Correlation of basic TL, OSL and IRSL properties of ten K-feldspar samples of various origins

NASA Astrophysics Data System (ADS)

Sfampa, I. K.; Polymeris, G. S.; Pagonis, V.; Theodosoglou, E.; Tsirliganis, N. C.; Kitis, G.

2015-09-01

Feldspars stand among the most widely used minerals in dosimetric methods of dating using thermoluminescence (TL), optically stimulated luminescence (OSL) and infrared stimulated luminescence (IRSL). Having very good dosimetric properties, they can in principle contribute to the dating of every site of archaeological and geological interest. The present work studies basic properties of ten naturally occurring K-feldspar samples belonging to three feldspar species, namely sanidine, orthoclase and microcline. The basic properties studied are (a) the influence of blue light and infrared stimulation on the thermoluminescence glow-curves, (b) the growth of OSL, IRSL, residual TL and TL-loss as a function of OSL and IRSL bleaching time and (c) the correlation between the OSL and IRSL signals and the energy levels responsible for the TL glow-curve. All experimental data were fitted using analytical expressions derived from a recently developed tunneling recombination model. The results show that the analytical expressions provide excellent fits to all experimental results, thus verifying the tunneling recombination mechanism in these materials and providing valuable information about the concentrations of luminescence centers.

Late Quaternary cooling rate constrained by multiple IRSL thermochronometers of potassium feldspars for granites from Kongur Shan, Chinese Pamir

NASA Astrophysics Data System (ADS)

Qin, Jintang; Chen, Jie; Valla, Pierre; Herman, Frédéric

2015-04-01

The Kongur Shan (East Pamir), located at the northwestern Tibetan Plateau, is one of the most active orogens on Earth, where both tectonic processes along major active faults and climatic forcing (extensive glaciers coverage) are contributing to the regional landscape evolution. The exhumation rates since late Miocene was constrained to be ~6.5 - 4.2 mm/yr. However, it is still debated whether the exhumation rate accelerated since the Quaternary, of which the climate was featured by the cyclic glaciations with periods of 100 ka and 40 ka. In this study, we tried to employ luminescence thermochronology, which is a still in developing method, to resolve the impact of glacial cycles on exhumation rate. Our study site is located ~10 km to the east of the active Kongur normal fault, along the major valley of Gez river. We sampled three granite rocks from a sub-horizontal tunnel across the granite massif; one was from the entrance of the tunnel, and other two samples were from inside of the tunnel, where the measured ambient temperature is as high as 60-70 ° C. The distances of these samples are within 2 km. Four types of IRSL signals extracted from potassium feldspars (K-feldspars) were measured for each individual sample, and the results of isothermal decay experiments indicated these signals were of different thermal stabilities. Therefore, they may serve as four thermochronometers with different closure temperature. We employ these multiple thermochronometers together for each single sample to constrain their cooling rates. Our preliminary results, which are based on the simplified luminescence model of K-feldspars, suggest that the averaged cooling rate of the last 200 ka is as high as 1.4 oC/ka, which corresponds to an exhumation rate of ~ 2.3 to 0.9 cm/yr with the geothermal gradient assumed to be 60 to 150 oC/km. It seems to imply that the glacial cycles during the Quaternary substantially accelerated the exhumation rate of granite massif of Kongur Shan.

Cooling and inferred uplift/erosion history of the Grenville Orogen, Ontario: Constraints from sup 40 Ar/ sup 39 Ar thermochronology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cosca, M.A.

1989-01-01

Thermochronological ({sup 40}Ar/{sup 39}Ar) data are presented from 76 mineral separates of hornblende, muscovite, biotite, phlogopite, and K-feldspar. Samples were selected from regionally metamorphosed gneiss, amphibolite, metasediment, marble, metagabbro and pegmatite across the two major metamorphic belts of the Grenville Province, the Central Metasedimentary Belt (CMB) and the Central Gneiss Belt (CGB). When combined with published temperature estimates for closure to argon diffusion in the phases analyzed, cooling rates from {approximately}500 C to {approximately}120 C of 1-4 C/MA are calculated across the entire Grenville Province of Ontario. Regional uplift/erosion rates for the Grenville Orogen of Ontario have been estimated frommore » the {sup 40}Ar/{sup 39}Ar data, a retrograde P-T path for rocks of the CGB, and an upper time constraint provided by flat, overlying Cambro-Ordovician sediments. Twenty-two of the hornblendes used for thermochronology have been quantitatively analyzed for major elements by microprobe, Fe{sup 2+}/Fe{sup 3+} by wet chemistry, and for H{sub 2}O by manometric measurement. Water activities calculated from hornblende equilibria are typically low (<0.01) because of the exponential dilutions in hornblende (tremolite) activity required by present activity-composition models. An oxyamphibole component of 25% further reduces any amphibole component and the H{sub 2}O activity by as much as 50% below that calculated with simplifying assumption. These findings indicate that different amphibole normalization schemes have a marked effect on the activity calculated for a specific amphibole or H{sub 2}O, and should be carefully evaluated.« less

A detailed study of ice nucleation by feldspar minerals

NASA Astrophysics Data System (ADS)

Whale, T. F.; Murray, B. J.; Wilson, T. W.; Carpenter, M. A.; Harrison, A.; Holden, M. A.; Vergara Temprado, J.; Morris, J.; O'Sullivan, D.

2015-12-01

when modelling ice nucleation in mixed phase clouds. Atkinson, J. D., Murray, B. J., Woodhouse, M. T., Carslaw, K. S., Whale, T. F., Baustian, K. J., Dobbie, S., O'Sullivan, D., and Malkin, T. L.: The importance of feldspar for ice nucleation by mineral dust in mixed-phase clouds, Nature, 10.1038/nature12278, (2013).

Naturally weathered feldspar surfaces in the Navajo Sandstone aquifer, Black Mesa, Arizona: Electron microscopic characterization

NASA Astrophysics Data System (ADS)

Zhu, Chen; Veblen, David R.; Blum, Alex E.; Chipera, Stephen J.

2006-09-01

Naturally weathered feldspar surfaces in the Jurassic Navajo Sandstone at Black Mesa, Arizona, was characterized with high-resolution transmission and analytical electron microscope (HRTEM-AEM) and field emission gun scanning electron microscope (FEG-SEM). Here, we report the first HRTEM observation of a 10-nm thick amorphous layer on naturally weathered K-feldspar in currently slightly alkaline groundwater. The amorphous layer is probably deficient in K and enriched in Si. In addition to the amorphous layer, the feldspar surfaces are also partially coated with tightly adhered kaolin platelets. Outside of the kaolin coatings, feldspar grains are covered with a continuous 3-5 μm thick layer of authigenic smectite, which also coats quartz and other sediment grains. Authigenic K-feldspar overgrowth and etch pits were also found on feldspar grains. These characteristics of the aged feldspar surfaces accentuate the differences in reactivity between the freshly ground feldspar powders used in laboratory experiments and feldspar grains in natural systems, and may partially contribute to the commonly observed apparent laboratory-field dissolution rate discrepancy. At Black Mesa, feldspars in the Navajo Sandstone are dissolving at ˜10 5 times slower than laboratory rate at comparable temperature and pH under far from equilibrium condition. The tightly adhered kaolin platelets reduce the feldspar reactive surface area, and the authigenic K-feldspar overgrowth reduces the feldspar reactivity. However, the continuous smectite coating layer does not appear to constitute a diffusion barrier. The exact role of the amorphous layer on feldspar dissolution kinetics depends on the origin of the layer (leached layer versus re-precipitated silica), which is uncertain at present. However, the nanometer thin layer can be detected only with HRTEM, and thus our study raises the possibility of its wide occurrence in geological systems. Rate laws and proposed mechanisms should consider the

Naturally weathered feldspar surfaces in the Navajo Sandstone aquifer, Black Mesa, Arizona: Electron microscopic characterization

USGS Publications Warehouse

Zhu, Chen; Veblen, D.R.; Blum, A.E.; Chipera, S.J.

2006-01-01

Naturally weathered feldspar surfaces in the Jurassic Navajo Sandstone at Black Mesa, Arizona, was characterized with high-resolution transmission and analytical electron microscope (HRTEM-AEM) and field emission gun scanning electron microscope (FEG-SEM). Here, we report the first HRTEM observation of a 10-nm thick amorphous layer on naturally weathered K-feldspar in currently slightly alkaline groundwater. The amorphous layer is probably deficient in K and enriched in Si. In addition to the amorphous layer, the feldspar surfaces are also partially coated with tightly adhered kaolin platelets. Outside of the kaolin coatings, feldspar grains are covered with a continuous 3-5 ??m thick layer of authigenic smectite, which also coats quartz and other sediment grains. Authigenic K-feldspar overgrowth and etch pits were also found on feldspar grains. These characteristics of the aged feldspar surfaces accentuate the differences in reactivity between the freshly ground feldspar powders used in laboratory experiments and feldspar grains in natural systems, and may partially contribute to the commonly observed apparent laboratory-field dissolution rate discrepancy. At Black Mesa, feldspars in the Navajo Sandstone are dissolving at ???105 times slower than laboratory rate at comparable temperature and pH under far from equilibrium condition. The tightly adhered kaolin platelets reduce the feldspar reactive surface area, and the authigenic K-feldspar overgrowth reduces the feldspar reactivity. However, the continuous smectite coating layer does not appear to constitute a diffusion barrier. The exact role of the amorphous layer on feldspar dissolution kinetics depends on the origin of the layer (leached layer versus re-precipitated silica), which is uncertain at present. However, the nanometer thin layer can be detected only with HRTEM, and thus our study raises the possibility of its wide occurrence in geological systems. Rate laws and proposed mechanisms should consider the

Iron isotope behavior during fluid/rock interaction in K-feldspar alteration zone - A model for pyrite in gold deposits from the Jiaodong Peninsula, East China

NASA Astrophysics Data System (ADS)

Zhu, Zhi-Yong; Jiang, Shao-Yong; Mathur, Ryan; Cook, Nigel J.; Yang, Tao; Wang, Meng; Ma, Liang; Ciobanu, Cristiana L.

2018-02-01

Mechanisms for Fe isotope fractionation in hydrothermal mineral deposits and in zones of associated K-feldspar alteration remain poorly constrained. We have analyzed a suite of bulk samples consisting of granite displaying K-feldspar alteration, Precambrian metamorphic rocks, and pyrite from gold deposits of the Jiaodong Peninsula, East China, by multi-collector inductively-coupled plasma mass spectrometry. Pyrites from disseminated (J-type) ores show a δ56Fe variation from +0.01 to +0.64‰, overlapping with the signature of the host granites (+0.08 to +0.39‰). In contrast, pyrites from quartz veins (L-type ores) show a wide range of Fe-isotopic composition from -0.78 to +0.79‰. Negative values are never seen in the J-type pyrites. The Fe isotope signature of the host granite with K-feldspar alteration is significantly heavier than that of the bulk silicate Earth. The Fe isotopic compositions of Precambrian metamorphic rocks across the district display a narrow range between -0.16‰ and +0.19‰, which is similar to most terrestrial rocks. Concentrations of major and trace elements in bulk samples were also determined, so as to evaluate any correlation between Fe isotope composition and degree of alteration. We note that during progressive K-feldspar alteration to rocks containing >70 wt% SiO2, >75 ppm Rb, and <1.2 wt% total Fe2O3, the Fe isotope composition of the granite changes systematically. The Fe isotope signature becomes heavier as the degree of alteration increases. The extremely light Fe isotopic compositions in L-type gold deposits may be explained by Rayleigh fractionation during pyrite precipitation in an open fracture system. We note that the sulfur isotopic compositions of pyrite in the two types of ores are also different. Pyrite from J-type ores has a systematically 3.5‰-higher δ34S value (11.2‰) than those of pyrite from the L-type ores (7.7‰). There is, however, no correlation between Fe and S isotope signatures. The isotopic

Low-Temperature Thermochronology for Unraveling Thermal Processes and Dating of Fault Zones

NASA Astrophysics Data System (ADS)

Tagami, T.

2016-12-01

Thermal signatures as well as timing of fault motions can be constrained by thermochronological analyses of fault-zone rocks (e.g., Tagami, 2012). Fault-zone materials suitable for such analyses are produced by tectocic and geochemical processes, such as (1) mechanical fragmentation of host rocks, grain-size reduction of fragments and recrystallization of grains to form mica and clay minerals, (2) secondary heating/melting of host rocks by frictional fault motions, and (3) mineral vein formation as a consequence of fluid advection associated with fault motions. The geothermal structure of fault zones are primarily controlled by the following three factors: (a) regional geothermal structure around the fault zone that reflect background thermo-tectonic history of studied province, (b) frictional heating of wall rocks by fault motions and resultant heat transfer into surrounding rocks, and (c) thermal influences by hot fluid advection in and around the fault zone. Thermochronological methods widely applied in fault zones are K-Ar (40Ar/39Ar), fission-track (FT), and U-Th methods. In addition, OSL, TL, ESR and (U-Th)/He methods are applied in some fault zones, in order to extract temporal imformation related to low temperature and/or very recent fault activities. Here I briefly review the thermal sensitivity of individual thermochronological systems, which basically controls the response of each method against faulting processes. Then, the thermal sensitivity of FTs is highlighted, with a particular focus on the thermal processes characteristic to fault zones, i.e., flash and hydrothermal heating. On these basis, representative examples as well as key issues, including sampling strategy, are presented to make thermochronologic analysis of fault-zone materials, such as fault gouges, pseudotachylytes and mylonites, along with geological, geomorphological and seismological implications. Finally, the thermochronologic analyses of the Nojima fault are overviewed, as an

A comparative study of K-rich and Na/Ca-rich feldspar ice-nucleating particles in a nanoliter droplet freezing assay

NASA Astrophysics Data System (ADS)

Peckhaus, Andreas; Kiselev, Alexei; Hiron, Thibault; Ebert, Martin; Leisner, Thomas

2016-09-01

A recently designed droplet freezing assay was used to study the freezing of up to 1500 identical 0.2 nL water droplets containing suspensions of one Na/Ca-rich feldspar and three K-rich and one Na/Ca-rich feldspar particles. Three types of experiments have been conducted: cooling ramp, isothermal freezing at a constant temperature, and freeze-thaw cycles. The observed freezing behavior has been interpreted with the help of a model based on the classical nucleation theory (soccer ball model (SBM); Niedermeier et al., 2015). By applying the model to the different freezing experiments conducted with the same ice-nucleating material, the unique sets of model parameters for specific feldspar suspensions could be derived. The SBM was shown to adequately describe the observed cooling rate dependence, the ice-nucleating active sites (INAS) surface density ns(T) in a wide temperature range, and the shift of the freezing curves towards lower temperature with dilution. Moreover, the SBM was capable of reproducing the variation of INAS surface density ns(T) with concentration of ice-nucleating particles in the suspension droplets and correctly predicting the leveling-off of ns(T) at low temperature. The freeze-thaw experiments have clearly shown that the heterogeneous freezing induced even by very active ice-nucleating species still possesses a stochastic nature, with the degree of randomness increasing towards homogeneous nucleation. A population of the high-temperature INAS has been identified in one of the K-rich feldspar samples. The freezing of 0.8 wt % suspension droplets of this particular feldspar was observed already at -5 °C. These high-temperature active sites could be deactivated by treating the sample with hydrogen peroxide but survived heating up to 90 °C. Given a high mass concentration of these high-temperature active sites (2.9 × 108 g-1) and a very low value of contact angle (0.56 rad) the possibility of biological contamination of the sample was

Apatite U-Pb thermochronolgy applied to complex geological settings - insights from geo/thermochronology and geochemistry

NASA Astrophysics Data System (ADS)

Paul, Andre; Spikings, Richard; Ulyanov, Alexey; Chew, David

2016-04-01

Application of high temperature (>350oC) thermochronology is limited to the U-Pb system of accessory minerals, such as apatite, under the assumption that radiogenic lead is lost to thermally activated volume diffusion into an infinite reservoir. Cochrane et al. (2015) have demonstrated a working example from the northern Andes of South America. Predictions from volume diffusion theory were compared with measured single grain U-Pb date correlated to shortest diffusion radius and in-situ profiles measured by LA-ICP-MS. Results from both techniques were found to be in agreement with predictions from thermally activated, volume diffusion. However, outliers from the ID-TIMS data suggested some complexity, as grains were found to be too young relative to their diffusion radius. Interaction of multiple processes can be responsible for the alteration of apatite U-Pb dates such as: (1) metamorphic (over)growth, (2) fluid aided alteration/recrystallization and (3) metamictization and fracturing of the grain. Further, predictions from volume diffusion rely on the input parameters: (a) diffusivity, (b) activation energy and (c) shortest diffusion radius. Diffusivity and activation energy are potentially influenced by the chemical composition and subsequent changes in crystal structure. Currently there is one value for diffusion parameter and activation energy established for (Durango) apatite (Cherniak et al., 1991). Correlation between diffusivity/activation energy and composition has not been established. We investigate if correlations exist between diffusivity/activation energy and composition by obtaining single grain apatite U-Pb date and chemical compostion and correlating these to their diffusion radius. We test the consistency of apatite closure temperature, by comparing the apatite U-Pb dates with lower temperature thermochronometers such as white mica and K-feldspar Ar/Ar and by petrographic observations. We test if chemical information can be a proxy to identify

Identification of Ice Nucleation Active Sites on Feldspar Dust Particles

PubMed Central

2015-01-01

Mineral dusts originating from Earth’s crust are known to be important atmospheric ice nuclei. In agreement with earlier studies, feldspar was found as the most active of the tested natural mineral dusts. Here we investigated in closer detail the reasons for its activity and the difference in the activity of the different feldspars. Conclusions are drawn from scanning electron microscopy, X-ray powder diffraction, infrared spectroscopy, and oil-immersion freezing experiments. K-feldspar showed by far the highest ice nucleation activity. Finally, we give a potential explanation of this effect, finding alkali-metal ions having different hydration shells and thus an influence on the ice nucleation activity of feldspar surfaces. PMID:25584435

An integrated study on microtectonics, geothermometry and thermochronology of the Çataldaǧ Core Complex (NW Turkey): Implications for cooling, deformation and uplift history

NASA Astrophysics Data System (ADS)

Kamaci, Omer; Altunkaynak, Safak

2017-04-01

We present an integrated study on structure, microstructure, geothermometry and thermochronology of the Çataldaǧ Core Complex (ÇCC) in NW Turkey in order to understand the cooling, deformation and uplift mechanisms. ÇCC is formed from an Eo-Oligocene granite-gneiss-migmatite complex (GGMC) and an Early Miocene I-type granodioritic body (ÇG: Çataldaǧ granodiorite) which were exhumed as a dome-shaped core complex in the footwall of a ring-shaped low-angle detachment zone (The Çataldaǧ Detachment Fault Zone; ÇDFZ) in the Early Miocene. New U-Pb zircon (LA-ICPMS) and monazite ages of GGMC yielded magmatic ages of 33.8 and 30.1 Ma (Latest Eocene-Early Oligocene). 40Ar/39Ar muscovite, biotite and K-feldspar from the GGMC yielded the deformation age span 21.38±0,05 Ma and 20.81±0.04 Ma, which is also the emplacement age (20.84±0.13 Ma and 21.6±0.04 Ma) of ÇG. ÇDFZ is responsible for mainly top-to-the-north sense kinematic processes. The microstructural features of quartz, feldspar and mica indicate that the ÇCC has undergone continuous deformations during its cooling, from submagmatic to cataclastic conditions. Five microstructural grades have been classified under ductile (DZ) and ductile-to-brittle shear zone (SZ), according to the estimated deformation temperature and intensity of the strain. Microcline twinning, marginally replacement myrmekite and flame-perthite are predominant features for feldspar while chessboard extinction, grain boundary migration and subgrain rotation recrystallization is common for quartz in the DZ which has a deformation temperature range of >600°C to 400°C. Grain size reduction is an important factor for the ductile to brittle shear zone (SZ). Feldspar is represented by bulging recrystallization (BLG), feldspar-fish and domino-type microfracture/microfaulting and quartz show more elongated structures such as ribbons with high aspect ratios. Mineral-fish (muscovite, biotite and feldspar) structures indicate a temperature

500 Myr of thermal history elucidated by multi-method detrital thermochronology of North Gondwana Cambrian sandstone (Eilat area, Israel)

NASA Astrophysics Data System (ADS)

Vermeesch, P.; Avigad, D.

2009-04-01

Following the Neoproterozoic Pan-African orogeny, the Arabian-Nubian Shield (ANS) of North Africa and Arabia was eroded and then covered by Cambrian sandstones that record the onset of platform sedimentation. We applied K-feldspar 40Ar/39Ar, zircon and apatite fission track and apatite (U-Th)/He thermochronology to detritus from Cambrian sandstones of southern Israel deposited at about 500 Ma. U-Pb detrital zircon ages from these sandstones predate deposition and record the earlier Neoproterozoic crustal evolution of the Pan-African orogens. 40Ar/39Ar ages from 50 single grains of K-feldspar yield a Cambrian mean of approximately 535 Ma. The 40Ar/39Ar age spectrum of a multi-grain K-feldspar aliquot displays diffusion behaviour compatible with >560 Ma cooling later affected by a heating event. Assuming that the high temperature domains of the K-feldspars have not been affected by subsequent (hydro)thermal events, and taking previously published K-Ar and Rb-Sr ages from other parts of the East African Orogen at face value, these ages apparently record Pan-African thermal resetting below a thick volcano-sedimentary pile similar to the Saramuj conglomerate in Jordan and/or the Hammamat in Egypt. Detrital zircon fission track (ZFT) ages cluster around 380 Ma, consistent with previous ZFT results from Neoproterozoic basement and sediments of the region, revealing that the Cambrian platform sequence experienced a middle Devonian thermal event and low-grade metamorphism. Regional correlation indicates that during Devonian time the sedimentary cover atop the Cambrian in Israel was never in excess of 2.5 km, requiring an abnormally steep geothermal gradient to explain the complete ZFT annealing. A basal Carboniferous unconformity can be traced from Syria to southern Saudi Arabia, suggesting that the observed Devonian ZFT ages represent a regional tectonothermal event. Similar Devonian ZFT ages were reported from ANS basement outcrops in the Eastern Desert, 500 km south of

K-feldspar megacryst accumulations formed by mechanical instabilities in magma chamber margins, Asha pluton, NW Argentina

NASA Astrophysics Data System (ADS)

Rocher, Sebastián; Alasino, Pablo H.; Grande, Marcos Macchioli; Larrovere, Mariano A.; Paterson, Scott R.

2018-07-01

The Asha pluton, the oldest unit of the San Blas intrusive complex (Early Carboniferous), exhibits impressive examples of magmatic structures formed by accumulation of K-feldspar megacrysts, enclaves, and schlieren. Almost all recognized structures are meter-scale, vertically elongate bodies of variable shapes defined as fingers, trails, drips, and blobs. They preferentially developed near the external margin of the Asha pluton and generally are superimposed by chamber-wide magmatic fabrics. They mostly have circular or sub-circular transverse sections with an internal fabric defined by margin-parallel, inward-dipping concentric foliation and steeply plunging lineation at upper parts and flat foliation at lower parts. The concentration of megacrysts usually grades from upper sections, where they appear in a proportion similar to the host granite, to highly packed accumulations of K-feldspar along with grouped flattened enclaves at lower ends. These features suggest an origin by downward localized multiphase magmatic flow, narrowing and 'log jamming', and gravitational sinking of grouped crystals and enclaves, with compaction and filter pressing as main mechanisms of melt removal. Crystal size distribution analysis supports field observations arguing for a mechanical origin of accumulations. The magmatic structures of the Asha pluton represent mechanical instabilities generated by thermal and compositional convection, probably owing to cooling and crystallization near the pluton margins during early stages of construction of the intrusive complex.

Comparative study of ice nucleating efficiency of K-feldspar in immersion and deposition freezing modes

NASA Astrophysics Data System (ADS)

Hiron, T.; Hoffmann, N.; Peckhaus, A.; Kiselev, A. A.; Leisner, T.; Flossmann, A. I.

2016-12-01

One of the main challenges in understanding the evolution of Earth's climate resides in the understanding the role of ice nucleation on the development of tropospheric clouds as well as its initiation. K-feldspar is known to be a very active ice nucleating particle and this study focuses on the characterization of its activity in two heterogeneous nucleation modes, immersion and deposition freezing.We use a newly built humidity-controlled cold stage allowing the simultaneous observation of up to 2000 identical 0.6-nanoliter droplets containing suspension of mineral dust particles. The droplets are first cooled down to observe immersion freezing, the obtained ice crystals are then evaporated and finally, the residual particles are exposed to the water vapor supersaturated with respect to ice.The ice nucleation abilities for the individual residual particles are then compared for the different freezing modes and correlation between immersion ice nuclei and deposition ice nuclei is investigated.Based on the electron microscopy analysis of the residual particles, we discuss the possible relationship between the ice nucleation properties of feldspar and its microstructure. Finally, we discuss the atmospheric implications of our experimental results, using DESCAM, a 1.5D bin-resolved microphysics model.

Application of Cathodoluminescence to The Study of Feldspars: Imaging and Spectrometry

NASA Astrophysics Data System (ADS)

Fonseca, Rute; Couto, Helena

2017-12-01

Cathodoluminescence (CL) studies were carried out on polished thin sections of different feldspar samples (from migmatites, granites, aplite-pegmatites and granitic aggregates) using a hot cathode CL equipment HC3-LM coupled to an optical microscope and to a spectrometer (SpectraPro 2300i and a CCD Pixis 400B detector and the software Winspec32) from the Faculty of Sciences of University of Porto. The system was operated at 14kV and a filament current of 0.18 mA. The samples were coated with a thin gold film using a Cressington 108 Auto device. Luminescence images were acquired during the CL analysis with an adapted digital video-camera (KAPPA PS 40C-285 (DX) with dual stage Peltier cooling) and an acquisition time between 351ms and 3,52s. The CL study, including imaging and spectrometry, proved to be an important tool to complement the feldspar petrography as it contributes to the identification of features not observed under optical microscope. The application of the Cathodoluminescence to feldspar allows distinguishing between potassic feldspar and plagioclase, differentiating generations of feldspar and displaying internal zoning and growth areas, among other. The spectrometry complements the CL imaging. It allows obtaining a qualitative level of emission intensity, which permits the interpretation of the nature of this luminescence in each feldspar. Bands shown in the spectra are related to the existing activator elements. In the present study, it was found an association of each feldspar to different spectra and respective colour. The plagioclases exhibit yellow or green luminescence. The activator element is Mn2+, showing a broad emission band between 550 - 570 nm specially detected on this type of feldspars, due to the replacement of K+ for Mn2+. The potassium feldspars have more or less intense blue colour associated with various activators elements: the activator element is Cu2+ showing a broad emission band between 420±5 nm. This emission band can be

Ammonium in aqueous fluids to 600 °C, 1.3 GPa: A spectroscopic study on the effects on fluid properties, silica solubility, and K-feldspar to muscovite reactions

NASA Astrophysics Data System (ADS)

Schmidt, Christian; Watenphul, Anke

2010-12-01

The behavior of ammonium, NH 4+, in aqueous systems was studied based on Raman spectroscopic experiments to 600 °C and about 1.3 GPa. Spectra obtained at ambient conditions revealed a strong reduction of the dynamic three-dimensional network of water with addition of ammonium chloride, particularly at small solute concentrations. The differential scattering cross section of the ν 1-NH 4+ Raman band in these solutions was found to be similar to that of salammoniac. The Raman band of silica monomers at ˜780 cm -1 was present in all spectra of the fluid at high temperatures in hydrothermal diamond-anvil cell experiments with H 2O ± NH 4Cl and quartz or the assemblage quartz + kyanite + K-feldspar ± muscovite/tobelite. However, these spectra indicated that dissolved silica is less polymerized in ammonium chloride solutions than in comparable experiments with water. Quantification based on the normalized integrated intensity of the H 4SiO 40 band showed that the silica solubility in experiments with H 2O + NH 4Cl was significantly lower than that in equimolal NaCl solutions. This suggests that ammonium causes a stronger decrease in the activity of water in chloridic solutions than sodium. The Raman spectra of the fluid also showed that a significant fraction of ammonium was converted to ammonia, NH 3, in all experiments at temperatures above 300 °C. This indicates a shift towards acidic conditions for experiments without a buffering mineral assemblage. The estimated pH of the fluid was ˜2 at 600 °C, 0.26 GPa, 6.6 m initial NH 4Cl, based on the ratio of the integrated ν 1-NH 3 and ν 1-NH 4+ intensities and the HCl 0 dissociation constant. The NH 3/NH 4+ ratio increased with temperature and decreased with pressure. This implies that more ammonium should be retained in K-bearing minerals coexisting with chloridic fluids upon high- P low- T metamorphism. At 500 °C, 0.73 GPa, ammonium partitions preferentially into the fluid, as constrained from infrared

Silicon self-diffusion in single-crystal natural quartz and feldspar

NASA Astrophysics Data System (ADS)

Cherniak, D. J.

2003-09-01

Silicon diffusion was measured in natural quartz and anorthitic feldspar under dry, low-pressure (0.1 MPa) conditions using a 30Si tracer. Sources of diffusant consisted of 30Si-enriched silica powder for experiments on quartz and microcrystalline 30Si-doped synthetic feldspar of composition comparable to the feldspar specimens. Distributions of 30Si were measured with Rutherford backscattering spectrometry and nuclear reaction analysis, using the reaction 30Si (p,γ) 31P. The following Arrhenius relations were obtained for anneals at 1 atm in air. For quartz: transport normal to c: Dqtz,⊥c=7.97×10 -6 exp (-447±31 kJ mol -1/ RT) m 2 s -1; transport parallel to c: Dqtz,∥c=6.40×10 -6 exp (-443±22 kJ mol -1/ RT) m 2 s -1. For anorthitic feldspar (An 93): DAn=3.79×10 -7 exp (-465±50 kJ mol -1/ RT) m 2 s -1. The few successful experiments on diffusion in plagioclase of more albitic compositions (An 67 and An 23) reveal Si diffusivities a few orders of magnitude faster than that in the anorthite. The results for these feldspars bracket the determination of CaAl-NaSi interdiffusion under dry conditions by Grove et al. [Geochim. Cosmochim. Acta 48 (1984) 2113-2121], suggesting that the rate-limiting process is indeed Si diffusion. Si diffusion in quartz under more reducing conditions (NNO) is slightly slower (by about half an order of magnitude) than diffusion in samples annealed in air. This is consistent with observations made in studies of synthetic quartz [Béjina and Jaoul, Phys. Earth Planet. Inter. 50 (1988) 240-250].

Late Paleozoic deformation and exhumation in the Sierras Pampeanas (Argentina): 40Ar/39Ar-feldspar dating constraints

NASA Astrophysics Data System (ADS)

Löbens, Stefan; Oriolo, Sebastián; Benowitz, Jeff; Wemmer, Klaus; Layer, Paul; Siegesmund, Siegfried

2017-09-01

Systematic 40Ar/39Ar feldspar data obtained from the Sierras Pampeanas are presented, filling the gap between available high- (> 300 °C) and low-temperature (< 150 °C) thermochronological data. Results show Silurian-Devonian exhumation related to the late stages of the Famatinian/Ocloyic Orogeny for the Sierra de Pocho and the Sierra de Pie de Palo regions, whereas the Sierras de San Luis and the Sierra de Comechingones regions record exhumation during the Carboniferous. Comparison between new and available data points to a Carboniferous tectonic event in the Sierras Pampeanas, which represents a key period to constrain the early evolution of the proto-Andean margin of Gondwana. This event was probably transtensional and played a major role during the evolution of the Paganzo Basin as well as during the emplacement of alkaline magmatism in the retroarc.

Cationic polyelectrolyte induced separation of some inorganic contaminants and their mixture (zirconium silicate, kaolin, K-feldspar, zinc oxide) as well as of the paraffin oil from water.

PubMed

Ghimici, Luminita

2016-03-15

The flocculation efficiency of a cationic polyelectrolyte with quaternary ammonium salt groups in the backbone, namely PCA5 was evaluated on zirconium silicate (kreutzonit), kaolin, K- feldspar and zinc oxide (ZnO) suspensions prepared either with each pollutant or with their mixture. The effect of several parameters such as settling time, polymer dose and the pollutant type on the separation efficacy was evaluated and followed by optical density and zeta potential measurements. Except for ZnO, the interactions between PCA5 and suspended particles led to low residual turbidity values (around 4% for kreutzonit, 5% for kaolin and 8% for K-feldspar) as well as to the reduction of flocs settling time (from 1200 min to 30 min and 120 min in case of kaolinit and K-feldspar, respectively), that meant a high efficiency in their separation. The negative value of the zeta potential and flocs size measurements, at the optimum polymer dose, point to contribution from charge patch mechanism for the particles flocculation. A good efficiency of PCA5 in separation of paraffin oil (a minimum residual turbidity of 9.8%) has been also found. Copyright © 2015 Elsevier Ltd. All rights reserved.

AUthigenic feldspar as an indicator of paleo-rock/water interactions in Permian carbonates of the Northern Calcareous Alps, Austria

USGS Publications Warehouse

Spotl, C.; Kralik, M.; Kunk, Michael J.

1996-01-01

Dolostones interbedded with Upper Permian evaporites at the base of the Northern Calcareous Alps contain abundant authigenic K-feldspar. Two petrographically, structurally, and isotopically distinct generations of K-feldspar can be distinguished: crystals composed of an inclusion-rich core and a clear rim, and optically unzoned, transparent crystals. Both feldspar types have essentially identical K-feldspar end-member compositions with ??? 99.5 mole % Or component. Low oxygen isotope ratios (+16.1??? to +18.1??? SMOW) suggest precipitation from 18O-enriched, saline fluids at temperatures in excess of ??? 140??C. 40Ar/39Ar plateau-age spectra of five samples range from 145 ?? 1 to 144 ?? 1 Ma (Early Berriasian) and suggest that both types of feldspar were formed within an interval that did not exceed ??? 2 m.y. Rb/Sr model ages range from 152 to 140 Ma, assuming that the burial diagenetic regime was buffered with respect to strontium by the associated marine Permian evaporites. Authigenic K-feldspar records two distinct events of hot brine flow, most likely triggered by tectonic movements (detachment) and by an increase in the subsurface temperature in response to thrust loading.

Bridging the timescales between thermochronological and cosmogenic nuclide data

NASA Astrophysics Data System (ADS)

Glotzbach, Christoph

2015-04-01

Reconstructing the evolution of Earth's landscape is a key to understand its future evolution and to identify the driving forces that shape Earth's surface. Cosmogenic nuclide and thermochronological methods are routinely used to quantify Earth surface processes over 102-104 yr and 106-107 yr, respectively (e.g. Lal 1991; Reiners and Ehlers 2005; von Blanckenburg 2006). A comparison of the rates of surface processes derived from these methods is, however, hampered by the large difference in their timescales. For instance, a constant erosion rate of 0.1 mm/yr yield an apatite (U-Th)/He age of ~24 Ma and a 10Be age of ~6 ka, respectively. Analytical methods that bridge this time gap are on the way, but are not yet fully established (e.g. Herman et al. 2010). A ready to use alternative are river profiles, which record the regional uplift history over 102-107 yr (e.g. Pritchard et al. 2009). Changes in uplift are retained in knickzones that propagate with a distinct velocity upstream, and therefore the time of an uplift event can be estimated. Here I present an integrative inverse modelling approach to simultaneously reconstruct river profiles, model thermochronological and cosmogenic nuclide data and to derive robust information about landscape evolution over thousands to millions of years. An efficient inversion routine is used to solve the forward problem and find the best uplift history and erosional parameters that reproduce the observed data. I test the performance of the algorithm by inverting a synthetic dataset and a dataset from the Sila massif (Italy). Results show that even complicated uplift histories can be reliably retrieved by the combined interpretation of river profiles, thermochronological and cosmogenic nuclide data. References Gallagher, K., Brown, R. & Johnson, C. (1998): Fission track analysis and its applications to geological problems. - Annu. Rev. Earth Planet., 26: 519-572. Herman, F., Rhodes, E.J., Braun, J. & Heiniger, L. (2010): Uniform

Regional fluid migration in the Illinois basin: evidence from in situ oxygen isotope analysis of authigenic K-feldspar and quartz from the Mount Simon Sandstone

USGS Publications Warehouse

Chen, Zhensheng; Riciputi, Lee R.; Mora, Claudia I.; Fishman, Neil S.

2001-01-01

Oxygen isotope compositions of widespread, authigenic K-feldspar and quartz overgrowths and cements in the Upper Cambrian Mount Simon Sandstone were measured by ion microprobe in 11 samples distributed across the Illinois basin and its periphery. Average K-feldspar δ18O values increase systematically from +14‰ ± 1‰ in the southernmost and deepest samples in Illinois to +24‰ ± 2‰ in the northernmost outcrop sample in Wisconsin. A similar trend was observed for quartz overgrowths (22‰ ± 2‰ to 28‰ ± 2‰). Constant homogenization temperatures (100–130 °C) of fluid inclusions associated with quartz overgrowths throughout the basin suggest that the geographic trend in oxygen isotope compositions is a result of diagenetic modification of a south to north migrating basinal fluid.

Neon diffusion kinetics and implications for cosmogenic neon paleothermometry in feldspars

DOE PAGES

Tremblay, Marissa M.; Shuster, David L.; Balco, Greg; ...

2017-02-20

Observations of cosmogenic neon concentrations in feldspars can potentially be used to constrain the surface exposure duration or surface temperature history of geologic samples. The applicability of cosmogenic neon to either application depends on the temperature-dependent diffusivity of neon isotopes. Here in this work, we investigate the kinetics of neon diffusion in feldspars of different compositions and geologic origins through stepwise degassing experiments on single, proton-irradiated crystals. To understand the potential causes of complex diffusion behavior that is sometimes manifest as nonlinearity in Arrhenius plots, we compare our results to argon stepwise degassing experiments previously conducted on the same feldspars.more » Many of the feldspars we studied exhibit linear Arrhenius behavior for neon whereas argon degassing from the same feldspars did not. This suggests that nonlinear behavior in argon experiments is an artifact of structural changes during laboratory heating. However, other feldspars that we examined exhibit nonlinear Arrhenius behavior for neon diffusion at temperatures far below any known structural changes, which suggests that some preexisting material property is responsible for the complex behavior. In general, neon diffusion kinetics vary widely across the different feldspars studied, with estimated activation energies (E a) ranging from 83.3 to 110.7 kJ/mol and apparent pre-exponential factors (D 0) spanning three orders of magnitude from 2.4 ×10 -3 to 8.9 × 10 -1 cm 2 s -1. Finally, as a consequence of this variability, the ability to reconstruct temperatures or exposure durations from cosmogenic neon abundances will depend on both the specific feldspar and the surface temperature conditions at the geologic site of interest.« less

Neon diffusion kinetics and implications for cosmogenic neon paleothermometry in feldspars

NASA Astrophysics Data System (ADS)

Tremblay, Marissa M.; Shuster, David L.; Balco, Greg; Cassata, William S.

2017-05-01

Observations of cosmogenic neon concentrations in feldspars can potentially be used to constrain the surface exposure duration or surface temperature history of geologic samples. The applicability of cosmogenic neon to either application depends on the temperature-dependent diffusivity of neon isotopes. In this work, we investigate the kinetics of neon diffusion in feldspars of different compositions and geologic origins through stepwise degassing experiments on single, proton-irradiated crystals. To understand the potential causes of complex diffusion behavior that is sometimes manifest as nonlinearity in Arrhenius plots, we compare our results to argon stepwise degassing experiments previously conducted on the same feldspars. Many of the feldspars we studied exhibit linear Arrhenius behavior for neon whereas argon degassing from the same feldspars did not. This suggests that nonlinear behavior in argon experiments is an artifact of structural changes during laboratory heating. However, other feldspars that we examined exhibit nonlinear Arrhenius behavior for neon diffusion at temperatures far below any known structural changes, which suggests that some preexisting material property is responsible for the complex behavior. In general, neon diffusion kinetics vary widely across the different feldspars studied, with estimated activation energies (Ea) ranging from 83.3 to 110.7 kJ/mol and apparent pre-exponential factors (D0) spanning three orders of magnitude from 2.4 × 10-3 to 8.9 × 10-1 cm2 s-1. As a consequence of this variability, the ability to reconstruct temperatures or exposure durations from cosmogenic neon abundances will depend on both the specific feldspar and the surface temperature conditions at the geologic site of interest.

Influence of rock strength variations on interpretation of thermochronologic data

NASA Astrophysics Data System (ADS)

Flowers, Rebecca; Ehlers, Todd

2017-04-01

Low temperature thermochronologic datasets are the primary means for estimating the timing, magnitude, and rates of erosion over extended (10s to 100s of Ma) timescales. Typically, abrupt shifts in cooling rates recorded by thermochronologic data are interpreted as changes in erosion rates caused by shifts in uplift rates, drainage patterns, or climate. However, recent work shows that different rock types vary in strength and erodibility by as much as several orders of magnitude, therefore implying that lithology should be an important control on how landscapes change through time and the thermochronometer record of erosion histories. Attention in the surface processes community has begun to focus on rock strength as a critical control on short-term (Ka to Ma) landscape evolution, but there has been less consideration of the influence of this factor on landscapes over longer intervals. If intrinsic lithologic variability can strongly modify erosion rates without changes in external factors, this result would have important implications for how thermochronologic datasets are interpreted. Here we evaluate the importance of rock strength for interpreting thermochronologic datasets by examining erosion rates and total denudation magnitudes across sedimentary rock-crystalline basement rock interfaces. We particularly focus on the 'Great Unconformity', a global stratigraphic surface between Phanerozoic sedimentary rocks and Precambrian crystalline basement, which based on rock strength studies marks a dramatic rock erodibility contrast across which erosion rates should decelerate. In the Rocky Mountain basement uplifts of the western U.S., thermochronologic data and geologic observations indicate that erosion rates were high during latest Cretaceous-early Tertiary denudation of the sedimentary cover (3-4 km over 10 m.y., 300-400 m/m.y.) but dramatically decelerated when less erodible basement rocks were encountered (0.1-0.5 km over 55 m.y., 2-9 m/m.y.). Similarly, the

Effects of chemical surface modification on the ice nucleation ability of feldspar and illite

NASA Astrophysics Data System (ADS)

Augustin, Stefanie; Wex, Heike; Kanter, Sandra; Ebert, Martin; Niedermeier, Dennis; Stratmann, Frank

2014-05-01

Mineral dust is the most abundant ice nuclei (IN) in the atmosphere and thus it is thought to be important for ice nucleation in clouds (Murray et al. [2012]). The clay minerals contribute approximately two thirds of the mineral dust mass (Atkinson et al. [2013]), and illite is the most abundant clay mineral found in the atmosphere [Broadley et al., 2012]. In the past years a lot of the ice nucleation research focused on proxies for clay minerals like Arizona Test Dust (ATD), kaolinite and illite (see reviews by Murray et al. [2012] and Hoose and Möhler. [2012]). In most experiments, these substances acted as IN only at relatively low temperatures (lower than -25°C). Very recently Atkinson et al. (2013) showed that K-feldspar, which is a common crustal material, is the most active mineral dust with freezing temperatures above -20°C. In the present study we compared the immersion freezing behavior of size segregated illite and feldspar particles. We used illite-NX (Arginotec) and a feldspar sample from Minas Gerais, Brazil (consisting to roughly 80% of a K-feldspar with the remainder being a Na-feldspar). Both substances were examined in the framework of the INUIT research project. For the illite-NX particles freezing onset was observed at temperatures around -34°C. The feldspar sample already induced freezing at -23°C. The data obtained was in agreement to those reported in Broadley el al. [2012] and Atkinson et al. [2013]. To simulate chemical aging of the particle surface we coated the particles with sulfuric acid and repeated the measurements. The illite-NX showed a rather small change in the ice nucleation ability, whereas the freezing ability of the feldspar was strongly reduced and became similar to that of illite-NX. It seems that the sulfuric acid destroyed those sites on the particle surface which are responsible for the initiation of freezing. We continue our work in trying to better understand what exactly it is that gives K-feldspar its good IN

Calorimetric investigation of the excess entropy of mixing in analbite-sanidine solid solutions: lack of evidence for Na,K short- range order and implications for two-feldspar thermometry.

USGS Publications Warehouse

Haselton, H.T.; Hovis, G.L.; Hemingway, B.S.; Robie, R.A.

1983-01-01

Heat capacities (5-380 K) have been measured by adiabatic calorimetry for five highly disordered alkali feldspars (Ab99Or1, Ab85Or15, Ab55Or45, Ab25Or75 and Ab1Or99). The thermodynamic and mineralogical implications of the results are discussed. The new data are also combined with recent data for plagioclases in order to derive a revised expression for the two-feldspar thermometer. T calculated from the revised expression tend to be higher than previous calculations.-J.A.Z.

Deformation behaviour of feldspar in greenschist facies granitoide shear zones from the Austroalpine basement to the south of the western Tauern window, Eastern Alps

NASA Astrophysics Data System (ADS)

Hentschel, Felix; Trepmann, Claudia

2015-04-01

Objective of this study is to elucidate the feldspar deformation behaviour at greenschist facies conditions relevant for the long-term rheological properties of continental crust. Uncertainties in models for the rheological properties are partly due to a poor knowledge of the deformation mechanisms taking place in granitoid rocks at inaccessible depth. The deformation behaviour of feldspar, the most abundant mineral in the continental crust, is characterized by an interaction of brittle, dissolution-precipitation and crystal-plastic processes, which is difficult to evaluate in experiments given the problematic extrapolation of experimental conditions to reasonable natural conditions. However, microfabrics of metamorphic granitoid rocks record the grain-scale deformation mechanisms and involved chemical reactions proceeding during their geological history. This usually includes deformation and modification through several stages in space (depth, i.e., P, T conditions) and/or time. For deciphering the rock's record this implies both, challenge and chance to resolve these different stages. Here, we use the deformation record of mylonitic pegmatites from the Austroalpine basement south to the western Tauern window. The structural, crystallographic and chemical characteristics of the feldspar microfabrics are determined via micro-analytical techniques (polarized light microscopy, scanning electron microscopy, SEM, electron back scatter diffraction, EBSD) to identify the relevant deformation mechanisms and deformation conditions. The pegmatites represent a relatively simple Ca-poor granitoid system, mineralogically dominated by albite-rich plagioclase, K-feldspar and quartz. The matrix of the mylonitic pegmatites is composed of alternating monomineralic albite and quartz ribbons defining the foliation. Fragmented tourmaline and K-feldspar porphyroclasts occur isolated within the matrix. At sites of dilation along the stretching lineation K-feldspar porphyroclasts show

A reporting protocol for thermochronologic modeling illustrated with data from the Grand Canyon

NASA Astrophysics Data System (ADS)

Flowers, Rebecca M.; Farley, Kenneth A.; Ketcham, Richard A.

2015-12-01

Apatite (U-Th)/He and fission-track dates, as well as 4He/3He and fission-track length data, provide rich thermal history information. However, numerous choices and assumptions are required on the long road from raw data and observations to potentially complex geologic interpretations. This paper outlines a conceptual framework for this path, with the aim of promoting a broader understanding of how thermochronologic conclusions are derived. The tiered structure consists of thermal history model inputs at Level 1, thermal history model outputs at Level 2, and geologic interpretations at Level 3. Because inverse thermal history modeling is at the heart of converting thermochronologic data to interpretation, for others to evaluate and reproduce conclusions derived from thermochronologic results it is necessary to publish all data required for modeling, report all model inputs, and clearly and completely depict model outputs. Here we suggest a generalized template for a model input table with which to arrange, report and explain the choice of inputs to thermal history models. Model inputs include the thermochronologic data, additional geologic information, and system- and model-specific parameters. As an example we show how the origin of discrepant thermochronologic interpretations in the Grand Canyon can be better understood by using this disciplined approach.

Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions - Part 1: The K-feldspar microcline

NASA Astrophysics Data System (ADS)

Kumar, Anand; Marcolli, Claudia; Luo, Beiping; Peter, Thomas

2018-05-01

Potassium-containing feldspars (K-feldspars) have been considered as key mineral dusts for ice nucleation (IN) in mixed-phase clouds. To investigate the effect of solutes on their IN efficiency, we performed immersion freezing experiments with the K-feldspar microcline, which is highly IN active. Freezing of emulsified droplets with microcline suspended in aqueous solutions of NH3, (NH4)2SO4, NH4HSO4, NH4NO3, NH4Cl, Na2SO4, H2SO4, K2SO4 and KCl, with solute concentrations corresponding to water activities aw = 0.9-1.0, were investigated by means of a differential scanning calorimeter (DSC). The measured heterogeneous IN onset temperatures, Thet(aw), deviate strongly from ThetΔawhet(aw), the values calculated from the water-activity-based approach (where ThetΔawhet(aw) = Tmelt(aw + Δawhet) with a constant offset Δawhet with respect to the ice melting point curve). Surprisingly, for very dilute solutions of NH3 and NH4+ salts (molalities ≲1 mol kg-1 corresponding to aw ≳ 0.96), we find IN temperatures raised by up to 4.5 K above the onset freezing temperature of microcline in pure water (Thet(aw = 1)) and 5.5 K above ThetΔawhet(aw), revealing NH3 and NH4+ to significantly enhance the IN of the microcline surface. Conversely, more concentrated NH3 and NH4+ solutions show a depression of the onset temperature below ThetΔawhet(aw) by as much as 13.5 K caused by a decline in IN ability accompanied with a reduction in the volume fraction of water frozen heterogeneously. All salt solutions not containing NH4+ as cation exhibit nucleation temperatures Thet(aw) < ThetΔawhet(aw) even at very small solute concentrations. In all these cases, the heterogeneous freezing peak displays a decrease as solute concentration increases. This deviation from Δawhet = const. indicates specific chemical interactions between particular solutes and the microcline surface not captured by the water-activity-based approach. One such interaction is the exchange of K+ available on the

Immobilization of enzyme using natural feldspar for use in the synthesis of oleyl oleate

NASA Astrophysics Data System (ADS)

Ali, Balqish Juliana; Othman, Siti Salhah; Harun, Farah Wahida; Jumal, Juliana; Rahman, Mohd Basyaruddin Abdul

2018-06-01

Natural feldspar from Tanah Putih, Gua Musang, Kelantan (Malaysia) was physico-chemically characterized using X-ray Diffraction (XRD), Surface Area and Porosity Analysis (ASAP) and Energy Dispersive X-ray (EDX) techniques. The feldspar was found to be of the potassium (K) type, with major components containing aluminum (Al), and silicon (Si). The feldspar also possesses 38.307 nm mean pore diameter and 18.717 m2/g surface area. Candida rugosa (CRL) was then immobilized onto natural feldspar by physical adsorption method. About 49.96% of protein content was immobilized onto the support. The catalytic activity of the immobilized lipase was determined by the esterification reaction using oleic acid and oleyl alcohol. The effects of various reaction temperatures, stability in organic solvent, and lipase recyclability on the esterification reaction for the native and immobilized lipase were investigated. Feldspar-immobilized lipase exhibited higher activity than that of the native lipase. Immobilized lipase retained its activity ca. 50% even after incubation at high temperature (70°C) with the optimum reaction temperature of 40°C, long incubation in hexane up to 10 days and after ten repeated cycles used. Feldspar-immobilized lipase also showed considerably efficient reusability where it was not easily leached even after being washed with large amount of hexane (20 mL). These results showed that physical adsorption method is suitable for the immobilization of lipase onto feldspar.

Authigenic potassium feldspar: a tracer for the timing of palaeofluid flow in carbonate rocks, Northern Calcareous Alps, Austria

USGS Publications Warehouse

Spotl, C.; Kunk, Michael J.; Ramseyer, K.; Longstaffe, F.J.

1998-01-01

This paper is included in the Special Publication entitled 'Dating and duration of fluid flow and fluid-rock interaction', edited by J. Parnell. Feldspar is a common authigenic constituent in Permian carbonate rocks which occur as tectonically isolated blocks within the evaporitic Haselgebirge melange in the Northern Calcareous Alps (NCA). Coexisting with pyrite, anhydrite, (saddle) dolomite, magnesite, fluorite and calcite, K-feldspar and minor albite record an event of regionally extensive interaction of hot brines with carbonate rocks. Detailed petrographic, crystallographic and geochemical studies reveal a variability in crystal size and shape, Al-Si ordering, elemental and stable isotopic compositions of the K-feldspar, which is only partially consistent with the traditional view of authigenic feldspar as a well-ordered, compositionally pure mineral. 40Ar-39Ar step- heating measurements of authigenic potassium feldspar from several localities yield two age populations, an older one of 145-154 Ma, and a younger one of c.90-97 Ma. Most age spectra reflect cooling through the argon retention temperature interval, which was rapid in some localities (as indicated by plateau ages) and slower in others. Rb-Sr isotope data are more difficult to interpret, because in many K-feldspar samples they are controlled largely by Sr-bearing inclusions. The Jurassic 40Ar-39Ar dates are interpreted as minimum ages of feldspar growth and hence imply that fluid-rock interaction is likely to be simultaneous with or to slightly predate melange formation. Deformation associated with the closure and subduction of the Meliata-Hallstatt ocean south of the NCA during the Upper Jurassic is regarded as the principal geodynamic driving force for both enhanced fluid circulation and melange formation. Some localities were reheated beyond the argon retention temperature for microcline during mid-Cretaceous nappe stacking of the NCA, thus obliterating the older signal.

Visible/near-infrared spectra of experimentally shocked plagioclase feldspars

USGS Publications Warehouse

Johnson, J. R.; Horz, F.

2003-01-01

High shock pressures cause structural changes in plagioclase feldspars such as mechanical fracturing and disaggregation of the crystal lattice at submicron scales, the formation of diaplectic glass (maskelynite), and genuine melting. Past studies of visible/ near-infrared spectra of shocked feldspars demonstrated few spectral variations with pressure except for a decrease in the depth of the absorption feature near 1250-1300 nm and an overall decrease in reflectance. New visible/near-infrared spectra (400-2500 nm) of experimentally shocked (17-56 GPa) albite- and anorthite-rich rock powders demonstrate similar trends, including the loss of minor hydrated mineral bands near 1410, 1930, 2250, and 2350 nm. However, the most interesting new observations are increases in reflectance at intermediate pressures, followed by subsequent decreases in reflectance at higher pressures. The amount of internal scattering and overall sample reflectance is controlled by the relative proportions of micro-fractures, submicron grains, diaplectic glass, and melts formed during shock metamorphism. We interpret the observed reflectance increases at intermediate pressures to result from progressively larger proportions of submicron feldspar grains and diaplectic glass. The ensuing decreases in reflectance occur after diaplectic glass formation is complete and the proportion of genuine melt inclusions increases. The pressure regimes over which these reflectance variations occur differ between albite and anorthite, consistent with thermal infrared spectra of these samples and previous studies of shocked feldspars. These types of spectral variations associated with different peak shock pressures should be considered during interpretation and modeling of visible/near-infrared remotely sensed spectra of planetary and asteroidal surfaces.

Mineral resource of the month: feldspar

USGS Publications Warehouse

,

2011-01-01

The article focuses on feldspar, a mineral that composes of potassium, sodium, or a fusion of the two, and its various applications. According to estimates by scientists, the mineral is present at 60 percent of the crust of Earth, wherein it is commonly used for making glass and ceramics. Global mining of feldspar was about 20 million metric tons in 2010, wherein Italy, Turkey, and China mine 55 percent of the feldspar worldwide.

Spatial Correlation Bias in Thermochronologically Derived Late Cenozoic Erosion Histories

NASA Astrophysics Data System (ADS)

Schildgen, T. F.; van Der Beek, P.; Sinclair, H. D.; Thiede, R. C.

2017-12-01

The potential link between erosion rates at the Earth's surface and changes in global climate has intrigued geoscientists for decades, as such a coupling has implications for the influence of silicate weathering and organic-carbon burial on climate, as well as the role of Quaternary glaciations on landscape evolution. A global increase in late-Cenozoic erosion rates in response to a cooling, more variable climate has been proposed based on a compilation of deposition rates in sedimentary basins worldwide. However, it has been argued that the stratigraphic record could show an apparent increase in rates toward the present due to a preservation bias linked to stochastic erosional events, depositional hiatuses, and varying measurement intervals. More recently, a global compilation of thermochronology data has been used to infer a nearly two-fold increase in erosion rates from mountainous landscapes over the late Cenozoic. It is contended that this result is free of the biases that affect sedimentary records. Here, we test this assumption and demonstrate that in addition to the bias resulting from the relative timescales over which thermochronological data are averaged, there is a bias associated with spatial variations in exhumation rates among points that are combined to derive exhumation histories. Whether one or multiple thermochronological systems are used to reconstruct an erosion history, there is always an apparent increase in rates toward the present when combining data that have not shared a common exhumation history (e.g., samples collected from different sides of an active tectonic boundary). Such unwarranted combinations commonly arise when inversions of thermochronological data are performed using an a priori scheme that combines data points according to an assumed spatial correlation structure. We find that in nearly all cases where such inversions have been performed, spatial gradients in erosion rates are converted into apparent temporal increases. On

As-bearing potassium feldspar - a product of fumarole exhalations and gas-rock interactions at the Tolbachik volcano, Kamchatka, Russia

NASA Astrophysics Data System (ADS)

Koshlyakova, Natalia; Pekov, Igor; Yapaskurt, Vasily; Shchipalkina, Nadezhda; Sidorov, Evgeny

2017-04-01

Potassium feldspar is abundant in products of active fumaroles at the Second scoria cone of the Northern Breakthrough of the Great Tolbachik Fissure Eruption (1975-1976), Tolbachik volcano, Kamchatka, Russia. The most intriguing fact is that the mineral here strongly differs chemically from potassium feldspar of all other geological formations. It demonstrates wide compositional variations and is typically enriched with As5+ and sometimes contains significant amounts of P, Zn, Cu, Fe and S. Filatovite K[(Al,Zn)_2(As,Si)_2O_8], the arsenate analogue of orthoclase, was discovered here (Vergasova et al., 2004). Samples from the Arsenatnaya fumarole located at the summit of the Second scoria cone (Pekov et al., 2014) contain, as our data show, complete solid-solution series between As-free potassium feldspar and filatovite. Potassium feldspar crystallizes in the Tolbachik fumaroles as a result of two processes: direct deposition from fumarolic gas and interaction of this gas with basalt scoria at temperatures not lower than 500°C. Exhalation feldspar occurs as incrustations sometimes consisting of well-formed prismatic crystals up to 1 mm long. Potassium feldspar produced by gas-rock interaction process replaces basalt and volcanic scoria. Cases of selective replacement of plagioclase in basalt for As-bearing potassium feldspar were observed. Potassium feldspar from the Arsenatnaya fumarole contains (our electron microprobe data, wt.{%}): SiO2 19.4-65.2 (corresponds to 1.05-3.01 atoms per formula unit = apfu; formulae are calculated on the basis of 8 O apfu), Al_2O3 14.3-30.6 (0.80 -1.95 apfu), As_2O5 0.00-34.2 (0.00-0.97 apfu), P_2O5 0.00-2.5 (0.00-0.10 apfu), SO3 0.00-3.2 (0.00-0.11 apfu), Fe_2O3 0.00-3.1 (0.00-0.11 apfu), ZnO 0.00-0.81 (0.00-0.03 apfu), CuO 0.00-2.1 (0.00-0.08 apfu). In feldspar structure all these constituents occupy tetrahedrally coordinated sites in the AlSi-framework (Filatov et al., 2004). Chemical variations of extra-framework cations in

Thermochronological modeling of the age of Vologda crystalline basement of the Russian platform

NASA Astrophysics Data System (ADS)

Gerasimov, V. Yu.; Petrov, D. B.; Lebedev, V. A.

2010-05-01

demonstrates regular progression of ages in a concordance with closure temperature of each mineral. The apparent Bt age is about 1670 Ma and Ms age is 1710 Ma. The estimation of closure temperature (Tc) for each of the minerals using Dodsn's theory [Dodson 1973] and DCT computer program with concordance procedure of cooling rate simulation for the two coexisting minerals demonstrate value 340° C and и 460° C for Bt and Ms respectively. The rate of cooling in this temperature range is about 3° C/Ma and time span between closure temperatures of the two micas is about 40 Ma. The value of the cooling rate is a very typical for regional metamorphism conditions. The linear extrapolation of the simulated time-temperature trend to the thermal peak of the regional metamorphism (estimated by mineral equilibriums at 550° C) demonstrates that cooling of the metamorphic system from the thermal peak to 460° C(closure temperature of Ms) takes about 30-40 Ma. It is a value of systematic thermochronological correction to the muscovite apparent K-Ar age which has to be added to estimate the age of regional metamorphism, after that we finally receive the age 1750+/-40 Ma. U-Th-Pb system of monazite grains was tested by electron microprobe JEOL 8200 in IGEM RAS using CHIME method. The analysis of 8 grains demonstrated averaged value of age 1790+/-55 Ma. It is in a very good agreement with K-Ar isotope dating results. Moreover, the estimation of monazite closure temperature using experimental data of Pb diffusion [Smith & Giletti 1997] shows the value Tc=540-560° C which almost exactly corresponds to the peak temperature of regional metamorphism. It is also an explanation of the very close results of dating in different isotope systems (conservative U-Th-Pb system of monazite and flexible K-Ar system) in the condition of slow cooling and demonstrates the thermochronological modeling effectiveness.

Equations of State and High-Pressure Behavior of Alkali Feldspars

NASA Astrophysics Data System (ADS)

Ross, N.; Zhao, J.; Angel, R. J.

2017-12-01

The response of the feldspar structure to changes in composition, pressure and temperature can be described in terms of the collective tilts of the tetrahedra that comprise the framework (Angel et al. 2012; 2013). Angel et al. (2013) showed that the extreme anisotropy of the changes in the unit-cell parameters of monoclinic alkali feldspars is not due to anisotropic interaction of the extra-framework cation with the anions of the framework, but due to the tilting of the tetrahedra. To date, a comprehensive study of the effect of pressure on the structural and elastic properties of alkali feldspars has been lacking. In this contribution, we present newly measured equation of state and structural data from high-pressure single-crystal X-ray diffraction experiments for a series of alkali feldspars with different symmetries and various states of Al/Si order:disorder. As observed by Benusa et al. (2005) for low albite, P-V data sets for Na-rich compositions are best fit with a fourth-order Birch-Murnaghan equation of state. Bulk moduli range from 52.3(9) GPa for low albite to 58.6(3) GPa for microcline. In comparison with microcline, sanidine has K=57.2(8) GPa indicating that the effect of Al:Si order:disorder has little effect on the bulk modulus. The anisotropy of the compression is pronounced with 65% of the volume compression accounted for by the compression of the (100) plane normal. This is due to the closing-up of the crankshaft chains of tetrahedra that are characteristic of the feldspar structure. Single-crystal X-ray intensity data sets show that the four-membered rings of tetrahedra within the alkali feldspar structure undergo significant shear at high pressures. Changes in the rate of shear of the four-membered rings with pressure are associated with changes in the variation of the unit-cell angles with pressure. The general conclusion is that that framework models which incorporate regular tetrahedra can be used to predict elastic properties and anisotropy

Investigation of Potassium Feldspar Reactivity in Wet Supercritical CO2 by In Situ Infrared Spectroscopy

NASA Astrophysics Data System (ADS)

Thompson, C.; Widener, C.; Schaef, T.; Loring, J.; McGrail, B. P.

2014-12-01

Capture and subsequent storage of CO2 in deep geologic reservoirs is progressively being considered as a viable approach to reduce anthropogenic greenhouse gas emissions. In the long term, injected CO2 may become permanently entrapped as silicate minerals react with CO2 enriched fluids to form stable carbonate minerals. Potassium feldspars are highly abundant in the earth's crust and are present in the caprocks and storage formations of many target reservoirs. While the dissolution kinetics and carbonation reactions of feldspars have been well studied in the aqueous phase, comparatively little work has focused on K-feldspar reactivity in the CO2-rich fluid. In this study, we used in situ infrared spectroscopy to investigate the carbonation reactions of natural microcline samples. Experiments were carried out at 50 °C and 91 bar by circulating dry or wet supercritical CO2 (scCO2) past a thin film of powdered sample. Water concentrations ranged from 0% to 125% relative to saturation, and transmission-mode absorbance spectra were recorded as a function of time for 48 hours. No discernible reaction was detected when the samples were exposed to anhydrous scCO2. However, in fully water-saturated scCO2, a thin film of liquid-like water was observed on the samples' surfaces, and up to 0.6% of the microcline was converted to a carbonate phase. Potassium carbonate is the most likely reaction product, but minor amounts of sodium carbonate and siderite may also have formed from minor sample impurities. The extent of reaction appears to be related to the thickness of the water film and is likely a consequence of the film's ability to solvate and transport ions in the vicinity of the mineral surface. Other features observed in the spectra correspond to microcline dissolution and precipitation of amorphous silica. Implications about the role of water in these reactions and the relative effectiveness of alkali feldspars for mineral trapping of CO2 will be discussed.

Peculiar Feldspar And Quartz Inclusions Within Zircons From Anorthosites, North Eastern Desert, Egypt

NASA Astrophysics Data System (ADS)

Eliwa, H. A.; Dawoud, M. I.; Khalaf, I. M.; Negendank, J. F.; Itaya, T.

2004-12-01

Zircons from three anorthosite outcrops along Wadi Dib area, north Eastern Desert of Egypt contain abundant and conspicuous inclusions of quartz, feldspar, amphibole and apatite. These anorthosites, as (50-100m thick) layers, represent the top of mafic-ultramafic intrusions exhibiting rhythmic layering visible by reputation of melanocratic and leucocratic layers. Field and microscopic studies exhibit that these anorthosites were affected by the action of residual magmatic solutions associated with the late stage crystallization of the younger granites, which modified their mineralogical composition. They are composed totally of plagioclase with subordinate amount of clinoenstatite, augite, amphibole, biotite, K-feldspar, and quartz. Accessories are magnetite, ilmenite, apatite and zircon. The abundance and the mode of occurrence of K-feldspar, quartz, and biotite with apatite and zircon among the megacrysts suggest their formation is ascribed to the interaction with the residual solutions. The microprobe data exhibit difference between feldspar and amphiboles contained herein zircons and those as anorthosite mineral constituents. The genetic relationship between zircons and their inclusions suggests later growth of zircons than inclusions and most probably at the final stage of rock modification. Zircons are magmatic and found in the interstitial feldspar and quartz among plagioclase megacrysts in aggregates or as individual grains. The microscopic and SEM images investigation exhibit that most zircons are subhedral to euhedral equant and prismatic crystals. Most zircons have same range of crystal morphologies and internal growth structures with predominance of prism /{100/} and pyramid /{101/} and occasionally prism /{110/} and pyramid /{111/}. No evidences for poly-faceted grains, inherited cores or later overgrowths were detected. CL images distinguished zircons with visible core-rim structures and others with regular and continuous growth zones contained herein

[Effects of ammonium sulfate on the metabolism and K-feldspar weathering of two potassium-bearing mineral-solubilizing bacteria].

PubMed

Huang, Zhi; Ma, Guangyou; He, Linyan; Sheng, Xiafang

2012-02-04

To determine the best conditions for Bacillus globisporus Q12 and Rhizobium sp. Q32 to produce organic acids and extracellular polysaccharides, respectively, and further elucidate the weathering mechanism of the two potassium-bearing mineral-solubilizing bacteria. Different contents (0-1.2 g/L) of (NH4)2SO4 were added to media to analyze the ability of the strains to produce organic acids and extracellular polysaccharides, and assess the ability of Q12, Q32 and their mixture to dissolve potassium feldspar. Scanning electron microscope (SEM) was also used to observe the distribution of the bacterial cells on the surfaces of the feldspar and the mineral weathering. Results show that Bacillus globisporus Q12 produced more organic acids, when the contents of (NH4)2SO4 were 0.6 g/L; Rhizobium sp. Q32 produced more extracellular polysaccharides, when there was no (NH4)2SO4 in the media; and the mixture of two strains produced more organic acids and extracellular polysaccharides, when the contents of (NH4)2SO4 were 0.3 g/L. Mineral dissolution experiment showed that Bacillus globisporus Q12, Rhizobium sp. Q32 and the mixture (Q12 + Q32) significantly dissolved the feldspar and released the elements from the mineral, of which the mixture of Q12 and Q32 had the best weathering ability than strain Q12 or Q32; SEM also indicated that the mixture of Q12 and Q32 had more ability to weather feldspar than each tested strain. The contents of (NH4)2SO4 in the media could affect the growth and metabolites of the strains Q12 and Q32 and the mineral bioweathering, the mixture of strains Q12 and Q32 had the more potential of feldspar weathering through the combined action of organic acids and extracellular polysaccharides produced by strains Q12 and Q32.

Using Neutron Diffraction to Determine the Low-Temperature Behavior of Pb2+ in Lead Feldspar

NASA Astrophysics Data System (ADS)

Kolbus, L. M.; Anovitz, L. M.; Chakoumackos, B. C.; Wesolowski, D. J.

2014-12-01

Feldspar minerals comprise 60% of the Earth's crust, so it imperative that the properties of feldspar be well understood for seismic modeling. The structure of feldspar consists of a three-dimensional framework of strongly-bonded TO4 tetrahedra formed by the sharing of oxygen atoms between tetrahedra. The main solid solution series found in natural feldspars are alkali NaAlSi3O8 -KAlSi3O8 and plagioclase CaAl2Si2O8-NaAlSi3O8. Recently, efforts have been made to systematically quantify feldspars structural change at non-ambient temperatures by considering only the relative tilts of the tetrahedral framework [1]. This serves as a tool to predict various behaviors of the structure such as the relative anisotropy of unit cell parameters and volume evolution with composition and temperature. Monoclinic feldspars are well predicted by the model [1], but discrepancies still remain between the model predictions and real structures with respect to absolute values of the unit cell parameters. To improve the existing model, a modification must be made to account for the M-cation interaction with its surrounding oxygen atoms. We have, therefore, chosen to study the structure of Pb-feldspar (PbAl2Si2O8), which provides the opportunity to characterize a monoclinic Al2Si2 feldspar containing a large M-site divalent cation using neutron diffraction. Neutron diffraction allows for the characterization of the M-site cation interaction between the oxygen atoms in the polyhedral cage by providing information to accurately determine the atomic displacement parameters.. Lead feldspar was synthesized for this study using the method described in [2], and confirmed to have a monoclinic C2/m space group. In this talk we will present structural determinations and atomic displacement parameters of Pb-feldspar from 10 - 300K generated from Neutron diffraction at the POWGEN beamline at the Spallation Neutron Source at Oak Ridge National lab, and compare our results to those predicted by the

Some observations on the stoichiometry of feldspar hydrolysis in granitic soil

Treesearch

James L. Clayton

1988-01-01

Weathering rates of orthoclase and plagioclase were computed from mass balances of Na, K, and Ca in three forested watersheds in the Idaho batholith. On the basis of stand conditions, two watersheds were assumed to have no net gains or losses of cations in biomass, and increases in biomass were measured in the third watershed. Balanced feldspar hydrolysis reactions...

Can cathodoluminescence of feldspar be used as provenance indicator?

NASA Astrophysics Data System (ADS)

Scholonek, Christiane; Augustsson, Carita

2016-05-01

We have studied feldspar from crystalline rocks for its textural and spectral cathodoluminescence (CL) characteristics with the aim to reveal their provenance potential. We analyzed ca. 60 rock samples of plutonic, volcanic, metamorphic, and pegmatitic origin from different continents and of 16 Ma to 2 Ga age for their feldspar CL textures and ca. 1200 feldspar crystals from these rocks for their CL color spectra. Among the analyzed rocks, igneous feldspar is most commonly zoned, whereby oscillatory zoning can be confirmed to be typical for volcanic plagioclase. The volcanic plagioclase also less commonly contains twin lamellae that are visible in CL light than crystals from other rock types. Alkali feldspar, particularly from igneous and pegmatitic rocks, was noted to be most affected by alteration features, visible as dark spots, lines and irregular areas. The size of all textural features of up to ca. 150 μm, in combination with possible alteration in both the source area and the sedimentary system, makes the CL textures of feldspar possible to use for qualitative provenance research only. We observed alkali feldspar mostly to luminesce in a bluish color and sometimes in red, and plagioclase in green to yellow. The corresponding CL spectra are dominated by three apparent intensity peaks at 440-520 nm (mainly blue), 540-620 nm (mainly green) and 680-740 nm (red to infrared). A dominance of the peak in the green wavelength interval over the blue one for plagioclase makes CL particularly useful for the differentiation of plagioclase from alkali feldspar. An apparent peak position in red to infrared at < 710 nm for plagioclase mainly is present in mafic rocks. Present-day coastal sand from Peru containing feldspar with the red to infrared peak position mainly exceeding 725 nm for northern Peruvian sand and a larger variety for sand from southern Peru illustrates a discriminative effect of different source areas. We conclude that the provenance application

Elasticity of plagioclase feldspars

NASA Astrophysics Data System (ADS)

Brown, J. Michael; Angel, Ross J.; Ross, Nancy L.

2016-02-01

Elastic properties are reported for eight plagioclase feldspars that span compositions from albite (NaSi3AlO8) to anorthite (CaSi2Al2O8). Surface acoustic wave velocities measured using Impulsive Stimulated Light Scattering and compliance sums from high-pressure X-ray compression studies accurately determine all 21 components of the elasticity tensor for these triclinic minerals. The overall pattern of elasticity and the changes in individual elastic components with composition can be rationalized on the basis of the evolution of crystal structures and chemistry across this solid-solution join. All plagioclase feldspars have high elastic anisotropy; a* (the direction perpendicular to the b and c axes) is the softest direction by a factor of 3 in albite. From albite to anorthite the stiffness of this direction undergoes the greatest change, increasing twofold. Small discontinuities in the elastic components, inferred to occur between the three plagioclase phases with distinct symmetry (C1>¯, I1>¯, and P1>¯), appear consistent with the nature of the underlying conformation of the framework-linked tetrahedra and the associated structural changes. Measured body wave velocities of plagioclase-rich rocks, reported over the last five decades, are consistent with calculated Hill-averaged velocities using the current moduli. This confirms long-standing speculation that previously reported elastic moduli for plagioclase feldspars are systematically in error. The current results provide greater assurance that the seismic structure of the middle and lower crusts can be accurately estimated on the basis of specified mineral modes, chemistry, and fabric.

Thermochronology of Cretaceous batholithic rocks in the northern Peninsular Ranges batholith, southern California: Implications for the Late Cretaceous tectonic evolution of southern California

USGS Publications Warehouse

Miggins, Daniel P.; Premo, Wayne R.; Snee, Lawrence W; Yeoman, Ross; Naeaer, Nancy D.; Naeser, Charles W.; Morton, Douglas M.

2014-01-01

The thermochronology for several suites of Mesozoic metamorphic and plutonic rocks collected throughout the northern Peninsular Ranges batholith (PRB) was studied as part of a collaborative isotopic study to further our understanding of the magmatic and tectonic history of southern California. These sample suites include: a traverse through the plutonic rocks across the northern PRB (N = 29), a traverse across a central structural and metamorphic transition zone of mainly metasedimentary rocks at Searl ridge (N = 20), plutonic samples from several drill cores (N = 7) and surface samples (N = 2) from the Los Angeles Basin, a traverse across the Eastern Peninsular Ranges mylonite zone (N = 6), and a suite of plutonic samples collected across the northern PRB (N = 13) from which only biotite 40Ar/39Ar ages were obtained. These geochronologic data help to characterize five major petrologic, geochemical, and isotopic zonations of the PRB (western zone, WZ; western transition zone, WTZ; eastern transition zone, ETZ; eastern zone, EZ; and upper-plate zone, UPZ).Apparent cooling rates were calculated using U-Pb zircon (zr) and titanite (sphene) ages; 40Ar/39Ar ages from hornblende (hbl), biotite (bi), and K-feldspar (Kf); and apatite fission-track (AFT) ages from the same samples. The apparent cooling rates across the northern PRB vary from relatively rapid in the west (zr-hbl ~210 °C/m.y.; zr-bio ~160 °C/m.y.; zr-Kf ~80 °C/m.y.) to less rapid in the central (zr-hb ~280 °C/m.y.; zr-bio ~90 °C/m.y.; zr-Kf ~60 °C/m.y.) and eastern (zr-hbl ~185 °C/m.y.; zr-bio ~180 °C/m.y.; zr-Kf ~60 °C/m.y.) zones. An exception in the eastern zone, the massive San Jacinto pluton, appears to have cooled very rapidly (zr-bio ~385 °C/m.y.). Apparent cooling rates for the UPZ samples are consistently slower in comparison (~25–45 °C/m.y.), regardless of which geochronometers are used.Notable characteristics of the various ages from different dating methods include: (1) Zircon

Morphological evolution of dissolving feldspar particles with anisotropic surface kinetics and implications for dissolution rate normalization and grain size dependence: A kinetic modeling study

NASA Astrophysics Data System (ADS)

Zhang, Li; Lüttge, Andreas

2009-11-01

With previous two-dimensional (2D) simulations based on surface-specific feldspar dissolution succeeding in relating the macroscopic feldspar kinetics to the molecular-scale surface reactions of Si and Al atoms ( Zhang and Lüttge, 2008, 2009), we extended our modeling effort to three-dimensional (3D) feldspar particle dissolution simulations. Bearing on the same theoretical basis, the 3D feldspar particle dissolution simulations have verified the anisotropic surface kinetics observed in the 2D surface-specific simulations. The combined effect of saturation state, pH, and temperature on the surface kinetics anisotropy has been subsequently evaluated, found offering diverse options for morphological evolution of dissolving feldspar nanoparticles with varying grain sizes and starting shapes. Among the three primary faces on the simulated feldspar surface, the (1 0 0) face has the biggest dissolution rate across an extensively wide saturation state range and thus acquires a higher percentage of the surface area upon dissolution. The slowest dissolution occurs to either (0 0 1) or (0 1 0) faces depending on the bond energies of Si-(O)-Si ( ΦSi-O-Si/ kT) and Al-(O)-Si ( ΦAl-O-Si/ kT). When the ratio of ΦSi-O-Si/ kT to ΦAl-O-Si/ kT changes from 6:3 to 7:5, the dissolution rates of three primary faces change from the trend of (1 0 0) > (0 1 0) > (0 0 1) to the trend of (1 0 0) > (0 0 1) > (0 1 0). The rate difference between faces becomes more distinct and accordingly edge rounding becomes more significant. Feldspar nanoparticles also experience an increasing degree of edge rounding from far-from-equilibrium to close-to-equilibrium. Furthermore, we assessed the connection between the continuous morphological modification and the variation in the bulk dissolution rate during the dissolution of a single feldspar particle. Different normalization treatments equivalent to the commonly used mass, cube assumption, sphere assumption, geometric surface area, and reactive

Feldspars as a source of nutrients for microorganisms

USGS Publications Warehouse

Rogers, J.R.; Bennett, P.C.; Choi, W.J.

1998-01-01

Phosphorus and nitrogen are essential macronutrients necessary for the survival of virtually all living organisms. In groundwater systems, these nutrients can be quite scarce and can represent limiting elements for growth of subsurface microorganisms. In this study we examined silicate sources of these elements by characterizing the colonization and weathering of feldspars in situ using field microcosms. We found that in carbon-rich anoxic groundwaters where P and N are scarce, feldspars that contain inclusions of P-minerals such as apatite are preferentially colonized over similar feldspars without P. A microcline from S. Dakota, which contains 0.24% P2O5 but ,1 mmol/ g NH , was heavily colonized 1 4 and deeply weathered. A similar microcline from Ontario, which has no detectable P or NH , was barren of attached organisms and completely unweathered after one year. An- 1 4 orthoclase (0.28% P2O5, ;1 mmol/g NH ) was very heavily colonized and weathered, 1 4 whereas plagioclase specimens (,0.01% P, ,1 mmmol/g NH ) were uncolonized and 1 4 unweathered. In addition, the observed weathering rates are faster than expected based on laboratory rates. We propose that this system is particularly sensitive to the availability of P, and the native subsurface microorganisms have developed biochemical strategies to aggressively scavenge P (or some other essential nutrient such as Fe31 ) from resistant feldspars. The result of this interaction is that only minerals containing P will be signifi- cantly colonized, and these feldspars will be preferentially destroyed, as the subsurface microbial community scavenges a limiting nutrient.

Formation of halloysite from feldspar: Low temperature, artificial weathering versus natural weathering

USGS Publications Warehouse

Parham, Walter E.

1969-01-01

Weathering products formed on surfaces of both potassium and plagioclase feldspar (An70), which were continuously leached in a Soxhlet extraction apparatus for 140 days with 7.21 of distilled water per day at a temperature of approximately 78°C, are morphologically identical to natural products developed on potassium feldspars weathered under conditions of good drainage in the humid tropics. The new products, which first appear as tiny bumps on the feldspar surface, start to develop mainly at exposed edges but also at apparently random sites on flat cleavage surfaces. As weathering continues, the bumps grow outward from the feldspar surface to form tapered projections, which then develop into wide-based thin films or sheets. The thin sheets of many projections merge laterally to form one continuous flame-shaped sheet. The sheets formed on potassium feldspars may then roll to form tubes that are inclined at a high angle to the feldspar surface. Etch pits of triangular outline on the artificially weathered potassium feldspars serve as sites for development of continuous, non-rolled, hollow tubes. It is inferred from its morphology that this weathering product is halloysite or its primitive form. The product of naturally weathered potassium feldspars is halloysite . 4H2O.The flame-shaped films or sheets formed on artificially weathered plagioclase feldspar do not develop into hollow tubes, but instead give rise to a platy mineral that is most probably boehmite. These plates form within the flame-shaped films, and with continued weathering are released as the film deteriorates. There is no indication from this experiment that platy pseudohexagonal kaolinite forms from any of these minerals under the initial stage of weathering.

APPLICATIONS OF CATHODOLUMINESCENCE OF QUARTZ AND FELDSPAR TO SEDIMENTARY PETROLOGY.

USGS Publications Warehouse

Ruppert, Leslie F.

1987-01-01

Cathodoluminescence (CL), the emission of visible light during electron bombardment, was first used in sandstone petrology in the mid-1960's. CL techniques are especially useful for determining the origin and source of quartz and feldspar, two of the most common constituents in clastic rocks. CL properties of both minerals are dependent on their temperature of crystallization, duration of cooling, and/or history of deformation. Detrital quartz and feldspar are typically derived from igneous and metamorphic sources and luminesce in the visible range whereas authigenic quartz and feldspar form at low temperatures and do not luminesce. Quantification of luminescent and non-luminescent quartz and feldspar with the scanning electron microscope, electron microprobe, or a commercial CL device can allow for the determination of origin, diagenesis, and source of clastic rocks when used in conjunction with field and other petrographic analyses.

Feldspar dissolution rates in the Topopah Spring Tuff, Yucca Mountain, Nevada

USGS Publications Warehouse

Bryan, C.R.; Helean, K.B.; Marshall, B.D.; Brady, P.V.

2009-01-01

Two different field-based methods are used here to calculate feldspar dissolution rates in the Topopah Spring Tuff, the host rock for the proposed nuclear waste repository at Yucca Mountain, Nevada. The center of the tuff is a high silica rhyolite, consisting largely of alkali feldspar (???60 wt%) and quartz polymorphs (???35 wt%) that formed by devitrification of rhyolitic glass as the tuff cooled. First, the abundance of secondary aluminosilicates is used to estimate the cumulative amount of feldspar dissolution over the history of the tuff, and an ambient dissolution rate is calculated by using the estimated thermal history. Second, the feldspar dissolution rate is calculated by using measured Sr isotope compositions for the pore water and rock. Pore waters display systematic changes in Sr isotopic composition with depth that are caused by feldspar dissolution. The range in dissolution rates determined from secondary mineral abundances varies from 10-16 to 10-17 mol s-1 kg tuff-1 with the largest uncertainty being the effect of the early thermal history of the tuff. Dissolution rates based on pore water Sr isotopic data were calculated by treating percolation flux parametrically, and vary from 10-15 to 10-16 mol s-1 kg tuff-1 for percolation fluxes of 15 mm a-1 and 1 mm a-1, respectively. Reconciling the rates from the two methods requires that percolation fluxes at the sampled locations be a few mm a-1 or less. The calculated feldspar dissolution rates are low relative to other measured field-based feldspar dissolution rates, possibly due to the age (12.8 Ma) of the unsaturated system at Yucca Mountain; because oxidizing and organic-poor conditions limit biological activity; and/or because elevated silica concentrations in the pore waters (???50 mg L-1) may inhibit feldspar dissolution. ?? 2009 Elsevier Ltd. All rights reserved.

Quartz and K-feldspar luminescence dating of sedimentation in the North Bohai coastal area (NE China) since the late pleistocene

NASA Astrophysics Data System (ADS)

Li, Yan; Shang, Zhiwen; Tsukamoto, Sumiko; Tamura, Toru; Yi, Liang; Wang, Hong; Frechen, Manfred; Li, Jianfen; Jiang, Xingyu

2018-02-01

In this study, luminescence dating of core sediments from the North Bohai Coast (China) was applied to provide a high-resolution chronological constraint, on a better understanding of the Holocene marine-terrestrial interaction. The studied sedimentary sequence contains a terrigenous deposit, a transgressive deposit and a prograding deltaic succession; all are believed to have formed during the late Pleistocene. To establish a reliable luminescence chronology, the luminescence signals of ten samples were investigated in order to quantify the degree of bleaching. This approach involved the use of quartz OSL, K-feldspar infrared stimulated luminescence (IRSL) and post-IR IRSL (pIRIR) ages. The resulting data were then compared with radiocarbon ages. The quartz OSL signals were well-bleached for all the samples, and the feldspar pIRIR150 and pIRIR225 signals yielded reliable ages for the pre-Holocene deposits but overestimated ages for late Holocene deposits (<1000 years). Radiocarbon data appeared to slightly overestimate the age of the young Holocene samples, therefore the chronological framework was established using quartz OSL ages. The early-mid Holocene transgressive deposits are relatively thin, which was attributed to the low-gradient relief and weak riverine fluvial input. Rapid deltaic progradation with high sedimentation rates over the last millennia, was revealed by the quartz OSL age results. This was supported by historical records for this section of the coastline. Episodic deposition around 700 years ago most likely triggered by frequent flooding events, was highlighted by the clustered OSL ages. While the sediment increment was 2.7 × 104 m3 a-1 for the period of ∼6-1 ka, this increased considerably to 9.1 × 106 m3 a-1 during the rapid progradation of the last millennium. The increase appears related to winter monsoon enhancement and human activity during the last 1000 years.

Systematic variations of argon diffusion in feldspars and implications for thermochronometry

DOE PAGES

Cassata, William S.; Renne, Paul R.

2013-03-07

Coupled information about the time-dependent production and temperature-dependent diffusion of radiogenic argon in feldspars can be used to constrain the thermal evolution attending a host of Earth and planetary processes. To better assess the accuracy of thermal models, an understanding of the mechanisms and pathways by which argon diffuses in feldspars is desirable. Here we present step-heating Ar diffusion experiments conducted on feldspars with diverse compositions, structural states, and microstructural characteristics. The experiments reveal systematic variations in diffusive behavior that appear closely related to these variables, with apparent closure temperatures for 0.1–1 mm grains of ~200–400 °C (assuming a 10more » °C/Ma cooling rate). Given such variability, there is no broadly applicable set of diffusion parameters that can be utilized in feldspar thermal modeling; sample-specific data are required. Diffusion experiments conducted on oriented cleavage flakes do not reveal directionally-dependent diffusive anisotropy to within the resolution limits of our approach (approximately a factor of 2). Additional experiments aimed at constraining the physical significance of the diffusion domain are presented and indicate that unaltered feldspar crystals with or without coherent exsolution lamellae diffuse at the grain-scale, whereas feldspars containing hydrothermal alteration and/or incoherent sub-grain intergrowths do not. Arrhenius plots for argon diffusion in plagioclase and alkali feldspars appear to reflect a confluence of intrinsic diffusion kinetics and structural transitions that occur during incremental heating experiments. These structural transitions, along with sub-grain domain size variations, cause deviations from linearity (i.e., upward and downward curvature) on Arrhenius plots. An atomistic model for Arrhenius behavior is proposed that incorporates the variable lattice deformations of different feldspars in response to heating and

Lateral thinking: 2-D interpretation of thermochronology in convergent orogenic settings

NASA Astrophysics Data System (ADS)

Batt, Geoffrey E.; Brandon, Mark T.

2002-05-01

Lateral motion of material relative to the regional thermal and kinematic frameworks is important in the interpretation of thermochronology in convergent orogens. Although cooling ages in denuded settings are commonly linked to exhumation, such data are not related to instantaneous behavior but rather to an integration of the exhumation rates experienced between the thermochronological 'closure' at depth and subsequent exposure at the surface. The short spatial wavelength variation of thermal structure and denudation rate typical of orogenic regions thus renders thermochronometers sensitive to lateral motion during exhumation. The significance of this lateral motion varies in proportion with closure temperature, which controls the depth at which isotopic closure occurs, and hence, the range of time and length scales over which such data integrate sample histories. Different chronometers thus vary in the fundamental aspects of the orogenic character to which they are sensitive. Isotopic systems with high closure temperature are more sensitive to exhumation paths and the variation in denudation and thermal structure across a region, while those of lower closure temperature constrain shorter-term behaviour and more local conditions. Discounting lateral motion through an orogenic region and interpreting cooling ages purely in terms of vertical exhumation can produce ambiguous results because variation in the cooling rate can result from either change in kinematics over time or the translation of samples through spatially varying conditions. Resolving this ambiguity requires explicit consideration of the physical and thermal framework experienced by samples during their exhumation. This can be best achieved through numerical simulations coupling kinematic deformation to thermal evolution. Such an approach allows the thermochronological implications of different kinematic scenarios to be tested, and thus provides an important means of assessing the contribution of

Feldspar diagenesis in the Frio Formation, Brazoria County, Texas Gulf Coast

DOE Office of Scientific and Technical Information (OSTI.GOV)

Land, L.S.; Milliken, K.L.

1981-07-01

Tremendous quantities of detrital feldspar have been dissolved or albitized below about 14000 ft (4267 m) in the Frio Formation (Oligocene), Chocolate Bayou Field, Brazoria County, Texas. Some sandstones no longer contain any unmodified detrital feldspar grains. Material transfer involved in these reactions is immense, affecting at least 15% of the rock volume. Thus, albitization has important implications for several other diagenetic processes that involve feldspars or their components. These processes include formation of secondary porosity, precipitation of quartz and carbonate cements, and the evolution of Na-Ca-Cl formation water.

Increase in Ice Nucleation Efficiency of Feldspars, Kaolinite and Mica in Dilute NH3 and NH4+-containing Solutions

NASA Astrophysics Data System (ADS)

Kumar, A.; Marcolli, C.; Luo, B.; Krieger, U. K.; Peter, T.

2017-12-01

Semivolatile species present in the atmosphere are prone to adhere to mineral dust particle surfaces during long range transport, and could potentially change the particle surface properties and its ice nucleation (IN) efficiency. Immersion freezing experiments were performed with microcline (K-feldspar), known to be highly IN active, suspended in aqueous solutions of ammonia, (NH4)2SO4, NH4HSO4, NH4NO3, NH4Cl, Na2SO4, H2SO4, K2SO4 and KCl to investigate the effect of solutes on the IN efficiency. Freezing of emulsified droplets investigated with a differential scanning calorimeter (DSC) showed that the heterogeneous ice nucleation temperatures deviate from the water activity-based IN theory, describing heterogeneous ice nucleation temperatures as a function of solution water activity by a constant offset with respect to the ice melting point curve (Zobrist et al. 2008). IN temperatures enhanced up to 4.5 K were observed for very dilute NH3 and NH4+-containing solutions while a decrease was observed as the concentration was further increased. For all solutes with cations other than NH4+, the IN efficiency decreased. An increase of the IN efficiency in very dilute NH3 and NH4+-containing solutions followed by a decrease with increasing concentration was also observed for sanidine (K-feldspar) and andesine (Na/Ca-feldspar). This is an important indication towards specific chemical interactions between solutes and the feldspar surface which is not captured by the water activity-based IN theory. A similar trend is present but less pronounced in case of kaolinite and mica, while quartz is barely affected. We hypothesize that the hydrogen bonding of NH3 molecules with surface -OH groups could be the reason for the enhanced freezing temperatures in dilute ammonia and ammonium containing solutions as they could form an ice-like overlayer providing hydrogen bonding groups for ice to nucleate on top of it. This implies to possibilities of enhanced IN efficiency, especially

Contact freezing induced by biological (Snomax) and mineral dust (K-feldspar) particles

NASA Astrophysics Data System (ADS)

Hoffmann, N.; Schäfer, M.; Duft, D.; Kiselev, A. A.; Leisner, T.

2013-12-01

The contact freezing of supercooled cloud droplets is one of the potentially important and the least investigated heterogeneous mechanism of ice formation in tropospheric clouds [1]. On the time scales of cloud lifetime the freezing of supercooled water droplets via contact mechanism may occur at higher temperature compared to the same IN immersed in the droplet. In our experiment we study single water droplets freely levitated in an Electrodynamic Balance [2]. We have shown previously that the rate of freezing at given temperature is governed only by the rate of droplet -particle collision and by the properties of the contact ice nuclei [2, 3]. Recently, we have extended our experiments to feldspar, being the most abundant component of the atmospheric mineral dust particles, and Snomax, as a proxy for atmospheric biological Ice Nuclei (IN). In this contribution we show that both IN exhibits the same temperature, size and material dependency observed previously in immersion mode [4, 5]. Based on these results, we limit the number of mechanisms that could be responsible for the enhancement of contact nucleation of ice in supercooled water. [1] - Ladino, L. A., Stetzer, O., and Lohmann, U.: Contact freezing: a review, Atmos. Chem. Phys. Discuss., 13, 7811-7869, doi:10.5194/acpd-13-7811-2013, 2013. [2] - Hoffmann, N., Kiselev, A., Rzesanke, D., Duft, D., and Leisner, T.: Experimental quantification of contact freezing in an electrodynamic balance, Atmos. Meas. Tech. Discuss., 6, 3407-3437, doi:10.5194/amtd-6-3407-2013, 2013. [3] - Hoffmann, N., Duft, D., Kiselev, A., and Leisner, T.: Contact freezing efficiency of mineral dust aerosols studied in an electrodynamic balance: quantitative size and temperature dependence for illite particles, Faraday Discuss., doi: 10.1039/C3FD00033H, 2013. [4] - Atkinson, James D., Murray, Benjamin J., Woodhouse, Matthew T., Whale, Thomas F., Baustian, Kelly J., Carslaw, Kenneth S., Dobbie, Steven, O'Sullivan, Daniel, and Malkin, Tamsin

Feldspars Detected by ChemCam in Gale Crater with Implications for Future Martian Exploration

NASA Astrophysics Data System (ADS)

Gasda, P. J.; Carlson, E.; Wiens, R. C.; Bridges, J.; Sautter, V.; Cousin, A.; Maurice, S.; Gasnault, O.; Clegg, S. M.

2015-12-01

Feldspar is a common igneous mineral that can shed light on parent magma temperatures, pressures, and compositions. During the first 801 sols of the NASA Mars Science Laboratory mission, we have detected 125 possible feldspar grains using the ChemCam LIBS instrument. We analyzed spectra from successive laser shots at the same location and approximate whole rock compositions for each target. Feldspar-containing targets range from tephrite-basanite to trachyandesite. The most common feldspar type is andesine; no targets are >An60. Over 30% are anorthoclase, and ~10% have potassium contents up to Or60. Individual shot measurements in a single spot suggest some feldspars are zoned. Most of these rocks are either float or incorporated into conglomerates, and thus we do not know their provenance. Many of the samples may originate from the Gale crater walls, indicative of Southern Highland ancient crust. Some may also be flung from further away (e.g., emplaced by impact processes). Hence, these rocks may give us a general clue to the variety of evolved igneous materials on Mars. The ubiquity of feldspars at Gale suggests that they have been significantly underestimated for the Southern Highlands, if not for the whole of Mars. For example, significant abundance of andesitic feldspars in both the southern highland and northern lowlands of Mars would imply that Martian volcanism has produced a greater extent of evolved igneous materials to a greater degree than previously thought. Remote sensing instruments are insensitive to plagioclase due to dust cover, lack of exposures, or low feldspar FeO content. However, the Mars 2020 rover will be equipped with 3 new instruments, the arm-mounted SHERLOC Raman, PIXL μXRF, and the mast-mounted SuperCam combined Raman-LIBS instruments, which should help characterize Martian feldspars. Additionally, the SuperCam instrument plans to include three feldspars in its suite of 20+ onboard standards to improve feldspar chemical analysis.

Deformation of quartz and feldspar at mid-crustal depths in an extensional normal fault (Viveiro Fault, NW Spain)

NASA Astrophysics Data System (ADS)

López-Sánchez, M. A.; Llana-Fúnez, S.; Marcos, A.; Martínez, F. J.

2012-04-01

Metamorphic reactions, deformation mechanism and chemical changes during mylonitization and ultramylonitization of granite affected by a crustal-scale shear zone are investigated using microstructural observations and quantitative analysis. The Vivero Fault (VF) is a large extensional shear zone (>140Km) in NW of Iberia that follows the main Variscan trend dipping 60° toward the West. The movement accumulated during its tectonic history affects the major lithostratigraphic sequence of Palaeozoic and Neoproterozoic rocks and the metamorphic facies developed during Variscan orogenesis. Staurolite, and locally, andalucite plus biotite grew in the hangingwall during the development of VF, overprinted the previous regional Variscan greenschist facies metamorphism. Andalusite growth took place during the intrusion of syntectonic granitic bodies, such as the deformed granite studied here. The Penedo Gordo granite is coarse-grained two-mica biotite-rich granite intruding the VF and its hangingwall. This granite developed a localized deformation consisting of a set of narrow zones (mm to metric scales) heterogeneously distributed subsequently to its intrusion. Based on pseudosections for representative hangingwall pelites hosting the granite and the inferred metamorphic evolution, the shear zone that outcrops at present-day erosion surface was previously active at 14,7-17 km depth (390-450 MPa). Temperature estimates during deformation reach at least the range 500-600° C, implying a local gradient of 35±6°C/km. Microstructures in the mylonites are characterized by bulging (BLG) to subgrain rotation (SGR) recristallization in quartz with the increasing of deformation. Albitisation, flame-perthite and tartan twining are common in K-feldspar at the early stage of deformation. The inferred dominant deformation mechanisms are: i) intracrystalline plasticity in quartz, ii) cataclasis with syntectonic crystallisation of very fine albite-oligoclase and micas in K-feldspar, and

40Ar/39Ar thermochronologic constraints on the tectonothermal evolution of the Northern East Humboldt range metamorphic core complex, Nevada

USGS Publications Warehouse

McGrew, A.J.; Snee, L.W.

1994-01-01

The northern East Humboldt Range (NEHR) of northeastern Nevada exposes a suite of complexly deformed migmatitic, upper amphibolite-facies rocks in the footwall of the Ruby Mountains-East Humboldt Range (RM-EHR) detachment fault. New 40Ar/39Ar data on hornblende, muscovite, biotite, and potassium feldspar help constrain the kinematic and thermal evolution of this terrain during Tertiary extensional exhumation. Hornblende samples from relatively high structural levels yield discordant age spectra that suggest initial cooling during early Tertiary time (63-49 Ma). When coupled with petrological constraints indicating a strongly decompressional P-T-t path above 550??C, the hornblende data suggest that exhumation of the RM-EHR may have initiated in early Tertiary time, approximately coincident with the initial phases of unroofing in the Wood Hills immediately to the east and with the end of thrusting in the late Mesozoic to early Tertiary Sevier orogenic belt of eastern Nevada and western Utah. This temporal coincidence suggests that gravitational collapse of tectonically thickened crust in the internal zone of the Sevier belt could have driven the initial phases of unroofing. Thermal history during the final stage of exhumation of the NEHR is constrained by discordant hornblende cooling ages of 36-29 Ma from deep structural levels and biotite, muscovite, and potassium feldspar cooling ages of 27-21 Ma from a range of structural levels. Comparison of muscovite, biotite, and potassium feldspar cooling ages with previously published fission-track cooling ages implies very rapid cooling rates at temperatures below the closure temperature for muscovite (270??-350??C), but time gaps of > 7 m.y. between hornblende and mica cooling ages suggest that cooling at higher temperatures was more gradual. In addition, comparison of 40Ar 39Ar mica cooling ages with previously published fission-track apatite cooling ages suggests pronounced thermal gradients between the NEHR and

Rare earth element geochemistry of feldspars: examples from Fe-oxide Cu-Au systems in the Olympic Cu-Au Province, South Australia

NASA Astrophysics Data System (ADS)

Kontonikas-Charos, Alkis; Ciobanu, Cristiana L.; Cook, Nigel J.; Ehrig, Kathy; Krneta, Sasha; Kamenetsky, Vadim S.

2018-04-01

Rare earth element (REE) fractionation trends in feldspars are reported from Olympic Dam (including Wirrda Well and Phillip's Ridge) and Cape Donington (Port Lincoln), for comparison with two other igneous-hydrothermal terranes within the eastern Gawler Craton: Moonta-Wallaroo and Hillside. The case studies were selected as they represent 1590 Ma Hiltaba Suite and/or 1845 - 1810 Ma Donington Suite granites, and, aside from Cape Donington, are associated with Mesoproterozoic iron-oxide copper gold (IOCG)-type mineralization. Both plagioclase and alkali feldspar were analyzed within selected samples with the purpose of constraining and linking changes in REE concentrations and fractionation trends in feldspars to local and whole-rock textures and geochemistry. Two unique, reproducible fractionation trends were obtained for igneous plagioclase and alkali feldspars, distinguished from one another by light rare earth element enrichment, Eu-anomalies and degrees of fractionation (e.g. La/Lu slopes). Results for hydrothermal albite and K-feldspar indicate that REE concentrations and fractionation trends are generally inherited from igneous predecessors, however in some instances, significant amounts of REE appear to have been lost to the fluid. These results may have critical implications for the formation of world-class IOCG systems, in which widespread alkali metasomatism plays a key role by altering the physical and chemical properties of the host rocks during early stages of IOCG formation, as well as trapping trace elements (including REE).

Reflecting on Progress in K-12 Dance Education

ERIC Educational Resources Information Center

Callahan-Russell, Colleen

2004-01-01

Dance as an art form is transformational to body, mind, and spirit. The author opines that public education would do just fine if dance was the "only" subject taught. This article presents the author's reflection on progress of dance in K-12 education. The author contends that progress in dance in K-12 education can perhaps be judged by the fact…

Particle size and X-ray analysis of Feldspar, Calvert, Ball, and Jordan soils

NASA Technical Reports Server (NTRS)

Chapman, R. S.

1977-01-01

Pipette analysis and X-ray diffraction techniques were employed to characterize the particle size distribution and clay mineral content of the feldspar, calvert, ball, and jordan soils. In general, the ball, calvert, and jordan soils were primarily clay size particles composed of kaolinite and illite whereas the feldspar soil was primarily silt-size particles composed of quartz and feldspar minerals.

New insights into the oleate flotation response of feldspar particles of different sizes: Anisotropic adsorption model.

PubMed

Xu, Longhua; Tian, Jia; Wu, Houqin; Deng, Wei; Yang, Yaohui; Sun, Wei; Gao, Zhiyong; Hu, Yuehua

2017-11-01

The anisotropic adsorption of sodium oleate (NaOL) on feldspar surfaces was investigated to elucidate the different flotation properties of feldspar particles of four different size ranges. Microflotation experiments showed that the feldspar flotation recovery of particles with sizes spanning different ranges decreased in the order 0-19>19-38>45-75>38-45μm. Zeta potential and FTIR measurements showed that NaOL was chemically adsorbed on the Al sites of the feldspar surface. The anisotropic surface energies and broken bond densities estimated by density functional theory calculations showed that, although feldspar mostly exposed (010) and (001) surfaces, only the (001) surfaces contained the Al sites needed for NaOL adsorption. The interaction energies calculated by molecular dynamics simulations confirmed the more favorable NaOL adsorption on (001) than (010) surfaces, which may represent the main cause for the anisotropic NaOL adsorption on feldspar particles of different sizes. SEM measurements showed that the main exposed surfaces on coarse and fine feldspar particles were the side (010) and basal (001) ones, respectively. A higher fraction of Al-rich (001) surfaces is exposed on fine feldspar particles, resulting in better floatability compared with coarse particles. XPS and adsorption measurements confirmed that the Al content on the feldspar surface varied with the particle size, explaining the different NaOL flotation of feldspar particles of different sizes. Therefore, the present results suggest that coarsely ground ore should be used for the separation of feldspar gangue minerals. Further improvements in the flotation separation of feldspar from associated valuable minerals can be achieved through selective comminution or grinding processes favoring the exposure of (010) surfaces. Copyright © 2017 Elsevier Inc. All rights reserved.

Effect of electrolyte on surface free energy components of feldspar minerals using thin-layer wicking method.

PubMed

Karagüzel, C; Can, M F; Sönmez, E; Celik, M S

2005-05-01

Application of the thin-layer wicking (TLW) technique on powdered minerals is useful for characterizing their surfaces. Albite (Na-feldspar) and orthoclase (K-feldspar) are feldspar minerals which are frequently found in the same matrix. Despite similarities in their physicochemical properties, separation of these minerals from each other by flotation is generally possible in the presence of monovalent salts such as NaCl. Both albite and orthoclase exhibit the same microflotation properties and rather close electrokinetic profiles in the absence of salt. In this study, contact angles of albite and orthoclase determined by the TLW technique yielded close values in the absence and presence of amine collector. While the calculated surface energies and their components determined using contact angle data reveal that the energy terms remain farther apart in the absence of the collector, the differences narrow down at collector concentrations where full flotation recoveries are obtained. However, the effect of addition of NaCl on contact angles and surface free energy components at constant amine concentration indicates that albite is significantly affected by salt addition, whereas orthoclase remains marginally affected. This interesting finding is explained on the basis of ion-exchange properties, the stability of the interface, flotation data, and zeta potential data in the presence of NaCl.

Iron removal on feldspar by using Averrhoa bilimbii as bioleaching agent

NASA Astrophysics Data System (ADS)

Amin, Muhammad; Aji, Bramantyo B.; Supriyatna, Yayat Iman; Bahfie, Fathan

2017-01-01

Investigation of Averrhoa bilimbii as bioleaching agent was carried out. Parameters of leaching duration, acid concentration, and temperature were performed in iron removal process. Feldspar with sized 149 µm was diluted in 30 ml acid solution in order to reduce its iron content. The experimental results showed a good technical feasibility of the process which iron oxide content of feldspar was decreased from 2.24% to 0.29%. The lowest iron concentration remained was obtained after 5 hours of leaching treatment at 60 °C, and concentrated (100 vol%) Averrhoa bilimbii extract as bioleaching agent. SEM characterizations were carried out on the feldspar before and after the leaching treatment. The result shows that there were no significant effect of leaching process on the ore morphology.

Feldspar basalts in lunar soil and the nature of the lunar continents

NASA Technical Reports Server (NTRS)

Reid, A. M.; Ridley, W. I.; Harmon, R. S.; Warner, J.; Brett, R.; Jakes, P.; Brown, R. W.

1974-01-01

It is found that 25% on the Apollo-14 glasses have the same composition as the glasses in two samples taken from the Luna-16 column. The compositions are equivalent to feldspar basalt and anorthosite gabbro, and are similar to the feldspar basalts identified from Surveyor-7 analysis for lunar continents.

Asbestos contamination in feldspar extraction sites: a failure of prevention? Commentary.

PubMed

Cavariani, Fulvio

2016-01-01

Fibrous tremolite is a mineral species belonging to the amphibole group. It is present almost everywhere in the world as a natural contaminant of other minerals, like talc and vermiculite. It can be also found as a natural contaminant of the chrysotile form of asbestos. Tremolite asbestos exposures result in respiratory health consequences similar to the other forms of asbestos exposure, including lung cancer and mesothelioma. Although abundantly distributed on the earth's surface, tremolite is only rarely present in significant deposits and it has had little commercial use. Significant presence of amphibole asbestos fibers, characterized as tremolite, was identified in mineral powders coming from the milling of feldspar rocks extracted from a Sardinian mining site (Italy). This evidence raises several problems, in particular the prevention of carcinogenic risks for the workers. Feldspar is widespread all over the world and every year it is produced in large quantities and it is used for several productive processes in many manufacturing industries (over 21 million tons of feldspar mined and marketed every year). Until now the presence of tremolite asbestos in feldspar has not been described, nor has the possibility of such a health hazard for workers involved in mining, milling and handling of rocks from feldspar ores been appreciated. Therefore the need for a wider dissemination of knowledge of these problems among professionals, in particular mineralogists and industrial hygienists, must be emphasized. In fact both disciplines are necessary to plan appropriate environmental controls and adequate protections in order to achieve safe working conditions.

Cation Diffusion in Plagioclase Feldspar

NASA Astrophysics Data System (ADS)

Morse, S. A.

1984-08-01

Steep compositional gradients in igneous plagioclase feldspar from slowly cooled intrusive bodies imply a maximum value of the intracrystalline diffusion coefficient for NaSi leftrightarrows CaAl exchange, Dmax~ 10-20 centimeters squared per second for temperatures in the range 1250 degrees to 1000 degrees C. Millimeter-sized grains cannot be homogenized in all geologic time; hence reactive equilibrium crystallization of plagioclase from the melt does not occur in dry systems.

Structure-dependent interactions between alkali feldspars and organic compounds: implications for reactions in geologic carbon sequestration.

PubMed

Yang, Yi; Min, Yujia; Jun, Young-Shin

2013-01-02

Organic compounds in deep saline aquifers may change supercritical CO(2) (scCO(2))-induced geochemical processes by attacking specific components in a mineral's crystal structure. Here we investigate effects of acetate and oxalate on alkali feldspar-brine interactions in a simulated geologic carbon sequestration (GCS) environment at 100 atm of CO(2) and 90 °C. We show that both organics enhance the net extent of feldspar's dissolution, with oxalate showing a more prominent effect than acetate. Further, we demonstrate that the increased reactivity of Al-O-Si linkages due to the presence of oxalate results in the promotion of both Al and Si release from feldspars. As a consequence, the degree of Al-Si order may affect the effect of oxalate on feldspar dissolution: a promotion of ~500% in terms of cumulative Si concentration was observed after 75 h of dissolution for sanidine (a highly disordered feldspar) owing to oxalate, while the corresponding increase for albite (a highly ordered feldspar) was ~90%. These results provide new insights into the dependence of feldspar dissolution kinetics on the crystallographic properties of the mineral under GCS conditions.

Cenozoic topographic build-up of the Iranien plateau: first constraints from low-temperature thermochronology

NASA Astrophysics Data System (ADS)

François, Thomas; Agard, Philippe; Meyer, Bertrand; Zarrinkoub, Mohammad; Chung, Sun-Lin; Bernet, Matthias; Burov, Evgueni

2013-04-01

Eocene (~42°C/Ma). These results are consistent with the reported formation of several small metamorphic core-complexes in Central Iran towards the end of oceanic subduction, possibly associated with slab rollback. Our thermochronological data allow to locate major topographic and erosional changes during the Cenozoic. Topographic build-up occurred in the SSZ during oceanic subduction and onset of collision (35 Ma) and shifted to the UDMA during continental collision (20 Ma), while progressing towards the external parts of the belt during the Mio-Pliocene (5-10 Ma). Most importantly, we conclude that the uplift of the Iranian plateau was a constant, steady process over the last 20 Ma, at least as a first approximation, as inferred from the combination of constant exhumation in the UDMA and sedimentary records of the central Iranian basin.

Diffusion in the Muscovite 40K Decay System (Invited)

NASA Astrophysics Data System (ADS)

Harrison, T. M.

2010-12-01

The considerable potential of muscovite for thermochronological applications is beginning to be fully exploited following the belated publication of Ar kinetic data. Muscovite’s high potassium content, low solubility for excess 40Ar*, and ubiquitous presence in regionally metamorphosed terranes make it an important phase for 40Ar/39Ar thermochronometry, particularly in light of recognition that both age spectra and vacuum-step-heating-derived 39Ar Arrhenius plots reflect Ar release via the same volume diffusion mechanism. Thus instead of assuming a nominal closure temperature to estimate a single T-t datum, continuous and accurate thermal histories can be inferred in a similar fashion to that well-documented for K-feldspar using the multi-diffusion domain (MDD) model. The Arrhenius parameters for Ar diffusion in muscovite (E=64 kcal/mol, Do=4 cm2/s) correspond to an effective intragrain closure temperature range of ~500 to 300oC for ca. 100 μm grains cooling at ~10oC/Ma at 5 kbar. However, even greater exploitation of the 40K decay system remains possible as only one of every ten 40K atoms decay to 40Ar. The other 90% decay to 40Ca giving the 40K-40Ca branch, in principle, greater sensitivity for dating high K/Ca minerals such as muscovite. The advent of the ‘double-plus’ SIMS 40K++-40Ca++ dating method, which permits analysis of Ca isotopes at an MRP of ~4k rather than the ~25k required for full separation of 40K+ from 40Ca+, opens up the prospect of directly revealing 40K-40Ca closure profiles in muscovite (as opposed to their indirect inference from inversion of 40Ar/39Ar data through the MDD model) at a gain of enhanced precision and accuracy in thermal history reconstruction. We have used SIMS to observe K-Ca age variations in natural muscovites pressed into In. Translating this data into thermal history information, however, requires knowledge of the Arrhenius parameters for Ca tracer diffusion in muscovite. We are undertaking hydrothermal piston

Sr and Pb isotopic geochemistry of feldspars and implications for the growth of megacrysts in plutonic settings.

NASA Astrophysics Data System (ADS)

Munnikhuis, J.; Glazner, A. F.; Coleman, D. S.; Mills, R. D.

2015-12-01

Why megacrystic textures develop in silicic igneous rocks is still unknown. One hypothesis is that these crystals nucleate early in a magma chamber with a high liquid content. A supportive observation of this hypothesis is areas in plutons with high concentrations of megacrysts suggesting flow sorting. Another group of hypotheses suggest megacrystic textures form during protracted late-stage coarsening in a low-melt, interlocked matrix due to either thermal oscillations from incremental pluton emplacement, or Ostwald ripening. Isotopic analyses of large, euhedral K-feldspar megacrysts from the Cretaceous intrusive suites of the Sierra Nevada batholith (SNB) provide new insight into their origin. Megacrysts from the SNB reach the decimeter scale, are Or rich (85-90%), are perthitic, and host mineral inclusions of nearly all phases in the host rock. In-situ micro-drilling of transects, from core to rim, of the alkali feldspars provides material for Sr and Pb isotopic analyses by thermal ionization mass spectrometry (TIMS). Preliminary 87Sr/86Sr(i) isotopic data from samples from the Cathedral Peak Granodiorite, of the Tuolumne Intrusive Suite range from 0.706337 to 0.706452 (~1.6ɛSr) near the cores, whereas a sawtooth pattern with larger variability, 0.706179 to 0.706533 (~5ɛSr), occurs nears the rims. We interpret these preliminary data to indicate that the late portion of growth (i.e. crystal rim) was dominated by either cannibalism of small K-feldspar crystals with isotopic variability, or by addition of isotopically diverse late components to the magma. By comparing the Sr and Pb isotopic stratigraphy of megacrysts from a variety of rock matrices and different granitoids in the SNB isotopic trends can be evaluated to determine if crystals sizes are dependent on disequilibrium processes or grow at a steady state.

Textural evolution of plagioclase feldspar across a shear zone: Implications for deformation mechanism and rock strength

NASA Astrophysics Data System (ADS)

Putnis, Andrew; Austrheim, Håkon; Mukai, Hiroki; Putnis, Christine V.

2014-05-01

Caledonian amphibolite facies shear zones developed in granulite facies anorthosites and anorthositic gabbros of the Bergen Arcs, western Norway allow a detailed study of the relationships between fluid-infiltration, mineral reactions, the evolution of microstructure and deformation mechanisms. A sequence of rocks from the relatively pristine granulites into a shear zone has been studied by optical microscopy, EMPA, SEM, EBSD and TEM, focusing on the progressive development of microstructure in the plagioclase feldspars, leading up to their deformation in the shear zone. At the outcrop scale, fluid infiltration into the granulites is marked by a distinct colour change in the plagioclase from lilac/brown to white. This is associated with the breakdown of the intermediate composition plagioclase (~An50) in the granulite to a complex intergrowth of Na-rich and Ca-rich domains. EBSD analysis shows that this intergrowth retains the crystallographic orientation of the parent feldspar, but that the Ca-rich domains contain many low-angle boundaries as well as twin-related domains. Within the shear zone, this complex intergrowth coarsens by grain boundary migration, annihilating grain boundaries but retaining the Na-rich and Ca-rich zoning pattern. Analysis of nearest-neighbour misorientations of feldspar grains in the shear zone demonstrates that local crystallographic preferred orientation (CPO) is inherited from the parent granulite grain orientations. Random pair misorientation angle distributions show that there is no CPO in the shear zone as a whole, nor is there significant shape preferred orientation (SPO) in individual grains. These observations are interpreted in terms of fluid-induced weakening and deformation by dissolution-precipitation (pressure solution) creep.

Southwest USA Exhumation History Recorded Below the Great Unconformity

NASA Astrophysics Data System (ADS)

Heizler, M. T.; Karlstrom, K. E.

2002-05-01

The Southwestern USA Precambrian terranes preserve a long and variable exhumation history that can be tracked using thermochronological methods. This exhumation history is controlled on two interrelated scales. At first order, it is recognized that 1.7 to 1.4 Ga mid-crustal (10 km, 2-4 kbar) rocks were ultimately exhumed and reside below unconformities of variable age. In Arizona, Mesoproterozoic Apache Group and Neoproterozoic Supergroup sedimentary rocks lie directly on basement and thus indicate exhumation of some regions relatively soon following the 1.4 Ga events. In the Rocky Mountains of Colorado and the Rio Grande rift uplifts of New Mexico, basement is generally overlain by Cambrian to Mississippian strata. The unconformities are useful markers of net exhumation; however do not reveal a time-integrated path. Using published, and hundreds of new 40Ar/39Ar analyses of hornblende, muscovite, biotite and K-feldspar, and a growing U/Pb accessory mineral thermochronology database, we are extracting exhumation information with great detail. The thermochronological data continue to support the claim that relatively low net exhumation occurred following 1.7 to 1.6 Ga accretion of volcanic arc terranes to the southern margin of Laurentia. Mid-crustal (2-4 kbar) rocks stabilized soon after accretion, whereas in some regions like the Upper Granite Gorge, Grand Canyon deeper (6 kbar) metamorphic terranes decompressed to 3 kbar before stabilization. The cooling history of these mid-crustal rocks post 1.65 Ga remains somewhat unknown. Overall slow-cooling models (550 \\deg C to 300 \\deg C from 1.7 to 1.4 Ga) require high geothermal gradients in order to maintain 10 km deep rocks at high temperatures for 100's of Ma. Alternatively, isobaric cooling models to more normal geothermal gradients (i.e. 25 \\deg C/km) at ca. 1.65 Ga require later (1.4 Ga) thermal pulses and/or Mesoproterozoic vertical displacements to explain highly discordant thermochronological data. Either

Testing fault growth models with low-temperature thermochronology in the northwest Basin and Range, USA

USGS Publications Warehouse

Curry, Magdalena A. E.; Barnes, Jason B.; Colgan, Joseph P.

2016-01-01

Common fault growth models diverge in predicting how faults accumulate displacement and lengthen through time. A paucity of field-based data documenting the lateral component of fault growth hinders our ability to test these models and fully understand how natural fault systems evolve. Here we outline a framework for using apatite (U-Th)/He thermochronology (AHe) to quantify the along-strike growth of faults. To test our framework, we first use a transect in the normal fault-bounded Jackson Mountains in the Nevada Basin and Range Province, then apply the new framework to the adjacent Pine Forest Range. We combine new and existing cross sections with 18 new and 16 existing AHe cooling ages to determine the spatiotemporal variability in footwall exhumation and evaluate models for fault growth. Three age-elevation transects in the Pine Forest Range show that rapid exhumation began along the range-front fault between approximately 15 and 11 Ma at rates of 0.2–0.4 km/Myr, ultimately exhuming approximately 1.5–5 km. The ages of rapid exhumation identified at each transect lie within data uncertainty, indicating concomitant onset of faulting along strike. We show that even in the case of growth by fault-segment linkage, the fault would achieve its modern length within 3–4 Myr of onset. Comparison with the Jackson Mountains highlights the inadequacies of spatially limited sampling. A constant fault-length growth model is the best explanation for our thermochronology results. We advocate that low-temperature thermochronology can be further utilized to better understand and quantify fault growth with broader implications for seismic hazard assessments and the coevolution of faulting and topography.

40Ar/39Ar Data for White Mica, Biotite, and K-Feldspar Samples from Low-Grade Metamorphic Rocks in the Westminster Terrane and Adjacent Rocks, Maryland

USGS Publications Warehouse

Kunk, Michael J.; McAleer, Ryan J.

2008-01-01

This report contains reduced 40Ar/39Ar data of white mica and K-feldspar mineral separates and matrix of a whole rock phyllite, all from low-grade metamorphic rocks of the Westminster terrane and adjacent strata in central Maryland. This report presents these data in a preliminary form, but in more detail than can be accommodated in todays professional journals. Also included in this report is information on the location of the samples and a brief description of the samples. The data contained herein are not interpreted in a geological context, and care should be taken by readers unfamiliar with argon isotopic data in the use of these results; many of the individual apparent ages are not geologically meaningful. This report is primarily a detailed source document for subsequent publications that will integrate these data into a geological context.

Tectono-thermal evolution of north Kuqa Depression and South Tian Shan: constraints from apatite (U-Th)/He thermochronology

NASA Astrophysics Data System (ADS)

Xiao, Y.; Qiu, N.; Chang, J.

2017-12-01

The Kuqa Depression, located between Tarim Basin and South Tian Shan Orogen, is considered the most promising site for study the tectono-thermal evolution of the Central Asia Orogenic Belt (CAOB). (U-Th)/He is a new dating method and apatite He ages can record the cooling histories at low temperature between 40 ° 75°1. At present, the low temperature thermochronological data, especially the (U-Th)/He, from north Kuqa Depression are scarce, resulting in controversial issues regarding the cooling history of the upper crust and the latest uplift of South Tian Shan. We present new apatite (U-Th)/He (AHe) thermochronologic data from kuqa depression, aiming to provide insights into exhumation and thermal history of the north kuqa depression. In this study, we firstly present 43 apatite (U-Th)/He ages of 9 samples in north rim of Kuqa Depression. The (U-Th)/He ages range from 1.4±1.0Ma to 17.9±1.2Ma, which are obviously both younger than both the depositional ages and the corresponding AFT ages. To better understand the deformation evolution and thermal history of north Tarim Basin, we use these thermochronological data as inputs for HeFTy software implemented with radiation damage accumulation and annealing model (RDAAM) for time-temperature reconstruction1,2. The relationship between AHe or AFT ages and the relative stratigraphic ages shows that the AHe ages are young and almost about 10 Ma.Thermal modeling using apatite (U-Th)/He ages and geological background information in the same area allow us to obtain a cooling history. The sample T-03 suffered a cooling between 170 and 130Ma, they were re-heated at around 100° between 100 and 40Ma then rapidly cooled and exhumed to reach the surface temperature at around 5Ma. The thermal modeling results indicated the north Kuqa Depression experienced a Miocene rapid cooling event initialed at 12Ma and continued to 5Ma, resulting from far field effect of India-Asia collision. References1. Ketcham, R.A. Forward and reverse

Preliminary constraints on the kinetics of OSL thermochronology

NASA Astrophysics Data System (ADS)

Guralnik, B.; Herman, F.; Lowick, S.; Preusser, F.; Rhodes, E. J.

2010-12-01

Utilizing the fact that temperature exerts a strong control on the retention of radiogenic products at their production sites (and hence their rate of accumulation), thermochronology is an extension of geochronology used to elucidate the cooling histories (t-T trajectories) of rocks over time (Dodson, 1973). Here we present a potential thermochronometer based on the optically stimulated luminescence (OSL) signal of bedrock quartz, with an estimated “closure” temperature of ~25-40°C (-dT/dt=10°C/Ma). In this method, the radiogenic “products” measured are electrons trapped at the naturally occurring lattice defects (electrically unbalanced sites). These electrons can be subsequently released back into the conduction band by exposure to heat and/or light. The mean lifetime of an electron in a particular trapping site is well described by an Arrhenius relationship of the form τ=s-1exp(-E/kT), where E and s are activation energy and frequency factors, respectively, and k is Boltzmann’s constant. Reported lifetimes of the major trap types at 20°C are well beyond Ma-timescale, but for typical natural radioactivity dose rates, these traps saturate well before ~0.5 Ma. In the current work, we analyzed the OSL signals of bedrock quartz from the KTB-VB drillhole (Southern Germany), where long-term stable temperature conditions provide a natural isothermal holding experiment at a Ma-timescale. Eleven core samples from a depth range of 560 m - 2335 m (22°C - 71°C, respectively), were processed to obtain an unbleached quartz fraction of 180-250 µm. Natural and regenerated luminescence signals were measured by stimulation with infrared and then blue light using a single-aliquot regeneration (SAR) protocol. As a function of sample depth, the measured OSL signal varies from a saturated signal at shallow depths to reset signals below a depth of 1 km (i.e., ambient rock temperature higher than 40°C). Several unstable trapping sites with potentially different closure

The Pinto shear zone; a Laramide synconvergent extensional shear zone in the Mojave Desert region of the southwestern United States

USGS Publications Warehouse

Wells, M.L.; Beyene, M.A.; Spell, T.L.; Kula, J.L.; Miller, D.M.; Zanetti, K.A.

2005-01-01

The Pinto shear zone is one of several Late Cretaceous shear zones within the eastern fringe of the Mesozoic magmatic arc of the southwest Cordilleran orogen that developed synchronous with continued plate convergence and backarc shortening. We demonstrate an extensional origin for the shear zone by describing the shear-zone geometry and kinematics, hanging wall deformation style, progressive changes in deformation temperature, and differences in hanging wall and footwall thermal histories. Deformation is constrained between ???74 and 68 Ma by 40Ar/39Ar thermochronology of the exhumed footwall, including multi-diffusion domain modeling of K-feldspar. We discount the interpretations, applied in other areas of the Mojave Desert region, that widespread Late Cretaceous cooling results from refrigeration due to subduction of a shallowly dipping Laramide slab or to erosional denudation, and suggest alternatively that post-intrusion cooling and exhumation by extensional structures are recorded. Widespread crustal melting and magmatism followed by extension and cooling in the Late Cretaceous are most consistent with production of a low-viscosity lower crust during anatexis and/or delamination of mantle lithosphere at the onset of Laramide shallow subduction. ?? 2005 Elsevier Ltd. All rights reserved.

The effect of SEM imaging on the Ar/Ar system in feldspars

NASA Astrophysics Data System (ADS)

Flude, S.; Sherlock, S.; Lee, M.; Kelley, S. P.

2010-12-01

Complex microtextures form in K-feldspar crystals as they cool and are affected by deuteric alteration. This complex structure is the cause of variable closure temperatures for Ar-Ar, a phenomenon which has been utilized in multi domain diffusion (MDD) modelling to recover thermal histories [1]. However, there has been substantial controversy regarding the precise interaction between feldspar microtextures and Ar-diffusion [2,3]. A number of studies have addressed this issue using coupled SEM imaging and Ar/Ar UV laser ablation microprobe (UV-LAMP) analysis on the same sample, to enable direct comparison of microtextures with Ar/Ar age data [4]. Here we have tested the idea that SEM work may affect Ar/Ar ages, leading to inaccurate results in subsequent Ar/Ar analyses. Three splits of alkali feldspar from the Dartmoor Granite in SW England were selected for Ar/Ar UV-LAMP analysis. Split 1 (“control”) was prepared as a polished thick section for Ar/Ar analysis. Split 2 (“SEM”) was prepared as a polished thick section, was chemically-mechanically polished with colloidal silica and underwent SEM imaging (uncoated) and focussed ion beam (FIB) milling (gold coated); electron beam damage in the SEM was maximised by leaving the sample at high magnification for eight minutes. Split 3 (“Etch”) is a cleavage fragment that was etched with HF vapour and underwent low to moderate magnification SEM imaging. The control split gave a range of laser-spot ages consistent with the expected cooling age of the granite and high yields of radiogenic 40Ar* (>90%). The area of the “SEM” split that experienced significant electron beam damage gave younger than expected ages and 40Ar* yields as low as 57%. These are interpreted as a combination of implantation of atmospheric Ar and local redistribution of K within the sample. The area of “SEM” that underwent FIB milling gave ages and 40Ar* yields comparable to the control split, suggesting that the Au-coat minimises FIB

New Elastic Moduli for Amphiboles and Feldspars: Impact on Interpretations of Seismic Velocities

NASA Astrophysics Data System (ADS)

Brown, J. M.; Angel, R. J.

2016-12-01

Seismic properties (both isotropic and anisotropic) of the crust and upper mantle require re-evaluation in light of improved single crystal properties for feldspars and amphiboles as a function of elemental partitioning. Together these minerals constitute more than half of the crust and are locally important in the lithospheric mantle. Their contribution in understanding seismic structures (both in the crust and mantle) has long been recognized. However, published single crystal elastic moduli, required in predictions of seismic velocities based on mineral properties, have remained inadequate for over 50 years. For example, the contribution of amphiboles to seismic velocities has often been approximated on the basis of the reported moduli for two hornblende crystals of unknown composition. New measurements now accurately characterize the plagioclase feldspars, the potassium feldspars, and the calcium and calcium-sodium amphiboles (including a range of compositions for common hornblende). The new moduli allow successful predictions of rock velocities with and without crystal preferred orientations. In contrast, the older moduli required inappropriate use of the Voigt upper aggregate bound in order to rationalize laboratory measurements. These minerals are also more anisotropic than suggested on the basis of the earlier work where cracks and open cleavage surfaces may have artificially depressed the apparent anisotropy. Both feldspars and amphiboles are nearly as anisotropic as sheet silicates with compressional velocity anisotropy of greater than 50%. The plagioclase feldspars show strong compositional trends with small discontinuities between minor structural transitions. In contrast, potassium substitution for sodium and differences in aluminum ordering have little impact on elastic moduli. In the amphiboles, elastic properties are strongly dependent on total aluminum and iron composition. The bulk modulus is most sensitive to aluminum and the shear modulus is

Complex Diffusion Mechanisms for Li in Feldspar: Re-thinking Li-in-Plag Geospeedometry

NASA Astrophysics Data System (ADS)

Holycross, M.; Watson, E. B.

2017-12-01

In recent years, the lithium isotope system has been applied to model processes in a wide variety of terrestrial environments. In igneous settings, Li diffusion gradients have been frequently used to time heating episodes. Lithium partitioning behavior during decompression or cooling events drives Li transfer between phases, but the extent of Li exchange may be limited by its diffusion rate in geologic materials. Lithium is an exceptionally fast diffuser in silicate media, making it uniquely suited to record short-lived volcanic phenomena. The Li-in-plagioclase geospeedometer is often used to time explosive eruptions by applying laboratory-calibrated Li diffusion coefficients to model concentration profiles in magmatic feldspar samples. To quantify Li transport in natural scenarios, experimental measurements are needed that account for changing temperature and oxygen fugacity as well as different feldspar compositions and crystallographic orientation. Ambient pressure experiments were run at RPI to diffuse Li from a powdered spodumene source into polished sanidine, albite, oligoclase or anorthite crystals over the temperature range 500-950 ºC. The resulting 7Li concentration gradients developed in the mineral specimens were evaluated using laser ablation ICP-MS. The new data show that Li diffusion in all feldspar compositions simultaneously operates by both a "fast" and "slow" diffusion mechanism. Fast path diffusivities are similar to those found by Giletti and Shanahan [1997] for Li diffusion in plagioclase and are typically 10 to 20 times greater than slow path diffusivities. Lithium concentration gradients in the feldspar experiments plot in the shape of two superimposed error function curves with the slow diffusion regime in the near-surface of the crystal. Lithium diffusion is most sluggish in sanidine and is significantly faster in the plagioclase feldspars. It is still unclear what diffusion mechanism operates in nature, but the new measurements may impact

Isothermal thermoluminescence dating of K-feldspar from sediments to determine fault slip rates: development and assessment

NASA Astrophysics Data System (ADS)

Rhodes, E. J.; Roder, B. J.; Lawson, M. J.; Dolan, J. F.; McGill, S. F.; McAuliffe, L.

2012-04-01

Faults in California accommodate most of the relative motion between the Pacific and North American tectonic plates, along either one main strike-slip fault, - the San Andreas fault - or a network of sub-parallel faults (e.g., the San Jacinto, Elsinore and San Andreas faults). Slip is also accommodated along many other associated faults and folds, and the region suffers frequent damaging earthquakes. Contemporary movements of different fault-bounded blocks are relatively well established on decadal timescales using remote sensing and GPS, and on timescales of 106 to 107 years, by dating offset geologic features with radiometric methods. However, on timescales of decades to several hundred thousand years, determining total fault offset and mean slip rate is harder. Critical questions for understanding fault dynamics and improving earthquake risk assessment include the degree to which slip is clustered into episodes of more rapid movement, and how slip is accommodated by different sub-parallel faults. In many cases, streams with offset courses can be recognised, and in some cases offset terrace surfaces can be located, especially when using LiDAR data to complement field mapping. Radiocarbon and terrestrial cosmogenic nuclides have been used to date these features, but both have limitations of age range, sample suitability and availability. OSL (optically stimulated luminescence) and IRSL (infra-red stimulated luminescence) have great potential to complement these techniques, though the characteristics of quartz in some parts of southern California are suboptimal, displaying low sensitivity and other limitations. In order to overcome these limitations encountered using quartz OSL, we are developing a new geochronometer based on the isothermal thermoluminescence (ITL) signal of K feldspar measured at 250°C. Preliminary ITL age estimates from the paleoseismic site of El Paso Peaks on the Central Garlock fault in the Mojave Desert, California, agree well with a well

Thermochronologic constraints on mylonite and detachment fault development, Kettle Highlands, northeastern Washington and southern British Columbia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berger, B.R.; Snee, L.W.

1992-01-01

The Kettle dome, northeastern Washington and southern British Columbia, is one of several large metamorphic core complexes in the region. New Ar-40/Ar-39 cooling dates from the mylonite immediately beneath the Kettle River detachment fault at Barney's Junction, a cross-cutting mafic dike, and the youngest Eocene lavas in the Republic graben set constraints on kinematic models of the tectonic evolution of the dome and related grabens: Amphibolite--hornblende (59.0 [+-] 0.2); Pegmatite--muscovite (49.3 [+-] 0.2); Pegmatite--K-feldspar (49.2 [+-] 1); Augen gneiss--K-feldspar (48.0 [+-] 1); Mafic dike--hornblende (54.5 [+-] 0.1) and biotite (49.6 [+-] 0.1); Klondike Mt. Formation lava--feeder dike (48.8 [+-] 1).more » The authors interpret the dates to indicate that the tectonized amphibolite, part of a Cretaceous and older metamorphosed terrane, had formed and cooled to [approx] 500 C by Late Paleocene, the mylonite zone was being domed above the ductile zone by Early Eocene at the time of emplacement of the dike--temporally equivalent to the Keller Butte suite, Eocene Colville batholith--which crosscuts the mylonite, and incipient rifting was occurring in the Republic graben as evidenced by dike swarms. The mylonite complex reached 300 C by 49Ma coincident with the termination of Sanpoil volcanism, and then cooled rapidly to near or below 150 C by 48 Ma. At about this time, mafic Klondike Mt. lavas mark the termination of Republic graben rifting and possibly detachment faulting along the Kettle River fault.« less

Quartz and feldspar glasses produced by natural and experimental shock.

NASA Technical Reports Server (NTRS)

Stoeffler, D.; Hornemann, U.

1972-01-01

Refractive index, density, and infrared absorption studies of naturally and experimentally shocked-produced glasses formed from quartz, plagioclase, and alkali-feldspar confirm the existence of two main groups of amorphous forms of the framework silicates: solid-state and liquid-state glasses. These were apparently formed as metastable release products of high-pressure-phases above and below the glass transition temperatures. Solid-state glasses exhibit a series of structural states with increasing disorder caused by increasing shock pressures and temperatures. They gradually merge into the structural state of fused minerals similar to that of synthetic glasses quenched from a melt. Shock-fused alkali feldspars can, however, be distinguished from their laboratory-fused counterparts by infrared absorption and by higher density.

Metasomatic alkali-feldspar syenites (episyenites) of the Proterozoic Suomenniemi rapakivi granite complex, southeastern Finland

NASA Astrophysics Data System (ADS)

Suikkanen, E.; Rämö, O. T.

2017-12-01

Peralkaline to marginally metaluminous alkali-feldspar syenites and quartz alkali-feldspar syenites are hosted by subalkaline, ferroan rapakivi granites in the 1644 Ma Suomenniemi complex of southeastern Finland. These alkali syenites form NW-oriented dikes and small (< 10 m in diameter) bodies that are distinguished from the surrounding granites by their color (violet-red), general lack of quartz, as well as pronounced interstitial character of mafic minerals. Microtextures of the syenites imply pervasive alkali metasomatism and growth of secondary sodic and oxidized ferromagnesian minerals. Both subsolvus ( Ab99 and Or90-100Ab0-10) and hypersolvus (Or40-60Ab40-60) feldspar assemblages are present and display red luminescence characteristic of alkali feldspar recrystallized in the presence of an oxidizing fluid. In the marginally metaluminous syenites, primary magmatic hastingsite has been metasomatized to ferro-actinolite or decomposed to ferro-ferri-hornblende and magnetite. In some of the peralkaline syenites, primary hastingsite was replaced by magnetite and feldspars and has been overgrown by aegirine-augite and riebeckite. Sodic clinopyroxene (sodic augite-aegirine) is the most common and, in many cases, the only ferromagnesian silicate in these syenites. Three peralkaline alkali-feldspar syenites analyzed for zircon U-Pb and O isotopic compositions by single-grain SIMS have zircon 207Pb/206Pb ages of 1645 ± 5, 1642 ± 4 and 1644 ± 4 Ma, and zircon δ18OVSMOW values of 8.04 ± 0.18, 8.19 ± 0.17 and 8.26 ± 0.17‰. Whole-rock Nd isotope data imply an overall εNd(1644 Ma) value of ca. - 1.5 for the syenites. These ages and isotopic fingerprints are, within error, identical to those of the subalkaline granites of the complex. We propose that the Suomenniemi alkali-feldspar syenites are episyenites, formed as the result of pervasive local metasomatism of the subalkaline granites caused by high-temperature oxidizing peralkaline fluids. The process led to

Assessing Past Surface Processes Rates Using Feldspar Luminescence

NASA Astrophysics Data System (ADS)

Lamothe, M.

2010-12-01

Luminescence dating methods (OSL) developed over the last decade offer absolute depositional ages for sediments, crystallization ages for volcanic material or firing ages for burnt archaeological materials. When these natural surface events are from well-documented geological sequences of events, the ages can decipher timing as well as intensity of processes rates. The advent of luminescence dating has yielded a unique window on the pace of the erosion-transport-depositional cycle as the event assessed using luminescence is last exposure to sunlight and burial. A unique advantage of luminescence is its universal applicability since the routinely used dosimeters, minerals of quartz and feldspar, are almost ubiquitous on the land surface. Dating applications to sediments are still clouded by low accuracy and near saturation of the natural luminescence level, commonly observed for sediments older than the Last Interglacial. The latter imposes severe constraints in the use of quartz as a reliable dosimeter for any environment beyond the Late Pleistocene. However, in the case of feldspar, if dates are corrected for anomalous fading, ages of ancient surface processes could potentially be obtained up to ca 500 ka. Nevertheless, large uncertainties inherent to older ages may therein limit usefulness to precisely assessing processes rates. Case-studies will be used to highlight the potential and limitation of luminescence to properly assess surface processes rates for a) Holocene and older aeolian sedimentary systems, b) rates of tectonic movement by dating relative sea level changes from moderately stable to highly dynamic coastal areas, and c) albeit at its early stages, processes in volcanism, by means of tephra-extracted feldspar luminescence dating.

Episodic crustal growth in the Bundelkhand craton of central India shield: Constraints from petrogenesis of the tonalite–trondhjemite–granodiorite gneisses and K-rich granites of Bundelkhand tectonic zone

NASA Astrophysics Data System (ADS)

Chauhan, Hiredya; Saikia, Ashima; Ahmad, Talat

2018-04-01

Tonalite-trondhjemite-granodiorite gneisses (TTG) and K-rich granites are extensively exposed in the Mesoarchean to Paleoproterozoic Bundelkhand craton of central India. The TTGs rocks are coarse- grained with biotite, plagioclase feldspar, K-feldspar and amphibole as major constituent phases. The major minerals constituting the K-rich granites are K-feldspar, plagioclase feldspar and biotite. They are also medium to coarse grained. Mineral chemical studies show that the amphiboles of TTG are calcic amphibole hastingsite, plagioclase feldspars are mostly of oligoclase composition, K-feldspars are near pure end members and biotites are solid solutions between annite and siderophyllite components. The K-rich granites have biotites of siderophyllite-annite composition similar to those of TTGs, plagioclase feldspars are oligoclase in composition, potassic feldspars have XK ranging from 0.97 to 0.99 and are devoid of any amphibole. The tonalite-trondhjemite-granodiorite gneiss samples have high SiO2 (64.17-74.52 wt%), Na2O (3.11-5.90 wt%), low Mg# (30-47) and HREE contents, with moderate (La/Yb)_{CN} values (14.7-33.50) and Sr/Y ratios (4.85-98.7). These geochemical characteristics suggest formation of the TTG by partial melting of the hydrous basaltic crust at pressures and depths where garnet and amphibole were stable phases in the Paleo-Mesoarchean. The K-rich granite samples show high SiO2 (64.72-76.73 wt%), K2O (4.31-5.42), low Na2O (2.75-3.31 wt%), Mg# (24-40) and HREE contents, with moderate to high (La/Yb)_{CN} values (9.26-29.75) and Sr/Y ratios (1.52-24). They differ from their TTG in having elevated concentrations of incompatible elements like K, Zr, Th, and REE. These geochemical features indicate formation of the K-granites by anhydrous partial melting of the Paleo-Mesoarchean TTG or mafic crustal materials in an extensional regime. Combined with previous studies it is interpreted that two stages of continental accretion (at 3.59-3.33 and 3.2-3.0 Ga) and

A model that helps explain Sr-isotope disequilibrium between feldspar phenocrysts and melt in large-volume silicic magma systems

USGS Publications Warehouse

Duffield, W.A.; Ruiz, J.

1998-01-01

Feldspar phenocrysts of silicic volcanic rocks are commonly in Sr-isotopic disequilibrium with groundmass. In some cases the feldspar is more radiogenic, and in others it is less radiogenic. Several explanations have been published previously, but none of these is able to accommodate both senses of disequilibrium. We present a model by which either more- or less-radiogenic feldspar (or even both within a single eruptive unit) can originate. The model requires a magma body open to interaction with biotite- and feldspar-bearing wall rock. Magma is incrementally contaminated as wall rock melts incongruently. Biotite preferentially melts first, followed by feldspar. Such melting behavior, which is supported by both field and experimental studies, first contaminates magma with a relatively radiogenic addition, followed by a less-radiogenic addition. Feldspar phenocrysts lag behind melt (groundmass of volcanic rock) in incorporating the influx of contaminant, thus resulting in Sr-isotopic disequilibrium between the crystals and melt. The sense of disequilibrium recorded in a volcanic rock depends on when eruption quenches the contamination process. This model is testable by isotopic fingerprinting of individual feldspar crystals. For a given set of geologic boundary conditions, specific core-to-rim Sr-isotopic profiles are expectable. Moreover, phenocrysts that nucleate at different times during the contamination process should record different and predictable parts of the history. Initial results of Sr-isotopic fingerprinting of sanidine phenocrysts from the Taylor Creek Rhyolite are consistent with the model. More tests of the model are desirable.Feldspar phenocrysts of silicic volcanic rocks are commonly in Sr-isotopic disequilibrium with groundmass. In some cases the feldspar is more radiogenic, and in others it is less radiogenic. Several explanations have been published previously, but none of these is able to accommodate both senses of disequilibrium. We present a

Feldspar 40Ar/39Ar dating of ICDP PALEOVAN cores

NASA Astrophysics Data System (ADS)

Engelhardt, Jonathan Franz; Sudo, Masafumi; Stockhecke, Mona; Oberhänsli, Roland

2017-11-01

Volcaniclastic fall deposits in ICDP drilling cores from Lake Van, Turkey, contain sodium-rich sanidine and calcium-rich anorthoclase, which both comprise a variety of textural zoning and inclusions. An age model records the lake's history and is based on climate-stratigraphic correlations, tephrostratigraphy, paleomagnetics, and earlier 40Ar/39Ar analyses (Stockhecke et al., 2014b). Results from total fusion and stepwise heating 40Ar/39Ar analyses presented in this study allow for the comparison of radiometric constraints from texturally diversified feldspar and the multi-proxy lacustrine age model and vice versa. This study has investigated several grain-size fractions of feldspar from 13 volcaniclastic units. The feldspars show textural features that are visible in cathodoluminescence (CL) or back-scattered electron (BSE) images and can be subdivided into three dominant zoning-types: (1) compositional zoning, (2) round pseudo-oscillatory zoning and (3) resorbed and patchy zoning (Ginibre et al., 2004). Round pseudo-oscillatory zoning records a sensitive alternation of Fe and Ca that also reflects resorption processes. This is only visible in CL images. Compositional zoning reflects anticorrelated anorthite and orthoclase contents and is visible in BSE. Eleven inverse isochron ages from total fusion and three from stepwise heating analyses fit the age model. Four experiments resulted in older inverse isochron ages that do not concur with the model within 2σ uncertainties and that deviate from 1 ka to 17 ka minimum. C- and R-type zoning are interpreted as representing growth in magma chamber cupolas, as wall mushes, or in narrow conduits. Persistent compositions of PO-type crystals and abundant surfaces recording dissolution features correspond to formation within a magma chamber. C-type zoning and R-type zoning have revealed an irregular incorporation of melt and fluid inclusions. These two types of zoning in feldspar are interpreted as preferentially

Metasomatism in the Chain of Ponds K-feldspars: Reassessing Discrete Domain 39Ar-40Ar Modelling

NASA Astrophysics Data System (ADS)

Villa, I. M.; Chafe, A. N.; Hanchar, J. M.; Wirth, R.

2012-12-01

The post-crystallization petrology of K-feldspar (Kfs) is mostly controlled by fluids. Accordingly, [1] documented that successive mineral generations in Kfs grains of the Aar metagranite can be concordantly identified by both cathodoluminescence (CL) and back-scattered electron (BSE) imaging, elemental, and multi-isotope techniques. Imaging microstructures is a particularly powerful tool appreciated by many U-Pb geochronologists, and its use in 39Ar-40Ar dating is beginning to show beneficial progress [2]. However, a dissenting reviewer of [1] argued that the Aar sample was not typical of "orthodox" Kfs and the results could not be generalized to all Kfs [3]. On a different front, [4] demonstrated that the mathematical modeling that assumed Fickian diffusion in discrete domains, defined once and for all by [5], lacked internal consistency on several counts. As Chain of Ponds Pluton (CPP) Kfs sample MH-10 played a foundational role in the development of the mathematical model by [5], we decided to obtain direct evidence whether the numerous internal inconsistencies of the model are due to the previously undescribed petrological history of MH-10. We collected sample JH-02-01 on the same CPP outcrop as MH-10 [6]. All age spectra of different sieve fractions of the Kfs separate, both handpicked and unpicked, show a staircase shape. The Arrhenius diagram of apparent diffusivity agrees with the original MH-10 [5] and shows the same apparent r/r0 behavior. However, Arrhenius trajectories for all size fractions are parallel to each other and self-similar, as predicted by [4], instead of being joined at low temperature ("small domains") and diverging only at high T ("largest domain"), as would be implicit in the model by [5]. The CL and BSE images demonstrate several successive Kfs generations of diverse luminescence and chemical and isotopic properties. Microchemical analyses document patchy Ba enrichment, a tell-tale fingerprint of deuteric fluid interaction and

QUANTIFICATION OF GLACIAL EROSION IN THE ALPS USING VERY LOW-TEMPERATURE THERMOCHRONOLOGY (OSL & AHe)

NASA Astrophysics Data System (ADS)

Champagnac, J.; Herman, F.; Rhodes, E. J.; Fellin, M.; Jaiswal, M.; Schwenninger, J.; Reverman, R. L.

2009-12-01

The impact of glaciations on the topography of the Alps is still unclear: Long-term denudation rate determined by low-T thermochronology are in the range of 0.2 to 1 mm/yr, and increased during the Plio-Quaternary by 3 fold (Vernon et al., 2008). Such an increase is also documented by peri-alpine sediment budget (Kuhleman, 2000), with a similar increase in sediment yields since 5-3 Ma. This increase was considered as evidence of a climatically-driven surface process change, attributed to increased precipitation (Cederbom et al., 2004) and erosion by glacial processes (Champagnac et al., 2007). The timing of the onset of intense glacial erosion as well as its rates are still ambiguous. The glacial erosion seems to have accelerated around 0.9 Ma as suggested by the ten fold increase of incision rates of a valley in the Central Alps (Häuselmann et al., 2007), and by information about vegetation and sedimentologic changes (Muttoni et al., 2003). There is however no direct quantification of topographic change during the Plio-Quaternary. We present here how we use OSL-thermochronology, a new thermochronometer of exceptionally low closure temperature (about 30°-40°C) (Herman et al subm.), new {U-Th}/He on apatites data, and a glacial erosion model (Herman and Braun 2008) to estimate topographic changes in the Alps in response to glaciations. Because of their low closure temperature, OSL and AHe thermochronology enables quantification of events of less than 1 Ma at very small wavelength of the topography. We collected two vertical profiles, one in the Zermatt Valley (Valais) and one in Maurienne Valley (Savoy). We infer from these results changes in topography, date and quantify relief creation under glacial-interglacial cycles. Cederbom, C.E, et al., Climate induced rebound and exhumation of the European Alps. Geology 32, 709-712 (2000). Champagnac, J.-D., et al., Quaternary erosion-induced isostatic rebound in the western Alps. Geology 35, 195-198 (2007). Ha

First thermochronological constraints on the Cenozoic extension along the Balkan fold-thrust belt (Central Stara Planina Mountains, Bulgaria)

NASA Astrophysics Data System (ADS)

Kounov, Alexandre; Gerdjikov, Ianko; Vangelov, Dian; Balkanska, Eleonora; Lazarova, Anna; Georgiev, Stoyan; Blunt, Edward; Stockli, Daniel

2017-11-01

The Balkan fold-thrust belt, exposed in Bulgaria and north-east Serbia, is part of the north-east vergent segment of the bi-vergent Eastern Mediterranean Alpine orogen. It was formed during two distinct compressional stages; the first one lasted from the Middle Jurassic to the Early Cretaceous and the second from Late Cretaceous to the Paleogene. Although the compressional tectonic evolution of the Balkan fold-thrust belt since the Middle Jurassic and during most of the Mesozoic is relatively well studied, the final exhumation of the rocks of the belt during the Cenozoic has remained poorly understood. Here, we present the first thermochronological constraints, based on fission-track and [U-Th-(Sm)]/He analysis, showing that along the central part of the belt syn- to post-orogenic extension could have started as early as the middle Eocene. Low-temperature thermochronological analysis of samples collected from three areas reveals at least two phases of increased cooling and exhumation during the Cenozoic. The first exhumation phase took place between 44 and 30 Ma and appears to be related to the syn- to post-orogenic collapse coeval with the earliest Cenozoic extensional stage observed across the southern Balkan Peninsula. A period of relative quiescence (between 30 and 25 Ma) is followed by the next cooling stage, between 25 and 20 Ma, which appears to be related to late Oligocene to early Miocene crustal extension across the Balkan Peninsula. Extension accommodated by the late Miocene to Recent age Sub-Balkan Graben System does not appear to have produced exhumation of rocks from beneath 2-4 km depth, as it was not detected by the low-temperature thermochronological methods applied in this study.

Progress in Cochlear Physiology after Békésy

PubMed Central

Guinan, John J.; Salt, Alec; Cheatham, Mary Ann

2012-01-01

In the fifty years since Békésy was awarded the Nobel Prize, cochlear physiology has blossomed. Many topics that are now current are things Békésy could not have imagined. In this review we start by describing progress in understanding the origin of cochlear gross potentials, particularly the cochlear microphonic, an area in which Békésy had extensive experience. We then review progress in areas of cochlear physiology that were mostly unknown to Békésy, including: (1) stereocilia mechano-electrical transduction, force production, and response amplification, (2) outer hair cell (OHC) somatic motility and its molecular basis in prestin, (3) cochlear amplification and related micromechanics, including the evidence that prestin is the main motor for cochlear amplification, (4) the influence of the tectorial membrane, (5) cochlear micromechanics and the mechanical drives to inner hair cell stereocilia, (6) otoacoustic emissions, and (7) olivocochlear efferents and their influence on cochlear physiology. We then return to a subject that Békésy knew well: cochlear fluids and standing currents, as well as our present understanding of energy dependence on the lateral wall of the cochlea. Finally, we touch on cochlear pathologies including noise damage and aging, with an emphasis on where the field might go in the future. PMID:22633944

Understanding the ice nucleation characteristics of feldspars suspended in solution

NASA Astrophysics Data System (ADS)

Kumar, Anand; Marcolli, Claudia; Kaufmann, Lukas; Krieger, Ulrich; Peter, Thomas

2017-04-01

Chemical) and 5 wt% lanolin (Fluka Chemical) is emulsified with a rotor-stator homogenizer for 40 s at a rotation frequency of 7000 rpm. 4 - 10 mg of this mixture is pipetted in an aluminum pan (closed hermetically), placed in the DSC and subjected to three freezing cycles. The first and the third freezing cycles are executed at a cooling rate of 10 K/min to control the stability of the sample. The second freezing cycle is executed at a 1 K/min cooling rate and is used for evaluation. Freezing temperatures are obtained by evaluating the onset of the freezing signal in the DSC curve and plotted against water activity. Results Based on Koop et al. (2000), a general decreasing trend in ice nucleation efficiency of the mineral samples with increasing solute concentrations is expected. Interestingly, feldspars (microcline, sanidine, plagioclase) in very dilute solutions of ammonia and ammonium salts (water activity close to one) show an increase in ice nucleation efficiency of 4 to 6 K compared to that in pure water. Similar trends but less pronounced are observed for kaolinite while quartz shows barely any effect. Therefore, there seem to be specific interactions between the feldspar surface and ammonia and/or ammonium ions which result in an increase in freezing temperatures at low solute concentrations. The surface ion exchange seems to be secondary for this effect since it is also present in ammonia solution. We hypothesize that ammonia adsorbs on the aluminol/silanol groups present on feldspar (viz. aluminosilicate surface) surfaces (Nash and Marshall, 1957; Belchinskaya et al., 2013). Hence allowing one of the N-H bonds to stick outwards from the surface, facing towards the bulk water and providing a favorable template for ice to grow. The current study gives an insight into the ice nucleation behavior of aluminosilicate minerals when present in conjunction with chemical species, eg. ammonium/sulfates, which is of high atmospheric relevance. References Koop et al., (2000

Mineral dissolution in the Cape Cod aquifer, Massachusetts, USA: I . Reaction stoichiometry and impact of accessory feldspar and glauconite on strontium isotopes, solute concentrations, and REY distribution

USGS Publications Warehouse

Bau, Michael; Alexander, Brian; Chesley, John T.; Dulski, Peter; Brantley, Susan L.

2004-01-01

To compare relative reaction rates of mineral dissolution in a mineralogically simple groundwater aquifer, we studied the controls on solute concentrations, Sr isotopes, and rare earth element and yttrium (REY) systematics in the Cape Cod aquifer. This aquifer comprises mostly carbonate-free Pleistocene sediments that are about 90% quartz with minor K-feldspar, plagioclase, glauconite, and Fe-oxides. Silica concentrations and pH in the groundwater increase systematically with increasing depth, while Sr isotopic ratios decrease. No clear relationship between 87Sr/86Sr and Sr concentration is observed. At all depths, the 87Sr/86Sr ratio of the groundwater is considerably lower than the Sr isotopic ratio of the bulk sediment or its K-feldspar component, but similar to that of a plagioclase-rich accessory separate obtained from the sediment. The Si-87Sr/86Sr-depth relationships are consistent with dissolution of accessory plagioclase. In addition, solutes such as Sr, Ca, and particularly K show concentration spikes superimposed on their respective general trends. The K-Sr-87Sr/86Sr systematics suggests that accessory glauconite is another major solute source to Cape Cod groundwater. Although the authigenic glauconite in the Cape Cod sediment is rich in Rb, it is low in in-grown radiogenic 87Sr because of its young Pleistocene age. The low 87Sr/86Sr ratios are consistent with equilibration of glauconite with seawater. The impact of glauconite is inferred to vary due to its variable abundance in the sediments. In the Cape Cod groundwater, the variation of REY concentrations with sampling depth resembles that of K and Rb, but differs from that of Ca and Sr. Shale-normalized REY patterns are light REY depleted, show negative Ce anomalies and super-chondritic Y/Ho ratios, but no Eu anomalies. REY input from feldspar, therefore, is insignificant compared to input from a K-Rb-bearing phase, inferred to be glauconite. These results emphasize that interpretation of groundwater

Applying Low Temperature Thermochronology to Constrain Exhumation Patterns along the Eastern Denali Fault Corner, Alaska

NASA Astrophysics Data System (ADS)

Warfel, T. S.; Fitzgerald, P. G.; Benowitz, J.; Ridgway, K.; Allen, W. K.

2017-12-01

The Denali Fault (DF) constitutes a long ( 2000 km), arcuate, dextrally transpressive intracontinental fault system sketching across south-central Alaska. Strain-partitioning along the DF is accommodated as slip on the fault and fault-normal motion on a series of thrusts located north and south of the fault itself. High topography in the central and eastern Alaska Range, also locations of the greatest exhumation along the fault, are associated with restraining bends in those regions. East of the Richardson Highway, along the eastern Denali fault corner (or east-central segment of the DF), thrust faults south of the DF, including the McCallum thrust have accommodated the fault-normal component of motion along the DF. The aim of this project is to better understand what controls exhumation along large strike-slip faults, in particular the DF. Previous work along the DF in the central and eastern Alaska Range (to the west of this region) indicate the importance of fault geometry and rheological contrasts between terranes that have been juxtaposed against one another in controlling the location of exhumation. Our area of interest is a largely unstudied section along the Denali Fault (eastern DF corner) located between the DF/Hines Creek fault intersection and the Totschunda/DF intersection. We are applying a combination of apatite fission track thermochronology and apatite (U-Th)/He dating to samples collected north and south of the DF, and across thrust faults south of the DF. Thermochronology is being applied to bedrock samples, collected in vertical profiles and/or hanging wall - footwall pairs. Cobbles were also collected within a stratigraphic framework (constrained by tephras), from Miocene sediments in inverted basins south of the DF. Thermochronologic data from these cobbles; using lag-time analyses and inverse thermal models, will constrain the exhumation history of the hinterland. Assuming modern rates for slip along the DF will allow constraints to be placed

Evidence for Coordination and Redox Changes of Iron in Shocked Feldspar from Synchrotron MicroXANES

NASA Technical Reports Server (NTRS)

Delaney, J. S.; Dyar, M. D.; Hoerz, F.; Johnson, J. R.

2003-01-01

Shock modification of feldspar has been documented and experimentally reproduced in many studies since the recognition of maskelynite in Shergotty. Experimentally shocked feldspar samples have been well studied using chemical and crystallographic techniques. The crystallographic, site-specific characterization of major and minor elements is less well documented. We present early x-ray absorption (XAS) spectral data for a suite of albitite samples that were experimentally shocked at pressures between 17 and 50 Gpa.

High temperature (>350 °C) thermal histories of the long lived (>500 Ma) active margin of Ecuador and Colombia: Apatite, titanite and rutile U-Pb thermochronology

NASA Astrophysics Data System (ADS)

Paul, Andre N.; Spikings, Richard A.; Ulianov, Alexey; Ovtcharova, Maria

2018-05-01

Quantitative reconstruction of thermal histories can be a powerful tool to study numerous natural processes such as tectonic plate interaction, cratonic stability and extra-terrestrial phenomena such as asteroid ejection. A majority of thermochronological studies have focused on temperatures lower than 300 °C. Few previous studies have demonstrated that U-Pb data from apatite and other accessory phases can be used to recover thermal history information at T > 350 °C. We present U-Pb data from apatite, to constrain the thermal histories of Triassic peralluminous anatectites from the Northern Andes between the temperatures of ∼350-550 °C. The accuracy of the thermal history models is assessed by comparisons with previous geological models, and comparisons with pre-existing and newly acquired U/Pb (titanite and rutile), 40Ar/39Ar (muscovite) and low temperature thermochronological data. This study also examines the feasibility of using a large, regionally dispersed apatite U-Pb data set to obtain continuous thermal history paths along a long-lived (>500 Ma) active margin. A second aim of this study is to further test the hypothesis that the dominant mechanism for Pb displacement through apatite is volume diffusion, as opposed to aqueous fluid interaction. The thermal history models derived from the Triassic anatectites exposed in the Andes of Colombia and Ecuador are entirely consistent with lower temperature thermochronological constraints, and previously established geochronological and geochemical constraints. They reveal and quantify trench parallel changes in the amount of Jurassic - Early Cretaceous extension, significantly bolstering and adding to previous tectonic interpretations. Confirmation of the utility of U-Pb thermochronology provides geologists with a powerful tool for investigating the high-temperature thermal evolution of accessory minerals.

Progress Toward a Compact 0.05 K Magnet Refrigerator Operating from 10 K

NASA Technical Reports Server (NTRS)

Canavan, Edgar; Shirron, Peter; DiPirro, Micheal; Tuttle, James; Jackson, Michael; King, Todd; Numazawa, Takenori

2003-01-01

Much of the most interesting information regarding our universe is hidden in the sub-millimeter, infrared, and x-rays bands of the spectrum, to which our atmosphere is largely opaque. Thus, missions exploring these bands are a very important part of NASA s Space Science program. Coincidentally, the most sensitive detectors in these spectral regions operate at extremely low temperatures, typically 0.05 - 0.10 K. Generally these temperatures will be achieved using magnetic refrigerators, also know as Adiabatic Demagnetization Refrigerators, or ADRs. Current ADRs, such as the one used in the XRS-II instrument on the Astro-E2 satellite, use a single-stage to cool detectors from 1.3 K to 0.06 K. The ADR is designed so that it can absorb the heat on the detector stage for at least 24 hours before it must stop, warm up to the helium bath temperature (1.3 K), and dump the accumulated heat. Future detector arrays will be much larger and will have higher heat dissipation. Furthermore, future missions will use mechanical cryocoolers to provide upper stage cooling, but they can only reach 4 - 10 K. Trying to scale heavy (-15 kg) single stage ADRs up to the higher heat loads and higher heat rejection temperatures required leads to unacceptably large systems. The GSFC Cryogenics Branch has developed the Continuous ADR (CADR) to solve this problem. The CADR consists of a series of ADR stages that sequentially pass heat from the load up to the high temperature heat sink. The stage connected to the load remains at a constant temperature. The continuous stage effectively decouples detector operation from ADR operation, allowing the ADR stages to be cycled much more rapidly. Rapid cycling leads to higher cooling power density. The cascading, multistage arrangement allows the magnetic refrigerant of each stage to be optimized for its own temperature swing. In the past year, we have made good progress toward a 0.05 to 10K system. A four-stage system that operates from 4.2 K was

Modern and Past Rock Exhumation in the St. Elias Mountains Revealed by Onshore and Offshore Detrital Thermochronology

NASA Astrophysics Data System (ADS)

Enkelmann, E.; Dunn, C. A.; Ridgway, K.; Allen, W. K.

2016-12-01

The St. Elias Mountains in southeastern Alaska provide a natural laboratory to study the interacting processes of tectonics and climate. Because of the high-latitude, coastal geography the surface processes in the St. Elias Mountains are dominated by glacial erosion that varied during late Cenozoic climate shifts. Sediment eroded from the St. Elias Mountains are transported into the Gulf of Alaska by large tidewater glaciers and rivers, where they are deposited on the shelf and in large deep-sea submarine fans. Surface uplift and erosion jointly results in exhumation of deep crustal rocks that has been quantified by thermochronology, revealing spatial variations in exhumation rates across the St. Elias Mountains. We present new thermochronology data (apatite and zircon fission-track ages) from offshore strata derived from boreholes drilled by IODP Expedition 341 in the Gulf of Alaska. This offshore record provides an integrated signal of rock exhumation from the St. Elias and southeast Alaska since 10 Ma. Integrating the offshore data with the existing onshore thermochronology reveals that very rapid exhumation (>2 km/Myr) from 8-10 km depths has been occurring in southeastern Alaska since 11­-10 Ma and thus prior to the onset of glaciation. The majority of our offshore data record the past 1 Myr of deposition related to the Bagley-Bering Glacier and allows assessing the long-standing question of the western limit of extreme exhumation observed at the St. Elias syntaxis in the Seward and Hubbard glacial drainages. The zircon fission-track ages from the Bering sediment reveal small age populations that peak between 15­-9 Ma, suggesting much slower exhumation beneath the Bagley Ice Valley than farther east underneath the Seward and Hubbard glacier. Our results point out the first-order role of tectonics in providing sustained uplift and crustal weakening in the upper plate that than serve as areas for focused exhumation due to secondary erosional/climate processes.

Thermal infrared spectroscopy and modeling of experimentally shocked plagioclase feldspars

USGS Publications Warehouse

Johnson, J. R.; Horz, F.; Staid, M.I.

2003-01-01

Thermal infrared emission and reflectance spectra (250-1400 cm-1; ???7???40 ??m) of experimentally shocked albite- and anorthite-rich rocks (17-56 GPa) demonstrate that plagioclase feldspars exhibit characteristic degradations in spectral features with increasing pressure. New measurements of albite (Ab98) presented here display major spectral absorptions between 1000-1250 cm-1 (8-10 ??m) (due to Si-O antisymmetric stretch motions of the silica tetrahedra) and weaker absorptions between 350-700 cm-1 (14-29 ??m) (due to Si-O-Si octahedral bending vibrations). Many of these features persist to higher pressures compared to similar features in measurements of shocked anorthite, consistent with previous thermal infrared absorption studies of shocked feldspars. A transparency feature at 855 cm-1 (11.7 ??m) observed in powdered albite spectra also degrades with increasing pressure, similar to the 830 cm-1 (12.0 ??m) transparency feature in spectra of powders of shocked anorthite. Linear deconvolution models demonstrate that combinations of common mineral and glass spectra can replicate the spectra of shocked anorthite relatively well until shock pressures of 20-25 GPa, above which model errors increase substantially, coincident with the onset of diaplectic glass formation. Albite deconvolutions exhibit higher errors overall but do not change significantly with pressure, likely because certain clay minerals selected by the model exhibit absorption features similar to those in highly shocked albite. The implication for deconvolution of thermal infrared spectra of planetary surfaces (or laboratory spectra of samples) is that the use of highly shocked anorthite spectra in end-member libraries could be helpful in identifying highly shocked calcic plagioclase feldspars.

New ages for Middle and Later Stone Age deposits at Mumba rockshelter, Tanzania: optically stimulated luminescence dating of quartz and feldspar grains.

PubMed

Gliganic, Luke A; Jacobs, Zenobia; Roberts, Richard G; Domínguez-Rodrigo, Manuel; Mabulla, Audax Z P

2012-04-01

The archaeological deposits at Mumba rockshelter, northern Tanzania, have been excavated for more than 70 years, starting with Margit and Ludwig Köhl-Larsen in the 1930s. The assemblages of Middle Stone Age (MSA) and Later Stone Age (LSA) artefacts collected from this site constitute the type sequences for these cultural phases in East Africa. Despite its archaeological importance, however, the chronology of the site is poorly constrained, despite the application since the 1980s of several dating methods (radiocarbon, uranium-series and amino acid racemisation) to a variety of materials recovered from the deposits. Here, we review these previous chronologies for Mumba and report new ages obtained from optically stimulated luminescence (OSL) and infrared stimulated luminescence (IRSL) measurements on single grains of quartz and multi-grain aliquots of potassium (K) feldspar from the MSA and LSA deposits. Measurements of single grains of quartz allowed the rejection of unrepresentative grains and the application of appropriate statistical models to obtain the most reliable age estimates, while measurements of K-feldspars allowed the chronology to be extended to older deposits. The seven quartz ages and four K-feldspar ages provide improved temporal constraints on the archaeological sequence at Mumba. The deposits associated with the latest Kisele Industry (Bed VI-A) and the earliest Mumba Industry (Bed V) are dated to 63.4 ± 5.7 and 56.9 ± 4.8 ka (thousands of years ago), respectively, thus constraining the time of transition between these two archaeological phases to ~60 ka. An age of 49.1 ± 4.3 ka has been obtained for the latest deposits associated with the Mumba Industry, which show no evidence for post-depositional mixing and contain ostrich eggshell (OES) beads and abundant microlithics. The Nasera Industry deposits (Bed III) contain large quantities of OES beads and date to 36.8 ± 3.4 ka. We compare the luminescence ages with the previous chronologies for

Sorption Mechanisms of Antibiotic Cephapirin onto Quartz and Feldspar by Raman Spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peterson, Jonathan; Wang, Wei; Gu, Baohua

2009-01-01

Raman spectroscopy was used to investigate the sorption mechanisms of cephapirin (CHP), a veterinary antibiotic, onto quartz (SiO2) and feldspar (KAlSi3O8) at different pH values. Depending on the charge and surface properties of the mineral, different reaction mechanisms including electrostatic attraction, monodentate and bidentate complexation were found to be responsible for CHP sorption. The zwitterion (CHPo) adsorbs to a quartz(+) surface by electrostatic attraction of the carboxylate anion group ( COO-) at a low pH, but adsorbs to a quartz(-) surface through electrostatic attraction of the pyridinium cation and possibly COO- bridge complexes at relatively higher pH conditions. CHP- bondsmore » to a quartz(-) surface by bidentate complexation between one oxygen of COO- and oxygen from the carbonyl (C=O) of the acetoxymethyl group. On a feldspar surface of mixed charge, CHPo forms monodentate complexes between C=O as well as COO- bridging complexes or electrostatically attached to localized edge (hydr)oxy-Al surfaces. CHP- adsorbs to feldspar(-) through monodentate C=O complexation, and similar mechanisms may operate for the sorption of other cephalosporins. This research demonstrates, for the first time, that Raman spectroscopic techniques can be effective for evaluating the sorption processes and mechanisms of cephalosporin antibiotics even at relatively low sorbed concentrations (97-120 μmol/kg).« less

Direct evidence for the participation of band-tails and excited-state tunnelling in the luminescence of irradiated feldspars

NASA Astrophysics Data System (ADS)

Poolton, N. R. J.; Kars, R. H.; Wallinga, J.; Bos, A. J. J.

2009-12-01

The significance and extent of band-tail states in the luminescence and dosimetry properties of natural aluminosilicates (feldspars) is investigated by means of studies using low temperature (10 K) irradiation and optically stimulated luminescence (OSL) stimulation spectroscopy, and thermoluminescence (TL) in the range 10-200 K, made in comparison with high temperature (300 K) irradiation and photo-transferred OSL and TL investigations undertaken at low temperature. These measurements allow mappings of the band-tails to be made; they are found to be ~0.4 eV in extent in the typical materials studied. Furthermore, by populating charge trapping centres at high temperature (300 K) and monitoring the OSL stimulation spectra at temperatures in the range 10-300 K, clear evidence is presented for the presence of both thermally activated and non-thermally activated OSL processes; it is argued that the former result from thermally activated hopping through the band-tail states, whilst the latter are due to tunnelling processes, either from the excited state of the OSL centres or through the tail states. The spectral measurements are supported by analysis of the temporal dependence of the OSL signals, which correspond to either tunnelling or general order kinetic decay processes.

Spatial variations in focused exhumation along a continental-scale strike-slip fault: The Denali fault of the eastern Alaska Range

USGS Publications Warehouse

Benowitz, J.A.; Layer, P.W.; Armstrong, P.; Perry, S.E.; Haeussler, Peter J.; Fitzgerald, P.G.; VanLaningham, S.

2011-01-01

40Ar/39Ar, apatite fission-track, and apatite (U-Th)/He thermochronological techniques were used to determine the Neogene exhumation history of the topographically asymmetric eastern Alaska Range. Exhumation cooling ages range from ~33 Ma to ~18 Ma for 40Ar/39Ar biotite, ~18 Ma to ~6 Ma for K-feldspar minimum closure ages, and ~15 Ma to ~1 Ma for apatite fission-track ages, and apatite (U-Th)/He cooling ages range from ~4 Ma to ~1 Ma. There has been at least ~11 km of exhumation adjacent to the north side of Denali fault during the Neogene inferred from biotite 40Ar/39Ar thermochronology. Variations in exhumation history along and across the strike of the fault are influenced by both far-field effects and local structural irregularities. We infer deformation and rapid exhumation have been occurring in the eastern Alaska Range since at least ~22 Ma most likely related to the continued collision of the Yakutat microplate with the North American plate. The Nenana Mountain region is the late Pleistocene to Holocene (~past 1 Ma) primary locus of tectonically driven exhumation in the eastern Alaska Range, possibly related to variations in fault geometry. During the Pliocene, a marked increase in climatic instability and related global cooling is temporally correlated with an increase in exhumation rates in the eastern Alaska Range north of the Denali fault system.

Biochemical evolution. I. Polymerization On internal, organophilic silica surfaces of dealuminated zeolites and feldspars.

PubMed

Smith, J V

1998-03-31

Catalysis at mineral surfaces might generate replicating biopolymers from simple chemicals supplied by meteorites, volcanic gases, and photochemical gas reactions. Many ideas are implausible in detail because the proposed mineral surfaces strongly prefer water and other ionic species to organic ones. The molecular sieve silicalite (Union Carbide; = Al-free Mobil ZSM-5 zeolite) has a three-dimensional, 10-ring channel system whose electrically neutral Si-O surface strongly adsorbs organic species over water. Three -O-Si tetrahedral bonds lie in the surface, and the fourth Si-O points inwards. In contrast, the outward Si-OH of simple quartz and feldspar crystals generates their ionic organophobicity. The ZSM-5-type zeolite mutinaite occurs in Antarctica with boggsite and tschernichite (Al-analog of Mobil Beta). Archean mutinaite might have become de-aluminated toward silicalite during hot/cold/wet/dry cycles. Catalytic activity of silicalite increases linearly with Al-OH substitution for Si, and Al atoms tend to avoid each other. Adjacent organophilic and catalytic Al-OH regions in nanometer channels might have scavenged organic species for catalytic assembly into specific polymers protected from prompt photochemical destruction. Polymer migration along weathered silicic surfaces of micrometer-wide channels of feldspars might have led to assembly of replicating catalytic biomolecules and perhaps primitive cellular organisms. Silica-rich volcanic glasses should have been abundant on the early Earth, ready for crystallization into zeolites and feldspars, as in present continental basins. Abundant chert from weakly metamorphosed Archaean rocks might retain microscopic clues to the proposed mineral adsorbent/catalysts. Other framework silicas are possible, including ones with laevo/dextro one-dimensional channels. Organic molecules, transition-metal ions, and P occur inside modern feldspars.

Biochemical evolution. I. Polymerization on internal, organophilic silica surfaces of dealuminated zeolites and feldspars

PubMed Central

Smith, Joseph V.

1998-01-01

Catalysis at mineral surfaces might generate replicating biopolymers from simple chemicals supplied by meteorites, volcanic gases, and photochemical gas reactions. Many ideas are implausible in detail because the proposed mineral surfaces strongly prefer water and other ionic species to organic ones. The molecular sieve silicalite (Union Carbide; = Al-free Mobil ZSM-5 zeolite) has a three-dimensional, 10-ring channel system whose electrically neutral Si-O surface strongly adsorbs organic species over water. Three -O-Si tetrahedral bonds lie in the surface, and the fourth Si-O points inwards. In contrast, the outward Si-OH of simple quartz and feldspar crystals generates their ionic organophobicity. The ZSM-5-type zeolite mutinaite occurs in Antarctica with boggsite and tschernichite (Al-analog of Mobil Beta). Archean mutinaite might have become de-aluminated toward silicalite during hot/cold/wet/dry cycles. Catalytic activity of silicalite increases linearly with Al-OH substitution for Si, and Al atoms tend to avoid each other. Adjacent organophilic and catalytic Al-OH regions in nanometer channels might have scavenged organic species for catalytic assembly into specific polymers protected from prompt photochemical destruction. Polymer migration along weathered silicic surfaces of micrometer-wide channels of feldspars might have led to assembly of replicating catalytic biomolecules and perhaps primitive cellular organisms. Silica-rich volcanic glasses should have been abundant on the early Earth, ready for crystallization into zeolites and feldspars, as in present continental basins. Abundant chert from weakly metamorphosed Archaean rocks might retain microscopic clues to the proposed mineral adsorbent/catalysts. Other framework silicas are possible, including ones with laevo/dextro one-dimensional channels. Organic molecules, transition-metal ions, and P occur inside modern feldspars. PMID:9520372

Conodont (U Th)/He thermochronology: Initial results, potential, and problems

NASA Astrophysics Data System (ADS)

Peppe, Daniel J.; Reiners, Peter W.

2007-06-01

We performed He diffusion experiments and (U-Th)/He age determinations on conodonts from a variety of locations to explore the potential of conodont (U-Th)/He thermochronology to constrain thermal and exhumation histories of some sedimentary-rock dominated terrains. Based on two diffusion experiments and age results from some specimens, He diffusion in conodont elements appears to be similar to that in Durango apatite fragments of similar size, and closure temperatures are approximately 60-70 °C (for cooling rates of ˜ 10 °C/m.y.). (U-Th)/He ages of conodonts from some locations yield reproducible ages consistent with regional thermal history constraints and, in at least two cases, require a closure temperature lower than ˜ 80 °C. Other samples however, yield irreproducible ages, and in one case yield ages much younger than expected based on regional geologic considerations. These irreproducible samples show inverse correlations between parent nuclides and age consistent with late-stage open-system U-Th behavior.

Europium anomaly in plagioclase feldspar - Experimental results and semiquantitative model.

NASA Technical Reports Server (NTRS)

Weill, D. F.; Drake, M. J.

1973-01-01

The partition of europium between plagioclase feldspar and magmatic liquid is considered in terms of the distribution coefficients for divalent and trivalent europium. A model equation is derived giving the europium anomaly in plagioclase as a function of temperature and oxygen fugacity. The model explains europium anomalies in plagioclase synthesized under controlled laboratory conditions as well as the variations of the anomaly observed in natural terrestrial and extraterrestrial igneous rocks.

Europium anomaly in plagioclase feldspar: experimental results and semiquantitative model.

PubMed

Weill, D F; Drake, M J

1973-06-08

The partition of europium between plagioclase feldspar and magmatic liquid is considered in terms of the distribution coefficients for divalent and trivalent europium. A model equation is derived giving the europium anomaly in plagioclase as a function of temperature and oxygen fugacity. The model explains europium anomalies in plagioclase synthesized under controlled laboratory conditions as well as the variations of the anomaly observed in natural terrestrial and extraterrestrial igneous rocks.

Monitoring Progress toward Successful K-12 STEM Education: A Nation Advancing?

ERIC Educational Resources Information Center

National Academies Press, 2013

2013-01-01

Following a 2011 report by the National Research Council (NRC) on successful K-12 education in science, technology, engineering, and mathematics (STEM), Congress asked the National Science Foundation to identify methods for tracking progress toward the report's recommendations. In response, the NRC convened the Committee on an Evaluation Framework…

The Thermochronologist's Progress

NASA Astrophysics Data System (ADS)

Zeitler, P. K.

2011-12-01

We owe our current understanding of thermochronology less to a series of revolutionary insights than to a somewhat uneven intellectual pilgrimage that over fifty years has progressed in fits and starts. Though hampered at times by overenthusiasm, oversimplification, and misunderstandings, on balance the field advanced thanks to a blend of curiosity-driven research, tool-building motivated by new ideas about Earth science, and improvements in technology. But now that we've exploited most radiogenic systems and the major minerals that host them, and now that our models can devour CPU time along with the best of them, are we done? Have we reached peak thermochron? The answer of course is no, and papers in this session will demonstrate what new technologies and techniques might have to offer in the coming years. However, I will argue that the discipline as a whole has matured to a point where if thermochronology is to remain a mainstream tool as opposed to a weekend sport, we need to get serious about several challenges. The most fundamental challenge is that current geodynamic models (and even more complex models we can envision coding) have outpaced our meagre stockpile of kinetic calibrations, our understanding of detailed isotope systematics, and our ability to generate data with sufficient throughput. These issues will not be addressed adequately through the business-as-usual approach that brought us to our current knowledge, and some community effort will probably be needed to coordinate the hard work that will be required. But any serious attempt to answer important questions with accurate thermal histories that have low and well-defined uncertainties will require that we actually know the kinetics for the specific samples we are analyzing, that we fully understand scatter in the data, that we work with the large sample numbers that are required for some problems like landscape evolution, and that inversion tools fully explore the important aspects of both the

K-Ar age constrains on chemically weathered granitic basement rocks (saprolites) in Scandinavia

NASA Astrophysics Data System (ADS)

Margreth, Annina; Fredin, Ola; Viola, Giulio; Knies, Jochen; Sørlie, Ronald; Lie, Jan-Erik; Margrethe Grandal, Else; Zwingmann, Horst; Vogt, Christoph

2017-04-01

Remnants of in-situ weathered bedrock, saprolite, are found in several locations in Scandinavia. Saprolites contain important information about past climate conditions and landscape evolution, although their age and genesis are commonly difficult to constrain. It is generally thought that clay-poor, coarse-grained (arêne) saprolites, mostly occurring as thin regolith blankets or in larger outcrops, formed in temperate climate during the Cenozoic, whereas clay-rich (argillic) saprolites, commonly restricted to small, fracture-bounded outcrops, formed in (sub-)tropical climate during the Mesozoic. Recent methodological and conceptual advances in K-Ar dating of illite-bearing fault rocks have been applied to date clay-rich saprolites. To test the K-Ar dating technique for saprolites, we first selected an offshore site in the Viking Graben of the North Sea, where weathered and fractured granitic basement highs have been drilled during petroleum exploration, and an abandoned kaolin mine in Southern Sweden. Both targets provide independent age control through the presence of overlying Mesozoic sedimentary rocks. Clay-rich saprolites occurring in fractured basement rocks were additionally sampled in a joint valley landscape on the southwestern coast of Norway, which can be regarded as the possible onland correlative to the offshore basement high. In order to offer a sound interpretation of the obtained K-Ar ages, the mineralogical and chemical composition of the saprolites requires a thorough characterization. Scanning electron microscopy of thin sections, integrated by XRD and XRF analysis, reveals the progressive transformation of primary granitic rock minerals into secondary clay minerals. The authigenesis of illite is particularly important to understand, since it is the only K-bearing clay mineral that can be dated by the K-Ar method. K-feldspars and mica are the common primary K-bearing minerals, from which illite can be formed. While progressive leaching of

FTIR measurements of OH in deformed quartz and feldspars of the South Tibetan Detachment, Greater Himalaya

NASA Astrophysics Data System (ADS)

Jezek, L.; Law, R. D.; Jessup, M. J.; Searle, M. P.; Kronenberg, A. K.

2017-12-01

OH absorption bands due to water in deformed quartz and feldspar grains of mylonites from the low-angle Lhotse Detachment (of the South Tibetan Detachment System, Rongbuk Valley north of Mount Everest) have been measured by Fourier Transform Infrared (FTIR) Spectroscopy. Previous microstructural studies have shown that these rocks deformed by dislocation creep at high temperature conditions in the middle crust (lower - middle amphibolite facies), and oxygen isotope studies suggest significant influx of meteoric water. OH absorption bands at 3400 cm-1 of quartz mylonites from the footwall of the Lhotse Detachment Fault are large, with the character of the molecular water band due to fluid inclusions in milky quartz. Mean water contents depend on structural position relative to the core of the Lhotse Detachment, from 1000 ppm (OH/106 Si) at 420 m below the fault to 11,350 (+/-1095) ppm near its center. The gradient in OH content shown by quartz grains implies influx of meteoric water along the Lhotse Detachment from the Tibetan Plateau ground surface to middle crustal depths, and significant fluid penetration into the extruding Himalayan slab by intergranular, permeable fluid flow processes. Feldspars of individual samples have comparable water contents to those of quartz and some are wetter. Large water contents of quartz and feldspar may have contributed to continued deformation and strain localization on the South Tibetan Detachment System. Dislocation creep in quartz is facilitated by water in laboratory experiments, and the water contents of the Lhotse fault rocks are similar to (and even larger than) water contents of quartz experimentally deformed during water weakening. Water contents of feldspars are comparable to those of plagioclase aggregates deformed experimentally by dislocation and diffusion creep under wet conditions.

Low temperature thermochronology in the Easter Alps. New data, interpretations and perspectives.

NASA Astrophysics Data System (ADS)

Wölfler, Andreas

2015-04-01

The aim of this study is to evaluate new and published low temperature thermochronological data of the Eastern Alps in terms of its Mesozoic and Cenozoic tectonic evolution and the possible connection with deep seated lithospheric processes. In the Eastern Alps, the tectonic units that originate from the Penninic domain are buried beneath the Austroalpine nappe stack. Overthrusting of the Austroalpine nappes over the Penninic units occurred throughout the Cretaceous and lasted until the Eocene. During lateral tectonic extrusion in Oligocene to Miocene times the footwall penninic units exposed in the Tauern Window, were tectonically exhumed from below the Austroalpine hanging wall. This is well documented by Miocene to Pliocene zircon- and apatite fission track (ZFT, AFT) and (U-Th)/He data. However, the Austroalpine hanging wall shows a more complex age pattern. Late Cretaceous ZFT data reflect post-metamorphic exhumational cooling after Eo-Alpine metamorphism that goes along with an extensional phase that affected large parts of the Eastern Alps. Paleogene AFT and apatite (U-Th)/He data of the Austroalpine units to the east of the Tauern Window reflect exhumation of this area that supplied clastic material, the so-called Augenstein formation. Exhumation and erosion of the area left a probably hilly surface in Early Miocene times that was only moderately uplifted since then. These areas are well known for paleosurfaces exposed in the Gurktal- Kor- and Seckauer Alps to the east of the Tauern Window and in the central and eastern Northern Calcareous Alps. However, distinct parts of the Austroalpine hanging wall experienced substantial exhumation and surface uplift in the Miocene, contemporaneous to the exhumation of Penninic units and lateral extrusion of the Eastern Alps. These areas are restricted to the south and northeast of the Tauern Window and are characterized by steep and rugged reliefs that contrast the hilly and moderately shaped reliefs of the

Deciphering the evolution of rapakivi magmas from mineral inclusions in alkali feldspar megacrysts and zircon

NASA Astrophysics Data System (ADS)

Heinonen, Aku; Mänttäri, Irmeli; Rämö, Tapani; Larjamo, Kirsi

2017-04-01

Rapakivi granites are ferroan (A-type) granites that are characterized by ovoid-shaped alkali feldspar megacrysts (diameter up to 15 cm) commonly mantled by plagioclase forming the namesake rapakivi texture. The 1.63 Ga Wiborg batholith in southeastern Finland is the type area of rapakivi granites. Recent studies into the chemistry and geochronology of the mineral inclusions within the Wiborg rapakivi granite ovoids have shown that the megacrysts may represent magmas that crystallized significantly earlier and either in different P/T conditions or from magmas with dissimilar compositions than the matrices of the respective granites. It is possible that the ovoids crystallized from magmas with more evolved geochemical characteristics than the matrices, including higher levels of REE and other incompatibe elements. All ovoids are perthitic and have concave and rod-shaped quartz, hypidiomorphic or slightly resorbed plagioclase (often with partial quartz rim), zircon, biotite, apatite, and ilmenite (and occasionally minor magnetite) inclusions. The ovoids of the mafic rapakivi granite types have also hornblende and sometimes olivine and clinopyroxene inclusions, whereas the more felsic types have abundant fluorite. In contrast to the ovoids, the groundmass feldspar grains have hardly any inclusions. Differences are also observed in the hornblende compositions between the ovoid inclusion (dominantly ferroedenitic) and matrix (ferropargasitic/hastingsitic) populations. As zircon is an almost ubiquitous inclusion phase, time-integrated trace element composition comparisons of not only ovoid inclusion and matrix populations but also between different morphological types have been possible. Also the zircon crystals themselves contain plenty of inclusions. Alkali feldspar (albite and potassic feldspar) and quartz constitute the bulk of the inclusions within zircon crystals but chloritized mafic minerals, and sometimes also fluorite and ilmenite are common. A detailed

Experimental progress of a 4K VM/PT hybrid cryocooler for pre-cooling 1K sorption cooler

NASA Astrophysics Data System (ADS)

Pan, Changzhao; Zhang, Tong; Wang, Jue; Chen, Liubiao; Guo, Jia; Zhou, Yuan; Wang, Junjie

2017-12-01

Sub-kelvin refrigerator has many applications in space detector and manned space station, such as for the transition-edge superconducting (TES) bolometers operated in the 50 mK range. In order to meet the requirement of space applications, the high efficient, vibration free and high stability refrigerator need to be designed. VM/PT hybrid cryocooler is a new type cryocooler capable of attaining temperature below 4K. As a low frequency Stirling type cryocooler, it has the advantages of high stability and high efficiency. Combined with the vibration free sorption cooler and ADR refrigerator, a novel sub-kelvin cooling chain can be designed for the TES bolometer. This paper presents the recent experimental progress of the 4K VM/PT hybrid cryocooler in our laboratory. By optimizing of regenerators, phase shifters and heat exchangers, a lowest temperature of 2.6K was attained. Based on this cryocooler, a preliminary sorption cooler could be designed.

Constraining the near-surface response to lithospheric reorientation: Structural thermochronology along the TRANSALP geophysical transect

NASA Astrophysics Data System (ADS)

Glotzbach, Christoph; Büttner, Lukas; Ehlers, Todd

2017-04-01

Tomographic analyses of the lithosphere structure underneath the Alps suggest a complex geodynamic history (e.g. Lippitsch et al. 2003), indicating, among other things, switches in the direction of subduction. A subduction polarity switch is proposed to have occurred in Miocene times between the Central and Eastern Alps (e.g. Lippitsch et al. 2003; Handy et al. 2015). In the Western and Central Alps SE-directed subduction of European continental lithosphere occurs, whereas NW-directed subduction of Adriatic lithosphere occurs further east (e.g. Kissling et al. 2006). The subducted slab steepens at the transition to the Eastern Alps, roughly at the position of the TRANSALP geophysical profile (S. Germany to N. Italy). This lithospheric reorientation was pre-dated by slab breakoff and also involves the delamination of the lower lithosphere, both processes producing distinct long-wavelength deformation (e.g. Gerya et al. 2004). Thermochronological data can be used to study the surface response to such a long-wavelength deformation. We present new apatite and zircon (U-Th)/He ages of 23 samples collected along 210 km of the TRANSALP profile. The samples were collected along a balanced cross section the TRANSALP profile (e.g. Lüschen et al. 2004) across individual structures that can be tied to deeper, seismically imaged, structures. The thermochronometer ages provide a record of exhumation related to both crustal shortening and post deformation erosional exhumation. Interpretation of the data is in progress and being used to discriminate between competing kinematic/geometric models, and the timing of major fault activity. Variations in exhumation along the section will also unravel the timing and shape of possible long-wavelength rock uplift event(s). References Gerya, T.V., Yuen, D.A., Maresch, W.V. 2004. Thermomechanical modelling of slab detachment. Earth Planet. Sci. Lett. 226, 101-116. Handy, M.R., Ustaszewski, K., Kissling, E. 2015. Reconstructing the Alps

Coupled CaAl-NaSi diffusion in plagioclase feldspar: Experiments and applications to cooling rate speedometry

NASA Astrophysics Data System (ADS)

Grove, Timothy L.; Baker, Michael B.; Kinzler, Rosamond J.

1984-10-01

The rate of CaAl-NaSi interdiffusion in plagioclase feldspar was determined under 1 atm anhydrous conditions over the temperature range 1400° to 1000°C in calcic plagioclase (An 80-81) by homogenizing coherent exsolution lamellae. The dependence of the average interdiffusion coefficient on temperature is given by the expression: D˜ = 10.99 ( cm 2/sec) exp (-123.4( kcal/mol)/RT), (T in °K). This value is for diffusion perpendicular to the (03 1¯) interface of the lamellae. CaAl-NaSi interdiffusion is 4 to 5 orders of magnitude slower than oxygen diffusion in the temperature range 1400° to 1200°C and possibly 10 orders of magnitude slower at subsolidus temperatures. The large differences in diffusion rates explain the apparent contradiction posed by the plagioclases of large layered intrusions ( e.g., the Skaergaard), which retain delicate Ca, Na compositional zoning profiles on the micron scale, but have undergone complete oxygen isotopic exchange with heated meteoric groundwater from the surrounding wall rocks. CaAl-NaSi diffusion is slow, the closure temperature is high (within the solidus-liquidus interval), and Ca-Na zoning is preserved. Oxygen diffusion is faster, the closure temperature is lower (350°-400°C) and the feldspars exchange oxygen with the low-temperature hydrothermal fluids. The complex micron-scale oscillatory zones in plagioclase can also be used as cooling rate speedometers for volcanic and plutonic plagioclase. Cooling histories typical of large mafic intrusions ( e.g. the Stillwater) are slow, begin at high initial temperatures (1200°C) and result in homogenization of oscillatory zones on the scale of 10 microns. The oscillatory zones found in the plagioclase of granodioritic plutons are preserved because cooling is initiated at a lower temperature (1000°C) limiting diffusion to submicron length scales despite the slow cooling rate of the intrusion.

Apatite (U-Th)/He thermochronology dataset interpretation: New insights from physical point of view

NASA Astrophysics Data System (ADS)

Gautheron, Cécile; Mbongo-Djimbi, Duval; Gerin, Chloé; Roques, Jérôme; Bachelet, Cyril; Oliviero, Erwan; Tassan-Got, Laurent

2015-04-01

demonstrate that in addition to grain chemistry, He diffusivity will be strongly influenced by damage and propose a new physical model. Finally, we propose a new way of interpreting AHe datasets and practical geological examples will be given. Flowers, R., Ketcham, R.A., Shuster, D., Farley, K.A., 2009. Apatite (U-Th)/He thermochronology using a radiation damage accumulation and annealing model. Geochimica et Cosmochimica Acta 73, 2347-2365. Gautheron, C., Tassan-got, L., Barbarand, J., Pagel, M., 2009. Effect of alpha-damage annealing on apatite (U-Th)/He thermochronology. Chemical Geology 266, 166-179. Gautheron, C., Barbarand, J., Ketcham R.A., Tassan-got, L., van der Beek, P., Pagel, M., Pinna-Jamme, R., Couffignal, F., Fialin, M., 2013. Chemical influence on α-recoil damage annealing in apatite: implications for (U-Th)/He dating. Chemical Geology 351, 257-267. Mbongo-Djimbi D., Gautheron C., Roques, J., Tassan-Got, L., Gerin, C., Simoni, E.. Apatite composition effect on (U-Th)/He thermochronometer: an atomistic point of view. In review at Geochimica Cosmochimica Acta.

Rock inhabiting potassium solubilizing bacteria from Kerala, India: characterization and possibility in chemical K fertilizer substitution.

PubMed

Anjanadevi, Indira Parameswaran; John, Neetha Soma; John, Kuzhivilayil Susan; Jeeva, Muthulekshmi Lajapathy; Misra, Raj Shekhar

2016-01-01

The role of rock inhabiting bacteria in potassium (K) solubilization from feldspar and their application in crop nutrition through substitution of fertilizer K was explored through the isolation of 36 different bacteria from rocks of a major hill station at Ponmudi in Thiruvananthapuram, Kerala, India. A comprehensive characterization of K solubilization from feldspar was achieved with these isolates which indicated that the K solubilizing efficiency increases with decrease in pH and increase in viscosity and viable cell count. Based on the level of K solubilization, two potent isolates were selected and identified as Bacillus subtilis ANctcri3 and Bacillus megaterium ANctcri7. Exopolysaccharide production, scanning electron microscopic and fourier transform infrared spectroscopic studies with these efficient strains conclusively depicted the role of low pH, increase in viscosity, and bacterial attachment in K solubilization. They were also found to be efficient in phosphorus (P) solubilization, indole acetic acid production as well as tolerant to wide range of physiological conditions. Moreover, the applicability of K containing rock powder as a carrier for K solubilizing bacteria was demonstrated. A field level evaluation on the yield of a high K demanding tuberous vegetable crop, elephant foot yam (Amorphophallus paeoniifolius (dennst.) nicolson) established the possibility of substituting chemical K fertilizer with these biofertilizer candidates successfully. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Late-Quaternary exhumation of Namche Barwa constrained using low-temperature multi-OSL-thermochronometry

NASA Astrophysics Data System (ADS)

King, Georgina; Herman, Frederic

2016-04-01

The influence of climate on tectonic processes remains a controversial concept. Exhumation rates of >5 mm/yr make Namche Barwa, Tibet, one of the most rapidly exhuming places on earth, and two main hypotheses have developed to explain the very high rates of exhumation there. The tectonic aneurysm model (Zeitler et al., 2001) proposes that crustal weakening coupled with extremely active surface processes causes a spatial stationarity of exhumation. Alternatively, a northward plunging antiform that is progressively migrating north-eastward (Seward and Burg, 2008) may explain the concentration of extremely low cooling ages and rapid exhumation that characterise the Namche Barwa massif. Here we use multi-OSL-thermochronometry of feldspar, which comprises a series of different systems with closure temperatures ranging from 30 to 70 C, to quantify spatial and temporal changes in exhumation rates. We have applied this new technique to a suite of samples from the Namche Barwa massif and inverting our data enables us to precisely resolve cooling histories over 0.1 Ma timescales. Our data indicate propagation of a knick-point along the Parlung river, which can be explained by progressive north-eastward migration of a northward plunging antiform. We suggest that river incision does not therefore feedback onto tectonics, as proposed by the aneurysm model. Zeitler, P.K., Meltzer, A.S., Koons, P.O., et al., 2001. Erosion, Himalayan Geodynamics, and the Geomorphology of Metamorphism. GSA Today 11, 4-9 Seward, D., Burg, J-P., 2008. Growth of the Namche Barwa Syntaxis and associated evolution of the Tsangpo Gorge: Constraints from structural and thermochronological data. Tectonophysics 451, 282-289.

PI3K pathway mutations are associated with longer time to local progression after radioembolization of colorectal liver metastases.

PubMed

Ziv, Etay; Bergen, Michael; Yarmohammadi, Hooman; Boas, F Ed; Petre, E Nadia; Sofocleous, Constantinos T; Yaeger, Rona; Solit, David B; Solomon, Stephen B; Erinjeri, Joseph P

2017-04-04

To establish the relationship between common mutations in the MAPK and PI3K signaling pathways and local progression after radioembolization. Retrospective review of a HIPAA-compliant institutional review-board approved database identified 40 patients with chemo-refractory colorectal liver metastases treated with radioembolization who underwent tumor genotyping for hotspot mutations in 6 key genes in the MAPK/PI3K pathways (KRAS, NRAS, BRAF, MEK1, PIK3CA, and AKT1). Mutation status as well as clinical, tumor, and treatment variables were recorded. These factors were evaluated in relation to time to local progression (TTLP), which was calculated from time of radioembolization to first radiographic evidence of local progression. Predictors of outcome were identified using a proportional hazards model for both univariate and multivariate analysis with death as a competing risk. Sixteen patients (40%) had no mutations in either pathway, eighteen patients (45%) had mutations in the MAPK pathway, ten patients (25%) had mutations in the PI3K pathway and four patients (10%) had mutations in both pathways. The cumulative incidence of progression at 6 and 12 months was 33% and 55% for the PI3K mutated group compared with 76% and 92% in the PI3K wild type group. Mutation in the PI3K pathway was a significant predictor of longer TTLP in both univariate (p=0.031, sHR 0.31, 95% CI: 0.11-0.90) and multivariate (p=0.015, sHR=0.27, 95% CI: 0.096-0.77) analysis. MAPK pathway alterations were not associated with TTLP. PI3K pathway mutation predicts longer time to local progression after radioembolization of colorectal liver metastases.

Structure and thermochronology of the metamorphic core of the Brooks Range, Alaska

NASA Astrophysics Data System (ADS)

Toro, Jaime

1999-11-01

Detailed field studies were undertaken in two key areas of the Central Belt of the Brooks Range: (1) the north flank of Mt. Igikpak in the Survey Pass Quadrangle and (2) in the Shishakshinovik Pass area in the eastern Ambler River Quadrangle. In both areas structural, stratigraphic, petrologic, 40Ar/39Ar, apatite fission-track and U-Pb data were used to constrain the kinematic and thermal history of metamorphic rocks of those areas. North of the Mt. Igikpak massif a crustal section ˜15 km thick is exposed. There are upper greenschist facies rocks in the deeper portions, and very low grade metamorphic rocks at higher structural levels. Two foliations are found: a higher grade relict S1 fabric and a lower grade S 2 fabric that controls the metamorphic layering. 40Ar/ 39Ar analyses from S1 white mica in the low-grade rocks at the northern end of the transect indicate that peak M1 metamorphism occurred before ˜112 Ma. We ascribe M1 to shortening that occurred during collision of an island arc against the Arctic Alaska margin. S 2 involved the retrogression of earlier assemblages. Kinematic indicators on S2 are top-to-the-north. A rapid cooling event from 500 +/- 50°C to 300 +/- 50°C took place between ˜98 and ˜90 Ma. The driving mechanism for ductile deformation during S2, and for rapid cooling documented by our thermochronologic data, was probably the gravitational collapse of the core of the orogen, over-thickened during the preceding collision. At Shishakshinovik Pass there are Mississippian Lisburne Group strata surrounded by metamorphic rocks typical of the Central Belt of the Brooks Range. All the rocks at Shishakshinovik Pass are intensely deformed, so that one cannot distinguish between an autochthonous and an allochthonous sequence. Furthermore the Mississippian rocks, instead of being attached to the underlying basement, are in the hanging wall of a northwest dipping shear zone. Based on the variations in metamorphic grade and the 40Ar/ 39Ar

Cenozoic tectono-thermal history of the Tordrillo Mountains, Alaska: Paleocene-Eocene ridge subduction, decreasing relief, and late Neogene faulting

USGS Publications Warehouse

Benowitz, Jeff A.; Haeussler, Peter J.; Layer, Paul W.; O'Sullivan, Paul B.; Wallace, Wes K.; Gillis, Robert J.

2012-01-01

Topographic development inboard of the continental margin is a predicted response to ridge subduction. New thermochronology results from the western Alaska Range document ridge subduction related orogenesis. K-feldspar thermochronology (KFAT) of bedrock samples from the Tordrillo Mountains in the western Alaska Range complement existing U-Pb, 40Ar/39Ar and AFT (apatite fission track) data to provide constraints on Paleocene pluton emplacement, and cooling as well as Late Eocene to Miocene vertical movements and exhumation along fault-bounded blocks. Based on the KFAT analysis we infer rapid exhumation-related cooling during the Eocene in the Tordrillo Mountains. Our KFAT cooling ages are coeval with deposition of clastic sediments in the Cook Inlet, Matanuska Valley and Tanana basins, which reflect high-energy depositional environments. The Tordrillo Mountains KFAT cooling ages are also the same as cooling ages in the Iliamna Lake region, the Kichatna Mountains of the western Alaska Range, and Mt. Logan in the Wrangell-St. Elias Mountains, thus rapid cooling at this time encompasses a broad region inboard of, and parallel to, the continental margin extending for several hundred kilometers. We infer these cooling events and deposition of clastic rocks are related to thermal effects that track the eastward passage of a slab window in Paleocene-Eocene time related to the subduction of the proposed Resurrection-Kula spreading ridge. In addition, we conclude that the reconstructed KFATmax negative age-elevation relationship is likely related to a long period of decreasing relief in the Tordrillo Mountains.

Ternary feldspar thermometry of Paleoproterozoic granulites from In-Ouzzal terrane (Western Hoggar, southern Algeria)

NASA Astrophysics Data System (ADS)

Benbatta, A.; Bendaoud, A.; Cenki-Tok, B.; Adjerid, Z.; Lacène, K.; Ouzegane, K.

2017-03-01

The In Ouzzal terrane in western Hoggar (Southern Algeria) preserves evidence of ultrahigh temperature (UHT) crustal metamorphism. It consists in Archean crustal units, composed of orthogneissic domes and greenstone belts, strongly remobilized during the Paleoproterozoic orogeny which was recognized as an UHT event (peak T > 1000 °C and P ≈ 9-12 kbar). This metamorphism was essentially defined locally in Al-Mg granulites, Al-Fe granulites and quartzites outcropping in the Northern part of the In Ouzzal terrane (IOT). In order to test and verify the regional spread of the UHT metamorphism in this terrane, ternary feldspar thermometry on varied rock types (Metanorite, Granulite Al-Mg and Orthogneiss) and samples that crop out in different zones of the In Ouzzal terrane. These rocks contain either perthitic, antiperthitic or mesoperthitic parageneses. Ternary feldspars used in this study have clearly a metamorphic origin. The obtained results combined with previous works show that this UHT metamorphism (>900 °C) affected the whole In Ouzzal crustal block. This is of major importance as for future discussion on the geodynamic context responsible for this regional UHT metamorphism.

Thermochronological evidence for polyphase post-rift reactivation in SE Brazil

NASA Astrophysics Data System (ADS)

Cogné, N.; Gallagher, K.; Cobbold, P. R.; Riccomini, C.

2012-04-01

The continental margin of SE Brazil shows good evidence for tectonic activity well after the break-up of Western Gondwana (see Cobbold et al., 2001 for a review). Additionally, SE Brazil ranks as an HEPM (high elevation passive margin), summits reaching 2800 m. To constrain the onshore evolution of the margin, especially during the Tertiary, we did a new thermochronological and structural study. After an initial regional study, during which we found additional evidence for a major phase of exhumation during the Late Cretaceous to Early Tertiary (Cogné et al., 2011), we focussed on a region that was clearly subject to Tertiary tectonics. This region includes the Tertiary Taubaté basin and the adjacent Serra do Mar and Serra da Mantiqueira. We used two thermochronolgical methods on the same samples, apatite fission tracks (AFT) and U-Th/He on apatite (AHe). AFT ages range from 129.3±4.3 Ma to 60.7±1.9 Ma with mean track lengths (MTL) from 14.31±0.24 μm to 11.41±0.23 μm, whereas AHe ages range from 519.6±16.6 to 10.1±0.1 Ma. A subset of AHe ages, selected on the basis of data consistency and geological arguments, has a smaller range (122.4±2.5 to 45.1±1.5 Ma). We have combined inverse and forward modelling to assess the range of acceptable thermal histories. Results of inverse modelling confirm our earlier study by showing a Late Cretaceous phase of cooling. Around the onshore Taubaté Basin, for a limited number of samples, another period of cooling occurred during the Early Tertiary, around the time when the basin formed. The inferred thermal histories for most of the samples also imply a later reheating, followed by a Neogene cooling. According to forward modelling, the evidence for reheating seems to be robust around the margins of the Taubaté Basin, but elsewhere the data cannot really discriminate between this and a less complex thermal history. However forward modelling and geologically independent information support the conclusion that the whole

Low-Temperature Thermochronology Investigation in Uruguay and Southernmost Brazil: Apatite (U-Th)/He Results

NASA Astrophysics Data System (ADS)

Machado, J. P.; Bicca, M. M.

2017-12-01

Low-temperature thermochronology has successfully allowed one to reveal exhumation histories of many orogenic belts across the Earth, and lately these techniques have been applied in cratonic regions. The present study aims to constrain thermal history and exhumation of the South Atlantic Passive Margin, between Uruguay and Southernmost Brazil, a region scarce of thermochronological data. This location has become relatively stable after the Neoproterozoic Brasiliano Orogeny, being more intensely disturbed by tectonics during the Gondwana Breakup and consequent opening of the Atlantic Ocean (Jurassic - Cretaceous). Both apatite and zircon (U-Th)/He methods are being applied on basement rocks, and since those have a long cooling history, radiation damage is expected to play an important role in crystal ages. A total of 25 samples were analyzed, and preliminary apatite (U-Th)/He results reveals unweighted sample ages ranging from Permian to Lower-Cretaceous in Southernmost Brazil, with a couple of outliers with Devonian - Carboniferous ages. In Uruguay results can be grouped in two different clusters: one of samples with Jurassic to Lower-Cretaceous ages, and another of Devonian to Permian ages. This wide range of results can be assign to variations in the uranium content of the grains, due the presence of inclusions, compositional zonation or substantial radiation damage of the crystalline lattice. In most cases, ages tend to increase with crystal eU content. No clear relationship between ages and tectonic terranes has been found so far, neither between ages and elevation, since the region does not have significant topographic variations. Younger ages are commonly found closer to the coastal region, possibly in response to the rift shoulders uplift during Gondwana breakup and further exhumation and denudation at higher rates. An anomalous concentration of older ages in the southern region of the Pelotas Batholith, close to the Brazil - Uruguay border, suggests a

Recent Progress in Graphite Intercalation Compounds for Rechargeable Metal (Li, Na, K, Al)-Ion Batteries.

PubMed

Xu, Jiantie; Dou, Yuhai; Wei, Zengxi; Ma, Jianmin; Deng, Yonghong; Li, Yutao; Liu, Huakun; Dou, Shixue

2017-10-01

Lithium-ion batteries (LIBs) with higher energy density are very necessary to meet the increasing demand for devices with better performance. With the commercial success of lithiated graphite, other graphite intercalation compounds (GICs) have also been intensively reported, not only for LIBs, but also for other metal (Na, K, Al) ion batteries. In this Progress Report, we briefly review the application of GICs as anodes and cathodes in metal (Li, Na, K, Al) ion batteries. After a brief introduction on the development history of GICs, the electrochemistry of cationic GICs and anionic GICs is summarized. We further briefly summarize the use of cationic GICs and anionic GICs in alkali ion batteries and the use of anionic GICs in aluminium-ion batteries. Finally, we reach some conclusions on the drawbacks, major progress, emerging challenges, and some perspectives on the development of GICs for metal (Li, Na, K, Al) ion batteries. Further development of GICs for metal (Li, Na, K, Al) ion batteries is not only a strong supplement to the commercialized success of lithiated-graphite for LIBs, but also an effective strategy to develop diverse high-energy batteries for stationary energy storage in the future.

Association of GBA Mutations and the E326K Polymorphism With Motor and Cognitive Progression in Parkinson Disease

PubMed Central

Davis, Marie Y.; Johnson, Catherine O.; Leverenz, James B.; Weintraub, Daniel; Trojanowski, John Q.; Chen-Plotkin, Alice; Van Deerlin, Vivianna M.; Quinn, Joseph F.; Chung, Kathryn A.; Peterson-Hiller, Amie L.; Rosenthal, Liana S.; Dawson, Ted M.; Albert, Marilyn S.; Goldman, Jennifer G.; Stebbins, Glenn T.; Bernard, Bryan; Wszolek, Zbigniew K.; Ross, Owen A.; Dickson, Dennis W.; Eidelberg, David; Mattis, Paul J.; Niethammer, Martin; Yearout, Dora; Hu, Shu-Ching; Cholerton, Brenna A.; Smith, Megan; Mata, Ignacio F.; Montine, Thomas J.; Edwards, Karen L.; Zabetian, Cyrus P.

2016-01-01

IMPORTANCE Parkinson disease (PD) is heterogeneous in symptom manifestation and rate of progression. Identifying factors that influence disease progression could provide mechanistic insight, improve prognostic accuracy, and elucidate novel therapeutic targets. OBJECTIVE To determine whether GBA mutations and the E326K polymorphism modify PD symptom progression. DESIGN, SETTING, AND PARTICIPANTS The entire GBA coding region was screened for mutations and E326K in 740 patients with PD enrolled at 7 sites from the PD Cognitive Genetics Consortium. Detailed longitudinal motor and cognitive assessments were performed with patients in the on state. MAIN OUTCOMES AND MEASURES Linear regression was used to test for an association between GBA genotype and motor progression, with the Movement Disorder Society–sponsored version of the Unified Parkinson’s Disease Rating Scale Part III (MDS-UPDRS III) score at the last assessment as the outcome and GBA genotype as the independent variable, with adjustment for levodopa equivalent dose, sex, age, disease duration, MDS-UPDRS III score at the first assessment, duration of follow-up, and site. Similar methods were used to examine the association between genotype and tremor and postural instability and gait difficulty (PIGD) scores. To examine the effect of GBA genotype on cognitive progression, patients were classified into those with conversion to mild cognitive impairment or dementia during the study (progression) and those without progression. The association between GBA genotype and progression status was then tested using logistic regression, adjusting for sex, age, disease duration, duration of follow-up, years of education, and site. RESULTS Of the total sample of 733 patients who underwent successful genotyping, 226 (30.8%) were women and 507 (69.2%) were men (mean [SD] age, 68.1 [8.8] years). The mean (SD) duration of follow-up was 3.0 (1.7) years. GBA mutations (β = 4.65; 95% CI, 1.72–7.58; P = .002), E326K (β = 3

Development of cataclastic foliation in deformation bands in feldspar-rich conglomerates of the Rio do Peixe Basin, NE Brazil

NASA Astrophysics Data System (ADS)

Nicchio, Matheus A.; Nogueira, Francisco C. C.; Balsamo, Fabrizio; Souza, Jorge A. B.; Carvalho, Bruno R. B. M.; Bezerra, Francisco H. R.

2018-02-01

In this work we describe the deformation mechanisms and processes that occurred during the evolution of cataclastic deformation bands developed in the feldspar-rich conglomerates of the Rio do Peixe Basin, NE Brazil. We studied bands with different deformation intensities, ranging from single cm-thick tabular bands to more evolved clustering zones. The chemical identification of cataclastic material within deformation bands was performed using compositional mapping in SEM images, EDX and XRD analyses. Deformation processes were identified by microstructural analysis and by the quantification of comminution intensity, performed using digital image processing. The deformation bands are internally non homogeneous and developed during five evolutionary stages: (1) moderate grain size reduction, grain rotation and grain border comminution; (2) intense grain size reduction with preferential feldspar fragmentation; (3) formation of subparallel C-type slip zones; (4) formation of S-type structures, generating S-C-like fabric; and (5) formation of C‧-type slip zones, generating well-developed foliation that resembles S-C-C‧-type structures in a ductile environment. Such deformation fabric is mostly imparted by the preferential alignment of intensely comminuted feldspar fragments along thin slip zones developed within deformation bands. These processes were purely mechanical (i.e., grain crushing and reorientation). No clays or fluids were involved in such processes.

Semi-volatiles at Mercury: Sodium (Na) and potassium (K)

NASA Technical Reports Server (NTRS)

Sprague, A.

1994-01-01

Several lines of evidence now suggest that Mercury is a planet rich in moderately-volatile elements such as Na and K. Recent mid-infrared spectral observations of Mercury's equatorial and mid-latitude region near 120 degrees mercurian longitude indicate the presence of plagioclase feldspar. Spectra of Mercury's surface exhibit spectral activity similar to labradorite (plagioclase feldspar with NaAlSi3O8: 30-50 percent) and bytownite (NaAlSi3O8: 10-30 percent). These surface studies were stimulated by the relatively large abundance of Na and K observed in Mercury's atmosphere. An enhanced column of K is observed at the longitudes of Caloris Basin and of the antipodal terrain. Extreme heating at these 'hot' longitudes and severe fracturing suffered from the large impact event could lead to enhanced outgassing from surface or subsurface materials. Alternatively, sputtering from a surface enriched in K could be the source of the observed enhancement. Recent microwave measurements of Mercury also give indirect evidence of a mercurian regolith less FeO-rich than the Moon. An anomalously high index of refraction derived from the whole-disk integrated phase curve of Danjon may also be indicative of surface sulfides contributing to a regolith that is moderately volatile-rich. The recent exciting observations of radar-bright spots at high latitudes also indicate that a substance of high volume scattering, like ice, is present in shadowed regions. Other radar-bright spots have been seen at locations of Na enhancements on the atmosphere. All combined, these pieces of evidence point to a planet that is not severely depleted in volatiles or semi-volatiles.

Episodic exhumation and relief growth in the Mont Blanc massif, Western Alps from numerical modelling of thermochronology data

NASA Astrophysics Data System (ADS)

Glotzbach, C.; van der Beek, P. A.; Spiegel, C.

2011-04-01

The Pliocene-Quaternary exhumational and topographic evolution of the European Alps and its potential climatic and tectonic controls remain a subject of controversy. Here, we apply inverse numerical thermal-kinematic modelling to a spatially dense thermochronological dataset (apatite fission-track and (U-Th)/He) of both tunnel and surface samples across the Mont Blanc massif in the Western Alps, complemented by new zircon fission-track data, in order to better quantify its Neogene exhumation and relief history. Age-elevation relationships and modelling results show that an episodic exhumation scenario best fits the data. Initiation of exhumation in the Mont Blanc massif at 22 ± 2 Ma with a rate of 0.8 ± 0.15 km/Myr is probably related to NW-directed thrusting during nappe emplacement. Exhumation rates decrease at 6 ± 2 Ma to values of 0.15 ± 0.65 km/Myr, which we interpret to be the result of a general decrease in convergence rates and/or extensive exposure of less erodible crystalline basement rocks from below more easily erodible Mesozoic sediments. Finally, local exhumation rates increase up to 2.0 ± 0.6 km/Myr at 1.7 ± 0.8 Ma. Modelling shows that this recent increase in local exhumation can be explained by valley incision and the associated increase in relief at 0.9 ± 0.8 Ma, leading to erosional unloading, isostatic rebound and additional rock uplift and exhumation. Given the lack of tectonic activity as evidenced by constant thermochronological ages along the tunnel transect, we suggest that the final increase in exhumation and relief in the Mont Blanc massif is the result of climate change, with the initiation of mid-Pleistocene glaciations leading to rapid valley incision and related local exhumation.

Dating Last Interglacial Coastal Systems Using New Feldspar Luminescence Technologies

NASA Astrophysics Data System (ADS)

Lamothe, M.

2017-12-01

The recent explosion in new luminescence dating technologies offers new opportunities to explore Quaternary marine coastal facies and landforms. However, tectonic and climatic processes controlling the development of Pleistocene coastal lithosomes are commonly obscured by their poorly constrained geological age. Luminescence dating of feldspar probes one order of magnitude deeper into geological time than radiocarbon and more than 5 times the current age range of quartz optically-stimulated luminescence, routinely used in luminescence dating. However, feldspar luminescence stimulated by infrared photons (eg IRSL) is hampered by anomalous fading. Successful correction methods developed by us over the last 15 years did produce sound chronologies but the fading-corrected ages carried large uncertainties. New approaches initiated by other laboratories, mainly in Europe, have isolated high temperature post-IRSL luminescence as this signal seems to be only slightly affected by fading. However, the gain in stability seems to be lessened due to bleachibility issues, generating age overestimations. We developed a novel protocol known as post-isothermal IRSL dating (Pit-IR) that focuses on a dual system of luminescence signals, probing low (50C) and medium (225C) temperature IRSL signals following isothermal treatments of various intensities. These protocols have been tested on Last interglacial coastal sediments in strikingly different GIA contexts along the Atlantic coastal areas of SE USA as well as from Morocco, Brazil and LIG sites in the Mediterranean basin. A systematic analysis of these results would suggest that a) falling-stages sequences are more commonly preserved as the OSL/IRSL ages are preferentially dating from the end of the MIS5e high stand and b) MIS5a marine sediments may be detectable away from areas generally thought to be affected by peripheral bulge collapse.

Trace-element and Nd-isotope systematics in detrital apatite of the Po river catchment: Implications for provenance discrimination and the lag-time approach to detrital thermochronology

NASA Astrophysics Data System (ADS)

Malusà, Marco G.; Wang, Jiangang; Garzanti, Eduardo; Liu, Zhi-Chao; Villa, Igor M.; Wittmann, Hella

2017-10-01

Detrital thermochronology is often employed to assess the evolutionary stage of an entire orogenic belt using the lag-time approach, i.e., the difference between the cooling and depositional ages of detrital mineral grains preserved in a stratigraphic succession. The impact of different eroding sources to the final sediment sink is controlled by several factors, including the short-term erosion rate and the mineral fertility of eroded bedrock. Here, we use apatite fertility data and cosmogenic-derived erosion rates in the Po river catchment (Alps-Apennines) to calculate the expected percentage of apatite grains supplied to the modern Po delta from the major Alpine and Apenninic eroding sources. We test these predictions by using a cutting-edge dataset of trace-element and Nd-isotope signatures on 871 apatite grains from 14 modern sand samples, and we use apatite fission-track data to validate our geochemical approach to provenance discrimination. We found that apatite grains shed from different sources are geochemically distinct. Apatites from the Lepontine dome in the Central Alps show relative HREE enrichment, lower concentrations in Ce and U, and higher 147Sm/144Nd ratios compared to apatites derived from the External Massifs. Derived provenance budgets point to a dominant apatite contribution to the Po delta from the high-fertility Lepontine dome, consistent with the range independently predicted from cosmonuclide and mineral-fertility data. Our results demonstrate that the single-mineral record in the final sediment sink can be largely determined by high-fertility source rocks exposed in rapidly eroding areas within the drainage. This implies that the detrital thermochronology record may reflect processes affecting relatively small parts of the orogenic system under consideration. A reliable approach to lag-time analysis would thus benefit from an independent provenance discrimination of dated mineral grains, which may allow to proficiently reconsider many

Time-temperature evolution of microtextures and contained fluids in a plutonic alkali feldspar during heating

NASA Astrophysics Data System (ADS)

Parsons, Ian; Fitz Gerald, John D.; Lee, James K. W.; Ivanic, Tim; Golla-Schindler, Ute

2010-08-01

Microtextural changes brought about by heating alkali feldspar crystals from the Shap granite, northern England, at atmospheric pressure, have been studied using transmission and scanning electron microscopy. A typical unheated phenocryst from Shap is composed of about 70 vol% of tweed orthoclase with strain-controlled coherent or semicoherent micro- and crypto-perthitic albite lamellae, with maximum lamellar thicknesses <1 μm. Semicoherent lamellae are encircled by nanotunnel loops in two orientations and cut by pull-apart cracks. The average bulk composition of this microtexture is Ab27.6Or71.8An0.6. The remaining 30 vol% is deuterically coarsened, microporous patch and vein perthite composed of incoherent subgrains of oligoclase, albite and irregular microcline. The largest subgrains are ~3 μm in diameter. Heating times in the laboratory were 12 to 6,792 h and T from 300°C into the melting interval at 1,100°C. Most samples were annealed at constant T but two were heated to simulate an 40Ar/39Ar step-heating schedule. Homogenisation of strain-controlled lamellae by Na↔K inter-diffusion was rapid, so that in all run products at >700°C, and after >48 h at 700°C, all such regions were essentially compositionally homogeneous, as indicated by X-ray analyses at fine scale in the transmission electron microscope. Changes in lamellar thickness with time at different T point to an activation energy of ~350 kJmol-1. A lamella which homogenised after 6,800 h at 600°C, therefore, would have required only 0.6 s to do so in the melting interval at 1,100°C. Subgrains in patch perthite homogenised more slowly than coherent lamellae and chemical gradients in patches persisted for >5,000 h at 700°C. Homogenisation T is in agreement with experimentally determined solvi for coherent ordered intergrowths, when a 50-100°C increase in T for An1 is applied. Homogenisation of lamellae appears to proceed in an unexpected manner: two smooth interfaces, microstructurally sharp

Accumulated phenocrysts and origin of feldspar porphyry in the Chanho area, western Yunnan, China

NASA Astrophysics Data System (ADS)

Xu, Xing-Wang; Jiang, Neng; Yang, Kai; Zhang, Bao-Lin; Liang, Guang-He; Mao, Qian; Li, Jin-Xiang; Du, Shi-Jun; Ma, Yu-Guang; Zhang, Yong; Qin, Ke-Zhang

2009-12-01

The No. 1 feldspar porphyry in the Chanho area, western Yunnan, China is characterized by the development of deformed glomeroporphyritic aggregates (GA) that contain diagnostic gravity settling textures. These textures include interlocking curved grain boundaries caused by compaction, bent twins, and arch-like structures. The GAs are accumulated phenocrysts (AP) and antecrysts. The unstable textural configurations such as extensive penetrative microfractures that are restricted within the AP and fractured cores of zircon grains, all suggest that the GAs are transported fragments of fractured cumulates that formed in a pre-emplacement magma chamber rather than form in situ at the current intrusion site. Compositions of minerals and melt as represented by different mineral aggregates formed at various stages of the magmatic process and their relations to the composition of porphyry bodies in the Chanho area indicate that the porphyritic melt for the No. 1 feldspar porphyry experienced two stages of melt mixing. Pulses of potassic melt flowed into a pre-emplacement magma chamber and mixed with crystallizing dioritic magma containing phenocrysts resulted in the first hybrid alkaline granitic melt. The mixing caused denser phenocrysts to settle and aggregate to form cumulates. Secondly, new dioritic melt was injected into the magma chamber and was mixed with the previously formed hybrid alkaline granitic melt to produce syenitic melt. Geochron data, including U-Pb age of zircon and 39Ar/ 40Ar age of hornblende and oligoclase phenocrysts, indicate that hornblende and oligoclase phenocrysts, as well as the core of zircon grains, were antecrysts that formed in a number of crystallization events between 36.3 and 32.78 Ma. Gravity settling of phenocrysts took place at about 33.1 to 32.78 Ma and melts with deformed GAs were transported upwards and emplaced into the current site at 32 Ma. Results of this research indicate that the No. 1 feldspar porphyry was a shallow

Middle Miocene Hotspot-Related Uplift, Exhumation, and Extension north of the Snake River Plain: Evidence from Apatite (U-Th)/He Thermochronology

NASA Astrophysics Data System (ADS)

Foster, D. A.; Vogl, J.; Min, K. K.; Bricker, A.; Gelato, P. W.

2013-12-01

Miocene mean ages suggest that exhumation is now reaching to depths of the Miocene He partial retention zone. Miocene-Pliocene erosional exhumation of the South Snowy block is partly attributed to integration of the Yellowstone River drainage system and incision of the Yellowstone Canyon. The thermochronology of these two locations shows that localized uplift, exhumation and incision occurred progressively as NA moved over the hot spot, but that exhumation is not uniform and not always controlled by Neogene basin-bounding faults. This suggests a causal relationship between hotspot processes and exhumation through potential contributions of flexure and mantle dynamics to uplift, and changes in drainage networks and base-level associate with uplift and/or extension.

Feldspar Variability in Northwest Africa 7034

NASA Technical Reports Server (NTRS)

Santos, A. R.; Lewis, J. A.; Agee, C. B.; Humayun, M.; McCubbin, F. M.; Shearer, C. K.

2017-01-01

The martian meteorite Northwest Africa 7034 (and pairings) is a breccia that provides important information about the rocks and processes of the martian crust (e.g., 1-3). Additional information can be gleaned from the components of the breccia. These components, specifically those designated as clasts, record the history of their parent rock (i.e., the rock that has been physically broken down to produce the clasts). In order to study these parent rocks, we must first determine which clasts within the breccia are de-rived from the same parent. Previous studies have be-gun this process (e.g., 4), but the search for genetic linkages between clasts has not integrated clasts with different grain sizes. We begin to take this approach here, incorporating igneous-textured clasts with both fine and coarse mineral grains. In NWA 7034, almost all materials (clasts and breccia matrix) are composed of the same mineral assemblages (feldspar, pyroxene, Fe-Ti oxides, apatite) with largely the same mineral compositions [1, 4-6]. Bulk breccia Sm-Nd systematics define a single isochron [7]. These observations are consistent with a majority of the components within NWA 7034 originating from the same geochemical source and crystallizing at roughly the same time.

Evidence of Variscan and Alpine tectonics in the structural and thermochronological record of the central Serbo-Macedonian Massif (south-eastern Serbia)

NASA Astrophysics Data System (ADS)

Antić, Milorad D.; Kounov, Alexandre; Trivić, Branislav; Spikings, Richard; Wetzel, Andreas

2017-07-01

The Serbo-Macedonian Massif (SMM) represents a composite crystalline belt within the Eastern European Alpine orogen, outcropping from the Pannonian basin in the north to the Aegean Sea in the south. The central parts of this massif (south-eastern Serbia) consist of the medium- to high-grade Lower Complex and the low-grade Vlasina Unit. Outcrop- and micro-scale ductile structures in this area document three major stages of ductile deformation. The earliest stage D1 is related to isoclinal folding, commonly preserved as up to decimetre-scale quartz-feldspar rootless fold hinges. D2 is associated with general south-eastward tectonic transport and refolding of earlier structures into recumbent metre- to kilometre-scale tight to isoclinal folds. Stages D1 and D2 could not be temporally separated and probably took place in close sequence. The age of these two ductile deformation stages was constrained to the Variscan orogeny based on indirect geological evidence (i.e. ca. 408-ca. 328). During this period, the SMM was involved in a transpressional amalgamation of the western and eastern parts of the Galatian super-terrane and subsequent collision with Laurussia. Outcrop-scale evidence of the final stage D3 is limited to spaced and crenulation cleavage, which are probably related to formation of large-scale open upright folds as reported previously. 40Ar/39Ar thermochronology was applied on hornblende, muscovite, and biotite samples in order to constrain the age of tectonothermal events and activity along major shear zones. These 40Ar/39Ar data reveal three major cooling episodes affecting the central SMM. Cooling below greenschist facies conditions in the western part of the Vlasina Unit took place in a post-orogenic setting (extensional or transtensional) in the early Permian (284 ± 1 Ma). The age of activity along the top-to-the-west shear zone formed within the orthogneiss in the Božica area of the Vlasina Unit was constrained to Middle Triassic (246 ± 1 Ma). This

Near-liquidus growth of feldspar spherulites in trachytic melts: 3D morphologies and implications in crystallization mechanisms

NASA Astrophysics Data System (ADS)

Arzilli, Fabio; Mancini, Lucia; Voltolini, Marco; Cicconi, Maria Rita; Mohammadi, Sara; Giuli, Gabriele; Mainprice, David; Paris, Eleonora; Barou, Fabrice; Carroll, Michael R.

2015-02-01

The nucleation and growth processes of spherulitic alkali feldspar have been investigated in this study through X-ray microtomography and electron backscatter diffraction (EBSD) data. Here we present the first data on Shape Preferred Orientation (SPO) and Crystal Preferred Orientation (CPO) of alkali feldspar within spherulites. The analysis of synchrotron X-ray microtomography and EBSD datasets allowed us to study the morphometric characteristics of spherulites in trachytic melts in quantitative fashion, highlighting the three-dimensional shape, preferred orientation, branching of lamellae and crystal twinning, providing insights about the nucleation mechanism involved in the crystallization of the spherulites. The nucleation starts with a heterogeneous nucleus (pre-existing crystal or bubble) and subsequently it evolves forming "bow tie" morphologies, reaching radially spherulitic shapes in few hours. Since each lamella within spherulite is also twinned, these synthetic spherulites cannot be considered as single nuclei but crystal aggregates originated by heterogeneous nucleation. A twin boundary may have a lower energy than general crystal-crystal boundaries and many of the twinned grains show evidence of strong local bending which, combined with twin plane, creates local sites for heterogeneous nucleation. This study shows that the growth rates of the lamellae (10- 6-10- 7 cm/s) in spherulites are either similar or slightly higher than that for single crystals by up to one order of magnitude. Furthermore, the highest volumetric growth rates (10- 11-10- 12 cm3/s) show that the alkali feldspar within spherulites can grow fast reaching a volumetric size of ~ 10 μm3 in 1 s.

Recent Progress in Graphite Intercalation Compounds for Rechargeable Metal (Li, Na, K, Al)‐Ion Batteries

PubMed Central

Xu, Jiantie; Dou, Yuhai; Wei, Zengxi; Li, Yutao; Liu, Huakun; Dou, Shixue

2017-01-01

Abstract Lithium‐ion batteries (LIBs) with higher energy density are very necessary to meet the increasing demand for devices with better performance. With the commercial success of lithiated graphite, other graphite intercalation compounds (GICs) have also been intensively reported, not only for LIBs, but also for other metal (Na, K, Al) ion batteries. In this Progress Report, we briefly review the application of GICs as anodes and cathodes in metal (Li, Na, K, Al) ion batteries. After a brief introduction on the development history of GICs, the electrochemistry of cationic GICs and anionic GICs is summarized. We further briefly summarize the use of cationic GICs and anionic GICs in alkali ion batteries and the use of anionic GICs in aluminium‐ion batteries. Finally, we reach some conclusions on the drawbacks, major progress, emerging challenges, and some perspectives on the development of GICs for metal (Li, Na, K, Al) ion batteries. Further development of GICs for metal (Li, Na, K, Al) ion batteries is not only a strong supplement to the commercialized success of lithiated‐graphite for LIBs, but also an effective strategy to develop diverse high‐energy batteries for stationary energy storage in the future. PMID:29051856

Cenozoic erosion of the Transantarctic Mountains: A source-to-sink thermochronological study

NASA Astrophysics Data System (ADS)

Zattin, M.; Pace, D.; Andreucci, B.; Rossetti, F.; Talarico, F. M.

2014-09-01

The formation of the Transantarctic Mountains (TAM) is strictly related to the evolution of the West Antarctic Rift system, but the timing of their exhumation is still not fully assessed. In this work, we provide new apatite fission-track data collected on the region between the Royal Society Range and the Britannia Range. Cooling ages are late Eocene-Oligocene in the center of the region but they get older both northwards and southwards. We infer that exhumation was strictly controlled by TAM-parallel fault strands that were active after the Oligocene. The Royal Society Range and the Britannia Range represent transition zones corresponding to transverse structures, probably inherited from early basement crustal discontinuities and reactivated as transfer regions during rift propagation. The exhumation of the investigated region has been then modeled and predicted thermochronological ages have been compared with detrital data from the Miocene sedimentary succession drilled in the Victoria Land Basin. Results indicate that this sector of the TAM is the most probable candidate for the source of sediments and that during the Neogene 3 km (but up to 5 km) of rocks was exhumed.

Increased expression of HERG K+ channels contributes to myelodysplastic syndrome progression and displays correlation with prognosis stratification.

PubMed

Lu, Li; Du, Wen; Liu, Wei; Guo, Dongmei; He, Xiaoqi; Li, Huiyu

2016-12-01

Human ether-a-go-go-related gene (HERG) K + channels are shown to be aberrantly expressed in a variety of cancer cells where they play roles in contributing to cancer progression. Myelodysplastic syndromes (MDS) are a group of clinical heterogeneous disorders characterized by bone marrow failure and dysplasia of blood cells. However, the involvement of HERG K + channels in MDS development is poorly understood. The expression of HERG K + channels in untreated MDS, acute myeloid leukemia (AML) patients and the control group was detected by flow cytometry. The roles of HERG K + channels in regulation of SKM-1 cell proliferation, apoptosis, and cell cycle were determined by CCK-8 assay and flow cytometry, respectively. We found that expression of HERG K + channels in MDS patients was significantly higher than controls and was lower than AML. Percentage of HERG K + channels on CD34+CD38- cells gradually increased from controls to high-grade MDS subtypes. And HERG K + channel levels showed an ascending tendency from low-risk to high-risk MDS group. In addition, the CCK-8 assay, apoptosis and cell cycle analysis were performed and showed that blockage of HERG K + channels decreased the proliferation of MDS cells but rarely had effects on cell apoptosis and cell cycle distribution. Our study demonstrated that HERG K + channels might be a potential tumor marker of MDS. These channels were likely to contribute to MDS progression and were helpful for predicting prognosis of MDS. Inhibition of HERG K + channels might be a novel therapeutic measure for MDS.

Muscovite-Dehydration Melting: A Textural Study of a Key Reaction in Transforming Continental Margin Strata Into a Migmatitic Orogenic Core

NASA Astrophysics Data System (ADS)

Dyck, B. J.; St Onge, M. R.; Waters, D. J.; Searle, M. P.

2015-12-01

Metamorphosed continental margin sedimentary sequences, which comprise the dominant tectonostratigraphic assemblage exposed in orogenic hinterlands, are crucial to understanding the architecture and evolution of collisional mountain belts. This study explores the textural effect of anatexis in amphibolite-grade conditions and documents the mineral growth mechanisms that control nucleation and growth of K-feldspar, sillimanite and silicate melt. The constrained textural evolution follows four stages: 1) Nucleation - K-feldspar is documented to nucleate epitaxially on isomorphic plagioclase in quartzofeldspathic (psammitic) domains, whereas sillimanite nucleates in the Al-rich (pelitic) domain, initially on [001] mica planes. The first melt forms at the site of muscovite breakdown. 2) Chemically driven growth - In the quartzofeldspathic domain, K-feldspar progressively replaces plagioclase by a K+ - Na+ cation transfer reaction, driven by the freeing of muscovite-bound K+ during breakdown of the mica. Sillimanite forms intergrowths with the remaining hydrous melt components, contained initially in ovoid clots. 3) Merge and coarsening - With an increase in pressure, melt and sillimanite migrate away from clots along grain boundaries. A melt threshold is reached once the grain-boundary network is wetted by melt, increasing the length-scale of diffusion, resulting in grain boundary migration and grain-size coarsening. The melt threshold denotes the transition to an open-system on the lithology scale, where melt is a transient phase. 4) Residual melt crystallization - Residual melt crystallizes preferentially on existing peritectic grains as anatectic quartz, plagioclase, and K-feldspar. As the system cools and closes, grain growth forces melt into the intersections of grain-boundaries, recognized as irregular shaped melt films, or as intergrowths of the volatile-rich phases (i.e. Tur-Ms-Ap). In the Himalayan metamorphic core these processes result in the formation of

Crustal-scale alpine tectonic evolution of the western Pyrenees - eastern Cantabrian Mountains (N Spain) from integration of structural data, low-T thermochronology and seismic constraint

NASA Astrophysics Data System (ADS)

DeFelipe, I.; Pedreira, D.; Pulgar, J. A.; Van der Beek, P.; Bernet, M.; Pik, R.

2017-12-01

The Pyrenean-Cantabrian Mountain belt extends in an E-W direction along the northern border of Spain and resulted from the convergence between the Iberian and European plates from the Late Cretaceous to the Miocene, in the context of the Alpine orogeny. The main aim of this work is to characterize the tectonic evolution at a crustal-scale of the transition zone from the Pyrenees to the Cantabrian Mountains, in the eastern Basque-Cantabrian Basin (BCB). We integrate structural work, thermochronology (apatite fission track and zircon (U-Th)/He) and geophysical information (shallow seismic reflection profiles, deep seismic refraction/wide-angle reflection profiles and seismicity distribution) to propose an evolutionary model since the Jurassic to the present. During the Albian, hyperextension related to the opening of the Bay of Biscay yielded to mantle unroofing to the base of the BCB. This process was favored by a detachment fault that connected the mantle in its footwall with the base of a deep basin in its hanging wall. During this process, the basin experienced HT metamorphism and fluid circulation caused the serpentinization of the upper part of the mantle. There is no evidence of seafloor mantle exhumation before the onset of the Alpine orogeny. The thermochronological study points to a N-vergent phase of contractional deformation in the late Eocene represented by the thin-skinned Leiza fault system followed in the early Oligocene by the S-vergent, thick-skinned, Ollín thrust. Exhumation rates for the late Eocene-early Oligocene are of 0.2-0.7 km/Myr. After that period, deformation continues southwards until the Miocene. The crustal-scale structure resultant of the Alpine orogeny consists of an Iberian plate that subducts below the European plate. The crust is segmented into four blocks separated by three S-vergent crustal faults inherited from the Cretaceous extensional period. The P-wave velocities in this transect show anomalous values (7.4 km/s) in the

Low-Temperature Thermochronology Of Rio Grande Rise, South Atlantic Ocean

NASA Astrophysics Data System (ADS)

Doranti Tiritan, Carolina; Hackspacher, Peter Christian; Carina Siqueira Ribeiro, Marli

2017-04-01

The Rio Grande Rise (RGR) is a submerse plateau 1500 km distant from Brazilian coast, on Ocidental South Atlantic Ocean. It is interpreted as a great igneous province connected in the past with the Walvis Ridge on the Oriental South Atlantic. First hypothesis about their genesis rely on the great magmatic activity associated with the Tristao Cunha-Gough plume. However, recently, more evidences suggest that the RGR is a fragment of continental crust that could have been separated from the São Paulo Plateau during the South Atlantic opening process. New seismic data and in situ observation have reinforced this interpretation, which has been created more significantly questioning about the from the continental break has occurred, as well on how was the role and genesis of the hot spots that were manifested through the plume. This work will be presenting thermochronological data from RGR rocks collected by Brazilian Geological Service (CPRM) and Bremen IODP repository. We intend to have more data that will allow to reconstruct the processes of subsidence and rock uplift that could have occurred during Cretaceous and Eocene. It will be possible calculate exhumation rates and correlate them or not to the formation of the oceanic crust, time as an island and if the velocity of the subsidence. This work is part of a major project called "Elevação do Alto Rio Grande, Atlantico Sul Ocidental", financed by IODP/CAPES.

Novel calibration for LA-ICP-MS-based fission-track thermochronology

NASA Astrophysics Data System (ADS)

Soares, C. J.; Guedes, S.; Hadler, J. C.; Mertz-Kraus, R.; Zack, T.; Iunes, P. J.

2014-01-01

We present a novel age-equation calibration for fission-track age determinations by laser ablation inductively coupled plasma mass spectrometry. This new calibration incorporates the efficiency factor of an internal surface, [ ηq]is, which is obtained by measuring the projected fission-track length, allowing the determination of FT ages directly using the recommended spontaneous fission decay constant. Also, the uranium concentrations in apatite samples are determined using a Durango (Dur-2, 7.44 μg/g U) crystal and a Mud Tank (MT-7, 6.88 μg/g U) crystal as uranium reference materials. The use of matrix-matched reference materials allows a reduction in the uncertainty of the uranium measurements to those related to counting statistics, which are ca. 1 % taking into account that no extra source of uncertainty has to be considered. The equations as well as the matrix-matched reference materials are evaluated using well-dated samples from Durango, Fish Canyon Tuff, and Limberg as unknown samples. The results compare well with their respective published ages determined through other dating methods. Additionally, the results agree with traditional fission-track ages using both the zeta approach and the absolute approach, suggesting that the calibration presented in this work can be robustly applied in geological context. Furthermore, considering that fission-track ages can be determined without an age standard sample, the fission-track thermochronology approach presented here is assumed to be a valuable dating tool.

How the Emitted Size Distribution and Mixing State of Feldspar Affect Ice Nucleating Particles in a Global Model

NASA Astrophysics Data System (ADS)

Perlwitz, J. P.; Fridlind, A. M.; Knopf, D. A.; Miller, R. L.; Pérez García-Pando, C.

2017-12-01

The effect of aerosol particles on ice nucleation and, in turn, the formation of ice and mixed phase clouds is recognized as one of the largest sources of uncertainty in climate prediction. We apply an improved dust mineral specific aerosol module in the NASA GISS Earth System ModelE, which takes into account soil aggregates and their fragmentation at emission as well as the emission of large particles. We calculate ice nucleating particle concentrations from K-feldspar abundance for an active site parameterization for a range of activation temperatures and external and internal mixing assumption. We find that the globally averaged INP concentration is reduced by a factor of two to three, compared to a simple assumption on the size distribution of emitted dust minerals. The decrease can amount to a factor of five in some geographical regions. The results vary little between external and internal mixing and different activation temperatures, except for the coldest temperatures. In the sectional size distribution, the size range 2-4 μm contributes the largest INP number.

How the Emitted Size Distribution and Mixing State of Feldspar Affect Ice Nucleating Particles in a Global Model

NASA Technical Reports Server (NTRS)

Perlwitz, Jan P.; Fridlind, Ann M.; Knopf, Daniel A.; Miller, Ron L.; García-Pando, Carlos Perez

2017-01-01

The effect of aerosol particles on ice nucleation and, in turn, the formation of ice and mixed phase clouds is recognized as one of the largest sources of uncertainty in climate prediction. We apply an improved dust mineral specific aerosol module in the NASA GISS Earth System ModelE, which takes into account soil aggregates and their fragmentation at emission as well as the emission of large particles. We calculate ice nucleating particle concentrations from K-feldspar abundance for an active site parameterization for a range of activation temperatures and external and internal mixing assumption. We find that the globally averaged INP concentration is reduced by a factor of two to three, compared to a simple assumption on the size distribution of emitted dust minerals. The decrease can amount to a factor of five in some geographical regions. The results vary little between external and internal mixing and different activation temperatures, except for the coldest temperatures. In the sectional size distribution, the size range 24 micrometer contributes the largest INP number.

β4-Integrin/PI3K Signaling Promotes Tumor Progression through the Galectin-3-N-Glycan Complex.

PubMed

Kariya, Yukiko; Oyama, Midori; Hashimoto, Yasuhiro; Gu, Jianguo; Kariya, Yoshinobu

2018-06-01

Malignant transformation is associated with aberrant N -glycosylation, but the role of protein N -glycosylation in cancer progression remains poorly defined. β4-integrin is a major carrier of N -glycans and is associated with poor prognosis, tumorigenesis, and metastasis. Here, N -glycosylation of β4-integrin contributes to the activation of signaling pathways that promote β4-dependent tumor development and progression. Increased expression of β1,6GlcNAc-branched N -glycans was found to be colocalized with β4-integrin in human cutaneous squamous cell carcinoma tissues, and that the β1,6GlcNAc residue was abundant on β4-integrin in transformed keratinocytes. Interruption of β1,6GlcNAc-branching formation on β4-integrin with the introduction of bisecting GlcNAc by N -acetylglucosaminyltransferase III overexpression was correlated with suppression of cancer cell migration and tumorigenesis. N -Glycan deletion on β4-integrin impaired β4-dependent cancer cell migration, invasion, and growth in vitro and diminished tumorigenesis and proliferation in vivo The reduced abilities of β4-integrin were accompanied with decreased phosphoinositol-3 kinase (PI3K)/Akt signals and were restored by the overexpression of the constitutively active p110 PI3K subunit. Binding of galectin-3 to β4-integrin via β1,6GlcNAc-branched N -glycans promoted β4-integrin-mediated cancer cell adhesion and migration. In contrast, a neutralizing antibody against galectin-3 attenuated β4-integrin N -glycan-mediated PI3K activation and inhibited the ability of β4-integrin to promote cell motility. Furthermore, galectin-3 knockdown by shRNA suppressed β4-integrin N -glycan-mediated tumorigenesis. These findings provide a novel role for N -glycosylation of β4-integrin in tumor development and progression, and the regulatory mechanism for β4-integrin/PI3K signaling via the galectin-3- N -glycan complex. Implications: N -Glycosylation of β4-integrin plays a functional role in promoting

Filling material for a buried cavity in a collapse area using light-weighted foam and active feldspar

NASA Astrophysics Data System (ADS)

Cho, Jin Woo; Lee, Ju-hyoung; Kim, Sung-Wook; Choi, Eun-Kyeong

2017-04-01

Concrete which is generally used as filling material for a buried cavity has very high strength but significantly high self-load is considered its disadvantage. If it is used as filling material, the second collapse due to additional load, causing irreversible damage. If light-weighted foam and active feldspar are used to solve this problem, the second collapse can be prevented by reducing of self-load of filling material. In this study, the specimen was produced by mixing light-weighted foam, active feldspar and cement, and changes in the density, unconfined compressive strength and hydraulic conductivity were analyzed. Using the light-weighted foam could enable the adjustment of density of specimen between 0.5 g/cm3 and 1.7 g/cm3, and if the mixing ratio of the light-weighted foam increases, the specimen has more pores and smaller range of cross-sectional area. It is confirmed that it has direct correlation with the density, and if the specimen has more pores, the density of the specimen is lowered. The density of the specimen influences the unconfined compressive strength and the hydraulic conductivity, and it was also confirmed that the unconfined compressive strength could be adjusted between 0.6 MPa and 8 MPa and the hydraulic conductivity could be adjusted between 10-9cm/sec and 10-3cm/sec. These results indicated that we can adjust unconfined compressive strength and hydraulic conductivity of filling materials by changing the mixing amount of lightweight-weighted foam according to the requirements of the field condition. Keywords: filling material, buried cavity, light-weighted foam, feldspar Acknowledgement This research was supported by a Grant from a Strategic Research Project (Horizontal Drilling and Stabilization Technologies for Urban Search and Rescue (US&R) Operation) funded by the Korea Institute of Civil Engineering and Building Technology.

Photoionization of radiation-induced traps in quartz and alkali feldspars.

PubMed

Hütt, G; Jaek, I; Vasilchenko, V

2001-01-01

For the optimization of luminescence dating and dosimetry techniques on the basis of the optically stimulated luminescence, the stimulation spectra of quartz and alkali feldspars were measured in the spectral region of 250-1100 nm using optically stimulated afterglow. Optically stimulated luminescence in all studied spectral regions is induced by the same kind of deep traps, that produce thermoluminescence in the regions of palaeodosimetric peaks for both minerals. The mechanism for photoionization of deep traps was proposed as being due to delocalization of the excited state of the corresponding lattice defects. The excited state overlaps the zone states; i.e. is situated in the conduction band. Because of the high quantum yield of deep electron trap ionization in the UV spectral region, the present aim was to study the possibility of using UV-stimulation for palaeodose reconstruction.

Association between circulating vitamin K1 and coronary calcium progression in community-dwelling adults: the Multi-Ethnic Study of Atherosclerosis

USDA-ARS?s Scientific Manuscript database

While animal studies found vitamin K treatment reduced vascular calcification, human data are limited. Using a case-cohort design, we determined the association between vitamin K status and coronary artery calcium (CAC) progression in the Multi-ethnic Study of Atherosclerosis. Serum phylloquinone (v...

Global analysis of H3K27me3 as an epigenetic marker in prostate cancer progression.

PubMed

Ngollo, Marjolaine; Lebert, Andre; Daures, Marine; Judes, Gaelle; Rifai, Khaldoun; Dubois, Lucas; Kemeny, Jean-Louis; Penault-Llorca, Frederique; Bignon, Yves-Jean; Guy, Laurent; Bernard-Gallon, Dominique

2017-04-12

H3K27me3 histone marks shape the inhibition of gene transcription. In prostate cancer, the deregulation of H3K27me3 marks might play a role in prostate tumor progression. We investigated genome-wide H3K27me3 histone methylation profile using chromatin immunoprecipitation (ChIP) and 2X400K promoter microarrays to identify differentially-enriched regions in biopsy samples from prostate cancer patients. H3K27me3 marks were assessed in 34 prostate tumors: 11 with Gleason score > 7 (GS > 7), 10 with Gleason score ≤ 7 (GS ≤ 7), and 13 morphologically normal prostate samples. Here, H3K27me3 profiling identified an average of 386 enriched-genes on promoter regions in healthy control group versus 545 genes in GS ≤ 7 and 748 genes in GS > 7 group. We then ran a factorial discriminant analysis (FDA) and compared the enriched genes in prostate-tumor biopsies and normal biopsies using ANOVA to identify significantly differentially-enriched genes. The analysis identified ALG5, EXOSC8, CBX1, GRID2, GRIN3B, ING3, MYO1D, NPHP3-AS1, MSH6, FBXO11, SND1, SPATS2, TENM4 and TRA2A genes. These genes are possibly associated with prostate cancer. Notably, the H3K27me3 histone mark emerged as a novel regulatory mechanism in poor-prognosis prostate cancer. Our findings point to epigenetic mark H3K27me3 as an important event in prostate carcinogenesis and progression. The results reported here provide new molecular insights into the pathogenesis of prostate cancer.

Electron microprobe evaluation of terrestrial basalts for whole-rock K-Ar dating

USGS Publications Warehouse

Mankinen, E.A.; Brent, Dalrymple G.

1972-01-01

Four basalt samples for whole-rock K-Ar dating were analyzed with an electron microprobe to locate potassium concentrations. Highest concentrations of potassium were found in those mineral phases which were the last to crystallize. The two reliable samples had potassium concentrated in fine-grained interstitial feldspar and along grain boundaries of earlier formed plagioclase crystals. The two unreliable samples had potassium concentrated in the glassy matrix, demonstrating the ineffectiveness of basaltic glass as a retainer of radiogenic argon. In selecting basalt samples for whole-rock K-Ar dating, particular emphasis should be placed on determining the nature and condition of the fine-grained interstitial phases. ?? 1972.

Reconciling Conflicting Geologic and Thermochronologic Interpretations Via Multiple Apatite Thermochronometers (AHe, AFT, and 4He/3He): 6 Ma Incision of the Westernmost Grand Canyon

NASA Astrophysics Data System (ADS)

Winn, C.; Karlstrom, K. E.; Shuster, D. L.; Kelley, S.; Fox, M.

2017-12-01

The application of low-temperature apatite thermochronology to the incision history of the Grand Canyon has led to conflicting hypotheses of either a 70 Ma ("old") or <6 Ma ("young") Grand Canyon. This controversy is best captured in the westernmost segment of the Grand Canyon, where several lines of evidence favor a "young" Canyon: 1) North-derived Paleocene Hindu Fanglomerate was deposited across the present track of the Canyon; 2) The Separation Point basalt (19 Ma) is stranded between high relief tributaries and the main stem of the Colorado River; 3) Relief generation in tributaries and on plateaus adjacent to the Canyon took place after 17 Ma; and 4) The late Miocene-Pliocene Muddy Creek Formation shows that no far-traveled materials entered the Grand Wash Trough until after 6 Ma. Some interpretations of apatite thermochronology data conflict with these lines of evidence and indicate a much older ( 70 Ma) westernmost Grand Canyon. We reconcile this conflict by applying apatite (U-Th)/He ages (AHe), 4He/3He thermochronometry, and apatite fission track ages and lengths (AFT) to the same sample at a key location. Using HeFTy, t-T paths that predict these data show cooling from ˜100 °C to 40-60 °C at 70-50 Ma, long-term residence at 40-60 °C from 50-10 Ma, and cooling to surface temperatures after 10 Ma, indicating young incision. New AFT (5) and AHe (3) datasets are also presented here. When datasets are examined separately, AHe data show t-T paths that cool to surface temperatures during the Laramide, consistent with an "old" Canyon. When multiple methods are applied, t-T paths instead show young incision. This inconsistency demonstrates the age of the Grand Canyon controversy. Here we reconcile the difference in t-T paths by adjusting model parameters to account for uncertainty in the rate of radiation damage annealing in apatite during burial heating and the resulting variations in He retentivity. In this area, peak burial conditions during the Laramide

From ocean depths to mountain tops: uplift of the Troodos Massif (Cyprus) constrained by (U-Th)/He thermochronology and geomorphic analysis

NASA Astrophysics Data System (ADS)

Morag, N.; Haviv, I.; Katzir, Y.

2013-12-01

The Troodos Massif of Cyprus, rising to nearly 2000 meters above sea level, encompasses one of the world's classic ophiolites. Following its formation at a seafloor spreading center in Late Cretaceous times, this slice of the NeoTethyan oceanic lithosphere was uplifted and eventually exposed on mountain tops during the Neogene. The final uplift and exhumation of the Troodos was previously assigned to Pleistocene age by observations in the circum-Troodos sedimentary strata. However, quantitative thermochronological and geomorphological data from the Massif itself were not available. Here we use apatite (U-Th)/He low-temperature thermochronology complemented by zircon (U-Th)/He and apatite fission track data, and combined with geomorphic analysis to constrain the exhumation and uplift history of the Troodos ophiolite. Apatite (U-Th)/He ages vary with depth from ~ 22 Ma at the top of the Gabbro sequence to ~ 6 Ma at the bottom of the sequence. The deepest sample from a Gabbro pegmatitic dyke intruding the ultramafic sequence yielded an age of ~ 3 Ma. Thermal modeling of apatite (U-Th)/He and fission track data delineates Plio - Pleistocene initiation of rapid uplift and exhumation of the Troodos ophiolite. The estimated cumulative exhumation since its initiation is 2-3 km. No evidence was found for significant uplift of the central Troodos area prior to that time. The geomorphic analysis delineates a bull's-eye zone at the center of the Troodos Massif, where local relief and channel steepness index are highest. The boundaries of this zone roughly correspond with the Mt. Olympus mantle outcrop and suggest recent, differential uplift of this zone relative to its surroundings. The most likely mechanism, which could drive such a focused bull's-eye uplift pattern is hydration of ultramafic rocks (serpentinization) leading to a decrease in rock density and subsequent diapiric uplift of the serpentinized lithospheric mantle.

Thermochronologic constraints on the tectonic evolution of the western Antarctic Peninsula in late Mesozoic and Cenozoic times

USGS Publications Warehouse

Brix, M.R.; Faundez, V.; Hervé, F.; Solari, M.; Fernandez, J.; Carter, A.; Stöckhert, B.

2007-01-01

West of the Antarctic Peninsula, oceanic lithosphere of the Phoenix plate has been subducted below the Antarctic plate. Subduction has ceased successively from south to north over the last 65 Myr. An influence of this evolution on the segmentation of the crust in the Antarctic plate is disputed. Opposing scenarios consider effects of ridge crest – trench interactions with the subduction zone or differences in slip along a basal detachment in the overriding plate. Fission track (FT) analyses on apatites and zircons may detect thermochronologic patterns to test these hypotheses. While existing data concentrate on accretionary processes in Palmer Land, new data extend information to the northern part of the Antarctic Peninsula. Zircons from different geological units over wide areas of the Antarctic Peninsula yield fission track ages between 90 and 80 Ma, indicating a uniform regional cooling episode. Apatite FT ages obtained so far show considerable regional variability

Deciphering the post-cratonization history of the Kaapvaal craton, South Africa from titanite and zircon (U-Th)/He thermochronology

NASA Astrophysics Data System (ADS)

Baughman, J. S.; Flowers, R. M.

2017-12-01

Cratons are the most stable portions of continents, but the degree to which they are affected by post-cratonization tectonic and magmatic processes is unclear. Complete time-temperature (t-T) histories are necessary to understand the timing, extent, and characteristics of post-cratonization events that disrupted these regions. However, deciphering extended cratonic t-T records is difficult owing to the incomplete stratigraphic records of continental interior settings, and the challenge of accessing the appropriate thermal history range with conventional thermochronometers. The Kaapvaal craton in South Africa is an archetypal craton that initially stabilized in the Archean and was subsequently affected by magmatic and marginal accretionary events. Here we exploit titanite and zircon (U-Th)/He (THe, ZHe) thermochronology to better decipher the somewhat cryptic Proterozoic through early Paleozoic history of the craton. Radiation damage effects on the He diffusivity of these two minerals provides the potential to access a wide temperature window from 200°C to near surface conditions. Existing low-temperature apatite (U-Th)/He and fission-track results constrain Late Paleozoic to Mesozoic burial of the Karoo basin and subsequent Cretaceous unroofing, while 40Ar/39Ar and Rb-Sr data document cooling through temperatures of 300°C by 2 Ga. We obtained THe and ZHe dates from across the northern Kaapvaal craton to fill in the thermal history gap between these constraints. THe and ZHe dates range from 1200 to 200 Ma, and 1000 to 30 Ma, respectively. Both sets of dates are negatively correlated with effective uranium concentration (eU), manifesting the effect of radiation damage on the He retentivity, and therefore closure temperature, of these minerals. The results allow us to assess the Mesoproterozoic through present day thermal history of the northern Kaapvaal craton. The THe data suggest that Mesoproterozoic exhumation and large-scale reheating associated with Namaqua

Zoning and exsolution in cumulate alkali feldspars from the eruption (12.9 Ka) of Laacher see volcano (Western Germany) as an indicator of time-scales and dynamics of carbonate-silicate unmixing

NASA Astrophysics Data System (ADS)

Sourav Rout, Smruti; Wörner, Gerhard

2017-04-01

Time-scales extracted from the detailed analysis of chemically zoned minerals provide insights into crystal ages, magma storage and compositional evolution, including mixing and unmixing events. This allows having a better understanding of pre-eruptive history of large and potentially dangerous magma chambers. We present a comprehensive study of chemical diffusion across zoning and exsolution patterns of alkali feldspars in carbonatite-bearing cognate syenites from the 6.3 km3 (D.R.E) phonolitic Laacher See Tephra (LST) eruption 12.9 ka ago. The Laacher See volcano is located in the Quaternary East Eifel volcanic field of the Paleozoic Rhenish Massif in Western Germany and has produced a compositionally variable sequence in a single eruption from a magma chamber that was zoned from mafic phonolite at the base to highly evolved, actively degassing phonolite magma at the top. Diffusion chronometry is applied to major and trace element compositions obtained on alkali feldspars from carbonate-bearing syenitic cumulates. Methods used were laser ablation inductively coupled plasma mass spectrometry (LA ICP-MS) in combination with energy-dispersive and wavelength-dispersive electron microprobe analyses (EDS & WDS-EMPA). The grey scale values extracted from multiple accumulations of back-scattered electron images represent the K/Na ratio owing to the extremely low concentrations of Ba and Sr (<30 ppm). The numerical grey scale profiles and the quantitative compositional profiles are anatomized using three different fitting models in MATLAB®, Mathematica® and Origin® to estimate related time-scales with minimized error for a temperature range of 750 deg C to 800 deg C (on the basis of existing experimental data on phase transition and phase separation). A distinctive uphill diffusive analysis is used specifically for the phase separation in the case of exsolution features (comprising of albite- and orthoclase-rich phases) in sanidines. The error values are aggregates of

Comment on “Systematic variations of argon diffusion in feldspars and implications for thermochronometry” by Cassata and Renne

NASA Astrophysics Data System (ADS)

Lovera, Oscar M.; Harrison, T. Mark; Boehnke, Patrick

2015-02-01

Cassata and Renne (2013) is a data-rich paper potentially providing opportunities to systematically test long-standing models of argon diffusion behavior in feldspars and we congratulate them on a heroic achievement. That said, several of their interpretations are highly problematic due to misconceptions of both the nature of their sample and diffusion modeling.

Comment on 'A reporting protocol for thermochronologic modeling illustrated with data from the Grand Canyon' by Flowers, Farley and Ketcham

NASA Astrophysics Data System (ADS)

Gallagher, Kerry

2016-05-01

Flowers et al. (2015) propose a framework for reporting modeling results for thermochronological data problems, particularly when using inversion approaches. In the final paragraph, they state 'we hope that the suggested reporting table template will stimulate additional community discussion about modeling philosophies and reporting formats'. In this spirit the purpose of this comment is to suggest that they have underplayed the importance of presenting a comparison of the model predictions with the observations. An inversion-based modeling approach aims to identify those models which makes predictions consistent, perhaps to varying degrees, with the observed data. The concluding section includes the phrase 'clear documentation of the model inputs and outputs', but their example from the Grand Canyon shows only the observed data.

Kiglapait Feldspar States 5 to <2 Kbar, 1250 to 240 Degrees C in 20 Ma: Liquidus, Solidus, Solvi, and Subsolidus with Sr Isotope Partitioning: a Review

NASA Astrophysics Data System (ADS)

Morse, S. A.

2017-12-01

The 1305 Ga Kiglapait Intrusion of coastal Labrador records the crystallization of troctolite through olivine gabbro to magnetite- and apatite-bearing rocks to monoclinic sanidine- mesoperthite-ferrosyenite below an inverted stratigraphy of a thin Upper Border Zone. The crystallization history was about 1 Ma. ¶The evolutionary history of Kiglapait feldspars in an 8.4 km thick magma chamber runs from plagioclase An70 at 5 kbar and 1250°C, cooling through to ferrosyenite with mesoperthite and two feldspars at 3 kbar and 1,000°C. The residual magma encountered the binodal solvus and finished crystallizing as an azeotrope with plagioclase (Or 21, An 15) and sanidine (Or 52, An 8) in liquid (Xor = 1/3; An 11). Cooling in the subsolidus brought the feldspars to compositions An15-Or 3, An0-Or 80-85 at 800-730°C. Metastable mesoperthite on the coherent solvus in various stages of late equilibration persists in the local assemblages. Arrested to complete feldspar symplectites suggest the local presence of a vapor phase. ¶Splits of the final Or-rich feldspar were found by mass spectrometry to have a dominant quantity of Rb and 87Sr/86Sr along with % amounts of Ba; in contrast, the plag fraction has very low Rb and 87Sr/86Sr. The estimated timing of the isotopic segregation was plausibly continuous with major-element fractionation or perhaps at the moment(s) of exsolution. ¶The cooling record of the solidified intrusion at 3 kbar is shown by 40Ar/39Ar data to have been rapid, reaching an ambient temperature near 240°C within the first 20 Ma, compared to the ambient country-rock temperature before intrusion of 350°C. The difference suggests a late uplift of the region after the Kiglapait magmatism. ¶Contributions from Y. Yu, T. Krogh, M. Hamilton, D. Lindsley, D. DePaolo, M. Jercinovic and S.R. Hart are especially acknowledged.

Geochronology and thermochronology of the gneisses of the Brasiliano/Pan-African Araguaia Belt: Records of exhumation of West Gondwana and Pangea break up

NASA Astrophysics Data System (ADS)

Dias, A. N. C.; Moura, C. A. V.; Milhomem Neto, J. M.; Chemale, F., Jr.; Girelli, T. J.; Masuyama, K. M.

2017-12-01

The 1200 km long Araguaia Belt, central-north Brazil, was formed as a result of the Neoproterozoic (Ediacaran) to Early Cambrian collage of West Gondwana and has several dome structures in whose nuclei crop out basement inliers of Archean and Paleoproterozoic orthogneisses. Thus, the orthogneisses from Lontra, Cocalândia, Colméia and Cantão dome structures were selected for fission-track thermochronology and U-Pb double dating. Three Archean magmatic episodes ranging from 2830.9 ± 6.9 Ma (Colméia dome) to 2905 ± 5.1 Ma (Lontra dome) and one Paleoproterozoic magmatic event at 1835 ± 31 Ma (Cantão dome) are recognized by U-Pb LA-MC-ICP-MS zircon dating. Fission-track thermochronology in zircon permitted to identify three well-defined age populations, which correspond to major regional geological events. The older population (489 ± 15 Ma to 498±8Ma) records the exhumation process and the orogenetic collapse of the Araguaia Belt. The intermediate population (331 ± 8 Ma to 345 ± 13 Ma) is related to the Gondwanides orogeny which affected the western margin of Gondwana and therefore the interior of South American. Finally, the younger fission track ages (197 ± 3 Ma, 197 ± 4 Ma, 198 ± 2 Ma and 208 ± 10 Ma) reflect crustal heating around 200 Ma, which is associated with the Lower Jurassic Mosquito tholeiitic magmatism and extended the influence of the Central Atlantic Magmatic Province to the Araguaia Belt. This mafic magmatism has been recognized in different regions of the South American and was an important source of heat for hydrocarbon generation in some Paleozoic intracratonic basins.

Geological setting and petrogenesis of symmetrically zoned, miarolitic granitic pegmatites at Stak Nala, Nanga Parbat - Haramosh Massif, northern Pakistan

USGS Publications Warehouse

Laurs, B.M.; Dilles, J.H.; Wairrach, Y.; Kausar, A.B.; Snee, L.W.

1998-01-01

Miarolitic granitic pegmatites in the Stak valley in the northeast part of the Nanga Parbat - Haramosh Massif, in northern Pakistan, locally contain economic quantities of bi- and tricolored tourmaline. The pegmatites form flat-lying sills that range from less than 1 m to more than 3 m thick and show symmetrical internal zonation. A narrow outer or border zone of medium-to coarse-grained oligoclase - K-feldspar - quartz grades inward to a very coarse-grained wall zone characterized by K-feldspar - oligoclase - quartz - schorl tourmaline. Radiating sprays of schorl and flaring megacrysts of K-feldspar (intermediate microcline) point inward, indicating progressive crystallization toward the core. The core zone consists of variable mixtures of blocky K-feldspar (intermediate microcline), oligoclase, quartz, and sparse schorl or elbaite, with local bodies of sodic aplite and miarolitic cavities or "pockets". Minor spessartine-almandine garnet and lo??llingite are disseminated throughout the pegmatite, but were not observed in the pockets. The pockets contain well-formed crystals of albite, quartz, K-feldspar (maximum microcline ?? orthoclase overgrowths), schorl-elbaite tourmaline, muscovite or lepidolite, topaz, and small amounts of other minerals. Elbaite is color-zoned from core to rim: green (Fe2+- and Mn2+-bearing), colorless (Mn2+-bearing), and light pink (trace Mn3+). Within ???10 cm of the pegmatites, the granitic gneiss wallrock is bleached owing to conversion of biotite to muscovite, with local quartz and albite added. Schorl is disseminated through the altered gneiss, and veins of schorl with bleached selvages locally traverse the wallrock up to 1 m from the pegmatite contact. The schorl veins can be traced into the outer part of the wall zone, which suggests that they formed from aqueous fluids derived during early saturation of the pegmatite-forming leucogranitic magma rich in H2O, F, B, and Li. Progressive crystallization resulted in a late-stage sodic

The brittle-viscous-plastic evolution of shear bands in the South Armorican Shear Zone

NASA Astrophysics Data System (ADS)

Bukovská, Zita; Jeřábek, Petr; Morales, Luiz F. G.; Lexa, Ondrej; Milke, Ralf

2014-05-01

Shear bands are microscale shear zones that obliquely crosscut an existing anisotropy such as a foliation. The resulting S-C fabrics are characterized by angles lower than 45° and the C plane parallel to shear zone boundaries. The S-C fabrics typically occur in granitoids deformed at greenschist facies conditions in the vicinity of major shear zones. Despite their long recognition, mechanical reasons for localization of deformation into shear bands and their evolution is still poorly understood. In this work we focus on microscale characterization of the shear bands in the South Armorican Shear Zone, where the S-C fabrics were first recognized by Berthé et al. (1979). The initiation of shear bands in the right-lateral South Armorican Shear Zone is associated with the occurrence of microcracks crosscutting the recrystallized quartz aggregates that define the S fabric. In more advanced stages of shear band evolution, newly formed dominant K-feldspar, together with plagioclase, muscovite and chlorite occur in the microcracks, and the shear bands start to widen. K-feldspar replaces quartz by progressively bulging into the grain boundaries of recrystallized quartz grains, leading to disintegration of quartz aggregates and formation of fine-grained multiphase matrix mixture. The late stages of shear band development are marked by interconnection of fine-grained white mica into a band that crosscuts the original shear band matrix. In its extremity, the shear band widening may lead to the formation of ultramylonites. With the increasing proportion of shear band matrix from ~1% to ~12%, the angular relationship between S and C fabrics increases from ~30° to ~40°. The matrix phases within shear bands show differences in chemical composition related to distinct evolutionary stages of shear band formation. The chemical evolution is well documented in K-feldspar, where the albite component is highest in porphyroclasts within S fabric, lower in the newly formed grains within

K-Ca and Rb-Sr Dating of Lunar Granite 14321 Revisited

NASA Technical Reports Server (NTRS)

Simon, Justin I.; Shih, C.-Y.; Nyquist, L. E.

2011-01-01

K-Ca and Rb-Sr age determinations were made for a bulk feldspar-rich portion of an Apollo rock fragment of the pristine lunar granite clast (14321,1062), an acid-leached split of the sample, and the leachate. K-Ca and Rb-Sr data were also obtained for a whole rock sample of Apollo ferroan anorthosite (FAN, 15415). The recent detection [1] of widespread intermediate composition plagioclase indicates that the generation of a diversity of evolved lunar magmas maybe more common and therefore more important to our understanding of crust formation than previously believed. Our new data strengthen the K-Ca and Rb-Sr internal isochrons of the well-studied Apollo sample 14321 [2], which along with a renewed effort to study evolved lunar magmas will provide an improved understanding of the petrogenetic history of evolved rocks on the Moon.

Glucocorticoids Suppress Renal Cell Carcinoma Progression by Enhancing Na,K-ATPase Beta-1 Subunit Expression

PubMed Central

Huynh, Thu P.; Barwe, Sonali P.; Lee, Seung J.; McSpadden, Ryan; Franco, Omar E.; Hayward, Simon W.; Damoiseaux, Robert; Grubbs, Stephen S.; Petrelli, Nicholas J.; Rajasekaran, Ayyappan K.

2015-01-01

Glucocorticoids are commonly used as palliative or chemotherapeutic clinical agents for treatment of a variety of cancers. Although steroid treatment is beneficial, the mechanisms by which steroids improve outcome in cancer patients are not well understood. Na,K-ATPase beta-subunit isoform 1 (NaK-β1) is a cell-cell adhesion molecule, and its expression is down-regulated in cancer cells undergoing epithelial-to mesenchymal-transition (EMT), a key event associated with cancer progression to metastatic disease. In this study, we performed high-throughput screening to identify small molecules that could up-regulate NaK-β1 expression in cancer cells. Compounds related to the glucocorticoids were identified as drug candidates enhancing NaK-β1 expression. Of these compounds, triamcinolone, dexamethasone, and fluorometholone were validated to increase NaK-β1 expression at the cell surface, enhance cell-cell adhesion, attenuate motility and invasiveness and induce mesenchymal to epithelial like transition of renal cell carcinoma (RCC) cells in vitro. Treatment of NaK-β1 knockdown cells with these drug candidates confirmed that these compounds mediate their effects through up-regulating NaK-β1. Furthermore, we demonstrated that these compounds attenuate tumor growth in subcutaneous RCC xenografts and reduce local invasiveness in orthotopically-implanted tumors. Our results strongly indicate that the addition of glucocorticoids in the treatment of RCC may improve outcome for RCC patients by augmenting NaK-β1 cell-cell adhesion function. PMID:25836370

Progress in Primary Acoustic Thermometry at NIST: 273 K to 505 K

NASA Astrophysics Data System (ADS)

Strouse, G. F.; Defibaugh, D. R.; Moldover, M. R.; Ripple, D. C.

2003-09-01

The NIST Acoustic Thermometer determines the thermodynamic temperature by measuring the speed of sound of argon in a spherical cavity. We obtained the thermodynamic temperature of three fixed points on the International Temperature Scale of 1990: the melting point of gallium [T(Ga) = 302.9146 K] and the freezing points of indium [T(In) = 429.7485 K] and tin [T(Sn) = 505.078 K]. The deviations of thermodynamic temperature from the ITS-90 defined temperatures are T - T90 = (4.7 ± 0.6) mK at T(Ga) , T - T90 = (8.8 ± 1.5) mK at T(In) , and T - T90 = (10.7 ± 3.0) mK at T(Sn) , where the uncertainties are for a coverage factor of k = 1. Our results at T(In) and T(Sn) reduce the uncertainty of T - T90 by a factor of two in this range. Both T - T90 at T(Ga) and the measured thermal expansion of the resonator between the triple point of water and T(Ga) are in excellent agreement with the 1992 determination at NIST. The dominant uncertainties in the present data come from frequency-dependent and time-dependent crosstalk between the electroacoustic transducers. We plan to reduce these uncertainties and extend this work to 800 K.

Development of the EarthChem Geochronology and Thermochronology database: Collaboration of the EarthChem and EARTHTIME efforts

NASA Astrophysics Data System (ADS)

Walker, J. D.; Ash, J. M.; Bowring, J.; Bowring, S. A.; Deino, A. L.; Kislitsyn, R.; Koppers, A. A.

2009-12-01

One of the most onerous tasks in rigorous development of data reporting and databases for geochronological and thermochronological studies is to fully capture all of the metadata needed to completely document both the analytical work as well as the interpretation effort. This information is available in the data reduction programs used by researchers, but has proven difficult to harvest into either publications or databases. For this reason, the EarthChem and EARTHTIME efforts are collaborating to foster the next generation of data management and discovery for age information by integrating data reporting with data reduction. EarthChem is a community-driven effort to facilitate the discovery, access, and preservation of geochemical data of all types and to support research and enable new and better science. EARTHTIME is also a community-initiated project whose aim is to foster the next generation of high-precision geochronology and thermochoronology. In addition, collaboration with the CRONUS effort for cosmogenic radionuclides is in progress. EarthChem workers have met with groups working on the Ar-Ar, U-Pb, and (U-Th)/He systems to establish data reporting requirements as well as XML schemas to be used for transferring data from reduction programs to database. At present, we have prototype systems working for the U-Pb_Redux, ArArCalc, MassSpec, and Helios programs. In each program, the user can select to upload data and metadata to the GEOCHRON system hosted at EarthChem. There are two additional requirements for upload. The first is having a unique identifier (IGSN) obtained either manually or via web services contained within the reduction program from the SESAR system. The second is that the user selects whether the sample is to be available for discovery (public) or remain hidden (private). Search for data at the GEOCHRON portal can be done using age, method, mineral, or location parameters. Data can be downloaded in the full XML format for ingestion back

New constraints on the thermochronologic evolution at the boundary between the Eastern and Western Alps - Vorarlberg, Austria

NASA Astrophysics Data System (ADS)

Bertrand, Audrey; Pomella, Hannah; Fügenschuh, Bernhard; Zerlauth, Michael; Ortner, Hugo

2013-04-01

temperature to < 100 °C, most likely reached between 20 Ma and 14 Ma by combined sediment and tectonic overburden. References Gleadow, A.J.W., and Duddy, I.R., 1981, A natural long-term annealing experiment for apatite. Nuclear Tracks Radiation Experiments, 5, 169-174. Pomella et al., this session. Alpine nappe stack in western Austria: A crustal-scale cross-section. Ravenhurst, C.E., and Donelick, R.A., 1992. Fission track thermochronology. In Short Course. Handbook on Low Temperature Thermochronology, ed. M. Zentilli & P.H. Reynolds. pp.21-42.

Near infrared spectra of muscovite, Tschermak substitution, and metamorphic reaction progress: Implications for remote sensing

NASA Astrophysics Data System (ADS)

Duke, Edward F.

1994-07-01

Near infrared (NIR) spectra of Precambrian metagraywacke in the Black Hills, South Dakota, demonstrate that reflectance spectroscopy can be used to monitor progressive changes in mineral chemistry as a function of metamorphic grade. The wavelength of a combination Al-O-H absorption band in muscovite, measured using both laboratory and field-portable NIR spectrometers, shifts from 2217 nm in the biotite zone to 2199 nm in the sillimanite + K-feldspar zone. The band shift corresponds to an increase in the Alvi content of muscovite, determined by electron microprobe, and is thus a monitor of Al2Si-1(Fe,Mg)-1 (Tschermak) exchange. Spectroscopic measurements such as these are useful in the case of aluminum-deficient rocks, which lack metamorphic index minerals or appropriate assemblages for thermobarometric studies, and in low-grade rocks (subgarnet zone), which lack quantitative indicators of metamorphic grade and are too fine grained for petrographic or microprobe studies. More important, spectroscopic detection of mineral-chemical variations in metamorphic rocks provides petrologists with a tool to recover information on metamorphic reaction histories from high-spectral-resolution aircraft or satellite remote sensing data.

Thermal and exhumation history of the central Tianshan (NW China): Constraints by U-Pb geochronology and Ar-Ar and (U-Th)/He thermochronology

NASA Astrophysics Data System (ADS)

Yin, J.; Chen, W.; Hodges, K. V.; Xiao, W.; Van Soest, M. C.; Cai, K.; Zhang, B.; Mercer, C. M.; Yuan, C.

2015-12-01

Geochronology and thermochronology using multiple mineral-isotopic chronometers reveals the thermo-tectonic history of the central Tianshan (NW China) from emplacement to exhumation. Granites from the central Tianshan, which are associated with the southward subduction of the northern Tianshan Ocean, have been dated at 362-354 Ma using the LA-ICP-MS Zircon U-Pb method. A younger diorite sample (282 ± 1 Ma, Zircon U-Pb method by LA-ICP-MS) from northern Tianshan formed during the final closure of the Northern Tianshan Ocean when the Junggar Block collided with the Yili-Central Tianshan Block. 40Ar/39Ar step-wise heating plateau dates (biotite Ar/Ar: 312-293 Ma; Plagioclase Ar/Ar: 270-229 Ma) from the Central Tianshan show rapid post-magmatic cooling during the Late Carboniferous-Early Permian followed by a more modest rate of cooling from the middle Permian to the middle Jurassic. The northern Tianshan diorite (biotite Ar/Ar: 240 ± 1 Ma) also reveals a middle Jurassic cooling. Apatite (U-Th )/He dates from the central Tianshan samples range from ca. 130 Ma to ca. 116 Ma. The Apatite (U-Th )/He date for the northern Tianshan sample is ca. 27 Ma. Previous studies also reported Apatite (U-Th)/He ages of ca. 44 Ma-11 Ma in the Baluntai area of the southern Central Tianshan[1]. Two episodes of cooling are distinguished by thermal history modelling: (1) Mesozoic cooling occurred as the result of the exhumation and tectonic reactivation of the central Tianshan; and (2) The Tianshan orogenic belt has been rapidly exhumed since the Middle Cenozoic. References [1] Lü, H.H., Chang, Y., Wang, W., Zhou, Z.Y., 2013. Rapid exhumation of the Tianshan Mountains since the early Miocene: Evidence from combined apatite fission track and (U-Th)/He thermochronology. Science China: Earth Sciences, 43(12): 1964-1974 (in Chinese).

Geology and mineralization of the Jabal Umm Al Suqian albitized apogranite, southern Najd region, Kingdom of Saudi Arabia

NASA Astrophysics Data System (ADS)

Bokhari, M. Madani; Jackson, Norman J.; Al Oweidi, Khalid

A porphyritic muscovite—albite—microcline microgranite crops out at Jabal Umm Al Suqian, 80 km NE of Bishah. It intrudes alkali-feldspar granite, quartz diorite and a conglomerate composed of dioritic clasts, and is enveloped by a shell of hydrothermally altered, albitized, greisenized and microclinized country rocks. The principal chemical features of the microgranite are: 5-7% Na 2O, Na 2O/K 2O = 1.7, Rb 978 ppm, Sn 94 ppm, and low Ba, Ce, Sr and Zr. Albitized microgranite is highly enriched in F, Nb and Y, and the greisenized assemblages are enriched in F, Li, Rb, Sn and Zn. Mineralization consists of small veins and lenses of fluorite and disseminated minerals such as ixiolite, monazite, bastnaesite, betafite and fluorite, but is not economically significant. The microgranite is probably an apogranite cupola in the roof of an alkali-feldspar granite. Crystallization at about 1 kb total volatile pressure was controlled by (1) variable (0-3 wt. %) F contents which significantly reduced the freezing temperature of the melt and resulted in an albite-rich residue; and (2) progressive decrease in K, which also produced a sodic residuum. K- and F-rich hydrothermal fluids produced the envelope of phyllic alteration. Repetitive increase and decrease in volatile pressure produced rhythmic banding of quartz and alkali feldspar in the upper part of the cupola.

Building Capacity in Understanding Foundational Biology Concepts: A K-12 Learning Progression in Genetics Informed by Research on Children's Thinking and Learning

ERIC Educational Resources Information Center

Elmesky, Rowhea

2013-01-01

This article describes the substance, structure, and rationale of a learning progression in genetics spanning kindergarten through twelfth grade (K-12). The learning progression is designed to build a foundation towards understanding protein structure and activity and should be viewed as one possible pathway to understanding concepts of genetics…

A Summary Report of Iowa's Review of PreK-6 Reading Assessments for Universal Screening and Progress

ERIC Educational Resources Information Center

Iowa Department of Education, 2013

2013-01-01

This document contains summary information for the Iowa Department of Education's review of PreK-6th grade reading assessments for the purposes of Universal Screening and Progress Monitoring. It is intended to provide general information to help inform decisions about selecting assessments for use as a part of Iowa's Response to Intervention…

Decoding Dynamic Topography: Geologic and Thermochronologic Constraints From Madagascar

NASA Astrophysics Data System (ADS)

Stephenson, S.; White, N.

2017-12-01

Madagascar's topography is characterized by flights of low relief peneplains separated by escarpments. Remarkably, nearly 50% of the landscape is higher than 500 m despite being surrounded by passive margins. Eocene marine limestones crop out at elevations of 400-800 m, staircases of Pleistocene marine terraces fringe the coastline and longitudinal river profiles are disequilibrated. Together, these observations suggest that Madagascar has experienced Neogene epeirogenic uplift. Positive oceanic residual depth anomalies surrounding the island, long wavelength free-air gravity anomalies, Neogene basaltic volcanism and slow sub-plate shear wave velocities show that Neogene uplift is generated by convective circulation within the upper mantle. However, the landscape's erosional response to long wavelength uplift is poorly known. Here, we present 18 apatite fission track and apatite He analyses of granitoid samples from sub-vertical transects in central and northern Madagascar. Apatite fission track ages are 200-250 Ma with mean track lengths of 12 μm. Apatite He ages are highly dispersed in samples from the highlands (i.e. AHe age > 150 Ma) but a narrower, younger range of 30-60 Ma is found on the coastal lowlands. Joint inverse modeling was carried out using the QTQt transdimensional reversible jump Markov Chain Monte Carlo (MCMC) algorithm to determine time-temperature histories. Results show that the coastal lowlands experienced up to 1 km of exhumation during the Neogene Period, whilst the central highlands experienced either very slow or negligible exhumation. This spatial distribution is expected when kinematic waves of incision propagate through a fluvially eroding landscape from coast to interior. Inverse modeling of suites of river profiles and forward landscape simulations support this interpretation. Our results show that the landscape response to modest (i.e. 1 km) regional uplift is diachronous and that thermochronologic observations can be used to

New insight into the thermal-tectonic history of the southern Antarctic Peninsula: (Uranium-Thorium-Samarium)/Helium and fission-track thermochronologic results from northwest Palmer Land and Alexander Island

NASA Astrophysics Data System (ADS)

Savrda, Amanda Marie

2011-12-01

This study examines the thermal history of the southern Antarctic Peninsula through the application of thermochronometry, and presents the first high-resolution thermochronologic dataset for arc rocks of northwest Palmer Land. I present 19 new thermochronologic ages obtained via (U-Th-Sm)/He and fission-track analyses of apatite and zircon from arc granitoids of northwest Palmer Land and fore-arc rocks of the LeMay and Fossil Bluff Groups of Alexander Island. These data were modeled via Monte Carlo simulations to generate time-temperature pathways. Thermal models generated for arc granitoids of northwest Palmer Land reveal a Late Cretaceous-Early Cenozoic episode of accelerated cooling from ca. 78--55 Ma not previously recognized in the southern Antarctic Peninsula. Here, faster cooling at an average rate of ˜15°C/Myr is bracketed by slower cooling at rates <3°C/Myr. Modeled thermal histories of metamorphosed fore-arc sedimentary rocks of Alexander Island reveal rapid cooling throughout the Eocene at an average rate of ˜13°C/Myr, preceded and followed by slower rates of cooling on the order of <3°C/Myr. The spatial and temporal distribution of the observed cooling trends may reflect localized variations in the thermal regime due to regional changes in plate kinematics, subduction dynamics, and related magmatism, but the cooling rates are also within range of those typical of exhumational processes such as normal faulting, ductile thinning, and erosion.

The Sidi Ifni transect across the rifted margin of Morocco (Central Atlantic): Vertical movements constrained by low-temperature thermochronology

NASA Astrophysics Data System (ADS)

Charton, Rémi; Bertotti, Giovanni; Arantegui, Angel; Bulot, Luc

2018-05-01

The occurrence of km-scale exhumations during syn- and post-rift stages has been documented along Atlantic continental margins, which are also characterised by basins undergoing substantial subsidence. The relationship between the exhuming and subsiding domains is poorly understood. In this study, we reconstruct the evolution of a 50 km long transect across the Moroccan rifted margin from the western Anti-Atlas to the Atlantic basin offshore the city of Sidi Ifni. Low-temperature thermochronology data from the Sidi Ifni area document a ca. 8 km exhumation between the Permian and the Early/Middle Jurassic. The related erosion fed sediments to the subsiding Mesozoic basin to the NW. Basement rocks along the transect were subsequently buried by 1-2 km between the Late Jurassic and the Early Cretaceous. From late Early/Late Cretaceous onwards, rocks present along the transect were exhumed to their present-day position.

Effect of vitamin K2 on progression of atherosclerosis and vascular calcification in nondialyzed patients with chronic kidney disease stages 3-5.

PubMed

Kurnatowska, Ilona; Grzelak, Piotr; Masajtis-Zagajewska, Anna; Kaczmarska, Magdalena; Stefańczyk, Ludomir; Vermeer, Cees; Maresz, Katarzyna; Nowicki, Michał

2015-01-01

Observational studies have shown that high dietary intake of vitamin K2 is associated with reduced risk of coronary vascular disease and vascular calcification. We assessed the effect of vitamin K2 substitution on the progression of atherosclerosis and calcification in nondialyzed patients with CKD stages 3-5. The study included 42 nondialyzed patients with CKD. The following measurements were taken at baseline and after 270 ±12 days of supplementation with vitamin K2 at a dose of 90 μg (menaquinone, MK-7) together with 10 μg of cholecalciferol (K+D group) or 10 μg of cholecalciferol (group D): common carotid intima-media thickness (CCA-IMT), coronary artery calcification score (CACS), basic biochemical parameters, lipids, and calcification modulators: matrix Gla protein (MGP), desphosphorylated-uncarboxylated MGP (dp-ucMGP), osteoprotegerin (OPG), fetuin A, osteocalcin (OC), and fibroblast growth factor 23. The increase of CCA-IMT was significantly lower in the K+D group compared with the D group: from 0.95 ±0.2 mm to 1.01 ±0.3, P = 0.003 vs from 1.02 ±0.2 mm to 1.16 ±0.3, P = 0.003 (ΔCCA-IMT, 0.06 ±0.08 vs 0.136 ±0.05 mm, P = 0.005, respectively). The increase in CACS was slightly lower in the K+D group than in the D group (ΔCACS, 58.1 ±106.5 AU vs 74.4 ±127.1 AU, P = 0.7). In the K+D group, a significant decrease in the level of dp-ucMGP and total OC was observed. A 270-day course of vitamin K2 administration in patients with CKD stages 3-5 may reduce the progression of atherosclerosis, but does not significantly affect the progression of calcification. Vitamin K2 significantly changes the levels of calcification promoters and inhibitors: dp-ucMGP, OC, and OPG.

Luminescence isochron dating: a new approach using different grain sizes.

PubMed

Zhao, H; Li, S H

2002-01-01

A new approach to isochron dating is described using different sizes of quartz and K-feldspar grains. The technique can be applied to sites with time-dependent external dose rates. It is assumed that any underestimation of the equivalent dose (De) using K-feldspar is by a factor F, which is independent of grain size (90-350 microm) for a given sample. Calibration of the beta source for different grain sizes is discussed, and then the sample ages are calculated using the differences between quartz and K-feldspar De from grains of similar size. Two aeolian sediment samples from north-eastern China are used to illustrate the application of the new method. It is confirmed that the observed values of De derived using K-feldspar underestimate the expected doses (based on the quartz De) but, nevertheless, these K-feldspar De values correlate linearly with the calculated internal dose rate contribution, supporting the assumption that the underestimation factor F is independent of grain size. The isochron ages are also compared with the results obtained using quartz De and the measured external dose rates.

Thermochronologic Evidence for Late Eocene Andean Mountain Building at 30°S

NASA Astrophysics Data System (ADS)

Lossada, Ana C.; Giambiagi, Laura; Hoke, Gregory D.; Fitzgerald, Paul G.; Creixell, Christian; Murillo, Ismael; Mardonez, Diego; Velásquez, Ricardo; Suriano, Julieta

2017-11-01

The Andes between 28° and 30°S represent a transition between the Puna-Altiplano Plateau and the Frontal/Principal Cordillera fold-and-thrust belts to the south. While significant early Cenozoic deformation documented in the Andean Plateau, deciphering the early episodes of deformation during Andean mountain building in the transition area is largely unstudied. Apatite fission track (AFT) and (U-Th-Sm)/He (AHe) thermochronology from a vertical and a horizontal transect reveal the exhumation history of the High Andes at 30°S, an area at the heart of this major transition. Interpretation of the age-elevation profile, combined with inverse thermal modeling, indicates that the onset of rapid cooling was underway by 35 Ma, followed by a significant decrease in cooling rate at 30-25 Ma. AFT thermal models also reveal a second episode of rapid cooling in the early Miocene ( 18 Ma) related to rock exhumation to its present position. Low exhumation between the rapid cooling events allowed for the development of a partial annealing zone. We interpret the observed Eocene rapid exhumation as the product of a previously unrecognized compressive event in this part of the Andes that reflects a southern extension of Eocene orogenesis recognized in the Puna/Altiplano. Renewed early-Miocene exhumation indicates that the late Cenozoic compressional stresses responsible for the main phase of uplift of the South Central Andes also impacted the core of the range in this transitional sector. The major episode of Eocene exhumation suggests the creation of significant topographic relief in the High Andes earlier than previously thought.

(U-Th-Sm)/He thermochronological age distribution in a slowly cooled plutonic complex (Ploumanac'h intrusion, France): insights into helium diffusion processes.

NASA Astrophysics Data System (ADS)

Recanati, A. C.; Gautheron, C.; Barbarand, J.; Tassan-Got, L.; Missenard, Y.; Pinna-Jamme, R.

2015-12-01

(U-Th-Sm)/He thermochronology is widely used to determine the thermal histories of mountain ranges and sedimentary basins. Apatite crystals retain helium at low temperatures, thus giving an insight into upper crustal evolution (e.g. exhumation, subsidence, erosion). Advanced models predict He production and diffusion rates in apatite crystals, thereby allowing determination of helium dates by integration over time/temperature paths (e.g. Gautheron et al., 2009). However, scattered dates and discordance between predicted and measured dates suggest that other parameters than time or temperature may also influence helium contents in apatite. The present study determines the variables that affect He diffusion in apatite over long timescales. We report the (U-Th-Sm)/He date distribution within a slowly cooled intrusion, along with AFT data, as well as extensive petrological and chemical characterization. The Ploumanac'h site (Brittany, France) was chosen because it includes small-scale spatial variations in petrology and chemistry (6-9106 tracks/cm2). GAUTHERON C., TASSAN-GOT L., BARBARAND J., PAGEL M., 2009. Effect of alpha-damage annealing on apatite (U-Th)/He thermochronology. Chem. Geol. 266, 166-179.

Thermochronology in southeast Alaska and southwest Yukon: Implications for North American Plate response to terrane accretion

NASA Astrophysics Data System (ADS)

Enkelmann, Eva; Piestrzeniewicz, Adam; Falkowski, Sarah; Stübner, Konstanze; Ehlers, Todd A.

2017-01-01

This study presents the first comprehensive dataset of low-temperature thermochronology from 43 bedrock samples collected north of the active Yakutat-North American plate boundary. Our apatite and zircon (U-Th)/He and fission-track data reveal the cooling history of the inboard Wrangellia Composite Terrane that is dominated by rapid cooling after Late Jurassic to Early Cretaceous arc magmatism followed by very little cooling and exhumation until today. Deformation resulting in rock exhumation due to the collision of the Yakutat microplate is spatially very limited (20-30 km) and is concentrated mainly in the Chugach-Prince William Terrane and rocks near the Border Ranges Fault. Focused exhumation from greater depths of ca. 10 km with very high rates (>5 km/Myr) is localized at the syntaxis region, starting ca. 10 Ma and shifted south through time. The rapid exhumation rates are explained by the development of strong feedbacks between tectonically driven surface uplift and erosion, which started already before glaciation of the area. The shift in the location towards the south is a consequence of continuous readjusting between tectonics and climate, which is changing on local and global scales since the Late Miocene.

Dating of major normal fault systems using thermochronology: An example from the Raft River detachment, Basin and Range, western United States

USGS Publications Warehouse

Wells, M.L.; Snee, L.W.; Blythe, A.E.

2000-01-01

Application of thermochronological techniques to major normal fault systems can resolve the timing of initiation and duration of extension, rates of motion on detachment faults, timing of ductile mylonite formation and passage of rocks through the crystal-plastic to brittle transition, and multiple events of extensional unroofing. Here we determine the above for the top-to-the-east Raft River detachment fault and shear zone by study of spatial gradients in 40Ar/39Ar and fission track cooling ages of footwall rocks and cooling histories and by comparison of cooling histories with deformation temperatures. Mica 40Ar/39Ar cooling ages indicate that extension-related cooling began at ???25-20 Ma, and apatite fission track ages show that motion on the Raft River detachment proceeded until ???7.4 Ma. Collective cooling curves show acceleration of cooling rates during extension, from 5-10??C/m.y. to rates in excess of 70-100??C/m.y. The apparent slip rate along the Raft River detachment, recorded in spatial gradients of apatite fission track ages, is 7 mm/yr between 13.5 and 7.4 Ma and is interpreted to record the rate of migration of a rolling hinge. Microstructural study of footwall mylonite indicates that deformation conditions were no higher than middle greenschist facies and that deformation occurred during cooling to cataclastic conditions. These data show that the shear zone and detachment fault represent a continuum produced by progressive exhumation and shearing during Miocene extension and preclude the possibility of a Mesozoic age for the ductile shear zone. Moderately rapid cooling in middle Eocene time likely records exhumation resulting from an older, oppositely rooted, extensional shear zone along the west side of the Grouse Creek, Raft River, and Albion Mountains. Copyright 2000 by the American Geophysical Union.

TRIM24 promotes glioma progression and enhances chemoresistance through activation of the PI3K/Akt signaling pathway.

PubMed

Zhang, L-H; Yin, A-A; Cheng, J-X; Huang, H-Y; Li, X-M; Zhang, Y-Q; Han, N; Zhang, X

2015-01-29

The tripartite motif protein TRIM24 (tripartite motif-containing 24) has been found to play distinct roles in tumor development and progression, according to different tumor contexts. However, it remains elusive whether TRIM24 plays a role in malignant gliomas that are the most common and deadly primary brain tumors in adults. We report here that TRIM24 expression is positively correlated with glioma malignancy and is negatively associated with prognosis of patients with newly diagnosed glioblastoma, which is the most malignant form of gliomas but displays highly heterogeneous clinical outcome. The multivariate Cox regression analysis demonstrates the independent predictive value of TRIM24 expression level for overall and progression-free survival. Knockdown of TRIM24 suppresses cell proliferation, cell cycle progression, clone formation and in vivo tumor development, whereas overexpression of TRIM24 promotes cell growth. Chromatin immunoprecipitation, real-time reverse transcription-PCR and mutation analyses demonstrate that TRIM24 binds to the PIK3CA promoter via its PHD-Bromo domain to activate the transcription of PIK3CA gene, thus enhancing phosphatidylinositide 3-kinase (PI3K)/Akt signaling. The pan-PI3K inhibitor LY294002 and small interfering RNA targeting PIK3CA both abrogate the growth-promoting effect of TRIM24. Moreover, TRIM24 regulates the expression of DNA repair enzyme O(6)-methylguanine-DNA methyltransferase (MGMT) through PI3K/Akt/nuclear factor-κB signaling transduction and enhances resistance to temozolomide, the standard chemotherapeutic agent for glioblastoma. Finally, glioblastoma patients with low TRIM24 expression benefit from chemotherapy, whereas those with high TRIM24 expression do not have such benefit. Our results suggest that TRIM24 might serve as a potential prognostic marker and therapeutic target for the management of malignant gliomas.

Phase relations among K-feldspar, muscovite and H2O at 1.0 GPa and 800°C: Implications for metasediment dissolution and melting at high pressures and temperatures

NASA Astrophysics Data System (ADS)

Fineman, D.; Manning, C. E.

2016-12-01

Melting and solubility of K-feldspar (ksp) and muscovite (mus) were investigated in the system KSi3O6.5 -Al2O3 - H2O at 1.0 GPa and 800 °C with rapid-quench piston-cylinder techniques. Equilibrium assemblages of ksp, mus, silicate liquid (L) and aqueous fluid (V) were deduced from optical and scanning electron microscopy. Quenched silicate liquids and aqueous fluids were distinguished using the methodology of Burnham and Jahns (1962, Am J Sci, 260, 721) and Makhluf et al. (2016, CMP, in press). Experiments on a range of bulk compositions constrain the locations of the V, ksp+V, ms+V, and ksp+L+V fields. This allowed geometrical constraints to be placed on additional phase boundaries in the ternary system. The results show that ksp dissolves incongruently in H2O, with residual liquid or ms depending on the fluid-rock ratio. In contrast, ms dissolves congruently in H2O and KSi3O6.5 -H2O solutions with up to 25 wt% KSi3O6.5. Results indicate that stable hydrous liquid at these conditions has an Al content intermediate between ksp and ms. There is no stable liquid along the ksp-H2O join, consistent with results of Goldsmith and Peterson (1990, Am Min, 75, 1362). All data are consistent with the stability of a supercritical fluid on the KAlSi3O8 -H2O join, with 5-10 wt% dissolved Al2O3. Compositional constraints imply that the liquid phase contains 25 wt% H2O and coexists with a V phase containing 25 wt% dissolved solutes. This in turn implies critical mixing of the fluid phases at higher temperature, which is similar to the systems NaAlSi3O8-H2O and simple granite-H2O. Our results help constrain the conditions of production of supercritical granitic-H2O fluids systems in deep crustal and subduction zone settings.

The tumor suppressor SirT2 regulates cell cycle progression and genome stability by modulating the mitotic deposition of H4K20 methylation

USDA-ARS?s Scientific Manuscript database

The establishment of the epigenetic mark H4K20me1 (monomethylation of H4K20) by PR-Set7 during G2/M directly impacts S-phase progression and genome stability. However, the mechanisms involved in the regulation of this event are not well understood. Here we show that SirT2 regulates H4K20me1 depositi...

U-Pb thermochronology of the lower crust: producing a long-term record of craton thermal evolution

NASA Astrophysics Data System (ADS)

Blackburn, T.; Bowring, S. A.; Mahan, K. H.; Perron, T.; Schoene, B.; Dudas, F. O.

2010-12-01

The EarthScope initiative is focused on providing an enhanced view of the North American lithosphere and the present day stress field of the North American continent. Of key interest is the interaction between convecting asthenosphere and the conducting lithospheric mantle that underlie the continents, especially the cold ‘keels’ that underlie Archean domains. Cratonic regions are in general characterized by minimal erosion and or sediment accumulation. The Integration of seismic tomography, and mantle xenolith studies reveal a keel of seismically fast and relatively buoyant and viscous mantle; physical properties that are intimately linked with the long-term stability and topographic expression of the region. Missing from this model of the continental lithosphere is the 4th dimension--time--and along with it our understanding of the long-term evolution of these stable continental interiors. Here we present a thermal record from the North American craton using U-Pb thermochronology of lower crustal xenoliths. The use of temperature sensitive dates on lower crustal samples can produce a unique time-temperature record for a well-insulated and slowly cooling lithosphere. The base of the crust is insulated enough to remain unperturbed by any plausible changes to surface topography, yet unlike the subadjacent lithospheric mantle, contains accessory phases amenable to U-Pb dating (rutile, apatite, titanite). With near steady state temperatures in the lower crust between 400-600 °C, U-Pb thermochronometers with similar average closure temperatures for Pb are perfectly suited to record the long-term cooling of the lithosphere. Xenoliths from multiple depths, and across the craton yield time-temperature paths produced from U-Pb thermochronometers that record extremely slow cooling (<0.25 °C/Ma) over time scales of billions of years. Combining these data with numerical thermal modeling allow constraints to be placed on the dominant heat transfer mechanisms operating

Early Mesozoic cooling from low temperature thermochronology in N Spain and N Africa

NASA Astrophysics Data System (ADS)

Grobe, R.; Alvarez-Marrón, J.; Glasmacher, U. A.; Menéndez-Duarte, R.

2009-04-01

In the western prolongation of the Pyrenees, the substratum of the Cantabrian Mountains consists of an E-W crustal section of the Gondwana continental margin involved in the Variscan collision. In Mesozoic times, the region was modified by rifting and the opening of the Atlantic and the Bay of Biscay, while in Paleogene-Neogene times it was affected by the convergence of the Iberian Plate with the Eurasian Plate resulting in the present mountains. Our thermochronological data and modelled time-temperature histories suggest an earlier, relative fast cooling period during Early Triassic to Early Jurassic. This cooling event coincides temporally with the process of rifting that caused Pangaea continental break-up and the opening of the North Atlantic. Other authors report similar cooling histories from Early Triassic to Middle Jurassic from other parts of the Iberian Peninsula (Juez-Larré, 2003; Barbero et al., 2005) as well as from the Moroccan Meseta, in N Africa (Ghorbal et al., 2008). Furthermore, the time span of this cooling event includes the period of main activity of the Central Atlantic Magmatic Province (CAMP) magmatism at around 200 Ma (Marzoli et al., 1999). Wilson (1997) postulates a relationship between this magmatic activity and upwelling of a large-scale mantle plume (super-plume) beneath the West African craton. Correlatives of this province have been identified as far as the southern Iberian Peninsula, Newfoundland, and possibly in Brittany, among other European areas (Pe-Piper et al., 1992; Jourdan et al., 2003). The current presentation aims to discuss possible African far-field effects on thermochronological data in the Cantabrian Mountains of NW Spain. References: Barbero, L.; Glasmacher, U. A.; Villaseca, C.; López García, J. A.; Martín-Romera, C. (2005). Long-term thermo-tectonic evolution of the Montes de Toledo area (Central Hercynian Belt, Spain): constraints from apatite fission-track analysis. International Journal of Earth Sciences

Beating the Heat: Magmatism in the Low-Temperature Thermochronologic Record

NASA Astrophysics Data System (ADS)

Murray, K. E.; Reiners, P. W.; Braun, J.; Karlstrom, L.; Morriss, M. C.

2017-12-01

The low-temperature thermochronology community was quick to recognize upper-crustal complexities in the geotherm that reflect landscape evolution, but the complex effects of crustal magmatism on thermochronometers can be difficult to independently document and remain underexplored. Because magmatism is common in many regions central to our understanding of tectonics, this is a significant gap in our ability to robustly interpret rock cooling. Here, we use several different numerical approaches to examine how local and regional crustal magmatism affects cooling age patterns and present examples from the western US that demonstrate the importance—and utility—of considering these effects. We modified the finite-element code Pecube to calculate how thermochronometers document the emplacement of simple hot bodies at different crustal levels. Results demonstrate the potential for mid-crustal plutons, emplaced at 10-15 km depth, to reset cooling ages in the overlying rocks at partial-retention depths at the time of magmatism. Permo-Triassic sandstones from the Colorado Plateau's Canyonlands region have apatite cooling ages that exemplify the resulting ambiguity: Oligocene rock cooling can be attributed to either 1 km of erosion or relaxation of a geothermal gradient transiently doubled by mid-crustal magmatism. Despite these complexities, there are compelling reasons to target rocks with magmatic histories. Shallowly emplaced plutons can usefully reset cooling ages in country rocks with protracted near-surface histories, as we have demonstrated in the Colorado Plateau's Henry Mountains. Cooling age patterns are also useful for quantifying magmatic processes themselves. In an ongoing project, we use the pattern of thermochronometer resetting around individual dikes that fed the Columbia River flood basalts, which are exposed in the Wallowa Mountains, to identify long-lived feeder dikes and model their thermal aureoles to further constrain eruptive dynamics. The pattern

40Ar/39Ar age-spectrum data for hornblende, biotite, white mica, and K-feldspar samples from metamorphic rocks in the Great Smoky Mountains of North Carolina and Tennessee

USGS Publications Warehouse

Kunk, Michael J.; McAleer, Ryan J.

2011-01-01

This report contains reduced 40Ar/39Ar data of hornblende, biotite, white mica and (or) sericite, and potassium-feldspar mineral separates and phyllite groundmass samples from metamorphic rocks of the Great Smoky Mountains in North Carolina and Tennessee. Included in this report are information on the location of the samples and a brief description of the samples. The data contained herein are not interpreted in a geological context, and care should be taken by users unfamiliar with argon isotopic data in the use of these results. No geological meaning is implied for any of the apparent ages presented below, and many of the individual apparent ages are not geologically meaningful. This report is primarily a detailed source document for subsequent publications that will integrate these data into a geological context. All the samples in this report were collected in and around the Great Smoky Mountain National Park in western North Carolina and eastern Tennessee.

Pegmatite/wallrock interactions, Black Hills, South Dakota: Progressive boron metasomatism adjacent to the Tip Top pegmatite

NASA Astrophysics Data System (ADS)

Shearer, C. K.; Papike, J. J.; Simon, S. B.; Laul, J. C.; Christian, R. P.

1984-12-01

Interaction between country rock and fluids derived from the Tip Top pegmatite has resulted in a series of boron enriched assemblages. Between unaltered quartz-mica schist to the pegmatite contact is a succession of four mineral assemblages: (1) Quartz-Biotite-Potassium Feldspar assemblage (Q-B-K), which consists essentially of the original metamorphic silicate assemblage plus anomalously high amounts of modal tourmaline (2) Quartz-Biotite-Tourmaline assemblage (Q-B-T) (3) Tourmaline-Quartz-Muscovite assemblage (T-Q-M) (4) Tourmaline-Quartz assemblage (T-Q). Alkali elements (Cs, Rb, K, Li), SiO 2, and Ba show a decrease from the Q-B-K assemblage to the T-Q assemblage. A1 2O 3, Ga, B, total Fe and Zn increase moderately from the Q-B-K assemblage to the T-Q assemblage. The mineral chemistries also change considerably. The Mg/(Mg + Fe 2+) ratios in biotites range from 0.54 to 0.50 in samples from the Q-B-K assemblage to 0.39 in the (Q-B-T) assemblage. The range in tourmaline end-member components from the Q-B-K assemblage to the T-Q assemblage is as follows: Q-B-K: Dravite .63 Schorl .23 Elbaite .05 Buergerite .09 T-Q: Dravite .23 Schorl .37 Elbaite .17 Buergerite .23. Observed variations in mineral assemblage and whole rock chemistry within the alteration zone appear to a first approximation to be a function of μB2O3 (boron metasomatism) and μK2O (alkali leaching). The breakdown of feldspar and biotite may be approximated by reactions: 2HCl + 2(K, Na)AlSi 3O 8 /ai 2(K, Na)Cl + Al 2SiO 5 + 5SiO 2 + H 2O and 2 Annite + SiO 2 + 5Al 2SiO 5 + 2NaCl + 6H 3BO 3 /ai 2 Tourmaline + 2KCl + 7H 2O. The alteration zone may represent either a single episode (B-, Cs-, Li-, Rb-enriched fluid) or multiple episodes (B, Zn, Mn fluid and Cs, Li, Rb fluid) of pegmatite fluid-schist interactions. In both situations, B in the aqueous fluid from the pegmatite reacts with the schist breaking down sheet silicate "traps" for Cs, Rb, Li, and K and forming tourmaline-rich assemblages.

Pegmatite/wallrock interactions, Black Hills, South Dakota: Progressive boron metasomatism adjacent to the Tip Top pegmatite

USGS Publications Warehouse

Shearer, C.K.; Papike, J.J.; Simon, S.B.; Laul, J.C.; Christian, R.P.

1984-01-01

Interaction between country rock and fluids derived from the Tip Top pegmatite has resulted in a series of boron enriched assemblages. Between unaltered quartz-mica schist to the pegmatite contact is a succession of four mineral assemblages: 1. (1) Quartz-Biotite-Potassium Feldspar assemblage (Q-B-K), which consists essentially of the original metamorphic silicate assemblage plus anomalously high amounts of modal tourmaline 2. (2) Quartz-Biotite-Tourmaline assemblage (Q-B-T) 3. (3) Tourmaline-Quartz-Muscovite assemblage (T-Q-M) 4. (4) Tourmaline-Quartz assemblage (T-Q). Alkali elements (Cs, Rb, K, Li), SiO2, and Ba show a decrease from the Q-B-K assemblage to the T-Q assemblage. A12O3, Ga, B, total Fe and Zn increase moderately from the Q-B-K assemblage to the T-Q assemblage. The mineral chemistries also change considerably. The Mg/(Mg + Fe2+) ratios in biotites range from 0.54 to 0.50 in samples from the Q-B-K assemblage to 0.39 in the (Q-B-T) assemblage. The range in tourmaline end-member components from the Q-B-K assemblage to the T-Q assemblage is as follows: Q-B-K: Dravite.63 Schorl.23 Elbaite.05 Buergerite.09 T-Q: Dravite.23 Schorl.37 Elbaite.17 Buergerite.23. Observed variations in mineral assemblage and whole rock chemistry within the alteration zone appear to a first approximation to be a function of ??B2O3 (boron metasomatism) and ??K2O (alkali leaching). The breakdown of feldspar and biotite may be approximated by reactions: 2HCl + 2(K, Na)AlSi3O8 /ai 2(K, Na)Cl + Al2SiO5 + 5SiO2 + H2O and 2 Annite + SiO2 + 5Al2SiO5 + 2NaCl + 6H3BO3 /ai 2 Tourmaline + 2KCl + 7H2O. The alteration zone may represent either a single episode (B-, Cs-, Li-, Rb-enriched fluid) or multiple episodes (B, Zn, Mn fluid and Cs, Li, Rb fluid) of pegmatite fluid-schist interactions. In both situations, B in the aqueous fluid from the pegmatite reacts with the schist breaking down sheet silicate "traps" for Cs, Rb, Li, and K and forming tourmaline-rich assemblages. ?? 1984.

Low-Temperature Thermochronology of Laramide Ranges in Montana and Wyoming Provides Information on Exhumation and Tectonics Associated with Flat-Slab Subduction

NASA Astrophysics Data System (ADS)

Armenta, M.; Carrapa, B.; DeCelles, P. G.

2014-12-01

Timing of exhumation of Laramide basement uplifts can be used as a proxy for tectonic processes associated with thick-skinned deformation resulting from flat-slab subduction. Despite its significance, the timing and pattern of Laramide deformation remains poorly constrained in Montana. Thermochronological data from Wyoming indicate exhumation of Laramide ranges during the late Cretaceous and Paleogene. Whereas a few data exist for the Bearthooth Range in Montana; the exhumation history of most of the Montana ranges remains unexplored preventing testing of current tectonic models. We report apatite fission track thermochronologic (AFT) data from modern river sands derived from Laramide ranges, bedrock basement samples, and synorogenic conglomerate clasts to determine the regional exhumation history of the Beartooth, Gravelly, Tobacco Root, Ruby, the Highland Mountains, and the Wind River Range. AFT permits reconstruction of thermal histories and rates of erosion of the upper few kilometers of the crust. In particular detrital AFT of river sands provides information on regional exhumation of the drainage area. AFT detrital ages derived from the southern end of the Beartooth Range are dominated by a 60-80 Ma signal, consistent with ages reported for bedrock basement samples in the Beartooth Range. A Cenozoic synorogenic conglomerate clast was obtained from the Highland Mountains, AFT results show a 69.56 +/- 5.45 Ma cooling age. In the Wind River Range, Wyoming AFT data from a Cenozoic synorogenic conglomerate clast from the Wind River Formation indicates a 59.32 +/- 4.83 Ma cooling age. This age is consistent with AFT ages from Gannett Peak indicating rapid cooling at ~60 Ma and ~50 Ma (Fan and Carrapa, 2014). Overall, samples from the easternmost ranges, the Beartooth and Bighorn, clearly preserve a Cretaceous signal; samples from Wind River Range and the rest of southwest Montana mainly record a Cenozoic signal. This suggests deeper and younger exhumation to the

New thermochronological constraints on the timing of shear from the Khlong Marui and Ranong faults, Peninsular Thailand: implications for Himalayan lateral extrusion.

NASA Astrophysics Data System (ADS)

Watkinson, I.; Elders, C.; Hall, R.

2009-04-01

New Ar-Ar data from the strike-slip faults of Peninsular Thailand indicate rapid uplift of mid-crustal ductile shear zones during the Eocene. The cooling ages are consistent with a northwards younging pattern of Ar-Ar cooling ages from the NW-trending Three Pagodas and Mae Ping faults in Northern Thailand, to the Ailao Shan-Red River fault in Vietnam and Yunnan, taken to reflect the northwards movement of India during the Cenozoic. The peninsular structures: the Khlong Marui fault (KMF) and Ranong fault (RF), are major NNE trending strike-slip faults of respectively 220 km and 420 km length. Exposed mylonitic rocks bear consistently dextral kinematic indicators, unlike the sinistral mylonites of the NW-trending structures to the north. Brittle strike-slip and dip-slip faults overprint all the shear zones. Rocks ranging from low grade mylonites to syn-kinematic amphibolite facies migmatites from the RF and KMF yield similar biotite Ar-Ar cooling ages, suggesting that uplift from all depths in the shear zone was rapid. Retrograde shear fabrics in places show that dextral shear may have continued during uplift. While the new thermochronological data show that the peninsular mylonites cooled during the Eocene, constraint from pre- and post-kinematic granitoids strongly suggests that ductile shear occurred during the Late-Cretaceous to Paleocene. Since this is well before the onset of India-Eurasia collision, much of the ductile shear must pre-date that orogeny, and therefore cannot be related to Himalayan lateral extrusion, as has been speculated. The regional cooling pattern, however, shows that Indian indentation may have triggered progressive northward exhumation of mylonitic rocks. If the model of the peninsular faults is applied to the NW-trending faults in northern Thailand, then a pre-Himalayan history may also be recorded by those mylonites, rather than a simple, lateral extrusion-related history.

Evidence for Late-Paleozoic brine migration in Cambrian carbonate rocks of the central and southern Appalachians: Implications for Mississippi Valley-type sulfide mineralization

USGS Publications Warehouse

Hearn, P.P.; Sutter, J.F.; Belkin, H.E.

1987-01-01

Many Lower Paleozoic limestones and dolostones in the Valley and Ridge province of the central and southern Appalachians contain 10 to 25 weight percent authigenic potassium feldspar. This was considered to be a product of early diagenesis, however, 40Ar 39Ar analyses of overgrowths on detrital K-feldspar in Cambrian carbonate rocks from Pennsylvania, Maryland, Virginia, and Tennessee yield Late Carboniferous-Early Permian ages (278-322 Ma). Simple mass balance calculations suggest that the feldspar could not have formed isochemically, but required the flux of multiple pore volumes of fluid through the rocks, reflecting regional fluid migration events during the Late-Paleozoic Alleghanian orogeny. Microthermometric measurements of fluid inclusions in overgrowths on detrital K-feldspar and quartz grains from unmineralized rocks throughout the study area indicate homogenization temperatures from 100?? to 200??C and freezing point depressions of -14?? to -18.5??C (18-21 wt.% NaCl equiv). The apparent similarity of these fluids to fluid inclusions in ore and gangue minerals of nearby Mississippi Valley-type (MVT) deposits suggests that the regional occurrences of authigenic K-feldspar and MVT mineralization may be genetically related. This hypothesis is supported by the discovery of authigenic K-feldspar intergrown with sphalerite in several mines of the Mascot-Jefferson City District, E. Tennessee. Regional potassic alteration in unmineralized carbonate rocks and localized occurrences of MVT mineralization are both explainable by a gravity-driven flow model, in which deep brines migrate towards the basin margin under a hydraulic gradient established during the Alleghanian orogeny. The authigenic K-feldspar may reflect the loss of K during disequilibrium cooling of the ascending brines. MVT deposits are probably localized manifestations of the same migrating fluids, occurring where the necessary physical and chemical traps are present. ?? 1987.

Thermochronological Evidence for Cenozoic Segmentation of Transantarctic Mountains

NASA Astrophysics Data System (ADS)

Zattin, M.; Pace, D.; Andreucci, B.; Rossetti, F.; Talarico, F.

2013-12-01

The Transantarctic Mountains (TAM) represent the boundary between the cratonic East Antarctica and the West Antarctica and are thus related to formation of the Western Antarctic Rift system (WARS). However, temporal relationships between timing of TAM uplift and evolution of the WARS are not clear. The large amount of existing thermochronological data indicate that exhumation of the TAM occurred at different times and extents, with main cooling events in the Early Cretaceous, Late Cretaceous, and early Cenozoic. Uplift of the different segments of the TAM was not recorded according to regular trends along the mountain chain, but instead appears diachronous and without a recognizable spatial pattern. Here we present apatite fission-track (AFT) data from 20 samples, collected from metamorphic and intrusive rocks from the region comprised between the Blue Glacier and the Byrd Glacier. AFT data show a large variety of ages, ranging from 28.0 to 88.8 Ma and without a clear correlation between age and elevation. As a whole, spatial variations suggest a decrease of ages from S to the region of the Koettlitz Glacier, where ages suddenly raise up to Cretaceous values. A marked increase of ages has been detected also south of Darwin Glacier, that is in correspondence of the Britannia Range. Thermal modelling shows that cooling paths are usually composite, with a main cooling event followed by slower cooling to present day temperatures. Time of main cooling event is late Cretaceous for samples from the Britannia Range whereas it is Eocene-Oligocene for samples from Koettlitz and Mulock areas. In any case, cooling rates are always quite low also during periods of enhanced uplift, with values not exceeding 5°C/Ma. These data support the idea of tectonic block segmentation of the TAM during the last phases of exhumation. Most of vertical displacements occurred during the Oligocene across transverse fault zones such as the Discovery Accommodation Zone to the north and the

Generalized Cahn-Hilliard equation for solutions with drastically different diffusion coefficients. Application to exsolution in ternary feldspar

NASA Astrophysics Data System (ADS)

Petrishcheva, E.; Abart, R.

2012-04-01

We address mathematical modeling and computer simulations of phase decomposition in a multicomponent system. As opposed to binary alloys with one common diffusion parameter, our main concern is phase decomposition in real geological systems under influence of strongly different interdiffusion coefficients, as it is frequently encountered in mineral solid solutions with coupled diffusion on different sub-lattices. Our goal is to explain deviations from equilibrium element partitioning which are often observed in nature, e.g., in a cooled ternary feldspar. To this end we first adopt the standard Cahn-Hilliard model to the multicomponent diffusion problem and account for arbitrary diffusion coefficients. This is done by using Onsager's approach such that flux of each component results from the combined action of chemical potentials of all components. In a second step the generalized Cahn-Hilliard equation is solved numerically using finite-elements approach. We introduce and investigate several decomposition scenarios that may produce systematic deviations from the equilibrium element partitioning. Both ideal solutions and ternary feldspar are considered. Typically, the slowest component is initially "frozen" and the decomposition effectively takes place only for two "fast" components. At this stage the deviations from the equilibrium element partitioning are indeed observed. These deviations may became "frozen" under conditions of cooling. The final equilibration of the system occurs on a considerably slower time scale. Therefore the system may indeed remain unaccomplished at the observation point. Our approach reveals the intrinsic reasons for the specific phase separation path and rigorously describes it by direct numerical solution of the generalized Cahn-Hilliard equation.

Coupled alkali feldspar dissolution and secondary mineral precipitation in batch systems: 4. Numerical modeling of kinetic reaction paths

NASA Astrophysics Data System (ADS)

Zhu, Chen; Lu, Peng; Zheng, Zuoping; Ganor, Jiwchar

2010-07-01

This paper explores how dissolution and precipitation reactions are coupled in batch reactor experimental systems at elevated temperatures. This is the fourth paper in our series of "Coupled Alkali Feldspar Dissolution and Secondary Mineral Precipitation in Batch Systems". In our third paper, we demonstrated via speciation-solubility modeling that partial equilibrium between secondary minerals and aqueous solutions was not attained in feldspar hydrolysis batch reactors at 90-300 °C and that a strong coupling between dissolution and precipitation reactions follows as a consequence of the slower precipitation of secondary minerals ( Zhu and Lu, 2009). Here, we develop this concept further by using numerical reaction path models to elucidate how the dissolution and precipitation reactions are coupled. Modeling results show that a quasi-steady state was reached. At the quasi-steady state, dissolution reactions proceeded at rates that are orders of magnitude slower than the rates measured at far from equilibrium. The quasi-steady state is determined by the relative rate constants, and strongly influenced by the function of Gibbs free energy of reaction ( ΔG) in the rate laws. To explore the potential effects of fluid flow rates on the coupling of reactions, we extrapolate a batch system ( Ganor et al., 2007) to open systems and simulated one-dimensional reactive mass transport for oligoclase dissolution and kaolinite precipitation in homogeneous porous media. Different steady states were achieved at different locations along the one-dimensional domain. The time-space distribution and saturation indices (SI) at the steady states were a function of flow rates for a given kinetic model. Regardless of the differences in SI, the ratio between oligoclase dissolution rates and kaolinite precipitation rates remained 1.626, as in the batch system case ( Ganor et al., 2007). Therefore, our simulation results demonstrated coupling among dissolution, precipitation, and flow rates

Linking time-Temperature history of the Aquitaine basin with post-orogenic evolution of the Pyrenees : new insights from borehole thermochronology

NASA Astrophysics Data System (ADS)

Fillon, Charlotte; Calassou, Sylvain; Mouthereau, Frédéric; Pik, Raphaël; Bellahsen, Nicolas; Gautheron, Cécile

2017-04-01

Within their sedimentary record, foreland basins document vertical movements of the lithosphere, climatic changes, paleogeograhic evolution but also history of exhumation of the adjacent mountain belt. Comparing vertical movements in a range and in its foreland is key to identify processes involved in growth and destruction of mountain belts. The Aquitaine basin, geomorphologically stable since the early Pyrenean orogenesis has the potential to help understanding the driving mechanisms during the late to post-orogenic phases, but the lack of outcrops makes the studies particularly difficult to achieve. To bring a new point of vue on the processes involved in the Cenozoic exhumation of this range, we present new low-Temperature thermochronology data from boreholes of the Aquitaine basin. With the objectives to study rift-related to post-orogenic processes, numerous low-T thermochronological ages ( 300 across the range) have been published, documenting pre-, syn- , and post-orogenic exhumation in the Pyrenees. Using thermal modeling of a new low-T database in the western Axial Zone, we show that a late Miocene (around 10 Ma) uplift occured in the western Pyrenees, which generalizes the post-orogenic signal already detected in the south central Pyrenees. In previous studies, we linked the post-orogenic exhumation in the Southern Pyrenees to the excavation of the foreland valleys caused by the opening of the endorheic Ebro basin towards the Mediterranean Sea. To the West, the tectonic out-of sequence reactivation of the Gavarnie thrust has been invoked to explain the late Miocene AHe ages in the Bielsa massif. These new data might lead us to re-think the causes for such an exhumation signal during "post-orogenic" times. We thus summarize all evidences for the post-orogenic phase and attempt to provide explanation for it: is exhumation driven by Aquitaine foreland basin evolution? Does it reflect a tectonic reactivation of the Pyrenees? or is the signature of a regional

In situ dating on Mars: A new approach to the K-Ar method utilizing cosmogenic argon

NASA Astrophysics Data System (ADS)

Cassata, William S.

2014-01-01

Cosmogenic argon isotopes are produced in feldspars via nuclear reactions between cosmic rays and Ca and K atoms within the lattice. These cosmogenic isotopes can be used as proxies for K and Ca, much like nuclear reactor-derived 39Ar and 37Ar are used as proxies for K and Ca, respectively, in 40Ar/39Ar geochronology. If Ca and K are uniformly distributed, then the ratio of radiogenic 40Ar (40Ar*) to cosmogenic 38Ar or 36Ar (38Arcos or 36Arcos) is proportional to the difference between the radioisotopic and exposure ages, as well as the K/Ca ratio of the degassing phase. Thus cosmogenic, radiogenic, and trapped Ar isotopes, all of which can be measured remotely and are stable over geologic time, are sufficient to generate an isochron-like diagram from which the isotopic composition of the trapped component may be inferred. Such data also provide a means to assess the extent to which the system has remained closed with respect to 40Ar*, thereby mitigating otherwise unquantifiable uncertainties that complicate the conventional K-Ar dating method.

Petrogenesis of mid-Miocene rhyolites from the Idaho-Oregon-Nevada region, USA: Implications from feldspar Sr and Pb isotope data

NASA Astrophysics Data System (ADS)

Wypych, A.; Hart, W. K.

2012-12-01

The Idaho-Oregon-Nevada (ION) region provides an excellent natural laboratory for studying the complex processes that form continental crust. During the Oligocene-Miocene, the ION region underwent widespread extension and volcanism with bimodal (silicic and mafic) volcanism dominating the mid-Miocene [1]. This bimodal volcanism is temporally related to the main Columbia River flood basalt activity to the north, and initiated with mafic eruptions at ~17 Ma, followed closely by silicic magmatism at ~16.5 Ma. This intimate link between mafic and silicic activity continued until ~13 Ma. The ION region is situated on a boundary between Proterozoic cratonic lithosphere to the east and Mesozoic accreted terrains to the west as defined by Sr and Nd isotopic compositions. In this region, however, the boundary is not sharp and distinctive, but rather forms a heterogeneous "transitional zone" between the two lithospheric domains. Another feature adding to the complexity of this region is the fact that it lies at the junction of two major volcanic trends: the Snake River Plain- Yellowstone (SRP-Y) progressing in time and space to the northeast and the High Lava Plains - Newberry (HPL-N) progressing to the northwest. The ION region volcanism as well as the SRP-Y and HLP-N volcanic trends is caused by mantle upwelling behind the subducting Juan de Fuca slab, voluminous mafic magma injections into the crust, melting of spatially, temporally, and compositionally heterogeneous crust, and mixing of the primitive and more evolved products [1,2,3]. An ongoing petrographic, major and trace element and Sr-Nd-Pb-Hf isotope investigation of 24 pairs of glass separates and whole rock samples from five ION silicic centers representing a west (off-craton) to east (on-craton) transect across this zone of transitional lithosphere provides evidence of open system processes involved in the production of the silicic material as well as spatial, temporal and compositional diversity within and

Dissolution kinetics as a function of the Gibbs free energy of reaction: An experimental study based on albite feldspar

NASA Astrophysics Data System (ADS)

Hellmann, Roland; Tisserand, Delphine

2006-01-01

Here we report on an experimental investigation of the relation between the dissolution rate of albite feldspar and the Gibbs free energy of reaction, Δ Gr. The experiments were carried out in a continuously stirred flow-through reactor at 150 °C and pH (150 °C) 9.2. The dissolution rates R are based on steady-state Si and Al concentrations and sample mass loss. The overall relation between Δ Gr and R was determined over a free energy range of -150 < Δ Gr < -15.6 kJ mol -1. The data define a continuous and highly non-linear, sigmoidal relation between R and Δ Gr that is characterized by three distinct free energy regions. The region furthest from equilibrium, delimited by -150 < Δ Gr < -70 kJ mol -1, represents an extensive dissolution rate plateau with an average rate R¯=1.0×10-8molm-2s-1. In this free energy range the rates of dissolution are constant and independent of Δ Gr, as well as [Si] and [Al]. The free energy range delimited by -70 ⩽ Δ Gr ⩽ -25 kJ mol -1, referred to as the 'transition equilibrium' region, is characterized by a sharp decrease in dissolution rates with increasing Δ Gr, indicating a very strong inverse dependence of the rates on free energy. Dissolution nearest equilibrium, defined by Δ Gr > -25 kJ mol -1, represents the 'near equilibrium' region where the rates decrease as chemical equilibrium is approached, but with a much weaker dependence on Δ Gr. The lowest rate measured in this study, R = 6.2 × 10 -11 mol m -2 s -1 at Δ Gr = -16.3 kJ mol -1, is more than two orders of magnitude slower than the plateau rate. The data have been fitted to a rate equation (adapted from Burch et al. [Burch, T. E., Nagy, K. L., Lasaga, A. C., 1993. Free energy dependence of albite dissolution kinetics at 80 °C and pH 8.8. Chem. Geol.105, 137-162]) that represents the sum of two parallel reactions R=k1[1-exp(-ng)]+k2[1-exp(-g)], where k1 and k2 are rate constants that have been determined by regression, with values 1.02 × 10 -8 and 1

Feldspar palaeo-isochrons from early Archaean TTGs: Pb-isotope evidence for a high U/Pb terrestrial Hadean crust

NASA Astrophysics Data System (ADS)

Kamber, B. S.; Whitehouse, M. J.; Moorbath, S.; Collerson, K. D.

2001-12-01

Feldspar lead-isotope data for 22 early Archaean (3.80-3.82 Ga) tonalitic gneisses from an area south of the Isua greenstone belt (IGB),West Greenland, define a steep linear trend in common Pb-isotope space with an apparent age of 4480+/-77 Ma. Feldspars from interleaved amphibolites yield a similar array corresponding to a date of 4455+/-540 Ma. These regression lines are palaeo-isochrons that formed during feldspar-whole rock Pb-isotope homogenisation a long time (1.8 Ga) after rock formation but confirm the extreme antiquity (3.81 Ga) of the gneissic protoliths [1; this study]. Unlike their whole-rock counterparts, feldspar palaeo-isochrons are immune to rotational effects caused by the vagaries of U/Pb fractionation. Hence, comparison of their intercept with mantle Pb-isotope evolution models yields meaningful information regarding the source history of the magmatic precursors. The locus of intersection between the palaeo-isochrons and terrestrial mantle Pb-isotope evolution lines shows that the gneissic precursors of these 3.81 Ga gneisses were derived from a source with a substantially higher time-integrated U/Pb ratio than the mantle. Similar requirements for a high U/Pb source have been found for IGB BIF [2], IGB carbonate [3], and particularly IGB galenas [4]. Significantly, a single high U/Pb source that separated from the MORB-source mantle at ca. 4.3 Ga with a 238U/204Pb of ca. 10.5 provides a good fit to all these observations. In contrast to many previous models based on Nd and Hf-isotope evidence we propose that this reservoir was not a mantle source but the Hadean basaltic crust which, in the absence of an operating subduction process, encased the early Earth. Differentiation of the early high U/Pb basaltic crust could have occurred in response to gravitational sinking of cold mantle material or meteorite impact, and produced zircon-bearing magmatic rocks. The subchondritic Hf-isotope ratios of ca. 3.8 Ga zircons support this model [5] provided that

Contribution of feldspar and marine organic aerosols to global ice nucleating particle concentrations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vergara-Temprado, Jesús; Murray, Benjamin J.; Wilson, Theodore W.

Ice-nucleating particles (INPs) are known to affect the amount of ice in mixed-phase clouds, thereby influencing many of their properties. The atmospheric INP concentration changes by orders of magnitude from terrestrial to marine environments, which typically contain much lower concentrations. Many modelling studies use parameterizations for heterogeneous ice nucleation and cloud ice processes that do not account for this difference because they were developed based on INP measurements made predominantly in terrestrial environments without considering the aerosol composition. Errors in the assumed INP concentration will influence the simulated amount of ice in mixed-phase clouds, leading to errors in top-of-atmosphere radiativemore » flux and ultimately the climate sensitivity of the model. Here we develop a global model of INP concentrations relevant for mixed-phase clouds based on laboratory and field measurements of ice nucleation by K-feldspar (an ice-active component of desert dust) and marine organic aerosols (from sea spray). The simulated global distribution of INP concentrations based on these two species agrees much better with currently available ambient measurements than when INP concentrations are assumed to depend only on temperature or particle size. Underestimation of INP concentrations in some terrestrial locations may be due to the neglect of INPs from other terrestrial sources. Our model indicates that, on a monthly average basis, desert dusts dominate the contribution to the INP population over much of the world, but marine organics become increasingly important over remote oceans and they dominate over the Southern Ocean. However, day-to-day variability is important. Because desert dust aerosol tends to be sporadic, marine organic aerosols dominate the INP population on many days per month over much of the mid- and high-latitude Northern Hemisphere. This study advances our understanding of which aerosol species need to be included in order

Characterization and Thermodynamics Studies of Feldspar and Feldspathoid Minerals

NASA Astrophysics Data System (ADS)

Rudow, M.; Lilova, K.

2015-12-01

The application of thermal analysis and calorimetry for the studies of minerals has a history as long as the existence of the thermal methods themselves. New advanced calorimetric techniques have been developed for more accurate characterization of both bulk and nano materials thus impacting their design, processing, and applications. TG-DTA and TG-DSC are used to characterize the composition of complex minerals (e.g. [KxNa1-x(AlSi3)O8]) based on the weight changes and phase transformations observed with temperature increase. Additionally, those techniques allow to determine the quantity of the different types of water contained in natural feldspars and feldspathoids (absorbed, interlayer, structural). The results for several clays will be discussed. The geochemical properties and thermal stability of another class of minerals - aluminosilicate frameworks (alkali sodalities, natrolites, etc.) as related to high-level nuclear waste treatment facilities, radioactive waste storage and management were studied. The natural sodalite Na8[Al6Si6O24]Cl2 and similar frameworks with different anions are part of sodium-aluminosilicate (NAS) low activity radioactive waste produced during steam reforming process treatment. The enthalpies and entropies of formation and the hydration enthalpies of the above-mentioned feltspathoids are obtained and the effect of the different cations and anions on the thermodynamic stability was studied. The results will allow to predict the long term behavior of the compounds in the environment under different conditions.

Petrography and geochemistry of distal spherules from the K-Pg boundary in the Umbria-Marche region (Italy) and their origin as fractional condensates and melts in the Chicxulub impact plume

NASA Astrophysics Data System (ADS)

Belza, J.; Goderis, S.; Montanari, A.; Vanhaecke, F.; Claeys, P.

2017-04-01

The impact spherules from the distal K-Pg boundary sections are considered to represent silicate droplets condensed and solidified from a laterally expanding, cooling vapor plume formed upon hypervelocity impact. In the present-day Cretaceous-Paleogene boundary (K-Pg) spherule population of the Umbria-Marche region in Italy, three texturally and compositionally distinct types of impact spherules can be identified that are dominantly composed of (1) goethite, (2) K-feldspar or (3) glauconite. Although these phases represent the products of diagenetic alteration, the remnant textural characteristics of the spherules and the type of alteration product are indicative of the spherules' original compositions, which are important to constrain the physicochemical conditions prevalent throughout the impact vapor plume. The presence of relict ghost crystals and the identification of 'iddingsite' indicate that goethite likely represents pseudomorphic replacement after olivine. Goethite spherules contain numerous dendritic, euhedral and skeletal spinel crystals variably dispersed in the groundmass. In terms of textures, five types of goethite spherules can be distinguished, showing striking similarities to chondrules: (I) skeletal, (II) barred, (III) radial/barred, (IV) porphyritic and (V) relict/granular. The morphology of both spinel and olivine (pseudomorphs) is consistent with established formation conditions (peak temperature Tmax, degree of supercooling ΔT, cooling rate, presence of nucleation sites) for different chondrule textural types. As goethite spherules are anomalously enriched in moderately to highly refractory lithophile (Sc, V, Y, Zr, Nb, REE, Hf, Ta, Th) and siderophile (Cr, Co, Ni, W, Ir, Pt) elements, they are interpreted to represent (diagenetically altered) refractory (high-T) condensation products from a well-homogenized plume consisting of both vaporized target and projectile matter. Different from goethite spherules, K-feldspar spherules exhibit

Chemical Zoning of Feldspars in Lunar Granitoids: Implications for the Origins of Lunar Silicic Magmas

NASA Technical Reports Server (NTRS)

Mills, R. D; Simon, J. I.; Alexander, C.M. O'D.; Wang, J.; Christoffersen, R.; Rahman, Z..

2014-01-01

Fine-scale chemical and textural measurements of alkali and plagioclase feldspars in the Apollo granitoids (ex. Fig. 1) can be used to address their petrologic origin(s). Recent findings suggest that these granitoids may hold clues of global importance, rather than of only local significance for small-scale fractionation. Observations of morphological features that resemble silicic domes on the unsampled portion of the Moon suggest that local, sizable net-works of high-silica melt (>65 wt % SiO2) were present during crust-formation. Remote sensing data from these regions suggest high concentrations of Si and heat-producing elements (K, U, and Th). To help under-stand the role of high-silica melts in the chemical differentiation of the Moon, three questions must be answered: (1) when were these magmas generated?, (2) what was the source material?, and (3) were these magmas produced from internal differentiation. or impact melting and crystallization? Here we focus on #3. It is difficult to produce high-silica melts solely by fractional crystallization. Partial melting of preexisting crust may therefore also have been important and pos-sibly the primary mechanism that produced the silicic magmas on the Moon. Experimental studies demonstrate that partial melting of gabbroic rock under mildly hydrated conditions can produce high-silica compositions and it has been suggested by that partial melting by basaltic underplating is the mechanism by which high-silica melts were produced on the Moon. TEM and SIMS analyses, coordinated with isotopic dating and tracer studies, can help test whether the minerals in the Apollo granitoids formed in a plutonic setting or were the result of impact-induced partial melting. We analyzed granitoid clasts from 3 Apollo samples: polymict breccia 12013,141, crystalline-matrix breccia 14303,353, and breccia 15405,78

New Constraints for Tectono-Thermal Alpine Evolution of the Pyrenees: Combining Zircon Fission-Track and (U-Th)/He Analyses with Raman Spectrometry and In-Situ K-Ar Geochronology

NASA Astrophysics Data System (ADS)

Waldner, M.; Bellahsen, N.; Mouthereau, F.; Pik, R.; Bernet, M.; Scaillet, S.; Rosenberg, C.

2017-12-01

The pyrenean range was formed by the convergence of European and Iberian plates following the inversion of the Mesozoic rifting in the north of Pyrenees. In the Axial Zone, the collision caused an antiformal nappe-stacking of tectonic units. Recent studies pointed out the importance of pre-collision structural and thermal inheritance that may play a major role for orogeny such as: 1) Paleozoic Variscan inheritance; 2) Mesozoic rift-related high geothermal gradients, which are maintained during the onset of convergence in the North Pyrenean Zone. From a mineralogical point of view, pre-collision feldspars have been destabilized and influenced the development of alpine phyllonite in brittle-ductile conditions which suggests a weak crustal behavior during the formation of the orogenic wedge. Our aim is to get a better understanding of alpine deformation and exhumation by coupling different thermochronological, geochronological and thermometric methods. We document the thermal evolution of each tectonic unit by using low-temperature thermochronometers (Zircon Fission Tracks, U-Th/He on zircons including laser ablation profiles). Our data on vertical profiles combined to existing dataset on apatite allows to model alpine exhumation across the Axial zone. Structural observations through alpine thrusts coupled to geochronology (in situ K/Ar on phengites), Raman and chlorite-phengite thermo(baro)metry provide new key data to unravel the alpine evolution of the Pyrenees. According to preliminary ZFT results on granite massifs in the central part of Pyrenean Axial zone (near ECORS profile), exhumation ages potentially indicates a migration of exhumation towards the south. Exhumation ages of the northern massifs seems to have preserved the North Pyrenean Cretaceous rift evolution. Further south, the onset of exhumation is as old as Paleocene, which precedes the Eocene ages of the literature. The low burial estimated in the northern massifs may indicate a high thermal gradient

Petrological features of selected components of the Cergowa sandstones (Outer Carpathians) recorded by scanning electron microscopy - preliminary study

NASA Astrophysics Data System (ADS)

Pszonka, Joanna

2017-11-01

The scanning electron microscope analysis of the Cergowa sandstones brings new data on their petrological features and chemical composition. Previous work in standard petrographic examination, e.g. polarising (PL) or cathodoluminescence (CL) microscopy, displayed limited information on grain surface topography and only assumptions to their geochemistry. Both identification and characterisation of minerals are fundamental in the progress of mining and minerals processing systems. Detrital grains of the Cergowa sandstones are bound by calcite and dolomitic cement and commonly corroded by diagenetic fluids, however, in varying degrees, which is illustrated here by feldspar, quartz and dolomite minerals. Dissolution processes of marginal parts of these mineral grains resulted in corrosion, which increased the contact surface between the grains and the cement. The difference in resistance to these processes was observed not only among distinct groups of minerals, but also within the group of feldspars: between K-feldspars and minerals of plagioclase. That combination resulted in exceptionally strong cementation of the Cergowa sandstones, which is expressed by their high hardness and resistance to abrasion, freezing, and thawing. Inherent parameters of sandstones are characterised by their petrographical properties.

Mesozoic fault reactivation along the St. Lawrence Rift System as constrained by (U-Th/He) thermochronology

NASA Astrophysics Data System (ADS)

Bouvier, L.; Pinti, D. L.; Tremblay, A.; Minarik, W. G.; Roden-Tice, M. K.; Pik, R.

2011-12-01

The Saint Lawrence Rift System (SLRS) is a half-graben, extending for 1000 km along St. Lawrence River valley. Late Proterozoic-Early Paleozoic faults of the graben form the contact with the metamorphic Grenvillian basement to the northwest and extend under the Paleozoic sedimentary sequences of the St. Lawrence Lowlands to the southeast. The SLRS is the second most seismically active area in Canada, but the causes of this activity remain unclear. Reactivation of the SLRS is believed to have occurred along Late Proterozoic to Early Paleozoic normal faults related to the opening of the Iapetus Ocean. The absence of strata younger than the Ordovician makes difficult to determine when the faults reactivated after the Ordovician. Field relations between the normal faults bordering the SLRS and those produced by the Charlevoix impact crater suggest a reactivation of the rift younger than the Devonian, the estimated age of the impact. Apatite (U-Th)/He thermochronology is an adequate tool to recognize thermal events related to fault movements. A thermochronology study was then started along three transects across the SLRS, from Québec up to Charlevoix. Apatites were extracted and separated from five granitic to charnockitic gneisses and an amphibolite of Grenvillian age. The samples were exposed on hanging wall and footwall of the Montmorency and Saint-Laurent faults at three different locations along the SLRS. For precision and accuracy, each of the six samples was analyzed for radiogenic 4He and U-Th contents at least twice. Apatite grains were isolated by heavy liquids and magnetic separation. For each sample, ten apatite grains were selected under optical microscope and inserted into Pt capsules. Particular care was taken to isolate apatite free of mineral and fluid inclusions. Indeed, SEM investigations showed that some inclusions are U-rich monazite, which is a supplementary source of 4He to be avoided. The 4He content was determined by using a static noble gas

Low temperature thermochronology in the Eastern Alps: Implications for structural and topographic evolution

PubMed Central

Wölfler, Andreas; Stüwe, Kurt; Danišík, Martin; Evans, Noreen J.

2012-01-01

According to new apatite fission track, zircon- and apatite (U–Th)/He data, we constrain the near-surface history of the southeastern Tauern Window and adjacent Austrolapine units. The multi-system thermochronological data demonstrate that age-elevation correlations may lead to false implications about exhumation and cooling in the upper crust. We suggest that isothermal warping in the Penninic units that are in the position of a footwall, is due to uplift, erosion and the buildup of topography. Additionally we propose that exhumation rates in the Penninic units did not increase during the Middle Miocene, thus during the time of lateral extrusion. In contrast, exhumation rates of the Austroalpine hangingwall did increase from the Paleogene to the Neogene and the isotherms in this unit were not warped. The new zircon (U–Th)/He ages as well as zircon fission track ages from the literature document a Middle Miocene exhumation pulse which correlates with a period of enhanced sediment accumulation during that time. However, enhanced sedimentation- and exhumation rates at the Miocene/Pliocene boundary, as observed in the Western- and Central Alps, cannot be observed in the Eastern Alps. This contradicts a climatic trigger for surface uplift, and makes a tectonic trigger and/or deep-seated mechanism more obvious to explain surface uplift in the Eastern Alps. In combination with already published geochronological ages, our new data demonstrate Oligocene to Late Miocene fault activity along the Möll valley fault that constitutes a major shear zone in the Eastern Alps. In this context we suggest a geometrical and temporal relationship of the Katschberg-, Polinik–Möll valley- and Mur–Mürz faults that define the extruding wedge in the eastern part of the Eastern Alps. Equal deformation- and fission track cooling ages along the Katschberg–Brenner- and Simplon normal faults demonstrate overall Middle Miocene extension in the whole alpine arc. PMID:27065501

Detrital Thermochronology Record of the Local-to-Extraregional Provenance Shift Recorded by the Northern Peninsular Ranges Forearc

NASA Astrophysics Data System (ADS)

Flores, M.; Shulaker, D. Z.

2016-12-01

Previously measured detrital zircon U-Pb age distributions have revealed that Late Cretaceous to Eocene forearc strata in the Santa Ana mountains region experienced a dramatic shift in sedimentary provenance from a 125-90 Ma northern Peninsular Ranges batholith (PRB) source region along the continental margin to a cratonal source area intruded by Late Cretaceous (85-75 Ma) plutons within the continental interior (western Sonora). To improve our understanding of the timing and magnitude of denudation prior to, and during this local to extraregional provenance shift, we have measured new detrital K-feldspar 40Ar/39Ar total fusion and zircon U-Pb age distributions from forearc sandstones. Our combined crystallization age and thermal history results confirm two pulses of rapid denudation of the PRB. These include a syn-batholith phase (Cenomanian) and a post-batholithic (Maastrichtian to Paleocene) phase attributed to shallow subduction. The new data require that significant (5-10 km) syn-batholithic erosional denudation of the northern PRB had already occurred by ca. 95 Ma and that post-emplacement denudation of the PRB accelerated again during the Maastrichtian with the eastern PRB providing the bulk of the detritus. Our new results demonstrate that deposition of the Paleocene Silverado Fm. occurred during a transitional period. Sand reaching the forearc during the Paleocene was derived from both the heavily denuded eastern PRB with additional input supplied either from Late Cretaceous plutons of northwestern Sonoran region and/or similar plutons emplaced in thrust sheets atop PRB basement within the Santa Rosa Mountains. In contrast, the Eocene Santiago Fm. was nearly entirely derived from extraregional sources that supplied abundant late Cretaceous (75-85 Ma) and Proterozoic (1.4 & 1.7 Ga) detritus with virtually no PRB-derived sediment detected.

Thermochronological Record of a Jurassic Heating-Cooling Cycle Within a Distal Rifted Margin (Calizzano Massif, Ligurian Alps)

NASA Astrophysics Data System (ADS)

Seno, S.; Decarlis, A.; Fellin, M. G.; Maino, M.; Beltrando, M.; Ferrando, S.; Manatschal, G.; Gaggero, L.; Stuart, F. M.

2017-12-01

The aim of the present study is to analyse, through thermochronological investigations, the thermal evolution of a fossil distal margin owing to the Alpine Tethys rifting system. The studied distal margin section consists of a polymetamorphic basement (Calizzano basement) and of a well-developed Mesozoic sedimentary cover (Case Tuberto unit) of the Ligurian Alps (NW Italy). The incomplete reset of zircon (U-Th)/He ages and the non-reset of the zircon fission track ages during the Alpine metamorphism indicate that during the subduction and the orogenic stages these rocks were subjected to temperatures lower than 200 ºC. Thus, the Alpine metamorphic overprint occurred during a short-lived, low temperature pulse. The lack of a pervasive orogenic reset, allowed the preservation of an older heating-cooling event that occurred during Alpine Tethys rifting. Zircon fission-track data indicate, in fact, that the Calizzano basement records a cooling under 240 °C, at 156 Ma (early Upper Jurassic). This cooling followed a Middle Jurassic syn-rift heating at temperatures of about 300-350°C, typical of greenschist facies conditions occurred at few kilometres depth, as indicated by stratigraphic and petrologic constraints. Thus, in our interpretation, major crustal thinning likely promoted high geothermal gradients ( 60-90°C/km) triggering the circulation of hot, deep-seated fluids along brittle faults, causing the observed thermal anomaly at shallow crustal level.

Micropaleontological and Paleomagnetic Characterization of La Ceiba K/T Boundary Section, Central Mexico

NASA Astrophysics Data System (ADS)

Martínez-López, M.; Urrutia-Fucugauchi, J.

2007-05-01

We report results of a micropaleontological and magnetostratigraphic study of the La Ceiba section that spans the K/T boundary. La Ceiba is located in central Mexico (20o 19.8' N, 97o 41.0' W) within the Tampico-Mizantla basin. The K/T boundary is marked by a clastic unit of about one-meter thickness intercalated between the carbonate hemipelagic marls of the Cretaceous Mendez Formation and the Paleocene Velasco Formation. The clastic unit can be divided into four sub-units, according to their texture and architectural characteristics following Arenillas et al. (2002). The basal sub-unit is formed by calcareous marls and is rich in shocked quartz and millimeter size spherules with microtektites and bioclasts of shallow water origin. The second sub-unit is formed by medium-grained sandstones, with clasts and quartz fragments, feldspars, metamorphic and calcareous fragments and re-worked benthic and planktic foraminifera. The third sub-unit is composed by a single body of medium- to fine-grained sandstones with tabular geometry. In this sub-unit, cross- and parallel-lamination trough cross-stratification, current ripples and climbing ripples have been observed. The top sub-unit is a tabular body of fine-grained sandstones, showing parallel-lamination and low-angle cross-lamination, with asymmetric ripples and burrow traces to the top. For the paleontologic and paleomagnetic study we collected twenty-five oriented samples across the section. We measured the low-field susceptibility, intensity and direction of the NRM. The vectorial composition and stability of NRM were analyzed by progressive thermal and alternating field demagnetization. Vectorial orthogonal diagrams and vector subtraction and principal component analysis were used to determine the characteristic magnetization and secondary components for each sample. The characteristic NRM negative inclination and southward declination in the K/T clastic sediments indicate a reverse polarity, which is correlated to

Oscillating brittle and viscous behavior through the earthquake cycle in the Red River Shear Zone: Monitoring flips between reaction and textural softening and hardening

NASA Astrophysics Data System (ADS)

Wintsch, Robert P.; Yeh, Meng-Wan

2013-03-01

Microstructures associated with cataclasites and mylonites in the Red River shear zone in the Diancang Shan block, Yunnan Province, China show evidence for both reaction hardening and softening at lower greenschist facies metamorphic conditions. The earliest fault-rocks derived from Triassic porphyritic orthogneiss protoliths are cataclasites. Brittle fractures and crushed grains are cemented by newly precipitated quartz. These cataclasites are subsequently overprinted by mylonitic fabrics. Truncations and embayments of relic feldspars and biotites show that these protolith minerals have been dissolved and incompletely replaced by muscovite, chlorite, and quartz. Both K-feldspar and plagioclase porphyroclasts are truncated by muscovite alone, suggesting locally metasomatic reactions of the form: 3K-feldspar + 2H+ = muscovite + 6SiO2(aq) + 2K+. Such reactions produce muscovite folia and fish, and quartz bands and ribbons. Muscovite and quartz are much weaker than the reactant feldspars and these reactions result in reaction softening. Moreover, the muscovite tends to align in contiguous bands that constitute textural softening. These mineral and textural modifications occurred at constant temperature and drove the transition from brittle to viscous deformation and the shift in deformation mechanism from cataclasis to dissolution-precipitation and reaction creep. These mylonitic rocks so produced are cut by K-feldspar veins that interrupt the mylonitic fabric. The veins add K-feldspar to the assemblage and these structures constitute both reaction and textural hardening. Finally these veins are boudinaged by continued viscous deformation in the mylonitic matrix, thus defining a late ductile strain event. Together these overprinting textures and microstructures demonstrate several oscillations between brittle and viscous deformation, all at lower greenschist facies conditions where only frictional behavior is predicted by experiments. The overlap of the depths of

Monitoring Progress: How the 2012 National Survey of Science and Mathematics Education Can Inform a National K-12 STEM Education Indicator System

ERIC Educational Resources Information Center

Fulkerson, William O.; Banilower, Eric R.

2014-01-01

"Monitoring Progress Toward Successful K-12 STEM Education: A Nation Advancing?" (National Research Council, 2013) describes a set of 14 indicators for assessing and tracking the health of pre-college STEM education in the United States. This 2012 National Survey of Science and Mathematics Education (NSSME), is the fifth in a series of…

Interpretation of thermochronological cooling ages using thermal modelling: an example from shallow magma intrusions from the Kerguelen archipelago

NASA Astrophysics Data System (ADS)

Ahadi, Floriane; Delpech, Guillaume; Gautheron, Cécile; Nomade, Sébastien; Zeyen, Hermann; Guillaume, Damien

2017-04-01

Low temperature thermochronology on plutonic rocks is traditionally used to calculate erosion rates over large time scale. However, this method requires a good knowledge of the local or regional geology and particularly the thermal structure and evolution of the crust. The Kerguelen Islands (48-50°S, 68/5-70.5°E, Indian Ocean) are the emerged part of a vast oceanic plateau and are mostly made up of Oligocene basaltic traps that are cross cut by a dense network of large and deep valleys. Numerous plutonic complexes of various age (20-4.5 Ma) locally intrude theses traps and cover about 15% of the main island's surface. The Rallier du Baty peninsula is the largest plutonic complex, it is mainly constituted of syenites and is divided into two adjacent circular plutonic complexes whose centres are distant of 15 km. The southern part has a laccolith structure with satellites plutons and was emplaced at shallow depth (about 1 to 3 km) between 13.7 ± 0.3 and 8.0 ± 0.2 Ma. The northern part was emplaced later between 7.8 ± 0.25 and 4.5 ± 0.1 Ma. The Kerguelen Islands are of particular interest to understand the impact of Cenozoïc climatic variations on the long-term geomorphological evolution of emerged reliefs at mid-latitudes. To understand the erosion of the area, we conducted the first study on the Kerguelen Islands using the biotite 40Ar/39Ar (BAr), apatite and zircon (U-Th)/He thermochronometers (AHe and ZHe). In the southern part, the BAr ages for the various intrusions of the complex range from 9.44 ± 0.13 Ma to 13.84 ± 0.07 Ma. These ages are identical to high-temperature crystallisation ages (U-Pb on zircon) indicating an extremely rapid cooling between ˜700 and ˜300°C. The mean ZHe ages range between 7.1 ± 2.3 and 8.8 ± 1.4 and the mean AHe ages range between 4.4 ± 0.3 Ma and 7.4 ± 0.7 Ma. The AHe ages of the southern complex are similar to the crystallization ages of the northern part of the complex. The mean AHe ages in the northern part are

The asymmetric evolution of the Colombian Eastern Cordillera. Tectonic inheritance or climatic forcing? New evidence from thermochronology and sedimentology

NASA Astrophysics Data System (ADS)

Ramirez-Arias, Juan Carlos; Mora, Andrés; Rubiano, Jorge; Duddy, Ian; Parra, Mauricio; Moreno, Nestor; Stockli, Daniel; Casallas, Wilson

2012-11-01

New thermochronological data, facies, paleocurrents and provenance allow us to refine the chronology of deformation in the central segment of the Colombian Eastern Cordillera. Based on a new extensive AFT dataset, we document the spatial evolution of active deformation, from the axial zone of the Eastern Cordillera at about 50 Ma in to active growth of the frontal thin skinned structures in Late Miocene time. Paleocurrents allow us to push backwards into the Middle to Early Late-Miocene the emergence of the easternmost frontal thrust; whereas careful assessment of exposure gates tied to AFT data enable to refine the unroofing history for Eocene to Miocene times. Based on that, we produced a kinematically restored cross section with higher resolution than previous assessments. Using these datasets, we compare the evolution of the central segment of the Eastern Cordillera in this region with the evolution of adjacent areas in the context of climatic forcing of orogenic evolution. We find that in this region and, in the Eastern Cordillera in general, tectonic inheritance and transpression exert an initial dominant control on the initial orogen asymmetry, which is later enhanced due to an orographically-focused erosion. We therefore suggest that it is not climate alone the factor controlling orogenic asymmetry in the Eastern Cordillera of Colombia.

Electron microprobe study of lunar and planetary zoned plagioclase feldspars: An analytical and experimental study of zoning in plagioclase

NASA Technical Reports Server (NTRS)

Smith, R. K.; Lofgren, G. E.

1982-01-01

Natural and experimentally grown zoned plagioclase feldspars were examined by electron microprobe. The analyses revealed discontinuous, sector, and oscillary chemical zoning superimposed on continuous normal or reverse zoning trends. Postulated mechanisms for the origin of zoning are based on either physical changes external to the magma (P, T, H2O saturation) or kinetic changes internal to the magma (diffusion, supersaturation, growth rate). Comparison of microprobe data on natural zoned plagioclase with zoned plagioclase grown in controlled experiments show that it may be possible to distinguish zonal development resulting from physio-chemical changes to the bulk magma from local kinetic control on the growth of individual crystals.

Provenance of sands from the confluence of the Amazon and Madeira rivers based on detrital heavy minerals and luminescence of quartz and feldspar

NASA Astrophysics Data System (ADS)

do Nascimento, Daniel R.; Sawakuchi, André O.; Guedes, Carlos C. F.; Giannini, Paulo C. F.; Grohmann, Carlos H.; Ferreira, Manuela P.

2015-03-01

Source-to-sink systems are poorly known in tropical rivers. For the Amazonian rivers, the majority of the provenance studies remain focused on the suspended load, implying a poor understanding of the processes governing production and distribution of sands. In this study, we perform heavy mineral and optically stimulated luminescence (OSL) analysis to cover the entire spectrum (heavy and light minerals fraction) of 29 sand samples of the Lower Madeira river region (Amazon and Madeira rivers), of which the main goal was to find provenance indicators specific to these rivers. Despite the tropical humid climate, the sands of the Amazon and Lower Madeira rivers are rich in unstable heavy minerals as augite, hypersthene, green hornblende and andalusite. The Madeira river is highlighted by its higher content of andalusite, with source attributed to the Amazon Craton (medium-to-high grade metamorphic rocks), while the Amazon river, upstream of the Madeira river mouth, has a signature of augite and hypersthene, that suggests an Andean provenance (volcanic rocks). Sands from the Madeira river can be tracked in the Amazon river by the increasing concentration in andalusite. OSL analysis of the light minerals fraction was used as an index of feldspar concentration and sedimentary history of quartz grains. Lower feldspar concentration and quartz grains with longer sedimentary history (higher OSL sensitivity) also point to a major contribution of cratonic sources for the sands in the Madeira river. While the sands from the Lower Madeira would be mainly supplied by cratonic rocks, previous work recognised that suspended sediments (silt and clay) are derived from Andean rocks. Therefore, we interpret a decoupling between the sources of sand and mud (silt and clay) under transport in the Madeira river. Andean sands (rich in augite and hypersthene) would be trapped in the foreland zones of the Beni and Mamoré tributaries. In the Amazon river sands, the low OSL sensitivity of the

Laboratory measurements of upwelled radiance and reflectance spectra of Calvert, Ball, Jordan, and Feldspar soil sediments

NASA Technical Reports Server (NTRS)

Whitlock, C. H.; Usry, J. W.; Witte, W. G.; Gurganus, E. A.

1977-01-01

An effort to investigate the potential of remote sensing for monitoring nonpoint source pollution was conducted. Spectral reflectance characteristics for four types of soil sediments were measured for mixture concentrations between 4 and 173 ppm. For measurements at a spectral resolution of 32 mm, the spectral reflectances of Calvert, Ball, Jordan, and Feldspar soil sediments were distinctly different over the wavelength range from 400 to 980 nm at each concentration tested. At high concentrations, spectral differences between the various sediments could be detected by measurements with a spectral resolution of 160 nm. At a low concentration, only small differences were observed between the various sediments when measurements were made with 160 nm spectral resolution. Radiance levels generally varied in a nonlinear manner with sediment concentration; linearity occurred in special cases, depending on sediment type, concentration range, and wavelength.

PRE-ORE POTASSIUM METASOMATISM, CREEDE MINING DISTRICT, COLORADO.

USGS Publications Warehouse

Bethke, P.M.; Rye, R.O.; Barton, P.B.

1985-01-01

Rhyolitic welded-tuff wallrocks of the epithermal base and precious metal veins of the Creede district were pervasively altered by the addition of more than two billion metric tons of potassium some 1. 5-2 million years before mineralization. Sodium, calcium and magnesium were strongly depleted, yielding a nearly binary quartz plus potassium feldspar assemblage containing as much as 13 weight percent K//2O. This large-scale metasomatism, originally noted by Steven and Rattle (1965), took place progressively by initial alteration of plagioclase phenocrysts to orthoclase or microcline followed by alteration of the groundmass feldspar to orthoclase and gradual change of the sanidine phenocrysts to more Or-rich compositions. Oxygen isotope and chemical studies show that the metasomatism resulted from the interaction of the tuffs with deeply circulating heated ground water and suggest that the potassium metasomatism of rhyolitic rocks is the facies equivalent of propylitization of volcanic rocks of more basic composition.

Thermochronology of the Sulu ultrahigh-pressure metamorphic terrane: Implications for continental collision and lithospheric thinning

NASA Astrophysics Data System (ADS)

Liu, Li-Ping; Li, Zheng-Xiang; Danišík, Martin; Li, Sanzhong; Evans, Noreen; Jourdan, Fred; Tao, Ni

2017-08-01

The thermal history of the Dabie-Sulu orogenic belt provides important constraints on the collision process between the South China and North China blocks during the Mesozoic, and possible lithospheric thinning event(s) in the eastern North China Block. This study reports on the thermal evolution of the Sulu ultrahigh-pressure metamorphic (UHP) terrane using zircon U-Pb geochronology and multiple thermochronology methods such as mica and hornblende 40Ar/39Ar, zircon and apatite fission track, and zircon and apatite (U-Th)/He dating. 40Ar/39Ar and zircon (U-Th)/He data show that the UHP terrane experienced accelerated cooling during 180-160 Ma. This cooling event could be interpreted to have resulted from extensional unroofing of an earlier southward thrusting nappe, or, more likely, an episode of northward thrusting of the UHP rocks as a hanging wall. A subsequent episode of exhumation took place between ca. 125 Ma and 90 Ma as recorded by zircon (U-Th)/He data. This event was more pronounced in the northwest section of the UHP terrane, whereas in the southeast section, the zircon (U-Th)/He system retained Jurassic cooling ages of ca. 180-160 Ma. The mid-Cretaceous episode of exhumation is interpreted to have resulted from crustal extension due to the removal of thickened, enriched mantle. A younger episode of exhumation was recorded by apatite fission track and apatite (U-Th)/He ages at ca. 65-40 Ma. Both latter events were linked to episodic thinning of lithosphere along the Sulu UHP terrane in an extensional environment, likely caused by the roll-back of the Western Pacific subduction system.

Origin of minor and trace element compositional diversity in anorthitic feldspar phenocrysts and melt inclusions from the Juan de Fuca Ridge

USGS Publications Warehouse

Adams, David T.; Nielsen, Roger L.; Kent, Adam J.R.; Tepley, Frank J.

2011-01-01

Melt inclusions trapped in phenocryst phases are important primarily due to their potential of preserving a significant proportion of the diversity of magma composition prior to modification of the parent magma array during transport through the crust. The goal of this investigation was to evaluate the impact of formational and post-entrapment processes on the composition of melt inclusions hosted in high anorthite plagioclase in MORB. Our observations from three plagioclase ultra-phyric lavas from the Endeavor Segment of the Juan de Fuca Ridge document a narrow range of major elements and a dramatically greater range of minor and trace elements within most host plagioclase crystals. Observed host/inclusion partition coefficients for Ti are consistent with experimental determinations. In addition, observed values of DTi are independent of inclusion size and inclusion TiO2 content of the melt inclusion. These observations preclude significant effects from the re-homogenization process, entrapment of incompatible element boundary layers or dissolution/precipitation. The observed wide range of TiO2 contents in the host feldspar, and between bands of melt inclusions within individual crystals rule out modification of TiO contents by diffusion, either pre-eruption or due to re-homogenization. However, we do observe comparatively small ranges for values of K2O and Sr compared to P2O5 and TiO2 in both inclusions and crystals that can be attributed to diffusive processes that occurred prior to eruption.

Extensional unroofing of the metamorphic core of the southern Appalachian orogen prior to the breakup of Pangea: Insights from 40Ar/39Ar thermochronology

NASA Astrophysics Data System (ADS)

Ma, C.; Foster, D. A.; Hames, W. E.; Mueller, P. A.

2017-12-01

Orogenic collapse commonly occurs following the collisional phase of an orogeny and often leads to exhumation of deep crustal metamorphic rocks. The Alleghanian orogeny in the southern Appalachian orogen (SAO) occurred during final assembly of Pangea. 40Ar/39Ar data of hornblende, muscovite, and biotite from Alleghanian granitic plutons in Georgia, Alabama, and Florida of the SAO give cooling ages that progressively young toward the south-southeast prior to ca. 280 Ma and young locally toward the north-northwest after ca. 280 Ma. These cooling-age gradients, along with geometry of the Suwannee suture zone and timing/structures of the South Georgia basin, suggest that metamorphic rocks north of the Suwannee suture in the study area formed the lower plate of a metamorphic core complex. The faults of the Suwannee suture zone were reactivated to form a master extensional detachment fault with the Suwannee terrane comprising the upper plate. Thermochronologic data show that rapid extension of the metamorphic core complex footwall started at ca. 300-295 Ma and the extension continued to at least ca. 240 Ma. The maximum average extension rate is estimated to be 10.3 km/m.y. during ca. 300-280 Ma along the master detachment fault and 2.4 km/m.y. during ca. 280-240 Ma along a secondary detachment fault, reflecting differential extension over time. Main cooling rates of 10‒85˚C/m.y. and exhumation rates of 0.3‒2.8 km/m.y. are calculated for the Alleghanian granitic plutons studied. This work shows that, in the southernmost Appalachians, orogenic collapse resulted in metamorphic core complex-style extension between about 300 and 240 Ma. The horst-and-graben systems of the South Georgia basin formed within the upper plate in this tectonic setting. Metamorphic core complex-style extension, therefore, played a critical role in initial rifting that led to the eventual breakup of Pangea and formation of the Atlantic Ocean and the Gulf of Mexico.

South Virgin-White Hills detachment fault system of SE Nevada and NW Arizona: Applying apatite fission track thermochronology to constrain the tectonic evolution of a major continental detachment fault

NASA Astrophysics Data System (ADS)

Fitzgerald, Paul G.; Duebendorfer, Ernest M.; Faulds, James E.; O'Sullivan, Paul

2009-04-01

The South Virgin-White Hills detachment (SVWHD) in the central Basin and Range province with an along-strike extent of ˜60 km is a major continental detachment fault system. Displacement on the SVWHD decreases north to south from ˜17 to <6 km. This is accompanied by a change in fault and footwall rock type from mylonite overprinted by cataclasite to chlorite cataclasite and then fault breccia reflecting decreasing fault displacement and footwall exhumation. Apatite fission track (AFT) thermochronology was applied both along-strike and across-strike to assess this displacement gradient. The overall thermal history reflects Laramide cooling (˜75 Ma) and then rapid cooling beginning in the late early Miocene. Age patterns reflect some complexity but extension along the SVWHD appears synchronous with rapid cooling initiated at ˜17 Ma due to tectonic exhumation. Slip rate is more rapid (˜8.6 km/Ma) in the north compared to ˜1 km/Ma in the south. The displacement gradient results from penecontemporaneous along-strike motion and formation of the SVWHD by linkage of originally separate fault segments that have differential displacements and hence differential slip rates. East-west transverse structures likely play a role in linkage of different fault segments. The preextension paleogeothermal gradient is well constrained in the Gold Butte block as 18-20°C/km. We present a new thermochronologic approach to constrain fault dip during slip, treating the vertical exhumation rate and the slip as vectors, with the angle between them used to constrain fault dip during slip through the closure temperature of a particular thermochronometer. AFT data from the western rim of the Colorado Plateau constrain the initiation of timing of cooling associated with the Laramide Orogeny at ˜75 Ma, and a reheating event in the late Eocene/early Oligocene associated with burial by sediments ("rim gravels") most likely shed from the Kingman High to the west of the plateau.

Thermochronologic constraints on post-Paleozoic tectonic evolution of the central Transantarctic Mountains, Antarctica

NASA Astrophysics Data System (ADS)

Fitzgerald, Paul G.

1994-08-01

Built upon the roots of a compressive orogenic belt of late Proterozoic-early Paleozoic age and once adjacent to North America, the present-day Transantarctic Mountains (TAM) represent a rift flank, resulting from episodic uplift in the Cretaceous and Cenozoic. Fault blocks are discernible in present-day topography and subglacial morphology. Fission track results give information on differential block movement (uplift and denudation) and are important in constraining models for the uplift of the range. Apatite fission track thermochronology on samples collected from the central TAM record a complex thermotectonic history for this region over the past 350 m.y. Apatite ages in the Miller Range vary from ˜250 to ˜350 Ma and are from an exhumed apatite partial annealing zone formed following cooling of Cambro-Ordovician granitoids. A period of Cretaceous denudation (≲2 km), beginning at ˜115 Ma, is recorded at Moody Nunatak on the inland side of the TAM. Near the coast, samples along the Beardmore Glacier record rapid cooling indicative of denudation initiated in the early Cenozoic (˜50 Ma). The amount of uplift ˜70 km inland of the coast in the Queen Alexandra Range since the early Cenozoic is ˜7 km, with the likelihood of an additional ˜3 km at the coast. Eastward facing topographic escarpments in the Queen Alexandra Range mark the likely position of steeply dipping normal faults, which offset the apatite ages. Apatite ages on the east side of the Beardmore Glacier mouth are generally younger (average 27 Ma) than on the west side (average 33 Ma), reflecting greater denudation. Assumptions made regarding the use of an assumed paleogeothermal gradient are tested with available geologic evidence. The fission track data neither conflict with nor confirm paleobotanical evidence from the Sirius Group in the central TAM which suggests significant surface uplift (2-3 km) of the TAM since the Pliocene. Results build upon the available fission track database along the

Is there a geochemical link between volcanic and plutonic rocks in the Organ Mountains caldera?

NASA Astrophysics Data System (ADS)

Memeti, V.; Davidson, J.

2013-12-01

determine within-crystal geochemical variations. Our current conclusions and working hypotheses are: 1) All igneous rocks from the Organ Mountains are crustal-mantle melt mixtures indicating two component mixing; 2) the caldera-forming ignimbrites are likely derived from a fractionating Organ Needle pluton; 3) pre- and post-caldera lavas are isotopically similar to the post-caldera Sugarloaf Peak quartz-monzonite; 4) K-feldspar cumulate textures in the structurally top 0.5-1 km of the Organ Needle pluton indicate that interstitial melt was lost from the magma mush, which likely fed the ignimbrite eruptions. 5) Plutonic feldspar textures are complex compared to rather simple zoned volcanic feldspars including K-feldspar rimmed plagioclase, plagioclase rimmed K-feldspar and unrimmed feldspars occurring over a range of grain sizes at thin section scale. Some volcanic feldspar phenocrysts have any previous zonation erased due to late stage albitization. Although the single mineral studies are still work in progress and details need resolving, our data so far suggest a geochemical link between volcanic and plutonic rocks of the Organ Mountains caldera, albeit a complex one; and greater complexity in plutonic versus volcanic minerals. [1] Seager (1980), NM Bureau of Mines and Min. Res. Memoir 36, 97 p. [2] Zimmerer & McIntosh (2013) Journal of Geophysical Research, v. 93, p. 4421-4433

Tangeretin and its metabolite 4'-hydroxytetramethoxyflavone attenuate EGF-stimulated cell cycle progression in hepatocytes; role of inhibition at the level of mTOR/p70S6K.

PubMed

Cheng, Z; Surichan, S; Ruparelia, K; Arroo, R; Boarder, M R

2011-04-01

The mechanisms by which the dietary compound tangeretin has anticancer effects may include acting as a prodrug, forming an antiproliferative product in cancer cells. Here we show that tangeretin also inhibits cell cycle progression in hepatocytes and investigate the role of its primary metabolite 4'-hydroxy-5,6,7,8-tetramethoxyflavone (4'-OH-TMF) in this effect. We used epidermal growth factor (EGF)-stimulated rat hepatocytes, with [(3)H]-thymidine incorporation into DNA as an index of progression to S-phase of the cell cycle, and Western blots for phospho-proteins involved in the cell signalling cascade. Incubation of tangeretin with microsomes expressing CYP1A, or with hepatocytes, generated a primary product we identified as 4'-OH-TMF. Low micromolar concentrations of tangeretin or 4'-OH-TMF gave a concentration-dependent inhibition of EGF-stimulated progression to S-phase while having little effect on cell viability. To determine whether time for conversion of tangeretin to an active metabolite would enhance the inhibitory effect we used long pre-incubations; this reduced the inhibitory effect, in parallel with a reduction in the concentration of tangeretin. The EGF-stimulation of hepatocyte cell cycle progression requires signalling through Akt/mTOR/p70S6K kinase cascades. The tangeretin metabolite 4'-OH-TMF selectively inhibited S6K phosphorylation in the absence of significant inhibition of upstream Akt activity, suggesting an effect at the level of mTOR. Tangeretin and 4'-OH-TMF both inhibit cell cycle progression in primary hepatocytes. The inhibition of p70S6K phosphorylation by 4'-OH-TMF raises the possibility that inhibition of the mTOR pathway may contribute to the anticancer influence of a flavonoid-rich diet. © 2011 The Authors. British Journal of Pharmacology © 2011 The British Pharmacological Society.

Expression of K19 and K7 in dysplastic nodules and hepatocellular carcinoma.

PubMed

Bae, Jun Sang; Choi, Ha Na; Noh, Sang Jae; Park, Byung Hyun; Jang, Kyu Yun; Park, Cheol Keun; Moon, Woo Sung

2012-08-01

Hepatocellular carcinoma (HCC) is one of the most common types of malignant tumors characterized by a multistep process of tumor development. Nodular lesions that differ from the surrounding liver parenchyma and are characterized by cytological or structural atypia are termed dysplastic nodules (DNs). DNs are well-known precancerous HCC lesions. Expression of keratin (K) 19 and K7, molecular markers of hepatic progenitor cells and cholangiocytes, has been reported in certain HCCs. However, it remains unclear whether K19-positive HCC cells are derived from true hepatic progenitor cells or mature cells that have undergone a dedifferentiation or a transdifferentiation process. In total, 107 tissue sections (13 low-grade DNs, 15 high-grade DNs, 27 small HCCs and 52 large HCCs) from resected liver samples and 132 HCC tissue microarray (TMA) cores were subjected to immunohistochemical analysis for K19 and K7. Clinicopathological data of the HCC patients were evaluated. K19 expression was found in 0% of DNs, 19% of small HCCs (≤2 cm), 8% of large HCCs (>2 cm) and 8% of TMA samples. K7 expression was found in 14% of DNs, 41% of small HCCs, 15% of large HCCs and 6% of TMA samples. Among the five K19-positive small HCCs, four were distinctly nodular and one tumor was an infiltrative type. No vaguely nodular HCC was positive for K19. K19 expression was significantly associated with histological grade (P=0.023), serum α-fetoprotein level (P=0.001) and K7 expression (P=0.001) in HCC. K19 expression was an independent prognostic factor for overall survival in non-viral HCC patients (P=0.003). K19 expression is extremely rare in DNs and occurs in progressed small HCCs. Our results suggest that K19 expression may be an acquired feature of carcinoma cells during HCC progression in certain HCCs.

Asymmetric Exhumation Patterns Revealed through Apatite-Zircon Thermochronology of the Santa Lucia Range, Central California

NASA Astrophysics Data System (ADS)

Mere, A.; Steely, A.; Hourigan, J. K.

2016-12-01

Previous thermochronological analyses of crystalline bedrock in the central Santa Lucia range have yielded surprisingly rapid rates of surface uplift and bedrock extrusion despite lack of modern seismicity along nearby faults. We use 8 new apatite and zircon (U-Th)/He dates in order to better constrain the history of bedrock extrusion in response to the transpressional North American-Pacific plate boundary. Granitic samples were collected along coastal fault blocks bounded by the Palo Colorado (PCF), Sur-Nacimiento (SNF), and San Gregorio Hosgri faults (SGHF); as well as one sample from Salinian Basement >25km NE of the SGHF. Helium was extracted and analyzed using a quadrupole equipped multi-sample laser microfurnace and U/Th content was measured using high precision isotope-dilution ICP mass spectrometry. Rapid late Cretaceous unroofing is captured in Salinian basement zircon and apatite by the respective 67Ma and 63Ma dates. Zircon along coastal silvers proximal to PCF and SNF record 28-31Ma dates while zircon in close proximity to SGHF record ages as young as 6.5Ma. Apatite ages proximal to PCF and SNF range between 6-9Ma and are as young as 1.5Ma directly NE of the SGHF. These data reflect increased exhumation beginning as recently as the Miocene and additionally indicate rates of modern (<2Ma) uplift exceeding 1.3 mm/yr. These results indicate that stresses caused by the active plate boundary are accommodated by the SGHF and associated faults as vertical deformation despite low rates of modern seismicity. We suggest that the SGHF and nearby faults are more active, or behave differently, that previously acknowledged. The pattern of focused exhumation within narrow fault blocks appears to be related to underplating of low strength schist that is thought to be synchronous with late Cretaceous unroofing of Salinian basement.

Experimental investigation of cephapirin adsorption to quartz filter sands and dune sands

NASA Astrophysics Data System (ADS)

Peterson, Jonathan W.; O'Meara, Theresa A.; Seymour, Michael D.

2008-08-01

Batch experiments were performed to investigate cephapirin (a widely used veterinary antibiotic) adsorption on various size sands of low total organic carbon content (0.08-0.36 wt%). In the aqueous concentration range investigated (11-112 μmol/L cephapirin), adsorption to nearly pure quartz filter sands (0.50-3.35 mm diameter) is low. Isotherms are S-shaped and most display a region of minimum adsorption, where decreased adsorption occurs with increasing solution concentration, followed by increased adsorption at higher concentrations. Cephapirin adsorption to quartz-rich, feldspar-bearing dune sands (0.06-0.35 mm diameter), and the smallest quartz filter sand investigated (0.43-0.50 mm), can be described by linear sorption isotherms over the range of concentrations investigated. Distribution coefficients ( K d) range from 0.94 to 3.45 L/kg. No systematic relationship exists between grain size and amount of adsorption for any of the sands investigated. Cephapirin adsorption is positively correlated to the feldspar ratio (K-feldspar/(albite + Ca-plagioclase). Feldspar-ratio normalization of distribution coefficients was more effective than organic carbon normalization at reducing variability of K d values in the dune sands investigated.

Geology and mineralization of the Jabalat alkali-feldspar granite, northern Asir region, Kingdom of Saudi Arabia

NASA Astrophysics Data System (ADS)

Al Tayyar, Jaffar; Jackson, Norman J.; Al-Yazidi, Saeed

The Jabalat post-tectonic granite pluton is composed of albite- and oligoclase-bearing, low-calcium, F-, Sn- and Rb-rich subsolvus granites. These granites display evidence of late-magmatic, granitophile- and metallic-element specialization, resulting ultimately in the development of post-magmatic, metalliferous hydrothermal systems characterized by a Mo sbnd Sn sbnd Cu sbnd Pb sbnd Zn sbnd Bi sbnd Ag sbnd F signature. Two main types of mineralization are present within the pluton and its environs: (1) weakly mineralized felsic and aplitic dikes and veins enhanced in Mo, Bi, Ag, Pb and Cu; and (2) pyrite—molybdenite—chalcopyrite-bearing quartz and quartz—feldspar veins rich in Mo, Sn, Bi, Cu, Zn and Ag. A satellite stock, 3 km north of the main intrusion, is composed of fine-grained, miarolitic, muscovite—albite—microcline (microperthite) granite. The flanks of this intrusion and adjacent dioritic rocks are greisenized and highly enriched in Sn, Bi and Ag. Quartz veins which transect the satellite stock contain molybdenite and stannite.

High-K granites of the Rum Jungle Complex, N-Australia: Insights into the Late Archean crustal evolution of the North Australian Craton

NASA Astrophysics Data System (ADS)

Drüppel, K.; McCready, A. J.; Stumpfl, E. F.

2009-08-01

The Late Archean (c. 2.54-2.52 Ga) high-K granitoids of the Rum Jungle Complex, Northern Australia, display the igneous mineral assemblage of K-feldspar, quartz, plagioclase, biotite, and magnetite, and accessories such as zircon, monazite, titanite, allanite, apatite, and ilmenite. The granites underwent a variably severe greenschist facies alteration and associated deformation during the Barramundi Orogeny (1.88-1.85 Ga). The K-rich granitoids have variable compositions, mainly comprising syenogranite and quartz-monzonite. They can be subdivided into two major groups, (1) felsic granites and (2) intermediate to felsic granites, quartz-monzonites, and diorite. The felsic group (69-76 wt.% SiO 2) shares many features with typical Late Archean potassic granites. They are K- and LILE-rich and show marked depletion in Sr and Eu and the high field strength elements (HFSE), particularly Nb and Ti, relative to LILE and LREE. Compared to the average upper crust they have anomalously high Th (up to 123 ppm) and U (up to 40 ppm). The intermediate to felsic group (56-69 wt.% SiO 2) differs from the felsic group in having weakly lower Th and U but higher Mg#, Ti, Ba, Sr, Ni, Cr and REE, with a less pronounced negative Eu anomaly. This group displays well-defined trends in Harker diagrams, involving a negative correlation of Si with Sr, Ca, Na, and P whereas K, Rb, and Ba increase in the same direction, suggesting fractional crystallization of feldspar was more prominent than in the felsic suite. The mineralogical and geochemical characteristics of the felsic group are consistent with granite formation by intracrustal melting of plagioclase-rich igneous protoliths, probably of tonaltic to granodioritic composition, at moderate crustal levels. The intermediate to felsic granites, on the other hand, appear to be the products of mantle-crust interaction, possibly by melting of or mixing with more mafic igneous rocks. As evidenced by the presence of older inherited zircons crustal

Luna 16 - Some Li, K, Rb, Sr, Ba, rare-earth, Zr, and Hf concentrations.

NASA Technical Reports Server (NTRS)

Philpotts, J. A.; Schnetzler, C. C.; Schuhmann, S.; Thomas , H. H.; Bottino, M. L.

1972-01-01

Concentrations of Li, K, Rb, Sr, Na, rare-earths, Zr and Hf have been determined for some Luna 16 core materials by mass-spectrometric isotope-dilution. Two regolith fines samples from different depths in the core, and four rock-chips, including both igneous rocks and breccias, have similar trace-element concentrations. The Luna 16 materials have general lunar trace-element characteristics but differ from other returned lunar samples in a manner that suggests the presence of excess feldspar. Unless the Luna 16 igneous rocks are fused soils, they appear to represent either partial plagioclase cumulates or the least differentiated igneous material yet returned from the moon. The similarity in trace-element concentrations of the igneous rocks and the fines would then suggest largely local derivation of the Luna 16 regolith.

The tumor suppressor SirT2 regulates cell cycle progression and genome stability by modulating the mitotic deposition of H4K20 methylation

PubMed Central

Serrano, Lourdes; Martínez-Redondo, Paloma; Marazuela-Duque, Anna; Vazquez, Berta N.; Dooley, Scott J.; Voigt, Philipp; Beck, David B.; Kane-Goldsmith, Noriko; Tong, Qiang; Rabanal, Rosa M.; Fondevila, Dolors; Muñoz, Purificación; Krüger, Marcus; Tischfield, Jay A.; Vaquero, Alejandro

2013-01-01

The establishment of the epigenetic mark H4K20me1 (monomethylation of H4K20) by PR-Set7 during G2/M directly impacts S-phase progression and genome stability. However, the mechanisms involved in the regulation of this event are not well understood. Here we show that SirT2 regulates H4K20me1 deposition through the deacetylation of H4K16Ac (acetylation of H4K16) and determines the levels of H4K20me2/3 throughout the cell cycle. SirT2 binds and deacetylates PR-Set7 at K90, modulating its chromatin localization. Consistently, SirT2 depletion significantly reduces PR-Set7 chromatin levels, alters the size and number of PR-Set7 foci, and decreases the overall mitotic deposition of H4K20me1. Upon stress, the interaction between SirT2 and PR-Set7 increases along with the H4K20me1 levels, suggesting a novel mitotic checkpoint mechanism. SirT2 loss in mice induces significant defects associated with defective H4K20me1–3 levels. Accordingly, SirT2-deficient animals exhibit genomic instability and chromosomal aberrations and are prone to tumorigenesis. Our studies suggest that the dynamic cross-talk between the environment and the genome during mitosis determines the fate of the subsequent cell cycle. PMID:23468428

Immersion freezing of ambient dust using WISDOM setup

NASA Astrophysics Data System (ADS)

Rudich, Y.; Reicher, N.

2017-12-01

A small subset of the atmospheric particles has the ability to induce ice formation. Among them are mineral dust particles that originate from arid regions. Mineral dust particles are internally mixed with various types of minerals such as kaolinite and illite from the clay minerals, quartz and feldspar. The mineral composition of the dust particles determine their freezing efficiency. Much attention was given to the clay group, as they are the most common minerals transported in the atmosphere. Recently, much focus has been directed to the feldspars, since its ice efficiency is higher at warmer temperatures, and as such is may dominate freezing in mixed phase clouds. Moreover, it was found that samples that contained higher content of feldspar had higher nucleation activity. In this study, we examine the immersion freezing of ambient dust particles that were collected in Rehovot, Israel (31.9N, 34.8E about 80m AMSL), during dust storms from the Sahara and the Syrian deserts. The size-segregated dust particles were collected on cyclopore polycarbonate filters using a Micro-orifice Uniform deposit Impactor (MOUDI). Freezing experiments were done using the WeIzmann Supercooled Droplets Observation on Microarray set (WISDOM). The particles were extracted from the filters by sonication and subsequently immersed in 100μm droplets that were cooled in a rate of 1°CPM to -37°C (homogenous freezing threshold). Investigation of the particles mineralogy was also performed. We observed freezing onset at 253K for particles of different diameters (0.3, 1.0, 1.8 and 3.2 μm). Most of the droplets were completely frozen by 243K. The number of active sites ranged from 108 to 1012 per m-2. Droplets that contained larger particles (higher surface area) froze at slightly warmer temperatures and contained slightly higher number of active sites. The freezing behavior fits well with measurements of K-feldspar particles and this may suggest that the feldspar dominated the dust freezing

Fission track length distributions in multi-system thermochronology (Invited)

NASA Astrophysics Data System (ADS)

Gleadow, A. J.; Seiler, C.

2013-12-01

Fission track length distributions contain a unique record of past temperature variations and therefore play a key role in low-temperature thermochronology, for which there is no exact equivalent in any other method. Confined track lengths closely approximate the true etchable ranges of latent fission tracks [1] and are therefore favoured for fission track studies, but they still have a number of practical limitations. These include small numbers of suitable tracks, especially when only horizontal confined tracks are measured. Using only track-in-track events for measurement further limits the sample size. These restrictions become acute for low track-density samples, where length measurements may be impossible. Irradiating the surface with 252Cf tracks [2] can substantially increase the number of confined tracks, but many researchers do not have access to a Cf source. An even more significant issue has emerged from inter-laboratory comparison experiments that demonstrate a disturbingly poor reproducibility of length measurements between observers [3], a problem compounded by a lack of standardisation in measurement techniques. As a result, individual observers may measure different positions for the end of a track, contributing significantly to variability, and consequently blurring the thermal histories obtained. New digital microscopes open up important opportunities for improved track length measurements by reducing restrictions on sample size, and eliminating some sources of inter-observer bias. We have developed a track length measurement system that enables precise determination of vertical as well as horizontal track dimensions, allowing 3D lengths to be obtained. Lengths are measured on captured image stacks that can be analysed easily and may also be shared, for greater standardisation between laboratories. Length measurements are highly reproducible between different observers using this system, suggesting that at least one source of variability can be

Experience from a (U-Th)/He thermochronology CAREER grant

NASA Astrophysics Data System (ADS)

Reiners, P. W.

2011-12-01

incorporate outreach is simply to open one's lab to the community to provide basic but valuable analyses. In my case this was routine (U-Th)/He dating for tectonic and geomorphic studies. This requires significant commitment to training and analytical reliability, but also provides broad scientific enrichment to the lab. In addition to a huge number of rocks-in-the-mailbox users, during the grant our lab hosted >50 visiting users from >35 institutions, generating thousands of analyses for outside users alone. But simply opening one's lab is not particularly distinctive outreach. A more important and consuming initiative was our summer workshops on thermochronology. These featured teaching and a fieldtrip but, most importantly, the chance for 8 or 9 visiting students to analyze as many (U-Th)/He (and recently, with help from colleagues, U/Pb and FT) dates as they could cram into a two-week period, interpret them, and present their results. The high-intensity workshops generated large amounts of data, many meeting abstracts, a few papers, valuable collaborations with advisors, and rewarding experiences with diverse students. They require a lot of time and effort, including stress of insuring continuous smooth analytical performance. One nugget of experience from these is that they are more rewarding when centered on a theme (e.g., Antarctichron 2011).

The Western North American Cretaceous-Tertiary (K-T) boundary interval and its content of shock-metamorphosed minerals: Implications concerning the K-T boundary impact-extinction theory

NASA Technical Reports Server (NTRS)

Izett, G. A.

1988-01-01

At 20 sites in the Raton Basin of Colorado and New Mexico, and at several other sites in Wyoming, Montana, and Canada, a pair of claystone units, an Ir abundance anomaly, and a concentration of shock-metamorphosed minerals mark the palynological K-T boundary. The K-T boundary claystone, which is composed of kaolinite and small amounts of illite/smectite mixed-layer clay, is similar in most respects to kaolinite tonstein layers in coal beds. At some, but not all, K-T boundary localities, the boundary claystone contains solid kaolinite and hollow and solid goyazite spherules, 0.05 to 1.2 mm in diameter. The upper unit, the K-T boundary impact layer, consists chiefly of kaolinite and various amounts of illite/smectite mixed-layer clay. The impact layer and boundary claystone are similar chemically, except that the former has slightly more Fe, K, Ba, Cr, Cu, Li, V, and Zn than the latter. The facts that the boundary claystone and impact layer contain anomalous amounts of Ir, comprise a stratigraphic couplet at Western North American sites, and form thin, discrete layers, similar to air-fall units (volcanic or impact), suggest that the claystone units are of impact origin. Significantly, the impact layer contains as much as 2 percent clastic mineral grains, about 30 percent of which contain multiple sets of shock lamellae. Only one such concentration of shocked minerals has been found near the K-T boundary. The type of K-T boundary shock-metamorphosed materials (quartzite and metaquartzite) in the impact layer and the lack of shock lamellae in quartz and feldspar of pumice lapilli and granitic xenoliths in air-fall pumice units of silicic tuffs, such as the Bishop Tuff, eliminate the possibility that the shock-metamorphosed minerals in the K-T impact layer are of volcanic origin. The global size distribution and abundance of shock-metamorphosed mineral grains suggest that the K-T impact occurred in North America.

Mueilha rare metals granite, Eastern Desert of Egypt: An example of a magmatic-hydrothermal system in the Arabian-Nubian Shield

NASA Astrophysics Data System (ADS)

Abu El-Rus, Mohamed A.; Mohamed, Mohamed A.; Lindh, Anders

2017-12-01

The Mueilha granite pluton is one of the rare-metals bearing peraluminous granitic plutons in the Arabian-Nubian Shield. It represents the apical part of a highly evolved magma chamber emplaced at a shallow level subsequent to the post Pan-African orogeny. The pluton can be seen as a highly leucocratic medium-grained albite/oligoclase framework infilled with quartz, K-feldspar and muscovite that are variably overgrown by K-feldspar, muscovite, quartz and topaz megacrysts. The increasing number and size of the K-feldspar megacrysts at the expense of the whitened albite/oligoclase framework imparts variably red color to the Mueilha granite. Contacts between the milky white and red granites are usually gradational, but may be locally sharp or may form narrow transition zones resulting from abrupt variations in texture and lithology. Textural relations indicate an initial stage of hydrothermal albitization of magmatic plagioclase and crystallization of topaz megacrysts resulting from infiltration of Na-rich fluorine bearing fluids. A subsequent stage of metasomatic enrichment is characterized by extensive growth of large K-feldspar, quartz and muscovite megacrysts at the expense of the albite/oligoclase crystals as a result of infiltration of K-Si rich hydrous fluids. Post-magmatic infiltration of hydrous fluids along the fault planes is shown by the intense replacement of alkali feldspar megacrysts by quartz, development of myrmekitic intergrowth pockets along the K-feldspar megacrysts and sealing of the micro-fractures by cryptocrystalline mixtures of clay minerals, iron oxides, sericite and chlorite. Compositionally, the red granitic rocks have higher SiO2, Fe2O3total, K2O/Na2O, Σ REE, Y, Th, U, Zr and Zn and lower Al2O3, Ga, Ta, Nb and Mo compared to the milky white granites. LILE and Sn do not show clear variation trends throughout the Mueilha granite pluton, suggesting their immobility during hydrothermal alteration. Microthermometric measurements indicate that

Adsorption mechanism of mixed cationic/anionic collectors in feldspar-quartz flotation system.

PubMed

Vidyadhar, A; Hanumantha Rao, K

2007-02-15

The adsorption mechanism of mixed cationic alkyl diamine and anionic sulfonate/oleate collectors at acidic pH values was investigated on microcline and quartz minerals through Hallimond flotation, electrokinetic and diffuse reflectance FTIR studies. In the presence of anionic collectors, neither of the minerals responded to flotation but the diamine flotation of the minerals was observed to be pH and concentration dependent. The presence of sulfonate enhanced the diamine flotation of the minerals by its co-adsorption. The difference in surface charge between the minerals at pH 2 was found to be the basis for preferential feldspar flotation from quartz in mixed diamine/sulfonate collectors. The infrared spectra revealed no adsorption of sulfonate collector when used alone but displayed its co-adsorption as diamine-sulfonate complex when used with diamine. The presence of sulfonate increased the diamine adsorption due to a decrease in the electrostatic head-head repulsion between the adjacent surface ammonium ions and thereby increasing the lateral tail-tail hydrophobic bonds. The mole ratio of diamine/sulfonate was found to be an important factor in the orientation of alkyl chains and thus the flotation response of minerals. The increase in sulfonate concentration beyond diamine concentration leads to the formation of soluble 1:2 diamine-sulfonate complex or precipitate and the adsorption of these species decreased the flotation since the alkyl chains are in chaotical orientation with a conceivable number of head groups directing towards the solution phase.

Rapakivi texture formation via disequilibrium melting in a contact partial melt zone, Antarctica

NASA Astrophysics Data System (ADS)

Currier, R. M.

2017-12-01

In the McMurdo Dry Valleys of Antarctica, a Jurassic aged dolerite sill induced partial melting of granite in the shallow crust. The melt zone can be traced in full, from high degrees of melting (>60%) along the dolerite contact, to no apparent signs of melting, 10s of meters above the contact. Within this melt zone, the well-known rapakivi texture is found, arrested in various stages of development. High above the contact, and at low degrees of melting, K-feldspar crystals are slightly rounded and unmantled. In the lower half of the melt zone, mantles of cellular textured plagioclase appear on K-feldspar, and thicken towards the contact heat source. At the highest degrees of melting, cellular-textured plagioclase completely replaces restitic K-feldspar. Because of the complete exposure and intact context, the leading models of rapakivi texture formation can be tested against this system. The previously proposed mechanisms of subisothermal decompression, magma-mixing, and hydrothermal exsolution all fail to adequately describe rapakivi generation in this melt zone. Preferred here is a closed system model that invokes the production of a heterogeneous, disequilibrium melt through rapid heating, followed by calcium and sodium rich melt reacting in a peritectic fashion with restitic K-feldspar crystals. This peritectic reaction results in the production of plagioclase of andesine-oligoclase composition—which is consistent with not just mantles in the melt zone, but globally as well. The thickness of the mantle is diffusion limited, and thus a measure of the diffusive length scale of sodium and calcium over the time scale of melting. Thermal modeling provides a time scale of melting that is consistent with the thickness of observed mantles. Lastly, the distribution of mantled feldspars is highly ordered in this melt zone, but if it were mobilized and homogenized—mixing together cellular plagioclase, mantled feldspars, and unmantled feldspars—the result would be

Two-phase Neogene extension in the northwestern basin and range recorded in a single thermochronology sample

USGS Publications Warehouse

Colgan, J.P.; Shuster, D.L.; Reiners, P.W.

2008-01-01

We use a combination of apatite 4He/3He, (U-Th)/ He, and fission-track thermochronology to date slip on the Surprise Valley fault in northeastern California by analyzing a single sample from the Warner Range in the footwall of the fault. This sample, a granitic clast from a conglomerate, yielded a fission-track age of 11.6 ?? 2.8 Ma and a (U-Th)/He age of 3.02 ?? 0.52 Ma. Geologic relationships indicate that this sample was buried to a depth of ???3.3 km prior to exhumation during slip on the Surprise Valley fault. Fission-track age and length data indicate that the sample was fully reset (>120 ??C) prior to exhumation, which began sometime after 14 Ma. A single aliquot of nine apatite grains was step-heated for 4He/3He analysis; modeling of the resulting 4He distribution indicates that cooling from <80 ??C to ???20 ??C occurred between 3 and 1 Ma. Interconsistent time-temperature (t-T) solutions to the combined 4He/3He, (U-Th)/He, and fission-track data require two distinct periods of cooling, consistent with non-continuous slip on the Surprise Valley fault. Early cooling and fault slip took place between 14 and 8 Ma, followed by more recent fault slip ca. 3 Ma. This timing is consistent with both local geologic relationships and with the regional timing of faulting along the western margin of the Basin and Range Province. These data demonstrate the resolving power of combined fission-track, (U-Th)/He, and 4He/3He thermochronometric data to extract low-temperature t-T information from a single sample close to Earth's surface. ?? 2008 The Geological Society of America.

Post-breakup tectonics in southeast Brazil from thermochronological data and combined inverse-forward thermal history modeling

NASA Astrophysics Data System (ADS)

Cogné, Nathan; Gallagher, Kerry; Cobbold, Peter R.; Riccomini, Claudio; Gautheron, Cecile

2012-11-01

The continental margin of southeast Brazil is elevated. Onshore Tertiary basins and Late Cretaceous/Paleogene intrusions are good evidence for post breakup tectono-magmatic activity. To constrain the impact of post-rift reactivation on the geological history of the area, we carried out a new thermochronological study. Apatite fission track ages range from 60.7 ± 1.9 Ma to 129.3 ± 4.3 Ma, mean track lengths from 11.41 ± 0.23 μm to 14.31 ± 0.24 μm and a subset of the (U-Th)/He ages range from 45.1 ± 1.5 to 122.4 ± 2.5 Ma. Results of inverse thermal history modeling generally support the conclusions from an earlier study for a Late Cretaceous phase of cooling. Around the onshore Taubaté Basin, for a limited number of samples, the first detectable period of cooling occurred during the Early Tertiary. The inferred thermal histories for many samples also imply subsequent reheating followed by Neogene cooling. Given the uncertainty of the inversion results, we did deterministic forward modeling to assess the range of possibilities of this Tertiary part of the thermal history. The evidence for reheating seems to be robust around the Taubaté Basin, but elsewhere the data cannot discriminate between this and a less complex thermal history. However, forward modeling results and geological information support the conclusion that the whole area underwent cooling during the Neogene. The synchronicity of the cooling phases with Andean tectonics and those in NE Brazil leads us to assume a plate-wide compressional stress that reactivated inherited structures. The present-day topographic relief of the margin reflects a contribution from post-breakup reactivation and uplift.

Buffering of potassium in seawater by alteration of basalt in low-temperature, off-axis, hydrothermal systems

NASA Astrophysics Data System (ADS)

Laureijs, C. T.; Coogan, L. A.

2016-12-01

It is generally accepted that the composition of seawater has varied through the Phanerzoic and that the variation is linked to changes in the same global fluxes that control the long-term carbon cycle. However, K is observed to be stable at a value of 10 mmol/L despite variable river and hydrothermal fluxes [1]. Secondary K-bearing phases are widely observed in altered upper oceanic crust, suggesting that reactions between seawater and basalt in low-temperature, off-axis, oceanic hydrothermal systems could buffer the K concentration of seawater [2]. As K-feldspar is a common secondary K-bearing mineral in Cretaceous and rare in Cenozoic oceanic crust, the formation of K-feldspar by breakdown of plagioclase reacting with a model Cretaceous seawater was modeled at 15 ºC using the PhreeqC code (version 3.2) and the associated llnl.dat database. A fluid with a K-content of 11 mmol/L in equilibrium with K-feldspar and calcite was generated, consistent with K-feldspar acting as a buffer for the K-content in Cretaceous seawater and the production of alkalinity stabilizing atmospheric CO2 levels on the long-term timescales. A compilation of the K2O content of lavas from DSDP and ODP drill cores (from: http://www.earthchem.org/petdb) shows that the average K-content of altered crust was higher in the Cretaceous than the Cenozoic. This data is inconsistent with the model for the composition of seawater presented in [2], but is consistent with an updated and modified version of this model, that uses more realistic fluxes [3]. We conclude that oceanic off-axis hydrothermal systems probably do buffer the K-content of seawater. [1] Timofeeff et al. (2006), Geochim. Cosmochim. Acta. 70, 1977-1994; [2] Demicco et al. (2005), Geology 33, 877-880. [3] Coogan & Dosso (2012), Earth Planet. Sci. Lett. 323-324, 92-101.

Building Capacity in Understanding Foundational Biology Concepts: A K-12 Learning Progression in Genetics Informed by Research on Children's Thinking and Learning

NASA Astrophysics Data System (ADS)

Elmesky, Rowhea

2013-06-01

This article describes the substance, structure, and rationale of a learning progression in genetics spanning kindergarten through twelfth grade (K-12). The learning progression is designed to build a foundation towards understanding protein structure and activity and should be viewed as one possible pathway to understanding concepts of genetics and ultimately protein expression, based on the existing research. The kindergarten through fifth grade segment reflects findings that show children have a rich knowledge base and sophisticated cognitive abilities, and therefore, is designed so that elementary-aged children can learn content in deep and abstract manners, as well as apply scientific explanations appropriate to their knowledge level. The article also details the LP segment facilitating secondary students' understanding by outlining the overlapping conceptual frames which guide student learning from cell structures and functions to cell splitting (both cell division and gamete formation) to genetics as trait transmission, culminating in genetics as protein expression. The learning progression product avoids the use of technical language, which has been identified as a prominent source of student misconceptions in learning cellular biology, and explicit connections between cellular and macroscopic phenomena are encouraged.

Apigenin inhibits prostate cancer progression in TRAMP mice via targeting PI3K/Akt/FoxO pathway

PubMed Central

Gupta, Sanjay

2014-01-01

Forkhead box O (FoxO) transcription factors play an important role as tumor suppressor in several human malignancies. Disruption of FoxO activity due to loss of phosphatase and tensin homolog and activation of phosphatidylinositol-3 kinase (PI3K)/Akt are frequently observed in prostate cancer. Apigenin, a naturally occurring plant flavone, exhibits antiproliferative and anticarcinogenic activities through mechanisms, which are not fully defined. In the present study, we show that apigenin suppressed prostate tumorigenesis in transgenic adenocarcinoma of the mouse prostate (TRAMP) mice through the PI3K/Akt/FoxO-signaling pathway. Apigenin-treated TRAMP mice (20 and 50 μg/mouse/day, 6 days/week for 20 weeks) exhibited significant decrease in tumor volumes of the prostate as well as completely abolished distant organ metastasis. Apigenin treatment resulted in significant decrease in the weight of genitourinary apparatus (P < 0.0001), dorsolateral (P < 0.0001) and ventral prostate (P < 0.028), compared with the control group. Apigenin-treated mice showed reduced phosphorylation of Akt (Ser473) and FoxO3a (Ser253), which correlated with its increased nuclear retention and decreased binding of FoxO3a with 14-3-3. These events lead to reduced proliferation as assessed by Ki-67 and cyclin D1, along with upregulation of FoxO-responsive proteins BIM and p27/Kip1. Complementing in vivo results, similar observations were noted in human prostate cancer LNCaP and PC-3 cells after apigenin treatment. Furthermore, binding of FoxO3a with p27/Kip1 was markedly increased after 10 and 20 μM apigenin treatment resulting in G0/G1-phase cell cycle arrest, which was consistent with the effects elicited by PI3K/Akt inhibitor, LY294002. These results provide convincing evidence that apigenin effectively suppressed prostate cancer progression, at least in part, by targeting the PI3K/Akt/FoxO-signaling pathway. PMID:24067903

The History of a Plutonic-Volcanic System Determined from Compositional and Mineral Inclusion Mapping of Alkali Feldspar Megacrysts

NASA Astrophysics Data System (ADS)

Belfanti, S. A. D.; Gualda, G. A. R.

2017-12-01

Alkali-feldspar megacrysts (2-20 cm long) occur in many granitic rocks, providing extensive records of crystallization within magma bodies. We will use megacrysts from Yosemite National Park's Tuolumne Intrusive Suite to determine if and how megacrysts record recharge and eruption. Preliminary work has focused on 4 crystals. Based on BSE patterns, crystals can be divided into 3 zones: (1) the core, which represents the crystal's first growth and sometimes displays some resorption; (2) the interior, including a series of sub-zones that correspond to different growth periods; and (3) the rim, or outermost growth stage. Common BSE patterns include decreasing brightness from the inner portion of a growth period outward, increasing brightness towards either side of a boundary, and periods of constant brightness, for a full or partial period. Most mineral inclusions appear as single crystals ( 10-25%) or as groups of 2-4 crystals ( 60-75%). Large clusters of 10 or more individuals are less common ( 5-15%), and clusters of >20 crystals are rare ( 1-3%). Most crystals (85-95%) occur on growth boundaries or within the core. Magnetite is common in the more central parts of the interior zone, appearing only occasionally in the core and towards the rim. Accessories, amphibole, and biotite are more evenly distributed within the megacryst. Biotite and titanite grains large enough to display habit appear to be within 20 degrees of parallel with zone boundaries. Most other inclusions are small or not elongated enough to display clear alignment. The total volume of inclusions (excluding quartz and plagioclase, which have X-ray attenuation very similar to that of alkali feldspar) does not exceed 1% of megacryst volume. Plagioclase seems to be at least equal in volume to all other inclusions combined, but as noted above, its exact volume is currently indiscernible. Magnetite makes up about 1/6 of inclusion volume, zircon 1/3, and all others the remaining half. We will complement our

The formation of the Late Cretaceous Xishan Sn-W deposit, South China: Geochronological and geochemical perspectives

NASA Astrophysics Data System (ADS)

Zhang, Lipeng; Zhang, Rongqing; Hu, Yongbin; Liang, Jinlong; Ouyang, Zhixia; He, Junjie; Chen, Yuxiao; Guo, Jia; Sun, Weidong

2017-10-01

The Xishan Sn-W deposit is spatially related to K-feldspar granites in the Yangchun basin, western Guangdong Province, South China. LA-ICP-MS zircon U-Pb dating for the Xishan pluton defines an emplacement age of 79 Ma (78.1 ± 0.9 Ma; 79.0 ± 1.2 Ma; 79.3 ± 0.8 Ma), consistent with the mineralization age of the Xishan Sn-W deposit constrained by molybdenite Re-Os isochron age (79.4 ± 4.5 Ma) and LA-ICP-MS cassiterite U-Pb ages (78.1 ± 0.9 Ma and 79.0 ± 1.2 Ma) for the cassiterite-quartz vein. These indicate a close genetic relationship between the granite and Sn-W mineralization. The Xishan K-feldspar granites have geochemical characteristics of A-type granites, e.g., high total alkali (Na2O + K2O = 7.88-10.07 wt.%), high Ga/Al ratios (10000*Ga/Al > 2.6) and high Zr + Nb + Ce + Y concentrations (> 350 ppm). They are further classified as A2-type granites. The whole-rock isotopic compositions of K-feldspar granites (initial 87Sr/86Sr = 0.705256-0.706181; εNd(t) = - 5.4 to - 4.8) and zircon εHf(t) values (- 7.8 to 2.0) suggest a mixed magma source. The low zircon Ce4 +/Ce3 + ratios (12-88) of K-feldspar granites suggest low oxygen fugacities, which is key for enrichment of tin in primary magmas. The K-feldspar granites have experienced strong differentiation as indicated by their high Rb/Sr and K/Rb ratios, and low Nb/Ta and Zr/Hf ratios, which play an important role in ore-forming element transportation and concentration. A-type granite characteristics of the Xishan pluton show that it formed in an extensional environment. The high F and low Cl characteristics of the K-feldspar granite are most probably attributed to slab rollback. In the Late Cretaceous, the Xishan Sn-W deposit was located near the interaction of the circum-Pacific and the Tethys tectonic realms. Late Cretaceous Sn-W deposits, including the Xishan deposit, form an EW-trending belt from Guangdong to Yunnan Province in South China. This belt is in accordance with the direction of the Neo

Thermochronological constraints on the Cambrian to recent geological evolution of the Argentina passive continental margin

NASA Astrophysics Data System (ADS)

Kollenz, Sebastian; Glasmacher, Ulrich A.; Rossello, Eduardo A.; Stockli, Daniel F.; Schad, Sabrina; Pereyra, Ricardo E.

2017-10-01

Passive continental margins are geo-archives that store information from the interplay of endogenous and exogenous forces related to continental rifting, post-breakup history, and climate changes. The recent South Atlantic passive continental margins (SAPCMs) in Brazil, Namibia, and South Africa are partly high-elevated margins ( 2000 m a.s.l.), and the recent N-S-trending SAPCM in Argentina and Uruguay is of low elevation. In Argentina, an exception in elevation is arising from the higher topography (> 1000 m a.s.l.) of the two NW-SE-trending mountain ranges Sierras Septentrionales and Sierras Australes. Precambrian metamorphic and intrusive rocks, and siliciclastic rocks of Ordovician to Permian age represent the geological evolution of both areas. The Sierras Australes have been deformed and metamorphosed (incipient - greenschist) during the Gondwanides Orogeny. The low-temperature thermochronological (LTT) data (< 240 °C) indicated that the Upper Jurassic to Lower Cretaceous opening of the South Atlantic has not completely thermally reset the surface rocks. The LTT archives apatite and zircon still revealed information on the pre- to post-orogenic history of the Gondwanides and the Mesozoic and Cenozoic South Atlantic geological evolution. Upper Carboniferous zircon (U-Th/He)-ages (ZHe) indicate the earliest cooling below 180 °C/1 Ma. Most of the ZHe-ages are of Upper Triassic to Jurassic age. The apatite fission-track ages (AFT) of Sierras Septentrionales and the eastern part of Sierras Australes indicate the South Atlantic rifting and, thereafter. AFT-ages of Middle to Upper Triassic on the western side of the Sierras Australes are in contrast, indicating a Triassic exhumation caused by the eastward thrusting along the Sauce Grande wrench. The corresponding t-T models report a complex subsidence and exhumation history with variable rates since the Ordovician. Based on the LTT-data and the numerical modelling we assume that the NW-SE-trending mountain ranges

Chemical weathering of a marine terrace chronosequence, Santa Cruz, California I: Interpreting rates and controls based on soil concentration-depth profiles

USGS Publications Warehouse

White, A.F.; Schulz, M.S.; Vivit, D.V.; Blum, A.E.; Stonestrom, David A.; Anderson, S.P.

2008-01-01

The spatial and temporal changes in element and mineral concentrations in regolith profiles in a chronosequence developed on marine terraces along coastal California are interpreted in terms of chemical weathering rates and processes. In regoliths up to 15 m deep and 226 kyrs old, quartz-normalized mass transfer coefficients indicate non-stoichiometric preferential release of Sr > Ca > Na from plagioclase along with lesser amounts of K, Rb and Ba derived from K-feldspar. Smectite weathering results in the loss of Mg and concurrent incorporation of Al and Fe into secondary kaolinite and Fe-oxides in shallow argillic horizons. Elemental losses from weathering of the Santa Cruz terraces fall within the range of those for other marine terraces along the Pacific Coast of North America. Residual amounts of plagioclase and K-feldspar decrease with terrace depth and increasing age. The gradient of the weathering profile bs is defined by the ratio of the weathering rate, R to the velocity at which the profile penetrates into the protolith. A spreadsheet calculator further refines profile geometries, demonstrating that the non-linear regions at low residual feldspar concentrations at shallow depth are dominated by exponential changes in mineral surface-to-volume ratios and at high residual feldspar concentrations, at greater depth, by the approach to thermodynamic saturation. These parameters are of secondary importance to the fluid flux qh, which in thermodynamically saturated pore water, controls the weathering velocity and mineral losses from the profiles. Long-term fluid fluxes required to reproduce the feldspar weathering profiles are in agreement with contemporary values based on solute Cl balances (qh = 0.025-0.17 m yr-1). During saturation-controlled and solute-limited weathering, the greater loss of plagioclase relative to K-feldspar is dependent on the large difference in their respective solubilities instead of the small difference between their respective

Evidence for a nonmagmatic component in potassic hydrothermal fluids of porphyry cu-Au-Mo systems, Yukon, Canada

NASA Astrophysics Data System (ADS)

Selby, David; Nesbitt, Bruce E.; Creaser, Robert A.; Reynolds, Peter H.; Muehlenbachs, Karlis

2001-02-01

Isotopic (H, Sr, Pb, Ar) and fluid inclusion data for hydrothermal fluids associated with potassic alteration from three Late Cretaceous porphyry Cu occurrences, west central Yukon, suggest a nonmagmatic fluid component was present in these hydrothermal fluids. Potassic stage quartz veins contain a dominant assemblage of saline and vapor-rich fluid inclusions that have δD values between -120 and -180‰. Phyllic stage quartz veins are dominated by vapor-rich fluid inclusions and have δD values that overlap with but are, on average, heavier (-117 to -132‰) than those in potassic stage quartz veins. These δD values are significantly lower than those from plutonic quartz phenocrysts (-91 to -113‰), and from values typically reported for primary fluids from porphyry-style mineralization (-40 to -100‰). The initial Sr ( 87Sr/ 86Sr i) isotopic values for the plutons are 0.7055 (Casino), 0.7048 (Mt. Nansen), and 0.7055 (Cash). The 87Sr/ 86Sr i compositions of hydrothermal K-feldspar ranges from magmatic Sr i values to more radiogenic compositions (Casino: 0.70551-0.70834, n = 8; Mt. Nansen: 0.7063-0.7070, n = 4; Cash: 0.7058, n = 1). The fluid inclusion waters from potassic quartz veins have 87Sr/ 86Sr i values that are similar to those of co-existing hydrothermal K-feldspar. The Pb isotopic compositions of hydrothermal K-feldspar show a weak positive correlation with Sr i for identical samples. Fluid inclusion waters of phyllic quartz veins also have Sr i compositions more radiogenic than the plutons. The Pb isotopic composition of pyrite and bornite from phyllic alteration veins are similar to, or more radiogenic than, hydrothermal K-feldspar Pb isotopic values. Hydrothermal K-feldspar samples yield 40Ar/ 39Ar ages (Casino = 71.9 ± 0.7 to 73.4 ± 0.8 Ma; Mt. Nansen = 68.2 ± 0.7 and 69.5 ± 0.6 Ma; Cash = 68.3 ± 0.8 Ma) similar to the U-Pb zircon, K-Ar biotite and Re-Os molybdenite ages of the Late Cretaceous plutons, with the age spectra indicating no excess

PreK-3rd: Next Steps for State Longitudinal Data Systems. PreK-3rd Policy Action Brief. No. Eight

ERIC Educational Resources Information Center

Hernandez, Donald J.

2012-01-01

The growing movement to strengthen PreK-3rd education as an essential foundation for student success, along with the rapid expansion in public funding for PreK, has created an urgent need to measure children's educational progress, in a continuous fashion, from the beginning of PreK through Grade Three. Currently, some state governments are…

Absolute absorption cross sections of ozone at 300 K, 228 K and 195 K in the wavelength region 185-240 nm

NASA Technical Reports Server (NTRS)

Yoshino, K.; Parkinson, W. H.; Freeman, D. E.

1992-01-01

An account is given of progress of work on absorption cross section measurements of ozone at 300 K, 228 K and 195 K in the wavelength region 185-240 nm. In this wavelength region, the penetration of solar radiation into the Earth's atmosphere is controlled by O2 and O3. The transmitted radiation is available to dissociate trace species such as halocarbons and nitrous oxide. We have recently measured absolute absorption cross sections of O3 in the wavelength region 240-350 nm (Freeman et al., 1985; Yoshino et al., 1988). We apply these proven techniques to the determination of the absorption cross section of O3 at 300 K, 228 K and 195 K throughout the wavelength region 185-240 nm. A paper titled 'Absolute Absorption Cross Section Measurements of Ozone in the Wavelength Region 185-254 nm and the Temperature Dependence' has been submitted for publication in the Journal of Geophysical Research.

Long-lived Control of Sierras Pampeanas Ranges on Andean Foreland Basin Evolution Revealed by Coupled Low-temperature Thermochronology and Sedimentology

NASA Astrophysics Data System (ADS)

Stevens Goddard, A.; Carrapa, B.; Larrovere, M.; Aciar, R. H.

2017-12-01

The Sierras Pampeanas ranges of west-central Argentina (28º- 31ºS) are a classic example of thick-skinned style basement block uplifts. The style and timing of uplift in these mountain ranges has widely been attributed to the onset of flat-slab subduction in the middle to late Miocene. However, the majority of low-temperature thermochronometers in the Sierras Pampeanas have much older cooling dates. Thermal modeling derived from new low-temperature thermochronometers in Sierra de Velasco, one of the highest relief (> 4 km) mountains in the Sierras Pampeanas, suggest that the rocks in these ranges have been at near-surface temperatures (< 50ºC) since the Paleozoic. Reheating to temperatures between 80ºC and 100ºC occurred during late Cretaceous rifting and may be partially attributed to a temporary elevation of the regional geothermal gradient. Cooling attributed to late Miocene exhumation, and coincident with estimates of the onset of flat-slab subduction, contributed to modern relief, but cannot explain all of the modern topography. We compare the results from low-temperature thermochronology with the regional sedimentary basin record to confirm that paleorelief plausibly controlled sedimentation patterns throughout the development of the Cenozoic Andean foreland basin at these latitudes. We propose that the history of long-lived topography illustrated in Sierra de Velasco can be expanded to other ranges in the Sierras Pampeanas by integrating multiple data sets.

Discordant K-Ar and Young Exposure Dates for the Windjana Sandstone, Kimberley, Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Vasconcelos, P. M.; Farley, K. A.; Malespin, C. A.; Mahaffy, P.; Ming, D.; McLennan, S. M.; Hurowitz, J. A.; Rice, Melissa S.

2016-01-01

K-Ar and noble gas surface exposure age measurements were carried out on the Windjana sandstone, Kimberley region, Gale Crater, Mars, by using the Sample Analysis at Mars instrument on the Curiosity rover. The sandstone is unusually rich in sanidine, as determined by CheMin X-ray diffraction, contributing to the high K2O concentration of 3.09 +/- 0.20 wt % measured by Alpha-Particle X-ray Spectrometer analysis. A sandstone aliquot heated to approximately 915 C yielded a K-Ar age of 627 +/- 50 Ma. Reheating this aliquot yielded no additional Ar. A second aliquot heated in the same way yielded a much higher K-Ar age of 1710 +/- 110 Ma. These data suggest incomplete Ar extraction from a rock with a K-Ar age older than 1710 Ma. Incomplete extraction at approximately 900 C is not surprising for a rock with a large fraction of K carried by Ar-retentive K-feldspar. Likely, variability in the exact temperature achieved by the sample from run to run, uncertainties in sample mass estimation, and possible mineral fractionation during transport and storage prior to analysis may contribute to these discrepant data. Cosmic ray exposure ages from He-3 and Ne-21 in the two aliquots are minimum values given the possibility of incomplete extraction. However, the general similarity between the He-3 (57 +/- 49 and 18 +/- 32 Ma, mean 30 Ma) and Ne-21 (2 +/- 32 and 83 +/- 24 Ma, mean 54 Ma) exposure ages provides no evidence for underextraction. The implied erosion rate at the Kimberley location is similar to that reported at the nearby Yellowknife Bay outcrop.

Regional uplift episodes along the NE Atlantic margin constrained by stratigraphic and thermochronologic data

NASA Astrophysics Data System (ADS)

Holford, S. P.; Green, P. F.; Hillis, R. R.; Duddy, I. R.; Turner, J. P.; Stoker, M. S.

2008-12-01

The magma-rich NE Atlantic passive margin provides a superb natural laboratory for studying vertical motions associated with continental rifting and the rift-drift transition. Here we present an extensive apatite fission-track analysis (AFTA) database from the British Isles which we combine with a detailed stratigraphic framework for the Cretaceous-Cenozoic sedimentary record of the NE Atlantic margin to constrain the uplift history along and inboard of this margin during the past 120 Myr. We show that the British Isles experienced a series of uplift episodes which began between 120 and 115 Ma, 65 and 55 Ma, 40 and 25 Ma and 20 and 15 Ma, respectively. Each episode is of regional extent (~100,000 sq km) and represents a major period of exhumation involving removal of up to 1 km or more of section. These uplift episodes can be correlated with a number of major tectonic unconformities recognised within the sedimentary succession of the NE Atlantic margin, suggesting that the margin was also affected by these uplift episodes. Anomalous syn- and post-rift uplift along this margin have been interpreted in terms of permanent and/or transient movements controlled by the Iceland plume, but neither the timing nor distribution of the uplift episodes, with the exception of the 65 to 55 Ma episode, supports a first-order control by plume activity on vertical motions. Each uplift episode correlates closely with key deformation events at adjacent plate boundaries, suggesting a causative link, and we examine the ways in which plate boundary forces can account for the observed uplift episodes. Similar km-scale uplift events are revealed by thermochronological studies in other magma-rich and magma-poor continental margins, e.g. SE Australia, South Africa, Brazil. The low angle unconformities which result from these regional episodes of km-scale burial and subsequent uplift are often incorrectly interpreted as representing periods of non-deposition and tectonic stability. Similar

Large Temporal and Spatial Variations in the Eastern Himalayan Syntaxis Exhumation From Detrital Thermochronology

NASA Astrophysics Data System (ADS)

Enkelmann, Eva; Ehlers, Todd A.

2010-05-01

The exhumation rates at the Eastern Himalayan Syntaxis, and in particular at the Namche Barwa anticline, are some of the highest in the Himalaya. At the core of the anticline high-grade metamorphic rocks of Indian crust were exhumed from ca. 40 km depth within <10 Ma. Bedrock thermochronology shows rapid exhumation since <4 Ma that has since migrated north and west of the anticline. The structural history of the anticline and its northern and western surroundings are relatively well studied. However, the geology and exhumation history of the southeastern flank is largely unknown. We present 1500 new detrital zircon fission track cooling ages from 15 modern river samples of the Tsangpo-Siang River and its tributaries. These samples provide cooling ages from drainage basins in the Namche Barwa anticline and the region north, west, and south of it (China and India). Results are as follows: (1) we find eight age populations (0.9 ± 0.2 Ma , 3.5 ± 1 Ma, 7 Ma, 11 ± 2 Ma, 18 ± 2 Ma, 24 ± 2 Ma, 35 ± 5 Ma and 50 - 55 Ma) that quantify temporal variations in the exhumation history of the eastern syntaxis since the Paleocene/Eocene. (2) Cooling ages are consistent with the development of the anticline structure since the Late Miocene. (3) Previous studies have suggested that ~ 50% of the Siang River sediments exiting the Himalaya today originate from only a small area of the Namche Barwa massif. However, our data reveal that the zone of localized rapid exhumation extends significantly (ca. 40 km) further to the southwest of the anticline than previously assumed. Finally, (4) spatial variations in cooling age populations suggest structural differences between the northwestern and southeastern flanks of the anticline. Northwest of the anticline rapid exhumation has migrated beyond the anticline and into the hangingwall (Asia). In the Southeast, the zone of exhumation is strictly limited to the anticline and bounded by a sharp structural boundary along by the Siang River

Volatile element chemistry in the solar nebula - Na, K, F, Cl, Br, and P

NASA Technical Reports Server (NTRS)

Fegley, B., Jr.; Lewis, J. S.

1980-01-01

The results of the most extensive set to date of thermodynamic calculations on the equilibrium chemistry of several hundred compounds of the elements Na, K, F, Cl, Br, and P in a solar composition system are reported. Two extreme models of accretion are investigated. In one extreme complete chemical equilibrium between condensates and gases is maintained because the time scale for accretion is long compared to the time scale for cooling or dissipation of the nebula. Condensates formed in this homogeneous accretion model include several phases such as whitlockite, alkali feldspars, and apatite minerals which are found in chondrites. In the other extreme complete isolation of newly formed condensates from prior condensates and gases occurs due to a time scale for accretion that is short relative to the time required for nebular cooling or dissipation. The condensates produced in this heterogeneous accretion model include alkali sulfides, ammonium halides, and ammonium phosphates. None of these phases are found in chondrites. Available observations of the Na, K, F, Cl, Br, and P elemental abundances in the terrestrial planets are found to be compatible with the predictions of the homogeneous accretion model.

PreK-3rd: How Superintendents Lead Change. PreK-3rd Policy Action Brief. No. Five

ERIC Educational Resources Information Center

Marietta, Geoff

2010-01-01

Leading change to create an integrated PreK-3rd education and connect early learning programs with the K-12 system is not easy. Superintendents require courage to take the first step, persistence and political skills to encourage organizational and community engagement, and a relentless focus on results to measure progress and build momentum. As a…

Intracratonic exhumation and uplift: Insight from low-temperature thermochronology and geomorphic analysis of the Ozark Plateau, Missouri

NASA Astrophysics Data System (ADS)

DeLucia, M. S.; Marshak, S.; Guenthner, W.; Anders, A. M.; Thomson, S. N.

2016-12-01

The Ozark Plateau is an uplift in the cratonic platform of Midcontinent United States. In the northeast corner of the plateau (the St. Francois Mountains), Precambrian basement of 1.47 Ga granite and rhyolite crops out. These rocks are overlain, at the Great Unconformity, by Paleozoic strata, defining the map pattern of the Ozark Dome. Strata thicken substantially eastward into the Illinois Basin, so that there is over 7 km of structural relief across the boundary between the Illinois Basin and the Ozark Dome at the level of the Great Unconformity. Multiple unconformities in the Paleozoic section indicates that the crest of the Ozark Dome was at or above sea level several times during the Paleozoic. Key questions about the Plateau remain. For example: (1) Did the 1.47 Ga basement remain at upper-crustal depths since its formation, or was it buried deeply and later exhumed? (2) Has the plateau remained high since the Paleozoic or has it undergone post-Paleozoic uplift? Results from new zircon (U-Th)/He thermochronology indicate that the 1.47 Ga granites were exhumed significantly in the Neoproterozoic (about 750Ma), after the Rodinia supercontinent assembly. Fission-track dates (Brown, 2005) and (U-Th)/He apatite dates (Flowers and Kelley, 2011; Zhang et al., 2012; and new results) hint that some post-Paleozoic exhumation has occurred. Analysis of a high-resolution DEM of the Ozark Plateau supports this proposal; bedrock-incising streams occur throughout the plateau (locally producing incised meanders), and strath terraces can be identified. The rate of uplift, however, must be relatively slow, for drainages do not display knick points, and drainage networks display mature profiles. Given these constraints, we propose that the lithospheric architecture that distinguished the Ozark Dome from the Illinois Basin became established in the Neoproterozoic, and that the Ozark Plateau has been maintained isostatically by subsequent slow exhumation.

Using apatite fission track thermochronology to document the deformation sequence in an exhumed foreland basin: an example from the southern Pyrenees.

NASA Astrophysics Data System (ADS)

Meresse, F.; Labaume, P.; Jolivet, M.; Teixell, A.

2009-04-01

Université Montpellier 2, INSU-CNRS, Laboratoire Géosciences Montpellier, cc060, 34095 Montpellier Cedex 5, France florian.meresse@gm.univ-montp2.fr The study of foreland basins provides important constraints on the evolution of orogenic wedges. In particular, the study of tectonics-sedimentation relationships is essential to date the tectonic activity. However, processes linked to wedge growth are not always completely recorded by the tecto-sedimentary markers, and thermochronological study of the basin-fill can provide further insights. In this work, we have combined apatite fission track analysis (apatite FTA) with structural analysis to precise the timing of the deformation sequence and to characterise the coupling between thrust activity, burial and denudation in the south-Pyrenean foreland basin, a proximal foredeep of the Pyrenees that has been incorporated in the Pyrenean thrust wedge. We have focused the study on a NNE-SSW cross-section of the south-vergent thrust system from the southern flank of the Axial Zone to the South-Pyrenean Frontal Thrust (SPFT), in the west-central part of the belt. This section provides a complete transverse of the South-Pyrenean Zone, here corresponding to the Ainsa and Jaca basins. Apatite FTA provides important new constraints on the south-Pyrenean foreland basin evolution: (i) Data show the southward decrease of the fission track reset level, from a total reset (indicating heating at Tmax>110°C) in the Paleozoic of the Axial Zone, to a partial reset (110°C>Tmax>60°C) in the lower-middle Eocene Hecho Group turbidites in the northern part of the Jaca basin, and to the absence of reset (Tmax<60°C) in the middle Eocene-Oligocene continental sediments of the southern part of the Jaca basin. This indicates a decreasing amount of denudation going southwards, from more than 4.5 km in the north to less than 2.5 km in the south if we assume an average geothermal gradient around 25°/km. The structural setting of the Jaca basin

Tackling Health Inequalities in the United Kingdom: The Progress and Pitfalls of Policy

PubMed Central

Exworthy, Mark; Blane, David; Marmot, Michael

2003-01-01

Goal Assess the progress and pitfalls of current United Kingdom (U.K.) policies to reduce health inequalities. Objectives (1) Describe the context enabling health inequalities to get onto the policy agenda in the United Kingdom. (2) Categorize and assess selected current U.K. policies that may affect health inequalities. (3) Apply the “policy windows” model to understand the issues faced in formulating and implementing such policies. (4) Examine the emerging policy challenges in the U.K. and elsewhere. Data Sources Official documents, secondary analyses, and interviews with policymakers. Study Design Qualitative, policy analysis. Data Collection 2001–2002. The methods were divided into two stages. The first identified policies which were connected with individual inquiry recommendations. The second involved case-studies of three policies areas which were thought to be crucial in tackling health inequalities. Both stages involved interviews with policy-makers and documentary analysis. Principal Findings (1) The current U.K. government stated a commitment to reducing health inequalities. (2) The government has begun to implement policies that address the wider determinants. (3) Some progress is evident but many indicators remain stubborn. (4) Difficulties remain in terms of coordinating policies across government and measuring progress. (5) The “policy windows” model explains the limited extent of progress and highlights current and possible future pitfalls. (6) The U.K.'s experience has lessons for other governments involved in tackling health inequalities. Conclusions Health inequalities are on the agenda of U.K. government policy and steps have been made to address them. There are some signs of progress but much remains to be done including overcoming some of the perverse incentives at the national level, improving joint working, ensuring appropriate measures of performance/progress, and improving monitoring arrangements. A conceptual policy model aids

Progress on 10 Kelvin cryo-cooled sapphire oscillator

NASA Technical Reports Server (NTRS)

Wang, Rabi T.; Dick, G. John; Diener, William A.

2004-01-01

We present recent progress on the 10 Kelvin Cryocooled Sapphire Oscillator (10K CSO). Included are incorporation of a new pulse tube cryocooler, cryocooler vibration comparisons between G-M and pulse-tube types, phase noise, and frequency stability tests. For the advantage of a single stage pulse tube cryocooler, we also present results for a 40K Compensated Sapphire Oscillator (40K CSO).

Progress report on geologic studies of the Ranger orebodies, Northern Territory, Australia

USGS Publications Warehouse

Nash, J.T.; Frishman, David

1982-01-01

that probably formed in part by progressive removal of carbonate rocks that are as much as 200 m thick adjacent to the No. 1 orebody and below the No. 3 orebody. Quartz-chlorite breccias have formed in the zone of carbonate thinning; uranium is spotty and low grade in these breccias. Chloritized and uraniferous broken and sheared zones, a few centimeters to a few meters thick, have an unknown attitude but must have small displacement. Blocks of altered Kombolgie sandstone are downfaulted into the No. 3 orebody and locally contain reduced uranium minerals. One or more shear zones 5-30 m thick of crushed and smeared fine to coarse rock fragments occur below the orebodies, and other low-angle shears probably occur in the orebodies. The shear zone dips about 40 o and displacement on it is not known. The footwall rocks generally are less retrograded than those in the hanging wall (orebody) and consist of quartz-biotite-feldspar schists and gneisses flanking the Nanambu Complex. A few scattered fractures in the footwall sequence contain pitchblende of unknown age and origin. Major element chemical analyses confirm the lithologic observations of large changes in composition during multiple stages of alteration. Granitic dikes and pelitic schists have gained Fe and Mg and lost Si, Ca, Na, and K during chloritization. Marbles have gained Si, Al, Fe, and P, and lost Mg, Ca, and K during jasperoid-chlorite alteration. Total net chemical gains and losses in the Ranger No. 1 orebody were huge: equal to about 37 percent of the mass of the ore-bearing rock that will be mined. There were net gains in Si and P and net losses in Al, Fe, Mg, Ca, K, and Na. The geologic age(s) of uranium emplacement are obscure because there are few age criteria. Reduced uranium minerals are younger than 1.8-b.y.-old granite dikes, and some occur locally in 1.65-b.y.-old Kombolgie Formation. Diabase dikes (age not known) are thoroughly chloritized and contain sparse ore minerals. Oxidized ura

Shocked quartz and more: Impact signatures in K-T boundary clays and claystones

NASA Technical Reports Server (NTRS)

Bohor, Bruce F.

1988-01-01

Quartz grains displaying multiple sets of planar features are described from numerous Cretaceous-Tertiary (K-T) boundary clays and claystones at both marine and nonmarine depositional sites around the world. All these sites also show anomalously high amounts of iridium and enrichments of other siderophile elements in cosmic ratios within these boundary units. This combination of mineralogical and geochemical features are used in support of an impact hypothesis for the end-Cretaceous event. Recently, it was suggested that some combination of explosive and nonexplosive volcanism associated with the formation of the Deccan traps in India could be responsible for the mineralogy and geochemistry seen in the K-T boundary units. Besides the obvious contradition of simultaneous explosive and nonexplosive volcanism from one locality during an instant of geologic time, there remains the difficulty of spreading both iridium (and trace elements in cosmic proportions) and quartz grains around the world by volcanic (atmospheric) transport. In addition, the ability of volcanism to produce the type of shock metamorphism seen in minerals at the K-T boundary was not demonstrated. Multiple sets of shock lamellae in quartz are considered characteristic of shock metamorphism in rocks at the sites of known impact craters and are the type of deformation seen in quartz from K-T boundary clays and claystones. Single sets of poorly defined lamellae described from rare quartz grains in certain volcanic deposits are characteristic of tectonic deformation and do not correspond to the shock lamellae in quartz from K-T sediments and impact structures. So-called shock mosaicism in quartz and feldspar grains described from volcanic deposits can result from many processes other than shock metamorphism, and therefore is not considered to be an effect characteristic solely of shock. The mineralogy of shock-metamorphosed grains at the K-T boundary also argues against a volcanic origin.

Magma hybridization in the Western Tatra Mts. granitoid intrusion (S-Poland, Western Carpathians).

PubMed

Burda, Jolanta; Gawęda, Aleksandra; Klötzli, Urs

In the Variscan Western Tatra granites hybridization phenomena such as mixing and mingling can be observed at the contact of mafic precursors of dioritic composition and more felsic granitic host rocks. The textural evidence of hybridization include: plagioclase-K-feldspar-sphene ocelli, hornblende- and biotite-rimmed quartz ocelli, plagioclase with Ca-rich spike zonation, inversely zoned K-feldspar crystals, mafic clots, poikilitic plagioclase and quartz crystals, mixed apatite morphologies, zoned K-feldspar phenocrysts. The apparent pressure range of the magma hybridization event was calculated at 6.1 kbar to 4.6 kbar, while the temperature, calculated by independent methods, is in the range of 810°C-770°C. U-Pb age data of the hybrid rocks were obtained by in-situ LA-MC-ICP-MS analysis of zircon. The oscillatory zoned zircon crystals yield a concordia age of 368 ± 8 Ma (MSWD = 1.1), interpreted as the age of magma hybridization and timing of formation of the magmatic precursors. It is the oldest Variscan magmatic event in that part of the Tatra Mountains.

Melting in feldspar-bearing systems to high pressures and the structures of aluminosilicate liquids

NASA Astrophysics Data System (ADS)

Boettcher, Art; Guo, Qiti; Bohlen, Steve; Hanson, Brooks

1984-04-01

To test the possibility that aluminosilicate liquids exhibit pressure-induced transformations, particularly involving changes in the coordination of aluminum, we determined melting relationships for the feldspar-bearing systems NaAlSi3O8-SiO2, KAlSi3O8-SiO2, and CaAl2Si2O8-SiO2 from 1 atm to 25 kbar. Albite and anorthite behave similarly in that they, and presumably liquids of these compositions, transform at high pressures to jadeite, kyanite, corundum, and other structures with aluminum in six-fold coordination, releasing SiO2 component. This results in a large increase in the activity of SiO2 component in the liquid (alqz), which is manifested by a significant decrease in the melting-point depression of albite and of anorthite by the addition of quartz at pressures above ˜15 kbar. In contrast, sanidine does not transform to denser phases at pressures below at least 100 kbar, but it melts incongruently to leucite + SiO2-rich liquid up to ˜ 15 kbar. This produces a relatively large alqz and a small freezing-point depression by quartz below this pressure; the opposite holds above ˜15 kbar. These results support the concept that significant structural changes, including coordination changes in aluminum, occur in magmas in the upper mantle.

Pupil Progression Plan: Requirements and Procedures 1982-83.

ERIC Educational Resources Information Center

Duval County School Board, Jacksonville, FL.

The Pupil Progression Plan detailed in this document was developed in response to Florida's Educational Accountability Act, which requires each school district to establish a comprehensive program for pupil progression, and to fulfill the requirements of school board policy. The first section details general procedures for promotion, grades K-12.…

Late Cenozoic cooling history of the central Menderes Massif and the contribution of erosion to rock exhumation during active continental extension

NASA Astrophysics Data System (ADS)

Nilius, Nils-Peter; Wölfler, Andreas; Heineke, Caroline; Glotzbach, Christoph; Hetzel, Ralf; Hampel, Andrea; Akal, Cüneyt; Dunkl, István

2017-04-01

The Menderes Massif constitutes the western part of the Anatolide belt in western Turkey and experienced a prolonged history of post-orogenic extension. A large amount of the extension was accommodated by the two oppositely dipping Gediz and Büyük Menderes detachment faults, which led to the exhumation of the central Menderes Massif (Gessner et al., 2013). Previous studies proposed a synchronous, bivergent exhumation of the central Menderes Massif since the Miocene (Gessner et al., 2001), although only the evolution of the north-dipping Gediz detachment is well constrained (Buscher et al., 2013). Detailed structural and thermochronological investigations from the south-dipping Büyük Menderes detachment have still been missing. Here we present results from different thermochronometers, which constrain the cooling and exhumation history of footwall and hanging wall rocks of the Büyük Menderes detachment. Our new zircon and apatite (U-Th)/He and fission track ages of footwall rocks from the Büyük Menderes detachment document two phases of increased cooling and exhumation (Wölfler et al., in revision). The first episode of increased footwall exhumation ( 0.9 km/Myr) occurred during the middle Miocene, followed by a second phase during latest Miocene and Pliocene ( 1.0 km/Myr). Apatite fission track ages yield a slip rate for the Pliocene movement along the Büyük Menderes detachment of 3.0 (+1.1/-0.6) km/Myr. Thermochronological data of hanging wall units reflect a slow phase of exhumation ( 0.2 km/Myr) in the late Oligocene and an increased exhumation rate of 1.0 km/Myr during the early to middle Miocene, when hanging wall units cooled below 80 °C. In comparison with the Gediz detachment, our thermochronological data from the Büyük Menderes detachment confirms the concurrent activity of both detachments during the late Miocene and Pliocene. With respect to the relative importance of normal faulting and erosion to rock exhumation, a comparison with 10Be

In-situ 40Ar/39Ar Laser Probe Dating of Micas from Mae Ping Shear Zone, Northern Thailand

NASA Astrophysics Data System (ADS)

Lin, Y. L.; Yeh, M. W.; Lo, C. H.; Lee, T. Y.; Charusiri, P.

2012-04-01

The Mae Ping Shear Zone (MPSZ, also known as Wang Chao Fault Zone), which trends NW-SE from Myanmar to central Thailand, was considered as the southern boundary of the SE extrusion of Indochina and Sibumasu block during the Cenozoic escape tectonic event of SE asia. Many analyses of 40Ar/39Ar dating on biotite and K-feldspar, K/Ar dating on biotite and illite, zircon fission-track and apatite fission-track dating had been accomplished to constrain the shearing period. Nevertheless, it is hard to convince that the ages could represent the end of the shearing since none of the dated minerals have been proved to be crystallized syn-tectonically. Meta-granitoid and gneiss from the MPSZ were analyzed in this study by applying in-situ 40Ar/39Ar laser probe dating with combination of petrology and micro-structural analysis in the purpose to decipher the geological significance of the dates. Plagioclase was replacing K-feldspar for K-feldspar was cut and embayed by plagioclase observed by SEM + EDS. Muscovite in the granitoid own fish shapes of sinistral sense of shearing, and are always in contact with plagioclase and quartz, which suggests that the muscovite crystallized from the dissolving K-feldspar under amphibolite facies condition. 117 spots on 12 muscovite fishes yield ages from 44 Ma to 35 Ma and have a mean age of 40 Ma. Since the growth condition of the muscovite is higher than the closure temperature, thus we can interpret these muscovite ages as cooling ages. Hence left-lateral shearing of the MPSZ can be deduced as syn- to post-muscovite growth and uplifted the crystalline rocks within the shear zone. The ages of matrix biotite in gneiss has a mean age of 35 Ma, which is consistent with the cooling path reconstructed from previous studies. While the ages of inclusion biotite in the K-feldspar phenocryst scatter from 40 to 50 Ma due to the isotopes were not totally re-equilibrated during the shearing. Consequently, the left-lateral shearing of the MPSZ was

Ordovician K-bentonites in the Argentine Precordillera: relations to Gondwana margin evolution

USGS Publications Warehouse

Huff, W.D.; Bergstrom, Stig M.; Kolata, Dennis R.; Cingolani, C.A.; Astini, R.A.

1998-01-01

This paper is included in the Special Publication entitled 'The proto- Andean margin of Gondwana', edited by R.J. Pankhurst and C.W. Rapela. Ordovician K-bentonites have now been recorded from >20 localities in the vicinity of the Argentine Precordillera. Most occur in the eastern thrust belts, in the San Juan Limestone and the overlying the Gualcamayo Formation, but a few ash beds are known also from the central thrust belts. The oldest occur in the middle Arenig I, victoriae lunatus graptolite (Oe. evae conodont) Zone, and the youngest in the middle Llanvirn P. elegans (P. suecicus) Zone. Mineralogical characteristics, typical of other Ordovician K-bentonites, include a matrix of illite/smectite mixed-layer clay and a typical felsic volcanic phenocryst assemblage: biotite, beta-form quartz, alkali and plagioclase feldspar, apatite, and zircon, with lesser amounts of hornblende, clinopyroxene, titanite and Fe-Ti oxides. The proportions of the mineral phases and variations in their crystal chemistry are commonly unique to individual (or small groups of) K-bentonite beds. Glass melt inclusions preserved in quartz are rhyolitic in composition. The sequence is unique in its abundance of K-bentonite beds, but a close association between the Precordillera and other Ordovician sedimentary basins cannot be established. The ash distribution is most consistent with palaeogeographical reconstructions in which early Ordovician drifting of the Precordillera occurred in proximity to one or more volcanic arcs, and with eventual collision along the Andean margin of Gondwana during the mid-Ordovician Ocloyic event of the Famatinian orogeny. The Puna-Famatina terrane northeast of the Precordillera might have served as the source of the K-bentonite ashes, possibly in concert with active arc magmatism on the Gondwana plate itself.

Progress in Noise Thermometry at 505 K and 693 K Using Quantized Voltage Noise Ratio Spectra

NASA Astrophysics Data System (ADS)

Tew, W. L.; Benz, S. P.; Dresselhaus, P. D.; Coakley, K. J.; Rogalla, H.; White, D. R.; Labenski, J. R.

2010-09-01

Technical advances and new results in noise thermometry at temperatures near the tin freezing point and the zinc freezing point using a quantized voltage noise source (QVNS) are reported. The temperatures are derived by comparing the power spectral density of QVNS synthesized noise with that of Johnson noise from a known resistance at both 505 K and 693 K. Reference noise is digitally synthesized so that the average power spectra of the QVNS match those of the thermal noise, resulting in ratios of power spectra close to unity in the low-frequency limit. Three-parameter models are used to account for differences in impedance-related time constants in the spectra. Direct comparison of noise temperatures to the International Temperature Scale of 1990 (ITS-90) is achieved in a comparison furnace with standard platinum resistance thermometers. The observed noise temperatures determined by operating the noise thermometer in both absolute and relative modes, and related statistics together with estimated uncertainties are reported. The relative noise thermometry results are combined with results from other thermodynamic determinations at temperatures near the tin freezing point to calculate a value of T - T 90 = +4(18) mK for temperatures near the zinc freezing point. These latest results achieve a lower uncertainty than that of our earlier efforts. The present value of T - T 90 is compared to other published determinations from noise thermometry and other methods.

Surface Evolution and Uplift History of the Central Apennines, Italy: New Constraints from Thermochronology and Paleoaltimetry

NASA Astrophysics Data System (ADS)

San José, M.; Faccenna, C.; Fellin, M. G.; Willett, S.; Funiciello, F.; Caves Rugenstein, J. K.

2017-12-01

The topography of mountain belts results from interactions between surface processes, lithospheric thickening, and mantle dynamics. However, the contributions of each mechanism have yet to be clearly quantified. The Apennines (Italy) provide a study area where all of these processes are at play. The central part of the Apennines is an orogenic wedge formed by the westward subducting Adriatic microplate during Miocene-Pliocene, and overlies an area of local slab detachment. Recent studies indicate anomalously high uplift rates in this area (Faccenna et al., 2015), as well as a simultaneous onset of post-orogenic extension across the Central Apennines at ̴ 2 Ma (Cosentino et al., 2017). These observations have been interpreted as an expression of dynamic topography due to the slab break-off and inherent mantle upwelling. In order to test this hypothesis and further constrain the topographic evolution of the orogen, we use low-temperature thermochronology to date the exhumation, and stable isotope paleoaltimetry (18O/16O on carbonates) to reconstruct paleoelevations. We couple this paleotopographic dataset with geomorphological analysis of the present day topography. Here we present a set of 30 new (U-Th)/He cooling ages on apatites (AHe) sampled from widespread syn-orogenic flysch basin deposits (including one high-resolution vertical profile), as well as preliminary isotopic measurements. Initial results show mean AHe ages ranging from 1.62 (± 0.38 ) Ma to 2.6 (±0.02) Ma, suggesting a regionally uniform exhumation during Pleistocene. Denudation rates inferred from our vertical profile are extremely high (>1 mm/year from 2 to 1 Ma). Some samples have not been thermally reset due to insufficient burial, and yield exhumation ages older than stratigraphic depositional ages (generally > 5 Ma). These results support the hypothesis that exhumation is mainly controlled by rapid regional scale uplift related to the opening of the Adriatic slab window at the end of the

Hydration Experiments and Physical Observations at 193 K and 243 K for Mg-Sulfates Relevant to Mars

NASA Astrophysics Data System (ADS)

Vaniman, D. T.; Chipera, S. J.; Carey, J. W.

2006-03-01

Hydration of kieserite and amorphous Mg-sulfate at 243 K progresses along simple pathways involving only hexahydrite and kieserite. Kieserite forms a duricrust-like cement, but the anhydrous precursor does not.

Tracking the multiple-stage exhumation history and magmatic-hydrothermal events of the West Junggar region, NW China: Evidence from 40Ar/39Ar and (U-Th)/He thermochronology

NASA Astrophysics Data System (ADS)

Yin, Jiyuan; Chen, Wen; Xiao, Wenjiao; Long, Xiaoping; Tao, Ni; Liu, Li-Ping; Yuan, Chao; Sun, Min

2018-06-01

To decipher cooling events in the West Junggar region, biotite and K-feldspar 40Ar/39Ar, and zircon and apatite (U-Th)/He isotopic analyses of intrusive rocks were carried out. Previous U-Pb data showed that intrusive bodies in the Baogutu area were emplaced at 315-310 Ma. U-Pb and zircon (U-Th)/He dating results (313-241 Ma) suggest that a magmatic-hydrothermal event lasted for 72 Ma in the Baogutu area of the West Junggar region. Early-stage high temperature alteration (900-300 °C) lasted for 6-2 Ma and was followed by prolonged phyllic and argillic alteration lasting 67-63 Ma between 350 and 200 °C. Finally, slower cooling occurred between 200 and 70 °C, accompanied by post-mineralization uplift and erosion. In this study, three main episodes of relatively rapid cooling were distinguished in the West Junggar region, i.e. late Carboniferous-early Permian (307-277 Ma), middle Triassic (241-232 Ma) and early Cretaceous (145-120 Ma). The first rapid cooling during the late Carboniferous-early Permian was possibly associated with the release of magmatic heat. The middle Triassic and early Cretaceous cooling and exhumation are interpreted as a response to collision(s) between the Qiangtang and Kunlun-Qaidam or Lhasa blocks. The Cenozoic India-Eurasia collision, however, may have had little or no effect on modern tectonic reactivation of the West Junggar region.

The activation of human endogenous retrovirus K (HERV-K) is implicated in melanoma cell malignant transformation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Serafino, A.; Balestrieri, E.; Pierimarchi, P.

2009-03-10

Melanoma development is a multi-step process arising from a series of genetic and epigenetic events. Although the sequential stages involved in progression from melanocytes to malignant melanoma are clearly defined, our current understanding of the mechanisms leading to melanoma onset is still incomplete. Growing evidence show that the activation of endogenous retroviral sequences might be involved in transformation of melanocytes as well as in the increased ability of melanoma cells to escape immune surveillance. Here we show that human melanoma cells in vitro undergo a transition from adherent to a more malignant, non-adherent phenotype when exposed to stress conditions. Melanoma-derivedmore » non-adherent cells are characterized by an increased proliferative potential and a decreased expression of both HLA class I molecules and Melan-A/MART-1 antigen, similarly to highly malignant cells. These phenotypic and functional modifications are accompanied by the activation of human endogenous retrovirus K expression (HERV-K) and massive production of viral-like particles. Down-regulation of HERV-K expression by RNA interference prevents the transition from the adherent to the non-adherent growth phenotype in low serum. These results implicate HERV-K in at least some critical steps of melanoma progression.« less

PSMA redirects cell survival signaling from the MAPK to the PI3K-AKT pathways to promote the progression of prostate cancer

PubMed Central

Caromile, Leslie Ann; Dortche, Kristina; Rahman, M. Mamunur; Grant, Christina L.; Stoddard, Christopher; Ferrer, Fernando A.; Shapiro, Linda H.

2017-01-01

Increased abundance of the prostate-specific membrane antigen (PSMA) on prostate epithelium is a hallmark of advanced metastatic prostate cancer (PCa) and correlates negatively with prognosis. However, direct evidence that PSMA functionally contributes to PCa progression remains elusive. We generated mice bearing PSMA-positive or PSMA-negative PCa by crossing PSMA-deficient mice with transgenic PCa (TRAMP) models, enabling direct assessment of PCa incidence and progression in the presence or absence of PSMA. Compared with PSMA-positive tumors, PSMA-negative tumors were smaller, lower-grade, and more apoptotic with fewer blood vessels, consistent with the recognized proangiogenic function of PSMA. Relative to PSMA-positive tumors, tumors lacking PSMA had less than half the abundance of type 1 insulin-like growth factor receptor (IGF-1R), less activity in the survival pathway mediated by PI3K-AKT signaling, and more activity in the proliferative pathway mediated by MAPK-ERK1/2 signaling. Biochemically, PSMA interacted with the scaffolding protein RACK1, disrupting signaling between the β1 integrin and IGF-1R complex to the MAPK pathway, enabling activation of the AKT pathway instead. Manipulation of PSMA abundance in PCa cell lines recapitulated this signaling pathway switch. Analysis of published databases indicated that IGF-1R abundance, cell proliferation, and expression of transcripts for antiapoptotic markers positively correlated with PSMA abundance in patients, suggesting that this switch may be relevant to human PCa. Our findings suggest that increase in PSMA in prostate tumors contributes to progression by altering normal signal transduction pathways to drive PCa progression and that enhanced signaling through the IGF-1R/β1 integrin axis may occur in other tumors. PMID:28292957

Progress toward a unified kJ-machine CANDY

NASA Astrophysics Data System (ADS)

Kitagawa, Yoneyoshi; Mori, Yoshitaka; Komeda, Osamu; Hanayama, Ryohei; Ishii, Katsuhiro; Okihara, Shinichiro; Fujita, Kazuhisa; Nakayama, Suisei; Sekine, Takashi; Sato, Nakahiro; Kurita, Takashi; Kawashima, Toshiyuki; Watari, Takeshi; Kan, Hirofumi; Nakamura, Naoki; Kondo, Takuya; Fujine, Manabu; Azuma, Hirozumi; Motohiro, Tomoyoshi; Hioki, Tatsumi; Kakeno, Mitsutaka; Nishimura, Yasuhiko; Sunahara, Atsushi; Sentoku, Yasuhiko; Miura, Eisuke; Arikawa, Yasunobu; Nagai, Takahiro; Abe, Yuki; Ozaki, Satoshi; Noda, Akira

2016-03-01

To construct a unified experimental machine CANDY using a kJ DPSSL driver in the fast-ignition scheme, the Laser for Fast Ignition Experiment (LFEX) at Osaka is used, showing that the laser-driven ions heat the preimploded core of a deuterated polystyrene (CD) shell target from 0.8 keV to 2 keV, resulting in 5 x 108 DD neutrons best ever obtained in the scheme. 4-J/10-Hz DPSSL laser HAMA is for the first time applied to the CD shell implosion- core heating experiments in the fast ignition scheme to yield neutrons and also to a continuous target injection, which yields neutrons of 3 x 105 n/4πsr n/shot.

Certain and progressive methylation of histone H4 at lysine 20 during the cell cycle.

PubMed

Pesavento, James J; Yang, Hongbo; Kelleher, Neil L; Mizzen, Craig A

2008-01-01

Methylation of histone H4 at lysine 20 (K20) has been implicated in transcriptional activation, gene silencing, heterochromatin formation, mitosis, and DNA repair. However, little is known about how this modification is regulated or how it contributes to these diverse processes. Metabolic labeling and top-down mass spectrometry reveal that newly synthesized H4 is progressively methylated at K20 during the G(2), M, and G(1) phases of the cell cycle in a process that is largely inescapable and irreversible. Approximately 98% of new H4 becomes dimethylated within two to three cell cycles, and K20 methylation turnover in vivo is undetectable. New H4 is methylated regardless of prior acetylation, and acetylation occurs predominantly on K20-dimethylated H4, refuting the hypothesis that K20 methylation antagonizes H4 acetylation and represses transcription epigenetically. Despite suggestions that it is required for normal mitosis and cell cycle progression, K20 methylation proceeds normally during colchicine treatment. Moreover, delays in PR-Set7 synthesis and K20 methylation which accompany altered cell cycle progression during sodium butyrate treatment appear to be secondary to histone hyperacetylation or other effects of butyrate since depletion of PR-Set7 did not affect cell cycle progression. Together, our data provide an unbiased perspective of the regulation and function of K20 methylation.

In Situ UV-Laser Ablation 40Ar/39Ar Muscovite Thermochronology Reveals Excess Argon and 405-399 Ma Age for the Nordfjord-Sogn Detachment Zone, Hornelen region, Norway

NASA Astrophysics Data System (ADS)

Johnston, S. M.; Hacker, B. R.; Eide, E. A.; Hendriks, B.

2006-12-01

The Nordfjord-Sogn Detachment Zone (NSDZ) is a 2-6 km thick, normal-sense shear zone that juxtaposes the eclogite-bearing Western Gneiss Complex in its footwall with Devonian sediments in its hangingwall, and is widely cited as the primary structure responsible for the exhumation of the Norwegian ultrahigh-pressure (UHP) rocks. Critical to our understanding of this crustal-scale detachment, detailed thermochronology places essential constraints on the rates of exhumation and documents spatial variability in the timing of exhumation- related cooling. Regional thermochronology has shown that 40Ar/39Ar muscovite ages increase gradually from 405-390 Ma across the Western Gneiss Complex and into the lower part of the NSDZ, but at higher structural levels within the NSDZ, these ~400 Ma ages are mixed with an older population at 420-418 Ma. Although neither excess argon nor incomplete resetting of argon in these older samples has been ruled out, these results have been interpreted to suggest that extension and exhumation within the NSDZ may have initiated as early as 420 Ma. Here, we investigate these older 40Ar/39Ar muscovite ages by comparing resistance furnace (RF) ages from bulk muscovite separates with in situ UV-laser ablation ages from a suite of 6 samples that transect the NSDZ. RF spectra from 5 of the 6 analyzed samples yield plateau ages that range from 405-399 Ma; in situ ages of these same 5 samples reveal no age zonation within large grains and no differences in ages among texturally different grains. In contrast, the structurally highest sample yields a RF plateau age of 425±6 Ma, and in situ ages of 474-417 Ma in grain cores and c. 400 Ma in grain rims and small grains. On an inverse isochron diagram, these in situ ages define two distinct populations, with grain cores distributed along a line between an excess argon component of 40Ar/36Ar = 660±60 and an age of 404±7 Ma. Analyses from rims and small grains plot in triangle defined by these two apices

Accretion and canal impacts in a rapidly subsiding wetland II: Feldspar marker horizon technique

USGS Publications Warehouse

Cahoon, D.R.; Turner, R.E.

1989-01-01

Recent (6-12 months) marsh sediment accretion and accumulation rates were measured with feldspar marker horizons in the vicinity of natural waterways and man-made canals with spoil banks in the rapidly subsiding environment of coastal Louisiana. Annual accretion rates in a Spartina alterniflora salt marsh in the Mississippi deltaic plain averaged 6 mm in marsh adjacent to canals compared to 10 mm in marsh adjacent to natural waterways. The rates, however, were not statistically significantly different. The average rate of sediment accretion in the same salt marsh region for a transect perpendicular to a canal (13 mm yr-1) was significantly greater than the rate measured for a transect perpendicular to a natural waterway (7 mm yr-1). Measurements of soil bulk density and organic matter content from the two transects were also different. This spatial variability in accretion rates is probably related to (1) spoil bank influences on local hydrology; and (2) a locally high rate of sediment input from lateral erosion associated with pond enlargement. In a brackish Spatina patens marsh on Louisiana's chenier plain, vertical accretion rates were the same along natural and canal waterways (3-4 mm yr-1) in a hydrologically restricted marsh region. However, the accretion rates for both waterways were significantly lower than the rates along a nonhydrologically restricted natural waterway nearby (11 mm yr-1). The vertical accretion of matter displayed semi-annual differences in the brackish marsh environment.

Meso-Cenozoic evolution of the Tuareg Shield (Algeria, Sahara): insights from new thermochronological data

NASA Astrophysics Data System (ADS)

Rougier, Sylvain; Missenard, Yves; Gautheron, Cécile; Barbarand, Jocelyn; Zeyen, Hermann; Pinna, Rosella; Liégeois, Jean-Paul; Bonin, Bernard; Ouabadi, Aziouz; El-Messaoud Derder, Mohammed; Frizon de Lamotte, Dominique; Kettouche, Djouher

2013-04-01

In North Africa, Meso-Cenozoic large scale topographic swells, such as Hoggar, Tibesti or Darfur domes, are superimposed to a Paleozoic arch and basin morphology which characterizes this region. Although these topographic highs are associated to Cenozoic intraplate volcanism, their development remains poorly constrained, both from temporal and spatial points of view. This study is focused on the Tuareg Shield bulge, a topographic high where Precambrian rocks, exposed over 500000 km², can reach 2400 m above sea level (Atakor district, Hoggar, South Algeria). While presumed Cretaceous sedimentary remnants, resting unconformably over the basement, suggest a possible stage of weak topography during the Mesozoic, current high topography is emphasized by <35 Ma volcanic formations, mostly basaltic in composition. In this context, we present first apatite (U-Th)/He thermochronological data acquired across the whole swell (Rougier et al., Geology, in press). Mean ages range from 78 ± 22 Ma to 13 ± 3 Ma. These results demonstrate the existence of a widespread Eocene exhumation of the shield before volcanic activity began. In the northeastern part of the swell, Cretaceous sedimentary remnants unconformably lying on the basement close to our samples evidence that they were near the surface at that time. We show that basement rocks have thus suffered a subsequent heating stage at 60-80 °C. We also present new apatite fission track ages on same samples. Central ages range from 71 ± 6 to 285 ± 29 Ma. When track length measurements were possible, preliminary modelings of the time-temperature history were performed. As previously deduced from apatite (U-Th)/He analyzes, these modelings show that samples underwent a heating to at least 80°C before their Late Eocene exhumation. Moreover, they also indicate that samples underwent another cooling stage during Lower Cretaceous, prior to Upper Cretaceous/Paleogene heating. We interpret these results as an evidence of a large

Adsorption of N-tallow 1,3-propanediamine-dioleate collector on albite and quartz minerals, and selective flotation of albite from greek stefania feldspar ore.

PubMed

Vidyadhar, A; Hanumantha Rao, K; Forssberg, K S E

2002-04-01

The adsorption behavior of tallow 1,3-propanediamine-dioleate (Duomeen TDO) collector on albite and quartz minerals is assessed through Hallimond flotation, zeta potential, and diffuse reflectance FTIR investigations, together with the species distribution of the collector. The collector performance on albite separation from a natural feldspar material is evaluated in bench scale flotation tests. The Hallimond flotation responses of the minerals as a function of pH and collector concentration indicate that albite can be selectively floated from quartz at pH 2 where the doubly positively charged collector species adsorb on albite but not on quartz. However, the zeta potential and infrared spectra reveal that the adsorption behavior of the collector is similar on both minerals. The discrepancy in the flotation and adsorption results is attributed to the coarse and fine particle size fractions, and the shorter and longer equilibration periods employed in these studies respectively. The comparable adsorption on fine particles of albite and quartz at pH 2 is explained by the interaction of ammonium ions on silanol groups by hydrogen bonding as well as electrostatic interactions. The changes in zeta potentials are in good agreement with the formation of ionic species and free molecular forms of the collector. The IR spectra show the coexistence of neutral oleic acid together with charged amine species at low pH values in accordance with the species distribution diagram. Selective flotation of albite is accomplished from a natural feldspar material with tallow diamine-dioleate collector at pH 2 using sulfuric acid, only when the feed is deslimed prior to the bench scale flotation tests. An albite recovery exceeding 85% is achieved from a feed material containing about 50% albite.

Progressive Chromatin Condensation and H3K9 Methylation Regulate the Differentiation of Embryonic and Hematopoietic Stem Cells

DOE PAGES

Ugarte, Fernando; Sousae, Rebekah; Cinquin, Bertrand; ...

2015-10-17

Epigenetic regulation serves as the basis for stem cell differentiation into distinct cell types, but it is unclear how global epigenetic changes are regulated during this process. Here, we tested the hypothesis that global chromatin organization affects the lineage potential of stem cells and that manipulation of chromatin dynamics influences stem cell function. Using nuclease sensitivity assays, we found a progressive decrease in chromatin digestion among pluripotent embryonic stem cells (ESCs), multipotent hematopoietic stem cells (HSCs), and mature hematopoietic cells. Quantitative high-resolution microscopy revealed that ESCs contain significantly more euchromatin than HSCs, with a further reduction in mature cells. Increasedmore » cellular maturation also led to heterochromatin localization to the nuclear periphery. Functionally, prevention of heterochromatin formation by inhibition of the histone methyltransferase G9A resulted in delayed HSC differentiation. Lastly, our results demonstrate global chromatin rearrangements during stem cell differentiation and that heterochromatin formation by H3K9 methylation regulates HSC differentiation.« less

Progressive Chromatin Condensation and H3K9 Methylation Regulate the Differentiation of Embryonic and Hematopoietic Stem Cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ugarte, Fernando; Sousae, Rebekah; Cinquin, Bertrand

Epigenetic regulation serves as the basis for stem cell differentiation into distinct cell types, but it is unclear how global epigenetic changes are regulated during this process. Here, we tested the hypothesis that global chromatin organization affects the lineage potential of stem cells and that manipulation of chromatin dynamics influences stem cell function. Using nuclease sensitivity assays, we found a progressive decrease in chromatin digestion among pluripotent embryonic stem cells (ESCs), multipotent hematopoietic stem cells (HSCs), and mature hematopoietic cells. Quantitative high-resolution microscopy revealed that ESCs contain significantly more euchromatin than HSCs, with a further reduction in mature cells. Increasedmore » cellular maturation also led to heterochromatin localization to the nuclear periphery. Functionally, prevention of heterochromatin formation by inhibition of the histone methyltransferase G9A resulted in delayed HSC differentiation. Lastly, our results demonstrate global chromatin rearrangements during stem cell differentiation and that heterochromatin formation by H3K9 methylation regulates HSC differentiation.« less

Thermal history and differential exhumation across the Eastern Musgrave Province, South Australia: Insights from low-temperature thermochronology

NASA Astrophysics Data System (ADS)

Glorie, Stijn; Agostino, Kate; Dutch, Rian; Pawley, Mark; Hall, James; Danišík, Martin; Evans, Noreen J.; Collins, Alan S.

2017-04-01

Multi-method geo- and thermochronological data obtained for Palaeo- and Mesoproterozoic granitoids traversing the main structural architecture of the eastern Musgrave Province within South Australia reveal multiphase cooling histories. Apatite U-Pb dating on six samples yield consistent ages of 1075-1025 Ma, suggesting a thermal reset coinciding with mantle-derived magmatism of the greater Warakurna Large Igneous Province ( 1080-1040 Ma). Apatite fission track (AFT) analysis indicate that four discrete thermal events affected the study area, inducing cooling through the AFT partial annealing zone ( 60-120 °C), supported by apatite and zircon (U-Th-Sm)/He data. Late Neoproterozoic cooling from deep crustal levels to temperatures < 200 °C was discerned, which is thought to be related to exhumation and denudation during the Petermann Orogeny. Subsequent cooling events at 450-400 Ma (Silurian-Devonian) and 310-290 Ma (Late Carboniferous) are interpreted to represent exhumation associated with the Alice Springs Orogeny. The latter event exhumed the sampled plutons to shallow crustal depths. An additional Triassic - early Jurassic thermal event, likely recording elevated geothermal gradients at that time, was observed throughout the study area, however, more data is needed to further support this interpretation. The high sample density across the structural architecture of the study area furthermore reveals patterns of fault reactivation and resulting differential exhumation, indicating shallower exhumation levels in the centre and deeper exhumation towards the margins of the sampled transect. The observed differential exhumation patterns match with existing seismic data and fit a model of an inverted graben system for the Phanerozoic evolution of the eastern Musgraves. The results highlight a complex Phanerozoic thermal history for the eastern Musgraves and help to elucidate the poorly appreciated tectonic evolution of inland Australia. This study further demonstrates

Interplay between Seismic Fracturing and Aseismic Creep in the Woodroffe Thrust, Central Australia - Inferences for the Rheology of Relatively "Dry" Middle Continental Crust

NASA Astrophysics Data System (ADS)

Wex, S.; Mancktelow, N. S.; Hawemann, F.; Pennacchioni, G.; Camacho, A.

2016-12-01

The over 600 km long mid-crustal Woodroffe Thrust developed during the intraplate Petermann Orogeny around 550 Ma. Ductile shearing was accommodated along a shallowly south-dipping plane with a top-to-north shear sense. Due to late-stage open folding of the thrust plane, a nearly continuous N-S profile of 60 km length in the direction of thrusting is now exposed. Metamorphic conditions of 500 °C - 600 °C at roughly 0.8 GPa and the rare availability of aqueous fluids are well constrained along the entire transect, providing an ideal framework for studying variation in microstructure and texture in the dominantly "dry" felsic middle continental crust. During the ductile thrusting quartz dynamically recrystallized by subgrain rotation and grain boundary migration, whereas plagioclase and K-feldspar underwent fracturing and neocrystallization. Quartz crystallographic preferred orientation (CPO) shows progressive variation from dominant prism to mixed rhomb/basal slip, while plagioclase and K-feldspar CPO is random. Flow stresses, estimated from quartz grain size piezometry, decrease towards higher metamorphic grade and deeper structural levels, yielding a strain rate that is up to two orders of magnitude faster than the geological average of 10-13 - 10-15 s-1. On this basis, a qualitative rheological model is developed explaining the observed cyclic interplay between ductile shearing (mylonitization) and brittle fracturing (pseudotachylyte formation) in the relatively "dry" middle continental crust, where the syn-deformational influx of water has not been pervasive.

Late Cenozoic thrusting of major faults along the central segment of Longmen Shan, eastern Tibet: Evidence from low-temperature thermochronology

NASA Astrophysics Data System (ADS)

Tan, Xi-Bin; Xu, Xi-Wei; Lee, Yuan-Hsi; Lu, Ren-Qi; Liu, Yiduo; Xu, Chong; Li, Kang; Yu, Gui-Hua; Kang, Wen-Jun

2017-08-01

The Cenozoic orogenic process of the Longmen Shan (LMS) and the kinematics of major faults along the LMS are crucial for understanding the growth history and mechanism of the eastern Tibetan Plateau. Three major faults, from west to east, are present in the central segment of the LMS: the Wenchuan-Maoxian Fault (WMF), the Beichuan-Yingxiu Fault (BYF), and the Jiangyou-Guanxian Fault (JGF). Previous researchers have placed great impetus on the Pengguan Massif, between the WMF and BYF. However, limited low-temperature thermochronology data coverage in other areas prevents us from fully delineating the tectonic history of the LMS. In this study, we collect 22 samples from vertical profiles in the Xuelongbao Massif and the range frontal area located at the hanging walls of the WMF and JGF respectively, and conduct apatite and zircon fission track analyses. New fission track data reveal that the Xuelongbao Massif has been undergoing rapid exhumation with an average rate of 0.7-0.9 mm/yr since 11 Ma, and the range frontal area began rapid exhumation at 7.5 Ma with total exhumation of 2.5-4.5 km. The exhumation histories indicate that the three major faults (WMF, BYF and JGF) in the central LMS are all reverse faults, and show a basinward in-sequence propagation from middle Miocene to present-day. Such a pattern further implies that upper crustal shortening is the primary driver for the LMS' uplift during the Late Cenozoic. Nevertheless, middle-lower crustal deformation is difficult to be constrained by the exhumation histories, and its contribution to LMS' uplift cannot be ruled out.

Dual PI3K/mTOR inhibitors, GSK2126458 and PKI-587, suppress tumor progression and increase radiosensitivity in nasopharyngeal carcinoma.

PubMed

Liu, Tongxin; Sun, Quanquan; Li, Qi; Yang, Hua; Zhang, Yuqin; Wang, Rong; Lin, Xiaoshan; Xiao, Dong; Yuan, Yawei; Chen, Longhua; Wang, Wei

2015-02-01

Although combined chemoradiotherapy has provided considerable improvements for nasopharyngeal carcinoma (NPC), recurrence and metastasis are still frequent. The PI3K/Akt/mTOR pathway plays a critical role in tumor formation and tumor cell survival after radiation-induced DNA damage. In the present study, we evaluated whether inhibition of PI3K/mTOR by two novel dual inhibitors, GSK2126458 and PKI-587, could suppress tumor progression and sensitize NPC cells to radiation. Four NPC cell lines (CNE-1, CNE-2, 5-8F, and 6-10B) were used to analyze the effects of GSK216458 and PKI-587 on cell proliferation, migration, invasion, clonogenic survival, amount of residual γ-H2AX foci, cell cycle, and apoptosis after radiation. A 5-8F xenograft model was used to evaluate the in vivo effects of the two compounds in combination with ionizing radiation (IR). Both GSK216458 and PKI-587 effectively inhibited cell proliferation and motility in NPC cells and suppressed phosphorylation of Akt, mTOR, S6, and 4EBP1 proteins in a concentration- and time-dependent manner. Moreover, both compounds sensitized NPC cells to IR by increasing DNA damage, enhancing G2-M cell-cycle delay, and inducing apoptosis. In vivo, the combination of IR with GSK2126458 or PKI-587 significantly inhibited tumor growth. Antitumor effect was correlated with induction of apoptosis and suppression of the phosphorylation of mTOR, Akt, and 4EBP1. These new findings suggest the usefulness of PI3K/mTOR dual inhibition for antitumor and radiosensitizing. The combination of IR with a dual PI3K/mTOR inhibitor, GSK2126458 or PKI-587, might be a promising therapeutic strategy for NPC. ©2014 American Association for Cancer Research.

Thermal history from both sides of the South Atlantic passive margin - A comparison: Argentinean pampa vs. South African escarpement.

NASA Astrophysics Data System (ADS)

Kollenz, Sebastian; Glasmacher, Ulrich A.

2014-05-01

The eastern Argentina South Atlantic passive continental margin is distinguished by a very flat topography. Out of the so called Pampean flat two mountain ranges are arising. These mountain ranges, the Sierras Australes and the Sierras Septentrionales, are located in the State of Buenos Aires south of the capital Buenos Aires. In existing literature the Sierras Australes are correlated with the South African cape fold belt (Torsvik 2009; Lopez Gamundi & Rossello 1998). Existing thermochronological data shows different post-breakup cooling histories for both areas and different AFT-ages. Published thermochronological ages (e.g. Raab et al. 2002, 2005, Gallagher et al et al. 1998)from the south African escarpement vary around 150 and 100 Ma (Gallagher et al. 1998). Only some spots in the eastern part of South Africa towards the pacific margin show older ages of 250 Ma and older than 350 Ma (Gallagher et al. 1998). New thermochronological data (AHe, AFT and ZHe) from the Sierras Australes indicate a different cooling history by revealing a range of varying ages due to younger tectonic activity. By comparing the data sets from both areas it is getting clear that the post-rift evolution of both continents is differing very strong. Gallagher, K., Brown, R. and Johnson, C. 1998. Fission track analysis and its application to geological problems. Annual review of Earth and Planetary Science, 26, 519-572. Lopez Gamundi, O.R., Rossello, E.A. (1998): Basin fill evolution and paleotectonic patterns along the Samfrau geosyncline: the Sauce Grande basin-Ventana foldbelt (Argentina) and Karoo basin-Cape foldbelt (South Africa) revisited. Geol Rundsch 86 :819-834. Raab, M.J., Brown, R.W., Gallagher, K., Carter, A. and Webber, K. 2002. late Cretaceous reactivation of major crustal shear zones in northern Namibia: constraints from apatite fission track analysis. Tectonophysics. 349, 75-92. Raab, M.J., Brown, R.W., Gallagher, K., Webber, K. and Gleadow, A.J.W. 2005. denudational and

Weathering of the New Albany Shale, Kentucky, USA: I. Weathering zones defined by mineralogy and major-element composition

USGS Publications Warehouse

Tuttle, M.L.W.; Breit, G.N.

2009-01-01

Comprehensive understanding of chemical and mineralogical changes induced by weathering is valuable information when considering the supply of nutrients and toxic elements from rocks. Here minerals that release and fix major elements during progressive weathering of a bed of Devonian New Albany Shale in eastern Kentucky are documented. Samples were collected from unweathered core (parent shale) and across an outcrop excavated into a hillside 40 year prior to sampling. Quantitative X-ray diffraction mineralogical data record progressive shale alteration across the outcrop. Mineral compositional changes reflect subtle alteration processes such as incongruent dissolution and cation exchange. Altered primary minerals include K-feldspars, plagioclase, calcite, pyrite, and chlorite. Secondary minerals include jarosite, gypsum, goethite, amorphous Fe(III) oxides and Fe(II)-Al sulfate salt (efflorescence). The mineralogy in weathered shale defines four weathered intervals on the outcrop-Zones A-C and soil. Alteration of the weakly weathered shale (Zone A) is attributed to the 40-a exposure of the shale. In this zone, pyrite oxidization produces acid that dissolves calcite and attacks chlorite, forming gypsum, jarosite, and minor efflorescent salt. The pre-excavation, active weathering front (Zone B) is where complete pyrite oxidation and alteration of feldspar and organic matter result in increased permeability. Acidic weathering solutions seep through the permeable shale and evaporate on the surface forming abundant efflorescent salt, jarosite and minor goethite. Intensely weathered shale (Zone C) is depleted in feldspars, chlorite, gypsum, jarosite and efflorescent salts, but has retained much of its primary quartz, illite and illite-smectite. Goethite and amorphous FE(III) oxides increase due to hydrolysis of jarosite. Enhanced permeability in this zone is due to a 14% loss of the original mass in parent shale. Denudation rates suggest that characteristics of Zone C

Should vitamin K be supplemented instead of antagonised in patients with idiopathic pulmonary fibrosis?

PubMed

De Brouwer, Bart; Piscaer, Ianthe; Von Der Thusen, Jan H; Grutters, Jan C; Schutgens, Roger Eg; Wouters, Emiel Fm; Janssen, Rob

2018-03-01

There is an ongoing need for additional interventions in idiopathic pulmonary fibrosis (IPF) as antifibrotic drugs currently available only inhibit and do not stall disease progression. Vitamin K is a co-factor for the activation of coagulation factors. However, it is also required to activate proteins with functions outside of the coagulation cascade, such as matrix Gla protein (MGP), a defender against soft tissue calcification. Vitamin K antagonists are anticoagulants that are, for unknown reasons, associated with increased mortality in IPF. Areas covered: We advance the hypothesis that modulation of vitamin K-dependent MGP activation in IPF patients by either vitamin K antagonism or administration may result in acceleration and deceleration of fibrosis progression, respectively. Furthermore, shortfall in vitamin K could be suspected in IPF based on the high prevalence of certain co-morbidities, such as vascular calcification and lung cancer. Expert commentary: We hypothesize that vitamin K status is reduced in IPF patients. This, in combination with studies suggesting that vitamin K may play a role in lung fibrosis pathogenesis, would provide a rationale for conducting a clinical trial assessing the potential mitigating effects of vitamin K administration on progression of lung fibrosis, prevention of co-morbidities and mortality in IPF.

Computational algebraic geometry for statistical modeling FY09Q2 progress.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thompson, David C.; Rojas, Joseph Maurice; Pebay, Philippe Pierre

2009-03-01

This is a progress report on polynomial system solving for statistical modeling. This is a progress report on polynomial system solving for statistical modeling. This quarter we have developed our first model of shock response data and an algorithm for identifying the chamber cone containing a polynomial system in n variables with n+k terms within polynomial time - a significant improvement over previous algorithms, all having exponential worst-case complexity. We have implemented and verified the chamber cone algorithm for n+3 and are working to extend the implementation to handle arbitrary k. Later sections of this report explain chamber cones inmore » more detail; the next section provides an overview of the project and how the current progress fits into it.« less

Magma-assisted strain localization in an orogen-parallel transcurrent shear zone of southern Brazil

NASA Astrophysics Data System (ADS)

Tommasi, AndréA.; Vauchez, Alain; Femandes, Luis A. D.; Porcher, Carla C.

1994-04-01

In a lithospheric-scale, orogen-parallel transcurrent shear zone of the Pan-African Dom Feliciano belt of southern Brazil, two successive generations of magmas, an early calc-alkaline and a late peraluminous, have been emplaced during deformation. Microstructures show that these granitoids experienced a progressive deformation from magmatic to solid state under decreasing temperature conditions. Magmatic deformation is indicated by the coexistence of aligned K-feldspar, plagioclase, micas, and/or tourmaline with undeformed quartz. Submagmatic deformation is characterized by strain features, such as fractures, lattice bending, or replacement reactions affecting only the early crystallized phases. High-temperature solid-state deformation is characterized by extensive grain boundary migration in quartz, myrmekitic K-feldspar replacement, and dynamic recrystallization of both K-feldspar and plagioclase. Decreasing temperature during solid-state deformation is inferred from changes in quartz crystallographic fabrics, decrease in grain size of recrystallized feldspars, and lower Ti amount in recrystallized biotites. Final low-temperature deformation is characterized by feldspar replacement by micas. The geochemical evolution of the synkinematic magmatism, from calc-alkaline metaluminous granodiorites with intermediate 87Sr/86Sr initial ratio to peraluminous granites with very high 87Sr/86Sr initial ratio, suggests an early lower crustal source or a mixed mantle/crustal source, followed by a middle to upper crustal source for the melts. Shearing in lithospheric faults may induce partial melting in the lower crust by shear heating in the upper mantle, but, whatever the process initiating partial melting, lithospheric transcurrent shear zones may collect melt at different depths. Because they enhance the vertical permeability of the crust, these zones may then act as heat conductors (by advection), promoting an upward propagation of partial melting in the crust

How to build a mid-crustal intrusive suite: geologic mapping, U-Pb geo-/thermochronology, and thermal modeling of the Bergell Intrusion, Central Alps

NASA Astrophysics Data System (ADS)

Samperton, K. M.; Schoene, B.; Annen, C.

2015-12-01

Insights into the characteristic rates and processes of crustal magmatic systems can best be made through the integration of observational, analytical and modeling perspectives. We present such an approach in reconstructing the emplacement, differentiation and cooling history of the Bergell Intrusion (N Italy/SE Switzerland), a normally-zoned pluton preserving a ~10 km mid-crustal transect. U-Pb zircon, titanite and allanite geo-/thermochronology of Bergell granitoids provide key empirical constraints for informing numerical simulations of pulse-wise, incremental assembly. Protracted zircon crystallization histories, representing the time between magma zircon saturation and cooling to the solidus, provide a direct petrologic link to forward models of magma emplacement, both of which can be used to derive quantitative magmatic cooling rates for the middle crust. Titanite and allanite dates provide additional constraints on the timing of solidification. Geochronology and modeling are performed in the context of detailed field and structural observations, including those previously interpreted as evidence of upward, pluton-scale melt migration via floor convergence/roof ballooning. Combined Bergell data and modeling demonstrate that pulsed assembly can lead to the formation of substantial melt reservoirs in the middle crust: this finding is largely in contrast to similar models of shallow crustal plutons, highlighting the importance of factors such as ambient country rock temperature in affecting melt residence timescales. This work emphasizes the importance of implementing joint data/modeling studies to intrusive rocks across the full range of spatial scales, emplacement levels and tectonic settings observed on Earth.

Gain-of-function mutant p53 but not p53 deletion promotes head and neck cancer progression in response to oncogenic K-ras

PubMed Central

Acin, Sergio; Li, Zhongyou; Mejia, Olga; Roop, Dennis R; El-Naggar, Adel K; Caulin, Carlos

2015-01-01

Mutations in p53 occur in over 50% of the human head and neck squamous cell carcinomas (SCCHN). The majority of these mutations result in the expression of mutant forms of p53, rather than deletions in the p53 gene. Some p53 mutants are associated with poor prognosis in SCCHN patients. However, the molecular mechanisms that determine the poor outcome of cancers carrying p53 mutations are unknown. Here, we generated a mouse model for SCCHN and found that activation of the endogenous p53 gain-of-function mutation p53R172H, but not deletion of p53, cooperates with oncogenic K-ras during SCCHN initiation, accelerates oral tumour growth, and promotes progression to carcinoma. Mechanistically, expression profiling of the tumours that developed in these mice and studies using cell lines derived from these tumours determined that mutant p53 induces the expression of genes involved in mitosis, including cyclin B1 and cyclin A, and accelerates entry in mitosis. Additionally, we discovered that this oncogenic function of mutant p53 was dependent on K-ras because the expression of cyclin B1 and cyclin A decreased, and entry in mitosis was delayed, after suppressing K-ras expression in oral tumour cells that express p53R172H. The presence of double-strand breaks in the tumours suggests that oncogene-dependent DNA damage resulting from K-ras activation promotes the oncogenic function of mutant p53. Accordingly, DNA damage induced by doxorubicin also induced increased expression of cyclin B1 and cyclin A in cells that express p53R172H. These findings represent strong in vivo evidence for an oncogenic function of endogenous p53 gain-of-function mutations in SCCHN and provide a mechanistic explanation for the genetic interaction between oncogenic K-ras and mutant p53. PMID:21952947

6 Ma age of carving Westernmost Grand Canyon: Reconciling geologic data with combined AFT, (U-Th)/He, and 4He/3He thermochronologic data

NASA Astrophysics Data System (ADS)

Winn, Carmen; Karlstrom, Karl E.; Shuster, David L.; Kelley, Shari; Fox, Matthew

2017-09-01

Conflicting hypotheses about the timing of carving of the Grand Canyon involve either a 70 Ma (;old;) or <6 Ma (;young;) Grand Canyon. This paper evaluates the controversial westernmost segment of the Grand Canyon where the following lines of published evidence firmly favor a ;young; Canyon. 1) North-derived Paleocene Hindu Fanglomerate was deposited across the present track of the westernmost Grand Canyon, which therefore was not present at ∼55 Ma. 2) The 19 Ma Separation Point basalt is stranded between high relief side canyons feeding the main stem of the Colorado River and was emplaced before these tributaries and the main canyon were incised. 3) Geomorphic constraints indicate that relief generation in tributaries and on plateaus adjacent to the westernmost Grand Canyon took place after 17 Ma. 4) The late Miocene-Pliocene Muddy Creek Formation constraint shows that no river carrying far-traveled materials exited at the mouth of the Grand Canyon until after 6 Ma. Interpretations of previously-published low-temperature thermochronologic data conflict with these lines of evidence, but are reconciled in this paper via the integration of three methods of analyses on the same sample: apatite (U-Th)/He ages (AHe), 4He/3He thermochronometry (4He/3He), and apatite fission-track ages and lengths (AFT). HeFTy software was used to generate time-temperature (t-T) paths that predict all new and published 4He/3He, AHe, and AFT data to within assumed uncertainties. These t-T paths show cooling from ∼100 °C to 40-60 °C in the Laramide (70-50 Ma), long-term residence at 40-60 °C in the mid-Tertiary (50-10 Ma), and cooling to near-surface temperatures after 10 Ma, and thus support young incision of the westernmost Grand Canyon. A subset of AHe data, when interpreted alone (i.e. without 4He/3He or AFT data), are better predicted by t-T paths that cool to surface temperatures during the Laramide, consistent with an ;old; Grand Canyon. However, the combined AFT, AHe, and 4He

Identification of cancer initiating cells in K-Ras driven lung adenocarcinoma.

PubMed

Mainardi, Sara; Mijimolle, Nieves; Francoz, Sarah; Vicente-Dueñas, Carolina; Sánchez-García, Isidro; Barbacid, Mariano

2014-01-07

Ubiquitous expression of a resident K-Ras(G12V) oncogene in adult mice revealed that most tissues are resistant to K-Ras oncogenic signals. Indeed, K-Ras(G12V) expression only induced overt tumors in lungs. To identify these transformation-permissive cells, we induced K-Ras(G12V) expression in a very limited number of adult lung cells (0.2%) and monitored their fate by X-Gal staining, a surrogate marker coexpressed with the K-Ras(G12V) oncoprotein. Four weeks later, 30% of these cells had proliferated to form small clusters. However, only SPC(+) alveolar type II (ATII) cells were able to form hyperplastic lesions, some of which progressed to adenomas and adenocarcinomas. In contrast, induction of K-Ras(G12V) expression in lung cells by intratracheal infection with adenoviral-Cre particles generated hyperplasias in all regions except the proximal airways. Bronchiolar and bronchioalveolar duct junction hyperplasias were primarily made of CC10(+) Clara cells. Some of them progressed to form benign adenomas. However, only alveolar hyperplasias, exclusively made up of SPC(+) ATII cells, progressed to yield malignant adenocarcinomas. Adenoviral infection induced inflammatory infiltrates primarily made of T and B cells. This inflammatory response was essential for the development of K-Ras(G12V)-driven bronchiolar hyperplasias and adenomas, but not for the generation of SPC(+) ATII lesions. Finally, activation of K-Ras(G12V) during embryonic development under the control of a Sca1 promoter yielded CC10(+), but not SPC(+), hyperplasias, and adenomas. These results, taken together, illustrate that different types of lung cells can generate benign lesions in response to K-Ras oncogenic signals. However, in adult mice, only SPC(+) ATII cells were able to yield malignant adenocarcinomas.

Instability of the southern Canadian Shield during the late Proterozoic

NASA Astrophysics Data System (ADS)

McDannell, Kalin T.; Zeitler, Peter K.; Schneider, David A.

2018-05-01

Cratons are generally considered to comprise lithosphere that has remained tectonically quiescent for billions of years. Direct evidence for stability is mainly founded in the Phanerozoic sedimentary record and low-temperature thermochronology, but for extensive parts of Canada, earlier stability has been inferred due to the lack of an extensive rock record in both time and space. We used 40Ar/39Ar multi-diffusion domain (MDD) analysis of K-feldspar to constrain cratonic thermal histories across an intermediate (∼150-350 °C) temperature range in an attempt to link published high-temperature geochronology that resolves the timing of orogenesis and metamorphism with lower-temperature data suited for upper-crustal burial and unroofing histories. This work is focused on understanding the transition from Archean-Paleoproterozoic crustal growth to later intervals of stability, and how uninterrupted that record is throughout Earth's Proterozoic "Middle Age." Intermediate-temperature thermal histories of cratonic rocks at well-constrained localities within the southern Canadian Shield of North America challenge the stability worldview because our data indicate that these rocks were at elevated temperatures in the Proterozoic. Feldspars from granitic rocks collected at the surface cooled at rates of <0.5 °C/Ma subsequent to orogenesis, seemingly characteristic of cratonic lithosphere, but modeled thermal histories suggest that at ca. 1.1-1.0 Ga these rocks were still near ∼200 °C - signaling either reheating, or prolonged residence at mid-crustal depths assuming a normal cratonic geothermal gradient. After 1.0 Ga, the regions we sampled then underwent further cooling such that they were at or near the surface (≪60 °C) in the early Paleozoic. Explaining mid-crustal residence at 1.0 Ga is challenging. A widespread, prolonged reheating history via burial is not supported by stratigraphic information, however assuming a purely monotonic cooling history requires at the

Relation between the axial length and lenticular progressive myopia.

PubMed

Lin, H-Y; Chang, C-W; Wang, H-Z; Tsai, R-K

2005-08-01

To investigate the possible risk factors associated with lenticular progressive myopia and to compare the differences between patients with lenticular progressive myopias and senile cataracts. We retrospectively reviewed cases that had been diagnosed as lenticular progressive myopia with a discrete nuclear sclerotic cataract and progressive myopic changes in one hospital from January 1998 to February 2003. A total of 47 eyes of 35 patients were enrolled in this study. In all, 32 eyes of 29 cases of common senile cataract receiving cataract extraction surgery during the study period were randomly chosen (every four cases in time sequence within a 2-month period by two ophthalmologists' clinic in 2002) as the control group. We compared the preoperative refraction status, keratometry (K-values) and axial lengths between these two groups. The possible ocular or systemic associating diseases were also investigated in the study group. In the lenticular progressive myopia group, the mean age at surgery (52.9+/-9.2 years) is younger than that in the senile cataract group (68.1+/-7.3 years). The mean axial length in the study group (25.68+/-1.93 mm) is statistically significant longer than that in the control group (22.97+/-0.83 mm) (P<0.0001). Besides, patients with lenticular progressive myopia had significantly lower mean K-values (43.25+/-1.42 diopters) than patients with senile cataracts (44.25+/-1.28 diopters) (P<0.01). There were no other ocular or systemic diseases closely associated with lenticular progressive myopia. Patients with nuclear cataract combined with lenticular progressive myopia have longer axial length than patients with senile cataract. The longer axial length may be one of the important risk factors predisposing to lenticular progressive myopia.

Effect of infiltrated water on rheology of plagioclase feldspar under lower crustal condition

NASA Astrophysics Data System (ADS)

Kido, M.; Muto, J.; Koizumi, S.; Nagahama, H.

2016-12-01

Fluids in the deep crust have an important role in deformation of lithosphere and seismicity. In this study, we performed deformation experiments to reveal rheological properties of plagioclase feldspars as a main constituent of crustal materials with infilitrated water. Axial compression tests on synthetic polycrystalline anorthite (An) were performed in a Griggs-type deformation apparatus at temparature of 900 °C, strain rates of roughly about 10-5 s-1 and various confining pressures of 0.8-1.4 GPa. Distilled water was added on samples before tests. Times for infiltration of water into samples were changed to investigate the variation of strength associated with diffusion of water. Strengths of wet An tended to decrease with infiltration time or strain magnitude. If other conditions such as temperature, time and strain being the same, strengths increase with confining pressures. Recovered samples show that deformation was concentrated in the lower part of samples. Differential stresses were significantly lower than predicted values by a previous flow law for wet An obtained by low pressure gas apparatus ( 0.4 GPa, Rybacki et al., 2006). This implies that the effect of water on mechanical behavior in higher pressure might be larger than those predicted by lower pressure experiments. Ideal water concentration and strength profile of internal of samples were estimated by one-dimensional model of grain boundary diffusion. Estimated strength of internal part of samples was significant higher than measured stresses. There is possibility that cataclastic flow partially occurred in samples. In addition, deformation-enhanced fluid flow probably occurred. In conclusion, strength of wet An depends on water infiltration time, strain magnitude and confining pressure. The results suggest that the strength of fluid-rich regions in the lower crust becomes lower than that predicted by previous studies.

Field Exploration and Life Detection Sampling for Planetary Analogue Research (FELDSPAR)

NASA Astrophysics Data System (ADS)

Gentry, D.; Stockton, A. M.; Amador, E. S.; Cable, M. L.; Cantrell, T.; Chaudry, N.; Cullen, T.; Duca, Z. A.; Jacobsen, M. B.; Kirby, J.; McCaig, H. C.; Murukesan, G.; Rennie, V.; Rader, E.; Schwieterman, E. W.; Stevens, A. H.; Sutton, S. A.; Tan, G.; Yin, C.; Cullen, D.; Geppert, W.

2017-12-01

Extraterrestrial studies are typically conducted on mg samples from cm-scale features, while landing sites are selected based on m to km-scale features. It is therefore critical to understand spatial distribution of organic molecules over scales from cm to the km, particularly in geological features that appear homogenous at m to km scales. This is addressed by FELDSPAR, a NASA-funded project that conducts field operations analogous to Mars sample return in its science, operations, and technology [1]. Here, we present recent findings from a 2016 and a 2017 campaign to multiple Martian analogue sites in Iceland. Icelandic volcanic regions are Mars analogues due to desiccation, low nutrient availability, temperature extremes [2], and are relatively young and isolated from anthropogenic contamination [3]. Operationally, many Icelandic analogue sites are remote enough to require that field expeditions address several sampling constraints that are also faced by robotic exploration [1, 2]. Four field sites were evaluated in this study. The Fimmvörðuháls lava field was formed by a basaltic effusive eruption associated with the 2010 Eyjafjallajökull eruption. Mælifellssandur is a recently deglaciated plain to the north of the Myrdalsjökull glacier. Holuhraun is a basaltic spatter and cinder cone formed by 2014 fissure eruptions just north of the Vatnajökull glacier. Dyngjusandur is a plain kept barren by repeated aeolian mechanical weathering. Samples were collected in nested triangular grids from 10 cm to the 1 km scale. We obtained overhead imagery at 1 m to 200 m elevation to create digital elevation models. In-field reflectance spectroscopy was obtained with an ASD spectrometer and chemical composition was measured by a Bruker handheld XRF. All sites chosen were homogeneous in apparent color, morphology, moisture, grain size, and reflectance spectra at all scales greater than 10 cm. Field lab ATP assays were conducted to monitor microbial habitation, and home

Formation of albitite-hosted uranium within IOCG systems: the Southern Breccia, Great Bear magmatic zone, Northwest Territories, Canada

NASA Astrophysics Data System (ADS)

Montreuil, Jean-François; Corriveau, Louise; Potter, Eric G.

2015-03-01

Uranium and polymetallic U mineralization hosted within brecciated albitites occurs one kilometer south of the magnetite-rich Au-Co-Bi-Cu NICO deposit in the southern Great Bear magmatic zone (GBMZ), Canada. Concentrations up to 1 wt% U are distributed throughout a 3 by 0.5 km albitization corridor defined as the Southern Breccia zone. Two distinct U mineralization events are observed. Primary uraninite precipitated with or without pyrite-chalcopyrite ± molybdenite within magnetite-ilmenite-biotite-K-feldspar-altered breccias during high-temperature potassic-iron alteration. Subsequently, pitchblende precipitated in earthy hematite-specular hematite-chlorite veins associated with a low-temperature iron-magnesium alteration. The uraninite-bearing mineralization postdates sodic (albite) and more localized high-temperature potassic-iron (biotite-magnetite ± K-feldspar) alteration yet predates potassic (K-feldspar), boron (tourmaline) and potassic-iron-magnesium (hematite ± K-feldspar ± chlorite) alteration. The Southern Breccia zone shares attributes of the Valhalla (Australia) and Lagoa Real (Brazil) albitite-hosted U deposits but contains greater iron oxide contents and lower contents of riebeckite and carbonates. Potassium, Ni, and Th are also enriched whereas Zr and Sr are depleted with respect to the aforementioned albitite-hosted U deposits. Field relationships, geochemical signatures and available U-Pb dates on pre-, syn- and post-mineralization intrusions place the development of the Southern Breccia and the NICO deposit as part of a single iron oxide alkali-altered (IOAA) system. In addition, this case example illustrates that albitite-hosted U deposits can form in albitization zones that predate base and precious metal ore zones in a single IOAA system and become traps for U and multiple metals once the tectonic regime favors fluid mixing and oxidation-reduction reactions.

Harnessing Technology to Improve K-12 Education. Discussion Paper 2012-05

ERIC Educational Resources Information Center

Chatterji, Aaron; Jones, Benjamin

2012-01-01

Technological progress has consistently driven remarkable advances in the U.S. economy, yet K-12 education sees little technological change compared to other sectors, even as U.S. K-12 students increasingly lag behind students in other nations. This proposal considers how we can take a signature American strength--innovation--and apply it to K-12…

Pyritized mudstone and associated facies in the Permian-Triassic boundary of the Çürük Daǧ section, Southern Turkey

NASA Astrophysics Data System (ADS)

Varol, Baki; Koşun, Erdal; Ünal Pinar, Neslihan; Ayranci, Korhan

2011-03-01

This paper is the first study of pyritized mudstones (PM) in the Permian-Triassic (P-T) boundary section of the Çürük Dağ (Taurus, Antalya Nappes, Turkey). The mudstones were generally formed as lensoidal-shaped layers or infill materials within nodular platform limestones (hardground). Normal marine fauna is diminished in the pyritized limestones, whereas tube-like microorganisms are apparently increased with the association of pyrite crystals consisting of both framboidal and cubic crystals. The total rock volumes are up to 50-60% clay minerals and are mainly made up of in situ kaolinite and subordinate mixed layer clays (illite-vermiculite). Kaolinite preferentially developed on feldspar crystals, sometimes covering ostracoda bivalves together with gypsum micronodules composed of fan-shaped gypsum crystals. The origin of the kaolinite is, in situ, directly related to feldspar dissolution via heterotrophic bacteria. Thus, kaolinite is found along with bacterial structures. Other mineralogical compositions include established quartz (mostly β-quartz), gypsum crystals (100-200 μm) glauconite and magnetite. Magnetite grains comprise a minor amount (1-2%) and show some bacterial-induced crystal orientations. Glauconite is formed as an accessory mineral that occurs as infill material in biogenic grains. On the other hand, some microspheres represented by a silica-dominated composition are only observed in scanning electron microscopes (SEM) studies under high magnification. Isotope values (d34S) obtained from the pyritized mudstones show an isotopic heterogeneity that suggests that the pyritized mudstone consists of at least two components, with different sulphur-concentrations and d34S values.

Sulfur mustard disrupts human α3β1-integrin receptors in concert with α6β4-integrin receptors and collapse of the keratin K5/K14 cytoskeleton

NASA Astrophysics Data System (ADS)

Werrlein, Robert J.; Braue, Catherine R.

2004-06-01

Sulfur mustard (SM; bis(2-chloroethyl) sulfide) is a chemical warfare agent that produces persistent, incapacitating blisters of the skin. The lesions inducing vesication remain elusive, and there is no completely effective treatment. Using mulitphoton microscopy and immunofluorescent staining, we found that exposing human epidermal keratinocytes (HEK) and intact epidermis to SM (400 μm for 5 min) caused progressive collapse of the keratin (K5/K14) cytoskeleton and depletion of α6β integrins. We now report that SM causes concomitant disruption nad collapse of the basal cell's α3β1-integrin receptors. At 1 h postexposure, images of Alexa488-conjugated HEK/α3β1 integrins showed almost complete withdrawal and disappearance of retraction fibers and a progressive loss of polarized mobility. With stero imaging, in vitro expression of this SM effect was characterized by collapse and abutment of adjacent cell membranes. At 2 h postexposure, there was an average 13% dorso-ventral collapse of HEK membranes that paralleled progressive collapse of the K5/K14 cytoskeleton. α3β1 integrin, like α6β4 integrin, is a regulator of cytoskeletal assembly, a receptor for laminin 5 and a mediator of HEK attachment to the basement membrane. Our images indicate that SM disrupts these receptors. We suggest that the progressive disruption destabilizes and potentiates blistering of the epidermal-dermal junction.

Shocked Quartz Aggregates of the Cretaceous-Tertiary Boundary at Colorado, USA

NASA Astrophysics Data System (ADS)

Miura, Y.; Okamoto, M.; Iancu, O. G.

1993-07-01

Shock-metamorphosed quartz (i.e., shocked quartz) at the Cretaceous-Tertiary boundary (K/T) at Colorado [1,2] reveals the following mineralogical data by X-ray diffractometry and high-resolution electron micrograph with energy- dispersive spectrometry. 1. Shocked quartz is not normal (perfect crystalline) quartz mineral but various quartz aggregates that show relatively low X-ray intensity (i.e., imperfect crystalline) and shock lamellae with crystalline quartz and amorphous glass [3]. 2. Analytical electron micrographs indicate that crystalline quartz silica with spotty dislocation features is included in dendritic amorphous glasses of potassium (K) feldspar composition. Various compositions of glassy materials are found in shocked quartz aggregates as matrix or alternate shock lamellae, which is important to estimate the target rock of impact. The composition of glassy matrix is dendritic K-feldspar in the K/T boundary at Clear Creak North (CCN), Colorado, whereas that in the Barringer Crater is quartz-rich composition from the target rock of sandstone (or some mixture with iron meteorite), and that in artificial impact rock [3] is dendritic silica composition. It is found in this study that shocked quartz aggregates from the CCN K/T boundary samples are supplied from quartz and K-feldspar-bearing target rock at impact event (Table 1). Table 1, which appears here in the hard copy, shows the compositions, texture, and origin of shocked quartz aggregates. References: [1] Alvarez L. W. et al. (1980) Science, 208, 1095-1107. [2] Izett G. (1989) GSA Spec. Pap. 249, 1-194. [3] Miura Y. (1991) Shock Waves, 1, 35-41, Springer-Verlag.

Differential unroofing within the central metasedimentary Belt of the Grenville Orogen: constraints from 40Ar/39Ar thermochronology

USGS Publications Warehouse

Cosca, M.A.; Essene, E.J.; Kunk, Michael J.; Sutter, J.F.

1992-01-01

An 40Ar/39Ar thermochronological investigation of upper greenschist to granulite facies gneiss, amphibolite and marble was conducted in the Central Metasedimentary Belt (CMB), Ontario, to constrain its cooling history. Incremental 40Ar/39Ar release spectra indicate that substantial differential unroofing occurred in the CMB between ??? 1000 and ??? 600 Ma. A consistent pattern of significantly older hornblende and phlogopite 40Ar/3Ar cooling ages on the southeast sides of major northeast striking shear zones is interpreted to reflect late displacement due to extensional deformation. Variations in hornblende 40Ar/39Ar age plateaus exceeding 200 Ma occur over distances less than 50 km with major age discontinuities occurring across the Robertson Lake shear zone and the Sharbot Lake mylonite zone which separate the Sharbot Lake terrane from the Elzevir and Frontenac terranes. Extensional displacements of up to 14 km are inferred between the Frontenac and Elzevir terranes of the CMB. No evidence for significant post argon-closure vertical displacement is indicated in the vicinity of the Perth Road mylonite within the Frontenac terrane. Variations of nearly 100 Ma in phlogopite 40Ar/39Ar plateau ages occur in undeformed marble on either side of the Bancroft Shear Zone. Phlogopites from sheared and mylonitized marble within the shear zone yield 40Ar/39Ar diffusional loss profiles, but have older geologically meaningless ages thought to reflect incorporation of excess argon. By ??? 900 Ma, southeast directed extension was occurring throughout the CMB, possibly initiated along previous zones of compressional shearing. An easterly migration of active zones of extension is inferred, possibly related to an earlier, overall easterly migration of active zones of regional thrusting and easterly migration of an ancient subduction zone. The duration of extensional shearing is not well constrained, but must have ceased before ??? 600 Ma as required by the deposition of overlying

Timing of Exhumation of the Mesozoic Blue Nile Rift, Ethiopia: A New Study from Apatite Fission Track Thermochronology

NASA Astrophysics Data System (ADS)

Gani, N. D.; Bowden, S. M.

2017-12-01

At present, tectonic features of Ethiopia are dominated by the 2.5 km high Ethiopian Plateau, and the NE-SW striking continental rift, the East African Rift System (EARS) that dissected the plateau into the northwest and southeast plateaus. The stress direction of the EARS is nearly perpendicular to the stress direction of the Mesozoic rifts of the Central African Rift System (CARS), located mostly in Sudan, Ethiopia and Kenya. During the Gondwana splitting in Mesozoic, active lithospheric extension within the CARS resulted in several NW-SE striking continental rifts including the Blue Nile, Muglad, Melut and Anza that are well documented in Sudan and Kenya, from a combination of geophysical and drill core analysis and field investigations. However, the timing and evolution of the poorly documented Blue Nile Rift in Ethiopia, now hidden in the subsurface of the Ethiopian Plateau and the EARS, is largely unknown. This study investigates, for the first time, the timing of tectono-thermal evolution of the Blue Nile Rift from cooling ages deduced from apatite fission track (AFT) thermochronology to understand the rift flank exhumation. Here, we report the AFT results from basement samples collected in a vertical transect from the Ethiopian Plateau. The fission track ages of the samples show a general trend of increasing cooling ages with elevations. The time-temperature simulations of the fission track ages illustrate that the cooling started at least 80 Ma ago with a significant amount of rapid cooling between 80 and 70 Ma, followed by a slow cooling after 70 Ma and then another accelerated cooling starting around 10 Ma. The Cretaceous rapid cooling event likely related to the flank uplift of the Blue Nile Rift and associated faulting, during which much of the exhumation occurred. Today, the Blue Nile Rift is buried under the thick cover of Mesozoic sedimentary rocks and Cenozoic volcanics. The late Neogene rapid cooling agrees well with our previous thermal model

Detrital thermochronology of Rhine, Elbe and Meuse river sediment (Central Europe): implications for provenance, erosion and mineral fertility

NASA Astrophysics Data System (ADS)

Glotzbach, C.; Busschers, F. S.; Winsemann, J.

2018-03-01

Here we present detrital apatite fission track (AFT), zircon fission track (ZFT) and a few apatite (U-Th)/He (AHe) data of Middle Pleistocene to modern Rhine, Meuse and Elbe river sediments in order to resolve processes that control detrital age distributions (provenance, erosion and mineral fertility). We used a modelling approach to compare observed with theoretically predicted age distributions from an interpolated in situ AFT and ZFT age map. In situ cooling ages do show large differences in the Rhine drainage basin, facilitating the differentiation between different source regions. Inconsistencies between observed and theoretical age distributions of the Meuse and Elbe samples can be explained by mixing and reworking of sediments with different provenances (Meuse Middle Pleistocene terrace sediment) and a yet unexplored source region with old AFT ages (Elbe samples). Overall, the results show that detrital thermochronology is capable of identifying the provenance of Middle Pleistocene to modern sediments. The AFT age distributions of Rhine sediments are dominated ( 70%) by AFT ages representing the Alps. A possible explanation is higher erosion rates in the Alps as compared to areas outside the Alps. A Late Pleistocene sample from the Upper Rhine Graben contains apatite grains from the Molasse and Hegau volcanics, which we explain with a shift of the headwaters of the Rhine to the north as a result of intense Middle Pleistocene Riss glaciation. Contrary to the observed dominance of Alpine-derived AFT ages in Rhine sediments, the relative contribution of zircon ages with sources in the Alps is lower and significantly decreases downstream, suggesting a major source of zircons outside the Alps. This can be explained by increased zircon fertility of sediments derived from the Rhenish massif. Therefore, we conclude that erosion and mineral fertility are the main processes controlling detrital AFT and ZFT age distributions of the sampled river sediment. In case of

Thermochronology of mineral grains in the Red and Mekong Rivers, Vietnam: Provenance and exhumation implications for Southeast Asia

NASA Astrophysics Data System (ADS)

Clift, Peter D.; Carter, Andrew; Campbell, Ian H.; Pringle, Malcolm S.; van Lap, Nguyen; Allen, Charlotte M.; Hodges, Kip V.; Tan, Mai Thanh

2006-10-01

Sand samples from the mouths of the Red and Mekong Rivers were analyzed to determine the provenance and exhumation history of their source regions. U-Pb dating of detrital zircon grains shows that the main sources comprise crust formed within the Yangtze Craton and during the Triassic Indosinian Orogeny. Indosinian grains in the Mekong are younger (210-240 Ma) than those in the Red River (230-290 Ma), suggesting preferential erosion of the Qiangtang Block of Tibet into the Mekong. The Red River has a higher proportion of 700-800 Ma grains originally derived from the Yangtze Craton. 40Ar/39Ar dating of muscovite grains demonstrates that rocks cooled during the Indosinian Orogeny are dominant in both rivers, although the Mekong also shows a grain population cooling at 150-200 Ma that is not seen in the Red River and which is probably of original Qiangtang Block origin. Conversely, the Red River contains a significant mica population (350-500 Ma) eroded from the Yangtze Craton. High-grade metamorphic rocks exposed in the Cenozoic shear zones of southeast Tibet-Yunnan are minority sources to the rivers. However, apatite and zircon fission track ages show evidence for the dominant sources, especially in the Red River, only being exhumed through the shallowest 5-3 km of the crust since ˜25 Ma. The thermochronology data are consistent with erosion of recycled sediment from the inverted Simao and Chuxiong Basins, from gorges that incise the eastern flank of the plateau. Average Neogene exhumation rates are 104-191 m/Myr in the Red River basin, which is within error of the 178 ± 35 m/Myr estimated from Pleistocene sediment volumes. Sparse fission track data from the Mekong River support the Ar-Ar and U-Pb ages in favoring tectonically driven rock uplift and gorge incision as the dominant control on erosion, with precipitation being an important secondary influence.

Origin of hydrous alkali feldspar-silica intergrowth in spherulites from intra-plate A2-type rhyolites at the Jabal Shama, Saudi Arabia

NASA Astrophysics Data System (ADS)

Surour, Adel A.; El-Nisr, Said A.; Bakhsh, Rami A.

2016-03-01

Miocene rhyolites (19.2 ± 0.9 Ma) at the Jabal Shama in western Saudi Arabia represent an example of rift-related silicic volcanism that took place during the formation of the Red Sea. They mostly consist of tuffaceous varieties with distinct flow banding, and pea-sized spherulites, obsidian and perlitized rhyolite tuffs. Although they have the geochemical signature of A2-type rhyolites, these silicic rocks are not typically alkaline but alkali-calcic to calc-alkaline. They developed in a within-plate regime and possibly derived from a recycled mafic subducted slab in depleted sub-continental mantle beneath the western Arabian plate. The Jabal Shama rhyolites are younger in age than their Miocene counterparts in Yemen and Ethiopia. The Jabal Shama spherulites consist of hydrous alkali feldspar-silica radial intergrowths with an occasional brown glass nucleus. Carbonate- and glass-free spherulites give up to 4.45 wt% L.O.I. The hydrous nature of these silicates and the absence of magnetite in the spherulites is a strong indication of oxidizing conditions. The spherulites contain hydrous feldspars with up to ∼6 wt% H2O, and they develop by diffusion and devitrification of glass in the rhyolite tuff at ∼800 °C. Owing to higher undercooling due to supersaturation, the radial hydrous phases within spherulites might grow faster and led to coagulation. The polygonal contacts between spherulites and the ∼120° dihedral angle suggest solid-state modification and recrystallization as the process of devitrification proceeds as low as ∼300 °C. The sum of FeO + MgO is positively correlated with total alkalies along with magnetite oxidation in the matrix to Fe-oxyhydroxides, and to the incorporation of OH- into silicates within the spehrulites themselves. Structural H2O in glass of the Jabal Shama perlite (obsidian) is considerable (∼9-12 wt%) with 3.72-5.6 wt% L.O.I. of the whole-rock. The presence of deleterious silica impurities would lower the ore grade due to

Applications of detrital geochronology and thermochronology from glacial deposits to the Paleozoic and Mesozoic thermal history of the Ross Embayment, Antarctica

NASA Astrophysics Data System (ADS)

Welke, Bethany; Licht, Kathy; Hennessy, Andrea; Hemming, Sidney; Pierce Davis, Elizabeth; Kassab, Christine

2016-07-01

Till from moraines at the heads of six major outlet glaciers in the Transantarctic Mountains (TAM) and from till beneath three West Antarctic ice streams have a ubiquitous zircon U-Pb age population spanning the time of the Ross/Pan-African Orogenies (610-475 Ma). Geochronology and thermochronology of detrital minerals in these Antarctic glacial tills reveal two different thermal histories for the central and southern TAM. Double-dating of the zircons reveals a geographically widespread (U-Th)/He (ZHe) population of 180-130 Ma in most of the till samples. Sandstone outcrops at Shackleton Glacier, and three Beacon Supergroup sandstone clasts from three moraines, have ZHe ages that fall entirely within this range. The similar population and proximity of many of the till samples to Beacon outcrops lead us to suggest that this extensive ZHe population in the tills is derived from Beacon Supergroup rocks and reflects the thermal response of the Beacon Basin to the breakup of Gondwana. A second population of older (>200 Ma) ZHe ages in tills at the head of Byrd, Nimrod, and Reedy Glaciers. For the tills at the head of the Nimrod and Byrd Glaciers, integrating the double-dated zircon results with 40Ar/39Ar of hornblende, muscovite and biotite, and U-Pb and (U-Th-Sm)/He double-dates on apatite yields a typical pattern of early rapid orogenic cooling (˜4-10°C/Myr) 590-475 Ma after the emplacement of the Granite Harbour Intrusives. Low temperature thermochronometers at these sites yield variable but quite old ages (ZHe 480-70 Ma and AHe 200-70 Ma) that require a long history at low temperature.

Laser ablation U-Th-Sm/He dating of detrital apatite

NASA Astrophysics Data System (ADS)

Guest, B.; Pickering, J. E.; Matthews, W.; Hamilton, B.; Sykes, C.

2016-12-01

Detrital apatite U-Th-Sm/He thermochronology has the potential to be a powerful tool for conducting basin thermal history analyses as well as complementing the well-established detrital zircon U-Pb approach in source to sink studies. A critical roadblock that prevents the routine application of detrital apatite U-Th-Sm/He thermochronology to solving geological problems is the costly and difficult whole grain approach that is generally used to obtain apatite U-Th-Sm/He data. We present a new analytical method for laser ablation thermochronology on apatite. Samples are ablated using a Resonetics™ 193 nm excimer laser and liberated 4He is measured using an ASI (Australian Scientific Instruments) Alphachron™ quadrupole mass spectrometer system; collectively known as the Resochron™. The ablated sites are imaged using a Zygo ZescopeTM optical profilometer and ablated pit volume measured using PitVol, a custom MatLabTM algorithm. The accuracy and precision of the method presented here was confirmed using well-characterized Durango apatite and Fish Canyon Tuff (FCT) apatite reference materials, with Durango apatite used as a primary reference and FCT apatite used as a secondary reference. The weighted average of our laser ablation Durango ages (30.5±0.35 Ma) compare well with ages obtained using conventional whole grain degassing and dissolution U-Th-Sm/He methods (32.56±0.43 Ma) (Jonckheere et.al., 1 993; Farley, 2000; McDowell et.al., 2005) for chips of the same Durango crystal. These Durango ages were used to produce a K-value to correct the secondary references and unknown samples. After correction, FCT apatite has a weighted average age of 28.37 ± 0.96 Ma, which agrees well with published ages. As a further test of this new method we have conducted a case study on a set of samples from the British Mountains of the Yukon Territory in NW Canada. Sandstone samples collected across the British Mountains were analyzed using conventional U-Th-Sm/He whole grain

High resolution luminescence chronology for Xiashu Loess deposits of Southeastern China

NASA Astrophysics Data System (ADS)

Yi, Shuangwen; Li, Xusheng; Han, Zhiyong; Lu, Huayu; Liu, Jinfeng; Wu, Jiang

2018-04-01

Loess deposits in Xiashu are representative of such deposits in Southeastern China that are mainly distributed in the middle and lower reaches of the Yangtze River valley. These loess-paleosol sequences provide a key archive of past climate change in humid, subtropical regions. However, the ages of the sequences are not well constrained. In this study, the standard quartz single-aliquot regenerative (SAR) dose optically stimulated luminescence (OSL) and K-feldspar post-infrared infrared stimulated luminescence (post-IR IRSL; pIRIR290) methods are used to date two loess sequences in Nanjing region. Our results show that quartz SAR OSL and K-feldspar pIRIR290 ages are more or less indistinguishable from one another up to ∼50 ka. Beyond this age, the K-feldspar pIRIR ages increased systematically with deposition depth, agreeing well with the expected ages as far as ∼200 ka. On the basis of a fully independently-dated timescale, we are therefore able to propose, for the first time, a new age model for the Xiashu Loess deposits accumulated since the penultimate interglacial period. Using our newly obtained luminescence dating ages, we observe a marked difference between the loess accumulation rates in the two sequences, potentially forced by regional depositional processes and loess preservation.

Evaluation of mineral-aqueous chemical equilibria of felsic reservoirs with low-medium temperature: A comparative study in Yangbajing geothermal field and Guangdong geothermal fields

NASA Astrophysics Data System (ADS)

Li, Jiexiang; Sagoe, Gideon; Yang, Guang; Lu, Guoping

2018-02-01

Classical geothermometers are useful tools for estimating reservoir temperatures of geothermal systems. However, their application to low-medium temperature reservoirs is limited because large variations of temperatures calculated by different classical geothermometers are usually observed. In order to help choose the most appropriate classical geothermometer for calculating the temperatures of low-medium temperature reservoirs, this study evaluated the mineral-aqueous equilibria of typical low-medium temperature felsic reservoirs in the Yangbajing geothermal field and Guangdong geothermal fields. The findings of this study support that reservoirs in the Guangdong geothermal fields have no direct magma influence. Also, natural reservoirs may represent the intermediate steady state before reaching full equilibrium, which rarely occurs. For the low-medium temperature geothermal systems without the influence of magma, even with seawater intrusion, the process of minerals reaching mineral-aqueous equilibrium is sequential: chlorite and chalcedony are the first, then followed by K-feldspar, kaolinite and K-mica. Chlorite may reach equilibrium at varying activity values, and the equilibrium between K-feldspar and kaolinite or K-feldspar and K-mica can fix the contents of K and Al in the solutions. Although the SiO2 and Al attain equilibrium state, albite and laumontite remain unsaturated and thus may affect low-medium temperature calculations. In this study, the chalcedony geothermometer was found to be the most suitable geothermometer for low-medium temperature reservoirs. The results of K-Mg geothermometer may be useful to complement that of the chalcedony geothermometer in low-medium temperature reservoir systems. Na-K geothermometer will give unreliable results at low-medium temperatures; and Na-K-Ca will also be unsuitable to calculate reservoir temperatures lower than 180 °C, probably caused by the chemical imbalance of laumontite.

Clay-mineral assemblages from some levels of K-118 drill core of Maha Sarakham evaporites, northeastern Thailand

NASA Astrophysics Data System (ADS)

Suwanich, Parkorn

Clay-mineral assemblages in Middle Clastic, Middle Salt, Lower Clastic, Potash Zone, and Lower Salt, totalling 13 samples from K-118 drill core, in the Maha Sarakham Formation, Khorat Basin, northeastern Thailand were studied. The clay-size particles were separated from the water-soluble salt by water leaching. Then the samples were leached again in the EDTA solution and separated into clay-size particles by using the timing sedimentation. The EDTA-clay residues were divided and analyzed by using the XRD and XRF method. The XRD peaks show that the major-clay minerals are chlorite, illite, and mixed-layer corrensite including traces of rectorite? and paragonite? The other clay-size particles are quartz and potassium feldspar. The XRF results indicate Mg-rich values and moderate MgAl atom ratio values in those clay minerals. The variable Fe, Na, and K contents in the clay-mineral assemblages can explain the environment of deposition compared to the positions of the samples from the core. Hypothetically, mineralogy and the chemistry of the residual assemblages strongly indicate that severe alteration and Mg-enrichment of normal clay detritus occurred in the evaporite environment through brine-sediment interaction. The various Mg-enrichment varies along the various members reflecting whether sedimentation is near or far from the hypersaline brine.

Annual Progress Report.

DTIC Science & Technology

1981-10-20

Jamming strategies. D W 3 k 4 2 i t-iew or I oev Be is o ~5e TU SS ia Y LA P 16CUTV10’:F-,n-zv fam o& nm.o ANNUAL PROGRESS REPORT for Office of Naval...7:ectrtcal Enineering and :ne j drtinateo lc.aqce ’_aboratory :nlersit )t :llinol$ It rbana-ChampaLgn -roana, Illinois ild~l Abstract La the...11 treat the related problems of -ioLsa ncortaincy. robust Winner filtering and minimax icace estima- n eac,, case :nere la Assumed to is sois

K-KIDS: Companioins to K Dwarfs Within 50 Parsecs

NASA Astrophysics Data System (ADS)

Nusdeo, Daniel Anthony; Winters, Jennifer; Paredes-Alvarez, Leonardo; Horch, Elliott; Jao, Wei-Chun; Henry, Todd J.; RECONS Institute

2017-01-01

How many K dwarfs have “kids?” Stellar multiplicity fractions have been obtained for most spectral types, most recently by Raghavan et al. (2010) and Winters et al. (2015), finding rates of 50% for solar-type stars and 27% for M dwarfs, respectively. These findings will be crucial to improving our understanding of solar-system formation, but there has not yet been a statistically significant survey for K dwarfs to bridge the gap between G and M stars. To create a sample for a robust multiplicity survey, an initial set of 1048 K dwarfs was built using the Hipparcos and 2MASS catalogs, the companions of which are called “K-KIDS.” Future releases from Gaia will help us to expand K-KIDS into a volume-complete sample out to 50-pc, and we project that the final sample will contain over 3000 stars, making this the largest volume-complete multiplicity survey ever undertaken. For observational purposes, the targeted K dwarfs are confined equatorially to -30 < DEC < +30 to ensure all stars are observable from either hemisphere. The survey for K-KIDS is split into three companion-separation regimes: small (0.02 - 2.00 arcseconds), medium (2.00 - 10.00 arcseconds), and distant (10.00+ arcseconds). Small separation companions are resolved using the Differential Speckle Survey Instrument, with which we have observed 964 out of 1048 systems to date, already finding 135 new K-KIDS. Medium separation companions are observed via a series of three observations per star at the CTIO 0.9-m telescope, integrating for 3, 30, and 300 seconds to reveal companions of various brightnesses. Finally, a common proper-motion search is used to find companions at distant separations via blinking of digitialized images in the SuperCOSMOS archive, in addition to a large-scale literature survey for previously-discovered multiples. The small and distant surveys are nearing completion, and continued progress on the medium survey ensures that a statistically significant multiplicity rate for K

Paleozoic to early Cenozoic cooling and exhumation of the basement underlying the eastern Puna plateau margin prior to plateau growth

NASA Astrophysics Data System (ADS)

Insel, N.; Grove, M.; Haschke, M.; Barnes, J. B.; Schmitt, A. K.; Strecker, M. R.

2012-12-01

Constraining the pre-Neogene history of the Puna plateau is crucial for establishing the initial conditions that attended the early stage evolution of the southern extent of the Andean plateau. We apply high- to low-temperature thermochronology data from plutonic rocks in northwestern Argentina to quantify the Paleozoic, Mesozoic and early Tertiary cooling history of the Andean crust. U-Pb crystallization ages of zircons indicate that pluton intrusion occurred during the early mid-Ordovician (490-470 Ma) and the late Jurassic (160-150 Ma). Lower-temperature cooling histories from 40Ar/39Ar analyses of K-feldspar vary substantially. Basement rocks underlying the western Puna resided at temperatures below 200°C (<6 km depth) since the Devonian (˜400 Ma). In contrast, basement rocks underlying the southeastern Puna were hotter (˜200-300°C) throughout the Paleozoic and Jurassic and cooled to temperatures of <200°C by ˜120 Ma. The southeastern Puna basement records a rapid cooling phase coeval with active extension of the Cretaceous Salta rift at ˜160-100 Ma that we associate with tectonic faulting and lithospheric thinning. The northeastern Puna experienced protracted cooling until the late Cretaceous with temperatures <200°C during the Paleocene. Higher cooling rates between 78 and 55 Ma are associated with thermal subsidence during the postrift stage of the Salta rift and/or shortening-related flexural subsidence. Accelerated cooling and deformation during the Eocene was focused within a narrow zone along the eastern Puna/Eastern Cordillera transition that coincides with Paleozoic/Mesozoic structural and thermal boundaries. Our results constrain regional erosion-induced cooling throughout the Cenozoic to have been less than ˜150°C, which implies total Cenozoic denudation of <6-4 km.

H3.1 K36M mutation in a congenital-onset soft tissue neoplasm.

PubMed

Kernohan, Kristin D; Grynspan, David; Ramphal, Raveena; Bareke, Eric; Wang, You Chang; Nizalik, Elizabeth; Ragoussis, Jiannis; Jabado, Nada; Boycott, Kym M; Majewski, Jacek; Sawyer, Sarah L

2017-12-01

We describe a patient who presented with a congenital soft tissue lesion initially diagnosed as infantile fibromatosis at 15 days of age. Unusually, the mass demonstrated malignant progression leading to death at 20 months of age. Biological progression to malignancy is not known to occur in fibromatosis, and fibrosarcoma is not known to progress from a benign lesion. Whole-exome sequencing of the tumor identified a driver mutation in histone H3.1 at lysine (K)36. Our findings support the link between oncohistones and infantile soft tissue tumors and provide additional evidence for the oncogenic effects of p.K36M in H3 variants. © 2017 Wiley Periodicals, Inc.

Solute profiles in soils, weathering gradients and exchange equilibrium/disequilibrium

USGS Publications Warehouse

White, A.F.; Schulz, M.S.; Stonestrom, David A.; Vivit, D.V.; Fitzpatrick, J.; Bullen, T.

2008-01-01

The spatial and temporal changes in hydrology and pore water elemental and 87/86Sr compositions were used to determine contemporary weathering rates in a 65 to 226 ky old soil chronosequence formed from granitic sediments deposited on marine terraces along coastal California. Cl-corrected Na, K and Si increased with depth denoting inputs from the weathering of plagioclase and K-feldspar. Solute 87/86Sr exhibited progressive mixing of sea water-dominated precipitation with inputs from less radiogenic plagioclase. Linear approximations to these weathering gradients were used to determine plagioclase weathering rates of between 0.38 and 8.9×10−15 moles m−2 s−1. The lack of corresponding weathering gradients for Ca and Sr indicated short-term equilibrium with the clay ion exchange pool which requires periodic resetting by natural perturbations to maintain continuity, in spite of soil composition changes reflecting the effects of long-term weathering.

Role of erosion and isostasy in the Cordillera Blanca uplift: insights from Low-T thermochronology and landscape evolution modeling (northern Peru, Andes)

NASA Astrophysics Data System (ADS)

Margirier, A.; Robert, X.; Braun, J.; Laurence, A.

2017-12-01

The uplift and exhumation of the highest Peruvian peaks seems closely linked to the Cordillera Blanca normal fault that delimits and shape the western flank of the Cordillera Blanca. Two models have been previously proposed to explain the occurrence of extension and the presence of this active normal fault in a compression setting but the Cordillera Blanca normal fault and the uplift and exhumation of the Cordillera Blanca remain enigmatic. Recent studies suggested an increase of exhumation rates during the Quaternary in the Cordillera Blanca and related this increase to a change in climate and erosion process (glacial erosion vs. fluvial erosion). The Cordillera Blanca granite has been significantly eroded since its emplacement (12-5 Ma) indicating a significant mass of rocks removal. Whereas it has been demonstrated recently that the effect of eroding denser rocks can contribute to an increase of uplift rate, the impact of erosion and isostasy on the increase of the Cordillera Blanca uplift rates has never been explored. Based on numerical modeling of landscape evolution we address the role of erosion and isostasy in the uplift and exhumation of the Cordillera Blanca. We performed inversions of the present-day topography, total exhumation and thermochronological data using a landscape evolution model (FastScape). Our results evidence the contribution of erosion and associated flexural rebound to the uplift of the Cordillera Blanca. Our models suggest that the erosion of the Cordillera Blanca dense intrusion since 3 Ma could also explain the Quaternary exhumation rate increase in this area. Finally, our results allow to question the previous models proposed for the formation of the Cordillera Blanca normal fault.

Late Holocene eolian activity in the mineralogically mature Nebraska Sand Hills

USGS Publications Warehouse

Muhs, D.R.; Stafford, Thomas W.; Swinehart, J.B.; Cowherd, S.D.; Mahan, S.A.; Bush, C.A.; Madole, R.F.; Maat, P.B.

1997-01-01

The age of sand dunes in the Nebraska Sand Hills has been controversial, with some investigators suggesting a full-glacial age and others suggesting that they were last active in the late Holocene. New accelerator mass spectrometry radiocarbon ages of unaltered bison bones and organic-rich sediments suggest that eolian sand deposition occurred at least twice in the past 3000 14C yr B.P. in three widely separated localities and as many as three times in the past 800 14C yr at three other localities. These late Holocene episodes of eolian activity are probably the result of droughts more intense than the 1930s "Dust Bowl" period, based on independent Great Plains climate records from lake sediments and tree rings. However, new geochemical data indicate that the Nebraska Sand Hills are mineralogically mature. Eolian sands in Nebraska have lower K-feldspar (and K2O, Rb, and Ba) contents than most possible source sediments and lower K-feldspar contents than dunes of similar age in Colorado. The most likely explanation for mineralogical maturity is reduction of sand-sized K-feldspar to silt-sized particles via ballistic impacts due to strong winds over many cycles of eolian activity. Therefore, dunes of the Nebraska Sand Hills must have had a long history, probably extending over more than one glacial-interglacial cycle, and the potential for reactivation is high, with or without a future greenhouse warming. ?? 1997 University of Washington.

K+-induced alterations in airway muscle responsiveness to electrical field stimulation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Murlas, C.; Ehring, G.; Suszkiw, J.

1986-07-01

We investigated possible pre- and postsynaptic effects of K+-induced depolarization on ferret tracheal smooth muscle (TSM) responsiveness to cholinergic stimulation. To assess electromechanical activity, cell membrane potential (Em) and tension (Tm) were simultaneously recorded in buffer containing 6, 12, 18, or 24 mM K+ before and after electrical field stimulation (EFS) or exogenous acetylcholine (ACh). In 6 mM K+, Em was -58.1 +/- 1.0 mV (mean +/- SE). In 12 mM K+, Em was depolarized to -52.3 +/- 0.9 mV, basal Tm did not change, and both excitatory junctional potentials and contractile responses to EFS at short stimulus duration weremore » larger than in 6 mM K+. No such potentiation occurred at a higher K+, although resting Em and Tm increased progressively above 12 mM K+. The sensitivity of ferret TSM to exogenous ACh appeared unaffected by K+. To determine whether the hyperresponsiveness in 12 mM K+ was due, in part, to augmented ACh release from intramural airway nerves, experiments were done using TSM preparations incubated with (3H)choline to measure (3H)ACh release at rest and during EFS. Although resting (3H)ACh release increased progressively in higher K+, release evoked by EFS was maximal in 12 mM K+ and declined in higher concentrations. We conclude that small elevations in the extracellular K+ concentration augment responsiveness of the airways, by increasing the release of ACh both at rest and during EFS from intramural cholinergic nerve terminals. Larger increases in K+ appear to be inhibitory, possibly due to voltage-dependent effects that occur both pre- and postsynaptically.« less

Multiple episodes of fast exhumation since Late Cretaceous in the Three Rivers region, SE Tibetan Plateau, revealed by low-temperature thermochronology

NASA Astrophysics Data System (ADS)

Liu, J.; Zhang, J.; McPhillips, D.; Reiners, P. W.; Wang, W.; Pik, R.; Zeng, L.; Hoke, G. D.; Xie, K.; Xiao, P.; Zheng, D.; Ge, Y.

2017-12-01

The Three Rivers region in southeast Tibet is characterized by deeply incised river valleys separated by a perched low relief landscape that gently descends from the high Tibetan plateau towards the southeast. When and how this unique landscape formed is debated. The onset of increased river incision is often interpreted as a proxy for the timing of surface uplift. Here,apatite and zircon U-Th/He and apatite fission track thermochronology are employed to map the spatial and temporal pattern of exhumation in the region. Vertical profiles of granitic rocks were collected near Deqin ( 28.5°N) and Weixi ( 27.5°N). The two transects share a similar exhumation history, with two episodes of relatively fast exhumation ( 100-300 m/Myr): during the Paleocene to Eocene (60-40 Ma) and Miocene to present (20-0 Ma), separated by an intervening period of slow exhumation. A pulse of moderate to high exhumation (70-300 m/Myr) during the mid- to late-Cretaceous (120-80 Ma) is also present in the data. Overall, the rate and total amount of exhumation near Deqin is larger than at Weixi and is especially pronounced in the interval between 20 Ma to present. This difference is likely related to whether a profile's is exposed adjacent to the more erosive trunk stream (Deqin) or contained within tributary (Weixi). In addition, the Paleocene to Eocene episode of fast exhumation in the Three Rivers region occurred prior to that observed on the eastern plateau margin. This Paleocene to Eocene period of rapid exhumation is likely due to early Cenozoic deformation related to the transpressional collision of the Indian plate with this region. Pre-Miocene episodes of fast exhumation corroborate with recent paleoaltimetry studies, which shows that the Three Rivers region was elevated prior to the Oligocene.

Function of minerals in the natural radioactivity level of Vaigai River sediments, Tamilnadu, India--spectroscopical approach.

PubMed

Ramasamy, V; Paramasivam, K; Suresh, G; Jose, M T

2014-01-03

Using Gamma ray and Fourier Transform Infrared (FTIR) spectroscopic techniques, level of natural radioactivity ((238)U, (232)Th and (40)K) and mineralogical characterization of Vaigai River sediments have been analyzed with the view of evaluating the radiation risk and its relation to available minerals. Different radiological parameters are calculated to know the entire radiological characterization. The average of activity concentrations and all radiological parameters are lower than the recommended safety limit. However, some sites are having higher radioactivity values than the safety limit. From the FTIR spectroscopic technique, the minerals such as quartz, microcline feldspar, orthoclase feldspar, kaolinite, gibbsite, calcite, montmorillonite and organic carbon are identified and they are characterized. The extinction co-efficient values are calculated to know the relative distribution of major minerals such as quartz, microcline feldspar, orthoclase feldspar and kaolinite. The calculated values indicate that the amount of quartz is higher than orthoclase feldspar, microcline feldspar and much higher than kaolinite. Crystallinity index is calculated to know the crystalline nature of quartz and the result indicates that the presence of ordered crystalline quartz in the present sediment. The role of minerals in the level of radioactivity is assessed by multivariate statistical analysis (Pearson's correlation and Cluster analysis). The statistical analysis confirms that the clay mineral kaolinite is the major factor than other major minerals to induce the important radioactivity variables such as absorbed dose rate and concentrations of (232)Th and (238)U. Copyright © 2013 Elsevier B.V. All rights reserved.

Progress on a novel VM-type pulse tube cryocooler for 4 K

NASA Astrophysics Data System (ADS)

Pan, Changzhao; Wang, Jue; Luo, Kaiqi; Wang, Junjie; Zhou, Yuan

2017-12-01

VM type pulse tube cryocooler is a new type pulse tube cryocooler driven by the thermal-compressor. This paper presented the recent experimental results on a novel single-stage VM type pulse tube cryocooler with multi-bypass. The low temperature double-inlet, orifice and gas reservoir, and multi-bypass were used as phase shifters. With the optimal operating frequency of 1.6 Hz and optimal average pressure of 1.4 MPa, a no-load temperature of 4.9 K has been obtained and 30 mW@5.6 K cooling power has been achieved. It was the first time for the single-stage VM-PTC obtaining liquid helium temperature reported so far. Moreover, it was also the first time for the multi-bypass being used in the low-frequency Stirling type pulse tube cryocooler.

Spelling Strategies: Take Stock of Students' Spelling Progress.

ERIC Educational Resources Information Center

Gentry, J. Richard

1998-01-01

Presents four informal assessments that elementary teachers can use to compare students' spelling progress to typical midyear benchmarks. The assessments, which target K-6 students, emphasize alphabet recognition, phonemic awareness, attitude and consciousness about spelling, and spelling growth through writing samples. The paper includes a…

Melting and subsolidus reactions in the system K2O-CaO-Al2O3-SiO2-H2O

NASA Astrophysics Data System (ADS)

Johannes, Wilhelm

1980-09-01

Beginning of melting and subsolidus relationships in the system K2O-CaO-Al2O3-SiO2-H2O have been experimentally investigated at pressures up to 20 kbars. The equilibria discussed involve the phases anorthite, sanidine, zoisite, muscovite, quartz, kyanite, gas, and melt and two invariant points: Point [Ky] with the phases An, Or, Zo, Ms, Qz, Vapor, and Melt; point [Or] with An, Zo, Ms, Ky, Qz, Vapor, and Melt. The invariant point [Ky] at 675° C and 8.7 kbars marks the lowest solidus temperature of the system investigated. At pressures above this point the hydrated phases zoisite and muscovite are liquidus phases and the solidus temperatures increase with increasing pressure. At 20 kbars beginning of melting occurs at 740 °C. The solidus temperatures of the quinary system K2O-CaO-Al2O3-SiO2-H2O are almost 60° C (at 20 kbars) and 170° C (at 2kbars) below those of the limiting quaternary system CaO-Al2O3-SiO2-H2O. The maximum water pressure at which anorthite is stable is lowered from 14 to 8.7 kbars in the presence of sanidine. The stability limits of anorthite+ vapor and anorthite+sanidine+vapor at temperatures below 700° C are almost parallel and do not intersect. In the wide temperature — pressure range at pressures above the reaction An+Or+Vapor = Zo+Ms+Qz and temperatures below the melting curve of Zo+Ms+Ky+Qz+Vapor, the feldspar assemblage anorthite+sanidine is replaced by the hydrated phases zoisite and muscovite plus quartz. CaO-Al2O3-SiO2-H2O. Knowledge of the melting relationships involving the minerals zoisite and muscovite contributes to our understanding of the melting processes occuring in the deeper parts of the crust. Beginning of melting in granites and granodiorites depends on the composition of plagioclase. The solidus temperatures of all granites and granodiorites containing plagioclases of intermediate composition are higher than those of the Ca-free alkali feldspar granite system and below those of the Na-free system discussed in this

Overexpression of periostin and distinct mesothelin forms predict malignant progression in a rat cholangiocarcinoma model

PubMed Central

Manzanares, Miguel Á.; Campbell, Deanna J.W.; Maldonado, Gabrielle T.

2017-01-01

Periostin and mesothelin have each been suggested to be predictors of poor survival for patients with intrahepatic cholangiocarcinoma, although the clinical prognostic value of both of these biomarkers remains uncertain. The aim of the current study was to investigate these biomarkers for their potential to act as tumor progression factors when assessed in orthotopic tumor and three‐dimensional culture models of rat cholangiocarcinoma progression. Using our orthotopic model, we demonstrated a strong positive correlation between tumor and serum periostin and mesothelin and increasing liver tumor mass and associated peritoneal metastases that also reflected differences in cholangiocarcinoma cell aggressiveness and malignant grade. Periostin immunostaining was most prominent in the desmoplastic stroma of larger sized more aggressive liver tumors and peritoneal metastases. In comparison, mesothelin was more highly expressed in the cholangiocarcinoma cells; the slower growing more highly differentiated liver tumors exhibited a luminal cancer cell surface immunostaining for this biomarker, and the rapidly growing less differentiated liver and metastatic tumor masses largely showed cytoplasmic mesothelin immunoreactivity. Two molecular weight forms of mesothelin were identified, one at ∼40 kDa and the other, a more heavily glycosylated form, at ∼50 kDa. Increased expression of the 40‐kDa mesothelin over that of the 50 kDa form predicted increased malignant progression in both the orthotopic liver tumors and in cholangiocarcinoma cells of different malignant potential in three‐dimensional culture. Moreover, coculturing of cancer‐associated myofibroblasts with cholangiocarcinoma cells promoted overexpression of the 40‐kDa mesothelin, which correlated with enhanced malignant progression in vitro. Conclusion: Periostin and mesothelin are useful predictors of tumor progression in our rat desmoplastic cholangiocarcinoma models. This supports their relevance to

Progress re-supply ship

NASA Image and Video Library

2010-01-14

ISS01-324-002 (18 November 2000) --- A Progress supply ship linked up to the orbiting International Space Station (ISS) at 3:48 GMT, November 18, bringing Expedition 1 commander William M. Shepherd, pilot Yuri P. Gidzenko and flight engineer Sergei K. Krikalev two tons of food, clothing, hardware and holiday gifts from their families. The photograph was taken with a 35mm camera and the film was later handed over to the STS-97 crew members for return to Earth and subsequent processing.

Influence of depositional environment on diagenesis in St. Peter sandstone, Michigan basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lundgren, C.E. Jr.; Barnes, D.A.

1989-03-01

The Middle Ordovician St. Peter Sandstone in the Michigan basin was deposited in marine peritidal to storm-dominated, outer shelf depositional environments that evolved in a regionally significant transgressive pattern. The formation is bounded by carbonate and shaly clastic strata of the Prairie du Chien Group below and is transitional to condensed sequence clastics and carbonates of the Glenwood Formation above. Sedimentologic and petrographic analysis of conventional core from 25 wells suggests that reservoir quality in the formation is strongly dependent on a complex diagenetic history, especially the nature and subsequent dissolution of intergranular carbonate in the sandstone. Petrographic evidence indicatesmore » that porosity in the formation formed by dissolution of precursor dolomite of various origins and, locally, the formation of pore-filling authigenic clay (chlorite-illite). Authigenic clay is the incongruent dissolution product of dolomite, detrital K-feldspar, and, possibly, muscovite and results in diminished reservoir quality where abundant in the St. Peter Sandstone. Authigenic clay is volumetrically more significant in the upper portions of the formation and is associated with higher concentrations of detrital K-feldspar. Depositional facies controlled the distribution and types of intergranular carbonate (now dolomite) and detrital K-feldspar in the St. Peter Sandstone and hence reservoir quality; both components were more significant in storm-shelf sandstone facies.« less

Electroproduction of K+ Λ at JLab Hall-C

NASA Astrophysics Data System (ADS)

Gogami, T.; Achenbach, P.; Ahmidouch, A.; Albayrak, I.; Androic, D.; Asaturyan, A.; Asaturyan, R.; Ates, O.; Baturin, P.; Badui, R.; Boeglin, W.; Bono, J.; Brash, E.; Carter, P.; Chen, C.; Chiba, A.; Christy, E.; Dalton, M.; Danagoulian, S.; De Leo, R.; Doi, D.; Elaasar, M.; Ent, R.; Fujii, Y.; Furic, M.; Gabrielyan, M.; Gan, L.; Garibaldi, F.; Gaskell, D.; Gasparian, A.; Hashimoto, O.; Horn, T.; Hu, B.; Hungerford, Ed. V.; Jones, M.; Kanda, H.; Kaneta, M.; Kato, S.; Kawai, M.; Kawama, D.; Khanal, H.; Kohl, M.; Liyanage, A.; Luo, W.; Maeda, K.; Margaryan, A.; Markowitz, P.; Maruta, T.; Matsumura, A.; Maxwell, V.; Mkrtchyan, A.; Mkrtchyan, H.; Nagao, S.; Nakamura, S. N.; Narayan, A.; Neville, C.; Niculescu, G.; Niculescu, M. I.; Nunez, A.; Nuruzzaman; Okayasu, Y.; Petkovic, T.; Pochodzalla, J.; Qiu, X.; Reinhold, J.; Rodriguez, V. M.; Samanta, C.; Sawatzky, B.; Seva, T.; Shichijo, A.; Tadevosyan, V.; Tang, L.; Taniya, N.; Tsukada, K.; Veilleux, M.; Vulcan, W.; Wesselmann, F. R.; Wood, S. A.; Yamamoto, T.; Ya, L.; Ye, Z.; Yokota, K.; Yuan, L.; Zhamkochyan, S.; Zhu, L.

2013-08-01

A Λ hypernuclear spectroscopic experiment, JLab E05-115 was performed at JLab Hall-C in 2009 by the (e, e'K+) reaction. Data of Λ hypernuclei with mass numbers from A = 7 to A = 52 were successfully taken, and the analyses are in progress. A polyethylene (CH2) target was used as a proton target to calibrate energy scales, and to study elementary process of the p(e, e'K+) Λ, Σ0 reaction. A preliminary differential cross section of K+ Λ electro-production at low Q2 [~0.01 (GeV/c)2] and at small kaon angles is reported in the present article.

Progress update of NASA's free-piston Stirling space power converter technology project

NASA Technical Reports Server (NTRS)

Dudenhoefer, James E.; Winter, Jerry M.; Alger, Donald

1992-01-01

A progress update is presented of the NASA LeRC Free-Piston Stirling Space Power Converter Technology Project. This work is being conducted under NASA's Civil Space Technology Initiative (CSTI). The goal of the CSTI High Capacity Power Element is to develop the technology base needed to meet the long duration, high capacity power requirements for future NASA space initiatives. Efforts are focused upon increasing system power output and system thermal and electric energy conversion efficiency at least five fold over current SP-100 technology, and on achieving systems that are compatible with space nuclear reactors. This paper will discuss progress toward 1050 K Stirling Space Power Converters. Fabrication is nearly completed for the 1050 K Component Test Power Converter (CTPC); results of motoring tests of the cold end (525 K), are presented. The success of these and future designs is dependent upon supporting research and technology efforts including heat pipes, bearings, superalloy joining technologies, high efficiency alternators, life and reliability testing, and predictive methodologies. This paper will compare progress in significant areas of component development from the start of the program with the Space Power Development Engine (SPDE) to the present work on CTPC.

Development of a Space-Flight ADR Providing Continuous Cooling at 50 mK with Heat Rejection at 10 K

NASA Technical Reports Server (NTRS)

Tuttle, Jim; Canavan, Ed; DeLee, Hudson; Dipirro, Michael; Jahromi, Amir; Kimball, Mark; Shirron, Peter; Sullivan, Dan; Switzer, Eric

2017-01-01

Future astronomical instruments will require sub-Kelvin detector temperatures to obtain high sensitivity. In many cases large arrays of detectors will be used, and the associated cooling systems will need performance surpassing the limits of present technologies. NASA is developing a compact cooling system that will lift heat continuously at temperatures below 50 mK and reject it at over 10 K. Based on Adiabatic Demagnetization Refrigerators (ADRs), it will have high thermodynamic efficiency and vibration-free operation with no moving parts. It will provide more than 10 times the current flight ADR cooling power at 50 mK and will also continuously cool a 4 K stage for instruments and optics. In addition, it will include an advanced magnetic shield resulting in external field variations below 5 T. We describe the cooling system here and report on the progress in its development.

Implementation of the K-12 Education Reform in Qatar's Schools. Monograph

ERIC Educational Resources Information Center

Zellman, Gail L.; Ryan Gery W.; Karam, Rita; Constant, Louay; Salem, Hanine; Gonzalez, Gabriella; Orr, Nate; Goldman, Charles A.; Al-Thani, Hessa; Al-Obaidli, Kholode

2009-01-01

The leadership of Qatar is greatly invested in its K-12 education reform, "Education for a New Era," because it views education as the key to the nation's economic and social progress. This study, one of a number of RAND studies that trace and document the reform process in Qatar, was designed to assess progress made in the first years…

Outstanding Science Trade Books for Students K-12

ERIC Educational Resources Information Center

Science Teacher, 2016

2016-01-01

Science teachers and mentors continue to be challenged to meet the high expectations of "A Framework for K-12 Science Education" and the "Next Generation Science Standards." Indeed the Framework urges teachers to help learners "[build] progressively more sophisticated explanations of natural phenomena..." while the…

Specific Detection of CD56 (NCAM) Isoforms for the Identification of Aggressive Malignant Neoplasms with Progressive Development

PubMed Central

Gattenlöhner, Stefan; Stühmer, Thorsten; Leich, Ellen; Reinhard, Matthias; Etschmann, Benjamin; Völker, Hans-Ulrich; Rosenwald, Andreas; Serfling, Edgar; Christian Bargou, Ralf; Ertl, Georg; Einsele, Hermann; Müller-Hermelink, Hans-Konrad

2009-01-01

Alternative splicing of transcripts from many cancer-associated genes is believed to play a major role in carcinogenesis as well as in tumor progression. Alternative splicing of one such gene, the neural cell adhesion molecule CD56 (NCAM), impacts the progression, inadequate therapeutic response, and reduced total survival of patients who suffer from numerous malignant neoplasms. Although previous investigations have determined that CD56 exists in three major isoforms (CD56120kD, CD56140kD, and CD56180kD) with individual structural and functional properties, neither the expression profiles nor the functional relevance of these isoforms in malignant tumors have been consistently investigated. Using new quantitative reverse transcriptase-polymerase chain reaction (qRT-PCR) strategies and novel CD56 isoform-specific antibodies, CD56140kD was shown to be exclusively expressed in a number of highly malignant CD56+ neoplasms and was associated with the progression of CD56+ precursor lesions of unclear malignant potential. Moreover, only CD56140kD induced antiapoptotic/proliferative pathways and specifically phosphorylated calcium-dependent kinases that are relevant for tumorigenesis. We conclude, therefore, that the specific detection of CD56 isoforms will help to elucidate their individual functions in the pathogenesis and progression of malignant neoplasms and may have a positive impact on the development of CD56-based immunotherapeutic strategies. PMID:19246644

Transcriptional regulators of Na,K-ATPase subunits

PubMed Central

Li, Zhiqin; Langhans, Sigrid A.

2015-01-01

The Na,K-ATPase classically serves as an ion pump creating an electrochemical gradient across the plasma membrane that is essential for transepithelial transport, nutrient uptake and membrane potential. In addition, Na,K-ATPase also functions as a receptor, a signal transducer and a cell adhesion molecule. With such diverse roles, it is understandable that the Na,K-ATPase subunits, the catalytic α-subunit, the β-subunit and the FXYD proteins, are controlled extensively during development and to accommodate physiological needs. The spatial and temporal expression of Na,K-ATPase is partially regulated at the transcriptional level. Numerous transcription factors, hormones, growth factors, lipids, and extracellular stimuli modulate the transcription of the Na,K-ATPase subunits. Moreover, epigenetic mechanisms also contribute to the regulation of Na,K-ATPase expression. With the ever growing knowledge about diseases associated with the malfunction of Na,K-ATPase, this review aims at summarizing the best-characterized transcription regulators that modulate Na,K-ATPase subunit levels. As abnormal expression of Na,K-ATPase subunits has been observed in many carcinoma, we will also discuss transcription factors that are associated with epithelial-mesenchymal transition, a crucial step in the progression of many tumors to malignant disease. PMID:26579519

Na,K-ATPase is a target of cigarette smoke and reduced expression predicts poor patient outcome of smokers with lung cancer

PubMed Central

Huynh, Thu P.; Mah, Vei; Sampson, Valerie B.; Chia, David; Fishbein, Michael C.; Horvath, Steve; Alavi, Mohammad; Wu, Debbie C.; Harper, Jeffrey; Sarafian, Ted; Dubinett, Steven M.; Langhans, Sigrid A.; Goodglick, Lee

2012-01-01

Diminished Na,K-ATPase expression has been reported in several carcinomas and has been linked to tumor progression. However, few studies have determined whether Na,K-ATPase function and expression are altered in lung malignancies. Because cigarette smoke (CS) is a major factor underlying lung carcinogenesis and progression, we investigated whether CS affects Na,K-ATPase activity and expression in lung cell lines. Cells exposed to CS in vitro showed a reduction of Na,K-ATPase activity. We detected the presence of reactive oxygen species (ROS) in cells exposed to CS before Na,K-ATPase inhibition, and neutralization of ROS restored Na,K-ATPase activity. We further determined whether Na,K-ATPase expression correlated with increasing grades of lung adenocarcinoma and survival of patients with smoking history. Immunohistochemical analysis of lung adenocarcinoma tissues revealed reduced Na,K-ATPase expression with increasing tumor grade. Using tissue microarray containing lung adenocarcinomas of patients with known smoking status, we found that high expression of Na,K-ATPase correlated with better survival. For the first time, these data demonstrate that CS is associated with loss of Na,K-ATPase function and expression in lung carcinogenesis, which might contribute to disease progression. PMID:22345575

Differential Expression of IL-17, 22 and 23 in the Progression of Colorectal Cancer in Patients with K-ras Mutation: Ras Signal Inhibition and Crosstalk with GM-CSF and IFN-γ

PubMed Central

Petanidis, Savvas; Anestakis, Doxakis; Argyraki, Maria; Hadzopoulou-Cladaras, Margarita; Salifoglou, Athanasios

2013-01-01

Recent studies have suggested that aberrant K-ras signaling is responsible for triggering immunological responses and inflammation-driven tumorigenesis. Interleukins IL-17, IL-22, and IL-23 have been reported in various types of malignancies, but the exact mechanistic role of these molecules remains to be elucidated. Given the role of K-ras and the involvement of interleukins in colorectal tumorigenesis, research efforts are reported for the first time, showing that differentially expressed interleukin IL-17, IL-22, and IL-23 levels are associated with K-ras in a stage-specific fashion along colorectal cancer progression. Specifically, a) the effect of K-ras signaling was investigated in the overall expression of interleukins in patients with colorectal cancer and healthy controls, and b) an association was established between mutant K-ras and cytokines GM-CSF and IFN-γ. The results indicate that specific interleukins are differentially expressed in K-ras positive patients and the use of K-ras inhibitor Manumycin A decreases both interleukin levels and apoptosis in Caco-2 cells by inhibiting cell viability. Finally, inflammation-driven GM-CSF and IFN-γ levels are modulated through interleukin expression in tumor patients, with interleukin expression in the intestinal lumen and cancerous tissue mediated by aberrant K-ras signaling. Collectively, the findings a) indicate that interleukin expression is influenced by ras signaling and specific interleukins play an oncogenic promoter role in colorectal cancer, highlighting the molecular link between inflammation and tumorigenesis, and b) accentuate the interwoven molecular correlations as leads to new therapeutic approaches in the future. PMID:24040001

The influence of crystallography and kinetics on phengite breakdown reactions in a low-pressure metamorphic aureole

NASA Astrophysics Data System (ADS)

Worden, R. H.; Droop, G. T. R.; Champness, P. E.

1992-04-01

A natural example of phengite that had undergone partial thermal decomposition at a pressure of about 0.5 kbar and a temperature of about 680° C in a contact aureole was exmined in the transmission electron microscope (TEM). Partially pseudomorphed phengites were found to consist of combinations of phengite, biotite, K-feldspar, mullite, sillimanite, spinel and cordierite. Different areas within individual, partially pseudomorphed, phengite grains show various degrees of reaction and different reaction products; the cores are the least reacted and the margins have reacted most. In the cores the assemblage Al-, Mg-enriched phengite+biotite +K-feldspar+mullite±spinel has formed, whereas the assemblage K-feldspar+mullite+sillimanite+spinel +biotite+cordierite has formed at the edges. According to our thermodynamic calculations, the breakdown of phengite should have produced cordierite+spinel +corundum+K-feldspar in regions isolated from the influx of SiO2 and cordierite+andalusite+quartz+K-feldspar in regions near the edge of the grains that were essentially saturated with SiO2. Chemical equilibrium was not achieved in any part of the partially pseudomorphed phengites on a micron scale or larger. Breakdown theoretically should have been complete by about 550° C; the reaction temperature was overstepped by at least 130° C for 20 25 years. The variations in the degree and type of reaction are probably due partly to the availability of suitable nucleation sites in different regions, partly to the need to remove H2O from reaction sites and partly to the influence of SiO2, which diffused into the grains during metamorphism. The presence of SiO2 lowers the equilibrium temperatures. Thus there is a higher driving force for breakdown near the grain boundaries than in the cores. Most of the products show an orientation relationship with the parent phengite and have consistent habit planes; they have their closest-packed planes and closest-packed directions parallel to one

U. K. to resume natural gas imports

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1992-02-17

This paper reports that the U.K. government has opened the way for resuming gas imports into Britain by approving a contract signed by U.K. electric power utility National Power to buy gas from Norway. A new joint marketing venture of BP Exploration, Den norske stats oljeselskap AS (Statoil), and Norsk Hydro AS also will be allowed to import gas for electric power plant fuel once it has a contract. National Power and the BP/Statoil/Norsk Hydro group will use the Frigg pipeline from Norwegian waters into St. Fergus, north of Aberdeen, the only existing link between the British transmission system andmore » foreign supplies of gas. Meantime, progress is under way toward a second pipeline to link the U.K. with foreign natural gas supplies, calling for a pipeline across the English Channel joining the continental European pipeline system to the U.K. network.« less

Tectono-thermal evolution of the southwestern Alxa Tectonic Belt, NW China: Constrained by apatite U-Pb and fission track thermochronology

NASA Astrophysics Data System (ADS)

Song, Dongfang; Glorie, Stijn; Xiao, Wenjiao; Collins, Alan S.; Gillespie, Jack; Jepson, Gilby; Li, Yongchen

2018-01-01

The Central Asian Orogenic Belt (CAOB) is regarded to have undergone multiple phases of intracontinental deformation during the Meso-Cenozoic. Located in a key position along the southern CAOB, the Alxa Tectonic Belt (ATB) connects the northernmost Tibetan Plateau with the Mongolian Plateau. In this paper we apply apatite U-Pb and fission track thermochronological studies on varieties of samples from the southwestern ATB, in order to constrain its thermal evolution. Precambrian bedrock samples yield late Ordovician-early Silurian ( 430-450 Ma) and late Permian ( 257 Ma) apatite U-Pb ages; the late Paleozoic magmatic-sedimentary samples yield relatively consistent early Permian ages from 276 to 290 Ma. These data reveal that the ATB experienced multiple Paleozoic tectono-thermal events, as the samples passed through the apatite U-Pb closure temperature ( 350-550 °C). We interpret these tectonic events to record the long-lived subduction-accretion processes of the Paleo-Asian Ocean during the formation of the southern CAOB, with possible thermal influence of the Permian Tarim mantle plume. Apatite fission track (AFT) data and thermal history modelling reveal discrete low-temperature thermal events for the ATB, inducing cooling/reheating through the AFT partial annealing zone ( 120-60 °C). During the Permian, the samples underwent rapid cooling via exhumation or denudation from deep crustal levels to temperatures < 200 °C. Subsequent thermal events in the Triassic were thought to be associated with the final amalgamation of the CAOB or the closure of the Paleotethys. During the Jurassic-Cretaceous the study area experienced heating by burial, followed by renewed cooling, which may be related with the construction and subsequent collapse of the Mongol-Okhotsk Orogeny, or the Lhasa-Eurasia collision and subsequent slab break-off. These results indicate that the ATB may have been stable after late Cretaceous in contrast to the Qilian Shan and Tianshan. Finally, our

A natural laboratory for 40Ar/39Ar geochronology: ICDP cores from Lake Van, Turkey

NASA Astrophysics Data System (ADS)

Engelhardt, Jonathan; Sudo, Masafumi; Oberhänsli, Roland

2015-04-01

Pore water samples from ICDP Paleovan cores indicate a limited pore water exchange within Quaternary lake sediments. The core's volcaniclastic sections bear unaltered K-rich ternary feldspar and fresh to altered glass shards of predominantly rhyolitic composition. Whereas applying the 40Ar/39Ar method on feldspars resulted in ages timing a late-stage crystallization, glass shards had the potential to date the eruption. Volcanic glass is prone to modifications such as hydrous alteration (palagonitization) and devitrification (Cerling et al., 1985). These modifications affect the glass' chemistry and challenge the application of the 40Ar/39Ar method. Gaining precise radiometric ages from two phases has the potential to strengthen a climate-stratigraphic age-model (Stockhecke et al., 2014), and to significantly increase the temporal resolution on the deposition of the lake sediments. Vice versa the core's previous age model has the ability to question the reliability of 40Ar/39Ar eruption ages derived from ternary feldspars and glass shards. Multi- and single-grain total fusion on alkali feldspars from six volcaniclastic deposits resulted in Pleistocene ages that are in good agreement with the predicted age model. Feldspar phenocrysts from three ashes in the core's youngest section yielded consistent isochron ages that are significantly older than the model's prediction. Several distinct stratigraphic and paleomagnetic time markers of similar stratigraphic positions contradict to the older radiometric dates (Stockhecke et al., 2014). Partial resorption features of inherited feldspar domains and the involvement of excess 40Ar indicate incomplete degassing of older domains. To evaluate the magmatic history of the different domains EMPA mappings of trace elements that could be interpreted as Ar diffusion couples are currently conducted. Geochronology on Paleovan cores offers unique opportunities to monitor the effect of alteration on the Ar-systematics of volcanic glass

Late Cenozoic cooling history of the central Menderes Massif: Timing of the Büyük Menderes detachment and the relative contribution of normal faulting and erosion to rock exhumation

NASA Astrophysics Data System (ADS)

Wölfler, Andreas; Glotzbach, Christoph; Heineke, Caroline; Nilius, Nils-Peter; Hetzel, Ralf; Hampel, Andrea; Akal, Cüneyt; Dunkl, István; Christl, Marcus

2017-10-01

Based on new thermochronological data and 10Be-derived erosion rates from the southern part of the central Menderes Massif (Aydın block) in western Turkey, we provide new insights into the tectonic evolution and landscape development of an area that undergoes active continental extension. Fission-track and (U-Th)/He data reveal that the footwall of the Büyük Menderes detachment experienced two episodes of enhanced cooling and exhumation. Assuming an elevated geothermal gradient of 50 °C/km, the first phase occurred with an average rate of 0.90 km/Myr in the middle Miocene and the second one in the latest Miocene and Pliocene with a rate of 0.43 km/Myr. The exhumation rates between these two phases were lower and range from 0.14 to 0.24 km/Myr, depending on the distance to the detachment. Cosmogenic nuclide-based erosion rates for catchments in the Aydın block range from 0.1 to 0.4 km/Myr. The similarity of the erosion rates on both sides of the Aydın block (northern and southern flank) indicate that a rather symmetric erosion pattern has prevailed during the Holocene. If these millennial erosion rates are representative on a million-year timescale they indicate that, apart from normal faulting, erosion in the hanging wall of the Büyük Menderes detachment fault did also contribute to the exhumation of the metamorphic rocks.

Petrochemistry and zircon U-Pb geochronology of granitic rocks in the Wang Nam Khiao area, Nakhon Ratchasima, Thailand: Implications for petrogenesis and tectonic setting

NASA Astrophysics Data System (ADS)

Fanka, Alongkot; Tsunogae, Toshiaki; Daorerk, Veerote; Tsutsumi, Yukiyasu; Takamura, Yusuke; Sutthirat, Chakkaphan

2018-05-01

Carboniferous biotite granite, Late Permian hornblende granite, and Triassic biotite-hornblende granite, all of which belong to the Eastern Granite Belt, expose in the Wang Nam Khiao area, Nakhon Ratchasima, northeastern Thailand. The Carboniferous biotite granite is dominated by quartz, K-feldspar, plagioclase, and biotite. The Late Permian hornblende granite contains dominant assemblages of plagioclase, quartz, K-feldspar, hornblende, and minor amount of biotite, while the Triassic biotite-hornblende granite consists of quartz, plagioclase, K-feldspar with small amounts of biotite, and hornblende. The REE patterns with steep decrease from light to heavy REE together with the LILE (e.g. K, Sr) enrichment and depletion of some particular HFSE (e.g. Nb, Ti) indicate low degree of partial melting. Mineral chemistry of biotite and hornblende in the granites reflects crystallization from hydrous calc-alkaline arc-derived magmas possibly formed by subduction. Amphibole-plagioclase thermometry and Al-in-hornblende barometry indicate that the Late Permian hornblende granite and the Triassic biotite-hornblende granite may have equilibrated at 3.0-5.8 kbar/700-820 °C and 2.0-3.2 kbar/600-750 °C, respectively, in the middle-upper crust (about 10-15 km depth). Zircon U-Pb geochronology of the Carboniferous biotite granite, Late Permian hornblende granite and Triassic biotite-hornblende granite yielded intrusion ages of 314.6-284.9 Ma, 253.4 Ma, and 237.8 Ma, respectively, which implies multiple episodes of arc-magmatism formed by Palaeo-Tethys subduction beneath Indochina Terrane during Late Carboniferous/Early Permian, Late Permian and Middle Triassic.

Thermodynamic assessment of hydrothermal alkali feldspar-mica-aluminosilicate equilibria

USGS Publications Warehouse

Sverjensky, D.A.; Hemley, J.J.; d'Angelo, W. M.

1991-01-01

The thermodynamic properties of minerals retrieved from consideration of solid-solid and dehydration equilibria with calorimetric reference values, and those of aqueous species derived from studies of electrolytes, are not consistent with experimentally measured high-temperature solubilities in the systems K2O- and Na2O-Al2O3-SiO2-H2O-HCl (e.g., K-fs - Ms - Qtz - K+ - H+). This introduces major inaccuracies into the computation of ionic activity ratios and the acidities of diagenetic, metamorphic, and magmatic hydrothermal fluids buffered by alkali silicate-bearing assemblages. We report a thermodynamic analysis of revised solubility equilibria in these systems that integrates the thermodynamic properties of minerals obtained from phase equilibria studies (Berman, 1988) with the properties of aqueous species calculated from a calibrated equation of state (Shock and Helgeson, 1988). This was achieved in two separate steps. First, new values of the free energies and enthalpies of formation at 25??C and 1 bar for the alkali silicates muscovite and albite were retrieved from the experimental solubility equilibria at 300??C and Psat. Because the latter have stoichiometric reaction coefficients different from those for solid-solid and dehydration equilibria, our procedure preserves exactly the relative thermodynamic properties of the alkali-bearing silicates (Berman, 1988). Only simple arithmetic adjustments of -1,600 and -1,626 (??500) cal/mol to all the K- and Na-bearing silicates, respectively, in Berman (1988) are required. In all cases, the revised values are within ??0.2% of calorimetric values. Similar adjustments were derived for the properties of minerals from Helgeson et al. (1978). Second, new values of the dissociation constant of HCl were retrieved from the solubility equilibria at temperatures and pressures from 300-600??C and 0.5-2.0 kbars using a simple model for aqueous speciation. The results agree well with the conductance-derived dissociation

Impact mineralogy and chemistry of the cretaceous-tertiary boundary at DSDP site 576

NASA Technical Reports Server (NTRS)

Bostwick, Jennifer A.; Kyte, Frank T.

1993-01-01

We have identified the K/T boundary in pelagic clay sediments from cores at DSDP Site 576 in the western North Pacific. Detailed geochemical and trace mineralogical analyses of this boundary section are in progress and initial results indicate similarities and differences relative to the only other clay core investigated in detail; DSDP Site 596, a locality in the western South Pacific. Peak Ir concentrations of 13 ng/g in DSDP Hole 576B are virtually identical with those observed in the South Pacific, but in the North Pacific this peak is much narrower and the integrated Ir fluence of 85 ng cm(exp -2) is 4 times lower (320 in Hole 596). Of the 34 elements measured, only Ir and Cr were found to have anomalous concentrations in K/T boundary samples. Trace mineral residues were obtained by washing away clays and sequential chemical leaches (including HF) to remove typical hydrogenous and biogenous sediment components (e.g., zeolites and radiolarian opal). We attempted to quantitatively recover the entire trace mineral assemblage for grains greater than 30 micrometers in diameter. Our mineral residues were dominated by two phases: quartz and magnesioferrite spinel. Other non-opaque mineral grains we have positively identified were trace K-feldspar, plagioclase, corundum, and muscovite. Of these only K-feldspar exhibited planar deformation features (PDF). We have not found abundant plagioclase, as in the South Pacific suggesting that this phase was either not preserved in the North Pacific, or that in the south, it has a non-impact (i.e., volcanic) source. PDF in quartz were commonly obscured by secondary overgrowths on the surfaces of quartz grains, presumably from diagenetic reprecipitation of silica dissolved from opaline radiolarian tests that are common in these sediments. However, careful examination revealed that most grains had multiple sets of PDF. Of the 133 quartz grains greater than 30 micrometers analyzed, 62 percent showed evidence of shock. The largest

Controls on Cenozoic exhumation of the Tethyan Himalaya from fission-track thermochronology and detrital zircon U-Pb geochronology in the Gyirong basin area, southern Tibet

NASA Astrophysics Data System (ADS)

Shen, Tianyi; Wang, Guocan; Leloup, Philippe Hervé; van der Beek, Peter; Bernet, Matthias; Cao, Kai; Wang, An; Liu, Chao; Zhang, Kexin

2016-07-01

The Gyirong basin, southern Tibet, contains the record of Miocene-Pliocene exhumation, drainage development, and sedimentation along the northern flank of the Himalaya. The tectonic controls on basin formation and their potential link to the South Tibetan Detachment System (STDS) are not well understood. We use detrital zircon (ZFT) and apatite (AFT) fission-track analysis, together with detrital zircon U-Pb dating to decipher the provenance of Gyirong basin sediments and the exhumation history of the source areas. Results are presented for nine detrital samples of Gyirong basin sediments (AFT, ZFT, and U-Pb), two modern river-sediment samples (ZFT and AFT), and six bedrock samples (ZFT) from transect across the Gyirong fault bounding the basin to the east. The combination of detrital zircon U-Pb and fission-track data demonstrates that the Gyirong basin sediments were sourced locally from the Tethyan Sedimentary Sequence. This provenance pattern indicates that deposition was controlled by the Gyirong fault, active since 10 Ma, whose vertical throw was probably < 5000 m, rather than being controlled by normal faults associated with the STDS. The detrital thermochronology data contain two prominent age groups at 37-41 and 15-18 Ma, suggesting rapid exhumation at these times. A 15-18 Ma phase of rapid exhumation has been recorded widely in both southern Tibet and the Himalaya. A possible interpretation for such a major regional exhumation event might be detachment of the subducting Indian plate slab during the middle Miocene, inducing dynamic uplift of the Indian plate overriding its own slab.

U. K. pressing campaign to improve offshore safety

DOE Office of Scientific and Technical Information (OSTI.GOV)

Knott, D.

1994-02-14

The U.K. government is making progress in its campaign to improve the safety of personnel working offshore. The government's Health and Safety Executive (HSE) plans to assess and pass judgment on at lease one safety plan, called a safety case, from each U.K. North Sea operator as soon as possible. HSE has agreed with the industry on a list of 61 priority safety cases, known as exemplars. Feedback from exemplar assessment will help operators review safety management and assist in preparation or revision of future safety cases. It also will give HSE practice in assessing a range of case types.more » The requirement for a safety program is part of new U.K. offshore legislation designed to prevent another accident similar to the Piper Alpha platform fire and explosion of 1988. After the transition period it will be against the law to operate an oil and gas installation in British waters without an accepted safety case. Besides existing installations, safety cases are also required for new installations reaching design stage by May 31, 1993, the date safety case regulations went into force. The paper describes the Cullen report, companies' experiences with the new law, and the safety assessment progress so far.« less

Processes of energy deposition by heavy-particle and electron impact. Final progress report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Salop, A.; Smith, F.T.

1978-04-18

Progress is reported in three areas of reasearch during the present period: K-shell ionization in high energy collisions of heavy ions with light target atoms using the sudden (Magnus) approximation, K-L level matching phenomena associated with K-shell vacancy production in heavy-ion collisions, and studies of low energy collisions of electrons with molecules using semi-classical perturbation theory. A brief discussion of each of these activities is given.

K/sup +/-induced alterations in airway muscle responsiveness to electrical field stimulation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Murlas, C.; Ehring, G.; Suszkiw, J.

1986-07-01

The authors investigated possible pre- and postsynaptic effects of K/sup +/-induced depolarization on ferret tracheal smooth muscle (TSM) responsiveness to cholinergic stimulation. To assess electromechanical activity, cell membrane potential (E/sub m/) and tension (T/sub m/) were simultaneously recorded in buffer containing 6, 12, 18, or 24 mM K/sup +/ before and after electrical field stimulation (EFS) or exogenous acetylcholine (ACh). In 6 mM K/sup +/ E/sub m/ was -58.1 +/- 1.0 m V (mean +/- SE). In 12 mM K/sup +/, E/sub m/ was depolarized to -52.3 +/- 0.9 mV, basal T/sub m/ did not change, and both excitatory junctionalmore » potentials and contractile responses to EFS at short stimulus duration were larger than in 6 mM K/sup +/. No such potentiation occurred at a higher K/sup +/, although resting E/sub m/ and T/sub m/ increased progressively above 12 mM K/sup +/. The sensitivity of ferret TSM to exogenous ACh appeared unaffected by K/sup +/. To determine whether the hyperresponsiveness in 12 mM K/sup +/ was due, in part, to augmented ACh release from intramural airway nerves, experiments were done using TSM preparations incubated with (/sup 3/H)choline to measure (/sup 3/H)ACh release at rest and during EFS. Although resting (/sup 3/H)ACh release increased progressively in higher K/sup +/, release evoked by EFS was maximal in 12 mM K/sup +/ and declined in higher concentrations. They conclude that small elevations in the extracellular K/sup +/ concentration augment responsiveness of the airways, by increasing the release of ACh both at rest and during EFS from intramural cholinergic nerve terminals. Larger increases in K/sup +/ appear to be inhibitory, possibly due to voltage-dependent effects that occur both pre- and postsynaptically.« less

Non-Coding Keratin Variants Associate with Liver Fibrosis Progression in Patients with Hemochromatosis

PubMed Central

Lunova, Mariia; Guldiken, Nurdan; Lienau, Tim C.; Stickel, Felix; Omary, M. Bishr

2012-01-01

Background Keratins 8 and 18 (K8/K18) are intermediate filament proteins that protect the liver from various forms of injury. Exonic K8/K18 variants associate with adverse outcome in acute liver failure and with liver fibrosis progression in patients with chronic hepatitis C infection or primary biliary cirrhosis. Given the association of K8/K18 variants with end-stage liver disease and progression in several chronic liver disorders, we studied the importance of keratin variants in patients with hemochromatosis. Methods The entire K8/K18 exonic regions were analyzed in 162 hemochromatosis patients carrying homozygous C282Y HFE (hemochromatosis gene) mutations. 234 liver-healthy subjects were used as controls. Exonic regions were PCR-amplified and analyzed using denaturing high-performance liquid chromatography and DNA sequencing. Previously-generated transgenic mice overexpressing K8 G62C were studied for their susceptibility to iron overload. Susceptibility to iron toxicity of primary hepatocytes that express K8 wild-type and G62C was also assessed. Results We identified amino-acid-altering keratin heterozygous variants in 10 of 162 hemochromatosis patients (6.2%) and non-coding heterozygous variants in 6 additional patients (3.7%). Two novel K8 variants (Q169E/R275W) were found. K8 R341H was the most common amino-acid altering variant (4 patients), and exclusively associated with an intronic KRT8 IVS7+10delC deletion. Intronic, but not amino-acid-altering variants associated with the development of liver fibrosis. In mice, or ex vivo, the K8 G62C variant did not affect iron-accumulation in response to iron-rich diet or the extent of iron-induced hepatocellular injury. Conclusion In patients with hemochromatosis, intronic but not exonic K8/K18 variants associate with liver fibrosis development. PMID:22412904

A Primary Grade (K-3) Earth Science Program

ERIC Educational Resources Information Center

Schwartz, Maurice L.; Slesnick, Irwin L.

1973-01-01

Describes the rationale and structure of a newly developed earth science program for elementary school children (K-3). The activities involve pre-operational and concrete operational stages, progressing from one to the other. Children show sustained interest and enthusiasm as they investigate landforms, the moon, fossils, and weather phenomena.…

Deciphering Past and Present Tectonics of the Rio Grande Rift in New Mexico Utilizing Apatite Fission Track Thermochronology, Geochronology, Quaternary Faulting, and Cross-Section Restoration

NASA Astrophysics Data System (ADS)

Ricketts, J. W.; Karlstrom, K. E.; Kelley, S. A.; Priewisch, A.; Crossey, L. J.; Asmerom, Y.; Polyak, V.; Selmi, M.

2011-12-01

The Rio Grande rift provides an excellent laboratory for understanding styles and processes of extensional tectonics, and their driving forces. We apply apatite fission track (AFT) thermochronology, geochronology, fracture analysis, and cross-section restoration to decipher past and present tectonics of the Rio Grande rift. AFT data has been compiled from rift flank uplifts along the Rio Grande rift in an attempt to recognize long wavelength spatial and temporal patterns. AFT ages record time of cooling of rocks below ~110°C and, when cooling is due to exhumation, age elevation traverses can record upward advection of rocks through paleo 110°C isotherms. The relatively passive sides of half-grabens (e.g. Manzanos and Santa Fe Range) preserve Laramide AFT ages ranging from 45-70 Ma, indicating they were cooled during the Laramide Orogeny and have remained cooler than 110°C since then. Rift flanks on the tectonically active sides of half-grabens, (e.g. Sierra Ladrones, Sandias, Taos Range, and Sierra Blanca) have AFT ages that range from 35 Ma to <10 Ma, and record cooling that initiated with the Oligocene ignimbrite flare-up and continues through the Neogene. Our analysis tracks the approximate elevation of paleo 110°C isotherms in 10 Ma intervals from the Laramide to the present and shows that reconstructed paleoisotherms have been differentially uplifted, warped, and faulted since their time of formation, and hence serve as markers of uplift history and its mechanisms. AFT data at Ladron Peak, an active rift flank along the western margin of the Rio Grande rift in central New Mexico, indicates that it was rapidly unroofed between 20-10 Ma. Preliminary apatite helium data gives a similar age vs. elevation trend, but apatites have highly radiogenically damaged lattices and hence have corrected closure temperatures tens of degrees higher than AFT ages. The style of faulting at Ladron Peak is unusual because it is bounded by the anomalously low-angle (~15°) Jeter

Preliminary data on boulders at station 6, Apollo 17 landing site

NASA Technical Reports Server (NTRS)

Heiken, G. H.; Butler, P., Jr.; Simonds, C. H.; Phinney, W. C.; Warner, J.; Schmitt, H. H.; Bogard, D. D.; Pearce, W. G.

1973-01-01

A cluster of boulders at Station 6 (Apollo 17 landing site) consists of breccias derived from the North Massif. Three preliminary lithologic units were established, on the basis of photogeologic interpretations; all lithologies identified photogeologically were sampled. Breccia clasts and matrices studied petrographically and chemically fall into two groups by modal mineralogy: (1) low-K Fra Mauro or high basalt composition, consisting of 50-60% modal feldspar, approximately 45% orthopyroxene and 1-7% Fe-Ti oxide; (2) clasts consisting of highland basalt composition, consisting of 70% feldspar, 30% orthopyroxene and olivine and a trace of Fe-Ti oxide.

Electron Impact K-shell Ionization of Atomic Targets

NASA Astrophysics Data System (ADS)

Saha, Bidhan; Basak, Arun K.; Alfaz Uddin, M.; Patoary, A. A. R.

2008-05-01

In spite of considerable progress -both theoretically and experimentally- recently in evaluating accurate K-shell ionization cross sections that play a decisive role for quantitative analyses using (i) electron probe microanalysis, (ii) Auger electron spectroscopy and (iii) electron energy loss spectra, attempts are still continuing to search for a model that can easily generate reliable cross sections for a wide range of energies and for various targets needed for plasma modeling code We report few modifications of the widely used binary encounter approximation (BEA) [1,2] and have tested by evaluating the electron impact K-shell ionization of few neutral targets at various projectile energies. Details will be presented at the meeting. [1] M. Gryziniski, Phys. Rev. A 138, 336 (1965); [2] L. Vriens, Proc. Phys. Soc. (London) 89, 13, (1966). [3M. A. Uddin , A. K. F. Haque, M. M. Billah, A. K. Basak, K, R, Karim and B. C. Saha, ,Phys. Rev. A 71,032715 (2005); [4] M. A. Uddin, A. K. Basak, and B. C. Saha, Int. J. Quan. Chem 100, 184 (2004).

Exhumation history of the Anqing Orefield in the Lower Yangtze River Metallogenic Belt: Evidence from apatite fission-track thermochronology

NASA Astrophysics Data System (ADS)

Li, X.; Yang, X.

2017-12-01

The Lower Yangtze River Metallogenic Belt (LYRMB) is one of the most important Cu-Au-Fe polymetallic belts in China. These deposits along the Yangtze River region have been related to the Yanshanian intrusive rocks in the Mesozoic. The Anqing orefield is located in the northwestern Anqing, southwestern Anhui Province, eastern China, along the Lower Yangtze River Belt. Here, we report new apatite fission-track (AFT) thermochronology of the granitoids ( 130 Ma for zircon U-Pb age) associated with the Anqing orefields to reveal the exhumation history of the Anqing orefields in LYRMB, eastern China. AFT ages from 54.4±2.1 to 63.9±3.4 Ma with mean measured track lengths between 12.4±1.8 and 13.1±1.4 μm, were obtained for the granitoids sampled from the ore fields in the Anqing orefield, and AFT age of 36.3±1.3 Ma with mean track length of 12.3±2.3μm for the granitoids adjacent to the south Tan-Lu fault. A long, slow exhumation ( 60-15 Ma), and a short, rapid tectonic exhumation (15-0 Ma) have been identified in the study region based on the AFT data and modeling results for the samples from the ore fields. The results show that the granitoids underwent roughly similar cooling, and inferred exhumation pattern. Assuming a steady-state paleogeothermal gradient of 35ºC/km founded on geological setting, the exhumations of 570 m and 1140 m, were achieved in the Anqing orefield, during 60-15 Ma and 15-0 Ma, respectively. Further, the AFT age of the granitoids adjacent to the south Tan-Lu fault is less than the AFT ages of the granitoids associated with the ore fields, possibly owing to the activation of the Tan-Lu fault in the Cenozoic. The exhumation history of the Anqing orefields may be closely response to the Pacific Plate subduction in the Cenozoic, which could be implications for the preservation potential of ore bodies in the Anqing orefield. This work is supported by the National Natural Science Foundation of China (41372227), and the DREAM project of MOST

Comparative study of long-term outcomes of accelerated and conventional collagen crosslinking for progressive keratoconus.

PubMed

Males, J J; Viswanathan, D

2018-01-01

PurposeTo compare the long-term outcomes of accelerated corneal collagen crosslinking (CXL) to conventional CXL for progressive keratoconus.Patients and methodsComparative clinical study of consecutive progressive keratoconic eyes that underwent either accelerated CXL (9 mW/cm 2 ultraviolet A (UVA) light irradiance for 10 min) or conventional CXL (3 mW/cm 2 UVA light irradiance for 30 min). Eyes with minimum 12 months' follow-up were included. Post-procedure changes in keratometry readings (Flat meridian: K1; steep meridian: K2), central corneal thickness (CCT), best spectacle-corrected visual acuity (BSCVA), and manifest refraction spherical equivalent (MRSE) were analysed.ResultsA total of 42 eyes were included. In all, 21 eyes had accelerated CXL (20.5±5.5 months' follow-up) and 21 eyes had conventional CXL group (20.2±5.6 months' follow-up). In the accelerated CXL group, a significant reduction in K2 (P=0.02), however no significant change in K1 (P=0.35) and CCT (P=0.62) was noted. In the conventional CXL group, a significant reduction was seen in K1 (P=0.01) and K2 (P=0.04), but not in CCT (P=0.95). Although both groups exhibited significant reductions in K2 readings, no noteworthy differences were noted between them (P=0.36). Improvements in BSCVA (accelerated CXL; P=0.22 and conventional CXL; P=0.20) and MRSE (accelerated CXL; P=0.97 and conventional CXL; P=0.54) were noted, however were not significant in either group.ConclusionAccelerated and conventional CXL appear to be effective procedures for stabilising progressive keratoconus in the long-term.

A Novel Approach to Experimental Studies of Mineral Dissolution Kinetics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen Zhu; William E. Seyfried

2005-01-01

Currently, DOE is conducting pilot CO{sub 2} injection tests to evaluate the concept of geological sequestration. One strategy that potentially enhances CO{sub 2} solubility and reduces the risk of CO{sub 2} leak back to the surface is dissolution of indigenous minerals in the geological formation and precipitation of secondary carbonate phases, which increases the brine pH and immobilizes CO{sub 2}. Clearly, the rates at which these dissolution and precipitation reactions occur directly determine the efficiency of this strategy. However, one of the fundamental problems in modern geochemistry is the persistent two to five orders of magnitude discrepancy between laboratory-measured andmore » field derived feldspar dissolution rates. To date, there is no real guidance as to how to predict silicate reaction rates for use in quantitative models. Current models for assessment of geological carbon sequestration have generally opted to use laboratory rates, in spite of the dearth of such data for compositionally complex systems, and the persistent disconnect between lab and field applications. Therefore, a firm scientific basis for predicting silicate reaction kinetics in CO{sub 2} injected geological formations is urgently needed to assure the reliability of the geochemical models used for the assessments of carbon sequestration strategies. The funded experimental and theoretical study attempts to resolve this outstanding scientific issue by novel experimental design and theoretical interpretation to measure silicate dissolution rates and iron carbonate precipitation rates at conditions pertinent to geological carbon sequestration. In the first year of the project, we have successfully developed a sample preparation method and completed three batch feldspar dissolution experiments at 200 C and 300 bars. The changes of solution chemistry as dissolution experiments progressed were monitored with on-line sampling of the aqueous phase at the constant temperature and

Strife and Progress: Portfolio Strategies for Managing Urban Schools

ERIC Educational Resources Information Center

Campbell, Christine; Gross, Betheny; Hill, Paul T.

2012-01-01

Deficient urban schooling remains one of America's most pressing--and stubborn--public policy problems. This important new book details and evaluates a radical and promising new approach to K-12 education reform. "Strife and Progress" explains for a broad audience the "portfolio strategy" for providing urban education--its…

Thermochronological evolution of an intra-plate magmatic event inferred from an integrated modeling approach: A case study in the Westerwald, Germany

NASA Astrophysics Data System (ADS)

Tirone, M.; Rokitta, K.; Schreiber, U.

2016-09-01

A lava sample from the Tertiary Westerwald volcanic field was selected for a detailed study using various analytical techniques in combination with petrological, thermodynamic and diffusion modeling to extract information related to the thermochronological evolution of a magmatic event before eruption. The lava sample contains large olivine phenocrysts which are compositionally zoned and two coexisting but chemically distinct melts, a host melt with basaltic composition and small spherical pockets of a less abundant trachytic melt (globules). The sample was analyzed by electron microprobe, x-ray fluorescence (XRF) X-ray diffraction (XRD) and electron backscatter diffraction (EBSD). The primary melt of the host lava was determined using the program PRIMELT2.XLS. Partial fractional crystallization of olivine was modeled using the program alphaMELTS. Timescale and cooling rate were retrieved by fitting the measured Fe-Mg zoning along two directions in four olivine grains from the host lava using a 3-D numerical diffusion model. The measured variation of Ca is also consistent with a chemical diffusion process, while a numerical growth model applied to the same olivines does not appear to explain the Fe-Mg zoning. Chemical zoning of major elements in the melt globules were reproduced with a multicomponent diffusion model. The results of this study show that the host magma fractionated about 9% of olivine in a first stage, then the crystallization proceeded without further separation of mineral phases. Modeling of diffusion in the olivine crystals suggests that this second stage lasted at least 5 yrs and the temperature of the melt decreased from 1120-1150 °C to 1090 °C during this time. According to the results of the multicomponent diffusion model applied to the melt globules, the coexistence of the two melts was extremely short (less than few hours), possibly recording the assimilation of the globules during eruption or cooling of the whole system on the surface.

miR-489 inhibits proliferation, cell cycle progression and induces apoptosis of glioma cells via targeting SPIN1-mediated PI3K/AKT pathway.

PubMed

Li, Yan; Ma, Xiaolin; Wang, Yanpeng; Li, Guohua

2017-09-01

microRNA-489 (miR-489), a newly identified tumor-related miRNA, functions as an oncogene or tumor suppressor via regulating growth and metastasis of human cancers. But, the clinical significance, biological function and underlying mechanisms of miR-489 in glioma remain rarely known. Here, we showed that the levels of miR-489 in glioma tissues were notably underexpressed compared to corresponding non-tumor tissues. In accordance, the relative levels of miR-489 were decreased in glioma cell lines compared with NHA cells. Kaplan-Meier plots indicated that miR-489 low expressing glioma patients showed a prominent shorter overall survival. In addition, miR-489 overexpression prohibited proliferation and cell cycle progression, and promoted apoptosis in U251 cells. While, miR-489 knockdown showed opposite effects on these cellular processes of U87 cells. In vivo experiments demonstrated that miR-489 restoration reduced the tumor volume and weight of subcutaneous glioma xenografts in nude mice. Notably, Spindlin 1 (SPIN1) was inversely and directly regulated by miR-489 in glioma cells. A negative correlation between the expression of miR-489 and SPIN1 mRNA was confirmed in glioma tissues. Interestingly, miR-489 inversely modulated activation of PI3K/AKT pathway and expression of downstream targets including p-mTOR, Cyclin D1 and BCL-XL. SPIN1 re-expression abolished the effects of miR-489 on U251 cells with enhanced activation of PI3K/AKT pathway and malignant phenotype. Meanwhile, AKT inhibitor MK-2206 blocked activation of PI3K/AKT pathway and resulted in reduced proliferation, cell cycle arrest and increased apoptosis in miR-489 down-regulating U87 cells. Altogether, our data support that miR-489 loss facilitates malignant phenotype of glioma cells probably via SPIN1-mediated PI3K/AKT pathway. Copyright © 2017 Elsevier Masson SAS. All rights reserved.

Evaluation of simple geochemical indicators of aeolian sand provenance: Late Quaternary dune fields of North America revisited

USGS Publications Warehouse

Muhs, Daniel

2017-01-01

Dune fields of Quaternary age occupy large areas of the world's arid and semiarid regions. Despite this, there has been surprisingly little work done on understanding dune sediment provenance, in part because many techniques are time-consuming, prone to operator error, experimental, highly specialized, expensive, or require sophisticated instrumentation. Provenance of dune sand using K/Rb and K/Ba values in K-feldspar in aeolian sands of the arid and semiarid regions of North America is tested here. Results indicate that K/Rb and K/Ba can distinguish different river sands that are sediment sources for dunes and dune fields themselves have distinctive K/Rb and K/Ba compositions. Over the Basin and Range and Great Plains regions of North America, the hypothesized sediment sources of dune fields are reviewed and assessed using K/Rb and K/Ba values in dune sands and in hypothesized source sediments. In some cases, the origins of dunes assessed in this manner are consistent with previous studies and in others, dune fields are found to have a more complex origin than previously thought. Use of K/Rb and K/Ba for provenance studies is a robust method that is inexpensive, rapid, and highly reproducible. It exploits one of the most common minerals found in dune sand, K-feldspar. The method avoids the problem of using simple concentrations of key elements that may be subject to interpretative bias due to changes in mineralogical maturity of Quaternary dune fields that occur over time.

Cross Sections for the Reactions e+e to K+ K- pi+pi-, K+ K- pi0pi0, and K+ K- K+ K- Measured Using Initial-State Radiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lees, J.P.; Poireau, V.; Prencipe, E.

2011-08-19

We study the processes e{sup +}e{sup -} {yields} K{sup +}K{sup -}{pi}{sup +}{pi}-{gamma}, K{sup +}K{sup -}{pi}{sup 0}{pi}{sup 0}{gamma}, and K{sup +}K{sup -}K{sup +}K{sup -}{gamma}, where the photon is radiated from the initial state. About 84000, 8000, and 4200 fully reconstructed events, respectively, are selected from 454 fb{sup -1} of BABAR data. The invariant mass of the hadronic final state defines the e{sup +}e{sup -} center-of-mass energy, so that the K{sup +}K{sup -}{pi}{sup +}{pi}{sup -}{gamma} data can be compared with direct measurements of the e{sup +}e{sup -} {yields} K{sup +}K{sup -}{pi}{sup +}{pi}{sup -} reaction. No direct measurements exist for the e{sup +}e{supmore » -} {yields} K{sup +}K{sup -}{pi}{sup 0}{pi}{sup 0} or e{sup +}e{sup -} {yields} K{sup +}K{sup -}K{sup +}K{sup -} reactions, and we present an update of our previous result with doubled statistics. Studying the structure of these events, we find contributions from a number of intermediate states, and extract their cross sections. In particular, we perform a more detailed study of the e{sup +}e{sup -} {yields} {phi}(1020){pi}{pi}{gamma} reaction, and confirm the presence of the Y (2175) resonance in the {phi}(1020)f{sub 0}(980) and K{sup +}K{sup -} f{sub 0}(980) modes. In the charmonium region, we observe the J/{psi} in all three final states and in several intermediate states, as well as the {phi}(2S) in some modes, and measure the corresponding branching fractions.« less

Recent cryocooler progress in Japan

NASA Technical Reports Server (NTRS)

Matsubara, Y.

1985-01-01

The progress of cryocoolers and related devices in Japan is reviewed. The Japanese National Railways has developed the light weight 4 K on-board refrigerators since 1977 as part of the MAGLEV train program. Superconducting and cryogenic fundamental technology was examined which included high performance cryocooler, magnetic refrigerator and superfluid refrigeration. Space cryogenics such as the cooling systems of IR-detectors was studied. Cryocooler for special applications such as cryopump, NMR-CT and JJ devices was investigated. Compact heat exchangers, high performance regenerators and reliable compressors are investigated as a critical component technology.

Small Quaternary Inhibitors K298 and K524: Cholinesterases Inhibition, Absorption, Brain Distribution, and Toxicity.

PubMed

Karasova, Jana Zdarova; Hroch, Milos; Musilek, Kamil; Kuca, Kamil

2016-02-01

Inhibitors of acetylcholinesterase (AChE) may be used in the treatment of various cholinergic deficits, among them being myasthenia gravis (MG). This paper describes the first in vivo data for promising small quaternary inhibitors (K298 and K524): acute toxicity study, cholinesterase inhibition, absorption, and blood-brain barrier penetration. The newly prepared AChE inhibitors (bis-quinolinium and quinolinium compounds) possess a positive charge in the molecule which ensures that anti-AChE action is restricted to peripheral effect. HPLC-MS was used for determination of real plasma and brain concentration in the pharmacokinetic part of the study, and standard non-compartmental analysis was performed. The maximum plasma concentrations were attained at 30 min (K298; 928.76 ± 115.20 ng/ml) and 39 min (K524; 812.40 ± 54.96 ng/ml) after i.m. Both compounds are in fact able to target the central nervous system. It seems that the difference in the CNS distribution profile depends on an active efflux system. The K524 brain concentration was actively decreased to below an effective level; in contrast, K298 progressively accumulated in brain tissue. Peripheral AChE inhibitors are still first-line treatment in the mild forms of MG. Commonly prescribed carbamates have many severe side effects related to AChE carbamylation. The search for new treatment strategies is still important. Unlike carbamates, these new compounds target AChE via apparent π-π or π-cationic interaction aside at the AChE catalytic site.

Cross sections for the reactions e+e-→K+K-π+π-, K+K-π0π0, and K+K-K+K- measured using initial-state radiation events

NASA Astrophysics Data System (ADS)

Lees, J. P.; Poireau, V.; Prencipe, E.; Tisserand, V.; Garra Tico, J.; Grauges, E.; Martinelli, M.; Milanes, D. A.; Palano, A.; Pappagallo, M.; Eigen, G.; Stugu, B.; Sun, L.; Brown, D. N.; Kerth, L. T.; Kolomensky, Yu. G.; Lynch, G.; Koch, H.; Schroeder, T.; Asgeirsson, D. J.; Hearty, C.; Mattison, T. S.; McKenna, J. A.; Khan, A.; Blinov, V. E.; Buzykaev, A. R.; Druzhinin, V. P.; Golubev, V. B.; Kravchenko, E. A.; Onuchin, A. P.; Serednyakov, S. I.; Skovpen, Yu. I.; Solodov, E. P.; Todyshev, K. Yu.; Yushkov, A. N.; Bondioli, M.; Curry, S.; Kirkby, D.; Lankford, A. J.; Mandelkern, M.; Stoker, D. P.; Atmacan, H.; Gary, J. W.; Liu, F.; Long, O.; Vitug, G. M.; Campagnari, C.; Hong, T. M.; Kovalskyi, D.; Richman, J. D.; West, C. A.; Eisner, A. M.; Kroseberg, J.; Lockman, W. S.; Martinez, A. J.; Schalk, T.; Schumm, B. A.; Seiden, A.; Cheng, C. H.; Doll, D. A.; Echenard, B.; Flood, K. T.; Hitlin, D. G.; Ongmongkolkul, P.; Porter, F. C.; Rakitin, A. Y.; Andreassen, R.; Dubrovin, M. S.; Meadows, B. T.; Sokoloff, M. D.; Bloom, P. C.; Ford, W. T.; Gaz, A.; Nagel, M.; Nauenberg, U.; Smith, J. G.; Wagner, S. R.; Ayad, R.; Toki, W. H.; Spaan, B.; Kobel, M. J.; Schubert, K. R.; Schwierz, R.; Bernard, D.; Verderi, M.; Clark, P. J.; Playfer, S.; Watson, J. E.; Bettoni, D.; Bozzi, C.; Calabrese, R.; Cibinetto, G.; Fioravanti, E.; Garzia, I.; Luppi, E.; Munerato, M.; Negrini, M.; Piemontese, L.; Baldini-Ferroli, R.; Calcaterra, A.; de Sangro, R.; Finocchiaro, G.; Nicolaci, M.; Pacetti, S.; Patteri, P.; Peruzzi, I. M.; Piccolo, M.; Rama, M.; Zallo, A.; Contri, R.; Guido, E.; Lo Vetere, M.; Monge, M. R.; Passaggio, S.; Patrignani, C.; Robutti, E.; Bhuyan, B.; Prasad, V.; Lee, C. L.; Morii, M.; Edwards, A. J.; Adametz, A.; Marks, J.; Uwer, U.; Bernlochner, F. U.; Ebert, M.; Lacker, H. M.; Lueck, T.; Dauncey, P. D.; Tibbetts, M.; Behera, P. K.; Mallik, U.; Chen, C.; Cochran, J.; Crawley, H. B.; Meyer, W. T.; Prell, S.; Rosenberg, E. I.; Rubin, A. E.; Gritsan, A. V.; Guo, Z. J.; Arnaud, N.; Davier, M.; Derkach, D.; Grosdidier, G.; Le Diberder, F.; Lutz, A. M.; Malaescu, B.; Roudeau, P.; Schune, M. H.; Stocchi, A.; Wormser, G.; Lange, D. J.; Wright, D. M.; Bingham, I.; Chavez, C. A.; Coleman, J. P.; Fry, J. R.; Gabathuler, E.; Hutchcroft, D. E.; Payne, D. J.; Touramanis, C.; Bevan, A. J.; Di Lodovico, F.; Sacco, R.; Sigamani, M.; Cowan, G.; Paramesvaran, S.; Brown, D. N.; Davis, C. L.; Denig, A. G.; Fritsch, M.; Gradl, W.; Hafner, A.; Alwyn, K. E.; Bailey, D.; Barlow, R. J.; Jackson, G.; Lafferty, G. D.; Cenci, R.; Hamilton, B.; Jawahery, A.; Roberts, D. A.; Simi, G.; Dallapiccola, C.; Salvati, E.; Cowan, R.; Dujmic, D.; Sciolla, G.; Lindemann, D.; Patel, P. M.; Robertson, S. H.; Schram, M.; Biassoni, P.; Lazzaro, A.; Lombardo, V.; Palombo, F.; Stracka, S.; Cremaldi, L.; Godang, R.; Kroeger, R.; Sonnek, P.; Summers, D. J.; Nguyen, X.; Taras, P.; De Nardo, G.; Monorchio, D.; Onorato, G.; Sciacca, C.; Raven, G.; Snoek, H. L.; Jessop, C. P.; Knoepfel, K. J.; LoSecco, J. M.; Wang, W. F.; Honscheid, K.; Kass, R.; Brau, J.; Frey, R.; Sinev, N. B.; Strom, D.; Torrence, E.; Feltresi, E.; Gagliardi, N.; Margoni, M.; Morandin, M.; Posocco, M.; Rotondo, M.; Simonetto, F.; Stroili, R.; Ben-Haim, E.; Bomben, M.; Bonneaud, G. R.; Briand, H.; Calderini, G.; Chauveau, J.; Hamon, O.; Leruste, Ph.; Marchiori, G.; Ocariz, J.; Sitt, S.; Biasini, M.; Manoni, E.; Rossi, A.; Angelini, C.; Batignani, G.; Bettarini, S.; Carpinelli, M.; Casarosa, G.; Cervelli, A.; Forti, F.; Giorgi, M. A.; Lusiani, A.; Neri, N.; Oberhof, B.; Paoloni, E.; Perez, A.; Rizzo, G.; Walsh, J. J.; Lopes Pegna, D.; Lu, C.; Olsen, J.; Smith, A. J. S.; Telnov, A. V.; Anulli, F.; Cavoto, G.; Faccini, R.; Ferrarotto, F.; Ferroni, F.; Gaspero, M.; Li Gioi, L.; Mazzoni, M. A.; Piredda, G.; Bünger, C.; Hartmann, T.; Leddig, T.; Schröder, H.; Waldi, R.; Adye, T.; Olaiya, E. O.; Wilson, F. F.; Emery, S.; Hamel de Monchenault, G.; Vasseur, G.; Yèche, Ch.; Aston, D.; Bard, D. J.; Bartoldus, R.; Benitez, J. F.; Cartaro, C.; Convery, M. R.; Dorfan, J.; Dubois-Felsmann, G. P.; Dunwoodie, W.; Field, R. C.; Franco Sevilla, M.; Fulsom, B. G.; Gabareen, A. M.; Graham, M. T.; Grenier, P.; Hast, C.; Innes, W. R.; Kelsey, M. H.; Kim, H.; Kim, P.; Kocian, M. L.; Leith, D. W. G. S.; Lewis, P.; Li, S.; Lindquist, B.; Luitz, S.; Luth, V.; Lynch, H. L.; MacFarlane, D. B.; Muller, D. R.; Neal, H.; Nelson, S.; Ofte, I.; Perl, M.; Pulliam, T.; Ratcliff, B. N.; Roodman, A.; Salnikov, A. A.; Santoro, V.; Schindler, R. H.; Snyder, A.; Su, D.; Sullivan, M. K.; Va'vra, J.; Wagner, A. P.; Weaver, M.; Wisniewski, W. J.; Wittgen, M.; Wright, D. H.; Wulsin, H. W.; Yarritu, A. K.; Young, C. C.; Ziegler, V.; Park, W.; Purohit, M. V.; White, R. M.; Wilson, J. R.; Randle-Conde, A.; Sekula, S. J.; Bellis, M.; Burchat, P. R.; Miyashita, T. S.; Alam, M. S.; Ernst, J. A.; Gorodeisky, R.; Guttman, N.; Peimer, D. R.; Soffer, A.; Lund, P.; Spanier, S. M.; Eckmann, R.; Ritchie, J. L.; Ruland, A. M.; Schilling, C. J.; Schwitters, R. F.; Wray, B. C.; Izen, J. M.; Lou, X. C.; Bianchi, F.; Gamba, D.; Lanceri, L.; Vitale, L.; Lopez-March, N.; Martinez-Vidal, F.; Oyanguren, A.; Ahmed, H.; Albert, J.; Banerjee, Sw.; Choi, H. H. F.; King, G. J.; Kowalewski, R.; Lewczuk, M. J.; Lindsay, C.; Nugent, I. M.; Roney, J. M.; Sobie, R. J.; Gershon, T. J.; Harrison, P. F.; Latham, T. E.; Puccio, E. M. T.; Band, H. R.; Dasu, S.; Pan, Y.; Prepost, R.; Vuosalo, C. O.; Wu, S. L.

2012-07-01

We study the processes e+e-→K+K-π+π-γ, K+K-π0π0γ, and K+K-K+K-γ, where the photon is radiated from the initial state. About 84 000, 8000, and 4200 fully reconstructed events, respectively, are selected from 454fb-1 of BABAR data. The invariant mass of the hadronic final state defines the e+e- center-of-mass energy, so that the K+K-π+π-γ data can be compared with direct measurements of the e+e-→K+K-π+π- reaction. No direct measurements exist for the e+e-→K+K-π0π0 or e+e-→K+K-K+K- reactions, and we present an update of our previous result based on a data sample that is twice as large. Studying the structure of these events, we find contributions from a number of intermediate states and extract their cross sections. In particular, we perform a more detailed study of the e+e-→ϕ(1020)ππγ reaction and confirm the presence of the Y(2175) resonance in the ϕ(1020)f0(980) and K+K-f0(980) modes. In the charmonium region, we observe the J/ψ in all three final states and in several intermediate states, as well as the ψ(2S) in some modes, and measure the corresponding products of branching fraction and electron width.

Progress on the Cluster Mission

NASA Technical Reports Server (NTRS)

Kivelson, Margaret; Khurana, Krishan; Acuna, Mario (Technical Monitor)

2002-01-01

Prof M. G. Kivelson and Dr. K. K. Khurana (UCLA (University of California, Los Angeles)) are co-investigators on the Cluster Magnetometer Consortium (CMC) that provided the fluxgate magnetometers and associated mission support for the Cluster Mission. The CMC designated UCLA as the site with primary responsibility for the inter-calibration of data from the four spacecraft and the production of fully corrected data critical to achieving the mission objectives. UCLA will also participate in the analysis and interpretation of the data. The UCLA group here reports its excellent progress in developing fully intra-calibrated data for large portions of the mission and an excellent start in developing inter-calibrated data for selected time intervals, especially extended intervals in August, 2001 on which a workshop held at ESTEC in March, 2002 focused. In addition, some scientific investigations were initiated and results were reported at meetings.

Myositis autoantibodies in Korean patients with inflammatory myositis: Anti-140-kDa polypeptide antibody is primarily associated with rapidly progressive interstitial lung disease independent of clinically amyopathic dermatomyositis

PubMed Central

2010-01-01

Background To investigate the association between myositis autoantibodies and clinical subsets of inflammatory myositis in Korean patients. Methods Immunoprecipitation was performed using the sera of classic polymyositis (PM) (n = 11) and dermatomyositis (DM) (n = 38) patients who met the Bohan and Peter criteria for definite inflammatory myositis. A panel of defined myositis autoantibodies was surveyed to investigate the association between each autoantibody and clinical subsets of inflammatory myositis. Results Either MSAs, anti-p140, or anti-p155/140 antibodies were found in 63.3% (31/49) of the study subjects. Anti-140-kDa-polypeptide (anti-p140) (18.4%, 9/49) and anti-155/140-kDa polypeptide (anti-p155/140) (16.3%, 8/49) antibodies were the most common, followed by anti-Mi2 (14.3%, 7/49), anti-ARS (12.2%, 6/49) and anti-SRP (2.0%, 1/49) antibodies. All MSAs and anti-p140 and anti-p155/140 antibodies were mutually exclusive. Anti-p140 (23.7%, 9/38), anti-p155/140 (21.1%, 8/38), and anti-Mi2 (18.4%, 3/38) antibodies were found exclusively in DM patients. Anti-p140 antibody was associated with rapidly progressive interstitial lung disease (ILD) (p = 0.001), with a sensitivity of 100.0% (4/4) and a specificity of 85.3% (29/34) in DM patients. Anti-p155/140 antibody was associated with cancer-associated DM (p = 0.009), with a sensitivity of 55.6% (5/9) and a specificity of 89.7% (26/29). Cancer-associated survival was significantly worse when anti-p155/140 antibody was present (19.2 ± 7.6 vs. 65.0 ± 3.5 months, p = 0.032). Finally, anti-ARS antibodies were associated with stable or slowly progressive ILD in PM and DM patients (p = 0.005). Conclusions Anti-p140 and anti-p155/140 antibodies were commonly found autoantibodies in Korean patients with inflammatory myositis. Despite the lack of clinically amyopathic DM patients in the study subjects, a strong association was observed between anti-p140 antibody and rapidly progressive ILD. Anti-p155/140 antibody was

Myositis autoantibodies in Korean patients with inflammatory myositis: anti-140-kDa polypeptide antibody is primarily associated with rapidly progressive interstitial lung disease independent of clinically amyopathic dermatomyositis.

PubMed

Kang, Eun Ha; Nakashima, Ran; Mimori, Tsuneyo; Kim, Jinhyun; Lee, Yun Jong; Lee, Eun Bong; Song, Yeong Wook

2010-09-28

To investigate the association between myositis autoantibodies and clinical subsets of inflammatory myositis in Korean patients. Immunoprecipitation was performed using the sera of classic polymyositis (PM) (n = 11) and dermatomyositis (DM) (n = 38) patients who met the Bohan and Peter criteria for definite inflammatory myositis. A panel of defined myositis autoantibodies was surveyed to investigate the association between each autoantibody and clinical subsets of inflammatory myositis. Either MSAs, anti-p140, or anti-p155/140 antibodies were found in 63.3% (31/49) of the study subjects. Anti-140-kDa-polypeptide (anti-p140) (18.4%, 9/49) and anti-155/140-kDa polypeptide (anti-p155/140) (16.3%, 8/49) antibodies were the most common, followed by anti-Mi2 (14.3%, 7/49), anti-ARS (12.2%, 6/49) and anti-SRP (2.0%, 1/49) antibodies. All MSAs and anti-p140 and anti-p155/140 antibodies were mutually exclusive. Anti-p140 (23.7%, 9/38), anti-p155/140 (21.1%, 8/38), and anti-Mi2 (18.4%, 3/38) antibodies were found exclusively in DM patients. Anti-p140 antibody was associated with rapidly progressive interstitial lung disease (ILD) (p = 0.001), with a sensitivity of 100.0% (4/4) and a specificity of 85.3% (29/34) in DM patients. Anti-p155/140 antibody was associated with cancer-associated DM (p = 0.009), with a sensitivity of 55.6% (5/9) and a specificity of 89.7% (26/29). Cancer-associated survival was significantly worse when anti-p155/140 antibody was present (19.2 ± 7.6 vs. 65.0 ± 3.5 months, p = 0.032). Finally, anti-ARS antibodies were associated with stable or slowly progressive ILD in PM and DM patients (p = 0.005). Anti-p140 and anti-p155/140 antibodies were commonly found autoantibodies in Korean patients with inflammatory myositis. Despite the lack of clinically amyopathic DM patients in the study subjects, a strong association was observed between anti-p140 antibody and rapidly progressive ILD. Anti-p155/140 antibody was associated with cancer-associated myositis

Progress of gas-insulated transformers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Togawa, Y.; Ikeda, M.; Toda, K.

The world`s first transformer was manufactured at Ganz in Hungary in 1885. Two years later in 1887 patents applications were made for about oil immersed transformers in the US. Since then, oil immersed types have predominated for medium- and large-capacity transformers, which are now giving way to gas insulated transformers in some areas. Behind such trends are plans to construct substations inside buildings or underground, because of the difficulty in acquiring land for substations in large cities where power demand is concentrated. Requirements are protection against accidents, compactness and overall economy. Total gas insulated substations combining GIS units and gasmore » insulated transformers these needs. Demand for gas insulated transformers has been increasing rapidly, particularly in Japan and Hong Kong. First, relatively small-capacity models below 20--30 MVA were put into practical use and today 275 kV, 300 MVa models are in use and 500kV, 1,500 MVA models are coming into use. Engineering is progressing very rapidly in these areas. This paper describes the design techniques and important maintenance techniques for the latest gas insulated transformers from 5,000 kVA to 300 MVA.« less

A Learning Progression for Energy in Socio-Ecological Systems

ERIC Educational Resources Information Center

Jin, Hui; Anderson, Charles W.

2012-01-01

This article reports on our work of developing a learning progression focusing on K-12 students' performances of using energy concept in their accounts of carbon-transforming processes in socio-ecological systems. Carbon-transforming processes--the ecological carbon cycle and the combustion of biomass and fossil fuels--provide all of the energy…

EDITORIAL: Catalysing progress Catalysing progress

NASA Astrophysics Data System (ADS)

Demming, Anna

2010-01-01

procedures. One man who was well aware of the role of nanostructured catalysts in the progress of material science research was the late Ulrich Gösele, director at the Max-Planck-Institut für Mikrostrukturphysik Halle, who passed away at the age of 60 on 8 November, 2009. Ulrich Gösele published over 750 papers of premium calibre research that have collectively been cited over 20,000 times. His research output includes a cornucopia of excellent work published in Nanotechnology, amongst which are a number of papers detailing the deft manipulation of nanocatalysts to control the quality and structure of nanomaterials [5-8]. Ulrich Gösele was a pioneer in nanoscience. In 1991, when the nanotechnology revolution was little more than a portentous rumble, he published a seminal report examining the effect of quantum confinement on the optical properties of silicon nanowires [9]. While we lament the loss to the community, we have much to celebrate in the insights his legacy has provided for the progress of materials science. It would be unwise to assume that science will or can ultimately advance in such a way as to allow ample means to indulge an unrestrained appetite for consumerism and energy consumption. As with most things, a balanced approach, considering solutions to the problem from many angles, seems sensible. Nonetheless, a browse through the latest literature leaves much cause for optimism for the positive role science can play in improving and sustaining our lifestyle. References [1] Mukherjee P, Roy M, Mandal B P, Dey G K, Mukherjee P K, Ghatak J, Tyagi A K and Kale S P 2008 Nanotechnology 19 075103 [2] Greenham N C and Grätzel M 2008 Nanotechnology 19 420201 [3] Vajo J, Pinkerton F and Stetson N 2009 Nanotechnology 20 200201 [4] Zhong C-J, Luo J, Fang B, Wanjala B N, Njoki P N, Loukrakpam R and Yin J 2010 Nanotechnology 21 062001 [5] Sivakov V A, Scholz A, Syrowatka F, Falk F, Gösele U and Christiansen S H 2009 Nanotechnology 20 405607 [6] Liu L, Lee W, Huang Z

Progression from Mild Cognitive Impairment to Alzheimer's disease: effects of gender, butyrylcholinesterase genotype and rivastigmine treatment

PubMed Central

Ferris, Steven; Nordberg, Agneta; Soininen, Hilkka; Darreh-Shori, Taher; Lane, Roger

2014-01-01

Objective Evaluate the influence of gender and butyrylcholinesterase (BuChE) genotype on incidence of progression to AD, rate of cognitive and functional decline, and response to rivastigmine treatment in mild cognitive impairment (MCI) subjects. Methods This retrospective exploratory analysis from a 3–4 year, randomized, placebo-controlled study of rivastigmine in MCI subjects included participants who consented to pharmacogenetic testing. Results Of 1018 total patients, 490 (253 [52%] female) were successfully genotyped for BuChE. In subjects receiving placebo, the BuChE wt/wt genotype was associated with a statistically significantly higher rate of progression to AD and functional decline in women, compared with men with the BuChE wt/wt genotype. In subjects with a BuChE-K allele receiving placebo, incidence of progression to AD and rate of functional decline were not significantly different by gender, however cognitive decline was significantly faster in men. Statistically significant benefits of rivastigmine treatment on progression to AD, functional decline, ventricular volume expansion, whole brain atrophy and white matter loss were evident in female BuChE wt/wt. Conclusion Gender appears to differentially influence the type of decline in MCI subjects according to BuChE genotype, with more rapid progression of cognitive decline in male BuChE-K, and more rapid progression to AD and functional decline in female BuChE wt/wt. Cognitive decline in male BuChE-K and functional decline and progression to AD in female BuChE wt/wt were significantly attenuated by rivastigmine. Rivastigmine treatment also significantly reduced ventricular expansion, whole brain atrophy rate and white matter loss in female BuChE wt/wt, suggesting a possible disease-modifying effect. PMID:19617863

Selectivity and permeation of alkali metal ions in K+-channels.

PubMed

Furini, Simone; Domene, Carmen

2011-06-24

Ion conduction in K(+)-channels is usually described in terms of concerted movements of K(+) progressing in a single file through a narrow pore. Permeation is driven by an incoming ion knocking on those ions already inside the protein. A fine-tuned balance between high-affinity binding and electrostatic repulsive forces between permeant ions is needed to achieve efficient conduction. While K(+)-channels are known to be highly selective for K(+) over Na(+), some K(+) channels conduct Na(+) in the absence of K(+). Other ions are known to permeate K(+)-channels with a more moderate preference and unusual conduction features. We describe an extensive computational study on ion conduction in K(+)-channels rendering free energy profiles for the translocation of three different alkali ions and some of their mixtures. The free energy maps for Rb(+) translocation show at atomic level why experimental Rb(+) conductance is slightly lower than that of K(+). In contrast to K(+) or Rb(+), external Na(+) block K(+) currents, and the sites where Na(+) transport is hindered are characterized. Translocation of K(+)/Na(+) mixtures is energetically unfavorable owing to the absence of equally spaced ion-binding sites for Na(+), excluding Na(+) from a channel already loaded with K(+). Copyright © 2011 Elsevier Ltd. All rights reserved.

Study of the D K K and D K K ¯ systems

NASA Astrophysics Data System (ADS)

Debastiani, V. R.; Dias, J. M.; Oset, E.

2017-07-01

Using the fixed center approximation to Faddeev equations, we investigate the D K K and D K K ¯ three-body systems, considering that the D K dynamically generates, through its I =0 component, the Ds0 *(2317 ) molecule. According to our findings, for the D K K ¯ interaction we find evidence of a state I (JP)=1 /2 (0-) just above the Ds0 *(2317 )K ¯ threshold and around the D f0(980 ) threshold, with mass of about 2833-2858 MeV, made mostly of D f0(980 ). On the other hand, no evidence related to a state from the D K K interaction is found. The state found could be seen in the π π D invariant mass.

Current Status and Future Prospect of K-NET and KiK-net

NASA Astrophysics Data System (ADS)

Aoi, S.; Kunugi, T.; Suzuki, W.; Nakamura, H.; Fujiwara, H.

2014-12-01

During 18 years since the deployment of K-NET following the Kobe earthquake, our attention has mainly focused on rapidity of the data collection and an unfailing and reliable observation. In this presentation, we review three generations of the instruments employed by K-NET and KiK-net from these two points of view.At beginning of the 2000's, we newly developed the second generation instruments (K-NET02, K-NET02A, KiK-net06) to replace the first generation instruments (K-NET95, SMAC-MDK) employed when the networks were constructed in the 1990's. These instruments have an automatic dial-out function. It takes typically 2-5 s to establish communication and a few seconds to send the pre-trigger data. After that, data is available typically within a 1.5 s delay. Not only waveform data but also strong motion indexes such as real-time intensity, PGA, PGV, PGD, and response spectra are continuously sent once a second.After the 2011 Tohoku earthquake, we have developed the third generation instruments (K-NET11, KiK-net11) and have replaced almost half of the all stations country wide. Main improvement of this instrument is more unfailing and reliable observation. Because we have often experienced very large ground motions (e.g. 45 records exceeding gravity), the maximum measureable range was expanded from 2000 gal to 4000 gal for the second generation instrument, and to 8000 gal for the third. For the third generation instrument, in case of power failure, observation (including transmission of data) works for seven days thanks to the backup battery, while for the second generation instruments it works only for one day. By adding an oblique component to the three-component accelerometers, we could automatically distinguish shaking data from noise such as electric pulses which may cause a false alarm in EEW. Implementation to guarantee the continuity of observation under severe conditions such as during the Tohoku earthquake is very important, as well as a highly efficient

Radiation damage-He diffusivity models applied to deep-time thermochronology: Zircon and titanite (U-Th)/He datasets from cratonic settings

NASA Astrophysics Data System (ADS)

Guenthner, W.; DeLucia, M. S.; Marshak, S.; Reiners, P. W.; Drake, H.; Thomson, S.; Ault, A. K.; Tillberg, M.

2017-12-01

Advances in understanding the effects of radiation damage on He diffusion in uranium-bearing accessory minerals have shown the utility of damage-diffusivity models for interpreting datasets from geologic settings with long-term, low-temperature thermal histories. Craton interiors preserve a billion-year record of long-term, long-wavelength vertical motions of the lithosphere. Prior thermochronologic work in these settings has focused on radiation damage models used in conjunction with apatite (U-Th)/He dates to constrain Phanerozoic thermal histories. Owing to the more complex damage-diffusivity relationship in zircon, the zircon (U-Th)/He system yields both higher and, in some cases, lower temperature sensitivities than the apatite system, and this greater range in turn allows researchers to access deeper time (i.e., Proterozoic) segments of craton time-temperature histories. Here, we show two examples of this approach by focusing on zircon (U-Th)/He datasets from 1.8 Ga granitoids of the Fennoscandian Shield in southeastern Sweden, and 1.4 Ga granites and rhyolites of the Ozark Plateau in southeastern Missouri. In the Ozark dataset, the zircon (U-Th)/He data, combined with a damage-diffusivity model, predict negative correlations between date and effective uranium (eU) concentration (a measurement proportional to radiation damage) from thermal histories that include an episode of Proterozoic cooling (interpreted as exhumation) following reheating (interpreted as burial) to temperature of 260°C at 850-680 Ma. In the Fennoscandian Shield, a similar damage model-based approach yields time-temperature constraints with burial to 217°C between 944 Ma and 851 Ma, followed by exhumation from 850 to 500 Ma, and burial to 154°C between 366 Ma and 224 Ma. Our Fennoscandian Shield samples also include titanite (U-Th)/He dates that span a wide range (945-160 Ma) and are negatively correlated with eU concentration, analogous to our zircon He dataset. These results support

Research progress on the anticancer effects of vitamin K2.

PubMed

Xv, Fan; Chen, Jiepeng; Duan, Lili; Li, Shuzhuang

2018-06-01

Despite the availability of multiple therapeutic methods for patients with cancer, the long-term prognosis is not satisfactory in a number of different cancer types. Vitamin K2 (VK2), which exerts anticancer effects on a number of cancer cell lines, is considered to be a prospective novel agent for the treatment of cancer. The present review aims to summarize the results of studies in which VK2 was administered either to patients with cancer or animals inoculated with cancerous cells, particularly investigating the inhibitory effects of VK2 on cancerous cells, primarily involving cell-cycle arrest, cell differentiation, apoptosis, autophagy and invasion. The present review summarizes evidence stating that treatment with VK2 could positively inhibit the growth of cancer cells, making it a potentially useful approach for the prevention and clinical treatment of cancer. Additionally, the combination treatment of VK2 and established chemotherapeutics may achieve better results, with fewer side effects. Therefore, more attention should be paid to the effects of micronutrients on tumors.

Use of Acoustic Emission to Monitor Progressive Damage Accumulation in KEVLAR® 49 Composites

NASA Astrophysics Data System (ADS)

Waller, J. M.; Andrade, E.; Saulsberry, R. L.

2010-02-01

Acoustic emission (AE) data acquired during intermittent load hold tensile testing of epoxy impregnated Kevlar® 49 (K/Ep) composite strands were analyzed to monitor progressive damage during the approach to tensile failure. Insight into the progressive damage of K/Ep strands was gained by monitoring AE event rate and energy. Source location based on energy attenuation and arrival time data was used to discern between significant AE attributable to microstructural damage and spurious AE attributable to noise. One of the significant findings was the observation of increasing violation of the Kaiser effect (Felicity ratio <1.0) with damage accumulation. The efficacy of three different intermittent load hold stress schedules that allowed the Felicity ratio to be determined analytically is discussed.

The Ignition Physics Campaign on NIF: Status and Progress

NASA Astrophysics Data System (ADS)

Edwards, M. J.; Ignition Team

2016-03-01

We have made significant progress in ICF implosion performance on NIF since the 2011 IFSA. Employing a 3-shock, high adiabat CH (“High-Foot”) design, total neutron yields have increased 10-fold to 6.3 x1015 (a yield of ∼ 17 kJ, which is greater than the energy invested in the DT fuel ∼ 12kJ). At that level, the yield from alpha self-heating is essentially equivalent to the compression yield, indicating that we are close to the alpha self-heating regime. Low adiabat, 4-shock High Density Carbon (HDC) capsules have been imploded in conventional gas-filled hohlraums, and employing a 6 ns, 2-shock pulse, HDC capsules were imploded in near-vacuum hohlraums with overall coupling ∼ 98%. Both the 4- and 2-shock HDC capsules had very low mix and high yield over simulated performance. Rugby holraums have demonstrated uniform x-ray drive with minimal Cross Beam Energy Transfer (CBET), and we have made good progress in measuring and modelling growth of ablation front hydro instabilities.

Questioning the Sedimentary Paradigm for Granites

NASA Astrophysics Data System (ADS)

Glazner, A. F.; Bartley, J. M.; Coleman, D. S.; Boudreau, A.; Walker, J. D.

2007-12-01

A critical question regarding volcano-pluton links is whether plutons are samples of magma that passed through on its way to eruption, or residues left behind after volcanic rocks were extracted. A persistent theme of recent work on granites sensu lato is that many are sedimentary accumulations of crystals that lost significant volumes of magmatic liquid. This view is based on observations of structures that clearly seem to reflect deposition on a magma chamber floor (e.g., flows of chilled mafic magma into silicic magma) and on the inference that many other structures, such as modal layering, truncated layering, and crystal accumulations, reflect crystal sedimentation on such chamber floors. There are significant physical and geochemical reasons to question this view, based on observations in the Sierra Nevada of California and similar results from other batholiths. First, few granites show the enrichments in Ba, Sr, and relative Eu that feldspar accumulation should produce. Second, sedimentary features such as graded bedding and cross-bedding form in highly turbulent flows, but turbulence is unachievable in viscous silicic liquids, where velocities on the order of 104 m/s would be required to induce turbulence in a liquid with η=104 Pa s. Third, tabular modally layered domains commonly cut surrounding modal layering on both sides, and orientations of modal layering and of the troughs of "ladder dikes" commonly scatter widely within hectare-sized areas; it is difficult to reconcile these features with gravity-driven settling. Fourth, accumulations of K-feldspar megacrysts are typically inferred to be depositional, but this is precluded by crystallization of most K- feldspar after rheologic lock-up occurs. Finally, accumulations of K-feldspar and hornblende are typically packed too tightly to be depositional. With analogy to layered mafic intrusions, many features attributed to crystal sedimentation in granites may be better explained by crystal aging and other in

Mountain building, strike-slip faulting, and landscape evolution in the Marlborough Fault System, NZ: Insights from new low-temperature thermochronology and modeling

NASA Astrophysics Data System (ADS)

Duvall, A. R.; Collett, C.; Flowers, R. M.; Tucker, G. E.; Upton, P.

2016-12-01

The 150 km wide Marlborough Fault System (MFS) and adjacent dextral-reverse Alpine Fault accommodate oblique convergence of the Australian and Pacific plates in a broad transform boundary that extends for much of the South Island New Zealand. Understanding the deformation history of the Marlborough region offers the opportunity to study topographic evolution in a strike-slip setting and a fuller picture of the evolving New Zealand plate boundary as the MFS lies at the transition from oceanic Pacific plate subduction to oblique continental collision. Here we present low-temperature thermochronology from the MFS to place new limits on the timing and style of mountain building. We sampled a range of elevations spanning 2 km within and adjacent to the Kaikoura Mountains, which stand high as topographic anomalies above active strike-slip faults. Young apatite (U-Th)/He ages ( 2-5 Ma) on both sides of range-bounding faults are consistent with regional distributed deformation since the Pliocene initiation of strike-slip faulting. However, large differences in both zircon helium and apatite fission track ages, from Paleogene/Neogene ages within hanging walls to unreset >100 Ma ages in footwalls, indicate an early phase of fault-related vertical exhumation. Thermal modeling using the QTQt program reveals two phases of exhumation within the Kaikoura Ranges: rapid cooling at 15-12 Ma localized to hanging wall rocks and regional rapid cooling reflected in all samples starting at 4-5 Ma. These results and landscape evolution models suggest that, despite the presence of active mountain front faults, much of the topographic relief in this region may predate the onset of strike-slip faulting and that portions of the Marlborough Faults are re-activated thrusts that coincide with the early development of the transpressive plate boundary. Regional exhumation after 5 Ma likely reflects increased proximity to the migrating Pacific plate subduction zone and the buoyant Chatham Rise.

Inclusions in Minerals: the Importance of Host Mineral Composition, Pressure and Temperature for Potential Inclusion Alteration

NASA Astrophysics Data System (ADS)

Marquardt, K.; Markl, G.

2017-12-01

Inclusions in minerals are used to decipher details of the host mineral/rock history. They frequently originate from the time of mineral formation; be it diamond, garnet or `common' feldspar. Thus protected they survive changing pressure and temperature for different durations compared to their non-enclosed counterparts. Inclusions may (partially) equilibrate at a later point in history, and thus provide complementary information on past processes and alteration pathways less commonly discussed. The study investigates partially altered pyroxene inclusions in feldspars indicative of high-p-T fluid transport during granulite facies metamorphism in charnockites from the Lofoten Islands in Northern Norway. The protoliths formed about 1750 Ma ago, at about 800 - 900°C and 4 kbar. During crustal thickening, they reached high-pressure granulite-facies conditions of about 8-11 kbar at 700°C (1). While this event caused large magmatic pyroxenes to react with an infiltrating fluid to form corona textures of amphibole; pyroxenes inside feldspars behaved very differently. Pyroxenes enclosed in orthoclase-rich feldspar were partially hydrated to amphiboles. Contrastingly, feldspar with lower orthoclase content protected the magmatic pyroxenes efficiently. Transport and transformation mechanisms recorded in these µm to nm textures were studied by EMPA and TEM. Focused Ion Beam (FIB) prepared TEM-foils revealed that pyroxenes, when spatially connected to albite exsolution lamellae, show dissolution features. Based on composition, nanostructures and the known p-T-history, we propose the following succession of events. Ternary feldspar containing small magmatic pyroxenes began to exsolve between about 800 and 700°C. The exsolution changed from coherent to incoherent and a fluid infiltrated the feldspar accompanied by a formation of nanotunnels. Gradually the tunnels grew larger so that finally whole film perthites acted as pathways. When the fluid had access to pyroxene

Lunar soil evolution processes and Apollo 16 core 60013/60014

NASA Astrophysics Data System (ADS)

Basu, A.; McKay, D. S.

1995-03-01

Soils of the 62-cm deep Apollo 16 double drive tube 60013/14 are mature at the top and submature at the bottom. Modal analyses of 5529 grains from the 90-150 um and the 500-1000 m fractions from 12 levels of the core show that, in general, agglutinate abundance increases somewhat monotonically to the top and mimics the Is/FeO profile. There is a general decrease in the modal abundance of monomineralic fragments towards the top, suggesting that agglutinates were formed in part at the expense of monomineralic grains, especially feldspars, which are by far the most abundant mineral in these soils. In detail, the top 27 cm of the core differs from the bottom 21 cm, and the middle 14 cm is intermediate in its properties. In the upper segment, variations in the abundances of feldspars correspond with those of feldspathic fragmental breccias and cataclastic anorthosites; in the bottom segment, a similar but weak correspondence between feldspars and crystalline matrix breccias is observed. Mixing of the comminuted products of these three rock types likely produced the bulk of the core material. Many single feldspars in all size fractions are remarkably fresh, show no damage from shock, and are similar in appearance to the large feldspars in anorthosites and feldspathic fragmental breccias, which we consider to be the primary sources of single feldspars in this core. Major (Na, Al, Si, K, Ca) and minor (Fe, Ba) element analyses of 198 single feldspar grains indicate the presence of only one population of feldspars, which is consistent with our interpretation of feldspar provenance. Classification of 890 monomineralic feldspar, olivine, pyroxene, and glass spherules on the basis of the presence or absence of thin brownish coating related to reworking at the surface-shows that coated grains are much more abundant in the top segment than in the bottom segment. A comparison with the mixing and maturation model (McKay et al., 1977) of soils in the core 60009/10, some 60 m away

Lunar soil evolution processes and Apollo 16 core 60013/60014

NASA Technical Reports Server (NTRS)

Basu, A.; McKay, D. S.

1995-01-01

Soils of the 62-cm deep Apollo 16 double drive tube 60013/14 are mature at the top and submature at the bottom. Modal analyses of 5529 grains from the 90-150 micrometers and the 500-1000 micrometers fractions from 12 levels of the core show that, in general, agglutinate abundance increases somewhat monotonically to the top and mimics the Is/FeO profile. There is a general decrease in the modal abundance of monomineralic fragments towards the top, suggesting that agglutinates were formed in part at the expense of monomineralic grains, especially feldspars, which are by far the most abundant mineral in these soils. In detail, the top 27 cm of the core differs from the bottom 21 cm, and the middle 14 cm is intermediate in its properties. In the upper segment, variations in the abundances of feldspars correspond with those of feldspathic fragmental breccias and cataclastic anorthosites; in the bottom segment, a similar but weak correspondence between feldspars and crystalline matrix breccias is observed. Mixing of the comminuted products of these three rock types likely produced the bulk of the core material. Many single feldspars in all size fractions are remarkably fresh, show no damage from shock, and are similar in appearance to the large feldspars in anorthosites and feldspathic fragmental breccias, which we consider to be the primary sources of single feldspars in this core. Major (Na, Al, Si, K, Ca) and minor (Fe, Ba) element analyses of 198 single feldspar grains indicate the presence of only one population of feldspars, which is consistent with our interpretation of feldspar provenance. Classification of 890 monomineralic feldspar, olivine, pyroxene, and glass spherules on the basis of the presence or absence of thin brownish coating--related to reworking at the surface--shows that coated grains are much more abundant in the top segment than in the bottom segment. A comparison with the mixing and maturation model (McKay et al., 1977) of soils in the core 60009

Lunar soil evolution processes and Apollo 16 core 60013/60014.

PubMed

Basu, A; McKay, D S

1995-03-01

Soils of the 62-cm deep Apollo 16 double drive tube 60013/14 are mature at the top and submature at the bottom. Modal analyses of 5529 grains from the 90-150 micrometers and the 500-1000 micrometers fractions from 12 levels of the core show that, in general, agglutinate abundance increases somewhat monotonically to the top and mimics the Is/FeO profile. There is a general decrease in the modal abundance of monomineralic fragments towards the top, suggesting that agglutinates were formed in part at the expense of monomineralic grains, especially feldspars, which are by far the most abundant mineral in these soils. In detail, the top 27 cm of the core differs from the bottom 21 cm, and the middle 14 cm is intermediate in its properties. In the upper segment, variations in the abundances of feldspars correspond with those of feldspathic fragmental breccias and cataclastic anorthosites; in the bottom segment, a similar but weak correspondence between feldspars and crystalline matrix breccias is observed. Mixing of the comminuted products of these three rock types likely produced the bulk of the core material. Many single feldspars in all size fractions are remarkably fresh, show no damage from shock, and are similar in appearance to the large feldspars in anorthosites and feldspathic fragmental breccias, which we consider to be the primary sources of single feldspars in this core. Major (Na, Al, Si, K, Ca) and minor (Fe, Ba) element analyses of 198 single feldspar grains indicate the presence of only one population of feldspars, which is consistent with our interpretation of feldspar provenance. Classification of 890 monomineralic feldspar, olivine, pyroxene, and glass spherules on the basis of the presence or absence of thin brownish coating--related to reworking at the surface--shows that coated grains are much more abundant in the top segment than in the bottom segment. A comparison with the mixing and maturation model (McKay et al., 1977) of soils in the core 60009

Measurements of the branching fractions for D + → K S 0 K S 0 K + , K S 0 K S 0 π + and D 0 → K S 0 K S 0 , K S 0 K S 0 K S 0

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ablikim, M.; Achasov, M. N.; Ahmed, S.

By analyzing 2.93 fb-1 of data taken at the ψ (3770) resonance peak with the BESIII detector, we measure the branching fractions for the hadronic decays D +→Kmore » $$0\\atop{S}$$K$$0\\atop{S}$$K +, D +→K$$0\\atop{S}$$K$$0\\atop{S}$$π +. D 0→K$$0\\atop{S}$$K$$0\\atop{S}$$ and D 0→K$$0\\atop{S}$$K$$0\\atop{S}$$K$$0\\atop{S}$$.« less

Measurements of the branching fractions for D + → K S 0 K S 0 K + , K S 0 K S 0 π + and D 0 → K S 0 K S 0 , K S 0 K S 0 K S 0

DOE PAGES

Ablikim, M.; Achasov, M. N.; Ahmed, S.; ...

2016-12-13

By analyzing 2.93 fb-1 of data taken at the ψ (3770) resonance peak with the BESIII detector, we measure the branching fractions for the hadronic decays D +→Kmore » $$0\\atop{S}$$K$$0\\atop{S}$$K +, D +→K$$0\\atop{S}$$K$$0\\atop{S}$$π +. D 0→K$$0\\atop{S}$$K$$0\\atop{S}$$ and D 0→K$$0\\atop{S}$$K$$0\\atop{S}$$K$$0\\atop{S}$$.« less

Configurations and decay hindrances of high- K states in Hf 180

DOE PAGES

Tandel, S. K.; Chowdhury, P.; Kondev, F. G.; ...

2016-12-02

Multi-quasiparticle high-K states, several of which are isomeric, were observed in Hf-180 with the Gammasphere array. We determined the lifetimes in the ns-μs range using centroid-shift and decay measurements within a mu s coincidence time window. The configurations of high-K states involve two and four quasiparticles, with states up to K π = (18 -) established. High-K excitations are found to be progressively more favored with increasing excitation energy. The K quantum number is quite robust up to the highest spins observed, as evidenced by the large values of the reduced hindrance for isomeric decays. Furthermore, rotational bands built onmore » three high-K states are identified, and the measured branching ratios in these sequences enable the assignment of underlying configurations. Multi-quasiparticle calculations using the Lipkin-Nogami approach for pairing, with blocking included, reproduce the observed high-K energies quite well.« less

Configurations and decay hindrances of high- K states in Hf 180

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tandel, S. K.; Chowdhury, P.; Kondev, F. G.

Multi-quasiparticle high-K states, several of which are isomeric, were observed in Hf-180 with the Gammasphere array. We determined the lifetimes in the ns-μs range using centroid-shift and decay measurements within a mu s coincidence time window. The configurations of high-K states involve two and four quasiparticles, with states up to K π = (18 -) established. High-K excitations are found to be progressively more favored with increasing excitation energy. The K quantum number is quite robust up to the highest spins observed, as evidenced by the large values of the reduced hindrance for isomeric decays. Furthermore, rotational bands built onmore » three high-K states are identified, and the measured branching ratios in these sequences enable the assignment of underlying configurations. Multi-quasiparticle calculations using the Lipkin-Nogami approach for pairing, with blocking included, reproduce the observed high-K energies quite well.« less

Field Exploration and Life Detection Sampling Through Planetary Analogue Sampling (FELDSPAR).

NASA Technical Reports Server (NTRS)

Stockton, A.; Amador, E. S.; Cable, M. L.; Cantrell, T.; Chaudry, N.; Cullen, T.; Duca, Z.; Gentry, D. M.; Kirby, J.; Jacobsen, M.;

Configurations and decay hindrances of high-K states in 180Hf

NASA Astrophysics Data System (ADS)

Tandel, S. K.; Chowdhury, P.; Kondev, F. G.; Janssens, R. V. F.; Khoo, T. L.; Carpenter, M. P.; Lauritsen, T.; Lister, C. J.; Seweryniak, D.; Zhu, S.; Deacon, A.; Freeman, S. J.; Hammond, N. J.; Jones, G. D.; Moore, E. F.; Smith, J. F.

2016-12-01

Multi-quasiparticle high-K states, several of which are isomeric, were observed in 180Hf with the Gammasphere array. Lifetimes in the ns-μ s range were determined using centroid-shift and decay measurements within a μ s coincidence time window. The configurations of high-K states involve two and four quasiparticles, with states up to Kπ=(18-) established. High-K excitations are found to be progressively more favored with increasing excitation energy. The K quantum number is quite robust up to the highest spins observed, as evidenced by the large values of the reduced hindrance for isomeric decays. Rotational bands built on three high-K states are identified, and the measured branching ratios in these sequences enable the assignment of underlying configurations. Multi-quasiparticle calculations using the Lipkin-Nogami approach for pairing, with blocking included, reproduce the observed high-K energies quite well.

Example of trondhjemite genesis by means of alkali metasomatism: Rockford Granite, Alabama Appalachians

DOE Office of Scientific and Technical Information (OSTI.GOV)

Drummond, M.S.; Wesolowski, D.; Ragland, P.C.

1985-01-01

An alternative model for trondhjemite genesis is proposed where granite is transformed to trondhjemite via infiltration by a Na-rich metamorphic fluid. The Rockford Granite serves as the case example for this process and is characterized as a synmetamorphic, peraluminous trondhjemite-granite suite. The major process operative in the conversion of granite to trondhjemite involves cation exchange of Na for K in the feldspar and mica phases through a volatile fluid medium. Whole-rock delta/sup 18/O values for the trondhjemites are negatively correlated with the atomic prop. K/Na ratio indicating a partial reequilibration of the altered granitoids with a Na- and /sup 18/O-richmore » metamorphically derived fluid. Biotite decomposition to an Al-epidote-paragonitic muscovite-quartz assemblage is also associated with the Na-metasomatism, as are apatite replacement by Al-epidote and secondary zircon crystallization. The replacement of magmatic phases by metasomatic phases exemplifies the chemical changes produced during infiltration metasomatism where the trondhjemites are depleted in all REE's. The timing of the infiltration metasomatism is thought to have occurred during regional metamorphism, producing a discrete fluid phase in the surrounding amphibolite-grade metasediments. Foliation planes in the granitoid apparently served as conduts for fluid flow with reaction enhanced permeability accompanying the 8% molar volume reduction during Na for K exchange in the feldspars. A model is proposed where metamorphic fluids migrated updip and along strike from their source and were buffered by the presence or absence of two feldspars in the metasediments.« less

Optical dating of eolian deposits since the last interglacial along the northern margin of the Chinese Loess Plateau

NASA Astrophysics Data System (ADS)

Lü, Tongyan; Sun, Jimin; Gong, Zhijun

2018-04-01

Understanding the chronology of eolian sand-loess-paleosol sequences along the northern margin of the Chinese Loess Plateau (CLP) is crucial for comprehending climate change and the advance and retreat of the adjacent Mu Us desert. In this study, a sand-loess-soil sequence from the northern margin of the CLP was studied by applying the single aliquot regenerative (SAR) protocol to quartz grains, and the multi-elevated-temperature post-IR IRSL (MET-pIRIR) protocol to K-feldspar grains. For equivalent dose (De) determination, 63-90 μm quartz and K-feldspar grains were used. Our results indicate that the MET-pIRIR ages of K-feldspar grains in this sequence range from 94.4 ± 7.0 ka to 148.3 ± 13.3 ka for the last interglacial paleosol (S1); for the upper part of the section, quartz-based SAR-OSL dating was used, yielding ages spanning from 5.8 ± 0.4 ka to 35.9 ± 4.1 ka. After cross-checking these results with previously-reported isochron OSL and TL ages, the reliability of the MET-pIRIR protocol when applied to the last interglacial paleosol was confirmed. Based on a new OSL chronology of the Shimao profile, the studied eolian deposits can be broadly correlated with the last glacial-interglacial cycle, but their dating also points to sedimentary hiatuses occurring at 94.4 ka, 35.9 ka and 5.8 ka, due most probably to strong wind erosion caused by intensified cold-dry winter monsoonal circulations during the last glacial maxima.

Foliation development and reaction softening by dissolution and precipitation in the transformation of granodiorite to orthogneiss, Glastonbury Complex, Connecticut, U.S.A

USGS Publications Warehouse

Wintsch, R.P.; Aleinikoff, J.N.; Yi, K.

2005-01-01

Textures, microstructures, and patterns of chemical zoning in minerals in a granodioritic orthogneiss in the Glastonbury Complex, Connecticut, lead to the interpretation that foliation development was facilitated by retrograde hydration reactions in the presence of an aqueous fluid. Incomplete replacement of the metastable magmatic minerals K-feldspar + hastingsite + magnetite produced foliation-defining biotite + epidote + quartz. These reaction products did not replace K-feldspar - hastingsite interfaces; rather, either biotite or epidote replaced the amphibole, and plagioclase replaced K-feldspar. Biotite and epidote precipitated syntectonically in discrete layers that define the foliation in the orthogneiss, whereas quartz precipitated primarily in ribbons, further enhancing the fabric. Metastable REE-rich igneous titanite also dissolved, and was incompletely replaced by REE-poor, Al-bearing metamorphic titanite. The similar concentrations of the REE in epidote and titanite show that the REE released by titanite dissolution were precipitated locally as the allanite component in adjacent grains of epidote. The entire process was syntectonic, with most grains showing multiple overgrowths in the direction of extension as defined by stretched xenoliths. Sufficient U was present in the titanite overgrowths to allow SHRIMP dating of cores, mantles, and rims. These results suggest at least three retrograde Alleghanian events of growth in a span of ???30 m.y. Thus the dissolution - transportation - precipitation process not only describes the reaction mechanism but also leads to the redistribution of reaction products into nearly monomineralic layers, thus contributing to metamorphic differentiation and to the development of the foliation. The resulting orthogneiss was much weaker that the granodiorite protolith, owing to this reaction and textural softening.

Type 2 Diabetes–Associated Missense Polymorphisms KCNJ11 E23K and ABCC8 A1369S Influence Progression to Diabetes and Response to Interventions in the Diabetes Prevention Program

PubMed Central

Florez, Jose C.; Jablonski, Kathleen A.; Kahn, Steven E.; Franks, Paul W.; Dabelea, Dana; Hamman, Richard F.; Knowler, William C.; Nathan, David M.; Altshuler, David

2008-01-01

The common polymorphisms KCNJ11 E23K and ABCC8 A1369S have been consistently associated with type 2 diabetes. We examined whether these variants are also associated with progression from impaired glucose tolerance (IGT) to diabetes and responses to preventive interventions in the Diabetes Prevention Program. We genotyped both variants in 3,534 participants and performed Cox regression analysis using genotype, intervention, and their interactions as predictors of diabetes incidence over ~3 years. We also assessed the effect of genotype on insulin secretion and insulin sensitivity at 1 year. As previously shown in other studies, lysine carriers at KCNJ11 E23K had reduced insulin secretion at baseline; however, they were less likely to develop diabetes than E/E homozygotes. Lysine carriers were less protected by 1-year metformin treatment than E/E homozygotes (P < 0.02). Results for ABCC8 A1369S were essentially identical to those for KCNJ11 E23K. We conclude that the lysine variant in KCNJ11 E23K leads to diminished insulin secretion in individuals with IGT. Given our contrasting results compared with case-control analyses, we hypothesize that its effect on diabetes risk may occur before the IGT-to-diabetes transition. We further hypothesize that the diabetes-preventive effect of metformin may interact with the impact of these variants on insulin regulation. Diabetes 56: 531–536, 2007 PMID:17259403

Participating in Authentic Science with the Aid of Learning Progressions through Mission Earth Workshops

NASA Astrophysics Data System (ADS)

Lewis, P. M., Jr.; Taylor, J.; Harte, T.; Czajkowski, K. P.

2016-12-01

"MISSION EARTH: Fusing GLOBE with NASA Assets to Build Systemic Innovation In STEM Education" is one of the new education cooperative agreements funded by the NASA Science Mission Directorate. Students will learn how to conduct "real science" through hands-on data collection using Global Learning and Observations to Benefit the Environment (GLOBE) protocols combined with other NASA science educational materials. This project aims to work with educators spanning the full K-12 range, requiring three grade bands of learning progressions and vertical alignment among materials and resources to best meet classroom needs. From K to 12 students have vastly different abilities to conduct and learn from scientific investigations. Hand-picked NASA assets will provide appropriate exposure across the curriculum and grade bands, and we are developing unique learning progressions that bring together GLOBE protocols for data collection and learning activities, NASA data sets through MY NASA DATA for data comparison, and more. The individual materials are not limited to science, but also include all elements of STEM with literacy components added in where appropriate. This will give the students an opportunity to work on better understanding the world around them in a well-rounded way, and offer cross-subject/classroom exposure to improve student understanding. To ensure that these learning progressions can continue to be used in the classroom in the future, alignment to the Next Generation Science Standards will help frame all of the materials and products. The learning progressions will be living documents that will change based on context. After several iterations, it is our goal to produce learning progressions for grades K-12 that will allow any STEM teacher to pick up and infuse NASA and GLOBE in their classroom at any location and at any time in their school year. This presentation will share results from the first year of development for this project.

Progress in High Power Free-Piston Stirling Convertor Development

NASA Technical Reports Server (NTRS)

Brandhorst, Henry W., Jr.; Kirby, Raymond L.; Chapman, Peter A.; Walter, Thomas J.

2008-01-01

The U.S. Space Exploration Policy has established a vision for human exploration of the moon and Mars. One option for power for future outposts on the lunar and Martian surfaces is a nuclear reactor coupled with a free-piston Stirling convertor at a power level of 30-40 kWe. A 25 kW convertor was developed in the 1990s under the SP-100 program. This system consisted of two 12.5 kWe engines connected at their hot ends and mounted in tandem to cancel vibration. Recently, NASA began a new project with Auburn University to develop a 5 kWe, single convertor for use in such a possible lunar power system. Goals of this development program include a specific power in excess of 140 We/kg at the convertor level, lifetime in excess of five years and a control system that will safely manage the convertors in case of an emergency. Foster-Miller, Inc. is developing the 5 kWe Stirling Convertor Assembly. The characteristics of the design along with progress in developing the system will be described.

Progress in High Power Free-Piston Stirling Convertor Development

NASA Astrophysics Data System (ADS)

Brandhorst, Henry W., Jr.; Kirby, Raymond L.; Chapman, Peter A.; Walter, Thomas J.

2008-09-01

The U.S. Space Exploration Policy has established a vision for human exploration of the moon and Mars. One option for power for future outposts on the lunar and Martian surfaces is a nuclear reactor coupled with a free-piston Stirling convertor at a power level of 30-40 kWe. A 25 kW convertor was developed in the 1990s under the SP-100 program. This system consisted of two 12.5 kWe engines connected at their hot ends and mounted in tandem to cancel vibration. Recently, NASA began a new project with Auburn University to develop a 5 kWe, single convertor for use in such a possible lunar power system. Goals of this development program include a specific power in excess of 140 We/kg at the convertor level, lifetime in excess of five years and a control system that will safely manage the convertors in case of an emergency. Foster-Miller, Inc. is developing the 5 kWe Stirling Convertor Assembly. The characteristics of the design along with progress in developing the system will be described.

40K-40Ca and 87Rb-86Sr Dating by SIMS: The Double-Plus Advantage

NASA Astrophysics Data System (ADS)

Harrison, T. M.; McKeegan, K. D.; Schmitt, A. K.

2009-12-01

retentivity of 40Ca* relative to 40Ar* in white micas. This approach offers the potential to develop a branched-decay thermochronometer (K-Ca-Ar) permitting simultaneous solution of temperature-time history from μm-scale isotopic variations. A further advantage is that even low resolution SIMS instruments (e.g., ims7f) can utilize the double-plus method. Initial investigations using the same double-plus approach for Rb-Sr dating show promise. While resolving 87Rb+ from 87Sr+ requires an MRP of ~290k, unattainable using any current SIMS instrument, 87Rb++ is so strongly suppressed that determination of 87Sr++ is possible with minor peak stripping. 87Rb/86Sr can be determined either from 85Rb+/88Sr+ at MRP≈ 8k or by the use of energy filtering. In addition to micas, these approaches may be applicable to any mineral systems enriched in alkali metals relative to alkaline earths, such as alkali feldspars, feldspathoids, and alkaline halides.

Orogen-scale anticline revealed in the Southern Alps of New Zealand by structural thermochronology

NASA Astrophysics Data System (ADS)

Zhou, Renjie; Brandon, Mark

2017-04-01

A dense set of cooling ages from the Southern Alps reveals an orogen-scale anticline of cooling-age isosurfaces (isochrones) and provides an interesting example of structural thermochronology, where isochrones are used as structural markers. The isochrone concept is an integral aspect of the age-elevation method, but the latter implicitly assumes that all isochrones are horizontal. Our experience in New Zeland and elsewhere is that isochrones are commonly tilted after formation. We use a more general approach that solves for orientation of the isochrone surfaces, and also the slope of the age-elevation trend, where "elevation" is measured normal to the isochrone surfaces. In New Zealand, collision and convergence between the Pacific and Australian plates have resulted in the formation and continuing growth of the Southern Alps, a prototypical orogenic wedge. In the western side, the Southern Alps is bounded by the Alpine fault, along with deeply exhumed rocks from depths up to 25 km. There are 150 apatite and 200 zircon fission-track (AFT, ZFT) ages that cover the vast region of the South Island of New Zealand from Lake Summer to Lake Wanaka. The AFT ages range from <0.5 to 140 Ma, and the ZFT ages, from <0.5 to 400 Ma. Our approach was initiated by McPhillips and Brandon (Earth and Planetary Science Letters, 2010, doi: 10.1016/j.epsl.2010.05.022). We use a least-squares method to solve for a best-fit sequence of dipping isochrone surfaces. The solution specifies the strike, dip and spacing of the parallel isochrones, the last of which indicates the velocity of the isochrones passing through the closure depth. We find that the calculation of the entire dataset failed to yield reasonable results, implying nonplanar structures at the regional scale. Using subsets of data, we observed three distinct zones of isochrones from E to W across the South Island. 1) The large area east of the Southern Alps in the central South Island contains ZFT isochrones that dip shallowly

Involvement of neutral endopeptidase in neoplastic progression.

PubMed

Sumitomo, Makoto; Shen, Ruoqian; Nanus, David M

2005-08-01

Neutral endopeptidase 24.11 (NEP) is a 90-110 kDa cell surface cell surface peptidase that is normally expressed by numerous tissues, including prostate, kidney, intestine, endometrium, adrenal glands and lung. This enzyme cleaves peptide bonds on the amino side of hydrophobic amino acids and inactivates a variety of physiologically active peptides, including atrial natriuretic factor, substance P, bradykinin, oxytocin, Leu- and Met-enkephalins, neurotensin, bombesin, endothelin-1, and bombesin-like peptides. NEP reduces the local concentration of peptide available for receptor binding and signal transduction. Loss or decreases in NEP expression have been reported in a variety of malignancies. Reduced NEP may promote peptide-mediated proliferation by allowing accumulation of higher peptide concentrations at the cell surface, and facilitate the development or progression of neoplasia. We have used prostate cancer as model in which to study the involvement of NEP in malignancy. Using a variety of experimental approaches, including recombinant NEP, cell lines expressing wild-type and mutant NEP protein, and cell lines expressing NEP protein with a mutated cytoplasmic domain, we have examined the effects of NEP on cell migration and cell survival. We have shown that the effects of NEP are mediated by its ability to catalytically inactivate substrates such as bombesin and endothelin-1, but also through direct protein-protein interaction with other protein such as Lyn kinase [which associates with the p85 subunit of phosphatidylinositol 3-kinase (PI3-K) resulting in NEP-Lyn-PI3-K protein complex], ezrin/radixin/moesin (ERM) proteins, and the PTEN tumor suppressor protein. We review the mechanisms of NEP's tumor suppressive action and how NEP loss contributes to tumor progression.

Thermochronology of mid-Cretaceous dioritic granulites adjacent "Big Bend" in Australia-Pacific plate boundary, northern South Island, New Zealand

NASA Astrophysics Data System (ADS)

Sagar, M.; Seward, D.; Heizler, M. T.; Palin, J. M.; Toy, V. G.; Tulloch, A. J.

2012-12-01

The Western Fiordland Orthogneiss (WFO), situated south-east of the Australian-Pacific plate boundary (Alpine Fault), southern South Island, New Zealand is the largest suite of plutonic rocks intruded into the Pacific margin of Gondwana during the final stages of arc plutonism preceding break-up of the supercontinent in the Late Cretaceous. Dextral motion of c. 480 km along the Alpine Fault during the Cenozoic has offset originally contiguous Pacific Gondwana margin rocks in northern and southern South Island. The Glenroy Complex in northern South Island, west of the Alpine Fault is dominated by two-pyroxene+hornblende granulite facies monzodioritic gneisses. U-Pb zircon geochronological and geochemical data indicate the Glenroy Complex was emplaced between 128-122 Ma and is a correlative of the WFO. The Glenroy Complex forms the lower-most block bounded by an east-dipping set of imbricate thrusts that developed during the late Cenozoic to the west of the largest S-shaped restraining bend ("Big Bend") in the Alpine Fault. New 40Ar/39Ar and fission-track thermochronological data, combined with previous geological field-mapping, demonstrate that the Glenroy Complex cooled rapidly (c. 30° C/Ma) after emplacement and granulite facies metamorphism (c. 850°C) at c. 120 Ma, through c. 550 °C by c. 110-100 Ma. The average cooling rate during the Late Cretaceous-Cenozoic was relatively slow, and initial exposure in the late Early Miocene (c. 16 Ma) was followed by reburial to c. 3-4 km (c. 80-100 °C) before final exhumation post-Pliocene. This thermal history is similar to the WFO, which cooled rapidly through c. 350 °C during mid-Cretaceous continental extension, followed by slow cooling during the Late Cretaceous and Cenozoic until development of the Australian-Pacific boundary through New Zealand facilitated rapid, exhumation-related cooling from c. 240 °C at c. 20 Ma and final exhumation post-10 Ma (Davids, 1999). However, the Glenroy Complex cooled at a faster

Experimental Insights into Multiphase (H2O-CO2) Fluid-Rock Interactions in Geothermal Systems

NASA Astrophysics Data System (ADS)

Kaszuba, J. P.; Lo Re, C.; Martin, J.; McPherson, B. J.; Moore, J. N.

2012-12-01

Integrated hydrothermal experiments and geochemical modeling elucidate fluid-rock interactions and reaction pathways in both natural and anthropogenic systems, including enhanced geothermal systems (EGS) in which CO2 is introduced as a working fluid. Experiments are conducted in rocker bombs and flexible Au-Ti reaction cells. Individual experiments require one to three months to complete; intensive in-situ fluid/gas sampling gauges reaction progress. Investigation of granitic reservoirs and associated vein minerals are broadly based on the Roosevelt Hot Springs thermal area, Utah, USA. The granite consists of subequal amounts of quartz, perthitic K-feldspar (~25% wt% albite and 75% wt% K-feldspar), and oligoclase (An23), and 4 wt% Fe-rich biotite. Vein minerals include epidote and chlorite (clinochlore). Experiments are conducted at 250°C and 25 to 45 MPa. Each experiment uses mineral powders (75 wt% of rock mass, ground to <45 um) to increase reactivity and also mineral pieces (0.1-0.7 cm in size) to promote petrologic evaluation of mineral reactions. The water (I ≈ 0.1 molal) initially contains millimolal quantities of SiO2, Al, Ca, Mg, K, SO4, and HCO3 and is designed to be saturated with all of the minerals present at the start of each experiment. Excess CO2 is injected to saturate the water and maintain an immiscible supercritical fluid phase. The entire evolutionary path of the natural system is not replicated at laboratory scales. Instead, experiments define a segment of the reaction path and, in combination with geochemical modeling, provide clear trajectories towards equilibrium. Reaction of granite+water yields illite+zeolite; smectite subsequently precipitates in response to CO2 injection. Reaction of granite+epidote+water yields illite+zeolite+smectite; zeolite does not precipitate after CO2 is injected. Water in all experiments become saturated with chalcedony. Carbonate minerals do not precipitate but are predicted as final equilbrium products

Development of a 2K x 2K GaAs QWIP Focal Plane Array

NASA Technical Reports Server (NTRS)

Jhabvala, M.; Choi, K.; Jhabvala, C.; Kelly, D.; Hess, L.; Ewin, A.; La, A.; Wacynski, A.; Sun, J.; Adachi, T.;

Addressing Excellence Gaps in K-12 Education. Position Statement

ERIC Educational Resources Information Center

National Association for Gifted Children, 2015

2015-01-01

Since the passage of the No Child Left Behind Act in 2001, a major objective of federal and state education policy has been to narrow K-12 achievement gaps. This position statement notes that the available data suggest that the singular focus on the most struggling learners has resulted in meaningful progress in closing minimum-competency…

Bax/Tubulin/Epithelial-Mesenchymal Pathways Determine the Efficacy of Silybin Analog HM015k in Colorectal Cancer Cell Growth and Metastasis.

PubMed

Amawi, Haneen; Hussein, Noor A; Ashby, Charles R; Alnafisah, Rawan; Sanglard, Leticia M; Manivannan, Elangovan; Karthikeyan, Chandrabose; Trivedi, Piyush; Eisenmann, Kathryn M; Robey, Robert W; Tiwari, Amit K

2018-01-01

The inhibition of apoptosis, disruption of cellular microtubule dynamics, and over-activation of the epithelial mesenchymal transition (EMT), are involved in the progression, metastasis, and resistance of colorectal cancer (CRC) to chemotherapy. Therefore, the design of a molecule that can target these pathways could be an effective strategy to reverse CRC progression and metastasis. In this study, twelve novel silybin derivatives, HM015a-HM015k (15a-15k) and compound 17, were screened for cytotoxicity in CRC cell lines. Compounds HM015j and HM015k (15k and 15j) significantly decreased cell proliferation, inhibited colony formation, and produced cell cycle arrest in CRC cells. Furthermore, 15k significantly induced the formation of reactive oxygen species and apoptosis. It induced the cleavage of the intrinsic apoptotic protein (Bax p21) to its more efficacious fragment, p18. Compound 15k also inhibited tubulin expression and disrupted its structure. Compound 15k significantly decreased metastatic LOVO cell migration and invasion. Furthermore, 15k reversed mesenchymal morphology in HCT116 and LOVO cells. Additionally, 15k significantly inhibited the expression of the mesenchymal marker N-cadherin and upregulated the expression of the epithelial marker, E-cadherin. Compound 15k inhibited the expression of key proteins known to induce EMT (i.e., DVL3, β-catenin, c-Myc) and upregulated the anti-metastatic protein, cyclin B1. Overall, in vitro , 15k significantly inhibited CRC progression and metastasis by inhibiting apoptosis, tubulin activity and the EMT pathways. Overall, these data suggest that compound 15k should be tested in vivo in a CRC animal model for further development.

Radiometric ages for basement rocks from the Emperor Seamounts, ODP Leg 197

NASA Astrophysics Data System (ADS)

Duncan, Robert A.; Keller, Randall A.

2004-08-01

The Hawaiian-Emperor seamount chain is the "type" example of an age-progressive, hot spot-generated intraplate volcanic lineament. However, our current knowledge of the age distribution within this province is based largely on radiometric ages determined several decades ago. Improvements in instrumentation, sample preparation methods, and new material obtained by recent drilling warrant a reexamination of the age relations among the older Hawaiian volcanoes. We report new age determinations (40Ar-39Ar incremental heating method) on whole rocks and feldspar separates from Detroit (Sites 1203 and 1204), Nintoku (Site 1205), and Koko (Site 1206) Seamounts (Ocean Drilling Program (ODP) Leg 197) and Meiji Seamount (Deep Sea Drilling Project (DSDP) Leg 19, Site 192). Plateaus in incremental heating age spectra for Site 1203 lava flows give a mean age of 75.8 ± 0.6 (2σ) Ma, which is consistent with the normal magnetic polarity directions observed and biostratigraphic age assignments. Site 1204 lavas produced discordant spectra, indicating Ar loss by reheating and K mobilization. Six plateau ages from lava flows at Site 1205 give a mean age of 55.6 ± 0.2 Ma, corresponding to Chron 24r. Drilling at Site 1206 intersected a N-R-N magnetic polarity sequence of lava flows, from which six plateau ages give a mean age of 49.1 ± 0.2 Ma, corresponding to the Chron 21n-22r-22n sequence. Plateau ages from two feldspar separates and one lava from DSDP Site 192 range from 34 to 41 Ma, significantly younger than the Cretaceous age of overlying sediments, which we relate to postcrystallization K mobilization. Combined with new dating results from Suiko Seamount (DSDP Site 433) and volcanoes near the prominent bend in the lineament [, 2002], the overall trend is increasing volcano age from south to north along the Emperor Seamounts, consistent with the hot spot model. However, there appear to be important departures from the earlier modeled simple linear age progression, which we

Deletion of tumor progression locus 2 attenuates alcohol induced hepatic inflammation

USDA-ARS?s Scientific Manuscript database

BACKGROUND: The pathogenesis of alcoholic liver disease (ALD) involves the interaction of several inflammatory signaling pathways. Tumor progression locus 2 (TPL2), also known as Cancer Osaka Thyroid (COT) and MAP3K8, is a serine threonine kinase that functions as a critical regulator of inflammator...

Use of Acoustic Emission to Monitor Progressive Damage Accumulation in Kevlar (R) 49 Composites

NASA Technical Reports Server (NTRS)

Waller, Jess M.; Saulsberry, Regor L.; Andrade, Eduardo

2009-01-01

Acoustic emission (AE) data acquired during intermittent load hold tensile testing of epoxy impregnated Kevlar(Registeres TradeMark) 49 (K/Ep) composite strands were analyzed to monitor progressive damage during the approach to tensile failure. Insight into the progressive damage of K/Ep strands was gained by monitoring AE event rate and energy. Source location based on energy attenuation and arrival time data was used to discern between significant AE attributable to microstructural damage and spurious AE attributable to noise. One of the significant findings was the observation of increasing violation of the Kaiser effect (Felicity ratio < 1.0) with damage accumulation. The efficacy of three different intermittent load hold stress schedules that allowed the Felicity ratio to be determined analytically is discussed.

Thermal-hydrodynamic-chemical (THC) modeling based on geothermal field data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kiryukhin, Alexey; Xu, Tianfu; Pruess, Karsten

Data on fluid chemistry and rock mineralogy are evaluated for a number of geothermal fields located in the volcanic arc of Japan and Kamchatka, Russia, Common chemical characteristics are identified and used to define scenarios for detailed numerical modeling of coupled thermal hydrodynamic chemical (THC) processes. The following scenarios of parental geothermal fluid upflow were studied: (1) single-phase conditions, 260 C at the bottom ( Ogiri type); (2) two-phase conditions, 300 C at the bottom ( Hatchobaru type); and (3) heat pipe conditions, 260 C at the bottom ( Matsukawa type). THC modeling for the single-phase upflow scenario shows wairakite,more » quartz, K-feld spar and chlorite formed as the principal secondary minerals in the production zone, and illite-smectite formed below 230 C. THC modeling of the two-phase upflow shows that quartz, K-feldspar (microcline), wairakite and calcite precipitate in the model as principal secondary minerals in the production zone. THC modeling of heat pipe conditions shows no significant secondary deposition of minerals (quartz, K-feldspar, zeolites) in the production zone. The influence of thermodynamic and kinetic parameters of chemical interaction, and of mass fluxes on mineral phase changes, was found to be significant, depending on the upflow regime. It was found that no parental geothermal fluid inflow is needed for zeolite precipitation, which occurs above 140 C in saturated andesite, provided that the porosity is greater than 0.001. In contrast, quartz and K-feldspar precipitation may result in a significant porosity reduction over a hundred-year time scale under mass flux conditions, and complete fracture sealing will occur given sufficient time under either single-phase or two-phase upflow scenarios. A heat pipe scenario shows no significant porosity reduction due to lack of secondary mineral phase deposition.« less

Disruption of the Gardos channel (KCa3.1) in mice causes subtle erythrocyte macrocytosis and progressive splenomegaly.

PubMed

Grgic, Ivica; Kaistha, Brajesh P; Paschen, Steffen; Kaistha, Anuradha; Busch, Christoph; Si, Han; Köhler, Kernt; Elsässer, Hans-Peter; Hoyer, Joachim; Köhler, Ralf

2009-06-01

Gardos channel, the erythrocyte Ca(2+)-activated K(+) channel (K(Ca)3.1), is considered a major regulator of red blood cell (RBC) volume by mediating efflux of potassium and thus cell dehydration and shrinkage. However, the functional importance of K(Ca)3.1 in RBC in vivo is incompletely understood. Here, we used K(Ca)3.1(-/-)-mice to investigate the consequences of K(Ca)3.1 deficiency for RBC indices, functions, and sequestration. RBCs of K(Ca)3.1(-/-)-mice of all ages were mildly macrocytic but their biconcave appearance being preserved. RBC number, total hemoglobin, and hematocrit were unchanged in the adult K(Ca)3.1(-/-)-mice and increased in the premature K(Ca)3.1(-/-)-mice. Filterability, Ca(2+)-dependent volume decrease and osmotic tolerance of RBCs lacking K(Ca)3.1 were noticeably reduced when compared to RBC of wild-type littermates. Deformability to increasing shear stress was unchanged. Strikingly, K(Ca)3.1(-/-)-mice developed progressive splenomegaly which was considerable ( approximately 200% of controls) in the >6-month-old mice and was paralleled by increased iron deposition in the aged mice presumably as a consequence of enhanced RBC sequestration. Daily injections of the K(Ca)3.1-blocker TRAM-34 (120 mg/kg) also produced mild splenomegaly in wild-type mice. We conclude that genetic deficit of erythroid K(Ca)3.1 causes mild RBC macrocytosis, presumably leading to reduced filterability, and impairs volume regulation. These RBC defects result in mild but progressive splenomegaly.

A Two-Stage Model for Origin of Al-rich Crustal Xenoliths in Miocene Andesite, Diablo Range, West-Central California

NASA Astrophysics Data System (ADS)

Metzger, E. P.; Ernst, W. G.

2003-12-01

Miocene ( ˜ 8-10.5 Ma) andesite exposed as small plugs and dikes in the Diablo Range of west-central California encloses scattered xenoliths with diverse compositions and textures. The andesite is part of the Diablo Range Volcanics (DRV), a mafic to intermediate suite that is broadly coeval with and may be erosional remnants of the more extensive Quien Sabe Field located to the south and east. The DRV suite is inferred to be part of a northwestwardly younging sequence of volcanic fields that may be related to migration of the Mendocino Triple Junction (MTJ). Two basic categories of xenoliths are present: (1) metasedimentary rocks including quartzite, biotite schist, garnet-clinopyroxene gneiss, and distinctive sillimanite-corundum rocks; and (2) gabbroic and dioritic rocks exhibiting plutonic textures. Preliminary analysis has focused on aluminous xenoliths in which blocky porphyroblasts consisting of intergrown plagioclase, corundum, and hercynite +/- sillimanite +/- alkali feldspar up to ˜ 2 cm in length are surrounded by a very fine-grained granoblastic matrix of plagioclase, orthopyroxene, and hercynite +/- biotite +/- alkali feldspar +/- minor quartz. Glass is present both within the inclusions and in the surrounding matrix. The square to elongate outlines of the plagioclase-corundum inclusions suggest that they are pseudomorphic after andalusite. The corundum-bearing xenoliths are interpreted as the products of two stages of high T-low P metamorphism. The first event involved mid-crustal metamorphism (reflecting cessation of outboard subduction/refrigeration?) to produce andalusite-bearing hornfels; other phases probably included K-feldspar, Na-plagioclase, muscovite, biotite, and quartz. The second stage of recrystallization took place when the previously metamorphosed wall rock was incorporated in andesitic magma, possibly during passage of the MTJ. In response to heating by the magma, andalusite was replaced by corundum, plagioclase +/- sillimanite

Loss of Desmocollin 3 in Skin Tumor Development and Progression

PubMed Central

Chen, Jiangli; O’Shea, Charlene; Fitzpatrick, James E.; Koster, Maranke I.; Koch, Peter J.

2011-01-01

Desmocollin 3 (DSC3) is a desmosomal cadherin that is required for maintaining cell adhesion in the epidermis as demonstrated by the intra-epidermal blistering observed in Dsc3 null skin. Recently, it has been suggested that deregulated expression of DSC3 occurs in certain human tumor types. It is not clear whether DSC3 plays a role in the development or progression of cancers arising in stratified epithelia such as the epidermis. To address this issue, we generated a mouse model in which Dsc3 expression is ablated in K-Ras oncogene-induced skin tumors. Our results demonstrate that loss of Dsc3 leads to an increase in K-Ras induced skin tumors. We hypothesize that acantholysis-induced epidermal hyperplasia in the Dsc3 null epidermis facilitates Ras-induced tumor development. Further, we demonstrate that spontaneous loss of DSC3 expression is a common occurrence during human and mouse skin tumor progression. This loss occurs in tumor cells invading the dermis. Interestingly, other desmosomal proteins are still expressed in tumor cells that lack DSC3, suggesting a specific function of DSC3 loss in tumor progression. While loss of DSC3 on the skin surface leads to epidermal blistering, it does not appear to induce loss of cell-cell adhesion in tumor cells invading the dermis, most likely due to a protection of these cells within the dermis from mechanical stress. We thus hypothesize that DSC3 can contribute to the progression of tumors both by cell adhesion-dependent (skin surface) and likely by cell adhesion-independent (invading tumor cells) mechanisms. PMID:21681825

Temporal dissection of K-ras(G12D) mutant in vitro and in vivo using a regulatable K-ras(G12D) mouse allele.

PubMed

Wang, Zuoyun; Feng, Yan; Bardeesy, Nabeel; Bardessy, Nabeel; Wong, Kwok-Kin; Liu, Xin-Yuan; Ji, Hongbin

2012-01-01

Animal models which allow the temporal regulation of gene activities are valuable for dissecting gene function in tumorigenesis. Here we have constructed a conditional inducible estrogen receptor-K-ras(G12D) (ER-K-ras(G12D)) knock-in mice allele that allows us to temporally switch on or off the activity of K-ras oncogenic mutant through tamoxifen administration. In vitro studies using mice embryonic fibroblast (MEF) showed that a dose of tamoxifen at 0.05 µM works optimally for activation of ER-K-ras(G12D) independent of the gender status. Furthermore, tamoxifen-inducible activation of K-ras(G12D) promotes cell proliferation, anchor-independent growth, transformation as well as invasion, potentially via activation of downstream MAPK pathway and cell cycle progression. Continuous activation of K-ras(G12D) in vivo by tamoxifen treatment is sufficient to drive the neoplastic transformation of normal lung epithelial cells in mice. Tamoxifen withdrawal after the tumor formation results in apoptosis and tumor regression in mouse lungs. Taken together, these data have convincingly demonstrated that K-ras mutant is essential for neoplastic transformation and this animal model may provide an ideal platform for further detailed characterization of the role of K-ras oncogenic mutant during different stages of lung tumorigenesis.

Glaucoma progression detection by retinal nerve fiber layer measurement using scanning laser polarimetry: event and trend analysis.

PubMed

Moon, Byung Gil; Sung, Kyung Rim; Cho, Jung Woo; Kang, Sung Yong; Yun, Sung-Cheol; Na, Jung Hwa; Lee, Youngrok; Kook, Michael S

2012-06-01

To evaluate the use of scanning laser polarimetry (SLP, GDx VCC) to measure the retinal nerve fiber layer (RNFL) thickness in order to evaluate the progression of glaucoma. Test-retest measurement variability was determined in 47 glaucomatous eyes. One eye each from 152 glaucomatous patients with at least 4 years of follow-up was enrolled. Visual field (VF) loss progression was determined by both event analysis (EA, Humphrey guided progression analysis) and trend analysis (TA, linear regression analysis of the visual field index). SLP progression was defined as a reduction of RNFL exceeding the predetermined repeatability coefficient in three consecutive exams, as compared to the baseline measure (EA). The slope of RNFL thickness change over time was determined by linear regression analysis (TA). Twenty-two eyes (14.5%) progressed according to the VF EA, 16 (10.5%) by VF TA, 37 (24.3%) by SLP EA and 19 (12.5%) by SLP TA. Agreement between VF and SLP progression was poor in both EA and TA (VF EA vs. SLP EA, k = 0.110; VF TA vs. SLP TA, k = 0.129). The mean (±standard deviation) progression rate of RNFL thickness as measured by SLP TA did not significantly differ between VF EA progressors and non-progressors (-0.224 ± 0.148 µm/yr vs. -0.218 ± 0.151 µm/yr, p = 0.874). SLP TA and EA showed similar levels of sensitivity when VF progression was considered as the reference standard. RNFL thickness as measurement by SLP was shown to be capable of detecting glaucoma progression. Both EA and TA of SLP showed poor agreement with VF outcomes in detecting glaucoma progression.

The amino-terminal matrix assembly domain of fibronectin stabilizes cell shape and prevents cell cycle progression.

PubMed

Christopher, R A; Judge, S R; Vincent, P A; Higgins, P J; McKeown-Longo, P J

1999-10-01

Adhesion to the extracellular matrix modulates the cellular response to growth factors and is critical for cell cycle progression. The present study was designed to address the relationship between fibronectin matrix assembly and cell shape or shape dependent cellular processes. The binding of fibronectin's amino-terminal matrix assembly domain to adherent cells represents the initial step in the assembly of exogenous fibronectin into the extracellular matrix. When added to monolayers of pulmonary artery endothelial cells, the 70 kDa fragment of fibronectin (which contains the matrix assembly domain) stabilized both the extracellular fibronectin matrix as well as the actin cytoskeleton against cytochalasin D-mediated structural reorganization. This activity appeared to require specific fibronectin sequences as fibronectin fragments containing the cell adhesion domain as well as purified vitronectin were ineffective inhibitors of cytochalasin D-induced cytoarchitectural restructuring. Such pronounced morphologic consequences associated with exposure to the 70 kDa fragment suggested that this region of the fibronectin molecule may affect specific growth traits known to be influenced by cell shape. To assess this possibility, the 70 kDa fragment was added to scrape-wounded monolayers of bovine microvessel endothelium and the effects on two shape-dependent processes (i.e. migration and proliferation) were measured as a function of time after injury and location from the wound. The addition of amino-terminal fragments of fibronectin to the monolayer significantly inhibited (by >50%) wound closure. Staining of wounded monolayers with BrdU, moreover, indicated that either the 70 kDa or 25 kDa amino-terminal fragments of fibronectin, but not the 40 kDa collagen binding fragment, also inhibited cell cycle progression. These results suggest that the binding of fibronectin's amino-terminal region to endothelial cell layers inhibits cell cycle progression by stabilizing cell

Âge 40K/ 40Ar, Carbonifère inférieur, du magmatisme basique filonien du synclinal paléozoïque de Tin Serririne, Sud-Est du Hoggar (Algérie)

NASA Astrophysics Data System (ADS)

Djellit, Hamou; Bellon, Hervé; Ouabadi, Aziouz; Derder, Mohamed E. M.; Henry, Bernard; Bayou, Boualem; Khaldi, Allaoua; Baziz, Kamal; Merahi, Mounir K.

2006-07-01

Palaeozoic formations of the Tassilis Oua-n-Ahaggar (southeastern Hoggar) include magmatic rocks in the Tin Serririne syncline. Slight contact metamorphism of the overlying bed and studies of anisotropy of magnetic susceptibility of these rocks show that the latter correspond to sills and NW-SE or north-south dykes. 40K/ 40Ar dating of separated feldspars and whole rock for one sample and of whole rock for two other samples give a mean age of 347.6±16.2Ma (at the 2- σ level), thus corresponding to a Lower Carboniferous (Tournaisian) age. Taking into account both the age of this magmatism and the stratigraphic and structural data for this region suggests that dolerites were emplaced within distensive zones that are related to the reactivation of Panafrican faults. To cite this article: H. Djellit et al., C. R. Geoscience 338 (2006).

Modeling slug tests in unconfined aquifers with both oscillatory and overdamped responses, and with low-K and high-K skin effects

NASA Astrophysics Data System (ADS)

Thoma, M. J.; Malama, B.; Barrash, W.; Bohling, G.; Butler, J. J.

2009-12-01

We extend the models for slug tests developed by Hyder et al. (1994) and Butler and Zhan (2004) to obtain a single general model for slug tests in unconfined aquifers in partially penetrating wells with a near-well disturbed zone (skin). The full range of responses, oscillatory to overdamped, is considered since both types of responses are common in wells in unconsolidated coarse fluvial aquifers, and others. The general semi-analytical solution allows for skin and formation storage as well as anisotropy in skin and formation hydraulic conductivity (K). The water table is treated as a fixed head boundary so the solution is applicable for wells screened below the water table. The model is validated by comparison with other models and by matching field data from unconfined fluvial aquifers at sites in Nebraska (MSEA) and Idaho (BHRS). We examine the effects of varying skin K and skin thickness to simulate the impact of a near-well disturbed zone that is lower (damage) or higher (filter pack) K than the formation. Results indicate that, for a given set of measured behavior at an example test zone, minor progressive decreases in estimated formation K occur with increases in assumed skin K, and moderate increases in estimated formation K occur with decreases in assumed skin K. Major increases (orders of magnitude) in estimated formation K occur with increased thickness of low-K skin. The importance of incorporating a finite-thickness representation of the skin, rather than the conventional infinitely thin representation, is also addressed.

Biomedical research with cyclotron produced radionuclides. Progress report, October 1, 1977--September 30, 1978

DOE Office of Scientific and Technical Information (OSTI.GOV)

Laughlin, J.S.; Benua, R.S.; Tilbury, R.S.

1978-09-30

Progress is reported on biomedical studies using cyclotron-produced /sup 18/F, /sup 15/O, /sup 11/C, /sup 13/N, /sup 52/Fe, /sup 38/K, /sup 206/Bi, /sup 73/Se, /sup 53/Co, and /sup 43/K. The following research projects are described: tumor detection and diagnosis; neurological studies; radiopharmaceutical development; /sup 38/K as an indicator of blood flow to the myocardium; dosimetry for internally deposited isotopes in animals and man; cyclotron development; positron tomographic imaging with the TOKIM System; and review of positron emission transaxial tomograph instruments. (HLW)

Effects of Arabia-Eurasia Collision on Strike-slip Faults in Central Anatolia?

NASA Astrophysics Data System (ADS)

Whitney, D. L.; Lefebvre, C.; Thomson, S. N.; Idleman, L.; Cosca, M. A.; Kaymakci, N.; Teyssier, C. P.; Umhoefer, P. J.

2013-12-01

The North and East Anatolian faults accommodate much of the tectonic escape of Anatolia in response to Arabia-Eurasia collision and building of the Turkish-Iranian plateau, but these structures formed <10 m.y. ago, at least 25 m.y. after the onset of collision at ~35 Ma. Some of the major strike-slip fault zones located between the North and East Anatolian faults have had long and complex histories of displacement. These faults have deformed, and in some cases exhumed, metamorphic massifs located between fault strands. One example is the Nigde Massif, which was initially exhumed in the Late Cretaceous, then reburied and reheated, along with its overlying sedimentary basin, to a depth of ~10 km at 30 × 5 Ma. Final exhumation and cooling occurred by ~15-17 Ma (massif margin) to ~12 Ma (structurally deepest levels). This depth-temperature-time-deformation history is tracked by a combination of thermobarometric methods, structural and stratigraphic analysis, and geo/thermochronometry (U-Pb zircon, monazite; 40Ar/39Ar hornblende, muscovite, biotite, K-feldspar; zircon and apatite fission-track in metamorphic rocks and basin deposits; and apatite (U-Th)/He). Recent mapping shows the presence of at least two oblique-thrust slices; the structurally higher one accounts for the resetting of detrital apatite fission track and AHe ages in the basin rocks as well as metamorphic apatite near the margin of the massif. The structurally deeper one cuts through the metamorphic basement and explains why mineral lineations and metamorphic assemblages are different along the eastern margin relative to those in the core of the massif. Although the timing of displacement has not been dated directly, low-T thermochronology age and modeling results document a perturbation at ~30 Ma, consistent with the idea that the Ecemis Fault of the Central Anatolian Fault Zone, and probably other pre-existing strike-slip faults in central Anatolia, experienced Late Eocene-Oligocene displacement in

Quantifying the Variation in Shear Zone Character with Depth: a Case Study from the Simplon Shear Zone, Central Alps

NASA Astrophysics Data System (ADS)

Cawood, T. K.; Platt, J. P.

2017-12-01

A widely-accepted model for the rheology of crustal-scale shear zones states that they comprise distributed strain at depth, in wide, high-temperature shear zones, which narrow to more localized, high-strain zones at lower temperature and shallower crustal levels. We test and quantify this model by investigating how the width, stress, temperature and deformation mechanisms change with depth in the Simplon Shear Zone (SSZ). The SSZ marks a major tectonic boundary in the central Alps, where normal-sense motion and rapid exhumation of the footwall have preserved evidence of older, deeper deformation in rocks progressively further into the currently-exposed footwall. As such, microstructures further from the brittle fault (which represents the most localized, most recently-active part of the SSZ) represent earlier, higher- temperature deformation from deeper crustal levels, while rocks closer to the fault have been overprinted by successively later, cooler deformation at shallower depths. This study uses field mapping and microstructural studies to identify zones representing deformation at various crustal levels, and characterize each in terms of zone width (representing width of the shear zone at that time and depth) and dominant deformation mechanism. In addition, quartz- (by Electron Backscatter Diffraction, EBSD) and feldspar grain size (measured optically) piezometry are used to calculate the flow stress for each zone, while the Ti-in-quartz thermometer (TitaniQ) is used to calculate the corresponding temperature of deformation. We document the presence of a broad zone in which quartz is recrystallized by the Grain Boundary Migration (GBM) mechanism and feldspar by Subgrain Rotation (SGR), which represents the broad, deep zone of deformation occurring at relatively high temperatures and low stresses. In map view, this transitions to successively narrower zones, respectively characterized by quartz SGR and feldspar Bulge Nucleation (BLG); quartz BLG and brittle

The mechanism of myrmekite formation deduced from steady-diffusion modeling based on petrography: Case study of the Okueyama granitic body, Kyushu, Japan

NASA Astrophysics Data System (ADS)

Yuguchi, Takashi; Nishiyama, Tadao

2008-12-01

Myrmekite is an intergrowth texture consisting of vermicular quartz and albitic plagioclase (Ab 93An 7 in this study), typically occurring between K-feldspar and plagioclase. It occurs ubiquitously in both metamorphic and granitic rocks; however, its genesis has been an enigma. This paper describes myrmekite's petrography and discusses its genesis from the Okueyama granitic body (OKG), which is a young (14 Ma) granite in Southwest Japan with no evidence of deformation after solidification. The genesis of a newly observed texture, the 'reaction rim', will be also discussed in relation to myrmekite. The reaction rim is an albite layer (Ab 95An 5) with no vermicular quartz between K-feldspar and plagioclase, and it occasionally makes a composite texture with myrmekite. Both myrmekite and the reaction rim are accompanied by a diffusive boundary layer (Olg-layer) with a mean composition of oligoclase (Ab 75An 25) in the rim of neighboring plagioclase rim. The overall reactions in an open system for the formation of myrmekite and that for the reaction rim are derived based on the following two models: 1) one based on the assumption of conservation of solid volume with arbitrarily specified closure components, and 2) the other based on the assumption of closure of AlO 3/2 together with an arbitrarily specified volume factor. Steady diffusion modeling in an open system based on the overall reaction thus derived defines the stability field of myrmekite and of the reaction rim in terms of the ratios of phenomenological coefficients ( L-ratios). The steady diffusion models for the above two models have essentially the same features. Myrmekite is stable for large values (> 10) of LAlAl/ LCaCa, for moderate values of LAlAl/ LSiSi, and for only small values (< 1) of LAlAl/ LNaNa. In the case of the reaction rim, the stability field is much wider in a plot of LAlAl/ LCaCa vs. LAlAl/ LNaNa, and its dependence on LAlAl/ LSiSi is stronger than that of myrmekite. The reaction rim is

Luminescence of quartz and feldspar fingerprints provenance and correlates with the source area denudation in the Amazon River basin

NASA Astrophysics Data System (ADS)

Sawakuchi, A. O.; Jain, M.; Mineli, T. D.; Nogueira, L.; Bertassoli, D. J.; Häggi, C.; Sawakuchi, H. O.; Pupim, F. N.; Grohmann, C. H.; Chiessi, C. M.; Zabel, M.; Mulitza, S.; Mazoca, C. E. M.; Cunha, D. F.

2018-06-01

The Amazon region hosts the world's largest watershed spanning from high elevation Andean terrains to lowland cratonic shield areas in tropical South America. This study explores variations in optically stimulated luminescence (OSL) and infrared stimulated luminescence (IRSL) signals in suspended silt and riverbed sands retrieved from major Amazon rivers. These rivers drain Pre-Cambrian to Cenozoic source rocks in areas with contrasting denudation rates. In contrast to the previous studies, we do not observe an increase in the OSL sensitivity of quartz with transport distance; for example, Tapajós and Xingu Rivers show more sensitive quartz than Solimões and Madeira Rivers, even though the latter have a significantly larger catchment area and longer sediment transport distance. Interestingly, high sensitivity quartz is observed in rivers draining relatively stable Central Brazil and Guiana shield areas (denudation rate ξ = 0.04 mmyr-1), while low sensitivity quartz occurs in less stable Andean terrains (ξ = 0.24 mmyr-1). An apparent linear correlation between quartz OSL sensitivity and denudation rate suggests that OSL sensitivity may be used as a proxy for erosion rates in the Amazon basin. Furthermore, luminescence sensitivity measured in sand or silt arises from the same mineral components (quartz and feldspar) and clearly discriminates between Andean and shield sediments, avoiding the grain size bias in provenance analysis. These results have implications for using luminescence sensitivity as a proxy for Andean and shield contributions in the stratigraphic record, providing a new tool to reconstruct past drainage configurations within the Amazon basin.

Na, K-ATPase subunits as markers for epithelial-mesenchymal transition in cancer and fibrosis

PubMed Central

Rajasekaran, Sigrid A.; Huynh, Thu P.; Wolle, Daniel G.; Espineda, Cromwell E.; Inge, Landon J.; Skay, Anna; Lassman, Charles; Nicholas, Susanne B.; Harper, Jeffrey F.; Reeves, Anna E.; Ahmed, Mansoor M.; Leatherman, James M; Mullin, James M.; Rajasekaran, Ayyappan K.

2010-01-01

Epithelial-to-mesenchymal transition (EMT) is an important developmental process, participates in tissue repair and occurs during pathological processes of tumor invasiveness, metastasis and tissue fibrosis. The molecular mechanisms leading to EMT are poorly understood. While it is well documented that transforming growth factor (TGF)-β plays a central role in the induction of EMT, the targets of TGF-β signaling are poorly defined. We have shown earlier that Na,K-ATPase β1-subunit levels are highly reduced in poorly differentiated kidney carcinoma cells in culture and in patients’ tumor samples. In this study, we provide evidence that Na,K-ATPase is a new target of TGF-β1-mediated EMT in renal epithelial cells, a model system used in studies of both cancer progression and fibrosis. We show that following treatment with TGF-β1 the surface expression of the β1-subunit of Na,K-ATPase is reduced, prior to well-characterized EMT markers and is associated with the acquisition of a mesenchymal phenotype. RNAi mediated knockdown confirmed the specific involvement of the Na,K-ATPase β1-subunit in the loss of the epithelial phenotype and exogenous over-expression of the Na,K-ATPase β1-subunit attenuated TGF-β1-mediated EMT. We further show that both Na,K-ATPase α- and β-subunit levels are highly reduced in renal fibrotic tissues. These findings for the first time reveal that Na,K-ATPase is a target of TGF-β1-mediated EMT and is associated with the progression of EMT in both cancer and fibrosis. PMID:20501797

Progress in the Development of a Continuous Adiabatic Demagnetization Refrigerator

NASA Technical Reports Server (NTRS)

Shirron, Peter; Canavan, Edgar; DiPirro, Michael; Jackson, Michael; King, Todd; Tuttle, James; Krebs, Carolyn A. (Technical Monitor)

2002-01-01

We report on recent progress in the development of a continuous adiabatic demagnetization refrigerator (CADR). Continuous operation avoids the constraints of long hold times and short recycle times that lead to the generally large mass of single-shot ADRs, allowing us to achieve an order of magnitude larger cooling power per unit mass. Our current design goal is 10 micro W of cooling at 50 mK using a 6-10 K heat sink. The estimated mass is less than 10 kg, including magnetic shielding of each stage. The relatively high heat rejection capability allows it to operate with a mechanical cryocooler as part of a cryogen-free, low temperature cooling system. This has the advantages of long mission life and reduced complexity and cost. We have assembled a three-stage CADR and have demonstrated continuous cooling using a superfluid helium bath as the heat sink. The temperature stability is 8 micro K rms or better over the entire cycle, and the cooling power is 2.5 micro W at 60 mK rising to 10 micro W at 100 mK.

Dissociation of sensitivities to tumor promotion and progression in outbred and inbred SENCAR mice.

PubMed

Gimenez-Conti, I B; Bianchi, A B; Fischer, S M; Reiners, J J; Conti, C J; Slaga, T J

1992-06-15

The sensitivity of outbred SENCAR mice and inbred SENCAR (SSIN) mice to multistage carcinogenesis was studied. Tumors were induced using either 7,12-dimethylbenz[a]anthracene or N-methyl-N'-nitro-N-nitrosoguanidine as initiators and 12-O-tetradecanoylphorbol-13-acetate or benzoyl peroxide as promoting agents. Although the number of papillomas per mouse was higher in SSIN than in outbred SENCAR mice, the number of carcinomas observed in the SSIN strain was significantly lower regardless of the initiator or promoter used. It was also observed that the expression of markers of premalignant progression (i.e., dysplasia, expression of keratin K13, and loss of keratin K1 expression) was markedly suppressed in SSIN papillomas. After 50 wk of promotion with 12-O-tetradecanoylphorbol-13-acetate, the pattern of expression of K13 and K1 in SSIN mice was comparable to the pattern observed in outbred SENCAR mice after 10 to 20 wk of promotion with 12-O-tetradecanoylphorbol-13-acetate. It was also observed that 67% of the tumors induced in SSIN mice by initiation with 7,12-dimethylbenz[a]anthracene exhibited a mutation in codon 61 of the Ha-ras-1 gene. This latter finding suggests that the differences observed in tumor progression between the inbred strain and the outbred stock are not related to a genetic alteration in the Ha-ras-1 gene but rather to an independent event that we have postulated to involve a putative suppressor gene. The data reported here suggest that the putative gene(s) that confers susceptibility to tumor promotion was segregated from the gene(s) involved in tumor progression during selection and inbreeding of the SENCAR mouse stock.

Time resolved quantitative imaging of charring in materials at temperatures above 1000 K

NASA Astrophysics Data System (ADS)

Böhrk, Hannah; Jemmali, Raouf

2016-07-01

A device is presented allowing for in situ investigation of chemically changing materials by means of X-ray imaging. A representative cork ablator sample, additionally instrumented with thermocouples, is encapsulated in an evacuated cell heating a sample surface with a heat flux of 230 kW/m2. The images show the sample surface and the in-depth progression of the char front dividing the char layer from the virgin material. Correlating the images to thermocouple data allows for the deduction of a reaction temperature. For the representative cork ablator investigated at the present conditions, the progression rate of the pyrolysis layer is determined to 0.0285 mm/s and pyrolysis temperature is 770 or 737 K, depending on the pre-existing conditions. It is found that the novel device is ideally suited for volume process imaging.

Linking craton stability and deep earth processes using thermochronology; a case study in the Superior Province of the Canadian Shield.

NASA Astrophysics Data System (ADS)

Sturrock, C. P.; Flowers, R. M.; Zhong, S.; Metcalf, J. R.; Kohn, B. P.

2017-12-01

Ancient, cratonic continental interiors are often presumed to be stable in the long term, neither accumulating nor shedding significant amounts of overlying sediment. However, recent low-temperature thermochronologic work suggests that such long term stability is an overly simplistic view and that forces besides plate tectonics, such as dynamic topography, may play a significant role. New apatite (U-Th)/He (AHe) and apatite fission track (AFT) data from Archean-Proterozoic basement rocks along a 1400km NW-SE transect in the Superior Province of the Canadian Shield record a spatially variable thermal history for the craton in Paleozoic through the end of Mesozoic time. Dates range from 600­­­­­­±60 Ma (AHe) and 529­±48 Ma (AFT) in the west to 184±14 Ma (AHe) and 174±9 Ma (AFT) in the east. Tectonic activity within the Superior Province ceased by 1.8 Ga, with the latest activity at the margins ending at 1 Ga. Widespread resetting of both AHe and AFT systems post 1 Ga is most likely due to regional scale burial at one or more times since the Cambrian. The temperature sensitivity of the AHe and AFT systems (30-90°C and 60-120°C, respectively) require at least a few km of burial across the craton that has since been stripped away. Preliminary inverse thermal history models, utilizing geologic constraints and radiation damage effects on He diffusion in apatite, indicate significant reheating in the Paleozoic-early Mesozoic (37 to >120°C) and a possible lesser reheating event since the mid Mesozoic (<100°C). Making the simplified assumption of a 25°C/km geothermal gradient and 0°C surface temperature, burial in some areas must have been at least 2-5km in the Paleozoic and was <4km in the Mesozoic. These burial and denudation patterns do not correlate with global sea level changes, making dynamic topography a good candidate for a driving mechanism. New AHe data from kimberlites emplaced in the early to mid-Jurassic will provide an important new constraint

Paleoproterozoic multistage metamorphic events in Jining metapelitic rocks from the Khondalite Belt in the North China Craton: Evidence from petrology, phase equilibria modelling and U-Pb geochronology

NASA Astrophysics Data System (ADS)

Cai, Jia; Liu, Fulai; Liu, Pinghua

2017-05-01

Metapelitic rocks of the Jining Complex (sillimanite-cordierite-garnet (Sil-Crd-Grt) gneisses, sillimanite-garnet (Sil-Grt) gneisses and quartzofeldspathic rocks) are exposed in the eastern segment of the Khondalite Belt (KB) in the North China Craton (NCC). The Sil-Crd-Grt gneisses have preserved polyphase mineral assemblages and microstructural evidence of anatexis, resulting from biotite dehydration melting. Petrological observations revealed that the Sil-Crd-Grt gneisses contain three metamorphic assemblages: a peak assemblage of garnet porphyroblast and matrix biotite + sillimanite + K-feldspar + plagioclase + quartz + ilmenite + magnetite, a post-peak near-isothermal decompressional assemblage of garnet + cordierite + biotite + sillimanite + K-feldspar + plagioclase + quartz + ilmenite + magnetite, and a decompressional cooling assemblage of garnet + biotite + cordierite + K-feldspar + plagioclase + quartz + ilmenite + magnetite. A clockwise P-T path was defined involving the inferred peak stage followed by post-peak near-isothermal decompression and decompressional cooling stages, with P-T conditions of 790-825 °C and 9-10 kbar, 810-890 °C and 6.0-6.5 kbar, and 780-810 °C and 4.0-5.5 kbar, respectively. Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) U-Pb analyses of the Sil-Crd-Grt gneisses and Sil-Grt gneisses for the detrital and metamorphic zircons yielded a protolith age of ∼2.0 Ga and the late Paleoproterozoic metamorphic age of 1895-1885 Ma. The results reveal that the metapelitic rocks of the Jining Complex underwent continent-continent subduction or collision in the peak metamorphic stage, followed by a post-collisional exhumation event in the post-peak decompressional stage, and a subsequent decompressional cooling stage between the Yinshan and Ordos blocks to form the Paleoproterozoic KB.

Ar-39-Ar-40 Age Dating Of Two Angrites and Two Brachinites

NASA Technical Reports Server (NTRS)

Garrison, Daniel; Bogard, Donald

2003-01-01

Angrites are a rare group (approximately 7 known) of igneous meteorites with basalt-like composition, which probably derive from a relatively small parent body that differs from those of other igneous meteorites. Angrites show evidence for extinct Mn-53, Sm-146, and Pu-244, and precise U-Pb, and Pb-Pb ages of 4.558 Gyr for two angrites define the time of early parent body differentiation. The Sm-147-Nd-143 ages of two angrites range between 4.53 +/- 0.04 and 4.56 +/- 0.04 Gyr, but no Ar-39-Ar-40 or Rb-Sr ages have been reported. Most angrites show no evidence for either shock brecciation or metamorphism. Brachinites are another very rare group' of differentiated meteorites consisting primarily of olivine, with minor augite, chromite, Fe-sulfides, and sometimes plagioclase and opx. Presence of excess Xe-129 and excess Cr53 from decay of Mn-53 in some brachinites indicate that they also formed very early. Brachinite petrogenesis is poorly defined. They may be igneous cumulates or metamorphic products of chondritic-like starting material. If after their formation, angrites and brachinites cooled quickly with minimal subsequent heating, then one might expect them to show uniquely old K-Ar ages, at least in comparison to other differentiated meteorites such as eucrites and mesosiderites. Most angrites and brachinites contain very little, if any K-feldspar, which has deterred measurements of their Ar-Ar ages. We made Ar-39-Ar-40 analyses on two angrites, LEW86010 (metamorphosed) and D'Orbigny, and on two brachinites, EET99402 and Brachina. All are finds. Any feldspar in angrites is highly calcic, with expected K concentrations of <100 ppm. We selected LEW86010 and D'Orbigny because they have been the objects of several other studies and because chemical analyses suggested [K] was approximately 70 ppm in both meteorites. Brachina contains approximately 9.9% plagioclase of higher K-content than angrites, and EET99402 is estimated to contain approximately 5% K

ELI-beamlines: progress in development of next generation short-pulse laser systems

NASA Astrophysics Data System (ADS)

Rus, B.; Bakule, P.; Kramer, D.; Naylon, J.; Thoma, J.; Fibrich, M.; Green, J. T.; Lagron, J. C.; Antipenkov, R.; Bartoníček, J.; Batysta, F.; Baše, R.; Boge, R.; Buck, S.; Cupal, J.; Drouin, M. A.; Durák, M.; Himmel, B.; Havlíček, T.; Homer, P.; Honsa, A.; Horáček, M.; Hríbek, P.; Hubáček, J.; Hubka, Z.; Kalinchenko, G.; Kasl, K.; Indra, L.; Korous, P.; Košelja, M.; Koubíková, L.; Laub, M.; Mazanec, T.; Meadows, A.; Novák, J.; Peceli, D.; Polan, J.; Snopek, D.; Šobr, V.; Trojek, P.; Tykalewicz, B.; Velpula, P.; Verhagen, E.; Vyhlídka, Å.; Weiss, J.; Haefner, C.; Bayramian, A.; Betts, S.; Erlandson, A.; Jarboe, J.; Johnson, G.; Horner, J.; Kim, D.; Koh, E.; Marshall, C.; Mason, D.; Sistrunk, E.; Smith, D.; Spinka, T.; Stanley, J.; Stolz, C.; Suratwala, T.; Telford, S.; Ditmire, T.; Gaul, E.; Donovan, M.; Frederickson, C.; Friedman, G.; Hammond, D.; Hidinger, D.; Chériaux, G.; Jochmann, A.; Kepler, M.; Malato, C.; Martinez, M.; Metzger, T.; Schultze, M.; Mason, P.; Ertel, K.; Lintern, A.; Edwards, C.; Hernandez-Gomez, C.; Collier, J.

2017-05-01

Overview of progress in construction and testing of the laser systems of ELI-Beamlines, accomplished since 2015, is presented. Good progress has been achieved in construction of all four lasers based largely on the technology of diode-pumped solid state lasers (DPSSL). The first part of the L1 laser, designed to provide 200 mJ <15 fs pulses at 1 kHz repetition rate, is up and running. The L2 is a development line employing a 10 J / 10 Hz cryogenic gas-cooled pump laser which has recently been equipped with an advanced cryogenic engine. Operation of the L3-HAPLS system, using a gas-cooled DPSSL pump laser and a Ti:sapphire broadband amplifier, was recently demonstrated at 16 J / 28 fs, at 3.33 Hz rep rate. Finally, the 5 Hz OPCPA front end of the L4 kJ laser is up running and amplification in the Nd:glass large-aperture power amplifiers was demonstrated.

Glaucoma Progression Detection by Retinal Nerve Fiber Layer Measurement Using Scanning Laser Polarimetry: Event and Trend Analysis

PubMed Central

Moon, Byung Gil; Cho, Jung Woo; Kang, Sung Yong; Yun, Sung-Cheol; Na, Jung Hwa; Lee, Youngrok; Kook, Michael S.

2012-01-01

Purpose To evaluate the use of scanning laser polarimetry (SLP, GDx VCC) to measure the retinal nerve fiber layer (RNFL) thickness in order to evaluate the progression of glaucoma. Methods Test-retest measurement variability was determined in 47 glaucomatous eyes. One eye each from 152 glaucomatous patients with at least 4 years of follow-up was enrolled. Visual field (VF) loss progression was determined by both event analysis (EA, Humphrey guided progression analysis) and trend analysis (TA, linear regression analysis of the visual field index). SLP progression was defined as a reduction of RNFL exceeding the predetermined repeatability coefficient in three consecutive exams, as compared to the baseline measure (EA). The slope of RNFL thickness change over time was determined by linear regression analysis (TA). Results Twenty-two eyes (14.5%) progressed according to the VF EA, 16 (10.5%) by VF TA, 37 (24.3%) by SLP EA and 19 (12.5%) by SLP TA. Agreement between VF and SLP progression was poor in both EA and TA (VF EA vs. SLP EA, k = 0.110; VF TA vs. SLP TA, k = 0.129). The mean (±standard deviation) progression rate of RNFL thickness as measured by SLP TA did not significantly differ between VF EA progressors and non-progressors (-0.224 ± 0.148 µm/yr vs. -0.218 ± 0.151 µm/yr, p = 0.874). SLP TA and EA showed similar levels of sensitivity when VF progression was considered as the reference standard. Conclusions RNFL thickness as measurement by SLP was shown to be capable of detecting glaucoma progression. Both EA and TA of SLP showed poor agreement with VF outcomes in detecting glaucoma progression. PMID:22670073

Prevalence and Properties of Planets from Kepler and K2

NASA Astrophysics Data System (ADS)

Petigura, Erik; Marcy, Geoffrey W.; Howard, Andrew; Crossfield, Ian; Beichman, Charles; Sinukoff, Evan

2015-12-01

Discoveries from the prime Kepler mission demonstrated that small planets (< 3 Earth-radii) are common outcomes of planet formation around G, K, and M stars. While Kepler detected many such planets, all but a handful orbit faint, distant stars, which are not amenable to precise follow up measurements. NASA's K2 mission has the potential to increase the number of known small, transiting planets around bright stars by an order of magnitude. I will present the latest results from my team's efforts to detect, confirm, and characterize planets using the K2 mission. I will highlight some of the progress and remaining challenges involved with generating denoised K2 photometry and with detecting planets in the presence of severe instrument systematics. Among our recent discoveries are the K2-3 and K2-21 planetary systems: M dwarfs hosting multiple transiting Earth-size planets with low equilibrium temperatures. These systems offer a convenient laboratory for studying the bulk composition and atmospheric properties of small planets receiving low levels of stellar irradiation, where processes such as mass loss by photo-evaporation could play a weaker role.

Precise K-Ar, 40Ar/39Ar, Rb-Sr and U/Pb mineral ages from the 27.5 Ma fish canyon tuff reference standard

USGS Publications Warehouse

Lanphere, M.A.; Baadsgaard, H.

2001-01-01

The accuracy of ages measured using the 40Ar/39Ar technique is affected by uncertainties in the age of radiation fluence-monitor minerals. At present, there is lack of agreement about the ages of certain minerals used as fluence monitors. The accuracy of the age of a standard may be improved if the age can be measured using different decay schemes. This has been done by measuring ages on minerals from the Oligocene Fish Canyon Tuff (FCT) using the K-Ar, 40Ar/39Ar. Rb-Sr and U/Pb methods. K-Ar and 40Ar/39Ar total fusion ages of sanidine, biotite and hornblende yielded a mean age of 27.57 ?? 0.36 Ma. The weighted mean 40Ar/39Ar plateau age of sanidine and biotite is 27.57 ?? 0.18 Ma. A biotite-feldspar Rb-Sr isochron yielded an age of 27.44 ?? 0.16 Ma. The U-Pb data for zircon are complex because of the presence of Precambrian zircons and inheritance of radiogenic Pb. Zircons with 207Pb/235U < 0.4 yielded a discordia line with a lower concordia intercept of 27.52 ?? 0.09 Ma. Evaluation of the combined data suggests that the best age for FCT is 27.51 Ma. Published by Elsevier Science B.V.

Electron Microprobe Analyses of Lithic Fragments and Their Minerals from Luna 20 Fines

NASA Technical Reports Server (NTRS)

Conrad, G. H.; Hlava, P. F.; Green, J. A.; Moore, R. B.; Moreland, G.; Dowty, E.; Prinz, M.; Keil, K.; Nehru, C. E.; Bunch, T. E.

1973-01-01

The bulk analyses (determined with the broad beam electron microprobe technique) of lithic fragments are given in weight percentages and are arranged according to the rock classification. Within each rock group the analyses are arranged in order of increasing FeO content. Thin section and lithic fragment numbers are given at the top of each column of analysis and correspond to the numbers recorded on photo mosaics on file in the Institute of Meteoritics. CIPW molecular norms are given for each analysis. Electron microprobe mineral analyses (given in oxide weight percentages), structural formulae and molecular end member values are presented for plagioclase, olivine, pyroxene and K-feldspar. The minerals are selected mostly from lithic fragments that were also analyzed for bulk composition. Within each mineral group the analyses are presented according to the section number and lithic fragment number. Within each lithic fragment the mineral analyses are arranged as follows: Plagioclase in order of increasing CaO; olivine and pyroexene in order of increasing FeO; and K-feldspar in order of increasing K2O. The mineral grains are identified at the top of each column of analysis by grain number and lithic fragment number.

Down-regulation of human endogenous retrovirus type K (HERV-K) viral env RNA in pancreatic cancer cells decreases cell proliferation and tumor growth

PubMed Central

Li, Ming; Radvanyi, Laszlo; Yin, Bingnan; Li, Jia; Chivukula, Raghavender; Lin, Kevin; Lu, Yue; Shen, JianJun; Chang, David Z.; Li, Donghui; Johanning, Gary L.; Wang-Johanning, Feng

2017-01-01

Purpose We investigated the role of the human endogenous retrovirus type K (HERV-K) envelope (env) gene in pancreatic cancer (PC). Experimental Design shRNA was employed to knockdown (KD) the expression of HERV-K in PC cells. Results HERV-K env expression was detected in seven PC cell lines and in 80% of PC patient biopsies, but not in two normal pancreatic cell lines or uninvolved normal tissues. A new HERV-K splice variant was discovered in several PC cell lines. RT activity and virus-like particles were observed in culture media supernatant obtained from Panc-1 and Panc-2 cells. HERV-K viral RNA levels and anti-HERV-K antibody titers were significantly higher in PC patient sera (N=106) than in normal donor sera (N=40). Importantly, the in vitro and in vivo growth rates of three PC cell lines were significantly reduced after HERV-K KD by shRNA targeting HERV-K env, and there was reduced metastasis to lung after treatment. RNA-seq results revealed changes in gene expression after HERV-K env KD, including RAS and TP53. Furthermore, downregulation of HERV-K Env protein expression by shRNA also resulted in decreased expression of RAS, p-ERK, p-RSK, and p-AKT in several PC cells or tumors. Conclusion These results demonstrate that HERV-K influences signal transduction via the RAS-ERK-RSK pathway in PC. Our data highlight the potentially important role of HERV-K in tumorigenesis and progression of PC, and indicate that HERV-K viral proteins may be attractive biomarkers and/or tumor-associated antigens, as well as potentially useful targets for detection, diagnosis and immunotherapy of PC. PMID:28679769

Ocurrence and genesis of kaolinite in sedimentary deposits from the Southern Iberian Range (Spain)

NASA Astrophysics Data System (ADS)

Bauluz, B.; Mayayo, M. J.; Yuste, A.; Fernández-Nieto, C.; González López, J. M.

2003-04-01

The kaolinite-rich clay deposits from the Southern Iberian Range (Spain) correspond to continental clay-sandy series developed during Lower Cretaceous times. The clay deposits are mined by ceramic industry nowadays, and are intercalated with coal levels (lignites) that are also mined for energetic purposes. We have characterized by XRD, optical, and electronic microscopy (SEM, TEM) the mineralogical composition of a set of 55 samples, emphasizing in the kaolinite features: texture, morphology, crystallinity, and composition. Studied rocks (lutites, limolites, and sandstones) are composed by different proportions of quartz, kaolinite, muscovite, and illite, with minor K-feldspar, pyrite and siderite. The XRD study shows that, in comparison to micaceous phases, kaolinite particles are preferentially concentrated in the finest fractions of the rocks, indicating a lower crystal size. In addition, electron microscopy observations show that kaolinite occurs in four distinct modes: (a) as subhedral-anhedral flakes (<20 μm) that are the major component of the lutites. This kaolinite shows a disordered type (XRD). Chemical composition of kaolinite and illite particles (TEM/AEM) show a broad compositional variation. Some of the particles correspond to kaolinite and illite compositions, but most of the analyses indicate intermediate compositions, suggesting the occurrence of submicroscopic intergrowths of kaolinite and illite. The detection of low Ca contents in some analyses indicate the presence of smectite phases in these intergrowths. Probably, this kaolinite was formed by alteration of aluminosilicates (micas and K-feldspars) in the source area of the sediments. (b) as flakes filling pyritized plants in some dark lutites. (c) as subhedral and hexagonal plates, up to 5 μm in size, in sandstones. They are replacing K-feldspar fragments with clear evidence of alteration under SEM. The kaolinites display a high degree of order. (d) as booklets of pseudo-hexagonal plates of

Building a viable decollement geometry for the Central Nepal Himalaya through integrating surface geology, thermochronology and data from the 2015 Gorkha Earthquake

NASA Astrophysics Data System (ADS)

Ghoshal, S.; McQuarrie, N.; Robinson, D. M.; Olree, E.; Valentino, C.; Olsen, J.

2017-12-01

geometry, allowing us to evaluate the different proposed cross-section geometries, and identify the best match to the regional distribution of cooling ages. We argue that this final geometry is the most accurate representation of the subsurface, being constrained by surface geology, thermochronological ages, and data from the earthquake.

Design and test of the 172K fluidic rudder

NASA Technical Reports Server (NTRS)

Belsterling, C. A.

1978-01-01

Progress in the development of concepts for control of aircraft without moving parts or a separate source of power is described. The design and wind tunnel tests of a full scale fluidic rudder for a Cessna 172K aircraft, intended for subsequent flight tests were documented. The 172K fluidic rudder was designed to provide a control force equivalent to 3.3 degrees of deflection of the conventional rudder. In spite of an extremely thin airfoil, cascaded fluidic amplifiers were built to fit, with the capacity for generating the required level of control force. Wind tunnel tests demonstrated that the principles of lift control using ram air power are sound and reliable under all flight conditions. The tests also demonstrated that the performance of the 172K fluidic rudder is not acceptable for flight tests until the design of the scoop is modified to prevent interference with the lift control phenomenon.

Specialized Functional Diversity and Interactions of the Na,K-ATPase

PubMed Central

Matchkov, Vladimir V.; Krivoi, Igor I.

2016-01-01

Na,K-ATPase is a protein ubiquitously expressed in the plasma membrane of all animal cells and vitally essential for their functions. A specialized functional diversity of the Na,K-ATPase isozymes is provided by molecular heterogeneity, distinct subcellular localizations, and functional interactions with molecular environment. Studies over the last decades clearly demonstrated complex and isoform-specific reciprocal functional interactions between the Na,K-ATPase and neighboring proteins and lipids. These interactions are enabled by a spatially restricted ion homeostasis, direct protein-protein/lipid interactions, and protein kinase signaling pathways. In addition to its “classical” function in ion translocation, the Na,K-ATPase is now considered as one of the most important signaling molecules in neuronal, epithelial, skeletal, cardiac and vascular tissues. Accordingly, the Na,K-ATPase forms specialized sub-cellular multimolecular microdomains which act as receptors to circulating endogenous cardiotonic steroids (CTS) triggering a number of signaling pathways. Changes in these endogenous cardiotonic steroid levels and initiated signaling responses have significant adaptive values for tissues and whole organisms under numerous physiological and pathophysiological conditions. This review discusses recent progress in the studies of functional interactions between the Na,K-ATPase and molecular microenvironment, the Na,K-ATPase-dependent signaling pathways and their significance for diversity of cell function. PMID:27252653

The omega-3 polyunsaturated fatty acid docosahexaenoic acid inhibits proliferation and progression of non-small cell lung cancer cells through the reactive oxygen species-mediated inactivation of the PI3K /Akt pathway.

PubMed

Yin, Yuanqin; Sui, Chengguang; Meng, Fandong; Ma, Ping; Jiang, Youhong

2017-05-03

Docosahexaenoic acid(DHA) inhibits tumor growth and progression in various cancers, including lung cancer. However, the mechanisms involved remain unclear. The aim of this study was to identify the mechanism of DHA in inhibiting progression of non-small cell lung cancer (NSCLC) in vitro. The proliferation of A549 was tested by MTT, and cell apoptosis was analysed using flow cytometer. The migration and invasion were examined respectively by wound healing assay and Transwell invasion assay. The level of ROS (reactive oxygen species, ROS) was checked by DCF (dichlorodihydrofluorescein, DCF) production in cells. The apoptosis associated protein (caspase-3, PARP,Bax,Bcl-2 and survivin) and metastases associated proteins including HEF1, MMP9 and VEGF were detected by Western blot, and the same method was used in the expression of PI3K and Akt. DHA inhibited proliferation and induced apoptosis of A549 cells. Moreover, it suppressed the invasion and metastasis of A549 cells, while downregulating the levels of metastasis-associated proteins, including HEF1, matrix metallopeptidase (MMP9), and vascular endothelial growth factor (VEGF), in a dose -dependent manner. In addition, DHA inactivated Akt phosphorylation. All of these responses were associated with the accumulation of intracellular ROS. DHA downregulated the level of antioxidant enzymes such as catalase, while the antioxidant N-acetyl-cysteine (NAC) reversed the effect of DHA, which further validated our findings. The present study demonstrates that DHA inhibits the development of non-small lung tumors through an ROS-mediated inactivation of the PI3K/Akt signaling pathway.

The Taili-Yiwulüshan metamorphic core complex corridor: Diachronous exhumation and relationships to the adjacent basins based on new 40Ar/39Ar and (U-Th-Sm)/He mineral ages

NASA Astrophysics Data System (ADS)

Liang, Chenyue; Neubauer, Franz; Liu, Yongjiang; Genser, Johann; Dunkl, István; Heberer, Bianca; Jin, Wei; Zeng, Zuoxun; Li, Weimin; Wen, Quanbo; Li, Jing

2015-04-01

The Xingcheng-Taili ductile shear zone (western Liaoning Province in China) formed during latest Jurassic to Early Cretaceous crustal extension of the eastern North China craton, and exhumed low to medium metamorphic grade Archean, Upper Triassic and Upper Jurassic granitic rocks. The Mesozoic Yiwulüshan metamorphic core complex (Yiwulüshan MCC) is dominated by a NNE-SSW elongated dome with a left-lateral shear zone, which is located in the northeastern part of Xingcheng-Taili ductile shear zone, and combine as Taili-Yiwulüshan metamorphic core complex corridor. To the east, it is bounded by the NNE-trending Cretaceous to Eocene Liaohe basin (the northern extension of the Bohai Bay basin), and to the west by the Cretaceous-aged Fuxin-Yixian basin, which could potentially interpreted as supra-detachment basins. Here, we present results from a multi-method thermochronological study and coupled with structural investigations and sections of adjacent supra-detachment basins, which constrain the timing of regional deformation as well as the cooling history and exhumation processes of the low- to middle-grade metamorphic complex in the Taili-Yiwulüshan MCC corridor, in order to understand the mode of lithospheric scale reactivation, extension and thinning of the North China craton. The new40Ar/39Ar muscovite, biotite, K-feldspar and (U-Th)/He apatite ages from granitic rocks help constrain the thermal evolution during its exhumation. The thermochronologic studies have shown at least three stages of exhumation and cooling from late Jurassic to Eocene in Xingcheng-Taili shear zone should be distinguished, e.g., ~ 150-130 Ma, 130-115 Ma and 115-52 Ma, respectively. Diachronous onset and subsequent parallel cooling and exhumation characterize the early thermal history. The Yiwulüshan MCC has a similar exhumation history from 135 to 97 Ma with a similar cooling history. The development of Taili-Yiwulüshan MCC corridor is associated with synkinematic emplacement

Intrusive rocks of the Wadi Hamad Area, North Eastern Desert, Egypt: Change of magma composition with maturity of Neoproterozoic continental island arc and the role of collisional plutonism in the differentiation of arc crust

NASA Astrophysics Data System (ADS)

Basta, Fawzy F.; Maurice, Ayman E.; Bakhit, Bottros R.; Azer, Mokhles K.; El-Sobky, Atef F.

2017-09-01

The igneous rocks of the Wadi Hamad area are exposed in the northernmost segment of the Arabian-Nubian Shield (ANS). These rocks represent part of crustal section of Neoproterozoic continental island arc which is intruded by late to post-collisional alkali feldspar granites. The subduction-related intrusives comprise earlier gabbro-diorites and later granodiorites-granites. Subduction setting of these intrusives is indicated by medium- to high-K calc-alkaline affinity, Ta-Nb troughs on the spider diagrams and pyroxene and biotite compositions similar to those crystallized from arc magmas. The collisional alkali feldspar granites have high-K highly fractionated calc-alkaline nature and their spider diagrams almost devoid of Ta-Nb troughs. The earlier subduction gabbro-diorites have lower alkalis, LREE, Nb, Zr and Hf values compared with the later subduction granodiorites-granites, which display more LILE-enriched spider diagrams with shallower Ta-Nb troughs, reflecting variation of magma composition with arc evolution. The later subduction granitoids were generated by lower degree of partial melting of mantle wedge and contain higher arc crustal component compared with the earlier subduction gabbro-diorites. The highly silicic alkali feldspar granites represent extensively evolved melts derived from partial melting of intermediate arc crustal sources during the collisional stage. Re-melting of arc crustal sources during the collisional stage results in geochemical differentiation of the continental arc crust and the silicic collisional plutonism drives the composition of its upper part towards that of mature continental crust.

Micro-X-Ray computed tomography of natural and experimental melt segregations and other geological materials with small absorption contrasts

NASA Astrophysics Data System (ADS)

Baumgartner, L.; Wohlers, A.; Müller, T.

2003-04-01

Micro X-ray tomography is rapidly advancing to an important tool for non-destructive 3-D imaging of geological and engineering materials. We have been using a Skyscan 1072 system (Skyscan, Belgium) to successfully image as diverse geological materials as sandstones, foraminifers, run products of hydrothermal partial melting experiments, and metamorphic rocks. The system has a conical x-ray source with a spot size of about 5µm. The X-ray source is powered by a 10W, 20--100kV, tunable supply. Images are acquired with a scintillator coupled by glass fiber optics to a 1024×1024 pixel, 12-bit CCD. The sample is rotated for 180^o (or 360^o) in steps as small as 0.24^o. Transmission image are back projected, using a Feldkamp algorithm, into a stack of up to 1000 1K×1K images, each of which represents a horizontal cross section of the sample. We have succeeded to image very low contrast systems (feldspar/quartz and olivine/calcite/dolomite), by using extended acquisition times (up to 24 hours), and low excitation voltages (30--40kV) in combination with aluminum filters to reduce beam hardening. Some quartzites collected in the Little Cottonwood contact aureole have been infiltrated by a pegmatitic liquid. These liquids are the products of partial melting in intercalated meta-pelites. 2-D images (thin sections) clearly show, that poly-crystalline interstitial feldspar and mica represent precipitates from the infiltrated pegmatitic liquid (acute quartz-feldspar junctions similar to melting experiments). The micro-CT images reveal a thin mica-feldspar network. It forms highly anastomosing, multiply interconnected networks surrounding quartz grains. They connect larger, up to 1mm sized ponds, located in triple junctions. These results have important consequences for porous melt transport in shallow crustal rocks. Micro-CT images of spinifex textured olivine in marbles from the Ubehebe Peak contact aureole (Death Valley, California) reveal two preferential growth

Optical and TEM study of shock metamorphism from the Sedan test site

NASA Technical Reports Server (NTRS)

Gratz, A. J.

1992-01-01

Thus far, detailed petrologic studies of shock metamorphism have been performed on samples recovered from laboratory experiments and on a few natural impactites. The loading history of these samples is quite different: In particular, laboratory experiments spend only a short time (less than 1 microsec) at peak pressure, whereas natural impactites may have stress pulses from 0.1 - 1 ms. On the other hand, laboratory experiments have known stress histories; natural impactites do not. Natural samples are also subjected to thousands or millions of years of postshock annealing and/or weathering. A useful intermediate case is that of nuclear detonation. Stress pulses for these events can reach 0.1 ms or higher, and samples are obtained in pristine condition. All three types of loading produce stresses of hundreds of kilobars. Samples studied were taken from the Sedan nulcear test site, and consist of a coarse-grained granodiorite containing quartz, K-feldspar, cordierite, and hornblende. Samples were studied optically in this section, then were thinned with an ion mill and studied by transmission electron microscopy (TEM). Optically, quartz and K-feldspar displayed numerous sets of planar deformation features (PDF's) identical to the nondecorated PDF's seen in laboratory samples and many natural impactites. TEM study showed that the PDF's in quartz and feldspar corresponded to densely packed wide transformation lamellae identical to those described in laboratory studies. The transformation lamellae in both minerals were amorphous, with no sign of high-pressure phases. In the case of K-feldspar only, narrow sublamellae extended outward from some wide lamellae. Quartz, which was more abundant and studied more extensively, contained no shock-induced dislocations. Some planar features were also seen in cordierite, but could not be identified due to rapid beam damage. No shock defects were seen in hornblende in TEM. The shock-induced defects present at the Sedan site are very

Conceptions of Progress: How Is Progress Perceived? Mainstream versus Alternative Conceptions of Progress

ERIC Educational Resources Information Center

Itay, Anat

2009-01-01

Progress is a powerful political concept, encompassing different and sometimes contradictory conceptions. This paper examines the results of a survey on progress conducted at the OECD World Forum entitled "Measuring and Fostering the Progress of Societies" held in Istanbul in June 2007. First, a distinction is drawn between the two approaches to…