of a blast-hole charge is presented. In addition to the variation of the thermodynamic parameters in the blast hole, the formation of the shock wave in the face space is shown, which is the source of gasmore » ignition. Further development of the numerical model of the action of blast-hole charges is planned which will involve an analysis of a number of applied problems.« less

Technical and economic analysis use of flare gas into alternative energy as a breakthrough in achieving zero routine flaring

NASA Astrophysics Data System (ADS)

Petri, Y.; Juliza, H.; Humala, N.

2018-03-01

The activity of exploring natural oil and gas will produce gas flare 0.584 MMSCFD. A gas flare is the combustion of gas remaining to avoid poisonous gas like H2S and CO which is very dangerous for human and environmental health. The combustion can bring about environmental pollution and losses because it still contains valuable energy. It needs the policy to encourage the use of flare gas with Zero Routine Flaring and green productivity to reduce waste and pollution. The objective of the research was to determine the use of gas flare so that it will have economic value and can achieve Zero Routine Flaring. It was started by analysing based on volume or rate and composition gas flare was used to determine technical feasibility, and the estimation of the gas reserves as the determination of the economy of a gas well. The results showed that the use of flare gas as fuel for power generation feasible to be implemented technically and economically with Internal Rate of Return (IRR) 19.32% and the Payback Period (PP) 5 year. Thus, it can increase gas flare value economically and can achieve a breakthrough in Zero Routine Flaring.

Superplastic Forming of Duplex Stainless Steel for Aerospace Part

NASA Astrophysics Data System (ADS)

Lee, Ho-Sung; Yoon, Jong-Hoon; Yoo, Joon-Tae; Yi, Young-Moo

2011-08-01

In this study, the high temperature forming behavior of duplex stainless steel has been characterized and the outer shell of a combustion chamber was fabricated with pressure difference of hot gas. It consists of two parts which are the outer skin made of stainless steel to sustain the internal pressure and the inner shell made of copper alloy for regenerative cooling channels. Two outer skins partitioned to half with respect to the symmetric axis was prepared by hot gas forming process with a maximum pressure of 7 MPa following to FEM analysis. For inner layer, copper alloy was machined for cooling channels and then placed in the gas pressure welding fixture. It is shown that the optimum condition of gas pressure welding is 7 MPa at 890 °C, for one hour. EDX analysis and scanning electron microscope micrograph confirm the atomic diffusion process is observed at the interface and copper atoms diffuse into steel, while iron and chrome atoms diffuse into copper. The result shows that the manufacturing method with superplastic forming and gas pressure welding of steel and copper alloy has been successful for near net shape manufacturing of scaled combustion chamber of launch vehicle.

Evaluation of a rapid breath hydrogen analyzer for clinical studies of carbohydrate absorption.

PubMed

Solomons, N W; Hamilton, L H; Christman, N T; Rothman, D

1983-05-01

A second-generation gas chromatograph for the analysis of H2 in expired air has been developed. It incorporates a solid-state detector with high sensitivity for H2 and has a small, internal pump which supplies air as the carrier gas, thus eliminating the need for a large tank of compressed gas for the carrier. A reference gas of known H2 concentration is, of course, still required. The entire system weighs 6.0 kg and is completely portable, requiring only 120 V electric current for use. The instrument has a mean intersample interval of less than 2 min, with H2 concentration registered on a digital display. The output has a track-hold feature which permits the output, in parts per million H2, to be retained by the meter so the reading can be verified. The chromatogram can also be recorded on a conventional analog strip-chart recorder. The sensitivity and precision are superior to those of a thermal conductivity H2 gas chromatograph. Moreover, the rapid response time encourages frequent calibration checks with the reference gas. This analyzer offers significant advantages over previous H2-measuring systems for breath-analysis tests used both for diagnostic clinical practice and for field studies of nutritional assessment.

Internal combustion engine for natural gas compressor operation

DOEpatents

Hagen, Christopher; Babbitt, Guy

2016-12-27

This application concerns systems and methods for compressing natural gas with an internal combustion engine. In a representative embodiment, a method is featured which includes placing a first cylinder of an internal combustion engine in a compressor mode, and compressing a gas within the first cylinder, using the cylinder as a reciprocating compressor. In some embodiments a compression check valve system is used to regulate pressure and flow within cylinders of the engine during a compression process.

49 CFR 192.475 - Internal corrosion control: General.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 49 Transportation 3 2010-10-01 2010-10-01 false Internal corrosion control: General. 192.475... TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.475 Internal corrosion control: General. (a) Corrosive gas may not be transported by...

49 CFR 192.475 - Internal corrosion control: General.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 49 Transportation 3 2011-10-01 2011-10-01 false Internal corrosion control: General. 192.475... TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.475 Internal corrosion control: General. (a) Corrosive gas may not be transported by...

49 CFR 192.477 - Internal corrosion control: Monitoring.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 49 Transportation 3 2011-10-01 2011-10-01 false Internal corrosion control: Monitoring. 192.477... TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.477 Internal corrosion control: Monitoring. If corrosive gas is being transported, coupons...

49 CFR 192.477 - Internal corrosion control: Monitoring.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 49 Transportation 3 2010-10-01 2010-10-01 false Internal corrosion control: Monitoring. 192.477... TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Requirements for Corrosion Control § 192.477 Internal corrosion control: Monitoring. If corrosive gas is being transported, coupons...

Internal combustion engine for natural gas compressor operation

DOEpatents

Hagen, Christopher L.; Babbitt, Guy; Turner, Christopher; Echter, Nick; Weyer-Geigel, Kristina

2016-04-19

This application concerns systems and methods for compressing natural gas with an internal combustion engine. In a representative embodiment, a system for compressing a gas comprises a reciprocating internal combustion engine including at least one piston-cylinder assembly comprising a piston configured to travel in a cylinder and to compress gas in the cylinder in multiple compression stages. The system can further comprise a first pressure tank in fluid communication with the piston-cylinder assembly to receive compressed gas from the piston-cylinder assembly until the first pressure tank reaches a predetermined pressure, and a second pressure tank in fluid communication with the piston-cylinder assembly and the first pressure tank. The second pressure tank can be configured to receive compressed gas from the piston-cylinder assembly until the second pressure tank reaches a predetermined pressure. When the first and second pressure tanks have reached the predetermined pressures, the first pressure tank can be configured to supply gas to the piston-cylinder assembly, and the piston can be configured to compress the gas supplied by the first pressure tank such that the compressed gas flows into the second pressure tank.

International comparison CCQM-K111—propane in nitrogen

NASA Astrophysics Data System (ADS)

van der Veen, Adriaan M. H.; Wouter van der Hout, J.; Ziel, Paul R.; Oudwater, Rutger J.; Fioravante, Andreia L.; Augusto, Cristiane R.; Coutinho Brum, Mariana; Uehara, Shinji; Akima, Dai; Bae, Hyun Kil; Kang, Namgoo; Woo, Jin-Chun; Liaskos, Christina E.; Rhoderick, George C.; Jozela, Mudalo; Tshilongo, James; Ntsasa, Napo G.; Botha, Angelique; Brewer, Paul J.; Brown, Andrew S.; Bartlett, Sam; Downey, Michael L.; Konopelko, L. A.; Kolobova, A. V.; Pankov, A. A.; Orshanskaya, A. A.; Efremova, O. V.

2017-01-01

This key comparison aims to assess the core capabilities of the participants in gas analysis. Such competences include, among others, the capabilities to prepare primary standard gas Mixtures (PSMs), perform the necessary purity analysis on the materials used in the gas mixture preparation, the verification of the composition of newly prepared PSMs against existing ones, and the capability of calibrating the composition of a gas mixture. According to the Strategy for Key Comparisons of the Gas Analysis Working Group, this key comparison is classified as a track A key comparison, which means that the results of this key comparison can be used to underpin calibration and measurement capabilities using the flexible scheme, and for propane under the default scheme. The artefacts were binary mixtures of propane in nitrogen at a nominal amount-of-substance fraction level of 1000 μmol/mol. The values and uncertainties from the gravimetric gas mixture preparation were used as key comparison reference values (KCRVs). Each transfer standard had its own KCRV. The results are generally good. All results but one are within +/- 0.2 % of the KCRV. Main text To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/. The final report has been peer-reviewed and approved for publication by the CCQM, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).

International comparison CCQM-K111.1—propane in nitrogen

NASA Astrophysics Data System (ADS)

van der Veen, Adriaan M. H.; Wouter van der Hout, J.; Ziel, Paul R.; Jozela, Mudalo; Tshilongo, James; Ntsasa, Napo G.; Botha, Angelique

2017-01-01

This key comparison aims to assess the core capabilities of the participants in gas analysis. Such competences include, among others, the capability of preparing Primary Standard gas Mixtures (PSMs), performing the necessary purity analysis on the materials used in the gas mixture preparation, the verification of the composition of newly prepared PSMs against existing ones, and the capability of calibrating the composition of a gas mixture. According to the Strategy for Key Comparisons of the Gas Analysis Working Group, this subsequent key comparison is classified as a track B key comparison, which means that the results of this key comparison can be used to underpin calibration and measurement capabilities for propane under the default scheme. The artefact was a binary mixture of propane in nitrogen at a nominal amount-of-substance fraction level of 1000 μmol/mol. The values and uncertainties from the gravimetric gas mixture preparation were used as key comparison reference values (KCRVs). Each transfer standard had its own KCRV. The result of the participating laboratory is consistent with the key comparison reference value within the respective expanded uncertainties and deviates less than 0.1 %. Main text To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/. The final report has been peer-reviewed and approved for publication by the CCQM, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).

SF6-alternative gases for application in gas-insulated switchgear

NASA Astrophysics Data System (ADS)

Li, Xingwen; Zhao, Hu; Murphy, Anthony B.

2018-04-01

The environmental problems caused by greenhouse gases have received unprecedented attention. Sulfur hexafluoride (SF6), which is the preferred gas for use in gas-insulated switchgear (circuit breakers, disconnect switches, etc. for high-voltage electrical circuits), has a very high global warming potential, and there is a large international effort to find alternative gases. Recently, this effort has made important progress, with promising alternative gases being identified and tested. An overview, in particular the current state of the art, of the study of SF6-alternative gases is presented in the paper. The review focuses on the application of the SF6-alternative gases in gas-insulated switchgear, with detailed analysis of calculations and measurements of their basic physical properties, dielectric strengths, and arc-quenching capabilities. Finally, a discussion of and perspectives on current research and future research directions are presented.

CRITERIA POLLUTANT EMISSIONS FROM INTERNAL COMBUSTION ENGINES IN THE NATURAL GAS INDUSTRY VOLUME II. APPENDICES A-I

EPA Science Inventory

The report summarizes emission factors for criteria pollutants (NOx, CO, CH4, C2H6, THC, NMHC, and NMEHC) from stationary internal combustion engines and gas turbines used in the natural gas industry. The emission factors were calculated from test results from five test campaigns...

CRITERIA POLLUTANT EMISSIONS FROM INTERNAL COMBUSTION ENGINES IN THE NATURAL GAS INDUSTRY VOLUME 1. TECHNICAL REPORT

EPA Science Inventory

The report summarizes emission factors for criteria pollutants (NOx, CO, CH4, C2H6, THC, NMHC, and NMEHC) from stationary internal combustion engines and gas turbines used in the natural gas industry. The emission factors were calculated from test results from five test campaigns...

Installation for the catalytic afterburning of exhaust gases of a multi-cylinder internal combustion engine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lange, K.

1974-04-24

An installation for the catalytic afterburning of exhaust gases of a multi-cylinder internal combustion engine has two cylinder rows with two exhaust gas lines, each of which includes at least one catalyst. A temperature-responsive control is operable during engine start-up to conduct substantially the entire exhaust gas flow from the internal combustion engine during warmup for a predetermined time by way of only one of the two catalyst and then, after a short period of time, to conduct the exhaust gas flow from each row of cylinders by way of its associated gas line and catalyst.

Internally-cooled centrifugal compressor with cooling jacket formed in the diaphragm

DOEpatents

Moore, James J.; Lerche, Andrew H.; Moreland, Brian S.

2014-08-26

An internally-cooled centrifugal compressor having a shaped casing and a diaphragm disposed within the shaped casing having a gas side and a coolant side so that heat from a gas flowing though the gas side is extracted via the coolant side. An impeller disposed within the diaphragm has a stage inlet on one side and a stage outlet for delivering a pressurized gas to a downstream connection. The coolant side of the diaphragm includes at least one passageway for directing a coolant in a substantially counter-flow direction from the flow of gas through the gas side.

IV INTERNATIONAL CONFERENCE ON ATOM AND MOLECULAR PULSED LASERS (AMPL'99): IV International Conference on Atomic and Molecular Pulsed Gas Lasers (AMPL'99)

NASA Astrophysics Data System (ADS)

Evtushenko, Gennadii S.; Kopylova, T. N.; Soldatov, A. N.; Tarasenko, Viktor F.; Yakovlenko, Sergei I.; Yancharina, A. M.

2000-06-01

A brief review of the most interesting papers presented at the IV International Conference on Atomic and Molecular Pulsed Gas Lasers (AMPL'99), which was held in Tomsk, September 13-17, 1999, is provided.

Performance Analysis of Wireless Networks for Industrial Automation-Process Automation (WIA-PA)

DTIC Science & Technology

2017-09-01

electrical, water and wastewater, oil and natural gas, chemical, transportation, pharmaceutical, pulp and paper, food and beverage, and discrete...scheduling method for isa100.11a,” in 2013 11th IEEE International Conference on Industrial Informatics (INDIN), 2013, pp. 649–654. [24] Y. Wei and D.-S

Radon in the DRIFT-II directional dark matter TPC: emanation, detection and mitigation

NASA Astrophysics Data System (ADS)

Battat, J. B. R.; Brack, J.; Daw, E.; Dorofeev, A.; Ezeribe, A. C.; Fox, J. R.; Gauvreau, J.-L.; Gold, M.; Harmon, L. J.; Harton, J. L.; Landers, J. M.; Lee, E. R.; Loomba, D.; Matthews, J. A. J.; Miller, E. H.; Monte, A.; Murphy, A. StJ.; Paling, S. M.; Phan, N.; Pipe, M.; Robinson, M.; Sadler, S. W.; Scarff, A.; Snowden-Ifft, D. P.; Spooner, N. J. C.; Telfer, S.; Walker, D.; Warner, D.; Yuriev, L.

2014-11-01

Radon gas emanating from materials is of interest in environmental science and also a major concern in rare event non-accelerator particle physics experiments such as dark matter and double beta decay searches, where it is a major source of background. Notable for dark matter experiments is the production of radon progeny recoils (RPRs), the low energy (~ 100 keV) recoils of radon daughter isotopes, which can mimic the signal expected from WIMP interactions. Presented here are results of measurements of radon emanation from detector materials in the 1 m3 DRIFT-II directional dark matter gas time projection chamber experiment. Construction and operation of a radon emanation facility for this work is described, along with an analysis to continuously monitor DRIFT data for the presence of internal 222Rn and 218Po. Applying this analysis to historical DRIFT data, we show how systematic substitution of detector materials for alternatives, selected by this device for low radon emanation, has resulted in a factor of ~ 10 reduction in internal radon rates. Levels are found to be consistent with the sum from separate radon emanation measurements of the internal materials and also with direct measurement using an attached alpha spectrometer. The current DRIFT detector, DRIFT-IId, is found to have sensitivity to 222Rn of 2.5 μBql-1 with current analysis efficiency, potentially opening up DRIFT technology as a new tool for sensitive radon assay of materials.

Fifth International Standard for Gas-Gangrene Antitoxin (Perfringens) (Clostridium welchii Type A Antitoxin)

PubMed Central

Evans, D. G.; Perkins, F. T.

1963-01-01

The Fifth International Standard Gas-Gangrene Antitoxin (Perfringens) (Clostridium welchii Type A Antitoxin) was prepared from serum from immunized horses. It was freeze-dried in ampoules each containing 1 ml. Seven laboratories collaborated in assaying its potency in terms of the Fourth International Standard by the intravenous inoculation of mice. The geometric mean value, taking the results of all the laboratories, was 270 International Units per ampoule and the maximum variation between laboratories was 15%. In vitro (lecithinase) tests were also done by three laboratories, giving an average of 261 International Units per ampoule. The dry weight contents of ampoules, determined in three laboratories, varied by less than 3%, with an average of 90.35 mg per ampoule. The standard was stable for 120 hours at 56°C. Each ampoule of the Fifth International Standard for Gas-Gangrene Antitoxin (Perfringens) contains 270 International Units, and one International Unit is contained in 0.3346 mg of the International Standard. PMID:14107745

Optical Multi-Gas Monitor Technology Demonstration on the International Space Station

NASA Technical Reports Server (NTRS)

Pilgrim, Jeffrey S.; Wood, William R.; Casias, Miguel E.; Vakhtin, Andrei B.; Johnson, Michael D.; Mudgett, Paul D.

2014-01-01

The International Space Station (ISS) employs a suite of portable and permanently located gas monitors to insure crew health and safety. These sensors are tasked with functions ranging from fixed mass spectrometer based major constituents analysis to portable electrochemical sensor based combustion product monitoring. An all optical multigas sensor is being developed that can provide the specificity of a mass spectrometer with the portability of an electrochemical cell. The technology, developed under the Small Business Innovation Research program, allows for an architecture that is rugged, compact and low power. A four gas version called the Multi-Gas Monitor was launched to ISS in November 2013 aboard Soyuz and activated in February 2014. The portable instrument is comprised of a major constituents analyzer (water vapor, carbon dioxide, oxygen) and high dynamic range real-time ammonia sensor. All species are sensed inside the same enhanced path length optical cell with a separate vertical cavity surface emitting laser (VCSEL) targeted at each species. The prototype is controlled digitally with a field-programmable gate array/microcontroller architecture. The optical and electronic approaches are designed for scalability and future versions could add three important acid gases and carbon monoxide combustion product gases to the four species already sensed. Results obtained to date from the technology demonstration on ISS are presented and discussed.

Leakage Currents and Gas Generation in Advanced Wet Tantalum Capacitors

NASA Technical Reports Server (NTRS)

Teverovsky, Alexander

2015-01-01

Currently, military grade, established reliability wet tantalum capacitors are among the most reliable parts used for space applications. This has been achieved over the years by extensive testing and improvements in design and materials. However, a rapid insertion of new types of advanced, high volumetric efficiency capacitors in space systems without proper testing and analysis of degradation mechanisms might increase risks of failures. The specifics of leakage currents in wet electrolytic capacitors is that the conduction process is associated with electrolysis of electrolyte and gas generation resulting in building up of internal gas pressure in the parts. The risk associated with excessive leakage currents and increased pressure is greater for high value advanced wet tantalum capacitors, but it has not been properly evaluated yet. In this work, in Part I, leakages currents in various types of tantalum capacitors have been analyzed in a wide range of voltages, temperatures, and time under bias. Gas generation and the level of internal pressure have been calculated in Part II for different case sizes and different hermeticity leak rates to assess maximal allowable leakage currents. Effects related to electrolyte penetration to the glass seal area have been studied and the possibility of failures analyzed in Part III. Recommendations for screening and qualification to reduce risks of failures have been suggested.

Modeling the Effects of Spacecraft Venting on Instrument Measurements of the Martian Atmosphere for an Elliptical Orbit

NASA Technical Reports Server (NTRS)

Petro, Elaine; Hughes, David

2011-01-01

Analysis has been performed for MAVEN mission. Due to the elliptical orbit, large pressure variations in orbit will be experienced, there is a need to understand how internal pressures change and the flux of gas from vents could potentially bias instrument measurements. Goal of this analysis is to predict the effect that atmospheric gases trapped and vented from spacecraft volumes could have on instrument measurements.

Desertification of the peritoneum by thin-film evaporation during laparoscopy.

PubMed

Ott, Douglas E

2003-01-01

To assess the effects of gas flow during insufflation on peritoneal fluid and peritoneal tissue regarding transient thermal behavior and thin-film evaporation. The effects of laparoscopic gas on peritoneal cell desiccation and peritoneal fluid thin-film evaporation were analyzed. Measurment of tissue and peritoneal fluid and analysis of gas flow dynamics during laparoscopy. High-velocity gas interface conditions during laparoscopic gas insufflation result in peritoneal surface temperature and decreases up to 20 degrees C/second due to rapid thin-film evaporation of the peritoneal fluid. Evaporation of the thin film of peritoneal fluid extends quickly to the peritoneal cell membrane, causing peritoneal cell desiccation, internal cytoplasmic stress, and disruption of the cell membrane, resulting in loss of peritoneal surface continuity and integrity. Changing the gas conditions to 35 degrees C and 95% humidity maintains normal peritoneal fluid thin-film characteristics, cellular integrity, and prevents evaporative losses. Cold, dry gas and the characteristics of the laparoscopic gas delivery apparatus cause local peritoneal damaging alterations by high-velocity gas flow with extremely dry gas, creating extreme arid surface conditions, rapid evaporative and hydrological changes, tissue desiccation, and peritoneal fluid alterations that contribute to the process of desertification and thin-film evaporation. Peritoneal desertification is preventable by preconditioning the gas to 35 degrees C and 95% humidity.

International Natural Gas Model 2011, Model Documentation Report

EIA Publications

2013-01-01

This report documents the objectives, analytical approach and development of the International Natural Gas Model (INGM). It also catalogues and describes critical assumptions, computational methodology, parameter estimation techniques, and model source code.

76 FR 2917 - Notice of Cancellation of Public Meeting on the International Maritime Organization Guidelines...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-01-18

... Public Meeting on the International Maritime Organization Guidelines for Exhaust Gas Cleaning Systems for... that a public meeting on the International Maritime Organization guidelines for exhaust gas cleaning..., 2011. F.J. Strum, Acting Director of Commercial Regulations and Standards. [FR Doc. 2011-1024 Filed 1...

Putting 'international' back in IPEC.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Veil, J. A.

During the previous six annual sessions of the International Petroleum Environmental Conference (IPEC), little attention has been given to international issues. Although the US is clearly a leader in oil field research and regulatory development information is available on interesting projects throughout the world Many participants in IPEC have little exposure to international oil and gas environmental problems and solutions. Beginning with the 7th IPEC, a stronger effort is being made to include international issues in the confidence. This paper describes some of the author's experiences in working with international oil and gas environmental issues in North America, Latin America,more » Europe, and Asia. Among the topics to be discussed are the issues that developing oil and gas-producing nations face and the need for sensitivity to other nation's cultures and legal systems.« less

Analytical Modelling of the Effects of Different Gas Turbine Cooling Techniques on Engine Performance =

NASA Astrophysics Data System (ADS)

Uysal, Selcuk Can

In this research, MATLAB SimulinkRTM was used to develop a cooled engine model for industrial gas turbines and aero-engines. The model consists of uncooled on-design, mean-line turbomachinery design and a cooled off-design analysis in order to evaluate the engine performance parameters by using operating conditions, polytropic efficiencies, material information and cooling system details. The cooling analysis algorithm involves a 2nd law analysis to calculate losses from the cooling technique applied. The model is used in a sensitivity analysis that evaluates the impacts of variations in metal Biot number, thermal barrier coating Biot number, film cooling effectiveness, internal cooling effectiveness and maximum allowable blade temperature on main engine performance parameters of aero and industrial gas turbine engines. The model is subsequently used to analyze the relative performance impact of employing Anti-Vortex Film Cooling holes (AVH) by means of data obtained for these holes by Detached Eddy Simulation-CFD Techniques that are valid for engine-like turbulence intensity conditions. Cooled blade configurations with AVH and other different external cooling techniques were used in a performance comparison study. (Abstract shortened by ProQuest.).

Internal reforming of methane in solid oxide fuel cell systems

NASA Astrophysics Data System (ADS)

Peters, R.; Dahl, R.; Klüttgen, U.; Palm, C.; Stolten, D.

Internal reforming is an attractive option offering a significant cost reduction, higher efficiencies and faster load response of a solid oxide fuel cell (SOFC) power plant. However, complete internal reforming may lead to several problems which can be avoided with partial pre-reforming of natural gas. In order to achieve high total plant efficiency associated with low energy consumption and low investment costs, a process concept has been developed based on all the components of the SOFC system. In the case of anode gas recycling an internal steam circuit exists. This has the advantage that there is no need for an external steam generator and the steam concentration in the anode gas is reduced. However, anode gas recycling has to be proven by experiments in a pre-reformer and for internal reforming. The addition of carbon dioxide clearly shows a decrease in catalyst activity, while for temperatures higher than 1000 K hydrogen leads to an increase of the measured methane conversion rates.

Validity and reliability assessment of the Brazilian version of the game addiction scale (GAS).

PubMed

Lemos, Igor Lins; Cardoso, Adriana; Sougey, Everton Botelho

2016-05-01

The uncontrolled use of video games can be addictive. The Game Addiction Scale (GAS) is an instrument that was developed to assess this type of addiction. The GAS consists of 21 items that are divided into the following seven factors: salience, tolerance, mood modification, relapse, withdrawal, conflict and problems. This study assessed the convergent validity and reliability of the GAS according to measures of internal consistency and test-retest stability. Three hundred and eighty four students completed the GAS, the Internet Addiction Test (IAT), the Liebowitz Social Anxiety Scale (LSAS), the Beck Depression Inventory (BDI) and the Video Game Addiction Test (VAT). A subgroup of the participants (n=76) completed the GAS again after 30days to determine test-retest stability. The GAS demonstrated excellent internal consistency (Cronbach's alpha=0.92), was highly correlated with the VAT (r=0.883) and was moderately correlated with the BDI (r=0.358), the LSAS (r=0.326) and the IAT (r=0.454). In the Brazilian Portuguese population, the GAS shows good internal consistency. These data indicate that the GAS can be used to assess video game addiction due to its demonstrated psychometric validity. Copyright © 2016 Elsevier Inc. All rights reserved.

Laboratory- and Field-Based Assessment of Maximal Aerobic Power of Elite Stand-Up Paddle-Board Athletes.

PubMed

Schram, Ben; Hing, Wayne; Climstein, Mike

2016-01-01

Stand-up paddle boarding (SUP) is a rapidly growing sport and recreational activity for which only anecdotal evidence exists on its proposed health, fitness, and injury-rehabilitation benefits. 10 internationally and nationally ranked elite SUP athletes. Participants were assessed for their maximal aerobic power on an ergometer in a laboratory and compared with other water-based athletes. Field-based assessments were subsequently performed using a portable gas-analysis system, and a correlation between the 2 measures was performed. Maximal aerobic power (relative) was significantly higher (P = .037) when measured in the field with a portable gas-analysis system (45.48 ± 6.96 mL · kg(-1) · min(-1)) than with laboratory-based metabolic-cart measurements (43.20 ± 6.67 mL · kg(-1) · min(-1)). There was a strong, positive correlation (r = .907) between laboratory and field maximal aerobic power results. Significantly higher (P = .000) measures of SUP paddling speed were found in the field than with the laboratory ergometer (+42.39%). There were no significant differences in maximal heart rate between the laboratory and field settings (P = .576). The results demonstrate the maximal aerobic power representative of internationally and nationally ranked SUP athletes and show that SUP athletes can be assessed for maximal aerobic power in the laboratory with high correlation to field-based measures. The field-based portable gas-analysis unit has a tendency to consistently measure higher oxygen consumption. Elite SUP athletes display aerobic power outputs similar to those of other upper-limb-dominant elite water-based athletes (surfing, dragon-boat racing, and canoeing).

Diagnostic techniques and treatments for internal disorders of Koi (Cyprinus carpio).

PubMed

Saint-Erne, Nicholas

2010-09-01

The most common problems that occur in koi involve external pathogens and environmental conditions. Techniques for external fish examination and water quality analysis have been well described in the veterinary literature. However, there are also some internal disorders of koi, such as gas bladder abnormalities affecting the fish's buoyancy, neoplasia, egg binding (roe retention), and spinal disorders that can be diagnosed with common veterinary medical procedures. Diagnostic techniques along with available treatments for these disorders are presented in this article. Copyright 2010 Elsevier Inc. All rights reserved.

Stratospheric Aerosol and Gas Experiment III on the International Space Station (SAGE III/ISS)

NASA Technical Reports Server (NTRS)

Gasbarre, Joseph; Walker, Richard; Cisewski, Michael; Zawodny, Joseph; Cheek, Dianne; Thornton, Brooke

2015-01-01

The Stratospheric Aerosol and Gas Experiment III on the International Space Station (SAGE III/ISS) mission will extend the SAGE data record from the ideal vantage point of the International Space Station (ISS). The ISS orbital inclination is ideal for SAGE measurements providing coverage between 70 deg north and 70 deg south latitude. The SAGE data record includes an extensively validated data set including aerosol optical depth data dating to the Stratospheric Aerosol Measurement (SAM) experiments in 1975 and 1978 and stratospheric ozone profile data dating to the Stratospheric Aerosol and Gas Experiment (SAGE) in 1979. These and subsequent data records, notably from the SAGE II experiment launched on the Earth Radiation Budget Satellite in 1984 and the SAGE III experiment launched on the Russian Meteor-3M satellite in 2001, have supported a robust, long-term assessment of key atmospheric constituents. These scientific measurements provide the basis for the analysis of five of the nine critical constituents (aerosols, ozone (O3), nitrogen dioxide (NO2), water vapor (H2O), and air density using O2) identified in the U.S. National Plan for Stratospheric Monitoring. SAGE III on ISS was originally scheduled to fly on the ISS in the same timeframe as the Meteor-3M mission, but was postponed due to delays in ISS construction. The project was re-established in 2009.

Rotationally inelastic collisions of H2+ ions with He buffer gas: Computing cross sections and rates

NASA Astrophysics Data System (ADS)

Hernández Vera, Mario; Gianturco, F. A.; Wester, R.; da Silva, H.; Dulieu, O.; Schiller, S.

2017-03-01

We present quantum calculations for the inelastic collisions between H2+ molecules, in rotationally excited internal states, and He atoms. This work is motivated by the possibility of experiments in which the molecular ions are stored and translationally cooled in an ion trap and a He buffer gas is added for deactivation of the internal rotational population, in particular at low (cryogenic) translational temperatures. We carry out an accurate representation of the forces at play from an ab initio description of the relevant potential energy surface, with the molecular ion in its ground vibrational state, and obtain the cross sections for state-changing rotationally inelastic collisions by solving the coupled channel quantum scattering equations. The presence of hyperfine and fine structure effects in both ortho- and para-H2+ molecules is investigated and compared to the results where such a contribution is disregarded. An analysis of possible propensity rules that may predict the relative probabilities of inelastic events involving rotational state-changing is also carried out, together with the corresponding elastic cross sections from several initial rotational states. Temperature-dependent rotationally inelastic rates are then computed and discussed in terms of relative state-changing collisional efficiency under trap conditions. The results provide the essential input data for modeling different aspects of the experimental setups which can finally produce internally cold molecular ions interacting with a buffer gas.

Flammability Analysis For Actinide Oxides Packaged In 9975 Shipping Containers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Laurinat, James E.; Askew, Neal M.; Hensel, Steve J.

2013-03-21

Packaging options are evaluated for compliance with safety requirements for shipment of mixed actinide oxides packaged in a 9975 Primary Containment Vessel (PCV). Radiolytic gas generation rates, PCV internal gas pressures, and shipping windows (times to reach unacceptable gas compositions or pressures after closure of the PCV) are calculated for shipment of a 9975 PCV containing a plastic bottle filled with plutonium and uranium oxides with a selected isotopic composition. G-values for radiolytic hydrogen generation from adsorbed moisture are estimated from the results of gas generation tests for plutonium oxide and uranium oxide doped with curium-244. The radiolytic generation ofmore » hydrogen from the plastic bottle is calculated using a geometric model for alpha particle deposition in the bottle wall. The temperature of the PCV during shipment is estimated from the results of finite element heat transfer analyses.« less

Increase in the thermodynamic efficiency of the working process of spark-ignited engines on natural gas with the addition of hydrogen

NASA Astrophysics Data System (ADS)

Mikhailovna Smolenskaya, Natalia; Vladimirovich Smolenskii, Victor; Vladimirovich Korneev, Nicholas

2018-02-01

The work is devoted to the substantiation and practical implementation of a new approach for estimating the change in internal energy by pressure and volume. The pressure is measured with a calibrated sensor. The change in volume inside the cylinder is determined by changing the position of the piston. The position of the piston is precisely determined by the angle of rotation of the crankshaft. On the basis of the proposed approach, the thermodynamic efficiency of the working process of spark ignition engines on natural gas with the addition of hydrogen was estimated. Experimental studies were carried out on a single-cylinder unit UIT-85. Their analysis showed an increase in the thermodynamic efficiency of the working process with the addition of hydrogen in a compressed natural gas (CNG).The results obtained make it possible to determine the characteristic of heat release from the analysis of experimental data. The effect of hydrogen addition on the CNG combustion process is estimated.

Formulation of US international energy policies

NASA Astrophysics Data System (ADS)

1980-09-01

To find out how the United States develops international energy policy, GAO reviewed five major energy issues covering the period from early 1977 through 1979. The issues are: vulnerabilities to petroleum supply interruptions; long term national security strategy on imported oil prices; export of U.S. oil and gas production equipment and technology to the Soviety Union; World Bank initiatives to assist in financing oil and gas exploration and development in oil-importing developing countries; and the role of gas imports relative to the nation's future sources of gas.

Review of codes, standards, and regulations for natural gas locomotives.

DOT National Transportation Integrated Search

2014-06-01

This report identified, collected, and summarized relevant international codes, standards, and regulations with potential : applicability to the use of natural gas as a locomotive fuel. Few international or country-specific codes, standards, and regu...

Entropy Generation/Availability Energy Loss Analysis Inside MIT Gas Spring and "Two Space" Test Rigs

NASA Technical Reports Server (NTRS)

Ebiana, Asuquo B.; Savadekar, Rupesh T.; Patel, Kaushal V.

2006-01-01

The results of the entropy generation and availability energy loss analysis under conditions of oscillating pressure and oscillating helium gas flow in two Massachusetts Institute of Technology (MIT) test rigs piston-cylinder and piston-cylinder-heat exchanger are presented. Two solution domains, the gas spring (single-space) in the piston-cylinder test rig and the gas spring + heat exchanger (two-space) in the piston-cylinder-heat exchanger test rig are of interest. Sage and CFD-ACE+ commercial numerical codes are used to obtain 1-D and 2-D computer models, respectively, of each of the two solution domains and to simulate the oscillating gas flow and heat transfer effects in these domains. Second law analysis is used to characterize the entropy generation and availability energy losses inside the two solution domains. Internal and external entropy generation and availability energy loss results predicted by Sage and CFD-ACE+ are compared. Thermodynamic loss analysis of simple systems such as the MIT test rigs are often useful to understand some important features of complex pattern forming processes in more complex systems like the Stirling engine. This study is aimed at improving numerical codes for the prediction of thermodynamic losses via the development of a loss post-processor. The incorporation of loss post-processors in Stirling engine numerical codes will facilitate Stirling engine performance optimization. Loss analysis using entropy-generation rates due to heat and fluid flow is a relatively new technique for assessing component performance. It offers a deep insight into the flow phenomena, allows a more exact calculation of losses than is possible with traditional means involving the application of loss correlations and provides an effective tool for improving component and overall system performance.

Performance analysis and optimization of power plants with gas turbines

NASA Astrophysics Data System (ADS)

Besharati-Givi, Maryam

The gas turbine is one of the most important applications for power generation. The purpose of this research is performance analysis and optimization of power plants by using different design systems at different operation conditions. In this research, accurate efficiency calculation and finding optimum values of efficiency for design of chiller inlet cooling and blade cooled gas turbine are investigated. This research shows how it is possible to find the optimum design for different operation conditions, like ambient temperature, relative humidity, turbine inlet temperature, and compressor pressure ratio. The simulated designs include the chiller, with varied COP and fogging cooling for a compressor. In addition, the overall thermal efficiency is improved by adding some design systems like reheat and regenerative heating. The other goal of this research focuses on the blade-cooled gas turbine for higher turbine inlet temperature, and consequently, higher efficiency. New film cooling equations, along with changing film cooling effectiveness for optimum cooling air requirement at the first-stage blades, and an internal and trailing edge cooling for the second stage, are innovated for optimal efficiency calculation. This research sets the groundwork for using the optimum value of efficiency calculation, while using inlet cooling and blade cooling designs. In the final step, the designed systems in the gas cycles are combined with a steam cycle for performance improvement.

Internship at Los Alamos National Laboratory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dunham, Ryan Q.

2012-07-11

Los Alamos National Laboratory (LANL) is located in Los Alamos, New Mexico. It provides support for our country's nuclear weapon stockpile as well as many other scientific research projects. I am an Undergraduate Student Intern in the Systems Design and Analysis group within the Nuclear Nonproliferation division of the Global Security directorate at LANL. I have been tasked with data analysis and modeling of particles in a fluidized bed system for the capture of carbon dioxide from power plant flue gas.

A Probabilistic Finite Element Analysis of Residual Stress Formation in Shrink-Fit Ceramic/Steel Gun Barrels

DTIC Science & Technology

2002-01-01

the present work, the Advanced Mean Value method developed by Millwater and co-workers is used [6-10]. II.1.1 Advanced Mean-Value Method The...Engineering A, submitted for publication, December, , 2001. 6. H. R. Millwater and Y.-T. Wu, “Computational Structural Reliability Analysis of a...Turbine Blade,” Proceedings International Gas Turbine and Aeroengine Congress and Exposition, Cincinnati, OH, May 24-27, 1993. 7. Millwater , H.R., Y

Valid internal standard technique for arson detection based on gas chromatography-mass spectrometry.

PubMed

Salgueiro, Pedro A S; Borges, Carlos M F; Bettencourt da Silva, Ricardo J N

2012-09-28

The most popular procedures for the detection of residues of accelerants in fire debris are the ones published by the American Society for Testing and Materials (ASTM E1412-07 and E1618-10). The most critical stages of these tests are the conservation of fire debris from the sampling to the laboratory, the extraction of residues of accelerants from the debris to the activated charcoal strips (ACS) and from those to the final solvent, as well as the analysis of sample extract by gas chromatography-mass spectrometry (GC-MS) and the interpretation of the instrumental signal. This work proposes a strategy for checking the quality of the sample conservation, the accelerant residues transference to final solvent and GC-MS analysis, using internal standard additions. It is used internal standards ranging from a highly volatile compound for checking debris conservation to low volatile compound for checking GC-MS repeatability. The developed quality control (QC) parameters are not affected by GC-MS sensitivity variation and, specifically, the GC-MS performance control is not affected by ACS adsorption saturation that may mask test performance deviations. The proposed QC procedure proved to be adequate to check GC-MS repeatability, ACS extraction and sample conservation since: (1) standard additions are affected by negligible uncertainty and (2) observed dispersion of QC parameters are fit for its intended use. Copyright © 2012 Elsevier B.V. All rights reserved.

Optical Multi-Gas Monitor Technology Demonstration on the International Space Station

NASA Technical Reports Server (NTRS)

Pilgrim, Jeffrey S.; Wood, William R.; Casias, Miguel E.; Vakhtin, Andrei B,; Johnson, Michael D.; Mudgett, Paul D.

2014-01-01

There are a variety of both portable and fixed gas monitors onboard the International Space Station (ISS). Devices range from rack-mounted mass spectrometers to hand-held electrochemical sensors. An optical Multi-Gas Monitor has been developed as an ISS Technology Demonstration to evaluate long-term continuous measurement of 4 gases. Based on tunable diode laser spectroscopy, this technology offers unprecedented selectivity, concentration range, precision, and calibration stability. The monitor utilizes the combination of high performance laser absorption spectroscopy with a rugged optical path length enhancement cell that is nearly impossible to misalign. The enhancement cell serves simultaneously as the measurement sampling cell for multiple laser channels operating within a common measurement volume. Four laser diode based detection channels allow quantitative determination of ISS cabin concentrations of water vapor (humidity), carbon dioxide, ammonia and oxygen. Each channel utilizes a separate vertical cavity surface emitting laser (VCSEL) at a different wavelength. In addition to measuring major air constituents in their relevant ranges, the multiple gas monitor provides real time quantitative gaseous ammonia measurements between 5 and 20,000 parts-per-million (ppm). A small ventilation fan draws air with no pumps or valves into the enclosure in which analysis occurs. Power draw is only about 3 W from USB sources when installed in Nanoracks or when connected to 28V source from any EXPRESS rack interface. Internal battery power can run the sensor for over 20 hours during portable operation. The sensor is controlled digitally with an FPGA/microcontroller architecture that stores data internally while displaying running average measurements on an LCD screen and interfacing with the rack or laptop via USB. Design, construction and certification of the Multi-Gas Monitor were a joint effort between Vista Photonics, Nanoracks and NASA-Johnson Space Center (JSC). Vista Photonics developed the core technology and built the sensor. Nanoracks designed, constructed the enclosure, interfaces, and battery power management circuitry, integrated all subsystems into the enclosure, and then managed the certification tests, documentation and manifesting. The unit was calibrated in the JSC Toxicology Laboratory. The Multi-Gas Monitor is manifested to fly as a technology demonstration to the ISS in November 2013 and will operate for at least 6 months with data sent to the ground for evaluation. The primary goal is to demonstrate long term interference free operation in the real spacecraft environment.

Amplitude versus offset analysis to marine seismic data acquired in Nankai Trough, offshore Japan where methane hydrate exists

NASA Astrophysics Data System (ADS)

Hato, M.; Inamori, T.; Matsuoka, T.; Shimizu, S.

2003-04-01

Occurrence of methane hydrates in the Nankai Trough, located off the south-eastern coast of Japan, was confirmed by the exploratory test well drilling conducted by Japan’s Ministry of International Trade and Industry in 1999. Confirmation of methane hydrate has given so big impact to the Japan's future energy strategy and scientific and technological interest was derived from the information of the coring and logging results at the well. Following the above results, Japan National Oil Corporation (JNOC) launched the national project, named as MH21, for establishing the technology of methane hydrate exploration and related technologies such as production and development. As one of the research project for evaluating the total amount of the methane hydrate, Amplitude versus Offset (AVO) was applied to the seismic data acquired in the Nankai Trough area. The main purpose of the AVO application is to evaluate the validity of delineation of methane hydrate-bearing zones. Since methane hydrate is thought to accompany with free-gas in general just below the methane hydrate-bearing zones, the AVO has a possibility of describing the presence of free-gas. The free-gas is thought to be located just below the base of methane hydrate stability zone which is characterized by the Bottom Simulating Reflectors (BSRs) on the seismic section. In this sense, AVO technology, which was developed as gas delineation tools, can be utilized for methane hydrate exploration. The result of AVO analysis clearly shows gas-related anomaly below the BSRs. Appearance of the AVO anomaly has so wide variety. Some of the anomalies might not correspond to the free-gas existence, however, some of them may show free-gas. We are now going to develop methodology to clearly discriminate free-gas from non-gas zone by integrating various types of seismic methods such as seismic inversion and seismic attribute analysis.

CHAP-2 heat-transfer analysis of the Fort St. Vrain reactor core

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kotas, J.F.; Stroh, K.R.

1983-01-01

The Los Alamos National Laboratory is developing the Composite High-Temperature Gas-Cooled Reactor Analysis Program (CHAP) to provide advanced best-estimate predictions of postulated accidents in gas-cooled reactor plants. The CHAP-2 reactor-core model uses the finite-element method to initialize a two-dimensional temperature map of the Fort St. Vrain (FSV) core and its top and bottom reflectors. The code generates a finite-element mesh, initializes noding and boundary conditions, and solves the nonlinear Laplace heat equation using temperature-dependent thermal conductivities, variable coolant-channel-convection heat-transfer coefficients, and specified internal fuel and moderator heat-generation rates. This paper discusses this method and analyzes an FSV reactor-core accident thatmore » simulates a control-rod withdrawal at full power.« less

Visibility graph network analysis of natural gas price: The case of North American market

NASA Astrophysics Data System (ADS)

Sun, Mei; Wang, Yaqi; Gao, Cuixia

2016-11-01

Fluctuations in prices of natural gas significantly affect global economy. Therefore, the research on the characteristics of natural gas price fluctuations, turning points and its influencing cycle on the subsequent price series is of great significance. Global natural gas trade concentrates on three regional markets: the North American market, the European market and the Asia-Pacific market, with North America having the most developed natural gas financial market. In addition, perfect legal supervision and coordinated regulations make the North American market more open and more competitive. This paper focuses on the North American natural gas market specifically. The Henry Hub natural gas spot price time series is converted to a visibility graph network which provides a new direction for macro analysis of time series, and several indicators are investigated: degree and degree distribution, the average shortest path length and community structure. The internal mechanisms underlying price fluctuations are explored through the indicators. The results show that the natural gas prices visibility graph network (NGP-VGN) is of small-world and scale-free properties simultaneously. After random rearrangement of original price time series, the degree distribution of network becomes exponential distribution, different from the original ones. This means that, the original price time series is of long-range negative correlation fractal characteristic. In addition, nodes with large degree correspond to significant geopolitical or economic events. Communities correspond to time cycles in visibility graph network. The cycles of time series and the impact scope of hubs can be found by community structure partition.

Lab-In-Syringe automation of stirring-assisted room-temperature headspace extraction coupled online to gas chromatography with flame ionization detection for determination of benzene, toluene, ethylbenzene, and xylenes in surface waters.

PubMed

Horstkotte, Burkhard; Lopez de Los Mozos Atochero, Natalia; Solich, Petr

2018-06-22

Online coupling of Lab-In-Syringe automated headspace extraction to gas chromatography has been studied. The developed methodology was successfully applied to surface water analysis using benzene, toluene, ethylbenzene, and xylenes as model analytes. The extraction system consisted of an automatic syringe pump with a 5 mL syringe into which all solutions and air for headspace formation were aspirated. The syringe piston featured a longitudinal channel, which allowed connecting the syringe void directly to a gas chromatograph with flame ionization detector via a transfer capillary. Gas injection was achieved via opening a computer-controlled pinch valve and compressing the headspace, upon which separation was initialized. Extractions were performed at room temperature; yet sensitivity comparable to previous work was obtained by high headspace to sample ratio V HS /V Sample of 1.6:1 and injection of about 77% of the headspace. Assistance by in-syringe magnetic stirring yielded an about threefold increase in extraction efficiency. Interferences were compensated by using chlorobenzene as an internal standard. Syringe cleaning and extraction lasting over 10 min was carried out in parallel to the chromatographic run enabling a time of analysis of <19 min. Excellent peak area repeatabilities with RSD of <4% when omitting and <2% RSD when using internal standard corrections on 100 μg L -1 level were achieved. An average recovery of 97.7% and limit of detection of 1-2 μg L -1 were obtained in analyses of surface water. Copyright © 2018 Elsevier B.V. All rights reserved.

Coherence between internal and external noise generated by gas turbine combustors

NASA Technical Reports Server (NTRS)

Strahle, W. C.; Muthukrishnan, M.; Neale, D. H.

1977-01-01

Experiments and analysis on a gas turbine combustor unit are reported with a view in mind to separate propagated acoustic power from non-propagating 'pseudo-sound'. Analytically, it is suggested that a transition frequency will exist below which the interior pressure fluctuations are non-propagating, whereas above this frequency, of the order of 100 Hz, the noise is dominated by propagating acoustic waves. Coherence measurements are reported which show this concept to be borne out experimentally. Coherence between interior and exterior microphones is measured over a wide range of experimental conditions for a gas turbine combustor exhausting directly to the atmosphere. The purpose is to show that below a certain frequency, measurements of interior noise are not indicative of combustion noise ultimately propagating from an engine.

Analysis of fragrance compounds in blood samples of mice by gas chromatography, mass spectrometry, GC/FTIR and GC/AES after inhalation of sandalwood oil.

PubMed

Jirovetz, L; Buchbauer, G; Jäger, W; Woidich, A; Nikiforov, A

1992-01-01

After inhalation experiments with sandalwood oil and the pure fragrance compounds coumarin and alpha-terpineol, substances were detected and measured in the blood samples of test animals (mice) using gas chromatography/mass spectrometry (GC/MS) (MID) in connection with GC/FTIR (SWC), GC/AES (carbon and oxygen trace) and flame ionization detection/gas chromatography. Using tiglinic acid benzyl ester as the internal standard the following concentrations in serum could be found: alpha-santalol 6.1 ng/mL, beta-santalol 5.3 ng/mL and alpha-santalene 0.5 ng/mL. In separate inhalation experiments with coumarin and with alpha-terpineol the corresponding concentrations were 7.7 ng/mL and 6.9 ng/mL, respectively.

Plasma polymerization of an ethylene-nitrogen gas mixture

NASA Technical Reports Server (NTRS)

Hudis, M.; Wydeven, T.

1975-01-01

A procedure has been developed whereby nitrogen can be incorporated into an organic film from an ethylene-nitrogen gas mixture using an internal electrode capacitively coupled radio frequency reactor. The presence of nitrogen has been shown directly by infrared transmittance spectra and electron spectroscopic chemical analysis data, and further indirect evidence was provided by dielectric measurements and by the reverse osmosis properties of the film. Preparation of a nitrogen containing film did not require vapor from an organic nitrogen containing liquid monomer. Some control over the bonding and stoichiometry of the polymer film was provided by the added degree of freedom of the nitrogen partial pressure in the gas mixture. This new parameter strongly affected the dielectric properties of the plasma polymerized film and could affect the reverse osmosis behavior.

Modeling internal ballistics of gas combustion guns.

PubMed

Schorge, Volker; Grossjohann, Rico; Schönekess, Holger C; Herbst, Jörg; Bockholdt, Britta; Ekkernkamp, Axel; Frank, Matthias

2016-05-01

Potato guns are popular homemade guns which work on the principle of gas combustion. They are usually constructed for recreational rather than criminal purposes. Yet some serious injuries and fatalities due to these guns are reported. As information on the internal ballistics of homemade gas combustion-powered guns is scarce, it is the aim of this work to provide an experimental model of the internal ballistics of these devices and to investigate their basic physical parameters. A gas combustion gun was constructed with a steel tube as the main component. Gas/air mixtures of acetylene, hydrogen, and ethylene were used as propellants for discharging a 46-mm caliber test projectile. Gas pressure in the combustion chamber was captured with a piezoelectric pressure sensor. Projectile velocity was measured with a ballistic speed measurement system. The maximum gas pressure, the maximum rate of pressure rise, the time parameters of the pressure curve, and the velocity and path of the projectile through the barrel as a function of time were determined according to the pressure-time curve. The maximum gas pressure was measured to be between 1.4 bar (ethylene) and 4.5 bar (acetylene). The highest maximum rate of pressure rise was determined for hydrogen at (dp/dt)max = 607 bar/s. The muzzle energy was calculated to be between 67 J (ethylene) and 204 J (acetylene). To conclude, this work provides basic information on the internal ballistics of homemade gas combustion guns. The risk of injury to the operator or bystanders is high, because accidental explosions of the gun due to the high-pressure rise during combustion of the gas/air mixture may occur.

Diesel Engine With Air Boosted Turbocharger

DTIC Science & Technology

2010-05-26

of the exhaust turbocharger over the entire RPM range of the internal combustion engine . To this end, the...Kriegler, discloses that in order to utilize recycling of exhaust gases at high engine loads in an internal- combustion engine with an exhaust gas...October 29, 2002) to Cook, discloses an apparatus for and method of exhaust gas recirculation in an internal combustion engine that operates

Hybrid life-cycle assessment of natural gas based fuel chains for transportation.

PubMed

Strømman, Anders Hammer; Solli, Christian; Hertwich, Edgar G

2006-04-15

This research compares the use of natural gas, methanol, and hydrogen as transportation fuels. These three fuel chains start with the extraction and processing of natural gas in the Norwegian North Sea and end with final use in Central Europe. The end use is passenger transportation with a sub-compact car that has an internal combustion engine for the natural gas case and a fuel cell for the methanol and hydrogen cases. The life cycle assessment is performed by combining a process based life-cycle inventory with economic input-output data. The analysis shows that the potential climate impacts are lowest for the hydrogen fuel scenario with CO2 deposition. The hydrogen fuel chain scenario has no significant environmental disadvantage compared to the other fuel chains. Detailed analysis shows that the construction of the car contributes significantly to most impact categories. Finally, it is shown how the application of a hybrid inventory model ensures a more complete inventory description compared to standard process-based life-cycle assessment. This is particularly significant for car construction which would have been significantly underestimated in this study using standard process life-cycle assessment alone.

Electrochemical and Infrared Absorption Spectroscopy Detection of SF₆ Decomposition Products.

PubMed

Dong, Ming; Zhang, Chongxing; Ren, Ming; Albarracín, Ricardo; Ye, Rixin

2017-11-15

Sulfur hexafluoride (SF₆) gas-insulated electrical equipment is widely used in high-voltage (HV) and extra-high-voltage (EHV) power systems. Partial discharge (PD) and local heating can occur in the electrical equipment because of insulation faults, which results in SF₆ decomposition and ultimately generates several types of decomposition products. These SF₆ decomposition products can be qualitatively and quantitatively detected with relevant detection methods, and such detection contributes to diagnosing the internal faults and evaluating the security risks of the equipment. At present, multiple detection methods exist for analyzing the SF₆ decomposition products, and electrochemical sensing (ES) and infrared (IR) spectroscopy are well suited for application in online detection. In this study, the combination of ES with IR spectroscopy is used to detect SF₆ gas decomposition. First, the characteristics of these two detection methods are studied, and the data analysis matrix is established. Then, a qualitative and quantitative analysis ES-IR model is established by adopting a two-step approach. A SF₆ decomposition detector is designed and manufactured by combining an electrochemical sensor and IR spectroscopy technology. The detector is used to detect SF₆ gas decomposition and is verified to reliably and accurately detect the gas components and concentrations.

A Study on the Characteristics of Design Variables for IRSS Diffuser

NASA Astrophysics Data System (ADS)

Cho, Yong-Jin; Ko, Dae-Eun

2017-11-01

In modern naval ships, infrared signature suppression systems (IRSS) are installed to decrease the temperature of waste gas generated in propulsion engine and the metallic surface temperature of heated exhaust pipes. Generally, IRSS is composed of eductor, mixing tube, and diffuser. Diffuser serves to reduce the temperature by creating an air film using the pressure difference between internal gas and external air. In this study, design variables were selected by analyzing the diffuser and the characteristics of design variables that affect the performance of diffuser were examined using Taguchi experiment method. For the diffuser performance analysis, a heat flow analysis technique established in previous research was used. The IRSS performance evaluation was carried out based on the average area value of the metal surface temperature and the temperature of the exhaust gas at the outlet of the diffuser, which are variables directly related to the intensity of infrared signature in naval ships. It was verified that the exhaust gas temperature is greatly affected by changes in the diameter of the diffuser outlet, and the metal surface temperature of diffuser is greatly affected by changes in the number of diffuser rings.

Observed oil and gas field size distributions: A consequence of the discovery process and prices of oil and gas

USGS Publications Warehouse

Drew, L.J.; Attanasi, E.D.; Schuenemeyer, J.H.

1988-01-01

If observed oil and gas field size distributions are obtained by random samplings, the fitted distributions should approximate that of the parent population of oil and gas fields. However, empirical evidence strongly suggests that larger fields tend to be discovered earlier in the discovery process than they would be by random sampling. Economic factors also can limit the number of small fields that are developed and reported. This paper examines observed size distributions in state and federal waters of offshore Texas. Results of the analysis demonstrate how the shape of the observable size distributions change with significant hydrocarbon price changes. Comparison of state and federal observed size distributions in the offshore area shows how production cost differences also affect the shape of the observed size distribution. Methods for modifying the discovery rate estimation procedures when economic factors significantly affect the discovery sequence are presented. A primary conclusion of the analysis is that, because hydrocarbon price changes can significantly affect the observed discovery size distribution, one should not be confident about inferring the form and specific parameters of the parent field size distribution from the observed distributions. ?? 1988 International Association for Mathematical Geology.

Experimental Investigations of the Internal Energy of Molecules Evaporated via Laser-induced Acoustic Desorption into a Fourier-transform Ion Cyclotron Resonance Mass Spectrometer (LIAD/FT-ICR)

PubMed Central

Shea, Ryan C.; Petzold, Christopher J.; Liu, Ji-ang; Kenttämaa, Hilkka I.

2008-01-01

The internal energy of neutral gas-phase organic and biomolecules, evaporated by means of laser-induced acoustic desorption (LIAD) into a Fourier-transform ion cyclotron resonance mass spectrometer (FT-ICR), was investigated through several experimental approaches. The desorbed molecules were demonstrated not to undergo degradation during the desorption process by collecting LIAD-evaporated molecules and subjecting them to analysis by electrospray ionization/quadrupole ion trap mass spectrometry. Previously established gas-phase basicity (GB) values were remeasured for LIAD-evaporated organic molecules and biomolecules with the use of the bracketing method. No endothermic reactions were observed. The remeasured basicity values are in close agreement with the values reported in the literature. The amount of internal energy deposited during LIAD is concluded to be less than a few kcal/mol. Chemical ionization with a series of proton transfer reagents was employed to obtain a breakdown curve for a protonated dipeptide, val-pro, evaporated by LIAD. Comparison of this breakdown curve with a previously published analogous curve obtained by using substrate-assisted laser desorption (SALD) to evaporate the peptide suggests that the molecules evaporated via LIAD have less internal energy than those evaporated via SALD. PMID:17263513

Technical and Socioeconomic Potential of Biogas from Cassava Waste in Ghana.

PubMed

Kemausuor, Francis; Addo, Ahmad; Darkwah, Lawrence

2015-01-01

This study analyses technical potential and ex ante socioeconomic impacts of biogas production using cassava waste from agroprocessing plants. An analysis was performed for two biodigesters in two cassava processing communities in Ghana. The results showed that the two communities generate an excess of 4,500 tonnes of cassava peels per year. Using approximately 5% of the peels generated and livestock manure as inoculum can generate approximately 75,000 m(3) of gas with an estimated 60% methane content from two separate plants of capacities 500 m(3) and 300 m(3) in the two communities. If used internally as process fuel, the potential gas available could replace over 300 tonnes of firewood per year for cassava processing. The displacement of firewood with gas could have environmental, economic, and social benefits in creating sustainable development. With a 10 percent discount rate, an assumed 20-year biodigester will have a Net Present Value of approximately US$ 148,000, 7-year Payback Period, and an Internal Rate of Return of 18.7%. The project will create 10 full-time unskilled labour positions during the investment year and 4 positions during operation years.

Technical and Socioeconomic Potential of Biogas from Cassava Waste in Ghana

PubMed Central

Kemausuor, Francis; Addo, Ahmad; Darkwah, Lawrence

2015-01-01

This study analyses technical potential and ex ante socioeconomic impacts of biogas production using cassava waste from agroprocessing plants. An analysis was performed for two biodigesters in two cassava processing communities in Ghana. The results showed that the two communities generate an excess of 4,500 tonnes of cassava peels per year. Using approximately 5% of the peels generated and livestock manure as inoculum can generate approximately 75,000 m3 of gas with an estimated 60% methane content from two separate plants of capacities 500 m3 and 300 m3 in the two communities. If used internally as process fuel, the potential gas available could replace over 300 tonnes of firewood per year for cassava processing. The displacement of firewood with gas could have environmental, economic, and social benefits in creating sustainable development. With a 10 percent discount rate, an assumed 20-year biodigester will have a Net Present Value of approximately US$ 148,000, 7-year Payback Period, and an Internal Rate of Return of 18.7%. The project will create 10 full-time unskilled labour positions during the investment year and 4 positions during operation years. PMID:26664752

Report on the International Rarefied Gas Dynamics Symposium (29th) held in Xi’an, China on 13-18 July 2014

DTIC Science & Technology

2014-11-21

cover in the region where gas expands all the way round the nozzle exit in the vacuum of space. This geome- try is investigated using hybrid NS/DSMC with...Final 3. DATES COVERED (From - To) 19 May 2014 – 18 Oct 2014 4. TITLE AND SUBTITLE Report on Rarefied Gas Dynamics Research Status 5a...Air Force about the current status of research in rarefied gas dynamics and related fields, primarily via the 29th International Symposium on Rarefied

Headspace Analysis of Philippine Civet Coffee Beans Using Gas Chromatography-Mass Spectrometry and Electronic Nose

NASA Astrophysics Data System (ADS)

Ongo, E.; Sevilla, F.; Antonelli, A.; Sberveglieri, G.; Montevecchi, G.; Sberveglieri, V.; de Paola, E. L.; Concina, I.; Falasconi, M.

2011-11-01

Civet coffee, the most expensive and best coffee in the world, is an economically important export product of the Philippines. With a growing threat of food adulteration and counterfeiting, a need for quality authentication is essential to protect the integrity and strong market value of Philippine civet coffee. At present, there is no internationally accepted method of verifying whether a bean is an authentic civet coffee. This study presented a practical and promising approach to identify and establish the headspace qualitative profile of Philippine civet coffee using electronic nose (E-nose) and gas chromatography-mass spectrometry (GC-MS). E-nose analysis revealed that aroma characteristic is one of the most important quality indicators of civet coffee. The findings were supported by GC-MS analysis. Principal component analysis (PCA) exhibited a clearly separated civet coffees from their control beans. The chromatographic fingerprints indicated that civet coffees differed with their control beans in terms of composition and concentration of individual volatile constituents.

Surface Properties of PEMFC Gas Diffusion Layers

DOE Office of Scientific and Technical Information (OSTI.GOV)

WoodIII, David L; Rulison, Christopher; Borup, Rodney

2010-01-01

The wetting properties of PEMFC Gas Diffusion Layers (GDLs) were quantified by surface characterization measurements and modeling of material properties. Single-fiber contact-angle and surface energy (both Zisman and Owens-Wendt) data of a wide spectrum of GDL types is presented to delineate the effects of hydrophobic post-processing treatments. Modeling of the basic sessile-drop contact angle demonstrates that this value only gives a fraction of the total picture of interfacial wetting physics. Polar forces are shown to contribute 10-20 less than dispersive forces to the composite wetting of GDLs. Internal water contact angles obtained from Owens-Wendt analysis were measured at 13-19 highermore » than their single-fiber counterparts. An inverse relationship was found between internal contact angle and both Owens-Wendt surface energy and % polarity of the GDL. The most sophisticated PEMFC mathematical models use either experimentally measured capillary pressures or the standard Young-Laplace capillary-pressure equation. Based on the results of the Owens-Wendt analysis, an advancement to the Young-Laplace equation is proposed for use in these mathematical models, which utilizes only solid surface energies and fractional surface coverage of fluoropolymer. Capillary constants for the spectrum of analyzed GDLs are presented for the same purpose.« less

The Best of Two Worlds: ALMA + IRAM30M Observations of the Orion Integral Shape Filament

NASA Astrophysics Data System (ADS)

Hacar Gonzalez, Alvaro

2018-01-01

We have investigated the internal gas structure of the Orion Integral Shape filament using two large-scale, 150-pointing ALMA-12m mosaics and previous IRAM30m single-dish (SD) observations. From the combination of both single-dish and interferometric data we have produced a high-dynamic range and high-sensitivity map describing the internal gas structure of this filament at scales between 2 pc and 2000 AU (Hacar et al, submitted to A&A). In a series of individual CASA reductions (w/o SD data + w/o feathering), we have investigated the impact of the different uv-coverages on both the total flux and line velocity structure of our ALMA maps. Our analysis highlights the critical role played by the zero-spacing data at the different stages of the cleaning process. The results of these ALMA+IRAM30m experiments emphasize the need of high-sensitivity SD observations for the analysis of large-scale interferometric maps. During my talk, I will discuss the implications of these experiments on the dawn of the ALMA era and in the context of the new AtLAST telescope.

Synthetic Biological Engineering of Photosynthesis

DTIC Science & Technology

2015-11-16

allowing for greater hydrogen yields and for dark fermentation of internal energy stores into hydrogen gas. These results proved our ability to connect...expressing strain, allowing for greater hydrogen yields and for dark fermentation of internal energy stores into hydrogen gas. These results proved our

Summary of International Exhibition and Congress (3rd): BIOTECHNICA 󈨛 Hannover Held in Hannover (Germany, F.R.) on 22-24 September 1987

DTIC Science & Technology

1988-01-21

nucleic acids which occur in DNA and seem to play an e Improved theoretical analysis of the important role in determining gene reg’- fntra- and...developed two retroviral vectors, based on the murine new peptide-based animal vaccines which myeloproliferative sarcoma virus (MPSV), are currertly...Structure tides are part of a precursor molecule elucidation is performed by gas-phase composed of 126 amino acids. From a pre- amino acid sequence analysis

Model documentation: Natural gas transmission and distribution model of the National Energy Modeling System. Volume 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1995-02-17

The Natural Gas Transmission and Distribution Model (NGTDM) is the component of the National Energy Modeling System (NEMS) that is used to represent the domestic natural gas transmission and distribution system. NEMS was developed in the Office of integrated Analysis and Forecasting of the Energy information Administration (EIA). NEMS is the third in a series of computer-based, midterm energy modeling systems used since 1974 by the EIA and its predecessor, the Federal Energy Administration, to analyze domestic energy-economy markets and develop projections. The NGTDM is the model within the NEMS that represents the transmission, distribution, and pricing of natural gas.more » The model also includes representations of the end-use demand for natural gas, the production of domestic natural gas, and the availability of natural gas traded on the international market based on information received from other NEMS models. The NGTDM determines the flow of natural gas in an aggregate, domestic pipeline network, connecting domestic and foreign supply regions with 12 demand regions. The methodology employed allows the analysis of impacts of regional capacity constraints in the interstate natural gas pipeline network and the identification of pipeline capacity expansion requirements. There is an explicit representation of core and noncore markets for natural gas transmission and distribution services, and the key components of pipeline tariffs are represented in a pricing algorithm. Natural gas pricing and flow patterns are derived by obtaining a market equilibrium across the three main elements of the natural gas market: the supply element, the demand element, and the transmission and distribution network that links them. The NGTDM consists of four modules: the Annual Flow Module, the Capacity F-expansion Module, the Pipeline Tariff Module, and the Distributor Tariff Module. A model abstract is provided in Appendix A.« less

A simplified and efficient method for the analysis of fatty acid methyl esters suitable for large clinical studies.

PubMed

Masood, Athar; Stark, Ken D; Salem, Norman

2005-10-01

Conventional sample preparation for fatty acid analysis is a complicated, multiple-step process, and gas chromatography (GC) analysis alone can require >1 h per sample to resolve fatty acid methyl esters (FAMEs). Fast GC analysis was adapted to human plasma FAME analysis using a modified polyethylene glycol column with smaller internal diameters, thinner stationary phase films, increased carrier gas linear velocity, and faster temperature ramping. Our results indicated that fast GC analyses were comparable to conventional GC in peak resolution. A conventional transesterification method based on Lepage and Roy was simplified to a one-step method with the elimination of the neutralization and centrifugation steps. A robotics-amenable method was also developed, with lower methylation temperatures and in an open-tube format using multiple reagent additions. The simplified methods produced results that were quantitatively similar and with similar coefficients of variation as compared with the original Lepage and Roy method. The present streamlined methodology is suitable for the direct fatty acid analysis of human plasma, is appropriate for research studies, and will facilitate large clinical trials and make possible population studies.

26 CFR 1.612-4 - Charges to capital and to expense in case of oil and gas wells.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 26 Internal Revenue 7 2011-04-01 2009-04-01 true Charges to capital and to expense in case of oil and gas wells. 1.612-4 Section 1.612-4 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES (CONTINUED) Natural Resources § 1.612-4 Charges to...

Features of the gas dynamics and local heat transfer in intake system of piston engine with supercharging

NASA Astrophysics Data System (ADS)

Plotnikov, L. V.

2017-09-01

Comparison of experimental research results of gas dynamics and instantaneous local heat transfer in the intake pipes for piston internal combustion engines (ICE) without and with supercharging are presented in the article. Studies were conducted on full-scale experimental setups in terms of gas dynamic nonstationarity, which is characteristic of piston engines. It has been established that the turbocharger installation in a gas-air system of piston internal combustion engine leads to significant differences in the patterns of change in gas-dynamic and heat transfer characteristics of flows. These data can be used in a modernization of piston engines due to installation of a turbocharger or in a development of gas-air systems for piston ICE with supercharging.

A simple and sensitive quantitation of N,N-dimethyltryptamine by gas chromatography with surface ionization detection.

PubMed

Ishii, A; Seno, H; Suzuki, O; Hattori, H; Kumazawa, T

1997-01-01

A simple and sensitive method for determination of N,N-dimethyltryptamine (DMT) by gas chromatography (GC) with surface ionization detection (SID) is presented. Whole blood or urine, containing DMT and gramine (internal standard), was subjected to solid-phase extraction with a Sep-Pak C18 cartridge before analysis by GC-SID. The calibration curve was linear in the DMT range of 1.25-20 ng/mL blood or urine. The detection limit of DMT was about 0.5 ng/mL (10 pg on-column). The recovery of both DMT and gramine spiked in biological fluids was above 86%.

On the Asymptotic Behavior of a Log Gas in the Bulk Scaling Limit in the Presence of a Varying External Potential I

NASA Astrophysics Data System (ADS)

Bothner, Thomas; Deift, Percy; Its, Alexander; Krasovsky, Igor

2015-08-01

We study the determinant , of the integrable Fredholm operator K s acting on the interval (-1, 1) with kernel . This determinant arises in the analysis of a log-gas of interacting particles in the bulk-scaling limit, at inverse temperature , in the presence of an external potential supported on an interval of length . We evaluate, in particular, the double scaling limit of as and , in the region , for any fixed . This problem was first considered by Dyson (Chen Ning Yang: A Great Physicist of the Twentieth Century. International Press, Cambridge, pp. 131-146, 1995).

The extinction and dust-to-gas structure of the planetary nebula NGC 7009 observed with MUSE

NASA Astrophysics Data System (ADS)

Walsh, J. R.; Monreal-Ibero, A.; Barlow, M. J.; Ueta, T.; Wesson, R.; Zijlstra, A. A.

2016-04-01

Context. Dust plays a significant role in planetary nebulae. Dust ejected with the gas in the asymptotic giant branch (AGB) phase is subject to the harsh environment of the planetary nebula (PN) while the star is evolving towards a white dwarf. Dust surviving the PN phase contributes to the dust content of the interstellar medium. Aims: The morphology of the internal dust extinction has been mapped for the first time in a PN, the bright nearby Galactic nebula NGC 7009. The morphologies of the gas, dust extinction and dust-to-gas ratio are compared to the structural features of the nebula. Methods: Emission line maps in H Balmer and Paschen lines were formed from analysis of MUSE cubes of NGC 7009 observed during science verification of the instrument. The measured electron temperature and density from the same cube were employed to predict the theoretical H line ratios and derive the extinction distribution across the nebula. After correction for the interstellar extinction to NGC 7009, the internal AV/NH has been mapped for the first time in a PN. Results: The extinction map of NGC 7009 has considerable structure, broadly corresponding to the morphological features of the nebula. The dust-to-gas ratio, AV/NH, increases from 0.7 times the interstellar value to >5 times from the centre towards the periphery of the ionized nebula. The integrated AV/NH is about 2× the mean ISM value. A large-scale feature in the extinction map is a wave, consisting of a crest and trough, at the rim of the inner shell. The nature of this feature is investigated and instrumental and physical causes considered; no convincing mechanisms were identified to produce this feature, other than AGB mass loss variations. Conclusions: Extinction mapping from H emission line imaging of PNe with MUSE provides a powerful tool for revealing the properties of internal dust and the dust-to-gas ratio. Based on observations collected at the European Organisation for Astronomical Research in the Southern Hemisphere under ESO programme 060.A-9347(A).

Measurements of methane emissions from natural gas gathering facilities and processing plants: measurement methods

DOE PAGES

Roscioli, J. R.; Yacovitch, T. I.; Floerchinger, C.; ...

2015-05-07

Increased natural gas production in recent years has spurred intense interest in methane (CH 4) emissions associated with its production, gathering, processing, transmission, and distribution. Gathering and processing facilities (G&P facilities) are unique in that the wide range of gas sources (shale, coal-bed, tight gas, conventional, etc.) results in a wide range of gas compositions, which in turn requires an array of technologies to prepare the gas for pipeline transmission and distribution. We present an overview and detailed description of the measurement method and analysis approach used during a 20-week field campaign studying CH 4 emissions from the natural gasmore » G&P facilities between October 2013 and April 2014. Dual-tracer flux measurements and on-site observations were used to address the magnitude and origins of CH 4 emissions from these facilities. The use of a second tracer as an internal standard revealed plume-specific uncertainties in the measured emission rates of 20–47%, depending upon plume classification. Furthermore, combining downwind methane, ethane (C 2H 6), carbon monoxide (CO), carbon dioxide (CO 2), and tracer gas measurements with on-site tracer gas release allows for quantification of facility emissions and in some cases a more detailed picture of source locations.« less

Internal limiting membrane peeling and gas tamponade for myopic foveoschisis: a systematic review and meta-analysis.

PubMed

Meng, Bo; Zhao, Lu; Yin, Yi; Li, Hongyang; Wang, Xiaolei; Yang, Xiufen; You, Ran; Wang, Jialin; Zhang, Youjing; Wang, Hui; Du, Ran; Wang, Ningli; Zhan, Siyan; Wang, Yanling

2017-09-08

Myopic foveoschisis (MF) is among the leading causes of visual loss in high myopia. However, it remains controversial whether internal limiting membrane (ILM) peeling or gas tamponade is necessary treatment option for MF. PubMed, EMBASE, CBM, CNKI, WANFANG DATA and VIP databases were systematically reviewed. Outcome indicators were myopic foveoschisis resolution rate, visual acuity improvement and postoperative complications. Nine studies that included 239 eyes were selected. The proportion of resolution of foveoschisis was higher in ILM peeling group than non-ILM peeling group (OR = 2.15, 95% CI: 1.06-4.35; P = 0.03). The proportion of postoperative complications was higher in Tamponade group than non-Tamponade group (OR = 10.81, 95% CI: 1.26-93.02; P = 0.03). However, the proportion of visual acuity improvement (OR = 1.63, 95% CI: 0.56-4.80; P = 0.37) between ILM peeling group and non-ILM peeling group and the proportion of resolution of foveoschisis (OR = 1.80, 95% CI: 0.76-4.28; P = 0.18) between Tamponade group and non-Tamponade group were similar. Vitrectomy with internal limiting membrane peeling could contribute to better resolution of myopic foveoschisis than non-peeling, however it does not significantly influence the proportion of visual acuity improvement and postoperative complications. Vitrectomy with gas tamponade is associated with more complications than non-tamponade and does not significantly influence the proportion of visual acuity improvement and resolution of myopic foveoschisis.

Inhibition and promotion of trace pollutant adsorption within electrostatic precipitators.

PubMed

Clack, Herek L

2017-08-01

Among the technologies available for reducing mercury emissions from coal-fired electric utilities is the injection of a powdered sorbent, often some form of activated carbon, into the flue gas upstream of the particulate control device, most commonly an electrostatic precipitator (ESP). Detailed measurements of mercury removal within ESPs are lacking due to the hazardous environment they pose, increasing the importance of analysis and numerical simulation in understanding the mechanisms involved. Our previous analyses revealed that mercury adsorption by particles suspended in the gas and mercury adsorption by particles collected on internal ESP surfaces are not additive removal mechanisms but rather are competitive. The present study expands on this counterintuitive finding. Presented are results from numerical simulations reflecting the complete range of possible mass transfer boundary conditions representing mercury adsorption by the accumulated dust cake covering internal ESP collection electrodes. Using the two mercury removal mechanisms operating concurrently and interdependently always underperforms the sum of the two mechanisms' individual contributions. The dual use of electrostatic precipitators (ESPs) for particulate removal and adsorption of trace gaseous pollutants such as mercury is increasing as mercury regulations become more widespread. Under such circumstances, mercury adsorption by particles suspended in the gas and mercury adsorption by particles collected on internal ESP surfaces are competitive. Together, the two mercury removal mechanisms always underperform the sum of their two independent contributions. These findings can inform strategies sought by electric utilities for reducing the usage costs of mercury sorbents.

Mid-IR spectroscopic instrumentation for point-of-care diagnosis using a hollow silica waveguide gas cell

NASA Astrophysics Data System (ADS)

Francis, Daniel; Hodgkinson, Jane; Walton, Christopher; Sizer, Jeremy; Black, Paul; Livingstone, Beth; Fowler, Dawn P.; Patel, Mitesh K.; Tatam, Ralph P.

2017-02-01

Laser spectroscopy provides the basis of instrumentation developed for the diagnosis of infectious disease, via quantification of organic biomarkers that are produced by associated bacteria. The technology is centred on a multichannel pulsed quantum cascade laser system that allows multiple lasers with different wavelengths to be used simultaneously, each selected to monitor a different diagnostic biomarker. The instrument also utilizes a hollow silica waveguide (HSW) gas cell which has a very high ratio of interaction pathlength to internal volume. This allows sensitive detection of low volume gas species from small volume biological samples. The spectroscopic performance of a range of HSW gas cells with different lengths and bore diameters has been assessed using methane as a test gas and a best-case limit of detection of 0.26 ppm was determined. The response time of this cell was measured as a 1,000 sccm flow of methane passed through it and was found to be 0.75 s. These results are compared with those obtained using a multi-pass Herriot cell. A prototype instrument has been built and approved for clinical trials for detection of lung infection in acute-care patients via analysis of ventilator breath. Demonstration of the instrument for headspace gas analysis is made by monitoring the methane emission from bovine faeces. The manufacture of a hospital-ready device for monitoring biomarkers of infection in the exhaled breath of intensive care ventilator patients is also presented.

Guide for studying and evaluating internal accounting controls. Oil and gas exploration, development and production

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1981-01-01

One of the most important responsibilities of any company's management is to establish and maintain, via periodic evaluations, is adequate internal accounting controls. Arthur Andersen and Co. approaches this problem as it relates to the oil and gas industry by logically dividing the economic events that affect a given company into four groups of activity termed ''business cycles'': treasury, expenditure, conversion (exploration, development, and production), and revenue activities. Independent public accountants can evaluate a company's existing internal controls much more thoroughly by studying only one category of business transactions at a time. Arthur Andersen's guide to reviewing internal controls coversmore » each step of this ''transaction-flow'' method as applied to a typical oil and gas company.« less

UNDERSTANDING METHANE EMISSIONS SOURCES AND VIABLE MITIGATION MEASURES IN THE NATURAL GAS TRANSMISSION SYSTEMS: RUSSIAN AND U.S. EXPERIENCE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ishkov, A.; Akopova, Gretta; Evans, Meredydd

This article will compare the natural gas transmission systems in the U.S. and Russia and review experience with methane mitigation technologies in the two countries. Russia and the United States (U.S.) are the world's largest consumers and producers of natural gas, and consequently, have some of the largest natural gas infrastructure. This paper compares the natural gas transmission systems in Russia and the U.S., their methane emissions and experiences in implementing methane mitigation technologies. Given the scale of the two systems, many international oil and natural gas companies have expressed interest in better understanding the methane emission volumes and trendsmore » as well as the methane mitigation options. This paper compares the two transmission systems and documents experiences in Russia and the U.S. in implementing technologies and programs for methane mitigation. The systems are inherently different. For instance, while the U.S. natural gas transmission system is represented by many companies, which operate pipelines with various characteristics, in Russia predominately one company, Gazprom, operates the gas transmission system. However, companies in both countries found that reducing methane emissions can be feasible and profitable. Examples of technologies in use include replacing wet seals with dry seals, implementing Directed Inspection and Maintenance (DI&M) programs, performing pipeline pump-down, applying composite wrap for non-leaking pipeline defects and installing low-bleed pneumatics. The research methodology for this paper involved a review of information on methane emissions trends and mitigation measures, analytical and statistical data collection; accumulation and analysis of operational data on compressor seals and other emission sources; and analysis of technologies used in both countries to mitigate methane emissions in the transmission sector. Operators of natural gas transmission systems have many options to reduce natural gas losses. Depending on the value of gas, simple, low-cost measures, such as adjusting leaking equipment components, or larger-scale measures, such as installing dry seals on compressors, can be applied.« less

(Gas discharges and applications)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sauers, I.

1988-10-04

The traveler attended the Ninth International Conference on Gas Discharges and Their Applications, which was held in Venice, Italy, on September 19--23, 1988; presented two papers, (1) Ion Chemistry in SF{sub 6} Corona'' and (2) Production of S{sub 2}F{sub 10} by SF{sub 6} Spark Discharge''; and participated in numerous discussions with conference participants on gas discharges related to his work on SF{sub 6}. The traveler visited the Centre de Physique Atomique at the University Paul Sabatier in Toulouse, France, to discuss with Dr. J. Casanovas his work on SF{sub 6} decomposition. Following that visit, the traveler visited the Laboratoire demore » Photoelectricite at the University of Dijon to discuss with Dr. J.-P. Goudonnet his work on surface studies and on the use of tunneling electron spectroscopy for the chemical analysis of surfaces.« less

Undergraduate ALFALFA Team: Analysis of Spatially-Resolved Star-Formation in Nearby Galaxy Groups and Clusters

NASA Astrophysics Data System (ADS)

Finn, Rose; Collova, Natasha; Spicer, Sandy; Whalen, Kelly; Koopmann, Rebecca A.; Durbala, Adriana; Haynes, Martha P.; Undergraduate ALFALFA Team

2017-01-01

As part of the Undergraduate ALFALFA Team, we are conducting a survey of the gas and star-formation properties of galaxies in 36 groups and clusters in the local universe. The galaxies in our sample span a large range of galactic environments, from the centers of galaxy groups and clusters to the surrounding infall regions. One goal of the project is to map the spatial distribution of star-formation; the relative extent of the star-forming and stellar disks provides important information about the internal and external processes that deplete gas and thus drive galaxy evolution. We obtained wide-field H-alpha observations with the WIYN 0.9m telescope at Kitt Peak National Observatory for galaxies in the vicinity of the MKW11 and NRGb004 galaxy groups and the Abell 1367 cluster. We present a preliminary analysis of the relative size of the star-forming and stellar disks as a function of galaxy morphology and local galaxy density, and we calculate gas depletion times using star-formation rates and HI gas mass. We will combine these results with those from other UAT members to determine if and how environmentally-driven gas depletion varies with the mass and X-ray properties of the host group or cluster. This work has supported by NSF grants AST-0847430, AST-1211005 and AST-1637339.

Applying of the Artificial Neural Networks (ANN) to Identify and Characterize Sweet Spots in Shale Gas Formations

NASA Astrophysics Data System (ADS)

Puskarczyk, Edyta

2018-03-01

The main goal of the study was to enhance and improve information about the Ordovician and Silurian gas-saturated shale formations. Author focused on: firstly, identification of the shale gas formations, especially the sweet spots horizons, secondly, classification and thirdly, the accurate characterization of divisional intervals. Data set comprised of standard well logs from the selected well. Shale formations are represented mainly by claystones, siltstones, and mudstones. The formations are also partially rich in organic matter. During the calculations, information about lithology of stratigraphy weren't taken into account. In the analysis, selforganizing neural network - Kohonen Algorithm (ANN) was used for sweet spots identification. Different networks and different software were tested and the best network was used for application and interpretation. As a results of Kohonen networks, groups corresponding to the gas-bearing intervals were found. The analysis showed diversification between gas-bearing formations and surrounding beds. It is also shown that internal diversification in sweet spots is present. Kohonen algorithm was also used for geological interpretation of well log data and electrofacies prediction. Reliable characteristic into groups shows that Ja Mb and Sa Fm which are usually treated as potential sweet spots only partially have good reservoir conditions. It is concluded that ANN appears to be useful and quick tool for preliminary classification of members and sweet spots identification.

Situ soil sampling probe system with heated transfer line

DOEpatents

Robbat, Jr., Albert

2002-01-01

The present invention is directed both to an improved in situ penetrometer probe and to a heated, flexible transfer line. The line and probe may be implemented together in a penetrometer system in which the transfer line is used to connect the probe to a collector/analyzer at the surface. The probe comprises a heater that controls a temperature of a geologic medium surrounding the probe. At least one carrier gas port and vapor collection port are located on an external side wall of the probe. The carrier gas port provides a carrier gas into the geologic medium, and the collection port captures vapors from the geologic medium for analysis. In the transfer line, a flexible collection line that conveys a collected fluid, i.e., vapor, sample to a collector/analyzer. A flexible carrier gas line conveys a carrier gas to facilitate the collection of the sample. A system heating the collection line is also provided. Preferably the collection line is electrically conductive so that an electrical power source can generate a current through it so that the internal resistance generates heat.

Analysis of the efficiency of recombinant Escherichia coli strain cultivation in a gas-vortex bioreactor.

PubMed

Savelyeva, Anna V; Nemudraya, Anna A; Podgornyi, Vladimir F; Laburkina, Nadezhda V; Ramazanov, Yuriy A; Repkov, Andrey P; Kuligina, Elena V; Richter, Vladimir A

2017-09-01

The levels of aeration and mass transfer are critical parameters required for an efficient aerobic bioprocess, and directly depend on the design features of exploited bioreactors. A novel apparatus, using gas vortex for aeration and mass transfer processes, was constructed in the Center of Vortex Technologies (Novosibirsk, Russia). In this paper, we compared the efficiency of recombinant Escherichia coli strain cultivation using novel gas-vortex technology with conventional bioprocess technologies such as shake flasks and bioreactors with mechanical stirrers. We demonstrated that the system of aeration and agitation used in gas-vortex bioreactors provides 3.6 times higher volumetric oxygen transfer coefficient in comparison with mechanical bioreactor. The use of gas-vortex bioreactor for recombinant E. coli strain cultivation allows to increase the efficiency of target protein expression at 2.2 times for BL21(DE3)/pFK2 strain and at 3.5 times for auxotrophic C600/pRT strain (in comparison with stirred bioreactor). © 2016 International Union of Biochemistry and Molecular Biology, Inc.

Determination of external and internal mass transfer limitation in nitrifying microbial aggregates.

PubMed

Wilén, Britt-Marie; Gapes, Daniel; Keller, Jürg

2004-05-20

In this article we present a study of the effects of external and internal mass transfer limitation of oxygen in a nitrifying system. The oxygen uptake rates (OUR) were measured on both a macro-scale with a respirometric reactor using off-gas analysis (Titrimetric and Off-Gas Analysis (TOGA) sensor) and on a micro-scale with microsensors. These two methods provide independent, accurate measurements of the reaction rates and concentration profiles around and in the granules. The TOGA sensor and microsensor measurements showed a significant external mass transfer effect at low dissolved oxygen (DO) concentrations in the bulk liquid while it was insignificant at higher DO concentrations. The oxygen distribution with anaerobic or anoxic conditions in the center clearly shows major mass transfer limitation in the aggregate interior. The large drop in DO concentration of 22-80% between the bulk liquid and aggregate surface demonstrates that the external mass transfer resistance is also highly important. The maximum OUR even for floccular biomass was only attained at much higher DO concentrations (approximately 8 mg/L) than typically used in such systems. For granules, the DO required for maximal activity was estimated to be >20 mg/L, clearly indicating the effects of the major external and internal mass transfer limitations on the overall biomass activity. Smaller aggregates had a larger volumetric OUR indicating that the granules may have a lower activity in the interior part of the aggregate. Copyright 2004 Wiley Periodicals, Inc.

Dynamics of pulsed expansion of polyatomic gas cloud: Internal-translational energy transfer contribution

NASA Astrophysics Data System (ADS)

Morozov, A. A.

2007-08-01

Polyatomic gas cloud expansion under pulsed laser evaporation is studied on the basis of one-dimensional direct Monte Carlo simulation. The effect of rotational-translational (RT) and vibrational-translational (VT) energy transfer on dynamics of the cloud expansion is considered. Efficiency of VT energy transfer dependence on the amount of evaporated matter is discussed. To analyze VT energy transfer impact, the number of collisions per molecule during the expansion is calculated. The data are generally in good agreement with available analytical and numerical predictions. Dependencies of the effective number of vibrational degrees of freedom on the number of vibrationally inelastic collisions are obtained and generalized. The importance of the consideration of energy transfer from the internal degrees of freedom to the translational ones is illustrated by an example of pulsed laser evaporation of polytetrafluoroethylene (PTFE). Based on the obtained regularities, analysis of experimental data on pulsed laser evaporation of aniline is performed. The calculated aniline vibrational temperature correlates well with the experimentally measured one.

Characterization of Ceramic Vane Materials for 10KW Turboalternator.

DTIC Science & Technology

1983-04-01

eide if necessary end identify by block number) Silicon nitride Gas turbine engine Failure analysis Silicon carbide Mechanical properties Ceramics...silicon carbide, and sil- iconized silicon carbide, being considered for use in a small turbine engine . Chemistry, phase content, and room-temperature...sponsored by USAMERADCOK, Ft. Belvoir, Va., and the engine testing and development was done by Solar Turbines International, San Diego, Calif. ANMHRC

Carbon pools - checking the deep end, before diving in (The ME Experience)

Treesearch

K. M. Laustsen

2006-01-01

Maine’s initial Greenhouse Gas (GHG) estimates of the Land Use Change and Forestry (LUCF) sub-accounts predicted that this account supplied 15 percent of the net emissions in 2000. The magnitude and direction of this estimate ran counter to internal assumptions and the recently published analysis on multiple and positive forest inventory changes for the period of 1995...

Full-scale hot cell test of an acoustic sensor dedicated to measurement of the internal gas pressure and composition of a LWR nuclear fuel rod

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ferrandis, J. Y.; Rosenkrantz, E.; Leveque, G.

2011-07-01

A full-scale hot cell test of the internal gas pressure and composition measurement by an acoustic sensor was carried on successfully between 2008 and 2010 on irradiated fuel rods in the LECA-STAR facility at Cadarache Centre. The acoustic sensor has been specially designed in order to provide a nondestructive technique to easily carry out the measurement of the internal gas pressure and gas composition of a LWR nuclear fuel rod. This sensor has been achieved in 2007 and is now covered by an international patent. The first positive result, concerning the device behaviour, is that the sensor-operating characteristics have notmore » been altered by a two-year exposure in the hot cell ambient. We performed the gas characterisation contained in irradiated fuel rods. The acoustic method accuracy is now {+-}5 bars on the pressure measurement result and {+-}0.3% on the evaluated gas composition. The results of the acoustic method were compared to puncture results. Another significant conclusion is that the efficiency of the acoustic method is not altered by the irradiation time, and possible modification of the cladding properties. These results make it possible to demonstrate the feasibility of the technique on irradiated fuel rods. The transducer and the associated methodology are now operational. (authors)« less

SITE PROGRAM DEMONSTRATION ECO LOGIC INTERNATIONAL GAS-PHASE CHEMICAL REDUCTION PROCESS, BAY CITY, MICHIGAN TECHNOLOGY EVALUATION REPORT

EPA Science Inventory

The SITE Program funded a field demonstration to evaluate the Eco Logic Gas-Phase Chemical Reduction Process developed by ELI Eco Logic International Inc. (ELI), Ontario, Canada. The Demonstration took place at the Middleground Landfill in Bay City, Michigan using landfill wa...

Alternative Fuels Data Center: Natural Gas Related Links

Science.gov Websites

, AGA provides services to member natural gas pipelines, marketers, gatherers, international gas Natural Gas Printable Version Share this resource Send a link to Alternative Fuels Data Center : Natural Gas Related Links to someone by E-mail Share Alternative Fuels Data Center: Natural Gas Related

Local Area Water Removal Analysis of a Proton Exchange Membrane Fuel Cell under Gas Purge Conditions

PubMed Central

Lee, Chi-Yuan; Lee, Yu-Ming; Lee, Shuo-Jen

2012-01-01

In this study, local area water content distribution under various gas purging conditions are experimentally analyzed for the first time. The local high frequency resistance (HFR) is measured using novel micro sensors. The results reveal that the liquid water removal rate in a membrane electrode assembly (MEA) is non-uniform. In the under-the-channel area, the removal of liquid water is governed by both convective and diffusive flux of the through-plane drying. Thus, almost all of the liquid water is removed within 30 s of purging with gas. However, liquid water that is stored in the under-the-rib area is not easy to remove during 1 min of gas purging. Therefore, the re-hydration of the membrane by internal diffusive flux is faster than that in the under-the-channel area. Consequently, local fuel starvation and membrane degradation can degrade the performance of a fuel cell that is started from cold. PMID:22368495

Solvent-modified solid-phase microextraction for the determination of diazepam in human plasma samples by capillary gas chromatography.

PubMed

Krogh, M; Grefslie, H; Rasmussen, K E

1997-02-21

This paper describes microextraction and gas chromatographic analysis of diazepam from human plasma. The method was based on immobilisation of 1.5 microliters of 1-octanol on a polyacrylate-coated fiber designed for solid-phase microextraction. The solvent-modified fibre was used to extract diazepam from the samples. The plasma sample was pre-treated to release diazepam from the protein binding. The fibre was inserted into the modified plasma sample, adjusted to pH 5.5 an internal standard was added and the mixture was carefully stirred for 4 min. The fibre with the immobilised solvent and the enriched analytes was injected into the capillary gas chromatograph. The solvent and the extracted analytes were evaporated at 300 degrees C in the split-splitless injection port of the gas chromatograph, separated on a methylsilicon capillary column and detected with a nitrogen-phosphorus detector. The method was shown to be reproducible with a detection limit of 0.10 nmol/ml in human plasma.

Local area water removal analysis of a proton exchange membrane fuel cell under gas purge conditions.

PubMed

Lee, Chi-Yuan; Lee, Yu-Ming; Lee, Shuo-Jen

2012-01-01

In this study, local area water content distribution under various gas purging conditions are experimentally analyzed for the first time. The local high frequency resistance (HFR) is measured using novel micro sensors. The results reveal that the liquid water removal rate in a membrane electrode assembly (MEA) is non-uniform. In the under-the-channel area, the removal of liquid water is governed by both convective and diffusive flux of the through-plane drying. Thus, almost all of the liquid water is removed within 30 s of purging with gas. However, liquid water that is stored in the under-the-rib area is not easy to remove during 1 min of gas purging. Therefore, the re-hydration of the membrane by internal diffusive flux is faster than that in the under-the-channel area. Consequently, local fuel starvation and membrane degradation can degrade the performance of a fuel cell that is started from cold.

Comprehensive Analysis of the Gas- and Particle-Phase Products of VOC Oxidation

NASA Astrophysics Data System (ADS)

Bakker-Arkema, J.; Ziemann, P. J.

2017-12-01

Controlled environmental chamber studies are important for determining atmospheric reaction mechanisms and gas and aerosol products formed in the oxidation of volatile organic compounds (VOCs). Such information is necessary for developing detailed chemical models for use in predicting the atmospheric fate of VOCs and also secondary organic aerosol (SOA) formation. However, complete characterization of atmospheric oxidation reactions, including gas- and particle-phase product yields, and reaction branching ratios, are difficult to achieve. In this work, we investigated the reactions of terminal and internal alkenes with OH radicals in the presence of NOx in an attempt to fully characterize the chemistry of these systems while minimizing and accounting for the inherent uncertainties associated with environmental chamber experiments. Gas-phase products (aldehydes formed by alkoxy radical decomposition) and particle-phase products (alkyl nitrates, β-hydroxynitrates, dihydroxynitrates, 1,4-hydroxynitrates, 1,4-hydroxycarbonyls, and dihydroxycarbonyls) formed through pathways involving addition of OH to the C=C double bond as well as H-atom abstraction were identified and quantified using a suite of analytical techniques. Particle-phase products were analyzed in real time with a thermal desorption particle beam mass spectrometer; and off-line by collection onto filters, extraction, and subsequent analysis of functional groups by derivatization-spectrophotometric methods developed in our lab. Derivatized products were also separated by liquid chromatography for molecular quantitation by UV absorbance and identification using chemical ionization-ion trap mass spectrometry. Gas phase aldehydes were analyzed off-line by collection onto Tenax and a 5-channel denuder with subsequent analysis by gas chromatography, or by collection onto DNPH-coated cartridges and subsequent analysis by liquid chromatography. The full product identification and quantitation, with careful minimization of uncertainties for the various components of the experiment and analyses, demonstrates our capability to comprehensively and accurately analyze the complex chemical composition of products formed in the oxidation of organic compounds in laboratory chamber studies.

Fossil Energy Program

NASA Astrophysics Data System (ADS)

McNeese, L. E.

1981-01-01

Increased utilization of coal and other fossil fuel alternatives as sources of clean energy is reported. The following topics are discussed: coal conversion development, chemical research and development, materials technology, component development and process evaluation studies, technical support to major liquefaction projects, process analysis and engineering evaluations, fossil energy environmental analysis, flue gas desulfurization, solid waste disposal, coal preparation waste utilization, plant control development, atmospheric fluidized bed coal combustor for cogeneration, TVA FBC demonstration plant program technical support, PFBC systems analysis, fossil fuel applications assessments, performance assurance system support for fossil energy projects, international energy technology assessment, and general equilibrium models of liquid and gaseous fuel supplies.

Microjet burners for molecular-beam sources and combustion studies

NASA Astrophysics Data System (ADS)

Groeger, Wolfgang; Fenn, John B.

1988-09-01

A novel microjet burner is described in which combustion is stabilized by a hot wall. The scale is so small that the entire burner flow can be passed through a nozzle only 0.2 mm or less in diameter into an evacuated chamber to form a supersonic free jet with expansion so rapid that all collisional processes in the jet gas are frozen in a microsecond or less. This burner can be used to provide high-temperature source gas for free jet expansion to produce intense beams of internally hot molecules. A more immediate use would seem to be in the analysis of combustion products and perhaps intermediates by various kinds of spectroscopies without some of the perturbation effects encountered in probe sampling of flames and other types of combustion devices. As an example of the latter application of this new tool, we present infrared emission spectra for jet gas obtained from the combustion of oxygen-hydrocarbon mixtures both fuel-rich and fuel-lean operation. In addition, we show results obtained by mass spectrometric analysis of the combustion products.

Data Base for CFD Validation

NASA Technical Reports Server (NTRS)

Deiwert, George S.

1997-01-01

The flow behind the shock wave formed around objects which fly at hypervelocity behaves differently from that of a perfect gas. Molecules become vibrationally excited, dissociated, and ionized. The hot gas may emit or absorb radiation. When the atoms produced by dissociation reach the wall surface, chemical reactions, including recombination, may occur. The thermochemical phenomena of vibration, dissociation, ionization, surface chemical reaction, and radiation are referred to commonly as high-temperature real-gas phenomena. The phenomena cause changes in the dynamic behavior of the flow and the surface pressure and heat transfer distribution around the object. The character of a real gas is described by the internal degrees of freedom and state of constituent molecules; nitrogen and oxygen for air. The internal energy states, rotation, vibration and electronic, of the molecules are excited and, in the limit, the molecular bonds are exceeded and the gas dissociated into atomic and, possibly, ionic constituents. The process of energy transfer causing excitation, dissociation and recombination is a rate process controlled by particle collisions. Binary, two-body, collisions are sufficient to cause internal excitation, dissociation and ionization while three-body collisions are required to recombine the particles into molecular constituents. If the rates of energy transfer are fast with respect to the local fluid dynamic time scale the gas is in, or nearly in, equilibrium. If the energy transfer rates are very slow the gas can be described as frozen. In all other instances, wherein any of the energy exchange rates are comparable to the local fluid time scale, the gas will be thermally or chemically reacting and out of equilibrium. Real gas thermochemical nonequilibrium processes are important in the determination of aerodynamic heating; both convective (including wall catalytic effects) and radiative heating. To illustrate this we consider the hypervelocity flow over a bluff body typical of an atmospheric entry vehicle or an aerospace transfer vehicle (ASTV). The qualitative aspects of a hypersonic flow field over a bluff body are discussed in two parts, forebody and afterbody, with attention to which particular physical effects must be included in an analysis. This will indicate what type of numerical modeling will be adequate in each region of the flow. A bluff forebody flow field is dominated by the presence of the strong bow shock wave and the consequent heating, and chemical reaction of the gas. At high altitude hypersonic flight conditions the thermal excitation and chemical reaction of the gas occur slowly enough that a significant portion of the flow field is in a state of thermochemical nonequilibrium. A second important effect is the presence of the thick boundary layer along the forebody surface. In this region there are large thermal and chemical species gradients due to the interaction of the gas with the wall. Also at high altitudes the shock wave and the boundary layer may become so thick that they merge; in this case the entire shock layer is dominated by viscous effects.

Potential Cost-Effective Opportunities for Methane Emission Abatement

DOE Office of Scientific and Technical Information (OSTI.GOV)

Warner, Ethan; Steinberg, Daniel; Hodson, Elke

2015-08-01

The energy sector was responsible for approximately 84% of carbon dioxide equivalent (CO 2e) greenhouse gas (GHG) emissions in the U.S. in 2012 (EPA 2014a). Methane is the second most important GHG, contributing 9% of total U.S. CO 2e emissions. A large portion of those methane emissions result from energy production and use; the natural gas, coal, and oil industries produce approximately 39% of anthropogenic methane emissions in the U.S. As a result, fossil-fuel systems have been consistently identified as high priority sectors to contribute to U.S. GHG reduction goals (White House 2015). Only two studies have recently attempted tomore » quantify the abatement potential and cost associated with the breadth of opportunities to reduce GHG emissions within natural gas, oil, and coal supply chains in the United States, namely the U.S. Environmental Protection Agency (EPA) (2013a) and ICF (2014). EPA, in its 2013 analysis, estimated the marginal cost of abatement for non-CO 2 GHG emissions from the natural gas, oil, and coal supply chains for multiple regions globally, including the United States. Building on this work, ICF International (ICF) (2014) provided an update and re-analysis of the potential opportunities in U.S. natural gas and oil systems. In this report we synthesize these previously published estimates as well as incorporate additional data provided by ICF to provide a comprehensive national analysis of methane abatement opportunities and their associated costs across the natural gas, oil, and coal supply chains. Results are presented as a suite of marginal abatement cost curves (MACCs), which depict the total potential and cost of reducing emissions through different abatement measures. We report results by sector (natural gas, oil, and coal) and by supply chain segment - production, gathering and boosting, processing, transmission and storage, or distribution - to facilitate identification of which sectors and supply chain segments provide the greatest opportunities for low cost abatement.« less

Executive reflects on progress in the oil and gas industry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Popov, S.

1997-08-01

This paper reflects on the UK oil and gas industry`s international globalization and progress from the perspective of a UK industry executive. Sir Ian Wood, managing director of John Wood Group plc, outlined past and future industry developments during a 1997 Offshore Technology Conference speech. He concludes that the UK supply and service industry is now fully involved in the international arena, and hopes to play a significant role in the exciting oil and gas developments in the Gulf of Mexico and frontiers worldwide.

Enhanced Efficiency of Internal Combustion Engines By Employing Spinning Gas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Geyko, Vasily; Fisch, Nathaniel

2014-02-27

The efficiency of the internal combustion engine might be enhanced by employing spinning gas. A gas spinning at near sonic velocities has an effectively higher heat capacity, which allows practical fuel cycles, which are far from the Carnot efficiency, to approach more closely the Carnot efficiency. A gain in fuel efficiency of several percent is shown to be theoretically possible for the Otto and Diesel cycles. The use of a flywheel, in principle, could produce even greater increases in the efficiency.

Enhanced efficiency of internal combustion engines by employing spinning gas.

PubMed

Geyko, V I; Fisch, N J

2014-08-01

The efficiency of the internal combustion engine might be enhanced by employing spinning gas. A gas spinning at near sonic velocities has an effectively higher heat capacity, which allows practical fuel cycles, which are far from the Carnot efficiency, to approach more closely the Carnot efficiency. A remarkable gain in fuel efficiency is shown to be theoretically possible for the Otto and Diesel cycles. The use of a flywheel, in principle, could produce even greater increases in efficiency.

Electrochemical and Infrared Absorption Spectroscopy Detection of SF6 Decomposition Products

PubMed Central

Dong, Ming; Ren, Ming; Ye, Rixin

2017-01-01

Sulfur hexafluoride (SF6) gas-insulated electrical equipment is widely used in high-voltage (HV) and extra-high-voltage (EHV) power systems. Partial discharge (PD) and local heating can occur in the electrical equipment because of insulation faults, which results in SF6 decomposition and ultimately generates several types of decomposition products. These SF6 decomposition products can be qualitatively and quantitatively detected with relevant detection methods, and such detection contributes to diagnosing the internal faults and evaluating the security risks of the equipment. At present, multiple detection methods exist for analyzing the SF6 decomposition products, and electrochemical sensing (ES) and infrared (IR) spectroscopy are well suited for application in online detection. In this study, the combination of ES with IR spectroscopy is used to detect SF6 gas decomposition. First, the characteristics of these two detection methods are studied, and the data analysis matrix is established. Then, a qualitative and quantitative analysis ES-IR model is established by adopting a two-step approach. A SF6 decomposition detector is designed and manufactured by combining an electrochemical sensor and IR spectroscopy technology. The detector is used to detect SF6 gas decomposition and is verified to reliably and accurately detect the gas components and concentrations. PMID:29140268

75 FR 75937 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-07

... engine. transmission, or distribution. 622110 Medical and surgical hospitals. 48621 Natural gas transmission. 211111 Crude petroleum and natural gas production. 211112 Natural gas liquids producers. 92811...

76 FR 12923 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-09

... hospitals. 48621 Natural gas transmission. 211111 Crude petroleum and natural gas production. 211112 Natural gas liquids producers. 92811 National security. \\1\\ North American Industry Classification System...

Producer gas production of Indonesian biomass in fixed-bed downdraft gasifier as an alternative fuels for internal combustion engines

NASA Astrophysics Data System (ADS)

Simanjuntak, J. P.; Lisyanto; Daryanto, E.; Tambunan, B. H.

2018-03-01

downdraft biomass gasification reactors, coupled with reciprocating internal combustion engines (ICE) are a viable technology for small scale heat and power generation. The direct use of producer gas as fuel subtitution in an ICE could be of great interest since Indonesia has significant land area in different forest types that could be used to produce bioenergy and convert forest materials to bioenergy for use in energy production and the versatility of this engine. This paper will look into the aspect of biomass energie as a contributor to energy mix in Indonesia. This work also contains information gathered from numerous previews study on the downdraft gasifier based on experimental or simulation study on the ability of producer gas as fuels for internal combustion engines aplication. All data will be used to complement the preliminary work on biomass gasification using downdraft to produce producer gas and its application to engines.

Gas exchange in fruits related to skin condition and fruit ripening studied with diode laser spectroscopy

NASA Astrophysics Data System (ADS)

Huang, Jing; Zhang, Hao; Lin, Huiying; Li, Tianqi; Mei, Liang; Svanberg, Katarina; Svanberg, Sune

2016-12-01

The concentration of the biologically active molecular oxygen gas is of crucial importance for fruits in the metabolic respiration, maturation, and ripening processes. In our study, oxygen content and oxygen transport in fruits, exemplified by apples and guavas, were studied noninvasively by gas in scattering media absorption spectroscopy. The technique is based on the fact that free gases typically have 10,000 times narrower absorption features than the bulk material. The technique was demonstrated in studies of the influence of the fruit skin in regulating the internal oxygen balance, by observing the signal response of the internal oxygen gas to a transient change in the ambient gas concentration on peeled and unpeeled fruits. In addition, the gas exchange rate at different ripening stages was also studied in intact guavas.

Gas exchange in fruits related to skin condition and fruit ripening studied with diode laser spectroscopy.

PubMed

Huang, Jing; Zhang, Hao; Lin, Huiying; Li, Tianqi; Mei, Liang; Svanberg, Katarina; Svanberg, Sune

2016-12-01

The concentration of the biologically active molecular oxygen gas is of crucial importance for fruits in the metabolic respiration, maturation, and ripening processes. In our study, oxygen content and oxygen transport in fruits, exemplified by apples and guavas, were studied noninvasively by gas in scattering media absorption spectroscopy. The technique is based on the fact that free gases typically have 10,000 times narrower absorption features than the bulk material. The technique was demonstrated in studies of the influence of the fruit skin in regulating the internal oxygen balance, by observing the signal response of the internal oxygen gas to a transient change in the ambient gas concentration on peeled and unpeeled fruits. In addition, the gas exchange rate at different ripening stages was also studied in intact guavas.

Atmospheric Gaseous Plasma with Large Dimensions

NASA Astrophysics Data System (ADS)

Korenev, Sergey

2012-10-01

The forming of atmospheric plasma with large dimensions using electrical discharge typically uses the Dielectric Barrier Discharge (DBD). The study of atmospheric DBD was shown some problems related to homogeneous volume plasma. The volume of this plasma determines by cross section and gas gap between electrode and dielectric. The using of electron beam for volume ionization of air molecules by CW relativistic electron beams was shown the high efficiency of this process [1, 2]. The main advantage of this approach consists in the ionization of gas molecules by electrons in longitudinal direction determines by their kinetic energy. A novel method for forming of atmospheric homogeneous plasma with large volume dimensions using ionization of gas molecules by pulsed non-relativistic electron beams is presented in the paper. The results of computer modeling for delivered doses of electron beams in gases and ionization are discussed. The structure of experimental bench with plasma diagnostics is considered. The preliminary results of forming atmospheric plasma with ionization gas molecules by pulsed nanosecond non-relativistic electron beam are given. The analysis of potential applications for atmospheric volume plasma is presented. Reference: [1] S. Korenev. ``The ionization of air by scanning relativistic high power CW electron beam,'' 2002 IEEE International Conference on Plasma Science. May 2002, Alberta, Canada. [2] S. Korenev, I. Korenev. ``The propagation of high power CW scanning electron beam in air.'' BEAMS 2002: 14th International Conference on High-Power Particle Beams, Albuquerque, New Mexico (USA), June 2002, AIP Conference Proceedings Vol. 650(1), pp. 373-376. December 17.

SiC/SiC Leading Edge Turbine Airfoil Tested Under Simulated Gas Turbine Conditions

NASA Technical Reports Server (NTRS)

Robinson, R. Craig; Hatton, Kenneth S.

1999-01-01

Silicon-based ceramics have been proposed as component materials for use in gas turbine engine hot-sections. A high pressure burner rig was used to expose both a baseline metal airfoil and ceramic matrix composite leading edge airfoil to typical gas turbine conditions to comparatively evaluate the material response at high temperatures. To eliminate many of the concerns related to an entirely ceramic, rotating airfoil, this study has focused on equipping a stationary metal airfoil with a ceramic leading edge insert to demonstrate the feasibility and benefits of such a configuration. Here, the idea was to allow the SiC/SiC composite to be integrated as the airfoil's leading edge, operating in a "free-floating" or unrestrained manner. and provide temperature relief to the metal blade underneath. The test included cycling the airfoils between simulated idle, lift, and cruise flight conditions. In addition, the airfoils were air-cooled, uniquely instrumented, and exposed to the same internal and external conditions, which included gas temperatures in excess of 1370 C (2500 F). Results show the leading edge insert remained structurally intact after 200 simulated flight cycles with only a slightly oxidized surface. The instrumentation clearly suggested a significant reduction (approximately 600 F) in internal metal temperatures as a result of the ceramic leading edge. The object of this testing was to validate the design and analysis done by Materials Research and Design of Rosemont, PA and to determine the feasibility of this design for the intended application.

Thermal design of a natural gas - diesel dual fuel turbocharged V18 engine for ship propulsion and power plant applications

NASA Astrophysics Data System (ADS)

Douvartzides, S.; Karmalis, I.

2016-11-01

A detailed method is presented on the thermal design of a natural gas - diesel dual fuel internal combustion engine. An 18 cylinder four stroke turbocharged engine is considered to operate at a maximum speed of 500 rpm for marine and power plant applications. Thermodynamic, heat transfer and fluid flow phenomena are mathematically analyzed to provide a real cycle analysis together with a complete set of calculated operation conditions, power characteristics and engine efficiencies. The method is found to provide results in close agreement to published data for the actual performance of similar engines such as V18 MAN 51/60DF.

[Gas chromatography in quantitative analysis of hydrocyanic acid and its salts in cadaveric blood].

PubMed

Iablochkin, V D

2003-01-01

A direct gas chromatography method was designed for the quantitative determination of cyanides (prussic acid) in cadaveric blood. Its sensitivity is 0.05 mg/ml. The routine volatile products, including substances, which emerge due to putrefaction of organic matters, do not affect the accuracy and reproducibility of the method; the exception is H-propanol that was used as the internal standard. The method was used in legal chemical expertise related with acute cyanide poisoning (suicide) as well as with poisoning of products of combustion of nonmetals (foam-rubber). The absolute error does not exceed 10% with a mean quadratic deviation of 0.0029-0.0033 mg.

Inflationary cosmology with Chaplygin gas in Palatini formalism

DOE Office of Scientific and Technical Information (OSTI.GOV)

Borowiec, Andrzej; Wojnar, Aneta; Stachowski, Aleksander

2016-01-01

We present a simple generalisation of the ΛCDM model which on the one hand reaches very good agreement with the present day experimental data and provides an internal inflationary mechanism on the other hand. It is based on Palatini modified gravity with quadratic Starobinsky term and generalized Chaplygin gas as a matter source providing, besides a current accelerated expansion, the epoch of endogenous inflation driven by type III freeze singularity. It follows from our statistical analysis that astronomical data favors negative value of the parameter coupling quadratic term into Einstein-Hilbert Lagrangian and as a consequence the bounce instead of initialmore » Big-Bang singularity is preferred.« less

Design Concepts for Cooled Ceramic Composite Turbine Vane

NASA Technical Reports Server (NTRS)

Boyle, Robert J.; Parikh, Ankur H.; Nagpal, VInod K.

2015-01-01

The objective of this work was to develop design concepts for a cooled ceramic vane to be used in the first stage of the High Pressure Turbine(HPT). To insure that the design concepts were relevant to the gas turbine industry needs, Honeywell International Inc. was subcontracted to provide technical guidance for this work. The work performed under this contract can be divided into three broad categories. The first was an analysis of the cycle benefits arising from the higher temperature capability of Ceramic Matrix Composite(CMC) compared with conventional metallic vane materials. The second category was a series of structural analyses for variations in the internal configuration of first stage vane for the High Pressure Turbine(HPT) of a CF6 class commercial airline engine. The third category was analysis for a radial cooled turbine vanes for use in turboshaft engine applications. The size, shape and internal configuration of the turboshaft engine vanes were selected to investigate a cooling concept appropriate to small CMC vanes.

An optical method for measuring exhaust gas pressure from an internal combustion engine at high speed

NASA Astrophysics Data System (ADS)

Leach, Felix C. P.; Davy, Martin H.; Siskin, Dmitrij; Pechstedt, Ralf; Richardson, David

2017-12-01

Measurement of exhaust gas pressure at high speed in an engine is important for engine efficiency, computational fluid dynamics analysis, and turbocharger matching. Currently used piezoresistive sensors are bulky, require cooling, and have limited lifetimes. A new sensor system uses an interferometric technique to measure pressure by measuring the size of an optical cavity, which varies with pressure due to movement of a diaphragm. This pressure measurement system has been used in gas turbine engines where the temperatures and pressures have no significant transients but has never been applied to an internal combustion engine before, an environment where both temperature and pressure can change rapidly. This sensor has been compared with a piezoresistive sensor representing the current state-of-the-art at three engine operating points corresponding to both light load and full load. The results show that the new sensor can match the measurements from the piezoresistive sensor except when there are fast temperature swings, so the latter part of the pressure during exhaust blowdown is only tracked with an offset. A modified sensor designed to compensate for these temperature effects is also tested. The new sensor has shown significant potential as a compact, durable sensor, which does not require external cooling.

An optical method for measuring exhaust gas pressure from an internal combustion engine at high speed.

PubMed

Leach, Felix C P; Davy, Martin H; Siskin, Dmitrij; Pechstedt, Ralf; Richardson, David

2017-12-01

Measurement of exhaust gas pressure at high speed in an engine is important for engine efficiency, computational fluid dynamics analysis, and turbocharger matching. Currently used piezoresistive sensors are bulky, require cooling, and have limited lifetimes. A new sensor system uses an interferometric technique to measure pressure by measuring the size of an optical cavity, which varies with pressure due to movement of a diaphragm. This pressure measurement system has been used in gas turbine engines where the temperatures and pressures have no significant transients but has never been applied to an internal combustion engine before, an environment where both temperature and pressure can change rapidly. This sensor has been compared with a piezoresistive sensor representing the current state-of-the-art at three engine operating points corresponding to both light load and full load. The results show that the new sensor can match the measurements from the piezoresistive sensor except when there are fast temperature swings, so the latter part of the pressure during exhaust blowdown is only tracked with an offset. A modified sensor designed to compensate for these temperature effects is also tested. The new sensor has shown significant potential as a compact, durable sensor, which does not require external cooling.

The MHOST finite element program: 3-D inelastic analysis methods for hot section components. Volume 3: Systems' manual

NASA Technical Reports Server (NTRS)

Nakazawa, Shohei

1989-01-01

The internal structure is discussed of the MHOST finite element program designed for 3-D inelastic analysis of gas turbine hot section components. The computer code is the first implementation of the mixed iterative solution strategy for improved efficiency and accuracy over the conventional finite element method. The control structure of the program is covered along with the data storage scheme and the memory allocation procedure and the file handling facilities including the read and/or write sequences.

Interactive Finite Elements for General Engine Dynamics Analysis

NASA Technical Reports Server (NTRS)

Adams, M. L.; Padovan, J.; Fertis, D. G.

1984-01-01

General nonlinear finite element codes were adapted for the purpose of analyzing the dynamics of gas turbine engines. In particular, this adaptation required the development of a squeeze-film damper element software package and its implantation into a representative current generation code. The ADINA code was selected because of prior use of it and familiarity with its internal structure and logic. This objective was met and the results indicate that such use of general purpose codes is viable alternative to specialized codes for general dynamics analysis of engines.

Analysis of transient fission gas behaviour in oxide fuel using BISON and TRANSURANUS

NASA Astrophysics Data System (ADS)

Barani, T.; Bruschi, E.; Pizzocri, D.; Pastore, G.; Van Uffelen, P.; Williamson, R. L.; Luzzi, L.

2017-04-01

The modelling of fission gas behaviour is a crucial aspect of nuclear fuel performance analysis in view of the related effects on the thermo-mechanical performance of the fuel rod, which can be particularly significant during transients. In particular, experimental observations indicate that substantial fission gas release (FGR) can occur on a small time scale during transients (burst release). To accurately reproduce the rapid kinetics of the burst release process in fuel performance calculations, a model that accounts for non-diffusional mechanisms such as fuel micro-cracking is needed. In this work, we present and assess a model for transient fission gas behaviour in oxide fuel, which is applied as an extension of conventional diffusion-based models to introduce the burst release effect. The concept and governing equations of the model are presented, and the sensitivity of results to the newly introduced parameters is evaluated through an analytic sensitivity analysis. The model is assessed for application to integral fuel rod analysis by implementation in two structurally different fuel performance codes: BISON (multi-dimensional finite element code) and TRANSURANUS (1.5D code). Model assessment is based on the analysis of 19 light water reactor fuel rod irradiation experiments from the OECD/NEA IFPE (International Fuel Performance Experiments) database, all of which are simulated with both codes. The results point out an improvement in both the quantitative predictions of integral fuel rod FGR and the qualitative representation of the FGR kinetics with the transient model relative to the canonical, purely diffusion-based models of the codes. The overall quantitative improvement of the integral FGR predictions in the two codes is comparable. Moreover, calculated radial profiles of xenon concentration after irradiation are investigated and compared to experimental data, illustrating the underlying representation of the physical mechanisms of burst release.

Harmonization of initial estimates of shale gas life cycle greenhouse gas emissions for electric power generation.

PubMed

Heath, Garvin A; O'Donoughue, Patrick; Arent, Douglas J; Bazilian, Morgan

2014-08-05

Recent technological advances in the recovery of unconventional natural gas, particularly shale gas, have served to dramatically increase domestic production and reserve estimates for the United States and internationally. This trend has led to lowered prices and increased scrutiny on production practices. Questions have been raised as to how greenhouse gas (GHG) emissions from the life cycle of shale gas production and use compares with that of conventionally produced natural gas or other fuel sources such as coal. Recent literature has come to different conclusions on this point, largely due to differing assumptions, comparison baselines, and system boundaries. Through a meta-analytical procedure we call harmonization, we develop robust, analytically consistent, and updated comparisons of estimates of life cycle GHG emissions for electricity produced from shale gas, conventionally produced natural gas, and coal. On a per-unit electrical output basis, harmonization reveals that median estimates of GHG emissions from shale gas-generated electricity are similar to those for conventional natural gas, with both approximately half that of the central tendency of coal. Sensitivity analysis on the harmonized estimates indicates that assumptions regarding liquids unloading and estimated ultimate recovery (EUR) of wells have the greatest influence on life cycle GHG emissions, whereby shale gas life cycle GHG emissions could approach the range of best-performing coal-fired generation under certain scenarios. Despite clarification of published estimates through harmonization, these initial assessments should be confirmed through methane emissions measurements at components and in the atmosphere and through better characterization of EUR and practices.

Harmonization of initial estimates of shale gas life cycle greenhouse gas emissions for electric power generation

PubMed Central

Heath, Garvin A.; O’Donoughue, Patrick; Arent, Douglas J.; Bazilian, Morgan

2014-01-01

Recent technological advances in the recovery of unconventional natural gas, particularly shale gas, have served to dramatically increase domestic production and reserve estimates for the United States and internationally. This trend has led to lowered prices and increased scrutiny on production practices. Questions have been raised as to how greenhouse gas (GHG) emissions from the life cycle of shale gas production and use compares with that of conventionally produced natural gas or other fuel sources such as coal. Recent literature has come to different conclusions on this point, largely due to differing assumptions, comparison baselines, and system boundaries. Through a meta-analytical procedure we call harmonization, we develop robust, analytically consistent, and updated comparisons of estimates of life cycle GHG emissions for electricity produced from shale gas, conventionally produced natural gas, and coal. On a per-unit electrical output basis, harmonization reveals that median estimates of GHG emissions from shale gas-generated electricity are similar to those for conventional natural gas, with both approximately half that of the central tendency of coal. Sensitivity analysis on the harmonized estimates indicates that assumptions regarding liquids unloading and estimated ultimate recovery (EUR) of wells have the greatest influence on life cycle GHG emissions, whereby shale gas life cycle GHG emissions could approach the range of best-performing coal-fired generation under certain scenarios. Despite clarification of published estimates through harmonization, these initial assessments should be confirmed through methane emissions measurements at components and in the atmosphere and through better characterization of EUR and practices. PMID:25049378

Optimization of simultaneous tritium–radiocarbon internal gas proportional counting

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bonicalzi, R. M.; Aalseth, C. E.; Day, A. R.

Specific environmental applications can benefit from dual tritium and radiocarbon measurements in a single compound. Assuming typical environmental levels, it is often the low tritium activity relative to the higher radiocarbon activity that limits the dual measurement. In this paper, we explore the parameter space for a combined tritium and radiocarbon measurement using a methane sample mixed with an argon fill gas in low-background proportional counters of a specific design. We present an optimized methane percentage, detector fill pressure, and analysis energy windows to maximize measurement sensitivity while minimizing count time. The final optimized method uses a 9-atm fill ofmore » P35 (35% methane, 65% argon), and a tritium analysis window from 1.5 to 10.3 keV, which stops short of the tritium beta decay endpoint energy of 18.6 keV. This method optimizes tritium counting efficiency while minimizing radiocarbon beta decay interference.« less

Thermodynamic DFT analysis of natural gas.

PubMed

Neto, Abel F G; Huda, Muhammad N; Marques, Francisco C; Borges, Rosivaldo S; Neto, Antonio M J C

2017-08-01

Density functional theory was performed for thermodynamic predictions on natural gas, whose B3LYP/6-311++G(d,p), B3LYP/6-31+G(d), CBS-QB3, G3, and G4 methods were applied. Additionally, we carried out thermodynamic predictions using G3/G4 averaged. The calculations were performed for each major component of seven kinds of natural gas and to their respective air + natural gas mixtures at a thermal equilibrium between room temperature and the initial temperature of a combustion chamber during the injection stage. The following thermodynamic properties were obtained: internal energy, enthalpy, Gibbs free energy and entropy, which enabled us to investigate the thermal resistance of fuels. Also, we estimated an important parameter, namely, the specific heat ratio of each natural gas; this allowed us to compare the results with the empirical functions of these parameters, where the B3LYP/6-311++G(d,p) and G3/G4 methods showed better agreements. In addition, relevant information on the thermal and mechanic resistance of natural gases were investigated, as well as the standard thermodynamic properties for the combustion of natural gas. Thus, we show that density functional theory can be useful for predicting the thermodynamic properties of natural gas, enabling the production of more efficient compositions for the investigated fuels. Graphical abstract Investigation of the thermodynamic properties of natural gas through the canonical ensemble model and the density functional theory.

Recent applications of gas chromatography with high-resolution mass spectrometry.

PubMed

Špánik, Ivan; Machyňáková, Andrea

2018-01-01

Gas chromatography coupled to high-resolution mass spectrometry is a powerful analytical method that combines excellent separation power of gas chromatography with improved identification based on an accurate mass measurement. These features designate gas chromatography with high-resolution mass spectrometry as the first choice for identification and structure elucidation of unknown volatile and semi-volatile organic compounds. Gas chromatography with high-resolution mass spectrometry quantitative analyses was previously focused on the determination of dioxins and related compounds using magnetic sector type analyzers, a standing requirement of many international standards. The introduction of a quadrupole high-resolution time-of-flight mass analyzer broadened interest in this method and novel applications were developed, especially for multi-target screening purposes. This review is focused on the development and the most interesting applications of gas chromatography coupled to high-resolution mass spectrometry towards analysis of environmental matrices, biological fluids, and food safety since 2010. The main attention is paid to various approaches and applications of gas chromatography coupled to high-resolution mass spectrometry for non-target screening to identify contaminants and to characterize the chemical composition of environmental, food, and biological samples. The most interesting quantitative applications, where a significant contribution of gas chromatography with high-resolution mass spectrometry over the currently used methods is expected, will be discussed as well. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Constraining the volatile fraction of planets from transit observations

NASA Astrophysics Data System (ADS)

Alibert, Y.

2016-06-01

Context. The determination of the abundance of volatiles in extrasolar planets is very important as it can provide constraints on transport in protoplanetary disks and on the formation location of planets. However, constraining the internal structure of low-mass planets from transit measurements is known to be a degenerate problem. Aims: Using planetary structure and evolution models, we show how observations of transiting planets can be used to constrain their internal composition, in particular the amount of volatiles in the planetary interior, and consequently the amount of gas (defined in this paper to be only H and He) that the planet harbors. We first explore planets that are located close enough to their star to have lost their gas envelope. We then concentrate on planets at larger distances and show that the observation of transiting planets at different evolutionary ages can provide statistical information on their internal composition, in particular on their volatile fraction. Methods: We computed the evolution of low-mass planets (super-Earths to Neptune-like) for different fractions of volatiles and gas. We used a four-layer model (core, silicate mantle, icy mantle, and gas envelope) and computed the internal structure of planets for different luminosities. With this internal structure model, we computed the internal and gravitational energy of planets, which was then used to derive the time evolution of the planet. Since the total energy of a planet depends on its heat capacity and density distribution and therefore on its composition, planets with different ice fractions have different evolution tracks. Results: We show for low-mass gas-poor planets that are located close to their central star that assuming evaporation has efficiently removed the entire gas envelope, it is possible to constrain the volatile fraction of close-in transiting planets. We illustrate this method on the example of 55 Cnc e and show that under the assumption of the absence of gas, the measured mass and radius imply at least 20% of volatiles in the interior. For planets at larger distances, we show that the observation of transiting planets at different evolutionary ages can be used to set statistical constraints on the volatile content of planets. Conclusions: These results can be used in the context of future missions like PLATO to better understand the internal composition of planets, and based on this, their formation process and potential habitability.

Surface nanobubbles studied by atomic force microscopy techniques: Facts, fiction, and open questions

NASA Astrophysics Data System (ADS)

Schönherr, Holger; Hain, Nicole; Walczyk, Wiktoria; Wesner, Daniel; Druzhinin, Sergey I.

2016-08-01

In this review surface nanobubbles, which are presumably gas-filled enclosures found at the solid-liquid interface, are introduced and discussed together with key experimental findings that suggest that these nanoscale features indeed exist and are filled with gas. The most prominent technique used thus far has been atomic force microscopy (AFM). However, due to its potentially invasive nature, AFM data must be interpreted with great care. Owing to their curved interface, the Laplace internal pressure of surface nanobubbles exceeds substantially the outside ambient pressure, and the experimentally observed long term stability is in conflict with estimates of gas transport rates and predicted surface nanobubble lifetimes. Despite recent explanations of both the stability and the unusual nanoscopic contact angles, the development of new co-localization approaches and the adequate analysis of AFM data of surface nanobubbles are important as a means to confirm the gaseous nature and correctly estimate the interfacial curvature.

The Ups and Downs of Repeated Cleavage and Internal Fragment Production in Top-Down Proteomics.

PubMed

Lyon, Yana A; Riggs, Dylan; Fornelli, Luca; Compton, Philip D; Julian, Ryan R

2018-01-01

Analysis of whole proteins by mass spectrometry, or top-down proteomics, has several advantages over methods relying on proteolysis. For example, proteoforms can be unambiguously identified and examined. However, from a gas-phase ion-chemistry perspective, proteins are enormous molecules that present novel challenges relative to peptide analysis. Herein, the statistics of cleaving the peptide backbone multiple times are examined to evaluate the inherent propensity for generating internal versus terminal ions. The raw statistics reveal an inherent bias favoring production of terminal ions, which holds true regardless of protein size. Importantly, even if the full suite of internal ions is generated by statistical dissociation, terminal ions are predicted to account for at least 50% of the total ion current, regardless of protein size, if there are three backbone dissociations or fewer. Top-down analysis should therefore be a viable approach for examining proteins of significant size. Comparison of the purely statistical analysis with actual top-down data derived from ultraviolet photodissociation (UVPD) and higher-energy collisional dissociation (HCD) reveals that terminal ions account for much of the total ion current in both experiments. Terminal ion production is more favored in UVPD relative to HCD, which is likely due to differences in the mechanisms controlling fragmentation. Importantly, internal ions are not found to dominate from either the theoretical or experimental point of view. Graphical abstract ᅟ.

The Ups and Downs of Repeated Cleavage and Internal Fragment Production in Top-Down Proteomics

NASA Astrophysics Data System (ADS)

Lyon, Yana A.; Riggs, Dylan; Fornelli, Luca; Compton, Philip D.; Julian, Ryan R.

2018-01-01

Analysis of whole proteins by mass spectrometry, or top-down proteomics, has several advantages over methods relying on proteolysis. For example, proteoforms can be unambiguously identified and examined. However, from a gas-phase ion-chemistry perspective, proteins are enormous molecules that present novel challenges relative to peptide analysis. Herein, the statistics of cleaving the peptide backbone multiple times are examined to evaluate the inherent propensity for generating internal versus terminal ions. The raw statistics reveal an inherent bias favoring production of terminal ions, which holds true regardless of protein size. Importantly, even if the full suite of internal ions is generated by statistical dissociation, terminal ions are predicted to account for at least 50% of the total ion current, regardless of protein size, if there are three backbone dissociations or fewer. Top-down analysis should therefore be a viable approach for examining proteins of significant size. Comparison of the purely statistical analysis with actual top-down data derived from ultraviolet photodissociation (UVPD) and higher-energy collisional dissociation (HCD) reveals that terminal ions account for much of the total ion current in both experiments. Terminal ion production is more favored in UVPD relative to HCD, which is likely due to differences in the mechanisms controlling fragmentation. Importantly, internal ions are not found to dominate from either the theoretical or experimental point of view. [Figure not available: see fulltext.

Internal reforming characteristics of cermet supported solid oxide fuel cell using yttria stabilized zirconia fed with partially reformed methane

NASA Astrophysics Data System (ADS)

Momma, Akihiko; Takano, Kiyonami; Tanaka, Yohei; Negishi, Akira; Kato, Ken; Nozaki, Ken; Kato, Tohru; Ichigi, Takenori; Matsuda, Kazuyuki; Ryu, Takashi

In order to investigate the internal reforming characteristics in a cermet supported solid oxide fuel cell (SOFC) using YSZ as the electrolyte, the concentration profiles of the gaseous species along the gas flow direction in the anode were measured. Partially reformed methane using a pre-reformer kept at a constant temperature is supplied to the center of the cell which is operated with a seal-less structure at the gas outlet. The anode gas is sucked in via silica capillaries to the initially evacuated gas tanks. The process is simultaneously carried out using five sampling ports. The sampled gas is analyzed by a gas chromatograph. Most of the measurements are made at the cell temperature (T cell) of 750 °C and at various temperatures of the pre-reformer (T ref) with various fuel utilizations (U f) of the cell. The composition of the fuel at the inlet of the anode was confirmed to be almost the same as that theoretically calculated assuming equilibrium at the temperature of the pre-reformer. The effect of internal reforming in the anode is clearly observed as a steady decrease in the methane concentration along the flow axis. The effect of the water-gas shift reaction is also observed as a decrease in the CO 2 concentration and an increase of CO concentration around the gas inlet region, as the water-gas shift reaction inversely proceeds when T cell is higher than T ref. The diffusion of nitrogen from the seal-less outermost edge is observed, and the diffusion is confirmed to be more significant as U f decreases. The observations are compared with the results obtained by the SOFC supported by lanthanum gallate electrolyte. With respect to the internal reforming performance, the cell investigated here is found to be more effective when compared to the previously reported electrolyte supported cell.

The Aging of Engines: An Operator’s Perspective

DTIC Science & Technology

2000-10-01

internal HCF failures of blades . Erosion of compressor gas path 2-3 components can be minimized through the use of inlet aluminide intermetallic...fatigue problems in the dovetails durability in accelerated burner rig tests [2,35]. areas of titanium alloy fan and compressor blades . Shot peening in...Criticality Analysis replacement of durability-critical components, such as FOD Foreign object damage blades and vanes. The need to balance risk and escalating

Caspian Sea International Environmental Security Game. Held at Carlisle Barracks, Pennsylvania on 16-17 November 1998

DTIC Science & Technology

1999-07-01

Environmental Security . . . . . . . . . . . . . . . . . . . . 17 Robert E. Ebel Caspian Basin Oil and Gas: An Overview . . . . . . . . . . . 21 Brian R ...choke point near Baku, posing a threat to security of supply. 32 ENVIRONMENTAL BASELINE ANALYSIS OF THE CASPIAN SEA REGION BRIAN R . SHAW TERRY...up to 70% of the seasonal Caspian Sea level. Sources of water include runoff ( R ), precipitation (P), and groundwater flow (G); sink include

Isotopic exchange during derivatization of platelet activating factor for gas chromatography-mass spectrometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Haroldsen, P.E.; Gaskell, S.J.; Weintraub, S.T.

1991-04-01

One approach to the quantitative analysis of platelet activating factor (PAF, 1-O-alkyl-2-acetyl-sn-glycerol-3-phosphocholine; also referred to as AGEPC, alkyl glyceryl ether phosphocholine) is hydrolytic removal of the phosphocholine group and conversion to an electron-capturing derivative for gas chromatography-negative ion mass spectrometry. (2H3)Acetyl-AGEPC has been commonly employed as an internal standard. When 1-hexadecyl-2-(2H3)acetyl glycerol (obtained by enzymatic hydrolysis of (2H3)-C16:0 AGEPC) is treated with pentafluorobenzoyl chloride at 120 degrees C, the resulting 3-pentafluorobenzoate derivative shows extensive loss of the deuterium label. This exchange is evidently acid-catalyzed since derivatization of 1-hexadecyl-2-acetyl glycerol under the same conditions in the presence of a trace ofmore » 2HCl results in the incorporation of up to three deuterium atoms. Isotope exchange can be avoided if the reaction is carried out at low temperature in the presence of base. Direct derivatization of (2H3)-C16:0 AGEPC by treatment with pentafluorobenzoyl chloride or heptafluorobutyric anhydride also results in loss of the deuterium label. The use of (13C2)-C16:0 AGEPC as an internal standard is recommended for rigorous quantitative analysis.« less

Advances in catalysts for internal reforming in high temperature fuel cells

NASA Astrophysics Data System (ADS)

Dicks, A. L.

Catalytic steam reforming of natural gas is an attractive method of producing the hydrogen required by the present generation of fuel cells. The molten carbonate (MCFC) and solid oxide (SOFC) fuel cells operate at high enough temperatures for the endothermic steam reforming reaction to be carried out within the stack. For the MCFC, the conventional anodes have insufficient activity to catalyse the steam reforming of natural gas. For these cells, internal reforming can be achieved only with the addition of a separate catalyst, preferably located in close proximity to the anode. However, in the so-called `Direct Internal Reforming' configuration, attack from alkali in the MCFC may severely limit catalyst lifetime. In the case of the state-of-the-art SOFC, natural gas can be reformed directly on the nickel cermet anode. However, in the SOFC, temperature variations in the cell caused by the reforming reaction may limit the amount of internal reforming that can be allowed in practice. In addition, some external pre-reforming may be desirable to remove high molecular weight hydrocarbons from the fuel gas, which would otherwise crack to produce elemental carbon. Degradation of the SOFC anode may also be a problem when internal reforming is carried out. This has prompted several research groups to investigate the use of alternative anode materials.

Cytolysin-dependent evasion of lysosomal killing.

PubMed

Håkansson, Anders; Bentley, Colette Cywes; Shakhnovic, Elizabeth A; Wessels, Michael R

2005-04-05

Local host defenses limit proliferation and systemic spread of pathogenic bacteria from sites of mucosal colonization. For pathogens such as streptococci that fail to grow intracellularly, internalization and killing by epithelial cells contribute to the control of bacterial growth and dissemination. Here, we show that group A Streptococcus (GAS), the agent of streptococcal sore throat and invasive soft tissue infections, evades internalization and intracellular killing by pharyngeal epithelial cells. Production of the cholesterol-binding cytotoxin streptolysin O (SLO) prevented internalization of GAS into lysosomes. In striking contrast, GAS rendered defective in production of SLO were internalized directly or rapidly transported into lysosomes, where they were killed by a pH-dependent mechanism. Because SLO is the prototype of cholesterol-dependent cytolysins produced by many Gram-positive bacteria, cytolysin-mediated evasion of lysosomal killing may be a general mechanism to protect such pathogens from clearance by host epithelial cells.

Internal Variability-Generated Uncertainty in East Asian Climate Projections Estimated with 40 CCSM3 Ensembles.

PubMed

Yao, Shuai-Lei; Luo, Jing-Jia; Huang, Gang

2016-01-01

Regional climate projections are challenging because of large uncertainty particularly stemming from unpredictable, internal variability of the climate system. Here, we examine the internal variability-induced uncertainty in precipitation and surface air temperature (SAT) trends during 2005-2055 over East Asia based on 40 member ensemble projections of the Community Climate System Model Version 3 (CCSM3). The model ensembles are generated from a suite of different atmospheric initial conditions using the same SRES A1B greenhouse gas scenario. We find that projected precipitation trends are subject to considerably larger internal uncertainty and hence have lower confidence, compared to the projected SAT trends in both the boreal winter and summer. Projected SAT trends in winter have relatively higher uncertainty than those in summer. Besides, the lower-level atmospheric circulation has larger uncertainty than that in the mid-level. Based on k-means cluster analysis, we demonstrate that a substantial portion of internally-induced precipitation and SAT trends arises from internal large-scale atmospheric circulation variability. These results highlight the importance of internal climate variability in affecting regional climate projections on multi-decadal timescales.

LCA to choose among alternative design solutions: the case study of a new Italian incineration line.

PubMed

Scipioni, A; Mazzi, A; Niero, M; Boatto, T

2009-09-01

At international level LCA is being increasingly used to objectively evaluate the performances of different Municipal Solid Waste (MSW) management solutions. One of the more important waste management options concerns MSW incineration. LCA is usually applied to existing incineration plants. In this study LCA methodology was applied to a new Italian incineration line, to facilitate the prediction, during the design phase, of its potential environmental impacts in terms of damage to human health, ecosystem quality and consumption of resources. The aim of the study was to analyse three different design alternatives: an incineration system with dry flue gas cleaning (without- and with-energy recovery) and one with wet flue gas cleaning. The last two technological solutions both incorporating facilities for energy recovery were compared. From the results of the study, the system with energy recovery and dry flue gas cleaning revealed lower environmental impacts in relation to the ecosystem quality. As LCA results are greatly affected by uncertainties of different types, the second part of the work provides for an uncertainty analysis aimed at detecting the extent output data from life cycle analysis are influenced by uncertainty of input data, and employs both qualitative (pedigree matrix) and quantitative methods (Monte Carlo analysis).

The wire-mesh sensor as a two-phase flow meter

NASA Astrophysics Data System (ADS)

Shaban, H.; Tavoularis, S.

2015-01-01

A novel gas and liquid flow rate measurement method is proposed for use in vertical upward and downward gas-liquid pipe flows. This method is based on the analysis of the time history of area-averaged void fraction that is measured using a conductivity wire-mesh sensor (WMS). WMS measurements were collected in vertical upward and downward air-water flows in a pipe with an internal diameter of 32.5 mm at nearly atmospheric pressure. The relative frequencies and the power spectral density of area-averaged void fraction were calculated and used as representative properties. Independent features, extracted from these properties using Principal Component Analysis and Independent Component Analysis, were used as inputs to artificial neural networks, which were trained to give the gas and liquid flow rates as outputs. The present method was shown to be accurate for all four encountered flow regimes and for a wide range of flow conditions. Besides providing accurate predictions for steady flows, the method was also tested successfully in three flows with transient liquid flow rates. The method was augmented by the use of the cross-correlation function of area-averaged void fraction determined from the output of a dual WMS unit as an additional representative property, which was found to improve the accuracy of flow rate prediction.

World Shale Gas Resources: An Initial Assessment of 14 Regions Outside the United States

EIA Publications

2011-01-01

The Energy Information Administration sponsored Advanced Resources International, Inc., to assess 48 gas shale basins in 32 countries, containing almost 70 shale gas formations. This effort has culminated in the report: World Shale Gas Resources: An Initial Assessment of 14 Regions Outside the United States.

77 FR 21748 - Oil and Gas Trade Mission to Israel

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-11

... DEPARTMENT OF COMMERCE International Trade Administration Oil and Gas Trade Mission to Israel... Foreign Commercial Service (CS), is organizing an Executive-led Oil and Gas Trade Mission to Israel.... The purpose of the mission is to introduce U.S. firms to Israel's rapidly expanding oil and gas market...

46 CFR 58.10-15 - Gas turbine installations.

Code of Federal Regulations, 2010 CFR

2010-10-01

... MACHINERY AND RELATED SYSTEMS Internal Combustion Engine Installations § 58.10-15 Gas turbine installations. (a) Standards. The design, construction, workmanship and tests of gas turbines and their associated... 46 Shipping 2 2010-10-01 2010-10-01 false Gas turbine installations. 58.10-15 Section 58.10-15...

46 CFR 58.10-15 - Gas turbine installations.

Code of Federal Regulations, 2011 CFR

2011-10-01

... MACHINERY AND RELATED SYSTEMS Internal Combustion Engine Installations § 58.10-15 Gas turbine installations. (a) Standards. The design, construction, workmanship and tests of gas turbines and their associated... 46 Shipping 2 2011-10-01 2011-10-01 false Gas turbine installations. 58.10-15 Section 58.10-15...

26 CFR 1.611-2 - Rules applicable to mines, oil and gas wells, and other natural deposits.

Code of Federal Regulations, 2011 CFR

2011-04-01

... other natural deposits. 1.611-2 Section 1.611-2 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES (CONTINUED) Natural Resources § 1.611-2 Rules applicable to mines, oil and gas wells, and other natural deposits. (a) Computation of cost...

Overview of the science activities for the 2002 Mallik gas hydrate production research well program, Mackenzie Delta, N.W.T., Canada

NASA Astrophysics Data System (ADS)

Dallimore, S. R.; Collett, T. S.; Uchida, T.; Weber, M.

2003-04-01

With the completion of scientific studies undertaken as part of the 1998 Mallik 2L-38 gas hydrate research well, an international research site was established for the study of Arctic natural gas hydrates in the Mackenzie Delta of northwestern Canada. Quantitative well log analysis and core studies reveal multiple gas hydrate layers from 890 m to 1106 m depth, exceeding 110 m in total thickness. High gas hydrate saturation values, which in some cases exceed 80% of the pore volume, establish the Mallik gas hydrate field as one of the most concentrated gas hydrate reservoirs in the world. Beginning in December 2001 and continuing to the middle of March 2002, two 1188 m deep science observation wells were drilled and instrumented and a 1166 m deep production research well program was carried out. The program participants include 8 partners; The Geological Survey of Canada (GSC), The Japan National Oil Corporation (JNOC), GeoForschungsZentrum Potsdam (GFZ), United States Geological Survey (USGS), United States Department of the Energy (USDOE), India Ministry of Petroleum and Natural Gas (MOPNG)/Gas Authority of India (GAIL) and the Chevron-BP-Burlington joint venture group. In addition the project has been accepted as part of the International Scientific Continental Drilling Program. The Geological Survey of Canada is coordinating the science program for the project and JAPEX Canada Ltd. acted as the designated operator for the fieldwork. Primary objectives of the research program are to advance fundamental geological, geophysical and geochemical studies of the Mallik gas hydrate field and to undertake advanced production testing of a concentrated gas hydrate reservoir. Full-scale field experiments in the production well monitored the physical behavior of the hydrate deposits in response to depressurization and thermal stimulation. The observation wells facilitated cross-hole tomography and vertical seismic profile experiments (before and after production) as well as the measurement of in situ formation conditions. A wide- ranging science and engineering research program included the collection of gas-hydrate-bearing core samples and downhole geophysical logging. Laboratory and modeling studies undertaken during the field program, and subsequently as part of a post-field research program, will document the sedimentology, physical/petrophysical properties, geochemistry, geophysics, reservoir characteristics and production behavior of the Mallik gas hydrate accumulation. The research team, including some 100 participant scientists from over 20 institutes in 7 countries, expects to publish the scientific results in 2004.

Computation and analysis of backward ray-tracing in aero-optics flow fields.

PubMed

Xu, Liang; Xue, Deting; Lv, Xiaoyi

2018-01-08

A backward ray-tracing method is proposed for aero-optics simulation. Different from forward tracing, the backward tracing direction is from the internal sensor to the distant target. Along this direction, the tracing in turn goes through the internal gas region, the aero-optics flow field, and the freestream. The coordinate value, the density, and the refractive index are calculated at each tracing step. A stopping criterion is developed to ensure the tracing stops at the outer edge of the aero-optics flow field. As a demonstration, the analysis is carried out for a typical blunt nosed vehicle. The backward tracing method and stopping criterion greatly simplify the ray-tracing computations in the aero-optics flow field, and they can be extended to our active laser illumination aero-optics study because of the reciprocity principle.

The Internal Ballistics of an Air Gun

NASA Astrophysics Data System (ADS)

Denny, Mark

2011-02-01

The internal ballistics of a firearm or artillery piece considers the pellet, bullet, or shell motion while it is still inside the barrel. In general, deriving the muzzle speed of a gunpowder firearm from first principles is difficult because powder combustion is fast and it very rapidly raises the temperature of gas (generated by gunpowder deflagration, or burning), which greatly complicates the analysis. A simple case is provided by air guns, for which we can make reasonable approximations that permit a derivation of muzzle speed. It is perhaps surprising that muzzle speed depends upon barrel length (artillerymen debated this dependence for centuries, until it was established experimentally and, later, theoretically ). Here we see that a simple physical analysis, accessible to high school or freshmen undergraduate physics students, not only derives realistic muzzle speed but also shows how it depends upon barrel length.

Development of the Next Generation Gas Trap for the Space Station Internal Thermal Control System

NASA Technical Reports Server (NTRS)

Leimkuehler, Thomas O.; Spelbring, Chris; Reeves, Daniel R.; Holt, James M.

2003-01-01

The current dual-membrane gas trap is designed to remove non-condensed gases (NCG) from the Internal Thermal Control System (ITCS) coolant on board the International Space Station (ISS). To date it has successfully served its purpose of preventing depriming, overspeed, and shutdown of the ITCS pump. However, contamination in the ITCS coolant has adversely affected the gas venting rate and lifetime of the gas trap, warranting a development effort for a next-generation gas trap. Design goals are to meet or exceed the current requirements to (1) include greater operating ranges and conditions, (2) eliminate reliance on the current hydrophilic tube fabrication process, and (3) increase operational life and tolerance to particulate and microbial growth fouling. In addition, the next generation gas trap will essentially be a 'dropin" design such that no modifications to the ITCS pump package assembly (PPA) will be required, and the implementation of the new design will not affect changes to the ITCS operational conditions, interfaces, or software. This paper will present the initial membrane module design and development work which has included (1) a trade study among several conceptual designs, (2) performance modeling of a hydrophobic-only design, and (3) small-scale development test data for the hydrophobic-only design. Testing has shown that the hydrophobic-only design is capable of performing even better than the current dual-membrane design for both steady-state gas removal and gas slug removal.

The U.S. Geological Survey’s Gas Hydrates Project

USGS Publications Warehouse

Ruppel, Carolyn D.

2018-01-17

The Gas Hydrates Project at the U.S. Geological Survey (USGS) focuses on the study of methane hydrates in natural environments. The project is a collaboration between the USGS Energy Resources and the USGS Coastal and Marine Geology Programs and works closely with other U.S. Federal agencies, some State governments, outside research organizations, and international partners. The USGS studies the formation and distribution of gas hydrates in nature, the potential of hydrates as an energy resource, and the interaction between methane hydrates and the environment. The USGS Gas Hydrates Project carries out field programs and participates in drilling expeditions to study marine and terrestrial gas hydrates. USGS scientists also acquire new geophysical data and sample sediments, the water column, and the atmosphere in areas where gas hydrates occur. In addition, project personnel analyze datasets provided by partners and manage unique laboratories that supply state-of-the-art analytical capabilities to advance national and international priorities related to gas hydrates.

Indian oil company joins efforts to reduce methane emissions

NASA Astrophysics Data System (ADS)

Kumar, Mohi

The Oil and Natural Gas Corp, Ltd. (ONGC), headquartered in Dehradun, India, has joined seven U.S. and Canadian oil and natural gas companies as a partner in a U.S. Environmental Protection Agency program to reduce greenhouse gas emissions. EPA's Natural Gas STAR International Program aims to reduce methane emissions from the oil and natural gas sector while delivering more gas to markets around the world. With this partnership, ONGC agrees to implement emissions reduction practices and to submit annual reports on progress achieved; EPA agrees to assist ONGC with training technicians in new cost-effective technologies that will help achieve target emissions. The Natural Gas STAR International Program is administered under the Methane to Markets Partnership, a group of 20 countries and 600 companies across the globe that since 2004 has volunteered to cut methane emissions. More information on EPA's agreement with ONGC can be found at http://www.epa.gov/gasstar/index.htm; information about the Methane to Markets Partnership can be found at http://www.methanetomarkets.org.

Gas-turbine expander power generating systems for internal needs of compressor stations of gas-main pipelines

NASA Astrophysics Data System (ADS)

Shimanov, A. A.; Biryuk, V. V.; Sheludko, L. P.; Shabanov, K. Yu.

2017-08-01

In the framework of this paper, there have been analyzed power station building methods to construct a power station for utilities for gas-main pipelines compressor stations. The application efficiency of turbo expanders in them to expand the power gas of compressor stations' gas compressor units has been shown. New schemes for gas-turbine expander power generating systems have been proposed.

Sonatrach prepares for greater exports of natural gas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Taleb, M.

1993-12-06

Algeria is increasing its capacity to export natural gas in order to reinforce its strong position in the growing international market. The country's reserves are estimated at more than 3.6 trillion cu m. Algerian energy and development policy is based on a rational exploitation of this resource. A liquefield natural gas (LNG) pioneer, Algeria has one of the world's most important LNG production capacities. With a location encouraging export to nearby countries, Algeria has an important place in the world natural gas market and an exclusive role within its trading region. The effort will especially focus on southern Europe. Themore » paper discusses Algeria's growing role in international markets, as well as local markets.« less

Comparison of gas chromatography-combustion-mass spectrometry and gas chromatography-flame ionization detector for the determination of fatty acid methyl esters in biodiesel without specific standards.

PubMed

Sobrado, Laura Alonso; Freije-Carrelo, Laura; Moldovan, Mariella; Encinar, Jorge Ruiz; Alonso, J Ignacio García

2016-07-29

GC-FID has been effectively used as a universal quantification technique for volatile organic compounds for a long time. In most cases, the use of the ECN allows for quantification by GC-FID without external calibration using only the response of a single internal standard. In this paper we compare the performance characteristics of GC-FID with those of post-column (13)C Isotope Dilution GC-Combustion-MS for the absolute quantification of organic compounds without the need for individual standards. For this comparison we have selected the quantification of FAMEs in biodiesel. The selection of the right internal standard was critical for GC-FID even when ECN were considered. On the other hand, the nature of the internal standard was not relevant when GC-Combustion-MS was employed. The proposed method was validated with the analysis of the certified reference material SRM 2772 and comparative data was obtained on real biodiesel samples. The analysis of the SRM 2772 biodiesel provided recoveries in the range 100.6-103.5% and 96.4-103.6% for GC-combustion-MS and GC-FID, respectively. The detection limit for GC-combustion-MS was found to be 4.2ng compound/g of injected sample. In conclusion, the quantitative performance of GC-Combustion-MS compared satisfactorily with that of GC-FID constituting a viable alternative for the quantification of organic compounds without the need for individual standards. Copyright © 2016 Elsevier B.V. All rights reserved.

An innovative acoustic sensor for first in-pile fission gas release determination - REMORA 3 experiment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rosenkrantz, E.; Ferrandis, J. Y.; Augereau, F.

2011-07-01

A fuel rod has been instrumented with a new design of an acoustic resonator used to measure in a non destructive way the internal rod plenum gas mixture composition. This ultrasonic sensor has demonstrated its ability to operate in pile during REMORA 3 irradiation experiment carried out in the OSIRIS Material Testing Reactor (CEA Saclay, France). Due to very severe experimental conditions such as temperature rising up to 150 deg.C and especially, high thermal fluence level up to 3.5 10{sup 19} n.cm{sup 2}, the initial sensor gas speed of sound efficiency measurement was strongly reduced due to the irradiation effectsmore » on the piezo-ceramic properties. Nevertheless, by adding a differential signal processing method to the initial data analysis procedure validated before irradiation, the gas resonance peaks were successfully extracted from the output signal. From these data, the molar fractions variations of helium and fission gas were measured from an adapted Virial state equation. Thus, with this sensor, the kinetics of gas release inside fuel rods could be deduced from the in-pile measurements and specific calculations. These data will also give information about nuclear reaction effect on piezo-ceramics sensor under high neutron and gamma flux. (authors)« less

A dynamically collapsing core and a precursor of a core in a filament supported by turbulent and magnetic pressures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Furuya, Ray S.; Kitamura, Yoshimi; Shinnaga, Hiroko, E-mail: rsf@tokushima-u.ac.jp, E-mail: kitamura@isas.jaxa.jp, E-mail: hiroko.shinnaga@nao.ac.jp

2014-10-01

To study physical properties of the natal filament gas around the cloud core harboring an exceptionally young low-mass protostar GF 9-2, we carried out J = 1-0 line observations of {sup 12}CO, {sup 13}CO, and C{sup 18}O molecules using the Nobeyama 45 m telescope. The mapping area covers ∼ one-fifth of the whole filament. Our {sup 13}CO and C{sup 18}O maps clearly demonstrate that the core formed at the local density maxima of the filament, and the internal motions of the filament gas are totally governed by turbulence with Mach number of ∼2. We estimated the scale height of themore » filament to be H = 0.3-0.7 pc, yielding the central density of n {sub c} = 800-4200 cm{sup –3}. Our analysis adopting an isothermal cylinder model shows that the filament is supported by the turbulent and magnetic pressures against the radial and axial collapse due to self-gravity. Since both the dissipation timescales of the turbulence and the transverse magnetic fields can be comparable to the free-fall time of the filament gas of 10{sup 6} yr, we conclude that the local decay of the supersonic turbulence and magnetic fields made the filament gas locally unstable, hence making the core collapse. Furthermore, we newly detected a gas condensation with velocity width enhancement to ∼0.3 pc southwest of the GF 9-2 core. The condensation has a radius of ∼0.15 pc and an LTE mass of ∼5 M {sub ☉}. Its internal motion is turbulent with Mach number of ∼3, suggesting a gravitationally unbound state. Considering the uncertainties in our estimates, however, we propose that the condensation is a precursor of a cloud core, which would have been produced by the collision of the two gas components identified in the filament.« less

Traits and causes of environmental loss-related chemical accidents in China based on co-word analysis.

PubMed

Wu, Desheng; Song, Yu; Xie, Kefan; Zhang, Baofeng

2018-04-25

Chemical accidents are major causes of environmental losses and have been debated due to the potential threat to human beings and environment. Compared with the single statistical analysis, co-word analysis of chemical accidents illustrates significant traits at various levels and presents data into a visual network. This study utilizes a co-word analysis of the keywords extracted from the Web crawling texts of environmental loss-related chemical accidents and uses the Pearson's correlation coefficient to examine the internal attributes. To visualize the keywords of the accidents, this study carries out a multidimensional scaling analysis applying PROXSCAL and centrality identification. The research results show that an enormous environmental cost is exacted, especially given the expected environmental loss-related chemical accidents with geographical features. Meanwhile, each event often brings more than one environmental impact. Large number of chemical substances are released in the form of solid, liquid, and gas, leading to serious results. Eight clusters that represent the traits of these accidents are formed, including "leakage," "poisoning," "explosion," "pipeline crack," "river pollution," "dust pollution," "emission," and "industrial effluent." "Explosion" and "gas" possess a strong correlation with "poisoning," located at the center of visualization map.

Synthesis of Energetic Polymers.

DTIC Science & Technology

1981-10-15

demonstrated by a single peak in the gc analysis (injector temperature 2500 C). The reaction will be repeated in a different solvent to avoid the formation of...glass column packed with 10% OV-101 on chrom Q, with n-decane as an internal standard. Rates of polymerization were calculated using the assumption...the Kelen-Tudos method. The disappearance of monomer was monitored by gas chromatography, using a glass column packed with 10% OV-101 on Chrom Q

Iraq: Oil and Gas Legislation, Revenue Sharing, and U.S. Policy

DTIC Science & Technology

2007-07-25

production and open to international oil companies or the INOC , and Annex 4 delineated 65 exploration blocks. The KRG posted its analysis of the draft...Oil Company ( INOC ). Under the hydrocarbon framework law, the responsibilities and authorities of the Ministry of Oil and the INOC would be altered...significantly, and the draft Ministry and INOC laws are necessary to ensure proper oversight, accountability, and separation of powers between the two

Iraq: Oil and Gas Legislation, Revenue Sharing, and U.S. Policy

DTIC Science & Technology

2008-04-02

international oil companies or the INOC , and Annex 4 delineated 65 exploration blocks. The KRG posted its analysis of the draft annexes on its website...establish an Iraqi National Oil Company ( INOC ). Under the hydrocarbon framework law, the responsibilities and authorities of the Ministry of Oil and the... INOC would be altered significantly, and the draft Ministry and INOC laws are necessary to ensure proper oversight, accountability, and separation of

49 CFR 193.2631 - Internal corrosion control.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 49 Transportation 3 2011-10-01 2011-10-01 false Internal corrosion control. 193.2631 Section 193... GAS FACILITIES: FEDERAL SAFETY STANDARDS Maintenance § 193.2631 Internal corrosion control. Each component that is subject to internal corrosive attack must be protected from internal corrosion by— (a...

Rarefied-continuum gas dynamics transition for SUMS project

NASA Technical Reports Server (NTRS)

Cheng, Sin-I

1989-01-01

This program is to develop an analytic method for reducing SUMS data for the determination of the undisturbed atmosphere conditions ahead of the shuttle along its descending trajectory. It is divided into an internal flow problem, an external flow problem and their matching conditions. Since the existing method of Direct Simulation Monte Carlo (DSMC) failed completely for the internal flow problem, the emphasis is on the internal flow of a highly non-equilibrium, rarefied air through a short tube of a diameter much less than the gaseous mean free path. A two fluid model analysis of this internal flow problem has been developed and studied with typical results illustrated. A computer program for such an analysis and a technical paper published in Lecture Notes in Physics No. 323 (1989) are included as Appendices 3 and 4. A proposal for in situ determination of the surface accommodation coefficients sigma sub t and sigma e is included in Appendix 5 because of their importance in quantitative data reduction. A two fluid formulation for the external flow problem is included as Appendix 6 and a review article for AIAA on Hypersonic propulsion, much dependent on ambient atmospheric density, is also included as Appendix 7.

Minor isotope safeguards techniques (MIST): Analysis and visualization of gas centrifuge enrichment plant process data using the MSTAR model

NASA Astrophysics Data System (ADS)

Shephard, Adam M.; Thomas, Benjamin R.; Coble, Jamie B.; Wood, Houston G.

2018-05-01

This paper presents a development related to the use of minor isotope safeguards techniques (MIST) and the MSTAR cascade model as it relates to the application of international nuclear safeguards at gas centrifuge enrichment plants (GCEPs). The product of this paper is a derivation of the universal and dimensionless MSTAR cascade model. The new model can be used to calculate the minor uranium isotope concentrations in GCEP product and tails streams or to analyze, visualize, and interpret GCEP process data as part of MIST. Applications of the new model include the detection of undeclared feed and withdrawal streams at GCEPs when used in conjunction with UF6 sampling and/or other isotopic measurement techniques.

Comparison of methods for extraction of ethyl carbamate from alcoholic beverages in gas chromatography/mass spectrometry analysis.

PubMed

Mirzoian, Armen; Mabud, Abdul

2006-01-01

A procedure to analyze ethyl carbamate (EC) by gas chromatography/mass spectrometry was optimized and validated. Deuterated EC (d5-EC) was added to the samples as an internal standard followed by extraction with polystyrene crosslinked polystyrene cartridges using minimal volumes of ethyl acetate. The EC response was measured in selective ion monitoring (SIM) mode and found to be linear in the range between the limit of quantitation (10 micro/L) and 1000 microg/L. EC recoveries varied from 92 to 112%, with the average value of 100 +/- 8%. The procedure compared well (r2 = 0.9970) with the existing AOAC Official Method with the added benefits of minimal solvent usage and reduced matrix interferences.

Determination of clebopride in plasma by capillary gas chromatography-negative-ion chemical ionization mass spectrometry.

PubMed

Robinson, P R; Jones, M D; Maddock, J

1988-11-18

A procedure for the analysis of clebopride in plasma using capillary gas chromatography-negative-ion chemical ionization mass spectrometry has been developed. Employing an ethoxy analogue as internal standard, the two compounds were extracted from basified plasma using dichloromethane. Subsequent reaction with heptafluorobutyryl imidazole produced volatile monoheptafluorobutyryl derivatives whose ammonia negative-ion mass spectra proved ideal for selected-ion monitoring. The recovery of clebopride from plasma at 0.536 nmol/l was found to be 85.5 +/- 0.9% (n = 3) whilst measurement down to 0.268 nmol/l was possible with a coefficient of variation of 7.9%. Plasma levels of the compound are reported in two volunteers following ingestion of 1 mg of clebopride as the malate salt.

Impaired Gas Exchange: Prognostic Clinical Indicators of Short-Term Survival in Children with Acute Respiratory Infection.

PubMed

Pascoal, Lívia Maia; de Oliveira Lopes, Marcos Venícios; Chaves, Daniel Bruno Resende; Beltrão, Beatriz Amorim; Nunes, Marília Mendes; da Silva, Viviane Martins; de Sousa Freire, Vanessa Emille Carvalho

2018-02-10

To establish prognostic indicators of survival for impaired gas exchange (IGE) (00030). Secondary analysis of data from an open prospective cohort developed with a group of 136 children with acute respiratory infection (ARI). On Day 1, IGE (00030) was present in 42.6% of the sample. New cases arose until the last day of evaluation. With regards to defining characteristics, only hypoxemia and abnormal skin color were associated with a higher risk of developing diagnosis. Children with ARI who exhibit hypoxemia and abnormal skin color had a worse prognosis for IGE (00030). Nurses can use the research findings as a predictive marker of the evolution of the patient's health status. © 2018 NANDA International, Inc.

Analysis of Poiseuille Flow Property in Two-Dimensional Mi-cro Channels of Microfluidic Pneumatic Micro-Valve

NASA Astrophysics Data System (ADS)

Yang, Shaohua; Long, Wei; Chen, Yajun

2018-03-01

In this paper, the control mechanism and mathematical description of the microfluidic flow in the microfluidic process of the PDMS membrane type pneumatic micro-valve were studied. The velocity and pressure variation law of the velocity field inside micro valve was analyzed by numerical simulation method. The influence of the two kinds of inlet drive modes on the working effect and the pressure flow characteristics of the pneumatic micro-valve was studied. The structure of the elastic solid valve diaphragm under the dual action of the airway and the liquid channel was analyzed. Deformation and stress distribution. The results show that the gas flow in the gas flow channel under the diaphragm by the vacuum part of the role of the formation of a suction gas vortex, pressure-driven mode was easier under the diaphragm to produce a strong gas vortex, resulting in internal and external pressure to promote diaphragm cut-off liquid channel; In the pressure pneumatic mode, the stress at both ends of the diaphragm was smaller, the membrane was not easy to tear failure.

Heat transfer technology for internal passages of air-cooled blades for heavy-duty gas turbines.

PubMed

Weigand, B; Semmler, K; von Wolfersdorf, J

2001-05-01

The present review paper, although far from being complete, aims to give an overview about the present state of the art in the field of heat transfer technology for internal cooling of gas turbine blades. After showing some typical modern cooled blades, the different methods to enhance heat transfer in the internal passages of air-cooled blades are discussed. The complicated flows occurring in bends are described in detail, because of their increasing importance for modern cooling designs. A short review about testing of cooling design elements is given, showing the interaction of the different cooling features as well. The special focus of the present review has been put on the cooling of blades for heavy-duty gas turbines, which show several differences compared to aero-engine blades.

On the internal structure of relativistic jets collimated by ambient gas pressure

NASA Astrophysics Data System (ADS)

Beskin, V. S.; Chernoglazov, A. V.; Kiselev, A. M.; Nokhrina, E. E.

2017-12-01

Recent progress in very long baseline interferometry (VLBI) observations of relativistic jets outflowing from active galactic nuclei gives us direct information about jet width rjet(l) dependence on the distance l from the 'central engine'. Being the missing link in previous works, this relation opens the possibility of determining the internal structure of a jet. In this article, we consider a relativistic jet submerged in an external medium with finite gas pressure Pext. Neither an external magnetic field nor an infinitely thin current sheet will be assumed. This approach allows us to construct a reasonable solution in which both the magnetic field and the flow velocity vanish at the jet boundary r = rjet. In particular, the connection between external gas pressure and internal structure of a relativistic jet is determined.

26 CFR 1.263A-13 - Oil and gas activities.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 26 Internal Revenue 3 2011-04-01 2011-04-01 false Oil and gas activities. 1.263A-13 Section 1.263A... (CONTINUED) INCOME TAXES (CONTINUED) Items Not Deductible § 1.263A-13 Oil and gas activities. (a) In general... section 263A(g)) of oil or gas property. For this purpose, oil or gas property consists of each separate...

26 CFR 1.263A-13 - Oil and gas activities.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 26 Internal Revenue 3 2014-04-01 2014-04-01 false Oil and gas activities. 1.263A-13 Section 1.263A... (CONTINUED) INCOME TAXES (CONTINUED) Items Not Deductible § 1.263A-13 Oil and gas activities. (a) In general... section 263A(g)) of oil or gas property. For this purpose, oil or gas property consists of each separate...

26 CFR 1.263A-13 - Oil and gas activities.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 26 Internal Revenue 3 2012-04-01 2012-04-01 false Oil and gas activities. 1.263A-13 Section 1.263A... (CONTINUED) INCOME TAXES (CONTINUED) Items Not Deductible § 1.263A-13 Oil and gas activities. (a) In general... section 263A(g)) of oil or gas property. For this purpose, oil or gas property consists of each separate...

26 CFR 1.263A-13 - Oil and gas activities.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 26 Internal Revenue 3 2013-04-01 2013-04-01 false Oil and gas activities. 1.263A-13 Section 1.263A... (CONTINUED) INCOME TAXES (CONTINUED) Items Not Deductible § 1.263A-13 Oil and gas activities. (a) In general... section 263A(g)) of oil or gas property. For this purpose, oil or gas property consists of each separate...

Alternative Fuels Data Center: How Do Bi-fuel Natural Gas Vehicles Work?

Science.gov Websites

AddThis.com... How Do Bi-fuel Natural Gas Vehicles Work? A bi-fuel natural gas vehicle can use either gasoline or natural gas in the same internal combustion engine. Both fuels are stored on board and the driver Components of a Bi-fuel Natural Gas Vehicle Battery: The battery provides electricity to start the engine and

Fracture mechanics analysis of NGV fuel cylinders. Part 1: Steel cylinders

NASA Astrophysics Data System (ADS)

Connolly, M. P.; Hudak, S. J.; Roy, S.

1993-02-01

Compressed natural gas (CNG) cylinders for natural gas vehicles (NGVs) are subject to a combination of pressure cycles, associated with periodic refueling, and a potentially corrosive CNG environment. Under these conditions it has been shown that the life of the cylinder is governed by the corrosion-fatigue crack growth of internal flaws such as voids, pits or folds that may be present after manufacture. For NGV applications, these cylinders are required to operate for at least 15 years and the report, through a detailed fracture mechanics analysis, describes approaches to achieving the desired life. The analysis shows that a 15 year cylinder life can be obtained by using quality control to ensure that no initial defects greater than 0.045 in. X 0.090 in. exist after manufacture. Alternatively, gas drying can be used at the distribution stations to reduce the detrimental effects of the remaining CNG impurities, and thereby, produce long cylinder lives. The analysis also considers the role of in-service inspection/retest and shows that in-service NDE has little advantage, either technically or economically, for ensuring the fitness-for-service of steel NGV cylinders. The analysis also shows that hydrostatic testing of cylinders, either at manufacture or in service, is ineffective for detecting fatigue cracks and therefore should not be implemented as part of a fitness-for-service plan for NGV fuel cylinders. The issue of cylinder geometry was also considered and the analysis shows that improperly designed flat-bottomed CNG cylinders can result in premature fatigue failures originating at the inner wall in the transition region between the cylinder end and sidewall.

Dioxin analysis by gas chromatography-Fourier transform ion cyclotron resonance mass spectrometry (GC-FTICRMS).

PubMed

Taguchi, Vince Y; Nieckarz, Robert J; Clement, Ray E; Krolik, Stefan; Williams, Robert

2010-11-01

The feasibility of utilizing a gas chromatograph-tandem quadrupole-Fourier transform ion cyclotron resonance mass spectrometer (GC-MS/MS-FTICRMS) to analyze chlorinated-dioxins/furans (CDDs/CDFs) and mixed halogenated dioxins/furans (HDDs/HDFs) was investigated by operating the system in the GC-FTICRMS mode. CDDs/CDFs and mixed HDDs/HDFs could be analyzed at 50,000 to 100,000 resolving power (RP) on the capillary gas chromatographic time scale. Initial experiments demonstrated that 1 pg of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) and 5 pg of 2-bromo-3,7,8-trichlorodibenzo-p-dioxin (BTrCDD) could be detected. The feasibility of utilizing an FTICRMS for screening of CDDs/CDFs, HDDs/HDFs and related compounds was also investigated by analyzing an extract from vegetation exposed to fall-out from an industrial fire. CDDs/CDFs, chlorinated pyrenes and chlorinated tetracenes could be detected from a Kendrick plot analysis of the ultrahigh resolution mass spectra. Mass accuracies were of the order of 0.5 ppm on standards with external mass calibration and 1 ppm on a sample with internal mass calibration. Copyright © 2010 American Society for Mass Spectrometry. Published by Elsevier Inc. All rights reserved.

Evaluation of solar thermal driven cooling system in office buildings in Saudi Arabia

NASA Astrophysics Data System (ADS)

Linjawi, Majid T.; Talal, Qazi; Al-Sulaiman, Fahad A.

2017-11-01

In this study solar driven absorption chiller is used to reduce the peak cooling load in office buildings in Saudi Arabia for different selected cities. The study is conducted for six cities of Abha, Dhahran, Hail, Jeddah, Nejran and Riyadh under three operating durations of 4, 6, and 8 hours using flat plate or evacuated tube collectors. The energy analysis concluded that flat plate collectors are better than evacuated tube collectors. However, the results from economic analysis suggest that while proposing a gas fired absorption chiller will reduce running costs, further reduction by using solar collectors is not feasible because of its high initial cost. At the best case scenario the Net Present Value of a 10 Ton Absorption chiller operated by natural gas boiler and two large flat plate collectors (12m2 each) running for 8 hours/day, 5days/week has a value of 117,000 and Internal Rate of Return (IRR) of 12%. Solar driven absorption chiller could be more feasible if the gas prices increases or the solar collector prices decreases significantly. Finally, government economic incentives and taxes are recommended to provide a boost for the feasibility of such projects.

Liquid rocket engine self-cooled combustion chambers

NASA Technical Reports Server (NTRS)

1977-01-01

Self-cooled combustion chambers are chambers in which the chamber wall temperature is controlled by methods other than fluid flow within the chamber wall supplied from an external source. In such chambers, adiabatic wall temperature may be controlled by use of upstream fluid components such as the injector or a film-coolant ring, or by internal flow of self-contained materials; e.g. pyrolysis gas flow in charring ablators, and the flow of infiltrated liquid metals in porous matrices. Five types of self-cooled chambers are considered in this monograph. The name identifying the chamber is indicative of the method (mechanism) by which the chamber is cooled, as follows: ablative; radiation cooled; internally regenerative (Interegen); heat sink; adiabatic wall. Except for the Interegen and heat sink concepts, each chamber type is discussed separately. A separate and final section of the monograph deals with heat transfer to the chamber wall and treats Stanton number evaluation, film cooling, and film-coolant injection techniques, since these subjects are common to all chamber types. Techniques for analysis of gas film cooling and liquid film cooling are presented.

Gas chromatographic quantitation of underivatized amines in the determination of their octanol-0.1 M sodium hydroxide partition coefficients by the shake-flask method.

PubMed

Grunewald, G L; Pleiss, M A; Gatchell, C L; Pazhenchevsky, R; Rafferty, M F

1984-06-01

The use of gas chromatography (GC) for the determination of 0.1 M sodium hydroxide-octanol partition coefficients (log P) for a wide variety of ethylamines is demonstrated. The conventional shake-flask procedure (SFP) is utilized, with the addition of an internal reference, which is cleanly separated from the desired solute and solvents on a 10% Apiezon L, 2% potassium hydroxide on 80-100 mesh Chromosorb W AW column. The partitioned solute is extracted from the aqueous phase with chloroform and analyzed by GC. The method provides an accurate and highly reproducible means of determining log P values, as demonstrated by the low relative standard errors. The technique is both rapid and extremely versatile. The use of the internal standard method of analysis introduces consistency, since variables like the exact weight of solute are not necessary (unlike the traditional SFP) and the volume of sample injected is not critical. The technique is readily accessible to microgram quantities of solutes, making it ideal for a wide range of volatile, amine-bearing compounds.

Quantitative on-line analysis of sulfur compounds in complex hydrocarbon matrices.

PubMed

Djokic, Marko R; Ristic, Nenad D; Olahova, Natalia; Marin, Guy B; Van Geem, Kevin M

2017-08-04

An improved method for on-line measurement of sulfur containing compounds in complex matrices is presented. The on-line system consists of a specifically designed sampling system connected to a comprehensive two-dimensional gas chromatograph (GC×GC) equipped with two capillary columns (Rtx ® -1 PONA×SGE BPX50), a flame ionization detector (FID) and a sulfur chemiluminescence detector (SCD). The result is an unprecedented sensitivity down to ppm level (1 ppm-w) for various sulfur containing compounds in very complex hydrocarbon matrices. In addition to the GC×GC-SCD, the low molecular weight sulfur containing compounds such as hydrogen sulfide (H 2 S) and carbonyl sulfide (COS) can be analyzed using a thermal conductivity detector of a so-called refinery gas analyzer (RGA). The methodology was extensively tested on a continuous flow pilot plant for steam cracking, in which quantification of sulfur containing compounds in the reactor effluent was carried out using 3-chlorothiophene as internal standard. The GC×GC-FID/-SCD settings were optimized for ppm analysis of sulfur compounds in olefin-rich (ethylene- and propylene-rich) hydrocarbon matrices produced by steam cracking of petroleum feedstocks. Besides that is primarily used for analysis of the hydrocarbon matrix, FID of the GC×GC-FID/-SCD set-up serves to double check the amount of added sulfur internal standard which is crucial for a proper quantification of sulfur compounds. When vacuum gas oil containing 780 ppm-w of elemental sulfur in the form of benzothiophenes and dibenzothiophenes is subjected to steam cracking, the sulfur balance was closed, with 75% of the sulfur contained in the feed is converted to hydrogen sulfide, 13% to alkyl homologues of thiophene while the remaining 12% is present in the form of alkyl homologues of benzothiophenes. The methodology can be applied for many other conversion processes which use sulfur containing feeds such as hydrocracking, catalytic cracking, kerogen evolution, bio-waste pyrolysis, supercritical water treatment, etc. Copyright © 2017 Elsevier B.V. All rights reserved.

On the siting of gases shock-emplaced from internal cavities in basalt

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wiens, R.C.

1988-12-01

Noble gases were extracted by stepped combustion and crushing from basalts which contained gas-filled cavities of controlled sizes prior to shock at 40 GPa. Analysis of fractions enriched and depleted in shock glass from a single sample gave a factor of 2 higher gas abundances in the glass-rich separate. Release patterns were nearly identical, suggesting similar siting (in glass) in both fractions. Crushing of a sample released {approximately}45% of implanted noble gases, but only {approximately}17% of N{sub 2}, indicating that most or all of the noble gas was trapped in vesicles. Analysis by SEM/EDS confirmed the presence of vesicles inmore » glassy areas, with an average diameter of {approximately}10 {mu}m. Samples with relatively large pre-shock cavities were found to consist of up to 70-80% glass locally and generally exhibit greater local shock effects than solid and densely-packed particulate targets at the same shock pressure, though the latter give higher glass emplacement efficiencies. The petrographic results indicate that in situ production of glassy pockets grossly similar to those in the shergottite EETA 79001 is possible from shock reverberations in the vicinity of a vug. However, the siting of the gases points to a more complex scenario, in which SPB gas and melt material were probably injected into EETA 79001.« less

Seismic and structural characterization of the fluid bypass system using 3D and partial stack seismic from passive margin: inside the plumbing system.

NASA Astrophysics Data System (ADS)

Iacopini, David; Maestrelli, Daniele; Jihad, Ali; Bond, Clare; Bonini, Marco

2017-04-01

In recent years enormous attention has been paid to the understanding of the process and mechanism controlling the gas seepage and more generally the fluid expulsion affecting the earth system from onshore to offshore environment. This is because of their demonstrated impact to our environment, climate change and during subsea drilling operation. Several example from active and paleo system has been so far characterized and proposed using subsurface exploration, geophysical and geochemical monitoring technology approaches with the aims to explore what trigger and drive the overpressure necessary maintain the fluid/gas/material expulsion and what are the structure that act as a gateway for gaseous fluid and unconsolidated rock. In this contribution we explore a series of fluid escape structure (ranging from seepage pipes to large blowout pipes structure of km length) using 3D and partial stack seismic data from two distinctive passive margin from the north sea (Loyal field, West Shetland) and the Equatorial Brazil (Ceara' Basin). We will focuses on the characterization of the plumbing system internal architecture and, for selected example, exploring the AVO response (using partial stack) of the internal fluid/unconsolidated rock. The detailed seismic mapping and seismic attributes analysis of the conduit system helped us to recover some detail from the signal response of the chimney internal structures. We observed: (1) small to medium seeps and pipes following structural or sedimentary discontinuities (2) large pipes (probably incipient mud volcanoes) and blowup structures propagating upward irrespective of pre-existing fault by hydraulic fracturing and assisted by the buoyancy of a fluidised and mobilised mud-hydrocarbon mixture. The reflector termination observed inside the main conduits, the distribution of stacked bright reflectors and the AVO analysis suggests an evolution of mechanisms (involving mixture of gas, fluid and probably mud) during pipe birth and development, cycling through classical fluid escape pipes evoking non-Darcy flow to Darcy flow exploiting surrounding permeable bodies (during low fluid recharge period). Limit and uncertainty of the seismic data imaging the internal structure are still controlled by illumination factor, the lateral and vertical resolution (Fresnel. Tuning thickness) and scattering/noise effect of seismic wave when they interact with the plumbing system.

DEMONSTRATION BULLETIN: GAS-PHASE CHEMICAL REDUCTION - ECO LOGIC INTERNATIONAL, INC.

EPA Science Inventory

The patented Eco Logic Process employs a gas-phase reduction reaction of hydrogen with organic and chlorinated organic compounds at elevated temperatures to convert aqueous and oily hazardous contaminants into a hydrocarbon-rich gas product. After passing through a scrubber, the ...

Program Helps To Determine Chemical-Reaction Mechanisms

NASA Technical Reports Server (NTRS)

Bittker, D. A.; Radhakrishnan, K.

1995-01-01

General Chemical Kinetics and Sensitivity Analysis (LSENS) computer code developed for use in solving complex, homogeneous, gas-phase, chemical-kinetics problems. Provides for efficient and accurate chemical-kinetics computations and provides for sensitivity analysis for variety of problems, including problems involving honisothermal conditions. Incorporates mathematical models for static system, steady one-dimensional inviscid flow, reaction behind incident shock wave (with boundary-layer correction), and perfectly stirred reactor. Computations of equilibrium properties performed for following assigned states: enthalpy and pressure, temperature and pressure, internal energy and volume, and temperature and volume. Written in FORTRAN 77 with exception of NAMELIST extensions used for input.

26 CFR 48.4041-21 - Compressed natural gas (CNG).

Code of Federal Regulations, 2010 CFR

2010-04-01

... 26 Internal Revenue 16 2010-04-01 2010-04-01 true Compressed natural gas (CNG). 48.4041-21 Section... natural gas (CNG). (a) Delivery of CNG into the fuel supply tank of a motor vehicle or motorboat—(1) Imposition of tax. Tax is imposed on the delivery of compressed natural gas (CNG) into the fuel supply tank...

30 CFR 250.522 - When do I have to repeat casing diagnostic testing?

Code of Federal Regulations, 2010 CFR

2010-07-01

..., previously on gas lift, has been shut-in or returned to flowing status without gas lift for more than 180... active gas lift are exempt from diagnostic testing. (c) your casing pressure request becomes invalid... percent of its minimum internal yield pressure (MIYP), except for production casings on active gas lift...

26 CFR 48.4041-21 - Compressed natural gas (CNG).

Code of Federal Regulations, 2013 CFR

2013-04-01

... 26 Internal Revenue 16 2013-04-01 2013-04-01 false Compressed natural gas (CNG). 48.4041-21... natural gas (CNG). (a) Delivery of CNG into the fuel supply tank of a motor vehicle or motorboat—(1) Imposition of tax. Tax is imposed on the delivery of compressed natural gas (CNG) into the fuel supply tank...

26 CFR 48.4041-21 - Compressed natural gas (CNG).

Code of Federal Regulations, 2012 CFR

2012-04-01

... 26 Internal Revenue 16 2012-04-01 2012-04-01 false Compressed natural gas (CNG). 48.4041-21... natural gas (CNG). (a) Delivery of CNG into the fuel supply tank of a motor vehicle or motorboat—(1) Imposition of tax. Tax is imposed on the delivery of compressed natural gas (CNG) into the fuel supply tank...

26 CFR 48.4041-21 - Compressed natural gas (CNG).

Code of Federal Regulations, 2011 CFR

2011-04-01

... 26 Internal Revenue 16 2011-04-01 2011-04-01 false Compressed natural gas (CNG). 48.4041-21... natural gas (CNG). (a) Delivery of CNG into the fuel supply tank of a motor vehicle or motorboat—(1) Imposition of tax. Tax is imposed on the delivery of compressed natural gas (CNG) into the fuel supply tank...

Probing Vitamine C, Aspirin and Paracetamol in the Gas Phase: High Resolution Rotational Studies

NASA Astrophysics Data System (ADS)

Mata, S.; Cabezas, C.; Varela, M.; Pena, I.; Nino, A.; López, J. C.; Alonso, J. L.; Grabow, J.-U.

2011-06-01

A solid sample of Vitamin C (m.p. 190°C) vaporized by laser ablation has been investigated in gas phase and characterized through their rotational spectra. Two spectroscopy techniques has been used to obtain the spectra: a new design of broadband chirped pulse Fourier transform microwave spectroscopy with in-phase/quadrature-phase-modulation passage-acquired-coherence technique (IMPACT) and conventional laser ablation molecular beam Fourier transform microwave spectroscopy (LA-MB-FTMW). Up to now, two low-energy conformer have been observed and their rotational constants determined. Ab initio calculations at the MP2/6-311++G (d,p) level of theory predicted rotational constants which helped us to identify these conformers unequivocally. Among the molecules to benefit from the LA-MB-FTMW technique there are common important drugs never observed in the gas phase through rotational spectroscopy. We present here the results on acetyl salicylic acid and acetaminophen (m.p. 136°C), commonly known as aspirin and paracetamol respectively. We have observed two stable conformers of aspirin and two for paracetamol. The internal rotation barrier of the methyl group in aspirin has been determined for both conformers from the analysis of the A-E splittings due to the coupling of internal and overall rotation. J. L. Alonso, C. Pérez, M. E. Sanz, J. C. López, S. Blanco, Phys. Chem. Chem. Phys. 11,617-627 (2009)and references therein

A Mass Computation Model for Lightweight Brayton Cycle Regenerator Heat Exchangers

NASA Technical Reports Server (NTRS)

Juhasz, Albert J.

2010-01-01

Based on a theoretical analysis of convective heat transfer across large internal surface areas, this paper discusses the design implications for generating lightweight gas-gas heat exchanger designs by packaging such areas into compact three-dimensional shapes. Allowances are made for hot and cold inlet and outlet headers for assembly of completed regenerator (or recuperator) heat exchanger units into closed cycle gas turbine flow ducting. Surface area and resulting volume and mass requirements are computed for a range of heat exchanger effectiveness values and internal heat transfer coefficients. Benefit cost curves show the effect of increasing heat exchanger effectiveness on Brayton cycle thermodynamic efficiency on the plus side, while also illustrating the cost in heat exchanger required surface area, volume, and mass requirements as effectiveness is increased. The equations derived for counterflow and crossflow configurations show that as effectiveness values approach unity, or 100 percent, the required surface area, and hence heat exchanger volume and mass tend toward infinity, since the implication is that heat is transferred at a zero temperature difference. To verify the dimensional accuracy of the regenerator mass computational procedure, calculation of a regenerator specific mass, that is, heat exchanger weight per unit working fluid mass flow, is performed in both English and SI units. Identical numerical values for the specific mass parameter, whether expressed in lb/(lb/sec) or kg/(kg/sec), show the dimensional consistency of overall results.

A Mass Computation Model for Lightweight Brayton Cycle Regenerator Heat Exchangers

NASA Technical Reports Server (NTRS)

Juhasz, Albert J.

2010-01-01

Based on a theoretical analysis of convective heat transfer across large internal surface areas, this paper discusses the design implications for generating lightweight gas-gas heat exchanger designs by packaging such areas into compact three-dimensional shapes. Allowances are made for hot and cold inlet and outlet headers for assembly of completed regenerator (or recuperator) heat exchanger units into closed cycle gas turbine flow ducting. Surface area and resulting volume and mass requirements are computed for a range of heat exchanger effectiveness values and internal heat transfer coefficients. Benefit cost curves show the effect of increasing heat exchanger effectiveness on Brayton cycle thermodynamic efficiency on the plus side, while also illustrating the cost in heat exchanger required surface area, volume, and mass requirements as effectiveness is increased. The equations derived for counterflow and crossflow configurations show that as effectiveness values approach unity, or 100 percent, the required surface area, and hence heat exchanger volume and mass tend toward infinity, since the implication is that heat is transferred at a zero temperature difference. To verify the dimensional accuracy of the regenerator mass computational procedure, calculation of a regenerator specific mass, that is, heat exchanger weight per unit working fluid mass flow, is performed in both English and SI units. Identical numerical values for the specific mass parameter, whether expressed in lb/(lb/sec) or kg/ (kg/sec), show the dimensional consistency of overall results.

Guidelines and recommended terms for expression of stable-isotope-ratio and gas-ratio measurement results

USGS Publications Warehouse

Coplen, Tyler B.

2011-01-01

To minimize confusion in the expression of measurement results of stable isotope and gas-ratio measurements, recommendations based on publications of the Commission on Isotopic Abundances and Atomic Weights of the International Union of Pure and Applied Chemistry (IUPAC) are presented. Whenever feasible, entries are consistent with the Système International d'Unités, the SI (known in English as the International System of Units), and the third edition of the International Vocabulary of Basic and General Terms in Metrology (VIM, 3rd edition). The recommendations presented herein are approved by the Commission on Isotopic Abundances and Atomic Weights and are designed to clarify expression of quantities related to measurement of isotope and gas ratios to ensure that quantity equations instead of numerical value equations are used for quantity definitions. Examples of column headings consistent with quantity calculus (also called the algebra of quantities) and examples of various deprecated usages connected with the terms recommended are presented.

Inferring the evolutionary stages of the internal structures of NGC 7538 S and IRS1 from chemistry

NASA Astrophysics Data System (ADS)

Feng, S.; Beuther, H.; Semenov, D.; Henning, Th.; Linz, H.; Mills, E. A. C.; Teague, R.

2016-09-01

Context. Radiative feedback of young (proto)stars and gas dynamics including gravitational collapse and outflows are important in high-mass star-forming regions (HMSFRs), for the reason that they may leave footprints on the gas density and temperature distributions, the velocity profile, and the chemical abundances. Aims: We unambiguously diagnose the detailed physical mechanisms and the evolutionary status of HMSFRs. Methods: We performed 0.4'' (~1000 AU) resolution observations at 1.37 mm towards two HMSFRs, NGC 7538 S and IRS1, using the Plateau de Bure Interferometre (PdBI). The observations covered abundant molecular lines, including tracers of gas column density, hot molecular cores, shocks, and complex organic molecules. We present a joint analysis of the 1.37 mm continuum emission and the line intensity of 15 molecular species (including 22 isotopologues). Assuming local thermal equilibrium (LTE), we derived molecular column densities and molecular abundances for each internal gas substructure that is spatially resolved. These derived quantities are compared with a suite of 1D gas-grain models. Results: NGC 7538 S is resolved into at least three dense gas condensations. Despite the comparable continuum intensity of these condensations, their differing molecular line emission is suggestive of an overall chemical evolutionary trend from the northeast to the southwest. Line emission from MM1 is consistent with a chemically evolved hot molecular core (HMC), whereas MM3 remains a prestellar candidate that only exhibits emission of lower-excitation lines. The condensation MM2, located between MM1 and MM3, shows an intermediate chemical evolutionary status. Since these three condensations are embedded within the same parent gas core, their differing chemical properties are most likely due to the different warm-up histories, rather than the different dynamic timescales. Despite remaining spatially unresolved, in IRS1 we detect abundant complex organic molecules (e.g. NH2CHO, CH3OH, HCOOCH3, CH3OCH3), indicating that IRS1 is the most chemically evolved HMC presented here. We observe a continuum that is dominated by absorption features with at least three strong emission lines, potentially from CH3OH. The CH3OH lines which are purely in emission have higher excitation than the ones being purely in absorption. Potential reasons for this difference are discussed. Conclusions: This is the first comprehensive comparison of observations of the two high-mass cores NGC 7538 S and IRS1 and a chemical model. We have found that different chemical evolutionary stages can coexist in the same natal gas core. Our achievement illustrates the strength of chemical analysis for understanding HMSFRs.

Stereo-selective partitioning of translation-to-internal energy conversion in gas ensembles

DOE Office of Scientific and Technical Information (OSTI.GOV)

McCaffery, Anthony J., E-mail: A.J.McCaffery@sussex.ac.uk

2014-11-07

A recent computational study of translation-to-internal energy transfer to H{sub 2} (v = 0,j = 0), hereinafter denoted H{sub 2} (0;0), in a bath of H atoms [A. J. McCaffery and R. J. Marsh, J. Chem. Phys. 139, 234310 (2013)] revealed an unexpected energy partitioning in which the H{sub 2} vibrational temperature greatly exceeds that of rotation. This occurs despite rotation and vibration distributions being close to Boltzmann from early in ensemble evolution. In this work, the study is extended to include H{sub 2} (0;0), O{sub 2} (0;0), and HF (0;0) in a wide range of atomic bath gases comprisingmore » some 22 ensembles in all. Translation-to-internal energy conversion in the systems studied was found to be relatively inefficient, falling approximately with (√μ′){sup −1} as bath gas mass increases, where μ′ is the reduced mass of the diatomic–bath gas pair. In all 22 systems studied, T{sub v} exceeds T{sub r} – by a factor > 4 for some pairs. Analysis of the constraints that influence (0;0) → (1;j) excitation for each diatomic–atom pair in momentum–angular momentum space demonstrates that a vibrational preference results from energy constraints that limit permitted collision trajectories to those of low effective impact parameter, i.e., to those that are axial or near axial on impact with the Newton surface. This implies that a steric constraint is an inherent feature of vibration-rotation excitation and arises because momentum and energy barriers must be overcome before rotational states may be populated in the higher vibrational level.« less

Analysis and simulation of the I C engine Otto cycle using the second law of thermodynamics

NASA Astrophysics Data System (ADS)

Abdel-Rahim, Y. M.

The present investigation is an application of the second law of thermodynamics to the spark ignition engine cycle. A comprehensive thermodynamic analysis of the air standard cycle is conducted using the first and second laws of thermodynamics, the ideal gas equation of state and the perfect gas properties for air. The study investigates the effect of the cycle parameters on the cycle performance reflected by the first and second law efficiencies, the heat added, the work done, the available energy added as well as the history of the internal, available and unavailable energies along the cycle. The study shows that the second law efficiency is a function of the compression ratio, the initial temperature, the maximum temperature as well as the dead state temperature. A non-dimensional comprehensive thermodynamic simulation model for the actual Otto cycle is developed to study the effects of the design and operating parameters of the cycle on the cycle performance. The analysis takes into account engine geometry, mixture strength, heat transfer, piston motion, engine speed, mechanical friction, spark advance and combustion duration.

CVD aluminiding process for producing a modified platinum aluminide bond coat for improved high temperature performance

NASA Technical Reports Server (NTRS)

Nagaraj, Bangalore A. (Inventor); Williams, Jeffrey L. (Inventor)

2003-01-01

A method of depositing by chemical vapor deposition a modified platinum aluminide diffusion coating onto a superalloy substrate comprising the steps of applying a layer of a platinum group metal to the superalloy substrate; passing an externally generated aluminum halide gas through an internal gas generator which is integral with a retort, the internal gas generator generating a modified halide gas; and co-depositing aluminum and modifier onto the superalloy substrate. In one form, the modified halide gas is hafnium chloride and the modifier is hafnium with the modified platinum aluminum bond coat comprising a single phase additive layer of platinum aluminide with at least about 0.5 percent hafnium by weight percent and about 1 to about 15 weight percent of hafnium in the boundary between a diffusion layer and the additive layer. The bond coat produced by this method is also claimed.

Internal Surface Adsorption of Methane in the Microporous and the Mesoporous Montmorillonite Models

NASA Astrophysics Data System (ADS)

Shao, Changjin; Nie, Dakai; Zhai, Zengqiang; Yang, Zhenqing

2018-05-01

Due to the rising worldwide energy demands and the shortage of natural gas resources, the development of shale gas has become the new research focus in the field of novel energy resources. To understand the adsorption mechanism of shale gas in the reservoir, we use grand canonical Monte Carlo (GCMC) method to investigate the internal surface adsorption behavior of methane (main component of shale gas) in microporous and mesoporous montmorillonite materials for changing pressure, temperature and surface spacing. The results show that the adsorption capacity of methane decreases with increasing temperature while increasing as the surface spacing increases. Especially, the adsorption isotherm of the microporous model has a mutation when the surface spacing is about 10 ˚A. According to the trend for the change in the adsorption capacity, the best scheme for the exploitation of shale gas can be selected so that the mining efficiency is greatly improved.

Compensation of matrix effects in gas chromatography-mass spectrometry analysis of pesticides using a combination of matrix matching and multiple isotopically labeled internal standards.

PubMed

Tsuchiyama, Tomoyuki; Katsuhara, Miki; Nakajima, Masahiro

2017-11-17

In the multi-residue analysis of pesticides using GC-MS, the quantitative results are adversely affected by a phenomenon known as the matrix effect. Although the use of matrix-matched standards is considered to be one of the most practical solutions to this problem, complete removal of the matrix effect is difficult in complex food matrices owing to their inconsistency. As a result, residual matrix effects can introduce analytical errors. To compensate for residual matrix effects, we have developed a novel method that employs multiple isotopically labeled internal standards (ILIS). The matrix effects of ILIS and pesticides were evaluated in spiked matrix extracts of various agricultural commodities, and the obtained data were subjected to simple statistical analysis. Based on the similarities between the patterns of variation in the analytical response, a total of 32 isotopically labeled compounds were assigned to 338 pesticides as internal standards. It was found that by utilizing multiple ILIS, residual matrix effects could be effectively compensated. The developed method exhibited superior quantitative performance compared with the common single-internal-standard method. The proposed method is more feasible for regulatory purposes than that using only predetermined correction factors and is considered to be promising for practical applications. Copyright © 2017 Elsevier B.V. All rights reserved.

Lessons Learned From the Analysis of the SAFOD Downhole Instrument Package.

NASA Astrophysics Data System (ADS)

Johnson, Wade; Mencin, David; Mattioli, Glen

2013-04-01

In September of 2008 a downhole instrument package (DIP) consisting of a string of seismometers and tilt meters in isolated pressure vessels (PODs) was installed in the SAFOD main borehole. This package was designed to protect the sensors from the corrosive borehole environment and to operate for two years. The SAFOD borehole is not sealed at the bottom allowing borehole gasses and fluids infiltratration. Previous short-term installations of instruments in the SAFOD main borehole had also failed as a result of corrosion of the wireline cable head. The average failure time for these installations was two weeks. The use of stainless steel tubing connected to the pressure vessels through gas tight fittings was designed to block borehole fluid and gas infiltration of the individual instruments within the PODs. Unfortunately, the DIP completely failed within a month of its installation. In October of 2010, the DIP was removed from the borehole and a failure analysis was performed. This analysis involved to following steps: 1. Analysis of data to understand timeline of failure 2. Remove instrument safely, maintaining integrity of spliced section and documenting any external clues. Test instrument at surface 3. Open PODs in a way that allows for sampling and avoids damaging instruments. 4. Chemical analysis of fluids recovered from splices and PODs. 5. Instrument failure analysis by the instrument manufacturers. The analysis found that there were several design flaws in the DIP. This included the use of motor oil to take up air space in the individual PODs, use of a large number of gas tight seals, lack of internal seals, poorly done solder joints, use of non-temperature rated sensors, and lack of management oversight. The lessons learned from the attempts to instrument the SAFOD borehole are critical to the success of future deep borehole projects.

1998 Technology Showcase. JOAP International Condition Monitoring Conference.

DTIC Science & Technology

1998-04-01

Systems using Automated SEM/ EDX and New Diagnostic Routines 276 N. W Farrant & T. Luckhurst ADVANCED DIAGNOSTIC SYSTEMS Model-Based Diagnostics of Gas...Microscopy with Energy Dispersive X-Ray (SEM/ EDX ) micro analysis packages and Energy Dispersive X-Ray Fluorescence (EDXRF) analytical equipment. Therqfore...wear particles separated by ferrogram method. a- I WEAR PARTICLE A SLAS 97 (HOME PAGE) Fig I Home Page NONFE;RROUS MATERIAL A wW~ a48 -1, rV fr , ý b

Proceedings of International Pyrotechnics Seminar (4th), Held at Steamboat Village, Colorado, 22-26 July 1974

DTIC Science & Technology

1974-06-17

10-1 I1. Burning Rate Modifiers, D.R. Dillehay ............................. 11-1 12. Spectroscopic Analysis of Azide Decomposition Products for use...solid, and Pit that they ignite a short distance from the surface. Further- more, decomposition of sodium nitrate, which produces the gas to blow the...decreasing U the thermal conductivity of the basic binary. Class 2 compounds, con- sisting of nanganese oxides, catalyze the normal decomposition of

Pore Formation and Mobility Investigation (PPMI): Description and Initial Analysis of Experiments Conducted aboard the International Space Station

NASA Technical Reports Server (NTRS)

Grugel, R. N.; Anilkumar, A. V.; Lee, C. P.

2003-01-01

Flow visualization experiments during the controlled directional melt back and re-solidification of succinonitrile (SCN) and SCN-water mixtures were conducted using the Pore Formation and Mobility Investigation (PFMI) apparatus in the glovebox facility (GBX) aboard the International Space Station. The study samples were initially 'cast' on earth under 450 millibar of nitrogen into 1 cm ID glass sample tubes approximately 30 cm in length, containing 6 in situ thermocouples. During the Space experiments, the processing parameters and flow visualization settings are remotely monitored and manipulated from the ground Telescience Center (TSC). The ground solidified sample is first subjected to a unidirectional melt back, generally at 10 microns per second, with a constant temperature gradient ahead of the melting interface. Bubbles of different sizes are seen to initiate at the melt interface and, upon release from the melting solid, translate at different speeds in the temperature field ahead of them before coming to rest. Over a period of time these bubbles dissolve into the melt. The gas-laden liquid is then directionally solidified in a controlled manner, generally starting at a rate of 1 micron /sec. Observation and preliminary analysis of bubble formation and mobility in pure SCN samples during melt back and the subsequent structure resulting during gas generation upon re-solidification are presented and discussed.

Pore Formation and Mobility Investigation (PFMI): Description and Initial Analysis of Experiments Conducted aboard the International Space Station

NASA Technical Reports Server (NTRS)

Grugel, R. N.; Anilkumar, A. V.; Lee, C. P.

2002-01-01

Flow visualization experiments during the controlled directional melt back and re-solidification of succinonitrile (SCN) and SCN-water mixtures were conducted using the Pore Formation and Mobility Investigation (PFMI) apparatus in the glovebox facility (GBX) aboard the International Space Station. The study samples were initially "cast" on earth under 450 millibar of nitrogen into 1 cm ID glass sample tubes approximately 30 cm in length, containing 6 in situ thermocouples. During the Space experiments, the processing parameters and flow visualization settings are remotely monitored and manipulated from the ground Telescience Center (TSC). The ground solidified sample is first subjected to a unidirectional melt back, generally at 10 microns per second, with a constant temperature gradient ahead of the melting interface. Bubbles of different sizes are seen to initiate at the melt interface and, upon release from the melting solid, translate at different speeds in the temperature field ahead of them before coming to rest. Over a period of time these bubbles dissolve into the melt. The gas-laden liquid is then directionally solidified in a controlled manner, generally starting at a rate of 1 micron /sec. Observation and preliminary analysis of bubble formation and mobility in pure SCN samples during melt back and the subsequent structure resulting during gas generation upon re-solidification are presented and discussed.

11. Photograph of a line drawing. 'CROSS SECTION OF GAS ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

11. Photograph of a line drawing. 'CROSS SECTION OF GAS PRODUCER.' From George R. Cooper (Wilputte Corporation). 'Operating Overview of a Producer Gas Plant (12 Machines) at Kingsport, Tennessee.' Presented at the Fifth Annual International Conference on Coal Gasification, Liquefaction and Conversion to Electricity. University of Pittsburgh, August 2, 1978. - Holston Army Ammunition Plant, Producer Gas Plant, Kingsport, Sullivan County, TN

26 CFR 1.611-2 - Rules applicable to mines, oil and gas wells, and other natural deposits.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 26 Internal Revenue 7 2013-04-01 2013-04-01 false Rules applicable to mines, oil and gas wells....611-2 Rules applicable to mines, oil and gas wells, and other natural deposits. (a) Computation of cost depletion of mines, oil and gas wells, and other natural deposits. (1) The basis upon which cost...

26 CFR 1.611-2 - Rules applicable to mines, oil and gas wells, and other natural deposits.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 26 Internal Revenue 7 2012-04-01 2012-04-01 false Rules applicable to mines, oil and gas wells....611-2 Rules applicable to mines, oil and gas wells, and other natural deposits. (a) Computation of cost depletion of mines, oil and gas wells, and other natural deposits. (1) The basis upon which cost...

Use of exhaust gas as sweep flow to enhance air separation membrane performance

DOEpatents

Dutart, Charles H.; Choi, Cathy Y.

2003-01-01

An intake air separation system for an internal combustion engine is provided with purge gas or sweep flow on the permeate side of separation membranes in the air separation device. Exhaust gas from the engine is used as a purge gas flow, to increase oxygen flux in the separation device without increasing the nitrogen flux.

Gas: MedlinePlus Health Topic

MedlinePlus

... Foods That May Cause Gas (International Foundation for Functional Gastrointestinal Disorders) ... References and abstracts from MEDLINE/PubMed (National Library of Medicine) Article: Daikenchuto for reducing postoperative ileus in patients ...

Nuclear Engine System Simulation (NESS) version 2.0

NASA Technical Reports Server (NTRS)

Pelaccio, Dennis G.; Scheil, Christine M.; Petrosky, Lyman J.

1993-01-01

The topics are presented in viewgraph form and include the following; nuclear thermal propulsion (NTP) engine system analysis program development; nuclear thermal propulsion engine analysis capability requirements; team resources used to support NESS development; expanded liquid engine simulations (ELES) computer model; ELES verification examples; NESS program development evolution; past NTP ELES analysis code modifications and verifications; general NTP engine system features modeled by NESS; representative NTP expander, gas generator, and bleed engine system cycles modeled by NESS; NESS program overview; NESS program flow logic; enabler (NERVA type) nuclear thermal rocket engine; prismatic fuel elements and supports; reactor fuel and support element parameters; reactor parameters as a function of thrust level; internal shield sizing; and reactor thermal model.

(Gas discharges and their applications)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Christophorou, L. G.

1988-10-06

The traveler attended the IX International Conference on Gas Discharges and Their Applications held in Venice, Italy, September 19--23, 1988. He was a member of the International Organizing Committee of the conference, chaired a scientific session, presented a paper, and participated in scientific discussions and the planning of the next conference. Also, he exchanged research information and ideas on electron, ion, and laser interactions in fluid media with many participants.

Influence of forced internal air circulation on airflow distribution and heat transfer in a gas double-dynamic solid-state fermentation bioreactor.

PubMed

Chen, Hongzhang; Qin, Lanzhi; Li, Hongqiang

2014-02-01

Internal air circulation affects the temperature field distribution in a gas double-dynamic solid-state fermentation bioreactor (GDSFB). To enhance heat transfer through strengthening internal air circulation in a GDSFB, we put an air distribution plate (ADP) into the bioreactor and studied the effects of forced internal air circulation on airflow, heat transfer, and cellulase activity of Trichoderma viride L3. Results showed that ADP could help form a steady and uniform airflow distribution, and with gas-guide tubes, air reversal was formed inside the bioreactor, thus resulting in a smaller temperature difference between medium and air by enhancing convective heat transfer inside the bioreactor. Using an ADP of 5.35 % aperture ratio caused a 1 °C decrease in the average temperature difference during the solid-state fermentation process of T. viride L3. Meanwhile, the cellulase activity of T. viride L3 increased by 13.5 %. The best heat-transfer effect was attained when using an ADP of 5.35 % aperture ratio and setting the fan power to 125 V (4.81 W) in the gas double-dynamic solid-state fermentation (GDSF) process. An option of suitable aperture ratio and fan power may be conducive to ADPs' industrial amplification.

Life cycle comparison of fuel cell vehicles and internal combustion engine vehicles for Canada and the United States

NASA Astrophysics Data System (ADS)

Zamel, Nada; Li, Xianguo

The objective of this study is to put forward a full analysis of the impact of the difference between the Canadian and American energy realities on the life cycle of fuel cell vehicles and internal combustion engine vehicles. Electricity is a major type of energy used in the transportation sector. Electricity is needed in the production of feedstock of fuel, the production of the fuel, the production of the vehicle material and the assembly of the vehicles. Therefore, it is necessary to investigate the impact of the electricity mix difference between Canada and the United States. In the analysis, the life cycle of the fuel consists of obtaining the raw material, extracting the fuel from the raw material, transporting and storing the fuel as well as using the fuel in the vehicle. Four different methods of obtaining hydrogen were analyzed; using coal and nuclear power to produce electricity and extract hydrogen through electrolysis and via steam reforming of natural gas in a natural gas plant and in a hydrogen refueling station. It is found that fuel cell vehicle fuelled by hydrogen has lower energy consumption and greenhouse gas emissions than internal combustion engine vehicle fuelled by conventional gasoline except for hydrogen production using coal as the primary energy source in Canada and the United States. Using the Canadian electricity mix will result in lower carbon dioxide emissions and energy consumption than using the American electricity mix. For the present vehicles, using the Canadian electricity mix will save up to 215.18 GJ of energy and 20.87 t of CO 2 on a per capita basis and 26.53 GJ of energy and 6.8 t of CO 2 on a per vehicle basis. Similarly, for the future vehicles, using the Canadian electricity mix will lower the total carbon dioxide emissions by 21.15 t and the energy consumed is reduced by 218.49 GJ on a per capita basis and 26.53 GJ of energy and 7.22 t of CO 2 on a per vehicle basis. The well-to-tank efficiencies are higher with the Canadian electricity mix.

Institutional practices and policies in acid-base testing: a self reported Croatian survey study on behalf of the Croatian society of medical biochemistry and laboratory medicine Working Group for acid-base balance.

PubMed

Dukić, Lora; Simundić, Ana-Maria

2014-01-01

The aim of this survey study was to assess the current practices and policies in use related to the various steps in the blood gas testing process, across hospital laboratories in Croatia. First questionnaire was sent by email to all medical biochemistry laboratories (N = 104) within general, specialized and clinical hospitals and university hospital centres to identify laboratories which perform blood gas analysis. Second questionnaire with detailed questions about sample collection, analysis and quality control procedures, was sent only to 47 laboratories identified by the first survey. Questionnaire was designed as combination of questions and statements with Likert scale. Third questionnaire was sent to all participating laboratories (N=47) for additional clarification for either indeterminate or unclear answers. Blood gas analysis is performed in 47/104 hospital laboratories in Croatia. In 25/41 (0.61) of the laboratories capillary blood gas sampling is the preferred sample type for adult patient population, whereas arterial blood sample is preferentially used in only 5/44 laboratories (0.11). Blood sampling and sample processing for capillary samples is done almost always by laboratory technicians (36/41 and 37/44, respectively), whereas arterial blood sampling is almost always done by the physician (24/29) and only rarely by a nurse (5/28). Sample acceptance criteria and sample analysis are in accordance with international recommendations for majority of laboratories. 43/44 laboratories participate in the national EQA program. POCT analyzers are installed outside of the laboratory in 20/47 (0.43) institutions. Laboratory staff is responsible for education and training of ward personnel, quality control and instrument maintenance in only 12/22, 11/20 and 9/20 institutions, respectively. Practices related to collection and analysis for blood gases in Croatia are not standardised and vary substantially between laboratories. POCT analyzers are not under the direct supervision by laboratory personnel in a large proportion of surveyed institutions. Collective efforts should be made to harmonize and improve policies and procedures related to blood gas testing in Croatian laboratories.

Computational simulation and aerodynamic sensitivity analysis of film-cooled turbines

NASA Astrophysics Data System (ADS)

Massa, Luca

A computational tool is developed for the time accurate sensitivity analysis of the stage performance of hot gas, unsteady turbine components. An existing turbomachinery internal flow solver is adapted to the high temperature environment typical of the hot section of jet engines. A real gas model and film cooling capabilities are successfully incorporated in the software. The modifications to the existing algorithm are described; both the theoretical model and the numerical implementation are validated. The accuracy of the code in evaluating turbine stage performance is tested using a turbine geometry typical of the last stage of aeronautical jet engines. The results of the performance analysis show that the predictions differ from the experimental data by less than 3%. A reliable grid generator, applicable to the domain discretization of the internal flow field of axial flow turbine is developed. A sensitivity analysis capability is added to the flow solver, by rendering it able to accurately evaluate the derivatives of the time varying output functions. The complex Taylor's series expansion (CTSE) technique is reviewed. Two of them are used to demonstrate the accuracy and time dependency of the differentiation process. The results are compared with finite differences (FD) approximations. The CTSE is more accurate than the FD, but less efficient. A "black box" differentiation of the source code, resulting from the automated application of the CTSE, generates high fidelity sensitivity algorithms, but with low computational efficiency and high memory requirements. New formulations of the CTSE are proposed and applied. Selective differentiation of the method for solving the non-linear implicit residual equation leads to sensitivity algorithms with the same accuracy but improved run time. The time dependent sensitivity derivatives are computed in run times comparable to the ones required by the FD approach.

Structure and stability of clusters of β-alanine in the gas phase: importance of the nature of intermolecular interactions.

PubMed

Piekarski, Dariusz Grzegorz; Díaz-Tendero, Sergio

2017-02-15

We present a theoretical study of neutral clusters of β-alanine molecules in the gas phase, (β-ala) n n ≤ 5. Classical molecular dynamics simulations carried out with different internal excitation energies provide information on the clusters formation and their thermal decomposition limits. We also present an assessment study performed with different families of density functionals using the dimer, (β-ala) 2 , as a benchmark system. The M06-2X functional provides the best agreement in geometries and relative energies in comparison with the reference values computed with the MP2 and CCSD(T) methods. The structure, stability, dissociation energies and vertical ionization potentials of the studied clusters have been investigated using this functional in combination with the 6-311++G(d,p) basis set. An exhaustive analysis of intermolecular interactions is also presented. These results provide new insights into the stability, interaction nature and formation mechanisms of clusters of amino acids in the gas phase.

Calculating the Optimum Angle of Filament-Wound Pipes in Natural Gas Transmission Pipelines Using Approximation Methods.

PubMed

Reza Khoshravan Azar, Mohammad; Emami Satellou, Ali Akbar; Shishesaz, Mohammad; Salavati, Bahram

2013-04-01

Given the increasing use of composite materials in various industries, oil and gas industry also requires that more attention should be paid to these materials. Furthermore, due to variation in choice of materials, the materials needed for the mechanical strength, resistance in critical situations such as fire, costs and other priorities of the analysis carried out on them and the most optimal for achieving certain goals, are introduced. In this study, we will try to introduce appropriate choice for use in the natural gas transmission composite pipelines. Following a 4-layered filament-wound (FW) composite pipe will consider an offer our analyses under internal pressure. The analyses' results will be calculated for different combinations of angles 15 deg, 30 deg, 45 deg, 55 deg, 60 deg, 75 deg, and 80 deg. Finally, we will compare the calculated values and the optimal angle will be gained by using the Approximation methods. It is explained that this layering is as the symmetrical.

Hyperfine structure of the MnH X 7Sigma + state: A large gas-to-matrix shift in the Fermi contact interaction

NASA Astrophysics Data System (ADS)

Varberg, Thomas D.; Field, Robert W.; Merer, Anthony J.

1990-06-01

Sub-Doppler spectra of the A 7Π-X 7Σ+ (0,0) band of gas phase MnH near 5680 Å were recorded by intermodulated fluorescence spectroscopy. The spectra reveal hyperfine splittings arising from both the 55Mn and 1H nuclear spins. Internal hyperfine perturbations have been observed between the different spin components of the ground state at low N`. From a preliminary analysis of several rotational lines originating from the isolated and unperturbed F1(J`=3) spin component of the X 7Σ+(N`=0) level, the 55Mn Fermi contact interaction in the ground state has been measured as bF=Aiso =276(1) MHz. This value is 11% smaller than the value obtained by Weltner et al. from an electron-nuclear double resonance (ENDOR) study of MnH in an argon matrix at 4 K. This unprecedented gas-to-matrix shift in the Fermi contact parameter is discussed.

Cycle analysis of MCFC/gas turbine system

NASA Astrophysics Data System (ADS)

Musa, Abdullatif; Alaktiwi, Abdulsalam; Talbi, Mosbah

2017-11-01

High temperature fuel cells such as the solid oxide fuel cell (SOFC) and the molten carbonate fuel cell (MCFC) are considered extremely suitable for electrical power plant application. The molten carbonate fuel cell (MCFC) performances is evaluated using validated model for the internally reformed (IR) fuel cell. This model is integrated in Aspen Plus™. Therefore, several MCFC/Gas Turbine systems are introduced and investigated. One of this a new cycle is called a heat recovery (HR) cycle. In the HR cycle, a regenerator is used to preheat water by outlet air compressor. So the waste heat of the outlet air compressor and the exhaust gases of turbine are recovered and used to produce steam. This steam is injected in the gas turbine, resulting in a high specific power and a high thermal efficiency. The cycles are simulated in order to evaluate and compare their performances. Moreover, the effects of an important parameters such as the ambient air temperature on the cycle performance are evaluated. The simulation results show that the HR cycle has high efficiency.

Performance, Efficiency, and Emissions Characterization of Reciprocating Internal Combustion Engines Fueled with Hydrogen/Natural Gas Blends

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kirby S. Chapman; Amar Patil

2007-06-30

Hydrogen is an attractive fuel source not only because it is abundant and renewable but also because it produces almost zero regulated emissions. Internal combustion engines fueled by compressed natural gas (CNG) are operated throughout a variety of industries in a number of mobile and stationary applications. While CNG engines offer many advantages over conventional gasoline and diesel combustion engines, CNG engine performance can be substantially improved in the lean operating region. Lean operation has a number of benefits, the most notable of which is reduced emissions. However, the extremely low flame propagation velocities of CNG greatly restrict the leanmore » operating limits of CNG engines. Hydrogen, however, has a high flame speed and a wide operating limit that extends into the lean region. The addition of hydrogen to a CNG engine makes it a viable and economical method to significantly extend the lean operating limit and thereby improve performance and reduce emissions. Drawbacks of hydrogen as a fuel source, however, include lower power density due to a lower heating value per unit volume as compared to CNG, and susceptibility to pre-ignition and engine knock due to wide flammability limits and low minimum ignition energy. Combining hydrogen with CNG, however, overcomes the drawbacks inherent in each fuel type. Objectives of the current study were to evaluate the feasibility of using blends of hydrogen and natural gas as a fuel for conventional natural gas engines. The experiment and data analysis included evaluation of engine performance, efficiency, and emissions along with detailed in-cylinder measurements of key physical parameters. This provided a detailed knowledge base of the impact of using hydrogen/natural gas blends. A four-stroke, 4.2 L, V-6 naturally aspirated natural gas engine coupled to an eddy current dynamometer was used to measure the impact of hydrogen/natural gas blends on performance, thermodynamic efficiency and exhaust gas emissions in a reciprocating four stroke cycle engine. The test matrix varied engine load and air-to-fuel ratio at throttle openings of 50% and 100% at equivalence ratios of 1.00 and 0.90 for hydrogen percentages of 10%, 20% and 30% by volume. In addition, tests were performed at 100% throttle opening, with an equivalence ratio of 0.98 and a hydrogen blend of 20% to further investigate CO emission variations. Data analysis indicated that the use of hydrogen/natural gas fuel blend penalizes the engine operation with a 1.5 to 2.0% decrease in torque, but provided up to a 36% reduction in CO, a 30% reduction in NOX, and a 5% increase in brake thermal efficiency. These results concur with previous results published in the open literature. Further reduction in emissions can be obtained by retarding the ignition timing.« less

KENNEDY SPACE CENTER, FLA. -- In the Space Life Sciences Lab, Lanfang Levine, with Dynamac Corp., transfers material into a sample bottle for analysis. She is standing in front of new equipment in the lab that will provide gas chromatography and mass spectrometry. The equipment will enable analysis of volatile compounds, such as from plants. The 100,000 square-foot facility houses labs for NASA’s ongoing research efforts, microbiology/microbial ecology studies and analytical chemistry labs. Also calling the new lab home are facilities for space flight-experiment and flight-hardware development, new plant growth chambers, and an Orbiter Environment Simulator that will be used to conduct ground control experiments in simulated flight conditions for space flight experiments. The SLS Lab, formerly known as the Space Experiment Research and Processing Laboratory or SERPL, provides space for NASA’s Life Sciences Services contractor Dynamac Corporation, Bionetics Corporation, and researchers from the University of Florida. NASA’s Office of Biological and Physical Research will use the facility for processing life sciences experiments that will be conducted on the International Space Station. The SLS Lab is the magnet facility for the International Space Research Park at KSC being developed in partnership with Florida Space Authority.

NASA Image and Video Library

2004-01-05

KENNEDY SPACE CENTER, FLA. -- In the Space Life Sciences Lab, Lanfang Levine, with Dynamac Corp., transfers material into a sample bottle for analysis. She is standing in front of new equipment in the lab that will provide gas chromatography and mass spectrometry. The equipment will enable analysis of volatile compounds, such as from plants. The 100,000 square-foot facility houses labs for NASA’s ongoing research efforts, microbiology/microbial ecology studies and analytical chemistry labs. Also calling the new lab home are facilities for space flight-experiment and flight-hardware development, new plant growth chambers, and an Orbiter Environment Simulator that will be used to conduct ground control experiments in simulated flight conditions for space flight experiments. The SLS Lab, formerly known as the Space Experiment Research and Processing Laboratory or SERPL, provides space for NASA’s Life Sciences Services contractor Dynamac Corporation, Bionetics Corporation, and researchers from the University of Florida. NASA’s Office of Biological and Physical Research will use the facility for processing life sciences experiments that will be conducted on the International Space Station. The SLS Lab is the magnet facility for the International Space Research Park at KSC being developed in partnership with Florida Space Authority.

Preliminary design of an auxiliary power unit for the space shuttle: Component and system configuration screening analysis

NASA Technical Reports Server (NTRS)

Binsley, R. L.; Maddox, J. P.; Marcy, R. D.; Siegler, R. S.; Spies, R.

1971-01-01

The auxiliary power unit (APU) for the space shuttle is required to provide hydraulic and electrical power on board the booster and orbiter vehicles. Five systems and their associated components, which utilize hot gas turbines to supply horsepower at gearbox output pads, were studied. Hydrogen-oxygen and storable propellants were considered for the hot gas supply. All APU's were required to be self-contained with respect to dissipating internally generated heat. These five systems were evaluated relative to a consistent criteria. The system supplied with high pressure gaseous hydrogen and oxygen was recommended as the best approach. It included a two-stage pressure-compounded partial-admission turbine, a propellant conditioning system with recuperation, a control system, and a gearbox. The gearbox output used was 240 hp. At the close of the study a 400 hp level was considered more appropriate for meeting the prime shuttle vehicle needs, and an in-depth analysis of the system at the 400 hp output level was recommended.

High-pressure plastic scintillation detector for measuring radiogenic gases in flow systems

NASA Astrophysics Data System (ADS)

Schell, W. R.; Vives-Batlle, J.; Yoon, S. R.; Tobin, M. J.

1999-02-01

Radioactive gases are emitted into the atmosphere from nuclear electric power and nuclear fuel reprocessing plants, from hospitals discarding xenon used in diagnostic medicine, as well as from nuclear weapons tests. A high-pressure plastic scintillation detector was constructed to measure atmospheric levels of such radioactive gases by detecting the beta and internal conversion (IC) electron decays. Operational tests and calibrations were made that permit integration of the flow detectors into a portable Gas Analysis, Separation and Purification system (GASP). The equipment developed can be used for measuring fission gases released from nuclear reactor sources and/or as part of monitoring equipment for enforcing the Comprehensive Test Ban Treaty. The detector is being used routinely for in-line gas separation efficiency measurements, at the elevated operational pressures used for the high-pressure swing analysis system (2070 kPa) and at flow rates of 5-15 l/min [1, 2]. This paper presents the design features, operational methods, calibration, and detector applications.

The measurement of acetanilide in plasma by spectrophotometric and selected ion monitoring methods.

PubMed

Baty, J D; Playfer, J; Evans, D A; Lamb, J

1977-08-01

Plasma samples from volunteers who had received an oral dose of acetanilide have been analysed by gas chromatography mass spectrometry and ultraviolet absorption techniques. The gas chromatography mass spectrometry method involved extraction of the plasma and analysis of the acetanilide using selected ion monitoring with a deuterated internal standard. In the ultraviolet method the plasma was hydrolysed with acid to convert the acetanilide to aniline, and this compound was diazotized and coupled with N-1-naphthylethylene-diamine. The absorbance of the resulting complex was read at 550 nm. Acetanilide levels in plasma determined by the selected ion monitoring method were significantly lower than those measured by spectrophotometry. Pharmacokinetic data calculated from the results obtained using these two assays are very different and illustrate the need for an accurate and specific method of analysis. The major metabolites of acetanilide are shown not to interfere with these assays and the results suggest the possible presence of a new metabolite of acetanilide.

Comparison method for uranium determination in ore sample by inductively coupled plasma optical emission spectrometry (ICP-OES).

PubMed

Sert, Şenol

2013-07-01

A comparison method for the determination (without sample pre-concentration) of uranium in ore by inductively coupled plasma optical emission spectrometry (ICP-OES) has been performed. The experiments were conducted using three procedures: matrix matching, plasma optimization, and internal standardization for three emission lines of uranium. Three wavelengths of Sm were tested as internal standard for the internal standardization method. The robust conditions were evaluated using applied radiofrequency power, nebulizer argon gas flow rate, and sample uptake flow rate by considering the intensity ratio of the Mg(II) 280.270 nm and Mg(I) 285.213 nm lines. Analytical characterization of method was assessed by limit of detection and relative standard deviation values. The certificated reference soil sample IAEA S-8 was analyzed, and the uranium determination at 367.007 nm with internal standardization using Sm at 359.260 nm has been shown to improve accuracy compared with other methods. The developed method was used for real uranium ore sample analysis.

A two-phase restricted equilibrium model for combustion of metalized solid propellants

NASA Technical Reports Server (NTRS)

Sabnis, J. S.; Dejong, F. J.; Gibeling, H. J.

1992-01-01

An Eulerian-Lagrangian two-phase approach was adopted to model the multi-phase reacting internal flow in a solid rocket with a metalized propellant. An Eulerian description was used to analyze the motion of the continuous phase which includes the gas as well as the small (micron-sized) particulates, while a Lagrangian description is used for the analysis of the discrete phase which consists of the larger particulates in the motor chamber. The particulates consist of Al and Al2O3 such that the particulate composition is 100 percent Al at injection from the propellant surface with Al2O3 fraction increasing due to combustion along the particle trajectory. An empirical model is used to compute the combustion rate for agglomerates while the continuous phase chemistry is treated using chemical equilibrium. The computer code was used to simulate the reacting flow in a solid rocket motor with an AP/HTPB/Al propellant. The computed results show the existence of an extended combustion zone in the chamber rather than a thin reaction region. The presence of the extended combustion zone results in the chamber flow field and chemical being far from isothermal (as would be predicted by a surface combustion assumption). The temperature in the chamber increases from about 2600 K at the propellant surface to about 3350 K in the core. Similarly the chemical composition and the density of the propellant gas also show spatially non-uniform distribution in the chamber. The analysis developed under the present effort provides a more sophisticated tool for solid rocket internal flow predictions than is presently available, and can be useful in studying apparent anomalies and improving the simple correlations currently in use. The code can be used in the analysis of combustion efficiency, thermal load in the internal insulation, plume radiation, etc.

78 FR 63017 - Exhaust Emissions Standards for New Aircraft Gas Turbine Engines and Identification Plate for...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-10-23

... Aircraft Gas Turbine Engines and Identification Plate for Aircraft Engines AGENCY: Federal Aviation... (NO X ), compliance flexibilities, and other regulatory requirements for aircraft turbofan or turbojet... adopting the gas turbine engine test procedures of the International Civil Aviation Organization (ICAO...

77 FR 48497 - Oil and Gas Trade Mission to Israel-Clarification and Amendment

Federal Register 2010, 2011, 2012, 2013, 2014

2012-08-14

... DEPARTMENT OF COMMERCE International Trade Administration Oil and Gas Trade Mission to Israel... Commercial Service (CS) is publishing this amendment to the Notice of the Oil and Gas Trade Mission to Israel... to Israel has been changed to October 28-November 1, 2012. [[Page 48498

Small Gas Engine Repair.

ERIC Educational Resources Information Center

Connecticut State Dept. of Education, Hartford. Div. of Vocational-Technical Schools.

Instructional materials are provided for a small gas engine course. A list of objectives appears first, followed by a list of internal parts and skills/competencies related to those parts for engine work, ignition and electrical systems, fuel system, crankcase lubrication system, arc welding skills, and gas welding skills. Outlines are provided…

Applications of UT results to confirm defects findings by utilization of relevant metallurgical investigations techniques on gas/condensate pipeline working in wet sour gas environment

NASA Astrophysics Data System (ADS)

El-Azhari, O. A.; Gajam, S. Y.

2015-03-01

The gas/condensate pipe line under investigation is a 12 inch diameter, 48 km ASTM, A106 steel pipeline, carrying hydrocarbons containing wet CO2 and H2S.The pipe line had exploded in a region 100m distance from its terminal; after 24 years of service. Hydrogen induced cracking (HIC) and sour gas corrosion were expected due to the presence of wet H2S in the gas analysis. In other areas of pipe line ultrasonic testing was performed to determine whether the pipeline can be re-operated. The results have shown presence of internal planner defects, this was attributed to the existence of either laminations, type II inclusions or some service defects such as HIC and step wise cracking (SWC).Metallurgical investigations were conducted on fractured samples as per NACE standard (TM-0284-84). The obtained results had shown macroscopic cracks in the form of SWC, microstructure of steel had MnS inclusions. Crack sensitivity analyses were calculated and the microhardness testing was conducted. These results had confirmed that the line material was suffering from sour gas deteriorations. This paper correlates the field UT inspection findings with those methods investigated in the laboratory. Based on the results obtained a new HIC resistance material pipeline needs to be selected.

GASP. V. Ram-pressure stripping of a ring Hoag's-like galaxy in a massive cluster

NASA Astrophysics Data System (ADS)

Moretti, A.; Poggianti, B. M.; Gullieuszik, M.; Mapelli, M.; Jaffé, Y. L.; Fritz, J.; Biviano, A.; Fasano, G.; Bettoni, D.; Vulcani, B.; D'Onofrio, M.

2018-04-01

Through an ongoing MUSE program dedicated to study gas removal processes in galaxies (GAs Stripping Phenomena in galaxies with MUSE, GASP), we have obtained deep and wide integral field spectroscopy of the galaxy JO171. This galaxy resembles the Hoag's galaxy, one of the most spectacular examples of ring galaxies, characterized by a completely detached ring of young stars surrounding a central old spheroid. At odds with the isolated Hoag's galaxy, JO171 is part of a dense environment, the cluster Abell 3667, which is causing gas stripping along tentacles. Moreover, its ring counter-rotates with respect to the central spheroid. The joint analysis of the stellar populations and the gas/stellar kinematics shows that the origin of the ring was not due to an internal mechanism, but was related to a gas accretion event that happened in the distant past, prior to accretion on to Abell 3667, most probably within a filament. More recently, since infall in the cluster, the gas in the ring has been stripped by ram pressure, causing the quenching of star formation in the stripped half of the ring. This is the first observed case of ram-pressure stripping in action in a ring galaxy, and MUSE observations are able to reveal both of the events (accretion and stripping) that caused dramatic transformations in this galaxy.

A model for internal oscillations in geysers, with application to Old Faithful (Yellowstone, USA)

NASA Astrophysics Data System (ADS)

Rudolph, Maxwell L.; Sohn, Robert A.

2017-09-01

We present a mechanical model for internal oscillations in geysers with "bubble trap" configurations, where ascending gas or vapor becomes trapped beneath the roof of a cavity that is laterally offset from the eruption conduit. We consider two cases, one in which the trapped gas behaves as an isothermal ideal gas, and one where it is treated as isenthalpic steam. In both cases the system behaves as a damped, harmonic oscillator with a resonant frequency that is sensitive to the conduit geometries and fluid volumes. We use the model to predict internal oscillation frequencies for Old Faithful geyser, in Yellowstone, USA, using conduit geometry constraints from the literature, and find that the frequencies predicted by the model are consistent with observations ( 1 Hz). We show that systematic frequency increases during the recharge cycle, when the fluid volume of the system is increasing due to recharge, are consistent with either a decrease in the amount (both volume and mass) of trapped gas or vapor, a decrease in the eruption conduit area, or a combination of both.

Flow structure and heat exchange analysis in internal cooling channel of gas turbine blade

NASA Astrophysics Data System (ADS)

Szwaba, Ryszard; Kaczynski, Piotr; Doerffer, Piotr; Telega, Janusz

2016-08-01

This paper presents the study of the flow structure and heat transfer, and also their correlations on the four walls of a radial cooling passage model of a gas turbine blade. The investigations focus on heat transfer and aerodynamic measurements in the channel, which is an accurate representation of the configuration used in aeroengines. Correlations for the heat transfer coefficient and the pressure drop used in the design of radial cooling passages are often developed from simplified models. It is important to note that real engine passages do not have perfect rectangular cross sections, but include corner fillet, ribs with fillet radii and special orientation. Therefore, this work provides detailed fluid flow and heat transfer data for a model of radial cooling geometry which possesses very realistic features.

Regional variation in water-related impacts of shale gas development and implications for emerging international plays.

PubMed

Mauter, Meagan S; Alvarez, Pedro J J; Burton, Allen; Cafaro, Diego C; Chen, Wei; Gregory, Kelvin B; Jiang, Guibin; Li, Qilin; Pittock, Jamie; Reible, Danny; Schnoor, Jerald L

2014-01-01

The unconventional fossil fuel industry is expected to expand dramatically in coming decades as conventional reserves wane. Minimizing the environmental impacts of this energy transition requires a contextualized understanding of the unique regional issues that shale gas development poses. This manuscript highlights the variation in regional water issues associated with shale gas development in the U.S. and the approaches of various states in mitigating these impacts. The manuscript also explores opportunities for emerging international shale plays to leverage the diverse experiences of U.S. states in formulating development strategies that minimize water-related impacts within their environmental, cultural, and political ecosystem.

The mechanism study between 3D Space-time deformation and injection or extraction of gas pressure change, the Hutubi Underground gas storage

NASA Astrophysics Data System (ADS)

Xiaoqiang, W.; Li, J.; Daiqing, L.; Li, C.

2017-12-01

The surface deformation of underground gas reservoir with the change of injection pressure is an excellent opportunity to study the load response under the action of tectonic movement and controlled load. This paper mainly focuses on the elastic deformation of underground structure caused by the change of the pressure state of reservoir rock under the condition of the irregular change of pressure in the underground gas storage of Hutubi, the largest underground gas storage in Xinjiang, at the same time, it makes a fine study on the fault activities of reservoir and induced earthquakes along with the equilibrium instability caused by the reservoir. Based on the 34 deformation integrated observation points and 3 GPS continuous observation stations constructed in the underground gas storage area of Hutubi, using modern measurement techniques such as GPS observation, precise leveling survey, flow gravity observation and so on, combined with remote sensing technology such as InSAR, the 3d space-time sequence images of the surface of reservoir area under pressure change were obtained. Combined with gas well pressure, physical parameters and regional seismic geology and geophysical data, the numerical simulation and analysis of internal changes of reservoir were carried out by using elastic and viscoelastic model, the deformation mechanical relationship of reservoir was determined and the storage layer under controlled load was basically determined. This research is financially supported by National Natural Science Foundation of China (Grant No.41474016, 41474051, 41474097)

Role of naturally occurring gas hydrates in sediment transport

DOE Office of Scientific and Technical Information (OSTI.GOV)

McIver, R.D.

1982-06-01

Naturally occurring gas hydrates have the potential to store enormous volumes of both gas and water in semi-solid form in ocean-bottom sediments and then to release that gas and water when the hydrate's equilibrium condition are disturbed. Therefore, hydrates provide a potential mechanism for transporting large volumes of sediments. Under the combined low bottom-water temperatures and moderate hydrostatic pressures that exist over most of the continental slopes and all of the continental rises and abyssal plains, hydrocarbon gases at or near saturation in the interstitial waters of the near-bottom sediments will form hydrates. The gas can either be autochthonous, microbiallymore » produced gas, or allochthonous, catagenic gas from deeper sediments. Equilibrium conditions that stabilize hydrated sediments may be disturbed, for example, by continued sedimentation or by lowering of sea level. In either case, some of the solid gas-water matrix decomposes. Released gas and water volume exceeds the volume occupied by the hydrate, so the internal pressure rises - drastically if large volumes of hydrate are decomposed. Part of the once rigid sediment is converted to a gas- and water-rich, relatively low density mud. When the internal pressure, due to the presence of the compressed gas or to buoyancy, is sufficiently high, the overlying sediment may be lifted and/or breached, and the less dense, gas-cut mud may break through. Such hydrate-related phenomena can cause mud diapirs, mud volcanos, mud slides, or turbidite flows, depending on sediment configuration and bottom topography. 4 figures.« less

Histogrammatic Method for Determining Relative Abundance of Input Gas Pulse

NASA Technical Reports Server (NTRS)

Mandrake, Lukas; Bornstein, Benjamin J.; Madzunkov, Stojan; MacAskill, John A.

2012-01-01

To satisfy the Major Constituents Analysis (MCA) requirements for the Vehicle Cabin Atmosphere Monitor (VCAM), this software analyzes the relative abundance ratios for N2, O2, Ar, and CO2 as a function of time and constructs their best-estimate mean. A histogram is first built of all abundance ratios for each of the species vs time. The abundance peaks corresponding to the intended measurement and any obfuscating background are then separated via standard peak-finding techniques in histogram space. A voting scheme is then used to include/exclude this particular time sample in the final average based on its membership to the intended measurement or the background population. This results in a robust and reasonable estimate of the abundance of trace components such as CO2 and Ar even in the presence of obfuscating backgrounds internal to the VCAM device. VCAM can provide a means for monitoring the air within the enclosed environments, such as the ISS (International Space Station), Crew Exploration Vehicle (CEV), a Lunar Habitat, or another vehicle traveling to Mars. Its miniature pre-concentrator, gas chromatograph (GC), and mass spectrometer can provide unbiased detection of a large number of organic species as well as MCA analysis. VCAM s software can identify the concentration of trace chemicals and whether the chemicals are on a targeted list of hazardous compounds. This innovation s performance and reliability on orbit, along with the ground team s assessment of its raw data and analysis results, will validate its technology for future use and development.

Crises Management in the Oil and Gas Industry: The Niger Delta Experience

NASA Astrophysics Data System (ADS)

Odemene, Glory C.

The Niger Delta crises escalated beyond the borders of the Nigerian nation to become an issue that affected individuals and corporations around the world. This study led to the discovery of how the local crises escalated with international implications. This discovery was accomplished by addressing how the Niger Delta crises escalated from villages to international scenes, with notable impacts on the environment, health, safety, security, and financial segments of local, international, private, and corporate entities. Using Sweeny's crisis decision theory and Lazarus and Folkman's coping theory, the study considered the coping strategies of community members, the decisions, and actions they took in response to the management approaches of the government and the oil and gas companies (OGCs). This qualitative study utilized historical narrative to collect data by interviewing 4 participants who lived and worked in the region during the crises. NVivo was used for manual and automatic coding of data, as well as for categorization and connection of codes. Content analysis of identified codes and categories revealed the themes and trends in the experiences narrated by participants. Findings include the root causes, trend of escalation, and management strategies of the government and the OGCs that influenced the crises. These findings will help to influence policies and practices in the region and enhance effective management of current and emerging conflicts, with possibilities of restoring stability and security in the areas and in the nation at large.

Electronic Nose Functionality for Breath Gas Analysis during Parabolic Flight

NASA Astrophysics Data System (ADS)

Dolch, Michael E.; Hummel, Thomas; Fetter, Viktor; Helwig, Andreas; Lenic, Joachim; Moukhamedieva, Lana; Tsarkow, Dimitrij; Chouker, Alexander; Schelling, Gustav

2017-06-01

The presence of humans in space represents a constant threat for their health and safety. Environmental factors such as living in a closed confinement, as well as exposure to microgravity and radiation, are associated with significant changes in bone metabolism, muscular atrophy, and altered immune response, which has impacts on human performance and possibly results in severe illness. Thus, maintaining and monitoring of crew health status has the highest priority to ensure whole mission success. With manned deep space missions to moon or mars appearing at the horizon where short-term repatriation back to earth is impossible the availability of appropriate diagnostic platforms for crew health status is urgently needed. In response to this need, the present experiment evaluated the functionality and practicability of a metal oxide based sensor system (eNose) together with a newly developed breath gas collecting device under the condition of altering acceleration. Parabolic flights were performed with an Airbus A300 ZeroG at Bordeaux, France. Ambient air and exhaled breath of five healthy volunteers was analyzed during steady state flight and parabolic flight maneuvres. All volunteers completed the study, the breath gas collecting device valves worked appropriately, and breathing through the collecting device was easy and did not induce discomfort. During breath gas measurements, significant changes in metal oxide sensors, mainly sensitive to aromatic and sulphur containing compounds, were observed with alternating conditions of acceleration. Similarly, metal oxide sensors showed significant changes in all sensors during ambient air measurements. The eNose as well as the newly developed breath gas collecting device, showed appropriate functionality and practicability during alternating conditions of acceleration which is a prerequisite for the intended use of the eNose aboard the International Space Station (ISS) for breath gas analysis and crew health status monitoring. The observed changes in breath gas composition are most likely associated with changes in ambient air volatile organic and inorganic compound composition and require further evaluation.

Thermal Fault Tolerance Analysis of Carbon Fiber Rope Barrier Systems for Use in the Reusable Solid Rocket Motor ( RSRM) Nozzle Joints

NASA Technical Reports Server (NTRS)

Clayton, J. Louie; Phelps, Lisa (Technical Monitor)

2001-01-01

Carbon Fiber Rope (CFR) thermal barrier systems are being considered for use in several RSRM (Reusable Solid Rocket Motor) nozzle joints as a replacement for the current assembly gap close-out process/design. This study provides for development and test verification of analysis methods used for flow-thermal modeling of a CFR thermal barrier subject to fault conditions such as rope combustion gas blow-by and CFR splice failure. Global model development is based on a 1-D (one dimensional) transient volume filling approach where the flow conditions are calculated as a function of internal 'pipe' and porous media 'Darcy' flow correlations. Combustion gas flow rates are calculated for the CFR on a per-linear inch basis and solved simultaneously with a detailed thermal-gas dynamic model of a local region of gas blow by (or splice fault). Effects of gas compressibility, friction and heat transfer are accounted for the model. Computational Fluid Dynamic (CFD) solutions of the fault regions are used to characterize the local flow field, quantify the amount of free jet spreading and assist in the determination of impingement film coefficients on the nozzle housings. Gas to wall heat transfer is simulated by a large thermal finite element grid of the local structure. The employed numerical technique loosely couples the FE (Finite Element) solution with the gas dynamics solution of the faulted region. All free constants that appear in the governing equations are calibrated by hot fire sub-scale test. The calibrated model is used to make flight predictions using motor aft end environments and timelines. Model results indicate that CFR barrier systems provide a near 'vented joint' style of pressurization. Hypothetical fault conditions considered in this study (blow by, splice defect) are relatively benign in terms of overall heating to nozzle metal housing structures.

Effect of internal and external conditions on ionization processes in the FAPA ambient desorption/ionization source.

PubMed

Orejas, Jaime; Pfeuffer, Kevin P; Ray, Steven J; Pisonero, Jorge; Sanz-Medel, Alfredo; Hieftje, Gary M

2014-11-01

Ambient desorption/ionization (ADI) sources coupled to mass spectrometry (MS) offer outstanding analytical features: direct analysis of real samples without sample pretreatment, combined with the selectivity and sensitivity of MS. Since ADI sources typically work in the open atmosphere, ambient conditions can affect the desorption and ionization processes. Here, the effects of internal source parameters and ambient humidity on the ionization processes of the flowing atmospheric pressure afterglow (FAPA) source are investigated. The interaction of reagent ions with a range of analytes is studied in terms of sensitivity and based upon the processes that occur in the ionization reactions. The results show that internal parameters which lead to higher gas temperatures afforded higher sensitivities, although fragmentation is also affected. In the case of humidity, only extremely dry conditions led to higher sensitivities, while fragmentation remained unaffected.

Methods for ensuring compliance in an international greenhouse gas trading system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hargrave, T.; Helme, E.A.

1998-12-31

At the third Conference of the Parties to the UN Framework Convention on Climate Change held in December, 1997, the international community established binding greenhouse gas (GHG) emissions obligations for industrialized countries. The Parties to the new Kyoto Protocol also agreed on the use of a number of market-based mechanisms, including international GHG emissions trading. These market mechanisms were of critical to the importance because they have the potential to significantly reduce the costs of treaty compliance. In principle, an international cap-and-trade system appears to be one of the most cost-effective means of reducing GHG emissions. Maintaining the integrity ofmore » the trading system is of primary importance in ensuring that trading helps countries to meet their GHG commitments. This paper explores methods for ensuring compliance in an international greenhouse gas trading system, starting with a discussion of preconditions for participation in trading and then moving to features of an international compliance system. Achieving maximum compliance with international requirements may best be accomplished by limiting participation in trading to Annex I countries that maintain strong domestic compliance systems. Prior to the climate negotiations in Kyoto in December 1997, the US Administration proposed a number of preconditions for participation in trading, including the adoption of international measurement standards and the establishment of domestic compliance and enforcement programs. This paper explores these and other preconditions, including the establishment of tough domestic financial penalties on companies that exceed allowed emissions and seller responsibility for the delivery of real reductions. The paper also discusses several necessary features of the international compliance system.« less

Hydrogen generation from natural gas for the fuel cell systems of tomorrow

NASA Astrophysics Data System (ADS)

Dicks, Andrew L.

In most cases hydrogen is the preferred fuel for use in the present generation of fuel cells being developed for commercial applications. Of all the potential sources of hydrogen, natural gas offers many advantages. It is widely available, clean, and can be converted to hydrogen relatively easily. When catalytic steam reforming is used to generate hydrogen from natural gas, it is essential that sulfur compounds in the natural gas are removed upstream of the reformer and various types of desulfurisation processes are available. In addition, the quality of fuel required for each type of fuel cell varies according to the anode material used, and the cell temperature. Low temperature cells will not tolerate high concentrations of carbon monoxide, whereas the molten fuel cell (MCFC) and solid oxide fuel cell (SOFC) anodes contain nickel on which it is possible to electrochemically oxidise carbon monoxide directly. The ability to internally reform fuel gas is a feature of the MCFC and SOFC. Internal reforming can give benefits in terms of increased electrical efficiency owing to the reduction in the required cell cooling and therefore parasitic system losses. Direct electrocatalysis of hydrocarbon oxidation has been the elusive goal of fuel cell developers over many years and recent laboratory results are encouraging. This paper reviews the principal methods of converting natural gas into hydrogen, namely catalytic steam reforming, autothermic reforming, pyrolysis and partial oxidation; it reviews currently available purification techniques and discusses some recent advances in internal reforming and the direct use of natural gas in fuel cells.

First Experiments with the Polarized Internal Gas Target (PIT) at ANKE/COSY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Engels, R.; Lorentz, B.; Prasuhn, D.

2008-02-06

For future few-nucleon interaction studies with polarized beams and targets at COSY-Juelich, a polarized internal storage-cell gas target was implemented at the magnet spectrometer ANKE in summer 2005. First commissioning of the polarized Atomic Beam Source (ABS) at ANKE was carried out and some improvements of the system have been done. Storage-cell tests to determine the COSY beam dimensions have been performed. Electron cooling combined with stacking and stochastic cooling have been studied. Experiments with N{sub 2} gas in the storage cell to simulate the background produced by beam interaction with the aluminum cell walls were performed to investigate themore » beam heating by the target gas. The analysis of the d-vector p-vector {yields}dp and d-vector p-vector{yields}(dp{sub sp}){pi}{sup 0} reactions showed that events from the extended target can be clearly identified in the ANKE detector system.The polarization of the atomic beam of the ABS, positioned close to the strong dipole magnet D2 of ANKE, was tuned with a Lamb-shift polarimeter (LSP) beneath the target chamber. With use of the known analyzing powers of the quasi-free np{yields}d{pi}{sup 0} reaction, the polarization in the storage cell was measured to be Q{sub y} = 0.79{+-}0.07 in the vertical stray field of the D2 magnet acting as a holding field. The achieved target thickness was 2x10{sup 13} atoms/cm{sup 2} for one hyperfine state populated in the ABS beam only. With a COSY beam intensity of 6x10{sup 9} stored polarized deuterons in the ring, the luminosity for double polarized experiments was 1x10{sup 29} cm{sup -2} s{sup -1}.« less

First Experiments with the Polarized Internal Gas Target (PIT) at ANKE/COSY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Engels, R.; Lorentz, B.; Prasuhn, D.

2009-08-04

For future few-nucleon interaction studies with polarized beams and targets at COSY-Juelich, a polarized internal storage-cell gas target was implemented at the magnet spectrometer ANKE. First commissioning of the polarized Atomic Beam Source (ABS) at ANKE was carried out and some improvements of the system have been done. Storage-cell tests to determine the COSY beam dimensions have been performed. Electron cooling combined with stacking and stochastic cooling have been studied. Experiments with N{sub 2} gas in the storage cell to simulate the background produced by beam interaction with the aluminum cell walls were performed to investigate the beam heating bymore » the target gas. The analysis of the d-vectorp-vector->dp and d-vectorp-vector->(dp{sub sp})pi{sup 0} reactions showed that events from different positions of the extended target can be clearly identified in the ANKE detector system. The polarization of the atomic beam of the ABS, positioned close to the strong dipole magnet D2 of ANKE, was tuned with a Lamb-shift polarimeter (LSP) beneath the target chamber. With use of the known analyzing powers of the quasi-free np->dpi{sup 0} reaction, the polarization in the storage cell was measured to be Q{sub y} = 0.79+-0.07 in the vertical stray field of the D2 magnet acting as a holding field. The target thickness achieved was 2x10{sup 13} atoms/cm{sup 2} for one hyperfine state populated in the ABS beam only. With a COSY beam intensity of 6x10{sup 9} stored polarized deuterons in the ring, the luminosity for double polarized experiments was 1x10{sup 29} cm{sup -2} s{sup -1}.« less

Simple and robust referencing system enables identification of dissolved-phase xenon spectral frequencies.

PubMed

Antonacci, Michael A; Zhang, Le; Burant, Alex; McCallister, Drew; Branca, Rosa T

2018-08-01

To assess the effect of macroscopic susceptibility gradients on the gas-phase referenced dissolved-phase 129 Xe (DPXe) chemical shift (CS) and to establish the robustness of a water-based referencing system for in vivo DPXe spectra. Frequency shifts induced by spatially varying magnetic susceptibility are calculated by finite-element analysis for the human head and chest. Their effect on traditional gas-phase referenced DPXe CS is then assessed theoretically and experimentally. A water-based referencing system for the DPXe resonances that uses the local water protons as reference is proposed and demonstrated in vivo in rats. Across the human brain, macroscopic susceptibility gradients can induce an apparent variation in the DPXe CS of up to 2.5 ppm. An additional frequency shift as large as 6.5 ppm can exist between DPXe and gas-phase resonances. By using nearby water protons as reference for the DPXe CS, the effect of macroscopic susceptibility gradients is eliminated and consistent CS values are obtained in vivo, regardless of shimming conditions, region of interest analyzed, animal orientation, or lung inflation. Combining in vitro and in vivo spectroscopic measurements finally enables confident assignment of some of the DPXe peaks observed in vivo. To use hyperpolarized xenon as a biological probe in tissues, the DPXe CS in specific organs/tissues must be reliably measured. When the gas-phase is used as reference, variable CS values are obtained for DPXe resonances. Reliable peak assignments in DPXe spectra can be obtained by using local water protons as reference. Magn Reson Med 80:431-441, 2018. © 2017 International Society for Magnetic Resonance in Medicine. © 2017 International Society for Magnetic Resonance in Medicine.

Application of CFD codes to the design and development of propulsion systems

NASA Technical Reports Server (NTRS)

Lord, W. K.; Pickett, G. F.; Sturgess, G. J.; Weingold, H. D.

1987-01-01

The internal flows of aerospace propulsion engines have certain common features that are amenable to analysis through Computational Fluid Dynamics (CFD) computer codes. Although the application of CFD to engineering problems in engines was delayed by the complexities associated with internal flows, many codes with different capabilities are now being used as routine design tools. This is illustrated by examples taken from the aircraft gas turbine engine of flows calculated with potential flow, Euler flow, parabolized Navier-Stokes, and Navier-Stokes codes. Likely future directions of CFD applied to engine flows are described, and current barriers to continued progress are highlighted. The potential importance of the Numerical Aerodynamic Simulator (NAS) to resolution of these difficulties is suggested.

26 CFR 301.9001-2 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-04-01

... ADMINISTRATION PROCEDURE AND ADMINISTRATION General Rules Application of Internal Revenue Laws § 301.9001-2..., and natural gas condensate, except that the term does not include natural gas. (c) “Person” means an...

Thin liquid films with time-dependent chemical reactions sheared by an ambient gas flow

NASA Astrophysics Data System (ADS)

Bender, Achim; Stephan, Peter; Gambaryan-Roisman, Tatiana

2017-08-01

Chemical reactions in thin liquid films are found in many industrial applications, e.g., in combustion chambers of internal combustion engines where a fuel film can develop on pistons or cylinder walls. The reactions within the film and the turbulent outer gas flow influence film stability and lead to film breakup, which in turn can lead to deposit formation. In this work we examine the evolution and stability of a thin liquid film in the presence of a first-order chemical reaction and under the influence of a turbulent gas flow. Long-wave theory with a double perturbation analysis is used to reduce the complexity of the problem and obtain an evolution equation for the film thickness. The chemical reaction is assumed to be slow compared to film evolution and the amount of reactant in the film is limited, which means that the reaction rate decreases with time as the reactant is consumed. A linear stability analysis is performed to identify the influence of reaction parameters, material properties, and environmental conditions on the film stability limits. Results indicate that exothermic reactions have a stabilizing effect whereas endothermic reactions destabilize the film and can lead to rupture. It is shown that an initially unstable film can become stable with time as the reaction rate decreases. The shearing of the film by the external gas flow leads to the appearance of traveling waves. The shear stress magnitude has a nonmonotonic influence on film stability.

Thermal Analysis of a Carbon Fiber Rope Barrier for Use in the Reusable Solid Rocket Motor Nozzle Joint-2

NASA Technical Reports Server (NTRS)

Clayton, J. Louie

2002-01-01

This study provides development and verification of analysis methods used to assess performance of a carbon fiber rope (CFR) thermal barrier system that is currently being qualified for use in Reusable Solid Rocket Motor (RSRM) nozzle joint-2. Modeled geometry for flow calculations considers the joint to be vented with the porous CFR barriers placed in the 'open' assembly gap. Model development is based on a 1-D volume filling approach where flow resistances (assembly gap and CFRs) are defined by serially connected internal flow and the porous media 'Darcy' relationships. Combustion gas flow rates are computed using the volume filling code by assuming a lumped distribution total joint fill volume on a per linear circumferential inch basis. Gas compressibility, friction and heat transfer are included in the modeling. Gas-to-wall heat transfer is simulated by concurrent solution of the compressible flow equations and a large thermal 2-D finite element (FE) conduction grid. The derived numerical technique loosely couples the FE conduction matrix with the compressible gas flow equations. Free constants that appear in the governing equations are calibrated by parametric model comparison to hot fire subscale test results. The calibrated model is then used to make full-scale motor predictions using RSRM aft dome environments. Model results indicate that CFR thermal barrier systems will provide a thermally benign and controlled pressurization environment for the RSRM nozzle joint-2 primary seal activation.

Thermal Analysis of a Carbon Fiber Rope Barrier for Use in the Reusable Solid Rocket Motor Nozzle Joint-2

NASA Technical Reports Server (NTRS)

Clayton, J. Louie; Phelps, Lisa (Technical Monitor)

2001-01-01

This study provides for development and verification of analysis methods used to assess performance of a carbon fiber rope (CFR) thermal barrier system that is currently being qualified for use in Reusable Solid Rocket Motor (RSRM) nozzle joint-2. Modeled geometry for flow calculations considers the joint to be vented with the porous CFR barriers placed in the "open' assembly gap. Model development is based on a 1-D volume filling approach where flow resistances (assembly gap and CFRs) are defined by serially connected internal flow and the porous media "Darcy" relationships. Combustion gas flow rates are computed using the volume filling code by assuming a lumped distribution total joint fill volume on a per linear circumferential inch basis. Gas compressibility, friction and heat transfer are included in the modeling. Gas-to-wall heat transfer is simulated by concurrent solution of the compressible flow equations and a large thermal 2-D finite element (FE) conduction grid. The derived numerical technique loosely couples the FE conduction matrix with the compressible gas flow equations, Free constants that appear in the governing equations are calibrated by parametric model comparison to hot fire subscale test results. The calibrated model is then used to make full-scale motor predictions using RSRM aft dome environments. Model results indicate that CFR thermal barrier systems will provide a thermally benign and controlled pressurization environment for the RSRM nozzle joint-2 primary seal activation.

Approximating Fluid Flow from Ambient to Very Low Pressures: Modeling ISS Experiments that Vent to Vacuum

NASA Technical Reports Server (NTRS)

Minor, Robert

2002-01-01

Two ISS (International Space Station) experiment payloads will vent a volume of gas overboard via either the ISS Vacuum Exhaust System or the Vacuum Resource System. A system of ducts, valves and sensors, under design, will connect the experiments to the ISS systems. The following tasks are required: Create an analysis tool that will verify the rack vacuum system design with respect to design requirements, more specifically approximate pressure at given locations within the vacuum systems; Determine the vent duration required to achieve desired pressure within the experiment modules; Update the analysis as systems and operations definitions mature.

ENVIRONMENTAL TECHNOLOGY REPORT, MIRATECH CORPORATION, GECO(TM) 3001 AIR/FUEL RATIO CONTROLLER (MANUFACTURED BY WOODWARD GOVERNOR COMPANY) PHASE II REPORT

EPA Science Inventory

In the natural gas industry, transmission pipeline operators use internal combustion (IC) gas-fired engines to provide the mechanical energy needed to drive pipeline gas compressors. As such, owners and operators of compressor stations are interested in the performance of these e...

75 FR 73065 - Tennessee Gas Pipeline Company; Notice of Application

Federal Register 2010, 2011, 2012, 2013, 2014

2010-11-29

.... CP11-22-000, an application pursuant to section 3 of the Natural Gas Act (NGA), to amend its authorization under NGA section 3 and Presidential Permits to allow it to import and export natural gas from the... NGA be amended to authorize Tennessee to operate bi- directionally two existing international border...

MIS High-Purity Plutonium Oxide Hydride Product 5501579 (SSR124): Final Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Veirs, Douglas Kirk; Stroud, Mary Ann; Berg, John M.

A high-purity plutonium dioxide material from the Material Identification and Surveillance (MIS) Program inventory has been studied with regard to gas generation and corrosion in a storage environment. Sample 5501579 represents process plutonium oxides from hydride oxide from Rocky Flats that are currently stored in 3013 containers. After calcination to 950°C, the material contained 87.42% plutonium with no major impurities. This study followed over time, the gas pressure of a sample with nominally 0.5 wt% water in a sealed container with an internal volume scaled to 1/500th of the volume of a 3013 container. Gas compositions were measured periodically overmore » a six year period. The maximum observed gas pressure was 124 kPa. The increase over the initial pressure of 70 kPa was primarily due to generation of nitrogen and carbon dioxide gas. Hydrogen and oxygen were minor components of the headspace gas. At the completion of the study, the internal components of the sealed container showed signs of corrosion.« less

The influence of porosity and structural parameters on different kinds of gas hydrate dissociation

PubMed Central

Misyura, S. Y.

2016-01-01

Methane hydrate dissociation at negative temperatures was studied experimentally for different artificial and natural samples, differing by macro- and micro-structural parameters. Four characteristic dissociation types are discussed in the paper. The internal kinetics of artificial granule gas hydrates and clathrate hydrates in coal is dependent on the porosity, defectiveness and gas filtration rate. The density of pores distribution in the crust of formed ice decreases by the several orders of magnitude and this change significantly the rate of decay. Existing models for describing dissociation at negative temperatures do not take into account the structural parameters of samples. The dissociation is regulated by internal physical processes that must be considered in the simulation. Non-isothermal dissociation with constant external heat flux was simulated numerically. The dissociation is simulated with consideration of heat and mass transfer, kinetics of phase transformation and gas filtering through a porous medium of granules for the negative temperatures. It is shown that the gas hydrate dissociation in the presence of mainly microporous structures is fundamentally different from the disintegration of gas hydrates containing meso and macropores. PMID:27445113

Bolt failure detection

DOEpatents

Sutton, Jr., Harry G.

1984-01-01

Bolts of a liquid metal fast breeder reactor, each bolt provided with an internal chamber filled with a specific, unique radioactive tag gas. Detection of the tag gas is indicative of a crack in an identifiable bolt.

Waste heat recovery system for recapturing energy after engine aftertreatment systems

DOEpatents

Ernst, Timothy C.; Nelson, Christopher R.

2014-06-17

The disclosure provides a waste heat recovery (WHR) system including a Rankine cycle (RC) subsystem for converting heat of exhaust gas from an internal combustion engine, and an internal combustion engine including the same. The WHR system includes an exhaust gas heat exchanger that is fluidly coupled downstream of an exhaust aftertreatment system and is adapted to transfer heat from the exhaust gas to a working fluid of the RC subsystem. An energy conversion device is fluidly coupled to the exhaust gas heat exchanger and is adapted to receive the vaporized working fluid and convert the energy of the transferred heat. The WHR system includes a control module adapted to control at least one parameter of the RC subsystem based on a detected aftertreatment event of a predetermined thermal management strategy of the aftertreatment system.

Laboratory and field based evaluation of chromatography ...

EPA Pesticide Factsheets

The Monitor for AeRosols and GAses in ambient air (MARGA) is an on-line ion-chromatography-based instrument designed for speciation of the inorganic gas and aerosol ammonium-nitrate-sulfate system. Previous work to characterize the performance of the MARGA has been primarily based on field comparison to other measurement methods to evaluate accuracy. While such studies are useful, the underlying reasons for disagreement among methods are not always clear. This study examines aspects of MARGA accuracy and precision specifically related to automated chromatography analysis. Using laboratory standards, analytical accuracy, precision, and method detection limits derived from the MARGA chromatography software are compared to an alternative software package (Chromeleon, Thermo Scientific Dionex). Field measurements are used to further evaluate instrument performance, including the MARGA’s use of an internal LiBr standard to control accuracy. Using gas/aerosol ratios and aerosol neutralization state as a case study, the impact of chromatography on measurement error is assessed. The new generation of on-line chromatography-based gas and particle measurement systems have many advantages, including simultaneous analysis of multiple pollutants. The Monitor for Aerosols and Gases in Ambient Air (MARGA) is such an instrument that is used in North America, Europe, and Asia for atmospheric process studies as well as routine monitoring. While the instrument has been evaluat

A Continuum Model for Metabolic Gas Exchange in Pear Fruit

PubMed Central

Ho, Q. Tri; Verboven, Pieter; Verlinden, Bert E.; Lammertyn, Jeroen; Vandewalle, Stefan; Nicolaï, Bart M.

2008-01-01

Exchange of O2 and CO2 of plants with their environment is essential for metabolic processes such as photosynthesis and respiration. In some fruits such as pears, which are typically stored under a controlled atmosphere with reduced O2 and increased CO2 levels to extend their commercial storage life, anoxia may occur, eventually leading to physiological disorders. In this manuscript we have developed a mathematical model to predict the internal gas concentrations, including permeation, diffusion, and respiration and fermentation kinetics. Pear fruit has been selected as a case study. The model has been used to perform in silico experiments to evaluate the effect of, for example, fruit size or ambient gas concentration on internal O2 and CO2 levels. The model incorporates the actual shape of the fruit and was solved using fluid dynamics software. Environmental conditions such as temperature and gas composition have a large effect on the internal distribution of oxygen and carbon dioxide in fruit. Also, the fruit size has a considerable effect on local metabolic gas concentrations; hence, depending on the size, local anaerobic conditions may result, which eventually may lead to physiological disorders. The model developed in this manuscript is to our knowledge the most comprehensive model to date to simulate gas exchange in plant tissue. It can be used to evaluate the effect of environmental stresses on fruit via in silico experiments and may lead to commercial applications involving long-term storage of fruit under controlled atmospheres. PMID:18369422

Kinetic theory-based numerical modeling and analysis of bi-disperse segregated mixture fluidized bed

DOE Office of Scientific and Technical Information (OSTI.GOV)

Konan, N. A.; Huckaby, E. D.

We discuss a series of continuum Euler-Euler simulations of an initially mixed bi-disperse fluidized bed which segregates under certain operating conditions. The simulations use the multi-phase kinetic theory-based description of the momentum and energy exchanges between the phases by Simonin’s Group [see e.g. Gourdel, Simonin and Brunier (1999). Proceedings of 6th International Conference on Circulating Fluidized Beds, Germany, pp. 205-210]. The discussion and analysis of the results focus on the fluid-particle momentum exchange (i.e. drag). Simulations using mono- and poly-disperse fluid-particle drag correlations are analyzed for the Geldart D-type size bi-disperse gas-solid experiments performed by Goldschmidt et al. [Powder Tech.,more » pp. 135-159 (2003)]. The poly-disperse gas-particle drag correlations account for the local particle size distribution by using an effective mixture diameter when calculating the Reynolds number and then correcting the resulting force coefficient. Simulation results show very good predictions of the segregation index for bidisperse beds with the mono-disperse drag correlations contrary to the poly-disperse drag correlations for which the segregation rate is systematically under-predicted. The statistical analysis of the results shows a clear separation in the distribution of the gas-particle mean relaxation times of the small and large particles with simulations using the mono-disperse drag. In contrast, the poly-disperse drag simulations have a significant overlap and also a smaller difference in the mean particle relaxation times. This results in the small and large particles in the bed to respond to the gas similarly without enough relative time lag. The results suggest that the difference in the particle response time induce flow dynamics favorable to a force imbalance which results in the segregation.« less

Kinetic theory-based numerical modeling and analysis of bi-disperse segregated mixture fluidized bed

DOE PAGES

Konan, N. A.; Huckaby, E. D.

2017-06-21

We discuss a series of continuum Euler-Euler simulations of an initially mixed bi-disperse fluidized bed which segregates under certain operating conditions. The simulations use the multi-phase kinetic theory-based description of the momentum and energy exchanges between the phases by Simonin’s Group [see e.g. Gourdel, Simonin and Brunier (1999). Proceedings of 6th International Conference on Circulating Fluidized Beds, Germany, pp. 205-210]. The discussion and analysis of the results focus on the fluid-particle momentum exchange (i.e. drag). Simulations using mono- and poly-disperse fluid-particle drag correlations are analyzed for the Geldart D-type size bi-disperse gas-solid experiments performed by Goldschmidt et al. [Powder Tech.,more » pp. 135-159 (2003)]. The poly-disperse gas-particle drag correlations account for the local particle size distribution by using an effective mixture diameter when calculating the Reynolds number and then correcting the resulting force coefficient. Simulation results show very good predictions of the segregation index for bidisperse beds with the mono-disperse drag correlations contrary to the poly-disperse drag correlations for which the segregation rate is systematically under-predicted. The statistical analysis of the results shows a clear separation in the distribution of the gas-particle mean relaxation times of the small and large particles with simulations using the mono-disperse drag. In contrast, the poly-disperse drag simulations have a significant overlap and also a smaller difference in the mean particle relaxation times. This results in the small and large particles in the bed to respond to the gas similarly without enough relative time lag. The results suggest that the difference in the particle response time induce flow dynamics favorable to a force imbalance which results in the segregation.« less

Using Isotope Ratio Infrared Spectrometer to determine δ13C of CaCO3 carbonate and DIC samples and δ18O of water

NASA Astrophysics Data System (ADS)

Mandic, M.; Stöbener, N.; Mandic, L.; Smajgl, D.; Jost, H. J. H.

2016-12-01

Precise and accurate determination of isotopic composition of carbon (13C) and oxygen (18O) from carbonate or DIC sample with proper referencing and data evaluation algorithm presents a challenge for scientists. Mass spectrometry was the only widely used technique for this kind of analysis, but recent advances make laser based isotope ratio infrared spectroscopy (IRIS) a viable alternative. To analyze discrete samples, the Universal Reference Interface (URI) Connect was developed. CO2 free syntethic air is used to flush out the contents of a sample container into a variable volume. If necessary, the sample is further diluted before entering the analysis chamber. Reference gas measurements are automatically performed at the same concentration as sample measurements to compensate for instrument drifts and non linearity. The URI Connect can handle about 100 samples per day from an autosampler, or samples can be injected one at a time through a septum on the front of the instrument. Gas samples collected in flasks, bags, syringes, or vials can be analyzed. The system only needs the equivalent of about 80µg - or 40µL - of pure CO2 gas to complete an analysis. Due to it's small weight and robustness, sample analysis can be performed in the field, e.g. aboard a research vessel. To demonstrate the performance, a test experiment with 1% CO2 in 12 ml vials was performed. We achieved an internal precision of better than 0.07‰ and 0.1‰ for δ13C and δ18O, respectively. Analyses with sample amounts as low as 200 μg of carbonate can also be performed reliably with IRIS. We present measurements of three international reference materials, and one of them treated as an unknown. Five samples each of approximately 1mg each were acidified using a few droplets of 43% H3PO4 and left for equilibration overnight at 25°C. The standard deviation was less than 0.1‰ δ13C and the accuracy <0.01‰ As another example of head space analysis in 12 ml vials, we determined δ18O of aliquots of 500 µl of water using equilibration with 1% CO2 in the volume above the water. The agreement with traditional IRMS methods was <0.06‰ was found.

Analysis of the strength of sea gas pipelines of positive buoyancy conditioned by glaciation

NASA Astrophysics Data System (ADS)

Malkov, Venyamin; Kurbatova, Galina; Ermolaeva, Nadezhda; Malkova, Yulia; Petrukhin, Ruslan

2018-05-01

A technique for estimating the stress state of a gas pipeline laid along the seabed in northern latitudes in the presence of glaciation is proposed. It is assumed that the pipeline lies on the bottom of the seabed, but under certain conditions on the some part of the pipeline a glaciation is formed and the gas pipeline section in the place of glaciation can come off the ground due to the positive buoyancy of the ice. Calculation of additional stresses caused by bending of the pipeline is of practical interest for strength evaluation. The gas pipeline is a two-layer cylindrical shell of circular cross section. The inner layer is made of high-strength steel, the outer layer is made of reinforced ferroconcrete. The proposed methodology for calculating the gas pipeline for strength is based on the equations of the theory of shells. The procedure takes into account the effect of internal gas pressure, external pressure of sea water, the weight of two-layer gas pipeline and the weight of the ice layer. The lifting force created by the displaced fluid and the positive buoyancy of the ice is also taken into account. It is significant that the listed loads cause only two types of deformation of the gas pipeline: axisymmetric and antisymmetric. The interaction of the pipeline with the ground as an elastic foundation is not considered. The main objective of the research is to establish the fact of separation of part of the pipeline from the ground. The method of calculations of stresses and deformations occurring in a model sea gas pipeline is presented.

26 CFR 1.614-4 - Treatment under the Internal Revenue Code of 1939 with respect to separate operating mineral...

Code of Federal Regulations, 2010 CFR

2010-04-01

... 26 Internal Revenue 7 2010-04-01 2010-04-01 true Treatment under the Internal Revenue Code of 1939..., in the case of oil and gas wells. 1.614-4 Section 1.614-4 Internal Revenue INTERNAL REVENUE SERVICE....614-4 Treatment under the Internal Revenue Code of 1939 with respect to separate operating mineral...

Changes of the territorial structure of gas demand and supply

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhouchenko, I.A.; Khrisanphov, V.P.; Schenkov, A.S.

1988-01-01

Substantial changes in overall energy supply stress the necessity to critically assess long-term prospects of the international gas industry development. This paper highlights the results of a research study on the problem ''Gas Industry of Capitalist Countries: Main Trends and Prospects of Development to the Year 2015''. The study is being conducted in the All-Union Gas Industry Scientific Research Institute of Economics, Management and Information.

About one discrete model of splitting by the physical processes of a piezoconductive medium with gas hydrate inclusions

NASA Astrophysics Data System (ADS)

Poveshchenko, Yu A.; Podryga, V. O.; Rahimly, P. I.; Sharova, Yu S.

2018-01-01

The thermodynamically equilibrium model for splitting by the physical processes of a two-component three-phase filtration fluid dynamics with gas hydrate inclusions is considered in the paper, for which a family of two-layer completely conservative difference schemes of the support operators method with time weights profiled in space is constructed. On the irregular grids of the theory of the support-operators method applied to the specifics of the processes of transfer of saturations and internal energies of water and gas in a medium with gas hydrate inclusions, methods of directwind approximation of these processes are considered. These approximations preserve the continual properties of divergence-gradient operations in their difference form and are related to the velocity field providing saturations transfer and internal energies of fluids. Fluid dynamics with gas hydrate inclusions are also calculated on the basis of the proposed approach, in particular, in areas of severe pressure depression in the collector space.

INTERNAL REPAIR OF PIPELINES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robin Gordon; Bill Bruce; Nancy Porter

2003-05-01

The two broad categories of deposited weld metal repair and fiber-reinforced composite repair technologies were reviewed for potential application for internal repair of gas transmission pipelines. Both are used to some extent for other applications and could be further developed for internal, local, structural repair of gas transmission pipelines. Preliminary test programs were developed for both deposited weld metal repairs and for fiber-reinforced composite repair. To date, all of the experimental work pertaining to the evaluation of potential repair methods has focused on fiber-reinforced composite repairs. Hydrostatic testing was also conducted on four pipeline sections with simulated corrosion damage: twomore » with composite liners and two without.« less

Catalytic cartridge SO.sub.3 decomposer

DOEpatents

Galloway, Terry R.

1982-01-01

A catalytic cartridge internally heated is utilized as a SO.sub.3 decomposer for thermochemical hydrogen production. The cartridge has two embodiments, a cross-flow cartridge and an axial flow cartridge. In the cross-flow cartridge, SO.sub.3 gas is flowed through a chamber and incident normally to a catalyst coated tube extending through the chamber, the catalyst coated tube being internally heated. In the axial-flow cartridge, SO.sub.3 gas is flowed through the annular space between concentric inner and outer cylindrical walls, the inner cylindrical wall being coated by a catalyst and being internally heated. The modular cartridge decomposer provides high thermal efficiency, high conversion efficiency, and increased safety.

Comparison of Test Procedures and Energy Efficiency Criteria in Selected International Standards & Labeling Programs for Copy Machines, External Power Supplies, LED Displays, Residential Gas Cooktops and Televisions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zheng, Nina; Zhou, Nan; Fridley, David

2012-03-01

This report presents a technical review of international minimum energy performance standards (MEPS), voluntary and mandatory energy efficiency labels and test procedures for five products being considered for new or revised MEPS in China: copy machines, external power supply, LED displays, residential gas cooktops and flat-screen televisions. For each product, an overview of the scope of existing international standards and labeling programs, energy values and energy performance metrics and description and detailed summary table of criteria and procedures in major test standards are presented.

Venezuela`s gas industry poised for long term growth

DOE Office of Scientific and Technical Information (OSTI.GOV)

Croft, G.D.

1995-06-19

Venezuela`s enormous gas resource, combined with a new willingness to invite outside investment, could result in rapid growth in that industry into the next century. The development of liquefied natural gas exports will depend on the future course of gas prices in the US and Europe, but reserves are adequate to supply additional projects beyond the proposed Cristobal Colon project. Venezuela`s gas reserves are likely to increase if exploration for nonassociated gas is undertaken on a larger scale. The paper discusses gas reserves in Venezuela, internal gas markets, the potential for exports, competition from Trinidad, LNG export markets, and themore » encouragement of foreign investment in the gas industry of Venezuela.« less

Internal aeration of paddy field rice (Oryza sativa) during complete submergence---importance of light and floodwater O2.

PubMed

Winkel, Anders; Colmer, Timothy D; Ismail, Abdelbagi M; Pedersen, Ole

2013-03-01

Flash floods can submerge paddy field rice (Oryza sativa), with adverse effects on internal aeration, sugar status and survival. Here, we investigated the in situ aeration of roots of rice during complete submergence, and elucidated how underwater photosynthesis and floodwater pO(2) influence root aeration in anoxic soil. In the field, root pO(2) was measured using microelectrodes during 2 d of complete submergence. Leaf gas films that formed on the superhydrophobic leaves were left intact, or experimentally removed, to elucidate their effect on internal aeration. In darkness, root pO(2) declined to very low concentrations (0.24 kPa) and was strongly correlated with floodwater pO(2). In light, root pO(2) was high (14 kPa) and primarily a function of the incident light determining the rates of underwater net photosynthesis. Plants with intact leaf gas films maintained higher underwater net photosynthesis relative to plants without gas films when the submerged shoots were in light. During complete submergence, internal aeration of rice in the field relies on underwater photosynthesis during the day and entry of O(2) from the floodwater during the night. Leaf gas films enhance photosynthesis during submergence leading to improved O(2) production and sugar status, and therefore contribute to the submergence tolerance of rice. © 2012 The Authors. New Phytologist © 2012 New Phytologist Trust.

Global impacts of energy demand on the freshwater resources of nations.

PubMed

Holland, Robert Alan; Scott, Kate A; Flörke, Martina; Brown, Gareth; Ewers, Robert M; Farmer, Elizabeth; Kapos, Valerie; Muggeridge, Ann; Scharlemann, Jörn P W; Taylor, Gail; Barrett, John; Eigenbrod, Felix

2015-12-01

The growing geographic disconnect between consumption of goods, the extraction and processing of resources, and the environmental impacts associated with production activities makes it crucial to factor global trade into sustainability assessments. Using an empirically validated environmentally extended global trade model, we examine the relationship between two key resources underpinning economies and human well--being-energy and freshwater. A comparison of three energy sectors (petroleum, gas, and electricity) reveals that freshwater consumption associated with gas and electricity production is largely confined within the territorial boundaries where demand originates. This finding contrasts with petroleum, which exhibits a varying ratio of territorial to international freshwater consumption, depending on the origin of demand. For example, although the United States and China have similar demand associated with the petroleum sector, international freshwater consumption is three times higher for the former than the latter. Based on mapping patterns of freshwater consumption associated with energy sectors at subnational scales, our analysis also reveals concordance between pressure on freshwater resources associated with energy production and freshwater scarcity in a number of river basins globally. These energy-driven pressures on freshwater resources in areas distant from the origin of energy demand complicate the design of policy to ensure security of fresh water and energy supply. Although much of the debate around energy is focused on greenhouse gas emissions, our findings highlight the need to consider the full range of consequences of energy production when designing policy.

Rapid Arctic Changes due to Infrastructure and Climate (RATIC) in the Russian North

NASA Astrophysics Data System (ADS)

Walker, D. A.; Kofinas, G.; Raynolds, M. K.; Kanevskiy, M. Z.; Shur, Y.; Ambrosius, K.; Matyshak, G. V.; Romanovsky, V. E.; Kumpula, T.; Forbes, B. C.; Khukmotov, A.; Leibman, M. O.; Khitun, O.; Lemay, M.; Allard, M.; Lamoureux, S. F.; Bell, T.; Forbes, D. L.; Vincent, W. F.; Kuznetsova, E.; Streletskiy, D. A.; Shiklomanov, N. I.; Fondahl, G.; Petrov, A.; Roy, L. P.; Schweitzer, P.; Buchhorn, M.

2015-12-01

The Rapid Arctic Transitions due to Infrastructure and Climate (RATIC) initiative is a forum developed by the International Arctic Science Committee (IASC) Terrestrial, Cryosphere, and Social & Human working groups for developing and sharing new ideas and methods to facilitate the best practices for assessing, responding to, and adaptively managing the cumulative effects of Arctic infrastructure and climate change. An IASC white paper summarizes the activities of two RATIC workshops at the Arctic Change 2014 Conference in Ottawa, Canada and the 2015 Third International Conference on Arctic Research Planning (ICARP III) meeting in Toyama, Japan (Walker & Pierce, ed. 2015). Here we present an overview of the recommendations from several key papers and posters presented at these conferences with a focus on oil and gas infrastructure in the Russian north and comparison with oil development infrastructure in Alaska. These analyses include: (1) the effects of gas- and oilfield activities on the landscapes and the Nenets indigenous reindeer herders of the Yamal Peninsula, Russia; (2) a study of urban infrastructure in the vicinity of Norilsk, Russia, (3) an analysis of the effects of pipeline-related soil warming on trace-gas fluxes in the vicinity of Nadym, Russia, (4) two Canadian initiatives that address multiple aspects of Arctic infrastructure called Arctic Development and Adaptation to Permafrost in Transition (ADAPT) and the ArcticNet Integrated Regional Impact Studies (IRIS), and (5) the effects of oilfield infrastructure on landscapes and permafrost in the Prudhoe Bay region, Alaska.

Global impacts of energy demand on the freshwater resources of nations

PubMed Central

Holland, Robert Alan; Scott, Kate A.; Flörke, Martina; Brown, Gareth; Ewers, Robert M.; Farmer, Elizabeth; Kapos, Valerie; Muggeridge, Ann; Taylor, Gail; Barrett, John; Eigenbrod, Felix

2015-01-01

The growing geographic disconnect between consumption of goods, the extraction and processing of resources, and the environmental impacts associated with production activities makes it crucial to factor global trade into sustainability assessments. Using an empirically validated environmentally extended global trade model, we examine the relationship between two key resources underpinning economies and human well-being—energy and freshwater. A comparison of three energy sectors (petroleum, gas, and electricity) reveals that freshwater consumption associated with gas and electricity production is largely confined within the territorial boundaries where demand originates. This finding contrasts with petroleum, which exhibits a varying ratio of territorial to international freshwater consumption, depending on the origin of demand. For example, although the United States and China have similar demand associated with the petroleum sector, international freshwater consumption is three times higher for the former than the latter. Based on mapping patterns of freshwater consumption associated with energy sectors at subnational scales, our analysis also reveals concordance between pressure on freshwater resources associated with energy production and freshwater scarcity in a number of river basins globally. These energy-driven pressures on freshwater resources in areas distant from the origin of energy demand complicate the design of policy to ensure security of fresh water and energy supply. Although much of the debate around energy is focused on greenhouse gas emissions, our findings highlight the need to consider the full range of consequences of energy production when designing policy. PMID:26627262

Life cycle assessment of pyrolysis, gasification and incineration waste-to-energy technologies: Theoretical analysis and case study of commercial plants.

PubMed

Dong, Jun; Tang, Yuanjun; Nzihou, Ange; Chi, Yong; Weiss-Hortala, Elsa; Ni, Mingjiang

2018-06-01

Municipal solid waste (MSW) pyrolysis and gasification are in development, stimulated by a more sustainable waste-to-energy (WtE) option. Since comprehensive comparisons of the existing WtE technologies are fairly rare, this study aims to conduct a life cycle assessment (LCA) using two sets of data: theoretical analysis, and case studies of large-scale commercial plants. Seven systems involving thermal conversion (pyrolysis, gasification, incineration) and energy utilization (steam cycle, gas turbine/combined cycle, internal combustion engine) are modeled. Theoretical analysis results show that pyrolysis and gasification, in particular coupled with a gas turbine/combined cycle, have the potential to lessen the environmental loadings. The benefits derive from an improved energy efficiency leading to less fossil-based energy consumption, and the reduced process emissions by syngas combustion. Comparison among the four operating plants (incineration, pyrolysis, gasification, gasification-melting) confirms a preferable performance of the gasification plant attributed to syngas cleaning. The modern incineration is superior over pyrolysis and gasification-melting at present, due to the effectiveness of modern flue gas cleaning, use of combined heat and power (CHP) cycle, and ash recycling. The sensitivity analysis highlights a crucial role of the plant efficiency and pyrolysis char land utilization. The study indicates that the heterogeneity of MSW and syngas purification technologies are the most relevant impediments for the current pyrolysis/gasification-based WtE. Potential development should incorporate into all process aspects to boost the energy efficiency, improve incoming waste quality, and achieve efficient residues management. Copyright © 2018 Elsevier B.V. All rights reserved.

Molecular characterization of macrolide resistant Streptococcus pyogenes isolates from pharyngitis patients in Serbia.

PubMed

Opavski, Natasa; Gajic, Ina; Borek, Anna L; Obszańska, Katarzyna; Stanojevic, Maja; Lazarevic, Ivana; Ranin, Lazar; Sitkiewicz, Izabela; Mijac, Vera

2015-07-01

A steady increase in macrolide resistance in Streptococcus pyogenes, group A streptococci (GAS) was reported in Serbia during 2004-2009 (9.9%). However, there are no data on the molecular epidemiology of pharyngeal macrolide resistance GAS (MRGAS) isolates. Therefore, the aims of this first nationwide study were to examine the prevalence of macrolide resistance in Serbian GAS and to determine their resistance phenotypes, genotypes and clonal relationships. Overall 3893 non-duplicate pharyngeal S. pyogenes isolates from outpatients with GAS infection were collected throughout country during 2008 and 2009. Among 486 macrolide resistant pharyngeal isolates collected, 103 were further characterized. Macrolide resistance phenotypes and genotypes were determined by double-disk diffusion test and PCR, respectively. Strain relatedness was determined by emm typing, multilocus sequence typing (MLST), multilocus variable tandem repeat analysis (MLVA), phage profiling (PP) and virulence factor profiling (VFP). Overall, macrolide resistance among GAS isolates in Serbia was 12.5%. M phenotype was the most common (71.8%), followed by iMLS (18.4%) and cMLS (9.7%). Three clonal complexes--emm75/mefA/ST49, emm12/mefA/ST36 and emm77/ermA/tetO/ST63 comprised over 90% of the tested strains. Although MLVA, PP and VFP distinguished 10, 20 and 12 different patterns, respectively, cluster analysis disclosed only small differences between strains which belonged to the same emm/ST type. Our data indicate dominance of three major internationally widely disseminated macrolide resistant clones and a high genetic homogeneity among the Serbian MRGAS population. Continued surveillance of macrolide resistance and clonal composition in MRGAS in Serbia in future is necessary to determine stability of MRGAS clones and to guide therapy strategies. Copyright © 2015 Elsevier B.V. All rights reserved.

Engine systems analysis results of the Space Shuttle Main Engine redesigned powerhead initial engine level testing

NASA Technical Reports Server (NTRS)

Sander, Erik J.; Gosdin, Dennis R.

1992-01-01

Engineers regularly analyze SSME ground test and flight data with respect to engine systems performance. Recently, a redesigned SSME powerhead was introduced to engine-level testing in part to increase engine operational margins through optimization of the engine internal environment. This paper presents an overview of the MSFC personnel engine systems analysis results and conclusions reached from initial engine level testing of the redesigned powerhead, and further redesigns incorporated to eliminate accelerated main injector baffle and main combustion chamber hot gas wall degradation. The conclusions are drawn from instrumented engine ground test data and hardware integrity analysis reports and address initial engine test results with respect to the apparent design change effects on engine system and component operation.

Experimental investigation of temperature rise in bone drilling with cooling: A comparison between modes of without cooling, internal gas cooling, and external liquid cooling.

PubMed

Shakouri, Ehsan; Haghighi Hassanalideh, Hossein; Gholampour, Seifollah

2018-01-01

Bone fracture occurs due to accident, aging, and disease. For the treatment of bone fractures, it is essential that the bones are kept fixed in the right place. In complex fractures, internal fixation or external methods are used to fix the fracture position. In order to immobilize the fracture position and connect the holder equipment to it, bone drilling is required. During the drilling of the bone, the required forces to chip formation could cause an increase in the temperature. If the resulting temperature increases to 47 °C, it causes thermal necrosis of the bone. Thermal necrosis decreases bone strength in the hole and, subsequently, due to incomplete immobilization of bone, fracture repair is not performed correctly. In this study, attempts have been made to compare local temperature increases in different processes of bone drilling. This comparison has been done between drilling without cooling, drilling with gas cooling, and liquid cooling on bovine femur. Drilling tests with gas coolant using direct injection of CO 2 and N 2 gases were carried out by internal coolant drill bit. The results showed that with the use of gas coolant, the elevation of temperature has limited to 6 °C and the thermal necrosis is prevented. Maximum temperature rise reached in drilling without cooling was 56 °C, using gas and liquid coolant, a maximum temperature elevation of 43 °C and 42 °C have been obtained, respectively. This resulted in decreased possibility of thermal necrosis of bone in drilling with gas and liquid cooling. However, the results showed that the values obtained with the drilling method with direct gas cooling are independent of the rotational speed of drill.

36th International Symposium on Combustion (ISOC2016)

DTIC Science & Technology

2016-12-01

GREENHOUSE GASES / IC ENGINE COMBUSTION I GAS TURBINE COMBUSTION I NOVEL COMBUSTION CONCEPTS, TECHNOLOGIES AND SYSTEMS 15. SUBJECT TERMS Reaction...pollutants and greenhouse gases; IC engine combustion; Gas turbine combustion; Novel combustion concepts, technologies and systems 16. SECURITY...PLENARY LECTURE TRANSFER (15 min) am Turbulent Flames IC Engines Laminar Flames Reaction Kinetics Gas Turbines Soot Solid Fuels/Pollutants

Alternative Fuels Data Center: St. Louis Airport Relies on Biodiesel and

Science.gov Websites

Natural Gas VehiclesA> St. Louis Airport Relies on Biodiesel and Natural Gas Vehicles to someone International Airport relies on biodiesel and natural gas buses and trucks. For information about this project FuelEconomy.gov. Provided by Maryland Public Television Related Videos Photo of a car Electric Vehicles Charge up

The Dairy Greenhouse Gas Model: A Tool for estimating greenhouse gas emissions and the carbon footprint of dairy production systems

USDA-ARS?s Scientific Manuscript database

Greenhouse gas (GHG) emissions and their potential impact on the environment has become an important national and international concern. Animal agriculture is a recognized source of GHG emissions, but good information does not exist on the net emissions from our farms. A software tool called the Dai...

Cooled-Spool Piston Compressor

NASA Technical Reports Server (NTRS)

Morris, Brian G.

1994-01-01

Proposed cooled-spool piston compressor driven by hydraulic power and features internal cooling of piston by flowing hydraulic fluid to limit temperature of compressed gas. Provides sufficient cooling for higher compression ratios or reactive gases. Unlike conventional piston compressors, all parts of compressed gas lie at all times within relatively short distance of cooled surface so that gas cooled more effectively.

A decision-analytic approach to predict state regulation of hydraulic fracturing.

PubMed

Linkov, Igor; Trump, Benjamin; Jin, David; Mazurczak, Marcin; Schreurs, Miranda

2014-01-01

The development of horizontal drilling and hydraulic fracturing methods has dramatically increased the potential for the extraction of previously unrecoverable natural gas. Nonetheless, the potential risks and hazards associated with such technologies are not without controversy and are compounded by frequently changing information and an uncertain landscape of international politics and laws. Where each nation has its own energy policies and laws, predicting how a state with natural gas reserves that require hydraulic fracturing will regulate the industry is of paramount importance for potential developers and extractors. We present a method for predicting hydraulic fracturing decisions using multiple-criteria decision analysis. The case study evaluates the decisions of five hypothetical countries with differing political, social, environmental, and economic priorities, choosing among four policy alternatives: open hydraulic fracturing, limited hydraulic fracturing, completely banned hydraulic fracturing, and a cap and trade program. The result is a model that identifies the preferred policy alternative for each archetypal country and demonstrates the sensitivity the decision to particular metrics. Armed with such information, observers can predict each country's likely decisions related to natural gas exploration as more data become available or political situations change. Decision analysis provides a method to manage uncertainty and address forecasting concerns where rich and objective data may be lacking. For the case of hydraulic fracturing, the various political pressures and extreme uncertainty regarding the technology's risks and benefits serve as a prime platform to demonstrate how decision analysis can be used to predict future behaviors.

Discontinuous Inter-Granular Separations (DIGS) in the Gas Nitride Layer of ISS Race Rings

NASA Technical Reports Server (NTRS)

Figert, John; Dasgupta, Rajib; Martinez, James

2010-01-01

The starboard solar alpha rotary joint (SARJ) race ring on the International space station (ISS) failed due to severe spalling of the outer diameter, 45 degree (outer canted) nitrided surface. Subsequent analysis at NASA-KSC revealed that almost all of the debris generated due to the failure was nitrided 15-5 stainless steel. Subsequent analysis of the nitride control coupons (NCC) at NASA-JSC revealed the presence of discontinuous inter-granular separations (DIGS) in the gas nitride layer. These DIGS were present in the inter-granular networking located in the top 2 mils of the nitride layer. The manufacturer's specification requires the maximum white structure to be 0.0003 inches and intergranular networking below the allowable white structure depth to be cause for rejection; a requirement that the NCCs did not meet. Subsequent testing and analysis revealed that lower DIGS content significantly lowered the probability of nitride spalling in simulated, dry condition runs. One batch of nitride samples with DIGS content similar to the port SARJ (did not fail on orbit) which exhibited almost no nitride spalling after being run on one test rig. Another batch of nitride samples with DIGS content levels similar to the starboard SARJ exhibited significant nitride spalling on the same test rig with the same load under dry conditions. Although DIGS were not the root cause of starboard race ring failure, testing indicates that increased DIGS reduced the robustness of the gas nitride layer under dry operating conditions.

Supersonic gas-liquid cleaning system

NASA Technical Reports Server (NTRS)

Caimi, Raoul E. B.; Thaxton, Eric A.

1994-01-01

A system to perform cleaning and cleanliness verification is being developed to replace solvent flush methods using CFC 113 for fluid system components. The system is designed for two purposes: internal and external cleaning and verification. External cleaning is performed with the nozzle mounted at the end of a wand similar to a conventional pressure washer. Internal cleaning is performed with a variety of fixtures designed for specific applications. Internal cleaning includes tubes, pipes, flex hoses, and active fluid components such as valves and regulators. The system uses gas-liquid supersonic nozzles to generate high impingement velocities at the surface of the object to be cleaned. Compressed air or any inert gas may be used to provide the conveying medium for the liquid. The converging-diverging nozzles accelerate the gas-liquid mixture to supersonic velocities. The liquid being accelerated may be any solvent including water. This system may be used commercially to replace CFC and other solvent cleaning methods widely used to remove dust, dirt, flux, and lubricants. In addition, cleanliness verification can be performed without the solvents which are typically involved. This paper will present the technical details of the system, the results achieved during testing at KSC, and future applications for this system.

Supersonic gas-liquid cleaning system

NASA Astrophysics Data System (ADS)

Caimi, Raoul E. B.; Thaxton, Eric A.

1994-02-01

A system to perform cleaning and cleanliness verification is being developed to replace solvent flush methods using CFC 113 for fluid system components. The system is designed for two purposes: internal and external cleaning and verification. External cleaning is performed with the nozzle mounted at the end of a wand similar to a conventional pressure washer. Internal cleaning is performed with a variety of fixtures designed for specific applications. Internal cleaning includes tubes, pipes, flex hoses, and active fluid components such as valves and regulators. The system uses gas-liquid supersonic nozzles to generate high impingement velocities at the surface of the object to be cleaned. Compressed air or any inert gas may be used to provide the conveying medium for the liquid. The converging-diverging nozzles accelerate the gas-liquid mixture to supersonic velocities. The liquid being accelerated may be any solvent including water. This system may be used commercially to replace CFC and other solvent cleaning methods widely used to remove dust, dirt, flux, and lubricants. In addition, cleanliness verification can be performed without the solvents which are typically involved. This paper will present the technical details of the system, the results achieved during testing at KSC, and future applications for this system.

Land Subsidence International Symposium held in Venice

NASA Astrophysics Data System (ADS)

The Third International Symposium on Land Subsidence was held March 18-25, 1984, in Venice, Italy. Sponsors were the Ground-Water Commission of the International Association of Hydrological Sciences (IAHS), the United Nations Educational, Scientific, and Cultural Organization (UNESCO), the Italian National Research Council (CNR), the Italian Regions of Veneto and Emilia-Romagna, the Italian Municipalities of Venice, Ravenna, and Modena, the Venice Province, and the European Research Office. Cosponsors included the International Association of Hydrogeologists (IAH), the International Society for Soil Mechanics and Foundation Engineering (ISSMFE), and the Association of Geoscientists for International Development (AGID).Organized within the framework of UNESCO's International Hydrological Program, the symposium brought together over 200 international interdisciplinary specialists in the problems of land subsidence due to fluid and mineral withdrawal. Because man's continuing heavy development of groundwater, gas, oil, and minerals is changing the natural regime and thus causing more and more subsiding areas in the world, there had been sufficient new land subsidence occurrence, problems, research, and remedial measures since the 1976 Second International Symposium held in Anaheim, California, to develop a most interesting program of nearly 100 papers from about 30 countries. The program consisted of papers covering case histories of fluid and mineral withdrawal, engineering theory and analysis, karst “sink-hole”-type subsidence, subsidence due to dewatering of organic deposits or due to application of water (hydrocompaction), instrumentation, legal, socioeconomic, and environmental effects of land subsidence, and remedial works.

Analysis of heat and mass transfer during condensation over a porous substrate.

PubMed

Balasubramaniam, R; Nayagam, V; Hasan, M M; Khan, L

2006-09-01

Condensing heat exchangers are important in many space applications for thermal and humidity control systems. The International Space Station uses a cooled fin surface to condense moisture from humid air that is blown over it. The condensate and the air are "slurped" into a system that separates air and water by centrifugal forces. The use of a cooled porous substrate is an attractive alternative to the fin where condensation and liquid/gas separation can be achieved in a single step. We analyze the heat and mass transfer during condensation of moisture from flowing air over such a cooled, flat, porous substrate. A fully developed regime is investigated for coupled mass, momentum and energy transport in the gas phase, and momentum and energy transport in the condensate layer on the porous substrate and through the porous medium.

Compressed Natural Gas Safety in Transit Operations

DOT National Transportation Integrated Search

1995-09-14

This report examines the safety issues relating to the use of Compressed Natural Gas (CNG) in transit service. The safety issues were determined by on-site surveys performed by Battelle of Columbus, Ohio and Science Applications International Corpora...

Recovering and Mining Asteroids with a Gas-Sealed Enclosure

NASA Astrophysics Data System (ADS)

Jenniskens, P.; Damer, B.; Norkus, R.; Pilotz, S.; Grigsby, B.; Adams, C.; Blair, B. R.

2015-01-01

The internal structure of weakly consolidated rubble piles and primitive asteroids can be studied closer to home, and such asteroids can be mined, if it is possible to create a gas-sealed enclosure around the asteroid.

Internal insulation system development

NASA Technical Reports Server (NTRS)

Gille, J. P.

1973-01-01

The development of an internal insulation system for cryogenic liquids is described. The insulation system is based on a gas layer concept in which capillary or surface tension effects are used to maintain a stable gas layer within a cellular core structure between the tank wall and the contained cryogen. In this work, a 1.8 meter diameter tank was insulated and tested with liquid hydrogen. Ability to withstand cycling of the aluminum tank wall to 450 K was a design and test condition.

International energy annual 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1996-12-01

The International Energy Annual presents information and trends on world energy production and consumption for petroleum, natural gas, coal, and electricity. Production and consumption data are reported in standard units as well as British thermal units (Btu). Trade and reserves are shown for petroleum, natural gas, and coal. Data are provided on crude oil refining capacity and electricity installed capacity by type. Prices are included for selected crude oils and for refined petroleum products in selected countries. Population and Gross Domestic Product data are also provided.

Internal energy fluctuations of a granular gas under steady uniform shear flow.

PubMed

Brey, J Javier; García de Soria, M I; Maynar, P

2012-09-01

The stochastic properties of the total internal energy of a dilute granular gas in the steady uniform shear flow state are investigated. A recent theory formulated for fluctuations about the homogeneous cooling state is extended by analogy with molecular systems. The theoretical predictions are compared with molecular dynamics simulation results. Good agreement is found in the limit of weak inelasticity, while systematic and relevant discrepancies are observed when the inelasticity increases. The origin of this behavior is discussed.

Development of a candidate reference measurement procedure for the analysis of cortisol in human serum samples by isotope dilution-gas chromatography-mass spectrometry.

PubMed

Kawaguchi, Migaku; Takatsu, Akiko

2009-08-01

A candidate reference measurement procedure involving isotope dilution coupled with gas chromatography-mass spectrometry (GC-MS) has been developed and critically evaluated. An isotopically labeled internal standard, cortisol-d(2), was added to a serum sample. After equilibration, solid-phase extractions (SPE) for sample preparation and derivatization with heptafluorobutyric anhydride (HFBA) were performed for GC-MS analysis. The limit of detection (LOD) and the limit of quantification (LOQ) were 5 and 20 ng g(-1), respectively. The recovery of the added cortisol ranged from 99.8 to 101.0%. Excellent precision was obtained with a within-day variation (RSD) of 0.7% for GC-MS analysis. The accuracy of the measurement was evaluated by comparing of results of this reference measurement procedure on lyophilized human serum reference materials for cortisol (European Reference Materials (ERM)-DA 192) as Certified Reference Materials (CRMs). The results of this method for total cortisol agreed with the certified values within some uncertainty. This method, which demonstrates simply, easy, good accuracy, high precision, and is free from interferences from structural analogues, qualifies as a reference measurement procedure.

Fast and solvent-free quantitation of boar taint odorants in pig fat by stable isotope dilution analysis-dynamic headspace-thermal desorption-gas chromatography/time-of-flight mass spectrometry.

PubMed

Fischer, Jochen; Haas, Torsten; Leppert, Jan; Lammers, Peter Schulze; Horner, Gerhard; Wüst, Matthias; Boeker, Peter

2014-09-01

Boar taint is a specific off-odour of boar meat products, known to be caused by at least three unpleasant odorants, with very low odour thresholds. Androstenone is a boar pheromone produced in the testes, whereas skatole and indole originate from the microbial breakdown of tryptophan in the intestinal tract. A new procedure, applying stable isotope dilution analysis (SIDA) and dynamic headspace-thermal desorption-gas chromatography/time-of-flight mass spectrometry (dynHS-TD-GC/TOFMS) for the simultaneous quantitation of these boar taint compounds in pig fat was elaborated and validated in this paper. The new method is characterised by a simple and solvent-free dynamic headspace sampling. The deuterated compounds d3-androstenone, d3-skatole and d6-indole were used as internal standards to eliminate matrix effects. The method validation performed revealed low limits of detection (LOD) and quantitation (LOQ) with high accuracy and precision, thus confirming the feasibility of the new dynHS-TD-GC/TOFMS approach for routine analysis. Copyright © 2014 Elsevier Ltd. All rights reserved.

Authentication of pineapple (Ananas comosus [L.] Merr.) fruit maturity stages by quantitative analysis of γ- and δ-lactones using headspace solid-phase microextraction and chirospecific gas chromatography-selected ion monitoring mass spectrometry (HS-SPME-GC-SIM-MS).

PubMed

Steingass, Christof B; Langen, Johannes; Carle, Reinhold; Schmarr, Hans-Georg

2015-02-01

Headspace solid phase microextraction and chirospecific gas chromatography-mass spectrometry in selected ion monitoring mode (HS-SPME-GC-SIM-MS) allowed quantitative determination of δ-lactones (δ-C8, δ-C10) and γ-lactones (γ-C6, γ-C8, γ-C10). A stable isotope dilution assay (SIDA) with d7-γ-decalactone as internal standard was used for quantitative analysis of pineapple lactones that was performed at three progressing post-harvest stages of fully ripe air-freighted and green-ripe sea-freighted fruits, covering the relevant shelf-life of the fruits. Fresh pineapples harvested at full maturity were characterised by γ-C6 of high enantiomeric purity remaining stable during the whole post-harvest period. In contrast, the enantiomeric purity of γ-C6 significantly decreased during post-harvest storage of sea-freighted pineapples. The biogenetical background and the potential of chirospecific analysis of lactones for authentication and quality evaluation of fresh pineapple fruits are discussed. Copyright © 2014 Elsevier Ltd. All rights reserved.

Gas release and conductivity modification studies

NASA Technical Reports Server (NTRS)

Linson, L. M.; Baxter, D. C.

1979-01-01

The behavior of gas clouds produced by releases from orbital velocity in either a point release or venting mode is described by the modification of snowplow equations valid in an intermediate altitude regime. Quantitative estimates are produced for the time dependence of the radius of the cloud, the average internal energy, the translational velocity, and the distance traveled. The dependence of these quantities on the assumed density profile, the internal energy of the gas, and the ratio of specific heats is examined. The new feature is the inclusion of the effect of the large orbital velocity. The resulting gas cloud models are used to calculate the characteristics of the field line integrated Pedersen conductivity enhancements that would be produced by the release of barium thermite at orbital velocity in either the point release or venting modes as a function of release altitude and chemical payload weight.

Iran seeking help in regaining prerevolution oil and gas flow

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tippee, B.

1996-02-19

This paper reviews the goals of the Iranian oil and gas industry to rebuild their oil and gas production facilities by using foreign investment. It discusses the historical consequences of war in the region to diminish the production and postpone the recovery of natural gas which is currently flared. It describes the major projects Iran hopes to develop through international partnerships and includes field development, pipeline construction, gas reinjection, gas treatment facilities, and new offshore operation. The paper also reviews the US policy on Iran and its attempt to apply sanctions towards this country.

Analysis of transient fission gas behaviour in oxide fuel using BISON and TRANSURANUS

DOE PAGES

Barani, T.; Bruschi, E.; Pizzocri, D.; ...

2017-01-03

The modelling of fission gas behaviour is a crucial aspect of nuclear fuel analysis in view of the related effects on the thermo-mechanical performance of the fuel rod, which can be particularly significant during transients. Experimental observations indicate that substantial fission gas release (FGR) can occur on a small time scale during transients (burst release). To accurately reproduce the rapid kinetics of burst release in fuel performance calculations, a model that accounts for non-diffusional mechanisms such as fuel micro-cracking is needed. In this work, we present and assess a model for transient fission gas behaviour in oxide fuel, which ismore » applied as an extension of diffusion-based models to allow for the burst release effect. The concept and governing equations of the model are presented, and the effect of the newly introduced parameters is evaluated through an analytic sensitivity analysis. Then, the model is assessed for application to integral fuel rod analysis. The approach that we take for model assessment involves implementation in two structurally different fuel performance codes, namely, BISON (multi-dimensional finite element code) and TRANSURANUS (1.5D semi-analytic code). The model is validated against 19 Light Water Reactor fuel rod irradiation experiments from the OECD/NEA IFPE (International Fuel Performance Experiments) database, all of which are simulated with both codes. The results point out an improvement in both the qualitative representation of the FGR kinetics and the quantitative predictions of integral fuel rod FGR, relative to the canonical, purely diffusion-based models, with both codes. The overall quantitative improvement of the FGR predictions in the two codes is comparable. Furthermore, calculated radial profiles of xenon concentration are investigated and compared to experimental data, demonstrating the representation of the underlying mechanisms of burst release by the new model.« less

Nanoporous Materials for the Onboard Storage of Natural Gas.

PubMed

Kumar, K Vasanth; Preuss, Kathrin; Titirici, Maria-Magdalena; Rodríguez-Reinoso, Francisco

2017-02-08

Climate change, global warming, urban air pollution, energy supply uncertainty and depletion, and rising costs of conventional energy sources are, among others, potential socioeconomic threats that our community faces today. Transportation is one of the primary sectors contributing to oil consumption and global warming, and natural gas (NG) is considered to be a relatively clean transportation fuel that can significantly improve local air quality, reduce greenhouse-gas emissions, and decrease the energy dependency on oil sources. Internal combustion engines (ignited or compression) require only slight modifications for use with natural gas; rather, the main problem is the relatively short driving distance of natural-gas-powered vehicles due to the lack of an appropriate storage method for the gas, which has a low energy density. The U.S. Department of Energy (DOE) has set some targets for NG storage capacity to obtain a reasonable driving range in automotive applications, ruling out the option of storing methane at cryogenic temperatures. In recent years, both academia and industry have foreseen the storage of natural gas by adsorption (ANG) in porous materials, at relatively low pressures and ambient temperatures, as a solution to this difficult problem. This review presents recent developments in the search for novel porous materials with high methane storage capacities. Within this scenario, both carbon-based materials and metal-organic frameworks are considered to be the most promising materials for natural gas storage, as they exhibit properties such as large surface areas and micropore volumes, that favor a high adsorption capacity for natural gas. Recent advancements, technological issues, advantages, and drawbacks involved in natural gas storage in these two classes of materials are also summarized. Further, an overview of the recent developments and technical challenges in storing natural gas as hydrates in wetted porous carbon materials is also included. Finally, an analysis of design factors and technical issues that need to be considered before adapting vehicles to ANG technology is also presented.

Determining gas hydrate distribution in sands using integrated analysis of well log and seismic data in the Terrebonne Basin, Gulf of Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hillman, Jess; Cook, Ann; Daigle, Hugh

The Terrebonne Basin is a salt bounded mini-basin in the northeast section of the Walker Ridge protraction area in the Gulf of Mexico, and the main site for an upcoming gas-hydrate focused International Ocean Discovery Program (IODP) cruise. The basin is infilled by an increasingly mud rich sedimentary sequence with several 5-15 meter gas-hydrate filled sand units of Miocene to Pliocene age overlying the up-domed salt. These gas-hydrate filled sand units can be identified in logging while drilling data from two existing wells in the Terrebonne Basin, drilled in 2009 by the Gas Hydrate Joint Industry Project (JIP) Leg 2.more » The sand units are cross cut by a distinct bottom-simulating reflector (BSR), and are clearly characterized by a polarity reversal in the sand units. The polarity reversal is caused by a positive gas-hydrate filled sand within the stability zone changing to negative gas-bearing sand. Using well data and calculated synthetic seismogram well ties we are able to identify several additional 1-4 meter gas-hydrate and water-saturated sand units associated with thick (100-200 m-thick), fine grained, hydrate bearing fractured units in the upper sedimentary sequence on the seismic data. Following on previous work, we propose that microbial generation of methane occurring within the fine-grained, fractured units acts as a source for gas hydrate formation in the thin sands. In contrast, it has been proposed that the gas hydrate in the 5-15 m-thick sands first discovered by the JIP was originates from a deeper thermogenic source. Through correlating hydrate occurrence in sands from well data, to amplitudes derived from the seismic data, we can estimate possible distribution of hydrate across the basin. Overall, we find the Terrebonne basin to be a complex gas hydrate system with multiple mechanisms of methane generation and migration.« less

Prospects for energy recovery during hydrothermal and biological processing of waste biomass.

PubMed

Gerber Van Doren, Léda; Posmanik, Roy; Bicalho, Felipe A; Tester, Jefferson W; Sills, Deborah L

2017-02-01

Thermochemical and biological processes represent promising technologies for converting wet biomasses, such as animal manure, organic waste, or algae, to energy. To convert biomass to energy and bio-chemicals in an economical manner, internal energy recovery should be maximized to reduce the use of external heat and power. In this study, two conversion pathways that couple hydrothermal liquefaction with anaerobic digestion or catalytic hydrothermal gasification were compared. Each of these platforms is followed by two alternative processes for gas utilization: 1) combined heat and power; and 2) combustion in a boiler. Pinch analysis was applied to integrate thermal streams among unit processes and improve the overall system efficiency. A techno-economic analysis was conducted to compare the feasibility of the four modeled scenarios under different market conditions. Our results show that a systems approach designed to recover internal heat and power can reduce external energy demands and increase the overall process sustainability. Copyright © 2016 Elsevier Ltd. All rights reserved.

Mobile membrane introduction tandem mass spectrometry for on-the-fly measurements and adaptive sampling of VOCs around oil and gas projects in Alberta, Canada

NASA Astrophysics Data System (ADS)

Krogh, E.; Gill, C.; Bell, R.; Davey, N.; Martinsen, M.; Thompson, A.; Simpson, I. J.; Blake, D. R.

2012-12-01

The release of hydrocarbons into the environment can have significant environmental and economic consequences. The evolution of smaller, more portable mass spectrometers to the field can provide spatially and temporally resolved information for rapid detection, adaptive sampling and decision support. We have deployed a mobile platform membrane introduction mass spectrometer (MIMS) for the in-field simultaneous measurement of volatile and semi-volatile organic compounds. In this work, we report instrument and data handling advances that produce geographically referenced data in real-time and preliminary data where these improvements have been combined with high precision ultra-trace VOCs analysis to adaptively sample air plumes near oil and gas operations in Alberta, Canada. We have modified a commercially available ion-trap mass spectrometer (Griffin ICX 400) with an in-house temperature controlled capillary hollow fibre polydimethylsiloxane (PDMS) polymer membrane interface and in-line permeation tube flow cell for a continuously infused internal standard. The system is powered by 24 VDC for remote operations in a moving vehicle. Software modifications include the ability to run continuous, interlaced tandem mass spectrometry (MS/MS) experiments for multiple contaminants/internal standards. All data are time and location stamped with on-board GPS and meteorological data to facilitate spatial and temporal data mapping. Tandem MS/MS scans were employed to simultaneously monitor ten volatile and semi-volatile analytes, including benzene, toluene, ethylbenzene and xylene (BTEX), reduced sulfur compounds, halogenated organics and naphthalene. Quantification was achieved by calibrating against a continuously infused deuterated internal standard (toluene-d8). Time referenced MS/MS data were correlated with positional data and processed using Labview and Matlab to produce calibrated, geographical Google Earth data-visualizations that enable adaptive sampling protocols. This real-time approach has been employed in a moving vehicle to identify and track downwind plumes of fugitive VOC emissions near hydrocarbon upgrading and chemical processing facilities in Fort Saskatchewan, Alberta. This information was relayed to a trailing vehicle, which collected stationary grab samples in evacuated canisters for ultra trace analysis of over seventy VOC analytes. In addition, stationary time series data were collected and compared with grab samples co-located with our sampling line. Spatially and temporally resolved, time referenced MS/MS data for several air contaminants associated with oil and gas processing were processed in real time to produce geospatial data for visualization in Google Earth. This information was used to strategically locate grab samples for high precision, ultra trace analysis.

Carbon pricing, nuclear power and electricity markets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cameron, R.; Keppler, J. H.

2012-07-01

In 2010, the NEA in conjunction with the International Energy Agency produced an analysis of the Projected Costs of Electricity for almost 200 power plants, covering nuclear, fossil fuel and renewable electricity generation. That analysis used lifetime costs to consider the merits of each technology. However, the lifetime cost analysis is less applicable in liberalised markets and does not look specifically at the viewpoint of the private investor. A follow-up NEA assessment of the competitiveness of nuclear energy against coal- and gas-fired generation under carbon pricing has considered just this question. The economic competition in electricity markets is today betweenmore » nuclear energy and gas-fired power generation, with coal-fired power generation not being competitive as soon as even modest carbon pricing is introduced. Whether nuclear energy or natural gas comes out ahead in their competition depends on a number of assumptions, which, while all entirely reasonable, yield very different outcomes. The analysis in this study has been developed on the basis of daily data from European power markets over the last five-year period. Three different methodologies, a Profit Analysis looking at historic returns over the past five years, an Investment Analysis projecting the conditions of the past five years over the lifetime of plants and a Carbon Tax Analysis (differentiating the Investment Analysis for different carbon prices) look at the issue of competitiveness from different angles. They show that the competitiveness of nuclear energy depends on a number of variables which in different configurations determine whether electricity produced from nuclear power or from CCGTs generates higher profits for its investors. These are overnight costs, financing costs, gas prices, carbon prices, profit margins (or mark-ups), the amount of coal with carbon capture and electricity prices. This paper will present the outcomes of the analysis in the context of a liberalised electricity market, looking at the impact of the seven key variables and provide conclusions on the portfolio that a utility would be advised to maintain, given the need to limit risks but also to move to low carbon power generation. Such portfolio diversification would not only limit financial investor risk, but also a number of non-financial risks (climate change, security of supply, accidents). (authors)« less

Slope stability analysis of landslide in Wayang Windu Geothermal Field, Pangalengan, West Java Province, Indonesia

NASA Astrophysics Data System (ADS)

Yuhendar, A. H.; Wusqa, U.; Kartiko, R. D.; Raya, N. R.; Misbahudin

2016-05-01

Large-scale landslide occurred in Margamukti village, Pangalengan, Bandung Regency, West Java Province, Indonesia. The landslide damaged geothermal gas pipeline along 300 m in Wayang Windu Geothermal Field. Based on field observation, landslide occured in rotational sliding movement. Laboratory analysis were conducted to obtain the characteristics of the soil. Based on the condition of the landslide in this area, the Factor of Safety can be simulated by the soil mechanics approach. Factor of safety analysis based on soil cohesion and internal friction angle was conducted using manual sensitivity analysis for back analysis. The analysis resulted soil cohesion in critical condition (FS<1) is 6.01 kPa. This value is smaller than cohesion of undisturbed slope soil sample. Water from rainfall is the most important instability factors in research area. Because it decreases cohesion in soils and increases weight and pore water pressure in granular media.

40 CFR 98.354 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... for Analysis of Reformed Gas by Gas Chromatography (incorporated by reference, see § 98.7). (4) GPA Standard 2261-00, Analysis for Natural Gas and Similar Gaseous Mixtures by Gas Chromatography (incorporated by reference, see § 98.7). (5) ASTM UOP539-97 Refinery Gas Analysis by Gas Chromatography...

Sensitivity Analysis of Methane Hydrate Reservoirs: Effects of Reservoir Parameters on Gas Productivity and Economics

NASA Astrophysics Data System (ADS)

Anderson, B. J.; Gaddipati, M.; Nyayapathi, L.

2008-12-01

This paper presents a parametric study on production rates of natural gas from gas hydrates by the method of depressurization, using CMG STARS. Seven factors/parameters were considered as perturbations from a base-case hydrate reservoir description based on Problem 7 of the International Methane Hydrate Reservoir Simulator Code Comparison Study led by the Department of Energy and the USGS. This reservoir is modeled after the inferred properties of the hydrate deposit at the Prudhoe Bay L-106 site. The included sensitivity variables were hydrate saturation, pressure (depth), temperature, bottom-hole pressure of the production well, free water saturation, intrinsic rock permeability, and porosity. A two-level (L=2) Plackett-Burman experimental design was used to study the relative effects of these factors. The measured variable was the discounted cumulative gas production. The discount rate chosen was 15%, resulting in the gas contribution to the net present value of a reservoir. Eight different designs were developed for conducting sensitivity analysis and the effects of the parameters on the real and discounted production rates will be discussed. The breakeven price in various cases and the dependence of the breakeven price on the production parameters is given in the paper. As expected, initial reservoir temperature has the strongest positive effect on the productivity of a hydrate deposit and the bottom-hole pressure in the production well has the strongest negative dependence. Also resulting in a positive correlation is the intrinsic permeability and the initial free water of the formation. Negative effects were found for initial hydrate saturation (at saturations greater than 50% of the pore space) and the reservoir porosity. These negative effects are related to the available sensible heat of the reservoir, with decreasing productivity due to decreasing available sensible heat. Finally, we conclude that for the base case reservoir, the break-even price (BEP) for natural gas is approximately 7/mcf and for warmer and deeper reservoirs the BEP can approach 5.33/mcf.

A Gas-Kinetic Scheme for Reactive Flows

NASA Technical Reports Server (NTRS)

Lian,Youg-Sheng; Xu, Kun

1998-01-01

In this paper, the gas-kinetic BGK scheme for the compressible flow equations is extended to chemical reactive flow. The mass fraction of the unburnt gas is implemented into the gas kinetic equation by assigning a new internal degree of freedom to the particle distribution function. The new variable can be also used to describe fluid trajectory for the nonreactive flows. Due to the gas-kinetic BGK model, the current scheme basically solves the Navier-Stokes chemical reactive flow equations. Numerical tests validate the accuracy and robustness of the current kinetic method.

A notable difference between ideal gas and infinite molar volume limit of van der Waals gas

NASA Astrophysics Data System (ADS)

Liu, Q. H.; Shen, Y.; Bai, R. L.; Wang, X.

2010-05-01

The van der Waals equation of state does not sufficiently represent a gas unless a thermodynamic potential with two proper and independent variables is simultaneously determined. The limiting procedures under which the behaviour of the van der Waals gas approaches that of an ideal gas are letting two van der Waals coefficients be zero rather than letting the molar volume become infinitely large; otherwise, the partial derivative of internal energy with respect to pressure at a fixed temperature does not vanish.

Gas chromatography-mass spectrometry analysis of di-n-octyl disulfide in a straight oil metalworking fluid: application of differential permeation and Box-Cox transformation.

PubMed

Xu, Wenhai; Que Hee, Shane S

2006-01-06

The aim of this study was to identify and quantify an unknown peak in the chromatogram of a very complex mixture, a straight oil metalworking fluid (MWF). The fraction that permeated through a thin nitrile polymer membrane had less mineral oil background than the original MWF did at the retention time of the unknown peak, thus facilitating identification by total ion current (TIC) gas chromatography-mass spectrometry (GC-MS). The peak proved to be di-n-octyl disulfide (DOD) through retention time and mass spectral comparisons. Quantitation of DOD was by extracted ion chromatogram analysis of the DOD molecular ion (mass-to-charge ratio (m/z) 290), and of the m/z 71 ion for the internal standard, n-triacontane. Linear models of the area ratio (y) of these two ions versus DOD concentration showed a systematic negative bias at low concentrations, a common occurrence in analysis. The linear model of y(0.8) (from Box-Cox power transformation) versus DOD concentration showed negligible bias from the lowest measured standard of 1.51 mg/L to the highest concentration tested at 75.5 mg/L. The intercept did not differ statistically from zero. The concentration of DOD in the MWF was then calculated to be 0.398+/-0.034% (w/w) by the internal standard method, and 0.387+/-0.036% (w/w) by the method of standard additions. These two results were not significantly different at p < or = 0.05. The Box-Cox transformation is therefore recommended when the data for standards are non-linear.

National surveys on internal quality control for blood gas analysis and related electrolytes in clinical laboratories of China.

PubMed

Duan, Min; Wang, Wei; Zhao, Haijian; Zhang, Chuanbao; He, Falin; Zhong, Kun; Yuan, Shuai; Wang, Zhiguo

2018-05-01

Internal quality control (IQC) is essential for precision evaluation and continuous quality improvement. This study aims to investigate the IQC status of blood gas analysis (BGA) in clinical laboratories of China from 2014 to 2017. IQC information on BGA (including pH, pCO2, pO2, Na+, K+, Ca2+, Cl-) was submitted by external quality assessment (EQA) participant laboratories and collected through Clinet-EQA reporting system in March from 2014 to 2017. First, current CVs were compared among different years and measurement systems. Then, percentages of laboratories meeting five allowable imprecision specifications for each analyte were calculated, respectively. Finally, laboratories were divided into different groups based on control rules and frequency to compare their variation trend. The current CVs of BGA were significantly decreasing from 2014 to 2017. pH and pCO2 got the highest pass rates when compared with the minimum imprecision specification, whereas pO2, Na+, K+, Ca2+, Cl- got the highest pass rates when 1/3 TEa imprecision specification applied. The pass rates of pH, pO2, Na+, K+, Ca2+, Cl- were significantly increasing during the 4 years. The comparisons of current CVs among different measurement systems showed that the precision performance of different analytes among different measurement systems had no regular distribution from 2014 to 2017. The analysis of IQC practice indicated great progress and improvement among different years. The imprecision performance of BGA has improved from 2014 to 2017, but the status of imprecision performance in China remains unsatisfying. Therefore, further investigation and continuous improvement measures should be taken.

In-situ study of the gas-phase composition and temperature of an intermediate-temperature solid oxide fuel cell anode surface fed by reformate natural gas

NASA Astrophysics Data System (ADS)

Santoni, F.; Silva Mosqueda, D. M.; Pumiglia, D.; Viceconti, E.; Conti, B.; Boigues Muñoz, C.; Bosio, B.; Ulgiati, S.; McPhail, S. J.

2017-12-01

An innovative experimental setup is used for in-depth and in-operando characterization of solid oxide fuel cell anodic processes. This work focuses on the heterogeneous reactions taking place on a 121 cm2 anode-supported cell (ASC) running with a H2, CH4, CO2, CO and steam gas mixture as a fuel, using an operating temperature of 923 K. The results have been obtained by analyzing the gas composition and temperature profiles along the anode surface in different conditions: open circuit voltage (OCV) and under two different current densities, 165 mA cm-2 and 330 mA cm-2, corresponding to 27% and 54% of fuel utilization, respectively. The gas composition and temperature analysis results are consistent, allowing to monitor the evolution of the principal chemical and electrochemical reactions along the anode surface. A possible competition between CO2 and H2O in methane internal reforming is shown under OCV condition and low current density values, leading to two different types of methane reforming: Steam Reforming and Dry Reforming. Under a current load of 40 A, the dominance of exothermic reactions leads to a more marked increase of temperature in the portion of the cell close to the inlet revealing that current density is not uniform along the anode surface.

Internal convective heat transfer to gases in the low-Reynolds-number “turbulent” range

DOE Office of Scientific and Technical Information (OSTI.GOV)

McEligot, Donald M.; Chu, Xu; Skifton, Richard S.

For internal vertical gas flow in tubes with strong heating rates at low turbulent Reynolds numbers, a typical experimental observation is that the local Nusselt number varies roughly as the square of the decreasing local Reynolds number. An aim of the present note is to examine this situation. This examination leads to the hypothesis that the behavior results from the evolution of the thermal boundary layer developing within the primarily molecular transport layer which is also growing from the wall. Comparisons to direct numerical simulations demonstrate that reasonable predictions are provided by an extension of the Leveque similarity analysis formore » laminar thermal boundary layers. Furthermore, the present observations modify and improve our fundamental understanding of the process called “relaminarization” in these flows.« less

Internal convective heat transfer to gases in the low-Reynolds-number “turbulent” range

DOE PAGES

McEligot, Donald M.; Chu, Xu; Skifton, Richard S.; ...

2018-03-07

For internal vertical gas flow in tubes with strong heating rates at low turbulent Reynolds numbers, a typical experimental observation is that the local Nusselt number varies roughly as the square of the decreasing local Reynolds number. An aim of the present note is to examine this situation. This examination leads to the hypothesis that the behavior results from the evolution of the thermal boundary layer developing within the primarily molecular transport layer which is also growing from the wall. Comparisons to direct numerical simulations demonstrate that reasonable predictions are provided by an extension of the Leveque similarity analysis formore » laminar thermal boundary layers. Furthermore, the present observations modify and improve our fundamental understanding of the process called “relaminarization” in these flows.« less

Strategies for restoration of deep-water coral ecosystems based on a global survey of oil and gas regulations

NASA Astrophysics Data System (ADS)

Cordes, E. E.; Jones, D.; Levin, L. A.

2016-02-01

The oil and gas industry is one of the most active agents of the global industrialization of the deep sea. The wide array of impacts following the Deepwater Horizon oil spill highlighted the need for a systematic review of existing regulations both in US waters and internationally. Within different exclusive economic zones, there are a wide variety of regulations regarding the survey of deep-water areas prior to leasing and the acceptable set-back distances from vulnerable marine ecosystems once they are discovered. There are also varying mitigation strategies for accidental release of oil and gas, including active monitoring systems, temporary closings of oil and gas production, and marine protected areas. The majority of these regulations are based on previous studies of typical impacts from oil and gas drilling, rather than accidental releases. However, the probability of an accident from standard operations increases significantly with depth. The Oil & Gas working group of the Deep Ocean Stewardship Initiative is an international partnership of scientists, managers, non-governmental organizations, and industry professionals whose goal is to review existing regulations for the oil & gas industry and produce a best practices document to advise both developed and developing nations on their regulatory structure as energy development moves into deeper waters.

Fuel development for gas-cooled fast reactors

NASA Astrophysics Data System (ADS)

Meyer, M. K.; Fielding, R.; Gan, J.

2007-09-01

The Generation IV Gas-cooled Fast Reactor (GFR) concept is proposed to combine the advantages of high-temperature gas-cooled reactors (such as efficient direct conversion with a gas turbine and the potential for application of high-temperature process heat), with the sustainability advantages that are possible with a fast-spectrum reactor. The latter include the ability to fission all transuranics and the potential for breeding. The GFR is part of a consistent set of gas-cooled reactors that includes a medium-term Pebble Bed Modular Reactor (PBMR)-like concept, or concepts based on the Gas Turbine Modular Helium Reactor (GT-MHR), and specialized concepts such as the Very High-Temperature Reactor (VHTR), as well as actinide burning concepts [A Technology Roadmap for Generation IV Nuclear Energy Systems, US DOE Nuclear Energy Research Advisory Committee and the Generation IV International Forum, December 2002]. To achieve the necessary high power density and the ability to retain fission gas at high temperature, the primary fuel concept proposed for testing in the United States is dispersion coated fuel particles in a ceramic matrix. Alternative fuel concepts considered in the US and internationally include coated particle beds, ceramic clad fuel pins, and novel ceramic 'honeycomb' structures. Both mixed carbide and mixed nitride-based solid solutions are considered as fuel phases.

Internal cooling circuit for gas turbine bucket

DOEpatents

Hyde, Susan Marie; Davis, Richard Mallory

2005-10-25

In a gas turbine bucket having a shank portion and an airfoil portion having leading and trailing edges and pressure and suction sides, an internal cooling circuit, the internal cooling circuit having a serpentine configuration including plural radial outflow passages and plural radial inflow passages, and wherein a coolant inlet passage communicates with a first of the radial outflow passages along the trailing edge, the first radial outflow passage having a plurality of radially extending and radially spaced elongated rib segments extending between and connecting the pressure and suction sides in a middle region of the first passage to prevent ballooning of the pressure and suction sides at the first radial outflow passage.

The Internal Energy for Molecular Hydrogen in Gravitationally Unstable Protoplanetary Disks

NASA Astrophysics Data System (ADS)

Boley, Aaron C.; Hartquist, Thomas W.; Durisen, Richard H.; Michael, Scott

2007-02-01

The gas equation of state may be one of the critical factors for the disk instability theory of gas giant planet formation. This Letter addresses the treatment of H2 in hydrodynamic simulations of gravitationally unstable disks. In our discussion, we point out possible consequences of erroneous specific internal energy relations, approximate specific internal energy relations with discontinuities, and assumptions of constant Γ1. In addition, we consider whether the ortho/para ratio for H 2 in protoplanetary disks should be treated dynamically as if the species are in equilibrium. Preliminary simulations indicate that the correct treatment is particularly critical for the study of gravitational instability when T=30-50 K.

Assessing drivers of export orientation in the subsea oil and gas industry.

PubMed

Aarstad, Jarle; Pettersen, Inger Beate; Jakobsen, Stig-Erik

2015-01-01

The purpose of this short study was to identify the drivers of export orientation of firms in the subsea oil and gas industry in Western Norway. As the oil fields in the North Sea are approaching a stage of maturity, gaining knowledge of these drivers is crucial. An online survey was conducted of firms operating in the subsea oil and gas industry in the region. Consistent with previous research, the data reveal that product innovation and a majority share of international ownership increase firms' export rates. The use of instrumental variables indicates that both product innovation and international ownership are causes of subsea petroleum exports. The study moreover finds that subcontractors have a lower rate of direct exports than system providers, but international ownership in particular boosts subcontractors' export rates, probably by decreasing their market dependency on regional system providers. A clear recommendation for managers and stakeholders is that they should encourage foreign investments throughout the value chain. The results of such a strategy appear to be especially positive for subcontractors.

JPRS Report, Soviet Union Economic Affairs

DTIC Science & Technology

1988-11-01

Shatlykgazstroy [ Shatlyk Gas Construction] Trust and a group of Romanian construc- tion workers. A creative camaraderie was established between the...international collectives, and competition developed for the fastest start-up of the facilities. The Shatlyk gas-construction workers are successfully

An Effective Continuum Model for the Gas Evolution in Internal Steam Drives

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tsimpanogiannis, Ioannis N.; Yortsos, Yanis C.

This report examines the gas phase growth from a supersaturated, slightly compressible, liquid in a porous medium, driven by heat transfer and controlled by the application of a constant-rate decline of the system pressure.

Well-to-wheels analysis of fast pyrolysis pathways with the GREET model.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Han, J.; Elgowainy, A.; Palou-Rivera, I.

The pyrolysis of biomass can help produce liquid transportation fuels with properties similar to those of petroleum gasoline and diesel fuel. Argonne National Laboratory conducted a life-cycle (i.e., well-to-wheels [WTW]) analysis of various pyrolysis pathways by expanding and employing the Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model. The WTW energy use and greenhouse gas (GHG) emissions from the pyrolysis pathways were compared with those from the baseline petroleum gasoline and diesel pathways. Various pyrolysis pathway scenarios with a wide variety of possible hydrogen sources, liquid fuel yields, and co-product application and treatment methods were considered. Atmore » one extreme, when hydrogen is produced from natural gas and when bio-char is used for process energy needs, the pyrolysis-based liquid fuel yield is high (32% of the dry mass of biomass input). The reductions in WTW fossil energy use and GHG emissions relative to those that occur when baseline petroleum fuels are used, however, is modest, at 50% and 51%, respectively, on a per unit of fuel energy basis. At the other extreme, when hydrogen is produced internally via reforming of pyrolysis oil and when bio-char is sequestered in soil applications, the pyrolysis-based liquid fuel yield is low (15% of the dry mass of biomass input), but the reductions in WTW fossil energy use and GHG emissions are large, at 79% and 96%, respectively, relative to those that occur when baseline petroleum fuels are used. The petroleum energy use in all scenarios was restricted to biomass collection and transportation activities, which resulted in a reduction in WTW petroleum energy use of 92-95% relative to that found when baseline petroleum fuels are used. Internal hydrogen production (i.e., via reforming of pyrolysis oil) significantly reduces fossil fuel use and GHG emissions because the hydrogen from fuel gas or pyrolysis oil (renewable sources) displaces that from fossil fuel natural gas and the amount of fossil natural gas used for hydrogen production is reduced; however, internal hydrogen production also reduces the potential petroleum energy savings (per unit of biomass input basis) because the fuel yield declines dramatically. Typically, a process that has a greater liquid fuel yield results in larger petroleum savings per unit of biomass input but a smaller reduction in life-cycle GHG emissions. Sequestration of the large amount of bio-char co-product (e.g., in soil applications) provides a significant carbon dioxide credit, while electricity generation from bio-char combustion provides a large energy credit. The WTW energy and GHG emissions benefits observed when a pyrolysis oil refinery was integrated with a pyrolysis reactor were small when compared with those that occur when pyrolysis oil is distributed to a distant refinery, since the activities associated with transporting the oil between the pyrolysis reactors and refineries have a smaller energy and emissions footprint than do other activities in the pyrolysis pathway.« less

BMP Report Of Survey Conducted At University Of New Orleans, LA Best Manufacturing Practices

DTIC Science & Technology

2003-01-01

external influences. Several differ- ent technologies have been used to combat this problem. Chromium , cop- per, lead, cadmium, and zinc metals are...SMAW) on AH36 and Stainless Steel • Gas Metal Arc Welding (GMAW) on Stain- less Steel • Gas Tungsten Arc Welding ( GTAW ) on Stainless Steel and...GCRMTC Gulf Coast Region Maritime Technology Center GMAW Gas Metal Arc Welding GTAW Gas Tungsten Arc Welding ISO International Standards Organization

33 CFR 145.10 - Locations and number of fire extinguishers required.

Code of Federal Regulations, 2011 CFR

2011-07-01

... vicinity of exits, either inside or outside of spaces. machinery spaces Gas-fired boilers B-II (CO2 or dry chemical) 2 required. Gas-fired boilers B-V 1 required. 1 Oil-fired boilers B-II 2 required. Oil-fired boilers B-V 2 required. 1 Internal combustion or gas turbine engines B-II 1 for each engine. 2 Electric...

33 CFR 145.10 - Locations and number of fire extinguishers required.

Code of Federal Regulations, 2012 CFR

2012-07-01

... vicinity of exits, either inside or outside of spaces. machinery spaces Gas-fired boilers B-II (CO2 or dry chemical) 2 required. Gas-fired boilers B-V 1 required. 1 Oil-fired boilers B-II 2 required. Oil-fired boilers B-V 2 required. 1 Internal combustion or gas turbine engines B-II 1 for each engine. 2 Electric...

33 CFR 145.10 - Locations and number of fire extinguishers required.

Code of Federal Regulations, 2013 CFR

2013-07-01

... vicinity of exits, either inside or outside of spaces. machinery spaces Gas-fired boilers B-II (CO2 or dry chemical) 2 required. Gas-fired boilers B-V 1 required. 1 Oil-fired boilers B-II 2 required. Oil-fired boilers B-V 2 required. 1 Internal combustion or gas turbine engines B-II 1 for each engine. 2 Electric...

33 CFR 145.10 - Locations and number of fire extinguishers required.

Code of Federal Regulations, 2014 CFR

2014-07-01

... vicinity of exits, either inside or outside of spaces. machinery spaces Gas-fired boilers B-II (CO2 or dry chemical) 2 required. Gas-fired boilers B-V 1 required. 1 Oil-fired boilers B-II 2 required. Oil-fired boilers B-V 2 required. 1 Internal combustion or gas turbine engines B-II 1 for each engine. 2 Electric...

33 CFR 145.10 - Locations and number of fire extinguishers required.

Code of Federal Regulations, 2010 CFR

2010-07-01

... vicinity of exits, either inside or outside of spaces. machinery spaces Gas-fired boilers B-II (CO2 or dry chemical) 2 required. Gas-fired boilers B-V 1 required. 1 Oil-fired boilers B-II 2 required. Oil-fired boilers B-V 2 required. 1 Internal combustion or gas turbine engines B-II 1 for each engine. 2 Electric...

40 CFR 60.4241 - What are my compliance requirements if I am a manufacturer of stationary SI internal combustion...

Code of Federal Regulations, 2014 CFR

2014-07-01

... meets the definition of pipeline-quality natural gas. The fuel used for certifying stationary SI natural... a gas chromatograph as allowed under 40 CFR 1065.267 and may measure ethane, as well as methane, for... stationary SI engines as certified or non-certified engines. (d) Manufacturers of natural gas fired...

40 CFR 60.4241 - What are my compliance requirements if I am a manufacturer of stationary SI internal combustion...

Code of Federal Regulations, 2013 CFR

2013-07-01

... meets the definition of pipeline-quality natural gas. The fuel used for certifying stationary SI natural... a gas chromatograph as allowed under 40 CFR 1065.267 and may measure ethane, as well as methane, for... stationary SI engines as certified or non-certified engines. (d) Manufacturers of natural gas fired...

76 FR 77583 - Vantage Pipeline US LP; Notice of Intent To Prepare an Environmental Assessment and Request for...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-13

... facilities of natural gas liquids to be located at the international border of the United States and Canada...) entitled ``An Interstate Natural Gas Facility On My Land? What Do I Need To Know?'' is available for your... Vantage Pipeline Project would serve the national interest by providing the natural gas, oil, and ethane...

MIS High-Purity Plutonium Oxide Metal Oxidation Product TS707001 (SSR123): Final Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Veirs, Douglas Kirk; Stroud, Mary Ann; Berg, John M.

A high-purity plutonium dioxide material from the Material Identification and Surveillance (MIS) Program inventory has been studied with regard to gas generation and corrosion in a storage environment. Sample TS707001 represents process plutonium oxides from several metal oxidation operations as well as impure and scrap plutonium from Hanford that are currently stored in 3013 containers. After calcination to 950°C, the material contained 86.98% plutonium with no major impurities. This study followed over time, the gas pressure of a sample with nominally 0.5 wt% water in a sealed container with an internal volume scaled to 1/500th of the volume of amore » 3013 container. Gas compositions were measured periodically over a six year period. The maximum observed gas pressure was 138 kPa. The increase over the initial pressure of 80 kPa was primarily due to generation of nitrogen and carbon dioxide gas in the first six months. Hydrogen and oxygen were minor components of the headspace gas. At the completion of the study, the internal components of the sealed container showed signs of corrosion, including pitting.« less

Evaluation test on a landfill gas-fired internal-combustion-engine system at the City of Glendale No. 1 Scholl Canyon Power Plant. Air pollution test report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1986-07-01

A cooperative test program was conducted from January 28 through January 31, 1986, by Air Resources Board (ARB) and South Coast Air Quality Management District (SCAQMD) staff to evaluate the gaseous constituents from untreated landfill gas used to fuel an internal combustion engine (ICE) and the emissions from that ICE located at the City of Glendale Scholl Canyon Power Plant. The ICE was fueled with gases generated by the anaerobic decomposition of buried refuse at the No. 1 Scholl Canyon Landfill operated by the City of Glendale, Public Service Department. The test was conducted as part of an ongoing programmore » by the SCAQMD to allow assessment of the inlet fuel gas (landfill gas) and exhaust gas characteristics from such devices as ICEs, gas turbines, and flares. Emissions of criteria pollutants as determined from test data are reported. Mass flow rates and destruction and removal efficiencies (DRE's) of non-criteria pollutants compounds determined from SCAQMD bag sample test data and mass flow rates and DRE's for chlorinated and aromatic compounds determined from data from ARB resin samples are presented.« less

Internal combustion engine with compressed air collection system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brown, P.W.

1988-08-23

This patent describes an internal combustion engine comprising cylinders respectively including a pressure port, pistons respectively movable in the cylinders through respective compression strokes, fuel injectors respectively connected to the cylinders and operative to supply, from a fuel source to the respective cylinders, a metered quantity of fuel conveyed by compressed gas in response to fuel injector operation during the compression strokes of the respective cylinders, a storage tank for accumulating and storing compressed gas, means for selectively connecting the pressure ports to the storage tank only during the compression strokes of the respective cylinders, and duct means connecting themore » storage tank to the fuel injectors for supplying the fuel injectors with compressed gas in response to fuel injector operation.« less

Capability of the Gas Analysis and Testing Laboratory at the NASA Johnson Space Center

NASA Technical Reports Server (NTRS)

Broerman, Craig; Jimenez, Javier; Sweterlitsch, Jeff

2012-01-01

The Gas Analysis and Testing Laboratory is an integral part of the testing performed at the NASA Johnson Space Center. The Gas Analysis and Testing Laboratory is a high performance laboratory providing real time analytical instruments to support manned and unmanned testing. The lab utilizes precision gas chromatographs, gas analyzers and spectrophotometers to support the technology development programs within the NASA community. The Gas Analysis and Testing Laboratory works with a wide variety of customers and provides engineering support for user-specified applications in compressed gas, chemical analysis, general and research laboratory.

Capability of the Gas Analysis and Testing Laboratory at the NASA Johnson Space Center

NASA Technical Reports Server (NTRS)

Broerman, Craig; Jimenez, Javier; Sweterlitsch, Jeff

2011-01-01

The Gas Analysis and Testing Laboratory is an integral part of the testing performed at the NASA Johnson Space Center. The Gas Analysis and Testing Laboratory is a high performance laboratory providing real time analytical instruments to support manned and unmanned testing. The lab utilizes precision gas chromatographs, gas analyzers and spectrophotometers to support the technology development programs within the NASA community. The Gas Analysis and Testing Laboratory works with a wide variety of customers and provides engineering support for user-specified applications in compressed gas, chemical analysis, general and research laboratory

Solar Wind Ablation of Terrestrial Planet Atmospheres

NASA Technical Reports Server (NTRS)

Moore, Thomas Earle; Fok, Mei-Ching H.; Delcourt, Dominique C.

2009-01-01

Internal plasma sources usually arise in planetary magnetospheres as a product of stellar ablation processes. With the ignition of a new star and the onset of its ultraviolet and stellar wind emissions, much of the volatiles in the stellar system undergo a phase transition from gas to plasma. Condensation and accretion into a disk is replaced by radiation and stellar wind ablation of volatile materials from the system- Planets or smaller bodies that harbor intrinsic magnetic fields develop an apparent shield against direct stellar wind impact, but UV radiation still ionizes their gas phases, and the resulting internal plasmas serve to conduct currents to and from the central body along reconnected magnetic field linkages. Photoionization and thermalization of electrons warms the ionospheric topside, enhancing Jeans' escape of super-thermal particles, with ambipolar diffusion and acceleration. Moreover, observations and simulations of auroral processes at Earth indicate that solar wind energy dissipation is concentrated by the geomagnetic field by a factor of 10-100, enhancing heavy species plasma and gas escape from gravity, and providing more current carrying capacity. Thus internal plasmas enable coupling with the plasma, neutral gas and by extension, the entire body. The stellar wind is locally loaded and slowed to develop the required power. The internal source plasma is accelerated and heated, inflating the magnetosphere as it seeks escape, and is ultimately blown away in the stellar wind. Bodies with little sensible atmosphere may still produce an exosphere of sputtered matter when exposed to direct solar wind impact. Bodies with a magnetosphere and internal sources of plasma interact more strongly with the stellar wind owing to the magnetic linkage between the two created by reconnection.

Large Eddy Simulation of a Supercritical Turbulent Mixing Layer

NASA Astrophysics Data System (ADS)

Sheikhi, Reza; Hadi, Fatemeh; Safari, Mehdi

2017-11-01

Supercritical turbulent flows are relevant to a wide range of applications such as supercritical power cycles, gas turbine combustors, rocket propulsion and internal combustion engines. Large eddy simulation (LES) analysis of such flows involves solving mass, momentum, energy and scalar transport equations with inclusion of generalized diffusion fluxes. These equations are combined with a real gas equation of state and the corresponding thermodynamic mixture variables. Subgrid scale models are needed for not only the conventional convective terms but also the additional high pressure effects arising due to the nonlinearity associated with generalized diffusion fluxes and real gas equation of state. In this study, LES is carried out to study the high pressure turbulent mixing of methane with carbon dioxide in a temporally developing mixing layer under supercritical condition. LES results are assessed by comparing with data obtained from direct numerical simulation (DNS) of the same layer. LES predictions agree favorably with DNS data and represent several key supercritical turbulent flow features such as high density gradient regions. Supported by DOE Grant SC0017097; computational support is provided by DOE National Energy Research Scientific Computing Center.

Versatile fluid-mixing device for cell and tissue microgravity research applications.

PubMed

Wilfinger, W W; Baker, C S; Kunze, E L; Phillips, A T; Hammerstedt, R H

1996-01-01

Microgravity life-science research requires hardware that can be easily adapted to a variety of experimental designs and working environments. The Biomodule is a patented, computer-controlled fluid-mixing device that can accommodate these diverse requirements. A typical shuttle payload contains eight Biomodules with a total of 64 samples, a sealed containment vessel, and a NASA refrigeration-incubation module. Each Biomodule contains eight gas-permeable Silastic T tubes that are partitioned into three fluid-filled compartments. The fluids can be mixed at any user-specified time. Multiple investigators and complex experimental designs can be easily accommodated with the hardware. During flight, the Biomodules are sealed in a vessel that provides two levels of containment (liquids and gas) and a stable, investigator-controlled experimental environment that includes regulated temperature, internal pressure, humidity, and gas composition. A cell microencapsulation methodology has also been developed to streamline launch-site sample manipulation and accelerate postflight analysis through the use of fluorescent-activated cell sorting. The Biomodule flight hardware and analytical cell encapsulation methodology are ideally suited for temporal, qualitative, or quantitative life-science investigations.

Gas-Induced Rectified Motion of a Solid Object in a Liquid-Filled Housing during Vibration: Analysis and Experiments

NASA Astrophysics Data System (ADS)

Torczynski, J. R.; O'Hern, T. J.; Clausen, J. R.; Koehler, T. P.

2017-11-01

The motion of a solid object (a piston) that fits closely within a housing filled with viscous liquid is studied. If a small amount of gas is introduced and the system is subjected to axial vibration, then the piston exhibits rectified motion when the drag on the piston depends on its position within the housing. An idealized system, in which the piston is suspended freely between two springs and the gas is replaced with two compressible bellows, is analyzed theoretically and studied experimentally. For a given vibration amplitude or frequency, the piston either remains near its original position (``up'') or moves to a different position (``down''), where its spring suspension is compressed. Analytical and experimental regime maps of the amplitudes and frequencies at which the piston is up or down are in good agreement. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology and Engineering Solutions of Sandia, LLC., a wholly owned subsidiary of Honeywell International, Inc., for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-NA0003525.

Multiple regression analysis in modelling of carbon dioxide emissions by energy consumption use in Malaysia

NASA Astrophysics Data System (ADS)

Keat, Sim Chong; Chun, Beh Boon; San, Lim Hwee; Jafri, Mohd Zubir Mat

2015-04-01

Climate change due to carbon dioxide (CO2) emissions is one of the most complex challenges threatening our planet. This issue considered as a great and international concern that primary attributed from different fossil fuels. In this paper, regression model is used for analyzing the causal relationship among CO2 emissions based on the energy consumption in Malaysia using time series data for the period of 1980-2010. The equations were developed using regression model based on the eight major sources that contribute to the CO2 emissions such as non energy, Liquefied Petroleum Gas (LPG), diesel, kerosene, refinery gas, Aviation Turbine Fuel (ATF) and Aviation Gasoline (AV Gas), fuel oil and motor petrol. The related data partly used for predict the regression model (1980-2000) and partly used for validate the regression model (2001-2010). The results of the prediction model with the measured data showed a high correlation coefficient (R2=0.9544), indicating the model's accuracy and efficiency. These results are accurate and can be used in early warning of the population to comply with air quality standards.

Gross alpha and beta activity analyses in urine-a routine laboratory method for internal human radioactivity detection.

PubMed

Chen, Xiaowen; Zhao, Luqian; Qin, Hongran; Zhao, Meijia; Zhou, Yirui; Yang, Shuqiang; Su, Xu; Xu, Xiaohua

2014-05-01

The aim of this work was to develop a method to provide rapid results for humans with internal radioactive contamination. The authors hypothesized that valuable information could be obtained from gas proportional counter techniques by screening urine samples from potentially exposed individuals rapidly. Recommended gross alpha and beta activity screening methods generally employ gas proportional counting techniques. Based on International Standards Organization (ISO) methods, improvements were made in the evaporation process to develop a method to provide rapid results, adequate sensitivity, and minimum sample preparation and operator intervention for humans with internal radioactive contamination. The method described by an American National Standards Institute publication was used to calibrate the gas proportional counter, and urine samples from patients with or without radionuclide treatment were measured to validate the method. By improving the evaporation process, the time required to perform the assay was reduced dramatically. Compared with the reference data, the results of the validation samples were very satisfactory with respect to gross-alpha and gross-beta activities. The gas flow proportional counting method described here has the potential for radioactivity monitoring in the body. This method was easy, efficient, and fast, and its application is of great utility in determining whether a sample should be analyzed by a more complicated method, for example radiochemical and/or γ-spectroscopy. In the future, it may be used commonly in medical examination and nuclear emergency treatment.Health Phys. 106(5):000-000; 2014.

High-Performance Ion Mobility Spectrometry Using Hourglass Electrodynamic Funnel And Internal Ion Funnel

DOEpatents

Smith, Richard D.; Tang, Keqi; Shvartsburg, Alexandre A.

2004-11-16

A method and apparatus enabling increased sensitivity in ion mobility spectrometry/mass spectrometry instruments which substantially reduces or eliminates the loss of ions in ion mobility spectrometer drift tubes utilizing an hourglass electrodynamic ion funnel at the entrance to the drift tube and/or an internal ion funnel at the exit of the drift tube. An hourglass electrodynamic funnel is formed of at least an entry element, a center element, and an exit element, wherein the aperture of the center element is smaller than the aperture of the entry element and the aperture of the exit elements. Ions generated in a relatively high pressure region by an ion source at the exterior of the hourglass electrodynamic funnel are transmitted to a relatively low pressure region at the entrance of the hourglass funnel through a conductance limiting orifice. Alternating and direct electrical potentials are applied to the elements of the hourglass electrodynamic funnel thereby drawing ions into and through the hourglass electrodynamic funnel thereby introducing relatively large quantities of ions into the drift tube while maintaining the gas pressure and composition at the interior of the drift tube as distinct from those at the entrance of the electrodynamic funnel and allowing a positive gas pressure to be maintained within the drift tube, if desired. An internal ion funnel is provided within the drift tube and is positioned at the exit of said drift tube. The advantage of the internal ion funnel is that ions that are dispersed away from the exit aperture within the drift tube, such as those that are typically lost in conventional drift tubes to any subsequent analysis or measurement, are instead directed through the exit of the drift tube, vastly increasing the amount of ions exiting the drift tube.

Space shuttle solid rocket booster water entry cavity collapse loads

NASA Technical Reports Server (NTRS)

Keefe, R. T.; Rawls, E. A.; Kross, D. A.

1982-01-01

Solid rocket booster cavity collapse flight measurements included external pressures on the motor case and aft skirt, internal motor case pressures, accelerometers located in the forward skirt, mid-body area, and aft skirt, as well as strain gages located on the skin of the motor case. This flight data yielded applied pressure longitudinal and circumferential distributions which compare well with model test predictions. The internal motor case ullage pressure, which is below atmospheric due to the rapid cooling of the hot internal gas, was more severe (lower) than anticipated due to the ullage gas being hotter than predicted. The structural dynamic response characteristics were as expected. Structural ring and wall damage are detailed and are considered to be attributable to the direct application of cavity collapse pressure combined with the structurally destabilizing, low internal motor case pressure.

46 CFR 169.234 - Integral fuel oil tank examinations.

Code of Federal Regulations, 2010 CFR

2010-10-01

... operator of the vessel shall have the tanks cleaned out and gas freed as necessary to permit internal... an examination of the fuel tanks of each vessel during an internal structural examination at... and internally examined if the marine inspector is able to determine by external examination that the...

Glenn-HT: The NASA Glenn Research Center General Multi-Block Navier-Stokes Heat Transfer Code

NASA Technical Reports Server (NTRS)

Gaugler, Raymond E.; Lee, Chi-Miag (Technical Monitor)

2001-01-01

For the last several years, Glenn-HT, a three-dimensional (3D) Computational Fluid Dynamics (CFD) computer code for the analysis of gas turbine flow and convective heat transfer has been evolving at the NASA Glenn Research Center. The code is unique in the ability to give a highly detailed representation of the flow field very close to solid surfaces in order to get accurate representation of fluid heat transfer and viscous shear stresses. The code has been validated and used extensively for both internal cooling passage flow and for hot gas path flows, including detailed film cooling calculations and complex tip clearance gap flow and heat transfer. In its current form, this code has a multiblock grid capability and has been validated for a number of turbine configurations. The code has been developed and used primarily as a research tool, but it can be useful for detailed design analysis. In this paper, the code is described and examples of its validation and use for complex flow calculations are presented, emphasizing the applicability to turbomachinery for space launch vehicle propulsion systems.

Glenn-HT: The NASA Glenn Research Center General Multi-Block Navier-Stokes Heat Transfer Code

NASA Technical Reports Server (NTRS)

Gaugfer, Raymond E.

2002-01-01

For the last several years, Glenn-HT, a three-dimensional (3D) Computational Fluid Dynamics (CFD) computer code for the analysis of gas turbine flow and convective heat transfer has been evolving at the NASA Glenn Research Center. The code is unique in the ability to give a highly detailed representation of the flow field very close to solid surfaces in order to get accurate representation of fluid heat transfer and viscous shear stresses. The code has been validated and used extensively for both internal cooling passage flow and for hot gas path flows, including detailed film cooling calculations and complex tip clearance gap flow and heat transfer. In its current form, this code has a multiblock grid capability and has been validated for a number of turbine configurations. The code has been developed and used primarily as a research tool, but it can be useful for detailed design analysis. In this presentation, the code is described and examples of its validation and use for complex flow calculations are presented, emphasizing the applicability to turbomachinery.

Glenn-HT: The NASA Glenn Research Center General Multi-Block Navier Stokes Heat Transfer Code

NASA Technical Reports Server (NTRS)

Gaugler, Raymond E.

2002-01-01

For the last several years, Glenn-HT, a three-dimensional (3D) Computational Fluid Dynamics (CFD) computer code for the analysis of gas turbine flow and convective heat transfer has been evolving at the NASA Glenn Research Center. The code is unique in the ability to give a highly detailed representation of the flow field very close to solid surfaces in order to get accurate representation of fluid beat transfer and viscous shear stresses. The code has been validated and used extensively for both internal cooling passage flow and for hot gas path flows, including detailed film cooling calculations and complex tip clearance gap flow and heat transfer. In its current form, this code has a multiblock grid capability and has been validated for a number of turbine configurations. The code has been developed and used primarily as a research tool, but it can be useful for detailed design analysis. In this presentation, the code is described and examples of its validation and use for complex flow calculations are presented, emphasizing the applicability to turbomachinery.

The true cost of greenhouse gas emissions: analysis of 1,000 global companies.

PubMed

Ishinabe, Nagisa; Fujii, Hidemichi; Managi, Shunsuke

2013-01-01

This study elucidated the shadow price of greenhouse gas (GHG) emissions for 1,024 international companies worldwide that were surveyed from 15 industries in 37 major countries. Our results indicate that the shadow price of GHG at the firm level is much higher than indicated in previous studies. The higher shadow price was found in this study as a result of the use of Scope 3 GHG emissions data. The results of this research indicate that a firm would carry a high cost of GHG emissions if Scope 3 GHG emissions were the focus of the discussion of corporate social responsibility. In addition, such shadow prices were determined to differ substantially among countries, among sectors, and within sectors. Although a number of studies have calculated the shadow price of GHG emissions, these studies have employed country-level or industry-level data or a small sample of firm-level data in one country. This new data from a worldwide firm analysis of the shadow price of GHG emissions can play an important role in developing climate policy and promoting sustainable development.

The True Cost of Greenhouse Gas Emissions: Analysis of 1,000 Global Companies

PubMed Central

Ishinabe, Nagisa; Fujii, Hidemichi; Managi, Shunsuke

2013-01-01

This study elucidated the shadow price of greenhouse gas (GHG) emissions for 1,024 international companies worldwide that were surveyed from 15 industries in 37 major countries. Our results indicate that the shadow price of GHG at the firm level is much higher than indicated in previous studies. The higher shadow price was found in this study as a result of the use of Scope 3 GHG emissions data. The results of this research indicate that a firm would carry a high cost of GHG emissions if Scope 3 GHG emissions were the focus of the discussion of corporate social responsibility. In addition, such shadow prices were determined to differ substantially among countries, among sectors, and within sectors. Although a number of studies have calculated the shadow price of GHG emissions, these studies have employed country-level or industry-level data or a small sample of firm-level data in one country. This new data from a worldwide firm analysis of the shadow price of GHG emissions can play an important role in developing climate policy and promoting sustainable development. PMID:24265710

The energetics of hydrogen atom recombination - Analysis, experiments, and modeling. [in electrothermal propulsion system

NASA Technical Reports Server (NTRS)

Filpus, J. W.; Hawley, M. C.

1984-01-01

A theoretical investigation of the effect of the microscopic energetics of the recombination reaction on the performance of a microwave-plasma electrothermal propulsion system is described, and the results of the analysis are presented. A series of experiments to test the concept is described and analyzed by comparison with a computer model of the recombination reaction. It is concluded that internal energy considerations are not likely to significantly affect the design of a microwave-plasma electrothermal rocket. The experimental results indicate that the microwave power is far higher than the capacity of the gas to absorb it; the cooling needed to control the energy dominates the experimental results.

Association between wood cooking fuel and maternal hypertension at delivery in central East India.

PubMed

Wylie, Blair J; Singh, Mrigendra P; Coull, Brent A; Quinn, Ashlinn; Yeboah-Antwi, Kojo; Sabin, Lora; Hamer, Davidson H; Singh, Neeru; MacLeod, William B

2015-01-01

Smoke from burning of biomass fuels has been linked with adverse pregnancy outcomes and hypertension among nonpregnant subjects; association with hypertension during pregnancy has not been well studied. We evaluated whether the use of wood cooking fuel increases the risk of maternal hypertension at delivery compared to gas which burns with less smoke. Information on fuel use and blood pressure was available for analysis from a cross-sectional survey of 1369 pregnant women recruited at delivery in India. Compared to gas users, women using wood as fuel had on average lower mean arterial pressure (adjusted effect size - 2.0 mmHg; 95% CI: -3.77, -0.31) and diastolic blood pressure (adjusted effect size -1.96 mmHg; 95% CI: -3.60, -0.30) at delivery. Risk of hypertension (systolic >139 mmHg or diastolic >89 mmHg) was 14.6% for wood users compared to 19.6% for gas users although this did not reach significance after adjustment, using propensity score techniques, for factors that make wood and gas users distinct (adjusted prevalence ratio 0.76; 95% CI: 0.49, 1.17). Combustion products from the burning of biomass fuels are similar to those released with tobacco smoking, which has been linked with a reduced risk for preeclampsia. The direction of our findings suggests the possibility of a similar effect for biomass cook smoke. Whether clean cooking interventions being promoted by international advocacy organizations will impact hypertension in pregnancy warrants further analysis as hypertension remains a leading cause of maternal death worldwide and cooking with biomass fuels is widespread.

FUEL CELL ENERGY RECOVERY FROM LANDFILL GAS

EPA Science Inventory

International Fuel Cells Corporation is conducting a US Environmental Protection Agency (EPA) sponsored program to demonstrate energy recovery from landfill gas using a commercial phosphoric acid fuel cell power plant. The US EPA is interested in fuel cells for this application b...

Clean air program : liquefied natural gas safety in transit operations

DOT National Transportation Integrated Search

1996-03-31

The report examines the safety issues relating to the use of Liquefied Natural Gas (LNG) in transit service. The safety issues were determined by on-site surveys performed by Battelle of Columbus, Ohio, and Science Applications International Corp. (S...

30 CFR 7.97 - Application requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... internal parts, exhaust inlet and outlet, sensors, and the exhaust gas path through the exhaust conditioner... temperature sensor setting and exhaust gas temperature sensor setting used to meet the performance... sensors, flame arresters, exhaust conditioner, emergency intake air shutoff device, automatic fuel shutoff...

30 CFR 7.97 - Application requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... internal parts, exhaust inlet and outlet, sensors, and the exhaust gas path through the exhaust conditioner... temperature sensor setting and exhaust gas temperature sensor setting used to meet the performance... sensors, flame arresters, exhaust conditioner, emergency intake air shutoff device, automatic fuel shutoff...

Cryosurgery in Cancer Treatment: Questions and Answers

MedlinePlus

... is the use of extreme cold produced by liquid nitrogen (or argon gas) to destroy abnormal tissue . Cryosurgery is used to ... and tumors in the bone). For internal tumors, liquid nitrogen or argon gas is circulated through a hollow instrument called a ...

Evaluation of a Fluidized-Bed Paint Stripper at Red River Army Depot

DTIC Science & Technology

1992-04-15

are summarized in Table 3-1. Calibra- tion guidelines are described in more detail in Appendix E. 0 Onsite audits of dry gas meters, thermocouples...experienced laboratory per- sonnel. o Internal and external audits to ensure accuracy in sampling and analysis. o Reagent, filter, and field blanks to...0.0 0.0 If below detection limits, replace 0 with 1. 0 0 0 ?Mn < polutant > mam mg 0.0 0.0 0.0 Co cpoliuLant> concentration gr/dscf 0.000E*00 0.000E.00

Determination of ethylene oxide, ethylene chlorohydrin, and ethylene glycol in aqueous solutions and ethylene oxide residues in associated plastics.

PubMed

Ball, N A

1984-09-01

A gas chromatographic (GC) method was developed for the determination of ethylene oxide and its two reaction products, ethylene chlorohydrin and ethylene glycol, in aqueous ophthalmic solutions. Propylene oxide was used as an internal standard. All three components were determined in one isothermal chromatographic analysis in less than 15 min. An extraction method for the determination of ethylene oxide residues in plastic components was also developed, and certain plastics with different ethylene oxide retention characteristics were identified.

Apparatus and method to inject a reductant into an exhaust gas feedstream

DOEpatents

Viola, Michael B [Macomb Township, MI

2009-09-22

An exhaust aftertreatment system for an internal combustion engine is provided including an apparatus and method to inject a reductant into the exhaust gas feedstream. Included is a fuel metering device adapted to inject reductant into the exhaust gas feedstream and a controllable pressure regulating device. A control module is operatively connected to the reductant metering device and the controllable pressure regulating device, and, adapted to effect flow of reductant into the exhaust gas feedstream over a controllable flow range.

21ST International Symposium on Rarefied Gas Dynamics, Marseille (France) 26-31 July 1998. Book of Abstracts, Volume I: Oral Sessions.

DTIC Science & Technology

1998-07-30

properties of gases, there are some major ite Gases, Academic Press, New York (1969). defects common to gas kinetic treatments. In hy- (1988). drodynamic...the incondensable gas are Recently, serious defects in classical gasdynamics comparable. in describing the behavior of a gas in the contin- We use the...Transition of Hypersonic, Chemically Reacting Boundary Layers J. Perraud, D. Arnal, F. Thivet ONERA CERT, DMAE , Toulouse, France 1 Introduction of

49 CFR 193.2631 - Internal corrosion control.

Code of Federal Regulations, 2010 CFR

2010-10-01

....2631 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE SAFETY LIQUEFIED NATURAL GAS FACILITIES: FEDERAL SAFETY STANDARDS Maintenance § 193.2631 Internal corrosion control. Each...

Discussion of Carbon Emissions for Charging Hot Metal in EAF Steelmaking Process

NASA Astrophysics Data System (ADS)

Yang, Ling-zhi; Jiang, Tao; Li, Guang-hui; Guo, Yu-feng

2017-07-01

As the cost of hot metal is reduced for iron ore prices are falling in the international market, more and more electric arc furnace (EAF) steelmaking enterprises use partial hot metal instead of scrap as raw materials to reduce costs and the power consumption. In this paper, carbon emissions based on 1,000 kg molten steel by charging hot metal in EAF steelmaking is studied. Based on the analysis of material and energy balance calculation in EAF, the results show that 146.9, 142.2, 137.0, and 130.8 kg/t of carbon emissions are produced at a hot metal ratio of 0 %, 30 %, 50 %, and 70 %, while 143.4, 98.5, 65.81, and 31.5 kg/t of carbon emissions are produced at a hot metal ratio of 0 %, 30 %, 50 %, and 70 % by using gas waste heat utilization (coal gas production) for EAF steelmaking unit process. However, carbon emissions are increased by charging hot metal for the whole blast furnace-electric arc furnace (BF-EAF) steelmaking process. In the condition that the hot metal produced by BF is surplus, as carbon monoxide in gas increased by charging hot metal, the way of coal gas production can be used for waste heat utilization, which reduces carbon emissions in EAF steelmaking unit process.

Advanced gasifier and water gas shift technologies for low cost coal conversion to high hydrogen syngas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kramer, Andrew Kramer

The Gas Technology Institute (GTI) and team members RTI International (RTI), Coanda Research and Development, and Nexant, are developing and maturing a portfolio of technologies to meet the United States Department of Energy (DOE) goals for lowering the cost of producing high hydrogen syngas from coal for use in carbon capture power and coal-to-liquids/chemicals. This project matured an advanced pilot-scale gasifier, with scalable and commercially traceable components, to readiness for use in a first-of-a-kind commercially-relevant demonstration plant on the scale of 500-1,000 tons per day (TPD). This was accomplished through cold flow simulation of the gasifier quench zone transition regionmore » at Coanda and through an extensive hotfire gasifier test program on highly reactive coal and high ash/high ash fusion temperature coals at GTI. RTI matured an advanced water gas shift process and catalyst to readiness for testing at pilot plant scale through catalyst development and testing, and development of a preliminary design basis for a pilot scale reactor demonstrating the catalyst. A techno-economic analysis was performed by Nexant to assess the potential benefits of the gasifier and catalyst technologies in the context of power production and methanol production. This analysis showed an 18%reduction in cost of power and a 19%reduction in cost of methanol relative to DOE reference baseline cases.« less

Vision for an Open, Global Greenhouse Gas Information System (GHGIS)

NASA Astrophysics Data System (ADS)

Duren, R. M.; Butler, J. H.; Rotman, D.; Ciais, P.; Greenhouse Gas Information System Team

2010-12-01

Over the next few years, an increasing number of entities ranging from international, national, and regional governments, to businesses and private land-owners, are likely to become more involved in efforts to limit atmospheric concentrations of greenhouse gases. In such a world, geospatially resolved information about the location, amount, and rate of greenhouse gas (GHG) emissions will be needed, as well as the stocks and flows of all forms of carbon through the earth system. The ability to implement policies that limit GHG concentrations would be enhanced by a global, open, and transparent greenhouse gas information system (GHGIS). An operational and scientifically robust GHGIS would combine ground-based and space-based observations, carbon-cycle modeling, GHG inventories, synthesis analysis, and an extensive data integration and distribution system, to provide information about anthropogenic and natural sources, sinks, and fluxes of greenhouse gases at temporal and spatial scales relevant to decision making. The GHGIS effort was initiated in 2008 as a grassroots inter-agency collaboration intended to identify the needs for such a system, assess the capabilities of current assets, and suggest priorities for future research and development. We will present a vision for an open, global GHGIS including latest analysis of system requirements, critical gaps, and relationship to related efforts at various agencies, the Group on Earth Observations, and the Intergovernmental Panel on Climate Change.

A comparative analysis of well-to-wheel primary energy demand and greenhouse gas emissions for the operation of alternative and conventional vehicles in Switzerland, considering various energy carrier production pathways

NASA Astrophysics Data System (ADS)

Yazdanie, Mashael; Noembrini, Fabrizio; Dossetto, Lionel; Boulouchos, Konstantinos

2014-03-01

This study provides a comprehensive analysis of well-to-wheel (WTW) primary energy demand and greenhouse gas (GHG) emissions for the operation of conventional and alternative passenger vehicle drivetrains. Results are determined based on a reference vehicle, drivetrain/production process efficiencies, and lifecycle inventory data specific to Switzerland. WTW performance is compared to a gasoline internal combustion engine vehicle (ICEV). Both industrialized and novel hydrogen and electricity production pathways are evaluated. A strong case is presented for pluggable electric vehicles (PEVs) due to their high drivetrain efficiency. However, WTW performance strongly depends on the electricity source. A critical electricity mix can be identified which divides optimal drivetrain performance between the EV, ICEV, and plug-in hybrid vehicle. Alternative drivetrain and energy carrier production pathways are also compared by natural resource. Fuel cell vehicle (FCV) performance proves to be on par with PEVs for energy carrier (EC) production via biomass and natural gas resources. However, PEVs outperform FCVs via solar energy EC production pathways. ICE drivetrains using alternative fuels, particularly biogas and CNG, yield remarkable WTW energy and emission reductions as well, indicating that alternative fuels, and not only alternative drivetrains, play an important role in the transition towards low-emission vehicles in Switzerland.

Towards a Global Greenhouse Gas Information System (GHGIS)

NASA Astrophysics Data System (ADS)

Duren, Riley; Butler, James; Rotman, Doug; Miller, Charles; Decola, Phil; Sheffner, Edwin; Tucker, Compton; Mitchiner, John; Jonietz, Karl; Dimotakis, Paul

2010-05-01

Over the next few years, an increasing number of entities ranging from international, national, and regional governments, to businesses and private land-owners, are likely to become more involved in efforts to limit atmospheric concentrations of greenhouse gases. In such a world, geospatially resolved information about the location, amount, and rate of greenhouse gas (GHG) emissions will be needed, as well as the stocks and flows of all forms of carbon through terrestrial ecosystems and in the oceans. The ability to implement policies that limit GHG concentrations would be enhanced by a global, open, and transparent greenhouse gas information system (GHGIS). An operational and scientifically robust GHGIS would combine ground-based and space-based observations, carbon-cycle modeling, GHG inventories, meta-analysis, and an extensive data integration and distribution system, to provide information about sources, sinks, and fluxes of greenhouse gases at policy-relevant temporal and spatial scales. The GHGIS effort was initiated in 2008 as a grassroots inter-agency collaboration intended to rigorously identify the needs for such a system, assess the capabilities of current assets, and suggest priorities for future research and development. We will present a status of the GHGIS effort including our latest analysis and ideas for potential near-term pilot projects with potential relevance to European initiatives including the Global Monitoring for Environment and Security (GMES) and the Integrated Carbon Observing System (ICOS).

Probing Cosmic Gas Accretion with RESOLVE and ECO

NASA Astrophysics Data System (ADS)

Kannappan, Sheila; Eckert, Kathleen D.; Stark, David; Lagos, Claudia; Nasipak, Zachary; Moffett, Amanda J.; Baker, Ashley; Berlind, Andreas A.; Hoversten, Erik A.; Norris, Mark A.; RESOLVE Team

2016-01-01

We review results bearing on the existence, controlling factors, and mechanisms of cosmic gas accretion in the RESOLVE and ECO surveys. Volume-limited analysis of RESOLVE's complete census of HI-to-stellar mass ratios and star formation histories for ~1500 galaxies points to the necessity of an "open box" model of galaxy fueling, with the most gas-dominated galaxies doubling their stellar masses on ~Gyr timescales in a regime of rapid accretion. Transitions in gas richness and disk-building activity for isolated or central galaxies with halo masses near ~10^11.5 Msun and ~10^12 Msun plausibly correspond to the endpoints of a theoretically predicted transition in halo gas temperature that slows accretion across this range. The same mass range is associated with the initial grouping of isolated galaxies into common halos, where "isolated" is defined relative to the survey baryonic mass limits of >~10^9 Msun. Above 10^11.5 Msun, patterns in central vs. satellite gas richness as a function of group halo mass suggest that galaxy refueling is valved off from the inside out as the halo grows, with total quenching beyond the virial radius for halo masses >~10^13-13.5 Msun. Within the transition range from ~10^11.5-10^12 Msun, theoretical models predict >3 dex dispersion in ratios of uncooled halo gas to cold gas in galaxies (or more generally gas and stars). In RESOLVE and ECO, the baryonic mass function of galaxies in this transitional halo mass range displays signs of stripping or destruction of satellites, leading us to investigate a possible connection with halo gas heating using central galaxy color and group dynamics to probe group evolutionary state. Finally, we take a first look at how internal variations in metallicity, dynamics, and star formation constrain accretion mechanisms such as cold streams, induced extraplanar gas cooling, isotropic halo gas cooling, and gas-rich merging in different mass and environment regimes. The RESOLVE and ECO surveys have been supported by funding from NSF grants AST-0955368 and OCI-1156614.

APPARATUS FOR SHEATHING RODS

DOEpatents

Ford, W.K.; Wyatt, M.; Plail, S.

1961-08-01

An arrangement is described for sealing a solid body of nuclear fuel, such as a uranium metal rod, into a closelyfitting thin metallic sheath with an internal atmosphere of inert gas. The sheathing process consists of subjecting the sheath, loaded with the nuclear fuel body, to the sequential operations of evacuation, gas-filling, drawing (to entrap inert gas and secure close contact between sheath and body), and sealing. (AEC)

26 CFR 1.263(c)-1 - Intangible drilling and development costs in the case of oil and gas wells.

Code of Federal Regulations, 2010 CFR

2010-04-01

... Intangible drilling and development costs in the case of oil and gas wells. For rules relating to the option to deduct as expenses intangible drilling and development costs in the case of oil and gas wells, see... 26 Internal Revenue 3 2010-04-01 2010-04-01 false Intangible drilling and development costs in the...

CFD analysis of a solid oxide fuel cell with internal reforming: Coupled interactions of transport, heterogeneous catalysis and electrochemical processes

NASA Astrophysics Data System (ADS)

Janardhanan, Vinod M.; Deutschmann, Olaf

Direct internal reforming in solid oxide fuel cell (SOFC) results in increased overall efficiency of the system. Present study focus on the chemical and electrochemical process in an internally reforming anode supported SOFC button cell running on humidified CH 4 (3% H 2 O). The computational approach employs a detailed multi-step model for heterogeneous chemistry in the anode, modified Butler-Volmer formalism for the electrochemistry and Dusty Gas Model (DGM) for the porous media transport. Two-dimensional elliptic model equations are solved for a button cell configuration. The electrochemical model assumes hydrogen as the only electrochemically active species. The predicted cell performances are compared with experimental reports. The results show that model predictions are in good agreement with experimental observation except the open circuit potentials. Furthermore, the steam content in the anode feed stream is found to have remarkable effect on the resulting overpotential losses and surface coverages of various species at the three-phase boundary.

A rapid analysis of plasma/serum ethylene and propylene glycol by headspace gas chromatography.

PubMed

Ehlers, Alexandra; Morris, Cory; Krasowski, Matthew D

2013-12-01

A rapid headspace-gas chromatography (HS-GC) method was developed for the analysis of ethylene glycol and propylene glycol in plasma and serum specimens using 1,3-propanediol as the internal standard. The method employed a single-step derivitization using phenylboronic acid, was linear to 200 mg/dL and had a lower limit of quantitation of 1 mg/dL suitable for clinical analyses. The analytical method described allows for laboratories with HS-GC instrumentation to analyze ethanol, methanol, isopropanol, ethylene glycol, and propylene glycol on a single instrument with rapid switch-over from alcohols to glycols analysis. In addition to the novel HS-GC method, a retrospective analysis of patient specimens containing ethylene glycol and propylene glycol was also described. A total of 36 patients ingested ethylene glycol, including 3 patients who presented with two separate admissions for ethylene glycol toxicity. Laboratory studies on presentation to hospital for these patients showed both osmolal and anion gap in 13 patients, osmolal but not anion gap in 13 patients, anion but not osmolal gap in 8 patients, and 1 patient with neither an osmolal nor anion gap. Acidosis on arterial blood gas was present in 13 cases. Only one fatality was seen; this was a patient with initial serum ethylene glycol concentration of 1282 mg/dL who died on third day of hospitalization. Propylene glycol was common in patients being managed for toxic ingestions, and was often attributed to iatrogenic administration of propylene glycol-containing medications such as activated charcoal and intravenous lorazepam. In six patients, propylene glycol contributed to an abnormally high osmolal gap. The common presence of propylene glycol in hospitalized patients emphasizes the importance of being able to identify both ethylene glycol and propylene glycol by chromatographic methods.

Controls for maintaining low nitrogen oxides content in internal combustion engine exhaust gases

DOE Office of Scientific and Technical Information (OSTI.GOV)

Siebke, H.; Moro, B.; Schoenborn, M.

1976-08-10

A control system and apparatus for measuring and monitoring the nitrogen oxides content of internal combustion engine exhaust gases is described. The exhaust gases are contacted with the reducing electrode of a sensor cell having a predetermined potential established between the cell electrodes so that the reducing electrode is able to reduce both the nitrogen oxides and oxygen content of the exhaust gas. The current flowing through the sensor cell is measured to determine whether the nitrogen oxides content of the exhaust gas is sufficiently low.

LANDFILL GAS PRETREATMENT FOR FUEL CELL APPLICATIONS

EPA Science Inventory

The paper discusses the U.S. EPA's program, underway at International Fuel Cells Corporation, to demonstrate landfill methane control and the fuel cell energy recovery concept. In this program, two critical issues are being addressed: (1) a landfill gas cleanup method that would ...

Trimethylsulfonium hydroxide as derivatization reagent for the chemical investigation of drying oils in works of art by gas chromatography.

PubMed

Dron, Julien; Linke, Robert; Rosenberg, Erwin; Schreiner, Manfred

2004-08-20

A procedure for the determination of fatty acids (FA) and glycerol in oils has been developed. The method includes a derivatization step of the FAs into their methyl esters or a transesterification of the triacylglycerols with trimethylsulfonium hydroxide (TMSH), respectively. The analysis is carried out by gas chromatography with parallel flame ionization and mass spectrometric detection. The parameters involved in the transesterification reaction were optimized. Only the stoichiometric ratio of TMSH:total FA amount showed a significant influence on the reaction yield. Relative standard deviations for 10 replicates were below 3% for all FAs studied and their linearity range was 0.5-50 mmol/L, when using heptadecanoic acid as an internal standard. The final procedure was rapid and required little sample handling. It was then tested on fresh oil samples and presented satisfying results, in agreement with previous works.

Pressure oscillations and instability of working processes in the combustion chambers of solid rocket motors

NASA Astrophysics Data System (ADS)

Emelyanov, V. N.; Teterina, I. V.; Volkov, K. N.; Garkushev, A. U.

2017-06-01

Metal particles are widely used in space engineering to increase specific impulse and to supress acoustic instability of intra-champber processes. A numerical analysis of the internal injection-driven turbulent gas-particle flows is performed to improve the current understanding and modeling capabilities of the complex flow characteristics in the combustion chambers of solid rocket motors (SRMs) in presence of forced pressure oscillations. The two-phase flow is simulated with a combined Eulerian-Lagrangian approach. The Reynolds-averaged Navier-Stokes equations and transport equations of k - ε model are solved numerically for the gas. The particulate phase is simulated through a Lagrangian deterministic and stochastic tracking models to provide particle trajectories and particle concentration. The results obtained highlight the crucial significance of the particle dispersion in turbulent flowfield and high potential of statistical methods. Strong coupling between acoustic oscillations, vortical motion, turbulent fluctuations and particle dynamics is observed.

Determination and discrimination of biodiesel fuels by gas chromatographic and chemometric methods

NASA Astrophysics Data System (ADS)

Milina, R.; Mustafa, Z.; Bojilov, D.; Dagnon, S.; Moskovkina, M.

2016-03-01

Pattern recognition method (PRM) was applied to gas chromatographic (GC) data for a fatty acid methyl esters (FAME) composition of commercial and laboratory synthesized biodiesel fuels from vegetable oils including sunflower, rapeseed, corn and palm oils. Two GC quantitative methods to calculate individual fames were compared: Area % and internal standard. The both methods were applied for analysis of two certified reference materials. The statistical processing of the obtained results demonstrates the accuracy and precision of the two methods and allows them to be compared. For further chemometric investigations of biodiesel fuels by their FAME-profiles any of those methods can be used. PRM results of FAME profiles of samples from different vegetable oils show a successful recognition of biodiesels according to the feedstock. The information obtained can be used for selection of feedstock to produce biodiesels with certain properties, for assessing their interchangeability, for fuel spillage and remedial actions in the environment.

Use of headspace sorptive extraction coupled to gas chromatography-mass spectrometry for the analysis of volatile polycyclic aromatic hydrocarbons in herbal infusions.

PubMed

Cacho, J I; Campillo, N; Viñas, P; Hernández-Córdoba, M

2014-08-22

A solvent-free method is described for the determination of 10 volatile polycyclic aromatic hydrocarbons (PAHs), considered as priority pollutants by the EU, in different herbal infusions using headspace sorptive extraction (HSSE) and gas chromatography-mass spectrometry (GC-MS). The parameters affecting both the extraction and thermal desorption steps in the HSSE were optimized by means of Plackett-Burman designs. Ten millilitres of the herbal infusion was submitted to the HSSE preconcentration in the presence of salt for 4h at 88 °C. The use of d(10)-phenanthrene as internal standard not only improved the repeatability of the method but allowed quantification of the samples against external aqueous standards. Detection limits ranged between 11 and 26 ng L(-1). Copyright © 2014 Elsevier B.V. All rights reserved.

Greenhouse Gas Inventory of a Typical High-End Industrial Park in China

PubMed Central

Chen, Bin; He, Guoxuan; Qi, Jing; Zhou, Shiyi; Jiang, Meiming

2013-01-01

Global climate change caused by greenhouse gas (GHG) emissions, which severely limits the development of human society and threatens the survival of humanity, has drawn the international community's long-term attention. Gathering the most important production factors in the region, an industrial park usually represents the development level of specific industries in the region. Therefore, the industrial park should be regarded as the base unit for developing a low-carbon economy and reducing GHG emissions. Focusing on a typical high-end industrial park in Beijing, we analyze the carbon sources within the system boundary and probe into the emission structure in view of life-cycle analysis. A GHG inventory is thereby set up to calculate all GHG emissions from the concerned park. Based on the results, suggestions are presented to guide the low-carbon development of the high-end industrial park. PMID:23431258

Greenhouse gas inventory of a typical high-end industrial park in China.

PubMed

Chen, Bin; He, Guoxuan; Qi, Jing; Su, Meirong; Zhou, Shiyi; Jiang, Meiming

2013-01-01

Global climate change caused by greenhouse gas (GHG) emissions, which severely limits the development of human society and threatens the survival of humanity, has drawn the international community's long-term attention. Gathering the most important production factors in the region, an industrial park usually represents the development level of specific industries in the region. Therefore, the industrial park should be regarded as the base unit for developing a low-carbon economy and reducing GHG emissions. Focusing on a typical high-end industrial park in Beijing, we analyze the carbon sources within the system boundary and probe into the emission structure in view of life-cycle analysis. A GHG inventory is thereby set up to calculate all GHG emissions from the concerned park. Based on the results, suggestions are presented to guide the low-carbon development of the high-end industrial park.

Degradation of trichloroethylene by photocatalysis in an internally circulating slurry bubble column reactor.

PubMed

Jeon, Jin Hee; Kim, Sang Done; Lim, Tak Hyoung; Lee, Dong Hyun

2005-08-01

The effects of initial trichloroethylene (TCE) concentration, recirculating liquid flow rate and gas velocity on photodegradation of TCE have been determined in an internally circulating slurry bubble column reactor (0.15m-ID x 0.85 m-high). Titanium dioxide (TiO2) powder was employed as a photocatalyst and the optimum loading of TiO2 in the present system is found to be approximately 0.2 wt%. The stripping fraction of TCE by air flow increases but photodegradation fraction of TCE decreases with increasing the initial TCE concentration, recirculating liquid flow rate and gas velocity. The average removal efficiency of TCE is found to be approximately 97% in an internally circulating slurry bubble column reactor.

26 CFR 1.613-3 - Gross income from the property.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 26 Internal Revenue 7 2011-04-01 2009-04-01 true Gross income from the property. 1.613-3 Section 1.613-3 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES (CONTINUED) Natural Resources § 1.613-3 Gross income from the property. Oil and gas...

Sizzling Qatar boom sparked by foreign money, technology, and gas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aalund, L.R.

International oil companies have collected advanced upstream and downstream technology and focused it on the small Persian Gulf emirate of Qatar, a roughly 110 mile long by 50 mile wide, thumb-like peninsula that juts out from Saudi Arabia. The emirate, in a burst of enlightened self interest, has opened its doors to international companies and is now riding a wave of foreign investment and new technology to major increases in oil, natural gas, and petrochemical production. The largest natural gas reserve in the world is under Qatari waters and is the driver for the activity that includes two LNG plants.more » Qatar has proven that you don`t need crude oil in the Persian Gulf to be important. Activities are discussed.« less

Stepwise Internal Energy Control for Protonated Methanol Clusters by Using the Inert Gas Tagging

NASA Astrophysics Data System (ADS)

Shimamori, Takuto; Kuo, Jer-Lai; Fujii, Asuka

2016-06-01

Preferred isomer structures of hydrogen-bonded clusters should depend on their temperature because of the entropy term in the free energy. To observe such temperature dependence, we propose a new approach to control the internal energy (vibrational temperature) of protonated clusters in the gas phase. We performed IR spectroscopy of protonated methanol clusters, H+ (CH{_3}OH) {_n}, n= 5 and 7, with the tagging by various inert gas species (Ar, CO{_2}, CO, CS{_2}, C{_2}H{_2}, and C{_6}H{_6}). We found that vibrational temperature of the tagged clusters raises with increase of the interaction energy with the tag species, and the observed cluster structures follow the theoretical prediction of the temperature dependence of the isomer population.

Feasibilities of a Coal-Biomass to Liquids Plant in Southern West Virginia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bhattacharyya, Debangsu; DVallance, David; Henthorn, Greg

This project has generated comprehensive and realistic results of feasibilities for a coal-biomass to liquids (CBTL) plant in southern West Virginia; and evaluated the sensitivity of the analyses to various anticipated scenarios and parametric uncertainties. Specifically the project has addressed economic feasibility, technical feasibility, market feasibility, and financial feasibility. In the economic feasibility study, a multi-objective siting model was developed and was then used to identify and rank the suitable facility sites. Spatial models were also developed to assess the biomass and coal feedstock availabilities and economics. Environmental impact analysis was conducted mainly to assess life cycle analysis and greenhousemore » gas emission. Uncertainty and sensitivity analysis were also investigated in this study. Sensitivity analyses on required selling price (RSP) and greenhouse gas (GHG) emissions of CBTL fuels were conducted according to feedstock availability and price, biomass to coal mix ratio, conversion rate, internal rate of return (IRR), capital cost, operational and maintenance cost. The study of siting and capacity showed that feedstock mixed ratio limited the CBTL production. The price of coal had a more dominant effect on RSP than that of biomass. Different mix ratios in the feedstock and conversion rates led to RSP ranging from $104.3 - $157.9/bbl. LCA results indicated that GHG emissions ranged from 80.62 kg CO 2 eq to 101.46 kg CO2 eq/1,000 MJ of liquid fuel at various biomass to coal mix ratios and conversion rates if carbon capture and storage (CCS) was applied. Most of water and fossil energy were consumed in conversion process. Compared to petroleum-derived-liquid fuels, the reduction in GHG emissions could be between -2.7% and 16.2% with CBTL substitution. As for the technical study, three approaches of coal and biomass to liquids, direct, indirect and hybrid, were considered in the analysis. The process models including conceptual design, process modeling and process validation were developed and validated for different cases. Equipment design and capital costs were investigated on capital coast estimation and economical model validation. Material and energy balances and techno-economic analysis on base case were conducted for evaluation of projects. Also, sensitives studies of direct and indirect approaches were both used to evaluate the CBTL plant economic performance. In this study, techno-economic analysis were conducted in Aspen Process Economic Analyzer (APEA) environment for indirect, direct, and hybrid CBTL plants with CCS based on high fidelity process models developed in Aspen Plus and Excel. The process thermal efficiency ranges from 45% to 67%. The break-even oil price ranges from $86.1 to $100.6 per barrel for small scale (10000 bbl/day) CBTL plants and from $65.3 to $80.5 per barrel for large scale (50000 bbl/day) CBTL plants. Increasing biomass/coal ratio from 8/92 to 20/80 would increase the break-even oil price of indirect CBTL plant by $3/bbl and decrease the break-even oil price of direct CBTL plant by about $1/bbl. The order of carbon capture penalty is direct > indirect > hybrid. The order of capital investment is hybrid (with or without shale gas utilization) > direct (without shale gas utilization) > indirect > direct (with shale gas utilization). The order of thermal efficiency is direct > hybrid > indirect. The order of break-even oil price is hybrid (without shale gas utilization) > direct (without shale gas utilization) > hybrid (with shale gas utilization) > indirect > direct (with shale gas utilization).« less

Trip internalization in multi-use developments : [summary].

DOT National Transportation Integrated Search

2014-04-01

Gas prices and fossil fuel concerns have promoted : reduced car use. More people are seeking : housing within a walk, bike, or shorter drive of : important destinations, leading to more mixed : use developments (MXD) with internal retail sites, : red...

Microtextured Surfaces for Turbine Blade Impingement Cooling

NASA Technical Reports Server (NTRS)

Fryer, Jack

2014-01-01

Gas turbine engine technology is constantly challenged to operate at higher combustor outlet temperatures. In a modern gas turbine engine, these temperatures can exceed the blade and disk material limits by 600 F or more, necessitating both internal and film cooling schemes in addition to the use of thermal barrier coatings. Internal convective cooling is inadequate in many blade locations, and both internal and film cooling approaches can lead to significant performance penalties in the engine. Micro Cooling Concepts, Inc., has developed a turbine blade cooling concept that provides enhanced internal impingement cooling effectiveness via the use of microstructured impingement surfaces. These surfaces significantly increase the cooling capability of the impinging flow, as compared to a conventional untextured surface. This approach can be combined with microchannel cooling and external film cooling to tailor the cooling capability per the external heating profile. The cooling system then can be optimized to minimize impact on engine performance.

Capabilities of the Impact Testing Facility at Marshall Space Flight Center

NASA Technical Reports Server (NTRS)

Finchum, Andy; Nehls, Mary; Young, Whitney; Gray, Perry; Suggs, Bart; Lowrey, Nikki M.

2011-01-01

The test and analysis capabilities of the Impact Testing Facility at NASA's Marshall Space Flight Center are described. Nine different gun systems accommodate a wide range of projectile and target sizes and shapes at velocities from subsonic through hypersonic, to accomplish a broad range of ballistic and hypervelocity impact tests. These gun systems include ballistic and microballistic gas and powder guns, a two-stage light gas gun, and specialty guns for weather encounter studies. The ITF "rain gun" is the only hydrometeor impact gun known to be in existence in the United States that can provide single impact performance data with known raindrop sizes. Simulation of high velocity impact is available using the Smooth Particle Hydrodynamic Code. The Impact Testing Facility provides testing, custom test configuration design and fabrication, and analytical services for NASA, the Department of Defense, academic institutions, international space agencies, and private industry in a secure facility located at Marshall Space Flight Center, on the US Army's Redstone Arsenal in Huntsville, Alabama. This facility performs tests that are subject to International Traffic in Arms Regulations (ITAR) and DoD secret classified restrictions as well as proprietary and unrestricted tests for civil space agencies, academic institutions, and commercial aerospace and defense companies and their suppliers.

Determination of guaifenesin in human serum by capillary gas chromatography and electron capture detection.

PubMed

Sharaf, Maged H M; Stiff, Dwight D

2004-06-29

A method for the quantitation of guaifenesin in human serum has been developed and validated. The procedure involves liquid-liquid extraction of the serum sample in the presence of mephenesin as an internal standard, followed by derivatization and analysis using capillary gas chromatography (GC) and electron capture detection (ECD). Different solvents were tested for extraction of guaifenesin from serum. n-Hexane/dichloromethane (1:1, v/v) gave the highest recovery and the lowest background and was chosen as the extraction solvent. After extraction, the residue of guaifenesin was derivatized at 60 degrees C for 30 min, with trifluoroacetic acid anhydride (TFAA) in toluene in the presence of pyridine. Excess trifluoroacetic acid anhydride was removed using dilute solution of ammonium hydroxide. The method proved to be linear over the range of 25.0-1000 ng/ml. Recovery of guaifenesin from spiked samples was consistent, averaging 75.5% at 50.0 ng/ml with a range of 72.0-80.0% (N = 8 determinations) and averaging 78% at 800 ng/ml with a range of 76.0-81.0% (N = 8 determinations). The internal standard recovery was also consistent averaging 72.8% with a range of 67.0-76.0% (N = 16 determinations). Copyright 2004 Elsevier B.V.

Quantification of plasma myo-inositol using gas chromatography-mass spectrometry.

PubMed

Guo, Jin; Shi, Yingfei; Xu, Chengbao; Zhong, Rugang; Zhang, Feng; Zhang, Ting; Niu, Bo; Wang, Jianhua

2016-09-01

Myo-inositol (MI) deficiency is associated with an increased risk for neural tube defects (NTDs), mental disorders and metabolic diseases. We developed a gas chromatography-mass spectrometry (GC-MS) method to detect MI in human plasma, which was accurate, relatively efficient and convenient for clinical application. An external standard method was used for determination of plasma MI. Samples were analyzed by GC-MS after derivatization. The stable-isotope labeled internal standard approach was used to validate the method's accuracy. Alpha fetal protein (AFP) was detected by chemiluminescence immunoassay. The method was validated by determining the linearity, sensitivity and recovery rate. There was a good agreement between the internal standard approach and the present method. The NTD-affected pregnancies showed lower plasma MI (P=0.024) and higher AFP levels (P=0.001) than control. Maternal MI level showed a better discrimination in spina bifida subgroup, while AFP level showed a better discrimination in anencephaly subgroup after stratification analysis. We developed a sensitive and reliable method for the detection of clinical plasma MI, which might be a marker for NTDs screening, and established fundamental knowledge for clinical diagnosis and prevention for the diseases related to disturbed MI metabolism. Copyright © 2016 Elsevier B.V. All rights reserved.

International Space Station (ISS)

NASA Image and Video Library

2003-01-16

In this International Space Station (ISS) onboard photo, Expedition Six Science Officer Donald R. Pettit works to set up the Pulmonary Function in Flight (PuFF) experiment hardware in the Destiny Laboratory. Expedition Six is the fourth and final crew to perform the PuFF experiment. The PuFF experiment was developed to better understand what effects long term exposure to microgravity may have on the lungs. The focus is on measuring changes in the everness of gas exchange in the lungs, and on detecting changes in respiratory muscle strength. It allows astronauts to measure blood flow through the lungs, the ability of the lung to take up oxygen, and lung volumes. Each PuFF session includes five lung function tests, which involve breathing only cabin air. For each planned extravehicular (EVA) activity, a crew member performs a PuFF test within one week prior to the EVA. Following the EVA, those crew members perform another test to document the effect of exposure of the lungs to the low-pressure environment of the space suits. This experiment utilizes the Gas Analyzer System for Metabolic Analysis Physiology, or GASMAP, located in the Human Research Facility (HRF), along with a variety of other Puff equipment including a manual breathing valve, flow meter, pressure-flow module, pressure and volume calibration syringes, and disposable mouth pieces.

Towards the Detection of Explosive Taggants: Microwave and Millimetre-Wave Gas-Phase Spectroscopies of 3-Nitrotoluene.

PubMed

Roucou, Anthony; Kleiner, Isabelle; Goubet, Manuel; Bteich, Sabath; Mouret, Gael; Bocquet, Robin; Hindle, Francis; Meerts, W Leo; Cuisset, Arnaud

2018-05-07

The monitoring of gas-phase mononitrotoluenes is crucial for defence, civil security and environmental interests because they are used as taggant for TNT detection and in the manufacturing of industrial compounds such as dyestuffs. In this study, we have succeeded to measure and analyse at high-resolution a room temperature rotationally resolved millimetre-wave spectrum of meta-nitrotoluene (3-NT). Experimental and theoretical difficulties have been overcome, in particular, those related to the low vapour pressure of 3-NT and to the presence of a CH 3 internal rotation in an almost free rotation regime (V 3 =6.7659(24) cm -1 ). Rotational spectra have been recorded in the microwave and millimetre-wave ranges using a supersonic jet Fourier Transform microwave spectrometer (T rot <10 K) and a millimetre-wave frequency multiplication chain (T=293 K), respectively. Spectral analysis of pure rotation lines in the vibrational ground state and in the first torsional excited state supported by quantum chemistry calculations permits the rotational energy of the molecule, the hyperfine structure due to the 14 N nucleus, and the internal rotation of the methyl group to be characterised. A line list is provided for future in situ detection. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Fuel saving and emissions cut through shore-side power concept for high-speed crafts at the red sea in egypt

NASA Astrophysics Data System (ADS)

Seddiek, Ibrahim S.; Mosleh, Mosaad A.; Banawan, Adel A.

2013-12-01

The progress of economic globalization, the rapid growth of international trade, and the maritime transportation has played an increasingly significant role in the international supply chain. As a result, worldwide seaports have suffered from a central problem, which appears in the form of massive amounts of fuel consumed and exhaust gas fumes emitted from the ships while berthed. Many ports have taken the necessary precautions to overcome this problem, while others still suffer due to the presence of technical and financial constraints. In this paper, the barriers, interconnection standards, rules, regulations, power sources, and economic and environmental analysis related to ships, shore-side power were studied in efforts to find a solution to overcome his problem. As a case study, this paper investigates the practicability, costs and benefits of switching from onboard ship auxiliary engines to shore-side power connection for high-speed crafts called Alkahera while berthed at the port of Safaga, Egypt. The results provide the national electricity grid concept as the best economical selection with 49.03 percent of annual cost saving. Moreover, environmentally, it could achieve an annual reduction in exhaust gas emissions of CO2, CO, NO x , P.M, and SO2 by 276, 2.32, 18.87, 0.825 and 3.84 tons, respectively.

Quantification of Short-Chain Chlorinated Paraffins by Deuterodechlorination Combined with Gas Chromatography-Mass Spectrometry.

PubMed

Gao, Yuan; Zhang, Haijun; Zou, Lili; Wu, Ping; Yu, Zhengkun; Lu, Xianbo; Chen, Jiping

2016-04-05

Analysis of short-chain chlorinated paraffins (SCCPs) is extremely difficult because of their complex compositions with thousands of isomers and homologues. A novel analytical method, deuterodechlorination combined with high resolution gas chromatography-high resolution mass spectrometry (HRGC-HRMS), was developed. A protocol is applied in the deuterodechlorination of SCCPs with LiAlD4, and the formed deuterated n-alkanes of different alkane chains can be distinguished readily from each other on the basis of their retention time and fragment mass ([M](+)) by HRGC-HRMS. An internal standard quantification of individual SCCP congeners was achieved, in which branched C10-CPs and branched C12-CPs were used as the extraction and reaction internal standards, respectively. A maximum factor of 1.26 of the target SCCP concentrations were determined by this method, and the relative standard deviations for quantification of total SCCPs were within 10%. This method was applied to determine the congener compositions of SCCPs in commercial chlorinated paraffins and environmental and biota samples after method validation. Low-chlorinated SCCP congeners (Cl1-4) were found to account for 32.4%-62.4% of the total SCCPs. The present method provides an attractive perspective for further studies on the toxicological and environmental characteristics of SCCPs.

Influence of the single EGR valve usability on development of the charge directed to individual cylinders of an internal combustion engine

NASA Astrophysics Data System (ADS)

Krakowian, Konrad; Kaźmierczak, Andrzej; Górniak, Aleksander; Wróbel, Radosław

2017-11-01

Exhaust gas recirculation systems (EGR), aside to a catalytic converters, are nowadays widely used in piston internal combustion engines to reduce nitrogen oxides (NOx) in the exhaust gas. They are characterized in that a portion of exhaust gases from the exhaust manifold is recirculated (via a condenser), and directed to a particular valve. The valve, depending on the current engine load and speed, doses the appropriate amount of exhaust gas into the exhaust manifold. Moreover, its location has a significant impact on the diverse formation of nitrogen oxides and fumes smokiness from the individual cylinders of the engine, which is a result of uneven propagation of exhaust gas into the channels of the intake manifold. This article contains the results of numerical characterized charges formed in symmetrical intake manifold with a centrally-placed EGR valve. Simulations were performed for the original intake system derived from the two-liter, turbocharged VW diesel engine.

Landfill gas to electricity demonstration project

NASA Astrophysics Data System (ADS)

Giuliani, A. J.; Cagliostro, L. A.

1982-03-01

Medium Btu methane gas is a naturally occurring by product of anaerobic digestion of landfilled municipal solid waste. The energy potential of landfill gas in New York State is estimated to be 61 trillion Btu's per year or the equivalent of 10 percent of the natural gas used annually in the State. The 18-month Landfill Gas to Electricity Demonstration Project conducted at the Fresh Kills Landfill in Staten Island, New York conclusively demonstrated that landfill gas is an acceptable fuel for producing electricity using an internal combustion engine/generator set. Landfill gas proved to be a reliable and consistent fuel source during a six-month field test program. Engine exhaust emissions were determined to be comparable to that of natural gas and no unusually high corrosion rates on standard pipeline material were found.

Gas stream purifier

NASA Technical Reports Server (NTRS)

Adam, Steven J.

1994-01-01

A gas stream purifier has been developed that is capable of removing corrosive acid, base, solvent, organic, inorganic, and water vapors as well as particulates from an inert mixed gas stream using only solid scrubbing agents. This small, lightweight purifier has demonstrated the ability to remove contaminants from an inert gas stream with a greater than 99 percent removal efficiency. The Gas Stream Purifier has outstanding market and sales potential in manufacturing, laboratory and science industries, medical, automotive, or any commercial industry where pollution, contamination, or gas stream purification is a concern. The purifier was developed under NASA contract NAS9-18200 Schedule A for use in the international Space Station. A patent application for the Gas Stream Purifier is currently on file with the United States Patent and Trademark Office.

Description and initial operating performance of the Langley 6-inch expansion tube using heated helium driver gas

NASA Technical Reports Server (NTRS)

Moore, J. A.

1975-01-01

A general description of the Langley 6-inch expansion tube is presented along with discussion of the basic components, internal resistance heater, arc-discharge assemblies, instrumentation, and operating procedure. Preliminary results using unheated and resistance-heated helium as the driver gas are presented. The driver-gas pressure ranged from approximately 17 to 59 MPa and its temperature ranged from 300 to 510 K. Interface velocities of approximately 3.8 to 6.7 km/sec were generated between the test gas and the acceleration gas using air as the test gas and helium as the acceleration gas. Test flow quality and comparison of measured and predicted expansion-tube flow quantities are discussed.

26 CFR 1.613A-1 - Post-1974 limitations on percentage depletion in case of oil and gas wells; general rule.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 26 Internal Revenue 7 2010-04-01 2010-04-01 true Post-1974 limitations on percentage depletion in... Resources § 1.613A-1 Post-1974 limitations on percentage depletion in case of oil and gas wells; general... attributable after such year, the allowance for depletion under section 611 with respect to any oil or gas well...

Need for Robust Sensors for Inherently Fail-Safe Gas Turbine Engine Controls, Monitoring, and Prognostics (Postprint)

DTIC Science & Technology

2006-09-01

MONITORING , AND PROGNOSTICS Alireza R. Behbahani Controls / Engine Health Management Turbine Engine Division / PRTS U.S. Air Force Research...Technical Report 2005. 8. Greitzer, Frank et al, “Gas Turbine Engine Health Monitoring and Prognostics ”, International Society of Logistics (SOLE...AFRL-PR-WP-TP-2007-217 NEED FOR ROBUST SENSORS FOR INHERENTLY FAIL-SAFE GAS TURBINE ENGINE CONTROLS, MONITORING , AND PROGNOSTICS (POSTPRINT

Quantitative analysis of multi-component gas mixture based on AOTF-NIR spectroscopy

NASA Astrophysics Data System (ADS)

Hao, Huimin; Zhang, Yong; Liu, Junhua

2007-12-01

Near Infrared (NIR) spectroscopy analysis technology has attracted many eyes and has wide application in many domains in recent years because of its remarkable advantages. But the NIR spectrometer can only be used for liquid and solid analysis by now. In this paper, a new quantitative analysis method of gas mixture by using new generation NIR spectrometer is explored. To collect the NIR spectra of gas mixtures, a vacuumable gas cell was designed and assembled to Luminar 5030-731 Acousto-Optic Tunable Filter (AOTF)-NIR spectrometer. Standard gas samples of methane (CH 4), ethane (C IIH 6) and propane (C 3H 8) are diluted with super pure nitrogen via precision volumetric gas flow controllers to obtain gas mixture samples of different concentrations dynamically. The gas mixtures were injected into the gas cell and the spectra of wavelength between 1100nm-2300nm were collected. The feature components extracted from gas mixture spectra by using Partial Least Squares (PLS) were used as the inputs of the Support Vector Regress Machine (SVR) to establish the quantitative analysis model. The effectiveness of the model is tested by the samples of predicting set. The prediction Root Mean Square Error (RMSE) of CH 4, C IIH 6 and C 3H 8 is respectively 1.27%, 0.89%, and 1.20% when the concentrations of component gas are over 0.5%. It shows that the AOTF-NIR spectrometer with gas cell can be used for gas mixture analysis. PLS combining with SVR has a good performance in NIR spectroscopy analysis. This paper provides the bases for extending the application of NIR spectroscopy analysis to gas detection.