Improved thermal storage material for portable life support systems

NASA Technical Reports Server (NTRS)

Kellner, J. D.

1975-01-01

The availability of thermal storage materials that have heat absorption capabilities substantially greater than water-ice in the same temperature range would permit significant improvements in performance of projected portable thermal storage cooling systems. A method for providing increased heat absorption by the combined use of the heat of solution of certain salts and the heat of fusion of water-ice was investigated. This work has indicated that a 30 percent solution of potassium bifluoride (KHF2) in water can absorb approximately 52 percent more heat than an equal weight of water-ice, and approximately 79 percent more heat than an equal volume of water-ice. The thermal storage material can be regenerated easily by freezing, however, a lower temperature must be used, 261 K as compared to 273 K for water-ice. This work was conducted by the United Aircraft Research Laboratories as part of a program at Hamilton Standard Division of United Aircraft Corporation under contract to NASA Ames Research Center.

Materials Genome in Action: Identifying the Performance Limits of Physical Hydrogen Storage

PubMed Central

2017-01-01

The Materials Genome is in action: the molecular codes for millions of materials have been sequenced, predictive models have been developed, and now the challenge of hydrogen storage is targeted. Renewably generated hydrogen is an attractive transportation fuel with zero carbon emissions, but its storage remains a significant challenge. Nanoporous adsorbents have shown promising physical adsorption of hydrogen approaching targeted capacities, but the scope of studies has remained limited. Here the Nanoporous Materials Genome, containing over 850 000 materials, is analyzed with a variety of computational tools to explore the limits of hydrogen storage. Optimal features that maximize net capacity at room temperature include pore sizes of around 6 Å and void fractions of 0.1, while at cryogenic temperatures pore sizes of 10 Å and void fractions of 0.5 are optimal. Our top candidates are found to be commercially attractive as “cryo-adsorbents”, with promising storage capacities at 77 K and 100 bar with 30% enhancement to 40 g/L, a promising alternative to liquefaction at 20 K and compression at 700 bar. PMID:28413259

Materials genome in action: Identifying the performance limits of physical hydrogen storage

DOE PAGES

Thornton, Aaron W.; Simon, Cory M.; Kim, Jihan; ...

2017-03-08

The Materials Genome is in action: the molecular codes for millions of materials have been sequenced, predictive models have been developed, and now the challenge of hydrogen storage is targeted. Renewably generated hydrogen is an attractive transportation fuel with zero carbon emissions, but its storage remains a significant challenge. Nanoporous adsorbents have shown promising physical adsorption of hydrogen approaching targeted capacities, but the scope of studies has remained limited. Here the Nanoporous Materials Genome, containing over 850 000 materials, is analyzed with a variety of computational tools to explore the limits of hydrogen storage. Optimal features that maximize net capacitymore » at room temperature include pore sizes of around 6 Å and void fractions of 0.1, while at cryogenic temperatures pore sizes of 10 Å and void fractions of 0.5 are optimal. Finally, our top candidates are found to be commercially attractive as “cryo-adsorbents”, with promising storage capacities at 77 K and 100 bar with 30% enhancement to 40 g/L, a promising alternative to liquefaction at 20 K and compression at 700 bar.« less

Materials genome in action: Identifying the performance limits of physical hydrogen storage

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thornton, Aaron W.; Simon, Cory M.; Kim, Jihan

The Materials Genome is in action: the molecular codes for millions of materials have been sequenced, predictive models have been developed, and now the challenge of hydrogen storage is targeted. Renewably generated hydrogen is an attractive transportation fuel with zero carbon emissions, but its storage remains a significant challenge. Nanoporous adsorbents have shown promising physical adsorption of hydrogen approaching targeted capacities, but the scope of studies has remained limited. Here the Nanoporous Materials Genome, containing over 850 000 materials, is analyzed with a variety of computational tools to explore the limits of hydrogen storage. Optimal features that maximize net capacitymore » at room temperature include pore sizes of around 6 Å and void fractions of 0.1, while at cryogenic temperatures pore sizes of 10 Å and void fractions of 0.5 are optimal. Finally, our top candidates are found to be commercially attractive as “cryo-adsorbents”, with promising storage capacities at 77 K and 100 bar with 30% enhancement to 40 g/L, a promising alternative to liquefaction at 20 K and compression at 700 bar.« less

Graphene and graphene-based materials for energy storage applications.

PubMed

Zhu, Jixin; Yang, Dan; Yin, Zongyou; Yan, Qingyu; Zhang, Hua

2014-09-10

With the increased demand in energy resources, great efforts have been devoted to developing advanced energy storage and conversion systems. Graphene and graphene-based materials have attracted great attention owing to their unique properties of high mechanical flexibility, large surface area, chemical stability, superior electric and thermal conductivities that render them great choices as alternative electrode materials for electrochemical energy storage systems. This Review summarizes the recent progress in graphene and graphene-based materials for four energy storage systems, i.e., lithium-ion batteries, supercapacitors, lithium-sulfur batteries and lithium-air batteries. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Porous polymeric materials for hydrogen storage

DOEpatents

Yu, Luping; Liu, Di-Jia; Yuan, Shengwen; Yang, Junbing

2013-04-02

A porous polymer, poly-9,9'-spirobifluorene and its derivatives for storage of H.sub.2 are prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO.sub.2/steam oxidation and supercritical water treatment.

The potential of organic polymer-based hydrogen storage materials.

PubMed

Budd, Peter M; Butler, Anna; Selbie, James; Mahmood, Khalid; McKeown, Neil B; Ghanem, Bader; Msayib, Kadhum; Book, David; Walton, Allan

2007-04-21

The challenge of storing hydrogen at high volumetric and gravimetric density for automotive applications has prompted investigations into the potential of cryo-adsorption on the internal surface area of microporous organic polymers. A range of Polymers of Intrinsic Microporosity (PIMs) has been studied, the best PIM to date (a network-PIM incorporating a triptycene subunit) taking up 2.7% H(2) by mass at 10 bar/77 K. HyperCrosslinked Polymers (HCPs) also show promising performance as H(2) storage materials, particularly at pressures >10 bar. The N(2) and H(2) adsorption behaviour at 77 K of six PIMs and a HCP are compared. Surface areas based on Langmuir plots of H(2) adsorption at high pressure are shown to provide a useful guide to hydrogen capacity, but Langmuir plots based on low pressure data underestimate the potential H(2) uptake. The micropore distribution influences the form of the H(2) isotherm, a higher concentration of ultramicropores (pore size <0.7 nm) being associated with enhanced low pressure adsorption.

Porous polymeric materials for hydrogen storage

DOEpatents

Yu, Luping [Hoffman Estates, IL; Liu, Di-Jia [Naperville, IL; Yuan, Shengwen [Chicago, IL; Yang, Junbing [Westmont, IL

2011-12-13

Porous polymers, tribenzohexazatriphenylene, poly-9,9'-spirobifluorene, poly-tetraphenyl methane and their derivatives for storage of H.sub.2 prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO.sub.2/steam oxidation and supercritical water treatment.

Recent Advances in Porous Carbon Materials for Electrochemical Energy Storage.

PubMed

Wang, Libin; Hu, Xianluo

2018-06-18

Climate change and the energy crisis have promoted the rapid development of electrochemical energy-storage devices. Owing to many intriguing physicochemical properties, such as excellent chemical stability, high electronic conductivity, and a large specific surface area, porous carbon materials have always been considering as a promising candidate for electrochemical energy storage. To date, a wide variety of porous carbon materials based upon molecular design, pore control, and compositional tailoring have been proposed for energy-storage applications. This focus review summarizes recent advances in the synthesis of various porous carbon materials from the view of energy storage, particularly in the past three years. Their applications in representative electrochemical energy-storage devices, such as lithium-ion batteries, supercapacitors, and lithium-ion hybrid capacitors, are discussed in this review, with a look forward to offer some inspiration and guidelines for the exploitation of advanced carbon-based energy-storage materials. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

5. INTERIOR, STORAGE AREA AT WESTERN END, FROM SOUTH OF ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

5. INTERIOR, STORAGE AREA AT WESTERN END, FROM SOUTH OF LOADING DOCK WELL, LOOKING NORTH. - Oakland Naval Supply Center, Coffee Roasting Plant, East of Fourth Street, between J & K, Oakland, Alameda County, CA

The rise of organic electrode materials for energy storage.

PubMed

Schon, Tyler B; McAllister, Bryony T; Li, Peng-Fei; Seferos, Dwight S

2016-11-07

Organic electrode materials are very attractive for electrochemical energy storage devices because they can be flexible, lightweight, low cost, benign to the environment, and used in a variety of device architectures. They are not mere alternatives to more traditional energy storage materials, rather, they have the potential to lead to disruptive technologies. Although organic electrode materials for energy storage have progressed in recent years, there are still significant challenges to overcome before reaching large-scale commercialization. This review provides an overview of energy storage systems as a whole, the metrics that are used to quantify the performance of electrodes, recent strategies that have been investigated to overcome the challenges associated with organic electrode materials, and the use of computational chemistry to design and study new materials and their properties. Design strategies are examined to overcome issues with capacity/capacitance, device voltage, rate capability, and cycling stability in order to guide future work in the area. The use of low cost materials is highlighted as a direction towards commercial realization.

Metal-Organic Framework-Derived Materials for Sodium Energy Storage.

PubMed

Zou, Guoqiang; Hou, Hongshuai; Ge, Peng; Huang, Zhaodong; Zhao, Ganggang; Yin, Dulin; Ji, Xiaobo

2018-01-01

Recently, sodium-ion batteries (SIBs) are extensively explored and are regarded as one of the most promising alternatives to lithium-ion batteries for electrochemical energy conversion and storage, owing to the abundant raw material resources, low cost, and similar electrochemical behavior of elemental sodium compared to lithium. Metal-organic frameworks (MOFs) have attracted enormous attention due to their high surface areas, tunable structures, and diverse applications in drug delivery, gas storage, and catalysis. Recently, there has been an escalating interest in exploiting MOF-derived materials as anodes for sodium energy storage due to their fast mass transport resulting from their highly porous structures and relatively simple preparation methods originating from in situ thermal treatment processes. In this Review, the recent progress of the sodium-ion storage performances of MOF-derived materials, including MOF-derived porous carbons, metal oxides, metal oxide/carbon nanocomposites, and other materials (e.g., metal phosphides, metal sulfides, and metal selenides), as SIB anodes is systematically and completely presented and discussed. Moreover, the current challenges and perspectives of MOF-derived materials in electrochemical energy storage are discussed. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Electrochemical energy storage in montmorillonite K10 clay based composite as supercapacitor using ionic liquid electrolyte.

PubMed

Maiti, Sandipan; Pramanik, Atin; Chattopadhyay, Shreyasi; De, Goutam; Mahanty, Sourindra

2016-02-15

Exploring new electrode materials is the key to realize high performance energy storage devices for effective utilization of renewable energy. Natural clays with layered structure and high surface area are prospective materials for electrical double layer capacitors (EDLC). In this work, a novel hybrid composite based on acid-leached montmorillonite (K10), multi-walled carbon nanotube (MWCNT) and manganese dioxide (MnO2) was prepared and its electrochemical properties were investigated by fabricating two-electrode asymmetric supercapacitor cells against activated carbon (AC) using 1.0M tetraethylammonium tetrafluroborate (Et4NBF4) in acetonitrile (AN) as electrolyte. The asymmetric supercapacitors, capable of operating in a wide potential window of 0.0-2.7V, showed a high energy density of 171Whkg(-1) at a power density of ∼1.98kWkg(-1). Such high EDLC performance could possibly be linked to the acid-base interaction of K10 through its surface hydroxyl groups with the tetraethylammonium cation [(C2H5)4N(+) or TEA(+)] of the ionic liquid electrolyte. Even at a very high power density of 96.4kWkg(-1), the cells could still deliver an energy density of 91.1Whkg(-1) exhibiting an outstanding rate capability. The present study demonstrates for the first time, the excellent potential of clay-based composites for high power energy storage device applications. Copyright © 2015 Elsevier Inc. All rights reserved.

Nanostructured materials for hydrogen storage

DOEpatents

Williamson, Andrew J.; Reboredo, Fernando A.

2007-12-04

A system for hydrogen storage comprising a porous nano-structured material with hydrogen absorbed on the surfaces of the porous nano-structured material. The system of hydrogen storage comprises absorbing hydrogen on the surfaces of a porous nano-structured semiconductor material.

High capacity hydrogen storage materials: attributes for automotive applications and techniques for materials discovery.

PubMed

Yang, Jun; Sudik, Andrea; Wolverton, Christopher; Siegel, Donald J

2010-02-01

Widespread adoption of hydrogen as a vehicular fuel depends critically upon the ability to store hydrogen on-board at high volumetric and gravimetric densities, as well as on the ability to extract/insert it at sufficiently rapid rates. As current storage methods based on physical means--high-pressure gas or (cryogenic) liquefaction--are unlikely to satisfy targets for performance and cost, a global research effort focusing on the development of chemical means for storing hydrogen in condensed phases has recently emerged. At present, no known material exhibits a combination of properties that would enable high-volume automotive applications. Thus new materials with improved performance, or new approaches to the synthesis and/or processing of existing materials, are highly desirable. In this critical review we provide a practical introduction to the field of hydrogen storage materials research, with an emphasis on (i) the properties necessary for a viable storage material, (ii) the computational and experimental techniques commonly employed in determining these attributes, and (iii) the classes of materials being pursued as candidate storage compounds. Starting from the general requirements of a fuel cell vehicle, we summarize how these requirements translate into desired characteristics for the hydrogen storage material. Key amongst these are: (a) high gravimetric and volumetric hydrogen density, (b) thermodynamics that allow for reversible hydrogen uptake/release under near-ambient conditions, and (c) fast reaction kinetics. To further illustrate these attributes, the four major classes of candidate storage materials--conventional metal hydrides, chemical hydrides, complex hydrides, and sorbent systems--are introduced and their respective performance and prospects for improvement in each of these areas is discussed. Finally, we review the most valuable experimental and computational techniques for determining these attributes, highlighting how an approach that

Effect of K loadings on nitrate formation/decomposition and on NOx storage performance of K-based NOx storage-reduction catalysts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Do Heui; Mudiyanselage, Kumudu K.; Szanyi, Janos

2013-10-25

We have investigated nitrate formation and decomposition processes, and measured NOx storage performance on Pt-K2O/Al2O3 catalysts as a function of potassium loading. After NO2 adsorption at room temperature, ionic and bidentate nitrates were observed by fourier transform infra-red (FTIR) spectroscopy. The ratio of the former to the latter species increased with increasing potassium loading up to 10 wt%, and then stayed almost constant with additional K, demonstrating a clear dependence of loading on the morphology of the K species. Although both K2O(10)/Al2O3 and K2O(20)/Al2O3 samples have similar nitrate species after NO2 adsorption, the latter has more thermally stable nitrate speciesmore » as evidenced by FTIR and NO2 temperature programmed desorption (TPD) results. With regard to NOx storage performance, the temperature of maximum NOx uptake (Tmax) is 573 K up to a potassium loading of 10 wt%. As the potassium loading increases from 10 wt% to 20 wt%, Tmax shifted from 573 K to 723 K. Moreover, the amount of NO uptake (38 cm3 NOx/g catal) at Tmax increased more than three times, indicating that efficiency of K in storing NOx is enhanced significantly at higher temperature, in good agreement with the NO2 TPD and FTIR results. Thus, a combination of characterization and NOx storage performance results demonstrates an unexpected effect of potassium loading on nitrate formation and decomposition processes; results important for developing Pt-K2O/Al2O3 for potential applications as high temperature NOx storage-reduction catalysts.« less

Comparative study of hydrogen storage on metal doped mesoporous materials

NASA Astrophysics Data System (ADS)

Carraro, P. M.; Sapag, K.; Oliva, M. I.; Eimer, G. A.

2018-06-01

The hydrogen adsorption capacity of mesoporous materials MCM-41 modified with Co, Fe, Ti, Mg and Ni at 77 K and 10 bar was investigated. Various techniques including XRD, N2 adsorption and DRUV-vis were employed for the materials characterization. The results showed that a low nickel loading on MCM-41 support promoted the presence of hydrogen-favorable sites, increasing the hydrogen storage capacity.

Carbon material for hydrogen storage

DOEpatents

Bourlinos, Athanasios; Steriotis, Theodore; Stubos, Athanasios; Miller, Michael A

2016-09-13

The present invention relates to carbon based materials that are employed for hydrogen storage applications. The material may be described as the pyrolysis product of a molecular precursor such as a cyclic quinone compound. The pyrolysis product may then be combined with selected transition metal atoms which may be in nanoparticulate form, where the metals may be dispersed on the material surface. Such product may then provide for the reversible storage of hydrogen. The metallic nanoparticles may also be combined with a second metal as an alloy to further improve hydrogen storage performance.

32 CFR 2001.53 - Open storage areas.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 32 National Defense 6 2012-07-01 2012-07-01 false Open storage areas. 2001.53 Section 2001.53....53 Open storage areas. This section describes the minimum construction standards for open storage... in its smallest dimension) that enter or pass through an open storage area shall be protected with...

32 CFR 2001.53 - Open storage areas.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 32 National Defense 6 2014-07-01 2014-07-01 false Open storage areas. 2001.53 Section 2001.53....53 Open storage areas. This section describes the minimum construction standards for open storage... in its smallest dimension) that enter or pass through an open storage area shall be protected with...

Activated carbon derived from waste coffee grounds for stable methane storage.

PubMed

Kemp, K Christian; Baek, Seung Bin; Lee, Wang-Geun; Meyyappan, M; Kim, Kwang S

2015-09-25

An activated carbon material derived from waste coffee grounds is shown to be an effective and stable medium for methane storage. The sample activated at 900 °C displays a surface area of 1040.3 m(2) g(-1) and a micropore volume of 0.574 cm(3) g(-1) and exhibits a stable CH4 adsorption capacity of ∼4.2 mmol g(-1) at 3.0 MPa and a temperature range of 298 ± 10 K. The same material exhibits an impressive hydrogen storage capacity of 1.75 wt% as well at 77 K and 100 kPa. Here, we also propose a mechanism for the formation of activated carbon from spent coffee grounds. At low temperatures, the material has two distinct types with low and high surface areas; however, activation at elevated temperatures drives off the low surface area carbon, leaving behind the porous high surface area activated carbon.

Activated carbon derived from waste coffee grounds for stable methane storage

NASA Astrophysics Data System (ADS)

Kemp, K. Christian; Baek, Seung Bin; Lee, Wang-Geun; Meyyappan, M.; Kim, Kwang S.

2015-09-01

An activated carbon material derived from waste coffee grounds is shown to be an effective and stable medium for methane storage. The sample activated at 900 °C displays a surface area of 1040.3 m2 g-1 and a micropore volume of 0.574 cm3 g-1 and exhibits a stable CH4 adsorption capacity of ˜4.2 mmol g-1 at 3.0 MPa and a temperature range of 298 ± 10 K. The same material exhibits an impressive hydrogen storage capacity of 1.75 wt% as well at 77 K and 100 kPa. Here, we also propose a mechanism for the formation of activated carbon from spent coffee grounds. At low temperatures, the material has two distinct types with low and high surface areas; however, activation at elevated temperatures drives off the low surface area carbon, leaving behind the porous high surface area activated carbon.

Sorbent Material Property Requirements for On-Board Hydrogen Storage for Automotive Fuel Cell Systems.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ahluwalia, R. K.; Peng, J-K; Hua, T. Q.

2015-05-25

Material properties required for on-board hydrogen storage in cryogenic sorbents for use with automotive polymer electrolyte membrane (PEM) fuel cell systems are discussed. Models are formulated for physical, thermodynamic and transport properties, and for the dynamics of H-2 refueling and discharge from a sorbent bed. A conceptual storage configuration with in-bed heat exchanger tubes, a Type-3 containment vessel, vacuum insulation and requisite balance-of-plant components is developed to determine the peak excess sorption capacity and differential enthalpy of adsorption for 5.5 wt% system gravimetric capacity and 55% well-to-tank (WTT) efficiency. The analysis also determines the bulk density to which the materialmore » must be compacted for the storage system to reach 40 g.L-1 volumetric capacity. Thermal transport properties and heat transfer enhancement methods are analyzed to estimate the material thermal conductivity needed to achieve 1.5 kg.min(-1) H-2 refueling rate. Operating temperatures and pressures are determined for 55% WTT efficiency and 95% usable H-2. Needs for further improvements in material properties are analyzed that would allow reduction of storage pressure to 50 bar from 100 bar, elevation of storage temperature to 175-200 K from 150 K, and increase of WTT efficiency to 57.5% or higher.« less

3. WESTERN STORAGE AREA, FROM EAST WALL APPROXIMATELY 50 FEET ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. WESTERN STORAGE AREA, FROM EAST WALL APPROXIMATELY 50 FEET NORTH OF SOUTH WALL, LOOKING WEST. - Oakland Naval Supply Center, Reserve Materials Storehouse, Between I & J Streets, between Fourth & Fifth Streets, Oakland, Alameda County, CA

WEAPONS STORAGE AREA. FROM RIGHT TO LEFT, ABOVEGROUND STORAGE MAGAZINE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

WEAPONS STORAGE AREA. FROM RIGHT TO LEFT, ABOVEGROUND STORAGE MAGAZINE (BUILDING 3568), SPARES INERT STORAGE BUILDING (BUILDING 3570), MISSILE ASSEMBLY SHOP (BUILDING 3578) AND SEGREGATED MAGAZINE STORAGE BUILDING (BUILDING 3572). VIEW TO NORTHWEST - Plattsburgh Air Force Base, U.S. Route 9, Plattsburgh, Clinton County, NY

Organic Carbon Storage in China's Urban Areas

PubMed Central

Zhao, Shuqing; Zhu, Chao; Zhou, Decheng; Huang, Dian; Werner, Jeremy

2013-01-01

China has been experiencing rapid urbanization in parallel with its economic boom over the past three decades. To date, the organic carbon storage in China's urban areas has not been quantified. Here, using data compiled from literature review and statistical yearbooks, we estimated that total carbon storage in China's urban areas was 577±60 Tg C (1 Tg  = 1012 g) in 2006. Soil was the largest contributor to total carbon storage (56%), followed by buildings (36%), and vegetation (7%), while carbon storage in humans was relatively small (1%). The carbon density in China's urban areas was 17.1±1.8 kg C m−2, about two times the national average of all lands. The most sensitive variable in estimating urban carbon storage was urban area. Examining urban carbon storages over a wide range of spatial extents in China and in the United States, we found a strong linear relationship between total urban carbon storage and total urban area, with a specific urban carbon storage of 16 Tg C for every 1,000 km2 urban area. This value might be useful for estimating urban carbon storage at regional to global scales. Our results also showed that the fraction of carbon storage in urban green spaces was still much lower in China relative to western countries, suggesting a great potential to mitigate climate change through urban greening and green spaces management in China. PMID:23991014

32 CFR 2001.53 - Open storage areas.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 32 National Defense 6 2013-07-01 2013-07-01 false Open storage areas. 2001.53 Section 2001.53....53 Open storage areas. This section describes the minimum construction standards for open storage... storage. Doors other than those secured with the aforementioned locks shall be secured from the inside...

32 CFR 2001.53 - Open storage areas.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 32 National Defense 6 2011-07-01 2011-07-01 false Open storage areas. 2001.53 Section 2001.53....53 Open storage areas. This section describes the minimum construction standards for open storage... storage. Doors other than those secured with the aforementioned locks shall be secured from the inside...

Thermal energy storage material

DOEpatents

Leifer, Leslie

1976-01-01

A thermal energy storage material which is stable at atmospheric temperature and pressure and has a melting point higher than 32.degree.F. is prepared by dissolving a specific class of clathrate forming compounds, such as tetra n-propyl or tetra n-butyl ammonium fluoride, in water to form a substantially solid clathrate. The resultant thermal energy storage material is capable of absorbing heat from or releasing heat to a given region as it transforms between solid and liquid states in response to temperature changes in the region above and below its melting point.

Thermal Storage Materials Laboratory | Energy Systems Integration Facility

Science.gov Websites

| NREL Materials Laboratory Thermal Storage Materials Laboratory In the Energy Systems Integration Facility's Thermal Storage Materials Laboratory, researchers investigate materials that can be used as high-temperature heat transfer fluids or thermal energy storage media in concentrating solar

Nanoporous Materials for the Onboard Storage of Natural Gas.

PubMed

Kumar, K Vasanth; Preuss, Kathrin; Titirici, Maria-Magdalena; Rodríguez-Reinoso, Francisco

2017-02-08

Climate change, global warming, urban air pollution, energy supply uncertainty and depletion, and rising costs of conventional energy sources are, among others, potential socioeconomic threats that our community faces today. Transportation is one of the primary sectors contributing to oil consumption and global warming, and natural gas (NG) is considered to be a relatively clean transportation fuel that can significantly improve local air quality, reduce greenhouse-gas emissions, and decrease the energy dependency on oil sources. Internal combustion engines (ignited or compression) require only slight modifications for use with natural gas; rather, the main problem is the relatively short driving distance of natural-gas-powered vehicles due to the lack of an appropriate storage method for the gas, which has a low energy density. The U.S. Department of Energy (DOE) has set some targets for NG storage capacity to obtain a reasonable driving range in automotive applications, ruling out the option of storing methane at cryogenic temperatures. In recent years, both academia and industry have foreseen the storage of natural gas by adsorption (ANG) in porous materials, at relatively low pressures and ambient temperatures, as a solution to this difficult problem. This review presents recent developments in the search for novel porous materials with high methane storage capacities. Within this scenario, both carbon-based materials and metal-organic frameworks are considered to be the most promising materials for natural gas storage, as they exhibit properties such as large surface areas and micropore volumes, that favor a high adsorption capacity for natural gas. Recent advancements, technological issues, advantages, and drawbacks involved in natural gas storage in these two classes of materials are also summarized. Further, an overview of the recent developments and technical challenges in storing natural gas as hydrates in wetted porous carbon materials is also included

Energy storage crystalline gel materials for 3D printing application

NASA Astrophysics Data System (ADS)

Mao, Yuchen; Miyazaki, Takuya; Gong, Jin; Zhu, Meifang

2017-04-01

Phase change materials (PCMs) are considered one of the most reliable latent heat storage and thermoregulation materials. In this paper, a vinyl monomer is used to provide energy storage capacity and synthesize gel with phase change property. The side chain of copolymer form crystal microcell to storage/release energy through phase change. The crosslinking structure of the copolymer can protect the crystalline micro-area maintaining the phase change stable in service and improving the mechanical strength. By selecting different monomers and adjusting their ratios, we design the chemical structure and the crystallinity of gels, which in further affect their properties, such as strength, flexibility, thermal absorb/release transition temperature, transparency and the water content. Using the light-induced polymerization 3D printing techniques, we synthesize the energy storage gel and shape it on a 3D printer at the same time. By optimizing the 3D printing conditions, including layer thickness, curing time and light source, etc., the 3D printing objects are obtained.

9 CFR 355.15 - Inedible material operating and storage rooms; outer premises, docks, driveways, etc.; fly...

Code of Federal Regulations, 2012 CFR

2012-01-01

... storage rooms; outer premises, docks, driveways, etc.; fly-breeding material; nuisances. 355.15 Section....15 Inedible material operating and storage rooms; outer premises, docks, driveways, etc.; fly... departments where certified products are prepared, handled, or stored. Docks and areas where cars and vehicles...

9 CFR 355.15 - Inedible material operating and storage rooms; outer premises, docks, driveways, etc.; fly...

Code of Federal Regulations, 2014 CFR

2014-01-01

... storage rooms; outer premises, docks, driveways, etc.; fly-breeding material; nuisances. 355.15 Section....15 Inedible material operating and storage rooms; outer premises, docks, driveways, etc.; fly... departments where certified products are prepared, handled, or stored. Docks and areas where cars and vehicles...

9 CFR 355.15 - Inedible material operating and storage rooms; outer premises, docks, driveways, etc.; fly...

Code of Federal Regulations, 2013 CFR

2013-01-01

... storage rooms; outer premises, docks, driveways, etc.; fly-breeding material; nuisances. 355.15 Section....15 Inedible material operating and storage rooms; outer premises, docks, driveways, etc.; fly... departments where certified products are prepared, handled, or stored. Docks and areas where cars and vehicles...

30 CFR 57.6102 - Explosive material storage practices.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Explosive material storage practices. 57.6102... Storage-Surface and Underground § 57.6102 Explosive material storage practices. (a) Explosive material... instructions and the date-plant-shift code are maintained with the product. Storage—Surface Only ...

30 CFR 57.6102 - Explosive material storage practices.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Explosive material storage practices. 57.6102... Storage-Surface and Underground § 57.6102 Explosive material storage practices. (a) Explosive material... instructions and the date-plant-shift code are maintained with the product. Storage—Surface Only ...

Microwavable thermal energy storage material

DOEpatents

Salyer, Ival O.

1998-09-08

A microwavable thermal energy storage material is provided which includes a mixture of a phase change material and silica, and a carbon black additive in the form of a conformable dry powder of phase change material/silica/carbon black, or solid pellets, films, fibers, moldings or strands of phase change material/high density polyethylene/ethylene-vinyl acetate/silica/carbon black which allows the phase change material to be rapidly heated in a microwave oven. The carbon black additive, which is preferably an electrically conductive carbon black, may be added in low concentrations of from 0.5 to 15% by weight, and may be used to tailor the heating times of the phase change material as desired. The microwavable thermal energy storage material can be used in food serving applications such as tableware items or pizza warmers, and in medical wraps and garments.

30 CFR 56.6102 - Explosive material storage practices.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Explosive material storage practices. 56.6102 Section 56.6102 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND... Storage § 56.6102 Explosive material storage practices. (a) Explosive material shall be— (1) Stored in a...

30 CFR 56.6102 - Explosive material storage practices.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Explosive material storage practices. 56.6102 Section 56.6102 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND... Storage § 56.6102 Explosive material storage practices. (a) Explosive material shall be— (1) Stored in a...

30 CFR 57.16003 - Storage of hazardous materials.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Storage of hazardous materials. 57.16003 Section 57.16003 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND... Storage and Handling § 57.16003 Storage of hazardous materials. Materials that can create hazards if...

30 CFR 56.16003 - Storage of hazardous materials.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Storage of hazardous materials. 56.16003 Section 56.16003 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND... Storage and Handling § 56.16003 Storage of hazardous materials. Materials that can create hazards if...

30 CFR 56.16003 - Storage of hazardous materials.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Storage of hazardous materials. 56.16003 Section 56.16003 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND... Storage and Handling § 56.16003 Storage of hazardous materials. Materials that can create hazards if...

30 CFR 57.16003 - Storage of hazardous materials.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Storage of hazardous materials. 57.16003 Section 57.16003 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND... Storage and Handling § 57.16003 Storage of hazardous materials. Materials that can create hazards if...

Fluoride salts and container materials for thermal energy storage applications in the temperature range 973 - 1400 K

NASA Technical Reports Server (NTRS)

Misra, Ajay K.; Whittenberger, J. Daniel

1987-01-01

Multicomponent fluoride salt mixtures were characterized for use as latent heat of fusion heat storage materials in advanced solar dynamic space power systems with operating temperatures in the range of 973 to 1400 K. The melting points and eutectic composition for many systems with published phase diagrams were verified, and several new eutectic compositions were identified. Additionally, the heats of fusion of several binary and ternary eutectics and congruently melting intermediate compounds were measured by differential scanning calorimetry. The extent of corrosion of various metals by fluoride melts was estimated from thermodynamic considerations, and equilibrium conditions inside a containment vessel were calculated as functions of the initial moisture content of the salt and free volume above the molten salt. Preliminary experimental data on the corrosion of commercial, high-temperature alloys in LiF-19.5CaF2 and NaF-27CaF2-36MgF2 melts are presented and compared to the thermodynamic predictions.

Selection of high temperature thermal energy storage materials for advanced solar dynamic space power systems

NASA Technical Reports Server (NTRS)

Lacy, Dovie E.; Coles-Hamilton, Carolyn; Juhasz, Albert

1987-01-01

Under the direction of NASA's Office of Aeronautics and Technology (OAST), the NASA Lewis Research Center has initiated an in-house thermal energy storage program to identify combinations of phase change thermal energy storage media for use with a Brayton and Stirling Advanced Solar Dynamic (ASD) space power system operating between 1070 and 1400 K. A study has been initiated to determine suitable combinations of thermal energy storage (TES) phase change materials (PCM) that result in the smallest and lightest weight ASD power system possible. To date the heats of fusion of several fluoride salt mixtures with melting points greater than 1025 K have been verified experimentally. The study has indicated that these salt systems produce large ASD systems because of their inherent low thermal conductivity and low density. It is desirable to have PCMs with high densities and high thermal conductivities. Therefore, alternate phase change materials based on metallic alloy systems are also being considered as possible TES candidates for future ASD space power systems.

Microwavable thermal energy storage material

DOEpatents

Salyer, I.O.

1998-09-08

A microwavable thermal energy storage material is provided which includes a mixture of a phase change material and silica, and a carbon black additive in the form of a conformable dry powder of phase change material/silica/carbon black, or solid pellets, films, fibers, moldings or strands of phase change material/high density polyethylene/ethylene vinyl acetate/silica/carbon black which allows the phase change material to be rapidly heated in a microwave oven. The carbon black additive, which is preferably an electrically conductive carbon black, may be added in low concentrations of from 0.5 to 15% by weight, and may be used to tailor the heating times of the phase change material as desired. The microwavable thermal energy storage material can be used in food serving applications such as tableware items or pizza warmers, and in medical wraps and garments. 3 figs.

174. STORAGE ROOM, SOUTH WEST CORNER OF STORAGE AREA ADDED ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

174. STORAGE ROOM, SOUTH WEST CORNER OF STORAGE AREA ADDED AS PART OF 1905 ELEVATOR ADDITION. - Gruber Wagon Works, Pennsylvania Route 183 & State Hill Road at Red Bridge Park, Bernville, Berks County, PA

30 CFR 77.208 - Storage of materials.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Storage of materials. 77.208 Section 77.208 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH... Installations § 77.208 Storage of materials. (a) Materials shall be stored and stacked in a manner which...

30 CFR 77.208 - Storage of materials.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Storage of materials. 77.208 Section 77.208 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH... Installations § 77.208 Storage of materials. (a) Materials shall be stored and stacked in a manner which...

Conceptual design report: Nuclear materials storage facility renovation. Part 6, Alternatives study

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1995-07-14

The Nuclear Materials Storage Facility (NMSF) at the Los Alamos National Laboratory (LANL) was a Fiscal Year (FY) 1984 line-item project completed in 1987 that has never been operated because of major design and construction deficiencies. This renovation project, which will correct those deficiencies and allow operation of the facility, is proposed as an FY 97 line item. The mission of the project is to provide centralized intermediate and long-term storage of special nuclear materials (SNM) associated with defined LANL programmatic missions and to establish a centralized SNM shipping and receiving location for Technical Area (TA)-55 at LANL. Based onmore » current projections, existing storage space for SNM at other locations at LANL will be loaded to capacity by approximately 2002. This will adversely affect LANUs ability to meet its mission requirements in the future. The affected missions include LANL`s weapons research, development, and testing (WRD&T) program; special materials recovery; stockpile survelliance/evaluation; advanced fuels and heat sources development and production; and safe, secure storage of existing nuclear materials inventories. The problem is further exacerbated by LANL`s inability to ship any materials offsite because of the lack of receiver sites for material and regulatory issues. Correction of the current deficiencies and enhancement of the facility will provide centralized storage close to a nuclear materials processing facility. The project will enable long-term, cost-effective storage in a secure environment with reduced radiation exposure to workers, and eliminate potential exposures to the public. This report is organized according to the sections and subsections outlined by Attachment 111-2 of DOE Document AL 4700.1, Project Management System. It is organized into seven parts. This document, Part VI - Alternatives Study, presents a study of the different storage/containment options considered for NMSF.« less

Metal hydride-based thermal energy storage systems

DOEpatents

Vajo, John J.; Fang, Zhigang

2017-10-03

The invention provides a thermal energy storage system comprising a metal-containing first material with a thermal energy storage density of about 1300 kJ/kg to about 2200 kJ/kg based on hydrogenation; a metal-containing second material with a thermal energy storage density of about 200 kJ/kg to about 1000 kJ/kg based on hydrogenation; and a hydrogen conduit for reversibly transporting hydrogen between the first material and the second material. At a temperature of 20.degree. C. and in 1 hour, at least 90% of the metal is converted to the hydride. At a temperature of 0.degree. C. and in 1 hour, at least 90% of the metal hydride is converted to the metal and hydrogen. The disclosed metal hydride materials have a combination of thermodynamic energy storage densities and kinetic power capabilities that previously have not been demonstrated. This performance enables practical use of thermal energy storage systems for electric vehicle heating and cooling.

Optical response of photopolymer materials for holographic data storage applications.

PubMed

Sheridan, J T; Gleeson, M R; Close, C E; Kelly, J V

2007-01-01

We briefly review the application of photopolymer recording materials in the area of holographic data storage. In particular we discuss the recent development of the Non-local Polymerisation Driven Diffusion model. Applying this model we develop simple first-order analytic expressions describing the spatial frequency response of photopolymer materials. The assumptions made in the derivation of these formulae are described and their ranges of validity are examined. The effects of particular physical parameters of a photopolymer on the material response are discussed.

A&M. Radioactive parts security storage area, heat removal storage casks. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

A&M. Radioactive parts security storage area, heat removal storage casks. Plan, section, and details. Ralph M. Parsons 1480-7 ANP/GE-3-720-S-1. Date: November 1958. Approved by INEEL Classification Office for public release. INEEL index no. 034-0720-60-693-107459 - Idaho National Engineering Laboratory, Test Area North, Scoville, Butte County, ID

30 CFR 57.6130 - Explosive material storage facilities.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Explosive material storage facilities. 57.6130 Section 57.6130 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND... Storage-Surface Only § 57.6130 Explosive material storage facilities. (a) Detonators and explosives shall...

30 CFR 57.6130 - Explosive material storage facilities.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Explosive material storage facilities. 57.6130 Section 57.6130 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND... Storage-Surface Only § 57.6130 Explosive material storage facilities. (a) Detonators and explosives shall...

Chemical hydrogen storage material property guidelines for automotive applications

NASA Astrophysics Data System (ADS)

Semelsberger, Troy A.; Brooks, Kriston P.

2015-04-01

Chemical hydrogen storage is the sought after hydrogen storage media for automotive applications because of the expected low pressure operation (<20 atm), moderate temperature operation (<200 °C), system gravimetric capacities (>0.05 kg H2/kgsystem), and system volumetric capacities (>0.05 kg H2/Lsystem). Currently, the primary shortcomings of chemical hydrogen storage are regeneration efficiency, fuel cost and fuel phase (i.e., solid or slurry phase). Understanding the required material properties to meet the DOE Technical Targets for Onboard Hydrogen Storage Systems is a critical knowledge gap in the hydrogen storage research community. This study presents a set of fluid-phase chemical hydrogen storage material property guidelines for automotive applications meeting the 2017 DOE technical targets. Viable material properties were determined using a boiler-plate automotive system design. The fluid-phase chemical hydrogen storage media considered in this study were neat liquids, solutions, and non-settling homogeneous slurries. Material properties examined include kinetics, heats of reaction, fuel-cell impurities, gravimetric and volumetric hydrogen storage capacities, and regeneration efficiency. The material properties, although not exhaustive, are an essential first step in identifying viable chemical hydrogen storage material properties-and most important, their implications on system mass, system volume and system performance.

30 CFR 56.6130 - Explosive material storage facilities.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Explosive material storage facilities. 56.6130 Section 56.6130 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND... Storage § 56.6130 Explosive material storage facilities. (a) Detonators and explosives shall be stored in...

30 CFR 56.6130 - Explosive material storage facilities.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Explosive material storage facilities. 56.6130 Section 56.6130 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND... Storage § 56.6130 Explosive material storage facilities. (a) Detonators and explosives shall be stored in...

Vascular plants of waste storage sites in the 200 areas of the Hanford reservation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Price, K.R.; Rickard, W.H.

1973-12-01

A brief accounting of terrestrial, riparian and semi-aquatic plants known to be associated with radioactive waste storage sites in the 200 Areas of the Hanford Reservation is given. In most cases the species are characteristic of those which generally inhabit the reservation, but some plants are restricted to specialized habitats provided by particular waste storage sites. It is impractical to list all species growing at each waste storage site because of seasonal variation and changes brought about by environmental management practices. An alpbabetical listing has been prepared with an example of where each species is known to occur. The listmore » will be updated as needed and expanded to include other waste storage areas. Plant specimens were collected during spring and fall when flowering material was available. Herbarium mounts were prepared of many specimens and have been retained as part of the Hanford Reservation herbarium collection. Identification to species level was made whenever possible. Color photographs of the specimen mounts are used as training aids and demonstration material by ARHCO Radiation Monitoring personnel. (auth)« less

Fluoride salts and container materials for thermal energy storage applications in the temperature range 973 to 1400 K

NASA Technical Reports Server (NTRS)

Misra, Ajay K.; Whittenberger, J. Daniel

1987-01-01

Multicomponent fluoride salt mixtures were characterized for use as latent heat of fusion heat storage materials in advanced solar dynamic space power systems with operating temperatures in the range of 973 to 1400 K. The melting points and eutectic composition for many systems with published phase diagrams were verified, and several new eutectic compositions were identified. Additionally, the heats of fusion of several binary and ternary eutectics and congruently melting intermediate compounds were measured by differential scanning calorimetry. The extent of corrosion of various metals by fluoride melts was estimated from thermodynamic considerations, and equilibrium conditions inside a containment vessel were calculated as functions of the initial moisture content of the salt and free volume above the molten salt. Preliminary experimental data on the corrosion of commercial, high-temperature alloys in LiF-19.5CaF2 and NaF-27CaF2-36MgF2 melts are presented and compared to the thermodynamic predictions.

48 CFR 36.510 - Operations and storage areas.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 48 Federal Acquisition Regulations System 1 2012-10-01 2012-10-01 false Operations and storage... Operations and storage areas. The contracting officer shall insert the clause at 52.236-10, Operations ald Storage Areas, in solicitations and contracts when a fixed-price construction contract or a fixed-price...

48 CFR 36.510 - Operations and storage areas.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 48 Federal Acquisition Regulations System 1 2011-10-01 2011-10-01 false Operations and storage... Operations and storage areas. The contracting officer shall insert the clause at 52.236-10, Operations ald Storage Areas, in solicitations and contracts when a fixed-price construction contract or a fixed-price...

48 CFR 36.510 - Operations and storage areas.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 48 Federal Acquisition Regulations System 1 2013-10-01 2013-10-01 false Operations and storage... Operations and storage areas. The contracting officer shall insert the clause at 52.236-10, Operations ald Storage Areas, in solicitations and contracts when a fixed-price construction contract or a fixed-price...

Redox-active Hybrid Materials for Pseudocapacitive Energy Storage

NASA Astrophysics Data System (ADS)

Boota, Muhammad

Organic-inorganic hybrid materials show a great promise for the purpose of manufacturing high performance electrode materials for electrochemical energy storage systems and beyond. Molecular level combination of two best suited components in a hybrid material leads to new or sometimes exceptional sets of physical, chemical, mechanical and electrochemical properties that makes them attractive for broad ranges of applications. Recently, there has been growing interest in producing redox-active hybrid nanomaterials for energy storage applications where generally the organic component provides high redox capacitance and the inorganic component offers high conductivity and robust support. While organic-inorganic hybrid materials offer tremendous opportunities for electrochemical energy storage applications, the task of matching the right organic material out of hundreds of natural and nearly unlimited synthetic organic molecules to appropriate nanostructured inorganic support hampers their electrochemical energy storage applications. We aim to present the recent development of redox-active hybrid materials for pseudocapacitive energy storage. We will show the impact of combination of suitable organic materials with distinct carbon nanostructures and/or highly conductive metal carbides (MXenes) on conductivity, charge storage performance, and cyclability. Combined experimental and molecular simulation results will be discussed to shed light on the interfacial organic-inorganic interactions, pseudocapacitive charge storage mechanisms, and likely orientations of organic molecules on conductive supports. Later, the concept of all-pseudocapacitive organic-inorganic asymmetric supercapacitors will be highlighted which open up new avenues for developing inexpensive, sustainable, and high energy density aqueous supercapacitors. Lastly, future challenges and opportunities to further tailor the redox-active hybrids will be highlighted.

Chemical hydrogen storage material property guidelines for automotive applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Semelsberger, Troy; Brooks, Kriston P.

2015-04-01

Chemical hydrogen storage is the sought after hydrogen storage media for automotive applications because of the expected low pressure operation (<20 atm), moderate temperature operation (<200 C), system gravimetric capacities (>0.05 kg H2/kg system), and system volumetric capacities (>0.05 kg H2/L system). Currently, the primary shortcomings of chemical hydrogen storage are regeneration efficiency, fuel cost and fuel phase (i.e., solid or slurry phase). Understanding the required material properties to meet the DOE Technical Targets for Onboard Hydrogen Storage Systems is a critical knowledge gap in the hydrogen storage research community. This study presents a set of fluid-phase chemical hydrogen storagemore » material property guidelines for automotive applications meeting the 2017 DOE technical targets. Viable material properties were determined using a boiler-plate automotive system design. The fluid phase chemical hydrogen storage media considered in this study were neat liquids, solutions, and non-settling homogeneous slurries. Material properties examined include kinetics, heats of reaction, fuel-cell impurities, gravimetric and volumetric hydrogen storage capacities, and regeneration efficiency. The material properties, although not exhaustive, are an essential first step in identifying viable chemical hydrogen storage material propertiesdand most important, their implications on system mass, system volume and system performance.« less

Effect of different new packaging materials on biscuit quality during accelerated storage.

PubMed

Romani, Santina; Tappi, Silvia; Balestra, Federica; Rodriguez Estrada, Maria Teresa; Siracusa, Valentina; Rocculi, Pietro; Dalla Rosa, Marco

2015-06-01

The effect of innovative multilayer packaging materials versus a standard one on biscuit quality was studied during accelerated storage at 25, 35, 45 °C and 50% relative humidity for 92 days. Three different packaging materials were used: metalized orientated polypropylene (OPP)/paper (control); metalized poly-lactic acid (PLA)/paper; metalized OPP with ethylene vinyl acetate pro-oxidant additive (EVA-POA)/paper. EVA-POA additive is used to make the plastic layer biodegradable. Various quality sample parameters (moisture, water activity (aw ), texture, peroxide value (PV), hexanal) were analysed during storage. Rate constants (k) and activation energies (Ea ) of hydration reactions and hexanal formation were calculated. No remarkable differences in the evolution of primary and secondary lipid oxidation were observed among differently packed biscuits during storage. All samples maintained PV levels between 4 and 14 meq O2 kg(-1) oil. The product in flexible packaging with PLA reached the highest moisture and aw levels, but they did not significantly and adversely affect the other quality characteristics. The obtained results demonstrate that the new tested packaging materials were suitable for commercial biscuit storage, having similar performance and preservation effects on the overall product quality to those of the standard one. Furthermore, these results could make a contribution to the food industry, encouraging the use of packaging materials with a negligible environmental impact as an alternative to petroleum-based ones. © 2014 Society of Chemical Industry.

30 CFR 56.6102 - Explosive material storage practices.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Explosive material storage practices. 56.6102 Section 56.6102 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-SURFACE METAL AND NONMETAL MINES Explosives Storage § 56.6102 Explosive material storag...

30 CFR 56.6102 - Explosive material storage practices.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Explosive material storage practices. 56.6102 Section 56.6102 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-SURFACE METAL AND NONMETAL MINES Explosives Storage § 56.6102 Explosive material storag...

30 CFR 56.6102 - Explosive material storage practices.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Explosive material storage practices. 56.6102 Section 56.6102 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-SURFACE METAL AND NONMETAL MINES Explosives Storage § 56.6102 Explosive material storag...

48 CFR 52.236-10 - Operations and Storage Areas.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 48 Federal Acquisition Regulations System 2 2012-10-01 2012-10-01 false Operations and Storage....236-10 Operations and Storage Areas. As prescribed in 36.510, insert the following clause: Operations and Storage Areas (APR 1984) (a) The Contractor shall confine all operations (including storage of...

48 CFR 52.236-10 - Operations and Storage Areas.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 48 Federal Acquisition Regulations System 2 2011-10-01 2011-10-01 false Operations and Storage....236-10 Operations and Storage Areas. As prescribed in 36.510, insert the following clause: Operations and Storage Areas (APR 1984) (a) The Contractor shall confine all operations (including storage of...

48 CFR 52.236-10 - Operations and Storage Areas.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 48 Federal Acquisition Regulations System 2 2010-10-01 2010-10-01 false Operations and Storage....236-10 Operations and Storage Areas. As prescribed in 36.510, insert the following clause: Operations and Storage Areas (APR 1984) (a) The Contractor shall confine all operations (including storage of...

48 CFR 52.236-10 - Operations and Storage Areas.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 48 Federal Acquisition Regulations System 2 2013-10-01 2013-10-01 false Operations and Storage....236-10 Operations and Storage Areas. As prescribed in 36.510, insert the following clause: Operations and Storage Areas (APR 1984) (a) The Contractor shall confine all operations (including storage of...

48 CFR 52.236-10 - Operations and Storage Areas.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 48 Federal Acquisition Regulations System 2 2014-10-01 2014-10-01 false Operations and Storage....236-10 Operations and Storage Areas. As prescribed in 36.510, insert the following clause: Operations and Storage Areas (APR 1984) (a) The Contractor shall confine all operations (including storage of...

Hydrogen storage in engineered carbon nanospaces.

PubMed

Burress, Jacob; Kraus, Michael; Beckner, Matt; Cepel, Raina; Suppes, Galen; Wexler, Carlos; Pfeifer, Peter

2009-05-20

It is shown how appropriately engineered nanoporous carbons provide materials for reversible hydrogen storage, based on physisorption, with exceptional storage capacities (approximately 80 g H2/kg carbon, approximately 50 g H2/liter carbon, at 50 bar and 77 K). Nanopores generate high storage capacities (a) by having high surface area to volume ratios, and (b) by hosting deep potential wells through overlapping substrate potentials from opposite pore walls, giving rise to a binding energy nearly twice the binding energy in wide pores. Experimental case studies are presented with surface areas as high as 3100 m(2) g(-1), in which 40% of all surface sites reside in pores of width approximately 0.7 nm and binding energy approximately 9 kJ mol(-1), and 60% of sites in pores of width>1.0 nm and binding energy approximately 5 kJ mol(-1). The findings, including the prevalence of just two distinct binding energies, are in excellent agreement with results from molecular dynamics simulations. It is also shown, from statistical mechanical models, that one can experimentally distinguish between the situation in which molecules do (mobile adsorption) and do not (localized adsorption) move parallel to the surface, how such lateral dynamics affects the hydrogen storage capacity, and how the two situations are controlled by the vibrational frequencies of adsorbed hydrogen molecules parallel and perpendicular to the surface: in the samples presented, adsorption is mobile at 293 K, and localized at 77 K. These findings make a strong case for it being possible to significantly increase hydrogen storage capacities in nanoporous carbons by suitable engineering of the nanopore space.

Microencapsulated Phase-Change Materials For Storage Of Heat

NASA Technical Reports Server (NTRS)

Colvin, David P.

1989-01-01

Report describes research on engineering issues related to storage and transport of heat in slurries containing phase-change materials in microscopic capsules. Specific goal of project to develop lightweight, compact, heat-management systems used safely in inhabited areas of spacecraft. Further development of obvious potential of technology expected to lead to commercialization and use in aircraft, electronic equipment, machinery, industrial processes, and other sytems in which requirements for management of heat compete with severe restrictions on weight or volume.

K Basins sludge removal temporary sludge storage tank system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mclean, M.A.

1997-06-12

Shipment of sludge from the K Basins to a disposal site is now targeted for August 2000. The current path forward for sludge disposal is shipment to Tank AW-105 in the Tank Waste Remediation System (TWRS). Significant issues of the feasibility of this path exist primarily due to criticality concerns and the presence of polychlorinated biphenyls (PCBS) in the sludge at levels that trigger regulation under the Toxic Substance Control Act. Introduction of PCBs into the TWRS processes could potentially involve significant design and operational impacts to both the Spent Nuclear Fuel and TWRS projects if technical and regulatory issuesmore » related to PCB treatment cannot be satisfactorily resolved. Concerns of meeting the TWRS acceptance criteria have evolved such that new storage tanks for the K Basins sludge may be the best option for storage prior to vitrification of the sludge. A reconunendation for the final disposition of the sludge is scheduled for June 30, 1997. To support this decision process, this project was developed. This project provides a preconceptual design package including preconceptual designs and cost estimates for the temporary sludge storage tanks. Development of cost estimates for the design and construction of sludge storage systems is required to help evaluate a recommendation for the final disposition of the K Basin sludge.« less

Outlook and Challenges for Hydrogen Storage in Nanoporous Materials

DOE PAGES

Broom, D. P.; Webb, C. J.; Hurst, Katherine E.; ...

2016-02-16

Considerable progress has been made recently in the use of nanoporous materials for hydrogen storage. In our article, the current status of the field and future challenges are discussed, ranging from important open fundamental questions, such as the density and volume of the adsorbed phase and its relationship to overall storage capacity, to the development of new functional materials and complete storage system design. With regard to fundamentals, the use of neutron scattering to study adsorbed H 2, suitable adsorption isotherm equations, and the accurate computational modelling and simulation of H 2 adsorption are discussed. We cover new materials andmore » they include flexible metal–organic frameworks, core–shell materials, and porous organic cage compounds. The article concludes with a discussion of the experimental investigation of real adsorptive hydrogen storage tanks, the improvement in the thermal conductivity of storage beds, and new storage system concepts and designs.« less

High-temperature thermal storage systems for advanced solar receivers materials selections

NASA Astrophysics Data System (ADS)

Wilson, D. F.; Devan, J. H.; Howell, M.

1990-09-01

Advanced space power systems that use solar energy and Brayton or Stirling heat engines require thermal energy storage (TES) systems to operate continuously through periods of shade. The receiver storage units, key elements in both Brayton and Stirling systems, are designed to use the latent heat of fusion of phase-change materials (PCMs). The power systems under current consideration for near-future National Aeronautics and Space Administration space missions require working fluid temperatures in the 1100 to 1400 K range. The PCMs under current investigation that gave liquid temperatures within this range are the fluoride family of salts. However, these salts have low thermal conductivity, which causes large temperature gradients in the storage systems. Improvements can be obtained, however, with the use of thermal conductivity enhancements or metallic PCMs. In fact, if suitable containment materials can be found, the use of metallic PCMs would virtually eliminate the orbit associated temperature variations in TES systems. The high thermal conductivity and generally low volume change on melting of germanium and alloys based on silicon make them attractive for storage of thermal energy in space power systems. An approach to solving the containment problem, involving both chemical and physical compatibility, preparation of NiSi/NiSi2, and initial results for containment of germanium and NiSi/NiSi2, are presented.

High-temperature thermal storage systems for advanced solar receivers materials selections

NASA Technical Reports Server (NTRS)

Wilson, D. F.; Devan, J. H.; Howell, M.

1990-01-01

Advanced space power systems that use solar energy and Brayton or Stirling heat engines require thermal energy storage (TES) systems to operate continuously through periods of shade. The receiver storage units, key elements in both Brayton and Stirling systems, are designed to use the latent heat of fusion of phase-change materials (PCMs). The power systems under current consideration for near-future National Aeronautics and Space Administration space missions require working fluid temperatures in the 1100 to 1400 K range. The PCMs under current investigation that gave liquid temperatures within this range are the fluoride family of salts. However, these salts have low thermal conductivity, which causes large temperature gradients in the storage systems. Improvements can be obtained, however, with the use of thermal conductivity enhancements or metallic PCMs. In fact, if suitable containment materials can be found, the use of metallic PCMs would virtually eliminate the orbit associated temperature variations in TES systems. The high thermal conductivity and generally low volume change on melting of germanium and alloys based on silicon make them attractive for storage of thermal energy in space power systems. An approach to solving the containment problem, involving both chemical and physical compatibility, preparation of NiSi/NiSi2, and initial results for containment of germanium and NiSi/NiSi2, are presented.

High-performance colossal permittivity materials of (Nb + Er) co-doped TiO2 for large capacitors and high-energy-density storage devices.

PubMed

Tse, Mei-Yan; Wei, Xianhua; Hao, Jianhua

2016-09-21

The search for colossal permittivity (CP) materials is imperative because of their potential for promising applications in the areas of device miniaturization and energy storage. High-performance CP materials require high dielectric permittivity, low dielectric loss and relatively weak dependence of frequency- and temperature. In this work, we first investigate the CP behavior of rutile TiO2 ceramics co-doped with niobium and erbium, i.e., (Er0.5Nb0.5)xTi1-xO2. Excellent dielectric properties were observed in the materials, including a CP of up to 10(4)-10(5) and a low dielectric loss (tan δ) down to 0.03, which are lower than that of the previously reported co-doped TiO2 CP materials when measured at 1 kHz. Stabilities of frequency and temperature were also accomplished via doping Er and Nb. Valence states of the elements in the material were analyzed using X-ray photoelectron spectroscopy. The Er induced secondary phases were observed using elemental mapping and energy-dispersive spectrometry. Consequently, this work may provide comprehensive guidance to develop high-performance CP materials for fully solid-state capacitor and energy storage applications.

PNNL Development and Analysis of Material-Based Hydrogen Storage Systems for the Hydrogen Storage Engineering Center of Excellence

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brooks, Kriston P.; Alvine, Kyle J.; Johnson, Kenneth I.

The Hydrogen Storage Engineering Center of Excellence is a team of universities, industrial corporations, and federal laboratories with the mandate to develop lower-pressure, materials-based, hydrogen storage systems for hydrogen fuel cell light-duty vehicles. Although not engaged in the development of new hydrogen storage materials themselves, it is an engineering center that addresses engineering challenges associated with the currently available hydrogen storage materials. Three material-based approaches to hydrogen storage are being researched: 1) chemical hydrogen storage materials 2) cryo-adsorbents, and 3) metal hydrides. As a member of this Center, Pacific Northwest National Laboratory (PNNL) has been involved in the design andmore » evaluation of systems developed with each of these three hydrogen storage materials. This report is a compilation of the work performed by PNNL for this Center.« less

Rapid charging of thermal energy storage materials through plasmonic heating.

PubMed

Wang, Zhongyong; Tao, Peng; Liu, Yang; Xu, Hao; Ye, Qinxian; Hu, Hang; Song, Chengyi; Chen, Zhaoping; Shang, Wen; Deng, Tao

2014-09-01

Direct collection, conversion and storage of solar radiation as thermal energy are crucial to the efficient utilization of renewable solar energy and the reduction of global carbon footprint. This work reports a facile approach for rapid and efficient charging of thermal energy storage materials by the instant and intense photothermal effect of uniformly distributed plasmonic nanoparticles. Upon illumination with both green laser light and sunlight, the prepared plasmonic nanocomposites with volumetric ppm level of filler concentration demonstrated a faster heating rate, a higher heating temperature and a larger heating area than the conventional thermal diffusion based approach. With controlled dispersion, we further demonstrated that the light-to-heat conversion and thermal storage properties of the plasmonic nanocomposites can be fine-tuned by engineering the composition of the nanocomposites.

Rapid Charging of Thermal Energy Storage Materials through Plasmonic Heating

PubMed Central

Wang, Zhongyong; Tao, Peng; Liu, Yang; Xu, Hao; Ye, Qinxian; Hu, Hang; Song, Chengyi; Chen, Zhaoping; Shang, Wen; Deng, Tao

2014-01-01

Direct collection, conversion and storage of solar radiation as thermal energy are crucial to the efficient utilization of renewable solar energy and the reduction of global carbon footprint. This work reports a facile approach for rapid and efficient charging of thermal energy storage materials by the instant and intense photothermal effect of uniformly distributed plasmonic nanoparticles. Upon illumination with both green laser light and sunlight, the prepared plasmonic nanocomposites with volumetric ppm level of filler concentration demonstrated a faster heating rate, a higher heating temperature and a larger heating area than the conventional thermal diffusion based approach. With controlled dispersion, we further demonstrated that the light-to-heat conversion and thermal storage properties of the plasmonic nanocomposites can be fine-tuned by engineering the composition of the nanocomposites. PMID:25175717

From the surface to volume: concepts for the next generation of optical-holographic data-storage materials.

PubMed

Bruder, Friedrich-Karl; Hagen, Rainer; Rölle, Thomas; Weiser, Marc-Stephan; Fäcke, Thomas

2011-05-09

Optical data storage has had a major impact on daily life since its introduction to the market in 1982. Compact discs (CDs), digital versatile discs (DVDs), and Blu-ray discs (BDs) are universal data-storage formats with the advantage that the reading and writing of the digital data does not require contact and is therefore wear-free. These formats allow convenient and fast data access, high transfer rates, and electricity-free data storage with low overall archiving costs. The driving force for development in this area is the constant need for increased data-storage capacity and transfer rate. The use of holographic principles for optical data storage is an elegant way to increase the storage capacity and the transfer rate, because by this technique the data can be stored in the volume of the storage material and, moreover, it can be optically processed in parallel. This Review describes the fundamental requirements for holographic data-storage materials and compares the general concepts for the materials used. An overview of the performance of current read-write devices shows how far holographic data storage has already been developed. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

10 CFR 20.1802 - Control of material not in storage.

Code of Federal Regulations, 2014 CFR

2014-01-01

... 10 Energy 1 2014-01-01 2014-01-01 false Control of material not in storage. 20.1802 Section 20.1802 Energy NUCLEAR REGULATORY COMMISSION STANDARDS FOR PROTECTION AGAINST RADIATION Storage and Control of Licensed Material § 20.1802 Control of material not in storage. The licensee shall control and...

10 CFR 20.1802 - Control of material not in storage.

Code of Federal Regulations, 2011 CFR

2011-01-01

... 10 Energy 1 2011-01-01 2011-01-01 false Control of material not in storage. 20.1802 Section 20.1802 Energy NUCLEAR REGULATORY COMMISSION STANDARDS FOR PROTECTION AGAINST RADIATION Storage and Control of Licensed Material § 20.1802 Control of material not in storage. The licensee shall control and...

10 CFR 20.1802 - Control of material not in storage.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 10 Energy 1 2010-01-01 2010-01-01 false Control of material not in storage. 20.1802 Section 20.1802 Energy NUCLEAR REGULATORY COMMISSION STANDARDS FOR PROTECTION AGAINST RADIATION Storage and Control of Licensed Material § 20.1802 Control of material not in storage. The licensee shall control and...

10 CFR 20.1802 - Control of material not in storage.

Code of Federal Regulations, 2013 CFR

2013-01-01

... 10 Energy 1 2013-01-01 2013-01-01 false Control of material not in storage. 20.1802 Section 20.1802 Energy NUCLEAR REGULATORY COMMISSION STANDARDS FOR PROTECTION AGAINST RADIATION Storage and Control of Licensed Material § 20.1802 Control of material not in storage. The licensee shall control and...

10 CFR 20.1802 - Control of material not in storage.

Code of Federal Regulations, 2012 CFR

2012-01-01

... 10 Energy 1 2012-01-01 2012-01-01 false Control of material not in storage. 20.1802 Section 20.1802 Energy NUCLEAR REGULATORY COMMISSION STANDARDS FOR PROTECTION AGAINST RADIATION Storage and Control of Licensed Material § 20.1802 Control of material not in storage. The licensee shall control and...

Polyaniline as a material for hydrogen storage applications.

PubMed

Attia, Nour F; Geckeler, Kurt E

2013-07-12

The main challenge of commercialization of the hydrogen economy is the lack of convenient and safe hydrogen storage materials, which can adsorb and release a significant amount of hydrogen at ambient conditions. Finding and designing suitable cost-effective materials are vital requirements to overcome the drawbacks of investigated materials. Because of its outstanding electronic, thermal, and chemical properties, the electrically conducting polyaniline (PANI) has a high potential in hydrogen storage applications. In this review, the progress in the use of different structures of conducting PANI, its nanocomposites as well as activated porous materials based on PANI as hydrogen storage materials is presented and discussed. The effect of the unique electronic properties based on the π-electron system in the backbone of these materials in view of the hydrogen uptake and the relevant mechanisms are highlighted. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

High-capacity electrode materials for electrochemical energy storage: Role of nanoscale effects

DOE PAGES

Nanda, Jagjit; Martha, Surendra K.; Kalyanaraman, Ramki

2015-06-02

In this review, we summarize the current state-of-the art electrode materials used for high-capacity lithium-ion-based batteries and their significant role towards revolutionizing the electrochemical energy storage landscape in the area of consumer electronics, transportation and grid storage application. We discuss the role of nanoscale effects on the electrochemical performance of high-capacity battery electrode materials. Decrease in the particle size of the primary electrode materials from micron to nanometre size improves the ionic and electronic diffusion rates significantly. Nanometre-thick solid electrolyte (such as lithium phosphorous oxynitride) and oxides (such as Al 2O 3, ZnO, TiO 2 etc.) material coatings also improvemore » the interfacial stability and rate capability of a number of battery chemistries. Finally, we elucidate these effects in terms of different high-capacity battery chemistries based on intercalation and conversion mechanism.« less

Carbon Storage in Urban Areas in the USA

NASA Astrophysics Data System (ADS)

Churkina, G.; Brown, D.; Keoleian, G.

2007-12-01

It is widely accepted that human settlements occupy a small proportion of the landmass and therefore play a relatively small role in the dynamics of the global carbon cycle. Most modeling studies focusing on the land carbon cycle use models of varying complexity to estimate carbon fluxes through forests, grasses, and croplands, but completely omit urban areas from their scope. Here, we estimate carbon storage in urban areas within the United States, defined to encompass a range of observed settlement densities, and its changes from 1950 to 2000. We show that this storage is not negligible and has been continuously increasing. We include natural- and human-related components of urban areas in our estimates. The natural component includes carbon storage in urban soil and vegetation. The human related component encompasses carbon stored long term in buildings, furniture, cars, and waste. The study suggests that urban areas should receive continued attention in efforts to accurately account for carbon uptake and storage in terrestrial systems.

Sol-gel Technology and Advanced Electrochemical Energy Storage Materials

NASA Technical Reports Server (NTRS)

Chu, Chung-tse; Zheng, Haixing

1996-01-01

Advanced materials play an important role in the development of electrochemical energy devices such as batteries, fuel cells, and electrochemical capacitors. The sol-gel process is a versatile solution for use in the fabrication of ceramic materials with tailored stoichiometry, microstructure, and properties. This processing technique is particularly useful in producing porous materials with high surface area and low density, two of the most desirable characteristics for electrode materials. In addition,the porous surface of gels can be modified chemically to create tailored surface properties, and inorganic/organic micro-composites can be prepared for improved material performance device fabrication. Applications of several sol-gel derived electrode materials in different energy storage devices are illustrated in this paper. V2O5 gels are shown to be a promising cathode material for solid state lithium batteries. Carbon aerogels, amorphous RuO2 gels and sol-gel derived hafnium compounds have been studied as electrode materials for high energy density and high power density electrochemical capacitors.

High-pressure torsion for new hydrogen storage materials.

PubMed

Edalati, Kaveh; Akiba, Etsuo; Horita, Zenji

2018-01-01

High-pressure torsion (HPT) is widely used as a severe plastic deformation technique to create ultrafine-grained structures with promising mechanical and functional properties. Since 2007, the method has been employed to enhance the hydrogenation kinetics in different Mg-based hydrogen storage materials. Recent studies showed that the method is effective not only for increasing the hydrogenation kinetics but also for improving the hydrogenation activity, for enhancing the air resistivity and more importantly for synthesizing new nanostructured hydrogen storage materials with high densities of lattice defects. This manuscript reviews some major findings on the impact of HPT process on the hydrogen storage performance of different titanium-based and magnesium-based materials.

High capacity hydrogen storage nanocomposite materials

DOEpatents

Zidan, Ragaiy; Wellons, Matthew S.

2017-12-12

A novel hydrogen absorption material is provided comprising a mixture of a lithium hydride with a fullerene. The subsequent reaction product provides for a hydrogen storage material which reversibly stores and releases hydrogen at temperatures of about 270.degree. C.

High capacity hydrogen storage nanocomposite materials

DOEpatents

Zidan, Ragaiy; Wellons, Matthew S

2015-02-03

A novel hydrogen absorption material is provided comprising a mixture of a lithium hydride with a fullerene. The subsequent reaction product provides for a hydrogen storage material which reversibly stores and releases hydrogen at temperatures of about 270.degree. C.

In silico design of porous polymer networks: high-throughput screening for methane storage materials.

PubMed

Martin, Richard L; Simon, Cory M; Smit, Berend; Haranczyk, Maciej

2014-04-02

Porous polymer networks (PPNs) are a class of advanced porous materials that combine the advantages of cheap and stable polymers with the high surface areas and tunable chemistry of metal-organic frameworks. They are of particular interest for gas separation or storage applications, for instance, as methane adsorbents for a vehicular natural gas tank or other portable applications. PPNs are self-assembled from distinct building units; here, we utilize commercially available chemical fragments and two experimentally known synthetic routes to design in silico a large database of synthetically realistic PPN materials. All structures from our database of 18,000 materials have been relaxed with semiempirical electronic structure methods and characterized with Grand-canonical Monte Carlo simulations for methane uptake and deliverable (working) capacity. A number of novel structure-property relationships that govern methane storage performance were identified. The relationships are translated into experimental guidelines to realize the ideal PPN structure. We found that cooperative methane-methane attractions were present in all of the best-performing materials, highlighting the importance of guest interaction in the design of optimal materials for methane storage.

Hydrogen storage materials and method of making by dry homogenation

DOEpatents

Jensen, Craig M.; Zidan, Ragaiy A.

2002-01-01

Dry homogenized metal hydrides, in particular aluminum hydride compounds, as a material for reversible hydrogen storage is provided. The reversible hydrogen storage material comprises a dry homogenized material having transition metal catalytic sites on a metal aluminum hydride compound, or mixtures of metal aluminum hydride compounds. A method of making such reversible hydrogen storage materials by dry doping is also provided and comprises the steps of dry homogenizing metal hydrides by mechanical mixing, such as be crushing or ball milling a powder, of a metal aluminum hydride with a transition metal catalyst. In another aspect of the invention, a method of powering a vehicle apparatus with the reversible hydrogen storage material is provided.

Composite materials for thermal energy storage

DOEpatents

Benson, David K.; Burrows, Richard W.; Shinton, Yvonne D.

1986-01-01

The present invention discloses composite material for thermal energy storage based upon polyhydric alcohols, such as pentaerythritol, trimethylol ethane (also known as pentaglycerine), neopentyl glycol and related compounds including trimethylol propane, monoaminopentaerythritol, diamino-pentaerythritol and tris(hydroxymethyl)acetic acid, separately or in combinations, which provide reversible heat storage through crystalline phase transformations. These phase change materials do not become liquid during use and are in contact with at least one material selected from the group consisting of metals, carbon siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, porous rock, and mixtures thereof. Particulate additions, such as aluminum or graphite powders, as well as metal and carbon fibers can also be incorporated therein. Particulate and/or fibrous additions can be introduced into molten phase change materials which can then be cast into various shapes. After the phase change materials have solidified, the additions will remain dispersed throughout the matrix of the cast solid. The polyol is in contact with at least one material selected from the group consisting of metals, carbon siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, and mixtures thereof.

Carbon-Based Functional Materials Derived from Waste for Water Remediation and Energy Storage.

PubMed

Ma, Qinglang; Yu, Yifu; Sindoro, Melinda; Fane, Anthony G; Wang, Rong; Zhang, Hua

2017-04-01

Carbon-based functional materials hold the key for solving global challenges in the areas of water scarcity and the energy crisis. Although carbon nanotubes (CNTs) and graphene have shown promising results in various fields of application, their high preparation cost and low production yield still dramatically hinder their wide practical applications. Therefore, there is an urgent call for preparing carbon-based functional materials from low-cost, abundant, and sustainable sources. Recent innovative strategies have been developed to convert various waste materials into valuable carbon-based functional materials. These waste-derived carbon-based functional materials have shown great potential in many applications, especially as sorbents for water remediation and electrodes for energy storage. Here, the research progress in the preparation of waste-derived carbon-based functional materials is summarized, along with their applications in water remediation and energy storage; challenges and future research directions in this emerging research field are also discussed. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

New perspectives on potential hydrogen storage materials using high pressure.

PubMed

Song, Yang

2013-09-21

In addressing the global demand for clean and renewable energy, hydrogen stands out as the most suitable candidate for many fuel applications that require practical and efficient storage of hydrogen. Supplementary to the traditional hydrogen storage methods and materials, the high-pressure technique has emerged as a novel and unique approach to developing new potential hydrogen storage materials. Static compression of materials may result in significant changes in the structures, properties and performance that are important for hydrogen storage applications, and often lead to the formation of unprecedented phases or complexes that have profound implications for hydrogen storage. In this perspective article, 22 types of representative potential hydrogen storage materials that belong to four major classes--simple hydride, complex hydride, chemical hydride and hydrogen containing materials--were reviewed. In particular, their structures, stabilities, and pressure-induced transformations, which were reported in recent experimental works together with supporting theoretical studies, were provided. The important contextual aspects pertinent to hydrogen storage associated with novel structures and transitions were discussed. Finally, the summary of the recent advances reviewed and the insight into the future research in this direction were given.

High-pressure torsion for new hydrogen storage materials

PubMed Central

Edalati, Kaveh; Akiba, Etsuo; Horita, Zenji

2018-01-01

Abstract High-pressure torsion (HPT) is widely used as a severe plastic deformation technique to create ultrafine-grained structures with promising mechanical and functional properties. Since 2007, the method has been employed to enhance the hydrogenation kinetics in different Mg-based hydrogen storage materials. Recent studies showed that the method is effective not only for increasing the hydrogenation kinetics but also for improving the hydrogenation activity, for enhancing the air resistivity and more importantly for synthesizing new nanostructured hydrogen storage materials with high densities of lattice defects. This manuscript reviews some major findings on the impact of HPT process on the hydrogen storage performance of different titanium-based and magnesium-based materials. PMID:29511396

Parallel algorithms for islanded microgrid with photovoltaic and energy storage systems planning optimization problem: Material selection and quantity demand optimization

NASA Astrophysics Data System (ADS)

Cao, Yang; Liu, Chun; Huang, Yuehui; Wang, Tieqiang; Sun, Chenjun; Yuan, Yue; Zhang, Xinsong; Wu, Shuyun

2017-02-01

With the development of roof photovoltaic power (PV) generation technology and the increasingly urgent need to improve supply reliability levels in remote areas, islanded microgrid with photovoltaic and energy storage systems (IMPE) is developing rapidly. The high costs of photovoltaic panel material and energy storage battery material have become the primary factors that hinder the development of IMPE. The advantages and disadvantages of different types of photovoltaic panel materials and energy storage battery materials are analyzed in this paper, and guidance is provided on material selection for IMPE planners. The time sequential simulation method is applied to optimize material demands of the IMPE. The model is solved by parallel algorithms that are provided by a commercial solver named CPLEX. Finally, to verify the model, an actual IMPE is selected as a case system. Simulation results on the case system indicate that the optimization model and corresponding algorithm is feasible. Guidance for material selection and quantity demand for IMPEs in remote areas is provided by this method.

Computational Design of Non-natural Sugar Alcohols to Increase Thermal Storage Density: Beyond Existing Organic Phase Change Materials.

PubMed

Inagaki, Taichi; Ishida, Toyokazu

2016-09-14

Thermal storage, a technology that enables us to control thermal energy, makes it possible to reuse a huge amount of waste heat, and materials with the ability to treat larger thermal energy are in high demand for energy-saving societies. Sugar alcohols are now one promising candidate for phase change materials (PCMs) because of their large thermal storage density. In this study, we computationally design experimentally unknown non-natural sugar alcohols and predict their thermal storage density as a basic step toward the development of new high performance PCMs. The non-natural sugar alcohol molecules are constructed in silico in accordance with the previously suggested molecular design guidelines: linear elongation of a carbon backbone, separated distribution of OH groups, and even numbers of carbon atoms. Their crystal structures are then predicted using the random search method and first-principles calculations. Our molecular simulation results clearly demonstrate that the non-natural sugar alcohols have potential ability to have thermal storage density up to ∼450-500 kJ/kg, which is significantly larger than the maximum thermal storage density of the present known organic PCMs (∼350 kJ/kg). This computational study suggests that, even in the case of H-bonded molecular crystals where the electrostatic energy contributes mainly to thermal storage density, the molecular distortion and van der Waals energies are also important factors to increase thermal storage density. In addition, the comparison between the three eight-carbon non-natural sugar alcohol isomers indicates that the selection of preferable isomers is also essential for large thermal storage density.

Enhancing pseudocapacitive charge storage in polymer templated mesoporous materials.

PubMed

Rauda, Iris E; Augustyn, Veronica; Dunn, Bruce; Tolbert, Sarah H

2013-05-21

layers of cathode or anode materials that occurs as batteries charge and discharge. Electrochemical analysis of these mesoporous films allows for a detailed understanding of the origin of charge storage by separating capacitive contributions from traditional diffusion-controlled intercalation processes. We also discuss methods to separate the two contributions to capacitance: double-layer capacitance and pseudocapacitance. Understanding these contributions should allow the selection of materials with an optimized architecture that maximize the contribution from pseudocapacitance. From our studies, we show that nanocrystal-based nanoporous materials offer an architecture optimized for high levels of redox or surface pseudocapacitance. Interestingly, in some cases, materials engineered to minimize the strain associated with lithium insertion can also show intercalation pseudocapacitance, which is a process where insertion processes become so kinetically facile that they appear capacitive. Finally, we conclude with a summary of simple design rules that should result in high-power, high-energy-density electrode architectures. These design rules include assembling small, nanosized building blocks to maximize electrode surface area; maintaining an interconnected, open mesoporosity to facilitate solvent diffusion; seeking flexibility in electrode structure to facilitate volume expansion during lithium insertion; optimizing crystalline domain size and orientation; and creating effective electron transport pathways.

Composite materials for thermal energy storage

NASA Astrophysics Data System (ADS)

Benson, D. K.; Burrows, R. W.; Shinton, Y. D.

1985-01-01

A composite material for thermal energy storage based upon polyhydric alcohols, such as pentaerythritol, trimethylol ethane (also known as pentaglycerine), neopentyl glycol and related compounds including trimethylol propane, monoaminopentaerythritol, diamino-pentaerythritol and tris(hydroxymethyl)acetic acid, separately or in combinations, which provide reversible heat storage through crystalline phase transformations are discussed. These PCM's do not become liquid during use and are in contact with at least one material selected from the group consisting of metals, carbon, siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, porous rock, and mixtures thereof. Particulate additions such as aluminum or graphite powders, as well as metal and carbon fibers can also be incorporated therein. Particulate and/or fibrous additions can be introduced into molten phase change materials which can then be cast into various shapes. After the phase change materials have solidified, the additions will remain dispersed throughout the matrix of the cast solid. The polyol is in contact with at least one material selected from the group consisting of metals, carbon, siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, and mixtures thereof.

Composite materials for thermal energy storage

DOEpatents

Benson, D.K.; Burrows, R.W.; Shinton, Y.D.

1985-01-04

A composite material for thermal energy storage based upon polyhydric alcohols, such as pentaerythritol, trimethylol ethane (also known as pentaglycerine), neopentyl glycol and related compounds including trimethylol propane, monoaminopentaerythritol, diamino-pentaerythritol and tris(hydroxymethyl)acetic acid, separately or in combinations, which provide reversible heat storage through crystalline phase transformations. These PCM's do not become liquid during use and are in contact with at least one material selected from the group consisting of metals, carbon, siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, porous rock, and mixtures thereof. Particulate additions such as aluminum or graphite powders, as well as metal and carbon fibers can also be incorporated therein. Particulate and/or fibrous additions can be introduced into molten phase change materials which can then be cast into various shapes. After the phase change materials have solidified, the additions will remain dispersed throughout the matrix of the cast solid. The polyol is in contact with at least one material selected from the group consisting of metals, carbon, siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, and mixtures thereof.

High-temperature molten salt thermal energy storage systems

NASA Technical Reports Server (NTRS)

Petri, R. J.; Claar, T. D.; Tison, R. R.; Marianowski, L. G.

1980-01-01

The results of comparative screening studies of candidate molten carbonate salts as phase change materials (PCM) for advanced solar thermal energy storage applications at 540 to 870 C (1004 to 1600 F) and steam Rankine electric generation at 400 to 540 C (752 to 1004 F) are presented. Alkali carbonates are attractive as latent heat storage materials because of their relatively high storage capacity and thermal conductivity, low corrosivity, moderate cost, and safe and simple handling requirements. Salts were tested in 0.1 kWhr lab scale modules and evaluated on the basis of discharge heat flux, solidification temperature range, thermal cycling stability, and compatibility with containment materials. The feasibility of using a distributed network of high conductivity material to increase the heat flux through the layer of solidified salt was evaluated. The thermal performance of an 8 kWhr thermal energy storage (TES) module containing LiKCO3 remained very stable throughout 5650 hours and 130 charge/discharge cycles at 480 to 535 C (896 to 995 F). A TES utilization concept of an electrical generation peaking subsystem composed of a multistage condensing steam turbine and a TES subsystem with a separate power conversion loop was defined. Conceptual designs for a 100 MW sub e TES peaking system providing steam at 316 C, 427 C, and 454 C (600 F, 800 F, and 850 F) at 3.79 million Pa (550 psia) were developed and evaluated. Areas requiring further investigation have also been identified.

Thermal performance analysis of a thermocline thermal energy storage system with FLiNaK molten salt

NASA Astrophysics Data System (ADS)

Liu, C.; Cheng, M. S.; Zhao, B. C.; Dai, Z. M.

2017-01-01

A thermocline thermal storage unit with a heat transfer fluid (HTF) of high-temperature molten salt is considered as one of the most promising methods of thermal storage due to its lower cost and smaller size. The main objective of this work is to analyze the transient behavior of the available molten salt FLiNaK used as the HTF in heat transfer and heat storage in a thermocline thermal energy storage (TES) system. Thermal characteristics including temperature profiles influenced by different inlet velocities of HTF and different void fractions of porous heat storage medium are analyzed. The numerical investigation on the heat storage and heat transfer characteristics of FLiINaK has been carried out. A comparison between two different molten salts, FLiNaK and Hitec, has been explored in this paper with regards to their charging and discharging operations. The results indicate the system with FLiNaK has a greater energy storage capability, a shorter charging time and a higher output power. The numerical investigation reveals heat storage and heat transfer characteristics of the thermocline TES system with FLiNaK, and provide important references for molten salt selection of the TES system in the future.

Using Encapsulated Phase Change Material in Thermal Energy Storage for Baseload Concentrating Solar Power (EPCM-TES)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mathur, Anoop

2013-12-15

Terrafore successfully demonstrated and optimized the manufacturing of capsules containing phase-changing inorganic salts. The phase change was used to store thermal energy collected from a concentrating solar-power plant as latent heat. This latent heat, in addition to sensible heat increased the energy density (energy stored per unit weight of salt) by over 50%, thus requiring 40% less salt and over 60% less capsule container. Therefore, the cost to store high-temperature thermal energy collected in a concentrating solar power plant will be reduced by almost 40% or more, as compared to conventional two-tank, sensible-only storage systems. The cost for thermal energymore » storage (TES) system is expected to achieve the Sun Shot goal of $15 per kWh(t). Costs associated with poor heat-transfer in phase change materials (PCM) were also eliminated. Although thermal energy storage that relies on the latent heat of fusion of PCM improves energy density by as much as 50%, upon energy discharge the salt freezes and builds on the heat transfer surfaces. Since these salts have low thermal conductivity, large heat-transfer areas, or larger conventional heat-exchangers are needed, which increases costs. By encapsulating PCM in small capsules we have increased the heat transfer area per unit volume of salt and brought the heat transfer fluid in direct contact with the capsules. These two improvements have increased the heat transfer coefficient and boosted heat transfer. The program was successful in overcoming the phenomenon of melt expansion in the capsules, which requires the creation of open volume in the capsules or shell to allow for expansion of the molten salt on melting and is heated above its melting point to 550°C. Under contract with the Department of Energy, Terrafore Inc. and Southwest Research Institute, developed innovative method(s) to economically create the open volume or void in the capsule. One method consists of using a sacrificial polymer coating as

The Use of Sodium Chloride & Aluminum as Phase Change Materials for High Temperature Thermal Energy Storage Characterized by Calorimetry

NASA Astrophysics Data System (ADS)

Solomon, Laura

2013-01-01

Encapsulated phase change materials (EPCM) have a great deal of potential for the storage of thermal energy in a wide range of applications. The present work is aimed at developing encapsulated phase change materials capable of storing thermal energy at temperatures above 700°C for use in concentrated solar power (CSP) systems. EPCM with a phase change material (PCM) with both a salt (sodium chloride) and a metal (aluminum) are considered here. Sodium chloride and aluminum are effective storage mediums because of their high melting points and large latent heats of fusion, 800°C and 660°C and 430kJ/kg and 397kJ/kg, respectively. Based on the heat capacities and the latent heat of fusion, for a 100 degree temperature range centered on the melting point of the PCM, 80% of the energy stored by the sodium chloride PCM can be attributed to the latent heat and 79% for the aluminum PCM. These large fractions attributed to latent heat have the potential for making EPCM based thermal energy storage devices smaller and less expensive. To study the performance of the candidate PCMs considered here, a specialized immersion calorimeter was designed, calibrated, and used to evaluate the storage capabilities of sodium chloride and aluminum based EPCMs. Additionally, the EPCMs were studied to ensure no loss of capacity would occur over the lifetime of the EPCM. While no reduction in the storage capacity of the sodium chloride EPCMs was found after repeated thermal cycles, there was a decrease in the storage capacity of the aluminum EPCMs after prolonged exposure to high temperatures.

Phase, microstructure and hydrogen storage properties of Mg-Ni materials synthesized from metal nanoparticles.

PubMed

Shao, Huaiyu; Chen, Chunguang; Liu, Tong; Li, Xingguo

2014-04-04

After Mg and Ni nanoparticles were fabricated by hydrogen plasma metal reaction, Mg-rich MgxNi₁₀₀₋x(75 < x < 90) materials were synthesized from these metal nanoparticles to study the synergistic effects for hydrogen storage in these samples to show both good kinetics and high capacity. These MgxNi₁₀₀₋x materials may absorb hydrogen with a capacity of around 3.3-5.1 wt% in 1 min at 573 K. The Mg₉₀Ni₁₀ sample shows a hydrogen capacity of 6.1 wt%. The significant kinetic enhancement is thought to be due to the unique nanostructure from the special synthesis route, the catalytic effect of the Mg₂Ni nano phase, and the synergistic effects between the Mg₂Ni and Mg phases in the materials. An interesting phenomenon which has never been reported before was observed during pressure composition isotherm (PCT) measurements. One steep step in the absorption process and two obviously separated steps in the desorption process during PCT measurements of Mg₈₀Ni₂₀ and Mg₉₀Ni₁₀ samples were observed and a possible reason from the kinetic performance of the Mg₂Ni and Mg phases in absorption and desorption processes was explained. These MgxNi₁₀₀₋x materials synthesized from Mg and Ni nanoparticles show high capacity and good kinetics, which makes these materials very promising candidates for thermal storage or energy storage and utilization for renewable power.

Analysis of Ignition Testing on K-West Basin Fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

J. Abrefah; F.H. Huang; W.M. Gerry

Approximately 2100 metric tons of spent nuclear fuel (SNF) discharged from the N-Reactor have been stored underwater at the K-Basins in the 100 Area of the Hanford Site. The spent fuel has been stored in the K-East Basin since 1975 and in the K-West Basin since 1981. Some of the SNF elements in these basins have corroded because of various breaches in the Zircaloy cladding that occurred during fuel discharge operations and/or subsequent handling and storage in the basins. Consequently, radioactive material in the fuel has been released into the basin water, and water has leaked from the K-East Basinmore » into the soil below. To protect the Columbia River, which is only 380 m from the basins, the SNF is scheduled to be removed and transported for interim dry storage in the 200 East Area, in the central portion of the Site. However, before being shipped, the corroded fuel elements will be loaded into Multi-Canister OverPacks and conditioned. The conditioning process will be selected based on the Integrated Process Strategy (IPS) (WHC 1995), which was prepared on the basis of the dry storage concept developed by the Independent Technical Assessment (ITA) team (ITA 1994).« less

Phase change material for temperature control and material storage

NASA Technical Reports Server (NTRS)

Wessling, Jr., Francis C. (Inventor); Blackwood, James M. (Inventor)

2011-01-01

A phase change material comprising a mixture of water and deuterium oxide is described, wherein the mole fraction of deuterium oxide is selected so that the mixture has a selected phase change temperature within a range between 0.degree. C. and 4.degree. C. The mixture is placed in a container and used for passive storage and transport of biomaterials and other temperature sensitive materials. Gels, nucleating agents, freezing point depression materials and colorants may be added to enhance the characteristics of the mixture.

FeOx‐Based Materials for Electrochemical Energy Storage

PubMed Central

Ma, Jingyi; Guo, Xiaotian; Yan, Yan; Xue, Huaiguo

2018-01-01

Abstract Iron oxides (FeOx), such as Fe2O3 and Fe3O4 materials, have attracted much attention because of their rich abundance, low cost, and environmental friendliness. However, FeOx, which is similar to most transition metal oxides, possesses a poor rate capability and cycling life. Thus, FeOx‐based materials consisting of FeOx, carbon, and metal‐based materials have been widely explored. This article mainly discusses FeOx‐based materials (Fe2O3 and Fe3O4) for electrochemical energy storage applications, including supercapacitors and rechargeable batteries (e.g., lithium‐ion batteries and sodium‐ion batteries). Furthermore, future perspectives and challenges of FeOx‐based materials for electrochemical energy storage are briefly discussed.

NREL's Energy Storage and REopt Teams Awarded $525k from TCF to Study

Science.gov Websites

Commercial Viability of Optimal, Reliable Building-Integrated Energy Storage | News | NREL NREL's Energy Storage and REopt Teams Awarded $525k from TCF to Study Commercial Viability of Optimal Study Commercial Viability of Optimal, Reliable Building-Integrated Energy Storage November 14, 2017

A&M. Radioactive parts security storage area. camera facing northwest. Outdoor ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

A&M. Radioactive parts security storage area. camera facing northwest. Outdoor storage of concrete storage casks. Photographer: M. Holmes. Date: November 21, 1959. INEEL negative no. 59-6081 - Idaho National Engineering Laboratory, Test Area North, Scoville, Butte County, ID

Embedding solar cell materials with on-board integrated energy storage for load-leveling and dark power delivery (Presentation Recording)

NASA Astrophysics Data System (ADS)

Pint, Cary L.; Westover, Andrew S.; Cohn, Adam P.; Erwin, William R.; Share, Keith; Metke, Thomas; Bardhan, Rizia

2015-10-01

This work will discuss our recent advances focused on integrating high power energy storage directly into the native materials of both conventional photovoltaics (PV) and dye-sensitized solar cells (DSSCs). In the first case (PV), we demonstrate the ability to etch high surface-area porous silicon charge storage interfaces directly into the backside of a conventional polycrystalline silicon photovoltaic device exhibiting over 14% efficiency. These high surface area materials are then coupled with solid-state ionic liquid-polymer electrolytes to produce solid-state fully integrated devices where the PV device can directly inject charge into an on-board supercapacitor that can be separately discharged under dark conditions with a Coulombic efficiency of 84%. In a similar manner, we further demonstrate that surface engineered silicon materials can be utilized to replace Pt counterelectrodes in conventional DSSC energy conversion devices. As the silicon counterelectrodes rely strictly on surface Faradaic chemical reactions with the electrolyte on one side of the wafer electrode, we demonstrate double-sided processing of electrodes that enables dual-function of the material for simultaneous energy storage and conversion, each on opposing sides. In both of these devices, we demonstrate the ability to produce an all-silicon coupled energy conversion and storage system through the common ability to convert unused silicon in solar cells into high power silicon-based supercapacitors. Beyond the proof-of-concept design and performance of this integrated solar-storage system, this talk will conclude with a brief discussion of the hurdles and challenges that we envision for this emerging area both from a fundamental and technological viewpoint.

76. VIEW OF SECOND WEAPONS STORAGE AREA ALONG SERVICE ROAD ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

76. VIEW OF SECOND WEAPONS STORAGE AREA ALONG SERVICE ROAD SHOWING BUILDINGS 338-333 LOOKING NORTHWEST. - Loring Air Force Base, Weapons Storage Area, Northeastern corner of base at northern end of Maine Road, Limestone, Aroostook County, ME

Microwave impregnation of porous materials with thermal energy storage materials

DOEpatents

Benson, D.K.; Burrows, R.W.

1993-04-13

A method for impregnating a porous, non-metallic construction material with a solid phase-change material is described. The phase-change material in finely divided form is spread onto the surface of the porous material, after which the porous material is exposed to microwave energy for a time sufficient to melt the phase-change material. The melted material is spontaneously absorbed into the pores of the porous material. A sealing chemical may also be included with the phase-change material (or applied subsequent to the phase-change material) to seal the surface of the porous material. Fire retardant chemicals may also be included with the phase-change materials. The treated construction materials are better able to absorb thermal energy and exhibit increased heat storage capacity.

Microwave impregnation of porous materials with thermal energy storage materials

DOEpatents

Benson, David K.; Burrows, Richard W.

1993-01-01

A method for impregnating a porous, non-metallic construction material with a solid phase-change material is described. The phase-change material in finely divided form is spread onto the surface of the porous material, after which the porous material is exposed to microwave energy for a time sufficient to melt the phase-change material. The melted material is spontaneously absorbed into the pores of the porous material. A sealing chemical may also be included with the phase-change material (or applied subsequent to the phase-change material) to seal the surface of the porous material. Fire retardant chemicals may also be included with the phase-change materials. The treated construction materials are better able to absorb thermal energy and exhibit increased heat storage capacity.

40 CFR 267.173 - What standards apply to the container storage areas?

Code of Federal Regulations, 2010 CFR

2010-07-01

... storage areas? 267.173 Section 267.173 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... container storage areas? (a) You must design and operate a containment system for your container storage areas according to the requirements in paragraph (b) of this section, except as otherwise provided by...

Reversible hydrogen storage materials

DOEpatents

Ritter, James A [Lexington, SC; Wang, Tao [Columbia, SC; Ebner, Armin D [Lexington, SC; Holland, Charles E [Cayce, SC

2012-04-10

In accordance with the present disclosure, a process for synthesis of a complex hydride material for hydrogen storage is provided. The process includes mixing a borohydride with at least one additive agent and at least one catalyst and heating the mixture at a temperature of less than about 600.degree. C. and a pressure of H.sub.2 gas to form a complex hydride material. The complex hydride material comprises MAl.sub.xB.sub.yH.sub.z, wherein M is an alkali metal or group IIA metal, Al is the element aluminum, x is any number from 0 to 1, B is the element boron, y is a number from 0 to 13, and z is a number from 4 to 57 with the additive agent and catalyst still being present. The complex hydride material is capable of cyclic dehydrogenation and rehydrogenation and has a hydrogen capacity of at least about 4 weight percent.

75. VIEW OF SECOND WEAPONS STORAGE AREA IGLOO FIELD FROM ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

75. VIEW OF SECOND WEAPONS STORAGE AREA IGLOO FIELD FROM ROOF OF BUILDING 328 LOOKING NORTHWEST SHOWING BUILDING 327-318. - Loring Air Force Base, Weapons Storage Area, Northeastern corner of base at northern end of Maine Road, Limestone, Aroostook County, ME

72. OVERALL VIEW OF WEAPONS STORAGE AREA IGLOO FIELDS. TAKEN ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

72. OVERALL VIEW OF WEAPONS STORAGE AREA IGLOO FIELDS. TAKEN FROM ROOF OF BUILDING 232 (MINE SHOP) LOOKING NORTH. - Loring Air Force Base, Weapons Storage Area, Northeastern corner of base at northern end of Maine Road, Limestone, Aroostook County, ME

Recommended Best Practices for the Characterization of Storage Properties of Hydrogen Storage Materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

2010-03-01

This is a reference guide to common methodologies and protocols for measuring critical performance properties of advanced hydrogen storage materials. It helps users to communicate clearly the relevant performance properties of new materials as they are discovered and tested.

33 CFR 127.1313 - Storage of hazardous materials.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Storage of hazardous materials. 127.1313 Section 127.1313 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY... HAZARDOUS GAS Waterfront Facilities Handling Liquefied Hazardous Gas Operations § 127.1313 Storage of...

33 CFR 127.1313 - Storage of hazardous materials.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Storage of hazardous materials. 127.1313 Section 127.1313 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY... HAZARDOUS GAS Waterfront Facilities Handling Liquefied Hazardous Gas Operations § 127.1313 Storage of...

33 CFR 127.1313 - Storage of hazardous materials.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Storage of hazardous materials. 127.1313 Section 127.1313 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY... HAZARDOUS GAS Waterfront Facilities Handling Liquefied Hazardous Gas Operations § 127.1313 Storage of...

33 CFR 127.1313 - Storage of hazardous materials.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Storage of hazardous materials. 127.1313 Section 127.1313 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY... HAZARDOUS GAS Waterfront Facilities Handling Liquefied Hazardous Gas Operations § 127.1313 Storage of...

33 CFR 127.1313 - Storage of hazardous materials.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Storage of hazardous materials. 127.1313 Section 127.1313 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY... HAZARDOUS GAS Waterfront Facilities Handling Liquefied Hazardous Gas Operations § 127.1313 Storage of...

Nanoencapsulation of phase change materials for advanced thermal energy storage systems

PubMed Central

Shchukina, E. M.; Graham, M.; Zheng, Z.

2018-01-01

Phase change materials (PCMs) allow the storage of large amounts of latent heat during phase transition. They have the potential to both increase the efficiency of renewable energies such as solar power through storage of excess energy, which can be used at times of peak demand; and to reduce overall energy demand through passive thermal regulation. 198.3 million tons of oil equivalent were used in the EU in 2013 for heating. However, bulk PCMs are not suitable for use without prior encapsulation. Encapsulation in a shell material provides benefits such as protection of the PCM from the external environment and increased specific surface area to improve heat transfer. This review highlights techniques for the encapsulation of both organic and inorganic PCMs, paying particular attention to nanoencapsulation (capsules with sizes <1 μm). We also provide insight on future research, which should focus on (i) the development of multifunctional shell materials to improve lifespan and thermal properties and (ii) advanced mass manufacturing techniques for the economically viable production of PCM capsules, making it possible to utilize waste heat in intelligent passive thermal regulation systems, employing controlled, “on demand” energy release/uptake. PMID:29658558

Nanoencapsulation of phase change materials for advanced thermal energy storage systems.

PubMed

Shchukina, E M; Graham, M; Zheng, Z; Shchukin, D G

2018-06-05

Phase change materials (PCMs) allow the storage of large amounts of latent heat during phase transition. They have the potential to both increase the efficiency of renewable energies such as solar power through storage of excess energy, which can be used at times of peak demand; and to reduce overall energy demand through passive thermal regulation. 198.3 million tons of oil equivalent were used in the EU in 2013 for heating. However, bulk PCMs are not suitable for use without prior encapsulation. Encapsulation in a shell material provides benefits such as protection of the PCM from the external environment and increased specific surface area to improve heat transfer. This review highlights techniques for the encapsulation of both organic and inorganic PCMs, paying particular attention to nanoencapsulation (capsules with sizes <1 μm). We also provide insight on future research, which should focus on (i) the development of multifunctional shell materials to improve lifespan and thermal properties and (ii) advanced mass manufacturing techniques for the economically viable production of PCM capsules, making it possible to utilize waste heat in intelligent passive thermal regulation systems, employing controlled, "on demand" energy release/uptake.

Fluoride salts as phase change materials for thermal energy storage in the temperature range 1000-1400 K

NASA Technical Reports Server (NTRS)

Misra, Ajay K.

1988-01-01

Eutectic compositions and congruently melting intermediate compounds in binary and ternary fluoride salt systems were characterized for potential use as latent heat of fusion phase change materials to store thermal energy in the temperature range 1000-1400 K. The melting points and eutectic compositions for many systems with published phase diagrams were experimentally verified and new eutectic compositions having melting points between 1000 and 1400 K were identified. Heats of fusion of several binary and ternary eutectics and congruently melting compounds were experimentally measured by differential scanning calorimetry. For a few systems in which heats of mixing in the melts have been measured, heats of fusion of the eutectics were calculated from thermodynamic considerations and good agreement was obtained between the measured and calculated values. Several combinations of salts with high heats of fusion per unit mass (greater than 0.7 kJ/g) have been identified for possible use as phase change materials in advanced solar dynamic space power applications.

Industrial waste materials and by-products as thermal energy storage (TES) materials: A review

NASA Astrophysics Data System (ADS)

Gutierrez, Andrea; Miró, Laia; Gil, Antoni; Rodríguez-Aseguinolaza, Javier; Barreneche, Camila; Calvet, Nicolas; Py, Xavier; Fernández, A. Inés; Grágeda, Mario; Ushak, Svetlana; Cabeza, Luisa F.

2016-05-01

A wide variety of potential materials for thermal energy storage (TES) have been identify depending on the implemented TES method, Sensible, latent or thermochemical. In order to improve the efficiency of TES systems more alternatives are continuously being sought. In this regard, this paper presents the review of low cost heat storage materials focused mainly in two objectives: on the one hand, the implementation of improved heat storage devices based on new appropriate materials and, on the other hand, the valorisation of waste industrial materials will have strong environmental, economic and societal benefits such as reducing the landfilled waste amounts, reducing the greenhouse emissions and others. Different industrial and municipal waste materials and by products have been considered as potential TES materials and have been characterized as such. Asbestos containing wastes, fly ashes, by-products from the salt industry and from the metal industry, wastes from recycling steel process and from copper refining process and dross from the aluminium industry, and municipal wastes (glass and nylon) have been considered. This work shows a great revalorization of wastes and by-product opportunity as TES materials, although more studies are needed to achieve industrial deployment of the idea.

Materials and structures for stretchable energy storage and conversion devices.

PubMed

Xie, Keyu; Wei, Bingqing

2014-06-11

Stretchable energy storage and conversion devices (ESCDs) are attracting intensive attention due to their promising and potential applications in realistic consumer products, ranging from portable electronics, bio-integrated devices, space satellites, and electric vehicles to buildings with arbitrarily shaped surfaces. Material synthesis and structural design are core in the development of highly stretchable supercapacitors, batteries, and solar cells for practical applications. This review provides a brief summary of research development on the stretchable ESCDs in the past decade, from structural design strategies to novel materials synthesis. The focuses are on the fundamental insights of mechanical characteristics of materials and structures on the performance of the stretchable ESCDs, as well as challenges for their practical applications. Finally, some of the important directions in the areas of material synthesis and structural design facing the stretchable ESCDs are discussed. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Research on medium and high temperature solar heat storage materials

NASA Technical Reports Server (NTRS)

Heine, D.; Jucker, J.; Koch, D.; Krahling, H.; Supper, W.

1979-01-01

Characteristics of solar heat storage materials, preliminary tests in which melting and solidification characteristics are tested, and service life and cycling tests are reported. Various aspects of corrosion are discussed as well as decision about ultimate selection of materials. A program for storage and evaluation of data is included.

Energy storage options for space power

NASA Astrophysics Data System (ADS)

Hoffman, H. W.; Martin, J. F.; Olszewski, M.

Including energy storage in a space power supply enhances the feasibility of using thermal power cycles (Rankine or Brayton) and providing high-power pulses. Superconducting magnets, capacitors, electrochemical batteries, thermal phase-change materials (PCM), and flywheels are assessed; the results obtained suggest that flywheels and phase-change devices hold the most promise. Latent heat storage using inorganic salts and metallic eutectics offers thermal energy storage densities of 1500 kJ/kg to 2000 kJ/kg at temperatures to 1675 K. Innovative techniques allow these media to operate in direct contact with the heat engine working fluid. Enhancing thermal conductivity and/or modifying PCM crystallization habit provide other options. Flywheels of low-strain graphite and Kevlar fibers have achieved mechanical energy storage densities of 300 kJ/kg. With high-strain graphite fibers, storage densities appropriate to space power needs (about 500 kJ/kg) seem feasible. Coupling advanced flywheels with emerging high power density homopolar generators and compulsators could result in electric pulse-power storage modules of significantly higher energy density.

New Pathways and Metrics for Enhanced, Reversible Hydrogen Storage in Boron-Doped Carbon Nanospaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pfeifer, Peter; Wexler, Carlos; Hawthorne, M. Frederick

This project, since its start in 2007—entitled “Networks of boron-doped carbon nanopores for low-pressure reversible hydrogen storage” (2007-10) and “New pathways and metrics for enhanced, reversible hydrogen storage in boron-doped carbon nanospaces” (2010-13)—is in support of the DOE's National Hydrogen Storage Project, as part of the DOE Hydrogen and Fuel Cells Program’s comprehensive efforts to enable the widespread commercialization of hydrogen and fuel cell technologies in diverse sectors of the economy. Hydrogen storage is widely recognized as a critical enabling technology for the successful commercialization and market acceptance of hydrogen powered vehicles. Storing sufficient hydrogen on board a wide rangemore » of vehicle platforms, at energy densities comparable to gasoline, without compromising passenger or cargo space, remains an outstanding technical challenge. Of the main three thrust areas in 2007—metal hydrides, chemical hydrogen storage, and sorption-based hydrogen storage—sorption-based storage, i.e., storage of molecular hydrogen by adsorption on high-surface-area materials (carbons, metal-organic frameworks, and other porous organic networks), has emerged as the most promising path toward achieving the 2017 DOE storage targets of 0.055 kg H2/kg system (“5.5 wt%”) and 0.040 kg H2/liter system. The objective of the project is to develop high-surface-area carbon materials that are boron-doped by incorporation of boron into the carbon lattice at the outset, i.e., during the synthesis of the material. The rationale for boron-doping is the prediction that boron atoms in carbon will raise the binding energy of hydro- gen from 4-5 kJ/mol on the undoped surface to 10-14 kJ/mol on a doped surface, and accordingly the hydro- gen storage capacity of the material. The mechanism for the increase in binding energy is electron donation from H2 to electron-deficient B atoms, in the form of sp2 boron-carbon bonds. Our team is proud to

30 CFR 57.6102 - Explosive material storage practices.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Explosive material storage practices. 57.6102 Section 57.6102 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Explosives Storage-Surface and Underground §...

30 CFR 57.6102 - Explosive material storage practices.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Explosive material storage practices. 57.6102 Section 57.6102 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Explosives Storage-Surface and Underground §...

30 CFR 57.6102 - Explosive material storage practices.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Explosive material storage practices. 57.6102 Section 57.6102 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Explosives Storage-Surface and Underground §...

Wetland survey of selected areas in the K-24 Site Area of responsibility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rosensteel, B.A.; Awl, D.J.

1995-07-01

In accordance with DOE Regulations for Compliance with Floodplain/Wetlands Environmental Review Requirements, wetland surveys were conducted in selected areas within the K-25 Area of Responsibility during the summer of 1994. These areas are Mitchell Branch, Poplar Creek, the K-770 OU, Duct Island Peninsula, the Powerhouse area, and the K-25 South Corner. Previously surveyed areas included in this report are the main plant area of the K-25 Site, the K-901 OU, the AVLIS site, and the K-25 South Site. Wetland determinations were based on the USACE methodology. Forty-four separate wetland areas, ranging in size from 0.13 to 4.23 ha, were identified.more » Wetlands were identified in all of the areas surveyed with the exception of the interior of the Duct Island Peninsula and the main plant area of the K-25 Site. Wetlands perform functions such as floodflow alteration, sediment stabilization, sediment and toxicant retention, nutrient transformation, production export, and support of aquatic species and wildlife diversity and abundance. The forested, scrub-shrub, and emergent wetlands identified in the K-25 area perform some or all of these functions to varying degrees.« less

Evolutionary search for new high-k dielectric materials: methodology and applications to hafnia-based oxides.

PubMed

Zeng, Qingfeng; Oganov, Artem R; Lyakhov, Andriy O; Xie, Congwei; Zhang, Xiaodong; Zhang, Jin; Zhu, Qiang; Wei, Bingqing; Grigorenko, Ilya; Zhang, Litong; Cheng, Laifei

2014-02-01

High-k dielectric materials are important as gate oxides in microelectronics and as potential dielectrics for capacitors. In order to enable computational discovery of novel high-k dielectric materials, we propose a fitness model (energy storage density) that includes the dielectric constant, bandgap, and intrinsic breakdown field. This model, used as a fitness function in conjunction with first-principles calculations and the global optimization evolutionary algorithm USPEX, efficiently leads to practically important results. We found a number of high-fitness structures of SiO2 and HfO2, some of which correspond to known phases and some of which are new. The results allow us to propose characteristics (genes) common to high-fitness structures--these are the coordination polyhedra and their degree of distortion. Our variable-composition searches in the HfO2-SiO2 system uncovered several high-fitness states. This hybrid algorithm opens up a new avenue for discovering novel high-k dielectrics with both fixed and variable compositions, and will speed up the process of materials discovery.

Nanoscale Engineering of Heterostructured Anode Materials for Boosting Lithium-Ion Storage.

PubMed

Chen, Gen; Yan, Litao; Luo, Hongmei; Guo, Shaojun

2016-09-01

Rechargeable lithium-ion batteries (LIBs), as one of the most important electrochemical energy-storage devices, currently provide the dominant power source for a range of devices, including portable electronic devices and electric vehicles, due to their high energy and power densities. The interest in exploring new electrode materials for LIBs has been drastically increasing due to the surging demands for clean energy. However, the challenging issues essential to the development of electrode materials are their low lithium capacity, poor rate ability, and low cycling stability, which strongly limit their practical applications. Recent remarkable advances in material science and nanotechnology enable rational design of heterostructured nanomaterials with optimized composition and fine nanostructure, providing new opportunities for enhancing electrochemical performance. Here, the progress as to how to design new types of heterostructured anode materials for enhancing LIBs is reviewed, in the terms of capacity, rate ability, and cycling stability: i) carbon-nanomaterials-supported heterostructured anode materials; ii) conducting-polymer-coated electrode materials; iii) inorganic transition-metal compounds with core@shell structures; and iv) combined strategies to novel heterostructures. By applying different strategies, nanoscale heterostructured anode materials with reduced size, large surfaces area, enhanced electronic conductivity, structural stability, and fast electron and ion transport, are explored for boosting LIBs in terms of high capacity, long cycling lifespan, and high rate durability. Finally, the challenges and perspectives of future materials design for high-performance LIB anodes are considered. The strategies discussed here not only provide promising electrode materials for energy storage, but also offer opportunities in being extended for making a variety of novel heterostructured nanomaterials for practical renewable energy applications. © 2016

Diffused holographic information storage and retrieval using photorefractive optical materials

NASA Astrophysics Data System (ADS)

McMillen, Deanna Kay

Holography offers a tremendous opportunity for dense information storage, theoretically one bit per cubic wavelength of material volume, with rapid retrieval, of up to thousands of pages of information simultaneously. However, many factors prevent the theoretical storage limit from being reached, including dynamic range problems and imperfections in recording materials. This research explores new ways of moving closer to practical holographic information storage and retrieval by altering the recording materials, in this case, photorefractive crystals, and by increasing the current storage capacity while improving the information retrieved. As an experimental example of the techniques developed, the information retrieved is the correlation peak from an optical recognition architecture, but the materials and methods developed are applicable to many other holographic information storage systems. Optical correlators can potentially solve any signal or image recognition problem. Military surveillance, fingerprint identification for law enforcement or employee identification, and video games are but a few examples of applications. A major obstacle keeping optical correlators from being universally accepted is the lack of a high quality, thick (high capacity) holographic recording material that operates with red or infrared wavelengths which are available from inexpensive diode lasers. This research addresses the problems from two positions: find a better material for use with diode lasers, and reduce the requirements placed on the material while maintaining an efficient and effective system. This research found that the solutions are new dopants introduced into photorefractive lithium niobate to improve wavelength sensitivities and the use of a novel inexpensive diffuser that reduces the dynamic range and optical element quality requirements (which reduces the cost) while improving performance. A uniquely doped set of 12 lithium niobate crystals was specified and

Synthesis and Engineering Materials Properties of Fluid Phase Chemical Hydrogen Storage Materials for Automotive Applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Choi, Young Joon; Westman, Matthew P.; Karkamkar, Abhijeet J.

Among candidates for chemical hydrogen storage in PEM fuel cell automotive applications, ammonia borane (AB, NH3BH3) is considered to be one of the most promising materials due to its high practical hydrogen content of 14-16 wt%. This material is selected as a surrogate chemical for a hydrogen storage system. For easier transition to the existing infrastructure, a fluid phase hydrogen storage material is very attractive and thus, we investigated the engineering materials properties of AB in liquid carriers for a chemical hydrogen storage slurry system. Slurries composed of AB and high temperature liquids were prepared by mechanical milling and sonicationmore » in order to obtain stable and fluidic properties. Volumetric gas burette system was adopted to observe the kinetics of the H2 release reactions of the AB slurry and neat AB. Viscometry and microscopy were employed to further characterize slurries engineering properties. Using a tip-sonication method we have produced AB/silicone fluid slurries at solid loadings up to 40wt% (6.5wt% H2) with viscosities less than 500cP at 25°C.« less

2D materials for renewable energy storage devices: Outlook and challenges.

PubMed

Sahoo, Ramkrishna; Pal, Anjali; Pal, Tarasankar

2016-11-15

Scientists are looking for cost-effective, clean and durable alternative energy devices. Superior charge storage devices can easily meet the demands of our daily needs. In this respect, a material with suitable dimensions for charge storage devices has been considered to be very important. Improved performance of charge storage devices has been derived from whole-body participation and the best are from 2D materials, which provide a viable and acceptable solution.

Quantifying and Addressing the DOE Material Reactivity Requirements with Analysis and Testing of Hydrogen Storage Materials & Systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khalil, Y. F.

2012-04-30

The objective of this project is to examine safety aspects of candidate hydrogen storage materials and systems being developed in the DOE Hydrogen Program. As a result of this effort, the general DOE safety target will be given useful meaning by establishing a link between the characteristics of new storage materials and the satisfaction of safety criteria. This will be accomplished through the development and application of formal risk analysis methods, standardized materials testing, chemical reactivity characterization, novel risk mitigation approaches and subscale system demonstration. The project also will collaborate with other DOE and international activities in materials based hydrogenmore » storage safety to provide a larger, highly coordinated effort.« less

Fires at storage sites of organic materials, waste fuels and recyclables.

PubMed

Ibrahim, Muhammad Asim; Alriksson, Stina; Kaczala, Fabio; Hogland, William

2013-09-01

During the last decade, the European Union has enforced the diversion of organic wastes and recyclables to waste management companies operating incineration plants, composting plants and recycling units instead of landfills. The temporary storage sites have been established as a buffer against fluctuations in energy demand throughout the year. Materials also need to be stored at temporary storage sites before recovery and recycling. However, regulations governing waste fuel storage and handling have not yet been developed, and, as a result, companies have engaged in risky practices that have resulted in a high number of fire incidents. In this study, a questionnaire survey was distributed to 249 of the 400 members of Avfall Sverige (Swedish Waste Management Association), which represents the waste management of 95% of the Swedish population. Information regarding 122 storage facilities owned by 69 companies was obtained; these facilities were responsible for the storage of 47% of the total treated waste (incineration + digestion + composting) in 2010 in Sweden. To identify factors related to fire frequency, the questionnaire covered the amounts of material handled and burnt per year, financial losses due to fires, storage duration, storage method and types of waste. The results show that 217 fire incidents corresponded to 170 kilotonnes of material burnt and cumulative losses of 49 million SEK (€4.3 million). Fire frequency and amount of material burnt per fire was found to be dependent upon type of management group (waste operator). Moreover, a correlation was found between fire frequency and material recycled during past years. Further investigations of financial aspects and externalities of fire incidents are recommended.

Ultrahigh Storage and Fast Diffusion of Na and K in Blue Phosphorene Anodes.

PubMed

Mukherjee, Sankha; Kavalsky, Lance; Singh, Chandra Veer

2018-03-14

In the wake of blue phosphorene's (BP) computational discovery and experimental realization, it has emerged as a versatile material with interesting optical, electrical, and mechanical properties. In this study, using first principles density functional theory calculations, we have investigated the adsorption and diffusion of Na and K over monolayer BP to assess its suitability as Na-ion and K-ion battery anodes. The optimized adsorption energies were found to be -0.96 eV for Na and -1.54 eV for K, which are sufficiently large to ensure stability and safety during operation. In addition, BP could adsorb Na and K atoms up to a stoichiometric ratio of 1:1 which yields a high storage capacity of 865 mA h/g for both adatom species. Through examination of the electronic structure and projected density of states of BP as a function of Na/K concentration, we predict that the band gap of the system increasingly shrinks, and in the case of maximum K adsorption, the band gap diminishes completely. Additionally, the diffusion of Na and K over BP is observed to be ultrafast, especially for K, and anisotropic with modest energy barriers of 0.11 and 0.093 eV for Na and K, respectively. Building upon these findings, we employed vibrational analysis techniques with transition state theory to incorporate kinetic effects and predicted a diffusivity of 7.2 × 10 -5 cm 2 /s for Na and 8.58 × 10 -5 cm 2 /s for K on BP. Given these advantages, that is, ultrahigh capacity, electrical conductivity, and high Na/K diffusivity, we conclude that BP can be considered as an excellent candidate for anodes in Na- and K-ion batteries.

Effects of Material Choice on Biocide Loss in Orion Water Storage Tanks

NASA Technical Reports Server (NTRS)

Wallace, W. T.; Wallace, S. L.; Gazda, D. B.; Lewis, J. F.

2016-01-01

When preparing for long-duration spaceflight missions, maintaining a safe supply of potable water is of the utmost importance. One major aspect of that is ensuring that microbial growth is minimized. Historically, this challenge has been addressed through the use of biocides. When using biocides, the choice of materials for the storage containers is important, because surface reactions can reduce biocide concentrations below their effective range. In the water storage system baselined for the Orion vehicle, the primary wetted materials are stainless steel (316 L) and a titanium alloy (Ti6Al4V). Previous testing with these materials has shown that the biocide selected for use in the system (ionic silver) will plate out rapidly upon initial wetting of the system. One potential approach for maintaining an adequate biocide concentration is to spike the water supply with high levels of biocide in an attempt to passivate the surface. To evaluate this hypothesis, samples of the wetted materials were tested individually and together to determine the relative loss of biocide under representative surface area-to-volume ratios after 24 hours. Additionally, we have analyzed the efficacy of disinfecting a system containing these materials by measuring reductions in bacterial counts in the same test conditions. Preliminary results indicate that the use of titanium, either individually or in combination with stainless steel, can result in over 95% loss of biocide, while less than 5% is lost when using stainless steel. In bacterial testing, viable organisms were recovered from samples exposed to the titanium coupons after 24 hours. By comparison, no organisms were recovered from the test vessels containing only stainless steel. These results indicate that titanium, while possessing some favorable attributes, may pose additional challenges when used in water storage tanks with ionic silver biocide.

Charge induced enhancement of adsorption for hydrogen storage materials

NASA Astrophysics Data System (ADS)

Sun, Xiang

2009-12-01

The rising concerns about environmental pollution and global warming have facilitated research interest in hydrogen energy as an alternative energy source. To apply hydrogen for transportations, several issues have to be solved, within which hydrogen storage is the most critical problem. Lots of materials and devices have been developed; however, none is able to meet the DOE storage target. The primary issue for hydrogen physisorption is a weak interaction between hydrogen and the surface of solid materials, resulting negligible adsorption at room temperature. To solve this issue, there is a need to increase the interaction between the hydrogen molecules and adsorbent surface. In this study, intrinsic electric dipole is investigated to enhance the adsorption energy. The results from the computer simulation of single ionic compounds with hydrogen molecules to form hydrogen clusters showed that electrical charge of substances plays an important role in generation of attractive interaction with hydrogen molecules. In order to further examine the effects of static interaction on hydrogen adsorption, activated carbon with a large surface area was impregnated with various ionic salts including LiCl, NaCl, KCl, KBr, and NiCl2 and their performance for hydrogen storage was evaluated by using a volumetric method. Corresponding computer simulations have been carried out by using DFT (Density Functional Theory) method combined with point charge arrays. Both experimental and computational results prove that the adsorption capacity of hydrogen and its interaction with the solid materials increased with electrical dipole moment. Besides the intrinsic dipole, an externally applied electric field could be another means to enhance hydrogen adsorption. Hydrogen adsorption under an applied electric field was examined by using porous nickel foil as electrodes. Electrical signals showed that adsorption capacity increased with the increasing of gas pressure and external electric voltage

Synthesis of vanadium-doped palladium nanoparticles for hydrogen storage materials

NASA Astrophysics Data System (ADS)

Yamamoto, Yuki; Miyachi, Mariko; Yamanoi, Yoshinori; Minoda, Ai; Maekawa, Shunsuke; Oshima, Shinji; Kobori, Yoshihiro; Nishihara, Hiroshi

2011-12-01

Palladium-vanadium (Pd/V) alloy nanoparticles stabilized with n-pentyl isocyanide were prepared as new hydrogen storage materials by a facile polyol-based synthetic route with tetraethylene glycol and NaOH at 250 °C. The size distribution of the nanoparticles thus obtained featured two peaks at 4.0 ± 1.1 and 1.4 ± 0.3 nm in diameter, which were the mixture of Pd/V alloy and Pd nanoparticles. The ratio between the number of Pd/V and that of Pd nanoparticles was 51:49, and the Pd:V ratio of the overall product was 9:1 in wt%, indicating that the 4.0 nm Pd/V nanoparticles were composed of 81% Pd and 19% V. The inclusion of vanadium caused the increase in the d-spacing and thus expansion of lattice constant. A rapid increase in hydrogen content at low H2 pressures was observed for the Pd/V nanoparticles, and a 0.47 wt% H2 adsorption capacity was achieved under a H2 pressure of 10 MPa at 303 K. Hydrogen storage performances of Pd/V alloy nanoparticles was superior compared with Pd nanoparticles.

NASICON-Structured Materials for Energy Storage.

PubMed

Jian, Zelang; Hu, Yong-Sheng; Ji, Xiulei; Chen, Wen

2017-05-01

The demand for electrical energy storage (EES) is ever increasing, which calls for better batteries. NASICON-structured materials represent a family of important electrodes due to its superior ionic conductivity and stable structures. A wide range of materials have been considered, where both vanadium-based and titanium-based materials are recommended as being of great interest. NASICON-structured materials are suitable for both the cathode and the anode, where the operation potential can be easily tuned by the choice of transition metal and/or polyanion group in the structure. NASICON-structured materials also represent a class of solid electrolytes, which are widely employed in all-solid-state ion batteries, all-solid-state air batteries, and hybrid batteries. NASICON-structured materials are reviewed with a focus on both electrode materials and solid-state electrolytes. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

New materials for thermal energy storage in concentrated solar power plants

NASA Astrophysics Data System (ADS)

Guerreiro, Luis; Collares-Pereira, Manuel

2016-05-01

Solar Thermal Electricity (STE) is an important alternative to PV electricity production, not only because it is getting more cost competitive with the continuous growth in installed capacity, engineering and associated innovations, but also, because of its unique dispatch ability advantage as a result of the already well established 2-tank energy storage using molten salts (MS). In recent years, research has been performed, on direct MS systems, to which features like modularity and combinations with other (solid) thermal storage materials are considered with the goal of achieving lower investment cost. Several alternative materials and systems have been studied. In this research, storage materials were identified with thermo-physical data being presented for different rocks (e.g. quartzite), super concrete, and other appropriate solid materials. Among the new materials being proposed like rocks from old quarries, an interesting option is the incorporation of solid waste material from old mines belonging to the Iberian Pyritic Belt. These are currently handled as byproducts of past mine activity, and can potentially constitute an environmental hazard due to their chemical (metal) content. This paper presents these materials, as part of a broad study to improve the current concept of solar energy storage for STE plants, and additionally presents a potentially valuable solution for environmental protection related to re-use of mining waste.

Design and synthesis of vanadium hydrazide gels for Kubas-type hydrogen adsorption: a new class of hydrogen storage materials.

PubMed

Hoang, Tuan K A; Webb, Michael I; Mai, Hung V; Hamaed, Ahmad; Walsby, Charles J; Trudeau, Michel; Antonelli, David M

2010-08-25

In this paper we demonstrate that the Kubas interaction, a nondissociative form of weak hydrogen chemisorption with binding enthalpies in the ideal 20-30 kJ/mol range for room-temperature hydrogen storage, can be exploited in the design of a new class of hydrogen storage materials which avoid the shortcomings of hydrides and physisorpion materials. This was accomplished through the synthesis of novel vanadium hydrazide gels that use low-coordinate V centers as the principal Kubas H(2) binding sites with only a negligible contribution from physisorption. Materials were synthesized at vanadium-to-hydrazine ratios of 4:3, 1:1, 1:1.5, and 1:2 and characterized by X-ray powder diffraction, X-ray photoelectron spectroscopy, nitrogen adsorption, elemental analysis, infrared spectroscopy, and electron paramagnetic resonance spectroscopy. The material with the highest capacity possesses an excess reversible storage of 4.04 wt % at 77 K and 85 bar, corresponding to a true volumetric adsorption of 80 kg H(2)/m(3) and an excess volumetric adsorption of 60.01 kg/m(3). These values are in the range of the ultimate U.S. Department of Energy goal for volumetric density (70 kg/m(3)) as well as the best physisorption material studied to date (49 kg H(2)/m(3) for MOF-177). This material also displays a surprisingly high volumetric density of 23.2 kg H(2)/m(3) at room temperature and 85 bar--roughly 3 times higher than that of compressed gas and approaching the DOE 2010 goal of 28 kg H(2)/m(3). These materials possess linear isotherms and enthalpies that rise on coverage and have little or no kinetic barrier to adsorption or desorption. In a practical system these materials would use pressure instead of temperature as a toggle and can thus be used in compressed gas tanks, currently employed in many hydrogen test vehicles, to dramatically increase the amount of hydrogen stored and therefore the range of any vehicle.

Flexible composite material with phase change thermal storage

NASA Technical Reports Server (NTRS)

Buckley, Theresa M. (Inventor)

2001-01-01

A highly flexible composite material having a flexible matrix containing a phase change thermal storage material. The composite material can be made to heat or cool the body or to act as a thermal buffer to protect the wearer from changing environmental conditions. The composite may also include an external thermal insulation layer and/or an internal thermal control layer to regulate the rate of heat exchange between the composite and the skin of the wearer. Other embodiments of the PCM composite also provide 1) a path for evaporation or direct absorption of perspiration from the skin of the wearer for improved comfort and thermal control, 2) heat conductive pathways within the material for thermal equalization, 3) surface treatments for improved absorption or rejection of heat by the material, and 4) means for quickly regenerating the thermal storage capacity for reuse of the material. Applications of the composite materials are also described which take advantage of the composite's thermal characteristics. The examples described include a diver's wet suit, ski boot liners, thermal socks, ,gloves and a face mask for cold weather activities, and a metabolic heating or cooling blanket useful for treating hypothermia or fever patients in a medical setting and therapeutic heating or cooling orthopedic joint supports.

Flexible composite material with phase change thermal storage

NASA Technical Reports Server (NTRS)

Buckley, Theresa M. (Inventor)

1999-01-01

A highly flexible composite material having a flexible matrix containing a phase change thermal storage material. The composite material can be made to heat or cool the body or to act as a thermal buffer to protect the wearer from changing environmental conditions. The composite may also include an external thermal insulation layer and/or an internal thermal control layer to regulate the rate of heat exchange between the composite and the skin of the wearer. Other embodiments of the PCM composite also provide 1) a path for evaporation or direct absorption of perspiration from the skin of the wearer for improved comfort and thermal control, 2) heat conductive pathways within the material for thermal equalization, 3) surface treatments for improved absorption or rejection of heat by the material, and 4) means for quickly regenerating the thermal storage capacity for reuse of the material. Applications of the composite materials are also described which take advantage of the composite's thermal characteristics. The examples described include a diver's wet suit, ski boot liners, thermal socks, gloves and a face mask for cold weather activities, and a metabolic heating or cooling blanket useful for treating hypothermia or fever patients in a medical setting and therapeutic heating or cooling orthopedic joint supports.

Hydrogen storage behaviors of Ni-doped graphene Oxide/MIL-101 hybrid composites.

PubMed

Lee, Seul-Yi; Park, Soo-Jin

2013-01-01

In this work, Ni-doped graphene oxide/MIL-101 hybrid composites (Ni--GO/MIL) were prepared to investigate their hydrogen storage behaviors. Ni--GO/MIL was synthesized by adding Ni--GO in situ during the synthesis of MIL-101 using a hydrothermal process, which was conducted by conventional convection heating with Cr(III) ion as a metal center and telephthalic acid as organic ligands. The crystalline structures and morphologies were measured by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The specific surface area and micropore volume were investigated by N2/77 K adsorption isotherms using the Brunauer-Emmett-Teller (BET) method and Dubinin-Radushkevic (D-R) equation, respectively. The hydrogen storage capacity was investigated by BEL-HP at 77 K and 1 bar. The obtained results show that Ni--GO/MIL presents new directions for achieving novel hybrid materials with higher hydrogen storage capacity.

Nanostructured Mo-based electrode materials for electrochemical energy storage.

PubMed

Hu, Xianluo; Zhang, Wei; Liu, Xiaoxiao; Mei, Yueni; Huang, Yunhui

2015-04-21

The development of advanced energy storage devices is at the forefront of research geared towards a sustainable future. Nanostructured materials are advantageous in offering huge surface to volume ratios, favorable transport features, and attractive physicochemical properties. They have been extensively explored in various fields of energy storage and conversion. This review is focused largely on the recent progress in nanostructured Mo-based electrode materials including molybdenum oxides (MoO(x), 2 ≤ x ≤ 3), dichalconides (MoX2, X = S, Se), and oxysalts for rechargeable lithium/sodium-ion batteries, Mg batteries, and supercapacitors. Mo-based compounds including MoO2, MoO3, MoO(3-y) (0 < y < 1), MMo(x)O(y) (M = Fe, Co, Ni, Ca, Mn, Zn, Mg, or Cd; x = 1, y = 4; x = 3, y = 8), MoS2, MoSe2, (MoO2)2P2O7, LiMoO2, Li2MoO3, etc. possess multiple valence states and exhibit rich chemistry. They are very attractive candidates for efficient electrochemical energy storage systems because of their unique physicochemical properties, such as conductivity, mechanical and thermal stability, and cyclability. In this review, we aim to provide a systematic summary of the synthesis, modification, and electrochemical performance of nanostructured Mo-based compounds, as well as their energy storage applications in lithium/sodium-ion batteries, Mg batteries, and pseudocapacitors. The relationship between nanoarchitectures and electrochemical performances as well as the related charge-storage mechanism is discussed. Moreover, remarks on the challenges and perspectives of Mo-containing compounds for further development in electrochemical energy storage applications are proposed. This review sheds light on the sustainable development of advanced rechargeable batteries and supercapacitors with nanostructured Mo-based electrode materials.

Carbon nanotube materials for hydrogen storage

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dillon, A.C.; Parilla, P.A.; Jones, K.M.

1998-08-01

Carbon single-wall nanotubes (SWNTs) are essentially elongated pores of molecular dimensions and are capable of adsorbing hydrogen at relatively high temperatures and low pressures. This behavior is unique to these materials and indicates that SWNTs are the ideal building block for constructing safe, efficient, and high energy density adsorbents for hydrogen storage applications. In past work the authors developed methods for preparing and opening SWNTs, discovered the unique adsorption properties of these new materials, confirmed that hydrogen is stabilized by physical rather than chemical interactions, measured the strength of interaction to be {approximately} 5 times higher than for adsorption onmore » planar graphite, and performed infrared absorption spectroscopy to determine the chemical nature of the surface terminations before, during, and after oxidation. This year the authors have made significant advances in synthesis and characterization of SWNT materials so that they can now prepare gram quantities of high-purity SWNT samples and measure and control the diameter distribution of the tubes by varying key parameters during synthesis. They have also developed methods which purify nanotubes and cut nanotubes into shorter segments. These capabilities provide a means for opening the tubes which were unreactive to the oxidation methods that successfully opened tubes, and offer a path towards organizing nanotube segments to enable high volumetric hydrogen storage densities. They also performed temperature programmed desorption spectroscopy on high purity carbon nanotube material obtained from collaborator Prof. Patrick Bernier and finished construction of a high precision Seivert`s apparatus which will allow the hydrogen pressure-temperature-composition phase diagrams to be evaluated for SWNT materials.« less

Effects of materials surface preparation for use in spacecraft potable water storage tanks

NASA Astrophysics Data System (ADS)

Wallace, William T.; Wallace, Sarah L.; Loh, Leslie J.; Kuo, C. K. Mike; Hudson, Edgar K.; Marlar, Tyler J.; Gazda, Daniel B.

2017-12-01

Maintaining a safe supply of potable water is of utmost importance when preparing for long-duration spaceflight missions, with the minimization of microbial growth being one major aspect. While biocides, such as ionic silver, historically have been used for microbial control in spaceflight, their effectiveness is sometimes limited due to surface reactions with the materials of the storage containers that reduce their concentrations below the effective range. For the Multi-Purpose Crew Vehicle, the primary wetted materials of the water storage system are stainless steel and a titanium alloy, and ionic silver has been chosen to serve as the biocide. As an attempt to understand what processes might reduce the known losses of silver, different treatment processes were attempted and samples of the wetted materials were tested, individually and together, to determine the relative loss of biocide under representative surface area-to-volume ratios. The results of testing presented here showed that the materials could be treated by a nitric acid rinse or a high-concentration silver spike to reduce the loss of silver and bacterial growth. It was also found that the minimum biocidal concentration could be maintained for over 28 days. These results have pointed to approaches that could be used to successfully maintain silver in spacecraft water systems for long-duration missions.

WEAPONS STORAGE AREA, LOOKING TOWARD ELECTRIC POWER STATION BUILDING (BUILDING ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

WEAPONS STORAGE AREA, LOOKING TOWARD ELECTRIC POWER STATION BUILDING (BUILDING 3583), STORAGE BUILDING (BUILDING 3584)NIGHT AND SECURITY POLICE ENTRY CONTROL (BUILDING 3582)LEFT. VIEW TO NORTHEAST - Plattsburgh Air Force Base, U.S. Route 9, Plattsburgh, Clinton County, NY

Storage depot for radioactive material

DOEpatents

Szulinski, Milton J.

1983-01-01

Vertical drilling of cylindrical holes in the soil, and the lining of such holes, provides storage vaults called caissons. A guarded depot is provided with a plurality of such caissons covered by shielded closures preventing radiation from penetrating through any linear gap to the atmosphere. The heat generated by the radioactive material is dissipated through the vertical liner of the well into the adjacent soil and thus to the ground surface so that most of the heat from the radioactive material is dissipated into the atmosphere in a manner involving no significant amount of biologically harmful radiation. The passive cooling of the radioactive material without reliance upon pumps, personnel, or other factor which might fail, constitutes one of the most advantageous features of this system. Moreover this system is resistant to damage from tornadoes or earthquakes. Hermetically sealed containers of radioactive material may be positioned in the caissons. Loading vehicles can travel throughout the depot to permit great flexibility of loading and unloading radioactive materials. Radioactive material can be shifted to a more closely spaced caisson after ageing sufficiently to generate much less heat. The quantity of material stored in a caisson is restricted by the average capacity for heat dissipation of the soil adjacent such caisson.

Satellite thermal storage systems using metallic phase-change materials

NASA Astrophysics Data System (ADS)

Lauf, R. J.; Hamby, C.

Solar (thermal) dynamic power systems for satellites require a heat storage system capable of operating the engine during eclipse. A system is described in which the phase-change material (PCM) is a metal rather than the more conventional fluoride salts. Thermal storage modules consisting of germanium contained in graphite have good thermal conductivity, low parasitic mass, and are physically and chemically stable. The result is described for thermal cycle testing of graphite capsules containing germanium and several germanium- and silicon-based alloys, as well as some initial tests of the compatibility of graphite with Nb-1 percent Zr structural materials.

Hydrogen storage studies on palladium-doped carbon materials (AC, CB, CNMs) @ metal-organic framework-5.

PubMed

Viditha, V; Srilatha, K; Himabindu, V

2016-05-01

Metal organic frameworks (MOFs) are a rapidly growing class of porous materials and are considered as best adsorbents for their high surface area and extraordinary porosity. The MOFs are synthesized by using various chemicals like triethylamine, terepthalic acid, zinc acetate dihydrate, chloroform, and dimethylformamide (DMF). Synthesized MOFs are intercalated with palladium/activated carbon, carbon black, and carbon nanomaterials by chemical reduction method for the purpose of enhancing the hydrogen adsorption capacities. We have observed that the palladium doped activated carbon on MOF-5 showed high hydrogen storage capacity. This may be due to the affinity of the palladium toward hydrogen molecule. The samples are characterized by X-ray diffraction, scanning electron microscopy (SEM), and Brunauer-Emmett-Teller (BET) surface area analysis. We have observed a clear decrease in the BET surface area and pore volume. The obtained results show a better performance for the synthesized sample. To our best knowledge, no one has reported the work on palladium-doped carbon materials (activated carbon, carbon black, carbon nanomaterials) impregnated to the metal-organic framework-5. We have attempted to synthesize carbon nanomaterials using indigenously fabricated chemical vapor deposition (CVD) unit as a support. We have observed an increase in the hydrogen storage capacities.

Functional Carbon Materials for Electrochemical Energy Storage

NASA Astrophysics Data System (ADS)

Zhou, Huihui

The ability to harvest and convert solar energy has been associated with the evolution of human civilization. The increasing consumption of fossil fuels since the industrial revolution, however, has brought to concerns in ecological deterioration and depletion of the fossil fuels. Facing these challenges, humankind is forced to seek for clean, sustainable and renewable energy resources, such as biofuels, hydraulic power, wind power, geothermal energy and other kinds of alternative energies. However, most alternative energy sources, generally in the form of electrical energy, could not be made available on a continuous basis. It is, therefore, essential to store such energy into chemical energy, which are portable and various applications. In this context, electrochemical energy-storage devices hold great promises towards this goal. The most common electrochemical energy-storage devices are electrochemical capacitors (ECs, also called supercapacitors) and batteries. In comparison to batteries, ECs posses high power density, high efficiency, long cycling life and low cost. ECs commonly utilize carbon as both (symmetric) or one of the electrodes (asymmetric), of which their performance is generally limited by the capacitance of the carbon electrodes. Therefore, developing better carbon materials with high energy density has been emerging as one the most essential challenges in the field. The primary objective of this dissertation is to design and synthesize functional carbon materials with high energy density at both aqueous and organic electrolyte systems. The energy density (E) of ECs are governed by E = CV 2/2, where C is the total capacitance and V is the voltage of the devices. Carbon electrodes with high capacitance and high working voltage should lead to high energy density. In the first part of this thesis, a new class of nanoporous carbons were synthesized for symmetric supercapacitors using aqueous Li2SO4 as the electrolyte. A unique precursor was adopted to

SECURITY GATE FOR WEAPONS STORAGE AREA. FROM LEFT TO RIGHT, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

SECURITY GATE FOR WEAPONS STORAGE AREA. FROM LEFT TO RIGHT, STORAGE BUILDING (BUILDING 3584), CONVENTIONAL MUNITIONS SHOP (BUILDING 3580), AND SECURITY POLICE ENTRY CONTROL BUILDING (BUILDING 3582). VIEW TO SOUTHWEST - Plattsburgh Air Force Base, U.S. Route 9, Plattsburgh, Clinton County, NY

Life and stability testing of packaged low-cost energy storage materials

NASA Astrophysics Data System (ADS)

Frysinger, G. R.

1980-07-01

A low-cost laminated plastic film which is used to contain a Glauber's salt-based phase change thermal energy storage material in sausage like containers called Chubs was developed. Results of tests performed on the Chub packages themselves and on the thermal energy storage capacity of the packaged phase change material are described. From the test results, a set of specifications was drawn up for a film material which will satisfactorily contain the phase change material under anticipated operating conditions. Calorimetric testing of the phase change material with thermal cycling indicates that a design capacity of 45 to 50 Btu/lb for a delta T of 30 F can be used for the packaged material.

Effect of storage time on the viscoelastic properties of elastomeric impression materials.

PubMed

Papadogiannis, Dimitris; Lakes, Roderic; Palaghias, George; Papadogiannis, Yiannis

2012-01-01

The aim of this study was to evaluate creep and viscoelastic properties of dental impression materials after different storage times. Six commercially available impression materials (one polyether and five silicones) were tested after being stored for 30 min to 2 weeks under both static and dynamic testing. Shear and Young's moduli, dynamic viscosity, loss tangent and other viscoelastic parameters were calculated. Four of the materials were tested 1 h after setting under creep for three hours and recovery was recorder for 50 h. The tested materials showed differences among them, while storage time had significant influence on their properties. Young's modulus E ranged from 1.81 to 12.99 MPa with the polyether material being the stiffest. All of the materials showed linear viscoelastic behavior exhibiting permanent deformation after 50h of creep recovery. As storage time affects the materials' properties, pouring time should be limited in the first 48 h after impression. Copyright © 2011 Japan Prosthodontic Society. Published by Elsevier Ltd. All rights reserved.

Analysis of thermal energy storage material with change-of-phase volumetric effects

NASA Technical Reports Server (NTRS)

Kerslake, Thomas W.; Ibrahim, Mounir B.

1990-01-01

NASA's Space Station Freedom proposed hybrid power system includes photovoltaic arrays with nickel hydrogen batteries for energy storage and solar dynamic collectors driving Brayton heat engines with change-of-phase Thermal Energy Storage (TES) devices. A TES device is comprised of multiple metallic, annular canisters which contain a eutectic composition LiF-CaF2 Phase Change Material (PCM) that melts at 1040 K. A moderately sophisticated LiF-CaF2 PCM computer model is being developed in three stages considering 1-D, 2-D, and 3-D canister geometries, respectively. The 1-D model results indicate that the void has a marked effect on the phase change process due to PCM displacement and dynamic void heat transfer resistance. Equally influential are the effects of different boundary conditions and liquid PCM natural convection. For the second stage, successful numerical techniques used in the 1-D phase change model are extended to a 2-D (r,z) PCM containment canister model. A prototypical PCM containment canister is analyzed and the results are discussed.

Assessing materials handling and storage capacities in port terminals

NASA Astrophysics Data System (ADS)

Dinu, O.; Roşca, E.; Popa, M.; Roşca, M. A.; Rusca, A.

2017-08-01

Terminals constitute the factual interface between different modes and, as a result, buffer stocks are unavoidable whenever transport flows with different discontinuities meet. This is the reason why assessing materials handling and storage capacities is an important issue in the course of attempting to increase operative planning of logistic processes in terminals. Proposed paper starts with a brief review of the compatibilities between different sorts of materials and corresponding transport modes and after, a literature overview of the studies related to ports terminals and their specialization is made. As a methodology, discrete event simulation stands as a feasible technique for assessing handling and storage capacities at the terminal, taking into consideration the multi-flows interaction and the non-uniform arrivals of vessels and inland vehicles. In this context, a simulation model, that integrates the activities of an inland water terminal and describes the essential interactions between the subsystems which influence the terminal capacity, is developed. Different scenarios are simulated for diverse sorts of materials, leading to bottlenecks identification, performance indicators such as average storage occupancy rate, average dwell or transit times estimations, and their evolution is analysed in order to improve the transfer operations in the logistic process

Effects of packaging materials on storage quality of peanut kernels

PubMed Central

Fu, Xiaoji; Xing, Shengping; Xiong, Huiwei; Min, Hua; Zhu, Xuejing; He, Jialin; Mu, Honglei

2018-01-01

In order to obtain optimum packaging materials for peanut kernels, the effects of four types of packaging materials on peanut storage quality (coat color, acid value, germination rate, relative damage, and prevention of aflatoxin contamination) were examined. The results showed that packaging materials had a major influence on peanut storage quality indexes. The color of the peanut seed coat packaged in the polyester/aluminum/polyamide/polyethylene (PET/AL/PA/PE) composite film bag did not change significantly during the storage period. Color deterioration was slower with polyamide/polyethylene (PA/PE) packaging materials than with polyethylene (PE) film bags and was slower in PE bags than in the woven bags. The use of PET/AL/PA/PE and PA/PE bags maintained peanut quality and freshness for more than one year and both package types resulted in better germination rates. There were significant differences between the four types of packaging materials in terms of controlling insect pests. The peanuts packaged in the highly permeable woven bags suffered serious invasion from insect pests, while both PET/AL/PA/PE and PA/PE bags effectively prevented insect infection. Peanuts stored in PET/AL/PA/PE and PA/PE bags were also better at preventing and controlling aflatoxin contamination. PMID:29518085

8. Interior view of former food service and storage area ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

8. Interior view of former food service and storage area looking towards hall way; showing closed and open doorways to walk-in storage; near southwest corner of building on main floor; view to southwest. - Ellsworth Air Force Base, Mess & Administration Building, 1561 Ellsworth Street, Blackhawk, Meade County, SD

38. Launch Area, Underground Missile Storage Structure, detail of conduit ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

38. Launch Area, Underground Missile Storage Structure, detail of conduit service junction - NIKE Missile Battery PR-79, Launch Area, East Windsor Road south of State Route 101, Foster, Providence County, RI

Advanced Energy Storage Devices: Basic Principles, Analytical Methods, and Rational Materials Design

PubMed Central

Liu, Jilei; Wang, Jin; Xu, Chaohe; Li, Chunzhong; Lin, Jianyi

2017-01-01

Abstract Tremendous efforts have been dedicated into the development of high‐performance energy storage devices with nanoscale design and hybrid approaches. The boundary between the electrochemical capacitors and batteries becomes less distinctive. The same material may display capacitive or battery‐like behavior depending on the electrode design and the charge storage guest ions. Therefore, the underlying mechanisms and the electrochemical processes occurring upon charge storage may be confusing for researchers who are new to the field as well as some of the chemists and material scientists already in the field. This review provides fundamentals of the similarities and differences between electrochemical capacitors and batteries from kinetic and material point of view. Basic techniques and analysis methods to distinguish the capacitive and battery‐like behavior are discussed. Furthermore, guidelines for material selection, the state‐of‐the‐art materials, and the electrode design rules to advanced electrode are proposed. PMID:29375964

Advanced Energy Storage Devices: Basic Principles, Analytical Methods, and Rational Materials Design.

PubMed

Liu, Jilei; Wang, Jin; Xu, Chaohe; Jiang, Hao; Li, Chunzhong; Zhang, Lili; Lin, Jianyi; Shen, Ze Xiang

2018-01-01

Tremendous efforts have been dedicated into the development of high-performance energy storage devices with nanoscale design and hybrid approaches. The boundary between the electrochemical capacitors and batteries becomes less distinctive. The same material may display capacitive or battery-like behavior depending on the electrode design and the charge storage guest ions. Therefore, the underlying mechanisms and the electrochemical processes occurring upon charge storage may be confusing for researchers who are new to the field as well as some of the chemists and material scientists already in the field. This review provides fundamentals of the similarities and differences between electrochemical capacitors and batteries from kinetic and material point of view. Basic techniques and analysis methods to distinguish the capacitive and battery-like behavior are discussed. Furthermore, guidelines for material selection, the state-of-the-art materials, and the electrode design rules to advanced electrode are proposed.

Composite Materials for Thermal Energy Storage: Enhancing Performance through Microstructures

PubMed Central

Ge, Zhiwei; Ye, Feng; Ding, Yulong

2014-01-01

Chemical incompatibility and low thermal conductivity issues of molten-salt-based thermal energy storage materials can be addressed by using microstructured composites. Using a eutectic mixture of lithium and sodium carbonates as molten salt, magnesium oxide as supporting material, and graphite as thermal conductivity enhancer, the microstructural development, chemical compatibility, thermal stability, thermal conductivity, and thermal energy storage performance of composite materials are investigated. The ceramic supporting material is essential for preventing salt leakage and hence provides a solution to the chemical incompatibility issue. The use of graphite gives a significant enhancement on the thermal conductivity of the composite. Analyses suggest that the experimentally observed microstructural development of the composite is associated with the wettability of the salt on the ceramic substrate and that on the thermal conduction enhancer. PMID:24591286

New infrared-sensitive photopolymer materials for information storage and processing

NASA Astrophysics Data System (ADS)

Nagtegaele, Patrice; Galstian, Tigran V.

2001-11-01

In response to the increasing demand of information systems, we need new materials with high performance for storage and processing applications. Available on the market optical storage materials present very useful characteristics but are still limited in the visible spectrum and are expansive. Recently, we have developed holographic polymer dispersed liquid crystal (H-PDLC) materials sensitive in the near infrared region (800 nm to 850 nm). These compounds are based on acrylate monomers and different liquid crystals (LC) and allow highly efficient in-situ recording of holographic optical elements using infra red lasers. Diffraction efficiency above 95% is demonstrated. Photosensitivity of the material, its dark ­development and photochemical stability of recorded gratings are investigated. The angular and spectral selectivities of gratings, recorded in these films are examined for recovering the refractive index modulation profile.

37. Launch Area, Underground Missile Storage Structure, detail of personnel ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

37. Launch Area, Underground Missile Storage Structure, detail of personnel entrance VIEW NORTH - NIKE Missile Battery PR-79, Launch Area, East Windsor Road south of State Route 101, Foster, Providence County, RI

Charging and Discharging Processes of Thermal Energy Storage System Using Phase change materials

NASA Astrophysics Data System (ADS)

Kanimozhi, B., Dr.; Harish, Kasilanka; Sai Tarun, Bellamkonda; Saty Sainath Reddy, Pogaku; Sai Sujeeth, Padakandla

2017-05-01

The objective of the study is to investigate the thermal characteristics of charging and discharge processes of fabricated thermal energy storage system using Phase change materials. Experiments were performed with phase change materials in which a storage tank have designed and developed to enhance the heat transfer rate from the solar tank to the PCM storage tank. The enhancement of heat transfer can be done by using a number of copper tubes in the fabricated storage tank. This storage tank can hold or conserve heat energy for a much longer time than the conventional water storage system. Performance evaluations of experimental results during charging and discharging processes of paraffin wax have discussed. In which heat absorption and heat rejection have been calculated with various flow rate.

Giant electrocaloric and energy storage performance of [(K0.5Na0.5)NbO3](1-x)-[LiSbO3] x nanocrystalline ceramics.

PubMed

Kumar, Raju; Singh, Satyendra

2018-02-16

Electrocaloric (EC) refrigeration, an EC effect based technology has been accepted as an auspicious way in the development of next generation refrigeration due to high efficiency and compact size. Here, we report the results of our experimental investigations on electrocaloric response and electrical energy storage properties in lead-free nanocrystalline (1 - x)K 0.5 Na 0.5 NbO 3 -xLiSbO 3 (KNN-xLS) ceramics in the range of 0.015 ≤ x ≤ 0.06 by the indirect EC measurements. Doping of LiSbO 3 has lowered both the transitions (T C and T O-T ) of KNN to the room temperature side effectively. A maximal value of EC temperature change, ΔT = 3.33 K was obtained for the composition with x = 0.03 at 345 K under an external electric field of 40 kV/cm. The higher value of EC responsivity, ζ = 8.32 × 10 -7  K.m/V is found with COP of 8.14 and recoverable energy storage of 0.128 J/cm 3 with 46% efficiency for the composition of x = 0.03. Our investigations show that this material is a very promising candidate for electrocaloric refrigeration and energy storage near room temperature.

High temperature metal hydrides as heat storage materials for solar and related applications.

PubMed

Felderhoff, Michael; Bogdanović, Borislav

2009-01-01

For the continuous production of electricity with solar heat power plants the storage of heat at a temperature level around 400 degrees C is essential. High temperature metal hydrides offer high heat storage capacities around this temperature. Based on Mg-compounds, these hydrides are in principle low-cost materials with excellent cycling stability. Relevant properties of these hydrides and their possible applications as heat storage materials are described.

High Temperature Metal Hydrides as Heat Storage Materials for Solar and Related Applications

PubMed Central

Felderhoff, Michael; Bogdanović, Borislav

2009-01-01

For the continuous production of electricity with solar heat power plants the storage of heat at a temperature level around 400 °C is essential. High temperature metal hydrides offer high heat storage capacities around this temperature. Based on Mg-compounds, these hydrides are in principle low-cost materials with excellent cycling stability. Relevant properties of these hydrides and their possible applications as heat storage materials are described. PMID:19333448

Contribution of postpolymerization conditioning and storage environments to the mechanical properties of three interim restorative materials.

PubMed

Thompson, Geoffrey A; Luo, Qing

2014-09-01

Because polymer-based interim restorative materials are weak, even well-made restorations sometimes fail before the definitive restoration is ready for insertion. Therefore, knowing which fabrication procedures and service conditions affect mechanical properties is important, particularly over an extended period. The purpose of this study was to evaluate the effect of thermal treatment, surface sealing, thermocycling, storage media, storage temperature, and age on autopolymerizing poly(methylmethacrylate) and bis-acryl interim restorative materials. Outcome measures were flexural strength, Vickers surface microhardness, and impact strength. Flexural strength and microhardness of poly(methylmethacrylate) (Jet Acrylic) and 2 bis-acryl-composite resin (Protemp 3 Garant and Integrity) interim restorative materials were evaluated as affected by storage media, storage temperature, storage time, thermocycling, postpolymerization thermal treatment, or application of a surface sealer. In total, 2880 beam specimens (25×2×2 mm) were fabricated. Mechanical property analyses were made at 10 days, 30 days, 6 months, and 1 year after specimen preparation. Flexural strength was determined by using a 3-point bending test in a universal testing machine with a 1 kN load cell at a crosshead speed of 5.0 mm min(-1). Fracture specimens were recovered and used for determining Vickers microhardness. Measurements were made with a 0.1 N load and 15 second dwell time. Three microhardness measurements were made for each specimen, and the mean was used for reporting Vickers microhardness. Notched impact specimens (64×12.7×6.35 mm) were fabricated from Jet, Protemp 3 Garant, and Integrity interim restorative materials, yielding 288 impact specimens. Impact strengths were assessed at 10 days, 30 days, 6 months, and 1 year with a 2 J pendulum. The effects of the various experimental treatments were determined and rank ordered with analysis of variance, F ratios, and least square means

108. View showing storage yard where material is received and ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

108. View showing storage yard where material is received and sorted: also shows derrick framed to raise material from tracks and land on deck of approach. Material is then moved by narrow gage locomotive out to erection traveler. - Carquinez Bridge, Spanning Carquinez Strait at Interstate 80, Vallejo, Solano County, CA

40. Launch Area, Underground Missile Storage Structure, detail of escape ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

40. Launch Area, Underground Missile Storage Structure, detail of escape hatch and decontamination shower VIEW WEST - NIKE Missile Battery PR-79, Launch Area, East Windsor Road south of State Route 101, Foster, Providence County, RI

Optically-controlled long-term storage and release of thermal energy in phase-change materials.

PubMed

Han, Grace G D; Li, Huashan; Grossman, Jeffrey C

2017-11-13

Thermal energy storage offers enormous potential for a wide range of energy technologies. Phase-change materials offer state-of-the-art thermal storage due to high latent heat. However, spontaneous heat loss from thermally charged phase-change materials to cooler surroundings occurs due to the absence of a significant energy barrier for the liquid-solid transition. This prevents control over the thermal storage, and developing effective methods to address this problem has remained an elusive goal. Herein, we report a combination of photo-switching dopants and organic phase-change materials as a way to introduce an activation energy barrier for phase-change materials solidification and to conserve thermal energy in the materials, allowing them to be triggered optically to release their stored latent heat. This approach enables the retention of thermal energy (about 200 J g -1 ) in the materials for at least 10 h at temperatures lower than the original crystallization point, unlocking opportunities for portable thermal energy storage systems.

Lead-Free Antiferroelectric Silver Niobate Tantalate with High Energy Storage Performance.

PubMed

Zhao, Lei; Liu, Qing; Gao, Jing; Zhang, Shujun; Li, Jing-Feng

2017-08-01

Antiferroelectric materials that display double ferroelectric hysteresis loops are receiving increasing attention for their superior energy storage density compared to their ferroelectric counterparts. Despite the good properties obtained in antiferroelectric La-doped Pb(Zr,Ti)O 3 -based ceramics, lead-free alternatives are highly desired due to the environmental concerns, and AgNbO 3 has been highlighted as a ferrielectric/antiferroelectric perovskite for energy storage applications. Enhanced energy storage performance, with recoverable energy density of 4.2 J cm -3 and high thermal stability of the energy storage density (with minimal variation of ≤±5%) over 20-120 °C, can be achieved in Ta-modified AgNbO 3 ceramics. It is revealed that the incorporation of Ta to the Nb site can enhance the antiferroelectricity because of the reduced polarizability of B-site cations, which is confirmed by the polarization hysteresis, dielectric tunability, and selected-area electron diffraction measurements. Additionally, Ta addition in AgNbO 3 leads to decreased grain size and increased bulk density, increasing the dielectric breakdown strength, up to 240 kV cm -1 versus 175 kV cm -1 for the pure counterpart, together with the enhanced antiferroelectricity, accounting for the high energy storage density. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Composite materials for thermal energy storage: enhancing performance through microstructures.

PubMed

Ge, Zhiwei; Ye, Feng; Ding, Yulong

2014-05-01

Chemical incompatibility and low thermal conductivity issues of molten-salt-based thermal energy storage materials can be addressed by using microstructured composites. Using a eutectic mixture of lithium and sodium carbonates as molten salt, magnesium oxide as supporting material, and graphite as thermal conductivity enhancer, the microstructural development, chemical compatibility, thermal stability, thermal conductivity, and thermal energy storage performance of composite materials are investigated. The ceramic supporting material is essential for preventing salt leakage and hence provides a solution to the chemical incompatibility issue. The use of graphite gives a significant enhancement on the thermal conductivity of the composite. Analyses suggest that the experimentally observed microstructural development of the composite is associated with the wettability of the salt on the ceramic substrate and that on the thermal conduction enhancer. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

High-temperature molten salt thermal energy storage systems for solar applications

NASA Astrophysics Data System (ADS)

Petri, R. J.; Claar, T. D.

1980-03-01

Alkali and alkaline earth carbonate latent-heat storage salts, metallic containment materials, and thermal conductivity enhancement materials were investigated to satisfy the high temperature (704 to 871 C) thermal energy storage requirements of advanced solar-thermal power generation concepts are described. Properties of the following six salts selected for compatibility studies are given: three pure carbonates, K2CO3, Li2CO3 and Na2CO3; two eutectic mixtures, BaCO3/Na2CO3 and K2CO3/NaCO3, and one off-eutectic mixture of Na2CO3/K2CO3.

High-temperature molten salt thermal energy storage systems for solar applications

NASA Technical Reports Server (NTRS)

Petri, R. J.; Claar, T. D.

1980-01-01

Alkali and alkaline earth carbonate latent-heat storage salts, metallic containment materials, and thermal conductivity enhancement materials were investigated to satisfy the high temperature (704 to 871 C) thermal energy storage requirements of advanced solar-thermal power generation concepts are described. Properties of the following six salts selected for compatibility studies are given: three pure carbonates, K2CO3, Li2CO3 and Na2CO3; two eutectic mixtures, BaCO3/Na2CO3 and K2CO3/NaCO3, and one off-eutectic mixture of Na2CO3/K2CO3.

42. Launch Area, Underground Missile Storage Structure, detail of escape ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

42. Launch Area, Underground Missile Storage Structure, detail of escape hatch, elevator and air vent VIEW SOUTH - NIKE Missile Battery PR-79, Launch Area, East Windsor Road south of State Route 101, Foster, Providence County, RI

36. Launch Area, Underground Missile Storage Structure, detail showing elevator, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

36. Launch Area, Underground Missile Storage Structure, detail showing elevator, air ventilators and personnel entrance VIEW SOUTHEAST - NIKE Missile Battery PR-79, Launch Area, East Windsor Road south of State Route 101, Foster, Providence County, RI

Multifunctional composites for energy storage

NASA Astrophysics Data System (ADS)

Shuvo, Mohammad Arif I.; Karim, Hasanul; Rajib, Md; Delfin, Diego; Lin, Yirong

2014-03-01

Electrochemical super-capacitors have become one of the most important topics in both academia and industry as novel energy storage devices because of their high power density, long life cycles, and high charge/discharge efficiency. Recently, there has been an increasing interest in the development of multifunctional structural energy storage devices such as structural super-capacitors for applications in aerospace, automobiles and portable electronics. These multifunctional structural super-capacitors provide lighter structures combining energy storage and load bearing functionalities. Due to their superior materials properties, carbon fiber composites have been widely used in structural applications for aerospace and automotive industries. Besides, carbon fiber has good electrical conductivity which will provide lower equivalent series resistance; therefore, it can be an excellent candidate for structural energy storage applications. Hence, this paper is focused on performing a pilot study for using nanowire/carbon fiber hybrids as building materials for structural energy storage materials; aiming at enhancing the charge/discharge rate and energy density. This hybrid material combines the high specific surface area of carbon fiber and pseudo-capacitive effect of metal oxide nanowires which were grown hydrothermally in an aligned fashion on carbon fibers. The aligned nanowire array could provide a higher specific surface area that leads to high electrode-electrolyte contact area and fast ion diffusion rates. Scanning Electron Microscopy (SEM) and XRay Diffraction (XRD) measurements were used for the initial characterization of this nanowire/carbon fiber hybrid material system. Electrochemical testing has been performed using a potentio-galvanostat. The results show that gold sputtered nanowire hybrid carbon fiber provides 65.9% better performance than bare carbon fiber cloth as super-capacitor.

Structural design of graphene for use in electrochemical energy storage devices.

PubMed

Chen, Kunfeng; Song, Shuyan; Liu, Fei; Xue, Dongfeng

2015-10-07

There are many practical challenges in the use of graphene materials as active components in electrochemical energy storage devices. Graphene has a much lower capacitance than the theoretical capacitance of 550 F g(-1) for supercapacitors and 744 mA h g(-1) for lithium ion batteries. The macroporous nature of graphene limits its volumetric energy density and the low packing density of graphene-based electrodes prevents its use in commercial applications. Increases in the capacity, energy density and power density of electroactive graphene materials are strongly dependent on their microstructural properties, such as the number of defects, stacking, the use of composite materials, conductivity, the specific surface area and the packing density. The structural design of graphene electrode materials is achieved via six main strategies: the design of non-stacking and three-dimensional graphene; the synthesis of highly packed graphene; the production of graphene with a high specific surface area and high conductivity; the control of defects; functionalization with O, N, B or P heteroatoms; and the formation of graphene composites. These methodologies of structural design are needed for fast electrical charge storage/transfer and the transport of electrolyte ions (Li(+), H(+), K(+), Na(+)) in graphene electrodes. We critically review state-of-the-art progress in the optimization of the electrochemical performance of graphene-based electrode materials. The structure of graphene needs to be designed to develop novel electrochemical energy storage devices that approach the theoretical charge limit of graphene and to deliver electrical energy rapidly and efficiently.

Do encapsulated heat storage materials really retain their original thermal properties?

PubMed

Chaiyasat, Preeyaporn; Noppalit, Sayrung; Okubo, Masayoshi; Chaiyasat, Amorn

2015-01-14

The encapsulation of Rubitherm®27 (RT27), which is one of the most common commercially supplied heat storage materials, by polystyrene (PS), polydivinyl benzene (PDVB) and polymethyl methacrylate (PMMA) was carried out using conventional radical microsuspension polymerization. The products were purified to remove free RT27 and free polymer particles without RT27. In the cases of PS and PDVB microcapsules, the latent heats of melting and crystallization for RT27 ( and , J/g-RT27) were clearly decreased by the encapsulation. On the other hand, those of the PMMA microcapsules were the same as pure RT27. A supercooling phenomenon was observed not only for PS and PDVB but also for the PMMA microcapsules. These results indicate that the thermal properties of the heat storage materials encapsulated depend on the type of polymer shells, i.e., encapsulation by polymer shell changes the thermal properties of RT27. This is quite different from the idea of other groups in the world, in which they discussed the thermal properties based on the ΔHm and ΔHc values expressed in J/g-capsule, assuming that the thermal properties of the heat storage materials are not changed by the encapsulation. Hereafter, this report should raise an alarm concerning the "wrong" common knowledge behind developing the encapsulation technology of heat storage materials.

Closure Report for Corrective Action Unit 166: Storage Yards and Contaminated Materials, Nevada Test Site, Nevada

DOE Office of Scientific and Technical Information (OSTI.GOV)

NSTec Environmental Restoration

2009-08-01

Corrective Action Unit (CAU) 166 is identified in the Federal Facility Agreement and Consent Order (FFACO) as 'Storage Yards and Contaminated Materials' and consists of the following seven Corrective Action Sites (CASs), located in Areas 2, 3, 5, and 18 of the Nevada Test Site: CAS 02-42-01, Condo Release Storage Yd - North; CAS 02-42-02, Condo Release Storage Yd - South; CAS 02-99-10, D-38 Storage Area; CAS 03-42-01, Conditional Release Storage Yard; CAS 05-19-02, Contaminated Soil and Drum; CAS 18-01-01, Aboveground Storage Tank; and CAS 18-99-03, Wax Piles/Oil Stain. Closure activities were conducted from March to July 2009 according tomore » the FF ACO (1996, as amended February 2008) and the Corrective Action Plan for CAU 166 (U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office, 2007b). The corrective action alternatives included No Further Action and Clean Closure. Closure activities are summarized. CAU 166, Storage Yards and Contaminated Materials, consists of seven CASs in Areas 2, 3, 5, and 18 of the NTS. The closure alternatives included No Further Action and Clean Closure. This CR provides a summary of completed closure activities, documentation of waste disposal, and confirmation that remediation goals were met. The following site closure activities were performed at CAU 166 as documented in this CR: (1) At CAS 02-99-10, D-38 Storage Area, approximately 40 gal of lead shot were removed and are currently pending treatment and disposal as MW, and approximately 50 small pieces of DU were removed and disposed as LLW. (2) At CAS 03-42-01, Conditional Release Storage Yard, approximately 7.5 yd{sup 3} of soil impacted with lead and Am-241 were removed and disposed as LLW. As a BMP, approximately 22 ft{sup 3} of asbestos tile were removed from a portable building and disposed as ALLW, approximately 55 gal of oil were drained from accumulators and are currently pending disposal as HW, the portable building was removed and

Strongly coupled inorganic-nano-carbon hybrid materials for energy storage.

PubMed

Wang, Hailiang; Dai, Hongjie

2013-04-07

The global shift of energy production from fossil fuels to renewable energy sources requires more efficient and reliable electrochemical energy storage devices. In particular, the development of electric or hydrogen powered vehicles calls for much-higher-performance batteries, supercapacitors and fuel cells than are currently available. In this review, we present an approach to synthesize electrochemical energy storage materials to form strongly coupled hybrids (SC-hybrids) of inorganic nanomaterials and novel graphitic nano-carbon materials such as carbon nanotubes and graphene, through nucleation and growth of nanoparticles at the functional groups of oxidized graphitic nano-carbon. We show that the inorganic-nano-carbon hybrid materials represent a new approach to synthesize electrode materials with higher electrochemical performance than traditional counterparts made by simple physical mixtures of electrochemically active inorganic particles and conducting carbon materials. The inorganic-nano-carbon hybrid materials are novel due to possible chemical bonding between inorganic nanoparticles and oxidized carbon, affording enhanced charge transport and increased rate capability of electrochemical materials without sacrificing specific capacity. Nano-carbon with various degrees of oxidation provides a novel substrate for nanoparticle nucleation and growth. The interactions between inorganic precursors and oxidized-carbon substrates provide a degree of control over the morphology, size and structure of the resulting inorganic nanoparticles. This paper reviews the recent development of inorganic-nano-carbon hybrid materials for electrochemical energy storage and conversion, including the preparation and functionalization of graphene sheets and carbon nanotubes to impart oxygen containing groups and defects, and methods of synthesis of nanoparticles of various morphologies on oxidized graphene and carbon nanotubes. We then review the applications of the SC

Thermal energy storage for smart grid applications

NASA Astrophysics Data System (ADS)

Al-Hallaj, Said; Khateeb, Siddique; Aljehani, Ahmed; Pintar, Mike

2018-01-01

Energy consumption for commercial building cooling accounts for 15% of all commercial building's electricity usage [1]. Electric utility companies charge their customers time of use consumption charges (/kWh) and additionally demand usage charges (/kW) to limit peak energy consumption and offset their high operating costs. Thus, there is an economic incentive to reduce both the electricity consumption charges and demand charges by developing new energy efficient technologies. Thermal energy storage (TES) systems using a phase change material (PCM) is one such technology that can reduce demand charges and shift the demand from on-peak to off-peak rates. Ice and chilled water have been used in thermal storage systems for many decades, but they have certain limitations, which include a phase change temperature of 0 degrees Celsius and relatively low thermal conductivity in comparison to other materials, which limit their applications as a storage medium. To overcome these limitations, a novel phase change composite (PCC) TES material was developed that has much higher thermal conductivity that significantly improves the charge / discharge rate and a customizable phase change temperature to allow for better integration with HVAC systems. Compared to ice storage, the PCC TES system is capable of very high heat transfer rate and has lower system and operational costs. Economic analysis was performed to compare the PCC TES system with ice system and favorable economics was proven. A 4.5 kWh PCC TES prototype system was also designed for testing and validation purpose.

Method of encapsulating solid radioactive waste material for storage

DOEpatents

Bunnell, Lee Roy; Bates, J. Lambert

1976-01-01

High-level radioactive wastes are encapsulated in vitreous carbon for long-term storage by mixing the wastes as finely divided solids with a suitable resin, formed into an appropriate shape and cured. The cured resin is carbonized by heating under a vacuum to form vitreous carbon. The vitreous carbon shapes may be further protected for storage by encasement in a canister containing a low melting temperature matrix material such as aluminum to increase impact resistance and improve heat dissipation.

Energy Conversion and Storage Program

NASA Astrophysics Data System (ADS)

Cairns, E. J.

1993-06-01

This report is the 1992 annual progress report for the Energy Conversion and Storage Program, a part of the Energy and Environment Division of the Lawrence Berkeley Laboratory. Work described falls into three broad areas: electrochemistry; chemical applications; and materials applications. The Energy Conversion and Storage Program applies principles of chemistry and materials science to solve problems in several areas: (1) production of new synthetic fuels, (2) development of high-performance rechargeable batteries and fuel cells, (3) development of advanced thermochemical processes for energy conversion, (4) characterization of complex chemical processes and chemical species, and (5) study and application of novel materials for energy conversion and transmission. Projects focus on transport-process principles, chemical kinetics, thermodynamics, separation processes, organic and physical chemistry, novel materials, and advanced methods of analysis. Electrochemistry research aims to develop advanced power systems for electric vehicle and stationary energy storage applications. Chemical applications research includes topics such as separations, catalysis, fuels, and chemical analyses. Included in this program area are projects to develop improved, energy-efficient methods for processing product and waste streams from synfuel plants, coal gasifiers, and biomass conversion processes. Materials applications research includes evaluation of the properties of advanced materials, as well as development of novel preparation techniques. For example, techniques such as sputtering, laser ablation, and poised laser deposition are being used to produce high-temperature superconducting films.

Effect of reservoir storage on peak flow

USGS Publications Warehouse

Mitchell, William D.

1962-01-01

For observation of small-basin flood peaks, numerous crest-stage gages now are operated at culverts in roadway embankments. To the extent that they obstruct the natural flood plains of the streams, these embankments serve to create detention reservoirs, and thus to reduce the magnitude of observed peak flows. Hence, it is desirable to obtain a factor, I/O, by which the observed outflow peaks may be adjusted to corresponding inflow peaks. The problem is made more difficult by the fact that, at most of these observation sites, only peak stages and discharges are observed, and complete hydrographs are not available. It is postulated that the inflow hydrographs may be described in terms of Q, the instantaneous discharge; A, the size of drainage area; Pe, the amount of rainfall excess; H, the time from beginning of rainfall excess; D, the duration of rainfall excess; and T and k, characteristic times for the drainage area, and indicative of the time lag between rainfall and runoff. These factors are combined into the dimensionless ratios (QT/APe), (H/T), (k/T), and (D/T), leading to families of inflow hydrographs in which the first ratio is the ordinate, the second is the abscissa, and the third and fourth are distinguishing parameters. Sixteen dimensionless inflow hydrographs have been routed through reservoir storage to obtain 139 corresponding outflow hydrographs. In most of the routings it has been assumed that the storage-outflow relation is linear; that is, that storage is some constant, K, times the outflow. The existence of nonlinear storage is recognized, and exploratory nonlinear routings are described, but analyses and conclusions are confined to the problems of linear storage. Comparisons between inflow hydrographs and outflow hydrographs indicate that, at least for linear storage, I/O=f(k/T, D/T, K/T) in which I and O are, respectively, the magnitudes of the inflow and the outflow peaks, and T, k, D, and K are as defined above. Diagrams are presented to

Underground storage of imported water in the San Gorgonio Pass area, southern California

USGS Publications Warehouse

Bloyd, Richard M.

1971-01-01

The San Gorgonio Pass ground-water basin is divided into the Beaumont, Banning, Cabazon, San Timoteo, South Beaumont, Banning Bench, and Singleton storage units. The Beaumont storage unit, centrally located in the agency area, is the largest in volume of the storage units. Estimated long-term average annual precipitation in the San Gorgonio Pass Water Agency drainage area is 332,000 acre-feet, and estimated average annual recoverable water is 24,000 acre-feet, less than 10 percent of the total precipitation. Estimated average annual surface outflow is 1,700 acre-feet, and estimated average annual ground-water recharge is 22,000 acre-feet. Projecting tack to probable steady-state conditions, of the 22.000 acre-feet of recharge, 16,003 acre-feet per year became subsurface outflow into Coachella Valley, 6,000 acre-feet into the Redlands area, and 220 acre-feet into Potrero Canyon. After extensive development, estimated subsurface outflow from the area in 1967 was 6,000 acre-feet into the Redlands area, 220 acre-feet into Potrero Canyon, and 800 acre-feet into the fault systems south of the Banning storage unit, unwatered during construction of a tunnel. Subsurface outflow into Coachella Valley in 1967 is probably less than 50 percent of the steady-state flow. An anticipated 17,000 .acre-feet of water per year will be imported by 1980. Information developed in this study indicates it is technically feasible to store imported water in the eastern part of the Beaumont storage unit without causing waterlogging in the storage area and without losing any significant quantity of stored water.

3. SHOP AREA. Looking west into storage cage from near ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. SHOP AREA. Looking west into storage cage from near northeast corner of room. - Edwards Air Force Base, Air Force Rocket Propulsion Laboratory, Test Stand 1-A Terminal Room, Test Area 1-120, north end of Jupiter Boulevard, Boron, Kern County, CA

Chemically Integrated Inorganic-Graphene Two-Dimensional Hybrid Materials for Flexible Energy Storage Devices.

PubMed

Peng, Lele; Zhu, Yue; Li, Hongsen; Yu, Guihua

2016-12-01

State-of-the-art energy storage devices are capable of delivering reasonably high energy density (lithium ion batteries) or high power density (supercapacitors). There is an increasing need for these power sources with not only superior electrochemical performance, but also exceptional flexibility. Graphene has come on to the scene and advancements are being made in integration of various electrochemically active compounds onto graphene or its derivatives so as to utilize their flexibility. Many innovative synthesis techniques have led to novel graphene-based hybrid two-dimensional nanostructures. Here, the chemically integrated inorganic-graphene hybrid two-dimensional materials and their applications for energy storage devices are examined. First, the synthesis and characterization of different kinds of inorganic-graphene hybrid nanostructures are summarized, and then the most relevant applications of inorganic-graphene hybrid materials in flexible energy storage devices are reviewed. The general design rules of using graphene-based hybrid 2D materials for energy storage devices and their current limitations and future potential to advance energy storage technologies are also discussed. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Superior pseudocapacitive behavior of confined lignin nanocrystals for renewable energy-storage materials.

PubMed

Kim, Sung-Kon; Kim, Yun Ki; Lee, Hyunjoo; Lee, Sang Bok; Park, Ho Seok

2014-04-01

Strong demand for high-performance energy-storage devices has currently motivated the development of emerging capacitive materials that can resolve their critical challenge (i.e., low energy density) and that are renewable and inexpensive energy-storage materials from both environmental and economic viewpoints. Herein, the pseudocapacitive behavior of lignin nanocrystals confined on reduced graphene oxides (RGOs) used for renewable energy-storage materials is demonstrated. The excellent capacitive characteristics of the renewable hybrid electrodes were achieved by synergizing the fast and reversible redox charge transfer of surface-confined quinone and the interplay with electron-conducting RGOs. Accordingly, pseudocapacitors with remarkable rate and cyclic performances (~96 % retention after 3000 cycles) showed a maximum capacitance of 432 F g(-1), which was close to the theoretical capacitance of 482 F g(-1) and sixfold higher than that of RGO (93 F g(-1)). The chemical strategy delineated herein paves the way to develop advanced renewable electrodes for energy-storage applications and understand the redox chemistry of electroactive biomaterials. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Storage of nuclear materials by encapsulation in fullerenes

DOEpatents

Coppa, Nicholas V.

1994-01-01

A method of encapsulating radioactive materials inside fullerenes for stable long-term storage. Fullerenes provide a safe and efficient means of disposing of nuclear waste which is extremely stable with respect to the environment. After encapsulation, a radioactive ion is essentially chemically isolated from its external environment.

Corrosion resistant storage container for radioactive material

DOEpatents

Schweitzer, Donald G.; Davis, Mary S.

1990-01-01

A corrosion resistant long-term storage container for isolating radioactive waste material in a repository. The container is formed of a plurality of sealed corrosion resistant canisters of different relative sizes, with the smaller canisters housed within the larger canisters, and with spacer means disposed between judxtaposed pairs of canisters to maintain a predetermined spacing between each of the canisters. The combination of the plural surfaces of the canisters and the associated spacer means is effective to make the container capable of resisting corrosion, and thereby of preventing waste material from leaking from the innermost canister into the ambient atmosphere.

Application of Ionic Liquids to Energy Storage and Conversion Materials and Devices.

PubMed

Watanabe, Masayoshi; Thomas, Morgan L; Zhang, Shiguo; Ueno, Kazuhide; Yasuda, Tomohiro; Dokko, Kaoru

2017-05-24

Ionic liquids (ILs) are liquids consisting entirely of ions and can be further defined as molten salts having melting points lower than 100 °C. One of the most important research areas for IL utilization is undoubtedly their energy application, especially for energy storage and conversion materials and devices, because there is a continuously increasing demand for clean and sustainable energy. In this article, various application of ILs are reviewed by focusing on their use as electrolyte materials for Li/Na ion batteries, Li-sulfur batteries, Li-oxygen batteries, and nonhumidified fuel cells and as carbon precursors for electrode catalysts of fuel cells and electrode materials for batteries and supercapacitors. Due to their characteristic properties such as nonvolatility, high thermal stability, and high ionic conductivity, ILs appear to meet the rigorous demands/criteria of these various applications. However, for further development, specific applications for which these characteristic properties become unique (i.e., not easily achieved by other materials) must be explored. Thus, through strong demands for research and consideration of ILs unique properties, we will be able to identify indispensable applications for ILs.

Risk ranking of LANL nuclear material storage containers for repackaging prioritization.

PubMed

Smith, Paul H; Jordan, Hans; Hoffman, Jenifer A; Eller, P Gary; Balkey, Simon

2007-05-01

Safe handling and storage of nuclear material at U.S. Department of Energy facilities relies on the use of robust containers to prevent container breaches and subsequent worker contamination and uptake. The U.S. Department of Energy has no uniform requirements for packaging and storage of nuclear materials other than those declared excess and packaged to DOE-STD-3013-2000. This report describes a methodology for prioritizing a large inventory of nuclear material containers so that the highest risk containers are repackaged first. The methodology utilizes expert judgment to assign respirable fractions and reactivity factors to accountable levels of nuclear material at Los Alamos National Laboratory. A relative risk factor is assigned to each nuclear material container based on a calculated dose to a worker due to a failed container barrier and a calculated probability of container failure based on material reactivity and container age. This risk-based methodology is being applied at LANL to repackage the highest risk materials first and, thus, accelerate the reduction of risk to nuclear material handlers.

Phase change material storage heater

DOEpatents

Goswami, D. Yogi; Hsieh, Chung K.; Jotshi, Chand K.; Klausner, James F.

1997-01-01

A storage heater for storing heat and for heating a fluid, such as water, has an enclosure defining a chamber therein. The chamber has a lower portion and an upper portion with a heating element being disposed within the enclosure. A tube through which the fluid flows has an inlet and an outlet, both being disposed outside of the enclosure, and has a portion interconnecting the inlet and the outlet that passes through the enclosure. A densely packed bed of phase change material pellets is disposed within the enclosure and is surrounded by a viscous liquid, such as propylene glycol. The viscous liquid is in thermal communication with the heating element, the phase change material pellets, and the tube and transfers heat from the heating element to the pellets and from the pellets to the tube. The viscous fluid has a viscosity so that the frictional pressure drop of the fluid in contact with the phase change material pellets substantially reduces vertical thermal convection in the fluid. As the fluid flows through the tube heat is transferred from the viscous liquid to the fluid flowing through the tube, thereby heating the fluid.

Stability of flavoured phytosterol-enriched drinking yogurts during storage as affected by different packaging materials.

PubMed

Semeniuc, Cristina Anamaria; Cardenia, Vladimiro; Mandrioli, Mara; Muste, Sevastiţa; Borsari, Andrea; Rodriguez-Estrada, Maria Teresa

2016-06-01

The aim of this study was to investigate the influence of different packaging materials on storage stability of flavoured phytosterol-enriched drinking yogurts. White vanilla (WV) and blood orange (BO) phytosterol-enriched drinking yogurts conditioned in mono-layer and triple-layer co-extruded plastic bottles were stored at +6 ± 1 °C for 35 days (under alternating 12 h light and 12 h darkness) to simulate shelf-life conditions. Samples were collected at three different storage times and subjected to determination of total sterol content (TSC), peroxide value (PV) and thiobarbituric acid reactive substances (TBARs). TSC was not significantly affected by packaging material or storage time and met the quantity declared on the label. PV was significantly influenced by yogurt type × packaging material × storage time interaction and TBARs by packaging material × storage time interaction. Between the two packaging materials, the triple-layer plastic mini bottle with black coloured and completely opaque intermediate layer offered the best protection against lipid oxidation. © 2015 Society of Chemical Industry. © 2015 Society of Chemical Industry.

Hydrogen storage materials discovery via high throughput ball milling and gas sorption.

PubMed

Li, Bin; Kaye, Steven S; Riley, Conor; Greenberg, Doron; Galang, Daniel; Bailey, Mark S

2012-06-11

The lack of a high capacity hydrogen storage material is a major barrier to the implementation of the hydrogen economy. To accelerate discovery of such materials, we have developed a high-throughput workflow for screening of hydrogen storage materials in which candidate materials are synthesized and characterized via highly parallel ball mills and volumetric gas sorption instruments, respectively. The workflow was used to identify mixed imides with significantly enhanced absorption rates relative to Li2Mg(NH)2. The most promising material, 2LiNH2:MgH2 + 5 atom % LiBH4 + 0.5 atom % La, exhibits the best balance of absorption rate, capacity, and cycle-life, absorbing >4 wt % H2 in 1 h at 120 °C after 11 absorption-desorption cycles.

Recent Development of Advanced Electrode Materials by Atomic Layer Deposition for Electrochemical Energy Storage.

PubMed

Guan, Cao; Wang, John

2016-10-01

Electrode materials play a decisive role in almost all electrochemical energy storage devices, determining their overall performance. Proper selection, design and fabrication of electrode materials have thus been regarded as one of the most critical steps in achieving high electrochemical energy storage performance. As an advanced nanotechnology for thin films and surfaces with conformal interfacial features and well controllable deposition thickness, atomic layer deposition (ALD) has been successfully developed for deposition and surface modification of electrode materials, where there are considerable issues of interfacial and surface chemistry at atomic and nanometer scale. In addition, ALD has shown great potential in construction of novel nanostructured active materials that otherwise can be hardly obtained by other processing techniques, such as those solution-based processing and chemical vapor deposition (CVD) techniques. This review focuses on the recent development of ALD for the design and delivery of advanced electrode materials in electrochemical energy storage devices, where typical examples will be highlighted and analyzed, and the merits and challenges of ALD for applications in energy storage will also be discussed.

Recent Development of Advanced Electrode Materials by Atomic Layer Deposition for Electrochemical Energy Storage

PubMed Central

2016-01-01

Electrode materials play a decisive role in almost all electrochemical energy storage devices, determining their overall performance. Proper selection, design and fabrication of electrode materials have thus been regarded as one of the most critical steps in achieving high electrochemical energy storage performance. As an advanced nanotechnology for thin films and surfaces with conformal interfacial features and well controllable deposition thickness, atomic layer deposition (ALD) has been successfully developed for deposition and surface modification of electrode materials, where there are considerable issues of interfacial and surface chemistry at atomic and nanometer scale. In addition, ALD has shown great potential in construction of novel nanostructured active materials that otherwise can be hardly obtained by other processing techniques, such as those solution‐based processing and chemical vapor deposition (CVD) techniques. This review focuses on the recent development of ALD for the design and delivery of advanced electrode materials in electrochemical energy storage devices, where typical examples will be highlighted and analyzed, and the merits and challenges of ALD for applications in energy storage will also be discussed. PMID:27840793

Effect of Packaging Materials on Orthosiphon Stamineus Dried-Leaf Quality During Storage

NASA Astrophysics Data System (ADS)

Norawanis, A. R.; Shaari, A. R.; Leng, L. Y.

2018-03-01

The experiment was conducted to determine the effects on the total phenolic content, antioxidant capacity, moisture content and total different color (ΔE) when the O. stamineus dried whole-leaf were packed in different packaging materials (plastic bag, paper bag and glass container) and stored under room temperature (±25 °C) and relative humidity (±65 %RH) for 8 weeks. The total phenolic compounds and antioxidant activity were measured using the Folin-Ciocalteu method and 2,2-diphenyl-1-picrylhydrazyl (DPPH) free radical scavenging activity assay respectively, and analyzed using UV/VIS Spectrophotometer. The moisture content changes were examined using a moisture analyzer and the color changes were analyzed using colorimeter. The results showed that packing O. stamineus dried whole-leaf in different packaging materials significantly affected the herbal leaves quality. After 8 weeks of storage period, the total phenolic content and antioxidant capacity exhibited the increase values during storage. Meanwhile, the moisture content of the samples decreased by storage period for the samples packed in plastic bag and glass container. The moisture content of the samples packed in the paper bag fluctuated along the 8 weeks of storage period. The total different color (ΔE) of the O. stamineus dried whole-leaf increased by storage period. The highest changes of ΔE belonged to the samples packed in the glass container, followed by paper and plastic bags. The selection of the packaging materials can be considered as an important element to control the quality of raw herbal materials for further processing and the herbal finished products.

Electrodes and electrochemical storage cells utilizing tin-modified active materials

DOEpatents

Anani, Anaba; Johnson, John; Lim, Hong S.; Reilly, James; Schwarz, Ricardo; Srinivasan, Supramaniam

1995-01-01

An electrode has a substrate and a finely divided active material on the substrate. The active material is ANi.sub.x-y-z Co.sub.y Sn.sub.z, wherein A is a mischmetal or La.sub.1-w M.sub.w, M is Ce, Nd, or Zr, w is from about 0.05 to about 1.0, x is from about 4.5 to about 5.5, y is from 0 to about 3.0, and z is from about 0.05 to about 0.5. An electrochemical storage cell utilizes such an electrode as the anode. The storage cell further has a cathode, a separator between the cathode and the anode, and an electrolyte.

Cleaning residual NaK in the fast flux test facility fuel storage cooling system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Burke, T.M.; Church, W.R.; Hodgson, K.M.

2008-01-15

The Fast Flux Test Facility (FFTF), located on the U.S. Department of Energy's Hanford Reservation, is a liquid metal-cooled test reactor. The FFTF was constructed to support the U.S. Liquid Metal Fast Breeder Reactor Program. The bulk of the alkali metal (sodium and NaK) has been drained and will be stored onsite prior to final disposition. Residual NaK needed to be removed from the pipes, pumps, heat exchangers, tanks, and vessels in the Fuel Storage Facility (FSF) cooling system. The cooling system was drained in 2004 leaving residual NaK in the pipes and equipment. The estimated residual NaK volume wasmore » 76 liters in the storage tank, 1.9 liters in the expansion tank, and 19-39 liters in the heat transfer loop. The residual NaK volume in the remainder of the system was expected to be very small, consisting of films, droplets, and very small pools. The NaK in the FSF Cooling System was not radiologically contaminated. The portions of the cooling system to be cleaned were divided into four groups: 1. The storage tank, filter, pump, and associated piping; 2. The heat exchanger, expansion tank, and associated piping; 3. Argon supply piping; 4. In-vessel heat transfer loop. The cleaning was contracted to Creative Engineers, Inc. (CEI) and they used their superheated steam process to clean the cooling system. It has been concluded that during the modification activities (prior to CEI coming onsite) to prepare the NaK Cooling System for cleaning, tank T-914 was pressurized relative to the In-Vessel NaK Cooler and NaK was pushed from the tank back into the Cooler and that on November 6, 2005, when the gas purge through the In-Vessel NaK Cooler was increased from 141.6 slm to 283.2 slm, NaK was forced from the In-Vessel NaK Cooler and it contacted water in the vent line and/or scrubber. The gases from the reaction then traveled back through the vent line coating the internal surface of the vent line with NaK and NaK reaction products. The hot gases also exited the

20. DECOMMISIONED HYDROGEN TANK IN FORMER LIQUID OXYGEN STORAGE AREA, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

20. DECOMMISIONED HYDROGEN TANK IN FORMER LIQUID OXYGEN STORAGE AREA, BETWEEN TEST STAND 1-A AND INSTRUMENTATION AND CONTROL BUILDING. Looking northwest. - Edwards Air Force Base, Air Force Rocket Propulsion Laboratory, Test Stand 1-A, Test Area 1-120, north end of Jupiter Boulevard, Boron, Kern County, CA

Redox flow cell energy storage systems

NASA Technical Reports Server (NTRS)

Thaller, L. H.

1979-01-01

The redox flow cell energy storage system being developed by NASA for use in remote power systems and distributed storage installations for electric utilities is presented. The system under consideration is an electrochemical storage device which utilizes the oxidation and reduction of two fully soluble redox couples (acidified chloride solutions of chromium and iron) as active electrode materials separated by a highly selective ion exchange membrane. The reactants are contained in large storage tanks and pumped through a stack of redox flow cells where the electrochemical reactions take place at porous carbon felt electrodes. Redox equipment has allowed the incorporation of state of charge readout, stack voltage control and system capacity maintenance (rebalance) devices to regulate cells in a stack jointly. A 200 W, 12 V system with a capacity of about 400 Wh has been constructed, and a 2 kW, 10kWh system is planned.

Progress on first-principles-based materials design for hydrogen storage.

PubMed

Park, Noejung; Choi, Keunsu; Hwang, Jeongwoon; Kim, Dong Wook; Kim, Dong Ok; Ihm, Jisoon

2012-12-04

This article briefly summarizes the research activities in the field of hydrogen storage in sorbent materials and reports our recent works and future directions for the design of such materials. Distinct features of sorption-based hydrogen storage methods are described compared with metal hydrides and complex chemical hydrides. We classify the studies of hydrogen sorbent materials in terms of two key technical issues: (i) constructing stable framework structures with high porosity, and (ii) increasing the binding affinity of hydrogen molecules to surfaces beyond the usual van der Waals interaction. The recent development of reticular chemistry is summarized as a means for addressing the first issue. Theoretical studies focus mainly on the second issue and can be grouped into three classes according to the underlying interaction mechanism: electrostatic interactions based on alkaline cations, Kubas interactions with open transition metals, and orbital interactions involving Ca and other nontransitional metals. Hierarchical computational methods to enable the theoretical predictions are explained, from ab initio studies to molecular dynamics simulations using force field parameters. We also discuss the actual delivery amount of stored hydrogen, which depends on the charging and discharging conditions. The usefulness and practical significance of the hydrogen spillover mechanism in increasing the storage capacity are presented as well.

Progress on first-principles-based materials design for hydrogen storage

PubMed Central

Park, Noejung; Choi, Keunsu; Hwang, Jeongwoon; Kim, Dong Wook; Kim, Dong Ok; Ihm, Jisoon

2012-01-01

This article briefly summarizes the research activities in the field of hydrogen storage in sorbent materials and reports our recent works and future directions for the design of such materials. Distinct features of sorption-based hydrogen storage methods are described compared with metal hydrides and complex chemical hydrides. We classify the studies of hydrogen sorbent materials in terms of two key technical issues: (i) constructing stable framework structures with high porosity, and (ii) increasing the binding affinity of hydrogen molecules to surfaces beyond the usual van der Waals interaction. The recent development of reticular chemistry is summarized as a means for addressing the first issue. Theoretical studies focus mainly on the second issue and can be grouped into three classes according to the underlying interaction mechanism: electrostatic interactions based on alkaline cations, Kubas interactions with open transition metals, and orbital interactions involving Ca and other nontransitional metals. Hierarchical computational methods to enable the theoretical predictions are explained, from ab initio studies to molecular dynamics simulations using force field parameters. We also discuss the actual delivery amount of stored hydrogen, which depends on the charging and discharging conditions. The usefulness and practical significance of the hydrogen spillover mechanism in increasing the storage capacity are presented as well. PMID:23161910

Multiscale modeling and experimental interpretation of perovskite oxide materials in thermochemical energy storage and conversion for application in concentrating solar power

NASA Astrophysics Data System (ADS)

Albrecht, Kevin J.

Decarbonization of the electric grid is fundamentally limited by the intermittency of renewable resources such as wind and solar. Therefore, energy storage will play a significant role in the future of grid-scale energy generation to overcome the intermittency issues. For this reason, concentrating solar power (CSP) plants have been a renewable energy generation technology of interest due to their ability to participate in cost effective and efficient thermal energy storage. However, the ability to dynamically dispatch a CSP plant to meet energy demands is currently limited by the large quantities of sensible thermal energy storage material needed in a molten salt plant. Perovskite oxides have been suggested as a thermochemical energy storage material to enhance the energy storage capabilities of particle-based CSP plants, which combine sensible and chemical modes of energy storage. In this dissertation, computational models are used to establish the thermochemical energy storage potential of select perovskite compositions, identify system configurations that promote high values of energy storage and solar-to-electric efficiency, assess the kinetic and transport limitation of the chemical mode of energy storage, and create receiver and reoxidation reactor models capable of aiding in component design. A methodology for determining perovskite thermochemical energy storage potential is developed based on point defect models to represent perovskite non-stoichiometry as a function of temperature and gas phase oxygen partial pressure. The thermodynamic parameters necessary for the model are extracted from non-stoichiometry measurements by fitting the model using an optimization routine. The procedure is demonstrated for Ca0.9Sr0.1MnO 3-d which displayed combined energy storage values of 705.7 kJ/kg -1 by cycling between 773 K and 0.21 bar oxygen to 1173 K and 10 -4 bar oxygen. Thermodynamic system-level models capable of exploiting perovskite redox chemistry for energy

21 CFR 225.135 - Work and storage areas.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 21 Food and Drugs 4 2012-04-01 2012-04-01 false Work and storage areas. 225.135 Section 225.135 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) DRUGS..., and other pesticides unless such articles are approved or index listed for use in the manufacture of...

21 CFR 225.135 - Work and storage areas.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 21 Food and Drugs 4 2014-04-01 2014-04-01 false Work and storage areas. 225.135 Section 225.135 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) DRUGS..., and other pesticides unless such articles are approved or index listed for use in the manufacture of...

21 CFR 225.135 - Work and storage areas.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 21 Food and Drugs 4 2010-04-01 2010-04-01 false Work and storage areas. 225.135 Section 225.135 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) DRUGS..., and other pesticides unless such articles are approved or index listed for use in the manufacture of...

21 CFR 225.135 - Work and storage areas.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 21 Food and Drugs 4 2013-04-01 2013-04-01 false Work and storage areas. 225.135 Section 225.135 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) DRUGS..., and other pesticides unless such articles are approved or index listed for use in the manufacture of...

21 CFR 225.135 - Work and storage areas.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 21 Food and Drugs 4 2011-04-01 2011-04-01 false Work and storage areas. 225.135 Section 225.135 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) DRUGS..., and other pesticides unless such articles are approved or index listed for use in the manufacture of...

Corrosion resistant storage container for radioactive material

DOEpatents

Schweitzer, D.G.; Davis, M.S.

1984-08-30

A corrosion resistant long-term storage container for isolating high-level radioactive waste material in a repository is claimed. The container is formed of a plurality of sealed corrosion resistant canisters of different relative sizes, with the smaller canisters housed within the larger canisters, and with spacer means disposed between juxtaposed pairs of canisters to maintain a predetermined spacing between each of the canisters. The combination of the plural surfaces of the canisters and the associated spacer means is effective to make the container capable of resisting corrosion, and thereby of preventing waste material from leaking from the innermost canister into the ambient atmosphere.

Enhanced performance and interfacial investigation of mineral-based composite phase change materials for thermal energy storage.

PubMed

Li, Chuanchang; Fu, Liangjie; Ouyang, Jing; Yang, Huaming

2013-01-01

A novel mineral-based composite phase change materials (PCMs) was prepared via vacuum impregnation method assisted with microwave-acid treatment of the graphite (G) and bentonite (B) mixture. Graphite and microwave-acid treated bentonite mixture (GBm) had more loading capacity and higher crystallinity of stearic acid (SA) in the SA/GBm composite. The SA/GBm composite showed an enhanced thermal storage capacity, latent heats for melting and freezing (84.64 and 84.14 J/g) was higher than those of SA/B sample (48.43 and 47.13 J/g, respectively). Addition of graphite was beneficial to the enhancement in thermal conductivity of the SA/GBm composite, which could reach 0.77 W/m K, 31% higher than SA/B and 196% than pure SA. Furthermore, atomic-level interfaces between SA and support surfaces were depicted, and the mechanism of enhanced thermal storage properties was in detail investigated.

Coupling of exothermic and endothermic hydrogen storage materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brooks, Kriston P.; Bowden, Mark E.; Karkamkar, Abhijeet J.

2016-08-01

Chemical hydrogen storage (CHS) materials are a high-storage-density alternative to the gaseous compressed hydrogen currently used to provide hydrogen for fuel cell vehicles. One of the challenges of CHS materials is addressing the thermodynamic and kinetic barriers required to break the chemical bonds and release the hydrogen. Coupling CHS reactions that are endothermic and exothermic during the dehydrogenation can improve the system on-board energy efficiency and thermal control, making such materials viable. Acceptable coupling between reactions requires both thermodynamic and kinetics considerations. Models were developed to predict the reaction enthalpy and rate required to achieve high conversions for both reactionsmore » based on experimental measurements. These modeling results show that the efficiency of coupling of an exothermic and endothermic reaction is more sensitive the magnitude of the ratio of the exothermic and endothermic enthalpies than the ratio of the rates of the two steps. The modeling shows further that a slower rate of the endothermic step is desirable to permit sufficient heating of the reactor by the exothermic step. We look at two examples of a sequential and parallel reaction scheme and provide some of the first insight into the required temperature range to maximize the H2 release from 1,2-BN cyclohexane and indoline.« less

Large-Area Carbon Nanosheets Doped with Phosphorus: A High-Performance Anode Material for Sodium-Ion Batteries.

PubMed

Hou, Hongshuai; Shao, Lidong; Zhang, Yan; Zou, Guoqiang; Chen, Jun; Ji, Xiaobo

2017-01-01

Large-area phosphorus-doped carbon nanosheets (P-CNSs) are first obtained from carbon dots (CDs) through self-assembly driving from thermal treatment with Na catalysis. This is the first time to realize the conversion from 0D CDs to 2D nanosheets doped with phosphorus. The sodium storage behavior of phosphorus-doped carbon material is also investigated for the first time. As anode material for sodium-ion batteries (SIBs), P-CNSs exhibit superb performances for electrochemical storage of sodium. When cycled at 0.1 A g -1 , the P-CNSs electrode delivers a high reversible capacity of 328 mAh g -1 , even at a high current density of 20 A g -1 , a considerable capacity of 108 mAh g -1 can still be maintained. Besides, this material also shows excellent cycling stability, at a current density of 5 A g -1 , the reversible capacity can still reach 149 mAh g -1 after 5000 cycles. This work will provide significant value for the development of both carbon materials and SIBs anode materials.

National assessment of geologic carbon dioxide storage resources: allocations of assessed areas to Federal lands

USGS Publications Warehouse

Buursink, Marc L.; Cahan, Steven M.; Warwick, Peter D.

2015-01-01

Following the geologic basin-scale assessment of technically accessible carbon dioxide storage resources in onshore areas and State waters of the United States, the U.S. Geological Survey estimated that an area of about 130 million acres (or about 200,000 square miles) of Federal lands overlies these storage resources. Consequently, about 18 percent of the assessed area associated with storage resources is allocated to Federal land management. Assessed areas are allocated to four other general land-ownership categories as follows: State lands about 4.5 percent, Tribal lands about 2.4 percent, private and other lands about 72 percent, and offshore areas about 2.6 percent.

A Framework for Managing Inter-Site Storage Area Networks using Grid Technologies

NASA Technical Reports Server (NTRS)

Kobler, Ben; McCall, Fritz; Smorul, Mike

2006-01-01

The NASA Goddard Space Flight Center and the University of Maryland Institute for Advanced Computer Studies are studying mechanisms for installing and managing Storage Area Networks (SANs) that span multiple independent collaborating institutions using Storage Area Network Routers (SAN Routers). We present a framework for managing inter-site distributed SANs that uses Grid Technologies to balance the competing needs to control local resources, share information, delegate administrative access, and manage the complex trust relationships between the participating sites.

Prediction of thermodynamically reversible hydrogen storage reactions utilizing Ca-M(M = Li, Na, K)-B-H systems: a first-principles study.

PubMed

Guo, Yajuan; Ren, Ying; Wu, Haishun; Jia, Jianfeng

2013-12-01

Calcium borohydride is a potential candidate for onboard hydrogen storage because it has a high gravimetric capacity (11.5 wt.%) and a high volumetric hydrogen content (∼130 kg m(-3)). Unfortunately, calcium borohydride suffers from the drawback of having very strongly bound hydrogen. In this study, Ca(BH₄)₂ was predicted to form a destabilized system when it was mixed with LiBH₄, NaBH₄, or KBH₄. The release of hydrogen from Ca(BH₄)₂ was predicted to proceed via two competing reaction pathways (leading to CaB₆ and CaH₂ or CaB₁₂H₁₂ and CaH₂) that were found to have almost equal free energies. Using a set of recently developed theoretical methods derived from first principles, we predicted five new hydrogen storage reactions that are among the most attractive of those presently known. These combine high gravimetric densities (>6.0 wt.% H₂) with have low enthalpies [approximately 35 kJ/(mol(-1) H₂)] and are thermodynamically reversible at low pressure within the target window for onboard storage that is actively being considered for hydrogen storage applications. Thus, the first-principles theoretical design of new materials for energy storage in future research appears to be possible.

Engineered Materials for Cesium and Strontium Storage Final Technical Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sean M. McDeavitt

2010-04-14

Closing the nuclear fuel cycle requires reprocessing spent fuel to recover the long-lived components that still have useful energy content while immobilizing the remnant waste fission products in stable forms. At the genesis of this project, next generation spent fuel reprocessing methods were being developed as part of the U.S. Department of Energy's Advanced Fuel Cycle Initiative. One of these processes was focused on solvent extraction schemes to isolate cesium (Cs) and strontium (Sr) from spent nuclear fuel. Isolating these isotopes for short-term decay storage eases the design requirements for long-term repository disposal; a significant amount of the radiation andmore » decay heat in fission product waste comes from Cs-137 and Sr-90. For the purposes of this project, the Fission Product Extraction (FPEX) process is being considered to be the baseline extraction method. The objective of this project was to evaluate the nature and behavior of candidate materials for cesium and strontium immobilization; this will include assessments with minor additions of yttrium, barium, and rubidium in these materials. More specifically, the proposed research achieved the following objectives (as stated in the original proposal): (1) Synthesize simulated storage ceramics for Cs and Sr using an existing labscale steam reformer at Purdue University. The simulated storage materials will include aluminosilicates, zirconates and other stable ceramics with the potential for high Cs and Sr loading. (2) Characterize the immobilization performance, phase structure, thermal properties and stability of the simulated storage ceramics. The ceramic products will be stable oxide powders and will be characterized to quantify their leach resistance, phase structure, and thermophysical properties. The research progressed in two stages. First, a steam reforming process was used to generate candidate Cs/Sr storage materials for characterization. This portion of the research was carried out at

Studies of Phase Change Materials and a Latent Heat Storage Unit Used for a Natural Circulation Cooling/Latent Heat Storage System

NASA Astrophysics Data System (ADS)

Sakitani, Katsumi; Honda, Hiroshi

Experiments were performed to investigate feasibility of using organic materials as a PCM for a latent heat storage unit of a natural circulation cooling/latent heat storage system. This system was designed to cool a shelter accommodating telecommunication equipment located in subtropical deserts or similar regions without using a power source. Taking into account practical considerations and the results of various experiments regarding the thermodynamic properties, thermal degradation, and corrosiveness to metals, lauric acid and iron was selected for the PCM and the latent heat storage unit material, respectively. Cyclic heating and cooling of the latent heat storage unit undergoing solid-liquid phase change was repeated for more than 430 days. The results showed that the heating-cooling curve was almost unchanged between the early stage and the 1,870th cycle. It was concluded that the latent heat storage unit could be used safely for more than ten years as a component of the cooling system.

Advanced materials and concepts for energy storage devices

NASA Astrophysics Data System (ADS)

Teng, Shiang Jen

Over the last decade, technological progress and advances in the miniaturization of electronic devices have increased demands for light-weight, high-efficiency, and carbon-free energy storage devices. These energy storage devices are expected to play important roles in automobiles, the military, power plants, and consumer electronics. Two main types of electrical energy storage systems studied in this research are Li ion batteries and supercapacitors. Several promising solid state electrolytes and supercapacitor electrode materials are investigated in this research. The first section of this dissertation is focused on the novel results on pulsed laser annealing of Li7La3Zr2O12 (LLZO). LLZO powders with a tetragonal structure were prepared by a sol-gel technique, then a pulsed laser annealing process was employed to convert the tetragonal powders to cubic LLZO without any loss of lithium. The second section of the dissertation reports on how Li5La 3Nb2O12 (LLNO) was successfully synthesized via a novel molten salt synthesis (MSS) method at the relatively low temperature of 900°C. The low sintering temperature prevented the loss of lithium that commonly occurs during synthesis using conventional solid state or wet chemical reactions. The second type of energy storage device studied is supercapacitors. Currently, research on supercapacitors is focused on increasing their energy densities and lowering their overall production costs by finding suitable electrode materials. The third section of this dissertation details how carbonized woods electrodes were used as supercapacitor electrode materials. A high energy density of 45.6 Wh/kg and a high power density of 2000 W/kg were obtained from the supercapacitor made from carbonized wood electrodes. The high performance of the supercapacitor was discovered to originate from the hierarchical porous structures of the carbonized wood. Finally, the fourth section of this dissertation is on the electrochemical effects of

Ultrasonic assisted synthesis of Bikitaite zeolite: A potential material for hydrogen storage application.

PubMed

Roy, Priyanka; Das, Nandini

2017-05-01

Li containing Bikitaite zeolite has been synthesized by an ultrasound-assisted method and used as a potential material for hydrogen storage application. The Sonication energy was varied from 150W to 250W and irradiation time from 3h to 6h. The Bikitaite nanoparticles were characterized by X-ray diffraction (XRD), infrared (IR) spectral analysis, and field-emission scanning electron microscopy (FESEM) thermo-gravimetrical analysis and differential thermal analysis (TGA, DTA). XRD and IR results showed that phase pure, nano crystalline Bikitaite zeolites were started forming after 3h irradiation and 72h of aging with a sonication energy of 150W and nano crystalline Bikitaite zeolite with prominent peaks were obtained after 6h irradiation of 250W sonic energy. The Brunauer-Emmett-Teller (BET) surface area of the powder by N 2 adsorption-desorption measurements was found to be 209m 2 /g. The TEM micrograph and elemental analysis showed that desired atomic ratio of the zeolite was obtained after 6h irradiation. For comparison, sonochemical method, followed by the hydrothermal method, with same initial sol composition was studied. The effect of ultrasonic energy and irradiation time showed that with increasing sonication energy, and sonication time phase formation was almost completed. The FESEM images revealed that 50nm zeolite crystals were formed at room temperature. However, agglomerated particles having woollen ball like structure was obtained by sonochemical method followed by hydrothermal treatment at 100°C for 24h. The hydrogen adsorption capacity of Bikitaite zeolite with different Li content, has been investigated. Experimental results indicated that the hydrogen adsorption capacities were dominantly related to their surface areas as well as total pore volume of the zeolite. The hydrogen adsorption capacity of 143.2c.c/g was obtained at 77K and ambient pressure of (0.11MPa) for the Bikitaite zeolite with 100% Li, which was higher than the reported values for

Cost projections for Redox Energy storage systems

NASA Technical Reports Server (NTRS)

Michaels, K.; Hall, G.

1980-01-01

A preliminary design and system cost analysis was performed for the redox energy storage system. A conceptual design and cost estimate was prepared for each of two energy applications: (1) electric utility 100-MWh requirement (10-MW for ten hours) for energy storage for utility load leveling application, and (2) a 500-kWh requirement (10-kW for 50 hours) for use with a variety of residential or commercial applications, including stand alone solar photovoltaic systems. The conceptual designs were based on cell performance levels, system design parameters, and special material costs. These data were combined with estimated thermodynamic and hydraulic analysis to provide preliminary system designs. Results indicate that the redox cell stack to be amenable to mass production techniques with a relatively low material cost.

Review of Phase Change Materials Based on Energy Storage System with Applications

NASA Astrophysics Data System (ADS)

Thamaraikannn, R.; Kanimozhi, B.; Anish, M.; Jayaprabakar, J.; Saravanan, P.; Rohan Nicholas, A.

2017-05-01

The use of Different types of storage system using phase change materials (PCMs) is an effective way of storing energy and also to make advantages of heating and cooling systems are installed to maintain temperatures within the well-being zone. PCMs have been extensively used in various storage systems for heat pumps, solar engineering, and thermal control applications. The use of PCM’s for heating and cooling applications have been investigated during the past decade. There are large numbers of PCM’s, which melt and solidify at a wide range of temperatures, making them attractive in a number of applications. This paper also outline the investigation and analysis of Phase Change materials used in Different Types of storage systems with different applications.

VIEW SHOWING STORAGE AREA IN CARPORT. VIEW FACING NORTH ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

VIEW SHOWING STORAGE AREA IN CARPORT. VIEW FACING NORTH - Camp H.M. Smith and Navy Public Works Center Manana Title VII (Capehart) Housing, Three-Bedroom Single-Family Type 9, Birch Circle, Elm Drive, Elm Circle, and Date Drive, Pearl City, Honolulu County, HI

Experimental study of compatibility of reduced metal oxides with thermal energy storage lining materials

NASA Astrophysics Data System (ADS)

El-Leathy, Abdelrahman; Danish, Syed Noman; Al-Ansary, Hany; Jeter, Sheldon; Al-Suhaibani, Zeyad

2016-05-01

Solid particles have been shown to be able to operate at temperatures higher than 1000 °C in concentrated solar power (CSP) systems with thermal energy storage (TES). Thermochemical energy storage (TCES) using metal oxides have also found to be advantageous over sensible and latent heat storage concepts. This paper investigates the compatibility of the inner lining material of a TES tank with the reduced metal oxide. Two candidate metal oxides are investigated against six candidate lining materials. XRD results for both the materials are investigated and compared before and after the reduction of metal oxide at 1000°C in the presence of lining material. It is found that the lining material rich in zirconia is suitable for such application. Silicon Carbide is also found non-reacting with one of the metal oxides so it needs to be further investigated with other candidate metal oxides.

Organ culture storage of pre-prepared corneal donor material for Descemet's membrane endothelial keratoplasty.

PubMed

Bhogal, Maninder; Matter, Karl; Balda, Maria S; Allan, Bruce D

2016-11-01

To evaluate the effect of media composition and storage method on pre-prepared Descemet's membrane endothelial keratoplasty (DMEK) grafts. 50 corneas were used. Endothelial wound healing and proliferation in different media were assessed using a standard injury model. DMEK grafts were stored using three methods: peeling with free scroll storage; partial peeling with storage on the stroma and fluid bubble separation with storage on the stroma. Endothelial cell (EC) phenotype and the extent of endothelial overgrowth were examined. Global cell viability was assessed for storage methods that maintained a normal cell phenotype. 1 mm wounds healed within 4 days. Enhanced media did not increase EC proliferation but may have increased EC migration into the wounded area. Grafts that had been trephined showed evidence of EC overgrowth, whereas preservation of a physical barrier in the bubble group prevented this. In grafts stored in enhanced media or reapposed to the stroma after trephination, endothelial migration occurred sooner and cells underwent endothelial-mesenchymal transformation. Ongoing cell loss, with new patterns of cell death, was observed after returning grafts to storage. Grafts stored as free scrolls retained more viable ECs than grafts prepared with the fluid bubble method (74.2± 3% vs 60.3±6%, p=0.04 (n=8). Free scroll storage is superior to liquid bubble and partial peeling techniques. Free scrolls only showed overgrowth of ECs after 4 days in organ culture, indicating a viable time window for the clinical use of pre-prepared DMEK donor material using this method. Methods for tissue preparation and storage media developed for whole corneas should not be used in pre-prepared DMEK grafts without prior evaluation. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://www.bmj.com/company/products-services/rights-and-licensing/.

Organ culture storage of pre-prepared corneal donor material for Descemet's membrane endothelial keratoplasty

PubMed Central

Bhogal, Maninder; Matter, Karl; Balda, Maria S; Allan, Bruce D

2016-01-01

Purpose To evaluate the effect of media composition and storage method on pre-prepared Descemet's membrane endothelial keratoplasty (DMEK) grafts. Methods 50 corneas were used. Endothelial wound healing and proliferation in different media were assessed using a standard injury model. DMEK grafts were stored using three methods: peeling with free scroll storage; partial peeling with storage on the stroma and fluid bubble separation with storage on the stroma. Endothelial cell (EC) phenotype and the extent of endothelial overgrowth were examined. Global cell viability was assessed for storage methods that maintained a normal cell phenotype. Results 1 mm wounds healed within 4 days. Enhanced media did not increase EC proliferation but may have increased EC migration into the wounded area. Grafts that had been trephined showed evidence of EC overgrowth, whereas preservation of a physical barrier in the bubble group prevented this. In grafts stored in enhanced media or reapposed to the stroma after trephination, endothelial migration occurred sooner and cells underwent endothelial-mesenchymal transformation. Ongoing cell loss, with new patterns of cell death, was observed after returning grafts to storage. Grafts stored as free scrolls retained more viable ECs than grafts prepared with the fluid bubble method (74.2± 3% vs 60.3±6%, p=0.04 (n=8). Conclusion Free scroll storage is superior to liquid bubble and partial peeling techniques. Free scrolls only showed overgrowth of ECs after 4 days in organ culture, indicating a viable time window for the clinical use of pre-prepared DMEK donor material using this method. Methods for tissue preparation and storage media developed for whole corneas should not be used in pre-prepared DMEK grafts without prior evaluation. PMID:27543290

32 CFR 807.3 - Requests for classified material, For Official Use Only material, accountable forms, storage...

Code of Federal Regulations, 2010 CFR

2010-07-01

... 32 National Defense 6 2010-07-01 2010-07-01 false Requests for classified material, For Official Use Only material, accountable forms, storage safeguard forms, Limited (L) distribution items, and items with restrictive distribution caveats. 807.3 Section 807.3 National Defense Department of Defense (Continued) DEPARTMENT OF THE AIR FORCE...

Foam/Aerogel Composite Materials for Thermal and Acoustic Insulation and Cryogen Storage

NASA Technical Reports Server (NTRS)

Williams, Martha K. (Inventor); Smith, Trent M. (Inventor); Fesmire, James E. (Inventor); Sass, Jared P. (Inventor); Weiser, Erik S. (Inventor)

2011-01-01

The invention involves composite materials containing a polymer foam and an aerogel. The composite materials have improved thermal insulation ability, good acoustic insulation, and excellent physical mechanical properties. The composite materials can be used, for instance, for heat and acoustic insulation on aircraft, spacecraft, and maritime ships in place of currently used foam panels and other foam products. The materials of the invention can also be used in building construction with their combination of light weight, strength, elasticity, ability to be formed into desired shapes, and superior thermal and acoustic insulation power. The materials have also been found to have utility for storage of cryogens. A cryogenic liquid or gas, such as N.sub.2 or H.sub.2, adsorbs to the surfaces in aerogel particles. Thus, another embodiment of the invention provides a storage vessel for a cryogen.

Foam/aerogel composite materials for thermal and acoustic insulation and cryogen storage

NASA Technical Reports Server (NTRS)

Smith, Trent M. (Inventor); Fesmire, James E. (Inventor); Williams, Martha K. (Inventor); Sass, Jared P. (Inventor); Weiser, Erik S. (Inventor)

2010-01-01

The invention involves composite materials containing a polymer foam and an aerogel. The composite materials have improved thermal insulation ability, good acoustic insulation, and excellent physical mechanical properties. The composite materials can be used, for instance, for heat and acoustic insulation on aircraft, spacecraft, and maritime ships in place of currently used foam panels and other foam products. The materials of the invention can also be used in building construction with their combination of light weight, strength, elasticity, ability to be formed into desired shapes, and superior thermal and acoustic insulation power. The materials have also been found to have utility for storage of cryogens. A cryogenic liquid or gas, such as N.sub.2 or H.sub.2, adsorbs to the surfaces in aerogel particles. Thus, another embodiment of the invention provides a storage vessel for a cryogen.

A highly resilient mesoporous SiOx lithium storage material engineered by oil-water templating.

PubMed

Park, Eunjun; Park, Min-Sik; Lee, Jaewoo; Kim, Ki Jae; Jeong, Goojin; Kim, Jung Ho; Kim, Young-Jun; Kim, Hansu

2015-02-01

Mesoporous silicon-based materials gained considerable attention as high-capacity lithium-storage materials. However, the practical use is still limited by the complexity and limited number of available synthetic routes. Here, we report carbon-coated porous SiOx as high capacity lithium storage material prepared by using a sol-gel reaction of hydrogen silsesquioxane and oil-water templating. A hydrophobic oil is employed as a pore former inside the SiOx matrix and a precursor for carbon coating on the SiOx . The anode exhibits a high capacity of 730 mAh g(-1) and outstanding cycling performance over 100 cycles without significant dimensional changes. Carbon-coated porous SiOx also showed highly stable thermal reliability comparable to that of graphite. These promising properties come from the mesopores in the SiOx matrix, which ensures reliable operation of lithium storage in SiOx . The scalable sol-gel process presented here can open up a new avenue for the versatile preparation of porous SiOx lithium storage materials. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Combining computation and experiment to accelerate the discovery of new hydrogen storage materials

NASA Astrophysics Data System (ADS)

Siegel, Donald

2009-03-01

The potential of emerging technologies such as fuel cells (FCs) and photovoltaics for environmentally-benign power generation has sparked renewed interest in the development of novel materials for high density energy storage. For applications in the transportation sector, the demands placed upon energy storage media are especially stringent, as a potential replacement for fossil-fuel-powered internal combustion engines -- namely, the proton exchange membrane FC -- utilizes hydrogen as a fuel. Although hydrogen has about three times the energy density of gasoline by weight, its volumetric energy density (even at 700 bar) is roughly a factor of six smaller. Consequently, the safe and efficient storage of hydrogen has been identified as one of the key materials-based challenges to realizing a transition to FC vehicles. This talk will present an overview of recent efforts at Ford aimed at developing new materials for reversible, solid state hydrogen storage. A tight coupling between first-principles modeling and experiments has greatly accelerated our efforts, and several examples illustrating the benefits of this approach will be presented.

CANE FIBERBOARD DEGRADATION WITHIN THE 9975 SHIPPING PACKAGE DURING LONG-TERM STORAGE APPLICATION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Daugherty, W.; Dunn, K.; Hackney, B.

The 9975 shipping package is used as part of the configuration for long-term storage of special nuclear materials in the K Area Complex at the Savannah River Site. The cane fiberboard overpack in the 9975 package provides thermal insulation, impact absorption and criticality control functions relevant to this application. The Savannah River National Laboratory has conducted physical, mechanical and thermal tests on aged fiberboard samples to identify degradation rates and support the development of aging models and service life predictions in a storage environment. This paper reviews the data generated to date, and preliminary models describing degradation rates of canemore » fiberboard in elevated temperature – elevated humidity environments.« less

A 160 kJ dual plasma focus (DuPF) for fusion-relevant materials testing and nano-materials fabrication

NASA Astrophysics Data System (ADS)

Saw, S. H.; Damideh, V.; Chong, P. L.; Lee, P.; Rawat, R. S.; Lee, S.

2014-08-01

This paper summarizes PF-160 Dual Plasma Focus (DuPF) numerical experiments using the Lee Model code and preliminary 3D design drawings using SolidWorks software. This DuPF consists of two interchangeable electrodes enabling it to be optimized for both Slow Pinch Mode (SFM) and Fast Pinch Mode (FFM); the latter using a speed factor (SF) of 90 kA cm-1 Torr-0.5 for FFM in deuterium [S Lee et al, IEEE Trans Plasma Science 24, 1101-1105 (1996)]; and the former with SF of less than half that value for SFM. Starting with available 6 × 450 µF capacitors rated at 11kV (10% reversal), numerical experiments indicate safe operation at 9 kV, 6 Torr deuterium with FFM anode of 5 cm radius; producing intense ion beam and streaming plasma pulses which would be useful for studies of potential fusion reactor wall materials. On the other hand operating at 5 kV, 10 Torr deuterium with SFM anode of 10 cm radius leads to long-duration, uniform large-area flow which could be more suitable for synthesis of nano-materials. The dual plasma focus design is illustrated here with two figures showing FFM and SFM electrodes.

Low-technology cooling box for storage of malaria RDTs and other medical supplies in remote areas.

PubMed

Chanthap, Lon; Ariey, Frédéric; Socheat, Duong; Tsuyuoka, Reiko; Bell, David

2010-01-23

With the increase in use of point-of-care diagnostic tests for malaria and other diseases comes the necessity of storing the diagnostic kits and the drugs required for subsequent management, in remote areas, where temperatures are high and electricity supply is unreliable or unavailable. To address the lack of temperature-controlled storage during the introduction of community-based malaria management in Cambodia, the Cambodian National Centre for Parasitology, Entomology and Malaria Control (CNM) developed prototype evaporative cooling boxes (Cambodian Cooler Boxes - CCBs) for storage of perishable medical commodities in remote clinics. The performance of these CCBs for maintaining suitable storage temperatures was evaluated over two phases in 2005 and 2006-7, comparing conditions in CCBs using water as designed, CCBs with no water for evaporation, and ambient storage room temperatures. Temperature and humidity was monitored, together with the capacity of the RDTs recommended for storage between 2 to 30 degree Celsius to detect low-density malaria parasite samples after storage under these conditions. Significant differences were recorded between the proportion of temperatures within the recommended RDT storage conditions in the CCBs with water and the temperatures in the storage room (p < 0.001) and maximum temperatures were lower. RDTs stored at ambient temperatures were negative when tested with parasitized blood (2,000 parasites per micro litre) at 210 days, while the field RDTs kept in CCBs with water gave positive results until 360 days. The CCB was an effective tool for storage of RDTs at optimal conditions, and extended the effective life-span of the tests. The concept of evaporative cooling has potential to greatly enhance access to perishable diagnostics and medicines in remote communities, as it allows prolonged storage at low cost using locally-available materials, in the absence of electricity.

Electrochemically fabricated polypyrrole-cobalt-oxygen coordination complex as high-performance lithium-storage materials.

PubMed

Guo, Bingkun; Kong, Qingyu; Zhu, Ying; Mao, Ya; Wang, Zhaoxiang; Wan, Meixiang; Chen, Liquan

2011-12-23

Current lithium-ion battery (LIB) technologies are all based on inorganic electrode materials, though organic materials have been used as electrodes for years. Disadvantages such as limited thermal stability and low specific capacity hinder their applications. On the other hand, the transition metal oxides that provide high lithium-storage capacity by way of electrochemical conversion reaction suffer from poor cycling stability. Here we report a novel high-performance, organic, lithium-storage material, a polypyrrole-cobalt-oxygen (PPy-Co-O) coordination complex, with high lithium-storage capacity and excellent cycling stability. Extended X-ray absorption fine structure and Raman spectroscopy and other physical and electrochemical characterizations demonstrate that this coordination complex can be electrochemically fabricated by cycling PPy-coated Co(3)O(4) between 0.0 V and 3.0 V versus Li(+)/Li. Density functional theory (DFT) calculations indicate that each cobalt atom coordinates with two nitrogen atoms within the PPy-Co coordination layer and the layers are connected with oxygen atoms between them. Coordination weakens the C-H bonds on PPy and makes the complex a novel lithium-storage material with high capacity and high cycling stability. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Basic features of waste material storage in underground space in relation to geomechanics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Konecny, P.

1994-12-31

It is logical to consider utilizing underground cavities for waste material disposal because, during mining, great volumes of rock materials are extracted, and underground hollow areas and communicating workings are created that can, in general, be utilized for waste disposal. Additionally, in many cases, underground waste disposal favorably supports mining process technology (for instance, application of power plant fly ash and preparation plant tailings as hardened backfill). However, it is necessary to give particular attention to the preparation, operation, and isolation of underground tip areas; errors and, in extreme cases, emergencies in underground tips are generally more difficult to dealmore » with than those in surface tips. A tip place constructed underground becomes part of the rock massif; therefore, all natural laws that rule the rock massif must be respected. Of course, such an approach requires knowledge of processes and natural regularities that will occur in rock strata where tip places have been constructed. Such knowledge is gained through familiarity with contemporary geomechanical science. The paper discusses basic geomechanical principles of underground waste disposal; geomechanical aspects of rock massif evaluation in view of waste material storage in mine workings; and plans for an experimental project for waste disposal in the Dul Ostrava underground mine.« less

20. VIEW OF THE RECORDS STORAGE AREA LOCATED ON THE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

20. VIEW OF THE RECORDS STORAGE AREA LOCATED ON THE FIRST FLOOR MEZZANINE. (1/83) - Rocky Flats Plant, General Manufacturing, Support, Records-Central Computing, Southern portion of Plant, Golden, Jefferson County, CO

Enhanced performance and interfacial investigation of mineral-based composite phase change materials for thermal energy storage

PubMed Central

Li, Chuanchang; Fu, Liangjie; Ouyang, Jing; Yang, Huaming

2013-01-01

A novel mineral-based composite phase change materials (PCMs) was prepared via vacuum impregnation method assisted with microwave-acid treatment of the graphite (G) and bentonite (B) mixture. Graphite and microwave-acid treated bentonite mixture (GBm) had more loading capacity and higher crystallinity of stearic acid (SA) in the SA/GBm composite. The SA/GBm composite showed an enhanced thermal storage capacity, latent heats for melting and freezing (84.64 and 84.14 J/g) was higher than those of SA/B sample (48.43 and 47.13 J/g, respectively). Addition of graphite was beneficial to the enhancement in thermal conductivity of the SA/GBm composite, which could reach 0.77 W/m K, 31% higher than SA/B and 196% than pure SA. Furthermore, atomic-level interfaces between SA and support surfaces were depicted, and the mechanism of enhanced thermal storage properties was in detail investigated. PMID:23712069

Storage and executive processes in the frontal lobes.

PubMed

Smith, E E; Jonides, J

1999-03-12

The human frontal cortex helps mediate working memory, a system that is used for temporary storage and manipulation of information and that is involved in many higher cognitive functions. Working memory includes two components: short-term storage (on the order of seconds) and executive processes that operate on the contents of storage. Recently, these two components have been investigated in functional neuroimaging studies. Studies of storage indicate that different frontal regions are activated for different kinds of information: storage for verbal materials activates Broca's area and left-hemisphere supplementary and premotor areas; storage of spatial information activates the right-hemisphere premotor cortex; and storage of object information activates other areas of the prefrontal cortex. Two of the fundamental executive processes are selective attention and task management. Both processes activate the anterior cingulate and dorsolateral prefrontal cortex.

13. Interior view of food storage area looking towards hallway; ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

13. Interior view of food storage area looking towards hallway; southeast corner of building on lower floor; view to north. - Ellsworth Air Force Base, Mess & Administration Building, 1561 Ellsworth Street, Blackhawk, Meade County, SD

21. VIEW OF AXLE AND WHEEL ASSEMBLY STORAGE AREA, adjacent ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

21. VIEW OF AXLE AND WHEEL ASSEMBLY STORAGE AREA, adjacent to Erecting Shop and Machine Shop. - Juniata Shops, Erecting Shop & Machine Shop, East of Fourth Avenue, between Fourth & Fifth Streets, Altoona, Blair County, PA

100-N Area underground storage tank closures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rowley, C.A.

1993-08-01

This report describes the removal/characterization actions concerning underground storage tanks (UST) at the 100-N Area. Included are 105-N-LFT, 182-N-1-DT, 182-N-2-DT, 182-N-3-DT, 100-N-SS-27, and 100-N-SS-28. The text of this report gives a summary of remedial activities. In addition, correspondence relating to UST closures can be found in Appendix B. Appendix C contains copies of Unusual Occurrence Reports, and validated sampling data results comprise Appendix D.

Three dimensional graphene based materials: Synthesis and applications from energy storage and conversion to electrochemical sensor and environmental remediation.

PubMed

Wang, Hou; Yuan, Xingzhong; Zeng, Guangming; Wu, Yan; Liu, Yang; Jiang, Qian; Gu, Shansi

2015-07-01

With superior electrical/thermal conductivities and mechanical properties, two dimensional (2D) graphene has become one of the most intensively explored carbon allotropes in materials science. To exploit the inherent properties fully, 2D graphene sheets are often fabricated or assembled into functional architectures (e.g. hydrogels, aerogels) with desired three dimensional (3D) interconnected porous microstructures. The 3D graphene based materials show many excellent characteristics including increased active material per projected area, accessible mass transport or storage, electro/thermo conductivity, chemical/electrochemical stability and flexibility. It has paved the way for practical requirements in electronics, adsorption as well as catalysis related system. This review shows an extensive overview of the main principles and the recent synthetic technologies about fabricating various innovative 3D graphene based materials. Subsequently, recent progresses in electrochemical energy devices (lithium/lithium ion batteries, supercapacitors, fuel cells and solar cells) and hydrogen energy generation/storage are explicitly discussed. The up to date advances for pollutants detection and environmental remediation are also reviewed. Finally, challenges and outlooks in materials development for energy and environment are suggested. Copyright © 2015 Elsevier B.V. All rights reserved.

Materials Assessment of Insulating Foam in the 9977 Shipping Package for Long-Term Storage - Annual Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

McWilliams, A. J.

The 9977 shipping package is being evaluated for long-term storage applications in the K-Area Complex (KAC) with specific focus on the packaging foam material. A rigid closed cell polyurethane foam, LAST-A-FOAM® FR-3716, produced by General Plastics Manufacturing Company is sprayed and expands to fill the void between the inner container and the outer shell of the package. The foam is sealed in this annular space and is not accessible. During shipping and storage, the foam experiences higher than ambient temperatures from the heat generated by nuclear material within the package creating the potential for degradation of the foam. A seriesmore » of experiments is underway to determine the extent of foam degradation. Foam samples of three densities have been aging at elevated temperatures 160 °F, 160 °F + 50% relative humidity (RH), 185 °F, 215 °F, and 250 °F since 2014. Samples were periodically removed and tested. After approximately 80 weeks, samples conditioned at 160 °F, 160 °F + 50% RH, and 185 °F have retained initial property values while samples conditioned at 215 °F have reduced intumescence. Samples conditioned at 250 °F have shown the most degradation, loss of volume, mass, absorbed energy under compression, intumescence, and increased flammability. Based on the initial data, temperatures up to 185 °F have not yet shown an adverse effect on the foam properties and it is recommended that exposure of FR-3716 foam to temperatures in excess of 250 °F be avoided or minimized. Testing will continue beyond the 96 week mark. This will provide additional data to help define the long-term behavior for the lower temperature conditions. Additional testing will be pursued in an attempt to identify transition points (threshold times and temperatures) at the higher temperatures of interest, as well as possible benefits of aging within the relatively oxygen-free environment the foam experiences inside the 9977 shipping package.« less

Tailoring the thermostability and hydrogen storage capacity of Li decorated carbon materials by heteroatom doping

NASA Astrophysics Data System (ADS)

Long, Jun; Li, Jieyuan; Nan, Fang; Yin, Shi; Li, Jianjun; Cen, Wanglai

2018-03-01

Li decorated graphene is supposed to be a promising material for the hydrogen storage, which can be further improved by heteroatom doping. But a unified promoting mechanism for various doping types and species are still lacking, which hinders the rational design of advanced materials. The potential of N/B doped Li decorated graphene for hydrogen storage is investigated with DFT calculations. A covalent interaction between Li and the graphene substrates is identified to control the thermostability and hydrogen storage capacity (HSC) of the Li decorated substrate, which is in turn subject to the electronegativity of doping species and the doping types. Additionally, a conceptual descriptor is proposed to predict the HSC of Li decorated graphene. These results provide a unified explanation and prediction of the effects of heteroatom doping on Li decorated carbon materials for hydrogen storage.

Preparation and characterization of flame retardant n-hexadecane/silicon dioxide composites as thermal energy storage materials.

PubMed

Fang, Guiyin; Li, Hui; Chen, Zhi; Liu, Xu

2010-09-15

Flame retardant n-hexadecane/silicon dioxide (SiO(2)) composites as thermal energy storage materials were prepared using sol-gel methods. In the composites, n-hexadecane was used as the phase change material for thermal energy storage, and SiO(2) acted as the supporting material that is fire resistant. In order to further improve flame retardant property of the composites, the expanded graphite (EG) was added in the composites. Fourier transformation infrared spectroscope (FT-IR), X-ray diffractometer (XRD) and scanning electronic microscope (SEM) were used to determine chemical structure, crystalloid phase and microstructure of flame retardant n-hexadecane/SiO(2) composites, respectively. The thermal properties and thermal stability were investigated by a differential scanning calorimeter (DSC) and a thermogravimetric analysis apparatus (TGA), respectively. The SEM results showed that the n-hexadecane was well dispersed in the porous network of the SiO(2). The DSC results indicated that the melting and solidifying latent heats of the composites are 147.58 and 145.10 kJ/kg when the mass percentage of the n-hexadecane in the composites is 73.3%. The TGA results showed that the loading of the EG increased the charred residue amount of the composites at 700 degrees C, contributing to the improved thermal stability of the composites. It was observed from SEM photographs that the homogeneous and compact charred residue structure after combustion improved the flammability of the composites. Copyright 2010 Elsevier B.V. All rights reserved.

Computational Evaluation of Latent Heat Energy Storage Using a High Temperature Phase Change Material

DTIC Science & Technology

2012-05-01

thermal energy storage system using molten silicon as a phase change material. A cylindrical receiver, absorber, converter system was evaluated using...temperature operation. This work computationally evaluates a thermal energy storage system using molten silicon as a phase change material. A cylindrical... salts ) offering a low power density and a low thermal conductivity, leading to a limited rate of charging and discharging (4). A focus on

Lignin Based Carbon Materials for Energy Storage Applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chatterjee, Sabornie; Saito, Tomonori; Rios, Orlando

The implementation of Li-ion battery technology into electric and hybrid electric vehicles and portable electronic devices such as smart phones, laptops and tablets, creates a demand for efficient, economic and sustainable materials for energy storage. However, the high cost and long processing time associated with manufacturing battery-grade anode and cathode materials are two big constraints for lowering the total cost of batteries and environmentally friendly electric vehicles. Lignin, a byproduct of the pulp and paper industry and biorefinery, is one of the most abundant and inexpensive natural biopolymers. It can be efficiently converted to low cost carbon fibers with optimalmore » properties for use as anode materials. Recent developments in the preparation of lignin precursors and conversion to carbon fiber-based anode materials have created a new class of anode materials with excellent electrochemical characteristics suitable for immediate use in existing Li- or Na-ion battery technologies.« less

Monitoring small reservoirs' storage with satellite remote sensing in inaccessible areas

NASA Astrophysics Data System (ADS)

Avisse, Nicolas; Tilmant, Amaury; François Müller, Marc; Zhang, Hua

2017-12-01

In river basins with water storage facilities, the availability of regularly updated information on reservoir level and capacity is of paramount importance for the effective management of those systems. However, for the vast majority of reservoirs around the world, storage levels are either not measured or not readily available due to financial, political, or legal considerations. This paper proposes a novel approach using Landsat imagery and digital elevation models (DEMs) to retrieve information on storage variations in any inaccessible region. Unlike existing approaches, the method does not require any in situ measurement and is appropriate for monitoring small, and often undocumented, irrigation reservoirs. It consists of three recovery steps: (i) a 2-D dynamic classification of Landsat spectral band information to quantify the surface area of water, (ii) a statistical correction of DEM data to characterize the topography of each reservoir, and (iii) a 3-D reconstruction algorithm to correct for clouds and Landsat 7 Scan Line Corrector failure. The method is applied to quantify reservoir storage in the Yarmouk basin in southern Syria, where ground monitoring is impeded by the ongoing civil war. It is validated against available in situ measurements in neighbouring Jordanian reservoirs. Coefficients of determination range from 0.69 to 0.84, and the normalized root-mean-square error from 10 to 16 % for storage estimations on six Jordanian reservoirs with maximal water surface areas ranging from 0.59 to 3.79 km2.

Hydrogen storage in Chabazite zeolite frameworks.

PubMed

Regli, Laura; Zecchina, Adriano; Vitillo, Jenny G; Cocina, Donato; Spoto, Giuseppe; Lamberti, Carlo; Lillerud, Karl P; Olsbye, Unni; Bordiga, Silvia

2005-09-07

We have recently highlighted that H-SSZ-13, a highly siliceous zeolite (Si/Al = 11.6) with a chabazitic framework, is the most efficient zeolitic material for hydrogen storage [A. Zecchina, S. Bordiga, J. G. Vitillo, G. Ricchiardi, C. Lamberti, G. Spoto, M. Bjørgen and K. P. Lillerud, J. Am. Chem. Soc., 2005, 127, 6361]. The aim of this new study is thus to clarify both the role played by the acidic strength and by the density of the polarizing centers hosted in the same framework topology in the increase of the adsorptive capabilities of the chabazitic materials towards H2. To achieve this goal, the volumetric experiments of H2 uptake (performed at 77 K) and the transmission IR experiment of H2 adsorption at 15 K have been performed on H-SSZ-13, H-SAPO-34 (the isostructural silico-aluminophosphate material with the same Brønsted site density) and H-CHA (the standard chabazite zeolite: Si/Al = 2.1) materials. We have found that a H2 uptake improvement has been obtained by increasing the acidic strength of the Brønsted sites (moving from H-SAPO-34 to H-SSZ-13). Conversely, the important increase of the Brønsted sites density (moving from H-SSZ-13 to H-CHA) has played a negative role. This unexpected behavior has been explained as follows. The additional Brønsted sites are in mutual interaction via H-bonds inside the small cages of the chabazitic framework and for most of them the energetic cost needed to displace the adjacent OH ligand is higher than the adsorption enthalpy of the OH...H2 adduct. From our work it can be concluded that proton exchanged chabazitic frameworks represent, among zeolites, the most efficient materials for hydrogen storage. We have shown that a proper balance between available space (volume accessible to hydrogen), high contact surface, and specific interaction with strong and isolated polarizing centers are the necessary characteristics requested to design better materials for molecular H2 storage.

Long-term myocardial preservation: effects of hyperkalemia, sodium channel, and Na/K/2Cl cotransport inhibition on extracellular potassium accumulation during hypothermic storage.

PubMed

Snabaitis, A K; Shattock, M J; Chambers, D J

1999-07-01

We previously demonstrated improved myocardial preservation with polarized (tetrodotoxin-induced), compared with depolarized (hyperkalemia-induced), arrest and hypothermic storage. This study was undertaken to determine whether polarized arrest reduced ionic imbalance during ischemic storage and whether this was influenced by Na+/K +/2Cl- cotransport inhibition. We used the isolated crystalloid perfused working rat heart preparation (1) to measure extracellular K+ accumulation (using a K+-sensitive intramyocardial electrode) during ischemic (control), depolarized (K+ 16 mmol/L), and polarized (tetrodotoxin, 22 micromol/L) arrest and hypothermic (7.5 degrees C) storage (5 hours), (2) to determine dose-dependent (0.1, 1.0, 10 and 100 micromol/L) effects of the Na +/K+/2Cl- cotransport inhibitor, furosemide, on extracellular K+ accumulation during polarized arrest and 7.5 degrees C storage, and (3) to correlate extracellular K+ accumulation to postischemic recovery of cardiac function. Characteristic triphasic profiles of extracellular K+ accumulation were observed in control and depolarized arrested hearts; a significantly attenuated profile with polarized arrested hearts demonstrated reduced extracellular K+ accumulation, correlating with higher postischemic function (recovery of aortic flow was 54% +/-4% [P =.01] compared with 39% +/-3% and 32% +/-3% in depolarized and control hearts, respectively). Furosemide (0.1, 1.0, 10, and 100 micromol/L) modified extracellular K+ accumulation by -18%, -38%, -0.2%, and +9%, respectively, after 30 minutes and by -4%, -27%, +31%, and +42%, respectively, after 5 hours of polarized storage. Recovery of aortic flow was 53% +/-4% (polarized arrest alone), 56% +/-8%, 70% +/-2% (P =.04 vs control), 69% +/-4% (P =.04 vs control), and 65% +/-3% ( P =. 04 vs control), respectively. Polarized arrest was associated with a reduced ionic imbalance (demonstrated by reduced extracellular K+ accumulation) and improved recovery of cardiac

Storage Area (1942 section), looking east, showing concrete structural elements ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Storage Area (1942 section), looking east, showing concrete structural elements and wall opening to vaults - Fort McNair, Film Store House, Fort Lesley J. McNair, P Street between Third & Fourth Streets, Southwest, Washington, District of Columbia, DC

Heat storage system utilizing phase change materials government rights

DOEpatents

Salyer, Ival O.

2000-09-12

A thermal energy transport and storage system is provided which includes an evaporator containing a mixture of a first phase change material and a silica powder, and a condenser containing a second phase change material. The silica powder/PCM mixture absorbs heat energy from a source such as a solar collector such that the phase change material forms a vapor which is transported from the evaporator to the condenser, where the second phase change material melts and stores the heat energy, then releases the energy to an environmental space via a heat exchanger. The vapor is condensed to a liquid which is transported back to the evaporator. The system allows the repeated transfer of thermal energy using the heat of vaporization and condensation of the phase change material.

Assessment of Surface Water Storage trends for increasing groundwater areas in India

NASA Astrophysics Data System (ADS)

Banerjee, Chandan; Kumar, D. Nagesh

2018-07-01

Recent studies based on Gravity Recovery and Climate Experiment (GRACE) satellite mission suggested that groundwater has increased in central and southern parts of India. However, surface water, which is an equally important source of water in these semi-arid areas has not been studied yet. In the present study, the study areas were outlined based on trends in GRACE data followed by trend identification in surface water storages and checking the hypothesis of causality. Surface Water Extent (SWE) and Surface Soil Moisture (SSM) derived from Moderate-resolution Imaging Spectroradiometer (MODIS) and Advanced Microwave Scanning Radiometer - Earth Observing System (AMSR-E) respectively, are selected as proxies of surface water storage (SWS). Besides SWE and SSM, trend test was performed for GRACE derived terrestrial water storage (TWS) for the study areas named as R1, R2, GOR1 and KOR1. Granger-causality test is used to test the hypothesis that rainfall is a causal factor of the inter-annual variability of SWE, SSM and TWS. Positive trends were observed in TWS for R1, R2 and GOR1 whereas SWE and SSM show increasing trends for all the study regions. Results suggest that rainfall is the granger-causal of all the storage variables for R1 and R2, the regions exhibiting the most significant positive trends in TWS.

Applications of large-area nanopatterning to energy generation and storage devices

NASA Astrophysics Data System (ADS)

Mills, Eric N.

This dissertation encompasses the creation and testing of nanostructured, electrochemically-active energy generation and storage devices, and development of the associated fabrication techniques. The fabricated devices include nanopatterned, plasmonically-active, TiO2+Au thin films for Photocatalytic Water Splitting (PCW), TiO2-based Dye-Sensitized Solar Cells (DSSCs) incorporating nanopatterned, plasmonically-active metallic front electrodes, and Si nanopillar anodes for Li-ion batteries. Techniques were also developed for encapsulation and removal of wet-etched Si nanowires from their mother substrates. TiO2 was the first material to be widely used for PCW. Its use is hampered by its large bandgap (~3.2eV), and poor recombination lifetimes. Au nanoparticles (NPs) have been previously used to improve recombination lifetimes in TiO2 by separating photogenerated carriers near the NP edges, and to increase photocurrents by injecting plasmonically-excited hot electrons into the TiO2 conduction band. Using nanostructured TiO 2+Au electrodes, we aim to increase the PCW efficiency of TiO2 -based electrodes. Dye-sensitized solar cells (DSSCs) employ visible-absorbing dyes anchored to a high-surface-area semiconducting scaffold. The front transparent conducting electrode (TCE) is typically ITO, a scarce and expensive material. We aim to increase the efficiency of thin-film DSSCs and eliminate the use of ITO by using a metallic subwavelength array (MESH) of nanoholes as the front TCE. Silicon holds promise as a high-capacity anode material for Li-ion batteries, as it can store ~10x the Li of graphite, the current leading anode material (3569 vs. 372 mAh/g). However, Si undergoes dramatic (>300%) volume expansion upon "lithiation", pulverizing any structure with non-nanoscopic dimensions (>250nm). We created large-area arrays of "nanopillars" with sub-100nm diameters, using roll-to-roll-compatible flexible-mold NIL on commercially-available metal substrates. Ordered

Efficient storage mechanisms for building better supercapacitors

NASA Astrophysics Data System (ADS)

Salanne, M.; Rotenberg, B.; Naoi, K.; Kaneko, K.; Taberna, P.-L.; Grey, C. P.; Dunn, B.; Simon, P.

2016-06-01

Supercapacitors are electrochemical energy storage devices that operate on the simple mechanism of adsorption of ions from an electrolyte on a high-surface-area electrode. Over the past decade, the performance of supercapacitors has greatly improved, as electrode materials have been tuned at the nanoscale and electrolytes have gained an active role, enabling more efficient storage mechanisms. In porous carbon materials with subnanometre pores, the desolvation of the ions leads to surprisingly high capacitances. Oxide materials store charge by surface redox reactions, leading to the pseudocapacitive effect. Understanding the physical mechanisms underlying charge storage in these materials is important for further development of supercapacitors. Here we review recent progress, from both in situ experiments and advanced simulation techniques, in understanding the charge storage mechanism in carbon- and oxide-based supercapacitors. We also discuss the challenges that still need to be addressed for building better supercapacitors.

Bismuth pyrochlore-based thin films for dielectric energy storage

NASA Astrophysics Data System (ADS)

Michael, Elizabeth K.

The drive towards the miniaturization of electronic devices has created a need for dielectric materials with large energy storage densities. These materials, which are used in capacitors, are a critical component in many electrical systems. Here, the development of dielectric energy storage materials for pulsed power applications, which require materials with the ability to accumulate a large amount of energy and then deliver it to the system rapidly, is explored. The amount of electrostatic energy that can be stored by a material is a function of the induced polarization and the dielectric breakdown strength of the material. An ideal energy storage dielectric would possess a high relative permittivity, high dielectric breakdown strength, and low loss tangent under high applied electric fields. The bismuth pyrochlores are a compositionally tunable family of materials that meet these requirements. Thin films of cubic pyrochlore bismuth zinc niobate, bismuth zinc tantalate, and bismuth zinc niobate tantalate, were fabricated using a novel solution chemistry based upon the Pechini method. This solution preparation is advantageous because it avoids the use of teratogenic solvents, such as 2-methoxyethanol. Crystalline films fabricated using this solution chemistry had very small grains that were approximately 27 nm in lateral size and 35 nm through the film thickness. Impedance measurements found that the resistivity of the grain boundaries was two orders of magnitude higher than the resistivity of the grain interior. The presence of many resistive grain boundaries impeded conduction through the films, resulting in high breakdown strengths for these materials. In addition to high breakdown strengths, this family of materials exhibited moderate relative permittivities of between 55 +/- 2 and 145 +/- 5, for bismuth zinc tantalate and bismuth zinc niobate, respectively, and low loss tangents on the order of 0.0008 +/- 0.0001. Increases in the concentration of the tantalum

Development of the ReaxFFCBN reactive force field for the improved design of liquid CBN hydrogen storage materials.

PubMed

Pai, Sung Jin; Yeo, Byung Chul; Han, Sang Soo

2016-01-21

Liquid CBN (carbon-boron-nitrogen) hydrogen-storage materials such as 3-methyl-1,2-BN-cyclopentane have the advantage of being easily accessible for use in current liquid-fuel infrastructure. To develop practical liquid CBN hydrogen-storage materials, it is of great importance to understand the reaction pathways of hydrogenation/dehydrogenation in the liquid phase, which are difficult to discover by experimental methods. Herein, we developed a reactive force field (ReaxFFCBN) from quantum mechanical (QM) calculations based on density functional theory for the storage of hydrogen in BN-substituted cyclic hydrocarbon materials. The developed ReaxFFCBN provides similar dehydrogenation pathways and energetics to those predicted by QM calculations. Moreover, molecular dynamics (MD) simulations with the developed ReaxFFCBN can predict the stability and dehydrogenation behavior of various liquid CBN hydrogen-storage materials. Our simulations reveal that a unimolecular dehydrogenation mechanism is preferred in liquid CBN hydrogen-storage materials. However, as the temperature in the simulation increases, the contribution of a bimolecular dehydrogenation mechanism also increases. Moreover, our ReaxFF MD simulations show that in terms of thermal stability and dehydrogenation kinetics, liquid CBN materials with a hexagonal structure are more suitable materials than those with a pentagonal structure. We expect that the developed ReaxFFCBN could be a useful protocol in developing novel liquid CBN hydrogen-storage materials.

Recent Advances of Flexible Data Storage Devices Based on Organic Nanoscaled Materials.

PubMed

Zhou, Li; Mao, Jingyu; Ren, Yi; Han, Su-Ting; Roy, Vellaisamy A L; Zhou, Ye

2018-03-01

Following the trend of miniaturization as per Moore's law, and facing the strong demand of next-generation electronic devices that should be highly portable, wearable, transplantable, and lightweight, growing endeavors have been made to develop novel flexible data storage devices possessing nonvolatile ability, high-density storage, high-switching speed, and reliable endurance properties. Nonvolatile organic data storage devices including memory devices on the basis of floating-gate, charge-trapping, and ferroelectric architectures, as well as organic resistive memory are believed to be favorable candidates for future data storage applications. In this Review, typical information on device structure, memory characteristics, device operation mechanisms, mechanical properties, challenges, and recent progress of the above categories of flexible data storage devices based on organic nanoscaled materials is summarized. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bunkhouse basement interior showing storage area and a conveyor belt ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Bunkhouse basement interior showing storage area and a conveyor belt (circa 1936) used to unload dry goods into the basement through an opening on the east side of the bunkhouse. - Sespe Ranch, Bunkhouse, 2896 Telegraph Road, Fillmore, Ventura County, CA

Nanoporous Ni with High Surface Area for Potential Hydrogen Storage Application.

PubMed

Zhou, Xiaocao; Zhao, Haibo; Fu, Zhibing; Qu, Jing; Zhong, Minglong; Yang, Xi; Yi, Yong; Wang, Chaoyang

2018-06-01

Nanoporous metals with considerable specific surface areas and hierarchical pore structures exhibit promising applications in the field of hydrogen storage, electrocatalysis, and fuel cells. In this manuscript, a facile method is demonstrated for fabricating nanoporous Ni with a high surface area by using SiO₂ aerogel as a template, i.e., electroless plating of Ni into an SiO₂ aerogel template followed by removal of the template at moderate conditions. The effects of the prepared conditions, including the electroless plating time, temperature of the structure, and the magnetism of nanoporous Ni are investigated in detail. The resultant optimum nanoporous Ni with a special 3D flower-like structure exhibited a high specific surface area of about 120.5 m²/g. The special nanoporous Ni exhibited a promising prospect in the field of hydrogen storage, with a hydrogen capacity of 0.45 wt % on 4.5 MPa at room temperature.

Certification of Compliance Audit Checklist for Hazardous Waste Container Storage Areas

EPA Pesticide Factsheets

Example of a Certification of Compliance Audit Checklist -- Container Storage, which includes a fillable table with areas to list requirements, federal regulations, descriptions, locations of information, and criteria met.

Coherence time of over a second in a telecom-compatible quantum memory storage material

NASA Astrophysics Data System (ADS)

Rančić, Miloš; Hedges, Morgan P.; Ahlefeldt, Rose L.; Sellars, Matthew J.

2018-01-01

Quantum memories for light will be essential elements in future long-range quantum communication networks. These memories operate by reversibly mapping the quantum state of light onto the quantum transitions of a material system. For networks, the quantum coherence times of these transitions must be long compared to the network transmission times, approximately 100 ms for a global communication network. Due to a lack of a suitable storage material, a quantum memory that operates in the 1,550 nm optical fibre communication band with a storage time greater than 1 μs has not been demonstrated. Here we describe the spin dynamics of 167Er3+: Y2SiO5 in a high magnetic field and demonstrate that this material has the characteristics for a practical quantum memory in the 1,550 nm communication band. We observe a hyperfine coherence time of 1.3 s. We also demonstrate efficient spin pumping of the entire ensemble into a single hyperfine state, a requirement for broadband spin-wave storage. With an absorption of 70 dB cm-1 at 1,538 nm and Λ transitions enabling spin-wave storage, this material is the first candidate identified for an efficient, broadband quantum memory at telecommunication wavelengths.

Advancement of Systems Designs and Key Engineering Technologies for Materials Based Hydrogen Storage

DOE Office of Scientific and Technical Information (OSTI.GOV)

van Hassel, Bart A.

UTRC lead the development of the Simulink Framework model that enables a comparison of different hydrogen storage systems on a common basis. The Simulink Framework model was disseminated on the www.HSECoE.org website that is hosted by NREL. UTRC contributed to a better understanding of the safety aspects of the proposed hydrogen storage systems. UTRC also participated in the Failure Mode and Effect Analysis of both the chemical- and the adsorbent-based hydrogen storage system during Phase 2 of the Hydrogen Storage Engineering Center of Excellence. UTRC designed a hydrogen storage system with a reversible metal hydride material in a compacted formmore » for light-duty vehicles with a 5.6 kg H2 storage capacity, giving it a 300 miles range. It contains a heat exchanger that enables efficient cooling of the metal hydride material during hydrogen absorption in order to meet the 3.3 minute refueling time target. It has been shown through computation that the kinetics of hydrogen absorption of Ti-catalyzed NaAlH4 was ultimately limiting the rate of hydrogen absorption to 85% of the material capacity in 3.3 minutes. An inverse analysis was performed in order to determine the material property requirements in order for a metal hydride based hydrogen storage system to meet the DOE targets. Work on metal hydride storage systems was halted after the Phase 1 to Phase 2 review due to the lack of metal hydride materials with the required material properties. UTRC contributed to the design of a chemical hydrogen storage system by developing an adsorbent for removing the impurity ammonia from the hydrogen gas, by developing a system to meter the transport of Ammonia Borane (AB) powder to a thermolysis reactor, and by developing a gas-liquid-separator (GLS) for the separation of hydrogen gas from AB slurry in silicone oil. Stripping impurities from hydrogen gas is essential for a long life of the fuel cell system on board of a vehicle. Work on solid transport of AB was halted

Mechanical degradation temperature of waste storage materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fink, M.C.; Meyer, M.L.

1993-05-13

Heat loading analysis of the Solid Waste Disposal Facility (SWDF) waste storage configurations show the containers may exceed 90{degrees}C without any radioactive decay heat contribution. Contamination containment is primarily controlled in TRU waste packaging by using multiple bag layers of polyvinyl chloride and polyethylene. Since literature values indicate that these thermoplastic materials can begin mechanical degradation at 66{degrees}C, there was concern that the containment layers could be breached by heating. To better define the mechanical degradation temperature limits for the materials, a series of heating tests were conducted over a fifteen and thirty minute time interval. Samples of a low-densitymore » polyethylene (LDPE) bag, a high-density polyethylene (HDPE) high efficiency particulate air filter (HEPA) container, PVC bag and sealing tape were heated in a convection oven to temperatures ranging from 90 to 185{degrees}C. The following temperature limits are recommended for each of the tested materials: (1) low-density polyethylene -- 110{degrees}C; (2) polyvinyl chloride -- 130{degrees}C; (3) high-density polyethylene -- 140{degrees}C; (4) sealing tape -- 140{degrees}C. Testing with LDPE and PVC at temperatures ranging from 110 to 130{degrees}C for 60 and 120 minutes also showed no observable differences between the samples exposed at 15 and 30 minute intervals. Although these observed temperature limits differ from the literature values, the trend of HDPE having a higher temperature than LDPE is consistent with the reference literature. Experimental observations indicate that the HDPE softens at elevated temperatures, but will retain its shape upon cooling. In SWDF storage practices, this might indicate some distortion of the waste container, but catastrophic failure of the liner due to elevated temperatures (<185{degrees}C) is not anticipated.« less

9 CFR 355.15 - Inedible material operating and storage rooms; outer premises, docks, driveways, etc.; fly...

Code of Federal Regulations, 2010 CFR

2010-01-01

...-breeding material; nuisances. All operating and storage rooms and departments of inspected plants used for... storage rooms; outer premises, docks, driveways, etc.; fly-breeding material; nuisances. 355.15 Section... premises of every inspected plant shall be kept in clean and orderly condition. All catchbasins on the...

9 CFR 355.15 - Inedible material operating and storage rooms; outer premises, docks, driveways, etc.; fly...

Code of Federal Regulations, 2011 CFR

2011-01-01

...-breeding material; nuisances. All operating and storage rooms and departments of inspected plants used for... storage rooms; outer premises, docks, driveways, etc.; fly-breeding material; nuisances. 355.15 Section... premises of every inspected plant shall be kept in clean and orderly condition. All catchbasins on the...

Nanowire modified carbon fibers for enhanced electrical energy storage

NASA Astrophysics Data System (ADS)

Shuvo, Mohammad Arif Ishtiaque; (Bill) Tseng, Tzu-Liang; Ashiqur Rahaman Khan, Md.; Karim, Hasanul; Morton, Philip; Delfin, Diego; Lin, Yirong

2013-09-01

The study of electrochemical super-capacitors has become one of the most attractive topics in both academia and industry as energy storage devices because of their high power density, long life cycles, and high charge/discharge efficiency. Recently, there has been increasing interest in the development of multifunctional structural energy storage devices such as structural super-capacitors for applications in aerospace, automobiles, and portable electronics. These multifunctional structural super-capacitors provide structures combining energy storage and load bearing functionalities, leading to material systems with reduced volume and/or weight. Due to their superior materials properties, carbon fiber composites have been widely used in structural applications for aerospace and automotive industries. Besides, carbon fiber has good electrical conductivity which will provide lower equivalent series resistance; therefore, it can be an excellent candidate for structural energy storage applications. Hence, this paper is focused on performing a pilot study for using nanowire/carbon fiber hybrids as building materials for structural energy storage materials; aiming at enhancing the charge/discharge rate and energy density. This hybrid material combines the high specific surface area of carbon fiber and pseudo-capacitive effect of metal oxide nanowires, which were grown hydrothermally in an aligned fashion on carbon fibers. The aligned nanowire array could provide a higher specific surface area that leads to high electrode-electrolyte contact area thus fast ion diffusion rates. Scanning Electron Microscopy and X-Ray Diffraction measurements are used for the initial characterization of this nanowire/carbon fiber hybrid material system. Electrochemical testing is performed using a potentio-galvanostat. The results show that gold sputtered nanowire carbon fiber hybrid provides 65.9% higher energy density than bare carbon fiber cloth as super-capacitor.

Sustainable Materials for Sustainable Energy Storage: Organic Na Electrodes

PubMed Central

Oltean, Viorica-Alina; Renault, Stéven; Valvo, Mario; Brandell, Daniel

2016-01-01

In this review, we summarize research efforts to realize Na-based organic materials for novel battery chemistries. Na is a more abundant element than Li, thereby contributing to less costly materials with limited to no geopolitical constraints while organic electrode materials harvested from biomass resources provide the possibility of achieving renewable battery components with low environmental impact during processing and recycling. Together, this can form the basis for truly sustainable electrochemical energy storage. We explore the efforts made on electrode materials of organic salts, primarily carbonyl compounds but also Schiff bases, unsaturated compounds, nitroxides and polymers. Moreover, sodiated carbonaceous materials derived from biomasses and waste products are surveyed. As a conclusion to the review, some shortcomings of the currently investigated materials are highlighted together with the major limitations for future development in this field. Finally, routes to move forward in this direction are suggested. PMID:28773272

Sustainable Materials for Sustainable Energy Storage: Organic Na Electrodes.

PubMed

Oltean, Viorica-Alina; Renault, Stéven; Valvo, Mario; Brandell, Daniel

2016-03-01

In this review, we summarize research efforts to realize Na-based organic materials for novel battery chemistries. Na is a more abundant element than Li, thereby contributing to less costly materials with limited to no geopolitical constraints while organic electrode materials harvested from biomass resources provide the possibility of achieving renewable battery components with low environmental impact during processing and recycling. Together, this can form the basis for truly sustainable electrochemical energy storage. We explore the efforts made on electrode materials of organic salts, primarily carbonyl compounds but also Schiff bases, unsaturated compounds, nitroxides and polymers. Moreover, sodiated carbonaceous materials derived from biomasses and waste products are surveyed. As a conclusion to the review, some shortcomings of the currently investigated materials are highlighted together with the major limitations for future development in this field. Finally, routes to move forward in this direction are suggested.

Nanostructured materials for advanced energy conversion and storage devices

NASA Astrophysics Data System (ADS)

Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno; Tarascon, Jean-Marie; van Schalkwijk, Walter

2005-05-01

New materials hold the key to fundamental advances in energy conversion and storage, both of which are vital in order to meet the challenge of global warming and the finite nature of fossil fuels. Nanomaterials in particular offer unique properties or combinations of properties as electrodes and electrolytes in a range of energy devices. This review describes some recent developments in the discovery of nanoelectrolytes and nanoelectrodes for lithium batteries, fuel cells and supercapacitors. The advantages and disadvantages of the nanoscale in materials design for such devices are highlighted.

Metal-organic frameworks and their derived materials for electrochemical energy storage and conversion: Promises and challenges.

PubMed

Wu, Hao Bin; Lou, Xiong Wen David

2017-12-01

In addition to their conventional uses, metal-organic frameworks (MOFs) have recently emerged as an interesting class of functional materials and precursors of inorganic materials for electrochemical energy storage and conversion technologies. This class of MOF-related materials can be broadly categorized into two groups: pristine MOF-based materials and MOF-derived functional materials. Although the diversity in composition and structure leads to diverse and tunable functionalities of MOF-based materials, it appears that much more effort in this emerging field is devoted to synthesizing MOF-derived materials for electrochemical applications. This is in view of two main drawbacks of MOF-based materials: the low conductivity nature and the stability issue. On the contrary, MOF-derived synthesis strategies have substantial advantages in controlling the composition and structure of MOF-derived materials. From this perspective, we review some emerging applications of both groups of MOF-related materials as electrode materials for rechargeable batteries and electrochemical capacitors, efficient electrocatalysts, and even electrolytes for electrochemical devices. By highlighting the advantages and challenges of each class of materials for different applications, we hope to shed some light on the future development of this highly exciting area.

Metal-organic frameworks and their derived materials for electrochemical energy storage and conversion: Promises and challenges

PubMed Central

Wu, Hao Bin; Lou, Xiong Wen (David)

2017-01-01

In addition to their conventional uses, metal-organic frameworks (MOFs) have recently emerged as an interesting class of functional materials and precursors of inorganic materials for electrochemical energy storage and conversion technologies. This class of MOF-related materials can be broadly categorized into two groups: pristine MOF-based materials and MOF-derived functional materials. Although the diversity in composition and structure leads to diverse and tunable functionalities of MOF-based materials, it appears that much more effort in this emerging field is devoted to synthesizing MOF-derived materials for electrochemical applications. This is in view of two main drawbacks of MOF-based materials: the low conductivity nature and the stability issue. On the contrary, MOF-derived synthesis strategies have substantial advantages in controlling the composition and structure of MOF-derived materials. From this perspective, we review some emerging applications of both groups of MOF-related materials as electrode materials for rechargeable batteries and electrochemical capacitors, efficient electrocatalysts, and even electrolytes for electrochemical devices. By highlighting the advantages and challenges of each class of materials for different applications, we hope to shed some light on the future development of this highly exciting area. PMID:29214220

Storage Area (1942 section), looking east, showing all of Vault ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Storage Area (1942 section), looking east, showing all of Vault No. 1 door behind wall opening and sprinkler system - Fort McNair, Film Store House, Fort Lesley J. McNair, P Street between Third & Fourth Streets, Southwest, Washington, District of Columbia, DC

44. GLAZE STORAGE AND MIXING AREA, GROUND FLOOR, EAST WING. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

44. GLAZE STORAGE AND MIXING AREA, GROUND FLOOR, EAST WING. TILES ARE DIPPED IN GLAZE AT THE COUNTER AGAINST THE FAR WALL. - Moravian Pottery & Tile Works, Southwest side of State Route 313 (Swamp Road), Northwest of East Court Street, Doylestown, Bucks County, PA

Supported Intrinsically Porous Oligomers as Hybrid Materials for Separations, Storage, and Sensing

NASA Astrophysics Data System (ADS)

Thompson, Anthony Boone

Adsorption-desorption phenomena are often difficult to study at the molecular level because the surfaces on which they occur can be heterogeneous, giving a wide distribution of adsorption sites and associated energies. Considering that these phenomena underlie an incredibly wide variety of industrially important processes, a better understanding could aid in the development of more efficient methods. In this work, we describe an approach to designing materials with well-defined adsorption sites by covalently attaching intrinsically porous molecules to solid surfaces by a rigid multidentate linker. These cup-shaped molecules are intended to act as adsorption sites on the material, whereas the rigid attachment to the solid support serves to prevent movement and conformational changes of the sites, leading to better understanding of adsorption phenomena. As a proof-of-concept application, materials were used for adsorption of n-butanol biofuel and related compounds from dilute aqueous solution. The materials were thermally and hydrolytically stable, and adsorption phenomena were reversible. Adsorption sites containing more hydrophobic molecular area led to stronger adsorption, suggesting that it is driven by weak van der Waals forces. Likewise, adsorption sites that were strongly polarized performed poorly, possibly reflecting a greater energy penalty of removing water molecules from the cavity. Upon placing a Lewis acidic metal at the bottom of the cavity, an enhancement was seen only with the most acidic metal, which may indicate weak guest coordination. Observing that hydrophobic interactions dominate adsorption on these materials, efforts were made to develop hybrid materials with large hydrophobic area for adsorption. Glaser coupling of diethynylbenzene was used to grow oligo(phenylene butadiynylene)s from the surface of silica, resulting in materials that were more than 25% organic by weight. In addition to their potential use as adsorbents, these materials may

Modelling challenges for battery materials and electrical energy storage

NASA Astrophysics Data System (ADS)

Muller, Richard P.; Schultz, Peter A.

2013-10-01

Many vital requirements in world-wide energy production, from the electrification of transportation to better utilization of renewable energy production, depend on developing economical, reliable batteries with improved performance characteristics. Batteries reduce the need for gasoline and liquid hydrocarbons in an electrified transportation fleet, but need to be lighter, longer-lived and have higher energy densities, without sacrificing safety. Lighter and higher-capacity batteries make portable electronics more convenient. Less expensive electrical storage accelerates the introduction of renewable energy to electrical grids by buffering intermittent generation from solar or wind. Meeting these needs will probably require dramatic changes in the materials and chemistry used by batteries for electrical energy storage. New simulation capabilities, in both methods and computational resources, promise to fundamentally accelerate and advance the development of improved materials for electric energy storage. To fulfil this promise significant challenges remain, both in accurate simulations at various relevant length scales and in the integration of relevant information across multiple length scales. This focus section of Modelling and Simulation in Materials Science and Engineering surveys the challenges of modelling for energy storage, describes recent successes, identifies remaining challenges, considers various approaches to surmount these challenges and discusses the potential of these methods for future battery development. Zhang et al begin with atoms and electrons, with a review of first-principles studies of the lithiation of silicon electrodes, and then Fan et al examine the development and use of interatomic potentials to the study the mechanical properties of lithiated silicon in larger atomistic simulations. Marrocchelli et al study ionic conduction, an important aspect of lithium-ion battery performance, simulated by molecular dynamics. Emerging high

Physiochemical and antioxidant properties of roselle-mango juice blends; effects of packaging material, storage temperature and time

PubMed Central

Mgaya-Kilima, Beatrice; Remberg, Siv Fagertun; Chove, Bernard Elias; Wicklund, Trude

2015-01-01

A study was conducted to determine the effects of packaging materials, seasonality, storage temperature and time on physiochemical and antioxidant properties of roselle-mango juice blends. Roselle extract (20%, 40%, 60%, and 80%) was mixed with mango juice and stored in glass and plastic bottles at 4°C and 28°C. Total soluble solids, pH, titratable acidity, reducing sugar, color, vitamin C, total monomeric anthocyanins, total phenols, and antioxidant activity (FRAP) were evaluated in freshly prepared juice, and after, 2, 4, and 6 months of storage. The results showed that total soluble solids, reducing sugars, and pH increased with storage times under different storage time, irrespective of packaging materials. The acidity, color, total monomeric anthocyanin, vitamin C, total phenols, and antioxidant activity decreased during storage irrespective of storage temperature and packaging material. Loss of anthocyanins, total phenols, and vitamin C content were higher in blends stored at 28°C than 4°C. PMID:25838888

Electrochemical energy storage devices for wearable technology: a rationale for materials selection and cell design.

PubMed

Sumboja, Afriyanti; Liu, Jiawei; Zheng, Wesley Guangyuan; Zong, Yun; Zhang, Hua; Liu, Zhaolin

2018-06-27

Compatible energy storage devices that are able to withstand various mechanical deformations, while delivering their intended functions, are required in wearable technologies. This imposes constraints on the structural designs, materials selection, and miniaturization of the cells. To date, extensive efforts have been dedicated towards developing electrochemical energy storage devices for wearables, with a focus on incorporation of shape-conformable materials into mechanically robust designs that can be worn on the human body. In this review, we highlight the quantified performances of reported wearable electrochemical energy storage devices, as well as their micro-sized counterparts under specific mechanical deformations, which can be used as the benchmark for future studies in this field. A general introduction to the wearable technology, the development of the selection and synthesis of active materials, cell design approaches and device fabrications are discussed. It is followed by challenges and outlook toward the practical use of electrochemical energy storage devices for wearable applications.

Cost-Efficient Storage of Cryogens

NASA Technical Reports Server (NTRS)

Fesmire, J. E.; Sass, J. P.; Nagy, Z.; Sojoumer, S. J.; Morris, D. L.; Augustynowicz, S. D.

2007-01-01

NASA's cryogenic infrastructure that supports launch vehicle operations and propulsion testing is reaching an age where major refurbishment will soon be required. Key elements of this infrastructure are the large double-walled cryogenic storage tanks used for both space vehicle launch operations and rocket propulsion testing at the various NASA field centers. Perlite powder has historically been the insulation material of choice for these large storage tank applications. New bulk-fill insulation materials, including glass bubbles and aerogel beads, have been shown to provide improved thermal and mechanical performance. A research testing program was conducted to investigate the thermal performance benefits as well as to identify operational considerations and associated risks associated with the application of these new materials in large cryogenic storage tanks. The program was divided into three main areas: material testing (thermal conductivity and physical characterization), tank demonstration testing (liquid nitrogen and liquid hydrogen), and system studies (thermal modeling, economic analysis, and insulation changeout). The results of this research work show that more energy-efficient insulation solutions are possible for large-scale cryogenic storage tanks worldwide and summarize the operational requirements that should be considered for these applications.

Materials screening tests for the krypton-85 storage development program

NASA Astrophysics Data System (ADS)

Nagata, P. K.

1981-04-01

The results of a materials testing program for krypton-85 storage techniques are reported. Corrosion and stress corrosion tests were performed on a variety of materials including AISI 4130, Type 316 SS, Type 304 SS, Type 310 SS, Nitronic 50, and alloy A286. Test environments were high-purity liquid rubidium, liquid rubidium contaminated with oxygen, and rubidium hydroxide. Oxygen and water contaminations in liquid rubidium were found to greatly increase both general and localized corrosion of the materials tested. Alloy A286, Type 304 SS, and AISI 4130 were eliminated as candidate materials due to their susceptibility to general corrosion and stress corrosion cracking.

2D Materials with Nanoconfined Fluids for Electrochemical Energy Storage

DOE Office of Scientific and Technical Information (OSTI.GOV)

Augustyn, Veronica; Gogotsi, Yury

2017-10-11

In the quest to develop energy storage with both high power and high energy densities, and while maintaining high volumetric capacity, recent results show that a variety of 2D and layered materials exhibit rapid kinetics of ion transport by the incorporation of nanoconfined fluids.

Graphene-based materials: fabrication, characterization and application for the decontamination of wastewater and wastegas and hydrogen storage/generation.

PubMed

Wang, Hou; Yuan, Xingzhong; Wu, Yan; Huang, Huajun; Peng, Xin; Zeng, Guangming; Zhong, Hua; Liang, Jie; Ren, Miaomiao

2013-07-01

Graphene, as an ideal two-dimensional material and single-atom layer of graphite, has attracted exploding interests in multidisciplinary research because of its unique structure and exceptional physicochemical properties. Especially, graphene-based materials offer a wide range of potentialities for environmental remediation and energy applications. This review shows an extensive overview of the main principles and the recent synthetic technologies about designing and fabricating various innovative graphene-based materials. Furthermore, an extensive list of graphene-based sorbents and catalysts from vast literature has been compiled. The adsorptive and catalytic properties of graphene-based materials for the removal of various pollutants and hydrogen storage/production as available in the literature are presented. Tremendous adsorption capacity, excellent catalytic performance and abundant availability are the significant factors making these materials suitable alternatives for environmental pollutant control and energy-related system, especially in terms of the removal of pollutants in water, gas cleanup and purification, and hydrogen generation and storage. Meanwhile, a brief discussion is also included on the influence of graphene materials on the environment, and its toxicological effects. Lastly, some unsolved subjects together with major challenges in this germinating area of research are highlighted and discussed. Conclusively, the expanding of graphene-based materials in the field of adsorption and catalysis science represents a viable and powerful tool, resulting in the superior improvement of environmental pollution control and energy development. Copyright © 2013 Elsevier B.V. All rights reserved.

VIEW OF CRANE LOADING AND UNLOADING AREA OF FUEL STORAGE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

VIEW OF CRANE LOADING AND UNLOADING AREA OF FUEL STORAGE BUILDING (CPP-603). PHOTO TAKEN LOOKING NORTH. INL PHOTO NUMBER HD-54-17-4. Mike Crane, Photographer, 8/2005 - Idaho National Engineering Laboratory, Idaho Chemical Processing Plant, Fuel Reprocessing Complex, Scoville, Butte County, ID

VIEW OF CRANE LOADING AND UNLOADING AREA OF FUEL STORAGE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

VIEW OF CRANE LOADING AND UNLOADING AREA OF FUEL STORAGE BUILDING (CPP-603). PHOTO TAKEN LOOKING SOUTH. INL PHOTO NUMBER HD-54-17-1. Mike Crane, Photographer, 8/2005 - Idaho National Engineering Laboratory, Idaho Chemical Processing Plant, Fuel Reprocessing Complex, Scoville, Butte County, ID

FRONT OBLIQUE SHOWING REAR OF CARPORT STORAGE AREA. VIEW FACING ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

FRONT OBLIQUE SHOWING REAR OF CARPORT STORAGE AREA. VIEW FACING SOUTH - Camp H.M. Smith and Navy Public Works Center Manana Title VII (Capehart) Housing, Three-Bedroom Single-Family Type 9, Birch Circle, Elm Drive, Elm Circle, and Date Drive, Pearl City, Honolulu County, HI

CLOSEUP OF STORAGE AREA IN ENCLOSED CARPORT. VIEW FACING WEST ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

CLOSEUP OF STORAGE AREA IN ENCLOSED CARPORT. VIEW FACING WEST - Camp H.M. Smith and Navy Public Works Center Manana Title VII (Capehart) Housing, Four-Bedroom, Single-Family Type 10, Birch Circle, Elm Drive, Elm Circle, and Date Drive, Pearl City, Honolulu County, HI

A review on on-board challenges of magnesium-based hydrogen storage materials for automobile applications

NASA Astrophysics Data System (ADS)

Rahman, Md. Wasikur

2017-06-01

The attempt of the review is to realize on-board hydrogen storage technologies concerning magnesium based solid-state matrix to allow fuel cell devices to facilitate sufficient storage capacity, cost, safety and performance requirements to be competitive with current vehicles. Hydrogen, a potential and clean fuel, can be applied in the state-of-the-art technology of `zero emission' vehicles. Hydrogen economy infrastructure both for stationary and mobile purposes is complicated due to its critical physico-chemical properties and materials play crucial roles in every stage of hydrogen production to utilization in fuel cells in achieving high conversion efficiency, safety and robustness of the technologies involved. Moreover, traditional hydrogen storage facilities are rather complicated due to its anomalous properties such as highly porous solids and polymers have intrinsic microporosity, which is the foremost favorable characteristics of fast kinetics and reversibility, but the major drawback is the low storage capacity. In contrast, metal hydrides and complex hydrides have high hydrogen storage capacity but thermodynamically unfavorable. Therefore, hydrogen storage is a real challenge to realize `hydrogen economy' that will solve the critical issues of humanity such as energy depletion, greenhouse emission, air pollution and ultimately climate change. Magnesium based materials, particularly magnesium hydride (MgH2) has been proposed as a potential hydrogen storage material due to its high gravimetric and volumetric capacity as well as environmentally benign properties to work the grand challenge out.

Towards regional, error-bounded landscape carbon storage estimates for data-deficient areas of the world.

PubMed

Willcock, Simon; Phillips, Oliver L; Platts, Philip J; Balmford, Andrew; Burgess, Neil D; Lovett, Jon C; Ahrends, Antje; Bayliss, Julian; Doggart, Nike; Doody, Kathryn; Fanning, Eibleis; Green, Jonathan; Hall, Jaclyn; Howell, Kim L; Marchant, Rob; Marshall, Andrew R; Mbilinyi, Boniface; Munishi, Pantaleon K T; Owen, Nisha; Swetnam, Ruth D; Topp-Jorgensen, Elmer J; Lewis, Simon L

2012-01-01

Monitoring landscape carbon storage is critical for supporting and validating climate change mitigation policies. These may be aimed at reducing deforestation and degradation, or increasing terrestrial carbon storage at local, regional and global levels. However, due to data-deficiencies, default global carbon storage values for given land cover types such as 'lowland tropical forest' are often used, termed 'Tier 1 type' analyses by the Intergovernmental Panel on Climate Change (IPCC). Such estimates may be erroneous when used at regional scales. Furthermore uncertainty assessments are rarely provided leading to estimates of land cover change carbon fluxes of unknown precision which may undermine efforts to properly evaluate land cover policies aimed at altering land cover dynamics. Here, we present a repeatable method to estimate carbon storage values and associated 95% confidence intervals (CI) for all five IPCC carbon pools (aboveground live carbon, litter, coarse woody debris, belowground live carbon and soil carbon) for data-deficient regions, using a combination of existing inventory data and systematic literature searches, weighted to ensure the final values are regionally specific. The method meets the IPCC 'Tier 2' reporting standard. We use this method to estimate carbon storage over an area of33.9 million hectares of eastern Tanzania, reporting values for 30 land cover types. We estimate that this area stored 6.33 (5.92-6.74) Pg C in the year 2000. Carbon storage estimates for the same study area extracted from five published Africa-wide or global studies show a mean carbon storage value of ∼50% of that reported using our regional values, with four of the five studies reporting lower carbon storage values. This suggests that carbon storage may have been underestimated for this region of Africa. Our study demonstrates the importance of obtaining regionally appropriate carbon storage estimates, and shows how such values can be produced for a relatively

Nanocomposite polymeric materials for high density optical storage

NASA Astrophysics Data System (ADS)

Criante, L.; Castagna, R.; Vita, F.; Lucchetta, D. E.; Simoni, F.

2009-02-01

We report the results of an extended investigation performed on composite polymeric materials with the aim of obtaining compounds suitable for holographic recording. In order to investigate the material properties a characterization of holographic reflection gratings at different writing wavelength (514.5, 457 and 405 nm) has been performed. The volume grating presents high diffraction efficiency (>60%), high sensitivity (>103 cm J-1) and refractive index modulation Δn≈0.01 even for writing wavelength in the blue range. We show that following a strategy of two basic components leading to phase separation during the photopolymerization process, most of the requirements for holographic data storage are achieved. The one that needs further improvement concerns long term mechanical stability.

SLUDGE TREATMENT PROJECT PHASE 1 SLUDGE STORAGE OPTIONS ASSESSMENT OF T PLANT VERSUS ALTERNATE STORAGE FACILITY

DOE Office of Scientific and Technical Information (OSTI.GOV)

RUTHERFORD WW; GEUTHER WJ; STRANKMAN MR

2009-04-29

The CH2M HILL Plateau Remediation Company (CHPRC) has recommended to the U.S. Department of Energy (DOE) a two phase approach for removal and storage (Phase 1) and treatment and packaging for offsite shipment (Phase 2) of the sludge currently stored within the 105-K West Basin. This two phased strategy enables early removal of sludge from the 105-K West Basin by 2015, allowing remediation of historical unplanned releases of waste and closure of the 100-K Area. In Phase 1, the sludge currently stored in the Engineered Containers and Settler Tanks within the 105-K West Basin will be transferred into sludge transportmore » and storage containers (STSCs). The STSCs will be transported to an interim storage facility. In Phase 2, sludge will be processed (treated) to meet shipping and disposal requirements and the sludge will be packaged for final disposal at a geologic repository. The purpose of this study is to evaluate two alternatives for interim Phase 1 storage of K Basin sludge. The cost, schedule, and risks for sludge storage at a newly-constructed Alternate Storage Facility (ASF) are compared to those at T Plant, which has been used previously for sludge storage. Based on the results of the assessment, T Plant is recommended for Phase 1 interim storage of sludge. Key elements that support this recommendation are the following: (1) T Plant has a proven process for storing sludge; (2) T Plant storage can be implemented at a lower incremental cost than the ASF; and (3) T Plant storage has a more favorable schedule profile, which provides more float, than the ASF. Underpinning the recommendation of T Plant for sludge storage is the assumption that T Plant has a durable, extended mission independent of the K Basin sludge interim storage mission. If this assumption cannot be validated and the operating costs of T Plant are borne by the Sludge Treatment Project, the conclusions and recommendations of this study would change. The following decision-making strategy

Davisson-Germer Prize Talk: Hydrogen storage in nanoporous materials

NASA Astrophysics Data System (ADS)

Chabal, Yves

2009-03-01

To develop a hydrogen-based energy technology, several classes of materials are being considered to achieve the DOE targets for gravimetric and volumetric hydrogen densities for hydrogen storage, including liquids (e.g. ammonium borohydrides), clathrate structures, complex metal hydrides, nanostructured (e.g. carbon) an nanoporous materials. Fundamental studies are necessary to determine the ultimate hydrogen capacity of each system. Nanoporous Metal-organic Framework (MOF) materials are promising candidates for hydrogen storage because the chemical nature and size of their unit cell can be tailored to weakly attract and incorporate H2 molecules, with good volumetric and mass density. In this talk, we consider the structure M2(BDC)2(TED), where M is a metal atom (Zn, Ni, Cu), BDC is benzenedicarboxylate and TED triethylenediamine, to determine the location and interaction of H2 molecules within the MOF. These compounds are isostructural and crystallize in the tetragonal phase (space group P4/ncc), they construct 3D porous structures with relatively large pore size (˜7-8 A ), pore volume (˜0.63-0.84 cc/g) and BET surface area (˜1500-1900 m^2/g). At high pressures (300-800 psi), the perturbation of the H-H stretching mode can be measured with IR absorption spectroscopy, showing a 35 cm-1 redshift from the unperturbed ortho (4155 cm-1 ) and para (4161 cm-1 ) frequencies. Using a newly developed non empirical van der Waals DFT method vdW-DFT),ootnotetextJ.Y. Lee, D.H. Olson, L. Pan, T.J. Emge, J. Li, Adv. Func. Mater. 17, 1255 (2007) it can be shown that the locus of the deepest H2 binding positions lies within to types of narrow channels. The energies of the most stable binding sites, as well as the number of such binding sites, are consistent with the values obtained from experimental adsorption isotherms, and heat of adsorption) data.ootnotetextM. Dion, H. Ryberg, E. Schroder, D. C. Langreth, B.I. Lundqvist, Phys. Rev. Lett. 92, 246401 (2004). Importantly, the

Radiation Heat Transfer Modeling Improved for Phase-Change, Thermal Energy Storage Systems

NASA Technical Reports Server (NTRS)

Kerslake, Thomas W.; Jacqmin, David A.

1998-01-01

Spacecraft solar dynamic power systems typically use high-temperature phase-change materials to efficiently store thermal energy for heat engine operation in orbital eclipse periods. Lithium fluoride salts are particularly well suited for this application because of their high heat of fusion, long-term stability, and appropriate melting point. Considerable attention has been focused on the development of thermal energy storage (TES) canisters that employ either pure lithium fluoride (LiF), with a melting point of 1121 K, or eutectic composition lithium-fluoride/calcium-difluoride (LiF-20CaF2), with a 1040 K melting point, as the phase-change material. Primary goals of TES canister development include maximizing the phase-change material melt fraction, minimizing the canister mass per unit of energy storage, and maximizing the phase-change material thermal charge/discharge rates within the limits posed by the container structure.

Multifunctional Carbon Nanostructures for Advanced Energy Storage Applications

PubMed Central

Wang, Yiran; Wei, Huige; Lu, Yang; Wei, Suying; Wujcik, Evan K.; Guo, Zhanhu

2015-01-01

Carbon nanostructures—including graphene, fullerenes, etc.—have found applications in a number of areas synergistically with a number of other materials.These multifunctional carbon nanostructures have recently attracted tremendous interest for energy storage applications due to their large aspect ratios, specific surface areas, and electrical conductivity. This succinct review aims to report on the recent advances in energy storage applications involving these multifunctional carbon nanostructures. The advanced design and testing of multifunctional carbon nanostructures for energy storage applications—specifically, electrochemical capacitors, lithium ion batteries, and fuel cells—are emphasized with comprehensive examples. PMID:28347034

Bi-Axial Strain Response of Structural Materials and Superconducting NB3SN Wires at 295 K, 7 K, and 4 K

NASA Astrophysics Data System (ADS)

Nyilas, A.; Weiss, K. P.

2008-03-01

A new extensometer capable of measuring diametral strains during axial loading of structural materials and superconducting composite wires has been developed. Using this new transducer it is possible to determine both the averaged axial strain and the transverse strain. The diametral extensometer with a mass of around 1 g is foreseen to be clamped onto the wire inside the averaging double extensometer sensing device system. The sensitivity of this new diametral extensometer is very high, nearly a factor of ten higher than the axial extensometer system. In addition, for structural materials and for composite materials an adjustable diametral extensometer enabling to test specimens between 5 mm and 15 mm diameter has been also developed and tested successfully at 4 K. For materials 304 L, Inconel 718, and modified Type 316LN stainless steel cast alloy the Poisson's coefficient could be determined at 295 K. Type 310 S stainless steel has been investigated at 7 K and at 4 K using the adjustable extensometer to determine the Poisson's coefficient, too. Furthermore, different types of superconducting A15 phase composite wires with diameters between 0.8 and 1.3 mm's were characterized in axial and diametral orientation.

Cryogenic temperature control by means of energy storage materials. [for long space voyages

NASA Technical Reports Server (NTRS)

Grodzka, P. G.; Picklesimer, E. A.; Connor, L. E.

1977-01-01

An investigation was conducted to study the concept of thermal control by means of physical or chemical reaction heats for applications involving the storage of cryogens during long-term space voyages. The investigation included some preliminary experimental tests of energy storage material (ESM) effectiveness. The materials considered can store and liberate large amounts of thermal energy by means of mechanisms such as sensible heat, heat of fusion, and physical or chemical reaction heat. A differential thermal analysis was utilized in the laboratory tests. Attention is given to the evaluation of cryogenic ESM thermal control concepts, the experimental determination of phase change materials characteristics, and adsorption ESMs. It is found that an ESM shield surrounded by multiple layer insulation provides the best protection for a cryogen store.

The potential impact of ozone on materials in the U.K.

NASA Astrophysics Data System (ADS)

Lee, David S.; Holland, Michael R.; Falla, Norman

Recent reports have highlighted the potential damage caused to a range of media, including materials, by ozone (O 3). The limited data available indicate significant damage to rubber products and surface coatings but either insignificant or unquantifiable damage to textiles and other polymeric materials at the range of atmospheric concentrations encountered in the U.K. Materials in the indoor environment have been excluded from economic analyses. Legislation was put in place in 1993 in the U.K. in order to reduce NO x (NO x = NO + NO 2) and VOC (volatile organic compounds) emissions from motor vehicles which is likely to result in reduced peak O 3 episodes but increased average levels of O 3 in urban areas which may result in increased damage to materials. A detailed assessment of the costs of O 3 damage to materials is not currently possible because of insufficient information on relevant dose-response functions and the stock at risk. Alternative methods were thus adopted to determine the potential scale of the problem. Scaling of U.S. estimates made in the late 1960s provides a range for the U.K. of £170 million-£345 million yr -1 in current terms. This includes damage to surface coatings and elastomers, and the cost of antiozonant protection applied to rubber goods. Independent estimates were made of the costs of protecting rubber goods in the U.K. These were based on the size of the antiozonant market, and provide cost ranges of £25 million-£63 million yr -1 to manufacturers and £25 million-£189 million yr -1 to consumers. The only rubber goods for which a damage estimate (not including protection costs) could be made were tyres, using data from the U.S.A. and information on annual tyre sales in the U.K. A range of £0-£4 million yr -1 was estimated. The cost of damage to other rubber goods could not be quantified because of a lack of data on both the stock at risk and exposure-response functions. The effect of O 3 on the costs of repainting were

Formation of CaB6 in the thermal decomposition of the hydrogen storage material Ca(BH4)2.

PubMed

Sahle, Christoph J; Sternemann, Christian; Giacobbe, Carlotta; Yan, Yigang; Weis, Christopher; Harder, Manuel; Forov, Yury; Spiekermann, Georg; Tolan, Metin; Krisch, Michael; Remhof, Arndt

2016-07-20

Using a combination of high resolution X-ray powder diffraction and X-ray Raman scattering spectroscopy at the B K- and Ca L2,3-edges, we analyzed the reaction products of Ca(BH4)2 after annealing at 350 °C and 400 °C under vacuum conditions. We observed the formation of nanocrystalline/amorphous CaB6 mainly and found only small contributions from amorphous B for annealing times larger than 2 h. For short annealing times of 0.5 h at 400 °C we observed neither CaB12H12 nor CaB6. The results indicate a reaction pathway in which Ca(BH4)2 decomposes to B and CaH2 and finally reacts to form CaB6. These findings confirm the potential of using Ca(BH4)2 as a hydrogen storage medium and imply the desired cycling capabilities for achieving high-density hydrogen storage materials.

Early Childhood Safety Checklist #3: Kitchen and Food Preparation and Storage Areas.

ERIC Educational Resources Information Center

Aronson, Susan S.

1994-01-01

This checklist of 24 specific health and safety concerns dealing with kitchen and food preparation storage areas can be used by day-care staff to identify and correct hazardous conditions. Areas of concern include hand washing, refrigeration, cooking, trash disposal, cleanliness, fire safety, burn hazards, and adult supervision. (MDM)

Electric field enhanced hydrogen storage on polarizable materials substrates

PubMed Central

Zhou, J.; Wang, Q.; Sun, Q.; Jena, P.; Chen, X. S.

2010-01-01

Using density functional theory, we show that an applied electric field can substantially improve the hydrogen storage properties of polarizable substrates. This new concept is demonstrated by adsorbing a layer of hydrogen molecules on a number of nanomaterials. When one layer of H2 molecules is adsorbed on a BN sheet, the binding energy per H2 molecule increases from 0.03 eV/H2 in the field-free case to 0.14 eV/H2 in the presence of an electric field of 0.045 a.u. The corresponding gravimetric density of 7.5 wt% is consistent with the 6 wt% system target set by Department of Energy for 2010. The strength of the electric field can be reduced if the substrate is more polarizable. For example, a hydrogen adsorption energy of 0.14 eV/H2 can be achieved by applying an electric field of 0.03 a.u. on an AlN substrate, 0.006 a.u. on a silsesquioxane molecule, and 0.007 a.u. on a silsesquioxane sheet. Thus, application of an electric field to a polarizable substrate provides a novel way to store hydrogen; once the applied electric field is removed, the stored H2 molecules can be easily released, thus making storage reversible with fast kinetics. In addition, we show that materials with rich low-coordinated nonmetal anions are highly polarizable and can serve as a guide in the design of new hydrogen storage materials. PMID:20133647

A study on cooling characteristics of clathrate compound as low temperature latent heat storage material

NASA Astrophysics Data System (ADS)

Kim, Chang Oh; Kim, Jin Heung; Chung, Nak Kyu

2007-07-01

Materials that can store low temperature latent heat are organic/inorganic chemicals, eutectic salt system and clathrate compound. Clathrate compound is the material that host compound in hydrogen bond forms cage and guest compound is included into it and combined. Crystallization of hydrate is generated at higher temperature than that of ice from pure water. And physical properties according to temperature are stable and congruent melting phenomenon is occurred without phase separation and it has relatively high latent heat. But clathrate compound still has supercooling problem occurred in the course of phase change and supercooling should be minimized because it affects efficiency of equipment very much. Therefore, various studies on additives to restrain this or heat storage methods are needed. Supercooling is the phenomenon that low temperature thermal storage material is not crystallized and existed as liquid for some time under phase change temperature. Because phase change into solid is delayed and it is existed as liquid due to this, heat transfer from low temperature thermal storage material is lowered. Therefore it is not crystallized at original phase change temperature and crystallized after cooled as much as supercooling degree and operation time of refrigerator is increased. In this study was investigated the cooling characteristics of the clathrate compound as a low temperature latent heat storage material. And additive was added to clathrate compound and its supercooling restrain effect was studied experimentally.

Improved dielectric constant and breakdown strength of γ-phase dominant super toughened polyvinylidene fluoride/TiO2 nanocomposite film: an excellent material for energy storage applications and piezoelectric throughput

NASA Astrophysics Data System (ADS)

Mehebub Alam, Md; Ghosh, Sujoy Kumar; Sarkar, Debabrata; Sen, Shrabanee; Mandal, Dipankar

2017-01-01

Titanium dioxide (TiO2) nanoparticles (NPs) embedded γ-phase containing polyvinylidene fluoride (PVDF) nanocomposite (PNC) film turns to an excellent material for energy storage application due to an increased dielectric constant (32 at 1 kHz), enhanced electric breakdown strength (400 MV m-1). It also exhibits a high energy density of 4 J cm-3 which is 25 times higher than that of virgin PVDF. 98% of the electroactive γ-phase has been acheived by the incorporation of TiO2 NPs and the resulting PNC behaves like a super-toughened material due to a dramatic improvement (more than 80%) in the tensile strength. Owing to their electroactive nature and extraordinary mechanical properties, PNC films have a strong ability to fabricate the piezoelectric nanogenerators (PNGs) that have recently been an area of focus regarding mechanical energy harvesting. The feasibility of piezoelectric voltage generation from PNGs is demostrated under the rotating fan that also promises further utility such as rotational speed (RPM) determination.

Thermal storage in drywall using organic phase-change material

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shapiro, M.M.; Feldman, D.; Hawes, D.

1987-01-01

Two mixtures of phase-change material (PCM), 49% butyl stearate with 48% butyl palmitate, and 55% lauric acid with 45% capric acid, diluted 10% with fire retardant, were diffused into 13-mm (0.5-in.) wallboard. No exudation of liquid PCM occurs below 25% by weight. In the wallboard, initial PCM freezing points were 21/sup 0/ and 22/sup 0/C (70/sup 0/ and 72/sup 0/F), respectively, with melting points of 17/sup 0/ and 18/sup 0/C (63/sup 0/ and 64/sup 0/F). For a 4/sup 0/C (7/sup 0/F) temperature swing, thermal storage capacities up to 350 kJ/m/sup 2/ (31 Btu/ft/sup 2/) and 317 kJ/m/sup 2/ (28 Btu/ft/supmore » 2/), respectively, are available. These are equivalent to about 3.8 cm (1.5 in.) of concrete cycled through 7/sup 0/C (13/sup 0/F). Preliminary tests showed little extra flame spread beyond that of unloaded wallboard. The thermal conductivity of the wallboard increased from 0.19 to 0.22 W/m /sup 0/C (0.11 to 0.13 Btu/h ft /sup 0/F) with liquid PCM. During melting, the effective thermal diffusivity falls from 2.1 x 10/sup -7/ m/sup 2//s (2.3 x 10/sup -6/ ft/sup 2//s) for the unloaded wallboard to 1.4 x 10/sup -7/ m/sup 2//s (1.5 x 10/sup -6/ ft/sup 2//s) with 23.4% butyl stearate-palmitate and to 1.6 x 10/sup -7/ m/sup 2//s (1.7 x 10/sup -6/ ft/sup 2//s) with 28% of the lauric-capric mixture. (The mixture fraction is defined as the ratio of PCM mass to gypsum mass.)« less

A Porphyrin Complex as a Self-Conditioned Electrode Material for High-Performance Energy Storage.

PubMed

Gao, Ping; Chen, Zhi; Zhao-Karger, Zhirong; Mueller, Jonathan E; Jung, Christoph; Klyatskaya, Svetlana; Diemant, Thomas; Fuhr, Olaf; Jacob, Timo; Behm, R Jürgen; Ruben, Mario; Fichtner, Maximilian

2017-08-21

The novel functionalized porphyrin [5,15-bis(ethynyl)-10,20-diphenylporphinato]copper(II) (CuDEPP) was used as electrodes for rechargeable energy-storage systems with an extraordinary combination of storage capacity, rate capability, and cycling stability. The ability of CuDEPP to serve as an electron donor or acceptor supports various energy-storage applications. Combined with a lithium negative electrode, the CuDEPP electrode exhibited a long cycle life of several thousand cycles and fast charge-discharge rates up to 53 C and a specific energy density of 345 Wh kg -1 at a specific power density of 29 kW kg -1 . Coupled with a graphite cathode, the CuDEPP anode delivered a specific power density of 14 kW kg -1 . Whereas the capacity is in the range of that of ordinary lithium-ion batteries, the CuDEPP electrode has a power density in the range of that of supercapacitors, thus opening a pathway toward new organic electrodes with excellent rate capability and cyclic stability. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Alkaline earth metal doped tin oxide as a novel oxygen storage material

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dong, Qiang, E-mail: dong@tagen.tohoku.ac.jp; Yin, Shu; Yoshida, Mizuki

2015-09-15

Alkaline earth metal doped tin oxide (SnO{sub 2}) hollow nanospheres with a diameter of 50 nm have been synthesized successfully via a facial solvothermal route in a very simple system composed of only ethanol, acetic acid, SnCl{sub 4}·5H{sub 2}O and A(NO{sub 3}){sub 2}·xH{sub 2}O (A = Mg, Ca, Sr, Ba). The synthesized undoped SnO{sub 2} and A-doped SnO{sub 2} hollow nanospheres were characterized by the oxygen storage capacity (OSC), X-ray diffraction, transmission electron microscopy and the Brunauer–Emmet–Teller (BET) technique. The OSC values of all samples were measured using thermogravimetric-differential thermal analysis. The incorporation of alkaline earth metal ion into tinmore » oxide greatly enhanced the thermal stability and OSC. Especially, Ba-doped SnO{sub 2} hollow nanospheres calcined at 1000 °C for 20 h with a BET surface area of 61 m{sup 2} g{sup −1} exhibited the considerably high OSC of 457 μmol-O g{sup −1} and good thermal stability. Alkaline earth metal doped tin oxide has the potential to be a novel oxygen storage material.« less

Standardized Testing Program for Solid-State Hydrogen Storage Technologies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miller, Michael A.; Page, Richard A.

2012-07-30

In the US and abroad, major research and development initiatives toward establishing a hydrogen-based transportation infrastructure have been undertaken, encompassing key technological challenges in hydrogen production and delivery, fuel cells, and hydrogen storage. However, the principal obstacle to the implementation of a safe, low-pressure hydrogen fueling system for fuel-cell powered vehicles remains storage under conditions of near-ambient temperature and moderate pressure. The choices for viable hydrogen storage systems at the present time are limited to compressed gas storage tanks, cryogenic liquid hydrogen storage tanks, chemical hydrogen storage, and hydrogen absorbed or adsorbed in a solid-state material (a.k.a. solid-state storage). Solid-statemore » hydrogen storage may offer overriding benefits in terms of storage capacity, kinetics and, most importantly, safety.The fervor among the research community to develop novel storage materials had, in many instances, the unfortunate consequence of making erroneous, if not wild, claims on the reported storage capacities achievable in such materials, to the extent that the potential viability of emerging materials was difficult to assess. This problem led to a widespread need to establish a capability to accurately and independently assess the storage behavior of a wide array of different classes of solid-state storage materials, employing qualified methods, thus allowing development efforts to focus on those materials that showed the most promise. However, standard guidelines, dedicated facilities, or certification programs specifically aimed at testing and assessing the performance, safety, and life cycle of these emergent materials had not been established. To address the stated need, the Testing Laboratory for Solid-State Hydrogen Storage Technologies was commissioned as a national-level focal point for evaluating new materials emerging from the designated Materials Centers of Excellence (MCoE) according

Investigation of potential waste material insulating properties at different temperature for thermal storage application

NASA Astrophysics Data System (ADS)

Ali, T. Z. S.; Rosli, A. B.; Gan, L. M.; Billy, A. S.; Farid, Z.

2013-12-01

Thermal energy storage system (TES) is developed to extend the operation of power generation. TES system is a key component in a solar energy power generation plant, but the main issue in designing the TES system is its thermal capacity of storage materials, e.g. insulator. This study is focusing on the potential waste material acts as an insulator for thermal energy storage applications. As the insulator is used to absorb heat, it is needed to find suitable material for energy conversion and at the same time reduce the waste generation. Thus, a small-scale experimental testing of natural cooling process of an insulated tank within a confined room is conducted. The experiment is repeated by changing the insulator from the potential waste material and also by changing the heat transfer fluid (HTF). The analysis presented the relationship between heat loss and the reserved period by the insulator. The results show the percentage of period of the insulated tank withstands compared to tank insulated by foam, e.g. newspaper reserved the period of 84.6% as much as foam insulated tank to withstand the heat transfer of cooking oil to the surrounding. The paper finally justifies the most potential waste material as an insulator for different temperature range of heat transfer fluid.

Theoretical Study of the Metal-Controlled Dehydrogenation Mechanism of MN2H3BH3 (M = Li, Na, K): A New Family of Hydrogen Storage Material.

PubMed

Li, Tong; Zhang, Jian-Guo

2018-02-08

Metal hydrazineboranes (MHBs), as a kind of new hydrogen storage materials, show excellent hydrogen storage performance and dehydrogenation properties. Herein, we designed multiple dehydrogenation pathways to compare the metal-controlled effect. Quantum chemistry theory is used to calculate the crystal structure for determining the molecular structure. With an increase of the metal radius, the energy difference of the isomers also increases. The dehydrogenation pathways of lithium hydrazineborane (path A) and sodium hydrazineborane (path B) appear totally similar to each other in the dehydrogenation process despite the energy barrier, as well as the comparison paths A' (for LiHB) and B' (for NaHB). In contrast with LiHB and NaHB, the tautomeric reaction occurs in the potassium hydrazineborane (KHB) first, and the following dehydrogenation path is similar to that of the LiHB and NaHB. It explores the hydrogen-release properties of the different metal hydrazineboranes and also indcates the affection of the metal in the metal hydrazineboranes hydrogen-storage system.

Metallic phase-change materials for solar dynamic energy storage systems

NASA Astrophysics Data System (ADS)

Lauf, R. J.; Hamby, C., Jr.

1990-12-01

Solar (thermal) dynamic power systems for satellites require a heat storage system that is capable of operating the engine during eclipse. The conventional approach to this thermal storage problem is to use the latent heat of fluoride salts, which would melt during insolation and freeze during eclipse. Although candidate fluorides have large heats of fusion per unit mass, their poor thermal conductivity limits the rate at which energy can be transferred to and from the storage device. System performance is further limited by the high parasitic mass of the superalloy canisters needed to contain the salt. A new thermal storage system is described in which the phase-change material (PCM) is a metal (typically germanium) contained in modular graphite canisters. These modules exhibit good thermal conductivity and low parasitic mass, and they are physically and chemically stable. Prototype modules have survived over 600 melt/freeze cycles without degradation. Advanced concepts to further improve performance are described. These concepts include the selection of ternary eutectic alloys to provide a wider range of useful melting temperatures and the use of infiltration to control the location of liquid alloy and to compensate for differences in thermal expansion.

Towards Regional, Error-Bounded Landscape Carbon Storage Estimates for Data-Deficient Areas of the World

PubMed Central

Willcock, Simon; Phillips, Oliver L.; Platts, Philip J.; Balmford, Andrew; Burgess, Neil D.; Lovett, Jon C.; Ahrends, Antje; Bayliss, Julian; Doggart, Nike; Doody, Kathryn; Fanning, Eibleis; Green, Jonathan; Hall, Jaclyn; Howell, Kim L.; Marchant, Rob; Marshall, Andrew R.; Mbilinyi, Boniface; Munishi, Pantaleon K. T.; Owen, Nisha; Swetnam, Ruth D.; Topp-Jorgensen, Elmer J.; Lewis, Simon L.

2012-01-01

Monitoring landscape carbon storage is critical for supporting and validating climate change mitigation policies. These may be aimed at reducing deforestation and degradation, or increasing terrestrial carbon storage at local, regional and global levels. However, due to data-deficiencies, default global carbon storage values for given land cover types such as ‘lowland tropical forest’ are often used, termed ‘Tier 1 type’ analyses by the Intergovernmental Panel on Climate Change (IPCC). Such estimates may be erroneous when used at regional scales. Furthermore uncertainty assessments are rarely provided leading to estimates of land cover change carbon fluxes of unknown precision which may undermine efforts to properly evaluate land cover policies aimed at altering land cover dynamics. Here, we present a repeatable method to estimate carbon storage values and associated 95% confidence intervals (CI) for all five IPCC carbon pools (aboveground live carbon, litter, coarse woody debris, belowground live carbon and soil carbon) for data-deficient regions, using a combination of existing inventory data and systematic literature searches, weighted to ensure the final values are regionally specific. The method meets the IPCC ‘Tier 2’ reporting standard. We use this method to estimate carbon storage over an area of33.9 million hectares of eastern Tanzania, reporting values for 30 land cover types. We estimate that this area stored 6.33 (5.92–6.74) Pg C in the year 2000. Carbon storage estimates for the same study area extracted from five published Africa-wide or global studies show a mean carbon storage value of ∼50% of that reported using our regional values, with four of the five studies reporting lower carbon storage values. This suggests that carbon storage may have been underestimated for this region of Africa. Our study demonstrates the importance of obtaining regionally appropriate carbon storage estimates, and shows how such values can be produced for

STORAGE AND RECIEVING, TRA662. ELEVATIONS. LOWBAY SECTION ON SOUTH SIDE ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

STORAGE AND RECIEVING, TRA-662. ELEVATIONS. LOW-BAY SECTION ON SOUTH SIDE WAS FLAMMABLE STORAGE AREA. HUMMEL HUMMEL & JONES 1038-MTR-ETR-662-A-3, 6/1960. INL INDEX NO. 532-0653-00-381-102036, REV. 3. - Idaho National Engineering Laboratory, Test Reactor Area, Materials & Engineering Test Reactors, Scoville, Butte County, ID

Krypton adsorption on rutile: State and cross-sectional area at 77 K

NASA Astrophysics Data System (ADS)

Grillet, Y.; Rouquerol, F.; Rouquerol, J.

1985-10-01

A krypton adsorption study was carried out on a polycrystalline TiO 2 sample (98.5% rutile) presently considered as a potential reference material for surface areas. Both adsorption microcalorimetry and volumetry show evidence of a two-dimensional phase change (from 2D fluid to 2D solid) taking place at 77 K before the completion of the monolayer. No such phenomenon is observed neither with nitrogen (which we explain by a strong orientation and a close-packing of this molecule on a polar surface) neither with argon (which we explain by a large incompatibility factor between rutile and an argon crystal). On completion of the monolayer, the krypton molecular cross-sectional area is here around 0.15 nm 2 (instead of the usual 0.17 to 0.21 nm 2).

A study of dynamic SIMS analysis of low-k dielectric materials

NASA Astrophysics Data System (ADS)

Mowat, Ian A.; Lin, Xue-Feng; Fister, Thomas; Kendall, Marius; Chao, Gordon; Yang, Ming Hong

2006-07-01

Dynamic SIMS is an established tool for the characterization of dielectric layers in semiconductors, both for contaminant levels and for composition. As the silicon-based semiconductor industry moves towards the use of copper rather than aluminum, there is also a need to use lower k-dielectric materials to reduce RC delays and to reduce cross-talk between closely spaced metal lines. New dielectric materials pose serious challenges for implementation into semiconductor processes and also for the analytical scientist doing measurements on them. The move from inorganic materials such as SiO 2 to organic or carbon-rich low-k materials is a large change for the SIMS analyst. Low-k dielectric films from different sources can be very different materials with different analytical issues. A SIMS challenge for these materials is dealing with their insulating nature and their also fragility, particularly for porous films. These materials can be extremely sensitive to electron beam damage during charge neutralization, leading to difficulties in determining depth scales and introducing unknown errors to secondary ion counts and their subsequent conversion to concentrations. This paper presents details regarding an investigation of the effects of electron beam exposure on a low-k material. These effects and their potential impact on SIMS data will be investigated using FT-IR, TOF-SIMS, AFM and stylus profilometry.

Sodium hydrazinidoborane: a chemical hydrogen-storage material.

PubMed

Moury, Romain; Demirci, Umit B; Ichikawa, Takayuki; Filinchuk, Yaroslav; Chiriac, Rodica; van der Lee, Arie; Miele, Philippe

2013-04-01

Herein, we present the successful synthesis and full characterization (by (11) B magic-angle-spinning nuclear magnetic resonance spectroscopy, infrared spectroscopy, powder X-ray diffraction) of sodium hydrazinidoborane (NaN2 H3 BH3 , with a hydrogen content of 8.85 wt %), a new material for chemical hydrogen storage. Using lab-prepared pure hydrazine borane (N2 H4 BH3 ) and commercial sodium hydride as precursors, sodium hydrazinidoborane was synthesized by ball-milling at low temperature (-30 °C) under an argon atmosphere. Its thermal stability was assessed by thermogravimetric analysis and differential scanning calorimetry. It was found that under heating sodium hydrazinidoborane starts to liberate hydrogen below 60 °C. Within the range of 60-150 °C, the overall mass loss is as high as 7.6 wt %. Relative to the parent N2 H4 BH3 , sodium hydrazinidoborane shows improved dehydrogenation properties, further confirmed by dehydrogenation experiments under prolonged heating at constant temperatures of 80, 90, 95, 100, and 110 °C. Hence, sodium hydrazinidoborane appears to be more suitable for chemical hydrogen storage than N2 H4 BH3 . Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Inertial energy storage for advanced space station applications

NASA Technical Reports Server (NTRS)

Van Tassel, K. E.; Simon, W. E.

1985-01-01

Because the NASA Space Station will spend approximately one-third of its orbital time in the earth's shadow, depriving it of solar energy and requiring an energy storage system to meet system demands, attention has been given to flywheel energy storage systems. These systems promise high mechanical efficiency, long life, light weight, flexible design, and easily monitored depth of discharge. An assessment is presently made of three critical technology areas: rotor materials, magnetic suspension bearings, and motor-generators for energy conversion. Conclusions are presented regarding the viability of inertial energy storage systems and of problem areas requiring further technology development efforts.

Composite aerogel insulation for cryogenic liquid storage

NASA Astrophysics Data System (ADS)

Kyeongho, Kim; Hyungmook, Kang; Soojin, Shin; In Hwan, Oh; Changhee, Son; Hyung, Cho Yun; Yongchan, Kim; Sarng Woo, Karng

2017-02-01

High porosity materials such as aerogel known as a good insulator in a vacuum range (10-3 ∼ 1 Torr) was widely used to storage and to transport cryogenic fluids. It is necessary to be investigated the performance of aerogel insulations for cryogenic liquid storage in soft vacuum range to atmospheric pressure. A one-dimensional insulating experimental apparatus was designed and fabricated to consist of a cold mass tank, a heat absorber and an annular vacuum space with 5-layer (each 10 mm thickness) of the aerogel insulation materials. Aerogel blanket for cryogenic (used maximum temperature is 400K), aerogel blanket for normal temperature (used maximum temperature is 923K), and combination of the two kinds of aerogel blankets were 5-layer laminated between the cryogenic liquid wall and the ambient wall in vacuum space. Also, 1-D effective thermal conductivities of the insulation materials were evaluated by measuring boil-off rate from liquid nitrogen and liquid argon. In this study, the effective thermal conductivities and the temperature-thickness profiles of the two kinds of insulators and the layered combination of the two different aerogel blankets were presented.

Conductive Boron-Doped Graphene as an Ideal Material for Electrocatalytically Switchable and High-Capacity Hydrogen Storage.

PubMed

Tan, Xin; Tahini, Hassan A; Smith, Sean C

2016-12-07

Electrocatalytic, switchable hydrogen storage promises both tunable kinetics and facile reversibility without the need for specific catalysts. The feasibility of this approach relies on having materials that are easy to synthesize, possessing good electrical conductivities. Graphitic carbon nitride (g-C 4 N 3 ) has been predicted to display charge-responsive binding with molecular hydrogen-the only such conductive sorbent material that has been discovered to date. As yet, however, this conductive variant of graphitic carbon nitride is not readily synthesized by scalable methods. Here, we examine the possibility of conductive and easily synthesized boron-doped graphene nanosheets (B-doped graphene) as sorbent materials for practical applications of electrocatalytically switchable hydrogen storage. Using first-principle calculations, we find that the adsorption energy of H 2 molecules on B-doped graphene can be dramatically enhanced by removing electrons from and thereby positively charging the adsorbent. Thus, by controlling charge injected or depleted from the adsorbent, one can effectively tune the storage/release processes which occur spontaneously without any energy barriers. At full hydrogen coverage, the positively charged BC 5 achieves high storage capacities up to 5.3 wt %. Importantly, B-doped graphene, such as BC 49 , BC 7 , and BC 5 , have good electrical conductivity and can be easily synthesized by scalable methods, which positions this class of material as a very good candidate for charge injection/release. These predictions pave the route for practical implementation of electrocatalytic systems with switchable storage/release capacities that offer high capacity for hydrogen storage.

Experimental Study of Thermal Energy Storage Characteristics using Heat Pipe with Nano-Enhanced Phase Change Materials

NASA Astrophysics Data System (ADS)

Krishna, Jogi; Kishore, P. S.; Brusly Solomon, A.

2017-08-01

The paper presents experimental investigations to evaluate thermal performance of heat pipe using Nano Enhanced Phase Change Material (NEPCM) as an energy storage material (ESM) for electronic cooling applications. Water, Tricosane and nano enhanced Tricosane are used as energy storage materials, operating at different heating powers (13W, 18W and 23W) and fan speeds (3.4V and 5V) in the PCM cooling module. Three different volume percentages (0.5%, 1% and 2%) of Nano particles (Al2O3) are mixed with Tricosane which is the primary PCM. This experiment is conducted to study the temperature distributions of evaporator, condenser and PCM during the heating as well as cooling. The cooling module with heat pipe and nano enhanced Tricosane as energy storage material found to save higher fan power consumption compared to the cooling module that utilities only a heat pipe.

Energy storage deployment and innovation for the clean energy transition

NASA Astrophysics Data System (ADS)

Kittner, Noah; Lill, Felix; Kammen, Daniel M.

2017-09-01

The clean energy transition requires a co-evolution of innovation, investment, and deployment strategies for emerging energy storage technologies. A deeply decarbonized energy system research platform needs materials science advances in battery technology to overcome the intermittency challenges of wind and solar electricity. Simultaneously, policies designed to build market growth and innovation in battery storage may complement cost reductions across a suite of clean energy technologies. Further integration of R&D and deployment of new storage technologies paves a clear route toward cost-effective low-carbon electricity. Here we analyse deployment and innovation using a two-factor model that integrates the value of investment in materials innovation and technology deployment over time from an empirical dataset covering battery storage technology. Complementary advances in battery storage are of utmost importance to decarbonization alongside improvements in renewable electricity sources. We find and chart a viable path to dispatchable US$1 W-1 solar with US$100 kWh-1 battery storage that enables combinations of solar, wind, and storage to compete directly with fossil-based electricity options.

High surface area aerogels for energy storage and efficiency

NASA Astrophysics Data System (ADS)

Maloney, Ryan Patrick

ADAI are demonstrated in a third-generation prototypical thermoelectric generator for automotive waste heat recovery. The second chapter then details two different aerogel-based materials for electrochemical energy storage. It begins with lithium titanate aerogel, which takes advantage of the high surface area of the aerogel morphology to display a batt-cap behavior. This should allow the lithium titanate aerogel to perform at higher rates than would normally be expected for the bulk oxide material. Additionally, the flexibility of the sol-gel process is demonstrated through the incorporation of electrically conductive high-surface area exfoliated graphite nanoplatelets in the oxide. The last section describes the characterization of a LiMn2O 4 spinel coated carbon nanofoam in a non-aqueous electrolyte. The short diffusion path, high surface area and intimately wired architecture of the nanofoam allows the oxide to retain its capacity at significantly higher rates when compared with literature values for the bulk oxide. Additionally, the nanometric length scale improves cycle life, and the high surface area dramatically increases the insertion capacity by providing a higher concentration of surface defects. Taken together, it is clear that aerogels are an extremely attractive class of material for applications pertaining to energy and efficiency, and further research in this area will provide valuable solutions for pressing societal needs. (Abstract shortened by UMI.).

30 CFR 57.4262 - Underground transformer stations, combustible liquid storage and dispensing areas, pump rooms...

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Underground transformer stations, combustible... and Control Firefighting Equipment § 57.4262 Underground transformer stations, combustible liquid storage and dispensing areas, pump rooms, compressor rooms, and hoist rooms. Transformer stations, storage...

30 CFR 57.4262 - Underground transformer stations, combustible liquid storage and dispensing areas, pump rooms...

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Underground transformer stations, combustible... and Control Firefighting Equipment § 57.4262 Underground transformer stations, combustible liquid storage and dispensing areas, pump rooms, compressor rooms, and hoist rooms. Transformer stations, storage...

30 CFR 57.4262 - Underground transformer stations, combustible liquid storage and dispensing areas, pump rooms...

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Underground transformer stations, combustible... and Control Firefighting Equipment § 57.4262 Underground transformer stations, combustible liquid storage and dispensing areas, pump rooms, compressor rooms, and hoist rooms. Transformer stations, storage...

30 CFR 57.4262 - Underground transformer stations, combustible liquid storage and dispensing areas, pump rooms...

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Underground transformer stations, combustible... and Control Firefighting Equipment § 57.4262 Underground transformer stations, combustible liquid storage and dispensing areas, pump rooms, compressor rooms, and hoist rooms. Transformer stations, storage...

30 CFR 57.4262 - Underground transformer stations, combustible liquid storage and dispensing areas, pump rooms...

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Underground transformer stations, combustible... and Control Firefighting Equipment § 57.4262 Underground transformer stations, combustible liquid storage and dispensing areas, pump rooms, compressor rooms, and hoist rooms. Transformer stations, storage...

11. The work area of a typical fuel storage and ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

11. The work area of a typical fuel storage and transfer basin. The wooden floor was built over the 20-foot deep water-filled basin. Buckets filled with irradiated fuel of dummy slugs in the floor and were hung on trolleys attached to the monorail tracks suspended from the ceiling. 85-H807 - B Reactor, Richland, Benton County, WA

A numerical model for thermal energy storage systems utilising encapsulated phase change materials

NASA Astrophysics Data System (ADS)

Jacob, Rhys; Saman, Wasim; Bruno, Frank

2016-05-01

In an effort to reduce the cost of thermal energy storage for concentrated solar power plants, a thermocline storage concept was investigated. Two systems were investigated being a sensible-only and an encapsulated phase change system. Both systems have the potential to reduce the storage tank volume and/or reduce the cost of the filler material, thereby reducing the cost of the system when compared to current two-tank molten salt systems. The objective of the current paper is to create a numerical model capable of designing and simulating the aforementioned thermocline storage concepts in the open source programming language known as Python. The results of the current study are compared to previous numerical results and are found to be in good agreement.

Research opportunities in salt hydrates for thermal energy storage

NASA Astrophysics Data System (ADS)

Braunstein, J.

1983-11-01

The state of the art of salt hydrates as phase change materials for low temperature thermal energy storage is reviewed. Phase equilibria, nucleation behavior and melting kinetics of the commonly used hydrate are summarized. The development of efficient, reliable inexpensive systems based on phase change materials, especially salt hydrates for the storage (and retrieval) of thermal energy for residential heating is outlined. The use of phase change material thermal energy storage systems is not yet widespread. Additional basic research is needed in the areas of crystallization and melting kinetics, prediction of phase behavior in ternary systems, thermal diffusion in salt hydrate systems, and in the physical properties pertinent to nonequilibrium and equilibrium transformations in these systems.

Tetra-n-butylammonium borohydride semiclathrate: a hybrid material for hydrogen storage.

PubMed

Shin, Kyuchul; Kim, Yongkwan; Strobel, Timothy A; Prasad, P S R; Sugahara, Takeshi; Lee, Huen; Sloan, E Dendy; Sum, Amadeu K; Koh, Carolyn A

2009-06-11

In this study, we demonstrate that tetra-n-butylammonium borohydride [(n-C(4)H(9))(4)NBH(4)] can be used to form a hybrid hydrogen storage material. Powder X-ray diffraction measurements verify the formation of tetra-n-butylammonium borohydride semiclathrate, while Raman spectroscopic and direct gas release measurements confirm the storage of molecular hydrogen within the vacant cavities. Subsequent to clathrate decomposition and the release of physically bound H(2), additional hydrogen was produced from the hybrid system via a hydrolysis reaction between the water host molecules and the incorporated BH(4)(-) anions. The additional hydrogen produced from the hydrolysis reaction resulted in a 170% increase in the gravimetric hydrogen storage capacity, or 27% greater storage than fully occupied THF + H(2) hydrate. The decomposition temperature of tetra-n-butylammonium borohydride semiclathrate was measured at 5.7 degrees C, which is higher than that for pure THF hydrate (4.4 degrees C). The present results reveal that the BH(4)(-) anion is capable of stabilizing tetraalkylammonium hydrates.

Doped calcium manganites for advanced high-temperature thermochemical energy storage

DOE PAGES

Babiniec, Sean M.; Coker, Eric N.; Miller, James E.; ...

2015-12-16

Developing efficient thermal storage for concentrating solar power plants is essential to reducing the cost of generated electricity, extending or shifting the hours of operation, and facilitating renewable penetration into the grid. Perovskite materials of the CaB xMn 1-xO 3-δ family, where B = Al or Ti, promise improvements in cost and energy storage density over other perovskites currently under investigation. Thermogravimetric analysis of the thermal reduction and reoxidation of these materials was used to extract equilibrium thermodynamic parameters. Lastly, the results demonstrate that these novel thermochemical energy storage media display the highest reaction enthalpy capacity for perovskites reported tomore » date, with a reaction enthalpy of 390 kJ/kg, a 56% increase over previously reported compositions.« less

Bio-Inspired Fluoro-polydopamine Meets Barium Titanate Nanowires: A Perfect Combination to Enhance Energy Storage Capability of Polymer Nanocomposites.

PubMed

Wang, Guanyao; Huang, Xingyi; Jiang, Pingkai

2017-03-01

Rapid evolution of energy storage devices expedites the development of high-energy-density materials with excellent flexibility and easy processing. The search for such materials has triggered the development of high-dielectric-constant (high-k) polymer nanocomposites. However, the enhancement of k usually suffers from sharp reduction of breakdown strength, which is detrimental to substantial increase of energy storage capability. Herein, the combination of bio-inspired fluoro-polydopamine functionalized BaTiO 3 nanowires (NWs) and a fluoropolymer matrix offers a new thought to prepare polymer nanocomposites. The elaborate functionalization of BaTiO 3 NWs with fluoro-polydopamine has guaranteed both the increase of k and the maintenance of breakdown strength, resulting in significantly enhanced energy storage capability. The nanocomposite with 5 vol % functionalized BaTiO 3 NWs discharges an ultrahigh energy density of 12.87 J cm -3 at a relatively low electric field of 480 MV m -1 , more than three and a half times that of biaxial-oriented polypropylene (BOPP, 3.56 J cm -3 at 600 MV m -1 ). This superior energy storage capability seems to rival or exceed some reported advanced nanoceramics-based materials at 500 MV m -1 . This new strategy permits insights into the construction of polymer nanocomposites with high energy storage capability.

40 CFR 63.1343 - What standards apply to my kilns, clinker coolers, raw material dryers, and open clinker storage...

Code of Federal Regulations, 2014 CFR

2014-07-01

..., clinker coolers, raw material dryers, and open clinker storage piles? 63.1343 Section 63.1343 Protection... Limits § 63.1343 What standards apply to my kilns, clinker coolers, raw material dryers, and open clinker... associated with that kiln, clinker cooler, raw material dryer, and open clinker storage pile. All D/F, HCl...

40 CFR 63.1343 - What standards apply to my kilns, clinker coolers, raw material dryers, and open clinker storage...

Code of Federal Regulations, 2013 CFR

2013-07-01

..., clinker coolers, raw material dryers, and open clinker storage piles? 63.1343 Section 63.1343 Protection... Limits § 63.1343 What standards apply to my kilns, clinker coolers, raw material dryers, and open clinker... associated with that kiln, clinker cooler, raw material dryer, and open clinker storage pile. All D/F, HCl...

High-Temperature Phase Change Materials (PCM) Candidates for Thermal Energy Storage (TES) Applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gomez, J. C.

2011-09-01

It is clearly understood that lower overall costs are a key factor to make renewable energy technologies competitive with traditional energy sources. Energy storage technology is one path to increase the value and reduce the cost of all renewable energy supplies. Concentrating solar power (CSP) technologies have the ability to dispatch electrical output to match peak demand periods by employing thermal energy storage (TES). Energy storage technologies require efficient materials with high energy density. Latent heat TES systems using phase change material (PCM) are useful because of their ability to charge and discharge a large amount of heat from amore » small mass at constant temperature during a phase transformation like melting-solidification. PCM technology relies on the energy absorption/liberation of the latent heat during a physical transformation. The main objective of this report is to provide an assessment of molten salts and metallic alloys proposed as candidate PCMs for TES applications, particularly in solar parabolic trough electrical power plants at a temperature range from 300..deg..C to 500..deg.. C. The physical properties most relevant for PCMs service were reviewed from the candidate selection list. Some of the PCM candidates were characterized for: chemical stability with some container materials; phase change transformation temperatures; and latent heats.« less

A review of catalyst-enhanced magnesium hydride as a hydrogen storage material

NASA Astrophysics Data System (ADS)

Webb, C. J.

2015-09-01

Magnesium hydride remains an attractive hydrogen storage material due to the high hydrogen capacity and low cost of production. A high activation energy and poor kinetics at practical temperatures for the pure material have driven research into different additives to improve the sorption properties. This review details the development of catalytic additives and their effect on the activation energy, kinetics and thermodynamic properties of magnesium hydride.

Toward 3D Printed Hydrogen Storage Materials Made with ABS-MOF Composites.

PubMed

Channell, Megan N; Sefa, Makfir; Fedchak, James A; Scherschligt, Julia; Bible, Michael; Natarajan, Bharath; Klimov, Nikolai N; Miller, Abigail E; Ahmed, Zeeshan; Hartings, Matthew R

2018-02-01

The push to advance efficient, renewable, and clean energy sources has brought with it an effort to generate materials that are capable of storing hydrogen. Metal-organic framework materials (MOFs) have been the focus of many such studies as they are categorized for their large internal surface areas. We have addressed one of the major shortcomings of MOFs (their processibility) by creating and 3D printing a composite of acrylonitrile butadiene styrene (ABS) and MOF-5, a prototypical MOF, which is often used to benchmark H 2 uptake capacity of other MOFs. The ABS-MOF-5 composites can be printed at MOF-5 compositions of 10% and below. Other physical and mechanical properties of the polymer (glass transition temperature, stress and strain at the breaking point, and Young's modulus) either remain unchanged or show some degree of hardening due to the interaction between the polymer and the MOF. We do observe some MOF-5 degradation through the blending process, likely due to the ambient humidity through the purification and solvent casting steps. Even with this degradation, the MOF still retains some of its ability to uptake H 2 , seen in the ability of the composite to uptake more H 2 than the pure polymer. The experiments and results described here represent a significant first step toward 3D printing MOF-5-based materials for H 2 storage.

Corrosion Behavior of Nuclear Waste Storage Canister Materials

NASA Astrophysics Data System (ADS)

Grant, John

The nature of interaction of mild steel nuclear waste storage containers with technetium ions is not fully known. Technetium is formed during nuclear processing and some of this technetium has leaked at the Hanford nuclear waste storage site in Washington State. It is often found as highly oxidized pertechnetate (TeO4-) anions at these storage sites which also happen to be highly alkaline and contain a significant amount of nitrate. Theoretically, pertechnetate anions can act as electron acceptors and interact with the mild steel containers and accelerate the oxidation (corrosion) of steel. It is of interest to identify if pertechnetate anions pose a corrosion hazard to the mild steel nuclear waste storage tanks, under the conditions of the storage sites, as that can accelerate the degradation of the tanks and lead to further contamination. In this thesis, the interaction of two relevant container materials, namely, steel alloys A285 and A537 with a technetium surrogate, rhenium was studied. Perrhenate was used as an analog for pertechnetate. As all isotopes of technetium are radioactive, rhenium was chosen as the experimental surrogate due to its chemical similarity to technetium. Electrochemical behavior was evaluated using potentiodynamic polarization tests, and the surface morphology was studied using optical microscopy and scanning electron microscopy. Potentiodynamic polarization tests were conducted in 1.0M NaNO3 + 0.1M NaOH and 1.0M NaNO3 + 0.1M NaOH + 0.02M NaReO4. Tests were performed at three different temperatures, namely, (i) room temperature, (ii) 50°C and (iii) 80°C to study the effect of higher temperatures found in the storage sites. Corrosion current, corrosion potential, anodic and cathodic Tafel slopes, polarization resistance and corrosion rates were obtained from electrochemical testing and evaluated. Increasing temperatures was found to lead to increasing corrosion rates for all samples. The data also revealed increased corrosion from

7. Photocopy of engineering drawing. PROJECT WS315A HELIUM STORAGE AREA: ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

7. Photocopy of engineering drawing. PROJECT WS-315A HELIUM STORAGE AREA: PLAN AND DETAILS-MECHANICAL, APRIL 1956. - Cape Canaveral Air Station, Launch Complex 17, Facility 28419, East end of Lighthouse Road, Cape Canaveral, Brevard County, FL

Wax: A benign hydrogen-storage material that rapidly releases H2-rich gases through microwave-assisted catalytic decomposition

PubMed Central

Gonzalez-Cortes, S.; Slocombe, D. R.; Xiao, T.; Aldawsari, A.; Yao, B.; Kuznetsov, V. L.; Liberti, E.; Kirkland, A. I.; Alkinani, M. S.; Al-Megren, H. A.; Thomas, J. M.; Edwards, P. P.

2016-01-01

Hydrogen is often described as the fuel of the future, especially for application in hydrogen powered fuel-cell vehicles (HFCV’s). However, its widespread implementation in this role has been thwarted by the lack of a lightweight, safe, on-board hydrogen storage material. Here we show that benign, readily-available hydrocarbon wax is capable of rapidly releasing large amounts of hydrogen through microwave-assisted catalytic decomposition. This discovery offers a new material and system for safe and efficient hydrogen storage and could facilitate its application in a HFCV. Importantly, hydrogen storage materials made of wax can be manufactured through completely sustainable processes utilizing biomass or other renewable feedstocks. PMID:27759014

Characterization of Representative Materials in Support of Safe, Long Term Storage of Surplus Plutonium in DOE-STD-3013 Containers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Narlesky, Joshua E.; Stroud, Mary Ann; Smith, Paul Herrick

2013-02-15

The Surveillance and Monitoring Program is a joint Los Alamos National Laboratory/Savannah River Site effort funded by the Department of Energy-Environmental Management to provide the technical basis for the safe, long-term storage (up to 50 years) of over 6 metric tons of plutonium stored in over 5,000 DOE-STD-3013 containers at various facilities around the DOE complex. The majority of this material is plutonium that is surplus to the nuclear weapons program, and much of it is destined for conversion to mixed oxide fuel for use in US nuclear power plants. The form of the plutonium ranges from relatively pure metalmore » and oxide to very impure oxide. The performance of the 3013 containers has been shown to depend on moisture content and on the levels, types and chemical forms of the impurities. The oxide materials that present the greatest challenge to the storage container are those that contain chloride salts. Other common impurities include oxides and other compounds of calcium, magnesium, iron, and nickel. Over the past 15 years the program has collected a large body of experimental data on 54 samples of plutonium, with 53 chosen to represent the broader population of materials in storage. This paper summarizes the characterization data, moisture analysis, particle size, surface area, density, wattage, actinide composition, trace element impurity analysis, and shelf life surveillance data and includes origin and process history information. Limited characterization data on fourteen nonrepresentative samples is also presented.« less

Characterization of representative materials in support of safe, long term storage of surplus plutonium in DOE-STD-3013 containers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, Paul H; Narlesky, Joshua E; Worl, Laura A

2010-01-01

The Surveillance and Monitoring Program (SMP) is a joint LANL/SRS effort funded by DOE/EM to provide the technical basis for the safe, long-term storage (up to 50 years) of over 6 metric tons of plutonium stored in over 5000 DOE-STD-3013 containers at various facilities around the DOE complex. The majority of this material is plutonium that is surplus to the nuclear weapons program, and much of it is destined for conversion to mixed oxide fuel for use in US nuclear power plants. The form of the plutonium ranges from relatively pure metal and oxide to very impure oxide. The performancemore » of the 3013 containers has been shown to depend on moisture content and on the levels, types and chemical forms of the impurities. The oxide materials that present the greatest challenge to the storage container are those that contain chloride salts. The chlorides (NaCl, KCl, CaCl{sub 2}, and MgCl{sub 2}) range from less than half of the impurities present to nearly all the impurities. Other common impurities include oxides and other compounds of calcium, magnesium, iron, and nickel. Over the past 15 years the program has collected a large body of experimental data on over 60 samples of plutonium chosen to represent the broader population of materials in storage. This paper will summarize the characterization data, including the origin and process history, particle size, surface area, density, calorimetry, chemical analysis, moisture analysis, prompt gamma, gas generation and corrosion behavior.« less

10 CFR 40.26 - General license for possession and storage of byproduct material as defined in this part.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 10 Energy 1 2010-01-01 2010-01-01 false General license for possession and storage of byproduct material as defined in this part. 40.26 Section 40.26 Energy NUCLEAR REGULATORY COMMISSION DOMESTIC LICENSING OF SOURCE MATERIAL General Licenses § 40.26 General license for possession and storage of...

Dilatometer setup for low coefficient of thermal expansion materials measurements in the 140 K-250 K temperature range.

PubMed

Spannagel, Ruven; Hamann, Ines; Sanjuan, Josep; Schuldt, Thilo; Gohlke, Martin; Johann, Ulrich; Weise, Dennis; Braxmaier, Claus

2016-10-01

Space applications demand light weight materials with excellent dimensional stability for telescopes, optical benches, optical resonators, etc. Glass-ceramics and composite materials can be tuned to reach very low coefficient of thermal expansion (CTE) at different temperatures. In order to determine such CTEs, very accurate setups are needed. Here we present a dilatometer that is able to measure the CTE of a large variety of materials in the temperature range of 140 K to 250 K. The dilatometer is based on a heterodyne interferometer with nanometer noise levels to measure the expansion of a sample when applying small amplitude controlled temperature signals. In this article, the CTE of a carbon fiber reinforced polymer sample has been determined with an accuracy in the 10 -8 K -1 range.

Natural diatomite modified as novel hydrogen storage material

NASA Astrophysics Data System (ADS)

Jin, Jiao; Zheng, Chenghui; Yang, Huaming

2014-03-01

Natural diatomite, subjected to different modifications, is investigated for hydrogen adsorption capacities at room temperature. An effective metal-modified strategy is developed to disperse platinum (Pt) and palladium (Pd) nanoparticles on the surface of diatomite. Hydrogen adsorption capacity of pristine diatomite (diatomite) is 0.463 wt.% at 2.63 MPa and 298 K, among the highest of the known sorbents, while that of acid-thermally activated diatomite (A-diatomite) could reach up to 0.833 wt.% due to the appropriate pore properties by activation. By incorporation with a small amount of Pt and Pd ( 0.5 wt.%), hydrogen adsorption capacities are enhanced to 0.696 wt.% and 0.980 wt.%, respectively, indicating that activated diatomite shows interesting application in the field of hydrogen storage at room temperature.

Display area, looking north towards the classified storage rooms, D.M. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Display area, looking north towards the classified storage rooms, D.M. Logistics and D.O. Offices in northwest corner. Viewing bridge is at upper left, and alert status display at upper right - March Air Force Base, Strategic Air Command, Combat Operations Center, 5220 Riverside Drive, Moreno Valley, Riverside County, CA

Organic n-type materials for charge transport and charge storage applications.

PubMed

Stolar, Monika; Baumgartner, Thomas

2013-06-21

Conjugated materials have attracted much attention toward applications in organic electronics in recent years. These organic species offer many advantages as potential replacement for conventional materials (i.e., silicon and metals) in terms of cheap fabrication and environmentally benign devices. While p-type (electron-donating or hole-conducting) materials have been extensively reviewed and researched, their counterpart n-type (electron-accepting or electron-conducting) materials have seen much less popularity despite the greater need for improvement. In addition to developing efficient charge transport materials, it is equally important to provide a means of charge storage, where energy can be used on an on-demand basis. This perspective is focused on discussing a selection of representative n-type materials and the efforts toward improving their charge-transport efficiencies. Additionally, this perspective will also highlight recent organic materials for battery components and the efforts that have been made to improve their environmental appeal.

Cryo-Milling and the Hydrogen Storage Properties of NaAlH4

NASA Astrophysics Data System (ADS)

Feller, Kevin; Dobbins, Tabbetha

2013-03-01

High energy ball milling of metal hydrides is a common way to both introduce catalysts (e.g. TiCl3) and to simultaneously increase the surface area. Both catalysis and increased surface area improve hydrogen storage capacity of the material. Nanostructuring of hydrides by depositing them into mesoporous templates (such as anodized alumina, MOFs, and SBA-15) has become a common way to increase surface area. However, the mesoporous template does not add hydrogen storage capacity--and thus, tends to decreased overall storage weight percent for the nanostructured hydride material. As with most materials, hydrides become brittle at low temperatures and will tend to fracture more readily. We will process Sodium Aluminum Hydride (NaAlH4) using cryogenic high energy ball milling using an in-house modified chamber SPEX Certiprep M8000 mixer/mill in order to gain a nanostructured hydride without mesoporous template material. Details of the modified mixer mill design will be presented. Ultimately, our planned future work is to study the resultant material using x-ray diffraction (Scherrer method for crystallite size), absorption/desorption temperature programmed desorption (TPD), and ultrasmall-angle x-ray scattering (USAXS) microstructural quantification to understand the role of cryomilling on enhancing the material's ability to store (and release) hydrogen.

48 CFR 252.223-7006 - Prohibition on storage and disposal of toxic and hazardous materials.

Code of Federal Regulations, 2012 CFR

2012-10-01

... disposal of toxic and hazardous materials. 252.223-7006 Section 252.223-7006 Federal Acquisition... and disposal of toxic and hazardous materials. As prescribed in 223.7103(a), use the following clause: Prohibition on Storage and Disposal of Toxic and Hazardous Materials (APR 2012) (a) Definitions. As used in...

48 CFR 252.223-7006 - Prohibition on storage and disposal of toxic and hazardous materials.

Code of Federal Regulations, 2010 CFR

2010-10-01

... disposal of toxic and hazardous materials. 252.223-7006 Section 252.223-7006 Federal Acquisition... and disposal of toxic and hazardous materials. As prescribed in 223.7103(a), use the following clause: Prohibition on Storage and Disposal of Toxic and Hazardous Materials (APR 1993) (a) Definitions. As used in...

48 CFR 252.223-7006 - Prohibition on storage and disposal of toxic and hazardous materials.

Code of Federal Regulations, 2013 CFR

2013-10-01

... disposal of toxic and hazardous materials. 252.223-7006 Section 252.223-7006 Federal Acquisition... and disposal of toxic and hazardous materials. As prescribed in 223.7103(a), use the following clause: Prohibition on Storage and Disposal of Toxic and Hazardous Materials (APR 2012) (a) Definitions. As used in...

48 CFR 252.223-7006 - Prohibition on storage and disposal of toxic and hazardous materials.

Code of Federal Regulations, 2011 CFR

2011-10-01

... disposal of toxic and hazardous materials. 252.223-7006 Section 252.223-7006 Federal Acquisition... and disposal of toxic and hazardous materials. As prescribed in 223.7103(a), use the following clause: Prohibition on Storage and Disposal of Toxic and Hazardous Materials (APR 1993) (a) Definitions. As used in...

Hydrogen-based electrochemical energy storage

DOEpatents

Simpson, Lin Jay

2013-08-06

An energy storage device (100) providing high storage densities via hydrogen storage. The device (100) includes a counter electrode (110), a storage electrode (130), and an ion conducting membrane (120) positioned between the counter electrode (110) and the storage electrode (130). The counter electrode (110) is formed of one or more materials with an affinity for hydrogen and includes an exchange matrix for elements/materials selected from the non-noble materials that have an affinity for hydrogen. The storage electrode (130) is loaded with hydrogen such as atomic or mono-hydrogen that is adsorbed by a hydrogen storage material such that the hydrogen (132, 134) may be stored with low chemical bonding. The hydrogen storage material is typically formed of a lightweight material such as carbon or boron with a network of passage-ways or intercalants for storing and conducting mono-hydrogen, protons, or the like. The hydrogen storage material may store at least ten percent by weight hydrogen (132, 134) at ambient temperature and pressure.

Phase Change Material Thermal Power Generator

NASA Technical Reports Server (NTRS)

Jones, Jack A. (Inventor); Chao, Yi (Inventor); Valdez, Thomas I. (Inventor)

2014-01-01

An energy producing device, for example a submersible vehicle for descending or ascending to different depths within water or ocean, is disclosed. The vehicle comprises a temperature-responsive material to which a hydraulic fluid is associated. A pressurized storage compartment stores the fluid as soon as the temperature-responsive material changes density. The storage compartment is connected with a hydraulic motor, and a valve allows fluid passage from the storage compartment to the hydraulic motor. An energy storage component, e.g. a battery, is connected with the hydraulic motor and is charged by the hydraulic motor when the hydraulic fluid passes through the hydraulic motor. Upon passage in the hydraulic motor, the fluid is stored in a further storage compartment and is then sent back to the area of the temperature-responsive material.

Phase change material thermal power generator

NASA Technical Reports Server (NTRS)

Jones, Jack A. (Inventor); Chao, Yi (Inventor); Valdez, Thomas I. (Inventor)

2011-01-01

An energy producing device, for example a submersible vehicle for descending or ascending to different depths within water or ocean, is disclosed. The vehicle comprises a temperature-responsive material to which a hydraulic fluid is associated. A pressurized storage compartment stores the fluid as soon as the temperature-responsive material changes density. The storage compartment is connected with a hydraulic motor, and a valve allows fluid passage from the storage compartment to the hydraulic motor. An energy storage component, e.g. a battery, is connected with the hydraulic motor and is charged by the hydraulic motor when the hydraulic fluid passes through the hydraulic motor. Upon passage in the hydraulic motor, the fluid is stored in a further storage compartment and is then sent back to the area of the temperature-responsive material.

Energy conversion and storage program

NASA Astrophysics Data System (ADS)

Cairns, E. J.

1992-03-01

The Energy Conversion and Storage Program applies chemistry and materials science principles to solve problems in: (1) production of new synthetic fuels; (2) development of high-performance rechargeable batteries and fuel cells; (3) development of advanced thermochemical processes for energy conversion; (4) characterization of complex chemical processes; and (5) application of novel materials for energy conversion and transmission. Projects focus on transport-process principles, chemical kinetics, thermodynamics, separation processes, organic and physical chemistry, novel materials, and advanced methods of analysis. Electrochemistry research aims to develop advanced power systems for electric vehicle and stationary energy storage applications. Topics include identification of new electrochemical couples for advanced rechargeable batteries, improvements in battery and fuel-cell materials, and the establishment of engineering principles applicable to electrochemical energy storage and conversion. Chemical Applications research includes topics such as separations, catalysis, fuels, and chemical analyses. Included in this program area are projects to develop improved, energy-efficient methods for processing waste streams from synfuel plants and coal gasifiers. Other research projects seek to identify and characterize the constituents of liquid fuel-system streams and to devise energy-efficient means for their separation. Materials Applications research includes the evaluation of the properties of advanced materials, as well as the development of novel preparation techniques. For example, the use of advanced techniques, such as sputtering and laser ablation, are being used to produce high-temperature superconducting films.

Hydrogen storage methods.

PubMed

Züttel, Andreas

2004-04-01

Hydrogen exhibits the highest heating value per mass of all chemical fuels. Furthermore, hydrogen is regenerative and environmentally friendly. There are two reasons why hydrogen is not the major fuel of today's energy consumption. First of all, hydrogen is just an energy carrier. And, although it is the most abundant element in the universe, it has to be produced, since on earth it only occurs in the form of water and hydrocarbons. This implies that we have to pay for the energy, which results in a difficult economic dilemma because ever since the industrial revolution we have become used to consuming energy for free. The second difficulty with hydrogen as an energy carrier is its low critical temperature of 33 K (i.e. hydrogen is a gas at ambient temperature). For mobile and in many cases also for stationary applications the volumetric and gravimetric density of hydrogen in a storage material is crucial. Hydrogen can be stored using six different methods and phenomena: (1) high-pressure gas cylinders (up to 800 bar), (2) liquid hydrogen in cryogenic tanks (at 21 K), (3) adsorbed hydrogen on materials with a large specific surface area (at T<100 K), (4) absorbed on interstitial sites in a host metal (at ambient pressure and temperature), (5) chemically bonded in covalent and ionic compounds (at ambient pressure), or (6) through oxidation of reactive metals, e.g. Li, Na, Mg, Al, Zn with water. The most common storage systems are high-pressure gas cylinders with a maximum pressure of 20 MPa (200 bar). New lightweight composite cylinders have been developed which are able to withstand pressures up to 80 MPa (800 bar) and therefore the hydrogen gas can reach a volumetric density of 36 kg.m(-3), approximately half as much as in its liquid state. Liquid hydrogen is stored in cryogenic tanks at 21.2 K and ambient pressure. Due to the low critical temperature of hydrogen (33 K), liquid hydrogen can only be stored in open systems. The volumetric density of liquid hydrogen

Hydrogen storage methods

NASA Astrophysics Data System (ADS)

Züttel, Andreas

Hydrogen exhibits the highest heating value per mass of all chemical fuels. Furthermore, hydrogen is regenerative and environmentally friendly. There are two reasons why hydrogen is not the major fuel of today's energy consumption. First of all, hydrogen is just an energy carrier. And, although it is the most abundant element in the universe, it has to be produced, since on earth it only occurs in the form of water and hydrocarbons. This implies that we have to pay for the energy, which results in a difficult economic dilemma because ever since the industrial revolution we have become used to consuming energy for free. The second difficulty with hydrogen as an energy carrier is its low critical temperature of 33 K (i.e. hydrogen is a gas at ambient temperature). For mobile and in many cases also for stationary applications the volumetric and gravimetric density of hydrogen in a storage material is crucial. Hydrogen can be stored using six different methods and phenomena: (1) high-pressure gas cylinders (up to 800 bar), (2) liquid hydrogen in cryogenic tanks (at 21 K), (3) adsorbed hydrogen on materials with a large specific surface area (at T<100 K), (4) absorbed on interstitial sites in a host metal (at ambient pressure and temperature), (5) chemically bonded in covalent and ionic compounds (at ambient pressure), or (6) through oxidation of reactive metals, e.g. Li, Na, Mg, Al, Zn with water. The most common storage systems are high-pressure gas cylinders with a maximum pressure of 20 MPa (200 bar). New lightweight composite cylinders have been developed which are able to withstand pressures up to 80 MPa (800 bar) and therefore the hydrogen gas can reach a volumetric density of 36 kg.m-3, approximately half as much as in its liquid state. Liquid hydrogen is stored in cryogenic tanks at 21.2 K and ambient pressure. Due to the low critical temperature of hydrogen (33 K), liquid hydrogen can only be stored in open systems. The volumetric density of liquid hydrogen is