The MEDA's Radiometer TIRS for the MARS2020 Mission

NASA Astrophysics Data System (ADS)

Pérez Izquierdo, Joel; Sebastián Martínez, Eduardo; Bravo, Andrés; Ferrándiz, Ricardo; Ramos, Miguel; Martínez, Germán; Rodríguez Manfredi, Jose Antonio

2016-10-01

The TIRS (Thermal InfraRed Sensor) instrument is one of the payloads of NASA MARS2020 mission, that is expected to take off in 2020, and is designed to operate for at least three Martian years on surface. The TIRS is part of the Mars Environmental Dynamics Analyzer (MEDA), formed for other environmental sensors, which will be placed in the MARS2020 Rover, and is been developing by the Spanish Center of Astrobiology (CAB).The main objectives of MEDA's Thermal InfraRed Sensor are:-Characterize the net radiative forcing (within 10%), and constrain the conductive forcing at the local surface and near-surface atmosphere.-Record the surface skin temperature and the UV-VIS-NIR irradiance solar flux at an accuracy of [10%] at full range of the atmosphere.TIRS design has heritage from GTS-REMS on the Mars Science Laboratory, in the Curiosity Rover. The aim of the instrument is to measure the radiative flux emitted from the Martian surface, sky and the CO2 atmosphere using five thermopiles sensors in four wavelength bands, model TS100 provided by IPHT (Institute of Photonic Technology, Jena, Germany). The TIRS has three downward pointing thermopiles to measure the IR fluxes emitted by the surface, separating brightness surface temperature from emissivity and surface reflected upward short wave radiation, using the thermopiles IR3 (0.3-3 µm), IR4 (6.5-inf µm), IR5 (8-14 µm). Additionally, it has two more thermopiles pointing to the sky, the thermopiles IR1 (6.5-inf µm) and IR2 (14.5-15.5 µm), which captures the downward fluxes of thermal infrared radiation and air temperature nearby the sensor.Thermopiles are accommodated inside a mechanical assembly that is designed to ensure a low thermal gradient. This assembly also accommodates a calibration plate, aimed to intercept part of the thermopiles FOV, and capable to do an in-flight recalibration.

Comparing Geophysical Methods for Determining the Thickness of Arctic Sea Ice: Is There a Correlation Between Thickness and Surface Temperature?

NASA Astrophysics Data System (ADS)

Robertson, R.; Bowman, T.; Eagle, J. L.; Fisher, L.; Mankowski, K.; McGrady, N.; Schrecongost, N.; Voll, H.; Zulfiqar, A.; Herman, R. B.

2016-12-01

Several small geophysical surveys were conducted on the Chukchi Sea ice just offshore from the Naval Arctic Research Laboratory near Barrow, Alaska, in March, 2016. The goal was to investigate a possible correlation between the surface temperature and the thickness of the sea ice, as well as to test a potential new method for more accurately determining ice thickness. Surveys were conducted using a capacitively coupled resistivity array, a custom built thermal sensor array sled, ground penetrating radar (GPR), and an ice drill. The thermal sensor array was based on an Arduino microcontroller. It used an infrared (IR) sensor to determine surface temperature, and thermistor-based sensors to determine vertical air temperatures at 6 evenly spaced heights up to a maximum of 1.5 meters. Surface temperature (IR) data show possible correlations with ice drill, resistivity, and GPR data. The vertical air sensors showed almost no variation for any survey line which we postulate is due to the constant wind during each survey. Ice drill data show ice thickness along one 200 meter line varied from 79-95 cm, with an average of 87 cm. The thickness appears to be inversely correlated to surface temperatures. Resistivity and IR data both showed abrupt changes when crossing from the shore to the sea ice along a 400 meter line. GPR and IR data showed similar changes along a separate 900 meter line, suggesting that surface temperature and subsurface composition are related. Resistivity data were obtained in two locations by using the array in an expanding dipole-dipole configuration with 2.5 meter dipoles. The depth to the ice/water boundary was calculated using a "cumulative resistivity" plot and matched the depths obtained via the ice drill to within 2%. This has initiated work to develop a microcontroller-based resistivity array specialized for thickness measurements of thin ice.

Water Plume Temperature Measurements by an Unmanned Aerial System (UAS)

PubMed Central

DeMario, Anthony; Lopez, Pete; Plewka, Eli; Wix, Ryan; Xia, Hai; Zamora, Emily; Gessler, Dan; Yalin, Azer P.

2017-01-01

We report on the development and testing of a proof of principle water temperature measurement system deployed on an unmanned aerial system (UAS), for field measurements of thermal discharges into water. The primary elements of the system include a quad-copter UAS to which has been integrated, for the first time, both a thermal imaging infrared (IR) camera and an immersible probe that can be dipped below the water surface to obtain vertical water temperature profiles. The IR camera is used to take images of the overall water surface to geo-locate the plume, while the immersible probe provides quantitative temperature depth profiles at specific locations. The full system has been tested including the navigation of the UAS, its ability to safely carry the sensor payload, and the performance of both the IR camera and the temperature probe. Finally, the UAS sensor system was successfully deployed in a pilot field study at a coal burning power plant, and obtained images and temperature profiles of the thermal effluent. PMID:28178215

Water Plume Temperature Measurements by an Unmanned Aerial System (UAS).

PubMed

DeMario, Anthony; Lopez, Pete; Plewka, Eli; Wix, Ryan; Xia, Hai; Zamora, Emily; Gessler, Dan; Yalin, Azer P

2017-02-07

We report on the development and testing of a proof of principle water temperature measurement system deployed on an unmanned aerial system (UAS), for field measurements of thermal discharges into water. The primary elements of the system include a quad-copter UAS to which has been integrated, for the first time, both a thermal imaging infrared (IR) camera and an immersible probe that can be dipped below the water surface to obtain vertical water temperature profiles. The IR camera is used to take images of the overall water surface to geo-locate the plume, while the immersible probe provides quantitative temperature depth profiles at specific locations. The full system has been tested including the navigation of the UAS, its ability to safely carry the sensor payload, and the performance of both the IR camera and the temperature probe. Finally, the UAS sensor system was successfully deployed in a pilot field study at a coal burning power plant, and obtained images and temperature profiles of the thermal effluent.

Near-surface temperature inversion during summer at Summit, Greenland, and its relation to MODIS-derived surface temperatures

NASA Astrophysics Data System (ADS)

Adolph, Alden C.; Albert, Mary R.; Hall, Dorothy K.

2018-03-01

As rapid warming of the Arctic occurs, it is imperative that climate indicators such as temperature be monitored over large areas to understand and predict the effects of climate changes. Temperatures are traditionally tracked using in situ 2 m air temperatures and can also be assessed using remote sensing techniques. Remote sensing is especially valuable over the Greenland Ice Sheet, where few ground-based air temperature measurements exist. Because of the presence of surface-based temperature inversions in ice-covered areas, differences between 2 m air temperature and the temperature of the actual snow surface (referred to as skin temperature) can be significant and are particularly relevant when considering validation and application of remote sensing temperature data. We present results from a field campaign extending from 8 June to 18 July 2015, near Summit Station in Greenland, to study surface temperature using the following measurements: skin temperature measured by an infrared (IR) sensor, 2 m air temperature measured by a National Oceanic and Atmospheric Administration (NOAA) meteorological station, and a Moderate Resolution Imaging Spectroradiometer (MODIS) surface temperature product. Our data indicate that 2 m air temperature is often significantly higher than snow skin temperature measured in situ, and this finding may account for apparent biases in previous studies of MODIS products that used 2 m air temperature for validation. This inversion is present during our study period when incoming solar radiation and wind speed are both low. As compared to our in situ IR skin temperature measurements, after additional cloud masking, the MOD/MYD11 Collection 6 surface temperature standard product has an RMSE of 1.0 °C and a mean bias of -0.4 °C, spanning a range of temperatures from -35 to -5 °C (RMSE = 1.6 °C and mean bias = -0.7 °C prior to cloud masking). For our study area and time series, MODIS surface temperature products agree with skin surface temperatures better than previous studies indicated, especially at temperatures below -20 °C, where other studies found a significant cold bias. We show that the apparent cold bias present in other comparisons of 2 m air temperature and MODIS surface temperature may be a result of the near-surface temperature inversion. Further investigation of how in situ IR skin temperatures compare to MODIS surface temperature at lower temperatures (below -35 °C) is warranted to determine whether a cold bias exists for those temperatures.

Estimate of the influence of muzzle smoke on function range of infrared system

NASA Astrophysics Data System (ADS)

Luo, Yan-ling; Wang, Jun; Wu, Jiang-hui; Wu, Jun; Gao, Meng; Gao, Fei; Zhao, Yu-jie; Zhang, Lei

2013-09-01

Muzzle smoke produced by weapons shooting has important influence on infrared (IR) system while detecting targets. Based on the theoretical model of detecting spot targets and surface targets of IR system while there is muzzle smoke, the function range for detecting spot targets and surface targets are deduced separately according to the definition of noise equivalent temperature difference(NETD) and minimum resolution temperature difference(MRTD). Also parameters of muzzle smoke affecting function range of IR system are analyzed. Base on measured data of muzzle smoke for single shot, the function range of an IR system for detecting typical targets are calculated separately while there is muzzle smoke and there is no muzzle smoke at 8-12 micron waveband. For our IR system function range has reduced by over 10% for detecting tank if muzzle smoke exists. The results will provide evidence for evaluating the influence of muzzle smoke on IR system and will help researchers to improve ammo craftwork.

Growth and phase transformations of Ir on Ge(111)

NASA Astrophysics Data System (ADS)

Mullet, C. H.; Stenger, B. H.; Durand, A. M.; Morad, J. A.; Sato, Y.; Poppenheimer, E. C.; Chiang, S.

2017-12-01

The growth of Ir on Ge(111) as a function of temperature between 23 °C and 820 °C is characterized with low energy electron microscopy (LEEM), low energy electron diffraction (LEED), scanning tunneling microscopy (STM), and x-ray photoemission spectroscopy (XPS). Deposition onto a substrate at 350 °C revealed a novel growth mode consisting of multilayer Ir islands with (√3 × √3)R30° (abbreviated as √3) structure interconnected by ;bridges; of single-layer Ir several atoms wide. For deposition onto substrates above 500 °C, the √3 Ir phase grows with dendritic morphology, and substrate step bunches act as barriers to √3 Ir growth. LEEM images showed Stranski-Krastanov growth for 650-820 °C: after the √3 phase covers the surface, corresponding to 2 monolayers (ML) Ir coverage, multilayer hexagonal-shaped Ir islands form, surrounded by regions of IrGe alloy. Hexagonal-shaped Ir islands also formed upon heating 1.2 ML of √3 Ir beyond 830 °C, which resulted in the elimination of √3 structure from the surface. The transformation from √3 to (1 × 1) structure upon heating to 830 °C was an irreversible surface phase transition. Annealing > 2.0 ML of Ir in the √3 phase above the 830 °C disorder temperature, followed by cooling, produced a (3 × 1) structure. Subsequent heating and cooling through 830 °C give evidence for a reversible (3 × 1) to (1 × 1) phase transition.

Airflow analyses using thermal imaging in Arizona's Meteor Crater as part of METCRAX II

NASA Astrophysics Data System (ADS)

Grudzielanek, A. Martina; Vogt, Roland; Cermak, Jan; Maric, Mateja; Feigenwinter, Iris; Whiteman, C. David; Lehner, Manuela; Hoch, Sebastian W.; Krauß, Matthias G.; Bernhofer, Christian; Pitacco, Andrea

2016-04-01

In October 2013 the second Meteor Crater Experiment (METCRAX II) took place at the Barringer Meteorite Crater (aka Meteor Crater) in north central Arizona, USA. Downslope-windstorm-type flows (DWF), the main research objective of METCRAX II, were measured by a comprehensive set of meteorological sensors deployed in and around the crater. During two weeks of METCRAX II five infrared (IR) time lapse cameras (VarioCAM® hr research & VarioCAM® High Definition, InfraTec) were installed at various locations on the crater rim to record high-resolution images of the surface temperatures within the crater from different viewpoints. Changes of surface temperature are indicative of air temperature changes induced by flow dynamics inside the crater, including the DWF. By correlating thermal IR surface temperature data with meteorological sensor data during intensive observational periods the applicability of the IR method of representing flow dynamics can be assessed. We present evaluation results and draw conclusions relative to the application of this method for observing air flow dynamics in the crater. In addition we show the potential of the IR method for METCRAX II in 1) visualizing airflow processes to improve understanding of these flows, and 2) analyzing cold-air flows and cold-air pooling.

Dryland pasture and crop conditions as seen by HCMM. [Washita River watershed

NASA Technical Reports Server (NTRS)

Harlan, J. C. (Principal Investigator); Rosenthal, W. D.; Blanchard, B. J.

1981-01-01

The antecedent precipitation index (API) was related to surface temperatures as measured from the NASA C-130 and HCMM thermal data. Significant results from the aircraft flight in May 1978, include: (1) canopy temperature were measured accurately remotely; (2) pasture surface temperatures were related to pasture and wheat soil moisture conditions; (3) no relationship was developed with that data set between wheat yield and thermal infrared data due to a lack of moisture stress during the measurement period; and (4) lake surface temperatures were useful in normalizing the thermal IR data. Results from HCMM also suggested a relationship between thermal IR data and antecedent precipitation index. While HCMM was adequate in detecting relative soil moisture differences, the overpass timing was infrequent and prevented detailed analysis of the API/thermal relationship.

Porous carbon materials synthesized using IRMOF-3 and furfuryl alcohol as precursor

NASA Astrophysics Data System (ADS)

Deka, Pemta Tia; Ediati, Ratna

2016-03-01

IRMOF-3 crystals have been synthesized using solvothermal method by adding zinc nitrate hexahydrate with 2-amino-1,4-benzenedicarboxylic acid in N'N-dimethylformamide (DMF) at 100°C for 24 (note as IR-24) and 72 h (note as IR-72). The obtained crystals were characterized using X-ray Diffraction (XRD), SEM (Scanning Electron Microscopy) and Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDX), FTIR and Isothermal adsorption-desorption N2. The diffractogram solids synthesized show characteristic peak at 2θ 6.8, 9.6 and 13.7°. SEM micrograph show cubic shape of IRMOF-3 crystal. Based on FTIR characterization, IRMOF-3 appear at wavelength (1691,46; 1425,3; 1238,21; 1319,22 dan 3504,42)cm-1. The Isotherm of crystal IRMOF-3 at heating time 24 h and 72 h are type IV. The surface area of IR-24 and IR-72 are respectively 24,758 m2/g and 29,139 m2/g with its dominant mesopores. Carbonaceous materials has been successfully synthesized using IR-24, IR-72 and furfuryl alcohol (FA) as second carbon precursor with variation of carbonation temperature 550, 700 and 850°C. The XRD result from both carbonaceous materials show formation of amorphous carbon and caharacteristic peak of ZnO oxide. Micrograph SEM show that carbonaceous materials have cubic shape as IRMOF-3 and SEM-EDX result indicate Zn and nitrogen content of these materials has decrease until temperature 850°C. Porous carbon using IR-24 and FA (notes as C-24) has increased surface area with higher carbonation temperature. The highest surface area is 1495,023 m2/g. Total pore volume and pore size of C-24 from low to high temperature respectively as (0,338; 0,539 and 1,598) cc/g; (0,107; 0,152 and 0,610) cc/g. Porous carbon using IR-72 and FA (notes as C-72) has smaller surface area than C-24 but its also increased during higher carbonation heating. The highest surface area is 1029,668 m2/g.The total pore volume and pore size of these carbon materials from low to high temperature respectively as (0,390; 0,727 and 1,345) cc/g and (0,065; 0,157 and 0,381) cc/g. Carbonaceous materials with high porosity and nitrogen content will be expected increase mechanical properties and hydrogen storage from these materials.

Improving aerosol vertical retrieval for NWP application: Studying the impact of IR-sensed aerosol on data assimilation systems.

NASA Astrophysics Data System (ADS)

Oyola, Mayra; Marquis, Jared; Ruston, Benjamin; Campbell, James; Baker, Nancy; Westphal, Douglas; Zhang, Jianglong; Hyer, Edward

2017-04-01

Radiometric measurements from passive infrared (IR) sensors are important in numerical weather prediction (NWP) because they are sensitive to surface temperatures and atmospheric temperature profiles. However, these measurements are also sensitive to absorbing and scattering constituents in the atmosphere. Dust aerosols absorb in the IR and are found over many global regions with irregular spatial and temporal frequency. Retrievals of temperature using IR data are thus vulnerable to dust-IR radiance biases, most notably over tropical oceans where accurate surface and atmospheric temperatures are critical to accurate prediction of tropical cyclone development. Previous studies have shown that dust aerosols can bias retrieved brightness temperatures (BT) by up to 10K in some IR channels that are assimilated to constrain atmospheric temperature and water vapor profiles. Other BT-derived parameters such as sea surface temperatures (SSTs) are susceptible to negative biases of at least 1K or higher, which conflicts with the accuracy requirement for most research and operational applications (i.e., +/- 0.3 K). This problem is not limited to just satellite retrievals. BT bias also impacts the incorporation of background fields from NWP analyses in data assimilation (DA) systems. The effect of aerosols on IR fluxes at the ocean surface is a function of both aerosol loading and vertical profile. Therefore, knowledge of the aerosol vertical distribution, and understanding of how well this distribution is captured by NWP models, is necessary to ensuring proper treatment of aerosol-affected radiances in both retrieval and data assimilation. This understanding can be achieved by conducting modeling studies and by the exploitation of a robust observational dataset, such as satellite-based lidar profiling, which can be used to characterize aerosol type and distribution. In this talk, we describe such an application using the Navy Aerosol Analysis Prediction System (NAAPS) and Naval Research Laboratory (NRL) Atmospheric Variational Data Assimilation System (NAVDAS). We describe the impact of aerosol-biased radiances on operational DA, and thus the quantitative impact of dust on model profiles of temperature and water vapor mixing ratio before and after data assimilation, using collocated hyperspectral Cross-track Infrared Sounder (CrIs) and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) observations over the Tropical Atlantic. We then describe how the NAVDAS radiance assimilation system responds when coupled with NAAPS dust concentration fields, and thus how the model representation of dust compares with observations.. The result is a conceptual description of how IR-absorbing dust impacts radiance DA for operational weather modeling, and a first-order description of how adept current aerosol transport models are for providing compulsory corrections.

Infrared Imaging Tools for Diagnostic Applications in Dermatology.

PubMed

Gurjarpadhye, Abhijit Achyut; Parekh, Mansi Bharat; Dubnika, Arita; Rajadas, Jayakumar; Inayathullah, Mohammed

Infrared (IR) imaging is a collection of non-invasive imaging techniques that utilize the IR domain of the electromagnetic spectrum for tissue assessment. A subset of these techniques construct images using back-reflected light, while other techniques rely on detection of IR radiation emitted by the tissue as a result of its temperature. Modern IR detectors sense thermal emissions and produce a heat map of surface temperature distribution in tissues. Thus, the IR spectrum offers a variety of imaging applications particularly useful in clinical diagnostic area, ranging from high-resolution, depth-resolved visualization of tissue to temperature variation assessment. These techniques have been helpful in the diagnosis of many medical conditions including skin/breast cancer, arthritis, allergy, burns, and others. In this review, we discuss current roles of IR-imaging techniques for diagnostic applications in dermatology with an emphasis on skin cancer, allergies, blisters, burns and wounds.

Surface characteristics and electrochemical corrosion behavior of NiTi alloy coated with IrO2.

PubMed

Li, M; Wang, Y B; Zhang, X; Li, Q H; Liu, Q; Cheng, Y; Zheng, Y F; Xi, T F; Wei, S C

2013-01-01

The aim of this work is to investigate the surface characteristics and corrosion behavior of NiTi (50.6 at.% Ni) shape memory alloy coated by a ceramic-like and highly biocompatible material, iridium oxide (IrO2). IrO2 coatings were prepared by thermal decomposition of H2IrCl6 · 6H2O precursor solution at the temperature of 300 °C, 400 °C and 500 °C, respectively. The surface morphology and microstructure of the coatings were investigated by scanning electron microscope (SEM) and glancing angle X-ray diffraction (GAXRD). X-ray photoelectron spectroscopy (XPS) was employed to determine the surface elemental composition. Corrosion resistance property of the coated samples was studied in a simulated body fluid at 37±1 °C by electrochemical method. It was found that the morphology and microstructure of the coatings were closely related to the oxidizing temperatures. A relatively smooth, intact and amorphous coating was obtained when the H2IrCl6·6H2O precursor solution (0.03 mol/L) was thermally decomposed at 300 °C for 0.5 h. Compared with the bare NiTi alloy, IrO2 coated samples exhibited better corrosion resistance behavior to some extent. Copyright © 2012 Elsevier B.V. All rights reserved.

Fabrication of IrSi(3)/p-Si Schottky diodes by a molecular beam epitaxy technique

NASA Technical Reports Server (NTRS)

Lin, T. L.; Iannelli, J. M.

1990-01-01

IrSi(3)/p-Si Schottky diodes have been fabricated by a molecular beam epitaxy technique at 630 C. Good surface morphology was observed for IrSi(3) layers grown at temperatures below 680 C, and an increasing tendency to form islands is observed in samples grown at higher temperatures. Good diode current-voltage characteristics were observed and Schottky barrier heights of 0.14-0.18 eV were determined by activation energy analysis and spectral response measurement.

Application of IR imaging for free-surface velocity measurement in liquid-metal systems

DOE PAGES

Hvasta, M. G.; Kolemen, E.; Fisher, A.

2017-01-05

Measuring free-surface, liquid-metal flow velocity is challenging to do in a reliable and accurate manner. This paper presents a non-invasive, easily calibrated method of measuring the surface velocities of open-channel liquid-metal flows using an IR camera. Unlike other spatially limited methods, this IR camera particle tracking technique provides full field-of-view data that can be used to better understand open-channel flows and determine surface boundary conditions. Lastly, this method could be implemented and automated for a wide range of liquid-metal experiments, even if they operate at high-temperatures or within strong magnetic fields.

High-Temperature Oxidation Behavior of Iridium-Rhenium Alloys

NASA Technical Reports Server (NTRS)

Reed, Brian D.

1995-01-01

The life-limiting mechanism for radiation-cooled rockets made from iridium-coated rhenium (Ir/Re) is the diffusion of Re into the Ir layer and the subsequent oxidation of the resulting Ir-Re alloy from the inner surface. In a previous study, a life model for Ir/Re rockets was developed. It incorporated Ir-Re diffusion and oxidation data to predict chamber lifetimes as a function of temperature and oxygen partial pressure. Oxidation testing at 1540 deg C suggested that a 20-wt percent Re concentration at the inner wall surface should be established as the failure criterion. The present study was performed to better define Ir-oxidation behavior as a function of Re concentration and to supplement the data base for the life model. Samples ranging from pure Ir to Ir-40 wt percent Re (Ir-40Re) were tested at 1500 deg C, in two different oxygen environments. There were indications that the oxidation rate of the Ir-Re alloy increased significantly when it went from a single-phase solid solution to a two-phase mixture, as was suggested in previous work. However, because of testing anomalies in this study, there were not enough dependable oxidation data to definitively raise the Ir/Re rocket failure criterion from 20-wt percent Re to a Re concentration corresponding to entry into the two-phase region.

Leveraging Oceanic and Surface Intensive Field Campaign Data Sets for Validation and Improvement of Recent Hyperspectral IR Satellite Data Products

NASA Astrophysics Data System (ADS)

Joseph, E.; Nalli, N. R.; Oyola, M. I.; Morris, V. R.; Sakai, R.

2014-12-01

An overview is given of research to validate or improve the retrieval of environmental data records (EDRs) from recently deployed hyperspectral IR satellite sensors such as Suomi NPP Cross-track Infrared Microwave Sounder Suite (CrIMSS). The effort centers around several surface field intensive campaigns that are designed or leveraged for EDR validation. These data include ship-based observations of upper air ozone, pressure, temperature and relative humidity soundings; aerosol and cloud properties; and sea surface temperature. Similar intensive data from two land-based sites are also utilized as well. One site, the Howard University Beltsville site, is at a single point location but has a comprehensive array of observations for an extended period of time. The other land site, presently being deployed by the University at Albany, is under development with limited upper air soundings but will have regionally distributed surface based microwave profiling of temperature and relative humidity on the scale of 10 - 50 km and other standard meteorological observations. Combined these observations provide data that are unique in their wide range including, a variety of meteorological conditions and atmospheric compositions over the ocean and urban-suburban environments. With the distributed surface sites the variability of atmospheric conditions are captured concurrently across a regional spatial scale. Some specific examples are given of comparisons of moisture and temperature correlative EDRs from the satellite sensors and surface based observations. An additional example is given of the use of this data to correct sea surface temperature (SST) retrieval biases from the hyperspectral IR satellite observations due to aerosol contamination.

Validation of Infrared Azimuthal Model as Applied to GOES Data Over the ARM SGP

NASA Technical Reports Server (NTRS)

Gambheer, Arvind V.; Doelling, David R.; Spangenberg, Douglas A.; Minnis, Patrick

2004-01-01

The goal of this research is to identify and reduce the GOES-8 IR temperature biases, induced by a fixed geostationary position, during the course of a day. In this study, the same CERES LW window channel model is applied to GOES-8 IR temperatures during clear days over the Atmospheric Radiation Measurement-Southern Great Plains Central Facility (SCF). The model-adjusted and observed IR temperatures are compared with topof- the-atmosphere (TOA) estimated temperatures derived from a radiative transfer algorithm based on the atmospheric profile and surface radiometer measurements. This algorithm can then be incorporated to derive more accurate Ts from real-time satellite operational products.

Infrared thermography and thermocouple mapping of radiofrequency renal ablation to assess treatment adequacy and ablation margins.

PubMed

Ogan, Kenneth; Roberts, William W; Wilhelm, David M; Bonnell, Leonard; Leiner, Dennis; Lindberg, Guy; Kavoussi, Louis R; Cadeddu, Jeffrey A

2003-07-01

The primary disadvantage of renal tumor RF ablation is the inability to monitor the intraoperative propagation of the RF lesion with real-time imaging. We sought to assess whether adequately lethal temperatures are obtained at the margins of the intended ablation zone using laparoscopic thermography to monitor radiofrequency (RF) lesions in real time, thermocouple measurements, and histopathologic evaluation. Renal RF lesions were created under direct laparoscopic vision in the upper (1 cm diameter) and lower (2 cm) poles of the right kidney in 5 female pigs. The RF lesions were produced with the RITA generator and probe, set at 105 degrees C for 5-minute ablations. During RF treatment, a laparoscopic infrared (IR) camera measured the surface parenchymal temperatures, as did multiple thermocouples. The pigs were then either immediately killed (n = 3) or allowed to live for 2 weeks (n = 2). The kidneys were removed to correlate the temperature measurements with histologic analysis of the ablated lesion. Using a threshold temperature of greater than 70 degrees C for visual "temperature" color change, the IR camera identified the region of pathologic necrosis of the renal parenchyma during RF ablation. Thermocouple measurements demonstrated that the temperatures at the intended ablation radius reached 77.5 degrees C at the renal surface and 83.7 degrees C centrally, and temperatures 5 mm beyond the set radius reached 52.6 degrees C at the surface and 47.7 degrees C centrally. The average diameter of the gross lesion on the surface of the kidney measured 17.1 mm and 22.4 mm for 1-cm and 2-cm ablations, respectively. These surface measurements correlated with an average diameter of 16.1 mm and 15.9 mm (1-cm and 2-cm ablations, respectively) as measured with the IR camera. All cells within these ablation zones were nonviable by nicotinamide adenine dinucleotide diaphorase analysis. The average depth of the lesions measured 19 mm (1-cm ablation) and 25 mm (2-cm ablation) on gross histologic examination. The laparoscopic IR camera is able to monitor the surface renal temperatures during RF treatment. Thermocouple measurements during RF ablation confirmed the thermographic findings and demonstrated that lethal temperatures at the margin of the intended treatment zone are routinely obtained and that a rapid decline in temperature occurs beyond the predicted ablation margin.

Optical and structural studies of films grown thermally on zirconium surfaces

NASA Astrophysics Data System (ADS)

Morgan, J. M.; McNatt, J. S.; Shepard, M. J.; Farkas, N.; Ramsier, R. D.

2002-06-01

Variable angle IR reflection spectroscopy and atomic force microscopy are used to determine the thickness and morphology of films grown thermally on Zr surfaces in air. The density and homogeneity of these films increases with temperature in the range studied (773-873 K) and growth at the highest temperature follows cubic rate law kinetics. We demonstrate a structure-property relationship for these thermally grown films and suggest the application of IR reflectivity as an inspection method during the growth of environmentally passive films on industrial Zr components.

Layered structure and related magnetic properties for annealed Fe/Ir(111) ultrathin films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jiang, Pei-Cheng; Chen, Wei-Hsiang; Hsieh, Chen-Yuan

2015-05-07

After annealing treatments for fcc-Fe/Ir(111) below 600 K, the surface layers remain pseudomorphic. The Ir(111) substrate plays an important role on the expanded Fe lattice. At temperatures between 750 and 800 K, the surface composition shows a stable state and a c(2 × 4) structure is observed. We discover a layered structure composed of some Fe atoms on the top of a Fe{sub 0.5}Ir{sub 0.5} interfacial alloy supported on the Ir(111) substrate. The competition between the negative formation heat of Fe{sub 0.5}Ir{sub 0.5} and surface free energy of Fe causes the formation of layered structure. The existence of ferromagnetic dead layer coincides with themore » formation of fcc-Fe for ultrathin Fe on Fe{sub 0.5}Ir{sub 0.5}/Ir(111). For Fe films thicker than three monolayers, the linear increase of the Kerr intensity versus the Fe coverage is related to the growing of bcc-Fe on the surface where the Fe layer is incoherent to the underlying Fe{sub 0.5}Ir{sub 0.5}/Ir(111). These results emphasize the importance of the substrate induced strain and layered structure of Fe/Fe{sub 0.5}Ir{sub 0.5}/Ir(111) on the magnetic properties and provide valuable information for future applications.« less

2D surface temperature measurement of plasma facing components with modulated active pyrometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Amiel, S.; Loarer, T.; Pocheau, C.

2014-10-01

In nuclear fusion devices, such as Tore Supra, the plasma facing components (PFC) are in carbon. Such components are exposed to very high heat flux and the surface temperature measurement is mandatory for the safety of the device and also for efficient plasma scenario development. Besides this measurement is essential to evaluate these heat fluxes for a better knowledge of the physics of plasma-wall interaction, it is also required to monitor the fatigue of PFCs. Infrared system (IR) is used to manage to measure surface temperature in real time. For carbon PFCs, the emissivity is high and known (ε ~more » 0.8), therefore the contribution of the reflected flux from environment and collected by the IR cameras can be neglected. However, the future tokamaks such as WEST and ITER will be equipped with PFCs in metal (W and Be/W, respectively) with low and variable emissivities (ε ~ 0.1–0.4). Consequently, the reflected flux will contribute significantly in the collected flux by IR camera. The modulated active pyrometry, using a bicolor camera, proposed in this paper allows a 2D surface temperature measurement independently of the reflected fluxes and the emissivity. Experimental results with Tungsten sample are reported and compared with simultaneous measurement performed with classical pyrometry (monochromatic and bichromatic) with and without reflective flux demonstrating the efficiency of this method for surface temperature measurement independently of the reflected flux and the emissivity.« less

Development of an inverse distance weighted active infrared stealth scheme using the repulsive particle swarm optimization algorithm.

PubMed

Han, Kuk-Il; Kim, Do-Hwi; Choi, Jun-Hyuk; Kim, Tae-Kuk

2018-04-20

Treatments for detection by infrared (IR) signals are higher than for other signals such as radar or sonar because an object detected by the IR sensor cannot easily recognize its detection status. Recently, research for actively reducing IR signal has been conducted to control the IR signal by adjusting the surface temperature of the object. In this paper, we propose an active IR stealth algorithm to synchronize IR signals from the object and the background around the object. The proposed method includes the repulsive particle swarm optimization statistical optimization algorithm to estimate the IR stealth surface temperature, which will result in a synchronization between the IR signals from the object and the surrounding background by setting the inverse distance weighted contrast radiant intensity (CRI) equal to zero. We tested the IR stealth performance in mid wavelength infrared (MWIR) and long wavelength infrared (LWIR) bands for a test plate located at three different positions on a forest scene to verify the proposed method. Our results show that the inverse distance weighted active IR stealth technique proposed in this study is proved to be an effective method for reducing the contrast radiant intensity between the object and background up to 32% as compared to the previous method using the CRI determined as the simple signal difference between the object and the background.

Thermal effectiveness of different IR radiators employed in rheumatoid hand therapy as assessed by thermovisual examination.

PubMed

Rutkowski, Radosław; Straburzyńska-Lupa, Anna; Korman, Paweł; Romanowski, Wojciech; Gizińska, Małgorzata

2011-01-01

We conducted a thermovisual comparison of mean hand surface temperature changes upon local heating with two different IR sources. Sixty-six patients with rheumatoid arthritis (47 women and 19 men; average age, 56.1 ± 8.6 years) were subjected to topical heat therapy for one hand with either the standard IR radiator (SIR) or the water filter IRA (wIRA). The surface temperature of the dorsal side of both hands was measured, and thermal images were taken before and up to 2 h after treatment. At 1 min after treatment, SIR application increased the surface skin temperature of the heated hand from 31.5 ± 1.9 to 35.0 ± 1.9 °C (P<0.05), while wIRA increased it from 32.1 ± 1.6 to 34.2 ± 1.1 °C (P<0.05). Constant decline in temperature was observed immediately after treatment, with the temperatures reaching baseline in about 30 and 120 min after wIRA and SIR treatment, respectively. Similar temperature changes were observed in the heated hands for wIRA and SIR, except at 1 min after treatment. Changes in the untreated hands indicated contralateral reaction. The temperature of the warmed hand showed a correlation to the body mass index. © 2011 The Authors. Photochemistry and Photobiology © 2011 The American Society of Photobiology.

CO Adsorption on Reconstructed Ir(100) Surfaces from UHV to mbar Pressure: A LEED, TPD, and PM-IRAS Study

PubMed Central

2016-01-01

Clean and stable surface modifications of an iridium (100) single crystal, i.e., the (1 × 1) phase, the (5 × 1) reconstruction, and the oxygen-terminated (2 × 1)-O surface, were prepared and characterized by low energy electron diffraction (LEED), temperature-programmed desorption (TPD), infrared reflection absorption spectroscopy (IRAS) and polarization modulation IRAS (PM-IRAS). The adsorption of CO in UHV and at elevated (mbar) pressure/temperature was followed both ex situ and in situ on all three surface modifications, with a focus on mbar pressures of CO. The Ir(1 × 1) surface exhibited c(4 × 2)/c(2 × 2) and c(6 × 2) CO structures under low pressure conditions, and remained stable up to 100 mbar and 700 K. For the (2 × 1)-O reconstruction CO adsorption induced a structural change from (2 × 1)-O to (1 × 1), as confirmed by LEED, TPD, and IR. For Ir (2 × 1)-O TPD indicated that CO reacted with surface oxygen forming CO2. The (5 × 1) reconstruction featured a reversible and dynamic behavior upon CO adsorption, with a local lifting of the reconstruction to (1 × 1). After CO desorption, the (5 × 1) structure was restored. All three reconstructions exhibited CO adsorption with on-top geometry, as evidenced by IR. With increasing CO exposure the resonances shifted to higher wavenumber, due to adsorbate–adsorbate and adsorbate–substrate interactions. The largest wavenumber shift (from 2057 to 2100 cm–1) was observed for Ir(5 × 1) upon CO dosing from 1 L to 100 mbar. PMID:27257467

The IRGen infrared data base modeler

NASA Technical Reports Server (NTRS)

Bernstein, Uri

1993-01-01

IRGen is a modeling system which creates three-dimensional IR data bases for real-time simulation of thermal IR sensors. Starting from a visual data base, IRGen computes the temperature and radiance of every data base surface with a user-specified thermal environment. The predicted gray shade of each surface is then computed from the user specified sensor characteristics. IRGen is based on first-principles models of heat transport and heat flux sources, and it accurately simulates the variations of IR imagery with time of day and with changing environmental conditions. The starting point for creating an IRGen data base is a visual faceted data base, in which every facet has been labeled with a material code. This code is an index into a material data base which contains surface and bulk thermal properties for the material. IRGen uses the material properties to compute the surface temperature at the specified time of day. IRGen also supports image generator features such as texturing and smooth shading, which greatly enhance image realism.

An introduction to selective surfaces for solar applications

NASA Astrophysics Data System (ADS)

Neal, W. E. J.

1983-12-01

The desired characteristics of spectrally selective surfaces for solar thermal applications include a high-level absorption of radiation in the solar region of the spectrum (from 0.3 to 2.5 microns) combined with a low value of emission in the IR region (greater than two microns). There are three energy collector temperature ranges for specific solar applications, taking into account a range from 25 to 40 C for swimming pools, a range from 40 to 150 C for space and water heating and air conditioning, and temperatures above 150 C for the production of steam and the generation of electricity. Flat plate and low concentrating collectors with suitable selective surfaces can be employed in connection with the first two temperature ranges. Various types of selective surfaces are presented in a table, giving attention to the absorptive properties for solar radiation and the emissive properties in the IR region.

Surface-Bound Intermediates in Low-Temperature Methanol Synthesis on Copper. Participants and Spectators

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Yong; Mei, Donghai; Peden, Charles H.F.

The reactivity of surface adsorbed species present on copper catalysts during methanol synthesis at low temperatures was studied by simultaneous infrared spectroscopy (IR) and mass spectroscopy (MS) measurements during “titration” (transient surface reaction) experiments with isotopic tracing. The results show that adsorbed formate is a major bystander species present on the surface under steady-state methanol synthesis reaction conditions, but it cannot be converted to methanol by reaction with pure H 2, nor with H 2 plus added water. Formate-containing surface adlayers for these experiments were produced during steady state catalysis in (a) H 2:CO 2 (with substantial formate coverage) andmore » (b) moist H 2:CO (with no IR visible formate species). Both these reaction conditions produce methanol at steady state with relatively high rates. Adlayers containing formate were also produced by (c) formic acid adsorption. Various "titration" gases were used to probe these adlayers at modest temperatures (T = 410-450K) and 6 bar total pressure. Methanol gas (up to ~1% monolayer equivalent) was produced in "titration" from the H 2:CO 2 catalytic adlayers by H 2 plus water, but not by dry hydrogen. The decay in the formate IR features accelerated in the presence of added water vapor. The H 2:CO:H 2O catalytic adlayer produced similar methanol titration yields in H 2 plus water but showed no surface formate features in IR (less than 0.2% monolayer coverage). Finally, formate from formic acid chemisorption produced no methanol under any titration conditions. Even under (H 2:CO 2) catalytic reaction conditions, isotope tracing showed that pre-adsorbed formate from formic acid did not contribute to the methanol produced. Although non-formate intermediates exist during low temperature methanol synthesis on copper which can be converted to methanol gas by titration with pure H 2 plus water in sufficient quantities for that intermediate to be observable by IR, formate itself is only a "spectator" in this reaction and gives no observable methanol upon any titration we performed with H 2 or H 2 plus water.« less

Surface temperature determination in surface analytic systems by infrared optical pyrometry

NASA Technical Reports Server (NTRS)

Wheeler, Donald R.; Jones, William R., Jr.; Pepper, Stephen V.

1988-01-01

An IR pyrometric technique for measuring the surface temperatures of metal specimens in an ultrahigh-vacuum analytic chamber is described and demonstrated. The experimental setup comprises a commercial IR microscope with a long-working-distance right-angle objective (focal spot diameter 1 mm at 53 cm), a metal-coated glass vacuum chamber with a Ta-mesh-covered quartz viewport, an Mo specimen stub with an internal heating element, and a Ta disk test specimen with a flat side coated with a high-emissivity graphite film. The results of an initial calibration test are presented graphically and briefly characterized. The measurement error at 450 C is found to be less than 10 C.

Diffusion mechanisms in chemical vapor-deposited iridium coated on chemical vapor-deposited rhenium

NASA Technical Reports Server (NTRS)

Hamilton, J. C.; Yang, N. Y. C.; Clift, W. M.; Boehme, D. R.; Mccarty, K. F.; Franklin, J. E.

1992-01-01

Radiation-cooled rocket thruster chambers have been developed which use CVD Re coated with CVD Ir on the interior surface that is exposed to hot combustion gases. The Ir serves as an oxidation barrier which protects the structural integrity-maintaining Re at elevated temperatures. The diffusion kinetics of CVD materials at elevated temperatures is presently studied with a view to the prediction and extension of these thrusters' performance limits. Line scans for Ir and Re were fit on the basis of a diffusion model, in order to extract relevant diffusion constants; the fastest diffusion process is grain-boundary diffusion, where Re diffuses down grain boundaries in the Ir overlayer.

Preparation of Ti/IrO2 Anode with Low Iridium Content by Thermal Decomposition Process: Electrochemical removal of organic pollutants in water

NASA Astrophysics Data System (ADS)

Yaqub, Asim; Isa, Mohamed Hasnain; Ajab, Huma; Kutty, S. R. M.; Ezechi, Ezerie H.; Farooq, Robina

2018-04-01

In this study IrO2 (Iridium oxide) was coated onto a titanium plate anode from a dilute (50 mg/10 ml) IrCl3×H2O salt solution. Coating was done at high temperature (550∘C) using thermal decomposition. Surface morphology and characteristics of coated surface of Ti/IrO2 anode were examined by FESEM and XRD. The coated anode was applied for electrochemical removal of organic pollutants from synthetic water samples in 100 mL compartment of batch electrochemical cell. About 50% COD removal was obtained at anode prepared with low Ir content solution while 72% COD removal was obtained with anode prepared at high Ir content. Maximum COD removal was obtained at 10 mA/cm2 current density.

Near Surface Thermal Stratification during Summer at Summit, Greenland, and its Impact on MODIS-derived Surface Temperatures

NASA Astrophysics Data System (ADS)

Adolph, A. C.; Albert, M. R.; Hall, D. K.

2017-12-01

As rapid warming of the Arctic occurs, it is imperative that we monitor climate parameters such as temperature over large areas to understand and predict the extent of climate changes. Temperatures are often tracked using in-situ 2 m air temperatures, but in remote locations such as on the Greenland Ice Sheet, temperature can be studied more comprehensively using remote sensing techniques. Because of the presence of surface-based temperature inversions in ice-covered areas, differences between 2 m air temperature and skin temperature can be significant and are particularly relevant when considering validation and application of remote sensing temperature data. We present results from a field campaign at Summit Station in Greenland to study surface temperature using the following measurements: skin temperature measured by IR sensors, thermochrons, and thermocouples; 2 m air temperature measured by a NOAA meteorological station; and two different MODerate-resolution Imaging Spectroradiometer (MODIS) surface temperature products. We confirm prior findings that in-situ 2 m air temperature is often significantly higher in the summer than in-situ skin temperature when incoming solar radiation and wind speed are low. This inversion may account for biases in previous MODIS surface temperature studies that used 2 m air temperature for validation. As compared to the in-situ IR skin temperature measurements, the MOD/MYD11 Collection 6 surface-temperature standard product has an RMSE of 1.0°C, and that the MOD29 Collection 6 product has an RMSE of 1.5°C, spanning a range of temperatures from -35°C to -5°C. For our study area and time series, MODIS surface temperature products agree with skin temperatures better than many previous studies have indicated, especially at temperatures below -20°C where other studies found a significant cold bias. Further investigation at temperatures below -35°C is warranted to determine if this bias does indeed exist.

Stacking-fault nucleation on Ir(111).

PubMed

Busse, Carsten; Polop, Celia; Müller, Michael; Albe, Karsten; Linke, Udo; Michely, Thomas

2003-08-01

Variable temperature scanning tunneling microscopy experiments reveal that in Ir(111) homoepitaxy islands nucleate and grow both in the regular fcc stacking and in the faulted hcp stacking. Analysis of this effect in dependence on deposition temperature leads to an atomistic model of stacking-fault formation: The large, metastable stacking-fault islands grow by sufficiently fast addition of adatoms to small mobile adatom clusters which occupy in thermal equilibrium the hcp sites with a significant probability. Using parameters derived independently by field ion microscopy, the model accurately describes the results for Ir(111) and is expected to be valid also for other surfaces.

Influence of carbon dioxide clouds on early martian climate.

PubMed

Mischna, M A; Kasting, J F; Pavlov, A; Freedman, R

2000-06-01

Recent studies have shown that clouds made of carbon dioxide ice may have warmed the surface of early Mars by reflecting not only incoming solar radiation but upwelling IR radiation as well. However, these studies have not treated scattering self-consistently in the thermal IR. Our own calculations, which treat IR scattering properly, confirm these earlier calculations but show that CO2 clouds can also cool the surface, especially if they are low and optically thick. Estimating the actual effect of CO2 clouds on early martian climate will require three-dimensional models in which cloud location, height, and optical depth, as well as surface temperature and pressure, are determined self-consistently. Our calculations further confirm that CO2 clouds should extend the outer boundary of the habitable zone around a star but that there is still a finite limit beyond which above-freezing surface temperatures cannot be maintained by a CO2-H2O atmosphere. For our own Solar System, the absolute outer edge of the habitable zone is at approximately 2.4 AU.

Materials characterization of impregnated W and W-Ir cathodes after oxygen poisoning

NASA Astrophysics Data System (ADS)

Polk, James E.; Capece, Angela M.

2015-05-01

Electric thrusters use hollow cathodes as the electron source for generating the plasma discharge and for beam neutralization. These cathodes contain porous tungsten emitters impregnated with BaO material to achieve a lower surface work function and are operated with xenon propellant. Oxygen contaminants in the xenon plasma can poison the emitter surface, resulting in a higher work function and increased operating temperature. This could lead directly to cathode failure by preventing discharge ignition or could accelerate evaporation of the BaO material. Exposures over hundreds of hours to very high levels of oxygen can result in increased temperatures, oxidation of the tungsten substrate, and the formation of surface layers of barium tungstates. In this work, we present results of a cathode test in which impregnated tungsten and tungsten-iridium emitters were operated with 100 ppm of oxygen in the xenon plasma for several hundred hours. The chemical and morphological changes were studied using scanning electron microscopy, energy dispersive spectroscopy, and laser profilometry. The results provide strong evidence that high concentrations of oxygen accelerate the formation of tungstate layers in both types of emitters, a phenomenon not inherent to normal cathode operation. Deposits of pure tungsten were observed on the W-Ir emitter, indicating that tungsten is preferentially removed from the surface and transported in the insert plasma. A W-Ir cathode surface will therefore evolve to a pure W composition, eliminating the work function benefit of W-Ir. However, the W-Ir emitter exhibited less erosion and redeposition at the upstream end than the pure W emitter.

Experimental determination of the Fermi surface of Sr3Ir4Sn13

NASA Astrophysics Data System (ADS)

Chen, Xiaoye; Goh, Swee K.; Tompsett, David A.; Yu, Wing Chi; Klintberg, Lina; Friedemann, Sven; Tan, Hong'En; Yang, Jinhu; Chen, Bin; Imai, M.; Yoshimura, Kazuyoshi; Gamza, Monika B.; Grosche, F. Malte; Sutherland, Michael L.

2016-06-01

The stannide family of materials A3T4 Sn13 (A =La ,Sr ,Ca ; T =Ir ,Rh ) is interesting due to the interplay between a tunable lattice instability and phonon-mediated superconductivity with Tc˜5 -7 K . In Sr3Ir4Sn13, a structural transition temperature T˜147 K associated with this instability has been reported, which is believed to result from a superlattice distortion of the high-temperature phase on cooling. Here we report an experimental study of the electronic structure of a member of this material family, Sr3Ir4Sn13, through measurements of quantum oscillations and comparison with density functional theory calculations. Our measurements reveal good agreement with theory using the lattice parameters consistent with a body-centered-cubic lattice of symmetry I 4 ¯3 d of the low-temperature phase. The study of the fermiology of Sr3Ir4Sn13 that we present here should help inform models of multiband superconductivity in the superconducting stannides.

Measurement of Two-Phase Flow and Heat Transfer Parameters using Infrared Thermometry

NASA Technical Reports Server (NTRS)

Kim, Tae-Hoon; Kommer, Eric; Dessiatoun, Serguei; Kim, Jungho

2012-01-01

A novel technique to measure heat transfer and liquid film thickness distributions over relatively large areas for two-phase flow and heat transfer phenomena using infrared (IR)thermometry is described. IR thermometry is an established technology that can be used to measure temperatures when optical access to the surface is available in the wavelengths of interest. In this work, a midwave IR camera (3.6-5.1 microns) is used to determine the temperature distribution within a multilayer consisting of a silicon substrate coated with a thin insulator. Since silicon is largely transparent to IR radiation, the temperature of the inner and outer walls of the multilayer can be measured by coating selected areas with a thin, IR opaque film. If the fluid used is also partially transparent to IR, the flow can be visualized and the liquid film thickness can be measured. The theoretical basis for the technique is given along with a description of the test apparatus and data reduction procedure. The technique is demonstrated by determining the heat transfer coefficient distributions produced by droplet evaporation and flow boiling heat transfer.

Directional satellite thermal IR measurements and modeling of a forest in winter and their relationship to air temperature

NASA Astrophysics Data System (ADS)

Balick, Lee K.; Ballard, Jerrell R., Jr.; Smith, James A.; Goltz, Stewart M.

2002-01-01

Data assimilation methods applied to hydrologic models can incorporate spatially distributed maps of near surface temperature, especially if such measurements can be reliably inferred from satellite observations. Uncalibrated thermal IR imagery sometimes is scaled to temperature units to obtain such observations using the assumption that dense forest canopies are close to air temperature. For fully leafed deciduous forest canopies in the summer, this approximation is usually valid within 2C. In a leafless canopy, however, the materials views are thick boles and branches and the forest floor, which can store heat and yield significantly higher variations. Winter coniferous forests are intermediate with needles and branches being the predominant viewed materials. The US Dept of Energy's Multispectral Thermal Imager (MTI) is an experimental satellite with the capability to perform quantitative scene measurements in the reflective and thermal infrared region respectively. Its multispectral thermal IR capability enables quantitative surface temperature retrieval if pixel emissivity is known. MTI is pointable and targets multiple times in the winter and spring of 2001 at the Howland, Maine AmeriFlux research site operated by the University of Maine. Supporting meteorological and optical depth measurements also were made from three towers at the site. Directional thermal models of forest woody materials and needles are driver by the surface measurements and compared to satellite data to help evaluate the relationship between air temperature and satellite thermal measurements as a function of look angles, day and night.

Simultaneous droplet impingement dynamics and heat transfer on nano-structured surfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shen, Jian; Graber, Christof; Liburdy, James

This study examines the hydrodynamics and temperature characteristics of distilled deionized water droplets impinging on smooth and nano-structured surfaces using high speed (HS) and infrared (IR) imaging at We = 23.6 and Re = 1593, both based on initial drop impingement parameters. Results for a smooth and nano-structured surface for a range of surface temperatures are compared. Droplet impact velocity, transient spreading diameter and dynamic contact angle are measured. The near surface average droplet fluid temperatures are evaluated for conditions of evaporative cooling and boiling. Also included are surface temperature results using a gold layered IR opaque surface on silicon.more » Four stages of the impingement process are identified: impact, boiling, near constant surface diameter evaporation, and final dry-out. For the boiling conditions there is initial nucleation followed by severe boiling, then near constant diameter evaporation resulting in shrinking of the droplet height. When a critical contact angle is reached during evaporation the droplet rapidly retracts to a smaller diameter reducing the contact area with the surface. This continues as a sequence of retractions until final dry out. The basic trends are the same for all surfaces, but the nano-structured surface has a lower dissipated energy during impact and enhances the heat transfer for evaporative cooling with a 20% shorter time to achieve final dry out. (author)« less

Identifying environmental features for land management decisions

NASA Technical Reports Server (NTRS)

1983-01-01

Pairs of HCMM day-night thermal infrared (IR) data were selected to examine patterns of surface temperature and thermal inertia (TI) of peninsular Florida. GOES and NOAA-6 thermal IR, as well as National Climatic Center temperatures and rainfall, were also used. The HCMM apparent thermal inertia (ATI) images closely correspond to the General Soil Map of Florida, based on soil drainage classes. Areas with low ATI overlay well-drained soils, such as deep sands and drained organic soils. Areas with high ATI overlay areas with wetlands and bodies of water. The HCMM ATI images also correspond well with GOES-detected winter nocturnal cold-prone areas. Use of HCMM data with Carlson's energy balance model shows both high moisture availability (MA) and high thermal inertia (TI) of wetland-type surfaces and low MA and low TI of upland, well-drained soils. Since soil areas with low TI develop higher temperatures during the day, then antecedent patterns of highest maximum daytime surface temperature can also be used to predict nocturnal cold-prone areas in Florida.

IR-based spot weld NDT in automotive applications

NASA Astrophysics Data System (ADS)

Chen, Jian; Feng, Zhili

2015-05-01

Today's auto industry primarily relies on destructive teardown evaluation to ensure the quality of the resistance spot welds (RSWs) due to their criticality in crash resistance and performance of vehicles. The destructive teardown evaluation is labor intensive and costly. The very nature of the destructive test means only a few selected welds will be sampled for quality. Most of the welds in a car are never checked. There are significant costs and risks associated with reworking and scrapping the defective welded parts made between the teardown tests. IR thermography as a non-destructive testing (NDT) tool has its distinct advantage — its non-intrusive and non-contact nature. This makes the IR based NDT especially attractive for the highly automated assembly lines. IR for weld quality inspection has been explored in the past, mostly limited to the offline post-processing manner in a laboratory environment. No online real-time RSW inspection using IR thermography has been reported. Typically for postprocessing inspection, a short-pulse heating via xenon flash lamp light (in a few milliseconds) is applied to the surface of a spot weld. However, applications in the auto industry have been unsuccessful, largely due to a critical drawback that cannot be implemented in the high-volume production line - the prerequisite of painting the weld surface to eliminate surface reflection and other environmental interference. This is due to the low signal-to-noise ratio resulting from the low/unknown surface emissivity and the very small temperature changes (typically on the order of 0.1°C) induced by the flash lamp method. An integrated approach consisting of innovations in both data analysis algorithms and hardware apparatus that effectively solved the key technical barriers for IR NDT. The system can be used for both real-time (during welding) and post-processing inspections (after welds have been made). First, we developed a special IR thermal image processing method that utilizes the relative IR intensity change, so that the influence of surface reflection and environment interference can be reduced. Second, for the post-processing inspection, a special induction heater is used to replace the flash lamp, resulting in temperature changes on the order of 10°C. As a result, the signal-to-noise ratio increased by several orders of magnitudes with no surface painting needed, and the inspection results are more accurate and reliable. For real-time inspection, the heat from welding (with temperature exceeding 1000°C) was utilized. Third, "thermal signatures" were identified to uniquely correlate to different weld quality attributes through computational modeling of heat transfer and extensive testing of specially designed ranges of welding conditions. Novel IR image analysis algorithms that automatically and intelligently identify the "thermal signatures" from the IR images and positively determine the weld quality in less than a second were developed.

Epitaxial growth of Al9Ir2 intermetallic compound on Al(100): Mechanism and interface structure

NASA Astrophysics Data System (ADS)

Kadok, J.; Pussi, K.; Šturm, S.; Ambrožič, B.; Gaudry, É.; de Weerd, M.-C.; Fournée, V.; Ledieu, J.

2018-04-01

The adsorption of Ir adatoms on Al(100) has been investigated under various exposures and temperature conditions. The experimental and theoretical results reveal a diffusion of Ir adatoms within the Al(100) surface selvedge already at 300 K. Above 593 K, two domains of a (√{5 }×√{5 }) R 26 .6∘ phase are identified by low energy electron diffraction (LEED) and scanning tunneling microscopy measurements. This phase corresponds to the initial growth of an Al9Ir2 compound at the Al(100) surface. The Al9Ir2 intermetallic domains are terminated by bulklike pure Al layers. The structural stability of Al9Ir2 (001) grown on Al(100) has been analyzed by density functional theory based calculations. Dynamical LEED analysis is consistent with an Ir adsorption leading to the growth of an Al9Ir2 intermetallic compound. We propose that the epitaxial relationship Al9Ir2(001 ) ∥Al (100) and Al9Ir2[100 ] ∥Al [031 ]/[013 ] originates from a matching of Al atomic arrangements present both on Al(100) and on pure Al(001) layers present in the Al9Ir2 compound. Finally, the interface between Al9Ir2 precipitates and the Al matrix has been characterized by transmission electron microscopy measurements. The cross-sectional observations are consistent with the formation of Al9Ir2 (001) compounds. These measurements indicate an important Ir diffusion within Al(100) near the surface region. The coherent interface between Al9Ir2 and the Al matrix is sharp.

Nighttime Infrared radiative cooling and opacity inferred by REMS Ground Temperature Sensor Measurements

NASA Astrophysics Data System (ADS)

Martín-Torres, Javier; Paz Zorzano, María; Pla-García, Jorge; Rafkin, Scot; Lepinette, Alain; Sebastián, Eduardo; Gómez-Elvira, Javier; REMS Team

2013-04-01

Due to the low density of the Martian atmosphere, the temperature of the surface is controlled primarily by solar heating, and infrared cooling to the atmosphere and space, rather than heat exchange with the atmosphere. In the absence of solar radiation the infrared (IR) cooling, and then the nighttime surface temperatures, are directly controlled by soil termal inertia and atmospheric optical thickness (τ) at infrared wavelengths. Under non-wind conditions, and assuming no processes involving latent heat changes in the surface, for a particular site where the rover stands the main parameter controlling the IR cooling will be τ. The minimal ground temperature values at a fixed position may thus be used to detect local variations in the total dust/aerosols/cloud tickness. The Ground Temperature Sensor (GTS) and Air Temperature Sensor (ATS) in the Rover Environmental Monitoring Station (REMS) on board the Mars Science Laboratory (MSL) Curiosity rover provides hourly ground and air temperature measurements respectively. During the first 100 sols of operation of the rover, within the area of low thermal inertia, the minimal nightime ground temperatures reached values between 180 K and 190 K. For this season the expected frost point temperature is 200 K. Variations of up to 10 K have been observed associated with dust loading at Gale at the onset of the dust season. We will use these measurements together with line-by-line radiative transfer simulations using the Full Transfer By Optimized LINe-by-line (FUTBOLIN) code [Martín-Torres and Mlynczak, 2005] to estimate the IR atmospheric opacity and then dust/cloud coverage over the rover during the course of the MSL mission. Monitoring the dust loading and IR nightime cooling evolution during the dust season will allow for a better understanding of the influence of the atmosphere on the ground temperature and provide ground truth to models and orbiter measurements. References Martín-Torres, F. J. and M. G. Mlynczak, Application of FUTBOLIN (FUll Transfer By Ordinary Line-by-Line) to the analysis of the solar system and extrasolar planetary atmospheres, Bulletin of the American Astronomical Society, Vol. 37, p.1566, 2005

An inverse method for estimation of the acoustic intensity in the focused ultrasound field

NASA Astrophysics Data System (ADS)

Yu, Ying; Shen, Guofeng; Chen, Yazhu

2017-03-01

Recently, a new method which based on infrared (IR) imaging was introduced. Authors (A. Shaw, et al and M. R. Myers, et al) have established the relationship between absorber surface temperature and incident intensity during the absorber was irradiated by the transducer. Theoretically, the shorter irradiating time makes estimation more in line with the actual results. But due to the influence of noise and performance constrains of the IR camera, it is hard to identify the difference in temperature with short heating time. An inverse technique is developed to reconstruct the incident intensity distribution using the surface temperature with shorter irradiating time. The algorithm is validated using surface temperature data generated numerically from three-layer model which was developed to calculate the acoustic field in the absorber, the absorbed acoustic energy during the irradiation, and the consequent temperature elevation. To assess the effect of noisy data on the reconstructed intensity profile, in the simulations, the different noise levels with zero mean were superposed on the exact data. Simulation results demonstrate that the inversion technique can provide fairly reliable intensity estimation with satisfactory accuracy.

The Infrared Sensor Suite for SnowEx 2017

NASA Technical Reports Server (NTRS)

Hall, D. K.; Chickadel, C. C.; Crawford, C. J.; DeMarco, E. L.; Jennings, D. E.; Jhabvala, M. D.; Kim, E. J.; Lundquist, J. D.; Lunsford, A. W.

2017-01-01

SnowEx is a winter airborne and field campaign designed to measure snow-water equivalent in forested landscapes. A major focus of Year 1 (2016-17) of NASA's SnowEx campaign will be an extensive field program involving dozens of participants from U.S. government agencies and from many universities and institutions, both domestic and foreign. Along with other instruments, two infrared (IR) sensors will be flown on a Naval Research Laboratory P-3 aircraft. Surface temperature is a critical input to hydrologic models and will be measured during the SnowEx mission. A Quantum Well Infrared Photodetector (QWIP) IR imaging camera system will be flown along with a KT-15 remote thermometer to aid in the calibration of the IR image data. Together, these instruments will measure surface temperature of snow and ice targets to an expected accuracy of less than 1C.

ERTS-1 observes algal blooms in Lake Erie and Utah Lake

NASA Technical Reports Server (NTRS)

Strong, A. E.

1973-01-01

During late summer when the surface waters of Lake Erie reach their maximum temperature an algal bloom is likely to develop. Such phenomena have been noticed on other shallow lakes using ERTS-1 and characterize eutrophic conditions. The concentration of the algae into long streamers provides additional information on surface circulations. To augment the ERTS-1 MSS data of Lake Erie an aircraft was flown to provide correlative thermal-IR and additional multiband photographs. The algal bloom is highly absorptive in the visible wavelengths but reverses contrast with the surrounding water in the near-IR bands. The absorption of shortwave energy heats the dark brown algal mass, providing a hot surface target for the thermal-IR scanner.

Martian surface weathering studies

NASA Technical Reports Server (NTRS)

Calvin, M.

1973-01-01

The nature of the Martian surface was characterized by means of its reflectance properties. The Mariner 9 photography was used to establish terrain units which were crossed by the Mariner 6 and 7 paths. The IR reflectance measured by the IR spectrometers on these spacecraft was to be used to indicate the nature of the surface within these units. There is an indication of physical size and/or compositional variation between units but too many natural parameters can vary (size, shape, composition, adsorbed phases, reradiation, atmospheric absorbtion, temperature gradients, etc.) to be certain what effect is causing those variations observed. It is suggested that the characterization could be fruitfully pursued by a group which was dedicated to peeling back the layers of minutia affecting IR reflectance.

A density functional study on adsorption and dissociation of O 2 on Ir(1 0 0) surface

NASA Astrophysics Data System (ADS)

Erikat, I. A.; Hamad, B. A.; Khalifeh, J. M.

2011-06-01

The adsorption and the reaction barrier for the dissociation of O 2 on Ir(1 0 0) surface are studied using periodic self-consistent density functional theory (DFT) calculations. Dissociative adsorption is found to be energetically more favorable compared to molecular adsorption. Parallel approaches Prl1 and Prl2 on a hollow site with the same adsorption energy of -3.93 eV for both of them are found to have the most energetically preferred sites of adsorptions among all the studied cases. Hybridization between p-O 2 and d-metal orbitals is responsible for the dissociative adsorption. The minimum energy path is determined by using the nudge elastic band method (NEB). We found that the dissociation occurs immediately and very early in the dissociation path with a small activation barrier (0.26 eV), which means that molecular adsorption of O 2 on Ir(1 0 0) surface occurs at very low temperatures; this is consistent with previous experimental and theoretical studies on Ir surfaces.

Far-infrared surface emissivity and climate.

PubMed

Feldman, Daniel R; Collins, William D; Pincus, Robert; Huang, Xianglei; Chen, Xiuhong

2014-11-18

Presently, there are no global measurement constraints on the surface emissivity at wavelengths longer than 15 μm, even though this surface property in this far-IR region has a direct impact on the outgoing longwave radiation (OLR) and infrared cooling rates where the column precipitable water vapor (PWV) is less than 1 mm. Such dry conditions are common for high-altitude and high-latitude locations, with the potential for modeled climate to be impacted by uncertain surface characteristics. This paper explores the sensitivity of instantaneous OLR and cooling rates to changes in far-IR surface emissivity and how this unconstrained property impacts climate model projections. At high latitudes and altitudes, a 0.05 change in emissivity due to mineralogy and snow grain size can cause a 1.8-2.0 W m(-2) difference in the instantaneous clear-sky OLR. A variety of radiative transfer techniques have been used to model the far-IR spectral emissivities of surface types defined by the International Geosphere-Biosphere Program. Incorporating these far-IR surface emissivities into the Representative Concentration Pathway (RCP) 8.5 scenario of the Community Earth System Model leads to discernible changes in the spatial patterns of surface temperature, OLR, and frozen surface extent. The model results differ at high latitudes by as much as 2°K, 10 W m(-2), and 15%, respectively, after only 25 y of integration. Additionally, the calculated difference in far-IR emissivity between ocean and sea ice of between 0.1 and 0.2, suggests the potential for a far-IR positive feedback for polar climate change.

Far-infrared surface emissivity and climate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Feldman, Daniel R.; Collins, William D.; Pincus, Robert

Presently, there are no global measurement constraints on the surface emissivity at wavelengths longer than 15 μm, even though this surface property in this far-IR region has a direct impact on the outgoing longwave radiation (OLR) and infrared cooling rates where the column precipitable water vapor (PWV) is less than 1 mm. Such dry conditions are common for high-altitude and high-latitude locations, with the potential for modeled climate to be impacted by uncertain surface characteristics. This paper explores the sensitivity of instantaneous OLR and cooling rates to changes in far-IR surface emissivity and how this unconstrained property impacts climate modelmore » projections. At high latitudes and altitudes, a 0.05 change in emissivity due to mineralogy and snow grain size can cause a 1.8–2.0 W m⁻² difference in the instantaneous clear-sky OLR. A variety of radiative transfer techniques have been used to model the far-IR spectral emissivities of surface types defined by the International Geosphere-Biosphere Program. Incorporating these far-IR surface emissivities into the Representative Concentration Pathway (RCP) 8.5 scenario of the Community Earth System Model leads to discernible changes in the spatial patterns of surface temperature, OLR, and frozen surface extent. The model results differ at high latitudes by as much as 2°K, 10 W m⁻², and 15%, respectively, after only 25 y of integration. The calculated difference in far-IR emissivity between ocean and sea ice of between 0.1 and 0.2, suggests the potential for a far-IR positive feedback for polar climate change.« less

Far-infrared surface emissivity and climate

PubMed Central

Feldman, Daniel R.; Collins, William D.; Pincus, Robert; Huang, Xianglei; Chen, Xiuhong

2014-01-01

Presently, there are no global measurement constraints on the surface emissivity at wavelengths longer than 15 μm, even though this surface property in this far-IR region has a direct impact on the outgoing longwave radiation (OLR) and infrared cooling rates where the column precipitable water vapor (PWV) is less than 1 mm. Such dry conditions are common for high-altitude and high-latitude locations, with the potential for modeled climate to be impacted by uncertain surface characteristics. This paper explores the sensitivity of instantaneous OLR and cooling rates to changes in far-IR surface emissivity and how this unconstrained property impacts climate model projections. At high latitudes and altitudes, a 0.05 change in emissivity due to mineralogy and snow grain size can cause a 1.8–2.0 W m−2 difference in the instantaneous clear-sky OLR. A variety of radiative transfer techniques have been used to model the far-IR spectral emissivities of surface types defined by the International Geosphere-Biosphere Program. Incorporating these far-IR surface emissivities into the Representative Concentration Pathway (RCP) 8.5 scenario of the Community Earth System Model leads to discernible changes in the spatial patterns of surface temperature, OLR, and frozen surface extent. The model results differ at high latitudes by as much as 2°K, 10 W m−2, and 15%, respectively, after only 25 y of integration. Additionally, the calculated difference in far-IR emissivity between ocean and sea ice of between 0.1 and 0.2, suggests the potential for a far-IR positive feedback for polar climate change. PMID:25368189

Far-infrared surface emissivity and climate

DOE PAGES

Feldman, Daniel R.; Collins, William D.; Pincus, Robert; ...

2014-11-03

Presently, there are no global measurement constraints on the surface emissivity at wavelengths longer than 15 μm, even though this surface property in this far-IR region has a direct impact on the outgoing longwave radiation (OLR) and infrared cooling rates where the column precipitable water vapor (PWV) is less than 1 mm. Such dry conditions are common for high-altitude and high-latitude locations, with the potential for modeled climate to be impacted by uncertain surface characteristics. This paper explores the sensitivity of instantaneous OLR and cooling rates to changes in far-IR surface emissivity and how this unconstrained property impacts climate modelmore » projections. At high latitudes and altitudes, a 0.05 change in emissivity due to mineralogy and snow grain size can cause a 1.8–2.0 W m⁻² difference in the instantaneous clear-sky OLR. A variety of radiative transfer techniques have been used to model the far-IR spectral emissivities of surface types defined by the International Geosphere-Biosphere Program. Incorporating these far-IR surface emissivities into the Representative Concentration Pathway (RCP) 8.5 scenario of the Community Earth System Model leads to discernible changes in the spatial patterns of surface temperature, OLR, and frozen surface extent. The model results differ at high latitudes by as much as 2°K, 10 W m⁻², and 15%, respectively, after only 25 y of integration. The calculated difference in far-IR emissivity between ocean and sea ice of between 0.1 and 0.2, suggests the potential for a far-IR positive feedback for polar climate change.« less

IR temperatures of Mauna Loa caldera obtained with multispectral thermal imager

NASA Astrophysics Data System (ADS)

Pendergast, Malcolm M.; O'Steen, Byron L.; Kurzeja, Robert J.

2002-01-01

A survey of surface temperatures of the Mauna Loa caldera during 7/14/00 and 7/15/00 was made by SRTC in conjunction with a MTI satellite image collection. The general variation of surface temperature appears quite predictable responding to solar heating. The analysis of detailed times series of temperature indicates systematic variations in temperature of 5 C corresponding to time scales of 3-5 minutes and space scales of 10-20 m. The average temperature patterns are consistent with those predicted by the Regional Atmospheric Modeling System (RAMS).

Adsorption of hydrogen on stable and metastable Ir(100) surfaces

NASA Astrophysics Data System (ADS)

Arman, Mohammad Alif; Klein, Andreas; Ferstl, Pascal; Valookaran, Abhilash; Gustafson, Johan; Schulte, Karina; Lundgren, Edvin; Heinz, Klaus; Schneider, Alexander; Mittendorfer, Florian; Hammer, Lutz; Knudsen, Jan

2017-02-01

Using the combination of high resolution core level spectroscopy and density functional theory we present a detailed spectroscopic study for all clean and hydrogen covered phases of Ir(100). The results are complemented by an investigation of the hydrogen desorption process from various phases using temperature programmed desorption spectroscopy and scanning tunneling microscopy. In total, all experimentally determined core level shifts match very well with those predicted by density functional theory based on established structural models. In particular, we find for the (bridge site) adsorption on the unreconstructed 1×1 phase that the initial core level shift of surface Ir atoms is altered by +0.17 eV for each Ir-H bond formed. In the submonolayer regime we find evidence for island formation at low temperatures. For the H-induced deconstructed 5×1-H phase we identify four different surface core level shifts with two of them being degenerate. Finally, for the reconstructed 5×1-hex phase also four surface components are identified, which undergo a rather rigid core level shift of +0.15 eV upon hydrogen adsorption suggesting a similarly homogeneous charge transfer to all Ir surface atoms. Thermodesorption experiments for the 5×1-H phase reveal two different binding states for hydrogen independent of the total coverage. We conclude that the surface always separates into patches of fully covered deconstructed and uncovered reconstructed phases. We could also show by tunneling microscopy that with the desorption of the last hydrogen atom from the deconstructed unit cell the surface instantaneously reverts into the reconstructed state. Eventually, we could determine the saturation coverage upon molecular adsorption for all phases to be θmax1 × 1 - H = 1.0 ML , θmax5 × 1 - H = 0.8 ML , and θmax5 × 1 - hex - H ≥ 1.0 ML .

In situ FTIR spectroscopic assessment of methylbutynol catalytic conversion products in relation to the surface acid-base properties of systematically modified aluminas

NASA Astrophysics Data System (ADS)

Mekhemer, Gamal A. H.; Zaki, Mohamed I.

2016-10-01

The present investigation was designed to assess the credibility of methylbutynol (MBOH) as an infrared (IR) reactive probe molecule for surface acid-base properties of metal oxides. Accordingly, pure alumina was systematically modified with varied amounts (0.5-10 wt.%) of K+ or SO42 - additives. Then, the influence of nature and amount of the additive on the following alumina properties were examined: (i) bulk composition and structure by X-ray powder diffractometry and ex-situ IR spectroscopy, (ii) surface area and net charge by N2 sorptiometry and pH-metry, respectively, and (iii) nature and strength of exposed surface acid sites by in-situ IR spectroscopy of adsorbed pyridine at ambient and higher temperatures. Results obtained were correlated with IR-identified product distribution of MBOH catalytic decomposition/conversion at 200 °C. It is thereby concluded that MBOH is superior to conventional IR inactive probe molecules in gauging sensitively the prevailing acid or base character, availability of base sites, relative population of Bronsted to Lewis acid sites, and strength and reactivity of the sites exposed on metal oxide surfaces. Hence, all that is needed to get this information is to handle IR spectra taken from the gas phase, a task that is experimentally much more accessible than taking spectra from adsorbed species of irreactive probe molecules.

Noncontact detection of dry eye using a custom designed IR thermal image system

NASA Astrophysics Data System (ADS)

Su, Tai Yuan; Chen, Kerh Hwa; Liu, Po Hsuan; Wu, Ming Hong; Chang, David O.; Chiang, Huihua

2011-03-01

Dry eye syndrome is a common irritating eye disease. Current clinical diagnostic methods are invasive and uncomfortable to patients. A custom designed noncontact infrared (IR) thermal image system was developed to measure the spatial and temporal variation of the ocular surface temperature over a 6-second eye-opening period. We defined two parameters: the temperature difference value and the compactness value to represent the degree of the temperature change and irregularity of the temperature distribution on the tear film. By using these two parameters, in this study, a linear discrimination result for the dry eye and the normal eye groups; the sensitivity is 0.9, the specificity is 0.86 and the receiver operating characteristic (ROC) area is 0.91. The result suggests that the custom designed IR thermal image system may be used as an effective tool for noncontact detection of dry eye.

Dryland pasture and crop conditions as seen by HCMM. [Washita River watershed, Oklahoma

NASA Technical Reports Server (NTRS)

Rosenthal, W. D.; Harlan, J. C.; Blanchard, B. J. (Principal Investigator)

1980-01-01

Ground truth, aircraft, and satellite data were examined in order to: (1) assess the capability for determining wheat and pasture canopy temperatures in a dryland farming region from HCMM data; (2) assess the capability for determining soil moisture from HCMM data in dryland crops (winter wheat) from adjacent range lands; and (3) determine the relationship of HCMM-derived soil moisture and canopy temperature values with the condition of winter wheat and dryland farming areas during the principal growth stages. The IR data were screened to include areas having greater than 60% pasture and surface temperatures were recalculated using the atmospheric correction factor calculated by the modified RADTRA model, and the July 29, 1978 IR data were analyzed. Screening the IR data improved the relationship for July 24/July 13 and October 7/August 31 temperature/API relationship. However the coefficient of determination was not improved in the July 29/July 13 relationship.

Limitations of using a thermal imager for snow pit temperatures

NASA Astrophysics Data System (ADS)

Schirmer, M.; Jamieson, B.

2013-10-01

Driven by temperature gradients, kinetic snow metamorphism is important for avalanche formation. Even when gradients appear to be insufficient for kinetic metamorphism, based on temperatures measured 10 cm apart, faceting close to a~crust can still be observed. Recent studies that visualized small scale (< 10 cm) thermal structures in a profile of snow layers with an infrared (IR) camera produced interesting results. The studies found melt-freeze crusts to be warmer or cooler than the surrounding snow depending on the large scale gradient direction. However, an important assumption within the studies was that a thermal photo of a freshly exposed snow pit was similar enough to the internal temperature of the snow. In this study, we tested this assumption by recording thermal videos during the exposure of the snow pit wall. In the first minute, the results showed increasing gradients with time, both at melt-freeze crusts and at artificial surface structures such as shovel scours. Cutting through a crust with a cutting blade or a shovel produced small concavities (holes) even when the objective was to cut a planar surface. Our findings suggest there is a surface structure dependency of the thermal image, which is only observed at times with large temperature differences between air and snow. We were able to reproduce the hot-crust/cold-crust phenomenon and relate it entirely to surface structure in a temperature-controlled cold laboratory. Concave areas cooled or warmed slower compared with convex areas (bumps) when applying temperature differences between snow and air. This can be explained by increased radiative transfer or convection by air at convex areas. Thermal videos suggest that such processes influence the snow temperature within seconds. Our findings show the limitations of the use of a thermal camera for measuring pit-wall temperatures, particularly in scenarios where large gradients exist between air and snow and the interaction of snow pit and atmospheric temperatures are enhanced. At crusts or other heterogeneities, we were unable to create a sufficiently homogenous snow pit surface and non-internal gradients appeared at the exposed surface. The immediate adjustment of snow pit temperature as it reacts with the atmosphere complicates the capture of the internal thermal structure of a snowpack even with thermal videos. Instead, the shown structural dependency of the IR signal may be used to detect structural changes of snow caused by kinetic metamorphism. The IR signal can also be used to measure near surface temperatures in a homogenous new snow layer.

Statistics of surface divergence and their relation to air-water gas transfer velocity

NASA Astrophysics Data System (ADS)

Asher, William E.; Liang, Hanzhuang; Zappa, Christopher J.; Loewen, Mark R.; Mukto, Moniz A.; Litchendorf, Trina M.; Jessup, Andrew T.

2012-05-01

Air-sea gas fluxes are generally defined in terms of the air/water concentration difference of the gas and the gas transfer velocity,kL. Because it is difficult to measure kLin the ocean, it is often parameterized using more easily measured physical properties. Surface divergence theory suggests that infrared (IR) images of the water surface, which contain information concerning the movement of water very near the air-water interface, might be used to estimatekL. Therefore, a series of experiments testing whether IR imagery could provide a convenient means for estimating the surface divergence applicable to air-sea exchange were conducted in a synthetic jet array tank embedded in a wind tunnel. Gas transfer velocities were measured as a function of wind stress and mechanically generated turbulence; laser-induced fluorescence was used to measure the concentration of carbon dioxide in the top 300 μm of the water surface; IR imagery was used to measure the spatial and temporal distribution of the aqueous skin temperature; and particle image velocimetry was used to measure turbulence at a depth of 1 cm below the air-water interface. It is shown that an estimate of the surface divergence for both wind-shear driven turbulence and mechanically generated turbulence can be derived from the surface skin temperature. The estimates derived from the IR images are compared to velocity field divergences measured by the PIV and to independent estimates of the divergence made using the laser-induced fluorescence data. Divergence is shown to scale withkLvalues measured using gaseous tracers as predicted by conceptual models for both wind-driven and mechanically generated turbulence.

Partially oxidized iridium clusters within dendrimers: size-controlled synthesis and selective hydrogenation of 2-nitrobenzaldehyde

NASA Astrophysics Data System (ADS)

Higaki, Tatsuya; Kitazawa, Hirokazu; Yamazoe, Seiji; Tsukuda, Tatsuya

2016-06-01

Iridium clusters nominally composed of 15, 30 or 60 atoms were size-selectively synthesized within OH-terminated poly(amidoamine) dendrimers of generation 6. Spectroscopic characterization revealed that the Ir clusters were partially oxidized. All the Ir clusters efficiently converted 2-nitrobenzaldehyde to anthranil and 2-aminobenzaldehyde under atmospheric hydrogen at room temperature in toluene via selective hydrogenation of the NO2 group. The selectivity toward 2-aminobenzaldehyde over anthranil was improved with the reduction of the cluster size. The improved selectivity is ascribed to more efficient reduction than intramolecular heterocyclization of a hydroxylamine intermediate on smaller clusters that have a higher Ir(0)-phase population on the surface.Iridium clusters nominally composed of 15, 30 or 60 atoms were size-selectively synthesized within OH-terminated poly(amidoamine) dendrimers of generation 6. Spectroscopic characterization revealed that the Ir clusters were partially oxidized. All the Ir clusters efficiently converted 2-nitrobenzaldehyde to anthranil and 2-aminobenzaldehyde under atmospheric hydrogen at room temperature in toluene via selective hydrogenation of the NO2 group. The selectivity toward 2-aminobenzaldehyde over anthranil was improved with the reduction of the cluster size. The improved selectivity is ascribed to more efficient reduction than intramolecular heterocyclization of a hydroxylamine intermediate on smaller clusters that have a higher Ir(0)-phase population on the surface. Electronic supplementary information (ESI) available. See DOI: 10.1039/c6nr01460g

Use of thermal inertia determined by HCMM to predict nocturnal cold prone areas in Florida

NASA Technical Reports Server (NTRS)

Allen, L. H., Jr. (Principal Investigator)

1983-01-01

Pairs of HCMM day-night thermal infrared (IR) data were selected during the 1978-79 winter to examine patterns of surface temperature and thermal inertia (TI) of peninsular Florida. The GOES and NOAA-6 thermal IR, as well as National Climatic Center temperatures and rainfall, were also used. The HCMM apparent thermal inertia (ATI) images closely corresponded to the general soil map of Florida, based on soil drainage classes. Areas with low ATI overlay well-drained soils, such as deep sands and drained organic soils, whereas with high ATI overlay areas with wetlands and bodies of water. The HCMM ATI images also corresponded well with GOES-detected winter nocturnal cold-prone areas. Use of HCMM data with Carlson's energy balance model showed both high moisture availability (MA) and high thermal inertia (TI) of wetland-type surfaces and low MA and low TI of upland, well-drained soils. Since soil areas with low TI develop higher temperatures during the day, then antecedent patterns of highest maximum daytime surface temperature can also be used to predict nocturnal cold-prone areas in Florida.

Water Hydrogen-Bonding Network Structure and Dynamics at Phospholipid Multibilayer Surface: Femtosecond Mid-IR Pump-Probe Spectroscopy.

PubMed

Kundu, Achintya; Błasiak, Bartosz; Lim, Joon-Hyung; Kwak, Kyungwon; Cho, Minhaeng

2016-03-03

The water hydrogen-bonding network at a lipid bilayer surface is crucial to understanding membrane structures and its functional activities. With a phospholipid multibilayer mimicking a biological membrane, we study the temperature dependence of water hydrogen-bonding structure, distribution, and dynamics at a lipid multibilayer surface using femtosecond mid-IR pump-probe spectroscopy. We observe two distinguished vibrational lifetime components. The fast component (0.6 ps) is associated with water interacting with a phosphate part, whereas the slow component (1.9 ps) is with bulk-like choline-associated water. With increasing temperature, the vibrational lifetime of phosphate-associated water remains constant though its relative fraction dramatically increases. The OD stretch vibrational lifetime of choline-bound water slows down in a sigmoidal fashion with respect to temperature, indicating a noticeable change of the water environment upon the phase transition. The water structure and dynamics are thus shown to be in quantitative correlation with the structural change of liquid multibilayer upon the gel-to-liquid crystal phase transition.

Limitations of using a thermal imager for snow pit temperatures

NASA Astrophysics Data System (ADS)

Schirmer, M.; Jamieson, B.

2014-03-01

Driven by temperature gradients, kinetic snow metamorphism plays an import role in avalanche formation. When gradients based on temperatures measured 10 cm apart appear to be insufficient for kinetic metamorphism, faceting close to a crust can be observed. Recent studies that visualised small-scale (< 10 cm) thermal structures in a profile of snow layers with an infrared (IR) camera produced interesting results. The studies found melt-freeze crusts to be warmer or cooler than the surrounding snow depending on the large-scale gradient direction. However, an important assumption within these studies was that a thermal photo of a freshly exposed snow pit was similar enough to the internal temperature of the snow. In this study, we tested this assumption by recording thermal videos during the exposure of the snow pit wall. In the first minute, the results showed increasing gradients with time, both at melt-freeze crusts and artificial surface structures such as shovel scours. Cutting through a crust with a cutting blade or shovel produced small concavities (holes) even when the objective was to cut a planar surface. Our findings suggest there is a surface structure dependency of the thermal image, which was only observed at times during a strong cooling/warming of the exposed pit wall. We were able to reproduce the hot-crust/cold-crust phenomenon and relate it entirely to surface structure in a temperature-controlled cold laboratory. Concave areas cooled or warmed more slowly compared with convex areas (bumps) when applying temperature differences between snow and air. This can be explained by increased radiative and/or turbulent energy transfer at convex areas. Thermal videos suggest that such processes influence the snow temperature within seconds. Our findings show the limitations of using a thermal camera for measuring pit-wall temperatures, particularly during windy conditions, clear skies and large temperature differences between air and snow. At crusts or other heterogeneities, we were unable to create a sufficiently planar snow pit surface and non-internal gradients appeared at the exposed surface. The immediate adjustment of snow pit temperature as it reacts with the atmosphere complicates the capture of the internal thermal structure of a snowpack with thermal videos. Instead, the shown structural dependency of the IR signal may be used to detect structural changes of snow caused by kinetic metamorphism. The IR signal can also be used to measure near surface temperatures in a homogenous new snow layer.

Microwave-Accelerated Surface Modification of Plasmonic Gold Thin Films with Self-Assembled Monolayers of Alkanethiols

PubMed Central

Grell, Tsehai A.J.; Alabanza, Anginelle M.; Gaskell, Karen; Aslan, Kadir

2013-01-01

A rapid surface modification technique for the formation of self-assembled monolayers (SAMs) of alkanethiols on gold thin films using microwave heating in less than 10 min is reported. In this regard, SAMs of two model alkanethiols, 11-mercaptoundecanoic acid (11-MUDA, to generate a hydrophilic surface) and undecanethiol (UDET, a hydrophobic surface), were successfully formed on gold thin films using selective microwave heating in 1) a semi-continuous and 2) a continuous fashion and at room temperature (24 hours, control experiment, no microwave heating). The formation of SAMs of 11-MUDA and UDET were confirmed by contact angle measurements, Fourier–transform infrared (FT-IR) spectroscopy and X-ray photoelectron spectroscopy (XPS). The contact angles for water on SAMs formed by the selective microwave heating and conventional room temperature incubation technique (24 hours) were measured to be similar for 11-MUDA and UDET. FT-IR spectroscopy results confirmed that the internal structure of SAMs prepared using both microwave heating and at room temperature were similar. XPS results revealed that the organic and sulfate contaminants found on bare gold thin films were replaced by SAMs after the surface modification process was carried out using both microwave heating and at room temperature. PMID:24083414

Qualitative study of sexual functioning in couples with erectile dysfunction: prospective evaluation of the thermography diagnostic system.

PubMed

Ng, Wan Kee; Ng, Yin Kwee; Tan, Yung Khan

2009-01-01

To evaluate the prospective use of the thermography diagnostic system in assessing sexual function in patients with erectile dysfunction (ED). Thermographs were taken on 14 subjects in a clinical trial conducted at Tan Tock Seng Hospital. After a thorough clinical interview with a standardized questionnaire, patients were scanned for baseline temperature profile before being given an oral dose of sildenafil 100 mg. Subjects were scanned again in the same setting an hour later. If so desired, subjects were given visual stimulation and were allowed minimum direct stimulation, excluding the penis, to elicit erection. Temperature profiles were analyzed using the thermography analysis software in the VarioCAM camera. Three representative cases are presented to illustrate the potential for using the Infrared thermography (IR) diagnostic system in differentiating psychogenic ED. IR was able to capture a significant difference in blood flow to the corpus cavernosum. Subjects with psychogenic ED have higher surface temperatures (34.3 degrees C +/- 0.71 in the flaccid state and 35.3 degrees C +/- 0.2 during erection) compared to subjects with organic ED (33.64 degrees C +/- 0.4 in flaccid and 33.55 degrees C +/- 0.91 during erection). The difference in surface temperature between flaccid and erected states in subjects with organic ED was not significant. The proposed diagnostic test based on IR has tremendous clinical potential in differentiating psychogenic ED from organic ED. IR could potentially be a portable, noninvasive and convenient adjunct in the diagnosis and management of ED.

[Monitoring the thermal plume from coastal nuclear power plant using satellite remote sensing data: modeling, and validation].

PubMed

Zhu, Li; Zhao, Li-Min; Wang, Qiao; Zhang, Ai-Ling; Wu, Chuan-Qing; Li, Jia-Guo; Shi, Ji-Xiang

2014-11-01

Thermal plume from coastal nuclear power plant is a small-scale human activity, mornitoring of which requires high-frequency and high-spatial remote sensing data. The infrared scanner (IRS), on board of HJ-1B, has an infrared channel IRS4 with 300 m and 4-days as its spatial and temporal resolution. Remote sensing data aquired using IRS4 is an available source for mornitoring thermal plume. Retrieval pattern for coastal sea surface temperature (SST) was built to monitor the thermal plume from nuclear power plant. The research area is located near Guangdong Daya Bay Nuclear Power Station (GNPS), where synchronized validations were also implemented. The National Centers for Environmental Prediction (NCEP) data was interpolated spatially and temporally. The interpolated data as well as surface weather conditions were subsequently employed into radiative transfer model for the atmospheric correction of IRS4 thermal image. A look-up-table (LUT) was built for the inversion between IRS4 channel radiance and radiometric temperature, and a fitted function was also built from the LUT data for the same purpose. The SST was finally retrieved based on those preprocessing procedures mentioned above. The bulk temperature (BT) of 84 samples distributed near GNPS was shipboard collected synchronically using salinity-temperature-deepness (CTD) instruments. The discrete sample data was surface interpolated and compared with the satellite retrieved SST. Results show that the average BT over the study area is 0.47 degrees C higher than the retrieved skin temperature (ST). For areas far away from outfall, the ST is higher than BT, with differences less than 1.0 degrees C. The main driving force for temperature variations in these regions is solar radiation. For areas near outfall, on the contrary, the retrieved ST is lower than BT, and greater differences between the two (meaning > 1.0 degrees C) happen when it gets closer to the outfall. Unlike the former case, the convective heat transfer resulting from the thermal plume is the primary reason leading to the temperature variations. Temperature rising (TR) distributions obtained from remote sensing data and in-situ measurements are consistent, except that the interpolated BT shows more level details (> 5 levels) than that of the ST (up to 4 levels). The areas with higher TR levels (> 2) are larger on BT maps, while for lower TR levels (≤ 2), the two methods perform with no obvious differences. Minimal errors for satellite-derived SST occur regularly around local time 10 a. m. This makes the remote sensing results to be substitutes for in-situ measurements. Therefore, for operational applications of HJ-1B IRS4, remote sensing technique can be a practical approach to monitoring the nuclear plant thermal pollution around this time period.

System and method for online inspection of turbines using an optical tube with broadspectrum mirrors

DOEpatents

Baleine, Erwan

2015-12-22

An optical inspection system for nondestructive internal visual inspection and non-contact infra-red (IR) temperature monitoring of an online, operating power generation turbine. The optical inspection system includes an optical tube having a viewing port, at least one reflective mirror or a mirror array having a reflectivity spectral range from 550 nm to 20 .mu.m, and capable of continuous operation at temperatures greater than 932 degrees Fahrenheit (500 degrees Celsius), and a transparent window with high transmission within the same spectral range mounted distal the viewing port. The same optical mirror array may be used to measure selectively surface temperature of metal turbine blades in the near IR range (approximately 1 .mu.m wavelength) and of thermal barrier coated turbine blades in the long IR range (approximately 10 .mu.m wavelength).

Study of optical techniques for the Ames unitary wind tunnel. Part 5: Infrared imagery

NASA Technical Reports Server (NTRS)

Lee, George

1992-01-01

A survey of infrared thermography for aerodynamics was made. Particular attention was paid to boundary layer transition detection. IR thermography flow visualization of 2-D and 3-D separation was surveyed. Heat transfer measurements and surface temperature measurements were also covered. Comparisons of several commercial IR cameras were made. The use of a recently purchased IR camera in the Ames Unitary Plan Wind Tunnels was studied. Optical access for these facilities and the methods to scan typical models was investigated.

In situ studies of surface of NiFe 2O 4 catalyst during complete oxidation of methane

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Shiran; Shan, Junjun; Nie, Longhui

2015-12-21

Here, NiFe 2O 4 with an inverse spinel structure exhibits high activity for a complete oxidation of methane at 400 °C–425 °C and a higher temperature. The surface of the catalyst and its adsorbates were well characterized with ambient pressure X-ray photoelectron spectroscopy (AP-XPS) and in situ infrared spectroscopy (IR). In situ studies of the surface of NiFe 2O 4 using AP-XPS suggest the formation of methoxy-like and formate-like intermediates at a temperature lower than 200 °C, supported by the observed vibrational signatures in in situ IR studies. Evolutions of C1s photoemission features and the nominal atomic ratios of C/(Nimore » + Fe) of the catalyst surface suggest that the formate-like intermediate is transformed to product molecules CO 2 and H 2O in the temperature range of 250–300 °C. In situ studies suggest the formation of a spectator, – O lattice – CH 2 – O lattice –. It strongly bonds to surface through C–O bonds and cannot be activated even at 400 °C.« less

Thermal stability of chemically bonded phases on silica gel by photoacoustic FT-IR spectroscopy

NASA Astrophysics Data System (ADS)

Kierys, A.; Pasieczna, S.; Ryczkowski, J.; Goworek, J.

2006-11-01

The temperature resistance of chemically bonded phases on commercial silica gel, LiChrosorb RP 2, RP 8, RP 18 and unmodified Si 60 were tested at different temperatures by photoacoustic FT-IR spectroscopy. The surface characteristics and possible degradation of hydrocarbon phase at higher temperatures were investigated by means of FT-IR/PAS technique. For a series of investigated samples heated up to 423 K, the FT-IR/PAS spectra are similar to those for initial silica samples. The most characteristic band for alkyl modified silica gel, i.e., RP 2, RP 8, and RP 18 was observed between 3200 cm-1 to 2800 cm-1 corresponding to various hydrocarbon species. The bands at 3745 cm-1, 3650 cm-1, and 3430 cm-1 observed in the photoacoustic FT-IR spectra may be ascribed to isolated silanol groups (Si-OH), geminal groups (Si-(OH)2) and hydrogen-bonded Si-OH groups, respectively. For all samples the intensity of the broad band in the region 3800 cm-1 to 3200 cm-1 decreases with the increasing temperature. The additional peak at 3745 cm-1 for chemically bonded long hydrocarbon chain, i.e., C18 and C8 after thermal treatment at 573 K is observed.

Scanning tone burst eddy-current thermography (S-TBET) for NDT of carbon fiber reinforced plastic (CFRP) components

DOE Office of Scientific and Technical Information (OSTI.GOV)

Libin, M. N.; Maxfield, B. W.; Balasubramanian, Krishnan

2014-02-18

Tone Burst Eddy Current technique uses eddy current to apply transient heating inside a component and uses a conventional IR camera for visualization of the response to the transient heating. This technique has been earliest demonstrated for metallic components made of AL, Steel, Stainless Steel, etc., and for detection of cracks, corrosion and adhesive dis-bonds. Although, not nearly as conducting as metals, the Carbon Fibre Reinforced Plastic (CFRP) material absorbs measurable electromagnetic radiation in the frequency range above 10 kHz. When the surface temperature is observed on the surface that is being heated (defined as the surface just beneath andmore » slightly to one side of the heating coil), the surface temperature increases with increasing frequency because the internal heating increases with frequency. A 2-D anisotropic transient Eddy current heating and thermal conduction model has been developed that provides a reasonable description of the processes described above. The inherent anisotropy of CFRP laminates is included in this model by calculating the heating due to three superimposed, tightly coupled isotropic layers having a specified ply-layup. The experimental apparatus consists of an induction heating coil and an IR camera with low NETD and high frame rates. The coil is moved over the sample using a stepper motor controlled manipulator. The IR data recording is synchronized with the motion control to provide a movie of the surface temperature over time. Several components were evaluated for detection of impact damage, location of stiffeners, etc. on CFRP components.« less

Ultrafast Silicon Photonics with Visible to Mid-Infrared Pumping of Silicon Nanocrystals.

PubMed

Diroll, Benjamin T; Schramke, Katelyn S; Guo, Peijun; Kortshagen, Uwe R; Schaller, Richard D

2017-10-11

Dynamic optical control of infrared (IR) transparency and refractive index is achieved using boron-doped silicon nanocrystals excited with mid-IR optical pulses. Unlike previous silicon-based optical switches, large changes in transmittance are achieved without a fabricated structure by exploiting strong light coupling of the localized surface plasmon resonance (LSPR) produced from free holes of p-type silicon nanocrystals. The choice of optical excitation wavelength allows for selectivity between hole heating and carrier generation through intraband or interband photoexcitation, respectively. Mid-IR optical pumping heats the free holes of p-Si nanocrystals to effective temperatures greater than 3500 K. Increases of the hole effective mass at high effective hole temperatures lead to a subpicosecond change of the dielectric function, resulting in a redshift of the LSPR, modulating mid-IR transmission by as much as 27%, and increasing the index of refraction by more than 0.1 in the mid-IR. Low hole heat capacity dictates subpicosecond hole cooling, substantially faster than carrier recombination, and negligible heating of the Si lattice, permitting mid-IR optical switching at terahertz repetition frequencies. Further, the energetic distribution of holes at high effective temperatures partially reverses the Burstein-Moss effect, permitting the modulation of transmittance at telecommunications wavelengths. The results presented here show that doped silicon, particularly in micro- or nanostructures, is a promising dynamic metamaterial for ultrafast IR photonics.

Ultrafast Silicon Photonics with Visible to Mid-Infrared Pumping of Silicon Nanocrystals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Diroll, Benjamin T.; Schramke, Katelyn S.; Guo, Peijun

Dynamic optical control of infrared (IR) transparency and refractive index is achieved using boron-doped silicon nanocrystals excited with mid-IR optical pulses. Also, unlike previous silicon-based optical switches, large changes in transmittance are achieved without a fabricated structure by exploiting strong light coupling of the localized surface plasmon resonance (LSPR) produced from free holes of p-type silicon nanocrystals. The choice of optical excitation wavelength allows selectivity between hole heating and carrier generation through intraband or interband photoexcitation, respectively. Mid-IR optical pumping heats the free holes of p-Si nanocrystals to effective temperatures greater than 3500 K. Increases of the hole effective massmore » at high effective hole temperatures lead to a sub-picosecond change of the dielectric function resulting in a redshift of the LSPR, modulating mid-IR transmission by as much as 27% and increasing the index of refraction by more than 0.1 in the mid-IR. Low hole heat capacity dictates sub-picosecond hole cooling, substantially faster than carrier recombination, and negligible heating of the Si lattice, permitting mid-IR optical switching at terahertz repetition frequencies. Further, the energetic distribution of holes at high effective temperatures partially reverses the Burstein-Moss effect, permitting modulation of transmittance at telecommunications wavelengths. Lastly, the results presented here show that doped silicon, particularly in micro- or nanostructures, is a promising dynamic metamaterial for ultrafast IR photonics.« less

Ultrafast Silicon Photonics with Visible to Mid-Infrared Pumping of Silicon Nanocrystals

DOE PAGES

Diroll, Benjamin T.; Schramke, Katelyn S.; Guo, Peijun; ...

2017-09-11

Dynamic optical control of infrared (IR) transparency and refractive index is achieved using boron-doped silicon nanocrystals excited with mid-IR optical pulses. Also, unlike previous silicon-based optical switches, large changes in transmittance are achieved without a fabricated structure by exploiting strong light coupling of the localized surface plasmon resonance (LSPR) produced from free holes of p-type silicon nanocrystals. The choice of optical excitation wavelength allows selectivity between hole heating and carrier generation through intraband or interband photoexcitation, respectively. Mid-IR optical pumping heats the free holes of p-Si nanocrystals to effective temperatures greater than 3500 K. Increases of the hole effective massmore » at high effective hole temperatures lead to a sub-picosecond change of the dielectric function resulting in a redshift of the LSPR, modulating mid-IR transmission by as much as 27% and increasing the index of refraction by more than 0.1 in the mid-IR. Low hole heat capacity dictates sub-picosecond hole cooling, substantially faster than carrier recombination, and negligible heating of the Si lattice, permitting mid-IR optical switching at terahertz repetition frequencies. Further, the energetic distribution of holes at high effective temperatures partially reverses the Burstein-Moss effect, permitting modulation of transmittance at telecommunications wavelengths. Lastly, the results presented here show that doped silicon, particularly in micro- or nanostructures, is a promising dynamic metamaterial for ultrafast IR photonics.« less

Relationship between dynamic infrared thermal images and blood perfusion rate of the tongue in anaemia patients

NASA Astrophysics Data System (ADS)

Xie, Haiwei; Zhang, Yan

2018-03-01

The relationship between dynamic infrared (IR) thermal images and blood perfusion rate of the tongues of anaemia patients was investigated. Blood perfusion rates at multiple locations on the tongues of 62 anaemia patients and 70 control subjects were measured. For both groups of subjects, dynamic IR thermal images were also recorded within 16 s after the mouth opened. The results showed that the blood perfusion rates at different sites (apex, middle, left side and right side) on the tongues in anaemia patients (3.49, 3.71, 3.85 and 3.77 kg/s m-3) were significantly lower than those at the corresponding sites in control subjects (4.45, 4.66, 4.81 and 4.70 kg/s m-3). After the mouth opened, the tongue temperature decreased more rapidly in anaemia patients than in control subjects. To analyse the heat transfer mechanism, a transient heat transfer model of the tongue was developed. The tongue temperatures in anaemia patients and control subjects were calculated using this model and compared to the tongue temperatures measured by the IR thermal imager. The relationship between the tongue surface temperature and the tongue blood perfusion rate was analysed. The simulation results indicated that the low blood perfusion rate and the correlated changes in anaemia patients can cause faster temperature decreases of the tongue surface.

A dual-band adaptor for infrared imaging.

PubMed

McLean, A G; Ahn, J-W; Maingi, R; Gray, T K; Roquemore, A L

2012-05-01

A novel imaging adaptor providing the capability to extend a standard single-band infrared (IR) camera into a two-color or dual-band device has been developed for application to high-speed IR thermography on the National Spherical Tokamak Experiment (NSTX). Temperature measurement with two-band infrared imaging has the advantage of being mostly independent of surface emissivity, which may vary significantly in the liquid lithium divertor installed on NSTX as compared to that of an all-carbon first wall. In order to take advantage of the high-speed capability of the existing IR camera at NSTX (1.6-6.2 kHz frame rate), a commercial visible-range optical splitter was extensively modified to operate in the medium wavelength and long wavelength IR. This two-band IR adapter utilizes a dichroic beamsplitter, which reflects 4-6 μm wavelengths and transmits 7-10 μm wavelength radiation, each with >95% efficiency and projects each IR channel image side-by-side on the camera's detector. Cutoff filters are used in each IR channel, and ZnSe imaging optics and mirrors optimized for broadband IR use are incorporated into the design. In-situ and ex-situ temperature calibration and preliminary data of the NSTX divertor during plasma discharges are presented, with contrasting results for dual-band vs. single-band IR operation.

Highly sensitive room temperature ammonia gas sensor based on Ir-doped Pt porous ceramic electrodes

NASA Astrophysics Data System (ADS)

Liu, Wenlong; Liu, Yen-Yu; Do, Jing-Shan; Li, Jing

2016-12-01

Room temperature NH3 gas sensors based on Pt and Pt-Ir (Ir doping Pt) porous ceramic electrodes have been fabricated by both electroplating and sputtering methods. The properties of the gaseous ammonia sensors have been examined by polarization and chronoamperometry techniques. The influence of humidity on the features of the resulting sensors in the system has also been discussed, and the working potential was optimized. Water vapors seem to hugely improve the electrochemical activity of the electrode. With increasing the relative humidity, the response of the Pt-Ir(E)/Pt(S)/PCP sensor to NH3 gas could be enhanced remarkably, and the sensitivity increases from 1.14 to 12.06 μA ppm-1 cm-2 .Then we have also discussed the sensing mechanism of the Pt-Ir sensor and the result has been confirmed by X-ray photoelectron spectroscopy of the electrode surface before and after reaction in the end.

Oxidation of CO by NO on planar and faceted Ir(210)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Wenhua; Bartynski, Robert A.; Kaghazchi, Payam

2012-06-11

Oxidation of CO by pre-adsorbed NO has been studied on planar Ir(210) and nanofaceted Ir(210) with average facet sizes of 5 nm and 14 nm by temperature programmed desorption (TPD). Both surfaces favor oxidation of CO to CO 2, which is accompanied by simultaneous reduction of NO with high selectivity to N 2. At low NO pre-coverage, the temperature (T i) for the onset of CO 2 desorption as well as CO 2 desorption peak temperature (T p) decreases with increasing CO exposure, and NO dissociation is affected by co-adsorbed CO. At high NO pre-coverage, T i and T pmore » are independent of CO exposure, and co-adsorbed CO has no influence on dissociation of NO. Moreover, at low NO pre-coverage, planar Ir(210) is more active than faceted Ir(210) for oxidation of CO to CO 2: T i and T p are much lower on planar Ir(210) than that on faceted Ir(210). In addition, faceted Ir(210) with an average facet size of 5 nm is more active for oxidation of CO to CO 2 than faceted Ir(210) with an average facet size of 14 nm, i.e., oxidation of CO by pre-adsorbed NO on faceted Ir(210) exhibits size effects on the nanometer scale. In comparison, at low O pre-coverage planar Ir(210) is more active than faceted Ir(210) for oxidation of CO to CO 2 but no evidence has been found for size effects in oxidation of CO by pre-adsorbed oxygen on faceted Ir(210) for average facet sizes of 5 nm and 14 nm. The TPD data indicate the same reaction pathway for CO 2 formation from CO + NO and CO + O reactions on planar Ir(210). Lastly, the adsorption sites of CO, NO, O, CO + O, and CO + NO on Ir are characterized by density functional theory.« less

Boundary-Layer Detection at Cryogenic Conditions Using Temperature Sensitive Paint Coupled with a Carbon Nanotube Heating Layer

NASA Technical Reports Server (NTRS)

Goodman, Kyle Z.; Lipford, William E.; Watkins, Anthony Neal

2016-01-01

Detection of flow transition on aircraft surfaces and models can be vital to the development of future vehicles and computational methods for evaluating vehicle concepts. In testing at ambient conditions, IR thermography is ideal for this measurement. However, for higher Reynolds number testing, cryogenic facilities are often used, in which IR thermography is difficult to employ. In these facilities, temperature sensitive paint is an alternative with a temperature step introduced to enhance the natural temperature change from transition. Traditional methods for inducing the temperature step by changing the liquid nitrogen injection rate often change the tunnel conditions. Recent work has shown that adding a layer consisting of carbon nanotubes to the surface can be used to impart a temperature step on the model surface with little change in the operating conditions. Unfortunately, this system physically degraded at 130 K and lost heating capability. This paper describes a modification of this technique enabling operation down to at least 77 K, well below the temperature reached in cryogenic facilities. This is possible because the CNT layer is in a polyurethane binder. This was tested on a Natural Laminar Flow model in a cryogenic facility and transition detection was successfully visualized at conditions from 200 K to 110 K. Results were also compared with the traditional temperature step method.

Boundary-Layer Detection at Cryogenic Conditions Using Temperature Sensitive Paint Coupled with a Carbon Nanotube Heating Layer.

PubMed

Goodman, Kyle Z; Lipford, William E; Watkins, Anthony Neal

2016-12-03

Detection of flow transition on aircraft surfaces and models can be vital to the development of future vehicles and computational methods for evaluating vehicle concepts. In testing at ambient conditions, IR thermography is ideal for this measurement. However, for higher Reynolds number testing, cryogenic facilities are often used, in which IR thermography is difficult to employ. In these facilities, temperature sensitive paint is an alternative with a temperature step introduced to enhance the natural temperature change from transition. Traditional methods for inducing the temperature step by changing the liquid nitrogen injection rate often change the tunnel conditions. Recent work has shown that adding a layer consisting of carbon nanotubes to the surface can be used to impart a temperature step on the model surface with little change in the operating conditions. Unfortunately, this system physically degraded at 130 K and lost heating capability. This paper describes a modification of this technique enabling operation down to at least 77 K, well below the temperature reached in cryogenic facilities. This is possible because the CNT layer is in a polyurethane binder. This was tested on a Natural Laminar Flow model in a cryogenic facility and transition detection was successfully visualized at conditions from 200 K to 110 K. Results were also compared with the traditional temperature step method.

Boundary-Layer Detection at Cryogenic Conditions Using Temperature Sensitive Paint Coupled with a Carbon Nanotube Heating Layer

PubMed Central

Goodman, Kyle Z.; Lipford, William E.; Watkins, Anthony Neal

2016-01-01

Detection of flow transition on aircraft surfaces and models can be vital to the development of future vehicles and computational methods for evaluating vehicle concepts. In testing at ambient conditions, IR thermography is ideal for this measurement. However, for higher Reynolds number testing, cryogenic facilities are often used, in which IR thermography is difficult to employ. In these facilities, temperature sensitive paint is an alternative with a temperature step introduced to enhance the natural temperature change from transition. Traditional methods for inducing the temperature step by changing the liquid nitrogen injection rate often change the tunnel conditions. Recent work has shown that adding a layer consisting of carbon nanotubes to the surface can be used to impart a temperature step on the model surface with little change in the operating conditions. Unfortunately, this system physically degraded at 130 K and lost heating capability. This paper describes a modification of this technique enabling operation down to at least 77 K, well below the temperature reached in cryogenic facilities. This is possible because the CNT layer is in a polyurethane binder. This was tested on a Natural Laminar Flow model in a cryogenic facility and transition detection was successfully visualized at conditions from 200 K to 110 K. Results were also compared with the traditional temperature step method. PMID:27918493

Testing of Wrought Iridium/Chemical Vapor Deposition Rhenium Rocket

NASA Technical Reports Server (NTRS)

Reed, Brian D.; Schneider, Steven J.

1996-01-01

A 22-N class, iridium/rhenium (Ir/Re) rocket chamber, composed of a thick (418 miocrometer) wrought iridium (Ir) liner and a rhenium substrate deposited via chemical vapor deposition, was tested over an extended period on gaseous oxygen/gaseous hydrogen (GO2/GH2) propellants. The test conditions were designed to produce species concentrations similar to those expected in an Earth-storable propellant combustion environment. Temperatures attained in testing were significantly higher than those expected with Earth-storable propellants, both because of the inherently higher combustion temperature of GO2/GH2 propellants and because the exterior surface of the rocket was not treated with a high-emissivity coating that would be applied to flight class rockets. Thus the test conditions were thought to represent a more severe case than for typical operational applications. The chamber successfully completed testing (over 11 hr accumulated in 44 firings), and post-test inspections showed little degradation of the Ir liner. The results indicate that use of a thick, wrought Ir liner is a viable alternative to the Ir coatings currently used for Ir/Re rockets.

Study of heating capacity of focused IR light soldering systems.

PubMed

Anguiano, C; Félix, M; Medel, A; Bravo, M; Salazar, D; Márquez, H

2013-10-07

An experimental study about four optical setups used for developing a Focused IR Light Soldering System (FILSS) for Surface Mount Technology (SMT) lead-free electronic devices specifically for Ball Grid Arrays (BGA) is presented. An analysis of irradiance and infrared thermography at BGA surface is presented, as well as heat transfer by radiation and conduction process from the surface of the BGA to the solder balls. The results of this work show that the heating provided by our proposed optical setups, measured at the BGA under soldering process, meets the high temperature and uniform thermal distribution requirements, which are defined by the reflow solder method for SMT devices.

The Response of the Ocean Thermal Skin Layer to Variations in Incident Infrared Radiation

NASA Astrophysics Data System (ADS)

Wong, Elizabeth W.; Minnett, Peter J.

2018-04-01

Ocean warming trends are observed and coincide with the increase in concentrations of greenhouse gases in the atmosphere resulting from human activities. At the ocean surface, most of the incoming infrared (IR) radiation is absorbed within the top micrometers of the ocean's surface where the thermal skin layer (TSL) exists. Thus, the incident IR radiation does not directly heat the upper few meters of the ocean. This paper investigates the physical mechanism between the absorption of IR radiation and its effect on heat transfer at the air-sea boundary. The hypothesis is that given the heat lost through the air-sea interface is controlled by the TSL, the TSL adjusts in response to variations in incident IR radiation to maintain the surface heat loss. This modulates the flow of heat from below and hence controls upper ocean heat content. This hypothesis is tested using the increase in incoming longwave radiation from clouds and analyzing vertical temperature profiles in the TSL retrieved from sea-surface emission spectra. The additional energy from the absorption of increasing IR radiation adjusts the curvature of the TSL such that the upward conduction of heat from the bulk of the ocean into the TSL is reduced. The additional energy absorbed within the TSL supports more of the surface heat loss. Thus, more heat beneath the TSL is retained leading to the observed increase in upper ocean heat content.

Evapotranspiration from combined reflected solar and emitted terrestrial radiation - Preliminary FIFE results from AVHRR data

NASA Technical Reports Server (NTRS)

Goward, S. N.; Hope, A. S.

1989-01-01

The relation between remotely sensed spectral vegetation indices and thermal IR measurements is studied. Land surface evapotranspiration is evaluated based on this relationship. Analysis of the AVHRR data, obtained in Kansas in 1987, reveal a strong correlation between the spectral vegetation indices and surface temperature and this relation covaries with surface moisture conditions. It is noted that the relation between remotely sensed measurements of canopy green foliage and surface temperature is useful for examining variations in the interface thermal inertia and energy balance Bowen ratio.

System and method for laser-based, non-evaporative repair of damage sites in the surfaces of fused silica optics

DOEpatents

Adams, John J.; Bolourchi, Masoud; Bude, Jeffrey D.; Guss, Gabriel M.; Jarboe, Jeffery A.; Matthews, Manyalibo J.; Nostrand, Michael C; Wegner, Paul J.

2016-09-06

A method for repairing a damage site on a surface of an optical material is disclosed. The method may involve focusing an Infrared (IR) laser beam having a predetermined wavelength, with a predetermined beam power, to a predetermined full width ("F/W") 1/e.sup.2 diameter spot on the damage site. The focused IR laser beam is maintained on the damage site for a predetermined exposure period corresponding to a predetermined acceptable level of downstream intensification. The focused IR laser beam heats the damage site to a predetermined peak temperature, which melts and reflows material at the damage site of the optical material to create a mitigated site.

Low-speed flowfield characterization by infrared measurements of surface temperatures

NASA Technical Reports Server (NTRS)

Gartenberg, E.; Roberts, A. S., Jr.; Mcree, G. J.

1989-01-01

An experimental program was aimed at identifying areas in low speed aerodynamic research where infrared imaging systems can make significant contributions. Implementing a new technique, a long electrically heated wire was placed across a laminar jet. By measuring the temperature distribution along the wire with the IR imaging camera, the flow behavior was identified. Furthermore, using Nusselt number correlations, the velocity distribution could be deduced. The same approach was used to survey wakes behind cylinders in a wind-tunnel. This method is suited to investigate flows with position dependent velocities, e.g., boundary layers, confined flows, jets, wakes, and shear layers. It was found that the IR imaging camera cannot accurately track high gradient temperature fields. A correlation procedure was devised to account for this limitation. Other wind-tunnel experiments included tracking the development of the laminar boundary layer over a warmed flat plate by measuring the chordwise temperature distribution. This technique was applied also to the flow downstream from a rearward facing step. Finally, the IR imaging system was used to study boundary layer behavior over an airfoil at angles of attack from zero up to separation. The results were confirmed with tufts observable both visually and with the IR imaging camera.

Results of a joint NOAA/NASA sounder simulation study

NASA Technical Reports Server (NTRS)

Phillips, N.; Susskind, Joel; Mcmillin, L.

1988-01-01

This paper presents the results of a joint NOAA and NASA sounder simulation study in which the accuracies of atmospheric temperature profiles and surface skin temperature measuremnents retrieved from two sounders were compared: (1) the currently used IR temperature sounder HIRS2 (High-resolution Infrared Radiation Sounder 2); and (2) the recently proposed high-spectral-resolution IR sounder AMTS (Advanced Moisture and Temperature Sounder). Simulations were conducted for both clear and partial cloud conditions. Data were analyzed at NASA using a physical inversion technique and at NOAA using a statistical technique. Results show significant improvement of AMTS compared to HIRS2 for both clear and cloudy conditions. The improvements are indicated by both methods of data analysis, but the physical retrievals outperform the statistical retrievals.

Hot filament CVD of boron nitride films

DOEpatents

Rye, Robert R.

1992-01-01

Using a hot filament (.apprxeq.1400.degree. C.) to activate borazine (B.sub.3 N.sub.3 H.sub.6) molecules for subsequent reaction with a direct line-of-sight substrate, transparent boron ntiride films as thick as 25,000 angstroms are grown for a substrate temperature as low as 100.degree. C. The minimum temperature is determined by radiative heating from the adjacent hot filament. The low temperature BN films show no indication of crystallinity with X-ray diffraction (XRD). X-ray photoelectron spectra (XPS) show the films to have a B:N ratio of 0.97:1 with no other XPS detectable impurities above the 0.5% level. Both Raman and infrared (IR) spectroscopy are characteristic of h-BN with small amounts of hydrogen detected as N-H and B-H bands in the IR spectrum. An important feature of this method is the separation and localization of the thermal activation step at the hot filament from the surface reaction and film growth steps at the substrate surface. This allows both higher temperature thermal activation and lower temperature film growth.

Aircraft and satellite remote sensing of desert soils and landscapes

NASA Technical Reports Server (NTRS)

Petersen, G. W.; Connors, K. F.; Miller, D. A.; Day, R. L.; Gardner, T. W.

1987-01-01

Remote sensing data on desert soils and landscapes, obtained by the Landsat TM, Heat Capacity Mapping Mission (HCMM), Simulated SPOT, and Thermal IR Multispectral Scanner (TIMS) aboard an aircraft, are discussed together with the analytical techniques used in the studies. The TM data for southwestern Nevada were used to discriminate among the alluvial fan deposits with different degrees of desert pavement and varnish, and different vegetation cover. Thermal-IR data acquired from the HCMM satellite were used to map the spatial distribution of diurnal surface temperatures and to estimate mean annual soil temperatures in central Utah. Simulated SPOT data for northwestern New Mexico identified geomorphic features, such as differences in eolian sand cover and fluvial incision, while the TIMS data depicted surface geologic features of the Saline Valley in California.

Characteristics of the surface chemistry of linden pyrochar after removal of labile organic matter

NASA Astrophysics Data System (ADS)

Valeeva, A. A.; Smirnova, E. V.; Giniyatullin, K. G.; Vorobev, V. V.; Biktasheva, L. R.; Grachev, A. N.

2018-01-01

The changes of chemical properties of the pyrochar surface were studied in the laboratory experiment that simulated pedogenic transformation of pyrochar under the influence of soil biota. The native pyrochar samples were obtained by pyrolysis of linden wood residues at the temperature of 250°C, 450°C and 650°C. Their modified samples were obtained by removing an easily degradable pool of organic substances that can be used by microorganisms during the first months after application to the soil. In low-temperature linden pyrochar (250°C and 450°C) dominated carboxylic and phenolic surface groups, in high-temperature (650°C) - lactonic groups. After removal of readily decomposable organic substances the acidity of the phenolic and lactonic groups in pyrochar of low-temperature pyrolysis sharply decreased. Characteristic feature of all studied samples is the presence in IR spectra of absorption bands of gyroxyl, carbonyl, methylene groups and organosilicon polymers. The feature of IR spectra of linden pyrochar (250°C and 450°C) is the presence of absorption bands of the stretching vibrations of the tertiary alcohols and phenols C-O group.

Analysis of The Surface Radiative Budget Using ATLAS Data for San Juan, Puerto Rico

NASA Technical Reports Server (NTRS)

Luvall, Jeffrey C.; Rickman, D. L.; Gonzalez, J.; Comarazamy, Daniel; Picon, Ana

2007-01-01

The additional beating of the air over the city is the result of the replacement of naturally vegetated surfaces with those composed of asphalt, concrete, rooftops and other man-made materials. The temperatures of these artificial surfaces can be 20 to 40 C higher than vegetated surfaces. This produces a dome of elevated air temperatures 5 to 8 C greater over the city, compared to the air temperatures over adjacent rural areas. Urban landscapes are a complex mixture of vegetated and nonvegetated surfaces. It is difficult to take enough temperature measurements over a large city area to characterize the complexity of urban radiant surface temperature variability. The NASA Airborne Thermal and Land Applications Sensor (ATLAS) operates in the visual and IR bands was used in February 2004 to collect data from San Juan, Puerto Rico with the main objective of investigating the Urban Heat Island (UHI) in tropical cities.

Stabilizing Ir(001) Epitaxy on Yttria-Stabilized Zirconia Using a Thin Ir Seed Layer Grown by Pulsed Laser Deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fan, Lisha; Jacobs, Christopher B.; Rouleau, Christopher M.

In this paper, we demonstrate the reproducible epitaxial growth of 100 nm thick Ir(001) films on a heteroepitaxial stack consisting of 5 nm Ir and 100 nm yttria-stabilized zirconia (YSZ) grown on Si(001) substrates. It is shown that a 5 nm thick Ir layer grown by pulsed laser deposition in the same chamber as the YSZ film without breaking the vacuum is the key to stabilizing Ir(001) epitaxial growth. Growth of the Ir seed layer with pure (001) orientation occurs only in a narrow growth temperature window from 550 to 750 °C, and the fraction of Ir(111) increases at substratemore » temperatures outside of this window. The Ir seed layer prevents exposure of the YSZ film to air during sample transfer and enables highly reproducible Ir(001) heteroepitaxy on YSZ buffered Si(001). In contrast, if Ir is grown directly on a bare YSZ layer that was exposed to ambient conditions, the films are prone to change orientation to (111). These results reveal that preserving the chemical and structural purity of the YSZ surface is imperative for achieving Ir(001) epitaxy. The narrow range of the mosaic spread values from eight experiments demonstrates the high yield and high reproducibility of Ir(001) heteroepitaxy by this approach. Lastly, the improved Ir(001) epitaxial growth method is of great significance for integrating a variety of technologically important materials such as diamond, graphene, and functional oxides on a Si platform.« less

Stabilizing Ir(001) Epitaxy on Yttria-Stabilized Zirconia Using a Thin Ir Seed Layer Grown by Pulsed Laser Deposition

DOE PAGES

Fan, Lisha; Jacobs, Christopher B.; Rouleau, Christopher M.; ...

2016-11-18

In this paper, we demonstrate the reproducible epitaxial growth of 100 nm thick Ir(001) films on a heteroepitaxial stack consisting of 5 nm Ir and 100 nm yttria-stabilized zirconia (YSZ) grown on Si(001) substrates. It is shown that a 5 nm thick Ir layer grown by pulsed laser deposition in the same chamber as the YSZ film without breaking the vacuum is the key to stabilizing Ir(001) epitaxial growth. Growth of the Ir seed layer with pure (001) orientation occurs only in a narrow growth temperature window from 550 to 750 °C, and the fraction of Ir(111) increases at substratemore » temperatures outside of this window. The Ir seed layer prevents exposure of the YSZ film to air during sample transfer and enables highly reproducible Ir(001) heteroepitaxy on YSZ buffered Si(001). In contrast, if Ir is grown directly on a bare YSZ layer that was exposed to ambient conditions, the films are prone to change orientation to (111). These results reveal that preserving the chemical and structural purity of the YSZ surface is imperative for achieving Ir(001) epitaxy. The narrow range of the mosaic spread values from eight experiments demonstrates the high yield and high reproducibility of Ir(001) heteroepitaxy by this approach. Lastly, the improved Ir(001) epitaxial growth method is of great significance for integrating a variety of technologically important materials such as diamond, graphene, and functional oxides on a Si platform.« less

Estimation of regional surface resistance to evapotranspiration from NDVI and thermal-IR AVHRR data. [Normalized Difference Vegetation Index

NASA Technical Reports Server (NTRS)

Nemani, Ramakrishna R.; Running, Steven W.

1989-01-01

Infrared surface temperatures from satellite sensors have been used to infer evaporation and soil moisture distribution over large areas. However, surface energy partitioning to latent versus sensible heat changes with surface vegetation cover and water availability. The hypothesis that the relationship between surface temperature and canopy density is sensitivite to seasonal changes in canopy resistance of conifer forests is presently tested. Surface temperature and canopy density were computed for a 20 x 25 km forested region in Montana, from the NOAA/AVHRR for 8 days during the summer of 1985. A forest ecosystem model, FOREST-BGC, simulated canopy resistance for the same period. For all eight days, surface temperatures had high association with canopy density, measured as Normalized Difference Vegetation Index, implying that latent heat exchange is the major cause of spatial variations in surface radiant tmeperatures.

Automated processing of thermal infrared images of Osservatorio Vesuviano permanent surveillance network by using Matlab code

NASA Astrophysics Data System (ADS)

Sansivero, Fabio; Vilardo, Giuseppe; Caputo, Teresa

2017-04-01

The permanent thermal infrared surveillance network of Osservatorio Vesuviano (INGV) is composed of 6 stations which acquire IR frames of fumarole fields in the Campi Flegrei caldera and inside the Vesuvius crater (Italy). The IR frames are uploaded to a dedicated server in the Surveillance Center of Osservatorio Vesuviano in order to process the infrared data and to excerpt all the information contained. In a first phase the infrared data are processed by an automated system (A.S.I.R.A. Acq- Automated System of IR Analysis and Acquisition) developed in Matlab environment and with a user-friendly graphic user interface (GUI). ASIRA daily generates time-series of residual temperature values of the maximum temperatures observed in the IR scenes after the removal of seasonal effects. These time-series are displayed in the Surveillance Room of Osservatorio Vesuviano and provide information about the evolution of shallow temperatures field of the observed areas. In particular the features of ASIRA Acq include: a) efficient quality selection of IR scenes, b) IR images co-registration in respect of a reference frame, c) seasonal correction by using a background-removal methodology, a) filing of IR matrices and of the processed data in shared archives accessible to interrogation. The daily archived records can be also processed by ASIRA Plot (Matlab code with GUI) to visualize IR data time-series and to help in evaluating inputs parameters for further data processing and analysis. Additional processing features are accomplished in a second phase by ASIRA Tools which is Matlab code with GUI developed to extract further information from the dataset in automated way. The main functions of ASIRA Tools are: a) the analysis of temperature variations of each pixel of the IR frame in a given time interval, b) the removal of seasonal effects from temperature of every pixel in the IR frames by using an analytic approach (removal of sinusoidal long term seasonal component by using a polynomial fit Matlab function - LTFC_SCOREF), c) the export of data in different raster formats (i.e. Surfer grd). An interesting example of elaborations of the data produced by ASIRA Tools is the map of the temperature changing rate, which provide remarkable information about the potential migration of fumarole activity. The high efficiency of Matlab in processing matrix data from IR scenes and the flexibility of this code-developing tool proved to be very useful to produce applications to use in volcanic surveillance aimed to monitor the evolution of surface temperatures field in diffuse degassing volcanic areas.

Reducing the biases in simulated polar climate by incorporating realistic surface spectral emissivity into the global climate model

NASA Astrophysics Data System (ADS)

Huang, X.; Chen, X.; Flanner, M.; Yang, P.; Feldman, D.; Kuo, C.

2017-12-01

Surface longwave emissivity can be less than unity and vary significantly with frequency. The emissivities of water, ice, and bare land all exhibit different spectral dependence, for both the far-IR and mid-IR bands. However, most climate models still assume blackbody surface in the longwave (LW) radiation scheme of their atmospheric modules. This study incorporates realistic surface spectral emissivity into the RRTMG_LW, the LW radiation scheme in CAM, which is the atmospheric component of the NCAR Community Earth System Model (CESM) version 1.1.1. Then we evaluate its impact on simulated climatology, especially for the polar regions. By ensuring the consistency of the broadband longwave flux across different modules of the CESM, the TOA energy balance in the simulation can be attained without additional tuning of the model. While the impact on global mean surface temperature is small, the surface temperature differences in Polar Regions are statistically significant. The mean surface temperature in Arctic in the modified CESM is 1.5K warmer than that in the standard CESM, reducing the cold bias that the standard CESM has with respect to observations. Accordingly the sea ice fraction in the modified CESM simulation is less than that in the standard CESM simulation by as much as 0.1, which significantly reduces the positive biases in the simulated sea ice coverage by the CESM. The largest sea-ice coverage difference happens in August and September, when new sea ice starts to form. The similar changes can be seen for the simulated Antarctic surface climate as well. In a nutshell, incorporating realistic surface spectral emissivity helps improving the fidelity of simulated surface energy budget in the polar region, which leads to a better simulation of the surface temperature and sea ice coverage.

Infrared and Passive Microwave Radiometric Sea Surface Temperatures and Their Relationships to Atmospheric Forcing

NASA Technical Reports Server (NTRS)

Castro, Sandra L.

2004-01-01

The current generation of infrared (IR) and passive microwave (MW) satellite sensors provides highly complementary information for monitoring sea surface temperature (SST). On the one hand, infrared sensors provide high resolution and high accuracy but are obscured by clouds. Microwave sensors on the other hand, provide coverage through non-precipitating clouds but have coarser resolution and generally poorer accuracy. Assuming that the satellite SST measurements do not have spatially variable biases, they can be blended combining the merits of both SST products. These factors have motivated recent work in blending the MW and IR data in an attempt to produce high-accuracy SST products with improved coverage in regions with persistent clouds. The primary sources of retrieval uncertainty are, however, different for the two sensors. The main uncertainty in the MW retrievals lies in the effects of wind-induced surface roughness and foam on emissivity, whereas the IR retrievals are more sensitive to the atmospheric water vapor and aerosol content. Average nighttime differences between the products for the month periods of January 1999 and June 2000 are shown. These maps show complex spatial and temporal differences as indicated by the strong spatially coherent features in the product differences and the changes between seasons. Clearly such differences need to be understood and accounted for if the products are to be combined. The overall goals of this project are threefold: (1) To understand the sources of uncertainty in the IR and MW SST retrievals and to characterize the errors affecting the two types of retrieval as a fiction of atmospheric forcing; (2) To demonstrate how representative the temperature difference between the two satellite products is of Delta T; (3) To apply bias adjustments and to device a comprehensive treatment of the behavior of the temperature difference across the oceanic skin layer to determine the best method for blending thermal infrared and passive microwave measurements of SSTs.

Analysis of Abrasive Blasting of DOP-26 Iridium Alloy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ohriner, Evan Keith; Zhang, Wei; Ulrich, George B

2012-01-01

The effects of abrasive blasting on the surface geometry and microstructure of DOP-26 iridium alloy (Ir-0.3% W-0.006% Th 0.005% Al) have been investigated. Abrasive blasting has been used to control emissivity of components operating at elevated temperature. The effects of abrasive blasting conditions on surface morphology were investigated both experimentally and by numerical modeling. The simplified model, based on finite element analysis of a single angular particle impacting on Ir alloy disk, calculates the surface deformation and residual strain distribution. The experimental results and modeling results both indicate that the surface geometry is not sensitive to the abrasive blast processmore » conditions of nozzle pressure and standoff distance considered in this study. On the other hand, the modeling results suggest that the angularity of the abrasive particle has an important role in determining surface geometry, which in turn, affects the emissivity. Abrasive blasting causes localized surface strains and localized recrystallization, but it does not affect grain size following extended exposure at elevated temperature. The dependence of emissivity of the DOP-26 alloy on mean surface slope follows a similar trend to that reported for pure iridium.« less

Calibration and Evaluation of Ultrasound Thermography using Infrared Imaging

PubMed Central

Hsiao, Yi-Sing; Deng, Cheri X.

2015-01-01

Real-time monitoring of the spatiotemporal evolution of tissue temperature is important to ensure safe and effective treatment in thermal therapies including hyperthermia and thermal ablation. Ultrasound thermography has been proposed as a non-invasive technique for temperature measurement, and accurate calibration of the temperature-dependent ultrasound signal changes against temperature is required. Here we report a method that uses infrared (IR) thermography for calibration and validation of ultrasound thermography. Using phantoms and cardiac tissue specimens subjected to high-intensity focused ultrasound (HIFU) heating, we simultaneously acquired ultrasound and IR imaging data from the same surface plane of a sample. The commonly used echo time shift-based method was chosen to compute ultrasound thermometry. We first correlated the ultrasound echo time shifts with IR-measured temperatures for material-dependent calibration and found that the calibration coefficient was positive for fat-mimicking phantom (1.49 ± 0.27) but negative for tissue-mimicking phantom (− 0.59 ± 0.08) and cardiac tissue (− 0.69 ± 0.18 °C-mm/ns). We then obtained the estimation error of the ultrasound thermometry by comparing against the IR measured temperature and revealed that the error increased with decreased size of the heated region. Consistent with previous findings, the echo time shifts were no longer linearly dependent on temperature beyond 45 – 50 °C in cardiac tissues. Unlike previous studies where thermocouples or water-bath techniques were used to evaluate the performance of ultrasound thermography, our results show that high resolution IR thermography provides a useful tool that can be applied to evaluate and understand the limitations of ultrasound thermography methods. PMID:26547634

Optical metrology for testing an all-composite 2-meter diameter mirror

NASA Technical Reports Server (NTRS)

Catanzaro, B.; Thomas, James A.; Small, D.; Johnston, R.; Barber, D.; Connell, S.; Whitmore, S.; Cohen, E.

2001-01-01

The Herschel Space Observatory (formerly known as FIRST) consists of a 3.5 m space telescope designed for use in the long IR and sub-milimeter wavebands. To demonstrate the viability of a carbon fiber composite telescope for this application, Composite Optics Incorporated (COI) manufactured a fast (f/1), large (2 m), lightweight (10.1 kg/m squared) demonstration mirror. A key challenge in demonstrating the performance of this novel mirror was to characterize the surface accuracy at cryogenic (70 K) temperatures. A wide variety of optical metrology techniques were investigated and a brief survey of empirical test results and limitations of the various techniques will be presented in this paper. Two complementary infrared (IR)techniques operating at a wavelength of 10.6 microns were chosen for further development: (1) IR Twyman-Green Phase Shifting Interferometry (IR PSI) and (2) IR Shack-Hartmann (IR SH) Wavefront Sensing. Innovative design modifications made to an existing IR PSI to achieve high-resolution, scannable, infrared measurements of the composite mirror are described. The modified interferometer was capable of measuring surface gradients larger than 350 microradians. The design and results of measurements made with a custom-built IR SH Wavefrong Sensor operating at 10.6 microns are also presented. A compact experimental setup permitting simultaneous operation of both the IR PSI and IR SH tools is shown. The advantages and the limitations of the two key IR metrology tools are discussed.

Progress in Understanding the Pre-Earthquake Associated Events by Analyzing IR Satellite Data

NASA Technical Reports Server (NTRS)

Ouzounov, Dimitar; Taylor, Patrick; Bryant, Nevin

2004-01-01

We present latest result in understanding the potential relationship between tectonic stress, electro-chemical and thermodynamic processes in the Earths crust and atmosphere with an increase in IR flux as a potential signature of electromagnetic (EM) phenomena that are related to earthquake activity, either pre-, co- or post seismic. Thermal infra-red (TIR) surveys performed by the polar orbiting (NOAA/AVHRR MODIS) and geosynchronous weather satellites (GOES, METEOSAT) gave an indication of the appearance (from days to weeks before the event) of "anomalous" space-time TIR transients that are associated with the location (epicenter and local tectonic structures) and time of a number of major earthquakes with M>5 and focal depths less than 50km. We analyzed broad category of associated pre-earthquake events, which provided evidence for changes in surface temperature, surface latent heat flux, chlorophyll concentrations, soil moisture, brightness temperature, emissivity of surface, water vapour in the atmosphere prior to the earthquakes occurred in Algeria, India, Iran, Italy, Mexico and Japan. The cause of such anomalies has been mainly related to the change of near-surface thermal properties due to complex lithosphere-hydrosphere-atmospheric interactions. As final results we present examples from the most recent (2000-2004) worldwide strong earthquakes and the techniques used to capture the tracks of EM emission mid-IR anomalies and a methodology for practical future use of such phenomena in the early warning systems.

Attachment of 3-(Aminopropyl)triethoxysilane on silicon oxide surfaces: dependence on solution temperature.

PubMed

Pasternack, Robert M; Rivillon Amy, Sandrine; Chabal, Yves J

2008-11-18

Parameters important to the self-assembly of 3-(aminopropyl)triethoxysilane (APTES) on chemically grown silicon oxide (SiO 2) to form an aminopropyl silane (APS) film have been investigated using in situ infrared (IR) absorption spectroscopy. Preannealing to approximately 70 degrees C produces significant improvements in the quality of the film: the APS film is denser, and the Si-O-Si bonds between the molecules and the SiO 2 surface are more structured and ordered with only a limited number of remaining unreacted ethoxy groups. In contrast, post-annealing the functionalized SiO 2 samples after room temperature reaction with APTES (i.e., ex situ annealing) does not lead to any spectral change, suggesting that post-annealing has no strong effect on the horizontal polymerization as suggested earlier. Both IR and ellipsometry data show that the higher the solution temperature, the denser and thinner the APS layer is for a given immersion time. Finally, the APS layer obtained by preannealing the solution at 70 degrees C exhibits a better stability in deionized water than the APS layer prepared at room temperature.

Modeling the non-grey-body thermal emission from the full moon

NASA Technical Reports Server (NTRS)

Vogler, Karl J.; Johnson, Paul E.; Shorthill, Richard W.

1991-01-01

The present series of thermophysical computer models for solid-surfaced planetary bodies whose surface roughness is modeled as paraboloidal craters of specified depth/diameter ratio attempts to characterize the nongrey-body brightness temperature spectra of the moon and of the Galilean satellites. This modeling, in which nondiffuse radiation properties and surface roughness are included for rigorous analysis of scattered and reemitted radiation within a crater, explains to first order the behavior of both limb-scans and disk-integrated IR brightness temperature spectra for the full moon. Only negative surface relief can explain lunar thermal emissions' deviation from smooth Lambert-surface expectations.

Chemistry and Spectroscopy of Frozen Chloride Salts on Icy Bodies

NASA Astrophysics Data System (ADS)

Johnson, Paul; Thomas, Elena C.; Hodyss, Robert; Vu, Tuan; Choukroun, Mathieu

2016-10-01

Currently, our understanding of the chemical composition of Europa's surface is our best means of inferring constraints on the subsurface ocean composition and its subsequent habitability. The bulk of our knowledge of Europa surface chemistry can be traced to near infrared spectra recorded by the Near Infrared Mapping Spectrometer on the Galileo spacecraft. However, the usefulness of this and other remote sensing data is limited by the availability of spectral libraries of candidate materials under relevant conditions (temperature, thermal/radiation history, etc.). Chloride salts are expected to exist on the surface of Europa, and other icy bodies, based on geochemical predictions of the ocean composition. In order to help improve our understanding of Europa's surface composition, we have conducted a study of frozen chloride-salt brines prepared under simulated Europa surface conditions (vacuum, temperature, and UV irradiation) using both near IR and Raman spectroscopies. Specifically, Raman spectroscopy was used to determine the hydration states of various chloride salts as a function of temperature. Near IR spectroscopy of identically prepared samples was used to provide reference reflectance spectra of the identified hydrated salts. Our results indicate that at temperatures ranging from 80 K to 233 K, hydrohalite is formed from the freezing of NaCl brines, while the freezing of KCl solutions does not form KCl hydrates. In addition, the freezing of MgCl2 solutions forms a stable hexahydrate, and the freezing of CaCl2 solutions forms a hexahydrate, a tetrahydrate, and a dihydrate. Dehydration of the salts was observed as temperatures were increased, leading to a succession of hydration states in the case of CaCl2.

The hydroxyl species and acid sites on diatomite surface: a combined IR and Raman study

NASA Astrophysics Data System (ADS)

Yuan, P.; Wu, D. Q.; He, H. P.; Lin, Z. Y.

2004-04-01

Diffuse reflectance infrared Fourier transform spectroscopy (DRIFT), Raman spectroscopy of adsorbed pyridine molecules (Py-Raman) and in situ Py-IR have been used to investigate the hydroxyl species and acid sites on diatomite surfaces. The Lewis (L) and Brønsted (B) acid sites, and various hydroxyl species, including isolated hydroxyl groups, H-bonded hydroxyl groups and physically adsorbed water, are identified. The L acid sites in diatomite samples are resulted from the clay impurities, and the B acid sites are resulted from some moderate strength H-bonded hydroxyl groups. At room temperature, both of the isolated and H-bonded silanols associate with the physically adsorbed water by hydrogen bond. After calcination treatment, physically adsorbed water will be desorbed from the silanols, and the silanols will condense with the increase of temperature. Generally, the H-bonded silanols condense more easily than the isolated ones. The properties of surface hydroxyl species of diatomaceous silica are more similar to precipitated silica rather than fumed silica.

Radiative and convective properties of 316L Stainless Steel fabricated using the Laser Engineered Net Shaping process

NASA Astrophysics Data System (ADS)

Knopp, Jonathan

Temperature evolution of metallic materials during the additive manufacturing process has direct influence in determining the materials microstructure and resultant characteristics. Through the power of Infrared (IR) thermography it is now possible to monitor thermal trends in a build structure, giving the power to adjust building parameters in real time. The IR camera views radiation in the IR wavelengths and determines temperature of an object by the amount of radiation emitted from the object in those wavelengths. Determining the amount of radiation emitted from the material, known as a materials emissivity, can be difficult in that emissivity is affected by both temperature and surface finish. It has been shown that the use of a micro-blackbody cavity can be used as an accurate reference temperature when the sample is held at thermal equilibrium. A micro-blackbody cavity was created in a sample of 316L Stainless Steel after being fabricated during using the Laser Engineered Net Shaping (LENS) process. Holding the sample at thermal equilibrium and using the micro-blackbody cavity as a reference and thermocouple as a second reference emissivity values were able to be obtained. IR thermography was also used to observe the manufacturing of these samples. When observing the IR thermography, patterns in the thermal history of the build were shown to be present as well as distinct cooling rates of the material. This information can be used to find true temperatures of 316L Stainless Steel during the LENS process for better control of desired material properties as well as future work in determining complete energy balance.

DOE Award No. FG02-93ER14331 Final Technical Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bartynski, Robert

We have studyed new aspects of the relationships between nanoscale surface features and heterogeneous catalysis or electrocatalysis. We concentrate on atomically rough and morphologically unstable surfaces of catalytic metal single crystals (Re, Ru, Ir) that undergo nanoscale faceting when interacting with strongly adsorbed species (e.g. O, N, C) at elevated temperatures.

Quantitative Infrared Image Analysis Of Thermally-Thin Cellulose Surface Temperatures During Upstream and Downstream Microgravity Flame Spread from A Central Ignition Line

NASA Technical Reports Server (NTRS)

Olson, Sandra L.; Lee, J. R.; Fujita, O.; Kikuchi, M.; Kashiwagi, T.

2012-01-01

Surface view calibrated infrared images of ignition and flame spread over a thin cellulose fuel were obtained at 30 Hz during microgravity flame spread tests in the 10 second Japan Microgravity Center (JAMIC). The tests also used a color video of the surface view and color images of the edge view using 35 millimeter 1600 Kodak Ektapress film at 2 Hz. The cellulose fuel samples (50% long fibers from lumi pine and 50% short fibers from birch) were made with an area density of 60 grams per square meters. The samples were mounted in the center of a 12 centimeter wide by 16 centimeter tall flow duct that uses a downstream fan to draw the air through the flow duct. Samples were ignited after the experiment package was released using a straight hot wire across the center of the 7.5 centimeter wide by 14 centimeter long samples. One case, at 1 atmosphere 35%O2 in N2, at a forced flow of 10 centimeters per second, is presented here. In this case, as the test progresses, the single flame begins to separate into simultaneous upstream and downstream flames. Surface temperature profiles are evaluated as a function of time, and temperature gradients for upstream and downstream flame spread are measured. Flame spread rates from IR image data are compared to visible image spread rate data. IR blackbody temperatures are compared to surface thermocouple readings to evaluate the effective emissivity of the pyrolyzing surface. Preheat lengths are evaluated both upstream and downstream of the central ignition point. A surface energy balance estimates the net heat flux from the flame to the fuel surface along the length of the fuel.

Surface ablation of aluminum and silicon by ultrashort laser pulses of variable width

NASA Astrophysics Data System (ADS)

Zayarny, D. A.; Ionin, A. A.; Kudryashov, S. I.; Makarov, S. V.; Kuchmizhak, A. A.; Vitrik, O. B.; Kulchin, Yu. N.

2016-06-01

Single-shot thresholds of surface ablation of aluminum and silicon via spallative ablation by infrared (IR) and visible ultrashort laser pulses of variable width τlas (0.2-12 ps) have been measured by optical microscopy. For increasing laser pulse width τlas < 3 ps, a drastic (threefold) drop of the ablation threshold of aluminum has been observed for visible pulses compared to an almost negligible threshold variation for IR pulses. In contrast, the ablation threshold in silicon increases threefold with increasing τlas for IR pulses, while the corresponding thresholds for visible pulses remained almost constant. In aluminum, such a width-dependent decrease in ablation thresholds has been related to strongly diminished temperature gradients for pulse widths exceeding the characteristic electron-phonon thermalization time. In silicon, the observed increase in ablation thresholds has been ascribed to two-photon IR excitation, while in the visible range linear absorption of the material results in almost constant thresholds.

Cryogenic Laboratory Experiments into Radiation Effects on the Spectra of Non-Ice Materials relevant to Ocean Worlds

NASA Astrophysics Data System (ADS)

Cahill, K. R. S.; Hibbitts, C.; Wing, B. R.

2017-12-01

The airless satellites of Jupiter and Saturn are bombarded by high-energy particles from solar wind and their planetary magnetospheres. The particles range up to MeV energies and penetrate sufficiently far (microns) into the surface to cause damage that can affect their UV - IR spectral signatures. These particles physically and chemically alter the exposed surface by damaging crystallinity, sputtering non-refractory neutrals, depositing into the material, and inducing chemical reactions between existing and/or exogenous components. Previous studies of salts irradiated at room temperature ( 293 K) under high vacuum (1e-7 Torr) demonstrated the formation of radiation-induced color centers, or Farbe-centers, that are active at near UV, visible, and near IR wavelengths [1,2]. In this study, we investigated the effects of irradiation on these and other materials at temperatures relevant to the surfaces of the Galilean and Saturnian satellites. Experiments at the appropriate temperatures are important because the diffusion of the H-centers, which can interact with F-centers [3], are strongly temperature dependent and may be inhibited. This could affect the spectral signature of the irradiated materials. The experiments simulated the radiation environment using 40 keV electrons at 80 microamps under high vacuum at 100 K while characterizing the spectral changes (UV through mid-IR). Spectral measurements were obtained in the UV-Visible ( 130-570 nm) using a McPherson monochromater and photomultiplier detector, in the Visible-SWIR ( 340-2500 nm) using a SVC point spectrometer, and in the NIR-MIR ( 1500 to 8000 nm) using a Bruker Vertex 70 FTIR coupled to a liquid nitrogen cooled MCT detector. Spectra were collected while the sample was held under high vacuum at cryogenic temperatures both before, during, and after irradiation. Our results characterize the spectral signature of radiation-induced color centers that can form at the temperatures present at the surface of airless ocean worlds. We will show the spectral change induced by irradiation at cryogenic temperatures and compare these results to performed at room temperature. [1] Hibbitts et al. [2017], Icarus, submitted. [2] Hand and Carlson. [2015], GRL, 42, 3174-3178. [3] Soppe et al. [1994] J. Nuc. Mat., 217, 1-31.

Atmospheric Effects on Radio Frequency (RF) Wave Propagation in a Humid, Near-Surface Environment

DTIC Science & Technology

2010-03-01

additional IR temperature and Campbell water temperature probes, as well as a 3-D sonic anemometer, pyranometer , and LI-COR open path gas analyzer for...Zonen CNR-1 pyranometer . Lastly, the Campbell sonic anemometer (CSAT3) and LI- COR (CS7500) were extended 2.5 meters over the water from an

An energy balance climate model with cloud feedbacks

NASA Technical Reports Server (NTRS)

Roads, J. O.; Vallis, G. K.

1984-01-01

The present two-level global climate model, which is based on the atmosphere-surface energy balance, includes physically based parameterizations for the exchange of heat and moisture across latitude belts and between the surface and the atmosphere, precipitation and cloud formation, and solar and IR radiation. The model field predictions obtained encompass surface and atmospheric temperature, precipitation, relative humidity, and cloudiness. In the model integrations presented, it is noted that cloudiness is generally constant with changing temperature at low latitudes. High altitude cloudiness increases with temperature, although the cloud feedback effect on the radiation field remains small because of compensating effects on thermal and solar radiation. The net global feedback by the cloud field is negative, but small.

Infrared Study of CO2 Sorption over ?Molecular Basket? Sorbent Consisting of Polyethylenimine-Modified Mesoporous Molecular Sieve

DOE Office of Scientific and Technical Information (OSTI.GOV)

Overbury, Steven; Wang, Xiaoxing; Clark, Jason

2009-01-01

An infrared study has been conducted on CO{sub 2} sorption into nanoporous CO{sub 2} 'molecular basket' sorbents prepared by loading polyethylenimine (PEI) into mesoporous molecular sieve SBA-15. IR results from DRIFTS showed that a part of loaded PEI is anchored on the surface of SBA-15 through the interaction between amine groups and isolated surface silanol groups. Raising the temperature from 25 to 75 C increased the molecular flexibility of PEI loaded in the mesopore channels, which may partly contribute to the increase of CO{sub 2} sorption capacity at higher temperatures. CO{sub 2} sorption/desorption behavior studied by in situ transmission FTIRmore » showed that CO{sub 2} is sorbed on amine sites through the formation of alkylammonium carbamates and absorbed into the multiple layers of PEI located in mesopores of SBA-15. A new observation by in situ IR is that two broad IR bands emerged at 2450 and 2160 cm{sup -1} with CO{sub 2} flowing over PEI(50)/SBA-15, which could be attributed to chemically sorbed CO{sub 2} species on PEI molecules inside the mesopores of SBA-15. The intensities of these two bands also increased with increasing CO{sub 2} exposure time and with raising CO{sub 2} sorption temperature. By comparison of the CO{sub 2} sorption rate at 25 and 75 C in terms of differential IR intensities, it was found that CO{sub 2} sorption over molecular basket sorbent includes two rate regimes which suggest two distinct steps: rapid sorption on exposed outer surface layers of PEI (controlled by sorption affinity or thermodynamics) and the diffusion and sorption inside the bulk of multiple layers of PEI (controlled by diffusion). The sorption of CO{sub 2} is reversible at 75 C. Comparative IR examination of the CO{sub 2} sorption/desorption spectra on dry and prewetted PEI/SBA-15 sorbent revealed that presorbed water does not significantly affect the CO{sub 2}-amine interaction patterns.« less

Layered chalcogenide glass structures for IR lenses

NASA Astrophysics Data System (ADS)

Gibson, Daniel; Bayya, Shyam; Sanghera, Jas; Nguyen, Vinh; Scribner, Dean; Maksimovic, Velimir; Gill, John; Yi, Allen; Deegan, John; Unger, Blair

2014-07-01

A technique for fabricating novel infrared (IR) lenses can enable a reduction in the size and weight of IR imaging optics through the use of layered glass structures. These structures can range from having a few thick glass layers, mimicking cemented doublets and triplets, to having many thin glass layers approximating graded index (GRIN) lenses. The effectiveness of these structures relies on having materials with diversity in refractive index (large Δn) and dispersion and similar thermo-viscous behavior (common glass transition temperature, ΔTg = 10°C). A library of 13 chalcogenide glasses with broad IR transmission (NIR through LWIR bands) was developed to satisfy these criteria. The lens fabrication methodology, including glass design and synthesis, sheet fabrication, preform making, lens molding and surface finishing are presented.

Atomic and polyatomic molecules at metal surfaces studied by synchrotron far-IR RAIRS

NASA Astrophysics Data System (ADS)

Raval, Rasmita; Roberts, Adam J.; Williams, Jamie; Nunney, Timothy S.; Surman, Mark

1997-10-01

Far-IR Reflection Absorption Infrared Spectroscopy (RAIRS) has been used to probe submonolayers of adsorbates created under clean controlled conditions on small area single crystal surfaces, using the newly commissioned Daresbury 13.3 Far-IR synchrotron beamline. Adsorbed formate species on Cu(110) were studied as an example of an adsorbate for which a large structural data-base already exists in the literature from other surface science techniques. Our high resolution Far-IR data has allowed two distinct vCu-O vibrations to be monitored for 0.25 monolayer of formate adsorbed on Cu(110) at 300 K. We rule out a lower symmetry formate complex giving rise to these vibrations and, instead, attribute the two bands to at least two chemically distinct species at the surface, a possibility that has hitherto not been included in the analyses of this system using other techniques. In addition, we also report the first RAIRS spectrum of the vCu-O stretching vibration for adsorbed atomic O on the Cu(110) surface at 300 K. The dissociative adsorption of oxygen, at room temperature, on this surface is known to induce a massive reconstruction of the surface in which `added' rows of Cu-O-Cu strings form on the surface in the [001] direction to give rise to the (1 X 2) missing row structure. The vCu-O vibration frequency is found to be invariant as a function of coverage, suggesting that the chemical nature of the Cu-O-Cu entity remains essentially unaltered during the growth of the reconstructed phase.

Helicopter- and ship-based measurements of mesoscale ocean color and thermal features in the marginal ice zone

NASA Astrophysics Data System (ADS)

Tanis, Fred J.; Manley, Thomas O.; Mitchell, Brian G.

1990-09-01

Eddies along the Polar Front/Marginal Ice Zone (MIZ) in Fram Strait are thought to make important contributions to nutrient flux and stimulation of primary productivity. During the Coordinated Eastern Arctic Regional Experiment (CEAREX) helicopter-based measurements of upwelling radiance were made in four visible spectral bands and in the thermal IR across mesoscale features associated with the MIZ. These structures were mapped by flying a grid pattern over the ocean surface to define eddy boundaries. Subsequently, the area was also sampled vertically with CTD and spectral radiometer profilers. Data obtained from a single structure were integrated to construct a three dimensional picture of physical and optical properties. Volume modeling of temperature, salinity, and density fields obtained from CTD survey define the subsurface eddy structure and are in good agreement with infrared derived characteristics. Maximum temperature in the core was found to be four degrees higher than the surrounding water. Volume modeling further indicates that a subsurface layer of Arctic Intermediate Water is intrinsically associated with the surface expression of the eddy. The ratio of upwelling radiances, L(44l)/L(565), was found to be correlated to surface chlorophyll, particulate absorption coefficient, and in water determinations of L using the optical profiling system. The remote sensing reflectance ratio along with the IR sea surface temperature were found to be useful to detect the surface expression of the eddy and to indicate near surface biological and physical processes.

Laser Infrared Desorption Spectroscopy to Detect Complex Organic Molecules on Icy Planetary Surfaces

NASA Technical Reports Server (NTRS)

Sollit, Luke S.; Beegle, Luther W.

2008-01-01

Laser Desorption-Infrared Spectroscopy (LD-IR) uses an IR laser pulse to desorb surface materials while a spectrometer measures the emission spectrum of the desorbed materials (Figure 1). In this example, laser desorption operates by having the incident laser energy absorbed by near surface material (10 microns in depth). This desorption produces a plume that exists in an excited state at elevated temperatures. A natural analog for this phenomenon can be observed when comets approach the sun and become active and individual molecular emission spectra can be observed in the IR [1,2,3,4,5]. When this occurs in comets, the same species that initially emit radiation down to the ground state are free to absorb it, reducing the amount of detectable emission features. The nature of our technique results in absorption not occurring, because the laser pulse could easily be moved away form the initial desorption plume, and still have better spatial resolution then reflectance spectroscopy. In reflectance spectroscopy, trace components have a relatively weak signal when compared to the entire active nature of the surface. With LDIR, the emission spectrum is used to identify and analyze surface materials.

Improving HJ-1B IRS land surface temperature product using ASTER global emissivity database

NASA Astrophysics Data System (ADS)

Li, H.; Hu, T.; Meng, X.; Yongming, D.; Cao, B.; Liu, Q.

2015-12-01

Land surface temperature (LST) is a key parameter for hydrological, meteorological, climatological and environmental studies. Currently many operational LST products have been generated using European and American satellite data, i.e., the Advanced Very High Resolution Radiometer (AVHRR), Advanced Along-Track Scanning Radiometer (AATSR) and Moderate Resolution Imaging Spectroradiometer (MODIS). However, few LST product has been produced using Chinese satellite data. Thus, the objective of this study is to generate reliable LST product using Chinese HJ-1B satellite data. The HJ-1B satellite of China, were launched on September 6, 2008, which are used for disaster and environment monitoring. IRS (Infrared Scanner) is one of the key instruments onboard HJ-1B satellite, it can scan the earth every four days, has four spectral bands ranging from the near-infrared to thermal infrared bands (band 1 0.75 - 1.10μm, band 2 1.55-1.75μm, MIR band 3 3.50 - 3.90μm, band 4 10.5-12.5μm) with 720 km swath. It scans ±29° from nadir and the spatial resolution for band1-3 is 150m and 300m for band4. In this study, a single-channel parametric model (SC-PM) algorithm were used to produce 300m LST product from HJ-1B IRS data. The NCEP atmospheric profiles and a parametric model were used for atmospheric correction. In order to improve the accuracy of the land surface emissivity (LSE), the 1km ASTER Global Emissivity Database (GED) and self-developed 5-day 1km vegetation cover product were used for estimating the LSE based on the Vegetation Cover Method. Two years of HJ-1B IRS LST product in Heihe River basin (Gansu province, China) from June 2012 to June 2014 were generated. The LST products were evaluated against ground observations in an arid area of northwest China during the Heihe Watershed Allied Telemetry Experimental Research (HiWATER) experiment. Four barren surface sites and ten vegetated sites were chosen for the evaluation. The results show that the developed HJ-1B IRS LST products demonstrate a good accuracy, with an average bias of 0.11 K and an average root mean square error (RMSE) of 2.43 K for all the sites during daytime. In addition, the biases are within 1K for all the barren surface sites, this indicate that using ASTER GED can produce reliable LST products from HJ-1B IRS data, especially for the barren surfaces.

Local Effects of Ice Floes on Skin Sea Surface Temperature in the Marginal Ice Zone from UAVs

NASA Astrophysics Data System (ADS)

Zappa, C. J.; Brown, S.; Emery, W. J.; Adler, J.; Wick, G. A.; Steele, M.; Palo, S. E.; Walker, G.; Maslanik, J. A.

2013-12-01

Recent years have seen extreme changes in the Arctic. Particularly striking are changes within the Pacific sector of the Arctic Ocean, and especially in the seas north of the Alaskan coast. These areas have experienced record warming, reduced sea ice extent, and loss of ice in areas that had been ice-covered throughout human memory. Even the oldest and thickest ice types have failed to survive through the summer melt period in areas such as the Beaufort Sea and Canada Basin, and fundamental changes in ocean conditions such as earlier phytoplankton blooms may be underway. Marginal ice zones (MIZ), or areas where the "ice-albedo feedback" driven by solar warming is highest and ice melt is extensive, may provide insights into the extent of these changes. Airborne remote sensing, in particular InfraRed (IR), offers a unique opportunity to observe physical processes at sea-ice margins. It permits monitoring the ice extent and coverage, as well as the ice and ocean temperature variability. It can also be used for derivation of surface flow field allowing investigation of turbulence and mixing at the ice-ocean interface. Here, we present measurements of visible and IR imagery of melting ice floes in the marginal ice zone north of Oliktok Point AK in the Beaufort Sea made during the Marginal Ice Zone Ocean and Ice Observations and Processes EXperiment (MIZOPEX) in July-August 2013. The visible and IR imagery were taken from the unmanned airborne vehicle (UAV) ScanEagle. The visible imagery clearly defines the scale of the ice floes. The IR imagery show distinct cooling of the skin sea surface temperature (SST) as well as a intricate circulation and mixing pattern that depends on the surface current, wind speed, and near-surface vertical temperature/salinity structure. Individual ice floes develop turbulent wakes as they drift and cause transient mixing of an influx of colder surface (fresh) melt water. The upstream side of the ice floe shows the coldest skin SST, and downstream the skin SST is mixed within the turbulent wake over 10s of meters. We compare the structure of circulation and mixing of the influx of cold skin SST driven by surface currents and wind. In-situ temperature measurements provide the context for the vertical structure of the mixing and its impact on the skin SST. Furthermore, comparisons to satellite-derived sea surface temperature of the region are presented. The accuracy of satellite derived SST products and how well the observed skin SSTs represent ocean bulk temperatures in polar regions is not well understood, due in part to lack of observations. Estimated error in the polar seas is relatively high at up to 0.4 deg. C compared to less than 0.2 deg. C for other areas. The goal of these and future analyses of the MIZOPEX data set is to elucidate a basic question that is significant for the entire Earth system. Have these regions passed a tipping point, such that they are now essentially acting as sub-Arctic seas where ice disappears in summer, or instead whether the changes are transient, with the potential for the ice pack to recover?

Nonlocal Coulomb correlations in pure and electron-doped Sr2IrO4 : Spectral functions, Fermi surface, and pseudo-gap-like spectral weight distributions from oriented cluster dynamical mean-field theory

NASA Astrophysics Data System (ADS)

Martins, Cyril; Lenz, Benjamin; Perfetti, Luca; Brouet, Veronique; Bertran, François; Biermann, Silke

2018-03-01

We address the role of nonlocal Coulomb correlations and short-range magnetic fluctuations in the high-temperature phase of Sr2IrO4 within state-of-the-art spectroscopic and first-principles theoretical methods. Introducing an "oriented-cluster dynamical mean-field scheme", we compute momentum-resolved spectral functions, which we find to be in excellent agreement with angle-resolved photoemission spectra. We show that while short-range antiferromagnetic fluctuations are crucial to accounting for the electronic properties of Sr2IrO4 even in the high-temperature paramagnetic phase, long-range magnetic order is not a necessary ingredient of the insulating state. Upon doping, an exotic metallic state is generated, exhibiting cuprate-like pseudo-gap spectral properties, for which we propose a surprisingly simple theoretical mechanism.

IR-thermography for Quality Prediction in Selective Laser Deburring

NASA Astrophysics Data System (ADS)

Möller, Mauritz; Conrad, Christian; Haimerl, Walter; Emmelmann, Claus

Selective Laser Deburring (SLD) is an innovative edge-refinement process being developed at the Laser Zentrum Nord (LZN) in Hamburg. It offers a wear-free processing of defined radii and bevels at the edges as well as the possibility to deburr several materials with the same laser source. Sheet metal parts of various applications need to be post-processed to remove sharp edges and burrs remaining from the initial production process. Thus, SLD will provide an extended degree of automation for the next generation of manufacturing facilities. This paper investigates the dependence between the deburring result and the temperature field in- and post-process. In order to achieve this, the surface temperature near to the deburred edge is monitored with IR-thermography. Different strategies are discussed for the approach using the IR-information as a quality assurance. Additional experiments are performed to rate the accuracy of the quality prediction method in different deburring applications.

Infrared study of CO{sub 2} sorption over 'molecular basket' sorbent consisting of polyethylenimine-modified mesoporous molecular sieve

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, X.X.; Schwartz, V.; Clark, J.C.

2009-04-15

An infrared study has been conducted on CO{sub 2} sorption into nanoporous CO{sub 2} 'molecular basket' sorbents prepared by loading polyethylenimine (PEI) into mesoporous molecular sieve SBA-15. IR results from DRIFTS showed that a part of loaded PEI is anchored on the surface of SBA-15 through the interaction between amine groups and isolated surface silanol groups. Raising the temperature from 25 to 75{sup o}C increased the molecular flexibility of PEI loaded in the mesopore channels, which may partly contribute to the increase of CO{sub 2} sorption capacity at higher temperatures. CO{sub 2} sorption/desorption behavior studied by in situ transmission FTIRmore » showed that CO{sub 2} is sorbed on amine sites through the formation of alkylammonium carbamates and absorbed into the multiple layers of PEI located in mesopores of SBA-15. A new observation by in situ IR is that two broad IR bands emerged at 2450 and 2160 cm{sup -1} with CO{sub 2} flowing over PEI(50)/SBA-15, which could be attributed to chemically sorbed CO{sub 2} species on PEI molecules inside the mesopores of SBA-15. The intensities of these two bands also increased with increasing CO{sub 2} exposure time and with raising CO{sub 2} sorption temperature. By comparison of the CO{sub 2} sorption rate at 25 and 75{sup o}C in terms of differential IR intensities, it was found that CO{sub 2} sorption over molecular basket sorbent includes two rate regimes which suggest two distinct steps: rapid sorption on exposed outer surface layers of PEI (controlled by sorption affinity or thermodynamics) and the diffusion and sorption inside the bulk of multiple layers of PEI (controlled by diffusion). The sorption of CO{sub 2} is reversible at 75{sup o}C.« less

Cavitation induced Becquerel effect.

PubMed

Prevenslik, T V

2003-06-01

The observation of an electrical current upon the ultraviolet (UV) illumination of one of a pair of identical electrodes in liquid water, called the Becquerel effect, was made over 150 years ago. More recently, an electrical current was found if the water surrounding one electrode was made to cavitate by focused acoustic radiation, the phenomenon called the cavitation induced Becquerel effect. Since cavitation is known to produce UV light, the electrode may simply absorb the UV light and produce the current by the photo-emission theory of photoelectrochemistry. But the current was found to be semi-logarithmic with the standard electrode potential which is characteristic of the oxidation of the electrode surface in the photo-decomposition theory, and not the photo-emission theory. High bubble collapse temperatures may oxidize the electrode, but this is unlikely because melting was not observed on the electrode surfaces. At ambient temperature, oxidation may proceed by chemical reaction provided a source of vacuum ultraviolet (VUV) radiation is available to produce the excited OH* states of water to react with the electrode. The source of VUV radiation is shown to be the spontaneous emission of coherent infrared (IR) radiation from water molecules in particles that form in bubbles because of surface tension, the spontaneous IR emission induced by cavity quantum electrodynamics. The excited OH* states are produced as the IR radiation accumulates to VUV levels in the bubble wall molecules.

Noncontact detection of dry eye using a custom designed infrared thermal image system

NASA Astrophysics Data System (ADS)

Su, Tai Yuan; Hwa, Chen Kerh; Liu, Po Hsuan; Wu, Ming Hong; Chang, David O.; Su, Po Fang; Chang, Shu Wen; Chiang, Huihua Kenny

2011-04-01

Dry eye syndrome is a common irritating eye disease. Current clinical diagnostic methods are invasive and uncomfortable for patients. This study developed a custom designed noncontact infrared (IR) thermal image system to measure the spatial and temporal variation of the ocular surface temperature over a 6-second eye-open period. This research defined two parameters: the temperature difference value and the compactness value to represent the temperature change and the irregularity of the temperature distribution on the tear film. Using these two parameters, this study achieved discrimination results for the dry eye and the normal eye groups; the sensitivity is 0.84, the specificity is 0.83, and the receiver operating characteristic area is 0.87. The results suggest that the custom designed IR thermal image system may be used as an effective tool for noncontact detection of dry eye.

Note: thermal imaging enhancement algorithm for gas turbine aerothermal characterization.

PubMed

Beer, S K; Lawson, S A

2013-08-01

An algorithm was developed to convert radiation intensity images acquired using a black and white CCD camera to thermal images without requiring knowledge of incident background radiation. This unique infrared (IR) thermography method was developed to determine aerothermal characteristics of advanced cooling concepts for gas turbine cooling application. Compared to IR imaging systems traditionally used for gas turbine temperature monitoring, the system developed for the current study is relatively inexpensive and does not require calibration with surface mounted thermocouples.

Infrared Thermometers

ERIC Educational Resources Information Center

Schaefers, John

2006-01-01

An infrared (IR) thermometer lab offers the opportunity to give science students a chance to measure surface temperatures, utilizing off-the-shelf technology. Potential areas of study include astronomy (exoplanets), electromagnetic spectrum, chemistry, evaporation rates, anatomy, crystal formation, and water or liquids. This article presents one…

Solid Layer Thermal-conductivity Measurement Techniques

DTIC Science & Technology

1994-03-01

deposited on the sample, and the absorption of laser radiation. Temperature-measurement tools include thermocouples, infrared (IR) pyrometers , and...A, Nishimura H, and Sawada T (1990), Laser-Induc~d Surface Acoustic Waves and Photothc:rmal Surfitce Gratings Generated by Crossing Two Pulsed

Surface Emissivity Retrieved with Satellite Ultraspectral IR Measurements for Monitoring Global Change

NASA Technical Reports Server (NTRS)

Zhou, Daniel K.; Larar, Allen M.; Liu, Xu; Smith, William L.; Schluessel, Peter

2009-01-01

Surface and atmospheric thermodynamic parameters retrieved with advanced ultraspectral remote sensors aboard Earth observing satellites are critical to general atmospheric and Earth science research, climate monitoring, and weather prediction. Ultraspectral resolution infrared radiance obtained from nadir observations provide atmospheric, surface, and cloud information. Presented here is the global surface IR emissivity retrieved from Infrared Atmospheric Sounding Interferometer (IASI) measurements under "clear-sky" conditions. Fast radiative transfer models, applied to the cloud-free (or clouded) atmosphere, are used for atmospheric profile and surface parameter (or cloud parameter) retrieval. The inversion scheme, dealing with cloudy as well as cloud-free radiances observed with ultraspectral infrared sounders, has been developed to simultaneously retrieve atmospheric thermodynamic and surface (or cloud microphysical) parameters. Rapidly produced surface emissivity is initially evaluated through quality control checks on the retrievals of other impacted atmospheric and surface parameters. Surface emissivity and surface skin temperature from the current and future operational satellites can and will reveal critical information on the Earth s ecosystem and land surface type properties, which can be utilized as part of long-term monitoring for the Earth s environment and global climate change.

Holocene glacier and climate variations in Vestfirðir, Iceland, from the modeling of Drangajökull ice cap

NASA Astrophysics Data System (ADS)

Anderson, Leif S.; Flowers, Gwenn E.; Jarosch, Alexander H.; Aðalgeirsdóttir, Guðfinna Th; Geirsdóttir, Áslaug; Miller, Gifford H.; Harning, David J.; Thorsteinsson, Thorsteinn; Magnússon, Eyjólfur; Pálsson, Finnur

2018-06-01

Drangajökull is a maritime ice cap located in northwest (Vestfirðir) Iceland. Drangajökull's evolution is therefore closely linked to atmospheric and ocean variability. In order to better constrain the Holocene climate and glacier history of Vestfirðir we model the past evolution of Drangajökull ice cap. Simulations from 10 ka to present are forced by general circulation model output, ice-core-based temperature reconstructions, and sea-surface temperature reconstructions. Based on these 10-thousand year simulations, Drangajökull did not persist through the Holocene. We estimate that air temperatures were 2.5-3.0 °C higher during the Holocene Thermal Maximum than the local 1960-1990 average. Simulations support Drangajökull's late Holocene inception between 2 and 1 ka, though intermittent ice likely occupied cirques as early as 2.6 ka. Drangajökull is primarily a Little Ice Age ice cap: it expanded between 1300 and 1750 CE, with the most rapid growth occurring between 1600 and 1750 CE. The maximum Holocene extent of Drangajökull occurred between 1700 and 1925 CE, despite the lowest late Holocene temperatures, occurring between 1650 and 1720 CE. Between 1700 and 1925 CE temperatures were likely 0.6-0.8 °C lower than the 1950-2015 reference temperature. The modern equilibrium line altitude (ELA) is bracketed by topographic thresholds: a 1 °C temperature increase from the modern ELA would eliminate the ice cap's accumulation area, while a reduction of 0.5 °C would lead to the rapid expansion of the ice cap across Vestfirðir. The proximity of Drangajökull to topographic thresholds may explain its late inception and rapid expansion during the Little Ice Age.

An infrared based sensor system for the detection of ethylene for the discrimination of fruit ripening

NASA Astrophysics Data System (ADS)

Kathirvelan, J.; Vijayaraghavan, R.

2017-09-01

We report the fabrication and testing of a prototype ethylene sensing device for use in fruit ripening applications. A sensor based on infrared (IR) thermal emission was developed and used to detect the ethylene level released during the fruit ripening process. An IR thermal source tuned to the 10.6 μm wavelength was linked to a high-sensitivity silicon temperature detector. When introduced into the wave path between the IR source and temperature detector, ethylene absorbs the 10.6 μm IR waves and decreases the surface temperature of the detector. The output is then converted to an electrical signal (in mV), which gives a direct measurement of the ethylene level. Using this sensor, ethylene concentration measured from a fruit sample continuously decreased from 59 to 5 ppm during the natural ripening process. The sensor exhibited a sensitivity of 3.3 ± 0.2% (change in detector output (mV)/ppm × 100) and could measure concentrations as low as 5 ppm with rise and recovery times of 1 and 3 s, respectively. The system demonstrated good reproducibility. Devices employing this sensor system may be used for fruit ripening applications on site and in the field and for screening artificially ripened fruits, therefore contributing to ensure food safety.

Development of Surface Eroding Thermocouples in DIII-D

NASA Astrophysics Data System (ADS)

Ren, Jun; Donovan, David; Watkins, Jon; Wang, Huiqian; Rudakov, Dmitry; Murphy, Christopher; Unterberg, Ezekial; Thomas, Dan; Boivin, Rejean

2017-10-01

The Surface Eroding Thermocouple (SETC) is a specialized diagnostic for characterizing the surface temperature evolution with a high temporal resolution ( 1ms) which is especially useful in areas unobservable by line-of-sight diagnostics (e.g. IR cameras). Recently, SETCs were tested in DiMES and successfully acquired temperature signals during strike point sweeps on the lower divertor shelf. We observed that the SETCs have a sub-10 ms time response and is sufficient to resolve ELM heat pulses. Preliminary analysis shows heat fluxes measured by SETCs and IR camera agree within 20%. Comparison of SETCs, calorimeters and Langmuir probe also show good agreement. We plan to implement an array of SETCs embedded in the tiles forming the new DIII-D small angle slot (SAS) divertor. Strategies to improve the SNR of these SETCs through testing in DiMES before the final installation will be discussed. This work was supported by the US Department of Energy under DE-SC0016318 (UTK), DE-AC05-00OR22725 (ORNL), DE-FG02-07ER54917 (UCSD), DE-FC02-04ER54698 (GA), DE-AC04-94AL85000 (SNL).

Survival of Pochonia chlamydosporia on the soil surface after different exposure intervals at ambient conditions.

PubMed

Fernandes, Rafael Henrique; Lopes, Everaldo Antônio; Borges, Darlan Ferreira; Bontempo, Amanda Ferreira; Zanuncio, José Cola; Serrão, José Eduardo

Exposure of the nematophagous fungus Pochonia chlamydosporia to solar radiation and elevated temperatures before being incorporated into the soil can reduce its survival and efficiency as biocontrol agent. A field experiment was carried out to assess the effect of the exposure period on the viability of P. chlamydosporia applied on the soil surface. A commercial bionematicide based on P. chlamydosporia was sprayed on soil, and soil samples were collected before and at 0, 30, 60, 90, 120, and 150min after fungal application. Relative humidity (RH), the irradiance (IR), air temperature (AT), and soil temperature (ST) were recorded. The number of P. chlamydosporia colony forming units (CFUs) was evaluated after 20 days of incubation. P. chlamydosporia survival decreased over the time of exposure on the soil surface. Overall, the number of CFUs decreased by more than 90% at 150min after application. Exposure to RH ≥61%, ST and AT between 25-35°C and 19-29°C, and IR between 1172 and 2126μmol of photons m -2 s -1 induced a negative exponential effect on the survival of the fungus over the time. Exposure to climatic conditions on the soil surface reduces P. chlamydosporia viability. Copyright © 2017 Asociación Española de Micología. Publicado por Elsevier España, S.L.U. All rights reserved.

Camouflage in thermal IR: spectral design

NASA Astrophysics Data System (ADS)

Pohl, Anna; Fagerström, Jan; Kariis, Hans; Lindell, Roland; Hallberg, Tomas; Högström, Herman

2016-10-01

In this work a spectral designed coating from SPECTROGON is evaluated. Spectral design in this case means that the coating has a reflectivity equal to one at 3-5 and 8-12 microns were sensors operate and a much lower reflectivity in the other wave length regions. Three boxes are evaluated: one metallic, one black-body and one with a spectral designed surface, all with a 15 W radiator inside the box. It is shown that the box with the spectral designed surface can combine the two good characteristics of the other boxes: low signature from the metallic box and reasonable inside temperature from the black-body box. The measurements were verified with calculations using RadThermIR.

Surface-induced brightness temperature variations and their effects on detecting thin cirrus clouds using IR emission channels in the 8-12 microns region

NASA Technical Reports Server (NTRS)

Gao, Bo-Cai; Wiscombe, W. J.

1994-01-01

A method for detecting cirrus clouds in terms of brightness temperature differences between narrowbands at 8, 11, and 12 microns has been proposed by Ackerman et al. In this method, the variation of emissivity with wavelength for different surface targets was not taken into consideration. Based on state-of-the-art laboratory measurements of reflectance spectra of terrestrial materials by Salisbury and D'Aria, it is found that the brightness temperature differences between the 8- and 11-microns bands for soils, rocks, and minerals, and dry vegetation can vary between approximately -8 and +8 K due solely to surface emissivity variations. The large brightness temperature differences are sufficient to cause false detection of cirrus clouds from remote sensing data acquired over certain surface targets using the 8-11-12-microns method directly. It is suggested that the 8-11-12-microns method should be improved to include the surface emissivity effects. In addition, it is recommended that in the future the variation of surface emissivity with wavelength should be taken into account in algorithms for retrieving surface temperatures and low-level atmospheric temperature and water vapor profiles.

Atmospheric effects on the remote determination of thermal inertia on Mars

NASA Technical Reports Server (NTRS)

Haberle, Robert M.; Jakosky, Bruce M.

1991-01-01

Measurements of the IR brightness temperature at the Martian surface at many different times of day are presently compared with temperatures predicted by thermal models which allow sunlight to reach the surface unattenuated, in order to determine the thermal inertia of the uppermost 1-10 cm of the Martian surface. The consequences of the assumptions made are assessed in view of results from a different thermal model which invokes radiation-transfer through a dusty CO2 atmosphere, as well as sensible heat-exchange with the surface. Smaller thermal inertias imply smaller particle sizes; the results obtained suggest that low thermal-inertia regions consist of 5-micron, rather than 50-micron, particle sizes.

Wavelet and Fractal Analysis of Remotely Sensed Surface Temperature with Applications to Estimation of Surface Sensible Heat Flux Density

NASA Technical Reports Server (NTRS)

Schieldge, John

2000-01-01

Wavelet and fractal analyses have been used successfully to analyze one-dimensional data sets such as time series of financial, physical, and biological parameters. These techniques have been applied to two-dimensional problems in some instances, including the analysis of remote sensing imagery. In this respect, these techniques have not been widely used by the remote sensing community, and their overall capabilities as analytical tools for use on satellite and aircraft data sets is not well known. Wavelet and fractal analyses have the potential to provide fresh insight into the characterization of surface properties such as temperature and emissivity distributions, and surface processes such as the heat and water vapor exchange between the surface and the lower atmosphere. In particular, the variation of sensible heat flux density as a function of the change In scale of surface properties Is difficult to estimate, but - in general - wavelets and fractals have proved useful in determining the way a parameter varies with changes in scale. We present the results of a limited study on the relationship between spatial variations in surface temperature distribution and sensible heat flux distribution as determined by separate wavelet and fractal analyses. We analyzed aircraft imagery obtained in the thermal infrared (IR) bands from the multispectral TIMS and hyperspectral MASTER airborne sensors. The thermal IR data allows us to estimate the surface kinetic temperature distribution for a number of sites in the Midwestern and Southwestern United States (viz., San Pedro River Basin, Arizona; El Reno, Oklahoma; Jornada, New Mexico). The ground spatial resolution of the aircraft data varied from 5 to 15 meters. All sites were instrumented with meteorological and hydrological equipment including surface layer flux measuring stations such as Bowen Ratio systems and sonic anemometers. The ground and aircraft data sets provided the inputs for the wavelet and fractal analyses, and the validation of the results.

Observations of ebb flows on tidal flats: Evidence of dewatering?

NASA Astrophysics Data System (ADS)

Rinehimer, J. P.; Thomson, J. M.; Chickadel, C.

2010-12-01

Incised channels are a common morphological feature of tidal flats. When the flats are inundated, flows are generally forced by the tidally varying sea surface height. During low tide, however, these channels continue to drain throughout flat exposure even without an upstream source of water. While the role of porewater is generally overlooked due to the low permeability of marine muds, it remains the only potential source of flows through the channels during low tide. In situ and remotely sensed observations (Figure 1) at an incised channel on a tidal flat in Willapa Bay from Spring 2010 indicate that dewatering of the flats may be driving these low tide flows. High resolution Aquadopp ADCP velocity profiles are combined with observations from tower-based infrared (IR) video to produce a complete time series of surface velocity measurements throughout low tide. The IR video observations provide a measurement of surface currents even when the channel depth is below the blanking distance of the ADCP (10 cm). As the depth within the channel drops from 50 cm to 10 cm surface velocities increase from 10 cm/s to 60 cm/s even as the tide level drops below the channel flanks and the flats are dry. As the drainage continues, the temperature of the flow rises throughout low tide, mirroring temperatures within the sediment bed on the tidal flat. Drainage salinity falls despite the lack of any freshwater input to the flat indicating that less saline porewater may be the source. The likely source of the drainage water is from the channel flanks where time-lapse video shows slumping and compaction of channel sediments. Velocity profiles, in situ temperatures, and IR observations also are consistent with the presence of fluid muds and a hyperpycnal, density driven outflow at the channel mouth highlighting a possible pathway for sediment delivery from the flats to the main distributary channels of the bay. Figure 1: Time series of tidal flat channel velocities and temperatures. Top: (soild) Water depth within the channel and (dashed) tidal flat elevation. Center: Channel surface velocities as measured by an (black) ADCP and (red) a Fourier technique using infrared video. Bottom: Temperatures of (blue) near bed water downstream of the incised channel, (black) channel outflow, and (red) tidal flat sediment at 10 cm depth within the bed.

Experimental study on infrared radiation temperature field of concrete under uniaxial compression

NASA Astrophysics Data System (ADS)

Lou, Quan; He, Xueqiu

2018-05-01

Infrared thermography, as a nondestructive, non-contact and real-time monitoring method, has great significance in assessing the stability of concrete structure and monitoring its failure. It is necessary to conduct in depth study on the mechanism and application of infrared radiation (IR) of concrete failure under loading. In this paper, the concrete specimens with size of 100 × 100 × 100 mm were adopted to carry out the uniaxial compressions for the IR tests. The distribution of IR temperatures (IRTs), surface topography of IRT field and the reconstructed IR images were studied. The results show that the IRT distribution follows the Gaussian distribution, and the R2 of Gaussian fitting changes along with the loading time. The abnormities of R2 and AE counts display the opposite variation trends. The surface topography of IRT field is similar to the hyperbolic paraboloid, which is related to the stress distribution in the sample. The R2 of hyperbolic paraboloid fitting presents an upward trend prior to the fracture which enables to change the IRT field significantly. This R2 has a sharp drop in response to this large destruction. The normalization images of IRT field, including the row and column normalization images, were proposed as auxiliary means to analyze the IRT field. The row and column normalization images respectively show the transverse and longitudinal distribution of the IRT field, and they have clear responses to the destruction occurring on the sample surface. In this paper, the new methods and quantitative index were proposed for the analysis of IRT field, which have some theoretical and instructive significance for the analysis of the characteristics of IRT field, as well as the monitoring of instability and failure for concrete structure.

Optimizing long-range order, band gap, and group velocities for graphene on close-packed metal surfaces.

PubMed

Natterer, F D; Rusponi, S; Papagno, M; Carbone, C; Brune, H

2012-08-08

We compare different growth methods with the aim of optimizing the long-range order of a graphene layer grown on Ru(0001). Combining chemical vapor deposition with carbon loading and segregation of the surface layer leads to autocorrelation lengths of 240 Å. We present several routes to band gap and charge carrier mobility engineering for the example of graphene on Ir(111). Ir cluster superlattices self-assembled onto the graphene moiré pattern produce a strong renormalization of the electron group velocity close to the Dirac point, leading to highly anisotropic Dirac cones and the enlargement of the gap from 140 to 340 meV. This gap can further be enhanced to 740 meV by Na co-adsorption onto the Ir cluster superlattice at room temperature. This value is close to that of Ge, and the high group velocity of the charge carriers is fully preserved. We also present data for Na adsorbed without the Ir clusters. In both cases we find that the Na is on top of the graphene layer.

Some observations on the greenhouse effect at the Earth's surface.

PubMed

Akitt, J W

2018-01-05

It is shown that the greenhouse gases carbon dioxide and water vapour reflect back to the surface, all IR radiation originating at the surface within their respective spectral bands. This reflection occurs in a very thin layer at the surface, not much over 12cm in thickness. Heat is lost from the surface by heat exchange with the atmosphere and by loss of radiation. About 52% of radiation leaves the surface in two principal window regions but this is not enough to account for the earth's equilibrium temperature. This window radiation seems to disappear quite quickly and is replaced by black body radiation. It is this which eventually contributes to the earth's radiation balance, and has to originate approximately between 40 and 50km altitude where the temperature is about correct, near 255K. Doubling the CO 2 concentration increases the surface temperature by about 0.9°C and this need not have any influence higher up in the atmosphere. The surface temperature seems indeed to have no direct influence on the earth's external radiation balance. Copyright © 2017 Elsevier B.V. All rights reserved.

Some observations on the greenhouse effect at the Earth's surface

NASA Astrophysics Data System (ADS)

Akitt, J. W.

2018-01-01

It is shown that the greenhouse gases carbon dioxide and water vapour reflect back to the surface, all IR radiation originating at the surface within their respective spectral bands. This reflection occurs in a very thin layer at the surface, not much over 12 cm in thickness. Heat is lost from the surface by heat exchange with the atmosphere and by loss of radiation. About 52% of radiation leaves the surface in two principal window regions but this is not enough to account for the earth's equilibrium temperature. This window radiation seems to disappear quite quickly and is replaced by black body radiation. It is this which eventually contributes to the earth's radiation balance, and has to originate approximately between 40 and 50 km altitude where the temperature is about correct, near 255 K. Doubling the CO2 concentration increases the surface temperature by about 0.9 °C and this need not have any influence higher up in the atmosphere. The surface temperature seems indeed to have no direct influence on the earth's external radiation balance.

Rapid and quantitative detection of the microbial spoilage of meat by fourier transform infrared spectroscopy and machine learning.

PubMed

Ellis, David I; Broadhurst, David; Kell, Douglas B; Rowland, Jem J; Goodacre, Royston

2002-06-01

Fourier transform infrared (FT-IR) spectroscopy is a rapid, noninvasive technique with considerable potential for application in the food and related industries. We show here that this technique can be used directly on the surface of food to produce biochemically interpretable "fingerprints." Spoilage in meat is the result of decomposition and the formation of metabolites caused by the growth and enzymatic activity of microorganisms. FT-IR was exploited to measure biochemical changes within the meat substrate, enhancing and accelerating the detection of microbial spoilage. Chicken breasts were purchased from a national retailer, comminuted for 10 s, and left to spoil at room temperature for 24 h. Every hour, FT-IR measurements were taken directly from the meat surface using attenuated total reflectance, and the total viable counts were obtained by classical plating methods. Quantitative interpretation of FT-IR spectra was possible using partial least-squares regression and allowed accurate estimates of bacterial loads to be calculated directly from the meat surface in 60 s. Genetic programming was used to derive rules showing that at levels of 10(7) bacteria.g(-1) the main biochemical indicator of spoilage was the onset of proteolysis. Thus, using FT-IR we were able to acquire a metabolic snapshot and quantify, noninvasively, the microbial loads of food samples accurately and rapidly in 60 s, directly from the sample surface. We believe this approach will aid in the Hazard Analysis Critical Control Point process for the assessment of the microbiological safety of food at the production, processing, manufacturing, packaging, and storage levels.

Heat Capacity Mapping Mission (HCMM): Interpretation of imagery over Canada

NASA Technical Reports Server (NTRS)

Cihlar, J. (Principal Investigator); Dixon, R. G.

1981-01-01

Visual analysis of HCMM images acquired over two sites in Canada and supporting aircraft and ground data obtained at a smaller subsite in Alberta show that nightime surface temperature distribution is primarily related to the near-surface air temperature; the effects of topography, wind, and land cover were low or indirect through air temperature. Surface cover and large altitudinal differences were important parameters influencing daytime apparent temperature values. A quantitative analysis of the relationship between the antecedent precipitation index and the satellite thermal IR measurements did not yield statistically significant correlation coefficients, but the correlations had a definite temporal trend which could be related to the increasing uniformity of vegetation cover. The large pixel size (resulting in a mixture of cover types and soil/canopy temperatures measured by the satellite) and high cloud cover frequency found in images covering both Canadian sites and northern U.S. were considered the main deficiencies of the thermal satellite data.

Complex permittivity measurements during high temperature recycling of space shuttle antenna window and dielectric heat shield materials

NASA Technical Reports Server (NTRS)

Bassett, H. L.; Bomar, S. H., Jr.

1973-01-01

The research performed and the data obtained on candidate space shuttle antenna window and heat shield materials are presented. The measurement technique employs a free-space focused beam microwave bridge for obtaining RF transmission data, and a device which rotates a sample holder which is heated on one side by natural gas-air flames. The surface temperature of each sample is monitored by IR pyrometry; embedded and rear surface thermocouples are also used in obtaining temperature data. The surface of the sample undergoing test is subjected to approximately the same temperature/time profile that occurs at a proposed antenna position on the space shuttle as it re-enters. The samples are cycled through ten of these temperature profiles to determine the recycling effects. Very little change was noted in the materials due to the recycling.

Satellite IR thermal measurements prior to the September 2004 earthquakes in central California

NASA Astrophysics Data System (ADS)

Ouzounov, D.; Logan, T.; Braynt, N.; Taylor, P.

2004-12-01

We present and discuss observed variations in thermal transients and radiation fields prior to the earthquakes of September 18 near Bodie (M5.5) and September 28, 2004 near Parkfield(M6.0) in California. Previous analysis of earthquake events have indicated the presence of a thermal anomaly, where temperatures increased or did not return to its usual nighttime value. The procedures used in our work is to analyze weather satellite data taken at night and to record the general condition where the ground cools after sunset. Two days before the Bodie earthquake lower temperature radiation was observed by the NOAA/AVHRR satellite. This occurred when the entire region was relatively cloud-free. IR land surface nighttime temperature from the MODIS instrument rose to +4 degrees C in a 100 km radius around the Bodie epicenter. The thermal transient field recorded by MODIS in the vicinity of Parkfield, also with a cloud free environment,was around +1degree C and it is significantly smaller than the thermal anomaly around the Bodie epicenter. Ground surface temperature near the Parkfield epicenter, however, for that period showed a steady increase 4 days prior to the earthquake and a significant drop of the night before the quake. Geosynchronous weather satellite thermal IR measurements taken every half hour from sunset to dawn, were also recorded for 10 days prior to the Parkfield event and 5 days after as well as the day of the quake. To establish a baseline we also obtained GOES data for the same Julian days for the three years prior to the Parkfield earthquake. These September 2004 IR data sets were then used to systematically observe and record any thermal anomaly prior to the events that deviated from the baseline. Our recent results support the hypothesis of a possible relationship between an thermodynamic processes produced by increasing tectonic stress in the Earth's crust and a subsequent electro-chemical interaction between this crust and the atmosphere/ionosphere.

Effect of L1{sub 2} ordering in antiferromagnetic Ir-Mn epitaxial layer on exchange bias of FePd films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chang, Y. C.; Duh, J. G., E-mail: pmami.hsiao@gmail.com, E-mail: lin.yg@nsrrc.org.tw, E-mail: jgd@mx.nthu.edu.tw; Hsiao, S. N., E-mail: pmami.hsiao@gmail.com, E-mail: lin.yg@nsrrc.org.tw, E-mail: jgd@mx.nthu.edu.tw

2015-05-07

Two series of samples of single-layer IrMn and IrMn/FePd bilayer films, deposited on a single-crystal MgO substrate at different IrMn deposition temperatures (T{sub s} = 300–700 °C), were investigated using magnetron sputtering. L1{sub 2} ordering was revealed for the 30 nm-thick IrMn epitaxial (001) films with T{sub s} ≥ 400 °C, determined by synchrotron radiation x-ray diffractometry (XRD). XRD results also provide evidence of the epitaxial growth of the IrMn films on MgO substrate. Increasing T{sub s} from 400 to 700 °C monotonically increases the ordering parameter of L1{sub 2} phases from 0.17 to 0.81. An in-plane exchange bias field (H{sub eb}) of 22 Oe is obtained in amore » 10 nm-thick FePd film that is deposited on the disordered IrMn films. As the L1{sub 2} ordering of the IrMn layers increases, the H{sub eb} gradually decreases to 0 Oe, meaning that the exchange bias behavior vanishes. The increased surface roughness, revealed by atomic force microscopy, of the epitaxial IrMn layers with increasing T{sub s} cannot be the main cause of the decrease in H{sub eb} due to the compensated surface spins regardless of the disordered and ordered (001) IrMn layers. The change of antiferromagnetic structure from the A1 to the L1{sub 2} phase was correlated with the evolution of H{sub eb}.« less

Multi-sensor Improved Sea-Surface Temperature (MISST) for IOOS - Navy Component

DTIC Science & Technology

2013-09-30

application and data fusion techniques. 2. Parameterization of IR and MW retrieval differences, with consideration of diurnal warming and cool-skin effects...associated retrieval confidence, standard deviation (STD), and diurnal warming estimates to the application user community in the new GDS 2.0 GHRSST...including coral reefs, ocean modeling in the Gulf of Mexico, improved lake temperatures, numerical data assimilation by ocean models, numerical

Projective rectification of infrared images from air-cooled condenser temperature measurement by using projection profile features and cross-ratio invariability.

PubMed

Xu, Lijun; Chen, Lulu; Li, Xiaolu; He, Tao

2014-10-01

In this paper, we propose a projective rectification method for infrared images obtained from the measurement of temperature distribution on an air-cooled condenser (ACC) surface by using projection profile features and cross-ratio invariability. In the research, the infrared (IR) images acquired by the four IR cameras utilized are distorted to different degrees. To rectify the distorted IR images, the sizes of the acquired images are first enlarged by means of bicubic interpolation. Then, uniformly distributed control points are extracted in the enlarged images by constructing quadrangles with detected vertical lines and detected or constructed horizontal lines. The corresponding control points in the anticipated undistorted IR images are extracted by using projection profile features and cross-ratio invariability. Finally, a third-order polynomial rectification model is established and the coefficients of the model are computed with the mapping relationship between the control points in the distorted and anticipated undistorted images. Experimental results obtained from an industrial ACC unit show that the proposed method performs much better than any previous method we have adopted. Furthermore, all rectified images are stitched together to obtain a complete image of the whole ACC surface with a much higher spatial resolution than that obtained by using a single camera, which is not only useful but also necessary for more accurate and comprehensive analysis of ACC performance and more reliable optimization of ACC operations.

High-Temperature Surface Thermometry Technique based on Upconversion Nano-Phosphors

NASA Astrophysics Data System (ADS)

Combs, C.; Clemens, N.; Guo, X.; Song, H.; Zhao, H.; Li, K. K.; Zou, Y. K.; Jiang, H.

2011-11-01

Downconversion thermographic phosphors have been extensively used for high-temperature surface thermometry applications (e.g., aerothermodynamics, turbine blades) where temperature-sensitive paint is not viable. In downconversion techniques the phosphorescence is at longer wavelengths than the excitation source. We are developing a new upconversion thermographic phosphor technique that employs rare-earth-doped ceramics whose phosphorescence exhibit a strong temperature dependence. In the upconversion technique the phosphor is excited with near-IR light and emission is at visible wavelengths; thus, it does not require expensive UV windows and does not suffer from interference from background fluorescence. In this work the upconversion phosphors have been characterized in terms of their intensity, lifetimes and spectral content over a temperature range of 300K to 1500K. The technique has been evaluated for applications of 2D surface temperature measurements by using the total integrated intensity and the ratio of emission in different visible color bands. The results indicate that upconversion phosphor thermometry is a promising technique for making non-contact high-surface temperature measurements with good accuracy. Work supported by NASA under contract NNX11CG89P.

A first principle study for the adsorption and absorption of carbon atom and the CO dissociation on Ir(100) surface

NASA Astrophysics Data System (ADS)

Erikat, I. A.; Hamad, B. A.

2013-11-01

We employ density functional theory to examine the adsorption and absorption of carbon atom as well as the dissociation of carbon monoxide on Ir(100) surface. We find that carbon atoms bind strongly with Ir(100) surface and prefer the high coordination hollow site for all coverages. In the case of 0.75 ML coverage of carbon, we obtain a bridging metal structure due to the balance between Ir-C and Ir-Ir interactions. In the subsurface region, the carbon atom prefers the octahedral site of Ir(100) surface. We find large diffusion barrier for carbon atom into Ir(100) surface (2.70 eV) due to the strong bonding between carbon atom and Ir(100) surface, whereas we find a very small segregation barrier (0.22 eV) from subsurface to the surface. The minimum energy path and energy barrier for the dissociation of CO on Ir(100) surface are obtained by using climbing image nudge elastic band. The energy barrier of CO dissociation on Ir(100) surface is found to be 3.01 eV, which is appreciably larger than the association energy (1.61 eV) of this molecule.

A first principle study for the adsorption and absorption of carbon atom and the CO dissociation on Ir(100) surface.

PubMed

Erikat, I A; Hamad, B A

2013-11-07

We employ density functional theory to examine the adsorption and absorption of carbon atom as well as the dissociation of carbon monoxide on Ir(100) surface. We find that carbon atoms bind strongly with Ir(100) surface and prefer the high coordination hollow site for all coverages. In the case of 0.75 ML coverage of carbon, we obtain a bridging metal structure due to the balance between Ir-C and Ir-Ir interactions. In the subsurface region, the carbon atom prefers the octahedral site of Ir(100) surface. We find large diffusion barrier for carbon atom into Ir(100) surface (2.70 eV) due to the strong bonding between carbon atom and Ir(100) surface, whereas we find a very small segregation barrier (0.22 eV) from subsurface to the surface. The minimum energy path and energy barrier for the dissociation of CO on Ir(100) surface are obtained by using climbing image nudge elastic band. The energy barrier of CO dissociation on Ir(100) surface is found to be 3.01 eV, which is appreciably larger than the association energy (1.61 eV) of this molecule.

Global Military Operating Environments (GMOE) Phase I: Linking Natural Environments, International Security, and Military Operations

DTIC Science & Technology

2013-01-30

example from the Negev Desert, Israel, Journal of Geophysical Research, (05 2009): 1. doi: 01/14/2013 5.00 Michael Young, Eric McDonald, Jianting Zhu... radiation (incoming – reflected) x Solar Radiation Eppley Incoming solar radiation x Surface temperature IR Apogee Continuous surface...and electrical properties (dielectric permittivity and electrical conductivity). Additional measurements of solar radiation (four components), air

Nanostructured F doped IrO2 electro-catalyst powders for PEM based water electrolysis

NASA Astrophysics Data System (ADS)

Kadakia, Karan Sandeep; Jampani, Prashanth H.; Velikokhatnyi, Oleg I.; Datta, Moni Kanchan; Park, Sung Kyoo; Hong, Dae Ho; Chung, Sung Jae; Kumta, Prashant N.

2014-12-01

Fluorine doped iridium oxide (IrO2:F) powders with varying F content ranging from 0 to 20 wt.% has been synthesized by using a modification of the Adams fusion method. The precursors (IrCl4 and NH4F) are mixed with NaNO3 and heated to elevated temperatures to form high surface area nanomaterials as electro-catalysts for PEM based water electrolysis. The catalysts were then coated on a porous Ti substrate and have been studied for the oxygen evolution reaction in PEM based water electrolysis. The IrO2:F with an optimum composition of IrO2:10 wt.% F shows remarkably superior electrochemical activity and chemical stability compared to pure IrO2. The results have also been supported via kinetic studies by conducting rotating disk electrode (RDE) experiments. The RDE studies confirm that the electro-catalysts follow the two electron transfer reaction for electrolysis with calculated activation energy of ∼25 kJ mol-1. Single full cell tests conducted also validate the superior electrochemical activity of the 10 wt.% F doped IrO2.

Effect of simultaneous infrared dry-blanching and dehydration on quality characteristics of carrot slices

USDA-ARS?s Scientific Manuscript database

This study investigated the effects of various processing parameters on carrot slices exposed to infrared (IR) radiation heating for achieving simultaneous infrared dry-blanching and dehydration (SIRDBD). The investigated parameters were product surface temperature, slice thickness and processing ti...

The thermal structure of Titan's atmosphere

NASA Technical Reports Server (NTRS)

Mckay, Christopher P.; Pollack, James B.; Courtin, Regis

1989-01-01

The present radiative-convective model of the Titan atmosphere thermal structure obtains the solar and IR radiation in a series of spectral intervals with vertical resolution. Haze properties have been determined with a microphysics model encompassing a minimum of free parameters. It is determined that gas and haze opacity alone, using temperatures established by Voyager observations, yields a model that is within a few percent of the radiative convective balance throughout the Titan atmosphere. Model calculations of the surface temperature are generally colder than the observed value by 5-10 K; better agreement is obtained through adjustment of the model parameters. Sunlight absorption by stratospheric haze and pressure-induced gas opacity in the IR are the most important thermal structure-controlling factors.

Monitoring Surface Climate With its Emissivity Derived From Satellite Measurements

NASA Technical Reports Server (NTRS)

Zhou, Daniel K.; Larar, Allen M.; Liu, Xu

2012-01-01

Satellite thermal infrared (IR) spectral emissivity data have been shown to be significant for atmospheric research and monitoring the Earth fs environment. Long-term and large-scale observations needed for global monitoring and research can be supplied by satellite-based remote sensing. Presented here is the global surface IR emissivity data retrieved from the last 5 years of Infrared Atmospheric Sounding Interferometer (IASI) measurements observed from the MetOp-A satellite. Monthly mean surface properties (i.e., skin temperature T(sub s) and emissivity spectra epsilon(sub v) with a spatial resolution of 0.5x0.5-degrees latitude-longitude are produced to monitor seasonal and inter-annual variations. We demonstrate that surface epsilon(sub v) and T(sub s) retrieved with IASI measurements can be used to assist in monitoring surface weather and surface climate change. Surface epsilon(sub v) together with T(sub s) from current and future operational satellites can be utilized as a means of long-term and large-scale monitoring of Earth 's surface weather environment and associated changes.

Effect of atomic layer deposition coatings on the surface structure of anodic aluminum oxide membranes.

PubMed

Xiong, Guang; Elam, Jeffrey W; Feng, Hao; Han, Catherine Y; Wang, Hsien-Hau; Iton, Lennox E; Curtiss, Larry A; Pellin, Michael J; Kung, Mayfair; Kung, Harold; Stair, Peter C

2005-07-28

Anodic aluminum oxide (AAO) membranes were characterized by UV Raman and FT-IR spectroscopies before and after coating the entire surface (including the interior pore walls) of the AAO membranes by atomic layer deposition (ALD). UV Raman reveals the presence of aluminum oxalate in bulk AAO, both before and after ALD coating with Al2O3, because of acid anion incorporation during the anodization process used to produce AAO membranes. The aluminum oxalate in AAO exhibits remarkable thermal stability, not totally decomposing in air until exposed to a temperature >900 degrees C. ALD was used to cover the surface of AAO with either Al2O3 or TiO2. Uncoated AAO have FT-IR spectra with two separate types of OH stretches that can be assigned to isolated OH groups and hydrogen-bonded surface OH groups, respectively. In contrast, AAO surfaces coated by ALD with Al2O3 display a single, broad band of hydrogen-bonded OH groups. AAO substrates coated with TiO2 show a more complicated behavior. UV Raman results show that very thin TiO2 coatings (1 nm) are not stable upon annealing to 500 degrees C. In contrast, thicker coatings can totally cover the contaminated alumina surface and are stable at temperatures in excess of 500 degrees C.

Satellite Infrared Radiation Measurements Prior to the Major Earthquakes

NASA Technical Reports Server (NTRS)

Ouzounov, Dimitar; Pulintes, S.; Bryant, N.; Taylor, Patrick; Freund, F.

2005-01-01

This work describes our search for a relationship between tectonic stresses and increases in mid-infrared (IR) flux as part of a possible ensemble of electromagnetic (EM) phenomena that may be related to earthquake activity. We present and &scuss observed variations in thermal transients and radiation fields prior to the earthquakes of Jan 22, 2003 Colima (M6.7) Mexico, Sept. 28 .2004 near Parkfield (M6.0) in California and Northern Sumatra (M8.5) Dec. 26,2004. Previous analysis of earthquake events has indicated the presence of an IR anomaly, where temperatures increased or did not return to its usual nighttime value. Our procedures analyze nighttime satellite data that records the general condtion of the ground after sunset. We have found from the MODIS instrument data that five days before the Colima earthquake the IR land surface nighttime temperature rose up to +4 degrees C in a 100 km radius around the epicenter. The IR transient field recorded by MODIS in the vicinity of Parkfield, also with a cloud free environment, was around +1 degree C and is significantly smaller than the IR anomaly around the Colima epicenter. Ground surface temperatures near the Parkfield epicenter four days prior to the earthquake show steady increase. However, on the night preceding the quake, a significant drop in relative humidity was indicated, process similar to those register prior to the Colima event. Recent analyses of continuous ongoing long- wavelength Earth radiation (OLR) indicate significant and anomalous variability prior to some earthquakes. The cause of these anomalies is not well understood but could be the result of a triggering by an interaction between the lithosphere-hydrosphere and atmospheric related to changes in the near surface electrical field and/or gas composition prior to the earthquake. The OLR anomaly usually covers large areas surrounding the main epicenter. We have found strong anomalies signal (two sigma) along the epicentral area signals on Dec 21, five days prior to the Northern Sumatra quake compared to the reference field for December 2001-2004 periods. Our recent results support the hypothesis of a possible relationship between a thermodynamic processes produced by increasing tectonic stress in the Earth's crust and a subsequent electro-chemical interaction between this crust and the atmosphere/ionosphere.

Thermal structure of the Martian atmosphere retrieved from the IR spectrometry in the 15 μm CO2 band: input to MIRA

NASA Astrophysics Data System (ADS)

Zasova, L. V.; Formisano, V.; Grassi, D.; Igantiev, N. I.; Moroz, V. I.

This paper describes one of the sources of the data concerning the thermal structure of the Martian atmosphere, based on the thermal IR spectrometry method. It allows to investigate the Martian atmosphere below 55 km by retrieving the temperature profiles from the 15 μm CO2 band. This approach enables to reach the vertical resolution of several kilometers and the temperature accuracy of several Kelvins. An aerosol abundance, which influences the temperature profile, is obtained from the continuum of the same spectrum parallel with the temperature profile and is taken into account in the temperature retrieval procedure in a self consistent way. Although this method has the limited vertical resolution, it possesses a significant advantage: the thermal IR spectrometry allows to monitor the temperature profiles with a good coverage both in space and local time. The Planetary Fourier spectrometer on board of Mars Express has the spectral range from 250 to 8000 cm-1 and a high spectral resolution of about 2 cm-1. Vertical temperature profiles retrieval is one of the main scientific goals of the experiment. The important data are expected to be obtained on the vertical thermal structure of the atmosphere, and its dependence on latitude, longitude, season, local time, clouds and dust loadings. These results should give a significant input in the future MIRA, being included in the Chapter “Structure of the atmosphere from the surface to 100 km”.

IR characteristic simulation of city scenes based on radiosity model

NASA Astrophysics Data System (ADS)

Xiong, Xixian; Zhou, Fugen; Bai, Xiangzhi; Yu, Xiyu

2013-09-01

Reliable modeling for thermal infrared (IR) signatures of real-world city scenes is required for signature management of civil and military platforms. Traditional modeling methods generally assume that scene objects are individual entities during the physical processes occurring in infrared range. However, in reality, the physical scene involves convective and conductive interactions between objects as well as the radiations interactions between objects. A method based on radiosity model describes these complex effects. It has been developed to enable an accurate simulation for the radiance distribution of the city scenes. Firstly, the physical processes affecting the IR characteristic of city scenes were described. Secondly, heat balance equations were formed on the basis of combining the atmospheric conditions, shadow maps and the geometry of scene. Finally, finite difference method was used to calculate the kinetic temperature of object surface. A radiosity model was introduced to describe the scattering effect of radiation between surface elements in the scene. By the synthesis of objects radiance distribution in infrared range, we could obtain the IR characteristic of scene. Real infrared images and model predictions were shown and compared. The results demonstrate that this method can realistically simulate the IR characteristic of city scenes. It effectively displays the infrared shadow effects and the radiation interactions between objects in city scenes.

First investigations to refine video-based IR thermography as a non-invasive tool to monitor the body temperature of calves.

PubMed

Hoffmann, G; Schmidt, M; Ammon, C

2016-09-01

In this study, a video-based infrared camera (IRC) was investigated as a tool to monitor the body temperature of calves. Body surface temperatures were measured contactless using videos from an IRC fixed at a certain location in the calf feeder. The body surface temperatures were analysed retrospectively at three larger areas: the head area (in front of the forehead), the body area (behind forehead) and the area of the entire animal. The rectal temperature served as a reference temperature and was measured with a digital thermometer at the corresponding time point. A total of nine calves (Holstein-Friesians, 8 to 35 weeks old) were examined. The average maximum temperatures of the area of the entire animal (mean±SD: 37.66±0.90°C) and the head area (37.64±0.86°C) were always higher than that of the body area (36.75±1.06°C). The temperatures of the head area and of the entire animal were very similar. However, the maximum temperatures as measured using IRC increased with an increase in calf rectal temperature. The maximum temperatures of each video picture for the entire visible body area of the calves appeared to be sufficient to measure the superficial body temperature. The advantage of the video-based IRC over conventional IR single-picture cameras is that more than one picture per animal can be analysed in a short period of time. This technique provides more data for analysis. Thus, this system shows potential as an indicator for continuous temperature measurements in calves.

Spacecraft thermal balance testing using infrared sources

NASA Technical Reports Server (NTRS)

Tan, G. B. T.; Walker, J. B.

1982-01-01

A thermal balance test (controlled flux intensity) on a simple black dummy spacecraft using IR lamps was performed and evaluated, the latter being aimed specifically at thermal mathematical model (TMM) verification. For reference purposes the model was also subjected to a solar simulation test (SST). The results show that the temperature distributions measured during IR testing for two different model attitudes under steady state conditions are reproducible with a TMM. The TMM test data correlation is not as accurate for IRT as for SST. Using the standard deviation of the temperature difference distribution (analysis minus test) the SST data correlation is better by a factor of 1.8 to 2.5. The lower figure applies to the measured and the higher to the computer-generated IR flux intensity distribution. Techniques of lamp power control are presented. A continuing work program is described which is aimed at quantifying the differences between solar simulation and infrared techniques for a model representing the thermal radiating surfaces of a large communications spacecraft.

Physicochemical properties of chars at different treatment temperatures.

PubMed

Kim, Sung Su; Kang, Youn Suk; Lee, Hyun Dong; Kim, Jae Kwan; Hong, Sung Chang

2012-02-01

In this study, the physicochemical properties of the char of Indonesian SM coal following heat treatment at various temperatures were evaluated using X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), and morphological and specific surface area analysis. Based on these analyses, heat treatment of coal was determined to be the most effective in increasing the coal rank. In the XPS analysis, the C-O and C-O-C groups and quaternary-N species were found to be of a lower grade coal when the pretreatment temperature decreased, meanwhile the C-C group and pyridinic species increased. In the FT-IR analysis, the collapse of the C-O and C-O-C group was observed due to the collapse of the ether group. In SEM and Brunauer-Emmett-Teller (BET) analysis, a decrease in the ether group was shown to be accompanied with the formation of micropores.

In situ high-temperature characterization of AlN-based surface acoustic wave devices

NASA Astrophysics Data System (ADS)

Aubert, Thierry; Bardong, Jochen; Legrani, Ouarda; Elmazria, Omar; Badreddine Assouar, M.; Bruckner, Gudrun; Talbi, Abdelkrim

2013-07-01

We report on in situ electrical measurements of surface acoustic wave delay lines based on AlN/sapphire structure and iridium interdigital transducers between 20 °C and 1050 °C under vacuum conditions. The devices show a great potential for temperature sensing applications. Burnout is only observed after 60 h at 1050 °C and is mainly attributed to the agglomeration phenomena undergone by the Ir transducers. However, despite the vacuum conditions, a significant oxidation of the AlN film is observed, pointing out the limitation of the considered structure at least at such extreme temperatures. Original structures overcoming this limitation are then proposed and discussed.

Skin Temperature Processes in the Presence of Sea Ice

NASA Astrophysics Data System (ADS)

Brumer, S. E.; Zappa, C. J.; Brown, S.; McGillis, W. R.; Loose, B.

2013-12-01

Monitoring the sea-ice margins of polar oceans and understanding the physical processes at play at the ice-ocean-air interface is essential in the perspective of a changing climate in which we face an accelerated decline of ice caps and sea ice. Remote sensing and in particular InfraRed (IR) imaging offer a unique opportunity not only to observe physical processes at sea-ice margins, but also to measure air-sea exchanges near ice. It permits monitoring ice and ocean temperature variability, and can be used for derivation of surface flow field allowing investigating turbulence and shearing at the ice-ocean interface as well as ocean-atmosphere gas transfer. Here we present experiments conducted with the aim of gaining an insight on how the presence of sea ice affects the momentum exchange between the atmosphere and ocean and investigate turbulence production in the interplay of ice-water shear, convection, waves and wind. A set of over 200 high resolution IR imagery records was taken at the US Army Cold Regions Research and Engineering Laboratory (CRREL, Hanover NH) under varying ice coverage, fan and pump settings. In situ instruments provided air and water temperature, salinity, subsurface currents and wave height. Air side profiling provided environmental parameters such as wind speed, humidity and heat fluxes. The study aims to investigate what can be gained from small-scale high-resolution IR imaging of the ice-ocean-air interface; in particular how sea ice modulates local physics and gas transfer. The relationship between water and ice temperatures with current and wind will be addressed looking at the ocean and ice temperature variance. Various skin temperature and gas transfer parameterizations will be evaluated at ice margins under varying environmental conditions. Furthermore the accuracy of various techniques used to determine surface flow will be assessed from which turbulence statistics will be determined. This will give an insight on how ice presence may affect the dissipation of turbulent kinetic energy.

IR spectral properties of dust and ice at the Mars south polar cap

NASA Astrophysics Data System (ADS)

Titus, T. N.; Kieffer, H. H.

2001-11-01

Removal of atmospheric dust effects is required to derive surface IR spectral emissivity. Commonly, the atmospheric-surface separation is based on radiative transfer (RT) spectral inversion methods using nadir-pointing observations. This methodology depends on a priori knowledge of the spectral shape of each atmospheric aerosol (e.g. dust or water ice) and a large thermal contrast between the surface and atmosphere. RT methods fail over the polar caps due to low thermal contrast between the atmosphere and the surface. We have used multi-angle Emission Phase Function (EPF) observations to estimate the opacity spectrum of dust over the springtime south polar cap and the underlying surface radiance, and thus, the surface emissivity. We include a few EPFs from Hellas Basin as a basis for comparisons between the spectral shape of polar and non-polar dust. Surface spectral emissivities over the seasonal cap are compared to CO2 models. Our results show that the spectral shape of the polar dust opacity is not constant, but is a two-parameter family that can be characterized by the 9 um and 20 um opacities. The 9 um opacity varies from 0.15 to 0.45 and characterizes the overall atmospheric conditions. The 9 um to 20 um opacity ratio varies from 2.0 to 5.1, suggesting changes in dust size distribution over the polar caps. Derived surface temperatures from the EPFs confirm that the slightly elevated temperatures (relative to CO2 frost temperature) observed in ``cryptic'' regions are a surface effect, not atmospheric. Comparison of broad-band reflectivity and surface emissivities to model spectra suggest the bright regions (e.g. perennial cap, Mountains of Mitchell) have higher albedos due to a thin surface layer of fine-grain CO2 (perhaps either frost or fractured ice) with an underlying layer of either coarse grain or slab CO2 ice.

Arctic PBL Cloud Height and Motion Retrievals from MISR and MINX

NASA Technical Reports Server (NTRS)

Wu, Dong L.

2012-01-01

How Arctic clouds respond and feedback to sea ice loss is key to understanding of the rapid climate change seen in the polar region. As more open water becomes available in the Arctic Ocean, cold air outbreaks (aka. off-ice flow from polar lows) produce a vast sheet of roll clouds in the planetary boundary layer (PBl). The cold air temperature and wind velocity are the critical parameters to determine and understand the PBl structure formed under these roll clouds. It has been challenging for nadir visible/IR sensors to detect Arctic clouds due to lack of contrast between clouds and snowy/icy surfaces. In addition) PBl temperature inversion creates a further problem for IR sensors to relate cloud top temperature to cloud top height. Here we explore a new method with the Multiangle Imaging Spectro-Radiometer (MISR) instrument to measure cloud height and motion over the Arctic Ocean. Employing a stereoscopic-technique, MISR is able to measure cloud top height accurately and distinguish between clouds and snowy/icy surfaces with the measured height. We will use the MISR INteractive eXplorer (MINX) to quantify roll cloud dynamics during cold-air outbreak events and characterize PBl structures over water and over sea ice.

Chemistry of Protostellar Envelopes and Disks

NASA Astrophysics Data System (ADS)

Flores Rivera, Lizxandra; Terebey, Susan; Willacy, Karen

2018-06-01

Molecule formation is dynamic during the protostar collapse phase, driven by changes in temperature, density, and UV radiation as gas and dust flows from the envelope onto the forming protoplanetary disk. In this work, we compare physical models based on two different collapse solutions. We modeled the chemistry (created by Karen Willacy) for C18O to see how its abundance changes over time using as primary input parameters the temperature and density profile that were produced by the dust Radiative Transfer (MCRT) model called HOCHUNK3D from Whitney (2003). Given this model, we produce synthetic line emission maps from L1527 IRS to simulate the Class 0/I protostar L1527 IRS using RADMC3D code and compare them with previous observations from ALMA. High concentrations of gas phase molecules of C18O are found within the 20 AU in areas in the envelope that are close to the surface of the disk. In the outermost part of the disk surface, the C18O freezes out beyond 400 AU, showing a much reduced abundance where the temperature profile drops down below 25 K. In cold regions, the radiation field plays an important role in the chemistry.

FTIR spectroscopy and thermodynamics of hydrogen adsorbed in a cross-linked polymer.

PubMed

Spoto, Giuseppe; Vitillo, Jenny G; Cocina, Donato; Damin, Alessandro; Bonino, Francesca; Zecchina, Adriano

2007-09-28

The adsorption of H(2) in a cross-linked poly(styrene-co-divinylbenzene) (St-DVB) microporous polymer (BET surface area 920 m(2) g(-1)) is studied by volumetric and gravimetric methods, FTIR spectroscopy at variable temperature (300-14 K) and ab initio calculations. At 77 K the polymer reversibly stores up to 1.3 mass% H(2) at a pressure of 1 bar and 1.8 mass% at 10 bar. The adsorption process involves the specific interaction of H(2) with the structural phenyl rings through weak dispersive forces. The interacting molecules become IR active and give rise to vibrational and rotational-vibrational manifestations which are affected by the temperature, the contact time and the H(2) equilibrium pressure. The spectra of the H(2)/St-DVB system reported here represent the first IR evidence of the adsorption of hydrogen on unsaturated molecules. The adsorption enthalpy is evaluated by the VTIR (variable temperature IR spectroscopy) method (C. Otero Areán et al., Phys. Chem. Chem. Phys., 2007, DOI: 10.1039/b615535a) and compared with the results of ab initio calculations for the H(2)/benzene interaction and with literature data.

A high resolution IR/visible imaging system for the W7-X limiter

NASA Astrophysics Data System (ADS)

Wurden, G. A.; Stephey, L. A.; Biedermann, C.; Jakubowski, M. W.; Dunn, J. P.; Gamradt, M.

2016-11-01

A high-resolution imaging system, consisting of megapixel mid-IR and visible cameras along the same line of sight, has been prepared for the new W7-X stellarator and was operated during Operational Period 1.1 to view one of the five inboard graphite limiters. The radial line of sight, through a large diameter (184 mm clear aperture) uncoated sapphire window, couples a direct viewing 1344 × 784 pixel FLIR SC8303HD camera. A germanium beam-splitter sends visible light to a 1024 × 1024 pixel Allied Vision Technologies Prosilica GX1050 color camera. Both achieve sub-millimeter resolution on the 161 mm wide, inertially cooled, segmented graphite tiles. The IR and visible cameras are controlled via optical fibers over full Camera Link and dual GigE Ethernet (2 Gbit/s data rates) interfaces, respectively. While they are mounted outside the cryostat at a distance of 3.2 m from the limiter, they are close to a large magnetic trim coil and require soft iron shielding. We have taken IR data at 125 Hz to 1.25 kHz frame rates and seen that surface temperature increases in excess of 350 °C, especially on leading edges or defect hot spots. The IR camera sees heat-load stripe patterns on the limiter and has been used to infer limiter power fluxes (˜1-4.5 MW/m2), during the ECRH heating phase. IR images have also been used calorimetrically between shots to measure equilibrated bulk tile temperature, and hence tile energy inputs (in the range of 30 kJ/tile with 0.6 MW, 6 s heating pulses). Small UFO's can be seen and tracked by the FLIR camera in some discharges. The calibrated visible color camera (100 Hz frame rate) has also been equipped with narrow band C-III and H-alpha filters, to compare with other diagnostics, and is used for absolute particle flux determination from the limiter surface. Sometimes, but not always, hot-spots in the IR are also seen to be bright in C-III light.

A high resolution IR/visible imaging system for the W7-X limiter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wurden, G. A., E-mail: wurden@lanl.gov; Dunn, J. P.; Stephey, L. A.

A high-resolution imaging system, consisting of megapixel mid-IR and visible cameras along the same line of sight, has been prepared for the new W7-X stellarator and was operated during Operational Period 1.1 to view one of the five inboard graphite limiters. The radial line of sight, through a large diameter (184 mm clear aperture) uncoated sapphire window, couples a direct viewing 1344 × 784 pixel FLIR SC8303HD camera. A germanium beam-splitter sends visible light to a 1024 × 1024 pixel Allied Vision Technologies Prosilica GX1050 color camera. Both achieve sub-millimeter resolution on the 161 mm wide, inertially cooled, segmented graphitemore » tiles. The IR and visible cameras are controlled via optical fibers over full Camera Link and dual GigE Ethernet (2 Gbit/s data rates) interfaces, respectively. While they are mounted outside the cryostat at a distance of 3.2 m from the limiter, they are close to a large magnetic trim coil and require soft iron shielding. We have taken IR data at 125 Hz to 1.25 kHz frame rates and seen that surface temperature increases in excess of 350 °C, especially on leading edges or defect hot spots. The IR camera sees heat-load stripe patterns on the limiter and has been used to infer limiter power fluxes (∼1–4.5 MW/m{sup 2}), during the ECRH heating phase. IR images have also been used calorimetrically between shots to measure equilibrated bulk tile temperature, and hence tile energy inputs (in the range of 30 kJ/tile with 0.6 MW, 6 s heating pulses). Small UFO’s can be seen and tracked by the FLIR camera in some discharges. The calibrated visible color camera (100 Hz frame rate) has also been equipped with narrow band C-III and H-alpha filters, to compare with other diagnostics, and is used for absolute particle flux determination from the limiter surface. Sometimes, but not always, hot-spots in the IR are also seen to be bright in C-III light.« less

Quantitative Infrared Image Analysis Of Simultaneous Upstream and Downstream Microgravity Flame Spread over Thermally-Thin Cellulose in Low Speed Forced Flow

NASA Technical Reports Server (NTRS)

Olson, S. L.; Lee, J. R.; Fujita, O.; Kikuchi, M.; Kashiwagi, T.

2013-01-01

The effect of low velocity forced flow on microgravity flame spread is examined using quantitative analysis of infrared video imaging. The objective of the quantitative analysis is to provide insight into the mechanisms of flame spread in microgravity where the flame is able to spread from a central location on the fuel surface, rather than from an edge. Surface view calibrated infrared images of ignition and flame spread over a thin cellulose fuel were obtained along with a color video of the surface view and color images of the edge view using 35 mm color film at 2 Hz. The cellulose fuel samples were mounted in the center of a 12 cm wide by 16 cm tall flow duct and were ignited in microgravity using a straight hot wire across the center of the 7.5 cm wide by 14 cm long samples. Four cases, at 1 atm. 35%O2 in N2, at forced flows from 2 cm/s to 20 cm/s are presented here. This flow range captures flame spread from strictly upstream spread at low flows, to predominantly downstream spread at high flow. Surface temperature profiles are evaluated as a function of time, and temperature gradients for upstream and downstream flame spread are measured. Flame spread rates from IR image data are compared to visible image spread rate data. IR blackbody temperatures are compared to surface thermocouple readings to evaluate the effective emissivity of the pyrolyzing surface. Preheat lengths and pyrolysis lengths are evaluated both upstream and downstream of the central ignition point. A surface energy balance estimates the net heat flux from the flame to the fuel surface along the length of the fuel. Surface radiative loss and gas-phase radiation from soot are measured relative to the net heat feedback from the flame. At high surface heat loss relative to heat feedback, the downstream flame spread does not occur.

Twins and their boundaries during homoepitaxy on Ir(111)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bleikamp, Sebastian; Michely, Thomas; Coraux, Johann

2011-02-01

The growth and annealing behavior of strongly twinned homoepitaxial films on Ir(111) have been investigated by scanning tunneling microscopy, low-energy electron diffraction, and surface x-ray diffraction. In situ surface x-ray diffraction during and after film growth turned out to be an efficient tool for the determination of twin fractions in multilayer films and to unravel the nature of lateral twin crystallite boundaries. The annealing of the twin structures is shown to take place in a two-step process; first, the length of the lateral twin crystallite boundaries is reduced, without affecting the amount of twinned material, and then, at much highermore » temperatures, the twins themselves anneal. Within moderately annealed films lateral twin crystallite boundaries are visible at the film surface as fractional steps from which strain fields extend. The nature of these boundaries is discussed.« less

Variability in surface infrared reflectance of thirteen nitrile rubber gloves at key wavelengths for analysis of captan.

PubMed

Phalen, R N; Que Hee, Shane S

2007-02-01

The aim of this study was to investigate the surface variability of 13 powder-free, unlined, and unsupported nitrile rubber gloves using attenuated total reflection Fourier transform infrared (ATR-FT-IR) spectrophotometry at key wavelengths for analysis of captan contamination. The within-glove, within-lot, and between-lot variability was measured at 740, 1124, 1252, and 1735 cm(-1), the characteristic captan reflectance minima wavelengths. Three glove brands were assessed after conditioning overnight at relative humidity (RH) values ranging from 2 +/- 1 to 87 +/- 4% and temperatures ranging from -8.6 +/- 0.7 to 59.2 +/- 0.9 degrees C. For all gloves, 1735 cm(-1) provided the lowest background absorbance and greatest potential sensitivity for captan analysis on the outer glove surface: absorbances ranged from 0.0074 +/- 0.0005 (Microflex) to 0.0195 +/- 0.0024 (SafeSkin); average within-glove coefficients of variation (CV) ranged from 2.7% (Best, range 0.9-5.3%) to 10% (SafeSkin, 1.2-17%); within-glove CVs greater than 10% were for one brand (SafeSkin); within-lot CVs ranged from 2.8% (Best N-Dex) to 28% (SafeSkin Blue); and between-lot variation was statistically significant (p < or = 0.05) for all but two SafeSkin lots. The RH had variable effects dependent on wavelength, being minimal at 1735, 1252, and 1124 cm(-1) and highest at 3430 cm(-1) (O-H stretch region). There was no significant effect of temperature conditioning. Substantial within-glove, within-lot, and between-lot variability was observed. Thus, surface analysis using ATR-FT-IR must treat glove brands and lots as different. ATR-FT-IR proved to be a useful real-time analytical tool for measuring glove variability, detecting surface humidity effects, and choosing selective and sensitive wavelengths for analysis of nonvolatile surface contaminants.

Characterization of the High-Albedo NEA 3691 Bede

NASA Technical Reports Server (NTRS)

Wooden, Diane H.; Lederer, Susan M.; Jehin, Emmanuel; Rozitis, Benjamin; Jefferson, Jeffrey D.; Nelson, Tyler W.; Dotson, Jessie L.; Ryan, Erin L.; Howell, Ellen S.; Fernandez, Yanga R.;

Characterization of the high-albedo NEA 3691 Bede

NASA Astrophysics Data System (ADS)

Wooden, Diane H.; Lederer, Susan M.; Jehin, Emmanuel; Rozitis, Benjamin; Jefferson, Jeffrey D.; Nelson, Tyler W.; Dotson, Jessie L.; Ryan, Erin L.; Howell, Ellen S.; Fernandez, Yanga R.; Lovell, Amy J.; Woodward, Charles E.; Harker, David Emerson

2016-10-01

Characterization of NEAs provides important inputs to models for atmospheric entry, risk assessment and mitigation. Diameter is a key parameter because diameter translates to kinetic energy in atmospheric entry. Diameters can be derived from the absolute magnitude, H(PA=0deg), and from thermal modeling of observed IR fluxes. For both methods, the albedo (pv) is important - high pv surfaces have cooler temperatures, larger diameters for a given Hmag, and shallower phase curves (larger slope parameter G). Thermal model parameters are coupled, however, so that a higher thermal inertia also results in a cooler surface temperature. Multiple parameters contribute to constraining the diameter.Observations made at multiple observing geometries can contribute to understanding the relationships between and potentially breaking some of the degeneracies between parameters. We present data and analyses on NEA 3691 Bede with the aim of best constraining the diameter and pv from a combination of thermal modeling and light curve analyses. We employ our UKIRT+Michelle mid-IR photometric observations of 3691 Bede's thermal emission at 2 phase angles (27&43 deg 2015-03-19 & 04-13), in addition to WISE data (33deg 2010-05-27, Mainzer+2011).Observing geometries differ by solar phase angles and by moderate changes in heliocentric distance (e.g., further distances produce somewhat cooler surface temperatures). With the NEATM model and for a constant IR beaming parameter (eta=constant), there is a family of solutions for (diameter, pv, G, eta) where G is the slope parameter from the H-G Relation. NEATM models employing Pravec+2012's choice of G=0.43, produce D=1.8 km and pv≈0.4, given that G=0.43 is assumed from studies of main belt asteroids (Warner+2009). We present an analysis of the light curve of 3691 Bede to constrain G from observations. We also investigate fitting thermophysical models (TPM, Rozitis+11) to constrain the coupled parameters of thermal inertia (Gamma) and surface roughness, which in turn affect diameter and pv. Surface composition can be related to pv. This study focuses on understanding and characterizing the dependency of parameters with the aim of constraining diameter, pv and thermal inertia for 3691 Bede.

Electronic signatures of dimerization in IrTe2

NASA Astrophysics Data System (ADS)

Dai, Jixia; Wu, Weida; Oh, Yoon Seok; Cheong, S.-W.; Yang, J. J.

2014-03-01

Recently, the mysterious phase transition around Tc ~ 260 K in IrTe2 has been intensively studied. A structural supermodulation with q =1/5 was identified below Tc. A variety of microscopic mechanisms have been proposed to account for this transition, including charge-density wave due to Fermi surface nesting, Te p-orbital driven structure instability, anionic depolymerization, ionic dimerization, and so on. However, there has not been an unified picture on the nature of this transition. To address this issue, we have performed low-temperature scanning tunneling microscopy and spectroscopy (STM/STS) experiments on IrTe2 and IrTe2-xSex. Our STM data clearly shows a strong bias dependence in both topography and local density of states (STS) maps. High resolution spectroscopic data further confirms the stripe-like electronic states modulation, which provides insight to the ionic dimerization revealed by X-ray diffraction.

IR thermography for dynamic detection of laminar-turbulent transition

NASA Astrophysics Data System (ADS)

Simon, Bernhard; Filius, Adrian; Tropea, Cameron; Grundmann, Sven

2016-05-01

This work investigates the potential of infrared (IR) thermography for the dynamic detection of laminar-turbulent transition. The experiments are conducted on a flat plate at velocities of 8-14 m/s, and the transition of the laminar boundary layer to turbulence is forced by a disturbance source which is turned on and off with frequencies up to 10 Hz. Three different heating techniques are used to apply the required difference between fluid and structure temperature: a heated aluminum structure is used as an internal structure heating technique, a conductive paint acts as a surface bounded heater, while an IR heater serves as an example for an external heating technique. For comparison of all heating techniques, a normalization is introduced and the frequency response of the measured IR camera signal is analyzed. Finally, the different heating techniques are compared and consequences for the design of experiments on laminar-turbulent transition are discussed.

Evaluation of the infrared test method for the olympus thermal balance tests

NASA Technical Reports Server (NTRS)

Donato, M.; Stpierre, D.; Green, J.; Reeves, M.

1986-01-01

The performance of the infrared (IR) rig used for the thermal balance testing of the Olympus S/C thermal model is discussed. Included in this evaluation are the rig effects themselves, the IRFLUX computer code used to predict the radiation inputs, the Monitored Background Radiometers (MBR's) developed to measure the absorbed radiation flux intensity, the Uniform Temperature Reference (UTR) based temperature measurement system and the data acquisition system. A preliminary set of verification tests were performed on a 1 m x 1 m zone to assess the performance of the IR lamps, calrods, MBR's and aluminized baffles. The results were used, in part, to obtain some empirical data required for the IRFLUX code. This data included lamp and calrod characteristics, the absorptance function for various surface types, and the baffle reflectivities.

Chemistry of the Burning Surface

DTIC Science & Technology

1993-10-12

simulated combustion and explo- the temperature is nonuniform along the filament length sion events. SUFKS V~V 100 IWAQ10 0 t 1 10 CABRAM OIRV...temperature. Ilee filament is slightly altered by the sample, the power results clearly show that it is the nonuniform temper%- dissipation is essentially...sample explosive and propellant material, was chosen because it is presnt on the filamenL Liquefaction of AMMO is illustrates the laIr amount of chemical

IR reflectance spectroscopy of carbon dioxide clathrate hydrates. Implications for Saturn's icy moons.

NASA Astrophysics Data System (ADS)

Oancea, A.; Grasset, O.; Le Menn, E.; Bezacier, L.; Bollengier, O.; Le Mouélic, S.; Tobie, G.

2012-04-01

A CO2 spectral band was discovered by VIMS on the Saturn's satellites Dione, Hyperion, Iapetus and Phoebe [1]. The band position on the three first satellites corresponds to CO2 trapped in a complex material, but no indication exists whether this latter is water ice or some mineral or complex organic compound [1]. On Phoebe, the CO2 spectral band is consistent with solid CO2 or CO2 molecules trapped in the small cages of a clathrate hydrate structure [2]. It is thought that clathrate hydrates could play a significant role in the chemistry of the solar nebula [3] and in the physical evolution of astrophysical objects [4]. But so far, no clathrate hydrate structure has been observed in astrophysical environments. Moreover, identification of molecules trapped in a clathrate hydrate structure is extremely difficult because of the strong IR vibration modes of the water ice matrix. In this work, experimental IR reflectance spectra for CO2 clathrate hydrates are studied on grains and films. Clathrates are synthesized in a high pressure autoclave at low temperatures. IR spectral analysis is made with a low pressure and low temperature cryostat. These experimental conditions - 80 < T < 110 K, P~10-5 bar - are relevant to icy moons' surfaces. We have observed that the IR reflectance, in the spectral region (3 - 5 μm) characterized by H2O and CO2 high absorption coefficients, is strongly dependent on physical (size, surface) and optical (n and k) properties of the samples. The impact of these parameters on the CO2 clathrate IR reflectance spectrum will be presented. A comparison between the absorption bands of CO2 clathrate hydrates obtained in our lab and CO2 absorption bands as detected by VIMS on the icy satellites of Saturn will be shown. This experimental work confirms that VIMS data are not consistent with the presence of structure I CO2 clathrate hydrates on the surface of the icy moons. Possibility of having metastable structure II still remains unsolved and will be discussed. [1] Dalton et al., Space Sci. Rev. 2010, 153 : 113-154. [2] Cruikshank D.P. et al, Icarus, 2010, 206: 561-572. [3] Mousis O. et al , Ap. J. 2009, 691: 1780-1786. [4] Choukroun M. et al, in Solar System Ices, edited by Castillo-Rogez, J. et al., 2011.

Surface Protonics Promotes Catalysis

PubMed Central

Manabe, R.; Okada, S.; Inagaki, R.; Oshima, K.; Ogo, S.; Sekine, Y.

2016-01-01

Catalytic steam reforming of methane for hydrogen production proceeds even at 473 K over 1 wt% Pd/CeO2 catalyst in an electric field, thanks to the surface protonics. Kinetic analyses demonstrated the synergetic effect between catalytic reaction and electric field, revealing strengthened water pressure dependence of the reaction rate when applying an electric field, with one-third the apparent activation energy at the lower reaction temperature range. Operando–IR measurements revealed that proton conduction via adsorbed water on the catalyst surface occurred during electric field application. Methane was activated by proton collision at the Pd–CeO2 interface, based on the inverse kinetic isotope effect. Proton conduction on the catalyst surface plays an important role in methane activation at low temperature. This report is the first describing promotion of the catalytic reaction by surface protonics. PMID:27905505

The Use of ATLAS Data to Quantify Surface Radiative Budgets in Four US Cities

NASA Technical Reports Server (NTRS)

Luvall, Jeffrey; Gonzalez, Jorge; Rickman, Douglas; Quattrochi, Dale; Schiller, Steve; Comarazamy, Daniel; Estes, Maury

2011-01-01

The additional heating of the air over the city is the result of the replacement of naturally vegetated surfaces with those composed of asphalt, concrete, rooftops and other manmade materials. The temperatures of these artificial surfaces can be 20 to 40 C higher than vegetated surfaces. This produces a dome of elevated air temperatures 5 to 8 C greater over the city, compared to the air temperatures over adjacent rural areas. This effect is called the "urban heat island". Urban landscapes are a complex mixture of vegetated and non-vegetated surfaces. It is difficult to take enough temperature measurements over a large city area to. The use of remotely sensed data from airborne scanners is ideal to characterize the complexity of urban albedo and radiant surface temperatures. The National Aeronautics and Space Administration (NASA) Airborne Thermal and Land Applications Sensor (ATLAS) operates in the visual and IR bands was used to collect data from Salt Lake City, UT, Sacramento, CA, Baton Rouge, LA. And San Juan, Puerto Rico with the main objective of investigating the Urban Heat Island (UHI). In this presentation we will examine the techniques of analyzing remotely sensed data for measuring the effect of various urban surfaces on their contribution to the urban heat island effect.

Vibrational spectroscopy and molecular dynamics of water monomers and dimers adsorbed on polycyclic aromatic hydrocarbons.

PubMed

Simon, Aude; Rapacioli, Mathias; Mascetti, Joëlle; Spiegelman, Fernand

2012-05-21

This paper reports structures, energetics, dynamics and spectroscopy of H2O and (H2O)2 systems adsorbed on coronene (C24H12), a compact polycyclic aromatic hydrocarbon (PAH). On-the-fly Born-Oppenheimer molecular dynamics simulations are performed for temperatures T varying from 10 to 300 K, on a potential energy surface obtained within the self-consistent-charge density-functional based tight-binding (SCC-DFTB) approach. Anharmonic infrared (IR) spectra are extracted from these simulations. We first benchmark the SCC-DFTB semi-empirical hamiltonian vs. DFT (Density Functional Theory) calculations that include dispersion, on (C6H6)(H2O)1,2 small complexes. We find that charge corrections and inclusion of dispersion contributions in DFTB are necessary to obtain consistent structures, energetics and IR spectra. Using this Hamiltonian, the structures, energetics and IR features of the low-energy isomers of (C24H12)(H2O)1,2 are found to be similar to the DFT ones, with evidence for a stabilizing edge-coordination. The temperature dependence of the motions of H2O and (H2O)2 on the surface of C24H12 is analysed, revealing ultra-fast periodic motion. The water dimer starts diffusing at a higher temperature than the water monomer (150 K vs. 10 K respectively), which appears to be consistent with the binding energies. Qualitative and quantitative analyses of the effects of T on the IR spectra are performed. Anharmonic factors in particular are derived and it is shown that they can be used as signatures for the presence of PAH-water complexes. Finally, this paper lays the foundations for the studies of larger (PAH)m(H2O)n clusters, that can be treated with the efficient computational approach benchmarked in this paper.

Surface-induced brightness temperature variations and their effects on detecting thin cirrus clouds using IR emission channels in the 8-12 micrometer region

NASA Technical Reports Server (NTRS)

Gao, Bo-Cai; Wiscombe, W. J.

1993-01-01

A method for detecting cirrus clouds in terms of brightness temperature differences between narrow bands at 8, 11, and 12 mu m has been proposed by Ackerman et al. (1990). In this method, the variation of emissivity with wavelength for different surface targets was not taken into consideration. Based on state-of-the-art laboratory measurements of reflectance spectra of terrestrial materials by Salisbury and D'Aria (1992), we have found that the brightness temperature differences between the 8 and 11 mu m bands for soils, rocks and minerals, and dry vegetation can vary between approximately -8 K and +8 K due solely to surface emissivity variations. We conclude that although the method of Ackerman et al. is useful for detecting cirrus clouds over areas covered by green vegetation, water, and ice, it is less effective for detecting cirrus clouds over areas covered by bare soils, rocks and minerals, and dry vegetation. In addition, we recommend that in future the variation of surface emissivity with wavelength should be taken into account in algorithms for retrieving surface temperatures and low-level atmospheric temperature and water vapor profiles.

Origin of dislocation luminescence centers and their reorganization in p-type silicon crystal subjected to plastic deformation and high temperature annealing.

PubMed

Pavlyk, Bohdan; Kushlyk, Markiyan; Slobodzyan, Dmytro

2017-12-01

Changes of the defect structure of silicon p-type crystal surface layer under the influence of plastic deformation and high temperature annealing in oxygen atmosphere were investigated by deep-level capacitance-modulation spectroscopy (DLCMS) and IR spectroscopy of molecules and atom vibrational levels. Special role of dislocations in the surface layer of silicon during the formation of its energy spectrum and rebuilding the defective structure was established. It is shown that the concentration of linear defects (N ≥ 10 4  cm -2 ) enriches surface layer with electrically active complexes (dislocation-oxygen, dislocation-vacancy, and dislocation-interstitial atoms of silicon) which are an effective radiative recombination centers.

Infrared surface temperature measurements for the surface tension driven convection experiment. M.S. Thesis - Case Western Reserve Univ., Aug. 1988

NASA Technical Reports Server (NTRS)

Pline, Alexander D.

1989-01-01

In support of the Surface Tension Driven Convection Experiment (STDCE), a planned space transportation system (STS) flight experiment, a commercially available infrared thermal imaging system is used to quantify the imposed thermal signature along the free surface. The system was tested and calibrated for the STDCE with ground-based equivalents of the STDCE hardware. Before using the system, consideration was given to the radiation characteristics of the target (silicone oil). Absorption coefficients were calculated to understand the surface depth as seen by the imager and the penetration depth of the surface heater (CO2 laser). The performance and operational specifications for the imager and image processing system are described in detail to provide an understanding of the equipment. Measurements made with the system were compared to thermocouple measurements and a calculated surface temperature distribution. This comparison showed that in certain regions the IR imager measurements were within 5 percent of the overall temperature difference across the free surface. In other regions the measurements were within + or - 10 percent of the overall temperature gradient across the free surface. The effective emissivity of silicone oil for these experimental conditions was also determined. Measurement errors and their possible solutions are discussed.

Thermal Infrared Signatures and Heat Fluxes of Sea Foam

DTIC Science & Technology

2015-01-13

4 air flow 0.5 m 0.5 m MWIR LWIR FTIR Pitot tube and Temperature air diffuser 1 m EO foam IR H20 vapor analyzer Heat...verify this, we measured velocity profiles with a pitot tube over 5 water and foam surfaces spanning our range of tested wind speeds. The profiles (not

Unconventional and conventional quantum criticalities in CeRh0.58Ir0.42In5

NASA Astrophysics Data System (ADS)

Luo, Yongkang; Lu, Xin; Dioguardi, Aadm P.; Rosa, Priscila F. S.; Bauer, Eric D.; Si, Qimiao; Thompson, Joe D.

2018-03-01

An appropriate description of the state of matter that appears as a second order phase transition is tuned toward zero temperature, viz. quantum-critical point (QCP), poses fundamental and still not fully answered questions. Experiments are needed both to test basic conclusions and to guide further refinement of theoretical models. Here, charge and entropy transport properties as well as AC specific heat of the heavy-fermion compound CeRh0.58Ir0.42In5, measured as a function of pressure, reveal two qualitatively different QCPs in a single material driven by a single non-symmetry-breaking tuning parameter. A discontinuous sign-change jump in thermopower suggests an unconventional QCP at pc1 accompanied by an abrupt Fermi-surface reconstruction that is followed by a conventional spin-density-wave critical point at pc2 across which the Fermi surface evolves smoothly to a heavy Fermi-liquid state. These experiments are consistent with some theoretical predictions, including the sequence of critical points and the temperature dependence of the thermopower in their vicinity.

Synthesis and characterization of nano TiO2-SiO2: PVA composite - a novel route

NASA Astrophysics Data System (ADS)

Venckatesh, Rajendran; Balachandaran, Kartha; Sivaraj, Rajeshwari

2012-07-01

A novel, simple, less time consuming and cost-effective sol-gel method has been developed to synthesize nano titania-silica with polyvinyl alcohol (PVA) composite relatively at low temperature in acidic pH. Titania sol is prepared by hydrolysis of titanium tetrachloride and was mixed with silicic acid and tetrahydrofuran mixture. The reaction was carried out under vigorous stirring for 6 h and dried at room temperature with the addition of PVA solution. The resulting powders were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared (FT-IR), UV-visible spectroscopy and thermal techniques. The grain size of the particles was calculated by X-ray diffraction; surface morphology and chemical composition were determined from scanning electron microscopy-energy dispersive spectroscopy; metal oxide stretching was confirmed from FT-IR spectroscopy; bandgap was calculated using UV-visible spectroscopy, and thermal stability of the prepared composite was determined by thermogravimetric/differential thermal analysis. Since TiO2 got agglomerated on the surface of SiO2, effective absorptive sites increase which in turn increase the photocatalytic efficiency of the resulting composite.

Modelling and simulation of heat pipes with TAIThermIR (Conference Presentation)

NASA Astrophysics Data System (ADS)

Winkelmann, Max E.

2016-10-01

Regarding thermal camouflage usually one has to reduce the surface temperature of an object. All vehicles and installations having a combustion engine usually produce a lot of heat with results on hot spots on the surface which are highly conspicuous. Using heat pipes to transfer this heat to another place on the surface more efficiently might be a way to reduce those hotspots and the overall conspicuity. In a first approach, a model for the Software TAIThermIR was developed to test which parameters of the heat pipes are relevant and what effects can be achieved. It will be shown, that the thermal resistivity of contact zones are quite relevant and the thermal coupling of the engine (source of heat) defines if the alteration of the thermal signature is large or not. Furthermore the impact of the use of heat pipes in relation to surface material is discussed. The influence of different weather scenarios on the change of signatures due to the use of heat pipes is of minor relevance and depends on the choice of the surface material. Finally application issues for real systems are discussed.

Constraining the Rheologic Properties of Channelized Basaltic Flows on Earth and Mars

NASA Astrophysics Data System (ADS)

Ramsey, M. S.; Harris, A. J. L.; Crown, D. A.

2015-12-01

Basaltic volcanism is ubiquitous on the terrestrial planets and is the most common form of extrusive activity on Earth, with over half of the world's volcanoes consisting largely of basalt. Recently, new eruptions (or new phases of ongoing eruptions) have occurred at Tolbachik in Russia (2012-2013); Bardarbunga in Iceland (2014); Etna in Italy (2014); and Kilauea in Hawaii (2014-2015) emphasizing both the hazard potential and volumetric production of basaltic activity. Furthermore, new high-resolution data of flows on Arsia Mons volcano (Mars) show very similar features. Therefore, this style of effusive volcanism and especially its surface manifestation (lava flows) warrants continued study both from a fundamental science as well as a hazard mitigation point of view. Monitoring flow propagation direction and velocity are critical in these situations and a number of models have evolved over time focused on heat loss and down-flow topography to predict flow advance. In addition to topography, the dominant (internal) factors controlling flow propagation are the discharge rate combined with cooling and increasing viscosity. However, all these models rely on accurate temperature measurements derived from the cooling glassy surface using infrared (IR) non-contact instruments. New laboratory and field-based studies are attempting to characterize the cooling, formation, and dynamics of basaltic surfaces using IR data. Preliminary results are focused on resolving inconsistencies in the derived flow temperature, composition, texture and silicate structure, which can all impact the surface-leaving heat flux. Improved accuracy in these retrievals increases our ability to constrain and model flow surface and interior temperatures. The impact of this improved accuracy has now been assessed using flow model simulations of active terrestrial and well-preserved Martian flows, Results are improving our understanding of the initial eruption conditions of these channelized basaltic lava flows on both planets.

Modeling of the ITER-like wide-angle infrared thermography view of JET.

PubMed

Aumeunier, M-H; Firdaouss, M; Travère, J-M; Loarer, T; Gauthier, E; Martin, V; Chabaud, D; Humbert, E

2012-10-01

Infrared (IR) thermography systems are mandatory to ensure safe plasma operation in fusion devices. However, IR measurements are made much more complicated in metallic environment because of the spurious contributions of the reflected fluxes. This paper presents a full predictive photonic simulation able to assess accurately the surface temperature measurement with classical IR thermography from a given plasma scenario and by taking into account the optical properties of PFCs materials. This simulation has been carried out the ITER-like wide angle infrared camera view of JET in comparing with experimental data. The consequences and the effects of the low emissivity and the bidirectional reflectivity distribution function used in the model for the metallic PFCs on the contribution of the reflected flux in the analysis are discussed.

Techniques for Transition and Surface Temperature Measurements on Projectiles at Hypersonic Velocities- A Status Report

NASA Technical Reports Server (NTRS)

Wilder, M. C.; Bogdanoff, D. W.

2005-01-01

A research effort to advance techniques for determining transition location and measuring surface temperatures on graphite-tipped projectiles in hypersonic flight in a ballistic range is described. Projectiles were launched at muzzle velocities of approx. 4.7 km/sec into air at pressures of 190-570 Torr. Most launches had maximum pitch and yaw angles of 2.5-5 degrees at pressures of 380 Torr and above and 3-6 degrees at pressures of 190-380 Torr. Arcjet-ablated and machined, bead-blasted projectiles were launched; special cleaning techniques had to be developed for the latter class of projectiles. Improved methods of using helium to remove the radiating gas cap around the projectiles at the locations where ICCD (intensified charge coupled device) camera images were taken are described. Two ICCD cameras with a wavelength sensitivity range of 480-870 nm have been used in this program for several years to obtain images. In the last year, a third camera, with a wavelength sensitivity range of 1.5-5 microns [in the infrared (IR)], has been added. ICCD and IR camera images of hemisphere nose and 70 degree sphere-cone nose projectiles at velocities of 4.0-4.7 km/sec are presented. The ICCD images clearly show a region of steep temperature rise indicative of transition from laminar to turbulent flow. Preliminary temperature data for the graphite projectile noses are presented.

Infrared imaging technology and biological applications.

PubMed

Kastberger, Gerald; Stachl, Reinhold

2003-08-01

Temperature is the most frequently measured physical quantity, second only to time. Infrared (IR) technology has been utilized successfully in astronomy (for a summary,see Hermans-Killam, 2002b) and in industrial and research settings (Gruner, 2002; Madding, 1982, 1989; Wolfe & Zissis, 1993) for decades. However, fairly recent innovations have reduced costs, increased reliability, and resulted in noncontact IR sensors offering mobile, smaller units of measurement (EOI, 2002; Flir, 2000, 2001,2002). The advantages of using IR imaging are (1) rapidity in the millisecond range, facilitating measurement of moving targets, (2) noncontact procedures, allowing measurements of hazardous or physically inaccessible objects, (3) no interference and no energy lost from the target, (4) no risk of contamination, and (5) no mechanical effect on the surface of the object. All these factors have led to IR technology's becoming an area of interest for new kinds of applications and users. In both manufacturing and quality control, temperature plays an important role as an indicator of the condition of a product or a piece of machinery (EOI, 2002; Flir, 2000, 2001, 2002; Raytek, 2002). In medical and veterinary applications, IR thermometry is increasingly used in organ diagnostics, in the evaluation of sports injuries and the progression of therapy, in disease evaluation (e.g, breast cancer, arthritis, and SARS; Flir, 2003), and in injury and inflammation examinations in horses, livestock (Tivey & Banhazi, 2002), and zoo animals (Hermans-Killam, 2002a; Thiesbrummel, 2002). Lastly, physiological expressions of life processes in animals (Kastberger, Winder, & Steindl, 2001; Stabentheiner, Kovac, & Hagmüller, 1995; Stabentheiner, Kovac, & Schmaranzer, 2002; Stabentheiner & Schmarnzer, 1987) and plants (Bermadinger-Stabentheiner & Stabentheiner, 1995) can be monitored. The most recent field in which IR technology has been applied is animal behavior. This article focuses on the practical options for noncontact IR thermometry--in particular, in biological applications.

Gas-phase measurements of combustion interaction with materials for radiation-cooled chambers

NASA Technical Reports Server (NTRS)

Barlow, R. S.; Lucht, R. P.; Jassowski, D. M.; Rosenberg, S. D.

1991-01-01

Foil samples of Ir and Pt are exposed to combustion products in a controlled premixed environment at atmospheric pressure. Electrical heating of the foil samples is used to control the surface temperature and to elevate it above the radiative equilibrium temperature within the test apparatus. Profiles of temperature and OH concentration in the boundary layer adjacent to the specimen surface are measured by laser-induced fluorescence. Measured OH concentrations are significantly higher than equilibrium concentrations calculated for the known mixture ratio and the measured temperature profiles. This result indicates that superequilibrium concentrations of H-atoms and O-atoms are also present in the boundary layer, due to partial equilibrium of the rapid binary reactions of the H2/O2 chemical kinetic system. These experiments are conducted as part of a research program to investigate fundamental aspects of the interaction of combustion gases with advanced high-temperature materials for radiation-cooled thrusters.

Apparatus and method for temperature mapping a turbine component in a high temperature combustion environment

DOEpatents

Baleine, Erwan; Sheldon, Danny M

2014-06-10

Method and system for calibrating a thermal radiance map of a turbine component in a combustion environment. At least one spot (18) of material is disposed on a surface of the component. An infrared (IR) imager (14) is arranged so that the spot is within a field of view of the imager to acquire imaging data of the spot. A processor (30) is configured to process the imaging data to generate a sequence of images as a temperature of the combustion environment is increased. A monitor (42, 44) may be coupled to the processor to monitor the sequence of images of to determine an occurrence of a physical change of the spot as the temperature is increased. A calibration module (46) may be configured to assign a first temperature value to the surface of the turbine component when the occurrence of the physical change of the spot is determined.

About possibility of temperature trace observing on a human skin through clothes by using computer processing of IR image

NASA Astrophysics Data System (ADS)

Trofimov, Vyacheslav A.; Trofimov, Vladislav V.; Shestakov, Ivan L.; Blednov, Roman G.

2017-05-01

One of urgent security problems is a detection of objects placed inside the human body. Obviously, for safety reasons one cannot use X-rays for such object detection widely and often. For this purpose, we propose to use THz camera and IR camera. Below we continue a possibility of IR camera using for a detection of temperature trace on a human body. In contrast to passive THz camera using, the IR camera does not allow to see very pronounced the object under clothing. Of course, this is a big disadvantage for a security problem solution based on the IR camera using. To find possible ways for this disadvantage overcoming we make some experiments with IR camera, produced by FLIR Company and develop novel approach for computer processing of images captured by IR camera. It allows us to increase a temperature resolution of IR camera as well as human year effective susceptibility enhancing. As a consequence of this, a possibility for seeing of a human body temperature changing through clothing appears. We analyze IR images of a person, which drinks water and eats chocolate. We follow a temperature trace on human body skin, caused by changing of temperature inside the human body. Some experiments are made with observing of temperature trace from objects placed behind think overall. Demonstrated results are very important for the detection of forbidden objects, concealed inside the human body, by using non-destructive control without using X-rays.

Performance of the Satellite Test Assistant Robot in JPL's Space Simulation Facility

NASA Technical Reports Server (NTRS)

Mcaffee, Douglas; Long, Mark; Johnson, Ken; Siebes, Georg

1995-01-01

An innovative new telerobotic inspection system called STAR (the Satellite Test Assistant Robot) has been developed to assist engineers as they test new spacecraft designs in simulated space environments. STAR operates inside the ultra-cold, high-vacuum, test chambers and provides engineers seated at a remote Operator Control Station (OCS) with high resolution video and infrared (IR) images of the flight articles under test. STAR was successfully proof tested in JPL's 25-ft (7.6-m) Space Simulation Chamber where temperatures ranged from +85 C to -190 C and vacuum levels reached 5.1 x 10(exp -6) torr. STAR's IR Camera was used to thermally map the entire interior of the chamber for the first time. STAR also made several unexpected and important discoveries about the thermal processes occurring within the chamber. Using a calibrated test fixture arrayed with ten sample spacecraft materials, the IR camera was shown to produce highly accurate surface temperature data. This paper outlines STAR's design and reports on significant results from the thermal vacuum chamber test.

Infrared spectroscopic study of radiation-induced adsorption of n-hexane on a beryllium surface

NASA Astrophysics Data System (ADS)

Gadzhieva, N. N.

2017-07-01

Radiation-stimulated adsorption on a beryllium surface is studied by IR reflection-absorption spectroscopy. It is found that γ-irradiation at room temperature leads to the appearance of n-hexane adsorption centers on a beryllium surface according to molecular and dissociation mechanisms. The kinetics of n-hexane adsorption in a Be- n-hexane system is studied; activated dissociative chemisorption accompanied by formation of beryllium alkyls and surface hydrides is observed at absorbed doses 15 kGy ≤ Vγ ≤ 35 kGy. A possible mechanism of this process is suggested.

The condensation and vaporization behavior of ices containing SO2, H2S, and CO2 - Implications for Io

NASA Astrophysics Data System (ADS)

Sandford, Scott A.; Allamandola, Louis J.

1993-12-01

The present compilation of measurements of the physical and IR spectral properties of ices whose molecular compositions are relevant to the case of Io encompasses ice systems containing SO2, H2S, and CO2. Surface-binding energies used to calculate the residence times of molecules on a surface as a function of temperature furnish crucially important parameters for models attending to the transport of such molecules to the surface of Io. The values thus derived show that SO2 frosts anneal rapidly.

Particle and heat flux estimates in Proto-MPEX in Helicon Mode with IR imaging

NASA Astrophysics Data System (ADS)

Showers, M. A.; Biewer, T. M.; Caughman, J. B. O.; Donovan, D. C.; Goulding, R. H.; Rapp, J.

2016-10-01

The Prototype Material Plasma Exposure eXperiment (Proto-MPEX) at Oak Ridge National Laboratory (ORNL) is a linear plasma device developing the plasma source concept for the Material Plasma Exposure eXperiment (MPEX), which will address plasma material interaction (PMI) science for future fusion reactors. To better understand how and where energy is being lost from the Proto-MPEX plasma during ``helicon mode'' operations, particle and heat fluxes are quantified at multiple locations along the machine length. Relevant diagnostics include infrared (IR) cameras, four double Langmuir probes (LPs), and in-vessel thermocouples (TCs). The IR cameras provide temperature measurements of Proto-MPEX's plasma-facing dump and target plates, located on either end of the machine. The change in surface temperature is measured over the duration of the plasma shot to determine the heat flux hitting the plates. The IR cameras additionally provide 2-D thermal load distribution images of these plates, highlighting Proto-MPEX plasma behaviors, such as hot spots. The LPs and TCs provide additional plasma measurements required to determine particle and heat fluxes. Quantifying axial variations in fluxes will help identify machine operating parameters that will improve Proto-MPEX's performance, increasing its PMI research capabilities. This work was supported by the U.S. D.O.E. contract DE-AC05-00OR22725.

Tropospheric Ozone Near-Nadir-Viewing IR Spectral Sensitivity and Ozone Measurements from NAST-I

NASA Technical Reports Server (NTRS)

Zhou, Daniel K.; Smith, William L.; Larar, Allen M.

2001-01-01

Infrared ozone spectra from near nadir observations have provided atmospheric ozone information from the sensor to the Earth's surface. Simulations of the NPOESS Airborne Sounder Testbed-Interferometer (NAST-I) from the NASA ER-2 aircraft (approximately 20 km altitude) with a spectral resolution of 0.25/cm were used for sensitivity analysis. The spectral sensitivity of ozone retrievals to uncertainties in atmospheric temperature and water vapor is assessed in order to understand the relationship between the IR emissions and the atmospheric state. In addition, ozone spectral radiance sensitivity to its ozone layer densities and radiance weighting functions reveals the limit of the ozone profile retrieval accuracy from NAST-I measurements. Statistical retrievals of ozone with temperature and moisture retrievals from NAST-I spectra have been investigated and the preliminary results from NAST-I field campaigns are presented.

More than Meets the Eye - Infrared Cameras in Open-Ended University Thermodynamics Labs

NASA Astrophysics Data System (ADS)

Melander, Emil; Haglund, Jesper; Weiszflog, Matthias; Andersson, Staffan

2016-12-01

Educational research has found that students have challenges understanding thermal science. Undergraduate physics students have difficulties differentiating basic thermal concepts, such as heat, temperature, and internal energy. Engineering students have been found to have difficulties grasping surface emissivity as a thermal material property. One potential source of students' challenges with thermal science is the lack of opportunity to visualize energy transfer in intuitive ways with traditional measurement equipment. Thermodynamics laboratories have typically depended on point measures of temperature by use of thermometers (detecting heat conduction) or pyrometers (detecting heat radiation). In contrast, thermal imaging by means of an infrared (IR) camera provides a real-time, holistic image. Here we provide some background on IR cameras and their uses in education, and summarize five qualitative investigations that we have used in our courses.

Advances in measuring techniques for turbine cooling test rigs

NASA Technical Reports Server (NTRS)

Pollack, F. G.

1972-01-01

Surface temperature distribution measurements for turbine vanes and blades were obtained by measuring the infrared energy emitted by the airfoil. The IR distribution can be related to temperature distribution by suitable calibration methods and the data presented in the form of isotherm maps. Both IR photographic and real time electro-optical methods are being investigated. The methods can be adapted to rotating as well as stationary targets, and both methods can utilize computer processing. Pressure measurements on rotating components are made with a rotating system incorporating 10 miniature transducers. A mercury wetted slip ring assembly was used to supply excitation power and as a signal transfer device. The system was successfully tested up to speeds of 9000 rpm and is now being adapted to measure rotating blade airflow quantities in a spin rig and a research engine.

Physical and chemical characterizations of biochars derived from different agricultural residues

NASA Astrophysics Data System (ADS)

Jindo, K.; Mizumoto, H.; Sawada, Y.; Sanchez-Monedero, M. A.; Sonoki, T.

2014-08-01

Biochar has received large attention as a strategy to tackle against carbon emission. Not only carbon fixation has been carried out but also other merits for agricultural application due to unique physical and chemical character such as absorption of contaminated compounds in soil, trapping ammonia and methane emission from compost, and enhancement of fertilizer quality. In our study, different local waste feed stocks (rice husk, rice straw, wood chips of apple tree (Malus Pumila) and oak tree (Quercus serrata)), in Aomori, Japan, were utilized for creating biochar with different temperature (400-800 °C). Concerning to the biochar production, the pyrolysis of lower temperature had more biochar yield than higher temperature pyrolysis process. On the contrary, surface areas and adsorption characters have been increased as increasing temperature. The proportions of carbon content in the biochars also increased together with increased temperatures. Infrared-Fourier spectra (FT-IR) and 13C-NMR were used to understand carbon chemical compositions in our biochars, and it was observed that the numbers of the shoulders representing aromatic groups, considered as stable carbon structure appeared as the temperature came closer to 600 °C, as well as in FT-IR. In rice materials, the peak assigned to SiO2, was observed in all biochars (400-800 °C) in FT-IR. We suppose that the pyrolysis at 600 °C creates the most recalcitrant character for carbon sequestration, meanwhile the pyrolysis at 400 °C produces the superior properties as a fertilizer by retaining volatile and easily labile compounds which promotes soil microbial activities.

Direct observation of surface ethyl to ethane interconversion upon C2H4 hydrogenation over Pt/Al2O3 catalyst by time-resolved FT-IR spectroscopy.

PubMed

Wasylenko, Walter; Frei, Heinz

2005-09-08

Time-resolved FT-IR spectra of ethylene hydrogenation over alumina-supported Pt catalyst were recorded at 25 ms resolution in the temperature range of 323-473 K using various H2 concentrations (1 atm total gas pressure). Surface ethyl species (2870 and 1200 cm(-1)) were detected at all temperatures along with the gas-phase ethane product (2954 and 2893 cm(-1)). The CH3CH2Pt growth was instantaneous on the time scale of 25 ms under all experimental conditions. At 323 K, the decay time of surface ethyl (122 +/- 10 ms) coincides with the rise time of ethane (144 +/- 14 ms). This establishes direct kinetic evidence for surface ethyl as the relevant reaction intermediate. Such a direct link between the temporal behavior of an unstable surface intermediate and the final product in a heterogeneous catalytic system has not been demonstrated before. A fraction (25%) of the asymptotic ethane growth at 323 K is prompt, indicating that there are surface ethyl species that react much faster than the majority of the CH3CH2Pt intermediates. The dispersive kinetics is attributed to the varying strength of interaction of the ethyl species with the Pt surface caused by heterogeneity of the surface environment. At 473 K, the majority of ethyl intermediates are hydrogenated prior to the recording of the first time slice (24 ms), and a correspondingly large prompt growth of ethane is observed. The yield and kinetics of the surface ethylidyne are in agreement with the known spectator nature of this species.

Temperature evolution during compaction of pharmaceutical powders.

PubMed

Zavaliangos, Antonios; Galen, Steve; Cunningham, John; Winstead, Denita

2008-08-01

A numerical approach to the prediction of temperature evolution in tablet compaction is presented here. It is based on a coupled thermomechanical finite element analysis and a calibrated Drucker-Prager Cap model. This approach is capable of predicting transient temperatures during compaction, which cannot be assessed by experimental techniques due to inherent test limitations. Model predictions are validated with infrared (IR) temperature measurements of the top tablet surface after ejection and match well with experiments. The dependence of temperature fields on speed and degree of compaction are naturally captured. The estimated transient temperatures are maximum at the end of compaction at the center of the tablet and close to the die wall next to the powder/die interface.

Global inter-comparison of microwave and infrared LST from multiple sensors (AMSR-E, MODIS, SEVIRI, GOES, and MTSAT-2)

NASA Astrophysics Data System (ADS)

Ermida, Sofia L.; Jiménez, Carlos; Prigent, Catherine; Trigo, Isabel F.; DaCamara, Carlos C.

2017-04-01

Land Surface Temperature (LST) is an important diagnostic parameter of land surface conditions. Satellite LST products generally rely on measurements in the thermal infrared (IR) atmospheric window, which only allows clear sky estimates. Microwave (MW) observations can alternatively be used to derive an all-weather LST. Here we present an inter-comparison between LST derived from the Advanced Microwave Scanning Radiometer - Earth observation system (AMSR-E), the MODerate resolution Imaging Spectroradiometer (MODIS) on-board Aqua, the Spinning Enhanced Visible and Infrared Imager (SEVIRI) on-board Meteosat Second Generation (MSG) satellites, the Geostationary Operational Environmental Satellite (GOES) and the Japanese Meteorological Imager (JAMI) on-board the Multifunction Transport SATellite (MTSAT-2). The higher discrepancies between MW and IR products are observed over snow covered areas. MW emissivity is highly variable for snow-covered ground and not always properly accounted for by the climatological emissivity used in the retrieval. There is a conspicuous bias between MODIS and AMSR-E over desert areas, which is most likely related to the underestimation of LST by MODIS as previously reported in other studies. Inter-comparison between all IR and MW retrievals shows that the STD of the differences between MW and IR LST is generally higher than between IR retrievals. However, the biases between MW and IR LST are, in some cases, of the same order as the ones observed among infrared products. In particular, GOES presents a daytime bias with respect to AMSR-E of 0.45 K whereas the bias with respect to MODIS is 0.60 K. Given that AMSR-E can provide LST under cloudy conditions, the use of microwaves, considering simultaneous overpasses with IR, represents an increase of more than 250% of the number of available LST estimates over equatorial regions. With the MW products of a comparable quality to the IR ones, the MW LST is a very powerful complement of the IR estimates.

Surface Structure Dependence of SO 2 Interaction with Ceria Nanocrystals with Well-defined Surface Facets

DOE PAGES

Tumuluri, Uma; Li, Meijun; Cook, Brandon G.; ...

2015-12-02

The effects of the surface structure of ceria (CeO 2) on the nature, strength, and amount of species resulting from SO 2 adsorption were studied using in situ IR and Raman spectroscopies coupled with mass spectrometry, along with first-principles calculations based on density functional theory (DFT). CeO 2 nanocrystals with different morphologies, namely, rods (representing a defective structure), cubes (100 facet), and octahedra (111 facet), were used to represent different CeO 2 surface structures. IR and Raman spectroscopic studies showed that the structure and binding strength of adsorbed species from SO 2 depend on the shape of the CeO 2more » nanocrystals. SO 2 adsorbs mainly as surface sulfites and sulfates at room temperature on CeO 2 rods, cubes, and octahedra that were either oxidatively or reductively pretreated. The formation of sulfites is more evident on CeO 2 octahedra, whereas surface sulfates are more prominent on CeO 2 rods and cubes. This is explained by the increasing reducibility of the surface oxygen in the order octahedra < cubes < rods. Bulk sulfites are also formed during SO 2 adsorption on reduced CeO 2 rods. The formation of surface sulfites and sulfates on CeO 2 cubes is in good agreement with our DFT results of SO 2 interactions with the CeO 2(100) surface. CeO 2 rods desorb SO2 at higher temperatures than cubes and octahedra nanocrystals, but bulk sulfates are formed on CeO 2 rods and cubes after high-temperature desorption whereas only some surface sulfates/sulfites are left on octahedra. This difference is rationalized by the fact that CeO 2 rods have the highest surface basicity and largest amount of defects among the three nanocrystals, so they bind and react with SO 2 strongly and are the most degraded after SO 2 adsorption cycles. The fundamental understanding obtained in this work on the effects of the surface structure and defects on the interaction of SO 2 with CeO 2 provides insights for the design of more sulfur-resistant CeO 2-based catalysts.« less

Maltodextrin: A consummate carrier for spray-drying of xylooligosaccharides.

PubMed

Zhang, Liangqing; Zeng, Xianhai; Fu, Nan; Tang, Xing; Sun, Yong; Lin, Lu

2018-04-01

The aim of this study was to evaluate the influence of spray-drying on the powder qualities and microstructures of prebiotic xylooligosaccharides (XOS). The relationships between glass transition temperature (T g ) and XOS retention, moisture content, drying yield as well as specific surface area under different inlet air temperatures and maltodextrin concentrations were investigated. Antioxidant activity retention, hygroscopicity, color attributes, X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR) of the spray-dried XOS product were also assessed. The results indicated that an increase in inlet air temperature decreased the moisture content, hence the T g value was increased. Higher maltodextrin concentration increased the T g value, and was attributed to the molecular weight increase. The wall deposition was a tendency to occur when the temperature beyond the T g , reduced the drying yield. Higher temperature and wall deposition promoted the decomposition of XOS into monosaccharide. The crust formation rate of droplets and stickiness of microparticles were affected by T g , and hence, influenced the specific surface area. The antioxidant activity retention of XOS exhibited a concentration-dependent behavior. The hygroscopicity of the microparticles could be reduced by both of the low inlet air temperature and high maltodextrin concentration. According to the results of color attributes, XRD and SEM, the particles were colorless and amorphous, and tended to become more spherical and scattered with the addition of maltodextrin. The FT-IR analysis confirmed that no chemical reaction occurred between XOS and agent, which indicated that maltodextrin is a promising carrier for producing bioactive XOS powder. Copyright © 2018 Elsevier Ltd. All rights reserved.

Catalytic behavior of metal catalysts in high-temperature RWGS reaction: In-situ FT-IR experiments and first-principles calculations

PubMed Central

Choi, Sungjun; Sang, Byoung-In; Hong, Jongsup; Yoon, Kyung Joong; Son, Ji-Won; Lee, Jong-Ho; Kim, Byung-Kook; Kim, Hyoungchul

2017-01-01

High-temperature chemical reactions are ubiquitous in (electro) chemical applications designed to meet the growing demands of environmental and energy protection. However, the fundamental understanding and optimization of such reactions are great challenges because they are hampered by the spontaneous, dynamic, and high-temperature conditions. Here, we investigated the roles of metal catalysts (Pd, Ni, Cu, and Ag) in the high-temperature reverse water-gas shift (RWGS) reaction using in-situ surface analyses and density functional theory (DFT) calculations. Catalysts were prepared by the deposition-precipitation method with urea hydrolysis and freeze-drying. Most metals show a maximum catalytic activity during the RWGS reaction (reaching the thermodynamic conversion limit) with formate groups as an intermediate adsorbed species, while Ag metal has limited activity with the carbonate species on its surface. According to DFT calculations, such carbonate groups result from the suppressed dissociation and adsorption of hydrogen on the Ag surface, which is in good agreement with the experimental RWGS results. PMID:28120896

Catalytic behavior of metal catalysts in high-temperature RWGS reaction: In-situ FT-IR experiments and first-principles calculations.

PubMed

Choi, Sungjun; Sang, Byoung-In; Hong, Jongsup; Yoon, Kyung Joong; Son, Ji-Won; Lee, Jong-Ho; Kim, Byung-Kook; Kim, Hyoungchul

2017-01-25

High-temperature chemical reactions are ubiquitous in (electro) chemical applications designed to meet the growing demands of environmental and energy protection. However, the fundamental understanding and optimization of such reactions are great challenges because they are hampered by the spontaneous, dynamic, and high-temperature conditions. Here, we investigated the roles of metal catalysts (Pd, Ni, Cu, and Ag) in the high-temperature reverse water-gas shift (RWGS) reaction using in-situ surface analyses and density functional theory (DFT) calculations. Catalysts were prepared by the deposition-precipitation method with urea hydrolysis and freeze-drying. Most metals show a maximum catalytic activity during the RWGS reaction (reaching the thermodynamic conversion limit) with formate groups as an intermediate adsorbed species, while Ag metal has limited activity with the carbonate species on its surface. According to DFT calculations, such carbonate groups result from the suppressed dissociation and adsorption of hydrogen on the Ag surface, which is in good agreement with the experimental RWGS results.

Design, analysis, and fabrication of oxide-coated iridium/rhenium combustion chambers

NASA Technical Reports Server (NTRS)

Jang, Q.; Tuffias, R. H.; Laferla, R.; Ghoniem, N. M.

1993-01-01

Iridium-coated rhenium (Ir/Re) combustion chambers provide high temperature, oxidation-resistant operation for radiation-cooled liquid-fueled rocket engines. A 22-N (5-lb(sub f)) chamber has been operated for 15 hours at 2200 C (4000 F) using nitrogen tetroxide/monomethyl hydrazine (NTO/MMH) propellant, with negligible internal erosion. The oxidation resistance of these chambers could be further increased by the addition of refractory oxide coatings, providing longer life and/or operation in more oxidizing and higher temperature environments. The oxide coatings would serve as a thermal and diffusion barrier for the iridium coating, lowering the temperature of the iridium layer while also preventing the ingress of oxygen and egress of iridium oxides. This would serve to slow the failure mechanisms of Ir/Re chambers, namely the diffusion of rhenium to the inner surface and the oxidation of iridium. Such protection could extend chamber lifetimes by tens or perhaps hundreds of hours, and allow chamber operation on stoichiometric or higher mixture ratio oxygen/hydrogen (O2/H2) propellant. Extensive thermomechanical, thermochemical, and mass transport modeling was performed as a key material/structure design tool. Based on the results of these analyses, several 22-N oxide-coated Ir/Re chambers were fabricated and delivered to NASA Lewis Research Center for hot-fire testing.

Deuterium trapping in the carbon-silicon co-deposition layers prepared by RF sputtering in D2 atmosphere

NASA Astrophysics Data System (ADS)

Zhang, Hongliang; Zhang, Weiyuan; Su, Ranran; Tu, Hanjun; Shi, Liqun; Hu, Jiansheng

2018-04-01

Deuterated carbon-silicon layers co-deposited on graphite and silicon substrates by radio frequency magnetron sputtering in pure D2 plasma were produced to study deuterium trapping and characteristics of the C-Si layers. The C-Si co-deposited layers were examined by ion beam analysis (IBA), Raman spectroscopy (RS), infrared absorption (IR) spectroscopy, thermal desorption spectroscopy (TDS) and scanning electron microscopy (SEM). It was found that the growth rate of the C-Si co-deposition layer decreased with increasing temperature from 350 K to 800 K, the D concentration and C/Si ratios increased differently on graphite and silicon substrates. TDS shows that D desorption is mainly as D2, HD, HDO, CD4, and C2D4 and release peaks occurred at temperatures of less than 900 K. RS and IR analysis reveal that the structure of the C-Si layers became more disordered with increasing temperatures. Rounded areas of peeling with 1-2 μm diameters were observed on the surface.

Unravelling thermal emissivity spectra of the main minerals on Mercury's surface by comparison with ab initio calculated IR-HT vibrational frequencies

NASA Astrophysics Data System (ADS)

Stangarone, C.; Helbert, J.; Tribaudino, M.; Maturilli, A.; D'Amore, M.; Ferrari, S.; Prencipe, M.

2015-12-01

Spectral signatures of minerals are intimately related to the crystal structure; therefore they may represent a remote sensing model to determine surface composition of planetary bodies, by analysing their spectral reflectance and emission. However, one of the most critical point is data interpretation considering planetary surfaces, as Mercury, where the changes in spectral characteristics are induced by the high temperatures conditions (Helbert et al., 2013). The aim of this work is to interpret the experimental thermal emissivity spectra with an innovative approach: simulating IR spectra of the main mineral families that compose the surface of Mercury, focusing on pyroxenes (Sprague et al., 2002), both at room and high temperature, exploiting the accuracy of ab initio quantum mechanical calculations, by means of CRYSTAL14 code (Dovesi et al., 2014). The simulations will be compared with experimental emissivity measurements of planetary analogue samples at temperature up to 1000K, performed at Planetary Emissivity Laboratory (PEL) by Institute of Planetary Research (DLR, Berlin). Results will be useful to create a theoretical background to interpret HT-IR emissivity spectra that will be collected by the Mercury Radiometer and Thermal Infrared Spectrometer (MERTIS), a spectrometer developed by DLR that will be on board of the ESA BepiColombo Mercury Planetary Orbiter (MPO) scheduled for 2017. The goal is to point out the most interesting spectral features for a geological mapping of Mercury and other rocky bodies, simulating the environmental conditions of the inner planets of Solar System. Dovesi R., Saunders V. R., Roetti C., Orlando R., Zicovich-Wilson C. M., Pascale F., Civalleri B., Doll K., Harrison N. M., Bush I. J., D'Arco P., Llunell M., Causà M. & Noël Y. 2014. CRYSTAL14 User's Manual, University of Torino. Sprague, A. L., Emery, J. P., Donaldson, K. L., Russell, R. W., Lynch, D. K., & Mazuk, A. L. (2002). Mercury: Mid-infrared (3-13.5 μm) observations show heterogeneous composition, presence of intermediate and basic soil types, and pyroxene. Meteoritics & Planetary Science, 37(9), 1255-1268.

HCMM energy budget data as a model input for assessing regions of high potential groundwater pollution

NASA Technical Reports Server (NTRS)

Moore, D. G. (Principal Investigator); Heilman, J.; Beutler, G.

1978-01-01

The author has identified the following significant results. In early April 1978, heavy spring runoff from snowmelt caused significant flooding along a portion of the Big Sioux River Basin in southeastern South Dakota. The flooded area was visible from surrounding areas on a May 15 HCMM IR test image. On May 15, the flood waters had receded but an area of anomalous residual high soil moisture remained. The high soil moisture area was not visible on a HCMM day visible test image of the same scene, or on LANDSAT imagery. To evaluate the effect of water table depth on surface temperatures, thermal scanner data collected on September 5 and 6, 1978 at approximate HCMM overpass times at an altitude of 3650 m were analyzed. Apparent surface temperatures measured by the scanner included emittance contributions from soil surface and the land cover. Results indicated that the shallow water tables produced a damping of the amplitude of the diurnal surface temperature wave.

Recent Advancements in the Infrared Flow Visualization System for the NASA Ames Unitary Plan Wind Tunnels

NASA Technical Reports Server (NTRS)

Garbeff, Theodore J., II; Baerny, Jennifer K.

2017-01-01

The following details recent efforts undertaken at the NASA Ames Unitary Plan wind tunnels to design and deploy an advanced, production-level infrared (IR) flow visualization data system. Highly sensitive IR cameras, coupled with in-line image processing, have enabled the visualization of wind tunnel model surface flow features as they develop in real-time. Boundary layer transition, shock impingement, junction flow, vortex dynamics, and buffet are routinely observed in both transonic and supersonic flow regimes all without the need of dedicated ramps in test section total temperature. Successful measurements have been performed on wing-body sting mounted test articles, semi-span floor mounted aircraft models, and sting mounted launch vehicle configurations. The unique requirements of imaging in production wind tunnel testing has led to advancements in the deployment of advanced IR cameras in a harsh test environment, robust data acquisition storage and workflow, real-time image processing algorithms, and evaluation of optimal surface treatments. The addition of a multi-camera IR flow visualization data system to the Ames UPWT has demonstrated itself to be a valuable analyses tool in the study of new and old aircraft/launch vehicle aerodynamics and has provided new insight for the evaluation of computational techniques.

Field studies in support of Nimbus-E surface composition mapping radiometer

NASA Technical Reports Server (NTRS)

Lyon, R. J. P.; Green, A. A.

1973-01-01

If the outputs of the two channels are spacially registered and combined to generate a third variable which reflects the differences between the two outputs, then this variable can then be redisplayed in image form and its magnitude should be relatable to the silica content of the rocks imaged. Two methods were proposed for generating this third variable, the first is to take the difference in apparent temperature between the two channels and the second is to ratio the voltage outputs of the two channels. The responses of the two channel high resolution surface composition mapping radiometer and the thermal channels of the MSDS scanner were calculated from data recorded with the NASA IR pallet and simulate the output of these systems had they been flying over the same targets as the IR pallet.

Distinct local structure of superconducting Ca10M4As8(Fe2As2)5 (M =Pt ,Ir)

NASA Astrophysics Data System (ADS)

Paris, E.; Wakita, T.; Proux, O.; Yokoya, T.; Kudo, K.; Mitsuoka, D.; Kimura, T.; Fujimura, K.; Nishimoto, N.; Ioka, S.; Nohara, M.; Mizokawa, T.; Saini, N. L.

2017-12-01

We have studied the local structure of superconducting Ca10Pt4As8(Fe2As2)5 (Pt10418) and Ca10Ir4As8(Fe2As2)5 (Ir10418) iron arsenides, showing different transition temperatures (Tc=38 and 16 K, respectively), by polarized Fe K -edge extended x-ray absorption fine-structure measurements. Despite the similar average crystal structures, the local structures of the FeAs4 tetrahedra in the two compounds are found to be very different. The FeAs4 in Pt10418 is close to a regular tetrahedron, while it deviates largely in Ir10418. The Fe-Fe correlations in the two compounds are characterized by similar bond-length characteristics; however, the static disorder in Pt10418 is significantly lower than that in Ir10418. The results suggest that the optimized local structure and reduced disorder are the reasons for higher Tc and well-defined electronic states in Pt10418 unlike Ir10418 showing the coexistence of glassy and normal electrons at the Fermi surface, and hence provide direct evidence of the local-structure-driven optimization of the electronic structure and superconductivity in iron arsenides.

Classifying Multi-Model Wheat Yield Impact Response Surfaces Showing Sensitivity to Temperature and Precipitation Change

NASA Technical Reports Server (NTRS)

Fronzek, Stefan; Pirttioja, Nina; Carter, Timothy R.; Bindi, Marco; Hoffmann, Holger; Palosuo, Taru; Ruiz-Ramos, Margarita; Tao, Fulu; Trnka, Miroslav; Acutis, Marco;

Wire-in-Tube IrOx Architectures: Alternative Label-Free Immunosensor for Amperometric Immunoassay toward α-Fetoprotein.

PubMed

Li, Qingling; Liu, Dali; Xu, Lin; Xing, Ruiqing; Liu, Wei; Sheng, Kuang; Song, Hongwei

2015-10-14

A sensitive, label-free immunosensor based on iridium oxide (IrOx, 0≤x≤2) nanofibers, which were synthesized through a simple one-spinneret electrospinning method, was first developed for immunoassay of the cancer biomarker α-fetoprotein (AFP). The specific wire-in-tube nanostructure could be obtained and the composition of IrOx nanofibers also could be controlled through changing the annealing temperature. The unique structure and properties of IrOx nanofibers obtained at 500 °C not only led to increased electrode surface area and accelerated electron transfer kinetics but also could provide a highly stable matrix for the convenient conjugation of biomolecules together with chitosan (CS). The good electrochemical properties of the IrOx-nanofiber-modified immunosensor allowed one to detect AFP over a wide concentration range from 0.05 to 150 ng/mL, with a detection limit of 20 pg/mL. The proposed immunosensor also has been used to determine AFP in human serum with satisfactory results. The present protocol was shown to be quite promising for clinical screening of cancer biomarkers and point-of-care diagnostics applications.

Sensitive photo-thermal response of graphene oxide for mid-infrared detection

NASA Astrophysics Data System (ADS)

Bae, Jung Jun; Yoon, Jung Hyun; Jeong, Sooyeon; Moon, Byoung Hee; Han, Joong Tark; Jeong, Hee Jin; Lee, Geon-Woong; Hwang, Ha Ryong; Lee, Young Hee; Jeong, Seung Yol; Lim, Seong Chu

2015-09-01

This study characterizes the effects of incident infrared (IR) radiation on the electrical conductivity of graphene oxide (GO) and examines its potential for mid-IR detection. Analysis of the mildly reduced GO (m-GO) transport mechanism near room temperature reveals variable range hopping (VRH) for the conduction of electrons. This VRH behavior causes the m-GO resistance to exhibit a strong temperature dependence, with a large negative temperature coefficient of resistance of approximately -2 to -4% K-1. In addition to this hopping transport, the presence of various oxygen-related functional groups within GO enhances the absorption of IR radiation significantly. These two GO material properties are synergically coupled and provoke a remarkable photothermal effect within this material; specifically, a large resistance drop is exhibited by m-GO in response to the increase in temperature caused by the IR absorption. The m-GO bolometer effect identified in this study is different from that exhibited in vanadium oxides, which require added gold-black films that function as IR absorbers owing to their limited IR absorption capability.This study characterizes the effects of incident infrared (IR) radiation on the electrical conductivity of graphene oxide (GO) and examines its potential for mid-IR detection. Analysis of the mildly reduced GO (m-GO) transport mechanism near room temperature reveals variable range hopping (VRH) for the conduction of electrons. This VRH behavior causes the m-GO resistance to exhibit a strong temperature dependence, with a large negative temperature coefficient of resistance of approximately -2 to -4% K-1. In addition to this hopping transport, the presence of various oxygen-related functional groups within GO enhances the absorption of IR radiation significantly. These two GO material properties are synergically coupled and provoke a remarkable photothermal effect within this material; specifically, a large resistance drop is exhibited by m-GO in response to the increase in temperature caused by the IR absorption. The m-GO bolometer effect identified in this study is different from that exhibited in vanadium oxides, which require added gold-black films that function as IR absorbers owing to their limited IR absorption capability. Electronic supplementary information (ESI) available. See DOI: 10.1039/c5nr04039f

Highly Active Iridium/Iridium Tin/Tin Oxide Heterogeneous Nanoparticles as Alternative Electrocatalysts for the Ethanol Oxidation Reaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Du W.; Su D.; Wang Q.

2011-08-03

Ethanol is a promising fuel for low-temperature direct fuel cell reactions due to its low toxicity, ease of storage and transportation, high-energy density, and availability from biomass. However, the implementation of ethanol fuel cell technology has been hindered by the lack of low-cost, highly active anode catalysts. In this paper, we have studied Iridium (Ir)-based binary catalysts as low-cost alternative electrocatalysts replacing platinum (Pt)-based catalysts for the direct ethanol fuel cell (DEFC) reaction. We report the synthesis of carbon supported Ir{sub 71}Sn{sub 29} catalysts with an average diameter of 2.7 {+-} 0.6 nm through a 'surfactant-free' wet chemistry approach. Themore » complementary characterization techniques, including aberration-corrected scanning transmission electron microscopy equipped with electron energy loss spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy, are used to identify the 'real' heterogeneous structure of Ir{sub 71}Sn{sub 29}/C particles as Ir/Ir-Sn/SnO{sub 2}, which consists of an Ir-rich core and an Ir-Sn alloy shell with SnO{sub 2} present on the surface. The Ir{sub 71}Sn{sub 29}/C heterogeneous catalyst exhibited high electrochemical activity toward the ethanol oxidation reaction compared to the commercial Pt/C (ETEK), PtRu/C (Johnson Matthey) as well as PtSn/C catalysts. Electrochemical measurements and density functional theory calculations demonstrate that the superior electro-activity is directly related to the high degree of Ir-Sn alloy formation as well as the existence of nonalloyed SnO{sub 2} on surface. Our cross-disciplinary work, from novel 'surfactant-free' synthesis of Ir-Sn catalysts, theoretical simulations, and catalytic measurements to the characterizations of 'real' heterogeneous nanostructures, will not only highlight the intriguing structure-property correlations in nanosized catalysts but also have a transformative impact on the commercialization of DEFC technology by replacing Pt with low-cost, highly active Ir-based catalysts.« less

Comparison of IR thermography and thermocouple measurement of heat loss from rabbit pinna.

PubMed

Mohler, F S; Heath, J E

1988-02-01

The temperature of the pinnae of male New Zealand White rabbits was measured by use of infrared thermography. At ambient temperatures of 15, 20, and 25 degrees C, the average pinna temperatures were 23.0, 28.7, and 36.2 degrees C, respectively. From these temperatures, average heat loss from the total pinna surface area was calculated to be 2.8, 3.3, and 4.4 W, respectively. Preoptic temperature changes also affect the vasomotor state of the rabbit. At an ambient temperature of 20 degrees C, cooling the preoptic area of the rabbit by approximately 1 degree C resulted in an average pinna temperature of 26.5 degrees C and a heat loss of 2.4 W. Heating the preoptic area by approximately 1 degree C resulted in an average pinna temperature of 33.5 degrees C and a heat loss of 5.4 W. Finally, pinna temperatures were measured by use of a thermocouple and infrared thermography simultaneously. When the pinnae were vasodilated, the thermocouple measurements were consistently higher than the pinna surface temperatures measured thermographically. When the pinnae were vasoconstricted, the thermocouple measurements were consistently lower than the pinna surface temperatures measured thermographically. The discrepancy between the two methods of measurement is discussed.

Surface Structure Dependence of SO 2 Interaction with Ceria Nanocrystals with Well-Defined Surface Facets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tumuluri, Uma; Li, Meijun; Cook, Brandon G.

2015-12-31

The effects of the surface structure of ceria (CeO2) on the nature, strength, and amount of species resulting from SO2 adsorption were studied using in situ IR and Raman spectroscopies coupled with mass spectrometry, along with first-principles calculations based on density functional theory (DFT). CeO2 nanocrystals with different morphologies, namely, rods (representing a defective structure), cubes (100 facet), and octahedra (111 facet), were used to represent different CeO2 surface structures. IR and Raman spectroscopic studies showed that the structure and binding strength of adsorbed species from SO2 depend on the shape of the CeO2 nanocrystals. SO2 adsorbs mainly as surfacemore » sulfites and sulfates at room temperature on CeO2 rods, cubes, and octahedra that were either oxidatively or reductively pretreated. The formation of sulfites is more evident on CeO2 octahedra, whereas surface sulfates are more prominent on CeO2 rods and cubes. This is explained by the increasing reducibility of the surface oxygen in the order octahedra < cubes < rods. Bulk sulfites are also formed during SO2 adsorption on reduced CeO2 rods. The formation of surface sulfites and sulfates on CeO2 cubes is in good agreement with our DFT results of SO2 interactions with the CeO2(100) surface. CeO2 rods desorb SO2 at higher temperatures than cubes and octahedra nanocrystals, but bulk sulfates are formed on CeO2 rods and cubes after high-temperature desorption whereas only some surface sulfates/sulfites are left on octahedra. This difference is rationalized by the fact that CeO2 rods have the highest surface basicity and largest amount of defects among the three nanocrystals, so they bind and react with SO2 strongly and are the most degraded after SO2 adsorption cycles. The fundamental understanding obtained in this work on the effects of the surface structure and defects on the interaction of SO2 with CeO2 provides insights for the design of more sulfur-resistant CeO2-based catalysts.« less

Detection of Subsurface Material Separation in Shuttle Orbiter Slip-Side Joggle Region of the Wing Leading Edge using Infrared Imaging Data from Arc Jet Tests

NASA Technical Reports Server (NTRS)

Daryabeigi, Kamran; Walker, Sandra P.

2009-01-01

The objective of the present study was to determine whether infrared imaging (IR) surface temperature data obtained during arc-jet tests of Space Shuttle Orbiter s reinforced carbon-carbon (RCC) wing leading edge panel slip-side joggle region could be used to detect presence of subsurface material separation, and if so, to determine when separation occurs during the simulated entry profile. Recent thermostructural studies have indicated thermally induced interlaminar normal stress concentrations at the substrate/coating interface in the curved joggle region can result in local subsurface material separation, with the separation predicted to occur during approach to peak heating during reentry. The present study was an attempt to determine experimentally when subsurface material separations occur. A simplified thermal model of a flat RCC panel with subsurface material separation was developed and used to infer general surface temperature trends due to the presence of subsurface material separation. IR data from previously conducted arc-jet tests on three test specimens were analyzed: one without subsurface material separation either pre or post test, one with pre test separation, and one with separation developing during test. The simplified thermal model trend predictions along with comparison of experimental IR data of the three test specimens were used to successfully infer material separation from the arc-jet test data. Furthermore, for the test specimen that had developed subsurface material separation during the arc-jet tests, the initiation of separation appeared to occur during the ramp up to the peak heating condition, where test specimen temperature went from 2500 to 2800 F.

Electrochemical Dissolution of Iridium and Iridium Oxide Particles in Acidic Media: Transmission Electron Microscopy, Electrochemical Flow Cell Coupled to Inductively Coupled Plasma Mass Spectrometry, and X-ray Absorption Spectroscopy Study.

PubMed

Jovanovič, Primož; Hodnik, Nejc; Ruiz-Zepeda, Francisco; Arčon, Iztok; Jozinović, Barbara; Zorko, Milena; Bele, Marjan; Šala, Martin; Šelih, Vid Simon; Hočevar, Samo; Gaberšček, Miran

2017-09-13

Iridium-based particles, regarded as the most promising proton exchange membrane electrolyzer electrocatalysts, were investigated by transmission electron microscopy and by coupling of an electrochemical flow cell (EFC) with online inductively coupled plasma mass spectrometry. Additionally, studies using a thin-film rotating disc electrode, identical location transmission and scanning electron microscopy, as well as X-ray absorption spectroscopy have been performed. Extremely sensitive online time-and potential-resolved electrochemical dissolution profiles revealed that Ir particles dissolve well below oxygen evolution reaction (OER) potentials, presumably induced by Ir surface oxidation and reduction processes, also referred to as transient dissolution. Overall, thermally prepared rutile-type IrO 2 particles are substantially more stable and less active in comparison to as-prepared metallic and electrochemically pretreated (E-Ir) analogues. Interestingly, under OER-relevant conditions, E-Ir particles exhibit superior stability and activity owing to the altered corrosion mechanism, where the formation of unstable Ir(>IV) species is hindered. Due to the enhanced and lasting OER performance, electrochemically pre-oxidized E-Ir particles may be considered as the electrocatalyst of choice for an improved low-temperature electrochemical hydrogen production device, namely a proton exchange membrane electrolyzer.

Assessment of COSMIC radio occultation and AIRS hyperspectral IR sounder temperature products in the stratosphere using observed radiances

NASA Astrophysics Data System (ADS)

Feltz, M. L.; Knuteson, R. O.; Revercomb, H. E.

2017-08-01

Upper air temperature is defined as an essential climate variable by the World Meteorological Organization. Two remote sensing technologies being promoted for monitoring stratospheric temperatures are GPS radio occultation (RO) and spectrally resolved IR radiances. This study assesses RO and hyperspectral IR sounder derived temperature products within the stratosphere by comparing IR spectra calculated from GPS RO and IR sounder products to coincident IR observed radiances, which are used as a reference standard. RO dry temperatures from the University Corporation for Atmospheric Research (UCAR) Constellation Observing System for Meteorology, Ionosphere, and Climate (COSMIC) mission are compared to NASA Atmospheric Infrared Sounder (AIRS) retrievals using a previously developed profile-to-profile collocation method and vertical temperature averaging kernels. Brightness temperatures (BTs) are calculated for both COSMIC and AIRS temperature products and are then compared to coincident AIRS measurements. The COSMIC calculated minus AIRS measured BTs exceed the estimated 0.5 K measurement uncertainty for the winter time extratropics around 35 hPa. These differences are attributed to seasonal UCAR COSMIC biases. Unphysical vertical oscillations are seen in the AIRS L2 temperature product in austral winter Antarctic regions, and results imply a small AIRS tropical warm bias around 35 hPa in the middle stratosphere.

Modelling free and oxide-supported nanoalloy catalysts: comparison of bulk-immiscible Pd-Ir and Au-Rh systems and influence of a TiO2 support.

PubMed

Demiroglu, Ilker; Fan, Tian-E; Li, Z Y; Yuan, Jun; Liu, Tun-Dong; Piccolo, Laurent; Johnston, Roy L

2018-05-24

The relative stabilities of different chemical arrangements of Pd-Ir and Au-Rh nanoalloys (and their pure metal equivalents) are studied, for a range of compositions, for fcc truncated octahedral 38- and 79-atom nanoparticles (NPs). For the 38-atom NPs, comparisons are made of pure and alloy NPs supported on a TiO2(110) slab. The relative energies of different chemical arrangements are found to be similar for Pd-Ir and Au-Rh nanoalloys, and depend on the cohesive and surface energies of the component metals. For supported nanoalloys on TiO2, the interaction with the surface is greater for Ir (Rh) than Pd (Au): most of the pure NPs and nanoalloys preferentially bind to the TiO2 surface in an edge-on configuration. When Au-Rh nanoalloys are bound to the surface through Au, the surface binding strength is lower than for the pure Au NP, while the Pd-surface interaction is found to be greater for Pd-Ir nanoalloys than for the pure Pd NP. However, alloying leads to very little difference in Ir-surface and Rh-surface binding strength. Comparing the relative stabilities of the TiO2-supported NPs, the results for Pd-Ir and Au-Rh nanoalloys are the same: supported Janus NPs, whose Ir (Rh) atoms bind to the TiO2 surface, bind most strongly to the surface, becoming closer in energy to the core-shell configurations (Ir@Pd and Rh@Au) which are favoured for the free particles.

A comparative study of high-mass cluster forming clumps

NASA Astrophysics Data System (ADS)

López-Sepulcre, A.; Cesaroni, R.; Walmsley, C. M.

2010-07-01

Aims: We have searched for star formation activity (mainly infall and outflow signatures) in a sample of high-mass molecular clumps (M > 100 M⊙) in different evolutionary stages and with a wide range of surface densities, with the aim of looking for evolutionary trends and testing observationally recent theoretical models which predict the need for a minimum surface density to form high-mass stars. Methods: Our sample has been selected from single-dish 1.2 mm continuum surveys and is composed of 48 massive molecular clumps, of which 29 are IR-loud and 19 are IR-dark. Each of these has been mapped in the HCO+(1-0), HCN(1-0) and C18O(2-1) transitions with the IRAM-30 m telescope on Pico Veleta (Spain). We derive basic parameters (mass, momentum, kinetic energy) for the clumps and their associated outflows and examine the HCO+(1-0) line profiles for evidence of infall or expansion. Results: Molecular outflows have been detected in 75% of our targets from the presence of high-velocity wings in the HCO+(1-0) spectra. These are equally frequent and massive (between ~1 and ~100 M⊙) in IR-dark and IR-loud clumps, implying similar levels of star formation activity in both kinds of objects. A surface density threshold at Σ = 0.3 g cm-2 has been found above which the outflow detection rate increases significantly and the outflows are on average more massive. The infall detection rate in our sample is low, but significantly higher in the IR-dark sub-sample. Our clump mass estimates using the mm dust emission and C18O(2-1) are sensitive to the temperature, but assuming a value of 15 K for the IR-dark sub-sample, we find evidence that C18O is depleted by a factor ~4.5. The HCO+(1-0) to HCN(1-0) integrated intensity ratios measured reveal a greater dispersion about the mean value in the IR-dark sub-sample than in the IR-loud by a factor of about 5. We find that a considerable number of IR-dark sources are self-absorbed in HCN(1-0) suggesting that radiative transport effects in the ground state transitions have an important influence on the integrated intensity ratio. Conclusions: Our results indicate that, in terms of outflow frequency and energetics, both IR-dark and IR-loud molecular clumps present equivalent signatures of star formation activity, and that the formation of high-mass stars requires sufficiently high clump surface densities. The higher infall detection rate measured for the IR-dark subsample suggests that these objects could be associated with the onset of star formation. Based on observations carried out with the IRAM 30-m telescope at Pico Veleta (Granada, Spain). IRAM is supported by INSU/CNRS (France), MPG (Germany), and IGN (Spain).Appendices A and B are only available in electronic form at http://www.aanda.org

The Temperature and Structure Dependence of Surface Tension of CaO-SiO2-Na2O-CaF2 Mold Fluxes

NASA Astrophysics Data System (ADS)

Gao, Qiang; Min, Yi; Jiang, Maofa

2018-06-01

The surface tension of mold flux is one of the most important properties and varies with the temperature from the top to the bottom of the mold, which influences the adhesion and lubrication between the liquid mold flux and the solidified shell, further influencing the quality of the continuous billet. In the present paper, the effect of temperature on the surface tension of CaO-SiO2-Na2O-CaF2 mold-flux melts with different CaO/SiO2 mass ratios was investigated using the maximum-pull method. Furthermore, the microstructure of mold fluxes was analyzed using FT-IR and Raman spectra to discuss the change mechanism of surface tension. The results indicated that the temperature dependence of surface tension was different with different CaO/SiO2 mass ratios, and agreed with the modification of melt structure. When the CaO/SiO2 mass ratio was 0.67 and 0.85, the change of surface tension with temperature was relatively stable, and the influence of temperature on the structure was small. When the CaO/SiO2 mass ratio was 1.03 and 1.16, with an increase of temperature, the surface tension decreased linearly and the changing amplitude was large; the degree of polymerization of melts and average radii of silicon-oxygen anions also decreased, which intensified the molecular thermal motion and weakened the intermolecular interaction, resulting in a decrease of surface tension of melts.

The Temperature and Structure Dependence of Surface Tension of CaO-SiO2-Na2O-CaF2 Mold Fluxes

NASA Astrophysics Data System (ADS)

Gao, Qiang; Min, Yi; Jiang, Maofa

2018-02-01

The surface tension of mold flux is one of the most important properties and varies with the temperature from the top to the bottom of the mold, which influences the adhesion and lubrication between the liquid mold flux and the solidified shell, further influencing the quality of the continuous billet. In the present paper, the effect of temperature on the surface tension of CaO-SiO2-Na2O-CaF2 mold-flux melts with different CaO/SiO2 mass ratios was investigated using the maximum-pull method. Furthermore, the microstructure of mold fluxes was analyzed using FT-IR and Raman spectra to discuss the change mechanism of surface tension. The results indicated that the temperature dependence of surface tension was different with different CaO/SiO2 mass ratios, and agreed with the modification of melt structure. When the CaO/SiO2 mass ratio was 0.67 and 0.85, the change of surface tension with temperature was relatively stable, and the influence of temperature on the structure was small. When the CaO/SiO2 mass ratio was 1.03 and 1.16, with an increase of temperature, the surface tension decreased linearly and the changing amplitude was large; the degree of polymerization of melts and average radii of silicon-oxygen anions also decreased, which intensified the molecular thermal motion and weakened the intermolecular interaction, resulting in a decrease of surface tension of melts.

Hurricane Data Analysis Tool

NASA Technical Reports Server (NTRS)

Liu, Zhong; Ostrenga, Dana; Leptoukh, Gregory

2011-01-01

In order to facilitate Earth science data access, the NASA Goddard Earth Sciences Data Information Services Center (GES DISC) has developed a web prototype, the Hurricane Data Analysis Tool (HDAT; URL: http://disc.gsfc.nasa.gov/HDAT), to allow users to conduct online visualization and analysis of several remote sensing and model datasets for educational activities and studies of tropical cyclones and other weather phenomena. With a web browser and few mouse clicks, users can have a full access to terabytes of data and generate 2-D or time-series plots and animation without downloading any software and data. HDAT includes data from the NASA Tropical Rainfall Measuring Mission (TRMM), the NASA Quick Scatterometer(QuikSCAT) and NECP Reanalysis, and the NCEP/CPC half-hourly, 4-km Global (60 N - 60 S) IR Dataset. The GES DISC archives TRMM data. The daily global rainfall product derived from the 3-hourly multi-satellite precipitation product (3B42 V6) is available in HDAT. The TRMM Microwave Imager (TMI) sea surface temperature from the Remote Sensing Systems is in HDAT as well. The NASA QuikSCAT ocean surface wind and the NCEP Reanalysis provide ocean surface and atmospheric conditions, respectively. The global merged IR product, also known as, the NCEP/CPC half-hourly, 4-km Global (60 N -60 S) IR Dataset, is one of TRMM ancillary datasets. They are globally-merged pixel-resolution IR brightness temperature data (equivalent blackbody temperatures), merged from all available geostationary satellites (GOES-8/10, METEOSAT-7/5 & GMS). The GES DISC has collected over 10 years of the data beginning from February of 2000. This high temporal resolution (every 30 minutes) dataset not only provides additional background information to TRMM and other satellite missions, but also allows observing a wide range of meteorological phenomena from space, such as, hurricanes, typhoons, tropical cyclones, mesoscale convection system, etc. Basic functions include selection of area of interest and time, single imagery, overlay of two different products, animation,a time skip capability and different image size outputs. Users can save an animation as a file (animated gif) and import it in other presentation software, such as, Microsoft PowerPoint. Since the tool can directly access the real data, more features and functionality can be added in the future.

Experimental study of IR-signature of water ices between 1 and 2.5 µm : a thermal probe for icy moons

NASA Astrophysics Data System (ADS)

Taffin, C.; Grasset, O.; Le Menn, E.; Le Mouélic, S.

2009-12-01

Near IR signatures of water ices are known to depend on temperature and grain size, a property that could be used to constrain the surface characteristics of icy moons1,2,3. Models indicate that the 1.65 µm absorption band depends strongly on temperature2,4,5 and on grain size. Other bands (1.03, 1.27, 1.50 and 2 µm) show a strong dependence with grain size (e.g. (6) for the 1.03 µm band). But the respective influence of temperature and grain size is still not fully understood. In this work, we focus on the 1.50 and 1.55 µm absorption bands. Characteristics of near-IR spectra of pure ice Ih grains have been experimentally investigated using temperature and pressure ranges relevant for icy moons. Nineteen experiments have been conducted both at microscopic (individual grains smaller than 100 mm) and macroscopic (grains ranging from 200 to 800 µm) scales, using a FTIR spectrometer. Position, area and depth of the four main absorption bands in the near-IR domain (1.50, 1.55, 1.65 and 2 µm) have been studied . It will be shown that the positions of the 1.50 µm and the 1.55 µm bands are very good indicators of grain size and of temperature, respectively (Fig.1). The scaling laws established from experimental data can be used to characterize the surface properties of icy moons. Preliminary tests are conducted on extensively studied regions to validate the approach. An application to the Tiger Stripes on Enceladus will be presented. The estimated temperatures are at first order consistent with those obtained by CIRS7, but they still appear slightly higher in average (between 10 and 20 K). Grain size are also bigger than in a previous model8 but the same tendency is observed, i.e., the grain size is larger on the Tiger Stripes than in the surroundings. Ref. : 1-Fink and Larson, Icarus, 1975. 2-Leto et al. Mem. S.A.It. Suppl. 2005. 3-Grundy, Icarus, 1999. 4-Grundy and Schmitt, JGR. 1998. 5-Mastrapa et al. Icarus, 2008. 6-Nolin and Dozier Rem. Sens. Environ. 2000. 7-Abramov and Spencer, Icarus 2009. 8-Jaumann et al. Icarus, 2007. Figure 1: a) Position of the 1.55 µm band versus temperature for ice (black) and frost (red). For each temperature a dispersion of 10 - 20 cm-1 is observed due to the grain size variations from 200 to 800 µm. b) Position of the 1.50 µm band relative to the grain size at microscopic (black) and macroscopic (red) scales. The grain size of macroscopic samples is estimated using the Nolin and Dozier’s method (6).

Thermal imaging of levitated fresh and salt water drops during laser irradiation

NASA Astrophysics Data System (ADS)

Brownell, Cody; Biggs, Harrison

2017-11-01

Simulation of high energy laser propagation and scattering in the maritime environment is problematic, due to the high likelihood of turbulence, fog, and rain or sea spray within the beam path. Considering large water drops (diameters of approximately 1-mm), such as those found in a light rain, an incident high energy laser will lead to rapid evaporation of the water drop as it traverses the beam path. In this work we present surface temperature measurements of a water drop obtained using a FLIR IR camera. The drop is acoustically levitated, and subject to a continuous wave laser with a wavelength of 1070-nm and a mean irradiance of approximately 800 W/cm2. These measurements show that the steady-state surface temperature of the drop is well below the saturation temperature, and for pure substances the equilibrium temperature decreases with decreasing drop volume similar to observations with smaller aqueous aerosols. Temperature non-uniformity within the drop is also assessed from statistics of the surface temperature fluctuations. Preliminary results from irradiated salt water drops show notably different behavior from fresh water drops, including temperature spikes as the drop volume decreases and occasional nucleate boiling. Acknowledge support from ONR #N00014-17-WX-00031.

Femtosecond-laser surface modification and micropatterning of diamond-like nanocomposite films to control friction on the micro and macroscale

NASA Astrophysics Data System (ADS)

Pimenov, S. M.; Zavedeev, E. V.; Arutyunyan, N. R.; Zilova, O. S.; Shupegin, M. L.; Jaeggi, B.; Neuenschwander, B.

2017-10-01

Laser surface micropatterning (texturing) of hard materials and coatings is an effective technique to improve tribological systems. In the paper, we have investigated the laser-induced surface modifications and micropatterning of diamond-like nanocomposite (DLN) films (a-C:H,Si:O) using IR and visible femtosecond (fs) lasers, focusing on the improvement of frictional properties of laser-patterned films on the micro and macroscale. The IR and visible fs-lasers, operating at λ = 1030 nm and λ = 515 nm wavelengths (pulse duration 320 fs and pulse repetition rate 101 kHz), are used to fabricate different patterns for subsequent friction tests. The IR fs-laser is applied to produce hill-like micropatterns under conditions of surface graphitization and incipient ablation, and the visible fs-laser is used for making microgroove patterns in DLN films under ablation conditions. Regimes of irradiation with low-energy IR laser pulses are chosen to produce graphitized micropatterns. For these regimes, results of numerical calculations of the temperature and graphitized layer growth are presented to show good correlation with surface relief modifications, and the features of fs-laser graphitization are discussed based on Raman spectroscopy analysis. Using lateral force microscopy, the role of surface modifications (graphitization, nanostructuring) in the improved microfriction properties is investigated. New data of the influence of capillary forces on friction forces, which strongly changes the microscale friction behaviour, are presented for a wide range of loads (from nN to μN) applied to Si tips. In macroscopic ball-on-disk tests, a pair-dependent friction behaviour of laser-patterned films is observed. The first experimental data of the improved friction properties of laser-micropatterned DLN films under boundary lubricated sliding conditions are presented. The obtained results show the DLN films as an interesting coating material suitable for laser patterning applications in tribology.

Multi-sensor analysis of urban ecosystems

USGS Publications Warehouse

Gallo, Kevin P.; Ji, Lei

2004-01-01

This study examines the synthesis of multiple space-based sensors to characterize the urban environment Single scene data (e.g., ASTER visible and near-IR surface reflectance, and land surface temperature data), multi-temporal data (e.g., one year of 16-day MODIS and AVHRR vegetation index data), and DMSP-OLS nighttime light data acquired in the early 1990s and 2000 were evaluated for urban ecosystem analysis. The advantages of a multi-sensor approach for the analysis of urban ecosystem processes are discussed.

Analysis of Near-Surface Oceanic Measurements Obtained During the Low-Wind Component of the Coupled Boundary Layers and Air-Sea Transfer (CBLAST) Experiment

DTIC Science & Technology

2006-09-30

temperature and the upwelling IR radiative heat flux were obtained from a pyrometer . The heat fluxes are combined to compute the net heat flux into or out...sampled acoustic Doppler velocimeters (ADVs) and thermistors (Figure 1b). These measurements provide inertial-range estimates of dissipation rates...horizontal velocity at the sea surface were obtained with a “fanbeam” acoustic Doppler current profiler (ADCP), which produces spatial maps of the

Thermo-Mechanical Characterization of Silicon Carbide-Silicon Carbide Composites at Elevated Temperatures Using a Unique Combustion Facility

DTIC Science & Technology

2009-09-10

Calibration Tool(s) Surface Temperature ~1250oC Furnace, R-type TC & IR Gas Temperature < 1800oC R-type TC Gas Velocity ~ Mach 0.5 XS -4 High Speed...Camera Equivalence Ratio ~ 0.9 HVOFTM Flow Controller Gas Composition H 2 O, O 2 ,CO 2 , CO, NOx Testo XL 350 Gas Analyzer Mechanical Loading Fatigue...unavailability, however, gas velocity was measured using the X-StreamTM XS -4 High Speed Camera. The range of our interest was the velocity in the upstream of a

Characterization and 2D structural model of corn straw and poplar leaf biochars.

PubMed

Zhao, Nan; Lv, YiZhong; Yang, XiXiang; Huang, Feng; Yang, JianWen

2017-12-22

The integrated experimental methods were used to analyze the physicochemical properties and structural characteristics and to build the 2D structural model of two kinds of biochars. Corn straw and poplar leaf biochars were gained by pyrolysing the raw materials slowly in a furnace at 300, 500, and 700 °C under oxygen-deficient conditions. Scanning electron microscope was applied to observe the surface morphology of the biochars. High temperatures destroyed the pore structures of the biochars, forming a particle mixture of varying sizes. The ash content, yield, pH, and surface area were also observed to describe the biochars' properties. The yield decreases as the pyrolysis temperature increases. The biochars are neutral to alkaline. The biggest surface area is 251.11 m 2 /g for 700 °C corn straw biochar. Elemental analysis, infrared microspectroscopy, solid-state C-13 NMR spectroscopy, and pyrolysis gas chromatography-mass spectrometry (Py-GC-MS) were also used to study the structural characteristics and build the 2D structural models of biochars. The C content in the corn straw and poplar leaf biochars increases with the increase of the pyrolysis temperature. A higher pyrolysis temperature makes the aryl carbon increase, and C=O, OH, and aliphatic hydrocarbon content decrease in the IR spectra. Solid-state C-13 NMR spectra show that a higher pyrolysis temperature makes the alkyl carbon and alkoxy carbon decrease and the aryl carbon increase. The results of IR microspectra and solid-state C-13 NMR spectra reveal that some noticeable differences exist in these two kinds of biochars and in the same type of biochar but under different pyrolysis temperatures. The conceptual elemental compositions of 500 °C corn straw and poplar leaf biochars are C 61 H 33 NO 13 and C 59 H 41 N 3 O 12 , respectively. Significant differences exist in the SEM images, physicochemical properties, and structural characteristics of corn straw and poplar leaf biochars.

Dissecting the steps of CO2 reduction: 2. The interaction of CO and CO2 with Pd/γ-Al2O3: an in situ FTIR study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Szanyi, Janos; Kwak, Ja Hun

2014-08-07

Alumina supported Pd catalysts with metal loadings of 0.5, 2.5 and 10 wt% were investigated by in situ FTIR spectroscopy in order to understand the nature of adsorbed species formed during their exposure to CO2 and CO. Exposing the annealed samples to CO2 at 295 K resulted in the formation of alumina support-bound surface species only: linear adsorbed CO2, bidentate carbonates and bicarbonates. Room temperature exposure of all three samples to CO produced IR features characteristic of both ionic and metallic Pd, as well as bands we observed upon CO2 adsorption (alumina support-bound species). Low temperature (100 K) adsorption ofmore » CO on the three samples provided information about the state of Pd after oxidation and reduction. Oxidized samples contained exclusively ionic Pd, while mostly metallic Pd was present in the reduced samples. Subsequent annealing of the CO-saturated samples revealed the facile (low temperature) reduction of PdOx species by adsorbed CO. This process was evidenced by the variations in IR bands characteristic of ionic and metallic Pd-bound CO, as well as by the appearance of IR bands associated with CO2 adsorption as a function of annealing temperature. Samples containing oxidized Pd species (oxidized, annealed or reduced) always produced CO2 upon their exposure to CO, while CO2-related surface entities were observed on samples having only fully reduced (metallic) Pd. Acknowledgements: The catalyst preparation was supported by a Laboratory Directed Research and Development (LDRD) project. This work was supported by the US Department of Energy Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy. JHK also acknowledges the support of this work by the 2013 Research Fund of UNIST (Ulsan National Institute of Science and Technology, Ulsan, Korea).« less

Infrared thermography--a non-invasive tool to evaluate thermal status of neonatal pigs based on surface temperature.

PubMed

Kammersgaard, T S; Malmkvist, J; Pedersen, L J

2013-12-01

Hypothermia is a major cause of mortality in neonatal pigs. Infrared (IR) thermography is a promising non-invasive method to assess thermal status, but has not been evaluated for use on neonatal pigs from birth. The aim of this study was to evaluate the application of IR thermography as a non-invasive tool to estimate body temperature and assess the thermal status in newborn pigs by (1) estimating the relationship between surface temperature and rectal temperature (RT) in neonatal pigs; and (2) estimating the influence of air temperature (AT), birth weight and the time from birth on the relationship between surface temperature and RT. The method was evaluated on the basis of 1695 thermograms and 915 RTs on 91 neonatal pigs born in loose farrowing pens with floor heating at 34°C, and three different ATs (15°C, 20°C and 25°C). Full-body thermograms of the back and the side of the pigs and RT were acquired at 11 sampling times between birth and 48 h after birth. The maximum (IRmax), minimum, average of the full body and ear minimum IR surface temperatures were derived from the thermograms. IRmax had the highest correlation with RT (0.82) and was therefore used in the statistical analysis. The relation of RT by IRmax depended on time at: 0 h (slope: 0.20°C, P<0.001), 0.25 h (slope: 0.42°C, P<0.01), and 0.5 and 1 h after birth (slope: 0.68°C, P<0.001). After the 1st hour (1.5 to 48 h) the relation of RT by IRmax was no longer affected by time (slope: 0.63°C, P<0.001). The agreement between RT and IRmax was improved (P<0.001) after the 1st hour (RT-IRmax 0 to 1 h: 2.02 (1.44)°C; 1.5 to 48 h: 0.95 (0.85)°C). IRmax below 30°C was indicative of piglets having RT<32°C (91.3%). The location of IRmax was identified predominantly at the base of the ears (27/50), other sites in the region of the head (12/50) and the axilla area (8/50). There was a small but significant effect of the angle as IRmax_side-IRmax_back: mean 0.20°C (P<0.001). On the basis of the low difference between IRmax from back and side view thermograms, and the location of IRmax, the angle seems less important and thus the method has the potential to be used without the need for manual restraint of the pigs. On the basis of the results of this study, we propose that IRmax temperature from full-body thermograms has implication as a valid tool to assess the thermal status in neonatal piglets but not as an identical substitute for RT.

Surface crystallization behavior and physical properties of (GeTe4)85(AgI)15 chalcogenide glass

NASA Astrophysics Data System (ADS)

Zhu, Erwei; Wu, Bo; Zhao, Xuhao; Wang, Jingsong; Lin, Changgui; Wang, Xunsi; Li, Xing; Tian, Peijing

2017-11-01

Glass-ceramics embedded Te and α-GeTe particles were fabricated from (GeTe4)85(AgI)15 chalcohalide glass using an appropriate heat-treatment at fairly low temperatures ranging from 160 to 190 °C for different times. The crystallization behavior and physical properties of the obtained samples were studied in detail. The glass transition temperature of crystallized samples increases with the elongation of crystallization times. And the results of mechanical properties show that, compared with the base glass, the crystallized samples present improved thermal shock resistance and fracture toughness, and meanwhile still remain its good IR transmittance. This study could provide an initial observation of crystallization in telluride glasses, and be of good guidance to fabricate novel telluride glass-ceramics that operating in far-IR spectral region ranging from 2.5 μm to 25 μm.

Land Surface Temperature Measurements form EOS MODIS Data

NASA Technical Reports Server (NTRS)

Wan, Zhengming

1996-01-01

We have developed a physics-based land-surface temperature (LST) algorithm for simultaneously retrieving surface band-averaged emissivities and temperatures from day/night pairs of MODIS (Moderate Resolution Imaging Spectroradiometer) data in seven thermal infrared bands. The set of 14 nonlinear equations in the algorithm is solved with the statistical regression method and the least-squares fit method. This new LST algorithm was tested with simulated MODIS data for 80 sets of band-averaged emissivities calculated from published spectral data of terrestrial materials in wide ranges of atmospheric and surface temperature conditions. Comprehensive sensitivity and error analysis has been made to evaluate the performance of the new LST algorithm and its dependence on variations in surface emissivity and temperature, upon atmospheric conditions, as well as the noise-equivalent temperature difference (NE(Delta)T) and calibration accuracy specifications of the MODIS instrument. In cases with a systematic calibration error of 0.5%, the standard deviations of errors in retrieved surface daytime and nighttime temperatures fall between 0.4-0.5 K over a wide range of surface temperatures for mid-latitude summer conditions. The standard deviations of errors in retrieved emissivities in bands 31 and 32 (in the 10-12.5 micrometer IR spectral window region) are 0.009, and the maximum error in retrieved LST values falls between 2-3 K. Several issues related to the day/night LST algorithm (uncertainties in the day/night registration and in surface emissivity changes caused by dew occurrence, and the cloud cover) have been investigated. The LST algorithms have been validated with MODIS Airborne Simulator (MAS) dada and ground-based measurement data in two field campaigns conducted in Railroad Valley playa, NV in 1995 and 1996. The MODIS LST version 1 software has been delivered.

Frequency selective infrared sensors

DOEpatents

Davids, Paul; Peters, David W

2014-11-25

A frequency selective infrared (IR) photodetector having a predetermined frequency band. The exemplary frequency selective photodetector includes: a dielectric IR absorber having a first surface and a second surface substantially parallel to the first surface; an electrode electrically coupled to the first surface of the dielectric IR absorber; and a frequency selective surface plasmonic (FSSP) structure formed on the second surface of the dielectric IR absorber. The FSSP structure is designed to selectively transmit radiation in the predetermined frequency band that is incident on the FSSP structure substantially independent of the angle of incidence of the incident radiation on the FSSP structure.

Frequency selective infrared sensors

DOEpatents

Davids, Paul; Peters, David W

2013-05-28

A frequency selective infrared (IR) photodetector having a predetermined frequency band. The exemplary frequency selective photodetector includes: a dielectric IR absorber having a first surface and a second surface substantially parallel to the first surface; an electrode electrically coupled to the first surface of the dielectric IR absorber; and a frequency selective surface plasmonic (FSSP) structure formed on the second surface of the dielectric IR absorber. The FSSP structure is designed to selectively transmit radiation in the predetermined frequency band that is incident on the FSSP structure substantially independent of the angle of incidence of the incident radiation on the FSSP structure.

Delineation of soil temperature regimes from HCMM data

NASA Technical Reports Server (NTRS)

Day, R. L.; Petersen, G. W. (Principal Investigator)

1982-01-01

The subsetting of HCMM data into ORSER format was completed for four dates using a modified SUBSET program. Large areas (approximately 2500 scan lines, 1680 elements) were selected to increase the occurrence of suitable control points for registration. Average daily temperatures (ADT) were calculated for each date. The MERGE program combined registered daytime temperature (DAY-IR) with nighttime temperature (NIGHT-IR) to form a separate two-channel data set. The SUBTRAN program averaged the DAY-IR and NIGHT-IR creating a third ADT channel. Registration equations for the four ADT data sets were generated. A one dimensional soil heat flow equation was modified to allow for mean annual soil temperature predictions using merged ADT data sets.

Non-contact local temperature measurement inside an object using an infrared point detector

NASA Astrophysics Data System (ADS)

Hisaka, Masaki

2017-04-01

Local temperature measurement in deep areas of objects is an important technique in biomedical measurement. We have investigated a non-contact method for measuring temperature inside an object using a point detector for infrared (IR) light. An IR point detector with a pinhole was constructed and the radiant IR light emitted from the local interior of the object is photodetected only at the position of pinhole located in imaging relation. We measured the thermal structure of the filament inside the miniature bulb using the IR point detector, and investigated the temperature dependence at approximately human body temperature using a glass plate positioned in front of the heat source.

Total Defense + Repair: A Novel Concept in Solar Protection and Skin Rejuvenation.

PubMed

McDaniel, David H; Hamzavi, Iltefat H; Zeichner, Joshua A; Fabi, Sabrina G; Bucay, Vivian W; Harper, Julie C; Comstock, Jody A; Makino, Elizabeth T; Mehta, Rahul C; Vega, Virginia L

2015-07-01

For more than a century, solar radiation has been known to contribute significantly to the extrinsic aging of skin. Until recently, this was almost exclusively attributed to the photodamage caused by ultraviolet (UV) light. However, a growing body of evidence now indicates that both infrared (IR) and visible light may also contribute to extrinsic skin aging. Infrared radiation, comprised of IR-A, IR-B, and IR-C, accounts for 54.3% of the total solar radiation reaching the skin. Studies have shown that IR radiation is also responsible for skin aging. Thus, IR-A radiation regulates hundreds of genes in skin, with roles in extracellular matrix (ECM) homeostasis regulation, apoptosis, cell growth, and stress responses. IR-B and IR-C radiation are primarily responsible for the increase in skin temperature associated with solar exposure, and are implicated in heat-related skin destruction of collagen and elastin, which is characterized by an increase in the expression of matrix metalloproteinases (MMPs). The contribution of visible light to photoaging is less well understood; however, some preliminary indication associates visible light with the upregulation of MMPs' expression, DNA damage, and keratinocyte proliferation. Interestingly, the common denominator that links skin damage to the different solar wavelengths is the enhanced production of reactive molecule species (RMS) and therewith increased oxidative stress. SkinMedica® Total Defense + Repair (TD+R; SkinMedica Inc., an Allergan company, Irvine, CA) is a "superscreen," which combines broad spectrum UV protection with a unique blend of antioxidants (SOL-IR Advanced Antioxidant Complex™) that provide protection from IR radiation while promoting skin repair. Preclinical studies have indicated that TD+R SPF34 prevents the formation of UV-induced sunburn cells and cyclobutane pyrimidine dimers while preserving or improving the expression of ECM genes. In addition, it prevents IR-A-triggered fragmentation of elastin fibers and expression of MMP-1. Initial clinical studies indicate that TDR+R SPF34 reduces the increase in surface temperature seen with IR radiation. A significant improvement in the appearance of lines and wrinkles was reported as early as week 2 in patients using TDR+R SPF34. In summary, we observed that the unique blend of antioxidants present in TD+R acts in harmony with SPF active ingredients, expanding solar protection beyond UV radiation and counterbalancing the deleterious effects of free radicals on skin cells by promoting endogenous repair.

Eddy Seeding in the Labrador Sea: a Submerged Autonomous Launching Platform (SALP) Application

NASA Astrophysics Data System (ADS)

Furey, Heather H.; Femke de Jong, M.; Bower, Amy S.

2013-04-01

A simplified Submerged Autonomous Launch Platform (SALP) was used to release profiling floats into warm-core Irminger Rings (IRs) in order to investigate their vertical structure and evolution in the Labrador Sea from September 2007 - September 2009. IRs are thought to play an important role in restratification after convection in the Labrador Sea. The SALP is designed to release surface drifters or subsurface floats serially from a traditional ocean mooring, using real-time ocean measurements as criteria for launch. The original prototype instrument used properties measured at multiple depths, with information relayed to the SALP controller via acoustic modems. In our application, two SALP carousels were attached at 500 meters onto a heavily-instrumented deep water mooring, in the path of recently-shed IRs off the west Greenland shelf. A release algorithm was designed to use temperature and pressure measured at the SALP depth only to release one or two APEX profiling drifters each time an IR passed the mooring, using limited historical observations to set release thresholds. Mechanically and electronically, the SALP worked well: out of eleven releases, there was only one malfunction when a float was caught in the cage after the burn-wire had triggered. However, getting floats trapped in eddies met with limited success due to problems with the release algorithm and float ballasting. Out of seven floats launched from the platform using oceanographic criteria, four were released during warm water events that were not related to passing IRs. Also, after float release, it took on average about 2.6 days for the APEX to adjust from its initial ballast depth, about 600 meters, to its park point of 300 meters, leaving the float below the trapped core of water in the IRs. The other mooring instruments (at depths of 100 to 3000 m), revealed that 12 IRs passed by the mooring in the 2-year monitoring period. With this independent information, we were able to assess and improve the release algorithm, still based on ocean conditions measured only at one depth. We found that much better performance could have been achieved with an algorithm that detected IRs based on a temperature difference from a long-term running mean rather than a fixed temperature threshold. This highlights the challenge of designing an appropriate release strategy with limited a priori information on the amplitude and time scales of the background variability.

Acceptors in bulk and nanoscale ZnO

NASA Astrophysics Data System (ADS)

McCluskey, M. D.

2012-02-01

Zinc oxide (ZnO) is a semiconductor that emits bright UV light, with little wasted heat. This intrinsic feature makes it a promising material for energy-efficient white lighting, nano-lasers, and other optical applications. For devices to be competitive, however, it is necessary to develop reliable p-type doping. Although substitutional nitrogen has been considered as a potential p-type dopant for ZnO, theoretical and experimental work indicates that nitrogen is a deep acceptor and will not lead to p-type conductivity. This talk will highlight recent experiments on ZnO:N at low temperatures. A red/near-IR photoluminescence (PL) band is correlated with the presence of deep nitrogen acceptors. PL excitation (PLE) measurements show an absorption threshold of 2.26 eV, in good agreement with theory. Magnetic resonance experiments provide further evidence for this assignment. The results of these studies seem to rule out group-V elements as shallow acceptors in ZnO, contradicting numerous reports in the literature. If these acceptors do not work as advertised, is there a viable alternative? Optical studies on ZnO nanocrystals show some intriguing leads. At liquid-helium temperatures, a series of sharp IR absorption peaks arise from an unknown acceptor impurity. The data are consistent with a hydrogenic acceptor 0.46 eV above the valence band edge. While this binding energy is still too deep for many practical applications, it represents a significant improvement over the ˜ 1.3 eV binding energy for nitrogen acceptors. Nanocrystals present another twist. Due to their high surface-to-volume ratio, surface states are especially important. Specifically, electron-hole recombination at the surface give rises to a red luminescence band. From our PL and IR experiments, we have developed a ``unified'' model that attempts to explain acceptor and surface states in ZnO nanocrystals. This model could provide a useful framework for designing future nanoscale ZnO devices.

Insulin receptor substrate-2 regulates aerobic glycolysis in mouse mammary tumor cells via glucose transporter 1.

PubMed

Pankratz, Shannon L; Tan, Ernest Y; Fine, Yumiko; Mercurio, Arthur M; Shaw, Leslie M

2009-01-23

The insulin receptor substrate (IRS) proteins are cytoplasmic adaptor molecules that function as signaling intermediates downstream of activated cell surface receptors. Based on data implicating IRS-2 but not IRS-1 in breast cancer invasion, survival, and metastasis, we assessed the contribution of IRS-1 and IRS-2 to aerobic glycolysis, which is known to impact tumor growth and progression. For this purpose, we used tumor cell lines derived from transgenic mice that express the polyoma virus middle T antigen (PyV-MT) in the mammary gland and that are wild-type (WT) or null for either Irs-1 (Irs-1-/-) or Irs-2 (Irs-2-/-). Aerobic glycolysis, as assessed by the rate of lactic acid production and glucose consumption, was diminished significantly in Irs-2-/- cells when compared with WT and Irs-1-/- cells. Expression of exogenous Irs-2 in Irs-2-/- cells restored the rate of glycolysis to that observed in WT cells. The transcription factor FoxO1 does not appear to be involved in Irs-2-mediated glycolysis. However, Irs-2 does regulate the surface expression of glucose transporter 1 (Glut1) as assessed by flow cytometry using a Glut1-specific ligand. Suppression of Glut1 expression inhibits Irs-2-dependent invasion, which links glycolysis to mammary tumor progression. Irs-2 was shown to be important for mammalian target of rapamycin (mTor) activation, and Irs-2-dependent regulation of Glut1 surface expression is rapamycin-sensitive. Collectively, our data indicate that Irs-2, but not Irs-1, promotes invasion by sustaining the aerobic glycolysis of mouse mammary tumor cells and that it does so by regulating the mTor-dependent surface expression of Glut1.

WE-FG-202-01: Early Prediction of Radiotherapy Induced Skin Reactions Using Dynamic Infrared Imaging

DOE Office of Scientific and Technical Information (OSTI.GOV)

Biswal, N; Cifter, G; Sun, J

Purpose: To predict radiotherapy induced skin reactions using dynamic infrared imaging. Methods: Thermal images were captured by our homebuilt system consisting of two flash lamps and an infrared (IR) camera. The surface temperature of the skin was first raised by ∼ 6 oC from ∼1 ms flashes. The camera then captured a series of IR images for 10 seconds. For each image, a baseline skin temperature was recorded for 0.5sec before heat impulse. The temporal temperature gradients were calculated between a reference point (immediately after the flash) and at a time point 9sec after that. Thermal effusivity, an intrinsic thermalmore » property of a material, was calculated from the surface temperature decay of skin. We present experimental data in five patients undergoing radiation therapy, of which 2 were Head & Neck, 1 was Sarcoma and 2 were Breast cancer patients. The prescribed doses were 45 – 60 Gy in 25 – 30 fractions. Each patient was imaged before treatment and after every fifth fraction until end of the treatment course. An area on the skin, outside the radiation field, was imaged as control region. During imaging, each patient’s irradiated skins were scored based on RTOG skin morbidity scoring criteria. Results: Temperature gradient, which is the temperature recovery rate, depends on the thermal properties of underlying tissue. It was observed that, the skin temperature and temporal temperature gradient increases with delivered radiation dose and skin RTOG score. The treatment does not change effusivity of superficial skin layer, however there was a significant difference in effusivity between treated and control areas at depth of ∼ 1.5 – 1.8 mm, increases with dose. Conclusion: The higher temporal temperature gradient and effusivity from irradiated areas suggest that there is more fluid under the irradiated skin, which causes faster temperature recovery. The mentioned effects may be predictors of Moist Desquamation.« less

Nanostructured diamond layers enhance the infrared spectroscopy of biomolecules.

PubMed

Kozak, Halyna; Babchenko, Oleg; Artemenko, Anna; Ukraintsev, Egor; Remes, Zdenek; Rezek, Bohuslav; Kromka, Alexander

2014-03-04

We report on the fabrication and practical use of high-quality optical elements based on Au mirrors coated with diamond layers with flat, nanocolumnar, and nanoporous morphologies. Diamond layers (100 nm thickness) are grown at low temperatures (about 300 °C) from a methane, carbon dioxide, and hydrogen gas mixture by a pulsed microwave plasma system with linear antennas. Using grazing angle reflectance (GAR) Fourier transform infrared spectroscopy with p-polarized light, we compare the IR spectra of fetal bovine serum proteins adsorbed on diamond layers with oxidized (hydrophilic) surfaces. We show that the nanoporous diamond layers provide IR spectra with a signal gain of about 600% and a significantly improved sensitivity limit. This is attributed to its enhanced internal surface area. The improved sensitivity enabled us to distinguish weak infrared absorption peaks of <10-nm-thick protein layers and thereby to analyze the intimate diamond-molecule interface.

3-(Triethoxysilyl)propionitrile sol-gel coating.

PubMed

Li, Ying-Sing; Xiao, Yun; Wright, Paul B; Tran, Tuan

2005-05-01

3-(Triethoxysilyl)propionitrile (TESPN) sol-gel has been prepared under different conditions. It was employed for coating the surfaces of quartz and aluminum. Infrared (IR) and Raman spectra of TESPN and TESPN sol-gels have been recorded in the study of the sol-gel process. Transmission and reflection absorption IR (RAIR) spectra of TESPN sol-gel coated quartz and aluminum have also been collected for better understanding the film formation on the substrate surfaces. Spectra collected at different temperatures indicated that the silane film on quartz decomposes at 700 degrees C. Results from thermal gravimetric analysis (TGA) supported this result. Based on the group frequencies and the spectral behavior in different states, some vibrational modes were assigned to the observed bands. The anticorrosion behavior of the sol-gel coated aluminum in comparison with the uncoated metal was evaluated by measuring the potentiodynamic polarization and electrochemical impedance spectra (EIS).

Passivation effect on optical and electrical properties of molecular beam epitaxy-grown HgCdTe/CdTe/Si layers

NASA Astrophysics Data System (ADS)

Kiran, Rajni; Mallick, Shubhrangshu; Hahn, Suk-Ryong; Lee, T. S.; Sivananthan, Sivalingam; Ghosh, Siddhartha; Wijewarnasuriya, P. S.

2006-06-01

The effects of passivation with two different passivants, ZnS and CdTe, and two different passivation techniques, physical vapor deposition (PVD) and molecular beam epitaxy (MBE), were quantified in terms of the minority carrier lifetime and extracted surface recombination velocity on both MBE-grown medium-wavelength ir (MWIR) and long-wavelength ir HgCdTe samples. A gradual increment of the minority carrier lifetime was reported as the passivation technique was changed from PVD ZnS to PVD CdTe, and finally to MBE CdTe, especially at low temperatures. A corresponding reduction in the extracted surface recombination velocity in the same order was also reported for the first time. Initial data on the 1/ f noise values of as-grown MWIR samples showed a reduction of two orders of noise power after 1200-Å ZnS deposition.

Defense Small Business Innovation Research Program (SBIR) FY 1985.

DTIC Science & Technology

1985-01-31

EO)/ INFRARED (IR) COUNTERMEASURES W CATEGORY: Exploratory Development DESCRIPTION: Analysis needs to be performed to determine how to counter weapon...MHz to 2 GHz. Electrically conducting surfaces of interest are cable shields and braids, and optically transparent (to visible and infrared ) screens...conjunction with a particular method of low temperature depositions from organometallics. 37 .. . -. . . . . . -67 - . ... . 43. TITLE: TUNABLE INFRARED LASER

In Situ FT-IR Spectroscopic Study of CO2 and CO Adsorption on Y2O3, ZrO2, and Yttria-Stabilized ZrO2

PubMed Central

2013-01-01

In situ FT-IR spectroscopy was exploited to study the adsorption of CO2 and CO on commercially available yttria-stabilized ZrO2 (8 mol % Y, YSZ-8), Y2O3, and ZrO2. All three oxides were pretreated at high temperatures (1173 K) in air, which leads to effective dehydroxylation of pure ZrO2. Both Y2O3 and YSZ-8 show a much higher reactivity toward CO and CO2 adsorption than ZrO2 because of more facile rehydroxylation of Y-containing phases. Several different carbonate species have been observed following CO2 adsorption on Y2O3 and YSZ-8, which are much more strongly bound on the former, due to formation of higher-coordinated polydentate carbonate species upon annealing. As the crucial factor governing the formation of carbonates, the presence of reactive (basic) surface hydroxyl groups on Y-centers was identified. Therefore, chemisorption of CO2 most likely includes insertion of the CO2 molecule into a reactive surface hydroxyl group and the subsequent formation of a bicarbonate species. Formate formation following CO adsorption has been observed on all three oxides but is less pronounced on ZrO2 due to effective dehydroxylation of the surface during high-temperature treatment. The latter generally causes suppression of the surface reactivity of ZrO2 samples regarding reactions involving CO or CO2 as reaction intermediates. PMID:24009780

New electrocatalysts for unitized regenerative fuel cell: Pt-Ir alloy deposited on the proton exchange membrane surface by impregnation-reduction method.

PubMed

Wan, Chieh-Hao; Wu, Chun-Lin; Lin, Meng-Tsun; Shih, Chihhsiong

2010-07-01

In this paper, a modified technique to prepare Pt-Ir catalyst layer on the proton exchange membrane (PEM) surface using the impregnation-reduction (IR) method is proposed to improve the electrocatalytic activity as well as the life cycle of the bifunctional oxygen electrode (BOE). The resulted electrocatalysts were characterized by the Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), Electron Probe Micro-Analysis (EPMA), and Transmission Electron Microscope (TEM). The electrocatalytic properties of the Pt-Ir layer on PEM surface for the oxygen reduction and water oxidation reactions as well as the life cycle of MEA were investigated. Experimental results showed that the Ir particles were dispersed densely in the platinum layer through the modified IR technique. The atomic ratio of Pt over Ir elements was 9:1, and the resulted thickness of the obtained Pt-Ir catalyst layer was about 1.0 microm. The Pt-Ir catalyst layer was composed of Pt layer doped with Ir nano-particles comprising nano Pt-Ir alloy phase. The large surface area of Ir core with Pt shell particles and the presence of nano Pt-Ir alloy phase led to a higher electrocatalytic activity of BOE. Due to the good binding between the Nafion membrane and the Pt-Ir alloy catalyst, as well as the composite structure of the resulted Pt-Ir, the life cycle of Unitized Regenerative Fuel Cell (URFC) is improved through this novel BOE.

Drosophila Ionotropic Receptor 25a mediates circadian clock resetting by temperature.

PubMed

Chen, Chenghao; Buhl, Edgar; Xu, Min; Croset, Vincent; Rees, Johanna S; Lilley, Kathryn S; Benton, Richard; Hodge, James J L; Stanewsky, Ralf

2015-11-26

Circadian clocks are endogenous timers adjusting behaviour and physiology with the solar day. Synchronized circadian clocks improve fitness and are crucial for our physical and mental well-being. Visual and non-visual photoreceptors are responsible for synchronizing circadian clocks to light, but clock-resetting is also achieved by alternating day and night temperatures with only 2-4 °C difference. This temperature sensitivity is remarkable considering that the circadian clock period (~24 h) is largely independent of surrounding ambient temperatures. Here we show that Drosophila Ionotropic Receptor 25a (IR25a) is required for behavioural synchronization to low-amplitude temperature cycles. This channel is expressed in sensory neurons of internal stretch receptors previously implicated in temperature synchronization of the circadian clock. IR25a is required for temperature-synchronized clock protein oscillations in subsets of central clock neurons. Extracellular leg nerve recordings reveal temperature- and IR25a-dependent sensory responses, and IR25a misexpression confers temperature-dependent firing of heterologous neurons. We propose that IR25a is part of an input pathway to the circadian clock that detects small temperature differences. This pathway operates in the absence of known 'hot' and 'cold' sensors in the Drosophila antenna, revealing the existence of novel periphery-to-brain temperature signalling channels.

Hydrogen storage and evolution catalysed by metal hydride complexes.

PubMed

Fukuzumi, Shunichi; Suenobu, Tomoyoshi

2013-01-07

The storage and evolution of hydrogen are catalysed by appropriate metal hydride complexes. Hydrogenation of carbon dioxide by hydrogen is catalysed by a [C,N] cyclometalated organoiridium complex, [Ir(III)(Cp*)(4-(1H-pyrazol-1-yl-κN(2))benzoic acid-κC(3))(OH(2))](2)SO(4) [Ir-OH(2)](2)SO(4), under atmospheric pressure of H(2) and CO(2) in weakly basic water (pH 7.5) at room temperature. The reverse reaction, i.e., hydrogen evolution from formate, is also catalysed by [Ir-OH(2)](+) in acidic water (pH 2.8) at room temperature. Thus, interconversion between hydrogen and formic acid in water at ambient temperature and pressure has been achieved by using [Ir-OH(2)](+) as an efficient catalyst in both directions depending on pH. The Ir complex [Ir-OH(2)](+) also catalyses regioselective hydrogenation of the oxidised form of β-nicotinamide adenine dinucleotide (NAD(+)) to produce the 1,4-reduced form (NADH) under atmospheric pressure of H(2) at room temperature in weakly basic water. In weakly acidic water, the complex [Ir-OH(2)](+) also catalyses the reverse reaction, i.e., hydrogen evolution from NADH to produce NAD(+) at room temperature. Thus, interconversion between NADH (and H(+)) and NAD(+) (and H(2)) has also been achieved by using [Ir-OH(2)](+) as an efficient catalyst and by changing pH. The iridium hydride complex formed by the reduction of [Ir-OH(2)](+) by H(2) and NADH is responsible for the hydrogen evolution. Photoirradiation (λ > 330 nm) of an aqueous solution of the Ir-hydride complex produced by the reduction of [Ir-OH(2)](+) with alcohols resulted in the quantitative conversion to a unique [C,C] cyclometalated Ir-hydride complex, which can catalyse hydrogen evolution from alcohols in a basic aqueous solution (pH 11.9). The catalytic mechanisms of the hydrogen storage and evolution are discussed by focusing on the reactivity of Ir-hydride complexes.

The thermal decomposition of fine-grained micrometeorites, observations from mid-IR spectroscopy

NASA Astrophysics Data System (ADS)

Suttle, Martin David; Genge, Matthew J.; Folco, Luigi; Russell, Sara S.

2017-06-01

We analysed 44 fine-grained and scoriaceous micrometeorites. A bulk mid-IR spectrum (8-13 μm) for each grain was collected and the entire micrometeorite population classified into 5 spectral groups, based on the positions of their absorption bands. Corresponding carbonaceous Raman spectra, textural observations from SEM-BSE and bulk geochemical data via EMPA were collected to aid in the interpretation of mid-IR spectra. The 5 spectral groups identified correspond to progressive thermal decomposition. Unheated hydrated chondritic matrix, composed predominantly of phyllosilicates, exhibit smooth, asymmetric spectra with a peak at ∼10 μm. Thermal decomposition of sheet silicates evolves through dehydration, dehydroxylation, annealing and finally by the onset of partial melting. Both CI-like and CM-like micrometeorites are shown to pass through the same decomposition stages and produce similar mid-IR spectra. Using known temperature thresholds for each decomposition stage it is possible to assign a peak temperature range to a given micrometeorite. Since the temperature thresholds for decomposition reactions are defined by the phyllosilicate species and the cation composition and that these variables are markedly different between CM and CI classes, atmospheric entry should bias the dust flux to favour the survival of CI-like grains, whilst preferentially melting most CM-like dust. However, this hypothesis is inconsistent with empirical observations and instead requires that the source ratio of CI:CM dust is heavily skewed in favour of CM material. In addition, a small population of anomalous grains are identified whose carbonaceous and petrographic characteristics suggest in-space heating and dehydroxylation have occurred. These grains may therefore represent regolith micrometeorites derived from the surface of C-type asteroids. Since the spectroscopic signatures of dehydroxylates are distinctive, i.e. characterised by a reflectance peak at 9.0-9.5 μm, and since the surfaces of C-type asteroids are expected to be heated via impact gardening, we suggest that future spectroscopic investigations should attempt to identify dehydroxylate signatures in the reflectance spectra of young carbonaceous asteroid families.

Laboratory Studies of Solid Carbon Dioxide in Planetary and Interstellar Ices

NASA Technical Reports Server (NTRS)

White, Douglas; Sandford, Scott A.; Mastrapa, Rachel M.

2012-01-01

Laboratory spectra have shown that CO2. is a powerful diagnostic tool for analyzing infrared data from remote observations, as it has been detected on icy moons in the outer solar system as well as dust grain surfaces in the interstellar medium. IR absorption profiles of CO2 wi thin ice mixtures containing H2O and CH30H change with respect to tem perature and mixture ratios. In this particular study, the CO2 stretch mode around 235O cm (exp -1) (4.3 rricrons) is systematically observ ed in different mixtures with H2O and CH30H in temperature ranges from 15K to 150 K, as well as vibrational modes in the near-IR such as th e combination bands near 3700 cm (exp -1) (2.7 microns) and 5080 (exp -1) (2.0 microns). Additionally, some high?temperature deposits (T > 50 K) of H2O, CH30H, and CO2 ice mixtures were performed to determine the maximum temperatures at which CO2 will deposit on the sample win dow. These data may then be used to interpret spectra obtained from remote IR observations. This research was sponsored by Oak Ridge Associ ated Universities (ORAU) through the NASA Postdoctoral Program (NPP) as well as Ames Research Center and the SETI institute who provided fa cilities and equipment.

Control of composition and crystallinity in hydroxyapatite films deposited by electron cyclotron resonance plasma sputtering

NASA Astrophysics Data System (ADS)

Akazawa, Housei; Ueno, Yuko

2014-01-01

Hydroxyapatite (HAp) films were deposited by electron cyclotron resonance plasma sputtering under a simultaneous flow of H2O vapor gas. Crystallization during sputter-deposition at elevated temperatures and solid-phase crystallization of amorphous films were compared in terms of film properties. When HAp films were deposited with Ar sputtering gas at temperatures above 460 °C, CaO byproducts precipitated with HAp crystallites. Using Xe instead of Ar resolved the compositional problem, yielding a single HAp phase. Preferentially c-axis-oriented HAp films were obtained at substrate temperatures between 460 and 500 °C and H2O pressures higher than 1×10-2 Pa. The absorption signal of the asymmetric stretching mode of the PO43- unit (ν3) in the Fourier-transform infrared absorption (FT-IR) spectra was the narrowest for films as-crystallized during deposition with Xe, but widest for solid-phase crystallized films. While the symmetric stretching mode of PO43- (ν1) is theoretically IR-inactive, this signal emerged in the FT-IR spectra of solid-phase crystallized films, but was absent for as-crystallized films, indicating superior crystallinity for the latter. The Raman scattering signal corresponding to ν1 PO43- sensitively reflected this crystallinity. The surface hardness of as-crystallized films evaluated by a pencil hardness test was higher than that of solid-phase crystallized films.

Determining the infrared radiative effects of Saharan dust: a radiative transfer modelling study based on vertically resolved measurements at Lampedusa

NASA Astrophysics Data System (ADS)

Meloni, Daniela; di Sarra, Alcide; Brogniez, Gérard; Denjean, Cyrielle; De Silvestri, Lorenzo; Di Iorio, Tatiana; Formenti, Paola; Gómez-Amo, José L.; Gröbner, Julian; Kouremeti, Natalia; Liuzzi, Giuliano; Mallet, Marc; Pace, Giandomenico; Sferlazzo, Damiano M.

2018-03-01

Detailed measurements of radiation, atmospheric and aerosol properties were carried out in summer 2013 during the Aerosol Direct Radiative Impact on the regional climate in the MEDiterranean region (ADRIMED) campaign in the framework of the Chemistry-Aerosol Mediterranean Experiment (ChArMEx) experiment. This study focusses on the characterization of infrared (IR) optical properties and direct radiative effects of mineral dust, based on three vertical profiles of atmospheric and aerosol properties and IR broadband and narrowband radiation from airborne measurements, made in conjunction with radiosonde and ground-based observations at Lampedusa, in the central Mediterranean. Satellite IR spectra from the Infrared Atmospheric Sounder Interferometer (IASI) are also included in the analysis. The atmospheric and aerosol properties are used as input to a radiative transfer model, and various IR radiation parameters (upward and downward irradiance, nadir and zenith brightness temperature at different altitudes) are calculated and compared with observations. The model calculations are made for different sets of dust particle size distribution (PSD) and refractive index (RI), derived from observations and from the literature. The main results of the analysis are that the IR dust radiative forcing is non-negligible and strongly depends on PSD and RI. When calculations are made using the in situ measured size distribution, it is possible to identify the refractive index that produces the best match with observed IR irradiances and brightness temperatures (BTs). The most appropriate refractive indices correspond to those determined from independent measurements of mineral dust aerosols from the source regions (Tunisia, Algeria, Morocco) of dust transported over Lampedusa, suggesting that differences in the source properties should be taken into account. With the in situ size distribution and the most appropriate refractive index the estimated dust IR radiative forcing efficiency is +23.7 W m-2 at the surface, -7.9 W m-2 within the atmosphere, and +15.8 W m-2 at the top of the atmosphere. The use of column-integrated dust PSD from AERONET may also produce a good agreement with measured irradiances and BTs, but with significantly different values of the RI. This implies large differences, up to a factor of 2.5 at surface, in the estimated dust radiative forcing, and in the IR heating rate. This study shows that spectrally resolved measurements of BTs are important to better constrain the dust IR optical properties, and to obtain a reliable estimate of its radiative effects. Efforts should be directed at obtaining an improved description of the dust size distribution and its vertical distribution, as well as at including regionally resolved optical properties.

Mid- and far-infrared spectroscopic studies of the influence of temperature, ultraviolet photolysis and ion irradiation on cosmic-type ices.

PubMed

Moore, M H; Hudson, R L; Gerakines, P A

2001-03-15

Infrared (IR) studies of laboratory ices can provide information on the evolution of cosmic-type ices as a function of different simulated space environments involving thermal, ultraviolet (UV), or ion processing. Laboratory radiation experiments can lead to the formation of complex organic molecules. However, because of our lack of knowledge about UV photon and ion fluxes, and exposure lifetimes, it is not certain how well our simulations represent space conditions. Appropriate laboratory experiments are also limited by the absence of knowledge about the composition, density, and temperature of ices in different regions of space. Our current understanding of expected doses due to UV photons and cosmic rays is summarized here, along with an inventory of condensed-phase molecules identified on outer solar system surfaces, comets and interstellar grains. Far-IR spectra of thermally cycled H2O are discussed since these results reflect the dramatic difference between the amorphous and crystalline phases of H2O ice, the most dominant condensed-phase molecule in cosmic ices. A comparison of mid-IR spectra of products in proton-irradiated and UV-photolyzed ices shows that few differences are observed for these two forms of processing for the simple binary mixtures studied to date. IR identification of radiation products and experiments to determine production rates of new molecules in ices during processing are discussed. A new technique for measuring intrinsic IR band strengths of several unstable molecules is presented. An example of our laboratory results applied to Europa observations is included.

IR Spectra of (HCOOH)2 and (DCOOH)2: Experiment, VSCF/VCI, and Ab Initio Molecular Dynamics Calculations Using Full-Dimensional Potential and Dipole Moment Surfaces.

PubMed

Qu, Chen; Bowman, Joel M

2018-05-17

We report quantum VSCF/VCI and ab initio molecular dynamics (AIMD) calculations of the IR spectra of (HCOOH) 2 and (DCOOH) 2 , using full-dimensional, ab initio potential energy and dipole moment surfaces (PES and DMS). These surfaces are fits, using permutationally invariant polynomials, to 13 475 ab initio CCSD(T)-F12a electronic energies and MP2 dipole moments. Here "AIMD" means using these ab initio potential and dipole moment surfaces in the MD calculations. The VSCF/VCI calculations use all (24) normal modes for coupling, with a four-mode representation of the potential. The quantum spectra align well with jet-cooled and room-temperature experimental spectra over the spectral range 600-3600 cm -1 . Analyses of the complex O-H and C-H stretch bands are made based on the mixing of the VSCF/VCI basis functions. The comparisons of the AIMD IR spectra with both experimental and VSCF/VCI ones provide tests of the accuracy of the AIMD approach. These indicate good accuracy for simple bands but not for the complex O-H stretch band, which is upshifted from experimental and VSCF/VCI bands by roughly 300 cm -1 . In addition to testing the AIMD approach, the PES, DMS, and VSCF/VCI calculations for formic acid dimer provide opportunities for testing other methods to represent high-dimensional data and other methods that perform postharmonic vibrational calculations.

Characterization of Platinum and Iridium Oxyhydrate Surface Layers from Platinum and Iridium Foils.

PubMed

Johnson, Benjamin; Ranjan, Chinmoy; Greiner, Mark; Arrigo, Rosa; Schuster, Manfred Erwin; Höpfner, Britta; Gorgoi, Mihaela; Lauermann, Iver; Willinger, Marc; Knop-Gericke, Axel; Schlögl, Robert

2016-07-07

Platinum and iridium polycrystalline foils were oxidized electrochemically through anodization to create thin platinum and iridium hydrous oxide layers, which were analyzed through laboratory photoelectron spectroscopy during heating and time series (temperature-programmed spectroscopy). The films contain oxygen in the form of bound oxides, water, and hydroxides and were investigated by depth profiling with high-energy photoelectron spectroscopy. The Pt films are unstable and begin to degrade immediately after removal from the electrolyte to form core-shell structures with a metallic inner core and a hydrous oxide outer shell almost devoid of Pt. However, evidence was found for metastable intermediate states of degradation; therefore, it may be possible to manufacture PtOx phases with increased stability. Heating the film to even 100 °C causes accelerated degradation, which shows that stoichiometric oxides such as PtO2 or PtO are not the active species in the electrolyte. The Ir films exhibit increased stability and higher surface Ir content, and gentle heating at low temperatures leads to a decrease in defect density. Although both layers are based on noble metals, their surface structures are markedly different. The complexity of such hydrous oxide systems is discussed in detail with the goal of identifying the film composition more precisely. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Investigation of thermal effects of infrared lasers on the rabbit retina: a study in the course of development of an active subretinal prosthesis.

PubMed

Sailer, Heiko; Shinoda, Kei; Blatsios, Georgios; Kohler, Konrad; Bondzio, Lars; Zrenner, Eberhart; Gekeler, Florian

2007-08-01

Retinal implants are intended to replace photoreceptors in patients suffering from degenerative retinal diseases such as retinitis pigmentosa. Data show that photodiodes in subretinal implants are not powerful enough to stimulate overlying retinal tissue by simply transforming light energy into electrical energy. Therefore, infrared (IR) irradiation has been envisioned to supply additional energy. While epiretinal implants mostly use induction coils for wireless energy transfer, IR irradiation seems to be an additional option. This study investigated the feasibility of an IR energy supply for an active subretinal implant by assessing thermal effects of IR irradiation onto the rabbit retina. Polyimide foil strips carrying an optical sensor as well as a thermal sensor were implanted into the subretinal space of the eyes of nine rabbits using a transchoroidal surgical approach. The area of the thermal sensor was irradiated by an IR laser (830 nm) focused on the device. The sensor provided simultaneous real-time measurements of absolute temperature and irradiation density, allowing direct correlation of the temperature increase to different intensities of IR irradiation. Possible IR-related damage to the retina was examined in histological sections. Temperature changes in living and dead animals were evaluated as a function of IR irradiation power of between 0.1 mW and 40 mW (0.03 mW/mm2-12.7 mW/mm2). We found an exponential relationship between IR irradiation power and temperature increase over the whole range (up to 12.7 mW/mm2) in the living animal. The maximum temperature increase caused by IR irradiation of 40 mW (12.7 mW/mm2) was 4.5 degrees C. The ratio of temperature increase to IR irradiation density postmortem (i.e., without ocular blood flow) was linear over the whole range, with 1.15 degrees C per 1 mW/mm2. Thus, the cooling effect of ocular blood flow varied depending on IR irradiance density. In histological sections, no IR-induced damage to the retina was detected. A temperature increase of 3.2 degrees C in the living rabbit eye is to be expected when powering a subretinal implant with 15 mW (4.8 mW/mm2) IR power, the wattage used in an external power supply for an active implant with 1,500 electrodes. This appears to be a tolerable increase for ocular tissue.

Optical effect of the contamination of infrared windows by the outgassing of materials in outer space

NASA Technical Reports Server (NTRS)

Silberman, E.

1975-01-01

The composition and evaporation rate of the outgassing of a space vehicle thermal control paint as a function of temperature were studied. A contamination chamber was designed, constructed, and tested. Samples of thermal control paint were tested to determine if heating to moderate temperatures causes them to release outgassing products which can be collected on a cooled cesium iodide window for identification by IR analysis. Results showed that outgassing of surfaces other than the sample was a problem. Spectral bands of the deposits collected were compared.

Hydrogen Doping into MoO3 Supports toward Modulated Metal-Support Interactions and Efficient Furfural Hydrogenation on Iridium Nanocatalysts.

PubMed

Xie, Lifang; Chen, Ting; Chan, Hang Cheong; Shu, Yijin; Gao, Qingsheng

2018-03-16

As promising supports, reducible metal oxides afford strong metal-support interactions to achieve efficient catalysis, which relies on their band states and surface stoichiometry. In this study, in situ and controlled hydrogen doping (H doping) by means of H 2 spillover was employed to engineer the metal-support interactions in hydrogenated MoO x -supported Ir (Ir/H-MoO x ) catalysts and thus promote furfural hydrogenation to furfuryl alcohol. By easily varying the reduction temperature, the resulting H doping in a controlled manner tailors low-valence Mo species (Mo 5+ and Mo 4+ ) on H-MoO x supports, thereby promoting charge redistribution on Ir and H-MoO x interfaces. This further leads to clear differences in H 2 chemisorption on Ir, which illustrates its potential for catalytic hydrogenation. As expected, the optimal Ir/H-MoO x with controlled H doping afforded high activity (turnover frequency: 4.62 min -1 ) and selectivity (>99 %) in furfural hydrogenation under mild conditions (T=30 °C, PH2 =2 MPa), which means it performs among the best of current catalysts. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Theoretical study of cathode surfaces and high-temperature superconductors

NASA Technical Reports Server (NTRS)

Mueller, Wolfgang

1995-01-01

Calculations are presented for the work functions of BaO on W, Os, Pt, and alloys of Re-W, Os-W, and Ir-W that are in excellent agreement with experiment. The observed emission enhancement for alloy relative to tungsten dispenser cathodes is attributed to properties of the substrate crystal structure and explained by the smaller depolarization of the surface dipole on hexagonal as compared to cubic substrates. For Ba and BaO on W(100), the geometry of the adsorbates has been determined by a comparison of inverse photoemission spectra with calculated densities of unoccupied states based on the fully relativistic embedded cluster approach. Results are also discussed for models of scandate cathodes and the electronic structure of oxygen on W(100) at room and elevated temperatures. A detailed comparison is made for the surface electronic structure of the high-temperature superconductor YBa2Cu3O7 as obtained with non-, quasi-, and fully relativistic cluster calculations.

Chemical characterization of solid polymer electrolyte membrane surfaces in LiFePO4 half-cells

NASA Astrophysics Data System (ADS)

Kyu, Thein; He, Ruixuan; Peng, Fang; Dunn, William E.; Kyu's Group Team, Dr.

High temperature (60 °C) capacity retention of succinonitrile plasticized solid polymer electrolyte membrane (PEM) in a LiFePO4 half-cell was investigated with or without lithium bis(oxalato)borate (LiBOB) modification. Various symmetric cells and half-cells were studied under different thermal and electrochemical conditions. At room temperature cycling, the unmodified PEM in the half-cell appeared stable up to 50 cycles tested. Upon cycling at 60 °C, the capacity decays rapidly and concurrently the cell resistance increased. The chemical compositions of the solid PEM surfaces on both cathode and anode sides were analyzed. New IR bands (including those belonged to amide) were discerned on the unmodified PEM surface of the Li electrode side at 60 °C suggestive of side reaction, but no new bands develop during room temperature cycling. To our astonishment, the side reaction was effectively suppressed upon LiBOB addition (0.4 wt%) into the PEM, contributing to increased high temperature capacity retention at 60°C. Plausible mechanisms of capacity fading and improved cycling performance due to LiBOB modification are discussed.

Electron dynamics and prompt ablation of aluminum surface excited by intense femtosecond laser pulse

NASA Astrophysics Data System (ADS)

Ionin, A. A.; Kudryashov, S. I.; Makarov, S. V.; Seleznev, L. V.; Sinitsyn, D. V.

2014-12-01

Thin aluminum film homogeneously heated by intense IR femtosecond laser pulses exhibits on the excitation timescale consequent fluence-dependent rise and drop of the IR-pump self-reflectivity, followed by its final saturation at higher fluences F > 0.3 J/cm2. This prompt optical dynamics correlates with the initial monotonic increase in the accompanying laser-induced electron emission, which is succeeded by its non-linear (three-photon) increase for F > 0.3 J/cm2. The underlying electronic dynamics is related to the initial saturation of IR resonant interband transitions in this material, followed by its strong instantaneous electronic heating via intraband transitions during the pump pulse resulting in thermionic emission. Above the threshold fluence of 0.3 J/cm2, the surface electronic heating is balanced during the pump pulse by simultaneous cooling via intense plasma removal (prompt ablation). The relationship between the deposited volume energy density in the film and its prompt electronic temperature derived from the self-reflection measurements using a Drude model, demonstrates a kind of electron "liquid-vapor" phase transition, driven by strong cubic optical non-linearity of the photo-excited aluminum.

More than meets the IR: the expanding roles of variant Ionotropic Glutamate Receptors in sensing odor, taste, temperature and moisture.

PubMed

van Giesen, Lena; Garrity, Paul A

2017-01-01

The ionotropic receptors (IRs) are a branch of the ionotropic glutamate receptor family and serve as important mediators of sensory transduction in invertebrates. Recent work shows that, though initially studied as olfactory receptors, the IRs also mediate the detection of taste, temperature, and humidity. Here, we summarize recent insights into IR evolution and its potential ecological significance as well as recent advances in our understanding of how IRs contribute to diverse sensory modalities.

More than meets the IR: the expanding roles of variant Ionotropic Glutamate Receptors in sensing odor, taste, temperature and moisture

PubMed Central

van Giesen, Lena; Garrity, Paul A.

2017-01-01

The ionotropic receptors (IRs) are a branch of the ionotropic glutamate receptor family and serve as important mediators of sensory transduction in invertebrates. Recent work shows that, though initially studied as olfactory receptors, the IRs also mediate the detection of taste, temperature, and humidity. Here, we summarize recent insights into IR evolution and its potential ecological significance as well as recent advances in our understanding of how IRs contribute to diverse sensory modalities. PMID:29034089

Preferred mirror coatings for UV, visible, and IR space optical instruments

NASA Astrophysics Data System (ADS)

Heaney, James B.; Kauder, Lonny R.; Freese, Scott C.; Quijada, Manuel A.

2012-09-01

This paper will review the suitability of the common four types of reflecting surfaces - Ag, Al, Au and Be - for use aboard satellite borne remote sensing and astrophysical observatories, from the uv to far-ir spectral bands. The choice of appropriate protecting and reflectance enhancing overcoats for these reflecting metals will be discussed. Laboratory test data and optical diagnostic techniques used to verify durability of the selected coatings in a terrestrial storage environment and their sensitivity to a space radiation and cold temperature environment will be presented. For some of the selected coatings, a connection will be made between pre-launch laboratory quality checks and post-launch performance on orbit.

Crystal growth, fabrication and evaluation of cadmium manganese telluride gamma ray detectors

NASA Astrophysics Data System (ADS)

Burger, Arnold; Chattopadhyay, Kaushik; Chen, Henry; Olivier Ndap, Jean; Ma, Xiaoyan; Trivedi, Sudhir; Kutcher, Susan W.; Chen, Rujin; Rosemeier, Robert D.

1999-03-01

Cadmium manganese telluride (Cd 1- xMn xTe) is a diluted magnetic semiconductor material which forms the basis for many important devices such as IR detectors, solar cells, magnetic field sensors, optical isolators, and visible and near IR lasers. High resistivity (>10 10 Ω cm) and high μ τ (>10 -6 cm 2/V) material, which are the two prerequisites in the fabrication of radiation detectors, has recently been demonstrated at Brimrose Corp. This paper presents the crystal growth of intentionally vanadium doped crystals, the surface preparation and contacting procedure, as well as the best detector performance obtained so far. Dark current characteristics, and low temperature photoluminescence results are also presented and discussed.

Detection of defects in multi-layered aramid composites by ultrasonic IR thermography

NASA Astrophysics Data System (ADS)

Pracht, Monika; Swiderski, Waldemar

2017-10-01

In military applications, laminates reinforced with aramid, carbon, and glass fibers are used for the construction of protection products against light ballistics. Material layers can be very different by their physical properties. Therefore, such materials represent a difficult inspection task for many traditional techniques of non-destructive testing (NDT). Defects which can appear in this type of many-layered composite materials usually are inaccuracies in gluing composite layers and stratifications or delaminations occurring under hits of fragments and bullets. IR thermographic NDT is considered as a candidate technique to detect such defects. One of the active IR thermography methods used in nondestructive testing is vibrothermography. The term vibrothermography was created in the 1990s to determine the thermal test procedures designed to assess the hidden heterogeneity of structural materials based on surface temperature fields at cyclical mechanical loads. A similar procedure can be done with sound and ultrasonic stimulation of the material, because the cause of an increase in temperature is internal friction between the wall defect and the stimulation mechanical waves. If the cyclic loading does not exceed the flexibility of the material and the rate of change is not large, the heat loss due to thermal conductivity is small, and the test object returns to its original shape and temperature. The most commonly used method is ultrasonic stimulation, and the testing technique is ultrasonic infrared thermography. Ultrasonic IR thermography is based on two basic phenomena. First, the elastic properties of defects differ from the surroundings, and acoustic damping and heating are always larger in the damaged regions than in the undamaged or homogeneous areas. Second, the heat transfer in the sample is dependent on its thermal properties. In this paper, both modelling and experimental results which illustrate the advantages and limitations of ultrasonic IR thermography in inspecting multi-layered aramide composite materials will be presented.

Surface emissivity and temperature retrieval for a hyperspectral sensor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Borel, C.C.

1998-12-01

With the growing use of hyper-spectral imagers, e.g., AVIRIS in the visible and short-wave infrared there is hope of using such instruments in the mid-wave and thermal IR (TIR) some day. The author believes that this will enable him to get around using the present temperature-emissivity separation algorithms using methods which take advantage of the many channels available in hyper-spectral imagers. A simple fact used in coming up with a novel algorithm is that a typical surface emissivity spectrum are rather smooth compared to spectral features introduced by the atmosphere. Thus, a iterative solution technique can be devised which retrievesmore » emissivity spectra based on spectral smoothness. To make the emissivities realistic, atmospheric parameters are varied using approximations, look-up tables derived from a radiative transfer code and spectral libraries. One such iterative algorithm solves the radiative transfer equation for the radiance at the sensor for the unknown emissivity and uses the blackbody temperature computed in an atmospheric window to get a guess for the unknown surface temperature. By varying the surface temperature over a small range a series of emissivity spectra are calculated. The one with the smoothest characteristic is chosen. The algorithm was tested on synthetic data using MODTRAN and the Salisbury emissivity database.« less

Surface temperature measurements of a levitated water drop during laser irradiation

NASA Astrophysics Data System (ADS)

Brownell, Cody; Tracey, Timothy

2016-11-01

Simulation of high energy laser propagation and scattering in the maritime environment is problematic, due to the high liklihood of turbulence, fog, and rain or sea spray within the beam path. Laser interactions with large water drops (diameters of approximately 1-mm), such as those found in a light rain, have received relatively less attention. In this regime a high energy laser will rapidly heat and vaporize a water drop as it traverses the beam path, but the exact heating / vaporization rate, its dependence on impurities, and ancillary effects on the drop or surroundings are unclear. In this work we present surface temperature measurements of a water drop obtained using a FLIR IR camera. The drop is acoustically levitated, and subject to a continuous wave laser with a wavelength of 1070-nm and a mean irradiance of approximately 500 W/cm2. These measurements show that the steady-state surface temperature of the drop is well below the saturation temperature, yet based on the time history of the drop volume vaporization begins almost immediately upon laser strike. Inferences on the turbulence characteristics within the drop are also made from measurements of the fluctuations in the surface temperature. Supported by ONR, HEL-JTO, and USNA Trident Scholar Program.

Atmospheric pressure and temperature profiling using near IR differential absorption lidar

NASA Technical Reports Server (NTRS)

Korb, C. L.; Schwemmer, G. K.; Dombrowski, M.; Weng, C. Y.

1983-01-01

The present investigation is concerned with differential absorption lidar techniques for remotely measuring the atmospheric temperature and pressure profile, surface pressure, and cloud top pressure-height. The procedure used in determining the pressure is based on the conduction of high-resolution measurements of absorption in the wings of lines in the oxygen A band. Absorption with respect to these areas is highly pressure sensitive in connection with the mechanism of collisional line broadening. The method of temperature measurement utilizes a determination of the absorption at the center of a selected line in the oxygen A band which originates from a quantum state with high ground state energy.

High temperature Ir segregation in Ir-B ceramics: Effect of oxygen presence on stability of IrB 2 and other Ir-B phases

DOE PAGES

Xie, Zhilin; Terracciano, Anthony C.; Cullen, David A.; ...

2015-05-13

The formation of IrB 2, IrB 1.35, IrB 1.1 and IrB monoboride phases in the Ir–B ceramic nanopowder was confirmed during mechanochemical reaction between metallic Ir and elemental B powders. The Ir–B phases were analysed after 90 h of high energy ball milling and after annealing of the powder for 72 h at 1050°C in vacuo. The iridium monoboride (IrB) orthorhombic phase was synthesised experimentally for the first time and identified by powder X-ray diffraction. Additionally, the ReB 2 type IrB 2 hexagonal phase was also produced for the first time and identified by high resolution transmission electron microscope. Irmore » segregation along disordered domains of the boron lattice was found to occur during high temperature annealing. Furthermore, these nanodomains may have useful catalytic properties.« less

Role of coordination geometry in dictating the barrier to hydride migration in d6 square-pyramidal iridium and rhodium pincer complexes.

PubMed

Findlater, Michael; Cartwright-Sykes, Alison; White, Peter S; Schauer, Cynthia K; Brookhart, Maurice

2011-08-10

Syntheses of the olefin hydride complexes [(POCOP)M(H)(olefin)][BAr(f)(4)] (6a-M, M = Ir or Rh, olefin = C(2)H(4); 6b-M, M = Ir or Rh, olefin = C(3)H(6); POCOP = 2,6-bis(di-tert-butylphosphinito)benzene; BAr(f) = tetrakis(3,5-trifluoromethylphenyl)borate) are reported. A single-crystal X-ray structure determination of 6b-Ir shows a square-pyramidal coordination geometry for Ir, with the hydride ligand occupying the apical position. Dynamic NMR techniques were used to characterize these complexes. The rates of site exchange between the hydride and the olefinic hydrogens yielded ΔG(++) = 15.6 (6a-Ir), 16.8 (6b-Ir), 12.0 (6a-Rh), and 13.7 (6b-Rh) kcal/mol. The NMR exchange data also established that hydride migration in the propylene complexes yields exclusively the primary alkyl intermediate arising from 1,2-insertion. Unexpectedly, no averaging of the top and bottom faces of the square-pyramidal complexes is observed in the NMR spectra at high temperatures, indicating that the barrier for facial equilibration is >20 kcal/mol for both the Ir and Rh complexes. A DFT computational study was used to characterize the free energy surface for the hydride migration reactions. The classical terminal hydride complexes, [M(POCOP)(olefin)H](+), are calculated to be the global minima for both Rh and Ir, in accord with experimental results. In both the Rh ethylene and propylene complexes, the transition state for hydride migration (TS1) to form the agostic species is higher on the energy surface than the transition state for in-place rotation of the coordinated C-H bond (TS2), while for Ir, TS2 is the high point on the energy surface. Therefore, only for the case of the Rh complexes is the NMR exchange rate a direct measure of the hydride migration barrier. The trends in the experimental barriers as a function of M and olefin are in good agreement with the trends in the calculated exchange barriers. The calculated barriers for the hydride migration reaction in the Rh complexes are ∼2 kcal/mol higher than for the Ir complexes, despite the fact that the energy difference between the olefin hydride ground state and the agostic alkyl structure is ∼4 kcal/mol larger for Ir than for Rh. This feature, together with the high barrier for interchange of the top and bottom faces of the complexes, is proposed to arise from the unique coordination geometry of the agostic complexes and the strong preference for a cis-divacant octahedral geometry in four-coordinate intermediates. © 2011 American Chemical Society

Infrared Algorithm Development for Ocean Observations with EOS/MODIS

NASA Technical Reports Server (NTRS)

Brown, Otis B.

1997-01-01

Efforts continue under this contract to develop algorithms for the computation of sea surface temperature (SST) from MODIS infrared measurements. This effort includes radiative transfer modeling, comparison of in situ and satellite observations, development and evaluation of processing and networking methodologies for algorithm computation and data accession, evaluation of surface validation approaches for IR radiances, development of experimental instrumentation, and participation in MODIS (project) related activities. Activities in this contract period have focused on radiative transfer modeling, evaluation of atmospheric correction methodologies, undertake field campaigns, analysis of field data, and participation in MODIS meetings.

Study of Sea Surface Temperatures changes due to tropical cyclone fanoos in the southwest Bay of Bengal using satellite and argo observations

NASA Astrophysics Data System (ADS)

Krishna Kailasam, Muni

Sea surface temperature (SST) plays an important role in the studies of global climate system and as a boundary condition for operational numerical forecasts. Estimation of SST has tra-ditionally been performed with satellite based sensors operating in the infrared (IR) portion of the electromagnetic spectrum, where the ocean emissivity is close to unity. The National Oceanic and Atmospheric Administration (NOAA) satellite series, the GOES Imagers on the Geostationary Operational Environmental Satellites, the Along Track Scanning Radiometer (ATSR) on the European Remote Sensing satellites and the Moderate Resolution Imaging Spectroradiometer (MODIS) on the NASA EOS platform are successful examples of IR sen-sors currently used for operational SST retrievals. Significant progress in SST retrieval from remote sensing data came with the introduction of a new low-frequency channel (10.7 GHz) on microwave (MW) sensors. The anthropogenic effects over a period of time resulted in increase of infrared absorbers such as greenhouse gases and absorbing aerosol would produce increase of both daytime maximum and nighttime minimum temperatures. In contrast, the increases of visible reflectors such as sulfate aerosols and low cloud amount would result in a decrease of the daytime maximum temperature. Solar radiation, wind stress and vertical mixing are known to be the three major factors impacting the SST seasonal variations. In the present study, impact of absorbing aerosols on the sea surface temperature (SST) over Bay of Bengal (BoB) region was investigated. Increased aerosol loading over BoB was observed due to advection of aerosols from continental region consisting of absorbing particles primarily from dust and biomass burning. This increased loading over BoB resulted in reduction of surface reaching solar radiation. Tropical Rainfall Measuring Mission (TRMM) Microwave Imager (TMI) de-rived SST over BoB showed negative correlation with OMI-Aerosol Index (AI) (R = 0.87) and Terra/Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) AOD550 (R = 0.77) suggesting reduction in SST due to absorption of incoming solar radiation by aerosols.

Laminar iridium coating produced by pulse current electrodeposition from chloride molten salt

NASA Astrophysics Data System (ADS)

Zhu, Li'an; Bai, Shuxin; Zhang, Hong; Ye, Yicong

2013-10-01

Due to the unique physical and chemical properties, Iridium (Ir) is one of the most promising oxidation-resistant coatings for refractory materials above 1800 °C in aerospace field. However, the Ir coatings prepared by traditional methods are composed of columnar grains throughout the coating thickness. The columnar structure of the coating is considered to do harm to its oxidation resistance. The laminar Ir coating is expected to have a better high-temperature oxidation resistance than the columnar Ir coating does. The pulse current electrodeposition, with three independent parameters: average current density (Jm), duty cycle (R) and pulse frequency (f), is considered to be a promising method to fabricate layered Ir coating. In this study, laminar Ir coatings were prepared by pulse current electrodeposition in chloride molten salt. The morphology, roughness and texture of the coatings were determined by scanning electron microscope (SEM), profilometer and X-ray diffraction (XRD), respectively. The results showed that the laminar Ir coatings were composed of a nucleation layer with columnar structure and a growth layer with laminar structure. The top surfaces of the laminar Ir coatings consisted of cauliflower-like aggregates containing many fine grains, which were separated by deep grooves. The laminar Ir coating produced at the deposition condition of 20 mA/cm2 (Jm), 10% (R) and 6 Hz (f) was quite smooth (Ra 1.01 ± 0.09 μm) with extremely high degree of preferred orientation of <1 1 1>, and its laminar structure was well developed with clear boundaries and uniform thickness of sub-layers.

Study on seasonal IR signature change of a ship by considering seasonal marine environmental conditions

NASA Astrophysics Data System (ADS)

Kim, Do-Hwi; Han, Kuk-Il; Choi, Jun-Hyuk; Kim, Tae-Kuk

2017-05-01

Infrared (IR) signal emitted from objects over 0 degree Kelvin has been used to detect and recognize the characteristics of those objects. Recently more delicate IR sensors have been applied for various guided missiles and they affect a crucial influence on object's survivability. Especially, in marine environment it is more vulnerable to be attacked by IR guided missiles since there are nearly no objects for concealment. To increase the survivability of object, the IR signal of the object needs to be analyzed properly by considering various marine environments. IR signature of a naval ship consists of the emitted energy from ship surface and the reflected energy by external sources. Surface property such as the emissivity and the absorptivity on the naval ship varies with different paints applied on the surface and the reflected IR signal is also affected by the surface radiative property, the sensor's geometric position and various climatic conditions in marine environment. Since the direct measurement of IR signal using IR camera is costly and time consuming job, computer simulation methods are developing rapidly to replace those experimental tasks. In this study, we are demonstrate a way of analyzing the IR signal characteristics by using the measured background IR signals using an IR camera and the estimated target IR signals from the computer simulation to find the seasonal trends of IR threats of a naval ship. Through this process, measured weather data are used to analyze more accurate IR signal conditions for the naval ship. The seasonal change of IR signal contrast between the naval ship and the marine background shows that the highest contrast radiant intensity (CRI) value is appeared in early summer.

About possibility of temperature trace observing on the human skin using commercially available IR camera

NASA Astrophysics Data System (ADS)

Trofimov, Vyacheslav A.; Trofimov, Vladislav V.; Shestakov, Ivan L.; Blednov, Roman G.

2016-09-01

One of urgent security problems is a detection of objects placed inside the human body. Obviously, for safety reasons one cannot use X-rays for such object detection widely and often. Three years ago, we have demonstrated principal possibility to see a temperature trace, induced by food eating or water drinking, on the human body skin by using a passive THz camera. However, this camera is very expensive. Therefore, for practice it will be very convenient if one can use the IR camera for this purpose. In contrast to passive THz camera using, the IR camera does not allow to see the object under clothing, if an image, produced by this camera, is used directly. Of course, this is a big disadvantage for a security problem solution based on the IR camera using. To overcome this disadvantage we develop novel approach for computer processing of IR camera images. It allows us to increase a temperature resolution of IR camera as well as increasing of human year effective susceptibility. As a consequence of this, a possibility for seeing of a human body temperature changing through clothing appears. We analyze IR images of a person, which drinks water and eats chocolate. We follow a temperature trace on human body skin, caused by changing of temperature inside the human body. Some experiments were made with measurements of a body temperature covered by T-shirt. Shown results are very important for the detection of forbidden objects, cancelled inside the human body, by using non-destructive control without using X-rays.

Thickness Dependence of the Dzyaloshinskii-Moriya Interaction in Co2 FeAl Ultrathin Films: Effects of Annealing Temperature and Heavy-Metal Material

NASA Astrophysics Data System (ADS)

Belmeguenai, M.; Roussigné, Y.; Bouloussa, H.; Chérif, S. M.; Stashkevich, A.; Nasui, M.; Gabor, M. S.; Mora-Hernández, A.; Nicholson, B.; Inyang, O.-O.; Hindmarch, A. T.; Bouchenoire, L.

2018-04-01

The interfacial Dzyaloshinskii-Moriya interaction (IDMI) is investigated in Co2FeAl (CFA) ultrathin films of various thicknesses (0.8 nm ≤tCFA≤2 nm ) grown by sputtering on Si substrates, using Pt, W, Ir, and MgO buffer or/and capping layers. Vibrating sample magnetometry reveals that the magnetization at saturation (Ms ) for the Pt- and Ir-buffered films is higher than the usual Ms of CFA due to the proximity-induced magnetization (PIM) in Ir and Pt estimated to be 19% and 27%, respectively. The presence of PIM in these materials is confirmed using x-ray resonant magnetic reflectivity. Moreover, while no PIM is induced in W, higher PIM is obtained with Pt when it is used as a buffer layer rather than a capping layer. Brillouin light scattering in the Damon-Eshbach geometry is used to investigate the thickness dependences of the IDMI constants from the spin-wave nonreciprocity and the perpendicular anisotropy field versus the annealing temperature. The IDMI sign is found to be negative for Pt /CFA and Ir /CFA , while it is positive for W /CFA . The thickness dependence of the effective IDMI constant for stacks involving Pt and W shows the existence of two regimes similar to that of the perpendicular anisotropy constant due to the degradation of the interfaces as the CFA thickness approaches a critical thickness. The surface IDMI and anisotropy constants of each stack are determined for the thickest samples where a linear thickness dependence of the effective IDMI constant and the effective magnetization are observed. The interface anisotropy and IDMI constants investigated for the Pt /CFA /MgO system show different trends with the annealing temperature. The decrease of the IDMI constant with increasing annealing temperature is probably due to the electronic structure changes at the interfaces, while the increase of the interface anisotropy constant is coherent with the interface quality and disorder enhancement.

Tracing the beginning of crystallization of amorphous forsterite thin films using AFM and IR spectroscopy

NASA Astrophysics Data System (ADS)

Oehm, B.; Burchard, M.; Lattard, D.; Dohmen, R.; Chakraborty, S.

2009-12-01

Observations of accretion disks of Young Stellar Objects revealed dust of crystalline Mg-silicates, in particular of forsterite, which is assumed to result from high temperature annealing of amorphous cosmic dust particles. We are performing annealing experiments to obtain kinetic parameters of the crystallization that are necessary for the numerical modeling of accretion disks. We use thin films obtained by Pulsed Laser Deposition (PLD) on Si (111) wafers. The thin films are completely amorphous, chemically homogeneous (on the Mg2SiO4 composition) and with a continuous and flat surface. They are annealed for 1 to 260 h at 1073K in a vertical furnace and drop-quenched. To monitor the progress of crystallization, the samples are characterized by AFM and SEM imaging and IR spectroscopy. After 2.5 h of annealing AFM images reveal elliptical features, below 1 µm in diameter, with a central elevation and surrounded by a lowering of the surface which indicate material transport within the elliptical domains. These elliptical features most probably represent early nucleation sites in an amorphous matrix. The IR spectra still show the broad bands of Si-O stretching modes typical of amorphous silica without clear evidence for crystalline forsterite. After 6 h of annealing, AFM and SEM images show circular and square features both with a central elevation in the range of 80 to 120 nm. IR spectra show a few weak bands that can be assigned to crystalline forsterite (bending and stretching of tetrahedra). After 10 h of annealing planar faces appear in the former pyramidal features and the surrounding matrix evolves into domains with spherolitic appearance. IR spectra of these samples display typical bands of crystalline forsterite. With increasing annealing time AFM images picture the further growth of the planar faces towards idiomorphic crystals. SEM imaging shows surface roughening with increasing annealing time. The quantitative evaluation of the surface roughness of AFM images point to three evolutionary stages during annealing. The quantitative evaluation of IR spectra reveals that the forsterite bands continuously grow with increasing annealing time up to 64 h but that no significant change appears for longer run durations. AFM imaging proves to be a powerful tool to detect the very first signs of crystallization and to trace its further evolution.

Structure sensitivity in the kinetics and the dynamics of CO oxidation over stepped Pd(335) studied by the molecular beam infrared chemiluminescence technique: Determination of working sites during the steady-state reaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Uetsuka, H.; Watanabe, K.; Kimpara, H.

Kinetics and dynamics of CO oxidation have been studied on a stepped Pd(335) surface at a steady-state condition and compared with those on flat Pd(111). The infrared (IR) chemiluminescence technique was applied to determine where the active catalytic sites are on the Pd(335) surface. Since the vibrational energy state of the product CO{sub 2} is sensitive to the structures of the reaction sites on Pd surfaces, information about the working reaction sites during the steady-state CO oxidation can be obtained from the IR emission spectra of the product CO{sub 2}. The production rate of CO{sub 2} was higher on Pd(335)more » than on Pd(111), indicating that the steps on the surface enhance the catalytic activity for Co oxidation under the steady-state condition. However, the rate data do not necessarily show the real active sites for the CO + O recombination reaction. At a surface temperature of 850 K, the vibrational Boltzmann temperature (T{sub v}) of the product CO{sub 2} on Pd(335) was quite different from (much lower than) that on Pd(111), although the Pd(335) surface has four-atom wide (111) terraces. The lower T{sub v} value on Pd(335) was similar to that on Pd(110)(1 x 1), indicating that a relatively linear activated CO{sub 2} complex was formed. Therefore, during the steady-state CO oxidation on Pd(335), the reaction does not take place on the (111) terrace sites, but mostly on the step sites at 850 K. On the contrary, as the CO coverage increased at a lower surface temperature and at a high CO/O{sub 2} ratio, the T{sub v} values on Pd(335) tend to approach those on Pd(111), indicating that the contribution of the active sites on the steps is decreased and the working reaction sites shift to the (111) terrace sites.« less

Tunable surface plasmon resonance frequency of Au-Ag bimetallic asymmetric structure thin films in the UV and IR region

NASA Astrophysics Data System (ADS)

Hong, Ruijin; Ji, Jialin; Tao, Chunxian; Zhang, Dawei

2016-10-01

Au/ZnO/Ag sandwich structure films were fabricated by DC magnetron sputter at room temperature. The tunability of the surface plasmon resonance wavelength was realized by varying the thickness of ZnO thin film. The effects of ZnO layer on the optical properties of Au/ZnO/Au thin films were investigated by optical absorption and Raman scattering measurements. It has been found that both the surface plasmon resonance frequency and SERS can be controlled by adjusting the thickness of ZnO layer due to the coupling of metal and semiconductor.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jiang, J.; Walters, D. M.; Zhou, D.

Vapor-deposited glasses can be anisotropic and molecular orientation is important for organic electronics applications. In organic light emitting diodes (OLEDs), for example, the orientation of dye molecules in two-component emitting layers significantly influences emission efficiency. Here we investigate how substrate temperature during vapor deposition influences the orientation of dye molecules in a model two-component system. We determine the average orientation of a linear blue light emitter 1,4-di-[4-( N,N-diphenyl)amino]styrylbenzene (DSA-Ph) in mixtures with aluminum-tris(8-hydroxyquinoline) (Alq 3) by spectroscopic ellipsometry and IR dichroism. We find that molecular orientation is controlled by the ratio of the substrate temperature during deposition and the glassmore » transition temperature of the mixture. Furthermore, these findings extend recent results for single component vapor-deposited glasses and suggest that, during vapor deposition, surface mobility allows partial equilibration towards orientations preferred at the free surface of the equilibrium liquid.« less

Quantification of the effect of surface heating on shock wave modification by a plasma actuator in a low-density supersonic flow over a flat plate

NASA Astrophysics Data System (ADS)

Joussot, Romain; Lago, Viviana; Parisse, Jean-Denis

2015-05-01

This paper describes experimental and numerical investigations focused on the shock wave modification induced by a dc glow discharge. The model is a flat plate in a Mach 2 air flow, equipped with a plasma actuator composed of two electrodes. A weakly ionized plasma was created above the plate by generating a glow discharge with a negative dc potential applied to the upstream electrode. The natural flow exhibited a shock wave with a hyperbolic shape. Pitot measurements and ICCD images of the modified flow revealed that when the discharge was ignited, the shock wave angle increased with the discharge current. The spatial distribution of the surface temperature was measured with an IR camera. The surface temperature increased with the current and decreased along the model. The temperature distribution was reproduced experimentally by placing a heating element instead of the active electrode, and numerically by modifying the boundary condition at the model surface. For the same surface temperature, experimental investigations showed that the shock wave angle was lower with the heating element than for the case with the discharge switched on. The results show that surface heating is responsible for roughly 50 % of the shock wave angle increase, meaning that purely plasma effects must also be considered to fully explain the flow modifications observed.

Optimization of concentrator photovoltaic solar cell performance through photonic engineering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harris, James

The goal of this program was to incorporate two new and innovative design concepts into the design and production of CPV cells that have near zero added cost, yet significantly increase the operational efficiency of CPV modules. The program focused developing luminescent coupling effects and radiative cooling layers to increase efficiency and suppress CPV module power losses due to spectral variations and heating. The major results of the program were: 1) The optics of three commercial refractive (Fresnel) concentrators were characterized and prevent application of radiative cooling concepts due to strong mid-IR absorption (4-12µm) required to effectively radiate blackbody radiationmore » from the cells and provide cooling. Investigation of alternative materials for the concentrator lenses produced only undesirable options—materials with reasonable mid-IR transmission for cooling only had about 30-40 visible transmission, thus reducing incident sunlight by >50%. While our investigation was somewhat limited, our work suggests that the only viable concentrator system that can incorporate radiative cooling utilizes reflective optics. 2) With limited ability to test high concentration CPV cells (requires outdoor testing), we acquired both semi-crystalline and crystalline Si cells and tested them in our outdoor facility and demonstrated 4°C cooling using a simple silica layer coating on the cells. 3) Characterizing Si cells in the IR associated with radiative cooling, we observed very significant near-IR absorption that increases the cell operating temperature by a similar amount, 4-5°C. By appropriate surface layer design, one can produce a layer that is highly reflective in the near-IR (1.5-4µm) and highly emissive in the mid-IR (5-15µm), thus reducing cell operational temperature by 10°C and increasing efficiency by ~1% absolute. The radiative cooling effect in c-Si solar cells might be further improved by providing a higher thermal conductive elastomer for securing the cover glass on top of the AR-coating. Since it was never imagined that the front surface would provide any cooling for solar cells, thermal conductivity of this elastomer was never a design consideration, but, improving the conductivity could decrease cell temperature by another 3-4°C. The combined effect could be an ~1.5% absolute increase in cell and module efficiency, a very significant improvement. 4) Developed a numerical model to explore dependence of luminescent coupling efficiency over a broad range of operating conditions. We developed a novel method and facility to experimentally measure the luminescent coupling that can be used to confirm the dependence of luminescent coupling on multi-junction cell design parameters.« less

First-principles study of the infrared spectra of the ice Ih (0001) surface

DOE PAGES

Pham, T. Anh; Huang, P.; Schwegler, E.; ...

2012-08-22

Here, we present a study of the infrared (IR) spectra of the (0001) deuterated ice surface based on first-principles molecular dynamics simulations. The computed spectra show a good agreement with available experimental IR measurements. We identified the bonding configurations associated with specific features in the spectra, allowing us to provide a detailed interpretation of IR signals. We computed the spectra of several proton ordered and disordered models of the (0001) surface of ice, and we found that IR spectra do not appear to be a sensitive probe of the microscopic arrangement of protons at ice surfaces.

Modeling and Compensating Temperature-Dependent Non-Uniformity Noise in IR Microbolometer Cameras

PubMed Central

Wolf, Alejandro; Pezoa, Jorge E.; Figueroa, Miguel

2016-01-01

Images rendered by uncooled microbolometer-based infrared (IR) cameras are severely degraded by the spatial non-uniformity (NU) noise. The NU noise imposes a fixed-pattern over the true images, and the intensity of the pattern changes with time due to the temperature instability of such cameras. In this paper, we present a novel model and a compensation algorithm for the spatial NU noise and its temperature-dependent variations. The model separates the NU noise into two components: a constant term, which corresponds to a set of NU parameters determining the spatial structure of the noise, and a dynamic term, which scales linearly with the fluctuations of the temperature surrounding the array of microbolometers. We use a black-body radiator and samples of the temperature surrounding the IR array to offline characterize both the constant and the temperature-dependent NU noise parameters. Next, the temperature-dependent variations are estimated online using both a spatially uniform Hammerstein-Wiener estimator and a pixelwise least mean squares (LMS) estimator. We compensate for the NU noise in IR images from two long-wave IR cameras. Results show an excellent NU correction performance and a root mean square error of less than 0.25 ∘C, when the array’s temperature varies by approximately 15 ∘C. PMID:27447637

Noncontact localized internal infrared radiation measurement using an infrared point detector

NASA Astrophysics Data System (ADS)

Hisaka, Masaki

2017-12-01

The techniques for temperature measurement within the human body are important for clinical applications. A method for noncontact local infrared (IR) radiation measurements was investigated deep within an object to simulate how the core human body temperature can be obtained. To isolate the IR light emitted from a specific area within the object from the external noise, the radiating IR light was detected using an IR point detector, which comprises a pinhole and a thermopile positioned at an imaging relation with the region of interest within the object. The structure of the helical filament radiating IR light inside a light bulb was thermally imaged by scanning the bulb in two dimensions. Moreover, this approach was used to effectively measure IR light in the range of human body temperature using a glass plate placed in front of the heat source, mimicking the ocular fundus.

Noncontact localized internal infrared radiation measurement using an infrared point detector

NASA Astrophysics Data System (ADS)

Hisaka, Masaki

2018-06-01

The techniques for temperature measurement within the human body are important for clinical applications. A method for noncontact local infrared (IR) radiation measurements was investigated deep within an object to simulate how the core human body temperature can be obtained. To isolate the IR light emitted from a specific area within the object from the external noise, the radiating IR light was detected using an IR point detector, which comprises a pinhole and a thermopile positioned at an imaging relation with the region of interest within the object. The structure of the helical filament radiating IR light inside a light bulb was thermally imaged by scanning the bulb in two dimensions. Moreover, this approach was used to effectively measure IR light in the range of human body temperature using a glass plate placed in front of the heat source, mimicking the ocular fundus.

A highly active and stable IrO x/SrIrO 3 catalyst for the oxygen evolution reaction

DOE PAGES

Seitz, Linsey C.; Dickens, Colin F.; Nishio, Kazunori; ...

2016-09-02

Oxygen electrochemistry plays a key role in renewable energy technologies such as fuel cells and electrolyzers, but the slow kinetics of the oxygen evolution reaction (OER) limit the performance and commercialization of such devices. Here we report an iridium oxide/strontium iridium oxide (IrO x/SrIrO 3) catalyst formed during electrochemical testing by strontium leaching from surface layers of thin films of SrIrO 3. This catalyst has demonstrated specific activity at 10 milliamps per square centimeter of oxide catalyst (OER current normalized to catalyst surface area), with only 270 to 290 millivolts of overpotential for 30 hours of continuous testing in acidicmore » electrolyte. Here, density functional theory calculations suggest the formation of highly active surface layers during strontium leaching with IrO 3 or anatase IrO 2 motifs. The IrO x/SrIrO 3 catalyst outperforms known IrO x and ruthenium oxide (RuO x) systems, the only other OER catalysts that have reasonable activity in acidic electrolyte.« less

A highly active and stable IrOx/SrIrO3 catalyst for the oxygen evolution reaction.

PubMed

Seitz, Linsey C; Dickens, Colin F; Nishio, Kazunori; Hikita, Yasuyuki; Montoya, Joseph; Doyle, Andrew; Kirk, Charlotte; Vojvodic, Aleksandra; Hwang, Harold Y; Norskov, Jens K; Jaramillo, Thomas F

2016-09-02

Oxygen electrochemistry plays a key role in renewable energy technologies such as fuel cells and electrolyzers, but the slow kinetics of the oxygen evolution reaction (OER) limit the performance and commercialization of such devices. Here we report an iridium oxide/strontium iridium oxide (IrO x /SrIrO 3 ) catalyst formed during electrochemical testing by strontium leaching from surface layers of thin films of SrIrO 3 This catalyst has demonstrated specific activity at 10 milliamps per square centimeter of oxide catalyst (OER current normalized to catalyst surface area), with only 270 to 290 millivolts of overpotential for 30 hours of continuous testing in acidic electrolyte. Density functional theory calculations suggest the formation of highly active surface layers during strontium leaching with IrO 3 or anatase IrO 2 motifs. The IrO x /SrIrO 3 catalyst outperforms known IrO x and ruthenium oxide (RuO x ) systems, the only other OER catalysts that have reasonable activity in acidic electrolyte. Copyright © 2016, American Association for the Advancement of Science.

The influence of iridium chemical oxidation state on the performance and durability of oxygen evolution catalysts in PEM electrolysis

NASA Astrophysics Data System (ADS)

Siracusano, S.; Baglio, V.; Grigoriev, S. A.; Merlo, L.; Fateev, V. N.; Aricò, A. S.

2017-10-01

Nanosized Ir-black (3 nm) and Ir-oxide (5 nm) oxygen evolution electrocatalysts showing high performance in polymer electrolyte membrane (PEM) water electrolysis based on Aquivion® short-side chain ionomer membrane are investigated to understand the role of the Ir oxidation state on the electrocatalytic activity and stability. Despite the smaller mean crystallite size, the Ir-black electrocatalyst shows significantly lower initial performance than the Ir-oxide. During operation at high current density, the Ir-black shows a decrease of cell potential with time whereas the Ir-oxide catalyst shows increasing cell potential resulting in a degradation rate of about 10 μV/h, approaching 1000 h. The unusual behaviour of the Ir-black results from the oxidation of metallic Ir to IrOx. The Ir-oxide catalyst shows instead a hydrated structure on the surface and a negative shift of about 0.5 eV for the Ir 4f binding energy after 1000 h electrolysis operation. This corresponds to the formation of a sub-stoichiometric Ir-oxide on the surface. These results indicate that a hydrated IrO2 with high oxidation state on the surface is favourable in decreasing the oxygen evolution overpotential. Modifications of the Ir chemical oxidation state during operation can affect significantly the catalytic activity and durability of the electrolysis system.

Substrate temperature controls molecular orientation in two-component vapor-deposited glasses

DOE PAGES

Jiang, J.; Walters, D. M.; Zhou, D.; ...

2016-02-22

Vapor-deposited glasses can be anisotropic and molecular orientation is important for organic electronics applications. In organic light emitting diodes (OLEDs), for example, the orientation of dye molecules in two-component emitting layers significantly influences emission efficiency. Here we investigate how substrate temperature during vapor deposition influences the orientation of dye molecules in a model two-component system. We determine the average orientation of a linear blue light emitter 1,4-di-[4-( N,N-diphenyl)amino]styrylbenzene (DSA-Ph) in mixtures with aluminum-tris(8-hydroxyquinoline) (Alq 3) by spectroscopic ellipsometry and IR dichroism. We find that molecular orientation is controlled by the ratio of the substrate temperature during deposition and the glassmore » transition temperature of the mixture. Furthermore, these findings extend recent results for single component vapor-deposited glasses and suggest that, during vapor deposition, surface mobility allows partial equilibration towards orientations preferred at the free surface of the equilibrium liquid.« less

Development and characterization of a microheater array device for real-time DNA mutation detection

NASA Astrophysics Data System (ADS)

Williams, Layne; Okandan, Murat; Chagovetz, Alex; Blair, Steve

2008-04-01

DNA analysis, specifically single nucleotide polymorphism (SNP) detection, is becoming increasingly important in rapid diagnostics and disease detection. Temperature is often controlled to help speed reaction rates and perform melting of hybridized oligonucleotides. The difference in melting temperatures, Tm, between wild-type and SNP sequences, respectively, to a given probe oligonucleotide, is indicative of the specificity of the reaction. We have characterized Tm's in solution and on a solid substrate of three sequences from known mutations associated with Cystic Fibrosis. Taking advantage of Tm differences, a microheater array device was designed to enable individual temperature control of up to 18 specific hybridization events. The device was fabricated at Sandia National Laboratories using surface micromachining techniques. The microheaters have been characterized using an IR camera at Sandia and show individual temperature control with minimal thermal cross talk. Development of the device as a real-time DNA detection platform, including surface chemistry and associated microfluidics, is described.

Development and characterization of a microheater array device for real-time DNA mutation detection

NASA Astrophysics Data System (ADS)

Williams, Layne; Okandan, Murat; Chagovetz, Alex; Blair, Steve

2008-02-01

DNA analysis, specifically single nucleotide polymorphism (SNP) detection, is becoming increasingly important in rapid diagnostics and disease detection. Temperature is often controlled to help speed reaction rates and perform melting of hybridized oligonucleotides. The difference in melting temperatures, Tm, between wild-type and SNP sequences, respectively, to a given probe oligonucleotide, is indicative of the specificity of the reaction. We have characterized Tm's in solution and on a solid substrate of three sequences from known mutations associated with Cystic Fibrosis. Taking advantage of Tm differences, a microheater array device was designed to enable individual temperature control of up to 18 specific hybridization events. The device was fabricated at Sandia National Laboratories using surface micromachining techniques. The microheaters have been characterized using an IR camera at Sandia and show individual temperature control with minimal thermal cross talk. Development of the device as a real-time DNA detection platform, including surface chemistry and associated microfluidics, is described.

Photo-catalyzed surface hydrolysis of iridium(iii) ions on semiconductors: a facile method for the preparation of semiconductor/IrOx composite photoanodes toward oxygen evolution reaction.

PubMed

Wu, Qingyong; Xu, Di; Xue, Ning; Liu, Tengyi; Xiang, Min; Diao, Peng

2016-12-21

We previously reported that the hydrolysis of Ir 3+ in homogeneous solution could be triggered by irradiation with light whose energy was larger than a threshold value. In this work, we demonstrated that, by introducing Fe 2 O 3 particles into solution, the incident light energy-restriction for the photo-catalyzed hydrolysis could be broken and the hydrolysis occurred at the Fe 2 O 3 /solution interface. The photo-generated holes on the Fe 2 O 3 surface played a key role in oxidizing Ir(iii) to Ir(iv) species and triggered the deposition of IrO x . We showed that this photo-catalyzed surface hydrolysis is a universal phenomenon that takes place on the surface of many n-type semiconductors such as Fe 2 O 3 , TiO 2 , and Ag 3 PO 4 . As IrO x is an efficient catalyst for oxygen evolution reaction, surface hydrolysis is a general, facile and efficient strategy to prepare semiconductor/IrO x composites, which can be used as anodic materials for photoelectrochemical water splitting.

Influence of iridium doping in MgB2 superconducting wires

NASA Astrophysics Data System (ADS)

Grivel, J.-C.

2018-04-01

MgB2 wires with iridium doping were manufactured using the in-situ technique in a composite Cu-Nb sheath. Reaction was performed at 700 °C, 800 °C or 900 °C for 1 h in argon atmosphere. A maximum of about 1.5 at.% Ir replaces Mg in MgB2. The superconducting transition temperature is slightly lowered by Ir doping. The formation of IrMg3 and IrMg4 secondary phase particles is evidenced, especially for a nominal stoichiometry with 2.0 at.% Ir doping. The critical current density and accommodation field of the wires are strongly dependent on the Ir content and are generally weakened in the presence of Ir, although the effect is less pronounced at lower temperatures.

Three-dimensional dynamics of temperature fields in phantoms and biotissue under IR laser photothermal therapy using gold nanoparticles and ICG dye

NASA Astrophysics Data System (ADS)

Akchurin, Georgy G.; Garif, Akchurin G.; Maksimova, Irina L.; Skaptsov, Alexander A.; Terentyuk, Georgy S.; Khlebtsov, Boris N.; Khlebtsov, Nikolai G.; Tuchin, Valery V.

2010-02-01

We describe applications of silica (core)/gold (shell) nanoparticles and ICG dye to photothermal treatment of phantoms, biotissue and spontaneous tumor of cats and dogs. The laser irradiation parameters were optimized by preliminary experiments with laboratory rats. Three dimensional dynamics of temperature fields in tissue and solution samples was measured with a thermal imaging system. It is shown that the temperature in the volume region of nanoparticles localization can substantially exceed the surface temperature recorded by the thermal imaging system. We have demonstrated effective optical destruction of cancer cells by local injection of plasmon-resonant gold nanoshells and ICG dye followed by continuous wave (CW) diode laser irradiation at wavelength 808 nm.

Dynamics of a Room Temperature Ionic Liquid in Supported Ionic Liquid Membranes vs the Bulk Liquid: 2D IR and Polarized IR Pump-Probe Experiments.

PubMed

Shin, Jae Yoon; Yamada, Steven A; Fayer, Michael D

2017-01-11

Supported ionic liquid membranes (SILMs) are membranes that have ionic liquids impregnated in their pores. SILMs have been proposed for advanced carbon capture materials. Two-dimensional infrared (2D IR) and polarization selective IR pump-probe (PSPP) techniques were used to investigate the dynamics of reorientation and spectral diffusion of the linear triatomic anion, SeCN - , in poly(ether sulfone) (PES) membranes and room-temperature ionic liquid (RTIL), 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EmimNTf 2 ). The dynamics in the bulk EmimNTf 2 were compared to its dynamics in the SILM samples. Two PES membranes, PES200 and PES30, have pores with average sizes, ∼300 nm and ∼100 nm, respectively. Despite the relatively large pore sizes, the measurements reveal that the reorientation of SeCN - and the RTIL structural fluctuations are substantially slower in the SILMs than in the bulk liquid. The complete orientational randomization, slows from 136 ps in the bulk to 513 ps in the PES30. 2D IR measurements yield three time scales for structural spectral diffusion (SSD), that is, the time evolution of the liquid structure. The slowest decay constant increases from 140 ps in the bulk to 504 ps in the PES200 and increases further to 1660 ps in the PES30. The results suggest that changes at the interface propagate out and influence the RTIL structural dynamics even more than a hundred nanometers from the polymer surface. The differences between the IL dynamics in the bulk and in the membranes suggest that studies of bulk RTIL properties may be poor guides to their use in SILMs in carbon capture applications.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Han, Chang W.; Iddir, Hakim; Uzun, Alper

To address the challenge of fast, direct atomic-scale visualization of the diffusion of atoms and clusters on surfaces, we used aberration-corrected scanning transmission electron microscopy (STEM) with high scan speeds (as little as ~0.1 s per frame) to visualize the diffusion of (1) a heavy atom (Ir) on the surface of a support consisting of light atoms, MgO(100), and (2) an Ir 3 cluster on MgO(110). Sequential Z-contrast images elucidate the diffusion mechanisms, including the hopping of Ir1 and the rotational migration of Ir 3 as two Ir atoms remain anchored to the surface. Density functional theory (DFT) calculations providedmore » estimates of the diffusion energy barriers and binding energies of the iridium species to the surfaces. The results show how the combination of fast-scan STEM and DFT calculations allow real-time visualization and fundamental understanding of surface diffusion phenomena pertaining to supported catalysts and other materials.« less

FTIR reflectance of selected minerals and their mixtures: implications for ground temperature-sensor monitoring on Mars surface environment (NASA/MSL-Rover Environmental Monitoring Station).

PubMed

Martín-Redondo, M Paz; Martínez, Eduardo Sebastian; Sampedro, M Teresa Fernández; Armiens, Carlos; Gómez-Elvira, Javier; Martinez-Frias, Jesus

2009-07-01

The Rover Environmental Monitoring Station (REMS) is one of NASA/MSL's instruments, which has been designed for measuring ambient pressure, humidity, wind speed and direction, UV radiation, and air and ground temperature (GT). The GT-sensor is dedicated to measure the real temperature of the Martian surface, integrating the IR energy coming from the ground. The existing IR spectral data of Martian dust, rocks and sediments allow for comparing the Martian spectra with the spectra of different terrestrial minerals and lithologies, and those of their alteration and weathering products. The FTIR reflectance of a set of selected astrobiologically significant minerals (including oxides, oxi/hydroxides, sulfates, chlorides, opal and clays) and basalt (as the main and most widespread volcanic Martian rock) was measured, considering different mixing amounts, and covering the specific working wavelength range of the REMS' GT-sensor. The results obtained show important percentage increases or decreases of reflectance in the entire wavelength range (e.g. basalt-hematite vs. basalt-magnetite) and specific variations limited to some spectral bands (e.g. basalt-smectite vs. basalt-jasper). The basalt reflectance percentage increases or decreases, even up to 100%, depending on the mixing of the different minerals. This unequivocally confirms the need for considering the chemical-mineralogical assemblages (and their textures) for any investigation and interpretation of Mars surface environment. Some complementary applications of this research on our planet, either in relation to the specific performances and characteristics of the GT-sensor autonomous recalibration system, or those oriented to carrying out similar studies on different types of terrestrial environmental settings, are also described.

The Other Chemistry of the Jovian Icy Satellites - Low Energy and Sulfurous

NASA Technical Reports Server (NTRS)

Hudson, Reggie L.; Loeffler, M. J.; Moore, M. H.

2010-01-01

Spectra of Jupiter's icy satellites reveal surfaces dominated by H2O-ice with minor amounts of SO2 and other materials. The co-existence of H2O and SO2 in surfaces exposed to jovian magnetospheric radiation suggests that sulfuric acid (H2SO4) also could be present. This was noted by Carlson et al. (1999), who supported this suggestion with assignments of near-IR bands in Europa spectra to hydrated H2SO4. Laboratory experiments since have demonstrated radiolytically-driven syntheses in S- and SO2-containing H2O-Ices (Carlson et al., 2002; Moore et al., 2006). In the Cosmic Ice Laboratory, we recently have investigated the thermal chemistry of SO2 trapped in H2O-ice. IR spectra of H2O + SO2 mixtures recorded at 10 to 230 K were used to follow low-temperature reactions in the absence of radiation effects. No SO2 reactions were found at 10 K, but warming to more-relevant Europa temperatures produced both HSO3(-) and S2O5(2-). Added NH3 shifted the product composition toward SO3(2-) and away from the other ions. We find that H2O and SO2 react to produce sulfur oxyanions, such as bisulfite, that as much as 30% of the SO2 can be consumed through this reaction, and that the products remain in the ice when the temperature is lowered, indicating that these reactions are irreversible. Our results suggest that thermally-induced reactions can alter the chemistry at and below the surfaces of the icy satellites in the jovian system.

Metal-insulator transition and superconductivity in the spinel-type Cu(Ir1-xRhx)2S4 system

NASA Astrophysics Data System (ADS)

Matsumoto, Nobuhiro; Endoh, Ryo; Nagata, Shoichi; Furubayashi, Takao; Matsumoto, Takehiko

1999-08-01

The normal thiospinel CuIr2S4 exhibits a temperature-induced metal-insulator (M-I) transition around 226 K with structural transformation, showing hysteresis on heating and cooling. It has been verified that d electrons of Ir atom on the octahedral B sites have a significant role for the M-I transition. On the other hand, CuRh2S4 is a superconductor with the transition temperature Tc=4.70 K, which is well understood on the basis of the BCS theory. It is important to investigate the effect on the M-I transition by substitution of Rh for Ir. We have systematically studied structural transformation and electrical and magnetic properties of Cu(Ir1-xRhx)2S4. The features of the M-I transition change with Rh concentration x. A phase diagram of temperature versus x will be proposed for the Cu(Ir1-xRhx)2S4 system. The sharp M-I transition temperature varies drastically from 226 to 93 K with x from 0.00 to 0.17 and disappears around x=0.20. In a region of 0.00<=x<=0.20, the magnetic susceptibility begins decreasing at a constant onset temperature 226 K on cooling process and shows rather broad temperature variation, even though the metallic state is kept in the resistivity. The sharp M-I transition can take place after the suppression of magnitude in the susceptibility has sufficiently developed far below 226 K. These experimental results are discussed with emphasis on the intrinsic difference between Cu(Ir1-xRhx)2S4 and CuIr2(S1-xSex)4 systems. Furthermore, we will mention the superconductivity for both systems of Cu(Ir1-xRhx)2S4 with high-Rh concentration region and Cu1-xNixRh2S4.

Astronomy in Denver: Spatial distributions of dust properties via far-IR broadband map with HerPlaNS

NASA Astrophysics Data System (ADS)

Asano, Kentaro; Ueta, Toshiya; Ladjal, Djazia; Exter, Katrina; Otsuka, Masaaki; HerPlaNS Consortium

2018-06-01

We present the results of our analyses on dust properties in all of Galactic planetary nebulae based on 5-band broadband images in the far-IR taken with the Herschel Space Observatory.By fitting surface brightness distributions of dust thermal emission at 70, 160, 250, 350 and 500 microns with a single-temperature modified black body function, we derive spatially resolved maps of the dust emissivity power-law index (beta) and dust temperature (Td), as well as the column density.We find that circumstellar dust grains in PNe occupy a specific region in the beta-Td space, which is distinct from that occupied by dust grains in the Interstellar Matter (ISM) and star forming regions (SFRs). Unlike those in the ISM and SFRs, dust grains in PNe exhibit little variation in beta while a large spread in Td, suggesting rather homogeneous dust properties.This work is part of the Herschel Planetary Nebula Survey Plus (HerPlaNS+) supported by the NASA Astrophysics Data Analysis Program.

Synthesis of ZnO nanopencils using wet chemical method and its investigation as LPG sensor

NASA Astrophysics Data System (ADS)

Shimpi, Navinchandra G.; Jain, Shilpa; Karmakar, Narayan; Shah, Akshara; Kothari, D. C.; Mishra, Satyendra

2016-12-01

ZnO nanopencils (NPCs) were prepared by a novel wet chemical process, using triethanolamine (TEA) as a mild base, which is relatively simple and cost effective method as compared to hydrothermal method. ZnO NPCs were characterized using powder X-ray diffraction (XRD), Fourier Transform Infra-Red (FTIR) spectroscopy in mid-IR and far-IR regions, X-ray Photoelectron Spectroscopy (XPS), UV-vis (UV-vis) absorption spectroscopy, room temperature Photoluminescence (PL) spectroscopy and Field Emission Scanning Electron Microscopy (FESEM). ZnO NPCs obtained, were highly pure, uniform and monodispersed.XRD pattern indicated hexagonal unit cell structure with preferred orientation along the c-axis. Sensing behaviour of ZnO NPCs was studied towards Liquefied Petroleum Gas (LPG) at different operating temperatures. The study shows that ZnO NPCs were most sensitive and promising candidate for detection of LPG at 250 °C with gas sensitivity > 60%. The high response towards LPG is due to high surface area of ZnO NPCs and their parallel alignment.

Ligand-tailored single-site silica supported titanium catalysts: Synthesis, characterization and towards cyanosilylation reaction

NASA Astrophysics Data System (ADS)

Xu, Wei; Li, Yani; Yu, Bo; Yang, Jindou; Zhang, Ying; Chen, Xi; Zhang, Guofang; Gao, Ziwei

2015-01-01

A successive anchoring of Ti(NMe2)4, cyclopentadiene and a O-donor ligand, 1-hydroxyethylbenzene (PEA), 1,1‧-bi-2-naphthol (Binol) or 2,3-dihydroxybutanedioic acid diethyl ester (Tartrate), on silica was conducted by SOMC strategy in moderate conditions. The silica, monitored by in-situ Fourier transform infrared spectroscopy (in-situ FT-IR), was pretreated at different temperatures (200, 500 and 800 °C). The ligand tailored silica-supported titanium complexes were characterized by in-situ FT-IR, 13C CP MAS-NMR, X-ray photoelectron spectroscopy (XPS), X-ray absorption near edge structure (XANES) and elemental analysis in detail, verifying that the surface titanium species are single sited. The catalytic activity of the ligand tailored single-site silica supported titanium complexes was evaluated by a cyanosilylation of benzaldehyde. The results showed that the catalytic activity is dependent strongly on the dehydroxylation temperatures of silica and the configuration of the ligands.

The Use of ATLAS Data to Quantify Surface Radiative Budget Alteration Through Urbanization for San Juan, Puerto Rico.

NASA Technical Reports Server (NTRS)

Luvall, Jeffrey C.; Rickman, Douglas L.; Gonzalez, Jorge; Schiller, Steve

2006-01-01

The additional heating of the air over the city is the result of the replacement of naturally vegetated surfaces with those composed of asphalt, concrete, rooftops and other manmade materials. The temperatures of these artificial surfaces can be 20 to 40 0 C higher than vegetated surfaces. Materials such as asphalt store much of the sun s energy and remains hot long after sunset. This produces a dome of elevated air temperatures 5 to 8 C greater over the city, compared to the air temperatures over adjacent rural areas. This effect is called the "urban heat island". Urban landscapes are a complex mixture of vegetated and nonvegetated surfaces. It is difficult to take enough temperature measurements over a large city area to characterize the complexity of urban radiant surface temperature variability. However, the use of remotely sensed thermal data from airborne scanners are ideal for the task. The NASA Airborne Thermal and Land Applications Sensor (ATLAS) operates in the visual and IR bands was used in February 2004 to collect data from San Juan, Puerto Rico with the main objective of investigating the Urban Heat Island (UHI) in tropical cities. In this presentation we will examine the techniques of analyzing remotely sensed data for measuring the effect of various urban surfaces on their contribution to the urban heat island effect. Results from data collected from other US cities of Sacramento, Salt Lake City and Baton Rouge will be used to compare the "urban fabric" among the cities.

Realization of Ru-C Eutectic Point for Evaluation of W-Re and IrRh/Ir Thermocouples

NASA Astrophysics Data System (ADS)

Ogura, H.; Masuyama, S.; Izuchi, M.; Yamazawa, K.; Arai, M.

2015-03-01

Tungsten-rhenium (W-Re) thermocouples are widely used in industry for measurements at high temperatures, up to . Since the electromotive force (emf) of a W-Re thermocouple is known to change during exposure at high temperatures, evaluation of the emf stability is essential for measuring temperature precisely and for realizing precise temperature control used to ensure the quality of products subject to annealing processes. To evaluate precisely the thermoelectric stability around , two Ru-C cells (crucible and Ru-C eutectic alloy) were constructed in our laboratory. The key feature of the cells is that their dimensions are large to ensure there is sufficient immersion available to evaluate the homogeneity characteristics of the thermocouples. By using one of the Ru-C cells, the drift and inhomogeneity of Type C (tungsten-5 % rhenium vs tungsten-26 % rhenium) thermocouples during an exposure to high temperature around were evaluated. Furthermore, to explore possible applications of the eutectic point to other types of high-temperature thermocouples, the drift of an IrRh/Ir thermocouple (iridium-40 % rhodium vs iridium) was also evaluated using another Ru-C cell. The tests with W-Re and IrRh/Ir thermocouples demonstrate that the newly developed Ru-C cells can be used to successfully realize melting plateaux repeatedly. This enables the long-term drift measurements essential for the evaluation and improvement of high-temperature thermocouples. The results obtained in this study will also be useful for evaluating the uncertainty of thermocouple calibrations at around.

Application of DIRI dynamic infrared imaging in reconstructive surgery

NASA Astrophysics Data System (ADS)

Pawlowski, Marek; Wang, Chengpu; Jin, Feng; Salvitti, Matthew; Tenorio, Xavier

2006-04-01

We have developed the BioScanIR System based on QWIP (Quantum Well Infrared Photodetector). Data collected by this sensor are processed using the DIRI (Dynamic Infrared Imaging) algorithms. The combination of DIRI data processing methods with the unique characteristics of the QWIP sensor permit the creation of a new imaging modality capable of detecting minute changes in temperature at the surface of the tissue and organs associated with blood perfusion due to certain diseases such as cancer, vascular disease and diabetes. The BioScanIR System has been successfully applied in reconstructive surgery to localize donor flap feeding vessels (perforators) during the pre-surgical planning stage. The device is also used in post-surgical monitoring of skin flap perfusion. Since the BioScanIR is mobile; it can be moved to the bedside for such monitoring. In comparison to other modalities, the BioScanIR can localize perforators in a single, 20 seconds scan with definitive results available in minutes. The algorithms used include (FFT) Fast Fourier Transformation, motion artifact correction, spectral analysis and thermal image scaling. The BioScanIR is completely non-invasive and non-toxic, requires no exogenous contrast agents and is free of ionizing radiation. In addition to reconstructive surgery applications, the BioScanIR has shown promise as a useful functional imaging modality in neurosurgery, drug discovery in pre-clinical animal models, wound healing and peripheral vascular disease management.

Epitaxial hexagonal boron nitride on Ir(111): A work function template

NASA Astrophysics Data System (ADS)

Schulz, Fabian; Drost, Robert; Hämäläinen, Sampsa K.; Demonchaux, Thomas; Seitsonen, Ari P.; Liljeroth, Peter

2014-06-01

Hexagonal boron nitride (h-BN) is a prominent member in the growing family of two-dimensional materials with potential applications ranging from being an atomically smooth support for other two-dimensional materials to templating growth of molecular layers. We have studied the structure of monolayer h-BN grown by chemical vapor deposition on Ir(111) by low-temperature scanning tunneling microscopy (STM) and spectroscopy (STS) experiments and state-of-the-art density functional theory (DFT) calculations. The lattice mismatch between the h-BN and Ir(111) surface results in the formation of a moiré superstructure with a periodicity of ˜29 Å and a corrugation of ˜0.4 Å. By measuring the field emission resonances above the h-BN layer, we find a modulation of the work function within the moiré unit cell of ˜0.5 eV. DFT simulations for a 13-on-12 h-BN/Ir(111) unit cell confirm our experimental findings and allow us to relate the change in the work function to the subtle changes in the interaction between boron and nitrogen atoms and the underlying substrate atoms within the moiré unit cell. Hexagonal boron nitride on Ir(111) combines weak topographic corrugation with a strong work function modulation over the moiré unit cell. This makes h-BN/Ir(111) a potential substrate for electronically modulated thin film and heterosandwich structures.

Brown adipose tissue thermogenesis does not explain the intra-administration hyperthermic sign-reversal induced by serial administrations of 60% nitrous oxide to rats.

PubMed

Al-Noori, Salwa; Ramsay, Douglas S; Cimpan, Andreas; Maltzer, Zoe; Zou, Jessie; Kaiyala, Karl J

2016-08-01

Initial administration of ≥60% nitrous oxide (N2O) to rats promotes hypothermia primarily by increasing whole-body heat loss. We hypothesized that the drug promotes heat loss via the tail and might initially inhibit thermogenesis via brown adipose tissue (BAT), major organs of thermoregulation in rodents. Following repeated administrations, N2O inhalation evokes hyperthermia underlain by increased whole-body heat production. We hypothesized that elevated BAT thermogenesis plays a role in this thermoregulatory sign reversal. Using dual probe telemetric temperature implants and infrared (IR) thermography, we assessed the effects of nine repeated 60% N2O administrations compared to control (con) administrations on core temperature, BAT temperature, lumbar back temperature and tail temperature. Telemetric core temperature, telemetric BAT temperature, and IR BAT temperature were reduced significantly during initial 60% N2O inhalation (p≤0.001 compared to con). IR thermography revealed that acute N2O administration unexpectedly reduced tail temperature (p=0.0001) and also inhibited IR lumbar temperature (p<0.0001). In the 9th session, N2O inhalation significantly increased telemetric core temperature (p=0.007) indicative of a hyperthermic sign reversal, yet compared to control administrations, telemetric BAT temperature (p=0.86), IR BAT temperature (p=0.85) and tail temperature (p=0.47) did not differ significantly. Thus, an initial administration of 60% N2O at 21°C may promote hypothermia via reduced BAT thermogenesis accompanied by tail vasoconstriction as a compensatory mechanism to limit body heat loss. Following repeated N2O administrations rats exhibit a hyperthermic core temperature but a normalized BAT temperature, suggesting induction of a hyperthermia-promoting thermogenic adaptation of unknown origin. Copyright © 2016 Elsevier Ltd. All rights reserved.

X-ray reflectometry and simulation of the parameters of SiC epitaxial films on Si(111), grown by the atomic substitution method

NASA Astrophysics Data System (ADS)

Kukushkin, S. A.; Nussupov, K. Kh.; Osipov, A. V.; Beisenkhanov, N. B.; Bakranova, D. I.

2017-05-01

The structure and composition of SiC nanolayers are comprehensively studied by X-ray reflectometry, IR-spectroscopy, and atomic-force microscopy (AFM) methods for the first time. SiC films were synthesized by the new method of topochemical substitution of substrate atoms at various temperatures and pressure of CO active gas on the surface of high-resistivity low-dislocation single-crystal n-type silicon (111). Based on an analysis and generalization of experimental data obtained using X-ray reflectometry, IR spectroscopy, and AFM methods, a structural model of SiC films on Si was proposed. According to this model, silicon carbide film consists of a number of layers parallel to the substrate, reminiscent of a layer cake. The composition and thickness of each layer entering the film structure is experimentally determined. It was found that all samples contain superstoichiometric carbon; however, its structure is significantly different for the samples synthesized at temperatures of 1250 and 1330°C, respectively. In the former case, the film surface is saturated with silicon vacancies and carbon in the structurally loose form reminiscent of HOPG carbon. In the films grown at 1330°C, carbon is in a dense structure with a close-to-diamond density.

Material of LAPAN's thermal IR camera equipped with two microbolometers in one aperture

NASA Astrophysics Data System (ADS)

Bustanul, A.; Irwan, P.; Andi M., T.

2017-11-01

Besides the wavelength used, there is another factor that we have to notice in designing an optical system. It is material used which is correct for the spectral bands determined. Basically, due the limitation of the available range and expensive, choosing and determining materials for Infra Red (IR) wavelength are more difficult and complex rather than visible spectrum. We also had the same problem while designing our thermal IR camera equipped with two microbolometers sharing aperture. Two spectral bands, 3 - 4 μm (MWIR) and 8 - 12 μm (LWIR), have been decided to be our thermal IR camera spectrum to address missions, i.e., peat land fire, volcanoes activities, and Sea Surface Temperature (SST). Referring those bands, we chose the appropriate material for LAPAN's IR camera optics. This paper describes material of LAPAN's IR camera equipped with two microbolometer in one aperture. First of all, we were learning and understanding of optical materials properties all matters of IR technology including its bandwidths. Considering some aspects, i.e., Transmission, Index of Refraction, Thermal properties covering the index gradient and coefficient of thermal expansion (CTE), the analysis then has been accomplished. Moreover, we were utilizing a commercial software, Thermal Desktop/Sinda Fluint, to strengthen the process. Some restrictions such as space environment, low cost, and performance mainly durability and transmission, were also cared throughout the trade off the works. The results of all those analysis, either in graphs or in measurement, indicate that the lens of LAPAN's IR camera with sharing aperture is based on Germanium/Zinc Selenide materials.

Mercury Underpotential Deposition to Determine Iridium and Iridium Oxide Electrochemical Surface Areas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alia, Shaun M.; Hurst, Katherine E.; Kocha, Shyam S.

Determining the surface areas of electrocatalysts is critical for separating the key properties of area-specific activity and electrochemical surface area from mass activity. Hydrogen underpotential deposition and carbon monoxide oxidation are typically used to evaluate iridium (Ir) surface areas, but are ineffective on oxides and can be sensitive to surface oxides formed on Ir metals. Mercury underpotential deposition is presented in this study as an alternative, able to produce reasonable surface areas on Ir and Ir oxide nanoparticles, and able to produce similar surface areas prior to and following characterization in oxygen evolution. Reliable electrochemical surface areas allow for comparativemore » studies of different catalyst types and the characterization of advanced oxygen evolution catalysts. Lastly, they also enable the study of catalyst degradation in durability testing, both areas of increasing importance within electrolysis and electrocatalysis.« less

Mercury Underpotential Deposition to Determine Iridium and Iridium Oxide Electrochemical Surface Areas

DOE PAGES

Alia, Shaun M.; Hurst, Katherine E.; Kocha, Shyam S.; ...

2016-06-02

Determining the surface areas of electrocatalysts is critical for separating the key properties of area-specific activity and electrochemical surface area from mass activity. Hydrogen underpotential deposition and carbon monoxide oxidation are typically used to evaluate iridium (Ir) surface areas, but are ineffective on oxides and can be sensitive to surface oxides formed on Ir metals. Mercury underpotential deposition is presented in this study as an alternative, able to produce reasonable surface areas on Ir and Ir oxide nanoparticles, and able to produce similar surface areas prior to and following characterization in oxygen evolution. Reliable electrochemical surface areas allow for comparativemore » studies of different catalyst types and the characterization of advanced oxygen evolution catalysts. Lastly, they also enable the study of catalyst degradation in durability testing, both areas of increasing importance within electrolysis and electrocatalysis.« less

Anionic 11-mercaptoundecanoic acid capped ZnO nanoparticles

NASA Astrophysics Data System (ADS)

Šimšíková, Michaela; Antalík, Marián; Kaňuchová, Mária; Škvarla, Jiří

2013-10-01

The anionic zinc oxide nanoparticles have been prepared at room temperature by a precipitation method using ZnCl2 and NaOH and surface modification with 11-mercaptoundecanoic acid (MUA). Atomic force microscopy (AFM) was used for definition of morphology and size of prepared nanoparticles which was proved by measurements of particle size distribution using Zetasizer. Successful coating with MUA as surfactant was acknowledged by X-ray photoelectron spectroscopy and ATR FT-IR spectroscopy. The isoelectric point (IEP) of ZnO-MUA nanoparticles was obtained by measurements of zeta potential and FT-IR dependence on pH; the obtained value was approximately 3.58. The value of exchanged protons was 2.88 which indicates a positive binding cooperativity of modified nanoparticles.

Surface Modified TiO2 Obscurants for Increased Safety and Performance

DTIC Science & Technology

2012-11-01

based obscurant devices in performance. 15. SUBJECT TERMS Obscurant, visible, IR , smoke, TiO2, aerosol, particle, surface modification...hexamethyldimethoxysilane IR Infrared wavelength LabRAM Lab scale Resonant Acoustic Mixer from Resodyn Corporation LPM Liters Per Minute M106 Currently fielded (Army...trinitrophloroglucinol UV-Vis Ultraviolet-visible wavelengths KEYWORDS Obscurant, visible, IR , smoke, TiO2, aerosol, particle, surface modification

Spitzer IRS (8-30 micron) Spectra of Basaltic Asteroids 1459 Magnya and 956 Elisa: Mineralogy and Thermal Properties

NASA Technical Reports Server (NTRS)

Lim, Lucy F.; Emery, J. P.; Moskovitz, N. A.

2009-01-01

We report preliminary results from Spitzer IRS (Infrared Spectrograph) spectroscopy of 956 Elisa, 1459 Magnya, and other small basaltic asteroids with the Spitzer IRS. Program targets include members of the dynamical family of the unique large differentiated asteroid 4 Vesta ("Vestoids"), several outer-main-belt basaltic asteroids whose orbits exclude them from originating on 4 Vesta, and the basaltic near-Earth asteroid 4055 Magellan. The preliminary thermal model (STM) fit to the 5--35 micron spectrum of 956 Elisa gives a radius of 5.4 +/- 0.3 km and a subsolar- point temperature of 282.2 +/- 0.5 K. This temperature corresponds to eta approximately equals 1.06 +/- 0.02, which is substantially higher than the eta approximately equals 0.756 characteristic of large main-belt asteroids. Unlike 4 Vesta and other large asteroids, therefore, 956 Elisa has significant thermal inertia in its surface layer. The wavelength of the Christiansen feature (emissivity maximum near 9 micron), the positions and shapes of the narrow maxima (10 micron, 11 micron) within the broad 9--14 micron silicate band, and the 19--20 micron minimum are consistent with features found in the laboratory spectra of diogenites and of low-Ca pyroxenes of similar composition (Wo<5, En50-En75).

Surface enrichment of Pt in stable Pt-Ir nano-alloy particles on MgAl 2O 4 spinel in oxidizing atmosphere

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Wei -Zhen; Nie, Lei; Cheng, Yingwen

With the capability of MgAl 2O 4 spinel {111} nano-facets in stabilizing small Rh, Ir and Pt particles, bimetallic Ir-Pt catalysts on the same support were investigated in this paper, aiming at further lowering the catalyst cost by substituting expensive Pt with cheaper Ir in the bulk. Small Pt-Ir nano-alloy particles (< 2 nm) were successfully stabilized on the spinel {111} nano-facets as expected. Interestingly, methanol oxidative dehydrogenation (ODH) rate on the surface Pt atoms increases with oxidizing aging but decreases upon reducing treatment, where Ir is almost inactive under the same reaction conditions. Up to three times enhancement inmore » Pt exposure was achieved when the sample was oxidized at 800 °C in air for 1 week and subsequently reduced by H 2 for 2 h, demonstrating successful surface enrichment of Pt on Pt-Ir nano-alloy particles. Finally, a dynamic stabilization mechanism involving wetting/nucleation seems to be responsible for the evolution of surface compositions upon cyclic oxidizing and reducing thermal treatments.« less

Surface enrichment of Pt in stable Pt-Ir nano-alloy particles on MgAl 2O 4 spinel in oxidizing atmosphere

DOE PAGES

Li, Wei -Zhen; Nie, Lei; Cheng, Yingwen; ...

2017-01-13

With the capability of MgAl 2O 4 spinel {111} nano-facets in stabilizing small Rh, Ir and Pt particles, bimetallic Ir-Pt catalysts on the same support were investigated in this paper, aiming at further lowering the catalyst cost by substituting expensive Pt with cheaper Ir in the bulk. Small Pt-Ir nano-alloy particles (< 2 nm) were successfully stabilized on the spinel {111} nano-facets as expected. Interestingly, methanol oxidative dehydrogenation (ODH) rate on the surface Pt atoms increases with oxidizing aging but decreases upon reducing treatment, where Ir is almost inactive under the same reaction conditions. Up to three times enhancement inmore » Pt exposure was achieved when the sample was oxidized at 800 °C in air for 1 week and subsequently reduced by H 2 for 2 h, demonstrating successful surface enrichment of Pt on Pt-Ir nano-alloy particles. Finally, a dynamic stabilization mechanism involving wetting/nucleation seems to be responsible for the evolution of surface compositions upon cyclic oxidizing and reducing thermal treatments.« less

Marginal Ice Zone Processes Observed from Unmanned Aerial Systems

NASA Astrophysics Data System (ADS)

Zappa, C. J.

2015-12-01

Recent years have seen extreme changes in the Arctic. Marginal ice zones (MIZ), or areas where the "ice-albedo feedback" driven by solar warming is highest and ice melt is extensive, may provide insights into the extent of these changes. Furthermore, MIZ play a central role in setting the air-sea CO2 balance making them a critical component of the global carbon cycle. Incomplete understanding of how the sea-ice modulates gas fluxes renders it difficult to estimate the carbon budget in MIZ. Here, we investigate the turbulent mechanisms driving mixing and gas exchange in leads, polynyas and in the presence of ice floes using both field and laboratory measurements. Measurements from unmanned aerial systems (UAS) in the marginal ice zone were made during 2 experiments: 1) North of Oliktok Point AK in the Beaufort Sea were made during the Marginal Ice Zone Ocean and Ice Observations and Processes EXperiment (MIZOPEX) in July-August 2013 and 2) Fram Strait and Greenland Sea northwest of Ny-Ålesund, Svalbard, Norway during the Air-Sea-Ice Physics and Biogeochemistry Experiment (ASIPBEX) April - May 2015. We developed a number of new payloads that include: i) hyperspectral imaging spectrometers to measure VNIR (400-1000 nm) and NIR (900-1700 nm) spectral radiance; ii) net longwave and net shortwave radiation for ice-ocean albedo studies; iii) air-sea-ice turbulent fluxes as well as wave height, ice freeboard, and surface roughness with a LIDAR; and iv) drone-deployed micro-drifters (DDµD) deployed from the UAS that telemeter temperature, pressure, and RH as it descends through the atmosphere and temperature and salinity of the upper meter of the ocean once it lands on the ocean's surface. Visible and IR imagery of melting ice floes clearly defines the scale of the ice floes. The IR imagery show distinct cooling of the skin sea surface temperature (SST) as well as an intricate circulation and mixing pattern that depends on the surface current, wind speed, and near-surface vertical temperature/salinity structure. Individual ice floes develop turbulent wakes as they drift and cause transient mixing of an influx of colder surface (fresh) melt water. We capture a melting and mixing event that explains the changing pattern observed in skin SST and is substantiated using laboratory experiments.

Quantifying the clear-sky bias of satellite-derived infrared LST

NASA Astrophysics Data System (ADS)

Ermida, S. L.; Trigo, I. F.; DaCamara, C.

2017-12-01

Land surface temperature (LST) is one of the most relevant parameters when addressing the physical processes that take place at the surface of the Earth. Satellite data are particularly appropriate for measuring LST over the globe with high temporal resolution. Remote-sensed LST estimation from space-borne sensors has been systematically performed over the Globe for nearly 3 decades and geostationary LST climate data records are now available. The retrieval of LST from satellite observations generally relies on measurements in the thermal infrared (IR) window. Although there is a large number of IR sensors on-board geostationary satellites and polar orbiters suitable for LST retrievals with different temporal and spatial resolutions, the use of IR observations limits LST estimates to clear sky conditions. As a consequence, climate studies based on IR LST are likely to be affected by the restriction of LST data to cloudless conditions. However, such "clear sky bias" has never been quantified and, therefore, the actual impact of relying only on clear sky data is still to be determined. On the other hand, an "all-weather" global LST database may be set up based on passive microwave (MW) measurements which are much less affected by clouds. An 8-year record of all-weather MW LST is here used to quantify the clear-sky bias of IR LST at global scale based on MW observations performed by the Advanced Microwave Scanning Radiometer-Earth Observing System (AMSR-E) onboard NASA's Aqua satellite. Selection of clear-sky and cloudy pixels is based on information derived from measurements performed by the Moderate Resolution Imaging Spectroradiometer (MODIS) on-board the same satellite.

Ligand-tailored single-site silica supported titanium catalysts: Synthesis, characterization and towards cyanosilylation reaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, Wei; Li, Yani; Yu, Bo

2015-01-15

A successive anchoring of Ti(NMe{sub 2}){sub 4}, cyclopentadiene and a O-donor ligand, 1-hydroxyethylbenzene (PEA), 1,1′-bi-2-naphthol (Binol) or 2,3-dihydroxybutanedioic acid diethyl ester (Tartrate), on silica was conducted by SOMC strategy in moderate conditions. The silica, monitored by in-situ Fourier transform infrared spectroscopy (in-situ FT-IR), was pretreated at different temperatures (200, 500 and 800 °C). The ligand tailored silica-supported titanium complexes were characterized by in-situ FT-IR, {sup 13}C CP MAS-NMR, X-ray photoelectron spectroscopy (XPS), X-ray absorption near edge structure (XANES) and elemental analysis in detail, verifying that the surface titanium species are single sited. The catalytic activity of the ligand tailored single-sitemore » silica supported titanium complexes was evaluated by a cyanosilylation of benzaldehyde. The results showed that the catalytic activity is dependent strongly on the dehydroxylation temperatures of silica and the configuration of the ligands. - Graphical abstract: The ligand-tailored silica supported “single site” titanium complexes were synthesized by SOMC strategy and fully characterized. Their catalytic activity were evaluated by benzaldehyde silylcyanation. - Highlights: • Single-site silica supported Ti active species was prepared by SOMC technique. • O-donor ligand tailored Ti surface species was synthesized. • The surface species was characterized by XPS, {sup 13}C CP-MAS NMR, XANES etc. • Catalytic activity of the Ti active species in silylcyanation reaction was evaluated.« less

Mock Target Window OTR and IR Design and Testing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wass, Alexander Joseph

In order to fully verify temperature measurements made on the target window using infrared (IR) optical non-contact methods, actual comparative measurements are made with a real beam distribution as the heat source using Argonne National Laboratory’s (ANL) 35 MeV electron accelerator. Using Monte Carlo N-Particle (MCNP) simulations and thermal Finite Element Analysis (FEA), a cooled mock target window with thermocouple implants is designed to be used in such a test to achieve window temperatures up to 700°C. An uncoated and blackcoated mock window is designed to enhance the IR temperature measurements and verify optical transmitted radiation (OTR) imagery. This allowsmore » us to fully verify and characterize our temperature accuracy with our current IR camera method and any future method we may wish to explore using actual production conditions. This test also provides us with valuable conclusions/concerns regarding the calibration method we developed using our IR test stand at TA-53 in MPF-14.« less

IRS-1 acts as an endocytic regulator of IGF-I receptor to facilitate sustained IGF signaling.

PubMed

Yoneyama, Yosuke; Lanzerstorfer, Peter; Niwa, Hideaki; Umehara, Takashi; Shibano, Takashi; Yokoyama, Shigeyuki; Chida, Kazuhiro; Weghuber, Julian; Hakuno, Fumihiko; Takahashi, Shin-Ichiro

2018-04-11

Insulin-like growth factor-I receptor (IGF-IR) preferentially regulates the long-term IGF activities including growth and metabolism. Kinetics of ligand-dependent IGF-IR endocytosis determines how IGF induces such downstream signaling outputs. Here, we find that the insulin receptor substrate (IRS)-1 modulates how long ligand-activated IGF-IR remains at the cell surface before undergoing endocytosis in mammalian cells. IRS-1 interacts with the clathrin adaptor complex AP2. IRS-1, but not an AP2-binding-deficient mutant, delays AP2-mediated IGF-IR endocytosis after the ligand stimulation. Mechanistically, IRS-1 inhibits the recruitment of IGF-IR into clathrin-coated structures; for this reason, IGF-IR avoids rapid endocytosis and prolongs its activity on the cell surface. Accelerating IGF-IR endocytosis via IRS-1 depletion induces the shift from sustained to transient Akt activation and augments FoxO-mediated transcription. Our study establishes a new role for IRS-1 as an endocytic regulator of IGF-IR that ensures sustained IGF bioactivity, independent of its classic role as an adaptor in IGF-IR signaling. © 2018, Yoneyama et al.

IRS-1 acts as an endocytic regulator of IGF-I receptor to facilitate sustained IGF signaling

PubMed Central

Yoneyama, Yosuke; Lanzerstorfer, Peter; Niwa, Hideaki; Umehara, Takashi; Shibano, Takashi; Yokoyama, Shigeyuki; Chida, Kazuhiro; Weghuber, Julian

2018-01-01

Insulin-like growth factor-I receptor (IGF-IR) preferentially regulates the long-term IGF activities including growth and metabolism. Kinetics of ligand-dependent IGF-IR endocytosis determines how IGF induces such downstream signaling outputs. Here, we find that the insulin receptor substrate (IRS)−1 modulates how long ligand-activated IGF-IR remains at the cell surface before undergoing endocytosis in mammalian cells. IRS-1 interacts with the clathrin adaptor complex AP2. IRS-1, but not an AP2-binding-deficient mutant, delays AP2-mediated IGF-IR endocytosis after the ligand stimulation. Mechanistically, IRS-1 inhibits the recruitment of IGF-IR into clathrin-coated structures; for this reason, IGF-IR avoids rapid endocytosis and prolongs its activity on the cell surface. Accelerating IGF-IR endocytosis via IRS-1 depletion induces the shift from sustained to transient Akt activation and augments FoxO-mediated transcription. Our study establishes a new role for IRS-1 as an endocytic regulator of IGF-IR that ensures sustained IGF bioactivity, independent of its classic role as an adaptor in IGF-IR signaling. PMID:29661273

Coupled heat transfer model and experiment study of semitransparent barrier materials in aerothermal environment

NASA Astrophysics Data System (ADS)

Wang, Da-Lin; Qi, Hong

Semi-transparent materials (such as IR optical windows) are widely used for heat protection or transfer, temperature and image measurement, and safety in energy , space, military, and information technology applications. They are used, for instance, ceramic coatings for thermal barriers of spacecrafts or gas turbine blades, and thermal image observation under extreme or some dangerous environments. In this paper, the coupled conduction and radiation heat transfer model is established to describe temperature distribution of semitransparent thermal barrier medium within the aerothermal environment. In order to investigate this numerical model, one semi-transparent sample with black coating was considered, and photothermal properties were measured. At last, Finite Volume Method (FVM) was used to solve the coupled model, and the temperature responses from the sample surfaces were obtained. In addition, experiment study was also taken into account. In the present experiment, aerodynamic heat flux was simulated by one electrical heater, and two experiment cases were designed in terms of the duration of aerodynamic heating. One case is that the heater irradiates one surface of the sample continually until the other surface temperature up to constant, and the other case is that the heater works only 130 s. The surface temperature responses of these two cases were recorded. Finally, FVM model of the coupling conduction-radiation heat transfer was validated based on the experiment study with relative error less than 5%.

Synthesis of monoclinic IrTe 2 under high pressure and its physical properties

DOE PAGES

Li, X.; Yan, J. -Q.; Singh, D. J.; ...

2015-10-12

In a pressure-temperature (P-T) diagram for synthesizing IrTe 2 compounds, the well-studied trigonal (H) phase with the CdI 2-type structure is stable at low pressures. The superconducting cubic (C) phase can be synthesized under higher temperatures and pressures. A rhombohedral phase with the crystal structure similar to the C phase can be made at ambient pressure; but the phase contains a high concentration of Ir deficiency. Here, we report that a rarely studied monoclinic (M) phase can be stabilized in narrow ranges of pressure and temperature in this P-T diagram. Moreover, the peculiar crystal structure of the M-IrTe 2 eliminatesmore » the tendency to form Ir-Ir dimers found in the H phase. The M phase has been fully characterized by structural determination and measurements of electrical resistivity, thermoelectric power, DC magnetization, and specific heat. These physical properties have been compared with those in the H and C phases of Ir 1-xTe 2. Finally, we present magnetic and transport properties and specific heat of the M-IrTe 2 can be fully justified by calculations with the density-functional theory.« less

Infrared imaging: a potential powerful tool for neuroimaging and neurodiagnostics

PubMed Central

Khoshakhlagh, Arezou; Gunapala, Sarath D.

2017-01-01

Abstract. Infrared (IR) imaging is used to detect the subtle changes in temperature needed to accurately detect and monitor disease. Technological advances have made IR a highly sensitive and reliable detection tool with strong potential in medical and neurophotonics applications. An overview of IR imaging specifically investigating quantum well IR detectors developed at Jet Propulsion Laboratory for a noninvasive, nonradiating imaging tool is provided, which could be applied for neuroscience and neurosurgery where it involves sensitive cellular temperature change. PMID:28382311

On the seasonal phytoplankton concentration and sea surface temperature cycles of the Gulf of Mexico as determined by satellites

NASA Technical Reports Server (NTRS)

Mueller-Karger, Frank E.; Walsh, John J.; Meyers, Mark B.; Evans, Robert H.

1991-01-01

Multiyear series of coastal zone color scanner (CZCS) and AVHRR observations are presently used to derive monthly climatologies of near-surface phytoplankton pigment concentration and SST for the Gulf of Mexico; these, in combination with 1946-1987 SST data and NOAA hydrographic profile data covering 1914-1985, show that the most important single factor controlling seasonal cycle surface-pigment concentration is the depth of the mixed layer. The CZCS images indicate that seasonal variation seaward of the continental shelf is synchronous throughout the Gulf. The combination of ocean color and IR images allows year-round observation of surface circulation spatial structure in the Gulf, as well as of the dispersal pattern of the Mississippi River's plume.

pH Mapping on Tooth Surfaces for Quantitative Caries Diagnosis Using Micro Ir/IrOx pH Sensor.

PubMed

Ratanaporncharoen, Chindanai; Tabata, Miyuki; Kitasako, Yuichi; Ikeda, Masaomi; Goda, Tatsuro; Matsumoto, Akira; Tagami, Junji; Miyahara, Yuji

2018-04-03

A quantitative diagnostic method for dental caries would improve oral health, which directly affects the quality of life. Here we describe the preparation and application of Ir/IrOx pH sensors, which are used to measure the surface pH of dental caries. The pH level is used as an indicator to distinguish between active and arrested caries. After a dentist visually inspected and defined 18 extracted dentinal caries at various positions as active or arrested caries, the surface pH values of sound and caries areas were directly measured with an Ir/IrOx pH sensor with a diameter of 300 μm as a dental explorer. The average pH values of the sound root, the arrested caries, and active caries were 6.85, 6.07, and 5.30, respectively. The pH obtained with an Ir/IrOx sensor was highly correlated with the inspection results by the dentist, indicating that the types of caries were successfully categorized. This caries testing technique using a micro Ir/IrOx pH sensor provides an accurate quantitative caries evaluation and has potential in clinical diagnosis.

Theoretical framework for quantitatively estimating ultrasound beam intensities using infrared thermography.

PubMed

Myers, Matthew R; Giridhar, Dushyanth

2011-06-01

In the characterization of high-intensity focused ultrasound (HIFU) systems, it is desirable to know the intensity field within a tissue phantom. Infrared (IR) thermography is a potentially useful method for inferring this intensity field from the heating pattern within the phantom. However, IR measurements require an air layer between the phantom and the camera, making inferences about the thermal field in the absence of the air complicated. For example, convection currents can arise in the air layer and distort the measurements relative to the phantom-only situation. Quantitative predictions of intensity fields based upon IR temperature data are also complicated by axial and radial diffusion of heat. In this paper, mathematical expressions are derived for use with IR temperature data acquired at times long enough that noise is a relatively small fraction of the temperature trace, but small enough that convection currents have not yet developed. The relations were applied to simulated IR data sets derived from computed pressure and temperature fields. The simulation was performed in a finite-element geometry involving a HIFU transducer sonicating upward in a phantom toward an air interface, with an IR camera mounted atop an air layer, looking down at the heated interface. It was found that, when compared to the intensity field determined directly from acoustic propagation simulations, intensity profiles could be obtained from the simulated IR temperature data with an accuracy of better than 10%, at pre-focal, focal, and post-focal locations. © 2011 Acoustical Society of America

A high-temperature, ambient-pressure ultra-dry operando reactor cell for Fourier-transform infrared spectroscopy

NASA Astrophysics Data System (ADS)

Köck, Eva-Maria; Kogler, Michaela; Pramsoler, Reinhold; Klötzer, Bernhard; Penner, Simon

2014-08-01

The construction of a newly designed high-temperature, high-pressure FT-IR reaction cell for ultra-dry in situ and operando operation is reported. The reaction cell itself as well as the sample holder is fully made of quartz glass, with no hot metal or ceramic parts in the vicinity of the high-temperature zone. Special emphasis was put on chemically absolute water-free and inert experimental conditions, which includes reaction cell and gas-feeding lines. Operation and spectroscopy up to 1273 K is possible, as well as pressures up to ambient conditions. The reaction cell exhibits a very easy and variable construction and can be adjusted to any available FT-IR spectrometer. Its particular strength lies in its possibility to access and study samples under very demanding experimental conditions. This includes studies at very high temperatures, e.g., for solid-oxide fuel cell research or studies where the water content of the reaction mixtures must be exactly adjusted. The latter includes all adsorption studies on oxide surfaces, where the hydroxylation degree is of paramount importance. The capability of the reaction cell will be demonstrated for two selected examples where information and in due course a correlation to other methods can only be achieved using the presented setup.

A high-temperature, ambient-pressure ultra-dry operando reactor cell for Fourier-transform infrared spectroscopy.

PubMed

Köck, Eva-Maria; Kogler, Michaela; Pramsoler, Reinhold; Klötzer, Bernhard; Penner, Simon

2014-08-01

The construction of a newly designed high-temperature, high-pressure FT-IR reaction cell for ultra-dry in situ and operando operation is reported. The reaction cell itself as well as the sample holder is fully made of quartz glass, with no hot metal or ceramic parts in the vicinity of the high-temperature zone. Special emphasis was put on chemically absolute water-free and inert experimental conditions, which includes reaction cell and gas-feeding lines. Operation and spectroscopy up to 1273 K is possible, as well as pressures up to ambient conditions. The reaction cell exhibits a very easy and variable construction and can be adjusted to any available FT-IR spectrometer. Its particular strength lies in its possibility to access and study samples under very demanding experimental conditions. This includes studies at very high temperatures, e.g., for solid-oxide fuel cell research or studies where the water content of the reaction mixtures must be exactly adjusted. The latter includes all adsorption studies on oxide surfaces, where the hydroxylation degree is of paramount importance. The capability of the reaction cell will be demonstrated for two selected examples where information and in due course a correlation to other methods can only be achieved using the presented setup.

In situ Fourier transform infrared (FTIR) investigation of CO{sub 2} adsorption onto zeolite materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robert W. Stevens Jr.; Ranjani V. Siriwardane; Jennifer Logan

2008-09-15

The adsorption of CO{sub 2} onto five zeolite materials (13X, WEG, AGP, 4A, and 5A) was studied by in situ infrared spectroscopy at 1 atm as a function of the pretreatment temperature (120 and 350{sup o}C) and adsorption temperature (30 and 120{sup o}C). Adsorbed CO{sub 2} surface species identified in the current work include physisorbed CO{sub 2}, bidentate carbonate, bridged bidentate carbonate, monodentate carbonate, and carboxylate. Both pretreatment temperature and CO{sub 2} adsorption temperature affected the type and amount of adsorbed CO{sub 2} species formed. Materials pretreated at 350{sup o}C, as opposed to 120{sup o}C, had more surface adsorption sitesmore » available as evidenced from the resulting more intense IR bands. Physisorbed CO{sub 2} was the most abundant species observed. Bridged bidentate carbonate was found to be more stable than bidentate carbonate. Tests involving both CO{sub 2} and H{sub 2}O showed that the two species competed for the same adsorption sites on the zeolite surface. 18 refs., 15 figs., 1 tab.« less

Spatial and Temporal Variabilities of Solar and Longwave Radiation Fluxes below a Coniferous Forest in the French Alps

NASA Astrophysics Data System (ADS)

Sicart, J. E.; Ramseyer, V.; Lejeune, Y.; Essery, R.; Webster, C.; Rutter, N.

2017-12-01

At high altitudes and latitudes, snow has a large influence on hydrological processes. Large fractions of these regions are covered by forests, which have a strong influence on snow accumulation and melting processes. Trees absorb a large part of the incoming shortwave radiation and this heat load is mostly dissipated as longwave radiation. Trees shelter the snow surface from wind, so sub-canopy snowmelt depends mainly on the radiative fluxes: vegetation attenuates the transmission of shortwave radiation but enhances longwave irradiance to the surface. An array of 13 pyranometers and 11 pyrgeometers was deployed on the snow surface below a coniferous forest at the CEN-MeteoFrance Col de Porte station in the French Alps (1325 m asl) during the 2017 winter in order to investigate spatial and temporal variabilities of solar and infrared irradiances in different meteorological conditions. Sky view factors measured with hemispherical photographs at each radiometer location were in a narrow range from 0.2 to 0.3. The temperature of the vegetation was measured with IR thermocouples and an IR camera. In clear sky conditions, the attenuation of solar radiation by the canopy reached 96% and its spatial variability exceeded 100 W m-2. Longwave irradiance varied by 30 W m-2 from dense canopy to gap areas. In overcast conditions, the spatial variabilities of solar and infrared irradiances were reduced and remained closely related to the sky view factor. A simple radiative model taking into account the penetration through the canopy of the direct and diffuse solar radiation, and isotropic infrared emission of the vegetation as a blackbody emitter, accurately reproduced the dynamics of the radiation fluxes at the snow surface. Model results show that solar transmissivity of the canopy in overcast conditions is an excellent proxy of the sky view factor and the emitting temperature of the vegetation remained close to the air temperature in this typically dense Alpine forest.

Method and apparatus for real time weld monitoring

DOEpatents

Leong, Keng H.; Hunter, Boyd V.

1997-01-01

An improved method and apparatus are provided for real time weld monitoring. An infrared signature emitted by a hot weld surface during welding is detected and this signature is compared with an infrared signature emitted by the weld surface during steady state conditions. The result is correlated with weld penetration. The signal processing is simpler than for either UV or acoustic techniques. Changes in the weld process, such as changes in the transmitted laser beam power, quality or positioning of the laser beam, change the resulting weld surface features and temperature of the weld surface, thereby resulting in a change in the direction and amount of infrared emissions. This change in emissions is monitored by an IR sensitive detecting apparatus that is sensitive to the appropriate wavelength region for the hot weld surface.

Recent Rapid Decline of the Arctic Winter Sea Ice in the Barents-Kara Seas Owing to Combined Effects of the Ural Blocking and SST

NASA Astrophysics Data System (ADS)

Luo, Binhe; Yao, Yao

2018-04-01

This study investigates why the Arctic winter sea ice loss over the Barents-Kara Seas (BKS) is accelerated in the recent decade. We first divide 1979-2013 into two time periods: 1979-2000 (P1) and 2001-13 (P2), with a focus on P2 and the difference between P1 and P2. The results show that during P2, the rapid decline of the sea ice over the BKS is related not only to the high sea surface temperature (SST) over the BKS, but also to the increased frequency, duration, and quasi-stationarity of the Ural blocking (UB) events. Observational analysis reveals that during P2, the UB tends to become quasi stationary and its frequency tends to increase due to the weakening (strengthening) of zonal winds over the Eurasia (North Atlantic) when the surface air temperature (SAT) anomaly over the BKS is positive probably because of the high SST. Strong downward infrared (IR) radiation is seen to occur together with the quasi-stationary and persistent UB because of the accumulation of more water vapor over the BKS. Such downward IR favors the sea ice decline over the BKS, although the high SST over the BKS plays a major role. But for P1, the UB becomes westward traveling due to the opposite distribution of zonal winds relative to P2, resulting in weak downward IR over the BKS. This may lead to a weak decline of the sea ice over the BKS. Thus, it is likely that the rapid decline of the sea ice over the BKS during P2 is attributed to the joint effects of the high SST over the BKS and the quasi-stationary and long-lived UB events.

Cell-polymer interactions of fluorescent polystyrene latex particles coated with thermosensitive poly(N-isopropylacrylamide) and poly(N-vinylcaprolactam) or grafted with poly(ethylene oxide)-macromonomer.

PubMed

Vihola, Henna; Marttila, Anna-Kaisa; Pakkanen, Jukka S; Andersson, Mirja; Laukkanen, Antti; Kaukonen, Ann Marie; Tenhu, Heikki; Hirvonen, Jouni

2007-10-01

Cell-polymer interactions of thermosensitive poly(N-isopropylacrylamide) (PNIPAM) or poly(N-vinylcaprolactam) (PVCL) coated particles with RAW264.7 macrophages and intestinal Caco-2 cells were evaluated. Nanosized particles were prepared by modifying the surface of fluorescent polystyrene (FPS) particles with the thermosensitive polymer gels or with poly(ethylene oxide) (PEO)-macromonomer grafts. The particles were characterized by IR-spectroscopy for functional groups, light scattering for size distribution and zeta-potential for surface charge. Effects of temperature and polymer coating/grafting on the cellular interactions were evaluated by cell association/uptake and visualized by confocal scanning microscope. PEO and PNIPAM inhibited the polymer-cell contact by steric repulsion, evidenced by weak attachment of the particles. PVCL-coated FPS was adsorbed on the cells more strongly, especially at 37 degrees C, because of more hydrophobic nature at higher temperatures. The results suggest feasibility of the PNIPAM and PVCL for biotechnological/pharmaceutical applications, as the cell-particle interactions may be modified by size, surface charge, hydrophobicity, steric repulsion and temperature.

Sorption-desorption of fipronil in some soils, as influenced by ionic strength, pH and temperature.

PubMed

Singh, Anand; Srivastava, Anjana; Srivastava, Prakash C

2016-08-01

The sorption-desorpion of fipronil insecticide is influenced by soil properties and variables such as pH, ionic strength, temperature, etc. A better understanding of soil properties and these variables in sorption-desorption processes by quantification of fipronil using liquid chromatography may help to optimise suitable soil management to reduce contamination of surface and groundwaters. In the present investigation, the sorption-desorption of fipronil was studied in some soils at varying concentrations, ionic strengths, temperatures and pH values, and IR specta of fipronil sorbed onto soils were studied. The sorption of fipronil onto soils conformed to the Freundlich isotherm model. The sorption-desorption of fipronil varied with ionic strength in each of the soils. Sorption decreased but desorption increased with temperature. Sorption did not change with increasing pH, but for desorption there was no correlation. The cumulative desorption of fipronil from soil was significantly and inversely related to soil organic carbon content. IR spectra of sorbed fipronil showed the involvement of amino, nitrile, sulfone, chloro and fluoro groups and the pyrazole nucleus of the fipronil molecule. The sorption of fipronil onto soils appeared to be a physical process with the involvement of hydrogen bonding. An increase in soil organic carbon may help to reduce desorption of fipronil. High-temperature regimes are more conducive to the desorption. © 2015 Society of Chemical Industry. © 2015 Society of Chemical Industry.

Transient thermography testing of unpainted thermal barrier coating surfaces

NASA Astrophysics Data System (ADS)

Ptaszek, Grzegorz; Cawley, Peter; Almond, Darryl; Pickering, Simon

2013-01-01

This paper has investigated the effects of uneven surface discolouration of a thermal barrier coating (TBC) and of its IR translucency on the thermal responses observed by using mid and long wavelength IR cameras. It has been shown that unpainted blades can be tested satisfactorily by using a more powerful flash heating system and a long wavelength IR camera. The problem of uneven surface emissivity can be overcome by applying 2nd derivative processing of the log-log surface cooling curves.

The Effects of Surface Roughness on the Apparent Thermal and Optical Properties of the Moon

NASA Astrophysics Data System (ADS)

Rubanenko, L.; Hayne, P. O.; Paige, D. A.

2017-12-01

The thermal inertia and albedo of airless planetary bodies such as the Moon can be inferred by measuring the surface temperatures and solar reflectance. However, roughness below the instrument resolution can affect these measured parameters. Scattering and IR emission from warm slopes onto colder slopes change the surface cooling rate, while shadowing and directional scattering change the reflectance. The importance of these effects grows with increasing solar incidence and emission angles, and during solar eclipses during which the insolation decreases rapidly. The high-quality data gathered by the Lunar Reconnaissance Orbiter (LRO) mission during the last seven years provides us with a unique opportunity to study these effects. Previous works have either adopted a simplified roughness model composed of a single slope, or an illumination model that does not account for subsurface conduction. Our approach incorporates data with simulations conducted using a coupled thermal and illumination model. First, we model the surface temperature distribution below the instrument resolution, considering two realizations: a cratered surface and a Gaussian random surface. Then, we fit the rough surface brightness temperature distribution to that of a flat surface with effective thermal and optical properties to find they differ from the original properties by up to 20% due to the added surface roughness. In the future, this will help to better constrain the intrinsic physical properties of the surface on both the Moon and Mercury and also other airless bodies such as asteroids.

Preparation of activated carbon from cherry stones by chemical activation with ZnCl 2

NASA Astrophysics Data System (ADS)

Olivares-Marín, M.; Fernández-González, C.; Macías-García, A.; Gómez-Serrano, V.

2006-06-01

Cherry stones (CS), an industrial product generated abundantly in the Valle del Jerte (Cáceres province, Spain), were used as precursor in the preparation of activated carbon by chemical activation with ZnCl 2. The influence of process variables such as the carbonisation temperature and the ZnCl 2:CS ratio (impregnation ratio) on textural and chemical-surface properties of the products obtained was studied. Such products were characterised texturally by adsorption of N 2 at -196 °C, mercury porosimetry and density measurements. Information on the surface functional groups and structures of the carbons was provided by FT-IR spectroscopy. Activated carbon with a high development of surface area and porosity is prepared. When using the 4:1 impregnation ratio, the specific surface area (BET) of the resultant carbon is as high as 1971 m 2 g -1. The effect of the increase in the impregnation ratio on the porous structure of activated carbon is stronger than that of the rise in the carbonisation temperature, whereas the opposite applies to the effect on the surface functional groups and structures.

Indigenous Construction Materials for Theater Facilities

DTIC Science & Technology

2013-09-01

pebbles removed. Mortars are used to accommodate ir - regularities in size, shape, and surface of blocks, and it keeps all gaps be- tween CEBs closed to...distance in southeast Ethiopia. • Dryer and hotter than other sites in the country, with an average daily temperature exceeding 28 °C, but...purportedly available at http://www.goss-online.org, but the link was not functional as of 8 July 2013. A web search has returned some evidence that

Rapid Oceanographic Data Gathering: Some Problems in Using Remote Sensing to Determine the Horizontal and Vertical Thermal Distributions in the Northeast Pacific Ocean.

DTIC Science & Technology

1981-09-01

Zulu time) GOES Geostationary Operational Environmental Satellite GOSSTCOMP Global Operational Sea Surface Temperature Computation HEPAD High Energy ...Manipulation System IFOV Instantaneous Field-of-View IMP Instrument Mounting Platofrm IR Infrared 12 K Kelvin km kilometer m meter MEPED Medium Energy ...Stratospheric Sounding Unit STREX Storm Transfer and Response Experiment TEP Total Energy Detector TIP TIROS Information Processor TOVS TIROS Operational

Poorly crystalline hydroxyapatite: A novel adsorbent for enhanced fulvic acid removal from aqueous solution

NASA Astrophysics Data System (ADS)

Wei, Wei; Yang, Lei; Zhong, Wenhui; Cui, Jing; Wei, Zhenggui

2015-03-01

In this study, poorly crystalline hydroxyapatite (HAP) was developed as an efficient adsorbent for the removal of fulvic acid (FA) from aqueous solution. Surface functionality, crystallinity, and morphology of the synthetic adsorbent were studied by Fourier-transformation infrared (FT-IR) spectroscopy, powder X-ray diffraction (XRD) and transmission electron microscopy (TEM). The effects of various parameters such as crystallinity of adsorbent, contact time, adsorbent dosage, pH, initial adsorbate concentration, temperature, ionic strength and the presence of alkaline earth metal ions on FA adsorption were investigated. Results indicated that the nanosized HAP calcined at lower temperature was poorly crystalline (Xc = 0.23) and had better adsorption capacity for FA than those (Xc = 0.52, 0.86) calcined at higher temperature. FA removal was increased with increases of adsorbent dosage, temperature, ionic strength and the presence of alkali earth metal ions, but decreased as the pH increased. Kinetic studies showed that pseudo-second-order kinetic model better described the adsorption process. Equilibrium data were best described by Sips models, and the estimated maximum adsorption capacity of poorly crystalline HAP was 90.20 mg/g at 318 K, displaying higher efficiency for FA removal than previously reported adsorbents. FT-IR results revealed that FA adsorption over the adsorbent could be attributed to the surface complexation between the oxygen atom of functional groups of FA and calcium ions of HAP. Regeneration studies indicated that HAP could be recyclable for a long term. Findings of the present work highlight the potential for using poorly crystalline HAP nanoparticles as an effective and recyclable adsorbent for FA removal from aqueous solution.

Dynamic thermal effects of epidermal melanin and plasmonic nanoparticles during photoacoustic breast imaging

NASA Astrophysics Data System (ADS)

Ghassemi, Pejhman; Wang, Quanzeng; Pfefer, T. Joshua

2016-03-01

Photoacoustic Tomography (PAT) employs high-power near-infrared (near-IR) laser pulses to generate structural and functional information on tissue chromophores up to several centimeters below the surface. Such insights may facilitate detection of breast cancer - the most common cancer in women. PAT mammography has been the subject of extensive research, including techniques based on exogenous agents for PAT contrast enhancement and molecular specificity. However, photothermal safety risks of PAT due to strong chromophores such as epidermal melanin and plasmonic nanoparticles have not been rigorously studied. We have used computational and experimental approaches to elucidate highly dynamic optical-thermal processes during PAT. A Monte Carlo model was used to simulate light propagation at 800 and 1064 nm in a multi-layer breast tissue geometry with different epidermal pigmentation levels and a tumorsimulating inclusion incorporating nanoparticles. Energy deposition results were then used in a bioheat transfer model to simulate temperature transients. Experimental measurements involved multi-layer hydrogel phantoms with inclusions incorporating gold nanoparticles. Phantom optical properties were measured using the inverse adding-doubling technique. Thermal imaging was performed as phantoms were irradiated with 5 ns near-IR pulses. Scenarios using 10 Hz laser irradiation of breast tissue containing various nanoparticle concentrations were implemented experimentally and computationally. Laser exposure levels were based on ANSI/IEC limits. Surface temperature measurements were compared to corresponding simulation data. In general, the effect of highly pigmented skin on temperature rise was significant, whereas unexpectedly small levels of temperature rise during nanoparticle irradiation were attributed to rapid photodegradation. Results provide key initial insights into light-tissue interactions impacting the safety and effectiveness of PAT.

Effect of IrMn inserted layer on anomalous-Hall resistance and spin-Hall magnetoresistance in Pt/IrMn/YIG heterostructures

NASA Astrophysics Data System (ADS)

Shang, T.; Yang, H. L.; Zhan, Q. F.; Zuo, Z. H.; Xie, Y. L.; Liu, L. P.; Zhang, S. L.; Zhang, Y.; Li, H. H.; Wang, B. M.; Wu, Y. H.; Zhang, S.; Li, Run-Wei

2016-10-01

We report an investigation of anomalous-Hall resistance (AHR) and spin-Hall magnetoresistance (SMR) in Pt/Ir20Mn80/Y3Fe5O12 (Pt/IrMn/YIG) heterostructures. The AHR of Pt/IrMn/YIG heterostructures with an antiferromagnetic inserted layer is dramatically enhanced as compared to that of the Pt/YIG bilayer. The temperature dependent AHR behavior is nontrivial, while the IrMn thickness dependent AHR displays a peak at an IrMn thickness of 3 nm. The observed SMR in the temperature range of 10-300 K indicates that the spin current generated in the Pt layer can penetrate the IrMn layer (≤3 nm) to interact with the ferromagnetic YIG layer. The lack of conventional anisotropic magnetoresistance (AMR) implies that the insertion of the IrMn layer between Pt and YIG could efficiently suppress the magnetic proximity effect (MPE) on induced Pt moments by YIG.

Surface enrichment of Pt in stable Pt-Ir nano-alloy particles on MgAl 2 O 4 spinel in oxidizing atmosphere

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Wei-Zhen; Nie, Lei; Cheng, Yingwen

With the capability of MgAl2O4 spinel {111} nano-facets in stabilizing small Rh, Ir and Pt particles, bimetallic Ir-Pt catalysts on the same support were investigated, aiming at further lowering the catalyst cost by substituting expensive Pt with cheaper Ir in the bulk. Small Pt-Ir nano-alloy particles (< 2nm) were successfully stabilized on the spinel {111} nano-facets as expected. Interestingly, methanol oxidative dehydrogenation (ODH) rate on the surface Pt atoms increases with oxidizing aging but decreases upon reducing treatment, where Ir is almost inactive under the same reaction conditions. Up to three times enhancement in Pt exposure was achieved when themore » sample was oxidized at 800 °C in air for 1 week and subsequently reduced by H2 for 2 h, demonstrating successful surface enrichment of Pt on Pt-Ir nano-alloy particles. A dynamic stabilization mechanism involving wetting\

Infrared nanoscopy down to liquid helium temperatures

NASA Astrophysics Data System (ADS)

Lang, Denny; Döring, Jonathan; Nörenberg, Tobias; Butykai, Ádám; Kézsmárki, István; Schneider, Harald; Winnerl, Stephan; Helm, Manfred; Kehr, Susanne C.; Eng, Lukas M.

2018-03-01

We introduce a scattering-type scanning near-field infrared microscope (s-SNIM) for the local scale near-field sample analysis and spectroscopy from room temperature down to liquid helium (LHe) temperature. The extension of s-SNIM down to T = 5 K is in particular crucial for low-temperature phase transitions, e.g., for the examination of superconductors, as well as low energy excitations. The low temperature (LT) s-SNIM performance is tested with CO2-IR excitation at T = 7 K using a bare Au reference and a structured Si/SiO2-sample. Furthermore, we quantify the impact of local laser heating under the s-SNIM tip apex by monitoring the light-induced ferroelectric-to-paraelectric phase transition of the skyrmion-hosting multiferroic material GaV4S8 at Tc = 42 K. We apply LT s-SNIM to study the spectral response of GaV4S8 and its lateral domain structure in the ferroelectric phase by the mid-IR to THz free-electron laser-light source FELBE at the Helmholtz-Zentrum Dresden-Rossendorf, Germany. Notably, our s-SNIM is based on a non-contact atomic force microscope (AFM) and thus can be complemented in situ by various other AFM techniques, such as topography profiling, piezo-response force microscopy (PFM), and/or Kelvin-probe force microscopy (KPFM). The combination of these methods supports the comprehensive study of the mutual interplay in the topographic, electronic, and optical properties of surfaces from room temperature down to 5 K.

The mid-IR spectral effects of darkening agents and porosity on the silicate surface features of airless bodies

NASA Astrophysics Data System (ADS)

Young, C. L.; Wray, J. J.; Poston, M.; Hand, K. P.; Carlson, R. W.

2017-12-01

The surfaces of airless bodies present opportunities to investigate the physical processes acting on planetary systems over time, without the need to account for surface-atmosphere interactions. Silicate surfaces mixed with fine-grained optically dark material with varying degrees of porosity are ubiquitous on many airless bodies (e.g., Earth's Moon, Deimos, Phobos, asteroids, meteorites, and moons of the outer solar system). Although the mid-IR is rich in emissivity features of important minerals and molecular groups, including organics [e.g., 1], it is less studied for airless conditions and presents challenges in signal-to-noise ratio, especially for the colder outer solar system bodies with fined-grained surfaces [2, 3]. We systematically measured the mid-IR spectra of different mixtures of three silicates (antigorite, lizardite, and pure silica) with varying porosities and amounts of darkening agent (iron oxide and carbon). Serpentines, such as antigorite and lizardite, are common to airless surfaces, and their mid-IR spectra in the presence of darkening agents and different surface porosities would be typical for those measured by spacecraft. Although pure silica has only been measured in the plumes of Enceladus, it presents exciting possibilities for other Saturn-system surfaces due to long range transport [4], and it is therefore important to investigate how its spectral signature would be manifested in the mid-IR. Overall, this work provides a library of mineral mixtures to facilitate dealing with current and future mid-IR datasets of airless bodies. These results are also applicable to the development of future missions to airless bodies, and our continuing efforts will help determine if mid-IR spectrometry is worthwhile for surface compositional studies of icy bodies. The mixtures presented here could be useful for testing future mid-IR instruments by confirming detectability of spectral features for typical materials on the surfaces of interest. [1] Hand, K. P., et al. (2009), In Europa, 589. [2] Carvano, J. M., et al. (2007), Icarus, 187, 574. [3] Young, C. L., et al. (2015), ApJ Lett., 811(2), L27. [4] Hsu, H. W. et al. (2014), Nature, 519, 207.

MODELING THE INFRARED SPECTRUM OF THE EARTH-MOON SYSTEM: IMPLICATIONS FOR THE DETECTION AND CHARACTERIZATION OF EARTHLIKE EXTRASOLAR PLANETS AND THEIR MOONLIKE COMPANIONS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robinson, Tyler D., E-mail: robinson@astro.washington.edu

2011-11-01

The Moon maintains large surface temperatures on its illuminated hemisphere and can contribute significant amounts of flux to spatially unresolved thermal infrared (IR) observations of the Earth-Moon system, especially at wavelengths where Earth's atmosphere is absorbing. In this paper we investigate the effects of an unresolved companion on IR observations of Earthlike exoplanets. For an extrasolar twin Earth-Moon system observed at full phase at IR wavelengths, the Moon consistently comprises about 20% of the total signal, approaches 30% of the signal in the 9.6 {mu}m ozone band and the 15 {mu}m carbon dioxide band, makes up as much as 80%more » of the signal in the 6.3 {mu}m water band, and more than 90% of the signal in the 4.3 {mu}m carbon dioxide band. These excesses translate to inferred brightness temperatures for Earth that are too large by 20-40 K and demonstrate that the presence of undetected satellites can have significant impacts on the spectroscopic characterization of exoplanets. The thermal flux contribution from an airless companion depends strongly on phase, implying that observations of exoplanets should be taken when the star-planet-observer angle (i.e., phase angle) is as large as feasibly possible if contributions from companions are to be minimized. We show that, by differencing IR observations of an Earth twin with a companion taken at both gibbous and crescent phases, Moonlike satellites may be detectable by future exoplanet characterization missions for a wide range of system inclinations.« less

Assimilation for skin SST in the NASA GEOS atmospheric data assimilation system.

PubMed

Akella, Santha; Todling, Ricardo; Suarez, Max

2017-01-01

The present article describes the sea surface temperature (SST) developments implemented in the Goddard Earth Observing System, Version 5 (GEOS-5) Atmospheric Data Assimilation System (ADAS). These are enhancements that contribute to the development of an atmosphere-ocean coupled data assimilation system using GEOS. In the current quasi-operational GEOS-ADAS, the SST is a boundary condition prescribed based on the OSTIA product, therefore SST and skin SST (Ts) are identical. This work modifies the GEOS-ADAS Ts by modeling and assimilating near sea surface sensitive satellite infrared (IR) observations. The atmosphere-ocean interface layer of the GEOS atmospheric general circulation model (AGCM) is updated to include near surface diurnal warming and cool-skin effects. The GEOS analysis system is also updated to directly assimilate SST-relevant Advanced Very High Resolution Radiometer (AVHRR) radiance observations. Data assimilation experiments designed to evaluate the Ts modification in GEOS-ADAS show improvements in the assimilation of radiance observations that extends beyond the thermal IR bands of AVHRR. In particular, many channels of hyperspectral sensors, such as those of the Atmospheric Infrared Sounder (AIRS), and Infrared Atmospheric Sounding Interferometer (IASI) are also better assimilated. We also obtained improved fit to withheld, in-situ buoy measurement of near-surface SST. Evaluation of forecast skill scores show marginal to neutral benefit from the modified Ts.

Surface treatment with Fenton for separation of acrylonitrile-butadiene-styrene and polyvinylchloride waste plastics by flotation.

PubMed

Wang, Jian-Chao; Wang, Hui; Huang, Luo-Luo; Wang, Chong-Qing

2017-09-01

Surface treatment with Fenton was applied to flotation separation of acrylonitrile-butadienestyrene (ABS) and polyvinylchloride (PVC). After treatment, the floatability of ABS has a dramatic decrease, while the floatability of PVC is not affected. Fourier transform infrared spectroscopy (FT-IR) spectra and X-ray photoelectron spectroscopy (XPS) spectra were recorded to ascertain the mechanism of Fenton treatment. FT-IR and XPS analysis confirms that the introduction of oxygen-containing group occurs on the surface of ABS. The optimum conditions are molar ration (H 2 O 2 :Fe 2+ ) 10000, H 2 O 2 concentration 0.4M/L, pH 5.8, treatment time 2min and temperature 25°C, frother concentration 15mg/L and flotation time 3min. Particle sizes and mixing ratios were also investigated. Plastic mixtures of ABS and PVC with different particle sizes and mixing ratios can be effectively separated. The purity of ABS and PVC are up to 100% and 99.78%, respectively; the recovery of ABS and PVC are up to 99.89% and 100%, respectively. A practical, environmentally friendly and effective reagent, namely Fenton, was originally applied to surface treatment of ABS and PVC waste plastics for flotation separation of their mixtures. Copyright © 2017 Elsevier Ltd. All rights reserved.

Effects of Temperature and X-rays on Plastic Scintillating Fiber and Infrared Optical Fiber.

PubMed

Lee, Bongsoo; Shin, Sang Hun; Jang, Kyoung Won; Yoo, Wook Jae

2015-05-11

In this study, we have studied the effects of temperature and X-ray energy variations on the light output signals from two different fiber-optic sensors, a fiber-optic dosimeter (FOD) based on a BCF-12 as a plastic scintillating fiber (PSF) and a fiber-optic thermometer (FOT) using a silver halide optical fiber as an infrared optical fiber (IR fiber). During X-ray beam irradiation, the scintillating light and IR signals were measured simultaneously using a dosimeter probe of the FOD and a thermometer probe of the FOT. The probes were placed in a beaker with water on the center of a hotplate, under variation of the tube potential of a digital radiography system or the temperature of the water in the beaker. From the experimental results, in the case of the PSF, the scintillator light output at the given tube potential decreased as the temperature increased in the temperature range from 25 to 60 °C. We demonstrated that commonly used BCF-12 has a significant temperature dependence of -0.263 ± 0.028%/°C in the clinical temperature range. Next, in the case of the IR fiber, the intensity of the IR signal was almost uniform at each temperature regardless of the tube potential range from 50 to 150 kVp. Therefore, we also demonstrated that the X-ray beam with an energy range used in diagnostic radiology does not affect the IR signals transmitted via a silver halide optical fiber.

Effects of Temperature and X-rays on Plastic Scintillating Fiber and Infrared Optical Fiber

PubMed Central

Lee, Bongsoo; Shin, Sang Hun; Jang, Kyoung Won; Yoo, Wook Jae

2015-01-01

In this study, we have studied the effects of temperature and X-ray energy variations on the light output signals from two different fiber-optic sensors, a fiber-optic dosimeter (FOD) based on a BCF-12 as a plastic scintillating fiber (PSF) and a fiber-optic thermometer (FOT) using a silver halide optical fiber as an infrared optical fiber (IR fiber). During X-ray beam irradiation, the scintillating light and IR signals were measured simultaneously using a dosimeter probe of the FOD and a thermometer probe of the FOT. The probes were placed in a beaker with water on the center of a hotplate, under variation of the tube potential of a digital radiography system or the temperature of the water in the beaker. From the experimental results, in the case of the PSF, the scintillator light output at the given tube potential decreased as the temperature increased in the temperature range from 25 to 60 °C. We demonstrated that commonly used BCF-12 has a significant temperature dependence of −0.263 ± 0.028%/°C in the clinical temperature range. Next, in the case of the IR fiber, the intensity of the IR signal was almost uniform at each temperature regardless of the tube potential range from 50 to 150 kVp. Therefore, we also demonstrated that the X-ray beam with an energy range used in diagnostic radiology does not affect the IR signals transmitted via a silver halide optical fiber. PMID:25970257

Serial removal of caries lesions from tooth occlusal surfaces using near-IR image-guided IR laser ablation

NASA Astrophysics Data System (ADS)

Chan, Kenneth H.; Tom, Henry; Darling, Cynthia L.; Fried, Daniel

2015-02-01

Previous studies have established that caries lesions can be imaged with high contrast without the interference of stains at near-IR wavelengths greater than 1300-nm. It has been demonstrated that computer controlled laser scanning systems utilizing IR lasers operating at high pulse repetition rates can be used for serial imaging and selective removal of caries lesions. In this study, we report our progress towards the development of algorithms for generating rasterized ablation maps from near-IR reflectance images for the removal of natural lesions from tooth occlusal surfaces. An InGaAs camera and a filtered tungsten-halogen lamp producing near-IR light in the range of 1500-1700-nm were used to collect crosspolarization reflectance images of tooth occlusal surfaces. A CO2 laser operating at a wavelength of 9.3- μm with a pulse duration of 10-15-μs was used for image-guided ablation.

Tungsten and iridium multilayered structure by DGP as ablation-resistance coatings for graphite

NASA Astrophysics Data System (ADS)

Wu, Wangping; Chen, Zhaofeng; Cheng, Han; Wang, Liangbing; Zhang, Ying

2011-06-01

Oxidation protection of carbon material under ultra-high temperature is a serious problem. In this paper, a newly designed multilayer coating of W/Ir was produced onto the graphite substrate by double glow plasma. As comparison, the Ir single-layer coating on the graphite was also prepared. The ablation property and thermal stability of the coatings were studied at 2000 °C in an oxyacetylene torch flame. Ablation tests showed that the coated graphite substrates were protected more effectively by W/Ir multilayer coating than Ir single-layer coating. Ir single-layer coating after ablation kept the integrality, although there was a poor adhesion of the Ir coating to the graphite substrate because of the thermal expansion mismatch and the non-wetting of the carbon by Ir coating. The mass loss rate of the W/Ir-coated specimen after ablation was about 1.62%. The interface of W/Ir multilayer coating and the graphite substrate exhibited good adherence no evidence of delamination after ablation. W/Ir multilayer coating could be useful for protecting graphite in high-temperature application for a short time.

VO2 /TiN Plasmonic Thermochromic Smart Coatings for Room-Temperature Applications.

PubMed

Hao, Qi; Li, Wan; Xu, Huiyan; Wang, Jiawei; Yin, Yin; Wang, Huaiyu; Ma, Libo; Ma, Fei; Jiang, Xuchuan; Schmidt, Oliver G; Chu, Paul K

2018-03-01

Vanadium dioxide/titanium nitride (VO 2 /TiN) smart coatings are prepared by hybridizing thermochromic VO 2 with plasmonic TiN nanoparticles. The VO 2 /TiN coatings can control infrared (IR) radiation dynamically in accordance with the ambient temperature and illumination intensity. It blocks IR light under strong illumination at 28 °C but is IR transparent under weak irradiation conditions or at a low temperature of 20 °C. The VO 2 /TiN coatings exhibit a good integral visible transmittance of up to 51% and excellent IR switching efficiency of 48% at 2000 nm. These unique advantages make VO 2 /TiN promising as smart energy-saving windows. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Remote sensing as a research tool. [sea ice surveillance from aircraft and spacecraft

NASA Technical Reports Server (NTRS)

Carsey, F. D.; Zwally, H. J.

1986-01-01

The application of aircraft and spacecraft remote sensing techniques to sea ice surveillance is evaluated. The effects of ice in the air-sea-ice system are examined. The measurement principles and characteristics of remote sensing methods for aircraft and spacecraft surveillance of sea ice are described. Consideration is given to ambient visible light, IR, passive microwave, active microwave, and laser altimeter and sonar systems. The applications of these systems to sea ice surveillance are discussed and examples are provided. Particular attention is placed on the use of microwave data and the relation between ice thickness and sea ice interactions. It is noted that spacecraft and aircraft sensing techniques can successfully measure snow cover; ice thickness; ice type; ice concentration; ice velocity field; ocean temperature; surface wind vector field; and air, snow, and ice surface temperatures.

The influence of topographic structures on night-time surface temperatures: Evaluation of a satellite thermal image of the upper Rhine plain and the surrounding highlands. [Germany and Switzerland

NASA Technical Reports Server (NTRS)

Gossmann, H. (Principal Investigator)

1980-01-01

The author has identified the following significant results. Satellite data supplied the same information as aerial IR registrations with corresponding averaging for all studies requiring a survey of the thermal pattern within an area measuring 10 km x 10 km ore more, provided that sufficiently precise control points could be established for the purpose of geometric rectification in the surroundings of the area observed. Satellite thermal data are more comprehensive than aircraft data for studies on a regional, rather than a local scale, since airborne images often obscure the basic correlation in thermal patterns because of a variety of irrelevant topographical detail. The satellite data demonstrate the dependence of surface temperature on relief more clearly than comparable airborne imagery.

Synthesis of porous nanocrystalline NiO with hexagonal sheet-like morphology by homogeneous precipitation method

NASA Astrophysics Data System (ADS)

Sharma, Ravi Kant; Ghose, Ranjana

2015-04-01

Porous nanocrystalline NiO has been synthesized by a simple homogeneous precipitation method in short time at low calcination temperature without using any surfactant, chelating or gelating agents. The porous nanocrystalline NiO with a hexagonal sheet-like morphology were obtained by calcination of Ni(OH)2 nanoflakes at 500 °C. The calcination temperature strongly influences the morphology, crystallite size, specific surface area, pore volume and optical band gap of the samples. The samples were characterized using powder X-ray diffraction, thermal gravimetric analysis, FT-IR spectroscopy, UV-Visible diffuse reflectance spectroscopy, surface area measurements, field emission scanning electron microscopy coupled with energy dispersive X-ray analysis and transmission electron microscopy. The chemical activity of the samples was tested by catalytic reduction of 4-nitrophenol with NaBH4.

Observational Evidence Linking Interstellar UV Absorption to PAH Molecules

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blasberger, Avi; Behar, Ehud; Perets, Hagai B.

The 2175 Å UV extinction feature was discovered in the mid-1960s, yet its physical origin remains poorly understood. One suggestion is absorption by polycyclic aromatic hydrocarbon (PAH) molecules, which is supported by theoretical molecular structure computations and by laboratory experiments. PAHs are positively detected by their 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 μ m IR emission bands, which are specified by their modes of vibration. A definitive empirical link between the 2175 Å UV extinction and the IR PAH emission bands, however, is still missing. We present a new sample of hot stars that have both 2175 Å absorptionmore » and IR PAH emission. We find significant shifts of the central wavelength of the UV absorption feature, up to 2350 Å, but predominantly in stars that also have IR PAH emission. These UV shifts depend on stellar temperature in a fashion that is similar to the shifts of the 6.2 and 7.7 μ m IR PAH bands, that is, the features are increasingly more redshifted as the stellar temperature decreases, but only below ∼15 kK. Above 15 kK both UV and IR features retain their nominal values. Moreover, we find a suggestive correlation between the UV and IR shifts. We hypothesize that these similar dependences of both the UV and IR features on stellar temperature hint at a common origin of the two in PAH molecules and may establish the missing link between the UV and IR observations. We further suggest that the shifts depend on molecular size, and that the critical temperature of ∼15 kK above which no shifts are observed is related to the onset of UV-driven hot-star winds and their associated shocks.« less

Observational Evidence Linking Interstellar UV Absorption to PAH Molecules

NASA Astrophysics Data System (ADS)

Blasberger, Avi; Behar, Ehud; Perets, Hagai B.; Brosch, Noah; Tielens, Alexander G. G. M.

2017-02-01

The 2175 Å UV extinction feature was discovered in the mid-1960s, yet its physical origin remains poorly understood. One suggestion is absorption by polycyclic aromatic hydrocarbon (PAH) molecules, which is supported by theoretical molecular structure computations and by laboratory experiments. PAHs are positively detected by their 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 μm IR emission bands, which are specified by their modes of vibration. A definitive empirical link between the 2175 Å UV extinction and the IR PAH emission bands, however, is still missing. We present a new sample of hot stars that have both 2175 Å absorption and IR PAH emission. We find significant shifts of the central wavelength of the UV absorption feature, up to 2350 Å, but predominantly in stars that also have IR PAH emission. These UV shifts depend on stellar temperature in a fashion that is similar to the shifts of the 6.2 and 7.7 μm IR PAH bands, that is, the features are increasingly more redshifted as the stellar temperature decreases, but only below ˜15 kK. Above 15 kK both UV and IR features retain their nominal values. Moreover, we find a suggestive correlation between the UV and IR shifts. We hypothesize that these similar dependences of both the UV and IR features on stellar temperature hint at a common origin of the two in PAH molecules and may establish the missing link between the UV and IR observations. We further suggest that the shifts depend on molecular size, and that the critical temperature of ˜15 kK above which no shifts are observed is related to the onset of UV-driven hot-star winds and their associated shocks.

Morin transition temperature in (0001)-oriented α-Fe{sub 2}O{sub 3} thin film and effect of Ir doping

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shimomura, Naoki, E-mail: shimomura@ecei.tohoku.ac.jp; Pati, Satya Prakash; Sato, Yuji

2015-05-07

The structural properties and Morin transition in c-plane-oriented α-Fe{sub 2}O{sub 3} and Ir-doped α-Fe{sub 2}O{sub 3} thin films have been investigated. The enhancement of the Morin transition temperature (T{sub M}) in α-Fe{sub 2}O{sub 3} film by Ir doping has been demonstrated. The T{sub M} in the c-plane-oriented α-Fe{sub 2}O{sub 3} thin film was determined from the temperature-dependent in-plane magnetization and change of coercivity (H{sub c}); this T{sub M} value was found close to that of bulk α-Fe{sub 2}O{sub 3}. The spin directions of non-doped and Ir-doped α-Fe{sub 2}O{sub 3} at room temperature were also estimated from conversion electron Mössbauer spectroscopymore » measurements. We confirmed that Ir doping dramatically enhances the T{sub M} of α-Fe{sub 2}O{sub 3} thin film.« less

Data indicating temperature response of Ti-6Al-4V thin-walled structure during its additive manufacture via Laser Engineered Net Shaping.

PubMed

Marshall, Garrett J; Thompson, Scott M; Shamsaei, Nima

2016-06-01

An OPTOMEC Laser Engineered Net Shaping (LENS(™)) 750 system was retrofitted with a melt pool pyrometer and in-chamber infrared (IR) camera for nondestructive thermal inspection of the blown-powder, direct laser deposition (DLD) process. Data indicative of temperature and heat transfer within the melt pool and heat affected zone atop a thin-walled structure of Ti-6Al-4V during its additive manufacture are provided. Melt pool temperature data were collected via the dual-wavelength pyrometer while the dynamic, bulk part temperature distribution was collected using the IR camera. Such data are provided in Comma Separated Values (CSV) file format, containing a 752×480 matrix and a 320×240 matrix of temperatures corresponding to individual pixels of the pyrometer and IR camera, respectively. The IR camera and pyrometer temperature data are provided in blackbody-calibrated, raw forms. Provided thermal data can aid in generating and refining process-property-performance relationships between laser manufacturing and its fabricated materials.

Data indicating temperature response of Ti–6Al–4V thin-walled structure during its additive manufacture via Laser Engineered Net Shaping

PubMed Central

Marshall, Garrett J.; Thompson, Scott M.; Shamsaei, Nima

2016-01-01

An OPTOMEC Laser Engineered Net Shaping (LENS™) 750 system was retrofitted with a melt pool pyrometer and in-chamber infrared (IR) camera for nondestructive thermal inspection of the blown-powder, direct laser deposition (DLD) process. Data indicative of temperature and heat transfer within the melt pool and heat affected zone atop a thin-walled structure of Ti–6Al–4V during its additive manufacture are provided. Melt pool temperature data were collected via the dual-wavelength pyrometer while the dynamic, bulk part temperature distribution was collected using the IR camera. Such data are provided in Comma Separated Values (CSV) file format, containing a 752×480 matrix and a 320×240 matrix of temperatures corresponding to individual pixels of the pyrometer and IR camera, respectively. The IR camera and pyrometer temperature data are provided in blackbody-calibrated, raw forms. Provided thermal data can aid in generating and refining process-property-performance relationships between laser manufacturing and its fabricated materials. PMID:27054180

Temperature dependent behavior of thermal conductivity of sub-5 nm Ir film: Defect-electron scattering quantified by residual thermal resistivity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, Zhe; Xu, Zaoli; Xu, Shen

2015-01-14

By studying the temperature-dependent behavior (300 K down to 43 K) of electron thermal conductivity (κ) in a 3.2 nm-thin Ir film, we quantify the extremely confined defect-electron scatterings and isolate the intrinsic phonon-electron scattering that is shared by the bulk Ir. At low temperatures below 50 K, κ of the film has almost two orders of magnitude reduction from that of bulk Ir. The film has ∂κ/∂T > 0, while the bulk Ir has ∂κ/∂T < 0. We introduce a unified thermal resistivity (Θ = T/κ) to interpret these completely different κ ∼ T relations. It is found that the film and the bulk Ir share a very similar Θ ∼ T trend,more » while they have a different residual part (Θ{sub 0}) at 0 K limit: Θ{sub 0} ∼ 0 for the bulk Ir, and Θ{sub 0} = 5.5 m·K{sup 2}/W for the film. The Ir film and the bulk Ir have very close ∂Θ/∂T (75–290 K): 6.33 × 10{sup −3} m K/W for the film and 7.62 × 10{sup −3} m K/W for the bulk Ir. This strongly confirms the similar phonon-electron scattering in them. Therefore, the residual thermal resistivity provides an unprecedented way to quantitatively evaluating defect-electron scattering (Θ{sub 0}) in heat conduction. Moreover, the interfacial thermal conductance across the grain boundaries is found larger than that of Al/Cu interface, and its value is proportional to temperature, largely due to the electron's specific heat. A unified interfacial thermal conductance is also defined and firmly proves this relation. Additionally, the electron reflection coefficient is found to be large (88%) and almost temperature independent.« less

Determination of the Thermal Offset of the Eppley Precision Spectral Pyranometer

NASA Technical Reports Server (NTRS)

Haeffelin, Martial; Kato, Seiji; Smith, Amie M.; Rutledge, C. Ken; Charlock, Thomas P.; Mahan, J. Robert

2001-01-01

Eppley's precision spectral pyranometer (PSP) is used in networks around the world to measure downwelling diffuse and global solar irradiance at the surface of the Earth. In recent years several studies have shown significant discrepancy between irradiances measured by pyranometers and those computed by atmospheric radiative transfer models. Pyranometer measurements have been questioned because observed diffuse irradiances sometimes are below theoretical minimum values for a pure molecular atmosphere, and at night the instruments often produce nonzero signals ranging between + 5 and - 10 W/sq m. We install thermistor sondes in the body of a PSP as well as on its inner dome to monitor the temperature gradients within the instrument, and we operate a pyrgeometer (PIR) instrument side by side with the PSP. We derive a relationship between the PSP output and thermal radiative exchange by the dome and the detector and a relationship between the PSP output and the PIR thermopile output (net-IR). We determine the true PSP offset by quickly capping the instrument at set time intervals. For a ventilated and shaded PSP, the thermal offset can reach - 15 W/sq m under clear skies, whereas it remains close to zero for low overcast clouds. We estimate the PSP thermal offset by two methods: (1) using the PSP temperatures and (2) using the PIR net-IR signal. The offset computed from the PSP temperatures yields a reliable estimate of the true offset (+/- 1 W/sq m). The offset computed from net-IR is consistent with the true offset at night and under overcast skies but predicts only part of the true range under clear skies.

Determination of the thermal offset of the Eppley precision spectral pyranometer.

PubMed

Haeffelin, M; Kato, S; Smith, A M; Rutledge, C K; Charlock, T P; Mahan, J R

2001-02-01

Eppley's precision spectral pyranometer (PSP) is used in networks around the world to measure downwelling diffuse and global solar irradiance at the surface of the Earth. In recent years several studies have shown significant discrepancy between irradiances measured by pyranometers and those computed by atmospheric radiative transfer models. Pyranometer measurements have been questioned because observed diffuse irradiances sometimes are below theoretical minimum values for a pure molecular atmosphere, and at night the instruments often produce nonzero signals ranging between +5 and -10 W m(-2). We install thermistor sondes in the body of a PSP as well as on its inner dome to monitor the temperature gradients within the instrument, and we operate a pyrgeometer (PIR) instrument side by side with the PSP. We derive a relationship between the PSP output and thermal radiative exchange by the dome and the detector and a relationship between the PSP output and the PIR thermopile output (net-IR). We determine the true PSP offset by quickly capping the instrument at set time intervals. For a ventilated and shaded PSP, the thermal offset can reach -15 W m(-2) under clear skies, whereas it remains close to zero for low overcast clouds. We estimate the PSP thermal offset by two methods: (1) using the PSP temperatures and (2) using the PIR net-IR signal. The offset computed from the PSP temperatures yields a reliable estimate of the true offset (+/-1 W m(-2)). The offset computed from net-IR is consistent with the true offset at night and under overcast skies but predicts only part of the true range under clear skies.

Reduction of shunt current in buffer-free IrMn based spin-valve structures

NASA Astrophysics Data System (ADS)

Kocaman, B.; Akdoğan, N.

2018-06-01

The presence of thick buffer layers in magnetic sensor devices decreases sensor sensitivity due to shunt currents. With this motivation, we produced IrMn-based spin-valve multilayers without using buffer layer. We also studied the effects of post-annealing and IrMn thickness on exchange bias field (HEB) and blocking temperature (TB) of the system. Magnetization measurements indicate that both HEB and TB values are significantly enhanced with post-annealing of IrMn layer. In addition, we report that IrMn thickness of the system strongly influences the magnetization and transport characteristics of the spin-valve structures. We found that the minimum thickness of IrMn layer is 6 nm in order to achieve the lowest shunt current and high blocking temperature (>300 K). We also investigated the training of exchange bias to check the long-term durability of IrMn-based spin-valve structures for device applications.

Interlamellar adsorption of carbon dioxide by smectites

USGS Publications Warehouse

Fripiat, J.J.; Cruz, M.I.; Bohor, B.F.; Thomas, J.

1974-01-01

The adsorption of CO2 at low temperature (∼ −70°C) on thin films of homoionic smectites was studied by X-ray diffraction and by i.r. absorption. An increase in the d001 spacings of these clay films upon adsorption of CO2 was observed. In addition, a dichroic effect was readily discernible by comparing the i.r. spectra at two different orientations of the smectite films; i.e. with the film normal and tilted 35° with respect to the i.r. beam. The CO2 stretching vibration at 2350 cm−1 was used for the i.r. study. These observations conclusively show that CO2 intercalates the smectite structure rather than being adsorbed only in pores between clay tactoids—the limiting process proposed by other investigators.Adsorption isotherm data from earlier surface area studies are re-examined here through application of the Dubinin equation. Again, intercalation is demonstrated by convergence of the plotted experimental data for smectites containing large monovalent interlayer cations toward a pore volume that is near the calculated theoretical value for a monolayer of intercalated CO2.Scanning electron photomicrographs of Li- and Cs- smectites provide additional evidence that aggregation differences are not responsible for the large observed difference in BET surface areas obtained for these smectites with CO2 as the adsorbate. At low magnification, visual differences in macro-aggregates are apparent, but at high magnification no significant differences are observed in the micro-structure of individual aggregates where the major amount of gas adsorption really occurs.

Interpretation of the Near-IR Spectra of the Kuiper Belt Object

NASA Technical Reports Server (NTRS)

Eluszkiewicz, Janusz; Cady-Pereira, Karen; Brown, Michael E.; Stansberry, John A.

2007-01-01

Visible and near-IR observations of the Kuiper Belt Object (136472) 2005 FY(9) have indicated the presence of unusually long (1 cm or more) optical path lengths in a layer of methane ice. Using microphysical and radiative transfer modeling, we show that even at the frigid temperatures in the outer reaches of the solar system, a slab of low porosity methane ice can indeed form by pressureless sintering of micron-sized grains, and it can qualitatively reproduce the salient features of the measured spectra. A good semiquantitative match with the near-IR spectra can be obtained with a realistic slab model, provided the spectra are scaled to a visible albedo of 0.6, at the low end of the values currently estimated from Spitzer thermal measurements. Consistent with previous modeling studies, matching spectra scaled to higher albedos requires the incorporation of strong backscattering effects. The albedo may become better constrained through an iterative application of the slab model to the analysis of the thermal measurements from Spitzer and the visible/near-IR reflectance spectra. The slab interpretation offers two falsifiable predictions (1) Absence of an opposition surge, which is commonly attributed to the fluffiness of the optical surface. This prediction is best testable with a spacecraft, as Earth-based observations at true opposition will not be possible until early next century. (2) Unlikelihood of the simultaneous occurrence of very long spectroscopic path lengths in both methane and nitrogen ice on the surface of any Kuiper Belt Object, as the more volatile nitrogen would hinder densification in methane ice.

Thermal modeling of grinding for process optimization and durability improvements

NASA Astrophysics Data System (ADS)

Hanna, Ihab M.

Both thermal and mechanical aspects of the grinding process are investigated in detail in an effort to predict grinding induced residual stresses. An existing thermal model is used as a foundation for computing heat partitions and temperatures in surface grinding. By numerically processing data from IR temperature measurements of the grinding zone; characterizations are made of the grinding zone heat flux. It is concluded that the typical heat flux profile in the grinding zone is triangular in shape, supporting this often used assumption found in the literature. Further analyses of the computed heat flux profiles has revealed that actual grinding zone contact lengths exceed geometric contact lengths by an average of 57% for the cases considered. By integrating the resulting heat flux profiles; workpiece energy partitions are computed for several cases of dry conventional grinding of hardened steel. The average workpiece energy partition for the cases considered was 37%. In an effort to more accurately predict grinding zone temperatures and heat fluxes, refinements are made to the existing thermal model. These include consideration of contact length extensions due to local elastic deformations, variations of the assumed contact area ratio as a function of grinding process parameters, consideration of coolant latent heat of vaporization and its effect on heat transfer beyond the coolant boiling point, and incorporation of coolant-workpiece convective heat flux effects outside the grinding zone. The result of the model refinements accounting for contact length extensions and process-dependant contact area ratios is excellent agreement with IR temperature measurements over a wide range of grinding conditions. By accounting for latent heat of vaporization effects, grinding zone temperature profiles are shown to be capable of reproducing measured profiles found in the literature for cases on the verge of thermal surge conditions. Computed peak grinding zone temperatures for the aggressive grinding examples given are 30--50% lower than those computed using the existing thermal model formulation. By accounting for convective heat transfer effects outside the grinding zone, it is shown that while surface temperatures in the wake of the grinding zone may be significantly affected under highly convective conditions, computed residual stresses are less sensitive to such conditions. Numerical models are used to evaluate both thermally and mechanically induced stress fields in an elastic workpiece, while finite element modeling is used to evaluate residual stresses for workpieces with elastic-plastic material properties. Modeling of mechanical interactions at the local grit-workpiece length scale is used to create the often measured effect of compressive surface residual stress followed by a subsurface tensile peak. The model is shown to be capable of reproducing trends found in the literature of surface residual stresses which are compressive for low temperature grinding conditions, with surface stresses increasing linearly and becoming tensile with increasing temperatures. Further modifications to the finite element model are made to allow for transiently varying inputs for more complicated grinding processes of industrial components such as automotive cam lobes.

Cell surface GRP78 facilitates hepatoma cells proliferation and migration by activating IGF-IR.

PubMed

Yin, Yancun; Chen, Chen; Chen, Jinliang; Zhan, Renhui; Zhang, Qiang; Xu, Xiaoyan; Li, Defang; Li, Minjing

2017-07-01

The 78kDa glucose regulated protein (GRP78) is a multifunctional chaperone that is involved in a variety of cellular processes. Insulin like growth factor I receptor (IGF-IR) often aberrant expresses in many types of tumor cells. The IGF-IR signaling plays key roles in carcinogenesis and maintenance of the malignant phenotype. The crosstalk between GRP78 and IGF-IR molecules has not well been illuminated. Here, we demonstrated a reciprocal regulation of GRP78 expression and IGF-IR pathway activation. IGF-I induced GRP78 expression in hepatoma cells. IGF-IR knockdown or IGF-IR inhibitor repressed GRP78 expression. Both phosphatidylinositol 3-kianase (PI3K) and mitogen-activated protein kinase (MAPK) pathways involved in IGF-I induction of GRP78 expression. Interestingly, treatment of hepatoma cells with IGF-I re-distributes GRP78 from endoplasmic reticulum (ER) to cell surface and promotes its physical interaction with IGF-IR. Also, GRP78 promotes IGF-IR phosphorylation and activation. Blocked of GRP78 by small interfering RNA or inhibition of GRP78 function by (-)-epigallocatechin gallate (EGCG) blocks IGF-I induced IGF-IR phosphorylation and its downstream signaling. Further, blocked cell surface GRP78 with antibody inhibits IGF-I stimulated cellular proliferation and migration. These data reveal an essential role for the molecular chaperone GRP78 in IGF-IR signaling and implicate the use of GRP78 inhibitors in blocking IGF-IR signaling in hepatoma cells. Copyright © 2017 Elsevier Inc. All rights reserved.

HYTHIRM Radiance Modeling and Image Analyses in Support of STS-119, STS-125 and STS-128 Space Shuttle Hypersonic Re-entries

NASA Technical Reports Server (NTRS)

Gibson, David M.; Spisz, Thomas S.; Taylor, Jeff C.; Zalameda, Joseph N.; Horvath, Thomas J.; Tomek, Deborah M.; Tietjen, Alan B.; Tack, Steve; Bush, Brett C.

2010-01-01

We provide the first geometrically accurate (i.e., 3-D) temperature maps of the entire windward surface of the Space Shuttle during hypersonic reentry. To accomplish this task we began with estimated surface temperatures derived from CFD models at integral high Mach numbers and used them, the Shuttle's surface properties and reasonable estimates of the sensor-to-target geometry to predict the emitted spectral radiance from the surface (in units of W sr-1 m-2 nm-1). These data were converted to sensor counts using properties of the sensor (e.g. aperture, spectral band, and various efficiencies), the expected background, and the atmosphere transmission to inform the optimal settings for the near-infrared and midwave IR cameras on the Cast Glance aircraft. Once these data were collected, calibrated, edited, registered and co-added we formed both 2-D maps of the scene in the above units and 3-D maps of the bottom surface in temperature that could be compared with not only the initial inputs but also thermocouple data from the Shuttle itself. The 3-D temperature mapping process was based on the initial radiance modeling process. Here temperatures were guessed for each node in a well-resolved 3-D framework, a radiance model was produced and compared to the processed imagery, and corrections to the temperature were estimated until the iterative process converged. This process did very well in characterizing the temperature structure of the large asymmetric boundary layer transition the covered much of the starboard bottom surface of STS-119 Discovery. Both internally estimated accuracies and differences with CFD models and thermocouple measurements are at most a few percent. The technique did less well characterizing the temperature structure of the turbulent wedge behind the trip due to limitations in understanding the true sensor resolution. (Note: Those less inclined to read the entire paper are encouraged to read an Executive Summary provided at the end.)

Phase diagram and electrical behavior of silicon-rich iridium silicide compounds

NASA Technical Reports Server (NTRS)

Allevato, C. E.; Vining, Cronin B.

1992-01-01

The iridium-silicon phase diagram on the silicon-rich side was investigated by means of X-ray powder diffraction, density, differential thermal analysis, metalography, microprobe analysis, and electrical resistivity. Attempts were made to prepare eight previously reported silicon-rich iridium silicide compounds by arc melting and Bridgman-like growth. However, microprobe analysis identified only four distinct compositions: IrSi, Ir3Si4, Ir3Si5 and IrSi sub about 3. The existence of Ir4Si5 could not be confirmed in this study, even though the crystal structure has been previously reported. Differential thermal analysis (DTA) in conjunction with X-ray powder diffraction confirm polymorphism in IrSi sub about 3, determined to have orthorhombic and monoclinic unit cells in the high and low temperature forms. A eutectic composition alloy of 83 +/- 1 atomic percent silicon was observed between IrSi sub about 3 and silicon. Ir3Si4 exhibits distinct metallic behavior while Ir3Si5 is semiconducting. Both and IrSi and IrSi sub about 3 exhibit nearly temperature independent electrical resistivities on the order of 5-10 x 10 exp -6 ohms-m.

[Determination of the content of sulfur of coal by the infrared absorption method with high acccuracy].

PubMed

Wang, Hai-Feng; Lu, Hai; Li, Jia; Sun, Guo-Hua; Wang, Jun; Dai, Xin-Hua

2014-02-01

The present paper reported the differential scanning calorimetry-thermogravimetry curves and the infrared (IR) absorption spectrometry under the temperature program analyzed by the combined simultaneous thermal analysis-IR spectrometer. The gas products of coal were identified by the IR spectrometry. This paper emphasized on the combustion at high temperature-IR absorption method, a convenient and accurate method, which measures the content of sulfur in coal indirectly through the determination of the content of sulfur dioxide in the mixed gas products by IR absorption. It was demonstrated, when the instrument was calibrated by varied pure compounds containing sulfur and certified reference materials (CRMs) for coal, that there was a large deviation in the measured sulfur contents. It indicates that the difference in chemical speciations of sulfur between CRMs and the analyte results in a systematic error. The time-IR absorption curve was utilized to analyze the composition of sulfur at low temperatures and high temperatures and then the sulfur content of coal sample was determined by using a CRM for coal with a close composition of sulfur. Therefore, the systematic error due to the difference in chemical speciations of sulfur between the CRM and analyte was eliminated. On the other hand, in this combustion at high temperature-IR absorption method, the mass of CRM and analyte were adjusted to assure the sulfur mass equal and then the CRM and the analyte were measured alternately. This single-point calibration method reduced the effect of the drift of the IR detector and improved the repeatability of results, compared with the conventional multi-point calibration method using the calibration curves of signal intensity vs sulfur mass. The sulfur content results and their standard deviations of an anthracite coal and a bituminous coal with a low sulfur content determined by this modified method were 0.345% (0.004%) and 0.372% (0.008%), respectively. The uncertainty (U, k =2) of sulfur contents of two coal samples was evaluated to be 0.019% and 0.021%, respectively. Two main modifications, namely the calibration using the coal CRM with a similar composition of low-temperature sulfur and high temperature sulfur, and the single-point calibration alternating CRM and analyte, endow the combustion at high temperature-IR absorption method with an accuracy obviously better than that of the ASTM method. Therefore, this modified method has a well potential in the analysis of sulfur content.

Ammonia modification of activated carbon to enhance carbon dioxide adsorption: Effect of pre-oxidation

NASA Astrophysics Data System (ADS)

Shafeeyan, Mohammad Saleh; Daud, Wan Mohd Ashri Wan; Houshmand, Amirhossein; Arami-Niya, Arash

2011-02-01

A commercial granular activated carbon (GAC) was subjected to thermal treatment with ammonia for obtaining an efficient carbon dioxide (CO2) adsorbent. In general, CO2 adsorption capacity of activated carbon can be increased by introduction of basic nitrogen functionalities onto the carbon surface. In this work, the effect of oxygen surface groups before introduction of basic nitrogen functionalities to the carbon surface on CO2 adsorption capacity was investigated. For this purpose two different approaches of ammonia treatment without preliminary oxidation and amination of oxidized samples were studied. Modified carbons were characterized by elemental analysis and Fourier Transform Infrared spectroscopy (FT-IR) to study the impact of changes in surface chemistry and formation of specific surface groups on adsorption properties. The texture of the samples was characterized by conducting N2 adsorption/desorption at -196 °C. CO2 capture performance of the samples was investigated using a thermogravimetric analysis (TGA). It was found that in both modification techniques, the presence of nitrogen functionalities on carbon surface generally increased the CO2 adsorption capacity. The results indicated that oxidation followed by high temperature ammonia treatment (800 °C) considerably enhanced the CO2 uptake at higher temperatures.

Viking Lander 2 Anniversary

NASA Image and Video Library

2002-12-13

This portion of NASA Mars Odyssey image covers NASA Viking 2 landing site shown with the X. The second landing on Mars took place September 3, 1976 in Utopia Planitia. The exact location of Lander 2 is not as well established as Lander 1 because there were no clearly identifiable features in the lander images as there were for the site of Lander 1. The Utopia landing site region contains pedestal craters, shallow swales and gentle ridges. The crater Goldstone was named in honor of the Tracking Station in the desert of California. The two Viking Landers operated for over 6 years (nearly four martian years) after landing. This one band IR (band 9 at 12.6 microns) image shows bright and dark textures, which are primarily due to differences in the abundance of rocks on the surface. The relatively cool (dark) regions during the day are rocky or indurated materials, fine sand and dust are warmer (bright). Many of the temperature variations are due to slope effects, with sun-facing slopes warmer than shaded slopes. The dark rings around several of the craters are due to the presence of rocky (cool) material ejected from the crater. These rocks are well below the resolution of any existing Mars camera, but THEMIS can detect the temperature variations they produce. Daytime temperature variations are produced by a combination of topographic (solar heating) and thermophysical (thermal inertia and albedo) effects. Due to topographic heating the surface morphologies seen in THEMIS daytime IR images are similar to those seen in previous imagery and MOLA topography. http://photojournal.jpl.nasa.gov/catalog/PIA04023

INFRARED AND ULTRAVIOLET SPECTRA OF METHANE DILUTED IN SOLID NITROGEN AND IRRADIATED WITH ELECTRONS DURING DEPOSITION AT VARIOUS TEMPERATURES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chin, Chih-Hao; Chen, Sian-Cong; Liu, Meng-Chen

We recorded the infrared and ultraviolet absorption spectra of CH{sub 4}:N{sub 2} matrix samples that underwent electron bombardment during deposition in the temperature range of 10–44 K. In contrast to a previous experiment on the IR spectroscopy of electron-bombarded icy samples, methyl and azide radicals became the main products upon electron bombardment during deposition; furthermore, reduced production of nitrile species was observed for deposition at 10 and 20 K. On the other hand, for deposition above 33 K, the observed bands of the radical species (such as methyl and azide) decreased, and bands of large nitriles appeared. This observation maymore » suggest that radical species easily diffuse and recombine to form more complex molecules in solid nitrogen at higher temperatures. Further measurements of similar samples at 10–33 K in the UV region revealed the intense band of azide radicals at 272.5 nm and weak, broad, overlapping features of methyl and azide radicals in the 225–197 nm region. For deposition at 44 K, only a broad feature centered at 219.4 nm was observed, and the possible carriers of nitrile species were proposed based on the corresponding IR spectrum and theoretical predictions of excitation energy. This band is similar to the observed absorption feature of Pluto’s surface recorded by the Hubble telescope in terms of both band position and bandwidth. Our findings therefore further support the suggestion that complex nitrile species may exist on the surface of Pluto.« less

Development of Yellow Sand Image Products Using Infrared Brightness Temperature Difference Method

NASA Astrophysics Data System (ADS)

Ha, J.; Kim, J.; Kwak, M.; Ha, K.

2007-12-01

A technique for detection of airborne yellow sand dust using meteorological satellite has been developed from various bands from ultraviolet to infrared channels. Among them, Infrared (IR) channels have an advantage of detecting aerosols over high reflecting surface as well as during nighttime. There had been suggestion of using brightness temperature difference (BTD) between 11 and 12¥ìm. We have found that the technique is highly depends on surface temperature, emissivity, and zenith angle, which results in changing the threshold of BTD. In order to overcome these problems, we have constructed the background brightness temperature threshold of BTD and then aerosol index (AI) has been determined from subtracting the background threshold from BTD of our interested scene. Along with this, we utilized high temporal coverage of geostationary satellite, MTSAT, to improve the reliability of the determined AI signal. The products have been evaluated by comparing the forecasted wind field with the movement fiend of AI. The statistical score test illustrates that this newly developed algorithm produces a promising result for detecting mineral dust by reducing the errors with respect to the current BTD method.

Long-lived room-temperature deep-red-emissive intraligand triplet excited state of naphthalimide in cyclometalated Ir(III) complexes and its application in triplet-triplet annihilation-based upconversion.

PubMed

Sun, Jifu; Wu, Wanhua; Zhao, Jianzhang

2012-06-25

Cyclometalated Ir(III) complexes with acetylide ppy and bpy ligands were prepared (ppy = 2-phenylpyridine, bpy = 2,2'-bipyridine) in which naphthal (Ir-2) and naphthalimide (NI) were attached onto the ppy (Ir-3) and bpy ligands (Ir-4) through acetylide bonds. [Ir(ppy)(3)] (Ir-1) was also prepared as a model complex. Room-temperature phosphorescence was observed for the complexes; both neutral and cationic complexes Ir-3 and Ir-4 showed strong absorption in the visible range (ε=39,600  M(-1)  cm(-1) at 402 nm and ε=25,100  M(-1)  cm(-1) at 404 nm, respectively), long-lived triplet excited states (τ(T)=9.30 μs and 16.45 μs) and room-temperature red emission (λ(em)=640 nm, Φ(p)=1.4 % and λ(em)=627 nm, Φ(p)=0.3 %; cf. Ir-1: ε=16,600  M(-1)  cm(-1) at 382 nm, τ(em)=1.16 μs, Φ(p)=72.6 %). Ir-3 was strongly phosphorescent in non-polar solvent (i.e., toluene), but the emission was completely quenched in polar solvents (MeCN). Ir-4 gave an opposite response to the solvent polarity, that is, stronger phosphorescence in polar solvents than in non-polar solvents. Emission of Ir-1 and Ir-2 was not solvent-polarity-dependent. The T(1) excited states of Ir-2, Ir-3, and Ir-4 were identified as mainly intraligand triplet excited states ((3)IL) by their small thermally induced Stokes shifts (ΔE(s)), nanosecond time-resolved transient difference absorption spectroscopy, and spin-density analysis. The complexes were used as triplet photosensitizers for triplet-triplet annihilation (TTA) upconversion and quantum yields of 7.1 % and 14.4 % were observed for Ir-2 and Ir-3, respectively, whereas the upconversion was negligible for Ir-1 and Ir-4. These results will be useful for designing visible-light-harvesting transition-metal complexes and for their applications as triplet photosensitizers for photocatalysis, photovoltaics, TTA upconversion, etc. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Low cost, surfactant-less, one pot synthesis of Cu 2O nano-octahedra at room temperature

NASA Astrophysics Data System (ADS)

Ahmed, Asar; Gajbhiye, Namdeo S.; Joshi, Amish G.

2011-08-01

Cu 2O octahedra were successfully synthesized via a novel wet-chemical method using D-glucose and hydrazine as reducing agent at room temperature without the presence of any other surfactant. Presence of D-glucose was important for the stabilization of the evolved copper octahedra and also for facilitating the reduction of the Cu(II) ions. The existence of glucose moieties on the surface as capping agent was confirmed by the FT-IR spectra while there was presence of excess oxygen atoms on the surface leading to the formation of a thin CuO layer at the octahedra surface, as confirmed by the XPS study, probably promoted by the capping glucose. Effect of NaOH concentration on the reaction and the formation of octahedra was also studied. The formation mechanism of obtained Cu 2O octahedra has been discussed. These octahedra were then studied for their photocatalytic properties in degradation of organic dyes, rhodamine B and methyl orange.

Measurement and modeling of surface temperature dynamics of the NSTX liquid lithium divertor

NASA Astrophysics Data System (ADS)

McLean, A. G.; Gan, K. F.; Ahn, J.-W.; Gray, T. K.; Maingi, R.; Abrams, T.; Jaworski, M. A.; Kaita, R.; Kugel, H. W.; Nygren, R. E.; Skinner, C. H.; Soukhanovskii, V. A.

2013-07-01

Dual-band infrared (IR) measurements of the National Spherical Torus eXperiment (NSTX) Liquid Lithium Divertor (LLD) are reported that demonstrate liquid Li is more effective at removing plasma heat flux than Li-conditioned graphite. Extended dwell of the outer strike point (OSP) on the LLD caused an incrementally larger area to be heated above the Li melting point through the discharge leading to enhanced D retention and plasma confinement. Measurement of Tsurface near the OSP demonstrates a significant reduction of the LLD surface temperature compared to that of Li-coated graphite at the same major radius. Modeling of these data with a 2-D simulation of the LLD structure in the DFLUX code suggests that the structure of the LLD was successful at handling up to q⊥,peak = 5 MW/m2 inter-ELM and up to 10 MW/m2 during ELMs from its plasma-facing surface as intended, and provide an innovative method for inferring the Li layer thickness.

Surface Characterization of Mesoporous CoOx/SBA-15 Catalyst upon 1,2-Dichloropropane Oxidation.

PubMed

Finocchio, Elisabetta; Gonzalez-Prior, Jonatan; Gutierrez-Ortiz, Jose Ignacio; Lopez-Fonseca, Ruben; Busca, Guido; de Rivas, Beatriz

2018-05-29

The active combustion catalyst that is based on 30 wt % cobalt oxide on mesoporous SBA-15 has been tested in 1,2-dichloropropane oxidation and is characterized by means of FT-IR (Fourier transform infrared spectroscopy) and ammonia-TPD (temperature-programmed desorption). In this work, we report the spectroscopic evidence for the role of surface acidity in chloroalkane conversion. Both Lewis acidity and weakly acidic silanol groups from SBA support are involved in the adsorption and initial conversion steps. Moreover, total oxidation reaction results in the formation of new Bronsted acidic sites, which are likely associated with the generation of HCl at high temperature and its adsorption at the catalyst surface. Highly dispersed Co oxide on the mesoporous support and Co-chloride or oxychloride particles, together with the presence of several families of acidic sites originated from the conditioning effect of reaction products may explain the good activity of this catalyst in the oxidation of Chlorinated Volatile Organic Compounds.

Preparation and characterization of mesoporous TiO2-sphere-supported Au-nanoparticle catalysts with high activity for CO oxidation at ambient temperature

NASA Astrophysics Data System (ADS)

Wang, Lili; Huang, Shouying; Zhu, Baolin; Zhang, Shoumin; Huang, Weiping

2016-11-01

Mesoporous TiO2-sphere-supported Au-nanoparticles (Au/m-TiO2-spheres) catalysts have been synthesized by a simple method using tetrabutyl titanate as TiO2 precursor and characterized with XRD, BET, ICP, SEM, TEM, UV-Vis DRS, XPS, as well as FT-IR. The samples with the size in the range of 200-400 nm were almost perfectly spherical. The average diameter of pores was about 3.6 nm, and the mesopore size distribution was in the range of 2-6 nm with a narrow distribution. When the catalyst was calcined at 300 °C, the Au NPs with the size ca. 5 nm were highly dispersed on the surfaces of m-TiO2 spheres and partially embedded in the supports. Remarkably, the specific surface area of the Au/m-TiO2-spheres was as high as 117 m2 g-1. The CO-adsorbed catalyst showed an apparent IR adsorption peak at 1714 cm-1 that matched with bridging model CO. It means the catalysts should be of high catalytic activity for the CO oxidation due to they could adsorb and activate CO commendably. When Au-content was 0.48 wt.%, the Au/m-TiO2-spheres could convert CO completely into CO2 at ambient temperature.

SO2 adsorption on silica supported iridium.

PubMed

Bounechada, Djamela; Anderson, David P; Skoglundh, Magnus; Carlsson, Per-Anders

2017-02-28

The interaction of SO 2 with Ir/SiO 2 was studied by simultaneous in situ diffuse reflectance infrared Fourier transform spectroscopy and mass spectrometry, exposing the sample to different SO 2 concentrations ranging from 10 to 50 ppm in the temperature interval 200-400 °C. Evidences of adsorption of sulfur species in both absence and presence of oxygen are found. For a pre-reduced sample in the absence of oxygen, SO 2 disproportionates such that the iridium surface is rapidly saturated with adsorbed S while minor amounts of formed SO 3 may adsorb on SiO 2 . Adding oxygen to the feed leads to the oxidation of sulfide species that either (i) desorb as SO 2 and/or SO 3 , (ii) remain at metal sites in the form of adsorbed SO 2 , or (iii) spillover to the oxide support and form sulfates (SO 4 2- ). Notably, significant formation of sulfates on silica is possible only in the presence of both SO 2 and O 2 , suggesting that SO 2 oxidation to SO 3 is a necessary first step in the mechanism of formation of sulfates on silica. During the formation of sulfates, a concomitant removal/rearrangement of surface silanol groups is observed. Finally, the interaction of SO 2 with Ir/SiO 2 depends primarily on the temperature and type of gas components but only to a minor extent on the inlet SO 2 concentration.

SO2 adsorption on silica supported iridium

NASA Astrophysics Data System (ADS)

Bounechada, Djamela; Anderson, David P.; Skoglundh, Magnus; Carlsson, Per-Anders

2017-02-01

The interaction of SO2 with Ir/SiO2 was studied by simultaneous in situ diffuse reflectance infrared Fourier transform spectroscopy and mass spectrometry, exposing the sample to different SO2 concentrations ranging from 10 to 50 ppm in the temperature interval 200-400 °C. Evidences of adsorption of sulfur species in both absence and presence of oxygen are found. For a pre-reduced sample in the absence of oxygen, SO2 disproportionates such that the iridium surface is rapidly saturated with adsorbed S while minor amounts of formed SO3 may adsorb on SiO2. Adding oxygen to the feed leads to the oxidation of sulfide species that either (i) desorb as SO2 and/or SO3, (ii) remain at metal sites in the form of adsorbed SO2, or (iii) spillover to the oxide support and form sulfates (SO42-). Notably, significant formation of sulfates on silica is possible only in the presence of both SO2 and O2, suggesting that SO2 oxidation to SO3 is a necessary first step in the mechanism of formation of sulfates on silica. During the formation of sulfates, a concomitant removal/rearrangement of surface silanol groups is observed. Finally, the interaction of SO2 with Ir/SiO2 depends primarily on the temperature and type of gas components but only to a minor extent on the inlet SO2 concentration.

Ti/IrO2/SnO2 anode for electrochemical degradation of chlorpyrifos in water: optimization and degradation performances

NASA Astrophysics Data System (ADS)

Pathiraja, G. C.; Wijesingha, M. S.; Nanayakkara, N.

2017-05-01

Chlorpyrifos, a widely used organophosphate pesticide which can be found in surface water bodies, is harmful for human body. Thus, treating water contaminated with chlorpyrifos is important. In our previous studies, novel Ti/IrO2-SnO2 anode was successfully developed for electrochemical degradation of chlorpyrifos in chloride free water. In this study, optimization of previously developed Ti/IrO2-SnO2 anode for mineralization of chlorpyrifos was successfully performed through response surface methodology. During the optimization study, two-level factorial design was used to determine the optimal coating solutions concentration for developing the Ti/IrO2-SnO2 anode. Cyclic voltammetry and open circuit potential were performed to investigate the electrochemically active surface area and stability of these anodes. The response surface and contour plots show that 0.3 M of [Ir] and 7.5 mM of [Sn] coated electrode has both highest anodic charge and stability. Scanning Electron Microscopic (SEM) images show the evidence of having both compact and porous regions in the surface of the thin film, resulting larger surface area. Within 6 h, the best result for mineralization (55.56%) of chlorpyrifos was obtained with 0.3 M of [Ir] and 7.5 mM of [Sn] coated anode using Total organic Carbon (TOC) analyzer. Therefore, the optimum coating concentration was found as 0.3 M of [Ir] and 7.5 mM of [Sn]. It would require an energy consumption of 6 kWhm-3.

Upper wide-angle viewing system for ITER.

PubMed

Lasnier, C J; McLean, A G; Gattuso, A; O'Neill, R; Smiley, M; Vasquez, J; Feder, R; Smith, M; Stratton, B; Johnson, D; Verlaan, A L; Heijmans, J A C

2016-11-01

The Upper Wide Angle Viewing System (UWAVS) will be installed on five upper ports of ITER. This paper shows major requirements, gives an overview of the preliminary design with reasons for some design choices, examines self-emitted IR light from UWAVS optics and its effect on accuracy, and shows calculations of signal-to-noise ratios for the two-color temperature output as a function of integration time and divertor temperature. Accurate temperature output requires correction for vacuum window absorption vs. wavelength and for self-emitted IR, which requires good measurement of the temperature of the optical components. The anticipated signal-to-noise ratio using presently available IR cameras is adequate for the required 500 Hz frame rate.

Spatial and Temporal Inter-Relationships between Anomalies and Trends of Temperature, Moisture, Cloud Cover, and OLR as Observed by AIRS/AMSU on Aqua

NASA Technical Reports Server (NTRS)

Susskind, Joel

2008-01-01

AIRS/AMSU is the advanced IR/MW atmospheric sounding system launched on EOS Aqua in May 2002. Products derived from AIRS/AMSU by the AIRS Science Team include surface skin temperature and atmospheric temperature profiles; atmospheric humidity profiles, fractional cloud cover and cloud top pressure, and OLR. Products covering the period September 2002 through the present have been derived from AIRS/AMSU using the AIRS Science Team Version 5 retrieval algorithm. In this paper, we will show results covering the time period September 2006 - November 2008. This time period is marked by a substantial warming trend of Northern Hemisphere Extratropical land surface skin temperatures, as well as pronounced El Nino - La Nina episodes. These both influence the spatial and temporal anomaly patterns of atmospheric temperature and moisture profiles, as well as of cloud cover and Clear sky and All Sky OLR. The relationships between temporal and spatial anomalies of these parameters over this time period, as determined from AIRS/AMSU observations, will be shown, with particular emphasis on which contribute significantly to OLR anomalies in each of the tropics and extra-tropics. Results will also be shown to validate the anomalies and trends of temperature profiles and OLR as determined from analysis of AIRS/AMSU data. Global and regional trends during the 6 1/3 year period are not necessarily indicative of what has happened in the past, or what may happen in the future. Nevertheless, the inter-relationships of spatial and temporal anomalies of atmospheric geophysical parameters with those of surface skin temperature are indicative of climate processes, and can be used to test the performance of climate models when driven by changes in surface temperatures.

Spatial and Temporal Inter-Relationship between Anomalies and Trends of Temperature, Moisture, Cloud Cover and OLR as Observed by AIRS/AMSU on Aqua

NASA Technical Reports Server (NTRS)

Susskind, Joel; Molnar, Gyula

2009-01-01

AIRS/AMSU is the advanced IR/MW atmospheric sounding system launched on EOS Aqua in May 2002. Products derived from AIRS/AMSU by the AIRS Science Team include surface skin temperature and atmospheric temperature profiled; atmospheric humidity profiles, fractional cloud clover and cloud top pressure, and OLR. Products covering the period September 2002 through the present have been derived from AIRS/AMSU using the AIRS Science Team Version 5 retrieval algorithm. In this paper, we will show results covering the time period September 2006 - November 2008. This time period is marked by a substantial warming trend of Northern Hemisphere Extra-tropical land surface skin temperatures, as well as pronounced El Nino - La Nina episodes. These both influence the spatial and temporal anomaly patterns of atmospheric temperature and moisture profiles, as well as of cloud cover and Clear Sky and All Sky OLR. The relationships between temporal and spatial anomalies of these parameters over this time period, as determined from AIRS/AMSU observations, will be shown with particular emphasis on which contribute significantly to OLR anomalies in each of the tropics and extra-tropics. Results will also be shown to evaluate the anomalies and trends of temperature profiles and OLR as determined from analysis of AIRS/AMSU data. Global and regional trends during the 6 1/3 year time period are not necessarily indicative of what has happened in the past, or what may happen in the future. Nevertheless, the inter-relationships of spatial and temporal anomalies of atmospheric geophysical parameters with those of surface skin temperature are indicative of climate processes, and can be used to test the performance of climate models when driven by changes in surface temperatures.

Efficacy, persistence and vector susceptibility to pirimiphos-methyl (Actellic 300CS) insecticide for indoor residual spraying in Zanzibar.

PubMed

Haji, Khamis A; Thawer, Narjis G; Khatib, Bakari O; Mcha, Juma H; Rashid, Abdallah; Ali, Abdullah S; Jones, Christopher; Bagi, Judit; Magesa, Stephen M; Ramsan, Mahdi M; Garimo, Issa; Greer, George; Reithinger, Richard; Ngondi, Jeremiah M

2015-12-09

Indoor residual spraying (IRS) of households with insecticide is a principal malaria vector control intervention in Zanzibar. In 2006, IRS using the pyrethroid lambda-cyhalothrine was introduced in Zanzibar. Following detection of pyrethroid resistance in 2010, an insecticide resistance management plan was proposed, and IRS using bendiocarb was started in 2011. In 2014, bendiocarb was replaced by pirimiphos methyl. This study investigated the residual efficacy of pirimiphos methyl (Actellic 300CS) sprayed on common surfaces of human dwellings in Zanzibar. The residual activity of Actellic 300CS was determined over 9 months through bioassay tests that measured the mortality of female Anopheles mosquitoes, exposed to sprayed surfaces under a WHO cone. The wall surfaces included; mud wall, oil or water painted walls, lime washed wall, un-plastered cement block wall and stone blocks. Insecticide susceptibility testing was done to investigate the resistance status of local malaria vectors against Actellic 300CS using WHO protocols; Anopheline species were identified using PCR methods. Baseline tests conducted one-day post-IRS revealed 100% mortality on all sprayed surfaces. The residual efficacy of Actellic 300CS was maintained on all sprayed surfaces up to 8 months post-IRS. However, the bioassay test conducted 9 months post-IRS showed the 24 h mortality rate to be ≤80% for lime wash, mud wall, water paint and stone block surfaces. Only oil paint surface retained the recommended residual efficacy beyond 9 months post-IRS, with mortality maintained at ≥97 %. Results of susceptibility tests showed that malaria vectors in Zanzibar were fully (100%) susceptible to Actellic 300CS. The predominant mosquito vector species was An. arabiensis (76.0%) in Pemba and An. gambiae (83.5%) in Unguja. The microencapsulated formulation of pirimiphos methyl (Actellic 300CS) is a highly effective and appropriate insecticide for IRS use in Zanzibar as it showed a relatively prolonged residual activity compared to other products used for the same purpose. The insecticide extends the residual effect of IRS thereby making it possible to effectively protect communities with a single annual spray round reducing overall costs. The insecticide proved to be a useful alternative in insecticide resistance management plans.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mei, Donghai; Lebarbier, Vanessa M.; Rousseau, Roger

In a combined experimental and first-principles density functional theory (DFT) study, benzene steam reforming (BSR) over MgAl 2O 4 supported Rh and Ir catalysts was investigated. Experimentally, it has been found that both highly dispersed Rh and Ir clusters (1-2 nm) on the MgAl 2O 4 spinel support are stable during the BSR in the temperature range of 700-850°C. Compared to the Ir/MgAl 2O 4 catalyst, the Rh/MgAl 2O 4 catalyst is more active with higher benzene turnover frequency and conversion. At typical steam conditions with the steam-to-carbon ratio > 12, the benzene conversion is only a weak function ofmore » the H 2O concentration in the feed. This suggests that the initial benzene decomposition step rather than the benzene adsorption is most likely the rate-determined step in BSR over supported Rh and Ir catalysts. In order to understand the differences between the two catalysts, we followed with a comparative DFT study of initial benzene decomposition pathways over two representative model systems for each supported metal (Rh and Ir) catalysts. A periodic terrace (111) surface and an amorphous 50-atom metal cluster with a diameter of 1.0 nm were used to represent the two supported model catalysts under low and high dispersion conditions. Our DFT results show that the decreasing catalyst particle size enhances the benzene decomposition on supported Rh catalysts by lowering both C-C and C-H bond scission. The activation barriers of the C-C and the C-H bond scission decrease from 1.60 and 1.61 eV on the Rh(111) surface to 1.34 and 1.26 eV on the Rh50 cluster. For supported Ir catalysts, the decreasing particle size only affects the C-C scission. The activation barrier of the C-C scission of benzene decreases from 1.60 eV on the Ir(111) surface to 1.35 eV on the Ir50 cluster while the barriers of the C-H scission are practically the same. The experimentally measured higher BSR activity on the supported highly dispersed Rh catalyst can be rationalized by the thermodynamic limitation for the very first C-C bond scission of benzene on the small Ir50 catalyst. The C-C bond scission of benzene on the small Ir50 catalyst is highly endothermic although the barrier is competitive with the barriers of both the C-C and the C-H bond-breakings on the small Rh50 catalyst. The calculations also imply that, for the supported Rh catalysts the C-C and C-H bond scissions are competitive, independently of the Rh cluster sizes. After the initial dissociation step via either the C-C or the C-H bond scission, the C-H bond breaking seems to be more favorable rather than the C-C bond breaking on the larger Rh terrace surface. This work was financially supported by the United States Department of Energy’s Office of Biomass Program’s. Computing time was granted by a user project at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.« less

Diffuse Reflectance FT-IR Of Surface Modified Kevlar

NASA Astrophysics Data System (ADS)

Benrashid, R.; Tesoro, G.; McKenzie, M. T., Jr.

1989-12-01

Diffuse reflectance FT-IR (DRIFT) has been applied to the characterization of surface modified Kevlar 29 and 49 fibers. The surface modifications include amination and sulfonation. The standard DRIFT experiment has been modified in the manner first described by Koenig et.al. 1 who used a KBR overlayer to enhance surface functional IR bands. The results from the DRIFT experiment have been correlated with those from a standard dye test. The results for degree of modification are in reasonable agreement between the two measurement approaches. However, the dye experiment is time-consuming and inconvenient. DRIFT has been shown to be useful in characterizing modified Kevlar surfaces in as-used conditions.

Iridium-Coated Rhenium Radiation-Cooled Rockets

NASA Technical Reports Server (NTRS)

Reed, Brian D.; Biaglow, James A.; Schneider, Steven J.

1997-01-01

Radiation-cooled rockets are used for a range of low-thrust propulsion functions, including apogee insertion, attitude control, and repositioning of satellites, reaction control of launch vehicles, and primary propulsion for planetary space- craft. The key to high performance and long lifetimes for radiation-cooled rockets is the chamber temperature capability. The material system that is currently used for radiation-cooled rockets, a niobium alloy (C103) with a fused silica coating, has a maximum operating temperature of 1370 C. Temperature limitations of C103 rockets force the use of fuel film cooling, which degrades rocket performance and, in some cases, imposes a plume contamination issue from unburned fuel. A material system composed of a rhenium (Re) substrate and an iridium (Ir) coating has demonstrated operation at high temperatures (2200 C) and for long lifetimes (hours). The added thermal margin afforded by iridium-coated rhenium (Ir/Re) allows reduction or elimination of fuel film cooling. This, in turn, leads to higher performance and cleaner spacecraft environments. There are ongoing government- and industry-sponsored efforts to develop flight Ir/ Re engines, with the primary focus on 440-N, apogee insertion engines. Complementing these Ir/Re engine development efforts is a program to address specific concerns and fundamental characterization of the Ir/Re material system, including (1) development of Ir/Re rocket fabrication methods, (2) establishment of critical Re mechanical properly data, (3) development of reliable joining methods, and (4) characterization of Ir/Re life-limiting mechanisms.

Millimeter-wave imaging sensor data evaluation

NASA Technical Reports Server (NTRS)

Wilson, William J.; Ibbott, Anthony C.

1987-01-01

A passive 3-mm radiometer system with a mechanically scanned antenna was built for use on a small aircraft or an Unmanned Aerial Vehicle to produce real near-real-time, moderate-resolution (0.5) images of the ground. One of the main advantages of this passive imaging sensor is that it is able to provide surveillance information through dust, smoke, fog and clouds when visual and IR systems are unusable. It can also be used for a variety of remote sensing applications, such as measurements of surface moisture, surface temperature, vegetation extent and snow cover. It is also possible to detect reflective objects under vegetation cover.

Infrared spectroscopic studies of the effect of elevated temperature on the association of pyroglutamic acid with clay and other minerals

NASA Astrophysics Data System (ADS)

Macklin, John W.; White, David H.

Fourier transform i.r. measurements of L-pyroglutamic acid dispersed in a matrix of a clay, silica or alumina have been obtained at various temperatures between 25 and 220°C. The i.r. spectrum of L-pyroglutamic acid varies in a manner slightly dependent upon the matrix material and shows considerable change as the temperature of the mixtures is increased. The differences in the spectrum at elevated temperatures are explained in terms of a chemical reaction between hydroxyl groups in the matrix and the carboxylic acid. The i.r. spectra of trimethylsilyl derivatives of L-pyroglutamic acid and aluminum pyroglutamate were also measured to assist the understanding of spectra and interpretation of the spectral changes dependent upon increasing temperature.

Infrared spectroscopic studies of the effect of elevated temperature on the association of pyroglutamic acid with clay and other minerals

NASA Technical Reports Server (NTRS)

Macklin, J. W.; White, D. H.

1985-01-01

Fourier transform i.r. measurements of L-pyroglutamic acid dispersed in a matrix of a clay, silica or alumina have been obtained at various temperatures between 25 and 220 degrees C. The i.r. spectrum of L-pyroglutamic acid varies in a manner dependent upon the matrix material and shows considerable change as the temperature of the mixtures is increased. The differences in the spectrum at elevated temperatures are explained in terms of a chemical reaction between hydroxyl groups in the matrix and the carboxylic acid. The i.r. spectra of trimethylsilyl derivatives of L-pyroglutamic acid and aluminum pyroglutamate were also measured to assist the understanding of spectra and interpretation of the spectral changes dependent upon increasing temperature.

Infrared target simulation environment for pattern recognition applications

NASA Astrophysics Data System (ADS)

Savakis, Andreas E.; George, Nicholas

1994-07-01

The generation of complete databases of IR data is extremely useful for training human observers and testing automatic pattern recognition algorithms. Field data may be used for realism, but require expensive and time-consuming procedures. IR scene simulation methods have emerged as a more economical and efficient alternative for the generation of IR databases. A novel approach to IR target simulation is presented in this paper. Model vehicles at 1:24 scale are used for the simulation of real targets. The temperature profile of the model vehicles is controlled using resistive circuits which are embedded inside the models. The IR target is recorded using an Inframetrics dual channel IR camera system. Using computer processing we place the recorded IR target in a prerecorded background. The advantages of this approach are: (1) the range and 3D target aspect can be controlled by the relative position between the camera and model vehicle; (2) the temperature profile can be controlled by adjusting the power delivered to the resistive circuit; (3) the IR sensor effects are directly incorporated in the recording process, because the real sensor is used; (4) the recorded target can embedded in various types of backgrounds recorded under different weather conditions, times of day etc. The effectiveness of this approach is demonstrated by generating an IR database of three vehicles which is used to train a back propagation neural network. The neural network is capable of classifying vehicle type, vehicle aspect, and relative temperature with a high degree of accuracy.

Facile preparation of porous carbon from coffee bean waste using low temperature solvothermal method

NASA Astrophysics Data System (ADS)

Baroroh, L. A. Al; Fitria, D.; Amal, M. I.; Wismogroho, A. S.; Widayatno, W. B.

2018-03-01

In this study, porous carbon made from coffee bean waste (CBW) was carbonized at 500 °C, 600 °C, and 700 °C to find effective temperature. It is verified from the IR spectrum that carbonization process at certain temperature can effectively break cellulose bonding and make aromatics functional group while preserving its carbon structure. The TG-DTA curve shows four stages of decomposition process and confirms most effective carbonization temperature. Activation process of as-carbonized CBW was carried out using solvothermal method in KOH and NH4OH steam environment at 200 °C with variation of 30%, 40%, and 50% solvothermal volume. Scanning electron micrographs reveals significant increase of porosity on the carbon surface and differences of structural pores between the variations. The results show the possible potential of utilizing low temperature-solvothermal method for nanoporous carbon material.

Large enhancement of Blocking temperature by control of interfacial structures in Pt/NiFe/IrMn/MgO/Pt multilayers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Xi; Wang, Shouguo, E-mail: sgwang@ustb.edu.cn; Han, Gang

2015-09-15

The Blocking temperature (T{sub B}) of Pt/NiFe/IrMn/MgO/Pt multilayers was greatly enhanced from far below room temperature (RT) to above RT by inserting 1 nm thick Mg layer at IrMn/MgO interface. Furthermore, the exchange bias field (H{sub eb}) was increased as well by the control of interfacial structures. The evidence for a significant fraction of Mn-O bonding at IrMn/MgO interface without Mg insertion layer was provided by X-ray photoelectron spectroscopy. The bonding between Mn and O can decrease the antiferromagnetism of IrMn film, leading to lower value of T{sub B} in Pt/NiFe/IrMn/MgO/Pt multilayers. Ultrathin Mg film inserted at IrMn/MgO interface actingmore » as an oxygen sinking layer can suppress the oxidation reactions between Mn and O and reduce the formation of Mn-O bonding greatly. The oxidation suppression results in the recovery of the antiferromagnetism of IrMn film, which can enhance T{sub B} and H{sub eb}. Furthermore, the high resolution transmission electron microscopy demonstrates that the Mg insertion layer can efficiently promote a high-quality MgO (200) texture. This study will enhance the understanding of physics in antiferromagnet-based spintronic devices.« less

Structural, electronic and magnetic properties of the series of double perovskites (Ca , Sr) 2 - xLaxFeIrO6

NASA Astrophysics Data System (ADS)

Bufaiçal, L.; Adriano, C.; Lora-Serrano, R.; Duque, J. G. S.; Mendonça-Ferreira, L.; Rojas-Ayala, C.; Baggio-Saitovitch, E.; Bittar, E. M.; Pagliuso, P. G.

2014-04-01

Polycrystalline samples of the series of double perovskites Sr2-xLaxFeIrO6 were synthesized. Their structural, electronic and magnetic properties were investigated by X-ray powder diffraction, Mössbauer spectroscopy, magnetic susceptibility, heat capacity and electrical resistivity experiments. The compounds crystallize in a monoclinic structure and were fitted in space group P21 / n, with a significant degree of Fe/Ir cationic disorder. As in Ca2-xLaxFeIrO6 the Sr-based system seems to evolve from an antiferromagnetic ground state for the end members (x=0.0 and x=2.0) to a ferrimagnetic order in the intermediate regions (x ~ 1). Since Mössbauer spectra indicate that Fe valence remains 3+ with doping, this tendency of change in the nature of the microscopic interaction could be attributed to Ir valence changes, induced by La3+ electrical doping. Upon comparing both Ca and Sr series, Sr2-xLaxFeIrO6 is more structurally homogenous and presents higher magnetization and transition temperatures. Magnetic susceptibility measurements at high temperatures on Sr1.2La0.8FeIrO6 indicate a very high ferrimagnetic Curie temperature TC ~ 700 K. For the Sr2FeIrO6 compound, electrical resistivity experiments under applied pressure suggest that this material might be a Mott insulator.

Thermal Imaging of Medical Saw Blades and Guides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dinwiddie, Ralph Barton; Steffner, Thomas E

2007-01-01

Better Than New, LLC., has developed a surface treatment to reduce the friction and wear of orthopedic saw blades and guides. The medical saw blades were thermally imaged while sawing through fresh animal bone and an IR camera was used to measure the blade temperature as it exited the bone. The thermal performance of as-manufactured saw blades was compared to surface-treated blades, and a freshly used blade was used for temperature calibration purposes in order to account for any emissivity changes due to organic transfer layers. Thermal imaging indicates that the treated saw blades cut faster and cooler than untreatedmore » blades. In orthopedic surgery, saw guides are used to perfectly size the bone to accept a prosthesis. However, binding can occur between the blade and guide because of misalignment. This condition increases the saw blade temperature and may result in tissue damage. Both treated ad untreated saw guides were also studied. The treated saw guide operated at a significantly lower temperature than untreated guide. Saw blades and guides that operate at a cooler temperature are expected to reduce the amount of tissue damage (thermal necrosis) and may reduce the number of post-operative complications.« less

Spatial and Temporal Inter-Relationships Between Anomalies of Temperature, Moisture, Cloud Cover, and OLR as Observed by AIRS/AMSU on Aqua

NASA Technical Reports Server (NTRS)

Susskind, Joel

2008-01-01

AIRS/AMSU is the advanced IR/MW atmospheric sounding system launched on EOS Aqua in May 2002. Products derived from AIRS/AMSU include surface skin temperature and atmospheric temperature profiles; atmospheric humidity profiles, percent cloud cover and cloud top pressure, and OLR. Near real time products, stating with September 2002, have been derived from AIRS/AMSU using the AIRS Science Team Version 5 retrieval algorithm. Results in this paper included products through April 2008. The time period studied is marked by a substantial warming trend of Northern Hemisphere Extropical land surface skin temperatures, as well as pronounced El Nino - La Nina episodes. These both influence the spatial and temporal anomaly patterns of atmospheric temperature and moisture profiles, as well as of cloud cover and Clear Sky and All Sky OLR The relationships between temporal and spatial anomalies of these parameters over this time period, as determined from AIRS/AMSU observations, are shown below, with particular emphasis on which contribute significantly to OLR anomalies in each of the tropics and extra-tropics. The ability to match this data represents a good test of a model's response to El Nino.

Recent Climate Variability in Antarctica from Satellite-derived Temperature Data

NASA Technical Reports Server (NTRS)

Schneider, David P.; Steig, Eric J.; Comiso, Josefino C.

2004-01-01

Recent Antarctic climate variability on month-to-month to interannual time scales is assessed through joint analysis of surface temperatures from satellite thermal infrared observations (T(sub IR)) and passive microwave brightness temperatures (T(sub B)). Although Tw data are limited to clear-sky conditions and T(sub B) data are a product of the temperature and emissivity of the upper approx. 1m of snow, the two data sets share significant covariance. This covariance is largely explained by three empirical modes, which illustrate the spatial and temporal variability of Antarctic surface temperatures. T(sub B) variations are damped compared to TIR variations, as determined by the period of the temperature forcing and the microwave emission depth; however, microwave emissivity does not vary significantly in time. Comparison of the temperature modes with Southern Hemisphere (SH) 500-hPa geopotential height anomalies demonstrates that Antarctic temperature anomalies are predominantly controlled by the principal patterns of SH atmospheric circulation. The leading surface temperature mode strongly correlates with the Southern Annular Mode (SAM) in geopotential height. The second temperature mode reflects the combined influences of the zonal wavenumber-3 and Pacific South American (PSA) patterns in 500-hPa height on month-to-month timescales. ENSO variability projects onto this mode on interannual timescales, but is not by itself a good predictor of Antarctic temperature anomalies. The third temperature mode explains winter warming trends, which may be caused by blocking events, over a large region of the East Antarctic plateau. These results help to place recent climate changes in the context of Antarctica's background climate variability and will aid in the interpretation of ice core paleoclimate records.

Experimental investigation of passive infrared ice detection for helicopter applications

NASA Technical Reports Server (NTRS)

Dershowitz, Adam; Hansman, R. John, Jr.

1991-01-01

A technique is proposed to remotely detect rotor icing on helicopters. Using passive infrared (IR) thermometry it is possible to detect the warming caused by latent heat released as supercooled water freezes. During icing, the ice accretion region on the blade leading edge will be warmer than the uniced trailing edge resulting in a chordwise temperature profile characteristic of icing. Preliminary tests were conducted on a static model in the NASA Icing Research Tunnel for a variety of wet (glaze) and dry (rime) ice conditions. The characteristic chordwise temperature profiles were observed with an IR thermal video system and confirmed with thermocouple measurements. A prototype detector system was built consisting of a single point IR pyrometer, and experiments were run on a small scale rotor model. Again the characteristic chordwise temperature profiles were observed during icing, and the IR system was able to remotely detect icing. Based on the static and subscale rotor tests the passive IR technique is promising for rotor ice detection.

Experimental investigation of passive infrared ice detection for helicopter applications

NASA Technical Reports Server (NTRS)

Dershowitz, Adam; Hansman, R. John, Jr.

1991-01-01

A technique is proposed to remotely detect rotor icing on helicopters. Using passive infrared (IR) thermometry, it is possible to detect the warming caused by latent heat released as supercooled water freezes. During icing, the ice accretion region on the blade leading edge will be warmer than the uniced trailing edge, resulting in a chordwise temperature profile characteristic of icing. Preliminary tests were conducted on a static model in the NASA Icing Research Tunnel for a variety of wet (glaze) and dry (rime) ice conditions. The characteristic chordwise temperature profiles were observed with an IR thermal video system and confirmed with thermocouple measurements. A prototype detector system was built consisting of a single point IR pyrometer. Experiments were run on a small scale rotor model. Again, the characteristic chordwise temperature profiles were observed during icing, and the IR system was able to remotely detect icing. Based on the static and subscale rotor tests, the passive IR technique is promising for rotor ice detection.

Cloud cover over the equatorial eastern Pacific derived from July 1983 International Satellite Cloud Climatology Project data using a hybrid bispectral threshold method

NASA Technical Reports Server (NTRS)

Minnis, Patrick; Harrison, Edwin F.; Gibson, Gary G.

1987-01-01

A set of visible and IR data obtained with GOES from July 17-31, 1983 is analyzed using a modified version of the hybrid bispectral threshold method developed by Minnis and Harrison (1984). This methodology can be divided into a set of procedures or optional techniques to determine the proper contaminate clear-sky temperature or IR threshold. The various optional techniques are described; the options are: standard, low-temperature limit, high-reflectance limit, low-reflectance limit, coldest pixel and thermal adjustment limit, IR-only low-cloud temperature limit, IR clear-sky limit, and IR overcast limit. Variations in the cloud parameters and the characteristics and diurnal cycles of trade cumulus and stratocumulus clouds over the eastern equatorial Pacific are examined. It is noted that the new method produces substantial changes in about one third of the cloud amount retrieval; and low cloud retrievals are affected most by the new constraints.

Electrodeposition of nickel-iridium alloy films from aqueous solutions

NASA Astrophysics Data System (ADS)

Wu, Wangping; Jiang, Jinjin; Jiang, Peng; Wang, Zhizhi; Yuan, Ningyi; Ding, Jianning

2018-03-01

Nickel-iridium (Ni-Ir) alloy films were electrodeposited from aqueous solutions on copper substrates under galvanostatic conditions. The effects of bath composition and deposition time on the faradaic efficiency (FE), partial current densities, chemical composition, morphology and crystallographic structure of the films were studied. The results show that the Ni-Ir alloys with Ir content as high as 37 at% and FE as high as 44% were obtained. Increase in concentration of citric acid had little or no effect on the composition of the alloys, but resulted in a significant decrease in FE and partial current densities of Ni and Ir. The FE and the partial current density of Ni slightly decreased with increasing Ir3+ concentration, however, Ir content increased while partial current density of Ir remained stable. The increase of Ni2+ concentration could result in the increase of the FE and the rate of Ni-Ir deposition, and even no cracks formed on the surface. The surface average roughness and root mean square roughness of the film were 6.8 ± 0.3 nm and 5.4 ± 0.3 nm, respectively. The mixture phases contained significant amounts of Ni oxides and a small amount of metallic Ni, Ir and Ir oxides on the surface. After argon ion sputter cleaning, the film was mainly composed of metallic Ni and Ir. The film consisted of the amorphous and nanocrystalline phases. The Ni content in the deposits was higher than that in the electrolyte, the co-deposition of Ni-Ir alloy was a normal deposition.

Thermal Image Sensing Model for Robotic Planning and Search.

PubMed

Castro Jiménez, Lídice E; Martínez-García, Edgar A

2016-08-08

This work presents a search planning system for a rolling robot to find a source of infra-red (IR) radiation at an unknown location. Heat emissions are observed by a low-cost home-made IR passive visual sensor. The sensor capability for detection of radiation spectra was experimentally characterized. The sensor data were modeled by an exponential model to estimate the distance as a function of the IR image's intensity, and, a polynomial model to estimate temperature as a function of IR intensities. Both theoretical models are combined to deduce a subtle nonlinear exact solution via distance-temperature. A planning system obtains feed back from the IR camera (position, intensity, and temperature) to lead the robot to find the heat source. The planner is a system of nonlinear equations recursively solved by a Newton-based approach to estimate the IR-source in global coordinates. The planning system assists an autonomous navigation control in order to reach the goal and avoid collisions. Trigonometric partial differential equations were established to control the robot's course towards the heat emission. A sine function produces attractive accelerations toward the IR source. A cosine function produces repulsive accelerations against the obstacles observed by an RGB-D sensor. Simulations and real experiments of complex indoor are presented to illustrate the convenience and efficacy of the proposed approach.

Comparison of iridium- and ruthenium-based, Pt-surface-enriched, nanosize catalysts for the oxygen-reduction reaction

NASA Astrophysics Data System (ADS)

Kaplan, D.; Goor, M.; Alon, M.; Tsizin, S.; Burstein, L.; Rosenberg, Y.; Popov, I.; Peled, E.

2016-02-01

Pt-surface-enriched nanosize catalysts (Pt-SENS catalysts) with ruthenium and iridium cores, supported on XC72, were synthesized and characterized. The structure and composition of the catalysts are determined by Energy-Dispersive X-ray Spectroscopy (EDS), X-ray Photoelectron Spectroscopy (XPS), Scanning Transmission Electron Microscopy (STEM) and X-Ray Diffraction (XRD). Electrochemical characterization tests, including oxygen-reduction-catalysis activity and durability studies of catalysts are performed with the use of cyclic-voltammetry and rotating-disk-electrode (RDE) techniques at room temperature. The ORR activity of the homemade catalysts is also compared to ORR activity of commercial 50%Pt/C catalyst. It is determined that the Ir-based catalyst (Pt/Ir/XC72) shows higher ORR activity in terms of A g-1 of Pt (at 0.85 V vs. RHE) than the Ru-based catalyst (Pt/Ru/XC72) and the commercial 50%Pt/C. The Ru-based catalyst shows similar ORR activity in terms of A g-1 of Pt, to that of the commercial 50%Pt/C, but with much lower durability.

Entrained-flow gasifier and fluidized-bed combustor temperature monitoring using arrays of fs-IR written fiber Bragg gratings

NASA Astrophysics Data System (ADS)

Walker, Robert B.; Ding, Huimin; Coulas, David; Grobnic, Dan; Mihailov, Stephen J.; Duchesne, Marc A.; Hughes, Robin W.; McCalden, David J.; Burchat, Ryan

2015-09-01

Femtosecond written fiber Bragg gratings, have shown great potential for sensing in extreme environments. This paper discusses the fabrication and deployment of several fs-IR written FBG arrays, for monitoring main-spool skin temperatures of an entrained-flow gasifier, as well as the internal temperature gradient of a fluidized bed combustor.

On the symmetry and crystal structures of Ba{sub 2}LaIrO{sub 6}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fu, W.T., E-mail: w.fu@chem.leidenuniv.n; Goetz, R.J.; IJdo, D.J.W.

2010-02-15

Accurate profile analysis of X-ray diffraction data was carried out to settle recent dispute on the symmetry and crystal structures of the double perovskite Ba{sub 2}LaIrO{sub 6}. Even through careful comparison of the full-width at half-maximum values, we found no evidence for Ba{sub 2}LaIrO{sub 6} adopting either monoclinic (I2/m) or mixed rhombohedral (R3-bar) and monoclinic (I2/m) structures at room temperature, becoming triclinic (I1-bar) at below about 200 K. The correct space group is just R3-bar at temperatures between 82 and 653 K. Furthermore, the R3-bar->Fm3-barm phase transition does occur in Ba{sub 2}LaIrO{sub 6}, but the transition temperature is found tomore » be much higher than the reported value. - Graphical abstract: Observed (crosses) and calculated (continuous line) profiles of Ba{sub 2}LaIrO{sub 6} at some selected temperature showing the region containing the basic (222), (321) and (400) reflections. Tick marks below indicate the positions of the allowed Bragg's reflections.« less

Retrieval of Surface Lambert Albedos and Aerosols Optical Depths Using OMEGA Near-IR EPF Observations of Mars

NASA Astrophysics Data System (ADS)

Vincendon, M.; Langevin, Y.; Poulet, F.; Bibring, J.-P.; Gondet, B.

2007-03-01

We have analyzed five EPF sequences acquired by OMEGA/Mars Express in the near-IR over ice-free and ice-covered surfaces to retrieve simultaneously the Lambert albedo of the surface and the optical depth of aerosols.

Real time quantitative imaging for semiconductor crystal growth, control and characterization

NASA Technical Reports Server (NTRS)

Wargo, Michael J.

1991-01-01

A quantitative real time image processing system has been developed which can be software-reconfigured for semiconductor processing and characterization tasks. In thermal imager mode, 2D temperature distributions of semiconductor melt surfaces (900-1600 C) can be obtained with temperature and spatial resolutions better than 0.5 C and 0.5 mm, respectively, as demonstrated by analysis of melt surface thermal distributions. Temporal and spatial image processing techniques and multitasking computational capabilities convert such thermal imaging into a multimode sensor for crystal growth control. A second configuration of the image processing engine in conjunction with bright and dark field transmission optics is used to nonintrusively determine the microdistribution of free charge carriers and submicron sized crystalline defects in semiconductors. The IR absorption characteristics of wafers are determined with 10-micron spatial resolution and, after calibration, are converted into charge carrier density.

Durable warmth retention finishing of down using titanium dioxide optimized by RSM

NASA Astrophysics Data System (ADS)

Li, Huihao; Qi, Lu; Li, Jun

2017-03-01

A new product, referred to herein as modified down, was prepared by grafting down fiber with titanium dioxide. Grafting modification brings new functionalities to down Using response surface methodology (RSM); the effect of titanium dioxide concentration, KH550 concentration, and baking temperature on the warmth retention is studied using the response surface method (RSM) to obtain the optimal experimental formula and models. The optimal preparation conditions for modified down were 19.35% titanium dioxide, 15.81% KH550, 10min baking time, and 115 °C temperature. The warmth retention of the modified down was 79.98%, The structure and property of modified down were characterized and analyzed by using Flat Plate Warmth Retaining Tester, FT-IR, and TG. The CLO value increased by 27.28%, the thermal resistance increased by 27.34%. The ultimate residual quantities of the modified down fibers were 30.05%.

Short poster presentations

NASA Astrophysics Data System (ADS)

Cremonese, Gabriele

I.Holin, core-mantle interplay from spin variation of Mercury's crust G.Murakami et al., de-velopment of the microchannel plate detector for fuv spectroscopy in the bepicolombo mission K.Yoshioka et al., performance of the euv detector of phebus for the bepicolombo mission L.Ksanfomality, large dark area on Mercury neighboring the s basin L.Czechowsk,delamination of the lithosphere and similar processes in terrestrial planets R.Ziethe, Mercury's thermal evo-lution, dynamical topography and geoid S.Ferrari et al., geo-structural mapping and age de-terminations of Rembrandt basin F.Nestola et al., low-high temperature behaviour of olivine: implication for Mercury surface M.Blecka, influence the temperatures of the surface and gaseous environment of Mercury on ir radiance spectra -the results of numerical simulation V.Iafolla et al., contributions of isa accelerometer to bepicolombo exploration of planet mercury Y.Miyake et al., particle-in-cell analysis of an electric antenna for the bepicolombo/mmo spacecraft

Stabilization of Co{sup 2+} in layered double hydroxides (LDHs) by microwave-assisted ageing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Herrero, M.; Benito, P.; Labajos, F.M.

2007-03-15

Co-containing layered double hydroxides at different pH have been prepared, and aged following different routes. The solids prepared have been characterized by element chemical analysis, powder X-ray diffraction, thermogravimetric and differential thermal analyses (both in nitrogen and in oxygen), FT-IR and Vis-UV spectroscopies, temperature-programmed reduction and surface area assessment by nitrogen adsorption at -196 deg. C. The best conditions found to preserve the cobalt species in the divalent oxidation state are preparing the samples at controlled pH, and then submit them to ageing under microwave irradiation. - Graphical abstract: The use of microwave-hydrothermal treatment, controlling both temperature and ageing time,more » permits to synthesize well-crystallized nanomaterials with controlled surface properties. An enhancement in the crystallinity degree and an increase in the particle size are observed when the irradiation time is prolonged.« less

Upper wide-angle viewing system for ITER

DOE PAGES

Lasnier, C. J.; McLean, A. G.; Gattuso, A.; ...

2016-08-15

The Upper Wide Angle Viewing System (UWAVS) will be installed on five upper ports of ITER. Here, this paper shows major requirements, gives an overview of the preliminary design with reasons for some design choices, examines self-emitted IR light from UWAVS optics and its effect on accuracy, and shows calculations of signal-to-noise ratios for the two-color temperature output as a function of integration time and divertor temperature. Accurate temperature output requires correction for vacuum window absorption vs. wavelength and for self-emitted IR, which requires good measurement of the temperature of the optical components. The anticipated signal-to-noise ratio using presently availablemore » IR cameras is adequate for the required 500 Hz frame rate.« less

Dissolution of brominated epoxy resins by dimethyl sulfoxide to separate waste printed circuit boards.

PubMed

Zhu, Ping; Chen, Yan; Wang, Liangyou; Qian, Guangren; Zhang, Wei Jie; Zhou, Ming; Zhou, Jin

2013-03-19

Improved methods are required for the recycling of waste printed circuit boards (WPCBs). In this study, WPCBs (1-1.5 cm(2)) were separated into their components using dimethyl sulfoxide (DMSO) at 60 °C for 45 min and a metallographic microscope was used to verify their delamination. An increased incubation time of 210 min yielded a complete separation of WPCBs into their components, and copper foils and glass fibers were obtained. The separation time decreased with increasing temperature. When the WPCB size was increased to 2-3 cm(2), the temperature required for complete separation increased to 90 °C. When the temperature was increased to 135 °C, liquid photo solder resists could be removed from the copper foil surfaces. The DMSO was regenerated by rotary decompression evaporation, and residues were obtained. Fourier transform infrared spectroscopy (FT-IR), thermal analysis, nuclear magnetic resonance, scanning electron microscopy, and energy-dispersive X-ray spectroscopy were used to verify that these residues were brominated epoxy resins. From FT-IR analysis after the dissolution of brominated epoxy resins in DMSO it was deduced that hydrogen bonding may play an important role in the dissolution mechanism. This novel technology offers a method for separating valuable materials and preventing environmental pollution from WPCBs.

Magnetocaloric effect in Sr2CrIrO6 double perovskite: Monte Carlo simulation

NASA Astrophysics Data System (ADS)

El Rhazouani, O.; Slassi, A.; Ziat, Y.; Benyoussef, A.

2017-05-01

Monte Carlo simulation (MCS) combined with the Metropolis algorithm has been performed to study the magnetocaloric effect (MCE) in the promising double perovskite (DP) Sr2CrIrO6 that has not so far been synthetized. This paper presents the global magneto-thermodynamic behavior of Sr2CrIrO6 compound in term of MCE and discusses the behavior in comparison to other DPs. Thermal dependence of the magnetization has been investigated for different values of reduced external magnetic field. Thermal magnetic entropy and its change have been obtained. The adiabatic temperature change and the relative cooling power have been established. Through the obtained results, Sr2CrIrO6 DP could have some potential applications for magnetic refrigeration over a wide temperature range above room temperature and at large magnetic fields.

Molecular hydrogen in the vicinity of NGC 7538 IRS 1 and IRS 2 - Temperature and ortho-to-para ratio

NASA Technical Reports Server (NTRS)

Hoban, Susan; Reuter, Dennis C.; Mumma, Michael J.; Storrs, Alex D.

1991-01-01

Near-infrared spectroscopic observations of the active star-forming region near NGC 7538 IRS 1 and IRS 2 were made. The relative intensities of the v = 1-0 Q(1), Q(3), and Q(5) lines of molecular hydrogen are used to calculate a rotational excitation temperature. Comparison of the measured intensity of the Q(2) transition relative to the intensity of Q(1) and Q(3) permitted the retrieval of the ratio of ortho-to-para hydrogen. It is found that an ortho-to-para ratio of between 1.6 and 2.35 is needed to explain the Q-branch line intensity ratios, depending on the excitation model used. This range in ortho-to-para ratios implies a range of molecular hydrogen formation temperature of approximately 105 K to 140 K.

A High-Resolution Measurement of Ball IR Black Paint's Low-Temperature Emissivity

NASA Technical Reports Server (NTRS)

Tuttle, Jim; Canavan, Ed; DiPirro, Mike; Li, Xiaoyi; Franck, Randy; Green, Dan

2011-01-01

High-emissivity paints are commonly used on thermal control system components. The total hemispheric emissivity values of such paints are typically high (nearly 1) at temperatures above about 100 Kelvin, but they drop off steeply at lower temperatures. A precise knowledge of this temperature-dependence is critical to designing passively-cooled components with low operating temperatures. Notable examples are the coatings on thermal radiators used to cool space-flight instruments to temperatures below 40 Kelvin. Past measurements of low-temperature paint emissivity have been challenging, often requiring large thermal chambers and typically producing data with high uncertainties below about 100 Kelvin. We describe a relatively inexpensive method of performing high-resolution emissivity measurements in a small cryostat. We present the results of such a measurement on Ball InfraRed BlackTM(BIRBTM), a proprietary surface coating produced by Ball Aerospace and Technologies Corp (BATC), which is used in spaceflight applications. We also describe a thermal model used in the error analysis.

Large-scale synthesis of a novel tri(8-hydroxyquioline) aluminum nanostructure.

PubMed

Tian, Xike; Fei, Jinbo; Pi, Zhenbang; Yang, Chao; Xiao, Zhidong; Zhang, Lide

2006-08-01

A novel tri(8-hydroxyquioline) aluminum (AlQ3) nanostructure was prepared on large scale at low cost by low-temperature physical vapor deposition (PVD). The morphologies, the chemical bondings, and photoluminescence of the AlQ3 nanostructure were investigated by environmental scanning electronic microscopy (ESEM), Fourier transform infrared spectrum (FT-IR), and photoluminescence (PL) spectra, respectively. The AlQ3 nanostructure was composed of micro-sphere with nanowire-cluster growing on the surface. The diameter of micro-sphere and nanowire were about 5 microm and 80 nm, respectively. FT-IR results indicated that the AlQ3 molecule had a strong thermal stability under research conditions. The growth mechanism of the novel nanostructure was discussed. The novel organic nanostructure would be believed to attractive building field-emission devices and other optical devices.

Thermally and vibrationally induced conformational isomerizations, infrared spectra, and photochemistry of gallic acid in low-temperature matrices

NASA Astrophysics Data System (ADS)

Justino, Licínia L. G.; Reva, Igor; Fausto, Rui

2016-07-01

Near-infrared (near-IR) narrowband selective vibrational excitation and annealing of gallic acid (3,4,5-trihydroxybenzoic acid) isolated in cryogenic matrices were used to induce interconversions between its most stable conformers. The isomerizations were probed by infrared spectroscopy. An extensive set of quantum chemical calculations, carried out at the DFT(B3LYP)/6-311++G(d,p) level of approximation, was used to undertake a detailed analysis of the ground state potential energy surface of the molecule. This investigation of the molecule conformational space allowed extracting mechanistic insights into the observed annealing- or near-IR-induced isomerization processes. The infrared spectra of the two most stable conformers of gallic acid in N2, Xe, and Ar matrices were fully assigned. Finally, the UV-induced photochemistry of the matrix isolated compound was investigated.

Elastic, magnetic and electronic properties of iridium phosphide Ir 2P

DOE PAGES

Wang, Pei; Wang, Yonggang; Wang, Liping; ...

2016-02-24

Cubic (space group: Fm3¯m) iridium phosphide, Ir 2P, has been synthesized at high pressure and high temperature. Angle-dispersive synchrotron X-ray diffraction measurements on Ir 2P powder using a diamond-anvil cell at room temperature and high pressures (up to 40.6 GPa) yielded a bulk modulus of B 0 = 306(6) GPa and its pressure derivative B 0'= 6.4(5). Such a high bulk modulus attributed to the short and strongly covalent Ir-P bonds as revealed by first – principles calculations and three-dimensionally distributed [IrP 4] tetrahedron network. Indentation testing on a well–sintered polycrystalline sample yielded the hardness of 11.8(4) GPa. Relatively lowmore » shear modulus of ~64 GPa from theoretical calculations suggests a complicated overall bonding in Ir 2P with metallic, ionic, and covalent characteristics. Additionally, a spin glass behavior is indicated by magnetic susceptibility measurements.« less

Magnetic and structural studies of trivalent Co-substituted Cd-Mn ferrites

NASA Astrophysics Data System (ADS)

Amer, M. A.; Meaz, T. M.; El-Kestawy, M.; Ghoneim, A. I.

2016-05-01

Series of polycrystalline Cd0.4Mn0.6CoxFe2-xO4 ferrites, 0≤x≤1, were prepared by solid state reaction method. The samples were characterized by inductive coupling plasma, X-ray diffraction, scanning electron microscopy, Fourier-transform infrared spectra and vibrating sample magnetometry. This study proved that all samples have single-phase cubic spinel structure. The true lattice constant, saturation magnetization, magnetic moment and trend of grain size and IR band νA showed decrease against x, whereas the trend of crystallite size, threshold frequency, Debye temperature, IR bands ν1 and ν2 and force constants F1 and F2, coercivity, anisotropy constant and residual magnetization showed increase. The IR analysis proved existence of Fe2+, Co2+, Fe4+, Co4+ and/or Mn4+ ions amongst the crystal sublattices. The characteristic bands ν1 and ν2 and force constants F1 and F2 showed decrease versus the tetrahedral- and octahedral-site bond length, respectively. The strain, specific surface area, refractive index, velocity, jump rate and remnant magnetization proved dependence on Co3+ ion content x.

Experimental and theoretical studies on IR, Raman, and UV-Vis spectra of quinoline-7-carboxaldehyde.

PubMed

Kumru, M; Küçük, V; Kocademir, M; Alfanda, H M; Altun, A; Sarı, L

2015-01-05

Spectroscopic properties of quinoline-7-carboxaldehyde (Q7C) have been studied in detail both experimentally and theoretically. The FT-IR (4000-50 cm(-1)), FT-Raman (4000-50 cm(-1)), dispersive-Raman (3500-50 cm(-1)), and UV-Vis (200-400 nm) spectra of Q7C were recorded at room temperature (25 °C). Geometry parameters, potential energy surface about CCH(O) bond, harmonic vibrational frequencies, IR and Raman intensities, UV-Vis spectrum, and thermodynamic characteristics (at 298.15K) of Q7C were computed at Hartree-Fock (HF) and density functional B3LYP levels employing the 6-311++G(d,p) basis set. Frontier molecular orbitals, molecular electrostatic potential, and Mulliken charge analyses of Q7C have also been performed. Q7C has two stable conformers that are energetically very close to each other with slight preference to the conformer that has oxygen atom of the aldehyde away from the nitrogen atom of the quinoline. Copyright © 2014 Elsevier B.V. All rights reserved.

Evaluation of HCMM satellite data for estuarine tidal circulation patterns and thermal inertia soil moisture measurements. [Delaware Bay, Cooper River, and the Potomac River estuaries; Luverne, Minnesota, soil moisture, and water temperature of Lake Anna, Virginia

NASA Technical Reports Server (NTRS)

Wiesnet, D. R.; Mcginnis, D. F., Jr. (Principal Investigator); Matson, M.; Pritchard, J. A.

1981-01-01

Digital thermal maps of the Cooper River (SC) and the Potomac River estuaries were prepared from heat capacity mapping radiometer (HCMR) tapes. Tidal phases were correctly interpreted and verified. Synoptic surface circulation patterns were charted by location thermal fronts and water mass boundaries within the estuaries. Thermal anomalies were detected adjacent of a conventional power plant on the Potomac. Under optimum conditions, estuaries as small as the Cooper River can be monitored for generalized thermal/tidal circulation patterns by the HCMM-type IR sensors. The HCMM thermal inertia approach to estimating soil moisture at the Luverne (MN) test site was found to be unsatisfactory as a NESS operational satellite technique because of cloud cover interference. Thermal-IR data show similar structure of the Baltimore and Washington heat islands when compared to NOAA AVHRR thermal-IR data. Thermal anomalies from the warm water discharge water of a nuclear power plant were mapped in Lake Anna, Virginia.

Satellite and Synoptic Studies of Chemical Fronts in the California Current and Coastal Upwelling Zone

DTIC Science & Technology

1987-05-31

phoosphor- ou%. The shoru~iard sigde i-. cold. %clI mixed. and relanttocl rich in theseu elcmcno (7 if 1. 19NI). 19,S)). The nutrient-rich Aater which io...Union, 62(36), 1981, September 8. Master’s Theses Nestor, D.A., M.S. Thesis , A Study of the Relationship Between Oceanic Chemical Mesoscale and Sea...Surface Temperature as Detected by Satellite IR Imagery; Naval Postgraduate School, Monterey, California, 1979. Conrad, J.C., M.S. Thesis , Relationship

An efficient routine for infrared radiative transfer in a cloudy atmosphere

NASA Technical Reports Server (NTRS)

Chou, M. D.; Kouvaris, L.

1981-01-01

A FORTRAN program that calculates the atmospheric cooling rate and infrared fluxes for partly cloudy atmospheres is documented. The IR fluxes in the water bands and the 9.6 and 15 micron bands are calculated at 15 levels ranging from 1.39 mb to the surface. The program is generalized to accept any arbitrary atmospheric temperature and humidity profiles and clouds as input and return the cooling rate and fluxes as output. Sample calculations for various atmospheric profiles and cloud situations are demonstrated.

Application of Pyrometry and IR-Thermography to High Surface Temperature Measurements

DTIC Science & Technology

2000-04-01

infrared spectra. Pneumatic thermal detectors use the effect of pres- sure change in a gas chamber due to radiation The second group of quantum detectors ...application of photo conductive detectors is re- a good signal to noise ratio. Each detector has a stricted by the recombination noise due to the elec...tricity. The signal power equal to the noise power of the detector is called the noise equivalent power AE tAE (NEP). It strongly depends on the

Remote sensing of the atmosphere of Mars using infrared pressure modulation and filter radiometry

NASA Technical Reports Server (NTRS)

Mccleese, D. J.; Schofield, J. T.; Zurek, R. W.; Martonchik, J. V.; Haskins, R. D.

1986-01-01

The study of the atmosphere and climate of Mars will soon be advanced considerably by the Mars Observer mission. This paper describes the atmospheric sounder for this mission and how it will measure key Martian atmospheric parameters using IR gas correlation and filter radiometry. The instrument now under development will provide high-resolution vertical profiles of atmospheric temperature, pressure, water vapor, dust, and clouds using limb sounding techniques as well as nadir observations of surface thermal properties and polar radiative balance.

A New Remote-Sensing Method for Mine Detection using HPM Irradiation and IR Detection.

DTIC Science & Technology

1999-12-01

absorption of microwave energy by the mine. This signature appears at the soil surface after a brief time-delay from the start of HPM illumination. At...detection de cible, l’operation de teledetection, la capacite de detecter des cibles sous un ciel couvert avec peu de dependance du cycle solaire et la...the temperature of the sample depends on the microwave energy absorbed by the sample and varies inversely with the sample thermal heat capacity. The

Classifying Infrastructure in an Urban Battlespace Using Thermal IR Signatures

DTIC Science & Technology

2006-11-01

Huntsville, Alabama for sharing their ATLAS data for Atlanta. REFERENCES Bentz , D . P . (2000). A Computer Model to Predict the Surface Temperature...10: 2 2 xt α Δ Δ ≤ (10) 2.2 Implementing the Model Bentz uses a 1- D finite difference grid with a varying number of nodes. The nodes are equally...and rooftops were modeled as a function of time and environmental conditions using 1- D heat transfer theory. The model was implemented in MATLAB

First Principles Calculations of Transition Metal Binary Alloys: Phase Stability and Surface Effects

NASA Astrophysics Data System (ADS)

Aspera, Susan Meñez; Arevalo, Ryan Lacdao; Shimizu, Koji; Kishida, Ryo; Kojima, Kazuki; Linh, Nguyen Hoang; Nakanishi, Hiroshi; Kasai, Hideaki

2017-06-01

The phase stability and surface effects on binary transition metal nano-alloy systems were investigated using density functional theory-based first principles calculations. In this study, we evaluated the cohesive and alloying energies of six binary metal alloy bulk systems that sample each type of alloys according to miscibility, i.e., Au-Ag and Pd-Ag for the solid solution-type alloys (SS), Pd-Ir and Pd-Rh for the high-temperature solid solution-type alloys (HTSS), and Au-Ir and Ag-Rh for the phase-separation (PS)-type alloys. Our results and analysis show consistency with experimental observations on the type of materials in the bulk phase. Varying the lattice parameter was also shown to have an effect on the stability of the bulk mixed alloy system. It was observed, particularly for the PS- and HTSS-type materials, that mixing gains energy from the increasing lattice constant. We furthermore evaluated the surface effects, which is an important factor to consider for nanoparticle-sized alloys, through analysis of the (001) and (111) surface facets. We found that the stability of the surface depends on the optimization of atomic positions and segregation of atoms near/at the surface, particularly for the HTSS and the PS types of metal alloys. Furthermore, the increase in energy for mixing atoms at the interface of the atomic boundaries of PS- and HTSS-type materials is low enough to overcome by the gain in energy through entropy. These, therefore, are the main proponents for the possibility of mixing alloys near the surface.

Study on the cloud detection of GOCI by using the simulated surface reflectance from BRDF-model for the land application and meteorological utilization

NASA Astrophysics Data System (ADS)

Kim, Hye-Won; Yeom, Jong-Min; Woo, Sun-Hee; Chae, Tae-Byeong

2016-04-01

COMS (Communication, Ocean, and Meteorological Satellite) was launched at French Guiana Kourou space center on 27 June 2010. Geostationary Ocean Color Imager (GOCI), which is the first ocean color geostationary satellite in the world for observing the ocean phenomena, is able to obtain the scientific data per an hour from 00UTC to 07UTC. Moreover, the spectral channels of GOCI would enable not only monitoring for the ocean, but for extracting the information of the land surface over the Korean Peninsula, Japan, and Eastern China. Since it is extremely important to utilize GOCI data accurately for the land application, cloud pixels over the surface have to be removed. Unfortunately, infra-red (IR) channels that can easily detect the water vapor with the cloud top temperature, are not included in the GOCI sensor. In this paper, the advanced cloud masking algorithm will be proposed with visible and near-IR (NIR) bands that are within GOCI bands. The main obstacle of cloud masking with GOCI is how to handle the high variable surface reflectance, which is mainly depending on the solar zenith angle. In this study, we use semi-empirical BRDF model to simulate the surface reflectance by using 16 day composite cloudy free image. When estimating the simulated surface reflectance, same geometry for GOCI observation was applied. The simulated surface reflectance is used to discriminate cloud areas especially for the thin cloud and shows more reasonable result than original threshold methods.

Infrared Imaging for Inquiry-Based Learning

ERIC Educational Resources Information Center

Xie, Charles; Hazzard, Edmund

2011-01-01

Based on detecting long-wavelength infrared (IR) radiation emitted by the subject, IR imaging shows temperature distribution instantaneously and heat flow dynamically. As a picture is worth a thousand words, an IR camera has great potential in teaching heat transfer, which is otherwise invisible. The idea of using IR imaging in teaching was first…

NOAA AVHRR Land Surface Albedo Algorithm Development

NASA Technical Reports Server (NTRS)

Toll, D. L.; Shirey, D.; Kimes, D. S.

1997-01-01

The primary objective of this research is to develop a surface albedo model for the National Oceanic and Atmospheric Administration (NOAA) Advanced Very High Resolution Radiometer (AVHRR). The primary test site is the Konza prairie, Kansas (U.S.A.), used by the International Satellite Land Surface Climatology Project (ISLSCP) in the First ISLSCP Field Experiment (FIFE). In this research, high spectral resolution field spectrometer data was analyzed to simulate AVHRR wavebands and to derive surface albedos. Development of a surface albedo algorithm was completed by analysing a combination of satellite, field spectrometer, and ancillary data. Estimated albedos from the field spectrometer data were compared to reference albedos derived using pyranometer data. Variations from surface anisotropy of reflected solar radiation were found to be the most significant albedo-related error. Additional error or sensitivity came from estimation of a shortwave mid-IR reflectance (1.3-4.0 micro-m) using the AVHRR red and near-IR bands. Errors caused by the use of AVHRR spectral reflectance to estimate both a total visible (0.4-0.7 micro-m) and near-IR (0.7-1.3 micro-m) reflectance were small. The solar spectral integration, using the derived ultraviolet, visible, near-IR and SW mid-IR reflectivities, was not sensitive to many clear-sky changes in atmospheric properties and illumination conditions.

On the structural and electronic properties of Ir-silicide nanowires on Si(001) surface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fatima,; Hossain, Sehtab; Mohottige, Rasika

Iridium (Ir) modified Silicon (Si) (001) surface is studied with Scanning Tunneling Microscopy/Spectroscopy (STM/STS) and Density Functional Theory (DFT). A model for Ir-silicide nanowires based on STM images and ab-initio calculations is proposed. According to our model, the Ir adatom is on the top of the substrate dimer row and directly binds to the dimer atoms. I-V curves measured at 77 K shows that the nanowires are metallic. DFT calculations confirm strong metallic nature of the nanowires.

Mice receiving infrared irradiation have a higher survival rate under forced swimming in cold.

PubMed

Tsai, Jui-Feng

2009-10-01

To explore the effect of infrared (IR) irradiation on the survival rates of mice under forced swimming in cold conditions. IR irradiation has been found to be beneficial for wound healing, tumor reduction, pain relief, and even against depression. However, whether the antidepressant effect of IR irradiation came from heat has remained unanswered. The goals of the study were originally aimed at using an animal model for depression to understand the relationship between the antidepressant effect of IR irradiation and hyperthermia as well as seasonality. Forty-four mice were housed in cages in a room subject to the outdoor temperature, and randomly assigned to the IR-treated group (n = 15), the heat-treated group (n = 14), and the control group (n = 15) during winter. The mice of the IR-treated group received whole-body IR irradiation for 60 min daily, while the heat-treated group received heat diffusion to reach the same temperature level. The control group received neither IR nor heat. All groups of mice underwent a forced swimming test weekly. Incidentally, two episodes of cold current occurred during the study period, and some mice died. The survival rates were compared pairwise against the control. The IR-treated group had a significantly reduced relative risk (p = 0.013) when compared with the control group, while the heat-treated group did not show any significant reduction (p = 0.087). There was no significant difference in body temperatures of the three groups before and after the irradiation. IR irradiation resulted in a significantly higher survival rate for mice that were concurrently subjected to cold and a forced swimming test. This result may be beyond the thermal effect.

Boosting water oxidation layer-by-layer.

PubMed

Hidalgo-Acosta, Jonnathan C; Scanlon, Micheál D; Méndez, Manuel A; Amstutz, Véronique; Vrubel, Heron; Opallo, Marcin; Girault, Hubert H

2016-04-07

Electrocatalysis of water oxidation was achieved using fluorinated tin oxide (FTO) electrodes modified with layer-by-layer deposited films consisting of bilayers of negatively charged citrate-stabilized IrO2 NPs and positively charged poly(diallyldimethylammonium chloride) (PDDA) polymer. The IrO2 NP surface coverage can be fine-tuned by controlling the number of bilayers. The IrO2 NP films were amorphous, with the NPs therein being well-dispersed and retaining their as-synthesized shape and sizes. UV/vis spectroscopic and spectro-electrochemical studies confirmed that the total surface coverage and electrochemically addressable surface coverage of IrO2 NPs increased linearly with the number of bilayers up to 10 bilayers. The voltammetry of the modified electrode was that of hydrous iridium oxide films (HIROFs) with an observed super-Nernstian pH response of the Ir(III)/Ir(IV) and Ir(IV)-Ir(IV)/Ir(IV)-Ir(V) redox transitions and Nernstian shift of the oxygen evolution onset potential. The overpotential of the oxygen evolution reaction (OER) was essentially pH independent, varying only from 0.22 V to 0.28 V (at a current density of 0.1 mA cm(-2)), moving from acidic to alkaline conditions. Bulk electrolysis experiments revealed that the IrO2/PDDA films were stable and adherent under acidic and neutral conditions but degraded in alkaline solutions. Oxygen was evolved with Faradaic efficiencies approaching 100% under acidic (pH 1) and neutral (pH 7) conditions, and 88% in alkaline solutions (pH 13). This layer-by-layer approach forms the basis of future large-scale OER electrode development using ink-jet printing technology.

Crystal structure, Hirshfeld surfaces computational study and physicochemical characterization of the hybrid material (C7H10N)2[SnCl6]·H2O

NASA Astrophysics Data System (ADS)

BelhajSalah, S.; Abdelbaky, Mohammed S. M.; García-Granda, Santiago; Essalah, K.; Ben Nasr, C.; Mrad, M. L.

2018-01-01

A novel hybrid compound, bis(4-methylanilinium)hexachlorostannate(IV) monohydrate, formulated as (C7H10N)2[SnCl6]·H2O, has been prepared and characterized by powder and single crystal X-ray diffraction (XRD), Hirshfeld surface analysis, infrared spectroscopy (IR), optical study, differential thermal analysis(DTA) and X-ray photoelectron spectroscopy analysis (XPS). The title compound crystallizes in the monoclinic space group P21/c with a = 13.093(1)Å, b = 7.093(6)Å, c = 24.152(2)Å, β = 98.536(4)⁰ and V = 2218.4(4) Å3. Their crystal structure exhibits alternating inorganic layers parallel to the (ab) plane at z = n/2. The different entities, [SnCl6]2-, organic cations and water molecules, are connected via hydrogen bonds to form a three-dimensional network. The powder XRD data confirms the phase purity of the crystalline sample. The intermolecular interactions were investigated by Hirshfeld surfaces. The vibrational absorption bands were identified by IR spectroscopy and have been discussed. The optical properties of the crystal were studied by using optical absorption, UV-visible absorption and photoluminescence spectroscopy studies. The compound was also characterized by DTA to determine its thermal behavior with respect to the temperature. Finally, XPS technique is reported for analyzing the surface chemistry of this compound.

Assimilation for skin SST in the NASA GEOS atmospheric data assimilation system

PubMed Central

Akella, Santha; Todling, Ricardo; Suarez, Max

2018-01-01

The present article describes the sea surface temperature (SST) developments implemented in the Goddard Earth Observing System, Version 5 (GEOS-5) Atmospheric Data Assimilation System (ADAS). These are enhancements that contribute to the development of an atmosphere-ocean coupled data assimilation system using GEOS. In the current quasi-operational GEOS-ADAS, the SST is a boundary condition prescribed based on the OSTIA product, therefore SST and skin SST (Ts) are identical. This work modifies the GEOS-ADAS Ts by modeling and assimilating near sea surface sensitive satellite infrared (IR) observations. The atmosphere-ocean interface layer of the GEOS atmospheric general circulation model (AGCM) is updated to include near surface diurnal warming and cool-skin effects. The GEOS analysis system is also updated to directly assimilate SST-relevant Advanced Very High Resolution Radiometer (AVHRR) radiance observations. Data assimilation experiments designed to evaluate the Ts modification in GEOS-ADAS show improvements in the assimilation of radiance observations that extends beyond the thermal IR bands of AVHRR. In particular, many channels of hyperspectral sensors, such as those of the Atmospheric Infrared Sounder (AIRS), and Infrared Atmospheric Sounding Interferometer (IASI) are also better assimilated. We also obtained improved fit to withheld, in-situ buoy measurement of near-surface SST. Evaluation of forecast skill scores show marginal to neutral benefit from the modified Ts. PMID:29628531

Intravenous fluid temperature management by infrared thermometer.

PubMed

Lapostolle, Frédéric; Catineau, Jean; Le Toumelin, Philippe; Proust, Clément; Garrigue, Bruno; Galinski, Michel; Adnet, Frédéric

2006-03-01

The management of intravenous (IV) fluid temperature is a daily challenge in critical care, anesthesiology, and emergency medicine. Infusion of IV fluids at the right temperature partly influences clinical outcomes of critically ill patients. Nowadays, intravenous fluid temperature is poorly managed, as no suitable device is routinely available. Infrared (IR) thermometers have been recently developed for industrial, personal, or medical purposes. The aim of this study was to evaluate the accuracy of an IR thermometer in measuring temperature of warmed and cooled infusion fluids in fluid bags. This study compared temperatures simultaneously recorded by an infrared thermometer and a temperature sensor. Temperatures of warmed (41 degrees C) and cooled (4 degrees C) infusion fluids in fluid bags were recorded by 2 independent operators every minute until IV bags' temperature reached ambient temperature. The relation curve was established with 576 measures. Temperature measures performed with an IR thermometer were perfectly linear and perfectly correlated with the reference method (R(2) = 0.995, P < 10(-5)). Infrared thermometers are efficient to measure IV fluid bag temperature in the range of temperatures used in clinical practice. As these devices are easy to use and inexpensive, they could be largely used in critical care, anesthesiology, or emergency medicine.

Resilience of rice (Oryza spp.) pollen germination and tube growth to temperature stress.

PubMed

Coast, Onoriode; Murdoch, Alistair J; Ellis, Richard H; Hay, Fiona R; Jagadish, Krishna S V

2016-01-01

Resilience of rice cropping systems to potential global climate change will partly depend on the temperature tolerance of pollen germination (PG) and tube growth (PTG). Pollen germination of high temperature-susceptible Oryza glaberrima Steud. (cv. CG14) and Oryza sativa L. ssp. indica (cv. IR64) and high temperature-tolerant O. sativa ssp. aus (cv. N22), was assessed on a 5.6-45.4 °C temperature gradient system. Mean maximum PG was 85% at 27 °C with 1488 μm PTG at 25 °C. The hypothesis that in each pollen grain, the minimum temperature requirements (Tn ) and maximum temperature limits (Tx ) for germination operate independently was accepted by comparing multiplicative and subtractive probability models. The maximum temperature limit for PG in 50% of grains (Tx(50) ) was the lowest (29.8 °C) in IR64 compared with CG14 (34.3 °C) and N22 (35.6 °C). Standard deviation (sx ) of Tx was also low in IR64 (2.3 °C) suggesting that the mechanism of IR64's susceptibility to high temperatures may relate to PG. Optimum germination temperatures and thermal times for 1 mm PTG were not linked to tolerating high temperatures at anthesis. However, the parameters Tx(50) and sx in the germination model define new pragmatic criteria for successful and resilient PG, preferable to the more traditional cardinal (maximum and minimum) temperatures. © 2014 John Wiley & Sons Ltd.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Dong; Xu, Pinghong; Guan, Erjia

Supported rhodium acetate dimers were prepared by the reaction of Rh2(OAc)4 (OAc is acetate) with highly dehydroxylated MgO powder and characterized by extended X-ray absorption fine structure and infrared (IR) spectra, which show that the supported species were well represented as Rh2(OAc)3, with each Rh atom on average bonded to one oxygen atom of the MgO surface. Aberration-corrected scanning transmission electron microscopy gave images of Rh atoms in pairs on the MgO. The supported rhodium dimers were probed with a pulse of CO, and the IR spectra indicate a Rh(II) species with weakly bonded carbonyl ligands; the sharpness of themore » νCO band indicates highly uniform surface species. Further treatment in CO led to breakup of the rhodium dimers into mononuclear species; such fragmentation took place in other treatment gases as well, with the degree of fragmentation decreasing in the order CO > C2H4 > helium. The fragmentation is inferred on the basis of IR spectra to have proceeded through intermediate Rh2 species without acetate ligands. In contrast, rhodium dimers were reduced and not fragmented in the presence of H2 at 353 K, but at higher temperatures the rhodium aggregated to give larger clusters. The supported species catalyzed ethylene hydrogenation at 298 K and 1 bar at a H2 to ethylene molar ratio of 4; after 27 h of catalysis in a once-through flow reactor, acetate ligands were removed from the dimers, and some of them fragmented, as shown by IR spectroscopy. The intermediate dirhodium species without acetate ligands are two or three orders of magnitude more active as catalysts than the supported mononuclear rhodium species or those present predominantly as Rh2(OAc)3, respectively.« less

Time-Resolved Imaging of the Phase Transition in the Melt-Grown Spherulites of Isotactic Polybutene-1 as Detected by the Two-Dimensional Polarized IR Imaging Technique.

PubMed

Hu, Jian; Tashiro, Kohji

2016-05-26

In order to visualize the 2D spatial distribution of the structural change in the phase transition from crystal form II to I of isotactic polybutene-1 spherulite grown from the melt, the time-dependent measurement of the 2D polarized FTIR spectra has been performed. At a melt-isothermal crystallization temperature of 103 °C, the square-shape spherulite appeared from the melt and grew with time. When the isothermal crystallization occurred at 98 °C, the round-shaped spherulite was observed. In both cases, after the temperature jump to an ambient temperature, the 2D images changed clearly in the process of the phase transition from form II to form I, but the spherulite morphology itself was not changed detectably. The polarized IR imaging has revealed the preferential orientation of the crystallites in the spherulite. In the case of the spherulite grown at 103 °C, the ab plane is oriented in parallel to the spherulite plane and the molecular chains stand along the normal to the surface. On the other hand, in the spherulite grown at 98 °C, the chains were found to lie on the spherulite plane preferentially. Such a difference in the crystal orientation in the spherulite is related intimately with the outer shape of the spherulite and also with the growth mechanism of the spherulite. In this way, the polarized 2D IR imaging was found to be quite useful for the in situ detection of the time-dependently changing 2D spatial distribution of the crystallites in the spherulite.

Screening for dry eye disease using infrared ocular thermography.

PubMed

Tan, Li Li; Sanjay, Srinivasan; Morgan, Philip B

2016-12-01

To evaluate the efficacy of infrared (IR) ocular thermography in screening for dry eye disease (DED). IR ocular thermography was performed on 62 dry eye and 63 age- and sex-matched control subjects. Marking of ocular surface and temperature acquisition was done using a novel 'diamond' demarcation method. 30 static- and 30 dynamic-metrics were studied and receiver operating characteristic curves were plotted. Efficacy of the temperature metrics in detecting DED were evaluated singly and in combination in terms of their area under the curve (AUC), Youden's index and discrimination power (DP). Absolute temperature of the extreme nasal conjunctiva 5s and 10s after eye opening were best detectors for DED. With threshold value for the first metric set at 34.7°C, sensitivity and specificity was 87.1% (95% CI: 76.2-94.3%) and 50.8% (95% CI: 37.9-63.6%) respectively. With threshold value for the second metric set at 34.5°C, sensitivity and specificity was 77.6% (95% CI: 64.7-87.5%) and 61.9% (95% CI: 48.8-73.9%) respectively. The two metrics had moderate accuracy and limited performances with AUC of 72% (95% CI: 63-81%) and 73% (95% CI: 64-82%); Youden index of about 0.4 and DP of 1.07 and 1.05 respectively. None of the dynamic metrics was good detector for DED. Combining metrics was not able to increase the AUC. This work suggests some utility for the application of IR ocular thermography for evaluation of dry eye patients. Copyright © 2016 British Contact Lens Association. Published by Elsevier Ltd. All rights reserved.

In situ DRIFTS study of O3 adsorption on CaO, γ-Al2O3, CuO, α-Fe2O3 and ZnO at room temperature for the catalytic ozonation of cinnamaldehyde

NASA Astrophysics Data System (ADS)

Wu, Jianfeng; Su, Tongming; Jiang, Yuexiu; Xie, Xinling; Qin, Zuzeng; Ji, Hongbing

2017-08-01

In situ DRIFTS were conducted to identify adsorbed ozone and/or adsorbed oxygen species on CaO, ZnO, γ-Al2O3, CuO and α-Fe2O3 surfaces at room temperature. Samples were characterized by means of TG, XRD, N2 adsorption-desorption, pyridine-IR, nitrobenzene-IR, chloroform-IR, and CO2-TPD. Pyridine-DRIFTS measurements evidence two kinds of acid sites in all the samples. Nitrobenzene, chloroform-DRIFTS, and CO2-TPD reveal that there are large amounts of medium-strength base sites on all the metal oxides, and only CaO, ZnO, and γ-Al2O3 have strong base sites. And the benzaldehyde selectivity was increased in the same order of the alkalinity of the metal oxides. With weaker sites, ozone molecules form coordinative complexes bound via the terminal oxygen atom, observed by vibrational frequencies at 2095-2122 and 1026-1054 cm-1. The formation of ozonide O3- at 790 cm-1, atomic oxygen at 1317 cm-1, and superoxide O2- at 1124 cm-1 was detected; these species are believed to be intermediates of O3 decomposition on strong acid/base sites. The adsorption of ozone on metal oxides is a weak adsorption, and other gases, such as CO2, will compete with O3 adsorption. The mechanism of cinnamaldehyde ozonation at room temperature over CaO shows that cinnamaldehyde can not only be oxidized into cinnamic acid, but also be further oxidized into benzaldehyde, benzoic acid, maleic anhydride, and ultimately mineralized to CO2 in the presence of O3.

Satellite IR Thermal Measurements Prior to the September 2004 Earthquakes in Central California

NASA Technical Reports Server (NTRS)

Ouzounov, D.; Logan, T.; Taylor, Patrick

2004-01-01

We present and discuss observed variations in thermal transients and radiation fields prior to the earthquakes of September 18 near Bodie (M5.5) and September 28,2004 near Parkfield(M6.0) in California. Previous analysis of earthquake events have indicated the presence of a thermal anomaly, where temperatures increased or did not return to its usual nighttime value. The procedures used in our work is to analyze weather satellite data taken at night and to record the general condition where the ground cools after sunset. Two days before the Bodie earthquake lower temperature radiation was observed by the NOAA/AVHRR satellite. This occurred when the entire region was relatively cloud-free. IR land surface nighttime temperature from the MODIS instrument rose to +4 C in a 100 km radius around the Bodie epicenter. The thermal transient field recorded by MODIS in the vicinity of Parkfield, also with a cloud free environment, was around +l C and it is significantly smaller than the Parkfield epicenter, however, for that period showed a steady increase 4 days prior to the earthquake and a significant drop of the night before the quake. Geosynchronous weather satellite thermal IR measurements taken every half hour from sunset to dawn, were also recorded for 10 days prior to the Parkfield event and 5 days after as well as the day of the quake. To establish a baseline we also obtained GOES data for the same Julian sets were then used to systematically observe and record any thermal anomaly prior to the events that deviated from the baseline. Our recent results support the hypothesis of a possible relationship between an thermodynamic processes produced by increasing tectonic stress in the Earth's crust and a subsequent electro-chemical interaction between this crust and the atmosphere/ionosphere.

SU-F-T-28: Evaluation of BEBIG HDR Co-60 After-Loading System for Skin Cancer Treatment Using Conical Surface Applicator

DOE Office of Scientific and Technical Information (OSTI.GOV)

Safigholi, H; Soliman, A; Song, W Y

Purpose: To evaluate the possibility of utilizing the BEBIG HDR 60Co remote after-loading system for malignant skin surface treatment using Monte Carlo (MC) simulation technique. Methods: First TG-43 parameters of BEBIG-Co-60 and Nucletron Ir-192-mHDR-V2 brachytherapy sources were simulated using MCNP6 code to benchmark the sources against the literature. Second a conical tungsten-alloy with 3-cm diameter of Planning-Target-Volume (PTV) at surface for use with a single stepping HDR source is designed. The HDR source is modeled parallel to treatment plane at the center of the conical applicator with a source surface distance (SSD) of 1.5-cm and a removable plastic end-cap withmore » a 1-mm thickness. Third, MC calculated dose distributions from HDR Co-60 for conical surface applicator were compared with the simulated data using HDR Ir-192 source. The initial calculations were made with the same conical surface applicator (standard-applicator) dimensions as the ones used with the Ir-192 system. Fourth, the applicator wall-thickness for the Co-60 system was increased (doubled) to diminish leakage dose to levels received when using the Ir-192 system. With this geometry, percentage depth dose (PDD), and relative 2D-dose profiles in transverse/coronal planes were normalized at 3-mm prescription-depth evaluated along the central axis. Results: PDD for Ir-192 and Co-60 were similar with standard and thick-walled applicator. 2D-relative dose distribution of Co-60, inside the standard-conical-applicator, generated higher penumbra (7.6%). For thick-walled applicator, it created smaller penumbra (<4%) compared to Ir-192 source in the standard-conicalapplicator. Dose leakage outside of thick-walled applicator with Co-60 source was approximately equal (≤3%) with standard applicator using Ir-192 source. Conclusion: Skin cancer treatment with equal quality can be performed with Co-60 source and thick-walled conical applicators instead of Ir-192 with standard applicators. These conical surface applicator must be used with a protective plastic end-cap to eliminate electron contamination and over-dosage of the skin.« less

Oxygen atom transfer reactions of iridium and osmium complexes: theoretical study of characteristic features and significantly large differences between these two complexes.

PubMed

Ishikawa, Atsushi; Nakao, Yoshihide; Sato, Hirofumi; Sakaki, Shigeyoshi

2009-09-07

Oxygen atom transfer reaction between ML(3)=O and ML(3) (L = 2,4,6-trimethylphenyl (Mes) for M = Ir and L = 2,6-diisopropylphenylimide (NAr) for M = Os) was theoretically investigated by DFT method. The optimized geometry of (Mes)(3)Ir-O-Ir(Mes)(3) agrees well with the experimental one, although those of (CH(3))(3)Ir-O-Ir(CH(3))(3) and Ph(3)Ir-O-IrPh(3) are much different from the experimental one of the Mes complex. These results indicate that the bulky ligand plays important roles to determine geometry of the mu-oxo dinuclear Ir complex. Theoretical study of the real systems presents clear pictures of these oxygen atom transfer reactions, as follows: In the Ir reaction system, (i) the mu-oxo bridged dinuclear complex is more stable than the infinite separation system in potential energy surface, indicating this is incomplete oxygen atom transfer reaction which does not occur at very low temperature, (ii) unsymmetrical transition state is newly found, in which one Ir-O distance is longer than the other one, (iii) unsymmetrical local minimum is also newly found between the transition state and the infinite separation system, and (iv) activation barrier (E(a)) is very small. In the Os reaction system, (v) the transition state is symmetrical, while no intermediate is observed unlike the Ir reaction system, and (vi) E(a) is very large. These results are consistent with the experimental results that the reaction rapidly occurs in the Ir system but very slowly in the Os system, and that the mu-oxo bridged dinuclear intermediate is detected in the Ir system but not in the Os system. To elucidate the reasons of these differences between Ir and Os systems, the E(a) value is decomposed into the nuclear and electronic factors. The former is the energy necessary to distort ML(3) and ML(3)=O moieties from their equilibrium geometries to those in the transition state. The latter depends on donor-acceptor interaction between ML(3)=O and ML(3). The nuclear factor is much larger in the Os system than in the Ir system and it contributes to about 70% of the difference in E(a). The energy gap between the donor orbital of ML(3) and the acceptor orbital of ML(3)=O is much larger in the Os system than in the Ir system, which also contributes to the lower E(a) value of the Ir system than that of the Os system.

Gas chromatography/matrix-isolation apparatus

DOEpatents

Reedy, G.T.

1986-06-10

A gas-sample collection device provides matrix isolation of individual gas bands from a gas chromatographic separation and for the spectroscopic analysis of the individual sample bands. The device includes a vacuum chamber containing a rotatably supported, specular carousel having at least one reflecting surface for holding a sample deposited thereon. A gas inlet is provided for depositing a mixture of sample and matrix material on the reflecting surface which is maintained at a sufficiently low temperature to cause solidification. A first parabolic mirror directs an incident beam of electromagnetic radiation, such as in the infrared (IR) spectrum, from a source onto the sample/matrix mixture while a second parabolic mirror directs a second beam of electromagnetic radiation reflected by the specular surface to an IR spectrometer for determining the absorption spectra of the sample material deposited on the reflecting surface. The pair of off-axis parabolic mirrors having a common focal point are positioned outside of the vacuum chamber and may be displaced in combination for improved beam positioning and alignment. The carousel is provided with an aperture for each reflecting surface to facilitate accurate positioning of the incident beam relative to the gas-samples under analysis. Improved gas-sample deposition is insured by the use of a long focal length stereomicroscope positioned outside of the vacuum chamber for monitoring sample formation through a window, while the sample collector is positioned outside of the zone bounded by the incident and reflected electromagnetic beams for improved sample access and monitoring. 10 figs.

Gas chromatography/matrix-isolation apparatus

DOEpatents

Reedy, Gerald T.

1986-01-01

A gas-sample collection device provides matrix isolation of individual gas bands from a gas chromatographic separation and for the spectroscopic analysis of the individual sample bands. The device includes a vacuum chamber containing a rotatably supported, specular carousel having at least one reflecting surface for holding a sample deposited thereon. A gas inlet is provided for depositing a mixture of sample and matrix material on the reflecting surface which is maintained at a sufficiently low temperature to cause solidification. A first parabolic mirror directs an incident beam of electromagnetic radiation, such as in the infrared (IR) spectrum, from a source onto the sample/matrix mixture while a second parabolic mirror directs a second beam of electromagnetic radiation reflected by the specular surface to an IR spectrometer for determining the absorption spectra of the sample material deposited on the reflecting surface. The pair of off-axis parabolic mirrors having a common focal point are positioned outside of the vacuum chamber and may be displaced in combination for improved beam positioning and alignment. The carousel is provided with an aperture for each reflecting surface to facilitate accurate positioning of the incident beam relative to the gas-samples under analysis. Improved gas-sample deposition is insured by the use of a long focal length stereomicroscope positioned outside of the vacuum chamber for monitoring sample formation through a window, while the sample collector is positioned outside of the zone bounded by the incident and reflected electromagnetic beams for improved sample access and monitoring.

CO2 to methanol conversion using hydride terminated porous silicon nanoparticles.

PubMed

Dasog, M; Kraus, S; Sinelnikov, R; Veinot, J G C; Rieger, B

2017-03-09

Porous silicon nanoparticles (Si-NPs) prepared via magnesiothermic reduction were used to convert carbon dioxide (CO 2 ) into methanol. The hydride surface of the silicon nanoparticles acted as a CO 2 reducing reagent without any catalyst at temperatures above 100 °C. The Si nanoparticles were reused up to four times without significant loss in methanol yields. The reduction process was monitored using in situ FT-IR and the materials were characterized using SEM, TEM, NMR, XPS, and powder XRD techniques. The influence of reaction temperature, pressure, and Si-NP concentration on CO 2 reduction were also investigated. Finally, Si particles produced directly from sand were used to convert CO 2 to methanol.

Thermal design and verification of an instrument cooling system for infrared detectors utilizing the Oxford Stirling cycle refrigerator

NASA Technical Reports Server (NTRS)

Werrett, Stephen; Seivold, Alfred L.

1990-01-01

A detailed nodal computer model was developed to thermally represent the hardware, and sensitivity studies were performed to evaluate design parameters and orbital environmental effects of an instrument cooling system for IR detectors. Thermal-vacuum testing showed excellent performance of the system and a correspondence with math model predictions to within 3 K. Results show cold stage temperature sensitivity to cold patch backload, outer stage external surface emittance degradation, and cold stage emittance degradation, respectively. The increase in backload on the cold patch over the mission lifetime is anticipated to be less than 3.0 watts, which translates to less than a 3-degree increase in detector temperatures.

Size and Site Dependence of the Catalytic Activity of Iridium Clusters toward Ethane Dehydrogenation.

PubMed

Ge, Yingbin; Jiang, Hao; Kato, Russell; Gummagatta, Prasuna

2016-12-01

This research focuses on optimizing transition metal nanocatalyst immobilization and activity to enhance ethane dehydrogenation. Ethane dehydrogenation, catalyzed by thermally stable Ir n (n = 8, 12, 18) atomic clusters that exhibit a cuboid structure, was studied using the B3LYP method with triple-ζ basis sets. Relativistic effects and dispersion corrections were included in the calculations. In the dehydrogenation reaction Ir n + C 2 H 6 → H-Ir n -C 2 H 5 → (H) 2 -Ir n -C 2 H 4 , the first H-elimination is the rate-limiting step, primarily because the reaction releases sufficient heat to facilitate the second H-elimination. The catalytic activity of the Ir clusters strongly depends on the Ir cluster size and the specific catalytic site. Cubic Ir 8 is the least reactive toward H-elimination in ethane: Ir 8 + C 2 H 6 → H-Ir 8 -C 2 H 5 has a large (65 kJ/mol) energy barrier, whereas Ir 12 (3 × 2 × 2 cuboid) and Ir 18 (3 × 3 × 2 cuboid) lower this energy barrier to 22 and 3 kJ/mol, respectively. The site dependence is as prominent as the size effect. For example, the energy barrier for the Ir 18 + C 2 H 6 → H-Ir 18 -C 2 H 5 reaction is 3, 48, and 71 kJ/mol at the corner, edge, or face-center sites of the Ir 18 cuboid, respectively. Energy release due to Ir cluster insertion into an ethane C-H bond facilitates hydrogen migration on the Ir cluster surface, and the second H-elimination of ethane. In an oxygen-rich environment, oxygen molecules may be absorbed on the Ir cluster surface. The oxygen atoms bonded to the Ir cluster surface may slightly increase the energy barrier for H-elimination in ethane. However, the adsorption of oxygen and its reaction with H atoms on the Ir cluster releases sufficient heat to yield an overall thermodynamically favored reaction: Ir n + C 2 H 6 + 1 / 2 O 2 → Ir n + C 2 H 4 + H 2 O. These results will be useful toward reducing the energy cost of ethane dehydrogenation in industry.

Detection of creatinine enriched on a surface imprinted polystyrene film using FT-ATR-IR.

PubMed

Sreenivasan, K

2006-01-01

The surface of polystyrene (PS) was chemically modified by coating a thin layer of polyaniline (PANI) by oxidizing aniline using ammonium persulfate. Affinity sites for creatinine, a clinically relevant molecule, were created in the coated layer by adding creatinine as print molecules during the oxidation. The imprinted layer adsorbed creatinine was compared to non-imprinted surface reflecting the creation of creatinine-specific sites on the surface. The equilibrium was attained rapidly, indicating that a material of this kind is suitable for sensing applications. The adsorbed creatinine on the surface was detected using the technique of Fourier transform attenuated total internal reflection infra red spectroscopy (FT-ATR-IR). The results show that molecularly imprinted surface can enrich molecules of interest and the enriched molecules can be detected using FT-IR.

Combined IR-Raman vs vibrational sum-frequency heterospectral correlation spectroscopy

NASA Astrophysics Data System (ADS)

Roy, Sandra; Beutier, Clémentine; Hore, Dennis K.

2018-06-01

Vibrational sum-frequency generation spectroscopy is a valuable probe of surface structure, particularly when the same molecules are present in one of the adjacent bulk solid or solution phases. As a result of the non-centrosymmetric requirement of SFG, the signal generated is a marker of the extent to which the molecules are ordered in an arrangement that breaks the up-down symmetry at the surface. In cases where the accompanying changes in the bulk are of interest in understanding and interpreting the surface structure, simultaneous analysis of the bulk IR absorption or bulk Raman scattering is helpful, and may be used in heterospectral surface-bulk two-dimensional correlation. We demonstrate that, in such cases, generating a new type of bulk spectrum that combines the IR and Raman amplitudes is a better candidate than the individual IR and Raman spectra for the purpose of correlation with the SFG signal.

Using surface segregation to design stable Ru-Ir oxides for the oxygen evolution reaction in acidic environments.

DOE PAGES

Danilovic, N.; Subbaraman, R.; Chang, K-C.; ...

2014-10-08

The methods used to improve catalytic activity are well-established, however elucidating the factors that simultaneously control activity and stability is still lacking, especially for oxygen evolution reaction (OER) catalysts. Here, by studying fundamental links between the activity and stability of well-characterized monometallic and bimetallic oxides, we found that there is generally an inverse relationship between activity and stability. To overcome this limitation, we developed a new synthesis strategy that is based on tuning the near-surface composition of Ru and Ir elements by surface segregation, thereby resulting in the formation of a nanosegregated domain that balances the stability and activity ofmore » surface atoms. We demonstrate that a Ru0.5Ir0.5 alloy synthesized by using this method exhibits four-times higher stability than the best Ru-Ir oxygen evolution reaction materials, while still preserving the same activity.« less

Thermal Image Sensing Model for Robotic Planning and Search

PubMed Central

Castro Jiménez, Lídice E.; Martínez-García, Edgar A.

2016-01-01

This work presents a search planning system for a rolling robot to find a source of infra-red (IR) radiation at an unknown location. Heat emissions are observed by a low-cost home-made IR passive visual sensor. The sensor capability for detection of radiation spectra was experimentally characterized. The sensor data were modeled by an exponential model to estimate the distance as a function of the IR image’s intensity, and, a polynomial model to estimate temperature as a function of IR intensities. Both theoretical models are combined to deduce a subtle nonlinear exact solution via distance-temperature. A planning system obtains feed back from the IR camera (position, intensity, and temperature) to lead the robot to find the heat source. The planner is a system of nonlinear equations recursively solved by a Newton-based approach to estimate the IR-source in global coordinates. The planning system assists an autonomous navigation control in order to reach the goal and avoid collisions. Trigonometric partial differential equations were established to control the robot’s course towards the heat emission. A sine function produces attractive accelerations toward the IR source. A cosine function produces repulsive accelerations against the obstacles observed by an RGB-D sensor. Simulations and real experiments of complex indoor are presented to illustrate the convenience and efficacy of the proposed approach. PMID:27509510

Nonuniformity correction based on focal plane array temperature in uncooled long-wave infrared cameras without a shutter.

PubMed

Liang, Kun; Yang, Cailan; Peng, Li; Zhou, Bo

2017-02-01

In uncooled long-wave IR camera systems, the temperature of a focal plane array (FPA) is variable along with the environmental temperature as well as the operating time. The spatial nonuniformity of the FPA, which is partly affected by the FPA temperature, obviously changes as well, resulting in reduced image quality. This study presents a real-time nonuniformity correction algorithm based on FPA temperature to compensate for nonuniformity caused by FPA temperature fluctuation. First, gain coefficients are calculated using a two-point correction technique. Then offset parameters at different FPA temperatures are obtained and stored in tables. When the camera operates, the offset tables are called to update the current offset parameters via a temperature-dependent interpolation. Finally, the gain coefficients and offset parameters are used to correct the output of the IR camera in real time. The proposed algorithm is evaluated and compared with two representative shutterless algorithms [minimizing the sum of the squares of errors algorithm (MSSE), template-based solution algorithm (TBS)] using IR images captured by a 384×288 pixel uncooled IR camera with a 17 μm pitch. Experimental results show that this method can quickly trace the response drift of the detector units when the FPA temperature changes. The quality of the proposed algorithm is as good as MSSE, while the processing time is as short as TBS, which means the proposed algorithm is good for real-time control and at the same time has a high correction effect.

Surface properties of ancient cratered terrain in the northern hemisphere of Mars

NASA Technical Reports Server (NTRS)

Zimbelman, J. R.; Greeley, R.

1982-01-01

Viking high resolution IR data is used in an examination of the hilly and cratered material of Scott and Carr (1978), supposed to be the oldest extensively exposed surface on Mars. Measured nighttime temperatures at 11 and 20 microns indicate inertia blocks, surrounded by lower thermal inertia soil. Geologic features crossed by the Viking data generally show no difference from the regional properties. Imaging data from within and around the Arabia low thermal inertia region indicate that subdued surface morphology is not always associated with low thermal inertias. The mantling of ancient northern hemisphere cratered terrain by fine grained material does not allow thermal measurements to be directly related to rock unit properties, but less mantling may be present in southern hemisphere locations of this material.

Plant cover, soil temperature, freeze, water stress, and evapotranspiration conditions. [south Texas

NASA Technical Reports Server (NTRS)

Wiegand, C. L.; Nixon, P. R.; Gausman, H. W.; Namken, L. N.; Leamer, R. W.; Richardson, A. J. (Principal Investigator)

1981-01-01

Emissive and reflective data for 10 days, and IR data for 6 nights in south Texas scenes were analyzed after procedures were developed for removing cloud-affected data. HCMM radiometric temperatures were: within 2 C of dewpoint temperatures on nights when air temperature approached dewpoint temperatures; significantly correlated with variables important in evapotranspiration; and, related to freeze severity and planting depth soil temperatures. Vegetation greenness indexes calculated from visible and reflective IR bands of NOAA-6 to -9 meteorological satellites will be useful in the AgRISTARS program for seasonal crop development, crop condition, and drought applications.