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Sample records for intracratonic magmas geochemistry

  1. FY 1984 and FY 1985 geochemistry and materials studies in support of the Magma Energy Extraction Program

    SciTech Connect

    Westrich, H.R.; Weirick, L.J.; Cygan, R.T.; Reece, M.; Hlava, P.F.; Stockman, H.W.; Gerlach, T.M.

    1986-04-01

    Geochemistry and materials studies are being performed in support of the Magma Energy Extraction Program. The work is largely restricted to: (1) characterizing magmatic environments at sites of interest, (2) testing engineering materials in laboratory simulated magmatic environments, (3) investigating chemical mass transport effects inherent in designs for direct contact heat exchangers, and (4) evaluating degassing hazards associated with drilling into and extracting energy from shallow magma. Magma characterization studies have been completed for shallow magma at Long Valley, Coso volcanic field, and Kilauea volcano. The behavior of 17 commercially available materials has been examined in rhyolite magma at 850/sup 0/C and 200 MPa for periods up to seven days. Analysis of reaction products from materials tests to date indicate that oxidation is the main corrosion problem for most alloys in rhyolitic magma. Considerations of corrosion resistance, high-temperature strength, and cost indicate nickel-base superalloys offer the most promise as candidates for use in rhyolitic magma.

  2. Geochemistry and materials studies in support of the Magma Energy Extraction Program

    SciTech Connect

    Westrich, H.R.; Weirick, L.J.

    1986-01-01

    Geochemistry and materials studies are being performed in support of the Magma Energy Extraction Program. The scope of the studies is dictated by the sites under consideration and the designs of the drilling and energy extraction systems. The work has been largely restricted to characterizing magmatic environments at sites of interest and testing engineering materials in laboratory simulated rhyolite magmatic environments. The behavior of 17 commercially available materials has been examined at magmatic conditions. Analysis of reaction products reveal that oxidation, and not sulfidation, is the main corrosion problem for most alloys in rhyolite, and that reaction with other magmatic components is limited. Considerations of corrosion resistance, high-temperature strength, and cost indicate nickel-base superalloys offer the most promise as candidates for use in rhyolitic magma.

  3. Palaeoweathering, composition and tectonics of provenance of the Proterozoic intracratonic Kaladgi-Badami basin, Karnataka, southern India: Evidence from sandstone petrography and geochemistry

    NASA Astrophysics Data System (ADS)

    Dey, Sukanta; Rai, A. K.; Chaki, Anjan

    2009-05-01

    Petrographic and geochemical data on the sandstones of the Proterozoic intracratonic Kaladgi-Badami basin, southern India are presented to elucidate the palaeoweathering pattern, and composition and tectonics of their provenance. The Kaladgi-Badami basin, hosting the Kaladgi Supergroup, occupies an E-W trending area. The Supergroup unconformably overlies Archaean basement TTG gneisses, granites and greenstones, comprises a cyclic arenite-pelite-carbonate association and is divided into the Bagalkot and Badami Groups. The immature arkosic character of the basal Saundatti Quartzite Member (Bagalkot Group) containing fresh and angular feldspars, along the northern margin of the basin, suggests that during the initial stage of deposition, this part of the basin received sediments from a restricted, uplifted and less weathered source dominated by K-rich granites occurring to the north. In contrast, the Saundatti Quartzite along the southern margin displays a mostly mature, quartz-rich character with less abundant but severely weathered feldspars, and higher SiO 2 and CIA but lower Al 2O 3, TiO 2, Rb, Sr, Ba, K 2O, K 2O/Na 2O, Zr/Ni and Zr/Cr. This is interpreted in terms of a tectonically stable, considerably weathered mixed source (Archaean gneisses, granites and greenstones) along the southern fringe of the basin. The highly mature (quartz arenite) Muchkundi Quartzite Member (also of the Bagalkot Group), occurring higher up in the succession, exhibits minor but severely altered feldspars, and higher SiO 2, Na 2O, CIA, Cr and Ni with lower K 2O, Al 2O 3, TiO 2 and K 2O/Na 2O. This reflects that with the passage of time the source evolved to a uniform, extensively weathered, tectonically stable peneplained provenance which consisted of less evolved TTG gneisses and greenstones. This was followed by closure, deformation and upliftment of the basin hosting the Bagalkot Group and subsequent deposition of the Badami Group. Sandstone Members of this younger Group (Cave

  4. Sr, Nd, Pb Isotope geochemistry and magma evolution of the potassic volcanic rocks, Wudalianchi, Northeast China

    USGS Publications Warehouse

    Junwen, W.; Guanghong, X.; Tatsumoto, M.; Basu, A.R.

    1989-01-01

    Wudalianchi volcanic rocks are the most typical Cenozoic potassic volcanic rocks in eastern China. Compositional comparisons between whole rocks and glasses of various occurrences indicate that the magma tends to become rich in silica and alkalis as a result of crystal differentiation in the course of evolution. They are unique in isotopic composition with more radiogenic Sr but less radiogenic Pb.87Sr /86 Sr is higher and143Nd/144Nd is lower than the undifferentiated global values. In comparison to continental potash volcanic rocks, Pb isotopes are apparently lower. These various threads of evidence indicate that the rocks were derived from a primary enriched mantle which had not been subjected to reworking and shows no sign of incorporation of crustal material. The correlation between Pb and Sr suggests the regional heterogeneity in the upper mantle in terms of chemical composition. ?? 1989 Institute of Geochemistry, Chinese Academy of Sciences.

  5. Volatile and lithophile trace-element geochemistry of Mexican tin rhyolite magmas deduced from melt inclusions

    NASA Astrophysics Data System (ADS)

    Webster, James D.; Burt, Donald M.; Aguillon, R. A.

    1996-09-01

    We have investigated the petrology and geochemistry of whole rocks from two small-volume, Sn- and F-mineralized rhyolitec dome complexes of the Mexican tin rhyolite belt, Cerro el Lobo and Cerro el Pajaro, to determine volcanic degassing and mineralizing processes in felsic igneous systems. The abundance and distribution of volatiles (H2O, B, F, and Cl) and lithophile trace and ore elements (Li, Rb, Cs, Be, Sr, Y, Ce, Th, U, Nb, Sn, and Mo) in the parental liquids were established by analyzing melt inclusions in quartz. The melt inclusions from both rhyolites are variably enriched in Li and the volatile constituents F and Cl, and some are extremely enriched in Li, although whole rocks are not correspondingly enriched. Compositional variations in the melt inclusions from both rhyolites also constrain magmatic differentiation. Melt evolution was dominated by crystal fractionation, modified by mass transport in a Cl- and H2O-rich magmatic-hydrothermal fluid, and resulted in increasing abundances of U, Nb, and Cs (± Li, F, Cl, B, Y, Ce, Be, Rb, Mo, and Sn) in both liquids. The rhyolite liquids apparently were heterogeneous prior to eruption. The Cerro el Lobo liquid contained gradients in volatiles and trace elements; comparatively less Cl, Be, B, Al2O3, and CaO (± Li, F, U, and Th) were present in the early-erupted, H2O-rich fractions of liquid. Comparing compositions of whole rocks with the mean compositions of melt inclusions constrains relative mobilities of magmatic constituents during and after eruption. Sodium, fluorine, lithium, uranium, and yttrium (± H2O, Cl, Sn) were lost from both magmas and the Cerro el Pajaro magma apparently also lost Nb and Al as a result of eruptive and posteruptive degassing. These geochemical relationships and constraints on pre-eruptive abundances and distributions of volatiles in tin rhyolite magmas probably apply to other tin rhyolites and, moreover, the high levels of Cl and Li enrichment maybe representative of other highly

  6. Geochemistry of the mantle source and magma feeding system beneath Turrialba volcano, Costa Rica

    NASA Astrophysics Data System (ADS)

    Di Piazza, A.; Rizzo, A. L.; Barberi, F.; Carapezza, M. L.; De Astis, G.; Romano, C.; Sortino, F.

    2015-09-01

    Turrialba volcano lies in the southern sector of the Central American Volcanic Front (CAVF) in Costa Rica. The geochemistry of major and trace elements, and Sr and Nd isotopes of a selected suite of volcanic rocks ranging in composition from basaltic andesite to dacite and belonging to the last 10 ka of activity of Turrialba volcano is described, together with the He-, Ne-, and Ar-isotope compositions of fluid inclusions hosted in olivine and pyroxene crystals. Most of the variability in the rock chemistry is consistent with typical trends of fractional crystallization, but there is an outlying group of andesites that displays an adakite-like composition (with a consistent depletion in high-field-strength elements and a marked enrichment in Sr) and low 3He/4He ratios (7.0-7.2 Ra). The trace-element composition of these rocks is typical of subduction-related magmas influenced by an OIB-like component at the source associated with the subduction of the Galapagos seamounts. The 87Sr/86Sr (0.703612-0.703678) and 143Nd/144Nd (0.512960-0.512984) ratios of the bulk rocks vary within narrow ranges, and are among the least-radiogenic isotope signatures of the CAVF volcanoes. The 3He/4He ratios measured in fluid inclusions hosted in olivine crystals (up to 8.1 Ra) are among the highest for the CAVF, and indicate that radiogenic 4He from fluids derived from the subducting slab contribute negligibly to the mantle wedge. The difference in He isotopes between most of studied rocks and those showing adakite-like features reasonably reflects two distinct components in the local mantle: (1) a MORB-like component, characterized by the highest He-isotope ratios (7.8-8.1 Ra), and (2) an OIB-like component, characterized by lower He-isotope ratios (7.0-7.2 Ra), coming from the subduction of the Galapagos seamounts. An overview at the regional scale indicates that high He-isotope ratios are peculiar to the two extreme sectors of the CAVF (Costa Rica to the south and Guatemala to the

  7. Geochemistry of basalts from small eruptive centers near Villarrica stratovolcano, Chile: Evidence for lithospheric mantle components in continental arc magmas

    NASA Astrophysics Data System (ADS)

    Hickey-Vargas, R.; Sun, M.; Holbik, S.

    2016-07-01

    In the Central Southern Volcanic Zone (CSVZ) of the Andes, the location of stratovolcanoes and monogenetic small eruptive centers (SEC) is controlled by the Liquiñe-Ofqui Fault Zone (LOFZ), a trench-parallel strike-slip feature of over 1000 km length. The geochemistry of basalts from SEC is different from those of stratovolcanoes, and are termed Type 2 and Type 1 basalts, respectively. In the region of Villarrica stratovolcano, contemporaneous SEC are more MgO-rich, and have greater light rare earth element (LREE) enrichment, lower 87Sr/86Sr and 143Nd/144Nd, and lower ratios of large ion lithophile elements (LILE) to LREE and high field strength elements (HFSE). A unique finding in this region is that basalts from one SEC, San Jorge, has Type 1 character, similar to basalts from Villarrica stratovolcano. Type 1 basalts from Villarrica and San Jorge SEC have strong signals from time-sensitive tracers of subduction input, such as high 10Be/9Be and high (238U/230Th), while Type 2 SEC have low 10Be/9Be and (238U/230Th) near secular equilibrium. Based on new trace element, radiogenic isotope and mineral analyses, we propose that Type 1 basaltic magma erupted at San Jorge SEC and Villarrica stratovolcano forms by melting of the ambient actively subduction-modified asthenosphere, while Type 2 SEC incorporate melts of pyroxenite residing in the supra-subduction zone mantle lithosphere. This scenario is consistent with the close proximity of the volcanic features and their inferred depths of magma separation. The pyroxenite forms from arc magma produced during earlier episodes of subduction modification and magmatism, which extend back >300 Ma along this segment of the western South American margin. Type 2 basaltic magmas may reach the surface during LOFZ-related decompression events, and they may also be a normal but episodic part of the magma supply to large stratovolcanoes, resulting in cryptic geochemical variations over time. The presence and mobilization of stored

  8. Magma genesis, storage and eruption processes at Aluto volcano, Ethiopia: lessons from remote sensing, gas emissions and geochemistry

    NASA Astrophysics Data System (ADS)

    Hutchison, William; Biggs, Juliet; Mather, Tamsin; Pyle, David; Gleeson, Matthew; Lewi, Elias; Yirgu, Gezahgen; Caliro, Stefano; Chiodini, Giovanni; Fischer, Tobias

    2016-04-01

    One of the most intriguing aspects of magmatism during the transition from continental rifting to sea-floor spreading is that large silicic magmatic systems develop within the rift zone. In the Main Ethiopian Rift (MER) these silicic volcanoes not only pose a significant hazard to local populations but they also sustain major geothermal resources. Understanding the journey magma takes from source to surface beneath these volcanoes is vital for determining its eruption style and for better evaluating the geothermal resources that these complexes host. We investigate Aluto, a restless silicic volcano in the MER, and combine a wide range of geochemical and geophysical techniques to constrain magma genesis, storage and eruption processes and shed light on magmatic-hydrothermal-tectonic interactions. Magma genesis and storage processes at Aluto were evaluated using new whole-rock geochemical data from recent eruptive products. Geochemical modelling confirms that Aluto's peralkaline rhyolites, that constitute the bulk of recent erupted products, are generated from protracted fractionation (>80 %) of basalt that is compositionally similar to rift-related basalts found on the margins of the complex. Crustal melting did not play a significant role in rhyolite genesis and melt storage depths of ~5 km can reproduce almost all aspects of their geochemistry. InSAR methods were then used to investigate magma storage and fluid movement at Aluto during an episode of ground deformation that took place between 2008 and 2010. Combining new SAR imagery from different viewing geometries we identified an accelerating uplift pulse and found that source models support depths of magmatic and/or fluid intrusion at ~5 km for the uplift and shallower depths of ~4 km for the subsidence. Finally, gas samples collected on Aluto in 2014 were used to evaluate magma and fluid transport processes. Our results show that gases are predominantly emanating from major fault zones on Aluto and that they

  9. Temporal Evolution of Volcanic and Plutonic Magmas Related to Porphyry Copper Ores Based on Zircon Geochemistry

    NASA Astrophysics Data System (ADS)

    Dilles, J. H.; Lee, R. G.; Wooden, J. L.; Koleszar, A. M.

    2015-12-01

    Porphyry Cu (Mo-Au) and epithermal Au-Ag ores are globally associated with shallow hydrous, strongly oxidized, and sulfur-rich arc intrusions. In many localities, long-lived magmatism includes evolution from early andesitic volcanic (v) and plutonic (p) rocks to later dacitic or rhyolitic compositions dominated by plutons. We compare zircon compositions from three igneous suites with different time spans: Yerington, USA (1 m.y., p>v), El Salvador, Chile (4 m.y., p>v), and Yanacocha, Peru (6 m.y., v>p). At Yerington granite dikes and ores formed in one event, at ES in 2 to 3 events spanning 3 m.y., and at Yanacocha in 6 events spanning 5 m.y. At both ES and Yanacocha, high-Al amphiboles likely crystallized at high temperature in the mid-crust and attest to deep magmas that periodically recharged the shallow chambers. At Yanacocha, these amphiboles contain anhydrite inclusions that require magmas were sulfur-rich and strongly oxidized (~NNO+2). The Ti-in-zircon geothermometer provides estimates of 920º to 620º C for zircon crystallization, and records both core to rim cooling and locally high temperature rim overgrowths. Ore-related silicic porphyries yield near-solidus crystallization temperatures of 750-650°C consistent with low zircon saturation temperatures. The latter zircons have large positive Ce/Ce* and small negative Eu/Eu*≥0.4 anomalies attesting to strongly oxidized conditions (Ballard et al., 2001), which we propose result from crystallization and SO2 loss to the magmatic-hydrothermal ore fluid (Dilles et al., 2015). The Hf, REE, Y, U, and Th contents of zircons are diverse in the magma suites, and Th/U vs Yb/Gd plots suggest a dominant role of crystal fractionation with lesser roles for both crustal contamination and mixing with high temperature deep-sourced mafic magma. Ce/Sm vs Yb/Gd plots suggest that magma REE contents at <900°C are dominated by early crystallization of hornblende and apatite, and late crystallization (~<780°C) of titanite

  10. Change in Magma Dynamics at Okataina Rhyolite Caldera revealed by Plagioclase Textures and Geochemistry

    NASA Astrophysics Data System (ADS)

    Shane, P. A. R.

    2015-12-01

    A fundamental reorganization of magma dynamics at Okataina volcano, New Zealand, occurred at 26 ka involving a change from smaller volume, high-temperature rhyodacite magmas to a lower eruptive tempo of larger volume, low-temperature, rhyolite magmas. Zircon studies demonstrate the presence of a periodically active, long-lived (100,000 yr) magmatic reservoir. However, there is little correlation between periods of zircon crystallization and eruption events. In contrast, the changing magmatic dynamics is revealed in plagioclase growth histories. Crystals from the ~0.7 ka Kaharoa eruption are characterized by resorbed cores displaying a cellular-texture of high-An (>40) zones partially replaced by low-An (<30) zones, surrounded by a resorption surface and a prominent normal-zoned rim (An50-20). Elevated An, Fe, Mg, Sr and Ti follow the resorption surface and display rimward depletion trends, accompanied by Ba and REE enrichment. The zonation is consistent with fractional crystallization and cooling. The cores display wide trace element diversity, pointing to crystallization in a variety of melts, before transport and mixing into a common magma where the rims grew. Plagioclase from the ~36 ka Hauparu eruption display several regrowth zones separated by resorption surfaces, which surround small resorbed cores with a spongy cellular texture of variable An content (An 40-50). The crystals display step-wise re-growth of successively higher An, Fe, Mg and Ti content, consistent with progressive mafic recharge. Two crystal groups are distinguished by trace element chemistry indicating growth in separate melts and co-occurrence via magma-mingling. The contrasting zoning patterns in plagioclase correspond to the evolutionary history of magmatism at Okataina. Emptying of the magma reservoir following caldera eruption at 46 ka reduced barriers to mafic magma ascent. This is recorded by the frequent resorption and recharge episodes in Hauparu crystals. Subsequent re

  11. Geochemistry.

    ERIC Educational Resources Information Center

    Fyfe, William S.

    1979-01-01

    Techniques in geochemistry continue to improve in sensitivity and scope. The exciting areas of geochemistry still include the classical fields of the origin of the elements and objects in space, but environmental crisis problems are important as well. (Author/BB)

  12. Geochemistry

    ERIC Educational Resources Information Center

    Ailin-Pyzik, Iris B.; Sommer, Sheldon E.

    1977-01-01

    Enumerates some of the research findings in geochemistry during the last year, including X-ray analysis of the Mars surface, trace analysis of fresh and esterarine waters, and analysis of marine sedements. (MLH)

  13. Magma Plumbing and Transport at Yellowstone--Implications from Geodesy and Geochemistry (Invited)

    NASA Astrophysics Data System (ADS)

    Dzurisin, D.; Wicks, C. W.; Lowenstern, J. B.

    2013-12-01

    Surface deformation, thermal activity, and outgassing at the Yellowstone caldera are manifestations of a vigorous magmatic system that has been active for more than 2 million years. Viable models for Yellowstone's magma plumbing and transport system must account for: (1) high contemporary fluxes of heat and CO2; (2) ground deformation sources beneath each of two resurgent domes, and a third near the intersection of the north caldera rim and Norris-Mammoth corridor; (3) interplay among these sources, as suggested by the timing of major changes in deformation mode; (4) repeated cycles of uplift and subsidence and sudden changes from uplift to subsidence or vice versa; (5) spatial and temporal relationships between changes in deformation mode and earthquake swarms; and (6) lateral dimensions of all three deforming areas that indicate source depths in the range 5-15 km. Seismic tomography studies have imaged a partly molten silicic magma body in the upper crust beneath the caldera and a mantle feeder zone for mafic magma. A model in which surface displacements are caused primarily by variations in the flux of mafic magma into the crust satisfies known thermal, geochemical, and geodetic constraints. In the model, a conduit system centered beneath the northeast part of the caldera supplies basalt from a mantle source to an accumulation zone 5-10 km deep, perhaps at a rheological boundary beneath a crystal-rich rhyolite body remnant from past eruptions. Increases in magma flux favor surface uplift and decreases favor subsidence. A delicate equilibrium exists among the mass and heat flux from basaltic intrusions, heat and volatile loss from the rhyolite, and the overlying hydrothermal system. In the absence of basalt input, steady subsidence should occur as a result of fluid loss from the rhyolite, but if a self-sealing zone in the deep hydrothermal system prevents fluid escape the resulting pressure increase contributes to surface uplift. Such episodes end when the seal

  14. Geochemistry and petrogenesis of the Fiskenaesset anorthosite complex, southern West Greenland: Nature of the parent magma

    NASA Astrophysics Data System (ADS)

    Weaver, Barry L.; Tarney, John; Windley, Brian

    1981-05-01

    The petrogenesis of the Fiskenaesset anorthosite body has been investigated using major and trace element data for a large range of rock types from each zone of the complex. The chemistry of these ultramafic to anorthositic cumulates is interpreted in terms of crystal fractionation of a parental, trace element impoverished, tholeiitic magma, involving crystallisation of the cumulus phases olivine, orthopyroxene, clinopyroxene and (dominant) plagioclase feldspar. Amphibole appears not to have been a significant cumulus phase at any stage of crystallisation of the body, the abundant amphibole found in the rocks of the complex being produced by primary intercumulus crystallisation, supplemented by secondary metamorphic recrystallisation. Similarly, magnetite is unlikely to have been a significant early cumulus phase, although, together with chromite, it crystallised as a cumulus phase at high stratigraphic levels in the complex. The metamorphism appears to be largely isochemical, although sub-solidus metamorphic re-equilibration of the REE can be demonstrated on a grain-size scale. The spatial and temporal association between the anorthosite complex and the bordering metavolcanic amphibolites is matched by a strong similarity between the observed trace element chemistry of the amphibolites and the trace element chemistry of calculated successive liquids for the complex. This is taken to suggest a genetic relationship between the evolution of the anorthosite complex and enclosing amphibolites. The presence of trace element impoverished amphibolites (which are not cumulates) with trace element abundances comparable to those of the suggested parental liquid to the anorthosite complex, is used to derive a major element composition for the primary Fiskenasset magma. This composition approximates a moderately aluminous tholeiitic basalt, which may have been generated by hydrous fusion of previously depleted mantle. This primary magma underwent crystal fractionation under

  15. Magma evolution as seen through zircon geochemistry: an example from the Southern Adamello Batholith, N. Italy

    NASA Astrophysics Data System (ADS)

    Broderick, C.; Schaltegger, U.; Gerdes, A.; Frick, D.; Guenther, D.; Brack, P.

    2012-04-01

    Zircon is an ubiquitous accessory mineral often used for U-Pb geochronology but is also an important recorder of geochemical information. The trace element and isotopic characteristics of zircon yield potential for tracking changes in an evolving magma through time. With recent advances in U-Pb zircon geochronology, 10-100 ka to Ma timescales are observed for incremental pluton construction (Michel et al., 2008, Schaltegger et al., 2009). In observed 100 ka timescales of zircon crystallization, can zircon record the processes that produce trace element variations in a magma? This study focuses on the Val Fredda Complex (VFC) in the southern tip of the 43 to 33 Ma Adamello batholith, N. Italy. The VFC displays complex relationships among mafic melts that were injected into solidifying felsic magmas. Single zircon crystals were dated using CA-ID-TIMS. With permil uncertainties on 206Pb/238U zircon dates, zircons reveal complexities within single populations. The mafic units crystallized potential autocrystic zircons over a duration of 100 - 150ka, whereas the felsic units record up to 200ka of zircon crystallization. In order to understand these complex zircon populations, we analyzed Hf isotopes and trace elements, on the same volume of zircon used for U-Pb dating, following the TIMS-TEA method (Schoene et al., 2010). This detailed zircon study will allow us to look at how magmas are evolving with time. Hf isotopes of VFC mafic zircons reveal distinct ɛHf values between the three mafic units and their ɛHf values remain consistent through time, whereas the VFC felsic units record more complexity in their ɛHf values. We observe changes such as increasing and slight decreases in ɛHf with time which suggest different processes are occurring to produce the different felsic units. Trace element ratios in zircon reveal differences which allow us to make distinctions between felsic and mafic units (e.g. Th/U, (Lu/Gd)N, REEs). The VFC records 200 ka of zircon

  16. Geochemistry and argon thermochronology of the Variscan Sila Batholith, southern Italy: source rocks and magma evolution

    USGS Publications Warehouse

    Ayuso, R.A.; Messina, A.; de Vivo, B.; Russo, S.; Woodruff, L.G.; Sutter, J.F.; Belkin, H.E.

    1994-01-01

    . Although the granitic groups cannot be uniquely distinguished on the basis of their Pb isotope compositions most of the post-tectonic tonalites to granodiorites as well as two-mica granites are somewhat less radiogenic than the syn-tetonic tonalites and granodiorites. Only a few of the mafic enclaves overlap the Pb isotope field of the granitic rocks and are consistent with a cogenetic origin. The Sila batholith was generated by mixing of material derived from at least two sources, mantle-derived and crustal, during the closing stages of plate collision and post-collision. The batholith ultimately owes its origin to the evolution of earlier, more mafic parental magmas, and to complex intractions of the fractionating mafic magmas with the crust. Hybrid rocks produced by mixing evolved primarily by crystal fractionation although a simple fractionation model cannot link all the granitic rocks, or explain the entire spectrum of compositions within each group of granites. Petrographic and geochemical features characterizing the Sila batholith have direct counterparts in all other granitic massifs in the Calabrian-Peloritan Arc. This implies that magmatic events in the Calabrian-Peloritan Arc produced a similar spectrum of granitic compositions and resulted in a distinctive type of granite magmatism consisting of coeval, mixed, strongly peraluminous and metaluminous granitic magmas. ?? 1994 Springer-Verlag.

  17. A two-component mantle source feeding Mt. Etna magmatism: Insights from the geochemistry of primitive magmas

    NASA Astrophysics Data System (ADS)

    Correale, Alessandra; Paonita, Antonio; Martelli, Mauro; Rizzo, Andrea; Rotolo, Silvio G.; Corsaro, Rosa Anna; Di Renzo, Valeria

    2014-01-01

    The major elements, trace elements and Sr and Nd isotopes of selected Etnean primitive rocks (< 15 ky BP) were studied in order to characterize their mantle source. The noble-gas geochemistry of fluid inclusions in minerals from the same lavas was also investigated. The major element compositions of whole rocks and minerals showed that these products are among the most primitive at Mt. Etna, comprising 6.3-17.5 wt.% MgO. The variable LREE (Light Rare Earth Elements) enrichment relative to MORB (Mid-Ocean Ridge Basalt) (Lan/Ybn = 11-26), together with the patterns of certain trace-element ratios (i.e., Ce/Yb versus Zr/Nb and Th/Y versus La/Yb), can be attributed to varying degrees of melting of a common mantle source. Numerical simulations performed with the MELTS program allowed the melting percentages associated with each product to be estimated. This led us to recalculate the hypothetical parental trace-element content of the Etnean mantle source, which was common to all of the investigated rocks. The characteristics of the Sr, Nd and He isotopes confirmed the primitive nature of the rocks, with the most-depleted and primitive lava being that of Mt. Spagnolo (SPA; 143Nd/144Nd = 0.512908 87Sr/86Sr = 0.703317-0.703325 and 3He/4He = 7.6 Ra), and highlighted the similarity of the mantle sources feeding the volcanic activity of Mt. Etna and the Hyblean Plateau (a region to the south of Mt. Etna and characterized by older magmatism than Mt. Etna). The coupling of noble gases and trace elements suggests an origin for the investigated Etnean lavas from melting of a Hyblean-like mantle, consisting of a two-component source where a peridotitic matrix is veined by 10% pyroxenite. A variable degree of mantle contamination by crustal-like fluids, probably related to subduction, is proposed to explain the higher Sr-isotope and lower Nd-isotope values in some rocks (143Nd/144Nd up to 0.512865 and 87Sr/86Sr up to 0.703707). This process probably occurred in the source prior to

  18. Unraveling the geochemistry of melts in exhumed mantle domains in present-day and fossil magma-poor rifted margins

    NASA Astrophysics Data System (ADS)

    Amann, Méderic; Ulrich, Marc; Autin, Julia; Manatschal, Gianreto; Epin, Marie-Eva; Müntener, Othmar; Boiron, Marie-Christine; Sauter, Daniel

    2016-04-01

    899B are less LREE depleted compared to clinopyroxenes from other sites in the Iberia margin, showing a lower partial melting rate and thus a differential magmatic activity within this margin transect trough time and space. Moreover, new analysis on clinopyroxenites from ODP leg 173 site 1070, will help to constrain the PT conditions during formation of the OCT. Future work in the Platta nappe will be useful to test whether or not the geochemistry of melts and its establishment are defined by the same characteristics in fossil magma-poor margins.

  19. Age and geochemistry of the Newania dolomite carbonatites, India: implications for the source of primary carbonatite magma

    NASA Astrophysics Data System (ADS)

    Ray, Jyotiranjan S.; Pande, Kanchan; Bhutani, Rajneesh; Shukla, Anil D.; Rai, Vinai K.; Kumar, Alok; Awasthi, Neeraj; Smitha, R. S.; Panda, Dipak K.

    2013-12-01

    The Newania carbonatite complex of India is one of the few dolomite-dominated carbonatites of the world. Intruding into Archean basement gneisses, the rocks of the complex have undergone limited diversification and are not associated with any alkaline silicate rock. Although the magmatic nature of the complex was generally accepted, its age of emplacement had remained equivocal because of the disturbed nature of radioisotope systems. Many questions about the nature of its mantle source and mode of origin had remained unanswered because of lack of geochemical and isotopic data. Here, we present results of our effort to date the complex using 147Sm-143Nd, 207Pb-206Pb and 40Ar-39Ar dating techniques. We also present mineral chemistry, major and trace element geochemistry and Sr-Nd isotopic ratio data for these carbonatites. Our age data reveal that the complex was emplaced at ~1,473 Ma and parts of it were affected by a thermal event at ~904 Ma. The older 207Pb-206Pb ages reported here (~2.4 Ga) and by one earlier study (~2.3 Ga; Schleicher et al. Chem Geol 140:261-273, 1997) are deemed to be a result of heterogeneous incorporation of crustal Pb during the post-emplacement thermal event. The thermal event had little effect on many magmatic signatures of these rocks, such as its dolomite-magnesite-ankerite-Cr-rich magnetite-magnesio-arfvedsonite-pyrochlore assemblage, mantle like δ13C and δ18O and typical carbonatitic trace element patterns. Newania carbonatites show fractional crystallization trend from high-Mg to high-Fe through high-Ca compositions. The least fractionated dolomite carbonatites of the complex possess very high Mg# (≥80) and have similar major element oxide contents as that of primary carbonatite melts experimentally produced from peridotitic sources. In addition, lower rare earth element (and higher Sr) contents than a typical calcio-carbonatite and mantle like Nb/Ta ratios indicate that the primary magma for the complex was a magnesio

  20. Magma energy

    SciTech Connect

    Dunn, J.C.

    1987-01-01

    The thermal energy contained in magmatic systems represents a huge potential resource. In the US, useful energy contained in molten and partially-molten magma within the upper 10 km of the crust has been estimated at 5 to 50 x 10/sup 22/ J (50,000 to 500,000 Quads). The objective of the Magma Energy Extraction Program is to determine the engineering feasibility of locating, accessing, and utilizing magma as a viable energy resource. This program follows the DOE/OBES-funded Magma Energy Research Project that concluded scientific feasibility of the magma energy concept. A primary long-range goal of this program is to conduct an energy extraction experiment directly in a molten, crustal magma body. Critical to determining engineering feasibility are several key technology tasks: (1) Geophysics - to obtain detailed definition of potential magma targets, (2) Geochemistry/Materials - to characterize the magma environment and select compatible engineering materials, (3) Drilling - to develop drilling and completion techniques for entry into a magma body, and (4) Energy Extraction - to develop heat extraction technology.

  1. Hydrocarbon potential of intracratonic rift basins

    SciTech Connect

    Baker, D.G.; Derksen, S.J.

    1984-09-01

    Significant world oil reserves have been added in recent years from rift system. Examples of petroliferous rift basins may be found on nearly every major continent. As our understanding of the mechanisms of sedimentation and structure in rift basins grows, more rift systems will be found. With a few notable exceptions, rifts that have been explored in the past are those that formed along continental margins. These contain marine sediments, and the conditions of source rock, sediment type, depositional environment, and structural style are well-known exploration concepts. Intracratonic rift systems containing continental sediments, and also because of the problems perceived to accompany continental sedimentation. A good modern analog is the East African rift system. Several companies have made significant oil discoveries in different components of the Central African rift system. Average daily production for 1982 from the basins associated with the Benue trough was 107.928 BOPD. In the Abu Gabra rift component, where Marathon is currently exploring, Chevron has drilled approximately 60 wells. Nineteen of these were discoveries and tested an average rate per well of 3,500 BOPD. The Abu Gabra rift may contain up to 10 billion bbl of oil. Research indicates that this type of rift system is present in other areas of the world. Ongoing worldwide exploration has shown that intracratonic rift basins have the potential to make a significant contribution to world oil reserves.

  2. Mechanisms and timescales of generating eruptible rhyolitic magmas at Yellowstone caldera from zircon and sanidine geochronology and geochemistry

    USGS Publications Warehouse

    Stelten, Mark; Cooper, Kari M.; Vazquez, Jorge A.; Calvert, Andrew T.; Glessner, Justin G

    2015-01-01

    We constrain the physical nature of the magma reservoir and the mechanisms of rhyolite generation at Yellowstone caldera via detailed characterization of zircon and sanidine crystals hosted in three rhyolites erupted during the (ca. 170 – 70 ka) Central Plateau Member eruptive episode – the most recent post-caldera magmatism at Yellowstone. We present 238U-230Th crystallization ages and trace-element compositions of the interiors and surfaces (i.e., unpolished rims) of individual zircon crystals from each rhyolite. We compare these zircon data to 238U- 230Th crystallization ages of bulk sanidine separates coupled with chemical and isotopic data from single sanidine crystals. Zircon age and trace-element data demonstrate that the magma reservoir that sourced the Central Plateau Member rhyolites was long-lived (150 – 250 kyr) and genetically related to the preceding episode of magmatism, which occurred ca. 256 ka. The interiors of most zircons in each rhyolite were inherited from unerupted material related to older stages of Central Plateau Member magmatism or the preceding late Upper Basin Member magmatism (i.e., are antecrysts). Conversely, most zircon surfaces crystallized near the time of eruption from their host liquids (i.e., are autocrystic). The repeated recycling of zircon interiors from older stages of magmatism demonstrates that sequentially erupted Central Plateau Member rhyolites are genetically related. Sanidine separates from each rhyolite yield 238U-230Th crystallization ages at or near the eruption age of their host magmas, coeval with the coexisting zircon surfaces, but are younger than the coexisting zircon interiors. Chemical and isotopic data from single sanidine crystals demonstrate that the sanidines in each rhyolite are in equilibrium with their host melts, which considered along with their near-eruption crystallization ages suggests that nearly all CPM sanidines are autocrystic. The paucity of antecrystic sanidine crystals relative to

  3. Mineralogy and geochemistry of microgranular enclaves in Palaeoproterozoic Malanjkhand granitoids, central India: evidence of magma mixing, mingling, and chemical equilibration

    NASA Astrophysics Data System (ADS)

    Kumar, Santosh; Rino, Vikoleno

    2006-11-01

    Palaeoproterozoic ( ca 2,480 Ma) felsic magmatism of Malanjkhand region of central Indian Precambrian shield, referred to as Malanjkhand granitoids (MG), contain xenoliths of country rocks and mesocratic to melanocratic, fine-grained porphyritic microgranular enclaves (ME). The shape of ME is spheroidal, ellipsoidal, discoidal, elongated, and lenticular, varying in size from a few centimeters to about 2 m across. The contact of ME with the host MG is commonly sharp, crenulate, and occasionally diffuse, which we attribute to the undercooling and disaggregation of ME globules within the cooler host MG. The ME as well as MG show hypidiomorphic texture with common mineral Hbl-Bt-Kfs-Pl-Qtz assemblage, but differ in modal proportions. The variation in minerals' composition, presence of apatite needles, elongated biotites, resorbed plagiclase, ocellar quartz, and other mafic-felsic xenocrysts strongly oppose the restite and cognate origins of ME. Compositions of plagioclases (An3-An29), amphiboles (Mg/Mg+Fe2+=0.55-0.69), and biotites (Mg/Mg+Fe2+=0.46-0.60) of ME are slightly distinct or similar to those of MG, which suggest partial to complete equilibration during mafic-felsic magma interactions. Al-in-amphibole estimates the MG pluton emplacement at ca 3.4 ± 0.5 kbar, and therefore, magma mixing and mingling must have occurred at or below this level. The FerightleftharpoonsMg substitution in biotites of ME and MG largely suggests subduction-related, calc-alkaline metaluminous (I-type) nature of felsic melts. Most major and trace elements against SiO2 produce near linear variation trends for ME and MG, probably generated by the mixing of mafic and felsic magmas in various proportions. Trace including rare earth elements patterns of ME-MG pairs, however, show partial to complete equilibration, most likely governed by different degrees of elemental diffusion. The available evidence supports the model of ME origin that coeval mafic (enclave) and felsic (MG) magmas produced

  4. Geochemistry of lavas from Taal volcano, southwestern Luzon, Philippines: evidence for multiple magma supply systems and mantle source heterogeneity

    USGS Publications Warehouse

    Miklius, Asta; Flower, M.F.J.; Huijsmans, J.P.P.; Mukasa, S.B.; Castillo, P.

    1991-01-01

    Taal lava series can be distinguished from each other by differences in major and trace element trends and trace element ratios, indicating multiple magmatic systems associated with discrete centers in time and space. On Volcano Island, contemporaneous lava series range from typically calc-alkaline to iron-enriched. Major and trace element variation in these series can be modelled by fractionation of similar assemblages, with early fractionation of titano-magnetite in less iron-enriched series. However, phase compositional and petrographic evidence of mineral-liquid disequilibrium suggests that magma mixing played an important role in the evolution of these series. -from Authors

  5. Trace element geochemistry of nyerereite and gregoryite phenocrysts from natrocarbonatite lava, Oldoinyo Lengai, Tanzania: Implications for magma mixing

    NASA Astrophysics Data System (ADS)

    Mitchell, Roger H.; Kamenetsky, Vadim S.

    2012-11-01

    The abundances of Li, P, Cl, V, Mn, Rb, Sr, Y, Cs, Ba, Pb, Th, U and REE, within and between, phenocrysts of nyerereite and gregoryite occurring in natrocarbonatite lavas erupted from the active volcano Oldoinyo Lengai (Tanzania) have been determined by electron microprobe, LA-ICP-MS and SIMS. These data show that, in general, nyerereite is enriched in Rb (71-137 ppm), Sr (14,485-23,240 ppm), Y (2.0-8.9 ppm), Cs (1.6-5.3 ppm), Ba (4000-11,510 ppm), but poorer in Li (21-91 ppm), P (820-1900 ppm) and V (5.1-47 ppm) relative to gregoryite (Rb = 43-106; Sr = 4255-7275; Y = 0.3-4.0; Cs = 0.6-5.1; Ba = 1125-7052; Li 84-489; P = 6790-15,860; V = 33-155 ppm). Nyerereite is highly enriched in REE (La = 236-973; Ce = 395-1044 ppm) relative to gregoryite (La = 59-309; Ce = 59-301 ppm). Chondrite normalized REE distribution patterns for nyerereite and gregoryite are parallel and linear with no Eu anomalies. They show extreme enrichment in light REE and depletion in heavy REE (nyerereite La/YbCN = 1759-7079; gregoryite La/YbCN = 1051-10,247). Significant differences exist in the abundances of trace elements within and between coexisting crystals occurring in diverse natrocarbonatite flows, although there do not appear to be any significant secular variations in phenocryst compositions in lavas erupted from a given vent. It is concluded that both major, minor and trace element compositional data for nyerereite and gregoryite phenocrysts occurring in natrocarbonatite lavas are derived by the crystallization of several different batches of magma in a continuously replenished fractionating magma chamber. Natrocarbonatite lavas are considered to be hybrids formed by the mixing of both crystals and melts formed from several batches of natrocarbonatite magma; thus bulk rock compositions cannot represent the compositions of the primary magma composition before the onset of fractionation. Differentiation of natrocarbonatite melts leads to enrichment of residua in Ba and Mg.

  6. Isotope geochemistry of early Kilauea magmas from the submarine Hilina bench: The nature of the Hilina mantle component

    USGS Publications Warehouse

    Kimura, Jun-Ichi; Sisson, Thomas W.; Nakano, Natsuko; Coombs, Michelle L.; Lipman, Peter W.

    2006-01-01

    Submarine lavas recovered from the Hilina bench region, offshore Kilauea, Hawaii Island provide information on ancient Kilauea volcano and the geochemical components of the Hawaiian hotspot. Alkalic lavas, including nephelinite, basanite, hawaiite, and alkali basalt, dominate the earliest stage of Kilauea magmatism. Transitional basalt pillow lavas are an intermediate phase, preceding development of the voluminous tholeiitic subaerial shield and submarine Puna Ridge. Most alkalic through transitional lavas are quite uniform in Sr–Nd–Pb isotopes, supporting the interpretation that variable extent partial melting of a relatively homogeneous source was responsible for much of the geochemical diversity of early Kilauea magmas (Sisson et al., 2002). These samples are among the highest 206Pb/204Pb known from Hawaii and may represent melts from a distinct geochemical and isotopic end-member involved in the generation of most Hawaiian tholeiites. This end-member is similar to the postulated literature Kea component, but we propose that it should be renamed Hilina, to avoid confusion with the geographically defined Kea-trend volcanoes. Isotopic compositions of some shield-stage Kilauea tholeiites overlap the Hilina end-member but most deviate far into the interior of the isotopic field defined by magmas from other Hawaiian volcanoes, reflecting the introduction of melt contributions from both “Koolau” (high 87Sr/86Sr, low 206Pb/204Pb) and depleted (low 87Sr/86Sr, intermediate 206Pb/204Pb) source materials. This shift in isotopic character from nearly uniform, end-member, and alkalic, to diverse and tholeiitic corresponds with the major increase in Kilauea's magmatic productivity. Two popular geodynamic models can account for these relations: (1) The upwelling mantle source could be concentrically zoned in both chemical/isotopic composition, and in speed/extent of upwelling, with Hilina (and Loihi) components situated in the weakly ascending margins and the

  7. Zircon trace element geochemistry and growth of the Pleistocene to Holocene Mono Craters rhyolite magma system, California (USA)

    NASA Astrophysics Data System (ADS)

    Baker, N.; Miller, J. S.; Vazquez, J. A.; Marcaida, M.; Lidzbarski, M. I.

    2015-12-01

    The Mono Craters, part of the Mono-Inyo volcanic chain in eastern California, comprise at least 27 high-silica Pleistocene to Holocene rhyolite domes, lava flows and tephra cones. The Holocene chronology of the Mono Craters is well constrained but only recently has 238U-230Th zircon and 40Ar/39Ar dating elucidated the Pleistocene eruptive history. We performed trace element analysis on dated zircon crystal rims and sectioned interiors (using SHRIMP-RG) from 3 rhyolite domes (21, 12.5, and 7 ka) with additional rim data on 5 ashes separated from juvenile pumice clasts in the correlative Wilson Creek Formation (spanning from 62 to 21 ka). Ti-in-zircon (TTi,zrc) thermometry (titania activity from coexisting Fe-Ti oxides) gives temperatures predominantly between 650°C and 750°C, similar to average zircon saturation temperatures (Tzrc,sat). The observation that Tzrc,sat ≈ TTi,zrc indicates that Mono Craters rhyolite magmas were zircon-saturated and erupted at these temperatures (near water-saturated granite eutectic). Variations in key trace elements are relatively limited overall and zircons display similar REE patterns with generally curved MREE to HREE patterns and prominent negative Eu anomalies. Most of the variation is observed in zircons from older eruptions (62-41 ka). Zircon rims from Ash 17 of the Wilson Creek Formation (59 ka) have elevated Th/U, Eu/Eu*, and Ti and lower Hf compared to Ash 19 (62 ka), which suggests a thermal rejuvenation event between these two eruptions. Zircon rims from Ash 15 (41 ka) are characterized by a trend toward high Hf, at relatively low and relatively constant Ti, and low Eu/Eu*, consistent with rhyolite magma undergoing eutectic-like crystallization just prior to eruption. Zircon surfaces and interiors for the 21, 12.5, and 7 ka dome eruptions have very similar Hf, low Eu/Eu*, low Ti, and low Th/U. This requires zircon crystallization in a very uniform thermal and chemical environment from the latest Pleistocene to Holocene

  8. Geochemistry and Magmagenesis of the Early May 2008 Rhyolitic Magma Erupted by Chaiten Volcano, Southern Andes Volcanic Zone

    NASA Astrophysics Data System (ADS)

    Munoz, J. O.; Basualto, D.; Moreno, H.; Peña, P.; Mella, M.

    2008-12-01

    , located 15 km to the east and to the Upper Pleistocene rhyolite from Yate volcano, approximately 100 km to the north. Geochemical data suggest that Chaiten rhyolites (both old and current eruption) were not produced by fractional crystallization of a basaltic magma derived from an astenospheric or lithospheric mantle source, as could be the case of the nearby Michinmahuida volcano. Also, Chaiten rhyolites appears to be derived from a less mafic source than the rhyolite from Yate volcano (Mella, 2008). Preliminary non-modal dynamic melting models for mafic and intermediate source suggests that 5-10 percent of partial melting of an intermediate source (modal composition including 10 Cpx, 30 Hb, 45 Pl, 4 Bt, 1 Mt) is the best fit model. As indicate by precursory and early eruption volcanotectonic seismicity, this intermediate source could be an amphibolite (facies either acquired during accretion or within the crust) located at 10-15 km depth, in a 30 km thickness crust with relatively high geothermal gradient, as it was previously proposed by Lopez et al. (1993). Crystals may be relict from the magma plumbing system. Lopez, L., Kilian, R., Kempton, P. D.., Tagiti, M. 1993. Rev. Geol.. Chile 22(1):33-55. Mella, M., 2008. Tese de Doutoramento, Universidade de Sao Paulo, 180 p. Brasil. Naranjo, J.A., Stern C., 2004. Rev. Geol. Chile 31(2): 225-240. Stern, C., Navarro, X. and Munoz, J. 2002. Anal. Inst. Patagonia 30: 167-174.

  9. Major, trace element and isotope geochemistry (Sr-Nd-Pb) of interplinian magmas from Mt. Somma-Vesuvius (Southern Italy)

    USGS Publications Warehouse

    Somma, R.; Ayuso, R.A.; de Vivo, B.; Rolandi, G.

    2001-01-01

    compositions in the interplinian rocks show a tendency to become slightly more radiogenic with age, from the Protohistoric (143Nd/144Nd=0.51240-0.51247) to Ancient Historic (143Nd/144Nd=0.51245-0.51251). Medieval interplinian activity (143Nd/144Nd: 0.51250-0.51241) lacks meaningful internal trends. All the interplinian rocks have virtually homogeneous compositions of 207Pb/204Pb and 208Pb/204Pb in acid-leached residues (207Pb/204Pb ???15.633 to 15.687, 208Pb/204Pb ???38.947 to 39.181). Values of 206Pb/204Pb are very distinctive, however, and discriminate among the three interplinian cycles of activity (Protohistoric: 18.929-18.971, Ancient Historic: 19.018-19.088, Medieval: 18.964-19.053). Compositional trends of major, trace element and isotopic compositions clearly demonstrate strong temporal variations of the magma types feeding the Somma-Vesuvius activity. These different trends are unlikely to be related only to low pressure evolutionary processes, and reveal variations of parental melt composition. Geochemical data suggest a three component mixing scheme for the interplinian activity. These involve HIMU-type and DMM-type mantle and Calabrian-type lower crust. Interaction between these components has taken place in the source; however, additional quantitative constraints must be acquired in order to better discriminate between magma characteristics inherited from the sources and those acquired during shallow level evolution.

  10. Late Triassic intrusive complex in the Jidong region, Jiamusi-Khanka Block, NE China: Geochemistry, zircon U-Pb ages, Lu-Hf isotopes, and implications for magma mingling and mixing

    NASA Astrophysics Data System (ADS)

    Yang, Hao; Ge, Wen-chun; Zhao, Guo-chun; Dong, Yu; Xu, Wen-liang; Ji, Zheng; Yu, Jie-jiang

    2015-05-01

    Whole-rock major and trace element geochemistry together with zircon U-Pb ages and Lu-Hf isotope compositions are reported for a Late Triassic intrusive complex in the Jidong region, Jiamusi-Khanka Block, NE China. Zircon U-Pb dating yields ages between 211 and 208 Ma for enclaves of microgranular diorite and quartz diorite, and between 211 and 209 Ma for the host granitoids. These ages correlate with a previously established intensive Late Triassic magmatic event along the eastern Asian margin. Field observations, together with petrographic features, geochemistry, and zircon Hf isotope data, preclude simple crystal fractionation or restite unmixing as a genetic link for the various rock types within the intrusive complex. The syenogranite suite has high SiO2 (75.5-76.3 wt.%) and low MgO (0.15-0.19 wt.%), and yields enriched LILE and LREE patterns. Most of the zircons in the syenogranites have two-stage model ages of 766 and 1461 Ma, together with positive εHf(t) values of + 0.6 to + 9.1. These results indicate that the granitoid magmas were generated by partial melting of Meso- to Neoproterozoic lower crust. The gabbro suite has a restricted range of SiO2 (46.1-51.9 wt.%) together with high Mg# values (49-70) and high concentrations of Ni, Co, and Cr. Zircons from two diorite samples have single-stage Hf model ages of 557-787 Ma and εHf(t) values of + 1.9 to + 8.3 that are consistent with the coeval gabbros previously studied in the Jidong region. These features, together with the observation that all the gabbros are enriched in LREE and LILE, suggest that the mafic magmas were derived from melting of depleted Neoproterozoic lithospheric mantle that had been metasomatized by slab-derived fluids. It is concluded that the dominant igneous suites within the Late Triassic intrusive complex formed by mingling/mixing of felsic and mafic magmas. The geochemical data, combined with regional geological investigations, indicate that the Late Triassic intrusive complex

  11. Petrology and geochemistry of ca. 2100-1000 a.B.P. magmas of Augustine volcano, Alaska, based on analysis of prehistoric pumiceous tephra

    NASA Astrophysics Data System (ADS)

    Tappen, Christine M.; Webster, James D.; Mandeville, Charles W.; Roderick, David

    2009-05-01

    Geochemical and textural features of whole-rock samples, phenocrysts, matrix glasses, and silicate melt inclusions from five prehistoric pumiceous tephra units of Augustine volcano, Alaska, were investigated to interpret processes of magma storage and evolution. The bulk-rock compositions of the tephra (designated G, erupted ca. 2100 a.B.P.; I ca. 1700 a.B.P.; H ca. 1400 a.B.P.; and C1 and C2 ca. 1000 a.B.P.) are silicic andesite; they contain rhyolitic matrix glasses and silicate melt inclusions with 74-79 wt.% SiO 2. The rocks are comprised of microlite-bearing matrix glass and phenocrysts of plagioclase, orthopyroxene, clinopyroxene, magnesio-hornblende, titanomagnetite, and ilmenite ± Al-rich amphibole with minor to trace apatite and rare sulfides and quartz. The felsic melt inclusions in plagioclase, pyroxenes, and amphibole are variably enriched in volatile components and contain 1.6-8.0 wt.% H 2O, 2100-5400 ppm Cl, < 40-1330 ppm CO 2, and 30-390 ppm S. Constraints from Fe-Ti oxides imply that magma evolution occurred at 796 ± 6 °C to 896 ± 8 °C and log ƒ O2 of NNO + 2.2 to + 2.6. This is consistent with conditions recorded for 1976, 1986, and 2006 eruptive materials and implies that magmatic and eruptive processes have varied little during the past 2100 years. Prehistoric Augustine magmas represented by these silicic andesites evolved via fractional crystallization, magma mingling and mixing, and/or chemical contamination due to magma-volcanic rock interaction. The occurrence of fractional crystallization is supported by the abundance of normally zoned phenocrysts, the presence of felsic matrix glass and melt inclusions within andesitic rock samples, trace-element data, and by geochemical modeling. The modeling constrains the influence of crystal fractionation on melt differentiation and is consistent with the evolution of the melt phase from felsic andesite to rhyodacite compositions. Magma mixing, mingling, and/or contamination by magma-volcanic rock

  12. Petrology and geochemistry of the ultrapotassic rocks from the Sabatini Volcanic District, central Italy: the role of evolutionary processes in the genesis of variably enriched alkaline magmas

    NASA Astrophysics Data System (ADS)

    Conticelli, Sandro; Francalanci, Lorella; Manetti, Piero; Cioni, Raffaello; Sbrana, Alessandro

    1997-01-01

    The Sabatini Volcanic District (SVD) is a large volcanic field characterised by the lack of any major volcanic center. Its activity, spread over a wide area, started at 0.6 Ma and developed through five main phases, during which several calderas and the Bracciano lake volcano-tectonic depression were formed. All the volcanic rocks belong to the Roman-type ultrapotassic series (HKS), ranging from leucite tephrites to leucite and haüyne phonolites. Although the major- and compatible-element contents indicate a single series of evolution, there are differences in the incompatible trace-element abundances. A high-Ba series (HBaS) has been distinguished from a low-Ba series (LBaS), with the former also enriched in all other incompatible elements (e.g., REE, Nb, Zr, Th) except Rb. The HBaS rocks are plagioclase-free, leucite-bearing lavas and were abundantly outpoured from the Bracciano volcanoes during the third and fifth phase of activity. Plagioclase- and phlogopite-bearing rocks constitute the LBaS and were erupted during the other phases generally from smaller and eccentric volcanic centers. The initial 87Sr/ 86Sr values are higher in the HBaS rocks and do not vary significantly with magma evolution (0.71047-0.71080), but cover a wider range in the LBaS rocks (0.70944-0.71038), with the lowest Sr isotope ratios occurring in the least evolved lavas. The higher Ca content in the olivine and Ti and Al IV in the clinopyroxene, and the lower ulvöspinel content of the Ti-magnetites of the HBaS rocks suggest an evolution at lower pressure and higher temperature for this magma. The observed petrologic characteristics suggest that the HBaS magma evolved at lower depths by processes of refilling, tapping, fractionation and probably assimilation (RTFA), where the crystallisation rate of clinopyroxene+leucite±olivine dominates over the input rate of the fresh magma. The LBaS magma evolved at slightly higher pressure, in separate and small magma bodies, by fractional

  13. From a long-lived upper-crustal magma chamber to rapid porphyry copper emplacement: Reading the geochemistry of zircon crystals at Bajo de la Alumbrera (NW Argentina)

    NASA Astrophysics Data System (ADS)

    Buret, Yannick; von Quadt, Albrecht; Heinrich, Christoph; Selby, David; Wälle, Markus; Peytcheva, Irena

    2016-09-01

    The formation of world class porphyry copper deposits reflect magmatic processes that take place in a deeper and much larger underlying magmatic system, which provides the source of porphyry magmas, as well as metal and sulphur-charged mineralising fluids. Reading the geochemical record of this large magmatic source region, as well as constraining the time-scales for creating a much smaller porphyry copper deposit, are critical in order to fully understand and quantify the processes that lead to metal concentration within these valuable mineral deposits. This study focuses on the Bajo de la Alumbrera porphyry copper deposit in Northwest Argentina. The deposit is centred on a dacitic porphyry intrusive stock that was mineralised by several pulses of porphyry magma emplacement and hydrothermal fluid injections. To constrain the duration of ore formation, we dated zircons from four porphyry intrusions, including pre-, syn- and post-mineralisation porphyries based on intersection relations between successive intrusion and vein generations, using high precision CA-ID-TIMS. Based on the youngest assemblages of zircon grains, which overlap within analytical error, all four intrusions were emplaced within 29 ka, which places an upper limit on the total duration of hydrothermal mineralisation. Re/Os dating of hydrothermal molybdenite fully overlaps with this high-precision age bracket. However, all four porphyries contain zircon antecrysts which record protracted zircon crystallisation during the ∼200 ka preceding the emplacement of the porphyries. Zircon trace element variations, Ti-in-zircon temperatures, and Hf isotopic compositions indicate that the four porphyry magmas record a common geochemical and thermal history, and that the four intrusions were derived from the same upper-crustal magma chamber. Trace element zoning within single zircon crystals confirms a fractional crystallisation trend dominated by titanite and apatite crystallisation. However, zircon

  14. How mantle heterogeneity can affect geochemistry of magmas and their styles of emplacement: a fascinating tale revealed by Etna alkaline lavas

    NASA Astrophysics Data System (ADS)

    Viccaro, Marco; Zuccarello, Francesco

    2016-04-01

    Geochemical investigations of Mt. Etna magmas have led to notable findings on the nature of compositional heterogeneity of the mantle source beneath the volcano. Some of the observed features explain the short-term geochemical variability of volcanic rocks erupted at Mt. Etna in recent times, which are characterized by increase of LILE, 87Sr/86Sr and decrease of 143Nd/144Nd, 206Pb/204Pb,176Hf/177Hf. This compositional behavior has not attributed exclusively to differentiation processes such as fractional crystallization, crustal assimilation and effects of volatile flushing. In this study, based on some geochemical similarities of the Etnean and Hyblean alkaline magmas, we have modeled partial melting of a composite source constituted by two rock types, inferred by various observations performed on some Hyblean xenoliths, namely: a spinel lherzolite bearing phlogopite-amphibole and a garnet pyroxenite in form of veins intruded into lherzolite that is interpreted as metasomatic high-temperature fluids (silicate melts) crystallized at mantle conditions. Partial melting modeling has been applied to each rock type and the resulting primary liquids have been then mixed in various proportions. The concentrations of major and trace elements along with the water obtained from the modeling are remarkably comparable with those of Etnean melts re-equilibrated at primary conditions. Different proportions of spinel lherzolite bearing metasomatic phases and garnet pyroxenite can account for the signature of a large spectrum of Etnean alkaline magmas and for their geochemical variability through time. Our study implies that magmas characterized by variable compositions and volatile contents directly inherited from the source can undergo distinct histories of ascent and evolution in the plumbing system at crustal levels, potentially leading to a wide range of eruptive styles. A rather shallow source inferred from the model also excludes the presence of deep mantle structures

  15. Paleozoic metasomatism at the origin of Mediterranean ultrapotassic magmas: Constraints from time-dependent geochemistry of Colli Albani volcanic products (Central Italy)

    NASA Astrophysics Data System (ADS)

    Gaeta, Mario; Freda, Carmela; Marra, Fabrizio; Arienzo, Ilenia; Gozzi, Fernando; Jicha, Brian; Di Rocco, Tommaso

    2016-02-01

    The major processes that control the genesis of potassic volcanic rocks, like the timing of multi-stage mantle metasomatism, remain largely unclear. In an attempt to clarify the timing of the metasomatic process, a detailed geochronologic and geochemical study has been conducted on the ultrapotassic rocks of the Colli Albani Volcanic District (Central Italy). New 40Ar/39Ar data coupled with literature and newly performed 87Sr/86Sr, 143Nd/144Nd and chemical data allow us to precisely delineate the time-dependent geochemical variations of the magmas erupted at the Colli Albani Volcanic District and to better define mantle source processes responsible for their genesis. The temporal geochemical variations observed in the Colli Albani magmas indicate that: i) the ultrapotassic magmas originated from a metasomatized mantle source in which phlogopite is the potassium-bearing phase; ii) the partial melting of the mantle source involved mainly phlogopite and clinopyroxene (± olivine), whereas the role of accessory phases was less significant; and iii) the metasomatic process that led to the formation of the phlogopite in the mantle can be reasonably related to events that have occurred during the Paleozoic Era.

  16. Formation and emplacement of two contrasting late-Mesoproterozoic magma types in the central Namaqua Metamorphic Complex (South Africa, Namibia): Evidence from geochemistry and geochronology

    NASA Astrophysics Data System (ADS)

    Bial, Julia; Büttner, Steffen H.; Frei, Dirk

    2015-05-01

    The Namaqua Metamorphic Complex is a Mesoproterozoic low-pressure, granulite facies belt along the southern and western margin of the Kaapvaal Craton. The NMC has formed between ~ 1.3 and 1.0 Ga and its central part consists essentially of different types of granitoids intercalated with metapelites and calc-silicate rocks. The granitoids can be subdivided into three major groups: (i) mesocratic granitoids, (ii) leucocratic granitoids and (iii) leucogranites. The high-K, ferroan mesocratic granitoids (54-75 wt% SiO2) have a variable composition ranging from granitic to tonalitic, and contain biotite and/or hornblende or orthopyroxene. They are strongly enriched in REE and LILE, indicating A-type chemical characteristics, and are depleted in Ba, Sr, Eu, Nb, Ta and Ti. The leucocratic granitoids and leucogranites (68-76 wt% SiO2) differ from the other group in having a granitic or slightly syenitic composition containing biotite and/or garnet/sillimanite. They have lower REE and MgO, FeOt, CaO, TiO2, MnO concentrations, but higher Na2O and K2O contents. Compositional variations in mesocratic granitoids indicate their formation by fractional crystallization of a mafic parental magma. Leucocratic granitoids and leucogranites lack such trends, which suggests melting of a felsic crustal source without subsequent further evolution of the generated magmas. The mineralogical and geochemical characteristics of the mesocratic granitoids are consistent magmatic differentiation of a mantle derived, hot (> 900 °C) parental magma. The leucocratic granitoids and leucogranites granites were formed from low-temperature magmas (< 730 °C), generated during fluid-present melting from metasedimentary sources. New U-Pb zircon ages reveal that both magma types were emplaced into the lower crust within a 30-40 million years interval between 1220-1180 Ma. In this time period the crust reached its thermal peak, which led to the formation of the leucocratic granitoids and leucogranites. A

  17. A review of the geochronology and geochemistry of Late Yanshanian (Cretaceous) plutons along the Fujian coastal area of southeastern China: Implications for magma evolution related to slab break-off and rollback in the Cretaceous

    NASA Astrophysics Data System (ADS)

    Li, Zhen; Qiu, Jian-Sheng; Yang, Xue-Mei

    2014-01-01

    The Cretaceous plutonic suites in the Fujian coastal area include abundant I-type and A-type granitoids and lesser gabbroids. They are important components of the Late Yanshanian magmatic belt along the southeastern coast of China, and define a linear NNE-SSW-trending belt of magmatism. Geochronological, geochemical and geological data from thirty intrusions are summarised in this paper, and the data provide distinct magmatic, geochemical and tectonic patterns in the area. A compilation of geochronological data for these intrusive rocks indicates emplacement mainly from around 125 to 90 Ma, with a major peak from 115 to 90 Ma, and a subordinate peak from 125 to 115 Ma. Besides their temporal and spatial coexistence, all these intrusive rocks have similar geochemical patterns which point to involvement of components from a depleted asthenospheric mantle source for the parental magmas, most probably by magma mixing. The first appearance of sparse I-type granitoids with post-collisional extensional granite affinities, and the emplacement of the Baijuhuajian and Suzhou A-type granites, mark the beginning of extension during the Early Cretaceous at ca. 125 to 119 Ma. The subsequent development of bimodal magmatism at 115 to 90 Ma, with numerous arc-related mafic gabbros and I-type granites, together with some A-type granites, suggests that this major igneous event took place as a response to back-arc extension. On the basis of petrology, geochronology, tectonics, and elemental and isotopic geochemistry, we speculate that break-off and rollback of the subducting Palaeo-Pacific Plate during the Cretaceous were responsible for the Late Yanshanian regional tectono-magmatic evolution in the area. We suggest that this process facilitated a strong and rapid linear upwelling of the asthenospheric mantle beneath the coastal area of southeastern China, with consequential extension of the overlying continental lithosphere, and ultimately the large-scale Late Yanshanian magmatism

  18. Geochemistry and tectonic significance of amphibolites of the Ducktown mining district, Tennessee

    SciTech Connect

    Lawson, J.S.; Misra, K.C.

    1985-01-01

    The Ducktown massive sulfide deposits have several characteristics of volcanogenic-exhalative deposits but occur in an overwhelmingly sedimentary environment. Recent isotopic studies have suggested a magmatic component to ore formation. This study is an evaluation of the geochemistry and tectonic significance of late Proterozoic amphibolite units spatially associated with the ore bodies. The amphibolites are interpreted to be igneous in origin based on Niggli trends, relict igneous textures, and bulk chemistry. The protolith was an olivine tholeiite, as judged from normative composition, the AFM diagram, and Y/Nb ratios. Discrimminant diagrams using immobile trace elements (Ti-Y-Zr, TiO/sub 2/-Zr, Zr/Y-Zr, Ti-Cr, Ti-V) indicate an affinity with mid-ocean ridge basalts, an interpretation in agreement with that suggested for amphibolites associated with the very similar Gossan Lead deposits (Virginia) in Ocoee-equivalent metasediments (Gair and Slack, 1984), but apparently inconsistent with the ensialic setting of the Ducktown deposits. However, tholeiitic magmas associated with continental breakup may show chemical affinities with MORB, despite their intrusion into continental crust. The Ducktown amphibolites are interpreted to be diabasic sills emplaced during deposition of Ocoee sediments and related to intracratonic rifting along the eastern margin of Laurentia during the incipient development of the Iapetus Ocean.

  19. Effect of Mantle Wedge Hybridization by Sediment Melt on Geochemistry of Arc Magma and Arc Mantle Source - Insights from Laboratory Experiments at High Pressures and Temperatures

    NASA Astrophysics Data System (ADS)

    Mallik, A.; Dasgupta, R.; Tsuno, K.; Nelson, J. M.

    2015-12-01

    Generation of arc magmas involves metasomatism of the mantle wedge by slab-derived H2O-rich fluids and/or melts and subsequent melting of the modified source. The chemistry of arc magmas and the residual mantle wedge are not only regulated by the chemistry of the slab input, but also by the phase relations of metasomatism or hybridization process in the wedge. The sediment-derived silica-rich fluids and hydrous partial melts create orthopyroxene-rich zones in the mantle wedge, due to reaction of mantle olivine with silica in the fluid/melt [1,2]. Geochemical evidence for such a reaction comes from pyroxenitic lithologies coexisting with peridotite in supra-subduction zones. In this study, we have simulated the partial melting of a parcel of mantle wedge modified by bulk addition of sediment-derived melt with variable H2O contents to investigate the major and trace element chemistry of the magmas and the residues formed by this process. Experiments at 2-3 GPa and 1150-1300 °C were conducted on mixtures of 25% sediment-derived melt and 75% lherzolite, with bulk H2O contents varying from 2 to 6 wt.%. Partial reactive crystallization of the rhyolitic slab-derived melt and partial melting of the mixed source produced a range of melt compositions from ultra-K basanites to basaltic andesites, in equilibrium with an orthopyroxene ± phlogopite ± clinopyroxene ± garnet bearing residue, depending on P and bulk H2O content. Model calculations using partition coefficients (from literature) of trace elements between experimental minerals and silicate melt suggest that the geochemical signatures of the slab-derived melt, such as low Ce/Pb and depletion in Nb and Ta (characteristic slab signatures) are not erased from the resulting melt owing to reactive crystallization. The residual mineral assemblage is also found to be similar to the supra-subduction zone lithologies, such as those found in Dabie Shan (China) and Sanbagawa Belt (Japan). In this presentation, we will also

  20. Thermochemical convection in and beneath intracratonic basins: Onset and effects

    NASA Astrophysics Data System (ADS)

    Schoofs, Stan; Trompert, Ron A.; Hansen, Ulrich

    2000-11-01

    Observations of episodic subsidence and high organic maturity in the intracratonic Michigan basin cannot be explained by simple conductive models. Moreover, the sylvinite deposits within the basin indicate an evaporite evolution other than a simple evapoconcentration of standard seawater. By means of numerical simulations we have investigated whether these deviations can be attributed to periods of free thermochemical convection (TCC) of aqueous fluids within a fractured igneous rift body underlying the sediments. Since crustal rocks are known to be heterogeneous and anisotropic, we have first investigated the onset of TCC in an idealized domain, for temperature and salinity linearly increasing with depth. The sensitivity study considers several heterogeneous permeability fields, by varying the stochastic correlation lengths of the medium and by introducing anisotropy on the subgrid scale. Due to destabilization of the fluid in pockets of relatively high porosity, the onset of convection in the heterogeneous media occurs at ratios of chemical to thermal buoyancy 1 order higher than in homogeneous media. Next we have studied the thermal, chemical, and subsidence effects of the convective flow in and beneath the Michigan basin, for the situations before and after closure from the open sea. TCC explains the elevated level of organic maturity in the sediments and up to a quarter of the observed fast subsidence rates. Finally, we argue that basement involvement could have changed the seawater composition, and so leads to the direct deposition of sylvinite.

  1. Adiabat_1ph 3.0 and the MAGMA website: educational and research tools for studying the petrology and geochemistry of plate margins

    NASA Astrophysics Data System (ADS)

    Antoshechkina, P. M.; Asimow, P. D.

    2010-12-01

    features to be incorporated into adiabat_1ph after its release was the ability to simulate flux melting, in which a metasomatic fluid or melt, of fixed composition, was added to the system before each equilibration step. This idea was further developed in the coupled dynamic and petrological subduction zone model GyPSM, so that fluid flux into the wedge was controlled by the location of dehydration reactions in the slab. The adiabat_1ph release candidate includes a similar option so that the user may specify assimilated compositions, which evolve as the calculation proceeds. This added flexibility opens up a number of possibilities, such as more realistic simulations of melt-rock reactions at mid-ocean ridges. Adiabat_1ph files may be downloaded from the MAGMA website at http://magmasource.caltech.edu/ and feedback is welcomed at a dedicated forum, especially ideas for new software features. MAGMA is an online resource for the study of mantle melting and magma evolution, hosted by Caltech. As well as MELTS-related resources, there are tools for visualization of binary and ternary phase diagrams. Flash movies of phase diagrams for adiabatic decompression melting of peridotite and pyroxenite sources can be played in a web browser or downloaded from a server.

  2. Evaluation of the ongoing rifting and subduction processes in the geochemistry of magmas from the western part of the Mexican Volcanic Belt

    NASA Astrophysics Data System (ADS)

    Verma, Surendra P.; Pandarinath, Kailasa; Rivera-Gómez, M. Abdelaly

    2016-03-01

    A compilation of new and published geochemical data for 1512 samples of volcanic rocks from the western part of the Mexican Volcanic Belt was first subdivided according to the age group (136 samples of Miocene and 1376 samples of Pliocene-Holocene). Rocks of the younger group were then subdivided as Rift (1014 samples from the triple-rift system) and No Rift (362 samples outside of the triple-rift system) or Near Trench (937 samples) and Far Trench (439 samples) magmas. These subdivisions were considered separately as basic, intermediate, and acid magmatic rocks. The application of the conventional and multidimensional techniques confirmed the great tectonic and geochemical complexity of this region. The presence of oceanic-type basalts suggested to result from a mantle plume was not confirmed from the tectonomagmatic multidimensional diagrams. The Miocene rocks, which are present at the surface far from the Middle-America Trench, showed a likely continental rift setting in most diagrams for basic rocks and a continental arc setting for intermediate rocks. These differences can be explained in terms of the petrogenetic origin of the magmas. Unlike the current thinking, the triple-rift system seems to have influenced the chemistry of Pliocene-Holocene basic rocks, which indicated a continental rift setting. The Pliocene-Holocene intermediate and acid rocks, however, did not show such an influence. The Pliocene-Holocene basic rocks indicated a continental rift setting, irrespective of the Near Trench and Far Trench subdivision because numerous Near Trench rocks also lie in the triple-rift and graben systems. However, the intermediate rocks having a crustal component in their genesis indicated a continental arc (Near Trench) or a transitional arc to within-plate setting (Far Trench). The acid rocks having a crustal component also suggested a continental arc (Near Trench) or a transitional setting (Far Trench). The application of the tectonomagmatic multidimensional

  3. Trace- and rare-earth-element geochemistry of the June 1993 natrocarbonatite lavas, Oldoinyo Lengai (Tanzania): Implications for the origin of carbonatite magmas

    NASA Astrophysics Data System (ADS)

    Simonetti, Antonio; Bell, Keith; Shrady, Catherine

    1997-01-01

    Major-, trace- and rare-earth-element data from ten natrocarbonatite lavas collected during the June 1993 extrusive activity define two distinct groups. Although both groups are characterized by low Nb and Zr contents, and low Th/U (~1.0); Ba/Sr>1.0; (La/Sm) N>40; high Ba, Mo, Sr, W contents; and LREE contents ~1000 to 2000×chondrite, one group has much higher Al 2O 3, Fe 2O 3, Nb, Pb, SiO 2, Zr and total REEs contents. These differences are attributed to the presence of silicate spheroids in natrocarbonatites that form within the latter group. Similarity in trace- and rare-earth-element-normalized patterns for both groups of natrocarbonatite lavas suggest either a common source or generation from a common parental melt. Models proposed for the origin of natrocarbonatites include immiscible separation from a peralkaline, silicate magma, or late-stage fractionation from a parent olivine sövite magma. Although natrocarbonatite melt formation may be controlled by either of these differentiation processes, certain trace-element ratios for the 1993 lavas, such as Ce/Pb (~9), and Th/Nb (~0.1) are similar to those estimated for primitive mantle, and their Sm/Nd ratios (~0.07) are quite different to the average value of 0.15 for most carbonatites world-wide. The similarity in element ratios in many of the older silicate lavas at Oldoinyo Lengai (e.g., Zr/Nb, La/Nb, Ba/Nb, Rb/Nb, and Ba/La) to those estimated for HIMU and EM I suggest that source characteristics can be reflected in such melts. Even if the natrocarbonatites are formed by liquid immiscibility, recent experiments have shown that partition coefficients for trace elements (e.g., Ba, Ce, Mo, Nb, Pb, Th, U) between conjugate carbonate and silicate melts approach unity with increasing temperature. Alternatively, the similarity in trace-element ratios between those for the silicate lavas from Oldoinyo Lengai and mantle components are simply fortuitous.

  4. Magma Fragmentation

    NASA Astrophysics Data System (ADS)

    Gonnermann, Helge M.

    2015-05-01

    Magma fragmentation is the breakup of a continuous volume of molten rock into discrete pieces, called pyroclasts. Because magma contains bubbles of compressible magmatic volatiles, decompression of low-viscosity magma leads to rapid expansion. The magma is torn into fragments, as it is stretched into hydrodynamically unstable sheets and filaments. If the magma is highly viscous, resistance to bubble growth will instead lead to excess gas pressure and the magma will deform viscoelastically by fracturing like a glassy solid, resulting in the formation of a violently expanding gas-pyroclast mixture. In either case, fragmentation represents the conversion of potential energy into the surface energy of the newly created fragments and the kinetic energy of the expanding gas-pyroclast mixture. If magma comes into contact with external water, the conversion of thermal energy will vaporize water and quench magma at the melt-water interface, thus creating dynamic stresses that cause fragmentation and the release of kinetic energy. Lastly, shear deformation of highly viscous magma may cause brittle fractures and release seismic energy.

  5. Lithosphere structure beneath the Phanerozoic intracratonic basins of North America

    NASA Astrophysics Data System (ADS)

    Kaminski, Edouard; Jaupart, Claude

    2000-05-01

    Four intracratonic basins of North America, the Hudson Bay, Michigan, Illinois and Williston basins, have similar ages and are close to one another. Yet, they exhibit different subsidence histories characterised by different time-scales and sediment thicknesses. They can be explained by local lithosphere thinning and by the cooling of the induced thermal anomaly. Within the framework of 1D thermal models for vertical heat transport, each basin requires a different lithosphere thickness or a different boundary condition at the base of the lithosphere. Heat flow and seismic studies show that, beneath the North American craton, the lithosphere is too thick for the assumption of purely vertical heat transfer to be valid. Thermal models are developed to account for finite thermal anomaly width and for two types of basal boundary conditions, fixed temperature or fixed heat flux. Different subsidence histories are explained by deep lithospheric anomalies of different sizes. The stability of thick continental roots requires the mantle part of the lithosphere to be compositionally buoyant with respect to 'normal' convecting mantle. Localised lithospheric thinning, due for example to plume penetration, results in the emplacement of compositionally denser mantle into the lithosphere. This represents a load which drives permanent flexure. The cooling time and the characteristics of flexure allow constraints on the dimensions of these deep lithospheric anomalies. There are no solutions for lithosphere thicknesses less than 170 km. The Williston and Illinois basins are associated with wide (˜200 km) and thin anomalies (˜100 km), whereas the Michigan and Hudson Bay are located on top of narrow (˜100 km) and tall (˜200 km) anomalies.

  6. Magma energy

    SciTech Connect

    Hardee, H.C.

    1985-01-01

    The paper briefly describes the potential magma resources in the US and worldwide, and possible ways of exploiting this resource. Two target sites for field experiments to characterize magma targets are identified: Long Valley Caldera and Coso Hot Springs. 11 refs. (ACR)

  7. Geochemistry of quaternary volcanism in the Sunda-Banda arc, Indonesia, and three-component genesis of island-arc basaltic magmas

    NASA Astrophysics Data System (ADS)

    Wheller, G. E.; Varne, R.; Foden, J. D.; Abbott, M. J.

    1987-06-01

    Volcanic rocks of the Sunda and Banda arcs range from tholeiitic through calcalkaline and shoshonitic to leucititic, the widest compositional span of mafic magmatism known from an active arc setting. Mafic rocks in our data set, which includes 315 new analyses of volcanic rocks from twelve Quaternary volcanoes, including Batu Tara in the previously geochemically unknown Flores-Lembata arc sector, are generally similar to those from other island arcs: most contain <1.3 wt. % TiO 2 and 16-22 wt. % Al 2O 3, and have characteristically high K/Nb and La/Nb values. Abundances of P, Ba, Rb, Sr, La, Ce, Nd, Zr and Nb increase sympathetically with increasing K 2O contents of mafic rocks but those of Na, Ti, Y and Sc vary little throughout the geochemical continuum from low-K tholeiitic to high-K leucititic rocks. Excluding Sumatra and Wetar, which possess mainly dacitic and rhyolitic volcanics, the Sunda-Banda arc is divisible into four geochemical arc sectors with boundaries that correlate with major changes in regional tectonic setting and geological history. From west to east, the West Java, Bali and Flores arc sectors each comprise volcanoes which become progressively more K-rich eastwards, culminating in the leucitite volcanoes Muriah, Soromundi and Sangenges, and Batu Tara, respectively. In the most easterly Banda sector, the volcanics vary from high- to low-K eastwards around the arc. Correlations between geochemistry and 87Sr/ 86Sr values show separate trends for each of the four arc sectors, believed to be the result of involvement of at least three geochemically and isotopically distinct components in the source regions of the arc magmatism. A dominant source component with a low K content and a low 87Sr/ 86Sr value, and common to all sectors, is probably peridotitic mantle. A second component, with low K content but high 87Sr/ 86Sr value, appears to be crustal material. This component is most apparent in the Banda sector, in keeping with that sector's tectonic

  8. The Surtsey Magma Series

    PubMed Central

    Ian Schipper, C.; Jakobsson, Sveinn P.; White, James D.L.; Michael Palin, J.; Bush-Marcinowski, Tim

    2015-01-01

    The volcanic island of Surtsey (Vestmannaeyjar, Iceland) is the product of a 3.5-year-long eruption that began in November 1963. Observations of magma-water interaction during pyroclastic episodes made Surtsey the type example of shallow-to-emergent phreatomagmatic eruptions. Here, in part to mark the 50th anniversary of this canonical eruption, we present previously unpublished major-element whole-rock compositions, and new major and trace-element compositions of sideromelane glasses in tephra collected by observers and retrieved from the 1979 drill core. Compositions became progressively more primitive as the eruption progressed, with abrupt changes corresponding to shifts between the eruption’s four edifices. Trace-element ratios indicate that the chemical variation is best explained by mixing of different proportions of depleted ridge-like basalt, with ponded, enriched alkalic basalt similar to that of Iceland’s Eastern Volcanic Zone; however, the systematic offset of Surtsey compositions to lower Nb/Zr than other Vestmannaeyjar lavas indicates that these mixing end members are as-yet poorly contained by compositions in the literature. As the southwestern-most volcano in the Vestmannaeyjar, the geochemistry of the Surtsey Magma Series exemplifies processes occurring within ephemeral magma bodies on the extreme leading edge of a propagating off-axis rift in the vicinity of the Iceland plume. PMID:26112644

  9. The Surtsey Magma Series

    NASA Astrophysics Data System (ADS)

    Ian Schipper, C.; Jakobsson, Sveinn P.; White, James D. L.; Michael Palin, J.; Bush-Marcinowski, Tim

    2015-06-01

    The volcanic island of Surtsey (Vestmannaeyjar, Iceland) is the product of a 3.5-year-long eruption that began in November 1963. Observations of magma-water interaction during pyroclastic episodes made Surtsey the type example of shallow-to-emergent phreatomagmatic eruptions. Here, in part to mark the 50th anniversary of this canonical eruption, we present previously unpublished major-element whole-rock compositions, and new major and trace-element compositions of sideromelane glasses in tephra collected by observers and retrieved from the 1979 drill core. Compositions became progressively more primitive as the eruption progressed, with abrupt changes corresponding to shifts between the eruption’s four edifices. Trace-element ratios indicate that the chemical variation is best explained by mixing of different proportions of depleted ridge-like basalt, with ponded, enriched alkalic basalt similar to that of Iceland’s Eastern Volcanic Zone; however, the systematic offset of Surtsey compositions to lower Nb/Zr than other Vestmannaeyjar lavas indicates that these mixing end members are as-yet poorly contained by compositions in the literature. As the southwestern-most volcano in the Vestmannaeyjar, the geochemistry of the Surtsey Magma Series exemplifies processes occurring within ephemeral magma bodies on the extreme leading edge of a propagating off-axis rift in the vicinity of the Iceland plume.

  10. The Surtsey Magma Series.

    PubMed

    Schipper, C Ian; Jakobsson, Sveinn P; White, James D L; Michael Palin, J; Bush-Marcinowski, Tim

    2015-06-26

    The volcanic island of Surtsey (Vestmannaeyjar, Iceland) is the product of a 3.5-year-long eruption that began in November 1963. Observations of magma-water interaction during pyroclastic episodes made Surtsey the type example of shallow-to-emergent phreatomagmatic eruptions. Here, in part to mark the 50(th) anniversary of this canonical eruption, we present previously unpublished major-element whole-rock compositions, and new major and trace-element compositions of sideromelane glasses in tephra collected by observers and retrieved from the 1979 drill core. Compositions became progressively more primitive as the eruption progressed, with abrupt changes corresponding to shifts between the eruption's four edifices. Trace-element ratios indicate that the chemical variation is best explained by mixing of different proportions of depleted ridge-like basalt, with ponded, enriched alkalic basalt similar to that of Iceland's Eastern Volcanic Zone; however, the systematic offset of Surtsey compositions to lower Nb/Zr than other Vestmannaeyjar lavas indicates that these mixing end members are as-yet poorly contained by compositions in the literature. As the southwestern-most volcano in the Vestmannaeyjar, the geochemistry of the Surtsey Magma Series exemplifies processes occurring within ephemeral magma bodies on the extreme leading edge of a propagating off-axis rift in the vicinity of the Iceland plume.

  11. The Surtsey Magma Series.

    PubMed

    Schipper, C Ian; Jakobsson, Sveinn P; White, James D L; Michael Palin, J; Bush-Marcinowski, Tim

    2015-01-01

    The volcanic island of Surtsey (Vestmannaeyjar, Iceland) is the product of a 3.5-year-long eruption that began in November 1963. Observations of magma-water interaction during pyroclastic episodes made Surtsey the type example of shallow-to-emergent phreatomagmatic eruptions. Here, in part to mark the 50(th) anniversary of this canonical eruption, we present previously unpublished major-element whole-rock compositions, and new major and trace-element compositions of sideromelane glasses in tephra collected by observers and retrieved from the 1979 drill core. Compositions became progressively more primitive as the eruption progressed, with abrupt changes corresponding to shifts between the eruption's four edifices. Trace-element ratios indicate that the chemical variation is best explained by mixing of different proportions of depleted ridge-like basalt, with ponded, enriched alkalic basalt similar to that of Iceland's Eastern Volcanic Zone; however, the systematic offset of Surtsey compositions to lower Nb/Zr than other Vestmannaeyjar lavas indicates that these mixing end members are as-yet poorly contained by compositions in the literature. As the southwestern-most volcano in the Vestmannaeyjar, the geochemistry of the Surtsey Magma Series exemplifies processes occurring within ephemeral magma bodies on the extreme leading edge of a propagating off-axis rift in the vicinity of the Iceland plume. PMID:26112644

  12. Imaging three-dimensional crustal conductivity structures reflecting continental flood basalt effects hidden beneath thick intracratonic sedimentary basin

    NASA Astrophysics Data System (ADS)

    Padilha, Antonio L.; Vitorello, Ícaro; Antunes, Cassio E.; Pádua, Marcelo B.

    2015-07-01

    A large-scale array of long-period magnetic data and a deep-probing magnetotelluric profile were recorded in the intracratonic Paraná sedimentary basin in central eastern South America, which presents a thick and extensive sedimentary-magmatic sequence that allows its basement to be investigated only by indirect methods. Integration of the results from both methods showed that the crust beneath the basin presents several quasi-linear highly conductive channeled zones with limited lateral extent, in coincidence with some of the main tectonic structures recognized at the surface, and a moderate but pervasive lithosphere conductivity enhancement beneath its central part. Upward movement of CO2-bearing volatiles and magmas precipitating highly conducting mineral phases along discrete subvertical fault zones that served as feeder conduits for Early Cretaceous voluminous continental flood basalts was a likely process responsible for the localized conductivity enhancements. Correlation between some of the linear conductive zones and elongated magnetic anomalies and between the maximum depth occurrence of most of these conductive anomalies and the Curie depth at which crustal rocks lose their magnetism gives strong support to interconnected iron oxides (especially magnetite) and iron sulfides (such as pyrrhotite) as the main conductive sources. The moderate bulk conductivity increase in the crust and upper mantle beneath the central part of the basin is unexpected for a postulated cratonic basement and is tentatively associated with impregnation of the lithosphere by conducting minerals related either to widespread tectonic events in the Ordovician or Late Precambrian or to dispersed magmatic residues of an Early Cretaceous magma differentiation contaminating the entire lithosphere.

  13. Geochemistry and petrogenesis of Mesoproterozoic A-type granitoids from the Danish island of Bornholm, southern Fennoscandia

    NASA Astrophysics Data System (ADS)

    Johansson, Åke; Waight, Tod; Andersen, Tom; Simonsen, Siri L.

    2016-02-01

    Granitoids and gneisses from the Danish island of Bornholm have been investigated using whole rock geochemistry, Sr and Nd isotope geochemistry and Hf isotopes in zircon. Recent U-Pb dating shows that the rocks were formed during a short time interval at 1.45 to 1.46 Ga, penecontemporaneous with ongoing deformation. The strong similarity in geochemical signatures indicate that they all belong to a single igneous suite composed of alkali-calcic biotite-hornblende quartz monzonites to more evolved biotite granites, albeit with an apparent gap in SiO2 content at around 70 wt%, dividing the suite into an intermediate and a felsic part. These dominantly metaluminous rocks are strongly ferroan and potassic, and with highly elevated concentrations of many trace elements, traits that are typical for A-type granitoids. The presence of magnetite and titanite indicates relatively oxidized compositions, and Nb/Y ratios designate them to the A2 subtype. Initial whole rock εNd values range between + 1 and - 2 (with one outlier at + 4), and initial zircon εHf values between + 3 and - 4. These values may be explained by melting of relatively juvenile crust similar to that forming the Transscandinavian Igneous Belt alone, but the spread in Hf and Nd isotope compositions to values overlapping with the Svecofennian mantle at 1.45 Ga suggests involvement of a mantle-derived component. This indicates the magmatism was associated with juvenile crustal growth. There are no systematic differences in isotope or trace element characteristics between the orthogneisses and the less deformed granitoids, suggesting similar origins for both rock types, and no systematic changes in isotopic composition with SiO2 concentration. Trace element compositions indicate a within-plate setting, similar to other 1.45 Ga granites in southwest Fennoscandia, in spite of the close relation between magmatism and deformation on Bornholm. We therefore suggest intracratonic A-type magmatism within an active

  14. The structure and sedimentary sequence of intracratonic rift from Late Sinian to Early Cambrian in the Sichuan Basin, South China

    NASA Astrophysics Data System (ADS)

    Gu, Zhidong; Zhang, Baomin; Lu, Weihu; Zhai, Xiufen; Jiang, Hua

    2016-04-01

    Sichuan Basin is located in the northwest of Upper Yangtze craton of South China, and there is developed an intracratonic rift from Late Sinian to Early Cambrian in the middle of Sichuan Basin, and the paper systematically discusses the structure and sedimentary sequence of the intracratonic rift based on the fields, drilling and seismic data, and so on. Detailed structural interpretation of 2D and 3D seismic profiles displays the development of two stages of intracratonic rift due to regional extension with the depth of 2000m, and plane distribution of intracratonic rift presents the V-pattern from the northwest to the southeast in the middle of Sichuan Basin with the width from 100km to 20km. The drilling data from the intracratonic rift shows the obvious thinning of Upper Sinian and thickening of Lower Cambrian. And field outcrops situated in the intracratonic rift reveal that the Upper Sinian is mainly composed of siliceous rock, shale and carbonate, with the thickness of less than 100m, but the thickness of Upper Sinian on the platform reaches 1000m by contrast; They also reveals that Lower Cambrian is mainly composed of shale, mudstone, and siltstone with the development of gravity current, and the thickness of Lower Cambrian reaches 2000m. The formation of intracratonic rift may be initiated by pre-existing basement weakness zone and deep mantle dynamics.

  15. Geochemistry of anorthositic differentiated sills in the Archean (~ 2970 Ma) Fiskenæsset Complex, SW Greenland: Implications for parental magma compositions, geodynamic setting, and secular heat flow in arcs

    NASA Astrophysics Data System (ADS)

    Polat, Ali; Fryer, Brian J.; Appel, Peter W. U.; Kalvig, Per; Kerrich, Robert; Dilek, Yildirim; Yang, Zhaoping

    2011-04-01

    The Fiskenæsset Complex, SW Greenland, is one of the best preserved layered Archean intrusions in the world, consisting of an association of ca. 550-meter-thick anorthosite, leucogabbro, gabbro, and ultramafic rocks (dunite, peridotite, pyroxenite, and hornblendite). Despite poly-phase deformation and amphibolite to granulite facies metamorphism, primary cumulate textures and igneous layering are well-preserved in the complex. This study reports new major and trace element data for three variably thick (1 to 5 m) differentiated (dunite, through peridotite, pyroxenite, gabbro leucogabbro, to anorthosite) sequences (Sequences 1, 2 and 3) in the Sinarssuk area of the Fiskenæsset region. On several variation diagrams, samples from these sequences plot along a well-defined liquid line of descent, consistent with in situ fractional crystallization. The average chemical compositions of these sequences are used to constrain their approximate parental magma compositions. Petrographic observations and geochemical data suggest that Sequences 2 and 3 solidified from evolved magmas that underwent olivine fractionation prior to their intrusion. In contrast, Sequence 1 appears to have been derived from a near-primary parental magma (SiO 2 = 43 wt.%, MgO = 20 wt.%, Al 2O 3 = 16 wt.%, CaO = 9.3 wt.%, Ni = 840 ppm, Mg-number = 80). The trace element patterns of this parental magma are comparable to those of Phanerozoic boninites, consistent with a supra-subduction zone geodynamic setting. If the relative thickness of ultramafic layers, the sum of dunite, peridotite and pyroxenite layers, in differentiated sequences is taken as an analog for the original complex emplaced into Archean oceanic crust, the Fiskenæsset Complex might have had a minimum thickness of 1000 m, with a 500 m thick ultramafic unit at the bottom. The thickness of the ultramafic unit in the preserved complex is less than 50 m, suggesting that more than 90% of the original ultramafic unit was either delaminated

  16. Exploration Geochemistry.

    ERIC Educational Resources Information Center

    Closs, L. Graham

    1983-01-01

    Contributions in mineral-deposit model formulation, geochemical exploration in glaciated and arid environments, analytical and sampling problems, and bibliographic research were made in symposia held and proceedings volumes published during 1982. Highlights of these symposia and proceedings and comments on trends in exploration geochemistry are…

  17. Zircon geochronology and geochemistry to constrain the youngest eruption events and magma evolution of the Mid-Miocene ignimbrite flare-up in the Pannonian Basin, eastern central Europe

    NASA Astrophysics Data System (ADS)

    Lukács, Réka; Harangi, Szabolcs; Bachmann, Olivier; Guillong, Marcel; Danišík, Martin; Buret, Yannick; von Quadt, Albrecht; Dunkl, István; Fodor, László; Sliwinski, Jakub; Soós, Ildikó; Szepesi, János

    2015-12-01

    A silicic ignimbrite flare-up episode occurred in the Pannonian Basin during the Miocene, coeval with the syn-extensional period in the region. It produced important correlation horizons in the regional stratigraphy; however, they lacked precise and accurate geochronology. Here, we used U-Pb (LA-ICP-MS and ID-TIMS) and (U-Th)/He dating of zircons to determine the eruption ages of the youngest stage of this volcanic activity and constrain the longevity of the magma storage in crustal reservoirs. Reliability of the U-Pb data is supported by (U-Th)/He zircon dating and magnetostratigraphic constraints. We distinguish four eruptive phases from 15.9 ± 0.3 to 14.1 ± 0.3 Ma, each of which possibly includes multiple eruptive events. Among these, at least two large volume eruptions (>10 km3) occurred at 14.8 ± 0.3 Ma (Demjén ignimbrite) and 14.1 ± 0.3 Ma (Harsány ignimbrite). The in situ U-Pb zircon dating shows wide age ranges (up to 700 kyr) in most of the crystal-poor pyroclastic units, containing few to no xenocrysts, which implies efficient recycling of antecrysts. We propose that long-lived silicic magma reservoirs, mostly kept as high-crystallinity mushes, have existed in the Pannonian Basin during the 16-14 Ma period. Small but significant differences in zircon, bulk rock and glass shard composition among units suggest the presence of spatially separated reservoirs, sometimes existing contemporaneously. Our results also better constrain the time frame of the main tectonic events that occurred in the Northern Pannonian Basin: We refined the upper temporal boundary (15 Ma) of the youngest counterclockwise block rotation and the beginning of a new deformation phase, which structurally characterized the onset of the youngest volcanic and sedimentary phase.

  18. Magma volumes and storage in the middle crust

    NASA Astrophysics Data System (ADS)

    Memeti, V.; Barnes, C. G.; Paterson, S. R.

    2015-12-01

    Quantifying magma volumes in magma plumbing systems is mostly done through geophysical means or based on volcanic eruptions. Detailed studies of plutons, however, are useful in revealing depths and evolving volumes of stored magmas over variable lifetimes of magma systems. Knowledge of the location, volume, and longevity of stored magma is critical for understanding where in the crust magmas attain their chemical signature, how these systems physically behave and how source, storage levels, and volcanoes are connected. Detailed field mapping, combined with single mineral geochemistry and geochronology of plutons, allow estimates of size and longevity of melt-interconnected magma batches that existed during the construction of magma storage sites. The Tuolumne intrusive complex (TIC) recorded a 10 myr magmatic history. Detailed maps of the major units in different parts of the TIC indicate overall smaller scale (cm- to <1 km) compositional variation in the oldest, outer Kuna Crest unit and mainly larger scale (>10 km) changes in the younger Half Dome and Cathedral Peak units. Mineral-scale trace element data from hornblende of granodiorites to gabbros from the Kuna Crest lobe show distinct hornblende compositions and zoning patterns. Mixed hornblende populations occur only at the transition to the main TIC. This compositional heterogeneity in the first 1-2 myr points to low volume magmatism resulting in smaller, discrete and not chemically interacting magma bodies. Trace element and Sr- and Pb-isotope data from growth zones of K-feldspar phenocrysts from the two younger granodiorites indicate complex mineral zoning, but general isotopic overlap, suggesting in-situ, inter-unit mixing and fractionation. This is supported by hybrid zones between units, mixing of zircon, hornblende, and K-feldspar populations and late leucogranites. Thus, magma body sizes increased later resulting in overall more homogeneous, but complexly mixing magma mushes that fractionated locally.

  19. Geochemistry for Chemists.

    ERIC Educational Resources Information Center

    Hostettler, John D.

    1985-01-01

    A geochemistry course for chemists is described. Includes: (1) general course information; (2) subject matter covered; and (3) a consideration of the uses of geochemistry in a chemistry curriculum, including geochemical "real world" examples, geochemistry in general chemistry, and geochemistry as an elective. (JN)

  20. Magma Energy Extraction

    SciTech Connect

    Dunn, J.C.; Ortega, A.; Hickox, C.E.; Chu, T.Y.; Wemple, R.P.; Boehm, R.F.

    1987-01-20

    The rate at which energy can be extracted from crustal magma bodies has an important influence on the economic viability of the magma energy concept. Open heat exchanger systems where fluid is circulated through solidified magma offer the promise of high energy extraction rates. This concept was successfully demonstrated during experiments in the molten zone of Kilauea Iki lava lake. Ongoing research is directed at developing a fundamental understanding of the establishment and long term operation of open systems in a crustal magma body. These studies show that magma solidifying around a cooled borehole will be extensively fractured and form a permeable medium through which fluid can be circulated. Numerical modeling of the complete magma energy extraction process predicts that high quality thermal energy can be delivered to the wellhead at rates that will produce from 25 to 30 MW electric. 10 figs., 10 refs.

  1. Characterization and architecture of fluvial sand bodies in a intracratonic alluvial fan

    SciTech Connect

    Martinius, A.W.; Cuevas Gozalo, M.C. )

    1993-09-01

    The fluvial deposits of the Tortola alluvial fan of late Oligocene to early Miocene were deposited in the intracratonic Loranca Basin (Spain). the fluvial facies comprise individual and amalgamated sand bodies embedded in flood-plain fines. The succession is a labyrinth-type reservoir analog. A distal and proximal fan locality have been compared. The sand bodies were characterized and quantified by means of three-dimensional (3-D) morphology and facies analysis, sandbody size statistics, permeability and gamma-ray log profiles, and geometry of permeability baffles. A classification of the sand bodies in six genetic types was established: meander-loop, low-sinuosity channel-fill, braided channel-fill, deltaic, interchannel bar, and crevasse-splay deposits. This classification is conditioned by a set og geological rules. The external geometry, internal organization, and spatial arrangement of the genetic types is determined by variation in hydrodynamic conditions, sediment supply, fan morphology, and basin subsidence. Significant differences in reservoir quality exist between the genetic types, and between the two fan localities. Analysis of the sequential development of the two localities shows that the 3-D architecture is the result of coalescing fan depositional systems: a minor fluvial fan systems from the eastern basin margin, and local minor fluvial systems. Shifting of the channels on the fan surface due to avulsion processes, differential basin subsidence, and tectonic movements influenced fan formation and hence reservoir quality.

  2. Seismic reflection structure of intracratonic palmyride fold-thrust belt and surrounding Arabian platform, Syria

    SciTech Connect

    McBride, J.H.; Barazangi, M.; Best, J. ); Al-Saad, D.; Sawaf, T.; Al-Otri, M.; Gebran, A. )

    1990-03-01

    Seismic reflection and drill-hole data from central Syria provide a detailed view of the subsurface structure (10-15 km depth) of the relatively little-studied intracratonic Palmyride fold and thrust belt. The data set, together with surface geologic mapping, constrains a structural/stratigraphic section spanning the northeast sector of the belt and the surrounding subprovinces of the Arabian platform. The seismic reflection and drill-hole data show Mesozoic stratigraphic sequences thickening abruptly into the Palmyrides from the adjacent, arched Paleozoic platforms Neogene (alpine) folding and thrusting of the Mesozoic basin, as documented on the seismic data, are sharply restricted to the narrow width of the belt ({approximately}100 km), in contrast to the relatively undeformed Phanerozoic strata of the platforms to the north and south. The seismic and drill-hole data support the hypothesis that the palmyrides began as a Permian-Triassic failed rift connected to the Levantine passive continental margin, which was inverted and complexly deformed by the interfering effects of Cenozoic movements along the Dead Sea transform fault system and the Turkish Bitlis convergent zone. The seismic data provide a first view into the extent and depth of the early basin formation and subsequent compressional deformation, and as such represent a necessary element for constraining reconstructions of northern Middle East plate motions. 20 figs.

  3. Anatomy of an intracratonic fold belt: Examples from the southwestern Palmyride fold belt in central Syria

    SciTech Connect

    Chaimov, T.A.; Barazangi, M.; Best, J.A. ); Al-Saad, D.; Sawaf, T.; Gebran, A. )

    1991-03-01

    The Palmyride fold belt, a 400 {times} 100 km, NE-trending, transpressive belt in central Syria, represents the late Mesozoic and Cenozoic inversion of a linear intracratonic basin. The southwestern Palmyrides are characterized by short wavelength (2-5 km) folds separated by small intermontane basins. To elucidate the subsurface structure, a three-dimensional model, based mainly on about 450 km of two-dimensional seismic reflection data, was generated using a LandMark{reg sign} graphics workstation. The new model includes many features not identified in outcrop. Short, NW-trending transcurrent, or transfer, faults link the short, en echelon NE-trending thrust faults and blind thrusts of the Palmyrides. Varying structural styles are observed within the southwestern part of the belt. In one instance the structure of Mesozoic and Cenozoic rocks mimics that in deeper Paleozoic rocks; elsewhere, a strong discordance between Paleozoic and Mesozoic rocks appears to be related to the development of a regional detachment in Triassic rocks at about 4 km depth. Shortening the southwestern palmyrides totals about 20-25 km, based on palinspastic restoration of a balanced cross section across the belt. Seismic stratigraphy constrains the timing of at least three distinct episodes of Palmyride shortening: Late Cretaceous, middle Eocene, and Miocene to present. All three episodes were penecontemporaneous with specific tectonic events along the northern Arabian plate boundaries.

  4. Intra-cratonic melting as a result of delamination of mantle lithosphere - insight from numerical modelling

    NASA Astrophysics Data System (ADS)

    Gorczyk, W.; Vogt, K.; Gerya, T.; Hobbs, B. E.

    2012-12-01

    It is becoming increasingly apparent that intense deformation, metamorphism and metasomatism occur within continental cratonic blocks far removed form subducting margins Such changes may occur intra-cratonically arising from lithospheric thickening and the development of gravitational instabilities, but mostly occur at the boundary of cratonic blocks. The contact of two cratons is characterized by rheological lateral variations within mantle-lithosphere and overlying crust. Tectonic stresses acting on craton/craton boundaries may lead to thinning or thickening due to delamination of the mantle lithosphere. This is reflected in tectonic deformation, topography evolution, melting and crustal metamorphism. To understand the controls on these processes a number of 2D, coupled petrological thermo-mechanical numerical experiments has been performed to test the response of a laterally weakened zone to a compressional regime. The results indicate that the presence of water-bearing minerals in the lithosphere and lower crust is essential to initiate melting, which in the later stages may expand to dry melting of crust and mantle. In the case of anhydrous crust and lithosphere, no melting occurs. Thus a variety of instabilities, melting behaviour and topographic responses occurs at the base of the lithosphere as well as intensive faulting and buckling in the crust dependent on the strength and "water" content of the lithosphere.

  5. Architecture and subsidence history of the intracratonic Hudson Bay Basin, northern Canada

    NASA Astrophysics Data System (ADS)

    Pinet, Nicolas; Lavoie, Denis; Dietrich, Jim; Hu, Kezhen; Keating, Pierre

    2013-10-01

    The Phanerozoic Hudson Bay Basin is a large intracratonic basin that is almost completely encircled by Precambrian rocks of the Canadian Shield. The preserved sedimentary succession is up to 2500 m thick and consists mainly of Upper Ordovician to Upper Devonian limestones, dolostones, evaporites and minor siliciclastics that were deposited in shallow marine conditions. Backstripping, based on new paleontological data and well correlations, reveals an irregular subsidence history marked by several periods of exhumation. In seismic data, the Hudson Bay Basin appears to have a relatively simple geometry, characterized by a lower sedimentary package cut by high-angle faults, overlain by a saucer-shape, essentially underformed upper sedimentary package. Normal (or transtensional) faults imaged on seismic reflection profiles provide clear evidence for crustal extension during deposition of the older sedimentary packages or slightly later, indicating that the basin is, at least partly, extensional in nature. However, significant changes in the depocenter location during the Paleozoic and variable exhumation values required by new maturation data indicate that other mechanisms influenced the subsidence/exhumation history of the basin. In particular, the influence of far-field events and dynamic topography transmitted by large-scale mantle flow in the continental interior (creating long-wavelength tilting and unconformities) is suspected but not yet proven.

  6. The Relationship Between Lithospheric Thickness and Tectonic Subsidence in Mildly- Extended Intra-Cratonic Basins

    NASA Astrophysics Data System (ADS)

    Crosby, A.; White, N.; Fishwick, S.

    2008-12-01

    In extensional sedimentary basins, the duration of post-rift subsidence depends on the thermal time constant and hence on the thickness of the lithosphere. It is well known that this thickness varies by at least a factor of two over the continents, and that many intra-cratonic basins have continued to accumulate accommodation space for longer than expected given a standard thickness of 125 km. In this study, we make use of recent advances in mapping the thickness of the lithosphere using surface wave tomography, and a global database of backstripped well-logs, to assess the applicability of the classic pure shear model to the stretching and subsidence of regions where the lithosphere is unusually thick. We start by using the known density structure of oceanic lithosphere, and independent seismic observations of crustal structure and lithosphere thickness, to isostatically quantify the average density depletion of the mantle. We find our observations are consistent with geochemical constraints. Using backstripped wells from basins where there has been only one obvious period of extension, and an adapted stretching model which incorporates temperature and composition-dependent thermal diffusivity and expansivity and the advection of depleted mantle, we then invert observations of tectonic subsidence for both thinning factors and lithospheric thickness, and compare our results with seismic observations at the present day. The subsidence of some basins, such as the Michigan Basin, is consistent with the thicker lithospheric template predicted using seismology. In other cases, such as the West Siberian Basin, the lithospheric thickness estimated from seismic tomography and subsidence analysis disagree. We also find strong local gradients in apparent lithospheric thickness, such as between the Michigan and Illinois Basins. The Congo Basin in central Africa can be explained fairly well by simple extension of locally thick lithosphere. However, the pronounced negative

  7. Evidence for crustal recycling during the Archean: The parental magmas of the stillwater complex

    NASA Technical Reports Server (NTRS)

    Mccallum, I. S.

    1988-01-01

    The petrology and geochemistry of the Stillwater Complex, an Archean (2.7 Ga) layered mafic intrusion in the Beartooth Mountains of Montana is discussed. Efforts to reconstruct the compositions of possible parental magmas and thereby place some constraints on the composition and history of their mantle source regions was studied. A high-Mg andesite or boninite magma best matches the crystallization sequences and mineral compositions of Stillwater cumulates, and represents either a primary magma composition or a secondary magma formed, for example, by assimilation of crustal material by a very Mg-rich melt such as komatiite. Isotopic data do not support the extensive amounts of assimilation required by the komatiite parent hypothesis, and it is argued that the Stillwater magma was generated from a mantle source that had been enriched by recycling and homogenization of older crustal material over a large area.

  8. Structural styles of the intracratonic reactivation of the Perimbó fault zone, Paraná basin, Brazil

    NASA Astrophysics Data System (ADS)

    Rostirolla, Sidnei Pires; Mancini, Fernando; Rigoti, Augustinho; Kraft, Ronaldo Paulo

    2003-08-01

    The style and origin of intracratonic deformation along the Perimbó fault zone (PFZ) in the Paraná basin, Santa Catarina State, southern Brazil, is defined by the integration of outcrop, borehole, aerial photography, and digital terrain modeling data. Typical structures are high-angle strike-slip and oblique-slip normal faults in the Permian sedimentary cover that propagate upward from medium-angle reverse faults in the underlying Precambrian basement. Regional and minor structures suggest blind transtensional faulting and tilting of the overlying strata controlled by the basement heritage. A hypothesis linking deformation between the cover and the basement is proposed on the basis of a structural analysis of a branched fault pattern striking N40-50E and N70-80E. Semi-detailed scale mapping shows that the PFZ has a complex history of polyphase reactivation and is characterized as a plate margin fault in the Proterozoic, evolving to an intracratonic fault in the Phanerozoic, with a main period of reactivation in Permian or Permian-Triassic transition times. The reported data imply that fault reactivation is characterized by normal to left-lateral strike-slip faulting produced by strain propagation from the La Ventana orogenic belt toward the continental interior.

  9. Watching magma from space

    USGS Publications Warehouse

    Lu, Zhong; Wicks, Charles W.; Dzurisin, Daniel; Thatcher, Wayne R.; Freymueller, Jeffrey T.; McNutt, Stephen R.; Mann, Dorte

    2000-01-01

    Westdahl is a broad shield volcano at the western end of Unimak Island in the Aleutian chain. It has apparently been dormant since a 1991-92 eruption and seismicity levels have been low. However, satellite radar imaging shows that in the years following 1992 the upper flanks of Westdahl have risen several centimeters, probably from the influx of new magma deep below its summit. Until now, deep magma reservoirs have been difficult to detect beneath most volcanoes. But using space geodetic technologies, specifically interferometric synthetic aperture radar (InSAR), we have discovered a deep magmatic source beneath Westdahl. 

  10. Self Sealing Magmas

    NASA Astrophysics Data System (ADS)

    von Aulock, Felix W.; Wadsworth, Fabian B.; Kennedy, Ben M.; Lavallee, Yan

    2015-04-01

    During ascent of magma, pressure decreases and bubbles form. If the volume increases more rapidly than the relaxation timescale, the magma fragments catastrophically. If a permeable network forms, the magma degasses non-violently. This process is generally assumed to be unidirectional, however, recent studies have shown how shear and compaction can drive self sealing. Here, we additionally constrain skin formation during degassing and sintering. We heated natural samples of obsidian in a dry atmosphere and monitored foaming and impermeable skin formation. We suggest a model for skin formation that is controlled by diffusional loss of water and bubble collapse at free surfaces. We heated synthetic glass beads in a hydrous atmosphere to measure the timescale of viscous sintering. The beads sinter at drastically shorter timescales as water vapour rehydrates an otherwise degassed melt, reducing viscosity and glass transition temperatures. Both processes can produce dense inhomogeneities within the timescales of magma ascent and effectively disturb permeabilities and form barriers, particularly at the margins of the conduit, where strain localisation takes place. Localised ash in failure zones (i.e. Tuffisite) then becomes associated with water vapour fluxes and alow rapid rehydration and sintering. When measuring permeabilities in laboratory and field, and when discussing shallow degassing in volcanoes, local barriers for degassing should be taken into account. Highlighting the processes that lead to the formation of such dense skins and sintered infills of cavities can help understanding the bulk permeabilities of volcanic systems.

  11. Magma energy for power generation

    SciTech Connect

    Dunn, J.C.

    1987-01-01

    Thermal energy contained in crustal magma bodies represents a large potential resource for the US and magma generated power could become a viable alternative in the future. Engineering feasibility of the magma energy concept is being investigated as part of the Department of Energy's Geothermal Program. This current project follows a seven-year Magma Energy Research Project where scientific feasibility of the concept was concluded.

  12. Magma energy: a feasible alternative

    SciTech Connect

    Colp, J.L.

    1980-03-01

    A short review of the work performed by Sandia Laboratories in connection with its Magma Energy Research Project is provided. Results to date suggest that boreholes will remain stable down to magma depths and engineering materials can survive the downhole environments. Energy extraction rates are encouraging. Geophysical sensing systems and interpretation methods require improvement, however, to clearly define a buried magma source.

  13. Zircon reveals protracted magma storage and recycling beneath Mount St. Helens

    USGS Publications Warehouse

    Claiborne, L.L.; Miller, C.F.; Flanagan, D.M.; Clynne, M.A.; Wooden, J.L.

    2010-01-01

    Current data and models for Mount St. Helens volcano (Washington, United States) suggest relatively rapid transport from magma genesis to eruption, with no evidence for protracted storage or recycling of magmas. However, we show here that complex zircon age populations extending back hundreds of thousands of years from eruption age indicate that magmas regularly stall in the crust, cool and crystallize beneath the volcano, and are then rejuvenated and incorporated by hotter, young magmas on their way to the surface. Estimated dissolution times suggest that entrained zircon generally resided in rejuvenating magmas for no more than about a century. Zircon elemental compositions reflect the increasing influence of mafic input into the system through time, recording growth from hotter, less evolved magmas tens of thousands of years prior to the appearance of mafic magmas at the surface, or changes in whole-rock geochemistry and petrology, and providing a new, time-correlated record of this evolution independent of the eruption history. Zircon data thus reveal the history of the hidden, long-lived intrusive portion of the Mount St. Helens system, where melt and crystals are stored for as long as hundreds of thousands of years and interact with fresh influxes of magmas that traverse the intrusive reservoir before erupting. ?? 2010 Geological Society of America.

  14. Mush Column Magma Chambers

    NASA Astrophysics Data System (ADS)

    Marsh, B. D.

    2002-12-01

    Magma chambers are a necessary concept in understanding the chemical and physical evolution of magma. The concept may well be similar to a transfer function in circuit or time series analysis. It does what needs to be done to transform source magma into eruptible magma. In gravity and geodetic interpretations the causative body is (usually of necessity) geometrically simple and of limited vertical extent; it is clearly difficult to `see' through the uppermost manifestation of the concentrated magma. The presence of plutons in the upper crust has reinforced the view that magma chambers are large pots of magma, but as in the physical representation of a transfer function, actual magma chambers are clearly distinct from virtual magma chambers. Two key features to understanding magmatic systems are that they are vertically integrated over large distances (e.g., 30-100 km), and that all local magmatic processes are controlled by solidification fronts. Heat transfer considerations show that any viable volcanic system must be supported by a vertically extensive plumbing system. Field and geophysical studies point to a common theme of an interconnected stack of sill-like structures extending to great depth. This is a magmatic Mush Column. The large-scale (10s of km) structure resembles the vertical structure inferred at large volcanic centers like Hawaii (e.g., Ryan et al.), and the fine scale (10s to 100s of m) structure is exemplified by ophiolites and deeply eroded sill complexes like the Ferrar dolerites of the McMurdo Dry Valleys, Antarctica. The local length scales of the sill reservoirs and interconnecting conduits produce a rich spectrum of crystallization environments with distinct solidification time scales. Extensive horizontal and vertical mushy walls provide conditions conducive to specific processes of differentiation from solidification front instability to sidewall porous flow and wall rock slumping. The size, strength, and time series of eruptive behavior

  15. Comparative Magma Oceanography

    NASA Technical Reports Server (NTRS)

    Jones, John H.

    1999-01-01

    The question of whether the Earth ever passed through a magma ocean stop is of considerable interest. Geochemical evidence strongly suggests that the Moon had a magma ocean and the evidence is mounting that the same was true for Mars. Analyses of mar (SNC) meteorites have yielded insights into the differentiation history of Mars, and consequently, it is interesting to compare that planet to the Earth. Three primary features of An contrast strongly to those of the Earth: (1) the extremely ancient ages of the martian core, mantle, and crust (approx. 4.55 b.y.); (2) the highly depleted nature of the martian mantle; and (3) the extreme ranges of Nd isotopic compositions that arise within the crust and depleted mantle.

  16. Calderas and magma reservoirs

    NASA Astrophysics Data System (ADS)

    Cashman, Katharine; Giordano, Guido

    2015-04-01

    Large caldera-forming eruptions have long been a focus of both petrological and volcanological studies; traditionally, both have assumed that eruptible magma is stored within a single long-lived melt body. Over the past decade, however, advances in analytical techniques have provided new views of magma storage regions, many of which provide evidence of multiple melt lenses feeding a single eruption, and/or rapid pre-eruptive assembly of large volumes of melt. These new petrological views of magmatic systems have not yet been fully integrated into volcanological perspectives of caldera-forming eruptions. We discuss the implications of syn-eruptive melt extraction from complex, rather than simple, reservoirs and its potential control over eruption size and style, and caldera collapse timing and style. Implications extend to monitoring of volcanic unrest and eruption progress under conditions where successive melt lenses may be tapped. We conclude that emerging views of complex magma reservoir configurations provide exciting opportunities for re-examining volcanological concepts of caldera-forming systems

  17. Lunar magma transport phenomena

    NASA Technical Reports Server (NTRS)

    Spera, Frank J.

    1992-01-01

    An outline of magma transport theory relevant to the evolution of a possible Lunar Magma Ocean and the origin and transport history of the later phase of mare basaltic volcanism is presented. A simple model is proposed to evaluate the extent of fractionation as magma traverses the cold lunar lithosphere. If Apollo green glasses are primitive and have not undergone significant fractionation en route to the surface, then mean ascent rates of 10 m/s and cracks of widths greater than 40 m are indicated. Lunar tephra and vesiculated basalts suggest that a volatile component plays a role in eruption dynamics. The predominant vapor species appear to be CO CO2, and COS. Near the lunar surface, the vapor fraction expands enormously and vapor internal energy is converted to mixture kinetic energy with the concomitant high-speed ejection of vapor and pyroclasts to form lunary fire fountain deposits such as the Apollo 17 orange and black glasses and Apollo 15 green glass.

  18. Modelling the petrogenesis of high Rb/Sr silicic magmas

    USGS Publications Warehouse

    Halliday, A.N.; Davidson, J.P.; Hildreth, W.; Holden, P.

    1991-01-01

    Rhyolites can be highly evolved with Sr contents as low as 0.1 ppm and Rb Sr > 2,000. In contrast, granite batholiths are commonly comprised of rocks with Rb Sr 100. Mass-balance modelling of source compositions, differentiation and contamination using the trace-element geochemistry of granites are therefore commonly in error because of the failure to account for evolved differentiates that may have been erupted from the system. Rhyolitic magmas with very low Sr concentrations (???1 ppm) cannot be explained by any partial melting models involving typical crustal source compositions. The only plausible mechanism for the production of such rhyolites is Rayleigh fractional crystallization involving substantial volumes of cumulates. A variety of methods for modelling the differentiation of magmas with extremely high Rb/Sr is discussed. In each case it is concluded that the bulk partition coefficients for Sr have to be large. In the simplest models, the bulk DSr of the most evolved types is modelled as > 50. Evidence from phenocryst/glass/whole-rock concentrations supports high Sr partition coefficients in feldspars from high silica rhyolites. However, the low modal abundance of plagioclase commonly observed in such rocks is difficult to reconcile with such simple fractionation models of the observed trace-element trends. In certain cases, this may be because the apparent trace-element trend defined by the suite of cognetic rhyolites is the product of different batches of magma with separate differentiation histories accumulating in the magma chamber roof zone. ?? 1991.

  19. Comparative Magma Oceanography

    NASA Technical Reports Server (NTRS)

    Jones, J. H.

    1999-01-01

    The question of whether the Earth ever passed through a magma ocean stage is of considerable interest. Geochemical evidence strongly suggests that the Moon had a magma ocean and the evidence is mounting that the same was true for Mars. Analyses of martian (SNC) meteorites have yielded insights into the differentiation history of Mars, and consequently, it is interesting to compare that planet to the Earth. Three primary features of Mars contrast strongly to those of the Earth: (i) the extremely ancient ages of the martian core, mantle, and crust (about 4.55 b.y.); (ii) the highly depleted nature of the martian mantle; and (iii) the extreme ranges of Nd isotopic compositions that arise within the crust and depleted mantle. The easiest way to explain the ages and diverse isotopic compositions of martian basalts is to postulate that Mars had an early magma ocean. Cumulates of this magma ocean were later remelted to form the SNC meteorite suite and some of these melts assimilated crustal materials enriched in incompatible elements. The REE pattern of the crust assimilated by these SNC magmas was LREE enriched. If this pattern is typical of the crust as a whole, the martian crust is probably similar in composition to melts generated by small degrees of partial melting (about 5%) of a primitive source. Higher degrees of partial melting would cause the crustal LREE pattern to be essentially flat. In the context of a magma ocean model, where large degrees of partial melting presumably prevailed, the crust would have to be dominated by late-stage, LREE-enriched residual liquids. Regardless of the exact physical setting, Nd and W isotopic evidence indicates that martian geochemical reservoirs must have formed early and that they have not been efficiently remixed since. The important point is that in both the Moon and Mars we see evidence of a magma ocean phase and that we recognize it as such. Several lines of theoretical inference point to an early Earth that was also hot

  20. Magma energy: engineering feasibility of energy extraction from magma bodies

    SciTech Connect

    Traeger, R.K.

    1983-12-01

    A research program was carried out from 1975 to 1982 to evaluate the scientific feasibility of extracting energy from magma, i.e., to determine if there were any fundamental scientific roadblocks to tapping molten magma bodies at depth. The next stage of the program is to evaluate the engineering feasibility of extracting energy from magma bodies and to provide insight into system economics. This report summarizes the plans, schedules and estimated costs for the engineering feasibility study. Tentative tasks and schedules are presented for discussion and critique. A bibliography of past publications on magma energy is appended for further reference. 69 references.

  1. Stability of rift axis magma reservoirs: Spatial and temporal evolution of magma supply in the Dabbahu rift segment (Afar, Ethiopia) over the past 30 kyr

    NASA Astrophysics Data System (ADS)

    Medynski, S.; Pik, R.; Burnard, P.; Vye-Brown, C.; France, L.; Schimmelpfennig, I.; Whaler, K.; Johnson, N.; Benedetti, L.; Ayelew, D.; Yirgu, G.

    2015-01-01

    Unravelling the volcanic history of the Dabbahu/Manda Hararo rift segment in the Afar depression (Ethiopia) using a combination of cosmogenic (36Cl and 3He) surface exposure dating of basaltic lava-flows, field observations, geological mapping and geochemistry, we show in this paper that magmatic activity in this rift segment alternates between two distinct magma chambers. Recent activity in the Dabbahu rift (notably the 2005-2010 dyking crises) has been fed by a seismically well-identified magma reservoir within the rift axis, and we show here that this magma body has been active over the last 30 kyr. However, in addition to this axial magma reservoir, we highlight in this paper the importance of a second, distinct magma reservoir, located 15 km west of the current axis, which has been the principal focus of magma accumulation from 15 ka to the subrecent. Magma supply to the axial reservoir substantially decreased between 20 ka and the present day, while the flank reservoir appears to have been regularly supplied with magma since 15 ka ago, resulting in less variably differentiated lavas. The trace element characteristics of magmas from both reservoirs were generated by variable degrees of partial melting of a single homogeneous mantle source, but their respective magmas evolved separately in distinct crustal plumbing systems. Magmatism in the Dabbahu/Manda Hararo rift segment is not focussed within the current axial depression but instead is spread out over at least 15 km on the western flank. This is consistent with magneto-telluric observations which show that two magma bodies are present below the segment, with the main accumulation of magma currently located below the western flank, precisely where the most voluminous recent (<15 ka) flank volcanism is observed at the surface. Applying these observations to slow spreading mid-ocean ridges indicates that magma bodies likely have a lifetime of a least 20 ka, and that the continuity of magmatic activity is

  2. Determining the Magma Genesis of Mo Porphyry Deposits

    NASA Astrophysics Data System (ADS)

    Gaynor, S.; Coleman, D. S.; Rosera, J.

    2015-12-01

    The high flux of magma associated with super eruptions is hypothesized to rebuild the deep crust, altering the source(s) of subsequent magmatism. Climax-type Mo deposits are commonly generated immediately after eruption of large ignimbrites within a volcanic field, and provide an opportunity to understand the evolution of magma sources following high flux events. The Questa caldera of the Latir volcanic field, NM exposes a 10 Ma long record of pre-, syn- and post-ignimbrite intrusive and extrusive rocks, and hosts the Questa Climax-type Mo deposit. New detailed geochronology and geochemistry from Questa (including extensive sampling of subsurface rocks in the mine) permit detailed reconstruction of the temporal evolution of magma sources through the waxing and waning stages of super eruption magmatism. Comparison of chemical and isotopic data waxing, ignimbrite, Mo-mineralizing and waning stage magmas reveals several patterns. Waxing and waning magmas (waxing: 29-25.7 Ma; waning: 24.5-19 Ma) have intermediate trace elements and radiogenic isotopes relative to other magmatism (87Sr/86Sri=0.7050 to 0.7070, ɛNd=-5.2 to -7.2). Ignimbrite magmatism (25.5 Ma) is depleted in incompatible elements, enriched in MREE and HREE's and has more evolved radiogenic isotopes (87Sr/86Sri=0.7095, ɛNd=-8.0). Molybdenum mineralizing magmas (24.9-24.5 Ma), are enriched in incompatible elements, depleted in MREE and HREE's and have distinct radiogenic isotopes (87Sr/86Sri=0.7055 to 0.7075, ɛNd=-4.2 to -5.7). We suggest the lower crustal source of magmas changed during ignimbrite generation, and as a result, subsequent mineralizing magmas incorporated more juvenile, mafic components. This mantle influence is the metallogenesis for Climax-type deposits and indicates that deep crustal hybridization, rather than upper crustal differentiation, is pivotal in their generation. These results indicate that a lower crustal source of magmatism for a volcanic field is altered due to super

  3. Intracratonic basins : subtle records of long wavelength deformations and eustasy - the case example of the Paris Basin

    NASA Astrophysics Data System (ADS)

    Robin, Cecile; Guillocheau, Francois

    2014-05-01

    Subtle vertical movements, major constraints for lithospheric and mantle dynamics models, are difficult to quantify and to date. In sedimentary basins, this quantification is based on subsidence measurements by backstripping. The error bars on this technique can be high, mainly in the low subsiding domains were dates, water depths and eustasy are important data. We developed a 3D high-resolution method of accommodation space measurement at the scale of intracratonic basins, with a precise quantification of the water depth. Based on this 3D quantification of the accommodation, it was possible to discriminate the deformation and the eustatic controls based on the principle that the basin-scale signal contain the eustasy and the local control is of tectonic origin. (1) The application of this technique to the Paris Basin questioned the importance of the long term subsidence signal versus major deformation events of at least European-scale (Mid and Neo-Cimmerian, Austrian, Senonian deformations..) that control, in the Paris Basin, major subsidence centers reorganization. (2) The stratigraphic record of the Paris Basin, with those excellent datings (inheritance of 2 centuries of biostratigraphy), is also a unique place for constraining eustasy, its timing (with now a good knowledge of the sea water temperatures since the Jurassic) and the order of magnitude of the sea level variations. Back, those sea level amplitude constraints can be inputs for a better quantification of the vertical movements.

  4. Structural styles of Paleozoic intracratonic fault reactivation: A case study of the Grays Point fault zone in southeastern Missouri, USA

    USGS Publications Warehouse

    Clendenin, C.W.; Diehl, S.F.

    1999-01-01

    A pronounced, subparallel set of northeast-striking faults occurs in southeastern Missouri, but little is known about these faults because of poor exposure. The Commerce fault system is the southernmost exposed fault system in this set and has an ancestry related to Reelfoot rift extension. Recent published work indicates that this fault system has a long history of reactivation. The northeast-striking Grays Point fault zone is a segment of the Commerce fault system and is well exposed along the southeast rim of an inactive quarry. Our mapping shows that the Grays Point fault zone also has a complex history of polyphase reactivation, involving three periods of Paleozoic reactivation that occurred in Late Ordovician, Devonian, and post-Mississippian. Each period is characterized by divergent, right-lateral oblique-slip faulting. Petrographic examination of sidwall rip-out clasts in calcite-filled faults associated with the Grays Point fault zone supports a minimum of three periods of right-lateral oblique-slip. The reported observations imply that a genetic link exists between intracratonic fault reactivation and strain produced by Paleozoic orogenies affecting the eastern margin of Laurentia (North America). Interpretation of this link indicate that right-lateral oblique-slip has occurred on all of the northeast-striking faults in southeastern Missouri as a result of strain influenced by the convergence directions of the different Paleozoic orogenies.

  5. Aspects of the magmatic geochemistry of bismuth

    USGS Publications Warehouse

    Greenland, L.P.; Gottfried, D.; Campbell, E.Y.

    1973-01-01

    Bismuth has been determined in 74 rocks from a differentiated tholeiitic dolerite, two calc-alkaline batholith suites and in 66 mineral separates from one of the batholiths. Average bismuth contents, weighted for rock type, of the Great Lake (Tasmania) dolerite, the Southern California batholith and the Idaho batholith are, 32, 50 and 70 ppb respectively. All three bodies demonstrate an enrichment of bismuth in residual magmas with magmatic differentiation. Bismuth is greatly enriched (relative to the host rock) in the calcium-rich accessory minerals, apatite and sphene, but other mineral analyses show that a Bi-Ca association is of little significance to the magmatic geochemistry of bismuth. Most of the bismuth, in the Southern California batholith at least, occurs in a trace mineral phase (possibly sulfides) present as inclusions in the rock-forming minerals. ?? 1973.

  6. Simulation of Layered Magma Chambers.

    ERIC Educational Resources Information Center

    Cawthorn, Richard Grant

    1991-01-01

    The principles of magma addition and liquid layering in magma chambers can be demonstrated by dissolving colored crystals. The concepts of density stratification and apparent lack of mixing of miscible liquids is convincingly illustrated with hydrous solutions at room temperature. The behavior of interstitial liquids in "cumulus" piles can be…

  7. Tectonism and an Upper Silurian ramp-prodelta-rimmed shelf succession from Arctic Canada: an intracratonic product of Caledonian Compression

    SciTech Connect

    Packard, J.J.; Dixon, O.A.

    1987-05-01

    Late Silurian and Early Devonian shelf architecture in the vicinity of Cornwallis Island in the central Arctic Archipelago was largely determined by a series of diastrophic events that are collectively termed the Cornwallis disturbance. The disturbance affected a fault-bounded, basement-cored, intracratonic crustal segment, the Boothia Uplift, which forms a northerly trending feature some 1000 km long and 80 to 150 km wide oriented normal to the tectonodepositional strike of both the Franklinian and younger Sverdrup basins. Marine deposition within the vicinity of the uplift can be divided into five phases corresponding to changes in the relative intensity of penecontemporaneous regional tectonism. Phase 1 (late Ludlovian) is a quiescent stage, typified by carbonate ramp sedimentation. The Douro Ramp was a homoclinal ramp that bordered a low-energy, turbid, meromict sea. Phase 2 represents the termination of the stable carbonate ramp and the onset of syntectonic sedimentation. Phase 2 (late Ludlovian) is represented in the rock record by the precipitous and near-simultaneous occurrence of stacked hardgrounds, slope failure phenomena, ox-redox banding, tempestites with significant siliciclastic content, and abrupt shallowing of biofacies. Phase 3 (latest Ludlovian) corresponds to a period of continental wasting and deltaic sedimentation as the newly emergent terrane of the Boothia Uplift shed its detritus northward to form the Hotham clinoform. Phase 4 (latest Ludlovian to earliest Lochkovian) is represented by the Barlow Inlet Platform, an attached rimmed shelf with an accretionary shelf margin. The platform sequence is punctuated by a number (7 minimum) of major forestepping and backstepping events that are attributed to episodic movement of the Boothia Uplift. Phase 5 is the denouement of carbonate sedimentation in the study area.

  8. Infrared Spectroscopy and Stable Isotope Geochemistry of Hydrous Silicate Glasses

    SciTech Connect

    Stolper, Edward

    2007-03-05

    The focus of this DOE-funded project has been the study of volatile components in magmas and the atmosphere. Over the twenty-one year period of this project, we have used experimental petrology and stable isotope geochemistry to study the behavior and properties of volatile components dissolved in silicate minerals and melts and glasses. More recently, we have also studied the concentration and isotopic composition of CO2 in the atmosphere, especially in relation to air quality issues in the Los Angeles basin.

  9. Using Intensive Variables to Constrain Magma Source Regions

    NASA Astrophysics Data System (ADS)

    Edwards, B. R.; Russell, J. K.

    2006-05-01

    In the modern world of petrology, magma source region characterization is commonly the realm of trace element and isotopic geochemistry. However, major element analyses of rocks representing magmatic compositions can also be used to constrain source region charactertistics, which enhance the results of isotopic and trace element studies. We show examples from the northern Cordilleran volcanic province (NCVP), in the Canadian Cordillera, where estimations of thermodynamic intensive variables are used to resolve different source regions for mafic alkaline magmas. We have taken a non-traditional approach to using the compositions of three groups of mafic, alkaline rocks to characterize the source regions of magmas erupted in the NCVP. Based on measured Fe2O3 and FeO in rocks from different locations, the Atlin volcanic district (AVD), the Fort Selkirk volcanic complex (FSVC), the West Tuya volcanic field, (WTVF), we have estimated oxygen fugacities (fO2) for the source regions of magmas based on the model of Kress and Carmichael (1991) and the computational package MELTS/pMelts (Ghiorso and Sack, 1995; Ghiorso et al., 2002). We also have used Melts/pMelts to estimate liquidus conditions for the compositions represented by the samples as well as activities of major element components. The results of our calculations are useful for distinguishing between three presumably different magma series: alkaline basalts, basanites, and nephelinites (Francis and Ludden, 1990; 1995). Calculated intensive variables (fO2, activities SiO2, KAlSiO4, Na2SiO3) show clear separation of the samples into two groups: i) nephelinites and ii) basanites/alkaline basalts. The separation is especially evident on plots of log fO2 versus activity SiO2. The source region for nephelinitic magmas in the AVD is up to 2 log units more oxidized than that for the basanites/basalts as well as having a distinctly lower range of activities of SiO2. Accepting that our assumptions about the magmas

  10. Appendix G: Geochemistry

    SciTech Connect

    Cantrell, Kirk J.; Serne, R. Jeffrey; Zachara, John M.; Krupka, Kenneth M.; Dresel, P. Evan; Brown, Christopher F.; Freshley, Mark D.

    2008-01-17

    This appendix discusses the geology of the Hanford Site and singe-shell tank (SST) waste management areas (WMAs). The purpose is to provide the most recent geochemical information available for the SST WMAs and the Integrated Disposal Facility. This appendix summarizes the information in the geochemistry data package for the SST WMAs.

  11. Pristine highland clasts in consortium breccia 14305 Petrology and geochemistry

    SciTech Connect

    Shervais, J.W.; Taylor, L.A.

    1984-11-15

    Data are presented on the petrography and mineral chemistry of six pristine highland clasts chipped from the polymict lunar breccia 14305. Major and trace elements in the clasts were determined by instrumental neutron activation analysis, and mineral analyses were performed by electron microprobe. Mg-suite clasts have eastern geochemical affinities, reaffirming the importance of local variations in geochemistry. These local variations are superimposed on the moon-wide, longitudinal variations noted by Warren and Wasson (1980). Alkali anorthosites and Mg-suite troctolites and anorthosites are not comagmatic, and cannot be related to a single parent magma by either fractional crystallization or variable assimilation of KREEP. Both magma suites may have assimilated varied amounts of KREEP into distinct parent magmas. Alternatively, alkali anorthosites may have crystallized directly from a KREEP-basalt parent magma. A thick crust of ferroan anorthosite probably never existed on the western lunar nearside, or was removed by basin-forming impacts prior to intrusion of later plutonic suites.

  12. Giant plagioclase growth during storage of basaltic magma in Emeishan Large Igneous Province, SW China

    NASA Astrophysics Data System (ADS)

    Cheng, Li-Lu; Yang, Zong-Feng; Zeng, Ling; Wang, Yu; Luo, Zhao-Hua

    2014-02-01

    Giant plagioclase basalts (GPBs) reflect the storage of flood basalt magma in subvolcanic magma chambers at crustal depths. In this study of the Late Permian Emeishan large igneous province in southwest China, we focus on understanding the plumbing system and ascent of large-volume basaltic magma. We report a quantitative textural analysis and bulk-rock geochemical composition of clustered touching crystals (CT-type) and single isolated crystal (SI-type) GPB samples from 5- to 240-m-thick flows in the Daqiao section. Both types of GPBs are evolved (<6 MgO wt%), but have high Ti/Y ratios (>500) and high total FeO content (11.5-15.2 wt%). The mineral chemistry of the two types of plagioclase displays a small range of anorthite content (<5 mol%), which is consistent with their unzoned characteristics. The two types of GPBs have S-type crystal size distributions but have quite different slopes, intercepts, and characteristic lengths. The characteristic lengths of the five flows are 1.54, 2.99, 1.70, 3.22, and 1.86 mm, respectively. For plagioclase growth rates of 10-11 to 10-10 mm/s, steady-state magma chamber models with simple continuous crystal growth suggest that CT-type plagioclase megacrysts have the residence time of about 500-6,000 years, whereas the residence time for SI-type plagioclase is significantly longer, about 1,000-10,000 years. By combining field geology, quantitative textural data with geochemistry, we suggest that CT- and SI-type crystals grew and were coarsened in the outer part and inner part of a magma chamber, respectively. Magma evolution during storage is controlled by crystallization, crystal growth, and magma mixing, and pulsating eruptions occur in response to the continuous supply of hot magma.

  13. The Mineralogy, Geochemistry, and Redox State of Multivalent Cations During the Crystallization of Primitive Shergottitic Liquids at Various (f)O2. Insights into the (f)O2 Fugacity of the Martian Mantle and Crustal Influences on Redox Conditions of Martian Magmas.

    NASA Technical Reports Server (NTRS)

    Shearer, C. K.; Bell, A. S.; Burger, P. V.; Papike, J. J.; Jones, J.; Le, L.; Muttik, N.

    2016-01-01

    The (f)O2 [oxygen fugacity] of crystallization for martian basalts has been estimated in various studies to range from IW-1 to QFM+4 [1-3]. A striking geochemical feature of the shergottites is the large range in initial Sr isotopic ratios and initial epsilon(sup Nd) values. Studies by observed that within the shergottite group the (f)O2 [oxygen fugacity] of crystallization is highly correlated with these chemical and isotopic characteristics with depleted shergottites generally crystallizing at reduced conditions and enriched shergottites crystallizing under more oxidizing conditions. More recent work has shown that (f)O2 [oxygen fugacity] changed during the crystallization of these magmas from one order of magnitude in Y980459 (Y98) to several orders of magnitude in Larkman Nunatak 06319. These real or apparent variations within single shergottitic magmas have been attributed to mixing of a xenocrystic olivine component, volatile loss-water disassociation, auto-oxidation during crystallization of mafic phases, and assimilation of an oxidizing crustal component (e.g. sulfate). In contrast to the shergottites, augite basalts such as NWA 8159 are highly depleted yet appear to be highly oxidized (e.g. QFM+4). As a first step in attempting to unravel petrologic complexities that influence (f)O2 [oxygen fugacity] in martian magmas, this study explores the effect of (f)O2 [oxygen fugacity] on the liquid line of descent (LLD) for a primitive shergottite liquid composition (Y98). The results of this study will provide a fundamental basis for reconstructing the record of (f)O2 [oxygen fugacity] in shergottites and other martian basalts, its effect on both mineral chemistries and valence state partitioning, and a means for examining the role of crystallization (and other more complex processes) on the petrologic linkages between olivine-phyric and pyroxene-plagioclase shergottites.

  14. Terrestrial magma ocean and core segregation in the earth

    NASA Technical Reports Server (NTRS)

    Ohtani, Eiji; Yurimoto, Naoyoshi

    1992-01-01

    According to the recent theories of formation of the earth, the outer layer of the proto-earth was molten and the terrestrial magma ocean was formed when its radius exceeded 3000 km. Core formation should have started in this magma ocean stage, since segregation of metallic iron occurs effectively by melting of the proto-earth. Therefore, interactions between magma, mantle minerals, and metallic iron in the magma ocean stage controlled the geochemistry of the mantle and core. We have studied the partitioning behaviors of elements into the silicate melt, high pressure minerals, and metallic iron under the deep upper mantle and lower mantle conditions. We employed the multi-anvil apparatus for preparing the equilibrating samples in the ranges from 16 to 27 GPa and 1700-2400 C. Both the electron probe microanalyzer (EPMA) and the Secondary Ion Mass spectrometer (SIMS) were used for analyzing the run products. We obtained the partition coefficients of various trace elements between majorite, Mg-perovskite, and liquid, and magnesiowustite, Mg-perovskite, and metallic iron. The examples of the partition coefficients of some key elements are summarized in figures, together with the previous data. We may be able to assess the origin of the mantle abundances of the elements such as transition metals by using the partitioning data obtained above. The mantle abundances of some transition metals expected by the core-mantle equilibrium under the lower mantle conditions cannot explain the observed abundance of some elements such as Mn and Ge in the mantle. Estimations of the densities of the ultrabasic magma Mg-perovskite at high pressure suggest existence of a density crossover in the deep lower mantle; flotation of Mg-perovskite occurs in the deep magma ocean under the lower mantle conditions. The observed depletion of some transition metals such as V, Cr, Mn, Fe, Co, and Ni in the mantle may be explained by the two stage process, the core-mantle equilibrium under the lower

  15. Quantifying magma segregation in dykes

    NASA Astrophysics Data System (ADS)

    Yamato, P.; Duretz, T.; May, D. A.; Tartèse, R.

    2015-10-01

    The dynamics of magma flow is highly affected by the presence of a crystalline load. During magma ascent, it has been demonstrated that crystal-melt segregation constitutes a viable mechanism for magmatic differentiation. Moreover, crystal-melt segregation during magma transport has important implications not only in terms of magma rheology, but also in terms of differentiation of the continental crust. However, the influences of the crystal volume percentage (φ), of their geometry, their size and their density on crystal-melt segregation are still not well constrained. To address these issues, we performed a parametric study using 2D direct numerical simulations, which model the ascension of a crystal-bearing magma in a vertical dyke. Using these models, we have characterised the amount of segregation as a function of different physical properties including φ, the density contrast between crystals and the melt phase (Δρ), the size of the crystals (Ac) and their aspect ratio (R). Results show that small values of R do not affect the segregation. In this case, the amount of segregation depends upon four parameters. Segregation is highest when Δρ and Ac are large, and lowest for large pressure gradient (Pd) and/or large values of dyke width (Wd). These four parameters can be combined into a single one, the Snumber, which can be used to quantify the amount of segregation occurring during magma ascent. Based on systematic numerical modelling and dimensional analysis, we provide a first order scaling law which allows quantification of the segregation for an arbitrary Snumber and φ, encompassing a wide range of typical parameters encountered in terrestrial magmatic systems. Although developed in a simplified system, this study has strong implications regarding our understanding of crystal segregation processes during magma transport. Our first order scaling law allows to immediately determine the amount of crystal-melt segregation occurring in any given magmatic

  16. Mare basalt magma source region and mare basalt magma genesis

    SciTech Connect

    Binder, A.B.

    1982-11-15

    Given the available data, we find that the wide range of mare basaltic material characteristics can be explained by a model in which: (1) The mare basalt magma source region lies between the crust-mantle boundary and a maximum depth of 200 km and consists of a relatively uniform peridotite containing 73--80% olivine, 11--14% pyroxene, 4--8% plagioclase, 0.2--9% ilmenite and 1--1.5% chromite. (2) The source region consists of two or more density-graded rhythmic bands, whose compositions grade from that of the very low TiO/sub 2/ magma source regions (0.2% ilmenite) to that of the very high TiO/sub 2/ magma source regions (9% ilmenite). These density-graded bands are proposed to have formed as co-crystallizing olivine, pyroxene, plagioclase, ilmenite, and chromite settled out of a convecting magma (which was also parental to the crust) in which these crystals were suspended. Since the settling rates of the different minerals were governed by Stoke's law, the heavier minerals settled out more rapidly and therefore earlier than the lighter minerals. Thus the crystal assemblages deposited nearest the descending side of each convection cell were enriched in heavy ilmenite and chromite with respect to lighter olivine and pyroxene and very much lighter plagioclase. The reverse being the case for those units deposited near the ascending sides of the convection cells.

  17. Electrical Properties of Hydrous Magmas

    NASA Astrophysics Data System (ADS)

    Laumonier, M.; Sifre, D.; Gaillard, F.

    2013-12-01

    Volatiles strongly affect physical and chemical properties of magmas which are major vectors of mass and heat transfer in the Earth's. In subduction zones, hydrated melts prevail during the entire course of differentiation from basalts, andesites, dacites to rhyolites. Several electrical surveys obtained by magneto telluric investigations are currently deployed at subduction zones. The electrical conductivity of hydrous melts is however poorly constrained: so far only three studies have experimentally addressed this topic. Here, we show in situ electrical impedance of natural dacites, andesites (from Uturuncu Volcano, Bolivia) and basaltic magmas obtained with a 4-wire set up in a piston cylinder and internally heated pressure vessel. The range of temperature (500 to 1300°C), pressure (0.3 to 2 Gpa), and the various water contents and crystal fractions covers the respective ranges occurring at natural conditions. First results show that the conductivity increases with the temperature, the melt fraction, and a slightly decreases with the pressure and the crystal fraction. The compilation of these results with previous studies (rhyolitic, phonolitic and basaltic compositions) will lead to a general model of the electrical properties of magmas. Such a model will help in (i) interpreting the electrical signature of natural magmas and (ii) constraining their conditions (chemical composition, temperature, pressure, water content, melt fraction) from the source to the storage location.

  18. Geochemistry and the environment

    NASA Astrophysics Data System (ADS)

    Moldan, Bedřich

    Geochemistry is one of the most important environmental disciplines. Indeed, a more proper term for this scientific field is biogeochemistry. The connection between the crucial aspects of the environment appears clearly from this term. It was coined by V.I. VERNADSKY in 1923 (MOCHALOV 1982). Later he incorporated this idea into the famous concept of the biosphere (VERNADSKY 1926) adopted by UNESCO in 1968 (UNESCO 1970) and is today one of the frequently used terms not only in scientific but also in general vocabulary.

  19. Carbonate assimilation during magma evolution at Nisyros (Greece), South Aegean Arc: Evidence from clinopyroxenite xenoliths

    NASA Astrophysics Data System (ADS)

    Spandler, Carl; Martin, Lukas H. J.; Pettke, Thomas

    2012-08-01

    To contribute to the understanding of magma evolution in arc settings we investigate the oldest volcanic unit (Kanafià Synthem) of Nisyros volcano, located in the eastern Aegean Sea (Greece). The unit consists of porphyritic pillow lavas of basaltic andesite composition with trace element signatures that are characteristic of island-arc magmas. Two lava types are distinguished on the basis of geochemistry and the presence or absence of xenoliths, with the xenolith-bearing lavas having distinctly elevated Sr, MREE/HREE and MgO/Fe2O3 compared to the xenolith-free lavas. Xenoliths include relatively rare quartzo-feldspathic fragments that represent continental-type material, and coarse clinopyroxenite xenoliths that consist largely of aluminous and calcic clinopyroxene, and accessory aluminous spinel. Anorthite-diopside reaction selvages preserved around the clinopyroxenite xenoliths demonstrate disequilibrium between the xenoliths and the host magma. The xenolith clinopyroxene is distinctly enriched in most lithophile trace elements compared to clinopyroxene phenocrysts in the host magmas. A notable exception is the Sr concentration, which is similar in both clinopyroxene types. The high Al and low Na contents of the clinopyroxenites preclude a cumulate, deep metamorphic, or mantle origin for these xenoliths. Instead, their composition and mineralogy are diagnostic of skarn rocks formed by magma-carbonate interaction in the mid/upper crust. The Kanafià lavas are interpreted to have undergone crystal fractionation, magma mixing/mingling and crustal assimilation while resident in the upper crust. We show that magma-carbonate reaction and associated skarn formation does not necessarily result in easily recognised modification of the melt composition, with the exception of increasing Sr contents. Carbonate assimilation also releases significant CO2, which will likely form a free vapour phase due to the low CO2 solubility of arc magmas. In the broader context, we stress

  20. Proceedings of the MEVTV Workshop on The Evolution of Magma Bodies on Mars

    NASA Technical Reports Server (NTRS)

    Mouginis-Mark, P. (Editor); Holloway, J. (Editor)

    1990-01-01

    The workshop focused on many of the diverse approaches related to the evolution of magma bodies on Mars that have been pursued during the course of the Mars Evolution of Volcanism, Tectonism, and Volatiles (MEVTV) Program. Approximately 35 scientists from the Mars volcanology, petrology, geochemistry, and modeling communities attended. Segments of the meeting concentrated of laboratory analyses and investigations of SNC meteorites, the interpretation of Viking Orbiter and Lander datasets, and the interpretation of computer codes that model volcanic and tectonic processes on Mars. Abstracts of these reports are presented.

  1. Comparative assessment of five potential sites for hydrothermal-magma systems: summary

    SciTech Connect

    Luth, W.C.; Hardee, H.C.

    1980-11-01

    A comparative assessment of five potential hydrothermal-magma sites for this facet of the Thermal Regimes part of the CSDP has been prepared for the DOE Office of Basic Energy Sciences. The five sites are: The Geysers-Clear Lake, CA, Long Valley, CA, Rio Grande Rift, NM, Roosevelt Hot Springs, UT, and Salton Trough, CA. This site assessment study has drawn together background information (geology, geochemistry, geophysics, and energy transport) on the five sites as a preliminary stage to site selection. Criteria for site selection are that potential sites have identifiable, or likely, hydrothermal systems and associated magma sources, and the important scientific questions can be identified and answered by deep scientific holes. Recommendations were made.

  2. Variations in magma supply and magma partitioning: the role of tectonic settings

    NASA Astrophysics Data System (ADS)

    Takada, Akira

    1999-11-01

    Magma supply rates for 200 years at Krafla and Lakagigar, Iceland, and those for 150 years at Kilauea and Mauna Loa, Hawaii, are estimated roughly, based on their geophysical and geological observations. A diagram that relates erupted volumes to eruption intervals at volcanoes under various tectonic settings is represented. These results lead to a new model that a large volume (1-10 km 3) of magma is supplied intermittently at a long interval (10 2-10 4 years) beneath volcanoes in rift zones, while magma is supplied continuously with oscillations or fluctuations beneath intraplate volcanoes. Chemical data such as the MgO wt.% of lava may be one indicator in evaluating the magma supply rates of Hawaiian volcanoes. Systematic variation with time in magma partitioning within a volcano or to the surface is obtained in comparisons between among migration patterns of eruption sites, cumulative supplied volumes, and the volume ratios of erupted to supplied magma at Krafla and Kilauea. The variations suggest that a magma plumbing system may act under self-control (regulating) system through stress as one system. In response to a change in magma supply rate, the system partitions magma horizontally into dikes or vertically toward the surface. A large magma supply rate promotes the vertical extent of a crack to result in an eruption with a large volume ratio of erupted to supplied magma. This tendency is supported by field observations of flood basalts. The partitioned magma as dike intrusions suppresses magma supply partially in the shallow crust. Using analog experiments on liquid-filled cracks in gelatin, this paper demonstrates fundamental processes for magma partitioning on the effect of magma supply and stress change by the partitioned magma. A dynamical system of two differential equations on magma supply rate and stress around a magma plumbing system is proposed, to understand the qualitative variations in magma supply rate imposed by tectonic settings.

  3. Impermeable high-porosity magmas

    NASA Astrophysics Data System (ADS)

    Heap, Michael; Vona, Alessandro; Kolzenburg, Stephan; Ryan, Amy; Russell, Kelly

    2016-04-01

    Magma vesiculation (i.e., porosity increase) is the consequence of decompression-driven volatile release during ascent and/or heating. The ease at which these exsolved volatiles can escape is thought to strongly impact volcanic explosivity. Permeability is usually considered to increase as a function of porosity. High and low porosity are typically associated with high and low permeability, respectively. Here we present permeability experiments on foamed natural rhyolitic melts containing total porosities from 0.12 to 0.65; we compliment these data with measurements on synthetic foamed glasses (prepared by FOAMGLAS®) that contain a total porosity of 0.9. The rhyolitic melts (from Krafla, Iceland: Tg = 690 °C) were kept at atmospheric pressure and 1000 °C for 0.5, 1, 2, and 4 hours, followed by quenching. The four experiments yielded total porosities of 0.12, 0.44, 0.51, and 0.65, respectively. The permeability of these samples was then measured using a steady-state, benchtop permeameter under a confining pressure of 1 MPa. The permeability of the foamed samples containing a porosity of 0.12 and 0.44 were not measurable in our system, meaning their permeabilities are lower than ~10-18 m2. The permeability of the samples containing a porosity of 0.51 and 0.65 were 8.7 × 10-15 and 1.0 × 10-15 m2, respectively. Both types of FOAMGLAS® - containing a porosity of 0.9 - also have permeabilities lower than ~10-18 m2. Our study highlights that highly porous magmas are not necessarily permeable due to the absence of a connected network of pores. These data suggest that (1) the percolation threshold for magma requires further thought and, (2) that the liberation of exsolved volatiles will require the fracturing of bubble walls to connect the network of pores within the magma.

  4. Partially molten magma ocean model

    SciTech Connect

    Shirley, D.N.

    1983-02-15

    The properties of the lunar crust and upper mantle can be explained if the outer 300-400 km of the moon was initially only partially molten rather than fully molten. The top of the partially molten region contained about 20% melt and decreased to 0% at 300-400 km depth. Nuclei of anorthositic crust formed over localized bodies of magma segregated from the partial melt, then grew peripherally until they coverd the moon. Throughout most of its growth period the anorthosite crust floated on a layer of magma a few km thick. The thickness of this layer is regulated by the opposing forces of loss of material by fractional crystallization and addition of magma from the partial melt below. Concentrations of Sr, Eu, and Sm in pristine ferroan anorthosites are found to be consistent with this model, as are trends for the ferroan anorthosites and Mg-rich suites on a diagram of An in plagioclase vs. mg in mafics. Clustering of Eu, Sr, and mg values found among pristine ferroan anorthosites are predicted by this model.

  5. Mushy magma processes in the Tuolumne intrusive complex, Sierra Nevada, California

    NASA Astrophysics Data System (ADS)

    Memeti, V.; Paterson, S. R.

    2012-12-01

    whole rock data. 4) Single mineral geochemistry suggests that this increased heterogeneity in the interior of the complex is likely caused by the presence of mixed mineral populations that acquired their compositional zoning in magmas different than the one they most recently crystallized in. 5) Mixed mineral populations have also been found in places of local magma mixing (e.g., tubes and troughs), and 6) oscillatory trace element zoning in K-feldspar phenocrysts most likely represents magma replenishment. All of these phenomena suggest a fairly dynamic environment of magma replenishment, magmatic erosion and extensive mixing at the locus of chamber growth. Magma replenishment subsided after episodic flare-ups and the magma mush dominantly underwent fractional crystallization and magmatic fabric formation during waning stages, when it was capable of preserving the evidence at map to crystal scale, lacking any later overprint by mixing. Fractionation related evidence is apparent in the presence of 1) map to outcrop scale leucogranite lenses and dikes in all major Tuolumne units (including the Johnson Peak granite itself), 2) the concentric compositional zonation of magmatic lobes (e.g., southern Half Dome lobe), 3) local crystal accumulations and widespread schlieren, and 4) fractionation related single mineral element zoning.

  6. Petrologic Insights into Magma System Response to Edifice Collapse

    NASA Astrophysics Data System (ADS)

    Shipman, J. S.; Izbekov, P. E.; Gavrilenko, M.

    2011-12-01

    In order to understand eruptive behavior at volcanic centers and to improve models for monitoring and prediction of volcanic eruptions, it is important to constrain magma storage conditions and transport in the system. Here the post-collapse eruptive behavior at Bezymianny and Shiveluch volcanoes, (Kamchatka Peninsula, Russia) are each compared to the well-known sequence at Mount St. Helens, Washington, USA (from 1956, 1964, and 1980, respectively). The magma system responds to rapid unloading of overburden pressure, due to edifice collapse, with a violent large-scale paroxysmal eruption. This reflects the amplitude of the triggering decompression event with later dome-building and explosive activity due to the reduction of vent elevation. The massive unloading events and post-collapse eruptive chronologies, provides a unique opportunity for comparison of the sources driving the catastrophic eruptions and eruptive style transitions. Analytical techniques employed included X-ray fluorescence spectroscopy, electron probe micro-analyses, Fe-Ti oxide and two-pyroxene geothermometry, X-ray elemental mapping, and a novel image processing technique. Presented here are results from petrological investigations into the temporal variations of whole-rock geochemistry, geothermometry, mineral modal abundances and textures. Bezymianny is becoming more mafic over time from 61.0 to 57.3 wt.% SiO2 (1956 and 2010). Pre-eruptive magma temperatures increased from 950oC to 1050oC from 1956 to 2006. Plagioclase and amphibole disequilibrium textures are observed throughout the time series and rare mafic enclaves exist. The whole-rock chemical trend at Shiveluch shows a subtle, yet reversed trend from 60.6 to 64.2 wt.% SiO2 (1964 and 2007). Two-pyroxene geothermometry yields ~950oC+30oC (2001-2007) and is consistent with data from the 2001 -2004 eruption, of 834-978oC+60oC. Mafic enclaves occurred throughout the entire period of eruptive activity at Shiveluch. In contrast to both

  7. Diverse magma flow directions during construction of sheeted dike complexes at fast- to superfast-spreading centers

    NASA Astrophysics Data System (ADS)

    Horst, A. J.; Varga, R. J.; Gee, J. S.; Karson, J. A.

    2014-12-01

    Dike intrusion is a fundamental process during upper oceanic crustal accretion at fast- to superfast-spreading ridges. Based on the distribution of magma along fast-spreading centers inferred from marine geophysical data, models predict systematic steep flow at magmatically robust segment centers and shallow magma flow toward distal segment ends. Anisotropy of magnetic susceptibility (AMS) fabrics from 48 fully-oriented block samples of dikes from upper oceanic crust exposed at Hess Deep Rift and Pito Deep Rift reveal a wide range of magma flow directions that are not consistent with such simple magma supply models. The AMS is interpreted to arise from distribution anisotropy of titanomagnetite crystals based on weak shape-preferred orientation of opaque oxide and plagioclase crystals generally parallel to AMS maximum eigenvectors. Most dike samples show normal AMS fabrics with maximum eigenvector directions ranging from subvertical to subhorizontal. The distributions of inferred magma flow lineations from maximum eigenvectors show no preferred flow pattern, even after structural correction. We use a Kolmogorov-Smirnov test (KS-test) to show that the distribution of bootstrapped flow lineation rakes from Pito Deep are not statistically distinct from Hess Deep, and neither are distinguishable from Oman and Troodos Ophiolite AMS data. Magma flow directions in sheeted dikes from these two seafloor escarpments also do not correlate with available geochemistry in any systematic way as previously predicted. These results indicate distinct compositional sources feed melt that is injected into dikes at fast- to superfast-spreading ridges with no preference for subhorizontal or subvertical magma flow. Collectively, results imply ephemeral melt lenses at different along-axis locations within the continuous axial magma chamber and either direct injection or intermingling of melt from other deeper ridge-centered or off-axis sources.

  8. Sulfide Mineralogy and Geochemistry

    NASA Astrophysics Data System (ADS)

    Dilles, John

    2007-02-01

    Reviews in Mineralogy and Geochemistry Series, Volume 61 David J. Vaughan, Editor Geochemical Society and Mineralogical Society of America; ISBN 0-939950-73-1 xiii + 714 pp.; 2006; $40. Sulfide minerals as a class represent important minor rock-forming minerals, but they are generally known as the chief sources of many economic metallic ores. In the past two decades, sulfide research has been extended to include important roles in environmental geology of sulfide weathering and resultant acid mine drainage, as well as in geomicrobiology in which bacteria make use of sulfides for metabolic energy sources. In the latter respect, sulfides played an important role in early evolution of life on Earth and in geochemical cycling of elements in the Earth's crust and hydrosphere.

  9. Shallow magma targets in the western US

    SciTech Connect

    Hardee, H.C.

    1984-10-01

    Within the next few years a hole will be drilled into a shallow magma body in the western US for the purpose of evaluating the engineering feasibility of magma energy. This paper examines potential drilling sites for these engineering feasibility experiments. Target sites high on the list are ones that currently exhibit good geophysical and geological data for shallow magma and also have reasonable operational requirements. Top ranked sites for the first magma energy well are Long Valley, CA, and Coso/Indian Wells, CA. Kilauea, HI, also in the top group, is an attractive site for some limited field experiments. A number of additional sites offer promise as eventual magma energy sites, but sparsity of geophysical data presently prevents these sites from being considered for the first magma energy well.

  10. Recent progress in magma energy extraction

    SciTech Connect

    Ortega, A.; Dunn, J.C.; Chu, T.Y.; Wemple, R.P.; Hickox, C.E.

    1987-01-01

    Ongoing research in the area of Magma Energy Extraction is directed at developing a fundamental understanding of the establishment and long term operation of an open, direct-contact heat exchanger in a crustal magma body. The energy extraction rate has a direct influence on the economic viability of the concept. An open heat exchanger, in which fluid is circulated through the interconnecting fissures and fractures in the solidified region around drilling tubing, offers the promise of very high rates of heat transfer. This paper discusses recent research in five areas: (1) fundamental mechanisms of solidifying and thermally fracturing magma; (2) convective heat transfer in the internally fractured solidified magma; (3) convective flow in the molten magma and heat transfer from the magma to the cooled heat exchanger protruding into it; (4) numerical simulation of the overall energy extraction process; and (5) the thermodynamics of energy conversion in a magma power plant at the surface. The studies show that an open heat exchanger can be formed by solidifying magma around a cooled borehole and that the resulting mass will be extensively fractured by thermally-induced stresses. Numerical models indicate that high quality thermal energy can be delivered at the wellhead at nominal rates from 25 to 30 MW electric. It is shown that optimum well circulation rates can be found that depend on the heat transfer characteristics of the magma heat exchanger and the thermodynamic power conversion efficiencies of the surface plant.

  11. Magma mixing in a zoned alkalic intrusion

    SciTech Connect

    Price, J.G.; Henry, C.D.; Barker, D.S.; Rubin, J.N.

    1985-01-01

    The Marble Canyon stock is unique among the alkalic intrusions of the Trans-Pecos magmatic province in being zoned from a critically silica-undersaturated rim of alkali gabbro (AG) to a silica-oversaturated core of quartz syenite (QS). Hybrid rocks of intermediate chemical and mineralogical compositions occur between the rim and core. Nepheline-syenite dikes occur only within the AG. Silica-rich dikes of quartz trachyte, pegmatite, and aplite cut the AG, QS, and hybrid rocks. Thermodynamic calculations of silica activity in the magmas illustrate the presence of two trends with decreasing temperature: a silica-poor trend from AG to nepheline syenite and a silica-rich trend from hybrid rocks to QS. Least-square modeling of rock and mineral compositions suggests 1) the nepheline syenites were derived by crystal-liquid fractionation from nearly solidified AG at the rim of the stock, 2) AG magma farther from the rim mixed with a small proportion of granitic magma, and 3) the mixture then differentiated to produce the hybrid rocks and QS. Zirconium dioxide inclusions in plagioclase crystals of the hybrid rocks and QS indicate that the AG magma contained some crystals before it mixed with the granitic magma. Two origins for the granitic magma are possible: 1) a late-stage differentiate of a mantle-derived hypersthene-normative magma and 2) melting of crustal material by the AG magma. Recognition of magma mixing might not have been possible if the AG had been hypersthene-normative.

  12. Evaluating volumes for magma chambers and magma withdrawn for caldera collapse

    NASA Astrophysics Data System (ADS)

    Geshi, Nobuo; Ruch, Joel; Acocella, Valerio

    2014-06-01

    We develop an analytical model to infer the total volume of a magma chamber associated with caldera collapse and the critical volume of magma that must be withdrawn to induce caldera collapse. The diameter of caldera border fault, depth to the magma chamber, and volumes of magma erupted before the onset of collapse and of entire eruption are compiled for 14 representative calderas. The volume of erupted magma at the onset of collapse aligns between the total erupted volume of the other representative caldera-forming eruptions and the volume of eruptions without collapse during the post-caldera stage, correlating with the structural diameter of the calderas. The total volume of magma chamber is evaluated using a piston-cylinder collapse model, in which the competition between the decompression inside magma chamber and friction along the caldera fault controls the collapse. Estimated volumes of the magma chambers associated with caldera collapse are 3-10 km3 for Vesuvius 79 A.D. to 3000-10 500 km3 for Long Valley, correlating with the cube of caldera diameters. The estimated volumes of magma chamber are always larger than the total volume of erupted magma for caldera formation, suggesting that the magma chambers are never completely emptied by the caldera-forming eruptions. The minimum volumes of erupted magma to trigger collapse are calculated from the correlation between the caldera diameters and the evaluated volume of magma chambers. The minimum eruptive volume for the collapse correlates with the square of the caldera radius r and the square of the depth to the magma chamber h, and inversely correlates with the bulk modulus of magma, which is mainly controlled by the bubble fraction in the magma. A bubble fraction between 5 and 10% at the onset of collapse may explain the distribution of the erupted volumes at the onset of collapse of the calderas in nature.

  13. Recurrent patterns in fluid geochemistry data prior to phreatic eruptions

    NASA Astrophysics Data System (ADS)

    Rouwet, Dmitri; Sandri, Laura; Todesco, Micol; Tonini, Roberto; Pecoraino, Giovannella; Diliberto, Iole Serena

    2016-04-01

    Not all volcanic eruptions are magma-driven: the sudden evaporation and expansion of heated groundwater may cause phreatic eruptions, where the magma involvement is absent or negligible. Active crater lakes top some of the volcanoes prone to phreatic activity. This kind of eruption may occur suddenly, and without clear warning: on September 27, 2014 a phreatic eruption of Ontake, Japan, occurred without timely precursors, killing 57 tourists near the volcano summit. Phreatic eruptions can thus be as fatal as higher VEI events, due to the lack of recognised precursory signals, and because of their explosive and violent nature. In this study, we tackle the challenge of recognising precursors to phreatic eruptions, by analysing the records of two "phreatically" active volcanoes in Costa Rica, i.e. Poás and Turrialba, respectively with and without a crater lake. These volcanoes cover a wide range of time scales in eruptive behaviour, possibly culminating into magmatic activity, and have a long-term multi-parameter dataset mostly describing fluid geochemistry. Such dataset is suitable for being analysed by objective pattern recognition techniques, in search for recurrent schemes. The aim is to verify the existence and nature of potential precursory patterns, which will improve our understanding of phreatic events, and allow the assessment of the associated hazard at other volcanoes, such as Campi Flegrei or Vulcano, in Italy. Quantitative forecast of phreatic activity will be performed with BET_UNREST, a Bayesian Event Tree tool recently developed within the framework of FP7 EU VUELCO project. The study will combine the analysis of fluid geochemistry data with pattern recognition and phreatic eruption forecast on medium and short-term. The study will also provide interesting hints on the features that promote or hinder phreatic activity in volcanoes that host well-developed hydrothermal circulation.

  14. Response of a low-subsiding intracratonic basin to long wavelength deformations: the Palaeocene-early Eocene period in the Paris Basin

    NASA Astrophysics Data System (ADS)

    Briais, J.; Guillocheau, F.; Lasseur, E.; Robin, C.; Châteauneuf, J. J.; Serrano, O.

    2016-02-01

    The uppermost Cretaceous to early Palaeogene is a period of major deformations of the western part of the Eurasian plate with prominent basin inversions starting from the Coniacian onwards. These deformations occur in a complex geodynamic setting within both the context of the Africa-Eurasia convergence and the North Atlantic opening. While Mesozoic graben inversions have been extensively studied, particularly in Eastern Europe and the North Sea, more gentle deformations that affect thicker crust areas (intracratonic basins and emerged lands) are not as well documented. The objective of this study is to constrain the exact timing, type, and magnitude of the early Palaeogene deformations affecting the intracratonic Paris Basin and to integrate them at the western European scale. Low-amplitude deformations are attempted through a high-resolution reconstitution of its stratigraphic record based on well-dated outcrops and well-dated wells, and a high number of well-logs that are correlated using the "stacking pattern" sequence stratigraphic technique. Two orders of sequences are identified (third and fourth order) and correlated throughout the basin. Basin geometric and palaeogeographic reconstitutions are based on sediment thickness and facies analysis. Two-dimensional accommodation space measurements were taken in order to quantify the magnitude of the deformations. Three phases of deformation were recognized. 1. An intra-Maastrichtian-pre-Thanetian (59 Ma) deformation, with major uplift and erosion of the Cretaceous strata with two sub-periods of deformation: Maastrichtian-pre-middle-Danian and Upper Danian-pre-Thanetian long-wavelength deformations. This period of major deformation is coeval with Upper Cretaceous/pre-Danian compressive deformations linked to the Africa-Eurasia convergence in southern France and with volcanic activity from the North Atlantic to Massif Central and the Rhenish Shield during the Palaeocene. 2. An early Ypresian (55.1-54.3 Ma) medium

  15. Response of a low subsiding intracratonic basin to long wavelength deformations: the Palaeocene-early Eocene period in the Paris basin

    NASA Astrophysics Data System (ADS)

    Briais, J.; Guillocheau, F.; Lasseur, E.; Robin, C.; Châteauneuf, J. J.; Serrano, O.

    2015-12-01

    The uppermost Cretaceous to early Palaeogene is a period of major deformations of the western part of the Eurasian plate with prominent basin inversions starting from the Coniacian onwards. These deformations occur in a complex geodynamic setting within both the context of the Africa-Eurasia convergence and the North Atlantic opening. While Mesozoic graben inversions have been extensively studied, particularly in Eastern Europe and the North Sea, more gentle deformations that affect thicker crust areas (intracratonic basins and emerged lands) are not as well documented. The objective of this study is to constrain the exact timing, type and magnitude of the early Palaeogene deformations affecting the intracratonic Paris basin and to integrate them at the Western European scale. Relatively gentle deformations are attempted through a high-resolution reconstitution of its stratigraphic record based on outcrops and well-dated wells, and a high number of well-logs that are correlated using the "stacking pattern" sequence stratigraphic technique. Two orders of sequences are identified (third- and fourth-order) and correlated throughout the basin. Basin geometric and palaeogeographic reconstitutions are based on sediment thickness and facies analysis. Two-dimensional accommodation space measurements were taken in order to quantify the magnitude of the deformations. Three phases of deformation were recognized. 1. An intra-Maastrichtian-pre-Thanetian (59 Ma) deformation, with major uplift and erosion of the Cretaceous strata with two sub-periods of deformation: Maastrichtian-pre-middle-Danian and Upper Danian-pre-Thanetian long wavelength deformations. This period of major deformation is coeval with Upper Cretaceous-pre-Danian compressive deformations linked to the Africa-Eurasia convergence in southern France and with volcanic activity from the North Atlantic to Massif Central and the Rhenish Shield during the Palaeocene; 2. an early Ypresian (55.1-54.3 Ma) medium

  16. Coal Formation and Geochemistry

    NASA Astrophysics Data System (ADS)

    Orem, W. H.; Finkelman, R. B.

    2003-12-01

    Coal is one of the most complex and challenging natural materials to analyze and to understand. Unlike most rocks, which consist predominantly of crystalline mineral grains, coal is largely an assemblage of amorphous, degraded plant remains metamorphosed to various degrees and intermixed with a generous sprinkling of minute syngenetic, diagenetic, epigenetic, and detrital mineral grains, and containing within its structure various amounts of water, oils, and gases. Each coal is unique, having been derived from different plant sources over geologic time, having experienty -45ced different thermal histories, and having been exposed to varying geologic processes. This diversity presents a challenge to constructing a coherent picture of coal geochemistry and the processes that influence the chemical composition of coal.Despite the challenge coal presents to geochemists, a thorough understanding of the chemistry and geology of this complex natural substance is essential because of its importance to our society. Coal is, and will remain for sometime, a crucial source of energy for the US and for many other countries (Figure 1). In the USA, more than half of the electricity is generated by coal-fired power plants, and almost 90% of the coal mined in the USA is sold for electricity generation (Pierce et al., 1996). It is also an important source of coke for steel production, chemicals, pharmaceuticals, and even perfumes ( Schobert, 1987). It may also, in some cases, be an economic source of various mineral commodities. The utilization of coal through mining, transport, storage, combustion, and the disposal of the combustion by-products, also presents a challenge to geochemists because of the wide range of environmental and human health problems arising from these activities. The sound and effective use of coal as a natural resource requires a better understanding of the geochemistry of coal, i.e., the chemical and mineralogical characteristics of the coal that control its

  17. Formation of redox gradients during magma-magma mixing

    NASA Astrophysics Data System (ADS)

    Ruprecht, P.; Fiege, A.; Simon, A. C.

    2015-12-01

    Magma-mixing is a key process that controls mass transfer in magmatic systems. The variations in melt compositions near the magma-magma interface potentially change the Fe oxidation state [1] and, thus, affect the solubility and transport of metals. To test this hypothesis, diffusion-couple experiments were performed at 1000 °C, 150 MPa and QFM+4. Synthesized crystal-bearing cylinders of hydrous dacite and hydrous basaltic andesite were equilibrated for up to 80 h. The run products show that mafic components (Fe, Mg, etc.) were transported from the andesite into the dacite, while Si, Na and K diffused from the dacite into the andesite. A crystal dissolution sequence in the order of cpx, opx, plag, and spl/il was observed for the andesite. We combined μ-XANES spectroscopy at Fe K-edge [2] with two-oxide oxybarometry [3] to measure redox profiles within our experiments. Here, fO2 decreased towards the interface within the dacite and increased towards the interface within the andesite. This discontinuous fO2 evolution, with a sharp redox gradient of ~1.8 log fO2 units at the interface was maintained throughout the time-series despite the externally imposed fO2 of the vessel. We propose a combination of two mechanisms that create and sustain this redox gradient: 1) The dissolution of cpx and opx in the andesite mainly introduced Fe2+ into the melt, which diffused towards the dacite, lowering Fe3+/SFe near the interface. 2) Charge balance calculations in the melt during diffusive exchange suggest net positive charge excess in the andesite near the interface (i.e., oxidation) and net negative charge excess in the dacite near the interface (i.e., reduction). We suggest that this (metastable) redox layer can help to explain the contrasting Au/Cu ratios observed for arc-related porphyry-type ore deposits. [1] Moretti (2005), Ann. Geophys. 48, 583-608. [2] Cottrell et al. (2009), Chem. Geol. 268, 167-179. [3] Ghiorso and Evans (2008), Am. J. Sci. 308, 957-1039.

  18. Why do Martian Magmas erupt?

    NASA Astrophysics Data System (ADS)

    Balta, J. B.; McSween, H. Y.

    2011-12-01

    Eruption of silicate lava, whether on Earth or another planet, requires that at some depth the melt has lower density than the surrounding rocks. As the densities of silicate liquids change during crystallization, whether a particular silicate liquid will erupt or be trapped at a level of neutral buoyancy is a complex yet fundamental issue for planetary dynamics. In general, 3 factors drive surface eruptions: inherent buoyancy relative to mantle phases, compositional evolution, and volatile contents. These factors manifest on Earth as terrestrial basalts commonly have compositions close to a density minimum [1]. Recent work has produced estimates of Martian parental magma compositions [2-5] based on shergottite meteorites and from Gusev crater. Using the MELTS algorithm [6] and other density calibrations, we simulated evolution of these liquids, focusing on density changes. For much of the crystallization path, density is controlled by FeO. All of the liquids begin with ρ ~ 2.8 g/cc at 1 bar, and the evolution of liquid density is controlled by the liquidus phases. At low pressures, olivine is the liquidus phase for each melt, and as FeO is not incompatible in olivine, olivine crystallization decreases liquid density, increasing buoyancy with crystallization. However, FeO is incompatible in pyroxene, and thus liquids crystallizing pyroxene become denser and less buoyant with crystallization, producing liquids with densities up to and above 3.0 g/cc. As the olivine-pyroxene saturation relationship is affected by pressure and chemistry, the identity of the liquidus phase and density evolution will vary between magmas. Without spreading centers, Mars has no location where the mantle approaches the surface, and it is likely that any magma which is denser than the crust will stall below or within that crust. The crystallization path of a liquid is a function of pressure, with pyroxene crystallizing first at P > 10 kbar (~80 km depth), close to the base of the Martian

  19. Taxonomy Of Magma Mixing I: Magma Mixing Metrics And The Thermochemistry Of Magma Hybridization Illuminated With A Toy Model

    NASA Astrophysics Data System (ADS)

    Spera, F. J.; Bohrson, W. A.; Schmidt, J.

    2013-12-01

    The rock record preserves abundant evidence of magma mixing in the form of mafic enclaves and mixed pumice in volcanic eruptions, syn-plutonic mafic or silicic dikes and intrusive complexes, replenishment events recorded in cumulates from layered intrusions, and crystal scale heterogeneity in phenocrysts and cumulate minerals. These evidently show that magma mixing in conjunction with crystallization (perfect fractional or incremental batch) is a first-order petrogenetic process. Magma mixing (sensu lato) occurs across a spectrum of mixed states from magma mingling to complete blending. The degree of mixing is quantified (Oldenburg et al, 1989) using two measures: the statistics of the segregation length scales (scale of segregation, L*) and the spatial contrast in composition (C) relative to the mean C (intensity of segregation, I). Mingling of dissimilar magmas produces a heterogeneous mixture containing discrete regions of end member melts and populations of crystals with L* = finite and I > 0. When L*→∞ and I→0 , the mixing magmas become hybridized and can be studied thermodynamically. Such hybrid magma is a multiphase equilibrium mixture of homogeneous melt, unzoned crystals and possible bubbles of a supercritical fluid. Here, we use a toy model to elucidate the principles of magma hybridization in a binary system (components A and B with pure crystals of α or β phase) with simple thermodynamics to build an outcome taxonomy. This binary system is not unlike the system Anorthite-Diopside, the classic low-pressure model basalt system. In the toy model, there are seven parameters describing the phase equilibria (eutectic T and X, specific heat, melting T and fusion enthalpies of α and β crystals) and five variables describing the magma mixing conditions: end member bulk compositions, temperatures and fraction of resident magma (M) that blends with recharge (R) magma to form a single equilibrium hybrid magma. There are 24 possible initial states when M

  20. Geochemistry and chronology of the Bunburra Rockhole ungrouped achondrite

    NASA Astrophysics Data System (ADS)

    Spivak-Birndorf, Lev J.; Bouvier, Audrey; Benedix, Gretchen K.; Hammond, Samantha; Brennecka, Gregory A.; Howard, Kieren; Rogers, Nick; Wadhwa, Meenakshi; Bland, Philip A.; Spurný, Pavel; Towner, Martin C.

    2015-05-01

    Bunburra Rockhole is a unique basaltic achondrite that has many mineralogical and petrographic characteristics in common with the noncumulate eucrites, but differs in its oxygen isotope composition. Here, we report a study of the mineralogy, petrology, geochemistry, and chronology of Bunburra Rockhole to better understand the petrogenesis of this meteorite and compare it to the eucrites. The geochemistry of bulk samples and of pyroxene, plagioclase, and Ca-phosphate in Bunburra Rockhole is similar to that of typical noncumulate eucrites. Chronological data for Bunburra Rockhole indicate early formation, followed by slow cooling and perhaps multiple subsequent heating events, which is also similar to some noncumulate eucrites. The 26Al-26Mg extinct radionuclide chronometer was reset in Bunburra Rockhole after the complete decay of 26Al, but a slight excess in the radiogenic 26Mg in a bulk sample allows the determination of a model 26Al-26Mg age that suggests formation of the parent melt for this meteorite from its source magma within the first ~3 Ma of the beginning of the solar system. The 207Pb-206Pb absolute chronometer is also disturbed in Bunburra Rockhole minerals, but a whole-rock isochron provides a re-equilibration age of ~4.1 Ga, most likely caused by impact heating. The mineralogy, geochemistry, and chronology of Bunburra Rockhole demonstrate the similarities of this achondrite to the eucrites, and suggest that it formed from a parent melt with a composition similar to that for noncumulate eucrites and subsequently experienced a thermal history and evolution comparable to that of eucritic basalts. This implies the formation of multiple differentiated parent bodies in the early solar system that had nearly identical bulk elemental compositions and petrogenetic histories, but different oxygen isotope compositions inherited from the solar nebula.

  1. Magma Energy Research Project, FY80 annual progress report

    SciTech Connect

    Colp, J.L.

    1982-04-01

    The technical feasibility of extracting energy from magma bodies is explored. Five aspects of the project are studied: resource location and definition, source tapping, magma characterization, magma/material compatibility, and energy extraction.

  2. Magma ocean: Mechanisms of formation

    NASA Technical Reports Server (NTRS)

    Kaula, W. M.

    1992-01-01

    The thermal state of the Earth at the time relevant to formation of a magma ocean was dominated by the great impact that created the Moon. As shown in computer experiments, the iron in the impacting bodies quickly sank to the core of the proto-Earth, while a significant fraction of silicates was pushed far enough out beyond the geosynchronous limit to constitute the main material of the Moon. Most of any atmosphere would have been pushed aside, rather than being expelled in the impact. However, the energy remaining in the material not going to the core or expelled was still sufficient to raise its temperature some 1000's of degrees, enough to vaporize silicates and to generate a strong 'planetary wind': a hydrodynamic expansion carrying with it virtually all volatiles plus appreciable silicates. This expansion was violent and uneven in its most energetic stage, but probably the resulting magma ocean was global. The duration, until cooling, was sufficient for silicates to condense to melt and the duration was probably short. Comparison of the Earth and Venus indicates that the great impact was extraordinarily effective in removing volatiles from the proto-Earth; in particular, the enormous differences in primordial inert gases between the planets demand a catastrophic difference in origin circumstances. On the other hand, the comparison limits the amount of silicates lost by the Earth to a rather minor fraction; most of that expelled in the wind must have condensed soon enough for the silicate to fall back to Earth or be swept up by the proto-Moon. So the Earth was left with a magma ocean. The question is whether sufficient water was retained to constitute a steam atmosphere. Probably not, but unknowns affecting this question are the efficiencies of outgassing in great impacts and in subsequent convective churnings deep in the mantle. During the stage when mantle convection is turbulent, an appreciable fraction of volatiles were also retained at depth, perhaps in

  3. Depth of origin of magma in eruptions

    PubMed Central

    Becerril, Laura; Galindo, Ines; Gudmundsson, Agust; Morales, Jose Maria

    2013-01-01

    Many volcanic hazard factors - such as the likelihood and duration of an eruption, the eruption style, and the probability of its triggering large landslides or caldera collapses - relate to the depth of the magma source. Yet, the magma source depths are commonly poorly known, even in frequently erupting volcanoes such as Hekla in Iceland and Etna in Italy. Here we show how the length-thickness ratios of feeder dykes can be used to estimate the depth to the source magma chamber. Using this method, accurately measured volcanic fissures/feeder-dykes in El Hierro (Canary Islands) indicate a source depth of 11–15 km, which coincides with the main cloud of earthquake foci surrounding the magma chamber associated with the 2011–2012 eruption of El Hierro. The method can be used on widely available GPS and InSAR data to calculate the depths to the source magma chambers of active volcanoes worldwide. PMID:24067336

  4. Gas-driven filter pressing in magmas

    USGS Publications Warehouse

    Sisson, T.W.; Bacon, C.R.

    1999-01-01

    Most silicic and some mafic magmas expand via second boiling if they crystallize at depths of about 10 km or less. The buildup of gas pressure due to second boiling can be relieved by expulsion of melt out of the region of crystallization, and this process of gas-driven filter pressing assists the crystallization differentiation of magmas. For gas-driven filter pressing to be effective, the region of crystallization must inflate slowly relative to buildup of pressure and expulsion of melt These conditions are satisfied in undercooled magmatic inclusions and in thin sheets of primitive magma underplating cooler magma reservoirs. Gas-driven filter pressing thereby adds fractionated melt to magma bodies. Gas-driven filter pressing is probably the dominant process by which highly evolved melts segregate from crystal mush to form aplitic dikes in granitic plutons; this process could also account for the production of voluminous, crystal-poor rhyolites.

  5. Depth of origin of magma in eruptions.

    PubMed

    Becerril, Laura; Galindo, Ines; Gudmundsson, Agust; Morales, Jose Maria

    2013-01-01

    Many volcanic hazard factors--such as the likelihood and duration of an eruption, the eruption style, and the probability of its triggering large landslides or caldera collapses--relate to the depth of the magma source. Yet, the magma source depths are commonly poorly known, even in frequently erupting volcanoes such as Hekla in Iceland and Etna in Italy. Here we show how the length-thickness ratios of feeder dykes can be used to estimate the depth to the source magma chamber. Using this method, accurately measured volcanic fissures/feeder-dykes in El Hierro (Canary Islands) indicate a source depth of 11-15 km, which coincides with the main cloud of earthquake foci surrounding the magma chamber associated with the 2011-2012 eruption of El Hierro. The method can be used on widely available GPS and InSAR data to calculate the depths to the source magma chambers of active volcanoes worldwide. PMID:24067336

  6. More Evidence for Multiple Meteorite Magmas

    NASA Astrophysics Data System (ADS)

    Taylor, G. J.

    2009-02-01

    Cosmochemists have identified six main compositional types of magma that formed inside asteroids during the first 100 million years of Solar System history. These magmas vary in their chemical and mineralogical make up, but all have in common low concentrations of sodium and other volatile elements. Our low-sodium-magma diet has now changed. Two groups of researchers have identified a new type of asteroidal magma that is rich in sodium and appears to have formed by partial melting of previously unmelted, volatile-rich chondritic rock. The teams, one led by James Day (University of Maryland) and the other by Chip Shearer (University of New Mexico), studied two meteorites found in Antarctica, named Graves Nunatak 06128 and 06129, using a battery of cosmochemical techniques. These studies show that an even wider variety of magmas was produced inside asteroids than we had thought, shedding light on the melting histories and formation of asteroids.

  7. Depth of origin of magma in eruptions.

    PubMed

    Becerril, Laura; Galindo, Ines; Gudmundsson, Agust; Morales, Jose Maria

    2013-09-26

    Many volcanic hazard factors--such as the likelihood and duration of an eruption, the eruption style, and the probability of its triggering large landslides or caldera collapses--relate to the depth of the magma source. Yet, the magma source depths are commonly poorly known, even in frequently erupting volcanoes such as Hekla in Iceland and Etna in Italy. Here we show how the length-thickness ratios of feeder dykes can be used to estimate the depth to the source magma chamber. Using this method, accurately measured volcanic fissures/feeder-dykes in El Hierro (Canary Islands) indicate a source depth of 11-15 km, which coincides with the main cloud of earthquake foci surrounding the magma chamber associated with the 2011-2012 eruption of El Hierro. The method can be used on widely available GPS and InSAR data to calculate the depths to the source magma chambers of active volcanoes worldwide.

  8. Fractional Crystallisation of Archaean Trondhjemite Magma at 12-7 Kbar: Constraints on Rheology of Archaean Continental Crust

    NASA Astrophysics Data System (ADS)

    Sarkar, Saheli; Saha, Lopamudra; Satyanarayan, Manavalan; Pati, Jayanta

    2015-04-01

    Fractional Crystallisation of Archaean Trondhjemite Magma at 12-7 Kbar: Constraints on Rheology of Archaean Continental Crust Sarkar, S.1, Saha, L.1, Satyanarayan, M2. and Pati, J.K.3 1. Department of Earth Sciences, Indian Institute of Technology Roorkee, Roorkee-247667, Haridwar, India, 2. HR-ICPMS Lab, Geochemistry Group, CSIR-National Geophysical Research Institute, Hyderabad-50007, India. 3. Department of Earth and Planetary Sciences, Nehru Science Centre, University of Allahabad, Allahabad-211002, India. Tonalite-Trondhjemite-Granodiorite (TTGs) group of rocks, that mostly constitute the Archaean continental crusts, evolved through a time period of ~3.8 Ga-2.7 Ga with major episodes of juvenile magma generations at ~3.6 Ga and ~2.7 Ga. Geochemical signatures, especially HREE depletions of most TTGs conform to formation of this type of magma by partial melting of amphibolites or eclogites at 15-20 kbar pressure. While TTGs (mostly sodic in compositions) dominates the Eoarchaean (~3.8-3.6 Ga) to Mesoarchaean (~3.2-3.0 Ga) domains, granitic rocks (with significantly high potassium contents) became more dominant in the Neoarchaean period. The most commonly accepted model proposed for the formation of the potassic granite in the Neoarchaean time is by partial melting of TTGs along subduction zones. However Archaean granite intrusive into the gabbro-ultramafic complex from Scourie, NW Scotland has been interpreted to have formed by fractional crystallization of hornblende and plagioclase from co-existing trondhjemitic gneiss. In this study we have studied fractional crystallization paths from a Mesoarchaean trondhjemite from the central Bundelkhand craton, India using MELTS algorithm. Fractional crystallization modeling has been performed at pressure ranges of 20 kbar to 7 kbar. Calculations have shown crystallization of garnet-clinopyroxene bearing assemblages with progressive cooling of the magma at 20 kbar. At pressure ranges 19-16 kbar, solid phases

  9. Lithospheric controls on magma composition along Earth's longest continental hotspot track.

    PubMed

    Davies, D R; Rawlinson, N; Iaffaldano, G; Campbell, I H

    2015-09-24

    Hotspots are anomalous regions of volcanism at Earth's surface that show no obvious association with tectonic plate boundaries. Classic examples include the Hawaiian-Emperor chain and the Yellowstone-Snake River Plain province. The majority are believed to form as Earth's tectonic plates move over long-lived mantle plumes: buoyant upwellings that bring hot material from Earth's deep mantle to its surface. It has long been recognized that lithospheric thickness limits the rise height of plumes and, thereby, their minimum melting pressure. It should, therefore, have a controlling influence on the geochemistry of plume-related magmas, although unambiguous evidence of this has, so far, been lacking. Here we integrate observational constraints from surface geology, geochronology, plate-motion reconstructions, geochemistry and seismology to ascertain plume melting depths beneath Earth's longest continental hotspot track, a 2,000-kilometre-long track in eastern Australia that displays a record of volcanic activity between 33 and 9 million years ago, which we call the Cosgrove track. Our analyses highlight a strong correlation between lithospheric thickness and magma composition along this track, with: (1) standard basaltic compositions in regions where lithospheric thickness is less than 110 kilometres; (2) volcanic gaps in regions where lithospheric thickness exceeds 150 kilometres; and (3) low-volume, leucitite-bearing volcanism in regions of intermediate lithospheric thickness. Trace-element concentrations from samples along this track support the notion that these compositional variations result from different degrees of partial melting, which is controlled by the thickness of overlying lithosphere. Our results place the first observational constraints on the sub-continental melting depth of mantle plumes and provide direct evidence that lithospheric thickness has a dominant influence on the volume and chemical composition of plume-derived magmas.

  10. Lithospheric Controls on Magma Composition along Earth's Longest Continental Hotspot-Track

    NASA Astrophysics Data System (ADS)

    Rawlinson, N.; Davies, R.; Iaffaldano, G.; Campbell, I. H.

    2014-12-01

    Hotspots are anomalous regions of volcanism at Earth's surface that show no obvious association with tectonic plate boundaries. Classic examples include the Hawaiian-Emperor chain and the Yellowstone-Snake River Plain province. The majority are believed to form as Earth's tectonic plates move over long-lived mantle plumes: buoyant upwellings that bring hot material from Earth's deep-mantle to its surface. It has long been recognised that lithospheric thickness limits the rise height of plumes and, thereby, their minimum melting pressure. It should, therefore, have a controlling influence on the geochemistry of plume-related magmas, although unambiguous evidence of this has, thus far, been lacking. Here we integrate observational constraints from surface geology, geochronology, plate-motion reconstructions, geochemistry and seismology to ascertain plume melting depths beneath Earth's longest continental hotspot-track, a ~2000 km long track in eastern Australia that displays a record of volcanic activity between ~33 and ~9 Ma, which we call the Cosgrove track. Our analyses highlight a strong correlation between lithospheric thickness and magma composition along this track, with: (i) standard basaltic compositions in regions where lithospheric thickness is less than ~110 km; (ii) volcanic gaps in regions where lithospheric thickness exceeds ~150 km; and (iii) low-volume, leucitite-bearing volcanism in regions of intermediate lithospheric thickness. Trace-element concentrations from samples along this track support the notion that these compositional variations result from different degrees of partial-melting, which is controlled by the thickness of overlying lithosphere. Our results place the first observational constraints on the subcontinental melting depth of mantle plumes and provide direct evidence that lithospheric thickness has a dominant influence on the volume and chemical composition of plume-derived magmas.

  11. Lithospheric controls on magma composition along Earth's longest continental hotspot track

    NASA Astrophysics Data System (ADS)

    Davies, D. R.; Rawlinson, N.; Iaffaldano, G.; Campbell, I. H.

    2015-09-01

    Hotspots are anomalous regions of volcanism at Earth's surface that show no obvious association with tectonic plate boundaries. Classic examples include the Hawaiian-Emperor chain and the Yellowstone-Snake River Plain province. The majority are believed to form as Earth's tectonic plates move over long-lived mantle plumes: buoyant upwellings that bring hot material from Earth's deep mantle to its surface. It has long been recognized that lithospheric thickness limits the rise height of plumes and, thereby, their minimum melting pressure. It should, therefore, have a controlling influence on the geochemistry of plume-related magmas, although unambiguous evidence of this has, so far, been lacking. Here we integrate observational constraints from surface geology, geochronology, plate-motion reconstructions, geochemistry and seismology to ascertain plume melting depths beneath Earth's longest continental hotspot track, a 2,000-kilometre-long track in eastern Australia that displays a record of volcanic activity between 33 and 9 million years ago, which we call the Cosgrove track. Our analyses highlight a strong correlation between lithospheric thickness and magma composition along this track, with: (1) standard basaltic compositions in regions where lithospheric thickness is less than 110 kilometres; (2) volcanic gaps in regions where lithospheric thickness exceeds 150 kilometres; and (3) low-volume, leucitite-bearing volcanism in regions of intermediate lithospheric thickness. Trace-element concentrations from samples along this track support the notion that these compositional variations result from different degrees of partial melting, which is controlled by the thickness of overlying lithosphere. Our results place the first observational constraints on the sub-continental melting depth of mantle plumes and provide direct evidence that lithospheric thickness has a dominant influence on the volume and chemical composition of plume-derived magmas.

  12. Lithospheric controls on magma composition along Earth's longest continental hotspot track.

    PubMed

    Davies, D R; Rawlinson, N; Iaffaldano, G; Campbell, I H

    2015-09-24

    Hotspots are anomalous regions of volcanism at Earth's surface that show no obvious association with tectonic plate boundaries. Classic examples include the Hawaiian-Emperor chain and the Yellowstone-Snake River Plain province. The majority are believed to form as Earth's tectonic plates move over long-lived mantle plumes: buoyant upwellings that bring hot material from Earth's deep mantle to its surface. It has long been recognized that lithospheric thickness limits the rise height of plumes and, thereby, their minimum melting pressure. It should, therefore, have a controlling influence on the geochemistry of plume-related magmas, although unambiguous evidence of this has, so far, been lacking. Here we integrate observational constraints from surface geology, geochronology, plate-motion reconstructions, geochemistry and seismology to ascertain plume melting depths beneath Earth's longest continental hotspot track, a 2,000-kilometre-long track in eastern Australia that displays a record of volcanic activity between 33 and 9 million years ago, which we call the Cosgrove track. Our analyses highlight a strong correlation between lithospheric thickness and magma composition along this track, with: (1) standard basaltic compositions in regions where lithospheric thickness is less than 110 kilometres; (2) volcanic gaps in regions where lithospheric thickness exceeds 150 kilometres; and (3) low-volume, leucitite-bearing volcanism in regions of intermediate lithospheric thickness. Trace-element concentrations from samples along this track support the notion that these compositional variations result from different degrees of partial melting, which is controlled by the thickness of overlying lithosphere. Our results place the first observational constraints on the sub-continental melting depth of mantle plumes and provide direct evidence that lithospheric thickness has a dominant influence on the volume and chemical composition of plume-derived magmas. PMID:26367795

  13. Lithospheric Controls on Magma Composition along Earth's Longest Continental Hotspot-Track

    NASA Astrophysics Data System (ADS)

    Rawlinson, N.; Davies, R.; Iaffaldano, G.; Campbell, I. H.

    2015-12-01

    Hotspots are anomalous regions of volcanism at Earth's surface that show no obvious association with tectonic plate boundaries. Classic examples include the Hawaiian-Emperor chain and the Yellowstone-Snake River Plain province. The majority are believed to form as Earth's tectonic plates move over long-lived mantle plumes: buoyant upwellings that bring hot material from Earth's deep-mantle to its surface. It has long been recognised that lithospheric thickness limits the rise height of plumes and, thereby, their minimum melting pressure. It should, therefore, have a controlling influence on the geochemistry of plume-related magmas, although unambiguous evidence of this has, thus far, been lacking. Here we integrate observational constraints from surface geology, geochronology, plate-motion reconstructions, geochemistry and seismology to ascertain plume melting depths beneath Earth's longest continental hotspot-track, a ~2000 km long track in eastern Australia that displays a record of volcanic activity between ~33 and ~9 Ma, which we call the Cosgrove track. Our analyses highlight a strong correlation between lithospheric thickness and magma composition along this track, with: (i) standard basaltic compositions in regions where lithospheric thickness is less than ~110 km; (ii) volcanic gaps in regions where lithospheric thickness exceeds ~150 km; and (iii) low-volume, leucitite-bearing volcanism in regions of intermediate lithospheric thickness. Trace-element concentrations from samples along this track support the notion that these compositional variations result from different degrees of partial-melting, which is controlled by the thickness of overlying lithosphere. Our results place the first observational constraints on the subcontinental melting depth of mantle plumes and provide direct evidence that lithospheric thickness has a dominant influence on the volume and chemical composition of plume-derived magmas.

  14. Source component mixing in the regions of arc magma generation

    NASA Astrophysics Data System (ADS)

    Arculus, Richard J.; Powell, Roger

    1986-05-01

    Most recent workers attribute the main features of island arc basalt geochemistry to variable contributions of at least two source components. The major source appears to be the peridotitic wedge of upper mantle overlying the subducted slab, but the nature of the second component and the processes by which the sources become mixed during genesis of arc magmas are in dispute. A metasomatic addition to the wedge resulting from devolatilization in the slab is the simplest explanation of the marked enrichment of the alkali and alkaline earth elements with respect to the rare earths in island arc basalts, together with the variably developed trends in Pb, Sr, and Nd isotopic data toward sedimentary contaminants. However, lack of the correlations between relative degrees of trace element fractionation and radiogenic isotopic ratios expected of such processes requires a more complex explanation. Alternative models that suggest that all of the characteristics of island arc basalts can be accounted for by melting of an intraoceanic, hot spot type of mantle source also face specific difficulties, particularly with regard to the strong depletions of trace high-field-strength elements in arc compared with hot spot magmas. A possible resolution of these specific geochemical difficulties may lie in dynamic transport processes within the wedge linked with the slab through coupled drag, and the marked depression of mantle isotherms in subduction zones. Inefficient escape of melts and subsequent repeated freezing within the overturning wedge can lead to local mineralogic and geochemical heterogeneity of the peridotite overlying the slab. Fluids released from the slab may infiltrate the heterogeneous wedge and preferentially scavenge the alkalis and alkaline earths with respect to the rare earths and high field strength elements from locally enriched portions of the wedge. Incorporation of such metasomatic fluids in renewed melting at shallower but hotter levels within the wedge can

  15. Forecasting the failure of heterogeneous magmas

    NASA Astrophysics Data System (ADS)

    Vasseur, J.; Wadsworth, F. B.; Lavallée, Y.; Bell, A. F.; Main, I. G.; Dingwell, D. B.

    2015-12-01

    Eruption prediction is a long-sought-after goal of volcanology. Yet applying existing techniques retrospectively (hindcasting), we fail to predict events more often than we success. As much of the seismicity associated with intermediate to silicic volcanic eruptions comes from the brittle response of the ascending magma itself, we clearly require a good understanding of the parameters that control the ability to forecast magma failure itself. Here, we present suites of controlled experiments at magmatic temperatures using a range of synthetic magmas to investigate the control of microstructures on the efficacy of forecast models for material failure. We find that the failure of magmas with very little microstructural heterogeneity - such as melts - is very challenging to predict; whereas, the failure of very heterogeneous magmas is always well-predicted. To shed further light on this issue, we provide a scaling law based on the relationship between the microstructural heterogeneity in a magma and the error in the prediction of its failure time. We propose this method be used to elucidate the variable success rate of predicting volcanic predictions. We discuss this scaling in the context of the birth, life and death of structural heterogeneity during magma ascent with specific emphasis on obsidian-forming eruptions such as Chaitèn, 2008. During such eruptions, the repetitive creation and destruction of fractures filled with granular magma, which are thought to be the in situ remnants of seismogenic fracturing itself, are expressions of the life-cycle of heterogeneity in an otherwise coherent, melt-rich magma. We conclude that the next generation of failure forecast tools available to monitoring teams should incorporate some acknowledgment of the magma microstructure and not be solely based on the geophysical signals prior to eruption.

  16. Magma chamber dynamics and Vesuvius eruption forecasting

    NASA Astrophysics Data System (ADS)

    Dobran, F.

    2003-04-01

    Magma is continuously or periodically refilling an active volcano and its eruption depends on the mechanical, fluid, thermal, and chemical aspects of the magma storage region and its surroundings. A cyclically loaded and unloaded system can fail from a weakness in the system or its surroundings, and the fluctuating stresses can produce system failures at stress levels that are considerably below the yield strength of the material. Magma in a fractured rock system within a volcano is unstable and propagates toward the surface with the rate depending on the state of the system defined by the inertia, gravity, friction, and permeability parameters of magma and its source region. Cyclic loading and unloading of magma from a reservoir caused by small- or medium-scale eruptions of Vesuvius can produce catastrophic plinian eruptions because of the structural failure of the system and the quiescent periods between these eruptions increase with time until the next eruption cycle which will be plinian or subplinian and will occur with a very high probability this century. Such a system behavior is predicted by a Global Volcanic Simulator of Vesuvius developed for simulating different eruption scenarios for the purpose of urban planning the territory, reducing the number of people residing too close to the cone of the volcano, and providing safety to those beyond about 5 km radius of the crater. The magma chamber model of the simulator employs a thermomechanical model that includes magma inflow and outflow from the chamber, heat and mass transfer between the chamber and its surroundings, and thermoelastoplastic deformation of the shell surrounding the magma source region. These magma chamber, magma ascent, and pyroclastic dispersion models and Vesuvius eruption forecasting are described in Dobran, F., VOLCANIC PROCESSES, Kluwer Academic/Plenum Publishers, 2001, 590 pp.

  17. Geochemistry of alkali syenites from the Budun massif and their petrogenetic properties (Ol'khon Island)

    NASA Astrophysics Data System (ADS)

    Makrygina, V. A.; Suvorova, L. F.; Zarubina, O. V.; Bryanskii, N. V.

    2016-07-01

    The first data on the geochemistry of the alkali syenite massif in Cape Budun of Ol'khon Island, where it makes contact in the south with the Khuzir gabbroid massif, are presented. Syenites occur among granite gneisses of the Sharanur dome and, like its granites, are enriched with Zr and REEs, but depleted in other trace elements. They contain anorthoclase, corundum, rare nepheline, zircon, and hercynite and are accompanied by desilicified pegmatites. Their unusual geochemical properties allow the assumption that alkaline magmas resulted from the interaction between basic and granitoid melts.

  18. Hyperextension, micro-continents, magma-poor and magma-rich segments in the pre-Caledonian margin of Baltica: research in progress

    NASA Astrophysics Data System (ADS)

    Andersen, Torgeir B.; Jakob, Johannes; Jørgen Kjøll, Hans; Corfu, Fernando; Tegner, Christian; Alsaif, Manar; Enger, Ander S.; Kjeldberg, Øystein

    2016-04-01

    The more than 2400 km long pre-Caledonian passive margin of Baltica evolved into a highly complex geological province, formed by magma-poor and magma-rich rifting and extreme crustal attenuation in the late Neoproterozoic (Ediacaran) and the Cambrian. Transition from continental rifting and extension to oceanic spreading was probably related to emplacement of a ~610-590 Ma Large Igneous Province (LIP) dominated by basalt magmatism. The LIP geochemistry and aspects of the dyke-swarm emplacement and geometries will be discussed further in other presentations at this meeting (see abstracts by Chr. Tegner et al. and HJ. Kjøll et al.). The magma-rich domain presently constitutes a more than 800km long segment in central Scandinavia. This segment shows transitions into a magma-poor domain in south-central Norway and possibly also in the north (see abstracts by J.Jakob et al.1 & 2 and F. Corfu & TB. Andersen). The magma-poor southern segment is dominated by large crystalline nappe complexes (NC) of Proterozoic continental crust with Baltican affinity, comprising both lower- to upper crustal units in the Jotun, Lindås and Bergsdalen NCs, respectively. These NCs are underlain and partly inter-finger with the melange matrix dominated by deep marine metasediments. The melange also contains numerous exhumed solitary mantle-peridotite, ophicarbonates and smaller slivers of Proterozoic gneisses of Baltican age affinity, as well as local coarser-grained meta-sediments including conglomerates and monomict detrital serpentinites. Some of these large crystalline nappes probably constituted structural highs of continental slivers or even micro-continents separated by hyperextended to immature oceanic (?) basins along the ancient margin of Baltica. The youngest basin sediments in the melange(s) are of Lower-Middle Ordovician age, as demonstrated by fossils and minimum ages of clastic zircons. Further details, including age and metamorphism as well as stable isotope signature of

  19. Eruption Depths, Magma Storage and Magma Degassing at Sumisu Caldera, Izu-Bonin Arc: Evidence from Glasses and Melt Inclusions

    NASA Astrophysics Data System (ADS)

    Johnson, E. R.

    2015-12-01

    Island arc volcanoes can become submarine during cataclysmal caldera collapse. The passage of a volcanic vent from atmospheric to under water environment involves complex modifications of the eruption style and subsequent transport of the pyroclasts. Here, we use FTIR measurements of the volatile contents of glass and melt inclusions in the juvenile pumice clasts in the Sumisu basin and its surroundings (Izu-Bonin arc) to investigate changes in eruption depths, magma storage and degassing over time. This study is based on legacy cores from ODP 126, where numerous unconsolidated (<65 ka), extremely thick (few m to >250 m), massive to normally graded pumice lapilli-tuffs were recovered over four cores (788C, 790A, 790B and 791A). Glass and clast geochemistry indicate the submarine Sumisu caldera as the source of several of these pumice lapilli-tuffs. Glass chips and melt inclusions from these samples were analyzed using FTIR for H2O and CO2 contents. Glass chips record variable H2O contents; most chips contain 0.6-1.6 wt% H2O, corresponding to eruption depths of 320-2100 mbsl. Variations in glass H2O and pressure estimates suggest that edifice collapse occurred prior-to or during eruption of the oldest of these samples, and that the edifice may have subsequently grown over time. Sanidine-hosted melt inclusions from two units record variably degassed but H2O-rich melts (1.1-5.6 wt% H2O). The lowest H2O contents overlap with glass chips, consistent with degassing and crystallization of melts until eruption, and the highest H2O contents suggest that large amounts of degassing accompanied likely explosive eruptions. Most inclusions, from both units, contain 2-4 wt% H2O, which further indicates that the magmas crystallized at pressures of ~50-100 MPa, or depths ~400-2800 m below the seafloor. Further glass and melt inclusion analyses, including major element compositions, will elucidate changes in magma storage, degassing and evolution over time.

  20. Timing magma ascent at Popocatepetl Volcano, Mexico, 2000-2001

    NASA Astrophysics Data System (ADS)

    Martin-Del Pozzo, A. L.; Cifuentes, G.; Cabral-Cano, E.; Bonifaz, R.; Correa, F.; Mendiola, I. F.

    2003-07-01

    Magnetic anomalies may be used to constrain magma ascent and are useful as precursors to eruptions especially when correlated with other geophysical and geochemical data. In this paper we present multiparameter data on the magnetics, dome morphology, geochemistry and seismicity associated with the December 2000-January 2001 eruptions, the largest of the recent eruptions at Popocatepetl Volcano. A 6-month data period was studied in order to evaluate the precursors and post-eruption processes. Several cycles of dome construction and destruction occurred from September 2000 through February 2001. In December, large amplitude tremor associated with a higher effusion rate resulted in the formation of a large dome which filled the crater to within about 50 m of the lowest part of the crater rim. Seismic activity in December was marked by many volcanotectonic earthquakes and both high frequency and harmonic tremor. On December 12 and 13, an increase in the tremor amplitude was followed by ash eruptions with 1.7-5-km-high columns. Tremor amplitude increased again on December 15 and oscillated for the next four days. Activity remained high until the end of the month. On January 22, an 18-km-high plume produced ash and pumice fall to the east as well as pyroclastic flows and mudflows which reached 6 km from the crater. The eruption left three concentric explosion pits, partially destroying the December dome. Mixing of a mafic olivine-bearing melt with a more evolved magma triggered the larger eruption on January 22 as can be seen from the higher MgO concentrations in some of the ejecta and the presence of a dark andesitic scoria with lower silica content and a white andesitic pumice with higher silica content. Precursory negative magnetic anomalies up to 5 nT (-3.2 nT, -5 nT, -2.9 nT) were associated with the ascent of the larger batches of magma which preceded the increases in seismicity, before the December 2000-January 22 VEI 3-4 eruptions. No significant increases in

  1. Tomography & Geochemistry: Precision, Repeatability, Accuracy and Joint Interpretations

    NASA Astrophysics Data System (ADS)

    Foulger, G. R.; Panza, G. F.; Artemieva, I. M.; Bastow, I. D.; Cammarano, F.; Doglioni, C.; Evans, J. R.; Hamilton, W. B.; Julian, B. R.; Lustrino, M.; Thybo, H.; Yanovskaya, T. B.

    2015-12-01

    Seismic tomography can reveal the spatial seismic structure of the mantle, but has little ability to constrain composition, phase or temperature. In contrast, petrology and geochemistry can give insights into mantle composition, but have severely limited spatial control on magma sources. For these reasons, results from these three disciplines are often interpreted jointly. Nevertheless, the limitations of each method are often underestimated, and underlying assumptions de-emphasized. Examples of the limitations of seismic tomography include its ability to image in detail the three-dimensional structure of the mantle or to determine with certainty the strengths of anomalies. Despite this, published seismic anomaly strengths are often unjustifiably translated directly into physical parameters. Tomography yields seismological parameters such as wave speed and attenuation, not geological or thermal parameters. Much of the mantle is poorly sampled by seismic waves, and resolution- and error-assessment methods do not express the true uncertainties. These and other problems have become highlighted in recent years as a result of multiple tomography experiments performed by different research groups, in areas of particular interest e.g., Yellowstone. The repeatability of the results is often poorer than the calculated resolutions. The ability of geochemistry and petrology to identify magma sources and locations is typically overestimated. These methods have little ability to determine source depths. Models that assign geochemical signatures to specific layers in the mantle, including the transition zone, the lower mantle, and the core-mantle boundary, are based on speculative models that cannot be verified and for which viable, less-astonishing alternatives are available. Our knowledge is poor of the size, distribution and location of protoliths, and of metasomatism of magma sources, the nature of the partial-melting and melt-extraction process, the mixing of disparate

  2. Time to Solidify an Ocean of Magma

    NASA Astrophysics Data System (ADS)

    Taylor, G. J.

    2009-03-01

    Cosmochemists are reasonably sure that a global ocean of magma surrounded the Moon when it formed. This was a monumentally important event in lunar history, forming the primary feldspar-rich crust of the lunar highlands and setting the stage for subsequent melting inside the Moon to make additional crustal rocks. Numerous questions remain about the complex array of processes that could have operated in such a huge amount of magma, and about how long it took to solidify the magma ocean. Alex Nemchin and colleagues at Curtin University of Technology (Australia), Westfailische Wilhelms-Universitat (Munster, Germany), and the Johnson Space Center (Houston, Texas, USA) dated a half-millimeter grain of the mineral zircon (ZrSiO4) in an impact melt breccia from the Apollo 17 landing site. They used an ion microprobe to measure the concentrations of lead and uranium isotopes in the crystal, finding that one portion of the grain recorded an age of 4.417 ± 0.006 billion years. Because zircon does not crystallize until more than 95% of the magma ocean has crystallized, this age effectively marks the end of magma ocean crystallization. Magma ocean cooling and crystallization began soon after the Moon-forming giant impact. Other isotopic studies show that this monumental event occurred 4.517 billion years ago. Thus, the difference between the two ages means that the magma ocean took 100 million years to solidify.

  3. Medical geochemistry of tropical environments

    NASA Astrophysics Data System (ADS)

    Dissanayake, C. B.; Chandrajith, Rohana

    1999-10-01

    Geochemically, tropical environments are unique. This uniqueness stems from the fact that these terrains are continuously subjected to extreme rainfall and drought with resulting strong geochemical fractionation of elements. This characteristic geochemical partitioning results in either severe depletion of elements or accumulation to toxic levels. In both these situations, the effect on plant, animal and human health is marked. Medical geochemistry involves the study of the relationships between the geochemistry of the environment in which we live and the health of the population living in this particular domain. Interestingly, the relationships between geochemistry and health are most marked in the tropical countries, which coincidentally are among the poorest in the world. The very heavy dependence on the immediate environment for sustainable living in these lands enables the medical geochemist to observe correlations between particular geochemical provinces and the incidence of certain diseases unique to these terrains. The aetiology of diseases such as dental and skeletal fluorosis, iodine deficiency disorders, diseases of humans and animals caused by mineral imbalances among others, lie clearly in the geochemical environment. The study of the chemistry of the soils, water and stream sediments in relation to the incidence of geographically distributed diseases in the tropics has not only opened up new frontiers in multidisciplinary research, but has offered new challenges to the medical profession to seriously focus attention on the emerging field of medical geochemistry with the collaboration of geochemists and epidemiologists.

  4. A model to forecast magma chamber rupture

    NASA Astrophysics Data System (ADS)

    Browning, John; Drymoni, Kyriaki; Gudmundsson, Agust

    2016-04-01

    An understanding of the amount of magma available to supply any given eruption is useful for determining the potential eruption magnitude and duration. Geodetic measurements and inversion techniques are often used to constrain volume changes within magma chambers, as well as constrain location and depth, but such models are incapable of calculating total magma storage. For example, during the 2012 unrest period at Santorini volcano, approximately 0.021 km3 of new magma entered a shallow chamber residing at around 4 km below the surface. This type of event is not unusual, and is in fact a necessary condition for the formation of a long-lived shallow chamber. The period of unrest ended without culminating in eruption, i.e the amount of magma which entered the chamber was insufficient to break the chamber and force magma further towards the surface. Using continuum-mechanics and fracture-mechanics principles, we present a model to calculate the amount of magma contained at shallow depth beneath active volcanoes. Here we discuss our model in the context of Santorini volcano, Greece. We demonstrate through structural analysis of dykes exposed within the Santorini caldera, previously published data on the volume of recent eruptions, and geodetic measurements of the 2011-2012 unrest period, that the measured 0.02% increase in volume of Santorini's shallow magma chamber was associated with magmatic excess pressure increase of around 1.1 MPa. This excess pressure was high enough to bring the chamber roof close to rupture and dyke injection. For volcanoes with known typical extrusion and intrusion (dyke) volumes, the new methodology presented here makes it possible to forecast the conditions for magma-chamber failure and dyke injection at any geodetically well-monitored volcano.

  5. Magma Beneath Yellowstone National park.

    PubMed

    Eaton, G P; Christiansen, R L; Iyer, H M; Pitt, A D; Mabey, D R; Blank, H R; Zietz, I; Gettings, M E

    1975-05-23

    The Yellowstone plateau volcanic field is less than 2 million years old, lies in a region of intense tectonic and hydrothermal activity, and probably has the potential for further volcanic activity. The youngest of three volcanic cycles in the field climaxed 600,000 years ago with a voluminous ashflow eruption and the collapse of two contiguous cauldron blocks. Doming 150,000 years ago, followed by voluminous rhyolitic extrusions as recently as 70,000 years ago, and high convective heat flow at present indicate that the latest phase of volcanism may represent a new magmatic insurgence. These observations, coupled with (i) localized postglacial arcuate faulting beyond the northeast margin of the Yellowstone caldera, (ii) a major gravity low with steep bounding gradients and an amplitude regionally atypical for the elevation of the plateau, (iii) an aeromagnetic low reflecting extensive hydrothermal alteration and possibly indicating the presence of shallow material above its Curie temperature, (iv) only minor shallow seismicity within the caldera (in contrast to a high level of activity in some areas immediately outside), (v) attenuation and change of character of seismic waves crossing the caldera area, and (vi) a strong azimuthal pattern of teleseismic P-wave delays, strongly suggest that a body composed at least partly of magma underlies the region of the rhyolite plateau, including the Tertiary volcanics immediately to its northeast. The Yellowstone field represents the active end of a system of similar volcanic foci that has migrated progressively northeastward for 15 million years along the trace of the eastern Snake River Plain (8). Regional aeromagnetic patterns suggest that this course was guided by the structure of the Precambrian basement. If, as suggested by several investigators (24), the Yellowstone magma body marks a contemporary deep mantle plume, this plume, in its motion relative to the North American plate, would appear to be "navigating" along a

  6. Volatiles Which Increase Magma Viscosity

    NASA Astrophysics Data System (ADS)

    Webb, S.

    2015-12-01

    The standard model of an erupting volcano is one in which the viscosity of a decompressing magma increases as the volatiles leave the melt structure to form bubbles. It has now been observed that the addition of the "volatiles" P, Cl and F result in an increase in silicate melt viscosity. This observation would mean that the viscosity of selected degassing magmas would decrease rather than increase. Here we look at P, Cl and F as three volatiles which increase viscosity through different structural mechanisms. In all three cases the volatiles increase the viscosity of peralkaline composition melts, but appear to always decrease the viscosity of peraluminous melts. Phosphorus causes the melt to unmix into a Na-P rich phase and a Na-poor silicate phase. Thus as the network modifying Na (or Ca) are removed to the phosphorus-rich melt, the matrix melt viscosity increases. With increasing amounts of added phosphorus (at network modifying Na ~ P) the addition of further phosphorus causes a decrease in viscosity. The addition of chlorine to Fe-free aluminosilicate melts results in an increase in viscosity. NMR data on these glass indicates that the chlorine sits in salt-like structures surrounded by Na and/or Ca. Such structures would remove network-modifying atoms from the melt structure and thus result in an increase in viscosity. The NMR spectra of fluorine-bearing glasses shows that F takes up at least 5 different structural positions in peralkaline composition melts. Three of these positions should result in a decrease in viscosity due to the removal of bridging oxygens. Two of the structural positons of F, however, should result in an increase in viscosity as they require the removal of network-modifying atoms from the melt structure (with one of the structures being that observed for Cl). This would imply that increasing amounts of F might result in an increase in viscosity. This proposed increase in viscosity with increasing F has now been experimentally confirmed.

  7. Magma Beneath Yellowstone National park.

    PubMed

    Eaton, G P; Christiansen, R L; Iyer, H M; Pitt, A D; Mabey, D R; Blank, H R; Zietz, I; Gettings, M E

    1975-05-23

    The Yellowstone plateau volcanic field is less than 2 million years old, lies in a region of intense tectonic and hydrothermal activity, and probably has the potential for further volcanic activity. The youngest of three volcanic cycles in the field climaxed 600,000 years ago with a voluminous ashflow eruption and the collapse of two contiguous cauldron blocks. Doming 150,000 years ago, followed by voluminous rhyolitic extrusions as recently as 70,000 years ago, and high convective heat flow at present indicate that the latest phase of volcanism may represent a new magmatic insurgence. These observations, coupled with (i) localized postglacial arcuate faulting beyond the northeast margin of the Yellowstone caldera, (ii) a major gravity low with steep bounding gradients and an amplitude regionally atypical for the elevation of the plateau, (iii) an aeromagnetic low reflecting extensive hydrothermal alteration and possibly indicating the presence of shallow material above its Curie temperature, (iv) only minor shallow seismicity within the caldera (in contrast to a high level of activity in some areas immediately outside), (v) attenuation and change of character of seismic waves crossing the caldera area, and (vi) a strong azimuthal pattern of teleseismic P-wave delays, strongly suggest that a body composed at least partly of magma underlies the region of the rhyolite plateau, including the Tertiary volcanics immediately to its northeast. The Yellowstone field represents the active end of a system of similar volcanic foci that has migrated progressively northeastward for 15 million years along the trace of the eastern Snake River Plain (8). Regional aeromagnetic patterns suggest that this course was guided by the structure of the Precambrian basement. If, as suggested by several investigators (24), the Yellowstone magma body marks a contemporary deep mantle plume, this plume, in its motion relative to the North American plate, would appear to be "navigating" along a

  8. Magma beneath Yellowstone National Park

    USGS Publications Warehouse

    Eaton, G.P.; Christiansen, R.L.; Iyer, H.M.; Pitt, A.M.; Mabey, D.R.; Blank, H.R.; Zietz, I.; Gettings, M.E.

    1975-01-01

    The Yellowstone plateau volcanic field is less than 2 million years old, lies in a region of intense tectonic and hydrothermal activity, and probably has the potential for further volcanic activity. The youngest of three volcanic cycles in the field climaxed 600,000 years ago with a voluminous ashflow eruption and the collapse of two contiguous cauldron blocks. Doming 150,000 years ago, followed by voluminous rhyolitic extrusions as recently as 70,000 years ago, and high convective heat flow at present indicate that the latest phase of volcanism may represent a new magmatic insurgence. These observations, coupled with (i) localized postglacial arcuate faulting beyond the northeast margin of the Yellowstone caldera, (ii) a major gravity low with steep bounding gradients and an amplitude regionally atypical for the elevation of the plateau, (iii) an aeromagnetic low reflecting extensive hydrothermal alteration and possibly indicating the presence of shallow material above its Curie temperature, (iv) only minor shallow seismicity within the caldera (in contrast to a high level of activity in some areas immediately outside), (v) attenuation and change of character of seismic waves crossing the caldera area, and (vi) a strong azimuthal pattern of teleseismic P-wave delays, strongly suggest that a body composed at least partly of magma underlies the region of the rhyolite plateau, including the Tertiary volcanics immediately to its northeast. The Yellowstone field represents the active end of a system of similar volcanic foci that has migrated progressively northeastward for 15 million years along the trace of the eastern Snake River Plain (8). Regional aeromagnetic patterns suggest that this course was guided by the structure of the Precambrian basement. If, as suggested by several investigators (24), the Yellowstone magma body marks a contemporary deep mantle plume, this plume, in its motion relative to the North American plate, would appear to be "navigating" along a

  9. Energy extraction from crustal magma bodies

    SciTech Connect

    Dunn, J.C.

    1982-01-01

    An open heat exchanger system for extracting thermal energy directly from shallow crustal magma bodies is described. The concept relies on natural properties of magma to create a permeable, solidified region surrounding a borehole drilled into the magma chamber. The region is fractured, possessing large surface area, and is sealed from the overburden. Energy is extracted by circulating a fluid through the system. Thermal stress analysis shows that such a fractured region can be developed at depths up to 10 km. An open heat exchanger experiment conducted in the partial melt zone of Kilauea Iki lava lake demonstrated the validity of this concept. Effective heat transfer surface area an order of magnitude greater than the borehole area was established during a two-day test period. The open heat exchanger concept greatly extends the number of magma systems that can be economically developed to produce energy.

  10. Status of the Magma Energy Project

    SciTech Connect

    Dunn, J.C.

    1987-01-01

    The current magma energy project is assessing the engineering feasibility of extracting thermal energy directly from crustal magma bodies. The estimated size of the US resource (50,000 to 500,000 quads) suggests a considerable potential impact on future power generation. In a previous seven-year study, we concluded that there are no insurmountable barriers that would invalidate the magma energy concept. Several concepts for drilling, energy extraction, and materials survivability were successfully demonstrated in Kilauea Iki lava lake, Hawaii. The present program is addressing the engineering design problems associated with accessing magma bodies and extracting thermal energy for power generation. The normal stages for development of a geothermal resource are being investigated: exploration, drilling and completions, production, and surface power plant design. Current status of the engineering program and future plans are described. 20 refs., 12 figs.

  11. Thermal stress fracturing of magma simulant materials

    SciTech Connect

    Wemple, R.P.; Longcope, D.B.

    1986-10-01

    Direct contact heat exchanger concepts for the extraction of energy from magma chambers are being studied as part of the DOE-funded Magma Energy Research Program at Sandia National Laboratories. These concepts require the solidification of molten material by a coolant circulated through a borehole drilled into the magma and subsequent fracture of the solid either as a natural consequence of thermal stress or by deliberate design (intentional flaws, high pressure, etc.). This report summarizes the results of several thermal stress fracturing experiments performed in the laboratory and compares the results with an analysis developed for use as a predictive tool. Information gained from this test series has been the basis for additional work now under way to simulate magma melt solidification processes.

  12. Process for forming hydrogen and other fuels utilizing magma

    DOEpatents

    Galt, John K.; Gerlach, Terrence M.; Modreski, Peter J.; Northrup, Jr., Clyde J. M.

    1978-01-01

    The disclosure relates to a method for extracting hydrogen from magma and water by injecting water from above the earth's surface into a pocket of magma and extracting hydrogen produced by the water-magma reaction from the vicinity of the magma.

  13. Magma Chambers, Thermal Energy, and the Unsuccessful Search for a Magma Chamber Thermostat

    NASA Astrophysics Data System (ADS)

    Glazner, A. F.

    2015-12-01

    Although the traditional concept that plutons are the frozen corpses of huge, highly liquid magma chambers ("big red blobs") is losing favor, the related notion that magma bodies can spend long periods of time (~106years) in a mushy, highly crystalline state is widely accepted. However, analysis of the thermal balance of magmatic systems indicates that it is difficult to maintain a significant portion in a simmering, mushy state, whether or not the system is eutectic-like. Magma bodies cool primarily by loss of heat to the Earth's surface. The balance between cooling via energy loss to the surface and heating via magma accretion can be denoted as M = ρLa/q, where ρ is magma density, L is latent heat of crystallization, a is the vertical rate of magma accretion, and q is surface heat flux. If M>1, then magma accretion outpaces cooling and a magma chamber forms. For reasonable values of ρ, L, and q, the rate of accretion amust be > ~15 mm/yr to form a persistent volume above the solidus. This rate is extremely high, an order of magnitude faster than estimated pluton-filling rates, and would produce a body 10 km thick in 700 ka, an order of magnitude faster than geochronology indicates. Regardless of the rate of magma supply, the proportion of crystals in the system must vary dramatically with depth at any given time owing to transfer of heat. Mechanical stirring (e.g., by convection) could serve to homogenize crystal content in a magma body, but this is unachievable in crystal-rich, locked-up magma. Without convection the lower part of the magma body becomes much hotter than the top—a process familiar to anyone who has scorched a pot of oatmeal. Thermal models that succeed in producing persistent, large bodies of magma rely on scenarios that are unrealistic (e.g., omitting heat loss to the planet's surface), self-fulfilling prophecies (e.g., setting unnaturally high temperatures as fixed boundary conditions), or physically unreasonable (e.g., magma is intruded

  14. Progressive enrichment of arc magmas caused by the subduction of seamounts under Nishinoshima volcano, Izu-Bonin Arc, Japan

    NASA Astrophysics Data System (ADS)

    Sano, Takashi; Shirao, Motomaro; Tani, Kenichiro; Tsutsumi, Yukiyasu; Kiyokawa, Shoichi; Fujii, Toshitsugu

    2016-06-01

    The chemical composition of intraplate seamounts is distinct from normal seafloor material, meaning that the subduction of seamounts at a convergent margin can cause a change in the chemistry of the mantle wedge and associated arc magmas. Nishinoshima, a volcanic island in the Izu-Bonin Arc of Japan, has been erupting continuously over the past 2 years, providing an ideal opportunity to examine the effect of seamount subduction on the chemistry of arc magmas. Our research is based on the whole-rock geochemistry and the chemistry of minerals within lavas and air-fall scoria from Nishinoshima that were erupted before 1702, in 1973-1974, and in 2014. The mineral phases within the analyzed samples crystallized under hydrous conditions (H2O = 3-4 wt.%) at temperatures of 970 °C-990 °C in a shallow (3-6 km depth) magma chamber. Trace element data indicate that the recently erupted Nishinoshima volcanics are much less depleted in the high field strength elements (Nb, Ta, Zr, Hf) than other volcanics within the Izu-Bonin Arc. In addition, the level of enrichment in the Nishinoshima magmas has increased in recent years, probably due to the addition of material from HIMU-enriched (i.e., high Nb/Zr and Ta/Hf) seamounts on the Pacific Plate, which is being subducted westwards beneath the Philippine Sea Plate. This suggests that the chemistry of scoria from Nishinoshima volcano records the progressive addition of components derived from subducted seamounts.

  15. Linking enclave formation to magma rheology

    NASA Astrophysics Data System (ADS)

    Hodge, K. F.; Jellinek, A. M.

    2012-10-01

    Magmatic enclaves record the history of deformation and disaggregation (i.e., fragmentation) of relatively hot, compositionally more mafic magmas injected into actively convecting silicic magma chambers through dikes. Enclave size distributions may provide crucial clues for understanding the nature of this mechanical mixing process. Accordingly, we conduct a comprehensive field study to measure enclave size distributions in six Cascade lava flows. Using results from recent fluid dynamics experiments along with thermodynamic and modeling constraints on key physical properties of the injected and host magmas (i.e., temperature, density and effective viscosity), we use the size distributions of enclaves to characterize the magmatic flow regime governing enclave formation. Scaling arguments suggest that the viscous stresses related to magma chamber flow acting against the yield strength of a crystallizing injected magma control the breakup of 1 m-wide mafic dikes into millimeter- to centimeter-scale enclaves. Our data analysis identifies a characteristic length scale of breakup that constrains the yield strength of the injected magmas in a more restrictive way than existing empirical models for yield strength based on crystal content. In all six lava flows, we show that the progressive fragmentation of the injected magma is self-similar and characterized by a fractal dimensionDf ˜ 2, which is comparable to previous studies on enclaves. We also find a small but statistically significant dependence of Df on the effective viscosity ratio between host and enclave magmas, such that large variations in effective viscosity enhance breakup. This work demonstrates that field observations of enclave size distributions can reliably constrain the rheological and flow conditions in which enclaves form.

  16. Basaltic injections into floored silicic magma chambers

    NASA Astrophysics Data System (ADS)

    Wiebe, R. A.

    Recent studies have provided compelling evidence that many large accumulations of silicic volcanic rocks erupted from long-lasting, floored chambers of silicic magma that were repeatedly injected by basaltic magma. These basaltic infusions are commonly thought to play an important role in the evolution of the silicic systems: they have been proposed as a cause for explosive silicic eruptions [Sparks and Sigurdsson, 1977], compositional variation in ash-flow sheets [Smith, 1979], mafic magmatic inclusions in silicic volcanic rocks [Bacon, 1986], and mixing of mafic and silicic magmas [Anderson, 1976; Eichelberger, 1978]. If, as seems likely, floored silicic magma chambers have frequently been invaded by basalt, then plutonic bodies should provide records of these events. Although plutonic evidence for mixing and commingling of mafic and silicic magmas has been recognized for many years, it has been established only recently that some intrusive complex originated through multiple basaltic injections into floored chambers of silicic magma [e.g., Wiebe, 1974; Michael, 1991; Chapman and Rhodes, 1992].

  17. Final report - Magma Energy Research Project

    SciTech Connect

    Colp, J.L.

    1982-10-01

    Scientific feasibility was demonstrated for the concept of magma energy extraction. The US magma resource is estimated at 50,000 to 500,000 quads of energy - a 700- to 7000-yr supply at the current US total energy use rate of 75 quads per year. Existing geophysical exploration systems are believed capable of locating and defining magma bodies and were demonstrated over a known shallow buried molten-rock body. Drilling rigs that can drill to the depths required to tap magma are currently available and experimental boreholes were drilled well into buried molten rock at temperatures up to 1100/sup 0/C. Engineering materials compatible with the buried magma environment are available and their performances were demonstrated in analog laboratory experiments. Studies show that energy can be extracted at attractive rates from magma resources in all petrologic compositions and physical configurations. Downhole heat extraction equipment was designed, built, and demonstrated successfully in buried molten rock and in the very hot margins surrounding it. Two methods of generating gaseous fuels in the high-temperature magmatic environment - generation of H/sub 2/ by the interaction of water with the ferrous iron and H/sub 2/, CH/sub 4/, and CO generation by the conversion of water-biomass mixtures - have been investigated and show promise.

  18. Are the Clast Lithologies Contained in Lunar Breccia 64435 Mixtures of Anorthositic Magmas

    NASA Technical Reports Server (NTRS)

    Simon, J. I.; Mittlefehldt, D. W.; Peng, Z. X.; Nyquist, L. E.; Shih, C.-Y.; Yamaguchi, A.

    2015-01-01

    The anorthositic crust of the Moon is often used as the archtypical example of a primary planetary crust. The abundance and purity of anorthosite in the Apollo sample collection and remote sensing data are generally attributed to an early global magma ocean which produced widespread floating plagioclase cumulates (the ferroan anorthosites; FANs. Recent geochronology studies report evidence of young (less than 4.4 Ga) FAN ages, which suggest that either some may not be directly produced from the magma ocean or that the final solidification age of the magma ocean was younger than previous estimates. A greater diversity of anorthositic rocks have been identified among lunar meteorites as compared to returned lunar samples. Granted that these lithologies are often based on small clasts in lunar breccias and therefore may not represent their actual whole rock composition. Nevertheless, as suggested by the abundance of anorthositic clasts with Mg# [Mg/(Mg+Fe)] less than 0.80 and the difficulty of producing the extremely high plagioclase contents observed in Apollo samples and the remote sensing data, modification of the standard Lunar Magma Ocean (LMO) model may be in order. To ground truth mission science and to further test the LMO and other hypotheses for the formation of the lunar crust, additional coordinated petrology and geochronology studies of lunar anorthosites would be informative. Here we report new mineral chemistry and trace element geochemistry studies of thick sections of a composite of FAN-suite igneous clasts contained in the lunar breccia 64435 in order to assess the significance of this type of sample for petrogenetic studies of the Moon. This work follows recent isotopic studies of the lithologies in 64435 focusing on the same sample materials and expands on previous petrology studies who identified three lithologies in this sample and worked on thin sections.

  19. Petrogenesis of the Late Triassic volcanic rocks in the Southern Yidun arc, SW China: Constraints from the geochronology, geochemistry, and Sr-Nd-Pb-Hf isotopes

    NASA Astrophysics Data System (ADS)

    Leng, Cheng-Biao; Huang, Qiu-Yue; Zhang, Xing-Chun; Wang, Shou-Xu; Zhong, Hong; Hu, Rui-Zhong; Bi, Xian-Wu; Zhu, Jing-Jing; Wang, Xin-Song

    2014-03-01

    Studies on zircon ages, petrology, major and trace element geochemistry, and Sr-Nd-Hf-Pb isotopic geochemistry of intermediate volcanic rocks from the Southern Yidun arc, Sanjiang-Tethyan Orogenic Belt, SW China have been undertaken in this paper. They are used to discuss the petrogenesis of these rocks and to constrain the tectonic setting and evolution of the Yidun arc. These intermediate volcanic rocks were erupted at ca. 220 Ma (U-Pb zircon ages). Trachyandesite is the dominant lithology among these volcanic rocks, and is mainly composed of hornblende and plagioclase, with minor clinopyroxene and biotite. A hornblende geobarometer suggests that the stagnation of magma in the lower crust, where plagioclase crystallization was suppressed while hornblende crystallized, giving rise to high Sr/Y ratios that are one of the distinguishing features of adakites, after the primary magma originated from the lithospheric mantle wedge. Steeply right-inclined Rare Earth Element (REE) pattern combined with high La/Yb ratios suggests adakitic affinity of these volcanic rocks, implying that slab-melt from the subducting oceanic crust is a necessary component in the primary magma. Besides, trace element geochemistry and isotopic geochemistry also indicate that partial melting of pelagic sediments in the subduction zone and noticeable contamination with the lower crust were involved in the evolution of parental magma of these volcanic rocks. Based on previous work on the Northern Yidun arc and this study, we propose that the subduction was initiated in the Northern Yidun arc and extended to the southern part and that the Northern Yidun arc is an island arc while the Southern Yidun arc represents a continental arc, probably caused by the existence of the Zhongza Massif, that was invoked to be derived from Yangtze Block, as a possible basement of the Southern Yidun arc.

  20. Volcanology and Geochemistry of the Taney Seamounts northeast Pacific Ocean

    NASA Astrophysics Data System (ADS)

    Coumans, J. P.; Clague, D. A.; Stix, J.

    2011-12-01

    The Taney seamounts are a NW-SE trending, linear, near-ridge chain consisting of five submarine volcanoes located on the Pacific plate 300 km west of San Francisco, California. Morphologically, the seamounts are characterized as truncated cones with nested calderas decreasing in age towards the ridge axis. This study examines the volcanology and geochemistry of the largest and oldest seamount, (Taney A, ~26 Ma), which is comprised of four well-exposed nested calderas. Each successive collapse event exposes previously infilled lavas, defining a relative chronology. The caldera walls and intracaldera pillow mounds were carefully sampled by the remotely operated vehicle (ROV) Doc Ricketts to obtain stratigraphically-controlled samples. Whole rock samples were analyzed for major and trace elements, volcanic glasses were analyzed for major and volatile elements(S, Cl), and plagioclase phenocrysts were separated for mineral and glass inclusion microprobe analysis. Overall, the erupted lavas are mostly subalkalic mid-ocean ridge basalts (MORB) varying from differentiated to more primitive (6.0 - 8.2 wt. % MgO) with decreasing age. Incompatible elements and REE profiles normalized to primitive mantle suggest that the lavas are transitional to slightly enriched (0.1 - 0.3 wt. % K2O; 1.1 - 2.2 wt. % TiO2), which is unusual for near-ridge seamounts. Sc, which is compatible in clinopyroxene, increases linearly with TiO2 at primitive compositions (>7.0 wt. % MgO). In more evolved seamount basalts (<7.0 wt. % MgO), the low CaO and Sc contents and decreasing CaO/Al2O3 suggest that there is either extensive clinopyroxene fractionation, or mixing with magmas that have undergone extensive clinopyroxene fractionation. MELTS modeling suggests that clinopyroxene fractionation occurs at <6.0 wt. % MgO, inconsistent with the observed clinopyroxene imprint at <7.0 wt. % MgO. The discrepancy could indicate magma mixing. Although whole rock ICP-MS data have some scatter, especially for

  1. Physical constraints of the evolution of felsic magma chambers: implications for the evolution of granite magmas

    NASA Astrophysics Data System (ADS)

    Bea, F.

    2012-04-01

    Igneous petrologist working on mafic magmas generally agree that magmas are stored and frac-tionated in crustal reservoirs called magma chambers. The current fashion among granite petrologist, on the other hand, is to minimize the importance of such reservoirs assuming that the huge granite bodies found in many crustal segments grew incrementally, due to the sequential addition of small magma batches. This idea is mostly based on the existence of cryptic contacts and isotope heterogenities inside a single pluton. However, these features can be as well explained by the crystallization dynamics of a viscous magma filling a km sized magma chamber, which is additionally consistent with field evidence. Magma chambers are transient structures that change by loosing and replenishment of magma and volatiles, that but also evolve as a whole due to the crystallization dynamics induced by cooling. The evolution of a given magma chamber depends on the ratios between (1) the rates of magma extraction/replenishment and (2) heat loss. To understand the complexity of magma chamber evolution, here we studied the evolution of an isolated magma chamber (no extraction/replenishment) during cooling, by coupling an internally consistent rheological dataset with the laws of fluids dynamics and heat transfer. Without regional stress, the evolution of the magma is dominated by top-down convection due to negative density gradient in the upper part of the body caused by crystallization. If the melt density is so low that permits fast melt-crystal segregation, the above-described mechanism is inhibited, and melt diapirs formed in the lower crystallizing zone can detach and ascend through the magma chamber producing so differentiation. Convective heat-loss leads most of the magma chamber to critical crystallinity in a few thousands years, which stops all magmatic dynamics except residual melt extraction due either to gravity-driven compaction, which produces short-range differentiation series

  2. Hydroxyl speciation in felsic magmas

    NASA Astrophysics Data System (ADS)

    Malfait, Wim J.; Xue, Xianyu

    2014-09-01

    The hydroxyl speciation of hydrous, metaluminous potassium and calcium aluminosilicate glasses was investigated by 27Al-1H cross polarization and quantitative 1H MAS NMR spectroscopy. Al-OH is present in both the potassium and the calcium aluminosilicate glasses and its 1H NMR partial spectrum was derived from the 27Al-1H cross polarization data. For the calcium aluminosilicate glasses, the abundance of Al-OH could not be determined because of the low spectral resolution. For the potassium aluminosilicate glasses, the fraction of Al-OH was quantified by fitting its partial spectrum to the quantitative 1H NMR spectra. The degree of aluminum avoidance and the relative tendency for Si-O-Si, Si-O-Al and Al-O-Al bonds to hydrolyze were derived from the measured species abundances. Compared to the sodium, lithium and calcium systems, potassium aluminosilicate glasses display a much stronger degree of aluminum avoidance and a stronger tendency for the Al-O-Al linkages to hydrolyze. Combining our results with those for sodium aluminosilicate glasses (Malfait and Xue, 2010a), we predict that the hydroxyl groups in rhyolitic and phonolitic magmas are predominantly present as Si-OH (84-89% and 68-78%, respectively), but with a significant fraction of Al-OH (11-16% and 22-32%, respectively). For both rhyolitic and phonolitic melts, the AlOH/(AlOH + SiOH) ratio is likely smaller than the Al/(Al + Si) ratio for the lower end of the natural temperature range but may approach the Al/(Al + Si) ratio at higher temperatures.

  3. Rethinking early Earth phosphorus geochemistry

    PubMed Central

    Pasek, Matthew A.

    2008-01-01

    Phosphorus is a key biologic element, and a prebiotic pathway leading to its incorporation into biomolecules has been difficult to ascertain. Most potentially prebiotic phosphorylation reactions have relied on orthophosphate as the source of phosphorus. It is suggested here that the geochemistry of phosphorus on the early Earth was instead controlled by reduced oxidation state phosphorus compounds such as phosphite (HPO32−), which are more soluble and reactive than orthophosphates. This reduced oxidation state phosphorus originated from extraterrestrial material that fell during the heavy bombardment period or was produced during impacts, and persisted in the mildly reducing atmosphere. This alternate view of early Earth phosphorus geochemistry provides an unexplored route to the formation of pertinent prebiotic phosphorus compounds, suggests a facile reaction pathway to condensed phosphates, and is consistent with the biochemical usage of reduced oxidation state phosphorus compounds in life today. Possible studies are suggested that may detect reduced oxidation state phosphorus compounds in ancient Archean rocks. PMID:18195373

  4. Magma movements and Iceland's next eruptions (Invited)

    NASA Astrophysics Data System (ADS)

    Sigmundsson, F.; Ofeigsson, B.; Hreinsdottir, S.; Hensch, M.; Gudmundsson, G.; Vogfjord, K. S.; Roberts, M. J.; Geirsson, H.; La Femina, P. C.; Hooper, A. J.; Sturkell, E. C.; Einarsson, P.; Gudmundsson, M. T.; Brandsdottir, B.; Loughlin, S. C.; Team, F.

    2013-12-01

    Iceland, created by hotspot-ridge interaction, is characterized by higher magmatic input and more complicated plate boundary structure than other parts of the Mid-Atlantic rift system. It has 30+ volcanic systems, where 20 confirmed eruptions have occurred in the last 40 years, the most recent at Eyjafjallajökull in 2010 and Grimsvotn in 2011. Likely candidates for the next eruption include the four most active volcanoes in Iceland (Hekla, Katla, Grimsvotn, and Bardarbunga) and other areas of volcanic unrest (Askja region, the Krisuvik area). Present volcano monitoring and research, including the FUTUREVOLC project, aims at providing warnings of impending eruptions and their character. Earthquake monitoring and deformation studies have hereto provided the most relevant information. Hekla continuously accumulates magma at a rate of about 0.003-0.02 km3/yr, according to GPS and InSAR studies, in a magma chamber placed below 14 km depth. A sequence of M0.4-1 earthquakes early this year stands out from otherwise mostly aseismic character of Hekla during repose periods. The Hekla magma chamber does not fail at a constant amount of magma volume, rather a clear pattern is observed with eruption size scaling with the length of the preceding period of dormancy. The ice capped Katla volcano shows unusual annual deformation pattern, seismic activity, and hydrological variations depending on time of year, presumably related to ice load and water pressure variations. It may be in a critical stage and renewed inflow of magma may quickly move the volcano towards failure. Bardarbunga had major earthquake and magma transfer activity in 1996, and has been the site of deep low-frequency earthquakes. Grímsvötn volcano is the only volcano with a shallow magma chamber with ongoing confirmed recharging, and failure criteria closest to 'expected'. A large eruption occurred in 2011 compared to much smaller eruption in 2004. However, the amount of erupted magma did not scale with the

  5. Convective Regimes in Crystallizing Basaltic Magma Chambers

    NASA Astrophysics Data System (ADS)

    Gilbert, A. J.; Neufeld, J. A.; Holness, M. B.

    2015-12-01

    Cooling through the chamber walls drives crystallisation in crustal magma chambers, resulting in a cumulate pile on the floor and mushy regions at the walls and roof. The liquid in many magma chambers, either the bulk magma or the interstitial liquid in the mushy regions, may convect, driven either thermally, due to cooling, or compositionally, due to fractional crystallization. We have constructed a regime diagram of the possible convective modes in a system containing a basal mushy layer. These modes depend on the large-scale buoyancy forcing characterised by a global Rayleigh number and the proportion of the chamber height constituting the basal mushy region. We have tested this regime diagram using an analogue experimental system composed of a fluid layer overlying a pile of almost neutrally buoyant inert particles. Convection in this system is driven thermally, simulating magma convection above and within a porous cumulate pile. We observe a range of possible convective regimes, enabling us to produce a regime diagram. In addition to modes characterised by convection of the bulk and interstitial fluid, we also observe a series of regimes where the crystal pile is mobilised by fluid motions. These regimes feature saltation and scouring of the crystal pile by convection in the bulk fluid at moderate Rayleigh numbers, and large crystal-rich fountains at high Rayleigh numbers. For even larger Rayleigh numbers the entire crystal pile is mobilised in what we call the snowglobe regime. The observed mobilisation regimes may be applicable to basaltic magma chambers. Plagioclase in basal cumulates crystallised from a dense magma may be a result of crystal mobilisation from a plagioclase-rich roof mush. Compositional convection within such a mush could result in disaggregation, enabling the buoyant plagioclase to be entrained in relatively dense descending liquid plumes and brought to the floor. The phenocryst load in porphyritic lavas is often interpreted as a

  6. Radiographic visualization of magma dynamics in an erupting volcano

    PubMed Central

    Tanaka, Hiroyuki K. M.; Kusagaya, Taro; Shinohara, Hiroshi

    2014-01-01

    Radiographic imaging of magma dynamics in a volcanic conduit provides detailed information about ascent and descent of magma, the magma flow rate, the conduit diameter and inflation and deflation of magma due to volatile expansion and release. Here we report the first radiographic observation of the ascent and descent of magma along a conduit utilizing atmospheric (cosmic ray) muons (muography) with dynamic radiographic imaging. Time sequential radiographic images show that the top of the magma column ascends right beneath the crater floor through which the eruption column was observed. In addition to the visualization of this magma inflation, we report a sequence of images that show magma descending. We further propose that the monitoring of temporal variations in the gas volume fraction of magma as well as its position in a conduit can be used to support existing eruption prediction procedures. PMID:24614612

  7. Radiographic visualization of magma dynamics in an erupting volcano.

    PubMed

    Tanaka, Hiroyuki K M; Kusagaya, Taro; Shinohara, Hiroshi

    2014-01-01

    Radiographic imaging of magma dynamics in a volcanic conduit provides detailed information about ascent and descent of magma, the magma flow rate, the conduit diameter and inflation and deflation of magma due to volatile expansion and release. Here we report the first radiographic observation of the ascent and descent of magma along a conduit utilizing atmospheric (cosmic ray) muons (muography) with dynamic radiographic imaging. Time sequential radiographic images show that the top of the magma column ascends right beneath the crater floor through which the eruption column was observed. In addition to the visualization of this magma inflation, we report a sequence of images that show magma descending. We further propose that the monitoring of temporal variations in the gas volume fraction of magma as well as its position in a conduit can be used to support existing eruption prediction procedures.

  8. Radiographic visualization of magma dynamics in an erupting volcano.

    PubMed

    Tanaka, Hiroyuki K M; Kusagaya, Taro; Shinohara, Hiroshi

    2014-01-01

    Radiographic imaging of magma dynamics in a volcanic conduit provides detailed information about ascent and descent of magma, the magma flow rate, the conduit diameter and inflation and deflation of magma due to volatile expansion and release. Here we report the first radiographic observation of the ascent and descent of magma along a conduit utilizing atmospheric (cosmic ray) muons (muography) with dynamic radiographic imaging. Time sequential radiographic images show that the top of the magma column ascends right beneath the crater floor through which the eruption column was observed. In addition to the visualization of this magma inflation, we report a sequence of images that show magma descending. We further propose that the monitoring of temporal variations in the gas volume fraction of magma as well as its position in a conduit can be used to support existing eruption prediction procedures. PMID:24614612

  9. Geochemistry and petrogenesis of the 595 Ma shoshonitic Qunai monzogabbro, Jordan

    NASA Astrophysics Data System (ADS)

    Ghanem, Hind; Jarrar, Ghaleb H.

    2013-12-01

    The last stage in the formation of the Arabian Nubian Shield in Jordan was dominated by post-orogenic igneous activity of the ˜610-542 Ma Araba Suite, including a monzogabbroic stock intruding the Saramuj Conglomerate, near the southeastern corner of the Dead Sea. The geological setting, petrography, geochemistry and geothermometry of the monzogabbro and other cogenetic varieties are used to shed light on the petrogenesis of this stock and reveal its magma source. The monzogabbro, megaporphyry dikes, and scattered syenite pockets are co-magmatic and alkaline, potassic and shoshonitic in nature. REE and trace elements patterns indicate that these magmas were produced from a mantle that had been modified by subduction-related metasomatism. The parental mafic magma could have been derived by 10% partial melting of LILE-enriched phlogopite-bearing spinel lherzolite, probably lithospheric mantle, in association with post-collisional extension. Fractional crystallization of this parental magma by olivine and pyroxene gave rise to the monzogabbroic magma. The megaporphyry dikes with their giant labradorite plagioclase megacrysts represent feeders of a voluminous volcanic activity that could have lasted for about 105 years. Thermodynamic modeling applying the MELTS software indicates crystallization of this suite in the temperature range of 1184-760 °C at a pressure of 2 kbars, agreeing with olivine-pyroxene, pyroxene, and two-feldspar thermometry. The modeled mineralogy and sequence of crystallization of constituent minerals using MELTS is in remarkable agreement with the observed modal mineralogy of the monzogabbro. Furthermore, a great degree of congruity exists between the modeled and observed chemistry of the major minerals with only minor discrepancies between modeled composition of biotite and olivine.

  10. Hydrothermal systems and volcano geochemistry

    USGS Publications Warehouse

    Fournier, R.O.

    2007-01-01

    The upward intrusion of magma from deeper to shallower levels beneath volcanoes obviously plays an important role in their surface deformation. This chapter will examine less obvious roles that hydrothermal processes might play in volcanic deformation. Emphasis will be placed on the effect that the transition from brittle to plastic behavior of rocks is likely to have on magma degassing and hydrothermal processes, and on the likely chemical variations in brine and gas compositions that occur as a result of movement of aqueous-rich fluids from plastic into brittle rock at different depths. To a great extent, the model of hydrothermal processes in sub-volcanic systems that is presented here is inferential, based in part on information obtained from deep drilling for geothermal resources, and in part on the study of ore deposits that are thought to have formed in volcanic and shallow plutonic environments.

  11. Crystallization kinetics in magmas during decompression

    NASA Astrophysics Data System (ADS)

    Arzilli, Fabio; Burton, Mike; Carroll, Michael R.

    2016-04-01

    Many variables play a role during magma crystallization at depth or in a volcanic conduit, and through experimentally derived constraints we can better understand pre- and syn-eruptive magma crystallization behavior. The thermodynamic properties of magmas have been extensively investigated as a function of T, P, fO2 and magma composition [1], and this allows estimation of the stability of equilibrium phases and physical parameters (e.g., density, viscosity). However, many natural igneous rocks contain geochemical, mineralogical and textural evidence of disequilibrium, suggesting that magmas frequently follow non-equilibrium, time-dependent pathways that are recorded in the geochemical and petrographic characteristics of the rocks. There are currently no suitable theoretical models capable of calculating nucleation and growth rates in disequilibrium conditions without experimental constraints. The aim of this contribution is provide quantitative data on growth and nucleation rates of feldspar crystals in silicate melts obtained through decompression experiments, in order to determine the magma evolution in pre- and sin-eruptive conditions. Decompression is one of the main processes that induce the crystallization of feldspar during the magma ascent in the volcanic conduit. Decompression experiments have been carried out on trachytic and basaltic melts to investigate crystallization kinetics of feldspar as a function of the effect of the degassing, undercooling and time on nucleation and crystal growth process [2; 3]. Furthermore, feldspar is the main crystals phase present in magmas, and its abundance can strongly vary with small changes in pressure, temperature and water content in the melt, implying appreciable variations in the textures and in the crystallization kinetics. Crystallization kinetics of trachytic melts show that long experiment durations involve more nucleation events of alkali feldspar than short experiment durations [2]. This is an important

  12. Magma mixing enhanced by bubble ascent

    NASA Astrophysics Data System (ADS)

    Wiesmaier, S.; Morgavi, D.; Perugini, D.; De Campos, C. P.; Hess, K.; Lavallee, Y.; Dingwell, D. B.

    2012-12-01

    Understanding the processes that affect the rate of liquid state homogenization provides fundamental clues on the otherwise inaccessible subsurface dynamics of magmatic plumbing systems. Compositional heterogeneities detected in the matrix of magmatic rocks represent the arrested state of a chemical equilibration. Magmatic homogenization has been divided into a) the mechanical interaction of magma batches (mingling) and b) the diffusive equilibration of compositional gradients, where diffusive equilibration is exponentially enhanced by progressive mechanical interaction [1]. The mechanical interaction between two distinct batches of magma has commonly been attributed to shear and folding movements between two liquids of distinct viscosities. A mode of mechanical interaction scarcely invoked is the advection of mafic material into a felsic one through bubble motion. Yet, experiments with analogue materials demonstrated that bubble ascent has the potential to enhance the fluid mechanical component of magma mixing [2]. Here, we present preliminary results from bubble-advection experiments. For the first time, experiments of this kind were performed using natural materials at magmatic temperatures. Cylinders of Snake River Plain (SRP) basalt were drilled with a cavity of defined volume and placed underneath cylinders of SRP rhyolite. Upon melting, the gas pocket, or bubble trapped within the cavity, rose into the rhyolite, so entraining a layer of basalt. Successive iterations of the same experiment at progressive intervals ensured a time series of magmatic interaction caused by bubble segregation. Variations in initial bubble size allowed the tracking of bubble volume to advected material ratio at defined viscosity contrast. The resulting plume-like structures that the advected basalt formed within the rhyolite were characterized by microCT and subsequent high-resolution EMP analyses. The mass of advected material per bubble correlated positively with bubble size. The

  13. Vesiculation of basaltic magma during eruption

    USGS Publications Warehouse

    Mangan, M.T.; Cashman, K.V.; Newman, S.

    1993-01-01

    Vesicle size distributions in vent lavas from the Pu'u "O'o-Kupaianaha eruption of Kilauea volcano are used to estimate nucleation and growth rates of H2O-rich gas bubbles in basaltic magma nearing the earth's surface (???120 m depth). By using well-constrained estimates for the depth of volatile exsolution and magma ascent rate, nucleation rates of 35.9 events.cm-3.s-1 and growth rates of 3.2 ?? 10-4cm/s are determined directly from size-distribution data. The results are consistent with diffusion-controlled growth as predicted by a parabolic growth law. -from Authors

  14. Evidence for the mixing of granitic and basaltic magmas in the Pleasant Bay layered intrusion, coastal Maine

    SciTech Connect

    Powers, P.M. . Geology Dept.)

    1993-03-01

    The Pleasant Bay layered intrusion has the shape of a shallow basin about 200 km[sup 2] in area and crops out along the coast of Maine between Bar Harbor and Machias. This intrusion evolved as repeated replenishments of basaltic magma were emplaced into a silicic magma chamber (Wiebe, in press). These replenishments surged into the chamber through fractures, spreading laterally on a floor of silicic cumulates and beneath silicic magma. This produced a sequence of layers (up to 100 m thick) that grade from chilled basalt at the base to gabbroic, dioritic, or granitic emulates at the top. This study focuses on two layers, each of which grades from chilled gabbro at the base to quartz syenite at the top. Petrography and geochemistry suggest that mechanical mixing and other interactions between two stably stratified magmas were responsible for much of this variation. Plagioclase grains typically have corroded calcic cores (An[sub 52--56]) that decrease in size upward and sodic rims (An[sub 32--36]) that thicken upward. Larger plagioclase grains at higher levels often have K-spar cores. Scarce large zircon, apatite, and biotite crystals in the lower parts of the layers are often corroded. The apatites have dark pleochroic halos, suggesting they crystallized from a liquid enriched in U and Th. The silicic melt was likely the source of K and H[sub 2]O needed to crystallize hornblende and biotite. The large corroded zircon, apatite, and biotite crystals, as well as much of the hornblende, probably grew at an interface between separately convecting silicic and basaltic magmas.

  15. Basalt Magma, Whisky and Tequila: finely-crafted mixes of small liquid batches that defy the parent liquid concept but whose complexities teach us much

    NASA Astrophysics Data System (ADS)

    Rubin, K. H.; Sinton, J. M.; Perfit, M. R.

    2015-12-01

    Basalt is the most ubiquitous magma type we know of in the solar system. It comes in various varieties manifested as compositional sub groups, erupts from a wide variety of volcanic systems and tectonic settings, and its eruptions span many order of magnitude in duration and volume. Igneous petrology, thermodynamics, geochemistry, and geodynamical modelling have been used to develop a sophisticated understanding of source lithologies, compositions and formation conditions (e.g., pressure and temperature) for parent melts and their subsequent transport, storage and evolution. These demonstrate some striking systematics as a function of volcano tectonic setting (on Earth). Yet much like Whisky, what makes it into the bottle, or the eruption, is a mixture of different liquids with unique characteristics, sometimes stirred so well that successive batches are indistinguishable, and sometimes stirred more incompletely, preserving small batch characters that are unique. Recently, geochemical and petrological studies in high spatial density within the products of individual eruptions have shown chemical and mineralogical evidence for incompletely mixed heterogeneous magmas in a majority of systems examined, begging the question of when, if ever, is it realistic to speak of a single parent magma composition, and even in cases where it apparently is, if these are instead just more thoroughly stirred multi-parent magmas. For instance, do monogenetic fields really erupt basalts of more varied parent melt compositions than large hot spot and flood basalt eruptions, or are they just more poorly stirred? This presentation will focus on work by ourselves and others constraining spatial and temporal single-eruption basaltic magma histories at different settings, using them to unravel the time and space scales of magma formation and mixing, how these translate to the assembly of an erupted basalt magma, and the implications for deducing things about and from presumed parents.

  16. Evolution and Consequences of Magma Ocean Solidifcation

    NASA Astrophysics Data System (ADS)

    Maurice, Maxime; Tosi, Nicola; Ana-Catalina, Plesa; Breuer, Doris

    2015-04-01

    The various and intense energy sources involved in the early stages of planetary formation, such as kinetic energy of accretion, decay of short-lived radiogenics, release of gravitational potential energy upon core formation, and tidal effects, are thought to have caused partial or possibly entire melting of the mantle of terrestrial planets and moons [Elkins-Tanton2012]. Global or local liquid magma oceans could thus have formed, whose solidification upon planetary cooling could have exerted a significant impact on the differentiation and subsequent evolution of the interior of terrestrial bodies. The solidification of such magma oceans likely proceeds from the bottom upwards because of the steeper slope of the mantle adiabat with respect to the slope of the solidus, and controls the initial compositional stratification of the solid mantle, which, in turn, can play an important role in shaping the earliest forms of mantle convection and surface tectonics. We investigate the thermal evolution of a whole-mantle magma ocean using the finite-volume code Gaia [Huettig2013]. We run two-dimensional simulations of magma ocean cooling and crystallization and investigate in particular the conditions for which the onset of solid-state thermal convection is possible before mantle solidification has completed. We assume an adiabatic temperature profile in the magma ocean and various cooling rates of the surface temperature according to coupled magma ocean-atmosphere models [Lebrun2013]. Upon reaching a critical melt fraction that marks the formation of the so-called rheological front, [Solomatov2007], we self-consistently solve with Gaia the conservation equations of solid-state mantle convection in the partially molten domain assuming a viscosity strongly dependent on temperature and melt content. By varying the reference Rayleigh number and the magma ocean cooling rate, we show that, even for a surface temperature decreasing very rapidly at a rate of 1000 K/Myr, a

  17. The redox state, FeO content, and origin of sulfur-rich magmas on Mercury

    NASA Astrophysics Data System (ADS)

    Zolotov, Mikhail Yu.; Sprague, Ann L.; Hauck, Steven A.; Nittler, Larry R.; Solomon, Sean C.; Weider, Shoshana Z.

    2013-01-01

    MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) orbital observations of Mercury have revealed elevated S abundances, Ca-S and Mg-S correlations, and a low upper limit for ferrous iron in surface silicates. These data indicate the presence of Ca and/or Mg sulfides in volcanic rocks and a low oxygen fugacity (fO2) in their parental magmas. We have evaluated coupled fO2 and fS2 values and FeO contents in Mercury's magmas from silicate-sulfide equilibria and empirical models for silicate melts and metallurgical slags. The evaluated fO2 at 1700-1800 K is 4.5 to 7.3 log10 units below the iron-wüstite buffer. These values correspond to 0.028-0.79 wt % FeO, implying that Fe must be also present in sulfides and metal and are also consistent with the composition of the partial melt of an enstatite chondrite. This derived upper limit for FeO is substantially lower than the limits obtained from reflectance measurements of Mercury's surface materials. The low fO2 and FeO values provide new constraints for igneous processes on Mercury as well as the formation, evolution, and internal structure of the innermost planet.

  18. Fractionation, ascent, and extrusion of magma at the Santiaguito volcanic dome, Guatemala

    NASA Astrophysics Data System (ADS)

    Scott, J.; Mather, T. A.; Pyle, D. M.

    2011-12-01

    The silicic dome complex of Santiaguito, Guatemala has exhibited continuous low-level activity for nearly 90 years[1]. Despite its longevity, remarkably little is known about the magmatic plumbing system beneath Santiaguito. We present preliminary constraints on this system, based on petrological analyses of lava samples. Amphibole thermobarometry suggests magma evolves during slow ascent through a phenocryst fractionation zone - a complex of dikes and sills, extending from at least ~24 km to at most ~12 km beneath Santiaguito. Discontinuous plagioclase size distributions suggest this slow fractionation ends at depth, and degassing-induced crystallization of microlites begins. The texture and geochemistry of microlites is consistent with uninterrupted final ascent; there is no evidence of shallow magma storage beneath Santiaguito. The normative composition of matrix glass, and the morphology and volume of plagioclase microlites suggests ascending magma crosses the rigidification threshold within <1 km of the surface. The term "rigidification" refers to the point at which crystallization ends, vesicles are preserved, and ductile behaviour is replaced by dominantly brittle behaviour, previously referred to as "final melt quench". We suggest rigidification slows the ascent of magma and may create the conduit plug previously observed at Santiaguito[2]. This rigid mass of magma may begin to fracture almost immediately to form a semi-permeable plug, before extruding onto the surface as blocky lava. The extrusion rate may be reflected in the extent of matrix glass decomposition to crystalline silica and alkali feldspar. This preliminary picture of the plumbing system beneath Santiaguito may lead to a greater understanding of the behaviour of this enigmatic volcano, and of the danger it poses to the region. However, our findings raise many further questions about the dynamics within silicic dome-forming systems that need to be addressed if we are to work towards a broad

  19. MORB differentiation: In situ crystallization in replenished-tapped magma chambers

    NASA Astrophysics Data System (ADS)

    Coogan, L. A.; O'Hara, M. J.

    2015-06-01

    The differentiation of mid-ocean ridge basalt (MORB) is investigated with a focus on intermediate- to fast-spreading ridges and two recently proposed differentiation mechanisms: (i) differentiation in replenished-tapped-crystallizing (RTX) magma chambers, and (ii) chromatographic element separation during melt-rock reaction in the lower crust. There is compelling evidence in the petrology and geochemistry of MORB indicating that magma chambers at mid-ocean ridges behave as open systems, as required on thermal grounds in locations where a steady-state magma chamber exists. It has recently been suggested that the commonly observed over-enrichment of more-to-less incompatible elements during MORB differentiation can be explained by such an RTX model. However, the petrology of samples from the lower oceanic crust suggests an alternative mechanism could produce this over-enrichment. Clinopyroxene crystals in oceanic gabbros are commonly strongly zoned in incompatible elements with crystal rims apparently having grown from melts with very high incompatible element abundances. Elevated Zr/LREE in clinopyroxene rims, which has been interpreted as indicating growth from a melt in which these elements had been fractionated from one another by melt-rock reaction (chromatographic separation), is shown to be more simply explained by post-crystallization diffusive fractionation. However, the high incompatible element abundances in crystal rims demonstrates that the interstitial melt in crystal mush zones becomes highly differentiated. Disaggregation of such mush zones is indicated by the crystal cargo of MORB and must be accompanied by the return of interstitial melt to the eruptible reservoir - a form of in situ crystallization. Both a magma chamber undergoing closed system in situ crystallization, and a RTX magma chamber in which crystallization occurs in situ, are shown to be capable of reproducing the differentiation trends observed in MORB. Simple stochastic models of the

  20. Frozen magma lenses below the oceanic crust.

    PubMed

    Nedimović, Mladen R; Carbotte, Suzanne M; Harding, Alistair J; Detrick, Robert S; Canales, J Pablo; Diebold, John B; Kent, Graham M; Tischer, Michael; Babcock, Jeffrey M

    2005-08-25

    The Earth's oceanic crust crystallizes from magmatic systems generated at mid-ocean ridges. Whereas a single magma body residing within the mid-crust is thought to be responsible for the generation of the upper oceanic crust, it remains unclear if the lower crust is formed from the same magma body, or if it mainly crystallizes from magma lenses located at the base of the crust. Thermal modelling, tomography, compliance and wide-angle seismic studies, supported by geological evidence, suggest the presence of gabbroic-melt accumulations within the Moho transition zone in the vicinity of fast- to intermediate-spreading centres. Until now, however, no reflection images have been obtained of such a structure within the Moho transition zone. Here we show images of groups of Moho transition zone reflection events that resulted from the analysis of approximately 1,500 km of multichannel seismic data collected across the intermediate-spreading-rate Juan de Fuca ridge. From our observations we suggest that gabbro lenses and melt accumulations embedded within dunite or residual mantle peridotite are the most probable cause for the observed reflectivity, thus providing support for the hypothesis that the crust is generated from multiple magma bodies. PMID:16121179

  1. Petrology and Physics of Magma Ocean Crystallization

    NASA Technical Reports Server (NTRS)

    Elkins-Tanton, Linda T.; Parmentier, E. M.; Hess, P. C.

    2003-01-01

    Early Mars is thought to have been melted significantly by the conversion of kinetic energy to heat during accretion of planetesimals. The processes of solidification of a magma ocean determine initial planetary compositional differentiation and the stability of the resulting mantle density profile. The stability and compositional heterogeneity of the mantle have significance for magmatic source regions, convective instability, and magnetic field generation. Significant progress on the dynamical problem of magma ocean crystallization has been made by a number of workers. The work done under the 2003 MFRP grant further explored the implications of early physical processes on compositional heterogeneity in Mars. Our goals were to connect early physical processes in Mars evolution with the present planet's most ancient observable characteristics, including the early, strong magnetic field, the crustal dichotomy, and the compositional characteristics of the SNC meteorite's source regions as well as their formation as isotopically distinct compositions early in Mars's evolution. We had already established a possible relationship between the major element compositions of SNC meteorite sources and processes of Martian magma ocean crystallization and overturn, and under this grant extended the analysis to the crucial trace element and isotopic SNC signatures. This study then demonstrated the ability to create and end the magnetic field through magma ocean cumulate overturn and subsequent cooling, as well as the feasibility of creating a compositionally- and volumetrically-consistent crustal dichotomy through mode-1 overturn and simultaneous adiabatic melting.

  2. Geology of magma systems: background and review

    SciTech Connect

    Peterfreund, A.R.

    1981-03-01

    A review of basic concepts and current models of igneous geology is presented. Emphasis is centered on studies of magma generation, ascent, emplacement, evolution, and surface or near-surface activity. An indexed reference list is also provided to facilitate future investigations.

  3. Unusual Iron Redox Systematics of Martian Magmas

    SciTech Connect

    Danielson, L.; Righter, K.; Pando, K.; Morris, R.V.; Graff, T.; Agresti, D.; Martin, A.; Sutton, S.; Newville, M.; Lanzirotti, A.

    2012-03-26

    Martian magmas are known to be FeO-rich and the dominant FeO-bearing mineral at many sites visited by the Mars Exploration rovers (MER) is magnetite. Morris et al. proposed that the magnetite appears to be igneous in origin, rather than of secondary origin. However, magnetite is not typically found in experimental studies of martian magmatic rocks. Magnetite stability in terrestrial magmas is well understood, as are the stabilities of FeO and Fe{sub 2}O{sub 3} in terrestrial magmas. In order to better understand the variation of FeO and Fe{sub 2}O{sub 3}, and the stability of magnetite (and other FeO-bearing phases) in martian magmas, we have undertaken an experimental study with two emphases. First, we determine the FeO and Fe{sub 2}O{sub 3} contents of super- and sub-liquidus glasses from a shergottite bulk composition at 1 bar to 4 GPa, and variable fO{sub 2}. Second, we document the stability of magnetite with temperature and fO{sub 2} in a shergottite bulk composition.

  4. Loki Patera: A Magma Sea Story

    NASA Technical Reports Server (NTRS)

    Veeder, G. J.; Matson, D. L.; Rathbun, A. G.

    2005-01-01

    We consider Loki Patera on Io as the surface expression of a large uniform body of magma. Our model of the Loki magma sea is some 200 km across; larger than a lake but smaller than an ocean. The depth of the magma sea is unknown, but assumed to be deep enough that bottom effects can be ignored. Edge effects at the shore line can be ignored to first order for most of the interior area. In particular, we take the dark material within Loki Patera as a thin solidified lava crust whose hydrostatic shape follows Io's isostatic surface (approx. 1815 km radius of curvature). The dark surface of Loki appears to be very smooth on both regional and local (subresolution) scales. The thermal contrast between the low and high albedo areas within Loki is consistent with the observed global correlation. The composition of the model magma sea is basaltic and saturated with dissolved SO2 at depth. Its average, almost isothermal, temperature is at the liquidus for basalt. Additional information is included in the original extended abstract.

  5. Unusual Iron Redox Systematics of Martian Magmas

    NASA Technical Reports Server (NTRS)

    Danielson, L.; Righter, K.; Pando, K.; Morris, R. V.; Graff, T.; Agresti, D.; Martin, A.; Sutton, S.; Newville, M.; Lanzirotti, A.

    2012-01-01

    Martian magmas are known to be FeO-rich and the dominant FeO-bearing mineral at many sites visited by the Mars Exploration rovers (MER) is magnetite. Morris et al. proposed that the magnetite appears to be igneous in origin, rather than of secondary origin. However, magnetite is not typically found in experimental studies of martian magmatic rocks. Magnetite stability in terrestrial magmas is well understood, as are the stabilities of FeO and Fe2O3 in terrestrial magmas. In order to better understand the variation of FeO and Fe2O3, and the stability of magnetite (and other FeO-bearing phases) in martian magmas, we have undertaken an experimental study with two emphases. First, we determine the FeO and Fe2O3 contents of super- and sub-liquidus glasses from a shergottite bulk composition at 1 bar to 4 GPa, and variable fO2. Second, we document the stability of magnetite with temperature and fO2 in a shergottite bulk composition.

  6. Iron Redox Systematics of Martian Magmas

    NASA Technical Reports Server (NTRS)

    Righter, K.; Danielson, L.; Martin, A.; Pando, K.; Sutton, S.; Newville, M.

    2011-01-01

    Martian magmas are known to be FeO-rich and the dominant FeO-bearing mineral at many sites visited by the Mars Exploration rovers (MER) is magnetite [1]. Morris et al. [1] propose that the magnetite appears to be igneous in origin, rather than of secondary origin. However, magnetite is not typically found in experimental studies of martian magmatic rocks [2,3]. Magnetite stability in terrestrial magmas is well understood, as are the stability of FeO and Fe2O3 in terrestrial magmas [4,5]. In order to better understand the variation of FeO and Fe2O3, and the stability of magnetite (and other FeO-bearing phases) in martian magmas we have undertaken an experimental study with two emphases. First we document the stability of magnetite with temperature and fO2 in a shergottite bulk composition. Second, we determine the FeO and Fe2O3 contents of the same shergottite bulk composition at 1 bar and variable fO2 at 1250 C, and at variable pressure. These two goals will help define not only magnetite stability, but pyroxene-melt equilibria that are also dependent upon fO2.

  7. Frozen magma lenses below the oceanic crust.

    PubMed

    Nedimović, Mladen R; Carbotte, Suzanne M; Harding, Alistair J; Detrick, Robert S; Canales, J Pablo; Diebold, John B; Kent, Graham M; Tischer, Michael; Babcock, Jeffrey M

    2005-08-25

    The Earth's oceanic crust crystallizes from magmatic systems generated at mid-ocean ridges. Whereas a single magma body residing within the mid-crust is thought to be responsible for the generation of the upper oceanic crust, it remains unclear if the lower crust is formed from the same magma body, or if it mainly crystallizes from magma lenses located at the base of the crust. Thermal modelling, tomography, compliance and wide-angle seismic studies, supported by geological evidence, suggest the presence of gabbroic-melt accumulations within the Moho transition zone in the vicinity of fast- to intermediate-spreading centres. Until now, however, no reflection images have been obtained of such a structure within the Moho transition zone. Here we show images of groups of Moho transition zone reflection events that resulted from the analysis of approximately 1,500 km of multichannel seismic data collected across the intermediate-spreading-rate Juan de Fuca ridge. From our observations we suggest that gabbro lenses and melt accumulations embedded within dunite or residual mantle peridotite are the most probable cause for the observed reflectivity, thus providing support for the hypothesis that the crust is generated from multiple magma bodies.

  8. Volcanology: Look up for magma insights

    USGS Publications Warehouse

    Segall, Paul; Anderson, Kyle

    2014-01-01

    Volcanic plumes can be hazardous to aircraft. A correlation between plume height and ground deformation during an eruption of Grímsvötn Volcano, Iceland, allows us to peer into the properties of the magma chamber and may improve eruption forecasts.

  9. Isotope Geochemistry Researches in China

    NASA Astrophysics Data System (ADS)

    Chen, James H.

    The publication of Isotope Geochemistry Researches in China represents a major milestone in such research in China. Every isotope geochemist will find at least one informative article in his or her own field of interest in this large and comprehensive volume.The book is divided into 27 chapters, written by 41 authors, and the scope, content, and quality of the chapters are variable. In general, each is a review or an overview of a topic in geochemistry. Some of the chapters are very short and provide only a very general overview. Others are long and provide a detailed and more comprehensive review of a specific subject. Most are translated into English and they are generally professionally done. The quality of the figures and tables varies, but most are clear and informative. An extensive, current bibliography (some in Chinese publications) is provided at the end of the book for each chapter, but there is no index.To help readers find the localities of the areas studied, a table is appended containing names in English and Chinese with latitude and longitude, but no map is included.

  10. Magma-poor and magma-rich segments along the hyperextended, pre-Caledonian passive margin of Baltica

    NASA Astrophysics Data System (ADS)

    Andersen, Torgeir B.; Alsaif, Manar; Corfu, Fernando; Jakob, Johannes; Planke, Sverre; Tegner, Christian

    2015-04-01

    The Scandinavian Caledonides constitute a more than 1850 km long 'Himalayan-type' orogen, formed by collision between Baltica-Avalonia and Laurentia. Subduction-related magmatism in the Iapetus ended at ~430 Ma and continental convergence continued for ~30 Myr until ~400 Ma. The collision produced a thick orogenic wedge comprising the stacked remnants of the rifted to hyperextended passive Baltican margin (Andersen et al. 2012), as well as suspect, composite and outboard terranes, which were successively emplaced as large-scale nappe complexes onto Baltica during the Scandian collision (see Corfu et al. 2014 for a recent review). Large parts (~800 km) of the mountain-belt in central Scandinavia, particularly in the Särv and Seve Nappes and their counterparts in Troms, are characterised by spectacular dyke complexes emplaced into continental sediments (e.g. Svenningsen 2001, Hollocher et al. 2007). These constitute a magma-rich segment formed along the margin of Baltica or within hyperextended continental slivers outboard of Baltica. The intensity of the pre-Caledonian magmatism is comparable to that of the present NE-Atlantic and other volcanic passive margins. The volumes and available U-Pb ages of 610-597 Ma (Baird et al. 2014 and refs therein) suggest that the magmatism was short lived, intense and therefore compatible with a large igneous province (LIP). By analogy with present-day margins this LIP may have been associated with continental break-up and onset of sea-floor spreading. The remnants of the passive margin both north and south of the magma-rich segment have different architectures, and are almost devoid of rift/drift related magmatic rocks. Instead, these magma-poor segments are dominated by heterogeneous sediment-filled basins characterised by the abundant presence of solitary bodies of variably altered mantle peridotites, also commonly present as detrital serpentinites. These basins are interpreted to have formed by hyperextension. We suggest that

  11. Magma Processes in Generating Basalts at the Poison Lake Chain, California

    NASA Astrophysics Data System (ADS)

    Wenner, J. M.; Teasdale, R.; Kroeninger, K. L.; Albanese, C.; Duhamel, N.

    2012-12-01

    We present new data for primitive basalts in the Poison Lake chain east of Lassen Volcanic National Park in northern California. The primitive composition and location of Poison Lake chain cinder cones on the western margin of the Basin and Range suggest that extensional tectonics may facilitate efficient magma ascent with little contamination. The Poison Lake chain is an ideal location to study small-scale variations in the mantle beneath the southern Cascades because of the small volumes erupted and the proximity to the Basin and Range. The volcanic field encompasses 39 units that comprise nine chemically distinct groups of primitive calc-alkaline basalts (defined by major element geochemistry and mineralogy). Olivine core compositions range from Fo72 - Fo89; most are in equilibrium with their whole rock compositions. Plagioclase core compositions range from An62-An88. Trace-element and isotope data for the groups confirm distinct chemistries that show little evidence of direct genetic relationships or a common source among these basalts. The small volume and distinct isotopic characteristics of individual groups suggest that they are the product of small mantle source domains. CaO compositions of olivine crystals further support that these basalts represent small independent magma batches. Isotope ratios, major and trace element compositions (whole rock) and crystal compositions reflect pre-eruption processing for some groups, which provide insights into the degree of pre-eruption processing versus the extent of source heterogeneities. Other groups have smaller compositional ranges (whole rock isotopes, trace, and major elements), more homogeneous olivine and plagioclase compositions, and reflect smaller degrees of processing prior to eruption. Compositional ranges within individual groups constrain the degree to which magmas were processed during transport from the mantle source to the surface in the Poison Lake chain.

  12. Direct Observation of Rhyolite Magma by Drilling: The Proposed Krafla Magma Drilling Project

    NASA Astrophysics Data System (ADS)

    Eichelberger, J. C.; Sigmundsson, F.; Papale, P.; Markusson, S.; Loughlin, S.

    2014-12-01

    Remarkably, drilling in Landsvirkjun Co.'s geothermal field in Krafla Caldera, Iceland has encountered rhyolite magma or hypersolidus rhyolite at 2.1-2.5 km depth in 3 wells distributed over 3.5 km2, including Iceland Deep Drilling Program's IDDP-1 (Mortensen, 2012). Krafla's most recent rifting and eruption (basalt) episode was 1975-1984; deformation since that time has been simple decay. Apparently rhyolite magma was either emplaced during that episode without itself erupting or quietly evolved in situ within 2-3 decades. Analysis of drill cuttings containing quenched melt from IDDP-1 yielded unprecedented petrologic data (Zierenberg et al, 2012). But interpreting active processes of heat and mass transfer requires knowing spatial variations in physical and chemical characteristics at the margin of the magma body, and that requires retrieving core - a not-inconceivable task. Core quenched in situ in melt up to 1150oC was recovered from Kilauea Iki lava lake, Hawaii by the Magma Energy Project >30 years ago. The site from which IDDP-1 was drilled, and perhaps IDDP-1 itself, may be available to attempt the first-ever coring of rhyolite magma, now proposed as the Krafla Magma Drilling Project (KMDP). KMDP would also include geophysical and geochemical experiments to measure the response of the magma/hydrothermal system to fluid injection and flow tests. Fundamental results will reveal the behavior of magma in the upper crust and coupling between magma and the hydrothermal system. Extreme, sustained thermal power output during flow tests of IDDP-1 suggests operation of a Kilauea-Iki-like freeze-fracture-flow boundary propagating into the magma and mining its latent heat of crystallization (Carrigan et al, EGU, 2014). Such an ultra-hot Enhanced Geothermal System (EGS) might be developable beneath this and other magma-heated conventional hydrothermal systems. Additionally, intra-caldera intrusions like Krafla's are believed to produce the unrest that is so troubling in

  13. Numerical simulation of magma energy extraction

    NASA Astrophysics Data System (ADS)

    Hickox, C. E.

    The Magma Energy Program is a speculative endeavor regarding practical utility of electrical power production from the thermal energy which resides in magma. The systematic investigation has identified a number of research areas which have application to the utilization of magma energy and to the field of geothermal energy. Eight topics were identified which involve thermal processes and which are areas for the application of the techniques of numerical simulation. These areas are (1) two-phase flow of the working fluid in the wellbore, (2) thermodynamic cycles for the production of electrical power, (3) optimization of the entire system, (4) solidification and fracturing of the magma caused by the energy extraction process, (5) heat transfer and fluid flow within an open, direct-contact, heat-exchanger, (6) thermal convection in the overlying geothermal region, (7) thermal convection within the magma body, and (8) induced natural convection near the thermal energy extraction device. Modeling issues have been identified which will require systematic investigation in order to develop the most appropriate strategies for numerical simulation. It appears that numerical simulations will be of ever increasing importance to the study of geothermal processes as the size and complexity of the systems of interest increase. It is anticipated that, in the future, greater emphasis will be placed on the numerical simulation of large-scale, three-dimensional, transient, mixed convection in viscous flows and porous media. Increased computational capabilities, e.g.; massively parallel computers, will allow for the detailed study of specific processes in fractured media, non-Darcy effects in porous media, and non-Newtonian effects.

  14. Io: Loki Patera as a Magma Sea

    NASA Technical Reports Server (NTRS)

    Matson, Dennis L.; Davies, Ashley Gerard; Veeder, Glenn J.; Rathbun, Julie A.; Johnson, Torrence V.; Castillo, Julie C.

    2006-01-01

    We develop a physical model for Loki Patera as a magma sea. We calculate the total volume of magma moving through the Loki Patera volcanic system every resurfacing cycle (approx.540 days) and the resulting variation in thermal emission. The rate of magma solidification at times reaches 3 x 10(exp 6) kg per second, with a total solidified volume averaging 100 cu km per year. A simulation of gas physical chemistry evolution yields the crust porosity profile and the timescale when it will become dense enough to founder in a manner consistent with observations. The Loki Patera surface temperature distribution shows that different areas are at different life cycle stages. On a regional scale, however, there can be coordinated activity, indicated by the wave of thermal change which progresses from Loki Patera's SW quadrant toward the NE at a rate of approx.1 km per day. Using the observed surface temperature distribution, we test several mechanisms for resurfacing Loki Patera, finding that resurfacing with lava flows is not realistic. Only the crustal foundering process is consistent with observations. These tests also discovered that sinking crust has a 'heat deficit' which promotes the solidification of additional magma onto the sinking plate ("bulking up"). In the limiting case, the mass of sinking material can increase to a mass of approx.3 times that of the foundering plate. With all this solid matter sinking, there is a compensating upward motion in the liquid magma. This can be in excess of 2 m per year. In this manner, solid-liquid convection is occurring in the sea.

  15. Surface deformation versus eruption rates of the two Eyjafjallajökull 2010 eruptions; implications for the magma plumbing system and origin of melts

    NASA Astrophysics Data System (ADS)

    Pedersen, R.; Sigmundsson, F.; Hreinsdottir, S.; Arnadottir, T.; Hoskuldsson, A.; Gudmundsson, M. T.; Magnusson, E.

    2010-12-01

    eruption rate. A pronounced peak in eruptive activity around May 5 is associated with a halt in volcano deflation and temporary renewed inflation. Finally, subsidence continued several weeks beyond the end of the eruption. Interpretations of the temporal and spatial variations of the observed deformation rates and associated eruption rates are not straightforward. When gathering information from several sources, e.g. geochemistry, seismicity, and geodesy, there is a strong indication that substantial magma replenishment of primitive melts originating at great depths occurred during the eruption. Other processes such as the evolved magma generation and extraction process as well as thermo-elastic responses in the sill intrusion region may need to be taken into account to better explain the relationship between volume changes inferred from geodetic data and estimates of the eruptive volume.

  16. Nature of Beypazari Granitoid: Geology and geochemistry, Northwest Anatolia, Turkey

    NASA Astrophysics Data System (ADS)

    Kadioğlu, Y. K.; Zoroğlu, O.

    2008-07-01

    metamorphic texture with clear metamorphic lineation, sharp contact with host rock and mostly observed at the northwest part of Kirbasi and Tahir region in the form of xenolithic enclaves. They have angular to sub-angular in shape. These types of the enclaves have hornfels in composition at the contact with the host rock as a product of contact metamorphism and amphibolites in composition at the core as a product of high temperature and middle pressure metamorphism. The textural features and mineral composition of the third type of the enclaves may indicate a fragment of metapelitic rocks, which caught by the granitoid magma in the form of xenolithic enclaves. Whole rock geochemistry reveals that Beypazari granitoids are subalkaline and calcalkaline in nature. They are enriched in Light-REE and LIL with respect to High-REE and HFS elements. Tectonic discrimination diagrams of Beypazari granitoid suggest a product of plate convergence and probably belong to Volcanic Arc Granitoid (VAG). The field observations, mineralogy, petrography with the whole geochemical data reveal that the Beypazari Granitoid magmas are derived from a subduction-modified magma and metasomatized mantle source with considerable crustal contribution.

  17. Deep magma transport at Kilauea volcano, Hawaii

    USGS Publications Warehouse

    Wright, T.L.; Klein, F.W.

    2006-01-01

    The shallow part of Kilauea's magma system is conceptually well-understood. Long-period and short-period (brittle-failure) earthquake swarms outline a near-vertical magma transport path beneath Kilauea's summit to 20 km depth. A gravity high centered above the magma transport path demonstrates that Kilauea's shallow magma system, established early in the volcano's history, has remained fixed in place. Low seismicity at 4-7 km outlines a storage region from which magma is supplied for eruptions and intrusions. Brittle-failure earthquake swarms shallower than 5 km beneath the rift zones accompany dike emplacement. Sparse earthquakes extend to a decollement at 10-12 km along which the south flank of Kilauea is sliding seaward. This zone below 5 km can sustain aseismic magma transport, consistent with recent tomographic studies. Long-period earthquake clusters deeper than 40 km occur parallel to and offshore of Kilauea's south coast, defining the deepest seismic response to magma transport from the Hawaiian hot spot. A path connecting the shallow and deep long-period earthquakes is defined by mainshock-aftershock locations of brittle-failure earthquakes unique to Kilauea whose hypocenters are deeper than 25 km with magnitudes from 4.4 to 5.2. Separation of deep and shallow long-period clusters occurs as the shallow plumbing moves with the volcanic edifice, while the deep plumbing is centered over the hotspot. Recent GPS data agrees with the volcano-propagation vector from Kauai to Maui, suggesting that Pacific plate motion, azimuth 293.5?? and rate of 7.4 cm/yr, has been constant over Kilauea's lifetime. However, volcano propagation on the island of Hawaii, azimuth 325??, rate 13 cm/yr, requires southwesterly migration of the locus of melting within the broad hotspot. Deep, long-period earthquakes lie west of the extrapolated position of Kilauea backward in time along a plate-motion vector, requiring southwesterly migration of Kilauea's magma source. Assumed ages of 0

  18. Outgassing of silicic magma through bubble and fracture networks (Invited)

    NASA Astrophysics Data System (ADS)

    Okumura, S.; Nakamura, M.; Uesugi, K.

    2013-12-01

    Outgassing of magma is a fundamental process that controls the style and explosivity of volcanic eruptions. Vesiculation during the ascent and decompression of magma results in the formation of bubble networks within the magma. The permeable gas escape through the bubble networks is an efficient way to induce the outgassing of silicic magma (Eichelberger et al., 1986). To understand magma ascent dynamics and predict the style and explosivity of eruptions, it is necessary to constrain the rate of magma outgassing as the magma ascends in a volcanic conduit. However, the gas permeability of natural samples should not be considered, because it reflects complicated processes involving vesiculation, deformation, outgassing, and compaction. Experimental studies have demonstrated that vesiculation and compaction processes show hysteresis behavior (Okumura et al., 2013). Thus, we have performed experiments to simulate magma decompression and the deformation of vesicular magmas (e.g., Okumura et al., 2009, 2012). A series of decompression and deformation experiments indicates that the gas permeability is less than the order of 10-15 m2 for isotropic vesiculation at vesicularity <60-80 vol%. When magma ascent is simulated with shear deformation, the gas permeability is much greater than that observed under isotropic conditions. Akin to bubble networks, permeable networks consisting of shear-induced brittle fractures are thought to be efficient outgassing pathways (Gonnermann and Manga, 2003). Our recent experiments demonstrated that fractured magma has a higher gas permeability than vesicular magma at least at vesicularities <~40 vol%. This indicates that fracture networks in magma become efficient parts for the outgassing. However, as shear fracturing results from high strain rates in highly viscous magma, outgassing via fracture networks can be enhanced in localized shear zones and shallow parts of the conduit. The permeable bubble and fracture networks are preferentially

  19. Differentiation mechanism of frontal-arc basalt magmas

    NASA Astrophysics Data System (ADS)

    Kuritani, T.; Yoshida, T.; Kimura, J.; Hirahara, Y.; Takahashi, T.

    2012-04-01

    In a cooling magma chamber, magmatic differentiation can proceed both by fractionation of crystals from the main molten part of the magma body (homogeneous fractionation) and by mixing of the main magma with fractionated melt derived from low-temperature mush zones (boundary layer fractionation) (Jaupart and Tait, 1995, and references therein). The geochemical path caused by boundary layer fractionation can be fairly different from a path resulting from homogeneous fractionation (e.g., Langmuir, 1989). Therefore, it is important to understand the relative contributions of these fractionation mechanisms in magma chambers. Kuritani (2009) examined the relative roles of the two fractionation mechanisms in cooling basaltic magma chambers using a thermodynamics-based mass balance model. However, the basaltic magmas examined in the work were alkali-rich (Na2O+K2O > 4 wt.%). In this study, to explore differentiation mechanisms of frontal-arc basalt magmas that are volumetrically much more important than rear-arc alkali basalt magmas, the relative roles of the two fractionation mechanisms are examined for low-K tholetiitic basalt magma from Iwate Volcano, NE Japan arc, using the same mass balance model. First, the water content and the temperature of the Iwate magma were estimated. The Iwate lavas are moderately porphyritic, consisting of ~8 vol.% olivine and ~20 vol.% plagioclase phenocrysts. The olivine and plagioclase phenocrysts show significant compositional variations, and the Mg# of olivine phenocrysts (Mg#78-81) correlates positively with the An content of coexisting plagioclase phenocrysts (An85-92). The olivine phenocrysts with Mg# > ~82 do not form crystal aggregates with plagioclase. It is inferred from these observations that the phenocrysts with variable compositions were derived from a common magma with variable temperature in a magma chamber, and the plagioclase phenocrysts were all derived from mushy boundary layers along the walls of the magma chamber. By

  20. Fractionation of a Basal Magma Ocean

    NASA Astrophysics Data System (ADS)

    Laneuville, M.; Hernlund, J. W.; Labrosse, S.

    2014-12-01

    Earth's magnetic field is thought to be sustained by dynamo action in a convecting metallic outer core since at least 3.45 Ga (Tarduno et al., 2010). Convection induces an isentropic temperature gradient that drains 13±3 TW of heat from the core by thermal conduction (de Koker et al., 2012; Pozzo et al., 2012; Gomi et al., 2013), and suggests that Earth's core has cooled by ˜1,000 K or more since Earth's formation (Gomi et al., 2013). However, models of Earth's initial thermal evolution following a giant-impact predict rapid cooling to the mantle melting temperature (e.g., Solomatov, 2007). In order to understand how the core could have retained enough heat to explain the age of the geodynamo, we relax a key assumption of the basal magma ocean model of (Labrosse et al., 2007) to allow for the possibility that the magma is stably stratified. Recent giant impact simulations suggest extensive core-mantle mixing (Saitoh and Makino, 2013), which could have produced such a large stratified magma layer at the core-mantle boundary. In the presence of a stable density gradient, heat transfer through the basal magma ocean occurs through conduction and therefore delays heat loss from the core. Partitioning of iron in the liquid phase upon crystallization changes the density profile and triggers convection in the upper part of the basal magma ocean. Our hypothesis suggests that early core cooling is dominated by the diffusion timescale through the basal magma ocean, and predicts a delayed onset of the geodynamo (i.e, during the late Headean/early Archean). This model can therefore be falsified if the existence of a geomagnetic field can be inferred from magnetization of inclusions in Hadean zircons. N. de Koker et al., Proc. Natl. Acad. Sci. 190, 4070-4073 (2012).H. Gomi et al., Phys. Earth Planet. Inter. 224, 88-103 (2013).S. Labrosse et al., Nature 450, 866-869 (2007).M. Pozzo et al., Nature 485, 355-358 (2012).T. Saitoh and J. Makino. Astrophys. J. 768, 44 (2013).V

  1. Geochemical investigation of a semi-continuous extrusive basaltic section from the Deccan Volcanic Province, India: implications for the mantle and magma chamber processes

    NASA Astrophysics Data System (ADS)

    Vijaya Kumar, Kopparapu; Chavan, Chakradhar; Sawant, Sariput; Naga Raju, K.; Kanakdande, Prachiti; Patode, Sangita; Deshpande, Krishna; Krishnamacharyulu, S. K. G.; Vaideswaran, T.; Balaram, V.

    2010-06-01

    Spatial and temporal variations in the geochemistry of an extrusive basaltic section of Deccan traps record progressive changes in mantle melting and crustal filtration and are relevant to understand continental flood basalt (CFB) magmatism. In the present work we have carried out detailed field, petrographic, density and magnetic susceptibility, and geochemical investigations on a small, semi-continuous extrusive section in the eastern Deccan Volcanic Province (DVP) to understand the role of shallow magma chambers in CFB magmatism. Four formations, Ajanta, Chikhli, Buldhana and Karanja crop out in the Gangakhed-Ambajogai area with increasing elevation. Our studies indicate that: (1) the Karanja Formation represents a major magma addition, as indicated by abrupt change in texture, increases in MgO, CaO, Ni, Cr, and Sr, and drastic decreases in Al2O3, Na2O, K2O, Rb, Ba, REE, bulk-rock density and magnetic susceptibility; (2) assimilation fractional crystallization, crystal-laden magmas, and accessory cumulus phases influence the trace element chemistry of Deccan basalts; (3) the predicted cumulate sequence of olivine gabbro-leucogabbro-oxide-apatite gabbro is supported by the observed layered series in a shallow magma chamber within the DVP; (4) the initial magma was saturated with olivine, plagioclase, and augite, and final the pressure of equilibration for the Gangakhed-Ambajogai section basalts is ~2 kbar (~6 km depth); (5) petrophysical parameters act as proxies for magmatic processes; (6) a small layer of oxide-rich basalts may represent the latest erupted pulse in a given magmatic cycle in the DVP; (7) parental basalts to some of the red boles, considered as formation boundaries, might represent small degree partial melts of the mantle; (8) SW Deccan basaltic-types continue into the eastern DVP; and (9) in addition to the magma chamber processes, dynamic melting of the mantle may have controlled DVP geochemistry. The present study underscores the importance of

  2. Magma oceanography. I - Thermal evolution. [of lunar surface

    NASA Technical Reports Server (NTRS)

    Solomon, S. C.; Longhi, J.

    1977-01-01

    Fractional crystallization and flotation of cumulate plagioclase in a cooling 'magma ocean' provides the simplest explanation for early emplacement of a thick feldspar-rich lunar crust. The complementary mafic cumulates resulting from the differentiation of such a magma ocean have been identified as the ultimate source of mare basalt liquids on the basis or rare-earth abundance patterns and experimental petrology studies. A study is conducted concerning the thermal evolution of the early differentiation processes. A range of models of increasing sophistication are considered. The models developed contain the essence of the energetics and the time scale for magma ocean differentiation. Attention is given to constraints on a magma ocean, modeling procedures, single-component magma oceans, fractionating magma oceans, and evolving magma oceans.

  3. The location and timing of magma degassing during Plinian eruptions

    NASA Astrophysics Data System (ADS)

    Giachetti, T.; Gonnermann, H. M.

    2014-12-01

    Water is the most abundant volatile species in explosively erupting silicic magmas and significantly affects magma viscosity, magma fragmentation and the dynamics of the eruption column. The effect that water has on these eruption processes can be modulated by outgassing degassing from a permeable magma. The magnitude, rate and timing of outgassing during magma ascent, in particular in relation to fragmentation, remains a subject of debate. Here we constrain how much, how fast and where the erupting magma lost its water during the 1060 CE Plinian phase of the Glass Mountain eruption of Medicine Lake Volcano, California. Using thermogravimetric analysis coupled with numerical modeling, we show that the magma lost >90% of its initial water upon eruption. Textural analyses of natural pumices, together with numerical modeling of magma ascent and degassing, indicate that 65-90% of the water exsolved before fragmentation, but very little was able to outgas before fragmentation. The magma attained permeability only within about 1 to 10 seconds before fragmenting and during that time interval permeable gas flow resulted in only a modest amount of gas flux from the un-fragmented magma. Instead, most of the water is lost shortly after fragmentation, because gas can escape rapidly from lapilli-size pyroclasts. This results in an efficient rarefaction of the gas-pyroclast mixture above the fragmentation level, indicating that the development of magma permeability and ensuing permeable outgassing are a necessary condition for sustain explosive eruptions of silicic magma. Magma permeability is thus a double-edged sword, it facilitates both, the effusive and the explosive eruption of silicic magma.

  4. Short-lived radioactivity and magma genesis

    NASA Astrophysics Data System (ADS)

    Gill, James; Condomines, Michel

    1992-09-01

    Short-lived decay products of uranium and thorium have half-lives and chemistries sensitive to the processes and time scales of magma genesis, including partial melting in the mantle and magmatic differentiation in the crust. Radioactive disequilibrium between U-238, Th-230, and Ra-226 is widespread in volcanic rocks. These disequilibria and the isotopic composition of thorium depend especially on the extent and rate of melting as well as the presence and composition of vapor during melting. The duration of mantle melting may be several hundred millennia, whereas ascent times are a few decades to thousands of years. Differentiation of most magmas commonly occurs within a few millennia, but felsic ones can be tens of millennia old upon eruption.

  5. Magma evolution at mount vulture (Southern Italy)

    NASA Astrophysics Data System (ADS)

    de Fino, M.; La Volpe, L.; Piccarreta, G.

    1982-06-01

    The Vulture complex is made up of foiditic, tephritic, phonolitic-trachytic and phonolitic products. New rock analyses have been performed in order to ascertain whether the various rock types derive from a unique parental magma and, if so, to define its nature. The data presented support that the Vulture suite originated from a foiditic melt which had differentiated at low pressures. The main process determining the foidite → → tephrite → phonolitic trachyte evolution seems to be the crystal fractionation of mainly clinopyroxenes, and opaques, with the contribution of plagioclases and haüyne too in the tephrite → trachyte evolution. Additionary role must have been played by a mixing of melts at different evolution stages occurred in a shallow seated magma chamber.

  6. Is magma cooling responsible for the periodic activity of Soufrière Hills volcano, Montserrat, West Indies?

    NASA Astrophysics Data System (ADS)

    Caricchi, Luca; Simpson, Guy; Chelle-Michou, Cyril; Neuberg, Jürgen

    2016-04-01

    in the period 2016-2018. Because cooling affects mainly the outer portions of the magmatic reservoir, pressurisation by cooling and crystallisation lead to the release of magma from the inner part of the reservoir with essentially constant composition, as observed at SHV over the last 20 years. REFERENCES Caricchi, L., Biggs, J., Annen, C., & Ebmeier, S. (2014). Earth and Planetary Science Letters, 388, 166-174. doi.org/10.1016/j.epsl.2013.12.002. Christopher, T. E., Blundy, J., Cashman, K., Cole, P., Edmonds, M., Smith, P. J., et al. (2015). Geochemistry Geophysics Geosystems, 16(9), 2797-2811. doi.org/10.1002/2015GC005791. Paulatto, M., Annen, C., Henstock, T. J., Kiddle, E., Minshull, T. A., Sparks, R. S. J., & Voight, B. (2012). Geochemistry Geophysics Geosystems, 13(1), doi.org/10.1029/2011GC003892. Tait, S., Jaupart, C., & Vergniolle, S. (1989). Earth and Planetary Science Letters, 92(1), 107-123. doi.org/10.1016/0012-821X(89)90025-3

  7. Geochemistry

    ERIC Educational Resources Information Center

    Brett, Robin; Hanshaw, Bruce B.

    1978-01-01

    The past year has seen the development of certain fields of geochemical research including Nd-Sm isotope studies of meteorites and ancient terrestrial rocks; the use of the consortium approach of assembling a multidisciplined team to tackle a problem; and the handling and analysis of small quantities of materials. (Author/MA)

  8. Yamato 980459: Crystallization of Martian Magnesian Magma

    NASA Technical Reports Server (NTRS)

    Koizumi, E.; Mikouchi, T.; McKay, G.; Monkawa, A.; Chokai, J.; Miyamoto, M.

    2004-01-01

    Recently, several basaltic shergottites have been found that include magnesian olivines as a major minerals. These have been called olivinephyric shergottites. Yamato 980459, which is a new martian meteorite recovered from the Antarctica by the Japanese Antarctic expedition, is one of them. This meteorite is different from other olivine-phyric shergottites in several key features and will give us important clues to understand crystallization of martian meteorites and the evolution of Martian magma.

  9. Magma Suspension As a Complex Fluid

    NASA Astrophysics Data System (ADS)

    Kurokawa, A.; Kurita, K.

    2012-12-01

    Magma is essentially a multiphase suspension of solid crystals, gaseous bubbles and silicate liquid. As for non-linear properties of magma two aspects have been focused for controlling factors in magma flow instability: the existence of the yield stress and the multiplicity in the relation between driving pressure and flow rate. The emergence of the yield stress in a suspension system has been experimentally investigated by using PNIPAM aqueous suspension as an analogue of magma (Kurokawa et al, EGU 2012-4105-2,2012). In this presentation we focus on the other aspect, the multiplicity in the rheological relationship. We investigate its physical origin of the rheology and its role in generating pressure oscillation associated with tube flow of suspension based on the PNIPAM analogue material. PNIPAM is a polymer gel and undergoes volumetric phase change at the temperature around 35 degree C: below this temperature the gel phase absorbs water and swells while over this temperature, it expels water and shrinks. Due to this property, the volume fraction of gel phase systematically changes with temperature. This makes it possible to observe the change of rheology continuously associated with the change of the fraction of solid phase. By series of rheological measurements PNIPAM aqueous suspension has been revealed to exhibit peculiar ageing effect, which is well known for complex suspension fluid. This ageing effect is responsible for generating the yield stress and the multiplicity. The multiplicity; coexistence of several flow rates at a certain pressure drives jumping between low and high flow rates, which causes oscillatory behavior of flow. We report experimental support of this model by demonstrating pressure oscillation in tube flow of PNIPAM aqueous suspension.

  10. Pressure waves in a supersaturated bubbly magma

    USGS Publications Warehouse

    Kurzon, I.; Lyakhovsky, V.; Navon, O.; Chouet, B.

    2011-01-01

    We study the interaction of acoustic pressure waves with an expanding bubbly magma. The expansion of magma is the result of bubble growth during or following magma decompression and leads to two competing processes that affect pressure waves. On the one hand, growth in vesicularity leads to increased damping and decreased wave amplitudes, and on the other hand, a decrease in the effective bulk modulus of the bubbly mixture reduces wave velocity, which in turn, reduces damping and may lead to wave amplification. The additional acoustic energy originates from the chemical energy released during bubble growth. We examine this phenomenon analytically to identify conditions under which amplification of pressure waves is possible. These conditions are further examined numerically to shed light on the frequency and phase dependencies in relation to the interaction of waves and growing bubbles. Amplification is possible at low frequencies and when the growth rate of bubbles reaches an optimum value for which the wave velocity decreases sufficiently to overcome the increased damping of the vesicular material. We examine two amplification phase-dependent effects: (1) a tensile-phase effect in which the inserted wave adds to the process of bubble growth, utilizing the energy associated with the gas overpressure in the bubble and therefore converting a large proportion of this energy into additional acoustic energy, and (2) a compressive-phase effect in which the pressure wave works against the growing bubbles and a large amount of its acoustic energy is dissipated during the first cycle, but later enough energy is gained to amplify the second cycle. These two effects provide additional new possible mechanisms for the amplification phase seen in Long-Period (LP) and Very-Long-Period (VLP) seismic signals originating in magma-filled cracks.

  11. Relative roles of rifting tectonics and magma ascent processes: Inferences from geophysical, structural, volcanological, and geochemical data for the Neapolitan volcanic region (southern Italy)

    NASA Astrophysics Data System (ADS)

    Piochi, Monica; Bruno, Pier Paolo; de Astis, Gianfilippo

    2005-07-01

    The Neapolitan volcanic region is located within the graben structure of the Campanian Plain (CP), which developed between the western sector of the Appenine Chain and the eastern margin of the Tyrrhenian Sea. Two volcanic areas, spaced less than 10 km apart, are situated within the CP: the Somma-Vesuvius Volcano (SVV) and the Phlegraean Volcanic District (PVD). SVV is a typical stratovolcano, whereas PVD, including Campi Flegrei, Procida, and Ischia, is composed mostly of monogenetic centers. This contrast is due to different magma supply systems: a widespread fissure-type system beneath the PVD and a central-type magma supply system for the SVV. Volcanological, geophysical, and geochemical data show that magma viscosity, magma supply rate, and depth of magma storage are comparable at PVD and SVV, whereas different structural arrangements characterize the two areas. On the basis of geophysical data and magma geochemistry, an oblique-extensional tectonic regime is proposed within the PVD, whereas in the SVV area a compressive stress regime dominates over extension. Geophysical data suggest that the area with the maximum deformation rate extends between the EW-running 41st parallel and the NE-running Magnaghi-Sebeto fault systems. The PVD extensional area is a consequence of the Tyrrhenian Sea opening and is decoupled from the surrounding areas (Roccamonfina and Somma-Vesuvius) which are still dominated by Adriatic slab dynamics. Spatially, we argue that the contribution of the asthenospheric wedge become much less important from W-NW to E-SE in the CP. The development of the two styles of volcanism in the CP reflects the different tectonic regimes acting in the area.

  12. Long Valley magma energy extraction project

    SciTech Connect

    Rintoul, B.

    1986-01-01

    The US Department of Energy Magma Energy Extraction Project has as its goal the extraction of geothermal energy from magma. To this end, the DOE is planning to drill close to or into magma from site in the Long Valley caldera in northeastern California. Scientific emphasis will be on the technology required to drill the hole under high temperatures and on the development of information on the geology. The drilling work is to be carried out in three stages. The first stage with drilling tentatively slated to start in October 1987, will take the hole to about 3000 feet. The second stage, starting around September 1989, will take the well to 7500 feet. The third stage, starting in September 1990, will take the hole to 18,000 feet or 500/sup 0/C. Basic tests planned for the well include temperature profile, seismic, fluid sampling, pressure, stress, and core sampling tests. It's anticipated that the temperature at about 14,000 feet will be around 325/sup 0/C, or 617/sup 0/F.

  13. Incorporation of Xenon in magmas at depth

    NASA Astrophysics Data System (ADS)

    Leroy, C.; Sanloup, C.; Bureau, H.; Schmidt, B.; Konopkova, Z.; Raepsaet, C.

    2014-12-01

    Incorporation of volatile elements in magmas is enhanced at high pressure. The dissolved volatiles affect in turn the physical and chemical properties of silicate melts. Understanding volatiles incorporation in magmas and their effect on the melt's structure can be approached by in situ characterizations such as X-ray diffraction or Raman spectroscopy.Here, we focus on Xenon (Xe) in order to constrain its past and modern geochemical cycles. Indeed the 129I/129Xe extinct isotopic system is used to constrain planetary and atmosphere formation models. Moreover, some studies propose that Xe is currently recycled from the atmosphere to the mantle.To study the solubility of Xe in silicate melts, we have performed in situ X-ray diffraction experiments on the synchrotron beam line P02 in PetraIII (DESY, Hamburg). Experiments were carried out using resistive heating diamond-anvil cells up to 7 GPa and 1300°C. Two compositions have been studied: a hydrous haplogranite (HPG) reference and a hydrous HPG doped with Xe. This composition is a magma analogue that is extremely well documented by petrological studies. Xenon can be identified on the radial distribution functions obtained by processing the x-ray diffraction data. Solubility mechanisms of Xe in silicate melts at depth will be discussed.

  14. Native gold in Hawaiian alkalic magma

    USGS Publications Warehouse

    Sisson, T.W.

    2003-01-01

    Native gold found in fresh basanite glass from the early submarine phase of Kilauea volcano, Hawaii, may be the first documented case of the transport of gold as a distinct precious metal phase in a mantle-derived magma. The gold-bearing glass is a grain in bedded volcanic glass sandstone (Japan Marine Science and Technology Center (JAMSTEC) sample S508-R3) collected by the submersible Shinkai 6500 at 3879 m depth off Kilauea's south flank. Extensive outcrops there expose debris-flow breccias and sandstones containing submarine-erupted alkalic rock fragments and glasses from early Kilauea. Precipitation of an immiscible gold liquid resulted from resorption of magmatic sulfides during crystallization-differentiation, with consequent liberation of sulfide-hosted gold. Elevated whole-rock gold concentrations (to 36 ppb) for fresh lavas and clasts from early Kilauea further show that some magmas erupted at the beginning stages of Hawaiian shield volcanoes were distinctly gold rich, most likely owing to limited residual sulfide in their mantle source. Alkalic magmas at other ocean islands may also be gold rich, and oceanic hot-spot provinces may contain underappreciated gold resources.

  15. Voluminous granitic magmas from common basaltic sources

    USGS Publications Warehouse

    Sisson, T.W.; Ratajeski, K.; Hankins, W.B.; Glazner, A.F.

    2005-01-01

    Granitic-rhyolitic liquids were produced experimentally from moderately hydrous (1.7-2.3 wt% H2O) medium-to-high K basaltic compositions at 700 MPa and f O2 controlled from Ni-NiO -1.3 to +4. Amount and composition of evolved liquids and coexisting mineral assemblages vary with fO2 and temperature, with melt being more evolved at higher fO2s, where coexisting mineral assemblages are more plagioclase- and Fe-Ti oxide-rich and amphibole-poor. At fO2 of Ni-NiO +1, typical for many silicic magmas, the samples produce 12-25 wt% granitic-rhyolitic liquid, amounts varying with bulk composition. Medium-to-high K basalts are common in subduction-related magmatic arcs, and near-solidus true granite or rhyolite liquids can form widely, and in geologically significant quantities, by advanced crystallization-differentiation or by low-degree partial remelting of mantle-derived basaltic sources. Previously differentiated or weathered materials may be involved in generating specific felsic magmas, but are not required for such magmas to be voluminous or to have the K-rich granitic compositions typical of the upper continental crust. ?? Springer-Verlag 2005.

  16. The fundamental role of asthenospherically-derived, OIB-like magmas in volcanism of the North American Cordillera, 50 Ma to present

    SciTech Connect

    Wolff, J.A.; Ellisor, R. . Dept. of Geology); Davidson, J.P. . Dept. of Earth and Space Sciences)

    1993-04-01

    Excluding the small proportion of magmas that bear a clear mantle lithosphere signature, the geochemistry of basalts erupted in the North American Cordillera, over the past 50 Ma, is broadly consistent with a simple model of crustal contamination of magma derived from a mantle source similar to that which produces ocean-island basalts (OIB). Within any one volcanic field or association, the most mafic lavas bear the closest resemblance to OIB; contamination yields basaltic andesites and andesites having characteristics that resemble those of arc magmas. Despite the smaller volumes of andesite produced since the onset of extension compared to the earlier Cenozoic, the same chemical trends are common to both periods. This conclusion can be refined somewhat by using Weaver's trace element characterization of OIB end-member types. Least-contaminated lavas typically lie on mixing lines between depleted MORB mantle (DMM) and enriched mantle (EM). However, a significant role for EM is precluded by high [sup 143]Nd/[sup 144]Nd in the most mafic lavas. Making the conservative assumption that no magma has completely escaped contamination, most suite trends project to a DMM-HIMU mix, typically with a high proportion of DMM. Thus, the mantle component in Cordilleran lavas is essentially identical to common OIB, and it is legitimate to speculate on the possible role of a vigorous mantle plume (or plume family) as the driving force for Cenozoic Cordilleran magmatism.

  17. Magma storage and evolution in the Henties Bay-Outjo dyke swarm, Namibia -feeder systems of the Etendeka lavas

    NASA Astrophysics Data System (ADS)

    Keiding, J. K.; Frei, O.; Renno, A.; Veksler, I. V.; Trumbull, R. B.

    2012-04-01

    At the roots of continental flood basalts in the Paraná-Etendeka province are mafic dyke swarms that cover areas of several hundred kilometers. Studies of these dykes have focused mainly on the age, paleomagnetic properties and geochemistry, but less on pressure (P) and temperature (T) conditions of emplacement. However, the P and T conditions under which dyke magmas are stored are crucial for models of magma plumbing systems in flood basalt provinces. The erupted lavas are typically far from primitive compositions and generally show evidence for strong crustal assimilation in addition to magma fractionation. Unknown is where this magma modification took place in the crust. This is the kind of information that dyke studies can provide. The Henties Bay Outjo dyke swarm (HOD) in NW Namibia is the subject of this study. This is inarguably the best exposed of major dyke swarms associated with South Atlantic rifting and breakup and its geochemical diversity is well documented but aspects relating to the magma dynamics in the dyke swarm have not been studied before. Our approach is to use geochemical data from selected dykes to assess the differentiation and assimilation history of the magmas, and combine that with petrologic constraints on the temperature-pressure conditions of crystallization derived from mineral-melt equilibria. We have determined P-T estimates from olivine-melt and clinopyroxene-melt equilibria using analysis of phenocrysts by electron microprobe and applying the thermodynamic relations from Putirka (2008), who considered the standard error to be 1.7 kbar and 30°C. The calculations reflect only mineral-melt (proxied by whole-rock) compositions that are consistent with equilibrium. Crystallization temperatures range from 1040°C to 1350°C with a mean (n=58) of 1170 °C. These T-variations are not random, the high-temperature results come from a specific region of dyke emplacement but the reason for this is not yet clear. Olivine-melt temperatures

  18. Petrology and Geochemistry of the Eocene Volcanic Rocks in the Kahrizak Mountains, Central Iran

    NASA Astrophysics Data System (ADS)

    Yazdani, S.; Castillo, P.; Tutti, F.

    2013-12-01

    The Eocene volcanic rocks in the Kahrizak (KH) Mountains in the northern part of Central Iran were mainly formed by magmatism that accompanied block-faulting tectonism in the region. In the KH area, the volcanic rocks are nonconformably overlain by Oligocene-Pliocene sedimentary deposits, suggesting that the Eocene magmatic activity in the region was followed by a sequence of uplift and shallow marine regression. The volcanic rocks consist of pyroclastics (tuff and ignimbrites) and lava flows (basalt, basaltic trachyandesite, trachyandesite, and rhyolite); superposition indicates an earlier explosive volcanic phase that caused the widespread distribution of rhyolitic ignimbrites and tuffs, and this was followed by a quieter phase of lava eruptions. Petrographic evidence such as mineral zoning, sieve texture and rounded crystals of plagioclase and pyroxene phenocrysts indicate non-equilibrium conditions between melt and crystals during magma cooling. These textures suggest magma mixing, although these may also be due to rapid decompression, where heat loss is minor relative to the ascent rate. The geochemistry of KH samples indicates their subalkaline to alkaline affinity. In terms of trace element contents, most samples exhibit the distinct geochemical trait of arc volcanism, i.e., Nb and Ta depletions relative to LILE (e.g., Ba, Rb) enrichment and positive Sr anomaly; however, Zr and Ti depletions are not prominent. The samples have a light-REE enriched but flat heavy-REE pattern and negative Eu anomaly in the rhyolites and trachyandesites. They have a ~narrow to ~moderate range of Pb isotopic ratios (206Pb/204Pb ~18.6-18.9, 207Pb/204Pb ~15.5-15.6, and 208Pb/204Pb ~38.5-38.8), with basaltic rocks somewhat higher than rhyolitic rocks. Available geochemical and isotopic data suggest a complex origin and evolution of the KH magmas. The magmas originated from an intrinsically ~heterogeneous source and, in addition to fractional crystallization, some of the

  19. Minor-element and Sr-isotope geochemistry of tertiary stocks, Colorado mineral belt

    USGS Publications Warehouse

    Simmons, E.C.; Hedge, C.E.

    1978-01-01

    Rocks of the northeast portion of the Colorado mineral belt form two petrographically, chemically and geographically distinct rock suites: (1) a silica oversaturated granodiorite suite; and (2) a silica saturated, high alkali monzonite suite. Rocks of the granodiorite suite generally have Sr contents less than 1000 ppm, subparallel REE patterns and initial 87Sr/ 86Sr ratios greater than 0.707. Rocks of the monzonite suite are restricted to the northeast part of the mineral belt, where few rocks of the granodiorite suite occur, and generally have Sr contents greater than 1000 ppm, highly variable REE patterns and 87Sr/86Sr initial ratios less than 0.706. Despite forming simple, smooth trends on major element variation diagrams, trace element data for rocks of the granodiorite suite indicate that they were not derived from a single magma. These rocks were derived from magmas having similar REE patterns, but variable Rb and Sr contents, and Rb/Sr ratios. The preferred explanation for these rocks is that they were derived by partial melting of a mixed source, which yielded pyroxene granulite or pyroxenite residues. The monzonite suite is chemically and petrographically more complex than the granodiorite suite. It is subdivided here into alkalic and mafic monzonites, and quartz syenites, based on the textural relations of their ferromagnesian phases and quartz. The geochemistry of these three rock types require derivation from separate and chemically distinct magma types. The preferred explanation for the alkalic monzonites is derivation from a heterogeneous mafic source, leaving a residue dominated by garnet and clinopyroxene. Early crystallization of sphene from these magmas was responsible for the severe depletion of the REE observed in the residual magmas. The lower Sr content and higher Rb/Sr ratios of the mafic monzonites requires a plagioclase-bearing source. The Sr-isotope systematics of the majority of these rocks are interpreted to be largely primary, and not

  20. Magma mixing enhanced by bubble segregation

    NASA Astrophysics Data System (ADS)

    Wiesmaier, S.; Morgavi, D.; Renggli, C. J.; Perugini, D.; De Campos, C. P.; Hess, K.-U.; Ertel-Ingrisch, W.; Lavallée, Y.; Dingwell, D. B.

    2015-08-01

    In order to explore the materials' complexity induced by bubbles rising through mixing magmas, bubble-advection experiments have been performed, employing natural silicate melts at magmatic temperatures. A cylinder of basaltic glass was placed below a cylinder of rhyolitic glass. Upon melting, bubbles formed from interstitial air. During the course of the experimental runs, those bubbles rose via buoyancy forces into the rhyolitic melt, thereby entraining tails of basaltic liquid. In the experimental run products, these plume-like filaments of advected basalt within rhyolite were clearly visible and were characterised by microCT and high-resolution EMP analyses. The entrained filaments of mafic material have been hybridised. Their post-experimental compositions range from the originally basaltic composition through andesitic to rhyolitic composition. Rheological modelling of the compositions of these hybridised filaments yield viscosities up to 2 orders of magnitude lower than that of the host rhyolitic liquid. Importantly, such lowered viscosities inside the filaments implies that rising bubbles can ascend more efficiently through pre-existing filaments that have been generated by earlier ascending bubbles. MicroCT imaging of the run products provides textural confirmation of the phenomenon of bubbles trailing one another through filaments. This phenomenon enhances the relevance of bubble advection in magma mixing scenarios, implying as it does so, an acceleration of bubble ascent due to the decreased viscous resistance facing bubbles inside filaments and yielding enhanced mass flux of mafic melt into felsic melt via entrainment. In magma mixing events involving melts of high volatile content, bubbles may be an essential catalyst for magma mixing. Moreover, the reduced viscosity contrast within filaments implies repeated replenishment of filaments with fresh end-member melt. As a result, complex compositional gradients and therefore diffusion systematics can be

  1. Geochemical Evidence for a Terrestrial Magma Ocean

    NASA Technical Reports Server (NTRS)

    Agee, Carl B.

    1999-01-01

    The aftermath of phase separation and crystal-liquid fractionation in a magma ocean should leave a planet geochemically differentiated. Subsequent convective and other mixing processes may operate over time to obscure geochemical evidence of magma ocean differentiation. On the other hand, core formation is probably the most permanent, irreversible part of planetary differentiation. Hence the geochemical traces of core separation should be the most distinct remnants left behind in the mantle and crust, In the case of the Earth, core formation apparently coincided with a magma ocean that extended to a depth of approximately 1000 km. Evidence for this is found in high pressure element partitioning behavior of Ni and Co between liquid silicate and liquid iron alloy, and with the Ni-Co ratio and the abundance of Ni and Co in the Earth's upper mantle. A terrestrial magma ocean with a depth of 1000 km will solidify from the bottom up and first crystallize in the perovskite stability field. The largest effect of perovskite fractionation on major element distribution is to decrease the Si-Mg ratio in the silicate liquid and increase the Si-Mg ratio in the crystalline cumulate. Therefore, if a magma ocean with perovskite fractionation existed, then one could expect to observe an upper mantle with a lower than chondritic Si-Mg ratio. This is indeed observed in modern upper mantle peridotites. Although more experimental work is needed to fully understand the high-pressure behavior of trace element partitioning, it is likely that Hf is more compatible than Lu in perovskite-silicate liquid pairs. Thus, perovskite fractionation produces a molten mantle with a higher than chondritic Lu-Hf ratio. Arndt and Blichert-Toft measured Hf isotope compositions of Barberton komatiites that seem to require a source region with a long-lived, high Lu-Hf ratio. It is plausible that that these Barberton komatiites were generated within the majorite stability field by remelting a perovskite

  2. Layer Formation in Convective Magma Chambers

    NASA Astrophysics Data System (ADS)

    Höink, T.; Schmalzl, J.; Hansen, U.

    2004-12-01

    The dynamics of a convective magma chamber is crucially influenced by the competetion between sedimentation and convective suspension of crystals. Crystal settling combined with the crystal's density contribution is a possible mechanism leading to differentiation and layer formation. Here we address the question whether crystals can remain suspended or whether they are able to dynamically form a layered structure within the convective lifetime of a magma chamber. We employ an existing numerical method that, by means of a finite volume scheme, discretizes the equations for thermally driven convection in an infinite Prandtl-number Boussinesq fluid in Cartesian geometry. We implement a newly developed settling algorithm for the numerical study of finite-sized-particle settling in a non-dilute convective suspension. Our approach considers a consistent settling velocity and the density contribution due to particle mass. The buoyancy ratio B, which is the ratio of the density variation due to crystal mass to the thermal density variation, is varied for five different Rayleigh numbers, covering a range of four orders of magnitude. We find B to be a critical parameter and its critical value to depend on the Rayleigh number. For subcritical values we observe that the presence of a crystal phase reduces convective vigor and most crystals stay suspended. When a critical buoyancy ratio is exceeded, the presence of crystals can significantly alter convective motion. For all investigated Rayleigh numbers we find a critical buoyancy ratio, above which layering can be achieved from an initially unstratified fluid. Most of the crystal mass collects in the dynamically created bottom layer, even for cases where the average settling velocity is three orders of magnitude smaller than the root mean square convective velocity. The time it takes a crystal to travel across the height of the cell with the full settling velocity in the absence of a thermal gradient defines the settling

  3. Magma deformation and emplacement in rhyolitic dykes

    NASA Astrophysics Data System (ADS)

    McGowan, Ellen; Tuffen, Hugh; James, Mike; Wynn, Peter

    2016-04-01

    Silicic eruption mechanisms are determined by the rheological and degassing behaviour of highly-viscous magma ascending within shallow dykes and conduits. However, we have little knowledge of how magmatic behaviour shifts during eruptions as dykes and conduits evolve. To address this we have analysed the micro- to macro-scale textures in shallow, dissected rhyolitic dykes at the Tertiary Húsafell central volcano in west Iceland. Dyke intrusion at ~3 Ma was associated with the emplacement of subaerial rhyolitic pyroclastic deposits following caldera formation[1]. The dykes are dissected to ~500 m depth, 2-3 m wide, and crop out in two stream valleys with 5-30 m-long exposures. Dykes intrude diverse country rock types, including a welded ignimbrite, basaltic lavas, and glacial conglomerate. Each of the six studied dykes is broadly similar, exhibiting obsidian margins and microcrystalline cores. Dykes within pre-fractured lava are surrounded by external tuffisite vein networks, which are absent from dykes within conglomerate, whereas dykes failed to penetrate the ignimbrite. Obsidian at dyke margins comprises layers of discrete colour. These display dramatic thickness variations and collapsed bubble structures, and are locally separated by zones of welded, brecciated and flow-banded obsidian. We use textural associations to present a detailed model of dyke emplacement and evolution. Dykes initially propagated with the passage of fragmented, gas-charged magma and generation of external tuffisite veins, whose distribution was strongly influenced by pre-existing fractures in the country rock. External tuffisites retained permeability throughout dyke emplacement due to their high lithic content. The geochemically homogenous dykes then evolved via incremental magma emplacement, with shear deformation localised along emplacement boundary layers. Shear zones migrated between different boundary layers, and bubble deformation promoted magma mobility. Brittle

  4. Oxidized sulfur-rich mafic magma at Mount Pinatubo, Philippines

    USGS Publications Warehouse

    de Hoog, J.C.M.; Hattori, K.H.; Hoblitt, R.P.

    2004-01-01

    Basaltic fragments enclosed in andesitic dome lavas and pyroclastic flows erupted during the early stages of the 1991 eruption of Mount Pinatubo, Philippines, contain amphiboles that crystallized during the injection of mafic magma into a dacitic magma body. The amphiboles contain abundant melt inclusions, which recorded the mixing of andesitic melt in the mafic magma and rhyolitic melt in the dacitic magma. The least evolved melt inclusions have high sulfur contents (up to 1,700 ppm) mostly as SO42, which suggests an oxidized state of the magma (NNO + 1.4). The intrinsically oxidized nature of the mafic magma is confirmed by spinel-olivine oxygen barometry. The value is comparable to that of the dacitic magma (NNO + 1.6). Hence, models invoking mixing as a means of releasing sulfur from the melt are not applicable to Pinatubo. Instead, the oxidized state of the dacitic magma likely reflects that of parental mafic magma and the source region in the sub-arc mantle. Our results fit a model in which long-lived SO2 discharge from underplated mafic magma accumulated in the overlying dacitic magma and immiscible aqueous fluids. The fluids were the most likely source of sulfur that was released into the atmosphere during the cataclysmic eruption. The concurrence of highly oxidized basaltic magma and disproportionate sulfur output during the 1991 Mt. Pinatubo eruption suggests that oxidized mafic melt is an efficient medium for transferring sulfur from the mantle to shallow crustal levels and the atmosphere. As it can carry large amounts of sulfur, effectively scavenge sulfides from the source mantle and discharge SO2 during ascent, oxidized mafic magma forms arc volcanoes with high sulfur fluxes, and potentially contributes to the formation of metallic sulfide deposits. ?? Springer-Verlag 2003.

  5. Magma-driven subcritical crack growth and implications for dike initiation from a magma chamber

    NASA Astrophysics Data System (ADS)

    Chen, Zuan; Jin, Z.-H.

    2006-10-01

    The purpose of this paper is to explore a viscoelastic energy dissipation theory for subcritical dike growth from a magma chamber. The theoretical relationship between the dike growth velocity and dike length is established using the viscoelastic subcritical crack growth theory proposed by the first author and the solutions of stress intensity factor at the crack tip derived by a perturbation method. Effects of magma chamber over-pressure, buoyancy and viscoelastic properties of the host rock on the subcritical growth rate are included in the model. The numerical results indicate that the viscous energy dissipation of the host rock could allow a short dike to slowly grow on the order of 10-7-10-5 m/s under modest over-pressure and to accelerate when the stress intensity factor increases close to the fracture toughness, followed by the unstable dike propagation. The proposed theory provides a reasonable understanding of dike initiation process from a magma chamber.

  6. The influence of magma viscosity on convection within a magma chamber

    NASA Astrophysics Data System (ADS)

    Schubert, M.; Driesner, T.; Ulmer, P.

    2012-12-01

    Magmatic-hydrothermal ore deposits are the most important sources of metals like Cu, Mo, W and Sn and a major resource for Au. It is well accepted that they are formed by the release of magmatic fluids from a batholith-sized magma body. Traditionally, it has been assumed that crystallization-induced volatile saturation (called "second boiling") is the main mechanism for fluid release, typically operating over thousands to tens of thousands of years (Candela, 1991). From an analysis of alteration halo geometries caused by magmatic fluids, Cathles and Shannon (2007) suggested much shorter timescales in the order of hundreds of years. Such rapid release of fluids cannot be explained by second boiling as the rate of solidification scales with the slow conduction of heat away from the system. However, rapid fluid release is possible if convection is assumed within the magma chamber. The magma would degas in the upper part of the magma chamber and volatile poor magma would sink down again. Such, the rates of degassing can be much higher than due to cooling only. We developed a convection model using Navier-Stokes equations provided by the computational fluid dynamics platform OpenFOAM that gives the possibility to use externally derived meshes with complex (natural) geometries. We implemented a temperature, pressure, composition and crystal fraction dependent viscosity (Ardia et al., 2008; Giordano et al., 2008; Moore et al., 1998) and a temperature, pressure, composition dependent density (Lange1994). We found that the new viscosity and density models strongly affect convection within the magma chamber. The dependence of viscosity on crystal fraction has a particularly strong effect as the steep viscosity increase at the critical crystal fraction leads to steep decrease of convection velocity. As the magma chamber is cooling from outside to inside a purely conductive layer is developing along the edges of the magma chamber. Convection continues in the inner part of the

  7. Rift initiation with volatiles and magma

    NASA Astrophysics Data System (ADS)

    Ebinger, Cynthia; Muirhead, James; Roecker, Steve; Tiberi, Christel; Muzuka, Alfred; Ferdinand, Rrichard; Mulibo, Gabrile; Kianji, Gladys

    2015-04-01

    Rift initiation in cratonic lithosphere remains an outstanding problem in continental tectonics, but strain and magmatism patterns in youthful sectors of the East African rift provide new insights. Few teleseisms occur in the Eastern rift arm of the East African rift system, except the southernmost sector in northern Tanzania where extension occurs in Archaean lithosphere. The change in seismic energy release occurs over a narrow along-axis zone, and between sectors with and without volcanoes in the central rift valley. Are these differences in strain behavior indicative of along-strike variations in a) rheology; b) strain transfer from border faults to magma intrusion zones; c) dike vs fault slip; and/or d) shallow vs deep magma chambers? We present time-space relations of seismicity recorded on a 38-station array spanning the Kenya-Tanzania border, focal mechanisms for the largest events during those time periods, and compare these to longer-term strain patterns. Lower crustal seismicity occurs along the rift length, including sectors on and off craton, and those with and without central rift valley volcanoes, and we see no clear along-strike variation in seismogenic layer thickness. One explanation for widespread lower crustal seismicity is high gas pressures and volatile migration from active metasomatism of upper mantle and magma degassing, consistent with very high volatile flux along fault zones, and widespread metasomatism of xenoliths. Volatile release and migration may be critical to strength reduction of initially cold, strong cratonic lithosphere. Seismicity patterns indicate strain (and fluid?) transfer from the Manyara border fault to Gelai shield volcano (faulting, diking) via Oldoinyo Lengai volcano. Our focal mechanisms and Global CMTs from an intense fault-dike episode (2007) show a local, temporally stable, rotation from ~E-W extension to NE-SE extension in this linkage zone, consistent with longer term patterns recorded in vent and eruptive

  8. Magma mixing enhanced by bubble segregation

    NASA Astrophysics Data System (ADS)

    Wiesmaier, S.; Daniele, M.; Renggli, C.; Perugini, D.; De Campos, C.; Hess, K. U.; Ertel-Ingrisch, W.; Lavallée, Y.; Dingwell, D. B.

    2014-12-01

    Rising bubbles may significantly affect magma mixing paths as has been demonstrated by analogue experiments in the past. Here, bubble-advection experiments are performed for the first time employing natural materials at magmatic temperatures. Cylinders of basaltic glass were placed below cylinders of rhyolite glass. Upon melting, interstitial air formed bubbles that rose into the rhyolite melt, thereby entraining tails of basaltic liquid. The formation of plume-like filaments of advected basalt within the rhyolite was characterized by microCT and subsequent high-resolution EMP analyses. Melt entrainment by bubble ascent appears as efficient mechanism to mingle contrasting melt compositions. MicroCT imaging shows bubbles trailing each other and trails of multiple bubbles having converged. Rheological modelling of the filaments yields viscosities of up to 2 orders of magnitude lower than for the surrounding rhyolitic liquid. Such a viscosity contrast implies that subsequent bubbles rising are likely to follow the same pathways that previously ascending bubbles have generated. Filaments formed by multiple bubbles would thus experience episodic replenishment with mafic material. Fundamental implications for the concept of bubble advection in magma mixing are thus a) an acceleration of mixing because of decreased viscous resistance for bubbles inside filaments and b) non-conventional diffusion systematics because of intermittent supply of mafic material (instead of a single pulse) inside a filament. Inside these filaments, the mafic material was variably hybridised to andesitic through rhyolitic composition. Compositional profiles alone are ambiguous, however, to determine whether single or multiple bubbles were involved during formation of a filament. Statistical analysis, employing concentration variance as measure of homogenisation, demonstrates that also filaments appearing as single-bubble filaments are likely to have experienced multiple bubbles passing through

  9. Asteroid differentiation - Pyroclastic volcanism to magma oceans

    NASA Technical Reports Server (NTRS)

    Taylor, G. J.; Keil, Klaus; Mccoy, Timothy; Haack, Henning; Scott, Edward R. D.

    1993-01-01

    A summary is presented of theoretical and speculative research on the physics of igneous processes involved in asteroid differentiation. Partial melting processes, melt migration, and their products are discussed and explosive volcanism is described. Evidence for the existence of asteroidal magma oceans is considered and processes which may have occurred in these oceans are examined. Synthesis and inferences of asteroid heat sources are discussed under the assumption that asteroids are heated mainly by internal processes and that the role of impact heating is small. Inferences of these results for earth-forming planetesimals are suggested.

  10. Special Relativity Derived from Spacetime Magma

    PubMed Central

    Greensite, Fred

    2014-01-01

    We present a derivation of relativistic spacetime largely untethered from specific physical considerations, in constrast to the many physically-based derivations that have appeared in the last few decades. The argument proceeds from the inherent magma (groupoid) existing on the union of spacetime frame components and Euclidean which is consistent with an “inversion symmetry” constraint from which the Minkowski norm results. In this context, the latter is also characterized as one member of a class of “inverse norms” which play major roles with respect to various unital -algebras more generally. PMID:24959889

  11. Special relativity derived from spacetime magma.

    PubMed

    Greensite, Fred

    2014-01-01

    We present a derivation of relativistic spacetime largely untethered from specific physical considerations, in constrast to the many physically-based derivations that have appeared in the last few decades. The argument proceeds from the inherent magma (groupoid) existing on the union of spacetime frame components [Formula: see text] and Euclidean [Formula: see text] which is consistent with an "inversion symmetry" constraint from which the Minkowski norm results. In this context, the latter is also characterized as one member of a class of "inverse norms" which play major roles with respect to various unital [Formula: see text]-algebras more generally.

  12. Special relativity derived from spacetime magma.

    PubMed

    Greensite, Fred

    2014-01-01

    We present a derivation of relativistic spacetime largely untethered from specific physical considerations, in constrast to the many physically-based derivations that have appeared in the last few decades. The argument proceeds from the inherent magma (groupoid) existing on the union of spacetime frame components [Formula: see text] and Euclidean [Formula: see text] which is consistent with an "inversion symmetry" constraint from which the Minkowski norm results. In this context, the latter is also characterized as one member of a class of "inverse norms" which play major roles with respect to various unital [Formula: see text]-algebras more generally. PMID:24959889

  13. Role of Yield Stress in Magma Rheology

    NASA Astrophysics Data System (ADS)

    Kurokawa, A.; Di Giuseppe, E.; Davaille, A.; Kurita, K.

    2012-04-01

    Magmas are essentially multiphase material composed of solid crystals, gaseous bubbles and silicate liquids. They exhibit various types of drastic change in rheology with variation of mutual volumetric fractions of the components. The nature of this variable rheology is a key factor in controlling dynamics of flowing magma through a conduit. Particularly the existence of yield stress in flowing magma is expected to control the wall friction and formation of density waves. As the volumetric fraction of solid phase increases yield stress emerges above the critical fraction. Several previous studies have been conducted to clarify this critical value of magmatic fluid both in numerical simulations and laboratory experiments ([Lejeune and Pascal, 1995], [Saar and Manga 2001], [Ishibashi and Sato 2010]). The obtained values range from 13.3 to 40 vol%, which display wide variation and associated change in rheology has not been clarified well. In this presentation we report physical mechanism of emergence of yield stress in suspension as well as the associated change in the rheology based on laboratory experiments using analog material. We utilized thermogel aqueous suspension as an analog material of multiphase magma. Thermogel, which is a commercial name for poly(N-isopropyl acrylamide) (PNIPAM) undergoes volumetric phase change at the temperature around 35C:below this temperature the gel phase absorbs water and swells while below this it expels water and its volume shrinks. Because of this the volumetric fraction of gel phase systematically changes with temperature and the concentration of gel powder. The viscosity measured at lower stress drastically decreases across this phase change with increasing temperature while the viscosity at higher stress does not exhibit large change across the transition. We have performed a series of rheological measurements focusing on the emergence of yield stress on this aqueous suspension. Since the definition of yield stress is not

  14. Magma storage under Iceland's Eastern Volcanic Zone

    NASA Astrophysics Data System (ADS)

    Maclennan, J.; Neave, D.; Hartley, M. E.; Edmonds, M.; Thordarson, T.; Morgan, D. J.

    2014-12-01

    The Eastern Volcanic Zone (EVZ) of Iceland is defined by a number of volcanic systems and large basaltic eruptions occur both through central volcanoes (e.g. Grímsvötn) and on associated fissure rows (e.g. Laki, Eldgjá). We have collected a large quantity of micro-analytical data from a number of EVZ eruptions, with the aim of identifying common processes that occur in the premonitory stages of significant volcanic events. Here, we focus on the AD 1783 Laki event, the early postglacial Saksunarvatn tephra and the sub-glacially erupted Skuggafjöll tindar and for each of these eruptions we have >100 olivine-hosted or plagioclase-hosted melt inclusion analyses for major, trace and volatile elements. These large datasets are vital for understanding the history of melt evolution in the plumbing system of basaltic volcanoes. Diverse trace element compositions in melt inclusions hosted in primitive macrocrysts (i.e. Fo>84, An>84) indicate that the mantle melts supplied to the plumbing system of EVZ eruptions are highly variable in composition. Concurrent mixing and crystallisation of these melts occurs in crustal magma bodies. The levels of the deepest of these magma bodies are not well constrained by EVZ petrology, with only a handful of high-CO2 melt inclusions from Laki providing evidence for magma supply from >5 kbar. In contrast, the volatile contents of melt inclusions in evolved macrocrysts, which are close to equilibrium with the carrier liquids, indicate that final depths of inclusion entrapment are 0.5-2 kbar. The major element composition of the matrix glasses shows that the final pressure of equilibration between the melt and its macrocryst phases also occurred at 0.5-2 kbar. The relationship between these pressures and seismic/geodetic estimates of chamber depths needs to be carefully evaluated. The melt inclusion and macrocryst compositional record indicates that injection of porphyritic, gas-rich primitive melt into evolved/enriched and degassed shallow

  15. Coupled effect of magma degassing and rheology on silicic volcanism

    NASA Astrophysics Data System (ADS)

    Okumura, Satoshi; Nakamura, Michihiko; Uesugi, Kentaro; Nakano, Tsukasa; Fujioka, Takuma

    2013-01-01

    Explosive volcanism such as the 1991 Mt. Pinatubo, Philippines, and the 2008 Mt. Chaitén, Chile, eruptions is caused by violent vesiculation of hydrous magma. However, gas may efficiently separate from magma owing to the enhancement of gas permeability by shear deformation of magma flowing in a volcanic conduit. This makes it difficult to maintain the driving force of explosive volcanism although explosive volcanism is actually common. Here, we propose that shear localization in a volcanic conduit controls the eruption style and explosivity based on deformation experiments of vesicular magma linked with synchrotron radiation X-ray radiography and computed tomography. We observed, for the first time in situ, that the shear localization caused magma fracturing and formed a slip plane, and thus inhibited deformation and outgassing elsewhere. We also observed the compaction of vesicular magma into a dense "lava" as a result of outgassing when shear localization did not occur. In a natural setting, shear localizes along the edges of a volcanic conduit, where the strain rate is high, causing a highly permeable fracturing layer to form at the conduit's edge and leaving less-sheared and less-outgassed magma at its center. The less-outgassed magma in the center may ascend rapidly and cause explosive volcanism. Non-explosive lava effusion may occur only when shear localization does not occur effectively. This new view explains the rapid ascent of viscous magma and the formation of pyroclasts with contrasting vesicularity (pyroclastic obsidian and highly vesiculated pumice).

  16. Selection of promising sites for magma energy experiments

    SciTech Connect

    Carson, C.C.

    1985-01-01

    The Long Valley and Coso Hot Springs areas of California have been identified as the most promising sites for conducting a magma energy extraction experiment. These two locations were selected from among the potential sites on the basis of several factors that are critical to the success of the proposed long-term energy extraction experiment. These factors include the likelihood of the existence of shallow magma targets as well as several other drilling, energy extraction and programmatic considerations. As the magma energy extraction program continues, these sites will be analyzed in detail so that one can be selected as the site for the planned magma experiment.

  17. Evidence for magma mixing within the Laacher See magma chamber (East Eifel, Germany)

    USGS Publications Warehouse

    Worner, G.; Wright, T.L.

    1984-01-01

    The final pyroclastic products of the late Quaternary phonolitic Laacher See volcano (East Eifel, W.-Germany) range from feldspar-rich gray phonolite to dark olivine-bearing rocks with variable amounts of feldspar and Al-augite megacrysts. Petrographically and chemically homogeneous clasts occur along with composite lapilli spanning the compositional range from phonolite (MgO 0.9%) to mafic hybrid rock (MgO 7.0%) for all major and trace elements. Both a basanitic and a phonolitic phenocryst paragenesis occur within individual clasts. The phonolite-derived phenocrysts are characterized by glass inclusions of evolved composition, rare inverse zoning and strong resorption indicating disequilibrium with the mafic hybrid matrix. Basanitic (magnesian) clinopyroxene and olivine, in contrast, show skeletal (normally zoned) overgrowths indicative of post-mixing crystallization. In accord with petrographical and other chemical evidence, mass balance calculations suggest mixing of an evolved Laacher See phonolite containing variable amounts of mineral cumulates and a megacryst-bearing basanite magma. Magma mixing occurred just prior to eruption (hours) of the lowermost magma layer of the Laacher See magma chamber but did not trigger the volcanic activity. ?? 1984.

  18. Degassing of the 1912 Katmai magmas

    NASA Astrophysics Data System (ADS)

    Westrich, H. R.; Eichelberger, J. C.; Hervig, R. L.

    1991-08-01

    Pre- and post-eruptive H2O, F, Cl, and S contents of the three 1912 Katmai magmas were inferred from analyses of melt inclusions and matrix glasses in tephra samples. With increasing silica content (andesite⇒rhyolite), pre-emptive melt H2O increases from ≥1.0 to 3.8 wt.%, Cl increases slightly from 1700 to 1900 ppm, S decreases from 170 to ≤65 ppm, and F remains constant at 550 ppm. These variations are not consistent with a simple crystal fractionation relationship. For plausible chamber depths, the magmas were vapor undersaturated during storage and fragmented during the last few hundred meters of ascent, consistent with geologic evidence for excavation of the vent funnel within the upper 1 km. Vitrophyres of welded intravent fallback tephra ejected late in the eruption show that extensive degassing and complete welding could take place in less than the 60-hour eruptive period. Release of HCl was twice that of the 1980 eruption of Mount St. Helens while H2SO4 output was comparable to that of the 3.5 ka Santorini eruption. Significant retention of Cl and F, which would be released along with residual H2O during high-temperature devitrification, may explain the important vapor transport that occurred in the Valley of Ten Thousand Smokes fumaroles following emplacement of the ignimbrite.

  19. Organic geochemistry - A retrospective of its first 70 years

    USGS Publications Warehouse

    Kvenvolden, K.A.

    2006-01-01

    Organic geochemistry had its origin in the early part of the 20th century when organic chemists and geologists realized that detailed information on the organic materials in sediments and rocks was scientifically interesting and of practical importance. The generally acknowledged "father" of organic geochemistry is Alfred E. Treibs (1899-1983), who discovered and described, in 1936, porphyrin pigments in shale, coal, and crude oil, and traced the source of these molecules to their biological precursors. Thus, the year 1936 marks the beginning of organic geochemistry. However, formal organization of organic geochemistry dates from 1959 when the Organic Geochemistry Division (OGD) of The Geochemical Society was founded in the United States, followed 22 years later (1981) by the establishment of the European Association of Organic Geochemists (EAOG). Organic geochemistry (1) has its own journal, Organic Geochemistry (beginning in 1979) which, since 1988, is the official journal of the EAOG, (2) convenes two major conferences [International Meeting on Organic Geochemistry (IMOG), since 1962, and Gordon Research Conferences on Organic Geochemistry (GRC), since 1968] in alternate years, and (3) is the subject matter of several textbooks. Organic geochemistry is now a widely recognized geoscience in which organic chemistry has contributed significantly not only to geology (i.e., petroleum geochemistry, molecular stratigraphy) and biology (i.e., biogeochemistry), but also to other disciplines, such as chemical oceanography, environmental science, hydrology, biochemical ecology, archaeology, and cosmochemistry.

  20. Magma evolution and ascent at the Craters of the Moon and neighboring volcanic fields, southern Idaho, USA: implications for the evolution of polygenetic and monogenetic volcanic fields

    USGS Publications Warehouse

    Putirka, Keith D.; Kuntz, Mel A.; Unruh, Daniel M.; Vaid, Nitin

    2009-01-01

    The evolution of polygenetic and monogenetic volcanic fields must reflect differences in magma processing during ascent. To assess their evolution we use thermobarometry and geochemistry to evaluate ascent paths for neighboring, nearly coeval volcanic fields in the Snake River Plain, in south-central Idaho, derived from (1) dominantly Holocene polygenetic evolved lavas from the Craters of the Moon lava field (COME) and (2) Quaternary non-evolved, olivine tholeiites (NEOT) from nearby monogenetic volcanic fields. These data show that NEOT have high magmatic temperatures (1205 + or - 27 degrees C) and a narrow temperature range (50 degrees C). Prolonged storage of COME magmas allows them to evolve to higher 87Sr/86Sr and SiO2, and lower MgO and 143Nd/144Nd. Most importantly, ascent paths control evolution: NEOT often erupt near the axis of the plain where high-flux (Yellowstone-related), pre-Holocene magmatic activity replaces granitic middle crust with basaltic sills, resulting in a net increase in NEOT magma buoyancy. COME flows erupt off-axis, where felsic crustal lithologies sometimes remain intact, providing a barrier to ascent and a source for crustal contamination. A three-stage ascent process explains the entire range of erupted compositions. Stage 1 (40-20 km): picrites are transported to the middle crust, undergoing partial crystallization of olivine + or - clinopyroxene. COME magmas pass through unarmored conduits and assimilate 1% or less of ancient gabbroic crust having high Sr and 87Sr/86Sr and low SiO2. Stage 2 (20-10 km): magmas are stored within the middle crust, and evolve to moderate MgO (10%). NEOT magmas, reaching 10% MgO, are positively buoyant and migrate through the middle crust. COME magmas remain negatively buoyant and so crystallize further and assimilate middle crust. Stage 3 (15-0 km): final ascent and eruption occurs when volatile contents, increased by differentiation, are sufficient (1-2 wt % H2O) to provide magma buoyancy through the

  1. Geochemistry and Minerality of Wine

    NASA Astrophysics Data System (ADS)

    Oze, C.; Horton, T. W.; Beaman, M.

    2010-12-01

    Kaolinite (Al2Si2O5(OH)4) and gibbsite (Al(OH)3) are capable of forming in a variety of environments including anthropogenic solutions such as wine. Here, we evaluate the geochemistry of twelve white wines in order to assess the potential relationship between kaolinite/gibbsite saturation and minerality, a common wine descriptor used to express the rock and/or soil character in the aromas and flavors of wines. Aluminum and Si concentrations ranged from 228-1,281 µg L-1 and 6,583-19,746 µg L-1, respectively, where Si and Al are the only elements to demonstrate positive covariance with minerality scores. Sulfur levels varied from 25,013-167,383 µg L-1 and show the strongest negative covariance with minerality scores. However, like all of the elements studied (Al, Si, Na, Mg, S, K, Ca, and Fe), these trends were not significantly different than random at the 95% confidence level. In contrast, the relative degrees of gibbsite/kaolinite saturation display strong positive covariance with minerality scores and these trends are not random at the greater than 95% confidence level. Overall, our tasters were able to accurately assess the degree of gibbsite/kaolinite saturation amongst the twelve wines based on the objective of assessing minerality. Although the wines were undersaturated with respect to gibbsite/kaolinite, geochemical modeling reveals that increasing the wines’ pHs from ~3.3 to 4.1-4.6 (which is achievable on the palate where saliva has a pH of 7.4) results in gibbsite/kaolinite oversaturation. By considering that minerality is a function of gibbsite/kaolinite saturation and decreasing S, the origin of minerality’s taste and chemical origin in wine with known physical standards becomes increasingly crystalline.

  2. Comparison of Magma Residence, Magma Ascent and Magma-Hydrothermal Interaction at EPR 9°N and Endeavour Segment

    NASA Astrophysics Data System (ADS)

    Michael, P. J.; Gill, J. B.; Ramos, F. C.

    2010-12-01

    We compare magmas’ temperatures (Mg#s), their degree of crustal assimilation (“excess” Chlorine) and their residence depth and ascent speed (dissolved CO2 content) at similar scales, using new data for Endeavour and new and published [1] data for EPR 9°N. We relate differences between the two segments to other differences, e.g., depth and width of the AMC reflector. Cl in glasses, and Cl/K or Cl/Nb ratios, are indicators of magma’s interaction with altered crust, probably at the roof of the AMC [1,2]. An excess Cl (in ppm) value for each glass can be calculated by subtracting mantle-derived Cl from measured Cl. At 9°N, excess Cl is negatively correlated with Mg#. Mg# is lower and excess Cl is higher off-axis (up to 4 km). At a given Mg#, Cl is higher off-axis [1]. Endeavour magmas on-axis have lower Mg# than EPR, while their ranges are similar off-axis. At Endeavour, there is no good correlation of excess Cl with Mg#, although glasses with high Mg# are found mostly on-axis. There is no trend of Mg# or excess Cl with distance from the axis. Excess Cl is similar on-axis between the two ridges. At both ridges, assimilation has a stochastic distribution, such that high- and low-Cl glasses are found in most locations. Because CO2 exsolution and bubble formation is slow compared to magma ascent and surface flow, many glasses are oversaturated compared to their eruption depth. Dissolved CO2 contents thus provide information about the duration of a magma’s transit between its last stopping point and final lava emplacement. If magma erupts and cools quickly, its dissolved CO2 should correspond to its last resting point, possibly the AMC. At EPR 9°N, maximum CO2 contents would be in equilibrium at the AMC roof, while minimum CO2 contents are nearly in equilibrium with collection depths. Glasses have high CO2 on-axis and low CO2 off-axis, and there is a negative correlation between CO2 and distance off-axis [1]. This is partly due to post-eruptive flow away from

  3. Zircons reveal magma fluxes in the Earth's crust.

    PubMed

    Caricchi, Luca; Simpson, Guy; Schaltegger, Urs

    2014-07-24

    Magma fluxes regulate the planetary thermal budget, the growth of continents and the frequency and magnitude of volcanic eruptions, and play a part in the genesis and size of magmatic ore deposits. However, because a large fraction of the magma produced on the Earth does not erupt at the surface, determinations of magma fluxes are rare and this compromises our ability to establish a link between global heat transfer and large-scale geological processes. Here we show that age distributions of zircons, a mineral often present in crustal magmatic rocks, in combination with thermal modelling, provide an accurate means of retrieving magma fluxes. The characteristics of zircon age populations vary significantly and systematically as a function of the flux and total volume of magma accumulated in the Earth's crust. Our approach produces results that are consistent with independent determinations of magma fluxes and volumes of magmatic systems. Analysis of existing age population data sets using our method suggests that porphyry-type deposits, plutons and large eruptions each require magma input over different timescales at different characteristic average fluxes. We anticipate that more extensive and complete magma flux data sets will serve to clarify the control that the global heat flux exerts on the frequency of geological events such as volcanic eruptions, and to determine the main factors controlling the distribution of resources on our planet.

  4. Post-Emplacement Behaviour of Magma Reservoirs

    NASA Astrophysics Data System (ADS)

    Roman, A. M.; Jaupart, C. P.

    2015-12-01

    For common crustal structures and melt compositions, basalts are buoyant in the lower crust and negatively buoyant in the upper crust. Intrusion and storage can occur at a depth or an interface where the density of magma becomes larger than that of the overlying rocks. After emplacement, magma density typically increases due to the formation of dense minerals. Fully solidified mafic bodies have bulk densities between 3000-3100 kg m-3 which are much higher than those of the continental rocks they intruded. This negative density contrast is much stronger than the positive one that drove magma ascent. We investigate the dynamical consequences of this marked buoyancy reversal using 3D laboratory experiments on viscous fluids and 2D numerical calculations with complex crustal rheologies. Material is emplaced at a density interface, such that its density is between those of the upper and lower layers. Its bulk density increases as temperature decreases and eventually exceeds that of the lower layer. We observe that the intrusion tends to spread laterally in an initial phase and to sag, and in some cases sink, in a later phase when its density exceeds that of the host. We identified two distinct instability modes. One consists of a single diapiric-like sinker and the other takes the form of spectacular nearly axisymmetric Rayleigh-Taylor-type downwellings. An intermediate mode consists of several long wavelength blobs which disrupt the initial symmetrical arrangement. The transition between the two modes is mainly determined by the aspect ratio of the intrusion at the onset of instability. Sagging can lead to full-fledged sinking to the base of the crust depending mainly on the temperature of country rocks. This proceeds over timescales that are relevant for true magmatic systems (in a range of a few kyr to a few Myr). At shallow crustal depths, cold temperatures and stiff country rocks are able to withstand the load of a large and dense intrusion. Significant post

  5. Experimental Constraints on a Vesta Magma Ocean

    NASA Technical Reports Server (NTRS)

    Hoff, C.; Jones, J. H.; Le, L.

    2014-01-01

    A magma ocean model was devised to relate eucrites (basalts) and diogenites (orthopyroxenites), which are found mixed together as clasts in a suite of polymict breccias known as howardites. The intimate association of eucritic and diogenitic clasts in howardites argues strongly that these three classes of achondritic meteorites all originated from the same planetoid. Reflectance spectral evidence (including that from the DAWN mission) has long suggested that Vesta is indeed the Eucrite Parent Body. Specifically, the magma ocean model was generated as follows: (i) the bulk Vesta composition was taken to be 0.3 CV chondrite + 0.7 L chondrite but using only 10% of the Na2O from this mixture; (ii) this composition is allowed to crystallize at 500 bar until approx. 80% of the system is solid olivine + low-Ca pyroxene; (iii) the remaining 20% liquid crystallizes at one bar from 1250C to 1110C, a temperature slightly above the eucrite solidus. All crystallization calculations were performed using MELTS. In this model, diogenites are produced by cocrystallization of olivine and pyroxene in the >1250C temperature regime, with Main Group eucrite liquids being generated in the 1300-1250C temperature interval. Low-Ca pyroxene reappears at 1210C in the one-bar calculations and fractionates the residual liquid to produce evolved eucrite compositions (Stannern Trend). We have attempted to experimentally reproduce the <1250C portion of the MELTS Vesta magma ocean. In the MELTS calculation, the change from 500 bar to one bar results in a shift of the olivine:low-Ca pyroxene boundary so that the 1250C liquid is now in the olivine field and, consequently, olivine should be the first-crystallizing phase, followed by low-Ca pyroxene at 1210C, and plagioclase at 1170C. Because at one bar the olivine:low-Ca pyroxene boundary is a peritectic, fractional crystallization of the 1210C liquid proceeds with only pyroxene crystallization until plagioclase appears. Thus, the predictions of the

  6. Magma mixing enhanced by bubble segregation

    NASA Astrophysics Data System (ADS)

    Wiesmaier, S.; Morgavi, D.; Renggli, C.; Perugini, D.; De Campos, C. P.; Hess, K.-U.; Ertel-Ingrisch, W.; Lavallée, Y.; Dingwell, D. B.

    2015-04-01

    That rising bubbles may significantly affect magma mixing paths has already been demon strated by analogue experiments. Here, for the first time, bubble-advection experiments are performed employing volcanic melts at magmatic temperatures. Cylinders of basaltic glass were placed below cylinders of rhyolite glass. Upon melting, interstitial air formed bubbles that rose into the rhyolite melt, thereby entraining tails of basaltic liquid. The formation of plume-like filaments of advected basalt within the rhyolite was characterized by microCT and subsequent high-resolution EMP analyses. Melt entrainment by bubble ascent appears to be an efficient mechanism for mingling volcanic melts of highly contrasting compositions and properties. MicroCT imaging reveals bubbles trailing each other and multiple filaments coalescing into bigger ones. Rheological modelling of the filaments yields viscosities of up to 2 orders of magnitude lower than for the surrounding rhyolitic liquid. Such a viscosity contrast implies that bubbles rising successively are likely to follow this pathway of low resistance that previously ascending bubbles have generated. Filaments formed by multiple bubbles would thus experience episodic replenishment with mafic material. Inevitable implications for the concept of bubble advection in magma mixing include thereby both an acceleration of mixing because of decreased viscous resistance for bubbles inside filaments and non-conventional diffusion systematics because of intermittent supply of mafic material (instead of a single pulse) inside a material. Inside the filaments, the mafic material was variably hybridised to andesitic through rhyolitic composition. Compositional profiles alone are ambiguous, however, to determine whether single or multiple bubbles were involved during formation of a filament. Statistical analysis, employing concentration variance as measure of homogenisation, demonstrates that also filaments appearing as single-bubble filaments

  7. Magma energy exploratory well Long Valley caldera, Mono County, California

    SciTech Connect

    Bender-Lamb, S.

    1991-04-01

    Intensive study of Long Valley over the past 15 years indicates evidence for magma at depths accessible to drilling. The Department of Energy's Magma Energy Extraction Program is currently drilling a 20,000 foot exploratory well into the Long Valley caldera. The purpose of this program is to determine the feasibility of producing electrical power from magma. If the magma energy experiment is successful, the Long Valley caldera could hypothetically supply the electrical power needs of California for 100 years at present power consumption rates. The paper describes calderas, the potential of geothermal energy, Long Valley geology, the Long Valley magma energy exploratory well, the four phases of the exploratory well drilling program, and Phase 1 results.

  8. Dynamic mixing in magma bodies - Theory, simulations, and implications

    NASA Technical Reports Server (NTRS)

    Oldenburg, Curtis M.; Spera, Frank J.; Yuen, David A.; Sewell, Granville

    1989-01-01

    The magma-mixing process is different from the mantle mixing process in that the mixing components of magma are dynamically active, with the melt density depending strongly on composition. This paper describes simulations of time-dependent variable-viscosity double-diffusive convection which were carried out to investigate quantitatively the mixing dynamics of magma in melt-dominated magma bodies. Results show that the dynamics of double-diffusive convection can impart complex patterns of composition, through time and space. The mixing time depends nonlinearly on many factors, including heat flux driving convection, the rate of diffusion of chemical species, the relative importance of thermal and chemical buoyancy, the viscosities of the mixing components, and the shape of the magma body.

  9. U.S. National Committee for Geochemistry

    ERIC Educational Resources Information Center

    Geotimes, 1974

    1974-01-01

    Reports highlights of the April, 1973 meeting of the U.S. National Committee for Geochemistry. Some of the topics reported on were: The Geophysics Research Board, deep drilling, exchange of geochemists with China and the activities of the Subcommittee on Geochemical Environment in Relation to Health and Disease. (BR)

  10. Source and magma mixing processes in continental subduction factory: Geochemical evidence from postcollisional mafic igneous rocks in the Dabie orogen

    NASA Astrophysics Data System (ADS)

    Dai, Li-Qun; Zhao, Zi-Fu; Zheng, Yong-Fei; Zhang, Juan

    2015-03-01

    derived from partial melting of the heterogeneously metasomatic mantle domains in the postcollisional stage. As a consequence, the source and magma mixing processes in the continental subduction factory are responsible for the significant variations in the whole-rock and mineral geochemistries of postcollisional mafic igneous rocks.

  11. Ponding Conditions and Degassing Dynamics of Mafic Magmas Beneath the Azores Islands

    NASA Astrophysics Data System (ADS)

    Metrich, N.; Zanon, V.; D'Oriano, C.

    2014-12-01

    The Azores archipelago is located at the triple junction between the North American, African and Eurasian plates, in an area dominated by transtensive tectonic. The magmatism is concentrated along elongated volcanic ridges, generally orthogonal to the Mid Atlantic Ridge (MAR), where central volcanoes alternate with fissure zones. In order to better understand the relationships between the regional and local tectonics and the magmatism, we carried out a systematic study of basaltic pyroclasts from monogenic Strombolian cones built up on both fissure zones and central volcanoes, on five Azores Islands. We combined the major and trace element geochemistry of bulk rocks, melt inclusions and minerals with microthermometric data of coexisting CO2-rich fluid inclusions. These latter, trapped in Fo88-82 olivines, reveal pressure decrease from west to east for each ridge, but the highest pressures are recorded by fluids trapped in mineral assemblage forming ultramafic cumulates (dunites, harzburgites and wehrlites). All these results fully confirm variable depths of the Moho Transition Zone (MTZ), which marks the upper limit for underplating and correspond to the magma ponding zones where the main processes of magmatic evolution occur. The MTZ is located at 25 km beneath Flores Island, on the North American plate, and 29.5 km beneath the island of São Miguel, 380 km eastward. It reaches a minimum (18.5 km depth) under Faial at ~120 km east of the MAR. In these pressure conditions, the volatile composition is XH2O =0.1 and XCO2=0.9, at 1155-1175 °C, under QFM redox conditions. The maximum dissolved volatile content achieves 1.8-1.9 wt% of H2O and 0.4-0.5 wt% of CO2 in the central archipelago, and 2.3-2.6 wt% of H2O and 0.8-1.0 wt% of CO2 at São Miguel. However, the total pressures (PCO2+PH2O) and the dissolved H2O content recorded by melt inclusions are commonly underestimated. The initial H2O content of the basaltic magmas characteristic of each volcanic system was re

  12. Magma heating by decompression-driven crystallization beneath andesite volcanoes.

    PubMed

    Blundy, Jon; Cashman, Kathy; Humphreys, Madeleine

    2006-09-01

    Explosive volcanic eruptions are driven by exsolution of H2O-rich vapour from silicic magma. Eruption dynamics involve a complex interplay between nucleation and growth of vapour bubbles and crystallization, generating highly nonlinear variation in the physical properties of magma as it ascends beneath a volcano. This makes explosive volcanism difficult to model and, ultimately, to predict. A key unknown is the temperature variation in magma rising through the sub-volcanic system, as it loses gas and crystallizes en route. Thermodynamic modelling of magma that degasses, but does not crystallize, indicates that both cooling and heating are possible. Hitherto it has not been possible to evaluate such alternatives because of the difficulty of tracking temperature variations in moving magma several kilometres below the surface. Here we extend recent work on glassy melt inclusions trapped in plagioclase crystals to develop a method for tracking pressure-temperature-crystallinity paths in magma beneath two active andesite volcanoes. We use dissolved H2O in melt inclusions to constrain the pressure of H2O at the time an inclusion became sealed, incompatible trace element concentrations to calculate the corresponding magma crystallinity and plagioclase-melt geothermometry to determine the temperature. These data are allied to ilmenite-magnetite geothermometry to show that the temperature of ascending magma increases by up to 100 degrees C, owing to the release of latent heat of crystallization. This heating can account for several common textural features of andesitic magmas, which might otherwise be erroneously attributed to pre-eruptive magma mixing.

  13. Magma heating by decompression-driven crystallization beneath andesite volcanoes.

    PubMed

    Blundy, Jon; Cashman, Kathy; Humphreys, Madeleine

    2006-09-01

    Explosive volcanic eruptions are driven by exsolution of H2O-rich vapour from silicic magma. Eruption dynamics involve a complex interplay between nucleation and growth of vapour bubbles and crystallization, generating highly nonlinear variation in the physical properties of magma as it ascends beneath a volcano. This makes explosive volcanism difficult to model and, ultimately, to predict. A key unknown is the temperature variation in magma rising through the sub-volcanic system, as it loses gas and crystallizes en route. Thermodynamic modelling of magma that degasses, but does not crystallize, indicates that both cooling and heating are possible. Hitherto it has not been possible to evaluate such alternatives because of the difficulty of tracking temperature variations in moving magma several kilometres below the surface. Here we extend recent work on glassy melt inclusions trapped in plagioclase crystals to develop a method for tracking pressure-temperature-crystallinity paths in magma beneath two active andesite volcanoes. We use dissolved H2O in melt inclusions to constrain the pressure of H2O at the time an inclusion became sealed, incompatible trace element concentrations to calculate the corresponding magma crystallinity and plagioclase-melt geothermometry to determine the temperature. These data are allied to ilmenite-magnetite geothermometry to show that the temperature of ascending magma increases by up to 100 degrees C, owing to the release of latent heat of crystallization. This heating can account for several common textural features of andesitic magmas, which might otherwise be erroneously attributed to pre-eruptive magma mixing. PMID:16957729

  14. Transition from magma dominant to magma poor rifting along the Nova Scotia Continental Margin

    NASA Astrophysics Data System (ADS)

    Lau, K. H.; Louden, K. E.; Nedimović, M. R.; Whitehead, M.; Farkas, A.; Watremez, L.; Dehler, S. A.

    2011-12-01

    Passive margins have been characterized as magma-dominant (volcanic) or magma-poor (non-volcanic). However, the conditions under which margins might switch states are not well understood as they typically have been studied as end member examples in isolation to each other. The Nova Scotia (NS) continental margin, however, offers an opportunity to study the nature of such a transition between the magma-dominant US East Coast margin to the south and the magma-poor Newfoundland margin to the north within a single rift segment. This transition is evidenced by a clear along-strike reduction in features characteristic of syn-rift volcanism from south-to-north along the NS margin, such as the weakening of the East Coast Magnetic Anomaly (ECMA) and the coincident disappearance of seaward dipping reflector sequences (SDRS) on multichannel seismic (MCS) reflection profiles. Results from recent industry MCS profiles along and across the margin suggest a potentially narrow magma-dominant to magma-poor along-strike transition between the southern and the central NS margin. Such a transition is broadly consistent with results of several widely-spaced, across-strike ocean bottom seismometer (OBS) wide-angle profiles. In the southern region, the crustal structure exhibits a narrow (~120-km wide) ocean-continent transition (OCT) with a high velocity (7.2 km/s) lower crust, interpreted as a gabbro-rich underplated melt, beneath the SDRS and the ECMA, similar to crustal models across the US East Coast. In contrast, profiles across the central and northern margin contain a much wider OCT (150-200-km wide) underlain by a low velocity mantle layer (7.3-7.9 km/s), interpreted as partially serpentinized olivine, which is similar to the magma-poor Newfoundland margin to the north. However, the central-to-northern OBS profiles also exhibit significant variations within the OCT and the along-strike continuity of these OCT structures is not yet clear. In November 2010, we acquired, in the

  15. Session 6: Magma Energy: Engineering Feasibility of Energy Extraction from Magma Bodies

    SciTech Connect

    Traeger, R.K.

    1983-12-01

    Extensive quantities of high-quality energy are estimated to be available from molten magma bodies existing within 10 Km of the US continent's surface. A five-year study sponsored by DOE/BES demonstrated that extraction of energy from these melts was scientifically feasible. The next stage of assessment is to evaluate the engineering feasibility of energy extraction and provide a preliminary economic evaluation. Should the second step demonstrate engineering feasibility, the third step would include detailed economic, market and commercialization endeavors. Evaluation of the engineering feasibility will be initiated in FY 84 in a program supported by DOE/GHTD and managed by Dave Allen. The project will be managed by Sandia Labs in James Kelsey's Geothermal Technology Development Division. The project will continue to draw on expertise throughout the country, especially the scientific base established in the previous BES Magma Energy Program.

  16. Intrusion of granitic magma into the continental crust facilitated by magma pulsing and dike-diapir interactions: Numerical simulations

    NASA Astrophysics Data System (ADS)

    Cao, Wenrong; Kaus, Boris J. P.; Paterson, Scott

    2016-06-01

    We conducted a 2-D thermomechanical modeling study of intrusion of granitic magma into the continental crust to explore the roles of multiple pulsing and dike-diapir interactions in the presence of visco-elasto-plastic rheology. Multiple pulsing is simulated by replenishing source regions with new pulses of magma at a certain temporal frequency. Parameterized "pseudo-dike zones" above magma pulses are included. Simulation results show that both diking and pulsing are crucial factors facilitating the magma ascent and emplacement. Multiple pulses keep the magmatic system from freezing and facilitate the initiation of pseudo-dike zones, which in turn heat the host rock roof, lower its viscosity, and create pathways for later ascending pulses of magma. Without diking, magma cannot penetrate the highly viscous upper crust. Without multiple pulsing, a single magma body solidifies quickly and it cannot ascent over a long distance. Our results shed light on the incremental growth of magma chambers, recycling of continental crust, and evolution of a continental arc such as the Sierra Nevada arc in California.

  17. Fractionation products of basaltic komatiite magmas at lower crustal pressures: implications for genesis of silicic magmas in the Archean

    NASA Astrophysics Data System (ADS)

    Mandler, B. E.; Grove, T. L.

    2015-12-01

    Hypotheses for the origin of crustal silicic magmas include both partial melting of basalts and fractional crystallization of mantle-derived melts[1]. Both are recognized as important processes in modern environments. When it comes to Archean rocks, however, partial melting hypotheses dominate the literature. Tonalite-trondhjemite-granodiorite (TTG)-type silicic magmas, ubiquitous in the Archean, are widely thought to be produced by partial melting of subducted, delaminated or otherwise deeply buried hydrated basalts[2]. The potential for a fractional crystallization origin for TTG-type magmas remains largely unexplored. To rectify this asymmetry in approaches to modern vs. ancient rocks, we have performed experiments at high pressures and temperatures to closely simulate fractional crystallization of a basaltic komatiite magma in the lowermost crust. These represent the first experimental determinations of the fractionation products of komatiite-type magmas at elevated pressures. The aim is to test the possibility of a genetic link between basaltic komatiites and TTGs, which are both magmas found predominantly in Archean terranes and less so in modern environments. We will present the 12-kbar fractionation paths of both Al-depleted and Al-undepleted basaltic komatiite magmas, and discuss their implications for the relative importance of magmatic fractionation vs. partial melting in producing more evolved, silicic magmas in the Archean. [1] Annen et al., J. Petrol., 47, 505-539, 2006. [2] Moyen J-F. & Martin H., Lithos, 148, 312-336, 2012.

  18. A decadal view of magma fragmentation

    NASA Astrophysics Data System (ADS)

    Cashman, K. V.; Rust, A.

    2010-12-01

    Although the past decade has seen fundamental advances in studies of explosive volcanism, the disruption to air traffic caused by the 2010 eruption of Eyjafjallajökull, Iceland, highlights the need for improved understanding of magmatic fragmentation in general, and of fine ash generation in particular. To develop a theoretical basis for predicting the fine ash content of eruptive plumes, we need to understand not only fragmentation mechanisms but also the dependence of those mechanisms on conditions of magma ascent and degassing. Experimental and analytical approaches to this problem include experimental studies of vesiculation and permeability development in silicic melts, quantitative textural studies of pyroclasts to constrain conditions that reduce fragmentation efficiency (that is, allow vesicular clasts to be preserved), direct experiments on fragmentation in both natural and analog materials, and determination of total grain size distributions (TGSDs) of pyroclastic deposits. Experiments on silicic melts have demonstrated that very high supersaturations (overpressures ΔP) may be achieved in silicic melts prior to homogeneous bubble nucleation, and that the high bubble number densities of silicic pumice require not only homogeneous nucleation but also nucleation of a mixed H2O-CO2 gas phase. In most pumice and scoria clasts, resulting vesicle populations form power law size distributions; power law exponents >3 in silicic tephras indicate that small vesicles comprise most of the vesicle volume (consistent with rapid late-stage vesiculation at high ΔP), while exponents < 3 in mafic tephras show that larger bubbles are volumetrically dominant and may reflect extensive bubble coalescence prior to fragmentation. Modal vesicularites of pyroclasts are typically high (> 60-70%) and show no dependence on either melt composition or mass eruption rate; this suggests that melt porosity is more important than either decompression rate or magma rheology for clast

  19. Chemical diffusion during isobaric degassing of magma

    NASA Astrophysics Data System (ADS)

    von Aulock, Felix W.; Kennedy, Ben M.; Lavallée, Yan; Henton-de Angelis, Sarah; Oze, Christopher; Morgan, Daniel J.; Clesham, Steve

    2014-05-01

    During ascent of magma, volatiles exsolve and bubbles form. Volatiles can either escape through a permeable network of bubbles in an open system or be trapped in non-connected pores during closed system degassing. Geochemical studies have shown that in most cases both- open system and closed system degassing take place at the same time. During cooling of the melt, diffusion slows down and eventually diffusional gradients get frozen in, preserving a history of degassing and rehydration during bubble growth, bubble collapse and crystal growth. We present data from experiments in which natural obsidian was degassed at atmospheric pressures at 950ºC over timescales of 3-24h. During bubble growth, a skin formed, at the outer edge of the sample, effectively prohibiting any degassing of its interior. Diffusion gradients were measured across the glass surrounding vesicles, and across this impermeable skin. Water contents were analyzed with synchrotron sourced Fourier transform infrared spectroscopy and several major, minor and trace elements were mapped using synchrotron sourced X-ray fluorescence spectroscopy. The samples show a dimpled surface, as well as signs of oxidation and growth of submicroscopic crystals. Water contents around bubbles decrease in simple heating experiments (from ~0.13 wt. % down to ~0.1 wt. %), whereas slight rehydration of the vesicle wall can be observed when a second, cooler step at 850ºC follows the initial 950ºC. Water gradients towards the outside of the sample decrease linearly to a minimum of ~0.045 wt. %, far below the solubility of water in melts at these temperatures. We mapped the distribution of K, Ca, Fe, Ti, Mn, Rb, Sr, Y and Zr. Especially the trace elements show a decrease towards the outside of the sample, whereas K, Fe, Ca and Ti generally do not show significant partitioning between melt and gas/crystal phase. Several effects could attribute to the distribution of these elements, such as the crystal growth and exchange with

  20. Iron geochemistry of the mantle

    NASA Astrophysics Data System (ADS)

    Humayun, M.; Campbell, T. J.; Brandon, A. D.; Davis, F. A.; Hirschmann, M. M.

    2011-12-01

    The Fe/Mg ratio is an important constraint on the compositionally controlled density of the mantle. However, this ratio cannot be inferred from erupted lavas from OIB or MORB sources, but must be determined directly from mantle peridotites. Recently, the Fe/Mn ratio of erupted lavas has been used as an indicator of potential Fe variability in the mantle driven by core-mantle interaction, recycled oceanic crust, or even variations in the temperature of mantle melting. The classic compilation of McDonough & Sun (1995) provided the currently accepted Fe/Mn ratio of the upper mantle, 60±10. The uncertainty on this ratio allows for 15-30% variability in mantle iron abundances, which is equivalent to a density variation larger than observed by seismic tomography in the mantle. To better understand the relationship between mantle peridotites and erupted lavas, and to search for real variability in the Fe/Mn ratio of mantle peridotites, we report precise new ICP-MS measurements of the transition element geochemistry of suites of mantle xenoliths that have known Fe/Mg ratios. For 12 Kilbourne Hole xenoliths, we observe a clear correlation between Fe/Mn and MgO (or Fe/Mg) over an Fe/Mn range of 59-72. Extrapolation of this trend to a Primitive Mantle (PM) MgO content of 37.8 yields an Fe/Mn of 59±1 for the PM. Our new analyses of KLB-1 powder and fused glass beads yield an Fe/Mn of 61.4 for both samples, which plots on the Kilbourne Hole Fe/Mn vs. MgO trend. A set of ten xenoliths from San Carlos yield a wide range of Fe/Mn (56-65) not correlated with MgO content. The San Carlos xenoliths may have experienced a metasomatic effect that imprinted variable Fe/Mn. A clinopyroxene-rich lithology from San Carlos yields an Fe/Mn of 38, which plots on an extension of the Kilbourne Hole Fe/Mn vs. MgO trend. These new results, and those from other xenolith localities being measured in our lab, provide new constraints on the compositional variability of the Earth's upper mantle. Mc

  1. Crystal Histories and Crustal Magmas: Insights into Magma Storage from U-Series Crystal Ages

    NASA Astrophysics Data System (ADS)

    Cooper, K. M.

    2014-12-01

    The dynamic processes operating within crustal magma reservoirs control many aspects of the chemical composition of erupted magmas, and crystals in volcanic rocks can provide a temporally-constrained archive of these changing environments. A new compilation of 238U-230Th ages of accessory phases and 238U-230Th-226Ra ages of bulk mineral separates of major phases documents that crystals in individual samples often have ages spanning most of the history of a volcanic center. Somewhat surprisingly, this observation holds for surface analyses as well as interior analyses, indicating that the latest stages of growth took place at different times for different grains. Nevertheless, average ages of surfaces are younger than interiors (as expected), and the dominant surface age population is often within error of eruption age. In contrast to accessory phase ages, less than half of the bulk separate 238U-230Th-226Ra ages for major phases are more than 10 kyr older than eruption. This suggests that major phases may in general reflect a later stage of development of an eruptible magma body than do accessory phases, or that the extent of discordance between ages of major and accessory phases reflects the extent to which a crystal mush was remobilized during processes leading to eruption. Crystal ages are most useful for illuminating magmatic processes when combined with crystal-scale trace-element or isotopic data, and I will present several case studies where such combined data sets exist. For example, at Yellowstone and at Okataina Caldera Complex, New Zealand, the combination zircon surface and interior analyses (of age, Hf isotopic, and trace-element data) with bulk dating and in-situ trace-element and isotopic compositions of feldspar allows a comparison of the early history of storage in a crystal mush with the later history of melt extraction and further crystallization prior to eruption, thus tracking development of erupted magma bodies from storage through eruption.

  2. Magma at depth: A retrospective analysis of the 1975 unrest at Mount Baker, Washington, USA

    USGS Publications Warehouse

    Crider, Juliet G.; Frank, David; Malone, Stephen D.; Poland, Michael P.; Werner, Cynthia; Caplan-Auerbach, Jacqueline

    2011-01-01

    Mount Baker volcano displayed a short interval of seismically-quiescent thermal unrest in 1975, with high emissions of magmatic gas that slowly waned during the following three decades. The area of snow-free ground in the active crater has not returned to pre-unrest levels, and fumarole gas geochemistry shows a decreasing magmatic signature over that same interval. A relative microgravity survey revealed a substantial gravity increase in the ~30 years since the unrest, while deformation measurements suggest slight deflation of the edifice between 1981-83 and 2006-07. The volcano remains seismically quiet with regard to impulsive volcano-tectonic events, but experiences shallow (10 km) long-period earthquakes. Reviewing the observations from the 1975 unrest in combination with geophysical and geochemical data collected in the decades that followed, we infer that elevated gas and thermal emissions at Mount Baker in 1975 resulted from magmatic activity beneath the volcano: either the emplacement of magma at mid-crustal levels, or opening of a conduit to a deep existing source of magmatic volatiles. Decadal-timescale, multi-parameter observations were essential to this assessment of magmatic activity.

  3. Insights into Magma Evolution in the Islands of the Four Mountains, Alaska

    NASA Astrophysics Data System (ADS)

    Fulton, A. A.; Izbekov, P. E.; Nicolaysen, K. P.

    2015-12-01

    The Islands of the Four Mountains (IFM) is a group of small volcanoes in the central region of Alaska's Aleutian island arc. There are few studies of this remote group of islands despite their rich archeological history and diverse eruptive histories. This study focuses on silicic deposits from the IFM to shed light on the area's history of large explosive eruptions and the IFM's chemical relationship to the rest of the central Aleutian Islands. This study applies whole rock geochemistry, detailed petrographic analysis, and electron microprobe analysis to samples of volcanic deposits from Tana, Cleveland, Carlisle, and Herbert volcanoes, including the first documented ignimbrite deposit in the IFM, found on northern Tana. The IFM lavas range from basaltic to dacitic and follow typical island arc and calc-alkaline chemical trends, providing evidence of high aqueous fluid input to the mantle wedge, as well as varying levels of influence from subducted sediments. Tana, the largest (~12 km2) and most siliceous of the IFM volcanoes, expresses anomalies in K and Rb concentrations that may aid in the refinement of the continental-oceanic crust boundary location along the Aleutian arc. Plagioclase phenocryst disequilibrium textures and compositions provide evidence of mixing and recharge in the IFM magma chambers. Multiple plagioclase phenocryst populations, euhedral pyroxene crystals in disequilibrium with the melt, and angular xenolithic clasts in the Tana ignimbrite suggest a rapid mixing and heating event that triggered its large explosive eruption during the Pleistocene.

  4. Magma at depth: a retrospective analysis of the 1975 unrest at Mount Baker, Washington, USA

    NASA Astrophysics Data System (ADS)

    Crider, Juliet G.; Frank, David; Malone, Stephen D.; Poland, Michael P.; Werner, Cynthia; Caplan-Auerbach, Jacqueline

    2011-03-01

    Mount Baker volcano displayed a short interval of seismically-quiescent thermal unrest in 1975, with high emissions of magmatic gas that slowly waned during the following three decades. The area of snow-free ground in the active crater has not returned to pre-unrest levels, and fumarole gas geochemistry shows a decreasing magmatic signature over that same interval. A relative microgravity survey revealed a substantial gravity increase in the ~30 years since the unrest, while deformation measurements suggest slight deflation of the edifice between 1981-83 and 2006-07. The volcano remains seismically quiet with regard to impulsive volcano-tectonic events, but experiences shallow (<3 km) low-frequency events likely related to glacier activity, as well as deep (>10 km) long-period earthquakes. Reviewing the observations from the 1975 unrest in combination with geophysical and geochemical data collected in the decades that followed, we infer that elevated gas and thermal emissions at Mount Baker in 1975 resulted from magmatic activity beneath the volcano: either the emplacement of magma at mid-crustal levels, or opening of a conduit to a deep existing source of magmatic volatiles. Decadal-timescale, multi-parameter observations were essential to this assessment of magmatic activity.

  5. Roman comagmatic province (central Italy): evidence for subduction-related magma genesis

    SciTech Connect

    Peccerillo, A.

    1985-02-01

    Geochemical data on mafic volcanics show that important affinities exist between the Roman and the calc-alkaline rocks from the Aeolian arc (south Tyrrhenian Sea). These affinities, together with the close association of calc-alkaline and K-rich volcanics in the Aeolian arc and in the Naples area, the continuity in the variation of abundances of incompatible elements from calc-alkaline to potassic suites, and the similarity in terms of major-element geochemistry, support a genetic relationship of the Roman magmatism and the subduction processes that affected the Apennines in Tertiary time and are still active under the Aeolian arc. In the genetic model presented here, both calc-alkaline and K-rich magmas were generated within a mantle heterogenously enriched in LIL elements. Composition of the mantle was modified by addition of material, probably sediments, dragged down by the undergoing slab. The geochemical and petrological differences displayed by the calc-alkaline and K-rich volcanics are accounted for by the different conditions of melting as well as by chemical and isotopic heterogeneities of the source. 26 references, 3 figures, 1 table.

  6. The Perils of Partition: Erroneous Results from Applying D Mineral/Magma to Rocks that Equilibrated Without Magma

    NASA Astrophysics Data System (ADS)

    Treiman, A. H.

    1995-09-01

    Compositions of extraterrestrial magmas are commonly derived from mineral compositions using, using experimentally determined mineral/basalt partition coefficients, Dmineral/basalt [1]. However, Dmineral/basalts cannot be applied to minerals which have experienced post-magmatic (subsolidus or metamorphic) chemical equilibration [2]. A failure to recognize post-magmatic equilibration can lead to wildly erroneous estimates of magma compositions and unrealistic scenarios of magmatic and planetary evolution [3]. To judge the effects of subsolidus chemical equilibration, consider REE distributions in a eucrite basalt, formed from a magma with CREE = 10 x CI. Let this magma crystallize and chemically equilibrate just below its solidus to a rock consisting of 49.5% plagioclase, 49.5% pigeonite, 0.1% whitlockite (a Ca phosphate), and 0.9% minor phases no REE content (silica, Fe metal, troilite); exact proportions are not critical. The total REE content ofthe rock is unchanged at 10 x CI, and distributions of REE among its minerals can be calculated from solidus-temperature Ds, e.g., Dpigeonite/plagioclase = Dpigeonite/basalt / Dplagioclase/basalt (where Dmineral/basalts are chosen to reflect the same magma compositions and temperature). REE abundances in minerals of this equilibrated rock (Figure 1 [5]) are significantly higher than they would be in the presence of magma. For instance, if this eucrite basalt system consisted of 50% magma, 25% pigeonite, and 25% plagioclase, one calculates C(La)Pigeonite = 0 04 x CI and C(La)Plagioclase = 0.8 x CI; with no magma present (Figure 1), C(La)Pigeonite = 0.4 x CI and CLaPIagioclase = 9 x CI! In the absence of magma, the incompatible REE must go somewhere!! If a mineral grain from this rock were used with Dmineral/basalts to derive a magma composition, that "Hparent basalt" would be rich in REE (130-200 x CI), enrichmed in light REE (La/Lu = 1.6 x CI), and strongly depleted in Eu. Compare this to the original eucrite, with REE at

  7. Solidifying the lunar magma ocean: Model results and geochronology (Invited)

    NASA Astrophysics Data System (ADS)

    Elkins-Tanton, L. T.; Burgess, S. D.; Meyer, J.; Wisdom, J.

    2009-12-01

    The Moon is posited to have formed by reconsolidation of materials produced during a giant impact with the Earth early in solar system evolution. The young Moon appears to have experienced a magma ocean of some depth, which resulted in the formation of an anorthosite flotation crust. There is no simple way to reconcile W-Hf results for the age of Moon formation, U-Pb and Sm-Nd ages of lunar crustal crystallization, and modeling results for magma ocean solidification. At the beginning of magma ocean solidification the dense iron- and magnesium-rich phases crystallizing from the cooling magma are believed to have sunk to the bottom of the magma ocean. When approximately 80% of the lunar magma ocean solidified, anorthite began to crystallize and float upward through the more dense magma ocean liquid; anorthite will continue to be added to this flotation crust until the last dregs of the magma ocean solidify. The crystallization times of the anorthite in the flotation crust, therefore, could span the range from about 80% solidification to what has been interpreted as the lunar magma ocean solidification age. Models including convection in the remaining magma ocean, conduction through the growing anorthosite lid, and radiation into space indicate that the magma ocean may freeze to the point of anorthosite formation in less than 104 years, and perhaps as little as 103 years. After this brief free-surface cooling period the growth of the anorthosite lid radically slows heat loss, and complete solidification of the magma ocean will require additional tens of millions of years. Young anorthosite crustal ages, far younger than models would predict possible, may be explained by further investigations into the evolution of the lunar orbit. Tidal heating of the anorthosite crust as the young Moon experiences a period of high eccentricity may delay closure of minerals with radiogenic phases; these late-closing minerals will then yield young ages, though they originally formed

  8. Limits to magma mixing based on chemistry and mineralogy of pumice fragments erupted from a chemically zoned magma body

    SciTech Connect

    Vogel, T.A.; Ryerson, F.J.; Noble, D.C.; Younker, L.W.

    1987-09-01

    The chemical variation among pumice fragments from the Pahute Mesa Member of the Thirsty Canyon Tuff (Black Mountain volcanic center, southwestern Nevada) is consistent with magma withdrawal from a chemically zoned magma body. The top of this magma body contained little chemical variations, the lowest concentration of light REEs, and the highest concentrations of SiO/sub 2/, heavy REEs, and Th. The pumice fragments derived from the top of the magma body contain nearly pure ferrohedenbergite and fayalite. The next discrete zone in the magma body contained lower SiO/sub 2/, heavy REEs, and Th concentrations, and very high concentrations of light REEs. The lowest erupted layer contained relatively low concentrations of SiO/sub 2/, Th, and light and heavy REEs. Pumice fragments with polymodal disequilibrium phenocryst populations are a priori evidence of magma mixing. The magma mixing process is constrained by: the systematic vertical distribution of chemically distinct pumice fragments throughout the ash-flow sheet; the presence of disequilibrium phenocrysts within some pumice fragments in all but the lowermost part of the sheet; and the presence of compositionally uniform glass in most pumice fragments, including those with widely varying phenocryst compositions. Negligible mixing occurred at the top of the magma body; limited mixing occurred in the second and third layers. Because mixing did not destroy the original layering, the amount of guest magma must have been small. In order for unzoned disequilibrium phenocrysts to not become zoned, they must have been preserved in the magma body only a short time. And yet, in order to produce the homogeneous liquid that surrounds these phenocrysts, mechanical mixing must have been very efficient. 44 references.

  9. A glassy lava flow from Toconce volcano and its relation with the Altiplano-Puna Magma Body in Central Andes

    NASA Astrophysics Data System (ADS)

    Godoy, B.; Rodriguez, I.; Aguilera, F.

    2012-12-01

    Toconce is a composite stratovolcano located at the San Pedro - Linzor volcanic chain (SPLVC). This volcanic chain distributes within the Altiplano-Puna region (Central Andes) which is characterized by extensive rhyodacitic-to-rhyolitic ignimbritic fields, and voluminous domes of dacitic-to-rhyolitic composition (de Silva, 1989). The felsic melts that gave origin to ignimbrites and domes at this area were generated by mixing of mantle-derived magmas and anatectic melts assimilated during their ascent through the thick crust. Thus, partially molten layers exist in the upper crust below the APVC (de Silva et al., 2006). Evidence of large volumes of such melts has been also proposed by geophysical methods (i.e. the Altiplano-Puna Magma Body; Chmielowsky et al., 1999) In this work, petrography and whole rock, mineralogical and melt inclusions geochemistry of a glassy lava flow of Toconce volcano are presented. Petrographically, this lava flow shows a porphyric texture, with euhdral to subhedral plagioclase, ortho- and clino-pyroxene phenocrysts immersed in a glassy groundmass. Geochemically, the lava flow has 64.7% wt. SiO2. The glassy groundmass (~70% wt. SiO2) is more felsic than all the lavas in the volcanic chain (47-68% wt., Godoy et al., 2011). Analyzed orthopyroxene-hosted melt inclusions show an even higher SiO2 content (72-75% wt.), and a decreasing on Al2O3, Na2O, and CaO content with differentiation. Crystallization pressures of this lava flow, obtained using Putirka's two-pyroxene and clinopyroxene-liquid models (Putirka, 2008), range between 6 and 9 kbar. According to crystallization pressures, and major element composition, a felsic source located at shallow crustal pressures - where plagioclase is a stable mineralogical phase - originated the inclusions. This could be related to the presence of the Altiplano-Puna Magma Body (APMB) located below SPLVC. On the other hand, glassy groundmass, and disequilibrium textures in minerals of this lava flow could

  10. Forecasting magma-chamber rupture at Santorini volcano, Greece

    NASA Astrophysics Data System (ADS)

    Browning, John; Drymoni, Kyriaki; Gudmundsson, Agust

    2015-10-01

    How much magma needs to be added to a shallow magma chamber to cause rupture, dyke injection, and a potential eruption? Models that yield reliable answers to this question are needed in order to facilitate eruption forecasting. Development of a long-lived shallow magma chamber requires periodic influx of magmas from a parental body at depth. This redistribution process does not necessarily cause an eruption but produces a net volume change that can be measured geodetically by inversion techniques. Using continuum-mechanics and fracture-mechanics principles, we calculate the amount of magma contained at shallow depth beneath Santorini volcano, Greece. We demonstrate through structural analysis of dykes exposed within the Santorini caldera, previously published data on the volume of recent eruptions, and geodetic measurements of the 2011-2012 unrest period, that the measured 0.02% increase in volume of Santorini’s shallow magma chamber was associated with magmatic excess pressure increase of around 1.1 MPa. This excess pressure was high enough to bring the chamber roof close to rupture and dyke injection. For volcanoes with known typical extrusion and intrusion (dyke) volumes, the new methodology presented here makes it possible to forecast the conditions for magma-chamber failure and dyke injection at any geodetically well-monitored volcano.

  11. Forecasting magma-chamber rupture at Santorini volcano, Greece.

    PubMed

    Browning, John; Drymoni, Kyriaki; Gudmundsson, Agust

    2015-10-28

    How much magma needs to be added to a shallow magma chamber to cause rupture, dyke injection, and a potential eruption? Models that yield reliable answers to this question are needed in order to facilitate eruption forecasting. Development of a long-lived shallow magma chamber requires periodic influx of magmas from a parental body at depth. This redistribution process does not necessarily cause an eruption but produces a net volume change that can be measured geodetically by inversion techniques. Using continuum-mechanics and fracture-mechanics principles, we calculate the amount of magma contained at shallow depth beneath Santorini volcano, Greece. We demonstrate through structural analysis of dykes exposed within the Santorini caldera, previously published data on the volume of recent eruptions, and geodetic measurements of the 2011-2012 unrest period, that the measured 0.02% increase in volume of Santorini's shallow magma chamber was associated with magmatic excess pressure increase of around 1.1 MPa. This excess pressure was high enough to bring the chamber roof close to rupture and dyke injection. For volcanoes with known typical extrusion and intrusion (dyke) volumes, the new methodology presented here makes it possible to forecast the conditions for magma-chamber failure and dyke injection at any geodetically well-monitored volcano.

  12. Forecasting magma-chamber rupture at Santorini volcano, Greece

    PubMed Central

    Browning, John; Drymoni, Kyriaki; Gudmundsson, Agust

    2015-01-01

    How much magma needs to be added to a shallow magma chamber to cause rupture, dyke injection, and a potential eruption? Models that yield reliable answers to this question are needed in order to facilitate eruption forecasting. Development of a long-lived shallow magma chamber requires periodic influx of magmas from a parental body at depth. This redistribution process does not necessarily cause an eruption but produces a net volume change that can be measured geodetically by inversion techniques. Using continuum-mechanics and fracture-mechanics principles, we calculate the amount of magma contained at shallow depth beneath Santorini volcano, Greece. We demonstrate through structural analysis of dykes exposed within the Santorini caldera, previously published data on the volume of recent eruptions, and geodetic measurements of the 2011–2012 unrest period, that the measured 0.02% increase in volume of Santorini’s shallow magma chamber was associated with magmatic excess pressure increase of around 1.1 MPa. This excess pressure was high enough to bring the chamber roof close to rupture and dyke injection. For volcanoes with known typical extrusion and intrusion (dyke) volumes, the new methodology presented here makes it possible to forecast the conditions for magma-chamber failure and dyke injection at any geodetically well-monitored volcano. PMID:26507183

  13. Earth's Mantle as the Product of Magma Ocean Solidification (Invited)

    NASA Astrophysics Data System (ADS)

    Elkins-Tanton, L. T.; Tikoo, S. M.; Brown, S. M.

    2013-12-01

    Large accretionary impacts on rocky planets have long been thought to produce partial or even complete melting of the growing planet. Models indicate that these magma oceans may solidify extremely fast, on the order of a million years or less, and thus production and freezing of magma oceans is likely to occur several times during the growth of a young planet, though solidification could be delayed by a thick atmosphere or by heating from the young star. Many questions persist about how magma oceans solidify. Do they crystallize fractionally or in bulk? Under what conditions would quench crusts occur, and do they substantially change the solidification timescale or chemical differentiation? Can bubbles efficiently escape a convecting magma ocean? Models can predict the geochemical consequences of different scenarios, and increasingly, geochemical evidence can be compared to model results. New noble gas geochemical evidence from the Earth supports the multiple magma ocean model, and other isotopic evidence supports fractional solidification of at least the last magma ocean. We will present models and geochemical evidence for magma ocean solidification on the Earth, and discuss ramifications for early convective vigor, water content of the mantle, and the onset of plate tectonics.

  14. Forecasting magma-chamber rupture at Santorini volcano, Greece.

    PubMed

    Browning, John; Drymoni, Kyriaki; Gudmundsson, Agust

    2015-01-01

    How much magma needs to be added to a shallow magma chamber to cause rupture, dyke injection, and a potential eruption? Models that yield reliable answers to this question are needed in order to facilitate eruption forecasting. Development of a long-lived shallow magma chamber requires periodic influx of magmas from a parental body at depth. This redistribution process does not necessarily cause an eruption but produces a net volume change that can be measured geodetically by inversion techniques. Using continuum-mechanics and fracture-mechanics principles, we calculate the amount of magma contained at shallow depth beneath Santorini volcano, Greece. We demonstrate through structural analysis of dykes exposed within the Santorini caldera, previously published data on the volume of recent eruptions, and geodetic measurements of the 2011-2012 unrest period, that the measured 0.02% increase in volume of Santorini's shallow magma chamber was associated with magmatic excess pressure increase of around 1.1 MPa. This excess pressure was high enough to bring the chamber roof close to rupture and dyke injection. For volcanoes with known typical extrusion and intrusion (dyke) volumes, the new methodology presented here makes it possible to forecast the conditions for magma-chamber failure and dyke injection at any geodetically well-monitored volcano. PMID:26507183

  15. MAGMA: analysis of two-channel microarrays made easy.

    PubMed

    Rehrauer, Hubert; Zoller, Stefan; Schlapbach, Ralph

    2007-07-01

    The web application MAGMA provides a simple and intuitive interface to identify differentially expressed genes from two-channel microarray data. While the underlying algorithms are not superior to those of similar web applications, MAGMA is particularly user friendly and can be used without prior training. The user interface guides the novice user through the most typical microarray analysis workflow consisting of data upload, annotation, normalization and statistical analysis. It automatically generates R-scripts that document MAGMA's entire data processing steps, thereby allowing the user to regenerate all results in his local R installation. The implementation of MAGMA follows the model-view-controller design pattern that strictly separates the R-based statistical data processing, the web-representation and the application logic. This modular design makes the application flexible and easily extendible by experts in one of the fields: statistical microarray analysis, web design or software development. State-of-the-art Java Server Faces technology was used to generate the web interface and to perform user input processing. MAGMA's object-oriented modular framework makes it easily extendible and applicable to other fields and demonstrates that modern Java technology is also suitable for rather small and concise academic projects. MAGMA is freely available at www.magma-fgcz.uzh.ch. PMID:17517778

  16. Timing and mechanisms of mafic magma ascent/emplacement in the continental middle crust: an example from the Permian Sondalo gabbroic complex (Alps, N-Italy)

    NASA Astrophysics Data System (ADS)

    Petri, Benoît; Mohn, Geoffroy; Skrzypek, Etienne; Mateeva, Tsvetomila; Galster, Federico; Robion, Philippe; Schulmann, Karel; Manatschal, Gianreto; Müntener, Othmar

    2015-04-01

    We explore the mechanisms of mafic magma ascent and emplacement in the continental crust by studying the mid-crustal Permian Sondalo gabbroic complex (Campo unit, Eastern Central Alps, N-Italy). We characterized the structure and anisotropy of magnetic susceptibility (AMS) fabric of the concentric gabbroic to dioritic intrusions. We used Laser Ablation ICP-MS U-Pb zircon dating on magmatic and metamorphic rock samples, zircon trace element geochemistry and existing P-T estimates to constrain the timing and depth of magma emplacement. Petrological and geochemical observations provide insights on the crystallization sequence in the magmatic rocks and facilitate the interpretation of the AMS record. The magmatic and magnetic fabrics (foliations and lineations) of the pluton reflect their original orientations and are essentially vertical, indicating vertical magma transfer through the crust. The intrusion was emplaced in two phases. (1) The concordant orientation between the main magmatic foliation and the host-rock xenoliths elongation and foliation in the centre of the pluton suggest that the first magma ascent phase occurred through fracture opening parallel to the vertical fabric of the host metasedimentary rocks. Trace element analyses point to late-magmatic zircon crystallization, which enable to interpret the associated U-Pb results of 289-288 Ma as the age of this initial emplacement stage. (2) The second magma ascent phase is marked by a rheological change in the host-rock. The temperature increase in the contact aureole induced partial melting and decreasing mechanical strength in the metasediments. This resulted in the formation of a vertical foliation in the metamorphic aureole and a weaker but concordant magmatic foliation at the rim of the pluton. This ascent phase occurred at 288-285 Ma and accounts for the contrasted P-T evolution of metasedimentary rocks in the contact aureole. Thermal models of the intrusion indicate that the contact aureole

  17. Long-distance magma transport from arc volcanoes inferred from the submarine eruptive fissures offshore Izu-Oshima volcano, Izu-Bonin arc

    NASA Astrophysics Data System (ADS)

    Ishizuka, Osamu; Geshi, Nobuo; Kawanabe, Yoshihisa; Ogitsu, Itaru; Taylor, Rex N.; Tuzino, Taqumi; Sakamoto, Izumi; Arai, Kohsaku; Nakano, Shun

    2014-09-01

    Long-distance lateral magma transport away from volcanic centers in island arcs is emerging as a common phenomenon where the regional stress regime is favorable. It should also be recognized as an important factor in the construction and growth of island arcs, and a potential trigger for devastating eruptions. In this contribution, we report on recent investigations into the magma dynamics of Izu-Oshima volcano, an active basaltic volcano with an extensive fissure system. Izu-Oshima is flanked by numerous, subparallel NW-SE trending submarine ridges extending up to 22 km to the NW and the SE from the central vent. During a recent submersible survey we have identified that these ridges are fissures which erupted basaltic spatter and lava flows. Furthermore, lavas are petrographically similar along each ridge, while there are noticeable differences between ridges. The subparallel ridges are observed to transect a series of seamounts - the Izu-Tobu monogenetic volcanoes - which are dispersed across this area of the rear-arc. However, there are consistent petrographic and chemical differences between these seamounts and the ridges, indicating that they have different magma sources, yet, they are essentially bounding each other in dive tracks. The most appropriate scenario for their development is one where the Izu-Tobu Volcanoes are fed by an "in-situ" underlying source, while the NW-SE ridges are fed by lateral magma transport from Izu-Oshima. Magma erupted from each ridge is of a consistent geochemistry along its length, but has experienced crystal fractionation and some plagioclase accumulation. Compositions of the ridges are also very similar to lavas from the subaerial cones that can be traced down the flanks of Izu-Oshima. This implies that pairs of subaerial cones and submarine ridges represent the locus of magma transport events away from the storage system beneath Izu-Oshima. Hence, magma from this crustal reservoir moved upward to feed the on-edifice cones

  18. The Growth of Magma Bodies by Amalgamation of Discrete Sheet Intrusions: Implications for the Formation of Magma Chambers

    NASA Astrophysics Data System (ADS)

    Annen, C.

    2007-12-01

    Until recently, igneous bodies (plutons and magma chambers) were commonly considered to be approximately spherical bodies, rapidly emplaced into the crust. However, field, structural, geophysical, and geochronological studies indicate that many plutons are low aspect-ratio tabular bodies (sills) that are formed by the amalgamation of successive discrete magma pulses. The thermal evolution of an igneous body that grows by accretion of thin magma sheets is fundamentally different from the evolution of a rapidly emplaced magma sphere or of a single thick magma sill. In thin sheet intrusions, the heat loss is through the walls of the sheets and the temperatures within the intrusions do not depend on the volumes injected but on the one-dimension sheets emplacement rate. The first sheets injected in a cold crust rapidly cool down and solidify. The ability of successive intrusions to stay at high temperature and eventually build up a long-lived magma chamber is controlled by the emplacement rate. Heat transfer modeling applied in the context of a volcanic arc shows that average emplacement rates of at least several centimeters per year and an incubation time of tens thousands of years are needed for a persistent magma chamber to form. During the incubation time, the intrusions solidify and when a chamber of high melt fraction magma eventually grows, the volume of eruptible magma only form a small part of the total intruded volume. The emplacement rate of plutons is controversial. Geochronological data suggest that some plutons may be emplaced over millions years. For a pluton that is assembled at a slow rate of a few millimeters per year, millions of years are needed, over which kilometric thicknesses are intruded, before a volume of magma larger than the size of a single intrusion becomes mobile and eruptible. In many cases, volcanic products may come from a deep source without being associated with a long-lived upper crust magma chamber. If volcanism is associated with

  19. Draining mafic magma from conduits during Strombolian eruption

    NASA Astrophysics Data System (ADS)

    Wadsworth, F. B.; Kennedy, B.; Branney, M. J.; Vasseur, J.; von Aulock, F. W.; Lavallée, Y.; Kueppers, U.

    2014-12-01

    During and following eruption, mafic magmas can readily drain downward in conduits, dykes and lakes producing complex and coincident up-flow and down-flow textures. This process can occur at the top of the plumbing system if the magma outgases as slugs or through porous foam, causing the uppermost magma surface to descend and the magma to densify. In this scenario the draining volume is limited by the gas volume outgassed. Additionally, magma can undergo wholesale backflow when the pressure at the base of the conduit or feeder dyke exceeds the driving pressure in the chamber beneath. This second scenario will continue until pressure equilibrium is established. These two scenarios may occur coincidently as local draining of uppermost conduit magma by outgassing can lead to wholesale backflow because the densification of magma is an effective way to modify the vertical pressure profile in a conduit. In the rare case where conduits are preserved in cross section, the textural record of draining is often complex and great care should be taken in interpreting bimodal kinematic trends in detail. Lateral cooling into country rock leads to lateral profiles of physical and flow properties and, ultimately, outgassing potential, and exploration of such profiles elucidates the complexity involved. We present evidence from Red Crater volcano, New Zealand, and La Palma, Canary Islands, where we show that at least one draining phase followed initial ascent and eruption. We provide a rheological model approach to understand gravitational draining velocities and therefore, the timescales of up- and down-flow cycles predicted. These timescales can be compared with observed geophysical signals at monitored mafic volcanoes worldwide. Finally, we discuss the implications of shallow magma draining for edifice stability, eruption longevity and magma-groundwater interaction.

  20. Diatexite Deformation and Magma Extraction on Kangaroo Island, South Australia

    NASA Astrophysics Data System (ADS)

    Hasalova, P.; Weinberg, R. F.; Ward, L.; Fanning, C. M.

    2012-12-01

    Migmatite terranes are structurally complex. We have investigated the relationships between deformation and magma extraction in migmatites formed during the Delamerian orogeny on Kangaroo Island. Several phases of deformation occurred in the presence of melt (D1-D4) and we describe how magma segregation, accumulation and extraction changes with deformation style. During an early upright folding event (D2), magma was channelled towards the hinge of antiforms. Funnel-shaped networks of leucosomes form a root that link towards a central axial planar channel, marking the main magma extraction paths. Extraction was associated with limb collapse, and antiformal hinge disruption. During a later deformation phase (D4), diatexites were sheared so that schollen were disaggregated into smaller blocks and schlieren, and deformed into asymmetric, sigmoidal shapes. Foliations in the magmatic matrix and schollen asymmetry indicate dextral shearing. During flow, magma accumulated in shear planes, indicating a dilational component during shearing (transtension) and on strain shadows of schollen. As deformation waned (post-D4), magma extraction from these diatexites gave rise to steeply dipping, funnel-shaped channels, similar to those developed during folding. The funnel-shape networks are interpreted as magma extraction networks and indicate magma flow direction. Structures developed during this phase are comparable with those developed during dewatering of soft sediments. The magmatic rocks from migmatites formed early, during folding, and formed late after deformation waned were dated. Both have two monazite (U-Pb, SHRIMP) age groups of ~490Ma and ~505-520Ma. The older sample has a well-defined peak at 505-510Ma and trails into the younger ages. The younger sample has the opposite, with few old spots and a well-defined young peak at ~490Ma. The age range indicates the duration of anatexis, and well-defined peaks are interpreted to mark the age of individual magma batch

  1. Magma energy extraction - Annual Report for FY88

    SciTech Connect

    Dunn, J.C.

    1989-08-01

    Thermal energy contained in magmatic systems represents a huge potential resource. In the US, useful energy contained in molten and partially-molten magma within the upper 10 km of the crust has been estimated at 50,000 to 500,000 Quads. The objective of the Magma Energy Extraction Program is to determine engineering feasibility of locating, accessing and utilizing magma as a viable energy resource. Engineering feasibility will depend on size and depth of the resource; extraction rates; and material life times. 11 refs., 29 figs., 1 tab.

  2. How do crystal-rich magmas outgas?

    NASA Astrophysics Data System (ADS)

    Oppenheimer, Julie; Cashman, Katharine V.; Rust, Alison C.; Sandnes, Bjornar

    2014-05-01

    Crystals can occupy ~0 to 100% of the total magma volume, but their role in outgassing remains poorly understood. In particular, the upper half of this spectrum - when the particles touch - involves complex flow behaviours that inevitably affect the geometry and rate of gas migration. We use analogue experiments to examine the role of high particle concentrations on outgassing mechanisms. Mixtures of sugar syrup and glass beads are squeezed between two glass plates to allow observations in 2D. The experiments are performed horizontally, so buoyancy does not intervene, and the suspensions are allowed to expand laterally. Gas flow regimes are mapped out for two sets of experiments: foams generated by chemical reactions, and single air bubbles injected into the particle suspension. Chemically induced bubble nucleation and growth throughout the suspension gradually generated a foam and allowed observations of bubble growth and migration as the foam developed. High particle fractions, close to the random maximum packing, reduced foam expansion (i.e. promoted outgassing). In the early phases of the experiments, they caused a flushing of bubbles from the system which did not occur at low crystal contents. High particle fractions also led to melt segregation and phase re-arrangements, eventually focusing gas escape through connected channels. A more in-depth study of particle-bubble interactions was carried out for single bubbles expanding in a mush. These show a clear change in behaviour close to the limit for loose maximum packing of dry beads, determined experimentally. At concentrations below loose packing, gas expands in a fingering pattern, characterized by a steady advance of widening lobes. This transits to a 'pseudo-fracturing' regime at or near loose packing, whereby gas advances at a point, often in an episodic manner, and outgases with little to no bulk expansion. However, before they can degas, pseudo-fractures typically build up larger internal gas pressures

  3. Modeling the compositional evolution of recharging, evacuating, and fractionating (REFC) magma chambers: Implications for differentiation of arc magmas

    NASA Astrophysics Data System (ADS)

    Lee, Cin-Ty A.; Lee, Tien Chang; Wu, Chi-Tang

    2014-10-01

    Equations are presented to describe the compositional evolution of magma chambers undergoing simultaneous recharge (R), evacuation (E), and fractional crystallization (FC). Constant mass magma chambers undergoing REFC will eventually approach a steady state composition due to the “buffering” effect of recharging magma. Steady state composition is attained after ∼3/(Dαx + αe) overturns of the magma chamber, where D is the bulk solid/melt partition coefficient for the element of interest and αx and αe are the proportions of crystallization and eruption/evacuation relative to the recharge rate. Steady state composition is given by Cre/(Dαx + αe). For low evacuation rates, steady state concentration and the time to reach steady state scale inversely with D. Compatible (D > 1) elements reach steady state faster than incompatible (D < 1) elements. Thus, magma chambers undergoing REFC will eventually evolve towards high incompatible element enrichments for a given depletion in a compatible element compared to magma chambers undergoing pure fractional crystallization. For example, REFC magma chambers will evolve to high incompatible element concentrations for a given MgO content compared to fractional crystallization. Not accounting for REFC will lead to over-estimation of the incompatible element content of primary magmas. Furthermore, unlike fractional crystallization alone, REFC can efficiently fractionate highly incompatible element ratios because the fractionation effect scales with the ratio of bulk D's. By contrast, in pure fractional crystallization, ratios fractionate according to the arithmetic difference between the bulk D's. The compositional impact of REFC should be most pronounced for magma chambers that are long-lived, have low rates of eruption/evacuation, and/or are characterized by high recharge rates relative to the mass of the magma chamber. The first two conditions are likely favored in deep crustal magma chambers where confining pressures

  4. Fifty years of IMOG (International Meetings on Organic Geochemistry)

    USGS Publications Warehouse

    Kvenvolden, Keith A.

    2012-01-01

    IMOG2011 is the 25th of a series of international meetings on organic geochemistry that began in 1962. Thus, this 25th meeting marks the 50th anniversary year of IMOG, which has (a) had a rich history with meetings taking place in 11 different countries, (b) published Proceedings, titled “Advances in Organic Geochemistry,” from each meeting that now number 24 volumes totaling almost 18,000 pages, and (c) documented the content and development of the science of organic geochemistry. IMOG2011 adds a new milestone to the progress of organic geochemistry through time.

  5. El Ventorrillo, a paleostructure of Popocatépetl volcano: insights from geochronology and geochemistry

    NASA Astrophysics Data System (ADS)

    Sosa-Ceballos, G.; Macías, J. L.; García-Tenorio, F.; Layer, P.; Schaaf, P.; Solís-Pichardo, G.; Arce, J. L.

    2015-10-01

    Volcán Popocatépetl (México) was constructed over the remains of a volcanic paleostructure. Based on fieldwork, 40Ar/39Ar dating, U-Pb dating, and geochemistry, we have determined the age, chemistry, and location of this paleostructure and named it El Ventorrillo. Most remnants of El Ventorrillo are covered by deposits from subsequent activity of Popocatépetl, except for the El Abanico scarp and the Barranca de Nexpayantla, where the stratigraphy of El Ventorrillo eruptive products can be investigated. Inception of volcanism at El Ventorrillo occurred at 331 ± 10 ka with emission of the Nexpayantla andesitic lavas, and continued with extrusion of the Yoloxochitl (267 ± 31 ka) and microwave (227 ± 6 ka) domes. Intrusion of dikes occurred at 298 ± 94 and 230 ± 3 ka. Activity at El Ventorrillo continued with the emission of lavas that built the El Abanico scarp (193 ± 29 to 96 ± 8 ka) and continued until the Tutti Frutti eruption destroyed the cone 14.1 kyr ago. El Ventorrillo magmas produced rocks divided into two mineralogical groups. The first group contains biotite-amphibole-rich rocks and the second group consists of biotite-amphibole-free lavas. The rocks that contain biotite and amphibole are older than 198 ± 13 ka, whereas the rocks with no hydrous phases are younger than 227 ± 6 ka and contain skarn and granodiorite xenoliths. We interpret the change to an anhydrous mineral assemblage and the occurrence of skarn and granodiorite xenoliths as evidence for the formation of a new, shallower reservoir. A granodiorite xenolith was chosen for 40Ar/39Ar dating and U-Pb zircon analyses. The U-Pb method yielded an age of 540 ± 110 ka and the 40Ar/39Ar an age of 109 ± 24 ka. These ages are interpreted to indicate granodiorite crystallization (540 ± 110 ka), which metamorphosed the calcareous basement beneath Popocatépetl into skarn and an influx of magma (109 ± 24 ka) that reheated the granodiorite. Major and trace elements, Sr, Nd, and Pb isotopic

  6. The role of magma mixing in the evolution of high-K calc-alkaline granitoid suites: in situ trace element and Sr-Nd-Hf isotope constraints

    NASA Astrophysics Data System (ADS)

    Laurent, Oscar; Zeh, Armin; Gerdes, Axel; Slaby, Ewa; Villaros, Arnaud

    2015-04-01

    The so-called "I-type", high-K calc-alkaline granitoids are often considered as "hybrid" in origin, i.e. involving both mantle and crustal components in their petrogenesis. The interactions between both components either take place (1) at mantle levels (i.e. enriched mantle source); (2) at emplacement levels (i.e. crustal contamination and/or magma mixing with crustal melts) or (3) both. Magma mixing is, in particular, frequently invoked to explain the compositional range of high-K calc-alkaline granitoid suites, especially phases of intermediate composition (SiO2 = 60-65 wt.%) such as quartz-diorites or granodiorites. We investigated the role of magma mixing in the origin of such rocks using elemental and isotope (Sr-Nd-Hf) chemistry of magmatic minerals (plagioclase, zircon, apatite, titanite, epidote), measured in situ by LA-(MC-)ICPMS, allowing a much greater spatial resolution than classical whole-rock geochemistry. We focused on a suite of late-Archaean (2.69 Ga-old) high-K, calc-alkaline granitoids from the Pietersburg block, northern Kaapvaal Craton (South Africa): the Mashashane, Matlala, Matok and Moletsi plutons. Those plutons range from diorites to monzogranites, emplaced at different crustal levels but all within a relatively short time span and showing evidence for interactions (mingling), both at the outcrop and mineral scale. Hf isotope data on zircon confirm that all rocks are cogenetic (identical ɛHf(t)), but trace element and Sr isotopes in plagioclase point to the involvement of several components in their petrogenesis, at different stages of the magma evolution. The most mafic rocks (diorites) derive from the interaction, at mantle levels, between depleted peridotite and a sedimentary component of quartzofeldspathic nature. The mineral chemistry of more felsic rocks can be explained by (1) differentiation from the diorite magmas through Amp + Plag fractionation; (2) interactions with magmas derived from melting of local crust (tonalites

  7. Precambrian organic geochemistry - Preservation of the record

    NASA Technical Reports Server (NTRS)

    Hayes, J. M.; Wedeking, K. W.; Kaplan, I. R.

    1983-01-01

    A review of earlier studies is presented, and new results in Precambrian organic geochemistry are discussed. It is pointed out that two lines of evidence can be developed. One is based on structural organic chemistry, while the other is based on isotopic analyses. In the present investigation, the results of both structural and isotopic investigations of Precambrian organic matter are discussed. Processes and products related to organic geochemistry are examined, taking into account the carbon cycle, an approximate view of the principal pathways of carbon cycling associated with organic matter in the present global ecosystem, processes affecting sedimentary organic matter, and distribution and types of organic matter. Attention is given to chemical fossils in Precambrian sediments, kerogen analyses, the determination of the structural characteristics of kerogen, and data concerning the preservation of the Precambrian organic geochemical record.

  8. Magma Dynamics at Yucca Mountain, Nevada

    SciTech Connect

    D. Krier

    2005-08-29

    Small-volume basaltic volcanic activity at Yucca Mountain has been identified as one of the potential events that could lead to release of radioactive material from the U.S. Department of Energy (DOE) designated nuclear waste repository at Yucca Mountain. Release of material could occur indirectly as a result of magmatic dike intrusion into the repository (with no associated surface eruption) by changing groundwater flow paths, or as a result of an eruption (dike intrusion of the repository drifts, followed by surface eruption of contaminated ash) or volcanic ejection of material onto the Earth's surface and the redistribution of contaminated volcanic tephra. Either release method includes interaction between emplacement drifts and a magmatic dike or conduit, and natural (geologic) processes that might interrupt or halt igneous activity. This analysis provides summary information on two approaches to evaluate effects of disruption at the repository by basaltic igneous activity: (1) descriptions of the physical geometry of ascending basaltic dikes and their interaction with silicic host rocks similar in composition to the repository host rocks; and (2) a summary of calculations developed to quantify the response of emplacement drifts that have been flooded with magma and repressurized following blockage of an eruptive conduit. The purpose of these analyses is to explore the potential consequences that could occur during the full duration of an igneous event.

  9. The Role of Magma Mixing in Creating Magmatic Diversity

    NASA Astrophysics Data System (ADS)

    Davidson, J. P.; Collins, S.; Morgan, D. J.

    2012-12-01

    Most magmas derived from the mantle are fundamentally basaltic. An assessment of actual magmatic rock compositions erupted at the earth's surface, however, shows greater diversity. While still strongly dominated by basalts, magmatic rock compositions extend to far more differentiated (higher SiO2, LREE enriched) compositions. Magmatic diversity is generated by differentiation processes, including crystal fractionation/ accumulation, crustal contamination and magma mixing. Among these, magma mixing is arguably inevitable in magma systems that deliver magmas from source-to-surface, since magmas will tend to multiply re-occupy plumbing systems. A given mantle-derived magma type will mix with any residual magmas (and crystals) in the system, and with any partial melts of the wallrock which are generated as it is repeatedly flushed through the system. Evidence for magma mixing can be read from the petrography (identification of crystals derived from different magmas), a technique which is now well-developed and supplemented by isotopic fingerprinting (1,2) As a means of creating diversity, mixing is inevitably not efficient as its tendency is to blend towards a common composition (i.e. converging on homogeneity rather than diversity). It may be surprising then that many systems do not tend to homogenise with time, meaning that the timescales of mixing episodes and eruption must be similar to external magma contributions of distinct composition (recharge?). Indeed recharge and mixing/ contamination may well be related. As a result, the consequences of magma mixing may well bear on eruption triggering. When two magmas mix, volatile exsolution may be triggered by retrograde boiling, with crystallisation of anhydrous phase(s) in either of the magmas (3) or volatiles may be generated by thermal breakdown of a hydrous phase in one of the magmas (4). The generation of gas pressures in this way probably leads to geophysical signals too (small earthquakes). Recent work pulling

  10. Preliminary considerations for extraction of thermal energy from magma

    SciTech Connect

    Hickox, C.E.; Dunn, J.C.

    1985-01-01

    Simplified mathematical models are developed to describe the extraction of thermal energy from magma based on the concept of a counterflow heat exchanger inserted into the magma body. Analytical solutions are used to investigate influence of the basic variables on electric power production. Calculations confirm that the proper heat exchanger flow path is down the annulus with hot fluid returning to the surface through the central core. The core must be insulated from the annulus to achieve acceptable wellhead temperatures, but this insulation thickness can be quite small. The insulation is effective in maintaining the colder annular flow below expected formation temperatures so that a net heat gain from the formation above a magma body is predicted. The analyses show that optimum flow rates exist that maximize electric power production. These optimum flow rates are functions of the heat transfer coefficients that describe magma energy extraction. 15 refs., 3 figs.

  11. The Magma Transport System of the Mono Craters, California

    NASA Astrophysics Data System (ADS)

    Johnson, M. R.; Putirka, K. D.

    2013-12-01

    The Mono Craters are a series of 28 volcanic domes, coulees, and craters, just 16 km north of Long Valley. The magmatic products of the Mono Craters include mostly small magmatic bodies, sills, and dikes set in a transtensional tectonic setting. New high-density sampling of the domes reveals a wider range of magma compositions than heretofore recognized, and thus reveals what is likely a more complex magmatic system, involving a greater number of batches of magma and a more complex magma storage/delivery system. Here, we present a model for the magma plumbing system based on space-composition patterns and preliminary estimates of crystallization temperatures and pressures based on olivine-, feldspar- and clinopyroxene-liquid equilibria. Whole rock analyses show three compositionally distinct batches of magma within the Mono Craters proper: a felsic (73-78.4% SiO2), intermediate (64.4-68% SiO2) and mafic (52.7-61% SiO2) group. The Mono Lake Islands (Paoha and Negit) fall into the intermediate group, but contain distinctly lower TiO2 and Fe2O3 at a given SiO2 compared to all other Mono Craters; on this basis, we surmise that the Paoha and Negit eruptions represent a distinct episode of magmatism that is not directly related to the magmatic activity that created the Mono Craters proper. The discontinuous nature of the three groups indicates that magma mixing, while evident to some degree within and between certain domes, did not encompass the entire range of compositions at any given time. The three groups, however, do form a rough linear trend, and some subsets of domes have compositions that fall on distinctly linear (if still discontinuous) trends that cannot be reproduced by fractional crystallization, but rather are indicative of magma mixing. Our high-density sampling also reveals interesting geographical patterns: for example, felsic magmas erupt throughout the entire Mono Craters chain, erupting at a wide range of temperatures, ranging from 650-995°C, but

  12. Water In The Lunar Mantle: Results From Magma Ocean Modeling

    NASA Astrophysics Data System (ADS)

    Elkins-Tanton, Linda

    2010-05-01

    The Moon is posited to have formed by reconsolidation of materials produced during a giant impact with the Earth. The young Moon appears to have experienced a magma ocean of some depth. The hypothetical energetics of such an impact and cooling process, combined with the low oxygen activity implied by lunar petrology, has lead investigators to believe that the Moon was free of water. Recent results, however, indicate that lunar volcanic glasses produced by fire fountaining contain small amounts of water (Saal et al., 2008). The volcanic glasses are reported to contain 4 to 46 ppm water, thought to be the remnant after degassing an original minimum 260 ppm. Lunar sample suites indicate fractional crystallization of a lunar magma ocean, including efficient flotation of anorthite to its surface, unimpeded by high crystal fractions or crystal networks. Modeling lunar magma ocean solidification including a small amount of initial water produces predictions for the locations and quantities of water that should be found in the lunar interior, and water that would have been degassed. Compositions of mineral phases are calculated in equilibrium with the magma ocean liquid composition at that stage of solidification, using experimentally-determined KDs for major elements and partition coefficients for hydroxyl and trace elements; for methods see Elkins-Tanton (2008). Water and all other incompatible elements are progressively enriched in the evolving magma ocean liquids as solidification progresses. Progressive enrichment of water in magma ocean liquids produces increasing water contents in solidifying cumulate minerals. Between 0.2 and 1% of the magma ocean liquid water content will be incorporated into solidifying cumulates, enhanced by trapped interstitial liquids. Upon later melting about 99% of cumulate source region water moves into the melt phase. Finally, upon eruption, Saal et al. (2008) estimate that 98% of magmatic water is degassed. Fractional solidification of

  13. Seismic Tremors and Three-Dimensional Magma Wagging

    NASA Astrophysics Data System (ADS)

    Liao, Y.; Bercovici, D.

    2015-12-01

    Seismic tremor is a feature shared by many silicic volcanoes and is a precursor of volcanic eruption. Many of the characteristics of tremors, including their frequency band from 0.5 Hz to 7 Hz, are common for volcanoes with very different geophysical and geochemical properties. The ubiquitous characteristics of tremor imply that it results from some generation mechanism that is common to all volcanoes, instead of being unique to each volcano. Here we present new analysis on the magma-wagging mechanism that has been proposed to generate tremor. The model is based on the suggestion given by previous work (Jellinek & Bercovici 2011; Bercovici et.al. 2013) that the magma column is surrounded by a compressible, bubble-rich foam annulus while rising inside the volcanic conduit, and that the lateral oscillation of the magma inside the annulus causes observable tremor. Unlike the previous two-dimensional wagging model where the displacement of the magma column is restricted to one vertical plane, the three-dimensional model we employ allows the magma column to bend in different directions and has angular motion as well. Our preliminary results show that, without damping from viscous deformation of the magma column, the system retains angular momentum and develops elliptical motion (i.e., the horizontal displacement traces an ellipse). In this ''inviscid'' limit, the magma column can also develop instabilities with higher frequencies than what is found in the original two-dimensional model. Lateral motion can also be out of phase for various depths in the magma column leading to a coiled wagging motion. For the viscous-magma model, we predict a similar damping rate for the uncoiled magma column as in the two-dimensional model, and faster damping for the coiled magma column. The higher damping thus requires the existence of a forcing mechanism to sustain the oscillation, for example the gas-driven Bernoulli effect proposed by Bercovici et al (2013). Finally, using our new 3

  14. The role of turbulence in explosive magma-water mixing

    NASA Astrophysics Data System (ADS)

    Mastin, L. G.; Walder, J. S.; Stern, L. A.

    2003-12-01

    Juvenile tephra from explosive hydromagmatic eruptions differs from that of dry magmatic eruptions by its fine average grain size and highly variable vesicularity. These characteristics are generally interpreted to indicate that fragmentation, which occurs in dry magmas by bubble growth, is supplemented in hydromagmatic eruptions by quench-fracturing. Quench fragmentation is thought to accelerate heat transfer to water, driving violent steam expansion and increasing eruptive violence. Although some observed hydromagmatic events (e.g. at Surtsey) are indeed violent, others (e.g. quiescent entry of lava into the ocean at Kilauea) are not. We suggest that the violence of magma-water mixing and the grain size and dispersal of hydromagmatic tephras are controlled largely by the turbulence of magma-water mixing. At Surtsey, fine-grained, widely dispersed hydromagmatic tephras were produced primarily during continuous uprush events in which turbulent jets of magma and gas passed through shallow water (Thorarinsson, 1967). During Kilauea's current eruption, videos show generation of fine-grained tephras when turbulent jets of magma, steam, and seawater exited through skylights at the coastline. Turbulence intensity, or the fraction of total jet kinetic energy contained in fine-scale turbulent velocity oscillations, has long been known to control the scale of atomization in spray nozzles and the rate of heat transfer and chemical reaction in fuel injectors. We hypothesize that turbulence intensity also influences grain size and heat transfer rate in magma-water mixing, though such processes are complicated by boiling (in water) and quench fracturing (in magma). We are testing this hypothesis in experiments involving turbulent injection of water (a magma analog) into liquid nitrogen (a water analog). We also suggest that turbulent mixing influences relative proportions of magma and water in hydromagmatic eruptions. Empirical studies indicate that pressure-neutral turbulent

  15. Diatexite Deformation and Magma Extraction on Kangaroo Island, South Australia

    NASA Astrophysics Data System (ADS)

    Hasalova, Pavlina; Weinberg, Roberto; Ward, Lindsay; Fanning, Mark

    2013-04-01

    Migmatite terranes are structurally complex because of strong rheological contrast between layers with different melt contents and because of magma migration leading to volume changes. Migmatite deformation is intimately linked with magma extraction and the origin of granitoids. We investigate here the relationships between an evolving deformation and magma extraction in migmatites formed during the ca. 500Ma Delamerian orogeny, exposed on Kangaroo Island, South Australia. Here, several phases of deformation occurred in the presence of melt. During an early upright, non-cylindrical folding event, magma was channeled towards the hinge zones of antiforms. Funnel-shaped networks of leucosomes form a root zone that link up towards a central axial planar channel, forming the main magma extraction paths during folding. Extraction was associated with fold limb collapse, and antiformal hinge disruption by magma accumulation and transfer. During a later deformation phase, melt-rich diatexites were deformed, and schollen were disaggregated into smaller blocks and schlieren, and deformed into asymmetric, sigmoidal shapes indicative of dextral shearing flow. During flow, magma accumulated preferentially along shear planes, indicating a dilatational component during shearing (transtension) and in strain shadows of schollen. As deformation waned, magma extraction from these diatexites gave rise to N-trending, steeply dipping, funnel-shaped channels not associated to any deformational feature. The funnel-shape of these structures indicates the direction of magma flow. Structures developed during this phase are comparable with those formed during dewatering of soft sediments. Despite a high degree of complexity, magma migration and extraction features record distinct responses to the evolving deformation which can be used to understand deformation, and nature and direction of melt extraction. The oldest and youngest magmatic rocks from migmatites were dated (U-Pb monazite, SHRIMP

  16. Magma Rich Events at Magma-Poor Rifted Margins: A South-East Indian Example

    NASA Astrophysics Data System (ADS)

    Harkin, Caroline; Kusznir, Nick; Tugend, Julie; Manatschal, Gianreto; Horn, Brian

    2016-04-01

    The south-east Indian continental rifted margin, as imaged by the INE1-1000 deep long-offset seismic reflection section by ION Geophysical, is a classic example of a magma-poor rifted margin, showing highly thinned continental crust, or possibly exhumed mantle, within the ocean-continent transition (OCT). Outboard, the steady-state oceanic crust is between 4 and 5 km thickness, consistent with magma-poor continental breakup and sea-floor spreading. It is therefore surprising that between the hyper-extended crust showing thin or absent continental crust (of approximately 75 km width) and the anomalously thin steady-state oceanic crust, there appears to be a region of thicker magmatic crust of approximately 11 km thickness and 100 km width. Magmatic events, at or just after continental breakup, have also been observed at other magma-poor rifted margins (e.g. NE Brazil). This interpretation of magma-poor OCT structure and thinner than global average oceanic crust separated by thicker magmatic crust on the SE Indian margin is supported by gravity inversion; which uses a 3D spectral technique and includes a lithosphere thermal gravity anomaly correction. Residual depth anomaly (RDA) analysis corrected for sediment loading using flexural backstripping, gives a small negative value (approximately -0.1 km) over the steady-state oceanic crust compared with a positive value (approximately +0.3 km) over the thicker magmatic crust. This RDA difference is consistent with the variation in crustal thickness seen by the seismic reflection interpretation and gravity inversion. We use joint inversion of the time domain seismic reflection and gravity data to investigate the average basement density and seismic velocity of the anomalously thick magmatic crust. An initial comparison of Moho depth from deep long-offset seismic reflection data and gravity inversion suggests that its basement density and seismic velocity are slightly less than that of the outboard steady-state oceanic

  17. Low-(18)O Silicic Magmas: Why Are They So Rare?

    SciTech Connect

    Balsley, S.D.; Gregory, R.T.

    1998-10-15

    LOW-180 silicic magmas are reported from only a small number of localities (e.g., Yellowstone and Iceland), yet petrologic evidence points to upper crustal assimilation coupled with fractional crystallization (AFC) during magma genesis for nearly all silicic magmas. The rarity of 10W-l `O magmas in intracontinental caldera settings is remarkable given the evidence of intense 10W-l*O meteoric hydrothermal alteration in the subvolcanic remnants of larger caldera systems. In the Platoro caldera complex, regional ignimbrites (150-1000 km3) have plagioclase 6180 values of 6.8 + 0.1%., whereas the Middle Tuff, a small-volume (est. 50-100 km3) post-caldera collapse pyroclastic sequence, has plagioclase 8]80 values between 5.5 and 6.8%o. On average, the plagioclase phenocrysts from the Middle Tuff are depleted by only 0.3%0 relative to those in the regional tuffs. At Yellowstone, small-volume post-caldera collapse intracaldera rhyolites are up to 5.5%o depleted relative to the regional ignimbrites. Two important differences between the Middle Tuff and the Yellowstone 10W-180 rhyolites elucidate the problem. Middle Tuff magmas reached water saturation and erupted explosively, whereas most of the 10W-l 80 Yellowstone rhyolites erupted effusively as domes or flows, and are nearly devoid of hydrous phenocrysts. Comparing the two eruptive types indicates that assimilation of 10W-180 material, combined with fractional crystallization, drives silicic melts to water oversaturation. Water saturated magmas either erupt explosively or quench as subsurface porphyrins bejiire the magmatic 180 can be dramatically lowered. Partial melting of low- 180 subvolcanic rocks by near-anhydrous magmas at Yellowstone produced small- volume, 10W-180 magmas directly, thereby circumventing the water saturation barrier encountered through normal AFC processes.

  18. Experimental Fractional Crystallization of the Lunar Magma Ocean

    NASA Technical Reports Server (NTRS)

    Rapp, J. F.; Draper, D. S.

    2012-01-01

    The current paradigm for lunar evolution is of crystallization of a global scale magma ocean, giving rise to the anorthositic crust and mafic cumulate interior. It is thought that all other lunar rocks have arisen from this differentiated interior. However, until recently this paradigm has remained untested experimentally. Presented here are the first experimental results of fractional crystallization of a Lunar Magma Ocean (LMO) using the Taylor Whole Moon (TWM) bulk lunar composition [1].

  19. Solidification of basaltic magma during flow in a dike.

    USGS Publications Warehouse

    Delaney, P.T.; Pollard, D.D.

    1982-01-01

    A model for time-dependent unsteady heat transfer from magma flowing in a dyke is developed. The ratio of solidification T to magma T is the most important parameter. Observations of volcanic fissure eruptions and study of dykes near Ship Rock, New Mexico, show that the low T at dyke margins and the rapidly advancing solidification front predicted by the model are qualitatively correct.-M.S.

  20. The Geochemistry of Mass Extinction

    NASA Astrophysics Data System (ADS)

    Kump, L. R.

    2003-12-01

    The course of biological evolution is inextricably linked to that of the environment through an intricate network of feedbacks that span all scales of space and time. Disruptions to the environment have biological consequences, and vice versa. Fossils provide the prima facie evidence for biotic disruptions: catastrophic losses of global biodiversity at various times in the Phanerozoic. However, the forensic evidence for the causes and environmental consequences of these mass extinctions resides primarily in the geochemical composition of sedimentary rocks deposited during the extinction intervals. Thus, advancement in our understanding of mass extinctions requires detailed knowledge obtained from both paleontological and geochemical records.This chapter reviews the state of knowledge concerning the geochemistry of the "big five" extinctions of the Phanerozoic (e.g., Sepkoski, 1993): the Late Ordovician (Hirnantian; 440 Ma), the Late Devonian (an extended or multiple event with its apex at the Frasnian-Famennian (F-F) boundary; 367 Ma), the Permian-Triassic (P-Tr; 251 Ma), the Triassic-Jurassic (Tr-J; 200 Ma), and the Cretaceous-Tertiary (K-T; 65 Ma). The focus on the big five is a matter of convenience, as there is a continuum in extinction rates from "background" to "mass extinction." Although much of the literature on extinctions centers on the causes and extents of biodiversity loss, in recent years paleontologists have begun to focus on recoveries (see, e.g., Hart, 1996; Kirchner and Weil, 2000; Erwin, 2001 and references therein).To the extent that the duration of the recovery interval may reflect a slow relaxation of the environment from perturbation, analysis of the geochemical record of recovery is an integral part of this effort. In interpreting the geochemical and biological records of recovery, we need to maintain a clear distinction among the characteristics of the global biota: their biodiversity (affected by differences in origination and extinction

  1. Experimental Magma Mixing and Mingling in Volcanic Environments

    NASA Astrophysics Data System (ADS)

    Morgavi, D.; Laumonier, M.; Petrelli, M.; Perugini, D.

    2015-12-01

    Magma mixing and mingling features are commonly observed in both plutonic and volcanic environments. Major occurrences are represented by hybrid products, enclaves and crystals in disequilibrium with the melt. According to present knowledge the complete mixing of magmas in crustal reservoirs (leading to the production of hybrids) requires a low viscosity contrast between the two end-members (0.5 log unit). On another hand, recent experimental and field works have shown that (1) crystal-free magmas with viscosity difference of 3 orders of magnitude produced mingling and mixing features at higher deformation conditions (strain and strain rate) and (2) these features are found in volcanic products out of the above mentioned rheological window. In this study, we performed magma mixing experiments, to test the effects of chaotic deformation of a two component system at volcanic conditions and strain rates comparable to natural magmatic systems (volcanic conduits and lava flows): in the ChaOtic Magma Mixing Apparatus (COMMA) installed at the University of Perugia, a synthetic haplotonalite and a natural basalt from Santorini volcano were juxtaposed and chaotically mixed for several hours at ~1140°C with a moderate strain rate of ~5.10-3. The textural and geochemical (electronic microprobe, laser ablation mass spectrometry) features developed during the experiments show the development of complex patterns with high inter-exchange between both magmas. Our results show how chaotic convection extends the mixing capacities at moderate strain rate.

  2. Composition and origin of basaltic magma of the Hawaiian Islands

    USGS Publications Warehouse

    Powers, H.A.

    1955-01-01

    Silica-saturated basaltic magma is the source of the voluminous lava flows, erupted frequently and rapidly in the primitive shield-building stage of activity, that form the bulk of each Hawaiian volcano. This magma may be available in batches that differ slightly in free silica content from batch to batch both at the same and at different volcanoes; differentiation by fractionation of olivine does not occur within this primitive magma. Silica-deficient basaltic magma, enriched in alkali, is the source of commonly porphyritic lava flows erupted less frequently and in relatively negligible volume during a declining and decadent stage of activity at some Hawaiian volcanoes. Differentiation by fractionation of olivine, plagioclase and augite is evident among these lavas, but does not account for the silica deficiency or the alkali enrichment. Most of the data of Hawaiian volcanism and petrology can be explained by a hypothesis that batches of magma are melted from crystalline paridotite by a recurrent process (distortion of the equatorial bulge by forced and free nutational stresses) that accomplishes the melting only of the plagioclase and pyroxene component but not the excess olivine and more refractory components within a zone of fixed and limited depth. Eruption exhausts the supply of meltable magma under a given locality and, in the absence of more violent melting processes, leaves a stratum of crystalline refractory components. ?? 1955.

  3. Crystallization and Cooling of a Deep Silicate Magma Ocean

    NASA Astrophysics Data System (ADS)

    Bower, Dan; Wolf, Aaron

    2016-04-01

    Impact and accretion simulations of terrestrial planet formation suggest that giant impacts are both common and expected to produce extensive melting. The moon-forming impact, for example, likely melted the majority of Earth's mantle to produce a global magma ocean that subsequently cooled and crystallised. Understanding the cooling process is critical to determining magma ocean lifetimes and recognising possible remnant signatures of the magma ocean in present-day mantle heterogeneities. Modelling this evolution is challenging, however, due to the vastly different timescales and lengthscales associated with turbulent convection (magma ocean) and viscous creep (present-day mantle), in addition to uncertainties in material properties and chemical partitioning. We consider a simplified spherically-symmetric (1-D) magma ocean to investigate both its evolving structure and cooling timescale. Extending the work of Abe (1993), mixing-length theory is employed to determine convective heat transport, producing a high resolution model that parameterises the ultra-thin boundary layer (few cms) at the surface of the magma ocean. The thermodynamics of mantle melting are represented using a pseudo-one-component model, which retains the simplicity of a standard one-component model while introducing a finite temperature interval for melting. This model is used to determine the cooling timescale for a variety of plausible thermodynamic models, with special emphasis on comparing the center-outwards vs bottom-up cooling scenarios that arise from the assumed EOS.

  4. Thermal and mechanical controls on magma supply and volcanic deformation

    NASA Astrophysics Data System (ADS)

    Hickey, James; Gottsmann, Jo; Nakamichi, Haruhisa; Iguchi, Masato

    2016-04-01

    Ground deformation often precedes volcanic eruptions, and results from complex interactions between source processes and the thermomechanical behaviour of surrounding rock. Geodetic models aimed at constraining source processes consequently require the implementation of realistic mechanical and thermal rock properties. However, most generic models ignore this requirement and employ oversimplified mechanical assumptions without regard for thermal effects. Here we show how spatio-temporal deformation and magma reservoir evolution are fundamentally controlled by three-dimensional thermomechanical heterogeneity. Using the example of continued inflation at Aira caldera, Japan, we demonstrate that despite on-going eruptions magma is accumulating faster than it can be ejected, and the current uplift is approaching the level inferred prior to the 1914 Plinian eruption. Our results from inverse and forward numerical models are consistent with petrological constraints and highlight how the location, volume, and rate of magma supply, 0.014 km3/yr, are thermomechanically controlled. Magma storage conditions coincide with estimates for the caldera-forming reservoir ˜29,000 years ago, and the inferred magma supply rate indicates a ˜130-year timeframe to amass enough magma to feed a future 1914-sized eruption. These new inferences are important for eruption forecasting and risk mitigation, and have significant implications for the interpretations of volcanic deformation worldwide.

  5. Tracking dynamics of magma migration in open-conduit systems

    NASA Astrophysics Data System (ADS)

    Valade, Sébastien; Lacanna, Giorgio; Coppola, Diego; Laiolo, Marco; Pistolesi, Marco; Donne, Dario Delle; Genco, Riccardo; Marchetti, Emanuele; Ulivieri, Giacomo; Allocca, Carmine; Cigolini, Corrado; Nishimura, Takeshi; Poggi, Pasquale; Ripepe, Maurizio

    2016-11-01

    Open-conduit volcanic systems are typically characterized by unsealed volcanic conduits feeding permanent or quasi-permanent volcanic activity. This persistent activity limits our ability to read changes in the monitored parameters, making the assessment of possible eruptive crises more difficult. We show how an integrated approach to monitoring can solve this problem, opening a new way to data interpretation. The increasing rate of explosive transients, tremor amplitude, thermal emissions of ejected tephra, and rise of the very-long-period (VLP) seismic source towards the surface are interpreted as indicating an upward migration of the magma column in response to an increased magma input rate. During the 2014 flank eruption of Stromboli, this magma input preceded the effusive eruption by several months. When the new lateral effusive vent opened on the Sciara del Fuoco slope, the effusion was accompanied by a large ground deflation, a deepening of the VLP seismic source, and the cessation of summit explosive activity. Such observations suggest the drainage of a superficial magma reservoir confined between the crater terrace and the effusive vent. We show how this model successfully reproduces the measured rate of effusion, the observed rate of ground deflation, and the deepening of the VLP seismic source. This study also demonstrates the ability of the geophysical network to detect superficial magma recharge within an open-conduit system and to track magma drainage during the effusive crisis, with a great impact on hazard assessment.

  6. Dynamically-induced structures formation in congested magma

    NASA Astrophysics Data System (ADS)

    Petford, N.

    2008-12-01

    Crystal fabrics preserved in igneous rocks offer a glimpse into the magma emplacement process. Detailed field mapping, in combination with AMS studies, seem to provide the best available data for unravelling intrusion architecture on the decimetre scale. However, a full and proper understanding of the fluid dynamics of congested fluid-particle mixtures during shear remains elusive. This is a shame as without recourse to such fundamental understanding, the interpretation of structural field data in the context of magma flow remains problematic. One way to gain insight into the process is to treat flowing magma as a dynamic material with a rheology similar to sheared, congested slurries. The fancy that dense magma equates to a high temperature slurry is an attractive one, and opens up a way to examine the emplacement process that does not rely exclusively on equilibrium thermodynamics as a final explanation of commonly observed igneous structures. Instead, using examples from mafic rocks where cooling has been rapid, the idea is put forward that in high Peclet number suspensions (where particle diffusion is negligible), shearing and non- Newtonian behaviour imparts a rich diversity of structures including layering, grading and flow segregation. Key to understanding the rheology, hence flow dynamics of congested magma, is the particle microstructure, a still poorly known essence of suspension flows. Where magma transport is continental in scale and long lived (e.g. Large Igneous Provinces), rotation of the earth may in theory endow a small but potentially measurable imprint on the preserved flow fabric.

  7. Evidence for an Early Cretaceous mineralizing event above the basement/sediment unconformity in the intracratonic Paris Basin: paragenetic sequence and Sm-Nd dating of the world-class Pierre-Perthuis stratabound fluorite deposit

    NASA Astrophysics Data System (ADS)

    Gigoux, Morgane; Delpech, Guillaume; Guerrot, Catherine; Pagel, Maurice; Augé, Thierry; Négrel, Philippe; Brigaud, Benjamin

    2015-04-01

    World-class stratabound fluorite deposits are spatially associated with the basement/sediment unconformity of the intracratonic Paris Basin and the Morvan Massif in Burgundy (France). The reserves are estimated to be about 5.5 Mt of fluorite within six fluorite deposits. In this study, we aim to determine the age of the major fluorite mineralization event of the Pierre-Perthuis deposit (1.4 Mt fluorite) by a combined study of the paragenetic mineral sequence and Sm-Nd dating on fluorite crystals. Fluorite occurs as isolated cubes or filling geodes in a Triassic, silicified, dolomitic formation. Three fluorite stages associated with sphalerite, pyrite, galena, barite, and quartz have been distinguished using optical, cathodoluminescence, and scanning electron microscopes. Seven crystals of the geodic fluorite stage were analyzed for their rare earth element (REE) contents and their 147Sm/144Nd and 143Nd/144Nd isotopic compositions. The normalized REE distribution displays homogeneous bell-shaped patterns for all the geodic fluorite samples with a Mid-REE enrichment over the Light-REE and Heavy-REE. The 147Sm/144Nd varies from 0.3108 to 0.5504 and the 143Nd/144Nd from 0.512313 to 0.512518. A six-point Sm-Nd isochron defines an age of 130 ± 15 Ma (initial 143Nd/144Nd = 0.512054, MSWD = 0.21). This Sm-Nd isochron provides the first age for the stratabound fluorite sediment-hosted deposit, related to an unconformity in the Paris Basin, and highlights a major Early Cretaceous fluid circulation event mainly above the basement/sediment unconformity during a flexural deformation of the Paris Basin, which relates to the rifting of the Bay of Biscay and the formation of the Ligurian Sea in the Western Europe domain.

  8. A refined model for Kilauea's magma plumbing system

    NASA Astrophysics Data System (ADS)

    Poland, M. P.; Miklius, A.; Montgomery-Brown, E. D.

    2011-12-01

    Studies of the magma plumbing system of Kilauea have benefitted from the volcano's frequent eruptive activity, ease of access, and particularly the century-long observational record made possible by the Hawaiian Volcano Observatory. The explosion of geophysical data, especially seismic and geodetic, collected since the first model of Kilauea's magmatic system was published in 1960 allows for a detailed characterization of Kilauea's magma storage areas and transport pathways. Using geological, geochemical, and geophysical observations, we propose a detailed model of Kilauea's magma plumbing that we hope will provide a refined framework for studies of Kilauea's eruptive and intrusive activity. Kilauea's summit region is underlain by two persistently active, hydraulically linked magma storage areas. The larger reservoir is centered at ~3 km depth beneath the south caldera and is connected to Kilauea's two rift zones, which radiate from the summit to the east and southwest. All magma that enters the Kilauea edifice passes through this primary storage area before intrusion or eruption. During periods of increased magma storage at the summit, as was the case during 2003-2007, uplift may occur above temporary magma storage volumes, for instance, at the intersection of the summit and east rift zone at ~3 km depth, and within the southwest rift zone at ~2 km depth. The east rift zone is the longer and more active of Kilauea's two rift zones and apparently receives more magma from the summit. Small, isolated pods of magma exist within both rift zones, as indicated by deformation measurements, seismicity, petrologic data, and geothermal drilling results. These magma bodies are probably relicts of past intrusions and eruptions and can be highly differentiated. Within the deeper part of the rift zones, between about 3 km and 9 km depth, magma accumulation is hypothesized based on surface deformation indicative of deep rift opening. There is no direct evidence for magma within

  9. H, O, Sr, Nd, and Pb isotope geochemistry of the Latir volcanic field and cogenetic intrusions, New Mexico, and relations between evolution of a continental magmatic center and modifications of the lithosphere

    USGS Publications Warehouse

    Johnson, C.M.; Lipman, P.W.; Czamanske, G.K.

    1990-01-01

    all the postcaldera plutons overlap those of the precaldera rocks and Amalia Tuff, except for those for two late-stage rhyolite dikes associated with the Rio Hondo pluton that have ??18O values of-8.6 and-9.5; these dikes are the only Latir rocks which may be largely crustal melts. Chemical and isotopic data from the Latir field suggest that large fluxes of mantle-derived basaltic magma are necessary for developing and sustaining large-volume volcanic centers. Development of a detailed model suggests that 6-15 km of new crust may have been added beneath the volcanic center; such an addition may result in significant changes in the chemical and Sr and Nd isotopic compositions of the crust, although Pb isotope ratios will remain relatively unchanged. If accompanied by assimilation, crystallization of pooled basaltic magma near the MOHO may produce substantial cumulates beneath the MOHO that generate large changes in the isotopic composition of the upper mantle. The Latir field may be similar to other large-volume, long-lived intracratonal volcanic fields that fundamentally owe their origins to extensive injection of basaltic magma into the lower parts of their magmatic systems. Such fields may overlie areas of significant crustal growth and hybridization. ?? 1990 Springer-Verlag.

  10. Deciphering Multistage Crystal Histories in Arc Magmas

    NASA Astrophysics Data System (ADS)

    George, R.; Turner, S.; Berlo, K.; Pearson, N.

    2005-12-01

    Discrepancy between crystal ages derived by short-lived chronometers with vastly differing half-lives is one manifestation of the potential for complex, multistage evolution of phenocrysts in arc magmatic systems. Deciphering these processes is critical for estimating realistic crystal histories and, ultimately, the physical mechanisms of differentiation. Some of the biggest chronological discrepancies are evident in the andesitic compositional range, the most ubiquitous material erupted at arcs. In some systems, such as Sangeang Api in the Sunda arc, U-Th and Ra-Th systematics of bulk plagioclase separates are not in conflict and indicate that differentiation occurred over several 1000 years via crystallization due to cooling in the lower crust. Here, 210Pb data indicate significant degassing occurred in the decade prior to eruption but post-dated phenocryst growth and magma differentiation. Combined textural and U-Th-Ra isotope approaches often, however, provide compelling evidence that plagioclase phenocrysts contain old cores and thus are zoned in both age and composition. One of the best examples of apparently conflicting time-scale information comes from Soufriere volcano on St. Vincent in the Lesser Antilles. U-Th isotopes analyses of bulk plagioclase separates conflict with whole-rock and mineral Ra-Th disequilibria and attest to non-linear growth histories, and involvement of recycled cumulates upon which renewed crystal growth has taken place. We augment this well-constrained case study with new in situ Sr isotope analyses for one of the Soufriere lavas and a cumulate xenolith erupted in 1979. Significant isotope heterogeneity is observed, and complimentary isotope variations exist between cumulate xenolith and lava plagioclase phenocryst cores, lending further support to the model of heterogeneous core-rim evolution in the Soufriere system. We conclude that mineral time scales should always be cross-examined with other textural and/or isotope techniques

  11. Anhydrite solubility in differentiated arc magmas

    NASA Astrophysics Data System (ADS)

    Masotta, M.; Keppler, H.

    2015-06-01

    The solubility of anhydrite in differentiated arc magmas was experimentally studied at 200 MPa and 800-1000 °C over a range of oxygen fugacities, from 0.5 log units above the Ni-NiO buffer to the hematite-magnetite buffer. Anhydrite is stable only at oxidizing conditions (fO2 ⩾ Re-ReO2), whereas sulfides only form under reducing conditions. The solubility of anhydrite in the melt ultimately regulates the amount of sulfur available to partition between melt and fluid phase during the eruption. At oxidizing conditions, the solubility product of anhydrite increases with temperature, nbo/t and melt water content. We provide a new calibration of the anhydrite solubility product (KSP = XCaO * XSO3), which reproduces all available experimental data with greatly improved accuracy: In this equation, the molar fractions XCaO and XSO3 in the melt as well as the number of non-bridging oxygen atoms per tetrahedron (nbo/t) are calculated on an anhydrous basis (H2O refers to the melt water content, T is temperature in Kelvin). We apply our model to estimate the sulfur yield of some recent volcanic eruptions and we show that the sulfur yield of the 1991 Mt. Pinatubo dacite eruption was unusually large, because only a small fraction of the sulfur was locked up in anhydrite. In general, high sulfur yields are expected when anhydrite solubility in the melt is high, i.e. for somewhat depolymerized melts. For rhyolitic systems, most of the available sulfur will be locked up in anhydrite, so that even very large eruptions may only have a small effect on global surface temperatures. Our model therefore allows improved predictions of the environmental impact of explosive volcanic eruptions.

  12. The rheology of crystal-rich magmas (Kuno Award Lecture)

    NASA Astrophysics Data System (ADS)

    Huber, Christian; Aldin Faroughi, Salah; Degruyter, Wim

    2016-04-01

    The rheology of magmas controls not only eruption dynamics but also the rate of transport of magmas through the crust and to a large extent the rate of magma differentiation and degassing. Magma bodies stalled in the upper crust are known to spend most of their lifespan above the solidus at a high crystal content (Cooper and Kent, 2014; Huber et al., 2009), where the probability of melt extraction (crystal fractionation) is the greatest (Dufek and Bachmann, 2010). In this study, we explore a new theoretical framework to study the viscosity of crystal bearing magmas. Since the seminal work of A. Einstein and W. Sutherland in the early 20th century, it has been shown theoretically and tested experimentally that a simple self-similar behavior exist between the relative viscosity of dilute (low crystal content) suspensions and the particle volume fraction. The self-similar nature of that relationship is quickly lost as we consider crystal fractions beyond a few volume percent. We propose that the relative viscosity of crystal-bearing magmas can be fully described by two state variables, the intrinsic viscosity and the crowding factor (a measure of the packing threshold in the suspension). These two state variables can be measured experimentally under different conditions, which allows us to develop closure relationships in terms of the applied shear stress and the crystal shape and size distributions. We build these closure equations from the extensive literature on the rheology of synthetic suspensions, where the nature of the particle shape and size distributions is better constrained and apply the newly developed model to published experiments on crystal-bearing magmas. We find that we recover a self-similar behavior (unique rheology curve) up to the packing threshold and show that the commonly reported break in slope between the relative viscosity and crystal volume fraction around the expected packing threshold is most likely caused by a sudden change in the state

  13. A conceptual model of Kilauea's magma plumbing system

    NASA Astrophysics Data System (ADS)

    Poland, M. P.; Miklius, A.; Montgomery-Brown, E. K.

    2013-12-01

    The current magma plumbing system of Kilauea Volcano, Hawai`i, is routinely described as consisting of a conduit that extends upward from mantle depths and feeds a magma storage reservoir beneath the summit caldera. From the summit reservoir, rift zones radiate to the east and southwest. Geological and geophysical observations, however, suggest a more complex picture. Models of the summit magma storage area include at least three discrete reservoirs. The largest is centered at ~3 km depth beneath the southern part of the caldera and serves as the main storage volume for the volcano. A smaller body lies 1-2 km beneath the east margin of Halema`uma`u Crater and presumably feeds the summit eruptive vent (active since 2008). Magma is also occasionally stored beneath the southeast part of the caldera near Keanakāko`i Crater, where the east rift zone intersects the summit. The reservoirs are interconnected, but the level of connectivity appears to vary according to pressurization of the magma plumbing system. Kilauea's rift zone system extends both to the east and southwest as paired shallow and deeper sections. The deeper rift zones (~3-km depth) are connected to the south caldera reservoir and, along with the Koa`e fault system, represent the structural boundaries of Kilauea's mobile south flank. Both trend southward near the summit before bending into east/northeast- and southwest-directed orientations, which may reflect southward migration of the rift zones over time due to seaward motion of the volcano's south flank (originally proposed by Swanson et al., 1976). Isolated pods of magma (relict from past intrusions) are scattered along the rift zone trends, and molten cores allow for rapid transport of magma between the summit and distal eruption/intrusion sites portions. The shallow rift zones (~1-km depth) are connected to the summit magma system via the Halema`uma`u reservoir and probably represent the former locations of the main rift systems. While this model is

  14. Magma storage prior to the 1912 eruption at Novarupta, Alaska

    USGS Publications Warehouse

    Hammer, J.E.; Rutherford, M.J.; Hildreth, W.

    2002-01-01

    New analytical and experimental data constrain the storage and equilibration conditions of the magmas erupted in 1912 from Novarupta in the 20th century's largest volcanic event. Phase relations at H2O+CO2 fluid saturation were determined for an andesite (58.7 wt% SiO2) and a dacite (67.7 wt%) from the compositional extremes of intermediate magmas erupted. The phase assemblages, matrix melt composition and modes of natural andesite were reproduced experimentally under H2O-saturated conditions (i.e., PH2O=PTOT) in a negatively sloping region in T-P space from 930 ??C/100 MPa to 960 ??C/75 MPa with fO2???N NO + 1. The H2O-saturated equilibration conditions of the dacite are constrained to a T-P region from 850 ??C/ 50 MPa to 880 ??C/25 MPa. If H2O-saturated, these magmas equilibrated at (and above) the level where coerupted rhyolite equilibrated (???100 MPa), suggesting that the andesite-dacite magma reservoir was displaced laterally rather than vertically from the rhyolite magma body. Natural mineral and melt compositions of intermediate magmas were also reproduced experimentally under saturation conditions with a mixed (H2O + CO2) fluid for the same range in PH2O. Thus, a storage model in which vertically stratified mafic to silicic intermediate magmas underlay H2O-saturated rhyolite is consistent with experimental findings only if the intermediates have XH2Ofl=0.7 and 0.9 for the extreme compositions, respectively. Disequilibrium features in natural pumice and scoria include pristine minerals existing outside their stability fields, and compositional zoning of titanomagnetite in contact with ilmenite. Variable rates of chemical equilibration which would eliminate these features constrain the apparent thermal excursion and re-distribution of minerals to the time scale of days.

  15. Crystallization and Cooling of a Deep Silicate Magma Ocean

    NASA Astrophysics Data System (ADS)

    Wolf, A. S.; Bower, D. J.

    2015-12-01

    Impact and accretion simulations of terrestrial planet formation suggest that giant impacts are both common and expected to produce extensive melting. The moon-forming impact, for example, likely melted the majority of Earth's mantle to produce a global magma ocean that subsequently cooled and crystallized (e.g. Nakajima and Stevenson, 2015). Understanding the cooling process is critical to determining magma ocean lifetimes and recognizing possible remnant signatures of the magma ocean in present-day mantle heterogeneities (i.e. Labrosse et al., 2007). Modeling this evolution is challenging, however, due to the vastly different timescales and lengthscales associated with turbulent convection (magma ocean) and viscous creep (present-day mantle), in addition to uncertainties in material properties and chemical partitioning. We consider a simplified spherically-symmetric (1-D) magma ocean to investigate both its evolving structure and cooling timescale. Extending the work of Abe (1993), mixing-length theory is employed to determine convective heat transport, producing a high resolution model that captures the ultra-thin boundary layer (few cms) at the surface of the magma ocean. The thermodynamics of mantle melting are represented using a pseudo-one-component model, which retains the simplicity of a standard one-component model while introducing a finite temperature interval for melting (important for multi-component systems). We derive a new high P-T equation of state (EOS) formulation designed to capture the energetics and physical properties of the partially molten system using parameters that are readily interpreted in the context of magma ocean crystallization. This model is used to determine the cooling timescale for a variety of plausible thermodynamic models, with special emphasis on comparing the center-outwards vs bottom-up cooling scenarios that arise from the assumed EOS (e.g., Mosenfelder et al., 2009; Stixrude et al., 2009).

  16. Linking Plagioclase Zoning Patterns to Active Magma Processes

    NASA Astrophysics Data System (ADS)

    Izbekov, P. E.; Nicolaysen, K. P.; Neill, O. K.; Shcherbakov, V.; Plechov, P.; Eichelberger, J. C.

    2015-12-01

    Plagioclase, one of the most common and abundant mineral phases in volcanic products, will vary in composition in response to changes in temperature, pressure, composition of the ambient silicate melt, and melt H2O concentration. Changes in these parameters may cause dissolution or growth of plagioclase crystals, forming characteristic textural and compositional variations (zoning patterns), the complete core-to-rim sequence of which describes events experienced by an individual crystal from its nucleation to the last moments of its growth. Plagioclase crystals in a typical volcanic rock may look drastically dissimilar despite their spatial proximity and the fact that they have erupted together. Although they shared last moments of their growth during magma ascent and eruption, their prior experiences could be very different, as plagioclase crystals often come from different domains of the same magma system. Distinguishing similar zoning patterns, correlating them across the entire population of plagioclase crystals, and linking these patterns to specific perturbations in the magmatic system may provide additional perspective on the variety, extent, and timing of magma processes at active volcanic systems. Examples of magma processes, which may be distinguished based on plagioclase zoning patterns, include (1) cooling due to heat loss, (2) heating and/or pressure build up due to an input of new magmatic material, (3) pressure drop in response to magma system depressurization, and (4) crystal transfer between different magma domains/bodies. This review will include contrasting examples of zoning patters from recent eruptions of Karymsky, Bezymianny, and Tolbachik Volcanoes in Kamchatka, Augustine and Cleveland Volcanoes in Alaska, as well as from the drilling into an active magma body at Krafla, Iceland.

  17. Megacrystals track magma convection between reservoir and surface

    NASA Astrophysics Data System (ADS)

    Moussallam, Yves; Oppenheimer, Clive; Scaillet, Bruno; Buisman, Iris; Kimball, Christine; Dunbar, Nelia; Burgisser, Alain; Ian Schipper, C.; Andújar, Joan; Kyle, Philip

    2015-03-01

    Active volcanoes are typically fed by magmatic reservoirs situated within the upper crust. The development of thermal and/or compositional gradients in such magma chambers may lead to vigorous convection as inferred from theoretical models and evidence for magma mixing recorded in volcanic rocks. Bi-directional flow is also inferred to prevail in the conduits of numerous persistently-active volcanoes based on observed gas and thermal emissions at the surface, as well as experiments with analogue models. However, more direct evidence for such exchange flows has hitherto been lacking. Here, we analyse the remarkable oscillatory zoning of anorthoclase feldspar megacrystals erupted from the lava lake of Erebus volcano, Antarctica. A comprehensive approach, combining phase equilibria, solubility experiments and melt inclusion and textural analyses shows that the chemical profiles are best explained as a result of multiple episodes of magma transport between a deeper reservoir and the lava lake at the surface. Individual crystals have repeatedly travelled up-and-down the plumbing system, over distances of up to several kilometers, presumably as a consequence of entrainment in the bulk magma flow. Our findings thus corroborate the model of bi-directional flow in magmatic conduits. They also imply contrasting flow regimes in reservoir and conduit, with vigorous convection in the former (regular convective cycles of ∼150 days at a speed of ∼0.5 mm s-1) and more complex cycles of exchange flow and re-entrainment in the latter. We estimate that typical, 1-cm-wide crystals should be at least 14 years old, and can record several (from 1 to 3) complete cycles between the reservoir and the lava lake via the conduit. This persistent recycling of phonolitic magma is likely sustained by CO2 fluxing, suggesting that accumulation of mafic magma in the lower crust is volumetrically more significant than that of evolved magma within the edifice.

  18. Experimental constraints on the outgassing dynamics of basaltic magmas

    NASA Astrophysics Data System (ADS)

    Pioli, L.; Bonadonna, C.; Azzopardi, B. J.; Phillips, J. C.; Ripepe, M.

    2012-03-01

    The dynamics of separated two-phase flow of basaltic magmas in cylindrical conduits has been explored combining large-scale experiments and theoretical studies. Experiments consisted of the continuous injection of air into water or glucose syrup in a 0.24 m diameter, 6.5 m long bubble column. The model calculates vesicularity and pressure gradient for a range of gas superficial velocities (volume flow rates/pipe area, 10-2-102 m/s), conduit diameters (100-2 m), and magma viscosities (3-300 Pa s). The model is calibrated with the experimental results to extrapolate key flow parameters such as Co (distribution parameter) and Froude number, which control the maximum vesicularity of the magma in the column, and the gas rise speed of gas slugs. It predicts that magma vesicularity increases with increasing gas volume flow rate and decreases with increasing conduit diameter, until a threshold value (45 vol.%), which characterizes churn and annular flow regimes. Transition to annular flow regimes is expected to occur at minimum gas volume flow rates of 103-104 m3/s. The vertical pressure gradient decreases with increasing gas flow rates and is controlled by magma vesicularity (in bubbly flows) or the length and spacing of gas slugs. This study also shows that until conditions for separated flow are met, increases in magma viscosity favor stability of slug flow over bubbly flow but suggests coexistence between gas slugs and small bubbles, which contribute to a small fraction of the total gas outflux. Gas flow promotes effective convection of the liquid, favoring magma homogeneity and stable conditions.

  19. Modelling of a magma energy geothermal power plant

    SciTech Connect

    Boehm, R.F.; Berg, D.L.; Jr.; Ortega, A.

    1987-01-01

    We are currently investigating the engineering feasibility of drilling into an active magma body at a depth of roughly 5 km from the earth's surface, establishing a downhole heat exchange region, and extracting thermal energy from the magma body by circulating fluid through this heat exchange region. In the present paper, we evaluate the overall thermodynamic performance of various conceptual magma energy systems in which energy is added as heat to the fluid within the magma region and is converted to useful work in a power conversion cycle at the surface. Unusually high return temperatures and pressures may be available at the wellhead of such a circulating well. Cycles investigated here are an open Rankine power system in which steam from the magma well is circulated directly through a power conversion cycle and a closed Rankine cycle where the heated fluid from downhole is circulated through an aboveground heat exchanger to heat the cycle fluid. The downhole heat exchange region is established during the drilling process. As drilling proceeds into the magma, a solidified layer forms about the drilling tube due to heat exchange to the fluid. This solidified layer thermally fractures because of large temperature gradients between the cooled inner region and the heated outer region, thereby opening secondary flow paths. Two models of the downhole behavior have been used. In the simplest approach, denoted as the ''infinite area model,'' the water entering the pipe to return to the surface is assumed to be always at the temperature of the magma, independent of mass flow rate and other parameters. The other model is more detatiled and the fractured heat exchange region is modelled as a cylindrical porous layer through which fluid flows vertically. The net power and the performance aspects for the systems are investigated in terms of various parameters, including the characteristics of the downhole heat transfer.

  20. Geochemistry and zircon geochronology of Late Proterozoic leucogranites north of Boston, eastern Massachusetts

    SciTech Connect

    Markus, R.; Hon, R. . Geology and Geophysics); Dunning, G. . Dept. of Earth Sciences)

    1993-03-01

    An igneous sequence that includes Late Precambrian volcanics (Lynn Volcanics) and granites, granodiorites, tonalites, plus diorites of the Dedham North suite, is located in a tectonic block bounded by the Walden Pond and Northern Boundary Faults north of the Boston Basin. Within the block between the rhyolites and granodiorites is a several hundred foot wide zone of leucogranites that contains frequent roof pendants in various stages of partial melting. The migmatitic nature of the pendants suggests that the leucogranites were locally derived by melt extraction from the partially melted pendant xenoliths. U-Pb zircon ages were obtained from samples of the leucogranite, granodiorite and diorite. Their crystallization ages are: leucogranite 609 [+-] 4 Ma, granodiorite 607 [+-] 4 Ma, and diorite 606 [+-] 3 Ma. All three samples yield ages that are identical within their statistical error limits and all three samples contain inherited component with average mid-Proterozoic ages. Major and trace element geochemistry of 43 samples of all representative types show that the predominantly pelitic'' layers underwent extensive partial melting and that the leucogranites represent a minimum granite melt at 0.5 to 2.0 kb of P(H2O). Geochemical modeling also supports the origin by partial melting of the pendant inclusions. Once formed, the leucogranite melts were then mixed with mafic magmas which must have also been the provider of the necessary heat to sustain the partial melting process. The data indicate that the Dedham North plutonic suite was formed at shallow crustal levels and that its compositional range is a result of magma mixing of varying proportions between the leucogranite and mafic melts.

  1. Magma Storage Conditions, Eruption Initiation and Magma Evolution Over Time: Investigating the Eruptions of Organ Caldera, Southern NM

    NASA Astrophysics Data System (ADS)

    Lente, J. L.; Johnson, E. R.

    2015-12-01

    The Organ caldera in southern New Mexico formed ~36 Ma from a series of three explosive, voluminous eruptions. The volcanic deposits are now exposed in the Organ Mountains and have a combined thickness of nearly 3 km and an estimated volume between 500 and1000 km3 (Seager & McCurry, 1988). This research uses analyses of quartz-hosted melt inclusions from the first- and last-erupted units to study the storage and differentiation of the magma body prior-to and during the initial eruption, as well as changes in the magma chamber over time as the eruptions progressed and ultimately ceased. Previous work suggests the Organ magma chamber was compositionally stratified (Seager, 1981) erupting top-down and tapping less-evolved magmas over time. However, preliminary results suggest a more complex system; possibly a convecting, homogenized magma chamber or a series of dykes and sills. Results obtained using FTIR analyses of H2O and CO2 in melt inclusions have shown variable volatile contents from the first erupted unit (~2.3 to 6.8 weight percent H2O, 0-118 ppm CO2). Using these values, saturation pressures of 45 to 266 MPa were calculated, indicating a minimum pressure at which the melt inclusion was trapped. These pressures suggest magma storage depths for the first erupted magmas of ~2 to 9 km (with most inclusions trapped between 4 and 8 km) which is inconsistent with the initial eruption coming from the top of a normally stratified chamber. The large variation in volatile contents and storage depths can have many explanations, such as degassing and shallow crystallization during ascent, or perhaps a more complex, elongate magma storage system. These possibilities, and whether or not magma mixing/rejuvenation triggered the initial eruption, will be explored with the acquisition of major and trace element compositions of melt inclusions. Additionally, analyses of melt inclusions from the last erupted ignimbrite, which erupted ~0.5 Ma after the first eruption, will enable

  2. Geochemistry of the Lathrop Wells volcanic center

    SciTech Connect

    Perry, F.V.; Straub, K.T.

    1996-03-01

    Over 100 samples have been gathered from the Lathrop Wells volcanic center to assess different models of basalt petrogenesis and constrain the physical mechanisms of magma ascent in the Yucca Mountain region. Samples have been analyzed for major and trace-element chemistry, Nd, Sr and Ph isotopes, and mineral chemistry. All eruptive units contain olivine phenocrysts, but only the oldest eruptive units contain plagioclase phenocrysts. Compositions of minerals vary little between eruptive units. Geochemical data show that most of the eruptive units at Lathrop Wells defined by field criteria can be distinguished by major and trace-element chemistry. Normative compositions of basalts at Lathrop Wells correlate with stratigraphic position. The oldest basalts are primarily nepheline normative and the youngest basalts are exclusively hypersthene normative, indicating increasing silica saturation with time. Trace-element and major-element variations among eruptive units are statistically significant and support the conclusion that eruptive units at Lathrop Wells represent separate and independent magma batches. This conclusion indicates that magmas in the Yucca Mountain region ascend at preferred eruption sites rather than randomly.

  3. Redox systematics of a magma ocean with variable pressure-temperature gradients and composition.

    PubMed

    Righter, K; Ghiorso, M S

    2012-07-24

    Oxygen fugacity in metal-bearing systems controls some fundamental aspects of the geochemistry of the early Earth, such as the FeO and siderophile trace element content of the mantle, volatile species that influence atmospheric composition, and conditions for organic compounds synthesis. Redox and metal-silicate equilibria in the early Earth are sensitive to oxygen fugacity (fO(2)), yet are poorly constrained in modeling and experimentation. High pressure and temperature experimentation and modeling in metal-silicate systems usually employs an approximation approach for estimating fO(2) that is based on the ratio of Fe and FeO [called "ΔIW (ratio)" hereafter]. We present a new approach that utilizes free energy and activity modeling of the equilibrium: Fe + SiO(2) + O(2) = Fe(2)SiO(4) to calculate absolute fO(2) and relative to the iron-wüstite (IW) buffer at pressure and temperature [ΔIW (P,T)]. This equilibrium is considered across a wide range of pressures and temperatures, including up to the liquidus temperature of peridotite (4,000 K at 50 GPa). Application of ΔIW (ratio) to metal-silicate experiments can be three or four orders of magnitude different from ΔIW (P,T) values calculated using free energy and activity modeling. We will also use this approach to consider the variation in oxygen fugacity in a magma ocean scenario for various thermal structures for the early Earth: hot liquidus gradient, 100 °C below the liquidus, hot and cool adiabatic gradients, and a cool subsolidus adiabat. The results are used to assess the effect of increasing P and T, changing silicate composition during accretion, and related to current models for accretion and core formation in the Earth. The fO(2) in a deep magma ocean scenario may become lower relative to the IW buffer at hotter and deeper conditions, which could include metal entrainment scenarios. Therefore, fO(2) may evolve from high to low fO(2) during Earth (and other differentiated bodies) accretion. Any

  4. Magma sources during Gondwana breakup: chemistry and chronology of Cretaceous magmatism in Westland, New Zealand

    NASA Astrophysics Data System (ADS)

    van der Meer, Quinten H. A.; Waight, Tod E.; Scott, James M.

    2013-04-01

    Cretaceous-Paleogene rifting of the Eastern Gondwana margin thinned the continental crust of Zealandia and culminated in the opening of the Tasman Sea between Australia and New Zealand and the Southern Ocean, separating both from Antarctica. The Western Province of New Zealand consists of a succession of metasedimentary rocks intruded by Palaeozoic and Mesozoic granitoids that formed in an active margin setting through the Phanerozoic. Upon cessation of subduction, the earliest stages of extension (~110-100 Ma) were expressed in the formation of metamorphic core complexes, followed by emplacement of granitoid plutons, the deposition of terrestrial Pororari Group sediments in extensional half-grabens across on- and offshore Westland, and the intrusion of mafic dikes from ~90 Ma. These dikes are concentrated in the swarms of the Paparoa and Hohonu Ranges and were intruded prior to and simultaneous with volumetrically minor A-type plutonism at 82 Ma. The emplacement of mafic dikes and A-type plutonism at ~82 Ma is significant as it coincides with the age of the oldest seafloor in the Tasman Sea, therefore it represents magmatism coincident with the initiation of seafloor spreading which continued until ~53 Ma. New 40Ar-39Ar ages indicate that the intrusion of mafic dikes in basement lithologies both preceded and continued after the initial opening of the Tasman Sea, including an additional population of ages at ~70 Ma. This indicates either a prolonged period of extension-related magmatism that continued >10 Ma after initial breakup, or two discrete episodes of magmatism during Tasman Sea spreading. Volumetrically minor Cenozoic within-plate magmatism continued sporadically throughout the South Island and bears a characteristic HIMU (high time integrated U/Pb) signature. A detailed geochemistry and chronological study of Cretaceous mafic and felsic magmatism is currently in progress and aims to better understand the transition of magma sources from a long lived active

  5. Redox systematics of a magma ocean with variable pressure-temperature gradients and composition

    PubMed Central

    Righter, K.; Ghiorso, M. S.

    2012-01-01

    Oxygen fugacity in metal-bearing systems controls some fundamental aspects of the geochemistry of the early Earth, such as the FeO and siderophile trace element content of the mantle, volatile species that influence atmospheric composition, and conditions for organic compounds synthesis. Redox and metal-silicate equilibria in the early Earth are sensitive to oxygen fugacity (fO2), yet are poorly constrained in modeling and experimentation. High pressure and temperature experimentation and modeling in metal-silicate systems usually employs an approximation approach for estimating fO2 that is based on the ratio of Fe and FeO [called “ΔIW (ratio)” hereafter]. We present a new approach that utilizes free energy and activity modeling of the equilibrium: Fe + SiO2 + O2 = Fe2SiO4 to calculate absolute fO2 and relative to the iron-wüstite (IW) buffer at pressure and temperature [ΔIW (P,T)]. This equilibrium is considered across a wide range of pressures and temperatures, including up to the liquidus temperature of peridotite (4,000 K at 50 GPa). Application of ΔIW (ratio) to metal-silicate experiments can be three or four orders of magnitude different from ΔIW (P,T) values calculated using free energy and activity modeling. We will also use this approach to consider the variation in oxygen fugacity in a magma ocean scenario for various thermal structures for the early Earth: hot liquidus gradient, 100 °C below the liquidus, hot and cool adiabatic gradients, and a cool subsolidus adiabat. The results are used to assess the effect of increasing P and T, changing silicate composition during accretion, and related to current models for accretion and core formation in the Earth. The fO2 in a deep magma ocean scenario may become lower relative to the IW buffer at hotter and deeper conditions, which could include metal entrainment scenarios. Therefore, fO2 may evolve from high to low fO2 during Earth (and other differentiated bodies) accretion. Any modeling of

  6. Redox systematics of a magma ocean with variable pressure-temperature gradients and composition.

    PubMed

    Righter, K; Ghiorso, M S

    2012-07-24

    Oxygen fugacity in metal-bearing systems controls some fundamental aspects of the geochemistry of the early Earth, such as the FeO and siderophile trace element content of the mantle, volatile species that influence atmospheric composition, and conditions for organic compounds synthesis. Redox and metal-silicate equilibria in the early Earth are sensitive to oxygen fugacity (fO(2)), yet are poorly constrained in modeling and experimentation. High pressure and temperature experimentation and modeling in metal-silicate systems usually employs an approximation approach for estimating fO(2) that is based on the ratio of Fe and FeO [called "ΔIW (ratio)" hereafter]. We present a new approach that utilizes free energy and activity modeling of the equilibrium: Fe + SiO(2) + O(2) = Fe(2)SiO(4) to calculate absolute fO(2) and relative to the iron-wüstite (IW) buffer at pressure and temperature [ΔIW (P,T)]. This equilibrium is considered across a wide range of pressures and temperatures, including up to the liquidus temperature of peridotite (4,000 K at 50 GPa). Application of ΔIW (ratio) to metal-silicate experiments can be three or four orders of magnitude different from ΔIW (P,T) values calculated using free energy and activity modeling. We will also use this approach to consider the variation in oxygen fugacity in a magma ocean scenario for various thermal structures for the early Earth: hot liquidus gradient, 100 °C below the liquidus, hot and cool adiabatic gradients, and a cool subsolidus adiabat. The results are used to assess the effect of increasing P and T, changing silicate composition during accretion, and related to current models for accretion and core formation in the Earth. The fO(2) in a deep magma ocean scenario may become lower relative to the IW buffer at hotter and deeper conditions, which could include metal entrainment scenarios. Therefore, fO(2) may evolve from high to low fO(2) during Earth (and other differentiated bodies) accretion. Any

  7. Oxygen Isotope Trajectories of Crystallizing Arc Magmas

    NASA Astrophysics Data System (ADS)

    Bucholz, C. E.; Jagoutz, O. E.; VanTongeren, J. A.; Wang, Z.

    2014-12-01

    Oxygen isotopes are essential to quantify mantle-derived versus 'recycled' crustal contributions to arc magmas. High δ18O values in igneous rocks (i.e., δ18OSMOW > ~5.7) are generally used to identify supra-crustal inputs, but a melt can also become enriched in 18O due to magmatic differentiation [1,2]. To assess magmatic δ18O values of plutonic rocks, δ18Ozircon values, which are resilient to secondary alteration, are often used. Thus, to disentangle the effects of assimilation versus fractionation, both the absolute increase in melt δ18O due to differentiation and ∆18O(WR-zircon) must be determined. However, existing constraints on the effect of magmatic fractionation on melt δ18O are model-based [2] and calculated relationships between WR SiO2, δ18Ozircon, and δ18Omelt do not incorporate complex melt SiO2, H2O, and temperature (T) relationships [3]. To build upon these initial constraints, we combine the first high-precision δ18O data set on natural samples documenting changes in δ18O melt values with increasing extent of differentiation and modeling which incorporates experimentally constrained melt SiO2, H2O, and T relationships. We analyzed 55 mineral separates with infrared laser-fluorination [4] across large fractionation intervals of two well-studied cumulate sequences: (I) a relatively dry (~1 wt.% H2O initial) tholeiitic sequence (analyzed minerals include plag, opx, cpx, & Fe-rich ol) from the Bushveld Complex and (II) a hydrous high-K sequence (analyzed minerals include ol, cpx, bt, fsp, & qtz) from the Dariv paleoarc in Mongolia. Our results indicate that multiple per mil increases in melt δ18O can occur during magmatic fractionation that in detail depend strongly on melt composition and T. Calculated relationships between WR SiO2 and δ18Ozircon for experimental melt compositions show that wet, 'cool' and dry, 'hot' melts are characterized by larger and smaller ∆18O (melt-zircon) fractionations, respectively. Applying our results to

  8. Contaminant geochemistry--a new perspective.

    PubMed

    Yaron, Bruno; Dror, Ishai; Berkowitz, Brian

    2010-01-01

    To date, the field of contaminant geochemistry--which deals with the study of chemical interactions in soil and aquifer environments--has focused mainly on pollutant toxicity, retention, persistence, and transport and/or on remediation of contaminated sites. Alteration of subsurface physicochemical properties by anthropogenic chemicals, which reach the land surface as a result of human activity, has been essentially neglected. Contaminant-induced changes in subsurface properties are usually considered as deviations from a normal geological environment, which will disappear under natural attenuation or following remediation procedures. However, contaminants may in many cases cause irreversible changes in both structure and properties of the soil-subsurface geosystem between the land surface and groundwater. The time scales associated with these changes are on a "human time scale", far shorter than geological scales relevant for geochemical processes. In this review, we draw attention to a new perspective of contaminant geochemistry, namely, irreversible changes in the subsurface as a result of anthropogenic chemical pollution. We begin by briefly reviewing processes governing contaminant-subsurface interactions. We then survey how chemical contamination causes irreversible changes in subsurface structure and properties. The magnitude of the anthropogenic impact on the soil and subsurface is linked directly to the amounts of chemical contaminants applied and/or disposed of on the land surface. This particular aspect is of major importance when examining the effects of humans on global environmental changes. Consideration of these phenomena opens new perspectives for the field of contaminant geochemistry and for research of human impacts on the soil and subsurface regimes.

  9. Eddy Flow during Magma Emplacement: The Basemelt Sill, Antarctica

    NASA Astrophysics Data System (ADS)

    Petford, N.; Mirhadizadeh, S.

    2014-12-01

    The McMurdo Dry Valleys magmatic system, Antarctica, forms part of the Ferrar dolerite Large Igneous Province. Comprising a vertical stack of interconnected sills, the complex provides a world-class example of pervasive lateral magma flow on a continental scale. The lowermost intrusion (Basement Sill) offers detailed sections through the now frozen particle macrostructure of a congested magma slurry1. Image-based numerical modelling where the intrusion geometry defines its own unique finite element mesh allows simulations of the flow regime to be made that incorporate realistic magma particle size and flow geometries obtained directly from field measurements. One testable outcome relates to the origin of rhythmic layering where analytical results imply the sheared suspension intersects the phase space for particle Reynolds and Peclet number flow characteristic of macroscopic structures formation2. Another relates to potentially novel crystal-liquid segregation due to the formation of eddies locally at undulating contacts at the floor and roof of the intrusion. The eddies are transient and mechanical in origin, unrelated to well-known fluid dynamical effects around obstacles where flow is turbulent. Numerical particle tracing reveals that these low Re number eddies can both trap (remove) and eject particles back into the magma at a later time according to their mass density. This trapping mechanism has potential to develop local variations in structure (layering) and magma chemistry that may otherwise not occur where the contact between magma and country rock is linear. Simulations indicate that eddy formation is best developed where magma viscosity is in the range 1-102 Pa s. Higher viscosities (> 103 Pa s) tend to dampen the effect implying eddy development is most likely a transient feature. However, it is nice to think that something as simple as a bumpy contact could impart physical and by implication chemical diversity in igneous rocks. 1Marsh, D.B. (2004), A

  10. Carbon dioxide in magmas and implications for hydrothermal systems

    USGS Publications Warehouse

    Lowenstern, J. B.

    2001-01-01

    This review focuses on the solubility, origin, abundance, and degassing of carbon dioxide (CO2) in magma-hydrothermal systems, with applications for those workers interested in intrusion-related deposits of gold and other metals. The solubility of CO2 increases with pressure and magma alkalinity. Its solubility is low relative to that of H2O, so that fluids exsolved deep in the crust tend to have high CO2/H2O compared with fluids evolved closer to the surface. Similarly, CO2/H2O will typically decrease during progressive decompression- or crystallization-induced degassing. The temperature dependence of solubility is a function of the speciation of CO2, which dissolves in molecular form in rhyolites (retrograde temperature solubility), but exists as dissolved carbonate groups in basalts (prograde). Magnesite and dolomite are stable under a relatively wide range of mantle conditions, but melt just above the solidus, thereby contributing CO2 to mantle magmas. Graphite, diamond, and a free CO2-bearing fluid may be the primary carbon-bearing phases in other mantle source regions. Growing evidence suggests that most CO2 is contributed to arc magmas via recycling of subducted oceanic crust and its overlying sediment blanket. Additional carbon can be added to magmas during magma-wallrock interactions in the crust. Studies of fluid and melt inclusions from intrusive and extrusive igneous rocks yield ample evidence that many magmas are vapor saturated as deep as the mid crust (10-15 km) and that CO2 is an appreciable part of the exsolved vapor. Such is the case in both basaltic and some silicic magmas. Under most conditions, the presence of a CO2-bearing vapor does not hinder, and in fact may promote, the ascent and eruption of the host magma. Carbonic fluids are poorly miscible with aqueous fluids, particularly at high temperature and low pressure, so that the presence of CO2 can induce immiscibility both within the magmatic volatile phase and in hydrothermal systems

  11. Insights Into Earthquake Nucleation and Fault Evolution Within Magma

    NASA Astrophysics Data System (ADS)

    Tuffen, H.; Sturton, S.; Dingwell, D. B.

    2004-05-01

    Volcanoes erupting highly viscous magma generate an exceptionally large amount of seismic energy per unit volume. Seismicity is unlike that generated on most tectonic faults, being characterised by repeated small events (Mw < 3) with identical waveforms and short inter-event times (from days to less than a second). Events occur in swarms with typical durations of hours to weeks and have anomalously low frequency content (dominant energy in the 1-3 Hz range). They also show no S-wave arrivals and occur within a small volume typically < 2 km from the surface. New field evidence suggests that these earthquakes may occur on small faults that nucleate by shear fracture of magma during conduit flow (Tuffen et al. Geology 31:1089-1092, 2003). Shear fracture occurs due to stress accumulation when strain rates are too high for purely viscous flow. The anastomosing fracture networks generated share many characteristics with "tectonic" pseudotachylites, including injection veins and evidence for fluidisation. Fracture networks evolve with continued slip into near-planar faults up to five metres in length that are rotated parallel to the magma flow direction. Cataclasite on fault planes bears the textural hallmarks of frictional stick-slip behaviour, with localised grain size reduction, slip localisation, and Riedel shear zones. Eventually, cohesive viscous deformation occurs due to frictional heating and strain rate decrease and completely heals the faults. This forms flow banding in obsidian, which is a kind of high-temperature pseudotachylite. This new evidence may help to explain some properties of the low-frequency earthquakes that occur during eruptions of high-viscosity magma: a) The short inter-event time may be due to high strain rates (10-6 to 10-2 s-1 are typical of eruptions of silicic magma). b) Similar events may be generated by multiple slip pulses on fault planes. c) The seismogenic lifetime of faults may be limited by the high temperature of the faulting

  12. Magmas, Mushes and Mobility: Thermal Histories of Magma Reservoirs from Combined U-Series and Diffusion Ages

    NASA Astrophysics Data System (ADS)

    Cooper, K. M.; Rubin, A. E.; Schrecengost, K.; Kent, A. J.; Huber, C.

    2014-12-01

    The thermal conditions of magma storage control many aspects of the dynamics of a magma reservoir system. For example, the temperature of magma storage directly relates to the crystallinity, and magmas stored at relatively low temperatures in a crystal mush (more than 40-50% crystalline) must be remobilized (e.g., by heating) before they can be erupted. A better understanding of the duration of magma storage at largely-liquid vs. largely-solid conditions is thus critical to understanding crustal magmatic processes such as magma mixing and for quantifying the hazard potential of a given volcano. Although mineral thermometry reflects the conditions of crystal growth or equilibration, these may not correspond to the thermal conditions of crystal storage. The duration of crystal storage at high temperatures can be quantified by comparing U-series crystal ages with the time scales over which disequilibrium trace-element profiles in the same crystals would be erased by diffusion. In the case of Mount Hood, OR, such a comparison for the two most recent eruptions shows that <12% of the total lifetime of plagioclase crystals (minimum 21 kyr) was spent at temperatures high enough that the magma would be easily mobilized. Partial data sets for other systems suggest such behavior is common, although the diffusion and U-series ages in these cases are from different samples and may not be directly comparable. We will present preliminary data combining U-series dating and diffusion timescales on the same samples for other volcanic systems (e.g., Lassen Volcanic Center, Mount St. Helens, Okataina Volcanic Center, New Zealand). Combining these data with numerical models offers additional insights into the controls on the conditions of storage. In addition, extension of this approach to combining U-Th ages with time scales of Li diffusion in zircon offers a promising new method to quantify thermal histories of silicic reservoir systems.

  13. Linking magma transport structures at Kīlauea volcano

    NASA Astrophysics Data System (ADS)

    Wech, Aaron G.; Thelen, Weston A.

    2015-09-01

    Identifying magma pathways is important for understanding and interpreting volcanic signals. At Kīlauea volcano, seismicity illuminates subsurface plumbing, but the broad spectrum of seismic phenomena hampers event identification. Discrete, long-period (LP) events dominate the shallow (5-10 km) plumbing, and deep (40+ km) tremor has been observed offshore. However, our inability to routinely identify these events limits their utility in tracking ascending magma. Using envelope cross-correlation, we systematically catalog non-earthquake seismicity between 2008 and 2014. We find that the LPs and deep tremor are spatially distinct, separated by the 15-25 km deep, horizontal mantle fault zone (MFZ). Our search corroborates previous observations, but we find broader band (0.5-20 Hz) tremor comprising collocated earthquakes and reinterpret the deep tremor as earthquake swarms in a volume surrounding and responding to magma intruding from the mantle plume beneath the MFZ. We propose that the overlying MFZ promotes lateral magma transport, linking this deep intrusion with Kīlauea's shallow magma plumbing.

  14. Linking magma transport structures at Kīlauea volcano

    USGS Publications Warehouse

    Wech, Aaron G.; Thelen, Weston A.

    2015-01-01

    Identifying magma pathways is important for understanding and interpreting volcanic signals. At Kīlauea volcano, seismicity illuminates subsurface plumbing, but the broad spectrum of seismic phenomena hampers event identification. Discrete, long-period events (LPs) dominate the shallow (5-10 km) plumbing, and deep (40+ km) tremor has been observed offshore. However, our inability to routinely identify these events limits their utility in tracking ascending magma. Using envelope cross-correlation, we systematically catalog non-earthquake seismicity between 2008-2014. We find the LPs and deep tremor are spatially distinct, separated by the 15-25 km deep, horizontal mantle fault zone (MFZ). Our search corroborates previous observations, but we find broader-band (0.5-20 Hz) tremor comprising collocated earthquakes and reinterpret the deep tremor as earthquake swarms in a volume surrounding and responding to magma intruding from the mantle plume beneath the MFZ. We propose the overlying MFZ promotes lateral magma transport, linking this deep intrusion with Kīlauea’s shallow magma plumbing.

  15. Magma intrusion and accumulation in the southern Altiplano: Structural observations from the PLUTONS project

    NASA Astrophysics Data System (ADS)

    West, M. E.; Christensen, D. H.; Pritchard, M. E.; Del Potro, R.; Gottsmann, J.; Unsworth, M.; Minaya, E.; Sunagua, M.; McNutt, S. R.; Yu, Q.; Farrell, A. K.

    2012-12-01

    The PLUTONS project is attempting to capture the process of magma intrusion and pluton formation, in situ, through multi-disciplinary study of known magmatic inflation centers. With support from the NSF Continental Dynamics program, and a sister project in the UK funded by NERC, two such centers are receiving focused study. Uturuncu volcano in the Altiplano of southern Bolivia is being investigated with combined seismics, magnetotellurics, geodesy, microgravity, geomorphology, petrology, geochemistry, historical studies and modeling. 350 km to the south, comparable investigations are targeting the Lastarria-Cordon del Azufre complex. Field studies are ongoing into 2013. In this presentation we highlight results from Uturuncu that bear on the crustal magmatic process. Seismic tomography, gravity and magnetotellurics indicate a complex structure in the upper 20 km with some evidence for partial melt. Seismic receiver functions indicate a layer of very low velocities across the region at 15-25 km depth that is almost certainly melt-rich. High conductivities corroborate the interpretation of a partial melt component to this layer. In addition to the throughgoing melt layer, seismic velocities and attenuation indicate shallow features above the melt body extending upward toward the surface. It is not clear whether these features are associated with recent uplift or are remnants from a previous period of activity. Uturuncu is seismically active with hundreds of locatable earthquakes each year. Seismic lineations and swarm behavior suggest that the seismicity reflects regional stress patterns. While there is little evidence that these earthquakes are the direct result of magmatic intrusion, the resulting high heat flow may be hastening existing strains.

  16. Geochemistry and eruptive behaviour of the Finca la Nava maar volcano (Campo de Calatrava, south-central Spain)

    NASA Astrophysics Data System (ADS)

    Lierenfeld, Matthias Bernhard; Mattsson, Hannes B.

    2015-10-01

    Here we present a detailed investigation into the geochemistry and the excavational/depositional processes involved in the maar-diatreme forming Finca la Nava (FlN) eruption in south-central Spain. Bulk rock compositions of hand-picked juvenile fragments indicate derivation of the FIN magma from a garnet-bearing mantle source, which has subsequently been overprinted in bulk rock samples by incorporation of a combination of spinel-bearing peridotites and upper-crustal lithics (i.e. quartzites and slates). The dominating phenocryst assemblage with clinopyroxene, olivine, amphibole and phlogopite points to the classification of the juvenile magma as being olivine melilititic in composition. Ascent through the lithosphere was rapid as indicated by the calculations of settling rates of mantle peridotites (~0.8 m s-1). The original magma fragmentation level in the conduit was probably relatively shallow carrying mainly juvenile pyroclasts (~60 %) intermixed with accidental crustal lithics (~35 %) and mantle xenoliths (<5 %) to the surface. The shapes of individual pyroclasts are sub-rounded to rounded and with highly variable vesicularities (5-45 %). This fact, in combination with abundant fine-grained material in the beginning of the eruption, indicates that both magmatic and phreatomagmatic fragmentation processes may have played important roles in forming the FIN maar. A relatively constant increase in quartzitic fragments from ~35 to <60 % with increasing stratigraphic height in the FIN deposits further indicates that the crater area successively widened during the eruption, which resulted in an increased recycling of quartzitic fragments. This eruption scenario, with the formation of a diatreme at depth, is also consistent with the absence of layers dipping inwards into the crater area.

  17. Magma storage in a strike-slip caldera.

    PubMed

    Saxby, J; Gottsmann, J; Cashman, K; Gutiérrez, E

    2016-01-01

    Silicic calderas form during explosive volcanic eruptions when magma withdrawal triggers collapse along bounding faults. The nature of specific interactions between magmatism and tectonism in caldera-forming systems is, however, unclear. Regional stress patterns may control the location and geometry of magma reservoirs, which in turn may control the spatial and temporal development of faults. Here we provide new insight into strike-slip volcano-tectonic relations by analysing Bouguer gravity data from Ilopango caldera, El Salvador, which has a long history of catastrophic explosive eruptions. The observed low gravity beneath the caldera is aligned along the principal horizontal stress orientations of the El Salvador Fault Zone. Data inversion shows that the causative low-density structure extends to ca. 6 km depth, which we interpret as a shallow plumbing system comprising a fractured hydrothermal reservoir overlying a magmatic reservoir with vol% exsolved vapour. Fault-controlled localization of magma constrains potential vent locations for future eruptions. PMID:27447932

  18. The magma ocean as an impediment to lunar plate tectonics

    NASA Technical Reports Server (NTRS)

    Warren, Paul H.

    1993-01-01

    The primary impediment to plate tectonics on the moon was probably the great thickness of its crust and particularly its high crust/lithosphere thickness ratio. This in turn can be attributed to the preponderance of low-density feldspar over all other Al-compatible phases in the lunar interior. During the magma ocean epoch, the moon's crust/lithosphere thickness ratio was at the maximum theoretical value, approximately 1, and it remained high for a long time afterwards. A few large regions of thin crust were produced by basin-scale cratering approximately contemporaneous with the demise of the magma ocean. However, these regions probably also tend to have uncommonly thin lithosphere, since they were directly heated and indirectly enriched in K, Th, and U by the same cratering process. Thus, plate tectonics on the moon in the form of systematic lithosphere subduction was impeded by the magma ocean.

  19. Phenomena associated with magma expansion into a drift

    SciTech Connect

    Gaffney, E. S.

    2002-01-01

    One of the significant threats to the proposed Yucca Mountain nuclear waste repository has been identified as the possibility of intersection of the underground structure by a basaltic intrusion. Based on the geology of the region, it is assumed that such an intrusion would consist of an alkali basalt similar to the nearby Lathrop Wells cone, which has been dated at about 78 ka. The threat of radioactive release may be either from eruption through the surface above the repository of basalt that had been contaminated or from migration through ground water of radionucleides released as a result of damage to waste packages that interact with the magma. As part of our study of these threats, we are analyzing the phenomena associated with magma expansion into drifts in tuff. The early phenomena of the encounter of volatile-rich basaltic magma with a drift are discussed here.

  20. Magma storage in a strike-slip caldera.

    PubMed

    Saxby, J; Gottsmann, J; Cashman, K; Gutiérrez, E

    2016-07-22

    Silicic calderas form during explosive volcanic eruptions when magma withdrawal triggers collapse along bounding faults. The nature of specific interactions between magmatism and tectonism in caldera-forming systems is, however, unclear. Regional stress patterns may control the location and geometry of magma reservoirs, which in turn may control the spatial and temporal development of faults. Here we provide new insight into strike-slip volcano-tectonic relations by analysing Bouguer gravity data from Ilopango caldera, El Salvador, which has a long history of catastrophic explosive eruptions. The observed low gravity beneath the caldera is aligned along the principal horizontal stress orientations of the El Salvador Fault Zone. Data inversion shows that the causative low-density structure extends to ca. 6 km depth, which we interpret as a shallow plumbing system comprising a fractured hydrothermal reservoir overlying a magmatic reservoir with vol% exsolved vapour. Fault-controlled localization of magma constrains potential vent locations for future eruptions.

  1. Magma storage in a strike-slip caldera

    PubMed Central

    Saxby, J.; Gottsmann, J.; Cashman, K.; Gutiérrez, E.

    2016-01-01

    Silicic calderas form during explosive volcanic eruptions when magma withdrawal triggers collapse along bounding faults. The nature of specific interactions between magmatism and tectonism in caldera-forming systems is, however, unclear. Regional stress patterns may control the location and geometry of magma reservoirs, which in turn may control the spatial and temporal development of faults. Here we provide new insight into strike-slip volcano-tectonic relations by analysing Bouguer gravity data from Ilopango caldera, El Salvador, which has a long history of catastrophic explosive eruptions. The observed low gravity beneath the caldera is aligned along the principal horizontal stress orientations of the El Salvador Fault Zone. Data inversion shows that the causative low-density structure extends to ca. 6 km depth, which we interpret as a shallow plumbing system comprising a fractured hydrothermal reservoir overlying a magmatic reservoir with vol% exsolved vapour. Fault-controlled localization of magma constrains potential vent locations for future eruptions. PMID:27447932

  2. Iron Redox Systematics of Shergottites and Martian Magmas

    NASA Technical Reports Server (NTRS)

    Righter, Kevin; Danielson, L. R.; Martin, A. M.; Newville, M.; Choi, Y.

    2010-01-01

    Martian meteorites record a range of oxygen fugacities from near the IW buffer to above FMQ buffer [1]. In terrestrial magmas, Fe(3+)/ SigmaFe for this fO2 range are between 0 and 0.25 [2]. Such variation will affect the stability of oxides, pyroxenes, and how the melt equilibrates with volatile species. An understanding of the variation of Fe(3+)/SigmaFe for martian magmas is lacking, and previous work has been on FeO-poor and Al2O3-rich terrestrial basalts. We have initiated a study of the iron redox systematics of martian magmas to better understand FeO and Fe2O3 stability, the stability of magnetite, and the low Ca/high Ca pyroxene [3] ratios observed at the surface.

  3. The magma ocean as an impediment to lunar plate tectonics

    NASA Astrophysics Data System (ADS)

    Warren, P. H.

    1993-03-01

    The primary impediment to plate tectonics on the moon was probably the great thickness of its crust and particularly its high crust/lithosphere thickness ratio. This in turn can be attributed to the preponderance of low-density feldspar over all other Al-compatible phases in the lunar interior. During the magma ocean epoch, the moon's crust/lithosphere thickness ratio was at the maximum theoretical value, approximately 1, and it remained high for a long time afterwards. A few large regions of thin crust were produced by basin-scale cratering approximately contemporaneous with the demise of the magma ocean. However, these regions probably also tend to have uncommonly thin lithosphere, since they were directly heated and indirectly enriched in K, Th, and U by the same cratering process. Thus, plate tectonics on the moon in the form of systematic lithosphere subduction was impeded by the magma ocean.

  4. Magma storage in a strike-slip caldera

    NASA Astrophysics Data System (ADS)

    Saxby, J.; Gottsmann, J.; Cashman, K.; Gutiérrez, E.

    2016-07-01

    Silicic calderas form during explosive volcanic eruptions when magma withdrawal triggers collapse along bounding faults. The nature of specific interactions between magmatism and tectonism in caldera-forming systems is, however, unclear. Regional stress patterns may control the location and geometry of magma reservoirs, which in turn may control the spatial and temporal development of faults. Here we provide new insight into strike-slip volcano-tectonic relations by analysing Bouguer gravity data from Ilopango caldera, El Salvador, which has a long history of catastrophic explosive eruptions. The observed low gravity beneath the caldera is aligned along the principal horizontal stress orientations of the El Salvador Fault Zone. Data inversion shows that the causative low-density structure extends to ca. 6 km depth, which we interpret as a shallow plumbing system comprising a fractured hydrothermal reservoir overlying a magmatic reservoir with vol% exsolved vapour. Fault-controlled localization of magma constrains potential vent locations for future eruptions.

  5. Failed magmatic eruptions: Late-stage cessation of magma ascent

    USGS Publications Warehouse

    Moran, S.C.; Newhall, C.; Roman, D.C.

    2011-01-01

    When a volcano becomes restless, a primary question is whether the unrest will lead to an eruption. Here we recognize four possible outcomes of a magmatic intrusion: "deep intrusion", "shallow intrusion", "sluggish/viscous magmatic eruption", and "rapid, often explosive magmatic eruption". We define "failed eruptions" as instances in which magma reaches but does not pass the "shallow intrusion" stage, i. e., when magma gets close to, but does not reach, the surface. Competing factors act to promote or hinder the eventual eruption of a magma intrusion. Fresh intrusion from depth, high magma gas content, rapid ascent rates that leave little time for enroute degassing, opening of pathways, and sudden decompression near the surface all act to promote eruption, whereas decreased magma supply from depth, slow ascent, significant enroute degassing and associated increases in viscosity, and impingement on structural barriers all act to hinder eruption. All of these factors interact in complex ways with variable results, but often cause magma to stall at some depth before reaching the surface. Although certain precursory phenomena, such as rapidly escalating seismic swarms or rates of degassing or deformation, are good indicators that an eruption is likely, such phenomena have also been observed in association with intrusions that have ultimately failed to erupt. A perpetual difficulty with quantifying the probability of eruption is a lack of data, particularly on instances of failed eruptions. This difficulty is being addressed in part through the WOVOdat database. Papers in this volume will be an additional resource for scientists grappling with the issue of whether or not an episode of unrest will lead to a magmatic eruption.

  6. Cooling magma model for deep volcanic long-period earthquakes

    NASA Astrophysics Data System (ADS)

    Aso, Naofumi; Tsai, Victor C.

    2014-11-01

    Deep long-period events (DLP events) or deep low-frequency earthquakes (deep LFEs) are deep earthquakes that radiate low-frequency seismic waves. While tectonic deep LFEs on plate boundaries are thought to be slip events, there have only been a limited number of studies on the physical mechanism of volcanic DLP events around the Moho (crust-mantle boundary) beneath volcanoes. One reasonable mechanism capable of producing their initial fractures is the effect of thermal stresses. Since ascending magma diapirs tend to stagnate near the Moho, where the vertical gradient of density is high, we suggest that cooling magma may play an important role in volcanic DLP event occurrence. Assuming an initial thermal perturbation of 400°C within a tabular magma of half width 41 m or a cylindrical magma of 74 m radius, thermal strain rates within the intruded magma are higher than tectonic strain rates of ~ 10-14 s-1 and produce a total strain of 2 × 10-4. Shear brittle fractures generated by the thermal strains can produce a compensated linear vector dipole mechanism as observed and potentially also explain the harmonic seismic waveforms from an excited resonance. In our model, we predict correlation between the particular shape of the cluster and the orientation of focal mechanisms, which is partly supported by observations of Aso and Ide (2014). To assess the generality of our cooling magma model as a cause for volcanic DLP events, additional work on relocations and focal mechanisms is essential and would be important to understanding the physical processes causing volcanic DLP events.

  7. Dike injection and magma mixing in Kenya rift volcanoes

    NASA Astrophysics Data System (ADS)

    Anthony, E. Y.; Espejel, V.; Biggs, J.

    2009-12-01

    A nexus of volcanoes in the rift graben at approximately the latitude of Nairobi consist of central vent trachyte, phonolite, and peralkaline rhyolite and cinder cone and fissure-fed flows of basalt to benmoreite. The volcanoes are referred to as the Central Kenya Peralkaline Province (CKPP, Macdonald and Scaillet, 2006, Lithos 91, 59-73) and formed by a combination of processes including fractional crystallization, magma mixing, and volatile transport (Ren et al., 2006, Lithos 91, 109-124; Macdonald et al., 2008, JPet 49, 1515-1547). This presentation focuses on magma mixing for trachytes and phonolites for Suswa rocks, which are the southernmost part of the CKPP. We also explore the contribution of magma process studies to the interpretation of recent geodetic data, which indicate inflation/deflation of up to 21 cm for Kenyan volcanoes from 1997 to present (Biggs et al., 2009, Geology, in press). Incontrovertible evidence for magma mixing is found in field evidence, where a basaltic trachyandesite ash horizon is found interbedded with syncaldera trachyte (Skilling, 1993, J. Geol. Society London 150, 885-896), hand-specimen and thin-section petrography, and disequilibrium mineral chemistry. Precaldera lavas contain a homogeneous group of anorthoclase crystals with An content 6% or less. Syncaldera samples contain this same group and two other populations: polysynthetic twinned labradorite and andesine and anorthoclase with An content of 17%. Textures for all three groups indicate disequilibrium. Postcaldera flows contain the high and low An anorthoclase populations but lack the polysynthetic twinned labradorite and andesine. These observations suggest a model of injection of mafic magmas via diking into shallow trachtytic magma systems. Recent geodetic studies of dike injection and subsequent seismic/volcanic activity in both Ethiopia and Lengai point to the ongoing importance of these processes to rift evolution in East Africa.

  8. Gas transport through magma near the percolation threshold (Invited)

    NASA Astrophysics Data System (ADS)

    Llewellin, E. W.; Blower, J.; Leslie, D.

    2009-12-01

    Explosive silicic eruptions may simultaneously produce both tube pumice - containing highly-elongate vesicles - and pumice containing sub-spherical vesicles. This has been cited as evidence for strain localization within the volcanic conduit: in a relatively-undeformed axial ‘plug’ bubbles are spherical (regime 1) whilst near the conduit margin rapidly-shearing magma bears elongate bubbles (regime 2). Published numerical studies support this model and indicate that bubbly-magma rheology or viscous heating may be responsible for strain localization. The difference in bubble morphology in these two regimes has important consequences for magma permeability. We present the results of fluid dynamic simulations which quantify the anisotropy of permeability in regime 2 as a function of gas volume fraction and bubble aspect ratio. In this regime, we find that vertical permeability may be many times greater than radial permeability, and that permeability anisotropy is most pronounced near the percolation threshold. We further use a network model to quantify the development of permeability in regime 1. In the case where the predominantly vertical expansion of the magma is slow compared with bubble relaxation time, we find that permeability is, again, anisotropic, but that radial permeability dominates. This effect is also most pronounced near the percolation threshold, and percolation is expected to occur radially before vertical percolation occurs. Our findings imply that gas transport in regime 1 is predominantly radial, whilst vertical gas transport is favoured in regime 2. Consequently, near the percolation threshold, conditions are appropriate for effective degassing of the central magma plug as gas permeates radially to the conduit margin and then vertically upwards. Repeated cycles of percolation, radial gas loss and densification may degas the central magma plug without the development of large gas volume fractions.

  9. Lunar Magma Ocean Crystallization: Constraints from Fractional Crystallization Experiments

    NASA Technical Reports Server (NTRS)

    Rapp, J. F.; Draper, D. S.

    2015-01-01

    The currently accepted paradigm of lunar formation is that of accretion from the ejecta of a giant impact, followed by crystallization of a global scale magma ocean. This model accounts for the formation of the anorthosite highlands crust, which is globally distributed and old, and the formation of the younger mare basalts which are derived from a source region that has experienced plagioclase extraction. Several attempts at modelling the crystallization of such a lunar magma ocean (LMO) have been made, but our ever-increasing knowledge of the lunar samples and surface have raised as many questions as these models have answered. Geodynamic models of lunar accretion suggest that shortly following accretion the bulk of the lunar mass was hot, likely at least above the solidus]. Models of LMO crystallization that assume a deep magma ocean are therefore geodynamically favorable, but they have been difficult to reconcile with a thick plagioclase-rich crust. A refractory element enriched bulk composition, a shallow magma ocean, or a combination of the two have been suggested as a way to produce enough plagioclase to account for the assumed thickness of the crust. Recently however, geophysical data from the GRAIL mission have indicated that the lunar anorthositic crust is not as thick as was initially estimated, which allows for both a deeper magma ocean and a bulk composition more similar to the terrestrial upper mantle. We report on experimental simulations of the fractional crystallization of a deep (approximately 100km) LMO with a terrestrial upper mantle-like (LPUM) bulk composition. Our experimental results will help to define the composition of the lunar crust and mantle cumulates, and allow us to consider important questions such as source regions of the mare basalts and Mg-suite, the role of mantle overturn after magma ocean crystallization and the nature of KREEP

  10. Efficiency of differentiation in the Skaergaard magma chamber

    NASA Astrophysics Data System (ADS)

    Tegner, C.; Lesher, C. E.; Holness, M. B.; Jakobsen, J. K.; Salmonsen, L.; Humphreys, M.; Thy, P.

    2011-12-01

    Although it is largely agreed that crystallization occurs inwardly in crystal mushes along the margins of magma chambers, the efficiency and mechanisms of differentiation are not well constrained. The fractionation paradigm hinges on mass exchange between the crystal mush and the main magma reservoir resulting in coarse-grained, refractory (cumulate) rocks of primary crystals, and complementary enrichment of incompatible elements in the main reservoir of magma. Diffusion, convection, liquid immiscibility and compaction have been proposed as mechanisms driving this mass exchange. Here we examine the efficiency of differentiation in basaltic crystal mushes in different regions of the Skaergaard magma chamber. The contents of incompatible elements such as phosphorus and calculated residual porosities are high in the lowermost cumulate rocks of the floor (47-30%) and decrease upsection, persisting at low values in the uppermost two-thirds of the floor rock stratigraphy (~5% residual porosity). The residual porosity is intermediate at the walls (~15%) and highest and more variable at the roof (10-100%). This is best explained by compaction and expulsion of interstitial liquid from the accumulating crystal mush at the floor and the inefficiency of these processes elsewhere in the intrusion. In addition, the roof data imply upwards infiltration of interstitial liquid. Remarkably uniform residual porosity of ~15% for cumulates formed along the walls suggest that their preservation is related to the rheological properties of the mush, i.e. at ≤ 15% porosity the mush is rigid enough to adhere to the wall, while at higher porosity it is easily swept away. We conclude that the efficiency of compaction and differentiation can be extremely variable along the margins of magma chambers. This should be taken into account in models of magma chamber evolution.

  11. Molybdenite saturation in silicic magmas: Occurrence and petrological implications

    USGS Publications Warehouse

    Audetat, A.; Dolejs, D.; Lowenstern, J. B.

    2011-01-01

    We identified molybdenite (MoS2) as an accessory magmatic phase in 13 out of 27 felsic magma systems examined worldwide. The molybdenite occurs as small (<20 ??m) triangular or hexagonal platelets included in quartz phenocrysts. Laser-ablation inductively coupled plasma mass spectrometry analyses of melt inclusions in molybdenite-saturated samples reveal 1-13 ppm Mo in the melt and geochemical signatures that imply a strong link to continental rift basalt-rhyolite associations. In contrast, arc-associated rhyolites are rarely molybdenite-saturated, despite similar Mo concentrations. This systematic dependence on tectonic setting seems to reflect the higher oxidation state of arc magmas compared with within-plate magmas. A thermodynamic model devised to investigate the effects of T, f O2 and f S2 on molybdenite solubility reliably predicts measured Mo concentrations in molybdenite-saturated samples if the magmas are assumed to have been saturated also in pyrrhotite. Whereas pyrrhotite microphenocrysts have been observed in some of these samples, they have not been observed from other molybdenite-bearing magmas. Based on the strong influence of f S2 on molybdenite solubility we calculate that also these latter magmas must have been at (or very close to) pyrrhotite saturation. In this case the Mo concentration of molybdenite-saturated melts can be used to constrain both magmatic f O2 and f S2 if temperature is known independently (e.g. by zircon saturation thermometry). Our model thus permits evaluation of magmatic f S2, which is an important variable but is difficult to estimate otherwise, particularly in slowly cooled rocks. ?? The Author 2011. Published by Oxford University Press. All rights reserved.

  12. Exoplanet Magma Ocean Magnetic Fields may be Common

    NASA Astrophysics Data System (ADS)

    Bourzutschky, Alexander; Stevenson, David

    2015-11-01

    Kepler data suggest that many exoplanets have low densities for their mass, and therefore probably have hydrogen-rich atmospheres. For all but very thin atmospheres, these have a convective zone beneath the radiative outer region, and as a consequence have high temperatures at the assumed silicate surface, usually above the liquidus, implying a magma ocean. In many cases, the resulting high internal temperatures are sufficient to allow for dynamo action in the magma. There, the electrical conductivities are high enough to support such a dynamo but not so high that the thermal conductivity favors conduction over convection. High conductivity is bad for a dynamo so this lower thermal conductivity makes such magma ocean dynamos preferable to a putative iron core dynamo.In our simple models, the atmospheres of exoplanets will contain a convective zone beneath a radiative zone if sufficiently thick. We develop a simple model for the surface temperature of a rocky exoplanet with atmosphere-to-planet mass ratios 0.001% to 10%, planet masses 1-10 M⊕, and effective temperatures 150-1000 K. In most models with atmosphere mass ratios greater than 0.1% the rocky surface is above 1500 K, above the liquidus for silicate magma. Assuming a fully molten silicate magma ocean planet of Earthlike composition, the primary mode of heat transport is convection except at the high-temperature, high atmosphere mass ratio end. From that, even with conservative estimates of the electrical conductivity of the liquid silicate magma, the nominal magnetic Reynolds number at the surface seldom falls below 10. Thus the tentative conclusion is that rocky exoplanets with sufficiently thick atmospheric envelopes to melt the surface can generate magnetic fields irrespective of their putative cores. Estimates of the magnetic field were done following Christensen, yielding surface values in the range of 0.1 to 0.5 Gauss.

  13. Mineralogy and geochemistry of the older (> 40 ka) ignimbrites on the Campanian Plain, southern Italy

    NASA Astrophysics Data System (ADS)

    Belkin, H. E.; Rolandi, G.; Jackson, J. C.; Cannatelli, C.; Doherty, A. L.; Petrosino, P.; De Vivo, B.

    2016-09-01

    The Campanian Plain in southern Italy has been volcanically active for at least the last 300 ka. The Campanian Ignimbrite (CI) erupted at 39.3 ka, has a volume of ≥ 310 km3 and a great areal extent. However, significant, but scattered deposits of older ignimbrites underlie the CI and document a long history of volcanism. We examined the mineralogy and geochemistry of 11 older ignimbrite strata by optical petrography, electron microprobe, scanning electron microscope, X-ray diffraction, and various whole-rock geochemical techniques. We have analyzed strata at Durazzano (116.1 ka), Moschiano (184.7 ka), Seiano Valley (245.9 and 289.6 ka), and Taurano - Acqua Feconia (157.4, 183.8, 205.6, and 210.4 ka) that have been previously dated on unaltered sanidine. The older ignimbrites are highly altered with loss on ignition (LOI) that ranges from 17 to 8 wt%. Whole-rock compositions reflect variable element mobility during weathering; e.g., CaO is enriched and Na2O depleted relative to hydration. X-ray diffraction identified major chabazite, kaolinite, and illite alteration products in some samples. Rhabdophane-(Nd), usually intergrown with chabazite and Mn-carbonate, indicates that some LREE were also mobilized during weathering. The phenocryst mineralogy is typical for Campanian Plain (CP) magmas and consists of plagioclase (An88 Ab11 Or1 to An32 Ab63 Or5), potassium feldspar (Or40 Ab57 An3 to Or79 Ab18 An3), biotite (TiO2 = ~ 4-7 wt%, BaO = up to 2 wt%, F = up to 2 wt%), diopside (Ca47Mg47Fe6 to Ca48Mg29Fe23), and titaniferous magnetite. Relatively immobile trace elements Zr, Hf, Th, Ta, V, and Nb were used to investigate element abundance and ratio compared to the Campanian Ignimbrite and other CP magmas. Zr/Hf of the older ignimbrites is similar to that of the CI, but Ta is depleted relative to Th and V is enriched compared to CI. Th/Ta and Nb/V distributions for most of the older ignimbrites are similar to those in the Neapolitan Yellow Tuff with the exception of

  14. Mineral and whole-rock geochemistry of the Topuk Granitoid (Bursa, Western Anatolia, Turkey)

    NASA Astrophysics Data System (ADS)

    Orhan, Ayşe; Demirbilek, Mehmet; Mutlu, Halim

    2014-05-01

    by the interaction of post-collisional, calc-alkaline, metaluminous and I-type coeval felsic and mafic magmas at shallow depths under similar physicochemical conditions. Keywords: Turkey, Western Anatolia, Topuk Granitoid, geochemistry. Acknowledgement: This study is supported by the Scientific and Technical Research Council of Turkey (TÜBİTAK; YDABAG-111Y289).

  15. Trends in organic geochemistry for petroleum exploration

    SciTech Connect

    Tissot, B.P.

    1988-08-01

    Exploration efficiency has increased since 1970 due to improvements in geophysical treatments and the development of organic geochemistry. Further increase of the success ratio in wildcats is expected during the 1990s from integrating all earth sciences in basin modeling. Explorationists expect from geochemistry a clear answer to several questions essential for prospect evaluation: existence and location of source rock kitchens, amount and type of hydrocarbons generated, migration paths, and quantity and type of petroleum accumulated in traps. Based on the scientific knowledge developed during the last 20 years, such a clear answer can now be given to all questions related to generation. Kinetic models of oil generation will help us quantify the evaluation. Regarding migration, both approaches - observations and basin model - offer promising trends for individual trap evaluation. However, further work is needed before a quantitative figure of inplace reserves can be given. Examples of bacterial and thermal gas prospects in the Po basin (northern Italy), mainly from lower Tertiary and lower Mesozoic sources, respectively, are presented. Occurrences of liquid oil at great depth in the same basin are also presented, and the influences of kerogen type, burial history, geothermal gradient, and pressure regime are discussed. Immature heavy oils are present in the Adriatic basin and in Sicily. Their conditions of generation are interpreted with respect to specific type of high-sulfur crudes and burial history. More generally the important role of a late subsidence associated with the Europe-Africa collision is emphasized.

  16. Water content of primitive low-K tholeiitic basalt magma from Iwate Volcano, NE Japan arc: implications for differentiation mechanism of frontal-arc basalt magmas

    NASA Astrophysics Data System (ADS)

    Kuritani, Takeshi; Yoshida, Takeyoshi; Kimura, Jun-Ichi; Hirahara, Yuka; Takahashi, Toshiro

    2014-02-01

    The water content of low-K tholeiitic basalt magma from Iwate volcano, which is located on the volcanic front of the NE Japan arc, was estimated using multi-component thermodynamic models. The Iwate lavas are moderately porphyritic, consisting of ~8 vol.% olivine and ~20 vol.% plagioclase phenocrysts. The olivine and plagioclase phenocrysts show significant compositional variations, and the Mg# of olivine phenocrysts (Mg#78-85) correlates positively with the An content of coexisting plagioclase phenocrysts (An85-92). The olivine phenocrysts with Mg# > ~82 do not form crystal aggregates with plagioclase phenocrysts. It is inferred from these observations that the phenocrysts with variable compositions were primarily derived from mushy boundary layers along the walls of a magma chamber. By using thermodynamic calculations with the observed petrological features of the lavas, the water content of the Iwate magma was estimated to be 4-5 wt.%. The high water content of the magma supports the recent consensus that frontal-arc magmas are remarkably hydrous. Using the estimated water content of the Iwate magma, the water content and temperature of the source mantle were estimated. Given that the Iwate magma was derived from a primary magma solely by olivine fractionation, the water content and temperature were estimated to be ~0.7 wt.% and ~1,310 °C, respectively. Differentiation mechanisms of low-K frontal-arc basalt magmas were also examined by application of a thermodynamics-based mass balance model to the Iwate magma. It is suggested that magmatic differentiation proceeds primarily through fractionation of crystals from the main molten part of a magma chamber when it is located at <~200 MPa, whereas magma evolves through a convective melt exchange between the main magma and mushy boundary layers when the magma body is located at >~200 MPa.

  17. Water content of primitive low-K tholeiitic basalt magma from Iwate Volcano, NE Japan arc: implications for differentiation mechanism of frontal-arc basalt magmas

    NASA Astrophysics Data System (ADS)

    Kuritani, Takeshi; Yoshida, Takeyoshi; Kimura, Jun-Ichi; Hirahara, Yuka; Takahashi, Toshiro

    2013-03-01

    The water content of low-K tholeiitic basalt magma from Iwate volcano, which is located on the volcanic front of the NE Japan arc, was estimated using multi-component thermodynamic models. The Iwate lavas are moderately porphyritic, consisting of ~8 vol.% olivine and ~20 vol.% plagioclase phenocrysts. The olivine and plagioclase phenocrysts show significant compositional variations, and the Mg# of olivine phenocrysts (Mg#78-85) correlates positively with the An content of coexisting plagioclase phenocrysts (An85-92). The olivine phenocrysts with Mg# > ~82 do not form crystal aggregates with plagioclase phenocrysts. It is inferred from these observations that the phenocrysts with variable compositions were primarily derived from mushy boundary layers along the walls of a magma chamber. By using thermodynamic calculations with the observed petrological features of the lavas, the water content of the Iwate magma was estimated to be 4-5 wt.%. The high water content of the magma supports the recent consensus that frontal-arc magmas are remarkably hydrous. Using the estimated water content of the Iwate magma, the water content and temperature of the source mantle were estimated. Given that the Iwate magma was derived from a primary magma solely by olivine fractionation, the water content and temperature were estimated to be ~0.7 wt.% and ~1,310 °C, respectively. Differentiation mechanisms of low-K frontal-arc basalt magmas were also examined by application of a thermodynamics-based mass balance model to the Iwate magma. It is suggested that magmatic differentiation proceeds primarily through fractionation of crystals from the main molten part of a magma chamber when it is located at <~200 MPa, whereas magma evolves through a convective melt exchange between the main magma and mushy boundary layers when the magma body is located at >~200 MPa.

  18. Imaging magma plumbing beneath Askja volcano, Iceland

    NASA Astrophysics Data System (ADS)

    Greenfield, Tim; White, Robert S.

    2015-04-01

    Volcanoes during repose periods are not commonly monitored by dense instrumentation networks and so activity during periods of unrest is difficult to put in context. We have operated a dense seismic network of 3-component, broadband instruments around Askja, a large central volcano in the Northern Volcanic Zone, Iceland, since 2006. Askja last erupted in 1961, with a relatively small basaltic lava flow. Since 1975 the central caldera has been subsiding and there has been no indication of volcanic activity. Despite this, Askja has been one of the more seismically active volcanoes in Iceland. The majority of these events are due to an extensive geothermal area within the caldera and tectonically induced earthquakes to the northeast which are not related to the magma plumbing system. More intriguing are the less numerous deeper earthquakes at 12-24km depth, situated in three distinct areas within the volcanic system. These earthquakes often show a frequency content which is lower than the shallower activity, but they still show strong P and S wave arrivals indicative of brittle failure, despite their location being well below the brittle-ductile boundary, which, in Askja is ~7km bsl. These earthquakes indicate the presence of melt moving or degassing at depth while the volcano is not inflating, as only high strain rates or increased pore fluid pressures would cause brittle fracture in what is normally an aseismic region in the ductile zone. The lower frequency content must be the result of a slower source time function as earthquakes which are both high frequency and low frequency come from the same cluster, thereby discounting a highly attenuating lower crust. To image the plumbing system beneath Askja, local and regional earthquakes have been used as sources to solve for the velocity structure beneath the volcano. Travel-time tables were created using a finite difference technique and the residuals were used to solve simultaneously for both the earthquake locations

  19. Magma dynamics above the Karoo plume, South Africa

    NASA Astrophysics Data System (ADS)

    Ferre, Eric; Geissman, John; Stephanie, Maes; Aneesa, Gillum; Julian, Marsh

    2015-04-01

    Mantle plumes produce voluminous amounts of magma (106 km3) during a short period of time (106 years). The heat input of such plumes into sedimentary basins has been proposed as a significant factor in several global climatic crises. Indeed heat transfer through conductive and advective processes is likely to bake organic matter-rich sediments, which in turn may release greenhouse gases (CO2 and CH4). One of the yet poorly understood aspects of this model is the regional pattern of magma flow. The objective of this study is to constrain magma dynamics in the Karoo Large Igneous Province (LIP) intruded in a continental basin of South Africa. Magnetic fabrics provide an efficient and accurate mean to determine magma flow direction in gabbroic rocks. The anisotropy of magnetic susceptibility (AMS) is particularly suited for this type of study. A previous study had shown that the AMS fabric is a reliable proxy for magma flow as long as samples are collected from the upper chilled margin of a sill. The central part is more complex due to interference caused by thermal convection. Oriented core samples were collected from 30 different sills and yielded 1598 specimens for AMS measurements. The low-field magnetic susceptibility Km ranges widely from about 100 to 20,000 . 10-6 [SI], while the degree of anisotropy P' ranges from 1.01 to 1.10. Thermomagnetic experiments reveal that the main magnetic carrier is titanomagnetite with variable ulvöspinel content. This is confirmed by measurement of hysteresis properties that also indicate that titanomagnetite in general has a pseudo-single domain grain size. The results of this study clearly indicate that magma flow followed a main NW-SE direction in the studied area. The AMS directional data is consistent with the nearly horizontal attitude of the sill in 23 out of 30 cases, with subvertical K3 axes. In 5 out of 30 sills, K3 axes are subhorizontal, characterized by scattered directional data and are considered anomalous AMS

  20. On the cooling of a deep terrestrial magma ocean

    NASA Astrophysics Data System (ADS)

    Monteux, J.; Andrault, D.; Samuel, H.

    2016-08-01

    Several episodes of complete melting have probably occurred during the first stages of the Earth's evolution. We have developed a numerical model to monitor the thermal and melt fraction evolutions of a cooling and crystallizing magma ocean from an initially fully molten mantle. For this purpose, we numerically solve the heat equation in 1D spherical geometry, accounting for turbulent heat transfer, and integrating recent and strong experimental constraints from mineral physics. We have explored different initial magma ocean viscosities, compositions, thermal boundary layer thicknesses and initial core temperatures. We show that the cooling of a thick terrestrial magma ocean is a fast process, with the entire mantle becoming significantly more viscous within 20 kyr. Due to the slope difference between the adiabats and the melting curves, the solidification of the molten mantle occurs from the bottom up. In the meantime, a crust forms due to the high surface radiative heat flow, the last drop of fully molten silicate is restricted to the upper mantle. Among the studied parameters, the magma ocean lifetime is primarily governed by its viscosity. Depending on the thermal boundary layer thickness at the core-mantle boundary, the thermal coupling between the core and magma ocean can either insulate the core during the magma ocean solidification and favor a hot core or drain the heat out of the core simultaneously with the cooling of the magma ocean. Reasonable thickness for the thermal boundary layer, however, suggests rapid core cooling until the core-mantle boundary temperature results in a sluggish lowermost mantle. Once the crystallization of the lowermost mantle becomes significant, the efficiency of the core heat loss decreases. Since a hotter liquidus favors crystallization at hotter temperatures, a hotter deep mantle liquidus favors heat retention within the core. In the context of an initially fully molten mantle, it is difficult to envision the formation of a

  1. The Relationship Between Amphibole Cumulates and Adakite Magma

    NASA Astrophysics Data System (ADS)

    Rooney, T. O.

    2009-12-01

    Amphibole, while uncommon as a primary fractioning phase is increasingly recognized as a key constituent in the petrogenesis of arc magmas. Fractional crystallization of water-saturated arc magmas in the lower crust can yield substantial volumes amphibole cumulates that, depending on the pressure of crystallization, may also contain garnet. Fractionation of this higher pressure assemblage has been invoked as a possible mechanism in the production adakite magmas. The origin of adakites, defined by their heavy REE and Y depletion and Sr enrichments, have vigorously debated since their re-discovery in Panama two decades ago. In addition to widespread modern adakitic volcanism, the Panamanian portion of the Central American Arc preserves the magmatic record of arc development in close spatial association with younger magmatism. Late-Oligocene hypabyssal crystal-rich andesites from Cerro Patacon are preserved near the Panama Canal region. These contain nodules of amphibole cumulates, and may be used to examine the amphibole-fractionation model for adakite origin. The cumulate nodules are ~6 cm in diameter and are almost entirely composed of 5-10mm amphibole crystals (dominantly ferri-tschermakite), and are accompanied in the host andesites by amphibole phenocrysts, antecrysts and megacryts. Cerro Patacon andesites have REE concentrations that plot at the most depleted end of the array defined by similarly differentiated (58-60% SiO2) Central American Arc magmas, and exhibit a distinctive depletion in the middle REE. These geochemical and petrographic observations strongly support significant amphibole fractionation during formation of the Cerro Patacon andesite. Sr/Y which is used as a geochemical tool for discriminating adakites from other arc magams, is transitional in the Cerro Patcon andesites. However La/Yb is within the range for ‘normal’ arc magmas and shows that amphibole fractionation alone is insufficient to generate adakite magmas - some garnet

  2. Geochemistry and paleotectonic setting of Ediacaran metabasites from the Ossa-Morena Zone (SW Iberia)

    NASA Astrophysics Data System (ADS)

    Sánchez Lorda, M. E.; Sarrionandia, F.; Ábalos, B.; Carrracedo, M.; Eguíluz, L.; Gil Ibarguchi, J. I.

    2014-07-01

    New results on the geochemistry of Neoproterozoic (late Ediacaran) metabasites of the Ossa-Morena Zone (OMZ, Iberian Massif) are presented. The metabasite suite exhibits N- and E-MORB signatures, as well as volcanic arc signatures. The three amphibolite groups are discerned on the basis of major and trace element contents, and the Nd isotope relations help unravel the existence of a diverse magmatism during late Ediacaran times across the OMZ. N-MORB "Serie Negra" metabasites are distributed in the southern and, mostly, the central OMZ (Monesterio antiform). Calc-alkaline metabasites are exclusively constrained to the Coimbra-Córdoba sector of the northern OMZ. Finally, E-MORB-type metabasites are widespread across the entire OMZ. In present-day active geodynamic settings, such magma types are typical of younger island arcs, notably of forearc zones that are affected by extension soon after the initiation of subduction. The new geochemical data permit us to postulate a petrological zonation congruent with a N-dipping subduction zone located to the S of the current OMZ during the late Ediacaran. We argue that the metabasite host units represent (continental) shallow-crustal forearc segments of a convergent margin. The volcanic arc edifice would have developed during the latest Ediacaran to early Cambrian times and has been preserved, often without major orogenic reworking, in the central and northern OMZ.

  3. Numerical Simulations of the Incremental Intrusion of Granitic Magma into Continental Crust

    NASA Astrophysics Data System (ADS)

    Cao, W.; Kaus, B. J.; Paterson, S. R.

    2012-12-01

    We have employed the visco-elasto-plastic Finite-Element & Marker-in-cell code, MILAMIN_VEP, to carry out a 2D modeling study of the incremental intrusion of granitic magma into continental crust. Algorithms of multiple pulses of magma and pseudo-diking are implemented into the code. New magma of an initial circular shape is regularly replenished at "magma source" regions at sub-crustal depths. Pseudo-dikes of rectangular shapes are added at location where the maximum differential stress along the melt-solid interface is greater than an assigned tensile strength of the surrounding solid host rock. Preliminary results show that when diking and multiple pulses of magma are included, later pulses of magma rise higher and faster and even reach the Earth's surface in some cases by taking advantage of the pre-heated low-viscosity pathways created by earlier dikes and pulses of magma. Host rocks display bedding rotation, and downward flow at two sides of a growing magma chamber but show discordantly truncation when magma ascend through the weak channels made by dikes. The effect of the thermal structure of the crust was tested as well. In a cold crust, "diking" is critical in breaking the high-viscosity crust, guiding the direction of magma rising, and facilitating later magma pulses to form chambers. In a warmer crust, magma rises in the form of diapirs, after which dikes take over in transporting later pulses of magma to the surface. The simulations also suggest that a magma chamber incrementally constructed by multiple magma bathes is a very dynamic environment featuring intra-chamber convection and recycling previous batches of magma. In simulations without diking and multiple pulses, magma is unable to reach the shallow crust. Instead, it is stuck in the middle crust, as the viscosity of the upper crust is too large to permit rapid motion, and at the same time magma-induced stresses are insufficient to deform the upper crust in a plastic manner. Intra

  4. Magma supply rates inferred from cinder cone volumes

    NASA Astrophysics Data System (ADS)

    Bemis, K. G.; Borgia, A.; Neri, M.; Kervyn, M.

    2010-12-01

    Revisiting the question of how cinder cones grow suggests the possibility of inferring magma supply rates from cinder cones sizes. We start with a conceptual model of cinder cone growth: (1) Eruption volume flux increases rapidly and then decreases exponentially. (2) Cinder cones get steeper during the initiation of the eruption and then maintain a constant steepness. (3) The initial basal diameter varies with volume flux into the cone. Based on these constraints, we propose a general form for the relationship between cinder cone volume and magma supply rate: V = Q(exp(-t/b)/b - exp(-t/a)/a), where V is volume (in m3), Q is the maximum potential magma flux (in m3/s), t is time (in s), a is a damping factor (in s) controlling the decline in volume flux, and b is a factor controlling the initial increase in volume flux. Then we use the data available on the growth of cinder cones from four modern eruptions to show the relevance of our model and to constrain the supply curves. All four modern cones (Paricutin, Mexico which erupted 1943-1974; Tolbachik, Kamchatka which erupted in 1975-1976; Cono del Laghetto, Mount Etna, Italy which formed in 2001; and a small cone on the summit of Oldoinyo Lengai, Tanzania, which formed during the 2007 eruption) show the basic growth pattern: initial rapid growth followed by declining growth (Figure 1). The regression results yeild the following magma supply rates: The southern Tolbachik cones have the largest predicted magma supply at ~100 m3/s. Paricutin and Laghetto are around 9 m3/s. The Oldoinyo Lengai cone has a magma supply of ~0.5 m3/s. The northern Tolbachik cone has the lowest magma supply of ~0.1 m3/s. In contrast, the damping factor a is generally on the order of 107 (it varies from 8 x 106 at southern Tolbachik to 4 x 107 at northern Tolbachik). The parameter b controlling the initial increase is generally small (<1). The predicted magma supply does not seem to be very sensitive to either parameter. Thus we suggest that

  5. Liquidus tracking by vigorous convection in ascending magma

    NASA Astrophysics Data System (ADS)

    Winslow, N. W.; Marsh, B.

    2007-12-01

    Basaltic magmas commonly erupt at or near their liquidi and have never been observed to be superheated. In the light of the steep P-T slope of magma adiabats relative to liquidi, superheated magmas should be common. That they are not may reflect a fundamental feature of rapid convective heat transfer in ascending magmas, and that they seem to adhere to the liquidus may also reflect this process. Moreover, this may alleviate the well-known thermal entry length enigma pointed out by Delaney and Pollard that magma under laminar flow in dikes should solidify after a relatively short transit distance. (This is, in essence, because the flow velocity is normal to the thermal gradient and their vector product vanishes, leaving the sheet to progressively solidify by conduction regardless of flow rate.) Key insight on the meaning of the lack of superheat comes from thermal convection studies involving crystallizing fluids. In experiments intended to simulate thermal convection in magmas using analog crystallizing fluids (paraffin, isopropanol-water), a number of studies have found thermal convection to be vigorous only when the 'magma' is superheated (Marsh, 89'; Brandeis & Marsh, 89'; 90'; Hort et al., 99'). Convection ceases once the superheat is evicted and further cooling is by conduction. Because of the relatively low viscosity and significant length scales of basaltic magmas, the governing Rayleigh number (Ra) for thermal convection is large for almost any appreciable superheat. All the physical features associated with convection can be related to Ra. The rate of convective heat transfer relative to conduction is measured by the Nusselt number (Nu) and, for example, Nu is proportional to Ra to the 1/3. We report here on analytical and numerical results that model this cooling process during magma ascent. The thermal history is a function of two dimensionless numbers: Rao based on the temperature difference between the liquidus at the initial depth and the surface, and

  6. Water-saturated magmas in the Panama Canal region: a precursor to adakite-like magma generation?

    NASA Astrophysics Data System (ADS)

    Rooney, Tyrone O.; Franceschi, Pastora; Hall, Chris M.

    2011-03-01

    Amphibole, while uncommon as a phenocryst in arc lavas, is increasingly recognized as a key constituent in the petrogenesis of arc magmas. Fractional crystallization of water-saturated arc magmas in the lower crust can yield substantial volumes of amphibole cumulates that, depending on the pressure of crystallization, may also contain garnet. Fractionation of this higher pressure assemblage has been invoked as a possible mechanism in the production of magmas that contain an adakitic signature. This study examines newly dated Late-Oligocene (25.37 ± 0.13 Ma) hypabyssal amphibole-rich andesites from Cerro Patacon in the Panama Canal region. These andesites contain nodules of amphibole cumulates that are ~4-6 cm in diameter and are almost entirely composed of 5-10-mm amphibole crystals (dominantly ferri-tschermakite). Geochemical variations, optical and chemical zoning of the Cerro Patacon amphiboles are consistent with their evolution in a crystal mush environment that had at least one recharge event prior to entrainment in the host andesite. Amphiboles hosted within the cumulate nodules differ from those hosted in the Cerro Patacon andesite and contain consistently higher values of Ti. We suggest these nodules represent the early stages of fractionation from a water-saturated magma. Cerro Patacon andesites have REE concentrations that plot at the most depleted end of Central American Arc magmas and exhibit a distinctive depletion in the middle REE. These geochemical and petrographic observations strongly support significant amphibole fractionation during formation of the Cerro Patacon andesite, consistent with the petrographic evidence. Fractionation of water-saturated magmas is a mechanism by which adakitic compositions may be produced, and the Cerro Patacon andesites do exhibit adakite-like geochemical characteristics (e.g., elevated Sr/Y; 28-34). However, the relatively elevated concentrations of Y and HREE indicate garnet was not stable in the fractionating

  7. Magma energy research project: state-of-the-project report, October 1, 1978

    SciTech Connect

    Colp, J.L.; Traeger, R.K.

    1980-02-01

    The feasibility of extracting energy from magma bodies is investigated. The work done in FY 76, 77, and 78 in the following tasks are summarized; resource location and definition, source tapping, magma characterization and materials compatibility, and energy extraction. (MHR)

  8. Chemical Composition of Lunar Magma Ocean Constrained by High Pressure Experiments

    NASA Astrophysics Data System (ADS)

    Sakai, R.; Kushiro, I.; Nagahara, H.; Ozawa, K.; Tachibana, S.

    2010-03-01

    We report our attempts to constrain bulk chemical compositions of lunar magma ocean based on experimental constraints from physical properties of magma that can float anorthite to form the lunar anorthosite crust.

  9. Assimilation of High 18O/16O Crust by Shergottite-Nakhlite-Chassigny (SNC) Magmas on Mars

    NASA Astrophysics Data System (ADS)

    Day, J. M.; Taylor, L. A.; Valley, J. W.; Spicuzza, M. J.

    2005-12-01

    There is significant geochemical evidence for assimilation of crustal material into sub-aerial, mantle-derived, terrestrial basaltic magmas. Some of the most powerful constraints on crustal assimilation come from oxygen isotope studies, because supracrustal rocks often have distinct 18O/16O ratios resulting from interaction with Earth's hydrosphere. From a planetary perspective, studies of carbonate concretions from meteorite ALH84001 have yielded evidence for low-temperature crustal interaction at or near the surface of its putative parent body, Mars. This finding raises the possibility that crustal assimilation processes may be tracked using oxygen isotopes in combination with geochemical data of other reputed martian (SNC) meteorites. The whole-rock oxygen isotope ratios (Laser fluorination δ18O = +4.21 to +5.85‰ VSMOW) of SNC meteorites, correlate with aspects of their incompatible element chemistry. Some of the oxygen isotope variability may be explained by post-magmatic alteration on Mars or Earth; however, it appears, based on petrographic and geochemical observations, that a number of SNC meteorites, especially Shergottites, retain the original whole-rock oxygen isotope values of their magmas prior to crystallisation. Correlations between oxygen isotopes and incompatible element geochemistry are consistent with assimilation of a high-18O/16O, incompatible-element rich, oxidizing crustal component by hot, mantle-derived magmas (δ18O = ~~4.2‰). A crustal component has previously been recognized from Sr-Nd-Os isotope systematics and oxygen fugacity measurements of SNC meteorites. Oxygen isotope evidence from SNC meteorites suggests high-18O/16O crustal contaminants on Mars result from low temperature (< 300°C) interaction with martian hydrosphere. The extent of apparent crustal contamination tracked by oxygen isotopes in SNC meteorites implies that the majority of martian crust may have undergone such interactions. Evidence for assimilation of

  10. Low-3He/4He sublithospheric mantle source for the most magnesian magmas of the Karoo large igneous province

    NASA Astrophysics Data System (ADS)

    Heinonen, Jussi S.; Kurz, Mark D.

    2015-09-01

    The massive outpourings of Karoo and Ferrar continental flood basalts (CFBs) ∼180 Ma ago mark the initial Jurassic rifting stages of the Gondwana supercontinent. The origin and sources of these eruptions have been debated for decades, largely due to difficulties in defining their parental melt and mantle source characteristics. Recent findings of Fe- and Mg-rich dikes (depleted ferropicrite suite) from Vestfjella, western Dronning Maud Land, Antarctica, have shed light on the composition of the deep sub-Gondwanan mantle: these magmas have been connected to upper mantle sources presently sampled by the Southwest Indian Ocean mid-ocean ridge basalts (SWIR MORBs) or to high 3He/4He plume-entrained non-chondritic primitive mantle sources formed early in Earth's history. In an attempt to determine their He isotopic composition and relative contributions from magmatic, cosmogenic, and radiogenic He sources, we performed in-vacuo stepwise crushing and melting analyses of olivine mineral separates, some of which were abraded to remove the outer layer of the grains. The best estimate for the mantle isotopic composition is given by a sample with the highest amount of He released (>50%) during the first crushing step of an abraded coarse fraction. It has a 3He/4He of 7.03 ± 0.23 (2σ) times the atmospheric ratio (Ra), which is indistinguishable from those measured from SWIR MORBs (6.3-7.3 Ra; source 3He/4He ∼6.4-7.6 Ra at 180 Ma) and notably lower than in the most primitive lavas from the North Atlantic Igneous Province (up to 50 Ra), considered to represent the epitome magmas from non-chondritic primitive mantle sources. Previously published trace element and isotopic (Sr, Nd, and Pb) compositions do not suggest a direct genetic link to any modern hotspot of Indian or southern Atlantic Oceans. Although influence of a mantle plume cannot be ruled out, the high magma temperatures and SWIR MORB-like geochemistry of the suite are best explained by supercontinent insulation

  11. Timescales and mechanisms of plume-lithosphere interactions: 40Ar/ 39Ar geochronology and geochemistry of alkaline igneous rocks from the Paraná-Etendeka large igneous province

    NASA Astrophysics Data System (ADS)

    Gibson, S. A.; Thompson, R. N.; Day, J. A.

    2006-11-01

    We have determined high-precision 40Ar/ 39Ar ages for alkaline igneous rocks from the western margin of the Early-Cretaceous Paraná-Etendeka large igneous province (Paraguay). These show that small-fraction melt generation occurred beneath the region in two phases; at 145 Ma and 127.5 Ma, i.e. before and at the end of the 139-127.5 Ma Paraná-Etendeka flood-basalt eruptions. Previously published 40Ar/ 39Ar ages for alkaline igneous rocks on the proto-Atlantic coastal margins range from 134 to 128 Ma and indicate that small-fraction melt generation in the east of the province was either synchronous or slightly later than the main pulse of tholeiitic volcanism (between 134 and 132 Ma). Our new 40Ar/ 39Ar phlogopite ages confirm that: (i) the earliest melts associated with the initial impact of the Tristan plume were generated in the west of the Paraná-Etendeka large igneous province and (ii) igneous activity was long lived and immediately predates continental break-up. The Early-Cretaceous Paraguayan alkaline magmas are silica-undersaturated, enriched in incompatible-trace elements, have very-low initial ɛNd values and probably represent melts of phlogopite-bearing, carbonate-metasomatised peridotite in the subcontinental lithospheric mantle. Our simple one-dimensional, conductive-heating models suggest that the early-phase (145 Ma) alkaline magmas were emplaced on the margins of the Rio de La Plata craton at the time of sublithospheric impact of the proto-Tristan plume. The late phase (127.5 Ma) of Paraguayan alkaline magmatism is concentrated in an intra-cratonic rift zone and melt generation appears to have been triggered by lithospheric extension, perhaps facilitated by conductive heating and thermal weakening associated with the upwelling Tristan plume. The location and timing of both alkaline and tholeiitic melt generation in the Paraná-Etendeka province appear to have been significantly influenced by the non-uniform composition and thickness of the South

  12. Computational Studies in Molecular Geochemistry and Biogeochemistry

    SciTech Connect

    Felmy, Andrew R.; Bylaska, Eric J.; Dixon, David A.; Dupuis, Michel; Halley, James W.; Kawai, R.; Rosso, Kevin M.; Rustad, James R.; Smith, Paul E.; Straatsma, TP; Voth, Gregory A.; Weare, John H.; Yuen, David A.

    2006-04-18

    The ability to predict the transport and transformations of contaminants within the subsurface is critical for decisions on virtually every waste disposal option facing the Department of Energy (DOE), from remediation technologies such as in situ bioremediation to evaluations of the safety of nuclear waste repositories. With this fact in mind, the DOE has recently sponsored a series of workshops on the development of a Strategic Simulation Plan on applications of high perform-ance computing to national problems of significance to the DOE. One of the areas selected for application was in the area of subsurface transport and environmental chemistry. Within the SSP on subsurface transport and environmental chemistry several areas were identified where applications of high performance computing could potentially significantly advance our knowledge of contaminant fate and transport. Within each of these areas molecular level simulations were specifically identified as a key capability necessary for the development of a fundamental mechanistic understanding of complex biogeochemical processes. This effort consists of a series of specific molecular level simulations and program development in four key areas of geochemistry/biogeochemistry (i.e., aqueous hydrolysis, redox chemistry, mineral surface interactions, and microbial surface properties). By addressing these four differ-ent, but computationally related, areas it becomes possible to assemble a team of investigators with the necessary expertise in high performance computing, molecular simulation, and geochemistry/biogeochemistry to make significant progress in each area. The specific targeted geochemical/biogeochemical issues include: Microbial surface mediated processes: the effects of lipopolysacchardies present on gram-negative bacteria. Environmental redox chemistry: Dechlorination pathways of carbon tetrachloride and other polychlorinated compounds in the subsurface. Mineral surface interactions: Describing

  13. Insights into Igneous Geochemistry from Trace Element Partitioning

    NASA Technical Reports Server (NTRS)

    Jones, J. H.; Hanson, B. Z.

    2001-01-01

    Partitioning of trivalent elements into olivine are used to explore basic issues relevant to igneous geochemistry, such as Henry's law. Additional information is contained in the original extended abstract.

  14. POLLUTION PREVENTION OPPORTUNITY ASSESSMENT - GEOCHEMISTRY LABORATORY AT SANDIA NATIONAL LABORATORIES

    EPA Science Inventory

    These reports summarize pollution prevention opportunity assessments conducted jointly by EPA and DOE at the Geochemistry Laboratory and the Manufacturing and Fabrication Repair Laboratory at the Department of Energy's Sandia National Laboratories facility in Albuquerque, New Mex...

  15. Electrical conductivity of intermediate magmas from Uturuncu Volcano (Bolivia)

    NASA Astrophysics Data System (ADS)

    Laumonier, Mickael; Gaillard, Fabrice; Sifre, David

    2015-04-01

    Magmas erupted at Uturuncu volcano (South Bolivia) comes from the Altiplano-Puna Magma Body (APMB, Chile-Bolivia), a crustal massive body of 80 km long by 10 km thick located at ~ 35 km depth named. Recent magneto telluric surveys reveal a resistivity lower than 1 ohm.m due to the presence of melt which could result in the reactivation of the volcano. In order to better constrain the resistivity profiles and thus the conditions of magma storage of the APMB, we have performed in situ electrical measurements on natural dacites and andesites from Uturuncu with a 4-wire set up in a piston cylinder and internally heated pressure vessel. The range of temperature (500 to 1300°C), pressure (0.3 to 2 Gpa), and the various water contents covers the respective ranges occurring at natural conditions. The results show that the conductivity increases with the temperature and the water content but slightly decreases with the pressure. Then a model was built from these results so as to help in (i) interpreting the electrical signature of natural magmas, (ii) constraining their conditions (chemical composition, temperature, pressure, water content, melt fraction) from the source to the storage location and (iii) providing information on the interior structure of a volcano and its reservoir.

  16. On the cooling of a deep terrestrial magma ocean

    NASA Astrophysics Data System (ADS)

    Monteux, J.; Andrault, D.; Samuel, H.

    2015-12-01

    In its early evolution, the Earth mantle likely experienced several episodes of complete melting enhanced by giant impact heating, short-lived radionuclides heating and viscous dissipation during the metal/silicate separation. We have developed numerical models to monitor the thermo-chemical evolution of a cooling and crystallizing magma ocean from an initially fully molten mantle. For this purpose, we use a 1D approach accounting for turbulent convective heat transfer. Our numerical model benchmarked with analytical solutions solves the heat equation in spherical geometry. This model also integrates recent and strong experimental constraints from mineral physics such as adiabatic temperature profiles and liquidus/solidus up 140 GPa for different mantle compositions. Our preliminary results show that a deep magma ocean starts to crystallize rapidly after its formation. The cooling efficiency of the magma ocean is strongly dependent on the coupling with the core cooling. Hence, depending on the thermal boundary layer thickness at the CMB, the thermal coupling between the core and magma ocean can either insulate the core during the MO solidification and favor a hot core, generate the formation of a thin basal molten layer or empty the heat from the core. Then, once the melt fraction reaches a critical value, the cooling efficiency becomes limited.

  17. Crystallization of Magma. CEGS Programs Publication Number 14.

    ERIC Educational Resources Information Center

    Berry, R. W.

    Crystallization of Magma is one of a series of single-topic problem modules intended for use in undergraduate geology and earth science courses. Through problems and observations based on two sets of experiments, this module leads to an understanding of how an igneous rock can form from molten material. Environmental factors responsible for…

  18. Magma plumbing for the 2014-2015 Holuhraun eruption, Iceland

    NASA Astrophysics Data System (ADS)

    Geiger, Harri; Mattsson, Tobias; Deegan, Frances M.; Troll, Valentin R.; Burchardt, Steffi; Gudmundsson, Ólafur; Tryggvason, Ari; Krumbholz, Michael; Harris, Chris

    2016-08-01

    The 2014-2015 Holuhraun eruption on Iceland was located within the Askja fissure swarm but was accompanied by caldera subsidence in the Bárðarbunga central volcano 45 km to the southwest. Geophysical monitoring of the eruption identified a seismic swarm that migrated from Bárðarbunga to the Holuhraun eruption site over the course of two weeks. In order to better understand this lateral connection between Bárðarbunga and Holuhraun, we present mineral textures and compositions, mineral-melt-equilibrium calculations, whole rock and trace element data, and oxygen isotope ratios for selected Holuhraun samples. The Holuhraun lavas are compositionally similar to recorded historical eruptions from the Bárðarbunga volcanic system but are distinct from the historical eruption products of the nearby Askja system. Thermobarometry calculations indicate a polybaric magma plumbing system for the Holuhraun eruption, wherein clinopyroxene and plagioclase crystallized at average depths of ˜17 km and ˜5 km, respectively. Crystal resorption textures and oxygen isotope variations imply that this multilevel plumbing system facilitated magma mixing and assimilation of low-δ18O Icelandic crust prior to eruption. In conjunction with the existing geophysical evidence for lateral migration, our results support a model of initial vertical magma ascent within the Bárðarbunga plumbing system followed by lateral transport of aggregated magma batches within the upper crust to the Holuhraun eruption site.

  19. Geologic evidence for a magma chamber beneath Newberry Volcano, Oregon

    SciTech Connect

    Macleod, N.S.; Sherrod, D.R.

    1988-09-10

    At Newberry Volcano, central Oregon, more than 0.5 m.y. of magmatic activity, including caldera collapse and renewed caldera-filling volcanism, has created a structural and thermal chimney that channels magma ascent. Holocene rhyolitic eruptions (1) have been confined mainly within the caldera in an area 5 km in diameter, (2) have been very similar in chemical composition, phenocryst mineralogy, and eruptive style, and (3) have occurred as recently as 1300 years ago, with repose periods of 2000--3000 years between eruptions. Holocene basaltic andesite eruptions are widespread on the flanks but are excluded from the area of rhyolitic volcanism. Basaltic andesite in fissures at the edge of the rhyolite area has silicic inclusions and shows mixed basalt-rhyolite magma relations. These geologic relations and the high geothermal gradient that characterizes the lower part of a drill hole in the caldera (U.S. Geological Survey Newberry 2) indicate that a rhyolitic magma chamber has existed beneath the caldera throughout the Holocene. Its longevity probably is a result of intermittent underplating by basaltic magma.

  20. Magma supply rate at Kilauea volcano, 1952-1971

    USGS Publications Warehouse

    Swanson, D.A.

    1972-01-01

    The three longest Kilauea eruptions since 1952 produced lava at an overall constant rate of about 9 ?? 106 cubic meters per month (vesicle-free). This is considered to represent the rate of magma supply from a deep source, probably the mantle, because little or no summit deformation indicating high-level storage accompanied any of the three eruptions.

  1. Degassing of rhyolitic magma during ascent and emplacement

    SciTech Connect

    Westrich, H.R.; Stockman, H.W.; Eichelberger, J.

    1988-06-10

    The degassing history of a rhyolitic igneous system was documented from analyses of drill core samples through the extrusive and intrusive portions of Obsidian Dome and of surface samples of associated tephra. The initial volatile composition of the Inyo magma was estimated to be 4.0 wt % H/sub 2/O, 500 ppm F, 800 ppm Cl, and 80 ppm S. Retained volatile contents of glassy and crystalline samples reflect the effects of decompression and second boiling. Decompression is rapid and involves loss of water-rich fluid until a close approach to lithostatic equilibrium is achieved. Second boiling is a slower process and produces a chlorine-rich fluid, some of which can be trapped during development of extremely fine crystallization textures. Nearly complete dewatering during decompression of surface-extruded magma strongly undercools the system (..delta..Tapprox. =175 /sup 0/C), suppressing crystallization and yielding glassy rhyolitic lava. Partial degassing of shallowly intruded magma permits pervasive crystallization even at high cooling rates. The subvolcanic intrusive regime is the zone of maximum volatile release because second boiling is incomplete in extrusives, and volatile-bearing crystalline phases are stable in magma crystallized at greater depth. copyright Amierican Geophysical Union 1988

  2. Evaluating the Controls on Magma Ascent Rates Through Numerical Modelling

    NASA Astrophysics Data System (ADS)

    Thomas, M. E.; Neuberg, J. W.

    2015-12-01

    The estimation of the magma ascent rate is a key factor in predicting styles of volcanic activity and relies on the understanding of how strongly the ascent rate is controlled by different magmatic parameters. The ability to link potential changes in such parameters to monitoring data is an essential step to be able to use these data as a predictive tool. We present the results of a suite of conduit flow models that assess the influence of individual model parameters such as the magmatic water content, temperature or bulk magma composition on the magma flow in the conduit during an extrusive dome eruption. By systematically varying these parameters we assess their relative importance to changes in ascent rate. The results indicate that potential changes to conduit geometry and excess pressure in the magma chamber are amongst the dominant controlling variables that effect ascent rate, but the single most important parameter is the volatile content (assumed in this case as only water). Modelling this parameter across a range of reported values causes changes in the calculated ascent velocities of up to 800%, triggering fluctuations in ascent rates that span the potential threshold between effusive and explosive eruptions.

  3. On depressurization of volcanic magma reservoirs by passive degassing

    NASA Astrophysics Data System (ADS)

    Girona, Társilo; Costa, Fidel; Newhall, Chris; Taisne, Benoit

    2014-12-01

    Many active volcanoes around the world alternate episodes of unrest and mildly explosive eruptions with quiescent periods dominated by abundant but passive gas emissions. These are the so-called persistently degassing volcanoes, and well-known examples are Mayon (Philippines) and Etna (Italy). Here, we develop a new lumped-parameter model to investigate by how much the gas released during quiescence can decrease the pressure within persistently degassing volcanoes. Our model is driven by the gas fluxes measured with monitoring systems and takes into account the size of the conduit and reservoir, the viscoelastic response of the crust, the magma density change, the bubble exsolution and expansion at depth, and the hydraulic connectivity between reservoirs and deeper magma sources. A key new finding is that, for a vast majority of scenarios, passive degassing reduces the pressure of shallow magma reservoirs by several MPa in only a few months or years, that is, within the intereruptive timescales of persistently degassing volcanoes. Degassing-induced depressurization could be responsible for the subsidence observed at some volcanoes during quiescence (e.g., at Satsuma-Iwojima and Asama, in Japan; Masaya, in Nicaragua; and Llaima, in Chile), and could play a crucial role in the onset and development of the physical processes which may in turn culminate in new unrest episodes and eruptions. For example, degassing-induced depressurization could promote magma replenishment, induce massive and sudden gas exsolution at depth, and trigger the collapse of the crater floor and reservoir roof.

  4. Petrological constrains of magma feeding system of Bezymyanny volcano (Kamchatka)

    NASA Astrophysics Data System (ADS)

    Plechov, P.; Shcherbakov, V. D.; Izbekov, P. E.

    2010-12-01

    Bezymyanny volcano is located in Central Kamchatka Depression and is in continuous eruption since 1956. Last decade is characterized by frequent (2 times per year) significant explosive events accompanied by extrusive dome growth. Composition of erupted lavas was changed gradually from hornblende-rich andesites (in wt%: SiO2 60-61, MgO 2.5-2.7, K2O 1.3) to two-pyroxene andesites (in wt%: SiO2 56-57, MgO 3.8-4.1, K2O 1.1) during last 54 years. We estimated PT-conditions of Bezymyanny magma chamber for 1956 from phenocrysts assemblage as 890±20°C and 600±200 MPa [1], whereas for 2000-2007 Bezymyanny magma chamber temperature and pressure were estimated as ~940°C and 77 - 87 MPa, respectively [2]. We suggest that temperature increased and lava compositions changed due to often influx of new magma portions since 1956. Changes in pressure of magma chamber can be explained by initiation of a new shallow magmatic chamber, which could have been formed after 1956. Harzburgite xenoliths in lavas first occurred in 2007-2009 eruption products and were described by authors. Primary assemblage consists of olivine (Fo87.2-91.0), orthopyroxene(En89.7-91.6Fs8.4-9.4Wo0-0.9) and Cr-spinel (Cr#=0.46-0.58). Equilibrium temperature for the assemblage is estimated as 950±40°C, ΔlogQFM =+2.1 and degree of mantle melting is 20-30%. We suggest that xenoliths represent fragments of lithosphere mantle, which were trapped by primitive magmas of Bezymyanny volcano during ascent. Occurrence of these xenoliths argued for the rapid penetration of xenolith-bearing magmas from mantle level to the shallow magma chamber during the last few years. [1] Plechov P. et al.(2008). Petrology:16:1:19-35. [2] Shcherbakov et al. (2010)CMP,accepted.

  5. Extensive, water-rich magma reservoir beneath southern Montserrat

    NASA Astrophysics Data System (ADS)

    Edmonds, M.; Kohn, S. C.; Hauri, E. H.; Humphreys, M. C. S.; Cassidy, M.

    2016-05-01

    South Soufrière Hills and Soufrière Hills volcanoes are 2 km apart at the southern end of the island of Montserrat, West Indies. Their magmas are distinct geochemically, despite these volcanoes having been active contemporaneously at 131-129 ka. We use the water content of pyroxenes and melt inclusion data to reconstruct the bulk water contents of magmas and their depth of storage prior to eruption. Pyroxenes contain up to 281 ppm H2O, with significant variability between crystals and from core to rim in individual crystals. The Al content of the enstatites from Soufrière Hills Volcano (SHV) is used to constrain melt-pyroxene partitioning for H2O. The SHV enstatite cores record melt water contents of 6-9 wt%. Pyroxene and melt inclusion water concentration pairs from South Soufriere Hills basalts independently constrain pyroxene-melt partitioning of water and produces a comparable range in melt water concentrations. Melt inclusions recorded in plagioclase and in pyroxene contain up to 6.3 wt% H2O. When combined with realistic melt CO2 contents, the depth of magma storage for both volcanoes ranges from 5 to 16 km. The data are consistent with a vertically protracted crystal mush in the upper crust beneath the southern part of Montserrat which contains heterogeneous bodies of eruptible magma. The high water contents of the magmas suggest that they contain a high proportion of exsolved fluids, which has implications for the rheology of the mush and timescales for mush reorganisation prior to eruption. A depletion in water in the outer 50-100 μm of a subset of pyroxenes from pumices from a Vulcanian explosion at Soufrière Hills in 2003 is consistent with diffusive loss of hydrogen during magma ascent over 5-13 h. These timescales are similar to the mean time periods between explosions in 1997 and in 2003, raising the possibility that the driving force for this repetitive explosive behaviour lies not in the shallow system, but in the deeper parts of a vertically

  6. Magma Plumbing and Emplacement Mechanisms within Sedimentary Basins

    NASA Astrophysics Data System (ADS)

    Schofield, Nick; Magee, Craig; Holford, Simon; Jackson, Christopher

    2013-04-01

    In recent years our understanding of sub-volcanic magmatic plumbing systems has been revolutionised by the study of hydrocarbon industry 3D seismic reflection datasets from offshore sedimentary basins. In particular, 3D seismic reflection data has provided important insights into sheet intrusion geometry and emplacement mechanisms as well as linkages and magma flow between multiple intrusions within sill-complexes. However, even high-quality 3D seismic reflection datasets have a limit to what they can resolve; thus, to allow a better understanding of detailed emplacement mechanisms and to test the validity of subsurface-based interpretations, it is critical to bridge the resolution gap that exists between seismic and outcrop datasets. Magmatic sheet (sill) intrusions contribute significantly to the upper crustal magma transport network. The emplacement mechanism of the magmatic sheets controls the final geometry of the intrusions and the characteristics of host rock deformation. Previous observations have highlighted the preponderance of brittle structures (e.g. intrusive steps and broken brides) associated with shallow-level sheet intrusions. However, recent studies have suggested that non-brittle host rock behaviour also occurs, particularly related to the formation of magma fingers during shallow-level sill intrusion. Importantly, these structures can provide insights into emplacement style and magma flow directions. Here, we examine both brittle and non-brittle intrusion mechanisms and structures using both field- and 3D seismic-based observations from a series of widespread and variable magmatic systems. Non-brittle emplacement (i.e. magma finger and lobe development) appears to be primarily associated with viscous flow of the host rock during intrusion and is therefore intimately linked to the contemporaneous host rock rheology as well as magma dynamics. Purely brittle and non-brittle emplacement processes are found to be end members with many intrusions

  7. Magma-water interactions in subaqueous and emergent basaltic

    NASA Astrophysics Data System (ADS)

    Kokelaar, Peter

    1986-10-01

    In the subaqueous growth and emergence of a basaltic volcano clasts are formed by one or a combination of (1) explosive release of magmatic volatiles; (2) explosive expansion and collapse of steam formed at magma-water contact surfaces; (3) explosive expansion of steam following enclosure of water in magma, or entrapment of water close to magma; and (4) cooling-contraction. These processes, named respectively magmatic explosivity, contact-surface steam explosivity, bulk interaction steam explosivity, and cooling-contraction granulation, can be enhanced by mutual interaction and feedback. The first three (explosive) processes are limited at certain water depths (hydrostatic pressures) and become increasingly vigorous at shallower levels. The depth of onset of magmatic explosivity depends largely on juvenile volatile content; it is up to 200 m for tholeiitic magmas and up to 1 km for alkalic magmas. At the depth where formation of clastic deposits becomes predominant over effusion of lavas, magmatic explosivity is subordinate to steam explosivity as a clast-forming process. The upward transition to accumulation of dominantly clastic deposits is not simply related to the onset of substantial exsolution of magmatic volatiles and can occur without it. Contact-surface explosivity commonly requires initiation by a vigorous impact between magma and water and, although no certain depth limit is known, likelihood of such explosivity decreases rapidly with depth. Clast generation by bulk interaction explosivity appears to be restricted to depths much shallower than that of the critical pressure of water, which in sea water is at about 3 km. Cooling-contraction granulation can occur in any depth of water, but at shallow levels may be replaced by contact-surface explosivity. During continuous eruption under water, tephra can be ejected and deposited within a cupola of steam such that rapid quenching does not occur. Emergent volcanoes are characterized by distinctive steam

  8. The crystal's view of upper-crustal magma reservoirs

    NASA Astrophysics Data System (ADS)

    Cooper, K. M.; Kent, A. J.; Huber, C.; Stelten, M. E.; Rubin, A. E.; Schrecengost, K.

    2015-12-01

    Upper-crustal magma reservoirs are important sites of magma mixing, crustal refining, and magma storage. Crystals residing in these reservoirs have been shown to represent valuable archives of the chemical and physical evolution of reservoirs, and the time scales of this evolution. This presentation addresses the question of "What do crystals "see" and record about processes within the upper crust? And how is that view similar or different between plutonic and volcanic records?" Three general observations emerge from study of the ages of crystals, combined with crystal-scale geochemical data: 1) Patterns of isotopic and trace-element data over time in zircon crystals from a given magmatic system (e.g., Yellowstone, WY, and Taupo Volcanic Zone, New Zealand) can show systematic changes in the degree of heterogeneity, consistent with extraction of melts from a long-lived (up to 100s of kyr), heterogeneous crystal mush and in some cases continued crystallization and homogenization of the magma during a short period (< a few kyr) preceding eruption. 2) Thermal histories of magma storage derived from crystal records also show that the vast majority of time recorded by major phases was spent in storage as a crystal mush, perhaps at near-solidus conditions. 3) Comparison of ages of accessory phases in both plutonic blocks and host magmas that brought them to the surface do not show a consistent relationship between the two. In some cases, zircons from plutonic blocks have age spectra much older than zircon in the host magma. In other cases, host and plutonic block zircons have similar age spectra and chemical characteristics, suggesting a closer genetic connection between the two. These observations suggest that crystals in plutonic bodies, if examined at similar spatial and temporal scales to those in volcanic rocks, would show records that are highly heterogeneous in chemistry and age on the scale of a pluton or a lobe of a pluton, but that local regions of limited

  9. Ascent and Eruption of Magma: A Planetary Perspective

    NASA Astrophysics Data System (ADS)

    Head, J. W.

    2013-12-01

    Analysis of the generation, ascent, and eruption of magma on the Earth and planets provides substantial information about the geological history and thermal evolution of each body. A synthesis of the array of extrusive features and landforms seen on the terrestrial planets provides insight into eruption styles, lithospheric stress states, and mantle convection. Surface elemental compositions of the terrestrial planets are consistent with a range of mantle compositions, but all are likely to produce mafic to ultramafic melts. The main controls on the types of surface volcanic features and accumulations are differences in 1) magma composition/volatile content, 2) tectonic regimes, 3) crustal densities, 4) crust and lithosphere thicknesses, and 5) mantle convective style. Preferred locations for magma reservoirs are either at depth within a planetary interior or relatively shallow within a volcanic edifice. Deeper reservoirs can form near the rheological change at the base of the lithosphere, at upwellings due to pressure-release melting, or at vertical discontinuities in density such as at the base of the crust. Evidence for reservoirs in edifices is seen in calderas. Evidence for deeper magma bodies is seen in giant dike swarms. The position of ascending mantle flow is marked by broad rises formed from thermal uplift, enhanced crustal construction, and individual edifices built by surface eruptions. On Venus, volcanic complexes/rises are accompanied by large annular deformational features (coronae) produced by a combination of uplift and accommodation of intrusive and extrusive loads. Shallow magma reservoirs are commonly formed within volcanic edifices on Earth, Mars, and Venus. Building a volcanic edifice and reservoir requires multiple pulses of magma to rise frequently within a spatially restricted region over an extended period of time. On the Moon, in contrast, low eruption frequencies and great flow lengths ensure that typical large edifices will not form

  10. Growth of continental crust: Clues from Nd isotopes and Nb-Th relationships in mantle-derived magmas

    NASA Technical Reports Server (NTRS)

    Arndt, N. T.; Chauvel, C.; Jochum, K.-P.; Gruau, G.; Hofmann, A. W.

    1988-01-01

    Isotope and trace element geochemistry of Precambrian mantle derived rocks and implications for the formation of the continental crust is discussed. Epsilon Nd values of Archean komatiites are variable, but range up to at least +5, suggesting that the Archean mantle was heterogeneous and, in part, very depleted as far back as 3.4 to 3.5 Ga. This may be taken as evidence for separation of continental crust very early in Earth history. If these komatiite sources were allowed to evolve in a closed system, they would produce modern day reservoirs with much higher epsilon Nd values than is observed. This implies recycling of some sort of enriched material, perhaps subducted sediments, although other possibilities exist. Archean volcanics show lower Nb/Th than modern volcanics, suggesting a more primitive mantle source than that observed nowadays. However, Cretaceous komatiites from Gorgona island have similar Nb/Th to Archean volcanics, indicating either the Archean mantle source was indeed more primitive, or Archean magmas were derived from a deep ocean island source like that proposed for Gorgona.

  11. Geochemistry of carbonatites of the Tomtor massif

    USGS Publications Warehouse

    Kravchenko, S.M.; Czamanske, G.; Fedorenko, V.A.

    2003-01-01

    Carbonatites compose sheet bodies in a 300-m sequence of volcanic lamproites, as well as separate large bodies at depths of >250-300 m. An analysis of new high-precision data on concentrations of major, rare, and rare earth elements in carbonatites shows that these rocks were formed during crystallization differentiation of a carbonatite magma, which resulted in enrichment of the later melt fractions in rare elements and was followed by autometasomatic and allometasomatic hydrothermal processes. Some independent data indicate that the main factor of ore accumulation in the weathered rock zone (also known as the "lower ore horizon" comprising metasomatized volcanics with interbedded carbonatites) was hydrothermal addition of Nb and REEs. The giant size of the Tomtor carbonatite-nepheline syenite massif caused advanced magma differentiation, extensive postmagmatic metasomatism and recrystallization of host rocks, and strong enrichment of carbonatites in incompatible rare and rare earth elements (except for Ta, Zr, Ti, K, and Rb) compared to the rocks of many other carbonatite massifs. We suggest that a wide range of iron contents in carbonatites-2 can be related to extensive magnetite fractionation at the magmatic stage in different parts of the huge massif. Copyright ?? 2003 by MAIK "Nauka/Interperiodica" (Russia).

  12. Progress integrating ID-TIMS U-Pb geochronology with accessory mineral geochemistry: towards better accuracy and higher precision time

    NASA Astrophysics Data System (ADS)

    Schoene, B.; Samperton, K. M.; Crowley, J. L.; Cottle, J. M.

    2012-12-01

    It is increasingly common that hand samples of plutonic and volcanic rocks contain zircon with dates that span between zero and >100 ka. This recognition comes from the increased application of U-series geochronology on young volcanic rocks and the increased precision to better than 0.1% on single zircons by the U-Pb ID-TIMS method. It has thus become more difficult to interpret such complicated datasets in terms of ashbed eruption or magma emplacement, which are critical constraints for geochronologic applications ranging from biotic evolution and the stratigraphic record to magmatic and metamorphic processes in orogenic belts. It is important, therefore, to develop methods that aid in interpreting which minerals, if any, date the targeted process. One promising tactic is to better integrate accessory mineral geochemistry with high-precision ID-TIMS U-Pb geochronology. These dual constraints can 1) identify cogenetic populations of minerals, and 2) record magmatic or metamorphic fluid evolution through time. Goal (1) has been widely sought with in situ geochronology and geochemical analysis but is limited by low-precision dates. Recent work has attempted to bridge this gap by retrieving the typically discarded elution from ion exchange chemistry that precedes ID-TIMS U-Pb geochronology and analyzing it by ICP-MS (U-Pb TIMS-TEA). The result integrates geochemistry and high-precision geochronology from the exact same volume of material. The limitation of this method is the relatively coarse spatial resolution compared to in situ techniques, and thus averages potentially complicated trace element profiles through single minerals or mineral fragments. In continued work, we test the effect of this on zircon by beginning with CL imaging to reveal internal zonation and growth histories. This is followed by in situ LA-ICPMS trace element transects of imaged grains to reveal internal geochemical zonation. The same grains are then removed from grain-mount, fragmented, and

  13. The role of magma mixing in Hawaiian fountaining eruptions

    NASA Astrophysics Data System (ADS)

    Edmonds, M.; Sides, I.; Maclennan, J.; Houghton, B. F.; Swanson, D. A.

    2013-12-01

    We present a detailed study of the major, trace and volatile element composition of olivine-hosted melt inclusions from the 1959 Kilauea Iki eruption at Kilauea Volcano, Hawai'i. The results show that mixing between buoyant, hot, primitive melts from depth, stored magmas and erupted lava that drained back down into the conduit controlled the dynamics of the eruption, with the degassed drainback lava having a critical role as a coolant. Temporal variations in melt H2O concentrations are explained well by a model of mixing between stored and incoming magmas and drainback lavas through the eruption, rendering the melt undersaturated with respect to H2O, consistent with previous studies (Wallace, P.J., Anderson, A.T., 1998. Effects of eruption and lava drainback on the H2O contents of basaltic magmas at Kilauea Volcano. Bull Volcanol 59, 327-344). Melt inclusion CO2 concentrations, however, reflect the sequestration of CO2 into a shrinkage bubble, and correlate with the degree of post-entrapment crystallization (PEC) that took place on the inclusion walls. The extent of PEC is controlled directly by the mixing process. Hot, buoyant, geochemically heterogeneous melts, possibly supersaturated with respect to CO2 and carrying olivines, mixed turbulently with drained-back lava. This mixing prompted cooling, rapid crystallization and vesiculation. Melt inclusions with the lowest CO2 concentrations experienced the most pre-eruptive cooling. The mean CO2 concentrations in the melt inclusions correlate negatively with maximum fountain heights for each episode, suggesting that the highest magma exit velocities occur when the interaction between incoming and stored melts prompts the highest degree of cooling, crystallization and vesiculation. We propose that the excess overpressure generated by the exsolution of volatiles during magma mixing is sufficient to trigger and drive fountains a few hundred meters high.

  14. Bubble plumes generated during recharge of basaltic magma reservoirs

    NASA Astrophysics Data System (ADS)

    Phillips, Jeremy C.; Woods, Andrew W.

    2001-03-01

    CO 2 is relatively insoluble in basaltic magma at low crustal pressures. It therefore exists as a gas phase in the form of bubbles in shallow crustal reservoirs. Over time these bubbles may separate gravitationally from the magma in the chamber. As a result, any new magma which recharges the chamber from deeper in the crust may be more bubble-rich and hence of lower density than the magma in the chamber. Using scaling arguments, we show that for typical recharge fluxes, such a source of low-viscosity, bubble-rich basalt may generate a turbulent bubble plume within the chamber. We also show that the bubbles are typically sufficiently small to have a low Reynolds number and to remain in the flow. We then present a series of analogue laboratory experiments which identify that the motion of such a turbulent bubble-driven line plume is well described by the classical theory of buoyant plumes. Using the classical plume theory we then examine the effect of the return flow associated with such bubble plumes on the mixing and redistribution of bubbles within the chamber. Using this model, we show that a relatively deep bubbly layer of magma may form below a thin foam layer at the roof. If, as an eruption proceeds, there is a continuing influx at the base of the chamber, then our model suggests that the bubble content of the bubbly layer may gradually increase. This may lead to a transition from lava flow activity to more explosive fire-fountaining activity. The foam layer at the top of the chamber may provide a flux for the continual outgassing from the flanks of the volcano [Ryan, Am. Geophys. Union Geophys. Monogr. 91 (1990)] and if it deepens sufficiently it may contribute to the eruptive activity [Vergniolle and Jaupart, J. Geophys. Res. 95 (1990) 2793-3001].

  15. Non-Newtonian effects during injection in partially crystallised magmas

    NASA Astrophysics Data System (ADS)

    Hallot, Erwan; Davy, Philippe; de Bremond d'Ars, Jean; Auvray, Bernard; Martin, Hervé; Van Damme, Henri

    1996-04-01

    Injection of Newtonian crystal-free magmas into a partially crystallised host which may exhibit non-Newtonian properties produces magmatic structures such as pipes, syn-plutonic dikes or dendritic structures. Field relationships between the structure and the host rock commonly indicate what the rheological contrasts during the injection were. The manner in which a magma deforms in response to injection is mainly linked to crystal content and strain rate (i.e., injection rate). Three kinds of behaviour can be distinguished: (1) Newtonian at low crystal contents; (2) Non-Newtonian at intermediate (40-60%) crystal contents, or at high crystal contents if the strain rate is small; and (3) brittle failure at high crystal content or strain rates. Petrologic observations indicate that injection can take place when the host magma still behaves as a fluid. To investigate the physics of the injection process we review the results of injection experiments in non-Newtonian fluids. These experiments were performed to study viscous fingering in 2-D Hele Shaw cells. They provide the first step to establishing the main non-Newtonian effects during the formation of interfacial instabilities arising when a Newtonian fluid is injected into a more viscous fluid or paste. The qualitative comparison of the morphological features of the interfaces between the fluids in the experiments with those in nature suggests that, in magmas, irregularities of the interfaces (dikes and dendrites) result from non-Newtonian properties of the host. We conclude that fluid-like deformation, rather than brittle behaviour of the host, during injection is likely to produce the general features observed on the field. Cooling effects might be responsible for the widespread phenomenon of fragmentation. We emphasise that the main effect of non-Newtonian properties in partially crystallised magmas is to generate strongly heterogeneous media producing discontinuities which could explain the main morphological

  16. Environmental geochemistry at the global scale

    USGS Publications Warehouse

    Plant, J.; Smith, D.; Smith, B.; Williams, L.

    2001-01-01

    Land degradation and pollution caused by population pressure and economic development pose a threat to the sustainability of the earth's surface, especially in tropical regions where a long history of chemical weathering has made the surface environment particularly fragile. Systematic baseline geochemical data provide a means of monitoring the state of the environment and identifying problem areas. Regional surveys have already been carried out in some countries, and with increased national and international funding they can be extended to cover the rest of the land surface of the globe. Preparations have been made, under the auspices of the International Union of Geological Surveys (IUGS) and the International Association of Geochemistry and Cosmochemistry (IAGC) for the establishment of just such an integrated global database. ?? 2001 NERC. Published by Elsevier Science Ltd.

  17. Geochemistry and health in the United Kingdom.

    PubMed

    Thornton, I; Webb, J S

    1979-12-11

    Before the 1960s, comparisons between the distribution of trace elements in the environment and health in the United Kingdom were primarily confined to ad hoc studies in areas associated with particular agricultural disorders or with unusual human mortality or morbidity records. More recently, increasing interest in the importance of trace elements in crop and animal production and in the hazards of environmental pollution have created a need for more systematic geochemical data. Geochemical reconnaissance maps for England, Wales, Northern Ireland and parts of Scotland have demonstrated the extent of many known clinical trace element problems in agriculture and have also been valuable in delineating areas within which subclinical disorders may occur. Their application to studies on the composition of soils, food crops and surface waters in relation to public health has proved encouraging. Current knowledge and present investigations into environmental geochemistry and human health in the U.K. are reviewed, together with future research requirements. PMID:43529

  18. Investigating urban geochemistry using Geographical Information Systems.

    PubMed

    Thums, C; Farago, M

    2001-01-01

    Geographical Information System (GIS) is an interactive digital extension of the two-dimensional paper map. Customised maps are created by the selection and aggregation of data from independent sources to assist studies in urban geochemistry. The metropolitan area of Wolverhampton, in the West Midlands, UK is used to illustrate the types of output that can be generated. These include: geographic and geological feature; geochemical data and land use. Multi-layered maps can be used to investigate spatial relationships, for example, between elevated concentrations of metals in soils and industrial land use. Such maps can also be used to assist the assessment of potential exposure of groundwater, ecosystems and humans using maps incorporating guideline values for metals in soils. PMID:11732156

  19. Petrology, Geochemistry and Genesis of Ureilites

    NASA Technical Reports Server (NTRS)

    Mittlefehldt, D. W.; Hudon, Pierre; Galindo, Charles, Jr.

    2005-01-01

    Ureilites are enigmatic achondrites that have some characteristics resulting from high temperature igneous processing, yet retain other characteristics inherited from the solar nebula. They are basalt-depleted ultramafic rocks containing 7-66 mg/g elemental C. They are rich in noble gases and display a correlation between mg# and Delta (17)O. This mishmash of properties has engendered various models for ureilite genesis, from those in which nebular processes dominate to those in which parent body igneous processes dominate. Characterization of new ureilites, especially of new subtypes, is an important part of attempts to unravel the history of the ureilite parent body or bodies. Here we report on the petrology and geochemistry of a suite of ureilites, mostly from Antarctica, and use these data to discuss ureilite petrogenesis. Additional information is included in the original extended abstract.

  20. Microbial Sulfur Geochemistry in Mine Systems (Invited)

    NASA Astrophysics Data System (ADS)

    Warren, L. A.; Norlund, K. L.; Hitchcock, A.

    2010-12-01

    Acid mine drainage (AMD), metal laden, acidic water, is the most pressing mining environmental issue on a global scale. While it is well recognized that the activity of autotrophic Fe and S bacteria amplify the oxidation of the sulfidic wastes, thereby generating acidity and leaching metals; the underlying microbial geochemistry is not well described. This talk will highlight results revealing the importance of microbial cooperation associated with a novel sulfur-metabolizing consortium enriched from mine waters. Results generated by an integrated approach, combining field characterization, geochemical experimentation, scanning transmission X-ray microscopy (STXM), and fluorescence in situ hybridization (FISH) [1]describing the underlying ecological drivers, the functionally relevant biogeochemical architecture of the consortial macrostructure as well as the identities of this environmental sulphur redox cycling consortium will be presented. The two common mine bacterial strains involved in this consortium, Acidithiobacillus ferroxidans and Acidiphilium sp., are specifically spatially segregated within a macrostructure (pod) of extracellular polymeric substance (EPS) that enables coupled sulphur oxidation and reduction reactions despite bulk, oxygenated conditions. Identical pod formation by type culture strains was induced and linked to ecological conditions. The proposed sulphur geochemistry associated with this bacterial consortium produces 40-90% less acid than expected based on abiotic AMD models, with implications for both AMD mitigation and AMD carbon flux modeling. We are currently investigating the implications of these sulphur-processing pods for metal dynamics in mine systems. These results demonstrate how microbes can orchestrate their geochemical environment to facilitate metabolism, and underscore the need to consider microbial interactions and ecology in constraining their geochemical impacts. [1] Norlund, Southam, Tyliszcczak, Hu, Karunakaran, Obst

  1. The geochemistry of iodine - a review.

    PubMed

    Fuge, R; Johnson, C C

    1986-06-01

    Iodine has long been recognised as an important element environmentally. Despite this there are many gaps in our knowledge of its geochemistry and even where information is available much of this is based on old data which, in the light of recent data, are suspect.Iodine forms few independent minerals and is unlikely to enter most rock-forming minerals. In igneous rocks its concentration is fairly uniform and averages 0.24 mg/kg. Sedimentary rocks tend to have higher concentrations with average iodine contents of:-recent sediments 5-200 mg/kg, carbonates 2.7 mg/kg, shales 2.3 mg/kg and sandstones 0.8 mg/kg. Organic-rich sediments are particularly enriched in iodine.Soils, generally, are much richer in iodine than the parent rocks with the actual level being decided mainly by soil type and locality. Little soil iodine is water-soluble and much iodine is thought to be associated with organic matter, clays and aluminium and iron oxides. Most iodine in soils is derived from the atmosphere where, in turn, it has been derived from the oceans. Seawater has a mean iodine content of 58 μg/L, while non-saline surface waters have lower and very variable levels. Subsurface brines and mineral waters are generally strongly enriched in iodine.Marine plants are frequently enriched in iodine while terrestrial plants have generally low contents. Iodine is essential for all mammals.Consideration of the geochemical cycle of iodine reveals that its transfer from the oceans to the atmosphere is probably the most important process in its geochemistry.

  2. Beryllium isotope geochemistry in tropical river basins

    SciTech Connect

    Brown, E.T.; Edmond, J.M. ); Raisbeck, G.M.; Bourles, D.L.; Yiou, F. ); Measures, C.I. )

    1992-04-01

    The distributions of beryllium-9 and beryllium-10 in rivers within the Orinoco and Amazon basins have been examined to extend the understanding of their geochemical cycles and to develop their use both in geochronometry, and in studying erosional processes. Analyses of {sup 9}Be in dissolved and suspended material from rivers with a wide range of chemical compositions indicate that its geochemistry is primarily controlled by two major factors: (1) its abundance in the rocks of the watershed and (2) the extent of its adsorption onto particle surfaces. The relative importance of these parameters in individual rivers is determined by the extent of interaction with flood-plain sediments and the riverine pH. This understanding of {sup 9}Be geochemistry forms a basis for examination of the geochemical cycling of {sup 10}Be. In rivers which are dominated by interaction with sediments, the riverine concentration of dissolved {sup 10}Be is far lower than that in the incoming rainwater, indicating that a substantial proportion of it is retained within the soils of the basin or is adsorbed onto riverine particles. However, in acidic rivers in which the stable dissolved Be concentration is determined by the Be level in the rocks of the drainage basin, dissolved {sup 10}Be has essentially the same concentration as in precipitation. These observations imply that the soil column in such regions must be saturated with respect to {sup 10}Be, and that the ratio of the inventory to the flux does not represent an age, as may be the case in temperate latitudes, but rather a residence time.

  3. Petrologic testament to changes in shallow magma storage and transport during 30+ years of recharge and eruption at Kīlauea Volcano, Hawai‘i: Chapter 8

    USGS Publications Warehouse

    Thornber, Carl R.; Orr, Tim R.; Heliker, Christina; Hoblitt, Richard P.; Carey, Rebecca; Cayol, Valerie; Poland, Michael; Weis, Dominique

    2015-01-01

    Petrologic monitoring of Kīlauea Volcano from January 1983 to October 2013 has yielded an extensive record of glass, phenocryst, melt inclusion, and bulk-lava chemistry from well-quenched lava. When correlated with 30+ years of geophysical and geologic monitoring, petrologic details testify to physical maturation of summit-to-rift magma plumbing associated with sporadic intrusion and prolonged magmatic overpressurization. Changes through time in bulk-lava major- and trace-element compositions, along with glass thermometry, record shifts in the dynamic balance of fractionation, mixing, and assimilation processes inherent to magma storage and transport during near-continuous recharge and eruption. Phenocryst composition, morphology, and texture, along with the sulfur content of melt inclusions, constrain coupled changes in eruption behavior and geochemistry to processes occurring in the shallow magmatic system. For the first 17 years of eruption, magma was steadily tapped from a summit reservoir at 1–4 km depth and circulating between 1180 and 1200°C. Furthermore, magma cooled another 30°C while flowing through the 18 km long rift conduit, before erupting olivine-spinel-phyric lava at temperatures of 1150–1170°C in a pattern linked with edifice deformation, vent formation, eruptive vigor, and presumably the flux of magma into and out of the summit reservoir. During 2000–2001, a fundamental change in steady state eruption petrology to that of relatively low-temperature, low-MgO, olivine(-spinel)-clinopyroxene-plagioclase-phryic lava points to a physical transformation of the shallow volcano plumbing uprift of the vent. Preeruptive comagmatic mixing between hotter and cooler magma is documented by resorption, overgrowth, and compositional zonation in a mixed population of phenocrysts grown at higher and lower temperatures. Large variations of sulfur (50 to >1000 ppm) in melt inclusions within individual phenocrysts and among phenocrysts in most samples

  4. Tracking the changing oxidation state of Erebus magmas, from mantle to surface, driven by magma ascent and degassing

    NASA Astrophysics Data System (ADS)

    Moussallam, Yves; Oppenheimer, Clive; Scaillet, Bruno; Gaillard, Fabrice; Kyle, Philip; Peters, Nial; Hartley, Margaret; Berlo, Kim; Donovan, Amy

    2014-05-01

    The conventional view holds that the oxidation state of a mantle-derived degassed magma reflects its source. During magma ascent and degassing the oxidation state is thought to follow a redox buffer. While this view has been challenged by petrological data, geochemical models and volcanic gas measurements, the fingerprints of such redox changes and their driving forces have not hitherto been captured by an integrated study. Here, we track the redox evolution of an alkaline magmatic suite at Erebus volcano, Antarctica, from the mantle to the surface, using X-ray absorption near-edge structure (XANES) spectroscopy at the iron and sulphur K-edges. We find that strong reduction of Fe and S dissolved in the melt accompanies magma ascent. Using a model of gas-melt chemical equilibria, we show that sulphur degassing is the driving force behind this evolutionary trend, which spans a wide compositional and depth range. Our results explain puzzling shifts in the oxidation state of gases emitted from Erebus volcano, and indicate that, where sulphur degassing occurs, the oxidation states of degassed volcanic rocks may not reflect their mantle source or co-eruptive gas phase. This calls for caution when inferring the oxidation state of the upper mantle from extrusive rocks and a possible re-assessment of the contribution of volcanic degassing to the early Earth's atmosphere and oceans. The relationship between magma redox conditions and pressure (depth) emphasises the value of measuring redox couples in gases emitted from volcanoes for the purposes of operational forecasting.

  5. Subsurface magma pathways inferred from statistical analysis of volcanic vent distribution and numerical model of magma ascent

    NASA Astrophysics Data System (ADS)

    Germa, Aurelie; Connor, Laura; Connor, Chuck; Malservisi, Rocco

    2015-04-01

    One challenge of volcanic hazard assessment in distributed volcanic fields (large number of small-volume basaltic volcanoes along with one or more silicic central volcanoes) is to constrain the location of future activity. Although the extent of the source of melts at depth can be known using geophysical methods or the location of past eruptive vents, the location of preferential pathways and zones of higher magma flux are still unobserved. How does the spatial distribution of eruptive vents at the surface reveal the location of magma sources or focusing? When this distribution is investigated, the location of central polygenetic edifices as well as clusters of monogenetic volcanoes denote zones of high magma flux and recurrence rate, whereas areas of dispersed monogenetic vents represent zones of lower flux. Additionally, central polygenetic edifices, acting as magma filters, prevent dense mafic magmas from reaching the surface close to their central silicic system. Subsequently, the spatial distribution of mafic monogenetic vents may provide clues to the subsurface structure of a volcanic field, such as the location of magma sources, preferential magma pathways, and flux distribution across the field. Gathering such data is of highly importance in improving the assessment of volcanic hazards. We are developing a modeling framework that compares output of statistical models of vent distribution with outputs form numerical models of subsurface magma transport. Geologic data observed at the Earth's surface are used to develop statistical models of spatial intensity (vents per unit area), volume intensity (erupted volume per unit area) and volume-flux intensity (erupted volume per unit time and area). Outputs are in the form of probability density functions assumed to represent volcanic flow output at the surface. These are then compared to outputs from conceptual models of the subsurface processes of magma storage and transport. These models are using Darcy's law

  6. The relative roles of boundary layer fractionation and homogeneous fractionation in cooling basaltic magma chambers

    NASA Astrophysics Data System (ADS)

    Kuritani, Takeshi

    2009-06-01

    In a cooling magma chamber, magmatic differentiation can proceed both by fractionation of crystals from the main molten part of the magma body (homogeneous fractionation) and by mixing of the main magma with fractionated melt derived from low-temperature mush zones (boundary layer fractionation). In this study, the relative roles of boundary layer fractionation and homogeneous fractionation in basaltic magma bodies were examined using a thermodynamics-based mass balance model. Model calculations show that boundary layer fractionation cannot be a dominant fractionation mechanism when magma chambers are located at low pressures (< ~ 50 MPa) or when magmas are less hydrous (< ~ 1 wt.%), such as mid-ocean ridge basalt and intraplate basalt, because of the low efficiency of melt transport from the mush zones to the main magma. Therefore, magmas evolve principally by homogeneous fractionation. If crystal-melt separation does not occur effectively in the main magma, the magma becomes crystal-rich in the early stages of magmatic evolution. On the other hand, boundary layer fractionation can occur effectively when magmas are hydrous (> ~ 2 wt.%), such as arc basalt, and the magma chambers are located at depth (> ~ 100 MPa). Because the melt derived from mush zones is enriched in alkalis and H 2O, crystallization from the main magma is suppressed by mixing with the mush melt as a consequence of depression of the liquidus temperature. Therefore, homogeneous fractionation is more effectively suppressed in magma chambers in which boundary layer fractionation is more active. If magmatic differentiation proceeds primarily by boundary layer fractionation, magmas can remain free of crystals for long periods during magmatic evolution.

  7. Source of magma for Elet-Ozero pluton (NE Baltic Shield) - subduction or plume-related material?

    NASA Astrophysics Data System (ADS)

    Ryabchikov, Igor; Kogarko, Liya

    2016-04-01

    is confirmed by the presence of carbonatites in Elet-Ozero and neighboring Tiksh-Ozero massifs. Manifestations of carbonatitic magmatism is in the majority of cases related to plume activity [3]. The contribution of material from ascending mantle plume as well as components introduced from subduction zones into parent magmas of these intrusions may not be excluded. Similar situation was analyzed in details for the Lau Basin, SW Pacific [4]. This work has been supported by Russian Science Foundation (grant 15-17-30019). [1] Hofmann A.W., Sampling mantle heterogeneity through oceanic basalts: isotopes and trace elements, in: R.W. Carlson, (Ed), Treatise on Geochemistry 2, Elsevier, Amsterdam, 2003, pp. 61-101. [2] Peltonen P., Brügmann G. Origin of layered continental mantle (Karelian craton, Finland): Geochemical and Re-Os isotope constraints // Lithos 2006. V. 89. P. 405-423. [3] Bell K., Carbonatites: relationship to mantle-plume activity, in: R.E. Ernst, K.L. Buchan, (Eds), Mantle plumes: their identification through time, Geological Society of America Special Paper 352, Boulder, Colorado, 2001, pp. 267-290l. [4] Lupton J., Rubin K.H., Arculus R., Lilley M., Butterfield D., Resing J., Baker E., Embley R. Helium isotope, C/He-3, and Ba-Nb-Ti signatures in the northern Lau Basin: Distinguishing arc, back-arc, and hotspot affinities // Geochemistry Geophysics Geosystems 2015. V. 16. P. 1133-1155.

  8. Ground surface deformation patterns, magma supply, and magma storage at Okmok volcano, Alaska, from InSAR analysis: 1. Intereruption deformation, 1997-2008

    NASA Astrophysics Data System (ADS)

    Lu, Zhong; Dzurisin, Daniel; Biggs, Juliet; Wicks, Charles; McNutt, Steve

    2010-05-01

    Starting soon after the 1997 eruption at Okmok volcano and continuing until the start of the 2008 eruption, magma accumulated in a storage zone centered ˜3.5 km beneath the caldera floor at a rate that varied with time. A Mogi-type point pressure source or finite sphere with a radius of 1 km provides an adequate fit to the deformation field portrayed in time-sequential interferometric synthetic aperture radar images. From the end of the 1997 eruption through summer 2004, magma storage increased by 3.2-4.5 × 107 m3, which corresponds to 75-85% of the magma volume erupted in 1997. Thereafter, the average magma supply rate decreased such that by 10 July 2008, 2 days before the start of the 2008 eruption, magma storage had increased by 3.7-5.2 × 107 m3 or 85-100% of the 1997 eruption volume. We propose that the supply rate decreased in response to the diminishing pressure gradient between the shallow storage zone and a deeper magma source region. Eventually the effects of continuing magma supply and vesiculation of stored magma caused a critical pressure threshold to be exceeded, triggering the 2008 eruption. A similar pattern of initially rapid inflation followed by oscillatory but generally slowing inflation was observed prior to the 1997 eruption. In both cases, withdrawal of magma during the eruptions depressurized the shallow storage zone, causing significant volcano-wide subsidence and initiating a new intereruption deformation cycle.

  9. Ground surface deformation patterns, magma supply, and magma storage at Okmok volcano, Alaska, from InSAR analysis: 1. Intereruption deformation, 1997–2008

    USGS Publications Warehouse

    Lu, Zhong; Dzurisin, Daniel; Biggs, Juliet; Wicks, Charles; McNutt, Steve

    2010-01-01

    Starting soon after the 1997 eruption at Okmok volcano and continuing until the start of the 2008 eruption, magma accumulated in a storage zone centered ~3.5 km beneath the caldera floor at a rate that varied with time. A Mogi-type point pressure source or finite sphere with a radius of 1 km provides an adequate fit to the deformation field portrayed in time-sequential interferometric synthetic aperture radar images. From the end of the 1997 eruption through summer 2004, magma storage increased by 3.2–4.5 × 107 m3, which corresponds to 75–85% of the magma volume erupted in 1997. Thereafter, the average magma supply rate decreased such that by 10 July 2008, 2 days before the start of the 2008 eruption, magma storage had increased by 3.7–5.2 × 107 m3 or 85–100% of the 1997 eruption volume. We propose that the supply rate decreased in response to the diminishing pressure gradient between the shallow storage zone and a deeper magma source region. Eventually the effects of continuing magma supply and vesiculation of stored magma caused a critical pressure threshold to be exceeded, triggering the 2008 eruption. A similar pattern of initially rapid inflation followed by oscillatory but generally slowing inflation was observed prior to the 1997 eruption. In both cases, withdrawal of magma during the eruptions depressurized the shallow storage zone, causing significant volcano-wide subsidence and initiating a new intereruption deformation cycle.

  10. Permeability of alkaline magmas: a study from Campi Flegrei, Italy

    NASA Astrophysics Data System (ADS)

    Polacci, M.; Bouvet de Maissoneuve, C.; Giordano, D.; Piochi, M.; Degruyter, W.; Bachmann, O.; Mancini, L.

    2012-04-01

    Knowledge of permeability is of paramount importance for understanding the evolution of magma degassing during pre-, syn- and post-eruptive volcanic processes. Most permeability estimates existing to date refer to magmas of calc-alkaline compositions. We report here the preliminary results of permeability measurements performed on alkali-trachyte products erupted from the Campanian Ignimbrite (CI) and Monte Nuovo (MTN), two explosive eruptions from Campi Flegrei (CF), an active, hazardous caldera west of Naples, Southern Italy. Darcian (viscous) permeability spans a wide range between 10^-11 and 10^-14 m^2. We observe that the most permeable samples are the scoria clasts from the upper units of MTN; pumice samples from the Breccia Museo facies of CI are instead the least permeable. Non-Darcian (inertial) permeability follows the same trend as Darcian permeability. The first implication of this study is that porosity in alkaline as well as calc-alkaline magmas does not exert a first order control on permeability (e.g. the MTN samples are the most permeable but not the most porous). Second, sample geometry exhibits permeability anisotropy (higher permeability in the direction of vesicle elongation), suggesting stronger degassing in the vertical direction in the conduit. In addition, inertial effects are higher across the sample. As inertial effects are potentially generated by tortuosity (or tortuous vesicle paths), tortuosity is likely higher horizontally than vertically in the conduit. Finally, the measured CF permeability values overlap with those of rhyolitic pumice clasts from the Kos Plateau Tuff (Bouvet de Maisonneuve et al., 2009), together with CI one of the major Quaternary explosive eruptions of the Mediterranean region. This indicates that gas flow is strongly controlled by the geometry of the porous media, which is generated by the bubble dynamics during magma ascent. Therefore, permeability will depend on composition through the rheological properties

  11. Oxygen fugacity of basaltic magmas and the role of gas-forming elements

    NASA Technical Reports Server (NTRS)

    Sato, M.

    1978-01-01

    It is suggested that major variations in the relative oxygen fugacity of a basaltic magma are caused primarily by gas-forming elements, especially carbon and hydrogen. According to this theory, carbon, present in the source region of a basaltic magma, reduces the host magma during ascent, as isothermally carbon becomes more reducing with decreasing pressure. For an anhydrous magma such as lunar basalts, this reduction continues through the extrusive phase and the relative oxygen fugacity decreases rapidly until buffered by the precipitation of a metallic phase. For hydrous magmas such as terrestrial basalts, reduction by carbon is eventually superceded by oxidation due to loss of H2 generated by the reaction of C with H2O and by thermal dissociation of H2O. The relative oxygen fugacity of a hydrous magma initially decreases as a magma ascends from the source region and then increases until magnetite crystallization curbs the rising trend of the relative oxygen fugacity.

  12. RADIOIODINE GEOCHEMISTRY IN THE SRS SUBSURFACE ENVIRONMENT

    SciTech Connect

    Kaplan, D.; Emerson, H.; Powell, B.; Roberts, K.; Zhang, S.; Xu, C.; Schwer, K.; Li, H.; Ho, Y.; Denham, M.; Yeager, C.; Santschi, P.

    2013-05-16

    Iodine-129 is one of the key risk drivers for several Savannah River Site (SRS) performance assessments (PA), including that for the Low-Level Waste Disposal Facility in E-Area. In an effort to reduce the uncertainty associated with the conceptual model and the input values used in PA, several studies have recently been conducted dealing with radioiodine geochemistry at the SRS. The objective of this report was to review these recent studies and evaluate their implications on SRS PA calculations. For the first time, these studies measured iodine speciation in SRS groundwater and provided technical justification for assuming the presence of more strongly sorbing species (iodate and organo-iodine), and measured greater iodine sediment sorption when experiments included these newly identified species; specifically they measured greater sorption coefficients (K{sub d} values: the concentration ratio of iodine on the solid phase divided by the concentration in the aqueous phase). Based on these recent studies, new best estimates were proposed for future PA calculations. The new K{sub d} values are greater than previous recommended values. These proposed K{sub d} values reflect a better understanding of iodine geochemistry in the SRS subsurface environment, which permits reducing the associated conservatism included in the original estimates to account for uncertainty. Among the key contributing discoveries supporting the contention that the K{sub d} values should be increased are that: 1) not only iodide (I{sup -}), but also the more strongly sorbing iodate (IO{sub 3}{sup -}) species exists in SRS groundwater (average total iodine = 15% iodide, 42% iodate, and 43% organoiodine), 2) when iodine was added as iodate, the measured K{sub d} values were 2 to 6 times greater than when the iodine was added as iodide, and perhaps most importantly, 3) higher desorption (10 to 20 mL/g) than (ad)sorption (all previous studies) K{sub d} values were measured. The implications of this

  13. Degassing during magma ascent in the Mule Creek vent (USA)

    NASA Astrophysics Data System (ADS)

    Stasiuk, Mark V.; Barclay, Jenni; Carroll, Michael R.; Jaupart, Claude; Ratté, James C.; Sparks, R. Stephen J.; Tait, Stephen R.

    1996-09-01

    The structures and textures of the rhyolite in the Mule Creek vent (New Mexico, USA) indicate mechanisms by which volatiles escape from silicic magma during eruption. The vent outcrop is a 300-m-high canyon wall comprising a section through the top of a feeder conduit, vent and the base of an extrusive lava dome. Field relations show that eruption began with an explosive phase and ended with lava extrusion. Analyses of glass inclusions in quartz phenocrysts from the lava indicate that the magma had a pre-eruptive dissolved water content of 2.5 3.0 wt% and, during eruption, the magma would have been water-saturated over the vertical extent of the present outcrop. However, the vesicularity of the rhyolite is substantially lower than that predicted from closed-system models of vesiculation under equilibrium conditions. At a given elevation in the vent, the volume fraction of primary vesicles in the rhyolite increases from zero close to the vent margin to values of 20 40 vol.% in the central part. In the centre the vesicularity increases upward from approximately 20 vol.% at 300 m below the canyon rim to approximately 40 vol.% at 200 m, above which it shows little increase. To account for the discrepancy between observed vesicularity and measured water content, we conclude that gas escaped during ascent, probably beginning at depths greater than exposed, by flow through the vesicular magma. Gas escape was most efficient near the vent margin, and we postulate that this is due both to the slow ascent of magma there, giving the most time for gas to escape, and to shear, favouring bubble coalescence. Such shear-related permeability in erupting magma is supported by the preserved distribution of textures and vesicularity in the rhyolite: Vesicles are flattened and overlapping near the dense margins and become progressively more isolated and less deformed toward the porous centre. Local zones have textures which suggest the coalescence of bubbles to form permeable

  14. Degassing during magma ascent in the Mule Creek vent (USA)

    USGS Publications Warehouse

    Stasiuk, M.V.; Barclay, J.; Carroll, M.R.; Jaupart, Claude; Ratte, J.C.; Sparks, R.S.J.; Tait, S.R.

    1996-01-01

    The structures and textures of the rhyolite in the Mule Creek vent (New Mexico, USA) indicate mechanisms by which volatiles escape from silicic magma during eruption. The vent outcrop is a 300-m-high canyon wall comprising a section through the top of a feeder conduit, vent and the base of an extrusive lava dome. Field relations show that eruption began with an explosive phase and ended with lava extrusion. Analyses of glass inclusions in quartz phenocrysts from the lava indicate that the magma had a pre-eruptive dissolved water content of 2.5-3.0 wt% and, during eruption, the magma would have been water-saturated over the vertical extent of the present outcrop. However, the vesicularity of the rhyolite is substantially lower than that predicted from closed-system models of vesiculation under equilibrium conditions. At a given elevation in the vent, the volume fraction of primary vesicles in the rhyolite increases from zero close to the vent margin to values of 20-40 vol.% in the central part. In the centre the vesicularity increases upward from approximately 20 vol.% at 300 m below the canyon rim to approximately 40 vol.% at 200 m, above which it shows little increase. To account for the discrepancy between observed vesicularity and measured water content, we conclude that gas escaped during ascent, probably beginning at depths greater than exposed, by flow through the vesicular magma. Gas escape was most efficient near the vent margin, and we postulate that this is due both to the slow ascent of magma there, giving the most time for gas to escape, and to shear, favouring bubble coalescence. Such shear-related permeability in erupting magma is supported by the preserved distribution of textures and vesicularity in the rhyolite: Vesicles are flattened and overlapping near the dense margins and become progressively more isolated and less deformed toward the porous centre. Local zones have textures which suggest the coalescence of bubbles to form permeable

  15. Finite difference seismic modeling of axial magma chambers

    SciTech Connect

    Swift, S.A.; Dougherty, M.E.; Stephen, R.A. )

    1990-11-01

    The authors tested the feasibility of using finite difference methods to model seismic propagation at {approximately}10 Hx through a two-dimensional representation of an axial magma chamber with a thin, liquid lid. This technique produces time series of displacement or pressure at seafloor receivers to mimic a seismic refraction experiment and snapshots of P and S energy propagation. The results indicate that the implementation is stable for models with sharp velocity contrasts and complex geometries. The authors observe a high-energy, downward-traveling shear phase, observable only with borehole receivers, that would be useful in studying the nature and shape of magma chambers. The ability of finite difference methods to model high-order wave phenomena makes this method ideal for testing velocity models of spreading axes and for planning near-axis drilling of the East Pacific Rise in order to optimize the benefits from shear wave imaging of sub-axis structure.

  16. Origin of High-Alumina Basalt, Andesite, and Dacite Magmas.

    PubMed

    Hamilton, W

    1964-10-30

    The typical volcanic rocks of most island arcs and eugeosynclines, and of some continental environments, are basalt, andesite, and dacite, of high alumina content. The high-alumina basalt differs from tholeiitic basalt primarily in having a greater content of the components of calcic plagioclase. Laboratory data indicate that in the upper mantle, below the level at which the basaltic component of mantle rock is transformed by pressure to eclogite or pyroxenite, the entire basaltic portion probably is melted within a narrow temperature range, but that above the level of that transformation plagioclase is melted selectively before pyroxene over a wide temperature range. The broad spectrum of high-alumina magmas may represent widely varying degrees of partial melting above the transformation level, whereas narrow-spectrum tholeiite magma may represent more complete melting beneath it.

  17. A magma ocean and the Earth's internal water budget

    NASA Technical Reports Server (NTRS)

    Ahrens, Thomas J.

    1992-01-01

    There are lines of evidence which relate bounds on the primordial water content of the Earth's mantle to a magma ocean and the accompanying Earth accretion process. We assume initially (before a magma ocean could form) that as the Earth accreted, it grew from volatile- (H2O, CO2, NH3, CH4, SO2, plus noble) gas-rich planetesimals, which accreted to form an initial 'primitive accretion core' (PAC). The PAC retained the initial complement of planetesimal gaseous components. Shock wave experiments in which both solid, and more recently, the gaseous components of materials such as serpentine and the Murchison meteorite have demonstrated that planetesimal infall velocities of less than 0.5 km/sec, induce shock pressures of less than 0.5 GPa and result in virtually complete retention of planetary gases.

  18. Origin of High-Alumina Basalt, Andesite, and Dacite Magmas.

    PubMed

    Hamilton, W

    1964-10-30

    The typical volcanic rocks of most island arcs and eugeosynclines, and of some continental environments, are basalt, andesite, and dacite, of high alumina content. The high-alumina basalt differs from tholeiitic basalt primarily in having a greater content of the components of calcic plagioclase. Laboratory data indicate that in the upper mantle, below the level at which the basaltic component of mantle rock is transformed by pressure to eclogite or pyroxenite, the entire basaltic portion probably is melted within a narrow temperature range, but that above the level of that transformation plagioclase is melted selectively before pyroxene over a wide temperature range. The broad spectrum of high-alumina magmas may represent widely varying degrees of partial melting above the transformation level, whereas narrow-spectrum tholeiite magma may represent more complete melting beneath it. PMID:17794034

  19. Origin of high-alumina basalt, andesite, and dacite magmas

    USGS Publications Warehouse

    Hamilton, W.

    1964-01-01

    The typical volcanic rocks of most island arcs and eugeosynclines, and of some continental environments, are basalt, andesite, and dacite, of high alumina content. The high-alumina basalt differs from tholeiitic basalt primarily in having a greater content of the components of calcic plagioclase. Laboratory data indicate that in the upper mantle, below the level at which the basaltic component of mantle rock is transformed by pressure to eclogite or pyroxenite, the entire basaltic portion probably is melted within a narrow temperature range, but that above the level of that transformation plagioclase is melted selectively before pyroxene over a wide temperature range. The broad spectrum of high-alumina magmas may represent widely varying degrees of partial melting above the transformation level, whereas narrow-spectrum tholeiite magma may represent more complete melting beneath it.

  20. Symmetries and nonlocal conservation laws of the general magma equation

    NASA Astrophysics Data System (ADS)

    Khamitova, Raisa

    2009-11-01

    In this paper the general magma equation modelling a melt flow in the Earth's mantle is discussed. Applying the new theorem on nonlocal conservation laws [Ibragimov NH. A new conservation theorem. J Math Anal Appl 2007;333(1):311-28] and using the symmetries of the model equation nonlocal conservation laws are computed. In accordance with Ibragimov [Ibragimov NH. Quasi-self-adjoint differential equations. Preprint in Archives of ALGA, vol. 4, BTH, Karlskrona, Sweden: Alga Publications; 2007. p. 55-60, ISSN: 1652-4934] it is shown that the general magma equation is quasi-self-adjoint for arbitrary m and n and self-adjoint for n = -m. These important properties are used for deriving local conservation laws.

  1. Dissolved volatile concentrations in an ore-forming magma

    USGS Publications Warehouse

    Lowenstern, J. B.

    1994-01-01

    Infrared spectroscopic measurements of glass inclusions within quartz phenocrysts from the Plinian fallout of the 22 Ma tuff of Pine Grove show that the trapped silicate melt contained high concentrations of H2O and CO2. Intrusive porphyries from the Pine Grove system are nearly identical in age, composition, and mineralogy to the tephra, and some contain high-grade Mo mineralization. Assuming that the porphyry magmas originally contained similar abundances of volatile components as the erupted rocks, they would have been saturated with fluid at pressures far greater than those at which the porphyries were emplaced and mineralized. The data are consistent with formation of Climax-type Mo porphyry deposits by prolonged fluid flux from a large volume of relatively Mo-poor (1-5 ppm) magma. -from Author

  2. Geochemistry of A-type granites in the Huangshaping polymetallic deposit (South Hunan, China): Implications for granite evolution and associated mineralization

    NASA Astrophysics Data System (ADS)

    Li, Huan; Watanabe, Koichiro; Yonezu, Kotaro

    2014-07-01

    The Huangshaping granites in Hunan Province, South China were investigated for their geochemical characteristics. Three types of granites have been petrographically identified: quartz porphyry, granophyre, and granite porphyry. Whole rock geochemistry suggests that the Huangshaping granites, especially the granite porphyry, exhibit typical A-type granite characteristics with their enrichment in Si, Rb, U, Th, and Nb and significant depletion in Ba, Sr, Ti, Eu, and P. Based on the Al, Y and Zr contents as well as the REE patterns of the rocks investigated, the quartz porphyry and the granophyre are classified as A1 type alkaline granites whereas the granite porphyry is considered as A2 type aluminous granite. Whole rock and quartz/feldspar O isotope data yields a wide range of δ18OSMOW values (11.09-26.32‰). The granites are characterized by high radiogenic Pb isotopic composition. The present-day whole rock Pb isotopic ratios are 206Pb/204Pb = 18.706-19.155, 207Pb/204Pb = 15.616-15.711 and 208Pb/204Pb = 38.734-39.296. Combining the O-Pb isotope compositions with major, trace and REE geochemistry and regional geology characteristics, the Huangshaping granites were determined to resemble within-plate granites that were mainly derived from a felsic infracrustal source related to continental extension. The magma source of the quartz porphyry and the granophyre may have been generated from deeper depths, and then ascended rapidly with limited water content and low oxygen fugacity, which contributed to Cu, Pb and Zn mineralization. On the other hand, the magma that generated the granite porphyry may have ascended relatively slower and experienced pronounced crystal fractionation, upper-crustal basement rock contamination (assimilation) and wall-rock interaction, producing the Sn- and W-rich granite porphyry. This study reveals the crustal extension process and associated magmatic-metallogenic activities during 180-150 Ma in South Hunan.

  3. Experiments on the rheology of vesicle-bearing magmas

    NASA Astrophysics Data System (ADS)

    Vona, Alessandro; Ryan, Amy G.; Russell, James K.; Romano, Claudia

    2016-04-01

    We present a series of high temperature uniaxial deformation experiments designed to investigate the effect of bubbles on the magma bulk viscosity. Starting materials having variable vesicularity (φ = 0 - 66%) were synthesized by high-temperature foaming (T = 900 - 1050 ° C and P = 1 bar) of cores of natural rhyolitic obsidian from Hrafntinnuhryggur, Krafla, Iceland. These cores were subsequently deformed using a high-temperature uniaxial press at dry atmospheric conditions. Each experiment involved deforming vesicle-bearing cores isothermally (T = 750 ° C), at constant displacement rates (strain rates between 0.5-1 x 10‑4 s‑1), and to total strains (ɛ) of 10-40%. The viscosity of the bubble-free melt (η0) was measured by micropenetration and parallel plate methods and establishes a baseline for comparing data derived from experiments on vesicle rich cores. At the experimental conditions, the presence of vesicles has a major impact on the rheological response, producing a marked decrease of bulk viscosity (maximum decrease of 2 log units Pa s) that is best described by a two-parameter empirical equation: log ηBulk = log η0 - 1.47 * [φ/(1-φ)]0.48. Our model provides a means to compare the diverse behaviour of vesicle-bearing melts reported in the literature and reflecting material properties (e.g., analogue vs. natural), geometry and distribution of pores (e.g. foamed/natural vs. unconsolidated/sintered materials), and flow regime. Lastly, we apply principles of Maxwell relaxation theory, combined with our parameterization of bubble-melt rheology, to map the potential onset of non-Newtonian behaviour (strain localization) in vesiculated magmas and lavas as a function of melt viscosity, vesicularity, strain rate, and geological condition. Increasing vesicularity in magmas can initiate non-Newtonian behaviour at constant strain rates. Lower melt viscosity sustains homogeneous Newtonian flow in vesiculated magmas even at relatively high strain rates.

  4. Magmas and magmatic rocks: An introduction to igneous petrology

    SciTech Connect

    Middlemost, E.A.K.

    1986-01-01

    This book melds traditional igneous petrology with the emerging science of planetary petrology to provide an account of current ideas on active magmatic and volcanic processes, drawing examples from all igneous provinces of the world as well as from the moon and planets. It reviews the history and development of concepts fundamental to modern igneous petrology and includes indepth sections on magmas, magnetic differentiation and volcanology.

  5. Experiments on the rheology of vesicle-bearing magmas

    NASA Astrophysics Data System (ADS)

    Vona, Alessandro; Ryan, Amy G.; Russell, James K.; Romano, Claudia

    2016-04-01

    We present a series of high temperature uniaxial deformation experiments designed to investigate the effect of bubbles on the magma bulk viscosity. Starting materials having variable vesicularity (φ = 0 - 66%) were synthesized by high-temperature foaming (T = 900 - 1050 ° C and P = 1 bar) of cores of natural rhyolitic obsidian from Hrafntinnuhryggur, Krafla, Iceland. These cores were subsequently deformed using a high-temperature uniaxial press at dry atmospheric conditions. Each experiment involved deforming vesicle-bearing cores isothermally (T = 750 ° C), at constant displacement rates (strain rates between 0.5-1 x 10-4 s-1), and to total strains (ɛ) of 10-40%. The viscosity of the bubble-free melt (η0) was measured by micropenetration and parallel plate methods and establishes a baseline for comparing data derived from experiments on vesicle rich cores. At the experimental conditions, the presence of vesicles has a major impact on the rheological response, producing a marked decrease of bulk viscosity (maximum decrease of 2 log units Pa s) that is best described by a two-parameter empirical equation: log ηBulk = log η0 - 1.47 * [φ/(1-φ)]0.48. Our model provides a means to compare the diverse behaviour of vesicle-bearing melts reported in the literature and reflecting material properties (e.g., analogue vs. natural), geometry and distribution of pores (e.g. foamed/natural vs. unconsolidated/sintered materials), and flow regime. Lastly, we apply principles of Maxwell relaxation theory, combined with our parameterization of bubble-melt rheology, to map the potential onset of non-Newtonian behaviour (strain localization) in vesiculated magmas and lavas as a function of melt viscosity, vesicularity, strain rate, and geological condition. Increasing vesicularity in magmas can initiate non-Newtonian behaviour at constant strain rates. Lower melt viscosity sustains homogeneous Newtonian flow in vesiculated magmas even at relatively high strain rates.

  6. Dynamic Heating and Decompression Experiments on Dacite and Rhyolite Magmas

    NASA Astrophysics Data System (ADS)

    Andrews, B. J.; Waters, L.; Grocke, S. B.

    2015-12-01

    Mineral reaction rims, zoned crystals, and myriad growth or dissolution textures provide evidence for changes in magma pressure, temperature, or composition. Quantifying the magnitudes, timescales and length scales of those variations is a fundamental challenge of volcanology and igneous petrology; experiments provide quantitative insights into how magmas react to changes in pressure and temperature that can be used to address that challenge. We use single-step and dynamic experiments conducted in cold seal pressure vessels to study the responses of dacite and rhyolite magmas to heating and decompression events. During single-step decompression (or heating) experiments, conditions are changed nearly instantaneously from the initial to final state in one step, or several smaller steps, whereas "dynamic experiments" have continuous variation in pressure and/or temperature. These two types of experiments yield useful and complementary information describing crystal nucleation, growth, and reaction rates in response to changing (as opposed to steady state) conditions. Here we discuss isothermal decompression experiments that show substantial path-dependence for runs with equivalent time-averaged decompression rates as slow as 0.27 MPa/h for >500 h. Continuous decompression experiments often contain fewer but larger plagioclase crystals than are present in single-step runs, and those new crystals often show complex growth textures. Our results suggest that even slow changes in storage conditions can disrupt melt structure and greatly retard nucleation provided the changes are steady. We hypothesize that if the decompression path remains steady and continuous (absent a stall on and/or rapid decompression), the magma can remain in a growth-dominated regime even though it is far from equilibrium.

  7. Magma Chamber Dynamics Recorded by Mineral Disequilibrium. Evidences and Questions.

    NASA Astrophysics Data System (ADS)

    Wagner, C.; Deloule, E.

    2004-05-01

    Clinopyroxenes (cpx) are one of the phases commonly used for tracing shallow-level processes in magma reservoirs. They are likely phases to constrain and record the magmatic evolution, as they are liquidus phases over a wide range of temperature and composition, and incorporate trace elements in sufficient amounts to be analysed. We discuss here the potentiality and limits for reconstructing magma chamber dynamics from a study of disequilibrium cpx assemblages from alkaline rocks from North Morocco. Cpx are Al-rich diopside and salite enriched in incompatible elements. Salite and diopside occur indifferently as resorbed cores or rims, and their respective composition is identical in both cases. The Al distribution between octahedral and tetrahedral sites shows that cores and rims follow a trend of low-pressure origin. This supports shallow-level crystallization for all cpx, including the cores, which then do not represent xenocrysts extracted from the wall-rock during ascent. The heterogeneous cpx population may result from : 1) a thermally and compositionally zoned reservoir in which salite crystallized from the mush layer (T = 950oC) and diopside from the main magma body (T = 1150oC). Residence times of 1 to 15 years have been estimated for cores and rims respectively, constraining the movement of the cpx in and out of the mush layer. 2) mixing processes: as both diopside and salite cores are present, mixing must have occurred subsequent the crystallization of both types of cpx in their respective magmas. Oscillatory zoning of diopsidic and salitic compositions suggests repeated mixing episodes (up to four cycles of crystallization interrupted by episodes of mixing between more or less evolved melts). Different scenarii will be proposed. Particularly, we discuss the importance of crystal-chemical controls (crystal lattice model) and liquid composition/structure on partitioning of some elements (HFSE, REE, Sr) between cpx and melt for using with confidence the cpx

  8. MAGMA: generalized gene-set analysis of GWAS data.

    PubMed

    de Leeuw, Christiaan A; Mooij, Joris M; Heskes, Tom; Posthuma, Danielle

    2015-04-01

    By aggregating data for complex traits in a biologically meaningful way, gene and gene-set analysis constitute a valuable addition to single-marker analysis. However, although various methods for gene and gene-set analysis currently exist, they generally suffer from a number of issues. Statistical power for most methods is strongly affected by linkage disequilibrium between markers, multi-marker associations are often hard to detect, and the reliance on permutation to compute p-values tends to make the analysis computationally very expensive. To address these issues we have developed MAGMA, a novel tool for gene and gene-set analysis. The gene analysis is based on a multiple regression model, to provide better statistical performance. The gene-set analysis is built as a separate layer around the gene analysis for additional flexibility. This gene-set analysis also uses a regression structure to allow generalization to analysis of continuous properties of genes and simultaneous analysis of multiple gene sets and other gene properties. Simulations and an analysis of Crohn's Disease data are used to evaluate the performance of MAGMA and to compare it to a number of other gene and gene-set analysis tools. The results show that MAGMA has significantly more power than other tools for both the gene and the gene-set analysis, identifying more genes and gene sets associated with Crohn's Disease while maintaining a correct type 1 error rate. Moreover, the MAGMA analysis of the Crohn's Disease data was found to be considerably faster as well.

  9. Slab melting and magma generation beneath the southern Cascade Arc

    NASA Astrophysics Data System (ADS)

    Walowski, K. J.; Wallace, P. J.; Clynne, M. A.

    2014-12-01

    Magma formation in subduction zones is interpreted to be caused by flux melting of the mantle wedge by fluids derived from dehydration of the downgoing oceanic lithosphere. In the Cascade Arc and other hot-slab subduction zones, however, most dehydration reactions occur beneath the forearc, necessitating a closer investigation of magma generation processes in this setting. Recent work combining 2-D steady state thermal models and the hydrogen isotope composition of olivine-hosted melt inclusions from the Lassen segment of the Cascades (Walowski et al., 2014; in review) has shown that partial melting of the subducted basaltic crust may be a key part of the subduction component in hot arcs. In this model, fluids from the slab interior (hydrated upper mantle) rise through the slab and cause flux-melting of the already dehydrated MORB volcanics in the upper oceanic crust. In the Shasta and Lassen segments of the southern Cascades, support for this interpretation comes from primitive magmas that have MORB-like Sr isotope compositions that correlate with subduction component tracers (H2O/Ce, Sr/P) (Grove et al. 2002, Borg et al. 2002). In addition, mass balance calculations of the composition of subduction components show ratios of trace elements to H2O that are at the high end of the global arc array (Ruscitto et al. 2012), consistent with the role of a slab-derived melt. Melting of the subducted basaltic crust should contribute a hydrous dacitic or rhyolitic melt (e.g. Jego and Dasgupta, 2013) to the mantle wedge rather than an H2O-rich aqueous fluid. We are using pHMELTS and pMELTS to model the reaction of hydrous slab melts with mantle peridotite as the melts rise through the inverted thermal gradient in the mantle wedge. The results of the modeling will be useful for understanding magma generation processes in arcs that are associated with subduction of relatively young oceanic lithosphere.

  10. Petrology and Geochemistry of the Northeast Seamounts of the Galapagos Platform

    NASA Astrophysics Data System (ADS)

    Sinton, C. W.; Harpp, K. S.; Christie, D. M.

    2010-12-01

    , the data indicate that the seamounts were produced by variable extents of melting of a depleted mantle source. The mineralogy and geochemistry of the Northeastern Seamounts is similar to off-axis volcanoes, such as the Lamont Seamounts. We suggest that the Northeast Seamounts formed by passive rifting of young oceanic crust in which partial melts in the underlying mantle migrate in response to regional stresses. The primitive nature of the melts indicates the lack of a large magma chamber typical of those underlying mid-ocean ridges.

  11. Magma ascent pathways associated with large mountains on Io

    NASA Astrophysics Data System (ADS)

    McGovern, Patrick J.; Kirchoff, Michelle R.; White, Oliver L.; Schenk, Paul M.

    2016-07-01

    While Jupiter's moon Io is the most volcanically active body in the Solar System, the largest mountains seen on Io are created by tectonic forces rather than volcanic construction. Pervasive compression, primarily brought about by subsidence induced by sustained volcanic resurfacing, creates the mountains, but at the same time inhibits magma ascent in vertical conduits (dikes). We superpose stress solutions for subsidence, along with thermal stress, (both from the "crustal conveyor belt" process of resurfacing) in Io's lithosphere with stresses from Io mountain-sized loads (in a shallow spherical shell solution) in order to evaluate magma ascent pathways. We use stress orientation (least compressive stress horizontal) and stress gradient (compression decreasing upwards) criteria to identify ascent pathways through the lithosphere. There are several configurations for which viable ascent paths transit nearly the entire lithosphere, arriving at the base of the mountain, where magma can be transported through thrust faults or perhaps thermally eroded flank sections. The latter is consistent with observations of some Io paterae in close contact with mountains.

  12. The chlorine isotope fingerprint of the lunar magma ocean

    PubMed Central

    Boyce, Jeremy W.; Treiman, Allan H.; Guan, Yunbin; Ma, Chi; Eiler, John M.; Gross, Juliane; Greenwood, James P.; Stolper, Edward M.

    2015-01-01

    The Moon contains chlorine that is isotopically unlike that of any other body yet studied in the Solar System, an observation that has been interpreted to support traditional models of the formation of a nominally hydrogen-free (“dry”) Moon. We have analyzed abundances and isotopic compositions of Cl and H in lunar mare basalts, and find little evidence that anhydrous lava outgassing was important in generating chlorine isotope anomalies, because 37Cl/35Cl ratios are not related to Cl abundance, H abundance, or D/H ratios in a manner consistent with the lava-outgassing hypothesis. Instead, 37Cl/35Cl correlates positively with Cl abundance in apatite, as well as with whole-rock Th abundances and La/Lu ratios, suggesting that the high 37Cl/35Cl in lunar basalts is inherited from urKREEP, the last dregs of the lunar magma ocean. These new data suggest that the high chlorine isotope ratios of lunar basalts result not from the degassing of their lavas but from degassing of the lunar magma ocean early in the Moon’s history. Chlorine isotope variability is therefore an indicator of planetary magma ocean degassing, an important stage in the formation of terrestrial planets. PMID:26601265

  13. Does temperature increase or decrease in adiabatic decompression of magma?

    NASA Astrophysics Data System (ADS)

    Kilinc, A. I.; Ghiorso, M. S.; Khan, T.

    2011-12-01

    We have modeled adiabatic decompression of an andesitic and a basaltic magma as an isentropic process using the Melts algorithm. Our modeling shows that during adiabatic decompression temperature of andesitic magma increases but temperature of basaltic magma decreases. In an isentropic process entropy is constant so change of temperature with pressure can be written as dT/dP=T (dV/dT)/Cp where T (dV/dT)/Cp is generally positive. If delta P is negative so is delta T. In general, in the absence of phase change, we expect the temperature to decrease with adiabatic decompression. The effect of crystallization is to turn a more entropic phase (liquid) into a less entropic phase (solid), which must be compensated by raising the temperature. If during adiabatic decompression there is small amount or no crystallization, T (dV/dT)/Cp effect which lowers the temperature overwhelms the small amount of crystallization, which raises the temperature, and overall system temperature decreases.

  14. Concentration variance decay during magma mixing: a volcanic chronometer.

    PubMed

    Perugini, Diego; De Campos, Cristina P; Petrelli, Maurizio; Dingwell, Donald B

    2015-01-01

    The mixing of magmas is a common phenomenon in explosive eruptions. Concentration variance is a useful metric of this process and its decay (CVD) with time is an inevitable consequence during the progress of magma mixing. In order to calibrate this petrological/volcanological clock we have performed a time-series of high temperature experiments of magma mixing. The results of these experiments demonstrate that compositional variance decays exponentially with time. With this calibration the CVD rate (CVD-R) becomes a new geochronometer for the time lapse from initiation of mixing to eruption. The resultant novel technique is fully independent of the typically unknown advective history of mixing - a notorious uncertainty which plagues the application of many diffusional analyses of magmatic history. Using the calibrated CVD-R technique we have obtained mingling-to-eruption times for three explosive volcanic eruptions from Campi Flegrei (Italy) in the range of tens of minutes. These in turn imply ascent velocities of 5-8 meters per second. We anticipate the routine application of the CVD-R geochronometer to the eruptive products of active volcanoes in future in order to constrain typical "mixing to eruption" time lapses such that monitoring activities can be targeted at relevant timescales and signals during volcanic unrest. PMID:26387555

  15. The chlorine isotope fingerprint of the lunar magma ocean.

    PubMed

    Boyce, Jeremy W; Treiman, Allan H; Guan, Yunbin; Ma, Chi; Eiler, John M; Gross, Juliane; Greenwood, James P; Stolper, Edward M

    2015-09-01

    The Moon contains chlorine that is isotopically unlike that of any other body yet studied in the Solar System, an observation that has been interpreted to support traditional models of the formation of a nominally hydrogen-free ("dry") Moon. We have analyzed abundances and isotopic compositions of Cl and H in lunar mare basalts, and find little evidence that anhydrous lava outgassing was important in generating chlorine isotope anomalies, because (37)Cl/(35)Cl ratios are not related to Cl abundance, H abundance, or D/H ratios in a manner consistent with the lava-outgassing hypothesis. Instead, (37)Cl/(35)Cl correlates positively with Cl abundance in apatite, as well as with whole-rock Th abundances and La/Lu ratios, suggesting that the high (37)Cl/(35)Cl in lunar basalts is inherited from urKREEP, the last dregs of the lunar magma ocean. These new data suggest that the high chlorine isotope ratios of lunar basalts result not from the degassing of their lavas but from degassing of the lunar magma ocean early in the Moon's history. Chlorine isotope variability is therefore an indicator of planetary magma ocean degassing, an important stage in the formation of terrestrial planets. PMID:26601265

  16. Magma mixing due to disruption of a compositional interface

    SciTech Connect

    Flood, T.P.; Schuraytz, B.C.; Vogel, T.A.

    1986-07-15

    The chemical compositions of glassy pumices are used to investigate the relationship between two ash-flow sheets that were erupted from the same volcanic center. The first ash-flow sheet, the large volume (>1200 km{sup 3}) Topopah Spring Member, represents an eruption from a magma body that contained a sharp compositional interface between a high-silica rhyolite and a lower-silica quartz latite. The second ash-flow sheet is the smaller volume (<40 km{sup 3}) Pah Canyon Member. It represents an eruption of a relatively homogenous magma that is intermediate in composition to the compositions of the Topopah Spring Member. Mixing of the quartz latite and rhyolite magmas to produce the Pah Canyon Member is evaluated using variation diagrams of the major and trace elements, ratio-ratio plots, and least-squares multiple linear regression. The latter includes two independent tests, one using the major elements, and the other using selected trace elements. Fractional crystallization of the quartz latite to produce the Pah Canyon Member is evaluated using multiple linear regression with both the major elements and selected trace elements.

  17. Deep degassing and the eruptibility of flood basalt magmas

    NASA Astrophysics Data System (ADS)

    Black, B. A.; Manga, M.

    2015-12-01

    Individual flood basalt lavas often exceed 103 km3 in volume, and many such lavas erupt during emplacement of flood basalt provinces. The large volume of individual flood basalt lavas demands correspondingly large magma reservoirs within or at the base of the crust. To erupt, some fraction of this magma must become buoyant and overpressure must be sufficient to encourage failure and dike propagation. Because the overpressure associated with a new injection of magma is inversely proportional to the total reservoir volume, buoyancy overpressure has been proposed as a trigger for flood basalt eruptions. To test this hypothesis, we develop a new one-dimensional model for buoyancy overpressure-driven eruptions that combines volatile exsolution, bubble growth and rise, assimilation, and permeable fluid escape through the surrounding country rocks. Degassing during emplacement of flood basalt provinces may have major environmental repercussions. We investigate the temporal evolution of permeable degassing through the crust and degassing during eruptive episodes. We find that assimilation of volatile-rich country rocks strongly enhances flood basalt eruptibility, implying that the eruptive dynamics of flood basalts may be intertwined with their climatic consequences.

  18. Concentration variance decay during magma mixing: a volcanic chronometer

    PubMed Central

    Perugini, Diego; De Campos, Cristina P.; Petrelli, Maurizio; Dingwell, Donald B.

    2015-01-01

    The mixing of magmas is a common phenomenon in explosive eruptions. Concentration variance is a useful metric of this process and its decay (CVD) with time is an inevitable consequence during the progress of magma mixing. In order to calibrate this petrological/volcanological clock we have performed a time-series of high temperature experiments of magma mixing. The results of these experiments demonstrate that compositional variance decays exponentially with time. With this calibration the CVD rate (CVD-R) becomes a new geochronometer for the time lapse from initiation of mixing to eruption. The resultant novel technique is fully independent of the typically unknown advective history of mixing – a notorious uncertainty which plagues the application of many diffusional analyses of magmatic history. Using the calibrated CVD-R technique we have obtained mingling-to-eruption times for three explosive volcanic eruptions from Campi Flegrei (Italy) in the range of tens of minutes. These in turn imply ascent velocities of 5-8 meters per second. We anticipate the routine application of the CVD-R geochronometer to the eruptive products of active volcanoes in future in order to constrain typical “mixing to eruption” time lapses such that monitoring activities can be targeted at relevant timescales and signals during volcanic unrest. PMID:26387555

  19. Viscosity of bubble- and crystal- bearing magmas: Analogue results

    NASA Astrophysics Data System (ADS)

    Namiki, A.; Manga, M.

    2006-12-01

    Natural magmas often include both phenocrysts and bubbles. Such magmas can be regarded as suspensions including particles and bubbles and should have a viscosity different from the particle- and bubble- free melt. Viscosity is one of the key physical properties that affects eruption dynamics and magma flow. To understand the relation between the viscosity and the volume fraction of bubbles and particles, we directly measure the viscosity of suspensions with both particles and bubbles. Measurements are performed with the 4 degree cone-and-plate type rheometer (Thermo HAAKE Rheoscope 1), which allows us to observe the samples in situ during the measurement. The suspending fluid is corn syrup whose viscosity is 1.7 Pa·s at 23 °C. Particles are Techpolymer (polymethylmethacrylate) 40 μm diameter spheres. Bubbles are made by dissolving baking soda and citric acid; reaction between them generates carbon dioxide. No surfactant is added. The Peclet number is sufficiently large that Brownian motion does not influence our results. The measured viscosity for the suspensions with particles, and with both particles and bubbles, show strong shear thinning. The measured viscosities during increasing and decreasing shear rate differ from each other, indicating that the microstructure is modified by flow. When the deformation of bubbles is not significant, the measured viscosity with bubbles is higher than that without bubbles, and vice versa.

  20. Dropping stones in magma oceans - Effects of early lunar cratering

    NASA Technical Reports Server (NTRS)

    Hartmann, W. K.

    1980-01-01

    A new methodology is used to calculate the accumulation rate of megaregolith materials for two models of early lunar cratering, both with and without episodes of late cataclysmic cratering. Results show that the pulverization of early rock layers was an important process competing with the formation of a coherent rock lithosphere at the surface of the hypothetical lunar magma ocean. If a magma ocean existed, then its initial cooling was marked by a period of pre-lithospheric chaos in which impacts punched through the initially thin rocky skin, mixing rock fragments with splashed magma. Furthermore, the results show that intense brecciation and pulverization of rock materials must have occurred to a depth of at least tens of kilometers in the first few hundred years of lunar history regardless of whether a 'terminal lunar cataclysm' occurred around 4.0 G.y. ago. The predicted pattern of brecciation and the ages of surviving rock fragments is similar to that actually observed among lunar samples. More reliable dating of basin-forming events and models of rock exhumation and survival are needed in order to understand better the relation between the early intense bombardment of the moon and the samples collected on the moon today.

  1. The chlorine isotope fingerprint of the lunar magma ocean.

    PubMed

    Boyce, Jeremy W; Treiman, Allan H; Guan, Yunbin; Ma, Chi; Eiler, John M; Gross, Juliane; Greenwood, James P; Stolper, Edward M

    2015-09-01

    The Moon contains chlorine that is isotopically unlike that of any other body yet studied in the Solar System, an observation that has been interpreted to support traditional models of the formation of a nominally hydrogen-free ("dry") Moon. We have analyzed abundances and isotopic compositions of Cl and H in lunar mare basalts, and find little evidence that anhydrous lava outgassing was important in generating chlorine isotope anomalies, because (37)Cl/(35)Cl ratios are not related to Cl abundance, H abundance, or D/H ratios in a manner consistent with the lava-outgassing hypothesis. Instead, (37)Cl/(35)Cl correlates positively with Cl abundance in apatite, as well as with whole-rock Th abundances and La/Lu ratios, suggesting that the high (37)Cl/(35)Cl in lunar basalts is inherited from urKREEP, the last dregs of the lunar magma ocean. These new data suggest that the high chlorine isotope ratios of lunar basalts result not from the degassing of their lavas but from degassing of the lunar magma ocean early in the Moon's history. Chlorine isotope variability is therefore an indicator of planetary magma ocean degassing, an important stage in the formation of terrestrial planets.

  2. Concentration variance decay during magma mixing: a volcanic chronometer

    NASA Astrophysics Data System (ADS)

    Perugini, D.; De Campos, C. P.; Petrelli, M.; Dingwell, D. B.

    2015-12-01

    The mixing of magmas is a common phenomenon in explosive eruptions. Concentration variance is a useful metric of this process and its decay (CVD) with time is an inevitable consequence during the progress of magma mixing. In order to calibrate this petrological/volcanological clock we have performed a time-series of high temperature experiments of magma mixing. The results of these experiments demonstrate that compositional variance decays exponentially with time. With this calibration the CVD rate (CVD-R) becomes a new geochronometer for the time lapse from initiation of mixing to eruption. The resultant novel technique is fully independent of the typically unknown advective history of mixing - a notorious uncertainty which plagues the application of many diffusional analyses of magmatic history. Using the calibrated CVD-R technique we have obtained mingling-to-eruption times for three explosive volcanic eruptions from Campi Flegrei (Italy) in the range of tens of minutes. These in turn imply ascent velocities of 5-8 meters per second. We anticipate the routine application of the CVD-R geochronometer to the eruptive products of active volcanoes in future in order to constrain typical "mixing to eruption" time lapses such that monitoring activities can be targeted at relevant timescales and signals during volcanic unrest.

  3. Concentration variance decay during magma mixing: a volcanic chronometer

    NASA Astrophysics Data System (ADS)

    Perugini, Diego; de Campos, Cristina P.; Petrelli, Maurizio; Dingwell, Donald B.

    2015-09-01

    The mixing of magmas is a common phenomenon in explosive eruptions. Concentration variance is a useful metric of this process and its decay (CVD) with time is an inevitable consequence during the progress of magma mixing. In order to calibrate this petrological/volcanological clock we have performed a time-series of high temperature experiments of magma mixing. The results of these experiments demonstrate that compositional variance decays exponentially with time. With this calibration the CVD rate (CVD-R) becomes a new geochronometer for the time lapse from initiation of mixing to eruption. The resultant novel technique is fully independent of the typically unknown advective history of mixing - a notorious uncertainty which plagues the application of many diffusional analyses of magmatic history. Using the calibrated CVD-R technique we have obtained mingling-to-eruption times for three explosive volcanic eruptions from Campi Flegrei (Italy) in the range of tens of minutes. These in turn imply ascent velocities of 5-8 meters per second. We anticipate the routine application of the CVD-R geochronometer to the eruptive products of active volcanoes in future in order to constrain typical “mixing to eruption” time lapses such that monitoring activities can be targeted at relevant timescales and signals during volcanic unrest.

  4. Freezing of a Magma Ocean and Subsequent Mantle Differentiation

    NASA Astrophysics Data System (ADS)

    Hansen, U.; Schmalzl, J.

    2007-12-01

    It seems likely that a Magma ocean, after separation of iron from silicate, did freeze from the bottom up, due to the increase of pressure with depth. A scenario can thus arise in which hot material at the bottom of the magma ocean is compositionally light and underlies colder but compositionally denser material. A rapid the evolution of chemical heterogeneities of this instable configuration has been proposed by several authors. By means of two- and three-dimensional convection models, we investigated the overturn-scenario and especially the subsequent evolution of the mantle, following the magma ocean period. The numerical models include finite element and finite volume procedures as well as front tracking methods to capture the evolution of chemical heterogeneities Our numerical experiments clearly reveals that an overturning puts the mantle into the diffusive regime, characterized by an unstable thermal, but stable compositional stratification. The formation of layered flow structures is, a typical phenomenon in this regime. In a wide parameter range (thermal/compositional Rayleighnumbers, realistic rheologies and various distribution of internal heat sources) , we observe the overturning followed by a long period of layered convection. Vigorous convection takes place in the upper- and lower mantle, while typically a less vigorous convection layer develops in between. The number of layers and their individual lifetime depends on the particular parameters. However in any case, layered structures develop over a significant time span, such that a profound influence on the chemical evolution seems reasonable to expect.

  5. DOE workshop: Sedimentary systems, aqueous and organic geochemistry

    SciTech Connect

    Not Available

    1993-07-01

    A DOE workshop on sedimentary systems, aqueous and organic geochemistry was held July 15-16, 1993 at Lawrence Berkeley Laboratory. Papers were organized into several sections: Fundamental Properties, containing papers on the thermodynamics of brines, minerals and aqueous electrolyte solutions; Geochemical Transport, covering 3-D imaging of drill core samples, hydrothermal geochemistry, chemical interactions in hydrocarbon reservoirs, fluid flow model application, among others; Rock-Water Interactions, with presentations on stable isotope systematics of fluid/rock interaction, fluid flow and petotectonic evolution, grain boundary transport, sulfur incorporation, tracers in geologic reservoirs, geothermal controls on oil-reservoir evolution, and mineral hydrolysis kinetics; Organic Geochemistry covered new methods for constraining time of hydrocarbon migration, kinetic models of petroleum formation, mudstones in burial diagenesis, compound-specific carbon isotope analysis of petroleums, stability of natural gas, sulfur in sedimentary organic matter, organic geochemistry of deep ocean sediments, direct speciation of metal by optical spectroscopies; and lastly, Sedimentary Systems, covering sequence stratigraphy, seismic reflectors and diagenetic changes in carbonates, geochemistry and origin of regional dolomites, and evidence of large comet or asteroid impacts at extinction boundaries.

  6. Oxygen isotope study of the Long Valley magma system, California: isotope thermometry and convection in large silicic magma bodies

    NASA Astrophysics Data System (ADS)

    Bindeman, Ilya; Valley, John

    2002-07-01

    Products of voluminous pyroclastic eruptions with eruptive draw-down of several kilometers provide a snap-shot view of batholith-scale magma chambers, and quench pre-eruptive isotopic fractionations (i.e., temperatures) between minerals. We report analyses of oxygen isotope ratio in individual quartz phenocrysts and concentrates of magnetite, pyroxene, and zircon from individual pumice clasts of ignimbrite and fall units of caldera-forming 0.76 Ma Bishop Tuff (BT), pre-caldera Glass Mountain (2.1-0.78 Ma), and post-caldera rhyolites (0.65-0.04 Ma) to characterize the long-lived, batholith-scale magma chamber beneath Long Valley Caldera in California. Values of δ18O show a subtle 1‰ decrease from the oldest Glass Mountain lavas to the youngest post-caldera rhyolites. Older Glass Mountain lavas exhibit larger ( 1‰) variability of δ18O(quartz). The youngest domes of Glass Mountain are similar to BT in δ18O(quartz) values and reflect convective homogenization during formation of BT magma chamber surrounded by extremely heterogeneous country rocks (ranging from 2 to +29‰). Oxygen isotope thermometry of BT confirms a temperature gradient between "Late" (815 °C) and "Early" (715 °C) BT. The δ18O(quartz) values of "Early" and "Late" BT are +8.33 and 8.21‰, consistent with a constant δ18O(melt)=7.8+/-0.1‰ and 100 °C temperature difference. Zircon-melt saturation equilibria gives a similar temperature range. Values of δ18O(quartz) for different stratigraphic units of BT, and in pumice clasts ranging in pre-eruptive depths from 6 to 11 km (based on melt inclusions), and document vertical and lateral homogeneity of δ18O(melt). Worldwide, five other large-volume rhyolites, Lava Creek, Lower Bandelier, Fish Canyon, Cerro Galan, and Toba, exhibit equal δ18O(melt) values of earlier and later erupted portions in each of the these climactic caldera-forming eruptions. We interpret the large-scale δ18O homogeneity of BT and other large magma chambers as evidence

  7. A model for the origin of large silicic magma chambers: precursors of caldera-forming eruptions

    SciTech Connect

    Jellinek, A. Mark; DePaolo, Donald J.

    2002-01-02

    The relatively low rates of magma production in island arcs and continental extensional settings require that the volume of silicic magma involved in large catastrophic caldera-forming (CCF) eruptions must accumulate over periods of 10(5) to 10(6) years. We address the question of why buoyant and otherwise eruptible high silica magma should accumulate for long times in shallow chambers rather than erupt more continuously as magma is supplied from greater depths. Our hypothesis is that the viscoelastic behavior of magma chamber wall rocks may prevent an accumulation of overpressure sufficient to generate rhyolite dikes that can propagate to the surface and cause an eruption. The critical overpressure required for eruption is based on the model of Rubin (1995a). An approximate analytical model is used to evaluate the controls on magma overpressure for a continuously or episodically replenished spherical magma chamber contained in wall rocks with a Maxwell viscoelastic rheology. The governing parameters are the long-term magma supply, the magma chamber volume, and the effective viscosity of the wall rocks. The long-term magma supply, a parameter that is not typically incorporated into dike formation models, can be constrained from observations and melt generation models. For effective wall-rock viscosities in the range 10(18) to 10(20) Pa s(-1), dynamical regimes are identified that lead to the suppression of dikes capable of propagating to the surface. Frequent small eruptions that relieve magma chamber overpressure are favored when the chamber volume is small relative to the magma supply and when the wall rocks are cool. Magma storage, leading to conditions suitable for a CCF eruption, is favored for larger magma chambers (>10(2) km(3)) with warm wall rocks that have a low effective viscosity. Magma storage is further enhanced by regional tectonic extension, high magma crystal contents, and if the effective wall-rock viscosity is lowered by microfracturing, fluid

  8. Evolution of a Chemically Zoned Magma Body: Black Mountain Volcanic Center, southwestern Nevada

    NASA Astrophysics Data System (ADS)

    Vogel, Thomas A.; Noble, Donald C.; Younker, Leland W.

    1989-05-01

    Rocks of the Black Mountain volcanic center consist of four ash flow sheets and units of lava that underlie, interfinger with, and overlie the sheets. Rocks from the center represent three magma types. Magma type c was present through the history of the center, whereas types a and b were available after the eruption of the Rocket Wash Member, during the eruptions of the Pahute Mesa and Trail Ridge members. The magma types are defined by trace element ratios; for example, magma types a, b, and c have La/Th values of 1.0-3.5, >7.5, and 3.5-7.5. Silica contents in the magma types a, b, and c range from 71.5 to 74.1, from 65.8 to 69.2, and from 55.6 to 73.8 wt %, respectively. The stratigraphic distribution of chemically distinct pumice fragments within the ash flow sheets is used to show that magma type a was located in the uppermost part of the chamber and was underlain successively by magma types b and c. Because pumice fragments that belong to all three magma types occur in individual cooling units, a zoned magma body must have existed during this period. Magma mixing is indicated by the disequilibrium phenocrysts which are common in pumice fragments from all magma types; however, this mixing did not destroy the original zoning of the upper part of the magma body. Most of the chemical variation of magma type c is consistent with fractionation of feldspar, olivine, and pyroxene, but abundant disequilibrium, mafic phenocrysts indicate that magma replenishment and mixing were common. Magma type b had much higher La/Th and light rare earth element (LREE)/heavy rare earth element values and must have originated independently from magma type c. Most likely the two types were derived from different source material. The low La/Th values of magma type a can be explained by separation of a phenocryst assemblage containing both a LREE-bearing phase and zircon from either magma types b or c, or possibly by the partial melting of source material containing these phases.

  9. The non-isothermal rheology of low viscosity magmas.

    NASA Astrophysics Data System (ADS)

    Kolzenburg, Stephan; Giordano, Daniele; Dingwell, Donald B.

    2016-04-01

    Accurate prediction of the run-out distance of lava flows, as well as the understanding of magma migration in shallow dyke systems is hampered by an incomplete understanding of the transient, sub-liquidus rheology of crystallizing melts. This sets significant limits to physical property based modelling of lava flow (especially flow width, length and advancement rate) and magma migration behaviour and the resulting accuracy of volcanic hazard assessment The importance of the dynamic rheology of a lava / magma on its emplacement style becomes especially apparent in towards later stages of flow and dyke emplacement, where the melt builds increasing resistance to flow, entering rheologic regimes that determine the halting of lava flows and sealing of dykes. Thermal gradients between the interior of a melt body and the contact with air or the substratum govern these rheologic transitions that give origin to flow directing or impeding features like levees, tubes and chilled margins. Besides the critical importance of non-isothermal and sub-liquidus processes for the understanding of natural systems, accurate rheologic data at these conditions are scarce and studies capturing the transient rheological evolution of lavas at conditions encountered during emplacement virtually absent. We describe the rheologic evolution of a series of natural, re-melted lava samples during transient and non-equilibrium crystallization conditions characteristic of lava flows and shallow magmatic systems in nature. The sample suite spans from foidites to basalts; the dominant compositions producing low viscosity lava flows. Our data show that all melts undergo one or more change zones in effective viscosity when subjected to sub liquidus temperatures. The apparent viscosity of the liquid-crystal suspension increases drastically from the theoretical temperature-viscosity relationship of a pure liquid once cooled below the liquidus temperature. We find that: 1) Both cooling rate a