Dark-field transmission electron microscopy and the Debye-Waller factor of graphene.

PubMed

Shevitski, Brian; Mecklenburg, Matthew; Hubbard, William A; White, E R; Dawson, Ben; Lodge, M S; Ishigami, Masa; Regan, B C

2013-01-15

Graphene's structure bears on both the material's electronic properties and fundamental questions about long range order in two-dimensional crystals. We present an analytic calculation of selected area electron diffraction from multi-layer graphene and compare it with data from samples prepared by chemical vapor deposition and mechanical exfoliation. A single layer scatters only 0.5% of the incident electrons, so this kinematical calculation can be considered reliable for five or fewer layers. Dark-field transmission electron micrographs of multi-layer graphene illustrate how knowledge of the diffraction peak intensities can be applied for rapid mapping of thickness, stacking, and grain boundaries. The diffraction peak intensities also depend on the mean-square displacement of atoms from their ideal lattice locations, which is parameterized by a Debye-Waller factor. We measure the Debye-Waller factor of a suspended monolayer of exfoliated graphene and find a result consistent with an estimate based on the Debye model. For laboratory-scale graphene samples, finite size effects are sufficient to stabilize the graphene lattice against melting, indicating that ripples in the third dimension are not necessary.

Testing the Deployment Repeatability of a Precision Deployable Boom Prototype for the Proposed SWOT Karin Instrument

NASA Technical Reports Server (NTRS)

Agnes, Gregory S.; Waldman, Jeff; Hughes, Richard; Peterson, Lee D.

2015-01-01

NASA's proposed Surface Water Ocean Topography (SWOT) mission, scheduled to launch in 2020, would provide critical information about Earth's oceans, ocean circulation, fresh water storage, and river discharge. The mission concept calls for a dual-antenna Ka-band radar interferometer instrument, known as KaRIn, that would map the height of water globally along two 50 km wide swaths. The KaRIn antennas, which would be separated by 10 meters on either side of the spacecraft, would need to be precisely deployable in order to meet demanding pointing requirements. Consequently, an effort was undertaken to design build and prototype a precision deployable Mast for the KaRIn instrument. Each mast was 4.5-m long with a required dilitation stability of 2.5 microns over 3 minutes. It required a minimum first mode of 7 Hz. Deployment repeatability was less than +/- 7 arcsec in all three rotation directions. Overall mass could not exceed 41.5 Kg including any actuators and thermal blanketing. This set of requirements meant the boom had to be three times lighter and two orders of magnitude more precise than the existing state of the art for deployable booms.

A Surrogate for Debye-Waller Factors from Dynamic Stokes Shifts

PubMed Central

Zhong, Qin; Johnson, Jerainne; Aamer, Khaled A.; Tyagi, Madhusudan

2011-01-01

We show that the short-time behavior of time-resolved fluorescence Stokes shifts (TRSS) are similar to that of the intermediate scattering function obtained from neutron scattering at q near the peak in the static structure factor for glycerol. This allows us to extract a Debye-Waller (DW) factor analog from TRSS data at times as short as 1 ps in a relatively simple way. Using the time-domain relaxation data obtained by this method we show that DW factors evaluated at times ≥ 40 ps can be directly influenced by α relaxation and thus should be used with caution when evaluating relationships between fast and slow dynamics in glassforming systems. PMID:21701673

Thermodynamic properties of semiconductor compounds studied based on Debye-Waller factors

NASA Astrophysics Data System (ADS)

Van Hung, Nguyen; Toan, Nguyen Cong; Ba Duc, Nguyen; Vuong, Dinh Quoc

2015-08-01

Thermodynamic properties of semiconductor compounds have been studied based on Debye-Waller factors (DWFs) described by the mean square displacement (MSD) which has close relation with the mean square relative displacement (MSRD). Their analytical expressions have been derived based on the statistical moment method (SMM) and the empirical many-body Stillinger-Weber potentials. Numerical results for the MSDs of GaAs, GaP, InP, InSb, which have zinc-blende structure, are found to be in reasonable agreement with experiment and other theories. This paper shows that an elements value for MSD is dependent on the binary semiconductor compound within which it resides.

Ab Initio Calculation of XAFS Debye-Waller Factors for Crystalline Materials

NASA Astrophysics Data System (ADS)

Dimakis, Nicholas

2007-02-01

A direct an accurate technique for calculating the thermal X-ray absorption fine structure (XAFS) Debye-Waller factors (DWF) for materials of crystalline structure is presented. Using the Density Functional Theory (DFT) under the hybrid X3LYP functional, a library of MnO spin—optimized clusters are built and their phonon spectrum properties are calculated; these properties in the form of normal mode eigenfrequencies and eigenvectors are in turn used for calculation of the single and multiple scattering XAFS DWF. DWF obtained via this technique are temperature dependent expressions and can be used to substantially reduce the number of fitting parameters when experimental spectra are fitted with a hypothetical structure without any ad hoc assumptions. Due to the high computational demand a hybrid approach of mixing the DFT calculated DWF with the correlated Debye model for inner and outer shells respectively is presented. DFT obtained DWFs are compared with corresponding values from experimental XAFS spectra on manganosite. The cluster size effect and the spin parameter on the DFT calculated DWFs are discussed.

Limits of metastability in amorphous ices: the neutron scattering Debye-Waller factor.

PubMed

Amann-Winkel, Katrin; Löw, Florian; Handle, Philip H; Knoll, Wiebke; Peters, Judith; Geil, Burkhard; Fujara, Franz; Loerting, Thomas

2012-12-21

Recently, it became clear that relaxation effects in amorphous ices play a very important role that has previously been overlooked. The thermodynamic history of amorphous samples strongly affects their transition behavior. In particular, well-relaxed samples show higher thermal stability, thereby providing a larger window to investigate their glass transitions. We here present neutron scattering experiments using fixed elastic window scans on relaxed forms of amorphous ice, namely expanded high density amorphous ice (eHDA), a variant of low density amorphous ice (LDA-II) and hyperquenched glassy water (HGW). These amorphous ices are expected to be true glassy counterparts of deeply supercooled liquid water, therefore fast precursor dynamics of structural relaxation are expected to appear below the calorimetric glass transition temperature. The Debye-Waller factor shows a very weak sub-T(g) anomaly in some of the samples, which might be the signature of such fast precursor dynamics. However, we cannot find this behavior consistently in all samples at all reciprocal length scales of momentum transfer.

The Ironic Hypocrisy of Killing: How Sanctioned Counterinsurgency Policies of the Philippine War Ends in the Court-Martial of Major Littleton Waller

DTIC Science & Technology

2013-04-01

Both civilian and military leaders dehumanized the Philippine people through predisposed racial socioeconomic stereotypes which were not uncommon in... dehumanized by his military and civilian superiors. While no defense will be made in support for Maj Waller specifically, when taken into context, his...States that dehumanized the Filipino, thus legitimizing, in the minds of U.S. soldiers, brutal measures such as burning villages, torture and executions

Search for anisotropy in the Debye-Waller factor of HCP solid 4He

NASA Astrophysics Data System (ADS)

Barnes, Ashleigh L.; Hinde, Robert J.

2016-02-01

The properties of hexagonal close packed (hcp) solid 4He are dominated by large atomic zero point motions. An accurate description of these motions is therefore necessary in order to accurately calculate the properties of the system, such as the Debye-Waller (DW) factors. A recent neutron scattering experiment reported significant anisotropy in the in-plane and out-of-plane DW factors for hcp solid 4He at low temperatures, where thermal effects are negligible and only zero-point motions are expected to contribute. By contrast, no such anisotropy was observed either in earlier experiments or in path integral Monte Carlo (PIMC) simulations of solid hcp 4He. However, the earlier experiments and the PIMC simulations were both carried out at higher temperatures where thermal effects could be substantial. We seek to understand the cause of this discrepancy through variational quantum Monte Carlo simulations utilizing an accurate pair potential and a modified trial wavefunction which allows for anisotropy. Near the melting density, we find no anisotropy in an ideal hcp 4He crystal. A theoretical equation of state is derived from the calculated energies of the ideal crystal over a range of molar volumes from 7.88 to 21.3 cm3, and is found to be in good qualitative agreement with experimental data.

Onboard Interferometric SAR Processor for the Ka-Band Radar Interferometer (KaRIn)

NASA Technical Reports Server (NTRS)

Esteban-Fernandez, Daniel; Rodriquez, Ernesto; Peral, Eva; Clark, Duane I.; Wu, Xiaoqing

2011-01-01

An interferometric synthetic aperture radar (SAR) onboard processor concept and algorithm has been developed for the Ka-band radar interferometer (KaRIn) instrument on the Surface and Ocean Topography (SWOT) mission. This is a mission- critical subsystem that will perform interferometric SAR processing and multi-look averaging over the oceans to decrease the data rate by three orders of magnitude, and therefore enable the downlink of the radar data to the ground. The onboard processor performs demodulation, range compression, coregistration, and re-sampling, and forms nine azimuth squinted beams. For each of them, an interferogram is generated, including common-band spectral filtering to improve correlation, followed by averaging to the final 1 1-km ground resolution pixel. The onboard processor has been prototyped on a custom FPGA-based cPCI board, which will be part of the radar s digital subsystem. The level of complexity of this technology, dictated by the implementation of interferometric SAR processing at high resolution, the extremely tight level of accuracy required, and its implementation on FPGAs are unprecedented at the time of this reporting for an onboard processor for flight applications.

The Debate on Dominant Culture and Cultural Imperialism

ERIC Educational Resources Information Center

Anchan, John P.

2012-01-01

In this commentary, the author reviews in depth Roland S. Persson's (2012a) target article. According to him Persson (2012a) presents a convincing argument as he wove through examples and explanations. The idea of superculture connects well with the established neocolonial literature and the North-South/Centre-Periphery debate. From general to…

A Catalyst for Charting a Path to Research Validity in the Field of Gifted Education

ERIC Educational Resources Information Center

Sisk, Dorothy A.

2012-01-01

Roland S. Persson's (2012a) article addresses a concern that many educators have stressed in their theoretical models, namely the importance of the interaction between the individual and the environment, and the impact of culture on not only values and beliefs, but on behaviour. As Persson (2012a) points out these models all have merit, but he…

Moral bioenhancement and agential risks: Good and bad outcomes.

PubMed

Torres, Phil

2017-11-01

In Unfit for the Future, Ingmar Persson and Julian Savulescu argue that our collective existetial predicment is unprecedentedly dangerous due to climate change and terrorism. Given these global risks to human prosperity and survival, Persson and Savulescu argue that we should explore the radical possibility of moral bioenhancement in addition to cognitive enhancement. In this article, I argue that moral bioenhancements could nontrivially exacerbate the threat posed by certain kinds of malicious agents, while reducing the threat of other kinds. This introduces a previously undiscussed complication to Persson and Savulescu's proposal. In the final section, I present a novel argument for why moral bioenhancement should either be compulsory or not be made available to the public at all. © 2017 John Wiley & Sons Ltd.

Joint Capabilities for Post-Conflict Operations

DTIC Science & Technology

2004-05-01

Political Geography (NY: John Wiley & Sons, 1989), 37. 2 Karin von Hippel , “Democracy by Force: A Renewed Commitment to Nation Building,” The...fear. Democratic states are vital to international security. In an article adapted from her book, Democracy by Force, Karin von Hippel , a civil...Parameters 33 (Autumn 2003) 101. 5 Karin von Hippel , “Democracy by Force: A Renewed Commitment to Nation Building,” The Washington Quarterly 23 (Winter

Constitutive Activation of NF-kappaB in Prostate Carcinoma Cells Through a Positive Feedback Loop: Implication of Inducible IKK-Related Kinase (IKKi)

DTIC Science & Technology

2006-08-01

to IkB kinases. Intenational Immunology. 11: 1357-1362, 1999. 3. Greten FR, Karin M. The IKK/NF-kappaB activation pathway-a target for prevention...is in turn NF- kB-dependent, is typical for tumor cells (Orlowski and Baldwin, 2002; Zerbini et al., 2003; Greten and Karin, 2004). Those cytokines...Polo JR. (2000). J Neurochem 75: 1377–1389. Greten FR, Karin M. (2004). Cancer Lett 206: 193–199. Gupta S, Afaq F, Mukhtar H. (2002). Oncogene 21: 3727

'Am I Sexually Abused?' Consent in a Coach-Athlete Lesbian Relationship

ERIC Educational Resources Information Center

Johansson, Susanne

2018-01-01

Elite-athlete Karin was 17 years old when the considerably older team coach Selma became her girlfriend. Responding to calls to prevent harm and sexual abuse in sport, this study represents Karin's story, investigates how she makes sense of her coach-athlete sexual relationship, and analyses what can be learnt about consent. Although sexual…

German General Staff Officer Education and Current Challenges

DTIC Science & Technology

2006-05-25

Dempsey, Fool’s Errands: America’s Recent Encounters with Nation Building, Washington, D.C. 2001; Bruce R. Pirnie, and Corazon M . Francisco, Assessing...Gladstone, Afghanistan Revisited, New York 2001; Antonio Donini , Norah Niland, and Karin Wermester, Nation-Building Unraveled?: Aid, Peace, and Justice...nation-building: from Germany to Iraq, Santa Monica, Arlington, Pittsburgh, Rand, 2003. Donini , Antonio, Norah Niland, and Karin Wermester, Nation

The Role of Stat3 Activation in Androgen Receptor Signaling and Prostate Cancer

DTIC Science & Technology

2006-07-01

S. C. & Xiao, G. (2003) Cancer Metastasis Rev. 22, 405–422. 10. Karin, M. & Greten , F. R. (2005) Nat. Rev. Immunol. 5, 749–759. 11. Karin, M., Cao, Y... Greten , F. R. & Li, Z. W. (2002) Nat. Rev. Cancer 2, 301–310. 12. Fan, C. M. & Maniatis, T. (1991) Nature 354, 395–398. 13. Betts, J. C. & Nabel, G

The Nuclear Death Domain Protein p84N5; A Candidate Breast Cancer Susceptibility Gene

DTIC Science & Technology

2007-05-01

hallmarks of cancer. Cell 100, 57-70, 2000. 35. Karin M, Cao Y, Greten FR, Li ZW. NF-kappaB in cancer: from innocent bystander to major culprit. Nat Rev...D., and Weinberg, R. A. (2000) Cell 100, 57-70 46. Karin, M., Cao, Y., Greten , F. R., and Li, Z. W. (2002) Nat Rev Cancer 2, 301-310 47. Cogswell, P

Structural Origin of Enhanced Dynamics at the Surface of a Glassy Alloy

NASA Astrophysics Data System (ADS)

Sun, Gang; Saw, Shibu; Douglass, Ian; Harrowell, Peter

2017-12-01

The enhancement of mobility at the surface of an amorphous alloy is studied using a combination of molecular dynamic simulations and normal mode analysis of the nonuniform distribution of Debye-Waller factors. The increased mobility at the surface is found to be associated with the appearance of Arrhenius temperature dependence. We show that the transverse Debye-Waller factor exhibits a peak at the surface. Over the accessible temperature range, we find that the bulk and surface diffusion coefficients obey the same empirical relationship with the respective Debye-Waller factors. Extrapolating this relationship to lower T , we argue that the observed decrease in the constraint at the surface is sufficient to account for the experimentally observed surface enhancement of mobility.

Proteomics: Determining Impacts on Health From Energy, Environment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rodland, Karin

Meet PNNL Cancer Biologist Karin Rodland. Karin sees a day when people no longer die from cancer. On this day, we will have the ability to detect the deadly disease early, well before tumors metastasize and spread. When masses are detected while still small and localized, they can be completely surgically removed. Karin is leveraging PNNL’s capabilities in analytical chemistry and proteomics—or the study of proteins, their structures and functions—in a search for cancer biomarkers that may reveal cancer at its earliest stages. PNNL researchers conduct studies and experiments to understand biological systems to advance DOE’s energy and environment missions.more » Our research contributes to bioenergy and bioremediation, as well as enabling the early detection of disease and improving therapies.« less

Immune Suppression and Inflammation in the Progression of Breast Cancer

DTIC Science & Technology

2008-03-01

CD14 association with complement receptor type 3, which is reversed by neutrophil adhesion. J Immunol 1996;156:430-3. 27. Karin M, Greten FR. NF...52. Greten FR, Eckmann L, Greten TF, et al. IKKbeta links inflammation and tumorigenesis in a mouse model of colitis-associated cancer. Cell...ceramide docking to CD14 provokes ligand-specific receptor clustering in rafts. Eur J Immunol 2001;31:3153-64. 26. Karin M, Greten FR. NF-kappaB

Annual compilation and analysis of hydrologic data for urban studies in the Austin, Texas Metropolitan Area, 1971

USGS Publications Warehouse

Tovar, F.H.

1973-01-01

The U.S. Geological Survey, in cooperation with the Texas Water Development Board, began hydrologic studies in the Austin urban area in 1954. The objectives of this project are as follows: 1. To determine the effects of progressive urbanization on infiltration, rates of peak discharge, and rainfall-runoff relations in the Waller Creek watershed. 2. To provide rainfall-and-runoff data from the rural Wilbarger Creek watershed to be used for comparative purposes in determining the effects of existing and progressive urbanization in the Waller Creek watershed. 3. To provide applied research facilities for studies at the University of Texas at Austin. The purpose of this report is to present rainfall-and-runoff data for the Waller Creek and Wilbarger Creek study areas for the 1971 water year (October 1, 1970, to September 30, 1971). To facilitate the publication and distribution of this report at the earliest feasible time, certain material has been included that does not conform to the formal publication standards of the U.S. Geological Survey.

Karin Sinclair | NREL

Science.gov Websites

effort under the Distributed Wind research portfolio focused on supporting the distributed wind sector to reduce the levelized cost of energy and increase the number of certified turbines for distributed

East-West Cultural Bias and Creativity: We Are Alike and We Are Different

ERIC Educational Resources Information Center

Kaufman, James C.; Lan, Lan

2012-01-01

Persson (2012a) correctly raises the question of how cultural biases may impact giftedness research. He alludes to East-West differences in perceptions of creativity and ways that the collectivist-individualistic approaches may lead to differences in creativity perception. In this commentary, the authors discuss different approaches, and attempt…

"small problems, Big Trouble": An Art and Science Collaborative Exhibition Reflecting Seemingly small problems Leading to Big Threats

NASA Astrophysics Data System (ADS)

Waller, J. L.; Brey, J. A.

2014-12-01

"small problems, Big Trouble" (spBT) is an exhibition of artist Judith Waller's paintings accompanied by text panels written by Earth scientist Dr. James A. Brey and several science researchers and educators. The text panels' message is as much the focus of the show as the art--true interdisciplinarity! Waller and Brey's history of art and earth science collaborations include the successful exhibition "Layers: Places in Peril". New in spBT is extended collaboration with other scientists in order to create awareness of geoscience and other subjects (i.e. soil, parasites, dust, pollutants, invasive species, carbon, ground water contaminants, solar wind) small in scale which pose significant threats. The paintings are the size of a mirror, a symbol suggesting the problems depicted are those we increasingly need to face, noting our collective reflections of shared current and future reality. Naturalistic rendering and abstract form in the art helps reach a broad audience including those familiar with art and those familiar with science. The goal is that gallery visitors gain greater appreciation and understanding of both—and of the sober content of the show as a whole. "small problems, Big Trouble" premiers in Wisconsin April, 2015. As in previous collaborations, Waller and Brey actively utilize art and science (specifically geoscience) as an educational vehicle for active student learning. Planned are interdisciplinary university and area high school activities linked through spBT. The exhibition in a public gallery offers a means to enhance community awareness of and action on scientific issues through art's power to engage people on an emotional level. This AGU presentation includes a description of past Waller and Brey activities: incorporating art and earth science in lab and studio classrooms, producing gallery and museum exhibitions and delivering workshops and other presentations. They also describe how walking the paths of several past earth science

The Recognition of Cultural Bias in Researching Those Labelled Gifted: An Overdue Perspective

ERIC Educational Resources Information Center

Mazzoli Smith, L.; Campbell, R. J.

2012-01-01

This commentary addresses the analysis in Persson's (2012a) article. According to the authors, the agenda for change amongst scholars has four productive proposals. These are: (1) that scholars should broaden their disciplinary outlook beyond psychology and education; (2) that they should eschew policy borrowing; (3) that they should clarify, for…

IFLA General Conference, 1990. Division of Collections and Services: Section of Acquisition and Exchange; Section of Interlending and Document Delivery, Section of Serial Publications. Booklet 5.

ERIC Educational Resources Information Center

International Federation of Library Associations, The Hague (Netherlands).

The 25 papers in this collection were presented at the meetings of three sections of the Division of Collections and Services and a workshop: (1) "Survey of International Exchange of Non-Official Publications: Progress Report" (Ulla Hojsgaard); (2) "Buying Media for Everyone: Public Library Acquisition in Scandinavia" (Tove Persson); (3) "The…

In the Shadows of Dominant Cultures: The Elusive Definition of Giftedness

ERIC Educational Resources Information Center

Polyzoi, Eleoussa; Haydey, Donna Copsey

2012-01-01

In this commentary, the authors contend that Persson's (2012a) paper, Cultural Variation and Dominance in a Globalised Knowledge-Economy: Towards a Culture-Sensitive Research Paradigm in the Science of Giftedness, lacks conciseness in defining the connections between the significance of cultural dominance and the definition of giftedness. However,…

On Universals, Cultural Variations and Individual Uniqueness: Throwing down the Gauntlet in Giftedness Research

ERIC Educational Resources Information Center

Garces-Bacsal, Rhoda Myra

2012-01-01

Roland S. Persson's (2012a) piece is extremely comprehensive, timely and very relevant especially in light of a growing appreciation of cultural diversity and the emergence of a global community--which is an inevitable offshoot of globalisation that goes beyond world economy and international markets. It covers multiple themes; ranging from…

Sunlight, Sea Ice, and the Ice Albedo Feedback in a Changing Arctic Sea Ice Cover

DTIC Science & Technology

2015-09-30

PUBLICATIONS Carmack, E .; I. Polyakov; L. Padman; I. Fer; E . Hunke; J. Hutchings; J. Jackson; D. Kelley; R. Kwok; C. Layton ; D.K. Perovich; O. Persson; B...Heygster, M. Huntemann, P. Schwarz, G. Birnbaum, C. Polashenski, D. Perovich, E . Zege, A. Malinka and A. Prikchach (2015), The melt pond fraction and

Some Thoughts on "Cultural Variation and Dominance in a Globalised Knowledge-Economy"

ERIC Educational Resources Information Center

Yang, Yang; Gentry, Marcia

2012-01-01

To view giftedness research in a global context is an important and desirable attempt. Roland S. Persson (2012a), in the target article entitled Cultural Variation and Dominance in a Globalised Knowledge-Economy: Towards a Cultural-Sensitive Research Paradigm in the Science of Giftedness, delivers thought-provoking views in the cultural influences…

You Say Ordinary, We Say Gifted: How Ontology Can Help Mitigate Cultural Variation in the Social Sciences

ERIC Educational Resources Information Center

Martin, Lee; Gordon, Shaun

2012-01-01

Persson's (2012a) article offers a timely contribution to the science of giftedness through questioning the validity of research emerging from within this paradigm. Using evidence from a number of disciplines he demonstrates that what is regarded as gifted behaviour in one culture could be regarded as quite ordinary within another. He therefore…

75 FR 76482 - Federal Housing Administration (FHA): FHA Maximum Loan Limits for 2011

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-08

... http://www.hud.gov/offices/adm/hudclips/letters/mortgagee/ . FOR FURTHER INFORMATION CONTACT: Karin B... be found at http://www.hud.gov/offices/adm/hudclips/letters/mortgagee/ mortgagee/. Dated: November 29...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rodland, Karin

New research identifies critical proteins present in the tumors of women with ovarian cancer. Karin Rodland discusses the work led by PNNL and Johns Hopkins researchers, working with collaborators across the nation.

The Inner Workings of Ovarian Cancer

ScienceCinema

Rodland, Karin

2018-06-12

New research identifies critical proteins present in the tumors of women with ovarian cancer. Karin Rodland discusses the work led by PNNL and Johns Hopkins researchers, working with collaborators across the nation.

Critique of Cultural Variation and Dominance in a Globalised Knowledge-Economy: Towards a Culture-Sensitive Research Paradigm in the Science of Giftedness

ERIC Educational Resources Information Center

Harris, Carole Ruth

2012-01-01

Persson's (2012a) article is concerned with giftedness research in the light of cultural bias with a view to cultural dominance that derives from ethnocentricity. He questions the validity of current research that appears to ignore or sidestep cultural difference and proposes that an agenda for amelioration of such bias lies in greater awareness…

The Misfortunes of Moral Enhancement.

PubMed

Azevedo, Marco Antonio

2016-10-01

In Unfit for the Future, Ingmar Persson and Julian Savulescu present a sophisticated argument in defense of the imperative of moral enhancement. They claim that without moral enhancement, the future of humanity is seriously compromised. The possibility of ultimate harm, caused by a dreadful terrorist attack or by a final unpreventable escalation of the present environmental crisis aggravated by the availability of cognitive enhancement, makes moral enhancement a top priority. It may be considered optimistic to think that our present moral capabilities can be successfully improved by means of moral education, moral persuasion, and fear of punishment. So, without moral enhancement, drastic restrictions on human freedom would become the only alternative to prevent those dramatic potential outcomes. In this article, I will try to show that we still have reason to be less pessimistic and that Persson & Savulescu's arguments are fortunately unconvincing. © The Author 2016. Published by Oxford University Press, on behalf of the Journal of Medicine and Philosophy Inc. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

A Distinction between Emic Research and Etic Research

ERIC Educational Resources Information Center

Gallagher, James J.

2012-01-01

Roland S. Persson (2012a) has made a significant contribution to the literature in pointing out the potential for cultural bias in the body of research related to gifted and talented. He encourages a distinction between emic research, where the results are limited to a particular culture and etic research, where the results can be generalised to…

De-Mystifying Giftedness: An Overdue Perspective

ERIC Educational Resources Information Center

Campbell, R. J.; Smith, L. Mazzoli

2012-01-01

Campbell and Mazzoli Smith state that it is rare to find two articles, linked, as they are by concerns with both giftedness and the limits of objectivity, so different in style, in degree of cognitive challenge, and in extent of tentativeness, as those by Professor Freeman and Professor Persson in the two issues of "Gifted and Talented…

Basic Framework to Understand Identity Development in a Multicultural Context

ERIC Educational Resources Information Center

Shaughnessy, Michael F.; Valdez, Gilbert

2012-01-01

In the lead article, Persson (2012a) focuses on salient issues that have not as yet been addressed by others, and which are relevant, and germane. With the advent of the Internet and web and e-mail, conversation and discussion among scholars have increased tremendously. At the current time, researchers are able to share their data, their thoughts…

The challenge of ecological restoration

Treesearch

John A. Stanturf

2012-01-01

Recent estimates by the World Conservation Union (IUCN) and World Resources Institute (WRI) suggest that over 2 billion ha of forests are degraded and in need of restoration. Goren Persson, former prime minister of Sweden, proposed the formation of a Global Restoration council to implement the Bonn Challenge to restore 150 million ha of degraded forests by 2020. The...

The Scenic Route Is Not Always the Most Informative

ERIC Educational Resources Information Center

Freeman, Joan

2012-01-01

Roland S. Persson's (2012a) argument is that there is a dominant research culture in the field of gifts and talents, which must of necessity distort research and practice in cultures which are different. He ties this to the dominance of the global economy and points to the need for more cross-cultural studies. In this commentary, the author points…

Adoptive T cell cancer therapy

NASA Astrophysics Data System (ADS)

Dzhandzhugazyan, Karine N.; Guldberg, Per; Kirkin, Alexei F.

2018-06-01

Tumour heterogeneity and off-target toxicity are current challenges of cancer immunotherapy. Karine Dzhandzhugazyan, Per Guldberg and Alexei Kirkin discuss how epigenetic induction of tumour antigens in antigen-presenting cells may form the basis for multi-target therapies.

A constrained Delaunay discretization method for adaptively meshing highly discontinuous geological media

NASA Astrophysics Data System (ADS)

Wang, Yang; Ma, Guowei; Ren, Feng; Li, Tuo

2017-12-01

A constrained Delaunay discretization method is developed to generate high-quality doubly adaptive meshes of highly discontinuous geological media. Complex features such as three-dimensional discrete fracture networks (DFNs), tunnels, shafts, slopes, boreholes, water curtains, and drainage systems are taken into account in the mesh generation. The constrained Delaunay triangulation method is used to create adaptive triangular elements on planar fractures. Persson's algorithm (Persson, 2005), based on an analogy between triangular elements and spring networks, is enriched to automatically discretize a planar fracture into mesh points with varying density and smooth-quality gradient. The triangulated planar fractures are treated as planar straight-line graphs (PSLGs) to construct piecewise-linear complex (PLC) for constrained Delaunay tetrahedralization. This guarantees the doubly adaptive characteristic of the resulted mesh: the mesh is adaptive not only along fractures but also in space. The quality of elements is compared with the results from an existing method. It is verified that the present method can generate smoother elements and a better distribution of element aspect ratios. Two numerical simulations are implemented to demonstrate that the present method can be applied to various simulations of complex geological media that contain a large number of discontinuities.

What Is a Bone Marrow Transplant?

MedlinePlus

... Print this page My Cart What is a bone marrow transplant? A bone marrow transplant is a ... blood.” – Edmund Waller, MD, PHD What is a bone marrow transplant? A bone marrow transplant is a ...

78 FR 24226 - Notice of Proposed Information Collection: Comment Request; FHA TOTAL (Technology Open to...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-24

... Information Collection: Comment Request; FHA TOTAL (Technology Open to Approved Lenders) Mortgage Scorecard... proposed information collection requirement described below will be submitted to the Office of Management... Information Service (1-800-877-8339). FOR FURTHER INFORMATION CONTACT: Karin B. Hill, Director, Office of...

77 FR 65361 - Xanthan Gum From Austria and the People's Republic of China: Postponement of Preliminary...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-10-26

... Austria and the People's Republic of China: Postponement of Preliminary Determinations of Antidumping Duty...: October 26, 2012. FOR FURTHER INFORMATION CONTACT: Karine Gziryan (Austria) or Brandon Farlander (People's... of initiation of antidumping duty investigations of xanthan gum from Austria and the People's...

In-situ X-ray diffraction studies of the phase transformations and structural states of B2, R and B19′ phases in Ti{sub 49.5}Ni{sub 50.5} alloy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ostapenko, Marina G., E-mail: artifakt@ispms.tsc.ru; National Research Tomsk Polytechnic University, Tomsk, 634050; Meisner, Ludmila L., E-mail: llm@ispms.tsc.ru

2015-10-27

The martensitic transformation, Debye–Waller factor, mean-square atomic displacements and the coefficient of thermal expansion on cooling of the Ti{sub 49.5}Ni{sub 50.5} shape memory alloy were examined using in-situ X-ray diffraction. It was revealed B2→R (T{sub R} ≡ T = 273 ± 10 K) along with B2→B19’ (M{sub s} ≡ T = 273 ± 10 K) transitions occur. It was found that Debye–Waller factor and mean-square displacement of B2 phase undergo significant increase as functions of temperature when phase transition B2→R and B2→B19’ take place. The analysis of the thermal expansion coefficient of the B2 phase indicates that the value of a increasesmore » almost linearly while cooling.« less

SHORTER MENSTRUAL CYCLES ASSOCIATED WITH CHLORINATION BY-PRODUCTS IN DRINKING WATER

EPA Science Inventory

Shorter Menstrual Cycles Associated with Chlorination by-Products in Drinking Water.
Gayle Windham, Kirsten Waller, Meredith Anderson, Laura Fenster, Pauline Mendola, Shanna Swan. California Department of Health Services.

In previous studies of tap water consumption we...

Circuit racing, track texture, temperature and rubber friction

NASA Astrophysics Data System (ADS)

Sharp, R. S.; Gruber, P.; Fina, E.

2016-04-01

Some general observations relating to tyre shear forces and road surfaces are followed by more specific considerations from circuit racing. The discussion then focuses on the mechanics of rubber friction. The classical experiments of Grosch are outlined and the interpretations that can be put on them are discussed. The interpretations involve rubber viscoelasticity, so that the vibration properties of rubber need to be considered. Adhesion and deformation mechanisms for energy dissipation at the interface between rubber and road and in the rubber itself are highlighted. The enquiry is concentrated on energy loss by deformation or hysteresis subsequently. Persson's deformation theory is outlined and the material properties necessary to apply the theory to Grosch's experiments are discussed. Predictions of the friction coefficient relating to one particular rubber compound and a rough surface are made using the theory and these are compared with the appropriate results from Grosch. Predictions from Persson's theory of the influence of nominal contact pressure on the friction coefficient are also examined. The extent of the agreement between theory and experiment is discussed. It is concluded that there is value in the theory but that it is far from complete. There is considerable scope for further research on the mechanics of rubber friction.

TIME TO PREGNANCY IN RELATION TO TOTAL TRIHALOMETHANE LEVELS IN TAP WATER

EPA Science Inventory

Time to pregnancy in relation to total trihalomethane levels in tap water
Shanna H. Swan, Cuirong Ren, Gayle C. Windham, Laura Fenster, Kirsten Waller. (University of Missouri and California Department of Health Services).

We have previously reported increased risks o...

STRAIN COMPARISON IN PREGNANT RATS OF ENDOCRINE RESPONSE TO BROMODICHLOROMETHANE: A DRINKING WATER DISINFECTION BY-PRODUCT

EPA Science Inventory

Bromodichloromethane (BDCM), a trihalomethane, is a by-product of the chlorination of drinking water. In an epidemiological study, consumption of drinking water with high levels of BDCM was associated with an increased risk of spontaneous abortion in pregnant women (Waller et al....

Schools That Succeed: How Educators Marshal the Power of Systems for Improvement

ERIC Educational Resources Information Center

Chenoweth, Karin

2017-01-01

Informed by years of research and on-the-ground reporting, "Schools That Succeed" is Karin Chenoweth's most inspiring and compelling book yet--an essential read for educators who seek to break the stubborn connection between academic achievement and socioeconomic status. Chenoweth draws on her decade-long journey into neighborhood…

The End of the Six-Party Talks?

DTIC Science & Technology

2007-01-01

Pyongyang is wary of Beijing’s international influence, its ability to collaborate with the United States and South Korea, its willingness to foster ...Kenneth Quinones, “ Dualism in the Bush Administration’s North Korea Policy,” Asian Perspective, XXVII, no. 1, 2003, 197-224; Karin Lee and Adam Miles

Contact mechanics for layered materials with randomly rough surfaces.

PubMed

Persson, B N J

2012-03-07

The contact mechanics model of Persson is applied to layered materials. We calculate the M function, which relates the surface stress to the surface displacement, for a layered material, where the top layer (thickness d) has different elastic properties than the semi-infinite solid below. Numerical results for the contact area as a function of the magnification are presented for several cases. As an application, we calculate the fluid leak rate for laminated rubber seals.

IMPROVING EXPOSURE ASSESSMENT IN DISINFECTION BYPRODUCTS (DBP) EPIDEMIOLOGIC STUDIES

EPA Science Inventory

In 1997, an EPA expert panel was convened to evaluate epidemiologic studies of adverse reproductive or developmental outcomes that may be associated with drinking water DBPs. The panel recommended that further efforts be made in an existing cohort study, headed by Dr. Waller and ...

CHLORINATION BY-PRODUCTS IN DRINKING WATER AND MENSTRUAL CYCLE FUNCTION

EPA Science Inventory

Chlorination by-Products in Drinking Water and Menstrual Cycle Function

Gayle C. Windham1, Kirsten Waller2, Meredith Anderson2, Laura Fenster1, Pauline Mendola3, Shanna Swan4

1California Department of Health Services, Division of Environmental and Occupational Disea...

Adaptive Rules In Emergent Logistics (ARIEL) An Agent-Based Analysis Environment to Study Adaptive Route-Finding Constantly Changing Road-Networks

DTIC Science & Technology

2003-06-01

my wife Karin, my daughter Jasmin and my son Jan for their support and huge patience. Without the security and support of a loving home, none of...contains the trucks, which are the only moveable objects in the system. In essence they provide functionality and cannot act themselves. The layer

Persistent Discourses in Physics Education: Gender Neutrality and the Gendering of Competence

ERIC Educational Resources Information Center

Gonsalves, Allison

2014-01-01

In her article, Karin Due presents us with a contradiction in physics: the construction of physics as a symbolically masculine discipline alongside a simultaneous discourse of the "gender-neutrality" of the discipline. Due's article makes an important contribution to the study of the gendering of physics practices, particularly in…

An alternative explanation of the change in T-dependence of the effective Debye-Waller factor at T{sub c} or T{sub B}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ngai, K. L.; CNR-IPCF, Largo Bruno Pontecorvo 3, I-56127 Pisa; Habasaki, J.

The cusp-like temperature dependence of the Debye-Waller factor or non-ergodicity parameter f{sub Q}(T) at some temperature T{sub c} above T{sub g} found by experiments in several fragile glassformers has been considered as critical evidence for validity of the ideal Mode Coupling Theory (MCT). A comprehensive review of experimental data of f{sub Q}(T) and beyond brings out various problems of the MCT predictions. For example, the molten salt, 0.4Ca(NO{sub 3}){sub 2}-0.6KNO{sub 3} (CKN), was the first glassformer measured by neutron scattering to verify the cusp-like behavior of f{sub Q}(T) at T{sub c} predicted by ideal MCT. While the fits of themore » other scaling laws of MCT to viscosity, light scattering, and dielectric relaxation data all give T{sub c} in the range from 368 to 375 K, there is no evidence of cusp-like behavior of f{sub Q}(T) at T{sub c} from more accurate neutron scattering data obtained later on by Mezei and Russina [J. Phys.: Condens. Matter 11, A341 (1999)] at temperatures below 400 K. In several molecular glass-formers, experiments have found at temperatures below T{sub c} that [1−f{sub Q}(T)] is manifested as nearly constant loss (NCL) in the frequency dependent susceptibility. The NCL persists down to below T{sub g} and is not predicted by the ideal MCT. No clear evidence of the change of T-dependence of f{sub Q}(T) at any T{sub c} was found in intermediate and strong glassformers, although ideal MCT does not distinguish fragile and strong glassformers in predicting the critical behavior of f{sub Q}(T) a priori. Experiments found f{sub Q}(T) changes T-dependence not only at T{sub c} but also at the glass transition temperature T{sub g}. The changes of T-dependence of f{sub Q}(T) at T{sub c} and T{sub g} are accompanied by corresponding changes of dynamic variables and thermodynamic quantities at T{sub B} ≈ T{sub c} and at T{sub g}. The dynamic variables include the relaxation time τ{sub α}(T), the non-exponentiality parameter n

Constitutive Activation of NF-kappaB in Prostate Carcinoma Cells Through a Positive Feedback Loop: Implication of Inducible IKK-Related Kinase (IKKi)

DTIC Science & Technology

2004-08-01

development in different tissues is strongly considered ( Greten and Karen, 2004). To assess the effect of w.t. IKKi and kinase inactive IKKi mutant...11: 1357-1362, 1999. 3. Greten FR, Karin M. The IKK/NF-kappaB activation pathway-a target for prevention and treatment of cancer. Cancer Lett. 206(2

Astronaut C. Michael Foale is briefed on use of Sky Genie

NASA Technical Reports Server (NTRS)

1994-01-01

Astronaut C. Michael Foale, STS-63 mission specialist, is briefed on the use of Sky Genie device by Karin L. Porter. The device would aid in emergency egress operations aboard a troubled Space Shuttle. Porter, an employee of Rockwell International, helps train astronauts in egress procedures at JSC's Shuttle mockup and integration laboratory.

77 FR 36285 - Notice of Proposed Information Collection: Comment Request; Application for Fee or Roster...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-06-18

... the FHA insurance fund. Agency form numbers, if applicable: HUD-92563I, HUD 92563A, HUD 92564-CN... to the proposal by name and/or OMB Control Number and should be sent to: Reports Liaison Officer... number for the Federal Information Relay Service (1-800-877-8339). FOR FURTHER INFORMATION CONTACT: Karin...

75 FR 23654 - Endangered and Threatened Wildlife and Plants; 90-Day Finding on a Petition to List Hermes Copper...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-05-04

... in our files, a personal communication (cited ``D. Faulkner, V. Marquez-Waller pers. comm. on 4/16/08... frequency may result in altered vegetation structure or type conversion throughout the range (Keeley and... require mature R. crocea to complete their lifecycle; therefore, increased fire frequency may reduce...

TRIHALOMETHANE LEVELS IN HOME TAP WATER AND SEMEN QUALITY

EPA Science Inventory

Trihalomethane Levels in Home Tap Water and Semen Quality
Laura Fenster, 1 Kirsten Waller, 2 Gayle Windham, 1 Tanya Henneman, 2 Meredith Anderson, 2 Pauline Mendola, 3 James W. Overstreet, 4 Shanna H. Swan5

1California Department of Health Services, Division of Environm...

On the nature of a glassy state of matter in a hydrated protein: Relation to protein function.

PubMed

Teeter, M M; Yamano, A; Stec, B; Mohanty, U

2001-09-25

Diverse biochemical and biophysical experiments indicate that all proteins, regardless of size or origin, undergo a dynamic transition near 200 K. The cause of this shift in dynamic behavior, termed a "glass transition," and its relation to protein function are important open questions. One explanation postulated for the transition is solidification of correlated motions in proteins below the transition. We verified this conjecture by showing that crambin's radius of gyration (Rg) remains constant below approximately 180 K. We show that both atom position and dynamics of protein and solvent are physically coupled, leading to a novel cooperative state. This glassy state is identified by negative slopes of the Debye-Waller (B) factor vs. temperature. It is composed of multisubstate side chains and solvent. Based on generalization of Adam-Gibbs' notion of a cooperatively rearranging region and decrease of the total entropy with temperature, we calculate the slope of the Debye-Waller factor. The results are in accord with experiment.

Color Transformations for the 2MASS Second Incremental Data Release

NASA Astrophysics Data System (ADS)

Carpenter, John M.

2001-05-01

Transformation equations are presented to convert colors and magnitudes measured in the AAO, ARNICA, CIT, DENIS, ESO, LCO (Persson standards), MSSSO, SAAO, and UKIRT photometric systems to the photometric system inherent in the 2MASS Second Incremental Data Release. The transformations have been derived by comparing 2MASS photometry with published magnitudes and colors for stars observed in these systems. Transformation equations have also been derived indirectly for the Bessell & Brett and Koornneef homogenized photometric systems.

Pyrolysis Gas Flow in Thermally Ablating Media Using Time-Implicit Discontinuous Galerkin Methods

DTIC Science & Technology

2011-01-01

Aeronautics and Astronautics 2 the dissociated and ionized gas species (present in the shock layer, which is between the bow shock and boundary layer... wind tunnel experiment was conducted in [20] with a carbon-phenolic sample that was exposed to a heat flux of 1400 W/cm 2 . Experiment results were...type of problems [7-10]. In work by Persson and Peraire, they have been applied to various problems of viscous flows, shocks , turbulent flows and

Getting It Done: Leading Academic Success in Unexpected Schools

ERIC Educational Resources Information Center

Chenoweth, Karin; Theokas, Christina

2011-01-01

"Getting It Done" describes in clear and helpful detail what leaders of successful high-poverty and high-minority schools have done to promote and sustain student achievement. It follows two celebrated books by Karin Chenoweth: "It's Being Done," which established that the work of educating all children is possible, and "How It's Being Done,"…

Correcting Distance Estimates by Interacting With Immersive Virtual Environments: Effects of Task and Available Sensory Information

ERIC Educational Resources Information Center

Waller, David; Richardson, Adam R.

2008-01-01

The tendency to underestimate egocentric distances in immersive virtual environments (VEs) is not well understood. However, previous research (A. R. Richardson & D. Waller, 2007) has demonstrated that a brief period of interaction with the VE prior to making distance judgments can effectively eliminate subsequent underestimation. Here the authors…

Relationship of Purported Measures of Pathological and Nonpathological Dissociation to Self-Reported Psychological Distress and Fantasy Immersion

ERIC Educational Resources Information Center

Levin, Ross; Spei, Ekaterina

2004-01-01

In order to investigate both the psychometric structure of the Dissociative Experiences Survey (DES) and the discriminant validity of the DES-Taxon (Waller, Putnam, & Carlson, 1996) as a specific marker of pathological dissociation, 376 non-clinical community based respondents completed the DES and a battery of psychopathology and imaginative…

Testing a Readable Writing Approach to Text Revision.

ERIC Educational Resources Information Center

Duffy, Thomas M.; Kabance, Paula

1982-01-01

The present findings imply that a readability formula is not an effective writing production criterion, even when the writer does not deliberately write to the formula. Comprehensibility of text might be better controlled through the proper use of the transformer concept (MacDonald-Ross and Waller). (Author/PN)

The Role of Personality in the Selection of a Major: With and without Vocational Self-Efficacy and Interests

ERIC Educational Resources Information Center

Larson, Lisa M.; Wu, Tsui Feng; Bailey, Donna C.; Gasser, Courtney E.; Bonitz, Verena S.; Borgen, Fred H.

2010-01-01

The purpose of this study is to examine the role of personality traits measured by the Multidimensional Personality Questionnaire (MPQ; [Tellegen, 2000] and [Tellegen and Waller, 2008]) in selecting educational majors. Personality traits were examined alone, and with the combination of Holland's hexagonal confidence domains, as measured by the…

Brokenhearts: Dissolution of Romantic Relationships.

ERIC Educational Resources Information Center

Meeker, F. B.; La Fong, Carl

Results of an investigation examining the dissolution of romantic relationships are analyzed. Men and women (N=105) who had ended romantic relationships were surveyed in structured individual interviews. Commonalities and differences in respondents' perceptions of the experience were examined. Specific tests were made of a corollary to Waller's…

Order parameters from image analysis: a honeycomb example

NASA Astrophysics Data System (ADS)

Kaatz, Forrest H.; Bultheel, Adhemar; Egami, Takeshi

2008-11-01

Honeybee combs have aroused interest in the ability of honeybees to form regular hexagonal geometric constructs since ancient times. Here we use a real space technique based on the pair distribution function (PDF) and radial distribution function (RDF), and a reciprocal space method utilizing the Debye-Waller Factor (DWF) to quantify the order for a range of honeycombs made by Apis mellifera ligustica. The PDFs and RDFs are fit with a series of Gaussian curves. We characterize the order in the honeycomb using a real space order parameter, OP 3 , to describe the order in the combs and a two-dimensional Fourier transform from which a Debye-Waller order parameter, u, is derived. Both OP 3 and u take values from [0, 1] where the value one represents perfect order. The analyzed combs have values of OP 3 from 0.33 to 0.60 and values of u from 0.59 to 0.69. RDF fits of honeycomb histograms show that naturally made comb can be crystalline in a 2D ordered structural sense, yet is more ‘liquid-like’ than cells made on ‘foundation’ wax. We show that with the assistance of man-made foundation wax, honeybees can manufacture highly ordered arrays of hexagonal cells. This is the first description of honeycomb utilizing the Debye-Waller Factor, and provides a complete analysis of the order in comb from a real-space order parameter and a reciprocal space order parameter. It is noted that the techniques used are general in nature and could be applied to any digital photograph of an ordered array.

Role of ets Oncogenes in the Progression of Breast Cancer

DTIC Science & Technology

1998-10-01

8217 References 167 Arias J, Alberts AS, Brindle P, Claret FX, Smeal T, Karin M, May WA, Lessnick SL, Braun BS, Klemsz M, Lewis BC, Feramisco J and Montminy M...0 and Shaw PE. (1994). Mol. Cell. Oncogene, 8, 3459-3464. Biol., 14, 4815-4824. Bories J, Willerford DM, Grevin D, Davidson L, Camus A, Lopez M

Radiation Dosimetry of Intratumoral Injection of Radionuclides into Human Breast Cancer

DTIC Science & Technology

2007-07-01

2 sites will be selected for a single inoculation each. The site will be shaved, the skin will be prepared in sterile fashion using betadine...0.0200 Ovaries 0.0150 0.0030 Pancreas 0.1400 0.0280 Red Marrow 0.1200 0.0240 Bone Surfaces 0.1700 0.0340 Skin 0.1600 0.0320 Spleen 0.1100 0.0220...mapping with intralesional tracer administration in breast carcinoma patients. Cancer. 88(11):2546-52, 2000. 10. Bergqvist L, Strand SE, Persson B, et

Radiation Dosimetry of Intratumoral Injection of Radionuclides into Human Breast Cancer. Revision

DTIC Science & Technology

2007-07-01

2 sites will be selected for a single inoculation each. The site will be shaved, the skin will be prepared in sterile fashion using betadine...0.0200 Ovaries 0.0150 0.0030 Pancreas 0.1400 0.0280 Red Marrow 0.1200 0.0240 Bone Surfaces 0.1700 0.0340 Skin 0.1600 0.0320 Spleen 0.1100 0.0220...mapping with intralesional tracer administration in breast carcinoma patients. Cancer. 88(11):2546-52, 2000. 10. Bergqvist L, Strand SE, Persson B, et

Maxims, Tacit Knowledge and Learning: Developing Expertise in Dry Stone Walling

ERIC Educational Resources Information Center

Farrar, Nicholas; Trorey, Gill

2008-01-01

This study attempts to further our understanding of how expertise is acquired in a specific vocational context. Using unstructured interviews with both individuals and groups, carried out whilst engaged in practice, it examines what happens when dry stone wallers are developing their skills, how they gain expertise and how they communicate their…

Securing Emergency State Data in a Tactical Computing Environment

DTIC Science & Technology

2010-12-01

in a Controlled Manner, 19th IEEE Symposium on Computer-Based Medical Systems (CBMS󈧊), 847–854. [38] K. Kifayat, D. Llewellyn - Jones , A. Arabo, O...Drew, M. Merabti, Q. Shi, A. Waller, R. Craddock, G. Jones , State-of-the-Art in System-of-Systems Security for Crisis Management, Fourth Annual

Blacks in Pop Music: A Short Story.

ERIC Educational Resources Information Center

Rickelman, Melinda

1991-01-01

A short history of black pop music includes artists who have changed pop music or culture and highlights from the 1920s into the 1980s, from Fats Waller to Michael Jackson. In black pop music, there is a direct line of influence from the sharecropper to the current Top 40. (SLD)

Perspectives on Positioning, Interaction, and Learning in Small-Group Discussion: Possibilities for Extending the Analytic Lens

ERIC Educational Resources Information Center

Kittleson, Julie M.; Wilson, Rachel E.

2014-01-01

In this forum piece, we respond to Karin Due's study of social dynamics in groups of students in physics class and gender issues that play out in this context. We discuss two threads that appear in Due's paper: one pertains to patterns of talk within groups and how these patterns open up possibilities for learning, the other pertains to…

Attachment Style and Dysfunctional Career Thoughts: How Attachment Style Can Affect the Career Counseling Process

ERIC Educational Resources Information Center

van Ecke, Yolanda

2007-01-01

This article examines the relationship between attachment style, measured by Experiences in Close Relationships-Revised (R C. Fraley, N. G. Waller, & K. A. Brennan, 2000), and dysfunctional career thoughts, measured by the Career Thoughts Inventory (CTI; J. P. J. Sampson, G. W. Peterson, J. G. Lenz, R. C. Reardon, & D. E. Saunders, 1994a).…

Photography, Motion Picture Film Cores and Spools, Performances, and Other Technical Information

DTIC Science & Technology

2000-01-01

process was an outgrowth of the Fred Waller Flexible Gunnery Trainer25 used to train aerial gunners to hit fast-moving air-borne targets. The realism ...34Travelling matte photography and the blue-screen system," published serially, Am. Cinemat , 44: 590-606, Oct. 1963; 45: 34-45, Jan. 1964; 208-210, 226-227

Leading Change in the Primary Science Curriculum

ERIC Educational Resources Information Center

Waller, Nicky; Baker, Chris

2014-01-01

Nicky Waller and Chris Baker believe that change can be a good thing and explain how their training has helped others to adjust to the new science curriculum. In September 2013, teachers across England received the definitive version of the new primary curriculum "Leading Change in the Primary Science Curriculum." This course aimed to…

Leaps in the Dark - The making of scientific reputations

NASA Astrophysics Data System (ADS)

Waller, John

2004-12-01

In Leaps in the Dark , John Waller presents another collection of revelations from the world of science. He considers experiments in which the scientists' awareness was not perhaps as keen as they might have claimed in retrospect; he investigates the jealousy and opposition that scientific ideas can provoke; he celebrates the scientists who were wrong, but for very good reasons; and he demonstrates how national interest can affect scientists and their theories. The result is an entertaining and highly readable re-examination of scientific discoveries and reputations from the Renaissance to the twentieth century. The tales in Leaps in the Dark range across a wide historical field, from a seventeenth-century witch-finder, Joseph Glanvill, to Sir Robert Watson-Watt, the self-proclaimed 'Father of radar'. Each story underscores the rich, fascinating complexity of scientific discovery. Writing in a clear and engaging style, and skilfully weaving history in with the science, John Waller brings these scientists to life, illustrating how their work and their discoveries influenced their careers and the wider world around them.

An Investigation of the Interatomic Bonding Characteristics of a Ti - 51at.% Al Alloy by X-Ray Diffraction

DTIC Science & Technology

1991-06-01

GROUP SUBGROUP X-ray Diffraction, XRD, TiAI, titanium , aluminum, bonding characteristics, titanium aluminides , Debye-Waller temperature factor...XRD Powder Particles (575X) .............. 47 viii I. INTRODUCTION Titanium aluminides are recognized for their high specific strength, particularly at...bonding characteristics of binary titanium aluminides . Upon the introduction of a third element to the system, a rearrangement of the valence

Conformers, Adaptors, Imitators, and Rejecters: How No-Excuses Teachers' Cultural Toolkits Shape Their Responses to Control

ERIC Educational Resources Information Center

Golann, Joanne W.

2018-01-01

In the past, sociologists have provided keen insights into the work of teaching, but classic studies by scholars like Dan Lortie and Willard Waller are now decades old. With the current emphasis on teacher evaluation and accountability, the field is ripe for new sociological studies of teaching. How do we understand the work of teaching in this…

Radiation Dosimetry from Intratumoral Injection of Radionuclides in Human Breast Cancer

DTIC Science & Technology

2004-07-01

0.1700 0.0340 Skin 0.0170 0.0085 0.1600 0.0320 Spleen 0.0130 0.0065 0.1100 0.0220 Testes 0.0011 0.0006 0.0053 0.0011 Thymus 0.0530 0.0265 0.5800 0.1160...Lymphatic mapping with intralesional tracer administration in breast carcinoma patients. Cancer. 88(11):2546-52, 2000. 10. Bergqvist L, Strand SE, Persson B...dosimetry in intra- cavitary injection of eight radionuclides in five shell models. J Nucl Med, 43(5):90P, 2002, Suppl. 20. Colombetti LG, Goodwin DA

Review of National Work Programme on the Long Term Effects of Sustained High G on the Cervical Spine (Analyse du programme de travail national : les effets long terme sur la colonne cervicale d’un nombre de G lev et prolong )

DTIC Science & Technology

2008-12-01

Prof. Karin Harms-Ringdahl, PhD, RPT Karolinska Institutet Department of Neurobiology, Care Sciences, and Society Division of Physiotherapy 23100...Äng Karolinska Institutet Department of Neurobiology, Care Sciences, and Society Division of Physiotherapy Alfred Nobels Allé 23100 SE-14183...report is in preparation. The RAF has an ongoing project (from August 2006 to September 2007) determining the need for physiotherapy for aircrew on the

JPRS Report, West Europe.

DTIC Science & Technology

1987-08-11

11 AUGUST 1987 WEST EUROPE CONTENTS POLITICAL FEDERAL REPUBLIC OF GERMANY Greens Divided Over Defense Policy (SUEDDEUTSCHE ZEITUNG, 20, 21 Jun...Depopulation (Karin Henriksson, Emily von Sydow; SVENSKA DAGBLADET, 30 May 87) H /9986 - d - FEDERAL REPUBLIC OF GERMANY POLITICAL GREENS DIVIDED ...React Much More Vigorously to Threats to Freedom In this connection, I want to draw the attention of the National Conference to the seriousness and

Forest statistics for Southeast Texas counties - 1986

Treesearch

William H. McWilliams; Daniel F. Bertelson

1986-01-01

These tables were derived from data obtained during a 1986 inventory of 22 counties comprising the Southeast Unit of Texas (fig. 1). Grimes, Leon, Madison, and Waller counties have been added to the Southeastern Unit since the previous inventory if 1975. All comparisons of the 1975 and 1986 forest statistics made in this Bulletin account for this change. The data on...

Identifying and Leveraging Trust as a Key Element in the Development, Implementation and Sustainment of the Salt Lake City Fire Department’s Intelligence Program

DTIC Science & Technology

2014-09-01

this amazing adventure. An education in self-exploration balanced with relentless tests of my stamina and mettle. To my classmates: Thank you for...Karin and son Scott, thank you for providing the comic relief so needed throughout this process. And most importantly, to my husband, Jeff: There...development of a fire intelligence program.190191 In her NPS Masters Thesis, Terrorism Awareness and Education as a Prevention Strategy for First

Training Aide: Research and Guidance for Effective Training User Guide

DTIC Science & Technology

2013-12-01

Research Product 2014-02 Training Aide: Research and Guidance for Effective Training User Guide Beth Plott Shaun...Effective Training User Guide 5a. CONTRACT OR GRANT NUMBER W91WAW-07-C-0081 5b. PROGRAM ELEMENT NUMBER 611102 6. AUTHOR(S) Beth Plott...Representative and Subject Matter POC: Karin A. Orvis 14. ABSTRACT: This is a user guide for the web-based tool called Training Aide: Research and Guidance

To Investigate the Therapeutic Efforts of the COX-2 Inhibitor NS-398 as a Single Agent, and in Combination with Vitamin D, in Vitro and in Vivo

DTIC Science & Technology

2008-01-01

by immunoelectron microscopy. The Journal Of Biological Chemistry 1998;273:9886-93. 29. Iniguez M, Rodriguez A, Volpert O, Fresno M, Redondo J...controlled by local hypoxia that induces the synthesis of angio- genic factors that can activate signal pathways and transcrip- tion for endothelial...Helmberg,A. and Karin,M. (1995) Immunosuppression by glucocorticoids: inhibition of NF-kappa B activity through induction of I kappa B synthesis . Science

CPTAC Investigators Discuss Research Insights and Perspectives as part of ASBMB Journal Club - 12 Nov | Office of Cancer Clinical Proteomics Research

Cancer.gov

On Wednesday, November 12, 2014 from 2:00 PM to 3:00 PM EST, Daniel Liebler, PhD (Vanderbilt University) and Karin Rodland, PhD (Pacific Northwestern National Laboratory) and Ruedi Aebersold, PhD (Swiss Federal Institute of Technology) will share their research insight as part of the ASBMB Journal Club.  Both Doctors Liebler and Rodland are Principal Investigators in the NCI’s Clinical Proteomic Tumor Analysis Consortium.

Vibrational properties of nanocrystals from the Debye Scattering Equation

DOE PAGES

Scardi, P.; Gelisio, L.

2016-02-26

One hundred years after the original formulation by Petrus J.W. Debije (aka Peter Debye), the Debye Scattering Equation (DSE) is still the most accurate expression to model the diffraction pattern from nanoparticle systems. A major limitation in the original form of the DSE is that it refers to a static domain, so that including thermal disorder usually requires rescaling the equation by a Debye-Waller thermal factor. The last is taken from the traditional diffraction theory developed in Reciprocal Space (RS), which is opposed to the atomistic paradigm of the DSE, usually referred to as Direct Space (DS) approach. Besides beingmore » a hybrid of DS and RS expressions, rescaling the DSE by the Debye-Waller factor is an approximation which completely misses the contribution of Temperature Diffuse Scattering (TDS). The present work proposes a solution to include thermal effects coherently with the atomistic approach of the DSE. Here, a deeper insight into the vibrational dynamics of nanostructured materials can be obtained with few changes with respect to the standard formulation of the DSE, providing information on the correlated displacement of vibrating atoms.« less

Abandoning the common law: medical negligence, genetic tests and wrongful life in the Australian High Court.

PubMed

Faunce, Thomas; Jefferys, Susannah

2007-05-01

The Australian High Court recently found that the common law could allow parents to claim tortious damages when medical negligence was proven to have led to the birth of an unplanned, but healthy, baby (Cattanach v Melchior (2003) 215 CLR 1). In Harriton v Stephens (2006) 80 ALJR 791; [2006] HCA 15 and Waller v James; Waller v Hoolahan (2006) 80 ALJR 846; [2006] HCA 16 the High Court in a six-to-one decision (Kirby J dissenting) decided that no such claim could be made by a child when medical negligence in failing to order an in utero genetic test caused the child severe disability. In an era when almost all pregnancies will soon require patented fetal genetic tests as part of the professional standard of care, the High Court, by barring so-called "wrongful life" (better termed "wrongful suffering") claims, may have created a partial immunity from suit for their corporate manufacturers and the doctors who administer them. What lessons can be learnt from this case about how the Australian High Court is, or should be, approaching medical negligence cases and its role as guardian of the Australian common law?

Computer Aided Dosimetry and Verification of Exposure to Radiation

DTIC Science & Technology

2002-06-01

Event matrix 2. Hematopoietic * Absolute blood counts * Relative blood counts 3. Dosimetry * TLD * EPDQuantitative * Radiation survey * Whole body...EI1 Defence Research and Recherche et developpement Development Canada pour la d6fense Canada DEFENCE •mI•DEFENSE Computer Aided Dosimetry and...Aided Dosimetry and Verification of Exposure to Radiation Edward Waller SAIC Canada Robert Z Stodilka Radiation Effects Group, Space Systems and

A search for T Tauri stars and related objects: Archival photometry of candidate variables in V733 Cep field

NASA Astrophysics Data System (ADS)

Jurdana-Šepić, R.; Poljančić Beljan, I.

Searching for T Tauri stars or related early type variables we carried out a BVRI photometric measurements of five candidates with positions within the field of the pre-main sequence object V733 Cephei (Persson's star) located in the dark cloud L1216 near to Cepheus OB3 Association: VES 946, VES 950, NSV 14333, NSV 25966 and V385 Cep. Their magnitudes are determined on the plates from Asiago Observatory historical photographic archive exposed 1971 - 1978. We provide finding charts for program stars and comparison sequence stars, magnitude estimations, magnitude mean values and BVR_cI_c light curves of program stars.

On the Energy of the Minimizers of the Ginzburg-Landau Functional for Exterior Magnetic Fields Between HC2 and HC3

NASA Astrophysics Data System (ADS)

Helffer, Bernard

2011-04-01

Superconductivity for Type II superconductors in external magnetic fields of magnitude between the second and third critical fields is known to be restricted to a narrow boundary region. The profile of the superconducting order parameter in the Ginzburg-Landau model is expected to be governed by an effective one-dimensional model. This is known to be the case for external magnetic fields sufficiently close to the third critical field. In this text we announce such a result on a larger interval of validity. These results have been obtained in collaboration with Soeren Fournais and Mikael Persson and the complete proofs will appear elsewhere.

Scanning the Horizon: Implications for Navy Strategy of National, Joint and Other Services’ Strategic Trends

DTIC Science & Technology

2012-02-01

CJCS’s) companion document, the Capstone Concept for Joint Operations (CCJO) (discussed below) "ibid., 28. "That said, it should be noted that it...Capstone Concept for Joint Operations (CCJO) The companion document to the JOE that answers the challenges of the future identified in the JOE (and...Karin E. Kitchens , Aaron Martin, A Review of the Army’s Modular Force Structure" (RAND National Defense Research Institute, Technical Report,Jun. 2011

Statements of IRAQI Communist Leaders.

DTIC Science & Technology

1960-07-19

Leader Abdul Karin Kassem J,.’l ; The Maintenance and Consolidation of Party Idfe Is a Deeply Sincere Policy of Cur Democratic Government STATEMENTS...OF IRAQI COMMUNIST LEADERS 1» Open Letter to His Excellency the Leader Abdul .Karflm Kassem /following is a ^translation of an article by the...they also exercised political influence and thus the fate of the feudalists was linked to the continued exploitation of our wealth, our natural

Equitable PERSTEMPO - The Challenge for Long-Term Deployed Armed Forces

DTIC Science & Technology

2003-04-07

substantial impact on the operational effectiveness of the Bundeswehr of the future.  Rudolf Scharping Former Federal Minister of Defense The vision...Federal Minister of Defense, Rudolf Scharping, initiated a new force planning by means of the so-called "Cornerstones Paper" on 01 June 2000, the Chief of...Annex 1) 77 Rainer Marr, Timea Biro, and Karin Steiner , Vereinbarkeit von Familie und Beruf des Soldaten – Moeglichkeiten und Grenzen einer

[G. Baglivi and scientific European community between rationalism and enlightenment].

PubMed

Toscano, A

2000-01-01

The Baglivi Correspondence, kept in the Waller Collection at the University Library of Uppsala, has been published in Italy for the first time in 1999. This Correspondence kept in Sweden provides new information about the scientific Italian culture between the second half of the seventeenth century and the beginning of the eighteenth. Moreover, it provides important knowledge on the diffusion the Baglivi's work in the scientific European context at that time.

The Strategic Utility of U.S. Navy SEALs

DTIC Science & Technology

2009-06-01

USA Swimming, rugby organizations and wrestling organizations. In addition, while the demographics do not fully support it, the Navy and NSW put a...guerrilla 66 forces mainly against the Soviet Union (Waller, 1994). Recognizing the successes of the OSS and its ability to effectively work with...operations. This improved both forces capabilities and proved a very useful union . 78 SEALs are capable of this SFA mission, but it is a difficult

A Comparison of the Compression Response of Thick (6.35mm) and Thin (1.60mm) Dry and Moisture Saturated AS4/3501-6 Laminates

DTIC Science & Technology

1990-10-01

of 1.27 mm/mm/min (0.05 in./in./min.) using a 60 kip Satec universal machine, with a spherically seated compression platen for alignment purposes. At...Task No. 6. AUTHOR(S) R3450SOS, ROOONOO, Work Karin Gipple Unit No. 2802-950 and 2844-220 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS( ES ) 8... ES ) 10. SPONSORING /MONITOR ING AGENCY REPORT NUMBER DTRC Materials Block, IR 11. SUPPLEMENTARY NOTES 12a. DISTRIBUTION /AVAILABILTY STATEMENT 12b

Chemotherapeutic Targeting of Fibulin-5 to Suppress Breast Cancer Invasion and Metastasis Stimulated by Transforming Growth Factor-Beta

DTIC Science & Technology

2012-10-22

Res. Commun 2004;316:997–1001. [PubMed: 15044083] 178. Karin M. NF-κB in cancer development and progression. Nature 2006;441:431. [PubMed: 16724054...of TWIST gene expression. Cancer Res 2007;67:9066–9076. [PubMed: 17909010] 199. Ali S, Coombes RC. Endocrine-responsive breast cancer and strategies...for combating resistance. Nat. Rev. Cancer 2002;2:101–112. [PubMed: 12635173] 200. Coombes RC, Gibson L, Hall E, Emson M, Bliss J. Aromatase

Structural Physics of Bee Honeycomb

NASA Astrophysics Data System (ADS)

Kaatz, Forrest; Bultheel, Adhemar; Egami, Takeshi

2008-03-01

Honeybee combs have aroused interest in the ability of honeybees to form regular hexagonal geometric constructs since ancient times. Here we use a real space technique based on the pair distribution function (PDF) and radial distribution function (RDF), and a reciprocal space method utilizing the Debye-Waller Factor (DWF) to quantify the order for a range of honeycombs made by Apis mellifera. The PDFs and RDFs are fit with a series of Gaussian curves. We characterize the order in the honeycomb using a real space order parameter, OP3, to describe the order in the combs and a two-dimensional Fourier transform from which a Debye-Waller order parameter, u, is derived. Both OP3 and u take values from [0, 1] where the value one represents perfect order. The analyzed combs have values of OP3 from 0.33 to 0.60 and values of u from 0.83 to 0.98. RDF fits of honeycomb histograms show that naturally made comb can be crystalline in a 2D ordered structural sense, yet is more `liquid-like' than cells made on `foundation' wax. We show that with the assistance of man-made foundation wax, honeybees can manufacture highly ordered arrays of hexagonal cells.

Structure determination from XAFS using high-accuracy measurements of x-ray mass attenuation coefficients of silver, 11 keV-28 keV, and development of an all-energies approach to local dynamical analysis of bond length, revealing variation of effective thermal contributions across the XAFS spectrum.

PubMed

Tantau, L J; Chantler, C T; Bourke, J D; Islam, M T; Payne, A T; Rae, N A; Tran, C Q

2015-07-08

We use the x-ray extended range technique (XERT) to experimentally determine the mass attenuation coefficient of silver in the x-ray energy range 11 kev-28 kev including the silver K absorption edge. The results are accurate to better than 0.1%, permitting critical tests of atomic and solid state theory. This is one of the most accurate demonstrations of cross-platform accuracy in synchrotron studies thus far. We derive the mass absorption coefficients and the imaginary component of the form factor over this range. We apply conventional XAFS analytic techniques, extended to include error propagation and uncertainty, yielding bond lengths accurate to approximately 0.24% and thermal Debye-Waller parameters accurate to 30%. We then introduce the FDMX technique for accurate analysis of such data across the full XAFS spectrum, built on full-potential theory, yielding a bond length accuracy of order 0.1% and the demonstration that a single Debye parameter is inadequate and inconsistent across the XAFS range. Two effective Debye-Waller parameters are determined: a high-energy value based on the highly-correlated motion of bonded atoms (σ(DW) = 0.1413(21) Å), and an uncorrelated bulk value (σ(DW) = 0.1766(9) Å) in good agreement with that derived from (room-temperature) crystallography.

Acquisition Review Quarterly (ARQ): Volume 10, Number 3, Summer 2003

DTIC Science & Technology

2003-01-01

PROJECT NUMBER Lt Col Robert L. Waller, USAF, (Ret), Robert Graham, Maj David R. King, USAF, Lt Col John D. Driessnack, USAF, LTC Michael D. Proctor...High-Technology Industries Implications for Industrial Policy Maj David R. King, USAF Lt Col John D. Driessnack, USAF Why the "T" in SMART A...Business School William H . Reed Director Michael Wynne Defense Contract Audit Agency Acting Under Secretary of Defense (Acquisition, Technology, and

Contact mechanics for poroelastic, fluid-filled media, with application to cartilage.

PubMed

Persson, B N J

2016-12-21

I study a simple contact mechanics model for a poroelastic, fluid-filled solid squeezed against a rigid, randomly rough substrate. I study how the fluid is squeezed out from the interface, and how the area of contact, and the average interfacial separation, change with time. I present numerical results relevant for a human cartilage. I show that for a fluid filled poroelastic solid the probability of cavitation (and the related wear as the cavities implode), and dynamical scraping (defined below and in Hutt and Persson, J. Chem. Phys. 144, 124903 (2016)), may be suppressed by fluid flow from the poroelastic solid into the (roughness induced) interfacial gap between the solids.

Contact mechanics for poroelastic, fluid-filled media, with application to cartilage

NASA Astrophysics Data System (ADS)

Persson, B. N. J.

2016-12-01

I study a simple contact mechanics model for a poroelastic, fluid-filled solid squeezed against a rigid, randomly rough substrate. I study how the fluid is squeezed out from the interface, and how the area of contact, and the average interfacial separation, change with time. I present numerical results relevant for a human cartilage. I show that for a fluid filled poroelastic solid the probability of cavitation (and the related wear as the cavities implode), and dynamical scraping (defined below and in Hutt and Persson, J. Chem. Phys. 144, 124903 (2016)), may be suppressed by fluid flow from the poroelastic solid into the (roughness induced) interfacial gap between the solids.

Implications of Integrating Women into the Marine Corps Infantry

DTIC Science & Technology

2015-01-01

account by the research. 17 Guy L. Siebold, “The Essence of Military Group Cohesion,” Armed Forces and Society, Vol. 33, No. 2, January 1, 2007, pp...assignment of female personnel reveals a dearth of critical mass concepts: 24 Jasmin Joecks, Kerstin Pull, and Karin Vetter, “Gender Diversity in the...Personnel Psychology, Vol. 60, No. 2, 2007, pp. 303–335. 42 David M. Marx and Jasmin S. Roman, “Female Role Models: Protecting Women’s Math Test

Prevention of Breast Cell Transformation by Blockade of the AP-1 Transcription Factor.

DTIC Science & Technology

1997-09-01

Alto, CA) to normal for transfection efficiency. Both the CAT (from Dr. M . Karin) and Luciferase reporter plasmids used were: -73/+63 ColCAT, -73/+63...1. Table 1: HMECs used in this study. Cells Name Source Phenotype Normal HMECs: NHMEC Clonetics Senescent, anchorage-dependent 184 M . Stampfer...Immortal HMECs: 184A I N5 M . Stampfer Immortal, anchorage dependent 184B5 M . Stampfer MCF10A A. Russo Transformed HMECs: MCF1OAneoT (ras) A. Russo Immortal

Regulation of Estrogen Receptor Transcription in Breast Carcinoma.

DTIC Science & Technology

1998-10-01

E-cadherin 40 and HSP27 41. It is certainly plausible to hypothesize a role for ERF-1 in the coordinate regulation of a set of genes in hormonally...responsive carcinomas. This conjecture is supported by the fact that breast carcinoma cell lines that express E-cadherin and HSP27 are also ERF- 1...regulatory promoter elements of the hsp27 gene in human breast cancer cells. Biochem. Biophys. Res. Com. 222, 155-163 (1996). 42. Imagawa, M., Chiu, R. & Karin

Comprehension and Memory of Spatial and Temporal Event Components

DTIC Science & Technology

2008-01-01

sitting in the leather chair listening to some music . [PROBE LAMP (filler)] He had headphones on, but Mary Agnes could still make out the lyrics. She...representation and processing of virtual spaces results in performance that is essentially identical to real spaces (e.g., Sun, Chan, & Campos , 2004) or with...that people treat virtual spaces in a manner very similar to real spaces (e.g., Sun, Chan, & Campos , 2004; Waller, Loomis, & Haun, 2004). The aim of

Higher-Order-Mode Diagnostics and Suppression in Superconducting Cavities (HOMSC12)

NASA Astrophysics Data System (ADS)

Jones, Roger M.

2014-01-01

From the 25th of June through Wednesday lunchtime of the 27th of June 2012 the Cockcroft Institute and ASTeC hosted an ICFA supported mini workshop on Higher-Order-Mode Diagnostics and Suppression in Superconducting Cavities (HOMSC12). The local organizing committee for this international workshop was chaired by S. Buckley (ASTeC/STFC), conference administration by S. Waller (ASTeC/STFC), and the scientific program committee by R.M. Jones (Cockcroft Institute/University of Manchester).

Soviet Countertrade

DTIC Science & Technology

1989-09-01

t5’ Wt USAFA-TR-89-5 SOVIET COUNTERTRADE Lt Col Robert L. Waller DEPARTMENT OF ECONOMICS AND GEOGRAPHY LOcv, Nv SEPTEMBER 1989 oFINAL REPORT APPROVED...8217Continue an owts if necelbary and identify by bloc* number) SWestern observers have noted the Soviet Union’s use of countertrade over the past...country before the buyer agrees to make the initial purchase. After defining the terms often used in relation to countertrade , this paper develops the

Deployment Repeatability

DTIC Science & Technology

2016-08-31

photogrammetry to track a set of LEDS in two dimensions, a method that was able to resolve 2.2-mm lateral displacements of a 40-meter boom. This method... displacements . Sub-milliradian repeatability in MOIRE [This is a stand-in section for the MOIRE case study, which Dave Waller is getting through...The structure will most likely be under this stowed state for a long time under displacement paths and put this data into a computationally cheap 1

A Case Study in Security Sector Reform: Learning from Security Sector Reform/Building in Afghanistan (October 2002-September 2003)

DTIC Science & Technology

2009-11-01

Amb G (Ambassador-Italy)10. Mrs. G (ISAF Political Advisor)11. Amb K (Amb-Japan)12. Mr. K (ISAF PolAd)13. Mrs. M (Chargé-Netherlands)14. Mr. M ...DCM-Japan)15. BG M (Senior Military Advisor-Finland)16. Amb N (Amb-UK)17. Mr. S (DCM-Germany)18. Lt Col S (MilAd-GE)19. Amb T (Donor Asst-U.S...Building, Year One: From Bonn to Kabul.” Antonio Donini , Norah Niland, and Karin Wermester, eds., Nation Building Unraveled, pp. 39-60. Bloomfield, CT

The U.S. Navy in the World (1991-2000): Context for U.S. Navy Capstone Strategies and Concepts

DTIC Science & Technology

2012-03-01

D0026420.A2/Final March 2012 CNA ANALYSIS & SOLUTIONS CNA is a not-for-profit organization whose professional staff of over 700 provides in-depth...www.dtic.mil or contact CNA Document Control and Distribution Section at 703-824-2123. Copyright © 2012 CNA This work was created in the performance of...N00014-11-D-0323 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER N/A 6. AUTHOR(S) Swartz, Peter M. Duggan, Karin 5d. PROJECT NUMBER N/A 5e. TASK

Multiscale weighted colored graphs for protein flexibility and rigidity analysis

NASA Astrophysics Data System (ADS)

Bramer, David; Wei, Guo-Wei

2018-02-01

Protein structural fluctuation, measured by Debye-Waller factors or B-factors, is known to correlate to protein flexibility and function. A variety of methods has been developed for protein Debye-Waller factor prediction and related applications to domain separation, docking pose ranking, entropy calculation, hinge detection, stability analysis, etc. Nevertheless, none of the current methodologies are able to deliver an accuracy of 0.7 in terms of the Pearson correlation coefficients averaged over a large set of proteins. In this work, we introduce a paradigm-shifting geometric graph model, multiscale weighted colored graph (MWCG), to provide a new generation of computational algorithms to significantly change the current status of protein structural fluctuation analysis. Our MWCG model divides a protein graph into multiple subgraphs based on interaction types between graph nodes and represents the protein rigidity by generalized centralities of subgraphs. MWCGs not only predict the B-factors of protein residues but also accurately analyze the flexibility of all atoms in a protein. The MWCG model is validated over a number of protein test sets and compared with many standard methods. An extensive numerical study indicates that the proposed MWCG offers an accuracy of over 0.8 and thus provides perhaps the first reliable method for estimating protein flexibility and B-factors. It also simultaneously predicts all-atom flexibility in a molecule.

Initial velocity V-shapes of young asteroid families

NASA Astrophysics Data System (ADS)

Bolin, Bryce T.; Walsh, Kevin J.; Morbidelli, Alessandro; Delbó, Marco

2018-01-01

Ejection velocity fields of asteroid families are largely unconstrained due to the fact that members disperse relatively quickly on Myr time-scales by secular resonances and the Yarkovsky effect. The spreading of fragments in a by the Yarkovsky effect is indistinguishable from the spreading caused by the initial ejection of fragments. By examining families <20 Myr old, we can use the V-shape identification technique to separate family shapes that are due to the initial ejection velocity field and those that are due to the Yarkovsky effect. Asteroid families that are <20 Myr old provide an opportunity to study the velocity field of family fragments before they become too dispersed. Only the Karin family's initial velocity field has been determined and scales inversely with diameter, D-1. We have applied the V-shape identification technique to constrain young families' initial ejection velocity fields by measuring the curvature of their fragments' V-shape correlation in semimajor axis, a, versus D-1 space. Curvature from a straight line implies a deviation from a scaling of D-1. We measure the V-shape curvature of 11 young asteroid families including the 1993 FY12, Aeolia, Brangane, Brasilia, Clarissa, Iannini, Karin, Konig, Koronis(2), Theobalda and Veritas asteroid families. We find that the majority of asteroid families have initial ejection velocity fields consistent with ∼D-1 supporting laboratory impact experiments and computer simulations of disrupting asteroid parent bodies.

An extended X-Ray absorption fine structure (exafs) study of copper (II) sulphate pentahydrate

NASA Astrophysics Data System (ADS)

Joyner, Richard W.

1980-05-01

The EXAFS spectrum of copper (II) sulphate pentahydrate has been measured using synchrotron radiation. Comparison with the results of ab initio calculation gives a mean copper-oxygen distance of 1.95 Å, in reasonable agreement with the known value of 1.97 Å. The relation between the EXAFS Debye-Waller factor and thermal parameters measured by neutron diffraction is discussed. Absence in the EXAFS spectrum of evidence for the second-nearest neighbour oxygen atoms, at Cu-O ≈ 2.4 Å, is discussed.

Combustion of Solid Propellants (La Combustion des Propergols Solides)

DTIC Science & Technology

1991-07-01

cin~tiques initiales. Il relatives A Ia granulom ~trie ct la surface eat s~me possible dWaller plus loin et sp~cifique des catalyseurs existent, il est...grand nombro do vari~t~s granulom ~triques des proporgols. On pout ainsi observer uno mont donc utilis~es induatriellemont pour notte influence du temps...et do la ajuster la vitosso des vari~tds do tempdrature do laminage sur la diminution granulom ~trie moyenno 400, 200, 100, 10, 3 de l’exposant do

Electron-beam induced amorphization of stishovite: Silicon-coordination change observed using Si K-edge extended electron energy-loss fine structure

NASA Astrophysics Data System (ADS)

van Aken, P. A.; Sharp, T. G.; Seifert, F.

The analysis of the extended energy-loss fine structure (EXELFS) of the Si K-edge for sixfold-coordinated Si in synthetic stishovite and fourfold-coordinated Si in natural α-quartz is reported by using electron energy-loss spectroscopy (EELS) in combination with transmission electron microscopy (TEM). The stishovite Si K-edge EXELFS spectra were measured as a time-dependent series to document irradiation-induced amorphization. The amorphization was also investigated through the change in Si K- and O K-edge energy-loss near edge structure (ELNES). For α-quartz, in contrast to stishovite, electron irradiation-induced vitrification, verified by selected area electron diffraction (SAED), produced no detectable changes of the EXELFS. The Si K-edge EXELFS were analysed with the classical extended X-ray absorption fine structure (EXAFS) treatment and compared to ab initio curve-waved multiple-scattering (MS) calculations of EXAFS spectra for stishovite and α-quartz. Highly accurate information on the local atomic environment of the silicon atoms during the irradiation-induced amorphization of stishovite is obtained from the EXELFS structure parameters (Si-O bond distances, coordination numbers and Debye-Waller factors). The mean Si-O bond distance R and mean Si coordination number N changes from R=0.1775 nm and N=6 for stishovite through a disordered intermediate state (R 0.172 nm and N 5) to R 0.167 nm and N 4.5 for a nearly amorphous state similar to α-quartz (R=0.1609 nm and N=4). During the amorphization process, the Debye-Waller factor (DWF) passes through a maximum value of as it changes from for sixfold to for fourfold coordination of Si. This increase in Debye-Waller factor indicates an increase in mean-square relative displacement (MSRD) between the central silicon atom and its oxygen neighbours that is consistent with the presence of an intermediate structural state with fivefold coordination of Si. The distribution of coordination states can be estimated by

Misfit strain of oxygen precipitates in Czochralski silicon studied with energy-dispersive X-ray diffraction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gröschel, A., E-mail: alexander.groeschel@fau.de; Will, J.; Bergmann, C.

Annealed Czochralski Silicon wafers containing SiO{sub x} precipitates have been studied by high energy X-ray diffraction in a defocused Laue setup using a laboratory tungsten tube. The energy dispersive evaluation of the diffracted Bragg intensity of the 220 reflection within the framework of the statistical dynamical theory yields the static Debye-Waller factor E of the crystal, which gives access to the strain induced by the SiO{sub x} precipitates. The results are correlated with precipitate densities and sizes determined from transmission electron microscopy measurements of equivalent wafers. This allows for the determination of the constrained linear misfit ε between precipitate andmore » crystal lattice. For samples with octahedral precipitates the values ranging from ε = 0.39 (+0.28/−0.12) to ε = 0.48 (+0.34/−0.16) indicate that self-interstitials emitted into the matrix during precipitate growth contribute to the lattice strain. In this case, the expected value calculated from literature values is ε = 0.26 ± 0.05. Further, the precise evaluation of Pendellösung oscillations in the diffracted Bragg intensity of as-grown wafers reveals a thermal Debye-Waller parameter for the 220 reflection B{sup 220}(293 K) of 0.5582 ± 0.0039 Å{sup 2} for a structure factor based on spherically symmetric scattering contributions.« less

The Future Nuclear Landscape

DTIC Science & Technology

2007-04-01

Paul I. Bernstein, John P . Caves, Jr., and John F. Reichart Center for the Study of Weapons of Mass Destruction A p ri l 20 07 Report...participants from the government and private sectors. JohN F. ReiChART Director S TA F F W. SeTh CARUS Deputy Director JohN P . CAveS, JR. Senior...Research Fellow RebeCCA K.C. heRSMAN Senior Research Fellow FoRReST e. WALLeR, JR. Senior Research Fellow RiChARD A. Love Research Fellow Stephen D . Carey

Rubber friction and tire dynamics.

PubMed

Persson, B N J

2011-01-12

We propose a simple rubber friction law, which can be used, for example, in models of tire (and vehicle) dynamics. The friction law is tested by comparing numerical results to the full rubber friction theory (Persson 2006 J. Phys.: Condens. Matter 18 7789). Good agreement is found between the two theories. We describe a two-dimensional (2D) tire model which combines the rubber friction model with a simple mass-spring description of the tire body. The tire model is very flexible and can be used to accurately calculate μ-slip curves (and the self-aligning torque) for braking and cornering or combined motion (e.g. braking during cornering). We present numerical results which illustrate the theory. Simulations of anti-blocking system (ABS) braking are performed using two simple control algorithms.

Comparative surface dynamics of amorphous and semicrystalline polymer films

PubMed Central

Becker, James S.; Brown, Ryan D.; Killelea, Daniel R.; Yuan, Hanqiu; Sibener, S. J.

2011-01-01

The surface dynamics of amorphous and semicrystalline polymer films have been measured using helium atom scattering. Time-of-flight data were collected to resolve the elastic and inelastic scattering components in the diffuse scattering of neutral helium atoms from the surface of a thin poly(ethylene terephthalate) film. Debye–Waller attenuation was observed for both the amorphous and semicrystalline phases of the polymer by recording the decay of elastically scattered helium atoms with increasing surface temperature. Thermal attenuation measurements in the specular scattering geometry yielded perpendicular mean-square displacements of 2.7•10-4 Å2 K-1 and 3.1•10-4 Å2 K-1 for the amorphous and semicrystalline surfaces, respectively. The semicrystalline surface was consistently ∼15% softer than the amorphous across a variety of perpendicular momentum transfers. The Debye–Waller factors were also measured at off-specular angles to characterize the parallel mean-square displacements, which were found to increase by an order of magnitude over the perpendicular mean-square displacements for both surfaces. In contrast to the perpendicular motion, the semicrystalline state was ∼25% stiffer than the amorphous phase in the surface plane. These results were uniquely accessed through low-energy neutral helium atom scattering due to the highly surface-sensitive and nonperturbative nature of these interactions. The goal of tailoring the chemical and physical properties of complex advanced materials requires an improved understanding of interfacial dynamics, information that is obtainable through atomic beam scattering methods. PMID:20713734

EXAFS and XANES investigation of (Li, Ni) codoped ZnO thin films grown by pulsed laser deposition.

PubMed

Mino, Lorenzo; Gianolio, Diego; Bardelli, Fabrizio; Prestipino, Carmelo; Senthil Kumar, E; Bellarmine, F; Ramanjaneyulu, M; Lamberti, Carlo; Ramachandra Rao, M S

2013-09-25

Ni doped, Li doped and (Li, Ni) codoped ZnO thin films were successfully grown using a pulsed laser deposition technique. Undoped and doped ZnO thin films were investigated using extended x-ray absorption fine structure (EXAFS) and x-ray absorption near edge spectroscopy (XANES). Preliminary investigations on the Zn K-edge of the undoped and doped ZnO thin films revealed that doping has not influenced the average Zn-Zn bond length and Debye-Waller factor. This shows that both Ni and Li doping do not appreciably affect the average local environment of Zn. All the doped ZnO thin films exhibited more than 50% of substitutional Ni, with a maximum of 77% for 2% Ni and 2% Li doped ZnO thin film. The contribution of Ni metal to the EXAFS signal clearly reveals the presence of Ni clusters. The Ni-Ni distance in the Ni(0) nanoclusters, which are formed in the film, is shorter with respect to the reference Ni metal foil and the Debye-Waller factor is higher. Both facts perfectly reflect what is expected for metal nanoparticles. At the highest doping concentration (5%), the presence of Li favors the growth of a secondary NiO phase. Indeed, 2% Ni and 5% Li doped ZnO thin film shows %Nisub = 75 ± 11, %Nimet = 10 ± 8, %NiO = 15 ± 8. XANES studies further confirm that the substitutional Ni is more than 50% in all the samples. These results explain the observed magnetic properties.

Communication: Relationship between solute localization and diffusion in a dynamically constrained polymer system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saylor, David M.; Jawahery, Sudi; Silverstein, Joshua S.

2016-07-21

We investigate the link between dynamic localization, characterized by the Debye–Waller factor, 〈u{sup 2}〉, and solute self-diffusivity, D, in a polymer system using atomistic molecular dynamics simulations and vapor sorption experiments. We find a linear relationship between lnD and 1/〈u{sup 2}〉 over more than four decades of D, encompassing most of the glass formation regime. The observed linearity is consistent with the Langevin dynamics in a periodically varying potential field and may offer a means to rapidly assess diffusion based on the characterization of dynamic localization.

Structural relaxation in a binary metallic melt: Molecular dynamics computer simulation of undercooled Al80Ni20

NASA Astrophysics Data System (ADS)

Das, Subir K.; Horbach, Jürgen; Voigtmann, Thomas

2008-08-01

Molecular dynamics computer simulations are performed to study structure and structural relaxation in the glassforming metallic alloy Al80Ni20 . The interactions between the particles are modeled by an effective potential of the embedded atom type. Our model of Al80Ni20 exhibits chemical short-range order (CSRO) that is reflected in a broad prepeak around a wave number of 1.8Å-1 in the partial static structure factor for the Ni-Ni correlations. The CSRO is due to the preference of Ni atoms to have Al rather than Ni atoms as nearest neighbors. By analyzing incoherent and coherent intermediate scattering functions as well as self-diffusion constants and shear viscosity, we discuss how the chemical ordering is reflected in the dynamics of the deeply undercooled melt. The q dependence of the α relaxation time as well as the Debye-Waller factor for the Al-Al correlations show oscillations at the location of the prepeak in the partial static structure factor for the Ni-Ni correlations. The latter feature of the Debye-Waller factor is well reproduced by a calculation in the framework of the mode coupling theory (MCT) of the glass transition, using the partial static structure factors from the simulation as input. We also check the validity of the Stokes-Einstein-Sutherland formula that relates the self-diffusion coefficients with the shear viscosity. We show that it breaks down already far above the mode coupling critical temperature Tc . The failure of the Stokes-Einstein-Sutherland relation is not related to the specific chemical ordering in Al80Ni20 .

Communication: Fast dynamics perspective on the breakdown of the Stokes-Einstein law in fragile glassformers

NASA Astrophysics Data System (ADS)

Puosi, F.; Pasturel, A.; Jakse, N.; Leporini, D.

2018-04-01

The breakdown of the Stokes-Einstein (SE) law in fragile glassformers is examined by Molecular-Dynamics simulations of atomic liquids and polymers and consideration of the experimental data concerning the archetypical ortho-terphenyl glassformer. All the four systems comply with the universal scaling between the viscosity (or the structural relaxation) and the Debye-Waller factor ⟨u2⟩, the mean square amplitude of the particle rattling in the cage formed by the surrounding neighbors. It is found that the SE breakdown is scaled in a master curve by a reduced ⟨u2⟩. Two approximated expressions of the latter, with no and one adjustable parameter, respectively, are derived.

Strangles: a pathogenic legacy of the war horse.

PubMed

Waller, Andrew S

2016-01-23

Strangles, characterised by pyrexia followed by abscessation of the lymph nodes of the head and neck, was first described in 1251 (Rufus 1251) and the causative agent, Streptococcus equi, was identified in 1888 (Schutz 1888). However, despite more than a century of research into this disease, strangles remains the most frequently diagnosed infection of horses with over 600 outbreaks being identified in the UK alone each year (Parkinson and others 2011). Here, Andrew Waller reviews some of the recent advances in the understanding of the evolution of S equi and puts this into the context of preventing and resolving outbreaks of infection. British Veterinary Association.

Structural anisotropy in amorphous SnO2 film probed by X-ray absorption spectroscopy

NASA Astrophysics Data System (ADS)

Zhu, Q.; Ma, Q.; Buchholz, D. B.; Chang, R. P. H.; Bedzyk, M. J.; Mason, T. O.

2013-07-01

Polarization-dependent X-ray absorption measurements reveal the existence of structural anisotropy in amorphous (a-) SnO2 film. The anisotropy is readily seen for the second neighbor interaction whose magnitude differs along three measured directions. The differences can be well accounted for by 10%-20% variation in the Debye-Waller factor. Instead of a single Gaussian distribution found in crystalline SnO2, the Sn-O bond distribution is bimodal in a-SnO2 whose separation shows a weak angular dependence. The oxygen vacancies, existing in the a-SnO2 film in the order of 1021 cm-3, distribute preferentially along the film surface direction.

Approximate changes in water levels in wells completed in the Chicot and Evangeline aquifers, 1977-92 and 1991-92, and measured compaction, 1973-91 in the Houston-Galveston region, Texas.

USGS Publications Warehouse

Kasmarek, Mark C.; Barbie, Dana L.; Campodonico, Al

1992-01-01

This report is one in a series of reports that depict water-level changes since 1977 and compaction of subsurface material since 1973.  The report was prepared in cooperation with the Harris-Galveston Coastal Subsidence District and the City of Houston, and presents maps showing the approximate changes in water-levels in wells completed in the Chicot and Evangeline aquifers, 1977-92 and 1991-92 (figs. 1-4), and measured compations, 1973-91 (figs. 5 and 6), in the Houston-Galveston region.  The Houston-Galveston region includes Harris and Galveston Counties and adjacent parts of Brazoria, Fort Bend, Waller, Montgomery, Liberty, and Chambers Counties.

Approximate changes in water levels in wells completed in the Chicot and Evangeline aquifers, 1977-93 and 1992-93, and measured compaction, 1973-92, in the Houston-Galveston region, Texas

USGS Publications Warehouse

Kasmarek, Mark C.; Coplin, L.S.; Campodonico, Al

1993-01-01

This report is one in a series of reports that depict water-level changes since 1977 and compaction of subsurface material since 1973.  The report was prepared in cooperation with the Harris-Galveston Coastal Subsidence District and the City of Houston, and presents maps showing the approximate changes in water levels in wells completed in the Chicot and Evangeline aquifers, 1977-93 and 1992-93 (figs. 1-4), and measured compaction, 1973-92 (figs. 5 and 6), in the Houston-Galveston region.  The Houston-Galveston region includes Harris and Galveston Counties and adjacent parts of Brazoria, Fort Bend, Waller, Montgomery, Liberty, and Chambers Counties.

VizieR Online Data Catalog: SN 2007on and SN 2011iv light curves (Gall+, 2018)

NASA Astrophysics Data System (ADS)

Gall, C.; Stritzinger, M. D.; Ashall, C.; Baron, E.; Burns, C. R.; Hoeflich, P.; Hsiao, E. Y.; Mazzali, P. A.; Phillips, M. M.; Filippenko, A. V.; Anderson, J. P.; Benetti, S.; Brown, P. J.; Campillay, A.; Challis, P.; Contreras, C.; Elias de La Rosa, N.; Folatelli, G.; Foley, R. J.; Fraser, M.; Holmbo, S.; Marion, G. H.; Morrell, N.; Pan, Y.-C.; Pignata, G.; Suntzeff, N. B.; Taddia, F.; Torres Robledo, S.; Valenti, S.

2017-11-01

Detailed optical and NIR light curves of SN 2007on obtained by the first phase of the Carnegie Supernova Project (CSP-I, 2004-2009; Hamuy et al., 2006PASP..118....2H) were published by Stritzinger et al. (2011, Cat. J/AJ/142/156).UV uvw2-, uvm2-, and uvw1-band imaging of both SN 2007on and SN 2011iv were obtained with Swift (+ UVOT). Photome- try of SN 2007on and SN 2011iv was computed following the method described in detail by Brown et al. (2014Ap&SS.354...89B), who use the calibration published by Breeveld et al. (2011, AIPCS, 1358, 373). The Swift UVOT images and photometry are also available as part of the Swift Optical Ultraviolet Supernova Archive (SOUSA; Brown et al. 2014Ap&SS.354...89B). Optical ugriBV-band imaging of SN 2007on and SN 2011iv was obtained with the Henrietta Swope 1.0m telescope (+ SITe3 direct CCD camera) located at the Las Campanas Observatory (LCO). The NIR YJH-band imaging of SN 2007on was obtained with the Swope (+ RetroCam) and the Irenee du Pont 2.5m (+ WIRC: Wide Field Infrared Camera) telescopes (Stritzinger et al., Cat. J/AJ/142/156), while in the case of SN 2011iv all NIR YJH-band imaging was taken with RetroCam attached to the Irenee du Pont telescope. The optical local sequence is calibrated relative to Landolt (1992AJ....104..372L) (BV) and Smith et al. (2002AJ....123.2121S) (ugri) standard-star fields observed over multiple photometric nights. The NIR J-band and H-band local sequences were calibrated relative to the Persson et al. (1998AJ....116.2475P) standard stars, while the Y- band local sequence was calibrated relative to standard Y-band magnitudes computed using a combination of stellar atmosphere models (Castelli & Kurucz, 2003, IAUSymp, 210, A20) with the J-Ks colours of the Persson et al. standard-star catalogue (Hamuy et al., 2006PASP..118....2H). (5 data files).

Rubber friction on road surfaces: Experiment and theory for low sliding speeds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lorenz, B.; Persson, B. N. J.; Oh, Y. R.

We study rubber friction for tire tread compounds on asphalt road surfaces. The road surface topographies are measured using a stylus instrument and atomic force microscopy, and the surface roughness power spectra are calculated. The rubber viscoelastic modulus mastercurves are obtained from dynamic mechanical analysis measurements and the large-strain effective modulus is obtained from strain sweep data. The rubber friction is measured at different temperatures and sliding velocities, and is compared to the calculated data obtained using the Persson contact mechanics theory. We conclude that in addition to the viscoelastic deformations of the rubber surface by the road asperities, theremore » is an important contribution to the rubber friction from shear processes in the area of contact. The analysis shows that the latter contribution may arise from rubber molecules (or patches of rubber) undergoing bonding-stretching-debonding cycles as discussed in a classic paper by Schallamach.« less

Correlated Debye model for atomic motions in metal nanocrystals

NASA Astrophysics Data System (ADS)

Scardi, P.; Flor, A.

2018-05-01

The Correlated Debye model for the mean square relative displacement of atoms in near-neighbour coordination shells has been extended to include the effect of finite crystal size. This correctly explains the increase in Debye-Waller coefficient observed for metal nanocrystals. A good match with Molecular Dynamics simulations of Pd nanocrystals is obtained if, in addition to the phonon confinement effect of the finite domain size, proper consideration is also given to the static disorder component caused by the undercoordination of surface atoms. The new model, which addresses the analysis of the Pair Distribution Function and powder diffraction data collected at different temperatures, was preliminarily tested on recently published experimental data on nanocrystalline Pt powders.

Chemical complexity induced local structural distortion in NiCoFeMnCr high-entropy alloy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Fuxiang; Tong, Yang; Jin, Ke

In order to study chemical complexity-induced lattice distortion in high-entropy alloys, the static Debye–Waller (D-W) factor of NiCoFeMnCr solid solution alloy is measured with low temperature neutron diffraction, ambient X-ray diffraction, and total scattering methods. Here, the static atomic displacement parameter of the multi-element component alloy at 0 K is 0.035–0.041 Å, which is obvious larger than that of element Ni (~0 Å). The atomic pair distance between individual atoms in the alloy investigated with extended X-ray absorption fine structure (EXAFS) measurements indicates that Mn has a slightly larger bond distance (~0.4%) with neighbor atoms than that of others.

Vibron Solitons and Soliton-Induced Infrared Spectra of Crystalline Acetanilide

NASA Astrophysics Data System (ADS)

Takeno, S.

1986-01-01

Red-shifted infrared spectra at low temperatures of amide I (C=O stretching) vibrations of crystalline acetanilide measured by Careri et al. are shown to be due to vibron solitons, which are nonlinearity-induced localized modes of vibrons arising from their nonlinear interactions with optic-type phonons. A nonlinear eigenvalue equation giving the eigenfrequency of stationary solitons is solved approximately by introducing lattice Green's functions, and the obtained result is in good agreement with the experimental result. Inclusion of interactions with acoustic phonons yields the Debye-Waller factor in the zero-phonon line spectrum of vibron solitons, in a manner analogous to the case of impurity-induced localized harmonic phonon modes in alkali halides.

Chemical complexity induced local structural distortion in NiCoFeMnCr high-entropy alloy

DOE PAGES

Zhang, Fuxiang; Tong, Yang; Jin, Ke; ...

2018-06-16

In order to study chemical complexity-induced lattice distortion in high-entropy alloys, the static Debye–Waller (D-W) factor of NiCoFeMnCr solid solution alloy is measured with low temperature neutron diffraction, ambient X-ray diffraction, and total scattering methods. Here, the static atomic displacement parameter of the multi-element component alloy at 0 K is 0.035–0.041 Å, which is obvious larger than that of element Ni (~0 Å). The atomic pair distance between individual atoms in the alloy investigated with extended X-ray absorption fine structure (EXAFS) measurements indicates that Mn has a slightly larger bond distance (~0.4%) with neighbor atoms than that of others.

VizieR Online Data Catalog: NGC1333-IRAS2A water snowline imaging (van 't Hoff+, 2018)

NASA Astrophysics Data System (ADS)

van't Hoff, M. L. R.; Persson, M. V.; Harsono, D.; Taquet, V.; Jorgensen, J. K.; Visser, R.; Bergin, E. A.; van Dishoeck, E. F.

2018-02-01

Datacubes in fits format of the H13CO+, H_{Persson et al., 2012A&A...541A..39P. The DCO+ J=2-1 transition at 144.068GHz was observed as part of a larger study during July, August, November 2010 and March 2011 with a spectral resolution of 4km/s. (2 data files).}

Is moral bioenhancement dangerous?

PubMed

Drake, Nicholas

2016-01-01

In a recent response to Persson and Savulescu's Unfit for the Future, Nicholas Agar argues that moral bioenhancement is dangerous. His grounds for this are that normal moral judgement should be privileged because it involves a balance of moral subcapacities; moral bioenhancement, Agar argues, involves the enhancement of only particular moral subcapacities, and thus upsets the balance inherent in normal moral judgement. Mistaken moral judgements, he says, are likely to result. I argue that Agar's argument fails for two reasons. First, having strength in a particular moral subcapacity does not necessarily entail a worsening of moral judgement; it can involve strength in a particular aspect of morality. Second, normal moral judgement is not sufficiently likely to be correct to be the standard by which moral judgements are measured. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://www.bmj.com/company/products-services/rights-and-licensing/

Parametric Dependencies in Aero-Elastic, Articulated, Flapping Flight

NASA Astrophysics Data System (ADS)

Willis, D. J.; Persson, P.; Peraire, J.; Breuer, K. S.

2006-11-01

Aero-elastic coupling and wing articulation both play a vital role in the generation of lift and propulsion in birds, bats and fish. We present results from a computational study that employs several tools of varying fidelity to explore the role of flexible structures on the performance and efficiency of bird and bat flight mechanics. The tools (both 2-D and 3-D) include a Wake only ``Betz'' analysis following the work of Hall, Pigott and Hall (J. Aircaft, 1998), a potential flow model coupled to a free-vortex wake (Willis, Peraire & White, AIAA 2005-0854), and lastly, a discontinuous Galerkin solver (Persson & Peraire, AIAA 2006-0113) for the full Navier-Stokes equations. Structural models include springs, beams and membranes to represent compliant biological structures. The results demonstrate the changes in efficiency that can be achieved by different parametric variations in the flight behavior, including the effects of increasing kinematic degrees of freedom (e.g. articulated wings) and the effect of compliance in wing and skeletal structures.

'It [HIV] is part of the relationship': exploring communication among HIV-serodiscordant couples in South Africa and Tanzania.

PubMed

Rispel, Laetitia C; Cloete, Allanise; Metcalf, Carol A; Moody, Kevin; Caswell, Georgina

2012-01-01

In many sub-Saharan African countries, a high proportion of people living with HIV are in long-term serodiscordant relationships. This paper explores how HIV serodiscordance shapes communication among couples in long-term HIV-serodiscordant relationships. A total of 36 couples were purposively recruited through healthcare providers and civil society organisations in South Africa (26) and Tanzania (10). We explored couples' portrayal of living in a serodiscordant relationship by conducting semi-structured interviews with each partner separately, followed by a joint interview with both partners. Using an adaptation of Persson's model on sero-silence and sero-sharing, we categorised coping style as 'sero-silent' if partners reported that they did not talk much with each other about issues related to their serodiscordant status or as 'sero-sharing' if they portrayed HIV as being an issue which they dealt with together. Some couples exhibited features of both coping styles and, at times, partners differed in their ways of coping.

Disorder in Ag7GeSe5I, a superionic conductor: temperature-dependent anharmonic structural study.

PubMed

Albert, Stéphanie; Pillet, Sébastien; Lecomte, Claude; Pradel, Annie; Ribes, Michel

2008-02-01

A temperature-dependent structural investigation of the substituted argyrodite Ag(7)GeSe(5)I has been carried out on a single crystal from 15 to 475 K, in steps of 50 K, and correlated to its conductivity properties. The argyrodite crystallizes in a cubic cell with the F\\bar 43m space group. The crystal structure exhibits high static and dynamic disorder which has been efficiently accounted for using a combination of (i) Gram-Charlier development of the Debye-Waller factors for iodine and silver, and (ii) a split-atom model for Ag(+) ions. An increased delocalization of the mobile d(10) Ag(+) cations with temperature has been clearly shown by the inspection of the joint probability-density functions; the corresponding diffusion pathways have been determined.

The origins of electrocardiography in Poland

PubMed Central

2015-01-01

The progress of science and technology in the 19th century enabled better understanding of the electrical activity that occurs during a heartbeat. However, it was only the construction and introduction of the galvanometer that cleared the way for appropriate experimental and clinical studies. Marey, Waller, Wenckebach, Einthoven, and Pardee are just examples of the world's pioneers of electrocardiography. Polish researchers, including Cybulski, Eiger, Rzętkowski, Surzycki, and Latkowski, also contributed to the development of this area of study. The following article is a review aiming to reconstruct the origins of electrocardiography in Poland, both as a measurement method used in experiments and as a diagnostic tool in clinical studies conducted in the years preceding the outbreak of World War I. PMID:26336508

PDB-NMA of a protein homodimer reproduces distinct experimental motility asymmetry.

PubMed

Tirion, Monique M; Ben-Avraham, Daniel

2018-01-16

We have extended our analytically derived PDB-NMA formulation, Atomic Torsional Modal Analysis or ATMAN (Tirion and ben-Avraham 2015 Phys. Rev. E 91 032712), to include protein dimers using mixed internal and Cartesian coordinates. A test case on a 1.3 [Formula: see text] resolution model of a small homodimer, ActVA-ORF6, consisting of two 112-residue subunits identically folded in a compact 50 [Formula: see text] sphere, reproduces the distinct experimental Debye-Waller motility asymmetry for the two chains, demonstrating that structure sensitively selects vibrational signatures. The vibrational analysis of this PDB entry, together with biochemical and crystallographic data, demonstrates the cooperative nature of the dimeric interaction of the two subunits and suggests a mechanical model for subunit interconversion during the catalytic cycle.

Fungible weights in logistic regression.

PubMed

Jones, Jeff A; Waller, Niels G

2016-06-01

In this article we develop methods for assessing parameter sensitivity in logistic regression models. To set the stage for this work, we first review Waller's (2008) equations for computing fungible weights in linear regression. Next, we describe 2 methods for computing fungible weights in logistic regression. To demonstrate the utility of these methods, we compute fungible logistic regression weights using data from the Centers for Disease Control and Prevention's (2010) Youth Risk Behavior Surveillance Survey, and we illustrate how these alternate weights can be used to evaluate parameter sensitivity. To make our work accessible to the research community, we provide R code (R Core Team, 2015) that will generate both kinds of fungible logistic regression weights. (PsycINFO Database Record (c) 2016 APA, all rights reserved).

PDB-NMA of a protein homodimer reproduces distinct experimental motility asymmetry

NASA Astrophysics Data System (ADS)

Tirion, Monique M.; ben-Avraham, Daniel

2018-03-01

We have extended our analytically derived PDB-NMA formulation, Atomic Torsional Modal Analysis or ATMAN (Tirion and ben-Avraham 2015 Phys. Rev. E 91 032712), to include protein dimers using mixed internal and Cartesian coordinates. A test case on a 1.3 {\\mathringA} resolution model of a small homodimer, ActVA-ORF6, consisting of two 112-residue subunits identically folded in a compact 50 {\\mathringA} sphere, reproduces the distinct experimental Debye-Waller motility asymmetry for the two chains, demonstrating that structure sensitively selects vibrational signatures. The vibrational analysis of this PDB entry, together with biochemical and crystallographic data, demonstrates the cooperative nature of the dimeric interaction of the two subunits and suggests a mechanical model for subunit interconversion during the catalytic cycle.

Pressure-induced positive electrical resistivity coefficient in Ni-Nb-Zr-H glassy alloy

NASA Astrophysics Data System (ADS)

Fukuhara, M.; Gangli, C.; Matsubayashi, K.; Uwatoko, Y.

2012-06-01

Measurements under hydrostatic pressure of the electrical resistivity of (Ni0.36Nb0.24Zr0.40)100-xHx (x = 9.8, 11.5, and 14) glassy alloys have been made in the range of 0-8 GPa and 0.5-300 K. The resistivity of the (Ni0.36Nb0.24Zr0.40)86H14 alloy changed its sign from negative to positive under application of 2-8 GPa in the temperature range of 300-22 K, coming from electron-phonon interaction in the cluster structure under pressure, accompanied by deformation of the clusters. In temperature region below 22 K, the resistivity showed negative thermal coefficient resistance by Debye-Waller factor contribution, and superconductivity was observed at 1.5 K.

Flat-ramp vs. convex-concave thrust geometries in a deformable hanging wall: new insights from analogue modeling experiments

NASA Astrophysics Data System (ADS)

Almeida, Pedro; Tomas, Ricardo; Rosas, Filipe; Duarte, Joao; Terrinha, Pedro

2015-04-01

Different modes of strain accommodation affecting a deformable hanging-wall in a flat-ramp-flat thrust system were previously addressed through several (sandbox) analog modeling studies, focusing on the influence of different variables, such as: a) thrust ramp dip angle and friction (Bonini et al, 2000); b) prescribed thickness of the hanging-wall (Koy and Maillot, 2007); and c) sin-thrust erosion (compensating for topographic thrust edification, e.g. Persson and Sokoutis, 2002). In the present work we reproduce the same experimental procedure to investigate the influence of two different parameters on hanging-wall deformation: 1) the geometry of the thrusting surface; and 2) the absence of a velocity discontinuity (VD) that is always present in previous similar analogue modeling studies. Considering the first variable we use two end member ramp geometries, flat-ramp-flat and convex-concave, to understand the control exerted by the abrupt ramp edges in the hanging-wall stress-strain distribution, comparing the obtain results with the situation in which such edge singularities are absent (convex-concave thrust ramp). Considering the second investigated parameter, our motivation was the recognition that the VD found in the different analogue modeling settings simply does not exist in nature, despite the fact that it has a major influence on strain accommodation in the deformable hanging-wall. We thus eliminate such apparatus artifact from our models and compare the obtained results with the previous ones. Our preliminary results suggest that both investigated variables play a non-negligible role on the structural style characterizing the hanging-wall deformation of convergent tectonic settings were such thrust-ramp systems were recognized. Acknowledgments This work was sponsored by the Fundação para a Ciência e a Tecnologia (FCT) through project MODELINK EXPL/GEO-GEO/0714/2013. Pedro Almeida wants to thank to FCT for the Ph.D. grant (SFRH/BD/52556/2014) under the

Willem Einthoven and the birth of clinical electrocardiography a hundred years ago.

PubMed

Barold, S Serge

2003-01-01

The first electrocardiogram (ECG) from the intact human heart was recorded with a mercury capillary electrometer by Augustus Waller in May 1887 at St. Mary's Hospital, London. The tracings were poor and exhibited only 2 distorted deflections. Willem Einthoven (1860-1927) who was professor of physiology at the University of Leiden, The Netherlands, began his studies of the ECG with the mercury capillary electrometer, and improved its distortion mathematically so that he was finally able to register a good representation of the ECG before the beginning of the twentieth century. He later further improved ECG recordings with the introduction of a string galvanometer of his design. Einthoven published his first article about the string galvanometer in 1901, followed by a more detailed description in 1903 which included a report of ECGs taken with the new instrument. The year 2002 marks the centennial of Willem Einthoven's first recording of the ECG in a clinically applicable fashion with the string galvanometer. The clinical use of Einthoven's immobile equipment required transtelephonic transmission of the ECG from the physiology laboratory to the clinic at the Academic Hospital about a mile away as documented in the 1906 paper on the "télécardiogramme". This report contained a wealth of ECG patterns and arrhythmias. Einthoven developed a system of electrocardiographic standardization that continues to be used all over the world and introduced the triaxial bipolar system with 3 limb leads and thus established uniformity of the recording process. Einthoven also conceived the famous equilateral triangle with leads I, II, and III at its sides and the calculation of the electrical axis (in the frontal plane) depicted as a single vector with an arrow at the center of the triangle. Einthoven recognized the great potential importance of the ECG as a diagnostic and investigative tool and his achievements made him the founder of modern electrocardiography. He was awarded the

Size-dependent penetrant diffusion in polymer glasses.

PubMed

Meng, Dong; Zhang, Kai; Kumar, Sanat K

2018-05-18

Molecular Dynamics simulations are used to understand the underpinning basis of the transport of gas-like solutes in deeply quenched polymeric glasses. As found in previous work, small solutes, with sizes smaller than 0.15 times the chain monomer size, move as might be expected in a medium with large pores. In contrast, the motion of larger solutes is activated and is strongly facilitated by matrix motion. In particular, solute motion is coupled to the local elastic fluctuations of the matrix as characterized by the Debye-Waller factor. While similar ideas have been previously proposed for the viscosity of supercooled liquids above their glass transition, to our knowledge, this is the first illustration of this concept in the context of solute mass transport in deeply quenched polymer glasses.

Coherent X-ray Scattering from Liquid-Air Interfaces

NASA Astrophysics Data System (ADS)

Shpyrko, Oleg

Advances in synchrotron x-ray scattering techniques allow studies of structure and dynamics of liquid surfaces with unprecedented resolution. I will review x-ray scattering measurements of thermally excited capillary fluctuations in liquids, thin polymer liquid films and polymer surfaces in confined geometry. X-ray Diffuse scattering profile due to Debye-Waller like roughening of the surface allows to probe the distribution of capillary fluctuations over a wide range of length scales, while using X-ray Photon Correlation Spectroscopy (XPCS) one is able to directly couple to nanoscale dynamics of these surface fluctuations, over a wide range of temporal and spacial scales. I will also discuss recent XPCS measurements of lateral diffusion dynamics in Langmuir monolayers assembled at the liquid-air interface. This research was supported by NSF CAREER Grant 0956131.

Temperature dependence of pre-edge features in Ti K-edge XANES spectra for ATiO₃ (A = Ca and Sr), A₂TiO₄ (A = Mg and Fe), TiO₂ rutile and TiO₂ anatase.

PubMed

Hiratoko, Tatsuya; Yoshiasa, Akira; Nakatani, Tomotaka; Okube, Maki; Nakatsuka, Akihiko; Sugiyama, Kazumasa

2013-07-01

XANES (X-ray absorption near-edge structure) spectra of the Ti K-edges of ATiO3 (A = Ca and Sr), A2TiO4 (A = Mg and Fe), TiO2 rutile and TiO2 anatase were measured in the temperature range 20-900 K. Ti atoms for all samples were located in TiO6 octahedral sites. The absorption intensity invariant point (AIIP) was found to be between the pre-edge and post-edge. After the AIIP, amplitudes damped due to Debye-Waller factor effects with temperature. Amplitudes in the pre-edge region increased with temperature normally by thermal vibration. Use of the AIIP peak intensity as a standard point enables a quantitative comparison of the intensity of the pre-edge peaks in various titanium compounds over a wide temperature range.

An Assessment of Spaceborne Near-Nadir Interferometric SAR Performance Over Inland Waters with Real

NASA Astrophysics Data System (ADS)

Tan, H.; Li, S. Y.; Liu, Z. W.

2018-04-01

Elevation measurements of the continental water surface have been poorly collected with in situ measurements or occasionally with conventional altimeters with low accuracy. Techniques using InSAR at near-nadir angles to measure the inland water elevation with large swath and with high accuracy have been proposed, for instance, the WSOA on Jason 2 and the KaRIn on SWOT. However, the WSOA was abandoned unfortunately and the SWOT is planned to be launched in 2021. In this paper, we show real acquisitions of the first spaceborne InSAR of such kind, the Interferometric Imaging Radar Altimeter (InIRA), which has been working on Tiangong II spacecraft since 2016. We used the 90-m SRTM DEM as a reference to estimate the phase offset, and then an empirical calibration model was used to correct the baseline errors.

Persistent discourses in physics education: gender neutrality and the gendering of competence

NASA Astrophysics Data System (ADS)

Gonsalves, Allison

2014-06-01

In her article, Karin Due presents us with a contradiction in physics: the construction of physics as a symbolically masculine discipline alongside a simultaneous discourse of the "gender-neutrality" of the discipline. Due's article makes an important contribution to the study of the gendering of physics practices, particularly in group dynamics, and how this serves to simultaneously reinforce the two competing discourses of physics as a masculine discipline, and the discourse of physics as a gender neutral discipline. Due also suggests that an implication of this contradiction is a limited number of available positions for girls in physics compared to those available to boys. I wish to take up this observation and discuss how available positions for boys and girls in physics are related quite closely to two other concepts discussed in Due's article: competence and recognition.

Site Testing at the Mexican National Astronomical Observatory in San Pedro Martir

NASA Astrophysics Data System (ADS)

Costero, R.; Echevarria, J.; Tapia, M.

1996-05-01

Measurements on the local seeing have been carried out during two and a half yea rs (March 29, 1992 to October 7, 1994), over a total of 378 nights. The Site Tes ting Telescope (STT) from the Steward Observatory yields a median seeing of 0.61 arcsec and a first quartile of 0.50 arcsec. Additional measurements with the Carnegie Monitor (CM), many of them done simultaneously with the STT, yield almost identical results. The Micro--Thermal Array (MTA), also from Steward Observatory, show that the seeing size decreases about 0.1 arcsec at 15 meters above the ground. The seeing does not show any dependence on wind velocity or direction, at least for wind velocities smaller than 40 kilometers per hour. We will present the details of these results. The participation of several persons in this project is here acknowledge, especially that of R. Cromwell and N. Wolf, from Steward Observatory, and S.E. Persson and D.M. Carr, from The Observatories of the Carnegie Institution of Washington.

New insights on the Karoo shale gas potential from borehole KZF-1 (Western Cape, South Africa)

NASA Astrophysics Data System (ADS)

Campbell, Stuart A.; Götz, Annette E.; Montenari, Michael

2016-04-01

A study on world shale reserves conducted by the Energy Information Agency (EIA) in 2013 concluded that there could be as much as 390 Tcf recoverable reserves of shale gas in the southern and south-western parts of the Karoo Basin. This would make it the 8th-largest shale gas resource in the world. However, the true extent and commercial viability is still unknown, due to the lack of exploration drilling and modern 3D seismic. Within the framework of the Karoo Research Initiative (KARIN), two deep boreholes were drilled in the Eastern and Western Cape provinces of South Africa. Here we report on new core material from borehole KZF-1 (Western Cape) which intersected the Permian black shales of the Ecca Group, the Whitehill Formation being the main target formation for future shale gas production. To determine the original source potential for shale gas we investigated the sedimentary environments in which the potential source rocks formed, addressing the research question of how much sedimentary organic matter the shales contained when they originally formed. Palynofacies indicates marginal marine conditions of a stratified basin setting with low marine phytoplankton percentages (acritarchs, prasinophytes), good AOM preservation, high terrestrial input, and a high spores:bisaccates ratio (kerogen type III). Stratigraphically, a deepening-upward trend is observed. Laterally, the basin configuration seems to be much more complex than previously assumed. Furthermore, palynological data confirms the correlation of marine black shales of the Prince Albert and Whitehill formations in the southern and south-western parts of the Karoo Basin with the terrestrial coals of the Vryheid Formation in the north-eastern part of the basin. TOC values (1-6%) classify the Karoo black shales as promising shale gas resources, especially with regard to the high thermal maturity (Ro >3). The recently drilled deep boreholes in the southern and south-western Karoo Basin, the first since the

Prime Contract Awards Alphabetically by Contractor, by State or Country, and Place, FY83, Part 10 (Universal Aircraft Parts Inc-Zytron Corp).

DTIC Science & Technology

1983-01-01

FIELDS & ALI 33-88 B C B 5 2 2 J070 000 A7 MAINT-REPAIR OF EQ/ADP EQUIP 3 6 4 1 1 K OCAO 0029 DAC , 33-88 B C A 5 3 2 W070 000 $1 LEASE-RENTAL OF EQ...D OCW63 0071 DAC 83-C0414 B C Z 5 3 2 S206 000 SI GUARD SERVICES 7 9 3 5 L 06 1 B J 2 D 83-C0450 B C Z 5 3 2 S206 000 Si GUARD SERVICES 7 9 7 5 L 06...C2470 J085 N62’ CONTRACTOR TOTAL 9 1,541 WALLER TODD & SADLI LA JUNTA COLORADO 040309 1520 06 1 C OCA65 0055 DAC 0-82-D4446 E C B 5 3 2 9140 000 A8A

Dynamics of proteins at low temperatures: fibrous vs. globular

NASA Astrophysics Data System (ADS)

Foucat, L.; Renou, J.-P.; Tengroth, C.; Janssen, S.; Middendorf, H. D.

We have measured quasielastic neutron scattering from H2O-hydrated collagen and haemoglobin at T<=270K. The data consist of sets of nearly elastic peaks showing (i) Q,T-dependent decreases in window-integrated intensities Sqe(Q;T) proportional to effective Debye-Waller factors and (ii) small line-shape changes due to various types of proton motions with ns>τ>10 ps. Relative to haemoglobin, the 200-K dynamic transition is shifted upward by 20-25 K in collagen, and the T-dependence of m.-sq. displacements derived from Sqe(Q;T) suggests that in triple-helical systems there are three rather than two regimes: one up to around 120K (probably purely harmonic), an intermediate quasiharmonic region with a linear dependence up to 240K, followed by a steeper nonlinear rise similar to that in globular proteins.

Electron-lattice energy relaxation in laser-excited thin-film Au-insulator heterostructures studied by ultrafast MeV electron diffraction.

PubMed

Sokolowski-Tinten, K; Shen, X; Zheng, Q; Chase, T; Coffee, R; Jerman, M; Li, R K; Ligges, M; Makasyuk, I; Mo, M; Reid, A H; Rethfeld, B; Vecchione, T; Weathersby, S P; Dürr, H A; Wang, X J

2017-09-01

We apply time-resolved MeV electron diffraction to study the electron-lattice energy relaxation in thin film Au-insulator heterostructures. Through precise measurements of the transient Debye-Waller-factor, the mean-square atomic displacement is directly determined, which allows to quantitatively follow the temporal evolution of the lattice temperature after short pulse laser excitation. Data obtained over an extended range of laser fluences reveal an increased relaxation rate when the film thickness is reduced or the Au-film is capped with an additional insulator top-layer. This behavior is attributed to a cross-interfacial coupling of excited electrons in the Au film to phonons in the adjacent insulator layer(s). Analysis of the data using the two-temperature-model taking explicitly into account the additional energy loss at the interface(s) allows to deduce the relative strength of the two relaxation channels.

Neutral Silicon-Vacancy Center in Diamond: Spin Polarization and Lifetimes

NASA Astrophysics Data System (ADS)

Green, B. L.; Mottishaw, S.; Breeze, B. G.; Edmonds, A. M.; D'Haenens-Johansson, U. F. S.; Doherty, M. W.; Williams, S. D.; Twitchen, D. J.; Newton, M. E.

2017-09-01

We demonstrate optical spin polarization of the neutrally charged silicon-vacancy defect in diamond (SiV0 ), an S =1 defect which emits with a zero-phonon line at 946 nm. The spin polarization is found to be most efficient under resonant excitation, but nonzero at below-resonant energies. We measure an ensemble spin coherence time T2>100 μ s at low-temperature, and a spin relaxation limit of T1>25 s . Optical spin-state initialization around 946 nm allows independent initialization of SiV0 and NV- within the same optically addressed volume, and SiV0 emits within the telecoms down-conversion band to 1550 nm: when combined with its high Debye-Waller factor, our initial results suggest that SiV0 is a promising candidate for a long-range quantum communication technology.

AAPB-B - Committee offers revised exchange format for transferring geologic and petroleum data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Waller, H.O.; Guinn, D.; Herkommer, M.

1990-04-01

Comments received since the publication of Exchange Format for Transfer of Geologic and Petroleum Data revealed the need for more flexibility with the AAPG-A Format (Shaw and Waller, 1989). This discussion resulted in the proposed AAPG-B version, which has unlimited number of data fields per record and unlimited number of records. Comment lines can appear anywhere, including in data records, to help document data transfer. Data dictionary hooks have been added. The American Petroleum Institute has assisted by supplying an ANSI envelope for this format, which will permit the electronic transfer with verification of data sets between any two ANSImore » installations. The American Association of Petroleum Geologists Database Standards Subcommittee invites comments on the proposed revisions, and will review the suggestions when it meets June 2 in San Francisco.« less

The influence of social anxiety on the body checking behaviors of female college students.

PubMed

White, Emily K; Warren, Cortney S

2014-09-01

Social anxiety and eating pathology frequently co-occur. However, there is limited research examining the relationship between anxiety and body checking, aside from one study in which social physique anxiety partially mediated the relationship between body checking cognitions and body checking behavior (Haase, Mountford, & Waller, 2007). In an independent sample of 567 college women, we tested the fit of Haase and colleagues' foundational model but did not find evidence of mediation. Thus we tested the fit of an expanded path model that included eating pathology and clinical impairment. In the best-fitting path model (CFI=.991; RMSEA=.083) eating pathology and social physique anxiety positively predicted body checking, and body checking positively predicted clinical impairment. Therefore, women who endorse social physique anxiety may be more likely to engage in body checking behaviors and experience impaired psychosocial functioning. Published by Elsevier Ltd.

A “re-vitalized” Greenwood and Williamson model of elastic contact between fractal surfaces

NASA Astrophysics Data System (ADS)

Ciavarella, M.; Delfine, V.; Demelio, G.

2006-12-01

. Refinements of the original GW theory using the full random process theory (such as that by Bush Gibson and Thomas, BGT) result only in small improvements with a significant additional complication. However, the BGT relationship between contact area and load at low loads is more accurate than the more recent theory by Persson. The distribution derived from the original GW theory has been obtained, and shown to be closer to the numerical results than that predicted by the Persson model, even if the area error is removed. It is concluded that the original GW theory deserves the general success received so far, since the resolution-dependence of geometrical features is an intrinsic feature of "fractals" but not a problem for the GW theory, when interaction effects are included.

Gastro-intestinal nematode infection in lambs — A model based on climatic indices for forecasting peak pasture larval contamination

NASA Astrophysics Data System (ADS)

Paton, G.

1987-06-01

The parasite Ostertagia circumcincta is the primary cause of parasitic gastro-enteritis in lambs during their first season at grass. The life-cycle of this nematode parasite involves the development and survival of the free-living stages on pasture. Accordingly the pasture is the site of deposition, development and transmission of infection and meteorological factors affecting the pasture will affect the parasites. In this paper two empirical models for forecasting the timing of the “summer wave” of infective larvae on pasture are presented. These models are similar in form to that described by Starr and Thomas (1980) but involve different approaches to assessing the temperature and moisture components of the daily index value. Further, using the prediction model described by Paton, Thomas and Waller (1984) as an investigative tool, certain tentative suggestions are made as to a general fundamental weakness of empirical index methods.

Cross-cultural generalizability of personality dimensions: relating indigenous and imported dimensions in two cultures.

PubMed

Katigbak, M S; Church, A T; Akamine, T X

1996-01-01

The cross-cultural generalizability of personality dimensions was investigated by (a) identifying indigenous Philippine dimensions, (b) testing the cross-cultural replicability of the NEO 5-factor model (P. T. Costa & R.R. McCrae, 1992), and (c) relating Philippine and Western dimensions in Philippine and U.S. samples of college students. Filipino self-ratings (N = 536) on indigenous items were factor analyzed, and 6 Philippine dimensions were obtained. Conclusions about the replicability of the 5-factor model in the Philippines (N = 432) depended on whether exploratory, Procrustes, or confirmatory factor methods were used. In regression and joint factor analyses, moderate to strong associations were found between the Philippine dimensions and (a) dimensions from the 5-factor model in both Philippine (N = 387) and U.S. (N = 610) samples, and (b) the Tellegen model (A. Tellegen, 1985; A. Tellegen & N.G. Waller, in press) in a U.S. sample (N = 603).

Electron-lattice energy relaxation in laser-excited thin-film Au-insulator heterostructures studied by ultrafast MeV electron diffraction

PubMed Central

Sokolowski-Tinten, K.; Shen, X.; Zheng, Q.; Chase, T.; Coffee, R.; Jerman, M.; Li, R. K.; Ligges, M.; Makasyuk, I.; Mo, M.; Reid, A. H.; Rethfeld, B.; Vecchione, T.; Weathersby, S. P.; Dürr, H. A.; Wang, X. J.

2017-01-01

We apply time-resolved MeV electron diffraction to study the electron-lattice energy relaxation in thin film Au-insulator heterostructures. Through precise measurements of the transient Debye-Waller-factor, the mean-square atomic displacement is directly determined, which allows to quantitatively follow the temporal evolution of the lattice temperature after short pulse laser excitation. Data obtained over an extended range of laser fluences reveal an increased relaxation rate when the film thickness is reduced or the Au-film is capped with an additional insulator top-layer. This behavior is attributed to a cross-interfacial coupling of excited electrons in the Au film to phonons in the adjacent insulator layer(s). Analysis of the data using the two-temperature-model taking explicitly into account the additional energy loss at the interface(s) allows to deduce the relative strength of the two relaxation channels. PMID:28795080

Hydrologic data for urban studies in the Austin, Texas, metropolitan area, 1979

USGS Publications Warehouse

Slade, R.M.; Dorsey, M.E.; Gordon, J.D.; Mitchell, R.N.; Gaylord, J.L.

1981-01-01

This report contains rainfall and runoff data collected during the 1979 water year for the Austin, Texas, metropolitan area. In 1975, the program was expanded to include the collection of water-quality data. In 1978, the program was expanded to include a groundwater resources study of the south Austin metropolitan area in the Balcones fault zone. The information will be useful in determining the extent to which progressive urbanization will affect the yeild and mode of occurrence of storm runoff. The major streams in the study area are the Colorado River, Onion Creek, Barton Creek, Walnut Creek, Bull Creek, Boggy Creek, Shoal Creek, Williamson Creek, Slaughter Creek, Bear Creek, and Waller Creek. Detailed rainfall-runoff computations are presented for eight storm periods during the 1979 water year. Water-quality data for sites in the Austin metropolitan area are also given in this report. (USGS)

John Martin Wood (1938-2008)--pioneering biochemist, educator and communicator.

PubMed

Tobin, Desmond J; Pittelkow, Mark R; Slominski, Andrzej

2008-07-01

John Martin Wood, Emeritus Professor of Medical Biochemistry at the University of Bradford died in Wieck by Greifswald, Germany after a short illness on February 5, 2008 - just short of his 70(th) year. John worked as a pioneering biochemist and educator in the US and in Britain across two research careers. He devoted the first twenty-five years to the role of transition metals in biology, and his last twenty-years to cutaneous enzymology and melanogenesis. Working together with his wife Professor Karin U. Schallreuter, his research on oxidative stress handling in skin and on the expression of a cutaneous catecholaminergic system will help direct research in these fields for many years to come. John impressed on his fellow cutaneous researchers and students the critical importance of appreciating the true role of enzymes in skin health and disease. This obituary aims to contextualize the significant contributions made by this remarkable man to experimental dermatology.

The Carnegie Supernova Project. I. Third Photometry Data Release of Low-redshift Type Ia Supernovae and Other White Dwarf Explosions

NASA Astrophysics Data System (ADS)

Krisciunas, Kevin; Contreras, Carlos; Burns, Christopher R.; Phillips, M. M.; Stritzinger, Maximilian D.; Morrell, Nidia; Hamuy, Mario; Anais, Jorge; Boldt, Luis; Busta, Luis; Campillay, Abdo; Castellón, Sergio; Folatelli, Gastón; Freedman, Wendy L.; González, Consuelo; Hsiao, Eric Y.; Krzeminski, Wojtek; Persson, Sven Eric; Roth, Miguel; Salgado, Francisco; Serón, Jacqueline; Suntzeff, Nicholas B.; Torres, Simón; Filippenko, Alexei V.; Li, Weidong; Madore, Barry F.; DePoy, D. L.; Marshall, Jennifer L.; Rheault, Jean-Philippe; Villanueva, Steven

2017-11-01

We present final natural-system optical (ugriBV) and near-infrared (YJH) photometry of 134 supernovae (SNe) with probable white dwarf progenitors that were observed in 2004-2009 as part of the first stage of the Carnegie Supernova Project (CSP-I). The sample consists of 123 Type Ia SNe, 5 Type Iax SNe, 2 super-Chandrasekhar SN candidates, 2 Type Ia SNe interacting with circumstellar matter, and 2 SN 2006bt-like events. The redshifts of the objects range from z=0.0037 to 0.0835; the median redshift is 0.0241. For 120 (90%) of these SNe, near-infrared photometry was obtained. Average optical extinction coefficients and color terms are derived and demonstrated to be stable during the five CSP-I observing campaigns. Measurements of the CSP-I near-infrared bandpasses are also described, and near-infrared color terms are estimated through synthetic photometry of stellar atmosphere models. Optical and near-infrared magnitudes of local sequences of tertiary standard stars for each supernova are given, and a new calibration of Y-band magnitudes of the Persson et al. standards in the CSP-I natural system is presented.

Determining the Locations of Brown Dwarfs in Young Star Clusters

NASA Technical Reports Server (NTRS)

Porter, Lauren A.

2005-01-01

Brown dwarfs are stellar objects with masses less than 0.08 times that of the Sun that are unable to sustain nuclear fusion. Because of the lack of fusion, they are relatively cold, allowing the formation of methane and water molecules in their atmospheres. Brown dwarfs can be detected by examining stars' absorption spectra in the near-infrared to see whether methane and water are present. The objective of this research is to determine the locations of brown dwarfs in Rho Ophiuchus, a star cluster that is only 1 million years old. The cluster was observed in four filters in the near-infrared range using the Wide-Field Infra-Red Camera (WIRC) on the 100" DuPont Telescope and Persson's Auxiliary Nasymith Infrared Camera (PANIC) on the 6.5-m Magellan Telescope. By comparing the magnitude of a star in each of the four filters, an absorption spectrum can be formed. This project uses standard astronomical techniques to reduce raw frames into final images and perform photometry on them to obtain publishable data. Once this is done, it will be possible to determine the locations and magnitudes of brown dwarfs within the cluster.

Generalized localization model of relaxation in glass-forming liquids

PubMed Central

Cicerone, Marcus T.; Zhong, Qin; Tyagi, Madhusudan

2012-01-01

Glassy solidification is characterized by two essential phenomena: localization of the solidifying material’s constituent particles and a precipitous increase in its structural relaxation time τ. Determining how these two phenomena relate is key to understanding glass formation. Leporini and coworkers have recently argued that τ universally depends on a localization length-scale (the Debye-Waller factor) in a way that depends only upon the value of at the glass transition. Here we find that this ‘universal’ model does not accurately describe τ in several simulated and experimental glass-forming materials. We develop a new localization model of solidification, building upon the classical Hall-Wolynes and free volume models of glass formation, that accurately relates τ to in all systems considered. This new relationship is based on a consideration of the the anisotropic nature of particle localization. The model also indicates the presence of a particle delocalization transition at high temperatures associated with the onset of glass formation. PMID:23393495

Bond-length relaxation in crystalline Si1-xGex alloys: An extended x-ray-absorption fine-structure study

NASA Astrophysics Data System (ADS)

Kajiyama, Hiroshi; Muramatsu, Shin-Ichi; Shimada, Toshikazu; Nishino, Yoichi

1992-06-01

Extended x-ray-absorption fine-structure spectra for crystalline Si1-xGex alloys, measured at the K edge of Ge at room temperature, are analyzed with a curve-fitting method based on the spherical-wave approximation. The Ge-Ge and Ge-Si bond lengths, coordination numbers of Ge and Si atoms around a Ge atom, and Debye-Waller factors of Ge and Si atoms are obtained. It is shown that Ge-Ge and Ge-Si bonds relax completely, for all Ge concentrations of their study, while the lattice constant varies monotonically, following Vegard's law. As noted by Bragg and later by Pauling and Huggins, the Ge-Ge and Ge-Si bond lengths are close to the sum of their constituent-element atomic radii: nearly 2.45 Å for Ge-Ge bonds and 2.40 Å for Ge-Si bonds. A study on the coordination around a Ge atom in the alloys revealed that Ge and Si atoms mix randomly throughout the compositional range studied.

Commensurability and stability in nonperiodic systems

PubMed Central

Fasano, Y.; De Seta, M.; Menghini, M.; Pastoriza, H.; de la Cruz, F.

2005-01-01

We have investigated the response of 3D Bi2Sr2CaCu2O8 vortex structures to a weak perturbation induced by 2D Fe pinning structures acting on one extremity of vortex lines. The pinning patterns were nano-engineered at the sample surface by means of either a Bitter decoration of the vortex lattice or electron-beam lithography. The commensurability conditions between 2D rigid pinning potentials and 3D elastic structures with short-range positional and long-range orientational correlation have been experimentally determined. When the 2D potential is a replica of the nonperiodic vortex structure an amplification of its interaction with the vortex structure takes place. This effect is detected only for the first matching field, becoming negligible for other matching fields. On the other hand, a periodic 2D perturbation is shown to transform the nonperiodic Bragg glass-like structure into an Abrikosov crystal with an effective Debye–Waller factor. PMID:16576763

Ge K-Edge Extended X-Ray Absorption Fine Structure Study of the Local Structure of Amorphous GeTe and the Crystallization

NASA Astrophysics Data System (ADS)

Maeda, Yoshihito; Wakagi, Masatoshi

1991-01-01

The local structure and crystallization of amorphous GeTe (a-GeTe) were examined by means of Ge K-edge EXAFS. In a-GeTe, both Ge-Ge and Ge-Te bonds were observed to exist in nearest neighbors of Ge. The average coordination number around Ge is 3.7, which is close to the tetrahedral structure. A random covalent network (RCN) model seems to be suitable for the local Structure. After a-GeTe crystallizes at 129°C, the Ge-Ge bond disappears and the Ge-Te bond length increases considerably. As temperature rises, in a-GeTe the Debye-Waller factor of the Ge-Te bond increases greatly, while that of the Ge-Ge bond increases only slightly. At the crystallization, it is found that the fluctuation of the Ge-Te bond length plays a major role in the change of the local structure and bonding state around Ge.

Assessing the feasibility of low temperature XAFS experiments at Indus-2, India: First results

NASA Astrophysics Data System (ADS)

Ramanan, Nitya; Rajput, Parasmani; Jha, S. N.; Lahiri, Debdutta

2015-05-01

In this work, we report installation of displex cryostat XAFS sample holder at XAFS beamline (BL-09) of Indus-2 synchrotron facility, India and make critical assessment of feasibility of low-temperature XAFS experiments in terms of data quality and reproducibility, temperature range, calibration and attainable resolution. We adopted the Debye Model-based calibration method by measuring XAFS of standard Au foil with known Debye temperature (ΘDebye)Autheory = 165 K. The data is of good quality and reproducible with international data. By fitting Debye Waller Factor (σexpt2 (T)), we deduced (ΘDebye)Auexpt = 163 K which implies calibration within 2 K. Error bars for σexpt2 (T) correspond to temperature uncertainty ΔT ≤ 5 K, which defines the temperature resolution for low temperature XAFS experiments. Thus, from both calibration and resolution points-of-view, this work demonstrates the feasibility of low temperature XAFS experiments at BL-09, Indus-2. Feasibility of extending XAFS experiments to lower temperature and unknown samples is discussed.

Doppler broadening of neutron-induced resonances using ab initio phonon spectrum

NASA Astrophysics Data System (ADS)

Noguere, G.; Maldonado, P.; De Saint Jean, C.

2018-05-01

Neutron resonances observed in neutron cross section data can only be compared with their theoretical analogues after a correct broadening of the resonance widths. This broadening is usually carried out by two different theoretical models, namely the Free Gas Model and the Crystal Lattice Model, which, however, are only applicable under certain assumptions. Here, we use neutron transmission experiments on UO2 samples at T=23.7 K and T=293.7 K, to investigate the limitations of these models when an ab initio phonon spectrum is introduced in the calculations. Comparisons of the experimental and theoretical transmissions highlight the underestimation of the energy transferred at low temperature and its impact on the accurate determination of the radiation widths Γ_{γ_{λ}} of the 238U resonances λ. The observed deficiency of the model represents an experimental evidence that the Debye-Waller factor is not correctly calculated at low temperature near the Neel temperature ( TN=30.8 K).

ADENOVIRUS INTERACTION WITH ITS CELLULAR RECEPTOR CAR.

DOE Office of Scientific and Technical Information (OSTI.GOV)

HOWITT,J.; ANDERSON,C.W.; FREIMUTH,P.

The mechanism of adenovirus attachment to the host cell plasma membrane has been revealed in detail by research over the past 10 years. It has long been known that receptor binding activity is associated with the viral fibers, trimeric spike proteins that protrude radially from the vertices of the icosahedral capsid (Philipson et al. 1968). In some adenovirus serotypes, fiber and other virus structural proteins are synthesized in excess and accumulate in the cell nucleus during late stages of infection. Fiber protein can be readily purified from lysates of cells infected with subgroup C viruses, for example Ad2 and Ad5more » (Boulanger and Puvion 1973). Addition of purified fiber protein to virus suspensions during adsorption strongly inhibits infection, indicating that fiber and intact virus particles compete for binding sites on host cells (Philipson et al. 1968; Hautala et al. 1998). Cell binding studies using purified radiolabeled fiber demonstrated that fiber binds specifically and with high affinity to the cell plasma membrane, and that cell lines typically used for laboratory propagation of adenovirus have approximately 10{sup 4} high-affinity receptor sites per cell (Persson et al. 1985; Freimuth 1996). Similar numbers of high-affinity binding sites for radiolabeled intact virus particles also were observed (Seth et al. 1994).« less

HESS Opinions "On forecast (in)consistency in a hydro-meteorological chain: curse or blessing?"

NASA Astrophysics Data System (ADS)

Pappenberger, F.; Cloke, H. L.; Persson, A.; Demeritt, D.

2011-01-01

Flood forecasting increasingly relies on Numerical Weather Prediction (NWP) forecasts to achieve longer lead times (see Cloke et al., 2009; Cloke and Pappenberger, 2009). One of the key difficulties that is emerging in constructing a decision framework for these flood forecasts is when consecutive forecasts are different, leading to different conclusions regarding the issuing of forecasts, and hence inconsistent. In this opinion paper we explore some of the issues surrounding such forecast inconsistency (also known as "jumpiness", "turning points", "continuity" or number of "swings"; Zoster et al., 2009; Mills and Pepper, 1999; Lashley et al., 2008). We begin by defining what forecast inconsistency is; why forecasts might be inconsistent; how we should analyse it; what we should do about it; how we should communicate it and whether it is a totally undesirable property. The property of consistency is increasingly emerging as a hot topic in many forecasting environments (for a limited discussion on NWP inconsistency see Persson, 2011). However, in this opinion paper we restrict the discussion to a hydro-meteorological forecasting chain in which river discharge forecasts are produced using inputs from NWP. In this area of research (in)consistency is receiving recent interest and application (see e.g., Bartholmes et al., 2008; Pappenberger et al., 2011).

Thickness-dependent electron–lattice equilibration in laser-excited thin bismuth films

DOE PAGES

Sokolowski-Tinten, K.; Li, R. K.; Reid, A. H.; ...

2015-11-19

Electron–phonon coupling processes determine electronic transport properties of materials and are responsible for the transfer of electronic excess energy to the lattice. With decreasing device dimensions an understanding of these processes in nanoscale materials is becoming increasingly important. We use time-resolved electron diffraction to directly study energy relaxation in thin bismuth films after optical excitation. Precise measurements of the transient Debye–Waller-effect for various film thicknesses and over an extended range of excitation fluences allow to separate different contributions to the incoherent lattice response. While phonon softening in the electronically excited state is responsible for an immediate increase of the r.m.s.more » atomic displacement within a few hundred fs, 'ordinary' electron–phonon coupling leads to subsequent heating of the material on a few ps time-scale. Moreover, the data reveal distinct changes in the energy transfer dynamics which becomes faster for stronger excitation and smaller film thickness, respectively. The latter effect is attributed to a cross-interfacial coupling of excited electrons to phonons in the substrate.« less

Vibrational density of states and Lindemann melting law

NASA Astrophysics Data System (ADS)

Luo, Sheng-Nian; Strachan, Alejandro; Swift, Damian C.

2005-05-01

We examine the Lindemann melting law at different pressures using the vibrational density of states (DOS), equilibrium melting curve, and Lindemann parameter δL (fractional root-mean-squared displacement, rmsd, at equilibrium melting) calculated independently from molecular dynamics simulations of the Lennard-Jones system. The DOS is obtained using spectra analysis of atomic velocities and accounts for anharmonicity. The increase of δL with pressure is non-negligible: δL is about 0.116 and 0.145 at ambient and extreme pressures, respectively. If the component of rmsd normal to a reflecting plane as in the Debye-Waller-factor-type measurements using x rays is adopted for δL, these values are about 0.067(±0.002) and 0.084(±0.003), and are comparable with experimental and calculated values for face-centered-cubic elements. We find that the Lindemann relation holds accurately at ambient and high pressures. The non-negligible pressure dependence of δL suggests that caution should be exerted in applying the Lindemann law to obtaining the high pressure melting curve anchored at ambient pressure.

Investigation of the spatially isotropic component of the laterally averaged molecular hydrogen/Ag(111) physisorption potential

NASA Astrophysics Data System (ADS)

Yu, Chien-fan; Whaley, K. Birgitta; Hogg, C. S.; Sibener, S. J.

1985-10-01

A comprehensive study of the spatially isotropic component of the laterally averaged molecular hydrogen/Ag(111) physisorption potential is presented. Diffractive selective adsorption scattering resonances for rotationally state-selected H2 and D2 on Ag(111) have been mapped out as a function of incident polar angle for several crystal azimuths and beam energies. These resonances have been used to determine the bound eigenvalues, and subsequently the shape, of the potential well. Best fit Lennard-Jones, Morse, variable exponent, and exponential-3 potentials having well depths of ˜32 meV are derived from the data. These measurements are supported by rotationally inelastic scattering measurements for HD and exact close-coupled quantum scattering calculations. Debye-Waller attenuation measurements are also presented for H2, D2, and HD. The ability to detect these diffractively coupled resonances on a closest-packed metallic surface, i.e., a surface of extremely low corrugation, suggests that such measurements can be carried out on a much wider class of surfaces than previously envisioned.

Investigation of the spatially isotropic component of the laterally averaged molecular hydrogen/Ag(3) physisorption potential

NASA Astrophysics Data System (ADS)

Yu, C. F.; Whaley, K. B.; Hogg, C. S.; Sibener, S. J.

1985-08-01

A comprehensive study of the spatially isotropic component of the laterally averaged molecular hydrogen/Ag(111) physisorption potential is presented. Diffractive selective adsorption scattering resonances for rotationally state-selected H2 and D2 on Ag(111) have been mapped out as a function of incident polar angle for several crystal azimuths and beam energies. These resonances have been used to determine the bound eigenvalues, and subsequently the shape, of the potential well. Best fit Lennard-Jones, Morse, variable exponent, and exponential-3 potentials having well depths of approximately 32 MeV are derived from the data. These measurements are supported by rotationally inelastic scattering measurements for HD and exact close-coupled quantum scattering calculations. Debye-Waller attenuation measurements are also presented for H2, D2, and HD. The ability to detect these diffractively coupled resonances on a closest-packed metallic surface, i.e., a surface of extremely low corrugation, suggests that such measurements can be carried out on a much wider class of surfaces than previously envisioned.

Psychopathic Personality Traits and Environmental Contexts: Differential Correlates, Gender Differences, and Genetic Mediation

PubMed Central

Hicks, Brian M.; Carlson, Marie D.; Blonigen, Daniel M.; Patrick, Christopher J.; Iacono, William G.; MGue, Matt

2011-01-01

Theorists have speculated that primary psychopathy (or Factor 1 affective-interpersonal features) is prominently heritable whereas secondary psychopathy (or Factor 2 social deviance) is more environmentally determined. We tested this differential heritability hypothesis using a large adolescent twin sample. Trait-based proxies of primary and secondary psychopathic tendencies were assessed using Multidimensional Personality Questionnaire (MPQ; Tellegen & Waller, 2008) estimates of Fearless Dominance and Impulsive Antisociality, respectively (Benning et al., 2005). The environmental contexts of family, school, peers, and stressful life events were assessed using multiple raters and methods. Consistent with prior research, MPQ Impulsive Antisociality was robustly associated with each environmental risk factor, and these associations were significantly greater than those for MPQ Fearless Dominance. However, MPQ Fearless Dominance and Impulsive Antisociality exhibited similar heritability, and genetic effects mediated the associations between MPQ Impulsive Antisociality and the environmental measures. Results were largely consistent across male and female twins. We conclude that gene-environment correlations rather than main effects of genes and environments account for the differential environmental correlates of primary and secondary psychopathy. PMID:22452762

Surface Structure of Bi(111) from Helium Atom Scattering Measurements. Inelastic Close-Coupling Formalism

PubMed Central

2015-01-01

Elastic and inelastic close-coupling (CC) calculations have been used to extract information about the corrugation amplitude and the surface vibrational atomic displacement by fitting to several experimental diffraction patterns. To model the three-dimensional interaction between the He atom and the Bi(111) surface under investigation, a corrugated Morse potential has been assumed. Two different types of calculations are used to obtain theoretical diffraction intensities at three surface temperatures along the two symmetry directions. Type one consists of solving the elastic CC (eCC) and attenuating the corresponding diffraction intensities by a global Debye–Waller (DW) factor. The second one, within a unitary theory, is derived from merely solving the inelastic CC (iCC) equations, where no DW factor is necessary to include. While both methods arrive at similar predictions for the peak-to-peak corrugation value, the variance of the value obtained by the iCC method is much better. Furthermore, the more extensive calculation is better suited to model the temperature induced signal asymmetries and renders the inclusion for a second Debye temperature for the diffraction peaks futile. PMID:26257838

Suppressed beta relaxations and reduced heat capacity in ultrastable organic glasses prepared by physical vapor deposition

NASA Astrophysics Data System (ADS)

Ediger, Mark

Glasses play an important role in technology as a result of their macroscopic homogeneity (e.g., the clarity of window glass) and our ability to tune properties through composition changes. A problem with liquid-cooled glasses is that they exhibit marginal kinetic stability and slowly evolve towards lower energy glasses and crystalline states. In contrast, we have shown that physical vapor deposition can prepare glasses with very high kinetic stability. These materials have properties expected for ``million-year-old'' glasses, including high density, low enthalpy, and high mechanical moduli. We have used nanocalorimetry to show that these high stability glasses have lower heat capacities than liquid-cooled glasses for a number of molecular systems. Dielectric relaxation has been used to show that the beta relaxation can be suppressed by nearly a factor of four in vapor-deposited toluene glasses, indicating a very tight packing environment. Consistent with this view, computer simulations of high stability glasses indicate reduced Debye-Waller factors. These high stability materials raise interesting questions about the limiting properties of amorphous packing arrangements.

On the structure of the disordered Bi 2Te 4O 11 phase

NASA Astrophysics Data System (ADS)

Masson, O.; Thomas, P.; Durand, O.; Hansen, T.; Champarnaud, J. C.; Mercurio, D.

2004-06-01

The structure of the disordered metastable Bi 2Te 4O 11 phase has been investigated using both neutron powder diffraction and reverse Monte Carlo (RMC) modelling. The average structure, of fluorite-type (space group Fm 3¯m ), is characterized by very high Debye-Waller parameters, especially for oxygen. Whereas the cations form a fairly well-defined FCC lattice, the oxygen sublattice is very disordered. It is shown that the local order is similar to that present in the stable monoclinic Bi 2Te 4O 11 phase. Clear differences are observed for the intermediate range order. The present phase is analogous to the "anti-glass" phases reported by Trömel in other tellurium-based mixed oxides. However, whereas Trömel defines anti-glass as having long range order but no short range order, it is shown here that this phase is best described as an intermediate state between the amorphous and crystalline states, i.e. having short and medium range order similar to that of tellurite glasses and a premise of long range order with the cations only.

Origin of the magnetic transition at 100 K in ɛ-Fe2O3 nanoparticles studied by x-ray absorption fine structure spectroscopy

NASA Astrophysics Data System (ADS)

López-Sánchez, J.; Muñoz-Noval, A.; Castellano, C.; Serrano, A.; del Campo, A.; Cabero, M.; Varela, M.; Abuín, M.; de la Figuera, J.; Marco, J. F.; Castro, G. R.; Rodríguez de la Fuente, O.; Carmona, N.

2017-12-01

The current study unveils the structural origin of the magnetic transition of the ɛ-Fe2O3 polymorph from an incommensurate magnetic order to a collinear ferrimagnetic state at low temperature. The high crystallinity of the samples and the absence of other iron oxide polymorphs have allowed us to carry out temperature-dependent x-ray absorption fine structure spectroscopy experiments out. The deformation of the structure is followed by the Debye-Waller factor for each selected Fe-O and Fe-Fe sub-shell. For nanoparticle sizes between 7 and 15 nm, the structural distortions between the Fete and Fe-D1oc sites are localized in a temperature range before the magnetic transition starts. On the contrary, the inherent interaction between the other sub-shells (named Fe-O1,2 and Fe-Fe1) provokes cooperative magneto-structural changes in the same temperature range. This means that the Fete with Fe-D1oc polyhedron interaction seems to be uncoupled with temperature dealing with these nanoparticle sizes wherein the structural distortions are likely moderate due to surface effects.

Complete coherent control of silicon vacancies in diamond nanopillars containing single defect centers

DOE PAGES

Zhang, Jingyuan Linda; Lagoudakis, Konstantinos G.; Tzeng, Yan -Kai; ...

2017-10-23

Arrays of identical and individually addressable qubits lay the foundation for the creation of scalable quantum hardware such as quantum processors and repeaters. Silicon-vacancy (SiV) centers in diamond offer excellent physical properties such as low inhomogeneous broadening, fast photon emission, and a large Debye–Waller factor. The possibility for all-optical ultrafast manipulation and techniques to extend the spin coherence times makes them promising candidates for qubits. Here, we have developed arrays of nanopillars containing single (SiV) centers with high yield, and we demonstrate ultrafast all-optical complete coherent control of the excited state population of a single SiV center at the opticalmore » transition frequency. The high quality of the chemical vapor deposition (CVD) grown SiV centers provides excellent spectral stability, which allows us to coherently manipulate and quasi-resonantly read out the excited state population of individual SiV centers on picosecond timescales using ultrafast optical pulses. Furthermore, this work opens new opportunities to create a scalable on-chip diamond platform for quantum information processing and scalable nanophotonics applications.« less

Electrocardiographic intricacies clarified by echocardiography--should the electrocardiogram be interpreted echocardiographically?

PubMed

Ker, James

2012-07-12

During the past century the electrocardiogram (ECG) has established itself as an integral part of the cardiovascular examination. Since the first direct recordings of cardiac potentials by Waller in 1887, to the invention of the string galvanometer by Willem Einthoven in 1901, to use in the clinic by 1910, the electrocardiogram has become the most widely used clinical tool in the diagnosis of virtually every type of heart disease. Currently up to 20 million ECGs are performed annually in the United States alone. However, in this era of readily available echocardiography, an important caveat in the interpretation of the electrocardiogram has emerged: variants of intracardiac structures which might mimic disease on the ECG. In this perspective various structural variants of intracardiac structures, specifically variants of papillary muscles and subaortic muscular bands, will be shown, together with their associated electrocardiographic changes, mimicking disease. It is concluded that in this era of readily available echocardiography, the electrocardiogram should be interpreted echocardiographically in instances where intricate variations are seen on the surface electrocardiogram. Copyright © 2011 Elsevier Ireland Ltd. All rights reserved.

Complete coherent control of silicon vacancies in diamond nanopillars containing single defect centers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Jingyuan Linda; Lagoudakis, Konstantinos G.; Tzeng, Yan -Kai

Arrays of identical and individually addressable qubits lay the foundation for the creation of scalable quantum hardware such as quantum processors and repeaters. Silicon-vacancy (SiV) centers in diamond offer excellent physical properties such as low inhomogeneous broadening, fast photon emission, and a large Debye–Waller factor. The possibility for all-optical ultrafast manipulation and techniques to extend the spin coherence times makes them promising candidates for qubits. Here, we have developed arrays of nanopillars containing single (SiV) centers with high yield, and we demonstrate ultrafast all-optical complete coherent control of the excited state population of a single SiV center at the opticalmore » transition frequency. The high quality of the chemical vapor deposition (CVD) grown SiV centers provides excellent spectral stability, which allows us to coherently manipulate and quasi-resonantly read out the excited state population of individual SiV centers on picosecond timescales using ultrafast optical pulses. Furthermore, this work opens new opportunities to create a scalable on-chip diamond platform for quantum information processing and scalable nanophotonics applications.« less

Delineating the Construct Network of the Personnel Reaction Blank: Associations with Externalizing Tendencies and Normal Personality

PubMed Central

Blonigen, Daniel M.; Patrick, Christopher J.; Gasperi, Marianna; Steffen, Benjamin; Ones, Deniz S.; Arvey, Richard D.; de Oliveira Baumgartl, Viviane; do Nascimento, Elizabeth

2010-01-01

Integrity testing has long been utilized in personnel selection to screen for tendencies toward counterproductive workplace behaviors. The construct of externalizing from the psychopathology literature represents a coherent spectrum marked by disinhibitory traits and behaviors. The present study used a sample of male and female undergraduates to examine the construct network of the Personnel Reaction Blank (PRB; Gough, Arvey, & Bradley, 2004), a measure of integrity, in relation to externalizing as well as normal-range personality constructs assessed by the Multidimensional Personality Questionnaire (MPQ; Tellegen & Waller, 2008). Results revealed moderate to strong associations between several PRB scales and externalizing, which were largely accounted for by MPQ traits subsumed by Negative Emotionality and Constraint. After accounting for MPQ traits in the prediction of externalizing, a modest predictive increment was achieved when adding the PRB scales, particularly biographical indicators from the Prosocial Background subscale. The findings highlight externalizing as a focal criterion for scale development in the integrity testing literature, and help delineate the construct network of the PRB within the domains of personality and psychopathology. PMID:21171783

Water-level altitudes 2001, water-level changes 1977-2001 and 2000-2001, and compaction 1973-2000 in the Chicot and Evangeline aquifers, Houston-Galveston region, Texas

USGS Publications Warehouse

Coplin, L.S.; Houston, Natalie A.; Brown, Dexter W.

2001-01-01

This report is one in an annual series of reports that depicts water-level altitudes and water-level changes since 1977 and compaction since 1973 in the Chicot and Evangeline aquifers in the Houston-Galveston region, Texas. The report, prepared in cooperation with the City of Houston and the Harris-Galveston Coastal Subsidence District, presents maps for the Chicot and Evangeline aquifers showing the approximate water-level altitudes in wells in 2001 (figs 1,4) and approximate water-level changes in wells from 1977 to 2001 and from 2000 to 2001 (figs 2,3,5,6), a map showing extensometer site locations (fig. 7), and graphs showing measured compaction of subserface material at selected sites from 1973 to 2000 (fig. 8). The most recent previously published water-level-altitude maps and water-level-change maps for the two aquifers in the region are by Coplin and Santos. (2000). The Houston-Galveston region comprises Harris and Galveston Counties and adjacent parts of Brazoria, Fort Bend, Waller, Montgomery, Liberty, and Chambers Counties.

KARIN: The Ka-Band Radar Interferometer for the Proposed Surface Water and Ocean Topography (SWOT) Mission

NASA Technical Reports Server (NTRS)

Esteban-Fernandez, Daniel; Peral, Eva; McWatters, Dalia; Pollard, Brian; Rodriguez, Ernesto; Hughes, Richard

2013-01-01

Over the last two decades, several nadir profiling radar altimeters have provided our first global look at the ocean basin-scale circulation and the ocean mesoscale at wavelengths longer than 100 km. Due to sampling limitations, nadir altimetry is unable to resolve the small wavelength ocean mesoscale and sub-mesoscale that are responsible for the vertical mixing of ocean heat and gases and the dissipation of kinetic energy from large to small scales. The proposed Surface Water and Ocean Topography (SWOT) mission would be a partnership between NASA, CNES (Centre National d'Etudes Spaciales) and the Canadian Space Agency, and would have as one of its main goals the measurement of ocean topography with kilometer-scale spatial resolution and centimeter scale accuracy. In this paper, we provide an overview of all ocean error sources that would contribute to the SWOT mission.

Elastic contact mechanics: percolation of the contact area and fluid squeeze-out.

PubMed

Persson, B N J; Prodanov, N; Krick, B A; Rodriguez, N; Mulakaluri, N; Sawyer, W G; Mangiagalli, P

2012-01-01

The dynamics of fluid flow at the interface between elastic solids with rough surfaces depends sensitively on the area of real contact, in particular close to the percolation threshold, where an irregular network of narrow flow channels prevails. In this paper, numerical simulation and experimental results for the contact between elastic solids with isotropic and anisotropic surface roughness are compared with the predictions of a theory based on the Persson contact mechanics theory and the Bruggeman effective medium theory. The theory predictions are in good agreement with the experimental and numerical simulation results and the (small) deviation can be understood as a finite-size effect. The fluid squeeze-out at the interface between elastic solids with randomly rough surfaces is studied. We present results for such high contact pressures that the area of real contact percolates, giving rise to sealed-off domains with pressurized fluid at the interface. The theoretical predictions are compared to experimental data for a simple model system (a rubber block squeezed against a flat glass plate), and for prefilled syringes, where the rubber plunger stopper is lubricated by a high-viscosity silicon oil to ensure functionality of the delivery device. For the latter system we compare the breakloose (or static) friction, as a function of the time of stationary contact, to the theory prediction.

Extremely red objects in the fields of high redshift radio galaxies

NASA Technical Reports Server (NTRS)

Persson, S. E.; Mccarthy, P. J.; Dressler, Alan; Matthews, Keith

1993-01-01

We are engaged in a program of infrared imaging photometry of high redshift radio galaxies. The observations are being done using NICMOS2 and NICMOS3 arrays on the DuPont 100-inch telescope at Las Campanas Observatory. In addition, Persson and Matthews are measuring the spectral energy distributions of normal cluster galaxies in the redshift range 0 to 1. These measurements are being done with a 58 x 62 InSb array on the Palomar 5-m telescope. During the course of these observations we have imaged roughly 20 square arcminutes of sky to limiting magnitudes greater than 20 in the J, H, and K passbands (3 sigma in 3 square arcseconds). We have detected several relatively bright, extremely red, extended objects during the course of this work. Because the radio galaxy program requires Thuan-Gunn gri photometry, we are able to construct rough photometric energy distributions for many of the objects. A sample of the galaxy magnitudes within 4 arcseconds diameter is given. All the detections are real; either the objects show up at several wavelengths, or in subsets of the data. The reddest object in the table, 9ab'B' was found in a field of galaxies in a rich cluster at z = 0.4; 9ab'A' lies 8 arcseconds from it.

Recommended guidelines for uniform reporting of pediatric advanced life support: the pediatric Utstein style.

PubMed

Zaritsky, A; Nadkarni, V; Hazinski, M F; Foltin, G; Quan, L; Wright, J; Fiser, D; Zideman, D; O'Malley, P; Chameides, L

1995-10-01

This statement is the product of a task force meeting held June 8, 1994, in Washington DC in conjunction with the First International Conference on Pediatric Resuscitation and a follow-up task force writing group meeting held September 18, 1994, in Chicago. Draft versions of the statement were circulated for comment to all members of the task force, the American Heart Association Subcommittee on Pediatric Resuscitation, and several outside reviewers. This statement and the International Conference on Pediatric Resuscitation were cosponsored by the American Academy of Pediatrics and the American Heart Association. The development of this statement was authorized by the American Academy of Pediatrics; the American Heart Association National Subcommittees on Pediatric Resuscitation, Basic Life Support, and Advanced Cardiac Life Support, the Committee on Emergency Cardiac Care, the Science Advisory Committee; and the European Resuscitation Council. In addition to the writing group, members of the Pediatric Utstein Task Force are Paul Anderson, M Douglas Baker, Jane Ball, Desmond Bohn, Dena Brownstein, J Michael Dean, Niranjan Kissoon, Bruce Klein, Patrick Malone, Karin McCloskey, James McCrory, P Pearl O'Rourke, Mary Patterson, Charles Schleien, James Seidel, Joseph J Tepas III, and Becky Yano.

Groundwater environmental tracer data collected from the Chicot, Evangeline, and Jasper aquifers in Montgomery County and adjacent counties, Texas, 2008

USGS Publications Warehouse

Oden, Timothy D.

2011-01-01

The Gulf Coast aquifer system is the primary water supply for Montgomery County in southeastern Texas, including part of the Houston metropolitan area and the cities of Magnolia, Conroe, and The Woodlands Township, Texas. The U.S. Geological Survey, in cooperation with the Lone Star Groundwater Conservation District, collected environmental tracer data in the Gulf Coast aquifer system, primarily in Montgomery County. Forty existing groundwater wells screened in the Gulf Coast aquifer system were selected for sampling in Montgomery County (38 wells), Waller County (1 well), and Walker County (1 well). Groundwater-quality samples, physicochemical properties, and water-level data were collected once from each of the 40 wells during March-September 2008. Groundwater-quality samples were analyzed for dissolved gases and the environmental tracers sulfur hexafluoride, chlorofluorocarbons, tritium, helium-4, and helium-3/tritium. Water samples were collected and processed onsite using methods designed to minimize changes to the water-sample chemistry or contamination from the atmosphere. Replicate samples for quality assurance and quality control were collected with each environmental sample. Well-construction information and environmental tracer data for March-September 2008 are presented.

Complete Quantum Control of a Single Silicon-Vacancy Center in a Diamond Nanopillar

NASA Astrophysics Data System (ADS)

Zhang, Jingyuan Linda; Lagoudakis, Konstantinos G.; Tzeng, Yan-Kai; Dory, Constantin; Radulaski, Marina; Kelaita, Yousif; Shen, Zhi-Xun; Melosh, Nicholas A.; Chu, Steven; Vuckovic, Jelena

Coherent quantum control of a quantum bit (qubit) is an important step towards its use in a quantum network. SiV- center in diamond offers excellent physical qualities such as low inhomogeneous broadening, fast photon emission, and a large Debye-Waller factor, while the fast spin manipulation and techniques to extend the spin coherence time are under active investigation. Here, we demonstrate full coherent control over the state of a single SiV- center in a diamond nanopillar using ultrafast optical pulses. The high quality of the chemical vapor deposition grown SiV- centers allows us to coherently manipulate and quasi-resonantly read out the state of the single SiV- center. Moreover, the SiV- centers being coherently controlled are integrated into diamond nanopillar arrays in a site-controlled, individually addressable manner with high yield, low strain, and high spectral stability, which paves the way for scalable on chip optically accessible quantum system in a quantum photonic network. Financial support is provided by the DOE Office of Basic Energy Sciences, Division of Materials Sciences through Stanford Institute for Materials and Energy Sciences (SIMES) under contract DE-AC02-76SF00515.

Diffuse X-ray scattering from benzil, C(14)H(10)O(2): analysis via automatic refinement of a Monte Carlo model.

PubMed

Welberry, T R; Goossens, D J; Edwards, A J; David, W I

2001-01-01

A recently developed method for fitting a Monte Carlo computer-simulation model to observed single-crystal diffuse X-ray scattering has been used to study the diffuse scattering in benzil, diphenylethanedione, C(6)H(5)-CO-CO-C(6)H(5). A model involving 13 parameters consisting of 11 intermolecular force constants, a single intramolecular torsional force constant and a local Debye-Waller factor was refined to give an agreement factor, R = [summation operator omega(Delta I)(2)/summation operator omega I(obs)(2)](1/2), of 14.5% for 101,324 data points. The model was purely thermal in nature. The analysis has shown that the diffuse lines, which feature so prominently in the observed diffraction patterns, are due to strong longitudinal displacement correlations. These are transmitted from molecule to molecule via a network of contacts involving hydrogen bonding of an O atom on one molecule and the para H atom of the phenyl ring of a neighbouring molecule. The analysis also allowed the determination of a torsional force constant for rotations about the single bonds in the molecule. This is the first diffuse scattering study in which measurement of such internal molecular torsion forces has been attempted.

"Your feet's too big": an inquiry into psychological and symbolic meanings of the foot.

PubMed

Zerbe, K J

1985-01-01

The foot is a highly cathected appendage that is commonly singled out as the brunt of humorous or derisive remarks, as if it embodies repugnance and disgust. Attitudes toward the foot are overdetermined, bearing the imprint of man's early linguistic patterns and individual dynamics. This article suggests that feet are symbolic because they bear the feelings derived from earlier separations, good and bad object representations, collective memories, and genital representations. The foot's role as symbol of both the male and female genitals, repository of badness, symbol of passivity, initiator of movement, and site of self-mutilation have been briefly reviewed. As Fats Waller rhapsodizes that the "feet's too big," he finds a convenient way to displace his symbiotic and erotic anxieties vis-à-vis women. Similarly, patients who come for psychiatric treatment and psychotherapy frequently make references to their feet or use them in specific ways. An understanding of this type of communication can often provide insight into individual dynamics and enhance treatment. The weight placed on these communications depends, of course, on the vicissitudes of the previous therapeutic work as well as on the particular problems of the patient.

Experimental evidence for an absorbing phase transition underlying yielding of a soft glass

NASA Astrophysics Data System (ADS)

Nagamanasa, K. Hima; Gokhale, Shreyas; Sood, A. K.; Ganapathy, Rajesh

2014-03-01

A characteristic feature of solids ranging from foams to atomic crystals is the existence of a yield point, which marks the threshold stress beyond which a material undergoes plastic deformation. In hard materials, it is well-known that local yield events occur collectively in the form of intermittent avalanches. The avalanche size distributions exhibit power-law scaling indicating the presence of self-organized criticality. These observations led to predictions of a non-equilibrium phase transition at the yield point. By contrast, for soft solids like gels and dense suspensions, no such predictions exist. In the present work, by combining particle scale imaging with bulk rheology, we provide a direct evidence for a non-equilibrium phase transition governing yielding of an archetypal soft solid - a colloidal glass. The order parameter and the relaxation time exponents revealed that yielding is an absorbing phase transition that belongs to the conserved directed percolation universality class. We also identified a growing length scale associated with clusters of particles with high Debye-Waller factor. Our findings highlight the importance of correlations between local yield events and may well stimulate the development of a unified description of yielding of soft solids.

Force microscopy experiments with ultrasensitive cantilevers.

PubMed

Rast, S; Gysin, U; Ruff, P; Gerber, Ch; Meyer, E; Lee, D W

2006-04-14

Force microscopy experiments with the pendulum geometry are performed with attonewton sensitivity (Rugar et al 2004 Nature 43 329). Single-crystalline cantilevers with sub-millinewton spring constants were annealed under ultrahigh-vacuum conditions. It is found that annealing with temperatures below 500 °C can improve the quality factor by an order of magnitude. The high force sensitivity of these ultrasoft cantilevers is used to characterize small magnetic and superconductive particles, which are mounted on the end of the cantilever. Their magnetic properties are analysed in magnetic fields as a function of temperature. The transition of a superconducting sample mounted on a cantilever is measured by the detection of frequency shifts. An increase of dissipation is observed below the critical temperature. The magnetic moment of ferromagnetic particles is determined by real time frequency detection with a phase-locked loop (PLL) as a function of the magnetic field. The dissipation between the probing tip and the sample is another important ingredient for ultrasensitive force measurements. It is found that dissipation increases at separations of 30 nm. The origins of this type of dissipation are poorly understood. However, it is predicted theoretically that adsorbates can increase this dissipation channel (Volokitin and Persson 2005 Phys. Rev. Lett. 94 086104). First experiments are performed under ultrahigh vacuum to investigate this type of dissipation. Long-range dissipation is closely related to long-range forces. The distance dependence of the contact potential is found to be an important aspect.

WatER: The proposed Water Elevation Recovery satellite mission

NASA Astrophysics Data System (ADS)

Alsdorf, D.; Mognard, N.; Rodriguez, E.; Participants, W.

2005-12-01

Surface fresh water is essential for life, yet we have surprisingly poor knowledge of the spatial and temporal dynamics of surface water storage and discharge globally. The core mission objective is to describe and understand the continental water cycle and the hydrological processes (e.g., floodplain hydraulics) at work in a river basin. The key question that will be answered by WatER is: "Where is water stored on Earth's land surfaces, and how does this storage vary in space and time?" WatER will facilitate societal needs by (1) improving our understanding of flood hazards; (2) freely providing water volume information to countries who critically rely on rivers that cross political borders; and (3) mapping the variations in water bodies that contribute to disease vectors (e.g., malaria). Conventional altimeter profiles are, without question, incapable of supplying the measurements needed to address scientific and societal questions. WatER will repeatedly measure the spatially distributed water surface elevations (h) of wetlands, rivers, lakes, reservoirs, etc. Successive h measurements yield dh/dt, (t is time), hence a volumetric change in water stored or lost. Individual images of h yield dh/dx (x is distance), hence surface water slope, which is necessary for estimating streamflow. WatER's main instrument is a Ka-band radar interferometer (KaRIN) which is the only technology capable of supplying the required imaging capability of h. KaRIN has a rich heritage based on (1) the many highly successful ocean observing radar altimeters, (2) the Shuttle Radar Topography Mission (SRTM), and (3) the development effort of the Wide Swath Ocean Altimeter (WSOA). The interferometric altimeter is a near-nadir viewing, 120 km wideswath based instrument that uses interferometric SAR processing of the returned pulses to yield single-look 5m azimuth and 10m to 70m range resolution, with an elevation accuracy of approximately 50 cm. Polynomial based averaging of heights along the

A high pressure La K-edge X-ray absorption fine structure spectroscopy investigation of La1/3NbO3

NASA Astrophysics Data System (ADS)

Marini, C.; Joseph, B.; Noked, O.; Shuker, R.; Kennedy, B. J.; Mathon, O.; Pascarelli, S.; Sterer, E.

2018-01-01

La K-edge X-ray absorption spectroscopy has been used to elucidate the changes in the local electronic and lattice structure that occur in the A-site deficient double perovskite La?NbO? up to 6 GPa. The pressure evolution of the oxygen dodecahedrum around the A-site has been examined. XANES (X-ray absorption near edge structure) data show modifications ascribed to the increase of bands overlapping as a consequence of the bond distance contraction, which has been directly probed by EXAFS (extended x-ray absorption fine structure) spectra. The La-O Debye Waller factors (DWFs) tend to increase whereas the La-Nb bond DWFs show only a tendency to decrease indicating the robustness of the crystal lattice structure, even in presence of the oxygen disordering. This permits the system to reverse back to its original conditions in this pressure range as evident from the measurements upon pressure release. The present results have been interpreted in the light of charge transfer related to the two-step reduction mechanism acting at the Nb site (with niobium ions passing from Nb? to Nb?) which also results in the elongation of the Nb-O bond distances in the octahedra, in agreement with the Nb K-edge results reported earlier.

Diffraction Studies of the Atomic Vibrations of Bulk and Surface Atoms in the Reciprocal and Real Spaces of Nanocrystalline SiC

NASA Technical Reports Server (NTRS)

Stelmakh, S.; Grzanka, E.; Weber, H.-P.; Vogel, S.; Palosz, B.; Palosz, B.

2004-01-01

To describe and evaluate the vibrational properties of nanoparticles it is necessary to distinguish between the surface and the core of the particles. Theoretical calculations show that vibrational density of states of the inner atoms of nanograins is similar to bulk material but shifted to higher energies which can be explained by the fact that the gain core is stressed (hardened) due to the presence of internal pressure. Theoretical calculations also show that there is a difference between vibrational properties of a crystal lattice of the grain interior in isolated particles and in a dense (sintered) nanocrystalline material. This is probably due to a coupling of the modes inside the grains via the grain boundaries in dense nanocrystalline bodies. We examined strains present in the surface shell based on examination of diamond and Sic nanocrystals in reciprocal (Bragg-type scattering) and real (PDF analysis) space analysis of neutron diffraction data. Recently we examined the atomic thermal motions in nanocrystalline Sic based on the assumption of a simple Einstein model for uncorrelated atomic notions. According to this model, the Bragg intensity is attenuated as a function of scattering angle by the Debye-Waller factor. Based on this assumption overall temperature factors were determined from the Wilson plots.

Modeling the interactions of phthalocyanines in water: from the Cu(II)-tetrasulphonate to the metal-free phthalocyanine.

PubMed

Martín, Elisa I; Martínez, Jose M; Sánchez Marcos, Enrique

2011-01-14

A quantum and statistical study on the effects of the ions Cu(2+) and SO(3)(-) in the solvent structure around the metal-free phthalocyanine (H(2)Pc) is presented. We developed an ab initio interaction potential for the system CuPc-H(2)O based on quantum chemical calculations and studied its transferability to the H(2)Pc-H(2)O and [CuPc(SO(3))(4)](4-)-H(2)O interactions. The use of the molecular dynamics technique allows the determination of energetic and structural properties of CuPc, H(2)Pc, and [CuPc(SO(3))(4)](4-) in water and the understanding of the keys for the different behaviors of the three phthalocyanine (Pc) derivatives in water. The inclusion of the Cu(2+) cation in the Pc structure reinforces the appearance of two axial water molecules and second-shell water molecules in the solvent structure, whereas the presence of SO(3)(-) anions implies a well defined hydration shell of about eight water molecules around them making the macrocycle soluble in water. Debye-Waller factors for axial water molecules have been obtained in order to examine the potential sensitivity of the extended x-ray absorption fine structure technique to detect the axial water molecules.

The ultraviolet imaging telescope: Instrument and data characteristics

NASA Astrophysics Data System (ADS)

Stecher, Theodore P.; Ultraviolet Imaging Telescope Team

1997-05-01

The Ultraviolet Imaging Telescope (UIT) was flown as part of the Astro Observatory on the Space Shuttle Columbia in December 1990 (see Figure 1) and again on the Space Shuttle Endeavour in March 1995. Ultraviolet (1200-3300 Å) images of a wide variety of astronomical objects were detected with UV image intensifiers and recorded on photographic film. Typical angular resolutions were 2-3 arcsec over a 40 arcmin field of view. The reduced and calibrated images from the first flight are available to the astronomical community through the National Space Science Data Center (NSSDC); the data recorded during the second flight will soon be available as well. UIT's design, operation, data reduction, and calibration are described in detail in Stecher et al. (1997), including a comprehensive description of the data characteristics. This publication provides UIT data users with information for understanding and using the data, as well as guidelines for analyzing other astronomical imagery made with image intensifiers and photographic film. Further information on the Astro missions and the UIT science program is available at the following website http://fondue.gsfc.nasa.gov/UIT/UIT_HomePage.html and in an educational slideset that is available from the Astronomical Society of the Pacific (Waller & Offenberg 1994).

EXAFS Study of Halato-Telechelic Polymers End-Capped With Group IVb Metal Carboxylates at Room and Low Temperatures

NASA Astrophysics Data System (ADS)

Vlaic, G.; Navarra, G.; Regnard, J.-R.; Williams, C. E.; Jérôme, R.

1995-05-01

The EXAFS analysis at 300, 70 and 5 K has shown that the thermal disorder is very low in a carboxylato telechelic polybutadiene neutralized with an increasing excess of Zr isopropoxide. Two types of Zr-O bonds in the first shell account for the experimental data. The Zr-O distances and number of oxygen neighbours in the two subshells are found to be independent of temperature in the investigated range. The proportion of Zr in the samples has no effect on the total number of oxygen atoms around Zr, in contrast to their relative distribution in the two subshells. The number of Zr atoms increases in the second shell with the total amount of this metal. Upon increasing degree of neutralization from 200 to 600%, the static disorder increases together with a strong reduction of the dynamic part of the Debye-Waller (DW) factor. At a high degree of neutralization (> 400%), the DW factor for the Zr-Zr bond is largely independent of temperature. These observations agree with formation of Zr polynuclear microdomains, the size and rigidity of which increase with the Zr content, in good agreement with the profound changes previously reported in the viscoelastic properties of these materials.

Thermal vibrations and polymorphic β → γ transition in cerium

NASA Astrophysics Data System (ADS)

Agafonov, S. S.; Blanter, M. S.; Glazkov, V. P.; Somenkov, V. A.; Shushunov, M. N.

2010-10-01

Method of neutron diffraction was used to determine the temperature dependence of the Debye-Waller factor and the related thermal atomic displacements for two polymorphic modifications of cerium, namely, for β-Ce with a double hexagonal closed-packed (dhcp) structure and for γ-Ce with a face-centered cubic (fcc) structure. It has been shown that the phase transition does not lead to substantial changes in the root-mean-square thermal atomic displacements and that the Debye temperatures of the two modifications are close: 131 K for β-Ce and 127 K for γ-Ce. However, the relative (with respect to the lattice parameters) displacements along the axes change considerably. The transition from the anisotropic hexagonal to the isotropic cubic modification leads, because of a redistribution of thermal atomic displacements along the crystallographic axes, to a decrease in the maximum values of these quantities and to a weakening of their temperature dependence. It has also been shown that a change in the thermal atomic vibrations and in the vibrational contribution to the entropy of the polymorphic transformations is connected with the sign of the volume effect of the transformation (stronger upon a positive effect and weaker, upon a negative one). The reasons for this behavior are discussed.

Bayes-Turchin analysis of x-ray absorption data above the Fe L{sub 2,3}-edges

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rossner, H. H.; Schmitz, D.; Imperia, P.

2006-10-01

Extended x-ray absorption fine structure (EXAFS) data and magnetic EXAFS (MEXAFS) data were measured at two temperatures (180 and 296 K) in the energy region of the overlapping L-edges of bcc Fe grown on a V(110) crystal surface. In combination with a Bayes-Turchin data analysis procedure these measurements enable the exploration of local crystallographic and magnetic structures. The analysis determined the atomic-like background together with the EXAFS parameters which consisted of ten shell radii, the Debye-Waller parameters, separated into structural and vibrational components, and the third cumulant of the first scattering path. The vibrational components for 97 different scattering pathsmore » were determined by a two parameter force-field model using a priori values adjusted to Born-von Karman parameters of inelastic neutron scattering data. The investigations of the system Fe/V(110) demonstrate that the simultaneous fitting of atomic background parameters and EXAFS parameters can be performed reliably. Using the L{sub 2}- and L{sub 3}-components extracted from the EXAFS analysis and the rigid-band model, the MEXAFS oscillations can only be described when the sign of the exchange energy is changed compared to the predictions of the Hedin Lundquist exchange and correlation functional.« less

New Techniques for Radar Altimetry of Sea Ice and the Polar Oceans

NASA Astrophysics Data System (ADS)

Armitage, T. W. K.; Kwok, R.; Egido, A.; Smith, W. H. F.; Cullen, R.

2017-12-01

Satellite radar altimetry has proven to be a valuable tool for remote sensing of the polar oceans, with techniques for estimating sea ice thickness and sea surface height in the ice-covered ocean advancing to the point of becoming routine, if not operational, products. Here, we explore new techniques in radar altimetry of the polar oceans and the sea ice cover. First, we present results from fully-focused SAR (FFSAR) altimetry; by accounting for the phase evolution of scatterers in the scene, the FFSAR technique applies an inter-burst coherent integration, potentially over the entire duration that a scatterer remains in the altimeter footprint, which can narrow the effective along track resolution to just 0.5m. We discuss the improvement of using interleaved operation over burst-more operation for applying FFSAR processing to data acquired by future missions, such as a potential CryoSat follow-on. Second, we present simulated sea ice retrievals from the Ka-band Radar Interferometer (KaRIn), the instrument that will be launched on the Surface Water and Ocean Topography (SWOT) mission in 2021, that is capable of producing swath images of surface elevation. These techniques offer the opportunity to advance our understanding of the physics of the ice-covered oceans, plus new insight into how we interpret more conventional radar altimetry data in these regions.

Discharge estimation in ungauged basins through variational data assimilation : The potential of the SWOT mission.

NASA Astrophysics Data System (ADS)

Oubanas, H.; Gejadze, I.; Malaterre, P. O.; Durand, M. T.; Wei, R.; Frasson, R. P. M.; Domeneghetti, A.

2017-12-01

This work investigates the estimation of river discharge from simulated observations of the forthcoming Surface Water and Ocean Topography (SWOT) mission, to be launched in 2021, using a variant of the standard variational data assimilation method `4D-Var'. The hydrology SWOT simulator, developed at the Jet Propulsion Laboratory (JPL) has been used to simulate the expected performance of the KaRIn instrument onboard the satellite, producing synthetic SWOT observations of height and width, at each satellite overpass. SWOT data products were synthesized at the spatial scale of 200 m along the river centerline. Using a 1.5D full Saint-Venant hydraulic model, variational data assimilation simultaneously estimates the inflow discharge, river bathymetry and bed roughness. The proposed method has been designed for an application to fully ungauged basins; therefore, the prior information is derived from the SWOT observations only and the globally available ancillary information. Two reaches of the Po and Sacramento Rivers of about 130 km and 150 km, respectively, have been considered in this study. Discharge was successfully recovered at the overpass time with a relative-root-mean-square error of 16% and 12.3% for the Po and Sacramento Rivers, respectively. The estimates of the bed level and the roughness coefficient demonstrate a local improvement; however they may not provide reliable global information of the river bathymetry and roughness.

Using Sentinel-2A multispectral imagery to explore for deep groundwater resources in the Ceres-Tankwa Karoo, Western Cape, South Africa: Significance for the 'water-energy(-food) nexus' in an arid region

NASA Astrophysics Data System (ADS)

Hartnady, Chris; Wise, Edward; Hartnady, Michael; Olianti, Camille; Hay, E. Rowena

2017-04-01

warming and increasing water scarcity in semi-arid regions, deep artesian groundwater systems provide a long-term solution to future demands for water, food and power. In contrast to shale-gas development, which competes for the scarce water resource and poses a substantial pollution threat, an alternative, synergistic and conjunctive development of solar energy, specifically Concentrating Solar Power plants facilitated by the deep artesian groundwater resource, is envisaged for the Ceres-Tankwa and other parts of the Southern Karoo, in a proposed "Sores-Kamma (Sun-Water) Initiative". In this effort, Sentinel-2A-based lithological mapping is integrated with a new digital elevation model, providing geomorphometry and morphotectonic interpretations, and with the systematic monitoring of surface- and groundwater fluxes using a conjunction of radar satellite, Global Navigation Satellite Systems and microgravity approaches. Reference De Kock, M.O., Beukes, N.J., Götz, A.E., Cole, D., Birch, A., Withers, A. and Van Niekerk, H.S. 2016. Open file progress report on exploration of the southern Karoo Basin through CIMERA-KARIN borehole KZF-1 in the Tankwa Karoo, Witzenberg (Ceres) District. 12 pp. Available online at http://www.cimera.co.za/index.php/karin-feedback

To deliver or not to deliver cognitive behavioral therapy for eating disorders: Replication and extension of our understanding of why therapists fail to do what they should do.

PubMed

Mulkens, Sandra; de Vos, Chloé; de Graaff, Anastacia; Waller, Glenn

2018-07-01

This study investigated the extent to which therapists fail to apply empirically supported treatments in a sample of clinicians in The Netherlands, delivering cognitive behavioral therapy for eating disorders (CBT-ED). It aimed to replicate previous findings, and to extend them by examining other potential intra-individual factors associated with the level of (non-)use of core CBT-ED techniques. Participants were 139 clinicians (127 women; mean age 41.4 years, range = 24-64) who completed an online survey about the level of use of specific techniques, their beliefs (e.g., about the importance of the alliance and use of pretreatment motivational techniques), anxiety (Intolerance of Uncertainty Scale), and personality (Ten Item Personality Inventory). Despite some differences with Waller's (2012) findings, the present results continue to indicate that therapists are not reliably delivering the CBT-ED techniques that would be expected to provide the best treatment to their patients. This 'non-delivery' appears to be related to clinician anxiety, temporal factors, and clinicians' beliefs about the power of the therapeutic alliance in driving therapy outcomes. Improving treatment delivery will involve working with clinicians' levels of anxiety, clarifying the lack of benefit of pre-therapy motivational enhancement work, and reminding clinicians that the therapeutic alliance is enhanced by behavioral change in CBT-ED, rather than the other way around. Copyright © 2018 Elsevier Ltd. All rights reserved.

Bond length variation in Zn substituted NiO studied from extended X-ray absorption fine structure

NASA Astrophysics Data System (ADS)

Singh, S. D.; Poswal, A. K.; Kamal, C.; Rajput, Parasmani; Chakrabarti, Aparna; Jha, S. N.; Ganguli, Tapas

2017-06-01

Bond length behavior for Zn substituted NiO is determined through extended x-ray absorption fine structure (EXAFS) measurements performed at ambient conditions. We report bond length value of 2.11±0.01 Å for Zn-O of rock salt (RS) symmetry, when Zn is doped in RS NiO. Bond length for Zn substituted NiO RS ternary solid solutions shows relaxed behavior for Zn-O bond, while it shows un-relaxed behavior for Ni-O bond. These observations are further supported by first-principles calculations. It is also inferred that Zn sublattice remains nearly unchanged with increase in lattice parameter. On the other hand, Ni sublattice dilates for Zn compositions up to 20% to accommodate increase in the lattice parameter. However, for Zn compositions more than 20%, it does not further dilate. It has been attributed to the large disorder that is incorporated in the system at and beyond 20% of Zn incorporation in the cubic RS lattice of ternary solid solutions. For these large percentages of Zn incorporation, the Ni and the Zn atoms re-arrange themselves microscopically about the same nominal bond length rather than systematically increase in magnitude to minimize the energy of the system. This results in an increase in the Debye-Waller factor with increase in the Zn concentration rather than a systematic increase in the bond lengths.

Disorder in Protein Crystals.

NASA Astrophysics Data System (ADS)

Clarage, James Braun, II

1990-01-01

Methods have been developed for analyzing the diffuse x-ray scattering in the halos about a crystal's Bragg reflections as a means of determining correlations in atomic displacements in protein crystals. The diffuse intensity distribution for rhombohedral insulin, tetragonal lysozyme, and triclinic lysozyme crystals was best simulated in terms of exponential displacement correlation functions. About 90% of the disorder can be accounted for by internal movements correlated with a decay distance of about 6A; the remaining 10% corresponds to intermolecular movements that decay in a distance the order of size of the protein molecule. The results demonstrate that protein crystals fit into neither the Einstein nor the Debye paradigms for thermally fluctuating crystalline solids. Unlike the Einstein model, there are correlations in the atomic displacements, but these correlations decay more steeply with distance than predicted by the Debye-Waller model for an elastic solid. The observed displacement correlations are liquid -like in the sense that they decay exponentially with the distance between atoms, just as positional correlations in a liquid. This liquid-like disorder is similar to the disorder observed in 2-D crystals of polystyrene latex spheres, and similar systems where repulsive interactions dominate; hence, these colloidal crystals appear to provide a better analogy for the dynamics of protein crystals than perfectly elastic lattices.

Quantitative x-ray diffraction analysis of bimodal damage distributions in Tm implanted Al0.15Ga0.85N

NASA Astrophysics Data System (ADS)

Magalhães, S.; Fialho, M.; Peres, M.; Lorenz, K.; Alves, E.

2016-04-01

In this work radial symmetric x-ray diffraction scans of Al0.15Ga0.85N thin films implanted with Tm ions were measured to determine the lattice deformation and crystal quality as functions of depth. The alloys were implanted with 300 keV Tm with 10° off-set to the sample normal to avoid channelling, with fluences varying between 1013 Tm cm-2 and 5  ×  1015 Tm cm-2. Simulations of the radial 2θ-ω scans were performed under the frame of the dynamical theory of x-ray diffraction assuming Gaussian distributions of the lattice strain induced by implantation defects. The structure factor of the individual layers is multiplied by a static Debye-Waller factor in order to take into account the effect of lattice disorder due to implantation. For higher fluences two asymmetric Gaussians are required to describe well the experimental diffractograms, although a single asymmetric Gaussian profile for the deformation is found in the sample implanted with 1013 Tm cm-2. After thermal treatment at 1200 °C, the crystal quality partially recovers as seen in a reduction of the amplitude of the deformation maximum as well as the total thickness of the deformed layer. Furthermore, no evidence of changes with respect to the virgin crystal mosaicity is found after implantation and annealing.

Water-level changes 1977-87, 1987-95, and 1995-2000 in the Chicot and Evangeline Aquifers, Houston-Galveston region, Texas

USGS Publications Warehouse

Kasmarek, Mark C.; Lanning-Rush, Jennifer

2002-01-01

This report depicts long-term water-level changes in the Chicot and Evangeline aquifers in the Houston-Galveston region. The Houston-Galveston region comprises Harris, Galveston, Fort Bend, Waller, and Montgomery Counties and adjacent parts of Brazoria, Grimes, Walker, San Jacinto, Liberty, and Chambers Counties. The report was prepared in cooperation with the Harris-Galveston Coastal Subsidence District and the Fort Bend Subsidence District. For the Chicot and Evangeline aquifers, maps show approximate water-level changes for the periods 1977 to 1987 (figs. 1 and 4), 1987 to 1995 (figs. 2 and 5), and 1995 to 2000 (figs. 3 and 6). Nineteen seventy-seven was the first year that water levels in a network of wells were measured and water-levelaltitude maps made for the Chicot and Evangeline aquifers. Nineteen eighty-seven, 1995, and 2000 were years in which land-surface altitudes throughout Harris, Galveston, and Fort Bend Counties were releveled using spirit leveling (1987) and Global Positioning Satellite technology (1995 and 2000); thus the selection of those years for the maps. The U.S. Geological Survey (USGS) has published annual reports of water-level altitudes and water-level changes for the Chicot and Evangeline aquifers in the Houston-Galveston region since 1979 and separate similar annual reports for the Fort Bend subregion since 1990. Beginning with 2002, the separate annual reports were combined into one report.

Retrospective reports of parenting received in their families of origin: relationships to adult attachment in adult children of alcoholics.

PubMed

Kelley, Michelle L; Nair, Veena; Rawlings, Tanaya; Cash, Thomas F; Steer, Kate; Fals-Stewart, William

2005-09-01

The present study examined general and romantic attachment and parenting students received in their families of origin among 401 college students who resided with an alcohol-abusing parent prior to age 16 years as compared to those who did not reside with alcohol-abusing parents. Participants completed the Children's Report of Parent Behavior Instrument [Schludermann, E. and Schludermann, S. (1970). Children's Report of Parent Behavior Inventory (CRPBI). Canada: University of Manitoba], Experiences in Close Relationships--Revised [Fraley, R. C., Waller, N. G., and Brennan, K. G. (2000). An item response theory analysis of self-report measures of adult attachment. Journal of Personality and Social Psychology, 78, 350-365], Relationship Scale Questionnaire [Griffin, D. W. and Bartholomew, K. (1994). Models of the self and other: Fundamental dimensions underlying measures of adult attachment. Journal of Personality and Social Psychology, 67, 430-445], and the Children of Alcoholics Screening Test [Jones, J. W. (1983). The Children of Alcoholics Screening Test: Test manual. Chicago: Camelot]. Young adults who met criteria for ACOAs reported more anxious and avoidant behavior in romantic relationships and a more fearful style of general adult attachment. Parenting behavior in one's family of origin predicted anxious behavior in romantic relationships and a fearful overall style of attachment, whereas being an ACOA and parenting in one's family of origin predicted avoidant behavior in romantic relationships.

X-ray absorption investigation of local structural disorder in Ni 1-xFe x (x=0.10, 0.20, 0.35, and 0.50) alloys

DOE PAGES

Zhang, Fuxiang X.; Jin, Ke; Zhao, Shijun; ...

2017-04-27

Defect energetics in structural materials has long been recognized to be affected by specific alloy compositions. Significantly enhanced radiation resistance has recently been observed in concentrated solid-solution alloys. However, the link between local structural disorder and modified defect dynamics in solid solutions remains unclear. To reveal the atomic-level lattice distortion, the local structures of Ni and Fe in Ni 1-xFe x (x=0.1, 0.2, 0.35 and 0.5) solid solution alloys were measured with extended X-ray absorption fine structure (EXAFS) technique. The lattice constant and the first-neighbor distances increase with the increase of Fe content in the solid solutions. EXAFS measurements havemore » revealed that the bond length of Fe with surrounding atoms is 0.01-0.03 larger than that of Ni in the alloy systems. Debye-Waller factor of the Fe-Fe bonds in all the systems is also slightly larger than that of the Ni-Ni bond. EXAFS fitting suggests that the local structural disorder is enhanced with the addition of Fe elements in the solid solution. The local bonding environments from ab initio calculation are in good agreement with the experimental results, which suggest that the Fe has a larger first-neighbor bonding distance than that of Ni, and thus Ni atom inside the Ni-Fe solid solution alloys undergoes compressive strain.« less

X-ray absorption investigation of local structural disorder in Ni 1-xFe x (x=0.10, 0.20, 0.35, and 0.50) alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Fuxiang X.; Jin, Ke; Zhao, Shijun

Defect energetics in structural materials has long been recognized to be affected by specific alloy compositions. Significantly enhanced radiation resistance has recently been observed in concentrated solid-solution alloys. However, the link between local structural disorder and modified defect dynamics in solid solutions remains unclear. To reveal the atomic-level lattice distortion, the local structures of Ni and Fe in Ni 1-xFe x (x=0.1, 0.2, 0.35 and 0.5) solid solution alloys were measured with extended X-ray absorption fine structure (EXAFS) technique. The lattice constant and the first-neighbor distances increase with the increase of Fe content in the solid solutions. EXAFS measurements havemore » revealed that the bond length of Fe with surrounding atoms is 0.01-0.03 larger than that of Ni in the alloy systems. Debye-Waller factor of the Fe-Fe bonds in all the systems is also slightly larger than that of the Ni-Ni bond. EXAFS fitting suggests that the local structural disorder is enhanced with the addition of Fe elements in the solid solution. The local bonding environments from ab initio calculation are in good agreement with the experimental results, which suggest that the Fe has a larger first-neighbor bonding distance than that of Ni, and thus Ni atom inside the Ni-Fe solid solution alloys undergoes compressive strain.« less

Calpains mediate axonal cytoskeleton disintegration during Wallerian degeneration

PubMed Central

Ma, Marek; Ferguson, Toby A.; Schoch, Kathleen M.; Li, Jian; Qian, Yaping; Shofer, Frances S.; Saatman, Kathryn E.; Neumar, Robert W.

2013-01-01

In both the central nervous system (CNS) and peripheral nervous system (PNS), transected axons undergo Wallerian degeneration. Even though Augustus Waller first described this process after transection of axons in 1850, the molecular mechanisms may be shared, at least in part, by many human diseases. Early pathology includes failure of synaptic transmission, target denervation, and granular disintegration of the axonal cytoskeleton (GDC). The Ca2+-dependent proteases calpains have been implicated in GDC but causality has not been established. To test the hypothesis that calpains play a causal role in axonal and synaptic degeneration in vivo, we studied transgenic mice that express human calpastatin (hCAST), the endogenous calpain inhibitor, in optic and sciatic nerve axons. Five days after optic nerve transection and 48 hours after sciatic nerve transection, robust neurofilament proteolysis observed in wild-type controls was reduced in hCAST transgenic mice. Protection of the axonal cytoskeleton in sciatic nerves of hCAST mice was nearly complete 48 hours post-transection. In addition, hCAST expression preserved the morphological integrity of neuromuscular junctions. However, compound muscle action potential amplitudes after nerve transection were similar in wild-type and hCAST mice. These results, in total, provide direct evidence that calpains are responsible for the morphological degeneration of the axon and synapse during Wallerian degeneration. PMID:23542511

210Pb dating

USGS Publications Warehouse

Swarzenski, Peter W.

2014-01-01

Roughly fifty years ago, a small group of scientists from Belgium and the United States, trying to better constrain ice sheet accumulation rates, attempted to apply what was then know about environmental lead as a potential geochronometer. Thus Goldberg (1963) developed the first principles of the 210Pb dating method, which was soon followed by a paper by Crozaz et al. (1964), who examined accumulation history of Antarctic snow using 210Pb. Shortly thereafter, Koide et al. (1972, 1973) adapted this technique to unravel sediment deposition and accumulation records in deep-sea environments. Serendipitously, they chose to work in a deep basin off California, where an independent and robust age model had already been developed. Krishanswami et al. (1971) extended the use of this technique to lacustrine deposits to reconstruct depositional histories of lake sediment, and maybe more importantly, contaminant inputs and burial. Thus, the powerful tool for dating recent (up to about one century old) sediment deposits was established and soon widely adopted. Today almost all oceanographic or limnologic studies that address recent depositional reconstructions employ 210Pb as one of several possible geochronometers (Andrews et al., 2009; Gale, 2009; Baskaran, 2011; Persson and Helms, 2011). This paper presents a short overview of the principles of 210Pb dating and provides a few examples that illustrate the utility of this tracer in contrasting depositional systems. Potential caveats and uncertainties (Appleby et al., 1986; Binford, 1990; Binford et al., 1993; Smith, 2001; Hancock et al., 2002) inherent to the use and interpretation of 210Pb-derived age-models are also introduced. Recommendations as to best practices for most reliable uses and reporting are presented in the summary.

[On the first studies of electrophysiology].

PubMed

de Micheli, Alfredo

2011-01-01

A historical outline of the evolution of electrophysiology from the eighteenth century is shortly presented. Topics concerning the so called animal electricity starting from the observations on descharges of Torpedo fish until Bolognese Galvani's researches on the frogs are exposed. The points of view of their oppositionists also are examined. These ones, leaded by the physicist Alessandro Volta, professor in the University of Pavia, believed that electricity detected by galvanists was not inherent to animal but was due to the action of the metallic conductors present in the circuit: contact electricity. Only towards the middle of the nineteenth century the physicist Carlo Matteucci attained to demonstrate the existente of the real animal electricity in form of injury current. It was possible to determine that quantitatively thanks to the capillary electrometer built in 1872 by the French physicist Gabriel Lippmann. This instrument was used by the English physiologist Waller in order to obtain the primitive electrocardiographic tracings in humans (1887). At beginnings of the twentieth century, the Dutch professor Willem Einthoven, of the University of Leiden, introduced his string galvanometer which permitted to allow the modern electrocardiography. So it was possible to record the electrical potentials of myocardial cells, first in vitro, later in isolated and perfused heart, son after in dog's heart in situ and finally in human heart. Therefore now it is possible to effectuate endocardial and epicardial mappings, indispensable in order to diagnose and treat the cardiac arrhythmias.

Electronic structures of WAlO(y) and WAlO(y)(-) (y = 2-4) determined by anion photoelectron spectroscopy and density functional theory calculations.

PubMed

Mann, Jennifer E; Waller, Sarah E; Jarrold, Caroline Chick

2012-07-28

The anion photoelectron spectra of WAlO(y)(-) (y = 2-4) are presented and assigned based on results of density functional theory calculations. The WAlO(2)(-) and WAlO(3)(-) spectra are both broad, with partially resolved vibrational structure. In contrast, the WAlO(4)(-) spectrum features well-resolved vibrational structure with contributions from three modes. There is reasonable agreement between experiment and theory for all oxides, and calculations are in particular validated by the near perfect agreement between the WAlO(4)(-) photoelectron spectrum and a Franck-Condon simulation based on computationally determined spectroscopic parameters. The structures determined from this study suggest strong preferential W-O bond formation, and ionic bonding between Al(+) and WO(y)(-2) for all anions. Neutral species are similarly ionic, with WAlO(2) and WAlO(3) having electronic structure that suggests Al(+) ionically bound to WO(y)(-) and WAlO(4) being described as Al(+2) ionically bound to WO(4)(-2). The doubly-occupied 3sp hybrid orbital localized on the Al center is energetically situated between the bonding O-local molecular orbitals and the anti- or non-bonding W-local molecular orbitals. The structures determined in this study are very similar to structures recently determined for the analogous MoAlO(y)(-)/MoAlO(y) cluster series, with subtle differences found in the electronic structures [S. E. Waller, J. E. Mann, E. Hossain, M. Troyer, and C. C. Jarrold, J. Chem. Phys. 137, 024302 (2012)].

Search for Functional Flexible Regions in the G-protein Family: New Reading of the FoldUnfold Program.

PubMed

Galzitskaya, Oxana; Deryusheva, Eugenia; Machulin, Andrey; Nemashkalova, Ekaterina; Glyakina, Anna

2018-06-21

High prediction accuracy of flexible loops in different protein families is a challenge because of the crucial functions associated with these regions. Results of the currently available programs for prediction of loops vary from protein to protein. For prediction of flexible regions in the G-domain for 23 representatives of G-proteins with the known 3D structure we have used eight programs. The results of predictions demonstrate that the FoldUnfold program predicts better loop positions than the PONDR, RОNN, DisEMBL, IUPred, GlobPlot 2, FoldIndex, and MobiDB programs. When classifying the predicted loops (rigid/flexible) according to the Debye-Waller fluctuation factors, our data reveal the existing weak correlation between the B-factors and the average number of closed residues according to the FoldUnfold program; the percentage of overlapping characteristics (residue fold/unfold status) of the protein residues from the two methods is about 60-70%. According to the FoldUnfold program, for G-proteins with the posttranslational modifications, the surrounding binding site residues by disordered-promoting glycine and alanine residues conduces to a more flexible position of the binding sites for fatty acid, while methionine, cysteine and isoleucine residues provide more rigid binding sites. Thus, our research demonstrates additional possibilities of the FoldUnfold program for prediction of flexible regions and characteristics of individual residues in a different protein family. Copyright© Bentham Science Publishers; For any queries, please email at epub@benthamscience.org.

Low clouds in central California

NASA Image and Video Library

2015-02-10

Low clouds filled California’s Central Valley in late January, 2015. Such winter fog is considered a common phenomenon, and can be so dense that it snarls traffic, causes fender-benders, and can make symptoms worse in those with respiratory disease. At the same time, the moist winter fog helps keep temperatures low in the rich agricultural region by reflecting sunlight and keeping the ground from warming, which helps keep the abundant fruit and nut trees dormant, allowing for bountiful harvests. Scientific studies have reported that winter fogs (also called Thule fogs) are occurring less frequently in the Central Valley. One study, by Dennis Baldocchi and Eric Waller, was published in May, 2014. It finds that since 1981 the number of fog days between November and February has decreased by 46 percent. The severe drought that California has experienced in recent years may also have decreased the number of fog events even more since 2012. The Moderate Resolution Imaging Spectroradiometer (MODIS) aboard NASA’s Terra satellite captured this true-color image on January 24, 2015. Credit: NASA/GSFC/Jeff Schmaltz/MODIS Land Rapid Response Team NASA image use policy. NASA Goddard Space Flight Center enables NASA’s mission through four scientific endeavors: Earth Science, Heliophysics, Solar System Exploration, and Astrophysics. Goddard plays a leading role in NASA’s accomplishments by contributing compelling scientific knowledge to advance the Agency’s mission. Follow us on Twitter Like us on Facebook Find us on Instagram

Local environments and transport properties of heavily doped strontium barium niobates Sr0.5Ba0.5Nb2O6

NASA Astrophysics Data System (ADS)

Ottini, Riccardo; Tealdi, Cristina; Tomasi, Corrado; Tredici, Ilenia G.; Soffientini, Alessandro; Burriel, Ramón; Palacios, Elías; Castro, Miguel; Anselmi-Tamburini, Umberto; Ghigna, Paolo; Spinolo, Giorgio

2018-02-01

Undoped as well as K-doped (40%), Y-doped (40%), Zr-doped (10%), and Mo-doped (12.5%) strontium barium niobate Sr0.5Ba0.5Nb2O6 (SBN50) materials have been investigated to explore the effect of heavy doping on the structural and functional properties (thermo-power, thermal and electrical conductivities) both in the as prepared (oxidized) and reduced states. For all materials, the EXAFS spectra at the Nb - K edge can be consistently analyzed with the same model of six shells around the Nb sites. Doping mostly gives a simple size effect on the structural parameters, but doping on the Nb sites weakens the Nb-O bond regardless of dopant size and charge. Shell sizes and Debye-Waller factors are almost unaffected by temperature and oxidation state, and the disorder is of static nature. The functional effects of heavy doping do not agree with a simple model of hole or electron injection by aliovalent substitutions on a large band gap semiconductor. With respect to the undoped samples, doping with Mo depresses the thermal conductivity by 30%, Y doping enhances the electrical conductivity by an order of magnitude, while Zr doping increases the Seebeck coefficient by a factor of 2-3. Globally, the ZT efficiency factor of the K-, Y-, and Zr-doped samples is enhanced at least by one order of magnitude with respect to the undoped or Mo-doped materials.

High Resolution Far Infrared Fourier Transform Spectroscopy of the NH_2 Radical.

NASA Astrophysics Data System (ADS)

Martin-Drumel, M. A.; Pirali, O.; Balcon, D.; Vervloet, M.

2011-06-01

First identified toward Sgr B2, the NH_2 radical has recently been detected in the interstellar medium by the HIFI instrument on board of Herschel. Despite the fact that this radical has not been detected in brown dwarfs and exoplanets yet, it is already included in physical and chemical models of those environments (temperature higher than 2000 K expected in several objects). Its detection in those objects will depend on the existence of a reliable high temperature and high resolution spectroscopic database on the NH_2 radical.The absorption spectrum of NH_2 has been recorded between 15 and 700 Cm-1 at the highest resolution available using the Bruker IFS125HR Fourier transform interferometer connected to the far infrared AILES beamline at SOLEIL (R=0.001 Cm-1). The radical was produced by an electrical discharge (DC) through a continuous flow of NH_3 and He using the White-type discharge cell developped on the beamline (optical path: 24m). Thanks to the brilliance of the synchrotron radiation, more than 700 pure rotational transitions of NH_2 have been identified with high N values (NMax=25) in its fundamental and first excited vibrational modes. By comparison to the previous FT spectroscopic study on that radical in the FIR spectral range, asymmetric splitting as well as fine and hyperfine structure have been resolved for several transitions. E. F. Van Dishoeck, D. J. Jansen, P. Schilke, T. G. Phillips The Astrophysical Journal 416, L83-L86 (1993) C. M. Persson, J. H. Black, J. Cernicharo et al. Astronomy and Astrophysics 521, L45 (2010) K. Lodders and B. Fegley, Jr Icarus 155, 393-424 (2002) I. Morino and K. Kawaguchi Journal of Molecular Spectroscopy 182, 428-438 (1997)

2012 Aspen Winter Conference New Paradigms for Low-Dimensional Electronic Materials, February 5-10, 2012

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moore, Joel; Rabe, Karin; Nayak, Chetan

2012-05-01

Aspen Center for Physics Project Summary DOE Budget Period: 10/1/2011 to 9/30/2012 Contract # DE-SC0007479 New Paradigms for Low-Dimensional Electronic Materials The 2012 Aspen Winter Conference on Condensed Matter Physics was held at the Aspen Center for Physics from February 5 to 10, 2012. Seventy-four participants from seven countries, and several universities and national labs attended the workshop titled, New Paradigms for Low-Dimensional Electronic Materials. There were 34 formal talks, and a number of informal discussions held during the week. Talks covered a variety of topics related to DOE BES priorities, including, for example, advanced photon techniques (Hasan, Abbamonte, Orenstein,more » Shen, Ghosh) and predictive theoretical modeling of materials properties (Rappe, Pickett, Balents, Zhang, Vanderbilt); the full conference schedule is provided with this report. The week's events included a public lecture (Quantum Matters given by Chetan Nayak from Microsoft Research) and attended by 234 members of the public, and a physics caf© geared for high schoolers that is a discussion with physicists conducted by Kathryn Moler (Stanford University) and Andrew M. Rappe (University of Pennsylvania) and attended by 67 locals and visitors. While there were no published proceedings, some of the talks are posted online and can be Googled. The workshop was organized by Joel Moore (University of California Berkeley), Chetan Nayak (Microsoft Research), Karin Rabe (Rutgers University), and Matthias Troyer (ETH Zurich). Two organizers who did not attend the conference were Gabriel Aeppli (University College London & London Centre for Nanotechnology) and Andrea Cavalleri (Oxford University & Max Planck Hamburg).« less

Magnetic and structural properties of nanoparticles of nickel oxide

NASA Astrophysics Data System (ADS)

Shim, Hyunja (Jenny)

In this dissertation, magnetic properties of NiO nanoparticles (NP) prepared by the sol-gel method in the size range D = 5 nm to 20 nm, with and without oleic acid (OA) coating, are reported. Transmission electron microscopy (TEM) studies show the morphology of the smaller particles to be primarily rod-like, changing over to nearly spherical shapes for D >10 nm. Average sizes D of NP determined by x-ray diffraction (XRD) are compared with the results from TEM. From the analysis of the XRD line intensities, the particle size dependence of the Debye-Waller factors for Ni and O atoms are derived. It is found that the Debye-Waller factors of nickel and oxygen atoms in smaller particles are larger than those in bulk NiO. For the coated and uncoated NiO nanorods of 5 nm diameter, variations of the magnetization M with temperature T (5 K to 370 K) and temperature variations of the EMR (electron magnetic resonance) spectra were measured to determine the respective blocking temperatures TB(m) and TB(EMR). The following differences are noted: (1) TB(m) is reduced from 230 K (uncoated) to 85 K(coated) for H = 25 Oe; (2) Decrease of TB(m) with H is weaker and the ratio TB(EMR)/T B(m) is smaller for the uncoated particles. These differences are due to stronger interparticle interaction present in the uncoated particles. Temperature variation (5 K-300 K) of the AC magnetic susceptibilities (chi' and chi") at various frequencies f (0.1-10,000 Hz) are reported for the coated and uncoated 5 nm diameter nanorods of NiO. Using the peak in chi' as the blocking temperature TB, it is observed that TB increases with increasing f. The data for the two samples fit the Vogel-Fulcher law: f = f0exp[-Ea/k(TB-T0)] with f 0 = 9.2 x 1011 Hz, Ea/k = 1085 K and T0 = 162 K (0 K) for the uncoated (coated) particles. This shows that T0 provides a good measure of the effects of interparticle interactions on magnetic relaxation and that these interactions are essentially eliminated with the OA coating

Multiscale virtual particle based elastic network model (MVP-ENM) for normal mode analysis of large-sized biomolecules.

PubMed

Xia, Kelin

2017-12-20

In this paper, a multiscale virtual particle based elastic network model (MVP-ENM) is proposed for the normal mode analysis of large-sized biomolecules. The multiscale virtual particle (MVP) model is proposed for the discretization of biomolecular density data. With this model, large-sized biomolecular structures can be coarse-grained into virtual particles such that a balance between model accuracy and computational cost can be achieved. An elastic network is constructed by assuming "connections" between virtual particles. The connection is described by a special harmonic potential function, which considers the influence from both the mass distributions and distance relations of the virtual particles. Two independent models, i.e., the multiscale virtual particle based Gaussian network model (MVP-GNM) and the multiscale virtual particle based anisotropic network model (MVP-ANM), are proposed. It has been found that in the Debye-Waller factor (B-factor) prediction, the results from our MVP-GNM with a high resolution are as good as the ones from GNM. Even with low resolutions, our MVP-GNM can still capture the global behavior of the B-factor very well with mismatches predominantly from the regions with large B-factor values. Further, it has been demonstrated that the low-frequency eigenmodes from our MVP-ANM are highly consistent with the ones from ANM even with very low resolutions and a coarse grid. Finally, the great advantage of MVP-ANM model for large-sized biomolecules has been demonstrated by using two poliovirus virus structures. The paper ends with a conclusion.

Structural evolution and atomic dynamics in Ni-Nb metallic glasses: A molecular dynamics study

NASA Astrophysics Data System (ADS)

Xu, T. D.; Wang, X. D.; Zhang, H.; Cao, Q. P.; Zhang, D. X.; Jiang, J. Z.

2017-10-01

The composition and temperature dependence of static and dynamic structures in NixNb1-x (x = 50-70 at. %) were systematically studied using molecular dynamics with a new-released semi-empirical embedded atom method potential by Mendelev. The calculated pair correlation functions and the structure factor match well with the experimental data, demonstrating the reliability of the potential within relatively wide composition and temperature ranges. The local atomic structures were then characterized by bond angle distributions and Voronoi tessellation methods, demonstrating that the icosahedral ⟨0,0,12,0⟩ is only a small fraction in the liquid state but increases significantly during cooling and becomes dominant at 300 K. The most abundant clusters are identified as ⟨0,0,12,0⟩ and distorted icosahedron ⟨0,2,8,2⟩. The large fraction of these two clusters hints that the relatively good glass forming ability is near the eutectic point. Unlike Cu-Zr alloys, both the self-diffusion coefficient and shear viscosity are insensitive to compositions upon cooling in Ni-Nb alloys. The breakdown of the Stokes-Einstein relation happens at around 1.6Tg (Tg: glass transition temperature). In the amorphous state, the solid and liquid-like atoms can be distinguished based on the Debye-Waller factor ⟨u2⟩. The insensitivity of the dynamic properties of Ni-Nb alloys to compositions may result from the relatively simple solidification process in the phase diagram, in which only one eutectic point exists in the studied composition range.

Structures and phase transitions of the A7PSe6 (A = Ag, Cu) argyrodite-type ionic conductors. II. Beta- and gamma-Cu7PSe6

PubMed

Gaudin; Boucher; Petricek; Taulelle; Evain

2000-06-01

The crystal structures of two of the three polymorphic forms of the Cu7PSe6 argyrodite compound are determined by means of single-crystal X-ray diffraction. In the high-temperature form, at 353 K, i.e. 33 K above the first phase transition, gamma-Cu7PSe6 crystallizes in cubic symmetry, space group F43m. The full-matrix least-squares refinement of the structure leads to the residual factors R = 0.0201 and wR = 0.0245 for 31 parameters and 300 observed independent reflections. In the intermediate form, at room temperature, beta-Cu7PSe6 crystallizes again in cubic symmetry, but with space group P2(1)3. Taking into account a merohedric twinning, the refinement of the beta-Cu7PSe6 structure leads to the residual factors R = 0.0297 and wR = 0.0317 for 70 parameters and 874 observed, independent reflections. The combination of a Gram-Charlier development of the Debye-Waller factor and a split model for copper cations reveals the possible diffusion paths of the d10 species in the gamma-Cu7PSe6 ionic conducting phase. The partial ordering of the Cu+ d10 element at the phase transition is found in concordance with the highest probability density sites of the high-temperature phase diffusion paths. A comparison between the two Cu7PSe6 and Ag7PSe6 analogues is carried out, stressing the different mobility of Cu+ and Ag+ and their relative stability in low-coordination chalcogenide environments.

Real-time sub-Ångstrom imaging of reversible and irreversible conformations in rhodium catalysts and graphene

NASA Astrophysics Data System (ADS)

Kisielowski, Christian; Wang, Lin-Wang; Specht, Petra; Calderon, Hector A.; Barton, Bastian; Jiang, Bin; Kang, Joo H.; Cieslinski, Robert

2013-07-01

The dynamic responses of a rhodium catalyst and a graphene sheet are investigated upon random excitation with 80 kV electrons. An extraordinary electron microscope stability and resolution allow studying temporary atom displacements from their equilibrium lattice sites into metastable sites across projected distances as short as 60 pm. In the rhodium catalyst, directed and reversible atom displacements emerge from excitations into metastable interstitial sites and surface states that can be explained by single atom trajectories. Calculated energy barriers of 0.13 eV and 1.05 eV allow capturing single atom trapping events at video rates that are stabilized by the Rh [110] surface corrugation. Molecular dynamics simulations reveal that randomly delivered electrons can also reversibly enhance the sp3 and the sp1 characters of the sp2-bonded carbon atoms in graphene. The underlying collective atom motion can dynamically stabilize characteristic atom displacements that are unpredictable by single atom trajectories. We detect three specific displacements and use two of them to propose a path for the irreversible phase transformation of a graphene nanoribbon into carbene. Collectively stabilized atom displacements greatly exceed the thermal vibration amplitudes described by Debye-Waller factors and their measured dose rate dependence is attributed to tunable phonon contributions to the internal energy of the systems. Our experiments suggest operating electron microscopes with beam currents as small as zepto-amperes/nm2 in a weak-excitation approach to improve on sample integrity and allow for time-resolved studies of conformational object changes that probe for functional behavior of catalytic surfaces or molecules.

Emergence: A Planetarium and Art Gallery Collaboration Between Artist, Astronomer, and Musician

NASA Astrophysics Data System (ADS)

Beaver, J.; Waller, J. B.; Turner, M.

2011-09-01

We describe an unusual planetarium program and art gallery exhibition that premiered in Menasha, Wisconsin. Emergence combines fine art and improvisational music with astronomy and physics. The authors, Judith Baker Waller, John Beaver, and Matt Turner, are, respectively, artist, astronomer, and musician. All three acted as partners in planning and executing the final production. The overall goal of Emergence is to use art, music, and natural science each as a point of departure to learn about the others, and to explore the interaction between humans and the natural world and the differences and commonalities between art, science, and music. Of particular interest, the planetarium portion includes techniques that are, so far as we know, unique. Each night the show is different, the details chosen randomly, but always according to the same theoretical scheme. Various elements are parameterized, the show varying with time according to subroutines that dictate the overall pacing and look, but with details always chosen randomly according to prearranged probabilities. We believe that some of these techniques could be of interest to others who wish to explore the unique possibilities of the planetarium as educational performance space. We argue that this provides a useful format for collaborations between artist and scientist, as scientific content can be delivered in a way that is consistent with the concerns of the artist. We describe some of the approaches taken toward these ends in Emergence, and some of the lessons learned about the process of collaboration between a scientist, a visual artist and a performing artist.

Mode localization in the cooperative dynamics of protein recognition

NASA Astrophysics Data System (ADS)

Copperman, J.; Guenza, M. G.

2016-07-01

The biological function of proteins is encoded in their structure and expressed through the mediation of their dynamics. This paper presents a study on the correlation between local fluctuations, binding, and biological function for two sample proteins, starting from the Langevin Equation for Protein Dynamics (LE4PD). The LE4PD is a microscopic and residue-specific coarse-grained approach to protein dynamics, which starts from the static structural ensemble of a protein and predicts the dynamics analytically. It has been shown to be accurate in its prediction of NMR relaxation experiments and Debye-Waller factors. The LE4PD is solved in a set of diffusive modes which span a vast range of time scales of the protein dynamics, and provides a detailed picture of the mode-dependent localization of the fluctuation as a function of the primary structure of the protein. To investigate the dynamics of protein complexes, the theory is implemented here to treat the coarse-grained dynamics of interacting macromolecules. As an example, calculations of the dynamics of monomeric and dimerized HIV protease and the free Insulin Growth Factor II Receptor (IGF2R) domain 11 and its IGF2R:IGF2 complex are presented. Either simulation-derived or experimentally measured NMR conformers are used as input structural ensembles to the theory. The picture that emerges suggests a dynamical heterogeneous protein where biologically active regions provide energetically comparable conformational states that are trapped by a reacting partner in agreement with the conformation-selection mechanism of binding.

Temperature determination of resonantly excited plasmonic branched gold nanoparticles by X-ray absorption spectroscopy.

PubMed

Van de Broek, Bieke; Grandjean, Didier; Trekker, Jesse; Ye, Jian; Verstreken, Kris; Maes, Guido; Borghs, Gustaaf; Nikitenko, Sergey; Lagae, Liesbet; Bartic, Carmen; Temst, Kristiaan; Van Bael, Margriet J

2011-09-05

The fields of bioscience and nanomedicine demand precise thermometry for nanoparticle heat characterization down to the nanoscale regime. Since current methods often use indirect and less accurate techniques to determine the nanoparticle temperature, there is a pressing need for a direct and reliable element-specific method. In-situ extended X-ray absorption fine structure (EXAFS) spectroscopy is used to determine the thermo-optical properties of plasmonic branched gold nanoparticles upon resonant laser illumination. With EXAFS, the direct determination of the nanoparticle temperature increase upon laser illumination is possible via the thermal influence on the gold lattice parameters. More specifically, using the change of the Debye-Waller term representing the lattice disorder, the temperature increase is selectively measured within the plasmonic branched nanoparticles upon resonant laser illumination. In addition, the signal intensity shows that the nanoparticle concentration in the beam more than doubles during laser illumination, thereby demonstrating that photothermal heating is a dynamic process. A comparable temperature increase is measured in the nanoparticle suspension using a thermocouple. This good correspondence between the temperature at the level of the nanoparticle and at the level of the suspension points to an efficient heat transfer between the nanoparticle and the surrounding medium, thus confirming the potential of branched gold nanoparticles for hyperthermia applications. This work demonstrates that X-ray absorption spectroscopy-based nanothermometry could be a valuable tool in the fast-growing number of applications of plasmonic nanoparticles, particularly in life sciences and medicine. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Local structure study of (In{sub 0.95−x}Fe{sub x}Cu{sub 0.05}){sub 2}O{sub 3} thin films using x-ray absorption spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ren, Yuan; Xing, Yaya; Ma, Guanxiong

2015-07-15

The (In{sub 0.95−x}Fe{sub x}Cu{sub 0.05}){sub 2}O{sub 3} (x = 0.06, 0.08, 0.15, and 0.20) films prepared by RF-magnetron sputtering were investigated by the combination of x-ray absorption spectroscopy (XAS) at Fe, Cu, and O K-edge. Although the Fe and O K-edge XAS spectra show that the Fe atoms substitute for the In sites of In{sub 2}O{sub 3} lattice for all the films, the Cu K-edge XAS spectra reveal that the codoped Cu atoms are separated to form the Cu metal clusters. After being annealed in air, the Fe atoms are still substitutionally incorporated into the In{sub 2}O{sub 3} lattice, while the Cumore » atoms form the CuO secondary phases. With the increase of Fe concentration, the bond length R{sub Fe-O} shortens and the Debye–Waller factor σ{sup 2}{sub Fe-O} increases in the first coordination shell of Fe, which are attributed to the relaxation of oxygen environment around the substitutional Fe ions. The forming of Cu relating secondary phases in the films is due to high ionization energy of Cu atoms, leading that the Cu atoms are energetically much harder to be oxidized to substitute for the In sites of In{sub 2}O{sub 3} lattice than Fe atoms. These results provide new experimental guidance in the preparation of the codoped In{sub 2}O{sub 3} based dilute magnetic oxides.« less

The mediating role of anger in the relationship between PTSD symptoms and impulsivity.

PubMed

Contractor, Ateka A; Armour, Cherie; Wang, Xin; Forbes, David; Elhai, Jon D

2015-03-01

Research indicates a significant relationship between posttraumatic stress disorder (PTSD) and anger (Olatunji, Ciesielski, & Tolin, 2010; Orth & Wieland, 2006). Individuals may seek urgent coping to deal with the distress of anger, which is a mobilizing and action-oriented emotion (Novaco & Chemtob, 2002); possibly in the form of impulsive actions consistent with impulsivity's association with anger (Milligan & Waller, 2001; Whiteside & Lynam, 2001). This could be 1 of the explanations for the relationship between PTSD and impulsivity (Kotler, Julian, Efront, & Amir, 2001; Ledgerwood & Petry, 2006). The present study assessed the mediating role of anger between PTSD (overall scores and subscales of arousal and negative alterations in mood/cognitions) and impulsivity, using gender as a covariate of impulsivity. The PTSD Checklist for Diagnostic and Statistical Manual of Mental Disorders, fifth edition (DSM-5), Dimensions of Anger Reaction scale-5, and the UPPS Impulsivity Scale were administered to a sample of 244 undergraduate students with a trauma history. Results based on 1000 bootstrapped samples indicated significant direct effects of PTSD (overall and 2 subscales) on anger, of anger on impulsivity, and of PTSD (overall and 2 subscales) on impulsivity. Further, anger significantly mediated the relationship between PTSD (overall and 2 subscales) and impulsivity, consistent with the hypothesized models. Results suggest that impulsivity aims at coping with distressing anger, possibly explaining the presence of substance usage, and other impulsive behaviors in people with PTSD. Further, anger probably serves as a mobilizing and action-oriented emotion coupled with PTSD symptoms. (PsycINFO Database Record (c) 2015 APA, all rights reserved).

Bayes-Turchin Analysis of Overlapping L-Edges EXAFS Data of Iron

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rossner, H. H.; Schmitz, D.; Imperia, P.

2007-02-02

Spin polarized and spin averaged extended x-ray absorption fine structure ((M)EXAFS) data were measured at temperatures of 180 K and 296 K in the soft x-ray energy regime of the overlapping L-edges of an iron film grown on V(110). The absorption coefficients were analyzed with the Bayes-Turchin procedure. The analysis yields the correction function to the atomic-like background-absorption coefficient calculated by FEFF8 and reveals components of atomic EXAFS oscillations. The EXAFS Debye-Waller (DW) parameters were determined. Their split into a thermal and a structural contribution was not possible without theoretical input since the two temperatures in this experiment were notmore » sufficiently far apart from each other and the k range of the data was too small. The a priori values of the thermal contribution to the DW parameters were therefore derived from a force-field model with two spring constants. They were adjusted to DW parameters calculated from Born-von Karman force constants which had been obtained from inelastic neutron scattering. Those two spring constants also nicely reproduce the unprojected vibrational density of states deduced from phonon dispersion curves. The MEXAFS oscillations can be described by the rigid-band model and the L2- and L3-EXAFS components. A negative exchange-related energy is obtained by fitting the MEXAFS signal in the extended energy region. This is in contrast to the predictions of the Hedin-Lundquist functional and the Dirac-Hara functional used in the FEFF8 code.« less

Well-ordered science and Indian epistemic cultures: toward a polycentered history of science.

PubMed

Ganeri, Jonardon

2013-06-01

This essay defends the view that "modern science," as with modernity in general, is a polycentered phenomenon, something that appears in different forms at different times and places. It begins with two ideas about the nature of rational scientific inquiry: Karin Knorr Cetina's idea of "epistemic cultures," and Philip Kitcher's idea of science as "a system of public knowledge," such knowledge as would be deemed worthwhile by an ideal conversation among the whole public under conditions of mutual engagement. This account of the nature of scientific practice provides us with a new perspective from which to understand key elements in the philosophical project of Jaina logicians in the seventh, eighth, and ninth centuries C.E. Jaina theory seems exceptionally well targeted onto two of the key constituents in the ideal conversation--the classification of all human points of view and the representation of end states of the deliberative process. The Buddhist theory of the Kathāvatthu contributes to Indian epistemic culture in a different way: by supplying a detailed theory of how human dialogical standpoints can be revised in the ideal conversation, an account of the phenomenon Kitcher labels "tutoring." Thus science in India has its own history, one that should be studied in comparison and contrast with the history of science in Europe. In answer to Joseph Needham, it was not 'modern science' which failed to develop in India or China but rather non-well-ordered science, science as unconstrained by social value and democratic consent. What I argue is that this is not a deficit in the civilisational histories of these countries, but a virtue.

The Effects of the Gaelic Athletic Association 15 Training Program on Neuromuscular Outcomes in Gaelic Football and Hurling Players: A Randomized Cluster Trial.

PubMed

OʼMalley, Edwenia; Murphy, John C; McCarthy Persson, Ulrik; Gissane, Conor; Blake, Catherine

2017-08-01

O'Malley, E, Murphy, JC, McCarthy Persson, U, Gissane, C, and Blake, C. The effects of the Gaelic Athletic Association 15 training program on neuromuscular outcomes in Gaelic football and hurling players: A randomized cluster trial. J Strength Cond Res 31(8): 2119-2130, 2017-Team-based neuromuscular training programs for injury prevention have been tested primarily in female and adolescent athletes in soccer, handball, and basketball with limited research in adult male field sports. This study explored whether the GAA 15, a multifaceted 8-week neuromuscular training program developed by the Gaelic Athletic Association (GAA), could improve risk factors for lower limb injury in male Gaelic footballers and hurlers. Four Gaelic sports collegiate teams were randomized into intervention or control groups. Two teams (n = 41), one football and one hurling, were allocated to the intervention, undertaking a 15 minutes program of neuromuscular training exercises at the start of team training sessions, twice weekly for 8 weeks. Two matched teams (n = 37) acted as controls, participating in usual team training. Lower extremity stability (Y-Balance test [YBT]) and jump-landing technique using the Landing Error Scoring System (LESS) were assessed preintervention and postintervention. There were moderate effect sizes in favor of the intervention for right (d = 0.59) and left (d = 0.69) composite YBT scores, with adjusted mean differences between intervention and control of 3.85 ± 0.91% and 4.34 ± 0.92% for right and left legs, respectively (p < 0.001). There was a greater reduction in the mean LESS score in favor of the intervention group after exercise training (Cohen's d = 0.72, adjusted mean difference 2.49 ± 0.54, p < 0.001). Clinically and statistically significant improvements in dynamic balance and jump-landing technique occurred in collegiate level Gaelic football and hurling players who adopted the GAA 15, when compared with usual training. These findings support

The Far-UV Albedo of the Moon Determined from Dayside LAMP Observations

NASA Astrophysics Data System (ADS)

Bullock, Mark A.; Retherford, K. D.; Gladstone, R.; Greathouse, T. K.; Mandt, K. E.; Hendrix, A. R.; Feldman, P. D.; Miles, P. F.; Egan, A. F.

2013-10-01

The Lyman Alpha Mapping Project (LAMP) onboard the Lunar Reconnaissance Orbiter (LRO) has been recording far-UV photons reflected from the lunar surface almost continuously since December 2009 (Gladstone et al., 2010). One photon at a time, LAMP builds up spectra from 575 to 1965 Å with a resolution of 26 Å. We will present 3 years of accumulated LAMP lunar dayside spectral maps and derive the lunar geometric albedo spectrum for a range of phase angles. These LAMP observations can thus be used to reconstruct the lunar far-UV photometric function and refine photometric models of the lunar surface (Hapke, 1963; Lucke et al., 1976). We will also compare LAMP lunar dayside albedo with the albedo from 820-1840 Å obtained by the Hopkins Ultraviolet Telescope (HUT) on the March 1995 Astro-2 Space Shuttle mission (Henry et al., 1995). The improved lunar photometric functions from our analysis of LAMP albedo spectra will enable a better quantitative assessment of how phase angle and composition affect the Moon’s reflectance in the far-UV. Gladstone, G. R., Stern, S. A., Retherford, K. D., Black, R. K., Slater, D. C., Davis, M. W., Versteeg, M. H., Persson, K. B., Parker, J. W., Kaufmann, D. E., Egan, A. F., Greathouse, T. K., Feldman, P. D., Hurley, D., Pryor, W. R., Hendrix, A. R., 2010. LAMP: The lyman alpha mapping project on NASA's lunar reconnaissance orbiter mission. Space Science Reviews. 150, 161-181. Hapke, B. W., 1963. A theoretical photometric function for the lunar surface. Journal of Geophysical Research. 68, 4571-4586. Henry, R. C., Feldman, P. D., Kruk, J. W., Davidsen, A. F., Durrance, S. T., 1995. Ultraviolet Albedo of the Moon with the Hopkins Ultraviolet Telescope. The Astrophysical Journal Letters. 454, L69. Lucke, R. L., Henry, R. C., Fastie, W. G., 1976. Far-ultraviolet albedo of the moon. The Astronomical Journal. 81, 1162-1169.

Structure and photoinduced structural changes in nonstoichiometric a -As sub x S sub 1 minus x : A study by x-ray-absorption fine structure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhou, W.; Paesler, M.A.; Sayers, D.E.

1992-08-15

X-ray-absorption fine-structure data show that chemical ordering plays an important role in nonstoichiometric amorphous ({ital a}-)As{sub {ital x}}S{sub 1{minus}{ital x}} films at 0.4{le}{ital x}{lt}=0.5. The mixture of different chemical bonding behaviors of As-S and As-As in an {ital a}-As{sub 2}S{sub 3} random covalent network and an {ital a}-As{sub 4}S{sub 4} disordered molecular solid lead the structure to a more disordered state for 0.4{lt}{ital x}{lt}0.5. In particular, the structure at a composition around {ital x}=0.43 in {ital a}-As{sub {ital x}}S{sub 1{minus}{ital x}} represents a maximum of flexibility. Photoillumination results in (1) a more disordered state as indicated by an increase inmore » the static Debye-Waller factors (which are related to the creation of As-As homopolar bonds) and (2) modifications in the network structure, such as the increase of the As-As radial distances in the second shells. In nonstoichiometric material, the presence of As{sub 4}S{sub 4} molecules in the As{sub 2}S{sub 3} network tends to break up this network into small segments. This decoupling of pieces of the As{sub 2}S{sub 3} network (composed of S-bridged AsS{sub 3} pyramids and As-As wrong bonds) may lead to increased steric freedom that is related to a more disordered state that appears to be associated with photoinduced structural changes in amorphous arsenic sulfide.« less

String-like collective motion and diffusion in the interfacial region of ice

NASA Astrophysics Data System (ADS)

Wang, Xinyi; Tong, Xuhang; Zhang, Hao; Douglas, Jack F.

2017-11-01

We investigate collective molecular motion and the self-diffusion coefficient Ds of water molecules in the mobile interfacial layer of the secondary prismatic plane (11 2 ¯ 0 ) of hexagonal ice by molecular dynamics simulation based on the TIP4P/2005 water potential and a metrology of collective motion drawn from the field of glass-forming liquids. The width ξ of the mobile interfacial layer varies from a monolayer to a few nm as the temperature is increased towards the melting temperature Tm, in accordance with recent simulations and many experimental studies, although different experimental methods have differed in their precise estimates of the thickness of this layer. We also find that the dynamics within this mobile interfacial ice layer is "dynamically heterogeneous" in a fashion that has many features in common with glass-forming liquids and the interfacial dynamics of crystalline Ni over the same reduced temperature range, 2/3 < T/Tm < 1. In addition to exhibiting non-Gaussian diffusive transport, decoupling between mass diffusion and the structural relaxation time, and stretched exponential relaxation, we find string-like collective molecular exchange motion in the interfacial zone within the ice interfacial layer and colored noise fluctuations in the mean square molecular atomic displacement 〈u2〉 after a "caging time" of 1 ps, i.e., the Debye-Waller factor. However, while the heterogeneous dynamics of ice is clearly similar in many ways to molecular and colloidal glass-forming materials, we find distinct trends between the diffusion coefficient activation energy Ea for diffusion Ds and the interfacial width ξ from the scale of collective string-like motion L than those found in glass-forming liquids.

Water-level altitudes 2017 and water-level changes in the Chicot, Evangeline, and Jasper Aquifers and compaction 1973–2016 in the Chicot and Evangeline Aquifers, Houston-Galveston region, Texas

USGS Publications Warehouse

Kasmarek, Mark C.; Ramage, Jason K.

2017-08-16

across parts of north-central, eastern, and south-central Fort Bend County into southeastern Waller County. Adjacent to the areas where water levels declined was a broad area where water levels rose in central, eastern, and southeastern Harris County, most of Galveston County, eastern and northernmost Brazoria County, and northeastern Fort Bend County. The largest rise (200 ft) in water-level altitudes in the Chicot aquifer from 1977 to 2017 was in southeastern Harris County.The water-level-altitude contours for the Evangeline aquifer in 2017 indicated two areas where the water-level altitudes were 250 ft below datum—one area extending from south-central Montgomery County into north-central Harris County and another area in western Harris County. Water-level altitudes in the Evangeline aquifer ranged from 50 to 200 ft below datum throughout most of Harris County in 2017. In Montgomery County, water-level altitudes in the Evangeline aquifer in 2017 ranged from the aforementioned area where they were 250 ft below datum to an area where they were 200 ft above datum in the northwestern part of the county. The 1977–2017 water-level-change contours for the Evangeline aquifer depict a broad area where water-level altitudes declined in north-central Harris and south-central Montgomery Counties, extending through north-central, northwestern, and southwestern Harris County into western Liberty, southeastern and northeastern Waller, and northeastern and east-central Fort Bend Counties. The largest water-level-altitude decline (280 ft) was in north-central Harris and south-central Montgomery Counties. Water-level altitudes rose in a broad area from central, east-central, and southern Harris County extending into the northernmost part of Brazoria County, the northernmost part of Galveston County, and the southwestern area of Liberty County. The largest rise in water-level altitudes in the Evangeline aquifer from 1977 to 2017 (240 ft) was in southeastern Harris County

The Praise and Price of Pokémon GO: A Qualitative Study of Children's and Parents' Experiences.

PubMed

Lindqvist, Anna-Karin; Castelli, Darla; Hallberg, Josef; Rutberg, Stina

2018-01-03

Physical activity has multiple health benefits; however, the majority of children around the world do not attain the recommended levels of daily physical activity. Research has shown that the game Pokémon GO has increased the amount of physical activity of players and that the game has the potential to reach populations that traditionally have low levels of physical activity. Therefore, there is a need to understand which game components can promote initial and sustained physical activity. By using a qualitative research approach, it is possible to achieve rich descriptions and enhance a deep understanding of the components promoting physical activity among children in a game such as Pokémon GO. The objective of this study was to explore children's and parents' experiences playing Pokémon GO. Eight families comprising 13 children (aged 7-12 years) and 9 parents were selected using purposeful sampling. Data collected using focus groups were analyzed using qualitative latent content analysis. The following three themes were revealed: (1) exciting and enjoyable exploration; (2) dangers and disadvantages; and (3) cooperation conquers competition. The first centers around the present and possible future aspects of Pokémon GO that promote physical activity. The second focuses on unwanted aspects and specific threats to safety when playing the game. The third shows that cooperation and togetherness are highly valued by the participants and that competition is fun but less important. Components from Pokémon GO could enhance the efficacy of physical activity interventions. Cooperation and exploration are aspects of the game that preferably could be transferred into interventions aimed at promoting children's physical activity. ©Anna-Karin Lindqvist, Darla Castelli, Josef Hallberg, Stina Rutberg. Originally published in JMIR Serious Games (http://games.jmir.org), 03.01.2018.

Common Ground on Climate Change: Pairing Opposing Viewpoints for Conversations about Climate Change

NASA Astrophysics Data System (ADS)

Kirk, K. B.; Duggan-Haas, D.; Hayhoe, K.

2017-12-01

In American public discourse, people tend to strongly identify with the viewpoints held by their cultural and political tribes. However, entrenched positions do little to advance understanding, or work toward solving problems constructively. Worse yet, it has become commonplace to dismiss or demonize those coming from a different point of view - leading to the vitriolic stalemate that often characterizes social media and comment threads when it comes to climate change. One way to break this pattern is to invite people with opposing opinions to actually talk to one another. This presentation describes the lessons learned during the Common Ground on Climate Change project, in which people with contrasting views about climate change engage in a moderated interview with each other. Prior to the interview, participants complete a set of values-based questions. The goal is to reveal areas of common ground between apparent opposites, such as a sense of stewardship for Earth's resources, or an opinion that solutions to climate change will be more beneficial than harmful. The structure of the interviews is based on the hypothesis that if a conversation begins with an appreciation of common values, it becomes easier to broach areas of disagreement. Participants are matched up in one-on-one moderated interviews where they are encouraged to share their concerns, ideas, and priorities about the validity of climate science, the need for urgent action, and the types of solutions they find most tenable. Emerging themes from this series of interviews include the value of a diversity of outlooks, and the ability for moderated conversations to find surprising areas of agreement. Articles about the interviews also appear on the Yale Climate Connections website, https://www.yaleclimateconnections.org/author/karin/.

Controlling cytoplasmic c-Fos controls tumor growth in the peripheral and central nervous system.

PubMed

Gil, Germán A; Silvestre, David C; Tomasini, Nicolás; Bussolino, Daniela F; Caputto, Beatriz L

2012-06-01

Some 20 years ago c-Fos was identified as a member of the AP-1 family of inducible transcription factors (Angel and Karin in Biochim Biophys Acta 1072:129-157, 1991). More recently, an additional activity was described for this protein: it associates to the endoplasmic reticulum and activates the biosynthesis of phospholipids (Bussolino et al. in FASEB J 15:556-558, 2001), (Gil et al. in Mol Biol Cell 15:1881-1894, 2004), the quantitatively most important components of cellular membranes. This latter activity of c-Fos determines the rate of membrane genesis and consequently of growth in differentiating PC12 cells (Gil et al. in Mol Biol Cell 15:1881-1894, 2004). In addition, it has been shown that c-Fos is over-expressed both in PNS and CNS tumors (Silvestre et al. in PLoS One 5(3):e9544, 2010). Herein, it is shown that c-Fos-activated phospholipid synthesis is required to support membrane genesis during the exacerbated growth characteristic of brain tumor cells. Specifically blocking c-Fos-activated phospholipid synthesis significantly reduces proliferation of tumor cells in culture. Blocking c-Fos expression also prevents tumor progression in mice intra-cranially xeno-grafted human brain tumor cells. In NPcis mice, an animal model of the human disease Neurofibromatosis Type I (Cichowski and Jacks in Cell 104:593-604, 2001), animals spontaneously develop tumors of the PNS and the CNS, provided they express c-Fos (Silvestre et al. in PLoS One 5(3):e9544, 2010). Treatment of PNS tumors with an antisense oligonucleotide that specifically blocks c-Fos expression also blocks tumor growth in vivo. These results disclose cytoplasmic c-Fos as a new target for effectively controlling brain tumor growth.

Lunar and Planetary Science XXXVI, Part 18

NASA Technical Reports Server (NTRS)

2005-01-01

Topics discussed include: PoDS: A Powder Delivery System for Mars In-Situ Organic, Mineralogic and Isotopic Analysis Instruments Planetary Differentiation of Accreting Planetesimals with 26Al and 60Fe as the Heat Sources Ground-based Observation of Lunar Surface by Lunar VIS/NIR Spectral Imager Mt. Oikeyama Structure: First Impact Structure in Japan? Central Mounds in Martian Impact Craters: Assessment as Possible Perennial Permafrost Mounds (Pingos) A Further Analysis of Potential Photosynthetic Life on Mars New Insight into Valleys-Ocean Boundary on Mars Using 128 Pixels per Degree MOLA Data: Implication for Martian Ocean and Global Climate Change; Recursive Topography Based Surface Age Computations for Mars: New Insight into Surficial Processes That Influenced Craters Distribution as a Step Toward the Formal Proof of Martian Ocean Recession, Timing and Probability; Laser-induced Breakdown Spectroscopy: A New Method for Stand-Off Quantitative Analysis of Samples on Mars; Milk Spring Channels Provide Further Evidence of Oceanic, >1.7-km-Deep Late Devonian Alamo Crater, Southern Nevada; Exploration of Martian Polar Residual Caps from HEND/ODYSSEY Data; Outflow Channels Influencing Martian Climate: Global Circulation Model Simulations with Emplaced Water; Presence of Nonmethane Hydrocarbons on Pluto; Difference in Degree of Space Weathering on the Newborn Asteroid Karin; Circular Collapsed Features Related to the Chaotic Terrain Formation on Mars; A Search for Live (sup 244)Pu in Deep-Sea Sediments: Preliminary Results of Method Development; Some Peculiarities of Quartz, Biotite and Garnet Transformation in Conditions of Step-like Shock Compression of Crystal Slate; Error Analysis of Remotely-Acquired Mossbauer Spectra; Cloud Activity on Titan During the Cassini Mission; Solar Radiation Pressure and Transient Flows on Asteroid Surfaces; Landing Site Characteristics for Europa 1: Topography; and The Crop Circles of Europa.

Bringing radical behaviorism to revolutionary Brazil and back: Fred Keller's Personalized System of Instruction and Cold War engineering education.

PubMed

Akera, Atsushi

2017-09-01

This article traces the shifting epistemic commitments of Fred S. Keller and his behaviorist colleagues during their application of Skinnerian radical behaviorism to higher education pedagogy. Building on prior work by Alexandra Rutherford and her focus on the successive adaptation of Skinnerian behaviorism during its successive applications, this study utilizes sociologist of science Karin Knorr Cetina's concept of epistemic cultures to more precisely trace the changes in the epistemic commitments of a group of radical behaviorists as they shifted their focus to applied behavioral analysis. The story revolves around a self-paced system of instruction known as the Personalized System of Instruction, or PSI, which utilized behaviorist principles to accelerate learning within the classroom. Unlike Skinner's entry into education, and his focus on educational technologies, Keller developed a mastery-based approach to instruction that utilized generalized reinforcers to cultivate higher-order learning behaviors. As it happens, the story also unfolds across a rather fantastic political terrain: PSI originated in the context of Brazilian revolutionary history, but circulated widely in the U.S. amidst Cold War concerns about an engineering manpower(sic) crisis. This study also presents us with an opportunity to test Knorr Cetina's conjecture about the possible use of a focus on epistemic cultures in addressing a classic problem in the sociology of science, namely unpacking the relationship between knowledge and its social context. Ultimately, however, this study complements another historical case study in applied behavioral analysis, where a difference in outcome helps to lay out the range of possible shifts in the epistemic commitments of radical behaviorists who entered different domains of application. The case study also has some practical implications for those creating distance learning environments today, which are briefly explored in the conclusion. © 2017 Wiley

Multiverse: Increasing Diversity in Earth and Space Science Through Multicultural Education

NASA Astrophysics Data System (ADS)

Peticolas, L. M.; Raftery, C. L.; Mendez, B.; Paglierani, R.; Ali, N. A.; Zevin, D.; Frappier, R.; Hauck, K.; Shackelford, R. L., III; Yan, D.; Thrall, L.

2015-12-01

Multiverse at the University of California, Berkeley Space Sciences Laboratory provides earth and space science educational opportunities and resources for a variety of audiences, especially for those who are underrepresented in the sciences. By way of carefully crafted space and earth science educational opportunities and resources, we seek to connect with people's sense of wonder and facilitate making personal ties to science and the learning process in order to, ultimately, bring the richness of diversity to science and make science discovery accessible for all. Our audiences include teachers, students, education and outreach professionals, and the public. We partner with NASA, the National Science Foundation, scientists, teachers, science center and museum educators, park interpreters, and others with expertise in reaching particular audiences. With these partners, we develop resources and communities of practice, offer educator workshops, and run events for the public. We will will present on our pedagogical techniques, our metrics for success, and our evaluation findings of our education and outreach projects that help us towards reaching our vision: We envision a world filled with science literate societies capable of thriving with today's technology, while maintaining a sustainable balance with the natural world; a world where people develop and sustain the ability to think critically using observation and evidence and participate authentically in scientific endeavors; a world where people see themselves and their culture within the scientific enterprise, and understand science within the context that we are all under one sky and on one Earth. Photo Caption: Multiverse Team Members at our Space Sciences Laboratory from left to right: Leitha Thrall, Daniel Zevin, Bryan Mendez, Nancy Ali, Igor Ruderman, Laura Peticolas, Ruth Paglierani, Renee Frappier, Rikki Shackelford, Claire Raftery, Karin Hauck, and Darlene Yan.

NASA Tech Briefs, December 2011

NASA Technical Reports Server (NTRS)

2011-01-01

Topics covered include: 1) SNE Industrial Fieldbus Interface; 2) Composite Thermal Switch; 3) XMOS XC-2 Development Board for Mechanical Control and Data Collection; 4) Receiver Gain Modulation Circuit; 5) NEXUS Scalable and Distributed Next-Generation Avionics Bus for Space Missions; 6) Digital Interface Board to Control Phase and Amplitude of Four Channels; 7) CoNNeCT Baseband Processor Module; 8) Cryogenic 160-GHz MMIC Heterodyne Receiver Module; 9) Ka-Band, Multi-Gigabit-Per-Second Transceiver; 10) All-Solid-State 2.45-to-2.78-THz Source; 11) Onboard Interferometric SAR Processor for the Ka-Band Radar Interferometer (KaRIn); 12) Space Environments Testbed; 13) High-Performance 3D Articulated Robot Display; 14) Athena; 15) In Situ Surface Characterization; 16) Ndarts; 17) Cryo-Etched Black Silicon for Use as Optical Black; 18) Advanced CO2 Removal and Reduction System; 19) Correcting Thermal Deformations in an Active Composite Reflector; 20) Umbilical Deployment Device; 21) Space Mirror Alignment System; 22) Thermionic Power Cell To Harness Heat Energies for Geothermal Applications; 23) Graph Theory Roots of Spatial Operators for Kinematics and Dynamics; 24) Spacesuit Soft Upper Torso Sizing Systems; 25) Radiation Protection Using Single-Wall Carbon Nanotube Derivatives; 26) PMA-PhyloChip DNA Microarray to Elucidate Viable Microbial Community Structure; 27) Lidar Luminance Quantizer; 28) Distributed Capacitive Sensor for Sample Mass Measurement; 29) Base Flow Model Validation; 30) Minimum Landing Error Powered-Descent Guidance for Planetary Missions; 31) Framework for Integrating Science Data Processing Algorithms Into Process Control Systems; 32) Time Synchronization and Distribution Mechanisms for Space Networks; 33) Local Estimators for Spacecraft Formation Flying; 34) Software-Defined Radio for Space-to-Space Communications; 35) Reflective Occultation Mask for Evaluation of Occulter Designs for Planet Finding; and 36) Molecular Adsorber Coating

Glass transition of polymers in bulk, confined geometries, and near interfaces

NASA Astrophysics Data System (ADS)

Napolitano, Simone; Glynos, Emmanouil; Tito, Nicholas B.

2017-03-01

When cooled or pressurized, polymer melts exhibit a tremendous reduction in molecular mobility. If the process is performed at a constant rate, the structural relaxation time of the liquid eventually exceeds the time allowed for equilibration. This brings the system out of equilibrium, and the liquid is operationally defined as a glass—a solid lacking long-range order. Despite almost 100 years of research on the (liquid/)glass transition, it is not yet clear which molecular mechanisms are responsible for the unique slow-down in molecular dynamics. In this review, we first introduce the reader to experimental methodologies, theories, and simulations of glassy polymer dynamics and vitrification. We then analyse the impact of connectivity, structure, and chain environment on molecular motion at the length scale of a few monomers, as well as how macromolecular architecture affects the glass transition of non-linear polymers. We then discuss a revised picture of nanoconfinement, going beyond a simple picture based on interfacial interactions and surface/volume ratio. Analysis of a large body of experimental evidence, results from molecular simulations, and predictions from theory supports, instead, a more complex framework where other parameters are relevant. We focus discussion specifically on local order, free volume, irreversible chain adsorption, the Debye-Waller factor of confined and confining media, chain rigidity, and the absolute value of the vitrification temperature. We end by highlighting the molecular origin of distributions in relaxation times and glass transition temperatures which exceed, by far, the size of a chain. Fast relaxation modes, almost universally present at the free surface between polymer and air, are also remarked upon. These modes relax at rates far larger than those characteristic of glassy dynamics in bulk. We speculate on how these may be a signature of unique relaxation processes occurring in confined or heterogeneous polymeric

Validation of reference genes for normalization of qPCR gene expression data from Coffea spp. hypocotyls inoculated with Colletotrichum kahawae

PubMed Central

2013-01-01

Background Coffee production in Africa represents a significant share of the total export revenues and influences the lives of millions of people, yet severe socio-economic repercussions are annually felt in result of the overall losses caused by the coffee berry disease (CBD). This quarantine disease is caused by the fungus Colletotrichum kahawae Waller and Bridge, which remains one of the most devastating threats to Coffea arabica production in Africa at high altitude, and its dispersal to Latin America and Asia represents a serious concern. Understanding the molecular genetic basis of coffee resistance to this disease is of high priority to support breeding strategies. Selection and validation of suitable reference genes presenting stable expression in the system studied is the first step to engage studies of gene expression profiling. Results In this study, a set of ten genes (S24, 14-3-3, RPL7, GAPDH, UBQ9, VATP16, SAND, UQCC, IDE and β-Tub9) was evaluated to identify reference genes during the first hours of interaction (12, 48 and 72 hpi) between resistant and susceptible coffee genotypes and C. kahawae. Three analyses were done for the selection of these genes considering the entire dataset and the two genotypes (resistant and susceptible), separately. The three statistical methods applied GeNorm, NormFinder, and BestKeeper, allowed identifying IDE as one of the most stable genes for all datasets analysed, and in contrast GADPH and UBQ9 as the least stable ones. In addition, the expression of two defense-related transcripts, encoding for a receptor like kinase and a pathogenesis related protein 10, were used to validate the reference genes selected. Conclusion Taken together, our results provide guidelines for reference gene(s) selection towards a more accurate and widespread use of qPCR to study the interaction between Coffea spp. and C. kahawae. PMID:24073624

Environmental contaminant hazards to Attwater's greater prairie-chickens

USGS Publications Warehouse

Flickinger, Edward L.; Swineford, Douglas M.

1983-01-01

The Attwater's greater prairie-chicken (Tympanuchus cupido attwateri) was declared an endangered species in 1966 and exists only on the upper Gulf Coast prairie of southeast Texas. Since 1975, total numbers have declined from 2,240 to 1,456 in 1981 (Jurries 19679; W. Shifflett, Manager Attwater Prairie Chicken National Wildlife Refuge [APCNWR], personal communication).The total population of this prairie grouse is presently scattered in a norther, largely agricultural, but also urban-rangeland area of 6 counties that contained about 600 individuals in 1971, and a southern, largely rangeland, but also agricultural-urban area of 4 counties that contained about 860 individuals in 1981. During the present study, Attwater's prairie-chickens completely disappeared in Wharton and Waller counties in the northern area (W. Shifflett, personal communication).Prairie-chickens in the northern area frequent crops of rice, soybeans, peanuts, or corn; those in the southern area frequent sorghum or cotton that are planted on or near ancestral booming grounds. The use of pesticides in the agricultural areas may have contributed to the initial decline of prairie-chicken numbers. In 1927, several hundred prairie-chickens were found dead in and near a cotton field in Wharton County shortly after it had been treated with arsenic (Lehmann and Mauermann 1963). The remains of 5 prairie-chickens were found in sorghum and soybean fields in Refugio and Colorado counties between 1975 and 1977 (R. Haeber and W. Kessler, personal communication) but were too decomposed to be analyzed for evidence of pesticide exposure. Parathion formulations had been applied to the soybeans and near the sorghum. Other pesticide use on the areas was uncertain. The objective of this study was to ascertain pesticide hazards to Attwater's greater prairie-chickens.

Structure of aqueous cesium metaborate solutions by X-ray scattering and DFT calculation

NASA Astrophysics Data System (ADS)

Zhang, W. Q.; Fang, C. H.; Fang, Y.; Zhu, F. Y.; Zhou, Y. Q.; Liu, H. Y.; Li, W.

2018-05-01

In the present work, precise radial distribution function (RDF) of cesium metaborate solutions with salt-water molar ratio of 1:25, 1:30 and 1:35 in large scattering vector range (3.91-214.26 nm-1) were obtained by X-ray scattering. Polyborate species were given using Newton iteration method with measured pH and literature equilibrium constants. In model calculation, structural parameters such as the coordination number, interatomic distance and Debye-Waller factor were given through model calculation. The B-O(H2O) distance was determined to be ∼0.37 nm with the hydration number of ∼7.8 for B(OH)4-. The Cs-B distance of the contact ions CsB(OH)40 was measured to be ∼0.46 nm with interaction number of ∼0.77. The interaction distances and coordination number for the first shell and the second shell of Cs-O(W) are ∼0.325 nm, ∼0.517 nm and ∼8.0, ∼11, respectively. Five low-energy configurations of [Cs(H2O)8]+ were given with DFT calculation, including the first and the second hydration shell, and the most stable eight-coordinated one is close to the model calculation. Furthermore, the effect of concentration is discussed in the X-ray scattering analysis part, showing that hydration degree changes with the concentration. For the coordination number and distance of Cs-O(H2O) and H-bonding decrease with the increasing concentration. The coordination number of Cs-O(H2O) keep stable, and the coordination distance changes from 3.25 nm to 3.30 nm. For H-bonding, which the coordination number varies from 2.20 to 2.24, and the coordination distance varies from 2.76 nm to 2.78 nm with the decreasing concentration.

Water-level altitudes 2005 and water-level changes in the Chicot, Evangeline, and Jasper aquifers and compaction 1973-2004 in the Chicot and Evangeline aquifers, Houston-Galveston region, Texas

USGS Publications Warehouse

Kasmarek, Mark C.; Houston, Natalie A.

2005-01-01

This report is one in an annual series of reports that depicts water-level altitudes and water-level changes in the Chicot, Evangeline, and Jasper aquifers, and compaction in the Chicot and Evangeline aquifers in the Houston-Galveston region. The Houston-Galveston region comprises Harris, Galveston, Fort Bend, Waller, and Montgomery Counties and adjacent parts of Brazoria, Grimes, Walker, San Jacinto, Liberty, and Chambers Counties. The report was prepared in cooperation with the Harris-Galveston Coastal Subsidence District, the City of Houston, the Fort Bend Subsidence District, and the Lone Star Groundwater Conservation District. For the Chicot and Evangeline aquifers, maps show approximate water-level altitudes in 2005, water-level changes from 2004 to 2005, and approximate water-level changes from 2000 to 2005, from 1990 to 2005, and from 1977 to 2005 (figs. 1, 2, 3, 4, 5, 6, 7, 8, 9, and 10). For the Jasper aquifer, maps show approximate water-level altitudes in 2005 and water-level changes from 2004 to 2005 and 2000 to 2005 (figs. 11, 12, and 13). The report also contains a map showing borehole extensometer (well equipped with compaction monitor) site locations (fig. 14) and graphs showing measured compaction of subsurface material at these sites from 1973 or later to 2004 (fig. 15).The U.S. Geological Survey (USGS) has published annual reports of water-level altitudes and water-level changes for the Chicot and Evangeline aquifers in the Houston-Galveston region since 1979; and annual reports of same for the Fort Bend subregion (Fort Bend County and adjacent areas) since 1990. The USGS published its first water-level-altitude map for the Jasper aquifer in the greater Houston area (primarily Montgomery County) in 2001. The 2005 water-level-altitude and water-level-change maps for the three aquifers are included in this report.

Water-level altitudes 2006 and water-level changes in the Chicot, Evangeline, and Jasper aquifers and compaction 1973-2005 in the Chicot and Evangeline aquifers, Houston-Galveston region, Texas

USGS Publications Warehouse

Kasmarek, Mark C.; Houston, Natalie A.; Brown, Dexter W.

2006-01-01

This report is one in an annual series of reports that depicts water-level altitudes and water-level changes in the Chicot, Evangeline, and Jasper aquifers, and compaction in the Chicot and Evangeline aquifers in the Houston-Galveston region. The Houston-Galveston region comprises Harris, Galveston, Fort Bend, Waller, and Montgomery Counties and adjacent parts of Brazoria, Grimes, Walker, San Jacinto, Liberty, and Chambers Counties. The report was prepared in cooperation with the Harris-Galveston Coastal Subsidence District, the City of Houston, the Fort Bend Subsidence District, and the Lone Star Groundwater Conservation District. For the Chicot and Evangeline aquifers, maps show approximate water-level altitudes in 2006, water-level changes from 2005 to 2006, and approximate water-level changes from 2001 to 2006, from 1990 to 2006, and from 1977 to 2006 (figs. 1, 2, 3, 4, 5, 6, 7, 8, 9, 10). For the Jasper aquifer, maps show approximate water-level altitudes in 2006 and water-level changes from 2005 to 2006 and 2000 to 2006 (figs. 11, 12, 13). The report also contains a map showing borehole extensometer (well equipped with compaction monitor) site locations (fig. 14) and graphs showing measured compaction of subsurface material at these sites from 1973 or later to 2005 (fig. 15).The U.S. Geological Survey (USGS) has published annual reports of water-level altitudes and water-level changes for the Chicot and Evangeline aquifers in the Houston-Galveston region since 1979; and annual reports of same for the Fort Bend subregion (Fort Bend County and adjacent areas) since 1990. The USGS published its first water-level-altitude map for the Jasper aquifer in the greater Houston area (primarily Montgomery County) in 2001. The 2006 water-level-altitude and water-level-change maps for the three aquifers are included in this report.

Depression Prevalence and Exposure to Organophosphate Esters in Aircraft Maintenance Workers.

PubMed

Hardos, Jennifer E; Whitehead, Lawrence W; Han, Inkyu; Ott, Darrin K; Waller, D Kim

2016-08-01

Previous studies found that aircraft maintenance workers may be exposed to organophosphates in hydraulic fluid and engine oil. Studies have also illustrated a link between long-term low-level organophosphate pesticide exposure and depression. A questionnaire containing the Patient Health Questionnaire 8 depression screener was e-mailed to 52,080 aircraft maintenance workers (with N = 4801 complete responses) in a cross-sectional study to determine prevalence and severity of depression and descriptions of their occupational exposures. There was no significant difference between reported depression prevalence and severity in similar exposure groups in which aircraft maintenance workers were exposed or may have been exposed to organophosphate esters compared to similar exposure groups in which they were not exposed. However, a dichotomous measure of the prevalence of depression was significantly associated with self-reported exposure levels from low (OR: 1.21) to moderate (OR: 1.68) to high exposure (OR: 2.70) and with each exposure route including contact (OR: 1.68), inhalation (OR: 2.52), and ingestion (OR: 2.55). A self-reported four-level measure of depression severity was also associated with a self-reported four-level measure of exposure. Based on self-reported exposures and outcomes, an association is observed between organophosphate exposure and depression; however, we cannot assume that the associations we observed are causal because some workers may have been more likely to report exposure to organophosphate esters and also more likely to report depression. Future studies should consider using a larger sample size, better methods for characterizing crew chief exposures, and bioassays to measure dose rather than exposure. Hardos JE, Whitehead LW, Han I, Ott DK, Waller DK. Depression prevalence and exposure to organophosphate esters in aircraft maintenance workers. Aerosp Med Hum Perform. 2016; 87(8):712-717.

On the role of thermal backbone fluctuations in myoglobin ligand gate dynamics.

PubMed

Krokhotin, Andrey; Niemi, Antti J; Peng, Xubiao

2013-05-07

We construct an energy function that describes the crystallographic structure of sperm whale myoglobin backbone. As a model in our construction, we use the Protein Data Bank entry 1ABS that has been measured at liquid helium temperature. Consequently, the thermal B-factor fluctuations are very small, which is an advantage in our construction. The energy function that we utilize resembles that of the discrete nonlinear Schrödinger equation. Likewise, ours supports topological solitons as local minimum energy configurations. We describe the 1ABS backbone in terms of topological solitons with a precision that deviates from 1ABS by an average root-mean-square distance, which is less than the experimentally observed Debye-Waller B-factor fluctuation distance. We then subject the topological multi-soliton solution to extensive numerical heating and cooling experiments, over a very wide range of temperatures. We concentrate in particular to temperatures above 300 K and below the Θ-point unfolding temperature, which is around 348 K. We confirm that the behavior of the topological multi-soliton is fully consistent with Anfinsen's thermodynamic principle, up to very high temperatures. We observe that the structure responds to an increase of temperature consistently in a very similar manner. This enables us to characterize the onset of thermally induced conformational changes in terms of three distinct backbone ligand gates. One of the gates is made of the helix F and the helix E. The two other gates are chosen similarly, when open they provide a direct access route for a ligand to reach the heme. We find that out of the three gates we investigate, the one which is formed by helices B and G is the most sensitive to thermally induced conformational changes. Our approach provides a novel perspective to the important problem of ligand entry and exit.

On the role of thermal backbone fluctuations in myoglobin ligand gate dynamics

NASA Astrophysics Data System (ADS)

Krokhotin, Andrey; Niemi, Antti J.; Peng, Xubiao

2013-05-01

We construct an energy function that describes the crystallographic structure of sperm whale myoglobin backbone. As a model in our construction, we use the Protein Data Bank entry 1ABS that has been measured at liquid helium temperature. Consequently, the thermal B-factor fluctuations are very small, which is an advantage in our construction. The energy function that we utilize resembles that of the discrete nonlinear Schrödinger equation. Likewise, ours supports topological solitons as local minimum energy configurations. We describe the 1ABS backbone in terms of topological solitons with a precision that deviates from 1ABS by an average root-mean-square distance, which is less than the experimentally observed Debye-Waller B-factor fluctuation distance. We then subject the topological multi-soliton solution to extensive numerical heating and cooling experiments, over a very wide range of temperatures. We concentrate in particular to temperatures above 300 K and below the Θ-point unfolding temperature, which is around 348 K. We confirm that the behavior of the topological multi-soliton is fully consistent with Anfinsen's thermodynamic principle, up to very high temperatures. We observe that the structure responds to an increase of temperature consistently in a very similar manner. This enables us to characterize the onset of thermally induced conformational changes in terms of three distinct backbone ligand gates. One of the gates is made of the helix F and the helix E. The two other gates are chosen similarly, when open they provide a direct access route for a ligand to reach the heme. We find that out of the three gates we investigate, the one which is formed by helices B and G is the most sensitive to thermally induced conformational changes. Our approach provides a novel perspective to the important problem of ligand entry and exit.

Ultrafast non-radiative dynamics of atomically thin MoSe 2

DOE PAGES

Lin, Ming -Fu; Kochat, Vidya; Krishnamoorthy, Aravind; ...

2017-10-17

Non-radiative energy dissipation in photoexcited materials and resulting atomic dynamics provide a promising pathway to induce structural phase transitions in two-dimensional materials. However, these dynamics have not been explored in detail thus far because of incomplete understanding of interaction between the electronic and atomic degrees of freedom, and a lack of direct experimental methods to quantify real-time atomic motion and lattice temperature. Here, we explore the ultrafast conversion of photoenergy to lattice vibrations in a model bi-layered semiconductor, molybdenum diselenide, MoSe 2. Specifically, we characterize sub-picosecond lattice dynamics initiated by the optical excitation of electronic charge carriers in the highmore » electron-hole plasma density regime. Our results focuses on the first ten picosecond dynamics subsequent to photoexcitation before the onset of heat transfer to the substrate, which occurs on a ~100 picosecond time scale. Photoinduced atomic motion is probed by measuring the time dependent Bragg diffraction of a delayed mega-electronvolt femtosecond electron beam. Transient lattice temperatures are characterized through measurement of Bragg peak intensities and calculation of the Debye-Waller factor (DWF). These measurements show a sub-picosecond decay of Bragg diffraction and a correspondingly rapid rise in lattice temperatures. We estimate a high quantum yield for the conversion of excited charge carrier energy to lattice motion under our experimental conditions, indicative of a strong electron-phonon interaction. First principles nonadiabatic quantum molecular dynamics simulations (NAQMD) on electronically excited MoSe 2 bilayers reproduce the observed picosecond-scale increase in lattice temperature and ultrafast conversion of photoenergy to lattice vibrations. Calculation of excited-state phonon dispersion curves suggests that softened vibrational modes in the excited state are involved in efficient and rapid energy

Cytochrome C in a dry trehalose matrix: structural and dynamical effects probed by x-ray absorption spectroscopy.

PubMed

Giachini, Lisa; Francia, Francesco; Cordone, Lorenzo; Boscherini, Federico; Venturoli, Giovanni

2007-02-15

We report on the structure and dynamics of the Fe ligand cluster of reduced horse heart cytochrome c in solution, in a dried polyvinyl alcohol (PVA) film, and in two trehalose matrices characterized by different contents of residual water. The effect of the solvent/matrix environment was studied at room temperature using Fe K-edge x-ray absorption fine structure (XAFS) spectroscopy. XAFS data were analyzed by combining ab initio simulations and multi-parameter fitting in an attempt to disentangle structural from disorder parameters. Essentially the same structural and disorder parameters account adequately for the XAFS spectra measured in solution, both in the absence and in the presence of glycerol, and in the PVA film, showing that this polymer interacts weakly with the embedded protein. Instead, incorporation in trehalose leads to severe structural changes, more prominent in the more dried matrix, consisting of 1), an increase up to 0.2 A of the distance between Fe and the imidazole N atom of the coordinating histidine residue and 2), an elongation up to 0.16 A of the distance between Fe and the fourth-shell C atoms of the heme pyrrolic units. These structural distortions are accompanied by a substantial decrease of the relative mean-square displacements of the first ligands. In the extensively dried trehalose matrix, extremely low values of the Debye Waller factors are obtained for the pyrrolic and for the imidazole N atoms. This finding is interpreted as reflecting a drastic hindering in the relative motions of the Fe ligand cluster atoms and an impressive decrease in the static disorder of the local Fe structure. It appears, therefore, that the dried trehalose matrix dramatically perturbs the energy landscape of cytochrome c, giving rise, at the level of local structure, to well-resolved structural distortions and restricting the ensemble of accessible conformational substates.

Experimental and theoretical study of rotationally inelastic diffraction of H2(D2) from methyl-terminated Si(111)

NASA Astrophysics Data System (ADS)

Nihill, Kevin J.; Hund, Zachary M.; Muzas, Alberto; Díaz, Cristina; del Cueto, Marcos; Frankcombe, Terry; Plymale, Noah T.; Lewis, Nathan S.; Martín, Fernando; Sibener, S. J.

2016-08-01

Fundamental details concerning the interaction between H2 and CH3-Si(111) have been elucidated by the combination of diffractive scattering experiments and electronic structure and scattering calculations. Rotationally inelastic diffraction (RID) of H2 and D2 from this model hydrocarbon-decorated semiconductor interface has been confirmed for the first time via both time-of-flight and diffraction measurements, with modest j = 0 → 2 RID intensities for H2 compared to the strong RID features observed for D2 over a large range of kinematic scattering conditions along two high-symmetry azimuthal directions. The Debye-Waller model was applied to the thermal attenuation of diffraction peaks, allowing for precise determination of the RID probabilities by accounting for incoherent motion of the CH3-Si(111) surface atoms. The probabilities of rotationally inelastic diffraction of H2 and D2 have been quantitatively evaluated as a function of beam energy and scattering angle, and have been compared with complementary electronic structure and scattering calculations to provide insight into the interaction potential between H2 (D2) and hence the surface charge density distribution. Specifically, a six-dimensional potential energy surface (PES), describing the electronic structure of the H2(D2)/CH3-Si(111) system, has been computed based on interpolation of density functional theory energies. Quantum and classical dynamics simulations have allowed for an assessment of the accuracy of the PES, and subsequently for identification of the features of the PES that serve as classical turning points. A close scrutiny of the PES reveals the highly anisotropic character of the interaction potential at these turning points. This combination of experiment and theory provides new and important details about the interaction of H2 with a hybrid organic-semiconductor interface, which can be used to further investigate energy flow in technologically relevant systems.

Time Resolved X-Ray Diffraction Study of Acoustoelectrically Amplified Phonons.

NASA Astrophysics Data System (ADS)

Chapman, Leroy Dean

X-rays diffracted by nearly perfect crystals of n-type InSb have been investigated in the presence of intense acoustoelectrically (A.E.) amplified phonons. The fact that these phonons are nearly monochromatic and have a well defined propagation and polarization direction presents an excellent opportunity to investigate the nature of x -ray photon-phonon scattering in a diffracting crystal. The Debye-Waller factor which accounts for the attenuation of diffracted x-ray intensities due to thermal phonons is reflection dependent owing to its sin (theta)/(lamda) dependence. We have performed experiments comparing the (004) and (008) anomalously transmitted intensities as a function of A.E. amplified flux. The attenuation of both reflections due to the amplified phonons was the same in direct contradiction to an expected sin (theta)/(lamda) dependence. Some possible reasons for this failure are discussed. In a Bragg reflection scattering geometry, the intense monochromatic amplified phonons give rise to satellite peaks symmetrically located about the central elastic Brag peak in a rocking profile. We report in this thesis on the first observation of satellites in a thin crystal Laue transmission geometry. We have theoretically simulated the rocking profiles with some success. The A.E. amplification process in InSb is strongly favored for {110} propagation fast transverse (FT) phonons. In earlier experiments it was found that non-{110} FT phonons were also produced during the amplification process. We have developed a time resolved x-ray counting system which, in conjunction with a spatially resolved x-ray beam and a localized, traveling A.E. phonon distribution, allow the time evolution of the amplified distribution to be followed. We report on time resolved measurements for both the symmetric Bragg and Laue geometries from which we can determine when and where non-{110 } FT flux is generated and restrict the possible mechanisms for its generation.

Ultrafast non-radiative dynamics of atomically thin MoSe 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lin, Ming -Fu; Kochat, Vidya; Krishnamoorthy, Aravind

Non-radiative energy dissipation in photoexcited materials and resulting atomic dynamics provide a promising pathway to induce structural phase transitions in two-dimensional materials. However, these dynamics have not been explored in detail thus far because of incomplete understanding of interaction between the electronic and atomic degrees of freedom, and a lack of direct experimental methods to quantify real-time atomic motion and lattice temperature. Here, we explore the ultrafast conversion of photoenergy to lattice vibrations in a model bi-layered semiconductor, molybdenum diselenide, MoSe 2. Specifically, we characterize sub-picosecond lattice dynamics initiated by the optical excitation of electronic charge carriers in the highmore » electron-hole plasma density regime. Our results focuses on the first ten picosecond dynamics subsequent to photoexcitation before the onset of heat transfer to the substrate, which occurs on a ~100 picosecond time scale. Photoinduced atomic motion is probed by measuring the time dependent Bragg diffraction of a delayed mega-electronvolt femtosecond electron beam. Transient lattice temperatures are characterized through measurement of Bragg peak intensities and calculation of the Debye-Waller factor (DWF). These measurements show a sub-picosecond decay of Bragg diffraction and a correspondingly rapid rise in lattice temperatures. We estimate a high quantum yield for the conversion of excited charge carrier energy to lattice motion under our experimental conditions, indicative of a strong electron-phonon interaction. First principles nonadiabatic quantum molecular dynamics simulations (NAQMD) on electronically excited MoSe 2 bilayers reproduce the observed picosecond-scale increase in lattice temperature and ultrafast conversion of photoenergy to lattice vibrations. Calculation of excited-state phonon dispersion curves suggests that softened vibrational modes in the excited state are involved in efficient and rapid energy

Water-level altitudes 2004 and water-level changes in the Chicot, Evangeline, and Jasper aquifers and compaction 1973-2003 in the Chicot and Evangeline aquifers, Houston-Galveston region, Texas

USGS Publications Warehouse

Kasmarek, Mark C.; Lanning-Rush, Jennifer

2004-01-01

This report is one in an annual series of reports that depicts water-level altitudes and water-level changes in the Chicot, Evangeline, and Jasper aquifers, and compaction in the Chicot and Evangeline aquifers in the Houston-Galveston region. The Houston-Galveston region comprises Harris, Galveston, Fort Bend, Waller, and Montgomery Counties and adjacent parts of Brazoria, Grimes, Walker, San Jacinto, Liberty, and Chambers Counties. The report was prepared in cooperation with the Harris-Galveston Coastal Subsidence District, the City of Houston, the Fort Bend Subsidence District, and the Lone Star Groundwater Conservation District. For the Chicot and Evangeline aquifers, maps show approximate water-level altitudes in 2004, water-level changes from 2003 to 2004, approximate water-level changes from 1977 to 2004, and approximate water-level changes from 1990 to 2004 (figs. 1, 2, 3, 4, 5, 6, 7, 8). For the Jasper aquifer, maps show approximate water-level altitudes in 2004 and water-level changes from 2003 to 2004 and 2000 to 2004 (figs. 9, 10, 11). The report also contains a map showing borehole extensometer (well equipped with compaction monitor) site locations (fig. 12) and graphs showing measured compaction of subsurface material at these sites from 1973 or later to 2003 (fig. 13). The U.S. Geological Survey (USGS) has published annual reports of water-level altitudes and water-level changes for the Chicot and Evangeline aquifers in the Houston-Galveston region since 1979; and annual reports of same for the Fort Bend subregion (Fort Bend County and adjacent areas) since 1990. The USGS published its first water-level-altitude map for the Jasper aquifer in the greater Houston area (primarily Montgomery County) in 2001. The 2004 water-level-altitude and water-level-change maps for the three aquifers are included in this report.

The innate oxygen dependant immune pathway as a sensitive parameter to predict the performance of biological graft materials.

PubMed

Bryan, Nicholas; Ashwin, Helen; Smart, Neil; Bayon, Yves; Scarborough, Nelson; Hunt, John A

2012-09-01

Clinical performance of a biomaterial is decided early after implantation as leukocytes interrogate the graft throughout acute inflammation. High degrees of leukocyte activation lead to poor material/patient compliance, accelerated degeneration and graft rejection. A number reactive oxygen species (ROS) are released by leukocytes throughout their interaction with a material, which can be used as a sensitive measure of leukocyte activation. The aim of this study was to compare leukocyte activation by commercially available biologic surgical materials and define the extent manufacturing variables influence down-stream ROS response. Chemiluminescence assays were performed using modifications to a commercially available kit (Knight Scientific, UK). Whole blood was obtained from 4 healthy human adults at 7 day intervals for 4 weeks, combined with Adjuvant K, Pholasin (a highly sensitive ROS excitable photoprotein) and biomaterial, and incubated for 60 min with continuous chemiluminescent measurements. Leukocyte ROS inducers fMLP and PMA were added as controls. Xeno- and allogeneic dermal and small intestinal submucosal (SIS) derived biomaterials were produced commercially (Surgisis Biodesign™, Alloderm(®), Strattice(®)Firm & Pliable & Permacol™) or fabricated in house to induce variations in decellularisation and cross-linking. Statistics were performed using Waller-Duncan post hoc ranking. Materials demonstrated significant differences in leukocyte activation as a function of decellularisation reagent and tissue origin. The data demonstrated SIS was significantly more pro-inflammatory than dermis. Additionally it was deduced that SDS during decellularisation induced pro-inflammatory changes to dermal materials. Furthermore, it was possible to conclude inter-patient variation in leukocyte response. The in vitro findings were validated in vivo which confirmed the chemiluminescence observations, highlighting the potential for translation of this technique as a

Blood Cadmium Levels and Incident Cardiovascular Events during Follow-up in a Population-Based Cohort of Swedish Adults: The Malmö Diet and Cancer Study

PubMed Central

Barregard, Lars; Sallsten, Gerd; Fagerberg, Björn; Borné, Yan; Persson, Margaretha; Hedblad, Bo; Engström, Gunnar

2015-01-01

é Y, Persson M, Hedblad B, Engström G. 2016. Blood cadmium levels and incident cardiovascular events during follow-up in a population-based cohort of Swedish adults: the Malmö Diet and Cancer Study. Environ Health Perspect 124:594–600; http://dx.doi.org/10.1289/ehp.1509735 PMID:26517380

The Key Role of Nuclear-Spin Astrochemistry

NASA Astrophysics Data System (ADS)

Le Gal, Romane; Herbst, Eric; Xie, Changjian; Guo, Hua; Talbi, Dahbia; Muller, Sebastien; Persson, Carina

2017-06-01

Thanks to the new spectroscopic windows opened by the recent generation of telescopes, a large number of molecular lines have been detected. In particular, nuclear-spin astrochemistry has gained interest owing to numerous ortho-to-para ratio (OPR) measurements for species including H_3^+, CH_2, C_3H_2, H_2O, NH_3, NH_2, H_2S, H_2CS, H_2O^+ and H_2Cl^+. Any multi-hydrogenated species can indeed present different spin configurations, if some of their hydrogen nuclei are identical, and the species thus exist in distinguishable forms, such as ortho and para. In thermal equilibrium, OPRs are only functions of the temperature and since spontaneous conversion between ortho and para states is extremely slow in comparison with typical molecular cloud lifetimes, OPRs were commonly believed to reflect a ``formation temperature''. However, observed OPRs are not always consistent with their thermal equilibrium values, as for the NH_3 and NH_2 cases. It is thus crucial to understand how interstellar OPRs are formed to constrain the information such new probes can provide. This involves a comprehensive analysis of the processes governing the interstellar nuclear-spin chemistry, including the formation and possible conversions of the different spin symmetries both in the gas and solid phases. If well understood, OPRs might afford new powerful astrophysical diagnostics on the chemical and physical conditions of their environments, and in particular could trace their thermal history. In this context, observations of non-thermal values for the OPR of the radical NH_2 toward four high-mass star-forming regions, and a 3:1 value measured for the H_2Cl^+ OPR toward diffuse and denser gas, led us to develop detailed studies of the mechanisms involved in obtaining such OPRs with the aid of quasi-classical trajectory calculations. We will present these new promising results, improving our understanding of the interstellar medium. Persson et al. 2016, A&A, 586, A128, Neufeld et al. 2016, Ap

Purification and characterization of an N alpha-acetyltransferase from Saccharomyces cerevisiae.

PubMed

Lee, F J; Lin, L W; Smith, J A

1988-10-15

N alpha-Acetyltransferase, which catalyzes the transfer of an acetyl group from acetyl coenzyme A to the alpha-NH2 group of proteins and peptides, was isolated from Saccharomyces cerevisiae and demonstrated by protein sequence analysis to be NH2-terminally blocked. The enzyme was purified 4,600-fold to apparent homogeneity by successive purification steps using DEAE-Sepharose, hydroxylapatite, DE52 cellulose, and Affi-Gel blue. The Mr of the native enzyme was estimated to be 180,000 +/- 10,000 by gel filtration chromatography, and the Mr of each subunit was estimated to be 95,000 +/- 2,000 by sodium dodecyl sulfate-polyacrylamide gel electrophoresis. The enzyme has a pH optimum near 9.0, and its pI is 4.3 as determined by chromatofocusing on Mono-P. The enzyme catalyzed the transfer of an acetyl group to various synthetic peptides, including human adrenocorticotropic hormone (ACTH) (1-24) and its [Phe2] analogue, yeast alcohol dehydrogenase I (1-24), yeast alcohol dehydrogenase II (1-24), and human superoxide dismutase (1-24). These peptides contain either Ser or Ala as NH2-terminal residues which together with Met are the most commonly acetylated NH2-terminal residues (Persson, B., Flinta, C., von Heijne, G., and Jornvall, H. (1985) Eur. J. Biochem. 152, 523-527). Yeast enolase, containing a free NH2-terminal Ala residue, is known not to be N alpha-acetylated in vivo (Chin, C. C. Q., Brewer, J. M., and Wold, F. (1981) J. Biol. Chem. 256, 1377-1384), and enolase (1-24), a synthetic peptide mimicking the protein's NH2 terminus, was not acetylated in vitro by yeast acetyltransferase. The enzyme did not catalyze the N alpha-acetylation of other synthetic peptides including ACTH(11-24), ACTH(7-38), ACTH(18-39), human beta-endorphin, yeast superoxide dismutase (1-24). Each of these peptides has an NH2-terminal residue which is rarely acetylated in proteins (Lys, Phe, Arg, Tyr, Val, respectively). Among a series of divalent cations, Cu2+ and Zn2+ were demonstrated to be

Sustainable Seas Student Intertidal Monitoring Project at Duxbury Reef in Bolinas, CA (Invited)

NASA Astrophysics Data System (ADS)

Soave, K.; Dean, A.; Darakananda, K.; Ball, O.; Butti, C.; Yang, G.; Vetter, M.; Grimaldi, Z.

2009-12-01

Sustainable Seas Student Intertidal Monitoring Project at Duxbury Reef in Bolinas, CA Kathy Soave, Amy Dean, Olivia Ball, Karin Darakananda, Matt Vetter, Grant Yang, Charlotte Butti, Zoe Grimaldi The Sustainable Seas Student Monitoring Project at the Branson School in Ross, CA has monitored Duxbury Reef in Bolinas, CA since 1999, in cooperation with the Farallones Marine Sanctuary Association and the Gulf of Farallones National Marine Sanctuary. Goals of the project include: 1) To monitor the rocky intertidal habitat and develop a baseline database of invertebrates and algal density and abundance; 2) To contribute to the conservation of the rocky intertidal habitat through education of students and visitors about intertidal species and the requirements for maintaining a healthy, diverse intertidal ecosystem; 3) To increase stewardship in the Gulf of the Farallones National Marine Sanctuary; and 4) To contribute abundance and population data on key algae and invertebrate species to the national database, LiMPETS (Long Term Monitoring Program & Experiential Training for Students). Student volunteers complete an intensive training course on the natural history of intertidal invertebrates and algae, identification of key species, rocky intertidal monitoring techniques, and history of the sanctuary. Students identify and count key invertebrate and algae species along two permanent transects (A and B) and using randomly determined points within a permanent 100 m2 area, three times per year (fall, winter, and late spring). Using the data collected since 2004, we will analyze the population densities, seasonal abundance and long-term population trends of key algal and invertebrate species. Future analyses and investigations will include intertidal abiotic factors (including water temperature and human foot-traffic) to enhance insights into the workings of the Duxbury Reef ecosystem, in particular, the high intertidal zone which experiences the greatest amount of human

Influence of Urbanicity and County Characteristics on the Association between Ozone and Asthma Emergency Department Visits in North Carolina

PubMed Central

Rappold, Ana G.; Davis, J. Allen; Richardson, David B.; Waller, Anna E.; Luben, Thomas J.

2014-01-01

Background: Air pollution epidemiologic studies, often conducted in large metropolitan areas because of proximity to regulatory monitors, are limited in their ability to examine potential associations between air pollution exposures and health effects in rural locations. Methods: Using a time-stratified case-crossover framework, we examined associations between asthma emergency department (ED) visits in North Carolina (2006–2008), collected by a surveillance system, and short-term ozone (O3) exposures using predicted concentrations from the Community Multiscale Air Quality (CMAQ) model. We estimated associations by county groupings based on four urbanicity classifications (representative of county size and urban proximity) and county health. Results: O3 was associated with asthma ED visits in all-year and warm season (April–October) analyses [odds ratio (OR) = 1.019; 95% CI: 0.998, 1.040; OR = 1.020; 95% CI: 0.997, 1.044, respectively, for a 20-ppb increase in lag 0–2 days O3]. The association was strongest in Less Urbanized counties, with no evidence of a positive association in Rural counties. Associations were similar when adjusted for fine particulate matter in copollutant models. Associations were stronger for children (5–17 years of age) compared with other age groups, and for individuals living in counties identified with poorer health status compared with counties that had the highest health rankings, although estimated associations for these subgroups had larger uncertainty. Conclusions: Associations between short-term O3 exposures and asthma ED visits differed by overall county health and urbanicity, with stronger associations in Less Urbanized counties, and no positive association in Rural counties. Results also suggest that children are at increased risk of O3-related respiratory effects. Citation: Sacks JD, Rappold AG, Davis JA Jr, Richardson DB, Waller AE, Luben TJ. 2014. Influence of urbanicity and county characteristics on the association

Correlated phonons and the Tc-dependent dynamical phonon anomalies

NASA Astrophysics Data System (ADS)

Hakioğlu, T.; Türeci, H.

1997-11-01

Anomalously large low-temperature phonon anharmonicities can lead to static as well as dynamical changes in the low-temperature properties of the electron-phonon system. In this work, we focus our attention on the dynamically generated low-temperature correlations in an interacting electron-phonon system using a self-consistent dynamical approach in the intermediate coupling range. In the context of the model, the polaron correlations are produced by the charge-density fluctuations which are generated dynamically by the electron-phonon coupling. Conversely, the latter is influenced in the presence of the former. The purpose of this work is to examine the dynamics of this dual mechanism between the two using the illustrative Fröhlich model. In particular, the influence of the low-temperature phonon dynamics on the superconducting properties in the intermediate coupling range is investigated. The influence on the Holstein reduction factor as well as the enhancement in the zero-point fluctuations and in the electron-phonon coupling are calculated numerically. We also examine these effects in the presence of superconductivity. Within this model, the contribution of the electron-phonon interaction as one of the important elements in the mechanisms of superconductivity can reach values as high as 15-20% of the characteristic scale of the lattice vibrational energy. The second motivation of this work is to understand the nature of the Tc-dependent temperature anomalies observed in the Debye-Waller factor, dynamical pair correlations, and average atomic vibrational energies for a number of high-temperature superconductors. In our approach we do not claim nor believe that the electron-phonon interaction is the primary mechanism leading to high-temperature superconductivity. Nevertheless, our calculations suggest that the dynamically induced low-temperature phonon correlation model can account for these anomalies and illustrates their possible common origin. Finally, the

Mode coupling theory for nonequilibrium glassy dynamics of thermal self-propelled particles.

PubMed

Feng, Mengkai; Hou, Zhonghuai

2017-06-28

We present a mode coupling theory study for the relaxation and glassy dynamics of a system of strongly interacting self-propelled particles, wherein the self-propulsion force is described by Ornstein-Uhlenbeck colored noise and thermal noises are included. Our starting point is an effective Smoluchowski equation governing the distribution function of particle positions, from which we derive a memory function equation for the time dependence of density fluctuations in nonequilibrium steady states. With the basic assumption of the absence of macroscopic currents and standard mode coupling approximation, we can obtain expressions for the irreducible memory function and other relevant dynamic terms, wherein the nonequilibrium character of the active system is manifested through an averaged diffusion coefficient D[combining macron] and a nontrivial structural function S 2 (q) with q being the magnitude of wave vector q. D[combining macron] and S 2 (q) enter the frequency term and the vertex term for the memory function, and thus influence both the short time and the long time dynamics of the system. With these equations obtained, we study the glassy dynamics of this thermal self-propelled particle system by investigating the Debye-Waller factor f q and relaxation time τ α as functions of the persistence time τ p of self-propulsion, the single particle effective temperature T eff as well as the number density ρ. Consequently, we find the critical density ρ c for given τ p shifts to larger values with increasing magnitude of propulsion force or effective temperature, in good accordance with previously reported simulation work. In addition, the theory facilitates us to study the critical effective temperature T for fixed ρ as well as its dependence on τ p . We find that T increases with τ p and in the limit τ p → 0, it approaches the value for a simple passive Brownian system as expected. Our theory also well recovers the results for passive systems and can be

Molecular beam studies of the growth and kinetics of self-assembled monolayers

NASA Astrophysics Data System (ADS)

Schwartz, Peter Vincent

-adlayer separation distance of about 4 A. Debye-Waller experiments were done to measure the stiffness of monolayers of different chain lengths, coverages and functional groups as well as overlayers.

Experimental and theoretical study of rotationally inelastic diffraction of H{sub 2}(D{sub 2}) from methyl-terminated Si(111)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nihill, Kevin J.; Hund, Zachary M.; Sibener, S. J., E-mail: s-sibener@uchicago.edu

2016-08-28

Fundamental details concerning the interaction between H{sub 2} and CH{sub 3}–Si(111) have been elucidated by the combination of diffractive scattering experiments and electronic structure and scattering calculations. Rotationally inelastic diffraction (RID) of H{sub 2} and D{sub 2} from this model hydrocarbon-decorated semiconductor interface has been confirmed for the first time via both time-of-flight and diffraction measurements, with modest j = 0 → 2 RID intensities for H{sub 2} compared to the strong RID features observed for D{sub 2} over a large range of kinematic scattering conditions along two high-symmetry azimuthal directions. The Debye-Waller model was applied to the thermal attenuationmore » of diffraction peaks, allowing for precise determination of the RID probabilities by accounting for incoherent motion of the CH{sub 3}–Si(111) surface atoms. The probabilities of rotationally inelastic diffraction of H{sub 2} and D{sub 2} have been quantitatively evaluated as a function of beam energy and scattering angle, and have been compared with complementary electronic structure and scattering calculations to provide insight into the interaction potential between H{sub 2} (D{sub 2}) and hence the surface charge density distribution. Specifically, a six-dimensional potential energy surface (PES), describing the electronic structure of the H{sub 2}(D{sub 2})/CH{sub 3}−Si(111) system, has been computed based on interpolation of density functional theory energies. Quantum and classical dynamics simulations have allowed for an assessment of the accuracy of the PES, and subsequently for identification of the features of the PES that serve as classical turning points. A close scrutiny of the PES reveals the highly anisotropic character of the interaction potential at these turning points. This combination of experiment and theory provides new and important details about the interaction of H{sub 2} with a hybrid organic-semiconductor interface, which can

Ridge interaction features of the Line Islands

NASA Astrophysics Data System (ADS)

Konter, J. G.; Koppers, A. A. P.; Storm, L. P.

2016-12-01

The sections of Pacific absolute plate motion history that precede the Hawaii-Emperor and Louisville chains are based on three chains: the Line Islands-Mid-Pacific Mountains, the Hess Rise-Shatsky Rise, and the Marshall Islands-Wake Islands (Rurutu hotspot). Although it has been clear that the Line Islands do not define a simple age progression (e.g. Schlanger et al., 1984), the apparent similarity to the Emperor Seamount geographic trend has been used to extend the overall Hawaii-Emperor track further into the past. However, we show here that plate tectonic reconstructions suggest that the Mid-Pacific Mountains (MPMs) and Line Islands (LIs) were erupted near a mid-ocean ridge, and thus these structures do not reflect absolute plate motion. Moverover, the morphology and geochemistry of the volcanoes show similarities with Pukapuka Ridge (e.g. Davis et al., 2002) and the Rano Rahi seamounts, presumed to have a shallow origin. Modern 40Ar/39Ar ages show that the LIs erupted at various times along the entire volcanic chain. The oldest structures formed within 10 Ma of plate formation. Given the short distance to the ridge system, large aseismic volcanic ridges, such as Necker Ridge and Horizon Guyot may simply reflect a connection between MPMs and the ridge, similar to the Pukapuka Ridge. The Line Islands to the south (including Karin Ridge) define short subchains of elongated seamounts that are widespread, resembling the Rano Rahi seamount field. During this time, the plate moved nearly parallel to the ridge system. The change from few large ridges to many subchains may reflect a change in absolute plate motion, similar to the Rano Rahi field. Here, significant MPMs volcanism is no longer connected to the ridge along plate motion. Similar to Pukapuka vs. Rano Rahi, the difference in direction between plate motion and the closest ridge determines whether larger ridges or smaller seamount subchains are formed. The difference between the largest structures (MPMs and LIs

Festive Nebulas Light Up Milky Way Galaxy Satellite

NASA Image and Video Library

2017-12-08

NASA’s Hubble Space Telescope captured two festive-looking nebulas, situated so as to appear as one. They reside in the Small Magellanic Cloud, a dwarf galaxy that is a satellite of our Milky Way galaxy. Intense radiation from the brilliant central stars is heating hydrogen in each of the nebulas, causing them to glow red. The nebulas, together, are called NGC 248. They were discovered in 1834 by the astronomer Sir John Herschel. NGC 248 is about 60 light-years long and 20 light-years wide. It is among a number of glowing hydrogen nebulas in the dwarf satellite galaxy, which is located approximately 200,000 light-years away in the southern constellation Tucana. The image is part of a study called Small Magellanic Cloud Investigation of Dust and Gas Evolution (SMIDGE). Astronomers are using Hubble to probe the Milky Way satellite to understand how dust is different in galaxies that have a far lower supply of heavy elements needed to create dust. The Small Magellanic Cloud has between a fifth and a tenth of the amount of heavy elements that the Milky Way does. Because it is so close, astronomers can study its dust in great detail, and learn about what dust was like earlier in the history of the universe. “It is important for understanding the history of our own galaxy, too,” explained the study’s principal investigator, Dr. Karin Sandstrom of the University of California, San Diego. Most of the star formation happened earlier in the universe, at a time where there was a much lower percentage of heavy elements than there is now. “Dust is a really critical part of how a galaxy works, how it forms stars,” said Sandstrom. Credit: NASA, ESA, STScI, K. Sandstrom (University of California, San Diego), and the SMIDGE team NASA image use policy. NASA Goddard Space Flight Center enables NASA’s mission through four scientific endeavors: Earth Science, Heliophysics, Solar System Exploration, and Astrophysics. Goddard plays a leading role in NASA’s accomplishments

Social Health Inequalities and eHealth: A Literature Review With Qualitative Synthesis of Theoretical and Empirical Studies.

PubMed

Latulippe, Karine; Hamel, Christine; Giroux, Dominique

2017-04-27

interventions, which are not likely to exacerbate SHI. ©Karine Latulippe, Christine Hamel, Dominique Giroux. Originally published in the Journal of Medical Internet Research (http://www.jmir.org), 27.04.2017.

Lunar and Planetary Science XXXV: Asteroids, Meteors, Comets

NASA Technical Reports Server (NTRS)

2004-01-01

Reports included:Long Term Stability of Mars Trojans; Horseshoe Asteroids and Quasi-satellites in Earth-like Orbits; Effect of Roughness on Visible Reflectance Spectra of Planetary Surface; SUBARU Spectroscopy of Asteroid (832) Karin; Determining Time Scale of Space Weathering; Change of Asteroid Reflectance Spectra by Space Weathering: Pulse Laser Irradiation on Meteorite Samples; Reflectance Spectra of CM2 Chondrite Mighei Irradiated with Pulsed Laser and Implications for Low-Albedo Asteroids and Martian Moons; Meteorite Porosities and Densities: A Review of Trends in the Data; Small Craters in the Inner Solar System: Primaries or Secondaries or Both?; Generation of an Ordinary-Chondrite Regolith by Repetitive Impact; Asteroid Modal Mineralogy Using Hapke Mixing Models: Validation with HED Meteorites; Particle Size Effect in X-Ray Fluorescence at a Large Phase Angle: Importance on Elemental Analysis of Asteroid Eros (433); An Investigation into Solar Wind Depletion of Sulfur in Troilite; Photometric Behaviour Dependent on Solar Phase Angle and Physical Characteristics of Binary Near-Earth-Asteroid (65803) 1996 GT; Spectroscopic Observations of Asteroid 4 Vesta from 1.9 to 3.5 micron: Evidence of Hydrated and/or Hydroxylated Minerals; Multi-Wavelength Observations of Asteroid 2100 Ra-Shalom: Visible, Infrared, and Thermal Spectroscopy Results; New Peculiarities of Cometary Outburst Activity; Preliminary Shape Modeling for the Asteroid (25143) Itokawa, AMICA of Hayabusa Mission; Scientific Capability of MINERVA Rover in Hayabusa Asteroid Mission; Characteristics and Current Status of Near Infrared Spectrometer for Hayabusa Mission; Sampling Strategy and Curation Plan of Hayabusa Asteroid Sample Return Mission; Visible/Near-Infrared Spectral Properties of MUSES C Target Asteroid 25143 Itokawa; Calibration of the NEAR XRS Solar Monitor; Modeling Mosaic Degradation of X-Ray Measurements of 433 Eros by NEAR-Shoemaker; Scattered Light Remediation and Recalibration of

Electron density determination and bonding in tetragonal binary intermetallics by convergent beam electron diffraction

NASA Astrophysics Data System (ADS)

Sang, Xiahan

Intermetallics offer unique property combinations often superior to those of more conventional solid solution alloys of identical composition. Understanding of bonding in intermetallics would greatly accelerate development of intermetallics for advanced and high performance engineering applications. Tetragonal intermetallics L10 ordered TiAl, FePd and FePt are used as model systems to experimentally measure their electron densities using quantitative convergent beam electron diffraction (QCBED) method and then compare details of the 3d-4d (FePd) and 3d-5d (FePt) electron interactions to elucidate their role on properties of the respective ferromagnetic L10-ordered intermetallics FePd and FePt. A new multi-beam off-zone axis condition QCBED method has been developed to increase sensitivity of CBED patterns to change of structure factors and the anisotropic Debye-Waller (DW) factors. Unprecedented accuracy and precision in structure and DW factor measurements has been achieved by acquiring CBED patterns using beam-sample geometry that ensures strong dynamical interaction between the fast electrons and the periodic potential in the crystalline samples. This experimental method has been successfully applied to diamond cubic Si, and chemically ordered B2 cubic NiAl, tetragonal L10 ordered TiAl and FePd. The accurate and precise experimental DW and structure factors for L10 TiAl and FePd allow direct evaluation of computer calculations using the current state of the art density functional theory (DFT) based electron structure modeling. The experimental electron density difference map of L1 0 TiAl shows that the DFT calculations describe bonding to a sufficient accuracy for s- and p- electrons interaction, e. g., the Al-layer. However, it indicate significant quantitative differences to the experimental measurements for the 3d-3d interactions of the Ti atoms, e.g. in the Ti layers. The DFT calculations for L10 FePd also show that the current DFT approximations

River Bookends: Headwaters, Delta and the Volumes of Stories in Between

NASA Astrophysics Data System (ADS)

Waller, J. L.; Brey, J. A.

2016-12-01

As professors of art and earth science, we were often pleased when our students found that integrating lessons of geoscience with art rewarded them in impactful and memorable ways. Inspired by student success and our very real concern for natural and human caused threats to treasured cities and areas on the globe, we produced "Layers: Places in Peril", a gallery exhibition of paintings and scientific explanation essays. We found the combination of art and earth science was a powerful tool that touched and informed a wide and diverse population beyond classrooms. Acutely aware that current crises facing Earth are not limited to gigantic forces, we then produced "small problems, BIG TROUBLE" that addressed how seemingly small problems lead to far-reaching threats. Our conversation expanded to include twenty other scientists from geoscience, biology, physics and chemistry whose science-based essays paired with Waller's paintings. In our newest presentation in production, River Bookends: Headwaters, Delta and the Volumes of Stories in Between, we address art and geo-cultural connections associated with World rivers. Our exploration is focused on rivers as markers of time, culture and identity, yet, the importance of stressing the geoscience in this exhibition is large, indeed. An understanding of geomorphology and river ecology and of the historical changes, both natural and human-engineered which may dramatically give rise to, enrich, distress, or ultimately destroy human settlements and culture, are essential to our intended emphases in the show. In this session, we will describe these exhibitions, show images of the work and discuss some of the gallery activities that resulted from the shows, which included a discussion panel of social science and humanities faculty focused on the exhibition topics. We will describe how local high school art and science students answered our invitation to create a parallel exhibition of our show premise, concurrently exhibited in an

Associations between Source-Specific Fine Particulate Matter and Emergency Department Visits for Respiratory Disease in Four U.S. Cities

PubMed Central

Krall, Jenna R.; Mulholland, James A.; Russell, Armistead G.; Balachandran, Sivaraman; Winquist, Andrea; Tolbert, Paige E.; Waller, Lance A.; Sarnat, Stefanie Ebelt

2016-01-01

Background: Short-term exposure to ambient fine particulate matter (PM2.5) concentrations has been associated with increased mortality and morbidity. Determining which sources of PM2.5 are most toxic can help guide targeted reduction of PM2.5. However, conducting multicity epidemiologic studies of sources is difficult because source-specific PM2.5 is not directly measured, and source chemical compositions can vary between cities. Objectives: We determined how the chemical composition of primary ambient PM2.5 sources varies across cities. We estimated associations between source-specific PM2.5 and respiratory disease emergency department (ED) visits and examined between-city heterogeneity in estimated associations. Methods: We used source apportionment to estimate daily concentrations of primary source-specific PM2.5 for four U.S. cities. For sources with similar chemical compositions between cities, we applied Poisson time-series regression models to estimate associations between source-specific PM2.5 and respiratory disease ED visits. Results: We found that PM2.5 from biomass burning, diesel vehicle, gasoline vehicle, and dust sources was similar in chemical composition between cities, but PM2.5 from coal combustion and metal sources varied across cities. We found some evidence of positive associations of respiratory disease ED visits with biomass burning PM2.5; associations with diesel and gasoline PM2.5 were frequently imprecise or consistent with the null. We found little evidence of associations with dust PM2.5. Conclusions: We introduced an approach for comparing the chemical compositions of PM2.5 sources across cities and conducted one of the first multicity studies of source-specific PM2.5 and ED visits. Across four U.S. cities, among the primary PM2.5 sources assessed, biomass burning PM2.5 was most strongly associated with respiratory health. Citation: Krall JR, Mulholland JA, Russell AG, Balachandran S, Winquist A, Tolbert PE, Waller LA, Sarnat SE. 2017

How electricity was discovered and how it is related to cardiology.

PubMed

de Micheli-Serra, Alfredo; Iturralde-Torres, Pedro; Izaguirre-Ávila, Raúl

2012-01-01

We relate the fundamental stages of the long road leading to the discovery of electricity and its uses in cardiology. The first observations on the electromagnetic phenomena were registered in ancient texts; many Greek and Roman writers referred to them, although they provided no explanations. The first extant treatise dates back to the XIII century and was written by Pierre de Maricourt during the siege of Lucera, Italy, by the army of Charles of Anjou, French king of Naples. There were no significant advances in the field of magnetism between the appearance of this treatise and the publication of the study De magnete magneticisque corporibus (1600) by the English physician William Gilbert. Scientists became increasingly interested in electromagnetic phenomena occurring in certain fish, i.e., the so-called electric ray that lived in the South American seas and the Torpedo fish that roamed the Mediterranean Sea. This interest increased in the 18th century, when condenser devices such as the Leyden jar were explored. It was subsequently demonstrated that the discharges produced by "electric fish" were of the same nature as those produced in this device. The famous "controversy" relating to animal electricity or electricity inherent to an animal's body also arose in the second half of the 18th century. The school of thought of the physicist Volta sustained the principle of a single electrical action generated by metallic contact. This led Volta to invent his electric pile, considered as the first wet cell battery. Toward the middle of the XIX century, the disciples of the physiologist Galvani were able to demonstrate the existence of animal electricity through experiments exploring the so-called current of injury. On the path of Volta's approach, many characteristics of electricity were detailed, which ultimately led to their usage in the industrial field. The route followed by Galvani-Nobili-Matteucci led to the successes of Waller, Einthoven, etcetera, enabling the

Associations between Source-Specific Fine Particulate Matter and Emergency Department Visits for Respiratory Disease in Four U.S. Cities.

PubMed

Krall, Jenna R; Mulholland, James A; Russell, Armistead G; Balachandran, Sivaraman; Winquist, Andrea; Tolbert, Paige E; Waller, Lance A; Sarnat, Stefanie Ebelt

2017-01-01

Short-term exposure to ambient fine particulate matter (PM2.5) concentrations has been associated with increased mortality and morbidity. Determining which sources of PM2.5 are most toxic can help guide targeted reduction of PM2.5. However, conducting multicity epidemiologic studies of sources is difficult because source-specific PM2.5 is not directly measured, and source chemical compositions can vary between cities. We determined how the chemical composition of primary ambient PM2.5 sources varies across cities. We estimated associations between source-specific PM2.5 and respiratory disease emergency department (ED) visits and examined between-city heterogeneity in estimated associations. We used source apportionment to estimate daily concentrations of primary source-specific PM2.5 for four U.S. cities. For sources with similar chemical compositions between cities, we applied Poisson time-series regression models to estimate associations between source-specific PM2.5 and respiratory disease ED visits. We found that PM2.5 from biomass burning, diesel vehicle, gasoline vehicle, and dust sources was similar in chemical composition between cities, but PM2.5 from coal combustion and metal sources varied across cities. We found some evidence of positive associations of respiratory disease ED visits with biomass burning PM2.5; associations with diesel and gasoline PM2.5 were frequently imprecise or consistent with the null. We found little evidence of associations with dust PM2.5. We introduced an approach for comparing the chemical compositions of PM2.5 sources across cities and conducted one of the first multicity studies of source-specific PM2.5 and ED visits. Across four U.S. cities, among the primary PM2.5 sources assessed, biomass burning PM2.5 was most strongly associated with respiratory health. Citation: Krall JR, Mulholland JA, Russell AG, Balachandran S, Winquist A, Tolbert PE, Waller LA, Sarnat SE. 2017. Associations between source-specific fine particulate

Investigating the interfacial dynamics of thin films

NASA Astrophysics Data System (ADS)

Rosenbaum, Aaron W.

surface specific nature of helium atom scattering allows for a deft study of the relationship between surface motion and the glass transition temperature. An added parameter in this complex organic system is the film thickness. The confinement effects and enhanced surface displacement were examined as a function of the thermal attenuation of both inelastic and elastic helium atom scattering. The Debye-Waller factor for these thin films of PMMA is similar to the low-density alkanethiol self-assembled monolayers discussed earlier.

Taking centre stage...

NASA Astrophysics Data System (ADS)

1998-11-01

HAMLET (Highly Automated Multimedia Light Enhanced Theatre) was the star performance at the recent finals of the `Young Engineer for Britain' competition, held at the Commonwealth Institute in London. This state-of-the-art computer-controlled theatre lighting system won the title `Young Engineers for Britain 1998' for David Kelnar, Jonathan Scott, Ramsay Waller and John Wyllie (all aged 16) from Merchiston Castle School, Edinburgh. HAMLET replaces conventional manually-operated controls with a special computer program, and should find use in the thousands of small theatres, schools and amateur drama productions that operate with limited resources and without specialist expertise. The four students received a £2500 prize between them, along with £2500 for their school, and in addition they were invited to spend a special day with the Royal Engineers. A project designed to improve car locking systems enabled Ian Robinson of Durham University to take the `Working in industry award' worth £1000. He was also given the opportunity of a day at sea with the Royal Navy. Other prizewinners with their projects included: Jun Baba of Bloxham School, Banbury (a cardboard armchair which converts into a desk and chair); Kobika Sritharan and Gemma Hancock, Bancroft's School, Essex (a rain warning system for a washing line); and Alistair Clarke, Sam James and Ruth Jenkins, Bishop of Llandaff High School, Cardiff (a mechanism to open and close the retractable roof of the Millennium Stadium in Cardiff). The two principal national sponsors of the competition, which is organized by the Engineering Council, are Lloyd's Register and GEC. Industrial companies, professional engineering institutions and educational bodies also provided national and regional prizes and support. During this year's finals, various additional activities took place, allowing the students to surf the Internet and navigate individual engineering websites on a network of computers. They also visited the

Tektite 1, man-in-the-sea project: Marine Science Program

USGS Publications Warehouse

Clifton, H.E.; Mahnken, C.V.W.; Van Derwalker, J. C.; Waller, R.A.

1970-01-01

The Tektite experiment was designed to provide data for a number of behavioral, biomedical, and engineering studies in addition to the marine sciences program. Conditions for some of these studies were not altogether compatible with the program for the marine sciences. For example, isolation imposed by human behavioral studies precluded physical contact with the surface team, even though such contact was physically possible and desirable for the conduct of the marine sciences program. Isolation also imposed on the scientific team the duty of all in-habitat maintenance, both scheduled and unscheduled, thereby taking substantial time from scientific research. In addition, between 10 and 20 percent of the waking time was devoted to performance of psychological tests required for the biomedical studies. Most of the experiments were directed toward detecting potentially adverse changes and thus were accepted as necessary and desirable. The only health problem to affect the scientific program during the dive was a minor external ear infection contracted by all the divers. Nonetheless, the experiment demon. strated, at least to our satisfaction, the advantages of underwater habitation and saturation diving for biological and geological research. A major advantage is the opportunity for continuous monitoring of organisms or processes. In addition, underwater habitation provides for considerably more research time in the water than surface diving or intermittent bottom dwelling, and this advantage increases greatly as the depth of habitation increases. Even in the relatively shallow depths at which Tektite 1 was conducted, the undersea team could spend appreciably more time at work in the water than their colleagues on the surface. Finally, Tektite 1 demonstrated that the scientist who lives in the sea need not have the extensive qualifications of a professional diver. Of the four scientists of the in-habitat team, only Crew Chief Waller was so qualified; the other three

New medicines in primary care: a review of influences on general practitioner prescribing.

PubMed

Mason, A

2008-02-01

The uptake of new medicines is slower in the UK than in many other countries. Previous research found that cost and price have little influence on general practitioner (GP) behaviour, but recent UK government policy may have heightened cost-consciousness. Focussing on new medicines, this review aimed to explore the determinants of uptake, the causes of geographical variations, and the influence of price, cost and financial incentives on prescribing behaviour. Two separate searches were conducted on nine electronic databases. Strategy 1, an update of a previous review, used key terms for primary care physicians, uptake, medicines and 'new'. Strategy 2 focussed on terms relating to incentives and prescribing. Records were screened for eligibility and data from relevant papers were extracted using Bonair and Persson's typology for determinants of the diffusion of innovation, which classified influences into three groups: actors, structural/environmental characteristics and product characteristics. The searches identified 550 records and 28 studies were included in the updated review. Prescribing of new medicines needs to be understood in the context of individual patient-centred care, which is characterized by stability and continuity. Hospital doctors, pharmaceutical representatives and prescribing advisers are all influential, but GP attitudes towards these actors vary and there are notable differences between high and low prescribers of new pharmaceuticals. Support systems can help provide appropriate guidance and increase the uptake of new medicines by identifying patients who may benefit from pharmaceutical therapy. There is evidence of a shift in GP attitudes towards central policy initiatives, with doctors slowly accepting the need for external scrutiny and national standards. Although cost does appear to inform prescribing decisions, it is typically of lower importance than both safety and efficacy concerns and does not represent a significant barrier to

Polar winter cloud depolarization measurements with the CANDAC Rayleigh-Mie-Raman Lidar

NASA Astrophysics Data System (ADS)

McCullough, E. M.; Nott, G. J.; Duck, T. J.; Sica, R. J.; Doyle, J. G.; Pike-thackray, C.; Drummond, J. R.

2011-12-01

), Evidence of liquid dependent ice nucleation in high-latitude stratiform clouds from surface remote sensors, Geophysical Research Letters, 38, L01803. Ebert, EE and J.A .Curry (1992), A parameterization of ice cloud optical properties for climate models, Journal of Geophysical Research 97:3831-3836. Intrieri JM, Fairall CW, Shupe MD, Persson POG, Andreas EL, Guest PS, Moritz RE. 2002. An annual cycle of Arctic surface cloud forcing at SHEBA. Journal of Geophysical Research 107 NO. C10, 8039 . Noel, V., H. Chepfer, M. Haeffelin, and Y. Morille (2006), Classification of ice crystal shapes in midlatitude ice clouds from three years of lidar observations over the SIRTA observatory. Journal of the Atmospheric Sciences, 63:2978 - 2991.

On Hilbert-Huang Transform Based Synthesis of a Signal Contaminated by Radio Frequency Interference or Fringes

NASA Technical Reports Server (NTRS)

Kizhner, Semion; Shiri, Ron S.; Vootukuru, Meg; Coletti, Alessandro

2015-01-01

Norden E. Huang et al. had proposed and published the Hilbert-Huang Transform (HHT) concept correspondently in 1996, 1998. The HHT is a novel method for adaptive spectral analysis of non-linear and non-stationary signals. The HHT comprises two components: - the Huang Empirical Mode Decomposition (EMD), resulting in an adaptive data-derived basis of Intrinsic Mode functions (IMFs), and the Hilbert Spectral Analysis (HSA1) based on the Hilbert Transform for 1-dimension (1D) applied to the EMD IMF's outcome. Although paper describes the HHT concept in great depth, it does not contain all needed methodology to implement the HHT computer code. In 2004, Semion Kizhner and Karin Blank implemented the reference digital HHT real-time data processing system for 1D (HHT-DPS Version 1.4). The case for 2-Dimension (2D) (HHT2) proved to be difficult due to the computational complexity of EMD for 2D (EMD2) and absence of a suitable Hilbert Transform for 2D spectral analysis (HSA2). The real-time EMD2 and HSA2 comprise the real-time HHT2. Kizhner completed the real-time EMD2 and the HSA2 reference digital implementations respectively in 2013 & 2014. Still, the HHT2 outcome synthesis remains an active research area. This paper presents the initial concepts and preliminary results of HHT2-based synthesis and its application to processing of signals contaminated by Radio-Frequency Interference (RFI), as well as optical systems' fringe detection and mitigation at design stage. The Soil Moisture Active Passive (SMAP mission (SMAP) carries a radiometer instrument that measures Earth soil moisture at L1 frequency (1.4 GHz polarimetric - H, V, 3rd and 4th Stokes parameters). There is abundant RFI at L1 and because soil moisture is a strategic parameter, it is important to be able to recover the RFI-contaminated measurement samples (15% of telemetry). State-of-the-art only allows RFI detection and removes RFI-contaminated measurements. The HHT-based analysis and synthesis facilitates

"Wish You Were Here": Examining Characteristics, Outcomes, and Statistical Solutions for Missing Cases in Web-Based Psychotherapeutic Trials.

PubMed

Karin, Eyal; Dear, Blake F; Heller, Gillian Z; Crane, Monique F; Titov, Nickolai

2018-04-19

likelihood and jointly predict lesser clinical improvement. Under such circumstances, individuals with potentially worst off treatment outcomes can become concealed, and failure to adjust for this can lead to substantial clinical measurement bias. Together, this preliminary research suggests that missing cases in Web-based psychotherapeutic interventions may not occur as random events and can be systematically predicted. Critically, at the same time, missing cases may experience outcomes that are distinct and important for a complete understanding of the treatment effect. ©Eyal Karin, Blake F Dear, Gillian Z Heller, Monique F Crane, Nickolai Titov. Originally published in JMIR Mental Health (http://mental.jmir.org), 19.04.2018.

Novel approaches to control of parasites—a workshop.

PubMed

Waller, P J; Thamsborg, S M; Larsen, M; Knox, M R; Peter, R; Miller, J E; Molento, M B; Beriajaya; Hood, G M

2004-10-28

With the advent of helminth parasite populations that have developed resistance to anthelmintics over the last decade or so, especially in small ruminants, sustainable productivity has been threatened. This workshop on novel approaches to control was held at the 19th International Conference of the World Association for the Advancement of Veterinary Parasitology (WAAVP) at New Orleans,LA, USA, during 10–14 August 2003. The workshop was organized and chaired by J.E. Miller and P.J. Waller. Novel or alternative approaches to control have been the focus of research (basic and applied) in many parts of the world. The objective of the workshop was to discuss where we have been and what direction(s) appears to be viable for both the short and long term future. In the long term, all represented regions at the workshop have promulgated programs where breeding for resistance may be the best approach as genes for resistance can be fixed in host populations. However,it does take many years to achieve results and the question of tradeoff concerning alteration of production traits needs further evaluation. Vaccination, especially against Haemonchus contortus,has been a thrust of laboratories in Scotland and Australia where natural “hidden gut” antigens have shown promise, but recombinant products have yet to be developed. In Europe, North and South America, Australia, South Africa and Asia, biocontrol using the nematode-trapping fungus Duddingtonia flagrans has been shown to be effective under experimental conditions, but some field evaluations have been disappointing. Most recently, the FAMACHA system was developed in South Africa. This system is directly and immediately applicable to all regions where H. contortus is a problem. Although not a new or novel approach, copper-oxide wire particles have been revived as a means to control H. contortus.Work being done in Europe, North and South America,South Africa and Australia have shown very encouraging results and can

Theoretical Studies of the Structure and the Dynamics on Clean and Chemisorbed Metal Surfaces

NASA Astrophysics Data System (ADS)

Yang, Liqiu

) surfaces, it is concluded that a substrate missing-row type reconstruction is induced by the adsorbates, but the local symmetry is C_{2v} with oxygen atoms at the long-bridge sites for the former and C_{s} with (110) being the only symmetry axis for the latter. In the above theoretical analysis, close contacts are made to many available experimental results such as surface phonon dispersion curves, interlayer relaxations, and Debye -Waller factors and adsorbate-substrate bond lengths.

Efficiency of preventive actions for landslides and flooding - evaluation of Scandinavian practices

NASA Astrophysics Data System (ADS)

Bergman, R.; Andersson-sköld, Y. B.; Nyberg, L.; Johansson, M.; Persson, E.

2011-12-01

Author: Ramona Bergman, Yvonne Andersson-Sköld, Lars Nyberg, Magnus Johansson, Erik Persson Preventive actions can be, and are frequently, taken to reduce accidents and their consequences in different ways. The MSB funded research programme "Effects of Society's Security actions" (ESS, 2009-2013) aims to study the relationship between such actions and their effects. The program is divided into three subgroups: Frequent accidents Natural hazards (such as flooding, erosion and landslide) Chemical and landfill accidents The results presented here covers natural hazards with focus on land slides and flooding. The results are based on Swedish/Scandinavian contexts. Natural events such as erosion, flooding and land slides are common, but the number of accidents (events causing severe negative impact) is rare. Therefore, in such analysis there is limited data and other information available which can be used for example in statistical analysis of actions and their effects. Instead, the analysis must be based on other information. Therefore, the analysis may have to include aspects that only can be assessed by scenario and "what-if" analyses. In this project the main method has been interviews with officials in Swedish municipalities and national agencies in Sweden and Norway. The two levels are chosen since policies are taken on national (or international) level, while the key actions and actors are on the municipal level. The interviews cover experiences and potential scenarios. In all municipalities, one politician and officials working with planning and rescue service have been interviewed. The study covers hazard and risk mapping, follow up of such maps, physical planning and lessons learned from previous events and activities. The final outcome of the research will be a review of what is found to be well functioning, identification of weak points and recommendations for the management of landslides, erosion and flooding. The present results indicate that hazard

Obituary: Einar A. Tandberg-Hanssen (1921-2011)

NASA Astrophysics Data System (ADS)

Gary, G.; Emslie, A.; Hathaway, David; Moore, Ronald

2011-12-01

Dr. Einar Andreas Tandberg-Hanssen was born on 6 August 1921, in Bergen, Norway, and died on July 22, 2011, in Huntsville, AL, USA, due to complications from ALS (Amyotrophic lateral sclerosis, often referred to as Lou Gehrig's disease). His parents were administrator Birger Tandberg-Hanssen (1883-1951) and secretary Antonie "Mona" Meier (1895-1967). He married Erna Rönning (27 October 1921 - 22 November 1994), a nurse, on 22 June 1951. She was the daughter of Captain Einar Rönning (1890-1969) and Borghild Lyshaug (1897-1980). Einar and Erna had two daughters, Else Biesman (and husband Allen of Rapid City, SD, USA) and Karin Brock (and husband Mike of Gulf Shores, AL, USA). At the time of his death Einar had eight grandchildren and eight great-grandchildren. Dr. Tandberg-Hanssen was an internationally-known member of the solar physics community, with over a hundred published scientific papers and several books, including Solar Activity (1967), Solar Prominences (1974), The Physics of Solar Flares (1988) and The Nature of Solar Prominences (1995). Einar grew up in Langesund and Skien, Norway, where he took the qualifying exams at Skien High School in 1941. After the war he studied natural sciences at the University of Oslo and received his undergraduate degree in astronomy in 1950. He worked as a research assistant in the Institute of Theoretical Astrophysics at the University of Oslo for three intervals in the 1950s, interspersed by fellowships at the Institut d'Astrophysique in Paris, Caltech in Pasadena, CA, the High Altitude Observatory in Boulder, CO, and the Cavendish Laboratory in the UK (at the invitation of British radio-astronomer Sir Martin Ryle). He earned a doctorate in astrophysics at the University in Oslo in 1960 with a dissertation titled "An Investigation of the Temperature Conditions in Prominences with a Special Study of the Excitation of Helium." From 1959-61, Tandberg-Hanssen was a professor at the University in Oslo. He then traveled back to

Adherence to Report and Patient Perception of an Interactive App for Managing Symptoms During Radiotherapy for Prostate Cancer: Descriptive Study of Logged and Interview Data.

PubMed

Langius-Eklöf, Ann; Christiansen, Mats; Lindström, Veronica; Blomberg, Karin; Hälleberg Nyman, Maria; Wengström, Yvonne; Sundberg, Kay

2017-10-31

a sense of security. Few technological problems were reported. The use of Interaktor increased patients' sense of security and their reflections on their own well-being and thereby served as a supportive tool for the self-management of symptoms during treatment of prostate cancer. Some further development of the app's content might be beneficial for future use. ©Ann Langius-Eklöf, Mats Christiansen, Veronica Lindström, Karin Blomberg, Maria Hälleberg Nyman, Yvonne Wengström, Kay Sundberg. Originally published in JMIR Cancer (http://cancer.jmir.org), 31.10.2017.

Universal Versus Conditional Third Day Follow-Up Visit for Children With Nonsevere Unclassified Fever at the Community Level in Ethiopia: Protocol for a Cluster Randomized Noninferiority Trial.

PubMed

Källander, Karin; Alfven, Tobias; Workineh, Ayalkibet Abebe; Hailemariam, Abreham; Petzold, Max; Getachew, Dawit; Barat, Lawrence; Steinhardt, Laura C; Gutman, Julie R

2018-04-12

persistent fever, using a cluster randomized controlled trial design embedded in a national program. Outcomes will be relevant for policy makers and are important for the evaluation of current and future World Health Organization guidelines for the management of children with fever. ClinicalTrials.gov NCT02926625; https://clinicaltrials.gov/ct2/show/NCT02926625 (Archived by WebCite at http://www.webcitation.org/6xrQWn50t). ©Karin Källander, Tobias Alfven, Ayalkibet Abebe Workineh, Abreham Hailemariam,, Max Petzold, Dawit Getachew, Lawrence Barat, Laura C Steinhardt, Julie R Gutman. Originally published in JMIR Research Protocols (http://www.researchprotocols.org), 12.04.2018.

Biological soil crusts in Chile along the precipitation gradient

NASA Astrophysics Data System (ADS)

Samolov, Elena; Glaser, Karin; Baumann, Karen; Leinweber, Peter; Jung, Patrick; Büdel, Burkhard; Mikhailyuk, Tatiana; Karsten, Ulf

2017-04-01

Biological soil crusts in Chile along a precipitation gradient Elena Samolov* (1), Karin Glaser (1), Karen Baumann (2), Peter Leinweber (2), Patrick Jung (3), Burkhard Büdel (3), Tatiana Mikhailyuk (4) and Ulf Karsten (1) (1) Institute of Biological Sciences - Applied Ecology and Phycology, University of Rostock, Rostock, Germany, (2) Faculty of Agricultural and Environmental Sciences - Soil Sciences, University of Rostock, Rostock, Germany (3) University of Kaiserslautern, Kaiserslautern, Germany (4) M.H. Kholodny Institute of Botany, National Academy of Science of Ukraine, Kyiv, Ukraine * elena.samolov@uni-rostock.de Biological soil crusts (BSCs) are an association of different microorganisms and soil particles in the top millimeters of the soil. They are formed by algae, cyanobacteria, microfungi, bacteria, bryophytes and lichens in various compositions; together with their by-products they create a micro-ecosystem that performs important ecological functions, e.g. primary production, nitrogen fixation, mineralization and stabilization of soils. These top-soil assemblages are almost unstudied in South America (Büdel et al. 2016). Therefore, our aim is to investigate for the first time biodiversity of the key photosynthetic organisms, green algae and cyanobacteria following a precipitation gradient along the west coast of Chile. We are applying polyphasic approach - a combination of microscopy, culture dependent (16S and 18S rRNA, ITS) and culture independent molecular techniques (NGS). First results, based on culturing and light microscopy, showed high diversity of eukaryotic algae in biocrusts from humid regions, followed by semi-arid regions. Lichen dominated biocrusts from arid regions were characterized by a high diversity of green algae, while cyanobacteria were scarcely present. The functional role of the BSCs in the biogeochemical cycle of phosphorous (P) was evaluated using state of the art analytical methods including 31P-NMR (nuclear magnetic

Factors affecting the uptake of new medicines in secondary care - a literature review.

PubMed

Chauhan, D; Mason, A

2008-08-01

The rate of uptake of new medicines in the UK is slower than in many other OECD countries. The majority of new medicines are introduced initially in secondary care and prescribed by specialists. However, the reasons for relatively low precribing levels are poorly understood. This review explores the determinants of uptake of new medicines in secondary care. Nine electronic databases were searched covering the period 1992-2006. Once the searches had been run, records were downloaded and those which evaluated uptake of new medicines in secondary care were identified. UK studies were of primary interest, although research conducted in other countries was also reviewed if relevant. With the exception of 'think pieces', eligibility was not limited by study design. Studies published in languages other than English were excluded from the review. Determinants of uptake in secondary care were classified using Bonair and Persson's typology for determinants of the diffusion of innovation. Almost 1400 records were screened for eligibility, and 29 studies were included in the review. Prescribing of new medicines in secondary care was found to be subject to a number of interacting influences. The support structures which exist within secondary care facilitate access to other colleagues and shape prescribing practices. Clinical trial investigators and physicians who sit on decision-making bodies such as Drug and Therapeutic Committees (DTCs) appear to have a special influence due to their proximity to their research and understanding of evidence base. Pharmaceutical representatives may also influence prescribing decisions through funding of meetings and academic detailing, but clinicians are wary of potential bias. Little evidence on the influence of patients upon prescribing decisions was identified. The impact of clinical guidelines has been variable. Some guidelines have significantly increased the uptake of new medicines, but others have had little discernible impact despite

Raman Spectroscopy and Structure of MgSiO3 High Temperature C2/c Clinoenstatite

NASA Astrophysics Data System (ADS)

Kusu, R.; Yoshiasa, A.; Nishiyama, T.; Akihiko, N.; Maki, O.; Hiroshi, A.; Sugiyama, K.

2014-12-01

The high-temperature clinoenstatite (HT-CEn) is one of the important MgSiO3 pyroxene polymorph. The single-crystal of C2/c HT-CEn endmember is firstly synthesized by rapid pressure-temperature quenching from 15-16 GPa and 900-1900 °C [1]. No report that it is produced as single crystal or large domain had been made on the MgSiO3 endmember. The HT-CEn-type modifications were observed in Ca-poor Mg-Fe clinoenstatite and pigeonite and are always found to be unquenchable in rapid cooling. The high pressure and high temperature experiments of MgSiO3 composition were carried out with a Kawai-type multi-anvil apparatus. The samples were quenched by rapidly releasing the oil pressure load and/or by blow out of anvil cell gasket. The space group of C2/c is strictly determined by Rigaku RAPID Weissenberg photographs and synchrotron radiation. HT-CEn and HP-CEn have the greatly different beta angles of 109° and 101°, respectively. Raman spectra of HT-CEn and OEn single crystals were collected at ambient conditions. The unusual bonding distances frozen in the metastable structure. The observed average Mg1-O and Si-O distances in HT-CEn [1.997 and 1.620 Å, respectively] are shorter than those in HP-CEn at 7.9GPa. The average Mg2-O distance in HT-CEn [2.311 Å] is significantly longer than that in L-CEn, providing an abnormal larger distance for the Mg2 atom. The Mg2 polyhedron in HT-CEn is more irregular than that in HP-CEn. The Debye-Waller factor of atoms in HT-CEn have abnormally larger amplitude. The static irregularity of the atomic displacement caused by the transition is frozen in the metastable state. Almost all Raman peaks are broad owing to the large statistical positional arrangement of atoms in HT-CEn. The braod patterns have the common feature which were obserbed by the high temperature Raman spectroscopy for pyroxene. The peaks have been confirmed at 108, 259, 684, and 1097 cm-1. Peak positions for HT-CEn are different from those for protoenstatite under high

Fast and anisotropic flexibility-rigidity index for protein flexibility and fluctuation analysis

NASA Astrophysics Data System (ADS)

Opron, Kristopher; Xia, Kelin; Wei, Guo-Wei

2014-06-01

Protein structural fluctuation, typically measured by Debye-Waller factors, or B-factors, is a manifestation of protein flexibility, which strongly correlates to protein function. The flexibility-rigidity index (FRI) is a newly proposed method for the construction of atomic rigidity functions required in the theory of continuum elasticity with atomic rigidity, which is a new multiscale formalism for describing excessively large biomolecular systems. The FRI method analyzes protein rigidity and flexibility and is capable of predicting protein B-factors without resorting to matrix diagonalization. A fundamental assumption used in the FRI is that protein structures are uniquely determined by various internal and external interactions, while the protein functions, such as stability and flexibility, are solely determined by the structure. As such, one can predict protein flexibility without resorting to the protein interaction Hamiltonian. Consequently, bypassing the matrix diagonalization, the original FRI has a computational complexity of O(N^2). This work introduces a fast FRI (fFRI) algorithm for the flexibility analysis of large macromolecules. The proposed fFRI further reduces the computational complexity to O(N). Additionally, we propose anisotropic FRI (aFRI) algorithms for the analysis of protein collective dynamics. The aFRI algorithms permit adaptive Hessian matrices, from a completely global 3N × 3N matrix to completely local 3 × 3 matrices. These 3 × 3 matrices, despite being calculated locally, also contain non-local correlation information. Eigenvectors obtained from the proposed aFRI algorithms are able to demonstrate collective motions. Moreover, we investigate the performance of FRI by employing four families of radial basis correlation functions. Both parameter optimized and parameter-free FRI methods are explored. Furthermore, we compare the accuracy and efficiency of FRI with some established approaches to flexibility analysis, namely, normal

Fast and anisotropic flexibility-rigidity index for protein flexibility and fluctuation analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Opron, Kristopher; Xia, Kelin; Wei, Guo-Wei, E-mail: wei@math.msu.edu

Protein structural fluctuation, typically measured by Debye-Waller factors, or B-factors, is a manifestation of protein flexibility, which strongly correlates to protein function. The flexibility-rigidity index (FRI) is a newly proposed method for the construction of atomic rigidity functions required in the theory of continuum elasticity with atomic rigidity, which is a new multiscale formalism for describing excessively large biomolecular systems. The FRI method analyzes protein rigidity and flexibility and is capable of predicting protein B-factors without resorting to matrix diagonalization. A fundamental assumption used in the FRI is that protein structures are uniquely determined by various internal and external interactions,more » while the protein functions, such as stability and flexibility, are solely determined by the structure. As such, one can predict protein flexibility without resorting to the protein interaction Hamiltonian. Consequently, bypassing the matrix diagonalization, the original FRI has a computational complexity of O(N{sup 2}). This work introduces a fast FRI (fFRI) algorithm for the flexibility analysis of large macromolecules. The proposed fFRI further reduces the computational complexity to O(N). Additionally, we propose anisotropic FRI (aFRI) algorithms for the analysis of protein collective dynamics. The aFRI algorithms permit adaptive Hessian matrices, from a completely global 3N × 3N matrix to completely local 3 × 3 matrices. These 3 × 3 matrices, despite being calculated locally, also contain non-local correlation information. Eigenvectors obtained from the proposed aFRI algorithms are able to demonstrate collective motions. Moreover, we investigate the performance of FRI by employing four families of radial basis correlation functions. Both parameter optimized and parameter-free FRI methods are explored. Furthermore, we compare the accuracy and efficiency of FRI with some established approaches to flexibility analysis

The Epital Care Model: A New Person-Centered Model of Technology-Enabled Integrated Care for People With Long Term Conditions.

PubMed

Phanareth, Klaus; Vingtoft, Søren; Christensen, Anders Skovbo; Nielsen, Jakob Sylvest; Svenstrup, Jørgen; Berntsen, Gro Karine Rosvold; Newman, Stanton Peter; Kayser, Lars

2017-01-16

and offered two additional services: an outgoing acute medical team and a local subacute bed function. Based on the findings from the iterative process, and evolving technology and workflow solutions, we propose a robust and feasible model that can provide a framework for developing solutions to support an active life with one or more LTCs. The resulting Epital Care Model (ECM) consists of six stages, and serves as a template for how a digitally-enhanced health service can be provided based on patients' medical needs. The model is designed to be a proactive, preventive, and monitoring health care system that involves individuals in the management of their own health conditions. The ECM is in accordance with WHO's framework for integrated people-centered health services, and may serve as a framework for the development of new technologies and provide a template for future reorganization. ©Klaus Phanareth, Søren Vingtoft, Anders Skovbo Christensen, Jakob Sylvest Nielsen, Jørgen Svenstrup, Gro Karine Rosvold Berntsen, Stanton Peter Newman, Lars Kayser. Originally published in JMIR Research Protocols (http://www.researchprotocols.org), 16.01.2017.

Pollen-inferred quantitative reconstructions of Holocene land-cover in NW Europe for the evaluation of past climate-vegetation feedbacks - methods and first maps of the cover of plant functional types at 6000, 3000, 600, 200 and 0 BP.

NASA Astrophysics Data System (ADS)

Trondman, Anna-Kari; Gaillard, Marie-José; Sugita, Shinya; Mazier, Florence; Fyfe, Ralph; Nielsen, Anne-Birgitte; Leydet, Michelle; Members, Landclim

2010-05-01

) number of pollen taxa, 3) PPEs dataset, and 4) number of dates per record used to establish the chronology (≥3 or ≥5) was tested (see Mazier et al. CL 1.21). Following the results of these tests, the first maps are based on REVEALS runs using pollen records from both lakes and bogs with ≥3 dates, 24 taxa (entomophilous taxa excluded), and the mean of all PPEs available in the study area. The maps are produced for 10 PFTs (LPJ-GUESS) and 3 PFTs (RCA3) at a spatial resolution of 1o x 1o for five selected time windows of the Holocene with contrasting human-induced land-cover (0-100 cal BP, 100-350 cal BP, 350-700 cal BP, 2700-3200 cal BP and 5700-6200 cal BP). The maps of PFTs show significant changes in the degree of human-induced vegetation openness through the Holocene over most of the study area. There are large discrepancies between these first quantitative land-cover maps and earlier maps based on pollen data and other methods such as biomization and the modern analogue approach. * The following LANDCLIM members are acknowledged for providing pollen records and for help with pollen databases: Teija Alenius (Espoo), Heather Almquist-Jacobson (Montana, USA), Lena Barnekow and Thomas Persson (Lund), Jonas Bergman (Stockholm), Anne Bjune and John Birks (Bergen), Thomas Giesecke (Göttingen), Rixt de Jong (Bern), Mihkel Kangur and Tiiuu Koff (Tallinn), Malgorzata Latalowa (Gdansk), Ann-Marie Robertsson (Stockholm), Ulf Segerström and Henrik von Stedingk (Umeå), Heikki Seppä (Helsinki). Sugita, S. 2007. The Holocene, 17, 229-241.

The Giant Branch of omega Centauri. IV. Abundance Patterns Based on Echelle Spectra of 40 Red Giants

NASA Astrophysics Data System (ADS)

Norris, John E.; Da Costa, G. S.

1995-07-01

Abundances of some 20 elements have been determined for a (biased) sample of 40 red giants having Mv < -1.5 in the chemically inhomogeneous globular cluster ω Centauri. The results are based on high-resolution, high signal-to-noise echelle spectra and permit one to examine the roles of primordial enrichment and stellar evolutionary mixing effects in the cluster. Our basic conclusions are as follows (1) There is an abundance range -1.8 < [Fe/H] < -0.8, and even more metal rich stars may exist in the cluster. (2) For the α (Mg, Si, Ca, Ti) and iron peak (Cr, Ni) elements and Sc and V, [metal/Fe] is flat as a function of [Fe/H] and is consistent with primordial enrichment from stars having mass greater than 10 Msun, as has been found for field halo stars. (3) There is a large scatter in the abundances of C, N, and 0. The bulk of the stars have -0.9 < [C/Fe] < -0.3 and [O/Fe] ˜ 0.3, as is found at the red giant branch tip in other "normal" (showing no spread in [Fe/H]) clusters of similar abundance, while there also exists a group of CN-strong stars having [C/Fe] ˜ -0.7 and [O/Fe] ˜ -0.5. Nitrogen appears to be enhanced in all of these carbon-depleted stars. These results are most readily explained in terms of evolutionary mixing effects not predicted by standard stellar evolution calculations and are consistent with the earlier suggestions of Cohen & Bell (1986) and Paltoglou & Norris (1989) concerning processing in both the CN and ON cycles in the stars being observed. In contrast, the group of CO-strong stars first identified by Persson et al. (1980) has [C/Fe] ˜ 0.0, [O/Fe] ˜ 0.4, and [N/Fe] ˜ 0.4 (or 0.9 if the nitrogen scale of Brown and Wallerstein is correct) and is suggestive of primordial enrichment of carbon and/or nitrogen from intermediate- and possibly low-mass stars, tempered by later stellar evolutionary effects. (4) [Na/Fe] and [Al/Fe] are anticorrelated with [O/Fe], and there is a positive correlation between [Na/Fe] and [Al/Fe], all of which

Barite recrystallization in the presence of 226Ra and 133Ba

NASA Astrophysics Data System (ADS)

Heberling, Frank; Metz, Volker; Böttle, Melanie; Curti, Enzo; Geckeis, Horst

2018-07-01

, recrystallization is extremely slow in the experiments presented here. While previous authors suggested complete equilibration of bulk microcrystalline barite within less than three years, a recrystallization of less than 7% of the barite mass is observed within five years. We describe the progress of recrystallization with a new modified homogeneous recrystallization model. Observed recrystallization rates are in the range 0.11-1.5 nmol/(m2 s) and increase with decreasing pH. According to this modified homogeneous recrystallization model, complete bulk barite equilibration is expected in about 1400-16,900 years. The strongly decreased recrystallization kinetics in our experiments is likely related to a strongly prolonged pre-equilibration time (0.8 years), which according to XRD investigations, leads to a higher crystallinity (higher crystal domain size and lower Debye-Waller parameters) of the barite powder.

Editorial: Focus on Laser- and Beam-Driven Plasma Accelerators

NASA Astrophysics Data System (ADS)

Joshi, Chan; Malka, Victor

2010-04-01

, S Mangles, L O Silva, R Fonseca and P A Norreys Electro-optic shocks from blowout laser wakefields D F Gordon, A Ting, M H Helle, D Kaganovich and B Hafizi Onset of self-steepening of intense laser pulses in plasmas J Vieira, F Fiúza, L O Silva, M Tzoufras and W B Mori Analysis of laser wakefield dynamics in capillary tubes N E Andreev, K Cassou, F Wojda, G Genoud, M Burza, O Lundh, A Persson, B Cros, V E Fortov and C-G Wahlstrom Characterization of the beam loading effects in a laser plasma accelerator C Rechatin, J Faure, X Davoine, O Lundh, J Lim, A Ben-Ismaïl, F Burgy, A Tafzi, A Lifschitz, E Lefebvre and V Malka Energy gain scaling with plasma length and density in the plasma wakefield accelerator P Muggli, I Blumenfeld, C E Clayton, F J Decker, M J Hogan, C Huang, R Ischebeck, R H Iverson, C Joshi, T Katsouleas, N Kirby, W Lu, K A Marsh, W B Mori, E Oz, R H Siemann, D R Walz and M Zhou Generation of tens of GeV quasi-monoenergetic proton beams from a moving double layer formed by ultraintense lasers at intensity 1021-1023Wcm-2 Lu-Le Yu, Han Xu, Wei-Min Wang, Zheng-Ming Sheng, Bai-Fei Shen, Wei Yu and Jie Zhang Carbon ion acceleration from thin foil targets irradiated by ultrahigh-contrast, ultraintense laser pulses D C Carroll, O Tresca, R Prasad, L Romagnani, P S Foster, P Gallegos, S Ter-Avetisyan, J S Green, M J V Streeter, N Dover, C A J Palmer, C M Brenner, F H Cameron, K E Quinn, J Schreiber, A P L Robinson, T Baeva, M N Quinn, X H Yuan, Z Najmudin, M Zepf, D Neely, M Borghesi and P McKenna Numerical modelling of a 10-cm-long multi-GeV laser wakefield accelerator driven by a self-guided petawatt pulse S Y Kalmykov, S A Yi, A Beck, A F Lifschitz, X Davoine, E Lefebvre, A Pukhov, V Khudik, G Shvets, S A Reed, P Dong, X Wang, D Du, S Bedacht, R Zgadzaj, W Henderson, A Bernstein, G Dyer, M Martinez, E Gaul, T Ditmire and M C Downer Effects of laser prepulses on laser-induced proton generation D Batani, R Jafer, M Veltcheva, R Dezulian, O Lundh, F Lindau, A

NASA Announces 2009 Astronomy and Astrophysics Fellows

NASA Astrophysics Data System (ADS)

2009-02-01

WASHINGTON -- NASA has selected fellows in three areas of astronomy and astrophysics for its Einstein, Hubble, and Sagan Fellowships. The recipients of this year's post-doctoral fellowships will conduct independent research at institutions around the country. "The new fellows are among the best and brightest young astronomers in the world," said Jon Morse, director of the Astrophysics Division in NASA's Science Mission Directorate in Washington. "They already have contributed significantly to studies of how the universe works, the origin of our cosmos and whether we are alone in the cosmos. The fellowships will serve as a springboard for scientific leadership in the years to come, and as an inspiration for the next generation of students and early career researchers." Each fellowship provides support to the awardees for three years. The fellows may pursue their research at any host university or research center of their choosing in the United States. The new fellows will begin their programs in the fall of 2009. "I cannot tell you how much I am looking forward to spending the next few years conducting research in the U.S., thanks to the fellowships," said Karin Oberg, a graduate student in Leiden, The Netherlands. Oberg will study the evolution of water and ices during star formation when she starts her fellowship at the Smithsonian Astrophysical Observatory in Cambridge, Mass. People Who Read This Also Read... Milky Way's Super-efficient Particle Accelerators Caught in The Act Cosmic Heavyweights in Free-for-all Galaxies Coming of Age in Cosmic Blobs Cassiopeia A Comes Alive Across Time and Space A diverse group of 32 young scientists will work on a wide variety of projects, such as understanding supernova hydrodynamics, radio transients, neutron stars, galaxy clusters and the intercluster medium, supermassive black holes, their mergers and the associated gravitational waves, dark energy, dark matter and the reionization process. Other research topics include

Young People, Adult Worries: Randomized Controlled Trial and Feasibility Study of the Internet-Based Self-Support Method "Feel the ViBe" for Adolescents and Young Adults Exposed to Family Violence.

PubMed

van Rosmalen-Nooijens, Karin; Lo Fo Wong, Sylvie; Prins, Judith; Lagro-Janssen, Toine

2017-06-12

. UNIANOVA showed no significant differences. Pre-post paired sample t tests showed significant improvements after 12 weeks for the SCL-90 DEP (P=.03) and ANX (P=.046) subscales. Reported mean Web-based time per week was 2.83 with a session time of 36 min. FtV was rated a mean 7.47 (1-10 Likert scale) with a helpfulness score of 3.16 (1-5 Likert scale). All participants felt safe. Two-thirds of the intervention participants started regular health care. No changes on the IES were found. SCL-90 DEP and ANX showed promising results; however, the calculated sample size was not reached (n=18). FtV functions best as a first step for adolescents and young adults in an early stage of change. FtV can be easily implemented without extensive resources and fits best in the field of public health care or national governmental care. Netherlands National Trial Register (NTR): NTR3692; http://www.trialregister.nl/trialreg/admin/ rctview.asp?TC=3692 (Archived by WebCite at http://www.webcitation.org/6qIeKyjA4). ©Karin van Rosmalen-Nooijens, Sylvie Lo Fo Wong, Judith Prins, Toine Lagro-Janssen. Originally published in the Journal of Medical Internet Research (http://www.jmir.org), 12.06.2017.

Experimental Compressibility of Molten Hedenbergite at High Pressure

NASA Astrophysics Data System (ADS)

Agee, C. B.; Barnett, R. G.; Guo, X.; Lange, R. A.; Waller, C.; Asimow, P. D.

2010-12-01

Experiments using the sink/float method have bracketed the density of molten hedenbergite (CaFeSi2O6) at high pressures and temperatures. The experiments are the first of their kind to determine the compressibility of molten hedenbergite at high pressure and are part of a collaborative effort to establish a new database for an array of silicate melt compositions, which will contribute to the development of an empirically based predictive model that will allow calculation of silicate liquid density and compressibility over a wide range of P-T-X conditions where melting could occur in the Earth. Each melt composition will be measured using: (i) double-bob Archimedean method for melt density and thermal expansion at ambient pressure, (ii) sound speed measurements on liquids to constrain melt compressibility at ambient pressure, (iii) sink/float technique to measure melt density to 15 GPa, and (iv) shock wave measurements of P-V-E equation of state and temperature between 10 and 150 GPa. Companion abstracts on molten fayalite (Waller et al., 2010) and liquid mixes of hedenbergite-diopside and anorthite-hedenbergite-diopside (Guo and Lange, 2010) are also presented at this meeting. In the present study, the hedenbergite starting material was synthesized at the Experimental Petrology Lab, University of Michigan, where melt density, thermal expansion, and sound speed measurements were also carried out. The starting material has also been loaded into targets at the Caltech Shockwave Lab, and experiments there are currently underway. We report here preliminary results from static compression measurement performed at the Department of Petrology, Vrije Universiteit, Amsterdam, and the High Pressure Lab, Institute of Meteoritics, University of New Mexico. Experiments were carried out in Quick Press piston-cylinder devices and a Walker-style multi-anvil device. Sink/float marker spheres implemented were gem quality synthetic forsterite (Fo100), San Carlos olivine (Fo90), and

Reach and Acceptability of a Mobile Reminder Strategy and Facebook Group Intervention for Weight Management in Less Advantaged Adolescents: Insights From the PRALIMAP-INÈS Trial.

PubMed

Saez, Laura; Langlois, Johanne; Legrand, Karine; Quinet, Marie-Hélène; Lecomte, Edith; Omorou, Abdou Y; Briançon, Serge

2018-05-18

-of-year face-to-face interviews, 78.1% (153/196) declared an interest in the Facebook challenge group, which implies having a Facebook account or being able to have access to one. However, only 21 adolescents went through the process of joining the group. Although there was satisfaction with the Facebook group among the participants, the low participation rate in the Facebook group does not allow conclusions to be drawn with confidence. The results are in line with the claim that using information and communication technologies in health programs is unlikely to widen health inequalities. However, in this population of French adolescents, mobile phone strategies seem more adapted to a high school context, and caution should be exercised with a younger audience. Although there is positive appreciation of the SMS attendance-reminders and a Facebook intervention is initially highly appealing to less advantaged adolescents, no evidence of impact could be demonstrated. These results highlight the difficulty in assessing the impact of specific interventions in complex health programs. Clinicaltrials.gov NCT01688453; https://clinicaltrials.gov/ct2/show/NCT01688453 (Archived by WebCite at http://www.webcitation.org/6yy6EQ0SM). ©Laura Saez, Johanne Langlois, Karine Legrand, Marie-Hélène Quinet, Edith Lecomte, Abdou Y Omorou, Serge Briançon, PRALIMAP-INÈS Trial Group. Originally published in JMIR Mhealth and Uhealth (http://mhealth.jmir.org), 18.05.2018.

The Hawaii trails project: comet-hunting in the main asteroid belt

NASA Astrophysics Data System (ADS)

Hsieh, H. H.

2009-10-01

Context: The mysterious solar system object 133P/(7968) Elst-Pizarro is dynamically asteroidal, yet displays recurrent comet-like dust emission. Two scenarios were hypothesized to explain this unusual behavior: 1) 133P is a classical comet from the outer solar system that has evolved onto a main-belt orbit or 2) 133P is a dynamically ordinary main-belt asteroid on which subsurface ice has recently been exposed. If 1) is correct, the expected rarity of a dynamical transition onto an asteroidal orbit implies that 133P could be alone in the main belt. In contrast, if 2) is correct, other icy main-belt objects should exist and could also exhibit cometary activity. Aims: Believing 133P to be a dynamically ordinary, yet icy main-belt asteroid, I set out to test the primary prediction of the hypothesis: that 133P-like objects should be common and could be found by an appropriately designed observational survey. Methods: I conducted just such a survey - the Hawaii Trails Project - of selected main-belt asteroids in a search for objects displaying cometary activity. Optical observations were made of targets selected from among the Themis, Koronis, and Veritas asteroid families, the Karin asteroid cluster, and low-inclination, kilometer-scale outer-belt asteroids, using the Lulin 1.0 m, small and moderate aperture research telescope system (SMARTS) 1.0 m, University of Hawaii 2.2 m, southern astrophysical research (SOAR) 4.1 m, Gemini North 8.1 m, Subaru 8.2 m, and Keck I 10 m telescopes. Results: I made 657 observations of 599 asteroids, discovering one active object now known as 176P/LINEAR, leading to the identification of the new cometary class of main-belt comets (MBCs). These results suggest that there could be ~100 currently active MBCs among low-inclination, kilometer-scale outer-belt asteroids. Physically and statistically, MBC activity is consistent with initiation by meter-sized impactors. The estimated rate of impacts and sizes of resulting active sites, however

Voluminous low-T granite: fluid present partial melting of the crust?

NASA Astrophysics Data System (ADS)

Hand, Martin; Barovich, Karin; Morrissey, Laura; Bockmann, Kiara; Kelsey, David; Williams, Megan

2017-04-01

Voluminous low-T granite: fluid present partial melting of the crust? Martin Hand(1), Karin Barovich(1), Laura Morrissey(1), Vicki Lau(1), Kiara Bockmann(1), David Kelsey(1), Megan Williams(1) (1) Department of Earth Sciences, University of Adelaide, Adelaide, Australia Two general schools of thought exist for the formation of granites from predominantly crustal sources. One is that large-scale anatexis occurs via fluid-absent partial melting. This essentially thermal argument is based on the reasonable premise that the lower crust is typically fluid depleted, and experimental evidence which indicates that fluid-absent partial melting can produce significant volumes of melt, creating compositionally depleted residua that many believe are recorded by granulite facies terranes. The other school of thought is that large-scale anatexis can occur via fluid-fluxed melting. This essentially compositional-based contention is also supported by experimental evidence which shows that fluid-fluxed melting is efficient, including at temperatures not much above the solidus. However, generating significant volumes of melt at low temperatures requires a large reservoir of fluid. If fluid-fluxed melting is a realistic model, the resultant granites should be comparatively low temperature compared to those derived from predominantly fluid-absent partial melting. Using a voluminous suite of aluminous granites in the Aileron Province in the North Australian Craton together with metasedimentary granulites as models for source behaviour, we evaluate fluid-absent verse fluid-present regimes for generating large volumes of crustally-derived melt. The central Aileron Province granites occupy 32,500km2, and in places are in excess of 8 km thick. They are characterised by abundant zircon inheritance that can be matched with metasedimentary successions in the region, suggesting they were derived in large part from melting of crust similar to that presently exposed. A notable feature of many of

Cosmic Blasts Much More Common, Astronomers Discover

NASA Astrophysics Data System (ADS)

2006-08-01

produce gamma rays and X-rays have disks of material rotating rapidly about the central object," Soderberg said. The powerful gamma ray bursts tap the tremendous gravitational energy of their black hole to produce strong beams of energetic radiation, while less-energetic X-ray bursts like the Feburary event tap energy from the strong magnetic field of the magnetar, the scientists speculated. "This discovery means that the 'zoo' of cosmic explosions has just gotten more numerous and more diverse. It also means that our understanding of how the cores of massive stars collapse to produce this variety of explosions is less complete than we had thought," Frail added. Multiwavelength follow-up observations were required by the team to measure the total energy release of the explosion. In particular, Soderberg adds that "Radio observations with the Very Large Array were additionally required to determine the geometry of the ejecta. We find that unlike typical GRBs which produce pencil-beam jets, this object more resembles a spherical explosion." In addition to Soderberg and Frail, the research team includes Shri Kulkarni. Ehud Nakar, Edo Berger, Brian Cameron, Avishay Gal-Yam, Re'em Sari, Mansi Kasiwal, Eran Ofek, Arne Rau, Brad Cenko, Eric Persson and Dae-Sik Moon of Caltech, Derrick Fox and Dave Burrows of Pennsylvania State University, Roger Chevalier of the University of Virginia, Tsvi Piran of the Hebrew University, Paul Price of the University of Hawaii, Brian Schmidt of Mount Stromlo Observatory in Australia, Guy Pooley of the Mullard Radio Astronomy Observatory in the UK, Bryan Penprase of Pomona College, and Neil Gehrels of the NASA Goddard Space Flight Center. The National Radio Astronomy Observatory is a facility of the National Science Foundation, operated under cooperative agreement by Associated Universities, Inc. http://www.nrao.edu/

Cosmic Blasts Much More Common, Astronomers Discover

NASA Astrophysics Data System (ADS)

2006-08-01

explosions is that the blasts that produce gamma rays and X-rays have disks of material rotating rapidly about the central object," Soderberg said. The powerful gamma ray bursts tap the tremendous gravitational energy of their black hole to produce strong beams of energetic radiation, while less-energetic X-ray bursts like the Feburary event tap energy from the strong magnetic field of the magnetar, the scientists speculated. "This discovery means that the 'zoo' of cosmic explosions has just gotten more numerous and more diverse. It also means that our understanding of how the cores of massive stars collapse to produce this variety of explosions is less complete than we had thought," Frail added. Multiwavelength follow-up observations were required by the team to measure the total energy release of the explosion. In particular, Soderberg adds that "Radio observations with the Very Large Array were additionally required to determine the geometry of the ejecta. We find that unlike typical GRBs which produce pencil-beam jets, this object more resembles a spherical explosion." In addition to Soderberg and Frail, the research team includes Shri Kulkarni. Ehud Nakar, Edo Berger, Brian Cameron, Avishay Gal-Yam, Re'em Sari, Mansi Kasiwal, Eran Ofek, Arne Rau, Brad Cenko, Eric Persson and Dae-Sik Moon of Caltech, Derrick Fox and Dave Burrows of Pennsylvania State University, Roger Chevalier of the University of Virginia, Tsvi Piran of the Hebrew University, Paul Price of the University of Hawaii, Brian Schmidt of Mount Stromlo Observatory in Australia, Guy Pooley of the Mullard Radio Astronomy Observatory in the UK, Bryan Penprase of Pomona College, and Neil Gehrels of the NASA Goddard Space Flight Center. The National Radio Astronomy Observatory is a facility of the National Science Foundation, operated under cooperative agreement by Associated Universities, Inc.

Pollen-inferred quantitative reconstructions of Holocene land-cover in NW Europe for the evaluation of past climate-vegetation feedbacks - The Swedish LANDCLIM project and the NordForsk LANDCLIM network

NASA Astrophysics Data System (ADS)

Gaillard, Marie-Jose; Sugita, Shinya; Rundgren, Mats; Smith, Benjamin; Mazier, Florence; Trondman, Anna-Kari; Fyfe, Ralph; Kokfelt, Ulla; Nielsen, Anne-Birgitte; Strandberg, Gustav

2010-05-01

of ca. 1o x 1o. The REVEALS estimates of the past cover of PFTs will be 1) compared with the outputs of the LPJ-GUESS (10 PFTs), a widely-used dynamic vegetation model and 2) used as an alternative to the LPJ-GUESS-simulated vegetation (3 PFTs) to run for the past the regional climate model RCA3 developed at the Rossby Centre, Norrköping, Sweden. The study will evaluate and further refine these models (RCA3 and LPJ-GUESS) using a data-model comparison approach that incorporates new syntheses of palaeoclimatic data as well. It will lead to new assessments of the possible effect of various factors on climate, such as deforestations and afforestations, and changes in vegetation composition and spatial patterns of land cover/land use. Refined climate models and empirical land-cover reconstructions will shed new light on controversial hypotheses of past climate change and human impacts, such as the "Ruddiman hypothesis". First maps of REVEALS estimates of plant functional types (PFTs) are now available for Sweden, Norway, Finland, Denmark, Estonia, Poland, Germany, The Czech Republic, Switzerland and Britain (see Mazier et al. C1.21 and Trondman et al. C1.22). Correlation tests show that the REVEALS estimates are robust in terms of ranking of the PFTs' abundance (see Mazier et al, C1.21). The LANDCLIM project and network are a contribution to the IGBP-PAGES-Focus 4 PHAROS programme on human impact on environmental changes in the past. The following LANDCLIM members are acknowledged for providing pollen records, for help with pollen databases, and for providing results to the project: Mihkel Kangur and Tiiu Koff (Univ. Tallinn, Tallinn); Erik Kjellström (SMHI, Norrköping), Anna Broström, Lena Barnekow and Thomas Persson (GeoBiosphere Science Centre, Lund University); Anneli Poska (Physical Geography and Ecosystems Analysis, Lund University); Thomas Giesecke (Albrecht-von-Haller-Institute for Plant Sciences, University of Göttingen), Anne Bjune and John Birks (Dept. of

EDITORIAL: Wind energy

NASA Astrophysics Data System (ADS)

Mann, Jakob; Nørkær Sørensen, Jens; Morthorst, Poul-Erik

2008-01-01

addressed within the issue is how much conventional power production can be replaced by the ceaseless wind, with the question of how Greece's target of 29% renewables by 2020 is to be met efficiently. Other topics include an innovative way to determine the power curve of a turbine experimentally more accurately, the use of fluid dynamics tools to investigate the implications of placing vortex generators on wind turbine blades (thereby possibly improving their efficiency) and a study of the perception of wind turbine noise. It turns out that a small but significant fraction of wind turbine neighbours feel that turbine generated noise impairs their ability to rest. The annoyance is correlated with a negative attitude towards the visual impact on the landscape, but what is cause and effect is too early to say. As mentioned there is a rush for wind turbines in many countries. However, this positive development for the global climate is currently limited by practical barriers. One bottleneck is the difficulties for the sub-suppliers of gears and other parts to meet the demand. Another is the difficulties to meet the demand for engineers specialized in wind. For that reason the Technical University of Denmark (DTU) recently launched the world's first Wind Energy Masters Program. Here and elsewhere in the world of wind education and research we should really speed up now, as our chances of contributing to emission free energy production and a healthier global climate have never been better. Focus on Wind Energy Contents The articles below represent the first accepted contributions and further additions will appear in the near future. Wind turbines—low level noise sources interfering with restoration? Eja Pedersen and Kerstin Persson Waye On the effect of spatial dispersion of wind power plants on the wind energy capacity credit in Greece George Caralis, Yiannis Perivolaris, Konstantinos Rados and Arthouros Zervos Large-eddy simulation of spectral coherence in a wind turbine wake

Water-level altitudes 2010 and water-level changes in the Chicot, Evangeline, and Jasper aquifers and compaction 1973-2009 in the Chicot and Evangeline aquifers, Houston-Galveston region, Texas

USGS Publications Warehouse

Kasmarek, Mark C.; Johnson, Michaela R.; Ramage, Jason K.

2010-01-01

-foot rise (2009-10), from a 25-foot decline to a 35-foot rise (2005-10), from a 40-foot decline to an 80-foot rise (1990-2010), and from a 140-foot decline to a 200-foot rise (1977-2010). In 2010, water-level-altitude contours for the Evangeline aquifer ranged from 300 feet below datum in north-central Harris County to 200 feet above datum at the boundary of Waller, Montgomery, and Grimes Counties. Water-level-altitude changes in the Evangeline aquifer ranged from a 58-foot decline to a 69-foot rise (2009-10), from an 80-foot decline to an 80-foot rise (2005-10), from a 200-foot decline to a 220-foot rise (1990-2010), and from a 320-foot decline to a 220-foot rise (1977-2010). In 2010, water-level-altitude contours for the Jasper aquifer ranged from 200 feet below datum in south-central Montgomery County to 250 feet above datum in eastern-central Grimes County. Water-level-altitude changes in the Jasper aquifer ranged from a 39-foot decline to a 39-foot rise (2009-10), from a 110-foot decline to no change (2005-10), and from a 180-foot decline to no change (2000-10). Compaction of subsurface materials (mostly in the clay layers) composing the Chicot and Evangeline aquifers was recorded continuously at 13 borehole extensometers at 11 sites. For the period of record beginning in 1973, or later, and ending in December 2009, cumulative clay compaction data measured by 12 extensometers ranged from 0.088 foot at the Texas City-Moses Lake site to 3.559 foot at the Addicks site. The rate of compaction varies from site to site because of differences in groundwater withdrawals near each site and differences among sites in the clay-to-sand ratio in the subsurface materials. Therefore, it is not possible to extrapolate or infer a rate of clay compaction for an area based on the rate of compaction measured at a nearby extensometer.

Water-level altitudes 2011 and water-level changes in the Chicot, Evangeline, and Jasper aquifers and compaction 1973-2010 in the Chicot and Evangeline aquifers, Houston-Galveston region, Texas

USGS Publications Warehouse

Johnson, Michaela R.; Ramage, Jason K.; Kasmarek, Mark C.

2011-01-01

decline to an 80-foot rise (2006–11), from a 140-foot decline to a 100-foot rise (1990–2011), and from a 120-foot decline to a 200-foot rise (1977–2011). In 2011, water-level-altitude contours for the Evangeline aquifer ranged from 300 feet below datum in north-central Harris County to 200 feet above datum at the boundary of Waller, Montgomery, and Grimes Counties. Water-level-altitude changes in the Evangeline aquifer ranged from a 43-foot decline to a 73-foot rise (2010–11), from a 40-foot decline to a 160-foot rise (2006–11), from a 200-foot decline to a 240-foot rise (1990–2011), and from a 340-foot decline to a 260-foot rise (1977–2011). In 2011, water-level-altitude contours for the Jasper aquifer ranged from 200 feet below datum in south-central Montgomery County to 250 feet above datum in east-central Grimes County. Water-level-altitude changes in the Jasper aquifer ranged from a 45-foot decline to a 29-foot rise (2010–11), from a 90-foot decline to a 10-foot rise (2006–11), and from a 190-foot decline to no change (2000–11). Compaction of subsurface materials (mostly in the clay layers) composing the Chicot and Evangeline aquifers was recorded continuously at 13 borehole extensometers at 11 sites. For the period of record beginning in 1973, or later, and ending in December 2010, cumulative clay compaction data measured by 12 extensometers ranged from 0.100 foot at the Texas City–Moses Lake site to 3.544 foot at the Addicks site. The rate of compaction varies from site to site because of differences in groundwater withdrawals near each site and differences among sites in the clay-to-sand ratio in the subsurface materials. Therefore, it is not possible to extrapolate or infer a rate of clay compaction for an area based on the rate of compaction measured at a nearby extensometer.

EDITORIAL: Focus on Quantum Control

NASA Astrophysics Data System (ADS)

Rabitz, Herschel

2009-10-01

, Yuri Khodorkovsky, Yehiam Prior and Ilya Sh Averbukh Optimal control of interacting particles: a multi-configuration time-dependent Hartree-Fock approach Michael Mundt and David J Tannor Exact quantum dissipative dynamics under external time-dependent driving fields Jian Xu, Rui-Xue Xu and Yi Jing Yan Pulse trains in molecular dynamics and coherent spectroscopy: a theoretical study J Voll and R de Vivie-Riedle Quantum control of electron localization in molecules driven by trains of half-cycle pulses Emil Persson, Joachim Burgdorfer and Stefanie Grafe Quantum control design by Lyapunov trajectory tracking for dipole and polarizability coupling Jean-Michel Coron, Andreea Grigoriu, Catalin Lefter and Gabriel Turinici Sliding mode control of quantum systems Daoyi Dong and Ian R Petersen Implementation of fault-tolerant quantum logic gates via optimal control R Nigmatullin and S G Schirmer Generalized filtering of laser fields in optimal control theory: application to symmetry filtering of quantum gate operations Markus Schroder and Alex Brown

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mukerjee, S.; Ziegelbauer, J; Arruda, T

transmission beams respectively. When the energy of the incident X-rays exceed the electron binding energy (E{sub 0}) of the element under investigation, the electron is ejected from the core to available excited states in the form of a photoelectron with kinetic energy: E{sub k} = h? - E{sub 0} (2) with, E{sub k} being the kinetic energy of the released photoelectron and h? the energy of the incident beam. In general, the X-ray absorption spectrum is broken down into two distinct energy regions: the X-ray absorption near-edge structure or XANES (-50eV {le} E{sub 0} {le} 50eV) and the extended X-ray absorption fine-structure or EXAFS (50eV {le} E{sub 0} {le} {approx}1000eV). The XANES region is dominated by low-energy photoelectrons which undergo multiple scattering events. As such, it can reveal information about oxidation state, local symmetry, electronic structure, and the extent of oxidation of a material. Due to this complex multiple scattering, there is no simple XANES equation to describe it quantitatively. However, recent advancements in computers and the evolution of numerical methods such as the FEFF code have made possible reliable XANES simulations. Photoelectrons in the EXAFS region have high enough E{sub k} to undergo primarily single back-scattering events. These back-scattered photoelectrons interfere with the outgoing photoelectrons, causing the oscillations in the absorption spectrum. Using the previously developed EXAFS equations it is now possible to model EXAFS data to determine coordination numbers, bond distances, and mean-square disorder (commonly referred to as Debye-Waller factor). EXAFS data is often shown by Fourier Transforming KSpace into distance, r, space where the total magnitude is plotted against the radial coordinates. This allow for easy qualitative comparison of samples. Employing EXAFS on nanoscale materials has the added advantage that it can quantitatively illustrate changes in atom-atom coordination, which can be related to particle

[Links between life events, traumatism and dementia; an open study including 565 patients with dementia].

PubMed

Charles, E; Bouby-Serieys, V; Thomas, P; Clément, J-P

2006-10-01

Ageing is due to a progressive loss of the person's adaptation capability, whereas during this period environmental aggression increases. In the elderly, life events re-present a psychological traumatism that overwhelms the old person and related family, disrupting and fragilising homeostatic balance. A number of authors have suggested a possible link between life traumatisms and the dementia processes. The aim of this study is to reveal the presence of life traumatisms preceding the apparition of the dementia syndrome. This is a retrospective and comparative work based on the PIXEL study on complaints and demands from the principle informal caregivers of Alzheimer patients. It includes 565 patients presenting the criterion of dementia as defined by the DSM IV, and questionnaires filled out by the principle caregivers. One item of the questionnaire referred to life events which could have played a part in the development of the disorder. In a second stage, the reported events were classified into 4 distinct categories: loss, repeated or prolonged stress, psychotraumatism and depression-inducing events. The statistics were produced using SAS and Stat 10 software. Student's test, ANOVA and chi2-test were used. 372 caregivers answered the first item (65%); 76 of them believed there was no event while 296 related the disorder to one or several life events (79% of responders, 52% of the sample). These results confirm Persson and Clement's study which evidenced a higher frequency of stressing life events for subjects afflicted with dementia as compared with older people without any psychic disorder. Reported events and their respective frequency: spouse death (15.39%), parents' death (15%), familial difficulty (10.08%), anaesthesia (8.49%), child's death (4.42%), somatic disturbance (4%), depression (3.89%), retirement (3.89%), financial problems (2.65%), loneliness (2.65%), removal (1.76%), fall (1%), alcohol (0.8%), traumatism (0.53%), spouse care (0.35%), leaving for

Human-induced environmental degradation during Anthropocene in Turkey

NASA Astrophysics Data System (ADS)

Efe, Recep; Curebal, Isa; Soykan, Abdullah; Sönmez, Suleyman

2015-04-01

.; Andreae, M.O.; Kadereit, J.W.; Esper, J.; Scholz, D.; Pöschl, U.; Jacob, D.E.; Schöne, B.R.; Schreg, R.; Vött, A.; Jordan, D.; Lelievld, J.: Weller, C.G.; Alt, K.W.; Gaudzinski-Windheuser, S.; Bruhn, K.C.; Tost, H.; Sirocko, F.; Crutzen, P.J. (2013), The Paleoanthropocene - The beginnings of anthropogenic environmental change, Anthropocene, 3: 83-88. Hoang, H.T.T.; Vanacker, V.; Van Rompaey, A.; Vu, K.C.; Nguyen, A.T. (2014), Changing human-landscape interactions after development of tourism in the nothern Vietnamese Highlands, Anthropocene, 5: 42-51 Matteo, G.; Lingua, E.; Marzano, R.; Urbinati, C.; Bhuju, D.; Carrer, M. (2014), Human interactions with forest landscape in the Khumbu valley, Nepal, Anthropocene, 6: 39-47 Sanderson, E.W.; Jaiteh, M.; Levy, M.A.; Redford, K.H.; Wannebo, A.V.; Woolmer, G. (2002), The Human Footprint and the Last of the Wild. Bioscience 52: (10).891-904 Steffen, W.; Persson, A.; Deutsch, L.; Zalasiewicz, J.; Williams, M.; Richardson, K.; Crumley, C.; Crutzen, P.; Folke, C.; Gordon, L.; Molina, M.; Ramanathan, V., Rockström, J.; Scheffer, M.; Schellnhuber, H.J.; Svedin, U. (2011), The Anthropocene: From Global Change to Planetary Stewardship, AMBIO, 40: 739-761 Web-1 http://www.anthropocene.info/en/home Zalasiewicz, J.; Williams, M.; Smith, A.; L. Barry, T.; L. Coe, A.; R. Bown, P.; Brenchley, P.; Cantrill, D.; Gale, A.; Gibbard, P.; Gregory, F.J.; Hounslow, M.W.; Kerr, A.C.; Pearson, P.; Knox, R.; Powell, J.; Waters, C.; Marshall, J.; Oates, M.; Rawson, P.; Stone, P. (2008), Are we now living in the Anthropocene? GSA Today 18 (2): 4-8.

a Passage to the Universe

NASA Astrophysics Data System (ADS)

1995-11-01

a concluding Press Conference , during which the outcome of this unique event will be summarized by the participants and the organisers: Monday, November 20, 1995, 15:30 pm, at the ESO Headquarters, Karl-Schwarzschild-Strasse 2, D-85748 Garching, Germany List of National First-Prize Winners Belgium: Mr. Freddy Allemeersch (Teacher), Mr. Pieter De Ceuninck, Mr. Jeroen Staelens (Onze-Lieve-Vrouwecollege, Brugge) Denmark: Mr. Joern C. Olsen, Mr. Henrik Struckmann, Mr. Uffe A. Hansen, Mr. Mogens Winther (Teacher) (Soenderborg Amtsgymnasium) Finland: Mr. Reima Eresmaa, Ms. Laura Elina Nykyri, Ms. Reetamaija Janhonen (Cygnaeues-Lukeo, Jyvaeskylae and Jyvaeskylaen Lyseon Lukeo) France: Mr. Rene Cavaroz (Teacher), Mr. Vincent Hardy, Mr. Antoine Lesuffleur (Lycee Chartier, Bayeux) Germany: Ms. Dorothee Barth, Mr. Walter Czech (Teacher), Mr. Uwe Kranz, Ms. Karin Wieland (Immanuel-Kant-Gymnasium, Leinfelden-Echterdingen, Baden-Wuerttemberg) Greece: Ms. Agni Ioannidi, Ms. Elena Katifori, Mr. Vassilis Samiotis, Mr. Vassillos Tzotzes (Teacher) (Second Varvakelo Experimental Lyceum, Athens) Ireland: Mr. Declan Maccuarta (Teacher), Mr. Colm Mcloughlin (St. Peter's College, Wexford, Co. Wexford) Italy: Mr. Pasquale Ciarletta, Ms. Francesca D'elia, Ms. Ada Fortugna (Teacher), Mr. Alfredo Pudano (Liceo Scientifico `Leonardo da Vinci', Reggio Calabria) The Netherlands: Mr. Alex De Beer, Mr. Klaas Huijbregts, Mr. Ruud Nellen (Norbertuscollege, Rosendaal) Spain: Mr. Aritz Atela Aio, Mr. Julen Sarasola Manich (Teacher), Mr. Jon Huertas Rodriquez (Txorierri Batxilergoko Institua, Derio Bizkaia) Sweden: Mr. Rahman Amanullah, Mr. Kjell L. Bonander (Teacher), Mr. Tomas Oppelstrup, Ms. Christin Wiedemann (Saltsjoebadens Samskola, Saltsjoebaden) United Kingdom: Mr. Michael Ching, Dr. Richard Field (Teacher) (Oundle School, Peterborough) National Committees Further information about the national contests may be obtained from the National Committees: Belgium: Dr. C. Sterken, Vrije Universiteit

Book Review: Beitraege zur Astronomiegeschichte, Band 5 (Acta Historica Astronomiae Vol. 15)

NASA Astrophysics Data System (ADS)

Duerbeck, H. W.; Dick, W. R.; Hamel, J.

2002-12-01

Pisa and the librarian Pozzetti at Bologna, and Karin Reich describes and edits Bessel's book critique of Gauss' Theoria Motus. How many one-time astronomers have to earn their living in other ways, become distracted from astronomical research, and vanish from the horizon of astronomical history? In the ninth paper, Hans-Joachim Ilgauds has traced the life of Georg Koch (1851-1905), who started his career as an astronomer at Leipzig Observatory in 1874. Later Koch worked at Hamburg Observatory, and then became an employee at the statistical office in Kiel, and finally director of the statistical office of the Hamburg revenue service. He was a collaborator for the statistical yearbook of German cities, and also contributed to a book investigating the causes and the impact of the cholera epidemic of 1892 in Hamburg. The last two papers deal with the circumstances of the discovery of the first Near-Earth asteroid (433) Eros. It was recorded on photographic plates taken at the Urania-Sternwarte Berlin and at Nice Observatory. The Berlin observer Witt announced the discovery, and only later, the Nice observer Charlois published a position of Eros. While all plates have disappeared, the authors Hans Scholl and Lutz D. Schmadel could prove that the Nice plate was poorly guided and Charlois would have been unable to discover the object. From a copy of the Berlin plate, published 50 years after the discovery by Witt's co-observer F. Linke, the exact position was determined, and the time of observation (which had not been published) was derived. The second article, by Lutz D. Schmadel, deals with the life of the Eros co-discoverer Felix Linke (1879-1959), who later worked in statistic offices, was a frequent writer of popular scientific articles, and later the editor of a journal, "Technik im Hotel'', and author of a book of the same title. As can be seen from the summaries given above, this collection of essays deals mainly with historical events that occurred in Germany and

Congratulations to Carey King

NASA Astrophysics Data System (ADS)

Hall, Charles A. S.

2012-03-01

importance of these more comprehensive EROIs but we do understand that our usual methods of including only energy used directly (e.g. to run a pump) or indirectly (e.g. to manufacture the steel forms used) greatly underestimates the total amount of energy needed to produce energy. In conclusion, Carey King appears to be one of the real rising energy stars as energy becomes again much more important. He is very bright, original and is a very hard worker. I look forward to much exciting, innovative and important work from his endeavors. References Barnett H and Morse C 1963 Scarcity and Growth: The Economics of Natural Resource Availability (Baltimore, MD: Johns Hopkins Press) Cleveland C J, Costanza R, Hall C A S and Kaufmann R 1984 Energy and the United States economy: a biophysical perspective Science 225 890-7 Denison E F 1989 Estimates of Productivity Change by Industry, an Evaluation and an Alternative (Washington, DC: The Brookings Institution) Hall C A S 1972 Migration and metabolism in a temperate stream ecosystem Ecology 53 585-604 Hall C A S and Cleveland C J 1981 Petroleum drilling and production in the United States: yield per effort and net energy analysis Science 211 576-9 Hall C A S and Klitgaard K 2011 Energy and the Wealth of Nations: Understanding the Biophysical Economy (New York: Springer) Kaufmann R 2004 The mechanisms for autonomous energy efficiency increases: a cointegration analysis of the US Energy/GDP Ratio The Energy Journal 25 63-86 King C W 2010 Energy intensity ratios as net energy measures of United States energy production and expenditures Environ. Res. Lett. 5 044006 Murphy D J and Hall C A S 2011 Energy return on investment, peak oil, and the end of economic growth in 'Ecological Economics Reviews' ed Robert Costanza, Karin Limburg and Ida Kubiszewski Ann. N.Y. Acad. Sci. 1219 52-72 Solow R M 1974 The economics of resources or the resources of economics American Economic Review 66 1-14 Odum H T 1973 Environment, Power and Society (New York

ESA's Integral detects closest cosmic gamma-ray burst

NASA Astrophysics Data System (ADS)

2004-08-01

be just sensitive enough to reveal a few more of them in the years to come. These could be just the tip of the iceberg and future gamma-ray observatories, such as the planned NASA's Swift mission, should be able to extend this search to a much larger volume of the Universe and find many more sub-energetic GRBs. Notes for editors The results of this investigation are presented in two articles that have appeared in today's issue of the scientific journal Nature. One of them, by S. Sazonov, A. Lutovinov and R. Sunyaev, is entitled "An apparently normal gamma-ray burst with unusually low luminosity". The other, entitled "The sub-energetic GRB 031203 as a cosmic analogue to GRB 980425", is signed by A. Soderberg, S. Kulkarni, E. Berger, D. Fox, M. Sako, D. Frail, A. Gal-Yam, D. Moon, S. Cenko, S. Yost, M. Phillips, E. Persson, W. Freedman, P. Wyatt, R. Jayawardhana and D. Paulson. The original announcement of the Integral detection of GRB 031203 was made by D. Goetz, S. Mereghetti, M. Beck, J. Borkowski and N. Mowlavi, via the Circular Service of the GRB Co-ordinates Network. More about Integral The International Gamma Ray Astrophysics Laboratory (Integral) is the first space observatory that can simultaneously observe celestial objects in gamma rays, X-rays and visible light. Integral was launched on a Russian Proton rocket on 17 October 2002 into a highly elliptical orbit around Earth. Its principal targets include regions of the galaxy where chemical elements are being produced and compact objects, such as black holes. For more information about Integral please see: http://www.esa.int/esaSC/spk.html More about XMM-Newton ESA's XMM-Newton can detect more X-ray sources than any previous satellite and is helping to solve many cosmic mysteries of the violent Universe, from black holes to the formation of galaxies. It was launched on 10 December 1999, using an Ariane-5 rocket, from French Guiana. It is expected to return data for a decade. XMM-Newton's high-tech design uses

Biological N2-FIXATION and Mineral N-Fertilization Effects on Soybean (Glicine max L. Merr.) Yield Under Temperate Climate Conditions

NASA Astrophysics Data System (ADS)

László Phd, M., ,, Dr.

2009-04-01

-fundamental processes and how to control them. Conference at the Royal Swedish Academy of Agriculture and Forestry. April 12th. 1999. (Ed's Jan Persson). 9-23. Kungl Skogs-och Lantbruksakademiens Tidskrift. Stockholm. Kádár, I. & Márton, L., 1999. Mineral Nutrient Cycle of Soya. Agrochemistry and Soil Science. 48:67-82. Kováts, A., Márton, L. & Szabó, L., 1985. Analysis of the relation between humus and pH on the ground of results of soil investigations on farm-scale plots. Plant Production. 34:507-512. László, M., Silva, J.B.C. & José, A.B., 2001. Ecological friendly dragée technics on different crops and vegetables seeds. Acta Agronomica Óváriensis. 43:9-13. László, M., & Jose, E.M., 2001. Effects of Crotalaria juncea L. and Crotalaria spectabilis ROTH on soil fertility and siol conservation in Hungary. Acta Agronomica Óváriensis. 43:1-8. Márton, L., 2000. Effect of NPK fertilization on potao (Solanum tuberosum L.) yield. Ph.D dissertation. University of Veszprém, Keszthely, 136. p. Márton, L., 2001. Climate change and N, P, K, Mg fertilization effect analysis at Tisza-river basin in a long term field experiment. Szent István University, Gödöllő, 21. p. Márton, L. & Kádár, I., 1998. Effect of nitrogen supplies on the yield components of soya. Plant production. 47:677-687. Reeves, T.G., 1998. Sustainable Intensification of Agriculture. International Maize and Wheat Improvement Center. Mexico city. Mexico. Wilcox, J.R., 1987. Soybeans: Improvement, Production, and Uses. Madison, Wisconsin, USA.

EDITORIAL: Van der Waals interactions in advanced materials, in memory of David C Langreth Van der Waals interactions in advanced materials, in memory of David C Langreth

NASA Astrophysics Data System (ADS)

Hyldgaard, Per; Rahman, Talat S.

2012-10-01

: potential-energy curves for H2 molecules on Cu(111), (100) and (110) surfacesKyuho Lee, Kristian Berland, Mina Yoon, Stig Andersson, Elsebeth Schröder, Per Hyldgaard and Bengt I Lundqvist Ab initio and semi-empirical van der Waals study of graphene-boron nitride interaction from a molecular point of viewVasile Caciuc, Nicolae Atodiresei, Martin Callsen, Predrag Lazić and Stefan Blügel Rationale for switching to nonlocal functionals in density functional theoryP Lazić, N Atodiresei, V Caciuc, R Brako, B Gumhalter and S Blügel Improved description of soft layered materials with van der Waals density functional theoryGabriella Graziano, Jiří Klimeš, Felix Fernandez-Alonso and Angelos Michaelides Structure and stability of weakly chemisorbed ethene adsorbed on low-index Cu surfaces: performance of density functionals with van der Waals interactionsFelix Hanke, Matthew S Dyer, Jonas Björk and Mats Persson Are we van der Waals ready?T Björkman, A Gulans, A V Krasheninnikov and R M Nieminen Nonequilibrium thermodynamics of interacting tunneling transport: variational grand potential, density functional formulation and nature of steady-state forcesP Hyldgaard

Young Astronomers' Observe with ESO Telescopes

NASA Astrophysics Data System (ADS)

1995-11-01

project concerned the actual construction of a working solar radio interferometer, a rather complex instrument that allows measurements of the long-wavelength radiation from the Sun and to map the locations in the solar corona where this radiation originates. The antennae and receiver were designed for frequences around 550 and 750 MHz and were built by the team members themselves. Radio signals from the Sun (as interference fringes) were effectively observed with this instrument, documenting the excellent functioning of this advanced equipment. Germany: Ms. Dorothee Barth, Mr. Walter Czech (Teacher), Mr. Uwe Kranz, Ms. Karin Wieland (Immanuel-Kant-Gymnasium, Leinfelden-Echterdingen, Baden-Wurttemberg) Following a careful planning phase, systematic observations of the 14-magnitude planet Pluto were made with a CCD camera and a 30-cm telescope during 18 nights in the spring and summer of this year. Five nearby stars were used to calibrate the resulting photometric measurements. In the end, this programme was shown to achieve a very good photometric accuracy of about +- 0.2 magnitude per measurement. The variation of Pluto's brightness was found to be about 0.7 magnitude for this particular instrumental combination (no filtre). It was thus possible to draw the lightcurve which was found to be in complete agreement with the established 6.4 day rotation period. Greece: Ms. Agni Ioannidi, Ms. Elena Katifori, Mr. Vassilis Samiotis, Mr. Vassillos Tzotzes (Teacher) (Varvakio Experimental Lyceum, Athens) The project starts out from a star of 1.56 solar mass and a certain density. From this, its size, luminosity, temperature, pressure and other parameters are calculated. With an analogue to the Titius-Bode law for planetary distances, a new planetary system is constructed. It has 5 planets, 3 of which are of the terrestrial type and the other 2 are giant gas planets, larger than Jupiter. Their physical characteristics are calculated. One planet (the 3rd from the central star) is