Dielectronic recombination experiments at the storage rings: From the present CSR to the future HIAF
NASA Astrophysics Data System (ADS)
Huang, Z. K.; Wen, W. Q.; Xu, X.; Wang, H. B.; Dou, L. J.; Chuai, X. Y.; Zhu, X. L.; Zhao, D. M.; Li, J.; Ma, X. M.; Mao, L. J.; Yang, J. C.; Yuan, Y. J.; Xu, W. Q.; Xie, L. Y.; Xu, T. H.; Yao, K.; Dong, C. Z.; Zhu, L. F.; Ma, X.
2017-10-01
Dielectronic recombination (DR) experiments of highly charged ions at the storage rings have been developed as a precision spectroscopic tool to investigate the atomic structure as well as nuclear properties of stable and unstable nuclei. The DR experiment on lithium-like argon ions was successfully performed at main Cooler Storage Ring (CSRm) at Heavy Ion Research Facility in Lanzhou (HIRFL) accelerator complex. The DR experiments on heavy highly charged ions and even radioactive ions are currently under preparation at the experimental Cooler Storage Ring (CSRe) at HIRFL. The current status of DR experiments at the CSRm and the preparation of the DR experiments at the CSRe are presented. In addition, an overview of DR experiments by employing an electron cooler and a separated ultra-cold electron target at the upcoming High Intensity heavy ion Accelerator Facility (HIAF) will be given.
Ion shaking in the 200 MeV XLS-ring
NASA Astrophysics Data System (ADS)
Bozoki, E.; Kramer, S. L.
1992-03-01
It has been shown that ions, trapped inside the beam's potential, can be removed by the clearing electrodes when the amplitude of the ion oscillation is increased by vertically shaking the ions. We will report on a similar experiment in the 200 MeV XLS ring. The design of the ion clearing system for the ring and the first results obtained were already reported. In the present series of experiments, RF voltage was applied on a pair of vertical strip-lines. The frequency was scanned in the range of the ion (from H2 to CO2) bounce frequencies in the ring (1-10 MHz). The response of the beam size, vertical betatron tune, and lifetime was studied.
Ring-averaged ion velocity distribution function probe for laboratory magnetized plasma experiment
NASA Astrophysics Data System (ADS)
Kawamori, Eiichirou; Chen, Jinting; Lin, Chiahsuan; Lee, Zongmau
2017-10-01
Ring-averaged velocity distribution function of ions at a fixed guiding center position is a fundamental quantity in the gyrokinetic plasma physics. We have developed a diagnostic tool for the ring averaged velocity distribution function of ions for laboratory plasma experiments, which is named as the ring-averaged ion distribution function probe (RIDFP). The RIDFP is a set of ion collectors for different velocities. It is designed to be immersed in magnetized plasmas and achieves momentum selection of incoming ions by the selection of the ion Larmor radii. To nullify the influence of the sheath potential surrounding the RIDFP on the orbits of the incoming ions, the electrostatic potential of the RIDFP body is automatically adjusted to coincide with the space potential of the target plasma with the use of an emissive probe and a voltage follower. The developed RIDFP successfully measured the equilibrium ring-averaged velocity distribution function of a laboratory magnetized plasma, which was in accordance with the Maxwellian distribution having an ion temperature of 0.2 eV.
Ring-averaged ion velocity distribution function probe for laboratory magnetized plasma experiment.
Kawamori, Eiichirou; Chen, Jinting; Lin, Chiahsuan; Lee, Zongmau
2017-10-01
Ring-averaged velocity distribution function of ions at a fixed guiding center position is a fundamental quantity in the gyrokinetic plasma physics. We have developed a diagnostic tool for the ring averaged velocity distribution function of ions for laboratory plasma experiments, which is named as the ring-averaged ion distribution function probe (RIDFP). The RIDFP is a set of ion collectors for different velocities. It is designed to be immersed in magnetized plasmas and achieves momentum selection of incoming ions by the selection of the ion Larmor radii. To nullify the influence of the sheath potential surrounding the RIDFP on the orbits of the incoming ions, the electrostatic potential of the RIDFP body is automatically adjusted to coincide with the space potential of the target plasma with the use of an emissive probe and a voltage follower. The developed RIDFP successfully measured the equilibrium ring-averaged velocity distribution function of a laboratory magnetized plasma, which was in accordance with the Maxwellian distribution having an ion temperature of 0.2 eV.
Status and outlook of the CRYRING@ESR project
NASA Astrophysics Data System (ADS)
Geithner, W.; Andelkovic, Z.; Beck, D.; Bräuning, H.; Bräuning-Demian, A.; Danared, H.; Dimopoulou, C.; Engström, M.; Fedotova, S.; Gorda, O.; Herfurth, F.; Hess, R.; Källberg, A.; Kleffner, C.; Kotovskiy, N.; Kraus, I.; Lestinsky, M.; Litvinov, S.; Nolden, F.; Reiter, A.; Sieber, T.; Steck, M.; Vorobyev, G.
2017-11-01
Once operational, CRYRING@ESR will store and decelerate ions delivered by the experimental storage ring ESR at energies well below those of ESR. In addition to that, CRYRING@ESR has an electron cooler operating with an ultracold electron beam, allowing to provide cooled ion beams for precision experiments. These ions will be delivered to a broad range of experiments presently in preparation; either in-ring or extracted to a dedicated beamline for experiments. An overview and status report of the installation and commissioning of the CRYRING-@ESR storage ring for highly charged ions at the GSI Helmholtzzentrum für Schwerionenforschung is presented. The installation of this storage ring started in 2014 and was completing end of 2016, when this publication was written.
Assembling a ring-shaped crystal in a microfabricated surface ion trap
Stick, Daniel Lynn; Tabakov, Boyan; Benito, Francisco; ...
2015-09-01
We report on experiments with a microfabricated surface trap designed for confining a chain of ions in a ring. Uniform ion separation over most of the ring is achieved with a rotationally symmetric design and by measuring and suppressing undesired electric fields. After reducing stray fields, the ions are confined primarily by a radio-frequency pseudopotential and their mutual Coulomb repulsion. As a result, approximately 400 40Ca + ions with an average separation of 9 μm comprise the ion crystal.
Assembling a ring-shaped crystal in a microfabricated surface ion trap
DOE Office of Scientific and Technical Information (OSTI.GOV)
Stick, Daniel Lynn; Tabakov, Boyan; Benito, Francisco
We report on experiments with a microfabricated surface trap designed for confining a chain of ions in a ring. Uniform ion separation over most of the ring is achieved with a rotationally symmetric design and by measuring and suppressing undesired electric fields. After reducing stray fields, the ions are confined primarily by a radio-frequency pseudopotential and their mutual Coulomb repulsion. As a result, approximately 400 40Ca + ions with an average separation of 9 μm comprise the ion crystal.
Ion shaking in the 200 MeV XLS-ring
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bozoki, E.; Kramer, S.L.
1992-01-01
It has been shown that ions, trapped inside the beam's potential, can be removed by the clearing electrodes when the amplitude of the ion oscillation is increased by vertically shaking the ions. We will report on a similar experiment in the 200 Mev XLS ring. The design of the ion clearing system for the ring and the first results obtained, were already reported. In the present series of experiments, RF voltage was applied on a pair of vertical strip-lines. The frequency was scanned in the range of the ion (from H[sub 2] to CO[sub 2]) bounce frequencies in the ringmore » (1--10 MHz). The response of the beam size, vertical betatron tune and lifetime was studied.« less
Ion shaking in the 200 MeV XLS-ring
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bozoki, E.; Kramer, S.L.
1992-12-31
It has been shown that ions, trapped inside the beam`s potential, can be removed by the clearing electrodes when the amplitude of the ion oscillation is increased by vertically shaking the ions. We will report on a similar experiment in the 200 Mev XLS ring. The design of the ion clearing system for the ring and the first results obtained, were already reported. In the present series of experiments, RF voltage was applied on a pair of vertical strip-lines. The frequency was scanned in the range of the ion (from H{sub 2} to CO{sub 2}) bounce frequencies in the ringmore » (1--10 MHz). The response of the beam size, vertical betatron tune and lifetime was studied.« less
A Study of Single Pass Ion Effects at the ALS
DOE Office of Scientific and Technical Information (OSTI.GOV)
Byrd, J.M.; Thomson, J.; /LBL, Berkeley
2011-09-13
We report the results of experiments on a 'fast beam-ion instability' at the Advanced Light Source (ALS). This ion instability, which can arise even when the ions are not trapped over multiple beam passages, will likely be important for many future accelerators. In our experiments, we filled the ALS storage ring with helium gas, raising the pressure approximately two orders of magnitude above the nominal pressure. With gaps in the bunch train large enough to avoid conventional (multi-turn) ion trapping, we observed a factor of 2-3 increase in the vertical beam size along with coherent beam oscillations which increased alongmore » the bunch train. Ion trapping has long been recognized as a potential limitation in electron storage rings. The ions, generated by beam-gas collisions, become trapped in the negative potential of the beam and accumulate over multiple beam passages. The trapped ions are then observed to cause a number of deleterious effects such as an increasing beam phase space, a broadening and shifting of the beam transverse oscillation frequencies (tunes), collective beam instabilities, and beam lifetime reductions. All of these effects are of concern for the next generation of accelerators, such as the B-factories or damping rings for future linear colliders, which will store high beam currents with closely spaced bunches and ultra-low beam emittances. One of the standard solutions used to prevent ion trapping is to include a gap in the bunch train which is long compared to the bunch spacing. In this case, the ions are first strongly-focused by the passing electron bunches and then over-focused in the gap. With a sufficiently large gap, the ions can be driven to large amplitudes where they form a diffuse halo and do not affect the beam. In this paper, we describe experiments that study a new regime of transient ion instabilities predicted to arise in future electron storage rings, and linacs with bunch trains. These future rings and linacs, which will be operated with higher beam currents, small transverse beam emittances, and long bunch trains, will use ion clearing gaps to prevent conventional ion trapping. But, while the ion clearing gap may suppress the conventional ion instabilities, it will not suppress a transient beam-ion instability where ions generated and trapped during the passage of a single train lead to a fast instability. While both conventional and transient ion instabilities have the same origin, namely ions produced by the beam, they have different manifestations and, more importantly, the new transient instability can arise even after the conventional ion instability is cured. This new instability is called the 'Fast Beam-Ion Instability' (FBII). In many future rings, the FBII is predicted to have very fast growth rates, much faster than the damping rates of existing and proposed transverse feedback systems, and thus is a potential limitation. To study the FBII, we performed experiments at the ALS, a 1.5 GeV electron storage ring. At the nominal ALS pressure of about 0.24 nTorr, the FBII is not evident. To study the instability, we intentionally added helium gas to the storage-ring vacuum system until the residual gas pressure was increased about 80 nTorr. This brought the predicted growth rate of the instability at least an order of magnitude above the growth rate of conventional multibunch instabilities driven by the RF cavities and above the damping rate of the transverse feedback system (TFB) in the ALS and, thereby, established conditions very similar to those in a future storage ring. We then filled the ring with a relatively short train of bunches, suppressing conventional ion instabilities. In the following, we will first briefly describe This paper describes the experiment and results in more detail.« less
Status of the Frankfurt low energy electrostatic storage ring (FLSR)
NASA Astrophysics Data System (ADS)
King, F.; Kruppi, T.; Müller, J.; Dörner, R.; Schmidt, L. Ph H.; Schmidt-Böcking, H.; Stiebing, K. E.
2015-11-01
Frankfurt low-energy storage ring (FLSR) is an electrostatic storage ring for low-energy ions up to q · 80 keV (q being the ion charge state) at Institut für Kernphysik der Goethe-Universität, Frankfurt am Main, Germany. It has especially been designed to provide a basis for experiments on the dynamics of ionic and molecular collisions in complete kinematics, as well as for high precision and time resolved laser spectroscopy. The ring has ‘racetrack’ geometry with a circumference of 14.23 m. It comprises four experimental/diagnostic sections with regions of enhanced ion density (interaction regions). First beam has successfully been stored in FLSR in summer 2013. Since then the performance of the ring has continuously been improved and an electron target for experiments on dissociative recombination has been installed in one of the experimental sections.
Non-linear Evolution of Velocity Ring Distributions: Generation of Whistler Waves
NASA Astrophysics Data System (ADS)
Mithaiwala, M.; Rudakov, L.; Ganguli, G.
2010-12-01
Although it is typically believed that an ion ring velocity distribution has a stability threshold, we find that they are universally unstable. This can substantially impact the understanding of dynamics in both laboratory and space plasmas. A high ring density neutralizes the stabilizing effect of ion Landau damping in a warm plasma and the ring is unstable to the generation of waves below the lower hybrid frequency- even for a very high temperature plasma. For ring densities lower than the background plasma density there is a slow instability with growth rate less than the background ion cyclotron frequency and consequently the background ion response is magnetized. This is in addition to the widely discussed fast instability where the wave growth rate exceeds the background ion cyclotron frequency and hence the background ions are effectively unmagnetized. Thus, even a low density ring is unstable to waves around the lower hybrid frequency range for any ring speed. This implies that effectively there is no velocity threshold for a sufficiently cold ring. The importance of these conclusions on the nonlinear evolution of space plasmas, in particular to solar wind-comet interaction, post-magnetospheric storm conditions, and chemical release experiments in the ionosphere will be discussed.
Universally Unstable Nature of Velocity Ring Distributions
NASA Astrophysics Data System (ADS)
Mithaiwala, Manish
2010-11-01
Although it is typically believed that an ion ring velocity distribution has a stability threshold, we find that they are universally unstable. This can substantially impact the understanding of dynamics in both laboratory and space plasmas. A high ring density neutralizes the stabilizing effect of ion Landau damping in a warm plasma and the ring is unstable to the generation of waves below the lower hybrid frequency- even for a very high temperature plasma. For ring densities lower than the background plasma density there is a slow instability with growth rate less than the background ion cyclotron frequency and consequently the background ion response is magnetized. This is in addition to the widely discussed fast instability where the wave growth rate exceeds the background ion cyclotron frequency and hence the background ions are effectively unmagnetized. Thus, even a low density ring is unstable to waves around the lower hybrid frequency range for any ring speed. This implies that effectively there is no velocity threshold for a sufficiently cold ring. The importance of these conclusions on the nonlinear evolution of space plasmas, in particular to solar wind-comet interaction, post-magnetospheric storm conditions, and chemical release experiments in the ionosphere will be discussed.
CsI-Silicon Particle detector for Heavy ions Orbiting in Storage rings (CsISiPHOS)
NASA Astrophysics Data System (ADS)
Najafi, M. A.; Dillmann, I.; Bosch, F.; Faestermann, T.; Gao, B.; Gernhäuser, R.; Kozhuharov, C.; Litvinov, S. A.; Litvinov, Yu. A.; Maier, L.; Nolden, F.; Popp, U.; Sanjari, M. S.; Spillmann, U.; Steck, M.; Stöhlker, T.; Weick, H.
2016-11-01
A heavy-ion detector was developed for decay studies in the Experimental Storage Ring (ESR) at the GSI Helmholtz Centre for Heavy Ion Research in Darmstadt, Germany. This detector serves as a prototype for the in-pocket particle detectors for future experiments with the Collector Ring (CR) at FAIR (Facility for Antiproton and Ion Research). The detector includes a stack of six silicon pad sensors, a double-sided silicon strip detector (DSSD), and a CsI(Tl) scintillation detector. It was used successfully in a recent experiment for the detection of the β+-decay of highly charged 142Pm60+ ions. Based on the ΔE / E technique for particle identification and an energy resolution of 0.9% for ΔE and 0.5% for E (Full Width at Half Maximum (FWHM)), the detector is well-suited to distinguish neighbouring isobars in the region of interest.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Zhao, H.; Li, X.; Baker, D. N.
Based on comprehensive measurements from Helium, Oxygen, Proton, and Electron Mass Spectrometer Ion Spectrometer, Relativistic Electron-Proton Telescope, and Radiation Belt Storm Probes Ion Composition Experiment instruments on the Van Allen Probes, comparative studies of ring current electrons and ions are performed and the role of energetic electrons in the ring current dynamics is investigated. The deep injections of tens to hundreds of keV electrons and tens of keV protons into the inner magnetosphere occur frequently; after the injections the electrons decay slowly in the inner belt but protons in the low L region decay very fast. Intriguing similarities between lowermore » energy protons and higher-energy electrons are also found. The evolution of ring current electron and ion energy densities and energy content are examined in detail during two geomagnetic storms, one moderate and one intense. Here, the results show that the contribution of ring current electrons to the ring current energy content is much smaller than that of ring current ions (up to ~12% for the moderate storm and ~7% for the intense storm), and <35 keV electrons dominate the ring current electron energy content at the storm main phases. Though the electron energy content is usually much smaller than that of ions, the enhancement of ring current electron energy content during the moderate storm can get to ~30% of that of ring current ions, indicating a more dynamic feature of ring current electrons and important role of electrons in the ring current buildup. Lastly, the ring current electron energy density is also shown to be higher at midnight and dawn while lower at noon and dusk.« less
Zhao, H.; Li, X.; Baker, D. N.; ...
2016-04-16
Based on comprehensive measurements from Helium, Oxygen, Proton, and Electron Mass Spectrometer Ion Spectrometer, Relativistic Electron-Proton Telescope, and Radiation Belt Storm Probes Ion Composition Experiment instruments on the Van Allen Probes, comparative studies of ring current electrons and ions are performed and the role of energetic electrons in the ring current dynamics is investigated. The deep injections of tens to hundreds of keV electrons and tens of keV protons into the inner magnetosphere occur frequently; after the injections the electrons decay slowly in the inner belt but protons in the low L region decay very fast. Intriguing similarities between lowermore » energy protons and higher-energy electrons are also found. The evolution of ring current electron and ion energy densities and energy content are examined in detail during two geomagnetic storms, one moderate and one intense. Here, the results show that the contribution of ring current electrons to the ring current energy content is much smaller than that of ring current ions (up to ~12% for the moderate storm and ~7% for the intense storm), and <35 keV electrons dominate the ring current electron energy content at the storm main phases. Though the electron energy content is usually much smaller than that of ions, the enhancement of ring current electron energy content during the moderate storm can get to ~30% of that of ring current ions, indicating a more dynamic feature of ring current electrons and important role of electrons in the ring current buildup. Lastly, the ring current electron energy density is also shown to be higher at midnight and dawn while lower at noon and dusk.« less
The design of the Spectrometer Ring at the HIAF
NASA Astrophysics Data System (ADS)
Wu, B.; Yang, J. C.; Xia, J. W.; Yan, X. L.; Hu, X. J.; Mao, L. J.; Sheng, L. N.; Wu, J. X.; Yin, D. Y.; Chai, W. P.; Shen, G. D.; Ge, W. W.; Wang, G.; Zhao, H.; Ruan, S.; Ma, X. W.; Wang, M.; Litvinov, S.; Wen, W. Q.; Chen, X. C.; Chen, R. J.; Tang, M. T.; Wu, W.; Luo, C.; Zhao, T. C.; Shi, C. F.; Fu, X.; Liu, J.; Liang, L.
2018-02-01
The Spectrometer Ring (SRing) is an essential part of the High Intensity heavy-ion Accelerator Facility project (HIAF) in China. It is designed as a multi-functional experimental storage ring, which will be able to operate in three ion optical operation modes. The SRing will be used as a time-of-flight mass spectrometer for short-lived, especially neutron-rich nuclei. It will also be used to collect and cool Rare Isotope Beams (RIBs) or highly-charged stable ion beams for nuclear and atomic physics experiments. The design magnetic rigidity is in the range 1.5 to 15 Tm. The beam cooling system consists of stochastic cooling and electron cooling devices. With a help of an electron cooler, stored ions will be decelerated to a minimum energy of 30 MeV/u by RF cavities. The extraction system of the SRing will allow cooled ion beams to be extracted to an external target for further ion manipulations or reaction experiments. The general ion optics design and technical requirements of SRing subsystems are presented and discussed in this paper.
Devakumar, Arugadoss; Mechref, Yehia; Kang, Pilsoo; Novotny, Milos V.; Reilly, James P.
2008-01-01
Characterization of structural isomers has become increasingly important and extremely challenging in glycobiology. This communication demonstrates the capability of ion-trap mass spectrometry in conjunction with 157 nm photofragmentation to identify different structural isomers of permethylated N-glycans derived from ovalbumin without chromatographic separation. The results are compared with CID experiments. Photodissociation generates extensive cross-ring fragment ions as well as diagnostic glycosidic product ions that are not usually observed in CID MS/MS experiments. The detection of these product ions aids in characterizing indigenous glycan isomers. The ion-trap facilitates MSn experiments on the diagnostic glycosidic fragments and cross-ring product ions generated through photofragmentation, thus allowing unambiguous assignment of all of the isomeric structures associated with the model glycoprotein utilized in this study. Photofragmentation is demonstrated to be a powerful technique for the structural characterization of glycans. PMID:18487060
First storage of ion beams in the Double Electrostatic Ion-Ring Experiment: DESIREE.
Schmidt, H T; Thomas, R D; Gatchell, M; Rosén, S; Reinhed, P; Löfgren, P; Brännholm, L; Blom, M; Björkhage, M; Bäckström, E; Alexander, J D; Leontein, S; Hanstorp, D; Zettergren, H; Liljeby, L; Källberg, A; Simonsson, A; Hellberg, F; Mannervik, S; Larsson, M; Geppert, W D; Rensfelt, K G; Danared, H; Paál, A; Masuda, M; Halldén, P; Andler, G; Stockett, M H; Chen, T; Källersjö, G; Weimer, J; Hansen, K; Hartman, H; Cederquist, H
2013-05-01
We report on the first storage of ion beams in the Double ElectroStatic Ion Ring ExpEriment, DESIREE, at Stockholm University. We have produced beams of atomic carbon anions and small carbon anion molecules (C(n)(-), n = 1, 2, 3, 4) in a sputter ion source. The ion beams were accelerated to 10 keV kinetic energy and stored in an electrostatic ion storage ring enclosed in a vacuum chamber at 13 K. For 10 keV C2 (-) molecular anions we measure the residual-gas limited beam storage lifetime to be 448 s ± 18 s with two independent detector systems. Using the measured storage lifetimes we estimate that the residual gas pressure is in the 10(-14) mbar range. When high current ion beams are injected, the number of stored particles does not follow a single exponential decay law as would be expected for stored particles lost solely due to electron detachment in collision with the residual-gas. Instead, we observe a faster initial decay rate, which we ascribe to the effect of the space charge of the ion beam on the storage capacity.
TSR: A storage and cooling ring for HIE-ISOLDE
NASA Astrophysics Data System (ADS)
Butler, P. A.; Blaum, K.; Davinson, T.; Flanagan, K.; Freeman, S. J.; Grieser, M.; Lazarus, I. H.; Litvinov, Yu. A.; Lotay, G.; Page, R. D.; Raabe, R.; Siesling, E.; Wenander, F.; Woods, P. J.
2016-06-01
It is planned to install the heavy-ion, low-energy ring TSR, currently at the Max-Planck-Institute for Nuclear Physics in Heidelberg, at the HIE-ISOLDE facility in CERN, Geneva. Such a facility will provide a capability for experiments with stored, cooled secondary beams that is rich and varied, spanning from studies of nuclear ground-state properties and reaction studies of astrophysical relevance, to investigations with highly-charged ions and pure isomeric beams. In addition to experiments performed using beams recirculating within the ring, the cooled beams can be extracted and exploited by external spectrometers for high-precision measurements. The capabilities of the ring facility as well as some physics cases will be presented, together with a brief report on the status of the project.
Lifetimes of relativistic heavy-ion beams in the High Energy Storage Ring of FAIR
NASA Astrophysics Data System (ADS)
Shevelko, V. P.; Litvinov, Yu. A.; Stöhlker, Th.; Tolstikhina, I. Yu.
2018-04-01
The High Energy Storage Ring, HESR, will be constructed at the Facility for Antiproton and Ion Research, FAIR, Darmstadt. For the first time, it will be possible to perform experiments with cooled high-intensity stable and radioactive heavy ions at highly relativistic energies. To design experiments at the HESR, realistic estimations of beam lifetimes are indispensable. Here we report calculated cross sections and lifetimes for typical U88+ , U90+ , U92+ , Sn49+ and Sn50+ ions in the energy range E = 400 MeV/u-5 GeV/u, relevant for the HESR. Interactions with the residual gas and with internal gas-jet targets are also considered.
Electron cooling of a bunched ion beam in a storage ring
NASA Astrophysics Data System (ADS)
Zhao, He; Mao, Lijun; Yang, Jiancheng; Xia, Jiawen; Yang, Xiaodong; Li, Jie; Tang, Meitang; Shen, Guodong; Ma, Xiaoming; Wu, Bo; Wang, Geng; Ruan, Shuang; Wang, Kedong; Dong, Ziqiang
2018-02-01
A combination of electron cooling and rf system is an effective method to compress the beam bunch length in storage rings. A simulation code based on multiparticle tracking was developed to calculate the bunched ion beam cooling process, in which the electron cooling, intrabeam scattering (IBS), ion beam space-charge field, transverse and synchrotron motion are considered. Meanwhile, bunched ion beam cooling experiments have been carried out in the main cooling storage ring (CSRm) of the Heavy Ion Research Facility in Lanzhou, to investigate the minimum bunch length obtained by the cooling method, and study the dependence of the minimum bunch length on beam and machine parameters. The experiments show comparable results to those from simulation. Based on these simulations and experiments, we established an analytical model to describe the limitation of the bunch length of the cooled ion beam. It is observed that the IBS effect is dominant for low intensity beams, and the space-charge effect is much more important for high intensity beams. Moreover, the particles will not be bunched for much higher intensity beam. The experimental results in CSRm show a good agreement with the analytical model in the IBS dominated regime. The simulation work offers us comparable results to those from the analytical model both in IBS dominated and space-charge dominated regimes.
NASA Astrophysics Data System (ADS)
Wang, H. B.; Wen, W. Q.; Huang, Z. K.; Zhang, D. C.; Hai, B.; Zhu, X. L.; Zhao, D. M.; Yang, J.; Li, J.; Li, X. N.; Mao, L. J.; Mao, R. S.; Wu, J. X.; Yang, J. C.; Yuan, Y. J.; Eidam, L.; Winters, D.; Beck, T.; Kiefer, D.; Rein, B.; Walther, Th.; Loeser, M.; Schramm, U.; Siebold, M.; Bussmann, M.; Ma, X.
2017-10-01
We report on an experiment that was conducted in preparation of laser cooling experiments at the heavy-ion storage ring CSRe. The lifetimes of ion beams made up of 12C3+ and 16O4+ ions stored at an energy of 122 MeV/u in the CSRe were determined by two independent methods, firstly via a DC current transformer (DCCT) and secondly via a Schottky resonator. Using electron-cooling, the signals of the 12C3+ and 16O4+ ions could be separated and clearly observed in the Schottky spectrum. The obtained individual lifetimes of the 12C3+ and 16O4+ components were 23.6 s and 17.8 s, respectively. The proportion of 12C3+ ions in the stored ion beam was measured to be more than 70% at the beginning of the injection and increasing as a function of time. In addition to these measurements, the operation and remote control of a pulsed laser system placed directly next to the storage ring was tested in a setup similar to the one envisaged for future laser experiments.
Study of the storm time fluxes of heavy ions
NASA Technical Reports Server (NTRS)
1978-01-01
The characteristics of the storm time ring current ions in the energy range of 0.5 to 16 keV were investigated. Data were processed and analyzed from the energetic ion mass spectrometer aboard the S3-3 satellite. Results are used for planning and operating the ion mass spectrometer experiment on the ISEE spacecraft, for selecting and processing the ISEE ion data, and for planning and conducting coordinated satellite experiments in support of the International Magnetospheric Study (IMS). It is established from the S3-3 ion data that relatively large fluxes of energetic (keV) 0(+) and H(+) ions are frequently flowing upward from the ionosphere along magnetic field lines in the polar auroral regions. Also, from investigations with the same instrument during the main phase of three moderate (D sub ST approximately 100) magnetic storms, it is found that the number density of 0(+) ions in the ring current was comparable to H(+) ion density the range 0.5 to 15 keV.
Quéméner, Bernard; Désiré, Cédric; Debrauwer, Laurent; Rathahao, Estelle
2003-01-17
The off-line coupling of high-performance anion-exchange chromatography to electrospray ion trap mass spectrometry (ESI-IT-MS) is described. Two sets of isocratic conditions were optimised for the semi-preparative purification of oligogalacturonates of degree of polymerisation from 4 to 6 by monitoring eluates with either pulsed amperometric detection or evaporative light scattering detection in the presence of an online Dionex Carbohydrate Membrane Desalter (CMD). In these conditions, purified oligogalacturonate solutions were suitable, without further desalting steps, for infusion ESI-IT-MS experiments. This paper provides some interesting features of positive and negative ESI-IT-multiple MS (MSn) of these acidic oligosaccharides. The spectra acquired in both ion modes show characteristic fragments resulting from glycosidic bond and cross-ring cleavages. Under negative ionization conditions, the fragmentation of the singly-charged [M-H]- ions, as well as the Ci-, and Zi-, fragment ions through sequential MSn experiments, was always dominated by product ions from C- and Z-type glycosidic cleavages. All spectra also displayed 0.2 A-type cross-ring cleavage ions which carry linkage information. Collision-induced dissociation (CID) spectra of sodium-cationized species obtained under positive ionization conditions were more complex. Successive MSn experiments also led to the 0.2 A-type cross-ring cleavage ions observed together with B- and Y-type ions. The presence of the 0.2 A ion series was related to Mr 60 (C2H4O2) losses. Combined with the absence of the Mr 30 (CH2O) and the Mr 90 (C3H6O3) ions, these ions were indicative of 1-4 type glycosidic linkage.
Zhao, H.; Li, X.; Baker, D. N.; ...
2015-08-25
Enabled by the comprehensive measurements from the Magnetic Electron Ion Spectrometer (MagEIS), Helium Oxygen Proton Electron mass spectrometer (HOPE), and Radiation Belt Storm Probes Ion Composition Experiment (RBSPICE) instruments onboard Van Allen Probes in the heart of the radiation belt, the relative contributions of ions with different energies and species to the ring current energy density and their dependence on the phases of geomagnetic storms are quantified. The results show that lower energy (<50 keV) protons enhance much more often and also decay much faster than higher-energy protons. During the storm main phase, ions with energies <50 keV contribute moremore » significantly to the ring current than those with higher energies; while the higher-energy protons dominate during the recovery phase and quiet times. The enhancements of higher-energy proton fluxes as well as energy content generally occur later than those of lower energy protons, which could be due to the inward radial diffusion. For the 29 March 2013 storm we investigated in detail that the contribution from O + is ~25% of the ring current energy content during the main phase and the majority of that comes from <50 keV O +. This indicates that even during moderate geomagnetic storms the ionosphere is still an important contributor to the ring current ions. Using the Dessler-Parker-Sckopke relation, the contributions of ring current particles to the magnetic field depression during this geomagnetic storm are also calculated. In conclusion, the results show that the measured ring current ions contribute about half of the Dst depression.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Zhao, H.; Li, X.; Baker, D. N.
Enabled by the comprehensive measurements from the Magnetic Electron Ion Spectrometer (MagEIS), Helium Oxygen Proton Electron mass spectrometer (HOPE), and Radiation Belt Storm Probes Ion Composition Experiment (RBSPICE) instruments onboard Van Allen Probes in the heart of the radiation belt, the relative contributions of ions with different energies and species to the ring current energy density and their dependence on the phases of geomagnetic storms are quantified. The results show that lower energy (<50 keV) protons enhance much more often and also decay much faster than higher-energy protons. During the storm main phase, ions with energies <50 keV contribute moremore » significantly to the ring current than those with higher energies; while the higher-energy protons dominate during the recovery phase and quiet times. The enhancements of higher-energy proton fluxes as well as energy content generally occur later than those of lower energy protons, which could be due to the inward radial diffusion. For the 29 March 2013 storm we investigated in detail that the contribution from O + is ~25% of the ring current energy content during the main phase and the majority of that comes from <50 keV O +. This indicates that even during moderate geomagnetic storms the ionosphere is still an important contributor to the ring current ions. Using the Dessler-Parker-Sckopke relation, the contributions of ring current particles to the magnetic field depression during this geomagnetic storm are also calculated. In conclusion, the results show that the measured ring current ions contribute about half of the Dst depression.« less
NASA Astrophysics Data System (ADS)
Bondarevskaya, A.; Prozorov, A.; Labzowsky, L.; Plunien, G.; Liesen, D.; Bosch, F.
2011-10-01
Theoretical concepts for the production, preservation and control of polarized highly charged ion beams in storage rings are investigated. It is argued that hydrogen-like ions can be polarized efficiently by optical pumping of the Zeeman sublevels of ground state hyperfine levels and that the maximum achievable nuclear polarization exceeds 90%. In order to study the preservation of the polarization during the ion motion through the magnetic system of the ring, the concept of the instantaneous quantization axis is introduced. It is suggested that the employment of “Siberian snakes” may help to preserve the ion beam polarization in the ring. The control of the beam polarization can be achieved by different methods: by measuring the Stokes parameters for the emitted photons or by observing the angular dependence of the transition rates for polarized ions. The important motivation for the production of polarized ion beams is the possibility to observe parity nonconservation effects in the hyperfine-quenched transitions in helium-like highly charged ions, where these effects can reach an unprecedented high value for atomic physics. The possible observation of parity nonconservation effects connected with the nuclear anapole moment is also discussed. A method for the observation of the electric dipole moment of an electron in a storage ring with a polarized highly charged ion beam is proposed. This method allows, in principle, to improve the existing boundaries for the electric dipole moment of an electron. However, the requirements of the corresponding experiment are very stringent.
Storage rings, internal targets and PEP
DOE Office of Scientific and Technical Information (OSTI.GOV)
Spencer, J.E.
Storage rings with internal targets are described, using PEP as an example. The difference between electrons and heavier particles such as protons, antiprotons, and heavy ions is also discussed because it raises possibilities of bypass insertions for more exotic experiments. PEP is compared to other rings in various contexts to verify the assertion that it is an ideal ring for many fundamental and practical applications that can be carried on simultaneously. (LEW)
NASA Astrophysics Data System (ADS)
Zamora, J. C.; Aumann, T.; Bagchi, S.; Bönig, S.; Csatlós, M.; Dillmann, I.; Dimopoulou, C.; Egelhof, P.; Eremin, V.; Furuno, T.; Geissel, H.; Gernhäuser, R.; Harakeh, M. N.; Hartig, A.-L.; Ilieva, S.; Kalantar-Nayestanaki, N.; Kiselev, O.; Kollmus, H.; Kozhuharov, C.; Krasznahorkay, A.; Kröll, Th.; Kuilman, M.; Litvinov, S.; Litvinov, Yu. A.; Mahjour-Shafiei, M.; Mutterer, M.; Nagae, D.; Najafi, M. A.; Nociforo, C.; Nolden, F.; Popp, U.; Rigollet, C.; Roy, S.; Scheidenberger, C.; von Schmid, M.; Steck, M.; Streicher, B.; Stuhl, L.; Thürauf, M.; Uesaka, T.; Weick, H.; Winfield, J. S.; Winters, D.; Woods, P. J.; Yamaguchi, T.; Yue, K.; Zenihiro, J.
2017-09-01
A novel method for measuring nuclear reactions in inverse kinematics with stored ion beams was successfully used to extract the nuclear-matter radius of 58Ni. The experiment was performed at the experimental heavy-ion storage ring at the GSI facility using a stored 58Ni beam at energies of 100 and 150 MeV/u and an internal helium gas-jet target. Elastically scattered α -recoils at low momentum transfers were measured with an in-ring detector system compatible with ultrahigh vacuum. Experimental angular distributions were fitted using density-dependent optical model potentials within the eikonal approximation. This permitted the extraction of the point-matter root-mean-square radius of 58Ni with an average value of 3.70(7) fm. Results from this work are in good agreement with several experiments performed in the past in normal kinematics. This pioneering experiment demonstrates a major breakthrough towards future investigations with far-from-stability stored beams using the present technique.
ELISA - an electrostatic storage ring for low-energy ions
NASA Astrophysics Data System (ADS)
Pape Moeller, Soeren
1997-05-01
The design of a new type of storage ring for low-energy ions using electrostatic deflection and focusing devices is described. Electrostatic bends and quadrupoles are used since they are more efficient than magnetic ones for low-velocity heavy ions. Furthermore, electrostatic devices are more compact and easier to construct than magnetic devices. In comparison to an electromagnetic trap, one important advantage of the elecrostatic ring is the easy access to the circulating beam and its decay products. These and other features, e.g. no magnetic fields, makes such storage devices attractive for many atomic-physics experiments. Also neigboring fields as chemistry and biology might benefit from such an relatively inexpensive device. One important difference between an electrostatic and a magnetic ring is, that the longitudinal energy is not conserved for the electrostatic ring. The actual ring will have a race-track shape as defined by two straight sections each with two quadrupole doublets connected by 180-degrees bends. The bends will consist of 160-degrees spherical deflection plates surrounded by two parallel plate 10-degrees bends. The storage ring ELISA, currently being built, will have a circumference of 6 meters. The first beam tests will take place during summer 1996.
Decay of equatorial ring current ions and associated aeronomical consequences
NASA Technical Reports Server (NTRS)
Fok, M.-C.; Kozyra, J. U.; Nagy, A. F.; Rasmussen, C. E.; Khazanov, G. V.
1993-01-01
The decay of the major ion species which constitute the ring current is studied by solving the time evolution of their distribution functions during the recovery phase of a moderate geomagnetic storm. In this work, only equatorially mirroring particles are considered. Particles are assumed to move subject to E x B and gradient drifts. They also experience loses along their drift paths. Two loss mechanisms are considered: charge exchange with neutral hydrogen atoms and Coulomb collisions with thermal plasma in the plasmasphere. Thermal plasma densities are calculated with a plasmaspheric model employing a time-dependent convection electric field model. The drift-loss model successfully reproduces a number of important and observable features in the distribution function. Charge exchange is found to be the major loss mechanism for the ring current ions; however the important effects of Coulomb collisions on both the ring current and thermal populations are also presented. The model predicts the formation of a low-energy (less than 500 eV) ion population as a result of energy degradation caused by Coulomb collision of the ring current ions with the plasmaspheric electrons; this population may be one source of the low-energy ions observed during active and quiet periods in the inner magnetosphere. The energy transferred to plasmaspheric electrons through Coulomb collisions with ring current ions is believed to be the energy source for the electron temperature enhancement and the associated 6300 A (stable auroral red (SAR) arc) emission in the subauroral region. The calculated energy deposition rate is sufficient to produce a subauroral electron temperature enhancement and SAR arc emissions that are consistent with observations of these quantities during moderate magnetic activity levels.
Ring Current He Ion Control by Bounce Resonant ULF Waves
NASA Astrophysics Data System (ADS)
Kim, Hyomin; Gerrard, Andrew J.; Lanzerotti, Louis J.; Soto-Chavez, Rualdo; Cohen, Ross J.; Manweiler, Jerry W.
2017-12-01
Ring current energy He ion (˜65 keV to ˜520 keV) differential flux data from the Radiation Belt Storm Probe Ion Composition Experiment (RBSPICE) instrument aboard the Van Allan Probes spacecraft show considerable variability during quiet solar wind and geomagnetic time periods. Such variability is apparent from orbit to orbit (˜9 h) of the spacecraft and is observed to be ˜50-100% of the nominal flux. Using data from the Electric and Magnetic Field Instrument Suite and Integrated Science (EMFISIS) instrument, also aboard the Van Allen Probes spacecraft, we identify that a dominant source of this variability is from ULF waveforms with periods of tens of seconds. These periods correspond to the bounce resonant timescales of the ring current He ions being measured by RBSPICE. A statistical survey using the particle and field data for one full spacecraft precession period (approximately 2 years) shows that the wave and He ion flux variations are generally anticorrelated, suggesting the bounce resonant pitch angle scattering process as a major component in the scattering of He ions.
NASA Astrophysics Data System (ADS)
Steiger, J.; Beck, B. R.; Gruber, L.; Church, D. A.; Holder, J. P.; Schneider, D.
1999-01-01
Storage rings and Penning traps are being used to study ions in their highest charge states. Both devices must have the capability for ion cooling in order to perform high precision measurements such as mass spectrometry and laser spectroscopy. This is accomplished in storage rings in a merged beam arrangement where a cold electron beam moves at the speed of the ions. In RETRAP, a Penning trap located at Lawrence Livermore National Laboratory, a sympathetic laser/ion cooling scheme has been implemented. In a first step, singly charged beryllium ions are cooled electronically by a tuned circuit and optically by a laser. Then hot, highly charged ions are merged into the cold Be plasma. By collisions, their kinetic energy is reduced to the temperature of the Be plasma. First experiments indicate that the highly charged ions form a strongly coupled plasma with a Coulomb coupling parameter exceeding 1000.
A model for particle confinement in a toroidal plasma subject to strong radial electric fields
NASA Technical Reports Server (NTRS)
Roth, J. R.
1977-01-01
The approach adopted in the NASA Lewis Bumpy Torus experiment is to confine and heat a toroidal plasma by the simultaneous application of strong dc magnetic fields and electric fields. Strong radial electric fields (about 1 kV/cm) are imposed by biasing the plasma with up to 12 negative electrode rings which surround its minor circumference. The plasma containment is consistent with a balance of two processes: a radial infusion of ions in those sectors not containing electrode rings, resulting from the radially inward electric fields; and ion losses to the electrode rings, each of which acts as a sink and draws ions out the plasma in the manner of a Langmuir probe in the ion saturation regime. The highest density on axis which has been observed so far in this steady-state plasma is 6.2 trillion particles per cu cm, for which the particle containment time is 2.5 msec. The deuterium ion kinetic temperature for these conditions was in the range of 360 to 520 eV.
A Versatile Ion Injector at KACST
NASA Astrophysics Data System (ADS)
El Ghazaly, M. O. A.; Behery, S. A.; Almuqhim, A. A.; Papash, A. I.; Welsch, C. P.
2011-10-01
A versatile ion-beam injector is presently being constructed at the National Centre for Mathematics and Physics (NCMP) at the King Abdul-Aziz City for Science and Technology (KACST), Saudi Arabia. This versatile injector will provide an electrostatic storage ring with high-quality ion beams of energies up to 30 keV per charge q. It will also allow for crossed-beams experiments in single-pass setups. The injector has been designed to include beams from two different ion sources, switched by a 90° deflection setup, and to allow for matching of the beam parameters to the Twiss parameters of the ring. The injector is equipped with two crossed beam-lines (inlets), with duplicated beam extraction and acceleration systems. As part of the initial setup, a simple electric discharge ion source has been developed for commissioning of the whole injector. In this paper, we report on the ion optics layout and the design parameters of the injector.
Oxygen ions observed near Saturn's A ring.
Waite, J H; Cravens, T E; Ip, W-H; Kasprzak, W T; Luhmann, J G; McNutt, R L; Niemann, H B; Yelle, R V; Mueller-Wodarg, I; Ledvina, S A; Scherer, S
2005-02-25
Ions were detected in the vicinity of Saturn's A ring by the Ion and Neutral Mass Spectrometer (INMS) instrument onboard the Cassini Orbiter during the spacecraft's passage over the rings. The INMS saw signatures of molecular and atomic oxygen ions and of protons, thus demonstrating the existence of an ionosphere associated with the A ring. A likely explanation for these ions is photoionization by solar ultraviolet radiation of neutral O2 molecules associated with a tenuous ring atmosphere. INMS neutral measurements made during the ring encounter are dominated by a background signal.
NASA Astrophysics Data System (ADS)
He, X.
In the proposed Electron-Ion Collider (EIC) experiments, particle identification (PID) of the final state hadrons in the semi-inclusive deep inelastic scattering allows the measurement of flavor-dependent gluon and quark distributions inside nucleons and nuclei. The EIC PID consortium (eRD14 Collaboration) has been formed for identifying and developing PID detectors using Ring Imaging Cherenkov (RICH) techniques for the EIC experiments. A modular Ring Imaging Cherenkov (mRICH) detector has been designed for particle identification in the momentum coverage from 3 GeV/c to 10 GeV/c. The mRICH detector consists of an aerogel radiator block, a Fresnel lens, a mirror-wall and a photosensor plane. The first prototype of this detector was successfully tested at Fermi National Accelerator Laboratory in April 2016 for verifying the detector working principles. This talk will highlight the mRICH beam test results and their comparison with GEANT4-based detector simulations. An implementation of the mRICH detector concept in the Forward Angle sPHENIX spectrometer at BNL will also be mentioned in this talk.
Impact parameter sensitive study of inner-shell atomic processes in the experimental storage ring
NASA Astrophysics Data System (ADS)
Gumberidze, A.; Kozhuharov, C.; Zhang, R. T.; Trotsenko, S.; Kozhedub, Y. S.; DuBois, R. D.; Beyer, H. F.; Blumenhagen, K.-H.; Brandau, C.; Bräuning-Demian, A.; Chen, W.; Forstner, O.; Gao, B.; Gassner, T.; Grisenti, R. E.; Hagmann, S.; Hillenbrand, P.-M.; Indelicato, P.; Kumar, A.; Lestinsky, M.; Litvinov, Yu. A.; Petridis, N.; Schury, D.; Spillmann, U.; Trageser, C.; Trassinelli, M.; Tu, X.; Stöhlker, Th.
2017-10-01
In this work, we present a pilot experiment in the experimental storage ring (ESR) at GSI devoted to impact parameter sensitive studies of inner shell atomic processes for low-energy (heavy-) ion-atom collisions. The experiment was performed with bare and He-like xenon ions (Xe54+, Xe52+) colliding with neutral xenon gas atoms, resulting in a symmetric collision system. This choice of the projectile charge states was made in order to compare the effect of a filled K-shell with the empty one. The projectile and target X-rays have been measured at different observation angles for all impact parameters as well as for the impact parameter range of ∼35-70 fm.
NASA Astrophysics Data System (ADS)
Herdrich, M. O.; Weber, G.; Gumberidze, A.; Wu, Z. W.; Stöhlker, Th.
2017-10-01
In experiments with highly charged, fast heavy ions the Radiative Recombination (RR) and Radiative Electron Capture (REC) processes have significant cross sections in an energy range of up to a few GeV / u . They are some of the most important charge changing processes in collisions of heavy ions with atoms and electrons, leading to the emission of a photon along with the formation of the ground and excited atomic states. Hence, for the understanding and planning of experiments, in particular for X-ray spectroscopy studies, at accelerator ring facilities, such as FAIR, it is crucial to have a good knowledge of these cross sections and the associated radiation characteristics. In the frame of this work a fast calculator, named RECAL, for the RR and REC process is presented and its capabilities are demonstrated with the analysis of a recently conducted experiment at the Experimental Storage Ring (ESR) at the GSI Helmholtz Center for Heavy Ion Research in Darmstadt, Germany. A method is presented to determine unknown X-ray emission cross sections via normalization of the recorded spectra to REC cross sections calculated by RECAL.
Fluorescence decay of naphthalene studied in an electrostatic storage ring, the Mini-Ring
NASA Astrophysics Data System (ADS)
Martin, S.; Matsumoto, J.; Kono, N.; Ji, M.-C.; Brédy, R.; Bernard, J.; Cassimi, A.; Chen, L.
2017-10-01
The cooling of naphthalene cations (C10H8)+ has been studied in a compact electrostatic ion storage ring, the Mini-Ring. A nano second laser pulse of 532 nm (2.33 eV) was used to probe the internal energy distribution every millisecond during the storage time up to 5 ms. The evolution of the internal energy distribution of the stored ions was simulated with a model taking into account the dissociation and the radiative decay processes. Calculated decay curves were fitted to the corresponding laser induced neutral decays. For a laser power of 200 μJ/pulse, a good agreement between experiment and modeling was found using an initial Gaussian energy distribution centered to 5.9 eV and a fluorescence decay rate varying from 200 to 300 s-1 in the energy range from 6 to 7 eV. This fast decay was attributed to the delayed Poincaré fluorescence process.
Stability of an ion-ring distribution in a multi-ion component plasma
NASA Astrophysics Data System (ADS)
Mithaiwala, Manish; Rudakov, Leonid; Ganguli, Gurudas
2010-04-01
The stability of a cold ion-ring velocity distribution in a thermal plasma is analyzed. In particular, the effect of plasma temperature and density on the instability is considered. A high ring density (compared to the background plasma) neutralizes the stabilizing effect of the warm background plasma and the ring is unstable to the generation of waves below the lower-hybrid frequency even for a very high temperature plasma. For ring densities lower than the background plasma density, there is a slow instability where the growth rate is less than the background-ion cyclotron frequency and, consequently, the background-ion response is magnetized. This is in addition to the widely discussed fast instability where the wave growth rate exceeds the background-ion cyclotron frequency and hence the background ions are effectively unmagnetized. Thus, even a low density ring is unstable to waves around the lower-hybrid frequency range for any ring speed. This implies that effectively there is no velocity threshold for a sufficiently cold ring.
NASA Astrophysics Data System (ADS)
Ganguli, G.; Crabtree, C. E.; Rudakov, L.; Mithaiwala, M.
2014-12-01
Velocity ring instabilities are a common naturally occuring magnetospheric phenomenon that can also be generated by man made ionospheric experiments. These instabilities are known to generate lower-hybrid waves, which generally cannot propagte out of the source region. However, nonlinear wave physics can convert these linearly driven electrostatic lower-hybrid waves into electromagnetic waves that can escape the source region. These nonlinearly generated waves can be an important source of VLF turbulence that controls the trapped electron lifetime in the radiation belts. We develop numerical solutions to the wave-kinetic equation in a periodic box including the effects of nonlinear (NL) scattering (nonlinear Landau damping) of Lower-hybrid waves giving the evolution of the wave-spectra in wavenumber space. Simultaneously we solve the particle diffusion equation of both the background plasma particles and the ring ions, due to both linear and nonlinear Landau resonances. At initial times for cold ring ions, an electrostatic beam mode is excited, while the kinetic mode is stable. As the instability progresses the ring ions heat, the beam mode is stabilized, and the kinetic mode destabilizes. When the amplitude of the waves becomes sufficient the lower-hybrid waves are scattered (by either nearly unmagnetized ions or magnetized electrons) into electromagnetic magnetosonic waves [Ganguli et al 2010]. The effect of NL scattering is to limit the amplitude of the waves, slowing down the quasilinear relaxation time and ultimately allowing more energy from the ring to be liberated into waves [Mithaiwala et al. 2011]. The effects of convection out of the instability region are modeled, additionally limiting the amplitude of the waves, allowing further energy to be liberated from the ring [Scales et al., 2012]. Results are compared to recent 3D PIC simulations [Winske and Duaghton 2012].
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cornejo, J. M.; Colombano, M.; Doménech, J.
A special ion trap was initially built up to perform β-ν correlation experiments with radioactive ions. The trap geometry is also well suited to perform experiments with laser-cooled ions, serving for the development of a new type of Penning trap, in the framework of the project TRAPSENSOR at the University of Granada. The goal of this project is to use a single {sup 40}Ca{sup +} ion as detector for single-ion mass spectrometry. Within this project and without any modification to the initial electrode configuration, it was possible to perform Doppler cooling on {sup 40}Ca{sup +} ions, starting from large cloudsmore » and reaching single ion sensitivity. This new feature of the trap might be important also for other experiments with ions produced at radioactive ion beam facilities. In this publication, the trap and the laser system will be described, together with their performance with respect to laser cooling applied to large ion clouds down to a single ion.« less
Determination of ion mobility in EHD flow zone of plasma generator
NASA Astrophysics Data System (ADS)
Sumariyah, Kusminarto, Hermanto, Arief; Nuswantoro, Pekik
2015-12-01
Determination has been carried out for ion mobility in EHD flow zone generated using a pin-concentric multiple ring electrodes and a pin-single ring electrode used as a comparator. The pin needle was made from stainless steel with a tip diameter of 0.18 mm. The concentris multiple ring electrode in form three/two concentric ring electrodes which made of metal material connected to each other. Each ring of three concentric ring electrode has a diameter of 24 mm, 16 mm and 8 mm. And each ring of two concentric ring electrode has a diameter of 24 mm and 16 mm. Single ring electrode has a diameter24 mm. The all ring has same of width and thickness were 2 mm and 3 mm. EHD was generated by using a DC high voltage of 10 kV. Pin functional as an active electrode of corona discharge while the all ring electrodes acted as ions collector and passive electrodes. The experimental results show that the ion current is proportional to V2 according to calculations by Chouelo for hyperbolic-field approach. Ion mobility obtained from the quadratic polynomial fitting of experimental data were current and voltage as well as Choelo formulation. The results showed that the mobility of ions in the EHD flow zones utilizing pin-consentric multiple ring electrode larger than utilizing pin-single ring electrode. Pin-three Consentic ring electrode has the largest of ion mobility
Experimental and analytical investigation of a modified ring cusp NSTAR engine
NASA Technical Reports Server (NTRS)
Sengupta, Anita
2005-01-01
A series of experimental measurements on a modified laboratory NSTAR engine were used to validate a zero dimensional analytical discharge performance model of a ring cusp ion thruster. The model predicts the discharge performance of a ring cusp NSTAR thruster as a function the magnetic field configuration, thruster geometry, and throttle level. Analytical formalisms for electron and ion confinement are used to predict the ionization efficiency for a given thruster design. Explicit determination of discharge loss and volume averaged plasma parameters are also obtained. The model was used to predict the performance of the nominal and modified three and four ring cusp 30-cm ion thruster configurations operating at the full power (2.3 kW) NSTAR throttle level. Experimental measurements of the modified engine configuration discharge loss compare well with the predicted value for propellant utilizations from 80 to 95%. The theory, as validated by experiment, indicates that increasing the magnetic strength of the minimum closed reduces maxwellian electron diffusion and electrostatically confines the ion population and subsequent loss to the anode wall. The theory also indicates that increasing the cusp strength and minimizing the cusp area improves primary electron confinement increasing the probability of an ionization collision prior to loss at the cusp.
Acceleration of polarized protons and deuterons in the ion collider ring of JLEIC
NASA Astrophysics Data System (ADS)
Kondratenko, A. M.; Kondratenko, M. A.; Filatov, Yu N.; Derbenev, Ya S.; Lin, F.; Morozov, V. S.; Zhang, Y.
2017-07-01
The figure-8-shaped ion collider ring of Jefferson Lab Electron-Ion Collider (JLEIC) is transparent to the spin. It allows one to preserve proton and deuteron polarizations using weak stabilizing solenoids when accelerating the beam up to 100 GeV/c. When the stabilizing solenoids are introduced into the collider’s lattice, the particle spins precess about a spin field, which consists of the field induced by the stabilizing solenoids and the zero-integer spin resonance strength. During acceleration of the beam, the induced spin field is maintained constant while the resonance strength experiences significant changes in the regions of “interference peaks”. The beam polarization depends on the field ramp rate of the arc magnets. Its component along the spin field is preserved if acceleration is adiabatic. We present the results of our theoretical analysis and numerical modeling of the spin dynamics during acceleration of protons and deuterons in the JLEIC ion collider ring. We demonstrate high stability of the deuteron polarization in figure-8 accelerators. We analyze a change in the beam polarization when crossing the transition energy.
Acceleration of polarized protons and deuterons in the ion collider ring of JLEIC
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kondratenko, A.; Kondratenko, M.; Filatov, Yu. N.
2017-07-01
The figure-8-shaped ion collider ring of Jefferson Lab Electron-Ion Collider (JLEIC) is transparent to the spin. It allows one to preserve proton and deuteron polarizations using weak stabilizing solenoids when accelerating the beam up to 100 GeV/c. When the stabilizing solenoids are introduced into the collider's lattice, the particle spins precess about a spin field, which consists of the field induced by the stabilizing solenoids and the zero-integer spin resonance strength. During acceleration of the beam, the induced spin field is maintained constant while the resonance strength experiences significant changes in the regions of "interference peaks". The beam polarization dependsmore » on the field ramp rate of the arc magnets. Its component along the spin field is preserved if acceleration is adiabatic. We present the results of our theoretical analysis and numerical modeling of the spin dynamics during acceleration of protons and deuterons in the JLEIC ion collider ring. We demonstrate high stability of the deuteron polarization in figure-8 accelerators. We analyze a change in the beam polarization when crossing the transition energy.« less
Ring current dynamics and plasma sheet sources. [magnetic storms
NASA Technical Reports Server (NTRS)
Lyons, L. R.
1984-01-01
The source of the energized plasma that forms in geomagnetic storm ring currents, and ring current decay are discussed. The dominant loss processes for ring current ions are identified as charge exchange and resonant interactions with ion-cyclotron waves. Ring current ions are not dominated by protons. At L4 and energies below a few tens of keV, O+ is the most abundant ion, He+ is second, and protons are third. The plasma sheet contributes directly or indirectly to the ring current particle population. An important source of plasma sheet ions is earthward streaming ions on the outer boundary of the plasma sheet. Ion interactions with the current across the geomagnetic tail can account for the formation of this boundary layer. Electron interactions with the current sheet are possibly an important source of plasma sheet electrons.
Theoretical study of the bonding of the first-row transition-metal positive ions to ethylene
NASA Technical Reports Server (NTRS)
Sodupe, M.; Bauschlicher, Charles W., Jr.; Langhoff, Stephen R.; Partridge, Harry
1992-01-01
Ab initio calculations were performed to study the bonding of the first-row transition-metal ions with ethylene. While Sc(+) and Ti(+) insert into the pi bond of ethylene to form a three-membered ring, the ions V(+) through Cu(+) form an electrostatic complex with ethylene. The binding energies are compared with those from experiment and with those of comparable calculations performed previously for the metal-acetylene ion systems.
Does Saturn have rings outside 10 R(s)?
NASA Technical Reports Server (NTRS)
Cheng, A. F.; Lanzerotti, L. J.; Maclennan, C. G.
1985-01-01
Voyager ion and electron data in the energy range 30-1000 keV as measured by the Low Energy Charged Particle experiment are reviewed to check suggestions based on star occultation data that there are additional tenuous rings of Saturn beyond 10 Saturn radii from that planet. In the Voyager data, there is no convincing evidence for such ring matter. Features in the charged particle fluxes in the regions in question are more readily explained by temporal variations and/or spatial structure unrelated to ring matter, such as the mantle on the dayside and/or detached plasma sheets.
NASA Technical Reports Server (NTRS)
Khazanov, G. V.; Gamayunov, K. V.; Jordanova, V. K.; Krivorutsky, E. N.
2002-01-01
Initial results from a newly developed model of the interacting ring current ions and ion cyclotron waves are presented. The model is based on the system of two kinetic equations: one equation describes the ring current ion dynamics, and another equation describes wave evolution. The system gives a self-consistent description of the ring current ions and ion cyclotron waves in a quasilinear approach. These equations for the ion phase space distribution function and for the wave power spectral density were solved on aglobal magnetospheric scale undernonsteady state conditions during the 2-5 May 1998 storm. The structure and dynamics of the ring current proton precipitating flux regions and the ion cyclotron wave-active zones during extreme geomagnetic disturbances on 4 May 1998 are presented and discussed in detail.
Ion Selectivity Mechanism in a Bacterial Pentameric Ligand-Gated Ion Channel
DOE Office of Scientific and Technical Information (OSTI.GOV)
Fritsch, Sebastian M; Ivanov, Ivaylo N; Wang, Hailong
2011-01-01
The proton-gated ion channel from Gloeobacter violaceus (GLIC) is a prokaryotic homolog of the eukaryotic nicotinic acetylcholine receptor (nAChR) that responds to the binding of neurotransmitter acetylcholine and mediates fast signal transmission. Recent emergence of a high resolution crystal structure of GLIC captured in a potentially open state allowed detailed, atomic-level insight into ion conduction and selectivity mechanisms in these channels. Herein, we have examined the barriers to ion conduction and origins of ion selectivity in the GLIC channel by the construction of potential of mean force (PMF) profiles for sodium and chloride ions inside the transmembrane region. Our calculationsmore » reveal that the GLIC channel is open for a sodium ion to transport, but presents a ~10 kcal/mol free energy barrier for a chloride ion, which arises primarily from the unfavorable interactions with a ring of negatively charged glutamate residues (E-2 ) at the intracellular end and a ring of hydrophobic residues (I9 ) in the middle of the transmembrane domain. Our collective findings further suggest that the charge selection mechanism can, to a large extent, be attributed to the narrow intracellular end and a ring of glutamate residues in this position their strong negative electrostatics and ability to bind cations. By contrast, E19 at the extracellular entrance only plays a minor role in ion selectivity of GLIC. In addition to electrostatics, both ion hydration and protein dynamics are found to be crucial for ion conduction as well, which explains why a chloride ion experiences a much greater barrier than a sodium ion in the hydrophobic region of the pore.« less
The KACST Heavy-Ion Electrostatic Storage Ring
NASA Astrophysics Data System (ADS)
Almuqhim, A. A.; Alshammari, S. M.; El Ghazaly, M. O. A.; Papash, A. I.; Welsch, C. P.
2011-10-01
A novel Electrostatic Storage Ring (ESR) for beams at energies up to 30keV/q is now being constructed at the National Centre for Mathematics and Physics (NCMP), King Abdul-Aziz City for Science and Technology (KACST). The ring is designed to be the core of a highly flexible experimental platform that will combine a large package of complementary beam techniques for atomic and molecular physics and related fields. The lattice design had to cover the different experimental techniques that the ring will be equipped with, such as e.g. Electron-Ion, Laser-Ion, Ion-Ion or Ion-Neutral beams, in both crossed and merged-beam configurations. The development of such an ESR is realized in a staged approach, in which a simple and early-run adaptation of the ring is built first, and then this basic version is upgraded to a higher symmetry of the ultimate version of the ring. Here, we report a general overview of this technical development with a focus on the layout of the first built stage of the ring.
Error Correction for the JLEIC Ion Collider Ring
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wei, Guohui; Morozov, Vasiliy; Lin, Fanglei
2016-05-01
The sensitivity to misalignment, magnet strength error, and BPM noise is investigated in order to specify design tolerances for the ion collider ring of the Jefferson Lab Electron Ion Collider (JLEIC) project. Those errors, including horizontal, vertical, longitudinal displacement, roll error in transverse plane, strength error of main magnets (dipole, quadrupole, and sextupole), BPM noise, and strength jitter of correctors, cause closed orbit distortion, tune change, beta-beat, coupling, chromaticity problem, etc. These problems generally reduce the dynamic aperture at the Interaction Point (IP). According to real commissioning experiences in other machines, closed orbit correction, tune matching, beta-beat correction, decoupling, andmore » chromaticity correction have been done in the study. Finally, we find that the dynamic aperture at the IP is restored. This paper describes that work.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Stamate, Eugen, E-mail: eust@dtu.dk; Venture Business Laboratory, Nagoya University, C3-1, Chikusa-ku, Nagoya 464-8603; Yamaguchi, Masahito
2015-08-31
Modal and discrete focusing effects associated with three-dimensional plasma-sheath-lenses show promising potential for applications in ion beam extraction, mass spectrometry, plasma diagnostics and for basic studies of plasma sheath. The ion focusing properties can be adjusted by controlling the geometrical structure of the plasma-sheath-lens and plasma parameters. The positive and negative ion kinetics within the plasma-sheath-lens are investigated both experimentally and theoretically and a modal focusing ring is identified on the surface of disk electrodes. The focusing ring is very sensitive to the sheath thickness and can be used to monitor very small changes in plasma parameters. Three dimensional simulationsmore » are found to be in very good agreement with experiments.« less
Gerrard, Andrew; Lanzerotti, Louis; Gkioulidou, Matina; Mitchell, Donald; Manweiler, Jerry; Bortnik, Jacob; Keika, Kunihiro
2014-01-01
H-ion (∼45 keV to ∼600 keV), He-ion (∼65 keV to ∼520 keV), and O-ion (∼140 keV to ∼1130 keV) integral flux measurements, from the Radiation Belt Storm Probe Ion Composition Experiment (RBSPICE) instrument aboard the Van Allan Probes spacecraft B, are reported. These abundance data form a cohesive picture of ring current ions during the first 9 months of measurements. Furthermore, the data presented herein are used to show injection characteristics via the He-ion/H-ion abundance ratio and the O-ion/H-ion abundance ratio. Of unique interest to ring current dynamics are the spatial-temporal decay characteristics of the two injected populations. We observe that He-ions decay more quickly at lower L shells, on the order of ∼0.8 day at L shells of 3–4, and decay more slowly with higher L shell, on the order of ∼1.7 days at L shells of 5–6. Conversely, O-ions decay very rapidly (∼1.5 h) across all L shells. The He-ion decay time are consistent with previously measured and calculated lifetimes associated with charge exchange. The O-ion decay time is much faster than predicted and is attributed to the inclusion of higher-energy (> 500 keV) O-ions in our decay rate estimation. We note that these measurements demonstrate a compelling need for calculation of high-energy O-ion loss rates, which have not been adequately studied in the literature to date. Key Points We report initial observations of ring current ions We show that He-ion decay rates are consistent with theory We show that O-ions with energies greater than 500 keV decay very rapidly PMID:26167435
Capture, acceleration and bunching rf systems for the MEIC booster and storage rings
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wang, Shaoheng; Guo, Jiquan; Lin, Fanglei
2015-09-01
The Medium-energy Electron Ion Collider (MEIC), proposed by Jefferson Lab, consists of a series of accelerators. The electron collider ring accepts electrons from CEBAF at energies from 3 to 12 GeV. Protons and ions are delivered to a booster and captured in a long bunch before being ramped and transferred to the ion collider ring. The ion collider ring accelerates a small number of long ion bunches to colliding energy before they are re-bunched into a high frequency train of very short bunches for colliding. Two sets of low frequency RF systems are needed for the long ion bunch energymore » ramping in the booster and ion collider ring. Another two sets of high frequency RF cavities are needed for re-bunching in the ion collider ring and compensating synchrotron radiation energy loss in the electron collider ring. The requirements from energy ramping, ion beam bunching, electron beam energy compensation, collective effects, beam loading and feedback capability, RF power capability, etc. are presented. The preliminary designs of these RF systems are presented. Concepts for the baseline cavity and RF station configurations are described, as well as some options that may allow more flexible injection and acceleration schemes.« less
NASA Technical Reports Server (NTRS)
Khazanov, G. V.; Gamayunov, K. V.; Jordanova, V. K.; Krivorutsky, E. N.; Whitaker, Ann F. (Technical Monitor)
2001-01-01
Initial results from the new developed model of the interacting ring current ions and ion cyclotron waves are presented. The model described by the system of two bound kinetic equations: one equation describes the ring current ion dynamics, and another one gives wave evolution. Such system gives a self-consistent description of the ring current ions and ion cyclotron waves in a quasilinear approach. Calculating ion-wave relationships, on a global scale under non steady-state conditions during May 2-5, 1998 storm, we presented the data at three time cuts around initial, main, and late recovery phases of May 4, 1998 storm phase. The structure and dynamics of the ring current proton precipitating flux regions and the wave active ones are discussed in detail.
Energy and Mass Transport of Magnetospheric Plasmas during the November 2003 Magnetic Storm
NASA Technical Reports Server (NTRS)
Fok, Mei-Chging; Moore, Thomas
2008-01-01
Intensive energy and mass transport from the solar wind across the magnetosphere boundary is a trigger of magnetic storms. The storm on 20-21 November 2003 was elicited by a high-speed solar wind and strong southward component of interplanetary magnetic field. This storm attained a minimum Dst of -422 nT. During the storm, some of the solar wind particles enter the magnetosphere and eventually become part of the ring current. At the same time, the fierce solar wind powers strong outflow of H+ and O+ from the ionosphere, as well as from the plasmasphere. We examine the contribution of plasmas from the solar wind, ionosphere and plasmasphere to the storm-time ring current. Our simulation shows, for this particular storm, ionospheric O+ and solar wind ions are the major sources of the ring current particles. The polar wind and plasmaspheric H+ have only minor impacts. In the storm main phase, the strong penetration of solar wind electric field pushes ions from the geosynchronous orbit to L shells of 2 and below. Ring current is greatly intensified during the earthward transport and produces a large magnetic depression in the surface field. When the convection subsides, the deep penetrating ions experience strong charge exchange loss, causing rapid decay of the ring current and fast initial storm recovery. Our simulation reproduces very well the storm development indicated by the Dst index.
High-energy accelerator for beams of heavy ions
Martin, Ronald L.; Arnold, Richard C.
1978-01-01
An apparatus for accelerating heavy ions to high energies and directing the accelerated ions at a target comprises a source of singly ionized heavy ions of an element or compound of greater than 100 atomic mass units, means for accelerating the heavy ions, a storage ring for accumulating the accelerated heavy ions and switching means for switching the heavy ions from the storage ring to strike a target substantially simultaneously from a plurality of directions. In a particular embodiment the heavy ion that is accelerated is singly ionized hydrogen iodide. After acceleration, if the beam is of molecular ions, the ions are dissociated to leave an accelerated singly ionized atomic ion in a beam. Extraction of the beam may be accomplished by stripping all the electrons from the atomic ion to switch the beam from the storage ring by bending it in magnetic field of the storage ring.
A Self-Consistent Model of the Interacting Ring Current Ions with Electromagnetic ICWs
NASA Technical Reports Server (NTRS)
Khazanov, G. V.; Gamayunov, K. V.; Jordanova, V. K.; Krivorutsky, E. N.; Whitaker, Ann F. (Technical Monitor)
2001-01-01
Initial results from a newly developed model of the interacting ring current ions and ion cyclotron waves are presented. The model is based on the system of two bound kinetic equations: one equation describes the ring current ion dynamics, and another equation describes wave evolution. The system gives a self-consistent description of ring current ions and ion cyclotron waves in a quasilinear approach. These two equations were solved on a global scale under non steady-state conditions during the May 2-5, 1998 storm. The structure and dynamics of the ring current proton precipitating flux regions and the wave active zones at three time cuts around initial, main, and late recovery phases of the May 4, 1998 storm phase are presented and discussed in detail. Comparisons of the model wave-ion data with the Polar/HYDRA and Polar/MFE instruments results are presented..
Investigation of the heavy-ion mode in the FAIR High Energy Storage Ring
NASA Astrophysics Data System (ADS)
Kovalenko, O.; Dolinskii, O.; Litvinov, Yu A.; Maier, R.; Prasuhn, D.; Stöhlker, T.
2015-11-01
High energy storage ring (HESR) as a part of the future accelerator facility FAIR (Facility for Antiproton and Ion Research) will serve for a variety of internal target experiments with high-energy stored heavy ions (SPARC collaboration). Bare uranium is planned to be used as a primary beam. Since a storage time in some cases may be significant—up to half an hour—it is important to examine the high-order effects in the long-term beam dynamics. A new ion optics specifically for the heavy ion mode of the HESR is developed and is discussed in this paper. The subjects of an optics design, tune working point and a dynamic aperture are addressed. For that purpose nonlinear beam dynamics simulations are carried out. Also a flexibility of the HESR ion optical lattice is verified with regard to various experimental setups. Specifically, due to charge exchange reactions in the internal target, secondary beams, such as hydrogen-like and helium-like uranium ions, will be produced. Thus the possibility of separation of these secondary ions and the primary {{{U}}}92+ beam is presented with different internal target locations.
The KACST Heavy-Ion Electrostatic Storage Ring
DOE Office of Scientific and Technical Information (OSTI.GOV)
Almuqhim, A. A.; Alshammari, S. M.; El Ghazaly, M. O. A.
2011-10-27
A novel Electrostatic Storage Ring (ESR) for beams at energies up to 30keV/q is now being constructed at the National Centre for Mathematics and Physics (NCMP), King Abdul-Aziz City for Science and Technology (KACST). The ring is designed to be the core of a highly flexible experimental platform that will combine a large package of complementary beam techniques for atomic and molecular physics and related fields. The lattice design had to cover the different experimental techniques that the ring will be equipped with, such as e.g. Electron-Ion, Laser-Ion, Ion-Ion or Ion-Neutral beams, in both crossed and merged-beam configurations. The developmentmore » of such an ESR is realized in a staged approach, in which a simple and early-run adaptation of the ring is built first, and then this basic version is upgraded to a higher symmetry of the ultimate version of the ring. Here, we report a general overview of this technical development with a focus on the layout of the first built stage of the ring.« less
NASA Astrophysics Data System (ADS)
LLera, K.; Goldstein, J.; McComas, D. J.; Valek, P. W.
2016-12-01
The two major loss processes for ring current decay are precipitation and energetic neutral atoms (ENAs). Since the exospheric neutral density increases with decreasing altitudes, precipitating ring current ions (reaching down to 200 - 800 km in altitude) also produce low-altitude ENA signatures that can be stronger than the ring current emission at equatorial distances ( 2 - 9 Re). The higher density results in multiple collisions between the ring current ions and exospheric oxygen. The affect on hydrogen ions is the focus of this study. Since the H particle sustains energy loss ( 36 eV) at each neutralizing or re-ionizing interaction, the escaped ENAs do not directly reflect the ring current properties. We model the energy loss due to multiple charge exchange and electron stripping interactions of 1 - 100 keV precipitating ring current ions undergo before emerging as low-altitude ENAs. The H particle is either an ion or an ENA throughout the simulation. Their lifetime is analytically determined by the length of one mean free path. We track the ion state with Lorentz motion while the ENA travels ballistically across the geomagnetic field. Our simulations show the energy loss is greater than 20% for hydrogen ring current ions below 30 keV (60 keV for the simulations that wander equatorward). This is the first quantification of the energy loss associated with the creation of low-altitude ENAs. Our model (currently constrained in the meridional plane) has revealed characteristics on how precipitation is affected by the near-Earth neutral exosphere. This ion-neutral interaction removes particles from the loss cone but promotes loss through ENA generation. These findings should be implemented in models predicting the ring current decay and used as an analysis tool to reconstruct the ring current population from observed low-altitude ENAs.
NASA Astrophysics Data System (ADS)
Bryzgunov, M. I.; Kamerdzhiev, V.; Li, J.; Mao, L. J.; Parkhomchuk, V. V.; Reva, V. B.; Yang, X. D.; Zhao, H.
2017-07-01
Electron cooling is used for damping both transverse and longitudinal oscillations of heavy particle. The cooling of bunch ion beam (with RF voltage on) is important part of experiments with inner target, ion collision system, stacking and RF manipulation. The short length of an ion bunch increases the peak luminosity, gives a start-time point for using of the time-of-flight methods and obtains a short extraction beam pulse. This article describes the review of last experiments with electron cooling carried out on the CSRm, CSRe (China) and COSY (Germany) storage rings. The accumulated experience may be used for the project of electron cooler on 2.5 MeV (NICA) and 0.5 MeV HIAF for obtaining high luminosity, depressing beam-beam effects and RF manipulation.
RF System Requirements for a Medium-Energy Electron-Ion Collider (MEIC) at JLab
DOE Office of Scientific and Technical Information (OSTI.GOV)
Rimmer, Robert A; Hannon, Fay E; Guo, Jiquan
2015-09-01
JLab is studying options for a medium energy electron-ion collider that could fit on the JLab site and use CEBAF as a full-energy electron injector. A new ion source, linac and booster would be required, together with collider storage rings for the ions and electrons. In order to achieve the maximum luminosity these will be high-current storage rings with many bunches. We present the high-level RF system requirements for the storage rings, ion booster ring and high-energy ion beam cooling system, and describe the technology options under consideration to meet them. We also present options for staging that might reducemore » the initial capital cost while providing a smooth upgrade path to a higher final energy. The technologies under consideration may also be useful for other proposed storage ring colliders or ultimate light sources.« less
HITRAP: A Facility for Experiments with Trapped Highly Charged Ions
NASA Astrophysics Data System (ADS)
Quint, W.; Dilling, J.; Djekic, S.; Häffner, H.; Hermanspahn, N.; Kluge, H.-J.; Marx, G.; Moore, R.; Rodriguez, D.; Schönfelder, J.; Sikler, G.; Valenzuela, T.; Verdú, J.; Weber, C.; Werth, G.
2001-01-01
HITRAP is a planned ion trap facility for capturing and cooling of highly charged ions produced at GSI in the heavy-ion complex of the UNILAC-SIS accelerators and the ESR storage ring. In this facility heavy highly charged ions up to uranium will be available as bare nuclei, hydrogen-like ions or few-electron systems at low temperatures. The trap for receiving and studying these ions is designed for operation at extremely high vacuum by cooling to cryogenic temperatures. The stored highly charged ions can be investigated in the trap itself or can be extracted from the trap at energies up to about 10 keV/q. The proposed physics experiments are collision studies with highly charged ions at well-defined low energies (eV/u), high-accuracy measurements to determine the g-factor of the electron bound in a hydrogen-like heavy ion and the atomic binding energies of few-electron systems, laser spectroscopy of HFS transitions and X-ray spectroscopy.
Effective Ion Heating in Guide Field Reconnection
NASA Astrophysics Data System (ADS)
Guo, Xuehan; Horiuchi, Ritoku; Usami, Shunsuke; Ono, Yasushi
2017-10-01
The energy conversion mechanism for ion perpendicular thermal energy is investigated by means of two-dimensional, full particle simulations in an open system. It is shown that ions gain kinetic energy due to the plasma potential drop, which is caused by the charge separation in the one pair of separatrix arms. Based on the force balance in the inflow direction, the strength of the normalized charge density can be expressed by electron Alfvén velocity, which is measurable value in the laboratory experiment and/or satellite observation. Meanwhile, we found that the accelerated ions form a ring shape like distribution in f(v1 ,v2) , as a result, the ion perpendicular temperature Ti , perp increases from inflow region. Here, both v1 and v2 are perpendicular to the magnetic field and v2 is parallel to the in-plane. The mixing of particle populations is verified by means of tracing ions and it is shown three typical particle orbits and each orbit has different entry angle to the potential drop. This ring shape like distribution consists three different population due to the difference of the entry angles to the potential drop. This mixing process will thermalize ions and produce entropy without collisions.
Dianion diagnostics in DESIREE: High-sensitivity detection of Cn2 - from a sputter ion source
NASA Astrophysics Data System (ADS)
Chartkunchand, K. C.; Stockett, M. H.; Anderson, E. K.; Eklund, G.; Kristiansson, M. K.; Kamińska, M.; de Ruette, N.; Blom, M.; Björkhage, M.; Källberg, A.; Löfgren, P.; Reinhed, P.; Rosén, S.; Simonsson, A.; Zettergren, H.; Schmidt, H. T.; Cederquist, H.
2018-03-01
A sputter ion source with a solid graphite target has been used to produce dianions with a focus on carbon cluster dianions, Cn2 -, with n = 7-24. Singly and doubly charged anions from the source were accelerated together to kinetic energies of 10 keV per atomic unit of charge and injected into one of the cryogenic (13 K) ion-beam storage rings of the Double ElectroStatic Ion Ring Experiment facility at Stockholm University. Spontaneous decay of internally hot Cn2 - dianions injected into the ring yielded Cn- anions with kinetic energies of 20 keV, which were counted with a microchannel plate detector. Mass spectra produced by scanning the magnetic field of a 90° analyzing magnet on the ion injection line reflect the production of internally hot C72 - - C242 - dianions with lifetimes in the range of tens of microseconds to milliseconds. In spite of the high sensitivity of this method, no conclusive evidence of C62 - was found while there was a clear C72 - signal with the expected isotopic distribution. This is consistent with earlier experimental studies and with theoretical predictions. An upper limit is deduced for a C62 - signal that is two orders-of-magnitude smaller than that for C72 -. In addition, CnO2- and CnCu2- dianions were detected.
The cryogenic storage ring CSR
NASA Astrophysics Data System (ADS)
von Hahn, R.; Becker, A.; Berg, F.; Blaum, K.; Breitenfeldt, C.; Fadil, H.; Fellenberger, F.; Froese, M.; George, S.; Göck, J.; Grieser, M.; Grussie, F.; Guerin, E. A.; Heber, O.; Herwig, P.; Karthein, J.; Krantz, C.; Kreckel, H.; Lange, M.; Laux, F.; Lohmann, S.; Menk, S.; Meyer, C.; Mishra, P. M.; Novotný, O.; O'Connor, A. P.; Orlov, D. A.; Rappaport, M. L.; Repnow, R.; Saurabh, S.; Schippers, S.; Schröter, C. D.; Schwalm, D.; Schweikhard, L.; Sieber, T.; Shornikov, A.; Spruck, K.; Sunil Kumar, S.; Ullrich, J.; Urbain, X.; Vogel, S.; Wilhelm, P.; Wolf, A.; Zajfman, D.
2016-06-01
An electrostatic cryogenic storage ring, CSR, for beams of anions and cations with up to 300 keV kinetic energy per unit charge has been designed, constructed, and put into operation. With a circumference of 35 m, the ion-beam vacuum chambers and all beam optics are in a cryostat and cooled by a closed-cycle liquid helium system. At temperatures as low as (5.5 ± 1) K inside the ring, storage time constants of several minutes up to almost an hour were observed for atomic and molecular, anion and cation beams at an energy of 60 keV. The ion-beam intensity, energy-dependent closed-orbit shifts (dispersion), and the focusing properties of the machine were studied by a system of capacitive pickups. The Schottky-noise spectrum of the stored ions revealed a broadening of the momentum distribution on a time scale of 1000 s. Photodetachment of stored anions was used in the beam lifetime measurements. The detachment rate by anion collisions with residual-gas molecules was found to be extremely low. A residual-gas density below 140 cm-3 is derived, equivalent to a room-temperature pressure below 10-14 mbar. Fast atomic, molecular, and cluster ion beams stored for long periods of time in a cryogenic environment will allow experiments on collision- and radiation-induced fragmentation processes of ions in known internal quantum states with merged and crossed photon and particle beams.
The cryogenic storage ring CSR.
von Hahn, R; Becker, A; Berg, F; Blaum, K; Breitenfeldt, C; Fadil, H; Fellenberger, F; Froese, M; George, S; Göck, J; Grieser, M; Grussie, F; Guerin, E A; Heber, O; Herwig, P; Karthein, J; Krantz, C; Kreckel, H; Lange, M; Laux, F; Lohmann, S; Menk, S; Meyer, C; Mishra, P M; Novotný, O; O'Connor, A P; Orlov, D A; Rappaport, M L; Repnow, R; Saurabh, S; Schippers, S; Schröter, C D; Schwalm, D; Schweikhard, L; Sieber, T; Shornikov, A; Spruck, K; Sunil Kumar, S; Ullrich, J; Urbain, X; Vogel, S; Wilhelm, P; Wolf, A; Zajfman, D
2016-06-01
An electrostatic cryogenic storage ring, CSR, for beams of anions and cations with up to 300 keV kinetic energy per unit charge has been designed, constructed, and put into operation. With a circumference of 35 m, the ion-beam vacuum chambers and all beam optics are in a cryostat and cooled by a closed-cycle liquid helium system. At temperatures as low as (5.5 ± 1) K inside the ring, storage time constants of several minutes up to almost an hour were observed for atomic and molecular, anion and cation beams at an energy of 60 keV. The ion-beam intensity, energy-dependent closed-orbit shifts (dispersion), and the focusing properties of the machine were studied by a system of capacitive pickups. The Schottky-noise spectrum of the stored ions revealed a broadening of the momentum distribution on a time scale of 1000 s. Photodetachment of stored anions was used in the beam lifetime measurements. The detachment rate by anion collisions with residual-gas molecules was found to be extremely low. A residual-gas density below 140 cm(-3) is derived, equivalent to a room-temperature pressure below 10(-14) mbar. Fast atomic, molecular, and cluster ion beams stored for long periods of time in a cryogenic environment will allow experiments on collision- and radiation-induced fragmentation processes of ions in known internal quantum states with merged and crossed photon and particle beams.
Resonant structure of low-energy H3+ dissociative recombination
NASA Astrophysics Data System (ADS)
Petrignani, Annemieke; Altevogt, Simon; Berg, Max H.; Bing, Dennis; Grieser, Manfred; Hoffmann, Jens; Jordon-Thaden, Brandon; Krantz, Claude; Mendes, Mario B.; Novotný, Oldřich; Novotny, Steffen; Orlov, Dmitry A.; Repnow, Roland; Sorg, Tobias; Stützel, Julia; Wolf, Andreas; Buhr, Henrik; Kreckel, Holger; Kokoouline, Viatcheslav; Greene, Chris H.
2011-03-01
High-resolution dissociative recombination rate coefficients of rotationally cool and hot H3+ in the vibrational ground state have been measured with a 22-pole trap setup and a Penning ion source, respectively, at the ion storage-ring TSR. The experimental results are compared with theoretical calculations to explore the dependence of the rate coefficient on ion temperature and to study the contributions of different symmetries to probe the rich predicted resonance spectrum. The kinetic energy release was investigated by fragment imaging to derive internal temperatures of the stored parent ions under differing experimental conditions. A systematic experimental assessment of heating effects is performed which, together with a survey of other recent storage-ring data, suggests that the present rotationally cool rate-coefficient measurement was performed at 380-130+50 K and that this is the lowest rotational temperature so far realized in storage-ring rate-coefficient measurements on H3+. This partially supports the theoretical suggestion that temperatures higher than assumed in earlier experiments are the main cause for the large gap between the experimental and the theoretical rate coefficients. For the rotationally hot rate-coefficient measurement a temperature of below 3250 K is derived. From these higher-temperature results it is found that increasing the rotational ion temperature in the calculations cannot fully close the gap between the theoretical and the experimental rate coefficients.
ISEE-1 data reduction and analysis plasma composition experiment
NASA Technical Reports Server (NTRS)
Lennartsson, W.; Sharp, R. D.
1985-01-01
The plasma composition experiment covers energies from OeV to 17 keV/e and has a mass-per-charge range from less than 1 to about 150 amu. Measurements were made from the inner ring current region to the plasma sheet, magnetotail lobes, and the magnetopause boundary layers and beyond. Possibly the most significant results from the experiment are those related to energetic (0+) ions of terrestrial origin. These ions are found in every region of the magnetosphere reached by the spacecraft and can have energy and pitch-angle distributions that are similar to those traditionally associated with protons of solar wind origin. The (0+) ions are commonly the most numerous ions in the 0.1 - 17 keV/e energy range and are often a substantial part of the ion population at large distances as well, especially during geomagnetically disturbed conditions. An overview of results obtained for the (0+) and other ions with energies in the 0.1 - 17 keV/e range in the magnetosphere is given.
Impact of Ring Current Ions on Electromagnetic Ion Cyclotron Wave Dispersion Relation
NASA Technical Reports Server (NTRS)
Khazanov, G. V.; Gamayunov, K. V.
2007-01-01
Effect of the ring current ions in the real part of electromagnetic ion Cyclotron wave dispersion relation is studied on global scale. Recent Cluster observations by Engebretson et al. showed that although the temperature anisotropy of is energetic (> 10 keV) ring current protons was high during the entire 22 November 2003 perigee pass, electromagnetic ion cyclotron waves were observed only in conjunction with intensification of the ion fluxes below 1 keV by over an order of magnitude. To study the effect of the ring current ions on the wave dispersive properties and the corresponding global wave redistribution, we use a self-consistent model of interacting ring current and electromagnetic ion cyclotron waves, and simulate the May 1998 storm. The main findings of our simulation can be summarized as follows: First, the plasma density enhancement in the night MLT sector during the main and recovery storm phases is mostly caused by injection of suprathermal plasma sheet H + (approximately < 1 keV), which dominate the thermal plasma density. Second, during the recovery storm phases, the ring current modification of the wave dispersion relation leads to a qualitative change of the wave patterns in the postmidnight-dawn sector for L > 4.75. This "new" wave activity is well organized by outward edges of dense suprathermal ring current spots, and the waves are not observed if the ring current ions are not included in the real part of dispersion relation. Third, the most intense wave-induced ring current precipitation is located in the night MLT sector and caused by modification of the wave dispersion relation. The strongest precipitating fluxes of about 8 X 10(exp 6)/ (cm(exp 2) - s X st) are found near L=5.75, MLT=2 during the early recovery phase on 4 May. Finally, the nightside precipitation is more intense than the dayside fluxes, even if there are less intense waves, because the convection field moves ring current ions into the loss cone on the nightside, but drives them out of the loss cone on the dayside. So convection and wave scattering reinforce each other in the nightside, but interfere in the dayside sector.
Manganese oxide helices, rings, strands, and films, and methods for their preparation
Suib, Steven L.; Giraldo, Oscar; Marquez, Manuel; Brock, Stephanie
2003-01-07
Methods for the preparation of mixed-valence manganese oxide compositions with quaternary ammonium ions are described. The compositions self-assemble into helices, rings, and strands without any imposed concentration gradient. These helices, rings, and strands, as well as films having the same composition, undergo rapid ion exchange to replace the quaternary ammonium ions with various metal ions. And the metal-ion-containing manganese oxide compositions so formed can be heat treated to form semi-conducting materials with high surface areas.
Plasmasphere Modeling with Ring Current Heating
NASA Technical Reports Server (NTRS)
Guiter, S. M.; Fok, M.-C.; Moore, T. E.
1995-01-01
Coulomb collisions between ring current ions and the thermal plasma in the plasmasphere will heat the plasmaspheric electrons and ions. During a storm such heating would lead to significant changes in the temperature and density of the thermal plasma. This was modeled using a time- dependent, one-stream hydrodynamic model for plasmaspheric flows, in which the model flux tube is connected to the ionosphere. The model simultaneously solves the coupled continuity, momentum, and energy equations of a two-ion (H(+) and O(+) quasineutral, currentless plasma. Heating rates due to collisions with ring current ions were calculated along the field line using a kinetic ring current model. First, diurnally reproducible results were found assuming only photoelectron heating of the thermal electrons. Then results were found with heating of the H(+) ions by the ring current during the recovery phase of a magnetic storm.
FLSR - The Frankfurt low energy storage ring
NASA Astrophysics Data System (ADS)
Stiebing, K. E.; Alexandrov, V.; Dörner, R.; Enz, S.; Kazarinov, N. Yu.; Kruppi, T.; Schempp, A.; Schmidt Böcking, H.; Völp, M.; Ziel, P.; Dworak, M.; Dilfer, W.
2010-02-01
An electrostatic storage ring for low-energy ions with a design energy of 50 keV is presently being set up at the Institut für Kernphysik der Johann Wolfgang Goethe-Universität Frankfurt am Main, Germany (IKF). This new device will provide a basis for new experiments on the dynamics of ionic and molecular collisions, as well as for high precision and time resolved laser spectroscopy. In this article, the design parameters of this instrument are reported.
Ring Current Ion Coupling with Electromagnetic Ion Cyclotron Waves
NASA Technical Reports Server (NTRS)
Khazanov. G. V.; Gamayunov, K. V.; Jordanova, V. K.; Six, N. Frank (Technical Monitor)
2002-01-01
A new ring current global model has been developed that couples the system of two kinetic equations: one equation describes the ring current (RC) ion dynamic, and another equation describes wave evolution of electromagnetic ion cyclotron waves (EMIC). The coupled model is able to simulate, for the first time self-consistently calculated RC ion kinetic and evolution of EMIC waves that propagate along geomagnetic field lines and reflect from the ionosphere. Ionospheric properties affect the reflection index through the integral Pedersen and Hall conductivities. The structure and dynamics of the ring current proton precipitating flux regions, intensities of EMIC global RC energy balance, and some other parameters will be studied in detail for the selected geomagnetic storms.
Advanced electric propulsion and space plasma contactor research
NASA Technical Reports Server (NTRS)
Wilbur, P. J.
1986-01-01
A series of experiments performed on an 8 cm dia. ring cusp magnetic field ion thruster are described. The results show the effects of anode and cathode position and size, ring cusp axial location and discharge chamber length on plasma ion energy cost and extracted ion fraction. Thruster performance is shown to be improved substantially when optimum values of these parameters are used. Investigations into the basic plasma phenomena associated with the process of plasma contacting are described. The results show the process of electron collection from a background plasma to a hollow cathode plasma contactor exhibits a higher impedance than the process of electron emission from the hollow cathode. The importance of having cold ions present to facilitate the plasma contacting process is shown. Results of experiments into the behavior of hollow cathodes operating at high interelectrode pressures (up to approx. 100 Torr) on nitrogen and ammonia are presented. They suggest that diffuse emission from the insert of a hollow cathode can be sustained at high interelectrode pressures if the cathode is made of non-conducting material and the cathode internal pressure is reduced by evacuating the cathode interior. A theoretical model of discharge chamber operation developed for inert gas thrusters is extended so it can be used to evaluste the performance of mercury ion thrusters. Predictions of the model are compared to experimental results obtained on two 30 cm dia. thrusters.
NASA Astrophysics Data System (ADS)
Rosner, Guenther
2007-05-01
The Facility for Antiproton and Ion Research, FAIR, is a new particle accelerator facility to be built at the GSI site in Germany. The research at FAIR will cover a wide range of topics in nuclear and hadron physics, high density plasma and atomic physics, and applications in condensed matter physics and biology. A 1.1 km circumference double ring of rapidly cycling 100 and 300 Tm synchrotrons, will be FAIR's central accelerator system. It will be used to produce, inter alia, high intensity secondary beams of antiprotons and short-lived radioactive nuclei. A subsequent suite of cooler and storage rings will deliver heavy ion and antiproton beams of unprecedented quality. Large experiments are presently being designed by the NUSTAR, PANDA, PAX, CBM, SPARC, FLAIR, HEDgeHOB and BIOMAT collaborations.
Effect of a strong-current ion ring on spheromak stability
DOE Office of Scientific and Technical Information (OSTI.GOV)
Litwin, C.; Sudan, R.N.
The stability of a spheromak with an energetic ion ring, carrying a current comparable to the plasma current, to the tilt mode is considered. For small departures from sphericity a perturbative approach is applied to an appropriate energy principle in order to calculate the lowest nontrivial kinetic contribution of the ion ring. An analytic stability criterion is obtained. It is seen that the prolate configuration becomes more stable while the oblate one is less stable than in the absence of the ring. The prolomak becomes stable when the ring kinetic energy exceeds the magnetic energy within the separatrix.
Particle simulation of ion heating in the ring current
NASA Technical Reports Server (NTRS)
Qian, S.; Hudson, M. K.; Roth, I.
1990-01-01
Heating of heavy ions has been observed in the equatorial magnetosphere in GEOS 1 and 2 and ATS 6 data due to ion cyclotron waves generated by anisotropic hot ring current ions. A one-dimensional hybrid-Darwin code has been developed to study ion heating in the ring current. Here, a strong instability and heating of thermal ions is investigated in a plasma with a los cone distribution of hot ions. The linear growth rate calculation and particle simulations are conducted for cases with different loss cones and relative ion densities. The linear instability of the waves, the quasi-linear heating of cold ions and dependence on the thermal H(+)/He(+) density ratio are analyzed, as well as nonlinear parallel heating of thermal ions. Effects of thermal oxygen and hot oxygen are also studied.
Stationary Temperature Distribution in a Rotating Ring-Shaped Target
NASA Astrophysics Data System (ADS)
Kazarinov, N. Yu.; Gulbekyan, G. G.; Kazacha, V. I.
2018-05-01
For a rotating ring-shaped target irradiated by a heavy-ion beam, a differential equation for computing the stationary distribution of the temperature averaged over the cross section is derived. The ion-beam diameter is assumed to be equal to the ring width. Solving this equation allows one to obtain the stationary temperature distribution along the ring-shaped target depending on the ion-beam, target, and cooling-gas parameters. Predictions are obtained for the rotating target to be installed at the DC-280 cyclotron. For an existing rotating target irradiated by an ion beam, our predictions are compared with the measured temperature distribution.
Achieving Translationally Invariant Trapped Ion Rings
NASA Astrophysics Data System (ADS)
Urban, Erik; Li, Hao-Kun; Noel, Crystal; Hemmerling, Boerge; Zhang, Xiang; Haeffner, Hartmut
2017-04-01
We present the design and implementation of a novel surface ion trap design in a ring configuration. By eliminating the need for wire bonds through the use of electrical vias and using a rotationally invariant electrode configuration, we have realized a trap that is able to trap up to 20 ions in a ring geometry 45um in diameter, 400um above the trap surface. This large trapping height to ring diameter ratio allows for global addressing of the ring with both lasers and electric fields in the chamber, thereby increasing our ability to control the ring as a whole. Applying compensating electric fields, we measure very low tangential trap frequencies (less than 20kHz) corresponding to rotational barriers down to 4mK. This measurement is currently limited by the temperature of the ions but extrapolation indicates the barrier can be reduced much further with more advanced cooling techniques. Finally, we show that we are able to reduce this energy barrier sufficiently such that the ions are able to overcome it either through thermal motion or rotational motion and delocalize over the full extent of the ring. This work was funded by the Keck Foundation and the NSF.
Neutral O2 and Ion O2+ Sources from Rings into the Inner Magnetosphere
NASA Astrophysics Data System (ADS)
Elrod, M. K.; Johnson, R. E.; Cassidy, T. A.; Wilson, R. J.; Tseng, W.; Ip, W.
2009-12-01
The primary source of neutral O2 for Saturn’s magnetosphere is due to solar UV photons protons that produce O2 from H2O ice decomposition over the main rings as well as the tenuous F and G rings resulting in a tenuous O2 atmosphere (Johnson et. al. 2006). The O2 atmosphere is very thin to the point of being nearly collisionless. Our model of the atmosphere predict that as it interacts with the ring particles, the O2 is adsorbed and desorbed from the rings causing changes in the trajectories, which in turn, allows for a distribution of O2 from the rings throughout the magnetosphere (Tokar et. al. 2005; Tseng et. al. 2009). Predominately through photo-ionization and ion-exchange these O2 neutrals from the ice grains become a source for O2+ ions in the inner magnetosphere. Once the O2 becomes ionized to become O2+ the ions then follow the field lines. The ions interact with the ice particles in the rings to stick to the ring particles effectively reducing the ion density. As a result the ion density is greater over the Cassini Division and the area between the F and G ring where the optical depth due to the ice grain is less. Accordingly, the neutral O2 densities would tend to be high over the higher optical depth of the B and A main rings where the source rates are higher. Models of the neutral densities have shown high densities over the main rings, with a tail through the magnetosphere. Analysis of the CAPS (Cassini Plasma Spectrometer) data from the Saturn Orbit Insertion (SOI) in 2004 shows a peak in density over the Cassini Division and a higher peak in O2+ ion density between the F and G rings. References: Johnson, R.E., J.G. Luhmann, R.L. Tokar, M. Bouhram, J.J. Berthelier, E.C. Siler, J.F. Cooper, T.W. Hill, H.T. Smith, M. Michael, M. Liu, F.J. Crary, D.T. Young, "Production, Ionization and Redistribution of O2 Saturn's Ring Atmosphere" Icarus 180, 393-402 (2006).(pdf) Tokar, R.L., and 12 colleagues, 2005. Cassini Observations of the Thermal Plasma in the Vicinity of Saturn’s Main Rings and the F and G Rings. Geophys. Res. Lett. 32, doi:10.1029/2005GL022690. L14S04. Martens, H. R., Reisenfeld, D. B., Williams, J. D., Johnson, R.E., Smith H. T., “Observations of molecular oxygen ions in Saturn’s inner magnetosphere”. Geophy. Res. Lett. 2009. W.-L. Tseng, Ip, W.-H., Johnson, R. E., Cassidy, T. A., Elrod, M. K., “The Structure and Time Variability of the Ring atmosphere and ionosphere”. Geophy. Res. Lett. 2009.
NASA Astrophysics Data System (ADS)
Kronberg, E. A.; Welling, D.; Kistler, L. M.; Mouikis, C.; Daly, P. W.; Grigorenko, E. E.; Klecker, B.; Dandouras, I.
2017-09-01
Magnetospheric plasma sheet ions drift toward the Earth and populate the ring current. The ring current plasma pressure distorts the terrestrial internal magnetic field at the surface, and this disturbance strongly affects the strength of a magnetic storm. The contribution of energetic ions (>40 keV) and of heavy ions to the total plasma pressure in the near-Earth plasma sheet is not always considered. In this study, we evaluate the contribution of low-energy and energetic ions of different species to the total plasma pressure for the storm observed by the Cluster mission from 27 September until 3 October 2002. We show that the contribution of energetic ions (>40 keV) and of heavy ions to the total plasma pressure is ≃76-98.6% in the ring current and ≃14-59% in the magnetotail. The main source of oxygen ions, responsible for ≃56% of the plasma pressure of the ring current, is located at distances earthward of XGSE ≃ -13.5 RE during the main phase of the storm. The contribution of the ring current particles agrees with the observed Dst index. We model the magnetic storm using the Space Weather Modeling Framework (SWMF). We assess the plasma pressure output in the ring current for two different ion outflow models in the SWMF through comparison with observations. Both models yield reasonable results. The model which produces the most heavy ions agrees best with the observations. However, the data suggest that there is still potential for refinement in the simulations.
Astrochemistry in TSR and CSR Ion Storage Rings
NASA Astrophysics Data System (ADS)
Novotny, Oldrich
2017-04-01
Dissociative recombination (DR) of molecular ions plays a key role in controlling the charge density and composition of the cold interstellar medium (ISM). Experimental data on DR are required in order to understand the chemical network in the ISM and related processes such as star formation from molecular clouds. Needed data include not only total reaction cross sections, but also the chemical composition and excitation states of the neutral products. Utilizing the TSR storage ring in Heidelberg, Germany, we have carried out DR measurements for astrophysically important molecular ions. We use a merged electron-ion beams technique combined with event-by-event fragment counting and fragment imaging. The count rate of detected neutral DR products yields the absolute DR rate coefficient. Imaging the distribution of fragment distances provides information on the kinetic energy released including the states of both the initial molecule and the final products. Additional kinetic energy sensitivity of the employed detector allows for identification of fragmentation channels by fragment-mass combination within each dissociation event. Such combined information is essential for studies on DR of polyatomic ions with multi-channel breakup. The recently commissioned Cryogenic Storage Ring (CSR) in Heidelberg, Germany, extends the experimental capabilities of TSR by operation at cryogenic temperatures down to 6 K. At these conditions residual gas densities down to 100 cm-3 can be reached resulting in beam storage times of several hours. Long storage in the cold environment allows the ions to relax down to their rotational ground state, thus mimicking well the conditions in the cold ISM. A variety of astrophysically relevant reactions will be investigated at these conditions, such as DR, electron impact excitation, ion-neutral collisions, etc. We report our TSR results on DR of HCl+ and D2Cl+. We also present first results from the CSR commissioning experiments.
Single-ring magnetic cusp low gas pressure ion source
Bacon, Frank M.; Brainard, John P.; O'Hagan, James B.; Walko, Robert J.
1985-01-01
A single-ring magnetic cusp low gas pressure ion source designed for use in a sealed, nonpumped neutron generator utilizes a cathode and an anode, three electrically floating electrodes (a reflector behind the cathode, a heat shield around the anode, and an aperture plate), together with a single ring-cusp magnetic field, to establish and energy-filtering mechanism for producing atomic-hydrogen ions.
Time-of-flight SIMS/MSRI reflectron mass analyzer and method
Smentkowski, Vincent S.; Gruen, Dieter M.; Krauss, Alan R.; Schultz, J. Albert; Holecek, John C.
1999-12-28
A method and apparatus for analyzing the surface characteristics of a sample by Secondary Ion Mass Spectroscopy (SIMS) and Mass Spectroscopy of Recoiled Ions (MSRI) is provided. The method includes detecting back scattered primary ions, low energy ejected species, and high energy ejected species by ion beam surface analysis techniques comprising positioning a ToF SIMS/MSRI mass analyzer at a predetermined angle .theta., where .theta. is the angle between the horizontal axis of the mass analyzer and the undeflected primary ion beam line, and applying a specific voltage to the back ring of the analyzer. Preferably, .theta. is less than or equal to about 120.degree. and, more preferably, equal to 74.degree.. For positive ion analysis, the extractor, lens, and front ring of the reflectron are set at negative high voltages (-HV). The back ring of the reflectron is set at greater than about +700V for MSRI measurements and between the range of about +15 V and about +50V for SIMS measurements. The method further comprises inverting the polarity of the potentials applied to the extractor, lens, front ring, and back ring to obtain negative ion SIMS and/or MSRI data.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bozoki, E.S.; Halama, H.
1990-01-01
The mechanism of ion capture by the beam, their effects on the beam as well as ways to clear the ions are discussed. Special attention is given to these questions for the SXLS ring. 20 refs., 5 figs., 4 tabs.
Improved ion containment using a ring-cusp ion thruster
NASA Technical Reports Server (NTRS)
Sovey, J. S.
1982-01-01
A 30-centimeter diameter ring-cusp ion thruster is described which operates at inert gas ion beam currents up to about 7 ampere, with significant improvements in discharge chamber performance over conventional divergent-field thrusters. The thruster has strong boundary ring-cusp magnetic fields, a diverging field on the cathode region, and a nearly field-free volume upstream of the ion extraction system. Minimum ion beam production costs of 90 to 100 watts per beam ampere (W/A) were obtained for argon, krypton and xenon. Propellant efficiencies in excess of 0.90 were achieved at 100 to 120 W/A for the three inert gases. The ion beam charge-state was documented with a collimating mass spectrometer probe to allow evaluation of overall thruster efficiencies.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Katayama, T.
On the basis of the achievement of the accelerator studies at present TARN, it is decided to construct the new ring TARN II which will be operated as an accumulator, accelerator, cooler and stretcher. It has the maximum magnetic rigidity of 7 Txm corresponding to the proton energy 1.3 GeV and the ring diameter is around 23 m. Light and heavy ions from the SF cyclotron will be injected and accelerated to the working energy where the ring will be operated as a desired mode, for example a cooler ring mode. At the cooler ring operation, the strong cooling devicesmore » such as stochastic and electron beam coolings will work together with the internal gas jet target for the precise nuclear experiments. TARN II is currently under the contruction with the schedule of completion in 1986. In this paper general features of the project are presented.« less
Ring Current Ion Coupling with Electromagnetic Ion Cyclotron Waves
NASA Technical Reports Server (NTRS)
Khazanov, George V.
2002-01-01
A new ring current global model has been developed for the first time that couples the system of two kinetic equations: one equation describes the ring current (RC) ion dynamic, and another equation describes wave evolution of electromagnetic ion cyclotron waves (EMIC). The coupled model is able to simulate, for the first time self-consistently calculated RC ion kinetic and evolution of EMIC waves that propagate along geomagnetic field lines and reflect from the ionosphere. Ionospheric properties affect the reflection index through the integral Pedersen and Hall coductivities. The structure and dynamics of the ring current proton precipitating flux regions, intensities of EMIC, global RC energy balance, and some other parameters will be studied in detail for the selected geomagnetic storms. The space whether aspects of RC modelling and comparison with the data will also be discussed.
Parkin, A Top Level Manager in the Cell’s Sanitation Department
Rankin, Carolyn A; Roy, Ambrish; Zhang, Yang; Richter, Mark
2011-01-01
Parkin belongs to a class of multiple RING domain proteins designated as RBR (RING, in between RING, RING) proteins. In this review we examine what is known regarding the structure/function relationship of the Parkin protein. Parkin contains three RING domains plus a ubiquitin-like domain and an in-between-RING (IBR) domain. RING domains are rich in cysteine amino acids that act as ligands to bind zinc ions. RING domains may interact with DNA or with other proteins and perform a wide range of functions. Some function as E3 ubiquitin ligases, participating in attachment of ubiquitin chains to signal proteasome degradation; however, ubiquitin may be attached for purposes other than proteasome degradation. It was determined that the C-terminal most RING, RING2, is essential for Parkin to function as an E3 ubiquitin ligase and a number of substrates have been identified. However, Parkin also participates in a number of other fiunctions, such as DNA repair, microtubule stabilization, and formation of aggresomes. Some functions, such as participation in a multi-protein complex implicated in NMDA activity at the post synaptic density, do not require ubiquitination of substrate molecules. Recent observations of RING proteins suggest their function may be regulated by zinc ion binding. We have modeled the three RING domains of Parkin and have identified a new set of RING2 ligands. This set allows for binding of two rather than just one zinc ion, opening the possibility that the number of zinc ions bound acts as a molecular switch to modulate Parkin function. PMID:21633666
NASA Astrophysics Data System (ADS)
Popov, M. A.; Kochetov, I. V.; Starikovskiy, A. Yu; Aleksandrov, N. L.
2018-07-01
The results of the experimental and numerical study of high-voltage nanosecond discharge afterglow in H2O:N2 and H2O:O2 mixtures are presented for room temperature and at pressures from 2 to 5 Torr. Time-resolved electron density during the plasma decay was measured with a microwave interferometer for initial electron densities in the range between 1 × 1012 and 2 × 1012 cm‑3. Calculations showed that the plasma decay was controlled by recombination of thermalized electrons with H3O+(H2O) n ions for n from 0 to 4. Agreement between calculated and measured electron density histories was obtained only when using the recombination coefficients measured in the pulsed plasma afterglow experiments. The electron densities calculated using the data from the storage ring experiments were consistently greater than the values measured in this work for all conditions. It was concluded that the measurements of recombination coefficients for H3O+(H2O) n ions in the pulsed plasma afterglow were more appropriate for simulating the properties of high-density plasmas with high fractions of H2O, O2 and N2, such as discharge plasmas in water vapor and in humid air instead of the measurements in the storage ring experiments.
Global, Energy-Dependent Ring Current Response During Two Large Storms
NASA Astrophysics Data System (ADS)
Goldstein, J.; Angelopoulos, V.; Burch, J. L.; De Pascuale, S.; Fuselier, S. A.; Genestreti, K. J.; Kurth, W. S.; LLera, K.; McComas, D. J.; Reeves, G. D.; Spence, H. E.; Valek, P. W.
2015-12-01
Two recent large (~200 nT) geomagnetic storms occurred during 17--18 March 2015 and 22--23 June 2015. The global, energy-dependent ring current response to these two extreme events is investigated using both global imaging and multi-point in situ observations. Energetic neutral atom (ENA) imaging by the Two Wide-angle Imaging Neutral-atom Spectrometers (TWINS) mission provides a global view of ring current ions. Local measurements are provided by two multi-spacecraft missions. The two Van Allen Probes measure in situ plasma (including ion composition) and fields at ring current and plasmaspheric L values. The recently launched Magnetospheric Multiscale (MMS) comprises four spacecraft that have just begun to measure particles (including ion composition) and fields at outer magnetospheric L-values. We analyze the timing and energetics of the stormtime evolution of ring current ions, both trapped and precipitating, using TWINS ENA images and in situ data by the Van Allen Probes and MMS.
Evaluation of ion collection area in Faraday probes.
Brown, Daniel L; Gallimore, Alec D
2010-06-01
A Faraday probe with three concentric rings was designed and fabricated to assess the effect of gap width and collector diameter in a systematic study of the diagnostic ion collection area. The nested Faraday probe consisted of two concentric collector rings and an outer guard ring, which enabled simultaneous current density measurements on the inner and outer collectors. Two versions of the outer collector were fabricated to create gaps of 0.5 and 1.5 mm between the rings. Distribution of current density in the plume of a low-power Hall thruster ion source was measured in azimuthal sweeps at constant radius from 8 to 20 thruster diameters downstream of the exit plane with variation in facility background pressure. A new analytical technique is proposed to account for ions collected in the gap between the Faraday probe collector and guard ring. This method is shown to exhibit excellent agreement between all nested Faraday probe configurations, and to reduce the magnitude of integrated ion beam current to levels consistent with Hall thruster performance analyses. The technique is further studied by varying the guard ring bias potential with a fixed collector bias potential, thereby controlling ion collection in the gap. Results are in agreement with predictions based on the proposed analytical technique. The method is applied to a past study comparing the measured ion current density profiles of two Faraday probe designs. These findings provide new insight into the nature of ion collection in Faraday probe diagnostics, and lead to improved accuracy with a significant reduction in measurement uncertainty.
Ring/Shell Ion Distributions at Geosynchronous Orbit
NASA Astrophysics Data System (ADS)
Thomsen, M. F.; Denton, M. H.; Gary, S. P.; Liu, Kaijun; Min, Kyungguk
2017-12-01
One year's worth of plasma observations from geosynchronous orbit is examined for ion distributions that may simultaneously be subject to the ion Bernstein (IB) instability (generating fast magnetosonic waves) and the Alfvén cyclotron (AC) instability (generating electromagnetic ion cyclotron waves). Confirming past analyses, distributions with robust ∂fp(v⊥)/∂v⊥ > 0 near v|| = 0, which we denote as "ring/shell" distributions, are commonly found primarily on the dayside of the magnetosphere. A new approach to high-fidelity representation of the observed ring/shell distribution functions in a form readily suited to both analytical moment calculation and linear dispersion analysis is presented, which allows statistical analysis of the ring/shell properties. The ring/shell temperature anisotropy is found to have a clear upper limit that depends on the parallel beta of the ring/shell (β||r) in a manner that is diagnostic of the operation of the AC instability. This upper limit is only reached in the postnoon events, which are primarily produced by the energy- and pitch angle-dependent magnetic drifts of substorm-injected ions. Further, it is primarily the leading edge of such injections, where the distribution is strongly ring-like, that the AC instability appears to be operating. By contrast, the ratio of the ring energy to the Alfvén energy remains well within the range of 0.25-4.0 suitable for IB instability throughout essentially all of the events, except those that occur in denser cold plasma of the outer plasmasphere.
Storage-ring Electron Cooler for Relativistic Ion Beams
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lin, Fanglei; Derbenev, Yaroslav; Douglas, David R.
Application of electron cooling at ion energies above a few GeV has been limited due to reduction of electron cooling efficiency with energy and difficulty in producing and accelerating a high-current high-quality electron beam. A high-current storage-ring electron cooler offers a solution to both of these problems by maintaining high cooling beam quality through naturally-occurring synchrotron radiation damping of the electron beam. However, the range of ion energies where storage-ring electron cooling can be used has been limited by low electron beam damping rates at low ion energies and high equilibrium electron energy spread at high ion energies. This papermore » reports a development of a storage ring based cooler consisting of two sections with significantly different energies: the cooling and damping sections. The electron energy and other parameters in the cooling section are adjusted for optimum cooling of a stored ion beam. The beam parameters in the damping section are adjusted for optimum damping of the electron beam. The necessary energy difference is provided by an energy recovering SRF structure. A prototype linear optics of such storage-ring cooler is presented.« less
INMS measures an influx of molecules from Saturn's rings
NASA Astrophysics Data System (ADS)
Perry, M. E.
2017-12-01
In 1984, Connerney and Waite proposed water influx from Saturn's rings to explain the low electron densities measured during Pioneer and Voyager radio occultation experiments. Charge exchange with this minor species depleted the H+ ions and provided a faster path to electron recombination. With ice the primary constituent of the rings, water was the most likely in-falling molecule. During the Grand Finale orbits, Cassini's Ion and Neutral Mass Spectrometer (INMS) detected and quantified an influx from the rings. Unexpectedly, the primary influx molecules are CH4 and a heavier carbon-bearing species. Water was detected, but quantities were factors of ten lower than these other species. Distribution in both altitude and latitude are consistent with a ring influx. The concentration of the minor species in Saturn's atmosphere shows that they enter Saturn's atmosphere from the top. Both molecules have their highest concentrations at the highest altitudes, with concentrations >0.4% at 3,500 km altitude and only 0.02% at 2,700 km. Molecules from the rings deorbit to Saturn's atmosphere at altitudes near 4,000 km, consistent with the INMS measurements. The latitudinal dependence of the minor species indicates that their source is near the equatorial plane. At high altitudes, the minor species were observed primarily at zero latitude, where the 28u species was six times more concentrated than at 5° latitude. At lower altitudes, the peaking ratio was 1, indicating that the species had diffused and was fully mixed into Saturn's H2 atmosphere. The lighter molecule, CH4, diffuses more rapidly than the 28u species. INMS also detected both of these species during the earlier F-ring passes, finding that the neutrals were centered at the ring plane and extended 3,000 km (half width, half max) north and south.
NASA Astrophysics Data System (ADS)
Bolshakov, A. E.; Golubev, A. A.; Zenkevich, P. R.; Kats, M. M.; Kolomiets, A. A.
2014-09-01
We report the results of a study into the feasibility of conducting the ELISE and EXL experiments on collisions of nuclei of radioactive fragments with electrons at the Institute for Theoretical and Experimental Physics (ITEP). A scheme for uranium ion acceleration in the ITEP accelerator complex is chosen, and it is shown that uranium ions may be accelerated with an intensity of ˜1 × 1011 ions/s as soon as the complex is modified and a new injector is constructed. The basic parameters of the modified complex are given, and a layout diagram indicating the positions of the target that serves to produce radioactive fragments, the separator, and the storage rings (CR, RESR, NESR, and ER) at the ITEP site is presented.
Study of the heavy ion bunch compression in CSRm
NASA Astrophysics Data System (ADS)
Yin, Da-Yu; Liu, Yong; Yuan, You-Jing; Yang, Jian-Cheng; Li, Peng; Li, Jie; Chai, Wei-Ping; Sha, Xiao-Ping
2013-05-01
The feasibility of attaining nanosecond pulse length heavy ion beam is studied in the main ring (CSRm) of the Heavy Ion Research Facility in Lanzhou. Such heavy ion beam can be produced by non-adiabatic compression, and it is implemented by a fast rotation in the longitudinal phase space. In this paper, the possible beam parameters during longitudinal bunch compression are studied with the envelope model and Particle in Cell simulation, and the results are compared. The result shows that the short bunch 238U28+ with the pulse duration of about 50 ns at the energy of 200 MeV/u can be obtained which can satisfy the research of high density plasma physics experiment.
Atmospheric, Ionospheric, and Energetic Radiation Environments of Saturn's Rings
NASA Astrophysics Data System (ADS)
Cooper, J. F.; Kollmann, P.; Sittler, E. C., Jr.; Johnson, R. E.; Sturner, S. J.
2015-12-01
Planetary magnetospheric and high-energy cosmic ray interactions with Saturn's rings were first explored in-situ during the Pioneer 11 flyby in 1979. The following Voyager flybys produced a wealth of new information on ring structure and mass, and on spatial structure of the radiation belts beyond the main rings. Next came the Cassini Orbiter flyover of the rings during Saturn Orbital Insertion in 2004 with the first in-situ measurements of the ring atmosphere and plasma ionosphere. Cassini has since fully explored the radiation belt and magnetospheric plasma region beyond the main rings, discovering how Enceladus acts as a source of water group neutrals and water ions for the ion plasma. But do the main rings also substantially contribute by UV photolysis to water group plasma (H+, O+, OH+, H2O+, H3O+, O2+) and neutrals inwards from Enceladus? More massive rings, than earlier inferred from Pioneer 11 and Voyager observations, would further contribute by bulk ring ice radiolysis from interactions of galactic cosmic ray particles. Products of these interactions include neutron-decay proton and electron injection into the radiation belts beyond the main rings. How does radiolysis from moon and ring sweeping of the radiation belt particles compare with direct gas and plasma sources from the main rings and Enceladus? Can the magnetospheric ion and electron populations reasonably be accounted for by the sum of the ring-neutron-decay and outer magnetospheric inputs? Pioneer 11 made the deepest radial penetration into the C-ring, next followed by Cassini SOI. What might Cassini's higher-inclination proximal orbits reveal about the atmospheric, ionospheric, and energetic radiation environments in the D-ring and the proximal gap region? Recent modeling predicts a lower-intensity innermost radiation belt extending from the gap to the inner D-ring. Other remaining questions include the lifetimes of narrow and diffuse dust rings with respect to plasma and energetic particle irradiation processes, the mass flux of water group ions along planetary magnetic field lines into the Saturn planetary atmosphere, seasonal dust charging dynamics of the now-reappeared Saturn ring spokes, and the exchange of energy via energetic neutral atoms between the outer magnetosphere and the rings.
Loss of Water from Saturn's E-Ring Through Ion Pick-Up
NASA Technical Reports Server (NTRS)
Leisner, J. S.; Russell, C. T.; Dougherty, M. K.; Blanco-Cano, X.; Smith, E. J.; Tsurutani, B. T.
2005-01-01
One of the possible loss processes for Saturn s E-ring is ionization followed by acceleration by the electric field associated with the corotating magnetized plasma. It is possible to determine if this process is occurring by detecting electromagnetic waves at the gyrofrequency of water group ions. If the energy the particle gains in this pick-up process is sufficiently great, the picked up ions will generate ion cyclotron waves. Pioneer 11 and Voyager 1 both observed intervals of such waves associated with water group ions during their passes through Saturn s E-ring. Presently the magnetometer onboard the Cassini spacecraft is also seeing water group ion cyclotron oscillations. The Cassini data allow the spatial and temporal behavior of the waves to be mapped in ways not possible during the previous flybys. Analyses of these waves allow us to study the rate of mass loading and its latitudinal and local time variation. In conjunction with previous data, we can then determine the variation as the inclination of the ring to the Sun changes, in accordance with Saturn's seasons. These waves may be the clue to how Saturn powers its magnetosphere as the newly born ions could be the driver for the radial motion of the plasma and to how the E-ring may play the equivalent role to that of Io in the jovian magnetosphere.
Modular focusing ring imaging Cherenkov detector for electron-ion collider experiments
NASA Astrophysics Data System (ADS)
Wong, C. P.; Alfred, M.; Allison, L.; Awadi, M.; Azmoun, B.; Barbosa, F.; Barion, L.; Bennett, J.; Brooks, W.; Butler, C.; Cao, T.; Chiu, M.; Cisbani, E.; Contalbrigo, M.; Datta, A.; Del Dotto, A.; Demarteau, M.; Durham, J. M.; Dzhygadlo, R.; Elder, T.; Fields, D.; Furletova, Y.; Gleason, C.; Grosse-Perdekamp, M.; Harris, J.; Haseler, T. O. S.; He, X.; van Hecke, H.; Horn, T.; Hruschka, A.; Huang, J.; Hyde, C.; Ilieva, Y.; Kalicy, G.; Kimball, M.; Kistenev, E.; Kulinich, Y.; Liu, M.; Majka, R.; McKisson, J.; Mendez, R.; Nadel-Turonski, P.; Park, K.; Peters, K.; Rao, T.; Pisani, R.; Qiang, Y.; Rescia, S.; Rossi, P.; Sarajlic, O.; Sarsour, M.; Schwarz, C.; Schwiening, J.; da Silva, C. L.; Smirnov, N.; Stien, H. D.; Stevens, J.; Sukhanov, A.; Syed, S.; Tate, A. C.; Toh, J.; Towell, C. L.; Towell, R. S.; Tsang, T.; Turisini, M.; Wagner, R.; Wang, J.; Woody, C.; Xi, W.; Xie, J.; Zhao, Z. W.; Zihlmann, B.; Zorn, C.
2017-11-01
A powerful new electron-ioncollider (EIC) has been recommended in the 2015 Long Range Plan for Nuclear Science for probing the partonic structure inside nucleons and nuclei with unprecedented precision and versatility [1]. EIC detectors are currently under development [2], all of which require hadron identification over a broad kinematic range. A prototype ring imaging Cherenkov detector has been developed for hadron identification in the momentum range from 3 GeV/c to 10 GeV/c. The key feature of this new detector is a compact and modular design, achieved by using aerogel as radiator and a Fresnel lens for ring focusing. In this paper, the results from a beam test of a prototype device at Fermilab are reported.
Davis, Jeffery T [College Park, MD; Sidorov, Vladimir [Richmond, VA; Kotch, Frank W [New Phila., PA
2008-04-08
A compound containing at least two aromatic rings covalently bonded together, with each aromatic ring containing at least one oxyacetamide-based side chain, the compound being capable of forming a chloride ion channel across a lipid bilayer, and transporting chloride ion across the lipid bilayer.
Ring Current Development During Storm Main Phase
NASA Technical Reports Server (NTRS)
Fok, Mei-Ching; Moore, Thomas E.; Greenspan, Marian E.
1996-01-01
The development of the ring current ions in the inner magnetosphere during the main phase of a magnetic storm is studied. The temporal and spatial evolution of the ion phase space densities in a dipole field are calculated using a three dimensional ring current model, considering charge exchange and Coulomb losses along drift paths. The simulation starts with a quiet time distribution. The model is tested by comparing calculated ion fluxes with Active Magnetospheric Particle Tracer Explorers/CCE measurement during the storm main phase on May 2, 1986. Most of the calculated omnidirectional fluxes are in good agreement with the data except on the dayside inner edge (L less than 2.5) of the ring current, where the ion fluxes are underestimated. The model also reproduces the measured pitch angle distributions of ions with energies below 10 keV. At higher energy, an additional diffusion in pitch angle is necessary in order to fit the data. The role of the induced electric field on the ring current dynamics is also examined by simulating a series of substorm activities represented by stretching and collapsing the magnetic field lines. In response to the impulsively changing fields, the calculated ion energy content fluctuates about a mean value that grows steadily with the enhanced quiescent field.
The source of O+ in the storm time ring current
NASA Astrophysics Data System (ADS)
Kistler, L. M.; Mouikis, C. G.; Spence, H. E.; Menz, A. M.; Skoug, R. M.; Funsten, H. O.; Larsen, B. A.; Mitchell, D. G.; Gkioulidou, M.; Wygant, J. R.; Lanzerotti, L. J.
2016-06-01
A stretched and compressed geomagnetic field occurred during the main phase of a geomagnetic storm on 1 June 2013. During the storm the Van Allen Probes spacecraft made measurements of the plasma sheet boundary layer and observed large fluxes of O+ ions streaming up the field line from the nightside auroral region. Prior to the storm main phase there was an increase in the hot (>1 keV) and more isotropic O+ ions in the plasma sheet. In the spacecraft inbound pass through the ring current region during the storm main phase, the H+ and O+ ions were significantly enhanced. We show that this enhanced inner magnetosphere ring current population is due to the inward adiabatic convection of the plasma sheet ion population. The energy range of the O+ ion plasma sheet that impacts the ring current most is found to be from ~5 to 60 keV. This is in the energy range of the hot population that increased prior to the start of the storm main phase, and the ion fluxes in this energy range only increase slightly during the extended outflow time interval. Thus, the auroral outflow does not have a significant impact on the ring current during the main phase. The auroral outflow is transported to the inner magnetosphere but does not reach high enough energies to affect the energy density. We conclude that the more energetic O+ that entered the plasma sheet prior to the main phase and that dominates the ring current is likely from the cusp.
Fast ion conductivity in strained defect-fluorite structure created by ion tracks in Gd 2Ti 2O 7
Aidhy, Dilpuneet S.; Sachan, Ritesh; Zarkadoula, Eva; ...
2015-11-10
In this research, the structure and ion-conducting properties of the defect-fluorite ring structure formed around amorphous ion-tracks by swift heavy ion irradiation of Gd 2Ti 2O 7 pyrochlore are investigated. High angle annular dark field imaging complemented with ion-track molecular dynamics simulations show that the atoms in the ring structure are disordered, and have relatively larger cation-cation interspacing than in the bulk pyrochlore, illustrating the presence of tensile strain in the ring region. Density functional theory calculations show that the non-equilibrium defect-fluorite structure can be stabilized by tensile strain. The pyrochlore to defect-fluorite structure transformation in the ring region ismore » predicted to be induced by recrystallization during a melt-quench process and stabilized by tensile strain. Static pair-potential calculations show that planar tensile strain lowers oxygen vacancy migration barriers in pyrochlores, in agreement with recent studies on fluorite and perovskite materials. From these results, it is suggested that strain engineering could be simultaneously used to stabilize the defect-fluorite structure and gain control over its high ion-conducting properties.« less
NASA Technical Reports Server (NTRS)
Krimigis, S. M.; Mcentire, R. W.; Potemra, T. A.; Gloeckler, G.; Scarf, F. L.; Shelley, E. G.
1985-01-01
Compositional studies of the equatorial distributions of ring current ions during the September 4, 1984 magnetic storm have been made possible by comprehensive energy, charge state, and mass coverage data from the Charge Composition Explorer satellite. An examination of ion spectra at an L value of about 4 on September 5, in the local evening sector, shows that energy density was dominated by protons, with O ions contributing about 27 percent at the peak of about 150 keV, while He ions contributed less than about 2 percent. September 6 ion spectra, taken during the recovery phase of the storm, indicate that ion densities at more than 20 keV had decreased markedly, and that the ring current energy density was primarily provided by protons.
Charged particle modification of ices in the Saturnian and Jovian systems
NASA Technical Reports Server (NTRS)
Johnson, R. E.; Barton, L. A.; Boring, J. W.; Jesser, W. A.; Brown, W. L.
1985-01-01
The modification by ion bombardment of the surfaces of icy objects in the Saturnian and Jovian systems is discussed. Chemical changes in ices are induced by breaking of bonds and by implantation of incident ions. Long-term irradiation by fast ions produces physical changes such as increasing the surface reflectivity and ability to scatter light. On large satellites, molecules which are ejected by ion bombardment are redistributed across the surfaces of large satellites. For small satellites and ring particles bombarded by ions, such as those of Saturn, most or all of the sputtered material is lost to space, forming a neutral torus in the locale of the satellite orbits and rings and supplying ions to the magnetosphere. Noting the existence of such a torus, the sputter erosion and possible stabilization of the E-ring of Saturn is discussed.
The role of spin–rotation coupling in the non-exponential decay of hydrogen-like heavy ions
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lambiase, Gaetano, E-mail: lambiase@sa.infn.it; INFN, Sezione di Napoli; International Institute for Advanced Scientific Studies, 89019 Vietri sul Mare
2013-05-15
Recent experiments carried out at the storage ring of GSI in Darmstadt reveal an unexpected oscillation in the orbital electron capture and subsequent decay of hydrogen-like {sup 140}Pr{sup 58+}, {sup 142}Pm{sup 60+} and {sup 122}I{sup 52+}. The modulations have periods of 7.069(8) s, 7.10(22) s and 6.1 s respectively in the laboratory frame and are superimposed on the expected exponential decays. In this paper we propose a semiclassical model in which the observed modulations arise from the coupling of rotation to the spins of electron and nucleus. We show that the modulations are connected to quantum beats and to themore » effect of the Thomas precession on the spins of bound electron and nucleus, the magnetic moment precessions of electron and nucleus and their cyclotron frequencies. We also show that the spin–spin coupling of electron and nucleus, though dominant relative to the magnetic moment coupling of electron and nucleus with the storage ring magnetic field, does not contribute to the modulation because these terms average out during the time of flight of the ions, or cancel out. The model also predicts that the anomaly cannot be observed if the motion of the ions is rectilinear, or if the ions are stopped in a target (decay of neutral atoms in solid environments). It also supports the notion that no modulation occurs for the β{sup +}-decay branch. -- Highlights: ► Spin precession of the spin of nucleus and electron in storage ring. ► Coupling of rotation to the spin of electron and nucleus. ► Modulation in the decay probability of the heavy ions induced by quantum beats. ► Comparison with experimental data.« less
The Effects of Hydrogen Band EMIC Waves on Ring Current H+ Ions
NASA Astrophysics Data System (ADS)
Wang, Zhiqiang; Zhai, Hao; Gao, Zhuxiu
2017-12-01
Hydrogen band electromagnetic ion cyclotron (EMIC) waves have received much attention recently because they are found to frequently span larger spatial areas than the other band EMIC waves. Using test particle simulations, we study the nonlinear effects of hydrogen band EMIC waves on ring current H+ ions. A dimensionless parameter R is used to characterize the competition between wave-induced and adiabatic motions. The results indicate that there are three regimes of wave-particle interactions for typical 35 keV H+ ions at L = 5: diffusive (quasi-linear) behavior when αeq ≤ 35° (R ≥ 2.45), the nonlinear phase trapping when 35° < αeq < 50° (0.75 < R < 2.45), and both the nonlinear phase bunching and phase trapping when αeq ≥ 50° (R ≤ 0.75). The phase trapping can transport H+ ions toward large pitch angle, while the phase bunching has the opposite effect. The phase-trapped H+ ions can be significantly accelerated (from 35 keV to over 500 keV) in about 4 min and thus contribute to the formation of high energy components of ring current ions. The results suggest that the effect of hydrogen band EMIC waves is not ignorable in the nonlinear acceleration and resonance scattering of ring current H+ ions.
NASA Astrophysics Data System (ADS)
Calvano, Cosima Damiana; Cataldi, Tommaso R. I.; Kögel, Julius F.; Monopoli, Antonio; Palmisano, Francesco; Sundermeyer, Jorge
2017-08-01
The superbasic proton sponge 1,8-bis(tripyrrolidinylphosphazenyl)naphthalene (TPPN) has been successfully employed for the structural characterization of neutral saccharides, cyclodextrins, and saccharide alditols by matrix assisted laser desorption/ionization tandem mass spectrometry (MALDI-MS/MS). Owing to its inherently high basicity, TPPN is capable of deprotonating neutral carbohydrates (M) providing an efficient and simple way to produce gas-phase [M - H]- ions. Highly informative negative ions MS/MS spectra showing several diagnostic fragment ions were obtained, mainly A-type cross-ring and C-type glycosidic cleavages. Indeed, cross-ring cleavages of monosaccharides with formation of 0,2A, 0,3A, 2,4A, 2,5A, 3,5A, and 0,3X product ions dominate the MS/MS spectra. A significant difference between reducing (e.g., lactose, maltose) and non-reducing disaccharides (e.g., sucrose, trehalose) was observed. Though disaccharides with the anomeric positions blocked give rise to deprotonated molecules, [M - H]-, at m/ z 341.1, reducing ones exhibited a peak at m/ z 340.1, most likely as radical anion, [M - H•- H]-•. The superiority of TPPN was clearly demonstrated by comparison with well recognized matrices, such as 2,5-dihydroxybenzoic acid and 2',4',6'-trihydroxyacetophenone (positive ion mode) and nor-harman (negative ion mode). MALDI MS/MS experiments on isotopically labeled sugars have greatly supported the interpretation of plausible fragmentation pathways.
Inference of the ring current ion composition by means of charge exchange decay
NASA Technical Reports Server (NTRS)
Smith, P. H.; Hoffman, R. A.; Bewtra, N. K.
1981-01-01
The analysis of data from the Explorer 45 (S3-A) electrostatic analyzer in the energy range 5-30 keV has provided some new results on the ring current ion composition. It has been well established that the storm time ring current has a decay time of several days, during which the particle fluxes decrease nearly monotonically. By analyzing the measured ion fluxes during the several day storm recovery period and assuming that beside hydrogen other ions were present and that the decays were exponential in nature, three separate lifetimes for the ions were established. These fitted decay lifetimes are in excellent agreement with the expected charge exchange decay lifetimes for H(+), O(+) and He(+) in the energy and L value range of the data.
The status of the SNS external antenna ion source and spare RFQ test facility
DOE Office of Scientific and Technical Information (OSTI.GOV)
Welton, R. F., E-mail: welton@ornl.gov; Aleksandrov, A. V.; Han, B. X.
The Oak Ridge National Laboratory operates the Spallation Neutron Source, consisting of a H{sup −} ion source, a 1 GeV linac and an accumulator ring. The accumulated <1 μs-long, ∼35 A beam pulses are extracted from the ring at 60 Hz and directed onto a liquid Hg target. Spalled neutrons are directed to ∼20 world class instruments. Currently, the facility operates routinely with ∼1.2 MW of average beam power, which soon will be raised to 1.4 MW. A future upgrade with a second target station calls for raising the power to 2.8 MW. This paper describes the status of twomore » accelerator components expected to play important roles in achieving these goals: a recently acquired RFQ accelerator and the external antenna ion source. Currently, the RFQ is being conditioned in a newly constructed 2.5 MeV Integrated Test Facility (ITF) and the external antenna source is also being tested on a separate test stand. This paper presents the results of experiments and the testing of these systems.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gao Yitian; Tian Bo; State Key Laboratory of Software Development Environment, Beijing University of Aeronautics and Astronautics, Beijing 100083
2006-11-15
The spherical modified Kadomtsev-Petviashvili (smKP) model is hereby derived with symbolic computation for the dust-ion-acoustic waves with zenith-angle perturbation in a cosmic dusty plasma. Formation and properties of both dark and bright smKP nebulons are obtained and discussed. The relevance of those smKP nebulons to the supernova shells and Saturn's F-ring is pointed out, and possibly observable nebulonic effects for the future cosmic plasma experiments are proposed. The difference of the smKP nebulons from other types of nebulons is also analyzed.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Benson, Stephen V.; Derbenev, Yaroslav S.; Douglas, David R.
Jefferson Lab is in the process of designing an electron ion collider with unprecedented luminosity at a 45 GeV center-of-mass energy. This luminosity relies on ion cooling in both the booster and the storage ring of the accelerator complex. The cooling in the booster will use a conventional DC cooler similar to the one at COSY. The high-energy storage ring, operating at a momentum of up to 100 GeV/nucleon, requires novel use of bunched-beam cooling. There are two designs for such a cooler. The first uses a conventional Energy Recovery Linac (ERL) with a magnetized beam while the second usesmore » a circulating ring to enhance both peak and average currents experienced by the ion beam. This presentation will describe the design of both the Circulator Cooling Ring (CCR) design and that of the backup option using the stand-alone ERL operated at lower charge but higher repetition rate than the ERL injector required by the CCR-based design.« less
2007-12-12
Like Earth, Saturn has an invisible ring of energetic ions trapped in its magnetic field. This feature is known as a "ring current." This ring current has been imaged with a special camera on Cassini sensitive to energetic neutral atoms. This is a false color map of the intensity of the energetic neutral atoms emitted from the ring current through a processed called charged exchange. In this process a trapped energetic ion steals and electron from cold gas atoms and becomes neutral and escapes the magnetic field. The Cassini Magnetospheric Imaging Instrument's ion and neutral camera records the intensity of the escaping particles, which provides a map of the ring current. In this image, the colors represent the intensity of the neutral emission, which is a reflection of the trapped ions. This "ring" is much farther from Saturn (roughly five times farther) than Saturn's famous icy rings. Red in the image represents the higher intensity of the particles, while blue is less intense. Saturn's ring current had not been mapped before on a global scale, only "snippets" or areas were mapped previously but not in this detail. This instrument allows scientists to produce movies (see PIA10083) that show how this ring changes over time. These movies reveal a dynamic system, which is usually not as uniform as depicted in this image. The ring current is doughnut shaped but in some instances it appears as if someone took a bite out of it. This image was obtained on March 19, 2007, at a latitude of about 54.5 degrees and radial distance 1.5 million kilometres (920,000 miles). Saturn is at the center, and the dotted circles represent the orbits of the moon's Rhea and Titan. The Z axis points parallel to Saturn's spin axis, the X axis points roughly sunward in the sun-spin axis plane, and the Y axis completes the system, pointing roughly toward dusk. The ion and neutral camera's field of view is marked by the white line and accounts for the cut-off of the image on the left. The image is an average of the activity over a (roughly) 3-hour period. http://photojournal.jpl.nasa.gov/catalog/PIA10094
Modular focusing ring imaging Cherenkov detector for electron–ion collider experiments
Wong, C. P.; Alfred, M.; Allison, L.; ...
2017-07-16
Here, a powerful new electron–ioncollider (EIC) has been recommended in the 2015 Long Range Plan for Nuclear Science for probing the partonic structure inside nucleons and nuclei with unprecedented precision and versatility. EIC detectors are currently under development, all of which require hadron identification over a broad kinematic range. A prototype ring imaging Cherenkov detector has been developed for hadron identification in the momentum range from 3 GeV/c to 10 GeV/c. The key feature of this new detector is a compact and modular design, achieved by using aerogel as radiator and a Fresnel lens for ring focusing. In this paper,more » the results from a beam test of a prototype device at Fermilab are reported.« less
The Thermal Ion Dynamics Experiment and Plasma Source Instrument
NASA Technical Reports Server (NTRS)
Moore, T. E.; Chappell, C. R.; Chandler, M. O.; Fields, S. A.; Pollock, C. J.; Reasoner, D. L.; Young, D. T.; Burch, J. L.; Eaker, N.; Waite, J. H., Jr.;
1995-01-01
The Thermal Ion Dynamics Experiment (TIDE) and the Plasma Source Instrument (PSI) have been developed in response to the requirements of the ISTP Program for three-dimensional (3D) plasma composition measurements capable of tracking the circulation of low-energy (0-500 eV) plasma through the polar magnetosphere. This plasma is composed of penetrating magnetosheath and escaping ionospheric components. It is in part lost to the downstream solar wind and in part recirculated within the magnetosphere, participating in the formation of the diamagnetic hot plasma sheet and ring current plasma populations. Significant obstacles which have previously made this task impossible include the low density and energy of the outflowing ionospheric plasma plume and the positive spacecraft floating potentials which exclude the lowest-energy plasma from detection on ordinary spacecraft. Based on a unique combination of focusing electrostatic ion optics and time of flight detection and mass analysis, TIDE provides the sensitivity (seven apertures of about 1 cm squared effective area each) and angular resolution (6 x 18 degrees) required for this purpose. PSI produces a low energy plasma locally at the POLAR spacecraft that provides the ion current required to balance the photoelectron current, along with a low temperature electron population, regulating the spacecraft potential slightly positive relative to the space plasma. TIDE/PSI will: (a) measure the density and flow fields of the solar and terrestrial plasmas within the high polar cap and magnetospheric lobes; (b) quantify the extent to which ionospheric and solar ions are recirculated within the distant magnetotail neutral sheet or lost to the distant tail and solar wind; (c) investigate the mass-dependent degree energization of these plasmas by measuring their thermodynamic properties; (d) investigate the relative roles of ionosphere and solar wind as sources of plasma to the plasma sheet and ring current.
Proton velocity ring-driven instabilities and their dependence on the ring speed: Linear theory
NASA Astrophysics Data System (ADS)
Min, Kyungguk; Liu, Kaijun; Gary, S. Peter
2017-08-01
Linear dispersion theory is used to study the Alfvén-cyclotron, mirror and ion Bernstein instabilities driven by a tenuous (1%) warm proton ring velocity distribution with a ring speed, vr, varying between 2vA and 10vA, where vA is the Alfvén speed. Relatively cool background protons and electrons are assumed. The modeled ring velocity distributions are unstable to both the Alfvén-cyclotron and ion Bernstein instabilities whose maximum growth rates are roughly a linear function of the ring speed. The mirror mode, which has real frequency ωr=0, becomes the fastest growing mode for sufficiently large vr/vA. The mirror and Bernstein instabilities have maximum growth at propagation oblique to the background magnetic field and become more field-aligned with an increasing ring speed. Considering its largest growth rate, the mirror mode, in addition to the Alfvén-cyclotron mode, can cause pitch angle diffusion of the ring protons when the ring speed becomes sufficiently large. Moreover, because the parallel phase speed, v∥ph, becomes sufficiently small relative to vr, the low-frequency Bernstein waves can also aid the pitch angle scattering of the ring protons for large vr. Potential implications of including these two instabilities at oblique propagation on heliospheric pickup ion dynamics are discussed.
Lackner, Florian; Chatterley, Adam S.; Pemmaraju, C. D.; ...
2016-12-21
Femtosecond extreme ultraviolet transient absorption spectroscopy is used to explore strong-field ionization induced dynamics in selenophene (C 4H 4Se). The dynamics are monitored in real-time from the viewpoint of the Se atom by recording the temporal evolution of element-specific spectral features near the Se 3d inner-shell absorption edge (~58 eV). The interpretation of the experimental results is supported by first-principles time-dependent density functional theory calculations. The experiments simultaneously capture the instantaneous population of stable molecular ions, the emergence and decay of excited cation states, and the appearance of atomic fragments. The experiments reveal, in particular, insight into the strong-field inducedmore » ring-opening dynamics in the selenophene cation, which are traced by the emergence of non-cyclic molecules as well as the liberation of Se + ions within an overall time scale of approximately 170 fs. In this study, we propose that both products may be associated with dynamics on the same electronic surfaces but with different degrees of vibrational excitation. The time-dependent inner-shell absorption features provide direct evidence for a complex relaxation mechanism that may be approximated by a two-step model, whereby the initially prepared, excited cyclic cation decays within τ 1 = 80 ± 30 fs into a transient molecular species, which then gives rise to the emergence of bare Se + and ring-open cations within an additional τ 2 = 80 ± 30 fs. The combined experimental and theoretical results suggest a close relationship between σ* excited cation states and the observed ring-opening reactions. In conclusion, the findings demonstrate that the combination of femtosecond time-resolved core-level spectroscopy with ab initio estimates of spectroscopic signatures provide new insights into complex, ultrafast photochemical reactions such as ring-opening dynamics in organic molecules in real-time and with simultaneous sensitivity for electronic and structural rearrangements.« less
Absorption spectrum of the firefly luciferin anion isolated in vacuo.
Støchkel, Kristian; Milne, Bruce F; Brøndsted Nielsen, Steen
2011-03-24
The excited-state physics of the firefly luciferin anion depends on its chemical environment, and it is therefore important to establish the intrinsic behavior of the bare ion. Here we report electronic absorption spectra of the anion isolated in vacuo obtained at an electrostatic ion storage ring and an accelerator mass spectrometer where ionic dissociation is monitored on a long time scale (from 33 μs and up to 3 ms) and on a short time scale (0-3 μs), respectively. In the ring experiment the yield of all neutrals (mainly CO(2)) as a function of wavelength was measured whereas in the single pass experiment, the abundance of daughter ions formed after loss of CO(2) was recorded to provide action spectra. We find maxima at 535 and 265 nm, and that the band shape is largely determined by the sampling time interval, which is due to the kinetics of the dissociation process. Calculations at the TD-B3LYP/TZVPP++ level predict maximum absorption at 533 and 275 nm for the carboxylate isomer in excellent agreement with the experimental findings. The phenolate isomer lies higher in energy by 0.22 eV, and also its absorption maximum is calculated to be at 463 nm, which is far away from the experimental value. Our data serve to benchmark future theoretical models for bioluminescence from fireflies.
US-Japan bumpy torus workshop. Final report
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
1985-01-01
A US-Japan ELMO Bumpy Torus Workshop was held on November 1 and 2, 1985 in Encinitas, California. The workshop focused on recent results from the Nagoya Bumpy Torus, EBT-1/S, and the proposed EBS program. The major results presented at the Workshop included extensive theoretical analyses of diamagnetic well formation by hot-electron rings in SM-1, a comprehensive review of recent experiments in NBT, and divertor concepts for EBS. Ikegami and Fujiwara summarized work on ring- and core-plasma properties, including conditions for stable ring operation, measurements of ring beta and the scaling of stored energy with heating power. Fujiwara reported a numbermore » of exciting results on ambipolar potential control in NBT. The successful outcome of ICRF experiments using twelve antennas was particularly striking. In operating regimes characterized by positive ambipolar potentials, the plasma density reached values in excess of 10/sup 13/cm/sup -3/ with ion temperatures in the 200 to 400 eV range. The plasma potential decayed with a time constant approach 0.1 sec after the ICRF pulse ended. These results appeared to be similar to predictions made over the past several years of greatly improved particle confinement in the positive ambipolar potential state.« less
NASA Astrophysics Data System (ADS)
Dertinger, Jennifer J.; Walker, Amy V.
2013-08-01
The role of the ionic liquid (IL) anion structure on analyte signal enhancements has been systematically investigated in secondary ion mass spectrometry (SIMS) using a variety of samples, including lipids, sterols, polymers, and peptides. Twenty-four ILs were synthesized. The 12 matrix acids were cinnamic acid derivatives. Two bases were employed: 1-methylimidazole and tripropylamine. Three matrices, methylimmidazolium o-coumarate, tripropylammonium o-coumarate, and tripropylammonium 3,4,5-trimethoxycinnamate, were "universal" matrices enhancing all analytes tested. The pKa of the matrix acid does not appear to have a strong effect on analyte ion intensities. Rather, it is observed that a single hydroxyl group on the anion aromatic ring leads to significantly increased molecular ion intensities. No analyte signal enhancements were observed for -CH3, -CF3 and -OCH3 groups present on the aromatic ring. The position of the -OH group on the aromatic ring also alters molecular ion intensity enhancements. As well as the chemical identity and position of substituents, the number of moieties on the aromatic ring may affect the analyte signal enhancements observed. These observations suggest that the activation of the IL anion aromatic ring is important for optimizing analyte signal intensities. The implications for SIMS imaging of complex structures, such as biological samples, are discussed.
Heteroaromatic-based electrolytes for lithium and lithium-ion batteries
Cheng, Gang; Abraham, Daniel P.
2017-04-18
The present invention provides an electrolyte for lithium and/or lithium-ion batteries comprising a lithium salt in a liquid carrier comprising heteroaromatic compound including a five-membered or six-membered heteroaromatic ring moiety selected from the group consisting of a furan, a pyrazine, a triazine, a pyrrole, and a thiophene, the heteroaromatic ring moiety bearing least one carboxylic ester or carboxylic anhydride substituent bound to at least one carbon atom of the heteroaromatic ring. Preferred heteroaromatic ring moieties include pyridine compounds, pyrazine compounds, pyrrole compounds, furan compounds, and thiophene compounds.
The electrons and ion characteristics of Saturn's plasma disk inside the Enceladus orbit
NASA Astrophysics Data System (ADS)
Morooka, Michiko; Wahlund, Jan-Erik; Ye, Sheng-Yi; Kurth, William; Persoon, Ann; Holmberg, Mika
2017-04-01
Cassini observations revealed that Saturn's icy moon Enceladus and surrounding E ring are the significant plasma source of the magnetosphere. However, the observations sometimes show the electron density enhancement even inside the Enceladus orbiting distance, 4RS. Further plasma contribution from the inner rings, the G and the F rings and main A ring are the natural candidate as an additional plasma source. The Cassini/RPWS Langmuir Probe (LP) measurement provides the characteristics of the electrons and ions independently in a cold dense plasma. The observations near the center of the E ring showed that the ion density being larger than the electron density, indicating that there is additional particle as a negative charge carrier. Those are the small nm and μm sized dust grains that are negatively charged by the electron attachments. The faint F and G rings, located at R=2RS and 3RS, consist of small grains and similar electron/ion density discrepancies can be expected. We will show different types of the LP observations when Cassini traveled the equator region of the plasma disk down to 3RS. One with the electron density increasing inside 4RS, and another with the electron density decreasing inside 4RS. During the orbit 016 (2005 doy-284/285), the electron density continued to increase toward the planet. On the other hand, the ion currents, the LP measured currents from the negative bias voltage, turn to decreasing inside 4RS, implying the density decrease of the ions. By comparing the observed LP ion current characteristics and the modeled values using the obtained electron density, we found that the characteristic ion mass can be several times larger than the water ions (AMU=18) that we expected in this region. During the orbit 015 (2005 doy-266/267), on the other hand, the LP observed sharp electron density drop near 3RS. The dust signals from the RPWS antenna showed the density enhancement of the μm sized grains coincide the electron density drop and we have estimated that the characteristic ion mass can exceed AMU=100. Throughout the whole Cassini observation near the equator inside 4RS, we didn't find the case with the ion densities larger than the electron densities as were found near the E ring and the Enceladus plume. We suggest that Saturn's plasmadisk inside the Enceladus orbit is dynamic in ion characteristics where the water molecules coagulate and grow into a small icy dust grains. In the presentation we discuss the relationship between the electron/ion density and the density of the nm and μm sized grains.
NASA Astrophysics Data System (ADS)
Willis, Christopher; Poole, Patrick; Schumacher, Douglas; Freeman, Richard; van Woerkom, Linn
2016-10-01
Laser-accelerated ions from thin targets have been widely studied for applications including secondary radiation sources and cancer therapy, with recent studies trending towards thinner targets which can provide improved ion energies and yields. Here we discuss results from an experiment on the Scarlet laser at OSU using variable thickness liquid crystal targets. On this experiment, the spatial and spectral distributions of accelerated ions were measured along target normal and laser axes at varying thicknesses from 150nm to 2000nm at a laser intensity of 1 ×1020W /cm2 . Maximum ion energy was observed for targets in the 600 - 800nm thickness range, with proton energies reaching 24MeV . The ions were further characterized using radiochromic film, revealing an unusual spatial distribution on many laser shots. Here, the peak ion yield falls in an annular ring surrounding the target normal, with an increasing divergence angle as a function of ion energy. Details of these spatial and spectral ion distributions will be presented, including spectral deconvolution of the RCF data, revealing additional trends in the accelerated ion distributions. Supported by the DARPA PULSE program through a Grant from AMRDEC, and by the NNSA under contract DE-NA0001976.
Jovanović, Marko; Peter-Katalinić, Jasna
2016-02-01
Oligosaccharides represent complex class of analytes for mass spectrometric analysis due to the high variety of structural isomers concerning glycosidic linkages and possible branching. A systematic study of the negative ion mode matrix-assisted laser desorption/ionization (MALDI) mass spectrometry of various neutral oligosaccharides under selection of an appropriate matrix, like 2,5-dihydroxyacetophenone (2,5-DHAP) is reported here, without commonly used anion dopant strategies. Nevertheless, we were able to generate relevant in-source decay (ISD) cross-ring fragment ions, typically obtained in the negative ion mode. Data observed indicate that the intrinsic property of the terminal non-reduced aldose is crucial for this behavior. A systematic study of the post source decay (PSD) of molecular, pseudomolecular and ISD cross-ring cleavage precursor ions is reported here. A direct comparison of the positive and negative ion mode MALDI MS1 and PSD behavior of neutral oligosaccharides could also be performed under the use of the same matrix preparation, because 2,5-DHAP is fully compatible with positive ion mode acquisition. We found that PSD spectra of deprotonated neutral oligosaccharides obtained in the negative ion mode are richer, because they contained both glycosidic and cross-ring fragment ions. However, we also found that cross-ring fragment ions are readily produced in the positive ion mode when potassiated precursor ions were selected. In addition, we show evidence that non-anionic dopants and specific instrumental parameters can also significantly influence the ISD fragmentation. Taken together, our results should increase our understanding of oligosaccharide behavior in the negative ion mode as well as increase our knowledge regarding many aspects of in-source MALDI chemistry. Copyright © 2016 John Wiley & Sons, Ltd.
NASA Technical Reports Server (NTRS)
Sheldon, R. B.
1994-01-01
We have studied the transport and loss of H(+), He(+), and He(++) ions in the Earth's quiet time ring current (1 to 300 keV/e, 3 to 7 R(sub E), Kp less than 2+, absolute value of Dst less than 11, 70 to 110 degs pitchangles, all LT) comparing the standard radial diffusion model developed for the higher-energy radiation belt particles with measurements of the lower energy ring current ions in a previous paper. Large deviations of that model, which fit only 50% of the data to within a factor of 10, suggested that another transport mechanism is operating in the ring current. Here we derive a modified diffusion coefficient corrected for electric field effects on ring current energy ions that fit nearly 80% of the data to within a factor of 2. Thus we infer that electric field fluctuations from the low-latitude to midlatitude ionosphere (ionospheric dynamo) dominated the ring current transport, rather than high-latitude or solar wind fluctuations. Much of the remaining deviation may arise from convective electric field transport of the E less than 30 keV particles. Since convection effects cannot be correctly treated with this azimuthally symmetric model, we defer treatment of the lowest-energy ions to a another paper. We give chi(exp 2) contours for the best fit, showing the dependence of the fit upon the internal/external spectral power of the predicted electric and magnetic field fluctuations.
ION EFFECTS IN THE APS PARTICLE ACCUMULATOR RING
DOE Office of Scientific and Technical Information (OSTI.GOV)
Calvey, J.; Harkay, K.; Yao, CY.
2017-06-25
Trapped ions in the APS Particle Accumulator Ring (PAR) lead to a positive coherent tune shift in both planes, which increases along the PAR cycle as more ions accumulate. This effect has been studied using an ion simulation code developed at SLAC. After modifying the code to include a realistic vacuum profile, multiple ionization, and the effect of shaking the beam to measure the tune, the simulation agrees well with our measurements. This code has also been used to evaluate the possibility of ion instabilities at the high bunch charge needed for the APS-Upgrade.
Loss of ring current O+ ions due to interaction with Pc 5 waves
NASA Astrophysics Data System (ADS)
Hudson, Mary; Chan, Anthony; Roth, Ilan
1993-01-01
The behavior of ring current ions in low-frequency geomagnetic pulsations is investigated analytically and numerically. We focus primarily on ring current O+ ions, whose flux increases dramatically during geomagnetic storms and decays at a rate which is not fully explained by collisional processes. This paper presents a new loss mechanism for the O+ ions due to the combined effects of convection and corotation electric fields and interaction with Pc 5 waves (wave period: 150-600 s) via a magnetic drift-bounce resonance. A test particle code has been developed to calculate the motion of the ring current O+ ions in a time-independent dipole magnetic field, and convection and corotation electric fields, plus Pc 5 wave fields, for which a simple analytical model has been formulated based on spacecraft observations. For given fields, whether a particle gains or loses energy depends on its initial kinetic energy, pitch angle at the equatorial plane, and the position of its guiding center with respect to the azimuthal phase of the wave. The ring current O+ ions show a dispersion in energies and L values with decreasing local time across the dayside, and a bulk shift to lower energies and higher L values. The former is due to the wave-particle interaction causing the ion to gain or lose energy, while the latter is due to the convection electric field. Our simulations show that, due to the interaction with the Pc 5 waves, the particle's kinetic energy can drop below that required to overcome the convection potential and the particle will be lost to the dayside magnetopause by a sunward E×B drift. This may contribute to the loss of O+ ions at intermediate energies (tens of keV) observed during the recovery phase of geomagnetic storms.
NO Chemisorption on Cu/SSZ-13: a Comparative Study from Infrared Spectroscopy and DFT Calculations
DOE Office of Scientific and Technical Information (OSTI.GOV)
Zhang, Renqin; McEwen, Jean-Sabin; Kollar, Marton
The locations and energies of Cu ions in a Cu/SSZ-13 zeolite catalyst were investigated by density functional theory (DFT) calculations. For 'naked' Cu2+ ions (i.e., Cu2+ ions with no ligands in their coordination spheres other than zeolite lattice oxygen atoms), the more energetically favorable sites are within a 6-membered ring. However, with the presence of various adsorbates, the energy difference between 6- and 8-membered ring locations greatly diminishes. Specifically, Cu2+ ions are substantially stabilized by -OH ligands (as [CuII(OH)]+), making the extra-framework sites in an 8-membered ring energetically more favorable than 6-membered ring sites. Under fully dehydrated high vacuum conditionsmore » with different Si/Al and Cu/Al ratios, three chemisorbed NO species coexist upon exposure of NO to Cu/SSZ-13: NO+, Cu2+-NO and Cu+-NO. The relative signal intensities for these bands vary greatly with Si/Al ratios. The vibrational frequency of chemisorbed NO was found to be very sensitive to the location of Cu2+ ions. On the one hand, with the aid from DFT calculations, the nature for these vibrations can be assigned in detail. On the other hand, the relative intensities for various Cu2+-NO species provide a good measure of the nature of Cu2+ ions as functions of Si/Al and Cu/Al ratios and the presence of humidity. These new findings cast doubt on the generally accepted proposal that only Cu2+ ions located in 6-membered rings are catalytically active for NH3-SCR.« less
NASA Astrophysics Data System (ADS)
Torvinen, Mika; Kalenius, Elina; Sansone, Francesco; Casnati, Alessandro; Jänis, Janne
2012-02-01
The noncovalent complexation of monoamine neurotransmitters and related ammonium and quaternary ammonium ions by a conformationally flexible tetramethoxy glucosylcalix[4]arene was studied by electrospray ionization Fourier transform ion cyclotron resonance (ESI-FTICR) mass spectrometry. The glucosylcalixarene exhibited highest binding affinity towards serotonin, norepinephrine, epinephrine, and dopamine. Structural properties of the guests, such as the number, location, and type of hydrogen bonding groups, length of the alkyl spacer between the ammonium head-group and the aromatic ring structure, and the degree of nitrogen substitution affected the complexation. Competition experiments and guest-exchange reactions indicated that the hydroxyl groups of guests participate in intermolecular hydrogen bonding with the glucocalixarene.
Recombination of open-f-shell tungsten ions
NASA Astrophysics Data System (ADS)
Krantz, C.; Badnell, N. R.; Müller, A.; Schippers, S.; Wolf, A.
2017-03-01
We review experimental and theoretical efforts aimed at a detailed understanding of the recombination of electrons with highly charged tungsten ions characterised by an open 4f sub-shell. Highly charged tungsten occurs as a plasma contaminant in ITER-like tokamak experiments, where it acts as an unwanted cooling agent. Modelling of the charge state populations in a plasma requires reliable thermal rate coefficients for charge-changing electron collisions. The electron recombination of medium-charged tungsten species with open 4f sub-shells is especially challenging to compute reliably. Storage-ring experiments have been conducted that yielded recombination rate coefficients at high energy resolution and well-understood systematics. Significant deviations compared to simplified, but prevalent, computational models have been found. A new class of ab initio numerical calculations has been developed that provides reliable predictions of the total plasma recombination rate coefficients for these ions.
NASA Astrophysics Data System (ADS)
Münzenberg, Gottfried; Geissel, Hans; Litvinov, Yuri A.
2010-04-01
This contribution is based on the combination of the talks: "What can we learn from large-scale mass measurements," "Present and future experiments with stored exotic nuclei at relativistic energies," and "Beta decay of highly-charged ions." Studying the nuclear mass surface gives information on the evolution of nuclear structure such as nuclear shells, the onset of deformation and the drip-lines. Previously, most of the masses far-off stability has been obtained from decay data. Modern methods allow direct mass measurements. They are much more sensitive, down to single atoms, access short-lived species and have high accuracy. Large-scale explorations of the nuclear mass surface are ideally performed with the combination of the in-flight FRagment Separator FRS and the Experimental Storage Ring ESR. After a brief historic introduction selected examples such as the evolution of shell closures far-off stability and the proton-neutron interaction will be discussed in the framework of our data. Recently, the experiments have been extended and led to the discovery of new heavy neutron-rich isotopes along with their mass and lifetime measurements. Storage rings applied at relativistic energies are a unique tool to study the radioactive decay of bare or few-electron atomic nuclei. New features observed with the analysis of stored circulating mother and daughter ions including oscillations in the decay curves of hydrogen-like nuclei will be addressed. Future experiments with NUSTAR at FAIR will further extend our knowledge to the borderlines of nuclear existence.
Hawking Radiation from an Acoustic Black Hole on an Ion Ring
DOE Office of Scientific and Technical Information (OSTI.GOV)
Horstmann, B.; Cirac, J. I.; Reznik, B.
2010-06-25
In this Letter we propose to simulate acoustic black holes with ions in rings. If the ions are rotating with a stationary and inhomogeneous velocity profile, regions can appear where the ion velocity exceeds the group velocity of the phonons. In these regions phonons are trapped like light in black holes, even though we have a discrete field theory and a nonlinear dispersion relation. We study the appearance of Hawking radiation in this setup and propose a scheme to detect it.
Hawking radiation from an acoustic black hole on an ion ring.
Horstmann, B; Reznik, B; Fagnocchi, S; Cirac, J I
2010-06-25
In this Letter we propose to simulate acoustic black holes with ions in rings. If the ions are rotating with a stationary and inhomogeneous velocity profile, regions can appear where the ion velocity exceeds the group velocity of the phonons. In these regions phonons are trapped like light in black holes, even though we have a discrete field theory and a nonlinear dispersion relation. We study the appearance of Hawking radiation in this setup and propose a scheme to detect it.
A new Ion Mobility Spectrometer
NASA Astrophysics Data System (ADS)
Butler, M. A.
1998-03-01
A new ion mobility spectrometer (IMS) concept has been demonstrated that traps ions in a potential well and then moves the well down a tube to a detector. The charge remaining in the well is measured as a function of well velocity or electric field that the ion experiences; thus separating the ions by mobility. The potential wave is generated and propagated down the tube by a series of ring electrodes along the tube under real-time computer control via an array of DACs. The operating characteristics of this device have been explored including the effects of ion "lifetime," well shape, and well velocity. The ion "lifetime" results from a radial field at the bottom of the potential well that pushes the ions toward the tube wall. This work was supported by the United States Department of Energy under Contract DE-AC04-94AL85000. Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy.
Ion-Acoustic Wave-Particle Energy Flow Rates
NASA Astrophysics Data System (ADS)
Berumen, Jorge; Chu, Feng; Hood, Ryan; Mattingly, Sean; Skiff, Fred
2017-10-01
We present an experimental characterization of the energy flow rates for ion acoustic waves. The experiment is performed in a cylindrical, magnetized, singly-ionized Argon, inductively-coupled gas discharge plasma that is weakly collisional with typical conditions: n 109cm-3 Te 9 eV and B 660 kG. A 4 ring antenna with diameter similar to the plasma diameter is used for launching the waves. A survey of the zeroth and first order ion velocity distribution functions (IVDF) is done using Laser-Induced Fluorescence (LIF) as the main diagnostics method. Using these IVDFs along with Vlasov's equation the different energy rates are measured for different values of ion velocity and separation from the antenna. We would like to acknowledge DOE DE-FG02-99ER54543 for their financial support throughout this research.
Performance characteristics of ring-cusp thrusters with xenon propellant
NASA Technical Reports Server (NTRS)
Patterson, M. J.
1986-01-01
The performance characteristics and operating envelope of several 30-cm ring-cusp ion thrusters with xenon propellant were investigated. Results indicate a strong performance dependence on the discharge chamber boundary magnetic fields and resultant distribution of electron currents. Significant improvements in discharge performance over J-series divergent-field thrusters were achieved for large throttling ranges, which translate into reduced cathode emission currents and reduced power dissipation which should be of significant benefit for operation at thruster power levels in excess of 10 kW. Mass spectrometry of the ion beam was documented for both the ring-cusp and J-series thrusters with xenon propellant for determination of overall thruster efficiency, and lifetime. Based on the lower centerline values of doubly charged ions in the ion beam and the lower operating discharge voltage, the screen grid erosion rate of the ring-cusp thruster is expected to be lower than the divergent-field J-series thruster by a factor of 2.
Performance characteristics of ring-cusp thrusters with xenon propellant
NASA Technical Reports Server (NTRS)
Patterson, M. J.
1986-01-01
The performance characteristics and operating envelope of several 30-cm ring-cusp ion thrusters with xenon propellant were investigated. Results indicate a strong performance dependence on the discharge chamber boundary magnetic fields and resultant distribution of electron currents. Significant improvements in discharge performance over J-series divergent-field thrusters were achieved for large throttling ranges, which translate into reduced cathode emission currents and reduced power dissipation which should be of significant benefit for operation at thruster power levels in excess of 10 kW. Mass spectrometer of the ion beam was documented for both the ring-cusp and J-series thrusters with xenon propellant for determination of overall thruster efficiency, and lifetime. Based on the lower centerline values of doubly charged ions in the ion beam and the lower operating discharge voltage, the screen grid erosion rate of the ring-cusp thruster is expected to be lower than the divergent-field J-series thruster by a factor of 2.
A multiple-orbit time-of-flight mass spectrometer based on a low energy electrostatic storage ring
NASA Astrophysics Data System (ADS)
Sullivan, M. R.; Spanjers, T. L.; Thorn, P. A.; Reddish, T. J.; Hammond, P.
2012-11-01
The results are presented for an electrostatic storage ring, consisting of two hemispherical deflector analyzers (HDA) connected by two separate sets of cylindrical lenses, used as a time-of-flight mass spectrometer. Based on the results of charged particle simulations and formal matrix model, the Ion Storage Ring is capable of operating with multiple stable orbits, for both single and multiply charged ions simultaneously.
NASA Astrophysics Data System (ADS)
Scholz, Pascal A.; Andrianov, Victor; Echler, Artur; Egelhof, Peter; Kilbourne, Caroline; Kiselev, Oleg; Kraft-Bermuth, Saskia; McCammon, Dan
2017-10-01
X-ray spectroscopy on highly charged heavy ions provides a sensitive test of quantum electrodynamics in very strong Coulomb fields. One limitation of the current accuracy of such experiments is the energy resolution of available X-ray detectors for energies up to 100 keV. To improve this accuracy, a novel detector concept, namely the concept of microcalorimeters, is exploited for this kind of measurements. The microcalorimeters used in the present experiments consist of silicon thermometers, ensuring a high dynamic range, and of absorbers made of high-Z material to provide high X-ray absorption efficiency. Recently, besides an earlier used detector, a new compact detector design, housed in a new dry cryostat equipped with a pulse tube cooler, was applied at a test beamtime at the experimental storage ring (ESR) of the GSI facility in Darmstadt. A U89+ beam at 75 MeV/u and a 124Xe54+ beam at various beam energies, both interacting with an internal gas-jet target, were used in different cycles. This test was an important benchmark for designing a larger array with an improved lateral sensitivity and statistical accuracy.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Abeyratne, S; Ahmed, S; Barber, D
2012-08-01
Researchers have envisioned an electron-ion collider with ion species up to heavy ions, high polarization of electrons and light ions, and a well-matched center-of-mass energy range as an ideal gluon microscope to explore new frontiers of nuclear science. In its most recent Long Range Plan, the Nuclear Science Advisory Committee (NSAC) of the US Department of Energy and the National Science Foundation endorsed such a collider in the form of a 'half-recommendation.' As a response to this science need, Jefferson Lab and its user community have been engaged in feasibility studies of a medium energy polarized electron-ion collider (MEIC), cost-effectivelymore » utilizing Jefferson Lab's already existing Continuous Electron Beam Accelerator Facility (CEBAF). In close collaboration, this community of nuclear physicists and accelerator scientists has rigorously explored the science case and design concept for this envisioned grand instrument of science. An electron-ion collider embodies the vision of reaching the next frontier in Quantum Chromodynamics - understanding the behavior of hadrons as complex bound states of quarks and gluons. Whereas the 12 GeV Upgrade of CEBAF will map the valence-quark components of the nucleon and nuclear wave functions in detail, an electron-ion collider will determine the largely unknown role sea quarks play and for the first time study the glue that binds all atomic nuclei. The MEIC will allow nuclear scientists to map the spin and spatial structure of quarks and gluons in nucleons, to discover the collective effects of gluons in nuclei, and to understand the emergence of hadrons from quarks and gluons. The proposed electron-ion collider at Jefferson Lab will collide a highly polarized electron beam originating from the CEBAF recirculating superconducting radiofrequency (SRF) linear accelerator (linac) with highly polarized light-ion beams or unpolarized light- to heavy-ion beams from a new ion accelerator and storage complex. Since the very beginning, the design studies at Jefferson Lab have focused on achieving high collider performance, particularly ultrahigh luminosities up to 10{sup 34} cm{sup -2}s{sup -1} per detector with large acceptance, while maintaining high polarization for both the electron and light-ion beams. These are the two key performance requirements of a future electron-ion collider facility as articulated by the NSAC Long Range Plan. In MEIC, a new ion complex is designed specifically to deliver ion beams that match the high bunch repetition and highly polarized electron beam from CEBAF. During the last two years, both development of the science case and optimization of the machine design point toward a medium-energy electron-ion collider as the topmost goal for Jefferson Lab. The MEIC, with relatively compact collider rings, can deliver a luminosity above 10{sup 34} cm{sup -2}s{sup -1} at a center-of-mass energy up to 65 GeV. It offers an electron energy up to 11 GeV, a proton energy up to 100 GeV, and corresponding energies per nucleon for heavy ions with the same magnetic rigidity. This design choice balances the scope of the science program, collider capabilities, accelerator technology innovation, and total project cost. An energy upgrade could be implemented in the future by adding two large collider rings housed in another large tunnel to push the center-of-mass energy up to or exceeding 140 GeV. After careful consideration of an alternative electron energy recovery linac on ion storage ring approach, a ring-ring collider scenario at high bunch repetition frequency was found to offer fully competitive performance while eliminating the uncertainties of challenging R&D on ampere-class polarized electron sources and many-pass energy-recovery linacs (ERLs). The essential new elements of an MEIC facility at Jefferson Lab are an electron storage ring and an entirely new, modern ion acceleration and storage complex. For the high-current electron collider ring, the upgraded 12 GeV CEBAF SRF linac will serve as a full-energy injector, and, if needed, provide top-off refilling. The CEBAF fixed-target nuclear physics program can be simultaneously operated since the filling time of the electron ring is very short. The ion complex for MEIC consists of sources for polarized light ions and unpolarized light to heavy ions, an SRF ion linac with proton energy up to 280 MeV, a 3 GeV prebooster synchrotron, a large booster synchrotron for proton energy up to 20 GeV, and a medium-energy collider ring with energy up to 100 GeV. The ion complex can accelerate other species of ions with corresponding energies at each accelerating stage. There are three collision points planned for MEIC. Two of them are for collisions with medium-energy ions; the third is for low energy ion beams stored in a dedicated low-energy compact storage ring, as a possible follow-on project.« less
Multifunctional carbon nanoelectrodes fabricated by focused ion beam milling.
Thakar, Rahul; Weber, Anna E; Morris, Celeste A; Baker, Lane A
2013-10-21
We report a strategy for fabrication of sub-micron, multifunctional carbon electrodes and application of these electrodes as probes for scanning electrochemical microscopy (SECM) and scanning ion conductance microscopy (SICM). The fabrication process utilized chemical vapor deposition of parylene, followed by thermal pyrolysis to form conductive carbon and then further deposition of parylene to form an insulation layer. To achieve well-defined electrode geometries, two methods of electrode exposure were utilized. In the first method, carbon probes were masked in polydimethylsiloxane (PDMS) to obtain a cone-shaped electrode. In the second method, the electrode area was exposed via milling with a focused ion beam (FIB) to reveal a carbon ring electrode, carbon ring/platinum disk electrode, or carbon ring/nanopore electrode. Carbon electrodes were batch fabricated (~35/batch) through the vapor deposition process and were characterized with scanning electron microscopy (SEM), scanning transmission electron microscopy (STEM), and cyclic voltammetry (CV) measurements. Additionally, Raman spectroscopy was utilized to examine the effects of Ga(+) ion implantation, a result of FIB milling. Constant-height, feedback mode SECM was performed with conical carbon electrodes and carbon ring electrodes. We demonstrate the utility of carbon ring/nanopore electrodes with SECM-SICM to simultaneously collect topography, ion current and electrochemical current images. In addition, carbon ring/nanopore electrodes were utilized in substrate generation/tip collection (SG/TC) SECM. In SG/TC SECM, localized delivery of redox molecules affords a higher resolution, than when the redox molecules are present in the bath solution. Multifunctional geometries of carbon electrode probes will find utility in electroanalytical applications, in general, and more specifically with electrochemical microscopy as discussed herein.
Crossed-beam velocity map imaging of collisional autoionization processes
NASA Astrophysics Data System (ADS)
Delmdahl, Ralph F.; Bakker, Bernard L. G.; Parker, David H.
2000-11-01
Applying the velocity map imaging technique Penning ion formation as well as generation of associative ions is observed in autoionizing collisions of metastable neon atoms (Ne* 2p5 3s 3P2,0) with ground state argon targets in a crossed molecular beam experiment. Metastable neon reactants are obtained by nozzle expansion through a dc discharge ring. The quality of the obtained results clearly demonstrates the suitability of this new, particularly straightforward experimental approach with respect to angle and kinetic energy resolved investigations of Penning processes in crossed-beam studies which are known to provide the highest level of detail.
Impact of Near-Earth Plasma Sheet Dynamics on the Ring Current Composition
NASA Astrophysics Data System (ADS)
Kistler, L. M.; Mouikis, C.; Menz, A.; Spence, H. E.; Mitchell, D. G.; Gkioulidou, M.; Lanzerotti, L. J.; Skoug, R. M.; Larsen, B.; Claudepierre, S. G.; Fennell, J. F.; Blake, J. B.
2014-12-01
How the dynamics in the near-earth plasma sheet affects the heavy ion content, and therefore the ion pressure, of the ring current in Earth's magnetosphere is an outstanding question. Substorms accelerate plasma in the near-earth region and drive outflow from the aurora, and both these processes can preferentially enhance the population of heavy ions in this region. These heavy ions are then driven into the inner magnetosphere during storms. Thus understanding how the composition of the ring current changes requires simultaneous observations in the near-earth plasma sheet and in the inner magnetosphere. We use data from the CODIF instrument on Cluster and HOPE, RBSPICE, and MagEIS instruments on the Van Allen Probes to study the acceleration and transport of ions from the plasma sheet into the ring current. During the main phase of a geomagnetic storm on Aug 4-6, 2013, the Cluster spacecraft were moving inbound in the midnight central plasma sheet, while the apogees of the two Van Allen Probes were located on the duskside. The Cluster spacecraft measure the composition and spectral changes in the plasma sheet, while the Van Allen Probes measure the ions that reach the inner magnetosphere. A strong increase in 1-40 keV O+ was observed at the Cluster location during the storm main phase, and the Van Allen Probes observed both H+ and O+ being driven deep into the inner magnetosphere. By comparing the variations in phase space density (PSD) vs. magnetic moment at the Cluster and the Van Allen Probes locations, we examine how the composition changes non-adiabatically in the near-earth plasma sheet, and how those changes are propagated into the inner magnetosphere, populating the hto ion ring current.
NASA Astrophysics Data System (ADS)
Ma, Lijun; Li, Yue; Li, Lei; Wu, Yuqing; Buchet, Rene; Ding, Yihong
2009-03-01
The detection of lead ion is very important both in environment and in biological systems because of its toxicity. A fluoroionophore sensor, N-[4(1-pyrene)-butyroyl]- L-tryptophan (PLT), distinguishing Pb 2+ from other 12 metal ions and exhibiting a very high sensitivity (0.15 μM) in aqueous solution, has been reported. The present study describes the spectroscopic clarification of the intrinsic differences of the binding model between PLT with Pb 2+ and with other ions. The fluorescent property of solid metal carboxylates reflects a character of the metal complex in solution, which results in a facility to solve problems by using solid sample of complex and vibrational spectroscopy. Both FT-infrared and Raman spectroscopy are employed to clarify the binding model between lead ion and its high sensitive and selective fluoroionophore sensor PLT, and essentially to explain why the metal ions other than Pb 2+ cannot response to PLT. The IR spectral data clearly show that a bridging bidentate coordination occurs when PLT is coordinated with Cu 2+ and Zn 2+; while a chelating bidentate coordination between the carboxyl anion and Pb 2+ exists in PLT-Pb, which is a new information beyond the NMR results in previous report. Meanwhile, the present study also indicates a characteristic interaction of lead ion and indole ring as well as the hydrogen bonding between amide groups. Furthermore, the quantum chemical calculations at the DFT level confirm the spectral and structural information of PLT-Pb 2+ proposed by experiments. Thus, the type of coordination, the interaction of the indole ring with the metal ion, and the hydrogen bonding between amide groups in PLT-Pb are likely responsible for the high selectivity of PLT to the lead(II) ion.
Ma, Lijun; Li, Yue; Li, Lei; Wu, Yuqing; Buchet, Rene; Ding, Yihong
2009-03-01
The detection of lead ion is very important both in environment and in biological systems because of its toxicity. A fluoroionophore sensor, N-[4(1-pyrene)-butyroyl]-l-tryptophan (PLT), distinguishing Pb(2+) from other 12 metal ions and exhibiting a very high sensitivity (0.15microM) in aqueous solution, has been reported. The present study describes the spectroscopic clarification of the intrinsic differences of the binding model between PLT with Pb(2+) and with other ions. The fluorescent property of solid metal carboxylates reflects a character of the metal complex in solution, which results in a facility to solve problems by using solid sample of complex and vibrational spectroscopy. Both FT-infrared and Raman spectroscopy are employed to clarify the binding model between lead ion and its high sensitive and selective fluoroionophore sensor PLT, and essentially to explain why the metal ions other than Pb(2+) cannot response to PLT. The IR spectral data clearly show that a bridging bidentate coordination occurs when PLT is coordinated with Cu(2+) and Zn(2+); while a chelating bidentate coordination between the carboxyl anion and Pb(2+) exists in PLT-Pb, which is a new information beyond the NMR results in previous report. Meanwhile, the present study also indicates a characteristic interaction of lead ion and indole ring as well as the hydrogen bonding between amide groups. Furthermore, the quantum chemical calculations at the DFT level confirm the spectral and structural information of PLT-Pb(2+) proposed by experiments. Thus, the type of coordination, the interaction of the indole ring with the metal ion, and the hydrogen bonding between amide groups in PLT-Pb are likely responsible for the high selectivity of PLT to the lead(II) ion.
Bunch Splitting Simulations for the JLEIC Ion Collider Ring
DOE Office of Scientific and Technical Information (OSTI.GOV)
Satogata, Todd J.; Gamage, Randika
2016-05-01
We describe the bunch splitting strategies for the proposed JLEIC ion collider ring at Jefferson Lab. This complex requires an unprecedented 9:6832 bunch splitting, performed in several stages. We outline the problem and current results, optimized with ESME including general parameterization of 1:2 bunch splitting for JLEIC parameters.
NASA Astrophysics Data System (ADS)
Min, K.; Liu, K.; Gary, S. P.
2017-12-01
The main challenge of the secondary ENA mechanism, a theory put forth to explain the IBEX ENA ribbon, is maintaining the stability of the pickup ion velocity distribution before the pickup ions in the outer heliosheath go through two consecutive charge exchanges. The Alfvén/ion-cyclotron instability, which has its maximum growth at propagation parallel to Bo, the background magnetic field, is believed to be the main agent leading to rapid isotropization of the pickup ions. However, recent studies found that this instability can be suppressed when parallel temperatures of the background plasma and the pickup ion ring distribution are comparable, allowing the pickup ion distribution to remain stable for a long period. This paper demonstrates that a pickup ion ring distribution can also drive the mirror and ion Bernstein instabilities which lead to growing modes at propagation oblique to Bo. For idealized proton-electron plasmas where relatively cool background electron and proton populations are represented by isotropic Maxwellian distributions and tenuous (1%) pickup protons are represented by a Maxwellian-ring distribution (assuming a 90˚ pickup angle), linear Vlasov theory predicts unstable mirror and ion Bernstein modes with growth rates comparable to or exceeding that of the Alfvén-cyclotron instability. According to quasilinear theory, interactions with these obliquely-propagating modes can lead to substantial pitch angle scattering of the ring protons. Two-dimensional hybrid (kinetic ions and massless fluid electrons) simulations are carried out to examine the nonlinear consequences of the mirror and Bernstein instabilities. The preliminary simulation results are presented. The study suggests a scenario that the oblique mirror and ion Bernstein modes can be an active agent of the pickup ion isotropization when the condition is such that the Alfvén-cyclotron instability is suppressed.
The impact of exospheric neutral dynamics on ring current decay
NASA Astrophysics Data System (ADS)
Ilie, R.; Liemohn, M. W.; Skoug, R. M.; Funsten, H. O.; Gruntman, M.; Bailey, J. J.; Toth, G.
2015-12-01
The geocorona plays an important role in the energy budget of the Earth's inner magnetosphere since charge exchange of energetic ions with exospheric neutrals makes the exosphere act as an energy sink for ring current particles. Long-term ring current decay following a magnetic storm is mainly due to these electron transfer reactions, leading to the formation energetic neutral atoms (ENAs) that leave the ring current system on ballistic trajectories. The number of ENAs emitted from a given region of space depends on several factors, such as the energy and species of the energetic ion population in that region and the density of the neutral gas with which the ions undergo charge exchange. However, the density and structure of the exosphere are strongly dependent on changes in atmospheric temperature and density as well as charge exchange with the ions of plasmaspheric origin, which depletes the geocorona (by having a neutral removed from the system). Moreover, the radiation pressure exerted by solar far-ultraviolet photons pushes the geocoronal hydrogen away from the Earth in an anti-sunward direction to form a tail of neutral hydrogen. TWINS ENA images provide a direct measurement of these ENA losses and therefore insight into the dynamics of the ring current decay through interactions with the geocorona. We assess the influence of geocoronal neutrals on ring current formation and decay by analysis of the predicted ENA emissions using 6 different geocoronal models and simulations from the HEIDI ring current model during storm time. Comparison with TWINS ENA images shows that the location of the peak ENA enhancements is highly dependent on the distribution of geocoronal hydrogen density. We show that the neutral dynamics has a strong influence on the time evolution of the ring current populations as well as on the formation of energetic neutral atoms.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Niemiec, J.; Florinski, V.; Heerikhuisen, J.
2016-08-01
The nearly circular ribbon of energetic neutral atom (ENA) emission discovered by NASA’s Interplanetary Boundary EXplorer satellite ( IBEX ), is most commonly attributed to the effect of charge exchange of secondary pickup ions (PUIs) gyrating about the magnetic field in the outer heliosheath (OHS) and the interstellar space beyond. The first paper in the series (Paper I) presented a theoretical analysis of the pickup process in the OHS and hybrid-kinetic simulations, revealing that the kinetic properties of freshly injected proton rings depend sensitively on the details of their velocity distribution. It was demonstrated that only rings that are notmore » too narrow (parallel thermal spread above a few km s{sup −1}) and not too wide (parallel temperature smaller than the core plasma temperature) could remain stable for a period of time long enough to generate ribbon ENAs. This paper investigates the role of electron dynamics and the extra spatial degree of freedom in the ring ion scattering process with the help of two-dimensional full particle-in-cell (PIC) kinetic simulations. A good agreement is observed between ring evolution under unstable conditions in hybrid and PIC models, and the dominant modes are found to propagate parallel to the magnetic field. We also present more realistic ribbon PUI distributions generated using Monte Carlo simulations of atomic hydrogen in the global heliosphere and examine the effect of both the cold ring-like and the hot “halo” PUIs produced from heliosheath ENAs on the ring stability. It is shown that the second PUI population enhances the fluctuation growth rate, leading to faster isotropization of the solar-wind-derived ring ions.« less
NASA Astrophysics Data System (ADS)
Niemiec, J.; Florinski, V.; Heerikhuisen, J.; Nishikawa, K.-I.
2016-08-01
The nearly circular ribbon of energetic neutral atom (ENA) emission discovered by NASA’s Interplanetary Boundary EXplorer satellite (IBEX), is most commonly attributed to the effect of charge exchange of secondary pickup ions (PUIs) gyrating about the magnetic field in the outer heliosheath (OHS) and the interstellar space beyond. The first paper in the series (Paper I) presented a theoretical analysis of the pickup process in the OHS and hybrid-kinetic simulations, revealing that the kinetic properties of freshly injected proton rings depend sensitively on the details of their velocity distribution. It was demonstrated that only rings that are not too narrow (parallel thermal spread above a few km s-1) and not too wide (parallel temperature smaller than the core plasma temperature) could remain stable for a period of time long enough to generate ribbon ENAs. This paper investigates the role of electron dynamics and the extra spatial degree of freedom in the ring ion scattering process with the help of two-dimensional full particle-in-cell (PIC) kinetic simulations. A good agreement is observed between ring evolution under unstable conditions in hybrid and PIC models, and the dominant modes are found to propagate parallel to the magnetic field. We also present more realistic ribbon PUI distributions generated using Monte Carlo simulations of atomic hydrogen in the global heliosphere and examine the effect of both the cold ring-like and the hot “halo” PUIs produced from heliosheath ENAs on the ring stability. It is shown that the second PUI population enhances the fluctuation growth rate, leading to faster isotropization of the solar-wind-derived ring ions.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Hahn, M.; Novotny, O.; Savin, D. W.
2013-04-10
We report measurements of electron impact ionization for Fe{sup 13+}, Fe{sup 16+}, and Fe{sup 17+} over collision energies from below threshold to above 3000 eV. The ions were recirculated using an ion storage ring. Data were collected after a sufficiently long time that essentially all the ions had relaxed radiatively to their ground state. For single ionization of Fe{sup 13+}, we find that previous single pass experiments are more than 40% larger than our results. Compared to our work, the theoretical cross section recommended by Arnaud and Raymond is more than 30% larger, while that of Dere is about 20%more » greater. Much of the discrepancy with Dere is due to the theory overestimating the contribution of excitation-autoionization via n = 2 excitations. Double ionization of Fe{sup 13+} is dominated by direct ionization of an inner shell electron accompanied by autoionization of a second electron. Our results for single ionization of Fe{sup 16+} and Fe{sup 17+} agree with theoretical calculations to within the experimental uncertainties.« less
NASA Astrophysics Data System (ADS)
Mitani, K.; Seki, K.; Keika, K.; Gkioulidou, M.; Lanzerotti, L. J.; Mitchell, D. G.; Kletzing, C.
2017-12-01
It is known that proton is main contributor of the ring current and oxygen ions can make significant contribution during major magnetic storms. Ions are supplied to the ring current by radial transport from the plasma sheet. Convective transport of lower-energy protons and diffusive transport of higher-energy protons were reported to contribute to the storm-time and quiet-time ring current respectively [e.g., Gkioulidou et al., 2016]. However, supply mechanisms of the oxygen ions are not clear. To characterize the supply of oxygen ions to the ring current during magnetic storms, we studied the properties of energetic proton and oxygen ion phase space densities (PSDs) for specific magnetic moment (μ) during the April 23-25, 2013, geomagnetic storm observed by the Van Allen Probes mission. We here report on radial transport of high-energy (μ ≥ 0.5 keV/nT) oxygen ions into the deep inner magnetosphere during the late main phase of the magnetic storm. Since protons show little change during this period, this oxygen radial transport is inferred to cause the development of the late main phase. Enhancement of poloidal magnetic fluctuations is simultaneously observed. We estimated azimuthal mode number ≤5 by using cross wavelet analysis with ground-based observation of IMAGE ground magnetometers. The fluctuations can resonate with drift and bounce motions of the oxygen ions. The results suggest that combination of the drift and drift-bounce resonances is responsible for the radial transport of high-energy oxygen ions into the deep inner magnetosphere. We also report on the radial transport of the high-energy oxygen ions into the deep inner magnetosphere during other magnetic storms.
The Abort Kicker System for the PEP-II Storage Rings at SLAC.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Delamare, Jeffrey E
2003-06-20
The PEP-II project has two storage rings. The HER (High Energy Ring) has up to 1.48 A of election beam at 9 GeV, and the LER (Low Energy Ring) has up to 2.14 A of positron beam at 3.1 GeV. To protect the HER and LER beam lines in the event of a ring component failure, each ring has an abort kicker system which directs the beam into a dump when a failure is detected. Due to the high current of the beams, the beam kick is tapered from 100% to 80% in 7.33 {micro}S (the beam transit time aroundmore » the ring). This taper distributes the energy evenly across the window which separates the ring from the beam dump such that the window is not damaged. The abort kicker trigger is synchronized with the ion clearing gap of the beam allowing for the kicker field to rise from 0-80% while there is no beam in the kicker magnet. Originally the kicker system was designed for a rise time of 370nS [1], but because the ion clearing gap was reduced in half, so was the rise time requirement for the kicker. This report discusses the design of the system interlocks, diagnostics, and modulator with the modifications necessary to accommodate an ion clearing gap of 185nS.« less
Miniature ion thruster ring-cusp discharge performance and behavior
NASA Astrophysics Data System (ADS)
Dankongkakul, Ben; Wirz, Richard E.
2017-12-01
Miniature ion thrusters are an attractive option for a wide range of space missions due to their low power levels and high specific impulse. Thrusters using ring-cusp plasma discharges promise the highest performance, but are still limited by the challenges of efficiently maintaining a plasma discharge at such small scales (typically 1-3 cm diameter). This effort significantly advances the understanding of miniature-scale plasma discharges by comparing the performance and xenon plasma confinement behavior for 3-ring, 4-ring, and 5-ring cusp by using the 3 cm Miniature Xenon Ion thruster as a modifiable platform. By measuring and comparing the plasma and electron energy distribution maps throughout the discharge, we find that miniature ring-cusp plasma behavior is dominated by the high magnetic fields from the cusps; this can lead to high loss rates of high-energy primary electrons to the anode walls. However, the primary electron confinement was shown to considerably improve by imposing an axial magnetic field or by using cathode terminating cusps, which led to increases in the discharge efficiency of up to 50%. Even though these design modifications still present some challenges, they show promise to bypassing what were previously seen as inherent limitations to ring-cusp discharge efficiency at miniature scales.
Hadron Physics with PANDA at FAIR
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wiedner, Ulrich
2011-10-21
The recently established FAIR facility in Darmstadt has a broad program in the field of hadron and nuclear physics utilizing ion beams with unprecedented intensity and accuracy. The PANDA experiment, which is integrated in the HESR storage ring for antiprotons is at the center of the hadron physics program. It includes among others topics like hadron spectroscopy in the charmonium mass region and below, hyperon physics and electromagnetic processes.
NASA Technical Reports Server (NTRS)
Ipavich, F. M.
1990-01-01
The Univ. of Maryland portion investigated the following areas. The Space Physics Group performed studies of data from the AMPTE/CCE spacecraft CHEM experiment and found that the ratio of solar wind to photospheric abundances decreased rather smoothly with the first ionization potential (FIP) of the ion with the low FIP ion being about a factor of two overabundant. Carbon and hydrogen fit this trend particularly well. Several occurrences were analyzed of field aligned beams observed when CCE was upstream of the Earth's bow shock. Also using CHEM data, ring current intensity and composition changes during the main and recovery phases of the great geomagnetic storm that occurred in February 1986 was examined in detail. Still using CHEM data, ring current characteristics were examined in a survey of 20 magnetic storms ranging in size from -50 nT to -312 nT. A study was done of energetic ion anisotropy characteristics in the Earth's magnetosheath region using data from the UMD/MPE experiment on ISEE-1. The properties were analyzed of approx. 30 to 130 keV/e protons and alpha particles upstream of six quasi-parallel interplanetary shocks that passed by the ISEE-3 spacecraft during 1978 to 1979. Work from NASA-Goddard include studies from the High Energy Cosmic Ray Group, Low Energy Cosmic Ray Group, Low Energy Gamma Ray Group, High Energy Astrophysics Theory Group, and the X ray Astronomy Group.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bogacz, Alex
Baseline design of the JLEIC booster synchrotron is presented. Its aim is to inject and accumulate heavy ions and protons at 285 MeV, to accelerate them to about 7 GeV, and finally to extract the beam into the ion collider ring. The Figure-8 ring features two 2600 achromatic arcs configured with negative momentum compaction optics, designed to avoid transition crossing for all ion species during the course of acceleration. The lattice also features a specialized high dispersion injection insert optimized to facilitate the transverse phase-space painting in both planes for multi-turn ion injection. Furthermore, the lattice has been optimized tomore » ease chromaticity correction with two families of sextupoles in each plane. The booster ring is configured with super-ferric, 3 Tesla bends. We are presently launching optimization of the booster synchrotron design to operate in the extreme space-charge dominated regime.« less
Double-ring structure formation of intense ion beams with finite radius in a pre-formed plasma
NASA Astrophysics Data System (ADS)
Hu, Zhang-Hu; Wang, Xiao-Juan; Zhao, Yong-Tao; Wang, You-Nian
2017-12-01
The dynamic structure evolution of intense ion beams with a large edge density gradient is investigated in detail with an analytical model and two-dimensional particle-in-cell (PIC) simulations, with special attention paid to the influence of beam radius. At the initial stage of beam-plasma interactions, the ring structure is formed due to the transverse focusing magnetic field induced by the unneutralized beam current in the beam edge region. As the beam-plasma system evolves self-consistently, a second ring structure appears in the case of ion beams with a radius much larger than the plasma skin depth, due to the polarity change in the transverse magnetic field in the central regions compared with the outer, focusing field. Influences of the current-filamentation and two-stream instability on the ring structure can be clearly observed in PIC simulations by constructing two different simulation planes.
NASA Technical Reports Server (NTRS)
Richardson, R. W.
1974-01-01
The modified Penning discharge in the NASA Lewis Bumpy Torus is normally produced by an anode ring at high voltage in each of the 12 magnetic mirror midplanes. For this investigation, the plasma was run with 12, 6, 3, and 1 anode rings. When 3 anode rings were used, the spectroscopically determined relative electron density and mean ion residence time increased by factors of 10 and 5, respectively, in one mode of operation. The discharge is observed to uniformly fill all bumps around the torus regardless of the anode arrangement and number. A plasma density on axis of 100 billion per cu cm is estimated for the 3-anode case in one mode of operation based on an observed discharge current to ion loss rate correlation and a measured mean ion residence time of .5 msec.
NASA Technical Reports Server (NTRS)
Richardson, R. W.
1974-01-01
The modified Penning discharge in the NASA Lewis Bumpy Torus is normally produced by an anode ring at high voltage in each of the 12 magnetic mirror midplanes. For this investigation, the plasma was run with 12, 6, 3, and 1 anode rings. When 3 anode rings were used, the spectroscopically determined relative electron density and mean ion residence time increase by factors of 10 and 5, respectively, in one mode of operation. The discharge is observed to uniformly fill all bumps around the torus regardless of the anode arrangement and number. A plasma density on axis of 10 to the 11th power cm/3 is estimated for the 3 anode case in one mode of operation based on an observed discharge current to ion loss rate correlation and a measured mean ion residence time of .5 msec.
Dust characteristics of dusty plasma ring of Saturn
NASA Astrophysics Data System (ADS)
Morooka, M.; Wahlund, J.-E.; Ye, S.-Y.; Persoon, A. M.; Kurth, W. S.
2017-09-01
During the Ring Grazing orbit, starting from December 2016, Cassini carried out twenty of the faint Saturn ring crossing observations at the distance of 2.45-2.51 RS (1RS 60,268 km) from Saturn center. We will show the electron and the ion density measurements of the RPWS/Langmuir Probe (LP) during these orbits. In most of the orbits significant ion/electron density differences have been observed, which indicates the presence of the charged nm and µm sized grains. The relationship between the observed charge densities and the electrical potential of the grains shows that the grains and the ambient electrons and ions are electro dynamical ensemble, a dusty plasma. The results show that characteristic dust size changes depending on the distance from the ring center. The result suggests that a dusty plasma state is related to the dynamics of the grain sizes.
Predicting electromagnetic ion cyclotron wave amplitude from unstable ring current plasma conditions
Fu, Xiangrong; Cowee, Misa M.; Jordanova, Vania K.; ...
2016-11-01
Electromagnetic ion cyclotron (EMIC) waves in the Earth's inner magnetosphere are enhanced fluctuations driven unstable by ring current ion temperature anisotropy. EMIC waves can resonate with relativistic electrons and play an important role in precipitation of MeV radiation belt electrons. In this study, we investigate the excitation and saturation of EMIC instability in a homogeneous plasma using both linear theory and nonlinear hybrid simulations. We have explored a four-dimensional parameter space, carried out a large number of simulations, and derived a scaling formula that relates the saturation EMIC wave amplitude to initial plasma conditions. Finally, such scaling can be usedmore » in conjunction with ring current models like ring current-atmosphere interactions model with self-consistent magnetic field to provide global dynamic EMIC wave maps that will be more accurate inputs for radiation belt modeling than statistical models.« less
Transfer matrix calculation for ion optical elements using real fields
NASA Astrophysics Data System (ADS)
Mishra, P. M.; Blaum, K.; George, S.; Grieser, M.; Wolf, A.
2018-03-01
With the increasing importance of ion storage rings and traps in low energy physics experiments, an efficient transport of ion species from the ion source area to the experimental setup becomes essential. Some available, powerful software packages rely on transfer matrix calculations in order to compute the ion trajectory through the ion-optical beamline systems of high complexity. With analytical approaches, so far the transfer matrices are documented only for a few ideal ion optical elements. Here we describe an approach (using beam tracking calculations) to determine the transfer matrix for any individual electrostatic or magnetostatic ion optical element. We verify the procedure by considering the well-known cases and then apply it to derive the transfer matrix of a 90-degree electrostatic quadrupole deflector including its realistic geometry and fringe fields. A transfer line consisting of a quadrupole deflector and a quadrupole doublet is considered, where the results from the standard first order transfer matrix based ion optical simulation program implementing the derived transfer matrix is compared with the real field beam tracking simulations.
NASA Astrophysics Data System (ADS)
Chen, Shu-Ting; Her, Guor-Rong
2012-08-01
A strategy based on negative ion electrospray ionization tandem mass spectrometry and closed-ring labeling with both 8-aminopyrene-1,3,6-trisulfonate (APTS) and p-aminobenzoic acid ethyl ester (ABEE) was developed for linkage and branch determination of high-mannose oligosaccharides. X-type cross-ring fragment ions obtained from APTS-labeled oligosaccharides by charge remote fragmentation provided information on linkages near the non-reducing terminus. In contrast, A-type cross-ring fragment ions observed from ABEE-labeled oligosaccharides yielded information on linkages near the reducing terminus. This complementary information provided by APTS- and ABEE-labeled oligosaccharides was utilized to delineate the structures of the high-mannose oligosaccharides. As a demonstration of this approach, the linkages and branches of high-mannose oligosaccharides Man5GlcNAc2, Man6GlcNAc2, Man8GlcNAc2, and Man9GlcNAc2 cleaved from the ribonuclease B were assigned from MS2 spectra of ABEE- and APTS-labeled derivatives.
NASA Technical Reports Server (NTRS)
Khazanov, G. V.; Gamayunov, K. V.; Jordanova, V. K.
2003-01-01
Complete description of a self-consistent model for magnetospheric ring current interacting with electromagnetic ion cyclotron waves is presented. The model is based on the system of two kinetic equations; one equation describes the ring current ion dynamics, and another equation describes the wave evolution. The effects on ring current ions interacting with electromagnetic ion cyclotron waves, and back on waves, are considered self-consistently by solving both equations on a global magnetospheric scale under non steady-state conditions. In the paper by Khazanov et al. [2002] this self-consistent model has only been shortly outlined, and discussions of many the model related details have been omitted. For example, in present study for the first time a new algorithm for numerical finding of the resonant numbers for quasilinear wave-particle interaction is described, or it is demonstrated that in order to describe quasilinear interaction in a multi-ion thermal plasma correctly, both e and He(+) modes of electromagnetic ion cyclotron waves should be employed. The developed model is used to simulate the entire May 2-7, 1998 storm period. Trapped number fluxes of the ring current protons are calculated and presented along with their comparison with the data measured by the 3D hot plasma instrument Polar/HYDRA. Examining of the wave (MLT, L shell) distributions produced during the storm progress reveals an essential intensification of the wave emissions in about two days after main phase of storm. This result is well consistent with the earlier ground-based observations. Also the theoretical shapes and the occurrence rates for power spectral densities of electromagnetic ion cyclotron waves are studied. It is found that in about 2 days after the storm main phase on May 4, mainly non Gaussian shapes of power spectral densities are produced.
Tomita, T; Ishikawa, D; Noguchi, T; Katayama, E; Hashimoto, Y
1998-07-01
Flammutoxin has been previously isolated as a cardiotoxic and cytolytic polypeptide of 22 or 32 kDa from the fruiting bodies of the edible mushroom Flammulina velutipes. In the present study, we purified flammutoxin as a single haemolytic protein of 31 kDa and studied the mode of its cytolytic action. (1) Flammutoxin caused efflux of potassium ions from human erythrocytes and swelling of the cells before haemolysis. (2) Flammutoxin did not lyse human erythrocytes in the presence of non-electrolytes with hydrodynamic diameters of >5.0 nm, although it caused leakage of potassium ions and swelling of the cells under the same conditions. (3) Experiments including solubilization of cell-bound toxin with 2% (w/v) SDS at 20 degrees C and subsequent Western immunoblots showed that flammutoxin formed a band corresponding to 180 kDa under the conditions where it lysed erythrocytes. (4) Electron microscopy of flammutoxin-treated human erythrocytes revealed the presence of a ring-shaped structure with outer and inner diameters of 10 and 5 nm, respectively, on the cells. (5) A ring-shaped toxin oligomer of the same dimensions was solubilized from the toxin-treated human erythrocytes with 2% (w/v) SDS at 20 degrees C and isolated by a sucrose-gradient ultracentrifugation. These data indicated that flammutoxin assembles into a ring-shaped oligomer possessing a hydrophilic pore of 4-5 nm on target cells.
Atkinson, Andrew J.; Logantha, Sunil Jit R. J.; Hao, Guoliang; Yanni, Joseph; Fedorenko, Olga; Sinha, Aditi; Gilbert, Stephen H.; Benson, Alan P.; Buckley, David L.; Anderson, Robert H.; Boyett, Mark R.; Dobrzynski, Halina
2013-01-01
Background The cardiac conduction system consists of the sinus node, nodal extensions, atrioventricular (AV) node, penetrating bundle, bundle branches, and Purkinje fibers. Node‐like AV ring tissue also exists at the AV junctions, and the right and left rings unite at the retroaortic node. The study aims were to (1) construct a 3‐dimensional anatomical model of the AV rings and retroaortic node, (2) map electrical activation in the right ring and study its action potential characteristics, and (3) examine gene expression in the right ring and retroaortic node. Methods and Results Three‐dimensional reconstruction (based on magnetic resonance imaging, histology, and immunohistochemistry) showed the extent and organization of the specialized tissues (eg, how the AV rings form the right and left nodal extensions into the AV node). Multiextracellular electrode array and microelectrode mapping of isolated right ring preparations revealed robust spontaneous activity with characteristic diastolic depolarization. Using laser microdissection gene expression measured at the mRNA level (using quantitative PCR) and protein level (using immunohistochemistry and Western blotting) showed that the right ring and retroaortic node, like the sinus node and AV node but, unlike ventricular muscle, had statistically significant higher expression of key transcription factors (including Tbx3, Msx2, and Id2) and ion channels (including HCN4, Cav3.1, Cav3.2, Kv1.5, SK1, Kir3.1, and Kir3.4) and lower expression of other key ion channels (Nav1.5 and Kir2.1). Conclusions The AV rings and retroaortic node possess gene expression profiles similar to that of the AV node. Ion channel expression and electrophysiological recordings show the AV rings could act as ectopic pacemakers and a source of atrial tachycardia. PMID:24356527
Takahashi, Kazunori
2012-08-01
A radiofrequency (rf) antenna for helicon plasma thruster experiments is developed and tested using a permanent magnets helicon plasma source immersed in a vacuum chamber. A magnetic nozzle is provided by permanent magnets arrays and an argon plasma is produced by a 13.56 MHz radiofrequency helicon-wave or inductively-coupled discharge. A parasitic discharge outside the source tube is successfully suppressed by covering the rf antenna with a ceramic ring and a grounded shield; a decrease in the ion saturation current of a Langmuir probe located outside the source tube is observed and the ion saturation current on axis increases simultaneously, compared with the case of a standard uncovered rf antenna. It is also demonstrated that the covered antenna can yield stable operation of the source.
NASA Technical Reports Server (NTRS)
Khazanov, G. V.; Gamayunov, K. V.; Jordanova, V. K.
2003-01-01
A complete description of a self-consistent model of magnetospheric ring current interacting with electromagnetic ion cyclotron waves is presented. The model is based on the system of two kinetic equations; one equation describes the ring current ion dynamics, and another equation describes the wave evolution. The effects on ring current ions interacting with electromagnetic ion cyclotron waves and back on waves are considered self-consistently by solving both equations on a global magnetospheric scale under nonsteady state conditions. The developed model is employed to simulate the entire 2-7 May 1998 storm period. First, the trapped number fluxes of the ring current protons are calculated and presented along with comparison with the data measured by the three- dimensional hot plasma instrument Polar/HYDRA. Incorporating in the model the wave-particle interaction leads to much better agreement between the experimental data and the model results. Second, examining of the wave (MLT, L shell) distributions produced by the model during the storm progress reveals an essential intensification of the wave emission about 2 days after the main phase of the storm. This result is well consistent with the earlier ground-based observations. Finally, the theoretical shapes and the occurrence rates of the wave power spectral densities are studied. It is found that about 2 days after the storm s main phase on 4 May, mainly non-Gaussian shapes of power spectral densities are produced.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Das, Ujjal; Zhang, Guanghui; Hu, Bo
2015-10-28
Amorphous silica (SiO 2) is commonly used as a support in heterogeneous catalysis. However, due to the structural disorder and temperature induced change of surface morphology, the structures of silica supported metal catalysts are difficult to determine. Most studies are primarily focused on understanding the interactions of different types of surface hydroxyl groups with metal ions. In comparison, the effect of siloxane ring size on the structure of silica supported metal catalysts and how it affects catalytic activity is poorly understood. Here, we have used density functional theory calculations to understand the effect of siloxane ring strain on structure andmore » activity of different monomeric Lewis acid metal sites on silica. In particular, we have found that large siloxane rings favor strong dative bonding interaction between metal ion and surface hydroxyls, leading to the formation of high-coordinate metal sites. In comparison, metal-silanol interaction is weak in small siloxane rings, resulting in low-coordinate metal sites. The physical origin of this size dependence is associated with siloxane ring strain, and, a correlation between metal-silanol interaction energy and ring strain energy has been observed. In addition to ring strain, the strength of the metal-silanol interaction also depends on the positive charge density of the cations. In fact, a correlation also exists between metal-silanol interaction energy and charge density of several first-row transition and post-transition metals. The theoretical results are compared with the EXAFS data of monomeric Zn(II) and Ga(III) ions grafted on silica. In conclusion, the molecular level insights of how metal ion coordination on silica depends on siloxane ring strain and cation charge density will be useful in the synthesis of new catalysts.« less
Simulations of phase space distributions of storm time proton ring current
NASA Technical Reports Server (NTRS)
Chen, Margaret W.; Lyons, Larry R.; Schulz, Michael
1994-01-01
We use results of guiding-center simulations of ion transport to map phase space densities of the stormtime proton ring current. We model a storm as a sequence of substorm-associated enhancements in the convection electric field. Our pre-storm phase space distribution is an analytical solution to a steady-state transport model in which quiet-time radial diffusion balances charge exchange. This pre-storm phase space spectra at L approximately 2 to 4 reproduce many of the features found in observed quiet-time spectra. Using results from simulations of ion transport during model storms having main phases of 3, 6, and 12 hr, we map phase space distributions from the pre-storm distribution in accordance with Liouville's theorem. We find stormtime enhancements in the phase space densities at energies E approximately 30-160 keV for L approximately 2.5 to 4. These enhancements agree well with the observed stormtime ring current. For storms with shorter main phases (approximately 3 hr), the enhancements are caused mainly by the trapping of ions injected from open night side trajectories, and diffusive transport of higher-energy (greater than or approximately 160 keV) ions contributes little to the stormtime ring current. However, the stormtime ring current is augmented also by the diffusive transport of higher-energy ions (E greater than or approximately 160 keV) durinng stroms having longer main phases (greater than or approximately 6 hr). In order to account for the increase in Dst associated with the formation of the stormtime ring current, we estimate the enhancement in particle-energy content that results from stormtime ion transport in the equatorial magnetosphere. We find that transport alone cannot account for the entire increase in absolute value of Dst typical of a major storm. However, we can account for the entire increase in absolute value of Dst by realistically increasing the stormtime outer boundary value of the phase space density relative to the quiet-time value. We compute the magnetic field produced by the ring current itself and find that radial profiles of the magnetic field depression resemble those obtained from observational data.
NASA Astrophysics Data System (ADS)
Yuan, Zhigang; Deng, Xiaohua; Lin, Xi; Pang, Ye; Zhou, Meng; Décréau, P. M. E.; Trotignon, J. G.; Lucek, E.; Frey, H. U.; Wang, Jingfang
2010-04-01
In this paper, we report observations from a Cluster satellite showing that ULF wave occurred in the outer boundary of a plasmaspheric plume on September 4, 2005. The band of observed ULF waves is between the He+ ion gyrofrequency and O+ ion gyrofrequency at the equatorial plane, implying that those ULF waves can be identified as EMIC waves generated by ring current ions in the equatorial plane and strongly affected by rich cold He+ ions in plasmaspheric plumes. During the interval of observed EMIC waves, the footprint of Cluster SC3 lies in a subauroral proton arc observed by the IMAGE FUV instrument, demonstrating that the subauroral proton arc was caused by energetic ring current protons scattered into the loss cone under the Ring Current (RC)-EMIC interaction in the plasmaspheric plume. Therefore, the paper provides a direct proof that EMIC waves can be generated in the plasmaspheric plume and scatter RC ions to cause subauroral proton arcs.
High-precision x-ray spectroscopy of highly charged ions with microcalorimeters
NASA Astrophysics Data System (ADS)
Kraft-Bermuth, S.; Andrianov, V.; Bleile, A.; Echler, A.; Egelhof, P.; Grabitz, P.; Ilieva, S.; Kilbourne, C.; Kiselev, O.; McCammon, D.; Meier, J.
2013-09-01
The precise determination of the energy of the Lyman α1 and α2 lines in hydrogen-like heavy ions provides a sensitive test of quantum electrodynamics in very strong Coulomb fields. To improve the experimental precision, the new detector concept of microcalorimeters is now exploited for such measurements. Such detectors consist of compensated-doped silicon thermistors and Pb or Sn absorbers to obtain high quantum efficiency in the energy range of 40-70 keV, where the Doppler-shifted Lyman lines are located. For the first time, a microcalorimeter was applied in an experiment to precisely determine the transition energy of the Lyman lines of lead ions at the experimental storage ring at GSI. The energy of the Ly α1 line E(Ly-α1, 207Pb81+) = (77937 ± 12stat ± 25syst) eV agrees within error bars with theoretical predictions. To improve the experimental precision, a new detector array with more pixels and better energy resolution was equipped and successfully applied in an experiment to determine the Lyman-α lines of gold ions 197Au78+.
NASA Technical Reports Server (NTRS)
Roth, J. R.; Richardson, R. W.; Gerdin, G. A.
1973-01-01
Initial results were obtained from low power operation of the NASA Lewis Bumpy Torus experiment, in which a steady-state ion heating method based on the modified Penning discharge is applied in a bumpy torus confinement geometry. The magnet facility consists of 12 superconducting coils, each 19 cm i.d. and capable of 3.0 T, equally spaced in a toroidal array 1.52 m in major diameter. A 18 cm i.d. anode ring is located at each of the 12 midplanes and is maintained at high positive potentials by a dc power supply. Initial observations indicate electron temperatures from 10 to 150 eV, and ion kinetic temperatures from 200 eV to 1200 eV. Two modes of operation were observed, which depend on background pressure, and have different radial density profiles. Steady state neutron production was observed. The ion heating process in the bumpy torus appears to parallel closely the mechanism observed when the modified Penning discharge was operated in a simple magnetic mirror field.
Hassan, Ayorinde; Dinadayalane, Tandabany C; Grabowski, Sławomir J; Leszczynski, Jerzy
2013-12-28
The effect of increasing the number of monocyclic six-membered rings or bicyclic rings of bicyclo[2.1.1]hexenyl fused to benzene on cation-π interactions involving alkali metal ions (Li(+), Na(+), and K(+)) has been investigated. The binding energy data at the B3LYP/6-311+G(2d,2p) level clearly indicate that the binding affinity of the metal ion with benzene is enhanced by increasing the number of rings fused irrespective of a monocyclic or a bicyclic ring. Calculated binding energies are in good agreement with the available experimental results. The binding strength of cations with ligands decreases in the order Li(+) > Na(+) > K(+). Our study establishes that trisannelation of bicyclo[2.1.1]hexene to benzene facilitates a very strong interaction between benzene and cations. Infrared (IR) frequencies and nuclear magnetic resonance (NMR) chemical shifts are shown to be valuable in characterizing cation-π interactions. The C-C bonds of the central six-membered rings are weakened due to metal ion binding. Based on the Quantum Theory of Atoms in Molecules (QTAIM), we have observed the presence of stabilizing H∙∙∙H interactions in two of the considered systems as opposed to the frequent description of these interactions as non-bonded repulsive interactions. Alkali metal ion binding with those two ligands slightly reduces the strength of such H∙∙∙H interactions.
Mechanisms of Ionospheric Mass Escape
NASA Technical Reports Server (NTRS)
Moore, T. E.; Khazanov, G. V.
2010-01-01
The dependence of ionospheric O+ escape flux on electromagnetic energy flux and electron precipitation into the ionosphere is derived for a hypothetical ambipolar pick-up process, powered the relative motion of plasmas and neutral upper atmosphere, and by electron precipitation, at heights where the ions are magnetized but influenced by photo-ionization, collisions with gas atoms, ambipolar and centrifugal acceleration. Ion pick-up by the convection electric field produces "ring-beam" or toroidal velocity distributions, as inferred from direct plasma measurements, from observations of the associated waves, and from the spectra of incoherent radar echoes. Ring-beams are unstable to plasma wave growth, resulting in rapid relaxation via transverse velocity diffusion, into transversely accelerated ion populations. Ion escape is substantially facilitated by the ambipolar potential, but is only weakly affected by centrifugal acceleration. If, as cited simulations suggest, ion ring beams relax into non-thermal velocity distributions with characteristic speed equal to the local ion-neutral flow speed, a generalized "Jeans escape" calculation shows that the escape flux of ionospheric O+ increases with Poynting flux and with precipitating electron density in rough agreement with observations.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Santana, J A; Ishikawa, Y; Tr�abert, E
2009-02-26
Ground configuration and low-lying levels of Al-like ions contribute to a variety of laboratory and solar spectra, but the available information in databases are neither complete not necessarily correct. We have performed multireference Moeller-Plesset perturbation theory calculations that approach spectroscopic accuracy in order to check the information that databases hold on the 40 lowest levels of Al-Like ions of iron group elements (K through Ge), and to provide input for the interpretation of concurrent experiments. Our results indicate problems of the database holdings on the levels of the lowest quartet levels in the lighter elements of the range studied. Themore » results of our calculations of the decay rates of five long-lived levels (3s{sup 2}3p {sup 2}p{sup o}{sub 3/2}, 3s3p{sup 2} {sup 4}P{sup o} J and 3s3p3d {sup 4}F{sup o}{sub 9/2}) are compared with lifetime data from beam-foil, electron beam ion trap and heavy-ion storage ring experiments.« less
Nonlinear Delta-f Simulations of Collective Effects in Intense Charged Particle Beams
NASA Astrophysics Data System (ADS)
Qin, Hong
2002-11-01
A nonlinear delta-f particle simulation method based on the Vlasov-Maxwell equations has been recently developed to study collective processes in high-intensity beams, where space-charge and magnetic self-field effects play a critical role in determining the nonlinear beam dynamics. Implemented in the Beam Equilibrium, Stability and Transport (BEST) code, the nonlinear delta-f method provides a low-noise and self-consistent tool for simulating collective interactions and nonlinear dynamics of high-intensity beams in modern and next- generation accelerators and storage rings, such as the Spallation Neutron Source, and heavy ion fusion drivers. Simulation results for the electron-proton two-stream instability in the Proton Storage Ring (PSR) experiment at Los Alamos National Laboratory agree well with experimental observations. Large-scale parallel simulations have also been carried out for the ion-electron two-stream instability in the very high-intensity heavy ion beams envisioned for heavy ion fusion applications. In both cases, the simulation results indicate that the dominant two-stream instability has a dipole-mode (hose-like) structure and can be stabilized by a modest axial momentum spread of the beam particles of less than 0.25collective processes in high-intensity beams, such as anisotropy-driven instabilities, collective eigenmode excitations for perturbations about stable beam equilibria, and the Darwin model for fully electromagnetic perturbations will also be discussed.
Time-lag and Correlation between ACE and RBSPICE Injection Event Observations during Storm Times
NASA Astrophysics Data System (ADS)
Madanian, H.; Patterson, J. D.; Manweiler, J. W.; Soto-chavez, A. R.; Gerrard, A. J.; Lanzerotti, L. J.
2017-12-01
The Radiation Belt Storm Probes Ion Composition Experiment (RBSPICE) on the Van Allen Probes mission measures energetic charged particles [ 20 keV to 1 MeV] in the inner magnetosphere and ring current. During geomagnetic storms, injections of energetic ions into the ring current change the ion population and produce geomagnetic field depressions on Earth's surface. We analyzed the magnetic field strength and particle composition in the interplanetary medium measured by instruments on the Advanced Composition Explorer (ACE) spacecraft near the inner Lagrangian point. The Electron, Proton, and Alpha Monitor-Low Energy Magnetic Spectrometer (EPAM-LEMS) sensor on ACE measures energetic particles [ 50 keV to 5 MeV] in the interplanetary space. The SYM-H index is utilized to classify the storm events by magnitude and to select more than 60 storm events between 2013 and 2017. We cross-compared ACE observations at storm times, with the RBSPICE ion measurements at dusk to midnight magnetic local time and over the 3-6 L-shell range. We report on the relative composition of the solar particles and the relative composition of the inner magnetospheric hot plasma during storm times. The data correlation is accomplished by shifting the observation time from ACE to RBSPICE using the solar wind velocity at the time of the observation. We will discuss time lags between storm onset at the magnetopause and injection events measured for each storm.
Structural effects of Cu(II)-coordination in the octapeptide region of the human prion protein.
Riihimäki, Eva-Stina; Martínez, José Manuel; Kloo, Lars
2008-05-14
The copper-binding ability of the prion protein is thought to be central to its function. The structural effects of copper coordination in the octapeptide region of the human prion protein have been investigated by molecular dynamics simulations. Simulations were performed with the apo state, in order to investigate the behavior of the region without copper ions, as well as with the octapeptide region in the presence of copper ions. While the structure of the apo state is greatly influenced by the interaction between the rings in the histidine, tryptophan and proline residues, the region shows evidence of highly ordered coordination sites in the presence of copper ions. The position of the tryptophan indole ring is stabilized by cation-pi interactions. Two stable orientations of the indole ring with respect to the equatorial coordination plane of copper were observed, which showed that the indole ring can reside on both sides of the coordination plane. The interaction with the indole ring was found to occur without a mediating axial water molecule.
The trigger system for the external target experiment in the HIRFL cooling storage ring
NASA Astrophysics Data System (ADS)
Li, Min; Zhao, Lei; Liu, Jin-Xin; Lu, Yi-Ming; Liu, Shu-Bin; An, Qi
2016-08-01
A trigger system was designed for the external target experiment in the Cooling Storage Ring (CSR) of the Heavy Ion Research Facility in Lanzhou (HIRFL). Considering that different detectors are scattered over a large area, the trigger system is designed based on a master-slave structure and fiber-based serial data transmission technique. The trigger logic is organized in hierarchies, and flexible reconfiguration of the trigger function is achieved based on command register access or overall field-programmable gate array (FPGA) logic on-line reconfiguration controlled by remote computers. We also conducted tests to confirm the function of the trigger electronics, and the results indicate that this trigger system works well. Supported by the National Natural Science Foundation of China (11079003), the Knowledge Innovation Program of the Chinese Academy of Sciences (KJCX2-YW-N27), and the CAS Center for Excellence in Particle Physics (CCEPP).
RHIC BEAM ABORT KICKER POWER SUPPLY SYSTEM COMMISSIONING EXPERIENCE AND REMAINING ISSUES.
DOE Office of Scientific and Technical Information (OSTI.GOV)
ZHANG,W.; AHRENS,L.A.; MI,J.
2001-06-18
The RHIC Beam Abort Kicker Power Supply Systems commissioning experience and the remaining issues will be reported in this paper. The RHIC Blue Ring Beam Abort Kicker Power Supply System initial commissioning took place in June 1999. Its identical system in Yellow Ring was brought on line during Spring 2000. Each of the RHIC Beam Abort Kicker Power Supply Systems consists of five high voltage modulators and subsystems. These systems are critical devices for RHIC machine protection and environmental protection. They are required to be effective, reliable and operating with sufficient redundancy to safely abort the beam to its beammore » dump at the end of accumulation or at any time when they are commanded. To deflect 66 GeV ion beam to the beam absorbers, the RHIC Beam Abort Kicker Power Supply Systems were operated at 22 kV level. The RHIC 2000 commissioning run was very successful.« less
Kinetic Simulation and Energetic Neutral Atom Imaging of the Magnetosphere
NASA Technical Reports Server (NTRS)
Fok, Mei-Ching H.
2011-01-01
Advanced simulation tools and measurement techniques have been developed to study the dynamic magnetosphere and its response to drivers in the solar wind. The Comprehensive Ring Current Model (CRCM) is a kinetic code that solves the 3D distribution in space, energy and pitch-angle information of energetic ions and electrons. Energetic Neutral Atom (ENA) imagers have been carried in past and current satellite missions. Global morphology of energetic ions were revealed by the observed ENA images. We have combined simulation and ENA analysis techniques to study the development of ring current ions during magnetic storms and substorms. We identify the timing and location of particle injection and loss. We examine the evolution of ion energy and pitch-angle distribution during different phases of a storm. In this talk we will discuss the findings from our ring current studies and how our simulation and ENA analysis tools can be applied to the upcoming TRIO-CINAMA mission.
Characteristics of ring-cusp discharge chambers
NASA Technical Reports Server (NTRS)
Matossian, J. N.; Beattie, J. R.
1991-01-01
Measurements have been obtained for the operating characteristics of a 30 cm diameter ring-cusp ion thruster (RCIT), quantitatively comparing its performance parameters to those of a divergent-field J-series cluster of the same size. The high level of performance established for the RCIT is due to its maintenance of both a higher primary-electron population and Maxwellian-electron temperature, as the beam-ion production cost is reduced to its baseline value. Ion losses to the discharge-chamber walls can be reduced by an applied electrostatic field.
Liu, Hao; Yu, Jing; Li, Xinyu; Yan, Rui; Xiao, Ji-Chang; Hong, Ran
2015-09-18
A stereoselective N-iminium ion cyclization with allylsilane to construct vicinal quaternary-tertiary carbon centers was developed for the concise synthesis of (±)-cephalotaxine. The current strategy features a TiCl4-promoted cyclization and ring-closure metathesis to furnish the spiro-ring system. The stereochemical outcome in the N-acyliminium ion cyclization was rationalized by the stereoelectronic effect of the Z- or E-allylsilane. Two diastereomers arising from the cyclization were merged into the formal synthesis of (±)-cephalotaxine.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wiedner, Ulrich
2011-10-24
The new FAIR facility in Darmstadt has a broad program in the field of hadron and nuclear physics utilizing ion beams with unprecedented intensity and accuracy. The hadron physics program centers around the the high-energy storage ring HESR for antiprotons and the PANDA experiment that is integrated in it. The physics program includes among others topics like hadron spectroscopy in the charmonium mass region and below, hyperon physics, electromagnetic processes and charm in nuclei.
A plasma generator utilizing the high intensity ASTROMAG magnets
NASA Technical Reports Server (NTRS)
Sullivan, James D.; Post, R. S.; Lane, B. G.; Tarrh, J. M.
1986-01-01
The magnet configuration for the proposed particle astrophysics magnet facility (ASTROMAG) on the space station includes a cusp magnetic field with an intensity of a few tesla. With these large magnets (or others) located in the outer ionosphere, many quite interesting and unique plasma physics experiments become possible. First there are studies utilizing the magnet alone to examine the supersonic, sub-Alfvenic interaction with the ambient medium; the scale length for the magnet perturbation is approx. 20 m. The magnetic field geometry when combined with the Earth's and their relative motion will give rise to a host of plasma phenomena: ring nulls, x-points, ion-acoustic and lower-hybrid shocks, electron heating (possible shuttle glow without a surface) launching of Alfvenwaves, etc. Second, active experiments are possible for a controlled study of fundamental plasma phenomena. A controlled variable species plasma can be made by using an RF ion source; use of two soft iron rings placed about the line cusp would give an adequate resonance zone (ECH or ICH) and a confining volume suitable for gas efficiency. The emanating plasma can be used to study free expansion of plasma along and across field lines (polar wind), plasma flows around the space platform, turbulent mixing in the wake region, long wavelength spectrum of convecting modes, plasma-dust interactions, etc.
Energy transfer between energetic ring current H(+) and O(+) by electromagnetic ion cyclotron waves
NASA Technical Reports Server (NTRS)
Thorne, Richard M.; Horne, Richard B.
1994-01-01
Electromagnetic ion cyclotron (EMIC) waves in the frequency range below the helium gyrofrequency can be excited in the equatorial region of the outer magnetosphere by cyclotron resonant instability with anisotropic ring current H(+) ions. As the unducted waves propagate to higher latitudes, the wave normal should become highly inclined to the ambient magnetic field. Under such conditions, wave energy can be absorbed by cyclotron resonant interactions with ambient O(+), leading to ion heating perpendicular to the ambient magnetic field. Resonant wave absorption peaks in the vicinity of the bi-ion frequency and the second harmonic of the O(+) gyrofrequrency. This absorption should mainly occur at latitudes between 10 deg and 30 deg along auroral field lines (L is greater than or equal to 7) in the postnoon sector. The concomitant ion heating perpendicular to the ambient magnetic field can contribute to the isotropization and geomagnetic trapping of collapsed O(+) ion conics (or beams) that originate from a low-altitude ionospheric source region. During geomagnetic storms when the O(+) content of the magnetosphere is significantly enhanced, the absorption of EMIC waves should become more efficient, and it may contribute to the observed acceleration of O(+) ions of ionospheric origin up to ring current energies.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lackner, Florian; Chatterley, Adam S.; Pemmaraju, C. D.
Femtosecond extreme ultraviolet transient absorption spectroscopy is used to explore strong-field ionization induced dynamics in selenophene (C 4H 4Se). The dynamics are monitored in real-time from the viewpoint of the Se atom by recording the temporal evolution of element-specific spectral features near the Se 3d inner-shell absorption edge (~58 eV). The interpretation of the experimental results is supported by first-principles time-dependent density functional theory calculations. The experiments simultaneously capture the instantaneous population of stable molecular ions, the emergence and decay of excited cation states, and the appearance of atomic fragments. The experiments reveal, in particular, insight into the strong-field inducedmore » ring-opening dynamics in the selenophene cation, which are traced by the emergence of non-cyclic molecules as well as the liberation of Se + ions within an overall time scale of approximately 170 fs. In this study, we propose that both products may be associated with dynamics on the same electronic surfaces but with different degrees of vibrational excitation. The time-dependent inner-shell absorption features provide direct evidence for a complex relaxation mechanism that may be approximated by a two-step model, whereby the initially prepared, excited cyclic cation decays within τ 1 = 80 ± 30 fs into a transient molecular species, which then gives rise to the emergence of bare Se + and ring-open cations within an additional τ 2 = 80 ± 30 fs. The combined experimental and theoretical results suggest a close relationship between σ* excited cation states and the observed ring-opening reactions. In conclusion, the findings demonstrate that the combination of femtosecond time-resolved core-level spectroscopy with ab initio estimates of spectroscopic signatures provide new insights into complex, ultrafast photochemical reactions such as ring-opening dynamics in organic molecules in real-time and with simultaneous sensitivity for electronic and structural rearrangements.« less
Ion optics for high power 50-cm-diam ion thrusters
NASA Technical Reports Server (NTRS)
Rawlin, Vincent K.; Millis, Marc G.
1989-01-01
The process used at the NASA-Lewis to fabricate 30 and 50-cm-diameter ion optics is described. The ion extraction capabilities of the 30 and 50-cm diameter ion optics were evaluated on divergent field and ring-cusp discharge chambers and compared. Perveance was found to be sensitive to the effects of the type and power of the discharge chamber and to the accelerator electrode hole diameter. Levels of up to 0.64 N and 20 kW for thrust and input power, respectively, were demonstrated with the divergent-field discharge chamber. Thruster efficiencies and specific impulse values up to 79 percent and 5000 sec., respectively, were achieved with the ring-cusp discharge chamber.
Inference of the ring current ion composition by means of charge exchange decay
NASA Technical Reports Server (NTRS)
Smith, P. H.; Bewtra, N. K.; Hoffman, R. A.
1978-01-01
The analysis of the measured ion fluxes during the several day storm recovery period and the assumption that beside hydrogen other ions were present and that the decays were exponential in nature, it was possible to establish three separate lifetimes for the ions. These fitted decay lifetimes are in excellent agreement with the expected charge exchange decay lifetimes for H(+), O(+), and He(+) in the energy and L-value range of the data. This inference technique, thus, establishes the presence of measurable and appreciable quantities of oxygen and helium ions as well as protons in the storm-time ring current. Indications that He(+) may also be present under these same conditions were found.
The role of nitrogen ions in the ring current dynamics
NASA Astrophysics Data System (ADS)
Ilie, R.; Liemohn, M. W.; Dandouras, I. S.
2017-12-01
Changes in the ion composition throughout the Earth's magnetosphere can have profound implications on plasma structures and dynamics, since it can modify the temperature and the magnetic field configuration, altering the convection patterns inside the magnetosphere. The ratio of hydrogen to oxygen ions has been shown to be highly dependent of geomagnetic activity, with the O+ content increasing with increasing activity. This suggests that ions of ionospheric origin can become the dominant species in the inner magnetosphere during disturbed times. Therefore, numerous studies have focused on the transport and energization of O+ through the ionosphere-magnetosphere system; however, relatively few have considered the contribution of N+, in addition to that of O+ to the near-Earth plasma dynamics, even though past observations have established that N+ is a significant ion species in the ionosphere and its presence in the magnetosphere is significant. Ring current observations from the Active Magnetospheric Particle Tracer Explorer (AMPTE) spacecraft show that high energy N+ fluxes are comparable to those of O+ during disturbed times, confirming the substantial presence of N+ions in the inner magnetosphere. In spite of only 12% mass difference, N+ and O+ have different ionization potentials, scale heights and charge exchange cross sections. The latter, together with the geocoronal density distribution, plays a key role in the formation of Energetic Neutral Atoms (ENAs), which in turn control the energy budget of the inner magnetosphere and the decay of the ring current. Numerical simulations using the Hot Electron and Ion Drift Integrator (HEIDI) model suggest that the contribution of N+ to the ring current dynamics is significant, as the presence of N+, in addition to that of O+, alters the development and the decay rate of the ring current. These findings suggest that differentiating the N+ transport from that of O+ in the near-Earth environment has a profound impact on global magnetosphere dynamics, as plasma composition affects both the local and the global properties of the plasma.
Global Structure and Sodium Ion Dynamics in Mercury's Magnetosphere With the Offset Dipole
NASA Astrophysics Data System (ADS)
Yagi, M.; Seki, K.; Matsumoto, Y.; Delcourt, D. C.; Leblanc, F.
2017-11-01
We conducted global magnetohydrodynamics (MHD) simulation of Mercury's magnetosphere with the dipole offset, which was revealed by MESSENGER (Mercury Surface, Space Environment, Geochemistry, and Ranging) observations, in order to investigate its global structure under northward interplanetary magnetic field conditions. Sodium ion dynamics originating from the Mercury's exosphere is also investigated based on statistical trajectory tracing in the electric and magnetic fields obtained from the MHD simulations. The results reveal a north-south asymmetry characterized by open field lines around the southern polar region and northward deflection of the plasma sheet in the far tail. The asymmetry of magnetic field structure near the planet drastically affects trajectories of sodium ion and thus their pressure distributions and precipitation pattern onto the planet. Weaker magnetic field strength in the southern hemisphere than in the north increases ion loss by precipitation onto the planetary surface in the southern hemisphere. The "sodium ring," which is formed by high-energy sodium ions drifting around the planet, is also found in the vicinity of the planet. The sodium ring is almost circular under nominal solar wind conditions. The ring becomes partial under high solar wind density, because dayside magnetosphere is so compressed that there is no space for the sodium ions to drift around. In both cases, the sodium ring is formed by sodium ions that are picked up, accelerated in the magnetosheath just outside the magnetopause, and reentered into the magnetosphere due to combined effects of finite Larmor radius and convection electric field in the dawnside magnetosphere.
Coaxial ion trap mass spectrometer: concentric toroidal and quadrupolar trapping regions.
Peng, Ying; Hansen, Brett J; Quist, Hannah; Zhang, Zhiping; Wang, Miao; Hawkins, Aaron R; Austin, Daniel E
2011-07-15
We present the design and results for a new radio-frequency ion trap mass analyzer, the coaxial ion trap, in which both toroidal and quadrupolar trapping regions are created simultaneously. The device is composed of two parallel ceramic plates, the facing surfaces of which are lithographically patterned with concentric metal rings and covered with a thin film of germanium. Experiments demonstrate that ions can be trapped in either region, transferred from the toroidal to the quadrupolar region, and mass-selectively ejected from the quadrupolar region to a detector. Ions trapped in the toroidal region can be transferred to the quadrupole region using an applied ac signal in the radial direction, although it appears that the mechanism of this transfer does not involve resonance with the ion secular frequency, and the process is not mass selective. Ions in the quadrupole trapping region are mass analyzed using dipole resonant ejection. Multiple transfer steps and mass analysis scans are possible on a single population of ions, as from a single ionization/trapping event. The device demonstrates better mass resolving power than the radially ejecting halo ion trap and better sensitivity than the planar quadrupole ion trap.
Modifcation of the Prolyl Ring of Val-Pro and the Impact of this Modification on b2 Ion Structure
NASA Astrophysics Data System (ADS)
Bernier, Matthew C.; Wysocki, Vicki H.; Gucinski, Ashley; Chamot-Rooke, Julia
2013-06-01
Here we present b2 ion studies on one tripeptide (VPA) and show how the addition of a fluorine or a hydroxyl group on the 3rd position of the proline ring can affect the b2 ion formation. Action IRMPD results of ValHyp (Hyp=hydroxyproline), ValFlp (Flp=trans-fluoroproline), and Valflp (flp=cis-fluoroproline) all show the presence of a strong oxazolone band in the CO region at 1900 cm-1. The presence of peaks in the diketopiperazine region between 1700 and 1800 cm-1 varies depending on which substituent is placed on the prolyl ring. Recently published data from our group showed a pair of medium sized diketopiperazine bands at 1760 and 1701 cm-1 for ValPro and we observed similarly intense bands for Valflp at 1752 and 1689 cm-1. ValHyp and ValFlp fail to show any significant diketopiperazine bands, but if zoomed in x10 a small band can be observed at 1756 cm-1 for ValHyp. From this data it is apparent that substitution of the second position prolyl ring can alter the formation of the b2 diketopiperazine ion.
Ion transport and loss in the earth's quiet ring current. I - Data and standard model
NASA Technical Reports Server (NTRS)
Sheldon, R. B.; Hamilton, D. C.
1993-01-01
A study of the transport and loss of ions in the earth's quiet time ring current, in which the standard radial diffusion model developed for the high-energy radiation belt particles is compared with the measurements of the lower-energy ring current ions, is presented. The data set provides ionic composition information in an energy range that includes the bulk of the ring current energy density, 1-300 keV/e. Protons are found to dominate the quiet time energy density at all altitudes, peaking near L of about 4 at 60 keV/cu cm, with much smaller contributions from O(+) (1-10 percent), He(+) (1-5 percent), and He(2+) (less than 1 percent). A minimization procedure is used to fit the amplitudes of the standard electric radial diffusion coefficient, yielding 5.8 x 10 exp -11 R(E-squared)/s. Fluctuation ionospheric electric fields are suggested as the source of the additional diffusion detected.
NASA Technical Reports Server (NTRS)
Huba, J. D.; Chen, J.; Anderson, R. R.
1992-01-01
Attention is given to a mechanism to generate a broad spectrum of electrostatic turbulence in the quiet time central plasma sheet (CPS) plasma. It is shown theoretically that multiple-ring ion distributions can generate short-wavelength (less than about 1), electrostatic turbulence with frequencies less than about kVj, where Vj is the velocity of the jth ring. On the basis of a set of parameters from measurements made in the CPS, it is found that electrostatic turbulence can be generated with wavenumbers in the range of 0.02 and 1.0, with real frequencies in the range of 0 and 10, and with linear growth rates greater than 0.01 over a broad range of angles relative to the magnetic field (5-90 deg). These theoretical results are compared with wave data from ISEE 1 using an ion distribution function exhibiting multiple-ring structures observed at the same time. The theoretical results in the linear regime are found to be consistent with the wave data.
Characteristics of the NASA Lewis bumpy-torus plasma generated with positive applied potentials
NASA Technical Reports Server (NTRS)
Roth, J. R.; Gerdin, G. A.; Richardson, R. W.
1976-01-01
Experimental observations were made during steady-state operation of a bumpy-torus plasma at input powers up to 150 kW in deuterium and helium gas and with positive potentials applied to the midplane electrodes. In this steady-state ion heating method a modified Penning discharge is operated such that the plasma is acted upon by a combination of strong electric and magnetic fields. Experimental investigation of a deuterium plasma revealed electron temperatures from 14 to 140 eV and ion kinetic temperatures from 160 to 1785 eV. At least two distinct modes of operation exist. Experimental data shows that the average ion residence time in the plasma is virtually independent of the magnetic field strength. Data was taken when all 12 anode rings were at high voltage, and in other symmetric configurations in which the toroidal plasma was generated by applying positive potentials to six anode rings, three anode rings, and a single anode ring.
High-Resolution Structure and Mechanism of an F/V-Hybrid Rotor Ring in a Na+-coupled ATP Synthase
Matthies, Doreen; Zhou, Wenchang; Klyszejko, Adriana L.; Anselmi, Claudio; Yildiz, Özkan; Brandt, Karsten; Müller, Volker; Faraldo-Gómez, José D.; Meier, Thomas
2014-01-01
All rotary ATPases catalyze the interconversion of ATP and ADP-Pi through a mechanism that is coupled to the transmembrane flow of H+ or Na+. Physiologically, however, F/A-type enzymes specialize in ATP synthesis driven by downhill ion diffusion, while eukaryotic V-type ATPases function as ion pumps. To begin to rationalize the molecular basis for this functional differentiation, we solved the crystal structure of the Na+-driven membrane rotor of the Acetobacterium woodii ATP synthase, at 2.1 Å resolution. Unlike known structures, this rotor ring is a 9:1 heteromer of F- and V-type c-subunits, and therefore features a hybrid configuration of ion-binding sites along its circumference. Molecular and kinetic simulations are used to dissect the mechanisms of Na+ recognition and rotation of this c-ring, and to explain the functional implications of the V-type c-subunit. These structural and mechanistic insights indicate an evolutionary path between synthases and pumps involving adaptations in the rotor ring. PMID:25381992
Space-time crystals of trapped ions.
Li, Tongcang; Gong, Zhe-Xuan; Yin, Zhang-Qi; Quan, H T; Yin, Xiaobo; Zhang, Peng; Duan, L-M; Zhang, Xiang
2012-10-19
Spontaneous symmetry breaking can lead to the formation of time crystals, as well as spatial crystals. Here we propose a space-time crystal of trapped ions and a method to realize it experimentally by confining ions in a ring-shaped trapping potential with a static magnetic field. The ions spontaneously form a spatial ring crystal due to Coulomb repulsion. This ion crystal can rotate persistently at the lowest quantum energy state in magnetic fields with fractional fluxes. The persistent rotation of trapped ions produces the temporal order, leading to the formation of a space-time crystal. We show that these space-time crystals are robust for direct experimental observation. We also study the effects of finite temperatures on the persistent rotation. The proposed space-time crystals of trapped ions provide a new dimension for exploring many-body physics and emerging properties of matter.
Baseline scheme for polarization preservation and control in the MEIC ion complex
DOE Office of Scientific and Technical Information (OSTI.GOV)
Derbenev, Yaroslav S.; Lin, Fanglei; Morozov, Vasiliy
2015-09-01
The scheme for preservation and control of the ion polarization in the Medium-energy Electron-Ion Collider (MEIC) has been under active development in recent years. The figure-8 configuration of the ion rings provides a unique capability to control the polarization of any ion species including deuterons by means of "weak" solenoids rotating the particle spins by small angles. Insertion of "weak" solenoids into the magnetic lattices of the booster and collider rings solves the problem of polarization preservation during acceleration of the ion beam. Universal 3D spin rotators designed on the basis of "weak" solenoids allow one to obtain any polarizationmore » orientation at an interaction point of MEIC. This paper presents the baseline scheme for polarization preservation and control in the MEIC ion complex.« less
SEE Observations of Ionospheric Heating from HAARP Using Orbital Angular Momentum
NASA Astrophysics Data System (ADS)
Briczinski, S. J.; Bernhardt, P. A.; Siefring, C. L.
2013-12-01
High power HF radio waves exciting the ionosphere provide aeronomers with a unique space-based laboratory capability. The High-Frequency Active Auroral Research Program (HAARP) in Gakona, Alaksa is the world's largest heating facility, providing effective radiated powers in the gigawatt range. Experiments performed at HAARP have allowed researchers to study many non-linear effects of wave-plasma interactions. Stimulated Electromagnetic Emission (SEE) is of interest to the ionospheric community for its diagnostic purposes. Typical SEE experiments at HAARP have focused on characterizing the parametric decay of the electromagnetic pump wave into several different wave modes such as upper and lower hybrid, ion acoustic, ion-Bernstein and electron-Bernstein. These production modes have been extensively studied at HAARP using traditional beam heating patterns and SEE detection. New results are present from HAARP experiments using an excitation mode that attempts to impart orbital angular momentum (OAM) into the heating region. This OAM mode is also referred to as a 'twisted beam.' Previous analysis of twisted beam heating shows that the SEE results obtained are nearly identical to the modes without OAM. Recent twisted beam heating experiments have produced SEE modes not previously characterized. These new modes are presented and discussed. One difference in the twisted beam mode is the heating region produced is in the shape of a ring as opposed to the more traditional 'solid spot' region. The ring heating pattern may be more conducive to the creation of artificial ionization clouds. The results of these runs include artificial ionization creation and evolution as pertaining to the twisted beam pattern.
Whitfield, Dennis M
2012-07-15
That the ring conformation of glycopyranosyl oxacarbenium ions can influence the stereochemical outcome of glycosylation reactions has been postulated for some time. Some new ionization calculations show that the ultimate conformation (4)H(3) or (5)S(1) of D-glucopyranosyl oxacarbenium ions depends on the initial ϕ(H) (CH-1-C-1-S(+)-SCH(3)) conformation of anomeric thiosulfonium ions. Evidence is also presented that nucleophile:electrophile hydrogen bonded complexes, 1,6-anhydro-carbenium ions and electron rich carbon nucleophile:oxacarbenium ion complexes are all probably artifacts of neglecting counter ions or nucleophiles in the DFT calculation. All three cationic species are likely important for glycosylation reaction side reactions but not as productive species. Copyright © 2012. Published by Elsevier Ltd.
Poly[diaquatris(μ4-1,3-phenylenediacetato)dineodymium(III)
Gao, Zhu-Qing; Lv, Dong-Yu; Li, Hong-Ji; Gu, Jin-Zhong
2011-01-01
In the title coordination polymer, [Nd2(C10H8O4)3(H2O)2]n, each of the two NdIII ions is nine-coordinated by eight O atoms from six different 2,2′-(m-phenylene)diacetate (pda) bivalent anions and by one O atom from a water molecule, forming a distorted tricapped trigonal–prismatic coordination geometry. Eight NdIII ions and 12 pda ligands form a large [Nd8(pda)12] ring, and four NdIII ions and six pda ligands form a small [Nd4(pda)6] ring. These rings are further connected by the coordination interactions of pda ligands and NdIII, generating a three-dimensional supramolecular framework. PMID:21522305
Plasma properties in electron-bombardment ion thrusters
NASA Technical Reports Server (NTRS)
Matossian, J. N.; Beattie, J. R.
1987-01-01
The paper describes a technique for computing volume-averaged plasma properties within electron-bombardment ion thrusters, using spatially varying Langmuir-probe measurements. Average values of the electron densities are defined by integrating the spatially varying Maxwellian and primary electron densities over the ionization volume, and then dividing by the volume. Plasma properties obtained in the 30-cm-diameter J-series and ring-cusp thrusters are analyzed by the volume-averaging technique. The superior performance exhibited by the ring-cusp thruster is correlated with a higher average Maxwellian electron temperature. The ring-cusp thruster maintains the same fraction of primary electrons as does the J-series thruster, but at a much lower ion production cost. The volume-averaged predictions for both thrusters are compared with those of a detailed thruster performance model.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Tabakov, Boyan
2015-07-01
Microfabricated segmented surface ion traps are one viable avenue to scalable quantum information processing. At Sandia National Laboratories we design, fabricate, and characterize such traps. Our unique fabrication capabilities allow us to design traps that facilitate tasks beyond quantum information processing. The design and performance of a trap with a target capability of storing hundreds of equally spaced ions on a ring is described. Such a device could aid experimental studies of phenomena as diverse as Hawking radiation, quantum phase transitions, and the Aharonov - Bohm effect. The fabricated device is demonstrated to hold a ~ 400 ion circular crystal,more » with 9 μm average spacing between ions. The task is accomplished by first characterizing undesired electric fields in the trapping volume and then designing and applying an electric field that substantially reduces the undesired fields. In addition, experimental efforts are described to reduce the motional heating rates in a surface trap by low energy in situ argon plasma treatment that reduces the amount of surface contaminants. The experiment explores the premise that carbonaceous compounds present on the surface contribute to the anomalous heating of secular motion modes in surface traps. This is a research area of fundamental interest to the ion trapping community, as heating adversely affects coherence and thus gate fidelity. The device used provides high optical laser access, substantially reducing scatter from the surface, and thus charging that may lead to excess micromotion. Heating rates for different axial mode frequencies are compared before and after plasma treatment. The presence of a carbon source near the plasma prevents making a conclusion on the observed absence of change in heating rates.« less
Electron molecular ion recombination: product excitation and fragmentation.
Adams, Nigel G; Poterya, Viktoriya; Babcock, Lucia M
2006-01-01
Electron-ion dissociative recombination is an important ionization loss process in any ionized gas containing molecular ions. This includes the interstellar medium, circumstellar shells, cometary comae, planetary ionospheres, fusion plasma boundaries, combustion flames, laser plasmas and chemical deposition and etching plasmas. In addition to controlling the ionization density, the process generates many radical species, which can contribute to a parallel neutral chemistry. Techniques used to obtain rate data and product information (flowing afterglows and storage rings) are discussed and recent data are reviewed including diatomic to polyatomic ions and cluster ions. The data are divided into rate coefficients and cross sections, including their temperature/energy dependencies, and quantitative identification of neutral reaction products. The latter involve both ground and electronically excited states and including vibrational excitation. The data from the different techniques are compared and trends in the data are examined. The reactions are considered in terms of the basic mechanisms (direct and indirect processes including tunneling) and recent theoretical developments are discussed. Finally, new techniques are mentioned (for product identification; electrostatic storage rings, including single and double rings; Coulomb explosion) and new ways forward are suggested.
Loss of ring current O(+) ions due to interaction with Pc 5 waves
NASA Astrophysics Data System (ADS)
Li, Xinlin; Hudson, Mary; Chan, Anthony; Roth, Ilan
1993-01-01
A test particle code is used here to investigate ring current ion interaction with Pc 5 waves, combined with convection and corotation electric fields, with emphasis on the loss of O(+) ions over the dayside magnetosphere. A new loss mechanism for the O(+) ions due to the combined effects of convection and corotation electric fields and interactions with Pc 5 waves via a magnetic drift-bound resonance is presented. For given fields, whether a particle gains or losses energy depends on its initial kinetic energy, pitch angle at the equatorial plane, and the position of its guiding center with respect to the azimuthal phase of the wave. The ring current O(+) ions show a dispersion in energies and L values with decreasing local time across the dayside, and a bulk shift to lower energies and higher L values. Due to interaction with the Pc 5 waves, the particle's kinetic energy can drop below that required to overcome the convection potential and the particle is lost to the dayside magnetopause by a sunward E x B drift.
Local spin density in the Cr 7Ni antiferromagnetic molecular ring and 53Cr-NMR
DOE Office of Scientific and Technical Information (OSTI.GOV)
Casadei, Cecilia M; Bordonali, L; Furukawa, Yuji
We present 53Cr-NMR spectra collected at low temperature in a single crystal of the heterometallic antiferromagnetic (AF) ring Cr 7Ni in the S = 1/2 ground state with the aim of establishing the distribution of the local electronic moment in the ring. Due to the poor S/N we observed only one signal which is ascribed to three almost equivalent 53Cr nuclei in the ring. The calculated spin density in Cr 7Ni in the ground state, with the applied magnetic field both parallel and perpendicular to the plane of the ring, turns out to be AF staggered with the greatest componentmore » of the local spin {s} for the Cr 3+ ions next to the Ni 2+ ion. The 53Cr-NMR frequency was found to be in good agreement with the local spin density calculated theoretically by assuming a core polarization field of H cp =₋ 11 T/μ B for both orientations, close to the value found previously in Cr 7Cd. Lastly, the observed orientation dependence of the local spin moments is well reproduced by the theoretical calculation and evidences the importance of single-ion and dipolar anisotropies.« less
A double-cusp type electrostatic analyzer for high-cadence ring current ion measurements
NASA Astrophysics Data System (ADS)
Ogasawara, K.; Allegrini, F.; Burch, J. L.; Desai, M. I.; Ebert, R. W.; Goldstein, J.; John, J. M.; Livi, S. A.; McComas, D. J.
2015-12-01
Detailed observations of a variety of ion species at a sufficiently high temporal resolution are essential to understanding the loss and acceleration processes of ring current ions. For example, CRESS/MICS observations indicated that the energy density of suprathermal O+ exceeds that of H+ in large magnetic storms (Daglis et al., 1997), while the H+ energy density dominates under quiet conditions. However, the primary ion loss processes during the storm recovery phase are still incompletely understood. The mechanisms to accelerate upflowing ions, regularly observed with energies of a few keV at ~1000 km altitude, up to the 100s-keV range in the geospace are also not fully understood. Our novel electrostatic analyzer (ESA) employs a toroidal double-shell structure to cover the entire ring current ion range of ~3-250 keV/Q with high temporal resolution (<1 minute with a necessary counting statistics for the quiet time), while saving significant resources in mass and size. In this presentation, we discuss the operation principle and the proof of concept study of the ESA in terms of numerical calculations and ion beam calibration activities. This presentation comprehensively covers the expected sensor performance important for the in-flight capabilities, such as sensor parameters (G-factor, K-factor, and energy resolution), cross-shell contaminations, and UV background counts.
Transport of ions using RF Carpets in Helium Gas
NASA Astrophysics Data System (ADS)
Lambert, Keenan; Kelly, James; Brodeur, Maxime
2017-09-01
Radio-Frequency (RF) carpet are critical components of large volume gas cells used to thermalize radioactive ion beams produced at in-flight facilities. RF carpets are formed by a series of co-centric conductive rings on which an alternating potential (in the radio-frequency range) is applied with opposite polarity on adjacent rings. This results in a strong repelling force that keep the ions a certain distance from the carpet. The transport of ions using RF carpet is accomplished using either a potential gradient applied on the individual all strips or traveling wave (using the so-called `ion surfing method'). A test setup has been constructed at the University of Notre Dame to perform studies on the repelling of ions using RF carpets. This test setup has recently been improved by the addiction of circuitry elements allowing the transport of ions using the ion surfing method. The developed circuitry, together with transport results for various ion beam currents, electric force applied on the ions, and traveling wave amplitude and speed will be presented
Correction to AD/RHIC-47, Beam Transfer From AGS to RHIC
DOE Office of Scientific and Technical Information (OSTI.GOV)
Claus, J.; Foelsche, H.
1988-12-12
RHIC an acronym for Relativistic Heavy Ion Collider, is a facility for colliding heavy ions with each other, proposed for construction at Brookhaven National Laboratory. This facility and the motivation for building it, have been described. It consists of two intersecting storage rings and the purpose of this note is to describe how these two rings are to be filled with beam.
Increasing the Extracted Beam Current Density in Ion Thrusters
NASA Astrophysics Data System (ADS)
Arthur, Neil Anderson
Ion thrusters have seen application on space science missions and numerous satellite missions. Ion engines offer higher electrical efficiency and specific impulse capability coupled with longer demonstrated lifetime as compared to other space propulsion technologies. However, ion engines are considered to have low thrust. This work aims to address the low thrust conception; whereby improving ion thruster performance and thrust density will lead to expanded mission capabilities for ion thruster technology. This goal poses a challenge because the mechanism for accelerating ions, the ion optics, is space charge limited according to the Child-Langmuir law-there is a finite number of ions that can be extracted through the grids for a given voltage. Currently, ion thrusters operate at only 40% of this limit, suggesting there is another limit artificially constraining beam current. Experimental evidence suggests the beam current can become source limited-the ion density within the plasma is not large enough to sustain high beam currents. Increasing the discharge current will increase ion density, but ring cusp ion engines become anode area limited at high discharge currents. The ring cusp magnetic field increases ionization efficiency but limits the anode area available for electron collection. Above a threshold current, the plasma becomes unstable. Increasing the engine size is one approach to increasing the operational discharge current, ion density, and thus the beam current, but this presents engineering challenges. The ion optics are a pair of closely spaced grids. As the engine diameter increases, it becomes difficult to maintain a constant grid gap. Span-to-gap considerations for high perveance optics limit ion engines to 50 cm in diameter. NASA designed the annular ion engine to address the anode area limit and scale-up problems by changing the discharge chamber geometry. The annular engine provides a central mounting structure for the optics, allowing the beam area to increase while maintaining a fixed span-to-gap. The central stalk also provides additional surface area for electron collection. Circumventing the anode area limitation, the annular ion engine can operate closer to the Child-Langmuir limit as compared to a conventional cylindrical ion thruster. Preliminary discharge characterization of a 65 cm annular ion engine shows >90% uniformity and validates the scalability of the technology. Operating beyond the Child-Langmuir limit would allow for even larger performance gains. This classic law does not consider the ion injection velocity into the grid sheath. The Child-Langmuir limit shifts towards higher current as the ion velocity increases. Ion drift velocity can be created by enhancing the axially-directed electric field. One method for creating this field is to modify the plasma potential distribution. This can be accomplished by biasing individual magnetic cusps, through isolated, conformal electrodes placed on each magnet ring. Experiments on a 15 cm ion thruster have shown that plasma potential in the bulk can be modified by as much as 5 V and establish ion drift towards the grid plane. Increases in ion current density at the grid by up to 20% are demonstrated. Performance implications are also considered, and increases in simulated beam current of 15% and decreases in discharge losses of 5% are observed. Electron density measurements within the magnetic cusps revealed, surprisingly, as cusp current draw increases, the leak width does not change. This suggests that instead of increasing the electron collection area, cusp bias enhances electron mobility along field lines.
NASA Technical Reports Server (NTRS)
Lipatov, A. S.; Sibeck, D. G.
2016-01-01
We use a new hybrid kinetic model to simulate the response of ring current, outer radiation belt, and plasmaspheric particle populations to impulsive interplanetary shocks. Since particle distributions attending the interplanetary shock waves and in the ring current and radiation belts are non-Maxwellian, waveparticle interactions play a crucial role in energy transport within the inner magnetosphere. Finite gyroradius effects become important in mass loading the shock waves with the background plasma in the presence of higher energy ring current and radiation belt ions and electrons. Initial results show that shocks cause strong deformations in the global structure of the ring current, radiation belt, and plasmasphere. The ion velocity distribution functions at the shock front, in the ring current, and in the radiation belt help us determine energy transport through the Earth's inner magnetosphere.
NASA Technical Reports Server (NTRS)
Morfill, G. E.; Gruen, E.; Johnson, T. V.
1980-01-01
The physical processes acting on charged microscopic dust grains in the Jovian atmosphere involve electromagnetic forces which dominate dust particle dynamics and diffusion across field lines resulting from random charge fluctuations of the dust grains. A model of the Jovian ring hypothesizes that the 'visible' ring particles are produced by erosive collisions between an assumed population of kilometer-sized parent bodies and submicron-sized magnetospheric dust particles. Fluctuations in the ring topology and intensity are determined over various time scales, showing that the ring is a quasipermanent and quasistable characteristic of the Jovian system. Finally, the interaction of the Jovian energetic belt electrons and the Jovian plasma with an ambient dust population is examined; the distribution of dust ejected from Io in the inner magnetosphere and losses of magnetospheric ions and electrons due to direct collisions with charged dust particles are calculated.
Multiple-Satellite Observation of Magnetic Dip Event During the Substorm on 10 October 2013
DOE Office of Scientific and Technical Information (OSTI.GOV)
He, Zhaoguo; Chen, Lunjin; Zhu, Hui
Here, we present a multiple-satellite observation of the magnetic dip event during the substorm on 10 October 2013. The observation illustrates the temporal and spatial evolution of the magnetic dip and gives a compelling evidence that ring current ions induce the magnetic dip by enhanced plasma beta. The dip moves with the energetic ions in a comparable drift velocity and affects the dynamics of relativistic electrons in the radiation belt. In addition, the magnetic dip provides a favorable condition for the electromagnetic ion cyclotron (EMIC) wave generation based on the linear theory analysis. The calculated proton diffusion coefficients show thatmore » the observed EMIC wave can lead to the pitch angle scattering losses of the ring current ions, which in turn partially relax the magnetic dip in the observations. This study enriches our understanding of magnetic dip evolution and demonstrates the important role of the magnetic dip for the coupling of radiation belt and ring current.« less
Multiple-Satellite Observation of Magnetic Dip Event During the Substorm on 10 October 2013
NASA Astrophysics Data System (ADS)
He, Zhaoguo; Chen, Lunjin; Zhu, Hui; Xia, Zhiyang; Reeves, G. D.; Xiong, Ying; Xie, Lun; Cao, Yong
2017-09-01
We present a multiple-satellite observation of the magnetic dip event during the substorm on 10 October 2013. The observation illustrates the temporal and spatial evolution of the magnetic dip and gives a compelling evidence that ring current ions induce the magnetic dip by enhanced plasma beta. The dip moves with the energetic ions in a comparable drift velocity and affects the dynamics of relativistic electrons in the radiation belt. In addition, the magnetic dip provides a favorable condition for the electromagnetic ion cyclotron (EMIC) wave generation based on the linear theory analysis. The calculated proton diffusion coefficients show that the observed EMIC wave can lead to the pitch angle scattering losses of the ring current ions, which in turn partially relax the magnetic dip in the observations. This study enriches our understanding of magnetic dip evolution and demonstrates the important role of the magnetic dip for the coupling of radiation belt and ring current.
Multiple-Satellite Observation of Magnetic Dip Event During the Substorm on 10 October 2013
He, Zhaoguo; Chen, Lunjin; Zhu, Hui; ...
2017-09-05
Here, we present a multiple-satellite observation of the magnetic dip event during the substorm on 10 October 2013. The observation illustrates the temporal and spatial evolution of the magnetic dip and gives a compelling evidence that ring current ions induce the magnetic dip by enhanced plasma beta. The dip moves with the energetic ions in a comparable drift velocity and affects the dynamics of relativistic electrons in the radiation belt. In addition, the magnetic dip provides a favorable condition for the electromagnetic ion cyclotron (EMIC) wave generation based on the linear theory analysis. The calculated proton diffusion coefficients show thatmore » the observed EMIC wave can lead to the pitch angle scattering losses of the ring current ions, which in turn partially relax the magnetic dip in the observations. This study enriches our understanding of magnetic dip evolution and demonstrates the important role of the magnetic dip for the coupling of radiation belt and ring current.« less
NASA Astrophysics Data System (ADS)
Sittler, E. C., Jr.; Elrod, M. K.; Johnson, R. E.; Cooper, J. F.; Tseng, W. L.; Smith, H. T.; Chornay, D. J.; Shappirio, M.; Simpson, D. G.
2017-12-01
In analyzing the Cassini data between Saturn's A-ring outer edge and Mimas' L shell numerous inconsistencies have been reported in estimates of total ionic charge and electron density. The primary focus of our work is to understand these inconsistencies. We present our recent discovery of plasma protons during Saturn Orbit Insertion (SOI) outbound pass of the magnetospheric region between the F and G rings. We also searched for H2+ ions but no such events were found. The discovery of protons was made possible by a recent analysis of the CAPS Ion Mass Spectrometer's (IMS's) time-of-flight (TOF) composition data in a mode of reduced post-acceleration voltage at 6 kV instead of the usual 14.6 kV. All previous work for this region had not considered the TOF data. The new proton analysis was enabled by minimum scattering of 6 kV protons in the instrument's ultrathin carbon foils (CF), in comparison to larger scattering for the heavier ions such as for O+ and O2+. We use a SIMION model of the CAPS IMS including the effects of energy straggling and scattering by the instrument's CFs in an attempt to understand the TOF composition data for the heavier ions. This analysis within the uncertainties of the instrument allows us to estimate the relative abundances of the heavier ions and thus run our 2D velocity ion moments code to get ion densities, temperatures and velocities during the SOI outbound pass through the F-ring and G-ring gap. Comparisons with other data sets will be made.
Magnetic Field Observations of Partial Ring Current during Storm Recovery Phase
NASA Technical Reports Server (NTRS)
Le, G.; Russell, C. T.; Slavin, J. A.; Lucek, E. A.
2008-01-01
We present results of an extensive survey of the magnetic field observations in the inner magnetosphere using 30 years of magnetospheric magnetic field data from Polar, Cluster, ISEE, and AMPTE/CCE missions. The purpose of this study is to understand the magnetic field evolution during the recovery phase of geomagnetic storms, and its implication to the ring current recovery and loss mechanisms of ring current particles. It is now commonly believed that a strong partial ring current is formed during the storm main phase due to the enhanced earthward convection of energetic ions from nightside plasma sheet. But the presence of a strong partial ring current throughout the recovery phase remains controversial. The magnetic field generated by the ring current inflates the inner magnetosphere and causes magnetic field depressions in the equatorial magnetosphere. During the storm recovery phase, we find that the distribution of the equatorial magnetic field depression exhibits similar local time dependence as the ring current distribution obtained from the combined dataset in the earlier study. It shows that a strong partial ring current is a permanent feature throughout the recovery phase. In the early recovery phase, the partial ring current peaks near the dusk terminator as indicated by the peak of the magnetic field depression. As the recovery phase progresses, the partial ring current decays most quickly near the dusk and results in a dusk-to-midnight moving of the peak of the partial ring current. Thus the loss mechanisms work most effectively near the dusk. The magnetic field depression increases the gyroradius of ring current protons to a scale greater or comparable to the thickness of the magnetopause, which increases the chance of ion drift loss near the dusk magnetopause at larger L-shell (L greater than 5). But the drift loss mechanism alone cannot explain the loss of ring current ions especially in the smaller L-shell (L less than 5). The precipitation loss due to wave-particle interaction is most likely the dominant loss mechanism in the small L-shell as it works most effectively at the same local time.
NASA Astrophysics Data System (ADS)
Min, Kyungguk; Liu, Kaijun
2018-01-01
Maintaining the stability of pickup ions in the outer heliosheath is a critical element for the secondary energetic neutral atom (ENA) mechanism, a theory put forth to explain the nearly annular band of ENA emission observed by the Interstellar Boundary EXplorer. A recent study showed that a pickup ion ring can remain stable to the Alfvén/ion cyclotron (AC) instability at propagation parallel to the background magnetic field when the parallel thermal spread of the ring is comparable to that of a background population. This study investigates the potential role that the mirror or ion Bernstein (IB) instabilities can play in the stability of pickup ions when conditions are such that the AC instability is suppressed. Linear Vlasov theory predicts relatively fast mirror and IB instability growth even though AC instability growth is suppressed. For a few such cases, two-dimensional hybrid and macroscopic quasi-linear simulations are carried out to examine how the unstable mirror and IB modes evolve and affect the pickup ion ring beyond the linear theory picture. For the parameters used, the mirror mode dominates initially and leads to a rapid parallel heating of the pickup ions in excess of the parallel temperature of the background protons. The heated pickup ions subsequently trigger onset of the AC mode, which grows sufficiently large to be the dominant pitch angle scattering agent after the mirror mode has decayed away. The present results indicate that the pickup ion stability needed may not be guaranteed once the mirror and IB instabilities are taken into account.
Photoionization and ion cyclotron resonance studies of the ion chemistry of ethylene oxide
NASA Technical Reports Server (NTRS)
Corderman, R. R.; Williamson, A. D.; Lebreton, P. R.; Buttrill, S. E., Jr.; Beauchamp, J. L.
1976-01-01
The formation of the ethylene oxide molecular ion and its subsequent ion-molecule reactions leading to the products C2H5O(+) and C3H5O(+) have been studied using time-resolved photoionization mass spectroscopy, ion cyclotron resonance spectroscopy, and photoelectron spectroscopy. An examination of the effects of internal energy on reactivity shows that the ratio of C3H5O(+) to C2H5O(+) increases by an order of magnitude with a single quantum of vibrational energy. The formation of (C2H4O/+/)-asterisk in a collision-induced isomerization is found which yields a ring-opened structure by C-C bond cleavage. The relaxed ring-opened C2H4O(+) ion reacts with neutral ethylene oxide by CH2(+) transfer to yield an intermediate product ion C3H6O(+) which gives C3H5O(+) by loss of H.
Charging of interplanetary grains
NASA Technical Reports Server (NTRS)
Baragiola, R. A.; Johnson, R. E.; Newcomb, John L.
1995-01-01
The objective of this program is to quantify, by laboratory experiments, the charging of ices and other insulators subject to irradiation with electrons, ions and ultraviolet photons and to model special conditions based on the data. The system and conditions to be studied are those relevant for charging of dust in magnetospheric plasmas. The measurements are supplemented by computer simulations of charging or grains under a variety of conditions. Our work for this period involved experiments on water ice, improved models of charging of ice grains for Saturn's E-ring, and the construction of apparatus for electron impact studies and measurements of electron energy distributions.
Results of magnetospheric barium ion cloud experiment of 1971
NASA Technical Reports Server (NTRS)
Adamson, D.; Fricke, C. L.; Long, S. A. T.
1975-01-01
The barium ion cloud experiment involved the release of about 2 kg of barium at an altitude of 31 482 km, a latitude of 6.926 N., and a longitude of 74.395 W. Significant erosion of plasma from the main ion core occurred during the initial phase of the ion cloud expansion. From the motion of the outermost striational filaments, the electric field components were determined to be 0.19 mV/m in the westerly direction and 0.68 mV/m in the inward direction. The differences between these components and those measured from balloons flown in the proximity of the extremity of the field line through the release point implied the existence of potential gradients along the magnetic field lines. The deceleration of the main core was greater than theoretically predicted. This was attributed to the formation of a polarization wake, resulting in an increase of the area of interaction and resistive dissipation at ionospheric levels. The actual orientation of the magnetic field line through the release point differed by about 10.5 deg from that predicted by magnetic field models that did not include the effect of ring current.
NASA Technical Reports Server (NTRS)
Shelley, E. G.; Klumpar, D. M.; Peterson, W. K.; Ghielmetti, A.; Balsiger, H.; Geiss, J.; Rosenbauer, H.
1985-01-01
Observations from the Hot Plasma Composition Experiment on the AMPTE/CCE spacecraft during the magnetic storm of 4-5 September 1984 reveal that significant injection of ions of terrestrial origin accompanied the storm development. The compression of the magnetosphere at storm sudden commencement carried the magnetopause inside the CCE orbit clearly revealing the shocked solar wind plasma. A build up of suprathermal ions is observed near the plasmapause during the storm main phase and recovery phase. Pitch angle distributions in the ring current during the main phase show differences between H(+) and O(+) that suggest mass dependent injection, transport and/or loss processes.
Min, Kyungguk; Liu, Kaijun; Gary, S. Peter
2016-03-18
Here, a ring-like proton velocity distribution with ∂f p(v ⊥)/∂v ⊥>0 and which is sufficiently anisotropic can excite two distinct types of growing modes in the inner magnetosphere: ion Bernstein instabilities with multiple ion cyclotron harmonics and quasi-perpendicular propagation and an Alfvén-cyclotron instability at frequencies below the proton cyclotron frequency and quasi-parallel propagation. Recent particle-in-cell simulations have demonstrated that even if the maximum linear growth rate of the latter instability is smaller than the corresponding growth of the former instability, the saturation levels of the fluctuating magnetic fields can be greater for the Alfvén-cyclotron instability than for the ion Bernsteinmore » instabilities. In this study, linear dispersion theory and two-dimensional particle-in-cell simulations are used to examine scalings of the linear growth rate and saturation level of the two types of growing modes as functions of the temperature anisotropy T ⊥/T || for a general ring-like proton distribution with a fixed ring speed of 2v A, where v A is the Alfvén speed. For the proton distribution parameters chosen, the maximum linear theory growth rate of the Alfvén-cyclotron waves is smaller than that of the fastest-growing Bernstein mode for the wide range of anisotropies (1≤T ⊥/T ||≤7) considered here. Yet the corresponding particle-in-cell simulations yield a higher saturation level of the fluctuating magnetic fields for the Alfvén-cyclotron instability than for the Bernstein modes as long as inline image. Since fast magnetosonic waves with ion Bernstein instability properties observed in the magnetosphere are often not accompanied by electromagnetic ion cyclotron waves, the results of the present study indicate that the ring-like proton distributions responsible for the excitation of these fast magnetosonic waves should not be very anisotropic.« less
Mirchi, Ali; Sizochenko, Natalia; Dinadayalane, Tandabany; Leszczynski, Jerzy
2017-11-22
The effect of substitution of phenyl and naphthyl rings to benzene was examined to elucidate the cation-π interactions involving alkali metal ions with 1,3,5-tri(phenyl)benzene (TPB) and 1,3,5-tri(naphthyl)benzene (TNB). Benzene, TPB, and four TNB isomers (with ααα, ααβ, αββ, and βββ types of fusion) and their complexes with Li + , Na + , K + , Rb + , and Cs + were optimized using DFT approach with B3LYP and M06-2X functionals in conjunction with the def2-QZVP basis set. Higher relative stability of β,β,β-TNB over α,α,α-TNB can be attributed to peri repulsion, which is defined as the nonbonding repulsive interaction between substituents in the 1- and the 8-positions on the naphthalene core. Binding energies, distances between ring centroid and the metal ions, and the distance to metal ions from the center of other six-membered rings were compared for all complexes. Our computational study reveals that the binding affinity of alkali metal cations increases significantly with the 1,3,5-trisubstitution of phenyl and naphthyl rings to benzene. The detailed computational analyses of geometries, partial charges, binding energies, and ligand organization energies reveal the possibility of favorable C-H···M + interactions when a α-naphthyl group exists in complexes of TNB structures. Like benzene-alkali metal ion complexes, the binding affinity of metal ions follows the order: Li + > Na + > K + > Rb + > Cs + for any considered 1,3,5-trisubstituted benzene systems. In case of TNB, we found that the strength of interactions increases as the fusion point changes from α to β position of naphthalene.
Resonant interactions between cometary ions and low frequency electromagnetic waves
NASA Technical Reports Server (NTRS)
Thorne, Richard M.; Tsurutani, Bruce T.
1987-01-01
The conditions for resonant wave amplification in a plasma with a ring-beam distribution which is intended to model pick-up ions in a cometary environment are investigated. The inclination between the interplanetary field and the solar wind is found to play a crucial role in governing both the resonant frequency and the growth rate of any unstable mode. It is suggested that the low-frequency MHD mode should experience the most rapid amplification for intermediate inclination. In the frame of the solar wind, such waves should propagate along the field in the direction upstream toward the sun with a phase speed lower than the beaming velocity of the pick-up ions. This mechanism may account for the presence of the interior MHD waves noted by satellites over a region surrounding comets Giacobini-Zinner and Halley.
Resonant interactions between cometary ions and low frequency electromagnetic waves
NASA Astrophysics Data System (ADS)
Thorne, R. M.; Tsurutani, B. T.
1987-12-01
The conditions for resonant wave amplification in a plasma with a ring-beam distribution which is intended to model pick-up ions in a cometary environment are investigated. The inclination between the interplanetary field and the solar wind is found to play a crucial role in governing both the resonant frequency and the growth rate of any unstable mode. It is suggested that the low-frequency MHD mode should experience the most rapid amplification for intermediate inclination. In the frame of the solar wind, such waves should propagate along the field in the direction upstream toward the sun with a phase speed lower than the beaming velocity of the pick-up ions. This mechanism may account for the presence of the interior MHD waves noted by satellites over a region surrounding comets Giacobini-Zinner and Halley.
Spatiospectral Analysis of Accelerated Protons from Sub-Micron Liquid Crystal Films
NASA Astrophysics Data System (ADS)
Willis, Christopher; Poole, Patrick; Cochran, Ginevra; van Woerkom, Linn; Schumacher, Douglass
2017-10-01
Recent studies on ion acceleration have trended towards ultra-thin (<1 μm) targets due to improved ion energies and yields from these targets. As discussed here, ultra-thin targets may exhibit unusual spatial distributions in the accelerated ions, such that ion spectrometer data may not be representative of the overall distribution. More complete characterization of the ions requires spectral unfolding of radiochromic film (RCF) data, yielding spatially dependent spectra. Spatiospectral data will be presented from several experiments using sub-micron liquid crystal film targets at the Scarlet (OSU), Texas Petawatt (UT, Austin) and PHELIX (GSI, Darmstadt) laser facilities, including evidence of >75 MeV protons from 300 nm films at PHELIX. Analysis of RCF data is supported by Monte-Carlo modeling of RCF response to ions and electrons using FLUKA. Trends in the resulting ion distributions will be discussed including spatially varying slope temperature and observation of annular ring features at moderate ion energies on many shots. This material is based upon work supported by the AFOSR under award FA9550-14-1-0085, by the DARPA PULSE program through a Grant from AMRDEC, and by the NNSA under contract DE-NA0003107.
NASA Technical Reports Server (NTRS)
Taylor, W. W. L.; Lyons, L. R.
1976-01-01
Eighteen events of large-amplitude (0.4-6 gammas) waves which may be propagating in the ion cyclotron mode have een observed by Explorer 45. Comparison with simultaneously measured proton distributions has allowed the events to be divided into two categories. The first category consists of waves accompanied by enhanced ion fluxes apparently injected into the plasmasphere with anisotropic pitch-angle distributions. This simultaneity suggests that these waves may be generated by the observed ring-current ions. Waves in the second category were found near or outside the plasmapause and were not correlated with any identifiable changes in the observed proton distribution. The generation mechanism for these waves remains unknown.
Leung, Ka-Ngo; Reijonen, Jani; Thomae, Rainer W.
2005-07-26
A compact microwave ion source has a permanent magnet dipole field, a microwave launcher, and an extractor parallel to the source axis. The dipole field is in the form of a ring. The microwaves are launched from the middle of the dipole ring using a coaxial waveguide. Electrons are heated using ECR in the magnetic field. The ions are extracted from the side of the source from the middle of the dipole perpendicular to the source axis. The plasma density can be increased by boosting the microwave ion source by the addition of an RF antenna. Higher charge states can be achieved by increasing the microwave frequency. A xenon source with a magnetic pinch can be used to produce intense EUV radiation.
NASA Astrophysics Data System (ADS)
Barsbay, Murat; Kavaklı, Pınar Akkaş; Güven, Olgun
2010-03-01
A novel polymeric ligand exchanger (PLE) was prepared for the removal of phosphate ions from water. 2,2'-dipyridylamine (DPA), a bidentate ligand forming compound with high coordination capacity with a variety of metal ions was bound to glycidyl methacrylate (GMA) grafted polypropylene/polyethylene (PP/PE) nonwoven fabric synthesized by radiation-induced grafting technique. DPA attachment on epoxy ring of GMA units was tested in different solvents, i.e. methanol, ethanol, dioxane and dimethylsulfoxide (DMSO). The highest amount of modification was achieved in dioxane. In order to prepare the corresponding PLE for the removal of phosphate, DPA-immobilized fabric was loaded with Cu(II) ions. Phosphate adsorption experiments were performed in batch mode at different pH (5-9) and phosphate concentrations. The fabric was found to be effective for the removal of phosphate ions. At every stage of preparation and use, the nonwoven fabric was characterized by thermal (i.e. DSC and TGA) and spectroscopic (FTIR) methods. Competitive adsorption experiments were also carried out using two solutions with different concentration levels at pH 7 to see the effect of competing ions. Phosphate adsorption was found to be effective and selective from solutions having trace amounts of competitive anions. It is expected that the novel PLE synthesized can be used for the removal of phosphate ions in low concentrations over a large range of pH.
Three-dimensional ring current decay model
NASA Technical Reports Server (NTRS)
Fok, Mei-Ching; Moore, Thomas E.; Kozyra, Janet U.; Ho, George C.; Hamilton, Douglas C.
1995-01-01
This work is an extension of a previous ring current decay model. In the previous work, a two-dimensional kinetic model was constructed to study the temporal variations of the equatorially mirroring ring current ions, considering charge exchange and Coulomb drag losses along drift paths in a magnetic dipole field. In this work, particles with arbitrary pitch angle are considered. By bounce averaging the kinetic equation of the phase space density, information along magnetic field lines can be inferred from the equator. The three-dimensional model is used to simulate the recovery phase of a model great magnetic storm, similar to that which occurred in early February 1986. The initial distribution of ring current ions (at the minimum Dst) is extrapolated to all local times from AMPTE/CCE spacecraft observations on the dawnside and duskside of the inner magnetosphere spanning the L value range L = 2.25 to 6.75. Observations by AMPTE/CCE of ring current distributions over subsequent orbits during the storm recovery phase are compared to model outputs. In general, the calculated ion fluxes are consistent with observations, except for H(+) fluxes at tens of keV, which are always overestimated. A newly invented visualization idea, designated as a chromogram, is used to display the spatial and energy dependence of the ring current ion differential flux. Important features of storm time ring current, such as day-night asymmetry during injection and drift hole on the dayside at low energies (less than 10 keV), are manifested in the chromogram representation. The pitch angle distribution is well fit by the function, J(sub o)(1 + Ay(sup n)), where y is sine of the equatorial pitch angle. The evolution of the index n is a combined effect of charge exchange loss and particle drift. At low energies (less than 30 keV), both drift dispersion and charge exchange are important in determining n.
A three-dimensional ring current decay model
NASA Technical Reports Server (NTRS)
Fok, Mei-Ching; Moore, Thomas E.; Kozyra, Janet U.; Ho, George C.; Hamilton, Douglas C.
1994-01-01
This work is an extension of a previous ring current decay model. In the previous work, a two-dimensional kinetic model was constructed to study the temporal variations of the equatorially mirroring ring current ions, considering charge exchange and Coulomb drag losses along drift paths in a magnetic dipole field. In this work, particles with arbitrary pitch angle are considered. By bounce averaging the kinetic equation of the phase space density, information along magnetic field lines can be inferred from the equator. The three-dimensional model is used to simulate the recovery phase of a model great magnetic storm, similar to that which occurred in early February 1986. The initial distribution of ring current ions (at the minimum Dst) is extrapolated to all local times from AMPTE/CCE spacecraft observations on the dawn and dusk sides of the inner magnetosphere spanning the L value range L = 2.25 to 6.75. Observations by AMPTE/CCE of ring current distributions over subsequent orbits during the storm recovery phase are compared to model outputs. In general, the calculated ion fluxes are consistent with observations, except for H+ fluxes at tens of keV, which are always over-estimated. A newly-invented visualization idea, designated as a chromogram, is used to display the spatial and energy dependence of the ring current ion differential flux. Important features of storm-time ring current, such as day-night asymmetry during injection and drift hole on the dayside at low energies (less than 10 keV), are manifested in the chromogram representation. The pitch angle distribution is well fit by the function, j(sub o)(1+Ay(exp n)), where y is sine of the equatorial pitch angle. The evolution of the index n is a combined effect of charge exchange loss and particle drift. At low energies (less than 30 keV), both drift dispersion and charge exchange are important in determining n.
On contribution of energetic and heavy ions to the plasma pressure: Storm Sept 27 - Oct 4, 2002
NASA Astrophysics Data System (ADS)
Kronberg, E. A.; Mouikis, C.; Kistler, L. M.; Dandouras, I. S.; Daly, P. W.; Welling, D. T.; Grigorenko, E. E.
2015-12-01
Contribution of the energetic ions (>> 40 keV) and of heavy ions into the total plasma pressure is often neglected. In this study we evaluate the contribution of these components for the storm observed from September 27 to October 4 in 2002. The thermal component of the pressure for the protons, helium and oxygen at 0--40 keV/q is measured by the Cluster/CIS/CODIF sensor. The contribution of the energetic ions at energies >> 40 keV is calculated from the Cluster/RAPID/IIMS observations. The results show that before the storm has initiated, the contribution of the energetic ions in to the total pressure is indeed negligible in the tail plasma sheet, less than ˜1%. However, with the storm development contribution of the energetic part becomes significant, up to ˜30%, towards the recovery phase and cannot be neglected. Heavy ions contribute to the 27% of the total pressure and half of them are energetic. The contribution of energetic ions to the pressure of the ring current (L≃5) is significant. The heavy ions play a dominant role in the plasma pressure, about 62% during the main phase of the magnetic storm. Half of them are energetic ions. The SWMF/BATS-R-US MHD model underestimates the contribution of the energetic and heavy ions in to the ion distribution in the magnetotail plasma sheet and the ring current. The ring current plasma pressure distorts the terrestrial internal magnetic field and defines magnetic storm. Therefore, it is essential to take in to account the contribution of the energetic and heavy ions.
NASA Astrophysics Data System (ADS)
Gao, Xiaobo; Li, Yu Xiao
2018-04-01
AC electro-osmotic (ACEO) micropumps presently involve the planar or nonplanar electrode pair array in the rectangular microchannel. However, this paper presented a theoretical model of an ultra-fast 3D ring ACEO micropump with arrays of asymmetric ring electrode pairs in the cylindrical microchannel. The theory is on the basis of the interaction between the nonuniform electric field and ions of an electric double layer (EDL) on the surface of ring electrodes. Therefore, we first established the equivalent hollow cylinder capacitance of EDL for ring ACEO micropumps. Then, the 3D Poisson-Boltzmann model by solving the electric field and fluidic flow field with the charge conservation and the slip velocity boundary conditions was numerically calculated. For a dilute strong electrolyte solution, the conductivity as a function of the electrolyte concentration can be obtained by the modified Kohlrausch's dilution empirical equation with the molar conductivity. The results revealed that the flow rate of ring ACEO was higher than the planar ACEO, which agreed well with the experiment. The dependences of the time-averaged pumping velocity on the frequency and concentration have similar bell profiles with a maximal value. Moreover, the optimal velocity with proper geometric parameters was obtained at a given frequency, voltage, concentration, and radius. The high-speed ring ACEO micropump will be significant for the experimental studies to further improve the flow rate and be hopeful for applications of microfluidic mixing, particle manipulation, and so on.
Magnetic Field Observations of Partial Ring Current during Storm Recovery Phase
NASA Technical Reports Server (NTRS)
Le, Guan; Russell, C. T.; Slavin, J. A.; Lucek, E. A.
2007-01-01
We present results of an extensive survey of the magnetic field observations in the inner magnetosphere using 30 years of magnetospheric magnetic field data from Polar, Cluster, ISEE, and AMPTE/CCE missions. The purpose of this study is to understand the magnetic field evolution during the recovery phase of geomagnetic storms, and its implication to the ring current recovery and loss mechanisms of ring current particles. Our previous work on global ring current distribution [Le et al., 2004] has shown that a significant partial ring current is always present at all Dst levels (regardless of storm phases) even for quiet time ring current. The total current carried by the partial ring current is much stronger than (during stormtime) or at least comparable to (during quiet time) the symmetric ring current. It is now commonly believed that a strong partial ring current is formed during the storm main phase due to the enhanced earthward convection of energetic ions from nightside plasma sheet. But the presence of a strong partial ring current throughout the recovery phase remains controversial. The magnetic field generated by the ring current inflates the inner magnetosphere and causes magnetic field depressions in the equatorial magnetosphere. During the storm recovery phase, we find that the distribution of the equatorial magnetic field depression exhibits similar local time dependence as the ring current distribution obtained from the combined dataset in the earlier study. It shows that a strong partial ring current is a permanent feature throughout the recovery phase. In the early recovery phase, the partial ring current peaks near the dusk terminator as indicated by the peak of the magnetic field depression. As the recovery phase progresses, the partial ring current decays most quickly near the dusk and results in a dusk-to-midnight moving of the peak of the partial ring current. Thus the loss mechanisms work most effectively near the dusk. The magnetic field depression increases the gyroradius of ring current protons to a scale greater or comparable to the thickness of the magnetopause, which increases the chance of ion drift loss near the dusk magnetopause at larger L-shell (L>5). But the drift loss mechanism alone cannot explain the loss of ring current ions especially in the smaller L-shell (L<5). The precipitation loss due to wave-particle interaction is most likely the dominant loss mechanism in the small L-shell as it works most effectively at the same local time.
Plasma contactor design for electrodynamic tether applications
NASA Technical Reports Server (NTRS)
Wilbur, Paul J.; Laupa, Thomas G.
1988-01-01
The plasma contacting process is described and experiments are discussed that suggest the key role that cold ions play in establishing a low impedance plasma bridge that can conduct current in either direction between a contactor electrode and a dilute plasma. A ring cusp contactor is shown to provide from 1000-mA of electron emission to 500-mA of electron collection as its bias relative to a simulated space plasma is varied through an 80-v range.
Investigating EMIC Wave Dynamics with RAM-SCB-E
NASA Astrophysics Data System (ADS)
Jordanova, V. K.; Fu, X.; Henderson, M. G.; Morley, S.; Welling, D. T.; Yu, Y.
2017-12-01
The distribution of ring current ions and electrons in the inner magnetosphere depends strongly on their transport in realistic electric (E) and magnetic (B) fields and concurrent energization or loss. To investigate the high variability of energetic particle (H+, He+, O+, and electron) fluxes during storms selected by the GEM Surface Charging Challenge, we use our kinetic ring current model (RAM) two-way coupled with a 3-D magnetic field code (SCB). This model was just extended to include electric field calculations, making it a unique, fully self-consistent, anisotropic ring current-atmosphere interactions model, RAM-SCB-E. Recently we investigated electromagnetic ion cyclotron (EMIC) instability in a local plasma using both linear theory and nonlinear hybrid simulations and derived a scaling formula that relates the saturation EMIC wave amplitude to initial plasma conditions. Global dynamic EMIC wave maps obtained with our RAM-SCB-E model using this scaling will be presented and compared with statistical models. These plasma waves can affect significantly both ion and electron precipitation into the atmosphere and the subsequent patterns of ionospheric conductance, as well as the global ring current dynamics.
Electrochemical Studies of Redox Systems for Energy Storage
NASA Technical Reports Server (NTRS)
Wu, C. D.; Calvo, E. J.; Yeager, E.
1983-01-01
Particular attention was paid to the Cr(II)/Cr(III) redox couple in aqueous solutions in the presence of Cl(-) ions. The aim of this research has been to unravel the electrode kinetics of this redox couple and the effect of Cl(1) and electrode substrate. Gold and silver were studied as electrodes and the results show distinctive differences; this is probably due to the role Cl(-) ion may play as a mediator in the reaction and the difference in state of electrical charge on these two metals (difference in the potential of zero charge, pzc). The competition of hydrogen evolution with CrCl3 reduction on these surfaces was studied by means of the rotating ring disk electrode (RRDE). The ring downstream measures the flux of chromous ions from the disk and therefore separation of both Cr(III) and H2 generation can be achieved by analyzing ring and disk currents. The conditions for the quantitative detection of Cr(2+) at the ring electrode were established. Underpotential deposition of Pb on Ag and its effect on the electrokinetics of Cr(II)/Cr(III) reaction was studied.
Continuous wave cavity ring-down spectroscopy for velocity distribution measurements in plasma.
McCarren, D; Scime, E
2015-10-01
We report the development of a continuous wave cavity ring-down spectroscopic (CW-CRDS) diagnostic for real-time, in situ measurement of velocity distribution functions of ions and neutral atoms in plasma. This apparatus is less complex than conventional CW-CRDS systems. We provide a detailed description of the CW-CRDS apparatus as well as measurements of argon ions and neutrals in a high-density (10(9) cm(-3) < plasma density <10(13) cm(-3)) plasma. The CW-CRDS measurements are validated through comparison with laser induced fluorescence measurements of the same absorbing states of the ions and neutrals.
NASA Technical Reports Server (NTRS)
Khazanov, G. V.; Gamayunov, K. V.; Gallagher, D. L.; Kozyra, J. U.; Liemohn, M. W.
2007-01-01
This paper continues presentation and discussion of the results from our new global self-consistent theoretical model of interacting ring current ions and propagating electromagnetic ion cyclotron waves [Khazanov et al., 2006]. To study the effects of electromagnetic ion cyclotron wave propagation and refraction on the wave induced ring current precipitation and heating of the thermal plasmaspheric electrons, we simulate the May 1998 storm. The main findings after a simulation can be summarized as follows. Firstly, the wave induced ring current precipitation exhibits quite a lot of fine structure, and is highly organized by location of the plasmapause gradient. The strongest fluxes of about 4 x 10(exp 6) (cm(raised dot) s(raised dot) sr(raised dot) (sup -1)) are observed during the maill and early recovery phases of the storm. The very interesting and probably more important finding is that in a number of cases the most intense precipitating fluxes are not connected to the most intense waves in simple manner. The characteristics of the wave power spectral density distribution over the wave normal angle are extremely crucial for the effectiveness of the ring current ion scattering. Secondly, comparison of the global proton precipitating patterns with the results from RAM [Kozyra et al., 1997a] reveals that although we observe a qualitative agreement between the localizations of the wave induced precipitations in the models, there is no quantitative agreement between the magnitudes of the fluxes. The quantitative differences are mainly due to a qualitative difference between the characteristics of the wave power spectral density distributions over the wave normal angle in RAM and in our model. Thirdly, the heat fluxes to plasmaspheric electrons caused by Landau resonate energy absorption from electromagnetic ion cyclotron waves are observed in the postnoon-premidnight MLT sector, and can reach the magnitude of 10(exp 11) eV/(cm(sup 2)(raised dot)s). The Coulomb energy degradation of the RC H(+) and O(+) ions maximizes at about 10(exp 11) (eV/(cm(sup 2) (raised dot) s), and typically leads to electron energy deposition rates of about 2(raised dot) 10(exp 10) (eV/(cm(sup 2)(raised dot)s) which are observed during two periods; 32-48 hours, and 76-86 hours after 1 May, 0000 UT. The theoretically derived spatial structure of the thermal electron heating caused by interaction of the ring current with the plasmasphere is strongly supported by concurrent and conjugate plasma measurements from the plasmasphere, ring current, and topside ionosphere [Gurgiolo et al., 2005]. Finally, the wave induced intense electron heating has a structure of the spot-like patches along the most enhanced density gradients in the plasmasphere boundary layer and can be a possible driver to the observed but still not explained small-scale structures of enhanced emissions in the stable auroral red arcs.
Cold Ion Escape from the Martian Ionosphere
NASA Astrophysics Data System (ADS)
Fraenz, M.; Dubinin, E.; Wei, Y.; Woch, J. G.; Morgan, D. D.; Barabash, S. V.; Lundin, R. N.; Fedorov, A.
2012-12-01
It has always been challenging to observe the flux of ions with energies of less than 10eV escaping from the planetary ionospheres. We here report on new measurements of the ionospheric ion flows at Mars by the ASPERA-3 experiment on board Mars Express. We first use support from the MARSIS radar experiment for some orbits with fortunate observation geometry. Here we have observed a transterminator flow of O+ and O2+ ions with a super-sonic velocity of around 5km/s and fluxes of 0.8x10^9/cm^2s. If we assume a symmetric flux around the terminator this corresponds to an ion flow of 3.1x10^25/s half of which is expected to escape from Mars (Fraenz et al, 2010). This escape flux is significantly higher than previously observed on the tailside of Mars, we discuss possible reasons for the difference. Since 2008 the MARSIS radar does nightside local plasma density measurement which often coincide with ASPERA-3 measurements. In a new analysis of the combined nightside datasets (Fig. 1) we show that the main escape channel is along the shadow boundary on the tailside of Mars. At a distance of about 0.5 R_M the flux settles at a constant value (Fig. 2) which indicates that about half of the transterminator ionospheric flow escapes from the planet. Possible mechanism to generate this flux can be the ionospheric pressure gradient between dayside and nightside or momentum transfer from the solar wind via the induced magnetic field since the flow velocity is in the Alfvenic regime.; Median oxygen ion flux reconstructed by combining ion velocity observations of the Mars Express ASPERA-3 IMA sensor and local plasma density observations by the MARSIS radar. Each bin value is the median from observations on about 3000 orbits between May 2007 and July 2011. Horizontal axis is MSO X-axis (Sun towards the left), vertical axis is vertical distance from MSO X-axis. ; Ring median flux of cylindrical ring regions of all bins shown in previous figure. The different colors show median fluxes for different regions in R-cylindrical (distance from MSO-X-axis) as a function of tailward distance from the terminator (or surface for Rcyl < 1).
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wang, Shaoheng; Guo, Jiquan; Wang, Haipeng
2016-05-01
The initial design of a low higher order modes (HOM) impedance superconducting RF (SRF) cavity is presented in this paper. The design of this SRF cavity is for the proposed Jefferson Lab Electron Ion Collider (JLEIC). The electron ring of JLEIC will operate with electrons of 3 to 10 GeV energy. The ion ring of JLEIC will operate with protons of up to 100 GeV energy. The bunch lengths in both rings are ~12 mm (RMS). In order to maintain the short bunch length in the ion ring, SRF cavities are adopted to provide large enough gradient. In the firstmore » phase of JLEIC, the PEP II RF cavities will be reused in the electron ring to lower the initial cost. The frequency of the SRF cavities is chosen to be the second harmonic of PEP II cavities, 952.6 MHz. In the second phase of JLEIC, the same frequency SRF cavities may replace the normal conducting PEP II cavities to achieve higher luminosity at high energy. At low energies, the synchro-tron radiation damping effect is quite weak, to avoid the coupled bunch instability caused by the intense closely-spaced electron bunches, low HOM impedance of the SRF cavities combined with longitudinal feedback sys-tem will be necessary.« less
Colliding or co-rotating ion beams in storage rings for EDM search
NASA Astrophysics Data System (ADS)
Koop, I. A.
2015-11-01
A new approach to search for and measure the electric dipole moment (EDM) of the proton, deuteron and some other light nuclei is presented. The idea of the method is to store two ion beams, circulating with different velocities, in a storage ring with crossed electric and magnetic guiding fields. One beam is polarized and its EDM is measured using the so-called ‘frozen spin’ method. The second beam, which is unpolarized, is used as a co-magnetometer, sensitive to the radial component of the ring’s magnetic field. The particle’s magnetic dipole moment (MDM) couples to the radial magnetic field and mimics the EDM signal. Measuring the relative vertical orbit separation of the two beams, caused by the presence of the radial magnetic field, one can control the unwanted MDM spin precession. Examples of the parameters for EDM storage rings for protons and other species of ions are presented. The use of crossed electric and magnetic fields helps to reduce the size of the ring by a factor of 10-20. We show that the bending radius of such an EDM storage ring could be about 2-3 m. Finally, a new method of increasing the spin coherence time, the so-called ‘spin wheel’, is proposed and its applicability to the EDM search is discussed.
Impact of the Tilted Detector Solenoid on the Ion Polarization at JLEIC
Kondratenko, A. M.; Kondratenko, M. A.; Filatov, Yu N.; ...
2017-12-01
Jefferson Lab Electron Ion Collider (JLEIC) is a figure-8 collider "transparent" to the spin. This allows one to control the ion polarization using a universal 3D spin rotator based on weak solenoids. Besides the 3D spin rotator, a coherent effect on the spin is produced by a detector solenoid together with the dipole correctors and anti-solenoids compensating betatron oscillation coupling. The 4 m long detector solenoid is positioned along a straight section of the electron ring and makes a 50 mrad horizontal angle with a straight section of the ion ring. Such a large crossing angle is needed for amore » quick separation of the two colliding beams near the interaction point to make sufficient space for placement of interaction region magnets and to avoid parasitic collisions of shortly-spaced 476 MHz electron and ion bunches. We present a numerical analysis of the detector solenoid effect on the proton and deuteron polarizations. We demonstrate that the effect of the detector solenoid on the proton and deuteron polarizations can be compensated globally using an additional 3D rotator located anywhere in the ring.« less
NASA Astrophysics Data System (ADS)
Sumida, Shuhei; Shinohara, Kouji; Ikezoe, Ryuya; Ichimura, Makoto; Sakamoto, Mizuki; Hirata, Mafumi; Ide, Shunsuke
2017-12-01
The Magneto-acoustic Cyclotron Instability (MCI) is a possible emission mechanism for Ion Cyclotron Emissions (ICEs). A dispersion model of the MCI driven by a drifting-ring-type ion velocity distribution has been proposed. In this study, the model was compared with the experimental observations of 3He ICEs [ICEs(3He)] on JT-60U. For this purpose, at first, velocity distributions of deuterium-deuterium fusion produced fast 3He ions at the time of an appearance of the ICE(3He) were evaluated by using a fast ion orbit following code under a realistic condition. The calculated distribution at the edge of the plasma on the midplane on the low field side is shown to have an inverted population and strong anisotropy. This distribution can be reasonably approximated by the drifting-ring-type distribution. Next, dispersions of the MCIs driven by the drifting-ring-type distribution were compared with those of observed ICEs(3He). The comparison shows that toroidal wavenumbers and frequencies of the calculated MCIs agree with those of the observed ICEs(3He).
Impact of the Tilted Detector Solenoid on the Ion Polarization at JLEIC
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kondratenko, A. M.; Kondratenko, M. A.; Filatov, Yu N.
Jefferson Lab Electron Ion Collider (JLEIC) is a figure-8 collider "transparent" to the spin. This allows one to control the ion polarization using a universal 3D spin rotator based on weak solenoids. Besides the 3D spin rotator, a coherent effect on the spin is produced by a detector solenoid together with the dipole correctors and anti-solenoids compensating betatron oscillation coupling. The 4 m long detector solenoid is positioned along a straight section of the electron ring and makes a 50 mrad horizontal angle with a straight section of the ion ring. Such a large crossing angle is needed for amore » quick separation of the two colliding beams near the interaction point to make sufficient space for placement of interaction region magnets and to avoid parasitic collisions of shortly-spaced 476 MHz electron and ion bunches. We present a numerical analysis of the detector solenoid effect on the proton and deuteron polarizations. We demonstrate that the effect of the detector solenoid on the proton and deuteron polarizations can be compensated globally using an additional 3D rotator located anywhere in the ring.« less
NASA Astrophysics Data System (ADS)
Budzyński, P.; Kamiński, M.; Pyszniak, K.
2016-09-01
The implantation of nitrogen, carbon, and oxygen can be used for enhancing the tribological properties of critical components for internal combustion engines. Hardox and Raex steels have very similar strength parameters as for steel used for piston rings in internal combustion engines. An essential criterion when selecting material for the production of piston rings is a low friction factor and a low wear index. The aim of this study was to determine the extent to which these parameters can be enhanced by nitrogen ion implantation. Samples were implanted with nitrogen ions with 65 keV energy and the fluence of implanted ions set to 1.1017 N + /cm2. Friction and wear measurements were performed on a pin-on disc stand. The results demonstrate that implantation with nitrogen ions significantly reduces the friction factor and wear of Hardox 450 and Raex 400 steels. Implantation can and should be used for enhancing the tribological properties of steel used for friction elements in internal combustion engines, particularly when heat treatment is excluded. Final elements can be subjected to implantation, as the process does not change their dimensions.
The magnetic toroidal sector: a broad-band electron-positron pair spectrometer
NASA Astrophysics Data System (ADS)
Hagmann, Siegbert; Hillenbrand, Pierre-Michel; Litvinov, Yuri; Spillmann, Uwe
2016-05-01
At the future relativistic storage-ring HESR at FAIR the study of electron-positron pairs from non-nuclear, atomic processes will be one of the goals of the experimental program with kinematically complete experiments focusing on momentum spectroscopy of coincident emission of electrons and positrons from free-free pairs and corresponding recoil ions. The underlying production mechanisms belong to central topics of QED in strong fields. We present first results on the electron-optical properties of a magnetic toroidal sector configuration enabling coincident detection of free-free electron-positron pairs; this spectrometer is suitable for implementation into a storage ring with a supersonic jet target and covering a wide range of lepton emission into the forward hemisphere. The simulation calculations are performed using the OPERA code.
NASA Astrophysics Data System (ADS)
Bleile, A.; Egelhof, P.; Kluge, H.-J.; Liebisch, U.; Mc Cammon, D.; Meier, H. J.; Sebastián, O.; Stahle, C. K.; Stöhlker, T.; Weber, M.
2000-06-01
The precise determination of the Lamb shift in heavy hydrogen-like ions provides a sensitive test of QED in very strong Coulomb fields, not accessible otherwise, and has also the potential to deduce nuclear charge radii. A brief overview on the present status of such experiments, performed at the storage ring ESR at GSI Darmstadt, is given. For the investigation of the Lyman-α transitions in Au78+- or U91+- ions with improved accuracy a high resolving calorimetric low temperature detector for hard x-rays (E⩽100 keV) is presently developed. The detector modules consist of arrays of silicon thermistors and of x-ray absorbers made of high Z material to optimize the absorption efficiency. The detectors are housed in a specially designed 3He/4He dilution refrigerator which fits to the geometry of the ESR target. The detector performance presently achieved is already close to fulfill the demands of the Lamb shift experiment. For a prototype detector an energy resolution of ΔEFWHM=75 eV is obtained for 60 keV x-rays.
Dissociative Recombination of Molecular Ions for Astrochemistry
NASA Astrophysics Data System (ADS)
Novotny, Oldrich; Becker, A.; Buhr, H.; Fleischmann, Andreas; Gamer, Lisa; Geppert, W.; Krantz, C.; Kreckel, H.; Schwalm, D.; Spruck, K.; Wolf, A.; Savin, Daniel Wolf
2014-06-01
Dissociative recombination (DR) of molecular ions is a key chemical process in the cold interstellar medium (ISM). DR affects the composition, charge state, and energy balance of such environments. Astrochemical models of the ISM require reliable total DR cross sections as well as knowledge of the chemical composition of the neutral DR products. We have systematically measured DR for many astrophysically relevant molecular ions utilizing the TSR storage ring at the Max-Planck-Institute for Nuclear Physics (MPIK) in Heidelberg, Germany. We used the merged ion-electron beam technique combined with an energy- and position-sensitive imaging detector and are able to study DR down to plasma temperatures as low as 10 K. The DR count rate is used to obtain an absolute merged beams DR rate coefficient from which we can derive a thermal rate coefficient needed for plasma models. Additionally we determine the masses of the DR products by measuring their kinetic energy in the laboratory reference frame. This allows us to assign particular DR fragmentation channels and to obtain their branching ratios. All this information is particularly important for understanding DR of heteronuclear polyatomic ions. We will present DR results for several ions recently investigated at TSR. A new Cryogenic Storage Ring (CSR) is currently being commissioned at MPIK. With the chamber cooled down to ~10 K and a base pressure better than 10-13 mbar, this setup will allow internal cooling of the stored ions down to their rotational ground states, thus opening a new era in DR experiments. New technological challenges arise due to the ultracold, ultra-high vacuum environment of the CSR and thus the detection techniques used at TSR cannot be easily transferred to CSR. We will present new approaches for DR fragment detection in cryogenic environment. This work is supported in part by NASA and the NSF.
Electron Detachment Dissociation (EDD) of Fluorescently Labeled Sialylated Oligosaccharides
Zhou, Wen; Håkansson, Kristina
2012-01-01
We explored the application of electron detachment dissociation (EDD) and infrared multiphoton dissociation (IRMPD) tandem mass spectrometry to fluorescently labeled sialylated oligosaccharides. Standard sialylated oligosaccharides and a sialylated N-linked glycan released from human transferrin were investigated. EDD yielded extensive glycosidic cleavages and cross-ring cleavages in all cases studied, consistently providing complementary structural information compared to IRMPD. Neutral losses and satellite ions such as C – 2H ions were also observed following EDD. In addition, we examined the influence of different fluorescent labels. The acidic label 2-aminobenzoic acid (2-AA) enhanced signal abundance in negative-ion mode. However, few cross-ring fragments were observed for 2-AA labeled oligosaccharides. The neutral label 2-aminobenzamide (2-AB) resulted in more cross-ring cleavages compared to 2-AA labeled species, but not as extensive fragmentation as for native oligosaccharides, likely resulting from altered negative charge locations from introduction of the fluorescent tag. PMID:22120881
Arrays of ferromagnetic nanorings with variable thickness fabricated by capillary force lithography.
Lee, Su Yeon; Jeong, Jong-Ryul; Kim, Shin-Hyun; Kim, Sarah; Yang, Seung-Man
2009-11-03
A new promising strategy is reported for the fabrication of ferromagnetic nanoring arrays with novel geometrical features through the use of capillary force lithography and subsequent reactive ion etching. In particular, we fabricated two different types of elliptic rings with variable width and height: one with pinching zones near the major axes and the other with pinching zones near the minor axes. We used PDMS stamps with either elliptic hole or antihole arrays for creating these elliptic rings with variable thickness by virtue of the uneven capillary rise, which was induced by the distributed Laplace pressure around the walls of elliptic holes or antiholes with nonuniform local curvatures. We transferred the polymer ring patterns to array of elliptical NiFe rings by Ar ion milling and characterized magnetic properties in terms of nonuniform ring width using magnetic force microscopy measurements. Our results demonstrated that the magnetic domain wall can be positioned in a controlled manner by using these novel elliptical ferromagnetic rings with local pinching zones and that the proposed CFL method can be utilized as a simple and effective fabrication tool.
Tikhonov, Denis B; Zhorov, Boris S
2011-01-28
In the absence of x-ray structures of sodium and calcium channels their homology models are used to rationalize experimental data and design new experiments. A challenge is to model the outer-pore region that folds differently from potassium channels. Here we report a new model of the outer-pore region of the NaV1.4 channel, which suggests roles of highly conserved residues around the selectivity filter. The model takes from our previous study (Tikhonov, D. B., and Zhorov, B. S. (2005) Biophys. J. 88, 184-197) the general disposition of the P-helices, selectivity filter residues, and the outer carboxylates, but proposes new intra- and inter-domain contacts that support structural stability of the outer pore. Glycine residues downstream from the selectivity filter are proposed to participate in knob-into-hole contacts with the P-helices and S6s. These contacts explain the adapted tetrodotoxin resistance of snakes that feed on toxic prey through valine substitution of isoleucine in the P-helix of repeat IV. Polar residues five positions upstream from the selectivity filter residues form H-bonds with the ascending-limb backbones. Exceptionally conserved tryptophans are engaged in inter-repeat H-bonds to form a ring whose π-electrons would facilitate passage of ions from the outer carboxylates to the selectivity filter. The outer-pore model of CaV1.2 derived from the NaV1.4 model is also stabilized by the ring of exceptionally conservative tryptophans and H-bonds between the P-helices and ascending limbs. In this model, the exceptionally conserved aspartate downstream from the selectivity-filter glutamate in repeat II facilitates passage of calcium ions to the selectivity-filter ring through the tryptophan ring. Available experimental data are discussed in view of the models.
Ring and plasma - The enigmae of Enceladus
NASA Technical Reports Server (NTRS)
Haff, P. K.; Siscoe, G. L.; Eviatar, A.
1983-01-01
The E ring associated with the Kronian moon Enceladus has a lifetime of only a few thousand years against sputtering by slow corotating O ions. The existence of the ring implies the necessity for a continuous supply of matter. Possible particle source mechanisms on Enceladus include meteoroidal impact ejection and geysering. Estimates of ejection rates of particulate debris following small meteoroid impact are on the order of 3 x 10 to the -18th g/(sq cm sec), more than an order of magnitude too small to sustain the ring. A geyser source would need to generate a droplet supply at a rate of approximately 10 to the -16th g/(sq cm sec) in order to account for a stable ring. Enceladus and the ring particles also directly supply both plasma and vapor to space via sputtering. The absence of a 60 eV plasma at the Voyager 2 Enceladus L-shell crossing, such as might have been expected from sputtering, cannot be explained by absorption and moderation of plasma ions by ring particles, because the ring is too diffuse. Evidently, the effective sputtering yield in the vicinity of Enceladus is on the order of, or smaller than, 0.4, about an order of magnitude less than te calculated value. Small scale surface roughness may account for some of this discrepancy.
Preiss, Laura; Klyszejko, Adriana L.; Hicks, David B.; Liu, Jun; Fackelmayer, Oliver J.; Yildiz, Özkan; Krulwich, Terry A.; Meier, Thomas
2013-01-01
The c-rings of ATP synthases consist of individual c-subunits, all of which harbor a conserved motif of repetitive glycine residues (GxGxGxG) important for tight transmembrane α-helix packing. The c-ring stoichiometry determines the number of ions transferred during enzyme operation and has a direct impact on the ion-to-ATP ratio, a cornerstone parameter of cell bioenergetics. In the extreme alkaliphile Bacillus pseudofirmus OF4, the glycine motif is replaced by AxAxAxA. We performed a structural study on two mutants with alanine-to-glycine changes using atomic force microscopy and X-ray crystallography, and found that mutants form smaller c12 rings compared with the WT c13. The molar growth yields of B. pseudofirmus OF4 cells on malate further revealed that the c12 mutants have a considerably reduced capacity to grow on limiting malate at high pH. Our results demonstrate that the mutant ATP synthases with either c12 or c13 can support ATP synthesis, and also underscore the critical importance of an alanine motif with c13 ring stoichiometry for optimal growth at pH >10. The data indicate a direct connection between the precisely adapted ATP synthase c-ring stoichiometry and its ion-to-ATP ratio on cell physiology, and also demonstrate the bioenergetic challenges and evolutionary adaptation strategies of extremophiles. PMID:23613590
NASA Astrophysics Data System (ADS)
Waldrop, L.; Cucho-Padin, G.; Ilie, R.
2017-12-01
Charge exchange collisions between ring current ions and hydrogen (H) atoms in the outer exosphere serve to dissipate magnetospheric energy, particularly during the slow recovery phase of geomagnetic storms, through the generation of energetic neutral atoms (ENAs) which escape the system. As a result, knowledge of the spatial distribution and temporal variability of exospheric H density is critical for reliable interpretation of ENA flux measurements as well as for accurate modeling of the ring current. Although numerous theoretical, numerical, and empirical H distributions have been used for such analyses, their reliance on ad hoc or unphysical assumptions, together with their inherently static formulations, is a source of significant uncertainty. Our recent development of a robust tomographic technique for the model-independent estimation of global exospheric H density from optical remote sensing data overcomes the limitations of past analysis and enables an unprecedented investigation of global exospheric and ring current dynamics. Here, we present sample results of our 3D, time-dependent reconstructions of exospheric structure, derived from measurements of resonantly scattered solar Lyman-alpha (121.6 nm) photons acquired by the Lyman-alpha detectors (LADs) onboard NASA's Two Wide-angle Imaging Neutral-atom Spectrometers (TWINS) mission. We use the Hot Electron and Ion Drift Integrator (HEIDI) kinetic model of the ring current to investigate the charge exchange interactions between the resulting H density distribution and ring current ions and generate synthetic images of ENA flux for comparison with those measured by TWINS.
Ho, Jr-Wei; Chen, Wei-Kan; Cheng, Po-Yuan
2009-10-07
We report studies of ultrafast dynamics of azobenzene cation using femtosecond photoionization-photofragmentation spectroscopy. In our experiments, a femtosecond pump pulse first produces an ensemble of azobenzene cations via photoionization of the neutrals. A delayed probe pulse then brings the evolving ionic system to excited states that ultimately undergo ion fragmentation. The dynamics is followed by monitoring either the parent-ion depletion or fragment-ion formation as a function of the pump-probe delay time. The observed transients for azobenzene cation are characterized by a constant ion depletion modulated by a rapidly damped oscillatory signal with a period of about 1 ps. Theoretical calculations suggest that the oscillation arises from a vibration motion along the twisting inversion coordinate involving displacements in CNNC and phenyl-ring torsions. The oscillation is damped rapidly with a time constant of about 1.2 ps, suggesting that energy dissipation from the active mode to bath modes takes place in this time scale.
Liu, Jian; Shi, Guosheng; Fang, Haiping
2017-02-24
Carbon-based nanoporous membranes, such as carbon nanotubes (CNTs), graphene/graphene oxide and graphyne, have shown great potential in water desalination and purification, gas and ion separation, biosensors, and lithium-based batteries, etc. A deep understanding of the interaction between hydrated ions in an aqueous solution and the graphitic surface in systems composed of water, ions and a graphitic surface is essential for applications with carbon-based nanoporous membrane platforms. In this review, we describe the recent progress of the interaction between hydrated ions and aromatic ring structures on the carbon-based surface and its applications in the water flow in a carbon nanotube. We expect that these works can be extended to the understanding of water flow in other nanoporous membranes, such as nanoporous graphene, graphyne and stacked sheets of graphene oxide.
Stoev, Georgi; Nazarov, Valeri
2008-06-01
Structures of seven impurities of the veterinary drug tilmicosin have been elucidated by multiple fragmentation with ion trap tandem mass spectrometry. All related compounds possess the main lactone ring of tilmicosin. The differences in their structures are due to the hydroxyl, mycaminose, 3,5-dimethylpiperidine and mycinose groups connected to C(3), C(5), C(6), C(14) of the lactone ring, respectively. The following compounds of the impurity profile of tilmicosin were identified: B - tilmicosin with a hydroxyl group at C(3); C - tilmicosin without a methyl group at the N-atom connected to C(3) of the mycaminose ring; D - tilmicosin with a hydroxyl group at C(6) of the mycaminose ring; E - tilmicosin with a methoxy group at C(3), F - desmicosin; G - 20-dihydrodesmicosin; and H - tilmicosin without a mycaminose ring. Isomers of the compounds B, C, D, E and H were identified by their mass chromatograms and retention times. The concentrations of the impurities varied in the range of 0.1% to 2.9%.
Marek, Aleš; Tureček, František
2014-05-01
Gas-phase dissociations were investigated for several peptide ions containing the Gly-Leu* N-terminal motif where Leu* was a modified norleucine residue containing the photolabile diazirine ring. Collisional activation of gas-phase peptide cations resulted in facile N₂ elimination that competed with backbone dissociations. A free lysine ammonium group can act as a Brønsted acid to facilitate N₂ elimination. This dissociation was accompanied by insertion of a lysine proton in the side chain of the photoleucine residue, as established by deuterium labeling and gas-phase sequencing of the products. Electron structure calculations were used to provide structures and energies of reactants, intermediates, and transition states for Gly-Leu*-Gly-Gly-Lys amide ions that were combined with RRKM calculations of unimolecular rate constants. The calculations indicated that Brønsted acid-catalyzed eliminations were kinetically preferred over direct loss of N₂ from the diazirine ring. Mechanisms are proposed to explain the proton-initiated reactions and discuss the reaction products. The non-catalyzed diazirine ring cleavage and N₂ loss is proposed as a thermometer dissociation for peptide ion dissociations.
Four faces of the interaction between ions and aromatic rings.
Papp, Dóra; Rovó, Petra; Jákli, Imre; Császár, Attila G; Perczel, András
2017-07-15
Non-covalent interactions between ions and aromatic rings play an important role in the stabilization of macromolecular complexes; of particular interest are peptides and proteins containing aromatic side chains (Phe, Trp, and Tyr) interacting with negatively (Asp and Glu) and positively (Arg and Lys) charged amino acid residues. The structures of the ion-aromatic-ring complexes are the result of an interaction between the large quadrupole moment of the ring and the charge of the ion. Four attractive interaction types are proposed to be distinguished based on the position of the ion with respect to the plane of the ring: perpendicular cation-π (CP ⊥ ), co-planar cation-π (CP ∥ ), perpendicular anion-π (AP ⊥ ), and co-planar anion-π (AP ∥ ). To understand more than the basic features of these four interaction types, a systematic, high-level quantum chemical study is performed, using the X - + C 6 H 6 , M + + C 6 H 6 , X - + C 6 F 6 , and M + + C 6 F 6 model systems with X - = H - , F - , Cl - , HCOO - , CH 3 COO - and M + = H + , Li + , Na + , NH4+, CH 3 NH3+, whereby C 6 H 6 and C 6 F 6 represent an electron-rich and an electron-deficient π system, respectively. Benchmark-quality interaction energies with small uncertainties, obtained via the so-called focal-point analysis (FPA) technique, are reported for the four interaction types. The computations reveal that the interactions lead to significant stabilization, and that the interaction energy order, given in kcal mol -1 in parentheses, is CP ⊥ (23-37) > AP ⊥ (14-21) > CP ∥ (9-22) > AP ∥ (6-16). A natural bond orbital analysis performed leads to a deeper qualitative understanding of the four interaction types. To facilitate the future quantum chemical characterization of ion-aromatic-ring interactions in large biomolecules, the performance of three density functional theory methods, B3LYP, BHandHLYP, and M06-2X, is tested against the FPA benchmarks, with the result that the M06-2X functional performs best. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.
Power law "thermalization" of ion pickup and ionospheric outflows
NASA Astrophysics Data System (ADS)
Moore, T. E.; Ofman, L.; Glocer, A.; Gershman, D. J.; Khazanov, G. V.; Paterson, W. R.
2016-12-01
One observed feature of ionospheric outflows is that the active ion heating processes produce power law tails of the core plasma velocity distribution, as well as transverse or conic peaks in the angular distributions. This characteristic is shared with hot ion distributions produced by ion pickup in the solar wind, resulting from cometary or interstellar gas ionization, and with hot ions observed around the Space Transportation System during gas releases. We revisit relevant observations and consider the hypothesis that the ion pickup thermalization process tends to produce power law (𝛋) energy distributions, using a simulation of the instability of a simple pickup (ring) distribution. Simulation results are derived for cases representative of both solar wind pickup, where ion velocities exceed the local Alfvén speed, and ionospheric pickup, where the local Alfvén speed exceeds ion velocities. The sub-Alfvenic pickup ring distribution appears to have a slow growth rate (per ion gyro period), that is, the instability evolves more slowly in the latter case than in the former. Implications for ionospheric outflow are discussed.
NASA Astrophysics Data System (ADS)
Yuan, Zhigang; Qiao, Zheng; Li, Haimeng; Huang, Shiyong; Wang, Dedong; Yu, Xiongdong; Yu, Tao
2017-04-01
Subauroral polarization stream (SAPS) electric field can play an important role in the coupling between the inner magnetosphere and ionosphere; however, the production mechanism of SAPS has not been yet solved. During an energetic ion injection event on 26 March 2004, at latitudes lower than the equatorward boundaries of precipitating plasma sheet electrons and ions, the Defense Meteorological Satellite Program (DMSP) F13 satellite simultaneously observed a strong SAPS with the peak velocity of 1294 m/s and downward flowing field-aligned currents (FACs). Conjugate observations of DMSP F13 and NOAA 15 satellites have shown that FACs flowing into the ionosphere just lie in the outer boundary of the ring current (RC). The downward flowing FACs were observed in a region of positive latitudinal gradients of the ion energy density, implying that the downward flowing FACs are more likely linked to the azimuthal gradient than the radial gradient of the RC ion pressure. Our result demonstrates that RC ion pressure gradients on the outer boundary of the RC in the evening sector during energetic ion injection events can lead to downward flowing FACs so as to cause strong SAPS in condition of low ionospheric conductivities.
On the stability of pick-up ion ring distributions in the outer heliosheath
DOE Office of Scientific and Technical Information (OSTI.GOV)
Summerlin, Errol J.; Viñas, Adolfo F.; Moore, Thomas E.
The 'secondary energetic neutral atom (ENA)' hypothesis for the ribbon feature observed by the Interstellar Boundary Explorer (IBEX) posits that the neutral component of the solar wind continues beyond the heliopause and charge exchanges with interstellar ions in the Outer Heliosheath (OHS). This creates pick-up ions that gyrate about the draped interstellar magnetic field (ISMF) lines at pitch angles near 90° on the locus where the ISMF lies tangential to the heliopause and perpendicular to the heliocentric radial direction. This location closely coincides with the location of the ribbon feature according to the prevailing inferences of the ISMF orientation andmore » draping. The locally gyrating ions undergo additional charge exchange and escape as free-flying neutral atoms, many of which travel back toward the inner solar system and are imaged by IBEX as a ribbon tracing out the locus described above. For this mechanism to succeed, the pick-up ions must diffuse in pitch angle slowly enough to permit secondary charge exchange before their pitch angle distribution substantially broadens away from 90°. Previous work using linear Vlasov dispersion analysis of parallel propagating waves has suggested that the ring distribution in the OHS is highly unstable, which, if true, would make the secondary ENA hypothesis incapable of rendering the observed ribbon. In this paper, we extend this earlier work to more realistic ring distribution functions. We find that, at the low densities necessary to produce the observed IBEX ribbon via the secondary ENA hypothesis, growth rates are highly sensitive to the temperature of the beam and that even very modest temperatures of the ring beam corresponding to beam widths of <1° are sufficient to damp the self-generated waves associated with the ring beam. Thus, at least from the perspective of linear Vlasov dispersion analysis of parallel propagating waves, there is no reason to expect that the ring distributions necessary to produce the observed IBEX ENA flux via the secondary ENA hypothesis will be unstable to their own self-generated turbulence.« less
On the Stability of Pick-up Ion Ring Distributions in the Outer Heliosheath
NASA Astrophysics Data System (ADS)
Summerlin, Errol J.; Viñas, Adolfo F.; Moore, Thomas E.; Christian, Eric R.; Cooper, John F.
2014-10-01
The "secondary energetic neutral atom (ENA)" hypothesis for the ribbon feature observed by the Interstellar Boundary Explorer (IBEX) posits that the neutral component of the solar wind continues beyond the heliopause and charge exchanges with interstellar ions in the Outer Heliosheath (OHS). This creates pick-up ions that gyrate about the draped interstellar magnetic field (ISMF) lines at pitch angles near 90° on the locus where the ISMF lies tangential to the heliopause and perpendicular to the heliocentric radial direction. This location closely coincides with the location of the ribbon feature according to the prevailing inferences of the ISMF orientation and draping. The locally gyrating ions undergo additional charge exchange and escape as free-flying neutral atoms, many of which travel back toward the inner solar system and are imaged by IBEX as a ribbon tracing out the locus described above. For this mechanism to succeed, the pick-up ions must diffuse in pitch angle slowly enough to permit secondary charge exchange before their pitch angle distribution substantially broadens away from 90°. Previous work using linear Vlasov dispersion analysis of parallel propagating waves has suggested that the ring distribution in the OHS is highly unstable, which, if true, would make the secondary ENA hypothesis incapable of rendering the observed ribbon. In this paper, we extend this earlier work to more realistic ring distribution functions. We find that, at the low densities necessary to produce the observed IBEX ribbon via the secondary ENA hypothesis, growth rates are highly sensitive to the temperature of the beam and that even very modest temperatures of the ring beam corresponding to beam widths of <1° are sufficient to damp the self-generated waves associated with the ring beam. Thus, at least from the perspective of linear Vlasov dispersion analysis of parallel propagating waves, there is no reason to expect that the ring distributions necessary to produce the observed IBEX ENA flux via the secondary ENA hypothesis will be unstable to their own self-generated turbulence.
Brusilowskij, Boris; Dzyuba, Egor V; Troff, Ralf W; Schalley, Christoph A
2011-12-07
3,3'-Bis(pyridin-[n]-ylethynyl)biphenyl (n = 3, 4) and the corresponding 2,2'-bipyridines assemble with (dppp)Pt(II) triflate into metallo-supramolecular polygons. Depending on the position of the terminal pyridine N atoms, the assembly reaction leads to different equilibrium products. With the slow ligand exchange on Pt(II) complexes, the equilibrium is reached on a many-hour time-scale. During the assembly process, larger polygons form under kinetic control. This was confirmed by time-dependent (1)H and (31)P NMR spectroscopy in line with complementary ESI mass spectrometric experiments. The constitutional difference in the pyridine N-atom position is reflected in the tandem mass spectra of the complex ions. In addition, a highly specific fragmentation process of mass-selected M(3)L(3) ions was observed, which proceeds through a ring contraction yielding smaller M(2)L(2) ions.
NASA Astrophysics Data System (ADS)
Martens, Sabrina M.; Marta, Rick A.; Martens, Jonathan K.; McMahon, Terry B.
2012-10-01
Protonated ferulic acid and its principle fragment ion have been characterized using infrared multiple photon dissociation spectroscopy and electronic structure calculations at the B3LYP/6-311 + G(d,p) level of theory. Due to its extensively conjugated structure, protonated ferulic acid is observed to yield three stable fragment ions in IRMPD experiments. It is proposed that two parallel fragmentation pathways of protonated ferulic acid are being observed. The first pathway involves proton transfer, resulting in the loss of water and subsequently carbon monoxide, producing fragment ions m/z 177 and 149, respectively. Optimization of m/z 177 yields a species containing an acylium group, which is supported by a diagnostic peak in the IRMPD spectrum at 2168 cm-1. The second pathway involves an alternate proton transfer leading to loss of methanol and rearrangement to a five-membered ring.
Space charge tune shift, fast resonance traversal, and current limits in circular accelerators
DOE Office of Scientific and Technical Information (OSTI.GOV)
Rees, G.H.
1996-06-01
Space charge tune shifts, fast resonance traversals, and current limits are important design issues for low energy, high power circular accelerators. Areas of interest are accumulator rings and fast cycling synchrotrons, and typical applications are for pulsed spallation neutron sources, heavy ion fusion storage ring drivers, and booster injectors for high energy proton and ion facilities. Aspects of the three topics are discussed in the paper. {copyright} {ital 1996 American Institute of Physics.}
Stationary-Afterglow measurements of dissociative recombination of H2D+ and HD2+ ions
NASA Astrophysics Data System (ADS)
Dohnal, Petr; Kalosi, Abel; Plasil, Radek; Johnsen, Rainer; Glosik, Juraj
2016-09-01
Binary recombination rate coefficients of H2D+ and HD2+ ions have been measured at a temperature of 80 K in an afterglow plasma experiment in which the fractional abundances of H3+, H2D+, HD2+, and D3+ ions were varied by adjusting the [D2]/([D2] + [H2]) ratio of the neutral gas. The fractional abundances of the four ion species during the afterglow and their rotational states were determined in situ by continuous-wave cavity ring-down absorption spectroscopy (CRDS), using overtone transitions from the ground vibrational states of the ions. The experimentally determined recombination rate coefficients will be compared to results of advanced theoretical calculations and to the known H3+ and D3+ recombination rate coefficients. We conclude that the recombination coefficients depend only weakly on the isotopic composition. Astrophysical implications of the measured recombination rate coefficients will be also discussed. Work supported by: Czech Science Foundation projects GACR 14-14649P, GACR 15-15077S, GACR P209/12/0233, and by Charles University in Prague Project Nr. GAUK 692214.
Ion-driven wind: Aerodynamics, performance limits, and optimization
NASA Astrophysics Data System (ADS)
Rickard, Matthew James Alan
When a strong electric field is generated between a sharp, charged object and a grounded electrode in a gas medium, ions that are generated via a corona discharge near the tip of the sharp object migrate to the electrical ground, setting the neutral hulk gas in motion. The strength of the flow generated from such a process; known as a "corona", "ionic", or "ion-driven" wind, increases with electric field until electrical breakdown is reached. Previous studies have found an upper bound on the velocity of the ion-driven wind, even when a series of electrode stages are aggregated. With the intent of maximizing the gas flow front such devices, this dissertation describes a series of experiments that have been conducted and a numerical model that has been employed. Although typical hardware configurations include a wire parallel to a plate, a wire placed concentrically within a cylinder, or a needle facing a perpendicular plate or mesh, the chosen setup for this study is a needle facing a concentric ring. Using multiple experimental techniques and numerical simulation, velocity profiles have been observed at the ring exit and are sensitive to the design of the mounting hardware. The numerical model predicts the ideal electrode geometry for maximizing flow through a single unit. A modular, multi-staged system has been constructed and, when loaded with an exit nozzle, the exit velocity can be substantially increased. Further, if a small-scale (sub-millimeter) system is created, it is expected that the velocity will increase with multi-staging, even in the absence of an exit nozzle.
Continuous wave cavity ring-down spectroscopy for velocity distribution measurements in plasma
DOE Office of Scientific and Technical Information (OSTI.GOV)
McCarren, D.; Lockheed Martin, Palmdale, California 93599; Scime, E., E-mail: earl.scime@mail.wvu.edu
2015-10-15
We report the development of a continuous wave cavity ring-down spectroscopic (CW-CRDS) diagnostic for real-time, in situ measurement of velocity distribution functions of ions and neutral atoms in plasma. This apparatus is less complex than conventional CW-CRDS systems. We provide a detailed description of the CW-CRDS apparatus as well as measurements of argon ions and neutrals in a high-density (10{sup 9} cm{sup −3} < plasma density <10{sup 13} cm{sup −3}) plasma. The CW-CRDS measurements are validated through comparison with laser induced fluorescence measurements of the same absorbing states of the ions and neutrals.
Winske, D.; Daughton, W.
2015-02-02
We present results of three-dimensional electromagnetic particle-in-cell simulations of the lower hybrid ion ring instability, similar to our earlier results [D. Winske and W. Daughton, Phys. Plasma, 19, 072109, 2012], but at higher electron beta (βe = ratio of electron thermal pressure to magnetic pressure = 0.06, rather than at 0.006) with Ti = Te. At higher electron beta the level of lower hybrid waves at saturation normalized to the ion thermal energy (βi = 0.06 also) is only slightly smaller, but the corresponding magnetic fluctuations are about an order of magnitude larger, consistent with linear theory. After saturation, themore » waves evolve into whistler waves, through a number of possible mechanisms, with an average growth rate considerably smaller than the linear growth rate of the lower hybrid waves, to a peak fluctuation level that is about 20% above the lower hybrid wave saturation level. The ratio of the peak magnetic fluctuations associated with the whistler waves relative to those of the saturated lower hybrid waves, the ratio of the nonlinear growth rate of whistlers relative to the linear growth rate of lower hybrid waves, the amount of energy extracted from the ring and the amount of heating of the background ions and electrons are comparable to those in the lower electron beta 3-D simulation. This suggests that even at higher electron beta, the linear and nonlinear physics of the lower hybrid ion ring instability is dominated by electrostatic, wave-particle rather than wave-wave interactions.« less
NASA Technical Reports Server (NTRS)
Khazanov, George V.
2006-01-01
The self-consistent treatment of the RC ion dynamics and EMIC waves, which are thought to exert important influences on the ion dynamical evolution, is an important missing element in our understanding of the storm-and recovery-time ring current evolution. Under certain conditions, relativistic electrons, with energies 21 MeV, can be removed from the outer radiation belt by EMIC wave scattering during a magnetic storm. That is why the modeling of EMIC waves is critical and timely issue in magnetospheric physics. To describe the RC evolution itself this study uses the ring current-atmosphere interaction model (RAM). RAM solves the gyration and bounce-averaged Boltzmann-Landau equation inside of geosynchronous orbit. Originally developed at the University of Michigan, there are now several branches of this model currently in use as describe by Liemohn namely those at NASA Goddard Space Flight Center This study will generalize the self-consistent theoretical description of RC ions and EMIC waves that has been developed by Khazanov and include the heavy ions and propagation effects of EMIC waves in the global dynamic of self-consistent RC - EMIC waves coupling. The results of our newly developed model that will be presented at GEM meeting, focusing mainly on the dynamic of EMIC waves and comparison of these results with the previous global RC modeling studies devoted to EMIC waves formation. We also discuss RC ion precipitations and wave induced thermal electron fluxes into the ionosphere.
Self-Consistent Magnetosphere-Ionosphere Coupling and Associated Plasma Energization Processes
NASA Technical Reports Server (NTRS)
Khazanov, G. V.; Six, N. Frank (Technical Monitor)
2002-01-01
Magnetosphere-Ionosphere (MI) coupling and associated with this process electron and ion energization processes have interested scientists for decades and, in spite of experimental and theoretical research efforts, are still ones of the least well known dynamic processes in space plasma physics. The reason for this is that the numerous physical processes associated with MI coupling occur over multiple spatial lengths and temporal scales. One typical example of MI coupling is large scale ring current (RC) electrodynamic coupling that includes calculation of the magnetospheric electric field that is consistent with the ring current (RC) distribution. A general scheme for numerical simulation of such large-scale magnetosphere-ionosphere coupling processes has been presented earlier in many works. The mathematical formulation of these models are based on "modified frozen-in flux theorem" for an ensemble of adiabatically drifting particles in the magnetosphere. By tracking the flow of particles through the inner magnetosphere, the bounce-averaged phase space density of the hot ions and electrons can be reconstructed and the magnetospheric electric field can be calculated such that it is consistent with the particle distribution in the magnetosphere. The new a self-consistent ring current model has been developed that couples electron and ion magnetospheric dynamics with calculation of electric field. Two new features were taken into account in addition to the RC ions, we solve an electron kinetic equation in our model, self-consistently including these results in the solution. Second, using different analytical relationships, we calculate the height integrated ionospheric conductances as the function of precipitated high energy magnetospheric electrons and ions as produced by our model. This results in fundamental changes to the electric potential pattern in the inner magnetosphere, with a smaller Alfven boundary than previous potential formulations would predict but one consistent with recent satellite observations. This leads to deeper penetration of the plasma sheet ions and electrons into the inner magnetosphere and more effective ring current ions and electron energization.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Fournier, Joseph A.; Wolke, Conrad T.; Johnson, Christopher J.
2015-02-14
We clarify the role of the critical imidazolium C{sub (2)}H position (the central C between N atoms in the heterocycle) in the assembly motif of the [EMIM][BF{sub 4}] ionic liquid by analyzing the vibrational spectra of the bare EMIM{sup +} ion as well as that of the cationic [EMIM]{sub 2}[BF{sub 4}]{sup +} (EMIM{sup +} = 1-ethyl-3-methylimidazolium, C{sub 6}H{sub 11}N{sub 2}{sup +}) cluster. Vibrational spectra of the cold, mass-selected ions are obtained using cryogenic ion vibrational predissociation of weakly bound D{sub 2} molecules formed in a 10 K ion trap. The C{sub (2)}H behavior is isolated by following the evolution ofmore » key vibrational features when the C{sub (2)} hydrogen, the proposed binding location of the anion to the imidazolium ring, is replaced by either deuterium or a methyl group (i.e., in the EMMIM{sup +} analogue). Strong features in the ring CH stretching region of the bare ion are traced to Fermi resonances with overtones of lower frequency modes. Upon incorporation into the EMIM{sup +} ⋅ ⋅ ⋅ BF{sub 4}{sup −} ⋅ ⋅ ⋅ EMIM{sup +} ternary complex, the C{sub (2)}H oscillator strength is dramatically increased, accounting for the much more complicated patterns derived from the EMIM{sup +} ring CH stretches in the light isotopomer, which are strongly suppressed in the deuterated analogue. Further changes in the spectra that occur when the C{sub (2)}H is replaced by a methyl group are consistent with BF{sub 4}{sup −} attachment directly to the imidazolium ring in an arrangement that maximizes the electrostatic interaction between the molecular ions.« less
Ion related problems for the XLS ring
NASA Astrophysics Data System (ADS)
Bozoki, Eva S.; Halama, Henry
1991-10-01
The electron beam in a storage ring collides with the residual gas in the vacuum chamber. As a consequence, low velocity positive ions are produced and trapped in the potential well of the electron beam. They perform stable or unstable oscillations around the beam under the repetitive Coulomb force of the bunches. If not cleared, the captured ions can lead to partial or total neutralization of the beam, causing both a decrease of lifetime and a change in the vertical tunes as well as an increase in the tune spread. It can also cause coherent and incoherent transverse instabilities. An electrostatic clearing electrodes system was designed to keep the neutralization below a desired limit. The location and the geometry of the clearing electrodes as well as the applied clearing voltage is based on the study of the ion production rate, longitudinal velocity of ions in field-free regions and in the dipoles, beam self-electric field, beam potential, critical mass for ion capture in the bunched beam and the bounce frequencies of the ions, tune shift and pressure rise due to trapped ions.
Neutral and Plasma Sources in the Saturn's Magnetosphere
NASA Astrophysics Data System (ADS)
Jurac, S.; Johnson, R. E.
1999-05-01
The heavy ion plasma in Saturnian inner magnetosphere is derived from the icy satellites and ring particles imbedded in the plasma. Recent Hubble Space Telescope measurements of the densities of neutral OH molecules which co-exist with and are precursors of the plasma ions have constrained models for the plasma sources. Richardson et al (1998) considered all existing HST observations and derived water-like neutral densities and estimated required sources to maintain equilibrium. Their neutral densities show maximum close to Enceladus (where the E-ring density peaks) and their total neutral source rate needed to maintain neutrals in steady state is for an order of magnitude larger than source rate given by Shi et al (1995). We model the sputtering of water-ice using the recently developed Monte-Carlo collisional transport code, and calculate neutral supply rates from sputtering of Enceladus and the E-ring. This collisional code, used previously to evaluate sputtering from the interstellar grains (Jurac et al, 1998) is modified to include electronic processes relevant to water-ice sputtering, and then applied to the E-ring grains. It is shown that the grain erosion rate increases substantially when the ion penetration depth becomes comparable to the grain radius. The sputtering and collection rates for plasma ions and neutrals are evaluated and it is shown that the E-ring might be the dominant source of water-like neutrals in the Saturnian magnetosphere. We also describe competition between grain growth and erosion and discuss implications to the existing E-ring evolutionary models. References: Jurac S., R. E. Johnson, B. Donn; Astroph. J. 503, 247, 1998 Richardson, J. D., A. Eviatar, M. A. McGrath, V. M. Vasyliunas; J. Geophys. Res., 103, 20245, 1998 Shi, M., R.A. Baragiola, D.E. Grosjean, R.E. Johnson, S. Jurac and J. Schou; J. Geophys. Res., 100, 26387, 1995.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Malapit, Giovanni M.; Department of Physical Sciences, University of the Philippines Baguio, Baguio City 2600; Mahinay, Christian Lorenz S.
2012-02-15
A plasma sputter-type negative ion source is utilized to produce and detect negative Zr ions with energies between 150 and 450 eV via a retarding potential-type electrostatic energy analyzer. Traditional and modified semi-cylindrical Faraday cups (FC) inside the analyzer are employed to sample negative Zr ions and measure corresponding ion currents. The traditional FC registered indistinct ion current readings which are attributed to backscattering of ions and secondary electron emissions. The modified Faraday cup with biased repeller guard ring, cut out these signal distortions leaving only ringings as issues which are theoretically compensated by fitting a sigmoidal function into themore » data. The mean energy and energy spread are calculated using the ion current versus retarding potential data while the beam width values are determined from the data of the transverse measurement of ion current. The most energetic negative Zr ions yield tighter energy spread at 4.11 eV compared to the least energetic negative Zr ions at 4.79 eV. The smallest calculated beam width is 1.04 cm for the negative Zr ions with the highest mean energy indicating a more focused beam in contrast to the less energetic negative Zr ions due to space charge forces.« less
NASA Technical Reports Server (NTRS)
Stuedemann, W.; Wilken, B.; Kremser, G.; Gloeckler, G.; Ipavich, F. M.
1986-01-01
Ion composition measurements in the entire energy range of the ring current population, obtained with the Charge-, Energy-, Mass-spectrometer instrument on the Charge Composition Explorer in September 1984, are reported. From the energy spectra obtained for all major constituents during the main phase of a magnetic storm, the number densities, energy densities, and mean energies are calculated and displayed as radial profiles. The mean energies of He(2+) are found to be about twice that of H(+) and He(+) throughout this storm, and the time profiles for the mean energies of all major ions are seen to bunch together (when normalizing mean energies by the ionic charge), with the largest variations of the energy densities and mean energies occurring for O(+) ions.
Phase locked multiple rings in the radiation pressure ion acceleration process
NASA Astrophysics Data System (ADS)
Wan, Y.; Hua, J. F.; Pai, C.-H.; Li, F.; Wu, Y. P.; Lu, W.; Zhang, C. J.; Xu, X. L.; Joshi, C.; Mori, W. B.
2018-04-01
Laser contrast plays a crucial role for obtaining high quality ion beams in the radiation pressure ion acceleration (RPA) process. Through one- and two-dimensional particle-in-cell (PIC) simulations, we show that a plasma with a bi-peak density profile can be produced from a thin foil on the effects of a picosecond prepulse, and it can then lead to distinctive modulations in the ion phase space (phase locked double rings) when the main pulse interacts with the target. These fascinating ion dynamics are mainly due to the trapping effect from the ponderomotive potential well of a formed moving standing wave (i.e. the interference between the incoming pulse and the pulse reflected by a slowly moving surface) at nodes, quite different from the standard RPA process. A theoretical model is derived to explain the underlying mechanism, and good agreements have been achieved with PIC simulations.
Ratiometric fluorescent nanosensor based on carbon dots for the detection of mercury ion
NASA Astrophysics Data System (ADS)
Ma, Yusha; Mei, Jing; Bai, Jianliang; Chen, Xu; Ren, Lili
2018-05-01
A novel ratiometric fluorescent nanosensor based on carbon dots has been synthesized via bonding rhodamine B hydrazide to the carbon dots surface by an amide reaction. The ratiometric fluorescent nanosensor showed only a single blue fluorescence emission around 450 nm. While, as mercury ion was added, due to the open-ring of rhodamine moiety bonded on the CDs surface, the orange emission of the open-ring rhodamine would increase obviously according to the concentration of mercury ion, resulting in the distinguishable dual emissions at 450 nm and 575 nm under a single 360 excitation wavelength. Meanwhile, the ratiometric fluorescent nanosensor based on carbon dots we prepared is more sensitive to qualitative and semi-quantitative detection of mercury ion in the range of 0–100 μM, because fluorescence changes gradually from blue to orange emission under 365 nm lamp with the increasing of mercury ion in the tested solution.
Phase locked multiple rings in the radiation pressure ion acceleration process
Wan, Y.; Hua, J. F.; Pai, C. -H.; ...
2018-03-05
Laser contrast plays a crucial role for obtaining high quality ion beams in the radiation pressure ion acceleration (RPA) process. Through one- and two-dimensional particle-in-cell (PIC) simulations, we show that a plasma with a bi-peak density profile can be produced from a thin foil on the effects of a picosecond prepulse, and it can then lead to distinctive modulations in the ion phase space (phase locked double rings) when the main pulse interacts with the target. These fascinating ion dynamics are mainly due to the trapping effect from the ponderomotive potential well of a formed moving standing wave (i.e. themore » interference between the incoming pulse and the pulse reflected by a slowly moving surface) at nodes, quite different from the standard RPA process. Here, a theoretical model is derived to explain the underlying mechanism, and good agreements have been achieved with PIC simulations.« less
Phase locked multiple rings in the radiation pressure ion acceleration process
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wan, Y.; Hua, J. F.; Pai, C. -H.
Laser contrast plays a crucial role for obtaining high quality ion beams in the radiation pressure ion acceleration (RPA) process. Through one- and two-dimensional particle-in-cell (PIC) simulations, we show that a plasma with a bi-peak density profile can be produced from a thin foil on the effects of a picosecond prepulse, and it can then lead to distinctive modulations in the ion phase space (phase locked double rings) when the main pulse interacts with the target. These fascinating ion dynamics are mainly due to the trapping effect from the ponderomotive potential well of a formed moving standing wave (i.e. themore » interference between the incoming pulse and the pulse reflected by a slowly moving surface) at nodes, quite different from the standard RPA process. Here, a theoretical model is derived to explain the underlying mechanism, and good agreements have been achieved with PIC simulations.« less
Thermal ion heating in the vicinity of the plasmapause: A Dynamics Explorer guest investigation
NASA Technical Reports Server (NTRS)
Comfort, R. H.
1986-01-01
The ion thermal structure of the plasmasphere was investigated in a series of experiments. It appears that energy may be generally available to ion and electrons in the vinicity of the plasmapause from Coulomb interactions between ambient thermal plasma and low energy ring current and suprathermal ions, particularly O+. The amount of energy transferred depends on the densities and energies of each of the components. The spatial distribution of heating in turn depends critically on the spatial distribution of the different populations, especially on the density gradients. The spatial distribution of the thermal plasma is found to vary significantly on a diurnal time scale and is complicated by the plasmasphere erosion and refilling processes associated with magnetic activity and its aftermath. Thermal ion composition also appears to be influenced by the heating taking place, often increasing the heavy ion population in the vicinity of the plasmapause. The observations of equatorial heating near the plasmapause in the presence of equatorial noise also raise the likelihood of a wave source of energy. It is not unreasonable to expect that both particle and wave heat sources are significant, although not necessarily at the same times and places.
NASA Astrophysics Data System (ADS)
Gkioulidou, M.; Ukhorskiy, A. Y.; Mitchell, D. G.; Lanzerotti, L. J.
2015-12-01
The ring current energy budget plays a key role in the global electrodynamics of Earth's space environment. Pressure gradients developed in the inner magnetosphere can shield the near-Earth region from solar wind-induced electric fields. The distortion of Earth's magnetic field due to the ring current affects the dynamics of particles contributing both to the ring current and radiation belts. Therefore, understanding the long-term evolution of the inner magnetosphere energy content is essential. We have investigated the evolution of ring current proton pressure (7 - 600 keV) in the inner magnetosphere based on data from the Radiation Belt Storm Probes Ion Composition Experiment (RBSPICE) instrument aboard Van Allen Probe B throughout the year 2013. We find that although the low-energy component of the protons (< 80 keV) is governed by convective timescales and is very well correlated with the Dst index, the high-energy component (>100 keV) varies on much longer timescales and shows either no or anti-correlation with the Dst index. Interestingly, the contributions of the high- and low-energy protons to the total energy content are comparable. Our results indicate that the proton dynamics, and as a consequence the total energy budget in the inner magnetosphere (inside geosynchronous orbit), is not strictly controlled by storm-time timescales as those are defined by the Dst index.
Non-destructive ion trap mass spectrometer and method
Frankevich, Vladimir E.; Soni, Manish H.; Nappi, Mario; Santini, Robert E.; Amy, Jonathan W.; Cooks, Robert G.
1997-01-01
The invention relates to an ion trap mass spectrometer of the type having an ion trapping volume defined by spaced end caps and a ring electrode. The ion trap includes a small sensing electrode which senses characteristic motion of ions trapped in said trapping volume and provides an image current. Ions are excited into characteristic motion by application of an excitation pulse to the trapped ions. The invention also relates to a method of operating such an ion trap.
Super Star Clusters and H II Regions in Nuclear Rings
NASA Astrophysics Data System (ADS)
Filippenko, Alex
1996-07-01
We propose to obtain WFPC2 optical broad-band {F547M and F814W} and narrow-band Halpha+ionN2 {F658N} images of nuclear starburst rings in four nearby galaxies for which we already have ultraviolet {F220W} FOC data. Nuclear rings {or ``hot- spot'' regions} in barred spirals are some of the nearest and least obscured starburst regions, and HST images of nuclear rings in several galaxies show that the rings contain large populations of super star clusters similar to those recently discovered in other types of starburst systems. These compact clusters, many having luminosities exceeding that of the R136 cluster in 30 Doradus, represent a violent mode of star formation distinct from that seen in ordinary disk ionH2 regions, and the nuclear rings present us with an opportunity to study large numbers of these extreme clusters in relatively unobscured starburst environments. It has been suggested that super star clusters are present-day versions of young globular clusters. To evaluate this hypothesis, it is important to understand the physical properties and stellar contents of the clusters, but previous HST studies of nuclear ring galaxies have only used single-filter observations. Together with our UV data, new WFPC2 images will enable us to determine the H II region and cluster luminosity functions within nuclear rings, measure cluster radii, derive age and mass estimates for the clusters by comparison with evolutionary synthesis models, and study the structure and evolution of nuclear rings.
Performance Evaluation of the NEXT Ion Engine
NASA Technical Reports Server (NTRS)
Soulas, George C.; Domonkos, Matthew T.; Patterson, Michael J.
2003-01-01
The performance test results of three NEXT ion engines are presented. These ion engines exhibited peak specific impulse and thrust efficiency ranges of 4060 4090 s and 0.68 0.69, respectively, at the full power point of the NEXT throttle table. The performance of the ion engines satisfied all project requirements. Beam flatness parameters were significantly improved over the NSTAR ion engine, which is expected to improve accelerator grid service life. The results of engine inlet pressure and temperature measurements are also presented. Maximum main plenum, cathode, and neutralizer pressures were 12,000 Pa, 3110 Pa, and 8540 Pa, respectively, at the full power point of the NEXT throttle table. Main plenum and cathode inlet pressures required about 6 hours to increase to steady-state, while the neutralizer required only about 0.5 hour. Steady-state engine operating temperature ranges throughout the power throttling range examined were 179 303 C for the discharge chamber magnet rings and 132 213 C for the ion optics mounting ring.
Bifunctional phenyl monophosphonic/sulfonic acid ion exchange resin and process for using the same
Alexandratos, Spiro; Shelley, Christopher A.; Horwitz, E. Philip; Chiarizia, Renato
2001-01-01
A cross-linked water-insoluble ion exchange resin comprised of polymerized monomers having a phenyl ring is disclosed. A contemplated resin contains (i) polymerized phenyl ring-containing monomers having a phosphonic acid ligand linked to the phenyl ring, (ii) about 2 to about 5 millimoles per gram (mmol/g) of phosphorus as phosphonic acid ligands, and (iii) a sufficient amount of a sulfonic acid ligand such that the ratio of mmol/g of phosphonic acid to mmol/g sulfonic acid is up to 3:1. A process for removing polyvalent metal cations from aqueous solution, and a process for removing iron(III) cations from acidic copper(II) cation-containing solutions that utilize the contemplated resin or other resins are disclosed.
Bifunctional phenyl monophosphonic/sulfonic acid ion exchange resin and process for using the same
Alexandratos, Spiro; Shelley, Christopher A.; Horwitz, E. Philip; Chiarizia, Renato; Gula, Michael J.; Xue, Sui; Harvey, James T.
2002-01-01
A cross-linked water-insoluble ion exchange resin comprised of polymerized monomers having a phenyl ring is disclosed. A contemplated resin contains (i) polymerized phenyl ring-containing monomers having a phosphonic acid ligand linked to the phenyl ring, (ii) about 2 to about 5 millimoles per gram (mmol/g) of phosphorus as phosphonic acid ligands, and (iii) a sufficient amount of a sulfonic acid ligand such that the ratio of mmol/g of phosphonic acid to mmol/g sulfonic acid is up to 3:1. A process for removing polyvalent metal cations from aqueous solution, and a process for removing iron(III) cations from acidic copper(II) cation-containing solutions that utilize the contemplated resin or other resins are disclosed.
Grutter, Thomas; Prado de Carvalho, Lia; Virginie, Dufresne; Taly, Antoine; Fischer, Markus; Changeux, Jean-Pierre
2005-03-01
To understand the mechanism of allosteric coupling between the ligand-binding domain and the ion channel of the Cys-loop ligand-gated ion channels (LGICs), we fused the soluble acetylcholine-binding protein (AChBP), which lacks an ion channel, to either the cationic serotonin type-3A ion channel (5HT(3A)) or the anionic glycine ion channel. Both linear chimeras expressed in HEK-293 cells display high affinity for the nicotinic agonist epibatidine (K(D) = 0.2-0.5 nM), but are not targeted to the cell surface. Only after substituting a ring of three loops located at the putative membrane side of the AChBP three-dimensional structure by the homologous residues of 5HT(3A), the resulting chimera AChBP(ring)/5HT(3A) (i) still displayed on intact cells an apparent high affinity for epibatidine, yet with a fourfold decrease (K(D) = 2.1 nM), (ii) displayed a high proportion of low affinity sites (11 +/- 7 microM) for the resting state stabilizing competitive antagonist alpha-bungarotoxin and (iii) was successfully targeted to the cell surface, as seen by immunofluorescence labelling. The AChBP(ring)/5HT(3A) chimera forms a pentameric structure, as revealed by sucrose gradient sedimentation. However, no whole-cell patch-clamp currents were detectable. Interestingly, binding assays with membrane fragments prepared from cells expressing AChBP(ring)/5HT(3A) showed a decrease in the apparent affinity for the agonists nicotine and epibatidine (5-fold), concomitant with an increase in the proportion of high-affinity sites (48 +/- 1 nM) for alpha-bungarotoxin. These results indicate that fusion of AChBP to an ion channel forms a pentameric receptor exposed to the cell surface and able to convert between discrete allosteric states, but stabilized in a high affinity state for epibatidine that likely corresponds to a desensitized form of LGICs. These artificial chimeras might offer a useful system to investigate signal transduction in LGICs.
Electron detachment dissociation of fluorescently labeled sialylated oligosaccharides.
Zhou, Wen; Håkansson, Kristina
2011-12-01
We explored the application of electron detachment dissociation (EDD) and infrared multiphoton dissociation (IRMPD) tandem mass spectrometry to fluorescently labeled sialylated oligosaccharides. Standard sialylated oligosaccharides and a sialylated N-linked glycan released from human transferrin were investigated. EDD yielded extensive glycosidic cleavages and cross-ring cleavages in all cases studied, consistently providing complementary structural information compared with infrared multiphoton dissociation. Neutral losses and satellite ions such as C-2H ions were also observed following EDD. In addition, we examined the influence of different fluorescent labels. The acidic label 2-aminobenzoic acid (2-AA) enhanced signal abundance in negative-ion mode. However, few cross-ring fragments were observed for 2-AA-labeled oligosaccharides. The neutral label 2-aminobenzamide (2-AB) resulted in more cross-ring cleavages compared with 2-AA-labeled species, but not as extensive fragmentation as for native oligosaccharides, likely resulting from altered negative charge locations from introduction of the fluorescent tag. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Laser Ablation Electrodynamic Ion Funnel for In Situ Mass Spectrometry on Mars
NASA Technical Reports Server (NTRS)
Johnson, Paul V.; Hodyss, Robert P.; Tang, Keqi; Smith, Richard D.
2012-01-01
A front-end instrument, the laser ablation ion funnel, was developed, which would ionize rock and soil samples in the ambient Martian atmosphere, and efficiently transport the product ions into a mass spectrometer for in situ analysis. Laser ablation creates elemental ions from a solid with a high-power pulse within ambient Mars atmospheric conditions. Ions are captured and focused with an ion funnel into a mass spectrometer for analysis. The electrodynamic ion funnel consists of a series of axially concentric ring-shaped electrodes whose inside diameters (IDs) decrease over the length of the funnel. DC potentials are applied to each electrode, producing a smooth potential slope along the axial direction. Two radio-frequency (RF) AC potentials, equal in amplitude and 180 out of phase, are applied alternately to the ring electrodes. This creates an effective potential barrier along the inner surface of the electrode stack. Ions entering the funnel drift axially under the influence of the DC potential while being restricted radially by the effective potential barrier created by the applied RF. The net result is to effectively focus the ions as they traverse the length of the funnel.
Design of barrier bucket kicker control system
NASA Astrophysics Data System (ADS)
Ni, Fa-Fu; Wang, Yan-Yu; Yin, Jun; Zhou, De-Tai; Shen, Guo-Dong; Zheng, Yang-De.; Zhang, Jian-Chuan; Yin, Jia; Bai, Xiao; Ma, Xiao-Li
2018-05-01
The Heavy-Ion Research Facility in Lanzhou (HIRFL) contains two synchrotrons: the main cooler storage ring (CSRm) and the experimental cooler storage ring (CSRe). Beams are extracted from CSRm, and injected into CSRe. To apply the Barrier Bucket (BB) method on the CSRe beam accumulation, a new BB technology based kicker control system was designed and implemented. The controller of the system is implemented using an Advanced Reduced Instruction Set Computer (RISC) Machine (ARM) chip and a field-programmable gate array (FPGA) chip. Within the architecture, ARM is responsible for data presetting and floating number arithmetic processing. The FPGA computes the RF phase point of the two rings and offers more accurate control of the time delay. An online preliminary experiment on HIRFL was also designed to verify the functionalities of the control system. The result shows that the reference trigger point of two different sinusoidal RF signals for an arbitrary phase point was acquired with a matched phase error below 1° (approximately 2.1 ns), and the step delay time better than 2 ns were realized.
Ring-breaking electron attachment to uracil: following bond dissociations via evolving resonances.
Gianturco, Franco A; Sebastianelli, F; Lucchese, R R; Baccarelli, I; Sanna, N
2008-05-07
Calculations are carried out at various distinct energies to obtain both elastic cross sections and S-matrix resonance indicators (poles) from a quantum treatment of the electron scattering from gas-phase uracil. The low-energy region confirms the presence of pi(*) resonances as revealed by earlier calculations and experiments which are compared with the present findings. They turn out to be little affected by bond deformation, while the transient negative ions (TNIs) associated with sigma(*) resonances in the higher energy region ( approximately 8 eV) indeed show that ring deformations which allow vibrational redistribution of the excess electron energy into the molecular target strongly affect these shape resonances: They therefore evolve along different dissociative pathways and stabilize different fragment anions. The calculations further show that the occurrence of conical intersections between sigma(*) and pi(*)-type potential energy surfaces (real parts) is a very likely mechanism responsible for energy transfers between different TNIs. The excess electron wavefunctions for such scattering states, once mapped over the molecular space, provide nanoscopic reasons for the selective breaking of different bonds in the ring region.
Simulation and 'TWINS Observations of the 22 July 2009 Storm
NASA Technical Reports Server (NTRS)
Fok, Mei-Ching; Buzulukova, Natalia Y.; Chen, Sheng-Hsien; Valek, Phil; Goldstein, Jerry; McComas, David
2010-01-01
TWINS is the first mission to perform stereo imaging of the Earth's ring current. The magnetic storm on 22 July 2009 is the largest storm observed since TWINS began routine stereo imaging in June 2008. On 22 July 2009, the Dst dropped to nearly -80nT at 7:00 and 10:00 UT. During the main phase and at the peak of the storm, TWINS 1 and 2 were near apogee and moving from pre-dawn to post-dawn local time. The energetic neutral atom (ENA) imagers on the 2 spacecraft captured the storm intensification and the formation of the partial ring current. The peak of the ENA emissions was seen in the midnight-to-dawn local-time sector. The development of this storm has been simulated using the Comprehensive Ring Current Model (CRCM) to understand and interpret the observed signatures. We perform CRCM runs with constant and time-varying magnetic field. The model calculations are validated by comparing the simulated ENA and ion flux intensities with TWINS ENA images and in-situ ion data from THEMIS satellites. Simulation with static magnetic field produces a strong shielding electric field that skews the ion drift trajectories toward dawn. The model's corresponding peak ENA emissions are always eastward than those in the observed TWINS images. On the other hand, simulation with a dynamic magnetic field gives better spatial agreements with both ENA and insitu particle data, suggesting that temporal variations of the geomagnetic field exert a significant influence upon global ring current ion dynamics.
Enhancement of negative hydrogen ion production in an electron cyclotron resonance source
NASA Astrophysics Data System (ADS)
Dugar-Zhabon, V. D.; Murillo, M. T.; Karyaka, V. I.
2013-07-01
In this paper, we present a method for improving the negative hydrogen ion yield in the electron cyclotron resonance source with driven plasma rings where the negative ion production is realized in two stages. First, the hydrogen and deuterium molecules are excited in collisions with plasma electrons to high-laying Rydberg and high vibration levels in the plasma volume. The second stage leads to negative ion production through the process of repulsive attachment of low-energy electrons by the excited molecules. The low-energy electrons originate due to a bombardment of the plasma electrode surface by ions of a driven ring and the thermoelectrons produced by a rare earth ceramic electrode, which is appropriately installed in the source chamber. The experimental and calculation data on the negative hydrogen ion generation rate demonstrate that very low-energy thermoelectrons significantly enhance the negative-ion generation rate that occurs in the layer adjacent to the plasma electrode surface. It is found that heating of the tungsten filaments placed in the source chamber improves the discharge stability and extends the pressure operation range.
Xenon ion propulsion for orbit transfer
NASA Technical Reports Server (NTRS)
Rawlin, V. K.; Patterson, M. J.; Gruber, R. P.
1990-01-01
For more than 30 years, NASA has conducted an ion propulsion program which has resulted in several experimental space flight demonstrations and the development of many supporting technologies. Technologies appropriate for geosynchronous stationkeeping, earth-orbit transfer missions, and interplanetary missions are defined and evaluated. The status of critical ion propulsion system elements is reviewed. Electron bombardment ion thrusters for primary propulsion have evolved to operate on xenon in the 5 to 10 kW power range. Thruster efficiencies of 0.7 and specific impulse values of 4000 s were documented. The baseline thruster currently under development by NASA LeRC includes ring-cusp magnetic field plasma containment and dished two-grid ion optics. Based on past experience and demonstrated simplifications, power processors for these thrusters should have approximately 500 parts, a mass of 40 kg, and an efficiency near 0.94. Thrust vector control, via individual thruster gimbals, is a mature technology. High pressure, gaseous xenon propellant storage and control schemes, using flight qualified hardware, result in propellant tankage fractions between 0.1 and 0.2. In-space and ground integration testing has demonstrated that ion propulsion systems can be successfully integrated with their host spacecraft. Ion propulsion system technologies are mature and can significantly enhance and/or enable a variety of missions in the nation's space propulsion program.
9-D polarized proton transport in the MEIC figure 8 collider ring - first steps
DOE Office of Scientific and Technical Information (OSTI.GOV)
Meot, F.; Morozov, V. S.
2015-05-03
Spin tracking studies in the MEIC figure-8 collider ion ring are presented, based on a very preliminary design of the lattice. They provide numerical illustrations of some of the aspects of the figure-8 concept, including spin-rotator based spin control, and lay out the path towards a complete spin tracking simulation of a figure-8 ring.
9-D polarized proton transport in the MEIC figure-8 collider ring: first steps
DOE Office of Scientific and Technical Information (OSTI.GOV)
Meot, F.; Thomas Jefferson National Accelerator Facility; Morozov, V. S.
2014-10-24
Spin tracking studies in the MEIC figure-8 collider ion ring are presented, based on a very preliminary design of the lattice. They provide numerical illustrations of some of the aspects of the figure-8 concept, including spin-rotator based spin control, and lay out the path towards a complete spin tracking simulation of a figure-8 ring.
Overtone spectroscopy of N2H+ molecular ions—application of cavity ring-down spectroscopy
NASA Astrophysics Data System (ADS)
Kálosi, Á.; Dohnal, P.; Shapko, D.; Roučka, Š.; Plašil, R.; Johnsen, R.; Glosík, J.
2017-10-01
A stationary afterglow apparatus in conjunction with a laser absorption cavity ring-down spectrometer has been employed to observe absorption lines in the P- and R-branches of the (200) <-- (000) and (2110) <-- (0110) vibrational bands of the N2H+ molecular ion as a part of an ongoing study of the electron-ion recombination of N2H+ in afterglow plasmas. The probed absorption lines lie in the near-infrared spectral region around 1580 nm. The observed transition wavenumbers were fitted to experimental accuracy and improved molecular constants for the (200) vibrational state were obtained. The employed experimental technique enables probing of the translational, rotational and vibrational temperature of the studied ions as well as the determination of the number densities of different quantum states of the ion in discharge and afterglow plasma.
NASA Technical Reports Server (NTRS)
Roth, J. R.
1976-01-01
Parametric variation of independent variables which may affect the characteristics of bumpy torus plasma have identified those which have a significant effect on the plasma current, ion kinetic temperature, and plasma number density, and those which do not. Empirical power law correlations of the plasma current, and the ion kinetic temperature and number density were obtained as functions of potential applied to the midplane electrode rings, the background neutral gas pressure, and the magnetic field strength. Additional parameters studied included the type of gas, the polarity of the midplane electrode rings, the mode of plasma operation, and the method of measuring the plasma number density. No significant departures from the scaling laws appear to occur at the highest ion kinetic temperatures or number densities obtained to date.
NASA Astrophysics Data System (ADS)
Qiang, Liming; Cao, Shuxia; Zhao, Xiaoyang; Mao, Xiangju; Guo, Yanchun; Liao, Xincheng; Zhao, Yufen
2007-10-01
The fragmentation patterns of N-diisopropyloxyphosphoryl-l-[alpha]-Ala (DIPP-l-[alpha]-Ala), N-diisopropyloxyphosphoryl-d-[alpha]-Ala (DIPP-d-[alpha]-Ala), N-diisopropyloxyphosphoryl-[beta]-Ala (DIPP-[beta]-Ala) and N-diisopropyloxyphosphoryl-[gamma]-amino butyric acid (DIPP-[gamma]-Aba) were investigated by electrospray ionization tandem mass spectrometry (ESI-MS/MS). DIPP-d-[alpha]-Ala showed the same fragmentation pathways as DIPP-l-[alpha]-Ala. In the fragmentation of protonated DIPP-[beta]-Ala, the characteristic fragment ion [M + H - 2C3H6 - H2O - CH2CO]+ appeared and could be used to distinguish [beta]-Ala from l-[alpha]-Ala and d-[alpha]-Ala through tandem mass spectra, even though they possess the same molecular weight. In the fragmentation of protonated DIPP-[gamma]-Aba, the break of PN bond occurred and an interesting protonated lactam ion with five-membered ring was generated. Furthermore, in the MS3 spectrum of [M + Na - 2C3H6]+ ion of DIPP-[gamma]-Aba, a strong intensity of unique fragment ion, namely lactam-sodium adduct with five-membered ring, was observed, which could be considered as a mark for [gamma]-amino acids. The stepwise fragmentations of their [M + Na]+ ions and [M - H]- ions showed that they all underwent a PN to PO bond migration through a five-membered or six-membered or even seven-membered ring transition state, respectively, which supported the great affinity of hydroxyl for phosphoryl group.
Non-invasive diagnostics of ion beams in strong toroidal magnetic fields with standard CMOS cameras
NASA Astrophysics Data System (ADS)
Ates, Adem; Ates, Yakup; Niebuhr, Heiko; Ratzinger, Ulrich
2018-01-01
A superconducting Figure-8 stellarator type magnetostatic Storage Ring (F8SR) is under investigation at the Institute for Applied Physics (IAP) at Goethe University Frankfurt. Besides numerical simulations on an optimized design for beam transport and injection a scaled down (0.6T) experiment with two 30°toroidal magnets is set up for further investigations. A great challenge is the development of a non-destructive, magnetically insensitive and flexible detector for local investigations of an ion beam propagating through the toroidal magnetostatic field. This paper introduces a new way of beam path measurement by residual gas monitoring. It uses a single board camera connected to a standard single board computer by a camera serial interface all placed inside the vacuum chamber. First experiments with one camera were done and in a next step two under 90 degree arranged cameras were installed. With the help of the two cameras which are moveable along the beam pipe the theoretical predictions are experimentally verified successfully. Previous experimental results have been confirmed. The transport of H+ and H2+ ion beams with energies of 7 keV and at beam currents of about 1 mA is investigated successfully.
Adolescent Experiences with the Vaginal Ring
Epstein, Laura B.; Sokal-Gutierrez, Karen; Ivey, Susan L.; Raine, Tina; Auerswald, Colette
2011-01-01
Purpose To understand racial/ethnic minority adolescent females’ experiences with the vaginal ring. Methods We conducted in-depth interviews with a clinic-based sample of 32 young women aged 15–24 years who had used the vaginal ring. Results Qualitative analysis using grounded theory revealed that adolescents undergo a multi-stage process when trying the ring and adopting ring use. These stages include hearing about the ring, initial reactions, first experiences with insertion and removal, and first sexual experiences. Adolescents subsequently enter an assessment and adjustment stage in which they decide whether to adopt or discontinue ring use. Ultimately they share their experiences with friends. Conclusions The model developed provides a context within which providers may advise adolescents as they begin use of the ring. Some specific recommendations are offered. PMID:18565439
Li, Xiaopeng; Chan, Yi-Tsu; Casiano-Maldonado, Madalis; Yu, Jing; Carri, Gustavo A; Newkome, George R; Wesdemiotis, Chrys
2011-09-01
The self-assembly of Zn(II) ions and bis(terpyridine) (tpy) ligands carrying 120° or 180° angles between their metal binding sites was utilized to prepare metallosupramolecular libraries with the
NASA Astrophysics Data System (ADS)
Mishin, E. V.; Burke, W. J.
2005-07-01
We compare plasma and field disturbances observed in the ring current/plasmasphere overlap region and in the conjugate ionosphere during the magnetic storm of 5 June 1991. Data come from the Combined Release and Radiation Effects Satellite (CRRES) flying in a geostationary transfer orbit and three satellites of the Defense Meteorological Satellite Program (DMSP) series in Sun-synchronous polar orbits. In the region between ring current nose structures and the electron plasma sheet, CRRES detected wave-like features in local electric and magnetic fields, embedded in structured cold plasmas. Mapped to the ionosphere, these fields should reflect structuring within subauroral plasma streams (SAPS). Indeed, during the period of interest, DMSP F8, F9, and F10 satellites observed highly structured SAPS in the evening ionosphere at topside altitudes. They were collocated with precipitating ring current ions, enhanced fluxes of suprathermal electrons and ions, elevated electron temperatures, and irregular plasma density troughs. Overall, these events are similar to electromagnetic structures observed by DMSP satellites within SAPS during recent geomagnetic storms (Mishin et al., 2003, 2004). Their features can be explained in terms of Alfvén and fast magnetosonic perturbations. We developed a scenario for the formation of elevated electron temperatures at the equatorward side of the SAPS. It includes a lower-hybrid drift instability driven by diamagnetic currents, consistent with strong lower- and upper-hybrid plasma wave activity and intense fluxes of the low-energy electrons and ions near the ring current's inner edge.
NASA Technical Reports Server (NTRS)
Khazanov, G. V.; Gamayunov, K. V.; Gallagher, D. L.; Kozyra, J. U.
2006-01-01
The further development of a self-consistent theoretical model of interacting ring current ions and electromagnetic ion cyclotron waves (Khazanov et al., 2003) is presented In order to adequately take into account wave propagation and refraction in a multi-ion magnetosphere, we explicitly include the ray tracing equations in our previous self-consistent model and use the general form of the wave kinetic equation. This is a major new feature of the present model and, to the best of our knowledge, the ray tracing equations for the first time are explicitly employed on a global magnetospheric scale in order to self-consistently simulate the spatial, temporal, and spectral evolution of the ring current and of electromagnetic ion cyclotron waves To demonstrate the effects of EMIC wave propagation and refraction on the wave energy distribution and evolution, we simulate the May 1998 storm. The main findings of our simulation can be summarized as follows. First, owing to the density gradient at the plasmapause, the net wave refraction is suppressed, and He+-mode grows preferably at the plasmapause. This result is in total agreement with previous ray tracing studies and is very clearly found in presented B field spectrograms. Second, comparison of global wave distributions with the results from another ring current model (Kozyra et al., 1997) reveals that this new model provides more intense and more highly plasmapause-organized wave distributions during the May 1998 storm period Finally, it is found that He(+)-mode energy distributions are not Gaussian distributions and most important that wave energy can occupy not only the region of generation, i.e., the region of small wave normal angles, but all wave normal angles, including those to near 90 . The latter is extremely crucial for energy transfer to thermal plasmaspheric electrons by resonant Landau damping and subsequent downward heat transport and excitation of stable auroral red arcs.
NASA Technical Reports Server (NTRS)
Khazanov, G. V.; Gumayunov, K. V.; Gallagher, D. L.; Kozyra, J. U.
2006-01-01
The further development of a self-consistent theoretical model of interacting ring current ions and electromagnetic ion cyclotron waves [Khazanov et al., 2003] is presented. In order to adequately take into account the wave propagation and refraction in a multi-ion plasmasphere, we explicitly include the ray tracing equations in our previous self-consistent model and use the general form of the wave kinetic equation. This is a major new feature of the present model and, to the best of our knowledge, the ray tracing equations for the first time are explicitly employed on a global magnetospheric scale in order to self-consistently simulate spatial, temporal, and spectral evolutions of the ring current and electromagnetic ion cyclotron waves. To demonstrate the effects of EMIC wave propagation and refraction on the EMIC wave energy distributions and evolution we simulate the May 1998 storm. The main findings of our simulation can be summarized as follows. First, due to the density gradient at the plasmapause, the net wave refraction is suppressed, and He(+)-mode grows preferably at plasmapause. This result is in a total agreement with the previous ray tracing studies, and very clear observed in presented B-field spectrograms. Second, comparison the global wave distributions with the results from other ring current model [Kozyra et al., 1997] reveals that our model provides more intense and higher plasmapause organized distributions during the May, 1998 storm period. Finally, the found He(+)-mode energy distributions are not Gaussian distributions, and most important that wave energy can occupy not only the region of generation, i. e. the region of small wave normal angles, but the entire wave normal angle region and even only the region near 90 degrees. The latter is extremely crucial for energy transfer to thermal plasmaspheric electrons by resonant Landau damping, and subsequent downward heat transport and excitation of stable auroral red arcs.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Shukla, Anil; Bogdanov, Bogdan
2015-02-14
Small cationic and anionic clusters of lithium formate were generated by electrospray ionization and their fragmentations were studied by tandem mass spectrometry. Singly as well as multiply charged clusters were formed with the general formulae, (HCOOLi)nLi+, (HCOOLi)nLimm+, (HCOOLi)nHCOO- and (HCOOLi)n(HCOO)mm-. Several magic number cluster ions were observed in both the positive and negative ion modes although more predominant in the positive ion mode with (HCOOLi)3Li+ being the most abundant and stable cluster ions. Fragmentations of singly charged clusters proceed first by the loss of a dimer unit ((HCOOLi)2) followed by sequential loss of monomer units (HCOOLi). In the case ofmore » positive cluster ions, all fragmentations lead to the magic cluster (HCOOLi)3Li+ at higher collision energies which later fragments to dimer and monomer ions in lower abundance. Quantum mechanical calculations performed for smaller cluster ions showed that the trimer ion has a closed ring structure similar to the phenalenylium structure with three closed rings connected to the lithium ion. Further additions of monomer units result in similar symmetric structures for hexamer and nonamer cluster ions. Thermochemical calculations show that trimer cluster ion is relatively more stable than neighboring cluster ions, supporting the experimental observation of a magic number cluster with enhanced stability.« less
Plasmasphere-Ring Current-Radiation Belts Interactions: Review of 16 Years of Cluster Observations
NASA Astrophysics Data System (ADS)
Dandouras, I. S.
2016-12-01
The Cluster mission is based on four identical spacecraft launched in 2000 on similar elliptical polar orbits with an initial perigee at about 4 RE and an apogee at 19.6 RE. This allows Cluster to cross the outer plasmasphere, the ring current region and the radiation belts, from south to north, during every perigee pass and to obtain their latitudinal profile following almost the same flux tube. Due to various perturbations the perigee geocentric distance decreased during 2007-2010 to about 2 RE, whereas actually it is again up to about 5 RE, allowing in this way to study, during the mission, the inner magnetosphere populations and their interactions at a wide range of L-shells and under different solar activity conditions. The CIS experiment, on board these spacecraft, provides the ion distribution functions from 1 eV (plasmasphere populations) up to 40 keV (ring current), whereas the MeV penetrating particles allow to monitor the position and dynamics of the radiation belts. The FGM experiment on board these four spacecraft allowed for the first time an instantaneous calculation of the magnetic field gradients and thus a direct measurement of the local current density using the curlometer technique. Earlier and more recent results, based on Cluster data acquired during the passes in inner magnetosphere, will be reviewed and analysed.
Ion source based on the cathodic arc
Sanders, David M.; Falabella, Steven
1994-01-01
A cylindrically symmetric arc source to produce a ring of ions which leave the surface of the arc target radially and are reflected by electrostatic fields present in the source to a point of use, such as a part to be coated. An array of electrically isolated rings positioned in the source serves the dual purpose of minimizing bouncing of macroparticles and providing electrical insulation to maximize the electric field gradients within the source. The source also includes a series of baffles which function as a filtering or trapping mechanism for any macroparticles.
Resonant neutral-particle emission in collisions of electrons with peptide ions in a storage ring.
Tanabe, T; Noda, K; Saito, M; Lee, S; Ito, Y; Takagi, H
2003-05-16
Electron-biomolecular ion collisions were studied using an electrostatic storage ring with a merging beam technique for singly protonated peptides (angiotensin I, II, and III). A strong neutral-particle emission at around 6.5 eV was found in addition to neutrals from recombination at low energies. The rates of the high-energy peak greatly decreased with a slight decrease in the number of amino-acid residues from angiotensin I to III. These results suggest that some peptide bonds were selectively cleaved.
NASA Technical Reports Server (NTRS)
Roth, J. R.; Gerdin, G. A.
1976-01-01
The toroidal ring of plasma contained in the NASA Lewis bumpy-torus superconducting magnet facility may be biased to positive or negative potentials approaching 50 kilovolts by applying direct-current voltages of the respective polarity to 12 or fewer of the midplane electrode rings. The electric fields which are responsible for heating the ions by E/B drift then point radially outward or inward. The low-frequency fluctuations below the ion cyclotron frequency appeared to be dominated by rotating spokes.
NASA Technical Reports Server (NTRS)
Doerbeck, F. H.; Yuan, H. T.; Mclevige, W. V.
1981-01-01
Ion implantation techniques that permit the reproducible fabrication of bipolar GaAs integrated circuits are studied. A 15 stage ring oscillator and discrete transistor were characterized between 25 and 400 C. The current gain of the transistor was found to increase slightly with temperature. The diode leakage currents increase with an activation energy of approximately 1 eV and dominate the transistor leakage current 1 sub CEO above 200 C. Present devices fail catastrophically at about 400 C because of Au-metallization.
Simulation studies for the PANDA experiment
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kopf, B.
2005-10-26
One main component of the planned Facility for Antiproton and Ion Research (FAIR) is the High Energy Storage Ring (HESR) at GSI, Darmstadt, which will provide cooled antiprotons with momenta between 1.5 and 15 GeV/c. The PANDA experiment will investigate p-barannihilations with internal hydrogen and nuclear targets. Due to the planned extensive physics program a multipurpose detector with nearly complete solid angle coverage, proper particle identification over a large momentum range, and high resolution calorimetry for neutral particles is required. For the optimization of the detector design simulation studies of several benchmark channels are in progress which are covering themore » most relevant physics topics. Some important simulation results are discussed here.« less
Design and R&D of RICH detectors for EIC experiments
NASA Astrophysics Data System (ADS)
Del Dotto, A.; Wong, C.-P.; Allison, L.; Awadi, M.; Azmoun, B.; Barbosa, F.; Brooks, W.; Cao, T.; Chiu, M.; Cisbani, E.; Contalbrigo, M.; Datta, A.; Demarteau, M.; Durham, J. M.; Dzhygadlo, R.; Fields, D.; Furletova, Y.; Gleason, C.; Grosse-Perdekamp, M.; Harris, J.; He, X.; van Hecke, H.; Horn, T.; Huang, J.; Hyde, C.; Ilieva, Y.; Kalicy, G.; Kimball, M.; Kistenev, E.; Kulinich, Y.; Liu, M.; Majka, R.; McKisson, J.; Mendez, R.; Nadel-Turonski, P.; Park, K.; Peters, K.; Rao, T.; Pisani, R.; Qiang, Y.; Rescia, S.; Rossi, P.; Sarsour, M.; Schwarz, C.; Schwiening, J.; da Silva, C. L.; Smirnov, N.; Stein, H.; Stevens, J.; Sukhanov, A.; Syed, S.; Tate, A.; Toh, J.; Towell, C.; Towell, R.; Tsang, T.; Wagner, R.; Wang, J.; Woody, C.; Xi, W.; Xie, J.; Zhao, Z. W.; Zihlmann, B.; Zorn, C.
2017-12-01
An Electron-Ion Collider (EIC) has been proposed to further explore the strong force and QCD, focusing on the structure and the interaction of gluon-dominated matter. A generic detector R&D program (EIC PID consortium) for the particle identification in EIC experiments was formed to explore technologically advanced solutions in this scope. In this context two Ring Imaging Cherenkov (RICH) counters have been proposed: a modular RICH detector which consists of an aerogel radiator, a Fresnel lens, a mirrored box, and pixelated photon sensor; a dual-radiator RICH, consisting of an aerogel radiator and C2F6 gas in a mirror-focused configuration. We present the simulations of the two detectors and their estimated performance.
Sources and Losses of Ring Current Ions
NASA Technical Reports Server (NTRS)
Chen, Sheng-Hsien; Fok, Mei-Ching H.; Angeloupoulos, Vassilis
2010-01-01
During geomagnetic quiet times, in-situ measurements of ring current energetic ions (few to few tens of keVs) from THEMIS spacecraft often exhibit multiple ion populations at discrete energies that extend from the inner magnetosphere to the magnetopause at dayside or plasma sheet at nightside. During geomagnetic storm times, the levels of fluxes as well as the mean energies of these ions elevated dramatically and the more smooth distributions in energies and distances during quiet times are disrupted into clusters of ion populations with more confined spatial extends. This reveals local plasma heating processes that might have come into play. Several processes have been proposed. Magnetotail dipolarization, sudden enhancement of field-aligned current, local current disruptions, and plasma waves are possible mechanisms to heat the ions locally as well as strong convections of energetic ions directly from the magnetotail due to reconnections. We will examine two geomagnetic storms on October 11, 2008 and July 22, 2009 to reveal possible heating mechanisms. We will analyze in-situ plasma and magnetic field measurements from THEMIS, GOES, and DMSP for the events to study the ion pitch angle distributions and magnetic field perturbations in the auroral ionosphere and inner magnetosphere where the plasma heating processes occur.
Heating and scattering of ring-beam distributions by turbulence
NASA Technical Reports Server (NTRS)
Gray, P. C.; Pontius, D. H., Jr.; Matthaeus, W. H.
1995-01-01
Pickup ions in the solar wind are initially are born in ring-beam distributions, i.e. f(v) varies as delta(v(sub perpendicular) - V(sub sw)sin(Theta)) delta(v(sub parallel) - V(sub sw)cos(Theta)), where Theta is the angle between the solar wind velocity and the IMF(Interplanetary Magnetic Field), and V(sub sw) is the solar wind speed. Often the distribution has been presumed to relax to a distribution that is isotropic in Theta and essentially mono-energetic, a shell or a 'bi-spherical distribution.' However solar wind turbulence is capable of heating the ring distribution on the timescale of a few tens of gyroperiods, a timescale not greatly distinct from that required for pitch angle scattering to a shell. To describe this effect, we have performed test-particle studies of the heating/scattering of the ring beam distribution by MHD turbulence, adopting various models for the MHD fluctuations, including slab and fully dynamic 2D and 3D incompressible turbulence. Furthermore, a system composed of a cold ion ring and a background plasma is unstable to several kinetic plasma instabilities. We carried out kinetic simulations of the ring beam distribution, showing that plasma instabilities also rapidly energize and scatter particles. Results will be presented comparing relaxation and heating rates of the ring-beam distribution by the various mechanisms.
Ion- and dust-acoustic instabilities in dusty plasmas
NASA Technical Reports Server (NTRS)
Rosenberg, M.
1993-01-01
Dust ion-acoustic and dust-acoustic instabilities in dusty plasmas are investigated using a standard Vlasov approach. Possible applications of these instabilities to various cosmic environments, including protostellar clouds and planetary rings, are briefly discussed.
Ion beam generated modes in the lower hybrid frequency range in a laboratory magnetoplasma
NASA Astrophysics Data System (ADS)
Van Compernolle, B.; Tripathi, S.; Gekelman, W. N.; Colestock, P. L.; Pribyl, P.
2012-12-01
The generation of waves by ion ring distributions is of great importance in many instances in space plasmas. They occur naturally in the magnetosphere through the interaction with substorms, or they can be man-made in ionospheric experiments by photo-ionization of neutral atoms injected perpendicular to the earth's magnetic field. The interaction of a fast ion beam with a low β plasma has been studied in the laboratory. Experiments were performed at the LArge Plasma Device (LAPD) at UCLA. The experiments were done in a Helium plasma (n ≃ 1012 \\ cm-3, B0 = 1000 G - 1800 G, fpe}/f{ce ≃ 1 - 5, Te = 0.25\\ eV, vte ≤ vA). The ion beam \\cite{Tripathi_ionbeam} is a Helium beam with energies ranging from 5 keV to 18 keV. The fast ion velocity is on the order of the Alfvén velocity. The beam is injected from the end of the machine, and spirals down the linear device. Waves were observed below fci in the shear Alfvén wave regime, and in a broad spectrum above fci in the lower hybrid frequency range, the focus of this paper. The wave spectra have distinct peaks close to ion cyclotron harmonics, extending out to the 100th harmonic in some cases. The wave generation was studied for various magnetic fields and background plasma densities, as well as for different beam energies and pitch angles. The waves were measured with 3-axis electric and magnetic probes. Detailed measurements of the perpendicular mode structure will be shown. Langmuir probes were used to measure density and temperature evolution due to the beam-plasma interaction. Retarding field energy analyzers captured the ion beam profiles. The work was performed at the LArge Plasma Device at the Basic Plasma Science Facility (BaPSF) at UCLA, funded by DOE/NSF.
MTF measurement and analysis of linear array HgCdTe infrared detectors
NASA Astrophysics Data System (ADS)
Zhang, Tong; Lin, Chun; Chen, Honglei; Sun, Changhong; Lin, Jiamu; Wang, Xi
2018-01-01
The slanted-edge technique is the main method for measurement detectors MTF, however this method is commonly used on planar array detectors. In this paper the authors present a modified slanted-edge method to measure the MTF of linear array HgCdTe detectors. Crosstalk is one of the major factors that degrade the MTF value of such an infrared detector. This paper presents an ion implantation guard-ring structure which was designed to effectively absorb photo-carriers that may laterally defuse between adjacent pixels thereby suppressing crosstalk. Measurement and analysis of the MTF of the linear array detectors with and without a guard-ring were carried out. The experimental results indicated that the ion implantation guard-ring structure effectively suppresses crosstalk and increases MTF value.
Single mask, simple structure micro rotational motor driven by electrostatic comb-drive actuators
NASA Astrophysics Data System (ADS)
Pham, Phuc Hong; Viet Dao, Dzung; Dang, Lam Bao; Sugiyama, Susumu
2012-01-01
We report a design and fabrication of a new micro rotational motor (MRM) using silicon micromachining technology with the overall diameter of 2.4 mm. This motor utilizes four silicon electrostatic comb-drive actuators to drive the outer ring (or rotor) through ratchet teeth. The novel design of the anti-reverse structure helps us to overcome the gap problem after deep reactive ion etching of silicon. The MRM was fabricated by using silicon on insulator wafer with the thickness of the device layer being 30 µm and one mask only. The motor was successfully tested for performance. It was driven by periodic voltage with different frequencies ranging from 1 to 50 Hz. The angular velocity of the outer ratchet ring was proportional to the frequency. Moreover, when the driving frequency is lower than 30 Hz, the experiment results perfectly match the theoretical calculation.
BEAM DYNAMICS ANALYSIS FOR THE ULTRA-FAST KICKER IN CIRCULAR COOLER RING OF JLEIC
DOE Office of Scientific and Technical Information (OSTI.GOV)
Huang, Yulu; Wang, Haipeng; Rimmer, Robert A.
An ultra-fast kicker system consisting of four quarter wavelength resonator based deflecting cavities was developed that simultaneously resonates at 10 subharmonic modes of the 476.3MHz bunch repetition frequency. Thus every 10th bunch in the bunch train will experience a transverse kick while all the other bunches are undisturbed. This fast kicker is being developed for the Energy Recovery Linac (ERL) based electron Circular Cooler Ring (CCR) in the proposed Jefferson Lab Electron Ion Collider (JLEIC, previously MEIC). The electron bunches can be reused 10-30 turns thus the beam current in the ERL can be reduced to 1/10 - 1/30 (150mAmore » - 50mA) of the cooling bunch current (1.5A). In this paper, several methods to synthesize such a kicker waveform and the comparison made by the beam dynamics tracking in Elegant will be discussed.« less
Ion mobility studies of PdC{sub n}{sup +} clusters: Where are the fullerenes?
DOE Office of Scientific and Technical Information (OSTI.GOV)
Shelimov, K.B.; Jarrold, M.F.
1995-12-14
Gas-phase ion mobility measurements have been used to study the structures and isomerization of PdC{sub n}{sup +} (n = 10-60) clusters. Non-fullerene isomers of PdC{sub n}{sup +} clusters are similar to those of C{sub n}{sup +} and MC{sub n}{sup +} (M = La and Nb) clusters, and include metal-containing mono- and bicyclic rings and graphite sheets. Neither endohedral nor nonendohedral PdC{sub n} {sup +} fullerene isomers are detected. When collisionally heated, PdC{sub n}{sup +} clusters efficiently convert into fullerenes, but the exothermicity of this process results in the loss of the Pd atom and the formation of a pure carbonmore » cluster cation. PdC{sub n}{sup +} bicyclic rings with an odd number of carbon atoms efficiently isomerize into monocyclic rings, while no evidence is found for this isomerization process for bicyclic rings with an even number of carbon atoms. 18 refs., 4 figs.« less
Cyclohexane Rings Reduce Membrane Permeability to Small Ions in Archaea-Inspired Tetraether Lipids.
Koyanagi, Takaoki; Leriche, Geoffray; Onofrei, David; Holland, Gregory P; Mayer, Michael; Yang, Jerry
2016-01-26
Extremophile archaeal organisms overcome problems of membrane permeability by producing lipids with structural elements that putatively improve membrane integrity compared to lipids from other life forms. Herein, we describe a series of lipids that mimic some key structural features of archaeal lipids, such as: 1) single tethering of lipid tails to create fully transmembrane tetraether lipids and 2) the incorporation of small rings into these tethered segments. We found that membranes formed from pure tetraether lipids leaked small ions at a rate that was about two orders of magnitude slower than common bilayer-forming lipids. Incorporation of cyclopentane rings into the tetraether lipids did not affect membrane leakage, whereas a cyclohexane ring reduced leakage by an additional 40 %. These results show that mimicking certain structural features of natural archaeal lipids results in improved membrane integrity, which may help overcome limitations of many current lipid-based technologies. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Astrochemistry at the Cryogenic Storage Ring
NASA Astrophysics Data System (ADS)
Kreckel, Holger; Becker, Arno; Blaum, Klaus; Breitenfeldt, Christian; George, Sebastian; Göck, Jürgen; Grieser, Manfred; Grussie, Florian; Guerin, Elisabeth; Heber, Oded; Karthein, Jonas; Krantz, Claude; Meyer, Christian; Mishra, Preeti; Novotny, Oldrich; O'Connor, Aodh; Saurabh, Sunny; Schippers, Stefan; Spruck, Kaija; Kumar, S. Sunil; Urbain, Xavier; Vogel, Stephen; von Hahn, Robert; Wilhelm, Patrick; Wolf, Andreas; Zajfman, Daniel
2017-01-01
Almost 200 different molecular species have been identified in space, and this number continues to grow steadily. This surprising molecular diversity bears witness to an active reaction network, in which molecular ions are the main drivers of chemistry in the gas phase. To study these reactions under controlled conditions in the laboratory is a major experimental challenge. The new Cryogenic Storage Ring (CSR) that has recently been commissioned at the Max Planck Institute for Nuclear Physics in Heidelberg will serve as an ideal testbed to study cold molecular ions in the gas phase. With residual gas densities of <140 cm-3 and temperatures below 10K, the CSR will allow for merged beams collision studies involving molecular ions, neutral atoms, free electrons and photons under true interstellar conditions.
Design of a cavity ring-down spectroscopy diagnostic for negative ion rf source SPIDER
DOE Office of Scientific and Technical Information (OSTI.GOV)
Pasqualotto, R.; Alfier, A.; Lotto, L.
2010-10-15
The rf source test facility SPIDER will test and optimize the source of the 1 MV neutral beam injection systems for ITER. Cavity ring-down spectroscopy (CRDS) will measure the absolute line-of-sight integrated density of negative (H{sup -} and D{sup -}) ions, produced in the extraction region of the source. CRDS takes advantage of the photodetachment process: negative ions are converted to neutral hydrogen atoms by electron stripping through absorption of a photon from a laser. The design of this diagnostic is presented with the corresponding simulation of the expected performance. A prototype operated without plasma has provided CRDS reference signals,more » design validation, and results concerning the signal-to-noise ratio.« less
Che, Yuliang; Yang, Hua; Wang, Zhimin; Jin, Hongxiao; Lu, Chunxin; Zuo, Tianming; Beavers, Christine M.
2009-01-01
The structures of two newly synthesized endohedral fullerenes - Tm@C3v-C94 and Ca@C3v-C94 - have been determined by single crystal X-ray diffraction on samples co-crystallized with NiII(octaethylporphyrin). Both compounds exhibit the same cage geometry and conform to the isolated pentagon rule (IPR). The metal ions within these rather large cages are localized near one end and along the C3 axis. While the calcium ion is situated over a C-C bond at a 6:6 ring junction, the thulium ion is positioned above a six-membered ring of the fullerene. PMID:19507844
ION BEAM POLARIZATION DYNAMICS IN THE 8 GEV BOOSTER OF THE JLEIC PROJECT AT JLAB
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kondratenko, A. M.; Kondratenko, M. A.; Morozov, Vasiliy
2016-05-01
In the Jefferson Lab’s Electron-Ion Collider (JLEIC) project, an injector of polarized ions into the collider ring is a superconducting 8 GeV booster. Both figure-8 and racetrack booster versions were considered. Our analysis showed that the figure-8 ring configuration allows one to preserve the polarization of any ion species during beam acceleration using only small longitudinal field with an integral less than 0.5 Tm. In the racetrack booster, to pre-serve the polarization of ions with the exception of deu-terons, it suffices to use a solenoidal Siberian snake with a maximum field integral of 30 Tm. To preserve deuteron polarization, wemore » propose to use arc magnets for the race-track booster structure with a field ramp rate of the order of 1 T/s. We calculate deuteron and proton beam polari-zations in both the figure-8 and racetrack boosters includ-ing alignment errors of their magnetic elements using the Zgoubi code.« less
Enhanced Discharge Performance in a Ring Cusp Plasma Source
NASA Technical Reports Server (NTRS)
Foster, John E.; Patterson, Michael J.
2000-01-01
There is a need for a lightweight, low power ion thruster for space science missions. Such an ion thruster is under development at NASA Glenn Research Center. In an effort to better understand the discharge performance of this thruster, a thruster discharge chamber with an anode containing electrically isolated electrodes at the cusps was fabricated and tested. Characteristics of this ring cusp ion discharge were measured without ion beam extraction. Discharge current was measured at collection electrodes located at the magnetic cusps and at the anode body itself. Discharge performance and plasma properties were measured as a function of power, which was varied between 20 and 50 W. It was found that ion production costs decreased by as much as 20 percent when the two most downstream cusp electrodes were allowed to float. Floating the electrodes did not give rise to a significant increase in discharge power even though the plasma density increased markedly. The improved performance is attributed to enhanced electron containment.
NASA Technical Reports Server (NTRS)
Khazanov, G. V.; Krivorutsky, E.; Gamayunov, K.; Avanov, L.
2003-01-01
The excitation of lower hybrid waves (LHWs) is a widely discussed mechanism of interaction between plasma species in space, and is one of the unresolved questions of magnetospheric multi-ion plasmas. In this paper we present the morphology, dynamics, and level of LHW activity generated by electromagnetic ion cyclotron (EMIC) waves during the May 2-7, 1998 storm period on the global scale. The LHWs were calculated based on our newly developed self-consistent model that couples the system of two kinetic equations: one equation describes the ring current (RC) ion dynamic, and another equation describes the evolution of EMIC waves. It is found that the LHWs are excited by helium ions due to their mass dependent drift in the electric field of EMIC waves. The level of LHW activity is calculated assuming that the induced scattering process is the main saturation mechanism for these waves. The calculated LHWs electric fields are consistent with the observational data.
NASA Technical Reports Server (NTRS)
Khazanov, G. V.
2004-01-01
The excitation of lower hybrid waves (LHWs) is a widely discussed mechanism of interaction between plasma species in space, and is one of the unresolved questions of magnetospheric multi-ion plasmas. In this paper we present the morphology, dynamics, and level of LHW activity generated by electromagnetic ion cyclotron (EMIC) waves during the May 2-7, 1998 storm period on the global scale. The LHWs were calculated based on a newly developed self-consistent model (Khazanov et. al., 2002, 2003) that couples the system of two kinetic equations: one equation describes the ring current (RC) ion dynamic, and another equation describes the evolution of EMIC waves. It is found that the LHWs are excited by helium ions due to their mass dependent drift in the electric field of EMIC waves. The level of LHW activity is calculated assuming that the induced scattering process is the main saturation mechanism for these waves. The calculated LHWs electric fields are consistent with the observational data.
Theoretical investigations of plasma processes in the ion bombardment thruster
NASA Technical Reports Server (NTRS)
Wilhelm, H. E.
1975-01-01
A physical model for a thruster discharge was developed, consisting of a spatially diverging plasma sustained electrically between a small ring cathode and a larger ring anode in a cylindrical chamber with an axial magnetic field. The associated boundary-value problem for the coupled partial differential equations with mixed boundary conditions, which describe the electric potential and the plasma velocity fields, was solved in closed form. By means of quantum-mechanical perturbation theory, a formula for the number S(E) of atoms sputtered on the average by an ion of energy E was derived from first principles. The boundary-value problem describing the diffusion of the sputtered atoms through the surrounding rarefied electron-ion plasma to the system surfaces of ion propulsion systems was formulated and treated analytically. It is shown that outer boundary-value problems of this type lead to a complex integral equation, which requires numerical resolution.
NASA Technical Reports Server (NTRS)
Roth, J. R.
1976-01-01
Parametric variation of independent variables which may affect the characteristics of the NASA Lewis Bumpy Torus plasma have identified those which have a significant effect on the plasma current, ion kinetic temperature, and plasma number density, and those which do not. Empirical power-law correlations of the plasma current, and the ion kinetic temperature and number density were obtained as functions of the potential applied to the midplane electrode rings, the background neutral gas pressure, and the magnetic field strength. Additional parameters studied include the type of gas, the polarity of the midplane electrode rings (and hence the direction of the radial electric field), the mode of plasma operation, and the method of measuring the plasma number density. No significant departures from the scaling laws appear to occur at the highest ion kinetic temperatures or number densities obtained to date.
Compact Torus plasma ring accelerator: a new type driver for inertial confinement fusion
DOE Office of Scientific and Technical Information (OSTI.GOV)
Hartman, C.W.; Eddleman, J.L.; Hammer, J.H.
1986-08-22
We discuss the acceleration of magnetically-confined plasma rings to provide a driver for ICF. The acceleration of plasma rings is predicted to be efficient and following focusing, to generate ion-bombardment power in the range 10/sup 15/ to 10/sup 16/ W/cm/sup 2/ at a total deposition energy of multimegajoules. The simplicity of plasma ring accelerator suggests that a 5 MJ (on target) driver would cost in the range 1 to 5 $/joule. First experimental tests of the accelerator are described.
NASA Astrophysics Data System (ADS)
Runov, A.; Angelopoulos, V.; Artemyev, A.; Lu, S.; Birn, J.; Pritchett, P. L.
2017-12-01
Electron interactions with Electromagnetic Ion Cyclotron (EMIC) amd Magnetosnic (MS) waves are considered as a mechanism of electron acceleration up to relativistic energies in the inner magnetosphere. The free energy for these waves is provided by ion populations with unstable energy distributions. It is established that the perpendicular anisotropy (T_perp > T_par) of energetic ions may provide the free energy for EMIC waves. The ring-type ion distributions are considered as the free energy source for the MS waves. Where and how do these distributions formed? To answer this question, we examined ion distribution functions within earthward-contracting dipolarizing flux bundles (DFBs) observed in the near-Earth plasma sheet at R 10 - 12 RE. It was found that ion distributions are often characterized by the perpendicular anisotropy at supra-thermal energies (at velocities V_thermal ≤ v ≤ 2*V_thermal). The effect was found to be stronger at largerbackground Bz (i.e., closer to the dipole). Similar characteristics wereobserved in particle-in-cell and test-particle simulations. Moreover, the simulations showed the ring-type ion distribution formation. These results suggest that ions, injected towards the inner magnetosphere with DFBs may indeed provide free energy for the EMIC and MS wave excitations.
Simulation and Twins Observations of the 22 July 2009 Storm
NASA Technical Reports Server (NTRS)
Fok, M.-C.; Buzulukova, N.; Chen, S.-H.; Valek, P. W.; Goldstein, J.; McComas, D. J.
2011-01-01
TWINS is the first mission to perform stereo imaging of the Earth's ring current. The magnetic storm on 22 July 2009 was at the time the largest storm observed since TWINS began routine stereo imaging in June 2008. On 22 July 2009, the Dst dropped to nearly .80 nT at 0700 and 1000 UT. During the main phase, and at the peak of the storm, TWINS 1 and 2 were near apogee and moving between predawn and postdawn local time. The energetic neutral atom (ENA) imagers on the two spacecraft captured the storm intensification and the formation of the partial ring current. The peak of the high-altitude ENA emissions was seen in the midnight-to-dawn local time sector. The development of this storm has been simulated using the comprehensive ring current model (CRCM) to understand and interpret the observed signatures. We perform CRCM runs with constant and time-varying magnetic field. The model calculations are validated by comparing the simulated ENA and ion flux intensities with TWINS ENA images and in situ ion data from a THEMIS satellite. Simulation with a static magnetic field produces a strong shielding electric field that skews the ion drift trajectories toward dawn. The model's corresponding peak ENA emissions are always more eastward than those in the observed TWINS images. On the other hand, the simulation with a dynamic magnetic field gives better spatial agreement with both ENA and in situ particle data, suggesting that temporal variations of the geomagnetic field exert a significant influence upon global ring current ion dynamics.
NASA Astrophysics Data System (ADS)
Keika, Kunihiro; Seki, Kanako; Nosé, Masahito; Miyoshi, Yoshizumi; Lanzerotti, Louis J.; Mitchell, Donald G.; Gkioulidou, Matina; Manweiler, Jerry W.
2018-01-01
We examine the spatiotemporal variations of the energy density and the energy spectral evolution of energetic ions in the inner magnetosphere during the main phase of the 17 March 2015 storm, using data from the RBSPICE and EMFISIS instruments onboard Van Allen Probes. The storm developed in response to two southward IMF intervals separated by about 3 h. In contrast to two steps seen in the
Scientific Achievements of Global ENA Imaging and Future Outlook
NASA Astrophysics Data System (ADS)
Brandt, P. C.; Stephens, G. K.; Hsieh, S. Y. W.; Demajistre, R.; Gkioulidou, M.
2017-12-01
Energetic Neutral Atom (ENA) imaging is the only technique that can capture the instantaneous global state of energetic ion distributions in planetary magnetospheres and from the heliosheath. In particular at Earth, ENA imaging has been used to diagnose the morphology and dynamics of the ring current and plasma sheet down to several minutes time resolution and is therefore a critical tool to validate global ring current physics models. However, this requires a detailed understanding for how ENAs are produced from the ring current and inversion techniques that are thoroughly validated against in-situ measurements. To date, several missions have carried out planetary and heliospheric ENA imaging including Cassini, JUICE, IBEX of the heliosphere, and POLAR, Astrid-1, Double Star, TWINS and IMAGE of the terrestrial magnetosphere. Because of their path-finding successes, a future global-imaging mission concept, MEDICI, has been recommended in the Heliophysics Decadal Survey. Its core mission consists of two satellites in one circular, near-polar orbit beyond the radiation belts at around 8 RE, with ENA, EUV and FUV cameras. This recommendation has driven the definition of smaller mission concepts that address specific science aspects of the MEDICI concept. In this presentation, we review the past scientific achievements of ENA imaging with a focus on the terrestrial magnetosphere from primarily the NASA IMAGE and the TWINS missions. The highlighted achievements include the storm, sub-storm and quiet-time morphology, dynamics and pitch-angle distributions of the ring current, global differential acceleration of protons versus O+ ions, the structure of the global electrical current systems associated with the plasma pressure of protons and O+ ions up to around 200 keV, and the relation between ring current and plasmasphere. We discuss the need for future global observations of the ring current, plasma sheet and magnetosheath ion distributions based and derive their measurement requirements, of which high-angular resolution (≤2˚) is critical. A significant aspect of the future science definition is the stability and accessibility of inversion algorithms that retrieve the 3D distribution from the 2D ENA images, that will also be discussed.
A Monte-Carlo Model for the Formation of Radiation-induced Chromosomal Aberrations
NASA Technical Reports Server (NTRS)
Ponomarev, Artem L.; Cornforth, Michael N.; Loucas, Brad D.; Cucinotta, Francis A.
2009-01-01
Purpose: To simulate radiation-induced chromosome aberrations in mammalian cells (e.g., rings, translocations, and dicentrics) and to calculate their frequency distributions following exposure to DNA double strand breaks (DSBs) produced by high-LET ions. Methods: The interphase genome was assumed to be comprised of a collection of 2 kbp rigid-block monomers following the random-walk geometry. Additional details for the modeling of chromosomal structure, such as chromosomal domains and chromosomal loops, were included. A radial energy profile for heavy ion tracks was used to simulate the high-LET pattern of induced DSBs. The induced DSB pattern depended on the ion charge and kinetic energy, but always corresponded to the DSB yield of 25 DSBs/cell/Gy. The sum of all energy contributions from Poisson-distributed particle tracks was taken to account for all possible one-track and multi-track effects. The relevant output of the model was DNA fragments produced by DSBs. The DSBs, or breakpoints, were defined by (x, y, z, l) positions, where x, y, z were the Euclidian coordinates of a DSB, and where l was the relative position along the genome. Results: The code was used to carry out Monte Carlo simulations for DSB rejoinings at low doses. The resulting fragments were analyzed to estimate the frequencies of specific types of chromosomal aberrations. Histograms for relative frequencies of chromosomal aberrations and P.D.F.s (probability density functions) of a given aberration type were produced. The relative frequency of dicentrics to rings was compared to empirical data to calibrate rejoining probabilities. Of particular interest was the predicted distribution of ring sizes, irrespective of their frequencies relative to other aberrations. Simulated ring sizes were . 4 kbp, which are far too small to be observed experimentally (i.e., by microscopy) but which, nevertheless, are conjectured to exist. Other aberrations, for example, inversions, translocations, as well as multi-centrics were also recorded. Conclusion: High-LET DNA damage affects the frequencies of chromosomal aberrations. The ratio of rings to dicentrics is correct for the genomic size cut-offs corresponding to available experimental data. The present work predicts a relative abundance of small rings following irradiation by heavy ions.
NASA Astrophysics Data System (ADS)
Pandey, Arun; Bandyopadhyay, M.; Sudhir, Dass; Chakraborty, A.
2017-10-01
Helicon wave heated plasmas are much more efficient in terms of ionization per unit power consumed. A permanent magnet based compact helicon wave heated plasma source is developed in the Institute for Plasma Research, after carefully optimizing the geometry, the frequency of the RF power, and the magnetic field conditions. The HELicon Experiment for Negative ion-I source is the single driver helicon plasma source that is being studied for the development of a large sized, multi-driver negative hydrogen ion source. In this paper, the details about the single driver machine and the results from the characterization of the device are presented. A parametric study at different pressures and magnetic field values using a 13.56 MHz RF source has been carried out in argon plasma, as an initial step towards source characterization. A theoretical model is also presented for the particle and power balance in the plasma. The ambipolar diffusion process taking place in a magnetized helicon plasma is also discussed.
Pandey, Arun; Bandyopadhyay, M; Sudhir, Dass; Chakraborty, A
2017-10-01
Helicon wave heated plasmas are much more efficient in terms of ionization per unit power consumed. A permanent magnet based compact helicon wave heated plasma source is developed in the Institute for Plasma Research, after carefully optimizing the geometry, the frequency of the RF power, and the magnetic field conditions. The HELicon Experiment for Negative ion-I source is the single driver helicon plasma source that is being studied for the development of a large sized, multi-driver negative hydrogen ion source. In this paper, the details about the single driver machine and the results from the characterization of the device are presented. A parametric study at different pressures and magnetic field values using a 13.56 MHz RF source has been carried out in argon plasma, as an initial step towards source characterization. A theoretical model is also presented for the particle and power balance in the plasma. The ambipolar diffusion process taking place in a magnetized helicon plasma is also discussed.
Zhang, Weidong; Li, Guoping; Xu, Letian; Zhuo, Yue; Wan, Wenming; Yan, Ni; He, Gang
2018-05-21
The introduction of main group elements into conjugated scaffolds is emerging as a key route to novel optoelectronic materials. Herein, an efficient and versatile way to synthesize polymerizable 9,10-azaboraphenanthrene ( BNP )-containing monomers by aromaticity-driven ring expansion reactions between highly antiaromatic borafluorene and azides is reported, and the corresponding conjugated small molecules and polymers are developed as well. The BNP -containing small molecules and conjugated polymers showed good air/moisture stability and notable fluorescence properties. Addition of fluoride ions to the BNP -based small molecules and polymers induced a rapid change in the emission color from blue to green/yellow, respectively, accompanied by strong intensity changes. The conjugated polymers showed better ratiometric sensing performance than small molecules due to the exciton migration along the conjugated chains. Further experiments showed that the sensing process is fully reversible. The films prepared by solution-deposition of BNP -based compounds in the presence of polycaprolactone also showed good ratiometric sensing for fluoride ions.
Pickup water group ions at Comet Grigg-Skjellerup
NASA Astrophysics Data System (ADS)
Coates, A. J.; Johnstone, A. D.; Huddleston, D. E.; Wilken, B.; Jockers, K.; Borg, H.; Amata, E.; Formisano, V.; Bavassano-Cattaneo, M. B.; Winningham, J. D.; Gurgiolo, C.; Neubauer, F. M.
1993-03-01
The density and velocity distribution of cometary water group ions was measured by the Giotto spacecraft in the regions upstream and downstream of the 'bow shock' at Comet Grigg-Skjellerup. The results show that the distributions of ions are ring-like until quite close to the shock, the timescales for pitch angle and energy diffusion appear similar and the ion density follows a r exp -2 dependence.
NASA Astrophysics Data System (ADS)
Kauschke, M.; Schroeder, C. H.
2004-06-01
The Gesellschaft fuer Schwerionenforschung (GSI), Darmstadt, is planning an extension of the existing heavy ion accelerator. The new facilities will contain two synchrotrons, four storage rings and approximately 1.4 km of beam transport, requiring different types of magnets and cooling regimes. As the magnets for the synchrotrons have to be fast-ramped magnets, the cryogenic system heat loads will be dominated by the AC-losses of the magnets. Our approach is to adopt and modify existing magnet designs to achieve a short development time for the facility. The cryogenic system has to provide 7.5 kW at 4.4 K in the two-phase cooling regime, 3 kW at 0.4 MPa and 4.2 K in forced-flow cooling for the synchrotrons. The storage ring magnets will be placed in bath cryostats and require a refrigeration capacity of 5 kW at 4.5 K. As the project will be commissioned in several steps, an economic plan for the cryogenic infrastructure is needed, which will be sufficient for every phase of the build-up and allow experiments in some parts of the facilities as well as the testing of the components for the later parts of the facility.
Mechanical properties of photomultiplier tube glasses for neutrino detection
Dongol, Ruhil; Chambliss, Kameron; Sundaram, Shanmugavelayutham K.; ...
2015-08-31
Photomultiplier tubes (PMT) are one of the primary components of water Cherenkov neutrino detection for the Long Baseline Neutrino Experiment (LBNE). Thousands of 10- to 12-inch diameter PMT bulbs are placed in the inner wall of a detection tank or a reservoir (e.g., deep mine) filled with 10,000 gallons of high purity water with a resistivity of 11–18.24 MΩ-cm. Long-term service of PMTs is vital to the success of neutrino detection projects. We report our results of our investigation on mechanical properties of PMT glasses from two vendors and the effect of ion exchange on their mechanical strength. Vickers indentation,more » four-point bend test, and ring-on-ring biaxial flexural strength test were used for evaluation of the mechanical strength. Chemical (potassium–sodium ion exchange) strengthening results show increased strength of 46% in one vendor glass and a 57% increase in the other, with no significant reduction in optical transmission in the ultraviolet-visible range of the electromagnetic spectrum that is critical to neutrino detection. Finally, our results also show narrowing of the distribution of strength calculated using Weibull statistics with chemical strengthening for comparable exchange depths of 22–28 μm.« less
Cationized Carbohydrate Gas-Phase Fragmentation Chemistry
NASA Astrophysics Data System (ADS)
Bythell, Benjamin J.; Abutokaikah, Maha T.; Wagoner, Ashley R.; Guan, Shanshan; Rabus, Jordan M.
2017-04-01
We investigate the fragmentation chemistry of cationized carbohydrates using a combination of tandem mass spectrometry, regioselective labeling, and computational methods. Our model system is D-lactose. Barriers to the fundamental glyosidic bond cleavage reactions, neutral loss pathways, and structurally informative cross-ring cleavages are investigated. The most energetically favorable conformations of cationized D-lactose were found to be similar. In agreement with the literature, larger group I cations result in structures with increased cation coordination number which require greater collision energy to dissociate. In contrast with earlier proposals, the B n -Y m fragmentation pathways of both protonated and sodium-cationized analytes proceed via protonation of the glycosidic oxygen with concerted glycosidic bond cleavage. Additionally, for the sodiated congeners our calculations support sodiated 1,6-anhydrogalactose B n ion structures, unlike the preceding literature. This affects the subsequent propensity of formation and prediction of B n /Y m branching ratio. The nature of the anomeric center (α/β) affects the relative energies of these processes, but not the overall ranking. Low-energy cross-ring cleavages are observed for the metal-cationized analytes with a retro-aldol mechanism producing the 0,2 A 2 ion from the sodiated forms . Theory and experiment support the importance of consecutive fragmentation processes, particularly for the protonated congeners at higher collision energies.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mautner, M.M.N.
The ionization energy of ferrocene (Cp{sub 2}Fe) was measured by charge-transfer equilibria as 6.81 {plus minus} 0.07 eV (157.1 {plus minus} 1.6 kcal/mol). The proton affinity was obtained from equilibrium temperature studies as 207 {plus minus} 1 kcal/mol. The protonation of Cp{sub 2}Fe also involves a significant entropy change of +6.3 cal/mol{center dot}K. Deuteration experiments show that, in the protonation of Cp{sub 2}Fe, the incoming proton goes to a sterically unique position and does not exchange with the ring protons. This is consistent with protonation on iron, but ring protonation exclusively in an exo position or an agostic ring-to-iron bridgedmore » structure are also possible. The results suggest that the proton affinity at Fe is greater by at least 5 kcal/mol than for ring protonation. The solvation energies of Cp{sub 2}Fe{sup +} and Cp{sub 2}FeH{sup +} by a CH{sub 3}CN molecule, 11.4 and 12.9 kcal/mol, respectively, are weaker than those of most gas-phase cations, and the attachment energies of dimethyl ether and benzene, <9 kcal/mol, are even weaker. These results support that the weak solution basicity of Cp{sub 2}Fe is due to inefficient ion solvation. The kinetics of proton transfer between Cp{sub 2}Fe and some cyclic compounds is unusually slow, with reaction efficiencies of 0.1-0.01, without significant temperature dependence. These are the first proton-transfer reactions to show such behavior, which may be due to a combination of an energy barrier and steric hindrance. Proton transfer is also observed from (RCN){sub 2}H{sup +} dimer ions to Cp{sub 2}Fe. These reactions may be direct or involve ligand switching, and in several cases either mechanism is endothermic and entropy-driven.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kaur, Manjit, E-mail: manjit@ipr.res.in; Bose, Sayak; Chattopadhyay, P. K.
2015-09-15
Observation of two well-separated dust vortices in an unmagnetized parallel plate DC glow discharge plasma is reported in this paper. A non-monotonic radial density profile, achieved by an especially designed cathode structure using a concentric metallic disk and ring of different radii, is observed to produce double dust tori between cathode and anode. PIV analysis of the still images of the double tori shows oppositely rotating dust structures between the central disk and the ring. Langmuir probe measurements of background plasma shows a non-uniform plasma density profile between the disk and the ring. Location and sense of rotation of themore » dust vortices coincides with the location and direction of the radial gradient in the ion drag force caused by the radial density gradient. The experimentally observed dust vorticity matches well with the calculated one using hydrodynamic formulations with shear in ion drag dominating over the dust charge gradient. These results corroborate that a radial gradient in the ion drag force directed towards cathode is the principal cause of dust rotation.« less
NASA Astrophysics Data System (ADS)
Sasoh, A.; Mizutani, K.; Iwakawa, A.
2017-06-01
Ion acceleration through a slowly diverging magnetic nozzle between a ring anode and a hollow cathode set on the axis of symmetry has been realized. Xenon was supplied as the propellant gas from an annular slit along the inner surface of the ring anode so that it was ionized near the anode, and the applied electric potential was efficiently transformed to an ion kinetic energy. As an electrostatic thruster, within the examined operation conditions, the thrust, F, almost scaled with the propellant mass flow rate; the discharge current, Jd, increased with the discharge voltage, Vd. An important characteristic was that the thrust also exhibited electromagnetic acceleration performance, i.e., the so-called "swirl acceleration," in which F ≅JdB Ra /√{2 }, where B and Ra were a magnetic field and an anode inner radius, respectively. Such a unique thruster performance combining both electrostatic and electromagnetic accelerations is expected to be useful as another option for in-space electric propulsion in its broad functional diversity.
NASA Astrophysics Data System (ADS)
Konda, Chiharu; Londry, Frank A.; Bendiak, Brad; Xia, Yu
2014-08-01
A systematic approach is described that can pinpoint the stereo-structures (sugar identity, anomeric configuration, and location) of individual sugar units within linear oligosaccharides. Using a highly modified mass spectrometer, dissociation of linear oligosaccharides in the gas phase was optimized along multiple-stage tandem dissociation pathways (MSn, n = 4 or 5). The instrument was a hybrid triple quadrupole/linear ion trap mass spectrometer capable of high-efficiency bidirectional ion transfer between quadrupole arrays. Different types of collision-induced dissociation (CID), either on-resonance ion trap or beam-type CID could be utilized at any given stage of dissociation, enabling either glycosidic bond cleavages or cross-ring cleavages to be maximized when wanted. The approach first involves optimizing the isolation of disaccharide units as an ordered set of overlapping substructures via glycosidic bond cleavages during early stages of MSn, with explicit intent to minimize cross-ring cleavages. Subsequently, cross-ring cleavages were optimized for individual disaccharides to yield key diagnostic product ions ( m/ z 221). Finally, fingerprint patterns that establish stereochemistry and anomeric configuration were obtained from the diagnostic ions via CID. Model linear oligosaccharides were derivatized at the reducing end, allowing overlapping ladders of disaccharides to be isolated from MSn. High confidence stereo-structural determination was achieved by matching MSn CID of the diagnostic ions to synthetic standards via a spectral matching algorithm. Using this MSn ( n = 4 or 5) approach, the stereo-structures, anomeric configurations, and locations of three individual sugar units within two pentasaccharides were successfully determined.
Experimental evidence of ion-induced instabilities in the NSLS-II storage ring
Cheng, Weixing; Li, Yongjun; Podobedov, Boris
2017-03-12
Fast ion instability has been identified as one of the most prominent instabilities in the recently constructed NSLS-II storage ring at Brookhaven National Laboratory. At a relatively low beam current (~ 25 mA) multi-bunch fills, ion-induced instabilities have already been observed during the early stages of machine commissioning. At present user operation with 250 mA in ~1000 bunches, the fast ion still remains the dominant instability, even after months of vacuum conditioning at high current. Ion-induced dipole motions of the electron beam have been suppressed using the transverse bunch-by-bunch (BxB) feedback system. However other adverse effects of this instability, suchmore » as the vertical beam size increase along the bunch train cannot be cured by the feedback system. Therefore, to achieve the NSLS-II design current of 500 mA while maintaining a small vertical beam emittance, it is important to further understand the fast ion instability and develop mitigation techniques. This paper reports on a series of ion-instability observations at various fill patterns and beam currents using start-of-art NSLS-II diagnostic tools.« less
Experimental evidence of ion-induced instabilities in the NSLS-II storage ring
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cheng, Weixing; Li, Yongjun; Podobedov, Boris
Fast ion instability has been identified as one of the most prominent instabilities in the recently constructed NSLS-II storage ring at Brookhaven National Laboratory. At a relatively low beam current (~ 25 mA) multi-bunch fills, ion-induced instabilities have already been observed during the early stages of machine commissioning. At present user operation with 250 mA in ~1000 bunches, the fast ion still remains the dominant instability, even after months of vacuum conditioning at high current. Ion-induced dipole motions of the electron beam have been suppressed using the transverse bunch-by-bunch (BxB) feedback system. However other adverse effects of this instability, suchmore » as the vertical beam size increase along the bunch train cannot be cured by the feedback system. Therefore, to achieve the NSLS-II design current of 500 mA while maintaining a small vertical beam emittance, it is important to further understand the fast ion instability and develop mitigation techniques. This paper reports on a series of ion-instability observations at various fill patterns and beam currents using start-of-art NSLS-II diagnostic tools.« less
Saturn's E, G, and F rings - Modulated by the plasma sheet?
NASA Technical Reports Server (NTRS)
Morfill, G. E.; Gruen, E.; Johnson, T. V.
1983-01-01
Saturn's broad E ring, the narrow G ring, and the structured and apparently time-variable F ring(s) contain many micron and submicron-sized particles, which make up the 'visible' component. These rings (or ring systems) are in direct contact with magnetospheric plasma. Fluctuations in the plasma density and/or mean energy, due to magnetospheric and solar wind processes, may induce stochastic charge variations on the dust particles, which in turn lead to an orbit perturbation and spatial diffusion. In addition, Coulomb drag forces may be important, in particular for the E ring. The possibility that electromagnetic effects may play a role in determining the F ring structure and its possible time variations is critically examined. Sputtering of micron-sized dust particles in the E ring by magnetospheric ions yields lifetimes of 100 to 10,000 years. This effect as well as the plasma induced transport processes require an active source for the E ring, probably Enceladus.
Kinetic modeling of the Saturn ring-ionosphere plasma environment
NASA Technical Reports Server (NTRS)
Wilson, G. R.; Waite, J. H., Jr.
1989-01-01
A time-independent kinetic plasma model was developed on the basis of the Li et al. (1988) semikinetic plasma model and was used to study the interaction of the Saturnian ionosphere and ring plasma. The model includes the gravitational magnetic mirror and centripetal and ambipolar electric forces, and the effect of the mixing of two plasma populations. The results obtained indicate that the density, temperature, and composition of plasma near the rings changing in the direction from the inner C ring to the outer A ring, due to the fact that the predominant source of plasma changes from the ionosphere to the rings. The model results also suggest that the outflow of hydrogen from the ionosphere to the rings may be shut off for field lines passing through the outer B and A ring, due to the ambipolar electric field set up by the warm ring plasma trapped near the ring plane by the centipetal force. In these regions, there will be a net flux of O(+) ions from the rings to the ionosphere.
Transport of Energetic Ions in the Ring Current During Geomagnetic Storms
NASA Technical Reports Server (NTRS)
Kistler, Lynn M.; Kaufmann, Richard
2001-01-01
In the final year (plus no-cost extentions) of this grant, we have: Used the particle tracing code to perform a systematic study of the expected energy spectra over the full range of local times in the ring current using a variety of electric and magnetic field models. Shown that the Weimer electric field is superior to the Volland-Stern electric field in reproducing the observed energy spectra on the AMPTE CCE spacecraft. Redone our analysis of the pitch angle spectra of energetic ions during storms in the magnetosphere, using a larger data set, and a more reliable classification technique.
Ion source based on the cathodic arc
Sanders, D.M.; Falabella, S.
1994-02-01
A cylindrically symmetric arc source to produce a ring of ions which leave the surface of the arc target radially and are reflected by electrostatic fields present in the source to a point of use, such as a part to be coated, is described. An array of electrically isolated rings positioned in the source serves the dual purpose of minimizing bouncing of macroparticles and providing electrical insulation to maximize the electric field gradients within the source. The source also includes a series of baffles which function as a filtering or trapping mechanism for any macroparticles. 3 figures.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Yuri, Yosuke, E-mail: yuri.yosuke@jaea.go.jp
Three-dimensional (3D) ordering of a charged-particle beams circulating in a storage ring is systematically studied with a molecular-dynamics simulation code. An ion beam can exhibit a 3D ordered configuration at ultralow temperature as a result of powerful 3D laser cooling. Various unique characteristics of the ordered beams, different from those of crystalline beams, are revealed in detail, such as the single-particle motion in the transverse and longitudinal directions, and the dependence of the tune depression and the Coulomb coupling constant on the operating points.
Physics and biophysics experiments needed for improved risk assessment in space
NASA Astrophysics Data System (ADS)
Sihver, L.
To improve the risk assessment of radiation carcinogenesis, late degenerative tissue effects, acute syndromes, synergistic effects of radiation and microgravity or other spacecraft factors, and hereditary effects, on future LEO and interplanetary space missions, the radiobiological effects of cosmic radiation before and after shielding must be well understood. However, cosmic radiation is very complex and includes low and high LET components of many different neutral and charged particles. The understanding of the radiobiology of the heavy ions, from GCRs and SPEs, is still a subject of great concern due to the complicated dependence of their biological effects on the type of ion and energy, and its interaction with various targets both outside and within the spacecraft and the human body. In order to estimate the biological effects of cosmic radiation, accurate knowledge of the physics of the interactions of both charged and non-charged high-LET particles is necessary. Since it is practically impossible to measure all primary and secondary particles from all projectile-target-energy combinations needed for a correct risk assessment in space, accurate particle and heavy ion transport codes might be a helpful instrument to overcome those difficulties. These codes have to be carefully validated to make sure they fulfill preset accuracy criteria, e.g. to be able to predict particle fluence and energy distributions within a certain accuracy. When validating the accuracy of the transport codes, both space and ground-based accelerator experiments are needed. In this paper current and future physics and biophysics experiments needed for improved risk assessment in space will be discussed. The cyclotron HIRFL (heavy ion research facility in Lanzhou) and the new synchrotron CSR (cooling storage ring), which can be used to provide ion beams for space related experiments at the Institute of Modern Physics, Chinese Academy of Sciences (IMP-CAS), will be presented together with the physical and biomedical research performed at IMP-CAS.
NASA Astrophysics Data System (ADS)
Nahar, S. N.
2003-01-01
Most astrophysical plasmas entail a balance between ionization and recombination. We present new results from a unified method for self-consistent and ab initio calculations for the inverse processes of photoionization and (e + ion) recombination. The treatment for (e + ion) recombination subsumes the non-resonant radiative recombination and the resonant dielectronic recombination processes in a unified scheme (S.N. Nahar and A.K. Pradhan, Phys. Rev. A 49, 1816 (1994);H.L. Zhang, S.N. Nahar, and A.K. Pradhan, J.Phys.B, 32,1459 (1999)). Calculations are carried out using the R-matrix method in the close coupling approximation using an identical wavefunction expansion for both processes to ensure self-consistency. The results for photoionization and recombination cross sections may also be compared with state-of-the-art experiments on synchrotron radiation sources for photoionization, and on heavy ion storage rings for recombination. The new experiments display heretofore unprecedented detail in terms of resonances and background cross sections and thereby calibrate the theoretical data precisely. We find a level of agreement between theory and experiment at about 10% for not only the ground state but also the metastable states. The recent experiments therefore verify the estimated accuracy of the vast amount of photoionization data computed under the OP, IP and related works. features. Present work also reports photoionization cross sections including relativistic effects in the Breit-Pauli R-matrix (BPRM) approximation. Detailed features in the calculated cross sections exhibit the missing resonances due to fine structure. Self-consistent datasets for photoionization and recombination have so far been computed for approximately 45 atoms and ions. These are being reported in a continuing series of publications in Astrophysical J. Supplements (e.g. references below). These data will also be available from the electronic database TIPTOPBASE (http://heasarc.gsfc.nasa.gov)
Experience with IBS-suppression lattice in RHIC
DOE Office of Scientific and Technical Information (OSTI.GOV)
Litvinenko,V.N.; Luo, Y.; Ptitsyn, V.
An intra-beam scattering (IBS) is the limiting factor of the luminosity lifetime for RHIC operating with heavy ions. In order to suppress the IBS we designed and implemented new lattice with higher betatron tunes. This lattice had been developed during last three years and had been used for gold ions in yellow ring of the RHIC during d-Au part of the RHIC Run-8. The use of this lattice allowed both significant increases in the luminosity lifetime and the luminosity levels via reduction of beta-stars in the IPS. In this paper we report on the development, the tests and the performancemore » of IBS-suppression lattice in RHIC, including the resulting increases in the peak and the average luminosity. We also report on our plans for future steps with the IBS suppression.« less
Saturn's Rings and Associated Ring Plasma Cavity: Evidence for Slow Ring Erosion
NASA Technical Reports Server (NTRS)
Farrell, W. M.; Kurth, W. S.; Gurnett, D. A.; Persoon, A. M.; MacDowall, R. J.
2017-01-01
We re-examine the radio and plasma wave observations obtained during the Cassini Saturn orbit insertion period, as the spacecraft flew over the northern ring surface into a radial distance of 1.3 Rs (over the C-ring). Voyager era studies suggest the rings are a source of micro-meteoroid generated plasma and dust, with theorized peak impact-created plasma outflows over the densest portion of the rings (central B-ring). In sharp contrast, the Cassini Radio and Plasma Wave System (RPWS) observations identify the presence of a ring-plasma cavity located in the central portion of the B-ring, with little evidence of impact-related plasma. While previous Voyager era studies have predicted unstable ion orbits over the C- ring, leading to field-aligned plasma transport to Saturns ionosphere, the Cassini RPWS observations do not reveal evidence for such instability-created plasma fountains. Given the passive ring loss processes observed by Cassini, we find that the ring lifetimes should extend >10(exp 9) years, and that there is limited evidence for prompt destruction (loss in <100 Myrs).
Saturn's rings and associated ring plasma cavity: Evidence for slow ring erosion
NASA Astrophysics Data System (ADS)
Farrell, W. M.; Kurth, W. S.; Gurnett, D. A.; Persoon, A. M.; MacDowall, R. J.
2017-08-01
We re-examine the radio and plasma wave observations obtained during the Cassini Saturn orbit insertion period, as the spacecraft flew over the northern ring surface into a radial distance of 1.3 Rs (over the C-ring). Voyager era studies suggest the rings are a source of micro-meteoroid generated plasma and dust, with theorized peak impact-created plasma outflows over the densest portion of the rings (central B-ring). In sharp contrast, the Cassini Radio and Plasma Wave System (RPWS) observations identify the presence of a ring-plasma cavity located in the central portion of the B-ring, with little evidence of impact-related plasma. While previous Voyager era studies have predicted unstable ion orbits over the C-ring, leading to field-aligned plasma transport to Saturn's ionosphere, the Cassini RPWS observations do not reveal evidence for such instability-created plasma 'fountains'. Given the passive ring loss processes observed by Cassini, we find that the ring lifetimes should extend >109 years, and that there is limited evidence for prompt destruction (loss in <100 Myrs).
Stormtime transport of ring current and radiation belt ions
NASA Technical Reports Server (NTRS)
Chen, Margaret W.; Schulz, Michael; Lyons, L. R.; Gorney, David J.
1993-01-01
This is an investigation of stormtime particle transport that leads to formation of the ring current. Our method is to trace the guiding-center motion of representative ions (having selected first adiabatic invariants mu) in response to model substorm-associated impulses in the convection electric field. We compare our simulation results qualitatively with existing analytically tractable idealizations of particle transport (direct convective access and radial diffusion) in order to assess the limits of validity of these approximations. For mu approximately less than 10 MeV/G (E approximately less than 10 keV at L equivalent to 3) the ion drift period on the final (ring-current) drift shell of interest (L equivalent to 3) exceeds the duration of the main phase of our model storm, and we find that the transport of ions to this drift shell is appropriately idealized as direct convective access, typically from open drift paths. Ion transport to a final closed drift path from an open (plasma-sheet) drift trajectory is possible for those portions of that drift path that lie outside the mean stormtime separatrix between closed and open drift trajectories, For mu approximately 10-25 MeV/G (110 keV approximately less than E approximately less than 280 keV at L equivalent to 3) the drift period at L equivalent to 3 is comparable to the postulated 3-hr duration of the storm, and the mode of transport is transitional between direct convective access and transport that resembles radial diffusion. (This particle population is transitional between the ring current and radiation belt). For mu approximately greater than 25 MeV/G (radiation-belt ions having E approximately greater than 280 keV at L equivalent to 3) the ion drift period is considerably shorter than the main phase of a typical storm, and ions gain access to the ring-current region essentially via radial diffusion. By computing the mean and mean-square cumulative changes in 1/L among (in this case) 12 representative ions equally spaced in drift time around the steady-state drift shell of interest (L equivalent to 3), we have estimated (from both our forward and our time-reversed simulations) the time-integrated radial-diffusion coefficients D(sup sim)(sub LL) for particles having selected values of mu approximately greater than 15 MeV/G. The results agree surprisingly well with the predictions (D(sup ql)(sub LL)) of quasilinear radial diffusion theory, despite the rather brief duration (approximately 3 hrs) of our model storm and despite the extreme variability (with frequency) of the spectral-density function that characterizes the applied electric field during our model storm. As expected, the values of D(sup sim)(sub LL) deduced (respectively) from our forward and time-reversed simulations agree even better with each other and with D(sup sim)(sub LL) when the impulse amplitudes which characterize the individual substorms of our model storm are systematically reduced.
ERIC Educational Resources Information Center
Baylie, M.; Ford, P. J.; Mathlin, G. P.; Palmer, C.
2009-01-01
The jumping ring experiment has become central to liquid nitrogen shows given as part of the outreach and open day activities carried out within the University of Bath. The basic principles of the experiment are described as well as the effect of changing the geometry of the rings and their metallurgical state. In general, aluminium rings are…
Facility for Antiproton and Ion Research, FAIR, at the GSI site
NASA Astrophysics Data System (ADS)
Rosner, Guenther
2006-11-01
FAIR is a new large-scale particle accelerator facility to be built at the GSI site in Germany. The research pursued at FAIR will cover a wide range of topics in nuclear and hadron physics, as well as high density plasma physics, atomic and antimatter physics, and applications in condensed matter physics and biology. The working horse of FAIR will be a 1.1km circumference double ring of rapidly cycling 100 and 300Tm synchrotrons, which will be used to produce high intensity secondary beams of short-lived radioactive ions or antiprotons. A subsequent suite of cooler and storage rings will deliver heavy ion and antiproton beams of unprecedented quality. Large experimental facilities are presently being designed by the NUSTAR, PANDA, PAX, CBM, SPARC, FLAIR, HEDgeHOB and BIOMAT collaborations.
Seasonal and radial trends in Saturn’s thermal plasma between the main rings and Enceladus
NASA Astrophysics Data System (ADS)
Elrod, M. K.; Tseng, W.-L.; Woodson, A. K.; Johnson, R. E.
2014-11-01
A goal of Cassini's extended mission is to examine the seasonal variations of Saturn's magnetosphere, moons, and rings. Recently we showed that the thermal plasma between the main rings and Enceladus exhibited a time dependence that we attributed to a seasonally variable source of oxygen from the main rings (Elrod, M.K., Tseng, W.-L., Wilson, R.J., Johnson, R.E. [2012]. J. Geophys. Res. 117, A03207. http://dx.doi.org/10.1029/2011JA017332). Such a temporal variation was subsequently seen in the energetic ion composition (Christon, S.P., Hamilton, D.C., DiFabio, R.D., Mitchel, D.G., Krimigis, S.M., Jontof-Hutter, D.S. [2013]. J. Geophys. Res. 28. http://dx.doi.org/10.1002/jgra.50383; Christon, S.P., Hamilton, D.C., Mitchell, D.G., DiFabio, R.D., Krimigis, S.M. [2014]. J. Geophys. Res., submitted for publication). Here we incorporate the most recent measurements by the Cassini Plasma Spectrometer (CAPS) into our earlier analysis (Elrod, M.K., Tseng, W.-L., Wilson, R.J., Johnson, R.E. [2012]. J. Geophys. Res. 117, A03207. http://dx.doi.org/10.1029/2011JA017332) and our modeling (Tseng, W.-L., Johnson, R.E., Elrod, M.K. [2013a]. Planet. Space Sci. 77, 126-135) of the thermal plasma in the region between the main rings and the orbit of Enceladus. Data taken in 2012, well past equinox for which the northern side of the main rings were illuminated, appear consistent with a seasonal variation. Although the thermal plasma in this region comes from two sources that have very different radial and temporal trends, the extended ring atmosphere and the Enceladus torus, the heavy ion density is found to exhibit a steep radial dependence that is similar for the years examined. Using our chemical model, we show that this dependence requires either a radial dependence for Enceladus torus that differs significantly from recent models or, as we suggest here, enhanced heavy ion quenching/neutralization with decreasing distance from the edge of the main rings. We examine the possible physical processes and suggest that the presence of small grains and the precipitation of the inward diffusing high-energy background radiation onto the edge of the main rings play important roles.
Characteristics of molecular ions in the ring current observed by the Arase (ERG) satellite
NASA Astrophysics Data System (ADS)
Seki, K.; Keika, K.; Kasahara, S.; Yokota, S.; Matsuoka, A.; Ogawa, Y.; Asamura, K.; Yoshizumi, M.; Shinohara, I.
2017-12-01
There are two plasma sources for the terrestrial magnetosphere, i.e., the ionosphere and the solar wind. It is observationally known that the terrestrial plasma contribution, especially that of heavy ions increases with increasing geomagnetic activities, while the mechanisms of the enhanced ionospheric supply are far from understood. While the O+ ions are the main species of terrestrial heavy ions, the heavier molecular ions such as NO+ and O2+ have been observed in the various regions of the magnetosphere during geomagnetically active periods [e.g., Klecker et al, 1986; Peterson et al., 1994; Christon et al, 1994; Poppe et al., 2016]. In order to get the molecular ion outflows from the deep ionosphere with altitudes of 250-500 km, they need to be energized at least up to the escape energy of 10 eV within a short time scale ( order of minutes) to overcome the dissociative recombination lifetime at the source altitudes. The observations of the high-energy ( 100keV) molecular ions in the ring current and outer magnetosphere suggest an effective acceleration mechanism is in operation during geomagnetically active periods. In this paper, we report on observations of molecular ions in the ring current by the Arase satellite and their relations to the solar wind and magnetospheric/ionospheric conditions. The ion composition data of the Arase satellite, which detects the ions less than 180 keV/q, were analyzed in details. The investigated period from late March to July 2017 includes four geomagnetic storms with peak Dst less than 40 nT. The molecular ions with energized above several tens of keV are detected during late main and/or early recovery phases of geomagnetic storms. The appearance of the molecular ions does not have a clear dependence on the substorm activities. It suggests that they are indirectly supplied from the polar ionosphere to the inner magnetosphere and requires additional acceleration mechanisms such as the circulation of the molecular ions in the magnetosphere. During quiet periods, the molecular ions stayed less than the detection threshold of the Arase/MEPi instrument. References: Klecker et al., Geophys. Res. Lett., 13, 632-635, 1986. Peterson et al., J. Geophys. Res., 99, 23257-23274, 1994. Christon et al., Geophys. Re. Lett., 21, 3023-3026, 1994. Poppe et al., J. Geophys. Re. Lett., 43, 6749-6758, 2016.
Inferring Core Tungsten Behavior Using SPRED During the DIII-D Metal Rings Campaign
NASA Astrophysics Data System (ADS)
Thomas, D. M.; Kaplan, D.; Groebner, R.; Grierson, B.; Unterberg, Z.; Victor, B.
2016-10-01
The GA SPRED EUV spectrometer was used to study core emission of highly charged tungsten ions (W40+-W45+) in the 120-135Å region during the recent Metal Rings Campaign. These experiments used two 5-cm wide toroidal rings of W-coated metal inserts exposed to a variety of DIII-D discharges to study effects of high-Z divertor erosion, migration, core uptake, and effects on advanced tokamak performance. For the proper core temperature range (2-4 keV), the measured multistate W emission forms a well defined spectral pattern that can be used to study the relative importance of strike point location, flux expansion, injected power, ELM characteristics and magnetic drift direction for high-Z core contamination in DIII-D. The spectra are fit using simple Gaussians to estimate concentrations using the historical SPRED intensity calibration. Calibration shots using known core dosages of pellet injected W are used to help infer the relative response of the instrument. Supported by US DOE under DE-FC02-04ER54698, DE-AC02-09CH11466, DE-AC05-00OR22725, DE-AC52-07NA27344.
Design and R&D of RICH detectors for EIC experiments
Del Dotto, A.; Wong, C. -P.; Allison, L.; ...
2017-03-18
An Electron-Ion Collider (EIC) has been proposed to further explore the strong force and QCD, focusing on the structure and the interaction of gluon-dominated matter. A generic detector R&D program (EIC PID consortium) for the particle identification in EIC experiments was formed to explore technologically advanced solutions in this scope. In this context two Ring Imaging Cherenkov (RICH) counters have been proposed: a modular RICH detector which consists of an aerogel radiator, a Fresnel lens, a mirrored box, and pixelated photon sensor; a dual-radiator RICH, consisting of an aerogel radiator and C 2F 6 gas in a mirror-focused configuration. Asmore » a result, we present the simulations of the two detectors and their estimated performance.« less
The phase slip factor of the electrostatic cryogenic storage ring CSR
NASA Astrophysics Data System (ADS)
Grieser, Manfred; von Hahn, Robert; Vogel, Stephen; Wolf, Andreas
2017-07-01
To determine the momentum spread of an ion beam from the measured revolution frequency distribution, the knowledge of the phase slip factor of the storage ring is necessary. The slip factor was measured for various working points of the cryogenic storage ring CSR at MPI for Nuclear Physics, Heidelberg and was compared with simulations. The predicted functional relationship of the slip factor and the horizontal tune depends on the different islands of stability, which has been experimentally verified. This behavior of the slip factor is in clear contrast to that of magnetic storage rings.
Pleasants, Elizabeth; Reddy, Krishnaveni; Atujuna, Millicent; Nakyanzi, Teopista; Chitukuta, Miria; Naidoo, Sarita; Palanee-Phillips, Thesla; Baeten, Jared M.; Montgomery, Elizabeth T.
2018-01-01
Vaginally-inserted HIV prevention methods have been reported to impact the sexual experience for women and their partners, and hence impacts acceptability of and adherence to the method. We analyzed in-depth interviews and focus group discussions about participants’ sexual experiences while wearing the ring, collected during the MTN-020/ASPIRE phase 3 safety and effectiveness trial of a dapivirine vaginal ring for HIV prevention in Malawi, South Africa, Uganda, and Zimbabwe. Most women reported that partners did not feel the ring during sex, however, women felt they had to manage their partners’ interaction with or reaction to the ring. In maintaining positive relationships, women were concerned about partners’ discovering ring use and about ensuring that partners had a good sexual experience with them. Finally women were concerned about how they themselves experienced sex with the ring. Some found that the ring made the vaginal environment more desirable for their partners and themselves. PMID:29151197
Laborde, Nicole D; Pleasants, Elizabeth; Reddy, Krishnaveni; Atujuna, Millicent; Nakyanzi, Teopista; Chitukuta, Miria; Naidoo, Sarita; Palanee-Phillips, Thesla; Baeten, Jared M; Montgomery, Elizabeth T
2018-02-01
Vaginally-inserted HIV prevention methods have been reported to impact the sexual experience for women and their partners, and hence impacts acceptability of and adherence to the method. We analyzed in-depth interviews and focus group discussions about participants' sexual experiences while wearing the ring, collected during the MTN-020/ASPIRE phase 3 safety and effectiveness trial of a dapivirine vaginal ring for HIV prevention in Malawi, South Africa, Uganda, and Zimbabwe. Most women reported that partners did not feel the ring during sex, however, women felt they had to manage their partners' interaction with or reaction to the ring. In maintaining positive relationships, women were concerned about partners' discovering ring use and about ensuring that partners had a good sexual experience with them. Finally women were concerned about how they themselves experienced sex with the ring. Some found that the ring made the vaginal environment more desirable for their partners and themselves.
Sub-keV ring current ions as the tracer of substorm injection
NASA Astrophysics Data System (ADS)
Yamauchi, M.; Lundin, R.
2006-03-01
The dynamics of the energy-latitude dispersed sub-keV trapped ions inside the ring current region, the so-called wedge-like dispersions structure, were statistically studied using Viking satellite data. Probabilities with/without these signatures at various local times in the dayside are obtained in terms of different time-lags from the substorm activity monitored by the AE index. The structure appears in the early morning sector within a few hours after the substorm, and it slowly propagates eastward while decaying with a time scale of several hours. The result qualitatively confirmed the previous model that the wedge-like dispersions are originated from past substorm-related plasma injections into the nightside ring current region, and that the dispersion is formed when these injected plasma slowly moves eastward to the dayside by the drift motion (E×B (eastward), grad-<|B| (westward), and curvature (westward) drifts). However, the appearance of the structure is twice or three times faster than the model prediction, and some structure reaches even to the evening sector. The results indicate that the start location of the drift is not as far as midnight and that the drift speed is slightly faster than the model prediction. The former means that the substorm-related increase of hot plasma in the ring current region shifts or extends to the early morning sector for large substorms, and the latter means that the substantial electric field driving the sub-keV ion drift is slightly different from the model field. We also detected the evacuating effect starting right after the substorm (or storm) onset. The electric field imposed in the dayside magnetosphere seems to remove the remainder of trapped ions.
Some experiments with the tunnel probe in a low temperature magnetized plasma
NASA Astrophysics Data System (ADS)
Kovačič, J.; Gyergyek, T.; Kavaš, B.; Vodnik, M.; Kavčič, J.; Gunn, J. P.
2018-02-01
Experiments were performed using a Tunnel Probe (TP) inside the weakly-ionised plasma of the Linear Magnetized Plasma Device (LMPD). The TP is designed as a concave probe, which should annihilate the problem of sheath expansion in the ion branch of the I-V characteristic. As the ion saturation current is consequently well defined, the ion parallel current and plasma density can be more accurately calculated. Furthermore the ratio between the ion saturation currents on the two collectors (tunnel ring and the back-plate) can be used to derive the electron temperature. The TP has been repeatedly used with success on the former Castor and Tore-Supra tokamaks and will be used on the upgraded version of Tore-supra, namely the WEST tokamak, as well [1, 2]. It was however never used successfully in a low-temperature plasma. We studied the feasibility of the TP use in a low-temperature plasma for direct measurements of plasma temperature and density. The various probe characteristic dimensions, such as the distance between the two collectors, the aperture size and the probe radius were varied to see influence of the individual probe feature. We also varied the level of magnetization of the charged particle species, the background gas pressure (which influences the electron energy distribution function), the plasma density (important for the ratio between the λ D and the ion Larmor radius). The sensitivity of the probe alignment to the magnetic field lines was also studied. We found, that the ion saturation current does not necessarily saturate and that the probe works according to expectations only in a limited amount of regimes.
NASA Technical Reports Server (NTRS)
Fok, Mei-Ching; Chen, Sheng-Hsien; Buzulukova, Natalia; Glocer, Alex
2010-01-01
Distinctive sources of ions reside in the plasmasphere, plasmasheet, and ring current regions at discrete energies constitute the major plasma populations in the inner/middle magnetosphere. They contribute to the electrodynamics of the ionosphere-magnetosphere system as important carriers of the global current system, in triggering; geomagnetic storm and substorms, as well as critical components of plasma instabilities such as reconnection and Kelvin-Helmholtz instability at the magnetospheric boundaries. Our preliminary analysis of in-situ measurements shoves the complexity of the plasmas pitch angle distributions at particularly the cold and warm plasmas, vary dramatically at different local times and radial distances from the Earth in response to changes in solar wind condition and Dst index. Using an MHD-ring current coupled code, we model the convection and interaction of cold, warm and energetic ions of plasmaspheric, plasmasheet, and ring current origins in the inner magnetosphere. We compare our simulation results with in-situ and remotely sensed measurements from recent instrumentation on Geotail, Cluster, THEMIS, and TWINS spacecraft.
Polyazulene based materials for heavy metal ions detection
NASA Astrophysics Data System (ADS)
Oprisanu, A.; Ungureanu, E. M.; Isopescu, R.; Birzan, L.; Mihai, M.; Vasiliu, C.
2017-06-01
Azulene is a special monomer used to functionalize electrodes, due to its spontaneous electron drift from the seven-membered ring to the five-membered ring. The seven-membered ring of the molecule may act as electron acceptor, while the five-membered ring - as electron donor. This leads to very attractive properties for the synthesis of functional advanced materials like: materials with nonlinear optical and photorefractive properties, cathode materials for lithium batteries, or light emitting diodes based on organic materials. Azulene derivatives have been used rarely to the metal ions electroanalysis. Our study concerns the synthesis and electrochemical characterization of a new azulene based monomer 4-(azulen-1-yl)-2,6-bis((E)-2-(thiophen-3-yl)vinyl)pyridine (L). L has been used to obtain modified electrodes by electrochemical polymerization. PolyL films modified electrodes have been characterized by cyclic voltammetry in ferrocene solutions. The complexing properties of polyL based functional materials have been investigated towards heavy metals (Pb, Cd Hg, Cu) by preconcentration - anodic stripping technique in order to analyze the content of these cations from water samples.
NASA Astrophysics Data System (ADS)
Chen, R. J.; Wang, M.; Yan, X. L.; Yang, Q.; Lam, Y. H.; Yang, L.; Zhang, Y. H.
2017-12-01
The periodic signals tracking algorithm has been used to determine the revolution times of ions stored in storage rings in isochronous mass spectrometry (IMS) experiments. It has been a challenge to perform real-time data analysis by using the periodic signals tracking algorithm in the IMS experiments. In this paper, a parallelization scheme of the periodic signals tracking algorithm is introduced and a new program is developed. The computing time of data analysis can be reduced by a factor of ∼71 and of ∼346 by using our new program on Tesla C1060 GPU and Tesla K20c GPU, compared to using old program on Xeon E5540 CPU. We succeed in performing real-time data analysis for the IMS experiments by using the new program on Tesla K20c GPU.
Vongboot, Monnapat; Suesoonthon, Monrudee
2015-01-01
Polyurethane foam (PUF) mini-column was used to eliminate copper and iron for the determination of nickel in pierced rings. The PUF mini-column was connected to FIA system for on-line sorption of copper and iron in complexes form of CuSCN(+) and FeSCN(2+). For this season, the acid solution containing a mixture of Ni(II), Fe(III), Cu(II) and SCN(-) ions was firstly flew into the PUF column. Then, the percolated solution which Fe(III) and Cu(II) ions is separated from analysis was injected into FIA system to react with 4-(2-pyridylazo) resorcinol (PAR) reagent in basic condition which this method is called pH gradient technique. The Ni-PAR complexes obtained were measured theirs absorbance at 500 nm by UV visible spectrophotometer. In this study, it was found that Cu(II) and Fe(III) were completely to form complexes with 400 mmol/L KSCN and entirely to eliminate in acidic condition at pH 3.0. In the optimum condition of these experiments, the method provided the linear relationship between absorbance and the concentration of Ni(II) in the range from 5.00 to 30.00 mg/L. Linear equation is y=0.0134x+0.0033 (R(2)=0.9948). Precision, assessed in the term of the relative standard deviation, RSD, and accuracy for multiple determinations obtained in values of 0.77-1.73% and 97.4%, respectively. The level of an average amount of Ni(II) in six piercing rings was evaluated to be 14.78 mg/g. Copyright © 2014 Elsevier B.V. All rights reserved.
Nanograin Density Outside Saturn’s A Ring
NASA Astrophysics Data System (ADS)
Johnson, Robert E.; Tseng, Wei-Ling; Elrod, M. K.; Persoon, A. M.
2017-01-01
The observed disparity between the radial dependence of the ion and electron densities measured by the Cassini plasma (CAPS) and radio (RPWS) science instruments are used to show that the region between the outer edge of Saturn’s main rings and its tenuous G ring is permeated with small charged grains (nanograins). These grains emanate from the edge of the A ring and from the tenuous F and G rings. This is a region of Saturn’s magnetosphere that is relatively unexplored, but will be a focus of Cassini’s F ring orbits prior to the end of mission in 2017 September. Confirmation of the grain densities predicted here will enhance our ability to describe the formation and destruction of material in this important region of Saturn’s magnetosphere.
FIBER AND INTEGRATED OPTICS: Integrated optical passive ring resonator for optical gyroscopes
NASA Astrophysics Data System (ADS)
Baĭborodin, Yu V.; Dyadin, S. S.; Lyadenko, A. F.; Mashchenko, A. I.; Ul'yanov, I. A.; Fatin, Yu L.
1992-02-01
A passive ring resonator based on channel waveguides, formed in a K8 glass substrate by diffusion ion exchange in molten potassium nitrate, was made and investigated. The waveguide structure of the resonator included a ring waveguide as well as two Y-type couplers, whose symmetric arms were coupled to the ring waveguide, whereas homogeneous arms were coupled to an external laser and a photodetector. The coupling of the external devices to the channel waveguides was implemented by prisms and butt (end face) contacts. The transfer function of the ring resonator was determined experimentally in order to illustrate its resonant properties and sharpness. Estimates were obtained of the ultimate sensitivity of an optical gyroscope utilizing a ring resonator with the properties described above and ways of improving this sensitivity were analyzed.
NANOGRAIN DENSITY OUTSIDE SATURN’S A RING
DOE Office of Scientific and Technical Information (OSTI.GOV)
Johnson, Robert E.; Tseng, Wei-Ling; Elrod, M. K.
The observed disparity between the radial dependence of the ion and electron densities measured by the Cassini plasma (CAPS) and radio (RPWS) science instruments are used to show that the region between the outer edge of Saturn’s main rings and its tenuous G ring is permeated with small charged grains (nanograins). These grains emanate from the edge of the A ring and from the tenuous F and G rings. This is a region of Saturn’s magnetosphere that is relatively unexplored, but will be a focus of Cassini ’s F ring orbits prior to the end of mission in 2017 September.more » Confirmation of the grain densities predicted here will enhance our ability to describe the formation and destruction of material in this important region of Saturn’s magnetosphere.« less
NASA Technical Reports Server (NTRS)
Foster, John (Inventor); Patterson, Michael (Inventor)
2008-01-01
An all permanent magnet Electron Cyclotron Resonance, large diameter (e.g., 40 cm) plasma source suitable for ion/plasma processing or electric propulsion, is capable of producing uniform ion current densities at its exit plane at very low power (e.g., below 200 W), and is electrodeless to avoid sputtering or contamination issues. Microwave input power is efficiently coupled with an ionizing gas without using a dielectric microwave window and without developing a throat plasma by providing a ferromagnetic cylindrical chamber wall with a conical end narrowing to an axial entrance hole for microwaves supplied on-axis from an open-ended waveguide. Permanent magnet rings are attached inside the wall with alternating polarities against the wall. An entrance magnet ring surrounding the entrance hole has a ferromagnetic pole piece that extends into the chamber from the entrance hole to a continuing second face that extends radially across an inner pole of the entrance magnet ring.
Cesium injection system for negative ion duoplasmatrons
Kobayashi, Maasaki; Prelec, Krsto; Sluyters, Theodorus J
1978-01-01
Longitudinally extending, foraminous cartridge means having a cylindrical side wall forming one flat, circular, tip end surface and an opposite end; an open-ended cavity, and uniformly spaced orifices for venting the cavity through the side wall in the annulus of a plasma ring for uniformly ejecting cesium for coating the flat, circular, surface. To this end, the cavity is filled with a cesium containing substance and attached to a heater in a hollow-discharge duoplasmatron. By coating the flat circular surface with a uniform monolayer of cesium and locating it in an electrical potential well at the end of a hollow-discharge, ion duoplasmatron source of an annular hydrogen plasma ring, the negative hydrogen production from the duoplasmatron is increased. The negative hydrogen is produced on the flat surface of the cartridge and extracted by the electrical potential well along a trajectory coaxial with the axis of the plasma ring.
TRANSIENT BEAM LOADING EFFECTS IN RF SYSTEMS IN JLEIC
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wang, Haipeng; Guo, Jiquan; Rimmer, Robert A.
2016-05-01
The pulsed electron bunch trains generated from the Continuous Electron Beam Accelerator Facility (CEBAF) linac to inject into the proposed Jefferson Lab Electron Ion Collider (JLEIC) e-ring will produce transient beam loading effects in the Superconducting Radio Frequency (SRF) systems that, if not mitigated, could cause unacceptably large beam energy deviation in the injection capture, or exceed the energy acceptance of CEBAF’s recirculating arcs. In the electron storage ring, the beam abort or ion clearing gaps or uneven bucket filling can cause large beam phase transients in the (S)RF cavity control systems and even beam loss due to Robinson instability.more » We have first analysed the beam stability criteria in steady state and estimated the transient effect in Feedforward and Feedback RF controls. Initial analytical models for these effects are shown for the design of the JLEIC e-ring from 3GeV to 12GeV.« less
Mass spectrometry of acoustically levitated droplets.
Westphall, Michael S; Jorabchi, Kaveh; Smith, Lloyd M
2008-08-01
Containerless sample handling techniques such as acoustic levitation offer potential advantages for mass spectrometry, by eliminating surfaces where undesired adsorption/desorption processes can occur. In addition, they provide a unique opportunity to study fundamental aspects of the ionization process as well as phenomena occurring at the air-droplet interface. Realizing these advantages is contingent, however, upon being able to effectively interface levitated droplets with a mass spectrometer, a challenging task that is addressed in this report. We have employed a newly developed charge and matrix-assisted laser desorption/ionization (CALDI) technique to obtain mass spectra from a 5-microL acoustically levitated droplet containing peptides and an ionic matrix. A four-ring electrostatic lens is used in conjunction with a corona needle to produce bursts of corona ions and to direct those ions toward the droplet, resulting in droplet charging. Analyte ions are produced from the droplet by a 337-nm laser pulse and detected by an atmospheric sampling mass spectrometer. The ion generation and extraction cycle is repeated at 20 Hz, the maximum operating frequency of the laser employed. It is shown in delayed ion extraction experiments that both positive and negative ions are produced, behavior similar to that observed for atmospheric pressure matrix-assisted laser absorption/ionization. No ion signal is observed in the absence of droplet charging. It is likely, although not yet proven, that the role of the droplet charging is to increase the strength of the electric field at the surface of the droplet, reducing charge recombination after ion desorption.
Mass Spectrometry of Acoustically Levitated Droplets
Westphall, Michael S.; Jorabchi, Kaveh; Smith, Lloyd M.
2008-01-01
Containerless sample handling techniques such as acoustic levitation offer potential advantages for mass spectrometry, by eliminating surfaces where undesired adsorption/desorption processes can occur. In addition, they provide a unique opportunity to study fundamental aspects of the ionization process as well as phenomena occurring at the air–droplet interface. Realizing these advantages is contingent, however, upon being able to effectively interface levitated droplets with a mass spectrometer, a challenging task that is addressed in this report. We have employed a newly developed charge and matrix-assisted laser desorption/ionization (CALDI) technique to obtain mass spectra from a 5-μL acoustically levitated droplet containing peptides and an ionic matrix. A four-ring electrostatic lens is used in conjunction with a corona needle to produce bursts of corona ions and to direct those ions toward the droplet, resulting in droplet charging. Analyte ions are produced from the droplet by a 337-nm laser pulse and detected by an atmospheric sampling mass spectrometer. The ion generation and extraction cycle is repeated at 20 Hz, the maximum operating frequency of the laser employed. It is shown in delayed ion extraction experiments that both positive and negative ions are produced, behavior similar to that observed for atmospheric pressure matrix-assisted laser absorption/ionization. No ion signal is observed in the absence of droplet charging. It is likely, although not yet proven, that the role of the droplet charging is to increase the strength of the electric field at the surface of the droplet, reducing chargere combination after ion desorption. PMID:18582090
Mauk, B H
2014-01-01
Investigated here are factors that control the intensities and shapes of energetic ion spectra that make up the ring current populations of the strongly magnetized planets of the solar system, specifically those of Earth, Jupiter, Saturn, Uranus, and Neptune. Following a previous and similar comparative investigation of radiation belt electrons, we here turn our attention to ions. Specifically, we examine the possible role of the differential ion Kennel-Petschek limit, as moderated by Electromagnetic Ion Cyclotron (EMIC) waves, as a standard for comparing the most intense ion spectra within the strongly magnetized planetary magnetospheres. In carrying out this investigation, the substantial complexities engendered by the very different ion composition distributions of these diverse magnetospheres must be addressed, given that the dispersion properties of the EMIC waves are strongly determined by the ion composition of the plasmas within which the waves propagate. Chosen for comparison are the ion spectra within these systems that are the most intense observed, specifically at 100 keV and 1 MeV. We find that Earth and Jupiter are unique in having their most intense ion spectra likely limited and sculpted by the Kennel-Petschek process. The ion spectra of Saturn, Uranus, and Neptune reside far below their respective limits and are likely limited by interactions with gas and dust (Saturn) and by the absence of robust ion acceleration processes (Uranus and Neptune). Suggestions are provided for further testing the efficacy of the differential Kennel-Petschek limit for ions using the Van Allen Probes. PMID:26167438
The Warm Plasma Composition in the Inner Magnetosphere during 2012–2015
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jahn, J. M.; Goldstein, J.; Reeves, Geoffrey D.
Ionospheric heavy ions play an important role in the dynamics of Earth's magnetosphere. The greater mass and gyro radius of ionospheric oxygen differentiates its behavior from protons at the same energies. Oxygen may have an impact on tail reconnection processes, and it can at least temporarily dominate the energy content of the ring current during geomagnetic storms. At sub-keV energies, multi-species ion populations in the inner magnetosphere form the warm plasma cloak, occupying the energy range between the plasmasphere and the ring current. Lastly, cold lighter ions from the mid-latitude ionosphere create the co-rotating plasmasphere whose outer regions can interactmore » with the plasma cloak, plasma sheet, ring current, and outer electron belt. Here in this paper we present a statistical view of warm, cloak-like ion populations in the inner magnetosphere, contrasting in particular the warm plasma composition during quiet and active times. We study the relative abundances and absolute densities of warm plasma measured by the Van Allen Probes, whose two spacecraft cover the inner magnetosphere from plasmaspheric altitudes close to Earth to just inside geostationary orbit. We observe that warm (>30 eV) oxygen is most abundant closer to the plasmasphere boundary whereas warm hydrogen dominates closer to geostationary orbit. Warm helium is usually a minor constituent, but shows a noticeable enhancement in the near-Earth dusk sector.« less
The Warm Plasma Composition in the Inner Magnetosphere during 2012–2015
Jahn, J. M.; Goldstein, J.; Reeves, Geoffrey D.; ...
2017-09-11
Ionospheric heavy ions play an important role in the dynamics of Earth's magnetosphere. The greater mass and gyro radius of ionospheric oxygen differentiates its behavior from protons at the same energies. Oxygen may have an impact on tail reconnection processes, and it can at least temporarily dominate the energy content of the ring current during geomagnetic storms. At sub-keV energies, multi-species ion populations in the inner magnetosphere form the warm plasma cloak, occupying the energy range between the plasmasphere and the ring current. Lastly, cold lighter ions from the mid-latitude ionosphere create the co-rotating plasmasphere whose outer regions can interactmore » with the plasma cloak, plasma sheet, ring current, and outer electron belt. Here in this paper we present a statistical view of warm, cloak-like ion populations in the inner magnetosphere, contrasting in particular the warm plasma composition during quiet and active times. We study the relative abundances and absolute densities of warm plasma measured by the Van Allen Probes, whose two spacecraft cover the inner magnetosphere from plasmaspheric altitudes close to Earth to just inside geostationary orbit. We observe that warm (>30 eV) oxygen is most abundant closer to the plasmasphere boundary whereas warm hydrogen dominates closer to geostationary orbit. Warm helium is usually a minor constituent, but shows a noticeable enhancement in the near-Earth dusk sector.« less
Contractile effect of the aqueous extract of Psidium guajava leaves on aortic rings in rat.
Olatunji-Bello, I I; Odusanya, A J; Raji, I; Ladipo, C O
2007-04-01
Aqueous leaves extract of Psidium guajava significantly and dose-dependently (0.25-2 mg/ml) contracted aorta rings. The effect was evaluated also in presence of nifedipine and phentolamine. The sensitivity of the aortic rings to cumulative doses of P. guajava was significantly enhanced in the presence of phentolamine suggesting that the effect of P. guajava was to a large extent mediated by activation of alpha-adrenoceptor and to a lesser extent by acting via calcium ion channel.
Abad-García, Beatriz; Garmón-Lobato, Sergio; Berrueta, Luis A; Gallo, Blanca; Vicente, Francisca
2009-09-01
A mass spectrometric method using electrospray ionization with triple quadrupole and quadrupole time-of-flight hybrid (Q-Tof) mass spectrometry has been applied to the structural characterization of dihydroflavonols. This family of compounds has been studied by liquid chromatography/tandem mass spectrometry (LC/MS/MS) for the first time in this work. A comprehensive study of the product ion MS spectra of the [M+H](+) ion of a commercially available standard has been performed. The most useful fragmentations in terms of structural identification are those that involve cleavage of the C-ring, resulting in diagnostic ions of dihydroflavonol family: (1,3)A(0) (+), (1,2)B(0) (+), (1,2)B(0) (+)-CO, (0,2)A(0) (+), (0,2)A(0) (+)-H(2)O, (0,2)A(0) (+)-CO, and (0,2)A(0) (+)-H(2)O-CO, that allow the characterization of the substituents in the A- and B-rings. In addition to those ions, other product ions due to losses of H(2)O and CO molecules from the Y(0) (+) ion were observed. Their fragmentation mechanisms and ion structures have been proposed. The established fragmentation patterns have been used to successfully identity three dihydroflavonols found in tangerine juices for the first time. Copyright (c) 2009 John Wiley & Sons, Ltd.
NASA Technical Reports Server (NTRS)
Khazanov, G. V.; Gamayunov, K. V.; Gallagher, D. L.; Kozyra, J. U.; Liemohn, M. W.
2006-01-01
The self-consistent treatment of the RC ion dynamics and EMlC waves, which are thought to exert important influences on the ion dynamical evolution, is an important missing element in our understanding of the storm-and recovery-time ring current evolution. Under certain conditions, relativistic electrons, with energies greater than or equal to 1 MeV, can be removed from the outer radiation belt by EMlC wave scattering during a magnetic storm (Summers and Thorne, 2003; Albert, 2003). That is why the modeling of EMlC waves is critical and timely issue in magnetospheric physics. This study will generalize the self-consistent theoretical description of RC ions and EMlC waves that has been developed by Khazanov et al. [2002, 2003] and include the heavy ions and propagation effects of EMlC waves in the global dynamic of self-consistent RC - EMlC waves coupling. The results of our newly developed model that will be presented at Huntsville 2006 meeting, focusing mainly on the dynamic of EMlC waves and comparison of these results with the previous global RC modeling studies devoted to EMlC waves formation. We also discuss RC ion precipitations and wave induced thermal electron fluxes into the ionosphere.
INJECTION OPTICS FOR THE JLEIC ION COLLIDER RING
DOE Office of Scientific and Technical Information (OSTI.GOV)
Morozov, Vasiliy; Derbenev, Yaroslav; Lin, Fanglei
2016-05-01
The Jefferson Lab Electron-Ion Collider (JLEIC) will accelerate protons and ions from 8 GeV to 100 GeV. A very low beta function at the Interaction Point (IP) is needed to achieve the required luminosity. One consequence of the low beta optics is that the beta function in the final focusing (FF) quadrupoles is extremely high. This leads to a large beam size in these magnets as well as strong sensitivity to errors which limits the dynamic aperture. These effects are stronger at injection energy where the beam size is maximum, and therefore very large aperture FF magnets are required tomore » allow a large dynamic aperture. A standard solution is a relaxed injection optics with IP beta function large enough to provide a reasonable FF aperture. This also reduces the effects of FF errors resulting in a larger dynamic aperture at injection. We describe the ion ring injection optics design as well as a beta-squeeze transition from the injection to collision optics.« less
NASA Technical Reports Server (NTRS)
Gamayunov, K. V.; Khazanov, G. V.; Liemohn, M. W.; Fok, M.-C.; Ridley, A. J.
2009-01-01
Further development of our self-consistent model of interacting ring current (RC) ions and electromagnetic ion cyclotron (EMIC) waves is presented. This model incorporates large scale magnetosphere-ionosphere coupling and treats self-consistently not only EMIC waves and RC ions, but also the magnetospheric electric field, RC, and plasmasphere. Initial simulations indicate that the region beyond geostationary orbit should be included in the simulation of the magnetosphere-ionosphere coupling. Additionally, a self-consistent description, based on first principles, of the ionospheric conductance is required. These initial simulations further show that in order to model the EMIC wave distribution and wave spectral properties accurately, the plasmasphere should also be simulated self-consistently, since its fine structure requires as much care as that of the RC. Finally, an effect of the finite time needed to reestablish a new potential pattern throughout the ionosphere and to communicate between the ionosphere and the equatorial magnetosphere cannot be ignored.
NASA Astrophysics Data System (ADS)
Tanabe, Hiroshi; Koike, Hideya; Hatano, Hironori; Hayashi, Takumi; Cao, Qinghong; Himeno, Shunichi; Kaneda, Taishi; Akimitsu, Moe; Sawada, Asuka; Ono, Yasushi
2017-10-01
A new type of high-throughput/high-resolution 96CH ion Doppler tomography diagnostics has been developed using ``multi-slit'' spectroscopy technique for detailed investigation of fine structure formation during high guide field magnetic reconnection. In the last three years, high field merging experiment in MAST pioneered new frontiers of reconnection heating: formation of highly peaked structure around X-point in high guide field condition (Bt > 0.3 T), outflow dissipation under the influence of better plasma confinement to form high temperature ring structure which aligns with closed flux surface of toroidal plasma, and interaction between ion and electron temperature profile during transport/confinement phase to form triple peak structure (τeiE 4 ms). To investigate more detailed mechanism with in-situ magnetic measurement, the university of Tokyo starts the upgrade of plasma parameters and spatial resolution of optical diagnostics as in MAST. Now, a new type of high-throughput/high-resolution 96CH ion Doppler tomography diagnostics system construction has been completed and it successfully resolved fine structure of ion heating downstream, aligned with closed flux surface formed by reconnected field. This work was supported by JSPS KAKENHI Grant Numbers 15H05750, 15K14279 and 17H04863.
OPENMED: A facility for biomedical experiments based on the CERN Low Energy Ion Ring (LEIR)
NASA Astrophysics Data System (ADS)
Carli, Christian
At present protons and carbon ions are in clinical use for hadron therapy at a growing number of treatment centers all over the world. Nevertheless, only limited direct clinical evidence of their superiority over other forms of radiotherapy is available [1]. Furthermore fundamental studies on biological effects of hadron beams have been carried out at different times (some a long time ago) in different laboratories and under different conditions. Despite an increased availability of ion beams for hadron therapy, beam time for preclinical studies is expected to remain insufficient as the priority for therapy centers is to treat the maximum number of patients. Most of the remaining beam time is expected to be required for setting up and measurements to guarantee appropriate good quality beams for treatments. The proposed facility for biomedical research [2] in support of hadron therapy centers would provide ion beams for interested research groups and allow them to carry out basic studies under well defined conditions. Typical studies would include radiobiological phenomena like relative biological effectiveness with different energies, ion species, and intensities. Furthermore possible studies include the development of advanced dosimetry in heterogeneous materials that resemble the human body, imaging techniques and, at a later stage, when the maximum energy with the LEIR magnets can be reached, fragmentation.
Feasibility study for a biomedical experimental facility based on LEIR at CERN.
Abler, Daniel; Garonna, Adriano; Carli, Christian; Dosanjh, Manjit; Peach, Ken
2013-07-01
In light of the recent European developments in ion beam therapy, there is a strong interest from the biomedical research community to have more access to clinically relevant beams. Beamtime for pre-clinical studies is currently very limited and a new dedicated facility would allow extensive research into the radiobiological mechanisms of ion beam radiation and the development of more refined techniques of dosimetry and imaging. This basic research would support the current clinical efforts of the new treatment centres in Europe (for example HIT, CNAO and MedAustron). This paper presents first investigations on the feasibility of an experimental biomedical facility based on the CERN Low Energy Ion Ring LEIR accelerator. Such a new facility could provide beams of light ions (from protons to neon ions) in a collaborative and cost-effective way, since it would rely partly on CERN's competences and infrastructure. The main technical challenges linked to the implementation of a slow extraction scheme for LEIR and to the design of the experimental beamlines are described and first solutions presented. These include introducing new extraction septa into one of the straight sections of the synchrotron, changing the power supply configuration of the magnets, and designing a new horizontal beamline suitable for clinical beam energies, and a low-energy vertical beamline for particular radiobiological experiments.
Feasibility study for a biomedical experimental facility based on LEIR at CERN
Abler, Daniel; Garonna, Adriano; Carli, Christian; Dosanjh, Manjit; Peach, Ken
2013-01-01
In light of the recent European developments in ion beam therapy, there is a strong interest from the biomedical research community to have more access to clinically relevant beams. Beamtime for pre-clinical studies is currently very limited and a new dedicated facility would allow extensive research into the radiobiological mechanisms of ion beam radiation and the development of more refined techniques of dosimetry and imaging. This basic research would support the current clinical efforts of the new treatment centres in Europe (for example HIT, CNAO and MedAustron). This paper presents first investigations on the feasibility of an experimental biomedical facility based on the CERN Low Energy Ion Ring LEIR accelerator. Such a new facility could provide beams of light ions (from protons to neon ions) in a collaborative and cost-effective way, since it would rely partly on CERN's competences and infrastructure. The main technical challenges linked to the implementation of a slow extraction scheme for LEIR and to the design of the experimental beamlines are described and first solutions presented. These include introducing new extraction septa into one of the straight sections of the synchrotron, changing the power supply configuration of the magnets, and designing a new horizontal beamline suitable for clinical beam energies, and a low-energy vertical beamline for particular radiobiological experiments. PMID:23824122
STORAGE RING CROSS SECTION MEASUREMENTS FOR ELECTRON IMPACT IONIZATION OF Fe{sup 7+}
DOE Office of Scientific and Technical Information (OSTI.GOV)
Hahn, M.; Novotný, O.; Savin, D. W.
2015-11-01
We have measured electron impact ionization for Fe{sup 7+} from the ionization threshold up to 1200 eV. The measurements were performed using the TSR heavy ion storage ring. The ions were stored long enough prior to measurements to remove most metastables, resulting in a beam of 94% ground-level ions. Comparing with the previously recommended atomic data, we find that the Arnaud and Raymond cross section is up to about 40% larger than our measurement, with the largest discrepancies below about 400 eV. The cross section of Dere agrees to within 10%, which is about the magnitude of the experimental uncertainties.more » The remaining discrepancies between our measurement and the Dere calculations are likely due to shortcomings in the theoretical treatment of the excitation-autoionization contribution.« less
Bäckström, E; Hanstorp, D; Hole, O M; Kaminska, M; Nascimento, R F; Blom, M; Björkhage, M; Källberg, A; Löfgren, P; Reinhed, P; Rosén, S; Simonsson, A; Thomas, R D; Mannervik, S; Schmidt, H T; Cederquist, H
2015-04-10
We use a novel electrostatic ion storage ring to measure the radiative lifetime of the upper level in the 3p^{5} ^{2}P_{1/2}^{o}→3p^{5} ^{2}P_{3/2}^{o} spontaneous radiative decay in ^{32}S^{-} to be 503±54 sec. This is by orders of magnitude the longest lifetime ever measured in a negatively charged ion. Cryogenic cooling of the storage ring gives a residual-gas pressure of a few times 10^{-14} mbar at 13 K and storage of 10 keV sulfur anions for more than an hour. Our experimental results differ by 1.3σ from the only available theoretical prediction [P. Andersson et al., Phys. Rev. A 73, 032705 (2006)].
The magnet system of the Relativistic Heavy Ion Collider (RHIC)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Greene, A.; Anerella, M.; Cozzolino, J.
1995-07-01
The Relativistic Heavy Ion Collider now under construction at Brookhaven National Laboratory (BNL) is a colliding ring accelerator to be completed in 1999. Through collisions of heavy ions it is hoped to observe the creation of matter at extremely high temperatures and densities, similar to what may have occurred in the original ``Big Bang.`` The collider rings will consist of 1740 superconducting magnet elements. Some of elements are being manufactured by industrial partners (Northrop Grumman and Everson Electric). Others are being constructed or assembled at BNL. A description is given of the magnet designs, the plan for manufacturing and testmore » results. In the manufacturing of the magnets, emphasis has been placed on uniformity of their performance and on quality. Results so far indicate that this emphasis has been very successful.« less
The magnet system of the Relativistic Heavy Ion Collider (RHIC)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Greene, A.; Anerella, M.; Cozzolino, J.
1996-07-01
The Relativistic Heavy Ion Collider now under construction at Brookhaven National Laboratory (BNL) is a colliding ring accelerator to be completed in 1999. Through collisions of heavy ions it is hoped to observe the creation of matter at extremely high temperatures and densities, similar to what may have occurred in the original ``Big Bang``. The collider rings will consist of 1,740 superconducting magnet elements. Some of these elements are being manufactured by industrial partners (Northrop Grumman and Everson Electric). Others are being constructed or assembled at BNL. A description is given of the magnet designs, the plan for manufacturing andmore » test results. In the manufacturing of the magnets, emphasis has been placed on uniformity of their performance and on quality. Results so far indicate that this emphasis has been very successful.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Barc, B.; Ryszka, M.; Spurrell, J.
Multi-photon ionization (MPI) of the RNA base uracil has been studied in the wavelength range 220–270 nm, coinciding with excitation to the S{sub 2}(ππ*) state. A fragment ion at m/z = 84 was produced by 2-photon absorption at wavelengths ≤232 nm and assigned to C{sub 3}H{sub 4}N{sub 2}O{sup +} following CO abstraction. This ion has not been observed in alternative dissociative ionization processes (notably electron impact) and its threshold is close to recent calculations of the minimum activation energy for a ring opening conical intersection to a σ(n-π)π* closed shell state. Moreover, the predicted ring opening transition leaves a COmore » group at one end of the isomer, apparently vulnerable to abstraction. An MPI mass spectrum of uracil-water clusters is presented for the first time and compared with an equivalent dry measurement. Hydration enhances certain fragment ion pathways (particularly C{sub 3}H{sub 3}NO{sup +}) but represses C{sub 3}H{sub 4}N{sub 2}O{sup +} production. This indicates that hydrogen bonding to water stabilizes uracil with respect to neutral excited-state ring opening.« less
Particle-in-cell simulations of the lower-hybrid instability driven by an ion-ring distribution
NASA Astrophysics Data System (ADS)
Swanekamp, Stephen; Richardson, Steve; Mithaiwala, Manish; Crabtree, Chris
2013-10-01
Fully electromagnetic particle-in-cell simulations of the excitation of the lower-hybrid mode in a plasma driven by an ion-ring distribution using the Lsp code are presented. At early times the simulations agree with linear theory. The resulting wave evolution and non-linear plasma and ring-ion heating are compared with theoretical models [Mithaiwala et al. 2010; Crabtree et al., this meeting] and previous simulation results [Winske and Daughton, 2012]. 2D simulations show that when the magnetic field is perpendicular to the wave vector, k, the electrostatic potential fluctuations work in conjunction with the applied magnetic field causing a circular electron E ×B drift around a positively charged center. Similar phenomena are observed in 2D simulations of magnetic-field penetration into a spatially inhomogeneous unmagnetized plasma [Richardson et al., this meeting] where circular paramagnetic vortices are formed. These vortices are altered by the addition of a small, in-plane, component of magnetic field which allows electrons to stream along field lines effectively shorting out one component of the electric field. In this case, the vortex structures are no longer circular but elongated along the direction of the in-plane magnetic field component.
Energy spectra of quantum rings.
Fuhrer, A; Lüscher, S; Ihn, T; Heinzel, T; Ensslin, K; Wegscheider, W; Bichler, M
2001-10-25
Quantum mechanical experiments in ring geometries have long fascinated physicists. Open rings connected to leads, for example, allow the observation of the Aharonov-Bohm effect, one of the best examples of quantum mechanical phase coherence. The phase coherence of electrons travelling through a quantum dot embedded in one arm of an open ring has also been demonstrated. The energy spectra of closed rings have only recently been studied by optical spectroscopy. The prediction that they allow persistent current has been explored in various experiments. Here we report magnetotransport experiments on closed rings in the Coulomb blockade regime. Our experiments show that a microscopic understanding of energy levels, so far limited to few-electron quantum dots, can be extended to a many-electron system. A semiclassical interpretation of our results indicates that electron motion in the rings is governed by regular rather than chaotic motion, an unexplored regime in many-electron quantum dots. This opens a way to experiments where even more complex structures can be investigated at a quantum mechanical level.
Linking heterometallic rings for quantum information processing and amusement.
Timco, Grigore A; Faust, Thomas B; Tuna, Floriana; Winpenny, Richard E P
2011-06-01
Linking polymetallic cages can be a method for creating new structures and new properties. In this tutorial review we use heterometallic anti-ferromagnetically coupled rings (AF-rings) as exemplars for three approaches that can be used to link cage compounds. The first of three routes involves an ion-pair interaction supported by hydrogen-bonding interactions, which allows the synthesis of hybrid rotaxanes among other materials. The second route involves functionalising the exterior of the AF-ring so that it will act as a Lewis base; complexes involving coordination of pyridine to bridging monometallic and dimetallic fragments are discussed. The third route involves creating a vacancy on one site of the AF-ring, and then using the ring as a Lewis acid. Di-imine ligands can then be used to link the AF-rings into dimers. A brief discussion of the physical properties of these systems is also included.
Mercury ion thruster technology
NASA Technical Reports Server (NTRS)
Beattie, J. R.; Matossian, J. N.
1989-01-01
The Mercury Ion Thruster Technology program was an investigation for improving the understanding of state-of-the-art mercury ion thrusters. Emphasis was placed on optimizing the performance and simplifying the design of the 30 cm diameter ring-cusp discharge chamber. Thruster performance was improved considerably; the baseline beam-ion production cost of the optimized configuration was reduced to Epsilon (sub i) perspective to 130 eV/ion. At a discharge propellant-utilization efficiency of 95 percent, the beam-ion production cost was reduced to about 155 eV/ion, representing a reduction of about 40 eV/ion over the corresponding value for the 30 cm diameter J-series thruster. Comprehensive Langmuir-probe surveys were obtained and compared with similar measurements for a J-series thruster. A successful volume-averaging scheme was developed to correlate thruster performance with the dominant plasma processes that prevail in the two thruster designs. The average Maxwellian electron temperature in the optimized ring-cusp design is as much as 1 eV higher than it is in the J-series thruster. Advances in ion-extraction electrode fabrication technology were made by improving materials selection criteria, hydroforming and stress-relieving tooling, and fabrications procedures. An ion-extraction performance study was conducted to assess the effect of screen aperture size on ion-optics performance and to verify the effectiveness of a beam-vectoring model for three-grid ion optics. An assessment of the technology readiness of the J-series thruster was completed, and operation of an 8 cm IAPS thruster using a simplified power processor was demonstrated.
Chen, Kewei; Ríos, José Julián; Roca, María; Pérez-Gálvez, Antonio
2015-09-18
Dephytylated chlorophylls (chlorophyllides and pheophorbides) are the starting point of the chlorophyll catabolism in green tissues, components of the chlorophyll pattern in storage/processed food vegetables, as well as the favoured structural arrangement for chlorophyll absorption. In addition, dephytylated native chlorophylls are prone to several modifications of their structure yielding pyro-, 13(2)-hydroxy- and 15(1)-hydroxy-lactone derivatives. Despite of these outstanding remarks only few of them have been analysed by MS(n). Besides new protocols for obtaining standards, we have developed a new high throughput methodology able to determine the fragmentation pathway of 16 dephytylated chlorophyll derivatives, elucidating the structures of the new product ions and new mechanisms of fragmentation. The new methodology combines, by first time, high resolution time-of-flight mass spectrometry and powerful post-processing software. Native chlorophyllides and pheophorbides mainly exhibit product ions that involve the fragmentation of D ring, as well as additional exclusive product ions. The introduction of an oxygenated function at E ring enhances the progress of fragmentation reactions through the β-keto ester group, developing also exclusive product ions for 13(2)-hydroxy derivatives and for 15(1)-hydroxy-lactone ones. Consequently, while MS(2)-based reactions of phytylated chlorophyll derivatives point to fragmentations at the phytyl and propionic chains, dephytylated chlorophyll derivatives behave different as the absence of phytyl makes β-keto ester group and E ring more prone to fragmentation. Proposals of the key reaction mechanisms underlying the origin of new product ions have been made. Copyright © 2015 Elsevier B.V. All rights reserved.
The c15 ring of the Spirulina platensis F-ATP synthase: F1/F0 symmetry mismatch is not obligatory
Pogoryelov, Denys; Yu, Jinshu; Meier, Thomas; Vonck, Janet; Dimroth, Peter; Muller, Daniel J
2005-01-01
The oligomeric c ring of the F-ATP synthase from the alkaliphilic cyanobacterium Spirulina platensis was isolated and characterized. Mass spectroscopy analysis indicated a mass of 8,210 Da, reflecting that of a c monomer. The mass increased by 206 Da after treatment with the c-subunit-specific inhibitor dicyclohexylcarbodiimide (DCCD), which indicated modification of the ion-binding carboxylate by DCCD. Atomic force microscopy topographs of c rings from S. platensis showed 15 symmetrically assembled subunits. The c15-mer reported here is the largest c ring that is isolated and does not show the classical c-ring mismatch to the three-fold symmetry of the F1 domain. PMID:16170308
Brookhaven highlights, October 1978-September 1979. [October 1978 to September 1979
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
1979-01-01
These highlights present an overview of the major research and development achievements at Brookhaven National Laboratory from October 1978 to September 1979. Specific areas covered include: accelerator and high energy physics programs; high energy physics research; the AGS and improvements to the AGS; neutral beam development; heavy ion fusion; superconducting power cables; ISABELLE storage rings; the BNL Tandem accelerator; heavy ion experiments at the Tandem; the High Flux Beam Reactor; medium energy physics; nuclear theory; atomic and applied physics; solid state physics; neutron scattering studies; x-ray scattering studies; solid state theory; defects and disorder in solids; surface physics; the Nationalmore » Synchrotron Light Source ; Chemistry Department; Biology Department; Medical Department; energy sciences; environmental sciences; energy technology programs; National Center for Analysis of Energy Systems; advanced reactor systems; nuclear safety; National Nuclear Data Center; nuclear materials safeguards; Applied Mathematics Department; and support activities. (GHT)« less
NASA Technical Reports Server (NTRS)
Cladis, J. B.; Francis, W. E.
1985-01-01
The transport of ions from the polar ionosphere to the inner magnetosphere during stormtime conditions has been computed using a Monte Carlo diffusion code. The effect of the electrostatic turbulence assumed to be present during the substorm expansion phase was simulated by a process that accelerated the ions stochastically perpendicular to the magnetic field with a diffusion coefficient proportional to the energization rate of the ions by the induced electric field. This diffusion process was continued as the ions were convected from the plasma sheet boundary layer to the double-spiral injection boundary. Inward of the injection boundary, the ions were convected adiabatically. By using as input an O(+) flux of 2.8 x 10 to the 8th per sq cm per s (w greater than 10 eV) and an H(+) flux of 5.5 x 10 to the 8th per sq cm per s (w greater than 0.63 eV), the computed distribution functions of the ions in the ring current were found to be in good agreement, over a wide range in L (4 to 8), with measurements made with the ISEE-1 satellite during a storm. This O(+) flux and a large part of the H(+) flux are consistent with the DE satellite measurements of the polar ionospheric outflow during disturbed times.
Magnetic anisotropy of the antiferromagnetic ring [Cr8F8Piv16].
van Slageren, Joris; Sessoli, Roberta; Gatteschi, Dante; Smith, Andrew A; Helliwell, Madeleine; Winpenny, Richard E P; Cornia, Andrea; Barra, Anne-Laure; Jansen, Aloysius G M; Rentschler, Eva; Timco, Grigore A
2002-01-04
A new tetragonal (P42(1)2) crystalline form of [Cr8F8Piv16] (HPiv = pivalic acid, trimethyl acetic acid) is reported. The ring-shaped molecules, which are aligned in a parallel fashion in the unit cell, form almost perfectly planar, regular octagons. The interaction between the CrIII ions is antiferromagnetic (J = 12 cm(-1)) which results in a S = 0 spin ground state. The low-lying spin excited states were investigated by cantilever torque magnetometry (CTM) and high-frequency EPR (HFEPR). The compound shows hard-axis anisotropy. The axial zero-field splitting (ZFS) parameters of the first two spin excited states (S = 1 and S = 2, respectively) are D1 = 1.59(3) cm(-1) or 1.63 cm(-1) (from CTM and HFEPR, respectively) and D2 = 0.37 cm(-1) (from HFEPR). The dipolar contributions to the ZFS of the S = 1 and S = 2 spin states were calculated with the point dipolar approximation. These contributions proved to be less than the combined single-ion contributions. Angular overlap model calculations that used parameters obtained from the electronic absorption spectrum, showed that the unique axis of the single-ion ZFS is at an angle of 19.3(1) degrees with respect to the ring axis. The excellent agreement between the experimental and the theoretical results show the validity of the used methods for the analysis of the magnetic anisotropy in antiferromagnetic CrIII rings.
Loss-free method of charging accumulator rings
Maschke, Alfred W.
1979-01-01
A method for the production of high current pulses of heavy ions having an atomic weight greater than 100. Also a linear accelerator based apparatus for carrying out said method. Pulses formed by the method of the subject invention are suitable for storage in a storage ring. The accumulated pulses may be used in inertial fusion apparatus.
Experimental investigation of discharge plasma magnetic confinement in the NSTASR ion thruster
NASA Technical Reports Server (NTRS)
Sengupta, Anita; Fitzgerald, Dennis; Owens, Al
2005-01-01
Magnetic confinement studies were performed on the state-of-the-art NSTAR ion thruster. The goal of the experimental studies was determine the dependence of plasma confinement and plasma uniformity on the strength and shape of the imposed ring-cusp magnetic field.
Reainthippayasakul, W; Paosawatyanyong, B; Bhanthumnavin, W
2013-05-01
Conjugated meso-alkynyl 5,15-dimesitylporphyrin metal complexes have been synthesized by Sonogashira coupling reaction in good yields. Alkynyl groups were chosen as a link at the meso positions in order to extend the pi-conjugated length of porphyrin rings. These synthesized porphyrin derivatives were characterized by 1H NMR spectroscopy and MALDI-TOF mass spectrometry. Moreover, UV-visible spectroscopy and fluorescence spectroscopy were also used to investigate their photophysical properties. It has been demonstrated that central metal ions as well as meso substituents on porphyrin rings affected the electronic absorption and emission spectra of the compounds. Spectroscopic results revealed that alkyne-linked porphyrin metal complexes showed higher pi-conjugation compared with porphyrin building blocks resulting in red shifts in both absorption and emission spectra. Coordination properties of synthesized porphyrins were preliminarily investigated by UV-visible absorption and fluorescence emission spectroscopic titration with pyridine as axial ligand. The formation of porphyrin-pyridine complexes resulted in significant red shifts in absorption spectra and decrease of fluorescence intensity in emission spectra. Moreover, the 1H NMR titration experiments suggested that central metal ions play an important role to coordinate with pyridine and the coordination of porphyrin zinc(II) complex with pyridine occur in a 1:1 ratio. From these spectroscopic results, alkyne-linked porphyrin metal complexes offer potential applications as materials for optical organic nanosensors.
Laboratory chemistry relevant to understanding and modeling the ionosphere of Titan.
Adams, Nigel G; Mathews, L Dalila; Osborne, David
2010-01-01
Laboratory data have a dual and critical role in interpreting information obtained from the Cassini spacecraft in its passes through the Titan ionosphere. Firstly, in situ mass spectra are obtained by Cassini and their conversion into atmospheric molecular composition requires chemical modeling to create agreement between the observed mass spectra and those determined from the models. Secondly, once agreement is obtained, then the chemical model can be considered to represent the evolution of the Titan atmosphere. As a contribution to these endeavors in the past, laboratory measurements have been made in the Selected Ion Flow Tube (SIFT) of the reactions of a series of ring molecules with the important ionospheric ion CH3+. These reactions showed that a dominant reaction channel is association. In the present study, this work has been extended to reactions of another important Titan ion C3H3+. These ion-molecule reactions have also been studied at room temperature using a SIFT. Reactions have been studied in detail with benzene, toluene and pyridine and show again that association is very important. The loss of ionization in the ionosphere is then controlled by electron-ion dissociative recombination of the association ions and their progeny. The recombination reactions have been studied as a function of temperature (300 to 550 K) using a flowing afterglow. These combined data have been used to develop a subset of the chemistry and test its viability. They have indicated that association of the important Titan ions with the abundant nitrogen, followed by switching of the nitrogen for the ring compounds, can build up larger species, perhaps resulting in multi-rings. Recombination of such species can affect the ionization balance and provide species which can contribute to the parallel neutral chemistry. Species are suggested that should be looked for in the in situ mass spectra.
Abiedalla, Younis; DeRuiter, Jack; Clark, C Randall
2016-07-30
Precursor materials are available to prepare aminoketone drugs containing regioisomeric propyl and isopropyl side-chain groups related to the drug alpha-pyrrovalerone (Flakka) and MDPV (3,4-methylenedioxypyrrovalerone). These compounds yield equivalent regioisomeric iminium cation base peaks in electron ionization mass spectrometry (EI-MS). The propyl and isopropyl side-chain groups related to alpha-pyrrovalerone and MDPV were prepared and evaluated in EI-MS and tandem mass spectrometry (MS/MS) product ion experiments. Deuterium labeling in both the pyrrolidine and alkyl side-chain groups allowed for the confirmation of the structures for the major product ions formed from the regioisomeric EI-MS iminium cation base peaks. These iminium cation base peaks show characteristic product ion spectra which allow differentiation of the side-chain propyl and isopropyl groups in the structure. The n-propyl side chain containing iminium cation base peak (m/z 126) in the EI-MS spectrum yields a major product ion at m/z 84 while the regioisomeric m/z 126 base peak for the isopropyl side chain yields a characteristic product ion at m/z 70. Deuterium labeling in both the pyrrolidine ring and the alkyl side chain confirmed the process for the formation of these major product ions. Product ion fragmentation provides useful data for differentiation of n-propyl and isopropyl side-chain iminium cations from cathinone derivative drugs of abuse. Regioisomeric n-propyl and isopropyl iminium cations of equal mass yield characteristic product ions identifying the alkyl side-chain regioisomers in the pyrrolidine cathinone derivatives. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.
Space Weather Effects Produced by the Ring Current Particles
NASA Astrophysics Data System (ADS)
Ganushkina, Natalia; Jaynes, Allison; Liemohn, Michael
2017-11-01
One of the definitions of space weather describes it as the time-varying space environment that may be hazardous to technological systems in space and/or on the ground and/or endanger human health or life. The ring current has its contributions to space weather effects, both in terms of particles, ions and electrons, which constitute it, and magnetic and electric fields produced and modified by it at the ground and in space. We address the main aspects of the space weather effects from the ring current starting with brief review of ring current discovery and physical processes and the Dst-index and predictions of the ring current and storm occurrence based on it. Special attention is paid to the effects on satellites produced by the ring current electrons. The ring current is responsible for several processes in the other inner magnetosphere populations, such as the plasmasphere and radiation belts which is also described. Finally, we discuss the ring current influence on the ionosphere and the generation of geomagnetically induced currents (GIC).
Wujcik, Chad E; Kadar, Eugene P
2008-10-01
Six chromatographically resolved sulopenem prodrugs were monitored for their potential to undergo both in-source collision-induced dissociation (CID) and thermolysis. Initial Q1 scans for each prodrug revealed the formation of intense [Prodrug2 + H]+, [Prodrug2 + Na]+, [Prodrug + Na]+, and [Sulopenem + Na]+ ions. Non-adduct-associated sulopenem ([Sulopenem + H]+) along with several additional lower mass ions were also observed. Product ion scans of [Prodrug3 + Na]+ showed the retention of the sodium adduct in the collision cell continuing down to opening of the beta-lactam ring. In-source CID and temperature experiments were conducted under chromatographic conditions while monitoring several of the latter ion transitions (i.e., adducts, dimers and degradants/fragments) for a given prodrug. The resulting ion profiles indicated the regions of greatest stability for temperature and declustering potential (DP) that provided the highest signal intensity for each prodrug and minimized in-source degradation. The heightened stability of adduct ions, relative to their appropriate counterpart (i.e., dimer to dimer adduct and prodrug to prodrug adduct ions), was observed under elevated temperature and DP conditions. The addition of 100 microM sodium to the mobile phase further enhanced the formation of these more stable adduct ions, yielding an optimal [Prodrug + Na]+ ion signal at temperatures from 400 to 600 degrees C. A clinical liquid chromatography/tandem mass spectrometry (LC/MS/MS) assay for sulopenem prodrug PF-04064900 in buffered whole blood was successfully validated using sodium-fortified mobile phase and the [PF-04064900 + Na]+ ion for quantitation. A conservative five-fold increase in sensitivity from previously validated preclinical assays using the [PF-04064900 + H]+ precursor ion was achieved.
Preliminary Tests of a Paul ion Trap as an Ion Source
NASA Astrophysics Data System (ADS)
Sadat Kiai, S. M.; Zirak, A. R.; Elahi, M.; Adlparvar, S.; Mortazavi, B. N.; Safarien, A.; Farhangi, S.; Sheibani, S.; Alhooie, S.; Khalaj, M. M. A.; Dabirzadeh, A. A.; Ruzbehani, M.; Zahedi, F.
2010-10-01
The paper reports on the design and construction of a Paul ion trap as an ion source by using an impact electron ionization technique. Ions are produced in the trap and confined for the specific time which is then extracted and detected by a Faraday cup. Especial electronic configurations are employed between the end caps, ring electrodes, electron gun and a negative voltage for the detector. This configuration allows a constant low level of pure ion source between the pulsed confined ion sources. The present experimental results are based on the production and confinement of Argon ions with good stability and repeatability, but in principle, the technique can be used for various Argon like ions.
Wang, Shanshan; Dong, Cheng; Yu, Lian; Guo, Cheng; Jiang, Kezhi
2016-01-15
In the tandem mass spectrometry of protonated N-(3-phenyl-2H-chromen-2-ylidene)benzenesulfonamides, the precursor ions have been observed to undergo gas-phase dissociation via two competing channels: (a) the predominant channel involves migration of the sulfonyl cation to the phenyl C atom and the subsequent loss of benzenesulfinic acid along with cyclization reaction, and (b) the minor one involves dissociation of the precursor ion to give an ion/neutral complex of [sulfonyl cation/imine], followed by decomposition to afford sulfonyl cation or the INC-mediated electron transfer to give an imine radical cation. The proposed reaction channels have been supported by theoretical calculations and D-labeling experiments. The gas-phase cyclization reaction originating from the N- to C-sulfonyl cation transfer has been first reported to the best of our knowledge. For the substituted sulfonamides, the presence of electron-donating groups (R(2) -) at the C-ring effectively facilitates the reaction channel of cyclization reaction, whereas that of electron-withdrawing groups inhibits this pathway. Copyright © 2015 John Wiley & Sons, Ltd.
NASA Astrophysics Data System (ADS)
Peroomian, Vahé; El-Alaoui, Mostafa; Brandt, Pontus C.:son
2011-05-01
The contribution of solar wind and ionospheric ions to the ion population of the magnetotail during the 17 April 2002 geomagnetic storm was investigated by using large-scale kinetic (LSK) particle tracing calculations. We began our investigation by carrying out a global magnetohydrodynamic simulation of the storm event by using upstream solar wind and interplanetary magnetic field data from the ACE spacecraft. We launched solar wind H+ ions and ionospheric O+ ions beginning at 0900 UT, ˜2 h prior to the sudden storm commencement (SSC), until 2000 UT. We found that during this Dst ˜ -98 nT storm, solar wind ions carried the bulk of the density and energy density in the nightside ring current and plasma sheet, with the notable exception of the 90 min immediately after the SSC when O+ densities in the ring current exceeded those of H+ ions. The LSK simulation did a very good job of reproducing ion densities observed by the Los Alamos National Laboratory spacecraft at geosynchronous orbit and reproduced the changes in the inner magnetosphere and the injection of ions observed by the IMAGE spacecraft during a substorm that occurred at 1900 UT. These comparisons with observations serve to validate our results throughout the magnetotail and allow us to obtain time-dependent maps of H+ and O+ density and energy density where IMAGE cannot make measurements. In essence, this work extends the viewing window of the IMAGE spacecraft far downtail.
Injector for the University of Maryland Electron Ring (UMER)
NASA Astrophysics Data System (ADS)
Kehne, D.; Godlove, T.; Haldemann, P.; Bernal, S.; Guharay, S.; Kishek, R.; Li, Y.; O'Shea, P.; Reiser, M.; Yun, V.; Zou, Y.; Haber, I.
2001-05-01
The electron beam injector constructed by FM technologies for the University of Maryland Electron Ring (UMER) program is described. The program will use an electron beam to model space-charge-dominated ion beams in a recirculating linac for heavy ion inertial fusion, as well as for high-current muon colliders. The injector consists of a 10 keV, 100 mA electron gun with 50-100 nsec pulse width and a repetition rate of 120 Hz. The e-gun system includes a 6-mask, rotatable aperture plate, a Rogowski current monitor, an ion pump, and a gate valve. The injector beamline consists of a solenoid, a five-quadrupole matching section, two diagnostic chambers, and a fast current monitor. An independent diagnostic chamber also built for UMER will be used to measure horizontal and vertical emittance, current, energy, energy spread, and the evolution of the beam envelope and profile along the injector beamline.
NASA Astrophysics Data System (ADS)
McCarren, Dustin; Vandervort, Robert; Soderholm, Mark; Carr, Jerry, Jr.; Galante, Matthew; Magee, Richard; Scime, Earl
2013-10-01
Cavity Ring-Down Spectroscopy CRDS is a proven, ultra-sensitive, cavity enhanced absorption spectroscopy technique. When combined with a continuous wavelength (CW) diode laser that has a sufficiently narrow line width, the Doppler broadened absorption line, i.e., the velocity distribution functions (IVDFs), can be measured. Measurements of IVDFS can be made using established techniques, such as laser induced fluorescence (LIF). However, LIF suffers from the requirement that the initial state of the LIF sequence have a substantial density. This usually limits LIF to ions and atoms with large metastable state densities for the given plasma conditions. CW-CRDS is considerably more sensitive than LIF and can potentially be applied to much lower density populations of ion and atom states. In this work we present ongoing measurements of the CW-CRDS diagnostic and discuss the technical challenges of using CW-CRDS to make measurements in a helicon plasma.
Strong Pitch-Angle Diffusion of Ring Current Ions in Geomagnetic Storm-Associated Conditions
NASA Technical Reports Server (NTRS)
Khazanov, G. V.; Gamayunov, K. V.; Gallagher, D. L.; Spann, J. F.
2005-01-01
Do electromagnetic ion cyclotron (EMIC) waves cause strong pitch-angle diffusion of RC ions? This question is the primary motivation of this paper and has been affirmatively answered from the theoretical point of view. The materials that are presented in the Results section show clear evidence that strong pitch-angle diffusion takes place in the inner magnetosphere indicating an important role for the wave-particle interaction mechanism in the formation of RC ions and EMIC waves.
Test measurement on ion-molecule reactions in a ringelectrode ion trap
NASA Astrophysics Data System (ADS)
Savic, I.; Lukic, S. R.; Guth, I.; Gerlich, D.
2006-05-01
Very recently a new experimental setup has been developed allowing studies of astrophysically relevant collisions between neutral atoms and small pure carbon molecules from one side and ions from the other side and first results are obtained (Savić et al., 2005). The ions are stored in a radio- frequency (rf) ring-electrode trap and during reaction time exposed to the effusive carbon beam. In this paper, one of the final tests of the experimental setup is presented.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Stein, Tamar; Bandyopadhyay, Biswajit; Troy, Tyler P.
The growth mechanism of hydrocarbons in ionizing environments, such as the interstellar medium (ISM), and some combustion conditions remains incompletely understood. Ab initio molecular dynamics (AIMD) simulations and molecular beam vacuum-UV (VUV) photoionization mass spectrometry experiments were performed to understand the ion-molecule growth mechanism of small acetylene clusters (up to hexamers). A dramatic dependence of product distribution on the ionization conditions is demonstrated experimentally and understood from simulations. The products change from reactive fragmentation products in a higher temperature, higher density gas regime toward a very cold collision-free cluster regime that is dominated by products whose empirical formula is (Cmore » 2H 2) n +, just like ionized acetylene clusters. The fragmentation products result from reactive ion- molecule collisions in a comparatively higher pressure and temperature regime followed by unimolecular decomposition. The isolated ionized clusters display rich dynamics that contain bonded C 4H 4 + and C 6H 6 + structures solvated with one or more neutral acetylene molecules. Such species contain large amounts ( > 2 eV) of excess internal energy. The role of the solvent acetylene molecules is to affect the barrier crossing dynamics in the potential energy surface (PES) between (C 2H 2) n + isomers and provide evaporative cooling to dissipate the excess internal energy and stabilize products including the aromatic ring of the benzene cation. Formation of the benzene cation is demonstrated in AIMD simulations of acetylene clusters with n > 3, as well as other metastable C 6H 6 + isomers. Lastly, these results suggest a path for aromatic ring formation in cold acetylene-rich environments such as parts of the ISM.« less
Stein, Tamar; Bandyopadhyay, Biswajit; Troy, Tyler P; Fang, Yigang; Kostko, Oleg; Ahmed, Musahid; Head-Gordon, Martin
2017-05-23
The growth mechanism of hydrocarbons in ionizing environments, such as the interstellar medium (ISM), and some combustion conditions remains incompletely understood. Ab initio molecular dynamics (AIMD) simulations and molecular beam vacuum-UV (VUV) photoionization mass spectrometry experiments were performed to understand the ion-molecule growth mechanism of small acetylene clusters (up to hexamers). A dramatic dependence of product distribution on the ionization conditions is demonstrated experimentally and understood from simulations. The products change from reactive fragmentation products in a higher temperature, higher density gas regime toward a very cold collision-free cluster regime that is dominated by products whose empirical formula is (C 2 H 2 ) n + , just like ionized acetylene clusters. The fragmentation products result from reactive ion-molecule collisions in a comparatively higher pressure and temperature regime followed by unimolecular decomposition. The isolated ionized clusters display rich dynamics that contain bonded C 4 H 4 + and C 6 H 6 + structures solvated with one or more neutral acetylene molecules. Such species contain large amounts (>2 eV) of excess internal energy. The role of the solvent acetylene molecules is to affect the barrier crossing dynamics in the potential energy surface (PES) between (C 2 H 2 ) n + isomers and provide evaporative cooling to dissipate the excess internal energy and stabilize products including the aromatic ring of the benzene cation. Formation of the benzene cation is demonstrated in AIMD simulations of acetylene clusters with n > 3, as well as other metastable C 6 H 6 + isomers. These results suggest a path for aromatic ring formation in cold acetylene-rich environments such as parts of the ISM.
Stein, Tamar; Bandyopadhyay, Biswajit; Troy, Tyler P.; ...
2017-05-08
The growth mechanism of hydrocarbons in ionizing environments, such as the interstellar medium (ISM), and some combustion conditions remains incompletely understood. Ab initio molecular dynamics (AIMD) simulations and molecular beam vacuum-UV (VUV) photoionization mass spectrometry experiments were performed to understand the ion-molecule growth mechanism of small acetylene clusters (up to hexamers). A dramatic dependence of product distribution on the ionization conditions is demonstrated experimentally and understood from simulations. The products change from reactive fragmentation products in a higher temperature, higher density gas regime toward a very cold collision-free cluster regime that is dominated by products whose empirical formula is (Cmore » 2H 2) n +, just like ionized acetylene clusters. The fragmentation products result from reactive ion- molecule collisions in a comparatively higher pressure and temperature regime followed by unimolecular decomposition. The isolated ionized clusters display rich dynamics that contain bonded C 4H 4 + and C 6H 6 + structures solvated with one or more neutral acetylene molecules. Such species contain large amounts ( > 2 eV) of excess internal energy. The role of the solvent acetylene molecules is to affect the barrier crossing dynamics in the potential energy surface (PES) between (C 2H 2) n + isomers and provide evaporative cooling to dissipate the excess internal energy and stabilize products including the aromatic ring of the benzene cation. Formation of the benzene cation is demonstrated in AIMD simulations of acetylene clusters with n > 3, as well as other metastable C 6H 6 + isomers. Lastly, these results suggest a path for aromatic ring formation in cold acetylene-rich environments such as parts of the ISM.« less
Nonuniformity for rotated beam illumination in directly driven heavy-ion fusion
DOE Office of Scientific and Technical Information (OSTI.GOV)
Runge, J.; Logan, B.G.
A key issue in heavy-ion beam inertial confinement fusion is target interaction, especially implosion symmetry. In this paper the 2D beam irradiation nonuniformity on the surface of a spherical target is studied. This is a first step to studies of 3D dynamical effects on target implosion. So far non-rotated beams have been studied. Because normal incidence may increase Rayleigh-Taylor instabilities, it has been suggested to rotate beams (to increase average uniformity) and hit the target tangentially. The level of beam irradiation uniformity, beam spill and normal incidence is calculated in this paper. In Mathematica the rotated beams are modeled asmore » an annular integrated Gaussian beam. To simplify the chamber geometry, the illumination scheme is not a 4{pi} system, but the beams are arranged on few polar rings around the target. The position of the beam spot rings is efficiently optimized using the analytical model. The number of rings and beams, rotation radii and widths are studied to optimize uniformity and spilled intensity. The results demonstrate that for a 60-beam system on four rings Peak-To-Valley nonuniformities of under 0.5% are possible.« less
RHIC Polarization Decay in FY15 pp Run due to Polarization Profile Development
DOE Office of Scientific and Technical Information (OSTI.GOV)
Huang, H.; Adams, P.
2016-05-23
The decay over time of ratio between polarization profile and beam profile has been analyzed previously. A follow up question is if we can get the decay of polarization profile and beam profile separately. With the beam profiles obtained from Ion Profile Monitor (IPM), this analysis was done and the results are analyzed. The results show that the contribution from polarization profile and beam profile is similar for yellow ring, but the contribution from polarization profile is much stronger in blue ring, which is consistent with lower polarization Blue ring.
Ion Composition in Saturn's Plasma Environment: Early Results from the Cassini Plasma Spectrometer
NASA Technical Reports Server (NTRS)
Reisenfeld, D. B.; Baragiola, R. A.; Crary, F. J.; Coates, A. J.; Goldstein, R.; Hill, T. W.; Johnson, R. E.; McComas, D. J.; Sittler, E. C.; Shappirio, M. D.
2005-01-01
Prior to Cassini s arrival at Saturn, most of what was known about the composition of the plasma in Saturn s environment was derived from limited measurements by Pioneer 11 and Voyager 1 and 2 in 1979-1981[1-3]. The measurements reported here were made by the Cassini Plasma Spectrometer (CAPS) [4] during the first two Cassini orbits, including the closest approach to Saturn and the rings during the tour, and a close flyby of Titan. The CAPS instrument resolves ion energy/charge from 1 V to 50 kV and ion mass/charge from 1 to approx.100 amu/e, and it measures electron energy from 1 eV to 28 keV. Initial composition measurements of Saturn s magnetosphere show that protons dominate outside approx.8 R(sub s), while inside this radius the plasma is dominated by a mix of water-derived ions and N(+). Over the A and B rings a plasma layer is observed composed of O2(+) and O(+) . The close passage near Titan shows a rich network of both positive and negative molecular ions. We report preliminary analysis of these and other composition findings.
Chakraborty Thakur, Saikat; McCarren, Dustin; Carr, Jerry; Scime, Earl E
2012-02-01
We report continuous wave cavity ring down spectroscopy (CW-CRDS) measurements of ion velocity distribution functions (VDFs) in low pressure argon helicon plasma (magnetic field strength of 600 G, T(e) ≈ 4 eV and n ≈ 5 × 10(11) cm(-3)). Laser induced fluorescence (LIF) is routinely used to measure VDFs of argon ions, argon neutrals, helium neutrals, and xenon ions in helicon sources. Here, we describe a CW-CRDS diagnostic based on a narrow line width, tunable diode laser as an alternative technique to measure VDFs in similar regimes but where LIF is inapplicable. Being an ultra-sensitive, cavity enhanced absorption spectroscopic technique; CW-CRDS can also provide a direct quantitative measurement of the absolute metastable state density. The proof of principle CW-CRDS measurements presented here are of the Doppler broadened absorption spectrum of Ar II at 668.6138 nm. Extrapolating from these initial measurements, it is expected that this diagnostic is suitable for neutrals and ions in plasmas ranging in density from 1 × 10(9) cm(-3) to 1 × 10(13) cm(-3) and target species temperatures less than 20 eV.
NASA Astrophysics Data System (ADS)
Chakraborty Thakur, Saikat; McCarren, Dustin; Carr, Jerry; Scime, Earl E.
2012-02-01
We report continuous wave cavity ring down spectroscopy (CW-CRDS) measurements of ion velocity distribution functions (VDFs) in low pressure argon helicon plasma (magnetic field strength of 600 G, Te ≈ 4 eV and n ≈ 5 × 1011 cm-3). Laser induced fluorescence (LIF) is routinely used to measure VDFs of argon ions, argon neutrals, helium neutrals, and xenon ions in helicon sources. Here, we describe a CW-CRDS diagnostic based on a narrow line width, tunable diode laser as an alternative technique to measure VDFs in similar regimes but where LIF is inapplicable. Being an ultra-sensitive, cavity enhanced absorption spectroscopic technique; CW-CRDS can also provide a direct quantitative measurement of the absolute metastable state density. The proof of principle CW-CRDS measurements presented here are of the Doppler broadened absorption spectrum of Ar II at 668.6138 nm. Extrapolating from these initial measurements, it is expected that this diagnostic is suitable for neutrals and ions in plasmas ranging in density from 1 × 109 cm-3 to 1 × 1013 cm-3 and target species temperatures less than 20 eV.
NASA Astrophysics Data System (ADS)
Duignan, Timothy T.; Baer, Marcel D.; Mundy, Christopher J.
2018-06-01
The tetra-phenyl arsonium and tetra-phenyl borate (TATB) assumption is a commonly used extra-thermodynamic assumption that allows single ion free energies to be split into cationic and anionic contributions. The assumption is that the values for the TATB salt can be divided equally. This is justified by arguing that these large hydrophobic ions will cause a symmetric response in water. Experimental and classical simulation work has raised potential flaws with this assumption, indicating that hydrogen bonding with the phenyl ring may favor the solvation of the TB- anion. Here, we perform ab initio molecular dynamics simulations of these ions in bulk water demonstrating that there are significant structural differences. We quantify our findings by reproducing the experimentally observed vibrational shift for the TB- anion and confirm that this is associated with hydrogen bonding with the phenyl rings. Finally, we demonstrate that this results in a substantial energetic preference of the water to solvate the anion. Our results suggest that the validity of the TATB assumption, which is still widely used today, should be reconsidered experimentally in order to properly reference single ion solvation free energy, enthalpy, and entropy.
Emittance measurements in low energy ion storage rings
NASA Astrophysics Data System (ADS)
Hunt, J. R.; Carli, C.; Resta-López, J.; Welsch, C. P.
2018-07-01
The development of the next generation of ultra-low energy antiproton and ion facilities requires precise information about the beam emittance to guarantee optimum performance. In the Extra-Low ENergy Antiproton storage ring (ELENA) the transverse emittances will be measured by scraping. However, this diagnostic measurement faces several challenges: non-zero dispersion, non-Gaussian beam distributions due to effects of the electron cooler and various systematic errors such as closed orbit offsets and inaccurate rms momentum spread estimation. In addition, diffusion processes, such as intra-beam scattering might lead to emittance overestimates. Here, we present algorithms to efficiently address the emittance reconstruction in presence of the above effects, and present simulation results for the case of ELENA.
Ion velocity distributions in dipolarization events: Distributions in the central plasma sheet
NASA Astrophysics Data System (ADS)
Birn, J.; Runov, A.; Zhou, X.-Z.
2017-08-01
Using combined MHD/test particle simulations, we further explore characteristic ion velocity distributions in the central plasma sheet (CPS) in relation to dipolarization events. Distributions in the CPS within the dipolarized flux bundle (DFB) that follows the passage of a dipolarization front typically show two opposing low subthermal-energy beams with a ring-like component perpendicular to the magnetic field at about twice the thermal energy. The dominance of the perpendicular anisotropy and a field-aligned peak at lower energy agree qualitatively with ion distribution functions derived from "Time History of Events and Macroscale Interactions during Substorms" observations. At locations somewhat off the equatorial plane the field-aligned peaks are shifted by a field-aligned component of the bulk flow, such that one peak becomes centered near zero net velocity, which makes it less likely to be observed. The origins of the field-aligned peaks are low-energy lobe (or near plasma sheet boundary layer) regions, while the ring distribution originates mostly from thermal plasma sheet particles on extended field lines. The acceleration mechanisms are also quite different: the beam ions are accelerated first by the E × B drift motion of the DFB and then by a slingshot effect of the earthward convecting DFB (akin to first-order Fermi, type B, acceleration), which causes an increase in field-aligned speed. In contrast, the ring particles are accelerated by successive, betatron-like acceleration after entering the high electric field region of an earthward propagating DFB.
NASA Astrophysics Data System (ADS)
Xia, Hanxue; Zhang, Yong; Attygalle, Athula B.
2018-06-01
Protonated methyl benzoate, upon activation, fragments by three distinct pathways. The m/z 137 ion for the protonated species generated by helium-plasma ionization (HePI) was mass-selected and subjected to collisional activation. In one fragmentation pathway, the protonated molecule generated a product ion of m/z 59 by eliminating a molecule of benzene (Pathway I). The m/z 59 ion (generally recognized as the methoxycarbonyl cation) produced in this way, then formed a methyl carbenium ion in situ by decarboxylation, which in turn evoked an electrophilic aromatic addition reaction on the benzene ring by a termolecular process to generate the toluenium cation (Pathway II). Moreover, protonated methyl benzoate undergoes also a methanol loss (Pathway III). However, it is not a simple removal of a methanol molecule after a protonation on the methoxy group. The incipient proton migrates to the ring and randomizes to a certain degree before a subsequent transfer of one of the ring protons to the alkoxy group for the concomitant methanol elimination. The spectrum recorded from deuteronated methyl benzoate showed two peaks at m/z 105 and 106 for the benzoyl cation at a ratio of 2:1, confirming the charge-imparting proton is mobile. However, the proton transfer from the benzenium intermediate to the methoxy group for the methanol loss occurs before achieving a complete state of scrambling. [Figure not available: see fulltext.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Florinski, V.; Heerikhuisen, J.; Niemiec, J.
2016-08-01
The nearly circular band of energetic neutral atom emission dominating the field of view of the Interplanetary Boundary Explorer ( IBEX ) satellite, is most commonly attributed to the effect of charge exchange of secondary pickup ions (PUIs) gyrating about the magnetic field in the outer heliosheath and the interstellar space beyond. Several models for the PUI dynamics of this mechanism have been proposed, each requiring either strong or weak scattering of the initial pitch angle. Conventional wisdom states that ring distributions tend to generate waves and scatter onto a shell on timescales too short for charge exchange to occur.more » We performed a careful study of ring and thin shell proton distribution stability using theoretical tools and hybrid plasma simulations. We show that the kinetic behavior of a freshly injected proton ring is a far more complicated process than previously thought. In the presence of a warm Maxwellian core, narrower rings could be more stable than broader toroidal distributions. The scattered rings possess a fine structure that can only be revealed using very large numbers of macroparticles in a simulation. It is demonstrated that a “stability gap” in ring temperature exists where the protons could retain large gyrating anisotropies for years, and the wave activity could remain below the level of the ambient magnetic fluctuations in interstellar space. In the directions away from the ribbon, however, a partial shell distribution is more likely to be unstable, leading to significant scattering into one hemisphere in velocity space. The process is accompanied by turbulence production, which is puzzling given the very low level of magnetic fluctuations measured in the outer heliosheath by Voyager 1 .« less
Linear and nonlinear properties of the ULF waves driven by ring-beam distribution functions
NASA Technical Reports Server (NTRS)
Killen, K.; Omidi, N.; Krauss-Varban, D.; Karimabadi, H.
1995-01-01
The problem of the exitation of obliquely propagating magnetosonic waves which can steepen up (also known as shocklets) is considered. Shocklets have been observed upstream of the Earth's bow shock and at comets Giacobini-Zinner and Grigg-Skjellerup. Linear theory as well as two-dimensional (2-D) hybrid (fluid electrons, particle ions) simulations are used to determine the properties of waves generated by ring-beam velocity distributions in great detail. The effects of both proton and oxygen ring-beams are considered. The study of instabilities excited by a proton ring-beam is relevant to the region upstream of the Earth's bow shock, whereas the oxygen ring-beam corresponds to cometary ions picked up by the solar wind. Linear theory has shown that for a ring-beam, four instabilities are found, one on the nonresonant mode, one on the Alfven mode, and two along the magnetosonic/whistler branch. The relative growth rate of these instabilities is a sensitive function of parameters. Although one of the magnetosonic instabilities has maximum growth along the magnetic field, the other has maximum growth in oblique directions. We have studied the competition of these instabilities in the nonlinear regime using 2-D simulations. As in the linear limit, the nonlinear results are a function of beam density and distribution function. By performing the simulations as both initial value and driven systems, we have found that the outcome of the simulations can vary, suggesting that the latter type simulations is needed to address the observations. A general conclusion of the simulation results is that field-aligned beams do not result in the formation of shocklets, whereas ring-beam distributions can.
In situ measurements of Saturn’s ionosphere show that it is dynamic and interacts with the rings
NASA Astrophysics Data System (ADS)
Wahlund, J.-E.; Morooka, M. W.; Hadid, L. Z.; Persoon, A. M.; Farrell, W. M.; Gurnett, D. A.; Hospodarsky, G.; Kurth, W. S.; Ye, S.-Y.; Andrews, D. J.; Edberg, N. J. T.; Eriksson, A. I.; Vigren, E.
2018-01-01
The ionized upper layer of Saturn’s atmosphere, its ionosphere, provides a closure of currents mediated by the magnetic field to other electrically charged regions (for example, rings) and hosts ion-molecule chemistry. In 2017, the Cassini spacecraft passed inside the planet’s rings, allowing in situ measurements of the ionosphere. The Radio and Plasma Wave Science instrument detected a cold, dense, and dynamic ionosphere at Saturn that interacts with the rings. Plasma densities reached up to 1000 cubic centimeters, and electron temperatures were below 1160 kelvin near closest approach. The density varied between orbits by up to two orders of magnitude. Saturn’s A- and B-rings cast a shadow on the planet that reduced ionization in the upper atmosphere, causing a north-south asymmetry.
NASA Astrophysics Data System (ADS)
Leach, Franklin E.; Riley, Nicholas M.; Westphall, Michael S.; Coon, Joshua J.; Amster, I. Jonathan
2017-09-01
The structural characterization of sulfated glycosaminoglycan (GAG) carbohydrates remains an important target for analytical chemists attributable to challenges introduced by the natural complexity of these mixtures and the defined need for molecular-level details to elucidate biological structure-function relationships. Tandem mass spectrometry has proven to be the most powerful technique for this purpose. Previously, electron detachment dissociation (EDD), in comparison to other methods of ion activation, has been shown to provide the largest number of useful cleavages for de novo sequencing of GAG oligosaccharides, but such experiments are restricted to Fourier transform ion cyclotron resonance mass spectrometers (FTICR-MS). Negative electron transfer dissociation (NETD) provides similar fragmentation results, and can be achieved on any mass spectrometry platform that is designed to accommodate ion-ion reactions. Here, we examine for the first time the effectiveness of NETD-Orbitrap mass spectrometry for the structural analysis of GAG oligosaccharides. Compounds ranging in size from tetrasaccharides to decasaccharides were dissociated by NETD, producing both glycosidic and cross-ring cleavages that enabled the location of sulfate modifications. The highly-sulfated, heparin-like synthetic GAG, ArixtraTM, was also successfully sequenced by NETD. In comparison to other efforts to sequence GAG chains without fully ionized sulfate constituents, the occurrence of sulfate loss peaks is minimized by judicious precursor ion selection. The results compare quite favorably to prior results with electron detachment dissociation (EDD). Significantly, the duty cycle of the NETD experiment is sufficiently short to make it an effective tool for on-line separations, presenting a straightforward path for selective, high-throughput analysis of GAG mixtures. [Figure not available: see fulltext.
Electrohydrodynamic (edh) drying of ginger slices (zingiber officinale)
NASA Astrophysics Data System (ADS)
Sumariyah; Khuriati, Ainie; Fachriyah, Enny
2018-05-01
Electrohydrodynamic (EHD) flow or ion wind of corona discharges has been generated utilizing pin-multi ring concentred electrodes. The pin was made of stainless steel with a tip diameter of 0.018 mm. The multi-ring constructed electrodes by a metal material connected to each other and each ring has a diameter of 24 mm, 16 mm and 8 mm in the same width and thickness is 4 mm and 1 mm. EHD was generated by using a DC high voltage of 5 kV. Pin as an active electrode of corona discharge and multi-ring concentric electrodes as a collector and passive electrodes. The ion wind or EHD flow is produced through changes in voltage and distance between electrodes. The ionic wind generated system outputs through multi-ring concentric electrodes which will further dry the sample. A circle ginger slices as a sample with a diameter of 26 mm with a thickness of 2 mm. The drying is done at the distance between the fixed electrodes of 4 mm and the varied voltages are 1.2 kV, 1.4 kV, and 1.6 kV. The sample drying time varied 30 minutes, 60 minutes, 90 minutes, 120 minutes and 150 minutes. The result of drying the sample at a fixed voltage is obtained moisture of ginger slices decreased with increased drying time.
Simons, Rudy; Vincken, Jean-Paul; Bohin, Maxime C; Kuijpers, Tomas F M; Verbruggen, Marian A; Gruppen, Harry
2011-01-15
Phytoalexins from soya are mainly characterised as prenylated pterocarpans, the glyceollins. Extracts of non-soaked and soaked soya beans, as well as that of soya seedlings, grown in the presence of Rhizopus microsporus var. oryzae, were screened for the presence of prenylated flavonoids with a liquid chromatography/mass spectrometry (LC/MS)-based screening method. The glyceollins I-III and glyceollidins I-II, belonging to the isoflavonoid subclass of the pterocarpans, were tentatively assigned. The formation of these prenylated pterocarpans was accompanied by that of other prenylated isoflavonoids of the subclasses of the isoflavones and the coumestans. It was estimated that approx. 40% of the total isoflavonoid content in Rhizopus-challenged soya bean seedlings were prenylated pterocarpans, whereas 7% comprised prenylated isoflavones and prenylated coumestans. The site of prenylation (A-ring or B-ring) of the prenylated isoflavones was tentatively annotated using positive-ion mode MS by comparing the (1,3) A(+) retro-Diels-Alder (RDA) fragments of prenylated and non-prenylated isoflavones. Furthermore, the fragmentation pathways of the five pterocarpans in negative-ion (NI) mode were proposed, which involved the cleavage of the C-ring and/or D-ring. The absence of the ring-closed prenyl (pyran or furan) gave exclusively -H(2) O(x,y) RDA fragments, whereas its presence gave predominantly the common RDA fragments. Copyright © 2010 John Wiley & Sons, Ltd.
Shelton, Jill T.; Elliott, Emily M.; Lynn, Sharon D.; Exner, Amanda L.
2010-01-01
The detrimental effects of a ringing phone on cognitive performance were investigated in four experiments. In Experiments 1 and 2, the effects of different types of sounds (a standard cell phone ring, irrelevant tones and an instrumental song commonly encountered by participants) on performance were examined. In Experiment 1, slower responses were observed in all auditory groups relative to a silence condition, but participants in the ring and song conditions recovered more slowly. In Experiment 2, participants who were warned about the potential for distraction recovered more quickly, suggesting a benefit of this prior knowledge. This investigation continued in a college classroom setting (Experiments 3a and 3b); students were exposed to a ringing cell phone during the lecture. Performance on a surprise quiz revealed low accuracy rates on material presented while the phone was ringing. These findings offer insight into top-down cognitive processes that moderate involuntary orienting responses associated with a common stimulus encountered in the environment. PMID:21234286
Using carrier-depletion silicon modulators for optical power monitoring.
Yu, Hui; Korn, Dietmar; Pantouvaki, Marianna; Van Campenhout, Joris; Komorowska, Katarzyna; Verheyen, Peter; Lepage, Guy; Absil, Philippe; Hillerkuss, David; Alloatti, Luca; Leuthold, Juerg; Baets, Roel; Bogaerts, Wim
2012-11-15
Defect-mediated subbandgap absorption is observed in ion-implanted silicon-on-oxide waveguides that experience a rapid thermal annealing at 1075°C. With this effect, general carrier-depletion silicon modulators exhibit the capability of optical power monitoring. Responsivity is measured to be 22 mA/W for a 3 mm long Mach-Zehnder modulator of 2×10(18) cm(-3) doping concentration at -7.1 V bias voltage and 5.9 mA/W for a ring modulator of 1×10(18) cm(-3) doping concentration at -10 V bias voltage. The former is used to demonstrate data detection of up to 35 Gbits/s.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Shukla, Anil, E-mail: Anil.Shukla@pnnl.gov; Bogdanov, Bogdan
2015-02-14
Small cationic and anionic clusters of lithium formate were generated by electrospray ionization and their fragmentations were studied by tandem mass spectrometry (collision-induced dissociation with N{sub 2}). Singly as well as multiply charged clusters were formed in both positive and negative ion modes with the general formulae, (HCOOLi){sub n}Li{sup +}, (HCOOLi){sub n}Li{sub m}{sup m+}, (HCOOLi){sub n}HCOO{sup −}, and (HCOOLi){sub n}(HCOO){sub m}{sup m−}. Several magic number cluster (MNC) ions were observed in both the positive and negative ion modes although more predominant in the positive ion mode with (HCOOLi){sub 3}Li{sup +} being the most abundant and stable cluster ion. Fragmentations ofmore » singly charged positive clusters proceed first by the loss of a dimer unit ((HCOOLi){sub 2}) followed by the loss of monomer units (HCOOLi) although the former remains the dominant dissociation process. In the case of positive cluster ions, all fragmentations lead to the magic cluster (HCOOLi){sub 3}Li{sup +} as the most abundant fragment ion at higher collision energies which then fragments further to dimer and monomer ions at lower abundances. In the negative ion mode, however, singly charged clusters dissociated via sequential loss of monomer units. Multiply charged clusters in both positive and negative ion modes dissociated mainly via Coulomb repulsion. Quantum chemical calculations performed for smaller cluster ions showed that the trimer ion has a closed ring structure similar to the phenalenylium structure with three closed rings connected to the central lithium ion. Further additions of monomer units result in similar symmetric structures for hexamer and nonamer cluster ions. Thermochemical calculations show that trimer cluster ion is relatively more stable than neighboring cluster ions, supporting the experimental observation of a magic number cluster with enhanced stability.« less
NASA Astrophysics Data System (ADS)
O'Donoghue, J.; Moore, L.; Stallard, T.; Melin, H.; Connerney, J. E. P.; Oliversen, R. J.
2017-09-01
In 2013, we discovered that the "ring rain" which falls on Saturn from the rings also leaves an imprint on the low-latitude upper-atmosphere. Specifically, the ionospheric-bound H3+ ion appeared to emit brightest where water products are known to fall. Here we show the first re-detections of the imprint of "ring rain" on Saturn's ionosphere, using ground-based Keck telescope data from 2013 and 2014. We have also found that the emission from low-latitudes decreases dramatically from 2011 to 2013, implying a planetary cooling over the time period, but we are unaware of the mechanism of this cooling at present.
Highly linear ring modulator from hybrid silicon and lithium niobate.
Chen, Li; Chen, Jiahong; Nagy, Jonathan; Reano, Ronald M
2015-05-18
We present a highly linear ring modulator from the bonding of ion-sliced x-cut lithium niobate onto a silicon ring resonator. The third order intermodulation distortion spurious free dynamic range is measured to be 98.1 dB Hz(2/3) and 87.6 dB Hz(2/3) at 1 GHz and 10 GHz, respectively. The linearity is comparable to a reference lithium niobate Mach-Zehnder interferometer modulator operating at quadrature and over an order of magnitude greater than silicon ring modulators based on plasma dispersion effect. Compact modulators for analog optical links that exploit the second order susceptibility of lithium niobate on the silicon platform are envisioned.
NASA Astrophysics Data System (ADS)
Eiskowitz, Skylar; Ballew, Nolan; Rojas, Rubén; Lathrop, Daniel
2017-11-01
The particles in Saturn's rings exhibit complex dynamic behavior. They experience solar radiation pressure, electromagnetic forces, and granular collisions. To investigate the possibility of the Hall Effect in the dusty plasma that comprise Saturn's rings, we have built an experiment that demonstrates the Hall Effect in granular matter. We focus on the Hall Effect because the rings' grains become collisionally charged and experience Saturn's dipolar magnetic field and Lorentz forces as they orbit. The experimental setup includes a closed ring-like track where granular matter is forced to circulate driven by compressed air. The structure sits between two electromagnets so that a portion of the track experiences up to a 0.2 T magnetic field. We vary the strength of the field and the speed of the particles. We report the voltage differences between two conducting plates on opposite sides of the track. If Saturn's rings do experience the Hall Effect, the inside and outside of the rings will develop a charge separation that can lead to a radial electric field and various phenomena including orbital effects due to the additional electric forces. Observational evidence from Cassini suggests that Saturn's rings exhibit lighting, supporting the notion that they are electrically charged. TREND REU program sponsored by the National Science Foundation.
NASA Astrophysics Data System (ADS)
Zhou, Qiujiao; Qi, Bing; Huang, Jianjun; Pan, Lizhu; Liu, Ying
2016-04-01
The properties of a helium atmospheric-pressure plasma jet (APPJ) are diagnosed with a dual assisted grounded electrode dielectric barrier discharge device. In the glow discharge, we captured the current waveforms at the positions of the three grounded rings. From the current waveforms, the time delay between the adjacent positions of the rings is employed to calculate the plasma bullet velocity of the helium APPJ. Moreover, the electron density is deduced from a model combining with the time delay and current intensity, which is about 1011 cm-3. In addition, The ion-neutral particles collision frequency in the radial direction is calculated from the current phase difference between two rings, which is on the order of 107 Hz. The results are helpful for understanding the basic properties of APPJs. supported by National Natural Science Foundation of China (No. 11105093), the Technological Project of Shenzhen, China (No. JC201005280485A), and the Planned S&T Program of Shenzhen, China (No. JC201105170703A)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bu, Caixia; Bahr, David A.; Dukes, Catherine A.
2016-07-10
Within Saturn's E-ring, dust grains are coated by water vapor co-released with ice grains from the geyser-like eruptions of Enceladus. These ice-coated grains have intrinsic surface potential and interact synergistically with the ions and electrons of Saturn's magnetospheric plasmas. We perform laboratory experiments to investigate the effects of water-ice growth on the surface potential, using amorphous solid water (ASW) films. We estimate the growth of the surface potential to be ∼ 2.5 mV (Earth) yr{sup 1} and 112 mV yr{sup 1} for E-ring grains at ∼4.5 R {sub s} and 3.95 R {sub s} outside Enceladus’s plume, respectively. In addition,more » our measurements show that the linear relationship between the surface potential and the film thickness, as described in previous studies, has an upper limit, where the film spontaneously cracks above a porosity-dependent critical thickness. Heating of the cracked films with (and without) deposited charge shows that significant positive (and negative) surface potentials are retained at temperatures above 110 K, contrary to the minimal values (roughly zero) for thin, transparent ASW films. The significant surface potentials observed on micron-scale cracked ice films after thermal cycling, (5–20) V, are consistent with Cassini measurements, which indicate a negative charge of up to 5 V for E-ring dust particles at ∼5 R {sub s}. Therefore, the native grain surface potential resulting from water-vapor coating must be included in modeling studies of interactions between E-ring icy surfaces and Saturn's magnetospheric plasma.« less
Jitonnom, Jitrayut; Mujika, Jon I; van der Kamp, Marc W; Mulholland, Adrian J
2017-12-05
Creatininase catalyzes the conversion of creatinine (a biosensor for kidney function) to creatine via a two-step mechanism: water addition followed by ring opening. Water addition is common to other known cyclic amidohydrolases, but the precise mechanism for ring opening is still under debate. The proton donor in this step is either His178 or a water molecule bound to one of the metal ions, and the roles of His178 and Glu122 are unclear. Here, the two possible reaction pathways have been fully examined by means of combined quantum mechanics/molecular mechanics simulations at the SCC-DFTB/CHARMM22 level of theory. The results indicate that His178 is the main catalytic residue for the whole reaction and explain its role as proton shuttle during the ring-opening step. In the first step, His178 provides electrostatic stabilization to the gem-diolate tetrahedral intermediate. In the second step, His178 abstracts the hydroxyl proton of the intermediate and delivers it to the cyclic amide nitrogen, leading to ring opening. The latter is the rate-limiting step with a free energy barrier of 18.5 kcal/mol, in agreement with the experiment. We find that Glu122 must be protonated during the enzyme reaction, so that it can form a stable hydrogen bond with its neighboring water molecule. Simulations of the E122Q mutant showed that this replacement disrupts the H-bond network formed by three conserved residues (Glu34, Ser78, and Glu122) and water, increasing the energy barrier. Our computational studies provide a comprehensive explanation for previous structural and kinetic observations, including why the H178A mutation causes a complete loss of activity but the E122Q mutation does not.
NASA Astrophysics Data System (ADS)
Tu, X. L.; Chen, X. C.; Zhang, J. T.; Shuai, P.; Yue, K.; Xu, X.; Fu, C. Y.; Zeng, Q.; Zhou, X.; Xing, Y. M.; Wu, J. X.; Mao, R. S.; Mao, L. J.; Fang, K. H.; Sun, Z. Y.; Wang, M.; Yang, J. C.; Litvinov, Yu. A.; Blaum, K.; Zhang, Y. H.; Yuan, Y. J.; Ma, X. W.; Zhou, X. H.; Xu, H. S.
2018-01-01
Lifetime measurements of β -decaying highly charged ions have been performed in the experimental storage ring (CSRe) by applying the isochronous Schottky mass spectrometry. The fully ionized 49Cr and 53Fe ions were produced in projectile fragmentation of 58Ni primary beam and were stored in the CSRe tuned into the isochronous ion-optical mode. The new resonant Schottky detector was applied to monitor the intensities of stored uncooled
Diclofenac removal in urine using strong-base anion exchange polymer resins.
Landry, Kelly A; Boyer, Treavor H
2013-11-01
One of the major sources of pharmaceuticals in the environment is wastewater effluent of which human urine contributes the majority of pharmaceuticals. Urine source separation has the potential to isolate pharmaceuticals at a higher concentration for efficient removal as well as produce a nutrient byproduct. This research investigated the efficacy of using strong-base anion exchange polymer resins to remove the widely detected and abundant pharmaceutical, diclofenac, from synthetic human urine under fresh and ureolyzed conditions. The majority of experiments were conducted using a strong-base, macroporous, polystyrene resin (Purolite A520E). Ion-exchange followed a two-step removal rate with rapid removal in 1 h and equilibrium removal in 24 h. Diclofenac removal was >90% at a resin dose of 8 mL/L in both fresh and ureolyzed urine. Sorption of diclofenac onto A520E resin was concurrent with desorption of an equivalent amount of chloride, which indicates the ion-exchange mechanism is occurring. The presence of competing ions such as phosphate and citrate did not significantly impact diclofenac removal. Comparisons of three polystyrene resins (A520E, Dowex 22, Dowex Marathon 11) as well as one polyacrylic resin (IRA958) were conducted to determine the major interactions between anion exchange resin and diclofenac. The results showed that polystyrene resins provide the highest level of diclofenac removal due to electrostatic interactions between quaternary ammonium functional groups of resin and carboxylic acid of diclofenac and non-electrostatic interactions between resin matrix and benzene rings of diclofenac. Diclofenac was effectively desorbed from A520E resin using a regeneration solution that contained 4.5% (m/m) NaCl in an equal-volume mixture of methanol and water. The greater regeneration efficiency of the NaCl/methanol-water mixture over the aqueous NaCl solution supports the importance of non-electrostatic interactions between resin matrix and benzene rings of diclofenac. Experiments with ketoprofen, in addition to diclofenac, suggest that polystyrene anion exchange resins can be used to selectively remove other acidic pharmaceuticals from urine. Copyright © 2013 Elsevier Ltd. All rights reserved.
Functional electrolyte for lithium-ion batteries
Zhang, Lu; Zhang, Zhengcheng; Amine, Khalil
2015-04-14
Functional electrolyte solvents include compounds having at least one aromatic ring with 2, 3, 4 or 5 substituents, at least one of which is a substituted or unsubstituted methoxy group, at least one of which is a tert-butyl group and at least one of which is a substituted or unsubstituted polyether or poly(ethylene oxide) (PEO) group bonded through oxygen to the aromatic ring, are provided.
Generalized Stability Conditions for an Ultra-Low Energy Electrostatic Charged Particle Storage Ring
NASA Astrophysics Data System (ADS)
Sullivan, Michael
A low energy (~50 eV) electrostatic storage ring has been constructed that can store a recirculating bunch of either electrons or ions. The charged particle bunch 'orbits' within an apparatus consisting of four lenses and two hemispherical deflector analysers, arranged in a 'race-track' configuration of length 64.1 cm. A theoretical study, using transfer matrices from charged particle optics for a 'symmetric' configuration of lens potentials, has been previously completed by Hammond et al. [New J. Phys. 11 (2009) 043033]. That approach was capable of predicting modes of storage which appeared as a resonant-like pattern. An 'asymmetric' configuration, new in this work and extending the previous study to apply to a more general case, has been completed and will be presented alongside experimental results. The level of agreement between the theoretical and experimental results is found to be excellent, and the robustness of the matrix formalism has eliminated the need to rely on computer simulation to achieve storage. This asymmetric arrangement of the lenses allows for greater flexibility in the operation of the ring, creating the potential for a more diverse range of applications and potentially aid in the design of future rings. Several spectra for both electrons and positive ions are presented to provide an indication as to how the charged particle bunch evolves as more orbits are completed. The number of counts inevitably decreases as a function of orbit number due to loss mechanisms. Enhanced measurement techniques, as well as the matrix theory, have made storage of the bunch for over a hundred orbits routine, corresponding to over 65 m travelled, and this is observed directly from the spectra. The application of the storage ring as a multi-pass time-of-flight mass spectrometer has been studied. The isotopes of krypton and xenon have been made to completely separate from one another out of a single pulse of ions. This is observed to occur after ~15 orbits of the ring, roughly 10 m of distance. Initial results have indicated that the mass resolution is approximately 5000. Limitations and potential improvements to the mass resolution are presented.
NASA Technical Reports Server (NTRS)
Sovey, James S. (Technical Monitor); Williams, George J., Jr.
2004-01-01
Relative erosion rates and impingement ion production mechanisms have been identified for the discharge cathode of a 30 cm ion engine using laser-induced fluorescence (LIF). Mo and W erosion products as well as neutral and singly ionized xenon were interrogated. The erosion increased with both discharge current and voltage and spatially resolved measurements agreed with observed erosion patters. Ion velocity mapping identified back-flowing ions near the regions of erosion with energies potentially sufficient to generate the level of observed erosion. Ion production regions downstream of the cathode were indicated and were suggested as possible sources of the erosion causing ions.
The ARASE (ERG) magnetic field investigation
NASA Astrophysics Data System (ADS)
Matsuoka, Ayako; Teramoto, Mariko; Nomura, Reiko; Nosé, Masahito; Fujimoto, Akiko; Tanaka, Yoshimasa; Shinohara, Manabu; Nagatsuma, Tsutomu; Shiokawa, Kazuo; Obana, Yuki; Miyoshi, Yoshizumi; Mita, Makoto; Takashima, Takeshi; Shinohara, Iku
2018-03-01
The fluxgate magnetometer for the Arase (ERG) spacecraft mission was built to investigate particle acceleration processes in the inner magnetosphere. Precise measurements of the field intensity and direction are essential in studying the motion of particles, the properties of waves interacting with the particles, and magnetic field variations induced by electric currents. By observing temporal field variations, we will more deeply understand magnetohydrodynamic and electromagnetic ion-cyclotron waves in the ultra-low-frequency range, which can cause production and loss of relativistic electrons and ring-current particles. The hardware and software designs of the Magnetic Field Experiment (MGF) were optimized to meet the requirements for studying these phenomena. The MGF makes measurements at a sampling rate of 256 vectors/s, and the data are averaged onboard to fit the telemetry budget. The magnetometer switches the dynamic range between ± 8000 and ± 60,000 nT, depending on the local magnetic field intensity. The experiment is calibrated by preflight tests and through analysis of in-orbit data. MGF data are edited into files with a common data file format, archived on a data server, and made available to the science community. Magnetic field observation by the MGF will significantly improve our knowledge of the growth and decay of radiation belts and ring currents, as well as the dynamics of geospace storms.
Stormtime ring current and radiation belt ion transport: Simulations and interpretations
NASA Technical Reports Server (NTRS)
Lyons, Larry R.; Gorney, David J.; Chen, Margaret W.; Schulz, Michael
1995-01-01
We use a dynamical guiding-center model to investigate the stormtime transport of ring current and radiation-belt ions. We trace the motion of representative ions' guiding centers in response to model substorm-associated impulses in the convection electric field for a range of ion energies. Our simple magnetospheric model allows us to compare our numerical results quantitatively with analytical descriptions of particle transport, (e.g., with the quasilinear theory of radial diffusion). We find that 10-145-keV ions gain access to L approximately 3, where they can form the stormtime ring current, mainly from outside the (trapping) region in which particles execute closed drift paths. Conversely, the transport of higher-energy ions (approximately greater than 145 keV at L approximately 3) turns out to resemble radial diffusion. The quasilinear diffusion coefficient calculated for our model storm does not vary smoothly with particle energy, since our impulses occur at specific (although randomly determined) times. Despite the spectral irregularity, quasilinear theory provides a surprisingly accurate description of the transport process for approximately greater than 145-keV ions, even for the case of an individual storm. For 4 different realizations of our model storm, the geometric mean discrepancies between diffusion coefficients D(sup sim, sub LL) obtained from the simulations and the quasilinear diffusion coefficient D(sup ql, sub LL) amount to factors of 2.3, 2.3, 1.5, and 3.0, respectively. We have found that these discrepancies between D(sup sim, sub LL) and D(sup ql, sub LL) can be reduced slightly by invoking drift-resonance broadening to smooth out the sharp minima and maxima in D(sup ql, sub LL). The mean of the remaining discrepancies between D(sup sim, sub LL) and D(sup ql, sub LL) for the 4 different storms then amount to factors of 1.9, 2.1, 1.5, and 2.7, respectively. We find even better agreement when we reduce the impulse amplitudes systematically in a given model storm (e.g., reduction of all the impulse amplitudes by half reduces the discrepancy factor by at least its square root) and also when we average our results over an ensemble of 20 model storms (agreement is within a factor of 1.2 without impulse-amplitude reduction). We use our simulation results also to map phase-space densities f in accordance with Liouville's theorem. We find that the stormtime transport of approximately greater than 145-keV ions produces little change in f-bar the drift-averaged phase-space density on any drift shell of interest. However, the stormtime transport produces a major enhancement from the pre-storm phase-space density at energies approximately 30-145 keV, which are representative of the stormtime ring current.
Dust Charging in Saturn's Rings: Observations and Theory
NASA Astrophysics Data System (ADS)
Horanyi, M.
2008-12-01
Saturn's rings show a variety of dusty plasma processes. The electrostatic charging and subsequent orbital dynamics of small grains can establish their size and spatial distributions, for example. Simultaneously, dust can alter the composition, density and temperature of the plasma surrounding it. The dynamics of charged dust particles can be surprisingly complex and fundamentally different from the well understood limits of gravitationally dominated motions of neutral particles or the adiabatic motion of electrons and ions in electromagnetic fields that dominate gravity. This talk will focus on recent Cassini observations at Saturn that are best explained by theories describing the effects of the magnetospheric fields and plasmas on the rings. As our best examples, we will discuss the physics describing the large-scale structure of the E-ring, and the formation of 'spokes' over the dense rings of Saturn.
In situ measurements of Saturn's ionosphere show that it is dynamic and interacts with the rings.
Wahlund, J-E; Morooka, M W; Hadid, L Z; Persoon, A M; Farrell, W M; Gurnett, D A; Hospodarsky, G; Kurth, W S; Ye, S-Y; Andrews, D J; Edberg, N J T; Eriksson, A I; Vigren, E
2018-01-05
The ionized upper layer of Saturn's atmosphere, its ionosphere, provides a closure of currents mediated by the magnetic field to other electrically charged regions (for example, rings) and hosts ion-molecule chemistry. In 2017, the Cassini spacecraft passed inside the planet's rings, allowing in situ measurements of the ionosphere. The Radio and Plasma Wave Science instrument detected a cold, dense, and dynamic ionosphere at Saturn that interacts with the rings. Plasma densities reached up to 1000 cubic centimeters, and electron temperatures were below 1160 kelvin near closest approach. The density varied between orbits by up to two orders of magnitude. Saturn's A- and B-rings cast a shadow on the planet that reduced ionization in the upper atmosphere, causing a north-south asymmetry. Copyright © 2018, American Association for the Advancement of Science.
Nonlinear wave particle interaction in the Earth's foreshock
NASA Technical Reports Server (NTRS)
Mazelle, C.; LeQueau, D.; Meziane, K.; Lin, R. P.; Parks, G.; Reme, H.; Sanderson, T.; Lepping, R. P.
1997-01-01
The possibility that ion beams could provide a free energy source for driving an ion/ion instability responsible for the ULF wave occurrence is investigated. For this, the wave dispersion relation with the observed parameters is solved. Secondly, it is shown that the ring-like distributions could then be produced by a coherent nonlinear wave-particle interaction. It tends to trap the ions into narrow cells in velocity space centered around a well-defined pitch-angle, directly related to the saturation wave amplitude in the analytical theory. The theoretical predictions with the observations are compared.
Ion-ion charge exchange processes. Final technical report, June 1, 1977-May 31, 1978
DOE Office of Scientific and Technical Information (OSTI.GOV)
Poe, R.T.; Choi, B.H.
Under the auspices of ERDA, we have undertaken a vigorous study of ion-ion charge exchange process pertinent to the storage-ring configurations in the heavy-ion fusion program. One particular reaction, singly charged helium charge exchange, was investigated in detail. General trend of the singly charged heavy-ion charge exchange reaction can be inferred from the present study. Some of our results were presented at Proceedings of the Heavy-Ion Fusion Workshop, Argonne National Laboratory (September 1978) as a paper entitled Charge Exchange Between Singly Ionized Helium Ions, by B.H. Choi, R.T. Poe and K.T. Tang. Here, we briefly describe our method and reportmore » the results.« less
New experimental developments for s- and p-process research
NASA Astrophysics Data System (ADS)
Reifarth, R.; Ershova, O.; Glorius, J.; Göbel, K.; Langer, C.; Meusel, O.; Plag, R.; Schmidt, S.; Sonnabend, K.; Heil, M.
2012-12-01
Almost all of the heavy elements are produced via neutron-induced processes in a multitude of stellar production sites. The remaining minor part is produced via photon- and proton-induced reactions. The predictive power of the underlying stellar models is currently limited because they contain poorly constrained physics components such as convection, rotation or magnetic fields. An important tool to determine such components is the comparison of observed with modeled abundance distributions based on improved nuclear physics input. The FRANZ facility at the Goethe University Frankfurt, which is currently under construction will provide unprecedented neutron fluxes and proton currents available for nuclear astrophysics. It will be possible to investigate important branchpoint nuclei of the s-process nucleosynthesis path and proton-induced reactions important for p-process modeling. At the GSI close to Darmstadt radioactive isotopes can be investigated in inverse kinematics. This allows experiments such as proton-induced cross section measurements using a heavy-ion storage ring or measurements of gamma-induced reactions using the Coulomb dissociation method. The future FAIR facility will allow similar experiments on very exotic nuclei, since orders of magnitude higher radioactive ions beams will be possible.
The Role of Ionospheric Outflow Preconditioning in Determining Storm Geoeffectiveness
NASA Astrophysics Data System (ADS)
Welling, D. T.; Liemohn, M. W.; Ridley, A. J.
2012-12-01
It is now well accepted that ionospheric outflow plays an important role in the development of the plasma sheet and ring current during geomagnetic storms. Furthermore, even during quiet times, ionospheric plasma populates the magnetospheric lobes, producing a reservoir of hydrogen and oxygen ions. When the Interplanetary Magnetic Field (IMF) turns southward, this reservoir is connected to the plasma sheet and ring current through magnetospheric convection. Hence, the conditions of the ionosphere and magnetospheric lobes leading up to magnetospheric storm onset have important implications for storm development. Despite this, there has been little research on this preconditioning; most global simulations begin just before storm onset, neglecting preconditioning altogether. This work explores the role of preconditioning in determining the geoeffectiveness of storms using a coupled global model system. A model of ionospheric outflow (the Polar Wind Outflow Model, PWOM) is two-way coupled to a global magnetohydrodynamic model (the Block-Adaptive Tree Solar wind Roe-type Upwind Scheme, BATS-R-US), which in turn drives a ring current model (the Ring current Atmosphere interactions Model, RAM). This unique setup is used to simulate an idealized storm. The model is started at many different times, from 1 hour before storm onset to 12 hours before. The effects of storm preconditioning are examined by investigating the total ionospheric plasma content in the lobes just before onset, the total ionospheric contribution in the ring current just after onset, and the effects on Dst, magnetic elevation angle at geosynchronous, and total ring current energy density. This experiment is repeated for different solar activity levels as set by F10.7 flux. Finally, a synthetic double-dip storm is constructed to see how two closely spaced storms affect each other by changing the preconditioning environment. It is found that preconditioning of the magnetospheric lobes via ionospheric outflow greatly influences the geoeffectiveness of magnetospheric storms.
Solid polymer battery electrolyte and reactive metal-water battery
Harrup, Mason K.; Peterson, Eric S.; Stewart, Frederick F.
2000-01-01
In one implementation, a reactive metal-water battery includes an anode comprising a metal in atomic or alloy form selected from the group consisting of periodic table Group 1A metals, periodic table Group 2A metals and mixtures thereof. The battery includes a cathode comprising water. Such also includes a solid polymer electrolyte comprising a polyphosphazene comprising ligands bonded with a phosphazene polymer backbone. The ligands comprise an aromatic ring containing hydrophobic portion and a metal ion carrier portion. The metal ion carrier portion is bonded at one location with the polymer backbone and at another location with the aromatic ring containing hydrophobic portion. The invention also contemplates such solid polymer electrolytes use in reactive metal/water batteries, and in any other battery.
Micrometeorite erosion of the man rings as a source of plasma in the inner Saturnian plasma torus
NASA Technical Reports Server (NTRS)
Pospieszalska, M. K.; Johnson, R. E.
1991-01-01
Micrometeorite bombardment is presently suggested to be a source of water molecules and molecular ions in the region between the outer edge of the main rings of Saturn and Encedalus, adding to those neutrals and plasma that are generated by the sputtering of icy satellites. In view of uncertainties concerning the magnitude and distribution of the ring source, an examination is conducted of limiting cases. The implications of such cases for the Cassini division are calculated, and a discussion of their possible relevance to the region's neutral and plasma cloud is presented.
Research progress on ionic plasmas generated in an intense hydrogen negative ion source
DOE Office of Scientific and Technical Information (OSTI.GOV)
Takeiri, Y., E-mail: takeiri@nifs.ac.jp; Tsumori, K.; Nagaoka, K.
2015-04-08
Characteristics of ionic plasmas, observed in a high-density hydrogen negative ion source, are investigated with a multi-diagnostics system. The ionic plasma, which consists of hydrogen positive- and negative-ions with a significantly low-density of electrons, is generated in the ion extraction region, from which the negative ions are extracted through the plasma grid. The negative ion density, i.e., the ionic plasma density, as high as the order of 1×10{sup 17}m{sup −3}, is measured with cavity ring-down spectroscopy, while the electron density is lower than 1×10{sup 16}m{sup −3}, which is confirmed with millimeter-wave interferometer. Reduction of the negative ion density is observedmore » at the negative ion extraction, and at that time the electron flow into the ionic plasma region is observed to conserve the charge neutrality. Distribution of the plasma potential is measured in the extraction region in the direction normal to the plasma grid surface with a Langmuir probe, and the results suggest that the sheath is formed at the plasma boundary to the plasma grid to which the bias voltage is applied. The beam extraction should drive the negative ion transport in the ionic plasma across the sheath formed on the extraction surface. Larger reduction of the negative ions at the beam extraction is observed in a region above the extraction aperture on the plasma grid, which is confirmed with 2D image measurement of the Hα emission and cavity ring-down spectroscopy. The electron distribution is also measured near the plasma grid surface. These various properties observed in the ionic plasma are discussed.« less
Molecular Dynamics Simulation of the Three-Dimensional Ordered State in Laser-Cooled Heavy-Ion Beams
NASA Astrophysics Data System (ADS)
Yuri, Yosuke
A molecular dynamics simulation is performed to study the formation of three-dimensional ordered beams by laser cooling in a cooler storage ring. Ultralow-temperature heavy-ion beams are generated by transverse cooling with displaced Gaussian lasers and resonant coupling. A three-dimensional ordered state of the ion beam is attained at a high line density. The ordered beam exhibits several unique characteristics different from those of an ideal crystalline beam.
Assessment of effect of Yb3+ ion pairs on a highly Yb-doped double-clad fibre laser
NASA Astrophysics Data System (ADS)
Vallés, J. A.; Martín, J. C.; Berdejo, V.; Cases, R.; Álvarez, J. M.; Rebolledo, M. Á.
2018-03-01
Using a previously validated characterization method based on the careful measurement of the characteristic parameters and fluorescence emission spectra of a highly Yb-doped double-clad fibre, we evaluate the contribution of ion pair induced processes to the output power of a double-clad Yb-doped fibre ring laser. This contribution is proved to be insignificant, contrary to analysis by other authors, who overestimate the role of ion pairs.
Liao, Jianjun; Zhang, Junping; Wang, Cai-Zhuang; Lin, Shiwei
2018-08-31
In order to further improve the electroanalytical performance toward heavy metal ions, core-ring structured NiCo 2 O 4 nanoplatelets were used to modify glass carbon electrode (GCE) for the determination of heavy metal ions in water. Owing to the high surface area of NiCo 2 O 4 nanoplatelets, the Pb(II) sensitivity increased by a factor of 1.70, and the detection limit decreased by a factor of 2.64 as compared to solid NiCo 2 O 4 nanoparticles modified GCE. Interestingly, NiCo 2 O 4 nanoplatelets showed different sensitivities toward heavy metal ions with the same valence states, following the order Pb(II) > Cd(II) > Hg(II) > Cu(II). To better and scientifically understand the difference in sensitivity, adsorption and desorption abilities were integrated into account. Density functional theory calculations verified that the adsorption capability of NiCo 2 O 4 toward Pb(II) was strongest among all heavy metal ions, thereby resulting in the largest sensitivity. Further desorption current measurements indicated the large desorption barrier of Cu(II) was another important factor leading to its lowest sensitivity. Finally, the applicability of the proposed method was demonstrated by the detection of heavy metal ions in real seawater. Copyright © 2018 Elsevier B.V. All rights reserved.
Lomozik, L; Gasowska, A; Krzysko, G
2006-11-01
The interactions of Cu(II) ions with adenosine-5'-monophosphate (AMP), cytidine-5'-monophosphate (CMP) and 1,12-diamino-4,9-dioxadodecane (OSpm) were studied. A potentiometric method was applied to determine the composition and stability constants of complexes formed, while the mode of interactions was analysed by spectral methods (ultraviolet and visible spectroscopy (UV-Vis), electron paramagnetic resonance (EPR), (13)C NMR, (31)P NMR). In metal-free systems, molecular complexes nucleotide-polyamine (NMP)H(x)(OSpm) were formed. The endocyclic nitrogen atoms of the purine ring N(1), N(7), the nitrogen atom of the pyrimidine ring N(3), the oxygen atoms of the phosphate group of the nucleotide and the protonated nitrogen atoms of the polyamine were the reaction centres. The mode of interaction of the metal ion with OSpm and the nucleotides (AMP or CMP) in the coordination compounds was established. In the system Cu(II)/OSpm the dinuclear complex Cu(2)(OSpm) forms, while in the ternary systems Cu(II)/nucleotide/OSpm the species type MH(x)LL' and MLL' appear. In the MH(x)LL' type species, the main centres of copper (II) ion binding in the nucleotide are the phosphate groups. The protonated amino groups of OSpm are involved in non-covalent interaction with the nitrogen atoms N(1), N(7) or N(3) of the purine or pyrimidine ring, whereas at higher pH, deprotonated nitrogen atoms of polyamine are engaged in metallation in MLL' species.
NASA Astrophysics Data System (ADS)
Kubes, P.; Paduch, M.; Sadowski, M. J.; Cikhardt, J.; Cikhardtova, B.; Klir, D.; Kravarik, J.; Munzar, V.; Rezac, K.; Zielinska, E.; Skladnik-Sadowska, E.; Szymaszek, A.; Tomaszewski, K.; Zaloga, D.
2018-01-01
This paper considers regions of a fast deuteron production in a correlation with an evolution of ordered structures inside a pinch column of a mega-ampere plasma focus discharge. Ion pinhole cameras equipped with plastic PM-355 track-detectors recorded fast deuterons escaping in the downstream and other directions (up to 60° to the z-axis). Time-integrated ion images made it possible to estimate sources of the deuteron acceleration at the known magnetic field and deuteron energy values. The images of the fast deuterons emitted in the solid angle ranging from 0° to 4° showed two forms: central spots and circular images. The spots of 1-2 cm in diameter were produced by deuterons from the central pinch regions. The circular-shaped images of a radius above 3 cm (or their parts) were formed by deuterons from the region surrounding the dense pinch column. The ion pinhole cameras placed at angles above 20° to the z-axis recorded the ion spots only, and the ring-images were missing. The central region of the deuteron acceleration could be associated mainly with plasmoids, and the circular images could be connected with ring-shaped regions of the radius corresponding to tops of the plasma lobules outside the dense pinch column. The deuteron tracks forming ring-shaped images of a smaller (0.5-1) cm radius could be produced by deflections of the fast deuterons, which were caused by a magnetic field inside the dense pinch column.
NASA Astrophysics Data System (ADS)
Malik, Pragati; Kakkar, Rita
2018-04-01
A computational study on the structural and electronic properties of a special class of artificial atoms, known as quantum dots, has been carried out. These are semiconductors with unique optical and electronic properties and have been widely used in various applications, such as bio-sensing, bio-imaging, and so on. We have considered quantum dots belonging to II-VI types of semiconductors, due to their wide band gap, possession of large exciton binding energies and unique optical and electronic properties. We have studied their applications as chemical ion sensors by beginning with the study of the ion sensing ability of (CdSe) n ( n = 3, 6, 9 which are in the size range of 0.24, 0.49, 0.74 nm, respectively) quantum dots for cations of the zinc triad, namely Zn2+, Cd2+, Hg2+, and various anions of biological and environmental importance, and studied the effect of increasing number of rings on their ion sensing ability. The various structural, electronic, and optical properties, their interaction energies, and charge transfer on interaction with metal ions and anions have been calculated and reported. Our studies indicate that the CdSe quantum dots can be employed as sensors for both divalent cations and anions, but they can sense cations better than anions.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bordonali, L.; Borsa, F.; Consorzio INSTM, Via Giusti 9, I-50121 Firenze
2014-04-14
A detailed experimental investigation of the {sup 19}F nuclear magnetic resonance is made on single crystals of the homometallic Cr{sub 8} antiferromagnetic molecular ring and heterometallic Cr{sub 7}Cd and Cr{sub 7}Ni rings in the low temperature ground state. Since the F{sup −} ion is located midway between neighboring magnetic metal ions in the ring, the {sup 19}F-NMR spectra yield information about the local electronic spin density and {sup 19}F hyperfine interactions. In Cr{sub 8}, where the ground state is a singlet with total spin S{sub T} = 0, the {sup 19}F-NMR spectra at 1.7 K and low external magnetic fieldmore » display a single narrow line, while when the magnetic field is increased towards the first level crossing field, satellite lines appear in the {sup 19}F-NMR spectrum, indicating a progressive increase in the Boltzmann population of the first excited state S{sub T} = 1. In the heterometallic rings, Cr{sub 7}Cd and Cr{sub 7}Ni, whose ground state is magnetic with S{sub T} = 3/2 and S{sub T} = 1/2, respectively, the {sup 19}F-NMR spectrum has a complicated structure which depends on the strength and orientation of the magnetic field, due to both isotropic and anisotropic transferred hyperfine interactions and classical dipolar interactions. From the {sup 19}F-NMR spectra in single crystals we estimated the transferred hyperfine constants for both the F{sup −}-Ni{sup 2+} and the F{sup −}-Cd{sup 2+} bonds. The values of the hyperfine constants compare well to the ones known for F{sup −}-Ni{sup 2+} in KNiF{sub 3} and NiF{sub 2} and for F{sup −}-Cr{sup 3+} in K{sub 2}NaCrF{sub 6}. The results are discussed in terms of hybridization of the 2s, 2p orbitals of the F{sup −} ion and the d orbitals of the magnetic ion. Finally, we discuss the implications of our results for the electron-spin decoherence.« less
Improvement of ion thruster design
NASA Technical Reports Server (NTRS)
Carpenter, R. T.
1986-01-01
Two types of measurements were performed on ion thrustors equipped with SmCo magnets in either ring cusp or line cusp arrangements. Langmuir probes were used to measure plasma potential, electron density, and electron temperture in all regions inside the thruster. Loss fluxes to various surfaces were determined by measuring the currents to foils attached to or imbedded in the surface. Data were obtained for several sets of discharge voltages and currents. The loss currents were determined from current vs voltage characteristics observed on a transistor curve tracer oscilloscope. Both ion and electron currents were measured to all parts of the walls and to all parts of the cathode assembly using collecting plates. These measurement were also made for various parameter sets. In line cusp configuration the plasma density is essentially as predicted by existing calculations. In the ring cusp arrangement the interior of the plasma contains an inhomogeneous and relatively large magnetic field so the geometry is decidely two-dimensional and the models of Self (1967) and of Kino and Sham (1966) do not agree.
Adarsh, N. N.; Dastidar, Parthasarathi
2010-01-01
In the title coordination polymer, {[Zn(SO4)(C18H16N6O2)(H2O)3]·CH3OH·H2O}n, the Zn2+ ion adopts a slightly distorted cis-ZnN2O4 octahedral geometry arising from three coordinated water molecules, one sulfate ion and two bridging 3,3′-bis(3-pyridyl)-1,1′-(m-phenylene)diurea (bpmpbu) ligands. The dihedral angles between the central benzene ring and two terminal pyridine rings of the bpmbpu molecule are 10.58 (17) and 34.63 (16)°. In the crystal, the ligands bridge the ZnII ions, thus generating a one-dimensional zigzag coordination polymer propagating in [010]. The crystal structure features extensive N—H⋯O and O—H⋯O hydrogen-bonding interactions. PMID:21580512
A study of small impact parameter ion channeling effects in thin crystals
NASA Astrophysics Data System (ADS)
Motapothula, Mallikarjuna Rao; Breese, Mark B. H.
2018-03-01
We have recorded channeling patterns produced by 1-2 MeV protons aligned with ⟨1 1 1⟩ axes in 55 nm thick silicon crystals which exhibit characteristic angular structure for deflection angles up to and beyond the axial critical angle, ψ a . Such large angular deflections are produced by ions incident on atomic strings with small impact parameters, resulting in trajectories which pass through several radial rings of atomic strings before exiting the thin crystal. Each ring may focus, steer or scatter the channeled ions in the transverse direction and the resulting characteristic angular structure beyond 0.6 ψ a at different depths can be related to peaks and troughs in the nuclear encounter probability. Such "radial focusing" underlies other axial channeling phenomena in thin crystals including planar channeling of small impact parameter trajectories, peaks around the azimuthal distribution at small tilts and large shoulders in the nuclear encounter probability at tilts beyond ψ a .
Intra-pulse transition between ion acceleration mechanisms in intense laser-foil interactions
DOE Office of Scientific and Technical Information (OSTI.GOV)
Padda, H.; King, M.; Gray, R. J.
Multiple ion acceleration mechanisms can occur when an ultrathin foil is irradiated with an intense laser pulse, with the dominant mechanism changing over the course of the interaction. Measurement of the spatial-intensity distribution of the beam of energetic protons is used to investigate the transition from radiation pressure acceleration to transparency-driven processes. It is shown numerically that radiation pressure drives an increased expansion of the target ions within the spatial extent of the laser focal spot, which induces a radial deflection of relatively low energy sheath-accelerated protons to form an annular distribution. Through variation of the target foil thickness, themore » opening angle of the ring is shown to be correlated to the point in time transparency occurs during the interaction and is maximized when it occurs at the peak of the laser intensity profile. Corresponding experimental measurements of the ring size variation with target thickness exhibit the same trends and provide insight into the intra-pulse laser-plasma evolution.« less
NASA Astrophysics Data System (ADS)
Hamilton, D. C.; Christon, S. P.
2017-12-01
In mid-2014 the Cassini/CHEMS instrument observed a rather dramatic increase in the relative abundances of both C+ and CO+ (factors of 2 to 4). The enhancements then decreased during 2015 and 2016, with CO+ decreasing much more quickly. C+ and CO+ (these mass 28 molecular ions could also include N2+) are trace components of the energetic (96-220 keV) ion population in Saturn's magnetosphere, which is dominated by water group ions W+ (O+, OH+, and H2O+ and H30+), H+, and H2+. We suggest that the C+ and CO+ enhancements are associated with CO2, possibly from Enceladus, building up on the cold rings near equinox, but then released from the north side of the A, and possibly B, rings as they were warmed above 80K in late 2013 or early 2014 by increasing solar illumination after the 2009 equinox (Morishima et al, 2016). Hodyss et al (2008) found preferential sublimation of CO2 from a CO2:H2O ice mixture when it was warmed above 80K. Meteoroid bombardment could be another source of carbon in the ring ice. After release from the ice, transport, dissociation, ionization, and then acceleration in the magnetosphere would produce the observed energetic C+ and CO+, with the enhancements subsiding as the CO2 and other carbon species gradually become depleted. We will report the relevant abundance ratios from SOI in 2004 through the Sept. 15, 2017 end of mission to test this hypothesis. Hodyss, R. et al, Icarus, 194, 836-842, 2008. Morishima, R. et al, Icarus, 279, 2-19, 2016.
HEATHER - HElium Ion Accelerator for RadioTHERapy
DOE Office of Scientific and Technical Information (OSTI.GOV)
Taylor, Jordan; Edgecock, Thomas; Green, Stuart
2017-05-01
A non-scaling fixed field alternating gradient (nsFFAG) accelerator is being designed for helium ion therapy. This facility will consist of 2 superconducting rings, treating with helium ions (He²⁺ ) and image with hydrogen ions (H + 2 ). Currently only carbon ions are used to treat cancer, yet there is an increasing interest in the use of lighter ions for therapy. Lighter ions have reduced dose tail beyond the tumour compared to carbon, caused by low Z secondary particles produced via inelastic nuclear reactions. An FFAG approach for helium therapy has never been previously considered. Having demonstrated isochronous acceleration frommore » 0.5 MeV to 900 MeV, we now demonstrate the survival of a realistic beam across both stages.« less
García Marrero, Danny E; Glasser, Wolfgang G; Pizzi, Antonio; Paczkowski, Sebastian; Laborie, Marie-Pierre G
2014-10-01
The structure of condensed tannins (CTs) from Pinus pinaster bark extract and their hydroxypropylated derivatives with four degrees of substitution (DS 1, 2, 3 and 4) has been characterized for the first time using negative-ion mode electrospray ionization tandem mass spectrometry (ESI(-)-MS/MS). The results showed that P. pinaster bark CTs possess structural homogeneity in terms of monomeric units (C(15), catechin). The oligomer sizes were detected to be dimers to heptamers. The derivatives showed typical phenyl-propyl ether mass fragmentation by substituent elimination (58 amu) and inherent C(15) flavonoid fissions. The relative abundance of the product ions revealed a preferential triple, tetra-/penta- and octa- hydroxypropylation substitution pattern in the monomer, dimer and trimer derivatives, respectively. A defined order of -OH reactivity towards propylene oxide was established by means of multistage experiments (A-ring ≥ B-ring > C-ring). A high structural heterogeneity of the modified oligomers was detected. Copyright © 2014 John Wiley & Sons, Ltd.
NASA Astrophysics Data System (ADS)
Lopatin, V. S.; Remnev, G. E.; Martynenko, A. A.
2017-05-01
We have studied the collective acceleration of protons and deuterons in an electron beam emitted from plasma formed at the surface of a dielectric anode insert. The experiments were performed with a pulsed electron accelerator operating at an accelerating voltage up to 1 MV, current amplitude up to 40 kA, and pulse duration of 50 ns. Reduction of the accelerating voltage pulse front width and optimization of the diode unit and drift region ensured the formation of several annular structures in the electron beam. As a result, up to 50% of the radioactivity induced in a copper target was concentrated in a ring with 4.5-cm diameter and 0.2-cm width. The formation of high energy density in these circular traces and the appearance of an axial component of the self-generated magnetic field of the electron beam are related with the increasing efficiency of acceleration of the most intense group of ions.
Precise Lamb Shift Measurements in Hydrogen-Like Heavy Ions—Status and Perspectives
NASA Astrophysics Data System (ADS)
Andrianov, V.; Beckert, K.; Bleile, A.; Chatterjee, Ch.; Echler, A.; Egelhof, P.; Gumberidze, A.; Ilieva, S.; Kiselev, O.; Kilbourne, C.; Kluge, H.-J.; Kraft-Bermuth, S.; McCammon, D.; Meier, J. P.; Reuschl, R.; Stöhlker, T.; Trassinelli, M.
2009-12-01
The precise determination of the energy of the Lyman α1 and α2 lines in hydrogen-like heavy ions provides a sensitive test of quantum electrodynamics in very strong Coulomb fields. For the first time, a calorimetric low-temperature detector was applied in an experiment to precisely determine the transition energy of the Lyman lines of lead ions 207Pb81+ at the Experimental Storage Ring (ESR) at GSI. The detectors consist of silicon thermistors, provided by the NASA/Goddard Space Flight Center, and Pb or Sn absorbers to obtain high quantum efficiency in the energy range of 40-80 keV, where the Doppler-shifted Lyman lines are located. The measured energy of the Lyman α1 line, E(Ly-α1, 207Pb81+) = (77937±12stat±23syst) eV, agrees within errors with theoretical predictions. The systematic error is mainly due to uncertainties in the non-linear energy calibration of the detectors as well as the relative position of detector and gas-jet target.
Steffen, K T; Hofrichter, M; Hatakka, A
2000-12-01
Within a screening program, 27 soil litter-decomposing basidiomycetes were tested for ligninolytic enzyme activities using agar-media containing 2,2'-azinobis(3-ethylbenzthiazoline-6-sulphonate), a humic acid or Mn2+ ions as indicator substrates. Most active species were found within the family Strophariaceae (Agrocybe praecox, Stropharia coronilla, S. rugosoannulata) and used for mineralisation experiments with a 14C-ring-labelled synthetic lignin (14C-DHP). The fungi mineralised around 25% of the lignin to 14CO2 within 12 weeks of incubation in a straw environment; about 20% of the lignin was converted to water-soluble fragments. Mn-peroxidase was found to be the predominant ligninolytic enzyme of all three fungi in liquid culture and its production was strongly enhanced in the presence of Mn2+ ions. The results of this study demonstrate that certain ubiquitous litter-decomposing basidiomycetes possess ligninolytic activities similar to the wood-decaying white-rot fungi, the most efficient lignin degraders in nature.
Crystal structures of two cross-bridged chromium(III) tetraazamacrocycles
Prior, Timothy J.; Maples, Danny L.; Maples, Randall D.; Hoffert, Wesley A.; Parsell, Trenton H.; Silversides, Jon D.; Archibald, Stephen J.; Hubin, Timothy J.
2014-01-01
The crystal structure of dichlorido(4,10-dimethyl-1,4,7,10-tetraazabicyclo[5.5.2]tetradecane)chromium(III) hexafluoridophosphate, [CrCl2(C12H26N4)]PF6, (I), has monoclinic symmetry (space group P21/n) at 150 K. The structure of the related dichlorido(4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane)chromium(III) hexafluoridophosphate, [CrCl2(C14H30N4)]PF6, (II), also displays monoclinic symmetry (space group P21/c) at 150 K. In each case, the CrIII ion is hexacoordinate with two cis chloride ions and two non-adjacent N atoms bound cis equatorially and the other two non-adjacent N atoms bound trans axially in a cis-V conformation of the macrocycle. The extent of the distortion from the preferred octahedral coordination geometry of the CrIII ion is determined by the parent macrocycle ring size, with the larger cross-bridged cyclam ring in (II) better able to accommodate this preference and the smaller cross-bridged cyclen ring in (I) requiring more distortion away from octahedral geometry. PMID:25309165
Binoy, J; Marchewka, M K; Jayakumar, V S
2013-03-01
The molecular geometry and vibrational spectral investigations of melaminium formate, a potential material known for toxicity and NLO activity, has been performed. The FT IR and FT Raman spectral investigations of melaminium formate is performed aided by the computed spectra of melaminium formate, triazine, melamine, melaminium and formate ion, along with bond orders and PED, computed using the density functional method (B3LYP) with 6-31G(d) basis set and XRD data, to reveal intermolecular interactions of amino groups with neighbor formula units in the crystal, intramolecular H⋯H repulsion of amino group hydrogen with protonating hydrogen, consequent loss of resonance in the melaminium ring, restriction of resonance to N(3)C(1)N(1) moiety leading to special type resonance of the ring and the resonance structure of CO(2) group of formate ion. The 3D matrix of hyperpolarizability tensor components has been computed to quantify NLO activity of melamine, melaminium and melaminium formate and the hyperpolarizability enhancement is analyzed using computed plots of HOMO and LUMO orbitals. A new mechanism of proton transfer responsible for NLO activity has been suggested, based on anomalous IR spectral bands in the high wavenumber region. The computed MEP contour maps have been used to analyze the interaction of melaminium and formate ions in the crystal. Copyright © 2012 Elsevier B.V. All rights reserved.