DOE Office of Scientific and Technical Information (OSTI.GOV)

Asahina, Yuta; Kawashima, Tomohisa; Furukawa, Naoko

The formation mechanism of CO clouds observed with the NANTEN2 and Mopra telescopes toward the stellar cluster Westerlund 2 is studied by 3D magnetohydrodynamic simulations, taking into account the interstellar cooling. These molecular clouds show a peculiar shape composed of an arc-shaped cloud on one side of the TeV γ -ray source HESS J1023-575 and a linear distribution of clouds (jet clouds) on the other side. We propose that these clouds are formed by the interaction of a jet with clumps of interstellar neutral hydrogen (H i). By studying the dependence of the shape of dense cold clouds formed bymore » shock compression and cooling on the filling factor of H i clumps, we found that the density distribution of H i clumps determines the shape of molecular clouds formed by the jet–cloud interaction: arc clouds are formed when the filling factor is large. On the other hand, when the filling factor is small, molecular clouds align with the jet. The jet propagates faster in models with small filling factors.« less

Isotope Fractionation in the Interstellar Medium

NASA Technical Reports Server (NTRS)

Charnley, Steven

2011-01-01

Anomalously fractionated isotopic material is found in many primitive Solar System objects, such as meteorites and comets. It is thought, in some cases, to trace interstellar matter that was incorporated into the Solar Nebula without undergoing significant processing. We will present the results of models of the nitrogen, oxygen, and carbon fractionation chemistry in dense molecular clouds, particularly in cores where substantial freeze-out of molecules on to dust has occurred. The range of fractionation ratios expected in different interstellar molecules will be discussed and compared to the ratios measured in molecular clouds, comets and meteoritic material. These models make several predictions that can be tested in the near future by molecular line observations, particularly with ALMA.

Chemistry and Evolution of Interstellar Clouds

NASA Technical Reports Server (NTRS)

Wooden, D. H.; Charnley, S. B.; Ehrenfreund, P.

2003-01-01

In this chapter we describe how elements have been and are still being formed in the galaxy and how they are transformed into the reservoir of materials present at the time of formation of our protosolar nebula. We discuss the global cycle of matter, beginning at its formation site in stars, where it is ejected through winds and explosions into the diffuse interstellar medium. In the next stage of the global cycle occurs in cold, dense molecular clouds, where the complexity of molecules and ices increases relative to the diffuse ISM.. When a protostar forms in a dense core within a molecular cloud, it heats the surrounding infalling matter warms and releases molecules from the solid phase into the gas phase in a warm, dense core, sponsoring a rich gas-phase chemistry. Some material from the cold and warm regions within molecular clouds probably survives as interstellar matter in the protostellar disk. For the diffuse ISM, for cold, dense clouds, and for dense-warm cores, the physio-chemical processes that occur within the gas and solid phases are discussed in detail.

A Herschel [C ii] Galactic plane survey. II. CO-dark H2 in clouds

NASA Astrophysics Data System (ADS)

Langer, W. D.; Velusamy, T.; Pineda, J. L.; Willacy, K.; Goldsmith, P. F.

2014-01-01

Context. H i and CO large scale surveys of the Milky Way trace the diffuse atomic clouds and the dense shielded regions of molecular hydrogen clouds, respectively. However, until recently, we have not had spectrally resolved C+ surveys in sufficient lines of sight to characterize the ionized and photon dominated components of the interstellar medium, in particular, the H2 gas without CO, referred to as CO-dark H2, in a large sample of interstellar clouds. Aims: We use a sparse Galactic plane survey of the 1.9 THz (158 μm) [C ii] spectral line from the Herschel open time key programme, Galactic Observations of Terahertz C+ (GOT C+), to characterize the H2 gas without CO in a statistically significant sample of interstellar clouds. Methods: We identify individual clouds in the inner Galaxy by fitting the [C ii] and CO isotopologue spectra along each line of sight. We then combine these spectra with those of H i and use them along with excitation models and cloud models of C+ to determine the column densities and fractional mass of CO-dark H2 clouds. Results: We identify1804 narrow velocity [C ii] components corresponding to interstellar clouds in different categories and evolutionary states. About 840 are diffuse molecular clouds with no CO, ~510 are transition clouds containing [C ii] and 12CO, but no 13CO, and the remainder are dense molecular clouds containing 13CO emission. The CO-dark H2 clouds are concentrated between Galactic radii of ~3.5 to 7.5 kpc and the column density of the CO-dark H2 layer varies significantly from cloud to cloud with a global average of 9 × 1020 cm-2. These clouds contain a significant fraction by mass of CO-dark H2, that varies from ~75% for diffuse molecular clouds to ~20% for dense molecular clouds. Conclusions: We find a significant fraction of the warm molecular ISM gas is invisible in H i and CO, but is detected in [C ii]. The fraction of CO-dark H2 is greatest in the diffuse clouds and decreases with increasing total column density, and is lowest in the massive clouds. The column densities and mass fraction of CO-dark H2 are less than predicted by models of diffuse molecular clouds using solar metallicity, which is not surprising as most of our detections are in Galactic regions where the metallicity is larger and shielding more effective. There is an overall trend towards a higher fraction of CO-dark H2 in clouds with increasing Galactic radius, consistent with lower metallicity there. Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.

A new interstellar molecule - Tricarbon monoxide

NASA Technical Reports Server (NTRS)

Matthews, H. E.; Irvine, W. M.; Friberg, P.; Brown, R. D.; Godfrey, P. D.

1984-01-01

The C3O molecule, whose pure rotational spectrum has only recently been studied in the laboratory, has been detected in the cold, dark interstellar Taurus Molecular Cloud 1. Since C3O is the first interstelar carbon chain molecule to contain oxygen, its existence places an important new constraint on chemical schemes for cold interstellar clouds. The abundance of C3O can be understood in terms of purely gas-phase ion-molecule chemistry.

Boundary conditions for the paleoenvironment: Chemical and physical processes in the pre-solar nebula

NASA Technical Reports Server (NTRS)

Irvine, William M.; Schloerb, F. Peter

1987-01-01

Detailed study of the first interstellar hydrocarbon ring, cyclopropenylidene (C3H2), is continuing. The singly deuterated isotope of this molecule, C3HD, was observed in several cold interstellar clouds. The results of a large survey for C3H2 in galactic sources of various types will soon be completed. It appears that cyclopropenylidene is present in virtually all interstellar clouds of at least moderate density. In order to make the first determinations of the CO2/CO abundance ratio in interstellar sources, observations of protonated CO2 were pursued. The spectrum from 18.5 to 22 GHz for several interstellar clouds is being systematically measured. Particular attention is being given to the cold, dark clouds TMC-1 and L124N, which may be formation sites for solar mass stars. The phenomena of maser emission from molecules of methanol is being studied in certain interstellar clouds. A comparison of 1 millimeter continuum emission from dust with the column density of carbon monoxide as determined from the rare C(18)O isotope for 4 molecular clouds in the Galaxy is nearing completion. Papers published during the period of this report are listed.

Vibrational Spectroscopy after OSU - From C2- to Interstellar Polycyclic Aromatic Hydrocarbons

NASA Technical Reports Server (NTRS)

Allamandola, Louis J.

2006-01-01

The composition of interstellar ice and dust provides insight into the chemical history of the interstellar medium and early solar system. It is now possible to probe this unique and unusual chemistry and determine the composition of these microscopic interstellar particles which are hundreds to many thousands of light years away thanks to substantial progress in two areas: astronomical spectroscopic techniques in the middle-infrared, the spectral region most diagnostic of chemical composition, and laboratory simulations which realistically reproduce the critical conditions in various interstellar environments. High quality infrared spectra of many different astronomical sources, some associated with giant, dark molecular clouds -the birthplace of stars and planets- and others in more tenuous, UV radiation rich regions are now available. The fundamentals of IR spectroscopy and what comparisons of astronomical IR spectra with laboratory spectra of materials prepared under realistic simulated interstellar conditions tell us about the components of these materials is the subject of this talk. These observations have shown that mixed molecular ices comprised of H2O, CH3OH, CO, NH3 and H2CO contain most of the molecular material in molecular clouds and that gas phase, ionized polycyclic aromatic hydrocarbons (PAHs) are widespread and surprisingly abundant throughout most of the interstellar medium.

Isotopic Fractionation in Primitive Material: Quantifying the Contribution of Interstellar Chemistry

NASA Technical Reports Server (NTRS)

Charnley, Steven

2010-01-01

Anomalously fractionated isotopic material is found in many primitive Solar System objects, such as meteorites and comets. It is thought, in some cases, to trace interstellar matter that was incorporated into the Solar Nebula without undergoing significant processing. We will present the results of models of the nitrogen, oxygen, and carbon fractionation chemistry in dense molecular clouds, particularly in cores where substantial freeze-out of molecules on to dust has occurred. The range of fractionation ratios expected in different interstellar molecules will be discussed and compared to the ratios measured in molecular clouds, comets and meteoritic material. These models make several predictions that can be tested in the near future by molecular line observations, particularly with ALMA.

Insights into H2 formation in space from ab initio molecular dynamics

PubMed Central

Casolo, Simone; Tantardini, Gian Franco; Martinazzo, Rocco

2013-01-01

Hydrogen formation is a key process for the physics and the chemistry of interstellar clouds. Molecular hydrogen is believed to form on the carbonaceous surface of dust grains, and several mechanisms have been invoked to explain its abundance in different regions of space, from cold interstellar clouds to warm photon-dominated regions. Here, we investigate direct (Eley–Rideal) recombination including lattice dynamics, surface corrugation, and competing H-dimers formation by means of ab initio molecular dynamics. We find that Eley–Rideal reaction dominates at energies relevant for the interstellar medium and alone may explain observations if the possibility of facile sticking at special sites (edges, point defects, etc.) on the surface of the dust grains is taken into account. PMID:23572584

From Interstellar PAHs and Ices to the Origin of Life

NASA Technical Reports Server (NTRS)

Allamandola, Louis J.; DeVincenzi, Donald L. (Technical Monitor)

2000-01-01

Tremendous strides have been made in our understanding of interstellar material over the past twenty years thanks to significant, parallel developments in observational astronomy and laboratory astrophysics. Twenty years ago the composition of interstellar dust was largely guessed at, the concept of ices in dense molecular clouds ignored, and the notion of large, abundant, gas phase, carbon rich molecules widespread throughout the interstellar medium (ISM) considered impossible. Today the composition of dust in the diffuse ISM is reasonably well constrained to micron-sized cold refractory materials comprised of amorphous and crystalline silicates mixed with an amorphous carbonaceous material containing aromatic structural units and short, branched aliphatic chains. In dense molecular clouds, the birthplace of stars and planets, these cold dust particles are coated with mixed molecular ices whose composition is very well constrained. Lastly, the signature of carbon-rich polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by earlier interstellar chemistry standards, is widespread throughout the Universe. The first part of this lecture will describe how infrared studies of interstellar space, combined with laboratory simulations, have revealed the composition of interstellar ices (the building blocks of comets) and the high abundance and nature of interstellar PAHs. The laboratory database has now enabled us to gain insight into the identities, concentrations, and physical state of many interstellar materials. Within a dense molecular cloud, and especially in the solar nebula during the star and planet formation stage, the materials frozen into interstellar/precometary ices are photoprocessed by ultraviolet light, producing more complex molecules. The remainder of the presentation will focus on the photochemical evolution of these materials and the possible role of these compounds on the early Earth. As these materials are thought to be the building blocks of comets and related to the carbonaceous components of micrometeorites, they are likely to have been important sources of complex organic materials on the early Earth and their composition may be related to the origin of life.

Interstellar clouds - From a dynamical perspective on their chemistry

NASA Technical Reports Server (NTRS)

Prasad, S. S.

1985-01-01

The possibility is examined that in the course of its dynamical evolution, a single mass of interstellar gas would exhibit properties of diffuse clouds, dense clouds and finally also of clouds perturbed by shocks or intense UV or X-ray radiation generated by a star of its own creation. This concept provides a common thread through the bewildering diversity of physical and chemical compositional properties shown by interstellar clouds. From this perspective, instead of being static objects, interstellar clouds are possibly incessantly evolving from initially diffuse to later dense state and then to star formation which ultimately restructures or disperses the remaining cloud material to begin the whole evolutionary process once again. Based on a simplified study of interstellar chemistry from a dynamical perspective, the ideas are presented as an heuristic: to encourage thought on the future direction of molecular astrophysics and the need to consider the chemical behavior of interstellar clouds in conjunction with, rather than in isolation from, their dynamical behavior. A physical basis must be sought for the semiempirical temperature formula which has been given a critical role in the collapse of diffuse clouds. Self-shielding effects in the chemistry of CO were neglected and this drawback should be removed; the ability of the model to explain the fractional abundances of more complex molecules, such as cyanopolyynes, should be examined.

The violent interstellar medium in Milky-Way like disk galaxies

NASA Astrophysics Data System (ADS)

Karoline Walch, Stefanie

2015-08-01

Molecular clouds are cold, dense, and turbulent filamentary structures that condense out of the multi-phase interstellar medium. They are also the sites of star formation. The minority of new-born stars is massive, but these stars are particularly important for the fate of their parental molecular clouds as their feedback drives turbulence and regulates star formation.I will present results from the SILCC project (SImulating the Life Cycle of molecular Clouds), in which we study the formation and dispersal of molecular clouds within the multi-phase ISM using high-performance, three-dimensional simulations of representative pieces of disk galaxies. Apart from stellar feedback, self-gravity, an external stellar potential, and magnetic fields, we employ an accurate description of gas heating and cooling as well as a small chemical network including molecule formation and (self-)shielding from the interstellar radiation field. We study the impact of the supernova rate and the positioning of the supernova explosions with respect to the molecular gas in a well defined set of simulations. This allows us to draw conclusions on structure of the multi-phase ISM, the amount of molecular gas formed, and the onset of galactic outflows. Furthermore, we show how important stellar wind feedback is for regulating star formation in these disks.

Analysis of ultraviolet spectrophotometric data from Copernicus

NASA Technical Reports Server (NTRS)

Snow, T. P., Jr.

1979-01-01

Ultraviolet spectral data from the OAO 3 satellite are being used to study interstellar absorption lines and stellar and circumstellar lines in hot stars. The interstellar data are beneficial in analyzing the depletions of heavy elements from the gas phase and in elucidating how these depletions depend on physical conditions. Abundances in separate velocity components were determined from line profiles. Observations were carried out for interstellar abundances, both atomic and molecular, towards a number of stars. The better quality data are being analyzed for profile information and the lesser data are being used in curve-of-growth analyses. Molecular observations were carried out as well, N2 was sought; interstellar C2 was detected and its rotational excitation utilized to establish limits in interstellar cloud temperatures. An extensive search for H2O resulted in a tentative identification which will produce new information on chemical reaction rates. Interstellar depletions and grain properties in the rho Ophiuchi cloud, stellar wind variability, and circumstellar lines are also under study.

Diamonds in dense molecular clouds - A challenge to the standard interstellar medium paradigm

NASA Technical Reports Server (NTRS)

Allamandola, L. J.; Sandford, S. A.; Tielens, A. G. G. M.; Herbst, T. M.

1993-01-01

Observations of a newly discovered infrared C-H stretching band indicate that interstellar diamond-like material appears to be characteristic of dense clouds. In sharp contrast, the spectral signature of dust in the diffuse interstellar medium is dominated by -CH2- and -CH3 groups. This dichotomy in the aliphatic organic component between the dense and diffuse media challenges standard assumptions about the processes occurring in, and interactions between, these two media. The ubiquity of this interstellar diamond-like material rules out models for meteoritic diamond formation in unusual circumstellar environments and implies that the formation of the diamond-like material is associated with common interstellar processes or stellar types.

Organic molecules in translucent interstellar clouds.

PubMed

Krełowski, Jacek

2014-09-01

Absorption spectra of translucent interstellar clouds contain many known molecular bands of CN, CH+, CH, OH, OH(+), NH, C2 and C3. Moreover, one can observe more than 400 unidentified absorption features, known as diffuse interstellar bands (DIBs), commonly believed to be carried by complex, carbon-bearing molecules. DIBs have been observed in extragalactic sources as well. High S/N spectra allow to determine precisely the corresponding column densities of the identified molecules, rotational temperatures which differ significantly from object to object in cases of centrosymmetric molecular species, and even the (12)C/(13)C abundance ratio. Despite many laboratory based studies of possible DIB carriers, it has not been possible to unambiguously link these bands to specific species. An identification of DIBs would substantially contribute to our understanding of chemical processes in the diffuse interstellar medium. The presence of substructures inside DIB profiles supports the idea that DIBs are very likely features of gas phase molecules. So far only three out of more than 400 DIBs have been linked to specific molecules but none of these links was confirmed beyond doubt. A DIB identification clearly requires a close cooperation between observers and experimentalists. The review presents the state-of-the-art of the investigations of the chemistry of interstellar translucent clouds i.e. how far our observations are sufficient to allow some hints concerning the chemistry of, the most common in the Galaxy, translucent interstellar clouds, likely situated quite far from the sources of radiation (stars).

Dissociative recombination in interstellar clouds

NASA Technical Reports Server (NTRS)

Black, John H.; Van Dishoeck, Ewine F.

1989-01-01

Molecular ions play a significant role in the chemistry and evolution of interstellar molecular clouds, even though these regions are overwhelmingly neutral. The dissociative recombination (DR) process governs the abundances of many of these ions and of related neutral species. The gas-phase ion-molecule chemistry of the simplest species is summarized, with emphasis on those problems which are most sensitive to uncertain rates or product branching ratios of DR processes. Examples of the kinds of information needed about DR processes are presented. The importance of the H3(+) ion and prospects for its direct observation are discussed.

Molecular diagnostics of interstellar shocks

NASA Technical Reports Server (NTRS)

Hartquist, T. W.; Dalgarno, A.; Oppenheimer, M.

1980-01-01

The chemistry of molecules in shocked regions of the interstellar gas is considered and calculations are carried out for a region subjected to a shock at a velocity of 8 km/sec. Substantial enhancements are predicted in the concentrations of the molecules H2S, SO, and SiO compared to those anticipated in cold interstellar clouds.

Molecular diagnostics of interstellar shocks

NASA Astrophysics Data System (ADS)

Hartquist, T. W.; Dalgarno, A.; Oppenheimer, M.

1980-02-01

The chemistry of molecules in shocked regions of the interstellar gas is considered and calculations are carried out for a region subjected to a shock at a velocity of 8 km/sec. Substantial enhancements are predicted in the concentrations of the molecules H2S, SO, and SiO compared to those anticipated in cold interstellar clouds.

Analysis of ultraviolet spectrophotometric data from Copernicus. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Snow, T.P. Jr

1979-04-17

Ultraviolet spectral data from the OAO 3 satellite are being used to study interstellar absorption lines and stellar and circumstellar lines in hot stars. The interstellar data are beneficial in analyzing the depletions of heavy elements from the gas phase and in elucidating how these depletions depend on physical conditions. Abundances in separate velocity components were determined from line profiles. Observations were carried out for interstellar abundances, both atomic and molecular, towards a number of stars. The better quality data are being analyzed for profile information and the lesser data are being used in curve-of-growth analyses. Molecular observations were carriedmore » out as well; N/sup 2/ was sought, interstellar C/sup 2/ was detected and its rotational excitation utilized to establish limits in interstellar cloud temperatures. An extensive search for H/sup 2/O resulted in a tentative identification which will produce new information on chemical reaction rates. Interstellar depletions and grain properties in the rho Ophiuchi cloud, stellar wind variability, and circumstellar lines are also under study.« less

Discovery of Molecular and Atomic Clouds Associated with the Magellanic Superbubble 30 Doradus C

NASA Astrophysics Data System (ADS)

Sano, H.; Yamane, Y.; Voisin, F.; Fujii, K.; Yoshiike, S.; Inaba, T.; Tsuge, K.; Babazaki, Y.; Mitsuishi, I.; Yang, R.; Aharonian, F.; Rowell, G.; Filipović, M. D.; Mizuno, N.; Tachihara, K.; Kawamura, A.; Onishi, T.; Fukui, Y.

2017-07-01

We analyzed the 2.6 mm CO and 21 cm H I lines toward the Magellanic superbubble 30 Doradus C, in order to reveal the associated molecular and atomic gas. We uncovered five molecular clouds in a velocity range from 251 to 276 km s-1 toward the western shell. The non-thermal X-rays are clearly enhanced around the molecular clouds on a parsec scale, suggesting possible evidence for magnetic field amplification via shock-cloud interaction. The thermal X-rays are brighter in the eastern shell, where there are no dense molecular or atomic clouds, opposite to the western shell. The TeV γ-ray distribution may spatially match the total interstellar proton column density as well as the non-thermal X-rays. If the hadronic γ-ray is dominant, the total energy of the cosmic-ray protons is at least ˜ 1.2× {10}50 erg with the estimated mean interstellar proton density ˜60 cm-3. In addition, the γ-ray flux associated with the molecular cloud (e.g., MC3) could be detected and resolved by the Cherenkov Telescope Array (CTA). This should permit CTA to probe the diffusion of cosmic-rays into the associated dense ISM.

On the Surface Formation of NH3 and HNCO in Dark Molecular Clouds - Searching for Wöhler Synthesis in the Interstellar Medium

NASA Astrophysics Data System (ADS)

Fedoseev, Gleb; Lamberts, Thanja; Linnartz, Harold; Ioppolo, Sergio; Zhao, Dongfeng

Despite its potential to reveal the link between the formation of simple species and more complex molecules (e.g., amino acids), the nitrogen chemistry of the interstellar medium (ISM) is still poorly understood. Ammonia (NH _{3}) is one of the few nitrogen-bearing species that have been observed in interstellar ices toward young stellar objects (YSOs) and quiescent molecular clouds. The aim of the present work is to experimentally investigate surface formation routes of NH _{3} and HNCO through non-energetic surface reactions in interstellar ice analogues under fully controlled laboratory conditions and at astrochemically relevant cryogenic temperatures. This study focuses on the formation of NH _{3} and HNCO in CO-rich (non-polar) interstellar ices that simulate the CO freeze-out stage in interstellar dark cloud regions, well before thermal and energetic processing start to become predominant. Our work confirms the surface formation of ammonia through the sequential addition of three hydrogen/deuterium atoms to a single nitrogen atom at low temperature. The H/D fractionation of the formed ammonia is also shown. Furthermore, we show the surface formation of solid HNCO through the interaction of CO molecules with NH radicals - one of the intermediates in the formation of solid NH _{3}. Finally, we discuss the implications of HNCO in astrobiology, as a possible starting point for the formation of more complex prebiotic species.

Molecular clouds in galaxies with different Z - Fragmentation of diffuse clouds driven by opacity

NASA Technical Reports Server (NTRS)

Franco, Jose; Cox, Donald P.

1986-01-01

Molecular clouds are formed from diffuse interstellar clouds when the external ultraviolet radiation field is prevented from penetrating into the cloud. The opacity is provided mainly by dust grains and the required column density to the cloud center is larger than about 5 x 10 to the 20th (solar Z/Z)/sq cm. This high-opacity criterion could have a significant impact on the radial trends observed in spiral galaxies, and on the distinctions between spiral and dwarf irregular galaxies.

Following the Interstellar History of Carbon: From the Interiors of Stars to the Surfaces of Planets.

PubMed

Ziurys, L M; Halfen, D T; Geppert, W; Aikawa, Y

2016-12-01

The chemical history of carbon is traced from its origin in stellar nucleosynthesis to its delivery to planet surfaces. The molecular carriers of this element are examined at each stage in the cycling of interstellar organic material and their eventual incorporation into solar system bodies. The connection between the various interstellar carbon reservoirs is also examined. Carbon has two stellar sources: supernova explosions and mass loss from evolved stars. In the latter case, the carbon is dredged up from the interior and then ejected into a circumstellar envelope, where a rich and unusual C-based chemistry occurs. This molecular material is eventually released into the general interstellar medium through planetary nebulae. It is first incorporated into diffuse clouds, where carbon is found in polyatomic molecules such as H 2 CO, HCN, HNC, c-C 3 H 2 , and even C 60 + . These objects then collapse into dense clouds, the sites of star and planet formation. Such clouds foster an active organic chemistry, producing compounds with a wide range of functional groups with both gas-phase and surface mechanisms. As stars and planets form, the chemical composition is altered by increasing stellar radiation, as well as possibly by reactions in the presolar nebula. Some molecular, carbon-rich material remains pristine, however, encapsulated in comets, meteorites, and interplanetary dust particles, and is delivered to planet surfaces. Key Words: Carbon isotopes-Prebiotic evolution-Interstellar molecules-Comets-Meteorites. Astrobiology 16, 997-1012.

Radioastronomical Searches for Instellar Biomolecules

NASA Technical Reports Server (NTRS)

Kuan, Y.-J.; Huang, H.-C.; Charnley, S. B.; Markwick, A.; Botta, O.; Ehrenfreund, P.; Kisiel, Z.; Butner, H. M.

2003-01-01

Impacts of comets and asteroids could have delivered large amounts of organic matter to the early Earth. to retain a significant interstellar signature; observations of recent bright comets indicate that they have a molecular inventory consistent with their ices being largely unmodified interstellar material. Many simple organic molecules with biochemical significance observed in circumstellar envelopes and in molecular clouds, similar to that from which the Solar System formed, may have acted as the precursors of the more complex organics found in meteorites. Therefore, there is potentially a strong link between interstellar organics and prebiotic chemical evolution. Radioastronomical observations, particularly at millimeter wavelengths, allow us to determine the chemical composition and characteristics of the molecular inventory in interstellar space. Here we report some of our recent results from extensive astronomical searches for astrobiologically-important interstellar organics.

The interstellar line spectra of zeta Ophiuchi and zeta Persei and their relation to the short wavelength microwave background radiation. Ph.D. Thesis - N. Y. Univ.

NASA Technical Reports Server (NTRS)

Bortolot, V. J., Jr.

1972-01-01

Thirty-one high dispersion Coude spectrograms of zeta Ophiuchi and seven of zeta Persei were numerically synthesized to produce high resolution, low noise spectra in the interval 3650 A to 4350 that yield data on atomic and molecular absorption in well-defined regions of the interstellar medium. The detection threshold is improved by as much as a factor 5 over single plates. Several interstellar lines were discovered in the zeta Oph - 15km/sec cloud and the zeta Per + 13 km/sec cloud.

From Interstellar Polycyclic Aromatic Hydrocarbons and Ice to the Origin of Life

NASA Technical Reports Server (NTRS)

Allamandola, Louis

2004-01-01

Tremendous strides have been made in our understanding of interstellar material over the past twenty years thanks to significant, parallel developments in observational astronomy and laboratory astrophysics. Twenty years ago the composition of interstellar dust was largely guessed at, the concept of ices in dense molecular clouds ignored, and the notion of large, abundant, gas phase, carbon rich molecules widespread throughout the interstellar medium (ISM) considered impossible. Today the composition of dust in the diffuse ISM is reasonably well constrained to cold refractory materials comprised of amorphous and crystalline silicates mixed with an amorphous carbonaceous material containing aromatic structural units and short, branched aliphatic chains. In the dense ISM, the birthplace of stars and planets, these cold dust particles are coated with mixed molecular ices whose composition is very well constrained. Lastly, the signature of carbon-rich polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by early interstellar chemistry standards, is widespread throughout the Universe. The first part of this talk will describe how infrared studies of interstellar space, combined with laboratory simulations, have revealed the composition of interstellar ices (the building blocks of comets) and the high abundance and nature of interstellar PAHs. The laboratory database has now enabled us to gain insight into the identities, abundances, and physical state of many interstellar materials. Within a dense molecular cloud, and especially in the presolar nebula, the materials frozen into the interstellar/precometary ices are photoprocessed by ultraviolet light and produce more complex molecules. The remainder of the presentation will focus on the photochemical evolution of these materials and the possible role of these compounds on the to the carbonaceous components of micrometeorites, they are likely to have been important sources of complex materials on the early Earth and their composition may be related to the origin of life.

The effect of catastrophic collisional fragmentation and diffuse medium accretion on a computational interstellar dust system

NASA Technical Reports Server (NTRS)

Liffman, Kurt

1990-01-01

The effects of catastrophic collisional fragmentation and diffuse medium accretion on a the interstellar dust system are computed using a Monte Carlo computer model. The Monte Carlo code has as its basis an analytic solution of the bulk chemical evolution of a two-phase interstellar medium, described by Liffman and Clayton (1989). The model is subjected to numerous different interstellar processes as it transfers from one interstellar phase to another. Collisional fragmentation was found to be the dominant physical process that shapes the size spectrum of interstellar dust. It was found that, in the diffuse cloud phase, 90 percent of the refractory material is locked up in the dust grains, primarily due to accretion in the molecular medium. This result is consistent with the observed depletions of silicon. Depletions were found to be affected only slightly by diffuse cloud accretion.

Astrophysics: Multi-Molecular Views of a Stellar Nursery

NASA Technical Reports Server (NTRS)

Wiseman, Jennifer; Sewilo, Marta

2017-01-01

New detectors for radio telescopes can map emissions from many different molecules simultaneously across interstellar clouds. One such pioneering study has probed a wide area of a star-forming cloud in the Orion constellation.

Astrophysics: Multi-molecular views of a stellar nursery

NASA Astrophysics Data System (ADS)

Wiseman, Jennifer; Sewilo, Marta

2017-06-01

New detectors for radio telescopes can map emissions from many different molecules simultaneously across interstellar clouds. One such pioneering study has probed a wide area of a star-forming cloud in the Orion constellation.

Interstellar C2, CH, and CN in translucent molecular clouds

NASA Technical Reports Server (NTRS)

Black, John H.; Van Dishoeck, Ewine F.

1989-01-01

Optical absorption-line techniques have been applied to the study of a number of translucent molecular clouds in which the total column densities are large enough that substantial molecular abundances can be maintained. Results are presented for a survey of absorption lines of interstellar C2, CH, and CN. Detections of CN through the A 2Pi-X 2Sigma(+) (1,O) and (2,O) bands of the red system are reported and compared with observations of the violet system for one line of sight. The population distributions in C2 provide diagnostic information on temperature and density. The measured column densities of the three species can be used to test details of the theory of molecule formation in clouds where photoprocesses still play a significant role. The C2 and CH column densities are strongly correlated with each other and probably also with the H2 column density. In contrast, the CN column densities are found to vary greatly from cloud to cloud. The observations are discussed with reference to detailed theoretical models.

HD 62542: Probing the Bare, Dense Core of an Interstellar Cloud

NASA Astrophysics Data System (ADS)

Welty, Daniel; Sonnentrucker, Paule G.; Rachford, Brian; Snow, Theodore; York, Donald G.

2018-01-01

We discuss the interstellar absorption from many atomic and molecular species seen in high-resolution HST/STIS UV spectra of the moderately reddened B3-5 V star HD 62542 [E(B-V) ~ 0.35; AV ~ 1.2]. This remarkable sight line exhibits both very steep far-UV extinction and a high fraction of hydrogen in molecular form -- with strong absorption from CH, C2, CN, and CO but weak absorption from CH+ and most of the commonly observed diffuse interstellar bands. Most of the material appears to reside in a single narrow velocity component -- thus offering a rare opportunity to probe the relatively dense, primarily molecular core of a single interstellar cloud, with little associated diffuse atomic gas.Detailed analyses of the absorption-line profiles seen in the UV spectra reveal a number of properties of the main diffuse molecular cloud toward HD 62542:1) The depletions of Mg, Si, and Fe are more severe than those seen in any other sight line, but the depletions of Cl and Kr are very mild; the overall pattern of depletions differs somewhat from those derived from larger samples of Galactic sight lines.2) The rotational excitation of H2 and C2 indicates that the gas is fairly cold (Tk = 40-45 K) and moderately dense (nH > 420 cm-3) somewhat higher densities are suggested by the fine-structure excitation of neutral carbon.3) The excitation temperatures characterizing the rotational populations of both 12CO (11.7 K) and 13CO (7.7 K) are higher than those typically found for Galactic diffuse molecular clouds.4) Carbon is primarily singly ionized -- N(C+) > N(CO) > N(C).5) The relative abundances of various trace neutral atomic species reflect the effects of both the steep far-UV extinction and the severe depletions of some elements.6) Differences in line widths for the various atomic and molecular species are suggestive of differences in spatial distribution within the main cloud.Support for this study was provided by NASA, via STScI grant GO-12277.008-A.

Theoretical Modeling of Interstellar Chemistry

NASA Technical Reports Server (NTRS)

Charnley, Steven

2009-01-01

The chemistry of complex interstellar organic molecules will be described. Gas phase processes that may build large carbon-chain species in cold molecular clouds will be summarized. Catalytic reactions on grain surfaces can lead to a large variety of organic species, and models of molecule formation by atom additions to multiply-bonded molecules will be presented. The subsequent desorption of these mixed molecular ices can initiate a distinctive organic chemistry in hot molecular cores. The general ion-molecule pathways leading to even larger organics will be outlined. The predictions of this theory will be compared with observations to show how possible organic formation pathways in the interstellar medium may be constrained. In particular, the success of the theory in explaining trends in the known interstellar organics, in predicting recently-detected interstellar molecules, and, just as importantly, non-detections, will be discussed.

Dust evolution, a global view I. Nanoparticles, nascence, nitrogen and natural selection … joining the dots

NASA Astrophysics Data System (ADS)

Jones, A. P.

2016-12-01

The role and importance of nanoparticles for interstellar chemistry and beyond is explored within the framework of The Heterogeneous dust Evolution Model for Interstellar Solids (THEMIS), focusing on their active surface chemistry, the effects of nitrogen doping and the natural selection of interesting nanoparticle sub-structures. Nanoparticle-driven chemistry, and in particular the role of intrinsic epoxide-type structures, could provide a viable route to the observed gas phase OH in tenuous interstellar clouds en route to becoming molecular clouds. The aromatic-rich moieties present in asphaltenes probably provide a viable model for the structures present within aromatic-rich interstellar carbonaceous grains. The observed doping of such nanoparticle structures with nitrogen, if also prevalent in interstellar dust, could perhaps have important and observable consequences for surface chemistry and the formation of precursor pre-biotic species.

Putting a Ring on it: Light Echoes from X-ray Transients as Probes of Interstellar Dust and Galactic Structure

NASA Astrophysics Data System (ADS)

Heinz, Sebastian

2017-09-01

When an X-ray transient exhibits a bright flare, scattering by interstellar dust clouds can give rise to a light echo in the form of concentric rings. To date, three such echoes have been detected, each leading to significant discoveries and press attention. We propose a Target-of-Opportunity campaign to observe future echoes with the aim to follow the temporal evolution of the echo in order to (a) map the 3D distribution interstellar dust along the line of sight to parsec accuracy, (b) constrain the composition and grain size distribution of ISM dust in each of the clouds towards the source, (c) measure the distance to the X-ray source, (d) constrain the velocity dispersion of molecular clouds and (e) search for evidence of streaming velocities by combing X-ray and CO data on the clouds.

The astrochemistry of H+3

NASA Astrophysics Data System (ADS)

Herbst, E.

2000-09-01

The reactions of the molecular ion H3+ are pivotal to the chemistry of dense interstellar clouds. Produced by the cosmic-ray ionizati on of molecular hydrogen, H3+ reacts with a variety of a toms and molecules to produce species that are precursors to many of the detect ed molecules in dense clouds. For example, the reaction of H3+ with atomic O leads, eventually, to the production of water, while the re action with HD leads to the production of a wide variety of deuterated isotopom ers. In this article, the chemistry of H3+ and the produc ts derived from it are discussed in the larger context of interstellar chemistr y.

ON THE INTERACTION OF ADENINE WITH IONIZING RADIATION: MECHANISTICAL STUDIES AND ASTROBIOLOGICAL IMPLICATIONS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Evans, Nicholas L.; Ullrich, Susanne; Bennett, Chris J.

2011-04-01

The molecular inventory available on the prebiotic Earth was likely derived from both terrestrial and extraterrestrial sources. A complete description of which extraterrestrial molecules may have seeded early Earth is therefore necessary to fully understand the prebiotic evolution which led to life. Galactic cosmic rays (GCRs) are expected to cause both the formation and destruction of important biomolecules-including nucleic acid bases such as adenine-in the interstellar medium within the ices condensed on interstellar grains. The interstellar ultraviolet (UV) component is expected to photochemically degrade gas-phase adenine on a short timescale of only several years. However, the destruction rate is expectedmore » to be significantly reduced when adenine is shielded in dense molecular clouds or even within the ices of interstellar grains. Here, biomolecule destruction by the energetic charged particle component of the GCR becomes important as it is not fully attenuated. Presented here are results on the destruction rate of the nucleobase adenine in the solid state at 10 K by energetic electrons, as generated in the track of cosmic ray particles as they penetrate ices. When both UV and energetic charged particle destructive processes are taken into account, the half-life of adenine within dense interstellar clouds is found to be {approx}6 Myr, which is on the order of a star-forming molecular cloud. We also discuss chemical reaction pathways within the ices to explain the production of observed species, including the formation of nitriles (R-C{identical_to}N), epoxides (C-O-C), and carbonyl functions (R-C=O).« less

Large Interstellar Polarisation Survey. II. UV/optical study of cloud-to-cloud variations of dust in the diffuse ISM

NASA Astrophysics Data System (ADS)

Siebenmorgen, R.; Voshchinnikov, N. V.; Bagnulo, S.; Cox, N. L. J.; Cami, J.; Peest, C.

2018-03-01

It is well known that the dust properties of the diffuse interstellar medium exhibit variations towards different sight-lines on a large scale. We have investigated the variability of the dust characteristics on a small scale, and from cloud-to-cloud. We use low-resolution spectro-polarimetric data obtained in the context of the Large Interstellar Polarisation Survey (LIPS) towards 59 sight-lines in the Southern Hemisphere, and we fit these data using a dust model composed of silicate and carbon particles with sizes from the molecular to the sub-micrometre domain. Large (≥6 nm) silicates of prolate shape account for the observed polarisation. For 32 sight-lines we complement our data set with UVES archive high-resolution spectra, which enable us to establish the presence of single-cloud or multiple-clouds towards individual sight-lines. We find that the majority of these 35 sight-lines intersect two or more clouds, while eight of them are dominated by a single absorbing cloud. We confirm several correlations between extinction and parameters of the Serkowski law with dust parameters, but we also find previously undetected correlations between these parameters that are valid only in single-cloud sight-lines. We find that interstellar polarisation from multiple-clouds is smaller than from single-cloud sight-lines, showing that the presence of a second or more clouds depolarises the incoming radiation. We find large variations of the dust characteristics from cloud-to-cloud. However, when we average a sufficiently large number of clouds in single-cloud or multiple-cloud sight-lines, we always retrieve similar mean dust parameters. The typical dust abundances of the single-cloud cases are [C]/[H] = 92 ppm and [Si]/[H] = 20 ppm.

Interstellar organic chemistry.

NASA Technical Reports Server (NTRS)

Sagan, C.

1972-01-01

Most of the interstellar organic molecules have been found in the large radio source Sagittarius B2 toward the galactic center, and in such regions as W51 and the IR source in the Orion nebula. Questions of the reliability of molecular identifications are discussed together with aspects of organic synthesis in condensing clouds, degradational origin, synthesis on grains, UV natural selection, interstellar biology, and contributions to planetary biology.

Search for molecular absorptions with the Fourier Transform Spectrometer

NASA Technical Reports Server (NTRS)

Knacke, Roger F.

1995-01-01

The objective of this research was a search for water molecules in the gas phase in molecular clouds. Water should be among the most abundant gases in the clouds and is of fundamental importance in gas chemistry, cloud cooling, shock wave chemistry, and gas-grain interactions of interstellar dust. Detection of water in Comet Halley in the 2.7 micron v(3) band in 1986 had shown that airborne H2O observations are feasible (ground-based observations of H2O are impossible because of the massive water content of the atmosphere). We planned to observe the v(3) band in interstellar clouds where a number of lines of this band should be in absorption. The search for H2O commenced in 1988 with a two flight program on the KAO. this resulted in a detection of interstellar H2O with S/N of 2-4 in the v(3) 1(01)-2(02) line at 3801.42/cm. A subsequent flight series of two flights in 1989 resulted in confirmation to the 3801.42/cm line detection and the detection of altogether four strong lines in the 000-001 v(3) vibration-rotation band of H2O.

Grain Surface Chemistry and the Composition of Interstellar Ices

NASA Technical Reports Server (NTRS)

Tielens, A. G. G. M.

2006-01-01

Submicron sized dust grains are an important component of the interstellar medium. In particular they provide surface where active chemistry can take place. At the low temperatures (-10 K) of the interstellar medium, colliding gas phase species will stick, diffuse, react, and form an icy mantle on these dust grains. This talk will review the principles of grain surface chemistry and delineate important grain surface routes, focusing on reactions involving H, D, and O among each other and with molecules such as CO. Interstellar ice mantles can be studied through the fundamental vibrations of molecular species in the mid-infrared spectra of sources embedded in or located behind dense molecular clouds. Analysis of this type of data has provided a complex view of the composition of these ices and the processes involved. Specifically, besides grain surface chemistry, the composition of interstellar ices is also affected by thermal processing due to nearby newly formed stars. This leads to segregation between different ice components as well as outgassing. The latter results in the formation of a so-called Hot Core region with a gas phase composition dominated by evaporated mantle species. Studies of such regions provide thus a different view on the ice composition and the chemical processes involved. Interstellar ices can also be processed by FUV photons and high energy cosmic ray ions. Cosmic ray processing likely dominates the return of accreted species to the gas phase where further gas phase reactions can take place. These different chemical routes towards molecular complexity in molecular clouds and particularly regions of star formation will be discussed.

Summer School on Interstellar Processes: Abstracts of contributed papers

NASA Technical Reports Server (NTRS)

Hollenbach, D. J. (Editor); Thronson, H. A., Jr. (Editor)

1986-01-01

The Summer School on Interstellar Processes was held to discuss the current understanding of the interstellar medium and to analyze the basic physical processes underlying interstellar phenomena. Extended abstracts of the contributed papers given at the meeting are presented. Many of the papers concerned the local structure and kinematics of the interstellar medium and focused on such objects as star formation regions, molecular clouds, HII regions, reflection nebulae, planetary nebulae, supernova remnants, and shock waves. Other papers studied the galactic-scale structure of the interstellar medium either in the Milky Way or other galaxies. Some emphasis was given to observations of interstellar grains and

Water in dense molecular clouds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wannier, P.G.; Kuiper, T.B.H.; Frerking, M.A.

1991-08-01

The G.P. Kuiper Airborne Observatory (KAO) was used to make initial observations of the half-millimeter ground-state transition of water in seven giant molecular clouds and in two late-type stars. No significant detections were made, and the resulting upper limits are significantly below those expected from other, indirect observations and from several theoretical models. The implied interstellar H2O/CO abundance is less than 0.003 in the cores of three giant molecular clouds. This value is less than expected from cloud chemistry models and also than estimates based on HDO and H3O(+) observations. 78 refs.

CaFe interstellar clouds

NASA Astrophysics Data System (ADS)

Bondar, A.; Kozak, M.; Gnaciński, P.; Galazutdinov, G. A.; Beletsky, Y.; Krełowski, J.

2007-07-01

A new kind of interstellar cloud is proposed. These are rare (just a few examples among ~300 lines of sight) objects with the CaI 4227-Å, FeI 3720-Å and 3860-Å lines stronger than those of KI (near 7699 Å) and NaI (near 3302 Å). We propose the name `CaFe' for these clouds. Apparently they occupy different volumes from the well-known interstellar HI clouds where the KI and ultraviolet NaI lines are dominant features. In the CaFe clouds we have not found either detectable molecular features (CH, CN) or diffuse interstellar bands which, as commonly believed, are carried by some complex, organic molecules. We have found the CaFe clouds only along sightlines toward hot, luminous (and thus distant) objects with high rates of mass loss. In principle, the observed gas-phase interstellar abundances reflect the combined effects of the nucleosynthetic history of the material, the depletion of heavy elements into dust grains and the ionization state of these elements which may depend on irradiation by neighbouring stars. Based on data collected using the Maestro spectrograph at the Terskol 2-m telescope, Russia; and on data collected using the ESO Feros spectrograph; and on data obtained from the ESO Science Archive Facility acquired with the UVES spectrograph, Chile. E-mail: `arctur'@rambler.ru (AB); marizak@astri.uni.torun.pl (MK); pg@iftia.univ.gda.pl (PG); gala@boao.re.kr (GAG); ybialets@eso.org (YB); jacek@astri.uni.torun.pl (JK)

Metastability of isoformyl ions in collisions with helium and hydrogen. [in interstellar molecular clouds

NASA Technical Reports Server (NTRS)

Green, S.

1984-01-01

The stability of HOC(+) ions under conditions in interstellar molecular clouds is considered. In particular, the possibility that collisions with helium or hydrogen will induce isomerization to the stable HCO(+) form is examined theoretically. Portions of the electronic potential energy surfaces for interaction with He and H atoms are obtained from standard quantum mechanical calculations. Collisions with He atoms are found to be totally ineffective for inducing isomerization. Collisions with H atoms are found to be ineffective at low interstellar temperatures owing to a small (about 500 K) barrier in the entrance channel; at higher temperatures where this barrier can be overcome, however, collisions with hydrogen atoms do result in conversion to the stable HCO(+) form. Although detailed calculations are not presented, it is argued that low-energy collisions with H2 molecules are also ineffective in destroying the metastable ion.

Organic Synthesis in Simulated Interstellar Ice Analogs

NASA Technical Reports Server (NTRS)

Dworkin, Jason P.; Bernstein, Max P.; Sandford, Scott A.; Allamandola, Louis J.; Deamer, David W.; Elsila, Jamie; Zare, Richard N.; DeVincenzi, Donald (Technical Monitor)

2001-01-01

Comets and carbonaceous micrometeorites may have been significant sources of organic compounds on the early Earth. Ices on grains in interstellar dense molecular clouds contain a variety of simple molecules as well as aromatic molecules of various sizes. While in these clouds the icy grains are processed by ultraviolet light and cosmic radiation which produces more complex organic molecules. ID We have run laboratory simulations to identify the types of molecules which could have been generated photolytically in pre-cometary ices. Experiments were conducted by forming various realistic interstellar mixed-molecular ices with and without polycyclic aromatic hydrocarbons (PAHs) at approx. 10 K under high vacuum irradiated with LTV light from a hydrogen plasma lamp: The residue that remained after warming to room temperature was analyzed by HPLC, and by laser desorption mass spectrometry. The residue contains several classes of compounds which may be of prebiotic significance.

Organic Synthesis in Simulated Interstellar Ice Analogs

NASA Technical Reports Server (NTRS)

Dworkin, Jason P.; Bernstein, Max P.; Sandford, Scott A.; Allamandola, Louis J.; Deamer, David W.; Elsila, Jamie; Zare, Richard N.

2001-01-01

Comets and carbonaceous micrometeorites may have been significant sources of organic compounds on the early Earth. Ices on grains in interstellar dense molecular clouds contain a variety of simple molecules as well as aromatic molecules of various sizes. While in these clouds the icy grains are processed by ultraviolet light and cosmic radiation which produces more complex organic molecules. We have run laboratory simulations to identify the types of molecules which could have been generated photolytically in pre-cometary ices. Experiments were conducted by forming various realistic interstellar mixed-molecular ices with and without polycyclic aromatic hydrocarbons (PAHs) at approx. 10 K under high vacuum irradiated with UV light from a hydrogen plasma lamp. The residue that remained after warming to room temperature was analyzed by HPLC, and by laser desorption mass spectrometry. The residue contains several classes of compounds which may be of prebiotic significance.

Spitzer Observations of Dust Destruction in the Puppis A Supernova Remnant

NASA Technical Reports Server (NTRS)

Arendt, Richard G.; Dweek, Eli; Blair, William P.; Ghavamian, Parviz; Hwang, Una; Long, Knox X.; Petre, Robert; Rho, Jeonghee; Winkler, P. Frank

2010-01-01

The interaction of the Puppis A supernova remnant (SNR) with a neighboring molecular cloud provides a unique opportunity to measure the amount of grain destruction in an SNR shock. Spitzer Space Telescope MIPS imaging of the entire SNR at 24, 70, and 160 micrometers shows an extremely good correlation with X-ray emission, indicating that the SNR's IR radiation is dominated by the thermal emission of swept-up interstellar dust, collisionally heated by the hot shocked gas. Spitzer IRS spectral observations targeted both the Bright Eastern Knot (BEK) of the SNR where a small cloud has been engulfed by the supernova blast wave and outlying portions of the associated molecular cloud that are yet to be hit by the shock front. Modeling the spectra from both regions reveals the composition and the grain size distribution of the interstellar dust, both in front of and behind the SNR shock front. The comparison shows that the ubiquitous polycyclic aromatic hydrocarbons of the interstellar medium are destroyed within the BEK, along with nearly 25% of the mass of graphite and silicate dust grains.

Interstellar grain chemistry and organic molecules

NASA Technical Reports Server (NTRS)

Allamandola, L. J.; Sandford, S. A.

1990-01-01

The detection of prominant infrared absorption bands at 3250, 2170, 2138, 1670 and 1470 cm(-1) (3.08, 4.61, 4.677, 5.99 and 6.80 micron m) associated with molecular clouds show that mixed molecular (icy) grain mantles are an important component of the interstellar dust in the dense interstellar medium. These ices, which contain many organic molecules, may also be the production site of the more complex organic grain mantles detected in the diffuse interstellar medium. Theoretical calculations employing gas phase as well as grain surface reactions predict that the ices should be dominated only by the simple molecules H2O, H2CO, N2, CO, O2, NH3, CH4, possibly CH3OH, and their deuterated counterparts. However, spectroscopic observations in the 2500 to 1250 cm(-1)(4 to 8 micron m) range show substantial variation from source reactions alone. By comparing these astronomical spectra with the spectra of laboratory-produced analogs of interstellar ices, one can determine the composition and abundance of the materials frozen on the grains in dense clouds. Experiments are described in which the chemical evolution of an interstellar ice analog is determined during irradiation and subsequent warm-up. Particular attention is paid to the types of moderately complex organic materials produced during these experiments which are likely to be present in interstellar grains and cometary ices.

H2CS abundances and ortho-to-para ratios in interstellar clouds

NASA Technical Reports Server (NTRS)

Minh, Y. C.; Irvine, W. M.; Brewer, M. K.

1991-01-01

Several H2CS ortho and para transitions have been observed toward interstellar molecular clouds, including cold, dark clouds and star-forming regions. H2CS fractional abundances f(H2CS) about 1-2 10 to the -9th relative to molecular hydrogen toward TMC-1, Orion A, and NGC 7538, and about 5 10 to the -10th for L134N are derived. The H2CS ortho-to-para ratios in TMC-1 are about 1.8 toward the cyanopolyyne peak and the ammonia peak, which may indicate the thermalization of H2CS on 10 K grains. A ratio of about 3, the statistical value, for Orion (3N, 1E) and NGC 7538 is derived, while a value of about 2 for Orion (KL) is found.

Submillimeter heterodyne detection of interstellar carbon monoxide at 434 micrometers

NASA Technical Reports Server (NTRS)

Fetterman, H. R.; Clifton, B. J.; Peck, D. D.; Tannenwald, P. E.; Koepf, G. A.; Goldsmith, P. F.; Erickson, N. R.; Buhl, D.; Mcavoy, N.

1981-01-01

Laser heterodyne observations of submillimeter emissions from carbon monoxide in the Orion molecular cloud are reported. High frequency and spatial resolution observations were made at the NASA Infrared Telescope Facility on Mauna Kea by the use of an optically pumped laser local oscillator and quasi-optical Schottky diode mixer for heterodyne detection of the J = 6 - 5 rotational transition of CO at 434 microns. Spectral analysis of the 434-micron emission indicates that the emitting gas is optically thin and is at a temperature above 180 K. Results thus demonstrate the potential contributions of ground-based high-resolution submillimeter astronomy to the study of active regions in interstellar molecular clouds.

Toward Measuring Galactic Dense Molecular Gas Properties and 3D Distribution with Hi-GAL

NASA Astrophysics Data System (ADS)

Zetterlund, Erika; Glenn, Jason; Maloney, Phil

2016-01-01

The Herschel Space Observatory's submillimeter dust continuum survey Hi-GAL provides a powerful new dataset for characterizing the structure of the dense interstellar medium of the Milky Way. Hi-GAL observed a 2° wide strip covering the entire 360° of the Galactic plane in broad bands centered at 70, 160, 250, 350, and 500 μm, with angular resolution ranging from 10 to 40 arcseconds. We are adapting a molecular cloud clump-finding algorithm and a distance probability density function distance-determination method developed for the Bolocam Galactic Plane Survey (BGPS) to the Hi-GAL data. Using these methods we expect to generate a database of 105 cloud clumps, derive distance information for roughly half the clumps, and derive precise distances for approximately 20% of them. With five-color photometry and distances, we will measure the cloud clump properties, such as luminosities, physical sizes, and masses, and construct a three-dimensional map of the Milky Way's dense molecular gas distribution.The cloud clump properties and the dense gas distribution will provide critical ground truths for comparison to theoretical models of molecular cloud structure formation and galaxy evolution models that seek to emulate spiral galaxies. For example, such models cannot resolve star formation and use prescriptive recipes, such as converting a fixed fraction of interstellar gas to stars at a specified interstellar medium density threshold. The models should be compared to observed dense molecular gas properties and galactic distributions.As a pilot survey to refine the clump-finding and distance measurement algorithms developed for BGPS, we have identified molecular cloud clumps in six 2° × 2° patches of the Galactic plane, including one in the inner Galaxy along the line of sight through the Molecular Ring and the termination of the Galactic bar and one toward the outer Galaxy. Distances have been derived for the inner Galaxy clumps and compared to Bolocam Galactic Plane Survey results. We present the pilot survey clump catalog, distances, clump properties, and a comparison to BGPS.

The abundance of CO in diffuse interstellar clouds - An ultraviolet survey

NASA Technical Reports Server (NTRS)

Federman, S. R.; Glassgold, A. E.; Jenkins, E. B.; Shaya, E. J.

1980-01-01

CO was detected in 17 directions and its upper limits were estimated in 21 directions by a UV survey carried out with the Copernicus satellite in the C-X 1088 A and E-X 1076 A lines toward 48 bright stars. The CO column densities range from 10 to the 12th to 10 to the 17th/sq cm and correlate with C I and H2. The tendency of the C I/CO ratio to be about 10 follows the ratio of particular atomic and molecular cross-sections and the physical parameters of interstellar clouds. Finally, the connection between UV observations in diffuse clouds and radio observations of (C-13)O in dark clouds is discussed.

Simulation of optical interstellar scintillation

NASA Astrophysics Data System (ADS)

Habibi, F.; Moniez, M.; Ansari, R.; Rahvar, S.

2013-04-01

Aims: Stars twinkle because their light propagates through the atmosphere. The same phenomenon is expected on a longer time scale when the light of remote stars crosses an interstellar turbulent molecular cloud, but it has never been observed at optical wavelengths. The aim of the study described in this paper is to fully simulate the scintillation process, starting from the molecular cloud description as a fractal object, ending with the simulations of fluctuating stellar light curves. Methods: Fast Fourier transforms are first used to simulate fractal clouds. Then, the illumination pattern resulting from the crossing of background star light through these refractive clouds is calculated from a Fresnel integral that also uses fast Fourier transform techniques. Regularisation procedure and computing limitations are discussed, along with the effect of spatial and temporal coherency (source size and wavelength passband). Results: We quantify the expected modulation index of stellar light curves as a function of the turbulence strength - characterised by the diffraction radius Rdiff - and the projected source size, introduce the timing aspects, and establish connections between the light curve observables and the refractive cloud. We extend our discussion to clouds with different structure functions from Kolmogorov-type turbulence. Conclusions: Our study confirms that current telescopes of ~4 m with fast-readout, wide-field detectors have the capability of discovering the first interstellar optical scintillation effects. We also show that this effect should be unambiguously distinguished from any other type of variability through the observation of desynchronised light curves, simultaneously measured by two distant telescopes.

Low-energy electron-induced chemistry of condensed methanol: implications for the interstellar synthesis of prebiotic molecules.

PubMed

Boamah, Mavis D; Sullivan, Kristal K; Shulenberger, Katie E; Soe, ChanMyae M; Jacob, Lisa M; Yhee, Farrah C; Atkinson, Karen E; Boyer, Michael C; Haines, David R; Arumainayagam, Christopher R

2014-01-01

In the interstellar medium, UV photolysis of condensed methanol (CH3OH), contained in ice mantles surrounding dust grains, is thought to be the mechanism that drives the formation of "complex" molecules, such as methyl formate (HCOOCH3), dimethyl ether (CH3OCH3), acetic acid (CH3COOH), and glycolaldehyde (HOCH2CHO). The source of this reaction-initiating UV light is assumed to be local because externally sourced UV radiation cannot penetrate the ice-containing dark, dense molecular clouds. Specifically, exceedingly penetrative high-energy cosmic rays generate secondary electrons within the clouds through molecular ionizations. Hydrogen molecules, present within these dense molecular clouds, are excited in collisions with these secondary electrons. It is the UV light, emitted by these electronically excited hydrogen molecules, that is generally thought to photoprocess interstellar icy grain mantles to generate "complex" molecules. In addition to producing UV light, the large numbers of low-energy (< 20 eV) secondary electrons, produced by cosmic rays, can also directly initiate radiolysis reactions in the condensed phase. The goal of our studies is to understand the low-energy, electron-induced processes that occur when high-energy cosmic rays interact with interstellar ices, in which methanol, a precursor of several prebiotic species, is the most abundant organic species. Using post-irradiation temperature-programmed desorption, we have investigated the radiolysis initiated by low-energy (7 eV and 20 eV) electrons in condensed methanol at - 85 K under ultrahigh vacuum (5 x 10(-10) Torr) conditions. We have identified eleven electron-induced methanol radiolysis products, which include many that have been previously identified as being formed by methanol UV photolysis in the interstellar medium. These experimental results suggest that low-energy, electron-induced condensed phase reactions may contribute to the interstellar synthesis of "complex" molecules previously thought to form exclusively via UV photons.

Theoretical studies of the extraterrestrial chemistry of biogenic elements and compounds

NASA Technical Reports Server (NTRS)

Defrees, D. J.

1991-01-01

Organic compounds, molecules related to those in living systems, are found in many different extraterrestrial environments. The study of organic astrochemistry is important to exobiology both because it demonstrates the ubiquity of processes which led to life on Earth and because the dust clouds where molecules are found are analogs of the solar nebula from which the Earth formed. In the long chain of events leading from the Big Bang, and a universe composed of atomic hydrogen and helium, to the emergence of life on Earth, molecular interstellar clouds are an early link, the most primitive objects which display any significant organic chemistry. One such cloud was the direct precursor to the solar system and to all objects which it contains. Theoretical methods are ideally suited to studying interstellar cloud chemistry. They have been applied to determine spectroscopic constants of candidate interstellar molecules, mechanisms of ion-molecule reactions, and composition of dust grains. Accurate predictions of rotational constants and dipole moments of long-chain carbon molecules HC13N, HC15N, and C5O have been made to aid in determining the size limit of gas-phase interstellar molecules. Models of gas-phase interstellar chemistry use reaction rate constants measured at room temperature and extrapolated to interstellar temperatures. The temperature dependence of NH3(+)+H2 yields NH4(+)+H is anomalous, however, with a minimum rate at about 100K, casting doubt on the extrapolation procedures. The temperature dependence has now been explained.

Interferometric observations of large biologically interesting interstellar and cometary molecules

PubMed Central

Snyder, Lewis E.

2006-01-01

Interferometric observations of high-mass regions in interstellar molecular clouds have revealed hot molecular cores that have substantial column densities of large, partly hydrogen-saturated molecules. Many of these molecules are of interest to biology and thus are labeled “biomolecules.” Because the clouds containing these molecules provide the material for star formation, they may provide insight into presolar nebular chemistry, and the biomolecules may provide information about the potential of the associated interstellar chemistry for seeding newly formed planets with prebiotic organic chemistry. In this overview, events are outlined that led to the current interferometric array observations. Clues that connect this interstellar hot core chemistry to the solar system can be found in the cometary detection of methyl formate and the interferometric maps of cometary methanol. Major obstacles to understanding hot core chemistry remain because chemical models are not well developed and interferometric observations have not been very sensitive. Differentiation in the molecular isomers glycolaldehdye, methyl formate, and acetic acid has been observed, but not explained. The extended source structure for certain sugars, aldehydes, and alcohols may require nonthermal formation mechanisms such as shock heating of grains. Major advances in understanding the formation chemistry of hot core species can come from observations with the next generation of sensitive, high-resolution arrays. PMID:16894168

The peculiar behaviour of the 5780 and 5797 DIBs in HD25137

NASA Technical Reports Server (NTRS)

Porceddu, Ignazio; Benvenuti, P.

1994-01-01

The interstellar environment close to the high latitude molecular cloud Lynds 1569 (L1569, Lynds 1962), also known as MBM 18 (Magnani, Blitz and Mundy, 1985), has been analyzed by Penrase et al. (1990) and Penrase (1993). Their observations of the CH, CH(sup+), and CN molecular features, are consistent with a region having a high molecular and reduced dust content. They also observed the background star HD 24263- located 8 degrees far from the center of L1569 - reporting a CH rich line of sight and the presence of two intervening clouds from a sodium lines spectra. The infrared excess which has been revealed by the IRAS survey at 12 microns might suggest the presence of PAH's molecules, the well know candidate for the Unidentified Infrared Bands and Diffuse Interstellar Bands. This interesting scenario led to the investigation of the behavior of the diffuse interstellar bands toward HD 25137, which is supposed to be a background object for L1569 (Penrase et al., 1990); as well as the field star HD 24263. As part of a wider observational program devoted to study the HLC's special environments, the observations of the diffuse interstellar bands (DIB's) at 5780 and 5797 lambda lambda in the direction of the two above mentioned stars, HD 24263 and HD 25137 are presented here.

Interstellar and Cometary Dust

NASA Technical Reports Server (NTRS)

Mathis, John S.

1997-01-01

'Interstellar dust' forms a continuum of materials with differing properties which I divide into three classes on the basis of observations: (a) diffuse dust, in the low-density interstellar medium; (b) outer-cloud dust, observed in stars close enough to the outer edges of molecular clouds to be observed in the optical and ultraviolet regions of the spectrum, and (c) inner-cloud dust, deep within the cores of molecular clouds, and observed only in the infrared by means of absorption bands of C-H, C=O, 0-H, C(triple bond)N, etc. There is a surprising regularity of the extinction laws between diffuse- and outer-cloud dust. The entire mean extinction law from infrared through the observable ultraviolet spectrum can be characterized by a single parameter. There are real deviations from this mean law, larger than observational uncertainties, but they are much smaller than differences of the mean laws in diffuse- and outer-cloud dust. This fact shows that there are processes which operate over the entire distribution of grain sizes, and which change size distributions extremely efficiently. There is no evidence for mantles on grains in local diffuse and outer-cloud dust. The only published spectra of the star VI Cyg 12, the best candidate for showing mantles, does not show the 3.4 micro-m band which appreciable mantles would produce. Grains are larger in outer-cloud dust than diffuse dust because of coagulation, not accretion of extensive mantles. Core-mantle grains favored by J. M. Greenberg and collaborators, and composite grains of Mathis and Whiffen (1989), are discussed more extensively (naturally, I prefer the latter). The composite grains are fluffy and consist of silicates, amorphous carbon, and some graphite in the same grain. Grains deep within molecular clouds but before any processing within the solar system are presumably formed from the accretion of icy mantles on and within the coagulated outer-cloud grains. They should contain a mineral/carbonaceous matrix, without organic refractory mantles, in between the ices. Unfortunately, they may be significantly processed by chemical processes accompanying the warming (over the 10 K of the dark cloud cores) which occurs in the outer solar system. Evidence of this processing is the chemical anomalies present in interplanetary dust particles collected in the stratosphere, which may be the most primitive materials we have obtained to date. The comet return mission would greatly clarify the situation, and probably provide samples of genuine interstellar grains.

Cosmic-ray ionisation of dense molecular clouds

NASA Astrophysics Data System (ADS)

Vaupre, Solenn

2015-07-01

Cosmic rays (CR) are of tremendous importance in the dynamical and chemical evolution of interstellar molecular clouds, where stars and planets form. CRs are likely accelerated in the shells of supernova remnants (SNR), thus molecular clouds nearby can be irradiated by intense fluxes of CRs. CR protons have two major effects on dense molecular clouds: 1) when they encounter the dense medium, high-energy protons (>280 MeV) create pions that decay into gamma-rays. This process makes SNR-molecular cloud associations intense GeV and/or TeV sources whose spectra mimic the CR spectrum. 2) at lower energies, CRs penetrate the cloud and ionise the gas, leading to the formation of molecular species characteristic of the presence of CRs, called tracers of the ionisation. Studying these tracers gives information on low-energy CRs that are unaccessible to any other observations. I studied the CR ionisation of molecular clouds next to three SNRs: W28, W51C and W44. These SNRs are known to be interacting with the nearby clouds, from the presence of shocked gas, OH masers and pion-decay induced gamma-ray emission. My work includes millimeter observations and chemical modeling of tracers of the ionisation in these dense molecular clouds. In these three regions, we determined an enhanced CR ionisation rate, supporting the hypothesis of an origin of the CRs in the SNR nearby. The evolution of the CR ionisation rate with the distance to the SNR brings valuable constraints on the propagation properties of low-energy CRs. The method used relies on observations of the molecular ions HCO+ and DCO+, which shows crucial limitations at high ionisation. Therefore, I investigated, both through modeling and observations, the chemical abundances of several other species to try and identity alternative tracers of the ionisation. In particular, in the W44 region, observations of N2H+ bring additional constraints on the physical conditions, volatile abundances in the cloud, and the ionisation state. This research brought valuable insight in to the CR induced chemistry in the interstellar medium. It also brought new perspectives of interdisciplinary research towards the understanding of CRs, from millimeter to gamma-ray observations.

Molecular Diagnostics of the Interstellar Medium and Star Forming Regions

NASA Astrophysics Data System (ADS)

Hartquist, T. W.; Dalgarno, A.

1996-03-01

Selected examples of the use of observationally inferred molecular level populations and chemical compositions in the diagnosis of interstellar sources and processes important in them (and in other diffuse astrophysical sources) are given. The sources considered include the interclump medium of a giant molecular cloud, dark cores which are the progenitors of star formation, material responding to recent star formation and which may form further stars, and stellar ejecta (including those of supernovae) about to merge with the interstellar medium. The measurement of the microwave background, mixing of material between different nuclear burning zones in evolved stars and turbulent boundary layers (which are present in and influence the structures and evolution of all diffuse astrophysical sources) are treated.

Laboratory and modeling studies of chemistry in dense molecular clouds

NASA Technical Reports Server (NTRS)

Huntress, W. T., Jr.; Prasad, S. S.; Mitchell, G. F.

1980-01-01

A chemical evolutionary model with a large number of species and a large chemical library is used to examine the principal chemical processes in interstellar clouds. Simple chemical equilibrium arguments show the potential for synthesis of very complex organic species by ion-molecule radiative association reactions.

Galactic gamma-ray observations and galactic structure

NASA Technical Reports Server (NTRS)

Stecker, F. W.

1975-01-01

Recent observations of gamma-rays originating in the galactic disk together with radio observations, support an emerging picture of the overall structure of our galaxy with higher interstellar gas densities and star formation rates in a region which corresponds to that of the inner arms. The emerging picture is one where molecular clouds make up the dominant constituent of the interstellar gas in the inner galaxy and play a key role in accounting for the gamma-rays and phenomena associated with the production of young stars and other population 1 objects. In this picture, cosmic rays are associated with supernovae and are primarily of galactic origin. These newly observed phenomena can be understood as consequences of the density wave theories of spiral structure. Based on these new developments, the suggestion is made that a new galactic population class, Population O, be added to the standard Populations 1 and 2 in order to recognize important differences in dynamics and distribution between diffuse galactic H1 and interstellar molecular clouds.

Molecular and mass spectroscopic analysis of isotopically labeled organic residues

NASA Technical Reports Server (NTRS)

Mendoza-Gomez, Celia X.; Greenberg, J. Mayo; Mccain, P.; Ferris, J. P.; Briggs, R.; Degroot, M. S.; Schutte, Willem A.

1989-01-01

Experimental studies aimed at understanding the evolution of complex organic molecules on interstellar grains were performed. The photolysis of frozen gas mixtures of various compositions containing H2O, CO, NH3, and CH4 was studied. These species were chosen because of their astrophysical importance as deducted from observational as well as theoretical studies of ice mantles on interstellar grains. These ultraviolet photolyzed ices were warmed up in order to produce refractory organic molecules like the ones formed in molecular clouds when the icy mantles are being irradiated and warmed up either by a nearby stellar source or impulsive heating. The laboratory studies give estimates of the efficiency of production of such organic material under interstellar conditions. It is shown that the gradual carbonization of organic mantles in the diffuse cloud phase leads to higher and higher visual absorptivity - yellow residues become brown in the laboratory. The obtained results can be applied to explaining the organic components of comets and their relevance to the origin of life.

Anomalous 13C isotope abundances in C3S and C4H observed toward the cold interstellar cloud, Taurus Molecular Cloud-1.

PubMed

Sakai, Nami; Takano, Shuro; Sakai, Takeshi; Shiba, Shoichi; Sumiyoshi, Yoshihiro; Endo, Yasuki; Yamamoto, Satoshi

2013-10-03

We have studied the abundances of the (13)C isotopic species of C3S and C4H in the cold molecular cloud, Taurus Molecular Cloud-1 (Cyanopolyyne Peak), by radioastronomical observations of their rotational emission lines. The CCCS/(13)CCCS and CCCS/C(13)CCS ratios are determined to be >206 and 48 ± 15, respectively. The CC(13)CS line is identified with the aid of laboratory microwave spectroscopy, and the range of the CCCS/CC(13)CS ratio is found to be from 30 to 206. The abundances of at least two (13)C isotopic species of C3S are thus found to be different. Similarly, it is found that the abundances of the four (13)C isotopic species of C4H are not equivalent. The CCCCH/(13)CCCCH, CCCCH/C(13)CCCH, CCCCH/CC(13)CCH, and CCCCH/CCC(13)CH ratios are evaluated to be 141 ± 44, 97 ± 27, 82 ± 15, and 118 ± 23, respectively. Here the errors denote 3 times the standard deviation. These results will constrain the formation pathways of C3S and C4H, if the nonequivalence is caused during the formation processes of these molecules. The exchange reactions after the formation of these two molecules may also contribute to the nonequivalence. In addition, we have confirmed that the (12)C/(13)C ratio of some species are significantly higher than the interstellar elemental (12)C/(13)C ratio of 60-70. The observations of the (13)C isotopic species provide us with rich information on chemical processes in cold interstellar clouds.

Cosmic Carbon Chemistry: From the Interstellar Medium to the Early Earth

PubMed Central

Ehrenfreund, Pascale; Cami, Jan

2010-01-01

Astronomical observations have shown that carbonaceous compounds in the gas and solid state, refractory and icy are ubiquitous in our and distant galaxies. Interstellar molecular clouds and circumstellar envelopes are factories of complex molecular synthesis. A surprisingly large number of molecules that are used in contemporary biochemistry on Earth are found in the interstellar medium, planetary atmospheres and surfaces, comets, asteroids and meteorites, and interplanetary dust particles. In this article we review the current knowledge of abundant organic material in different space environments and investigate the connection between presolar and solar system material, based on observations of interstellar dust and gas, cometary volatiles, simulation experiments, and the analysis of extraterrestrial matter. Current challenges in astrochemistry are discussed and future research directions are proposed. PMID:20554702

Cold and warm atomic gas around the Perseus molecular cloud. I. Basic properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stanimirović, Snežana; Murray, Claire E.; Miller, Jesse

2014-10-01

Using the Arecibo Observatory, we have obtained neutral hydrogen (HI) absorption and emission spectral pairs in the direction of 26 background radio continuum sources in the vicinity of the Perseus molecular cloud. Strong absorption lines were detected in all cases, allowing us to estimate spin temperature (T{sub s} ) and optical depth for 107 individual Gaussian components along these lines of sight. Basic properties of individual H I clouds (spin temperature, optical depth, and the column density of the cold and warm neutral medium (CNM and WNM), respectively) in and around Perseus are very similar to those found for randommore » interstellar lines of sight sampled by the Millennium H I survey. This suggests that the neutral gas found in and around molecular clouds is not atypical. However, lines of sight in the vicinity of Perseus have, on average, a higher total H I column density and the CNM fraction, suggesting an enhanced amount of cold H I relative to an average interstellar field. Our estimated optical depth and spin temperature are in stark contrast with the recent attempt at using Planck data to estimate properties of the optically thick H I. Only ∼15% of lines of sight in our study have a column density weighted average spin temperature lower than 50 K, in comparison with ≳ 85% of Planck's sky coverage. The observed CNM fraction is inversely proportional to the optical depth weighted average spin temperature, in excellent agreement with the recent numerical simulations by Kim et al. While the CNM fraction is, on average, higher around Perseus relative to a random interstellar field, it is generally low, between 10%-50%. This suggests that extended WNM envelopes around molecular clouds and/or significant mixing of CNM and WNM throughout molecular clouds are present and should be considered in the models of molecule and star formation. Our detailed comparison of H I absorption with CO emission spectra shows that only 3 of the 26 directions are clear candidates for probing the CO-dark gas as they have N(H I)>10{sup 21} cm{sup –2} yet no detectable CO emission.« less

Decoding IR Spectra of Cosmic Ices and Organics in the Laboratory

NASA Technical Reports Server (NTRS)

Allamandola, Louis J.

2006-01-01

Tremendous strides have been made in our understanding of interstellar material over the past twenty-five years thanks to significant developments in observational IR astronomy and dedicated laboratory experiments. Twenty-five years ago the composition of interstellar dust was largely guessed at. Today the composition of interstellar dust is reasonably well understood. In the diffuse interstellar medium (ISM) the dust population is mainly comprised of small grains of silicates and amorphous carbon. In dark molecular clouds, the birthplace of stars and planets, these cold refractory dust particles are coated with mixed molecular ices whose composition is reasonably well constrained. Lastly, the signature of carbon-rich polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by early interstellar chemistry standards, is widespread throughout the Universe. This extraordinary progress has been made possible by the close collaboration of laboratory experimentalists and theoreticians with IR astronomers using groundbased, air-borne, and orbiting telescopes.

Interstellar Matter

NASA Astrophysics Data System (ADS)

Savage, B.; Murdin, P.

2000-11-01

The enormous volume of space between the stars in the Milky Way Galaxy is filled with interstellar matter (ISM). The ISM plays a central role in the processes of STAR FORMATION and GALAXY EVOLUTION. Stars form from the ISM in dense molecular clouds. The radiant and mechanical energy produced by stars heats, ionizes, and produces structures in the ISM. Gradual or catastrophic mass loss from stars ...

The Production of Complex Organics from Interstellar Ices

NASA Technical Reports Server (NTRS)

Sandford, Scott A.; Allamandola, Louis; Bernstein, Max; Deamer, David; Dworkin, Jason; Zare, Richard

2001-01-01

Infrared spectroscopy of ices in interstellar dense molecular clouds has shown that they contain a variety of simple molecules, as well as aromatic hydrocarbons. While in these clouds, these ices are processed by ultraviolet light and cosmic rays. High vacuum, UV irradiation laboratory simulations conducted using various realistic approx. 10 K interstellar mixed-molecular ice analogs, both with and without polycyclic aromatic hydrocarbons (PAHs), have been carried out in NASA-Ames' Astrochemistry Laboratory. Upon warming, these irradiated ices are found to produce refractory organic residues. These residues have been analyzed using a variety of techniques, including HPLC and laser desorption mass spectrometry, and they have been shown to contain a variety of complex organic compounds. Several of these compounds may be of prebiotic significance. In particular, we will discuss the detection of quinones (substituted PAHs that are used by living systems for electron transport) and amphiphiles (molecules that self-assemble to form membranes). Laboratory simulations have also demonstrated that the organic products can show isotopic enrichments in D that provide clues for the mechanisms of their formation. Similar compounds and D enrichments are seen in the organics found in primitive meteorites, suggesting a direct link between interstellar chemistry and the delivery of organics to newly formed planets.

Circumstellar gas associated with HL Tauri - Evidence for a remnant infalling envelope

NASA Technical Reports Server (NTRS)

Grasdalen, Gary L.; Sloan, Gregory; Stout, Natalie; Strom, Stephen E.; Welty, Alan D.

1989-01-01

Molecular carbon absorption lines in the spectrum of HL Tau has been discovered near 8775 A. These C2 lines have a heliocentric radial velocity of 43 + or - 3 km/s, redshifted by 23 + or - 3 km/s relative to the star and the associated molecular cloud. This velocity difference suggests that the molecular carbon absorption arises in an infalling envelope. Since KI and diffuse interstellar bands are much weaker than expected, the chemical composition and/or excitation conditions in the HL Tau envelope appear to differ substantially from those in the interstellar medium.

Into the Darkness: Interstellar Extinction Near the Cepheus OB3 Molecular Cloud

NASA Astrophysics Data System (ADS)

Fitzpatrick, Edward L.; Jacklin, S.; Massa, D.

2014-01-01

We present the results of a followup investigation to a study performed by Massa and Savage (1984, ApJ, 279, 310) of the properties of UV interstellar extinction in the region of the Cepheus OB3 molecular cloud. That study was performed using UV photometry and spectro-photometry from the ANS and IUE satellites. We have extended this study into the IR, utilizing the uniform database of IR photometry available from the 2MASS project. This is a part of a larger program whose goal is to study the properties of extinction in localized regions, where we hope to find clues to dust grain growth and destruction processes through spatial correlations of extinction with distinct environmental properties. Similarly to Massa and Savage’s UV results, we find that the IR extinction properties on the Cepheus OB3 region vary systematically with the apparent proximity of the target stars to the molecular cloud. We also find that the UV extinction and the IR extinction are crudely correlated. The methodology leading to these results and their implications are discussed.

C+/CO Transitions in the Diffuse ISM: Transitional Cloud Sample from the GOT C+ Survey of [CII] in the inner Galaxy at l = -30deg to 30deg

NASA Astrophysics Data System (ADS)

Velusamy, T.; Pineda, J. L.; Langer, W. D.; Willacy, K.; Goldsmith, P. F.

2011-05-01

Our knowledge of interstellar gas has been limited primarily to the diffuse atomic phase traced by HI and the well-shielded molecular phase traced by CO. Recently, using the first results of the Herschel Key Project GOT C+, a HIFI C+ survey of the Galactic plane, Velusamy, Langer, Pineda et al. (A&A 521, L18, 2010) have shown that in the diffuse interstellar transition clouds a significant fraction of the carbon exists primarily as C^+ with little C^0 and CO in a warm 'dark gas' layer in which hydrogen is mostly H_2 with little atomic H, surrounding a modest 12CO-emitting core. The [CII] fine structure transition, at 1.9 THz (158 μm) is the best tracer of this component of the interstellar medium, which is critical to our understanding of the atomic to molecular cloud transitions. The Herschel Key Project GOT C+ is designed to study such clouds by observing with HIFI the [CII] line emission along 500 lines of sight (LOSs) throughout the Galactic disk. Here we present the identification and chemical status of a few hundred diffuse and transition clouds traced by [CII], along with auxiliary HI and CO data covering ~100 LOSs in the inner Galaxy between l= -30° and 30°. We identify transition clouds as [CII] components that are characterized by the presence of both HI and 12CO, but no 13CO emission. The intensities, I(CII) and I(HI), are used as measures of the visual extinction, AV, in the cloud up to the C^+/C^0/CO transition layer and a comparison with I(12CO) yields a more complete H_2 molecular inventory. Our results show that [CII] emission is an excellent tool to study transition clouds and their carbon chemistry in the ISM, in particular as a unique tracer of molecular H_2, which is not easily observed by other means. The large sample presented here will serve as a resource to study the chemical and physical status of diffuse transition clouds in a wide range of Galactic environments and constrain the physical parameters such as the FUV intensity and cosmic ray ionization rate that drive the CO chemistry in the diffuse ISM.

The Potential Role Played by the Fullerene-Like Structures of Interstellar Carbon Dust in the Formation of Molecular Hydrogen in Space

NASA Astrophysics Data System (ADS)

Cataldo, Franco; Iglesias-Groth, Susana

After a general introduction to the problem of formation of molecular hydrogen from atomic hydrogen in the interstellar medium and in the dense molecular clouds in particular, and after the explanation of the key role played by the surfaces on this process, it is proposed that the most suitable carbon surface for the formation of molecular hydrogen (from the radiative association process of atomic hydrogen) can be represented by carbon black rather than by graphite. Furthermore, it is proposed that the fullerene-like structures present in the carbon black graphene sheets are the reaction sites where molecular hydrogen may be formed.

Recent observations of interstellar molecules - Detection of CCO and a limit on H2C3O

NASA Technical Reports Server (NTRS)

Brown, R. D.; Cragg, D. M.; Godfrey, P. D.; Irvine, W. M.; Mcgonagle, D.; Ohishi, M.

1992-01-01

In order to test gas-phase reaction schemes for the production of small oxides of carbon in cold, dense interstellar clouds, we have searched for the radical CCO and for propadienone (H2C3O) in Taurus Molecular Cloud 1, a nearby cloud which exhibits a rich organic chemistry. The radical CCO has been detected with a fractional abundance some two orders of magnitude less than that of CCS, about one order of magnitude less than that of H2CCO, and slightly less than that of C3O. An upper limit has been obtained on the abundance of propadienone which is slightly less than that of its isomer propynal (HC2CHO).

Fragmentation of interstellar clouds and star formation

NASA Technical Reports Server (NTRS)

Silk, J.

1982-01-01

The principal issues are addressed: the fragmentation of molecular clouds into units of stellar mass and the impact of star formation on molecular clouds. The observational evidence for fragmentation is summarized, and the gravitational instability described of a uniform spherical cloud collapsing from rest. The implications are considered of a finite pressure for the minimum fragment mass that is attainable in opacity-limited fragmentation. The role of magnetic fields is discussed in resolving the angular momentum problem and in making the collapse anisotropic, with notable consequences for fragmentation theory. Interactions between fragments are described, with emphasis on the effect of protostellar winds on the ambient cloud matter and on inhibiting further star formation. Such interactions are likely to have profound consequences for regulating the rate of star formation and on the energetics and dynamics of molecular clouds.

Interactions of stars and interstellar matter in Scorpio Centaurus

NASA Technical Reports Server (NTRS)

De Geus, E. J.

1992-01-01

The interaction of the stars in the Scorpio-Centaurus OB association with the ambient interstellar medium is investigated. Large H I loops in the fourth galactic quadrant are parts of expanding shells surrounding the subgroups of the association. The energy output of the original stellar population of the subgroups is calculated. Comparison with the kinetic energy of the shells shows that the energy output of the stars in the subgroups is sufficient to form the shells. The masses of the shells are consistent with those of giant molecular clouds GMCs, suggesting that the shells consist of swept-up, original GMC material. The influence of the expanding shell around the young Upper-Scorpius subgroup on the morphology of the Ophiuchus molecular clouds is investigated. The interaction of the shell with the Ophiuchus clouds accounts for the presence of a slow shock and for the shape of the elongated dark clouds connected to the Rho Oph dense cloud. The close passage of the trajectory of the runaway star Zeta Oph by the center of the Upper-Scorpius shell, combined with the time scale of formation of the shell, strongly suggests that the star has originated in the Upper-Scorpius subgroup.

Molecular Astrophysics from Space: the Physical and Chemical Effects of Star Formation and the Destruction of Planetary Systems around Evolved Stars

NASA Technical Reports Server (NTRS)

Neufeld, David

2005-01-01

The research conducted during the reporting period is grouped into three sections: 1) Warm molecular gas in the interstellar medium (ISM); 2) Absorption line studies of "cold" molecular clouds; 3) Vaporization of comets around the AGB star IRC+10216.

Multiple generations of grain aggregation in different environments preceded solar system body formation.

PubMed

Ishii, Hope A; Bradley, John P; Bechtel, Hans A; Brownlee, Donald E; Bustillo, Karen C; Ciston, James; Cuzzi, Jeffrey N; Floss, Christine; Joswiak, David J

2018-06-26

The solar system formed from interstellar dust and gas in a molecular cloud. Astronomical observations show that typical interstellar dust consists of amorphous ( a -) silicate and organic carbon. Bona fide physical samples for laboratory studies would yield unprecedented insight about solar system formation, but they were largely destroyed. The most likely repositories of surviving presolar dust are the least altered extraterrestrial materials, interplanetary dust particles (IDPs) with probable cometary origins. Cometary IDPs contain abundant submicron a- silicate grains called GEMS (glass with embedded metal and sulfides), believed to be carbon-free. Some have detectable isotopically anomalous a- silicate components from other stars, proving they are preserved dust inherited from the interstellar medium. However, it is debated whether the majority of GEMS predate the solar system or formed in the solar nebula by condensation of high-temperature (>1,300 K) gas. Here, we map IDP compositions with single nanometer-scale resolution and find that GEMS contain organic carbon. Mapping reveals two generations of grain aggregation, the key process in growth from dust grains to planetesimals, mediated by carbon. GEMS grains, some with a- silicate subgrains mantled by organic carbon, comprise the earliest generation of aggregates. These aggregates (and other grains) are encapsulated in lower-density organic carbon matrix, indicating a second generation of aggregation. Since this organic carbon thermally decomposes above ∼450 K, GEMS cannot have accreted in the hot solar nebula, and formed, instead, in the cold presolar molecular cloud and/or outer protoplanetary disk. We suggest that GEMS are consistent with surviving interstellar dust, condensed in situ, and cycled through multiple molecular clouds. Copyright © 2018 the Author(s). Published by PNAS.

Formation of Benzene in the Interstellar Medium

NASA Technical Reports Server (NTRS)

Jones, Brant M.; Zhang, Fangtong; Kaiser, Ralf I.; Jamal, Adeel; Mebel, Alexander M.; Cordiner, Martin A.; Charnley, Steven B.; Crim, F. Fleming (Editor)

2010-01-01

Polycyclic aromatic hydrocarbons and related species have been suggested to play a key role in the astrochemical evolution of the interstellar medium, but the formation mechanism of even their simplest building block-the aromatic benzene molecule-has remained elusive for decades. Here we demonstrate in crossed molecular beam experiments combined with electronic structure and statistical calculations that benzene (C6H6) can be synthesized via the barrierless, exoergic reaction of the ethynyl radical and 1,3- butadiene, C2H + H2CCHCHCH2 --> C6H6, + H, under single collision conditions. This reaction portrays the simplest representative of a reaction class in which aromatic molecules with a benzene core can be formed from acyclic precursors via barrierless reactions of ethynyl radicals with substituted 1,3-butadlene molecules. Unique gas-grain astrochemical models imply that this low-temperature route controls the synthesis of the very first aromatic ring from acyclic precursors in cold molecular clouds, such as in the Taurus Molecular Cloud. Rapid, subsequent barrierless reactions of benzene with ethynyl radicals can lead to naphthalene-like structures thus effectively propagating the ethynyl-radical mediated formation of aromatic molecules in the interstellar medium.

Formation of benzene in the interstellar medium

PubMed Central

Jones, Brant M.; Zhang, Fangtong; Kaiser, Ralf I.; Jamal, Adeel; Mebel, Alexander M.; Cordiner, Martin A.; Charnley, Steven B.

2011-01-01

Polycyclic aromatic hydrocarbons and related species have been suggested to play a key role in the astrochemical evolution of the interstellar medium, but the formation mechanism of even their simplest building block—the aromatic benzene molecule—has remained elusive for decades. Here we demonstrate in crossed molecular beam experiments combined with electronic structure and statistical calculations that benzene (C6H6) can be synthesized via the barrierless, exoergic reaction of the ethynyl radical and 1,3-butadiene, C2H + H2CCHCHCH2 → C6H6 + H, under single collision conditions. This reaction portrays the simplest representative of a reaction class in which aromatic molecules with a benzene core can be formed from acyclic precursors via barrierless reactions of ethynyl radicals with substituted 1,3-butadiene molecules. Unique gas-grain astrochemical models imply that this low-temperature route controls the synthesis of the very first aromatic ring from acyclic precursors in cold molecular clouds, such as in the Taurus Molecular Cloud. Rapid, subsequent barrierless reactions of benzene with ethynyl radicals can lead to naphthalene-like structures thus effectively propagating the ethynyl-radical mediated formation of aromatic molecules in the interstellar medium. PMID:21187430

Interstellar Polycyclic Aromatic Compounds and Astrophysics

NASA Technical Reports Server (NTRS)

Hodgins, Douglas M.; DeVincenzi, Donald (Technical Monitor)

1999-01-01

Polycyclic aromatic compounds (PACs), a class of organic molecules whose structures are characterized by the presence of two or more fused aromatic rings, have been the subject of astrophysical interest for nearly two decades. Large by interstellar standards (from as few as 20 to perhaps as many as several hundred atoms), it has been suggested that these species are among the most abundant interstellar molecules impacting a wide range of astrophysical phenomena including: the ubiquitous family of infrared emission bands observed in an ever-increasing assortment of astronomical objects; the subtle but rich array of discrete visible/near-infrared interstellar molecular absorption features known as the diffuse interstellar bands (DIBs); the broad near-infrared quasi-continuum observed in a number of nebulae known as excess red emission (ERE); the interstellar ultraviolet extinction curve and broad '2200 Angstrom bump'; the heating/cooling mechanisms of interstellar clouds. Nevertheless, until recently a lack of good-quality laboratory spectroscopic data on PACs under astrophysically relevant conditions (i.e. isolated, ionized molecules; ionized molecular clusters, etc.) has hindered critical evaluation and extension of this model

Optical observations related to the molecular chemistry in diffuse interstellar clouds

NASA Technical Reports Server (NTRS)

Federman, S. R.

1987-01-01

Observations, which have been published since 1979, of molecular species in diffuse clouds are discussed. Particular attention is given to the ultraviolet measurements of CO with the Copernicus and IUE satellites and to ground-based optical measurements of CH, CH(+), CN, and 02. These data encompass large enough samples to test the chemical schemes expected to occur in diffuse clouds. Upper limits for other species (e.g., H2O, H2O(+), and C3) place restrictions on the pathways for molecular production. Moreover, analysis of the rotational distribution of the C2 molecule results in the determination of the physical conditions of the cloud. These parameters, including density, temperature, and the intensity of the radiation field, are necessary for modeling the chemistry.

Galaxy and the solar system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smoluchowski, R.; Bahcall, J.M.; Matthews, M.S.

1986-01-01

The solar-Galactic neighborhood, massive interstellar clouds and other Galactic features, the Oort cloud, perturbations of the solar system, and the existence and stability of a solar companion star are examined in chapters based on contributions to a conference held in Tucson, AZ during January 1985. The individual topics addressed include: the Galactic environment of the solar system; stars within 25 pc of the sun; the path of the sun in 100 million years; the local velocity field in the last billion years; interstellar clouds near the sun; and evidence for a local recent supernova. Also considered are: dynamic influence ofmore » Galactic tides and molecular clouds on the Oort cloud; cometary evidence for a solar companion; dynamical interactions between the Oort cloud and the Galaxy; geological periodicities and the Galaxy; giant comets and the Galaxy; dynamical evidence for Planet X; evolution of the solar system in the presence of a solar companion star; mass extinctions, crater ages, and comet showers; evidence for Nemesis, a solar companion star.« less

Scientists Discover Sugar in Space

NASA Astrophysics Data System (ADS)

2000-06-01

The prospects for life in the Universe just got sweeter, with the first discovery of a simple sugar molecule in space. The discovery of the sugar molecule glycolaldehyde in a giant cloud of gas and dust near the center of our own Milky Way Galaxy was made by scientists using the National Science Foundation's 12 Meter Telescope, a radio telescope on Kitt Peak, Arizona. "The discovery of this sugar molecule in a cloud from which new stars are forming means it is increasingly likely that the chemical precursors to life are formed in such clouds long before planets develop around the stars," said Jan M. Hollis of the NASA Goddard Space Flight Center in Greenbelt, MD. Hollis worked with Frank J. Lovas of the University of Illinois and Philip R. Jewell of the National Radio Astronomy Observatory (NRAO) in Green Bank, WV, on the observations, made in May. The scientists have submitted their results to the Astrophysical Journal Letters. "This discovery may be an important key to understanding the formation of life on the early Earth," said Jewell. Conditions in interstellar clouds may, in some cases, mimic the conditions on the early Earth, so studying the chemistry of interstellar clouds may help scientists understand how bio-molecules formed early in our planet's history. In addition, some scientists have suggested that Earth could have been "seeded" with complex molecules by passing comets, made of material from the interstellar cloud that condensed to form the Solar System. Glycolaldehyde, an 8-atom molecule composed of carbon, oxygen and hydrogen, can combine with other molecules to form the more-complex sugars Ribose and Glucose. Ribose is a building block of nucleic acids such as RNA and DNA, which carry the genetic code of living organisms. Glucose is the sugar found in fruits. Glycolaldehyde contains exactly the same atoms, though in a different molecular structure, as methyl formate and acetic acid, both of which were detected previously in interstellar clouds. Glycolaldehyde is a simpler molecular cousin to table sugar, the scientists say. The sugar molecule was detected in a large cloud of gas and dust some 26,000 light-years away, near the center of our Galaxy. Such clouds, often many light-years across, are the material from which new stars are formed. Though very rarified by Earth standards, these interstellar clouds are the sites of complex chemical reactions that occur over hundreds of thousands or millions of years. So far, about 120 different molecules have been discovered in these clouds. Most of these molecules contain a small number of atoms, and only a few molecules with eight or more atoms have been found in interstellar clouds. The 12 Meter Telescope "Finding glycolaldehyde in one of these interstellar clouds means that such molecules can be formed even in very rarified conditions," said Hollis. "We don't yet understand how it could be formed there," he added. "A combination of more astronomical observations and theoretical chemistry work will be required to resolve the mystery of how this molecule is formed in space." "We hope this discovery inspires renewed efforts to find even more kinds of molecules, so that, with a better idea of the total picture, we may be able to deduce the details of the prebiotic chemistry taking place in interstellar clouds," Hollis said. The discovery was made by detecting faint radio emission from the sugar molecules in the interstellar cloud. Molecules rotate end-for-end, and as they change from one rotational energy state to another, they emit radio waves at precise frequencies. The "family" of radio frequencies emitted by a particular molecule forms a unique "fingerprint" that scientists can use to identify that molecule. The scientists identified glycolaldehyde by detecting six frequencies of radio emission in what is termed the millimeter-wavelength region of the electromagnetic spectrum -- a region between more-familiar microwaves and infrared radiation. The NRAO 12 Meter Telescope used to detect the sugar molecule has been a pioneer instrument in the detection of molecules in space. Built in 1967, it made the first detections of dozens of the molecules now known to exist in space, including the important first discovery of carbon monoxide, now widely used by astronomers as a signpost showing regions where stars are being formed. The 12 Meter Telescope is scheduled to be closed at the end of July, in preparation for the Atacama Large Millimeter Array, an advanced system of 64 radio-telescope antennas in northern Chile now being developed by an international partnership. The National Radio Astronomy Observatory is a facility of the National Science Foundation, operated under cooperative agreement by Associated Universities, Inc. Giant Molecular Cloud Near Milky Way's Center The giant molecular cloud, known as Sagittarius B2 (North), as seen by the NSF's Very Large Array (VLA) radio telescope in New Mexico. This is the cloud in which scientists using the 12 Meter Telescope detected the simple sugar molecule glycolaldehyde. This VLA image shows hydrogen gas in a region nearly 3 light-years across. In this image, red indicates stronger radio emission; blue weaker. The 12 Meter Telescope studied this region at much shorter wavelengths, which revealed the evidence of sugar molecules. CREDIT: R. Gaume, M. Claussen, C. De Pree, W.M. Goss, D. Mehringer, NRAO/AUI/NSF.

Prebiotic chemical evolution in the astrophysical context.

PubMed

Ziurys, L M; Adande, G R; Edwards, J L; Schmidt, D R; Halfen, D T; Woolf, N J

2015-06-01

An ever increasing amount of molecular material is being discovered in the interstellar medium, associated with the birth and death of stars and planetary systems. Radio and millimeter-wave astronomical observations, made possible by high-resolution laboratory spectroscopy, uniquely trace the history of gas-phase molecules with biogenic elements. Using a combination of both disciplines, the full extent of the cycling of molecular matter, from circumstellar ejecta of dying stars - objects which expel large amounts of carbon - to nascent solar systems, has been investigated. Such stellar ejecta have been found to exhibit a rich and varied chemical content. Observations demonstrate that this molecular material is passed onto planetary nebulae, the final phase of stellar evolution. Here the star sheds almost its entire original mass, becoming an ultraviolet-emitting white dwarf. Molecules such as H2CO, HCN, HCO(+), and CCH are present in significant concentrations across the entire age span of such nebulae. These data suggest that gas-phase polyatomic, carbon-containing molecules survive the planetary nebula phase and subsequently are transported into the interstellar medium, seeding the chemistry of diffuse and then dense clouds. The extent of the chemical complexity in dense clouds is unknown, hindered by the high spectral line density. Organic species such as acetamide and methyl amine are present in such objects, and NH2CHO has a wide Galactic distribution. However, organophosphorus compounds have not yet been detected in dense clouds. Based on carbon and nitrogen isotope ratios, molecular material from the ISM appears to become incorporated into solar system planetesimals. It is therefore likely that interstellar synthesis influences prebiotic chemistry on planet surfaces.

The chemistry of dense interstellar clouds

NASA Technical Reports Server (NTRS)

Irvine, W. M.

1991-01-01

The basic theme of this program is the study of molecular complexity and evolution in interstellar and circumstellar clouds incorporating the biogenic elements. Recent results include the identification of a new astronomical carbon-chain molecule, C4Si. This species was detected in the envelope expelled from the evolved star IRC+10216 in observations at the Nobeyama Radio Observatory in Japan. C4Si is the carrier of six unidentified lines which had previously been observed. This detection reveals the existence of a new series of carbon-chain molecules, C sub n Si (n equals 1, 2, 4). Such molecules may well be formed from the reaction of Si(+) with acetylene and acetylene derivatives. Other recent research has concentrated on the chemical composition of the cold, dark interstellar clouds, the nearest dense molecular clouds to the solar system. Such regions have very low kinetic temperatures, on the order of 10 K, and are known to be formation sites for solar-type stars. We have recently identified for the first time in such regions the species of H2S, NO, HCOOH (formic acid). The H2S abundance appears to exceed that predicted by gas-phase models of ion-molecule chemistry, perhaps suggesting the importance of synthesis on grain surfaces. Additional observations in dark clouds have studied the ratio of ortho- to para-thioformaldehyde. Since this ratio is expected to be unaffected by both radiative and ordinary collisional processes in the cloud, it may well reflect the formation conditions for this molecule. The ratio is observed to depart from that expected under conditions of chemical equilibrium at formation, perhaps reflecting efficient interchange between cold dust grains in the gas phase.

Indirect observation of unobservable interstellar molecules

NASA Technical Reports Server (NTRS)

Herbst, E.; Green, S.; Thaddeus, P.; Klemperer, W.

1977-01-01

It is suggested that the abundances of neutral non-polar interstellar molecules unobservable by radio astronomy can be systematically determined by radio observation of the protonated ions. As an example, observed N2H(+) column densities are analyzed to infer molecular nitrogen abundances in dense interstellar clouds. The chemistries and expected densities of the protonated ions of O2, C2, CO2, C2H2 and CH4 are then discussed. Microwave transition frequencies fo HCO2(+) and C2H3(+) are estimated, and a preliminary astronomical search for HCO2(+) is described.

CO near the Pleiades: Encounter of a star cluster with a small molecular cloud

NASA Technical Reports Server (NTRS)

Bally, J.; White, R. E.

1986-01-01

Although there is a large amount of interstellar matter near the Pleiades star cluster, the observed dust and gas is not a remnant of the placental molecular cloud from which the star cluster was formed. Carbon monoxide (CO) associated with the visible reflection nebulae was discovered by Cohen (1975). Its radial velocity differs from that of the cluster by many times the cluster escape velocity, which implies that the cloud-cluster association is the result of a chance encounter. This circumstance and the proximity of the Pleiades to the sun creates an unique opportunity for study of interstellar processes at high spatial resolution. To study the molecular component of the gas, a 1.7 square degree field was mapped with the AT&T Bell Laboratories 7-meter antenna (1.7' beam) on a 1' grid in the J=1.0 C(12)O line, obtaining over 6,000 spectra with 50 kHz resolution. The cloud core was mapped in the J=1-0 line of C(13)O. Further observations include an unsuccessful search for CS (J=2-1) at AT&T BL, and some C(12)O J=2-1 spectra obtained at the Millimeter Wave Observatory of the University of Texas.

Comment on "The shape and composition of interstellar silicate grains"

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bradley, J P; Ishii, H

2007-09-27

In the paper entitled 'The shape and composition of interstellar silicate grains' (A & A, 462, 667-676 (2007)), Min et al. explore non-spherical grain shape and composition in modeling the interstellar 10 and 20 {micro}m extinction features. This progression towards more realistic models is vitally important to enabling valid comparisons between dust observations and laboratory measurements. Min et al. proceed to compare their model results with GEMS (glass with embedded metals and sulfides) from IDPs (interplanetary dust particles) and to discuss the nature and origin of GEMS. Specifically, they evaluate the hypothesis of Bradley (1994) that GEMS are interstellar (IS)more » amorphous silicates. From a comparison of the mineralogy, chemical compositions, and infrared (IR) spectral properties of GEMS with their modeling results, Min et al. conclude: 'GEMS are, in general, not unprocessed leftovers from the diffuse ISM'. This conclusion is based, however, on erroneous and incomplete GEMS data. It is important to clarify first that Bradley (1994) never proposed that GEMS are unprocessed leftovers from the diffuse ISM, nor did he suggest that individual subnanogram mass GEMS are a representative sampling of the enormous mass of silicates in the diffuse ISM. Bradley (1994) simply showed that GEMS properties are consistent with those of IS amorphous silicates. It is widely accepted that circumstellar outflows are important sources of IS silicates, and whether GEMS are processed or not, the circumstellar heritage of some has been rigorously confirmed through measurements of non-solar oxygen (O) isotope abundances (Messenger et al., 2003; Floss et al., 2006). Keller et al. (2000) assert that even GEMS without detectable O isotope anomalies are probably also extrasolar IS silicates because they are embedded in carbonaceous material with non-solar D/H isotopic composition. (Much of the silicate dust in the ISM may be isotopically homogenized (Zhukovska et al., 2007)). Recent measurements show that the elemental compositions of GEMS with non-solar isotopic compositions are 'remarkably similar' to those with solar isotopic compositions (Keller & Messenger, 2007). About 80% of all isotopically anomalous IS silicates identified to date are GEMS with detectable and variable O isotopic memories of a circumstellar ancestry (Messenger, 2007). Bradley (1999) proposed that GEMS are IS silicates from 'a presolar interstellar molecular cloud, presumably the local molecular cloud from which the solar system formed'. Although based on incorrect data (detailed below), Min et al. propose that most GEMS actually formed in the presolar molecular cloud, and they further propose that none of them are IS silicates. IS silicate sources include molecular clouds, circumstellar outflows, supernovae, and even recently discovered black hole winds (Molster & Waters; 2003; Jones, 2005; Zhukovska et al. 2007; Markwick-Kemper et al. 2007). The average IS 10 {micro}m extinction feature observed along lines of sight towards the galactic center (modeled by Min et al.) presumably provides a good average for IS silicates, but it cannot distinguish amorphous silicates originating in the presolar molecular cloud from amorphous silicates originating in other interstellar molecular clouds or indeed other sources of amorphous IS silicates. Even if most GEMS accreted in the presolar molecular cloud, then they must also be representatives of some portion of the IS amorphous silicate population. Laboratory heating experiments indicate it is highly unlikely that GEMS were modified in a protoplanetary accretion disk environment (Brownlee et al. 2005). In summary, Min et al. conclude from their modeling of the shape and composition of IS silicates that the properties of GEMS are generally inconsistent with those of IS silicates. First, it has been rigorously confirmed via ion microprobe measurements that some GEMS are indeed presolar IS silicates. Second, regardless of whether GEMS, or components of GEMS, originated in presolar circumstellar outflows or a presolar molecular cloud they are all IS silicates. Third, key GEMS data reported in Min et al. are inaccurate. Had complete isotopic, chemical, mineralogical and infrared (IR) spectral properties of GEMS been considered, Min et al. may have concluded that the properties of GEMS, although not an exact match, are generally consistent with those of amorphous silicates in the ISM.« less

Prospects for Studying Interstellar Magnetic Fields with a Far-Infrared Polarimeter for SAFIR

NASA Technical Reports Server (NTRS)

Dowell, C. Darren; Chuss, D. T.; Dotson, J. L.

2008-01-01

Polarimetry at mid-infrared through millimeter wavelengths using airborne and ground-based telescopes has revealed magnetic structures in dense molecular clouds in the interstellar medium, primarily in regions of star formation. Furthermore, spectropolarimetry has offered clues about the composition of the dust grains and the mechanism by which they are aligned with respect to the local magnetic field. The sensitivity of the observations to date has been limited by the emission from the atmosphere and warm telescopes. A factor of 1000 in sensitivity can be gained by using instead a cold space telescope. With 5 arcminute resolution, Planck will make the first submillimeter polarization survey of the full Galaxy early in the next decade. We discuss the science case for and basic design of a far-infrared polarimeter on the SAFIR space telescope, which offers resolution in the few arcsecond range and wavelength selection of cold and warm dust components. Key science themes include the formation and evolution of molecular clouds in nearby spiral galaxies, the magnetic structure of the Galactic center, and interstellar turbulence.

Deep, Broadband Spectral Line Surveys of Molecule-rich Interstellar Clouds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Widicus Weaver, Susanna L.; Laas, Jacob C.; Zou, Luyao

2017-09-01

Spectral line surveys are an indispensable tool for exploring the physical and chemical evolution of astrophysical environments due to the vast amount of data that can be obtained in a relatively short amount of time. We present deep, broadband spectral line surveys of 30 interstellar clouds using two broadband λ  = 1.3 mm receivers at the Caltech Submillimeter Observatory. This information can be used to probe the influence of physical environment on molecular complexity. We observed a wide variety of sources to examine the relative abundances of organic molecules as they relate to the physical properties of the source (i.e., temperature,more » density, dynamics, etc.). The spectra are highly sensitive, with noise levels ≤25 mK at a velocity resolution of ∼0.35 km s{sup −1}. In the initial analysis presented here, column densities and rotational temperatures have been determined for the molecular species that contribute significantly to the spectral line density in this wavelength regime. We present these results and discuss their implications for complex molecule formation in the interstellar medium.« less

VARIATIONS BETWEEN DUST AND GAS IN THE DIFFUSE INTERSTELLAR MEDIUM. II. SEARCH FOR COLD GAS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reach, William T.; Heiles, Carl; Bernard, Jean-Philippe, E-mail: wreach@sofia.usra.edu

2017-01-01

The content of interstellar clouds, in particular the inventory of diffuse molecular gas, remains uncertain. We identified a sample of isolated clouds, approximately 100 M {sub ⊙} in size, and used the dust content to estimate the total amount of gas. In Paper I, the total inferred gas content was found significantly larger than that seen in 21 cm emission measurements of H i. In this paper we test the hypothesis that the apparent excess “dark” gas is cold H i, which would be evident in absorption but not in emission due to line saturation. The results show that theremore » is not enough 21 cm absorption toward the clouds to explain the total amount of “dark” gas.« less

Ion-molecule calculation of the abundance ratio of CCD to CCH in dense interstellar clouds

NASA Technical Reports Server (NTRS)

Herbst, Eric; Adams, Nigel G.; Smith, David; Defrees, D. J.

1987-01-01

Laboratory measurements and calculations have been performed to determine the abundance ratio of the deuterated ethynyl radical (CCD) to the normal radical (CCH) which can be achieved in dense interstellar clouds via isotopic fractionation in the C2H2(+) (HD)=C2HD(+)(H2) system of reactions. According to this limited treatment, the CCD/CCH abundance ratio which can be attained is in the range 0.02-0.03 for the Orion molecular cloud and 0.0l-0.02 for TMC-1. These ranges of numbers are in reasonable agreement with the observed values in Orion and TMC-1. However, the analysis of the CCD/CCH abundance ratio is complicated via the presence of competing fractionation mechanisms, especially in the low-temperature source TMC-1.

Collisional excitation of interstellar methyl cyanide

NASA Technical Reports Server (NTRS)

Green, Sheldon

1986-01-01

Theoretical calculations are used to determine the collisional excitation rates of methyl cyanide under interstellar molecular cloud conditions. The required Q(L,M) as a function of kinetic temperature were determined by averaging fixed energy IOS (infinite order sudden) results over appropriate Boltzmann distributions of collision energies. At a kinetic temperature of 40 K, rates within a K ladder were found to be accurate to generally better than about 30 percent.

Molecular Line Studies of Ballistic Stellar Interlopers Burrowing through Dense Interstellar Clouds

NASA Astrophysics Data System (ADS)

Rosen, Anna; Sahai, R.; Claussen, M.; Morris, M.

2010-01-01

When an intermediate-mass star speeds through a dense interstellar cloud at a high velocity, it can produce a cometary or bow shock structure due to the cloud being impacted by the intense stellar wind. This class of objects, recently discovered in an HST imaging survey, has been dubbed "ballistic stellar interlopers" (Sahai et al. 2009). Using the ARO's 12m and SMT 10m millimeter-wave dishes, we have obtained molecular line emission data towards 10 stellar interloper sources, in order to identify and characterize the dense clouds with which the interlopers are interacting. We have made small "on-the-fly" maps in the 12CO (J=2-1) and 13CO (J=2-1) lines for each cloud, and obtained spectra of high-density tracers such as N2H+ (J=3-2), HCO+ (J=3-2), CN(N=2-1), and SO(J=5-4), which probe a range of physical conditions in the interstellar clouds being impacted by the interlopers. The data have been reduced and analyzed, and preliminary estimates of the cloud temperatures (9-22 K) and 13CO optical depths (0.18-0.37) have been made. The maps, which show the emission as a function of radial velocity and spatial offset from the location of the interlopers, have helped us distinguish between the clouds interacting with the interlopers, and those which are unrelated but happen to lie along the line of sight. These data will now enable us to carry out high-resolution mm-wave interferometric observations of the interlopers in the future. This research was performed at JPL under the Minority Education Initiatives program. RS and MM were funded by a Long Term Space Astrophysics award from NASA for this work. The National Radio Astronomy Observatory is a facility of the National Science Foundation operated under cooperative agreement by Associated Universities, Inc. Special thanks goes to John Bieging and Bill Peters of the Arizona Radio Observatory.

Nonequilibrium chemistry in shocked molecular clouds. [interstellar gases

NASA Technical Reports Server (NTRS)

Iglesias, E. R.; Silk, J.

1978-01-01

The gas-phase chemistry is studied behind a 10-km/s shock propagating into a dense molecular cloud. The principal conclusions are that: the concentrations of certain molecules (CO, NH3, HCN, N2) are unperturbed by the shock; other molecules (H2CO, CN, HCO(+)) are greatly decreased in abundance; and substantial amounts of H2O, HCO, and CH4 are produced. Approximately 1 million yr (independent of the density) must elapse after shock passage before chemical equilibrium is attained.

Researchers Use NRAO Telescope to Study Formation Of Chemical Precursors to Life

NASA Astrophysics Data System (ADS)

2006-08-01

In just two years of work, an international research team has discovered eight new complex, biologically-significant molecules in interstellar space using the National Science Foundation's Robert C. Byrd Green Bank Telescope (GBT) in West Virginia. "This is a feat unprecedented in the 35-year history of searching for complex molecules in space and suggests that a universal prebiotic chemistry is at work," said Jan M. Hollis of the NASA Goddard Space Flight Center, leader of the research team. Chemistry Cycle The Cosmic Chemistry Cycle CREDIT: Bill Saxton, NRAO/AUI/NSF Full Size Image Files Interactive Graphic With "Mouseover" Text Blocks Chemical Cycle Graphic (above image, JPEG, 129K) Graphic With Text Blocks (JPEG, 165K) High-Res TIFF (44.2M) High-Res TIFF With Text Blocks (44.2M) Green Bank Telescope and Molecule Diagrams (JPEG, 58K) Green Bank Telescope and Molecule Diagrams (TIFF, 21M) New Molecules: Chemical Diagrams (PDF, 64K) The new discoveries are helping scientists unlock the secrets of how the molecular precursors to life can form in the giant clouds of gas and dust in which stars and planets are born. "The first of the many chemical processes that ultimately led to life on Earth probably took place even before our planet was formed. The GBT has taken the leading role in exploring the origin of biomolecules in interstellar clouds," said Phil Jewell of the National Radio Astronomy Observatory (NRAO). The eight new molecules discovered with the GBT bring the total to 141 different molecular species found in interstellar space. About 90 percent of those interstellar molecules contain carbon, which is required for a molecule to be classified as organic. The newly-discovered molecules all contain carbon and are composed of 6 to 11 atoms each. These results suggest, the scientists say, that chemical evolution occurs routinely in the gas and dust from which stars and planets eventually are born. The mass of an interstellar cloud is 99 percent gas and one percent dust. The GBT discoveries have been made in just two prototypical interstellar clouds. The molecules acetamide (CH3CONH2), cyclopropenone (H2C3O), propenal (CH2CHCHO), propanal (CH3CH2CHO), and ketenimine (CH2CNH) were found in a cloud called Sagittarius B2(N), which is near the center of our Milky Way Galaxy some 26,000 light years from Earth. This star-forming region is the largest repository of complex interstellar molecules known. The molecules methyl-cyano-diacetylene (CH3C5N), methyl-triacetylene (CH3C6H), and cyanoallene (CH2CCHCN) were found in the Taurus Molecular Cloud (TMC-1), which is relatively nearby at a distance of 450 light years. The starless TMC-1 cloud is dark and cold with a temperature of only 10 degrees above absolute zero and may eventually evolve into a star-forming region. "The discovery of these large organic molecules in the coldest regions of the interstellar medium has certainly changed the belief that large organic molecules would only have their origins in hot molecular cores. It has forced us to rethink the paradigms of interstellar chemistry," said Anthony Remijan of the NRAO. These large molecules found with the GBT are built up from smaller ones, the scientists say, by two principal mechanisms. In the first, simple chemical reactions add an atom to a molecular structure residing on the surface of a dust grain. As an example of this process, the researchers cite a molecule called cyclopropenylidene (c-C3H2, where "c-" means cyclic), which contains three carbon atoms in a ring. Cyclopropenylidene was discovered in interstellar space in 1987, and is known to be highly reactive. In 2005, using the GBT, scientists discovered another molecule, cyclopropenone (c-H2C3O), which can be produced by adding an oxygen atom to cyclopropenylidene. The second method for constructing larger molecules from smaller ones involves neutral-radical reactions that can occur within the gas in an interstellar cloud. For example, in 2006, the scientists discovered acetamide (CH3CONH2), which can be formed when a previously-discovered neutral molecule called formamide (HCONH2) combines with radicals such as CH2 and CH3, also previously discovered. Acetamide is particularly interesting because it contains a peptide bond which is the means for linking amino acids together to form proteins. Once interstellar molecules are ejected from dust grains into the gas phase, presumably by shock waves, they are free to rotate end-over-end. As gas molecules change their rotational modes, they can emit or absorb radiation at precise radio frequencies, called transitions, that are unique to each type of molecule. By detecting several rotational transitions, astronomers can unambiguously identify a specific interstellar molecule. "It is important to note that likely interstellar molecule candidates are first studied in gas-phase laboratory experiments so that transition frequencies are known in advance of an interstellar experiment," said Frank Lovas of the National Institute of Standards and Technology. Along the line of sight from the interstellar cloud to the telescope, thousands of billions of molecules undergo the exact same transition, producing a signal strong enough to be detected by sensitive equipment. For this type of work, the GBT is the world's most sensitive tool that can be accurately pointed and track astronomical objects. In addition to Hollis, Jewell, Remijan, and Lovas, the research team included Lewis Snyder of the University of Illinois; Harald Mollendal of the University of Oslo, Norway; Vadim Ilyushin of the Institute of Radio Astronomy of the National Academy of Sciences of the Ukraine; and Isabell Kleiner of the Universite Paris, France. The astronomers' reports on their results appeared in 8 separate editions of the Astrophysical Journal. The National Radio Astronomy Observatory is a facility of the National Science Foundation, operated under cooperative agreement by Associated Universities, Inc.

Interstellar Ice and Dust: The Feedstock of the Solar System

NASA Technical Reports Server (NTRS)

Allamandola, L. J.; Morrison, David (Technical Monitor)

1994-01-01

Studying the chemical and isotopic composition of interstellar ice and dust provides insight into the composition and chemical history of the solid bodies in the solar nebula and the nature of the material subsequently brought into the inner part of the solar system by comets and meteorites. It is now possible to probe the composition of these microscopic interstellar particles (some hundreds of light years away), thanks to substantial progress in two areas: astronomical spectroscopic techniques in the middle-infrared, the spectral region most diagnostic of composition; and laboratory simulations which realistically reproduce the critical conditions in various interstellar environments. High quality infrared spectra of many different astronomical sources, some associated with dark molecular clouds, and others in the diffuse interstellar medium (DISM) are now available. What comparisons of these spectra with laboratory spectra tell us about the complex organic components of these materials is the subject of this talk. Most interstellar material is concentrated in large molecular clouds where simple molecules are formed by gas phase and dust grain surface reactions. Gaseous species (except H2) striking the cold (10K) dust will stick, forming an icy grain mantle. This accretion, coupled with energetic particle bombardment and UV photolysis, will produce a complex chemical mixture containing volatile, non-volatile, and isotopically fractionated species. One can compare spectra of the diffuse and dense interstellar medium with the spectra of analogs produced in the laboratory under conditions which mimic those in these different environments. In this way one can determine the composition and abundances of the major constituents present and place general constraints on the types and relative abundances of organics coating the grains. Ices in dense clouds contain H2O, CH3OH, CO, perhaps some NH3 and H2CO, as well as nitriles and ketones or esters. There is some evidence that the later, more complex species, are also present on the grains in the DISM. The evidence for these materials, in addition to carbon rich materials such as amorphous carbon, microdiamonds, and polycyclic aromatic hydrocarbons will be reviewed and the possible connection with meteoritic organics will be discussed.

Extinction and Star Formation Study in Molecular Clouds with DENIS infrared data and USNO optical data

NASA Astrophysics Data System (ADS)

Cambrésy, Laurent

1999-11-01

This thesis consists in a study of molecular clouds, essentially of the point of view of the interstellar environment, but also of the one of the star formation. The original method to estimate extinction presented here is based on adaptive star counts as well as on a wavelet decomposition. For the first time, an extinction map of the whole sky is proposed (USNO-PMM optical data). Access to very large field maps offers the opportunity to analyze the interstellar matter distribution in various environments. A first result is that the contained mass in regions for which AV > 1 would not exceed half of the total cloud mass. Using DENIS data, it becomes possible to probe dense regions of clouds. For instance, star counts in the Chamaeleon complex show cores which were not resolved before. Moreover, the selection of stars with a strong infrared excess yields about fifty T Tauri candidates. From their luminosity function, I derived the average lifetime of circumstellar disc of low--mass stars: ~4cdot 106 years. It is difficult to understand the relation between extinction and molecular emission, but it appears clearly that molecular emission is a bad estimator of the column density for low extinction area. Actually, thresholds exist in the CO detection and I conclude that photodissociation, density and cloud geometry have important consequences on the CO emission when AV < 2. Investigation of the relation between extinction and far--infrared emission in Polaris leads to a four times larger emissivity in cold areas than in hot areas. This result explains the low temperatures in this cloud and implies severe restrictions concerning the use of far--infrared fluxes as an extinction estimator.

Copernicus studies of interstellar material in the Perseus II complex. III - The line of sight to Zeta Persei

NASA Technical Reports Server (NTRS)

Snow, T. P., Jr.

1977-01-01

Ultraviolet spectrophotometric data obtained with Copernicus are used to analyze the distribution, composition, density, temperature, and kinematics of the interstellar material along the line of sight to Zeta Persei. The far-UV extinction curve for the star is evaluated along with the kinematics of the interstellar gas, observations of atomic and molecular hydrogen, curves of growth for neutral and ionized species, atomic abundances and depletions, ionization equilibria, and observations of CO and OH lines. The results show that there are apparently three clouds along the line of sight to Zeta Persei: a main cloud at approximately +13 km/s which contains most of the material and forms all the neutral and molecular lines as well as most of the ionic lines, a second component at +22 km/s which must contribute to the strong UV lines of most ions, and a third component at roughly +2 km/s which gives rise to a strong Si III line at 1206 A. It is also found that the UV extinction curve has a somewhat steep far-UV rise, indicating the presence of a substantial number of small grains, and that about 30% of the hydrogen nuclei over the entire line of sight are in molecular form.

The origin and evolution of dust in interstellar and circumstellar environments

NASA Technical Reports Server (NTRS)

Whittet, Douglas C. B.; Leung, Chun M.

1993-01-01

This status report covers the period from the commencement of the research program on 1 Jul. 1992 through 30 Apr. 1993. Progress is reported for research in the following areas: (1) grain formation in circumstellar envelopes; (2) photochemistry in circumstellar envelopes; (3) modeling ice features in circumstellar envelopes; (4) episodic dust formation in circumstellar envelopes; (5) grain evolution in the diffuse interstellar medium; and (6) grain evolution in dense molecular clouds.

Galactic Observations of Terahertz C+ (GOT C+): Inner Galaxy Survey

NASA Astrophysics Data System (ADS)

Yorke, Harold; Langer, William; Velusamy, T.; Pineda, J. L.; Goldsmith, P. F.; Li, D.

To understand the lifecycle of the interstellar gas and star formation we need detailed information about the diffuse atomic and diffuse molecular gas cloud properties. The ionized carbon [CII] 1.9 THz fine structure line is an important tracer of the atomic gas in the diffuse regions and the interface regions of atomic gas to molecular clouds. Furthermore, C+ is a major ISM coolant and among the Galaxy's strongest far-IR emission lines, and thus controls the thermal conditions throughout large parts of the Galaxy. Until now our knowledge of interstellar gas has been limited to the diffuse atomic phase traced by HI and to the dense molecular H2 phase traced by CO. However, we are missing an important phase of the ISM, called "dark gas" in which there is no or little, HI, and mostly molecular hydrogen but with insufficient shielding of UV to allow CO to form. C+ emission and absorption lines at 1.9 THz have the potential to trace such cloud transitions and evolution. Galactic Observations of the Terahertz C+ Line (GOT C+) is a Herschel Space Observatory Open Time Key Program to study the diffuse interstellar medium by sampling [CII] 1.9 THz line emission throughout the Galactic disk. We discuss the broader perspective of this survey and the first results of GOT C+ obtained during the Science Demonstration Phase (SDP) and Priority Science Phase (PSP) of HIFI, which focus on approximately 100 lines of sight in the inner galaxy. These observations are being carried out with the Herschel Space Observatory, which is an ESA cornerstone mission, with contributions from NASA. This research was conducted at the Jet Propulsion Laboratory, California Institute of Technology under contract with the National Aeronautics and Space Administration. JLP is a Caltech-JPL Postdoctoral Associate.

Laboratory Investigations of the Physical and Optical Properties of the Analogs of Individual Cosmic Dust Grains

NASA Technical Reports Server (NTRS)

Abbas, M. M.; Tankosic, D.; Craven, P. D.; Spann, J. F.; LeClair, A.; West, E. A.

2005-01-01

Microdsub-micron size cosmic dust grains play an important role in the physical and dynamical process in the galaxy, the interstellar medium, and the interplanetary and planetary environments. The dust grains in various astrophysical environments are generally charged by a variety of mechanisms that include collisional process with electrons and ions, and photoelectric emissions with UV radiation. The photoelectric emission process is believed to be the dominant process in many astrophysical environments with nearby UV sources, such as the interstellar medium, diffuse clouds, the outer regions of the dense molecular clouds, interplanetary medium, dust in planetary environments and rings, cometary tails, etc. Also, the processes and mechanisms involved in the rotation and alignment of interstellar dust grains are of great interest in view of the polarization of observed starlight as a probe for evaluation of the galactic magnetic field.

Environmental Catastrophes in the Earth's History Due to Solar Systems Encounters with Giant Molecular Clouds

NASA Technical Reports Server (NTRS)

Pavlov, Alexander A.

2011-01-01

In its motion through the Milky Way galaxy, the solar system encounters an average density (>=330 H atoms/cubic cm) giant molecular cloud (GMC) approximately every 108 years, a dense (approx 2 x 103 H atoms/cubic cm) GMC every approx 109 years and will inevitably encounter them in the future. However, there have been no studies linking such events with severe (snowball) glaciations in Earth history. Here we show that dramatic climate change can be caused by interstellar dust accumulating in Earth's atmosphere during the solar system's immersion into a dense (approx ,2 x 103 H atoms/cubic cm) GMC. The stratospheric dust layer from such interstellar particles could provide enough radiative forcing to trigger the runaway ice-albedo feedback that results in global snowball glaciations. We also demonstrate that more frequent collisions with less dense GMCs could cause moderate ice ages.

Are CO Observations of Interstellar Clouds Tracing the H2?

NASA Astrophysics Data System (ADS)

Federrath, Christoph; Glover, S. C. O.; Klessen, R. S.; Mac Low, M.

2010-01-01

Interstellar clouds are commonly observed through the emission of rotational transitions from carbon monoxide (CO). However, the abundance ratio of CO to molecular hydrogen (H2), which is the most abundant molecule in molecular clouds is only about 10-4. This raises the important question of whether the observed CO emission is actually tracing the bulk of the gas in these clouds, and whether it can be used to derive quantities like the total mass of the cloud, the gas density distribution function, the fractal dimension, and the velocity dispersion--size relation. To evaluate the usability and accuracy of CO as a tracer for H2 gas, we generate synthetic observations of hydrodynamical models that include a detailed chemical network to follow the formation and photo-dissociation of H2 and CO. These three-dimensional models of turbulent interstellar cloud formation self-consistently follow the coupled thermal, dynamical and chemical evolution of 32 species, with a particular focus on H2 and CO (Glover et al. 2009). We find that CO primarily traces the dense gas in the clouds, however, with a significant scatter due to turbulent mixing and self-shielding of H2 and CO. The H2 probability distribution function (PDF) is well-described by a log-normal distribution. In contrast, the CO column density PDF has a strongly non-Gaussian low-density wing, not at all consistent with a log-normal distribution. Centroid velocity statistics show that CO is more intermittent than H2, leading to an overestimate of the velocity scaling exponent in the velocity dispersion--size relation. With our systematic comparison of H2 and CO data from the numerical models, we hope to provide a statistical formula to correct for the bias of CO observations. CF acknowledges financial support from a Kade Fellowship of the American Museum of Natural History.

A survey of interstellar neutral potassium. I - Abundances and physical conditions in clouds toward 188 early-type stars

NASA Technical Reports Server (NTRS)

Chaffee, F. H., Jr.; White, R. E.

1982-01-01

Observations of interstellar absorption in the resonance doublet 7664, 7698 A of neutral potassium toward 188 early-type stars at a spectral resolution of 8 km/s are reported. The 7664 A line is successfully separated from nearly coincident telluric O2 absorption for all but a few of the 165 stars for which K I absorption is detected, making possible an abundance analysis by the doublet ratio method. The relationships between the potassium abundances and other atomic abundances, the abundance of molecular hydrogen, and interstellar reddening are investigated.

Modeling the chemistry of the dense interstellar clouds. I - Observational constraints for the chemistry

NASA Technical Reports Server (NTRS)

Federman, S. R.; Huntress, W. T., Jr.; Prasad, S. S.

1990-01-01

A search for correlations arising from molecular line data is made in order to place constraints on the chemical models of interstellar clouds. At 10 to the 21st H2/sq cm, N(CO) for dark clouds is a factor of six greater than the value for diffuse clouds. This implies that the strength of the UV radiation field where CO shields itself from dissociation is about one-half the strength of the average Galactic field. The dark cloud data indicate that the abundance of CO continues to increase with A(V) for directions with A(V) of 4 mag or less, although less steeply with N(H2) than for diffuse clouds. For H2CO, a quadratic relationship is obtained in plots versus H2 column density. The data suggest a possible turnover at the highest values for A(V). NH3 shows no correlation with H2, C(O-18), HC3N, or HC5N; a strong correlation is found between HC5N and HC3N, indicating a chemical link between the cyanopolyynes.

Low-temperature surface formation of NH3 and HNCO: hydrogenation of nitrogen atoms in CO-rich interstellar ice analogues

NASA Astrophysics Data System (ADS)

Fedoseev, G.; Ioppolo, S.; Zhao, D.; Lamberts, T.; Linnartz, H.

2015-01-01

Solid-state astrochemical reaction pathways have the potential to link the formation of small nitrogen-bearing species, like NH3 and HNCO, and prebiotic molecules, specifically amino acids. To date, the chemical origin of such small nitrogen-containing species is still not well understood, despite the fact that ammonia is an abundant constituent of interstellar ices towards young stellar objects and quiescent molecular clouds. This is mainly because of the lack of dedicated laboratory studies. The aim of this work is to experimentally investigate the formation routes of NH3 and HNCO through non-energetic surface reactions in interstellar ice analogues under fully controlled laboratory conditions and at astrochemically relevant temperatures. This study focuses on the formation of NH3 and HNCO in CO-rich (non-polar) interstellar ices that simulate the CO freeze-out stage in dark interstellar cloud regions, well before thermal and energetic processing start to become relevant. We demonstrate and discuss the surface formation of solid HNCO through the interaction of CO molecules with NH radicals - one of the intermediates in the formation of solid NH3 upon sequential hydrogenation of N atoms. The importance of HNCO for astrobiology is discussed.

The efficiency of photodissociation for molecules in interstellar ices

NASA Astrophysics Data System (ADS)

Kalvāns, J.

2018-05-01

Processing by interstellar photons affects the composition of the icy mantles on interstellar grains. The rate of photodissociation in solids differs from that of molecules in the gas phase. The aim of this work was to determine an average, general ratio between photodissociation coefficients for molecules in ice and gas. A 1D astrochemical model was utilized to simulate the chemical composition for a line of sight through a collapsing interstellar cloud core, whose interstellar extinction changes with time. At different extinctions, the calculated column densities of icy carbon oxides and ammonia (relative to water ice) were compared to observations. The latter were taken from literature data of background stars sampling ices in molecular clouds. The best-fit value for the solid/gas photodissociation coefficient ratio was found to be ≈0.3. In other words, gas-phase photodissociation rate coefficients have to be reduced by a factor of 0.3 before applying them to icy species. A crucial part of the model is a proper inclusion of cosmic-ray induced desorption. Observations sampling gas with total extinctions in excess of ≈22 mag were found to be uncorrelated to modelling results, possibly because of grains being covered with non-polar molecules.

Reduction of unsaturated compounds under interstellar conditions: chemoselective reduction of C≡C and C=C bonds over C=O functional group

NASA Astrophysics Data System (ADS)

Jonusas, Mindaugas; Guillemin, Jean-Claude; Krim, Lahouari

2017-07-01

The knowledge of the H-addition reactions on unsaturated organic molecules bearing a triple or a double carbon-carbon bond such as propargyl or allyl alcohols and a CO functional group such as propynal, propenal or propanal may play an important role in the understanding of the chemical complexity of the interstellar medium. Why different aldehydes like methanal, ethanal, propynal and propanal are present in dense molecular clouds while the only alcohol detected in those cold regions is methanol? In addition, ethanol has only been detected in hot molecular cores. Are those saturated and unsaturated aldehyde and alcohol species chemically linked in molecular clouds through solid phase H-addition surface reactions or are they formed through different chemical routes? To answer such questions, we have investigated a hydrogenation study of saturated and unsaturated aldehydes and alcohols at 10 K. We prove through this experimental study that while pure unsaturated alcohol ices bombarded by H atoms lead to the formation of the corresponding fully or partially saturated alcohols, surface H-addition reactions on unsaturated aldehyde ices exclusively lead to the formation of fully saturated aldehyde. Such results show that in addition to a chemoselective reduction of C≡C and C=C bonds over the C=O group, there is no link between aldehydes and their corresponding alcohols in reactions involving H atoms in dense molecular clouds. Consequently, this could be one of the reasons why some aldehydes such as propanal are abundant in dense molecular clouds in contrast to the non-detection of alcohol species larger than methanol.

Cyanide and isocyanide abundances in the cold, dark cloud TMC-1

NASA Technical Reports Server (NTRS)

Irvine, W. M.; Schloerb, F. P.

1984-01-01

Cold, dark molecular clouds are particularly useful for the study of interstellar chemistry because their physical parameters are better understood than those of heterogeneous, complex giant molecular clouds. Another advantage is their relatively small distance from the solar system. The present investigaation has the objective to provide accurate abundance ratios for several cyanides and isocyanides in order to constrain models of dark cloud chemistry. The relative abundances of such related species can be particularly useful for the study of chemical processes. The cloud TMC-1 considered in the current study has a remarkably high abundance of acetylene and polyacetylene derivatives. Data at 3 mm, corresponding to the J = 1 to 0 transitions of HCN, H(C-13)N, HN(C-13), HC(N-15), and H(N-15)C were obtained.

SHOCKFIND - an algorithm to identify magnetohydrodynamic shock waves in turbulent clouds

NASA Astrophysics Data System (ADS)

Lehmann, Andrew; Federrath, Christoph; Wardle, Mark

2016-11-01

The formation of stars occurs in the dense molecular cloud phase of the interstellar medium. Observations and numerical simulations of molecular clouds have shown that supersonic magnetized turbulence plays a key role for the formation of stars. Simulations have also shown that a large fraction of the turbulent energy dissipates in shock waves. The three families of MHD shocks - fast, intermediate and slow - distinctly compress and heat up the molecular gas, and so provide an important probe of the physical conditions within a turbulent cloud. Here, we introduce the publicly available algorithm, SHOCKFIND, to extract and characterize the mixture of shock families in MHD turbulence. The algorithm is applied to a three-dimensional simulation of a magnetized turbulent molecular cloud, and we find that both fast and slow MHD shocks are present in the simulation. We give the first prediction of the mixture of turbulence-driven MHD shock families in this molecular cloud, and present their distinct distributions of sonic and Alfvénic Mach numbers. Using subgrid one-dimensional models of MHD shocks we estimate that ˜0.03 per cent of the volume of a typical molecular cloud in the Milky Way will be shock heated above 50 K, at any time during the lifetime of the cloud. We discuss the impact of this shock heating on the dynamical evolution of molecular clouds.

Synthesis and chirality of amino acids under interstellar conditions.

PubMed

Giri, Chaitanya; Goesmann, Fred; Meinert, Cornelia; Evans, Amanda C; Meierhenrich, Uwe J

2013-01-01

Amino acids are the fundamental building blocks of proteins, the biomolecules that provide cellular structure and function in all living organisms. A majority of amino acids utilized within living systems possess pre-specified orientation geometry (chirality); however the original source for this specific orientation remains uncertain. In order to trace the chemical evolution of life, an appreciation of the synthetic and evolutional origins of the first chiral amino acids must first be gained. Given that the amino acids in our universe are likely to have been synthesized in molecular clouds in interstellar space, it is necessary to understand where and how the first synthesis might have occurred. The asymmetry of the original amino acid synthesis was probably the result of exposure to chiral photons in the form of circularly polarized light (CPL), which has been detected in interstellar molecular clouds. This chirality transfer event, from photons to amino acids, has been successfully recreated experimentally and is likely a combination of both asymmetric synthesis and enantioselective photolysis. A series of innovative studies have reported successful simulation of these environments and afforded production of chiral amino acids under realistic circumstellar and interstellar conditions: irradiation of interstellar ice analogues (CO, CO2, NH3, CH3OH, and H2O) with circularly polarized ultraviolet photons at low temperatures does result in enantiomer enriched amino acid structures (up to 1.3% ee). This topical review summarizes current knowledge and recent discoveries about the simulated interstellar environments within which amino acids were probably formed. A synopsis of the COSAC experiment onboard the ESA cometary mission ROSETTA concludes this review: the ROSETTA mission will soft-land on the nucleus of the comet 67P/Churyumov-Gerasimenko in November 2014, anticipating the first in situ detection of asymmetric organic molecules in cometary ices.

The interstellar chemistry of H2C3O isomers

PubMed Central

Loison, Jean-Christophe; Agúndez, Marcelino; Marcelino, Núria; Wakelam, Valentine; Hickson, Kevin M.; Cernicharo, José; Gerin, Maryvonne; Roueff, Evelyne; Guélin, Michel

2016-01-01

We present the detection of two H2C3O isomers, propynal and cyclopropenone, toward various starless cores and molecular clouds, together with upper limits for the third isomer propadienone. We review the processes controlling the abundances of H2C3O isomers in interstellar media showing that the reactions involved are gas-phase ones. We show that the abundances of these species are controlled by kinetic rather than thermodynamic effects. PMID:27013768

CNO isotopes in red giant stars

NASA Technical Reports Server (NTRS)

Wannier, P. G.

1985-01-01

The production and distribution of the CNO nuclides is discussed in light of observed abundance ratios in red giants and in the interstellar medium. Isotope abundances have been measured in the atmospheres and in the recent ejecta of cool giants, including carbon stars, S-type stars and red supergiants as well as in oxygen-rich giants making their first ascent of the giant branch. Several of the observations suggest revision of currently accepted nuclear cross-sections and of the mixing processes operating in giant envelopes. By comparing red giant abundances with high-quality observations of the interstellar medium, conclusions are reached about the contribution of intermediate-mass stars to galactic nuclear evolution. The three oxygen isotopes, O-16, -17 and -18, are particularly valuable for such comparison because they reflect three different stages of stellar nucleosynthesis. One remarkable result comes from observations of O-17/O-18 in several classes of red giant stars. The observed range of values for red giants excludes the entire range of values seen in interstellar molecular clouds. Furthermore, both the observations of stars and interstellar clouds exclude the isotopic ratio found in the solar system.

H2 spectroscopy as an agent for extinction determinations The near-infrared curve for the Orion molecular cloud

NASA Technical Reports Server (NTRS)

Davis, D. S.; Larson, H. P.; Hofmann, R.

1986-01-01

A near-infrared (1.8 to 3.5) microns extinction curve for the Orion molecular cloud is presented. The curve is derived from high-resolution spectra of the Orion H2 source recorded from the Kuiper Airborne Observatory. The data reveal that the Orion extinction law is indistinguishable from a 1/lambda form in the near-infrared, except for strongly enhanced extinction near a wavelength of about 3 microns. The implications of these results, in the context of current interstellar grain models, are discussed.

Astrophysical radiation environments of habitable worlds

NASA Astrophysics Data System (ADS)

Smith, David Samuel

Numerous astrophysical sources of radiation affect the environment of planets orbiting within the liquid-water habitable zone of main-sequence stars. This dissertation reaches a number of conclusions about the ionizing radiation environment of the habitable zone with respect to X-rays and gamma-rays from stellar flares and background Galactic cosmic rays. Gamma-rays and X-rays incident on terrestrial-like exoplanet atmospheres can be efficiently reprocessed into diffuse UV emission that, depending on the presence of atmospheric UV absorbers, can reach the surface. Extreme solar X-ray flares over the last 4.6 Gyr could have delivered large enough radiation doses to the Martian surface to sterilize any unprotected organisms, depending on the largest energy releases possible. These flares also pose a significant hazard to manned space missions, since a large flare can occur with little or no warning during an extravehicular activity. A flare as large as the largest observed could deliver radiation doses exceeding safety limits to an astronaut protected by only a spacesuit. With respect to particle radiation, the nature of Galactic cosmic-ray modulation by astrospheres means that habitable-zone cosmic-ray fluxes change by much larger magnitudes when passing through low- densities regions of the interstellar medium. In contrast to the popular idea that passages through dense molecular clouds are required to significantly enhance Galactic cosmic-ray fluxes and affect planets' electrical circuits, background mutation rates, and climates, we find that densities of only 0.1-10 cm -3 , the densities of most interstellar clouds, are sufficient to bring fluxes close to the full, interstellar level. Finally, passages through dense molecular clouds are necessary to shrink astrospheres to within the habitable zone, but such events produce even higher interstellar hydrogen and dust accretion rates than have been estimated because of the combination of enhanced charge-exchange rates between stellar-wind ions and interstellar neutrals and the growing importance of the central star's gravity on particle trajectories as the astrosphere shrinks.

Ice Chemistry in Starless Molecular Cores

NASA Astrophysics Data System (ADS)

Kalvāns, J.

2015-06-01

Starless molecular cores are natural laboratories for interstellar molecular chemistry research. The chemistry of ices in such objects was investigated with a three-phase (gas, surface, and mantle) model. We considered the center part of five starless cores, with their physical conditions derived from observations. The ice chemistry of oxygen, nitrogen, sulfur, and complex organic molecules (COMs) was analyzed. We found that an ice-depth dimension, measured, e.g., in monolayers, is essential for modeling of chemistry in interstellar ices. Particularly, the H2O:CO:CO2:N2:NH3 ice abundance ratio regulates the production and destruction of minor species. It is suggested that photodesorption during the core-collapse period is responsible for the high abundance of interstellar H2O2 and O2H and other species synthesized on the surface. The calculated abundances of COMs in ice were compared to observed gas-phase values. Smaller activation barriers for CO and H2CO hydrogenation may help explain the production of a number of COMs. The observed abundance of methyl formate HCOOCH3 could be reproduced with a 1 kyr, 20 K temperature spike. Possible desorption mechanisms, relevant for COMs, are gas turbulence (ice exposure to interstellar photons) or a weak shock within the cloud core (grain collisions). To reproduce the observed COM abundances with the present 0D model, 1%-10% of ice mass needs to be sublimated. We estimate that the lifetime for starless cores likely does not exceed 1 Myr. Taurus cores are likely to be younger than their counterparts in most other clouds.

Synthetic observations of molecular clouds in a galactic centre environment - I. Studying maps of column density and integrated intensity

NASA Astrophysics Data System (ADS)

Bertram, Erik; Glover, Simon C. O.; Clark, Paul C.; Ragan, Sarah E.; Klessen, Ralf S.

2016-02-01

We run numerical simulations of molecular clouds, adopting properties similar to those found in the central molecular zone (CMZ) of the Milky Way. For this, we employ the moving mesh code AREPO and perform simulations which account for a simplified treatment of time-dependent chemistry and the non-isothermal nature of gas and dust. We perform simulations using an initial density of n0 = 103 cm-3 and a mass of 1.3 × 105 M⊙. Furthermore, we vary the virial parameter, defined as the ratio of kinetic and potential energy, α = Ekin/|Epot|, by adjusting the velocity dispersion. We set it to α = 0.5, 2.0 and 8.0, in order to analyse the impact of the kinetic energy on our results. We account for the extreme conditions in the CMZ and increase both the interstellar radiation field (ISRF) and the cosmic ray flux (CRF) by a factor of 1000 compared to the values found in the solar neighbourhood. We use the radiative transfer code RADMC-3D to compute synthetic images in various diagnostic lines. These are [C II] at 158 μm, [O I] (145 μm), [O I] (63 μm), 12CO (J = 1 → 0) and 13CO (J = 1 → 0) at 2600 and 2720 μm, respectively. When α is large, the turbulence disperses much of the gas in the cloud, reducing its mean density and allowing the ISRF to penetrate more deeply into the cloud's interior. This significantly alters the chemical composition of the cloud, leading to the dissociation of a significant amount of the molecular gas. On the other hand, when α is small, the cloud remains compact, allowing more of the molecular gas to survive. We show that in each case the atomic tracers accurately reflect most of the physical properties of both the H2 and the total gas of the cloud and that they provide a useful alternative to molecular lines when studying the interstellar medium in the CMZ.

Massive stars: privileged sources of cosmic-rays for interstellar astrochemistry

NASA Astrophysics Data System (ADS)

De Becker, M.

2015-01-01

Massive stars can be considered as crucial engines for interstellar physics. They are indeed the main providers of UV radiation field, and constitute a substantial source of chemical enrichment. On their evolution time-scale (at most about 10 Myr), they typically stay close to their formation site, i.e. close to molecular clouds very rich in interstellar molecules. These stellar objects have also the property to be involved in particle acceleration processes leading to the production of high energy charged particles (cosmic-rays). After rejection in the interstellar medium, these particles will play a substantial role in processes such as those simulated in various facilities dedicated to experimental astrochemistry. This short contribution intends to put these particles, crucial for astrochemistry, in their adequate astrophysical context.

Three milieux for interstellar chemistry: gas, dust, and ice

NASA Astrophysics Data System (ADS)

Herbst, Eric

The interdisciplinary science of astrochemistry is 45 years of age, if we pinpoint its origin to have occurred when the first polyatomic molecules were detected in the interstellar gas. Since that time, the field has grown remarkably from an esoteric area of research to one that unites scientists around the globe. Almost 200 different molecules have been detected in the gas-phase of interstellar clouds, mainly by rotational spectroscopy, while dust particles and their icy mantles in colder regions can be probed by vibrational spectroscopy. Astrochemistry is exciting to scientists in a number of different fields. Astronomers are interested in molecular spectra from the heavens because such spectra are excellent probes of the physical conditions where molecules exist, while chemists are interested in the exotic molecules, their spectra, and the unusual chemical processes that produce and destroy them under conditions often very different from those on our home planet. Chemical simulations involving thousands of reactions are now used to calculate concentrations and spectra of interstellar molecules as functions of time. Even biologists share an interest in the subject, because the interstellar clouds of gas and dust, portions of which collapse to form stars and planetary systems, contain organic molecules that may become part of the initial inventory of new planets and may indeed be the precursors of life. An irresistible subject to its practitioners, astrochemistry is proving to be exciting to a much wider audience. In this perspective article, the field is first introduced, and the emphasis is then placed on the three environments in which chemistry occurs in the interstellar medium: the gas phase, the surfaces of bare dust particles, and the ice mantles that cover bare grains in cold dense interstellar clouds. What we do know and what we do not know is distinguished. The status of chemical simulations for a variety of interstellar sources having to do with stellar and planetary evolution is surveyed. An optimistic view of the future of astrochemistry ends the article.

High Abundance of Ions in Cosmic Ices

NASA Technical Reports Server (NTRS)

Gudipati, Murthy S.; Allamandola, Louis J.; Fonda, Mark (Technical Monitor)

2002-01-01

Water-rich, mixed molecular ices and polycyclic aromatic hydrocarbons (PAHs) are common throughout interstellar molecular clouds and the Solar System. Vacuum ultraviolet (VUV) irradiation and particle bombardment of these abiotic ices produces complex organic species, including important biogenic molecules such as amino acids and functionalized PAHs which may have played a role in the origin of life. This ability of such water-rich, oxygen dominated ices to promote production of complex organic species is surprising and points to an important, unusual, but previously overlooked mechanism at play within the ice. Here we report the nature of this mechanism using electronic spectroscopy. VUV-irradiation of PAH/H2O ices leads to an unprecedented and efficient (greater than 70 %) conversion of the neutral PAHs to their cation form (PAH+). Further, these H2O/PAH+ ices are stabile at temperatures below 50 K, a temperature domain common throughout interstellar clouds and the Solar System. Between 50 and 125 K they react to form the complex organics. In view of this, we conclude that charged PAHs and other molecular ions should be common and abundant in many cosmic ices. The chemical, spectroscopic and physical properties of these ion-rich ices can be of fundamental importance for objects as diverse as comets, planets, and molecular clouds and may account for several poorly understood phenomena associated with each of these object classes.

The Exobiological Role of Interstellar Polycyclic Aromatic Hydrocarbons and Ices

NASA Technical Reports Server (NTRS)

Hudgins, Douglas M.; DeVincenzi, Donald (Technical Monitor)

2002-01-01

Tremendous strides have been made in our understanding of interstellar material over the past twenty years thanks to significant, parallel developments in observational astronomy and laboratory astrophysics. Before this time, the composition of interstellar dust was largely guessed-at, the presence of ices in interstellar clouds ignored, and the notion that large, gas phase, carbon rich molecules might be abundant and widespread throughout the interstellar medium (ISM) considered impossible. Today, the composition of dust in the ISM is reasonably well constrained to micron-sized cold refractory materials comprised of amorphous and crystalline silicates mixed with an amorphous carbonaceous material containing aromatic structural units and short, branched aliphatic chains. Shrouded within the protective confines of cold, opaque molecular clouds--the birthplace of stars and planets--these cold dust particles secrete mantles of mixed molecular ices whose compositions are also well constrained. Finally, amidst the molecular inventory of these ice mantles are likely to be found polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by the standards of interstellar chemistry, the telltale infrared spectral signature of which is now recognized throughout the Universe. In the first part of this talk, we will review the spectroscopic evidence that forms the basis for the currently accepted abundance and ubiquity of PANs in the ISM. We will then look at a few specific examples which illustrate how experimental and theoretical data can be applied to interpret the interstellar spectra and track how the PAN population evolves as it passes from its formation site in the circumstellar outflows of dying stars, through the various phases of the ISM, and into forniing planetary systems. Nevertheless, despite the fact that PANs likely represent the single largest molecular reservoir of organic carbon in evolving planetary systems, they are not what would be considered "biogenic" molecules. Although interesting from a chemical and astrophysical standpoint, in the absence of a mechanism by which this population can be dislodged from the precipitous thermodynamic well afforded by their extensive aromatic networks, they are of little Astrobiological significance. Consequently, for the remainder of the talk, we will consider the photochemical evolution of PANS under conditions similar to those found in the ISM and in proto-planetary systems with an eye toward means by which this rich repository of pre-biotic organic "ore" might be converted into materials of greater importance to Astrobiology.

Molecules as diagnostic tools in the interstellar medium

NASA Astrophysics Data System (ADS)

Spielfiedel, A.; Feautrier, N.; Balança, C.; Dayou, F.; Lique, F.; Senent, M.-L.

Analysis of light emission from different regions of the interstellar medium and circumstellar environments provides crucial information about the chemical composition and the physical conditions in these regions. Interpretation of the observed spectra requires the knowledge of collisional excitation rates as well as radiative rates participating to the line formation. In the first part, the paper focuses on collisional excitation rates of molecules relevant to the interstellar medium. It discusses currently available data and outlines new work carried out by the authors. Due to the use of accurate ab initio potential energy surfaces, the new rate coefficients differ significantly from previously published ones. In the second part, it is analysed from two examples how the use of the new rate coefficients could lead to important changes in the interpretation of molecular emission emerging from molecular clouds.

The interstellar medium and star formation of galactic disks. I. Interstellar medium and giant molecular cloud properties with diffuse far-ultraviolet and cosmic-ray backgrounds

NASA Astrophysics Data System (ADS)

Li, Qi; Tan, Jonathan C.; Christie, Duncan; Bisbas, Thomas G.; Wu, Benjamin

2018-05-01

We present a series of adaptive mesh refinement hydrodynamic simulations of flat rotation curve galactic gas disks, with a detailed treatment of the interstellar medium (ISM) physics of the atomic to molecular phase transition under the influence of diffuse far-ultraviolet (FUV) radiation fields and cosmic-ray backgrounds. We explore the effects of different FUV intensities, including a model with a radial gradient designed to mimic the Milky Way. The effects of cosmic rays, including radial gradients in their heating and ionization rates, are also explored. The final simulations in this series achieve 4 pc resolution across the ˜20 kpc global disk diameter, with heating and cooling followed down to temperatures of ˜10 K. The disks are evolved for 300 Myr, which is enough time for the ISM to achieve a quasi-statistical equilibrium. In particular, the mass fraction of molecular gas is stabilized by ˜200 Myr. Additional global ISM properties are analyzed. Giant molecular clouds (GMCs) are also identified and the statistical properties of their populations are examined. GMCs are tracked as the disks evolve. GMC collisions, which may be a means of triggering star cluster formation, are counted and their rates are compared with analytic models. Relatively frequent GMC collision rates are seen in these simulations, and their implications for understanding GMC properties, including the driving of internal turbulence, are discussed.

Time scales for molecule formation by ion-molecule reactions

NASA Technical Reports Server (NTRS)

Langer, W. D.; Glassgold, A. E.

1976-01-01

Analytical solutions are obtained for nonlinear differential equations governing the time-dependence of molecular abundances in interstellar clouds. Three gas-phase reaction schemes are considered separately for the regions where each dominates. The particular case of CO, and closely related members of the Oh and CH families of molecules, is studied for given values of temperature, density, and the radiation field. Nonlinear effects and couplings with particular ions are found to be important. The time scales for CO formation range from 100,000 to a few million years, depending on the chemistry and regime. The time required for essentially complete conversion of C(+) to CO in the region where the H3(+) chemistry dominates is several million years. Because this time is longer than or comparable to dynamical time scales for dense interstellar clouds, steady-state abundances may not be observed in such clouds.

The formation of molecules in interstellar clouds from singly and multiply ionized atoms

NASA Technical Reports Server (NTRS)

Langer, W. D.

1978-01-01

The suggestion is considered that multiply ionized atoms produced by K- and L-shell X-ray ionization and cosmic-ray ionization can undergo ion-molecule reactions and also initiate molecule production. The role of X-rays in molecule production in general is discussed, and the contribution to molecule production of the C(+) radiative association with hydrogen is examined. Such gas-phase reactions of singly and multiply ionized atoms are used to calculate molecular abundances of carbon-, nitrogen-, and oxygen-bearing species. The column densities of the molecules are evaluated on the basis of a modified version of previously developed isobaric cloud models. It is found that reactions of multiply ionized carbon with H2 can contribute a significant fraction of the observed CH in diffuse interstellar clouds in the presence of diffuse X-ray structures or discrete X-ray sources and that substantial amounts of CH(+) can be produced under certain conditions.

The sensitivity of gas-phase models of dense interstellar clouds to changes in dissociative recombination branching ratios

NASA Technical Reports Server (NTRS)

Millar, T. J.; Defrees, D. J.; Mclean, A. D.; Herbst, E.

1988-01-01

The approach of Bates to the determination of neutral product branching ratios in ion-electron dissociative recombination reactions has been utilized in conjunction with quantum chemical techniques to redetermine branching ratios for a wide variety of important reactions of this class in dense interstellar clouds. The branching ratios have then been used in a pseudo time-dependent model calculation of the gas phase chemistry of a dark cloud resembling TMC-1 and the results compared with an analogous model containing previously used branching ratios. In general, the changes in branching ratios lead to stronger effects on calculated molecular abundances at steady state than at earlier times and often lead to reductions in the calculated abundances of complex molecules. However, at the so-called 'early time' when complex molecule synthesis is most efficient, the abundances of complex molecules are hardly affected by the newly used branching ratios.

Molecules in celestial objects. III - Study of CO in interstellar diffuse clouds

NASA Technical Reports Server (NTRS)

Tarafdar, S. P.; Krishna Swamy, K. S.

1982-01-01

The absorption lines corresponding to the A-X transition of CO have been looked for in the IUE spectra of 14 stars with varying values of the colour excess, E(B-V) and found to be present in the spectra of nine stars with E(B-V) at least 0.28. The column density of CO has been determined towards these nine stars and its upper limit towards the rest of the stars. The curve of growth analysis has been found to show that the contribution to CO absorption is possibly from a single interstellar cloud for stars with E(B-V) less than 0.4 and from more than one cloud for stars with E(B-V) greater than 0.4. The observed column density of CO as a function of E(B-V) has been found to be in good agreement with that expected from the theory of ion-molecular chemistry.

The molecular universe: from astronomy to laboratory astrophysics and back

NASA Astrophysics Data System (ADS)

van Dishoeck, Ewine

2015-08-01

Molecules are found in a wide range of astronomical environments, fromour Solar System to distant starburst galaxies at the highest redshifts. Thanks to the opening up of the infrared and (sub)millimeter wavelength regime, culminating with Herschel and ALMA, more than 180 different species have now been found throughout the various stages of stellar birth and death: diffuse and dense interstellar clouds, protostars and disks, the envelopes of evolved stars and planetary nebulae, and exo-planetary atmospheres. Molecules and solid-state features are now also routinely detected in the interstellar medium of external galaxies, near and far.There are many motivations for studying this molecular universe. From the chemical perspective, interstellar space provides a unique laboratory to study basic molecular processes under very different conditions from those normally found in a laboratory on Earth. For astronomers, molecules are unique probes of the many environments where they are found, providing information on density, temperature, dynamics, ionization fractions and magnetic fields. Molecules also play an important role in the cooling of clouds allowing them to collapse, including the formation of the very first stars and galaxies. Finally, the molecular composition is sensitive to the history of the material, and ultimately provides critical information on our origins.This talk will summarize a number of recent observational highlights and provide examples of cases where the availability of new laboratory data proved crucial in the analysis. This includes basic data such as spectroscopy and collisional rate coefficients, but also an improved understanding of photoprocesses in the gaseous and solid state. Much of the chemistry in star- and planet-forming regions is now thought to be driven by gas-grain chemistry rather than pure gas-phase chemistry, and a few examples of the close link between models and laboratory experiments will be given. In spite of lingering uncertainties, the future of molecular astrophysics is bright and will allow increased understanding of the journey of gas and solids from clouds to comets and planets.

Polarization of seven MBM clouds at high Galactic latitude

NASA Astrophysics Data System (ADS)

Neha, S.; Maheswar, G.; Soam, A.; Lee, C. W.

2018-06-01

We made R-band polarization measurements of 234 stars towards the direction of the MBM 33-39 cloud complex. The distance of the MBM 33-39 complex was determined as 120 ± 10 pc using polarization results and near-infrared photometry from the 2MASS survey. The magnetic field geometry of the individual clouds inferred from our polarimetric results reveals that the field lines are in general consistent with the global magnetic field geometry of the region obtained from previous studies. This implies that the clouds in the complex are permeated by the interstellar magnetic field. Multi-wavelength polarization measurements of a few stars projected on to the complex suggest that the size of the dust grains in these clouds is similar to those found in the normal interstellar medium of the Milky Way. We studied a possible formation scenario of the MBM 33-39 complex by combining the polarization results from our study with those from the literature and by identifying the distribution of ionized, atomic and molecular (dust) components of material in the region.

Composition, structure, and chemistry of interstellar dust

NASA Technical Reports Server (NTRS)

Tielens, A. G. G. M.; Allamandola, L. J.

1987-01-01

Different dust components present in the interstellar medium (IM) such as amorphous carbon, polycyclic aromatic hydrocarbons, and those IM components which are organic refractory grains and icy grain mantles are discussed as well as their relative importance. The physical properties of grain surface chemistry are discussed with attention given to the surface structure of materials, the adsorption energy and residence time of species on a grain surface, and the sticking probability. Consideration is also given to the contribution of grains to the gas-phase composition of molecular clouds.

Life from the stars?. [extraterrestrial sources contributing to chemical evolution on Earth

NASA Technical Reports Server (NTRS)

Pendleton, Yvonne J.; Cruikshank, Dale P.

1994-01-01

Scientists are now seriously considering the possibility that organic matter from interstellar space could have influenced, or even spurred, the origin of life on Earth. Various aspects of chemical evolution are discussed along with possible extraterrestrial sources responsible for contributing to Earth's life-producing, chemical composition. Specific topics covered include the following: interstellar matter, molecular clouds, asteroid dust, organic molecules in our solar system, interplanetary dust and comets, meteoritic composition, and organic-rich solar-system bodies.

On the impact of the magnitude of interstellar pressure on physical properties of molecular cloud

NASA Astrophysics Data System (ADS)

Anathpindika, S.; Burkert, A.; Kuiper, R.

2017-04-01

Recently reported variations in the typical physical properties of Galactic and extra-Galactic molecular clouds (MCs), and, in their star-forming ability, have been attributed to local variations in the magnitude of interstellar pressure. Inferences from these surveys have called into question two long-standing beliefs that: (1) MCs are virialized and (2) they obey the Larson's third law. Here we invoked the framework of cloud formation via collision between warm gas-flows to examine if these latest observational inferences can be reconciled. To this end, we traced the temporal evolution of the gas surface density, the fraction of dense gas, the distribution of gas column density (N-PDF) and the virial nature of the assembled clouds. We conclude that these physical properties exhibit temporal variation and their respective peak magnitude also increases in proportion with the magnitude of external pressure, Pext. The velocity dispersion in assembled clouds appears to follow the power law, σ _{gas}∝ P_{ext}^{0.23}. The power-law tail of the N-PDFs at higher densities becomes shallower with increasing magnitude of external pressure for Pext/kB ≲ 107 K cm-3; at higher magnitudes such as those typically found in the Galactic Central Molecular Zone (Pext/kB > 107 K cm-3), the power-law shows significant steepening. While our results are broadly consistent with inferences from various recent observational surveys, it appears that MCs do not exhibit a unique set of properties, but rather a wide variety that can be reconciled with a range of magnitudes of pressure between 104 and 108 K cm-3.

TWO-STAGE FRAGMENTATION FOR CLUSTER FORMATION: ANALYTICAL MODEL AND OBSERVATIONAL CONSIDERATIONS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bailey, Nicole D.; Basu, Shantanu, E-mail: nwityk@uwo.ca, E-mail: basu@uwo.ca

2012-12-10

Linear analysis of the formation of protostellar cores in planar magnetic interstellar clouds shows that molecular clouds exhibit a preferred length scale for collapse that depends on the mass-to-flux ratio and neutral-ion collision time within the cloud. We extend this linear analysis to the context of clustered star formation. By combining the results of the linear analysis with a realistic ionization profile for the cloud, we find that a molecular cloud may evolve through two fragmentation events in the evolution toward the formation of stars. Our model suggests that the initial fragmentation into clumps occurs for a transcritical cloud onmore » parsec scales while the second fragmentation can occur for transcritical and supercritical cores on subparsec scales. Comparison of our results with several star-forming regions (Perseus, Taurus, Pipe Nebula) shows support for a two-stage fragmentation model.« less

Mid-infrared rotational line emission from interstellar molecular hydrogen

NASA Astrophysics Data System (ADS)

Burton, Michael G.; Hollenbach, D. J.; Tielens, A. G. G.

1992-11-01

The line emission from the v = 0-0 S(0), S(2), and S(3), and the v = 1-0 and v = 2-1 S(1) transitions of molecular hydrogen in clouds exposed to high FUV fluxes and in shocks is modeled. Particular attention is given to the lowest pure rotational H2 transitions at 20 and 17 microns, respectively. It is found that, in photodissociation regions (PDRs), the emission comes from warm (greater than about 100 k) molecular gas, situated at optical depths greater than about 1, beyond the hot atomic surface layer of the clouds. For FUV fields, G0 = 1000 to 100,000 times the average interstellar field densities n = 10 exp 3 - 10 exp 7/cu cm, the typical line intensities are in the range 10 exp -6 to 10 exp -4 ergs/s sq cm sr. The predictions for the line intensities from both C-type and J-type shock models are compared. The results are applied to recent observations of the 0-0 S(1) transition in both the PDR and the shocked gas in Orion.

Gas, dust, stars, star formation, and their evolution in M 33 at giant molecular cloud scales

NASA Astrophysics Data System (ADS)

Komugi, Shinya; Miura, Rie E.; Kuno, Nario; Tosaki, Tomoka

2018-06-01

We report on a multi-parameter analysis of giant molecular clouds (GMCs) in the nearby spiral galaxy M 33. A catalog of GMCs identifed in 12CO(J = 3-2) was used to compile associated 12CO(J = 1-0), dust, stellar mass, and star formation rate. Each of the 58 GMCs are categorized by their evolutionary stage. Applying the principal component analysis on these parameters, we construct two principal components, PC1 and PC2, which retain 75% of the information from the original data set. PC1 is interpreted as expressing the total interstellar matter content, and PC2 as the total activity of star formation. Young (< 10 Myr) GMCs occupy a distinct region in the PC1-PC2 plane, with lower interstellar medium (ISM) content and star formation activity compared to intermediate-age and older clouds. Comparison of average cloud properties in different evolutionary stages imply that GMCs may be heated or grow denser and more massive via aggregation of diffuse material in their first ˜ 10 Myr. The PCA also objectively identified a set of tight relations between ISM and star formation. The ratio of the two CO lines is nearly constant, but weakly modulated by massive star formation. Dust is more strongly correlated with the star formation rate than the CO lines, supporting recent findings that dust may trace molecular gas better than CO. Stellar mass contributes weakly to the star formation rate, reminiscent of an extended form of the Schmidt-Kennicutt relation with the molecular gas term substituted by dust.

Gas, dust, stars, star formation, and their evolution in M 33 at giant molecular cloud scales

NASA Astrophysics Data System (ADS)

Komugi, Shinya; Miura, Rie E.; Kuno, Nario; Tosaki, Tomoka

2018-04-01

We report on a multi-parameter analysis of giant molecular clouds (GMCs) in the nearby spiral galaxy M 33. A catalog of GMCs identifed in 12CO(J = 3-2) was used to compile associated 12CO(J = 1-0), dust, stellar mass, and star formation rate. Each of the 58 GMCs are categorized by their evolutionary stage. Applying the principal component analysis on these parameters, we construct two principal components, PC1 and PC2, which retain 75% of the information from the original data set. PC1 is interpreted as expressing the total interstellar matter content, and PC2 as the total activity of star formation. Young (< 10 Myr) GMCs occupy a distinct region in the PC1-PC2 plane, with lower interstellar medium (ISM) content and star formation activity compared to intermediate-age and older clouds. Comparison of average cloud properties in different evolutionary stages imply that GMCs may be heated or grow denser and more massive via aggregation of diffuse material in their first ˜ 10 Myr. The PCA also objectively identified a set of tight relations between ISM and star formation. The ratio of the two CO lines is nearly constant, but weakly modulated by massive star formation. Dust is more strongly correlated with the star formation rate than the CO lines, supporting recent findings that dust may trace molecular gas better than CO. Stellar mass contributes weakly to the star formation rate, reminiscent of an extended form of the Schmidt-Kennicutt relation with the molecular gas term substituted by dust.

An infrared measurement of chemical desorption from interstellar ice analogues

NASA Astrophysics Data System (ADS)

Oba, Y.; Tomaru, T.; Lamberts, T.; Kouchi, A.; Watanabe, N.

2018-03-01

In molecular clouds at temperatures as low as 10 K, all species except hydrogen and helium should be locked in the heterogeneous ice on dust grain surfaces. Nevertheless, astronomical observations have detected over 150 different species in the gas phase in these clouds. The mechanism by which molecules are released from the dust surface below thermal desorption temperatures to be detectable in the gas phase is crucial for understanding the chemical evolution in such cold clouds. Chemical desorption, caused by the excess energy of an exothermic reaction, was first proposed as a key molecular release mechanism almost 50 years ago1. Chemical desorption can, in principle, take place at any temperature, even below the thermal desorption temperature. Therefore, astrochemical network models commonly include this process2,3. Although there have been a few previous experimental efforts4-6, no infrared measurement of the surface (which has a strong advantage to quantify chemical desorption) has been performed. Here, we report the first infrared in situ measurement of chemical desorption during the reactions H + H2S → HS + H2 (reaction 1) and HS + H → H2S (reaction 2), which are key to interstellar sulphur chemistry2,3. The present study clearly demonstrates that chemical desorption is a more efficient process for releasing H2S into the gas phase than was previously believed. The obtained effective cross-section for chemical desorption indicates that the chemical desorption rate exceeds the photodesorption rate in typical interstellar environments.

Adolescent Interstellar Cloud Poised to Make Star-forming Debut

NASA Astrophysics Data System (ADS)

2001-06-01

Astronomers using the National Science Foundation's (NSF) 140-foot radio telescope at the National Radio Astronomy Observatory (NRAO) in Green Bank, W.Va., have discovered a highly unusual, massive interstellar cloud that appears poised to begin a burst of star formation. The cloud may be the first ever to be detected in the transition between atomic and molecular states. NRAO scientists Felix J. Lockman and Anthony H. Minter presented their findings at the American Astronomical Society meeting in Pasadena, Calif. Radio Image of G28.17+0.05 The scientists discovered the cloud, identified as G28.17+0.05, lying along the inner plane of the Milky Way Galaxy, approximately 16,300 light-years from Earth. Observations of the cloud indicate that it is near one of the Galaxy's sweeping spiral arms, which are outlined by young stars and the massive clouds that form them. Lockman and Minter speculate that as the interstellar cloud slams into the Galactic arm, the resulting shock wave may be precipitating the conversion of the neutral hydrogen atoms into heavier molecules, which could herald the onset of star formation. "These may be the first observations of a cloud that is in the transition between the neutral atomic hydrogen and molecular phases," said Lockman. "This provides astronomers a unique opportunity to study the chemistry of very young interstellar clouds, which could give us significant insights into the early stages of star formation and the structure of the Galaxy." Interstellar clouds that contain neutral atomic hydrogen, called HI (H-one) clouds, are thought of as giant, cold blobs of gas. Researchers study these objects because they offer intriguing glimpses of the composition of our Galaxy and the cosmos, and reveal much about how stars and planets are born. Hydrogen atoms in these clouds give off natural signals (at the 21-cm wavelength), which can be detected only by radio telescopes. The scientists discovered that this HI cloud was unusual in many respects. First, it was uncharacteristically massive, about 500 light- years across and containing nearly 100,000 times the mass of the sun in atomic hydrogen. The gas in clouds this large and massive has typically undergone the transition to the molecular phase, and has begun making stars. The size and mass of this cloud indicate that it is gravitationally bound, which means that it should be collapsing and forming new stars. "When you find a cloud that is as massive as the one we detected, and one that is gravitationally bound as this structure indicates, then you would expect to see areas of star formation," said Lockman. The scientists were able to identify a few indicators of star formation, but not at the rate that one would expect. "We think we have caught something in a special state." Lockman said, "It could be one of the missing links in the cycle of star formation." The core of the cloud also gives off radio signals at 1720 MHz from the molecule OH in an unusual state of excitation. Since other astronomers have detected similar signals throughout the Galactic plane, the researchers believe that these emissions may be an indication that this previously undetected type of cloud may turn out to be fairly common. "We suspect that this cloud may be the first example of an object that may be fairly common in the inner Galactic plane," said Lockman, "but has not been recognized. That is, a cloud that is observed while entering a spiral shock and is in the transition between atomic to molecular hydrogen." The NRAO 140-Foot Telescope The scientists caution, however, that additional research is needed to confirm their speculations. "The presence of anomalous OH through the Galactic plane does suggest that other clouds of this nature can be detected," said Lockman, "and it would be particularly valuable if a similar cloud could be detected entering the 'spiral shock' on the opposite side of the Galactic center." The patterns of velocities of atomic and molecular gas should be reversed there, due to the difference in galactic rotation. Such a discovery could help to validate the possible interaction among the spiral shock, atomic hydrogen, and star formation. The NSF's 140-foot radio telescope now is decommissioned after a long and highly productive career. Research will continue on the newly commissioned Robert C. Byrd Green Bank Telescope, which is the world's largest fully steerable radio telescope. "Though the 140-foot telescope enabled us to make remarkable observations," commented Minter, "we anticipate that the new Green Bank Telescope, with its increased sensitivity and better resolution, will enable us to see more clearly the nature of this peculiar object." In addition to Minter and Lockman, other astronomers involved in this research include Glen I. Langston, NRAO; and Jennifer A. Lockman who was a student from the College of Charleston, S.C., at the time the research was conducted. The National Radio Astronomy Observatory is a facility of the National Science Foundation, operated under cooperative agreement by Associated Universities, Inc.

Mapping low-frequency carbon radio recombination lines towards Cassiopeia A at 340, 148, 54, and 43 MHz

NASA Astrophysics Data System (ADS)

Salas, P.; Oonk, J. B. R.; van Weeren, R. J.; Wolfire, M. G.; Emig, K. L.; Toribio, M. C.; Röttgering, H. J. A.; Tielens, A. G. G. M.

2018-04-01

Quantitative understanding of the interstellar medium requires knowledge of its physical conditions. Low-frequency carbon radio recombination lines (CRRLs) trace cold interstellar gas and can be used to determine its physical conditions (e.g. electron temperature and density). In this work, we present spatially resolved observations of the low-frequency (≤390 MHz) CRRLs centred around C268α, C357α, C494α, and C539α towards Cassiopeia A on scales of ≤1.2 pc. We compare the spatial distribution of CRRLs with other interstellar medium tracers. This comparison reveals a spatial offset between the peak of the CRRLs and other tracers, which is very characteristic for photodissociation regions and that we take as evidence for CRRLs being preferentially detected from the surfaces of molecular clouds. Using the CRRLs, we constrain the gas electron temperature and density. These constraints on the gas conditions suggest variations of less than a factor of 2 in pressure over ˜1 pc scales, and an average hydrogen density of 200-470 cm-3. From the electron temperature and density maps, we also constrain the ionized carbon emission measure, column density, and path length. Based on these, the hydrogen column density is larger than 1022 cm-2, with a peak of ˜4 × 1022 cm-2 towards the south of Cassiopeia A. Towards the southern peak, the line-of-sight length is ˜40 pc over a ˜2 pc wide structure, which implies that the gas is a thin surface layer on a large (molecular) cloud that is only partially intersected by Cassiopeia A. These observations highlight the utility of CRRLs as tracers of low-density extended H I and CO-dark gas halo's around molecular clouds.

Time-dependent interstellar chemistry

NASA Technical Reports Server (NTRS)

Glassgold, A. E.

1985-01-01

Some current problems in interstellar chemistry are considered in the context of time-dependent calculations. The limitations of steady-state models of interstellar gas-phase chemistry are discussed, and attempts to chemically date interstellar clouds are reviewed. The importance of studying the physical and chemical properties of interstellar dust is emphasized. Finally, the results of a series of studies of collapsing clouds are described.

Carbon Chemistry in Transitional Clouds from the GOT C+ Survey of CII 158 micron Emission in the Galactic Plane

NASA Astrophysics Data System (ADS)

Langer, W. D.; Velusamy, T.; Pineda, J.; Willacy, K.; Goldsmith, P. F.

2011-05-01

In understanding the lifecycle and chemistry of the interstellar gas, the transition from diffuse atomic to molecular gas clouds is a very important stage. The evolution of carbon from C+ to C0 and CO is a fundamental part of this transition, and C+ along with its carbon chemistry is a key diagnostic. Until now our knowledge of interstellar gas has been limited primarily to the diffuse atomic phase traced by HI and the dense molecular H2 phase traced by CO. However, we have generally been missing an important layer in diffuse and transition clouds, which is denoted by the warm "dark gas'', that is mostly H2 and little HI and CO, and is best traced with C+. Here, we discuss the chemistry in the transition from C+ to C0 and CO in these clouds as understood by a survey of the CII 1.9 THz (158 micron) line from a sparse survey of the inner galaxy over about 40 degrees in longitude as part of the Galactic Observations of Terahertz C+ (GOT C+) program, a Herschel Space Observatory Open Time Key Program to study interstellar clouds by sampling ionized carbon. Using the first results from GOT C+ along 11 LOSs, in a sample of 53 transition clouds, Velusamy, Langer et al. (A&A 521, L18, 2010) detected an excess of CII intensities indicative of a thick H2 layer (a significant warm H2, "dark gas'' component) around the 12CO core. Here we present a much larger, statistically significant sample of a few hundred diffuse and transition clouds traced by CII, along with auxiliary HI and CO data in the inner Galaxy between l=-30° and +30°. Our new and more extensive sample of transition clouds is used to elucidate the time dependent physical and carbon chemical evolution of diffuse to transition clouds, and transition layers. We consider the C+ to CO conversion pathways such as H++ O and C+ + H2 chemistry for CO production to constrain the physical parameters such as the FUV intensity and cosmic ray ionization rate that drive the CO chemistry in the diffuse transition clouds.

Abundances and Excitation of H2, H3+ & CO in Star-Forming Regions

NASA Astrophysics Data System (ADS)

Kulesa, Craig A.

Although most of the 123 reported interstellar molecules to date have been detected through millimeter-wave emission-line spectroscopy, this technique is inapplicable to non-polar molecules like H2 and H3+, which are central to our understanding of interstellar chemistry. Thus high resolution infrared absorption-line spectroscopy bears an important role in interstellar studies: chemically important non-polar molecules can be observed, and their abundances and excitation conditions can be referred to the same ``pencil beam'' absorbing column. In particular, through a weak quadrupole absorption line spectrum at near-infrared wavelengths, the abundance of cold H2 in dark molecular clouds and star forming regions can now be accurately measured and compared along the same ``pencil beam'' line of sight with the abundance of its most commonly cited surrogate, CO, and its rare isotopomers. Also detected via infrared line absorption is the pivotal molecular ion H3+, whose abundance provides the most direct measurement of the cosmic ray ionization rate in dark molecular clouds, a process that initiates the formation of many other observed molecules there. Our growing sample of H2 and CO detections now includes detailed multi-beam studies of the ρ Ophiuchi molecular cloud and NGC 2024 in Orion. We explore the excitation and degree of ortho- and para-H2 thermalization in dark clouds, variation of the CO abundance over a cloud, and the relation of H2 column density to infrared extinction mapping, far-infrared/submillimeter dust continuum emission, and large scale submillimeter CO, [C I] and HCO+ line emission -- all commonly invoked to indirectly trace H2 during the past 30+ years. For each of the distinct velocity components seen toward some embedded young stellar objects, we are also able to determine the temperature, density, and a CO/H2 abundance ratio, thus unraveling some of the internal structure of a star-forming cloud. H2 and H3+ continue to surprise and delight us with more mysteries. We present imaging and spectroscopy of excited H2 line emission from two Crab Nebula filaments, leading to intriguing questions -- such as the rapid formation, excitation, and continued survival of hydrogen molecules in such a hostile environment. Similarly, we depict the recent detection of CO and H3+ emission from the circumstellar disks of nearby Herbig AeBe stars, providing an outstanding diagnostic of energetic pre-planetary environments and a valuable study of the non-thermal excitation of H3+ in its own right. These studies spotlight the role of molecules as regulators and probes of physical processes in molecular clouds and star- & planet-forming regions. See: http://loke.as.arizona.edu/˜ckulesa/research/ for preprints & more information

Evidence for a Neutral Iron Line Generated by MeV Protons from Supernova Remnants Interacting with Molecular Clouds

NASA Astrophysics Data System (ADS)

Nobukawa, Kumiko K.; Nobukawa, Masayoshi; Koyama, Katsuji; Yamauchi, Shigeo; Uchiyama, Hideki; Okon, Hiromichi; Tanaka, Takaaki; Uchida, Hiroyuki; Tsuru, Takeshi G.

2018-02-01

Supernova remnants (SNRs) have been prime candidates for Galactic cosmic-ray accelerators. When low-energy cosmic-ray protons (LECRp) collide with interstellar gas, they ionize neutral iron atoms and emit the neutral iron line (Fe I Kα) at 6.40 keV. We search for the iron K-shell line in seven SNRs from the Suzaku archive data of the Galactic plane in the 6^\\circ ≲ l≲ 40^\\circ ,| b| < 1^\\circ region. All of these SNRs interact with molecular clouds. We discover Fe I Kα line emissions from five SNRs (W28, Kes 67, Kes 69, Kes 78, and W44). The spectra and morphologies suggest that the Fe I Kα line is produced by interactions between LECRp and the adjacent cold gas. The proton energy density is estimated to be ≳10–100 eV cm‑3, which is more than 10 times higher than that in the ambient interstellar medium.

The Evolution of Interstellar Gas: Massive Stars and the Dispersal of Neutral Material

NASA Technical Reports Server (NTRS)

Federman, Steven R.

2003-01-01

We studied the effects of newly formed O and B stars on their surrounding interstellar material through a combination of observations and theoretical modeling. The observational data came from measurements of absorption seen in the spectra of background, newly formed stars. Particular attention was given to stellar radiation which converts molecular to atomic material. Laboratory data on absorption cross sections relevant to the analysis and interpretation of carbon monoxide formed part of the effort. The grant supported Postdoctoral Fellows, Drs. Min Yan and Yaron Sheffer, and a laboratory technician. Though the students themselves were not supported. one M.S. Thesis and two Ph.D. dissertations from the University of Toledo were based on the research done under the grant. The research accomplished under this grant led directly to other funded programs. An observing proposal to study the chemistry of diffuse molecular clouds in the Large and Small Magellanic Clouds with ESO s Very Large Telescope was another example of a successful outcome of my LTSA program.

Recent Advances in Organic Cosmochemistry

NASA Technical Reports Server (NTRS)

Sandford, Scott A.; Witteborn, Fred C. (Technical Monitor)

1994-01-01

The Astrochemistry Laboratory at NASA's Ames Research Center pursues a variety of activities, most of which center around the use of spectroscopy (ultraviolet to far-infrared) for the interpretation of astronomical and meteoritic data. One of our key activities is the study of the chemical and physical properties of cometary, interstellar, and planetary ice analogs and matrix-isolated molecules of astrophysical interest. As a result of these studies it is now known that a significant fraction of the carbon in the interstellar medium (ISM) is in reasonably complex forms, some of which are clearly of interest for exobiology. Examples of compounds known or suspected to be present in space include polycyclic aromatic hydrocarbons (PAHs), microdiamonds, an aliphatic-rich component found in the diffuse interstellar medium, and a variety of molecular species produced by the irradiation of mixed molecular ices in dense clouds. A number of the species produced by irradiation contain nitrogen and appear to offer an additional means of producing some of the amino acids found in meteorites. I will review these complex carbonaceous materials and discuss how they are connected with each other and the organic materials that ultimately ended up as part of our own Solar System. Specific points that will probably be covered include: (1) the composition of the ices in interstellar dense molecular clouds; (2) the more complex organic compounds produced when these ices are irradiated and/or warmed; (3) the detection of microdiamonds in space; (4) the discovery that aliphatic materials may constitute as much as 15% of all the carbon in the diffuse ISM, appears to be present everywhere in the galaxy, and yet seems to be present everywhere in the galaxy, and yet seems to be significantly concentrated towards the center of the galaxy.

IRAS Colors of the Pleiades

NASA Technical Reports Server (NTRS)

Carey, Sean J.; Shipman, R. F.; Clark, F. O.

1996-01-01

We present large scale images of the infrared emission of the region around the Pleiades using the ISSA data product from the IRAS mission. Residual Zodiacal background and a discontinuity in the image due to the scanning strategy of the satellite necessitated special background subtraction methods. The 60/100 color image clearly shows the heating of the ambient interstellar medium by the cluster. The 12/100 and 25/100 images peak on the cluster as expected for exposure of small dust grains to an enhanced UV radiation field; however, the 25/100 color declines to below the average interstellar value at the periphery of the cluster. Potential causes of the color deficit are discussed. A new method of identifying dense molecular material through infrared emission properties is presented. The difference between the 100 micron flux density and the 60 micron flux density scaled by the average interstellar 60/100 color ratio (Delta I(sub 100) is a sensitive diagnostic of material with embedded heating sources (Delta I(sub 100) less than 0) and cold, dense cores (Delta I(sub 100) greater than 0). The dense cores of the Taurus cloud complex as well as Lynds 1457 are clearly identified by this method, while the IR bright but diffuse Pleiades molecular cloud is virtually indistinguishable from the nearby infrared cirrus.

The Atomic to Molecular Transition in the Interstellar Medium

NASA Technical Reports Server (NTRS)

Goldsmith, Paul F.

2012-01-01

Study of H2 in UV and IR continues to surprise us with complexity of excitation state, OPR, and role in astrochemistry. Atomic H in molecular clouds is a very powerful tool suggesting that they are not "young" but that it takes millions of years to convert primarily atomic hydrogen clouds to 99.9% molecular form. Laboratory data suggests that H2 formation is efficient over broader range of temperatures than thought to be the case a few years ago, but range is still limited. Issues of complex grain morphology and surface structure make this a very difficult field in which to obtain definitively meaningful results. Ongoing and future observations of CI and CII will improve our understanding of the structure of clouds, their total mass, and how they have evolved and will continue to do so.

Evolution of Interstellar Grains

NASA Technical Reports Server (NTRS)

Allamandola, Lou J.; DeVincenzi, Donald L. (Technical Monitor)

1998-01-01

During the past two decades observations combined with laboratory simulations, have revolutionized our understanding of interstellar ice and dust, the raw materials from which planets, comets and stars form. Most interstellar material is concentrated in large molecular clouds where simple molecules are formed by dust-grain and gas-phase reactions. Gaseous species striking the cold (10K) dust stick, forming an icy grain mantle. This accretion, coupled with UV photolysis, produces a complex chemical mixture containing volatile, non-volatile, and isotopically fractionated species. Ices in molecular clouds contain the very simple molecules H2O, CH3OH, CO, CO2, H2, and perhaps some NH3 and H2CO, as well as more complex species. The evidence for these compounds, as well as carbon-rich materials, will be reviewed and the possible connections with comets and meteorites will be presented in the first part of the talk . The second part of the presentation will focus on interstellar/precometary ice photochemical evolution and the species likely to be found in comets. The chemical composition and photochemical evolution of realistic interstellar/pre-cometary ice analogs will be discussed. Ultraviolet photolysis of these ices produces H2, H2CO, CO2, CO, CH4, HCO, and more complex molecules. When ices representative of interstellar grains and comets are exposed to UV radiation at low temperature a series of moderately complex organic molecules are formed in the ice including: CH3CH2OH (ethanol), HC(=O)NH2 (formamide), CH3C(=O)NH2 (acetamide), and R-C=N (nitriles). Several of these are already known to be in the interstellar medium, and their presence indicates the importance of grain processing. After warming to room temperature an organic residue remains. This is composed primarily of hexamethylenetetramine (HMT, C6H12N4), with lesser amounts of polyoxymethylene-related species (POMs), amides, and ketones. This is in sharp contrast to the organic residues produced by irradiating unrealistic interstellar ice analogs or thermally promoted polymerization-type reactions in unirradiated realistic ice mixtures.

Galactic Observations of Terahertz C+ (GOT C+): First Results: Inner Galaxy Survey

NASA Astrophysics Data System (ADS)

Langer, William; Velusamy, T.; Pineda, J. L.; Goldsmith, P. F.; Li, D.; Yorke, H. W.

2010-05-01

To understand the lifecycle of the interstellar gas and star formation we need detailed information about the diffuse atomic and diffuse molecular gas cloud properties. The ionized carbon [CII] 1.9 THz fine structure line is an important tracer of the atomic gas in the diffuse regions and the interface regions of atomic gas to molecular clouds. Furthermore, C+ is a major ISM coolant and among the Galaxy's strongest far-IR emission lines, and thus controls the thermal conditions throughout large parts of the Galaxy. Until now our knowledge of interstellar gas has been limited to the diffuse atomic phase traced by HI and to the dense molecular H2 phase traced by CO. However, we are missing an important phase of the ISM called "dark gas” in which there is no or little, HI, and mostly molecular hydrogen but with insufficient shielding of UV to allow CO to form. C+ emission and absorption lines at 1.9 THz have the potential to trace this gas. Galactic Observations of the Terahertz C+ Line (GOT C+) is a Herschel Space Observatory Open Time Key Program to study the diffuse interstellar medium by sampling [CII] 1.9 THz line emission throughout the Galactic disk. We discuss the broader perspective of this survey and the first results of GOT C+ obtained during the Science Demonstration Phase (SDP) and Priority Science Phase (PSP) of HIFI, which focus on approximately 100 lines of sight in the inner galaxy. This research was conducted at the Jet Propulsion Laboratory, California Institute of Technology under contract with the National Aeronautics and Space Administration.

Comets, carbonaceous chondrites, and interstellar clouds: Condensation of carbon

NASA Technical Reports Server (NTRS)

Field, G. B.

1979-01-01

Comets, carbonaceous chondrites, and interstellar clouds are discussed in relation to information on interstellar dust. The formation and presence of carbon in stars, comets, and meteorites is investigated. The existence of graphite in the interstellar medium, though it is predicted from thermodynamic calculations, is questioned and the form of carbon contained in comets is considered.

Molecular studies of Planetary Nebulae

NASA Astrophysics Data System (ADS)

Zhang, Yong

2017-10-01

Circumstellar envelopes (CEs) around evolved stars are an active site for the production of molecules. After evolving through the Asymptotic Giant Branch (AGB), proto-planetary nebula (PPN), to planetary nebula (PN) phases, CEs ultimately merge with the interstellar medium (ISM). The study of molecules in PNe, therefore, is essential to understanding the transition from stellar to interstellar materials. So far, over 20 molecular species have been discovered in PNe. The molecular composition of PNe is rather different from those of AGB and PPNe, suggesting that the molecules synthesized in PN progenitors have been heavily processed by strong ultraviolet radiation from the central star. Intriguingly, fullerenes and complex organic compounds having aromatic and aliphatic structures can be rapidly formed and largely survive during the PPN/PN evolution. The similar molecular compositions in PNe and diffuse clouds as well as the detection of C60 + in the ISM reinforce the view that the mass-loss from PNe can significantly enrich the ISM with molecular species, some of which may be responsible for the diffuse interstellar bands. In this contribution, I briefly summarize some recent observations of molecules in PNe, with emphasis on their implications on circumstellar chemistry.

Infrared emission from hydrogenated amorphous carbon and amorphous carbon grains in the interstellar medium

NASA Technical Reports Server (NTRS)

Duley, W. W.; Jones, A. P.; Taylor, S. D.; Williams, D. A.

1993-01-01

The correlations deduced by Boulanger et al. (1990) from IRAS maps of the Chamaeleon, Taurus and Ursa Major molecular cloud complexes are interpreted in terms of the evolutionary hydrogenated amorphous carbon model of interstellar dust. In particular, regions of relatively strong 12-micron emission may be regions where recently accreted carbon is being converted by ambient UV to small PAHs in situ. Regions of weak 12-micron emission are probably quiescent regions where carbon has been annealed to amorphous carbon. Observational consequences of these inferences are briefly described.

Chemical evolution of primitive solar system bodies

NASA Technical Reports Server (NTRS)

Oro, J.; Mills, T.

1989-01-01

Observations on organic molecules and compounds containing biogenic elements in the interstellar medium and in the primitive bodies of the solar system are reviewed. The discovery of phosphorus molecular species in dense interstellar clouds, the existence of organic ions in the dust and gas phase of the comas of Comet Halley, and the presence of presolar, deuterium-hydrogen ratios in the amino acids of carbonaceous chondrites are discussed. The relationships between comets, dark asteroids, and carbonaceous chondrites are examined. Also, consideration is given to the chemical evolution of Titan, the primitive earth, and early Mars.

Extinct radioactivities - A three-phase mixing model. [for early solar system abundances

NASA Technical Reports Server (NTRS)

Clayton, D. D.

1983-01-01

A new class of models is advanced for interpreting the relationship of radioactive abundances in the early solar system to their average concentration in the interstellar medium. The model assumes that fresh radioactivities are ejected from supernovae into the hot interstellar medium, and that the time scales for changes of phase into molecular clouds determine how much survives for formation therein of the solar system. A more realistic and physically motivated understanding of the low observed concentrations of I-129, Pu-244, and Pd-107 may result.

Morphology and ionization of the interstellar cloud surrounding the solar system.

PubMed

Frisch, P C

1994-09-02

The first encounter between the sun and the surrounding interstellar cloud appears to have occurred 2000 to 8000 years ago. The sun and cloud space motions are nearly perpendicular, an indication that the sun is skimming the cloud surface. The electron density derived for the surrounding cloud from the carbon component of the anomalous cosmic ray population in the solar system and from the interstellar ratio of Mg(+) to Mg degrees toward Sirius support an equilibrium model for cloud ionization (an electron density of 0.22 to 0.44 per cubic centimeter). The upwind magnetic field direction is nearly parallel to the cloud surface. The relative sun-cloud motion indicates that the solar system has a bow shock.

Rotational spectrum of 13C{2}-methyl formate (HCOO13CH{3}) and detection of the two 13C-methyl formate in Orion

NASA Astrophysics Data System (ADS)

Carvajal, M.; Margulès, L.; Tercero, B.; Demyk, K.; Kleiner, I.; Guillemin, J. C.; Lattanzi, V.; Walters, A.; Demaison, J.; Wlodarczak, G.; Huet, T. R.; Møllendal, H.; Ilyushin, V. V.; Cernicharo, J.

2009-06-01

Context: Laboratory measurements and analysis of the microwave and millimeter-wave spectra of potential interstellar molecules are a prerequisite for their subsequent identification by radioastronomical techniques. The spectral analysis provides spectroscopic parameters that are used in the assignment procedure of the laboratory spectra, and that also predict the frequencies of transitions not measured in the laboratory with a high degree of precision. Aims: An experimental laboratory study and its theoretical analysis is presented for 13C2-methyl formate (HCOO13CH3) allowing a search for this isotopologue in the Orion molecular cloud. The 13C1-methyl formate (H13COOCH3) molecule was also searched for in this interstellar cloud, using previously published spectroscopic data. Methods: The experimental spectra of 13C2-methyl formate were recorded in the microwave and sub-mm energy ranges (4-20 GHz, 8-80 GHz, 150-700 GHz). The spectra were analyzed using the Rho-Axis Method (RAM), which takes the CH3 internal rotation and the coupling between internal rotation and global rotation into account. Results: Twenty-seven spectroscopic constants of 13C2-methyl formate have been obtained from a fit of 936 transitions of the ground torsional state with a standard (unitless) deviation of 1.08. A prediction of line positions and intensities is also produced. This prediction allowed us to identify 230 13C2-methyl formate lines in the Orion interstellar molecular cloud. We refitted all previously published ground state transitions of the 13C1-methyl formate molecule in order to provide a prediction of its ground state spectrum. 234 lines of 13C1-methyl formate were detected in the Orion interstellar cloud using that prediction. Tables A.1-A.5 are only available in electronic form at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/500/1109

EVALUATING THE MORPHOLOGY OF THE LOCAL INTERSTELLAR MEDIUM: USING NEW DATA TO DISTINGUISH BETWEEN MULTIPLE DISCRETE CLOUDS AND A CONTINUOUS MEDIUM

DOE Office of Scientific and Technical Information (OSTI.GOV)

Redfield, Seth; Linsky, Jeffrey L., E-mail: sredfield@wesleyan.edu, E-mail: jlinsky@jila.colorado.edu

Ultraviolet and optical spectra of interstellar gas along the lines of sight to nearby stars have been interpreted by Redfield and Linsky and previous studies as a set of discrete warm, partially ionized clouds each with a different flow vector, temperature, and metal depletion. Recently, Gry and Jenkins proposed a fundamentally different model consisting of a single cloud with nonrigid flows filling space out to 9 pc from the Sun that they propose better describes the local ISM. Here we test these fundamentally different morphological models against the spatially unbiased Malamut et al. spectroscopic data set, and find that themore » multiple cloud morphology model provides a better fit to both the new and old data sets. The detection of three or more velocity components along the lines of sight to many nearby stars, the presence of nearby scattering screens, the observed thin elongated structures of warm interstellar gas, and the likely presence of strong interstellar magnetic fields also support the multiple cloud model. The detection and identification of intercloud gas and the measurement of neutral hydrogen density in clouds beyond the Local Interstellar Cloud could provide future morphological tests.« less

The molecular composition of dense interstellar clouds

NASA Technical Reports Server (NTRS)

Allen, M.; Robinson, G. W.

1977-01-01

Presented in this paper is an ab initio chemical model for dense interstellar clouds that incorporates 598 grain surface reactions, with small grains providing the reaction area. Gas-phase molecules are depleted through collisions with grains. The abundances of 372 chemical species are calculated as a function of time and are found to be of sufficient magnitude to explain most observations. Peak abundances are achieved on time scales of the order of 100,000 to 1 million years, depending on cloud density and kinetic temperature. The reaction rates for ion-molecule chemistry are approximately the same, indicating that surface and gas-phase chemistry may be coupled in certain regions. The composition of grain mantles is shown to be a function of grain radius. In certain grain-size ranges, large molecules containing two or more heavy atoms are more predominant than lighter 'ices' - H2O, NH3, and CH4. It is possible that absorption due to these large molecules in the mantle may contribute to the observed 3-micron band in astronomical spectra.

Experimental evidence for glycolaldehyde and ethylene glycol formation by surface hydrogenation of CO molecules under dense molecular cloud conditions

NASA Astrophysics Data System (ADS)

Fedoseev, G.; Cuppen, H. M.; Ioppolo, S.; Lamberts, T.; Linnartz, H.

2015-04-01

This study focuses on the formation of two molecules of astrobiological importance - glycolaldehyde (HC(O)CH2OH) and ethylene glycol (H2C(OH)CH2OH) - by surface hydrogenation of CO molecules. Our experiments aim at simulating the CO freeze-out stage in interstellar dark cloud regions, well before thermal and energetic processing become dominant. It is shown that along with the formation of H2CO and CH3OH - two well-established products of CO hydrogenation - also molecules with more than one carbon atom form. The key step in this process is believed to be the recombination of two HCO radicals followed by the formation of a C-C bond. The experimentally established reaction pathways are implemented into a continuous-time random-walk Monte Carlo model, previously used to model the formation of CH3OH on astrochemical time-scales, to study their impact on the solid-state abundances in dense interstellar clouds of glycolaldehyde and ethylene glycol.

A survey of interstellar HI from L alpha absorption measurements 2

NASA Technical Reports Server (NTRS)

Bohlin, R. C.; Savage, B. D.; Drake, J. F.

1977-01-01

The Copernicus satellite surveyed the spectral region near L alpha to obtain column densities of interstellar HI toward 100 stars. The distance to 10 stars exceeds 2 kpc and 34 stars lie beyond 1 kpc. Stars with color excess E(B-V) up to 0.5 mag are observed. The value of the mean ratio of total neutral hydrogen to color excess was found to equal 5.8 x 10 to the 21st power atoms per (sq cm x mag). For stars with accurate E(B-V), the deviations from this mean are generally less than a factor of 1.5. A notable exception is the dark cloud star, rho Oph. A reduction in visual reddening efficiency for the grains that are larger than normal in the rho Oph dark cloud probably explains this result. The conversion of atomic hydrogen into molecular form in dense clouds was observed in the gas to E(B-V) correlation plots. The best estimate for the mean total gas density for clouds and the intercloud medium, as a whole, in the solar neighborhood and in the plane of the galaxy is 1.15 atoms per cu. cm; those for the atomic gas and molecular gas alone are 0.86 atoms per cu cm and 0.143 molecules per cu cm respectively. For the intercloud medium, where molecular hydrogen is a negligible fraction of the total gas, atomic gas density was found to equal 0.16 atoms per cu cm with a Gaussian scale height perpendicular to the plane of about 350 pc, as derived from high latitude stars.

Probing the Origin and Evolution of Interstellar and Protoplanetary Biogenic Molecules:A Comprehensive Survey of Interstellar Ices with SPHEREx

NASA Astrophysics Data System (ADS)

Melnick, Gary J.; SPHEREx Science Team

2016-01-01

Many of the most important building blocks of life are locked in interstellar and protoplanetary ices. Examples include H2O, CO, CO2, and CH3OH, among others. There is growing evidence that in some environments, such as within the cores of dense molecular clouds and the mid-plane of protoplanetary disks, the amounts of these species in ices far exceeds that in the gas phase. As a result, collisions between ice-bearing bodies and newly forming planets are thought to be a major means of delivering these key species to young planets. There currently exist fewer than 250 ice absorption spectra toward Galactic molecular clouds, which is insufficient to reliably trace the ice content of clouds through the various stages of collapse to star and planet formation, or assess the effects of their environments and physical conditions, such as cloud density, internal temperature, presence or absence of embedded sources, external UV and X-ray radiation, gas-phase composition, or cosmic-ray ionization rate, on the ice composition for clouds at similar evolutionary stages. Ultimately, our goal is to understand how these findings connect to our own Solar System.SPHEREx, which is a mission in NASA's Small Explorer (SMEX) program that was selected for a Phase A study in July 2015, will be a game changer for the study of interstellar, circumstellar, and protoplanetary disk ices. SPHEREx will obtain spectra over the entire sky in the optical and near-IR, including the 2.5 to 4.8 micron region, which contains the above biogenic ice features. SPHEREx will detect millions of potential background continuum point sources already catalogued by NASA's Wide-field Infrared Survey Explorer (WISE) at 3.4 and 4.6 microns for which there is evidence for intervening gas and dust based on the 2MASS+WISE colors with sufficient sensitivity to yield ice absorption spectra with SNR ≥ 100 per spectral resolution element. The resulting > 100-fold increase in the number of high-quality ice absorption spectra toward a wide variety of regions distributed throughout the Galaxy will reveal correlations between ice content and environment not possible with current spectra. Finally, SPHEREx will provide JWST with an ice source catalog for follow-up.

Laboratory simulation of interstellar grain chemistry and the production of complex organic molecules

NASA Technical Reports Server (NTRS)

Allamandola, L. J.; Sandford, S. A.; Valero, G. J.

1990-01-01

During the past 15 years considerable progress in observational techniques has been achieved in the middle infrared (5000 to 500 cm(-1), 2 to 20 microns m), the spectral region most diagnostic of molecular vibrations. Spectra of many different astronomical infrared sources, some deeply embedded in dark molecular clouds, are now available. These spectra provide a powerful probe, not only for the identification of interstellar molecules in both the gas solid phases, but also of the physical and chemical conditions which prevail in these two very different domains. By comparing these astronomical spectra with the spectra of laboratory ices one can determine the composition and abundance of the icy materials frozen on the cold (10K) dust grains present in the interior of molecular clouds. These grains and their ice mantles may well be the building blocks from which comets are made. As an illustration of the processes which can take place as an ice is irradiated and subsequently warmed, researchers present the infrared spectra of the mixture H2O:CH3OH:CO:NH3:C6H14 (100:50:10:10:10). Apart from the last species, the ratio of these compounds is representative of the simplest ices found in interstellar clouds. The last component was incorporated into this particular experiment as a tracer of the behavior of a non-aromatic hydrocarbon. The change in the composition that results from ultraviolet photolysis of this ice mixture using a UV lamp to simulate the interstellar radiation field is shown. Photolysis produces CO, CO2, CH4, HCO, H2CO, as well as a family of moderately volatile hydrocarbons. Less volatile carbonaceous materials are also produced. The evolution of the infrared spectrum of the ice as the sample is warmed up to room temperature is illustrated. Researchers believe that the changes are similar to those which occur as ice is ejected from a comet and warmed up by solar radiation. The warm-up sequence shows that the nitrile or iso-nitrile bearing compound produced during photolysis evaporates between 200 and 250K, suggesting that it is carried by a small molecular species. These molecules could be similar to the source material in Comet Halley that is ejected in grains into the coma, freed by sublimation, and photolyzed by solar radiation to produce the observed jets.

Odin observations of H2O and O2 in comets and interstellar clouds

NASA Astrophysics Data System (ADS)

Hjalmarson, Åke; Odin Team

2002-11-01

We here report on results from single-position observations, and in some cases also mapping, of the 557 GHz ortho-H2O line in several comets and in many interstellar molecular clouds by the Odin sub-millimetre wave spectroscopy satellite. The H2O production rates have been accurately determined in four comets, C/2001 A2 (LINEAR), 19P/Borrelly, C/2000 WM1 (LINEAR), and 153P/2002 C1 (Ikeya-Zhang). In comet Ikeya-Zhang our detection at a low level of the corresponding H218O emission line verifies the H2O production rate (which depends upon the assumed radiative and collisional excitation and also upon radiative transfer modelling) and is consistent with a nearly terrestrial 16O/18O-isotope ratio. In an astrobiological context, the cometary H2O production rates are especially important as reference levels for comparison with abundances of other molecules simultaneously observed with ground-based telescopes. In interstellar clouds the observed gas-phase H2O abundances (vs H2) range from 5×10-4 in the Orion KL outflow/shock region (where essentially all oxygen is locked up in H2O) to circa 10-8 in quiescent cloud regions (where H2O) is just one of many trace molecules). From an astrobiological point of view, the molecular abundances in star forming clouds are important in terms of initial conditions for the chemistry in proto-planetary disks ("proto-solar nebulae"), the formation sites of new planetary systems. In simultaneous observations, Odin has also detected the 572 GHz ortho-NH3 line in cold and warm clouds as well as in the Orion outflow and Bar/PDR regions (an area of increased ionisation caused by the intense UV flux from newly born massive stars). In other simultaneous observations, we have performed sensitive searches for O2 at 119 GHz. Although no detection can be reported as yet, the resulting very low abundance limits (<10-7) are very intriguing when they are compared with current "standard" model expectations, which fall in the range 10-5-10-4.

Diamond, aromatic, aliphatic components of interstellar dust grains: Random covalent networks in carbonaceous grains

NASA Astrophysics Data System (ADS)

Duley, W. W.

1995-05-01

A formalism based on the theory of random covalent networks (RCNs) in amorphous solids is developed for carbonaceous dust grains. RCN solutions provide optimized structures and relative compositions for amorphous materials. By inclusion of aliphatic, aromatic, and diamond clusters, solutions specific to interstellar materials can be obtained and compared with infrared spectral data. It is found that distinct RCN solutions corresponding to diffuse cloud and molecular cloud materials are possible. Specific solutions are derived for three representative objects: VI Cyg No. 12, NGC 7538 (IRS 9), and GC IRS 7. While diffuse cloud conditions with a preponderance of sp2 and sp3 bonded aliphatic CH species can be reproduced under a variety of RCN conditions, the presence of an abundant tertiary CH or diamond component is highly constrained. These solutions are related quantitatively to carbon depletions and can be used to provide a quantitative estimate of carbon in these various dust components. Despite the abundance of C6 aromatic rings in many RCN solutions, the infrared absorption due to the aromatic stretch at approximately 3.3 micrometers is weak under all conditions. The RCN formalism is shown to provide a useful method for tracing the evolutionary properties of interstellar carbonaceous grains.

Implications of SWAS Observations for Interstellar Chemistry and Star Formation

NASA Technical Reports Server (NTRS)

Bergin, Edwin A.; Melnick, Gary J.; Stauffer, John R.; Ashby, Matthew L. N.; Chin, Gordon; Erickson, Neal R.; Goldsmith, Paul F.; Harwit, Martin; Howe, John E.; Kleiner, Steven C.

2000-01-01

A long standing prediction of steady state gas-phase chemical theory is that H2O and O2 are important reservoirs of elemental oxygen and major coolants of the interstellar medium. Analysis of SWAS observations has set sensitive upper limits on the abundance Of O2 and has provided H2O abundances toward a variety of star forming regions. Based on these results, we show that gaseous H2O and O2 are not dominant carriers of elemental oxygen in molecular clouds. Instead the available oxygen is presumably frozen on dust grains in the form of molecular ices, with a significant portion potentially remaining in atomic form, along with CO, in the gas phase. H2O and O2 are also not significant coolants for quiescent molecular gas. In the case of H2O, a number of known chemical processes can locally elevate its abundance in regions with enhanced temperatures, such as warm regions surrounding young stars or in hot shocked gas. Thus, water can be a locally important coolant. The new information provided by SWAS, when combined with recent results from the Infrared Space Observatory, also provide several hard observational constraints for theoretical models of the chemistry in molecular clouds and we discuss various models that satisfy these conditions.

Laboratory experiments on interstellar ice analogs: The sticking and desorption of small physisorbed molecules

NASA Technical Reports Server (NTRS)

Fuchs, G. W.; Acharyya, K.; Bisschop, S. E.; Oberg, K. I.; vanBroekhuizen, F. A.; Fraser, H. J.; Schlemmer, S.; vanDishoeck, E. F.; Linnartz, H.

2006-01-01

Molecular oxygen and nitrogen are difficult to observe since they are infrared inactive and radio quiet. The low O2 abundances found so far combined with general considerations of dense cloud conditions suggest molecular oxygen is frozen out at low temperatures (< 20 K) in the shielded inner regions of cloud cores. In solid form O2 and N2 can only be observed as adjuncts within other ice constituents, like CO. In this work we focus on fundamental properties of N2 and O2 in CO ice-gas systems, e.g. desorption characteristics and sticking probabilities at low temperatures for different ice morphologies.

The state of clouds in a violent interstellar medium

NASA Astrophysics Data System (ADS)

Heathcote, S. R.; Brand, P. W. J. L.

1983-04-01

A highly approximate but simple model is developed which describes the interaction of a supernova blast wave with an interstellar cloud. The behavior of a cloud when exposed to conditions prevalent in a violent interstellar medium is examined using this model. Results show that after a cloud has been shocked it is rarely allowed sufficient time to return to pressure equilibrium with its surroundings before encountering a second shock. Thus, significant departures from pressure equilibrium are inevitable. It is determined that the disruption of a cloud by its passage through a blast wave is quite effective and the half life of clouds cannot greatly exceed the mean interval between shocks striking a given cloud. In addition, it is found that composite core-envelope clouds are not viable under typical conditions.

Detection of interstellar HCS and its metastable isomer HSC: new pieces in the puzzle of sulfur chemistry

NASA Astrophysics Data System (ADS)

Agúndez, M.; Marcelino, N.; Cernicharo, J.; Tafalla, M.

2018-03-01

We present the first identification in interstellar space of the thioformyl radical (HCS) and its metastable isomer HSC. These species were detected toward the molecular cloud L483 through observations carried out with the IRAM 30 m telescope in the λ3 mm band. We derive beam-averaged column densities of 7 × 1012 cm-2 for HCS and 1.8 × 1011 cm-2 for HSC, which translate into fractional abundances relative to H2 of 2 × 10-10 and 6 × 10-12, respectively. Although the amount of sulfur locked by these radicals is low, their detection allows placing interesting constraints on the chemistry of sulfur in dark clouds. Interestingly, the H2CS/HCS abundance ratio is found to be quite low, 1, in contrast with the oxygen analog case, in which the H2CO/HCO abundance ratio is around 10 in dark clouds. Moreover, the radical HCS is found to be more abundant than its oxygen analog, HCO. The metastable species HOC, the oxygen analog of HSC, has not yet been observed in space. These observational constraints are compared with the outcome of a recent model of the chemistry of sulfur in dark clouds. The model underestimates the fractional abundance of HCS by at least one order of magnitude, overestimates the H2CS/HCS abundance ratio, and does not provide an abundance prediction for the metastable isomer HSC. These observations should prompt a revision of the chemistry of sulfur in interstellar clouds.

Interaction of a supernova shock with two interstellar clouds

NASA Astrophysics Data System (ADS)

Hansen, J. F.; McKee, C. F.

2005-10-01

The interaction of supernova shocks and interstellar clouds is an important astrophysical phenomenon since it can result in stellar and planetary formation. Our experiments attempt to simulate this mass-loading as it occurs when a shock passes through interstellar clouds. We drive a strong shock using a 5 kJ laser into a foam-filled cylinder with embedded Al spheres (diameter D=120 μm) simulating interstellar clouds. The density ratio between Al and foam is ˜9. We have previously reported on the interaction between shock and a single cloud, and the ensuing Kelvin-Helmholtz and Widnall instabilities. We now report on experiments under way in which two clouds are placed side by side. Cloud separation (center to center) is either 1.2xD or 1.5xD. Initial results for 1.2xD show that cloud material merges and travels further downstream than in the single cloud case. For 1.5xD, material does not merge, but the clouds tilt toward each other. Work performed under the auspices of the Department of Energy by the Lawrence Livermore National Laboratory under contract number W-7405-ENG-48.

Cosmic-rays, gas, and dust in nearby anticentre clouds. II. Interstellar phase transitions and the dark neutral medium

NASA Astrophysics Data System (ADS)

Remy, Q.; Grenier, I. A.; Marshall, D. J.; Casandjian, J. M.

2018-03-01

Aim. H I 21-cm and 12CO 2.6-mm line emissions trace the atomic and molecular gas phases, respectively, but they miss most of the opaque H I and diffuse H2 present in the dark neutral medium (DNM) at the transition between the H I-bright and CO-bright regions. Jointly probing H I, CO, and DNM gas, we aim to constrain the threshold of the H I-H2 transition in visual extinction, AV, and in total hydrogen column densities, NHtot. We also aim to measure gas mass fractions in the different phases and to test their relation to cloud properties. Methods: We have used dust optical depth measurements at 353 GHz, γ-ray maps at GeV energies, and H I and CO line data to trace the gas column densities and map the DNM in nearby clouds toward the Galactic anticentre and Chamaeleon regions. We have selected a subset of 15 individual clouds, from diffuse to star-forming structures, in order to study the different phases across each cloud and to probe changes from cloud to cloud. Results: The atomic fraction of the total hydrogen column density is observed to decrease in the (0.6-1) × 1021 cm-2 range in NHtot (AV ≈ 0.4 mag) because of the formation of H2 molecules. The onset of detectable CO intensities varies by only a factor of 4 from cloud to cloud, between 0.6 × 1021 cm-2 and 2.5 × 1021 cm-2 in total gas column density. We observe larger H2 column densities than linearly inferred from the CO intensities at AV > 3 mag because of the large CO optical thickness; the additional H2 mass in this regime represents on average 20% of the CO-inferred molecular mass. In the DNM envelopes, we find that the fraction of diffuse CO-dark H2 in the molecular column densities decreases with increasing AV in a cloud. For a half molecular DNM, the fraction decreases from more than 80% at 0.4 mag to less than 20% beyond 2 mag. In mass, the DNM fraction varies with the cloud properties. Clouds with low peak CO intensities exhibit large CO-dark H2 fractions in molecular mass, in particular the diffuse clouds lying at high altitude above the Galactic plane. The mass present in the DNM envelopes appears to scale with the molecular mass seen in CO as MHDNM = 62 ± 7 MH2CO0.51 ± 0.02 across two decades in mass. Conclusions: The phase transitions in these clouds show both common trends and environmental differences. These findings will help support the theoretical modelling of H2 formation and the precise tracing of H2 in the interstellar medium.

Newly detected molecules in dense interstellar clouds

NASA Astrophysics Data System (ADS)

Irvine, William M.; Avery, L. W.; Friberg, P.; Matthews, H. E.; Ziurys, L. M.

Several new interstellar molecules have been identified including C2S, C3S, C5H, C6H and (probably) HC2CHO in the cold, dark cloud TMC-1; and the discovery of the first interstellar phosphorus-containing molecule, PN, in the Orion "plateau" source. Further results include the observations of 13C3H2 and C3HD, and the first detection of HCOOH (formic acid) in a cold cloud.

A Model for Atomic and Molecular Interstellar Gas: The Meudon PDR Code

NASA Astrophysics Data System (ADS)

Le Petit, Franck; Nehmé, Cyrine; Le Bourlot, Jacques; Roueff, Evelyne

2006-06-01

We present the revised ``Meudon'' model of photon-dominated region (PDR) code, available on the Web under the GNU Public License. General organization of the code is described down to a level that should allow most observers to use it as an interpretation tool with minimal help from our part. Two grids of models, one for low-excitation diffuse clouds and one for dense highly illuminated clouds, are discussed, and some new results on PDR modelization highlighted.

Physical properties and scaling relations of molecular clouds: the effect of stellar feedback

NASA Astrophysics Data System (ADS)

Grisdale, Kearn; Agertz, Oscar; Renaud, Florent; Romeo, Alessandro B.

2018-06-01

Using hydrodynamical simulations of entire galactic discs similar to the Milky Way, reaching 4.6{ pc} resolution, we study the origins of observed physical properties of giant molecular clouds (GMCs). We find that efficient stellar feedback is a necessary ingredient in order to develop a realistic interstellar medium (ISM), leading to molecular cloud masses, sizes, velocity dispersions and virial parameters in excellent agreement with Milky Way observations. GMC scaling relations observed in the Milky Way, such as the mass-size (M-R), velocity dispersion-size (σ-R), and the σ-RΣ relations, are reproduced in a feedback driven ISM when observed in projection, with M∝R2.3 and σ∝R0.56. When analysed in 3D, GMC scaling relations steepen significantly, indicating potential limitations of our understanding of molecular cloud 3D structure from observations. Furthermore, we demonstrate how a GMC population's underlying distribution of virial parameters can strongly influence the scatter in derived scaling relations. Finally, we show that GMCs with nearly identical global properties exist in different evolutionary stages, where a majority of clouds being either gravitationally bound or expanding, but with a significant fraction being compressed by external ISM pressure, at all times.

Gas-grain chemical models of star-forming molecular clouds as constrained by ISO and SWAS observations

NASA Astrophysics Data System (ADS)

Charnley, S. B.; Rodgers, S. D.; Ehrenfreund, P.

2001-11-01

We have investigated the gaseous and solid state molecular composition of dense interstellar material that periodically experiences processing in the shock waves associated with ongoing star formation. Our motivation is to confront these models with the stringent abundance constraints on CO2, H2O and O2, in both gas and solid phases, that have been set by ISO and SWAS. We also compare our results with the chemical composition of dark molecular clouds as determined by ground-based telescopes. Beginning with the simplest possible model needed to study molecular cloud gas-grain chemistry, we only include additional processes where they are clearly required to satisfy one or more of the ISO-SWAS constraints. When CO, N2 and atoms of N, C and S are efficiently desorbed from grains, a chemical quasi-steady-state develops after about one million years. We find that accretion of CO2 and H2O cannot explain the [CO2/H2O]ice ISO observations; as with previous models, accretion and reaction of oxygen atoms are necessary although a high O atom abundance can still be derived from the CO that remains in the gas. The observational constraints on solid and gaseous molecular oxygen are both met in this model. However, we find that we cannot explain the lowest H2O abundances seen by SWAS or the highest atomic carbon abundances found in molecular clouds; additional chemical processes are required and possible candidates are given. One prediction of models of this type is that there should be some regions of molecular clouds which contain high gas phase abundances of H2O, O2 and NO. A further consequence, we find, is that interstellar grain mantles could be rich in NH2OH and NO2. The search for these regions, as well as NH2OH and NO2 in ices and in hot cores, is an important further test of this scenario. The model can give good agreement with observations of simple molecules in dark molecular clouds such as TMC-1 and L134N. Despite the fact that S atoms are assumed to be continously desorbed from grain surfaces, we find that the sulphur chemistry independently experiences an ``accretion catastrophe''. The S-bearing molecular abundances cease to lie within the observed range after about 3 x 106 years and this indicates that there may be at least two efficient surface desorption mechanisms operating in dark clouds - one quasi-continous and the other operating more sporadically on this time-scale. We suggest that mantle removal on short time-scales is mediated by clump dynamics, and by the effects of star formation on longer time-scales. The applicability of this type of dynamical-chemical model for molecular cloud evolution is discussed and comparison is made with other models of dark cloud chemistry.

The jet-ISM interactions in IC 5063

NASA Astrophysics Data System (ADS)

Mukherjee, Dipanjan; Wagner, Alexander Y.; Bicknell, Geoffrey V.; Morganti, Raffaella; Oosterloo, Tom; Nesvadba, Nicole; Sutherland, Ralph S.

2018-05-01

The interstellar medium of the radio galaxy IC 5063 is highly perturbed by an AGN jet expanding in the gaseous disc of the galaxy. We model this interaction with relativistic hydrodynamic simulations and multiphase initial conditions for the interstellar medium and compare the results with recent observations. As the jets flood through the intercloud channels of the disc, they ablate, accelerate, and disperse clouds to velocities exceeding 400 km s-1. Clouds are also destroyed or displaced in bulk from the central regions of the galaxy. Our models with jet powers of 1044 and 1045 erg s-1 are capable of reproducing many of the observed features in the position velocity diagram of IC 5063, and confirm the notion that the jet is responsible for the strongly perturbed gas dynamics seen in the ionized, neutral, and molecular gas phases. In our simulations, we also see strong venting of the jet plasma perpendicular to the disc, which entrains clumps and diffuse filaments into the halo of the galaxy. Our simulations are the first 3D hydrodynamic simulations of the jet and interstellar matter of IC 5063.

KPOT_wlanger_1: State of the Diffuse ISM: Galactic Observations of the Terahertz CII Line (GOT CPlus)

NASA Astrophysics Data System (ADS)

Langer, W.

2007-10-01

Star formation activity throughout the Galactic disk depends on the thermal and dynamical state of the interstellar gas, which in turn depends on heating and cooling rates, modulated by the gravitational potential and shock and turbulent pressures. Molecular cloud formation, and thus the star formation, may be regulated by pressures in the interstellar medium (ISM). To understand these processes we need information about the properties of the diffuse atomic and diffuse molecular gas clouds, and Photon Dominated Regions (PDR). An important tracer of these regions is the CII line at 158 microns (1900.5 GHz). We propose a "pencil-beam" survey of CII with HIFI band 7b, based on deep integrations and systematic sparse sampling of the Galactic disk plus selected targets, totaling over 900 lines of sight. We will detect both emission and, against the bright inner Galaxy and selected continuum sources, absorption lines. These spectra will provide the astronomical community with a large rich statistical database of the diffuse cloud properties throughout the Galaxy for understanding the Milky Way ISM and, by extension, other galaxies. It will be extremely valuable for determining the properties of the atomic gas, the role of barometric pressure and turbulence in cloud evolution, and the properties of the interface between the atomic and molecular clouds. The CII line is one of the major ISM cooling lines and is present throughout the Galactic plane. It is the strongest far-IR emission line in the Galaxy, with a total luminosity about a 1000 times that of the CO J=1-0 line. Combined with other data, it can be used to determine density, pressure, and radiation environment in gas clouds, and PDRs, and their dynamics via velocity fields. HSO is the best opportunity over the next several years to probe the ISM in this tracer and will provide a template for large-scale surveys with dedicated small telescopes and future surveys of other important ISM tracers.

SDP_wlanger_3: State of the Diffuse ISM: Galactic Observations of the Terahertz CII Line (GOT CPlus)

NASA Astrophysics Data System (ADS)

Langer, W.

2011-09-01

Star formation activity throughout the Galactic disk depends on the thermal and dynamical state of the interstellar gas, which in turn depends on heating and cooling rates, modulated by the gravitational potential and shock and turbulent pressures. Molecular cloud formation, and thus the star formation, may be regulated by pressures in the interstellar medium (ISM). To understand these processes we need information about the properties of the diffuse atomic and diffuse molecular gas clouds, and Photon Dominated Regions (PDR). An important tracer of these regions is the CII line at 158 microns (1900.5 GHz). We propose a "pencil-beam" survey of CII with HIFI band 7b, based on deep integrations and systematic sparse sampling of the Galactic disk plus selected targets, totaling over 900 lines of sight. We will detect both emission and, against the bright inner Galaxy and selected continuum sources, absorption lines. These spectra will provide the astronomical community with a large rich statistical database of the diffuse cloud properties throughout the Galaxy for understanding the Milky Way ISM and, by extension, other galaxies. It will be extremely valuable for determining the properties of the atomic gas, the role of barometric pressure and turbulence in cloud evolution, and the properties of the interface between the atomic and molecular clouds. The CII line is one of the major ISM cooling lines and is present throughout the Galactic plane. It is the strongest far-IR emission line in the Galaxy, with a total luminosity about a 1000 times that of the CO J=1-0 line. Combined with other data, it can be used to determine density, pressure, and radiation environment in gas clouds, and PDRs, and their dynamics via velocity fields. HSO is the best opportunity over the next several years to probe the ISM in this tracer and will provide a template for large-scale surveys with dedicated small telescopes and future surveys of other important ISM tracers.

Life and the Universe: From Astrochemistry to Astrobiology

NASA Technical Reports Server (NTRS)

Allamandola, Louis J.

2013-01-01

Great strides have been made in our understanding of interstellar material thanks to advances in infrared astronomy and laboratory astrophysics. Ionized polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by earlier astrochemical standards, are widespread and very abundant throughout much of the cosmos. In cold molecular clouds, the birthplace of planets and stars, interstellar atoms and molecules freeze onto extremely cold dust and ice particles forming mixed molecular ices dominated by simple species such as water, methanol, ammonia, and carbon monoxide. Within these clouds, and especially in the vicinity of star and planet forming regions, these ices and PAHs are processed by ultraviolet light and cosmic rays forming hundreds of far more complex species, some of biogenic interest. Eventually, these are delivered to primordial planets by comets and meteorites. As these materials are the building blocks of comets and related to carbonaceous micrometeorites, they are likely to be important sources of complex organic materials delivered to habitable planets (including the primordial Earth) and their composition may be related to the origin of life. This talk will focus on the chemical evolution of these cosmic materials and their relevance to astrobiology.

Infrared emission spectra of candidate interstellar aromatic molecules

NASA Technical Reports Server (NTRS)

Schlemmer, S.; Balucani, N.; Wagner, D. R.; Steiner, B.; Saykally, R. J.

1996-01-01

Interstellar dust is responsible, through surface reactions, for the creation of molecular hydrogen, the main component of the interstellar clouds in which new stars form. Intermediate between small, gas-phase molecules and dust are the polycyclic aromatic hydrocarbons (PAHs). Such molecules could account for 2-30% of the carbon in the Galaxy, and may provide nucleation sites for the formation of carbonaceous dust. Although PAHs have been proposed as the sources of the unidentified infrared emission bands that are observed in the spectra of a variety of interstellar sources, the emission characteristics of such molecules are still poorly understood. Here we report laboratory emission spectra of several representative PAHs, obtained in conditions approximating those of the interstellar medium, and measured over the entire spectral region spanned by the unidentified infrared bands. We find that neutral PAHs of small and moderate size can at best make only a minor contribution to these emission bands. Cations of these molecules, as well as much larger PAHs and their cations, remain viable candidates for the sources of these bands.

OH+ and H2O+: Probes of the Molecular Hydrogen Fraction and Cosmic-Ray Ionization Rate

NASA Astrophysics Data System (ADS)

Indriolo, Nick; Neufeld, D. A.; Gerin, M.; PRISMAS; WISH

2014-01-01

The fast ion-molecule chemistry that occurs in the interstellar medium (ISM) is initiated by cosmic-ray ionization of both atomic and molecular hydrogen. Species that are near the beginning of the network of interstellar chemistry such as the oxygen-bearing ions OH+ and H2O+ can be useful probes of the cosmic-ray ionization rate. This parameter is of particular interest as, to some extent, it controls the abundances of several molecules. Using observations of OH+ and H2O+ made with HIFI on board Herschel, we have inferred the cosmic-ray ionization rate of atomic hydrogen in multiple distinct clouds along 12 Galactic sight lines. These two molecules also allow us to determine the molecular hydrogen fraction (amount of hydrogen nuclei in H2 versus H) as OH+ and H2O+ abundances are dependent on the competition between dissociative recombination with electrons and hydrogen abstraction reactions involving H2. Our observations of OH+ and H2O+ indicate environments where H2 accounts for less than 10% of the available hydrogen nuclei, suggesting that these species primarily reside in the diffuse, atomic ISM. Average ionization rates in this gas are on the order of a few times 10-16 s-1, with most values in specific clouds above or below this average by a factor of 3 or so. This result is in good agreement with the most up-to-date determination of the distribution of cosmic-ray ionization rates in diffuse molecular clouds as inferred from observations of H3+.

The Spitzer Survey of Interstellar Clouds in the Gould Belt. VI. The Auriga-California Molecular Cloud Observed with IRAC and MIPS

NASA Technical Reports Server (NTRS)

Broekhoven-Fiene, Hannah; Matthews, Brenda C.; Harvey, Paul M.; Gutermuth, Robert A.; Huard, Tracy L.; Tothill, Nicholas F. H.; Nutter, David; Bourke, Tyler L.; DiFrancesco, James; Jorgensen, Jes K.;

Carbon chain abundance in the diffuse interstellar medium

NASA Technical Reports Server (NTRS)

Allamandola, L. J.; Hudgins, D. M.; Bauschlicher, C. W. Jr; Langhoff, S. R.

1999-01-01

Thanks to the mid-IR sensitivities of the ISO and IRTS orbiting spectrometers it is now possible to search the diffuse interstellar medium for heretofore inaccessible molecular emission. In view of the recent strong case for the presence of C(7-) (Kirkwood et al. 1998, Tulej et al. 1998),and the fact that carbon chains possess prominent infrared active modes in a very clean portion of the interstellar spectrum, we have analyzed the IRTS spectrum of the diffuse interstellar medium for the infrared signatures of these species. Theoretical and experimental infrared band frequencies and absolute intensities of many different carbon chain species are presented. These include cyanopolyynes, neutral and anionic linear carbon molecules, and neutral and ionized, even-numbered, hydrogenated carbon chains. We show that--as a family--these species have abundances in the diffuse ISM on the order of 10(-10) with respect to hydrogen, values consistent with their abundances in dense molecular clouds. Assuming an average length of 10 C atoms per C-chain implies that roughly a millionth of the cosmically available carbon is in the form of carbon chains and that carbon chains can account for a few percent of the visible to near-IR diffuse interstellar band (DIB) total equivalent width (not DIB number).

The third flight of CHESS: Preliminary analysis of interstellar H2 on the β1 Sco sightline

NASA Astrophysics Data System (ADS)

Kruczek, Nick; France, Kevin

2018-01-01

We describe the scientific motivation and technical development of the Colorado High-resolution Echelle Stellar Spectrograph (CHESS), focusing on the preliminary science results for the third launch of the payload (CHESS-3). CHESS is a far ultraviolet rocket-borne instrument designed to study the atomic-to-molecular transitions within translucent cloud regions in the interstellar medium. CHESS is an objective echelle spectrograph, which uses a mechanically-ruled echelle and a powered (f/12.4) cross-dispersing grating, and is designed to achieve a resolving power R > 100,000 over the band pass λλ 1000-1600 Å. CHESS-3 launched on 14 June 2017 aboard NASA/CU sounding rocket mission 36.323 UG. The target for the flight was β1 Sco, a B1V star with a sightline that is likely sampling translucent material. We present flight results of interstellar molecular hydrogen excitation, including initial measurements of the column density and temperature, on the sightline.

Trans-cis molecular photoswitching in interstellar space

NASA Astrophysics Data System (ADS)

Cuadrado, S.; Goicoechea, J. R.; Roncero, O.; Aguado, A.; Tercero, B.; Cernicharo, J.

2016-11-01

As many organic molecules, formic acid (HCOOH) has two conformers (trans and cis). The energy barrier to internal conversion from trans to cis is much higher than the thermal energy available in molecular clouds. Thus, only the most stable conformer (trans) is expected to exist in detectable amounts. We report the first interstellar detection of cis-HCOOH. Its presence in ultraviolet (UV) irradiated gas exclusively (the Orion Bar photodissociation region), with a low trans-to-cis abundance ratio of 2.8 ± 1.0, supports a photoswitching mechanism: a given conformer absorbs a stellar photon that radiatively excites the molecule to electronic states above the interconversion barrier. Subsequent fluorescent decay leaves the molecule in a different conformer form. This mechanism, which we specifically study with ab initio quantum calculations, was not considered in Space before but likely induces structural changes of a variety of interstellar molecules submitted to UV radiation. This paper makes use of observations obtained with the IRAM-30 m telescope. IRAM is supported by INSU/CNRS (France), MPG (Germany), and IGN (Spain).

IRAS and the Boston University Arecibo Galactic H I Survey: A catalog of cloud properties

NASA Technical Reports Server (NTRS)

Bania, Thomas M.

1992-01-01

The Infrared Astronomy Satellite (IRAS) Galactic Plane Surface Brightness Images were used to identify infrared emission associated with cool, diffuse H I clouds detected by the Boston University-Arecibo Galactic H I Survey. These clouds are associated with galactic star clusters, H II regions, and molecular clouds. Using emission-absorption experiments toward galactic H II regions, we determined the H I properties of cool H I clouds seen in absorption against the thermal continuum, including their kinematic distances. Correlations were then made between IRAS sources and these H II regions, thus some of the spatial confusion associated with the IRAS fields near the galactic plane was resolved since the distances to these sources was known. Because we can also correlate the BU-Arecibo clouds with existing CO surveys, these results will allow us to determine the intrinsic properties of the gas (neutral and ionized atomic as well as molecular) and dust for interstellar clouds in the inner galaxy. For the IRAS-identified H II region sample, we have established the far infrared (FIR) luminosities and galactic distribution of these sources.

The Origin of Cosmic Rays: What can GLAST Say?

NASA Technical Reports Server (NTRS)

Ormes, Jonathan F.; Digel, Seith; Moskalenko, Igor V.; Moiseev, Alexander; Williamson, Roger

2000-01-01

Gamma rays in the band from 30 MeV to 300 GeV, used in combination with direct measurements and with data from radio and X-ray bands, provide a powerful tool for studying the origin of Galactic cosmic rays. Gamma-ray Large Area Space Telescope (GLAST) with its fine 10-20 arcmin angular resolution will be able to map the sites of acceleration of cosmic rays and their interactions with interstellar matter, It will provide information that is necessary to study the acceleration of energetic particles in supernova shocks, their transport in the interstellar medium and penetration into molecular clouds.

Isomerization and fragmentation of acetonitrile upon interaction with N(4S) atoms: the chemistry of nitrogen in dense molecular clouds

NASA Astrophysics Data System (ADS)

Mencos, Alejandro; Krim, Lahouari

2016-08-01

We experimentally show that the reaction between ground state nitrogen atoms N(4S) and acetonitrile CH3CN can lead to two distinct chemical pathways that are both thermally activated at very low temperatures. First is CH3CN isomerization which produces CH3NC and H2CCNH. Second is CH3CN decomposition which produces HNC and CH3CNH+CN- fragments, with the possible release of H2. Our results reveal that the mobility of N(4S)-atoms is stimulated in the 3-11 K temperature range, and that its subsequent encounter with one acetonitrile molecule is sufficient for the aforementioned reactions to occur without the need for additional energy to be supplied to the CH3CN + N(4S) system. These findings shed more light on the nitrogen chemistry that can possibly take place in dense molecular clouds, which until now was thought to only involve high-energy processes and therefore be unlikely to occur in such cold and dark interstellar regions. The reaction pathways we propose in this study have very important astrochemical implications, as it was shown recently that the atomic nitrogen might be more abundant, in many interstellar icy grain mantles, than previously thought. Also, these reaction pathways can now be considered within dense molecular clouds, and possibly affect the branching ratios for N-bearing molecules computed in astrochemical modelling.

On the Formation of Interstellar Water Ice: Constraints from a Search for Hydrogen Peroxide Ice in Molecular Clouds

NASA Technical Reports Server (NTRS)

Smith, R. G.; Charnely, S. B.; Pendleton, Y. J.; Wright, C. M.; Maldoni, M. M.; Robinson, G.

2011-01-01

Recent surface chemistry experiments have shown that the hydrogenation of molecular oxygen on interstellar dust grains is a plausible formation mechanism, via hydrogen peroxide (H2O2), for the production of water (H2O) ice mantles in the dense interstellar medium. Theoretical chemistry models also predict the formation of a significant abundance of H2O2 ice in grain mantles by this route. At their upper limits, the predicted and experimental abundances are sufficiently high that H2O2 should be detectable in molecular cloud ice spectra. To investigate this further, laboratory spectra have been obtained for H2O2/H2O ice films between 2.5 and 200 micron, from 10 to 180 K, containing 3%, 30%, and 97% H2O2 ice. Integrated absorbances for all the absorption features in low-temperature H2O2 ice have been derived from these spectra. For identifying H2O2 ice, the key results are the presence of unique features near 3.5, 7.0, and 11.3 micron. Comparing the laboratory spectra with the spectra of a group of 24 protostars and field stars, all of which have strong H2O ice absorption bands, no absorption features are found that can definitely be identified with H2O2 ice. In the absence of definite H2O2 features, the H2O2 abundance is constrained by its possible contribution to the weak absorption feature near 3.47 micron found on the long-wavelength wing of the 3 micron H2O ice band. This gives an average upper limit for H2O2, as a percentage of H2O, of 9% +/- 4%. This is a strong constraint on parameters for surface chemistry experiments and dense cloud chemistry models.

A reanalysis of the HCO(+)/HOC(+) abundance ratio in dense interstellar clouds

NASA Technical Reports Server (NTRS)

Jarrold, M. F.; Bowers, M. T.; Defrees, D. J.; Mclean, A. D.; Herbst, E.

1986-01-01

New theoretical and experimental results have prompted a reinvestigation of the HCO(+)/HOC(+) abundance ratio in dense interstellar clouds. These results pertain principally but not exclusively to the reaction between HOC(+) and H2, which was previously calculated by DeFrees et al. (1984) to possess a large activation energy barrier. New calculations, reported here, indicate that this activation energy barrier is quite small and may well be zero. In addition, experimental results at higher energy and temperature indicate strongly that the reaction proceeds efficiently at interstellar temperatures. If HOC(+) does indeed react efficiently with H2 in interstellar clouds, the calculated HCO(+)/HOC(+) abundance ratio rises to a substantially greater value under standard dense cloud conditions than is deduced via the tentative observation of HOC(+) in Sgr B2.

Carbon chemistry in dense molecular clouds: Theory and observational constraints

NASA Technical Reports Server (NTRS)

Blake, Geoffrey A.

1990-01-01

For the most part, gas phase models of the chemistry of dense molecular clouds predict the abundances of simple species rather well. However, for larger molecules and even for small systems rich in carbon these models often fail spectacularly. Researchers present a brief review of the basic assumptions and results of large scale modeling of the carbon chemistry in dense molecular clouds. Particular attention is to the influence of the gas phase C/O ratio in molecular clouds, and the likely role grains play in maintaining this ratio as clouds evolve from initially diffuse objects to denser cores with associated stellar and planetary formation. Recent spectral line surveys at centimeter and millimeter wavelengths along with selected observations in the submillimeter have now produced an accurate inventory of the gas phase carbon budget in several different types of molecular clouds, though gaps in our knowledge clearly remain. The constraints these observations place on theoretical models of interstellar chemistry can be used to gain insights into why the models fail, and show also which neglected processes must be included in more complete analyses. Looking toward the future, larger molecules are especially difficult to study both experimentally and theoretically in such dense, cold regions, and some new methods are therefore outlined which may ultimately push the detectability of small carbon chains and rings to much heavier species.

Physical properties and evolution of GMCs in the Galaxy and the Magellanic Clouds

NASA Astrophysics Data System (ADS)

Onishi, Toshikazu

2015-08-01

Most stars are born as clusters in Giant Molecular Clouds (hereafter GMCs), and therefore the understanding of the evolution of GMCs in a galaxy is one of the key issues to investigate the evolution of the galaxy. The recent state-of-the-art radio telescopes have been enabling us to reveal the distribution of GMCs extensively in the Galaxy as well as in the nearby galaxies, and the physical properties and the evolution of the GMCs leading to cluster formations are actively being investigated. Here we present a review of studies of spatially resolved GMCs in the Galaxy and in the Large Magellanic Cloud (LMC), aiming at providing a template of GMC properties. For the Galactic GMCs, we will focus on the recent extensive survey of GMCs along the Galactic plane; the recent studies suggest cloud-cloud collision as mechanism of massive star formation. For the extra galactic GMCs, we will present recent high-resolution observations of GMCs in the LMC.The LMC is among the nearest star-forming galaxy (distance ~ 50kpc) and is almost face-on. From these aspects, it is becoming the most popular region for studying interstellar medium over an entire galaxy. For molecular gas, the NANTEN covered the entire LMC with a spatial resolution of 40 pc, revealing 272 molecular clouds whose mass ranges from ~104 to ~107 M⊙, which is the first uniform sample of GMCs in a single galaxy. Our Spitzer SAGE and Herschel HERITAGE surveys show that the interstellar medium has much smaller scale structures; full of filamentary and shell-like structures. In order to resolve the filamentary distributions and pre-stellar cores we definitely need to resolve clouds at sub-pc resolutions with ALMA and to cover regions of active cluster formation which are to be selected based on the Spitzer and Hershel data. Our ALMA targets in Cycle 1 and Cycle 2 include N159, which is the most intense and concentrated molecular cloud as shown by the brightest CO J=3-2 source in the LMC, and GMCs with different evolutionary stages. We present the maps of pre-stellar cores and linking filaments at sub-pc resolution and discuss the formation process of massive clusters.

Observing Interstellar and Intergalactic Magnetic Fields

NASA Astrophysics Data System (ADS)

Han, J. L.

2017-08-01

Observational results of interstellar and intergalactic magnetic fields are reviewed, including the fields in supernova remnants and loops, interstellar filaments and clouds, Hii regions and bubbles, the Milky Way and nearby galaxies, galaxy clusters, and the cosmic web. A variety of approaches are used to investigate these fields. The orientations of magnetic fields in interstellar filaments and molecular clouds are traced by polarized thermal dust emission and starlight polarization. The field strengths and directions along the line of sight in dense clouds and cores are measured by Zeeman splitting of emission or absorption lines. The large-scale magnetic fields in the Milky Way have been best probed by Faraday rotation measures of a large number of pulsars and extragalactic radio sources. The coherent Galactic magnetic fields are found to follow the spiral arms and have their direction reversals in arms and interarm regions in the disk. The azimuthal fields in the halo reverse their directions below and above the Galactic plane. The orientations of organized magnetic fields in nearby galaxies have been observed through polarized synchrotron emission. Magnetic fields in the intracluster medium have been indicated by diffuse radio halos, polarized radio relics, and Faraday rotations of embedded radio galaxies and background sources. Sparse evidence for very weak magnetic fields in the cosmic web is the detection of the faint radio bridge between the Coma cluster and A1367. Future observations should aim at the 3D tomography of the large-scale coherent magnetic fields in our Galaxy and nearby galaxies, a better description of intracluster field properties, and firm detections of intergalactic magnetic fields in the cosmic web.

Stormy Clouds of Star Birth

NASA Technical Reports Server (NTRS)

2004-01-01

Hidden behind a shroud of dust in the constellation Cygnus is an exceptionally bright source of radio emission called DR21. Visible light images reveal no trace of what is happening in this region because of heavy dust obscuration. In fact, visible light is attenuated in DR21 by a factor of more than 10,000,000,000,000,000,000,000,000,000, 000,000,000,000 (ten thousand trillion heptillion).

New images from NASA's Spitzer Space Telescope allow us to peek behind the cosmic veil and pinpoint one of the most massive natal stars yet seen in our Milky Way galaxy. The never-before-seen star is 100,000 times as bright as the Sun. Also revealed for the first time is a powerful outflow of hot gas emanating from this star and bursting through a giant molecular cloud.

This image shows a 24-micron image mosaic, obtained with the Multiband Imaging Photometer aboard Spitzer (MIPS). This image maps the cooler infrared emission from interstellar dust found throughout the interstellar medium. The DR21 complex is clearly seen near the center of the strip, which covers about twice the area of the IRAC image.

Perhaps the most fascinating feature in this image is a long and shadowy linear filament extending towards the 10 o'clock position of DR21. This jet of cold and dense gas, nearly 50 light-years in extent, appears in silhouette against a warmer background. This filament is too long and massive to be a stellar jet and may have formed from a pre-existing molecular cloud core sculpted by DR21's strong winds. Regardless of its true nature, this jet and the numerous other arcs and wisps of cool dust signify the interstellar turbulence normally unseen by the human eye.

The interstellar medium in the starburst regions of NGC 253 and NGC 3256

NASA Astrophysics Data System (ADS)

Carral, P.; Hollenbach, D. J.; Lord, S. D.; Colgan, S. W. J.; Haas, Michael R.; Rubin, R. H.; Erickson, E. F.

1994-03-01

We discuss observations of the (C II) 158 micrometers, (O I) 63 micrometers, (Si II) 35 micrometers, (O III) 52,88 micrometers, and (S III) 33 micrometers fine-structure transitions toward the central 45 seconds of the starburst galaxies NGC 253 and NGC 3256. The (C II) and (O I) emission probably originates in photodissociated gas at the surfaces of molecular clouds, although a small (less than or approximately 30%) contribution to the (C II) flux from H II regions cannot be ruled out. The (O III) and (S III) lines originate in H II regions and the (Si II) flux is best explained as originating in H II regions with some contribution from photodissociation regions (PDRs). The gas phase silicon abundance is nearly solar in NGC 253, which we interpret as evidence for grain destruction in the starburst region. We find that the photodissociated atomic gas has densities approximately 104/cu cm and temperature 200-300 K. About 2% of the gas is in this phase. The thermal gas pressure in the PDRs, P(PDR)/k approximately 1-3 x 106 K/cu cm, might represent the 'typical' interstellar gas pressure in starburst systems. The Far Ultraviolet (FUV) radiation fields illuminating the clouds are 103-104 stronger than the local Galactic FUV field and come from the contribution of many closely packed O and B stars. For the central 250 pc of NGC 253, we find that the H II gas has an average density ne is approximately 400/cu cm. This corresponds to a thermal pressure P(H II)/k approximately 7 x 106 K/cu cm which is approximately P(PDR)/k, suggesting that the ionized gas is in pressure equilibrium with the photodissociated gas at the surfaces of molecular clouds. The H II gas fills a significant fraction, approximately 0.01-0.3, of the volume between the clouds. The effective temperature of the ionizing stars in NGC 253 is greater than or approximately 34,500 K; 2 x 105 O7.5 stars would produce the observed Lyman continuum photon luminosity. The average separation between the stars is approximately 3 pc. Applying the simple model for the interstellar medium in galactic nuclei of Wolfire, Tielens, & Hollenbach (1990), we find the molecular gas in the central regions of NGC 253 and NGC 3256 to be distributed in a large number (5 x 103 to 5 x 105) of small (0.5-2 pc), dense (approximately 104/cu cm) clouds (or alternatively 'thin-flattened' structures) with volume filling factors 10-3 to 10-2, very different from the local Interstellar Medium (ISM) of the Galaxy. We suggest a self-consistent scenario for the ISM in NGC 253 in which clouds and H II gas are in pressure balance with a supernova-shocked, hot 1-3 x 106 K, low-density (approximately 104/cu cm), all pervasive medium. A feedback mechanism may be indicated in which the pressure generated by the supernovae compresses the molecular clouds and triggers further massive star formation. The similarity of ISM parameters deduced for NGC 253, NGC 3256, and M82 (Lord et al. 1993) suggests that the ISM properties are independent of the luminosity of the starburst or the triggering mechanism, but are rather endemic to starburst systems. The starburst in NGC 3256 appears to be a scaled-up version of the NGC 253 and M82 starbursts.

Recognition and characterization of hierarchical interstellar structure. II - Structure tree statistics

NASA Technical Reports Server (NTRS)

Houlahan, Padraig; Scalo, John

1992-01-01

A new method of image analysis is described, in which images partitioned into 'clouds' are represented by simplified skeleton images, called structure trees, that preserve the spatial relations of the component clouds while disregarding information concerning their sizes and shapes. The method can be used to discriminate between images of projected hierarchical (multiply nested) and random three-dimensional simulated collections of clouds constructed on the basis of observed interstellar properties, and even intermediate systems formed by combining random and hierarchical simulations. For a given structure type, the method can distinguish between different subclasses of models with different parameters and reliably estimate their hierarchical parameters: average number of children per parent, scale reduction factor per level of hierarchy, density contrast, and number of resolved levels. An application to a column density image of the Taurus complex constructed from IRAS data is given. Moderately strong evidence for a hierarchical structural component is found, and parameters of the hierarchy, as well as the average volume filling factor and mass efficiency of fragmentation per level of hierarchy, are estimated. The existence of nested structure contradicts models in which large molecular clouds are supposed to fragment, in a single stage, into roughly stellar-mass cores.

Probing the chemical environments of early star formation: A multidisciplinary approach

NASA Astrophysics Data System (ADS)

Hardegree-Ullman, Emily Elizabeth

Chemical compositions of prestellar and protostellar environments in the dense interstellar medium are best quantified using a multidisciplinary approach. For my dissertation, I completed two projects to measure molecular abundances during the earliest phases of star formation. The first project investigates gas phase CO depletion in molecular cloud cores, the progenitors of star systems, using infrared photometry and molecular line spectroscopy at radio wavelengths. Hydrogenation of CO depleted onto dust is an important first step toward building complex organic molecules. The second project constrains polycyclic aromatic hydrocarbon (PAH) abundances toward young stellar objects (YSO). Band strengths measured from laboratory spectroscopy of pyrene/water ice mixtures were applied to estimate abundances from features attributed to PAHs in observational YSO spectra. PAHs represent a distinct but important component of interstellar organic material that is widely observed but not well quantified in star-forming regions.

Observations of molecular and atomic gas in photodissociation regions. [interstellar chemistry

NASA Technical Reports Server (NTRS)

Jaffe, D. T.; Howe, J. E.

1989-01-01

Dense gas at the ionized/neutral boundaries of molecular clouds illuminated by far-UV photons plays an important role in the appearance of the neutral interstellar medium. It also is a laboratory for the study of UV-photochemistry and of a number of heating and cooling phenomena not seen elsewhere. Fine structure lines of neutral and low ionization potential species dominate the cooling in the outer part of the photodissociation regions. Observations of these lines show that the regions are dense and highly clumped. Observations of H2 and CO show that heating by UV photons plays a significant role in the excitation of molecular lines near the H II/neutral boundary. Warm CO is more abundant in these regions than predicted by the standard theoretical models. Optical reflection nebulas provide an ideal laboratory for the study of photodissocciation region phenomena.

Desorption from interstellar grains

NASA Technical Reports Server (NTRS)

Leger, A.; Jura, M.; Omont, A.

1985-01-01

Different desorption mechanisms from interstellar grains are considered to resolve the conflict between the observed presence of gaseous species in molecular clouds and their expected depletion onto grains. The physics of desorption is discussed with particular reference to the process of grain heating and the specific heat of the dust material. Impulsive heating by X-rays and cosmic rays is addressed. Spot heating of the grains by cosmic rays and how this can lead to desorption of mantles from very large grains is considered. It is concluded that CO depletion on grains will be small in regions with A(V) less than five from the cloud surface and n(H) less than 10,000, in agreement with observations and in contrast to expectations from pure thermal equilibrium. Even in very dense and obscured regions and in the absence of internal ultraviolet sources, the classical evaporation of CO or N2 and O2-rich mantles by cosmic rays is important.

REVISITING THE CHLORINE ABUNDANCE IN DIFFUSE INTERSTELLAR CLOUDS FROM MEASUREMENTS WITH THE COPERNICUS SATELLITE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moomey, Daniel; Federman, S. R.; Sheffer, Y., E-mail: steven.federman@utoledo.edu, E-mail: ysheffer@astro.umd.edu

2012-01-10

We reanalyzed interstellar Cl I and Cl II spectra acquired with the Copernicus satellite. The directions for this study come from those of Crenny and Federman and sample the transition from atomic to molecular-rich clouds where the unique chemistry leading to molecules containing chlorine is initiated. Our profile syntheses relied on up-to-date laboratory oscillator strengths and component structures derived from published high-resolution measurements of K I absorption that were supplemented with Ca II and Na I D results. We obtain self-consistent results for the Cl I lines at 1088, 1097, and 1347 A from which precise column densities are derived.more » The improved set of results reveals clearer correspondences with H{sub 2} and total hydrogen column densities. These linear relationships arise from rapid conversion of Cl{sup +} to Cl{sup 0} in regions where H{sub 2} is present.« less

Ortho- and para-hydrogen in dense clouds, protoplanets, and planetary atmospheres

NASA Technical Reports Server (NTRS)

Decampli, W. M.; Cameron, A. G. W.; Bodenheimer, P.; Black, D. C.

1978-01-01

If ortho- and para-hydrogen achieve a thermal ratio on dynamical time scales in a molecular hydrogen cloud, then the specific heat is high enough in the temperature range 35-70 K to possibly induce hydrodynamic collapse. The ortho-para ratio in many interstellar cloud fragments is expected to meet this condition. The same may have been true for the primitive solar nebula. Detailed hydrodynamic and hydrostatic calculations are presented that show the effects of the assumed ortho-para ratio on the evolution of Jupiter during its protoplanetary phase. Some possible consequences of a thermalized ortho-para ratio in the atmospheres of the giant planets are also discussed.

Properties of Cold HI Emission Clouds in the Inner-Galaxy ALFA Survey

NASA Astrophysics Data System (ADS)

Hughes, James Marcus; Gibson, Steven J.; Noriega-Crespo, Alberto; Newton, Jonathan; Koo, Bon-Chul; Douglas, Kevin A.; Peek, Joshua Eli Goldston; Park, Geumsook; Kang, Ji-hyun; Korpela, Eric J.; Heiles, Carl E.; Dame, Thomas M.

2017-01-01

Star formation, a critical process within galaxies, occurs in the coldest, densest interstellar clouds, whose gas and dust content are observed primarily at radio and infrared wavelengths. The formation of molecular hydrogen (H2) from neutral atomic hydrogen (HI) is an essential early step in the condensation of these clouds from the ambient interstellar medium, but it is not yet completely understood, e.g., what is the predominant trigger? Even more troubling, the abundance of H2 may be severely underestimated by standard tracers like CO, implying significant "dark" H2, and the quantity of HI may also be in error if opacity effects are neglected. We have developed an automated method to account for both HI and H2 in cold, diffuse clouds traced by narrow-line HI 21-cm emission in the Arecibo Inner-Galaxy ALFA (I-GALFA) survey. Our algorithm fits narrow (2-5 km/s), isolated HI line profiles to determine their spin temperature, optical depth, and true column density. We then estimate the "visible" H2 column in the same clouds with CfA and Planck CO data and the total gas column from dust emission measured by Planck, IRAS, and other surveys. Together, these provide constraints on the dark H2 abundance, which we examine in relation to other cloud properties and stages of development. Our aim is to build a database of H2-forming regions with significant dark gas to aid future analyses of coalescing interstellar clouds. We acknowledge support from NSF, NASA, Western Kentucky University, and Williams College. I-GALFA is a GALFA-HI survey observed with the 7-beam ALFA receiver on the 305-meter William E. Gordon Telescope. The Arecibo Observatory is a U.S. National Science Foundation facility operated under sequential cooperative agreements with Cornell University and SRI International, the latter in alliance with the Ana G. Mendez-Universidad Metropolitana and the Universities Space Research Association.

Copernicus observations of C I and CO in diffuse interstellar clouds

NASA Technical Reports Server (NTRS)

Jenkins, E. B.; Jura, M.; Loewenstein, M.

1980-01-01

Copernicus was used to observe absorption lines of C I in its ground state and excited fine structure levels and CO toward 29 stars. We use the C I data to infer densities and pressures within the observed clouds, and because our results are of higher precision than previous work, much more precise estimates of the physical conditions in clouds are obtained. In agreement with previous work, the interstellar thermal pressure appears to be variable, with most clouds having values of p/k between 1000/cu cm K and 10,000/cu cm K, but there are some clouds with p/k as high as 100,000/cu cm K. Our results are consistent with the view that the interstellar thermal pressure is so variable that the gas undergoes continuous dynamic evolution. Our observations provide useful constraints on the physical processes on the surfaces of grains. In particular, we find that grains are efficient catalysts of interstellar H2 in the sense that at least half of the hydrogen atoms that strike grains come off as part of H2. Results place strong constraints on models for the formation and destruction of interstellar CO. In many clouds, an order of magnitude less CO than predicted in some models was found.

Physical conditions in CaFe interstellar clouds

NASA Astrophysics Data System (ADS)

Gnaciński, P.; Krogulec, M.

2008-01-01

Interstellar clouds that exhibit strong Ca I and Fe I lines are called CaFe clouds. Ionisation equilibrium equations were used to model the column densities of Ca II, Ca I, K I, Na I, Fe I and Ti II in CaFe clouds. We find that the chemical composition of CaFe clouds is solar and that there is no depletion into dust grains. CaFe clouds have high electron densities, n_e≈1 cm-3, that lead to high column densities of neutral Ca and Fe.

Millimeter-wave Absorption Studies of Molecules in Diffuse Clouds

NASA Astrophysics Data System (ADS)

Lucas, Robert; Liszt, Harvey S.

1999-10-01

With IRAM instruments in the last few years, we have been using compact extragalactic millimeter wave radio sources as background objects to study the absorption spectrum of diffuse interstellar gas at millimeter wavelengths. The molecular content of interstellar gas has turned out to be unexpectedly rich. Simple polyatomic molecules such as HCO+, C2H are quite ubiquitous near the Galactic plane (beta < 15o), and many species are detected in some directions (CO, HCO+, H2CO, HCN, HNC, CN, C2H, C3H2, H2S, CS, HCS+, SO, SiO). Remarkable proportionality relations are found between related species such as HCO+ and OH, or CN, HCN and HNC. The high abundance of some species is still a challenge for current models of diffuse cloud chemistry. A factor of 10 increase in the sensitivity will make such studies achievable in denser clouds, where the chemistry is still more active and where abundances are nowadays only available by emission measurements, and thus subject to uncertainties due to sometimes poorly understood line formation and excitation conditions.

A detailed investigation of proposed gas-phase syntheses of ammonia in dense interstellar clouds

NASA Technical Reports Server (NTRS)

Herbst, Eric; Defrees, D. J.; Mclean, A. D.

1987-01-01

The initial reactions of the Herbst and Klemperer (1973) and the Dalgarno (1974) schemes (I and II, respectively) for the gas-phase synthesis of ammonia in dense interstellar clouds were investigated. The rate of the slightly endothermic reaction between N(+) and H2 to yield NH(+) and H (scheme I) under interstellar conditions was reinvestigated under thermal and nonthermal conditions based on laboratory data. It was found that the relative importance of this reaction in synthesizing ammonia is determined by how the laboratory data at low temperature are interpreted. On the other hand, the exothermic reaction between N and H3(+) to form NH2(+) + H (scheme II) was calculated to possess significant activation energy and, therefore, to have a negligible rate coefficient under interstellar conditions. Consequently, this reaction cannot take place appreciably in interstellar clouds.

Optical observations of nearby interstellar gas

NASA Astrophysics Data System (ADS)

Frisch, P. C.; York, D. G.

1984-11-01

Observations indicated that a cloud with a heliocentric velocity of approximately -28 km/s and a hydrogen column density that possibly could be on the order of, or greater than, 5 x 10 to the 19 power/square cm is located within the nearest 50 to 80 parsecs in the direction of Ophiuchus. This is a surprisingly large column density of material for this distance range. The patchy nature of the absorption from the cloud indicates that it may not be a feature with uniform properties, but rather one with small scale structure which includes local enhancements in the column density. This cloud is probably associated with the interstellar cloud at about the same velocity in front of the 20 parsec distant star alpha Oph (Frisch 1981, Crutcher 1982), and the weak interstellar polarization found in stars as near as 35 parsecs in this general region (Tinbergen 1982). These data also indicate that some portion of the -14 km/s cloud also must lie within the 100 parsec region. Similar observations of both Na1 and Ca2 interstellar absorption features were performed in other lines of sight. Similar interstellar absorption features were found in a dozen stars between 20 and 100 parsecs of the Sun.

Optical Observations of Nearby Interstellar Gas

NASA Technical Reports Server (NTRS)

Frisch, P. C.; York, D. G.

1984-01-01

Observations indicated that a cloud with a heliocentric velocity of approximately -28 km/s and a hydrogen column density that possibly could be on the order of, or greater than, 5 x 10 to the 19 power/square cm is located within the nearest 50 to 80 parsecs in the direction of Ophiuchus. This is a surprisingly large column density of material for this distance range. The patchy nature of the absorption from the cloud indicates that it may not be a feature with uniform properties, but rather one with small scale structure which includes local enhancements in the column density. This cloud is probably associated with the interstellar cloud at about the same velocity in front of the 20 parsec distant star alpha Oph (Frisch 1981, Crutcher 1982), and the weak interstellar polarization found in stars as near as 35 parsecs in this general region (Tinbergen 1982). These data also indicate that some portion of the -14 km/s cloud also must lie within the 100 parsec region. Similar observations of both Na1 and Ca2 interstellar absorption features were performed in other lines of sight. Similar interstellar absorption features were found in a dozen stars between 20 and 100 parsecs of the Sun.

A general theory for the lifetimes of giant molecular clouds under the influence of galactic dynamics

NASA Astrophysics Data System (ADS)

Jeffreson, Sarah M. R.; Kruijssen, J. M. Diederik

2018-05-01

We propose a simple analytic theory for environmentally dependent molecular cloud lifetimes, based on the large-scale (galactic) dynamics of the interstellar medium. Within this theory, the cloud lifetime is set by the time-scales for gravitational collapse, galactic shear, spiral arm interactions, epicyclic perturbations, and cloud-cloud collisions. It is dependent on five observable quantities, accessible through measurements of the galactic rotation curve, the gas and stellar surface densities, and the gas and stellar velocity dispersions of the host galaxy. We determine how the relative importance of each dynamical mechanism varies throughout the space of observable galactic properties, and conclude that gravitational collapse and galactic shear play the greatest role in setting the cloud lifetime for the considered range of galaxy properties, while cloud-cloud collisions exert a much lesser influence. All five environmental mechanisms are nevertheless required to obtain a complete picture of cloud evolution. We apply our theory to the galaxies M31, M51, M83, and the Milky Way, and find a strong dependence of the cloud lifetime upon galactocentric radius in each case, with a typical cloud lifetime between 10 and 50 Myr. Our theory is ideally suited for systematic observational tests with the Atacama Large Millimetre/submillimetre array.

Synthesis of Large Molecules in Cometary Ice Analogs: Physical Properties Related to Self-Assembly Processes

NASA Technical Reports Server (NTRS)

Dworkin, Jason P.; Sandford, Scott A.; Deamer, David W.; Gillette, J. Seb; Zare, Richard N.; Allamandola, Louis J. (Technical Monitor)

1999-01-01

The combination of realistic laboratory simulations and infrared observations have revolutionized our understanding of interstellar dust and ice-the main component of comets. Since comets and carbonaceous micrometeorites may have been important sources of volatiles and carbon compounds on the early Earth, their organic composition may be related to the origin of life. Ices on grains in molecular clouds contain a variety of simple molecules. The D/H ratios of the comets Hale-Bopp and Hyakutake are consistent with a primarily interstellar ice mixture. Within the cloud and especially in the presolar nebula through the early solar system, these icy grains would have been photoprocessed by the ultraviolet producing more complex species such as hexamethylenetetramine, polyoxymethylenes, and simple keones. We reported at the 1999 Bioastronomy meeting laboratory simulations studied to identify the types of molecules which could have been generated in pre-cometary ices. Experiments were conducted by forming a realistic interstellar mixed-molecular ice (H2O, CH3OH, NH3 and CO) at approximately 10 K under high vacuum irradiated with UV light from a hydrogen plasma lamp. The gas mixture was typically 100:50:1:1, however when different ratios were used material with similar characteristics was still produced. The residue that remained after warming to room temperature was analyzed by HPLC, and by several mass spectrometric methods. This material contains a rich mixture of complex compounds with mass spectral profiles resembling those found in IDPs and meteorites. Surface tension measurements show that an amphiphilic component is also present. These species do not appear in various controls or in unphotolyzed samples. Residues from the simulations were also dispersed in aqueous media for microscopy. The organic material forms 10-40 gm diameter droplets that fluoresce at 300-450 nm under UV excitation. These droplets have a morphology and internal structure which appear strikingly similar to those produced by extracts of the Murchison meteorite. Together, these results suggest a link between organic material photochemically synthesized on the cold grains in dense, interstellar molecular clouds and compounds that may have contributed to the organic inventory of the primitive Earth. For example, the amphiphilic properties of such compounds permit self-assembly into the membranous boundary structures that required for the first forms of cellular life.

[Activities of Harvard College Observatory

NASA Technical Reports Server (NTRS)

Dalgarno, A.; Smith, Peter L.; Stark, G.; Yoshino, K.

2002-01-01

With support from this grant, we have: 1) Developed techniques for improving wavelengths and f-values for singly and doubly charged ions of the iron group and have improved the accuracy of Fe III wavelengths by an order of magnitude. New Fe II f-values have also resulted from this work. 2) Measured line oscillator strengths and photoabsorption cross sections for UV molecular spectral feature that have been, or could be, used for searches for and detection of molecules in diffuse and translucent interstellar clouds and for determination of molecular column densities there. In addition, we have determined other molecular parameters -- line assignments, wavelengths, and line widths -- that are essential for theoretical descriptions of the abundance, fractionation, and excitation of interstellar molecules and for comparison of predictions with observations. 3) Measured A-values for spin-changing and other weak lines in low-Z ions. When A-values are available, these spectral features are useful for astrophysical plasma density and temperature diagnostics. Such lines are also used in interstellar abundance determinations in cases where the stronger allowed lines are saturated in astronomical spectra. 4) Taken an activist approach to ensuring that, (i), astronomers have ready access to our data, and, (ii), avenues of communication between data users and producers are strengthened.

The Behavior of Selected Diffuse Interstellar Bands with Molecular Fraction in Diffuse Atomic and Molecular Clouds

NASA Astrophysics Data System (ADS)

Fan, Haoyu; Welty, Daniel E.; York, Donald G.; Sonnentrucker, Paule; Dahlstrom, Julie A.; Baskes, Noah; Friedman, Scott D.; Hobbs, Lewis M.; Jiang, Zihao; Rachford, Brian; Snow, Theodore P.; Sherman, Reid; Zhao, Gang

2017-12-01

We study the behavior of eight diffuse interstellar bands (DIBs) in different interstellar environments, as characterized by the fraction of hydrogen in molecular form (f H2), with comparisons to the corresponding behavior of various known atomic and molecular species. The equivalent widths of the five “normal” DIBs (λλ5780.5, 5797.1, 6196.0, 6283.8, and 6613.6), normalized to E B-V , show a “lambda-shaped” behavior: they increase at low f H2, peak at f H2 ˜ 0.3, and then decrease. The similarly normalized column densities of Ca, Ca+, Ti+, and CH+ also decline for f H2 > 0.3. In contrast, the normalized column densities of Na, K, CH, CN, and CO increase monotonically with f H2, and the trends exhibited by the three C2 DIBs (λλ4726.8, 4963.9, and 4984.8) lie between those two general behaviors. These trends with f H2 are accompanied by cosmic scatter, the dispersion at any given f H2 being significantly larger than the individual errors of measurement. The lambda-shaped trends suggest the balance between creation and destruction of the DIB carriers differs dramatically between diffuse atomic and diffuse molecular clouds; additional processes aside from ionization and shielding are needed to explain those observed trends. Except for several special cases, the highest W λ (5780)/W λ (5797) ratios, characterizing the so-called “sigma-zeta effect,” occur only at f H2 < 0.2. We propose a sequence of DIBs based on trends in their pair-wise strength ratios with increasing f H2. In order of increasing environmental density, we find the λ6283.8 and λ5780.5 DIBs, the λ6196.0 DIB, the λ6613.6 DIB, the λ5797.1 DIB, and the C2 DIBs.

Radiative heating of interstellar grains falling toward the solar nebula: 1-D diffusion calculations

NASA Technical Reports Server (NTRS)

Simonelli, D. P.; Pollack, J. B.; McKay, C. P.

1997-01-01

As the dense molecular cloud that was the precursor of our Solar System was collapsing to form a protosun and the surrounding solar-nebula accretion disk, infalling interstellar grains were heated much more effectively by radiation from the forming protosun than by radiation from the disk's accretion shock. Accordingly, we have estimated the temperatures experienced by these infalling grains using radiative diffusion calculations whose sole energy source is radiation from the protosun. Although the calculations are 1-dimensional, they make use of 2-D, cylindrically symmetric models of the density structure of a collapsing, rotating cloud. The temperature calculations also utilize recent models for the composition and radiative properties of interstellar grains (Pollack et al. 1994. Astrophys. J. 421, 615-639), thereby allowing us to estimate which grain species might have survived, intact, to the disk accretion shock and what accretion rates and molecular-cloud rotation rates aid that survival. Not surprisingly, we find that the large uncertainties in the free parameter values allow a wide range of grain-survival results: (1) For physically plausible high accretion rates or low rotation rates (which produce small accretion disks), all of the infalling grain species, even the refractory silicates and iron, will vaporize in the protosun's radiation field before reaching the disk accretion shock. (2) For equally plausible low accretion rates or high rotation rates (which produce large accretion disks), all non-ice species, even volatile organics, will survive intact to the disk accretion shock. These grain-survival conclusions are subject to several limitations which need to be addressed by future, more sophisticated radiative-transfer models. Nevertheless, our results can serve as useful inputs to models of the processing that interstellar grains undergo at the solar nebula's accretion shock, and thus help address the broader question of interstellar inheritance in the solar nebula and present Solar System. These results may also help constrain the size of the accretion disk: for example, if we require that the calculations produce partial survival of organic grains into the solar nebula, we infer that some material entered the disk intact at distances comparable to or greater than a few AU. Intriguingly, this is comparable to the heliocentric distance that separates the C-rich outer parts of the current Solar System from the C-poor inner regions.

Radiative heating of interstellar grains falling toward the solar nebula: 1-D diffusion calculations.

PubMed

Simonelli, D P; Pollack, J B; McKay, C P

1997-02-01

As the dense molecular cloud that was the precursor of our Solar System was collapsing to form a protosun and the surrounding solar-nebula accretion disk, infalling interstellar grains were heated much more effectively by radiation from the forming protosun than by radiation from the disk's accretion shock. Accordingly, we have estimated the temperatures experienced by these infalling grains using radiative diffusion calculations whose sole energy source is radiation from the protosun. Although the calculations are 1-dimensional, they make use of 2-D, cylindrically symmetric models of the density structure of a collapsing, rotating cloud. The temperature calculations also utilize recent models for the composition and radiative properties of interstellar grains (Pollack et al. 1994. Astrophys. J. 421, 615-639), thereby allowing us to estimate which grain species might have survived, intact, to the disk accretion shock and what accretion rates and molecular-cloud rotation rates aid that survival. Not surprisingly, we find that the large uncertainties in the free parameter values allow a wide range of grain-survival results: (1) For physically plausible high accretion rates or low rotation rates (which produce small accretion disks), all of the infalling grain species, even the refractory silicates and iron, will vaporize in the protosun's radiation field before reaching the disk accretion shock. (2) For equally plausible low accretion rates or high rotation rates (which produce large accretion disks), all non-ice species, even volatile organics, will survive intact to the disk accretion shock. These grain-survival conclusions are subject to several limitations which need to be addressed by future, more sophisticated radiative-transfer models. Nevertheless, our results can serve as useful inputs to models of the processing that interstellar grains undergo at the solar nebula's accretion shock, and thus help address the broader question of interstellar inheritance in the solar nebula and present Solar System. These results may also help constrain the size of the accretion disk: for example, if we require that the calculations produce partial survival of organic grains into the solar nebula, we infer that some material entered the disk intact at distances comparable to or greater than a few AU. Intriguingly, this is comparable to the heliocentric distance that separates the C-rich outer parts of the current Solar System from the C-poor inner regions.

Gas-phase chemistry in dense interstellar clouds including grain surface molecular depletion and desorption

NASA Technical Reports Server (NTRS)

Bergin, E. A.; Langer, W. D.; Goldsmith, P. F.

1995-01-01

We present time-dependent models of the chemical evolution of molecular clouds which include depletion of atoms and molecules onto grain surfaces and desorption, as well as gas-phase interactions. We have included three mechanisms to remove species from the grain mantles: thermal evaporation, cosmic-ray-induced heating, and photodesorption. A wide range of parameter space has been explored to examine the abundance of species present both on the grain mantles and in the gas phase as a function of both position in the cloud (visual extinction) and of evolutionary state (time). The dominant mechanism that removes molecules from the grain mantles is cosmic-ray desorption. At times greater than the depletion timescale, the abundances of some simple species agree with abundances observed in the cold dark cloud TMC-1. Even though cosmic-ray desorption preserves the gas-phase chemistry at late times, molecules do show significant depletions from the gas phase. Examination of the dependence of depletion as a function of density shows that when the density increases from 10(exp 3)/cc to 10(exp 5)/cc several species including HCO(+), HCN, and CN show gas-phase abundance reductions of over an order of magnitude. The CO: H2O ratio in the grain mantles for our standard model is on the order of 10:1, in reasonable agreement with observations of nonpolar CO ice features in rho Ophiuchus and Serpens. We have also examined the interdependence of CO depletion with the space density of molecular hydrogen and binding energy to the grain surface. We find that the observed depletion of CO in Taurus in inconsistent with CO bonding in an H2O rich mantle, in agreement with observations. We suggest that if interstellar grains consist of an outer layer of CO ice, then the binding energies for many species to the grain mantle may be lower than commonly used, and a significant portion of molecular material may be maintained in the gas phase.

FOREST unbiased Galactic plane imaging survey with the Nobeyama 45 m telescope (FUGIN). I. Project overview and initial results

NASA Astrophysics Data System (ADS)

Umemoto, Tomofumi; Minamidani, Tetsuhiro; Kuno, Nario; Fujita, Shinji; Matsuo, Mitsuhiro; Nishimura, Atsushi; Torii, Kazufumi; Tosaki, Tomoka; Kohno, Mikito; Kuriki, Mika; Tsuda, Yuya; Hirota, Akihiko; Ohashi, Satoshi; Yamagishi, Mitsuyoshi; Handa, Toshihiro; Nakanishi, Hiroyuki; Omodaka, Toshihiro; Koide, Nagito; Matsumoto, Naoko; Onishi, Toshikazu; Tokuda, Kazuki; Seta, Masumichi; Kobayashi, Yukinori; Tachihara, Kengo; Sano, Hidetoshi; Hattori, Yusuke; Onodera, Sachiko; Oasa, Yumiko; Kamegai, Kazuhisa; Tsuboi, Masato; Sofue, Yoshiaki; Higuchi, Aya E.; Chibueze, James O.; Mizuno, Norikazu; Honma, Mareki; Muller, Erik; Inoue, Tsuyoshi; Morokuma-Matsui, Kana; Shinnaga, Hiroko; Ozawa, Takeaki; Takahashi, Ryo; Yoshiike, Satoshi; Costes, Jean; Kuwahara, Sho

2017-10-01

The FUGIN project is one of legacy projects using a new multi-beam FOREST (four-beam receiver system on the 45 m telescope). This project aims to simultaneously investigate the distribution, kinematics, and physical properties of both diffuse and dense molecular gases in the Galaxy by observing 12CO, 13CO, and C18O J = 1-0 lines simultaneously. Mapping regions are parts of the first quadrant (10° ≤ l ≤ 50°, |b| ≤ 1°) and the third quadrant (198° ≤ l ≤ 236°, |b| ≤ 1°) of the Galaxy, where spiral arms, bar structure, and the molecular gas ring are included. This survey achieves the highest angular resolution to date (˜20″) for the Galactic plane survey in the CO J = 1-0 lines, which makes it possible to find dense clumps located farther away than the previous surveys. FUGIN will provide us an invaluable dataset for investigating the physics of the Galactic interstellar medium (ISM), particularly the evolution of interstellar gas covering galactic-scale structures to the internal structures of giant molecular clouds, such as small filaments/clumps/cores. We present an overview of the FUGIN project, the observation plan and initial results. These results reveal wide-field and detailed structures of molecular clouds, such as entangled filaments that have not been obvious in previous surveys, and large-scale kinematics of molecular gas, such as spiral arms.

Interstellar Chemistry Special Feature: The chemistry in circumstellar envelopes of evolved stars: Following the origin of the elements to the origin of life

NASA Astrophysics Data System (ADS)

Ziurys, Lucy M.

2006-08-01

Mass loss from evolved stars results in the formation of unusual chemical laboratories: circumstellar envelopes. Such envelopes are found around carbon- and oxygen-rich asymptotic giant branch stars and red supergiants. As the gaseous material of the envelope flows from the star, the resulting temperature and density gradients create a complex chemical environment involving hot, thermodynamically controlled synthesis, molecule "freeze-out," shock-initiated reactions, and photochemistry governed by radical mechanisms. In the circumstellar envelope of the carbon-rich star IRC+10216, >50 different chemical compounds have been identified, including such exotic species as C8H, C3S, SiC3, and AlNC. The chemistry here is dominated by molecules containing long carbon chains, silicon, and metals such as magnesium, sodium, and aluminum, which makes it quite distinct from that found in molecular clouds. The molecular composition of the oxygen-rich counterparts is not nearly as well explored, although recent studies of VY Canis Majoris have resulted in the identification of HCO+, SO2, and even NaCl in this object, suggesting chemical complexity here as well. As these envelopes evolve into planetary nebulae with a hot, exposed central star, synthesis of molecular ions becomes important, as indicated by studies of NGC 7027. Numerous species such as HCO+, HCN, and CCH are found in old planetary nebulae such as the Helix. This "survivor" molecular material may be linked to the variety of compounds found recently in diffuse clouds. Organic molecules in dense interstellar clouds may ultimately be traced back to carbon-rich fragments originally formed in circumstellar shells.

Structures Of Magnetically-Supported Filaments And Their Appearance In The Linear Polarization

NASA Astrophysics Data System (ADS)

Tomisaka, Kohji

2017-10-01

Dust thermal emissions observed with Herschel have revealed that interstellar molecular clouds consist of many filaments. Polarization observation of interstellar extinctions in the optical and near IR wavelengths shows that the dense filaments are extending perpendicular to the interstellar magnetic field. Magnetohydrostatic structures of such filaments are studied. It is well known that a hydrostatic filament without magnetic field has a maximum line mass of ¥lambda_max=2c_s^2/G (c_s:the isothermal sound speed and G: the gravitational constant). On the other hand, the magnetically-supported maximum line mass increases in proportion to the magnetic flux per unit length threading the filament (¥phi), as ¥lambda_max 2c_s^2/G + ¥phi/(2¥pi G^1/2). Comparison is made with 3D clouds. Stability of these magnetized filaments is studied using time-dependent 3D MHD simulations to discuss star formation in the filaments. Polarization pattern expected for the magnetically subcritical filaments is calculated. The distribution function of the angle between B-field and the axis of the filament, which is obtained with Planck Satellite, is compared with this mock observation.

Far-infrared Spectroscopy of Interstellar Gas

NASA Technical Reports Server (NTRS)

Phillips, T. G.

1984-01-01

Research results of far-infrared spectroscopy with the Kuiper Airborne Observatory are discussed. Both high and intermediate resolution have been successfully employed in the detection of many new molecular and atomic lines including rotational transition of hydrides such as OH, H2O, NH3 and HCl; high J rotational transitions of CO; and the ground state fine structure transitions of atomic carbon, oxygen, singly ionized carbon and doubly ionized oxygen and nitrogen. These transitions have been used to study the physics and chemistry of clouds throughout the galaxy, in the galactic center region and in neighboring galaxies. This discussion is limited to spectroscopic studies of interstellar gas.

Organic Chemistry of Meteorites

NASA Technical Reports Server (NTRS)

Chang, S.; Morrison, David (Technical Monitor)

1994-01-01

Studies of the molecular structures and C,N,H-isotopic compositions of organic matter in meteorites reveal a complex history beginning in the parent interstellar cloud which spawned the solar system. Incorporation of interstellar dust and gas in the protosolar nebula followed by further thermal and aqueous processing on primordial parent bodies of carbonaceous, meteorites have produced an inventory of diverse organic compounds including classes now utilized in biochemistry. This inventory represents one possible set of reactants for chemical models for the origin of living systems on the early Earth. Evidence bearing on the history of meteoritic organic matter from astronomical observations and laboratory investigations will be reviewed and future research directions discussed.

The formation of stellar systems from interstellar molecular clouds

NASA Technical Reports Server (NTRS)

Gehrz, R. D.; Black, D. C.; Solomon, P.M.

1984-01-01

The observational and theoretical study of regions of continuing star formation promises greater insight into the physical conditions and events associated with the formation of the solar system, and elucidates the role played by star formation in the evolutionary cycle which seems to dominate interstellar material's processing by successive generations of stars in the spiral galaxies. Novel astronomical methods incorporated by the new facilities scheduled for development in the 1980s may yield substantial advancements in star formation process theory; most significant among these efforts will be the identification and examination of the elusive protostellar collapse phase of both star and planetary system formation.

Evaluating the Morphology of the Local Interstellar Medium: Using New Data to Distinguish between Multiple Discrete Clouds and a Continuous Medium

NASA Astrophysics Data System (ADS)

Redfield, Seth; Linsky, Jeffrey L.

2015-10-01

Ultraviolet and optical spectra of interstellar gas along the lines of sight to nearby stars have been interpreted by Redfield & Linsky and previous studies as a set of discrete warm, partially ionized clouds each with a different flow vector, temperature, and metal depletion. Recently, Gry & Jenkins proposed a fundamentally different model consisting of a single cloud with nonrigid flows filling space out to 9 pc from the Sun that they propose better describes the local ISM. Here we test these fundamentally different morphological models against the spatially unbiased Malamut et al. spectroscopic data set, and find that the multiple cloud morphology model provides a better fit to both the new and old data sets. The detection of three or more velocity components along the lines of sight to many nearby stars, the presence of nearby scattering screens, the observed thin elongated structures of warm interstellar gas, and the likely presence of strong interstellar magnetic fields also support the multiple cloud model. The detection and identification of intercloud gas and the measurement of neutral hydrogen density in clouds beyond the Local Interstellar Cloud could provide future morphological tests. Based on observations made with the NASA/ESA Hubble Space Telescope, obtained from the Data Archive at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS AR-09525.01A. These observations are associated with programs #11568.

Molecular clouds and the large-scale structure of the galaxy

NASA Technical Reports Server (NTRS)

Thaddeus, Patrick; Stacy, J. Gregory

1990-01-01

The application of molecular radio astronomy to the study of the large-scale structure of the Galaxy is reviewed and the distribution and characteristic properties of the Galactic population of Giant Molecular Clouds (GMCs), derived primarily from analysis of the Columbia CO survey, and their relation to tracers of Population 1 and major spiral features are described. The properties of the local molecular interstellar gas are summarized. The CO observing programs currently underway with the Center for Astrophysics 1.2 m radio telescope are described, with an emphasis on projects relevant to future comparison with high-energy gamma-ray observations. Several areas are discussed in which high-energy gamma-ray observations by the EGRET (Energetic Gamma-Ray Experiment Telescope) experiment aboard the Gamma Ray Observatory will directly complement radio studies of the Milky Way, with the prospect of significant progress on fundamental issues related to the structure and content of the Galaxy.

CO line ratios in molecular clouds: the impact of environment

NASA Astrophysics Data System (ADS)

Peñaloza, Camilo H.; Clark, Paul C.; Glover, Simon C. O.; Klessen, Ralf S.

2018-04-01

Line emission is strongly dependent on the local environmental conditions in which the emitting tracers reside. In this work, we focus on modelling the CO emission from simulated giant molecular clouds (GMCs), and study the variations in the resulting line ratios arising from the emission from the J = 1-0, J = 2-1, and J = 3-2 transitions. We perform a set of smoothed particle hydrodynamics simulations with time-dependent chemistry, in which environmental conditions - including total cloud mass, density, size, velocity dispersion, metallicity, interstellar radiation field (ISRF), and the cosmic ray ionization rate (CRIR) - were systematically varied. The simulations were then post-processed using radiative transfer to produce synthetic emission maps in the three transitions quoted above. We find that the cloud-averaged values of the line ratios can vary by up to ±0.3 dex, triggered by changes in the environmental conditions. Changes in the ISRF and/or in the CRIR have the largest impact on line ratios since they directly affect the abundance, temperature, and distribution of CO-rich gas within the clouds. We show that the standard methods used to convert CO emission to H2 column density can underestimate the total H2 molecular gas in GMCs by factors of 2 or 3, depending on the environmental conditions in the clouds.

Formaldehyde in the Diffuse Interstellar Cloud MBM40

NASA Astrophysics Data System (ADS)

Joy, Mackenzie; Magnani, Loris A.

2018-06-01

MBM40, a high-latitude molecular cloud, has been extensively studied using different molecular tracers. It appears that MBM40 is composed of a relatively dense, helical filament embedded in a more diffuse substrate of low density molecular gas. In order to study the transition between the two regimes, this project presents the first high-resolution mapping of MBM40 using the 110-111 hyperfine transition of formaldehyde (H2CO) at 4.83 GHz. We used H2CO spectra obtained with the Arecibo telescope more than a decade ago to construct this map. The results can be compared to previous maps made from the CO(1-0) transition to gain further understanding of the structure of the cloud. The intensity of the H2CO emission was compared to the CO emission. Although a correlation exists between the H2CO and CO emissivity, there seems to be a saturation of H2CO line strength for stronger CO emissivity. This is probably a radiative transfer effect of the CO emission. We have also found that the velocity dispersion of H2CO in the lower ridge of the cloud is significantly lower than in the rest of the cloud. This may indicate that this portion of the cloud is a coherent structure (analogous to an eddy) in a turbulent flow.

A Combined Experimental and Theoretical Study on the Formation of Interstellar Propylene Oxide (CH3CHCH2O)—A Chiral Molecule

NASA Astrophysics Data System (ADS)

Bergantini, Alexandre; Abplanalp, Matthew J.; Pokhilko, Pavel; Krylov, Anna I.; Shingledecker, Christopher N.; Herbst, Eric; Kaiser, Ralf I.

2018-06-01

This work reveals via a combined experimental, computational, and astrochemical modeling study that racemic propylene oxide (c-C3H6O)—the first chiral molecule detected outside Earth toward the high-mass star-forming region Sagittarius B2(N)—can be synthesized by non-equilibrium reactions initiated by the effects of secondary electrons generated in the track of cosmic rays interacting with ice-coated interstellar grains through excited-state and spin-forbidden reaction pathways operating within low-temperature interstellar ices at 10 K. Our findings confront traditional hypotheses that thermal chemistries followed by processing of interstellar grains dictate the formation of complex organic molecules (COMs) in molecular clouds. Instead, we reveal a hitherto poorly quantified reaction class involving excited-state and spin-forbidden chemistry leading to racemic mixtures of COMs inside interstellar ices prior to their sublimation in star-forming regions. This fundamental production mechanism is of essential consequence in aiding our understanding of the origin and evolution of chiral molecules in the universe.

A note on compressibility and energy cascade in turbulent molecular clouds

NASA Technical Reports Server (NTRS)

Fleck, R. C., Jr.

1983-01-01

Observed velocity-size correlations are reexamined in the light of an improved theory of turbulent energy cascade that is developed. It is shown that observed velocity-size correlations cannot be compared with the Kolmogorov law, which is based on incompressible turbulent flow. The fact that the log v-log(l/rho) scaling law (v the turbulent velocity, l the associated region size, and rho the fluid density) predicted for compressible energy cascade is always steeper than that observed in molecular clouds indicates the injection rather than the dissipation of mechanical energy at smaller scales of motion. It is also shown that the concept of strict energy cascade may not be generally applicable in the interstellar medium. The agreement between theory and observation turns out to be best for small cool clouds and cloud cores, suggesting that, for these regions at least, the dominant process in establishing the observed v-l-rho correlation is a turbulent energy cascade.

Molecular Anions in Protostars, Prestellar Cores and Dark Clouds

NASA Technical Reports Server (NTRS)

Cordiner, Martin; Charnley, Steven; Buckle, Jane; Wash, Catherine; Millar, Tom

2011-01-01

From our recent survey work using the Green Bank Telescope, microwave emission lines from the hydrocarbon anion C6H(-) and its parent neutral C6H have been detected in six new sources. Using HC3N = 10(exp -9) emission maps, we targeted the most carbon-chain-rich sources for our anion survey, which included the low-mass Class 0 protostar L1251A-IRS3, the prestellar cores L1389-SMM1 and L1512, and the interstellar clouds Ll172A, TMC-1C and L1495B. Derived [C6H(-)]/[C6H] anion-to-neutral ratios are approximately 1-10. The greatest C6H(-) column densities are found in the quiescent clouds TMC-1C and L1495B, but the anion-to-neutral ratios are greatest in the prestellar cores and protostars. These results are interpreted in terms of the physical and chemical properties of the sources, and the implications for molecular cloud chemistry are discussed.

A Search for Interstellar Oxiranecarbonitrile (C3H3NO)

NASA Technical Reports Server (NTRS)

Dicken, J. E.; Irvine, W. M.; Ohishi, M.; Arrhenius, G.; Bauder, A.; Mueller, F.; Eschenmoser, A.

1996-01-01

We report a search in cold, quiescent and in 'hot core' type interstellar molecular clouds for the small cyclic molecule oxiranecarbonitrile (C3H3NO), which has been suggested as a precursor of important prebiotic molecules. We have determined upper limits to the column density and fractional abundance for the observed sources and find that, typically, the fractional abundance by number relative to molecular hydrogen Of C3H3NO is less than a few times 10(exp -10). This limit is one to two orders of magnitude less than the measured abundance of such similarly complex species as CH3CH2CN and HCOOCH3 in well-studied hot cores. A number of astrochemical discoveries were made, including the first detection of the species CH3CH2CN in the massive star-forming clouds G34.3+0.2 and W51M and the first astronomical detections of some eight rotational transitions of CH3CH2CN, CH3CCH, and HCOOCH3. In addition, we found 8 emission lines in the 89 GHz region and 18 in the 102 GHz region which we were unable to assign.

Hyperfine excitation of C2H and C2D by para-H2

NASA Astrophysics Data System (ADS)

Dumouchel, Fabien; Lique, François; Spielfiedel, Annie; Feautrier, Nicole

2017-10-01

The [C2H]/[C2D] abundance ratio is a useful tool to explore the physical and chemical conditions of cold molecular clouds. Hence, an accurate determination of both the C2H and C2D abundances is of fundamental interest. Due to the low density of the interstellar medium, the population of the energy levels of the molecules is not at local thermodynamical equilibrium. Thus, the accurate modelling of the emission spectra requires the calculation of collisional rate coefficients with the most abundant interstellar species. Hence, we provide rate coefficients for the hyperfine excitation of C2H and C2D by para-H2(j=0), the most abundant collisional partner in cold molecular clouds. State-to-state rate coefficients between the lowest levels were computed for temperatures ranging from 5 to 80 K. For both isotopologues, the Δj = ΔF propensity rule is observed. The comparison between C2H and C2D rate coefficients shows that differences by up to a factor of two exist, mainly for Δj = ΔN = 1 transitions. The new rate coefficients will significantly help in the interpretation of recent observed spectra.

Micro-ion Traps for Detection of (Pre)-Biotic Organic Compounds on Comets

NASA Technical Reports Server (NTRS)

vanAmerom, Friso H. W.; Chaudhary, A.; Short, R. T.; Brinkerhoff, William; Glavin, Daniel; Mahaffy, Paul R.; Roman, Patrick A.

2013-01-01

Comets are currently believed to be a mixture of interstellar and nebular material. Many of the volatiles in comets are attributed to interstellar chemistry, because the same species of carbonaceous compounds are also observed in ices in interstellar molecular (ISM) clouds. Comets are thus likely to be a relatively pristine reservoir of primitive material and carbonaceous compounds in our solar system. They could be a major contributor to the delivery of prebiotic organic compounds, from which life emerged through impacts on early Earth. Mass spectrometers are very powerful tools to identify unknown chemicals, and much progress bas been made in miniaturizing mas spectrometers for space applications. Most miniatu rized mass spectrometers developed to date, however, are still relatively large, power hungry, complicated to assemble, and would have significant impact on space flight vehicle total payload and resource allocations.

Chemical Evolution of Interstellar Dust into Planetary Materials

NASA Technical Reports Server (NTRS)

Fomenkova, M. N.; Chang, S.; DeVincenzi, Donald L. (Technical Monitor)

1995-01-01

Comets are believed to retain some interstellar materials, stored in fairly pristine conditions since-their formation. The composition and properties of cometary dust grains should reflect those of grains in the outer part of the protosolar nebula which, at least in part, were inherited from the presolar molecular cloud. However, infrared emission features in comets differ from their interstellar counterparts. These differences imply processing of interstellar material on its way to incorporation in comets, but C and N appear to be retained. Overall dust evolution from the interstellar medium (ISM) to planetary materials is accompanied by an increase in proportion of complex organics and a decrease in pure carbon phases. The composition of cometary dust grains was measured in situ during fly-by missions to comet Halley in 1986. The mass spectra of about 5000 cometary dust grains with masses of 5 x 10(exp -17) - 5 x 10(exp -12) g provide data about the presence and relative abundances of the major elements H, C, N, O,Na, Mg, Al, Si, S, Cl, K, Ca, Ti, Cr, Fe, Ni. The bulk abundances of major rock-forming elements integrated over all spectra were found to be solar within a factor of 2, while the volatile elements H, C, N, O in dust are depleted in respect to their total cosmic abundances. The abundances of C and N in comet dust are much closer to interstellar than to meteoritic and are higher than those of dust in the diffuse ISM. In dense molecular clouds dust grains are covered by icy mantles, the average composition of which is estimated to be H:C:N:O = 96:14:1:34. Up to 40% of elemental C and O may be sequestered in mantles. If we use this upper limit to add H, C, N and O as icy mantle material to the abundances residing in dust in the diffuse ISM, then the resulting values for H. C, and N match cometary abundances. Thus, ice mantles undergoing chemical evolution on grains in the dense ISM appear to have been transformed into less volatile and more complex organic residues wherein the H, C and N are largely retained and ultimately accreted in cometary dust. The abundance of O is about the same for cometary dust, meteorites and interstellar dust. In all these samples, most of O in a solid phase is bonded to silicates. In dense molecular clouds, the abundance of O in dust+mantles is significantly higher then in cometary dust. This difference may reflect the greater lability of oxygenated species toward astrophysical processing. Laboratory studies show that O-bearing functional groups in organic compounds tend to be relatively easily removed by heating and/or UV and particle irradiation . In Halley's coma, O-containing organic grains, being unstable, were located closest to the nucleus. The decomposition of the organic grain component in the coma provided a significant extended source contribution to O-containing gaseous species such as CO and H2CO.

Million-degree plasma pervading the extended Orion Nebula.

PubMed

Güdel, Manuel; Briggs, Kevin R; Montmerle, Thierry; Audard, Marc; Rebull, Luisa; Skinner, Stephen L

2008-01-18

Most stars form as members of large associations within dense, very cold (10 to 100 kelvin) molecular clouds. The nearby giant molecular cloud in Orion hosts several thousand stars of ages less than a few million years, many of which are located in or around the famous Orion Nebula, a prominent gas structure illuminated and ionized by a small group of massive stars (the Trapezium). We present x-ray observations obtained with the X-ray Multi-Mirror satellite XMM-Newton, revealing that a hot plasma with a temperature of 1.7 to 2.1 million kelvin pervades the southwest extension of the nebula. The plasma flows into the adjacent interstellar medium. This x-ray outflow phenomenon must be widespread throughout our Galaxy.

Self-Assembling Amphiphilic Molecules: A Possible Relationship Between Interstellar Chemistry and Meteoritic Organics

NASA Technical Reports Server (NTRS)

Sandford, Scott A.; Dworkin, Jason P.; Deamer, David W.; Allamandola, Louis J.; DeVincenzi, Donald (Technical Monitor)

2001-01-01

Interstellar gas and dust comprise the primary material from which the solar system formed. Evidence that some of this material was organic in nature and survived incorporation into the protosolar nebula is provided by the presence of deuterium-enriched organics in meteorites and interplanetary dust particles. Once the inner planets had sufficiently cooled, late accretionary infall of meteoroids and cosmic dust must have seeded them with some of these complex organic compounds. Delivery of such extraterrestrial compounds may have contributed to the organic inventory necessary for the origin of life. Interstellar ices, the building blocks of comets, tie up a large fraction of the biogenic elements available in molecular clouds. In our efforts to understand their synthesis, chemical composition, and physical properties, we report here that a complex mixture of molecules is produced by ultraviolet (UV) photolysis of realistic, interstellar ice analogs, and that some of the components have properties relevant to the origin of life, including the ability to self-assemble into vesicular structures.

Cosmic rays, gas and dust in nearby anticentre clouds. I. CO-to-H2 conversion factors and dust opacities

NASA Astrophysics Data System (ADS)

Remy, Q.; Grenier, I. A.; Marshall, D. J.; Casandjian, J. M.

2017-05-01

Aims: We aim to explore the capabilities of dust emission and γ rays for probing the properties of the interstellar medium in the nearby anti-centre region, using γ-ray observations with the Fermi Large Area Telescope (LAT), and the thermal dust optical depth inferred from Planck and IRAS observations. We also aim to study massive star-forming clouds including the well known Taurus, Auriga, Perseus, and California molecular clouds, as well as a more diffuse structure which we refer to as Cetus. In particular, we aim at quantifying potential variations in cosmic-ray density and dust properties per gas nucleon across the different gas phases and different clouds, and at measuring the CO-to-H2 conversion factor, XCO, in different environments. Methods: We have separated six nearby anti-centre clouds that are coherent in velocities and distances, from the Galactic-disc background in H I 21-cm and 12CO 2.6-mm line emission. We have jointly modelled the γ-ray intensity recorded between 0.4 and 100 GeV, and the dust optical depth τ353 at 353 GHz as a combination of H I-bright, CO-bright, and ionised gas components. The complementary information from dust emission and γ rays was used to reveal the gas not seen, or poorly traced, by H I, free-free, and 12CO emissions, namely (I) the opaque H iand diffuse H2 present in the Dark Neutral Medium at the atomic-molecular transition, and (II) the dense H2 to be added where 12CO lines saturate. Results: The measured interstellar γ-ray spectra support a uniform penetration of the cosmic rays with energies above a few GeV through the clouds, from the atomic envelopes to the 12CO-bright cores, and with a small ± 9% cloud-to-cloud dispersion in particle flux. We detect the ionised gas from the H iiregion NGC 1499 in the dust and γ-ray emissions and measure its mean electron density and temperature. We find a gradual increase in grain opacity as the gas (atomic or molecular) becomes more dense. The increase reaches a factor of four to six in the cold molecular regions that are well shielded from stellar radiation. Consequently, the XCO factor derived from dust is systematically larger by 30% to 130% than the γ-ray estimate. We also evaluate the average γ-ray XCO factor for each cloud, and find that XCO tends to decrease from diffuse to more compact molecular clouds, as expected from theory. We find XCO factors in the anti-centre clouds close to or below 1020 cm-2 K-1 km-1 s, in agreement with other estimates in the solar neighbourhood. Together, they confirm the long-standing unexplained discrepancy, by a factor of two, between the mean XCO values measured at parsec scales in nearby clouds and those obtained at kiloparsec scale in the Galaxy. Our results also highlight large quantitative discrepancies in 12CO intensities between simulations and observations at low molecular gas densities.

Interstellar gas in the Gum Nebula

NASA Technical Reports Server (NTRS)

Wallerstein, G.; Jenkins, E. B.; Silk, J.

1980-01-01

A survey of the interstellar gas near the Gum Nebula by optical observation of 67 stars at Ca II, 42 stars at Na I, and 14 stars in the UV with the Copernicus satellite provided radial velocities and column densities for all resolved absorption components. Velocity dispersions for gas in the Gum Nebula are not significantly larger than in the general interstellar medium; the ionization structure is predominantly that of an H II region with moderately high ionization. Denser, more highly ionized clouds are concentrated toward the Gum Nebula; these clouds do not show the anomalously high ionization observed in the Vela remnant clouds.

GOT C+: Galactic Plane Survey of the 1.9 THz [CII] Line

NASA Astrophysics Data System (ADS)

Langer, William

2012-01-01

The ionized carbon [CII] 1.9 THz fine structure line is a major gas coolant in the interstellar medium (ISM) and controls the thermal conditions in diffuse gas clouds and Photodissociation Regions (PDRs). The [CII] line is also an important tracer of the atomic gas and atomic to molecular transition in diffuse clouds throughout the Galaxy. I will review some of the results from the recently completed Galactic Observations of Terahertz C+ (GOT C+) survey. This Herschel Open Time Key Project is a sparse, but uniform volume sample survey of [CII] line emission throughout the Galactic disk using the HIFI heterodyne receiver. HIFI observations, with their high spectral resolution, isolate and locate individual clouds in the Galaxy and provide excitation information on the gas. I will present [CII] position-velocity maps that reveal the distribution and motion of the clouds in the inner Galaxy and discuss results on the physical properties of the gas using spectral observations of [CII] and ancillary HI and 12CO, 13CO, and C18O J=1-0 data. The [CII] emission is also a useful tracer of the "Dark H2 Gas", and I will discuss its distribution in a sample of interstellar clouds. This research was conducted at the Jet Propulsion Laboratory, California Institute of Technology under contract with the National Aeronautics and Space Administration.

Detection of nitric oxide in the dark cloud L134N

NASA Technical Reports Server (NTRS)

Mcgonagle, D.; Irvine, W. M.; Minh, Y. C.; Ziurys, L. M.

1990-01-01

The first detection of interstellar nitric oxide (NO) in a cold dark cloud, L134N is reported. Nitric oxide was observed by means of its two 2 Pi 1/2, J = 3/2 - 1/2, rotational transitions at 150.2 and 150.5 GHz, which occur because of Lambda-doubling. The inferred column density for L134N is about 5 x 10 to the 14th/sq cm toward the SO peak in that cloud. This value corresponds to a fractional abundance relative to molecular hydrogen of about 6 x 10 to the -8th and is in good agreement with predictions of quiescent cloud ion-molecule chemistry. NO was not detected toward the dark cloud TMC-1 at an upper limit of 3 x 10 to the -8th or less.

GOT C+ Survey of [CII] 158 Micrometer Emission: Atomic to Molecular Cloud Transitions in the Inner Galaxy

NASA Technical Reports Server (NTRS)

Velusamy, T.; Langer, W. D.; Willacy, K.; Pineda, J. L.; Goldsmith, P. F.

2012-01-01

We present the results of the distribution of CO-dark H2 gas in a sample of 2200 interstellar clouds in the inner Galaxy (l = 90 deg to +57 deg) detected in the velocity resolved [CII] spectra observed in the GOT C+ survey using the Herschel HIFI. We analyze the [CII] intensities along with the ancillary HI, (12)CO and (13)CO data for each cloud to determine their evolutionary state and to derive the H2 column densities in the C(+) and C(+)/CO transition layers in the cloud. We discuss the overall Galactic distribution of the [CII] clouds and their properties as a function Galactic radius. GOT C+ results on the global distribution of [CII] clouds and CO-dark H2 gas traces the FUV and star formation rates in the Galactic disk.

GOT C+ Survey of [CII] 158 μm Emission: Atomic to Molecular Cloud Transitions in the Inner Galaxy

NASA Astrophysics Data System (ADS)

Velusamy, T.; Langer, W. D.; Willacy, K.; Pineda, J. L.; Goldsmith, P. F.

2013-03-01

We present the results of the distribution of CO-dark H2 gas in a sample of 2223 interstellar clouds in the inner Galaxy (l=-90° to +57°) detected in the velocity resolved [CII] spectra observed in the GOT C+ survey using the Herschel HIFI. We analyze the [CII] intensities along with the ancillary HI, 12CO and 13CO data for each cloud to determine their evolutionary state and to derive the H2 column densities in the C+ and C+/CO transition layers in the cloud. We discuss the overall Galactic distribution of the [CII] clouds and their properties as a function Galactic radius. GOT C+ results on the global distribution of [CII] clouds and CO-dark H2 gas traces the FUV intensity and star formation rate in the Galactic disk.

ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES) - Merging Observations and Laboratory Data

NASA Technical Reports Server (NTRS)

Salama, Farid

2016-01-01

The Diffuse Interstellar Bands (DIBs) are a set of 500 absorption bands that are detected in the spectra of stars with interstellar clouds in the line of sight. DIBs are found from the NUV to the NIR in the spectra of reddened stars spanning different interstellar environments in our local, and in other galaxies. DIB carriers are a significant part of the interstellar chemical inventory. They are stable and ubiquitous in a broad variety of environments and play a unique role in interstellar physics/chemistry. It has long been realized that the solving of the DIB problem requires a strong synergy between astronomical observations, laboratory astrophysics, and astrophysical modeling of line-of-sights. PAHs are among the molecular species that have been proposed as DIB carriers. We will present an assessment of the PAH-DIB model in view of the progress and the advances that have been achieved over the past years through a series of studies involving astronomical observations of DIBs, laboratory simulation of interstellar analogs for neutrals and ionized PAHs, theoretical calculations of PAH spectra and the modelization of diffuse and translucent interstellar clouds. We will present a summary of what has been learned from these complementary studies, the constraints that can now be derived for the PAHs as DIB carriers in the context of the PAH-DIB model and how these constraints can be applied to the EDIBLES project. The spectra of several neutral and ionized PAHs isolated in the gas phase at low temperature have been measured in the laboratory under experimental conditions that mimic interstellar conditions and are compared with an extensive set of astronomical spectra of reddened, early type stars. The comparisons of astronomical and laboratory data provide upper limits for the abundances of specific neutral PAH molecules and ions along specific lines-of-sight. Something that is not attainable from infrared observations alone. We present the characteristics of the laboratory facilities, MIS and COSmIC, that have been developed for this study and discuss the findings resulting from the comparison of the laboratory data with high resolution, high S/N ratio astronomical observations. MIS stands for Matrix Isolation Spectroscopy, a well-proven technique for isolating cold molecular species in inert solid environments. COSmIC stands for Cosmic Simulation Chamber. It combines a supersonic free jet expansion with discharge plasma and high-sensitivity cavity ringdown spectroscopy and time-of-flight mass spectrometry detection tools for the generation and the detection of cold, isolated gas-phase molecules and ions under experimental conditions that closely mimic interstellar conditions. The column densities of the individual neutral PAH molecules and ions probed in these surveys are derived from the comparison of these unique laboratory data with high resolution, high S/N ratio astronomical observations. The comparisons of astronomical and laboratory data lead to clear and unambiguous conclusions regarding the expected abundances for PAHs of various sizes and charge states in the interstellar environments probed in the surveys. Band profile comparisons between laboratory and astronomical spectra lead to information regarding the molecular structures and characteristics associated with the DIB carriers in the corresponding lines-of-sight. These quantitative surveys of neutral and ionized PAHs in the optical range open the way for unambiguous quantitative searches of PAHs and complex organics in a variety of interstellar and circumstellar environments.

DESPOTIC - a new software library to Derive the Energetics and SPectra of Optically Thick Interstellar Clouds

NASA Astrophysics Data System (ADS)

Krumholz, Mark R.

2014-01-01

I describe DESPOTIC, a code to Derive the Energetics and SPectra of Optically Thick Interstellar Clouds. DESPOTIC represents such clouds using a one-zone model, and can calculate line luminosities, line cooling rates, and in restricted cases line profiles using an escape probability formalism. It also includes approximate treatments of the dominant heating, cooling and chemical processes for the cold interstellar medium, including cosmic ray and X-ray heating, grain photoelectric heating, heating of the dust by infrared and ultraviolet radiation, thermal cooling of the dust, collisional energy exchange between dust and gas, and a simple network for carbon chemistry. Based on these heating, cooling and chemical rates, DESPOTIC can calculate clouds' equilibrium gas and dust temperatures, equilibrium carbon chemical state and time-dependent thermal and chemical evolution. The software is intended to allow rapid and interactive calculation of clouds' characteristic temperatures, identification of their dominant heating and cooling mechanisms and prediction of their observable spectra across a wide range of interstellar environments. DESPOTIC is implemented as a PYTHON package, and is released under the GNU General Public License.

H{sub 2} MOLECULAR CLUSTERS WITH EMBEDDED MOLECULES AND ATOMS AS THE SOURCE OF THE DIFFUSE INTERSTELLAR BANDS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bernstein, L. S.; Clark, F. O.; Lynch, D. K., E-mail: larry@spectral.com, E-mail: dave@thulescientific.com

2013-05-01

We suggest that the diffuse interstellar bands (DIBs) arise from absorption lines of electronic transitions in molecular clusters primarily composed of a single molecule, atom, or ion ({sup s}eed{sup )}, embedded in a single-layer shell of H{sub 2} molecules. Less abundant variants of the cluster, including two seed molecules and/or a two-layer shell of H{sub 2} molecules, may also occur. The lines are broadened, blended, and wavelength-shifted by interactions between the seed and surrounding H{sub 2} shell. We refer to these clusters as contaminated H{sub 2} clusters (CHCs). We show that CHC spectroscopy matches the diversity of observed DIB spectralmore » profiles and provides good fits to several DIB profiles based on a rotational temperature of 10 K. CHCs arise from {approx}centimeter-sized, dirty H{sub 2} ice balls, called contaminated H{sub 2} ice macro-particles (CHIMPs), formed in cold, dense, giant molecular clouds (GMCs), and later released into the interstellar medium (ISM) upon GMC disruption. Attractive interactions, arising from Van der Waals and ion-induced dipole potentials, between the seeds and H{sub 2} molecules enable CHIMPs to attain centimeter-sized dimensions. When an ultraviolet (UV) photon is absorbed in the outer layer of a CHIMP, it heats the icy matrix and expels CHCs into the ISM. While CHCs are quickly destroyed by absorbing UV photons, they are replenished by the slowly eroding CHIMPs. Since CHCs require UV photons for their release, they are most abundant at, but not limited to, the edges of UV-opaque molecular clouds, consistent with the observed, preferred location of DIBs. An inherent property of CHCs, which can be characterized as nanometer size, spinning, dipolar dust grains, is that they emit in the radio-frequency region. We also show that the CHCs offer a natural explanation for the anomalous microwave emission feature in the {approx}10-100 GHz spectral region.« less

Substantial reservoirs of molecular hydrogen in the debris disks around young stars.

PubMed

Thi, W F; Blake, G A; van Dishoeck, E F; van Zadelhoff, G J; Horn, J M; Becklin, E E; Mannings, V; Sargent, A I; van Den Ancker, M E; Natta, A

2001-01-04

Circumstellar accretion disks transfer matter from molecular clouds to young stars and to the sites of planet formation. The disks observed around pre-main-sequence stars have properties consistent with those expected for the pre-solar nebula from which our own Solar System formed 4.5 Gyr ago. But the 'debris' disks that encircle more than 15% of nearby main-sequence stars appear to have very small amounts of gas, based on observations of the tracer molecule carbon monoxide: these observations have yielded gas/dust ratios much less than 0.1, whereas the interstellar value is about 100 (ref. 9). Here we report observations of the lowest rotational transitions of molecular hydrogen (H2) that reveal large quantities of gas in the debris disks around the stars beta Pictoris, 49 Ceti and HD135344. The gas masses calculated from the data are several hundreds to a thousand times greater than those estimated from the CO observations, and yield gas/dust ratios of the same order as the interstellar value.

New Insights Concerning the Local Interstellar medium

NASA Astrophysics Data System (ADS)

Linsky, Jeffrey L.; Redfield, Seth

2015-08-01

We have been analyzing HST high-resolution ultraviolet spectra of nearby stars to measure the radial velocities, turbulence, temperature, and depletions on warm diffuse interstellar gas within a few parsecs of the Sun. These data reveal a picture of many partially-ionized warm gas clouds, each with their own vector velocity and physical characteristics. This picture has been recently challenged by Gry and Jenkins (2014), who argue for a single nonrigid cloud surrounding the Sun. We present a test of these two very different morphological structure by checking how well each predicts the radial velocities in a new data set (Malamut et al. 2014) that was not available when both models were constructed. We find that the multicloud model (Redfield & Linsky 2008) provides a much better fit to the new data. We compare the new IBEX results for the temperature and velocity of inflowing He gas (McComas et al. 2015) with the properties of the Local Interstellar Cloud and the G cloud. We also show a preliminary three-dimensional model for the local interstellar medium.

Ultraviolet Studies of Interstellar Molecular Hydrogen

NASA Astrophysics Data System (ADS)

Sarlin, Scott Peter

1998-12-01

This work covers the design and conduct of two experiments designed to observe molecular hydrogen in the interstellar medium. The first experiment was intended to directly observe the ratio between H2 and CO column densities in translucent molecular clouds in order to calibrate CO radio maps and observations of this galaxy and others. H2 cannot be directly observed from the ground under ordinary circumstances, so a novel high resolution (30,000 λΔλ) ultraviolet (UV) spectrograph was designed and built to observe it in absorption in the spectra of a distant star (HD 206267). The instrument operated properly, but the target was not acquired and the sounding rocket's parachute did not deploy, destroying the instrument. The second experiment was to observe H2 absorption towards γ Cassiopeia at very high spectral resolution (-240,000 λΔλ) with a space shuttle experiment called IMAPS. Despite several problems, including a dramatic loss in sensitivity, H2 absorption lines from J=0, 1, 2, and 3 were detected and measured. In conjunction with published atomic line observations, this gas was determined to be from a very small, thermally dominated cloud embedded in a larger H I region. The lack of higher J-state detections preclude a definitive statement concerning the radiation field, although the data point towards limited UV excitation. Future directions for instrument development are then briefly discussed.

High-latitude dust clouds LDN 183 and LDN 169: distances and extinctions

NASA Astrophysics Data System (ADS)

Straižys, V.; Boyle, R. P.; Zdanavičius, J.; Janusz, R.; Corbally, C. J.; Munari, U.; Andersson, B.-G.; Zdanavičius, K.; Kazlauskas, A.; Maskoliūnas, M.; Černis, K.; Macijauskas, M.

2018-03-01

Interstellar extinction is investigated in a 2°× 2° area containing the dust and molecular clouds LDN 183 (MBM 37) and LDN 169, which are located at RA = 15h 54m, Dec = - 3°. The study is based on a photometric classification in spectral and luminosity classes of 782 stars selected from the catalogs of 1299 stars down to V = 20 mag observed in the Vilnius seven-color system. For control, the MK types for the 18 brightest stars with V between 8.5 and 12.8 mag were determined spectroscopically. For 14 stars, located closer than 200 pc, distances were calculated from trigonometric parallaxes taken from the Gaia Data Release 1. For about 70% of the observed stars, two-dimensional spectral types, interstellar extinctions AV, and distances were determined. Using 57 stars closer than 200 pc, we estimate that the front edge of the clouds begins at 105 ± 8 pc. The extinction layer in the vicinities of the clouds can be about 20 pc thick. In the outer parts of the clouds and between the clouds, the extinction is 0.5-2.0 mag. Behind the Serpens/Libra clouds, the extinction range does not increase; this means that the dust layer at 105 pc is a single extinction source. Full Tables 1 and 2 are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/611/A9

Herschel HIFI GOT C+ Survey: CII, HI, and CO Emissions in a Sample of Transition Clouds and Star-Forming regions in the Inner Galaxy

NASA Astrophysics Data System (ADS)

Pineda, Jorge; Velusamy, Thangasamy; Langer, William D.; Goldsmith, Paul; Li, Di; Yorke, Harold

The GOT C+ a HIFI Herschel Key Project, studies the diffuse ISM throughout the Galactic Plane, using C+ as cloud tracer. The C+ line at 1.9 THz traces a so-far poorly studied stage in ISM cloud evolution -the transitional clouds going from atomic HI to molecular H2. This transition cloud phase, which is difficult to observe in HI and CO alone, may be best characterized via CII emission or absorption. The C+ line is also an excellent tracer of the warm diffuse gas and the warm, dense gas in the Photon Dominated Regions (PDRs). We can, therefore, use the CII emission as a probe to understand the effects of star formation on their interstellar environment. We present our first results on the transition between dense and hot gas (traced by CII) and dense and cold gas (traced by 12CO and 13CO) along a few representative lines of sight in the inner Galaxy from longitude 325 degrees to 25 degrees, taken during the HIFI Priority Science Phase. Comparisons of the high spectral resolution ( 1 km/s) HIFI data on C+ with HI, 12CO, and 13CO spectra allow us to separate out the different ISM components along each line of sight. Our results provide detailed information about the transition of diffuse atomic to molecular gas clouds needed to understand star formation and the lifecycle of the interstellar gas. These observations are being carried out with the Herschel Space Observatory, which is an ESA cornerstone mission, with contributions from NASA. This research was conducted at the Jet Propulsion Laboratory, California Institute of Technology under contract with the National Aeronautics and Space Administration. JLP was supported under the NASA Postdoctoral Program at JPL, Caltech, administered by Oak Ridge Associated Universities through a contract with NASA, and is currently supported as a Caltech-JPL Postdoctoral associate.

Discussion session on star formation, molecular clouds and the interstellar medium

NASA Technical Reports Server (NTRS)

Strom, Karen M.; Nordh, Lennart; Dwek, Eli

1994-01-01

In this panel discussion contributions were made by K. Strom, L. Nordh and H. Zinnecker on the contributions of surveys to the study of star formation regions, by B. Burton on a survey of galactic H I and by E. Dwek on the detection of galactic supernovae by infrared surveys. The contributions of K. Strom, L. Nordh and E. Dwek are summarized here.

I(CO)/N(H2) conversions and molecular gas abundances in spiral and irregular galaxies

NASA Technical Reports Server (NTRS)

Maloney, Philip; Black, John H.

1988-01-01

Observations of emission in the J = 1-0 rotational transition of interstellar CO are used to obtain column densities and masses of hydrogen. By taking into account the effects of variations in molecular cloud parameters on conversion factors between integrated CO intensity and molecular hydrogen column density, it is shown that conversion factors are very sensitive to the kinetic temperature of the emitting gas. Results indicate that the gas temperatures in systems with high star formation rates can be quite high, and it is suggested that use of a standard conversion factor will lead to systematic overestimation of the amount of molecular gas.

Processing Mechanisms for Interstellar Ices: Connections to the Solar System

NASA Technical Reports Server (NTRS)

Pendleton, Y. J.; Cuzzi, Jeffrey N. (Technical Monitor)

1995-01-01

The organic component of the interstellar medium, which has revealed itself through the ubiquitous 3.4 micrometers hydrocarbon absorption feature, is widespread throughout the disk of our galaxy and has been attributed to dust grains residing in the diffuse interstellar medium. The absorption band positions near 3.4 micrometers are characteristic of C-H stretching vibrations in the -CH3 and -CH2- groups of saturated aliphatic hydrocarbons associated with perturbing chemical groups. The production of complex molecules is thought to occur within dense molecular clouds when ice-mantled grains are processed by various energetic mechanisms. Studies of the processing of interstellar ices and the subsequent production of organic residues have relevance to studies of ices in the solar system, because primitive, icy solar system bodies such as those in the Kuiper belt are likely reservoirs of organic material, either preserved from the interstellar medium or produced in situ. Connections between the interstellar medium and the early solar nebula have long been a source of interest. A comparison of the interstellar organics and the Murchison meteorite illustrates the importance of probing the interstellar connection to the solar system, because although the carbonaceous meteorites are undoubtedly highly processed, they do retain specific interstellar signatures (such as diamonds, SiC grains, graphite and enriched D/H). The organic component, while not proven interstellar, has a remarkable similarity to the interstellar organics observed in over a dozen sightlines through our galaxy. This paper compares spectra from laboratory organics produced through the processing of interstellar ice analog materials with the high resolution infrared observations of the interstellar medium in order to investigate the mechanisms (such as ion bombardment, plasma processing, and UV photolysis) that may be producing the organics in the ISM.

Penetration of Cosmic Rays into Dense Molecular Clouds: Role of Diffuse Envelopes

NASA Astrophysics Data System (ADS)

Ivlev, A. V.; Dogiel, V. A.; Chernyshov, D. O.; Caselli, P.; Ko, C.-M.; Cheng, K. S.

2018-03-01

A flux of cosmic rays (CRs) propagating through a diffuse ionized gas can excite MHD waves, thus generating magnetic disturbances. We propose a generic model of CR penetration into molecular clouds through their diffuse envelopes, and identify the leading physical processes controlling their transport on the way from a highly ionized interstellar medium to the dense interior of the cloud. The model allows us to describe a transition between a free streaming of CRs and their diffusive propagation, determined by the scattering on the self-generated disturbances. A self-consistent set of equations, governing the diffusive transport regime in an envelope and the MHD turbulence generated by the modulated CR flux, is characterized by two dimensionless numbers. We demonstrate a remarkable mutual complementarity of different mechanisms leading to the onset of the diffusive regime, which results in a universal energy spectrum of the modulated CRs. In conclusion, we briefly discuss implications of our results for several fundamental astrophysical problems, such as the spatial distribution of CRs in the Galaxy as well as the ionization, heating, and chemistry in dense molecular clouds. This paper is dedicated to the memory of Prof. Vadim Tsytovich.

Organic chemical evolution

NASA Technical Reports Server (NTRS)

Chang, S.

1981-01-01

The course of organic chemical evolution preceding the emergence of life on earth is discussed based on evidence of processes occurring in interstellar space, the solar system and the primitive earth. Following a brief review of the equilibrium condensation model for the origin and evolution of the solar system, consideration is given to the nature and organic chemistry of interstellar clouds, comets, Jupiter, meteorites, Venus and Mars, and the prebiotic earth. Major issues to be resolved in the study of organic chemical evolution on earth are identified regarding condensation and accretion in the solar nebula, early geological evolution, the origin and evolution of the atmosphere, organic production rates, organic-inorganic interactions, environmental fluctuations, phase separation and molecular selectivity.

Is interstellar detection of higher members of the linear radicals CnCH and CnN feasible?

NASA Technical Reports Server (NTRS)

Pauzat, F.; Ellinger, Y.; Mclean, A. D.

1991-01-01

Rotational constants and dipole moments for linear-chain radicals CnCH and CnN are estimated using a combinatiaon of ab initio molecular orbital calculations and observed data on the starting members of the series. CnCH with n = 0-5 have been observed by radioastronomy in carbon-rich interstellar clouds; higher members of the series have 2Pi ground states with large dipole moments and are strong candidates for observation. CN and C3N have also been observed by radioastronomy; higher members of the series, with the possible exception of C5N, have 2Pi ground states with near-zero dipole moments making their interstellar detection hopeless under present observational conditions. C5N can be a strong candidate only if it has a 2Sigma ground state, and best computations so far indicate that this is not the case.

Is interstellar detection of higher members of the linear radicals CnCH and CnN feasible?

PubMed

Pauzat, F; Ellinger, Y; McLean, A D

1991-03-01

Rotational constants and dipole moments for linear-chain radicals CnCH and CnN are estimated using a combination of ab initio molecular orbital calculations and observed data on the starting members of the series. CnCH with n = 0-5 have been observed by radioastronomy in carbon-rich interstellar clouds; higher members of the series have 2 pi ground states with large dipole moments and are strong candidates for observation. CN and C3N have also been observed by radioastronomy; higher members of the series, with the possible exception of C5N, have 2 pi ground states with near-zero dipole moments making their interstellar detection hopeless under present observational conditions. C5N can be a strong candidate only if it has a 2 sigma ground state, and our best computations so far indicate that this is not the case.

Is interstellar detection of higher members of the linear radicals CnCH and CnN feasible

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pauzat, F.; Ellinger, Y.; Mclean, A.D.

1991-03-01

Rotational constants and dipole moments for linear-chain radicals CnCH and CnN are estimated using a combinatiaon of ab initio molecular orbital calculations and observed data on the starting members of the series. CnCH with n = 0-5 have been observed by radioastronomy in carbon-rich interstellar clouds; higher members of the series have 2Pi ground states with large dipole moments and are strong candidates for observation. CN and C3N have also been observed by radioastronomy; higher members of the series, with the possible exception of C5N, have 2Pi ground states with near-zero dipole moments making their interstellar detection hopeless under presentmore » observational conditions. C5N can be a strong candidate only if it has a 2Sigma ground state, and best computations so far indicate that this is not the case. 20 refs.« less

GAS PHASE SYNTHESIS OF (ISO)QUINOLINE AND ITS ROLE IN THE FORMATION OF NUCLEOBASES IN THE INTERSTELLAR MEDIUM

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parker, Dorian S. N.; Kaiser, Ralf I.; Kostko, Oleg

Nitrogen-substituted polycyclic aromatic hydrocarbons (NPAHs) have been proposed to play a key role in the astrochemical evolution of the interstellar medium, yet the formation mechanisms of even their simplest prototypes—quinoline and isoquinoline—remain elusive. Here, we reveal a novel concept that under high temperature conditions representing circumstellar envelopes of carbon stars, (iso)quinoline can be synthesized via the reaction of pyridyl radicals with two acetylene molecules. The facile gas phase formation of (iso)quinoline in circumstellar envelopes defines a hitherto elusive reaction class synthesizing aromatic structures with embedded nitrogen atoms that are essential building blocks in contemporary biological-structural motifs. Once ejected from circumstellarmore » shells and incorporated into icy interstellar grains in cold molecular clouds, these NPAHs can be functionalized by photo processing forming nucleobase-type structures as sampled in the Murchison meteorite.« less

Chemistry of nitrile anions in the interstellar medium

NASA Astrophysics Data System (ADS)

Carles, S.; Le Garrec, J.-L.; Guillemin, J.-C.; Biennier, L.

2015-12-01

Despite the extreme conditions of temperature (down to 10K) and density (down to 100 molecules/cm3), the giant molecular clouds and the circumstellar envelopes present a rich and complex chemistry. To date, more than 180 molecules have been detected in the InterStellar Medium (ISM) with a large abundance of nitriles (RC≡N). In addition, several anions have been recently observed in this medium: C4H¯, C6H¯, C8H¯, CN¯, C3N¯ and C5N¯. These last species should play a key role in the molecular growth towards complexity. To explore this hypothesis, their reactivity must be studied in the laboratory. The FALP-MS and the CRESU experimental apparatuses of the Rennes University are able to measure absolute rate coefficient of various chemical reactions, including the ion - molecule reactions, in gas phase at low temperature (from 300K for the FALP-MS down to 15K for the CRESU). Therefore, these experimental tools are particularly adapted to the kinetic studies of reactions potentially involved in the Interstellar Medium. One of the difficulties encountered in experiments with anions is their generation. We describe here the formation of the CN¯ and C3N¯ anions by dissociative electron attachment on the molecular precursors BrCN and BrC3N.

A comparison of UV surface brightness and HI surface densities for spiral galaxies

NASA Technical Reports Server (NTRS)

Federman, S. R.; Strom, C.

1990-01-01

Shaya and Federman (1987) suggested that the ambient ultraviolet flux at 1000 A permeating a spiral galaxy controls the neutral hydrogen (HI) surface density in the galaxy. They found that the atomic envelopes surrounding small molecular clouds, because of their great number, provide the major contribution to the HI surface density over the stellar disk. The increase in HI surface density with later Hubble types was ascribed to the stronger UV fields from more high-mass stars in later Hubble types. These hypotheses are based on the observations of nearby diffuse interstellar clouds, which show a sharp atomic-to-molecular transition (Savage et al. 1977), and on the theoretical framework introduced by Federman, Glassgold, and Kwan (1979). Atomic envelopes around interstellar clouds in the solar neighborhood arise when a steady state is reached between photodissociation of H2 and the formation of H2 on grains. The photodissociation process involves photons with wavelengths between 912 A and 1108 A. Shaya and Federman used H-alpha flux as an approximate measure for the far UV flux and made their comparisons based on averages over Hubble type. Here, researchers compare, on an individual basis, UV data obtained with space-borne and balloon-borne instruments for galaxies with measurements of HI surface density (Warmels 1988a, b). The comparisons substantiate the conclusion of Shaya and Federman that the far UV field controls the HI content of spiral galaxies.

Silicon chemistry in interstellar clouds

NASA Technical Reports Server (NTRS)

Langer, William D.; Glassgold, A. E.

1990-01-01

A new model of interstellar silicon chemistry is presented that explains the lack of SiO detections in cold clouds and contains an exponential temperature dependence for the SiO abundance. A key aspect of the model is the sensitivity of SiO production by neutral silicon reactions to density and temperature, which arises from the dependence of the rate coefficients on the population of the excited fine-structure levels of the silicon atom. As part of the explanation of the lack of SiO detections at low temperatures and densities, the model also emphasizes the small efficiencies of the production routes and the correspondingly long times needed to reach equilibrium. Measurements of the abundance of SiO, in conjunction with theory, can provide information on the physical properties of interstellar clouds such as the abundance of oxygen bearing molecules and the depletion of interstellar silicon.

Probing the Origin and Evolution of Interstellar and Protoplanetary Biogenic Ices with SPHEREx

NASA Astrophysics Data System (ADS)

Melnick, Gary; SPHEREx Science Team

2018-01-01

Many of the most important building blocks of life are locked in interstellar and protoplanetary ices. Examples include H2O, CO, CO2, and CH3OH, among others. There is growing evidence that within the cores of dense molecular clouds and the mid-plane of protoplanetary disks the abundance of these species in ices far exceeds that in the gas phase. As a result, collisions between ice-bearing bodies and newly forming planets are thought to be a major means of delivering these key species to young planets. There currently exist fewer than 250 ice absorption spectra toward Galactic molecular clouds, which is insufficient to reliably trace the ice content of clouds through the various evolutionary stages of collapse to form stars and planets. Likewise, the current number of spectra is inadequate to assess the effects of environment, such as cloud density and temperature, presence or absence of embedded sources, external FUV and X-ray radiation, gas-phase composition, or cosmic-ray ionization rate, on the ice composition of clouds at similar stages of evolution. Ultimately, our goal is to understand how these findings connect to our own Solar System.SPHEREx will be a game changer for the study of interstellar, circumstellar, and protoplanetary disk ices. SPHEREx will obtain spectra over the entire sky in the optical and near-IR, including the 2.5 to 5.0 micron region, which contains the above biogenic ice features. SPHEREx will detect millions of potential background continuum point sources already catalogued by NASA’s Wide-field Infrared Survey Explorer (WISE) at 3.4 and 4.6 microns for which there is evidence for intervening gas and dust based on the 2MASS+WISE colors with sufficient sensitivity to yield ice absorption spectra with SNR ≥ 100 per spectral resolution element. The resulting > 100-fold increase in the number of high-quality ice absorption spectra toward a wide variety of regions distributed throughout the Galaxy will reveal correlations between ice content and environment not possible with current spectra or the limited number that will be obtained with JWST. Finally, because SPHEREx and JWST will overlap beyond 2022, SPHEREx will provide JWST with a complete ice source catalog for follow-up.

Radiolysis of astrophysical ices by heavy ion irradiation: Destruction cross section measurement

NASA Astrophysics Data System (ADS)

de Barros, A. L. F.; Boduch, P.; Domaracka, A.; Rothard, H.; da Silveira, E. F.

2012-08-01

Many solar system objects, such as planets and their satellites, dust grains in rings, and comets, are known to either be made of ices or to have icy surfaces. These ices are exposed to ionizing radiation including keV, MeV and GeV ions from solar wind or cosmic rays. Moreover, icy dust grains are present in interstellar space and, in particular, in dense molecular clouds. Radiation effects include radiolysis (the destruction of molecules leading to formation of radicals), the formation of new molecules following radiolysis, the desorption or sputtering of atoms or molecules from the surface, compaction of porous ices, and phase changes. This review discusses the application of infrared spectroscopy FTIR to study the evolution of the chemical composition of ices containing the most abundant molecular species found in the solar system and interstellar medium, such as H2O, CO, CO2 and hydrocarbons. We focus on the evolution of chemical composition with ion fluence in order to deduce the corresponding destruction and formation cross sections. Although initial approach focused on product identification, it became increasingly necessary to work toward a comprehensive understanding of ice chemistry. The abundances of these molecules in different phases of ice mantles provide important clues to the chemical processes in dense interstellar clouds, and therefore it is of importance to accurately measure the quantities such as dissociation and formation cross sections of the infrared features of these molecules. We also are able to obtain the scaling of these cross sections with deposited energy.

The bird: A pressure-confined explosion in the interstellar medium

NASA Technical Reports Server (NTRS)

Lane, A. P.; Stark, A. A.; Helfand, D. J.

1986-01-01

The non-thermal radio continuum source G5.3-1.0, mapped at 20 cm with the Very Large Array (VLA) by Becker and Helfand, has an unusual bird-like shape. In order to determine possible interaction of this source with adjacent cold gas, we have mapped this region in the J=1-0 line of CO using the AT and T Bell Laboratories 7m antenna and the FCRAO 14m antenna. The map shown contains 1859 spectra sampled on a 1.5 arcminute grid; each spectrum has an rms noise of 0.2 K in 1 MHz channels. There are several molecular clouds at different velocities along the line of sight. The outer regions of a previously unknown Giant Molecular Cloud (GMC) at l=4.7 deg., b=-0.85 deg., v=200 km s(-1) appears to be interacting with G5.3-10: the molecular cloud has a bird-shaped hole at the position of the continuum source, except that the brightest continuum point (the bird's head) appears to be embedded in the cloud. The velocity of this GMC indicates it is within 2 kpc of the galactic center. The morphology suggests that a supernova or other explosive event occurred near the outside of the GMC, in a region where (n) is approximately 300 cm(-3), and expanded into a region of lower density and pressure. The pressures, densities, and velocity gradients of molecular clouds near the galactic center are on average higher than those of clouds near the Sun. We therefore expect that Type II supernovae near the galactic center would be distorted by their interactions with their parent molecular clouds.

Carbon monoxide in clouds at low metallicity in the dwarf irregular galaxy WLM.

PubMed

Elmegreen, Bruce G; Rubio, Monica; Hunter, Deidre A; Verdugo, Celia; Brinks, Elias; Schruba, Andreas

2013-03-28

Carbon monoxide (CO) is the primary tracer for interstellar clouds where stars form, but it has never been detected in galaxies in which the oxygen abundance relative to hydrogen is less than 20 per cent of that of the Sun, even though such 'low-metallicity' galaxies often form stars. This raises the question of whether stars can form in dense gas without molecules, cooling to the required near-zero temperatures by atomic transitions and dust radiation rather than by molecular line emission; and it highlights uncertainties about star formation in the early Universe, when the metallicity was generally low. Here we report the detection of CO in two regions of a local dwarf irregular galaxy, WLM, where the metallicity is 13 per cent of the solar value. We use new submillimetre observations and archival far-infrared observations to estimate the cloud masses, which are both slightly greater than 100,000 solar masses. The clouds have produced stars at a rate per molecule equal to 10 per cent of that in the local Orion nebula cloud. The CO fraction of the molecular gas is also low, about 3 per cent of the Milky Way value. These results suggest that in small galaxies both star-forming cores and CO molecules become increasingly rare in molecular hydrogen clouds as the metallicity decreases.

Molecule Formation at High Extinction and Low Metallicity in the Magellanic Clouds

NASA Technical Reports Server (NTRS)

Shull, J. Michael

2005-01-01

During 2005, our FUSE research group prepared two major FUSE surveys of interstellar molecular hydrogen: 1. Galactic Disk Sightlines. We measured N(H2) in rotational states J = 0 and 1 and in higher states, J = 2,3,4,5, sometimes up to J = l, for 139 sightlines to Galactic OB stars. 2. High-Latitude QSO sightlines. We surveyed 50 sightlines to high-latitude QSOs, finding H2 in most of them (44 of 50). 3 . Molecular Hydrogen in Infrared Cirrus. Related to the high-latitude H2 survey (#2), we examined the high-latitude infrared cirrus and its correlation with H2. In addition, we are accumulating H2 measurements for additional 0 stars in the Magellanic Clouds (LMC and SMC) to add to the previously published survey.

Unfolding the laws of star formation: the density distribution of molecular clouds.

PubMed

Kainulainen, Jouni; Federrath, Christoph; Henning, Thomas

2014-04-11

The formation of stars shapes the structure and evolution of entire galaxies. The rate and efficiency of this process are affected substantially by the density structure of the individual molecular clouds in which stars form. The most fundamental measure of this structure is the probability density function of volume densities (ρ-PDF), which determines the star formation rates predicted with analytical models. This function has remained unconstrained by observations. We have developed an approach to quantify ρ-PDFs and establish their relation to star formation. The ρ-PDFs instigate a density threshold of star formation and allow us to quantify the star formation efficiency above it. The ρ-PDFs provide new constraints for star formation theories and correctly predict several key properties of the star-forming interstellar medium.

Disintegration of Dust Aggregates in Interstellar Shocks and the Lifetime of Dust Grains in the ISM

NASA Technical Reports Server (NTRS)

Dominik, C.; Jones, A. P.; Tielens, A. G. G. M.; Cuzzi, Jeff (Technical Monitor)

1994-01-01

Interstellar grains are destroyed by shock waves moving through the ISM. In fact, the destruction of grains may be so effective that it is difficult to explain the observed abundance of dust in the ISM as a steady state between input of grains from stellar sources and destruction of grains in shocks. This is especially a problem for the larger grains. Therefore, the dust grains must be protected in some way. Jones et al. have already considered coatings and the increased post-shock drag effects for low density grains. In molecular clouds and dense clouds, coagulation of grains is an important process, and the largest interstellar grains may indeed be aggregates of smaller grains rather than homogeneous particles. This may provide a means to protect the larger grains, in that, in moderate velocity grain-grain collisions in a shock the aggregates may disintegrate rather than be vaporized. The released small particles are more resilient to shock destruction (except in fast shocks) and may reform larger grains later, recovering the observed size distribution. We have developed a model for the binding forces in grain aggregates and apply this model to the collisions between an aggregate and fast small grains. We discuss the results in the light of statistical collision probabilities and grain life times.

The impact of different interstellar medium structures on the dynamical evolution of supernova remnants

NASA Astrophysics Data System (ADS)

Wang, Yueyang; Bao, Biwen; Yang, Chuyuan; Zhang, Li

2018-05-01

The dynamical properties of supernova remnants (SNRs) evolving with different interstellar medium structures are investigated through performing extensive two-dimensional magnetohydrodynamic (MHD) simulations in the cylindrical symmetry. Three cases of different interstellar medium structures are considered: the uniform medium, the turbulent medium and the cloudy medium. Large-scale density and magnetic fluctuations are calculated and mapped into the computational domain before simulations. The clouds are set by random distribution in advance. The above configuration allows us to study the time-dependent dynamical properties and morphological evolution of the SNR evolving with different ambient structures, along with the development of the instabilities at the contact discontinuity. Our simulation results indicate that remnant morphology deviates from symmetry if the interstellar medium contains clouds or turbulent density fluctuations. In the cloudy medium case, interactions between the shock wave and clouds lead to clouds' fragmentation. The magnetic field can be greatly enhanced by stretching field lines with a combination of instabilities while the width of amplification region is quite different among the three cases. Moreover, both the width of amplification region and the maximum magnetic-field strength are closely related to the clouds' density.

Gas-Grain Chemical Models: Inclusion of a Grain Size Distribution and a Study Of Young Stellar Objects in the Magellanic Clouds

NASA Astrophysics Data System (ADS)

Pauly, Tyler Andrew

2017-06-01

Computational models of interstellar gas-grain chemistry have aided in our understanding of star-forming regions. Chemical kinetics models rely on a network of chemical reactions and a set of physical conditions in which atomic and molecular species are allowed to form and react. We replace the canonical single grain-size in our chemical model MAGICKAL with a grain size distribution and analyze the effects on the chemical composition of the gas and grain surface in quiescent and collapsing dark cloud models. We find that a grain size distribution coupled with a temperature distribution across grain sizes can significantly affect the bulk ice composition when dust temperatures fall near critical values related to the surface binding energies of common interstellar chemical species. We then apply the updated model to a study of ice formation in the cold envelopes surrounding massive young stellar objects in the Magellanic Clouds. The Magellanic Clouds are local satellite galaxies of the Milky Way, and they provide nearby environments to study star formation at low metallicity. We expand the model calculation of dust temperature to include a treatment for increased interstellar radiation field intensity; we vary the radiation field to model the elevated dust temperatures observed in the Magellanic Clouds. We also adjust the initial elemental abundances used in the model, guided by observations of Magellanic Cloud HII regions. We are able to reproduce the relative ice fractions observed, indicating that metal depletion and elevated grain temperature are important drivers of the envelope ice composition. The observed shortfall in CO in Small Magellanic Cloud sources can be explained by a combination of reduced carbon abundance and increased grain temperatures. The models indicate that a large variation in radiation field strength is required to match the range of observed LMC abundances. CH 3OH abundance is found to be enhanced (relative to total carbon abundance) in low-metallicity models, providing seed material for complex organic molecule formation. We conclude with a preliminary study of the recently discovered hot core in the Large Magellanic Cloud; we create a grid of models to simulate hot core formation in Magellanic Cloud environments, comparing them to models and observations of well-characterized galactic counterparts.

The Inventory of Interstellar Materials Available for the Formation of the Solar System

NASA Technical Reports Server (NTRS)

Sandford, Scott A.; Witteborn, Fred C. (Technical Monitor)

1996-01-01

Dr. Derek Sears, the editor of the journal Meteoritics and Planetary Science, has established a policy of having each issue of the journal contain an invited review of an area that he deems to be of special cur-rent importance. Typically 20 to 25 pages of the beginning of the journal are devoted to each review. He has asked me to prepare such a review summarizing what we know about the composition and structure of interstellar materials. The attached paper is the result. This is a good time for such a review since tremendous progress has been made in the field of interstellar dust in recent years through the use of telescopic observations, theoretical studies, laboratory studies of analogs, and the study of actual interstellar samples found in meteorites. It is increasing clear that the interstellar medium (ISM) contains an enormous diversity of materials created by a wide range of chemical and physical processes. This understanding is a far cry from the picture of interstellar materials held as recently as two decades ago, a picture which incorporated only a few generic types of grains and few molecules. In the paper I review our current knowledge of the more abundant materials thought to exist in the ISM. The review concentrates on matter in interstellar dense molecular clouds since it is the materials in these environments from which new stars and planetary systems are formed, although materials in circumstellar environments and in the diffuse ISM are also discussed. The paper focuses largely on solid materials since they contain a major fraction of the heavier elements in clouds and because solids are most likely to survive incorporation into new planetary systems in identifiable form. The paper concludes with discussion of some of the implications resulting from the identification of these interstellar materials. I also present some new thoughts, the most intriguing being that meteoritic 'microdiamonds' may be the same material that modelers of the interstellar extinction call graphite! If my suggestion is correct it will help resolve the dilemma associated with the current over-subscription of cosmic C and should lead to some new approaches to both extinction models and the study of meteoritic interstellar microdiamonds.

A Rigorous Attempt to Verify Interstellar Glycine

NASA Technical Reports Server (NTRS)

Snyder, L. E.; Lovas, F. J.; Hollis, J. M.; Friedel, D. N.; Jewell, P. R.; Remijan, A.; Ilyushin, V. V.; Alekseev, E. A.; Dyubko, S. F.

2004-01-01

In 2003, Kuan, Charnley, and co-workers reported the detection of interstellar glycine (NH2CH2COOH) based on observations of 27 lines in 19 different spectral bands in one or more of the sources Sgr BP(N-LMH), Orion KL, and W51 e1/e2. They supported their detection report with rotational temperature diagrams for all three sources. In this paper, we present essential criteria which can be used in a straightforward analysis technique to confirm the identity of an interstellar asymmetric rotor such as glycine. We use new laboratory measurements of glycine as a basis for applying this analysis technique, both to our previously unpublished 12 m telescope data and to the previously published SEST data of Nummelin and colleagues. We conclude that key lines necessary for an interstellar glycine identification have not yet been found. We identify several common molecular candidates that should be examined further as more likely carriers of the lines reported as glycine. Finally, we illustrate that rotational temperature diagrams used without the support of correct spectroscopic assignments are not a reliable tool for the identification of interstellar molecules. Subject headings: ISM: abundances - ISM: clouds - ISM: individual (Sagittarius B2[N-

Laboratory Studies on the Formation of Carbon-Bearing Molecules in Extraterrestrial Environments: From the Gas Phase to the Solid State

NASA Technical Reports Server (NTRS)

Jamieson, C. S.; Guo, Y.; Gu, X.; Zhang, F.; Bennett, C. J.; Kaiser, R. I.

2006-01-01

A detailed knowledge of the formation of carbon-bearing molecules in interstellar ices and in the gas phase of the interstellar medium is of paramount interest to understand the astrochemical evolution of extraterrestrial environments (1). This research also holds strong implications to comprehend the chemical processing of Solar System environments such as icy planets and their moons together with the atmospheres of planets and their satellites (2). Since the present composition of each interstellar and Solar System environment reflects the matter from which it was formed and the processes which have changed the chemical nature since the origin (solar wind, planetary magnetospheres, cosmic ray exposure, photolysis, chemical reactions), a detailed investigation of the physicochemical mechanisms altering the pristine environment is of paramount importance to grasp the contemporary composition. Once these underlying processes have been unraveled, we can identify those molecules, which belonged to the nascent setting, distinguish molecular species synthesized in a later stage, and predict the imminent chemical evolution of, for instance, molecular clouds. Laboratory experiments under controlled physicochemical conditions (temperature, pressure, chemical composition, high energy components) present ideal tools for simulating the chemical evolution of interstellar and Solar System environments. Here, laboratory experiments can predict where and how (reaction mechanisms; chemicals necessary) in extraterrestrial environments and in the interstellar medium complex, carbon bearing molecules can be formed on interstellar grains and in the gas phase. This paper overviews the experimental setups utilized in our laboratory to mimic the chemical processing of gas phase and solid state (ices) environments. These are a crossed molecular beams machine (3) and a surface scattering setup (4). We also present typical results of each setup (formation of amino acids, aldehydes, epoxides; synthesis of hydrogen terminated carbon chains as precursors to complex PAHs and to carbonaceous dust grains in general; nitriles as precursor to amino acids).

The influence of Oort clouds on the mass and chemical balance of the interstellar medium

NASA Technical Reports Server (NTRS)

Stern, S. Alan; Shull, J. Michael

1990-01-01

The contribution of stellar encounters and interstellar erosion to comet cloud mass injection to the ISM is calculated. It is shown that evaporative mass loss from passing stars and SNe results in an average Galactic mass injection rate of up to 10 to the -5th solar mass/yr if such clouds are frequent around solar-type stars. Cometary erosion by interstellar grains produces an injection rate of 10 to the -5th to 10 to the -4th solar mass/yr. An injection rate of 2 x 10 to the -5th solar mass/yr is calculated. Each of these rates could be increased by a factor of about 15 if the comet clouds contain a significant amount of smaller debris. It is concluded that the total mass injection rate of material to the ISM by comet clouds is small compared to other ISM mass injection sources. Comet cloud mass loss to the ISM could be responsible for a sizeable fraction of the metal and dust abundances of the ISM if Oort clouds are common.

The Galactic Distribution of OB Associations in Molecular Clouds

NASA Astrophysics Data System (ADS)

Williams, Jonathan P.; McKee, Christopher F.

1997-02-01

Molecular clouds account for half of the mass of the interstellar medium interior to the solar circle and for all current star formation. Using cloud catalogs of two CO surveys of the first quadrant, we have fitted the mass distribution of molecular clouds to a truncated power law in a similar manner as the luminosity function of OB associations in the companion paper to this work. After extrapolating from the first quadrant to the entire inner Galaxy, we find that the mass of cataloged clouds amounts to only 40% of current estimates of the total Galactic molecular mass. Following Solomon & Rivolo, we have assumed that the remaining molecular gas is in cold clouds, and we normalize the distribution accordingly. The predicted total number of clouds is then shown to be consistent with that observed in the solar neighborhood where cloud catalogs should be more complete. Within the solar circle, the cumulative form of the distribution is \\Nscrc(>M)=105[(Mu/M)0.6-1], where \\Nscrc is the number of clouds, and Mu = 6 × 106 M⊙ is the upper mass limit. The large number of clouds near the upper cutoff to the distribution indicates an underlying physical limit to cloud formation or destruction processes. The slope of the distribution corresponds to d\\Nscrc/dM~M-1.6, implying that although numerically most clouds are of low mass, most of the molecular gas is contained within the most massive clouds. The distribution of cloud masses is then compared to the Galactic distribution of OB association luminosities to obtain statistical estimates of the number of massive stars expected in any given cloud. The likelihood of massive star formation in a cloud is determined, and it is found that the median cloud mass that contains at least one O star is ~105 M⊙. The average star formation efficiency over the lifetime of an association is about 5% but varies by more than 2 orders of magnitude from cloud to cloud and is predicted to increase with cloud mass. O stars photoevaporate their surrounding molecular gas, and even with low rates of formation, they are the principal agents of cloud destruction. Using an improved estimate of the timescale for photoevaporation and our statistics on the expected numbers of stars per cloud, we find that 106 M⊙ giant molecular clouds (GMCs) are expected to survive for about 3 × 107 yr. Smaller clouds are disrupted, rather than photoionized, by photoevaporation. The porosity of H II regions in large GMCs is shown to be of order unity, which is consistent with self-regulation of massive star formation in GMCs. On average, 10% of the mass of a GMC is converted to stars by the time it is destroyed by photoevaporation.

A cloud/particle model of the interstellar medium - Galactic spiral structure

NASA Technical Reports Server (NTRS)

Levinson, F. H.; Roberts, W. W., Jr.

1981-01-01

A cloud/particle model for gas flow in galaxies is developed that incorporates cloud-cloud collisions and supernovae as dominant local processes. Cloud-cloud collisions are the main means of dissipation. To counter this dissipation and maintain local dispersion, supernova explosions in the medium administer radial snowplow pushes to all nearby clouds. The causal link between these processes is that cloud-cloud collisions will form stars and that these stars will rapidly become supernovae. The cloud/particle model is tested and used to investigate the gas dynamics and spiral structures in galaxies where these assumptions may be reasonable. Particular attention is given to whether large-scale galactic shock waves, which are thought to underlie the regular well-delineated spiral structure in some galaxies, form and persist in a cloud-supernova dominated interstellar medium; this question is answered in the affirmative.

Collisional excitation of CH2 rotational/fine-structure levels by helium

NASA Astrophysics Data System (ADS)

Dagdigian, P. J.; Lique, F.

2018-02-01

Accurate determination of the abundance of CH2 in interstellar media relies on both radiative and collisional rate coefficients. We investigate here the rotational/fine-structure excitation of CH2 induced by collisions with He. We employ a recoupling technique to generate fine-structure-resolved cross-sections and rate coefficients from close coupling spin-free scattering calculations. The calculations are based on a recent, high-accuracy CH2-He potential energy surface computed at the coupled clusters level of theory. The collisional cross-section calculations are performed for all fine-structure transitions among the first 22 and 24 energy levels of ortho- and para-CH2, respectively, and for temperatures up to 300 K. As a first application, we simulate the excitation of CH2 in typical molecular clouds. The excitation temperatures of the CH2 lines are found to be small at typical densities of molecular clouds, showing that the non-local thermodynamic equilibrium approach has to be used to analyse interstellar spectra. We also found that the fine-structure lines connected with the 404 - 313 and 505 - 414 rotational transitions show possible maser emissions so that they can be easily seen in emission. These calculations show that CH2 may have to be detected mainly through absorption spectra.

Model for diffuse interstellar clouds: improvements to the theory of molecular hydrogen photodestruction and to the gas phase chemistry of carbon monoxide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Federman, S.R.

1979-01-01

A theoretical model has been developed to determine physical processes in conjunction with astrophysical observation. The calculations are based on isobaric, steady-state, plane-parallel conditions. In the model, the cloud is illuminated by ultraviolet radiation from one side. The density and temperature of the gas are derived by invoking energy conservation in terms of thermal balance. The derived values for density and temperature then are used to determine the abundances of approximately fifty atomic and molecular species, including important ionic species and simple carbon and oxygen bearing molecules. Except for molecular hydrogen formation on dust grains, binary gas phase reactions aremore » used to develop the chemistry of the model cloud. The theoretical model has been found to be appropriate for a particular range of physical parameters. The results of the steady-state calculations have been compared to ultraviolet observations, predominantly those made with the Copernicus satellite. The theory of molecular hydrogen photodestruction has been reexamined so that improvements to the model can be made. By analyzing the region where the atomic to molecuar hydrogen transition occurs, several processes have been found to contribute to dissociation.« less

Structure formation in a colliding flow: The Herschel view of the Draco nebula

NASA Astrophysics Data System (ADS)

Miville-Deschênes, M.-A.; Salomé, Q.; Martin, P. G.; Joncas, G.; Blagrave, K.; Dassas, K.; Abergel, A.; Beelen, A.; Boulanger, F.; Lagache, G.; Lockman, F. J.; Marshall, D. J.

2017-03-01

Context. The Draco nebula is a high Galactic latitude interstellar cloud observed at velocities corresponding to the intermediate velocity cloud regime. This nebula shows unusually strong CO emission and remarkably high-contrast small-scale structures for such a diffuse high Galactic latitude cloud. The 21 cm emission of the Draco nebula reveals that it is likely to have been formed by the collision of a cloud entering the disk of the Milky Way. Such physical conditions are ideal to study the formation of cold and dense gas in colliding flows of diffuse and warm gas. Aims: The objective of this study is to better understand the process of structure formation in a colliding flow and to describe the effects of matter entering the disk on the interstellar medium. Methods: We conducted Herschel-SPIRE observations of the Draco nebula. The clumpfind algorithm was used to identify and characterize the small-scale structures of the cloud. Results: The high-resolution SPIRE map reveals the fragmented structure of the interface between the infalling cloud and the Galactic layer. This front is characterized by a Rayleigh-Taylor (RT) instability structure. From the determination of the typical length of the periodic structure (2.2 pc) we estimated the gas kinematic viscosity. This allowed us to estimate the dissipation scale of the warm neutral medium (0.1 pc), which was found to be compatible with that expected if ambipolar diffusion were the main mechanism of turbulent energy dissipation. The statistical properties of the small-scale structures identified with clumpfind are found to be typical of that seen in molecular clouds and hydrodynamical turbulence in general. The density of the gas has a log-normal distribution with an average value of 103 cm-3. The typical size of the structures is 0.1-0.2 pc, but this estimate is limited by the resolution of the observations. The mass of these structures ranges from 0.2 to 20 M⊙ and the distribution of the more massive structures follows a power-law dN/ dlog (M) M-1.4. We identify a mass-size relation with the same exponent as that found in molecular clouds (M L2.3). On the other hand, we found that only 15% of the mass of the cloud is in gravitationally bound structures. Conclusions: We conclude that the collision of diffuse gas from the Galactic halo with the diffuse interstellar medium of the outer layer of the disk is an efficient mechanism for producing dense structures. The increase of pressure induced by the collision is strong enough to trigger the formation of cold neutral medium out of the warm gas. It is likely that ambipolar diffusion is the mechanism dominating the turbulent energy dissipation. In that case the cold structures are a few times larger than the energy dissipation scale. The dense structures of Draco are the result of the interplay between magnetohydrodynamical turbulence and thermal instability as self-gravity is not dominating the dynamics. Interestingly they have properties typical of those found in more classical molecular clouds. Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.The reduced Herschel data (FITS files) are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/599/A109

Search for the CO-dark Mass in the Central Molecular Zone by using the ASTE 10-m Telescope

NASA Astrophysics Data System (ADS)

Tanaka, Kunihiko

2017-01-01

Atomic carbon (C0) is one of the most abundant carbon-bearing species in the interstellar molecular gas, and its submillimeter lines are good tracers of low-density molecular clouds which are often dark in CO rotational lines. We present a new map of the central 150 pc region of the Milky Way in the 500 GHz [CI] line, which has been recently obtained with the ASTE 10-m telescope. The [CI] emission is brightest toward the central 5-pc region, where massive GMCs are absent. This [CI]-bright region is approximately centered toward Sgr A*, covering the entire circum-nuclear ring (CND) and the western part of the 50-km/s cloud. The C0/CO abundance ratio is 0.5-2 there, and the highest ratio is observed toward the CND but just outside of the 2-pc ring of dense gas. This discovery may suggest that the CO-dark component occupies a significant fraction of the molecular gas in the circumnuclear region.

Champagne flutes and brandy snifters: modelling protostellar outflow-cloud chemical interfaces

NASA Astrophysics Data System (ADS)

Rollins, R. P.; Rawlings, J. M. C.; Williams, D. A.; Redman, M. P.

2014-10-01

A rich variety of molecular species has now been observed towards hot cores in star-forming regions and in the interstellar medium. An increasing body of evidence from millimetre interferometers suggests that many of these form at the interfaces between protostellar outflows and their natal molecular clouds. However, current models have remained unable to explain the origin of the observational bias towards wide-angled `brandy snifter' shaped outflows over narrower `champagne flute' shapes in carbon monoxide imaging. Furthermore, these wide-angled systems exhibit unusually high abundances of the molecular ion HCO+. We present results from a chemodynamic model of such regions where a rich chemistry arises naturally as a result of turbulent mixing between cold, dense molecular gas and the hot, ionized outflow material. The injecta drives a rich and rapid ion-neutral chemistry in qualitative and quantitative agreement with the observations. The observational bias towards wide-angled outflows is explained naturally by the geometry-dependent ion injection rate causing rapid dissociation of CO in the younger systems.

Laboratory Studies of Extraterrestrial Ices and PAHs: Making an Astrobiological Silk Purse Out of An Interstellar Sow's Ear

NASA Technical Reports Server (NTRS)

Hudgins, Douglas M.; DeVincenzi, Donald (Technical Monitor)

2002-01-01

Tremendous strides have been made in our understanding of interstellar material over the past twenty years thanks to significant, parallel developments in observational astronomy and laboratory astrophysics. Today, the composition of dust in the ISM is reasonably well constrained to cold, micron-sized particles of various refractory materials. Shrouded within the protective confines of cold, opaque molecular clouds--the birthplace of stars and planets--these particles secrete mantles of mixed molecular lees whose major components are also well constrained. Finally, amidst the molecular inventory of these ice mantles are likely to be found polycyclic aromatic hydrocarbons (PAHs), whose telltale infrared signature I is now recognized throughout the Universe. However, of what significance is this scenario to the origin of life in our solar system--or any other? The major components of the icy materials observed in interstellar clouds and in our own solar system are uniformly quite simple. In addition, despite the fact that PAHs likely represent the single largest molecular reservoir of organic carbon in evolving planetary systems, they are not what would be considered "biogenic" molecules. Although interesting from a chemical and astrophysical standpoint, in the absence of a mechanism by which these materials can be transformed into more biochemically significant structures, they are of little Astrobiological significance. In this talk, we will begin with a brief review of the nature and abundance of the "raw" population of PAHs and PAH-related materials in the ISM. From there, we will move on to explore our laboratory simulations of the photochemical evolution of realistic mixed molecular ices under conditions which simulate those encountered in the ISM and in evolving planetary systems. Particular attention will be paid to the surprisingly complex array of organic species that are produced in these ices from such a deceptively simple inventory of starting materials. In addition, we will explore the chemistry of PAHs under these conditions and consider its potential for transforming that rich repository of pre-biotic organic "ore" into materials of greater importance to Astrobiology.

The determination of cloud masses and dust characteristics from submillimetre thermal emission

NASA Technical Reports Server (NTRS)

Hildebrand, R. H.

1983-01-01

The principles by which the dust and masses and total masses of interstellar clouds and certain characteristics of interstellar dust grains can be derived from observations of far infrared and submillimeter thermal emission are reviewed. To the extent possible, the discussion will be independent of particular grain models.

Shocked molecular gas and the origin of cosmic rays

NASA Astrophysics Data System (ADS)

Reach, William; Gusdorf, Antoine; Richter, Matthew

2018-06-01

When massive stars reach the end of their ability to remain stable with core nuclear fusion, they explode in supernovae that drive powerful shocks into their surroundings. Because massive stars form in and remain close to molecular clouds they often drive shocks into dense gas, which is now believed to be the origin of a significant fraction of galactic cosmic rays. The nature of the supernova-molecular cloud interaction is not well understood, though observations are gradually elucidating their nature. The range of interstellar densities, and the inclusion of circumstellar matter from the late-phase mass-loss of the stars before their explosions, leads to a wide range of possible appearances and outcomes. In particular, it is not even clear what speed or physical type of shocks are present: are they dense, magnetically-mediated shocks where H2 is not dissociated, or are they faster shocks that dissociate molecules and destroy some of the grains? SOFIA is observing some of the most significant (in terms of cosmic ray production potential and infrared energy output) supernova-molecular cloud interactions for measurement of the line widths of key molecular shocks tracers: H2, [OI], and CO. The presence of gas at speeds 100 km/s or greater would indicate dissociative shocks, while speeds 30 km/s and slower retain most molecules. The shock velocity is a key ingredient in modeling the interaction between supernovae and molecular clouds including the potential for formation of cosmic rays.

Racemic amino acids from the ultraviolet photolysis of interstellar ice analogues.

PubMed

Bernstein, Max P; Dworkin, Jason P; Sandford, Scott A; Cooper, George W; Allamandola, Louis J

2002-03-28

The delivery of extraterrestrial organic molecules to Earth by meteorites may have been important for the origin and early evolution of life. Indigenous amino acids have been found in meteorites-over 70 in the Murchison meteorite alone. Although it has been generally accepted that the meteoritic amino acids formed in liquid water on a parent body, the water in the Murchison meteorite is depleted in deuterium relative to the indigenous organic acids. Moreover, the meteoritical evidence for an excess of laevo-rotatory amino acids is hard to understand in the context of liquid-water reactions on meteorite parent bodies. Here we report a laboratory demonstration that glycine, alanine and serine naturally form from ultraviolet photolysis of the analogues of icy interstellar grains. Such amino acids would naturally have a deuterium excess similar to that seen in interstellar molecular clouds, and the formation process could also result in enantiomeric excesses if the incident radiation is circularly polarized. These results suggest that at least some meteoritic amino acids are the result of interstellar photochemistry, rather than formation in liquid water on an early Solar System body.

H2-rich interstellar grain mantles: An equilibrium description

NASA Technical Reports Server (NTRS)

Dissly, Richard W.; Allen, Mark; Anicich, Vincent G.

1994-01-01

Experiments simulating the codeposition of molecular hydrogen and water ice on interstellar grains demonstrate that amorphous water ice at 12 K can incorporate a substantial amount of H2, up to a mole ratio of H2/H2O = 0.53. We find that the physical behavior of approximately 80% of the hydrogen can be explained satisfactorily in terms of an equilibrium population, thermodynamically governed by a wide distribution of binding site energies. Such a description predicts that gas phase accretion could lead to mole fractions of H2 in interstellar grain mantles of nearly 0.3; for the probable conditions of WL5 in the rho Ophiuchi cloud, an H2 mole fraction of between 0.05 and 0.3 is predicted, in possible agreement with the observed abundance reported by Sandford, Allamandola, & Geballe. Accretion of gas phase H2 onto grain mantles, rather than photochemical production of H2 within the ice, could be a general explanation for frozen H2 in interstellar ices. We speculate on the implications of such a composition for grain mantle chemistry and physics.

Racemic amino acids from the ultraviolet photolysis of interstellar ice analogues

NASA Technical Reports Server (NTRS)

Bernstein, Max P.; Dworkin, Jason P.; Sandford, Scott A.; Cooper, George W.; Allamandola, Louis J.

2002-01-01

The delivery of extraterrestrial organic molecules to Earth by meteorites may have been important for the origin and early evolution of life. Indigenous amino acids have been found in meteorites-over 70 in the Murchison meteorite alone. Although it has been generally accepted that the meteoritic amino acids formed in liquid water on a parent body, the water in the Murchison meteorite is depleted in deuterium relative to the indigenous organic acids. Moreover, the meteoritical evidence for an excess of laevo-rotatory amino acids is hard to understand in the context of liquid-water reactions on meteorite parent bodies. Here we report a laboratory demonstration that glycine, alanine and serine naturally form from ultraviolet photolysis of the analogues of icy interstellar grains. Such amino acids would naturally have a deuterium excess similar to that seen in interstellar molecular clouds, and the formation process could also result in enantiomeric excesses if the incident radiation is circularly polarized. These results suggest that at least some meteoritic amino acids are the result of interstellar photochemistry, rather than formation in liquid water on an early Solar System body.

Evolutionary Models of Cold, Magnetized, Interstellar Clouds

NASA Technical Reports Server (NTRS)

Gammie, Charles F.; Ostriker, Eve; Stone, James M.

2004-01-01

We modeled the long-term and small-scale evolution of molecular clouds using direct 2D and 3D magnetohydrodynamic (MHD) simulations. This work followed up on previous research by our group under auspices of the ATP in which we studied the energetics of turbulent, magnetized clouds and their internal structure on intermediate scales. Our new work focused on both global and smallscale aspects of the evolution of turbulent, magnetized clouds, and in particular studied the response of turbulent proto-cloud material to passage through the Galactic spiral potential, and the dynamical collapse of turbulent, magnetized (supercritical) clouds into fragments to initiate the formation of a stellar cluster. Technical advances under this program include developing an adaptive-mesh MHD code as a successor to ZEUS (ATHENA) in order to follow cloud fragmentation, developing a shearing-sheet MHD code which includes self-gravity and externally-imposed gravity to follow the evolution of clouds in the Galactic potential, and developing radiative transfer models to evaluate the internal ionization of clumpy clouds exposed to external photoionizing UV and CR radiation. Gammie's work at UIUC focused on the radiative transfer aspects of this program.

X-Ray Dust Tomography: Mapping the Galaxy one X-ray Transient at a Time

NASA Astrophysics Data System (ADS)

Heinz, Sebastian; Corrales, Lia

2018-01-01

Tomography using X-ray light echoes from dust scattering by interstellar clouds is an accurate tool to study the line-of-sight distribution of dust. It can be used to measure distances to molecular clouds and X-ray sources, it can map Galactic structure in dust, and it can be used for precision measurements of dust composition and grain size distribution. Necessary conditions for observing echoes include a suitable X-ray lightcurve and sufficient dust column density to the source. I will discuss a tool set for studying dust echoes and show results obtained for some of the brightest echoes detected to date.

GOT C+: A Herschel Space Observatory Key Program to Study the Diffuse ISM

NASA Astrophysics Data System (ADS)

Langer, William; Velusamy, T.; Goldsmith, P. F.; Li, D.; Pineda, J.; Yorke, H.

2010-01-01

Star formation activity is regulated by pressures in the interstellar medium, which in turn depend on heating and cooling rates, modulated by the gravitational potential, and shock and turbulent pressures. To understand these processes we need information about the diffuse atomic and diffuse molecular gas cloud properties. The ionized carbon CII fine structure line at 1.9 THz is an important tracer of the atomic gas in the diffuse regions and the atomic to molecular cloud transformation. Furthermore, C+ is a major ISM coolant, the Galaxy's strongest emission line, with a total luminosity about a 1000 times that of CO J=1-0. Galactic Observations of the Terahertz C+ Line (GOT C+) is a Herschel Space Observatory Open Time Key Program to study the diffuse interstellar medium by sampling CII line emission throughout the Galactic disk. GOT C+ will obtain high spectral resolution CII using the Heterodyne Instrument for the Far Infrared (HIFI) instrument. It employees deep integrations, wide velocity coverage (350 km s-1) with 0.22 km s-1 resolution, and systematic sparse sampling of the Galactic disk together with observations of selected targets, of over 900 lines of sight. It will be a resource of the atomic gas properties, in the (a) Galactic disk, (b) Galaxy's central 300pc, (c) Galactic warp, (d) high latitude HI clouds, and (e) Photon Dominated Regions (PDRs). Along with HI, CO isotopes, and CI spectra, our C+ data will provide the astronomical community with a rich statistical database of diffuse cloud properties, for understanding the role of barometric pressure and turbulence in cloud evolution in the Galactic ISM and, by extension, other galaxies. The GOT C+ project will provide a template for future even larger-scale CII surveys. This research was conducted at the Jet Propulsion Laboratory, California Institute of Technology and is supported by a NASA grant.

Interstellar gas and X-rays toward the Young supernova remnant RCW 86; pursuit of the origin of the thermal and non-thermal X-ray

NASA Astrophysics Data System (ADS)

Sano, H.; Reynoso, E. M.; Mitsuishi, I.; Nakamura, K.; Furukawa, N.; Mruganka, K.; Fukuda, T.; Yoshiike, S.; Nishimura, A.; Ohama, A.; Torii, K.; Kuwahara, T.; Okuda, T.; Yamamoto, H.; Tachihara, K.; Fukui, Y.

2017-09-01

We have analyzed the atomic and molecular gas using the 21 cm HI and 2.6/1.3 mm CO emissions toward the young supernova remnant (SNR) RCW 86 in order to identify the interstellar medium with which the shock waves of the SNR interact. We have found an HI intensity depression in the velocity range between -46 and - 28 kms-1 toward the SNR, suggesting a cavity in the interstellar medium. The HI cavity coincides with the thermal and non-thermal emitting X-ray shell. The thermal X-rays are coincident with the edge of the HI distribution, which indicates a strong density gradient, while the non-thermal X-rays are found toward the less dense, inner part of the HI cavity. The most significant non-thermal X-rays are seen toward the southwestern part of the shell where the HI gas traces the dense and cold component. We also identified CO clouds which are likely interacting with the SNR shock waves in the same velocity range as the HI, although the CO clouds are distributed only in a limited part of the SNR shell. The most massive cloud is located in the southeastern part of the shell, showing detailed correspondence with the thermal X-rays. These CO clouds show an enhanced CO J = 2- 1 / 1- 0 intensity ratio, suggesting heating/compression by the shock front. We interpret that the shock-cloud interaction enhances non-thermal X-rays in the southwest and the thermal X-rays are emitted by the shock-heated gas of density 10-100 cm-3. Moreover, we can clearly see an HI envelope around the CO cloud, suggesting that the progenitor had a weaker wind than the massive progenitor of the core-collapse SNR RX J1713.7-3949. It seems likely that the progenitor of RCW 86 was a system consisting of a white dwarf and a low-mass star with low-velocity accretion winds.

Observational Approach to Molecular Cloud Evolutation with the Submillimeter-Wave CI Lines

NASA Astrophysics Data System (ADS)

Oka, T.; Yamamoto, S.

Neutral carbon atoms (CI) play important roles both in chemistry and cooling processes of interstellar molecular clouds. It is thus crucial to explore its large area distribution to obtain information on formation processes and thermal balance of molecular clouds. However, observations of the submillimeter-wave CI lines have been limited to small areas around some representative objects. We have constructed a 1.2 m submillimeter-wave telescope at the summit of Mt.Fuji. The telescope was designed for the exclusive use of surveying molecular clouds in two submillimeter-wave CI lines, 3 P1 -3 P0 (492GHz) and 3 P2 -3 P1 (809 GHz), of atomic carbon. A superconductor-insulator-superconductor (SIS) mixer receiver was equipped on the Nasmyth focus of the telescope. The receiver noise temperatures [Trx(DSB)] are 300 K and 1000 K for the 492 GHz and the 809 GHz mixers, respectively. The intermediate frequency is centered at 2 GHz, having a 700 MHz bandwidth. An acousto-optical spectrometer (AOS) with 1024 channel outputs is used as a receiver backend. The telescope was installed at Nishi-yasugawara (alt. 3725 m), which is 200 m north of the highest peak, Kengamine (3776 m), in July 1998. It has b en operatede successfully during 4 observing seasons in a remote way from the Hongo campus of the University of Tokyo. We have already observed more than 40 square degrees of the sky with the CI 492 GHz line. The distribution of CI emission is found to be different from those of the 13 CO or C1 8 O emission in some clouds. These differences are discussed in relation to formation processes of molecular clouds.

O+OH-->O(2)+H: A key reaction for interstellar chemistry. New theoretical results and comparison with experiment.

PubMed

Lique, F; Jorfi, M; Honvault, P; Halvick, P; Lin, S Y; Guo, H; Xie, D Q; Dagdigian, P J; Kłos, J; Alexander, M H

2009-12-14

We report extensive, fully quantum, time-independent (TID) calculations of cross sections at low collision energies and rate constants at low temperatures for the O+OH reaction, of key importance in the production of molecular oxygen in cold, dark, interstellar clouds and in the chemistry of the Earth's atmosphere. Our calculations are compared with TID calculations within the J-shifting approximation, with wave-packet calculations, and with quasiclassical trajectory calculations. The fully quantum TID calculations yield rate constants higher than those from the more approximate methods and are qualitatively consistent with a low-temperature extrapolation of earlier experimental values but not with the most recent experiments at the lowest temperatures.

CNO isotopes in red giant stars

NASA Technical Reports Server (NTRS)

Wannier, P. G.

1985-01-01

Observational data on CNO abundance ratios in red giants and the interstellar medium (ISM) are analyzed for the implications for the production and distribution of CNO nuclides. The data included isotope abundance measurements for the atmospheres and recent ejecta of cool giants, e.g., carbon stars, S-type stars, red supergiants and oxygen-rich giants beginning an ascent of the giant branch. The contribution of intermediate-mass stars to galactic nuclear evolution is discussed after comparing red giant abundances with ISM abundances, particularly the isotopes O-16, -17 and -18. The O-12/O-18 ratios of red giants are distinctly different from those in interstellar molecular clouds. The CNO values also vary widely from the values found in the solar system.

Detection of the aromatic molecule benzonitrile (c-C6H5CN) in the interstellar medium

NASA Astrophysics Data System (ADS)

McGuire, Brett A.; Burkhardt, Andrew M.; Kalenskii, Sergei; Shingledecker, Christopher N.; Remijan, Anthony J.; Herbst, Eric; McCarthy, Michael C.

2018-01-01

Polycyclic aromatic hydrocarbons and polycyclic aromatic nitrogen heterocycles are thought to be widespread throughout the universe, because these classes of molecules are probably responsible for the unidentified infrared bands, a set of emission features seen in numerous Galactic and extragalactic sources. Despite their expected ubiquity, astronomical identification of specific aromatic molecules has proven elusive. We present the discovery of benzonitrile (c-C6H5CN), one of the simplest nitrogen-bearing aromatic molecules, in the interstellar medium. We observed hyperfine-resolved transitions of benzonitrile in emission from the molecular cloud TMC-1. Simple aromatic molecules such as benzonitrile may be precursors for polycyclic aromatic hydrocarbon formation, providing a chemical link to the carriers of the unidentified infrared bands.

Terahertz Spectroscopy of Deuterated Methylene Bi-Radical CD_2

NASA Astrophysics Data System (ADS)

Ozeki, Hiroyuki; Bailleux, Stephane

2015-06-01

Methylene, the parent of the carbene compounds, plays a crucial role in many chemical reactions. This bi-radical is a known interstellar molecule that has been detected towards hot cores in dense interstellar clouds. CH_2 is also thought to be present in cometary atmospheres. In the gas phase chemical models of both dense and diffuse molecular clouds, CH_2 is a key intermediate in interstellar carbon chemistry which is produced primarily by dissociative recombination of the methyl ion, CH^+_3. Recently tentative detection of the mono-deuterated methyl ion, CH_2D^+ has been reported toward an infrared source in the vicinity of Orion. Deuterated methylene CHD and CD_2 can be produced from this ion or its counterpart CHD^+_2 by dissociative recombination with an electron: CH2D+ + e- → CHD+ H or {CH2 + D}, CHD2+ ~+ e- → CHD+ D or CD2 + H. Thus, both CHD and CD_2 can be observed in warm interstellar clouds, where the deuterium fractionation process is important. Precise laboratory reference data are desirable for radioastronomical observation of these molecules. Here we report on our high-resolution spectroscopic investigation on the deuterated methylene radical, CD_2 (X ^3B_1) up to 1.45 THz. At present time, eleven out of the twelve fine-structure components of four pure rotational transitions have been newly recorded, and these measurements double the number of previously observed transitions. CD_2 was generated in a discharge in CD_2CO which was obtained from the flash pyrolysis of acetic anhydride-d6 ((CD_3CO)_2O). Effort is currently made to measure the astronomically important 111 - 000 transition whose fine-structure components are predicted to occur at 1.224,1.228 and 1.234 THz. D. C. Lis, P. F. Goldsmith, E. A. Bergin et al. 2009, in Submillimeter Astrophysics and Technology, ASP Conf. Ser., 417, 23. H. Ozeki and S. Saito J. Chem. Phys. 1996, 104, 2167.

Formation of complex precursors of amino acids by irradiation of simulated interstellar media with heavy ions

NASA Astrophysics Data System (ADS)

Kobayashi, K.; Suzuki, N.; Taniuchi, T.; Kaneko, T.; Yoshida, S.

A wide variety of organic compounds have been detected in such extraterrestrial bodies as meteorites and comets Amino acids were identified in the extracts from Murchison meteorite and other carbonaceous chondrites It is hypothesized that these compounds are originally formed in ice mantles of interstellar dusts ISDs in molecular clouds by cosmic rays and ultraviolet light UV Formation of amino acid precursors by high energy protons or UV irradiation of simulated ISDs was reported by several groups The amino acid precursors were however not well-characterized We irradiated a frozen mixture of methanol ammonia and water with heavy ions to study possible organic compounds abiotically formed in molecular clouds by cosmic rays A mixture of methanol ammonia and water was irradiated with carbon beams 290 MeV u from a heavy ion accelerator HIMAC of National Institute of Radiological Sciences Japan Irradiation was performed either at room temperature liquid phase or at 77 K solid phase The products were characterized by gel filtration chromatography GFC FT-IR pyrolysis PY -GC MS etc Amino acids were analyzed by HPLC and GC MS after acid hydrolysis or the products Amino acids such as glycine and alanine were identified in the products in both the cases of liquid phase and solid phase irradiation Energy yields G-values of glycine were 0 014 liquid phase and 0 007 solid phase respectively Average molecular weights of the products were estimated as to 2300 in both the case Aromatic hydrocarbons N-containing heterocyclic

Unusually high rotational temperature of the CN radical

NASA Astrophysics Data System (ADS)

Krełowski, J.; Galazutdinov, G.; Beletsky, Y.

2011-07-01

We analyse a high-resolution, high signal-to-noise spectrogram of the hot reddened star Trumpler 16 112 to find relationships between the physical parameters of the intervening interstellar medium (e.g., the rotational temperature of the CN radical) and the intensities of interstellar lines/bands. We report on the discovery of an interstellar cloud that shows an exceptionally high rotational temperature of CN (4.5 K) and unusually strong Ca I and Fe I interstellar lines. This rare CaFe-type cloud seemingly contains no diffuse band carriers. Based on observations collected at the European Organisation for Astronomical Research in the Southern Hemisphere, Chile. Programs 073.D-0609(A) and 082.C-0566(A).

GOT C+ Survey of Transition Clouds in the Inner Galaxy

NASA Astrophysics Data System (ADS)

Velusamy, Thangasamy; Langer, W. D.; Pineda, J. L.; Goldsmith, P. F.; Li, D.; Yorke, H. W.

2010-05-01

To understand star formation and the lifecycle of the interstellar gas we need detailed information about the transition of diffuse atomic to molecular clouds. The C+ line at 1.9 THz traces a so-far poorly studied stage in cloud evolution - the transitional clouds going from atomic HI to molecular H2 The transition cloud phase, which is difficult to observe in HI and CO alone, may be best characterized via CII emission or absorption. Here we present the first results on transition clouds along a few representative lines of sight in the inner Galaxy from longitude 325 degrees to 10 degrees, observed under the GOT C+ program, a HIFI Herschel Key Project to study the diffuse ISM. We can separate out the different ISM components along each line of sight by comparisons of the high spectral resolution ( 1 km/s) and high sensitivity (rms 0.1 K to 0.2 K) HIFI data on C+ with HI, 12CO, and 13CO spectra. These observations are being carried out with the Herschel Space Observatory. This research was conducted at the Jet Propulsion Laboratory, California Institute of Technology under contract with the National Aeronautics and Space Administration. JLP is supported under the NASA Postdoctoral Program at JPL, Caltech, administered by Oak Ridge Associated Universities through a contract with NASA.

Variations between Dust and Gas in the Diffuse Interstellar Medium. III. Changes in Dust Properties

NASA Astrophysics Data System (ADS)

Reach, William T.; Bernard, Jean-Philippe; Jarrett, Thomas H.; Heiles, Carl

2017-12-01

We study infrared emission of 17 isolated, diffuse clouds with masses of order {10}2 {M}ȯ to test the hypothesis that grain property variations cause the apparently low gas-to-dust ratios that have been measured in those clouds. Maps of the clouds were constructed from Wide-field Infrared Survey Explorer (WISE) data and directly compared with the maps of dust optical depth from Planck. The mid-infrared emission per unit dust optical depth has a significant trend toward lower values at higher optical depths. The trend can be quantitatively explained by the extinction of starlight within the clouds. The relative amounts of polycyclic aromatic hydrocarbon and very small grains traced by WISE, compared with large grains tracked by Planck, are consistent with being constant. The temperature of the large grains significantly decreases for clouds with larger dust optical depth; this trend is partially due to dust property variations, but is primarily due to extinction of starlight. We updated the prediction for molecular hydrogen column density, taking into account variations in dust properties, and find it can explain the observed dust optical depth per unit gas column density. Thus, the low gas-to-dust ratios in the clouds are most likely due to “dark gas” that is molecular hydrogen.

Searching for Bio-Precursors and Complex Organic Molecules in Space using the GBT

NASA Technical Reports Server (NTRS)

Cordiner, M.; Charnley, S.; Kisiel, Z.

2012-01-01

Using the latest microwave receiver technology, large organic molecules with abundances as low as approx. 10(exp -11) times that of molecular hydrogen are detectable in cold interstellar clouds via their rotational emission line spectra. We report new observations to search for complex molecules, including molecules of possible pre-biotic importance, using the newly-commissioned Kband focal plane array (KFPA) of the NRAO Robert C. Byrd Green Bank Telescope. Spectra are presented of the dense molecular cloud TMC-1, showing strict upper limits on the level of emission from nitrogen-bearing rings pyrimidine, quinoline and iso-quinoline, carbon-chain oxides C60, C70, HC60 and HC70, and the carbon-chain anion C4H-. The typical RMS brightness temperature noise levels we achieved are approx. 1 mK at around 20 GHz.

Occurrence and Forms of Water and Ice on the Earth and Beyond, and the Origin(s) of Life

NASA Technical Reports Server (NTRS)

Blake, David F.; DeVincenzi, Donald L. (Technical Monitor)

1998-01-01

The natural history of the biogenic elements (H,C,O,N) from their first association within cold molecular clouds to their delivery to the Earth during the late bombardment of the inner solar system, is intimately linked to water ice. The earliest organic compounds are formed in cold interstellar molecular clouds as a result of UV and thermal processing of sub-micrometer ice grains which contain trapped carbon and nitrogen molecules. Structural changes in the water ice host underlie and fundamentally control important macroscopic phenomena such as the outgassing of volatiles, the rates of chemical reactions, and processing and retention of organic compounds. Prebiotic organic material was in all likelihood delivered the early Earth in a pristine state as a consequence of its sequestration within a protective water ice host.

Evolutionary models of interstellar chemistry

NASA Technical Reports Server (NTRS)

Prasad, Sheo S.

1987-01-01

The goal of evolutionary models of interstellar chemistry is to understand how interstellar clouds came to be the way they are, how they will change with time, and to place them in an evolutionary sequence with other celestial objects such as stars. An improved Mark II version of an earlier model of chemistry in dynamically evolving clouds is presented. The Mark II model suggests that the conventional elemental C/O ratio less than one can explain the observed abundances of CI and the nondetection of O2 in dense clouds. Coupled chemical-dynamical models seem to have the potential to generate many observable discriminators of the evolutionary tracks. This is exciting, because, in general, purely dynamical models do not yield enough verifiable discriminators of the predicted tracks.

The Infrared Reflection Nebula Around the Protostellar System in S140

NASA Technical Reports Server (NTRS)

Harker, D.; Bregman, J.; Tielens, A. G. G. M.; Temi, P.; Rank, D.; Morrison, David (Technical Monitor)

1994-01-01

We have studied the protostellar system in S140 at 2.2, 3.1 and 3.45 microns using a 128x128 InSb array at the Lick Observatory 3m telescope. Besides the protostellar sources, the data reveal a bright infrared reflection nebula. We have developed a simple model of this region and derived the physical conditions. IRSI is surrounded by a dense dusty disk viewed almost edge-on. Photons leaking out through the poles illuminate almost directly north and south the inner edge of a surrounding shell of molecular gas, Analysis of the observed colors and intensities of the NIR light, using Mie scattering theory, reveal that the dust grains in the molecular cloud are somewhat larger than in the general diffuse interstellar medium. Moreover, the incident light has a "cool" color temperature, approximately equals 800K, and likely originates from a dust photosphere close to the protostar. Finally, we find little H2O ice associated with the dusty disk around IRSI. Most of the 3.1 micron ice extinction arises instead from cool intervening molecular cloud material. We have compared our infrared dust observations with millimeter and radio observations of molecular gas associated with this region. The large scale structure observable in the molecular gas is indicative of the interaction between the protostellar wind and the surrounding molecular cloud rather than the geometry of the protostellar disk. We conclude that S140 is a young blister formed by this outflow on the side of a molecular cloud and viewed edge-on.

Chemical evolution in space--a source of prebiotic molecules.

PubMed

Greenberg, J M

1983-01-01

In Laboratory Astrophysics at Leiden University a laboratory analog for following the chemical evolution of interstellar dust in space shows that the dust contains the bulk of organic material in the universe. We follow the photoprocessing of low temperature (10 K) mixtures of ices subjected to vacuum ultraviolet radiation in simulation of interstellar conditions. The most important, but necessary, difference is in the time scales for photo-processing. One hour in the laboratory is equivalent to one thousand years in low density regions of space and as much as, or greater than, ten thousand to one million years in the depths of dense molecular clouds. The ultimate product of photoprocessing of grain material in the laboratory is a complex nonvolatile residue which is yellow in color and soluble in water and methanol. The molecular weight is greater than the mid-hundreds. The infrared absorption spectra indicate the presence of carboxylic acid and amino groups resembling those of other molecules of presumably prebiological significance produced by more classical methods. One of our residues, when subjected to high resolution mass spectroscopy gave a mass of 82 corresponding to C4H6H2 after release of CO2 and trace ammounts of urea suggesting amino pyroline rings. The deposit of prebiotic dust molecules occurred as many as 5 times in the first 500-700 million years on a primitive Earth by accretion during the passage of the solar system through a dense interstellar cloud. The deposition rate during each passage is estimated to be between 10(9) and 10(10) g per year during the million or so years of each passage; i.e., a total deposition of 1O(9)-10(10) metric tons of complex organic material per passage.

Lower mass limit of an evolving interstellar cloud and chemistry in an evolving oscillatory cloud

NASA Technical Reports Server (NTRS)

Tarafdar, S. P.

1986-01-01

Simultaneous solution of the equation of motion, equation of state and energy equation including heating and cooling processes for interstellar medium gives for a collapsing cloud a lower mass limit which is significantly smaller than the Jeans mass for the same initial density. The clouds with higher mass than this limiting mass collapse whereas clouds with smaller than critical mass pass through a maximum central density giving apparently similar clouds (i.e., same Av, size and central density) at two different phases of its evolution (i.e., with different life time). Preliminary results of chemistry in such an evolving oscillatory cloud show significant difference in abundances of some of the molecules in two physically similar clouds with different life times. The problems of depletion and short life time of evolving clouds appear to be less severe in such an oscillatory cloud.

Goulds Belt, Interstellar Clouds, and the Eocene-Oligocene Helium-3 Spike

NASA Technical Reports Server (NTRS)

Rubincam, David Parry

2015-01-01

Drag from hydrogen in the interstellar cloud which formed Gould's Belt may have sent small meteoroids with embedded helium to the Earth, perhaps explaining part or all of the (sup 3) He spike seen in the sedimentary record at the Eocene-Oligocene transition. Assuming the Solar System passed through part of the cloud, meteoroids in the asteroid belt up to centimeter size may have been dragged to the resonances, where their orbital eccentricities were pumped up into Earth-crossing orbits.

Observations of Carbon Isotopic Fractionation in Interstellar Formaldehyde

NASA Technical Reports Server (NTRS)

Wirstrom, E. S.; Charnley, S. B.; Geppert, W. D.; Persson, C. M.

2012-01-01

Primitive Solar System materials (e.g. chondrites. IDPs, the Stardust sample) show large variations in isotopic composition of the major volatiles (H, C, N, and O ) even within samples, witnessing to various degrees of processing in the protosolar nebula. For ex ample. the very pronounced D enhancements observed in IDPs [I] . are only generated in the cold. dense component of the interstellar medium (ISM), or protoplanetary disks, through ion-molecule reactions in the presence of interstellar dust. If this isotopic anomaly has an interstellar origin, this leaves open the possibility for preservation of other isotopic signatures throughout the form ation of the Solar System. The most common form of carbon in the ISM is CO molecules, and there are two potential sources of C-13 fractionation in this reservoir: low temperature chemistry and selective photodissociation. While gas-phase chemistry in cold interstellar clouds preferentially incorporates C-13 into CO [2], the effect of self-shielding in the presence of UV radiation instead leads to a relative enhancement of the more abundant isotopologue, 12CO. Solar System organic material exhibit rather small fluctuations in delta C-13 as compared to delta N-15 and delta D [3][1], the reason for which is still unclear. However, the fact that both C-13 depleted and enhanced material exists could indicate an interstellar origin where the two fractionation processes have both played a part. Formaldehyde (H2CO) is observed in the gas-phase in a wide range of interstellar environments, as well as in cometary comae. It is proposed as an important reactant in the formation of more complex organic molecules in the heated environments around young stars, and formaldehyde polymers have been suggested as the common origin of chondritic insoluable organic matter (IOM) and cometary refractory organic solids [4]. The relatively high gas-phase abundance of H2CO observed in molecular clouds (10(exp- 9) - 10(exp- 8) relative to H2) makes it feasible to observe its less common isotopologues. As a step in our investigation of C-13 fractionation patterns in the ISM, we here present comparisons between observations of the C-13 fraction in formaldehyde, and chemical fractionation models.

Effect of Ambipolar Diffusion on Ion Abundances in Contracting Protostellar Cores

NASA Astrophysics Data System (ADS)

Ciolek, Glenn E.; Mouschovias, Telemachos Ch.

1998-09-01

Numerical simulations and analytical solutions have established that ambipolar diffusion can reduce the dust-to-gas ratio in magnetically and thermally supercritical cores during the epoch of core formation. We study the effect that this has on the ion chemistry in contracting protostellar cores and present a simplified analytical method that allows one to calculate the ion power-law exponent k (≡d ln ni/d ln nn, where ni and nn are the ion and neutral densities, respectively) as a function of core density. We find that, as in earlier numerical simulations, no single value of k can adequately describe the ion abundance for nn <~ 109 cm-3, a result that is contrary to the ``canonical'' value of k = 1/2 found in previous static equilibrium chemistry calculations and often used to study the effect of ambipolar diffusion in interstellar clouds. For typical cloud and grain parameters, reduction of the abundance of grains results in k > 1/2 during the core formation epoch (densities <~105 cm-3). As a consequence, observations of the degree of ionization in cores could be used, in principle, to determine whether ambipolar diffusion is responsible for core formation in interstellar molecular clouds. For densities >>105 cm-3, k is generally <<1/2.

Abundances and Reactions of Sulfur Contianing Molecules in Interstellar Ices- Spectroscopic and Radiation-Chemical Investigations

NASA Astrophysics Data System (ADS)

Hudson, Reggie

Infrared (IR) telescopes, such as ISO, Spitzer, KAO, Keck, VLT, and IRTF, have revealed a rich variety of molecules trapped in interstellar ices. However, quantifying the abundances of these molecules has been difficult because reference IR data, such as band strengths and optical constants, often are poorly known. This scarcity of data has severe implications for the study of sulfur-containing molecules, such as OCS and SO2, since accurate molecular abundances are needed to address the missing-sulfur problem in interstellar space. The expected abundances of sulfur-containing species in dense molecular clouds are much higher than reported from telescopic observations, although the latter are based on laboratory data of questionable relevance, such as with liquids at room temperature compared to the 10 K ices of some interstellar regions. Exacerbating the problem is that few sulfur-containing molecules of any type have been examined in the laboratory under the necessary, relevant icy conditions. We propose to address and correct the problems associated with abundance determinations of interstellar sulfur-containing ices. We will combine several recent successful efforts from our laboratory and measure near- and mid-IR spectral intensities for ices containing SO2, OCS, H2S, CS2, CH3SH, and C2H5SH both in the presence and absence of H2O-ice. This work will be done at multiple temperatures and ice phases to generate reference IR spectra and band strengths, accompanied by refractive indices, and optical constants. Moreover, we will study the radiation chemistry of these molecules to determine their radiolytic half-lives (stabilities) and uncover product molecules that can become candidates for future searches and perhaps help better understand the missingsulfur problem. This proposal is a convergence of three lines of work in our laboratory: recent successes in deriving IR optical constants of interstellar molecular ices (Hudson et al. 2014a, 2014b), measurements of radiolytic stabilities of interstellar and planetary molecules (Gerakines & Hudson 2013, 2015), and our long history of working with sulfur-containing molecules and ions (Moore et al. 1988; Loeffler & Hudson 2010, 2012). Our collaborators were selected specifically for their interest in this proposal's focus and for their expertise in interstellar chemistry.

Fermi large area telescope study of cosmic rays and the interstellar medium in nearby molecular clouds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ackermann, M.; Ajello, M.; Allafort, A.

Here, we report an analysis of the interstellar γ-ray emission from the Chamaeleon, R Coronae Australis (R CrA), and Cepheus and Polaris flare regions with the Fermi Large Area Telescope. They are among the nearest molecular cloud complexes, within ~300 pc from the solar system. The γ-ray emission produced by interactions of cosmic rays (CRs) and interstellar gas in those molecular clouds is useful to study the CR densities and distributions of molecular gas close to the solar system. The obtained γ-ray emissivities above 250 MeV are (5.9 ± 0.1stat +0.9 –1.0sys) × 10 –27 photons s –1 sr –1more » H-atom –1, (10.2 ± 0.4 stat +1.2 –1.7sys) × 10 –27 photons s –1 sr –1 H-atom –1, and (9.1 ± 0.3 stat +1.5 –0.6sys) × 10 –27 photons s –1 sr–1 H-atom–1 for the Chamaeleon, R CrA, and Cepheus and Polaris flare regions, respectively. Whereas the energy dependences of the emissivities agree well with that predicted from direct CR observations at the Earth, the measured emissivities from 250 MeV to 10 GeV indicate a variation of the CR density by ~20% in the neighborhood of the solar system, even if we consider systematic uncertainties. Furthermore, we found that the molecular mass calibrating ratio, X CO = N(H 2)/W CO, was (0.96 ± 0.06 stat +0.15 –0.12sys) × 10 20 H 2-molecule cm –2 (K km s –1) –1, (0.99 ± 0.08 stat +0.18 –0.10sys) × 10 20 H 2-molecule cm –2 (K km s –1) –1, and (0.63 ± 0.02 stat +0.09 –0.07sys) × 10 20 H 2-molecule cm –2 (K km s –1) –1 for the Chamaeleon, R CrA, and Cepheus and Polaris flare regions, respectively, suggesting a variation of X CO in the vicinity of the solar system. The obtained values of X CO, the masses of molecular gas traced by W CO in the Chamaeleon, R CrA, and Cepheus and Polaris flare regions are estimated to be ~5 × 10 3 M ,⊙ ~10 3 M ,⊙ and ~3.3 × 10 4 M ,⊙ respectively. A comparable amount of gas not traced well by standard H I and CO surveys is found in the regions investigated.« less

Fermi large area telescope study of cosmic rays and the interstellar medium in nearby molecular clouds

DOE PAGES

Ackermann, M.; Ajello, M.; Allafort, A.; ...

2012-07-23

Here, we report an analysis of the interstellar γ-ray emission from the Chamaeleon, R Coronae Australis (R CrA), and Cepheus and Polaris flare regions with the Fermi Large Area Telescope. They are among the nearest molecular cloud complexes, within ~300 pc from the solar system. The γ-ray emission produced by interactions of cosmic rays (CRs) and interstellar gas in those molecular clouds is useful to study the CR densities and distributions of molecular gas close to the solar system. The obtained γ-ray emissivities above 250 MeV are (5.9 ± 0.1stat +0.9 –1.0sys) × 10 –27 photons s –1 sr –1more » H-atom –1, (10.2 ± 0.4 stat +1.2 –1.7sys) × 10 –27 photons s –1 sr –1 H-atom –1, and (9.1 ± 0.3 stat +1.5 –0.6sys) × 10 –27 photons s –1 sr–1 H-atom–1 for the Chamaeleon, R CrA, and Cepheus and Polaris flare regions, respectively. Whereas the energy dependences of the emissivities agree well with that predicted from direct CR observations at the Earth, the measured emissivities from 250 MeV to 10 GeV indicate a variation of the CR density by ~20% in the neighborhood of the solar system, even if we consider systematic uncertainties. Furthermore, we found that the molecular mass calibrating ratio, X CO = N(H 2)/W CO, was (0.96 ± 0.06 stat +0.15 –0.12sys) × 10 20 H 2-molecule cm –2 (K km s –1) –1, (0.99 ± 0.08 stat +0.18 –0.10sys) × 10 20 H 2-molecule cm –2 (K km s –1) –1, and (0.63 ± 0.02 stat +0.09 –0.07sys) × 10 20 H 2-molecule cm –2 (K km s –1) –1 for the Chamaeleon, R CrA, and Cepheus and Polaris flare regions, respectively, suggesting a variation of X CO in the vicinity of the solar system. The obtained values of X CO, the masses of molecular gas traced by W CO in the Chamaeleon, R CrA, and Cepheus and Polaris flare regions are estimated to be ~5 × 10 3 M ,⊙ ~10 3 M ,⊙ and ~3.3 × 10 4 M ,⊙ respectively. A comparable amount of gas not traced well by standard H I and CO surveys is found in the regions investigated.« less

The detection of interstellar methylcyanoacetylene

NASA Technical Reports Server (NTRS)

Broten, N. W.; Macleod, J. M.; Avery, L. W.; Friberg, P.; Hjalmarson, A.; Hoglund, B.; Irvine, W. M.

1984-01-01

A new interstellar molecule, methylcyanoacetylene (CH3C3N), has been detected in the molecular cloud TMC-1. The J = 8 to 7, J = 7 to 6, J = 6 to 5, and J = 5 to 4 transitions have been observed. For the first three of these, both the K = 0 and K = 1 components are present, while for J = 5 to 4, only the K = 0 line has been detected. The observed frequencies were calculated by assuming a value of radial velocity V(LSR) = 5.8 km/s for TMC-1, typical of other molecules in the cloud. All observed frequencies are within 10 kHz of the calculated frequencies, which are based on the 1982 laboratory constants of Moises et al. (1982), so the identification is secure. The lines are broadened by hyperfine splitting, and the J = 5 to 4, K = 0 transition shows incipient resolution into three hyperfine components. The rotational temperature determined from these observations is quite low, with T(rot) in the range from 2.7 to 4 K. The total column density is approximately 5 x 10 to the 12th per sq cm.

Complex Organics from Laboratory Simulated Interstellar Ices

NASA Technical Reports Server (NTRS)

Dworkin, J. P.

2003-01-01

Many of the volatiles in interstellar dense clouds exist in ices surrounding dust grains. The low temperatures of these ices (T < 50 K) preclude most chemical reactions, but photolysis can drive reactions that produce a suite of new species, many of which are complex organics. We study the UV and proton radiation processing of interstellar ice analogs to explore links between interstellar chemistry, the organics in comets and meteorites, and the origin of life on Earth. The high D/H ratios in some interstellar species, and the knowledge that many of the organics in primitive meteorites are D-enriched, suggest that such links are plausible. Once identified, these species may serve as markers of interstellar heritage of cometary dust and meteorites. Of particular interest are our findings that UV photolysis of interstellar ice analogs produce molecules of importance in current living organisms, including quinones, amphiphiles, and amino acids. Quinones are essential in vital metabolic roles such as electron transport. Studies show that quinones should be made wherever polycyclic aromatic hydrocarbons are photolyzed in interstellar ices. In the case of anthracene-containing ices, we have observed the production of 9-anthrone and 9,10 anthraquinone, both of which have been observed in the Murchison meteorite. Amphiphiles are also made when mixed molecular ices are photolyzed. These amphiphiles self-assemble into fluorescent vesicles when placed in liquid water, as do Murchison extracts. Both have the ability to trap an ionic dye. Photolysis of plausible ices can also produce alanine, serine, and glycine as well as a number of small alcohols and amines. Flash heating of the room temperature residue generated by such experiments generates mass spectral distributions similar to those of IDPs. The detection of high D/H ratios in some interstellar molecular species, and the knowledge that many of the organics, such as hydroxy and amino acids, in primitive meteorites are D-enriched provides evidence for a connection between intact organic material in the interstellar medium and in meteorites. Thus, some of the oxidized aromatics, amphiphiles, amino acids, hydroxy acids, and other compounds found in meteorites may have had an interstellar ancestry and not solely a product of parent body aqueous alteration. Such compounds should also be targeted for searches of organics in cometary dust.

DIBS independent of accretion in T Tauri stars

NASA Technical Reports Server (NTRS)

Ghandour, Louma; Jenniskens, Peter; Hartigan, P.

1994-01-01

The examination of high resolution spectra (5200 - 7000 Angstroms) of 36 T Tauri stars ranging in accretion rates was performed. Only the lambda lambda 5780, 5797, and 6613 bands were found detectable to within an equivalent width of 10 micro Angstroms. They are strongest in DG Tau, DR Tau, Dl Tau, and AS 353A. DR Tau was monitored over the course of four years; during this time, the accretion rate varied by a factor of five, but the equivalent widths of the DIB's (Diffuse Interstellar Bands) remained constant. The lack of correlation of the strength of the bands with the accretion rates implies that the bands are not directly produced by UV radiation from the accretion process. The bands have line strengths and ratios characteristic of the diffuse interstellar medium, from which we conclude that the diffuse interstellar bands seen in the spectra of T Tauri stars do not originate in the stars' immediate environment. Instead, they are part of a foreground extinction, probably due to the parent molecular cloud.

Organic Chemistry in Interstellar Ices: Connection to the Comet Halley Results

NASA Technical Reports Server (NTRS)

Schutte, W. A.; Agarwal, V. K.; deGroot, M. S.; Greenberg, J. M.; McCain, P.; Ferris, J. P.; Briggs, R.

1997-01-01

Mass spectroscopic measurements on the gas and dust in the coma of Comet Halley revealed the presence of considerable amounts of organic species. Greenberg (1973) proposed that prior to the formation of the comet UV processing of the ice mantles on grains in dense clouds could lead to the formation of complex organic molecules. Theoretical predictions of the internal UV field in dense clouds as well as the discovery in interstellar ices of species like OCS and OCN- which have been formed in simulation experiments by photoprocessing of interstellar ice analogues point to the importance of such processing. We undertook a laboratory simulation study of the formation of organic molecules in interstellar ices and their possible relevance to the Comet Halley results.

Interstellar Dust: Contributed Papers

NASA Technical Reports Server (NTRS)

Tielens, Alexander G. G. M. (Editor); Allamandola, Louis J. (Editor)

1989-01-01

A coherent picture of the dust composition and its physical characteristics in the various phases of the interstellar medium was the central theme. Topics addressed included: dust in diffuse interstellar medium; overidentified infrared emission features; dust in dense clouds; dust in galaxies; optical properties of dust grains; interstellar dust models; interstellar dust and the solar system; dust formation and destruction; UV, visible, and IR observations of interstellar extinction; and quantum-statistical calculations of IR emission from highly vibrationally excited polycyclic aromatic hydrocarbon (PAH) molecules.

Photometry and Classification of Stars around the Reflection Nebula NGC 7023 IN Cepheus. II. Interstellar Extinction and Cloud Distances

NASA Astrophysics Data System (ADS)

Zdanavičius, K.; Zdanavičius, J.; Straižys, V.; Maskoliūnas, M.

Interstellar extinction is investigated in a 1.5 square degree area in the direction of the reflection nebula NGC 7023 at ℓ = 104.1\\degr, b = +14.2\\degr. The study is based on photometric classification and the determination of interstellar extinctions and distances of 480 stars down to V = 16.5 mag from photometry in the Vilnius seven-color system published in Paper I (2008). The investigated area is divided into five smaller subareas with slightly different dependence of the extinction on distance. The distribution of reddened stars is in accordance with the presence of two dust clouds at 282 pc and 715 pc, however in some directions the dust distribution can be continuous or more clouds can be present.

Molecular gas excitation in Kleinmann-Low nebula

NASA Astrophysics Data System (ADS)

Callejo, Gonzague; Lemaire, Jean-Louis; Le Petit, F.; Pineau Des Forets, Guillaume; Field, David

2004-12-01

The Orion molecular cloud OMC-1 is the perfect object for the study of the dense interstellar medium accounting for active star formation; the intrinsic complexity of this region serves as a stallion, both for observing techniques and for interstellar medium modelling. A detailed dynamic and spectroscopic study has been performed using VLT and CFHT observations of the infrared Kleinmann-Low nebula; yielding a complete small-scale structure in velocity and most importantly powerful diagnosis tools in order to put a new light into the gas behaviour. These results allow to build up a consistent model of the gas excitation, and a clear dynamical view of the region. The crucial action of the shock waves is confirmed, and the discrepancies between the observations and the standard models are discussed. The consequences of this modelling will be discussed in terms of extinction, magnetic field, and other quantities related to induced star formation. The goodness of the models used for the interpretations will be also discussed and some future directions of investigation enhanced.

HI-to-H2 Transitions in the Perseus Molecular Cloud

NASA Astrophysics Data System (ADS)

Bialy, Shmuel; Sternberg, Amiel; Lee, Min-Young; Le Petit, Franck; Roueff, Evelyne

2015-08-01

We use the Sternberg et al. theory for interstellar atomic to molecular hydrogen (H i-to-H2) conversion to analyze H i-to-H2 transitions in five (low-mass) star-forming and dark regions in the Perseus molecular cloud, B1, B1E, B5, IC348, and NGC1333. The observed H i mass surface densities of 6.3-9.2 {M}⊙ {{pc}}-2 are consistent with H i-to-H2 transitions dominated by H i-dust shielding in predominantly atomic envelopes. For each source, we constrain the dimensionless parameter α G, and the ratio {I}{UV}/n, of the FUV intensity to hydrogen gas density. We find α G values from 5.0 to 26.1, implying characteristic atomic hydrogen densities 11.8-1.8 cm-3, for {I}{UV}≈ 1 appropriate for Perseus. Our analysis implies that the dusty H i shielding layers are probably multiphased, with thermally unstable UNM gas in addition to cold CNM within the 21 cm kinematic radius.

Gas Phase Spectroscopy of Cold PAH Ions: Contribution to the Interstellar Extinction and the Diffuse Interstellar Bands

NASA Technical Reports Server (NTRS)

Biennier, L.; Salama, F.; Allamandola, L. J.; Scherer, J. J.; OKeefe, A.

2002-01-01

Polycyclic Aromatic Hydrocarbon molecules (PAHs) are ubiquitous in the interstellar medium (ISM) and constitute the building blocks of interstellar dust grains. Despite their inferred important role in mediating the energetic and chemical processes in thc ISM, their exact contribution to the interstellar extinction, and in particular to the diffuse interstellar bands (DIBs) remains unclear. The DIBs are spectral absorption features observed in the line of sight of stars that are obscured by diffuse interstellar clouds. More than 200 bands have been reported to date spanning from the near UV to the near IR with bandwidths ranging from 0.4 to 40 Angstroms (Tielens & Snow 1995). The present consensus is that the DIBs arise from free flying, gas-phase, organic molecules and/or ions that are abundant under the typical conditions reigning in the diffuse ISM. PAHs have been proposed as possible carriers (Allamandola et al. 1985; Leger & DHendecourt 1985). The PAH hypothesis is consistent with the cosmic abundance of Carbon and Hydrogen and with the required photostability of the DIB carriers against the strong VUV radiation field in the diffuse interstellar clouds. A significant fraction of PAHs is expected to be ionized in the diffuse ISM.

A rigorous detection of interstellar CH3NCO: An important missing species in astrochemical networks.

PubMed

Cernicharo, J; Kisiel, Z; Tercero, B; Kolesniková, L; Medvedev, I R; López, A; Fortman, S; Winnewisser, M; de Lucia, F C; Alonso, J L; Guillemin, J-C

2016-03-01

The recent analysis of the composition of the frozen surface of comet 67P/Churyumov-Gerasimenko has revealed a significant number of complex organic molecules. Methyl isocyanate (CH 3 NCO) is one of the more abundant species detected on the comet surface. In this work we report extensive characterization of its rotational spectrum resulting in a list of 1269 confidently assigned laboratory lines and its detection in space towards the Orion clouds where 399 lines of the molecule have been unambiguously identified. We find that the limited mm-wave laboratory data reported prior to our work require some revision. The abundance of CH 3 NCO in Orion is only a factor of ten below those of HNCO and CH 3 CN. Unlike the molecular abundances in the coma of comets, which correlate with those of warm molecular clouds, molecular abundances in the gas phase in Orion are only weakly correlated with those measured on the comet surface. We also compare our abundances with those derived recently for this molecule towards Sgr B2 (Halfen et al. 2015). A more accurate abundance of CH 3 NCO is provided for this cloud based on our extensive laboratory work.

A rigorous detection of interstellar CH3NCO: An important missing species in astrochemical networks⋆,⋆⋆

PubMed Central

Cernicharo, J.; Kisiel, Z.; Tercero, B.; Kolesniková, L.; Medvedev, I.R.; López, A.; Fortman, S.; Winnewisser, M.; de Lucia, F. C.; Alonso, J. L.; Guillemin, J.-C.

2016-01-01

The recent analysis of the composition of the frozen surface of comet 67P/Churyumov-Gerasimenko has revealed a significant number of complex organic molecules. Methyl isocyanate (CH3NCO) is one of the more abundant species detected on the comet surface. In this work we report extensive characterization of its rotational spectrum resulting in a list of 1269 confidently assigned laboratory lines and its detection in space towards the Orion clouds where 399 lines of the molecule have been unambiguously identified. We find that the limited mm-wave laboratory data reported prior to our work require some revision. The abundance of CH3NCO in Orion is only a factor of ten below those of HNCO and CH3CN. Unlike the molecular abundances in the coma of comets, which correlate with those of warm molecular clouds, molecular abundances in the gas phase in Orion are only weakly correlated with those measured on the comet surface. We also compare our abundances with those derived recently for this molecule towards Sgr B2 (Halfen et al. 2015). A more accurate abundance of CH3NCO is provided for this cloud based on our extensive laboratory work. PMID:27274565

The Effects of Grain Size and Temperature Distributions on the Formation of Interstellar Ice Mantles

NASA Astrophysics Data System (ADS)

Pauly, Tyler; Garrod, Robin T.

2016-02-01

Computational models of interstellar gas-grain chemistry have historically adopted a single dust-grain size of 0.1 micron, assumed to be representative of the size distribution present in the interstellar medium. Here, we investigate the effects of a broad grain-size distribution on the chemistry of dust-grain surfaces and the subsequent build-up of molecular ices on the grains, using a three-phase gas-grain chemical model of a quiescent dark cloud. We include an explicit treatment of the grain temperatures, governed both by the visual extinction of the cloud and the size of each individual grain-size population. We find that the temperature difference plays a significant role in determining the total bulk ice composition across the grain-size distribution, while the effects of geometrical differences between size populations appear marginal. We also consider collapse from a diffuse to a dark cloud, allowing dust temperatures to fall. Under the initial diffuse conditions, small grains are too warm to promote grain-mantle build-up, with most ices forming on the mid-sized grains. As collapse proceeds, the more abundant, smallest grains cool and become the dominant ice carriers; the large population of small grains means that this ice is distributed across many grains, with perhaps no more than 40 monolayers of ice each (versus several hundred assuming a single grain size). This effect may be important for the subsequent processing and desorption of the ice during the hot-core phase of star formation, exposing a significant proportion of the ice to the gas phase, increasing the importance of ice-surface chemistry and surface-gas interactions.

The Formation of N- and O-Heterocycles from the Irradiation of Benzene and Naphthalene in H2O/NH3- Containing Ices

NASA Technical Reports Server (NTRS)

Sandford, S. A.; Materese, C. K.; Nuevo, M.

2015-01-01

Aromatic hydrocarbons are an important class of molecules for both astrochemistry and astrobiology (Fig. 1). Within this class of molecules, polycyclic aromatic hydrocarbons (PAHs) are known to be ubiquitous in many astrophysical environments, and are likely present in interstellar clouds and protostellar disks. In dense clouds, PAHs are expected to condense onto grains as part of mixed molecular ice mantles dominated by small molecules like H2O,CH3OH, NH3, CO, and CO2. These ices are exposed to ionizing radiation in the form of cosmic rays and ambient high-energy X-ray and UV photons.

Search for water and life's building blocks in the Universe: An Introduction

NASA Astrophysics Data System (ADS)

Kwok, Sun

Water and organics are commonly believed to be the essential ingredients for life on Earth. The development of infrared and submillimeter observational techniques has resulted in the detection of water in circumstellar envelopes, interstellar clouds, comets, asteroids, planetary satellites and the Sun. Complex organics have also been found in stellar ejecta, diffuse and molecular clouds, meteorites, interplanetary dust particles, comets and planetary satellites. In this Focus Meeting, we will discuss the origin, distribution, and detection of water and other life's building blocks both inside and outside of the Solar System. The possibility of extraterrestrial organics and water on the origin of life on Earth will also be discussed.

Diffuse Interstellar Bands. A Survey of Observational Facts

NASA Astrophysics Data System (ADS)

Krełowski, J.

2018-07-01

The paper presents and documents the most important observational results concerning the enigmatic diffuse interstellar bands (DIBs) that have remained unidentified since 1922. It demonstrates why the bands are commonly considered as having originated in many still unknown carriers. The mutual correlations of different DIBs, aiming at finding “families” of common origin, are briefly discussed. It was found that the strength ratio of the major DIBs, 5780 and 5797, is heavily variable; at the same E(B‑V), the DIB intensities may vary by as much as a factor of three or more. Certain DIB strength ratios seem to be related to intensities of the known features of simple molecular species; this led to the introduction of the so-called σ and ζ type interstellar clouds. In the former (prototype HD147165), broad DIBs are very strong, while the narrow ones and molecular features are weak. In the latter (prototype HD149757), narrow DIBs, as well as bands of simple radicals, are strong while the broad DIBs are weak (in relation to E(B‑V)). Details of the profiles of narrow DIBs, documenting their molecular origin, are presented. The relative DIB strengths as well as those of the simple radicals seem to be related to the shapes of interstellar extinction curves. Possible carriers of DIBs are only mentioned, as all of the proposed ones remain uncertain. The survey is biased in the sense that it presents the author’s point of view. It was prepared for the thirtieth anniversary of the first DIB survey, published in PASP (Krełowski 1988), and demonstrates how far our knowledge has evolved since then.

ULTRAVIOLET ESCAPE FRACTIONS FROM GIANT MOLECULAR CLOUDS DURING EARLY CLUSTER FORMATION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Howard, Corey; Pudritz, Ralph; Klessen, Ralf

2017-01-01

The UV photon escape fraction from molecular clouds is a key parameter for understanding the ionization of the interstellar medium and extragalactic processes such as cosmic reionization. We present the ionizing photon flux and the corresponding photon escape fraction ( f {sub esc}) arising as a consequence of star cluster formation in a turbulent, 10{sup 6} M {sub ⊙} giant molecular cloud, simulated using the code FLASH. We make use of sink particles to represent young, star-forming clusters coupled with a radiative transfer scheme to calculate the emergent UV flux. We find that the ionizing photon flux across the cloudmore » boundary is highly variable in time and space due to the turbulent nature of the intervening gas. The escaping photon fraction remains at ∼5% for the first 2.5 Myr, followed by two pronounced peaks at 3.25 and 3.8 Myr with a maximum f {sub esc} of 30% and 37%, respectively. These peaks are due to the formation of large H ii regions that expand into regions of lower density, some of which reaching the cloud surface. However, these phases are short-lived, and f {sub esc} drops sharply as the H ii regions are quenched by the central cluster passing through high-density material due to the turbulent nature of the cloud. We find an average f {sub esc} of 15% with factor of two variations over 1 Myr timescales. Our results suggest that assuming a single value for f {sub esc} from a molecular cloud is in general a poor approximation, and that the dynamical evolution of the system leads to large temporal variation.« less

Linear proportional relationship between N(OH) and N(CH) in the diffuse interstellar medium

NASA Astrophysics Data System (ADS)

Hong, Seung Yeong; Kwak, Kyujin

2018-04-01

It has been known that there is a linearly proportional relationship between the column densities of CH and OH measured toward bright UV-emitting stars, although there are four outliers in this relationship among the total 24 measured targets. By using the Simbad database, we investigate reasonable configurations of diffuse interstellar medium (ISM) which could explain the observed relationship. We first identify the locations of 24 targets on the celestial sphere getting the distances to them and then count the number of molecular clouds, nebulae, and peculiar stars toward the targets which could contribute to the production of OH and CH. We present the results of our search by testing three hypothetical configurations of diffuse ISM which may explain the observed relationship.

Evolution of Morphological and Physical Properties of Laboratory Interstellar Organic Residues with Ultraviolet Irradiation

NASA Astrophysics Data System (ADS)

Piani, L.; Tachibana, S.; Hama, T.; Tanaka, H.; Endo, Y.; Sugawara, I.; Dessimoulie, L.; Kimura, Y.; Miyake, A.; Matsuno, J.; Tsuchiyama, A.; Fujita, K.; Nakatsubo, S.; Fukushi, H.; Mori, S.; Chigai, T.; Yurimoto, H.; Kouchi, A.

2017-03-01

Refractory organic compounds formed in molecular clouds are among the building blocks of the solar system objects and could be the precursors of organic matter found in primitive meteorites and cometary materials. However, little is known about the evolutionary pathways of molecular cloud organics from dense molecular clouds to planetary systems. In this study, we focus on the evolution of the morphological and viscoelastic properties of molecular cloud refractory organic matter. We found that the organic residue, experimentally synthesized at ˜10 K from UV-irradiated H2O-CH3OH-NH3 ice, changed significantly in terms of its nanometer- to micrometer-scale morphology and viscoelastic properties after UV irradiation at room temperature. The dose of this irradiation was equivalent to that experienced after short residence in diffuse clouds (≤104 years) or irradiation in outer protoplanetary disks. The irradiated organic residues became highly porous and more rigid and formed amorphous nanospherules. These nanospherules are morphologically similar to organic nanoglobules observed in the least-altered chondrites, chondritic porous interplanetary dust particles, and cometary samples, suggesting that irradiation of refractory organics could be a possible formation pathway for such nanoglobules. The storage modulus (elasticity) of photo-irradiated organic residues is ˜100 MPa irrespective of vibrational frequency, a value that is lower than the storage moduli of minerals and ice. Dust grains coated with such irradiated organics would therefore stick together efficiently, but growth to larger grains might be suppressed due to an increase in aggregate brittleness caused by the strong connections between grains.

Evolution of Morphological and Physical Properties of Laboratory Interstellar Organic Residues with Ultraviolet Irradiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Piani, L.; Tachibana, S.; Endo, Y.

Refractory organic compounds formed in molecular clouds are among the building blocks of the solar system objects and could be the precursors of organic matter found in primitive meteorites and cometary materials. However, little is known about the evolutionary pathways of molecular cloud organics from dense molecular clouds to planetary systems. In this study, we focus on the evolution of the morphological and viscoelastic properties of molecular cloud refractory organic matter. We found that the organic residue, experimentally synthesized at ∼10 K from UV-irradiated H{sub 2}O-CH{sub 3}OH-NH{sub 3} ice, changed significantly in terms of its nanometer- to micrometer-scale morphology andmore » viscoelastic properties after UV irradiation at room temperature. The dose of this irradiation was equivalent to that experienced after short residence in diffuse clouds (≤10{sup 4} years) or irradiation in outer protoplanetary disks. The irradiated organic residues became highly porous and more rigid and formed amorphous nanospherules. These nanospherules are morphologically similar to organic nanoglobules observed in the least-altered chondrites, chondritic porous interplanetary dust particles, and cometary samples, suggesting that irradiation of refractory organics could be a possible formation pathway for such nanoglobules. The storage modulus (elasticity) of photo-irradiated organic residues is ∼100 MPa irrespective of vibrational frequency, a value that is lower than the storage moduli of minerals and ice. Dust grains coated with such irradiated organics would therefore stick together efficiently, but growth to larger grains might be suppressed due to an increase in aggregate brittleness caused by the strong connections between grains.« less

A Free-Radical Pathway to Hydrogenated Phenanthrene in Molecular Clouds-Low Temperature Growth of Polycyclic Aromatic Hydrocarbons.

PubMed

Thomas, Aaron M; Lucas, Michael; Yang, Tao; Kaiser, Ralf I; Fuentes, Luis; Belisario-Lara, Daniel; Mebel, Alexander M

2017-08-05

The hydrogen-abstraction/acetylene-addition mechanism has been fundamental to unravelling the synthesis of polycyclic aromatic hydrocarbons (PAHs) detected in combustion flames and carbonaceous meteorites like Orgueil and Murchison. However, the fundamental reaction pathways accounting for the synthesis of complex PAHs, such as the tricyclic anthracene and phenanthrene along with their dihydrogenated counterparts, remain elusive to date. By investigating the hitherto unknown chemistry of the 1-naphthyl radical with 1,3-butadiene, we reveal a facile barrierless synthesis of dihydrophenanthrene adaptable to low temperatures. These aryl-type radical additions to conjugated hydrocarbons via resonantly stabilized free-radical intermediates defy conventional wisdom that PAH growth is predominantly a high-temperature phenomenon and thus may represent an overlooked path to PAHs as complex as coronene and corannulene in cold regions of the interstellar medium like in the Taurus Molecular Cloud. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Discovery of very-high-energy gamma-rays from the Galactic Centre ridge.

PubMed

Aharonian, F; Akhperjanian, A G; Bazer-Bachi, A R; Beilicke, M; Benbow, W; Berge, D; Bernlöhr, K; Boisson, C; Bolz, O; Borrel, V; Braun, I; Breitling, F; Brown, A M; Chadwick, P M; Chounet, L-M; Cornils, R; Costamante, L; Degrange, B; Dickinson, H J; Djannati-Ataï, A; Drury, L O'C; Dubus, G; Emmanoulopoulos, D; Espigat, P; Feinstein, F; Fontaine, G; Fuchs, Y; Funk, S; Gallant, Y A; Giebels, B; Gillessen, S; Glicenstein, J F; Goret, P; Hadjichristidis, C; Hauser, D; Hauser, M; Heinzelmann, G; Henri, G; Hermann, G; Hinton, J A; Hofmann, W; Holleran, M; Horns, D; Jacholkowska, A; de Jager, O C; Khélifi, B; Klages, S; Komin, Nu; Konopelko, A; Latham, I J; Le Gallou, R; Lemière, A; Lemoine-Goumard, M; Leroy, N; Lohse, T; Marcowith, A; Martin, J M; Martineau-Huynh, O; Masterson, C; McComb, T J L; de Naurois, M; Nolan, S J; Noutsos, A; Orford, K J; Osborne, J L; Ouchrif, M; Panter, M; Pelletier, G; Pita, S; Pühlhofer, G; Punch, M; Raubenheimer, B C; Raue, M; Raux, J; Rayner, S M; Reimer, A; Reimer, O; Ripken, J; Rob, L; Rolland, L; Rowell, G; Sahakian, V; Saugé, L; Schlenker, S; Schlickeiser, R; Schuster, C; Schwanke, U; Siewert, M; Sol, H; Spangler, D; Steenkamp, R; Stegmann, C; Tavernet, J-P; Terrier, R; Théoret, C G; Tluczykont, M; van Eldik, C; Vasileiadis, G; Venter, C; Vincent, P; Völk, H J; Wagner, S J

2006-02-09

The source of Galactic cosmic rays (with energies up to 10(15) eV) remains unclear, although it is widely believed that they originate in the shock waves of expanding supernova remnants. At present the best way to investigate their acceleration and propagation is by observing the gamma-rays produced when cosmic rays interact with interstellar gas. Here we report observations of an extended region of very-high-energy (> 10(11) eV) gamma-ray emission correlated spatially with a complex of giant molecular clouds in the central 200 parsecs of the Milky Way. The hardness of the gamma-ray spectrum and the conditions in those molecular clouds indicate that the cosmic rays giving rise to the gamma-rays are likely to be protons and nuclei rather than electrons. The energy associated with the cosmic rays could have come from a single supernova explosion around 10(4) years ago.

Hydrogen isotopic substitution of solid methylamine through atomic surface reactions at low temperatures: A potential contribution to the D/H ratio of methylamine in molecular clouds

NASA Astrophysics Data System (ADS)

Oba, Yasuhiro; Chigai, Takeshi; Osamura, Yoshihiro; Watanabe, Naoki; Kouchi, Akira

2014-01-01

We experimentally studied hydrogen (H)-deuterium (D) substitution reactions of solid methylamine (CH3NH2) under astrophysically relevant conditions. We also calculated the potential energy surface for the H-D substitution reactions of methylamine isotopologues using quantum chemical methods. Despite the relatively large energy barrier of more than 18 kJ mol-1, CH3NH2 reacted with D atoms to yield deuterated methylamines at 10 K, suggesting that the H-D substitution reaction proceeds through quantum tunneling. Deuterated methylamines reacted with H atoms as well. On the basis of present results, we propose that methylamine has potential for D enrichment through atomic surface reactions on interstellar grains at very low temperatures in molecular clouds. D enrichment would occur in particular in the methyl group of methylamine.

A survey of the molecular ISM properties of nearby galaxies using the Herschel FTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kamenetzky, J.; Rangwala, N.; Glenn, J.

2014-11-10

The {sup 12}CO J = 4 → 3 to J = 13 → 12 lines of the interstellar medium from nearby galaxies, newly observable with the Herschel SPIRE Fourier transform spectrometer, offer an opportunity to study warmer, more luminous molecular gas than that traced by {sup 12}CO J = 1 → 0. Here we present a survey of 17 nearby infrared-luminous galaxy systems (21 pointings). In addition to photometric modeling of dust, we modeled full {sup 12}CO spectral line energy distributions from J = 1 → 0 to J = 13 → 12 with two components of warm and coolmore » CO gas, and included LTE analysis of [C I], [C II], [N II], and H{sub 2} lines. CO is emitted from a low-pressure/high-mass component traced by the low-J lines and a high-pressure/low-mass component that dominates the luminosity. We found that, on average, the ratios of the warm/cool pressure, mass, and {sup 12}CO luminosity are 60 ± 30, 0.11 ± 0.02, and 15.6 ± 2.7. The gas-to-dust-mass ratios are <120 throughout the sample. The {sup 12}CO luminosity is dominated by the high-J lines and is 4 × 10{sup –4} L {sub FIR} on average. We discuss systematic effects of single-component and multi-component CO modeling (e.g., single-component J ≤ 3 models overestimate gas pressure by ∼0.5 dex), as well as compare to Galactic star-forming regions. With this comparison, we show the molecular interstellar medium of starburst galaxies is not simply an ensemble of Galactic-type giant molecular clouds. The warm gas emission is likely dominated by regions resembling the warm extended cloud of Sgr B2.« less

Self-assembling amphiphilic molecules: Synthesis in simulated interstellar/precometary ices

PubMed Central

Dworkin, Jason P.; Deamer, David W.; Sandford, Scott A.; Allamandola, Louis J.

2001-01-01

Interstellar gas and dust constitute the primary material from which the solar system formed. Near the end of the hot early phase of star and planet formation, volatile, less refractory materials were transported into the inner solar system as comets and interplanetary dust particles. Once the inner planets had sufficiently cooled, late accretionary infall seeded them with complex organic compounds [Oró, J. (1961) Nature (London) 190, 389–390; Delsemme, A. H. (1984) Origins Life 14, 51–60; Anders, E. (1989) Nature (London) 342, 255–257; Chyba, C. F. & Sagan, C. (1992) Nature (London) 355, 125–131]. Delivery of such extraterrestrial compounds may have contributed to the organic inventory necessary for the origin of life. Interstellar ices, the building blocks of comets, tie up a large fraction of the biogenic elements available in molecular clouds. In our efforts to understand their synthesis, chemical composition, and physical properties, we report here that a complex mixture of molecules is produced by UV photolysis of realistic, interstellar ice analogs, and that some of the components have properties relevant to the origin of life, including the ability to self-assemble into vesicular structures. PMID:11158552

The Bending Vibrations of the C_3-ISOTOPOLOGUES in the 1.9 Terahertz Region

NASA Astrophysics Data System (ADS)

Breier, A.; Büchling, Thomas; Lutter, Volker; Schnierer, Rico; Fuchs, Guido W.; Giesen, Thomas

2016-06-01

Short carbon chains are fundamental for the chemistry of stellar and interstellar ambiences. The linear carbon chain molecule C_3 has been found in various interstellar and circumstellar environments, encompassing diffuse interstellar clouds, star forming regions, shells of late type stars, as well as cometary tails. Due to the lack of a permanent dipole moment C_3 can only be detected by electronic transitions in the visible spectral range or by vibrational bands in the mid-and far-infrared region. We performed experiments where C_3 was produced via laser-ablation of a graphite rod with a 3 bar He purge and a subsequent adiabatic expansion into a vaccum resulting in a supersonic jet. We report laboratory measurements of the lowest bending mode transitions of six 13C-isotopologues of the linear C_3 molecule. Fifty-eight transitions have been measured between 1.8-1.9 THz with an accuracy of better than 1 MHz. Molecular parameters have been derived to give accurate line frequency positions of all 13C isotopologues to ease their future interstellar detection. A dedicated observation for singly substituted 13CCC is projected within the SOFIA airborne observatory mission.

Identifying Organic Molecules in Space: The AstroBiology Explorer (ABE) Mission Concept

NASA Technical Reports Server (NTRS)

Ennico, K. A.; Sandford, S. A.; Allamandola, L.; Bregman, J.; Cohen, M.; Cruikshank, D.; Dumas, C.; Greene, T.; Hudgins, D.; Kwok, S.

2004-01-01

The AstroBiology Explorer (ABE) mission concept consists of a dedicated space observatory having a 60 cm class primary mirror cooled to T < 50 K equipped with medium resolution cross-dispersed spectrometers having cooled large format near- and mid-infrared detector arrays. Such a system would be capable of addressing outstanding problems in Astrochemistry and Astrophysics that are particularly relevant to Astrobiology and addressable via astronomical observation. The mission s observational program would make fundamental scientific progress in establishing the nature, distribution, formation and evolution of organic and other molecular materials in the following extra-terrestrial environments: 1) The Outflow of Dying Stars, 2) The Diffuse Interstellar Medium, 3) Dense Molecular Clouds, Star Formation Regions, and Young StellarPlanetary Systems, 4) Planets, Satellites, and Small Bodies within the Solar System, and 5 ) The Interstellar Media of Other Galaxies. ABE could make fundamental progress in all of these areas by conducting a 1 to 2 year mission to obtain a coordinated set of infrared spectroscopic observations over the 2.5-20 micron spectral range at a spectral resolution of R > 2000 of about 1500 objects including galaxies, stars, planetary nebulae, young stellar objects, and solar system objects. Keywords: Astrobiology, infrared, Explorers, interstellar organics, telescope, spectrometer, space, infrared detectors

The photodissociation and chemistry of CO isotopologues: applications to interstellar clouds and circumstellar disks

NASA Astrophysics Data System (ADS)

Visser, R.; van Dishoeck, E. F.; Black, J. H.

2009-08-01

Aims: Photodissociation by UV light is an important destruction mechanism for carbon monoxide (CO) in many astrophysical environments, ranging from interstellar clouds to protoplanetary disks. The aim of this work is to gain a better understanding of the depth dependence and isotope-selective nature of this process. Methods: We present a photodissociation model based on recent spectroscopic data from the literature, which allows us to compute depth-dependent and isotope-selective photodissociation rates at higher accuracy than in previous work. The model includes self-shielding, mutual shielding and shielding by atomic and molecular hydrogen, and it is the first such model to include the rare isotopologues C17O and 13C17O. We couple it to a simple chemical network to analyse CO abundances in diffuse and translucent clouds, photon-dominated regions, and circumstellar disks. Results: The photodissociation rate in the unattenuated interstellar radiation field is 2.6 × 10-10 s-1, 30% higher than currently adopted values. Increasing the excitation temperature or the Doppler width can reduce the photodissociation rates and the isotopic selectivity by as much as a factor of three for temperatures above 100 K. The model reproduces column densities observed towards diffuse clouds and PDRs, and it offers an explanation for both the enhanced and the reduced N(12CO)/N(13CO) ratios seen in diffuse clouds. The photodissociation of C17O and 13C17O shows almost exactly the same depth dependence as that of C18O and 13C18O, respectively, so 17O and 18O are equally fractionated with respect to 16O. This supports the recent hypothesis that CO photodissociation in the solar nebula is responsible for the anomalous 17O and 18O abundances in meteorites. Grain growth in circumstellar disks can enhance the N(12CO)/N(C17O) and N(12CO)/N(C18O) ratios by a factor of ten relative to the initial isotopic abundances. Tables [see full textsee full text]-[see full textsee full text] are only available in electronic form at http://www.aanda.org

Chemistry in Magnetohydrodynamic Shock Waves in Diffuse Molecular Clouds

NASA Astrophysics Data System (ADS)

Peimbert, Antonio

1998-09-01

Absorption observations of the CH+ molecule with column densities of up to 1014 cm-2 in diffuse molecular clouds in many lines of sight are reviewed, and compared to the reddening and to abundances and velocity shifts of molecules like CH. Special attention is placed on the observations of the line of sight towards ς Ophiuchi where high quality observations of many chemical species are available. The problem of the required CH+ is described, and many formation mechanisms from the literature are reviewed, finding that none of them is particularly apt at describing the observations towards ς-Oph. Two fluid J-type shock models are studied as an alternative. The necessary conditions for their formation are discussed, and it is shown how they are expected to be present widely in the interstellar medium. Plane parallel numerical integrations, for the particular case in which the magnetic field is perpendicular to the shock velocity, are employed to study the region of phase-space of initial conditions that will produce 2 fluid shocks. A chemical network is developed and formation of key molecules like CH+, CH and OH, along with the excited roto-vibrational levels of H2, are studied under the shock dynamics. These models are then compared to the observations of the different lines of sight, showing they are capable of reproducing the features of the observations towards most of those clouds. An attempt to model the line of sight towards ς-Oph is done, finding that a shock with a shock speed vs = 9.0km/s going through a cloud with a density of nH = 14cm-3 with a magnetic field of B = 4.7μG does a reasonable job at satisfying most of the observations with the exception of the highest rotational excited states of molecular hydrogen for which observations are available. There is a small family of solutions capable of explaining the observed results which make specific predictions for the velocity profiles of the H2 lines of various excited levels. New observations with the Interstellar Medium Absorption Profile Spectrograph (IMAPS) camera would be useful in confirming or rejecting these models.

Application of Stochastic and Deterministic Approaches to Modeling Interstellar Chemistry

NASA Astrophysics Data System (ADS)

Pei, Yezhe

This work is about simulations of interstellar chemistry using the deterministic rate equation (RE) method and the stochastic moment equation (ME) method. Primordial metal-poor interstellar medium (ISM) is of our interest and the socalled “Population-II” stars could have been formed in this environment during the “Epoch of Reionization” in the baby universe. We build a gas phase model using the RE scheme to describe the ionization-powered interstellar chemistry. We demonstrate that OH replaces CO as the most abundant metal-bearing molecule in such interstellar clouds of the early universe. Grain surface reactions play an important role in the studies of astrochemistry. But the lack of an accurate yet effective simulation method still presents a challenge, especially for large, practical gas-grain system. We develop a hybrid scheme of moment equations and rate equations (HMR) for large gas-grain network to model astrochemical reactions in the interstellar clouds. Specifically, we have used a large chemical gas-grain model, with stochastic moment equations to treat the surface chemistry and deterministic rate equations to treat the gas phase chemistry, to simulate astrochemical systems as of the ISM in the Milky Way, the Large Magellanic Cloud (LMC) and Small Magellanic Cloud (SMC). We compare the results to those of pure rate equations and modified rate equations and present a discussion about how moment equations improve our theoretical modeling and how the abundances of the assorted species are changed by varied metallicity. We also model the observed composition of H2O, CO and CO2 ices toward Young Stellar Objects in the LMC and show that the HMR method gives a better match to the observation than the pure RE method.

Laboratory investigation of the contribution of complex aromatic/aliphatic polycyclic hybrid molecular structures to interstellar ultraviolet extinction and infrared emission

NASA Technical Reports Server (NTRS)

Arnoult, K. M.; Wdowiak, T. J.; Beegle, L. W.

2000-01-01

We have demonstrated by experiment that, in an energetic environment, a simple polycyclic aromatic hydrocarbon (PAH) such as naphthalene will undergo chemical reactions that produce a wide array of more complex species (an aggregate). For a stellar wind of a highly evolved star (post-asymptotic giant branch [post-AGB]), this process would be in addition to what is expected from reactions occurring under thermodynamic equilibrium. A surprising result of that work was that produced in substantial abundance are hydrogenated forms that are hybrids of polycyclic aromatic and polycyclic alkanes. Infrared spectroscopy described here reveals a spectral character for these materials that has much in common with that observed for the constituents of circumstellar clouds of post-AGB stars. It can be demonstrated that a methylene (-CH2-) substructure, as in cycloalkanes, is the likely carrier of the 6.9 microns band emission of dust that has recently been formed around IRAS 22272+5433, NGC 7027, and CPD -56 8032. Ultraviolet spectroscopy previously done with a lower limit of 190 nm had revealed that this molecular aggregate can contribute to the interstellar extinction feature at 2175 angstroms. We have now extended our UV spectroscopy of these materials to 110 nm by a vacuum ultraviolet technique. That work, described here, reveals new spectral characteristics and describes how material newly formed during the late stages of stellar evolution could have produced an extinction feature claimed to exist at 1700 angstroms in the spectrum of HD 145502 and also how the newly formed hydrocarbon material would be transformed/aged in the general interstellar environment. The contribution of this molecular aggregate to the rise in interstellar extinction at wavelengths below 1500 angstroms is also examined. The panspectral measurements of the materials produced in the laboratory, using plasmas of H, He, N, and O to convert the simple PAH naphthalene to an aggregate of complex species, provide insight into possible molecular structure details of newly formed hydrocarbon-rich interstellar dust and its transformation into aged material that becomes resident in the interstellar medium. Specifically the presence of naphthalene-like and butadiene-like conjugated structures as chromophores for the 2175 angstroms ultraviolet extinction feature is indicated.

Observations of the interstellar gas with the Copernicus satellite

NASA Technical Reports Server (NTRS)

Morton, D. C.

1975-01-01

Results are reviewed for Copernicus far-UV measurements of the absorption lines of H I, D I, H2, and heavier elements in the interstellar gas. Column densities along several lines of sight, as estimated from Ly-alpha absorption-line profiles, confirm that wide differences in the gas density are present in various directions. The measurement of interstellar D I implies an open universe unless alternate sources for this nuclide are found. Analysis of reddened stars for which the line of sight passes through one or more interstellar clouds indicates a depletion of several heavy elements in the gas. It is suggested that the depleted elements may be present in grains rather than molecules and that the intercloud medium may consist primarily of H II with a few small H I clouds.

The ratio of molecular to atomic gas in spiral galaxies as a function of morphological type

NASA Technical Reports Server (NTRS)

Knezek, Patricia M.; Young, Judith S.

1990-01-01

In order to gain an understanding of the global processes which influence cloud and star formation in disk galaxies, it is necessary to determine the relative amounts of atomic, molecular, and ionized gas both as a function of position in galaxies and from galaxy to galaxy. With observations of the CO distributions in over 200 galaxies now completed as part of the Five College Radio Astronomy Observatory (FCRAO) Extragalactic CO Survey (Young et al. 1989), researchers are finally in a position to determine the type dependence of the molecular content of spiral galaxies, along with the ratio of molecular to atomic gas as a function of type. Do late type spirals really have more gas than early types when the molecular gas content is included. Researchers conclude that there is more than an order of magnitude decrease in the ratio of molecular to atomic gas mass as a function of morphological type from Sa-Sd; an average Sa galaxy has more molecular than atomic gas, and an average Sc has less. Therefore, the total interstellar gas mass to blue luminosity ratio, M sub gas/L sub B, increases by less than a factor of two as a function of type from Sa-Sd. The dominant effect found is that the phase of the gas in the cool interstellar medium (ISM) varies along the Hubble sequence. Researchers suggest that the more massive and centrally concentrated galaxies are able to achieve a molecular-dominated ISM through the collection of more gas in the potential. That gas may then form molecular clouds when a critical density is exceeded. The picture which these observations support is one in which the conversion of atomic gas to molecular gas is a global process which depends on large scale dynamics (cf Wyse 1986). Among interacting and merging systems, researchers find considerable scatter in the M(H2)/M(HI) ratio, with the mean ratio similar to that in the early type galaxies. The high global ratio of molecular to atomic gas could result from the removal of HI gas, the enhanced conversion of HI into H2, or both.

Extraterrestrial organic matter: a review

NASA Technical Reports Server (NTRS)

Irvine, W. M.

1998-01-01

We review the nature of the widespread organic material present in the Milky Way Galaxy and in the Solar System. Attention is given to the links between these environments and between primitive Solar System objects and the early Earth, indicating the preservation of organic material as an interstellar cloud collapsed to form the Solar System and as the Earth accreted such material from asteroids, comets and interplanetary dust particles. In the interstellar medium of the Milky Way Galaxy more than 100 molecular species, the bulk of them organic, have been securely identified, primarily through spectroscopy at the highest radio frequencies. There is considerable evidence for significantly heavier organic molecules, particularly polycyclic aromatics, although precise identification of individual species has not yet been obtained. The so-called diffuse interstellar bands are probably important in this context. The low temperature kinetics in interstellar clouds leads to very large isotopic fractionation, particularly for hydrogen, and this signature is present in organic components preserved in carbonaceous chondritic meteorites. Outer belt asteroids are the probable parent bodies of the carbonaceous chondrites, which may contain as much as 5% organic material, including a rich variety of amino acids, purines, pyrimidines, and other species of potential prebiotic interest. Richer in volatiles and hence less thermally processed are the comets, whose organic matter is abundant and poorly characterized. Cometary volatiles, observed after sublimation into the coma, include many species also present in the interstellar medium. There is evidence that most of the Earth's volatiles may have been supplied by a 'late' bombardment of comets and carbonaceous meteorites, scattered into the inner Solar System following the formation of the giant planets. How much in the way of intact organic molecules of potential prebiotic interest survived delivery to the Earth has become an increasingly debated topic over the last several years. The principal source for such intact organics was probably accretion of interplanetary dust particles of cometary origin.

Changes in the morphology of interstellar ice analogues after hydrogen atom exposure.

PubMed

Accolla, Mario; Congiu, Emanuele; Dulieu, François; Manicò, Giulio; Chaabouni, Henda; Matar, Elie; Mokrane, Hakima; Lemaire, Jean Louis; Pirronello, Valerio

2011-05-07

The morphology of water ice in the interstellar medium is still an open question. Although accretion of gaseous water could not be the only possible origin of the observed icy mantles covering dust grains in cold molecular clouds, it is well known that water accreted from the gas phase on surfaces kept at 10 K forms ice films that exhibit a very high porosity. It is also known that in the dark clouds H(2) formation occurs on the icy surface of dust grains and that part of the energy (4.48 eV) released when adsorbed atoms react to form H(2) is deposited in the ice. The experimental study described in the present work focuses on how relevant changes of the ice morphology result from atomic hydrogen exposure and subsequent recombination. Using the temperature-programmed desorption (TPD) technique and a method of inversion analysis of TPD spectra, we show that there is an exponential decrease in the porosity of the amorphous water ice sample following D-atom irradiation. This decrease is inversely proportional to the thickness of the ice and has a value of ϕ(0) = 2 × 10(16) D-atoms cm(-2) per layer of H(2)O. We also use a model which confirms that the binding sites on the porous ice are destroyed regardless of their energy depth, and that the reduction of the porosity corresponds in fact to a reduction of the effective area. This reduction appears to be compatible with the fraction of D(2) formation energy transferred to the porous ice network. Under interstellar conditions, this effect is likely to be efficient and, together with other compaction processes, provides a good argument to believe that interstellar ice is amorphous and non-porous. This journal is © the Owner Societies 2011

A Simple and Accurate Network for Hydrogen and Carbon Chemistry in the Interstellar Medium

NASA Astrophysics Data System (ADS)

Gong, Munan; Ostriker, Eve C.; Wolfire, Mark G.

2017-07-01

Chemistry plays an important role in the interstellar medium (ISM), regulating the heating and cooling of the gas and determining abundances of molecular species that trace gas properties in observations. Although solving the time-dependent equations is necessary for accurate abundances and temperature in the dynamic ISM, a full chemical network is too computationally expensive to incorporate into numerical simulations. In this paper, we propose a new simplified chemical network for hydrogen and carbon chemistry in the atomic and molecular ISM. We compare results from our chemical network in detail with results from a full photodissociation region (PDR) code, and also with the Nelson & Langer (NL99) network previously adopted in the simulation literature. We show that our chemical network gives similar results to the PDR code in the equilibrium abundances of all species over a wide range of densities, temperature, and metallicities, whereas the NL99 network shows significant disagreement. Applying our network to 1D models, we find that the CO-dominated regime delimits the coldest gas and that the corresponding temperature tracks the cosmic-ray ionization rate in molecular clouds. We provide a simple fit for the locus of CO-dominated regions as a function of gas density and column. We also compare with observations of diffuse and translucent clouds. We find that the CO, {{CH}}x, and {{OH}}x abundances are consistent with equilibrium predictions for densities n=100{--}1000 {{cm}}-3, but the predicted equilibrium C abundance is higher than that seen in observations, signaling the potential importance of non-equilibrium/dynamical effects.

Far Ultraviolet Spectroscopy of the Intergalactic and Interstellar Absorption Toward 3C 273

NASA Technical Reports Server (NTRS)

Sembach, Kenneth R.; Howk, J. Christopher; Savage, Blair D.; Shull, J. Michael; Oegerle, William R.; Fisher, Richard R. (Technical Monitor)

2001-01-01

We present Far Ultraviolet Spectroscopic Explorer observations of the molecular, neutral atomic, weakly ionized, and highly ionized components of the interstellar and intergalactic material toward the quasar 3C273. We identify Ly-beta absorption in eight of the known intergalactic Ly-alpha absorbers along the sight line with the rest-frame equivalent widths W(sub r)(Ly-alpha) > 50 micro-angstroms. Refined estimates of the H(I) column densities and Doppler parameters (b) of the clouds are presented. We find a range of b = 16-46 km/s. We detect multiple H(I) lines (Ly-beta - Ly-theta) in the 1590 km/s Virgo absorber and estimate logN(H(I)) = 15.85 +/- 0.10, ten times more H(I) than all of the other absorbers along the sight line combined. The Doppler width of this absorber, b = 16 km/s, implies T < 15,000 K. We detect O(VI) absorption at 1015 km/s at the 2-3(sigma) level that may be associated with hot, X-ray emitting gas in the Virgo Cluster. We detect weak C(III) and O(VI) absorption in the IGM at z=0.12007; this absorber is predominantly ionized and has N(H+)/N(H(I)) > 4000/Z, where Z is the metallicity. Strong Galactic interstellar O(VI) is present between -100 and +100 km/s with an additional high-velocity wing containing about 13% of the total O(VI) between +100 and +240 km/s. The Galactic O(VI), N(V), and C(IV) lines have similar shapes, with roughly constant ratios across the -100 to +100 km/s velocity range. The high velocity O(VI) wing is not detected in other species. Much of the interstellar high ion absorption probably occurs within a highly fragmented medium within the Loop IV remnant or in the outer cavity walls of the remnant. Multiple hot gas production mechanisms are required. The broad O(VI) absorption wing likely traces the expulsion of hot gas out of the Galactic disk into the halo. A flux limit of 5.4 x 10(epx -16) erg/sq cm/s on the amount of diffuse O(VI) emission present = 3.5' off the 3C273 sight line combined with the observed O(VI) column density toward 3C273, logN O(VI) = 14.73 +/- 0.04, implies n(sub e) < 0.02/cubic cm and P/k < 11,500/cubic cm for an assumed temperature of 3 x 10(exp 5) K. The elemental abundances in the neutral and weakly-ionized interstellar clouds are similar to those found for other halo clouds. The warm neutral and warm ionized clouds along the sight line have similar dust-phase abundances, implying that the properties of the dust grains in the two types of clouds are similar. Interstellar H2 absorption is present at positive velocities at a level of logN(H2) = 15.71, but is very weak at the velocities of the main column density concentration along the sight line observed in H(I) 21 cm emission.

Millimeter and submillimeter spectra of hot cores and diffuse clouds: comparing IRAM and Herschel spectra with CASSIS simulations.

NASA Astrophysics Data System (ADS)

de Luca, Massimo

The primary goal of the PRISMAS Herschel key program is the spectroscopic study of key molecular lines towards bright Galactic star-forming regions and the diffuse interstellar clouds distributed along the lines of sight. Models of the source emission and absorption spectra have been constructed with CASSIS, based on 1) observational evidence in comparable environments, 2) warm-up chemical models with gas-grain networks, and 3) ground-based spectra of various molecules in the target sources obtained at the IRAM 30m telescope. These models include contributions from the hot core, its parental molecular cloud and the foreground diffuse inter-stellar matter. The considerable complexity of the hot core chemistry, together with the huge amount of information buried in the spectra, often prevents a straightforward interpretation of the data without the help simulations. This is particularly true for the largely unexplored wavelength range of HIFI. In this contribution, we compare HIFI and IRAM observations to our models, in order to either consolidate present day assumptions and knowledge of these environments, or to highlight the model limitations, poorly understood physical and chemical conditions or unexpected abundances. We pay particular attention to the ground state tran-sitions of the most important hydrides, which the PRISMAS program has been designed for, though the HIFI spectra are expected to be rich in other molecules as well. List of Authors De Luca, M., Observatoire de Paris, Ecole Normale Supérieure and CNRS, FRANCE; Bell, T., CalTech, UNITED STATES; Coutens, A., CESR, FRANCE; Godard, B., IAS, FRANCE; Gupta, H., JPL, UNITED STATES; Mook-erjea, B., Tata Institute for Fundamental Research, INDIA; and the PRISMAS consortium, PRISMAS, FRANCE

Interstellar and Solar Nebula Materials in Cometary Dust

NASA Technical Reports Server (NTRS)

Messenger, Scott; Nakamura-Messenger, Keiko; Keller, Lindsay; Nguyen, Ann; Clemett, Simon

2017-01-01

Laboratory studies of cometary dust collected in the stratosphere and returned from comet 81P/Wild 2 by the Stardust spacecraft have revealed ancient interstellar grains and molecular cloud organic matter that record a range of astrophysical processes and the first steps of planetary formation. Presolar materials are rarer meteorites owing to high temperature processing in the solar nebula and hydrothermal alteration on their asteroidal parent bodies. The greater preservation of presolar materials in comets is attributed to their low accretion temperatures and limited planetary processing. Yet, comets also contain a large complement of high temperature materials from the inner Solar System. Owing to the limited and biased sampling of comets to date, the proportions of interstellar and Solar System materials within them remains highly uncertain. Interstellar materials are identified by coordinated isotopic, mineralogical, and chemical measurements at the scale of individual grains. Chondritic porous interplanetary dust particles (CP IDPs) that likely derive from comets are made up of 0.1 - 10 micron-sized silicates, Fe-Ni-sulfides, oxides, and other phases bound by organic material. As much as 1% of the silicates are interstellar grains that have exotic isotopic compositions imparted by nucleosynthetic processes in their parent stars. Crystalline silicates in CP IDPs dominantly have normal isotopic compositions and probably formed in the Solar System. 81P samples include isotopically normal refractory minerals that resemble Ca-Al rich inclusions and chondrules common in meteorites. The origins of sub-micron amorphous silicates in IDPs are not certain, but at least a few % of them are interstellar grains. The remainder have isotopic compositions consistent with Solar System origins and elemental compositions that are inconsistent with interstellar grain properties, thus favoring formation in the solar nebula [4]. The organic component in comets and primitive meteorites has large enrichments in D/H and N-15/N-14 relative to terrestrial materials. These isotopic signatures are probably due to low temperature chemical processes in cold molecular clouds or the outermost reaches of the protoplanetary disk. The greatest isotopic anomalies are found in sub-micron organic nanoglobules that show chemical signatures of interstellar chemistry. The observation that cometary dust is mostly composed of isotopically normal minerals within isotopically anomalous organic matter is difficult to reconcile with the formation models of each component. The mineral component likely formed in high temperature processes in the inner Solar System, while the organic fraction shows isotopic and chemical signatures of formation near 10 K. Studying more primitive remnants of the Solar System starting materials would help in resolving this paradox. Comets formed across a vast expanse of the outer disk under differing thermal and collisional regimes, and some are likely to be better preserved than others. Finding truly pristine aggregates of presolar materials may require return of a pristine sample of comet nucleus material.

Theoretical studies in interstellar cloud chemistry

NASA Technical Reports Server (NTRS)

Chiu, Y. T.; Prasad, S. S.

1993-01-01

This final report represents the completion of the three tasks under the purchase order no. SCPDE5620,1,2F. Chemical composition of gravitationally contracting, but otherwise quiescent, interstellar clouds and of interstellar clouds traversed by high velocity shocks, were modeled in a comprehensive manner that represents a significant progress in modeling these objects. The evolutionary chemical modeling, done under this NASA contract, represents a notable advance over the 'classical' fixed condition equilibrium models because the evolutionary models consider not only the chemical processes but also the dynamical processes by which the dark interstellar clouds may have assumed their present state. The shock calculations, being reported here, are important because they extend the limited chemical composition derivable from dynamical calculations for the total density and temperature structures behind the shock front. In order to be tractable, the dynamical calculations must severely simplify the chemistry. The present shock calculations take the shock profiles from the dynamical calculations and derive chemical composition in a comprehensive manner. The results of the present modeling study are still to be analyzed with reference to astronomical observational data and other contemporary model predictions. As far as humanly possible, this analysis will be continued with CRE's (Creative Research Enterprises's) IR&D resources, until a sponsor is found.

Laboratory and observational study of the interrelation of the carbonaceous component of interstellar dust and solar system materials

NASA Technical Reports Server (NTRS)

Allamandola, L. J.; Sanford, S. A.; Schutte, W. A.; Tielens, A. G. G. M.

1991-01-01

By studying the chemical and isotopic composition of interstellar ice and dust, one gains insight into the composition and chemical evolution of the solid bodies in the solar nebula and the nature of the material subsequently brought into the inner part of the solar system by comets and meteorites. It is now possible to spectroscopically probe the composition of interstellar ice and dust in the mid-infrared, the spectral range which is most diagnostic of fundamental molecular vibrations. We can compare these spectra of various astronomical objects (including the diffuse and dense interstellar medium, comets, and the icy outer planets and their satellites) with the spectra of analogs we produce in the laboratory under conditions which mimic those in these different objects. In this way one can determine the composition and abundances of the major constituents of the various ices and place general constraints on the types of organics coating the grains in the diffuse interstellar medium. In particular we have shown the ices in the dense clouds contain H2O, CH3OH, CO, perhaps some NH3 and H2CO, we well as nitriles and ketones or esters. Furthermore, by studying the photochemistry of these ice analogs in the laboratory, one gains insight into the chemistry which takes place in interstellar/precometary ices. Chemical and spectroscopic studies of photolyzed analogs (including deuterated species) are now underway. The results of some of these studies will be presented and implications for the evolution of the biogenic elements in interstellar dust and comets will be discussed.

Diffuse interstellar clouds as a chemical laboratory - The chemistry of diatomic carbon species

NASA Technical Reports Server (NTRS)

Federman, S. R.; Huntress, W. T., Jr.

1989-01-01

The chemistry of C2, CH, and CO in diffuse interstellar clouds is analyzed and compared to absorption line measurements toward background stars. Analytical expressions in terms of column densities are derived for the rate equations. The results indicate that in clouds with 4 mag of visual extinction, the abundance of C+ has to decrease by a factor of about 15 from the value traditionally used for clouds with 1 mag of extinction. The rate coefficients for the reactions C+ + CH - C2+ + H and C+ + H2 - CH2+ + h-nu need to be reduced from previous estimates. Chemical arguments are presented for the revised rate coefficients.

Mass extinctions and missing matter

NASA Technical Reports Server (NTRS)

Stothers, R. B.

1984-01-01

The possible influence of 'invisible matter' on the solar system's comet halo, and therefore on quasi-periodic cometary bombardment of the earth and consequent mass extinctions, is briefly addressed. Invisible matter consisting of small or cold interstellar molecular clouds could significantly modulate the comet background flux, while invisible matter consisting of a large population of old, dead stars with a relatively small galactic concentration probably could not. It is also shown that the downward force exerted by the Galaxy will perturb the halo, but will not produce any periodicity.

Molecular complexes in close and far away

PubMed Central

Klemperer, William; Vaida, Veronica

2006-01-01

In this review, gas-phase chemistry of interstellar media and some planetary atmospheres is extended to include molecular complexes. Although the composition, density, and temperature of the environments discussed are very different, molecular complexes have recently been considered as potential contributors to chemistry. The complexes reviewed include strongly bound aggregates of molecules with ions, intermediate-strength hydrogen bonded complexes (primarily hydrates), and weakly bonded van der Waals molecules. In low-density, low-temperature environments characteristic of giant molecular clouds, molecular synthesis, known to involve gas-phase ion-molecule reactions and chemistry at the surface of dust and ice grains is extended here to involve molecular ionic clusters. At the high density and high temperatures found on planetary atmospheres, molecular complexes contribute to both atmospheric chemistry and climate. Using the observational, laboratory, and theoretical database, the role of molecular complexes in close and far away is discussed. PMID:16740667

The Origins of Polycyclic Aromatic Hydrocarbons: Are They Everywhere?

NASA Technical Reports Server (NTRS)

Allamandola, L. J.; Morrison, David (Technical Monitor)

1994-01-01

During the past 15 years considerable progress in observational techniques has been achieved in the middle-infrared region (5000-500 per centimeter, 2-20 micron), the region where most diagnostic molecular vibrations occur. Spectra of many different astronomical infrared sources, some deeply embedded in dark molecular clouds and others at their edges, are now available. These spectra provide a powerful probe, not only for the identification of interstellar molecules in both the gas and solid phases, but also of the physical and chemical conditions which prevail in these two very different domains. The two lectures will focus on the evidence that polycyclic aromatic hydrocarbons (PAHs) are an important, ubiquitous and abundant interstellar species. PAHs are. extremely stable species which can range in size from a few angstroms across to several hundred angstroms (PAHs are also the building blocks of amorphous carbon particles). This identification rests on the suggestive agreement between the laboratory spectra of PAHs with a set of IR emission bands which emanate from many different sources where ultraviolet starlight impinges on a "dusty" region. The picture is that individual PAHs are first pumped into highly vibrationally excited states and relax by fluorescence at their fundamental vibrational frequencies. That PAHs are a ubiquitous interstellar component has serious ramifications in other spectral regions as well, including the strong extinction in the ultraviolet, and the classic visible diffuse interstellar bands discovered more than 50 years ago (but unexplained to this day) The first part of the course will focus on the interpretation of astronomical spectra. The second lecture will start by showing how recent laboratory data on PAHs taken under realistic interstellar conditions has con borated the PAH hypothesis and led to great insight into the conditions in the PAH containing regions. This lecture will end by reviewing the ever-increasing evidence for interstellar PAHs in meteorites and interplanetary dust particles. This in conjunction with the recent suggestion that PAHs are abundant in Jupiter's atmosphere will make the point that "PAHs are Everywhere".

VizieR Online Data Catalog: 2mm molecular line survey of IRC+10 216 (Cernicharo+, 2000)

NASA Astrophysics Data System (ADS)

Cernicharo, J.; Guelin, M.; Kahane, C.

2000-01-01

The mm-wave spectrum of the C-star envelope IRC+10 216 has been continuously surveyed between 129.0 and 172.5GHz with the IRAM 30-m telescope. 380 lines are detected, of which 317 have been identified. The identified lines arise from 30 different molecules and radicals which, in their vast majority, are not observed in hot and dense interstellar clouds such as Orion A or W3(OH). Actually, half of the molecular species identified in the mm-wave spectrum of IRC+10216 were first observed in the course of this spectral survey. (9 data files).

Dynamics of the interstellar matter in galaxies : isolated barred spiral galaxies : cloud formation processes

NASA Astrophysics Data System (ADS)

Helmuth, Kristen

1998-12-01

The dynamical components of six isolated barred spiral (SB) galaxies are investigated. No evidence is found supporting the hypothesis of a low amount of dark matter being characteristic of SB galaxies. The presence of companion galaxies is found to correlate with an increased statistical spread in the neutral hydrogen (HI) extent. It is concluded that the selection of galaxies with large HI extent may introduce a bias towards tidally interacting systems. The circumnuclear region of the SB galaxy NGC 1365 is studied with the Hubble Space Telescope (HST). Numerous bright "super star clusters" (SSCs) are detected, surrounding the active nucleus. The bright compact radio source NGC 1365:A is found to coincide spatially with one of the SSCs. We conclude that the source is a "radio supernova". In the [OIII] l 5007 line, the HST resolves individual clouds within the conical outflow from the nucleus, some of which gather in larger agglomerations. An in-depth study of the dynamics of the SB galaxy NGC 1300 is presented. Multi-wavelength data yield an estimate of the velocity field and gravitational potential. Subsequent hydrodynamical simulations are able to reproduce the morphology and kinematics in the bar region using a pure bar perturbing potential. To reproduce the spiral structure a weak spiral component has to be added, indicative of stellar spiral response to the bar and/or self-gravitating gas in the arms. Two separate models, differing mainly with respect to pattern speed and associated resonance structure, are found to reproduce the observations. We study numerically the linear polarization and extinction of light from background stars passing through molecular clouds, illuminating the intricacies of the derivation of the magnetic-field-line pattern in a cloud from the observed polarization pattern: Due to a higher gas-grain collision frequency within the cloud, the polarization caused by the cloud may well be dominated by background/foreground polarization. Furthermore, variations in field-orientation along the line-of-sight may cause notable differences between the observed polarization vectors and the true magnetic-field-line pattern. Small-scale, helical, interstellar filaments are discussed on the basis of optical observations of an "elephant trunk" structure in the Rosette nebula. The observed sinusoidal filaments are suggested to be helices lined up by magnetic fields. We propose that the Rosette elephant trunks form an interconnected system of rope-like structures which are relics from filamentary skeletons of magnetic fields in the primordial cloud. Stochastic mass fractionation of a molecular cloud is simulated numerically. It is found that geometry alone may constrain the resulting mass spectrum of molecular cloud clumps. We demonstrate that further fragmentation of the cloud clumps, under the assumption of a lower limit of the self-similar regime, produces a mass spectrum that has qualitative and quantitative similarities with the empirically determined stellar initial mass function.

Velocity-resolved [{\\rm{C}}\\,{\\rm{II}}] Emission from Cold Diffuse Clouds in the Interstellar Medium

NASA Astrophysics Data System (ADS)

Goldsmith, Paul F.; Pineda, Jorge L.; Neufeld, David A.; Wolfire, Mark G.; Risacher, Christophe; Simon, Robert

2018-04-01

We have combined emission from the 158 μm fine structure transition of C+ observed with the GREAT and upGREAT instruments on SOFIA with 21 cm absorption spectra and visual extinction to characterize the diffuse interstellar clouds found along the lines of sight. The weak [C II] emission is consistent in velocity and line width with the strongest H I component produced by the cold neutral medium. The H I column density and kinetic temperature are known from the 21 cm data and, assuming a fractional abundance of ionized carbon, we calculate the volume density and thermal pressure of each source, which vary considerably, with 27 {cm}}-3≤slant n({{{H}}}0) ≤slant 210 cm‑3 considering only the atomic hydrogen along the lines of sight to be responsible for the C+, while 13 {cm}}-3≤slant n({{{H}}}0+{{{H}}}2)≤slant 190 cm‑3 including the hydrogen in both forms. The thermal pressure varies widely with 1970 cm‑3 K ≤slant {P}th}/k≤slant 10,440 cm‑3 K for H0 alone and 750 cm‑3 K ≤ P th/k ≤ 9360 cm‑3 K including both H0 and H2. The molecular hydrogen fraction varies between 0.10 and 0.67. Photoelectric heating is the dominant heating source, supplemented by a moderately enhanced cosmic ray ionization rate, constrained by the relatively low 45 K to 73 K gas temperatures of the clouds. The resulting thermal balance for the two lower-density clouds is satisfactory, but for the two higher-density clouds, the combined heating rate is insufficient to balance the observed C+ cooling.

Interstellar/Precometary Organic Material and the Photochemical Evolution of Complex Organics

NASA Technical Reports Server (NTRS)

Allamandola, Lou J.; Bernstein, Max; Sandford, Scott; Witteborn, Fred (Technical Monitor)

1996-01-01

During the past two decades ground-, air-, and space-based infrared spectroscopic observations, combined with realistic laboratory simulations, have revolutionized our understanding of interstellar ice and dust, the raw materials from which planets, comets and stars form. Most interstellar material is concentrated in Large molecular clouds where simple molecules are formed by dust grain and gas phase reactions. Gaseous species striking the cold (10 K) dust will stick, forming an icy grain mantle. This accretion, coupled with energetic particle bombardment and UV photolysis, will produce a complex chemical mixture containing volatile, non-volatile, and isotopically fractionated species. Ices in molecular clouds contain the very simple molecules H2O, CH3OH, CO, CO2, H2, and perhaps some NH3 and H2CO, as well as more complex species including nitriles and ketones or esters. The evidence for these compounds as well as carbon rich materials such as polycyclic aromatic hydrocarbons (PAHs), microdiamonds, and amorphous carbon will be reviewed and the possible connections with comets and meteorites will be presented in the first part of the talk. The second part of the presentation will focus on interstellar/precometary ice photochemical evolution. The chemical composition and photochemical evolution of realistic interstellar/pre-cometary ice analogs containing methanol will be discussed. ultraviolet photolysis of these ices produces H2, H2CO, CO2, CO, CH4, HCO, and more complex molecules. Infrared spectroscopy, H-1 and C-13 nuclear magnetic resonance (NMR) spectroscopy, and gas chromatography-mass spectrometry demonstrate that when ices representative of interstellar grains and comets are exposed to UV radiation at low temperature a series of moderately complex organic molecules are formed in the ice including: CH3CH2OH (ethanol), HC(=O)NH2 (formamide), CH3C(=O)NH2 (acetamide), and R-C(integral)N (nitriles). Several of these are already known to be in the interstellar medium, and their presence indicates the importance of grain processing. After warming to room temperature what remains is an organic residue composed primarily of Hexamethylenetetramine (HMT, C6H12N4), with lesser amounts of polyoxymethylene related species (POMs), amides, and ketones. This is in sharp contrast to the organic residues produced by irradiating ices which do not contain methanol (unrealistic interstellar ice analogs) or thermally promoted polymerization-type reactions in unirradiated realistic ice mixtures. Here HMT is only a minor product in a residue dominated by a mixture of polyoxymethylene related species. The implications, for infrared astronomy and astrochemistry, of high concentrations of HMT in interstellar and cometary ices may be profound. The ultraviolet photolysis of HMT frozen in H20 ice produces the "XCN" band observed in the spectra of protostellar objects and laboratory ices, as well as carbon oxides and other nitriles. Thus, HMT may be a precursor of XCN in protostellar objects and a source of CN and CO in the tail of comets. Also, HMT is known to hydrolyze under acidic conditions to yield ammonia and formaldehyde as well as amino acids. Thus, HMT may have been a source of organic material delivered to the early earth by comets.

GRAVITATIONAL CONTRACTION VERSUS SUPERNOVA DRIVING AND THE ORIGIN OF THE VELOCITY DISPERSION–SIZE RELATION IN MOLECULAR CLOUDS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ibáñez-Mejía, Juan C.; Mac Low, Mordecai-Mark; Klessen, Ralf S.

Molecular cloud (MC) observations show that clouds have non-thermal velocity dispersions that scale with the cloud size as σ ∝ R {sup 1/2} at a constant surface density, and for varying surface density scale with both the cloud’s size and surface density, σ {sup 2} ∝ R Σ. The energy source driving these chaotic motions remains poorly understood. We describe the velocity dispersions observed in a cloud population formed in a numerical simulation of a magnetized, stratified, supernova (SN)-driven, interstellar medium, including diffuse heating and radiative cooling, before and after we include the effects of the self-gravity of the gas.more » We compare the relationships between velocity dispersion, size, and surface density measured in the simulated cloud population to those found in observations of Galactic MCs. Our simulations prior to the onset of self-gravity suggest that external SN explosions alone do not drive turbulent motions of the observed magnitudes within dense clouds. On the other hand, self-gravity induces non-thermal motions as gravitationally bound clouds begin to collapse in our model, approaching the observed relations between velocity dispersion, size, and surface density. Energy conservation suggests that the observed behavior is consistent with the kinetic energy being proportional to the gravitational energy. However, the clouds in our model show no sign of reaching a stable equilibrium state at any time, even for strongly magnetized clouds. We conclude that gravitationally bound MCs are always in a state of gravitational contraction and their properties are a natural result of this chaotic collapse. In order to agree with observed star formation efficiencies, this process must be terminated by the early destruction of the clouds, presumably from internal stellar feedback.« less

High-energy radiation from collisions of high-velocity clouds and the Galactic disc

NASA Astrophysics Data System (ADS)

del Valle, Maria V.; Müller, A. L.; Romero, G. E.

2018-04-01

High-velocity clouds (HVCs) are interstellar clouds of atomic hydrogen that do not follow normal Galactic rotation and have velocities of a several hundred kilometres per second. A considerable number of these clouds are falling down towards the Galactic disc. HVCs form large and massive complexes, so if they collide with the disc a great amount of energy would be released into the interstellar medium. The cloud-disc interaction produces two shocks: one propagates through the cloud and the other through the disc. The properties of these shocks depend mainly on the cloud velocity and the disc-cloud density ratio. In this work, we study the conditions necessary for these shocks to accelerate particles by diffusive shock acceleration and we study the non-thermal radiation that is produced. We analyse particle acceleration in both the cloud and disc shocks. Solving a time-dependent two-dimensional transport equation for both relativistic electrons and protons, we obtain particle distributions and non-thermal spectral energy distributions. In a shocked cloud, significant synchrotron radio emission is produced along with soft gamma rays. In the case of acceleration in the shocked disc, the non-thermal radiation is stronger; the gamma rays, of leptonic origin, might be detectable with current instruments. A large number of protons are injected into the Galactic interstellar medium, and locally exceed the cosmic ray background. We conclude that under adequate conditions the contribution from HVC-disc collisions to the galactic population of relativistic particles and the associated extended non-thermal radiation might be important.

Interstellar Antifreeze: Ethylene Glycol

NASA Technical Reports Server (NTRS)

Hollis, J. M.; Lovas, F. J.; Jewell, P. R.; Coudert, L. H.

2002-01-01

Interstellar ethylene glycol (HOCH2CH2,OH) has been detected in emission toward the Galactic center source Sagittarius B2(N-LMH) by means of several millimeter-wave rotational torsional transitions of its lowest energy conformer. The types and kinds of molecules found to date in interstellar clouds suggest a chemistry that favors aldehydes and their corresponding reduced alcohols-e.g., formaldehyde (H2CO)/methanol (CH3OH), acetaldehyde (CH3CHO)/ethanol (CH3CH2OH). Similarly, ethylene glycol is the reduced alcohol of glycolaldehyde (CH2OHCHO), which has also been detected toward Sgr B2(N-LMH). While there is no consensus as to how any such large complex molecules are formed in the interstellar clouds, atomic hydrogen (H) and carbon monoxide (CO) could form formaldehyde on grain surfaces, but such surface chemistry beyond that point is uncertain. However, laboratory experiments have shown that the gas-phase reaction of atomic hydrogen (H) and solid-phase CO at 10-20 K can produce formaldehyde and methanol and that alcohols and other complex molecules can be synthesized from cometary ice analogs when subject to ionizing radiation at 15 K. Thus, the presence of aldehyde/ reduced alcohol pairs in interstellar clouds implies that such molecules are a product of a low-temperature chemistry on grain surfaces or in grain ice mantles. This work suggests that aldehydes and their corresponding reduced alcohols provide unique observational constraints on the formation of complex interstellar molecules.

Interstellar gas in the Gum Nebula

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wallerstein, G.; Silk, J.; Jenkins, E.B.

1980-09-15

We have surveyed the interstellar gas in and around the Gum Nebula by optically observing 67 stars at Ca II, 42 stars at Na I, and 14 stars in the ultraviolet with the Copernicus satellite. Velocity dispersions for gas in the Gum Nebula, excluding the region of Vela remnant filaments, are not significantly larger than in the general interstellar medium. The ionization structure is predominantly that of an H II region with moderately high ionization, i.e., strong Si III and S III, in clouds with Vertical BarV/sub LSR/Vertical Bar> or approx. =10 km s/sup -1/. Furthermore, we find an increasemore » in fine-structure excitation with increasing component LSR velocity, suggestive of ram-pressure confinement for the intermediate-velocity clouds. These denser, more highly ionized clouds appear to be concentrated toward the inner Gum Nebula, where a somewhat higher velocity dispersion is found than in the outer regions. Clouds in the Gum Nebula do not show the anomalously high ionization seen in the Vela remnant clouds. The observational data are generally consistent with a model of the Gum Nebula as an H II region ionized by OB stars and stirred up by multiple stellar winds.« less

A search for diffuse band profile variations in the rho Ophiuchi cloud

NASA Technical Reports Server (NTRS)

Snow, T. P.; Timothy, J. G.; Sear, S.

1982-01-01

High signal-to-noise profiles of the broad diffuse interstellar band at 4430 A were obtained on the 2.2-m telescope at the Mauna Kea Observatory, using the newly-developed pulse-counting multi-anode microchannel array detector system in an effort to determine whether the band profile varies with mean grain size as expected if the band is produced by absorbers embedded in grain lattices. The lack of profile variability over several lines of sight where independent evidence indicates that the mean grain size varies shows that lambda 4430 is probably not formed by the same grains that are responsible for interstellar extinction at visible wavelengths. The possibility that this band is created by a population of very small ( approximately 100 A) grains is still viable, as is the hypothesis that it has a molecular origin.

Exploring the Excluded Galactic Cosmic Rays--those at the Lowest Energies.

NASA Astrophysics Data System (ADS)

Shapiro, Maurice M.

2001-04-01

The solar wind prevents the lowest- energy Galactic cosmic rays (GCR) from entering the heliosphere. Consequently, space probes have thus far been unable to sample them. We suggest that astrochemistry may provide a ``handle" on these particles. Clouds in the interstellar medium (ISM) are sites of chemical-reaction networks that produce various molecular species detectable by their radioastronomical signatures. Highly ionizing low-energy cosmic rays are thought to be the principal agents of molecule production in clouds. Some anomalous abundances, e.g., of deuterium molecules, have been detected. Could studies of the foregoing networks of reactions and their products yield clues to the fluxes and energy spectra of the lowest-energy GCR in the ISM? Other approaches to this problem are also cited.

Exploring the Galactic Cosmic Rays at the lowest energies

NASA Astrophysics Data System (ADS)

Shapiro, M. M.

2001-08-01

The solar wind prevents the lowest-energy Galactic cosmic rays (GCR) from entering the Heliosphere. Consequently, space probes have thus far been unable to sample them. We suggest that astrochemistry may provide a handle on these particles. Clouds in the interstellar medium (ISM) are sites of chemical-reaction networks that produce various molecular species detectable by their radioastronomical signatures. Highly ionizing low-energy cosmic rays are thought to be the principal agents of molecule production in clouds. Some anomalous abundances, e.g., of deuterium molecules, have been detected. Could studies of the foregoing networks of reactions and their products yield clues to the fluxes and energy spectra of the lowest-energy GCR in the ISM? Other approaches to this problem are also cited.

FERMI LARGE AREA TELESCOPE STUDY OF COSMIC RAYS AND THE INTERSTELLAR MEDIUM IN NEARBY MOLECULAR CLOUDS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ackermann, M.; Ajello, M.; Allafort, A.

We report an analysis of the interstellar {gamma}-ray emission from the Chamaeleon, R Coronae Australis (R CrA), and Cepheus and Polaris flare regions with the Fermi Large Area Telescope. They are among the nearest molecular cloud complexes, within {approx}300 pc from the solar system. The {gamma}-ray emission produced by interactions of cosmic rays (CRs) and interstellar gas in those molecular clouds is useful to study the CR densities and distributions of molecular gas close to the solar system. The obtained {gamma}-ray emissivities above 250 MeV are (5.9 {+-} 0.1{sub stat}{sup +0.9}{sub -1.0sys}) Multiplication-Sign 10{sup -27} photons s{sup -1} sr{sup -1}more » H-atom{sup -1}, (10.2 {+-} 0.4{sub stat}{sup +1.2}{sub -1.7sys}) Multiplication-Sign 10{sup -27} photons s{sup -1} sr{sup -1} H-atom{sup -1}, and (9.1 {+-} 0.3{sub stat}{sup +1.5}{sub -0.6sys}) Multiplication-Sign 10{sup -27} photons s{sup -1} sr{sup -1} H-atom{sup -1} for the Chamaeleon, R CrA, and Cepheus and Polaris flare regions, respectively. Whereas the energy dependences of the emissivities agree well with that predicted from direct CR observations at the Earth, the measured emissivities from 250 MeV to 10 GeV indicate a variation of the CR density by {approx}20% in the neighborhood of the solar system, even if we consider systematic uncertainties. The molecular mass calibrating ratio, X{sub CO} = N(H{sub 2})/W{sub CO}, is found to be (0.96 {+-} 0.06{sub stat}{sup +0.15}{sub -0.12sys}) Multiplication-Sign 10{sup 20} H{sub 2}-molecule cm{sup -2} (K km s{sup -1}){sup -1}, (0.99 {+-} 0.08{sub stat}{sup +0.18}{sub -0.10sys}) Multiplication-Sign 10{sup 20} H{sub 2}-molecule cm{sup -2} (K km s{sup -1}){sup -1}, and (0.63 {+-} 0.02{sub stat}{sup +0.09}{sub -0.07sys}) Multiplication-Sign 10{sup 20} H{sub 2}-molecule cm{sup -2} (K km s{sup -1}){sup -1} for the Chamaeleon, R CrA, and Cepheus and Polaris flare regions, respectively, suggesting a variation of X{sub CO} in the vicinity of the solar system. From the obtained values of X{sub CO}, the masses of molecular gas traced by W{sub CO} in the Chamaeleon, R CrA, and Cepheus and Polaris flare regions are estimated to be {approx}5 Multiplication-Sign 10{sup 3} M{sub Sun }, {approx}10{sup 3} M{sub Sun }, and {approx}3.3 Multiplication-Sign 10{sup 4} M{sub Sun }, respectively. A comparable amount of gas not traced well by standard H I and CO surveys is found in the regions investigated.« less

Large Interstellar Polarisation Survey:The Dust Elongation When Combining Optical-Submm Polarisation

NASA Astrophysics Data System (ADS)

Siebenmorgen, Ralf; Voschinnikov, N.; Bagnulo, S.; Cox, N.; Cami, J.

2017-10-01

The Planck mission has shown that dust properties of the diffuse ISM varies on a large scale and we present variability on a small scales. We present FORS spectro-polarimetry obtained by the Large Interstellar Polarisation Survey along 60 sight-lines. We fit these combined with extinction data by a silicate and carbon dust model with grain sizes ranging from the molecular to the sub-mic. domain. Large silicates of prolate shape account for the observed polarisation. For 37 sight-lines we complement our data set with UVES high-resolution spectra that establish the presence of single or multiple clouds along individual sight-lines. We find correlations between extinction and Serkowski parameters with the dust model and that the presence of multiple clouds depolarises the incoming radiation. However, there is a degeneracy in the dust model between alignment efficiency and the elongation of the grains. This degeneracy can be broken by combining polarization data in the optical-to-submm. This is of wide general interest as it improves the accuracy of deriving dust masses. We show that a flat IR/submm polarisation spectrum with substantial polarisation is predicted from dust models.

Coagulation of grains in static and collapsing protostellar clouds

NASA Technical Reports Server (NTRS)

Weidenschilling, S. J.; Ruzmaikina, T. V.

1993-01-01

The wavelength dependence of extinction in the diffuse interstellar medium implies that it is produced by particles of dominant size of approximately 10(exp -5) cm. There is some indication that in the cores of dense molecular clouds, sub-micron grains can coagulate to form larger particles; this process is probably driven by turbulence. The most primitive meteorites (carbonaceous chondrites) are composed of particles with a bimodal size distribution with peaks near 1 micron (matrix) and 1 mm (chondrules). Models for chondrule formation that involve processing of presolar material by chemical reactions or through an accretion shock during infall assume that aggregates of the requisite mass could form before or during collapse. The effectiveness of coagulation during collapse has been disputed; it appears to depend on specific assumptions. The first results of detailed numerical modeling of spatial and temporal variations of particle sizes in presolar clouds, both static and collapsing, is reported in this article.

Planetary atmospheres program

NASA Technical Reports Server (NTRS)

1982-01-01

Non-solar compositional models of the troposphere of Jupiter, halide cloud condensation and volatile element inventories on Venus, and shock-wave processing of interstellar cloud materials are discussed.

Gamma-ray observations of the Orion Molecular Clouds with the Fermi Large Area Telescope

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ackermann, M.; Ajello, M.; Allafort, A.

We report on the gamma-ray observations of giant molecular clouds Orion A and B with the Large Area Telescope (LAT) on board the Fermi Gamma-ray Space Telescope. The gamma-ray emission in the energy band between ~100 MeV and ~100 GeV is predicted to trace the gas mass distribution in the clouds through nuclear interactions between the Galactic cosmic rays (CRs) and interstellar gas. The gamma-ray production cross-section for the nuclear interaction is known to ~10% precision which makes the LAT a powerful tool to measure the gas mass column density distribution of molecular clouds for a known CR intensity. Wemore » present here such distributions for Orion A and B, and correlate them with those of the velocity-integrated CO intensity (W CO) at a 1° × 1° pixel level. The correlation is found to be linear over a W CO range of ~10-fold when divided in three regions, suggesting penetration of nuclear CRs to most of the cloud volumes. The W CO-to-mass conversion factor, X CO, is found to be ~2.3 × 10 20 cm -2(K km s –1) –1 for the high-longitude part of Orion A (l > 212°), ~1.7 times higher than ~1.3 × 10 20 found for the rest of Orion A and B. We interpret the apparent high X CO in the high-longitude region of Orion A in the light of recent works proposing a nonlinear relation between H2 and CO densities in the diffuse molecular gas. W CO decreases faster than the H 2 column density in the region making the gas "darker" to W CO.« less

Gamma-Ray Observations of the Orion Molecular Clouds with the Fermi Large Area Telescope

NASA Technical Reports Server (NTRS)

Ackermann, M.; Ajello, M.; Allafort, A.; Antolini, E.; Baldini, L.; Ballet, J.; Barbiellini, G.; Bastieri, D.; Bechtol, K.; Bellazzini, R.;

On the Ubiquity of Molecular Anions in the Dense Interstellar Medium

NASA Technical Reports Server (NTRS)

Cordiner, M. A.; Buckle, J. V.; Wirstroem, E. S.; Olofsson, A. O. H.; Charnley, S. B.

2013-01-01

Results are presented from a survey for molecular anions in seven nearby Galactic star-forming cores and molecular clouds. The hydrocarbon anion C6H(-) is detected in all seven target sources, including four sources where no anions have been previously detected: L1172, L1389, L1495B, and TMC-1C. The C6H(-) /C6H column density ratio is approx. > 1.0% in every source, with a mean value of 3.0% (and standard deviation 0.92%). Combined with previous detections, our results show that anions are ubiquitous in dense clouds wherever C6H is present. The C6H(-)/C6H ratio is found to show a positive correlation with molecular hydrogen number density, and with the apparent age of the cloud.We also report the first detection of C4H(-) in TMC-1 (at 4.8 sigma confidence), and derive an anion-to-neutral ratio C4H(-) /C4H = (1.2 +/- 0.4)×10(exp -5)(= 0.0012% +/- 0.0004%). Such a low value compared with C6H(-) highlights the need for a revised radiative electron attachment rate for C4H. Chemical model calculations show that the observed C4H(-) could be produced as a result of reactions of oxygen atoms with C5H(-) and C6H(-).

Interstellar gas in the middle-aged SNRs

NASA Astrophysics Data System (ADS)

Yoshiike, Satoshi; Fukuda, Tatsuya; Sano, Hidetoshi; Fukui, Yasuo

2017-01-01

An analysis of neutral interstellar gas in the γ-ray middle-aged supernova remnants (SNRs) is presented. We carried out multi-line CO observations of 12CO(J = 1-0) and 12CO(J = 2-1) toward three middle-aged SNRs, W44, IC 443 and W28, with the NANTEN2 telescope. For all three SNRs, we identified the shocked molecular gas which has high-velocity wing emission and the high 12CO J = 2-1/1-0 line intensity ratio of greater than 1. The distribution of these shocked gas has the good correlation with that of GeV-TeV γ-rays, which indicates these γ-rays originate from hadronic process and the interaction between SNR shock and clouds plays an major role in the cosmic-ray acceleration for these SNRs. By combining CO results with archive H I data, we derived the amount of total interstellar protons responsible for the γ-rays. Every SNRs have the averaged proton densities ranged from a few hundred to less than 103 cm-3 and we estimated the total cosmic-ray proton energy to be ˜ 1048-1049 erg as lower limits.

GEMS Revealed: Spectrum Imaging of Aggregate Grains in Interplanetary Dust

NASA Technical Reports Server (NTRS)

Keller, L. P.; Messenger, S.; Christoffersen, R.

2005-01-01

Anhydrous interplanetary dust particles (IDPs) of cometary origin contain abundant materials that formed in the early solar nebula. These materials were transported outward and subsequently mixed with molecular cloud materials and presolar grains in the region where comets accreted [1]. GEMS (glass with embedded metal and sulfides) grains are a major component of these primitive anhydrous IDPs, along with crystalline Mg-rich silicates, Fe-Ni sulfides, carbonaceous material, and other trace phases. Some GEMS grains (5%) are demonstrably presolar based on their oxygen isotopic compositions [2]. However, most GEMS grains are isotopically solar and have bulk chemical compositions that are incompatible with inferred compositions of interstellar dust, suggesting a solar system origin [3]. An alternative hypothesis is that GEMS grains represent highly irradiated interstellar grains whose oxygen isotopic compositions were homogenized through processing in the interstellar medium (ISM) [4]. We have obtained the first quantitative X-ray maps (spectrum images) showing the distribution of major and minor elements in individual GEMS grains. Nanometer-scale chemical maps provide critical data required to evaluate the differing models regarding the origin of GEMS grains.

Iron hydrides formation in interstellar clouds

NASA Astrophysics Data System (ADS)

Bar-Nun, A.; Pasternak, M.; Barrett, P. H.

1980-07-01

A recent Moessbauer study with Fe-57 in a solid hydrogen or hydrogen-argon matrix demonstrated the formation of an iron hydride molecule (FeH2) at 2.5-5 K. Following this and other studies, the possible existence of iron hydride molecules in interstellar clouds is proposed. In clouds, the iron hydrides FeH and FeH2 would be formed only on grains, by encounters of H atoms or H2 molecules with Fe atoms which are adsorbed on the grains. The other transition metals, Sc, Ti, V, Cr, Mn, Co, N, Cd and also Cu and Ca form hydrides of the type M-H, which could be responsible, at least in part, for the depletion of these metals in clouds.

ON THE STAR FORMATION LAW FOR SPIRAL AND IRREGULAR GALAXIES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elmegreen, Bruce G., E-mail: bge@us.ibm.com

2015-12-01

A dynamical model for star formation on a galactic scale is proposed in which the interstellar medium is constantly condensing to star-forming clouds on the dynamical time of the average midplane density, and the clouds are constantly being disrupted on the dynamical timescale appropriate for their higher density. In this model, the areal star formation rate scales with the 1.5 power of the total gas column density throughout the main regions of spiral galaxies, and with a steeper power, 2, in the far outer regions and in dwarf irregular galaxies because of the flaring disks. At the same time, theremore » is a molecular star formation law that is linear in the main and outer parts of disks and in dIrrs because the duration of individual structures in the molecular phase is also the dynamical timescale, canceling the additional 0.5 power of surface density. The total gas consumption time scales directly with the midplane dynamical time, quenching star formation in the inner regions if there is no accretion, and sustaining star formation for ∼100 Gyr or more in the outer regions with no qualitative change in gas stability or molecular cloud properties. The ULIRG track follows from high densities in galaxy collisions.« less

The chemistry of planet-forming regions is not interstellar.

PubMed

Pontoppidan, Klaus M; Blevins, Sandra M

2014-01-01

Advances in infrared and submillimeter technology have allowed for detailed observations of the molecular content of the planet-forming regions of protoplanetary disks. In particular, disks around solar-type stars now have growing molecular inventories that can be directly compared with both prestellar chemistry and that inferred for the early solar nebula. The data directly address the old question of whether the chemistry of planet-forming matter is similar or different and unique relative to the chemistry of dense clouds and protostellar envelopes. The answer to this question may have profound consequences for the structure and composition of planetary systems. The practical challenge is that observations of emission lines from disks do not easily translate into chemical concentrations. Here, we present a two-dimensional radiative transfer model of RNO 90, a classical protoplanetary disk around a solar-mass star, and retrieve the concentrations of dominant molecular carriers of carbon, oxygen and nitrogen in the terrestrial region around 1 AU. We compare our results to the chemical inventory of dense clouds and protostellar envelopes, and argue that inner disk chemistry is, as expected, fundamentally different from prestellar chemistry. We find that the clearest discriminant may be the concentration of CO2, which is extremely low in disks, but one of the most abundant constituents of dense clouds and protostellar envelopes.

The Surprising Complexity of Diffuse and Translucent Clouds Toward SGR B2: Diatomics and COMs from 4 GHz to 1.2 THz

NASA Astrophysics Data System (ADS)

McGuire, Brett A.; Corby, Joanna F.; Martin-Drumel, Marie-Aline; Schilke, P.; McCarthy, Michael C.; Remijan, Anthony

2017-06-01

Many diffuse and translucent clouds lie along the line of sight between Earth and the Galactic Center that can be probed through molecular absorption at characteristic velocities. We highlight results of a study of diffuse and translucent clouds along the line of sight to Sgr B2, including SOFIA observations of SH near 1.4 THz and GBT PRIMOS observations from 4 to 50 GHz. We find significant variation in the chemical conditions within these clouds, and the abundances do not appear to correlate with the total optical depth. Additionally, from the GBT observations, we report the first detections of multiple complex organic molecules (COMs) in diffuse and translucent clouds, including CH_3CN, HC_3N, CH_3CHO, and NH_2CHO. We compare the GBT results to complementary observations of SH, H_2S, and others at mm, sub-mm, and THz frequencies from the NRAO 12m, Herschel HIFI, and SOFIA facilities, and comment on the insights into interstellar sulfur chemistry which is currently not well constrained.

Interstellar abundances and depletions inferred from observations of neutral atoms

NASA Technical Reports Server (NTRS)

Snow, T. P.

1984-01-01

Data on neutral atomic species are analyzed for the purpose of inferring relative elemental abundances and depletions in diffuse cloud cores, where it is assumed that densities are enhanced in comparison with mean densities over integrated lines of sight. Column densities of neutral atoms are compared to yield relative column densities of singly ionized species, which are assumed dominant in cloud cores. This paper incorporates a survey of literature data on neutral atomic abundances with the result that no systematic enhancement in the depletions of calcium or iron in cloud cores is found, except for zeta Ophiuchi. This may imply that depletions are not influenced by density, but other data argue against this interpretation. It is concluded either that in general all elements are depleted together in dense regions so that their relative abundances remain constant, or that typical diffuse clouds do not have significant cores, but instead are reasonably homogeneous. The data show a probable correlation between cloud-core depletion and hydrogen-molecular fraction, supporting the assumption that overall depletions are a function of density.

Detection of interstellar CH in the far-infrared

NASA Technical Reports Server (NTRS)

Stacey, Gordon J.; Lugten, J. B.; Genzel, R.

1987-01-01

The first astronomical detection of CH in the far-infrared has been made. A ground state of rotational transition was observed in absorption against the far-infrared continuum peak of Sgr B2. The lines are resolved at a velocity resolution of 62 km/s, have a line width of roughly 250 km/s, and a line center optical depth of about 0.29. The inferred total column density of CH in the ground state along the line of sight is roughly 1.6 x 10 to the 15th/sq cm. Comparison of the far-infrared profiles to the 3 GHz emission lines confirms that the ground-state Lambda-doublet levels are inverted and gives an accurate estimate of the excitation temperature. The excitation temperature of the 3264 MHz line varies from cloud to cloud along the line of sight, the levels being most inverted in the Sgr B2 molecular cloud. The large intensity of the 3264 MHz line in this cloud relative to other clouds along the line of sight may thus be primarily an excitation effect.

Dynamics of the Interstellar Matter in Galaxies

NASA Astrophysics Data System (ADS)

Kristen, H.

The dynamical components of six isolated barred spiral (SB) galaxies are investigated. No evidence is found supporting the hypothesis of a low amount of dark matter being characteristic of SB galaxies. The presence of companion galaxies is found to correlate with an increased statistical spread in the neutral hydrogen (HI) extent. It is concluded that the selection of galaxies with large HI~extent may introduce a bias towards tidally interacting systems. The circumnuclear region of the SB galaxy NGC 1365 is studied with the Hubble Space Telescope (HST). Numerous bright ``super star clusters'' (SSCs) are detected, surrounding the active nucleus. The bright compact radio source NGC 1365:A is found to coincide spatially with one of the SSCs. We conclude that the source is a ``radio supernova''. In the [OIII] 5007 line, the HST resolves individual clouds within the conical outflow from the nucleus, some of which gather in larger agglomerations. An in-depth study of the dynamics of the SB galaxy NGC 1300 is presented. Multi-wavelength data yield an estimate of the velocity field and gravitational potential. Subsequent hydrodynamical simulations are able to reproduce the morphology and kinematics in the bar region using a pure bar perturbing potential. To reproduce the spiral structure a weak spiral component has to be added, indicative of stellar spiral response to the bar and/or self-gravitating gas in the arms. Two separate models, differing mainly with respect to pattern speed and associated resonance structure, are found to reproduce the observations. We study numerically the linear polarization and extinction of light from background stars passing through molecular clouds, illuminating the intricacies of the derivation of the magnetic-field-line pattern in a cloud from the observed polarization pattern: Due to a higher gas-grain collision frequency within the cloud, the polarization caused by the cloud may well be dominated by background/foreground polarization. Furthermore, variations in field-orientation along the line-of-sight may cause notable differences between the observed polarization vectors and the true magnetic-field-line pattern. Small-scale, helical, interstellar filaments are discussed on the basis of optical observations of an ``elephant trunk'' structure in the Rosette nebula. The observed sinusoidal filaments are suggested to be helices lined up by magnetic fields. We propose that the Rosette elephant trunks form an interconnected system of rope-like structures which are relics from filamentary skeletons of magnetic fields in the primordial cloud. Stochastic mass fractionation of a molecular cloud is simulated numerically. It is found that geometry alone may constrain the resulting mass spectrum of molecular cloud clumps. We demonstrate that further fragmentation of the cloud clumps, under the assumption of a lower limit of the self-similar regime, produces a mass spectrum that has qualitative and quantitative similarities with the empirically determined stellar initial mass function.

The evolution of grain mantles and silicate dust growth at high redshift

NASA Astrophysics Data System (ADS)

Ceccarelli, Cecilia; Viti, Serena; Balucani, Nadia; Taquet, Vianney

2018-05-01

In dense molecular clouds, interstellar grains are covered by mantles of iced molecules. The formation of the grain mantles has two important consequences: it removes species from the gas phase and promotes the synthesis of new molecules on the grain surfaces. The composition of the mantle is a strong function of the environment that the cloud belongs to. Therefore, clouds in high-zeta galaxies, where conditions - like temperature, metallicity, and cosmic ray flux - are different from those in the Milky Way, will have different grain mantles. In the last years, several authors have suggested that silicate grains might grow by accretion of silicon-bearing species on smaller seeds. This would occur simultaneously with the formation of the iced mantles and be greatly affected by its composition as a function of time. In this work, we present a numerical study of the grain mantle formation in high-zeta galaxies, and we quantitatively address the possibility of silicate growth. We find that the mantle thickness decreases with increasing redshift, from about 120 to 20 layers for z varying from 0 to 8. Furthermore, the mantle composition is also a strong function of the cloud redshift, with the relative importance of CO, CO2, ammonia, methane, and methanol highly varying with z. Finally, being Si-bearing species always a very minor component of the mantle, the formation of silicates in molecular clouds is practically impossible.

The GBT PRIMOS Project - A Broadband Spectral Line Survey of SgrB2N from 300 MHz to 46 GHz

NASA Astrophysics Data System (ADS)

Remijan, Anthony J.; Hollis, J. M.; Jewell, P. R.; Lovas, F.; Corby, J.

2013-01-01

Broadband, very sensitive, high spectral resolution spectral line surveys in recent years have made profound impacts into the understanding of interstellar reaction processes and in the identification of new molecular material in astronomical environments. Molecular line surveys are studies of the spectra of astronomical sources over a wide and usually continuous range of frequencies in order to determine the chemical composition (i.e., "molecular inventory"), physical properties (temperature, density), and kinematics of such regions. The National Radio Astronomy Observatory's (NRAO) 100-m Robert C. Byrd Green Bank Telescope (GBT) PRebiotic Interstellar MOlecule Survey (PRIMOS) Legacy Project started in Jan 2008 and concluded in July 2011. The PRIMOS project recorded a nearly frequency-continuous astronomical spectrum from 300 MHz to 46 GHz towards the Sgr B2(N) molecular cloud, with the pointing position centered on the Large Molecule Heimat (LMH). The PRIMOS data have resulted in numerous new detections and discoveries in astrochemistry. The data have also been widely used to demonstrate advances in molecular astrophysics in a variety of venues and have been instrumental in training the next generation of astronomers and chemists. The GBT is the only telescope in the world capable of making these groundbreaking discoveries. This presentation will highlight the recent successes from the survey and how to access these publically-available observations.

Cometary Materials Originating from Interstellar Ices: Clues from Laboratory Experiments

NASA Astrophysics Data System (ADS)

Fresneau, A.; Abou Mrad, N.; d'Hendecourt, L. LS; Duvernay, F.; Flandinet, L.; Orthous-Daunay, F.-R.; Vuitton, V.; Thissen, R.; Chiavassa, T.; Danger, G.

2017-03-01

We use laboratory experiments to derive information on the chemistry occurring during the evolution of astrophysical ices from dense molecular clouds to interplanetary objects. Through a new strategy that consists of coupling very high resolution mass spectrometry and infrared spectroscopy (FT-IR), we investigate the molecular content of the organic residues synthesized from different initial ice compositions. We also obtain information on the evolution of the soluble part of the residues after their over-irradiation. The results give insight into the role of water ice as a trapping and diluting agent during the chemical evolution. They also give information about the importance of the amount of ammonia in such ices, particularly regarding its competition with the carbon chemistry. All of these results allow us to build a first mapping of the evolution of soluble organic matter based on its chemical and physical history. Furthermore, our results suggest that interstellar ices should lead to organic materials enriched in heteroatoms that present similarities with cometary materials but strongly differ from meteoritic organic material, especially in their C/N ratios.

A Survey of Near-infrared Diffuse Interstellar Bands

NASA Astrophysics Data System (ADS)

Hamano, Satochi; Kobayashi, Naoto; Kawakita, Hideyo; Ikeda, Yuji; Kondo, Sohei; Sameshima, Hiroaki; Arai, Akira; Matsunaga, Noriyuki; Yasui, Chikako; Mizumoto, Misaki; Fukue, Kei; Izumi, Natsuko; Otsubo, Shogo; Takenada, Keiichi

2018-04-01

We propose a study of interstellar molecules with near-infrared (NIR) high-resolution spectroscopy as a science case for the 3.6-m Devasthal Optical Telescope (DOT). In particular, we present the results obtained on-going survey of diffuse interstellar bands (DIBs) in NIR with the newly developed NIR high-resolution spectrograph WINERED, which offers a high sensitivity in the wavelength range of 0.91-1.36 µm. Using the WINERED spectrograph attached to the 1.3-m Araki telescope in Japan, we obtained high-quality spectra of a number of early-type stars in various environments, such as diffuse interstellar clouds, dark clouds and star-forming regions, to investigate the properties of NIR DIBs and constrain their carriers. As a result, we successfully identified about 50 new NIR DIBs, where only five fairly strong DIBs had been identified previously. Also, some properties of DIBs in the NIR are discussed to constrain the carriers of DIBs.

The distribution of interstellar dust in the solar neighborhood

NASA Technical Reports Server (NTRS)

Gaustad, John E.; Van Buren, Dave

1993-01-01

We surveyed the IRAS data base at the positions of the 1808 O6-B9.5 stars in The Bright Star Catalog for extended objects with excess emission at 60 microns, indicating the presence of interstellar dust at the location of the star. Within 400 pc the filling factor of the interstellar medium, for dust clouds with a density greater than 0.5/cu cm is 14.6 + or - 2.4%. Above a density of 1.0/cu cm, the density distribution function appears to follow a power law index - 1.25. When the dust clouds are mapped onto the galactic plane, the sun appears to be located in a low-density region of the interstellar medium of width about 60 pc extending at least 500 pc in the direction of longitudes 80 deg - 260 deg, a feature we call the 'local trough'.

On the cosmic ray diffusion in a violent interstellar medium

NASA Technical Reports Server (NTRS)

Bykov, A. M.; Toptygin, I. N.

1985-01-01

A variety of the available observational data on the cosmic ray (CR) spectrum, anisotropy and composition are in good agreement with a suggestion on the diffusion propagation of CR with energy below 10(15) eV in the interstellar medium. The magnitude of the CR diffusion coefficient and its energy dependence are determined by interstellar medium (ISM) magnetic field spectra. Direct observational data on magnetic field spectra are still absent. A theoretical model to the turbulence generation in the multiphase ISM is resented. The model is based on the multiple generation of secondary shocks and concomitant large-scale rarefactions due to supernova shock interactions with interstellar clouds. The distribution function for ISM shocks are derived to include supernova statistics, diffuse cloud distribution, and various shock wave propagation regimes. This permits calculation of the ISM magnetic field fluctuation spectrum and CR diffusion coefficient for the hot phase of ISM.

SEDIGISM: Structure, excitation, and dynamics of the inner Galactic interstellar medium

NASA Astrophysics Data System (ADS)

Schuller, F.; Csengeri, T.; Urquhart, J. S.; Duarte-Cabral, A.; Barnes, P. J.; Giannetti, A.; Hernandez, A. K.; Leurini, S.; Mattern, M.; Medina, S.-N. X.; Agurto, C.; Azagra, F.; Anderson, L. D.; Beltrán, M. T.; Beuther, H.; Bontemps, S.; Bronfman, L.; Dobbs, C. L.; Dumke, M.; Finger, R.; Ginsburg, A.; Gonzalez, E.; Henning, T.; Kauffmann, J.; Mac-Auliffe, F.; Menten, K. M.; Montenegro-Montes, F. M.; Moore, T. J. T.; Muller, E.; Parra, R.; Perez-Beaupuits, J.-P.; Pettitt, A.; Russeil, D.; Sánchez-Monge, Á.; Schilke, P.; Schisano, E.; Suri, S.; Testi, L.; Torstensson, K.; Venegas, P.; Wang, K.; Wienen, M.; Wyrowski, F.; Zavagno, A.

2017-05-01

Context. The origin and life-cycle of molecular clouds are still poorly constrained, despite their importance for understanding the evolution of the interstellar medium. Many large-scale surveys of the Galactic plane have been conducted recently, allowing for rapid progress in this field. Nevertheless, a sub-arcminute resolution global view of the large-scale distribution of molecular gas, from the diffuse medium to dense clouds and clumps, and of their relationshipto the spiral structure, is still missing. Aims: We have carried out a systematic, homogeneous, spectroscopic survey of the inner Galactic plane, in order to complement the many continuum Galactic surveys available with crucial distance and gas-kinematic information. Our aim is to combine this data set with recent infrared to sub-millimetre surveys at similar angular resolutions. Methods: The SEDIGISM survey covers 78 deg2 of the inner Galaxy (-60°≤ℓ≤ 18°, |b|≤ 0.5°) in the J = 2-1 rotational transition of 13CO. This isotopologue of CO is less abundant than 12CO by factors up to 100. Therefore, its emission has low to moderate optical depths, and higher critical density, making it an ideal tracer of the cold, dense interstellar medium. The data have been observed with the SHFI single-pixel instrument at APEX. The observational setup covers the 13CO(2-1) and C18O(2-1) lines, plus several transitions from other molecules. Results: The observations have been completed. Data reduction is in progress, and the final data products will be made available in the near future. Here we give a detailed description of the survey and the dedicated data reduction pipeline. To illustrate the scientific potential of this survey, preliminary results based on a science demonstration field covering -20°≤ℓ ≤ -18.5° are presented. Analysis of the 13CO(2-1) data in this field reveals compact clumps, diffuse clouds, and filamentary structures at a range of heliocentric distances. By combining our data with data in the (1-0) transition of CO isotopologues from the ThrUMMS survey, we are able to compute a 3D realization of the excitation temperature and optical depth in the interstellar medium. Ultimately, this survey will provide a detailed, global view of the inner Galactic interstellar medium at an unprecedented angular resolution of 30''. This publication is based on data acquired with the Atacama Pathfinder EXperiment (APEX) under programmes 092.F-9315(A) and 193.C-0584(A). APEX is a collaboration between the Max-Planck-Institut für Radioastronomie, the European Southern Observatory, and the Onsala Space Observatory.Full Table 5 and Table A.1 are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/601/A124

First-principles study of the formation of glycine-producing radicals from common interstellar species

NASA Astrophysics Data System (ADS)

Sato, Akimasa; Kitazawa, Yuya; Ochi, Toshiro; Shoji, Mitsuo; Komatsu, Yu; Kayanuma, Megumi; Aikawa, Yuri; Umemura, Masayuki; Shigeta, Yasuteru

2018-03-01

Glycine, the simplest amino acid, has been intensively searched for in molecular clouds, and the comprehensive clarification of the formation path of interstellar glycine is now imperative. Among all the possible glycine formation pathways, we focused on the radical pathways revealed by Garrod (2013). In the present study, we have precisely investigated all the chemical reaction steps related to the glycine formation processes based on state-of-the-art density functional theory (DFT) calculations. We found that two reaction pathways require small activation barriers (ΔE‡ ≤ 7.75 kJ mol-1), which demonstrates the possibility of glycine formation even at low temperatures in interstellar space if the radical species are generated. The origin of carbon and nitrogen in the glycine backbone and their combination patterns are further discussed in relation to the formation mechanisms. According to the clarification of the atomic correspondence between glycine and its potential parental molecules, it is shown that the nitrogen and two carbons in the glycine can originate in three common interstellar molecules, methanol, hydrogen cyanide, and ammonia, and that the source molecules of glycine can be described by any of their combinations. The glycine formation processes can be categorized into six patterns. Finally, we discussed two other glycine formation pathways expected from the present DFT calculation results.

Evolutionary Description of Giant Molecular Cloud Mass Functions on Galactic Disks

NASA Astrophysics Data System (ADS)

Kobayashi, Masato I. N.; Inutsuka, Shu-ichiro; Kobayashi, Hiroshi; Hasegawa, Kenji

2017-02-01

Recent radio observations show that giant molecular cloud (GMC) mass functions noticeably vary across galactic disks. High-resolution magnetohydrodynamics simulations show that multiple episodes of compression are required for creating a molecular cloud in the magnetized interstellar medium. In this article, we formulate the evolution equation for the GMC mass function to reproduce the observed profiles, for which multiple compressions are driven by a network of expanding shells due to H II regions and supernova remnants. We introduce the cloud-cloud collision (CCC) terms in the evolution equation in contrast to previous work (Inutsuka et al.). The computed time evolution suggests that the GMC mass function slope is governed by the ratio of GMC formation timescale to its dispersal timescale, and that the CCC effect is limited only in the massive end of the mass function. In addition, we identify a gas resurrection channel that allows the gas dispersed by massive stars to regenerate GMC populations or to accrete onto pre-existing GMCs. Our results show that almost all of the dispersed gas contributes to the mass growth of pre-existing GMCs in arm regions whereas less than 60% contributes in inter-arm regions. Our results also predict that GMC mass functions have a single power-law exponent in the mass range <105.5 {M}⊙ (where {M}⊙ represents the solar mass), which is well characterized by GMC self-growth and dispersal timescales. Measurement of the GMC mass function slope provides a powerful method to constrain those GMC timescales and the gas resurrecting factor in various environments across galactic disks.

A scaling law of radial gas distribution in disk galaxies

NASA Technical Reports Server (NTRS)

Wang, Zhong

1990-01-01

Based on the idea that local conditions within a galactic disk largely determine the region's evolution time scale, researchers built a theoretical model to take into account molecular cloud and star formations in the disk evolution process. Despite some variations that may be caused by spiral arms and central bulge masses, they found that many late-type galaxies show consistency with the model in their radial atomic and molecular gas profiles. In particular, researchers propose that a scaling law be used to generalize the gas distribution characteristics. This scaling law may be useful in helping to understand the observed gas contents in many galaxies. Their model assumes an exponential mass distribution with disk radius. Most of the mass are in atomic gas state at the beginning of the evolution. Molecular clouds form through a modified Schmidt Law which takes into account gravitational instabilities in a possible three-phase structure of diffuse interstellar medium (McKee and Ostriker, 1977; Balbus and Cowie, 1985); whereas star formation proceeds presumably unaffected by the environmental conditions outside of molecular clouds (Young, 1987). In such a model both atomic and molecular gas profiles in a typical galactic disk (as a result of the evolution) can be fitted simultaneously by adjusting the efficiency constants. Galaxies of different sizes and masses, on the other hand, can be compared with the model by simply scaling their characteristic length scales and shifting their radial ranges to match the assumed disk total mass profile sigma tot(r).

The Fourth Flight of CHESS: Analysis of Interstellar H2 on the γ Ara Sightline

NASA Astrophysics Data System (ADS)

Kruczek, Nick E.; France, Kevin; Nell, Nicholas; Fleming, Brian

2018-06-01

In this talk, we describe the scientific motivation and technical development of the Colorado High-resolution Echelle Stellar Spectrograph (CHESS) sounding rocket, focusing on the preliminary science results for the fourth launch of the payload (CHESS-4). CHESS is a far ultraviolet rocket-borne instrument designed to study the atomic-to-molecular transitions within translucent cloud regions in the interstellar medium. CHESS-4 launched on 13 April 2018 aboard NASA/CU sounding rocket mission 36.333 UG. The target for this flight was γ Ara, a B1I star that is known to display a variable and equatorially enhanced stellar wind. We present flight results of interstellar molecular hydrogen excitation, including initial measurements of the column density and temperature, on the sightline. These results are compared to previous values that were calculated using the damping wings of low-J H2 absorption features in Copernicus spectra. We also present analogous flight data for the sightline toward β Sco, finding that the derived column density of the J” = 1 rotational level differs by a factor of ~2 when compared to the previous observations. We discuss the discrepancies between the two measurements and show that the source of the difference is likely due to the opacity of higher rotational levels contributing to the J” = 1 absorption wing, increasing the inferred column density in the previous work.

Ultraviolet observations of the gas phase abundances in the diffuse clouds toward Zeta Ophiuchi at 3.5 kilometers per second resolution

NASA Technical Reports Server (NTRS)

Savage, Blair D.; Cardelli, Jason A.; Sofia, Ulysses J.

1992-01-01

Goddard High Resolution Spectrograph echelle mode measurements at 3.5 km/s resolution are presented for interstellar absorption produced by C II, O I, Mg I, Mg II, Al III, P II, Cr II, Mn II, Fe II, Ni II, Cu II, Zn II, Ga II, Ge II, and Kr I. The absorption line measurements are converted into representations of apparent column density per unit velocity in order to study the multicomponent nature of the absorption. The high spectral resolution of the measurements allows a comparative study of gas phase abundances for many species in the absorbing clouds near -27 and -15 km/s with a typical precision of about 0.05 dex. The matter absorbing near -27 km/s is situated in the local interstellar medium and has log N(H I) of about 19.74. This absorption provides information about the modest 'base' depletion associated with the lower density interstellar medium. The depletion results suggest that accretion processes are operating interstellar clouds that exhibit similar depletion efficiencies for some elements but much higher depletion efficiencies for others.

Interstellar Aldehydes and their corresponding Reduced Alcohols: Interstellar Propanol?

NASA Astrophysics Data System (ADS)

Etim, Emmanuel; Chakrabarti, Sandip Kumar; Das, Ankan; Gorai, Prasanta; Arunan, Elangannan

2016-07-01

There is a well-defined trend of aldehydes and their corresponding reduced alcohols among the known interstellar molecules; methanal (CH_2O) and methanol (CH_3OH); ethenone (C_2H_2O) and vinyl alcohol (CH_2CHOH); ethanal (C_2H_4O) and ethanol(C_2H_5OH); glycolaldehyde (C_2H_4O_2) and ethylene glycol(C_2H_6O_2). The reduced alcohol of propanal (CH_3CH_2CHO) which is propanol (CH_3CH_2CH_2OH) has not yet been observed but its isomer; ethyl methyl ether (CH_3CH_2OCH_3) is a known interstellar molecule. In this article, different studies are carried out in investigating the trend between aldehydes and their corresponding reduced alcohols and the deviation from the trend. Kinetically and with respect to the formation route, alcohols could have been produced from their corresponding reduced aldehydes via two successive hydrogen additions. This is plausible because of (a) the unquestionable high abundance of hydrogen, (b) presence of energy sources within some of the molecular clouds and (c) the ease at which successive hydrogen addition reaction occurs. In terms of stability, the observed alcohols are thermodynamically favorable as compared to their isomers. Regarding the formation process, the hydrogen addition reactions are believed to proceed on the surface of the interstellar grains which leads to the effect of interstellar hydrogen bonding. From the studies, propanol and propan-2-ol are found to be more strongly attached to the surface of the interstellar dust grains which affects its overall gas phase abundance as compared to its isomer ethyl methyl ether which has been observed.

QUANTIFYING THE INTERSTELLAR MEDIUM AND COSMIC RAYS IN THE MBM 53, 54, AND 55 MOLECULAR CLOUDS AND THE PEGASUS LOOP USING FERMI -LAT GAMMA-RAY OBSERVATIONS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mizuno, T.; Abdollahi, S.; Fukui, Y.

A study of the interstellar medium (ISM) and cosmic rays (CRs) using Fermi Large Area Telescope (LAT) data, in a region encompassing the nearby molecular clouds MBM 53, 54, and 55 and a farinfrared loop-like structure in Pegasus, is reported. By comparing Planck dust thermal emission model with Fermi -LAT γ-ray data, it was found that neither the dust radiance (R) nor the dust opacity at 353 GHz (τ353) were proportional to the total gas column density N(Htot) primarily because N(Htot)/R and N(Htot)/τ353 depend on the dust temperature (Td). The N(Htot) distribution was evaluated using γ-ray data by assuming themore » regions of high Td to be dominated by optically thin atomic hydrogen (HI) and by employing an empirical linear relation of N(Htot)/R to Td. It was determined that the mass of the gas not traced by the 21-cm or 2.6-mm surveys is ~25% of the mass of HI in the optically thin case and is larger than the mass of the molecular gas traced by carbon monoxide by a factor of up to 5. The measured γ-ray emissivity spectrum is consistent with a model based on CR spectra measured at the Earth and the nuclear enhancement factor of ≤1.5. It is, however, lower than local HI emissivities reported by previous Fermi -LAT studies employing different analysis methods and assumptions on ISM properties by 15%–20% in energies below a few GeV, even if we take account of the statistical and systematic uncertainties. The origin of the discrepancy is also discussed.« less

QUANTIFYING THE INTERSTELLAR MEDIUM AND COSMIC RAYS IN THE MBM 53, 54, AND 55 MOLECULAR CLOUDS AND THE PEGASUS LOOP USING FERMI -LAT GAMMA-RAY OBSERVATIONS

DOE PAGES

Mizuno, T.; Abdollahi, S.; Fukui, Y.; ...

2016-12-20

A study of the interstellar medium (ISM) and cosmic rays (CRs) using Fermi Large Area Telescope (LAT) data, in a region encompassing the nearby molecular clouds MBM 53, 54, and 55 and a farinfrared loop-like structure in Pegasus, is reported. By comparing Planck dust thermal emission model with Fermi -LAT γ-ray data, it was found that neither the dust radiance (R) nor the dust opacity at 353 GHz (τ353) were proportional to the total gas column density N(Htot) primarily because N(Htot)/R and N(Htot)/τ353 depend on the dust temperature (Td). The N(Htot) distribution was evaluated using γ-ray data by assuming themore » regions of high Td to be dominated by optically thin atomic hydrogen (HI) and by employing an empirical linear relation of N(Htot)/R to Td. It was determined that the mass of the gas not traced by the 21-cm or 2.6-mm surveys is ~25% of the mass of HI in the optically thin case and is larger than the mass of the molecular gas traced by carbon monoxide by a factor of up to 5. The measured γ-ray emissivity spectrum is consistent with a model based on CR spectra measured at the Earth and the nuclear enhancement factor of ≤1.5. It is, however, lower than local HI emissivities reported by previous Fermi -LAT studies employing different analysis methods and assumptions on ISM properties by 15%–20% in energies below a few GeV, even if we take account of the statistical and systematic uncertainties. The origin of the discrepancy is also discussed.« less

Neutral hydrogen self-absorption in the Milky Way Galaxy

NASA Astrophysics Data System (ADS)

Kavars, Dain William

2006-06-01

To develop a better understanding of the cold neutral medium phase of the interstellar medium, we present a detailed analysis of neutral hydrogen self- absorption (HISA) clouds in the Milky Way Galaxy. These HISA clouds are in the Southern Galactic Plane Survey (SGPS), spanning the region l = 253°--358° and | b | <= 1.3°, and in the VLA Galactic Plane Survey (VGPS), spanning the region l = 18°--67° and | b | <= 1.3°--2.3°. The SGPS and VGPS have an angular resolution of ~1 arcminute and a velocity channel spacing of 0.82 km s -1 . With the recent completion of these surveys, we can study HISA features across the Galaxy at a much better resolution and sensitivity than any previous work. To analyze HISA in detail, catalogs of clouds of all sizes, including those undetectable by eye alone, are required. We present an automated search routine to detect all HISA clouds in the SGPS. We compare HISA to CO data and find some HISA clouds associated with CO, but others have no associated CO. This suggests that HISA clouds are in a transition between molecular and atomic gas, bridging the gap between dense molecular clouds and warmer, diffuse atomic clouds. HISA thus plays an important role in the overall evolution of the Galaxy. To study this transition further, we present observations of the OH molecule toward a select sample of HISA clouds in the VGPS, using the Green Bank Telescope (GBT). We present an analysis of the molecular properties of this sample, including a derivation of an OH to H 2 conversion factor and H 2 to H I abundance ratios. We discuss the complex relationship between H I, OH, 12 CO, and 13 CO emission. Finally we present a statistical analysis comparing HISA with infrared data from the Galactic Legacy Infrared Mid-Plane Survey Extraordinaire (GLIMPSE) project. The GLIMPSE data reveal a large number of compact, dark infrared clouds believed to be in the early stages of star formation. If GLIMPSE clouds are associated with HISA, they provide valuable information on the evolution of HISA clouds.

Reactions of Azine Anions with Nitrogen and Oxygen Atoms: Implications for Titan's Upper Atmosphere and Interstellar Chemistry.

PubMed

Wang, Zhe-Chen; Cole, Callie A; Demarais, Nicholas J; Snow, Theodore P; Bierbaum, Veronica M

2015-08-26

Azines are important in many extraterrestrial environments, from the atmosphere of Titan to the interstellar medium. They have been implicated as possible carriers of the diffuse interstellar bands in astronomy, indicating their persistence in interstellar space. Most importantly, they constitute the basic building blocks of DNA and RNA, so their chemical reactivity in these environments has significant astrobiological implications. In addition, N and O atoms are widely observed in the ISM and in the ionospheres of planets and moons. However, the chemical reactions of molecular anions with abundant interstellar and atmospheric atomic species are largely unexplored. In this paper, gas-phase reactions of deprotonated anions of benzene, pyridine, pyridazine, pyrimidine, pyrazine, and s-triazine with N and O atoms are studied both experimentally and computationally. In all cases, the major reaction channel is associative electron detachment; these reactions are particularly important since they control the balance between negative ions and free electron densities. The reactions of the azine anions with N atoms exhibit larger rate constants than reactions of corresponding chain anions. The reactions of azine anions with O atoms are even more rapid, with complex product patterns for different reactants. The mechanisms are studied theoretically by employing density functional theory; spin conversion is found to be important in determining some product distributions. The rich gas-phase chemistry observed in this work provides a better understanding of ion-atom reactions and their contributions to ionospheric chemistry as well as the chemical processing that occurs in the boundary layers between diffuse and dense interstellar clouds.

Helical magnetic fields in molecular clouds?. A new method to determine the line-of-sight magnetic field structure in molecular clouds

NASA Astrophysics Data System (ADS)

Tahani, M.; Plume, R.; Brown, J. C.; Kainulainen, J.

2018-06-01

Context. Magnetic fields pervade in the interstellar medium (ISM) and are believed to be important in the process of star formation, yet probing magnetic fields in star formation regions is challenging. Aims: We propose a new method to use Faraday rotation measurements in small-scale star forming regions to find the direction and magnitude of the component of magnetic field along the line of sight. We test the proposed method in four relatively nearby regions of Orion A, Orion B, Perseus, and California. Methods: We use rotation measure data from the literature. We adopt a simple approach based on relative measurements to estimate the rotation measure due to the molecular clouds over the Galactic contribution. We then use a chemical evolution code along with extinction maps of each cloud to find the electron column density of the molecular cloud at the position of each rotation measure data point. Combining the rotation measures produced by the molecular clouds and the electron column density, we calculate the line-of-sight magnetic field strength and direction. Results: In California and Orion A, we find clear evidence that the magnetic fields at one side of these filamentary structures are pointing towards us and are pointing away from us at the other side. Even though the magnetic fields in Perseus might seem to suggest the same behavior, not enough data points are available to draw such conclusions. In Orion B, as well, there are not enough data points available to detect such behavior. This magnetic field reversal is consistent with a helical magnetic field morphology. In the vicinity of available Zeeman measurements in OMC-1, OMC-B, and the dark cloud Barnard 1, we find magnetic field values of - 23 ± 38 μG, - 129 ± 28 μG, and 32 ± 101 μG, respectively, which are in agreement with the Zeeman measurements. Tables 1 to 7 are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/614/A100

Spectroscopy and reactions of molecules important in chemical evolution

NASA Technical Reports Server (NTRS)

Becker, R. S.

1974-01-01

The research includes: (1) hot hydrogen atom reactions in terms of the nature of products produced, mechanism of the reactions and the implication and application of such reactions for molecules existing in interstellar clouds, in planetary atmospheres, and in chemical evolution; (2) photochemical reactions that can lead to molecules important in chemical evolution, interstellar clouds and as constituents in planetary atmospheres; and (3) spectroscopic and theoretical properties of biomolecules and their precursors and where possible, use these to understand their photochemical behavior.

Compression of turbulent magnetized gas in giant molecular clouds

NASA Astrophysics Data System (ADS)

Birnboim, Yuval; Federrath, Christoph; Krumholz, Mark

2018-01-01

Interstellar gas clouds are often both highly magnetized and supersonically turbulent, with velocity dispersions set by a competition between driving and dissipation. This balance has been studied extensively in the context of gases with constant mean density. However, many astrophysical systems are contracting under the influence of external pressure or gravity, and the balance between driving and dissipation in a contracting, magnetized medium has yet to be studied. In this paper, we present three-dimensional magnetohydrodynamic simulations of compression in a turbulent, magnetized medium that resembles the physical conditions inside molecular clouds. We find that in some circumstances the combination of compression and magnetic fields leads to a rate of turbulent dissipation far less than that observed in non-magnetized gas, or in non-compressing magnetized gas. As a result, a compressing, magnetized gas reaches an equilibrium velocity dispersion much greater than would be expected for either the hydrodynamic or the non-compressing case. We use the simulation results to construct an analytic model that gives an effective equation of state for a coarse-grained parcel of the gas, in the form of an ideal equation of state with a polytropic index that depends on the dissipation and energy transfer rates between the magnetic and turbulent components. We argue that the reduced dissipation rate and larger equilibrium velocity dispersion has important implications for the driving and maintenance of turbulence in molecular clouds and for the rates of chemical and radiative processes that are sensitive to shocks and dissipation.

The environment and star formation of H II region Sh2-163: a multi-wavelength study

NASA Astrophysics Data System (ADS)

Yu, Naiping; Wang, Jun-Jie; Li, Nan

2014-12-01

To investigate the environment of H II region Sh2-163 and search for evidence of triggered star formation in this region, we performed a multi-wavelength study of this H II region. Most of our data were taken from large-scale surveys: 2MASS, CGPS, MSX and SCUBA. We also made CO molecular line observations, using the 13.7-m telescope. The ionized region of Sh2-163 is detected by both the optical and radio continuum observations. Sh2-163 is partially bordered by an arc-like photodissociation region (PDR), which is coincident with the strongest optical and radio emissions, indicating interactions between the H II region and the surrounding interstellar medium. Two molecular clouds were discovered on the border of the PDR. The morphology of these two clouds suggests they are compressed by the expansion of Sh2-163. In cloud A, we found two molecular clumps. And it seems star formation in clump A2 is much more active than in clump A1. In cloud B, we found new outflow activities and massive star(s) are forming inside. Using 2MASS photometry, we tried to search for embedded young stellar object (YSO) candidates in this region. The very good agreement between CO emission, infrared shell and YSOs suggest that it is probably a star formation region triggered by the expansion of Sh2-163. We also found the most likely massive protostar related to IRAS 23314+6033.

Testing spatial uniformity of the CR spectrum in the local ISM with γ-ray observations

NASA Astrophysics Data System (ADS)

Prokhorov, D. A.; Colafrancesco, S.

2018-05-01

Gamma-ray observations of nearby radio-line-emitting gas structures in the interstellar medium allow us to probe the spectrum of cosmic rays (CRs). In this paper, we analysed Fermi Large Area Telescope (LAT) γ-ray observations of three such structures located near each other to check if their CR spectra are compatible with that of the CR background or might provide evidence for a population of "fresh" CRs. We found that the shape of the γ-ray spectrum in the Aquarius HI shell is consistent with the previously published stacked γ-ray spectrum of the Gould Belt molecular clouds. We also found that assumptions on the diffuse Galactic γ-ray background affect the spectral shapes of CRs derived in the R Coronae Australis and ρ Ophiuchi molecular clouds in which spectral deviations had previously been suggested. These two facts provide evidence to support the hypothesis of uniformity of the shapes of cosmic ray spectra in the local Galaxy environment.

The formation of stellar systems from interstellar molecular clouds.

PubMed

Gehrz, R D; Black, D C; Solomon, P M

1984-05-25

Star formation, a crucial link in the chain of events that led from the early expansion of the universe to the formation of the solar system, continues to play a major role in the evolution of many galaxies. Observational and theoretical studies of regions of ongoing star formation provide insight into the physical conditions and events that must have attended the formation of the solar system. Such investigations also elucidate the role played by star formation in the evolutionary cycle which appears to dominate the chemical processing of interstellar material by successive generations of stars in spiral galaxies like our own. New astronomical facilities planned for development during the 1980's could lead to significant advances in our understanding of the star formation process. Efforts to identify and examine both the elusive protostellar collapse phase of star formation and planetary systems around nearby stars will be especially significant.

Detection of a new interstellar molecule, H2CN

NASA Technical Reports Server (NTRS)

Ohishi, Masatoshi; Mcgonagle, Douglas; Irvine, William M.; Yamamoto, Satoshi; Saito, Shuji

1994-01-01

We have detected a new interstellar molecule, H2CN (methylene amidogen), in the cold, dark molecular cloud TMC-1. The column density of H2CN is estimated to be approximately 1.5 x 10(exp 11) cm(exp -2) by assuming an excitation temperature of 5 K. This column density corresponds to a fractional abundance relative to H2 of approximately 1.5 x 10(exp -11). This value is more than three orders of magnitude less than the abundance of the related molecule HCN in TMC-1. We also report a tentative detection of H2CN in Sgr B2(N). The formation mechanism of H2CN is discussed. Our detection of the N2CN molecule may suggest the existence of a new series of carbon-chain molecules, CH2C(n)N (N = 0, 1, 2, ...).

Copernicus observations of distant unreddened stars. II - Line of sight to HD 50896

NASA Technical Reports Server (NTRS)

Shull, J. M.

1977-01-01

Copernicus UV data on interstellar lines toward HD 50896, a Wolf-Rayet star, are analyzed to study abundances and physical conditions in the line of sight. About 20% of the low-velocity neutral gas is contained in a dense cloud with 10% to 50% of its hydrogen in molecular form; the atomic abundances show typical interstellar depletions. The low-velocity H II gas may be associated with the high ionizing flux of the Wolf-Rayet star or with H II regions along the line of sight. Si III exhibits strong absorption shortward of the low-velocity H II gas, characteristic of a collisionally ionized component at 30,000 to 80,000 K; the possible connections with an unobserved supernova remnant or stellar mass loss are discussed. High-velocity features at 78 and -96 km/sec, in which Fe and Si are near their cosmic abundances, are also indicative of strong shocks.

KINETIC TOMOGRAPHY. I. A METHOD FOR MAPPING THE MILKY WAY’S INTERSTELLAR MEDIUM IN FOUR DIMENSIONS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tchernyshyov, Kirill; Peek, J. E. G.

2017-01-01

We have developed a method for deriving the distribution of the Milky Way’s interstellar medium as a function of longitude, latitude, distance, and line-of-sight velocity. This method takes as input maps of reddening as a function of longitude, latitude, distance, and maps of line emission as a function of longitude, latitude, and line-of-sight velocity. We have applied this method to data sets covering much of the Galactic plane. The output of this method correctly reproduces the line-of-sight velocities of high-mass star-forming regions with known distances from Reid et al. and qualitatively agrees with results from the Milky Way kinematics literature.more » These maps will be useful for measuring flows of gas around the Milky Way’s spiral arms and into and out of giant molecular clouds.« less

The Anatomy of the Perseus Spiral Arm: 12 CO and IRAS Imaging Observations of the W3-W4-W5 Cloud Complex

NASA Technical Reports Server (NTRS)

Heyer, Mark H.; Terebey, S.

1998-01-01

Panoramic images of 12CO J = 1-0 and thermal dust emissions from the W3-W4-W5 region of the outer Galaxy are presented. These data and recently published H I 21 cm line emission images provide an approximate 1' resolution perspective to the dynamics and thermal energy content of the interstellar gas and dust components contained within a 9 deg. arc of the Perseus spiral arm. We tabulate the molecular properties of 1560 clouds identified as closed surfaces within the l-b-v CO data cube at a threshold of 0.9 K T* (sub R). Relative surface densities of the molecular (28:1) and atomic (2.5:1) gas components determined within the arm and interarm velocity intervals demonstrate that the gas component that enters the spiral arm is predominantly atomic. Molecular clouds must necessarily condense from the compressed atomic material that enters the spiral arm and are likely short lived within the interarm regions. From the distribution of centroid velocities of clouds, we determine a random cloud-to-cloud velocity dispersion of 4 km s (exp. -1) over the width of the spiral arm but find no clear evidence within the molecular gas for streaming motions induced by the spiral potential. The far-infrared images are analyzed with the CO J = 1-0 and H I 21 cm line emission. The enhanced UV (Ultraviolet) radiation field from members of the Cas OB6 association and embedded newborn stars provide a significant source of heating to the extended dust component within the Perseus arm relative to the quiescent cirrus regions. Much of the measured far-infrared flux (69% at 60 micrometers and 47% at 100 micrometers) originates from regions associated with star formation rather than the extended, infrared cirrus component.

The Anatomy of the Perseus Spiral ARM: (sup 12)CO and IRAS Imaging Observations of the W3-W4-W5 Cloud Complex

NASA Technical Reports Server (NTRS)

Heyer, Mark H.; Terebey, S.; Oliversen, R. (Technical Monitor)

1998-01-01

Panoramic images of (sup l2)CO J = 1-0 and thermal dust emissions from the W3-W4-W5 region of the outer Galaxy are presented. These data and recently published H (sub I) 21 cm line emission images provide an approx. 1 min resolution perspective to the dynamics and thermal energy content of the interstellar gas and dust components contained within a 9 deg arc of the Perseus spiral arm. We tabulate the molecular properties of 1560 clouds identified as closed surfaces within the l-b-v CO data cube at a threshold of 0.9 K T(sup *)(sub R). Relative surface densities of the molecular (28:1) and atomic (2.5: 1) gas components determined within the arm and interarm velocity intervals demonstrate that the gas component that enters the spiral arm is predominantly atomic. Molecular clouds must necessarily condense from the compressed atomic material that enters the spiral arm and are likely short lived within the interarm regions. From the distribution of centroid velocities of clouds, we determine a random cloud-to-cloud velocity dispersion of 4 km/s over the width of the spiral arm but find no clear evidence within the molecular gas for streaming motions induced by the spiral potential. The far-infrared images are analyzed with the CO J = 1-0 and H (sub I) 21 cm line emission. The enhanced UV radiation field from members of the Cas OB6 association and embedded newborn stars provide a significant source of heating to the extended dust component within the Perseus arm relative to the quiescent cirrus regions. Much of the measured far-infrared flux (69% at 60 microns and 47% at 100 microns) originates from regions associated with star formation rather than the extended, infrared cirrus component.

High Resolution UV Emission Spectroscopy of Molecules Excited by Electron Impact

NASA Technical Reports Server (NTRS)

James, G. K.; Ajello, J. M.; Beegle, L.; Ciocca, M.; Dziczek, D.; Kanik, I.; Noren, C.; Jonin, C.; Hansen, D.

1999-01-01

Photodissociation via discrete line absorption into predissociating Rydberg and valence states is the dominant destruction mechanism of CO and other molecules in the interstellar medium and molecular clouds. Accurate values for the rovibronic oscillator strengths of these transitions and predissociation yields of the excited states are required for input into the photochemical models that attempt to reproduce observed abundances. We report here on our latest experimental results of the electron collisional properties of CO and N2 obtained using the 3-meter high resolution single-scattering spectroscopic facility at JPL.

SH Observations In and Toward Sgr B2(N): Linking the Missing Sulfur

NASA Astrophysics Data System (ADS)

McCarthy, Michael

Where is the missing sulfur in the molecular reservoir of the interstellar medium (ISM)? In the warm gas phase ISM, the abundance of sulfur is nearly equivalent to its solar value, but in the cold, diffuse clouds which span the space between stars, sulfur is depleted by several orders of magnitude. Our inability to account for this depletion represents a significant gap in our understanding of the fundamental chemical and physical processes occurring in the primordial reservoirs of gas and dust in the ISM. Central to this chemistry is SH, a radical for which few observations presently exist, and for which SOFIA is uniquely capable of accessing in its ground rotational state. We propose observations of SH in the cold, shocked molecular shell surrounding Sgr B2(N), and, simultaneously, in diffuse and translucent clouds along the line of sight to Sgr B2(N). We will constrain the abundance of SH, and compare it to previous measurements of SO, CS, C_2S, HCS(+) , H_2CS, and H_2S in these sources which span the evolutionary timescale from diffuse clouds to dense, cold shocked regions.

Chemistry in dynamically evolving clouds

NASA Technical Reports Server (NTRS)

Tarafdar, S. P.; Prasad, S. S.; Huntress, W. T., Jr.; Villere, K. R.; Black, D. C.

1985-01-01

A unified model of chemical and dynamical evolution of isolated, initially diffuse and quiescent interstellar clouds is presented. The model uses a semiempirically derived dependence of the observed cloud temperatures on the visual extinction and density. Even low-mass, low-density, diffuse clouds can collapse in this model, because the inward pressure gradient force assists gravitational contraction. In contrast, previous isothermal collapse models required the low-mass diffuse clouds to be unrealistically cold before gravitational contraction could start. Theoretically predicted dependences of the column densities of various atoms and molecules, such as C and CO, on visual extinction in diffuse clouds are in accord with observations. Similarly, the predicted dependences of the fractional abundances of various chemical species (e.g., CO, H2CO, HCN, HCO(+)) on the total hydrogen density in the core of the dense clouds also agree with observations reported to date in the literature. Compared with previous models of interstellar chemistry, the present model has the potential to explain the wide spectrum of chemical and physical properties of both diffuse and dense clouds with a common formalism employing only a few simple initial conditions.

Are comets connected to the origin of life

NASA Technical Reports Server (NTRS)

Delsemme, A. H.

1981-01-01

Possible connections between comets and the origin of life on earth are discussed. The orbital evolution of comets and their origin are considered within a framework for the origin of the solar system, with particular attention given to the origin of the biosphere, and the origin of the Oort cloud. Evidence suggesting that cometary nuclei are undifferentiated throughout is considered, and a model of the average composition of a mean new comet is obtained from observational data which is similar to that of an interstellar frost. The chemistry of the model composition giving rise to the species observed in cometary spectra is considered, as well as the relations of cometary to cosmic abundances of oxygen, carbon and sulfur. The characteristics of possible sites for prebiotic chemistry, including interstellar clouds, the protosolar nebula, comets in the Oort cloud, periodic comets and the primitive earth, are examined, and a possible role of comets in bringing the interstellar prebiotic chemistry to earth is suggested.

Dust near luminous ultraviolet stars

NASA Technical Reports Server (NTRS)

Henry, Richard C.

1993-01-01

This report describes research activities related to the Infrared Astronomical Satellite (IRAS) sky survey. About 745 luminous stars were examined for the presence of interstellar dust heated by a nearby star. The 'cirrus' discovered by IRAS is thermal radiation from interstellar dust at moderate and high galactic latitudes. The IRAS locates the dust which must (at some level) scatter ultraviolet starlight, although it was expected that thermal emission would be found around virtually every star, most stars shown no detectable emission. And the emission found is not uniform. It is not that the star is embedded in 'an interstellar medium', but rather what is found are discrete clouds that are heated by starlight. An exception is the dearth of clouds near the very hottest stars, implying that the very hottest stars play an active role with respect to destroying or substantially modifying the dust clouds over time. The other possibility is simply that the hottest stars are located in regions lacking in dust, which is counter-intuitive. A bibliography of related journal articles is attached.

Measuring the Dust Grains and Distance to X Persei Via Its X-ray Halo

NASA Astrophysics Data System (ADS)

Smith, Randall

2006-09-01

We propose to observe the X-ray halo of the high mass X-ray binary pulsar X Per to measure interstellar dust grains along the line of sight (LOS) and to determine the distance to X Per. The X-ray halo is formed by scattering from grains along the LOS, which for X Per appear to be concentrated in one molecular cloud. Unlike many other X-ray halo observations, this low-absorption high-latitude sightline is well-characterized from absorption spectroscopy done with HST, Copernicus, and FUSE. This halo observation will measure the distance to the cloud and the dust size distribution in it. We will also be able to determine the distance to X Per by measuring the time delayed pulses in the X-ray halo.

Ultraviolet photometry from the orbiting astronomical observatory. XXX - The Orion reflection nebulosity

NASA Technical Reports Server (NTRS)

Witt, A. N.; Lillie, C. F.

1978-01-01

Surface-brightness measurements are presented that cover the region of Orion in nine intermediate-width bandpasses ranging from 4250 to 1550 A. The existence of an extended ultraviolet reflection nebulosity in this area is confirmed, and the characteristics of its spectrum and spatial distribution are derived. The observations are consistent with a model in which the dense molecular cloud complex in Orion is illuminated by the foreground Orion aggregate of early-type stars. The interpretation is complicated by the fact that foreground dust may contribute to the observed scattered light. The scattering particles in the cloud appear to exhibit a wavelength-dependent albedo similar to that found for interstellar grains in general, with a strong indication that the phase function changes to a less forward-scattering form in the ultraviolet.

IR Laboratory Astrophysics at Forty: Some Highlights and a Look to the Future

NASA Astrophysics Data System (ADS)

Allamandola, Louis John

2016-06-01

Space was thought to be chemically barren until about forty years ago. Astrochemistry was in its infancy, the composition of interstellar dust was largely guessed at, the presence of mixed molecular ices in dense molecular clouds was not taken seriously, and the notion of large, gas phase, carbon-rich molecules (PAHs) abundant and widespread throughout the interstellar medium (ISM) was inconceivable. The rapid development of infrared astronomy between 1970 and 1985, especially observations made by the Kuiper Airborne Observatory (KAO) and the Infrared Astronomical Satellite IRAS), which made it possible to measure mid-infrared spectra between 2.5 to 14 µm, changed all that. Since then observations made from ground-based, airborne and orbiting IR telescopes, together with radio and submm observations, have revealed that we live in a Universe that is not a hydrogen-dominated, physicist's paradise, but in a molecular Universe with complex molecules directly interwoven into its fabric. Today we recognize that molecules are an abundant and important component of astronomical objects at all stages of their evolution and that they play important roles in many processes that contribute to the structure and evolution of galaxies. Furthermore, many of these organic molecules are thought to be delivered to habitable planets such as Earth, and their composition may be related to the origin of life. Laboratory astrophysics has been key to making this great progress; progress which has only been made possible thanks to the close collaboration of laboratory experimentalists with astronomers and theoreticians. These collaborations are essential to meet the growing interdisciplinary challenges posed by astrophysics. This talk will touch on some of the milestones that have been reached in IR astrospectroscopy over the past four decades, focusing on the experimental work that revealed the widespread presence of interstellar PAHs and the composition of interstellar/precometary ices, and concluding with a personal view of important, key objectives in each area

New Large Interstellar Molecules Detected with the GBT

NASA Technical Reports Server (NTRS)

Hollis, Jan M.

2005-01-01

At present, more than 135 different molecules have been identified in interstellar clouds. The newest instrument in the interstellar molecule search arsenal is the recently commissioned Green Bank Telescope (GBT). In 2004, the large aldehydes propenal (CH2CHCHO) and propanal (CH3CH2CHO) were the first new interstellar molecules discovered with the GBT. At the same time, the GBT was used to observe interstellar glycolaldehyde (CH2OHCHO), which is the simplest possible aldehyde sugar; interstellar ethylene glycol (HOCH2CH2OH), which is the sugar alcohol of glycolaldehyde; and interstellar methylcyanodiacetylene (CH3C5N). These new GBT observations suggest that successive atomic addition reactions are common in the formation of larger related species. The observations will be presented and discussed.

Mapping the Frozen Void

NASA Astrophysics Data System (ADS)

Suutarinen, Aleksi; Fraser, Helen

2013-07-01

Reactions on the surfaces of dust grains play a vital role in the overall chemistry of interstellar matter. These grains become covered by icy layers, which are the largest molecular reservoir in the interstellar medium. Given this, it is surprising that the effect ice has on the overall chain of reactions is poorly characterized. One step on the path of gaining better understanding here is to develop methods of figuring out how much ice is present in these clouds, the links between ice components, and synergy between the ices and gas phase molecules. We do this by examining the absorption spectra of ices on lines of sight towards several stars behind clouds of interstellar matter. From these we can reconstruct spatial maps of the ice distribution on scales of as little as 1000 AU, as a test of the chemical variation within a cloud. By overlapping the ice data with other maps of the same region (gas emission, temperature, density etc) we create combined maps to reveal the astrochemistry of star-forming regions and pre-stellar cores. In this poster we present the continuing results of our ice mapping programme, using data from the AKARI satellite, specifically in slitless spectroscopy observations in the NIR. In this region the key ice features encompass H2O, CO and CO2. The maps illustrate the power of our dedicated AKARI data reduction pipeline, and the novelty of our observing programme. We also detail the next steps' in our ice mapping research. The method is being expanded to include the full 10'x10' AKARI field of view, taking account of image distortion induced by the dispersing optics. These maps are then combined with exiting gas-phase observations and SCUBA maps. The latest attempts at this are shown here. What is clear already is that it is difficult to predict ice abundances from factors such as extinction or gas density alone, and that ice formation and evolution can vary hugely over even very small astronomical scales.

Planck early results. XXIV. Dust in the diffuse interstellar medium and the Galactic halo

NASA Astrophysics Data System (ADS)

Planck Collaboration; Abergel, A.; Ade, P. A. R.; Aghanim, N.; Arnaud, M.; Ashdown, M.; Aumont, J.; Baccigalupi, C.; Balbi, A.; Banday, A. J.; Barreiro, R. B.; Bartlett, J. G.; Battaner, E.; Benabed, K.; Benoît, A.; Bernard, J.-P.; Bersanelli, M.; Bhatia, R.; Blagrave, K.; Bock, J. J.; Bonaldi, A.; Bond, J. R.; Borrill, J.; Bouchet, F. R.; Boulanger, F.; Bucher, M.; Burigana, C.; Cabella, P.; Cantalupo, C. M.; Cardoso, J.-F.; Catalano, A.; Cayón, L.; Challinor, A.; Chamballu, A.; Chiang, L.-Y.; Chiang, C.; Christensen, P. R.; Clements, D. L.; Colombi, S.; Couchot, F.; Coulais, A.; Crill, B. P.; Cuttaia, F.; Danese, L.; Davies, R. D.; Davis, R. J.; de Bernardis, P.; de Gasperis, G.; de Rosa, A.; de Zotti, G.; Delabrouille, J.; Delouis, J.-M.; Désert, F.-X.; Dickinson, C.; Donzelli, S.; Doré, O.; Dörl, U.; Douspis, M.; Dupac, X.; Efstathiou, G.; Enßlin, T. A.; Eriksen, H. K.; Finelli, F.; Forni, O.; Frailis, M.; Franceschi, E.; Galeotta, S.; Ganga, K.; Giard, M.; Giardino, G.; Giraud-Héraud, Y.; González-Nuevo, J.; Górski, K. M.; Gratton, S.; Gregorio, A.; Gruppuso, A.; Hansen, F. K.; Harrison, D.; Helou, G.; Henrot-Versillé, S.; Herranz, D.; Hildebrandt, S. R.; Hivon, E.; Hobson, M.; Holmes, W. A.; Hovest, W.; Hoyland, R. J.; Huffenberger, K. M.; Jaffe, A. H.; Joncas, G.; Jones, A.; Jones, W. C.; Juvela, M.; Keihänen, E.; Keskitalo, R.; Kisner, T. S.; Kneissl, R.; Knox, L.; Kurki-Suonio, H.; Lagache, G.; Lamarre, J.-M.; Lasenby, A.; Laureijs, R. J.; Lawrence, C. R.; Leach, S.; Leonardi, R.; Leroy, C.; Linden-Vørnle, M.; Lockman, F. J.; López-Caniego, M.; Lubin, P. M.; Macías-Pérez, J. F.; MacTavish, C. J.; Maffei, B.; Maino, D.; Mandolesi, N.; Mann, R.; Maris, M.; Marshall, D. J.; Martin, P.; Martínez-González, E.; Masi, S.; Matarrese, S.; Matthai, F.; Mazzotta, P.; McGehee, P.; Meinhold, P. R.; Melchiorri, A.; Mendes, L.; Mennella, A.; Miville-Deschênes, M.-A.; Moneti, A.; Montier, L.; Morgante, G.; Mortlock, D.; Munshi, D.; Murphy, A.; Naselsky, P.; Nati, F.; Natoli, P.; Netterfield, C. B.; Nørgaard-Nielsen, H. U.; Noviello, F.; Novikov, D.; Novikov, I.; O'Dwyer, I. J.; Osborne, S.; Pajot, F.; Paladini, R.; Pasian, F.; Patanchon, G.; Perdereau, O.; Perotto, L.; Perrotta, F.; Piacentini, F.; Piat, M.; Pinheiro Gonçalves, D.; Plaszczynski, S.; Pointecouteau, E.; Polenta, G.; Ponthieu, N.; Poutanen, T.; Prézeau, G.; Prunet, S.; Puget, J.-L.; Rachen, J. P.; Reach, W. T.; Reinecke, M.; Renault, C.; Ricciardi, S.; Riller, T.; Ristorcelli, I.; Rocha, G.; Rosset, C.; Rowan-Robinson, M.; Rubiño-Martín, J. A.; Rusholme, B.; Sandri, M.; Santos, D.; Savini, G.; Scott, D.; Seiffert, M. D.; Shellard, P.; Smoot, G. F.; Starck, J.-L.; Stivoli, F.; Stolyarov, V.; Stompor, R.; Sudiwala, R.; Sygnet, J.-F.; Tauber, J. A.; Terenzi, L.; Toffolatti, L.; Tomasi, M.; Torre, J.-P.; Tristram, M.; Tuovinen, J.; Umana, G.; Valenziano, L.; Vielva, P.; Villa, F.; Vittorio, N.; Wade, L. A.; Wandelt, B. D.; Wilkinson, A.; Yvon, D.; Zacchei, A.; Zonca, A.

2011-12-01

This paper presents the first results from a comparison of Planck dust maps at 353, 545 and 857GHz, along with IRAS data at 3000 (100 μm) and 5000GHz (60 μm), with Green Bank Telescope 21-cm observations of Hi in 14 fields covering more than 800 deg2 at high Galactic latitude. The main goal of this study is to estimate the far-infrared to sub-millimeter (submm) emissivity of dust in the diffuse local interstellar medium (ISM) and in the intermediate-velocity (IVC) and high-velocity clouds (HVC) of the Galactic halo. Galactic dust emission for fields with average Hi column density lower than 2 × 1020 cm-2 is well correlated with 21-cm emission because in such diffuse areas the hydrogen is predominantly in the neutral atomic phase. The residual emission in these fields, once the Hi-correlated emission is removed, is consistent with the expected statistical properties of the cosmic infrared background fluctuations. The brighter fields in our sample, with an average Hi column density greater than 2 × 1020 cm-2, show significant excess dust emission compared to the Hi column density. Regions of excess lie in organized structures that suggest the presence of hydrogen in molecular form, though they are not always correlated with CO emission. In the higher Hi column density fields the excess emission at 857 GHz is about 40% of that coming from the Hi, but over all the high latitude fields surveyed the molecular mass faction is about 10%. Dust emission from IVCs is detected with high significance by this correlation analysis. Its spectral properties are consistent with, compared to the local ISM values, significantly hotter dust (T ~ 20K), lower submm dust opacity normalized per H-atom, and a relative abundance of very small grains to large grains about four times higher. These results are compatible with expectations for clouds that are part of the Galactic fountain in which there is dust shattering and fragmentation. Correlated dust emission in HVCs is not detected; the average of the 99.9% confidence upper limits to the emissivity is 0.15 times the local ISM value at 857 and 3000GHz, in accordance with gas phase evidence for lower metallicity and depletion in these clouds. Unexpected anti-correlated variations of the dust temperature and emission cross-section per H atom are identified in the local ISM and IVCs, a trend that continues into molecular environments. This suggests that dust growth through aggregation, seen in molecular clouds, is active much earlier in the cloud condensation and star formation processes. Corresponding author: M.-A. Miville-Deschênes, e-mail: mamd@ias.u-psud.fr

Goulds Belt, Interstellar Clouds, and the Eocene Oligocene Helium-3 Enhancement

NASA Technical Reports Server (NTRS)

Rubincam, David Parry

2015-01-01

Drag from hydrogen in the interstellar cloud which formed Gould's Belt may have sent interplanetary dust particle (IDPs) and small meteoroids with embedded helium to the Earth, perhaps explaining part the helium-3 flux increase seen in the sedimentary record near the Eocene-Oligocene transition. Assuming the Solar System passed through part of the cloud, IDPs in the inner Solar System may have been dragged to Earth, while dust and small meteoroids in the asteroid belt up to centimeter size may have been dragged to the resonances, where their orbital eccentricities were pumped up into Earth-crossing orbits; however, this hypotheses does not explain the Popigai and Chesapeake Bay impacts.

A search with Copernicus for interstellar N2 in diffuse clouds

NASA Technical Reports Server (NTRS)

Lutz, B. L.; Snow, T. P., Jr.; Owen, T.

1979-01-01

Multiple Copernicus scans of two N2 band regions (near 958.5 and 960.2A) of Delta Sco and Epsilon Per are reported. The observations indicate upper limits for the number of N2 molecules equal to 1.0-3.8 times 10 to the -12th/sq cm and 1.2-4.4 times 10 to the -12th/sq cm, respectively; the limits depend on the cloud temperature. It is suggested that the limits are consistent with the column densities predicted by chemical models for diffuse interstellar clouds, and the predicted relative abundances are presented in terms of the ratio of N(N2)/(2N(H2) + N(Hl)).

The 15 273 Å diffuse interstellar band in the dark cloud Barnard 68

NASA Astrophysics Data System (ADS)

Elyajouri, Meriem; Cox, Nick L. J.; Lallement, Rosine

2017-09-01

High obscuration of background stars behind dark clouds precludes the detection of optical diffuse interstellar bands (DIBs) and hence our knowledge of DIB carriers in these environments. Taking advantage of the reduced obscuration of starlight in the near-infrared (NIR) we used one of the strongest NIR DIBs at 15 273 Å to probe the presence and properties of its carrier throughout the nearby interstellar dark cloud Barnard 68. We measured equivalent widths (EW) for different ranges of visual extinction AV, using VLT/KMOS H-band (1.46-1.85 μm) moderate-resolution (R 4000) spectra of 43 stars situated behind the cloud. To do so, we fitted the data with synthetic stellar spectra from the APOGEE project and TAPAS synthetic telluric transmissions appropriate for the observing site and time period. The results show an increase of DIB EW with increasing AV. However, the rate of increase is much flatter than expected from the EW-AV quasi-proportionality established for this DIB in the Galactic diffuse interstellar medium. Based on a simplified inversion assuming sphericity, it is found that the volume density of the DIB carrier is 2.7 and 7.9 times lower than this expected average value in the external and central regions of the cloud, which have nH≃ 0.4 and 3.5 × 105 cm-3, respectively. Further measurements with multiplex NIR spectrographs should allow detailed modeling of such an edge effect of this DIB and other bands and help clarify its actual origin. Based on observations collected at the European Organisation for Astronomical Research in the Southern Hemisphere under ESO programme 096.C-0931(A).

The cosmic-ray and gas content of the Cygnus region as measured in γ -rays by the Fermi Large Area Telescope

DOE PAGES

Ackermann, M.

2012-02-01

Context. The Cygnus region hosts a giant molecular-cloud complex that actively forms massive stars. Interactions of cosmic rays with interstellar gas and radiation fields make it shine at γ-ray energies. Several γ-ray pulsars and other energetic sources are seen in this direction. Aims. In this paper we analyze the γ-ray emission measured by the Fermi Large Area Telescope in the energy range from 100 MeV to 100 GeV in order to probe the gas and cosmic-ray content on the scale of the whole Cygnus complex. The γ-ray emission on the scale of the central massive stellar clusters and from individualmore » sources is addressed elsewhere. Methods. The signal from bright pulsars is greatly reduced by selecting photons in their off-pulse phase intervals. We compare the diffuse γ-ray emission with interstellar gas maps derived from radio/mm-wave lines and visual extinction data. A general model of the region, including other pulsars and γ-ray sources, is sought. Results. The integral Hi emissivity above 100 MeV averaged over the whole Cygnus complex amounts to [2.06 ± 0.11 (stat.) +0.15 -0.84 (syst.)] × 10 -26 photons s -1 sr -1 H-atom -1, where the systematic error is dominated by the uncertainty on the Hi opacity to calculate its column densities. The integral emissivity and its spectral energy distribution are both consistent within the systematics with LAT measurements in the interstellar space near the solar system. The average XCO = N(H2)/WCO ratio is found to be [1.68 ± 0.05 (stat.) +0.87 -0.10 (Hi opacity)] × 1020 molecules cm -2 (K km s -1) -1, consistent with other LAT measurements in the Local Arm. We detect significant γ-ray emission from dark neutral gas for a mass corresponding to ~ 40% of what is traced by CO. The total interstellar mass in the Cygnus complex inferred from its γ-ray emission amounts to 8 +5 -1 × 106M⊙ at a distance of 1.4 kpc. Conclusions. Despite the conspicuous star formation activity and high masses of the interstellar clouds, the cosmic-ray population in the Cygnus complex averaged over a few hundred parsecs is similar to that of the local interstellar space.« less

The Cosmic-Ray and Gas Content of the Cygnus Region as Measured in Gamma Rays by the Fermi Large Area Telescope

NASA Technical Reports Server (NTRS)

Ackermann, M.; Ajello, M.; Allafort, A.; Baldini, L.; Ballet, J.; Barbiellini, G.; Bastieri, D.; Belfiore, A.; Bellazzini, R.; Berenji, B.;

TEMPERATURE SPECTRA OF INTERSTELLAR DUST GRAINS HEATED BY COSMIC RAYS. I. TRANSLUCENT CLOUDS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kalvāns, Juris, E-mail: juris.kalvans@venta.lv

Heating of whole interstellar dust grains by cosmic-ray (CR) particles affects the gas–grain chemistry in molecular clouds by promoting molecule desorption, diffusion, and chemical reactions on grain surfaces. The frequency of such heating, f{sub T}, s{sup −1}, determines how often a certain temperature T{sub CR}, K, is reached for grains hit by CR particles. This study aims to provide astrochemists with a comprehensive and updated data set on CR-induced whole-grain heating. We present calculations of f{sub T} and T{sub CR} spectra for bare olivine grains with radius a of 0.05, 0.1, and 0.2 μ m and such grains covered withmore » ice mantles of thickness 0.1 a and 0.3 a . Grain shape and structure effects are considered, as well as 30 CR elemental constituents with an updated energy spectrum corresponding to a translucent cloud with A{sub V} = 2 mag. Energy deposition by CRs in grain material was calculated with the srim program. We report full T{sub CR} spectra for all nine grain types and consider initial grain temperatures of 10 K and 20 K. We also provide frequencies for a range of minimum T{sub CR} values. The calculated data set can be simply and flexibly implemented in astrochemical models. The results show that, in the case of translucent clouds, the currently adopted rate for heating of whole grains to temperatures in excess of 70 K is underestimated by approximately two orders of magnitude in astrochemical numerical simulations. Additionally, grains are heated by CRs to modest temperatures (20–30 K) with intervals of a few years, which reduces the possibility of ice chemical explosions.« less

The frequency and nature of `cloud-cloud collisions' in galaxies

NASA Astrophysics Data System (ADS)

Dobbs, C. L.; Pringle, J. E.; Duarte-Cabral, A.

2015-02-01

We investigate cloud-cloud collisions and giant molecular cloud evolution in hydrodynamic simulations of isolated galaxies. The simulations include heating and cooling of the interstellar medium (ISM), self-gravity and stellar feedback. Over time-scales <5 Myr most clouds undergo no change, and mergers and splits are found to be typically two-body processes, but evolution over longer time-scales is more complex and involves a greater fraction of intercloud material. We find that mergers or collisions occur every 8-10 Myr (1/15th of an orbit) in a simulation with spiral arms, and once every 28 Myr (1/5th of an orbit) with no imposed spiral arms. Both figures are higher than expected from analytic estimates, as clouds are not uniformly distributed in the galaxy. Thus, clouds can be expected to undergo between zero and a few collisions over their lifetime. We present specific examples of cloud-cloud interactions in our results, including synthetic CO maps. We would expect cloud-cloud interactions to be observable, but find they appear to have little or no impact on the ISM. Due to a combination of the clouds' typical geometries, and moderate velocity dispersions, cloud-cloud interactions often better resemble a smaller cloud nudging a larger cloud. Our findings are consistent with the view that spiral arms make little difference to overall star formation rates in galaxies, and we see no evidence that collisions likely produce massive clusters. However, to confirm the outcome of such massive cloud collisions we ideally need higher resolution simulations.

Chemical Complexity in Local Diffuse and Translucent Clouds: Ubiquitous Linear C3H and CH3CN, a Detection of HC3N and an Upper Limit on the Abundance of CH2CN

NASA Astrophysics Data System (ADS)

Liszt, Harvey; Gerin, Maryvonne; Beasley, Anthony; Pety, Jerome

2018-04-01

We present Jansky Very Large Array observations of 20–37 GHz absorption lines from nearby Galactic diffuse molecular gas seen against four cosmologically distant compact radio continuum sources. The main new observational results are that l-C3H and CH3CN are ubiqitous in the local diffuse molecular interstellar medium at {\\text{}}{A}{{V}} ≲ 1, while HC3N was seen only toward B0415 at {\\text{}}{A}{{V}} > 4 mag. The linear/cyclic ratio is much larger in C3H than in C3H2 and the ratio CH3CN/HCN is enhanced compared to TMC-1, although not as much as toward the Horsehead Nebula. More consequentially, this work completes a long-term program assessing the abundances of small hydrocarbons (CH, C2H, linear and cyclic C3H and C3 {{{H}}}2, and C4H and C4H‑) and the CN-bearing species (CN, HCN, HNC, HC3N, HC5N, and CH3CN): their systematics in diffuse molecular gas are presented in detail here. We also observed but did not strongly constrain the abundances of a few oxygen-bearing species, most prominently HNCO. We set limits on the column density of CH2CN, such that the anion CH2CN‑ is only viable as a carrier of diffuse interstellar bands if the N(CH2CN)/N(CH2CN‑) abundance ratio is much smaller in this species than in any others for which the anion has been observed. We argue that complex organic molecules (COMS) are not present in clouds meeting a reasonable definition of diffuse molecular gas, i.e., {\\text{}}{A}{{V}} ≲ 1 mag. Based on observations obtained with the NRAO Jansky Very Large Array (VLA).

Detection of organic matter in interstellar grains.

PubMed

Pendleton, Y J

1997-06-01

Star formation and the subsequent evolution of planetary systems occurs in dense molecular clouds, which are comprised, in part, of interstellar dust grains gathered from the diffuse interstellar medium (DISM). Radio observations of the interstellar medium reveal the presence of organic molecules in the gas phase and infrared observational studies provide details concerning the solid-state features in dust grains. In particular, a series of absorption bands have been observed near 3.4 microns (approximately 2940 cm-1) towards bright infrared objects which are seen through large column densities of interstellar dust. Comparisons of organic residues, produced under a variety of laboratory conditions, to the diffuse interstellar medium observations have shown that aliphatic hydrocarbon grains are responsible for the spectral absorption features observed near 3.4 microns (approximately 2940 cm-1). These hydrocarbons appear to carry the -CH2- and -CH3 functional groups in the abundance ratio CH2/CH3 approximately 2.5, and the amount of carbon tied up in this component is greater than 4% of the cosmic carbon available. On a galactic scale, the strength of the 3.4 microns band does not scale linearly with visual extinction, but instead increases more rapidly for objects near the Galactic Center. A similar trend is noted in the strength of the Si-O absorption band near 9.7 microns. The similar behavior of the C-H and Si-O stretching bands suggests that these two components may be coupled, perhaps in the form of grains with silicate cores and refractory organic mantles. The ubiquity of the hydrocarbon features seen in the near infrared near 3.4 microns throughout out Galaxy and in other galaxies demonstrates the widespread availability of such material for incorporation into the many newly forming planetary systems. The similarity of the 3.4 microns features in any organic material with aliphatic hydrocarbons underscores the need for complete astronomical observational coverage in the 2-30 microns region, of lines of sight which sample dust in both dense and diffuse interstellar clouds, in order to uniquely specify the composition of interstellar organics. This paper reviews the information available from ground-based observations, although currently the Infrared Satellite Observatory is adding to our body of knowledge on this subject by providing more extensive wavelength coverage. The Murchison carbonaceous meteorite has also been used as an analog to the interstellar observations and has revealed a striking similarity between the light hydrocarbons in the meteorite and the ISM; therefore this review includes comparisons with the meteoritic analog as well as with relevant laboratory residues. Fundamental to the evolution of the biogenic molecules, to the process of planetary system formation, and perhaps to the origin of life, is the connection between the organic material found in the interstellar medium and that incorporated in the most primitive solar system bodies.

Interpreting the sub-linear Kennicutt-Schmidt relationship: the case for diffuse molecular gas

NASA Astrophysics Data System (ADS)

Shetty, Rahul; Clark, Paul C.; Klessen, Ralf S.

2014-08-01

Recent statistical analysis of two extragalactic observational surveys strongly indicate a sub-linear Kennicutt-Schmidt (KS) relationship between the star formation rate (ΣSFR) and molecular gas surface density (Σmol). Here, we consider the consequences of these results in the context of common assumptions, as well as observational support for a linear relationship between ΣSFR and the surface density of dense gas. If the CO traced gas depletion time (τ_dep^CO) is constant, and if CO only traces star-forming giant molecular clouds (GMCs), then the physical properties of each GMC must vary, such as the volume densities or star formation rates. Another possibility is that the conversion between CO luminosity and Σmol, the XCO factor, differs from cloud-to-cloud. A more straightforward explanation is that CO permeates the hierarchical interstellar medium, including the filaments and lower density regions within which GMCs are embedded. A number of independent observational results support this description, with the diffuse gas comprising at least 30 per cent of the total molecular content. The CO bright diffuse gas can explain the sub-linear KS relationship, and consequently leads to an increasing τ_dep^CO with Σmol. If ΣSFR linearly correlates with the dense gas surface density, a sub-linear KS relationship indicates that the fraction of diffuse gas fdiff grows with Σmol. In galaxies where Σmol falls towards the outer disc, this description suggests that fdiff also decreases radially.

15N fractionation in star-forming regions and Solar System objects

NASA Astrophysics Data System (ADS)

Wirström, Eva; Milam, Stefanie; Adande, Gilles; Charnley, Steven B.; Cordiner, Martin A.

2015-08-01

A central issue for understanding the formation and evolution of matter in the early Solar System is the relationship between the chemical composition of star-forming interstellar clouds and that of primitive Solar System materials. The pristine molecular content of comets, interplanetary dust particles and carbonaceous chondrites show significant bulk nitrogen isotopic fractionation relative to the solar value, 14N/15N ~ 440. In addition, high spatial resolution measurements in primitive materials locally show even more extreme enhancements of 14N/15N < 100.The coherent 15N enrichment in comets from different formation zones suggests that these isotopic enhancements are remnants of the interstellar chemistry in the natal molecular cloud core and the outer protosolar nebula. Indeed, early chemical models of gas-phase ion-molecule nitrogen fractionation showed that HCN and HNC (nitriles) can hold significant 15N enrichments in cold dark clouds where CO is depleted onto dust grains. In addition, 15N fractionation in nitriles and amines (NH2, NH3) follow different chemical pathways. More recently we have shown that once the spin-state dependence in rates of reactions with H2 is included in the models, amines can either be enhanced or depleted in 15N, depending on the core’s evolutionary stage. Observed 15N fractionation in amines and nitriles therefore cannot be expected to be the same, instead their ratio is a potential chemical clock.Observations of molecular isotope ratios in dark cores are challenging. Limited published results in general show higher 15N/14N ratios in HCN and HNC than ammonia, but more measurements are necessary to confirm these trends. We will present recent results from our ongoing observing campaign of 14N/15N isotopic ratios in HCN, HNC and NH3 in dense cores and protostars which seem consistent with significant fractionation in nitriles as compared to other molecules in each object. The few 14N/15N ratios observed in N2H+ are similar to those in NH3, contrary to our model results which predict a significant 15N enhancement in N2 and N2H+. Model upgrades which may address this discrepancy will be presented and discussed.

DUST AND GAS IN THE MAGELLANIC CLOUDS FROM THE HERITAGE HERSCHEL KEY PROJECT. II. GAS-TO-DUST RATIO VARIATIONS ACROSS INTERSTELLAR MEDIUM PHASES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Roman-Duval, Julia; Gordon, Karl D.; Meixner, Margaret

2014-12-20

The spatial variations of the gas-to-dust ratio (GDR) provide constraints on the chemical evolution and lifecycle of dust in galaxies. We examine the relation between dust and gas at 10-50 pc resolution in the Large and Small Magellanic Clouds (LMC and SMC) based on Herschel far-infrared (FIR), H I 21 cm, CO, and Hα observations. In the diffuse atomic interstellar medium (ISM), we derive the GDR as the slope of the dust-gas relation and find GDRs of 380{sub −130}{sup +250} ± 3 in the LMC, and 1200{sub −420}{sup +1600} ± 120 in the SMC, not including helium. The atomic-to-molecular transition is locatedmore » at dust surface densities of 0.05 M {sub ☉} pc{sup –2} in the LMC and 0.03 M {sub ☉} pc{sup –2} in the SMC, corresponding to A {sub V} ∼ 0.4 and 0.2, respectively. We investigate the range of CO-to-H{sub 2} conversion factor to best account for all the molecular gas in the beam of the observations, and find upper limits on X {sub CO} to be 6 × 10{sup 20} cm{sup –2} K{sup –1} km{sup –1} s in the LMC (Z = 0.5 Z {sub ☉}) at 15 pc resolution, and 4 × 10{sup 21} cm{sup –2} K{sup –1} km{sup –1} s in the SMC (Z = 0.2 Z {sub ☉}) at 45 pc resolution. In the LMC, the slope of the dust-gas relation in the dense ISM is lower than in the diffuse ISM by a factor ∼2, even after accounting for the effects of CO-dark H{sub 2} in the translucent envelopes of molecular clouds. Coagulation of dust grains and the subsequent dust emissivity increase in molecular clouds, and/or accretion of gas-phase metals onto dust grains, and the subsequent dust abundance (dust-to-gas ratio) increase in molecular clouds could explain the observations. In the SMC, variations in the dust-gas slope caused by coagulation or accretion are degenerate with the effects of CO-dark H{sub 2}. Within the expected 5-20 times Galactic X {sub CO} range, the dust-gas slope can be either constant or decrease by a factor of several across ISM phases. Further modeling and observations are required to break the degeneracy between dust grain coagulation, accretion, and CO-dark H{sub 2}. Our analysis demonstrates that obtaining robust ISM masses remains a non-trivial endeavor even in the local Universe using state-of-the-art maps of thermal dust emission.« less

Observational evidence of dust evolution in galactic extinction curves

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cecchi-Pestellini, Cesare; Casu, Silvia; Mulas, Giacomo

Although structural and optical properties of hydrogenated amorphous carbons are known to respond to varying physical conditions, most conventional extinction models are basically curve fits with modest predictive power. We compare an evolutionary model of the physical properties of carbonaceous grain mantles with their determination by homogeneously fitting observationally derived Galactic extinction curves with the same physically well-defined dust model. We find that a large sample of observed Galactic extinction curves are compatible with the evolutionary scenario underlying such a model, requiring physical conditions fully consistent with standard density, temperature, radiation field intensity, and average age of diffuse interstellar clouds.more » Hence, through the study of interstellar extinction we may, in principle, understand the evolutionary history of the diffuse interstellar clouds.« less

Copernicus observations of interstellar matter toward the Orion OB1 association. I - Epsilon and Pi-5 Orionis

NASA Technical Reports Server (NTRS)

Shull, J. M.

1979-01-01

Copernicus UV data on interstellar lines toward Epsilon Ori and Pi-5 Ori are analyzed to study abundances and physical conditions in both low- and intermediate-velocity components. Clouds at -8 and +5 km/s (LSR) toward Epsilon Ori show typical depletions of Fe, Ti, Mg, and Si in dense (H number density about 100 per cu cm) gas. Low-column-density intermediate-velocity clouds toward both stars, with low densities (hydrogen number density less than 1 per cu cm) and near-cosmic Si abundances, are consistent with a widespread pattern of high-velocity gas over a 15-deg area surrounding the Orion region. Such activity may be attributed to the repeated action of supernovae in a patchy low-density region of interstellar gas.

More on the lambda 2800 A 'interstellar extinction' feature

NASA Astrophysics Data System (ADS)

McLachlan, A.; Nandy, K.

1985-02-01

In a response made to a recent letter by Karim et al. (1984), it is shown that the examples of interstellar absorption at 2800 A that they attribute to proteinaceous material can all be attributed to overexposure of IUE detectors. It is pointed out that stars in the Large Magellanic Cloud show pronounced absorption at 2800 A which cannot be due to interstellar protein since there is no associated absorption at 2200 A; this lack of absorption cannot be due to presence of graphite, whose absorption is weak in the Cloud. The claim by Karim et al. that the spectra of eight stars show 2800 A absorption and that these spectra are saturation-free is considered, and it is shown that data processing problems at IUE ground stations make these spectra unreliable.

An interstellar cloud density from Copernicus observations of CO in the spectrum of Zeta Ophiuchi

NASA Technical Reports Server (NTRS)

Smith, A. M.; Stecher, T. P.; Krishna Swamy, K. S.

1978-01-01

Interstellar CO absorption bands in Copernicus spectra of Zeta Oph have been studied. Absorption profiles, computed under the assumption that excitation is due to collisions with H2 molecules and interaction with the 3-K background radiation field, were fitted to the reduced data of nine bands. When a gas kinetic temperature of 56 K is assumed, the best-fit condition implies a hydrogen-nucleus density of 120 per cu cm, a CO column density of 1.2 by 10 to the 15th power per sq cm, and a radial-velocity dispersion of 0.9 km/s. The relevance of these results to existing ideas concerning the Zeta Oph interstellar clouds is discussed. It is suggested that the strongest interstellar component is not circumstellar in origin but is instead part of a supernova remnant. Simple calculations are made to establish the plausibility of the supernova-remnant identification. This suggestion is also supported by Heiles's (1976) 21-cm pictures.

Correlation properties of interstellar dust: Diffuse interstellar bands

NASA Technical Reports Server (NTRS)

Somerville, W. B.

1989-01-01

Results are presented from a research program in which an attempt was made to establish the physical nature of the interstellar grains, and the carriers of the diffuse interstellar bands, by comparing relations between different observed properties; the properties used include the extinction in the optical and ultraviolet (including wavelength 2200 and the far-UV rise), cloud density, atomic depletions, and strengths of the diffuse bands. Observations and also data from literature were used, selecting particularly sight-lines where some observed property was found to have anomalous behavior.

A survey of bimolecular ion-molecule reactions for use in modeling the chemistry of planetary atmospheres, cometary comae, and interstellar clouds

NASA Technical Reports Server (NTRS)

Anicich, V. G.; Huntress, W. T., Jr.

1986-01-01

All bimolecular positive ion-molecule reactions reported from 1965 to 1985 for temperatures below 1000 K are included in the present survey of those ion-molecule reactions pertinent to the chemistries of planetary atmospheres, cometary comae, and interstellar clouds. This survey is intended as an update of the first, by Huntress (1977). The tabular presentation is organized according to reactant ion, with cross-references for both the ionic and the neutral reactants as well as the ionic and neutral products.

LONG CARBON-CHAIN MOLECULES AND THEIR ANIONS IN THE STARLESS CORE, LUPUS-1A

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sakai, Nami; Shiino, Tatsuya; Yamamoto, Satoshi

2010-08-01

We have recently discovered a new starless core with bright radio emissions of long carbon-chain molecules in the Lupus molecular cloud, which we have named as Lupus-1A. Toward this source, the peak intensities of the C{sub 6}H and C{sub 8}H lines are found to be higher than toward TMC-1 by a factor of 2-3. Even the lines of their anions, C{sub 6}H{sup -} and C{sub 8}H{sup -}, are also brighter than in TMC-1. Moreover, the line of C{sub 4}H{sup -} has been detected for the first time in a starless core. The column densities of these long carbon-chain molecules aremore » almost comparable to those in TMC-1, and hence, this source can be regarded as the second 'TMC-1 like cloud'. TMC-1 has long been an outstanding molecular cloud with rich carbon-chain molecules since its discovery in 1976. In spite of extensive efforts, no comparable sources have been found so far. Lupus-1A will be used for hunting of new interstellar molecules as well as understanding of carbon-chain chemistry through critical comparison of physical and chemical properties with TMC-1. This source is important not only for astronomy but also for molecular science as an ideal spectroscopic laboratory because of narrow line shapes and bright intensities.« less

The interstellar chemistry of C3H and C3H2 isomers

PubMed Central

Loison, Jean-Christophe; Agúndez, Marcelino; Wakelam, Valentine; Roueff, Evelyne; Gratier, Pierre; Marcelino, Núria; Nuñez Reyes, Dianailys; Cernicharo, José; Gerin, Maryvonne

2017-01-01

We report the detection of linear and cyclic isomers of C3H and C3H2 towards various starless cores and review the corresponding chemical pathways involving neutral (C3Hx with x=1,2) and ionic (C3Hx+ with x = 1,2,3) isomers. We highlight the role of the branching ratio of electronic Dissociative Recombination (DR) reactions of C3H2+ and C3H3+ isomers showing that the statistical treatment of the relaxation of C3H* and C3H2* produced in these DR reactions may explain the relative c,l-C3H and c,l-C3H2 abundances. We have also introduced in the model the third isomer of C3H2 (HCCCH). The observed cyclic-to-linear C3H2 ratio vary from 110 ± 30 for molecular clouds with a total density around 1×104 molecules.cm-3 to 30 ± 10 for molecular clouds with a total density around 4×105 molecules.cm-3, a trend well reproduced with our updated model. The higher ratio for low molecular cloud densities is mainly determined by the importance of the H + l-C3H2 → H + c-C3H2 and H + t-C3H2 → H + c-C3H2 isomerization reactions. PMID:29142332

The interstellar chemistry of C3H and C3H2 isomers

NASA Astrophysics Data System (ADS)

Loison, Jean-Christophe; Agúndez, Marcelino; Wakelam, Valentine; Roueff, Evelyne; Gratier, Pierre; Marcelino, Núria; Reyes, Dianailys Nuñez; Cernicharo, José; Gerin, Maryvonne

2017-10-01

We report the detection of linear and cyclic isomers of C3H and C3H2 towards various starless cores and review the corresponding chemical pathways involving neutral (C3Hx with x = 1,2) and ionic (C3Hx+ with x = 1,2,3) isomers. We highlight the role of the branching ratio of electronic dissociative recombination (DR) reactions of C3H2+ and C3H3+ isomers, showing that the statistical treatment of the relaxation of C3H* and C3H2* produced in these DR reactions may explain the relative c,l-C3H and c,l-C3H2 abundances. We have also introduced in the model the third isomer of C3H2 (HCCCH). The observed cyclic-to-linear C3H2 ratio varies from 110 ± 30 for molecular clouds with a total density of about 1 × 104 molecules cm-3 to 30 ± 10 for molecular clouds with a total density of about 4 × 105 molecules cm-3, a trend well reproduced with our updated model. The higher ratio for molecular clouds with low densities is determined mainly by the importance of the H + l-C3H2 → H + c-C3H2 and H + t-C3H2 → H + c-C3H2 isomerization reactions.

GRO source candidates: (A) Nearby modest-size molecular clouds; (B) Pulsar with Wolf-Rayet companion that has lost its H-envelope

NASA Technical Reports Server (NTRS)

Silberberg, R.; Murphy, Ronald J.

1989-01-01

Within 100 pc of the sun there are over a hundred cirrus clouds with masses of approx. 60 solar mass and dense molecular clouds with masses of approx. 4 solar mass. If the local interstellar density of cosmic rays is also present in these clouds, the flux of neutral pion from the decay of gamma rays from the core of a cloud at a distance of 20 pc is approx. 13 x 10(exp -8) photons/sq cm/s. The flux from the more extensive cirrus cloud is approx 4 x 10(exp -7) photons/sq cm/s. A relativistic beam of particles generated by a compact stellar object and incident upon a large, close companion can be a strong gamma ray line source if more of the beam energy is used in interactions with C and O and heavier nuclei and less with H and He. This would be the case if the companion has lost its hydrogen envelope and nucleosynthesized much of its He into C, O, and Ne. Such objects are Wolf-Rayet stars and it is believed that some Wolf-Rayet stars do, in fact, have compact companions. For a beam of protons of 10(exp 37) erg/s, the flux at 1 kpc of the 4.4 MeV C-12 line could be as high as 5 x 10(exp -6) photons/sq cm/s. The fluxes of the deexcitation lines from the spallation products of O-16 are also presented.

Some new reaction pathways for the formation of cytosine in interstellar space - A quantum chemical study

NASA Astrophysics Data System (ADS)

Gupta, V. P.; Tandon, Poonam; Mishra, Priti

2013-03-01

The detection of nucleic acid bases in carbonaceous meteorites suggests that their formation and survival is possible outside of the Earth. Small N-heterocycles, including pyrimidine, purines and nucleobases, have been extensively sought in the interstellar medium. It has been suggested theoretically that reactions between some interstellar molecules may lead to the formation of cytosine, uracil and thymine though these processes involve significantly high potential barriers. We attempted therefore to use quantum chemical techniques to explore if cytosine can possibly form in the interstellar space by radical-radical and radical-molecule interaction schemes, both in the gas phase and in the grains, through barrier-less or low barrier pathways. Results of DFT calculations for the formation of cytosine starting from some of the simple molecules and radicals detected in the interstellar space are being reported. Global and local descriptors such as molecular hardness, softness and electrophilicity, and condensed Fukui functions and local philicity indices were used to understand the mechanistic aspects of chemical reaction. The presence and nature of weak bonds in the molecules and transition states formed during the reaction process have been ascertained using Bader's quantum theory of atoms in molecules (QTAIMs). Two exothermic reaction pathways starting from propynylidyne (CCCH) and cyanoacetylene (HCCCN), respectively, have been identified. While the first reaction path is found to be totally exothermic, it involves a barrier of 12.5 kcal/mol in the gas phase against the lowest value of about 32 kcal/mol reported in the literature. The second path is both exothermic and barrier-less. The later has, therefore, a greater probability of occurrence in the cold interstellar clouds (10-50 K).

The Physics of Molecular Shocks in Star-Forming Regions

NASA Technical Reports Server (NTRS)

Hollenbach, David; Cuzzi, Jeffrey (Technical Monitor)

1996-01-01

Molecular shocks are produced by the impact of the supersonic infall of gas and dust onto protostars and by the interaction of the supersonic outflow from the protostar with the circumstellar material. Infalling gas creates an accretion shock around the circumstellar disk which emits a unique infrared spectrum and which processes the interstellar dust as it enters the disk. The winds and jets from protostars also impact the disk, the infalling material, and the ambient molecular cloud core creating shocks whose spectrum and morphology diagnose the mass loss processes of the protostar and the orientation and structure of the star forming system. We discuss the physics of these shocks, the model spectra derived from theoretical models, and comparisons with observations of H2O masers, H2 emission, as well as other shocks tracers. We show the strong effect of magnetic fields on molecular shock structure, and elucidate the chemical changes induced by the shock heating and compression.

The meteoritic record of presolar and early solar system organic chemistry. [Abstract only

NASA Technical Reports Server (NTRS)

Cronin, John R.; Pizzarello, Sandra

1994-01-01

Carbon, hydrogen, and nitrogen isotopic analyses of various classes of organic compounds done in collaboration with Epstein and Krishnamurthy (Caltech) have shown these compounds to be enriched to varying degrees in the heavier isotopes. These results, in particular the large deuterium enrichments, have been interpreted as indicating an interstellar origin for the meteorite compounds or their precursors. Such isotopic fractionations, of hydrogen especially, are characteristic of low temperature ion-molecule reactions in cold interstellar clouds. There is also evidence from the large corresponding suites of alpha-amino and alpha-hydroxy acids found in meteorites suggesting that aqueous phase chemistry on the meteorite parent body played an important role in the formation of these compounds. These data support the hypothesis that interstellar compounds survived in the solar nebula at a radial distance corresponding to the asteroid belt, were incorporated into the parent body in icy, volatile-rich, planetesinals, and underwent further reactions during a period of aqueous activity within the early parent body to give the present suite of meteorite compounds. This formation hypothesis will be discussed and the results of recent isotopic and molecular analyses bearing on it will be presented.

Laboratory Formation of Fullerenes from PAHs: Top-down Interstellar Chemistry

NASA Astrophysics Data System (ADS)

Zhen, Junfeng; Castellanos, Pablo; Paardekooper, Daniel M.; Linnartz, Harold; Tielens, Alexander G. G. M.

2014-12-01

Interstellar molecules are thought to build up in the shielded environment of molecular clouds or in the envelope of evolved stars. This follows many sequential reaction steps of atoms and simple molecules in the gas phase and/or on (icy) grain surfaces. However, these chemical routes are highly inefficient for larger species in the tenuous environment of space as many steps are involved and, indeed, models fail to explain the observed high abundances. This is definitely the case for the C60 fullerene, recently identified as one of the most complex molecules in the interstellar medium. Observations have shown that, in some photodissociation regions, its abundance increases close to strong UV-sources. In this Letter we report laboratory findings in which C60 formation can be explained by characterizing the photochemical evolution of large polycyclic aromatic hydrocarbons (PAHs). Sequential H losses lead to fully dehydrogenated PAHs and subsequent losses of C2 units convert graphene into cages. Our results present for the first time experimental evidence that PAHs in excess of 60 C-atoms efficiently photo-isomerize to buckminsterfullerene, C60. These laboratory studies also attest to the importance of top-down synthesis routes for chemical complexity in space.

The Pelican Nebula and its Vicinity: a New Look at Stellar Population in the Cloud and around It

NASA Astrophysics Data System (ADS)

Boyle, Richard P.; Janusz, R.; Vrba, F. J.; Straizys, V.; Laugalys, V.; Kazlauskas, A.; Stott, J.; Philip, A. G. D.

2011-01-01

A region of active star formation is located in the complex of dust and molecular clouds known as the Pelican Nebula and the dark cloud L935. In this paper we describe the results of our investigation in the area bounded by the coordinates (2000) RA 20h50m - 20h54m and DEC +44d20m - 44m55d. Our CCD photometry in the Vilnius seven-color system, obtained on the 1.8 m Vatican Advanced Technology Telescope, Mt. Graham, and the 1 m telescope of the USNO Flagstaff Station, is used to classify stars down to V = 17 mag in spectral and luminosity classes. The interstellar extinction values and distances to these stars are determined. Additionally, the data from the 2MASS, MegaCam, IPHAS and Spitzer surveys are analyzed. We present star population maps in the foreground and background of the complex and within it. The known and newly identified YSOs in the area are tabulated.

Term Projects on Interstellar Comets

ERIC Educational Resources Information Center

Mack, John E.

1975-01-01

Presents two calculations of the probability of detection of an interstellar comet, under the hypothesis that such comets would escape from comet clouds similar to that believed to surround the sun. Proposes three problems, each of which would be a reasonable term project for a motivated undergraduate. (Author/MLH)

Fifteen Years of Laboratory Astrophysics at Ames

NASA Technical Reports Server (NTRS)

Allamandola, L. J.; Sandford, S. A.; Salama, F.; Hudgins, D. M.; Bernstein, M.; Goorvitch, David (Technical Monitor)

1998-01-01

Tremendous strides have been made in our understanding of interstellar material over the past fifteen years thanks to significant, parallel developments in two closely related areas: observational astronomy and laboratory astrophysics. Fifteen years ago the composition of interstellar dust was largely guessed at, the concept of ices in dense molecular clouds ignored, and the notion of large, abundant, gas phase, carbon-rich molecules widespread throughout the interstellar medium (ISM) considered impossible. Today the composition of dust in the diffuse ISM is reasonably well constrained to cold refractory materials comprised of amorphous and crystalline silicates mixed with an amorphous carbonaceous material containing aromatic structural units and short, branched aliphatic chains. In the dense ISM, these cold dust particles are coated with mixed-molecular ices whose compositions are very well known. Lastly, the signature of carbon-rich polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by early interstellar chemistry standards, is widespread throughout the ISM. This great progress has only been made possible by the close collaboration of laboratory experimentalists with observers and theoreticians, all with the goal of applying their skills to astrophysical problems of direct interest to NASA programs. Such highly interdisciplinary collaborations ensure fundamental, in depth coverage of the wide-ranging challenges posed by astrophysics. These challenges include designing astrophysically focused experiments and data analysis, tightly coupled with astrophysical searches spanning 2 orders of magnitude in wavelength, and detailed theoretical modeling. The impact of our laboratory has been particularly effective as there is constant cross-talk and feedback between quantum theorists; theoretical astrophysicists and chemists; experimental physicists; organic, physical and petroleum chemists; and infrared and UV/Vis astronomers. In this paper, two examples of the Ames Program will be given. We have been involved in identifying 9 out of the 14 interstellar pre-cometary ice species known, determined their abundances and the physical nature of the ice structure. Details on our ice work are given in the paper by Sandford et al. Our group is among the pioneers of the PAH model. We built the theoretical framework, participated in the observations and developed the experimental techniques needed to test the model. We demonstrated that the ubiquitous infrared emission spectrum associated with many interstellar objects can be matched by laboratory spectra of neutral and positively charged PAHs and that PAHs were excellent candidates for the diffuse interstellar band (DIB) carriers. See Salama et al. and Hudgins et al.

Star Formation in the DR21 Region (B)

NASA Technical Reports Server (NTRS)

2004-01-01

[figure removed for brevity, see original site] Annotated mosaic

Hidden behind a shroud of dust in the constellation Cygnus is an exceptionally bright source of radio emission called DR21. Visible light images reveal no trace of what is happening in this region because of heavy dust obscuration. In fact, visible light is attenuated in DR21 by a factor of more than 10,000,000,000,000,000,000,000,000,000,000,000,000,000 (ten thousand trillion heptillion).

New images from NASA's Spitzer Space Telescope allow us to peek behind the cosmic veil and pinpoint one of the most massive natal stars yet seen in our Milky Way galaxy. The never-before-seen star is 100,000 times as bright as the Sun. Also revealed for the first time is a powerful outflow of hot gas emanating from this star and bursting through a giant molecular cloud.

The upper image is a large-scale mosaic assembled from individual photographs obtained with the InfraRed Array Camera (IRAC) aboard Spitzer. The image covers an area about two times that of a full moon. The mosaic is a composite of images obtained at mid-infrared wavelengths of 3.6 microns (blue), 4.5 microns (green), 5.8 microns (orange) and 8 microns (red). The brightest infrared cloud near the top center corresponds to DR21, which presumably contains a cluster of newly forming stars at a distance of 10,000 light-years.

Protruding out from DR21 toward the bottom left of the image is a gaseous outflow (green), containing both carbon monoxide and molecular hydrogen. Data from the Spitzer spectrograph, which breaks light into its constituent individual wavelengths, indicate the presence of hot steam formed as the outflow heats the surrounding molecular gas. Outflows are physical signatures of processes that create supersonic beams, or jets, of gas. They are usually accompanied by discs of material around the new star, which likely contain the materials from which future planetary systems are formed. Additional newborn stars, depicted in green, can be seen surrounding the DR21 region.

The red filaments stretching across this image denote the presence of polycyclic aromatic hydrocarbons. These organic molecules, comprised of carbon and hydrogen, are excited by surrounding interstellar radiation and become luminescent at wavelengths near 8.0 microns. The complex pattern of filaments is caused by an intricate combination of radiation pressure, gravity and magnetic fields. The result is a tapestry in which winds, outflows and turbulence move and shape the interstellar medium.

To the lower left of the mosaic is a large bubble of gas and dust, which may represent the remnants of a past generation of stars.

The lower panel shows a 24-micron image mosaic, obtained with the Multiband Imaging Photometer aboard Spitzer (MIPS). This image maps the cooler infrared emission from interstellar dust found throughout the interstellar medium. The DR21 complex is clearly seen near the center of the strip, which covers about twice the area of the IRAC image.

Perhaps the most fascinating feature in this image is a long and shadowy linear filament extending towards the 10 o'clock position of DR21. This jet of cold and dense gas, nearly 50 light-years in extent, appears in silhouette against a warmer background. This filament is too long and massive to be a stellar jet and may have formed from a pre-existing molecular cloud core sculpted by DR21's strong winds. Regardless of its true nature, this jet and the numerous other arcs and wisps of cool dust signify the interstellar turbulence normally unseen by the human eye.

Hydrogen cyanide polymerization: a preferred cosmochemical pathway.

PubMed

Matthews, C N

1992-01-01

Current research in cosmochemistry shows that crude organic solids of high molecular weight are readily formed in planetary, interplanetary and interstellar environments. Underlying much of this ubiquitous chemistry is a low energy route leading directly to the synthesis of hydrogen cyanide and its polymers. Evidence from laboratory and extraterrestrial investigations suggests that these polymers plus water yield heteropolypeptides, a truly universal process that accounts not only for the past synthesis of protein ancestors on Earth but also for reactions proceeding elsewhere today within our solar system, on planetary bodies and satellites around other stars and in the dusty molecular clouds of spiral galaxies. The existence of this preferred pathway - hydrogen cyanide polymerization - surely increases greatly the probability that carbon-based life is widespread in the universe.

Isotopic Measurements of Sulphonates and Phosphonates and Investigations of Possible Formaldehyde Products from the Murchison Meteorite

NASA Technical Reports Server (NTRS)

Cooper, George

1996-01-01

Intramolecular carbon, hydrogen, and sulfur isotope measurements have been made on a homologous series of organic sulfonates discovered in the Murchison meteorite. Mass independent sulfur isotope fractionations were observed along with D/H ratios clearly larger than terrestrial. The sulfur fractionations may be produced chemically and due to molecular symmetry factors. The deuterium enrichments indicate formation of the hydrocarbon portion of these compounds in a low temperature astrophysical environment consistent with that of molecular clouds. The source of the sulfonate precursors may have been the reactive interstellar molecule, CS. Low temperature CS reactions also produce other sulfur containing compounds as well as a solid phase. Isotopic measurements on bulk phosphonates were also made.

Electron-impact excitation and recombination of molecular cations in edge fusion plasma: application to H2+and BeD+

NASA Astrophysics Data System (ADS)

Pop, Nicolina; Iacob, Felix; Mezei, Zsolt; Motapon, Ousmanou; Niyonzima, Sebastien; Schneider, Ioan

2017-10-01

Dissociative recombination, ro-vibrational excitation and dissociative excitation of molecular cations with electrons are major elementary process in the kinetics and in the energy balance of astrophysically-relevant ionized media (supernovae, interstellar molecular clouds, planetary ionospheres, early Universe), in edge fusion and in many other cold media of technological interest. For the fusion plasma edge, extensive cross sections and rate coefficients have been produced for reactions induced on HD+, H2+ and BeD+ using the Multichannel Quantum Defect Theory (MQDT). Our calculations resulted in good agreement with the CRYRING (Stockholm) and TSR (Heidelberg) magnetic storage ring results, and our approach is permanently improved in order to face the new generation of electrostatic storage rings, as CSR (Heidelberg) and DESIREE (Stockholm). Member of APS Reciprocal Society: European Physics Society.

Hot interstellar gas and ionization of embedded clouds

NASA Technical Reports Server (NTRS)

Cheng, K.-P.; Bruhweiler, F.

1990-01-01

Researchers present detailed photoionization calculations for the instellar cloud in which the Sun is embedded. They consider the EUV radiation field with contribution from discrete stellar sources and from a thermal bremsstrahlung-radiative recombination spectrum emitted from the surrounding 10 to the 6th power k coronal substrate. They establish lower limits to the fractional ionization of hydrogen and helium of 0.17 and 0.29 respectively. The high He ionization fraction results primarily from very strong line emission below 500 A originating in the surrounding coronal substrate while the H ionization is dominated by the EUV radiation from the discrete stellar sources. The dual effects of thermal conduction and the EUV spectrum of the 10 to the 6th k plasma on ionization in the cloud skin are explored. The EUV radiation field and Auger ionization have insignificant effects on the resulting ionic column densities of Si IV, C IV, N V and O VI through the cloud skin. Calculations show that the abundances of these species are dominated by collisional ionization in the thermal conduction front. Because of a low charge exchange rate with hydrogen, the ionic column density ratios of N (CIII)/N (CII) and N (NII)/N (NI) are dominated by the EUV radiation field in the local interstellar medium. These ratios should be important diagnostics for the EUV radiation field and serve as surrogate indicators of the interstellar He and H ionization fraction respectively. Spacecraft such as Lyman which is designed to obtain high resolution spectral data down to the Lyman limit at 912 A could sample interstellar lines of these ions.

The evolution of organic matter in space.

PubMed

Ehrenfreund, Pascale; Spaans, Marco; Holm, Nils G

2011-02-13

Carbon, and molecules made from it, have already been observed in the early Universe. During cosmic time, many galaxies undergo intense periods of star formation, during which heavy elements like carbon, oxygen, nitrogen, silicon and iron are produced. Also, many complex molecules, from carbon monoxide to polycyclic aromatic hydrocarbons, are detected in these systems, like they are for our own Galaxy. Interstellar molecular clouds and circumstellar envelopes are factories of complex molecular synthesis. A surprisingly high number of molecules that are used in contemporary biochemistry on the Earth are found in the interstellar medium, planetary atmospheres and surfaces, comets, asteroids and meteorites and interplanetary dust particles. Large quantities of extra-terrestrial material were delivered via comets and asteroids to young planetary surfaces during the heavy bombardment phase. Monitoring the formation and evolution of organic matter in space is crucial in order to determine the prebiotic reservoirs available to the early Earth. It is equally important to reveal abiotic routes to prebiotic molecules in the Earth environments. Materials from both carbon sources (extra-terrestrial and endogenous) may have contributed to biochemical pathways on the Earth leading to life's origin. The research avenues discussed also guide us to extend our knowledge to other habitable worlds.

Identifying Organic Molecules in Space: The AstroBiology Explorer (ABE) Mission Concept

NASA Technical Reports Server (NTRS)

Ennico, Kimberly; Sandford, S.; Allamandola, L.; Bregman, J.; Cohen, M.; Cruikshank, D.; Dumas, C.; Greene, T.; Hudgins, D.; Kwok, S.

2004-01-01

The AstroBiology Explorer (ABE) mission concept consists of a modest dedicated space observatory having a 60 cm class primary mirror cooled to T less than 50 K equipped with medium resolution cross-dispersed spectrometers having cooled large format near- and mid-infrared detector arrays. Such a system would be capable of addressing outstanding problems in Astrochemistry and Astrophysics that are particularly relevant to Astrobiology and addressable via astronomical observation. The mission's observaticxiai program woiild make fundamental scieztific: prngress in establishing the nature, distribution, formation and evolution of organic and other molecular materials in the following extra-terrestrial environments: 1) The Outflow of Dying Stars; 2) The Diffuse Interstellar Medium (DISM); 3) Dense Molecular Clouds, Star Formation Regions, and Young Stellar/Planetary Systems; 4) Planets, Satellites, and Small Bodies within the Solar System; and 5) The Interstellar Media of Other Galaxies ABE could make fundamental progress in all of these area by conducting a 1 to 2 year mission to obtain a coordinated set of infrared spectroscopic observations over the 2.5 - 20 micron spectral range at a spectral resolution of R greater than 2500 of about 1500 galaxies, stars, planetary nebulae, young stellar objects, and solar system objects.

Molecular gas in high-mass filament WB673

NASA Astrophysics Data System (ADS)

Kirsanova, Maria S.; Salii, Svetlana V.; Sobolev, Andrej M.; Olofsson, Anders Olof Henrik; Ladeyschikov, Dmitry A.; Thomasson, Magnus

2017-12-01

We studied the distribution of dense gas in a filamentary molecular cloud containing several dense clumps. The center of the filament is given by the dense clump WB673. The clumps are high-mass and intermediate-mass starforming regions. We observed CS (2-1), 13CO (1-0), C18O(1-0), and methanol lines at 96 GHz toward WB673 with the Onsala Space Observatory 20-m telescope. We found CS (2-1) emission in the inter-clump medium so the clumps are physically connected and the whole cloud is indeed a filament. Its total mass is 104 M⊙ and mass-to-length ratio is 360M⊙ pc-1 from 13CO (1-0) data. Mass-to-length ratio for the dense gas is 3.4 - 34M⊙ pc-1 from CS (2-1) data. The PV-diagram of the filament is V-shaped. We estimated physical conditions in the molecular gas using methanol lines. Location of the filament on the sky between extended shells suggests that it could be a good example to test theoretical models of formation of the filaments via multiple compression of interstellar gas by supersonic waves.

Copernicus observations of interstellar absorption at Lyman alpha

NASA Technical Reports Server (NTRS)

Bohlin, R. C.

1975-01-01

Column densities NH of atomic hydrogen have been derived for 40 OB stars from spectral scans at Lyman alpha obtained by the Copernicus (OAO-3) satellite. The stars are all between 60 and 1100 pc away with a range of mean densities n sub H of 0.01 to 2.5 atoms cm-3. The gas to color-excess ratio in clouds varies from 1 to 3 times the mean outside of clouds. The presence of molecular hydrogen correlates with E(B-V), but the best tracer for H2 is atomic hydrogen. The mean density of the gas for all 40 stars is much smaller than the mean of 0.7 atoms cm-3 obtained from 21-cm observations, because the brightest stars with less than average amounts of matter in the line of sight were selected for observation.

Fast molecular shocks. I - Reformation of molecules behind a dissociative shock

NASA Technical Reports Server (NTRS)

Neufeld, David A.; Dalgarno, A.

1989-01-01

The physical and chemical processes that operate in the cooling gas behind a fast, dissociative, single-fluid shock propagating in a dense interstellar cloud are discussed. The treatment extends previous theoretical work on fast molecular shocks by including the effects of the conversion of Ly-alpha photons into radiation of the two-photon continuum and into H2 Lyman band emission lines, the effects of CO photodissociation following line absorption, and the formation and destruction of molecules containing the elements nitrogen, silicon, and sulphur, and of the complex hydrocarbons. Abundance profiles for the molecular species of interest are presented. After molecular hydrogen begins to reform, by means of gas phase and grain surface processes, the neutral species OH, H2O, O2, CO, CN, HCN, N2, NO, SO, and SiO reach substantial abundances. The molecular ions HeH(+), OH(+), SO(+), CH(+), H2(+), and H3(+), are produced while the gas is still hot and partially ionized. Emissions from them provide a possible diagnostic probe of fast molecular shocks.

Distribution of hot stars and hydrogen in the Large Magellanic Cloud

NASA Technical Reports Server (NTRS)

Page, T.; Carruthers, G. R.

1981-01-01

Imagery of the Large Magellanic Cloud (LMC), in the wavelength ranges 1050 to 1600 A and 1250 to 1600 A, was obtained by the S201 far ultraviolet camera during the Apollo 16 mission. These images were reduced to absolute far-UV intensity distributions over the area of the LMC, with 3 to 5 arc min angular resolution. Comparison of these far-UV measurements in the LMC with H sub alpha and 21 cm surveys reveals that interstellar hydrogen in the LMC is often concentrated in 100 pc clouds within 500 pc clouds. Furthermore, at least 25 associations of O-B stars in the LMC are outside the interstellar hydrogen clouds; four of them appear to be on the far side. Far-UV and mid-UV spectra were obtained of stars in 12 of these associations, using the International Ultraviolet Explorer. Equivalent widths of L alpha and six other lines, and relative intensities of the continuum at seven wavelength from 1300 A to 2900 A, were measured. These spectra are also discussed.

A flux-limited treatment for the conductive evaporation of spherical interstellar gas clouds

NASA Technical Reports Server (NTRS)

Dalton, William W.; Balbus, Steven A.

1993-01-01

In this work, we present and analyze a new analytic solution for the saturated (flux-limited) thermal evaporation of a spherical cloud. This work is distinguished from earlier analytic studies by allowing the thermal conductivity to change continuously from a diffusive to a saturated form, in a manner usually employed only in numerical calculations. This closed form solution will be of interest as a computational benchmark. Using our calculated temperature profiles and mass-loss rates, we model the thermal evaporation of such a cloud under typical interstellar medium (ISM) conditions, with some restrictions. We examine the ionization structure of the cloud-ISM interface and evaluate column densities of carbon, nitrogen, oxygen, neon, and silicon ions toward the cloud. In accord with other investigations, we find that ionization equilibrium is far from satisfied under the assumed conditions. Since the inclusion of saturation effects in the heat flux narrows the thermal interface relative to its classical structure, we also find that saturation effects tend to lower predicted column densities.

The interstellar D1 line at high resolution

NASA Technical Reports Server (NTRS)

Hobbs, L. M.; Welty, D. E.

1990-01-01

Observations at a resolving power or a velocity resolution are reported of the interstellar D(sub 1) line of Na I in the spectra of gamma Cas, delta Ori, epsilon Ori, pi Sco, delta Cyg, and alpha Cyg. An echelle grating was used in a double-pass configuration with a CCD detector in the coude spectrograph of the 2.7 m reflector at McDonald Observatory. At least 42 kinematically distinct clouds are detected along the light paths to the five more distant stars, in addition to a single cloud seen toward delta Cyg. The absorption lines arising in 13 of the clouds are sufficiently narrow and unblended to reveal clearly resolved hyperfine structure components split by 1.05 km/s. An additional 13 clouds apparently show comparably narrow, but more strongly blended, lines. For each individual cloud, upper limits T(sub max) and (v sub t)(sub max) on the temperature and the turbulent velocity, respectively, are derived by fitting the observed lines with theoretical absorption profiles.

Interplay of dust alignment, grain growth, and magnetic fields in polarization: lessons from the emission-to-extinction ratio

NASA Astrophysics Data System (ADS)

Fanciullo, L.; Guillet, V.; Boulanger, F.; Jones, A. P.

2017-06-01

Context. Polarized extinction and emission from dust in the interstellar medium (ISM) are hard to interpret, as their dependence on dust optical properties, grain alignment, and magnetic field orientation is complex. This is particularly true in molecular clouds. The aforementioned phenomena are usually considered independently in polarization studies, while it is likely that they all contribute and their effects have yet to be disentangled. Aims: The data available today are not yet used to their full potential. The combination of emission and extinction, in particular, provides information not available from either of them alone. We combine data from the scientific literature on polarized dust extinction with Planck data on polarized emission, and we use them to constrain the possible variations in dust and environmental conditions inside molecular clouds, and especially translucent lines of sight, taking the magnetic field orientation into account. Methods: We focused on the dependence between λmax (the wavelength of maximum polarization in extinction) and other observables such as the extinction polarization, the emission polarization, and the ratio between the two. We set out to reproduce these correlations using Monte Carlo simulations in which we varied the relevant quantities in a dust model, which are grain alignment, size distribution, and magnetic field orientation, to mimic the diverse conditions that are expected inside molecular clouds. Results: None of the quantities we chose can explain the observational data on their own: the best results are obtained when all quantities vary significantly across and within clouds. However, some of the data, most notably the stars with a low ratio of polarization in emission to polarization in extinction, are not reproduced by our simulation. Conclusions: Our results suggest not only that dust evolution is necessary to explain polarization in molecular clouds, but that a simple change in size distribution is not sufficient to explain the data. Our results also point the way for future and more sophisticated models.

Non-equilibrium ionization around clouds evaporating in the interstellar medium

NASA Technical Reports Server (NTRS)

Ballet, J.; Luciani, J. F.; Mora, P.

1986-01-01

It is of prime importance for global models of the interstellar medium to know whether dense clouds do or do not evaporate in the hot coronal gas. The rate of mass exchanges between phases depends very much on that. McKee and Ostriker's model, for instance, assumes that evaporation is important enough to control the expansion of supernova remnants, and that mass loss obeys the law derived by Cowie and McKee. In fact, the geometry of the magnetic field is nearly unknown, and it might totally inhibit evaporation, if the clouds are not regularly connected to the hot gas. Up to now, the only test of the theory is the U.V. observation (by the Copernicus and IUE satellites) of absorption lines of ions such as OVI or NV, that exist at temperatures of a few 100,000 K typical of transition layers around evaporating clouds. Other means of testing the theory are discussed.

The Genesis Project: Science Cases for a Large Submm Telescope

NASA Astrophysics Data System (ADS)

Schneider, Nicola

2018-01-01

The formation of stars is intimately linked to the structure and evolution of molecular clouds in the interstellar medium. In the context of the ANR/DFG project GENESIS (GENeration and Evolution of Structures in the Ism, http://www.astro.uni-koeln.de/node/965), we explore this link with a new approach by combining far-infrared maps and surveys of dust (Herschel) and cooling lines (CII, CI, CO, OI with SOFIA), with molecular line maps. Dedicated analysis tools are used to characterise molecular cloud structure, and we explore the coupling of turbulence with heating- and cooling processes. The project gathers a large observational data set, from molecular line maps at (sub)-mm wavelengths from ground-based telescopes (e.g. IRAM) up to high-frequency airborne spectroscopic and continuum observations (SOFIA). Nevertheless, we identified the need for a large single-dish submm telescope, operating in the southern hemisphere at high frequencies. Only such an instrument is able to observe important ISM cooling lines, like the CI lines at 490 and 810 GHz or high-J CO lines, shock tracers, or probes of turbulence dissipation with high angular resolution in Galactic and extragalactic sources. We will discuss possible science cases and demonstrate how those are addressed within GENESIS, and the science done with the new 6m Cologne-Cornell CCAT-prime submm telescope.

The essential signature of a massive starburst in a distant quasar.

PubMed

Solomon, P; Vanden Bout, P; Carilli, C; Guelin, M

2003-12-11

Observations of carbon monoxide emission in high-redshift (zeta > 2) galaxies indicate the presence of large amounts of molecular gas. Many of these galaxies contain an active galactic nucleus powered by accretion of gas onto a supermassive black hole, and a key question is whether their extremely high infrared luminosities result from the active galactic nucleus, from bursts of massive star formation (associated with the molecular gas), or both. In the Milky Way, high-mass stars form in the dense cores of interstellar molecular clouds, where gas densities are n(H2) > 10(5) cm(-3) (refs 1, 2). Recent surveys show that virtually all galactic sites of high-mass star formation have similarly high densities. The bulk of the cloud material traced by CO observations, however, is at a much lower density. For galaxies in the local Universe, the HCN molecule is an effective tracer of high-density molecular gas. Here we report observations of HCN emission from the infrared-luminous 'Cloverleaf' quasar (at a redshift zeta = 2.5579). The HCN line luminosity indicates the presence of 10 billion solar masses of very dense gas, an essential feature of an immense starburst, which contributes, together with the active galactic nucleus it harbours, to its high infrared luminosity.

The Properties of Single Interstellar Clouds: Cycle 1, SIDE-2 Observations

NASA Astrophysics Data System (ADS)

Hobbs, Lewis

1990-12-01

WE PROPOSE TO USE THE ECHELLE GRATING OF THE HIGH RESOLUTION SPECTROGRAPH OVER A TWO-YEAR PERIOD TO OBSERVE THE PROFILES OF INTERSTELLAR ABSORPTION LINES. THE COLUMN DENSITES OF 18 NEUTRAL OR IONIZED FORMS OF THE ELEMENTS C,N,O,Mg,Si,P,S,Fe, AND Zn WILL BE MEASURED IN THE APPROXIMATELY 100 INDIVIDUAL INTERSTELLAR CLOUDS ALONG THE LIGHT PATHS TO 18 BRIGHT, BROAD-LINED STARS OF EARLY SPECTRAL TYPE WITHIN 1 KPC OF THE SUN. THE PRIMARY PURPOSE OF THE OBSERVATIONS IS TO DETERMINE MORE ACCURATELY THAN WAS HITHERTO POSSIBLE THE FUNDAMENTAL PHYSICAL PROPERTIES OF THE RESOLVED CLOUDS, INCLUDING LINEAR SIZE, TEMPERATURE, TOTAL DENSITY, FRACTIONAL IONIZATION AND THE RELATIVE ABUNDANCES OF THE 9 SELECTED ELEMENTS. THE REST OF THIS OBSERVING PROGRAM IS CONTAINED IN APPROVED PROPOSAL ID = 2251; THE PROGRAM EUNUMERATED HERE CONSISTS OF THAT PART OF OUR ORIGINAL PROGRAM WHICH CAN BE CARRIED OUT USING ONLY SIDE 2 OF THE GHRS. THIS PROGRAM THEREFORE CONSISTS OF ECH-B OBSERVATIONS OF EACH OF 4 STARS AT 7 WAVELENGTHS. PROGRAM 2251 SHOULD BE CONSULTED FOR ADDITIONAL DETAILS.

The Properties of Single Interstellar Clouds: Hopr Repeat Cycle 1, SIDE-2 Observations

NASA Astrophysics Data System (ADS)

Hobbs, Lewis

1990-12-01

WE PROPOSE TO USE THE ECHELLE GRATING OF THE HIGH RESOLUTION SPECTROGRAPH OVER A TWO-YEAR PERIOD TO OBSERVE THE PROFILES OF INTERSTELLAR ABSORPTION LINES. THE COLUMN DENSITES OF 18 NEUTRAL OR IONIZED FORMS OF THE ELEMENTS C,N,O,Mg,Si,P,S,Fe, AND Zn WILL BE MEASURED IN THE APPROXIMATELY 100 INDIVIDUAL INTERSTELLAR CLOUDS ALONG THE LIGHT PATHS TO 18 BRIGHT, BROAD-LINED STARS OF EARLY SPECTRAL TYPE WITHIN 1 KPC OF THE SUN. THE PRIMARY PURPOSE OF THE OBSERVATIONS IS TO DETERMINE MORE ACCURATELY THAN WAS HITHERTO POSSIBLE THE FUNDAMENTAL PHYSICAL PROPERTIES OF THE RESOLVED CLOUDS, INCLUDING LINEAR SIZE, TEMPERATURE, TOTAL DENSITY, FRACTIONAL IONIZATION AND THE RELATIVE ABUNDANCES OF THE 9 SELECTED ELEMENTS. THE REST OF THIS OBSERVING PROGRAM IS CONTAINED IN APPROVED PROPOSAL ID = 2251; THE PROGRAM EUNUMERATED HERE CONSISTS OF THAT PART OF OUR ORIGINAL PROGRAM WHICH CAN BE CARRIED OUT USING ONLY SIDE 2 OF THE GHRS. THIS PROGRAM THEREFORE CONSISTS OF ECH-B OBSERVATIONS OF EACH OF 4 STARS AT 7 WAVELENGTHS. PROGRAM 2251 SHOULD BE CONSULTED FOR ADDITIONAL DETAILS.

The Properties of Single Interstellar Clouds Cycle 2

NASA Astrophysics Data System (ADS)

Hobbs, Lewis

1991-07-01

IN THIS CONTINUATION PROPOSAL, WE PROPOSE TO USE THE ECHELLEAND 160M GRATINGS OF THE HIGH RESOLUTION SPECTROGRAPH TO OBSERVE THE PZROFILES OF INTERSTELLAR ABSORPTION LINES, DURING THE SECOND YEAR OF A TWO-YEAR PROGRAM. IN THE TWO CYCLES TOGETHER, THE COLUMN DENSITES OF 17 NEUTRAL OR IONIZED FORMS OF THE ELEMENTS C,N,O,Mg,Si,P,S,Fe, AND Zn WILL BE MEASURED IN THE APPROXIMATELY 100 INDIVIDUAL INTERSTELLAR CLOUDS ALONG THE LIGHT PATHS TO 12 BRIGHT, BROAD-LINED STARS OF EARLY SPECTRAL TYPE WITHIN 1 KPC OF THE SUN. THE PRIMARY PURPOSE OF THE OBSERVATIONS IS TO DETERMINE MORE ACCURATELY THAN WAS HITHERTO POSSIBLE THE FUNDAMENTAL PHYSICAL PROPERTIES OF THE RESOLVED CLOUDS, INCLUDING LINEAR SIZE, TEMPERATURE, TOTAL DENSITY, FRACTIONAL IONIZATION AND THE RELATIVE ABUNDANCES OF THE 9 SELECTED ELEMENTS. THIS SECOND-YEAR PROGRAM CONSISTS OF ECH-B AND G160M OBSERVATIONS OF EACH OF 4 STARS AT 21 OR MORE WAVELENGTHS, AND OF A SUBSET OF THESE OBSERVATIONS FOR A FIFTH STAR, PI SCO. PROGRAMS 2251 AND 3993 SHOULD BE CONSULTED FOR DETAILS OF THE PREVIOUS OBSERVATIONS OBTAINED DURING CYCLE 1.

Star-Forming Clouds Feed, Churn, and Fall

NASA Astrophysics Data System (ADS)

Kohler, Susanna

2017-12-01

Molecular clouds, the birthplaces of stars in galaxies throughout the universe, are complicated and dynamic environments. A new series of simulations has explored how these clouds form, grow, and collapse over their lifetimes.This composite image shows part of the Taurus Molecular Cloud. [ESO/APEX (MPIfR/ESO/OSO)/A. Hacar et al./Digitized Sky Survey]Stellar BirthplacesMolecular clouds form out of the matter in between stars, evolving through constant interactions with their turbulent environments. These interactions taking the form of accretion flows and surface forces, while gravity, turbulence, and magnetic fields interplay are thought to drive the properties and evolution of the clouds.Our understanding of the details of this process, however, remains fuzzy. How does mass accretion affect these clouds as they evolve? What happens when nearby supernova explosions blast the outsides of the clouds? What makes the clouds churn, producing the motion within them that prevents them from collapsing? The answers to these questions can tellus about the gas distributed throughout galaxies, revealing information about the environments in which stars form.A still from the simulation results showing the broader population of molecular clouds that formed in the authors simulations, as well as zoom-in panels of three low-mass clouds tracked in high resolution. [Ibez-Meja et al. 2017]Models of TurbulenceIn a new study led by Juan Ibez-Meja (MPI Garching and Universities of Heidelberg and Cologne in Germany, and American Museum of Natural History), scientists have now explored these questions using a series of three-dimensional simulations of a population of molecular clouds forming and evolving in the turbulent interstellar medium.The simulations take into account a whole host of physics, including the effects of nearby supernova explosions, self-gravitation, magnetic fields, diffuse heating, and radiative cooling. After looking at the behavior of the broader population of clouds, the authors zoom in and explore three clouds in high-resolution to learn more about the details.Watching Clouds EvolveIbez-Meja and collaborators find that mass accretion occurring after the molecular clouds form plays an important role in the clouds evolution, increasing the mass available to form stars and carrying kinetic energy into the cloud. The accretion process is driven both by background turbulent flows and gravitational attraction as the cloud draws in the gas in its nearby environment.Plots of the cloud mass and radius (top) and mass accretion rate (bottom) for one of the three zoomed-in clouds, shown as a function of time over the 10-Myr simulation. [Adapted from Ibez-Meja et al. 2017]The simulations show that nearby supernovae have two opposing effects on a cloud. On one hand, the blast waves from supernovae compress the envelope of the cloud, increasing the instantaneous rate of accretion. On the other hand, the blast waves disrupt parts of the envelope and erode mass from the clouds surface, decreasing accretion overall. These events ensure that the mass accretion rate of molecular clouds is non-uniform, regularly punctuated by sporadic increases and decreases as the clouds are battered by nearby explosions.Lastly, Ibez-Meja and collaborators show that mass accretion alone isnt enough to power the turbulent internal motions we observe inside molecular clouds. Instead, they conclude, the cloud motions must be primarily powered by gravitational potential energy being converted into kinetic energy as the cloud contracts.The authors simulations therefore show that molecular clouds exist in a state of precarious balance, prevented from collapsing by internal turbulence driven by interactions with their environment and by their own contraction. These results give us an intriguing glimpse into the complex environments in which stars are born.BonusCheck out the animated figure below, which displays how the clouds in the authors simulations evolve over the span of 10 million years.http://cdn.iopscience.com/images/0004-637X/850/1/62/Full/apjaa93fef1_video.mp4CitationJuan C. Ibez-Meja et al 2017 ApJ 850 62. doi:10.3847/1538-4357/aa93fe

Abundances of Neutral and Ionized PAH Along The Lines-of-Sight of Diffuse and Translucent Interstellar Clouds

NASA Technical Reports Server (NTRS)

Salama, Farid; Galazutdinov, Gazinur; Krewloski, Jacek; Biennier, Ludovic; Beletsky, Yuri; Song, In-Ok

2013-01-01

The spectra of neutral and ionized PAHs isolated in the gas phase at low temperature have been measured in the laboratory under conditions that mimic interstellar conditions and are compared with a set of astronomical spectra of reddened, early type stars. The comparisons of astronomical and laboratory data provide upper limits for the abundances of neutral PAH molecules and ions along specific lines-of-sight. Something that is not attainable from infrared observations. We present the characteristics of the laboratory facility (COSmIC) that was developed for this study and discuss the findings resulting from the comparison of the laboratory data with high resolution, high S/N ratio astronomical observations. COSmIC combines a supersonic jet expansion with discharge plasma and cavity ringdown spectroscopy and provides experimental conditions that closely mimic the interstellar conditions. The column densities of the individual PAH molecules and ions probed in these surveys are derived from the comparison of the laboratory data with high resolution, high S/N ratio astronomical observations. The comparisons of astronomical and laboratory data lead to clear conclusions regarding the expected abundances for PAHs in the interstellar environments probed in the surveys. Band profile comparisons between laboratory and astronomical spectra lead to information regarding the molecular structures and characteristics associated with the DIB carriers in the corresponding lines-of-sight. These quantitative surveys of neutral and ionized PAHs in the optical range open the way for quantitative searches of PAHs and complex organics in a variety of interstellar and circumstellar environments.

Iron and Silicate Dust Growth in the Galactic Interstellar Medium: Clues from Element Depletions

NASA Astrophysics Data System (ADS)

Zhukovska, Svitlana; Henning, Thomas; Dobbs, Clare

2018-04-01

The interstellar abundances of refractory elements indicate a substantial depletion from the gas phase, which increases with gas density. Our recent model of dust evolution, based on hydrodynamic simulations of the life cycle of giant molecular clouds (GMCs), proves that the observed trend for [Sigas/H] is driven by a combination of dust growth by accretion in the cold diffuse interstellar medium (ISM) and efficient destruction by supernova (SN) shocks. With an analytic model of dust evolution, we demonstrate that even with optimistic assumptions for the dust input from stars and without destruction of grains by SNe it is impossible to match the observed [Sigas/H]–n H relation without growth in the ISM. We extend the framework developed in our previous work for silicates to include the evolution of iron grains and address a long-standing conundrum: “Where is the interstellar iron?” Much higher depletion of Fe in the warm neutral medium compared to Si is reproduced by the models, in which a large fraction of interstellar iron (70%) is locked as inclusions in silicate grains, where it is protected from efficient sputtering by SN shocks. The slope of the observed [Fegas/H]–n H relation is reproduced if the remaining depleted iron resides in a population of metallic iron nanoparticles with sizes in the range of 1–10 nm. Enhanced collision rates due to the Coulomb focusing are important for both silicate and iron dust models to match the slopes of the observed depletion–density relations and the magnitudes of depletion at high gas density.

Photochemical fractionation of O-16 in the space medium modeled by resonance excitation of CO by H-Lyman alpha

NASA Technical Reports Server (NTRS)

Arrhenius, G.; Corrigan, M. J.; Fitzgerald, R. W.

1988-01-01

Analyses of meteorite matter, the present structure of the solar system, and the evolution of matter in stellar systems are used to provide inferences concerning the formation of primordial matter in the solar system. Results indicate that molecular excitation processes similar to those observed today in circumstellar regions and dark interstellar clouds were operating in the early solar nebula. It is suggested that resonance excitation of broad isotopic bands by strong UV line sources may have resulted in the anomalous isotopic compositions noted in meteorites.

The Abundance and Distribution of Presolar Materials in Cluster IDPS

NASA Technical Reports Server (NTRS)

Messenger, Scott; Keller, Lindsay; Nakamura-Messenger, Keiko; Ito, Motoo

2007-01-01

Presolar grains and remnants of interstellar organic compounds occur in a wide range of primitive solar system materials, including meteorites, interplanetary dust particles (IDPs), and comet Wild-2 samples. Among the most abundant presolar phases are silicate stardust grains and molecular cloud material. However, these materials have also been susceptible to destruction and alteration during parent body and nebular processing. In addition to their importance as direct samples of remote and ancient astrophysical environments, presolar materials thus provide a measure of how well different primitive bodies have preserved the original solar system starting materials.

Ab initio study of C + H3+ reactions

NASA Technical Reports Server (NTRS)

Talbi, D.; DeFrees, D. J.

1991-01-01

The reaction C + H3+ --> CH(+) + H2 is frequently used in models of dense interstellar cloud chemistry with the assumption that it is fast, i.e. there are no potential energy barriers inhibiting it. Ab initio molecular orbital study of the triplet CH3+ potential energy surface (triplet because the reactant carbon atom is a ground state triplet) supports this hypothesis. The reaction product is 3 pi CH+; the reaction is to exothermic even though the product is not in its electronic ground state. No path has been found on the potential energy surface for C + H3+ --> CH2(+) + H reaction.

The Role of Low-Energy (less than 20 eV) Electrons in Astrochemistry: A Tale of Two Molecules

NASA Astrophysics Data System (ADS)

Arumainayagam, Chris

2016-07-01

In the interstellar medium, UV photolysis of ice mantles encasing dust grains is thought to be the mechanism that drives the synthesis of "complex" molecules. The source of this reaction-initiating UV light is assumed to be local because externally-sourced UV radiation cannot pass through the ice-containing dark, dense molecular clouds. Externally sourced cosmic rays (E_{max} ˜10^{20} eV), in addition to producing UV light within these clouds, also produce large numbers of low-energy (≤ 20 eV) secondary electrons. The goal of our studies is to understand the low-energy electron-induced processes that occur when high-energy cosmic rays interact with interstellar ices. Using electron stimulated desorption (ESD), post-irradiation temperature-programmed desorption (TPD), and infrared reflection absorption spectroscopy (IRAS), we have investigated the radiolysis initiated by electrons in condensed methanol and ammonia at ˜90K under ultrahigh vacuum (1 × 10^{-9} Torr) conditions. We have identified fifteen low-energy electron-induced methanol radiolysis products, many of which have been previously identified as being formed by methanol UV photolysis in the interstellar medium. We have also found evidence for the electron-induced formation from ammonia of hydrazine (N_2 H_4), diazene (N_2 H_2), cyclotriazane/triazene (N_3 H_3) and triazane (N_3 H_5). We have investigated the reaction yields' dependence on film thickness, irradiation time, incident current, electron energy, and metal substrate. These results provide a basis from which we can begin to understand the mechanisms by which methanol and ammonia can form more complex species in cosmic ices. Studies such as ours may ultimately help us better understand the initial stages of the genesis of life.

The Role of Low-Energy Electrons in Astrochemistry: A Tale of Two Molecules

NASA Astrophysics Data System (ADS)

Arumainayagam, Chris; Cambell, Jyoti; Leon Sanche, Michael Boyer, and Petra Swiderek.

2016-06-01

In the interstellar medium, UV photolysis of ice mantles encasing dust grains is thought to be the mechanism that drives the synthesis of “complex” molecules. The source of this reaction-initiating UV light is assumed to be local because externally-sourced UV radiation cannot pass through the ice-containing dark, dense molecular clouds. Externally sourced cosmic rays (Emax ~ 1020 eV), in addition to producing UV light within these clouds, also produce large numbers of low-energy (≤ 20 eV) secondary electrons. The goal of our studies is to understand the low-energy electron-induced processes that occur when high-energy cosmic rays interact with interstellar ices. Using electron stimulated desorption (ESD), post-irradiation temperature-programmed desorption (TPD), and infrared reflection absorption spectroscopy (IRAS), we have investigated the radiolysis initiated by electrons in condensed methanol and ammonia at ~ 90 K under ultrahigh vacuum (1×10-9 Torr) conditions. We have identified fifteen low-energy (≤ 20 eV) electron-induced methanol radiolysis products, many of which have been previously identified as being formed by methanol UV photolysis in the interstellar medium. We have also found evidence for the electron-induced formation from ammonia of hydrazine (N2H4), diazene (N2H2), cyclotriazane/triazene (N3H3) and triazane (N3H5). We have investigated the reaction yields’ dependence on film thickness, irradiation time, incident current, electron energy, and metal substrate. These results provide a basis from which we can begin to understand the mechanisms by which methanol and ammonia can form more complex species in cosmic ices. Studies such as ours may ultimately help us better understand the initial stages of the genesis of life.

Constraints on the Cosmic-Ray Density Gradient beyond the Solar Circle from Fermi γ-ray Observations of the Third Galactic Quadrant

DOE PAGES

Ackermann, M.; Ajello, M.; Baldini, L.; ...

2010-12-17

Here,we report an analysis of the interstellar γ-ray emission in the third Galactic quadrant measured by the Fermi Large Area Telescope. The window encompassing the Galactic plane from longitude 210° to 250° has kinematically well-defined segments of the Local and the Perseus arms, suitable to study the cosmic-ray (CR) densities across the outer Galaxy. We measure no large gradient with Galactocentric distance of the γ-ray emissivities per interstellar H atom over the regions sampled in this study. The gradient depends, however, on the optical depth correction applied to derive the H I column densities. No significant variations are found inmore » the interstellar spectra in the outer Galaxy, indicating similar shapes of the CR spectrum up to the Perseus arm for particles with GeV to tens of GeV energies. The emissivity as a function of Galactocentric radius does not show a large enhancement in the spiral arms with respect to the interarm region. The measured emissivity gradient is flatter than expectations based on a CR propagation model using the radial distribution of supernova remnants and uniform diffusion properties. In this context, observations require a larger halo size and/or a flatter CR source distribution than usually assumed. The molecular mass calibrating ratio, X CO = N(H 2)/W CO, is found to be (2.08 ± 0.11) × 10 20 cm -2(K km s –1) –1 in the Local arm clouds and is not significantly sensitive to the choice of H I spin temperature. No significant variations are found for clouds in the interarm region.« less