Determination of the sources of nitrate contamination in karst springs using isotopic and chemical indicators

USGS Publications Warehouse

Panno, S.V.; Hackley, Keith C.; Hwang, H.-H.; Kelly, W.R.

2001-01-01

The sources of nitrate (NO-3) in groundwater of the shallow karst aquifer in southwestern Illinois' sinkhole plain were investigated using chemical and isotopic techniques. The groundwater in this aquifer is an important source of potable water for about half of the residents of the sinkhole plain area. Previous work has shown that groundwater from approximately 18% of the wells in the sinkhole plain has NO-3 concentrations in excess of the USEPA's drinking water standard of 10 mg N/1. Relative to background levels, the NO-3 concentrations in water from 52% of the wells, and probably all of the springs in the study area, are anomalously high, suggesting that sources other than naturally occurring soil organic matter have contributed additional NO-3 to groundwater in the shallow karst aquifer. This information, and the dominance of agriculture in the study area, suggest that agrichemical contributions may be significant. To test this hypothesis, water samples from 10 relatively large karst springs were collected during four different seasons and analyzed for inorganic constituents, dissolved organic carbon, atrazine, and ??15N and ??18O of the NO-3 ions. The isotopic data were most definitive and suggested that the sources of NO-3 in spring water are dominated by N-fertilizer with some possible influence of atmospheric NO-3 and, to a much lesser extent, human and/or animal waste. Differences in the isotopic composition of NO-3 and some of the chemical characteristics were observed during the four consecutive seasons in which spring water samples were collected. Isotopic values for ??15N and ??18O of the NO-3 ranged from 3.2??? to 19.1??? and from 7.2??? to 18.7???, respectively. The trend of ??15N and ??18O data for NO-3 also indicated that a significant degree of denitrification is occurring in the shallow karst hydrologic system (within the soil zone, the epikarst and the shallow karst aquifer) prior to discharging to springs. ?? 2001 Elsevier Science B.V. All

Groundwater vulnerability assessment for the karst aquifer of Tanour and Rasoun spring using EPIK, COP, and travel time methods

NASA Astrophysics Data System (ADS)

Hamdan, Ibraheem; Sauter, Martin; Margane, Armin; Ptak, Thomas; Wiegand, Bettina

2016-04-01

Key words: Karst, groundwater vulnerability, EPIK, COP, travel time, Jordan. Karst aquifers are especially sensitive to short-lived contaminants because of fast water travel times and a low storage capacity in the conduit system. Tanour and Rasoun karst springs located around 75 km northwest of the city of Amman in Jordan represent the main domestic water supply for the surrounding villages. Both springs suffer from pollution events especially during the winter season, either by microbiological contamination due to wastewater leakage from septic tanks or by wastewater discharge from local olive oil presses. To assess the vulnerability of the karst aquifer of Tanour and Rasoun spring and its sensitivity for pollution, two different intrinsic groundwater vulnerability methods were applied: EPIK and COP. In addition, a travel time vulnerability method was applied to determine the time water travels from different points in the catchment to the streams, as a function of land surface gradients and presumed lateral flow within the epikarst. For the application of the COP and EPIK, a detailed geological survey was carried out to determine karst features and the karst network development within the catchment area. In addition, parameters, such as soil data, long term daily precipitation data, land use and topographical data were collected. For the application of the travel time vulnerability method, flow length, hydraulic conductivity, effective porosity, and slope gradient was used in order to determining the travel time in days. ArcGIS software was used for map preparation. The results of the combined vulnerability methods (COP, EPIK and travel time) show a high percentage of "very high" to "moderate" vulnerable areas within the catchment area of Tanour and Rasoun karst springs. Therefore, protection of the catchment area of Tanour and Rasoun springs from pollution and proper management of land use types is urgently needed to maintain the quality of drinking water in the

Research in karst aquifers developed in high-mountain areas combining KARSYS models with springs discharge records. Picos de Europa, Spain

NASA Astrophysics Data System (ADS)

Ballesteros, Daniel; Meléndez, Mónica; Malard, Arnauld; Jiménez-Sánchez, Montserrat; Heredia, Nemesio; Jeannin, Pierre-Yves; García-Sansegundo, Joaquín

2014-05-01

The study of karst aquifers developed in high-mountain areas is quite complex since the application of many techniques of hydrogeology in these areas is difficult, expensive, and requires many hours of field work. In addition, the access to the study area is usually conditioned by the orography and the meteorological conditions. A pragmatic approach to study these aquifers can be the combination of geometric models of the aquifer with the monitoring of the discharge rate of springs and the meteorological records. KARSYS approach (Jeannin et al. 2013) allows us to elaborate a geometric model of karst aquifers establishing the boundaries of the groundwater bodies, the main drainage axes and providing evidences of the catchment delineation of the springs. The aim of this work is to analyse the functioning of the karst aquifer from the western and central part of the Picos de Europa Mountains (Spain) combining the KARSYS approach, the discharge record from two springs and the meteorological records (rain, snow and temperature). The Picos de Europa (North Spain) is a high-mountains area up to 2.6 km altitude with 2,500 mm/year of precipitations. The highest part of these mountains is covered by snow four to seven months a year. The karst aquifer is developed in Carboniferous limestone which is strongly compartmentalized in, at least, 17 groundwater bodies. The method of work includes: 1) the elaboration of a hydrogeological 3D model of the geometry of the karst aquifers by KARSYS approach, 2) the definition of the springs catchment areas based on the hydrogeological 3D model, 3) the selection of two representative springs emerging from the aquifers to study it, 4) the continuous monitoring of water levels in two karst springs since October 2013, 5) the transformation of the water level values to flow values using height-stream relation curves constructed by measures of the spring discharge, and 5) the comparison of the spring discharge rate records and meteorological

Assessing vulnerability mapping and protection zones of karst spring waters and validating by the joint use of natural and artificial tracers. The case of Auta Spring (Southern Spain)

NASA Astrophysics Data System (ADS)

Marín, Ana Isabel; Mudarra, Matías; Andreo, Bartolomé

2016-04-01

Delineation of protection zones for water supply and implementation of proper land-use practices in surrounding areas are crucial aspects for a sustainable use of valuable drinking water resources. This is even more important in karst aquifers, which are particularly sensitive to contamination, having a very low self-cleaning capacity due to their structure and hydrological behavior. Consequently, specific methodologies adapted to the particular characteristics of karst media are necessary. In this work, an approach for protection zoning of the pilot site of Auta karst spring (southern Spain) is proposed, based on the application of COP+K method for contamination vulnerability and validation of results by natural (organic) tracers of infiltration (NO3-, TOC, intrinsic fluorescence) and by a dye tracer test conducted on June, 2011 (injecting 500 mg uranine). The aquifer drained by Auta spring (8.5 km2) presents a complex geological structure, formed by Jurassic dolostones and limestones highly folded and fractured. Recharge takes place by the infiltration of rainfall through karst landforms and also by losses in an adjacent river when it flows over the carbonate outcrops (dye injection point). Drainage is mainly through several springs located at the southwest, including Auta spring and 5 overflow springs. The source vulnerability map obtained by applying COP+K method can be adopted as the baseline to delineate the protection zones, through the conversion from vulnerability classes to degrees of protection. Dye tracer test and natural tracers of infiltration corroborate that aquifer sectors influenced by the river can be extremely vulnerable to pollution, but also well-developed exokarst features. In fact, slight evidences of pollution have been detected during the study period, with relatively-high NO3- contents and high fluorescence linked to bacteriological activity in Auta spring water. The jointly use of natural and artificial tracers constitute a reliable and

Determining the groundwater potential recharge zone and karst springs catchment area: Saldoran region, western Iran

NASA Astrophysics Data System (ADS)

Karami, Gholam Hossein; Bagheri, Rahim; Rahimi, Fahimeh

2016-12-01

Assessing the groundwater recharge potential zone and differentiation of the spring catchment area are extremely important to effective management of groundwater systems and protection of water quality. The study area is located in the Saldoran karstic region, western Iran. It is characterized by a high rate of precipitation and recharge via highly permeable fractured karstic formations. Pire-Ghar, Sarabe-Babaheydar and Baghe-rostam are three major karstic springs which drain the Saldoran anticline. The mean discharge rate and electrical conductivity values for these springs were 3, 1.9 and 0.98 m3/s, and 475, 438 and 347 μS/cm, respectively. Geology, hydrogeology and geographical information system (GIS) methods were used to define the catchment areas of the major karstic springs and to map recharge zones in the Saldoran anticline. Seven major influencing factors on groundwater recharge rates (lithology, slope value and aspect, drainage, precipitation, fracture density and karstic domains) were integrated using GIS. Geology maps and field verification were used to determine the weights of factors. The final map was produced to reveal major zones of recharge potential. More than 80 % of the study area is terrain that has a recharge rate of 55-70 % (average 63 %). Evaluating the water budget of Saldoran Mountain showed that the total volume of karst water emerging from the Saldoran karst springs is equal to the total annual recharge on the anticline. Therefore, based on the geological and hydrogeological investigations, the catchment area of the mentioned karst springs includes the whole Saldoran anticline.

Microbial Source Tracking in Adjacent Karst Springs.

PubMed

Ohad, Shoshanit; Vaizel-Ohayon, Dalit; Rom, Meir; Guttman, Joseph; Berger, Diego; Kravitz, Valeria; Pilo, Shlomo; Huberman, Zohar; Kashi, Yechezkel; Rorman, Efrat

2015-08-01

Modern man-made environments, including urban, agricultural, and industrial environments, have complex ecological interactions among themselves and with the natural surroundings. Microbial source tracking (MST) offers advanced tools to resolve the host source of fecal contamination beyond indicator monitoring. This study was intended to assess karst spring susceptibilities to different fecal sources using MST quantitative PCR (qPCR) assays targeting human, bovine, and swine markers. It involved a dual-time monitoring frame: (i) monthly throughout the calendar year and (ii) daily during a rainfall event. Data integration was taken from both monthly and daily MST profile monitoring and improved identification of spring susceptibility to host fecal contamination; three springs located in close geographic proximity revealed different MST profiles. The Giach spring showed moderate fluctuations of MST marker quantities amid wet and dry samplings, while the Zuf spring had the highest rise of the GenBac3 marker during the wet event, which was mirrored in other markers as well. The revelation of human fecal contamination during the dry season not connected to incidents of raining leachates suggests a continuous and direct exposure to septic systems. Pigpens were identified in the watersheds of Zuf, Shefa, and Giach springs and on the border of the Gaaton spring watershed. Their impact was correlated with partial detection of the Pig-2-Bac marker in Gaaton spring, which was lower than detection levels in all three of the other springs. Ruminant and swine markers were detected intermittently, and their contamination potential during the wet samplings was exposed. These results emphasized the importance of sampling design to utilize the MST approach to delineate subtleties of fecal contamination in the environment. Copyright © 2015, American Society for Microbiology. All Rights Reserved.

Spring distributions and relationships with land cover and hydrogeologic strata in a karst landscape in Winona County, Minnesota, USA

USGS Publications Warehouse

Williams, M.A.; Vondracek, B.

2010-01-01

Karst aquifers are important groundwater resources, but are vulnerable to contamination due to relatively rapid subsurface transport. Springs, points where the landscape and water table intersect and cold groundwater discharges, link aquifer systems with land surfaces and water bodies. As such, in many regions, they are critical to the viability of lakes, streams and cold-water fish communities. An understanding of where springs are located is important to watershed, fishery and environmental management efforts in karst regions. To better understand spatial distribution of springs and as a potential method for identifying variables that characterize locations of springs for improved land and watershed management, a nearest-neighbor analysis and a discriminant function analysis (DFA) of springs were conducted in Winona County, Minnesota USA, a karst landscape. Nearestneighbor analysis examined the spatial spring distribution. Twenty-two variables describing the locations of springs were analyzed to ascertain their ability to discriminate correct aquifer unit or bedrock unit classification for each spring. Springs were clumped with the highest densities in the lowest elevations. Springs were correctly assigned to aquifer units and bedrock units with eight and 11 landscape variables, respectively. Forest land cover was the only land cover type contributing to spring discrimination. Consideration of upland human activities, particularly in forested areas, on spring discharge along with a better understanding of characteristics describing spring locations could lead to better management activities that locate and protect springs and their important contributions to regional ecohydrology. ?? 2010 Springer-Verlag.

The geochemical characteristics of soil water and epikarst springs and their response to vegetation-soil degradation in a karst area

NASA Astrophysics Data System (ADS)

Xiao, D. A.; Xu, H.

2012-04-01

Samples of soil waters and epi-karst springs in four vegetation types were collected at Maolan nature reserve in Libo county, which including protogenetic arbors, secondary arbor-shrub, shrubs and shrub-grass, to analyze their hydro-geochemical properties and the variations of nutrient elements, and further to illustrate the intrinsic correlations of vegetation, soil, environment changes and their geochemical information. The conclusions have been concluded as follows: (1) The pH of soil waters in the study area varies between 5.32 and 7.93, with a mean value of 6.78, and the conductivity changes between 31.82 and 353.65 μS/cm, with a mean value of 126.19 μS/cm. Both descend as the vegetation degrades. The hydro-chemistry of soil waters are Ca- HCO3-, and their ions mainly consist of Ca2+, Mg2+, HCO3-, SO42-. Ca2+, Mg2+, HCO3-are very sensitive to vegetations degradation. Ion contents are high in rain seasons and low in dry ones. (2) The pH of surface karst springs in the study area vary between 6.7 and 8.42, with a mean value of 7.65, and the conductivity between 125.6 and 452 μS/cm, with a mean value of 288.09 μS/cm. The hydro-chemistry of surface karst springs are Ca- HCO3-. HCO3-and SO42-are the main anions while Ca2+and Mg2+as main cations. The chemical properties and geochemical process of surface springs are mainly controlled by the solubility equilibrium of carbonate rocks, thus not sensitive to vegetation degradations. (3) All the calcite saturation indices of soil waters in four vegetation types are below 0, while most indices of surface karst springs are above 0, demonstrating greater denudation of soil waters than surface karst springs. As soil waters flow to surface springs, the partial pressure of CO2decreases, the denudation of water lessens, and saturation index, Ca2+, HCO3-, consequently, pH and conductivity increase. (4) Inorganic nitrogen in soil waters exist mainly as N-NO3- and N-NH4+, accounting ~ 95% of the 3 Ns. As vegetation degrades

Classification of Thermal Patterns at Karst Springs and Cave Streams

USGS Publications Warehouse

Luhmann, A.J.; Covington, M.D.; Peters, Albert J.; Alexander, S.C.; Anger, C.T.; Green, J.A.; Runkel, Anthony C.; Alexander, E.C.

2011-01-01

Thermal patterns of karst springs and cave streams provide potentially useful information concerning aquifer geometry and recharge. Temperature monitoring at 25 springs and cave streams in southeastern Minnesota has shown four distinct thermal patterns. These patterns can be divided into two types: those produced by flow paths with ineffective heat exchange, such as conduits, and those produced by flow paths with effective heat exchange, such as small fractures and pore space. Thermally ineffective patterns result when water flows through the aquifer before it can equilibrate to the rock temperature. Thermally ineffective patterns can be either event-scale, as produced by rainfall or snowmelt events, or seasonal scale, as produced by input from a perennial surface stream. Thermally effective patterns result when water equilibrates to rock temperature, and the patterns displayed depend on whether the aquifer temperature is changing over time. Shallow aquifers with seasonally varying temperatures display a phase-shifted seasonal signal, whereas deeper aquifers with constant temperatures display a stable temperature pattern. An individual aquifer may display more than one of these patterns. Since karst aquifers typically contain both thermally effective and ineffective routes, we argue that the thermal response is strongly influenced by recharge mode. ?? 2010 The Author(s). Journal compilation ?? 2010 National Ground Water Association.

Reply to Discussion by Zekai Șen on "Modeling karst spring hydrograph recession based on head drop at sinkholes"

NASA Astrophysics Data System (ADS)

Field, Malcolm S.; Goldscheider, Nico; Li, Guangquan

2018-02-01

We are pleased to learn that the model presented in our paper dealing with the "modeling karst spring hydrograph recession based on head drop at sinkholes," published in the Journal of Hydrology in 2016 (Li et al., 2016), is of interest to readers of this journal. Our study presented a new non-exponential model for assessing spring hydrographs in terms of head drop at flooded sinkholes, as an extension of an earlier model proposed by Li and Field (2014). In both papers, we used two spring hydrographs measured in the St. Marks Karst Watershed in northwest Florida to test the applicability and to verify the validity of our models.

Geochemical and statistical evidence of recharge, mixing, and controls on spring discharge in an eogenetic karst aquifer

NASA Astrophysics Data System (ADS)

Moore, Paul J.; Martin, Jonathan B.; Screaton, Elizabeth J.

2009-10-01

SummaryInformation about sources of recharge, distributions of flow paths, and the extent of water-rock reactions in karst aquifers commonly result from monitoring spring chemistry and discharge. To investigate the relationship between spring characteristics and the complexities of karst aquifers, we couple variations in surface- and groundwater chemistry to physical conditions including river stage, precipitation, and evapotranspiration (ET) within a sink-rise system through a 6-km portion of the Upper Floridan aquifer (UFA) in north-central Florida. Principal component analysis (PCA) of time series major-element compositions suggests that at least three sources of water affect spring discharge, including allogenic recharge into a swallet, diffuse recharge through a thin vadose zone, and water upwelling from deep within the aquifer. The deep-water source exerts the strongest influence on water chemistry by providing a majority of Na +, Mg 2+, K +, Cl -, and SO42- to the system. Anomalously high temperature at one of several monitoring wells reflects vertical flow of about 1 m/year. Mass-balance calculations suggest diffuse recharge and deep-water upwelling can provide up to 50% of the spring discharge; however, their contributions depend on head gradients between the conduit and surrounding aquifer matrix, which are influenced by variations in precipitation, ET, and river stage. Our results indicate that upwelling from deep flow paths may provide significant contributions of water to spring discharge, and that monitoring only springs limits interpretations of karst systems by masking critical components of the aquifer, such as water sources and flow paths. These results also suggest the matrix in eogenetic aquifers is a major pathway for flow even in a system dominated by conduits.

Electronic structure of BaNi2As2

NASA Astrophysics Data System (ADS)

Zhou, Bo; Xu, Min; Zhang, Yan; Xu, Gang; He, Cheng; Yang, L. X.; Chen, Fei; Xie, B. P.; Cui, Xiao-Yu; Arita, Masashi; Shimada, Kenya; Namatame, Hirofumi; Taniguchi, Masaki; Dai, X.; Feng, D. L.

2011-01-01

BaNi2As2, with a first-order phase transition around 131 K, is studied by the angle-resolved photoemission spectroscopy. The measured electronic structure is compared to the local-density approximation calculations, revealing similar large electronlike bands around M¯ and differences along Γ¯-X¯. We further show that the electronic structure of BaNi2As2 is distinct from that of the sibling iron pnictides. Particularly, there is no signature of band folding, indicating no collinear spin-density-wave-related magnetic ordering. Moreover, across the strong first-order phase transition, the band shift exhibits a hysteresis, which is directly related to the significant lattice distortion in BaNi2As2.

Quantification of frequency-components contributions to the discharge of a karst spring

NASA Astrophysics Data System (ADS)

Taver, V.; Johannet, A.; Vinches, M.; Borrell, V.; Pistre, S.; Bertin, D.

2013-12-01

of the input variables, here the frequency components, over output signal. Applied to the Lez karst aquifer, the combination of frequency decomposition and knowledge extraction improves knowledge on hydrological behavior. Both models and both extraction methods were applied and assessed using a fictitious reference model. Discussion is proposed in order to analyze efficiency of the methods compared to in situ measurements and tracing. [1] D. Labat et al. 'Rainfall-runoff relations for karst springs. Part II: continuous wavelet and discrete orthogonal multiresolution' In J of Hydrology, Vol. 238, 2000, pp. 149-178. [2] A. Johannet et al. 'Prediction of Lez Spring Discharge (Southern France) by Neural Networks using Orthogonal Wavelet Decomposition'.IJCNN Proceedings Brisbane 2012. [3] L. Kong A Siou et al. 'Modélisation hydrodynamique des karsts par réseaux de neurones : Comment dépasser la boîte noire. (Karst hydrodynamic modelling using artificial neural networks: how to surpass the black box ?)'. Proceedings of the 9th conference on limestone hydrogeology,2011 Besançon, France.

Overexploitation of karst spring as a measure against water scarcity.

PubMed

Dimkić, Dejan; Dimkić, Milan; Soro, Andjelko; Pavlović, Dusan; Jevtić, Goran; Lukić, Vladimir; Svrkota, Dragan

2017-09-01

Water scarcity, especially in the hydrologically critical part of the year, is a problem often present in many cities and regions, particularly in arid and sub-arid areas. Climate change and human water demand compound the problem. This paper discusses a climate change adaptation measure-the possibility of karst spring overexploitation, where there is a siphon-shaped cavity inside the mountain. The pilot area is near the city of Niš, where a decreasing precipitation trend has already been observed and is expected to continue in the future. The paper also presents some basic information related to the pilot area and undertaken investigations. The project, successfully implemented in 2004, has provided the city of Niš with an additional amount of 200 l/s of spring water during the most critical part of the year.

Karst flash floods: an example from the Dinaric karst (Croatia)

NASA Astrophysics Data System (ADS)

Bonacci, O.; Ljubenkov, I.; Roje-Bonacci, T.

2006-03-01

Flash floods constitute one of the deadliest and costliest natural disasters worldwide. This paper explains the karst flash flood phenomenon, which represents a special kind of flash flood. As the majority of flash floods karst flash floods are caused by intensive short-term precipitation in an area whose surface rarely exceeds a few square kilometres. The characteristics of all flash floods are their short duration, small areal extent, high flood peaks and rapid flows, and heavy loss of life and property. Karst flash floods have specific characteristics due to special conditions for water circulation, which exist in karst terrains. During karst flash floods a sudden rise of groundwater levels occurs, which causes the appearance of numerous, unexpected, abundant and temporary karst springs. This paper presents in detail an example of a karst flash flood in the Marina bay (Dinaric karst region of Croatia), which occurred in December 2004.

An examination of short-term variations in water quality at a karst spring in Kentucky

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ryan, M.; Meiman, J.

1996-01-01

Water quality at many karst springs undergoes very high amplitude but relatively brief degradation following influxes of runoff. Accurately recording transient variations requires more rigorous sampling strategies than traditional methods. A pilot study to determine the usefulness of high-frequency, flow-dependent sampling strategies, combined with coincidental quantitative dye tracer tests, was implemented in the Big Spring Ground-Water Basin in Mammoth Cave National Park, Kentucky. Data recorded following two separate runoff events showed that the concentrations of two nonpoint source pollutants, fecal coliform bacteria and suspended sediment, greatly exceeded prerunoff event values for very short periods of time. A phreatic conduit segment,more » calculated at 17 million liters in volume, instantaneously propagated head changes, caused by direct runoff entering the aquifer, from the ground-water inputs to Big Spring. A significant delay between the initial increases in discharge and the arrival of direct runoff, as indicated by a steady decrease in specific conductance, represented the time required to displace this volume of phreatic water. The delay showed that sampling a karst spring only during peak discharge would be an unreliable sampling method. Runoff from two different subcatchments was tagged with tracer dye and the timing of the passage of the resultant dye clouds through Big Spring were compared to water quality variations. Distinct lag times between the arrival of direct runoff at Big Spring and the bacteria and suspended sediment waveforms were shown through the concurrent quantitative tracer tests to be related to the areal distribution of land-cover type within the basin.« less

Dynamic Vulnerability of Karst Systems: a Concept to understand qualitative and quantitative Aspects of Karst springs due to Changes in Groundwater Recharge

NASA Astrophysics Data System (ADS)

Huggenberger, P.; Butscher, C.; Epting, J.; Auckenthaler, A.

2015-12-01

Karst groundwater resources represent valuable water resources, which may be affected by different types of pollution and changes of groundwater recharge by climate change. In many parts of Europe, it has been predicted that record-breaking heat waves, such as the one experienced in 2003 and 2015, will become more frequent. At the same time, even as summers become drier, the incidence of severe precipitation events could increase. What is the influence such changes to the quantitative and qualitative aspects of Karst groundwater systems? A factor to be considered in conjunction with groundwater quality is the vulnerability of the resource, which is defined as the sensitivity of a groundwater system to pollution. Intrinsic vulnerability refers to the sensitivity to pollution when considering only natural, geogenic conditions without the effects of human activities such as contaminant release. Intrinsic vulnerability depends on the recharge conditions, which are dependent on the surface and subsurface structure and on precipitation and evaporation patterns. The latter are highly time dependent. Therefore, our groundwater vulnerability concept also includes dynamic aspects of the system, the variations of spatial and temporal components. We present results of combined monitoring and modelling experiments of several types of Karst systems in the Tabular and the Folded Jura of NW Switzerland. The recharge, conduit flow, diffuse flow(RCD) rainfall-discharge model "RCD-seasonal" was used to simulate the discharge and substance concentration of several spring. This lumped parameter model include: the recharge system (soil and epikarst system), the conduit flow system, and the diffuse flow system. The numerically derived Dynamic Vulnerability Index (DVI) can indicate qualitative changes of spring water with sufficient accuracy to be used for drinking water management. In addition, the results obtained from the test sites indicate a decrease in short-lived contaminants in

[Transportation and sources of the suspended particle in a karst spring during a storm event].

PubMed

Yang, Ping-Heng; Liu, Zi-Qi; He, Qiu-Fang

2012-10-01

Storm periods are the crucial stage to reveal input and outlet of material and energy in groundwater system. Jiangjia spring, the outlet of Qingmuguan groundwater system, was taken as an example. Distribution of suspended particle in the Jiangjia spring was continuously monitored. Supported by hydrochemical data, characteristics and sources of the suspended particle in the karst groundwater system were investigated. Results show that the number of suspended particle in size of 0-11 microm abruptly increased in the channel of Jiangjia spring at the beginning of rainfall occurred. It indicates the suspended particle was derived from allochthonous material. While the groundwater was recharged by karst fissure, the number of suspended particle in size of 0-11 microm sharply raised, which shows that the suspended particle was autochthonous. Finally, the number of suspended particle in size of 0-4 microm elevated due to the entire groundwater watershed recharged by rainfall and dilution effect occurring again, suggesting the suspended particle was derived from allochthonous material. Owing to the intrinsic hydrogeological settings and rainfall intensity, the threshold of size for the suspended particle was 4 pm in Qingmuguan groundwater system. It probably was a high practical significance to indicate the groundwater was whether polluted by microbe or not.

Invasive vascular plant species of limnocrenic karst springs in Poland

NASA Astrophysics Data System (ADS)

Spałek, Krzysztof

2015-04-01

Natural water reservoirs are very valuable floristic sites in Poland. Among them, the most important for preservation of biodiversity of flora are limnocrenic karst springs. The long-term process of human pressure on habitats of this type caused disturbance of their biological balance. Changes in the water regime, industrial development and chemisation of agriculture, especially in the period of last two hundred years, led to systematic disappearance of localities of many plant species connected with rare habitats and also to appear numerous invasive plant species. They are: Acorus calamus, Echinocystis lobata, Elodea canadensis, Erechtites hieraciifolia, Impatiens glandulifera, Solidago canadensis, S. gigantea and S. graminifolia. Fielworks were conducted in 2010-2014.

Long distance seawater intrusion through a karst conduit network in the Woodville Karst Plain, Florida

NASA Astrophysics Data System (ADS)

Xu, Zexuan; Bassett, Seth Willis; Hu, Bill; Dyer, Scott Barrett

2016-08-01

Five periods of increased electrical conductivity have been found in the karst conduits supplying one of the largest first magnitude springs in Florida with water. Numerous well-developed conduit networks are distributed in the Woodville Karst Plain (WKP), Florida and connected to the Gulf of Mexico. A composite analysis of precipitation and electrical conductivity data provides strong evidence that the increases in conductivity are directly tied to seawater intrusion moving inland and traveling 11 miles against the prevailing regional hydraulic gradient from from Spring Creek Spring Complex (SCSC), a group of submarine springs at the Gulf Coast. A geochemical analysis of samples from the spring vent rules out anthropogenic contamination and upwelling regional recharge from the deep aquifer as sources of the rising conductivity. The interpretation is supported by the conceptual model established by prior researchers working to characterize the study area. This paper documents the first and longest case of seawater intrusion in the WKP, and also indicates significant possibility of seawater contamination through subsurface conduit networks in a coastal karst aquifer.

Long distance seawater intrusion through a karst conduit network in the Woodville Karst Plain, Florida.

PubMed

Xu, Zexuan; Bassett, Seth Willis; Hu, Bill; Dyer, Scott Barrett

2016-08-25

Five periods of increased electrical conductivity have been found in the karst conduits supplying one of the largest first magnitude springs in Florida with water. Numerous well-developed conduit networks are distributed in the Woodville Karst Plain (WKP), Florida and connected to the Gulf of Mexico. A composite analysis of precipitation and electrical conductivity data provides strong evidence that the increases in conductivity are directly tied to seawater intrusion moving inland and traveling 11 miles against the prevailing regional hydraulic gradient from from Spring Creek Spring Complex (SCSC), a group of submarine springs at the Gulf Coast. A geochemical analysis of samples from the spring vent rules out anthropogenic contamination and upwelling regional recharge from the deep aquifer as sources of the rising conductivity. The interpretation is supported by the conceptual model established by prior researchers working to characterize the study area. This paper documents the first and longest case of seawater intrusion in the WKP, and also indicates significant possibility of seawater contamination through subsurface conduit networks in a coastal karst aquifer.

Long distance seawater intrusion through a karst conduit network in the Woodville Karst Plain, Florida

PubMed Central

Xu, Zexuan; Bassett, Seth Willis; Hu, Bill; Dyer, Scott Barrett

2016-01-01

Five periods of increased electrical conductivity have been found in the karst conduits supplying one of the largest first magnitude springs in Florida with water. Numerous well-developed conduit networks are distributed in the Woodville Karst Plain (WKP), Florida and connected to the Gulf of Mexico. A composite analysis of precipitation and electrical conductivity data provides strong evidence that the increases in conductivity are directly tied to seawater intrusion moving inland and traveling 11 miles against the prevailing regional hydraulic gradient from from Spring Creek Spring Complex (SCSC), a group of submarine springs at the Gulf Coast. A geochemical analysis of samples from the spring vent rules out anthropogenic contamination and upwelling regional recharge from the deep aquifer as sources of the rising conductivity. The interpretation is supported by the conceptual model established by prior researchers working to characterize the study area. This paper documents the first and longest case of seawater intrusion in the WKP, and also indicates significant possibility of seawater contamination through subsurface conduit networks in a coastal karst aquifer. PMID:27557803

Hydrogeology of northern Sierra de Chiapas, Mexico: a conceptual model based on a geochemical characterization of sulfide-rich karst brackish springs

NASA Astrophysics Data System (ADS)

Rosales Lagarde, Laura; Boston, Penelope J.; Campbell, Andrew R.; Hose, Louise D.; Axen, Gary; Stafford, Kevin W.

2014-09-01

Conspicuous sulfide-rich karst springs flow from Cretaceous carbonates in northern Sierra de Chiapas, Mexico. This is a geologically complex, tropical karst area. The physical, geologic, hydrologic and chemical attributes of these springs were determined and integrated into a conceptual hydrogeologic model. A meteoric source and a recharge elevation below 1,500 m are estimated from the spring-water isotopic signature regardless of their chemical composition. Brackish spring water flows at a maximum depth of 2,000 m, as inferred from similar chemical attributes to the produced water from a nearby oil well. Oil reservoirs may be found at depths below 2,000 m. Three subsurface environments or aquifers are identified based on the B, Li+, K+ and SiO2 concentrations, spring water temperatures, and CO2 pressures. There is mixing between these aquifers. The aquifer designated Local is shallow and contains potable water vulnerable to pollution. The aquifer named Northern receives some brackish produced water. The composition of the Southern aquifer is influenced by halite dissolution enhanced at fault detachment surfaces. Epigenic speleogenesis is associated with the Local springs. In contrast, hypogenic speleogenesis is associated with the brackish sulfidic springs from the Northern and the Southern environments.

Karst hydrology and chemical contamination

DOE Office of Scientific and Technical Information (OSTI.GOV)

Field, M.S.

1993-01-01

Ground-water flow in karst aquifers is very different from flow in granular or fractured aquifers. Chemical contamination may be fed directly to a karst aquifer via overland flow to a sinkhole with little or no attenuation and may contaminate downgradient wells, springs, and sinkholes within a few hours or a few days. Contaminants may also become temporarily stored in the epikarstic zone for eventual release to the aquifer. Flood pulses may flush the contaminants to cause transiently higher levels of contamination in the aquifer and discharge points. The convergent nature of flow in karst aquifers may result in contaminants becomingmore » concentrated in conduits. Once contaminants have reached the subsurface conduits, they are likely to be rapidly transported to spring outlets. Traditional aquifer remediation techniques for contaminated aquifers are less applicable to karst aquifers.« less

Determination of the recharge area and salinization degree of karst springs in the Lamas Basin (Turkey).

PubMed

Yüce, Galip

2005-12-01

The Lamas Basin is an area covering approximately 4,400 km(2) situated on the eastern Mediterranean coast of Turkey covered with highly karstified limestone and dolomitic limestone from the Miocene and Mesozoic age, respectively. Owing to the area's low karstification basement, groundwater in the karst aquifer circulates deep from the surface towards the springs along the coast as well as to the submarine springs. This study aims working out the salinization level and recharge characteristics of the Lamas Basin using environmental isotopes techniques. In the study, the data collected previously to discover, in general terms, the groundwater characteristics within the area are reanalyzed to fulfil the purpose of the study. In conclusion, it is found that the down gradient karst springs discharging along the Mediterranean coast mostly contain groundwater contributions from higher altitudes with depleted delta(18)O and delta(2)H compositions. The delta(18)O-altitude effect was determined as approximately-0.12 per thousand/100 m which may indicate sea-spray intrusion towards inland. As a result, the salinization level of coastal springs changes ranging between 1.2 % and 17.0 %. Owing to the seawater encroachment, Ca-HCO(3) water type changes to Na-HCO(3) or Na-Cl water by the cation exchange during the dry period. As the unique freshwater potential extends along the coastal area, the groundwater production should be exploited in a way that seawater encroachment is kept at minimum.

Use of two artificial sweeteners, cyclamate and acesulfame, to identify and quantify wastewater contributions in a karst spring.

PubMed

Zirlewagen, Johannes; Licha, Tobias; Schiperski, Ferry; Nödler, Karsten; Scheytt, Traugott

2016-03-15

The identification and differentiation of different sources of contamination are crucial aspects of risk assessment in water resource protection. This is especially challenging in karst environments due to their highly heterogeneous flow fields. We have investigated the use of two artificial sweeteners, cyclamate and acesulfame, as an indicator set for contamination by wastewater within the rural catchment of a karst spring. The catchment was investigated in detail to identify the sources of artificial sweeteners and quantify their impact. Spring water was analysed following two different but typical recharge events: (1) a rain-on-snow event in winter, when no wastewater overflow from the sewer system was observed, and (2) an intense rainfall event in summer triggering an overflow from a stormwater detention basin. Acesulfame, which is known to be persistent, was quantified in all spring water samples. Its concentrations decreased after the winter event with no associated wastewater spillage but increased during the summer event following a recent input of untreated wastewater. Cyclamate, which is known to be degradable, was only detected following the wastewater inflow incident. The cyclamate signal matched very well the breakthrough of faecal indicator bacteria, indicating a common origin. Knowing the input function, cyclamate was used quantitatively as a tracer in transport modelling and the impact of 'combined sewer overflow' on spring water quality was quantified. Signals from artificial sweeteners were compared to those from bulk parameters (discharge, electrical conductivity and turbidity) and also to those from the herbicides atrazine and isoproturon, which indicate 'old' and 'fresh' flow components, respectively, both originating from croplands. High concentration levels of the artificial sweeteners in untreated wastewater (cyclamate and acesulfame) and in treated wastewater (acesulfame only) make them powerful indicators, especially in rural settings

A study of the characteristics of karst groundwater circulation based on multi-isotope approach in the Liulin spring area, North China.

PubMed

Zang, Hongfei; Zheng, Xiuqing; Qin, Zuodong; Jia, Zhenxing

2015-01-01

Due to the significance of karst groundwater for water supply in arid and semi-arid regions, the characteristics of the karst groundwater flow system in the Liulin spring area, North China, are analysed through isotopic tracing (δ(2)H, δ(18)O, δ(13)C and (3)H) and dating approaches ((14)C). The results show that the primary recharge source of karst groundwater is precipitation. Evaporation during dropping and infiltration of rainfall results in a certain offset in the values of δ(2)H and δ(18)O in groundwater samples from the global meteoric water line (GMWL) and the local meteoric water line (LMWL). The altitudes of the recharge region calculated by δ(18)O range from 1280 to 2020 m above sea level, which is consistent with the altitudes of the recharge area. The Liulin spring groups could be regarded as the mixing of groundwater with long and short flow paths at a ratio of 4:1. In the upgradient of the Liulin spring, the groundwater represents modern groundwater features and its [Formula: see text] is mainly derived from dissolution of soil CO(2), while in the downgradient of the Liulin spring, the (14)C age of dissolved inorganic carbon (DIC) in groundwater shows an apparent increase and [Formula: see text] is mainly derived from the dissolution of carbonate rocks. The mean flow rate calculated by (14)C ages of DIC between IS10 and IS12 is 1.23 m/year.

Runoff generation in karst catchments: multifractal analysis

NASA Astrophysics Data System (ADS)

Majone, Bruno; Bellin, Alberto; Borsato, Andrea

2004-07-01

Time series of hydrological and geochemical signals at two karst springs, located in the Dolomiti del Brenta region, near Trento, Italy, are used to infer how karst catchments work internally to generate runoff. The data analyzed include precipitation, spring flow and electric conductivity of the spring water. All the signals show the signature of multifractality but with different intermittency and non-stationarity. In particular, precipitation and spring flow are shown to have nearly the same degree of non-stationarity and intermittency, while electric conductivity, which mimics the travel time distribution of water in the karst system, is less intermittent and smoother than both spring flow and precipitations. We found that spring flow can be obtained from precipitation through fractional convolution with a power law transfer function. An important result of our study is that the probability distribution of travel times is inconsistent with the advection dispersion equation, while it supports the anomalous transport model. This result is in line with what was observed by Painter et al. [Geophys. Res. Lett. 29 (2002) 21.1] for transport in fractured rocks.

Karst development in central Butler County, Kansas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bain, B.A.

1993-02-01

Research was conducted to study the geology and hydrology of sinkholes, springs, and caves formed in Lower Permian, Fort Riley Limestone, located in central Butler County, Kansas. The goal was to better understand the controlling factors of these karst features and the processes that produce them in a portion of Kansas that is undergoing rapid population growth and increased groundwater usage. Research was accomplished in seven phases: literature search, locating karst features, measuring bedrock fracture joint trends, surveying major caves, estimating discharge of springs, dye tracing, and water chemistry analysis. Recognizable karst landforms within the study area were plotted ontomore » a base map to demonstrate their geographic, geologic, and hydrologic relationships. Karst features identified were 125 sinkholes, a major cave system composed of at least three enterable cave segments, and one large spring. The karst terrain found within the study area is clearly a system of interrelated features and processes. Long-term solution of the bedrock allows karst features to form, joints and bedding planes to enlarge, and creates an efficient network of subsurface drainage. Factors that control karst development in the study area are lithology, thickness, and dip of the bedrock; presence of well defined joints and bedding planes; relatively level topography; nearby entrenched river valleys; lack of thick surficial cover; and climate. Of these influences, solutional activity at joints plays a major role in the formation of sinkholes and cave passages; however, a complex combination of all the controlling factors is responsible for the present, unique, and dynamic karst system.« less

Time-series variations in CFC and 3H/3He ages in springs discharging from an eogenetic karst aquifer (Invited)

NASA Astrophysics Data System (ADS)

Martin, J. B.; Kurz, M. J.; Khadka, M. B.; Cohen, M. J.

2013-12-01

One of the hallmarks of karst aquifers is rapid mixing between surface water and groundwater, which results in changes in flow and water chemistry at springs. Aquifers with little matrix porosity (telogenetic karst) tend to respond to storm events within days to weeks (e.g., are flashy) while aquifers characterized by elevated matrix porosity (eogenetic karst) may take months or years to respond. This response time is an important control on remediation of storm-derived contaminants as well as the magnitude of water-rock reactions that may result from mixing of surface water and groundwater with different compositions. Responses of flashy springs may be observed through time-series measurements of various solute compositions of the discharge, but response at springs discharging from eogenetic aquifers are difficult to observe because the chemical composition of the recharged storm water may be altered during its residence in the subsurface. For these aquifers, conservative tracers such as chlorofluorocarbon and 3H/3He ratios may provide useful information on the mixing, residence time, and variation in the average age of discharged water. We are testing this hypothesis at six springs discharging from the Floridan Aquifer to the Ichetucknee River in north Florida. Samples were first collected September 3, 2009 during record low flow when the river was discharging 7.2 m3/sec and subsequently after about 400 mm of rain fell over the springshed from June 23 to 26, 2012 during Tropical Storm Debby. Following the storm, samples were collected July 27, 2012 (all six springs) when flow had increased to 10.5 m3/sec. Three of the six springs were sampled during the recession on October 25, 2012 (Q = 10.3 m3/sec), February 14, 2013 (Q = 8.7 m3/sec), and May 16, 2013 (Q = 8.6 m3/sec). CFC dates are available now for all sampling times but 3H/3He dates are only available through October 25, 2012. The two different tracers yield conflicting results with CFC ages generally

Dissolved oxygen fluctuations in karst spring flow and implications for endemic species: Barton Springs, Edwards aquifer, Texas, USA

USGS Publications Warehouse

Mahler, Barbara J.; Bourgeais, Renan

2013-01-01

Karst aquifers and springs provide the dissolved oxygen critical for survival of endemic stygophiles worldwide, but little is known about fluctuations of dissolved oxygen concentrations (DO) and factors that control those concentrations. We investigated temporal variation in DO at Barton Springs, Austin, Texas, USA. During 2006–2012, DO fluctuated by as much as a factor of 2, and at some periods decreased to concentrations that adversely affect the Barton Springs salamander (Eurycea sorosum) (≤4.4 mg/L), a federally listed endangered species endemic to Barton Springs. DO was lowest (≤4.4 mg/L) when discharge was low (≤1 m3/s) and spring water temperature was >21 °C, although not at a maximum; the minimum DO recorded was 4.0 mg/L. Relatively low DO (3/s) and maximum T (22.2 °C). A four-segment linear regression model with daily data for discharge and spring water temperature as explanatory variables provided an excellent fit for mean daily DO (Nash–Sutcliffe coefficient for the validation period of 0.90). DO also fluctuated at short-term timescales in response to storms, and DO measured at 15-min intervals could be simulated with a combination of discharge, spring temperature, and specific conductance as explanatory variables. On the basis of the daily-data regression model, we hypothesize that more frequent low DO corresponding to salamander mortality could result from (i) lower discharge from Barton Springs resulting from increased groundwater withdrawals or decreased recharge as a result of climate change, and (or) (ii) higher groundwater temperature as a result of climate change.

Determination of groundwater travel time in a karst aquifer by stable water isotopes, Tanour and Rasoun spring (Jordan)

NASA Astrophysics Data System (ADS)

Hamdan, Ibraheem; Wiegand, Bettina; Sauter, Martin; Ptak, Thomas

2016-04-01

Key words: karst aquifers, stable isotopes, water travel time, Jordan. Tanour and Rasoun karst springs are located about 75 kilometers northwest of the city of Amman in Jordan. The aquifer is composed of Upper Cretaceous limestone that exhibits a moderate to high degree of karstification. The two springs represent the main drinking water resources for the surrounding villages. The yearly water production is about 1,135,000 m3/yr for Tanour spring and 125,350 m3/yr for Rasoun spring (MWI 2015). Due to contamination from microbiological pollution (leakage of wastewater from septic tanks) or infiltration of wastewater from local olive presses, drinking water supply from the two springs is frequently interrupted. From November 2014 through March 2015, spring water samples were collected from Tanour and Rasoun spring for the analysis of stable hydrogen and oxygen isotopes to investigate spring response to precipitation and snowmelt events. Both Tanour and Rasoun spring show a fast response to precipitation and snowmelt events, implying short water travel times. Based on the variation of δ 18O and δ 2H in spring discharge, the average maximum water travel time is in the order of 8 days for Tanour spring and 6 days for Rasoun spring. Due to fast water travel times, Tanour and Rasoun spring can be considered as highly vulnerable to pollutants. δ 18O and δ 2H values of Tanour and Rasoun springs parallel other monitored parameter like water temperature, turbidity, electrical conductivity and spring discharge. In addition, a high turbidity peak was monitored in Tanour spring during a pollution event from olive mills wastewater (Hamdan et al., 2016; Hamdan, in prep.). The fast response in both Tanour and Rasoun springs to precipitation events requires monitoring potential sources of pollution within the catchment area. References: MWI (Ministry of Water and Irrigation) (2015) Monthly Production values for Tanour and Rasoun Springs for the time period between 1996 and 2014

Transport of agricultural contaminants through karst soil

USDA-ARS?s Scientific Manuscript database

Karst landscapes are common in many agricultural regions in the US. Well-developed karst landscapes are characterized by shallow soils, sinkholes, sinking streams, underground conduits, and springs. In these landscapes surface runoff is minimal and most recharge enters the subsurface relatively quic...

Hydrological response of karst systems to large-scale climate variability for different catchments of the French karst observatory network INSU/CNRS SNO KARST

NASA Astrophysics Data System (ADS)

Massei, Nicolas; Labat, David; Jourde, Hervé; Lecoq, Nicolas; Mazzilli, Naomi

2017-04-01

The french karst observatory network SNO KARST is a national initiative from the National Institute for Earth Sciences and Astronomy (INSU) of the National Center for Scientific Research (CNRS). It is also part of the new french research infrastructure for the observation of the critical zone OZCAR. SNO KARST is composed by several karst sites distributed over conterminous France which are located in different physiographic and climatic contexts (Mediterranean, Pyrenean, Jura mountain, western and northwestern shore near the Atlantic or the English Channel). This allows the scientific community to develop advanced research and experiments dedicated to improve understanding of the hydrological functioning of karst catchments. Here we used several sites of SNO KARST in order to assess the hydrological response of karst catchments to long-term variation of large-scale atmospheric circulation. Using NCEP reanalysis products and karst discharge, we analyzed the links between large-scale circulation and karst water resources variability. As karst hydrosystems are highly heterogeneous media, they behave differently across different time-scales : we explore the large-scale/local-scale relationships according to time-scales using a wavelet multiresolution approach of both karst hydrological variables and large-scale climate fields such as sea level pressure (SLP). The different wavelet components of karst discharge in response to the corresponding wavelet component of climate fields are either 1) compared to physico-chemical/geochemical responses at karst springs, or 2) interpreted in terms of hydrological functioning by comparing discharge wavelet components to internal components obtained from precipitation/discharge models using the KARSTMOD conceptual modeling platform of SNO KARST.

Water quality deterioration at a karst spring (Gallusquelle, Germany) due to combined sewer overflow: evidence of bacterial and micro-pollutant contamination

NASA Astrophysics Data System (ADS)

Heinz, B.; Birk, S.; Liedl, R.; Geyer, T.; Straub, K. L.; Andresen, J.; Bester, K.; Kappler, A.

2009-04-01

The concurrent use of karst aquifers as drinking water resources and receptors of combined sewer overflow lacking appropriate pre-treatment may cause conflicts between drinking water supply and storm water management. A storm water tank (SWT) for combined wastewater is identified as the source of sporadic contamination of a karst spring (Gallusquelle, “Schwäbische Alb”, SW Germany) used for public water supply. Spring water quality was examined by routine and event sampling and by evaluating physicochemical and microbiological parameters. The total number of microbial colonies growing at 20°C and the number of Escherichia coli colonies rose to values up to four orders of magnitude higher than background, 2-5 days after overflow of the SWT. High concentrations of chloride, sodium, and total organic carbon (TOC) and high values of turbidity coincide with this increase. However, high bacterial contamination is also observed while turbidity and TOC are low. Several wastewater-related organic micro-pollutants such as chlorinated and non-chlorinated organophosphates were detected in the SWT and, depending on their K ow values and their biodegradability, in lower concentrations at the spring.

Eogenetic karst hydrology: Insights from the 2004 hurricanes, peninsular Florida

USGS Publications Warehouse

Florea, L.J.; Vacher, H. Leonard

2007-01-01

Eogenetic karst lies geographically and temporally close to the depositional environment of limestone in warm marine water at low latitude, in areas marked by midafternoon thunderstorms during a summer rainy season. Spring hydrographs from such an environment in north-central Florida are characterized by smooth, months-long, seasonal maxima. The passage of Hurricanes Frances and Jeanne in September 2004 over three field locations shows how the eogenetic karst of the Upper Floridan Aquifer responds to unequivocal recharge events. Hydrographs at wells in the High Springs area, Rainbow Springs, and at Morris, Briar, and Bat Caves all responded promptly with a similar drawn-out rise to a maximum that extended long into the winter dry season. The timing indicates that the typical hydrograph of eogenetic karst is not the short-term fluctuations of springs in epigenic, telogenetic karst, or the smoothed response to all the summer thunderstorms, but rather the protracted response of the system to rainfall that exceeds a threshold. The similarity of cave and noncave hydrographs indicates distributed autogenic recharge and a free communication between secondary porosity and permeable matrix - both of which differ from the hydrology of epigenic, telogenetic karst. At Briar Cave, drip rates lagged behind the water table rise, suggesting that recharge was delivered by fractures, which control the cave's morphology. At High Springs, hydrographs at the Santa Fe River and a submerged conduit apparently connected to it show sharp maxima after the storms, unlike the other cave hydrographs. Our interpretation is that the caves, in general, are discontinuous. ?? 2007 National Ground Water Association.

Eogenetic karst hydrology: insights from the 2004 hurricanes, peninsular Florida.

PubMed

Florea, Lee J; Vacher, H L

2007-01-01

Eogenetic karst lies geographically and temporally close to the depositional environment of limestone in warm marine water at low latitude, in areas marked by midafternoon thunderstorms during a summer rainy season. Spring hydrographs from such an environment in north-central Florida are characterized by smooth, months-long, seasonal maxima. The passage of Hurricanes Frances and Jeanne in September 2004 over three field locations shows how the eogenetic karst of the Upper Floridan Aquifer responds to unequivocal recharge events. Hydrographs at wells in the High Springs area, Rainbow Springs, and at Morris, Briar, and Bat Caves all responded promptly with a similar drawn-out rise to a maximum that extended long into the winter dry season. The timing indicates that the typical hydrograph of eogenetic karst is not the short-term fluctuations of springs in epigenic, telogenetic karst, or the smoothed response to all the summer thunderstorms, but rather the protracted response of the system to rainfall that exceeds a threshold. The similarity of cave and noncave hydrographs indicates distributed autogenic recharge and a free communication between secondary porosity and permeable matrix-both of which differ from the hydrology of epigenic, telogenetic karst. At Briar Cave, drip rates lagged behind the water table rise, suggesting that recharge was delivered by fractures, which control the cave's morphology. At High Springs, hydrographs at the Santa Fe River and a submerged conduit apparently connected to it show sharp maxima after the storms, unlike the other cave hydrographs. Our interpretation is that the caves, in general, are discontinuous.

Volatile organic compound data from three karst springs in middle Tennessee, February 2000 to May 2001

USGS Publications Warehouse

Williams, Shannon D.; Farmer, James

2003-01-01

The U.S. Geological Survey (USGS), in cooperation with the Tennessee Department of Environment and Conservation, Division of Superfund, collected discharge, rainfall, continuous water-quality (temperature, dissolved oxygen, specific conductance, and pH), and volatile organic compound (VOC) data from three karst springs in Middle Tennessee from February 2000 to May 2001. Continuous monitoring data indicated that each spring responds differently to storms. Water quality and discharge at Wilson Spring, which is located in the Central Basin karst region of Tennessee, changed rapidly after rainfall. Water quality and discharge also varied at Cascade Spring; however, changes did not occur as frequently or as quickly as changes at Wilson Spring. Water quality and discharge at Big Spring at Rutledge Falls changed little in response to storms. Cascade Spring and Big Spring at Rutledge Falls are located in similar hydrogeologic settings on the escarpment of the Highland Rim. Nonisokinetic dip-sampling methods were used to collect VOC samples from the springs during base-flow conditions. During selected storms, automatic samplers were used to collect water samples at Cascade Spring and Wilson Spring. Water samples were collected as frequently as every 15 minutes at the beginning of a storm, and sampling intervals were gradually increased following a storm. VOC samples were analyzed using a portable gas chromatograph (GC). VOC samples were collected from Wilson, Cascade, and Big Springs during 600, 199, and 55 sampling times, respectively, from February 2000 to May 2001. Chloroform concentrations detected at Wilson Spring ranged from 0.073 to 34 mg/L (milligrams per liter). Chloroform concentrations changed during most storms; the greatest change detected was during the first storm in fall 2000, when chloroform concentrations increased from about 0.5 to about 34 mg/L. Concentrations of cis-1,2-dichloroethylene (cis-1,2-DCE) detected at Cascade Spring ranged from 0.30 to 1.8 ?g

Development of a process-oriented vulnerability concept for water travel time in karst aquifers-case study of Tanour and Rasoun springs catchment area.

NASA Astrophysics Data System (ADS)

Hamdan, Ibraheem; Sauter, Martin; Ptak, Thomas; Wiegand, Bettina; Margane, Armin; Toll, Mathias

2017-04-01

Key words: Karst aquifer, water travel time, vulnerability assessment, Jordan. The understanding of the groundwater pathways and movement through karst aquifers, and the karst aquifer response to precipitation events especially in the arid to semi-arid areas is fundamental to evaluate pollution risks from point and non-point sources. In spite of the great importance of the karst aquifer for drinking purposes, karst aquifers are highly sensitive to contamination events due to the fast connections between the land-surface and the groundwater (through the karst features) which is makes groundwater quality issues within karst systems very complicated. Within this study, different methods and approaches were developed and applied in order to characterise the karst aquifer system of the Tanour and Rasoun springs (NW-Jordan) and the flow dynamics within the aquifer, and to develop a process-oriented method for vulnerability assessment based on the monitoring of different multi-spatially variable parameters of water travel time in karst aquifer. In general, this study aims to achieve two main objectives: 1. Characterization of the karst aquifer system and flow dynamics. 2. Development of a process-oriented method for vulnerability assessment based on spatially variable parameters of travel time. In order to achieve these aims, different approaches and methods were applied starting from the understanding of the geological and hydrogeological characteristics of the karst aquifer and its vulnerability against pollutants, to using different methods, procedures and monitored parameters in order to determine the water travel time within the aquifer and investigate its response to precipitation event and, finally, with the study of the aquifer response to pollution events. The integrated breakthrough signal obtained from the applied methods and procedures including the using of stable isotopes of oxygen and hydrogen, the monitoring of multi qualitative and quantitative parameters

Karst hydrogeology and hydrochemistry of the Cave Springs basin near Chattanooga, Tennessee

USGS Publications Warehouse

Pavlicek, D.J.

1996-01-01

The Cave Springs ground-water basin, located near Chattanooga, Tennessee, was chosen as one of the Valley and Ridge physiographic province type area studies for the Appalachian Valley-Piedmont Regional Aquifer-System Analysis study in 1990. Karstic Paleozoic carbonate rocks, residual clay-rich regolith, and coarse alluvium form the aquifer framework. Recharge from rainfall dispersed over the basin enters the karst aquifer through the thick regolith. The area supplying recharge to the Cave Springs Basin is approximately 7 square miles. Recharge from North Chickamauga Creek may contribute recharge to the Cave Springs Basin along losing reaches. The flow medium consists of mixed dolomite and limestone with cavernous and fracture porosity. Flow type as determined by the coefficient of variation of long-term continuous specific conductance (18 and 15 percent) from two wells completed in cavernous intervals about 150 feet northeast of Cave Springs, indicates an aquifer with conduit flow. Flow type, based on the ratio (6:1) of spring flood-flow discharge to spring base-flow discharge, indicates an aquifer with diffuse flow. Conduit flow probably dominates the aquifer system west of Cave Springs Ridge from the highly transmissive, unconfined, alluvium capped aquifer and along losing reaches of North Chickamauga Creek. Diffuse flow probably predominates in the areas along and east of Cave Springs Ridge covered with the thick, clay-rich regolith that forms a leaky confining layer. Based on average annual long-term precipitation and runoff records, the amount of water available for recharge to Cave Springs is 11.8 cubic feet per second. The mean annual long-term discharge of Cave Springs is 16.4 cubic feet per second which leaves 4.6 cubic feet per second of recharge unaccounted for. As determined by low-flow stream discharge measurements, recharge along losing reaches of North Chickamauga Creek may be an important source of unaccounted-for-recharge to the Cave Springs Basin

Evaporite-karst problems and studies in the USA

USGS Publications Warehouse

Johnson, K.S.

2008-01-01

Evaporites, including rock salt (halite) and gypsum (or anhydrite), are the most soluble among common rocks; they dissolve readily to form the same types of karst features that commonly are found in limestones and dolomites. Evaporites are present in 32 of the 48 contiguous states in USA, and they underlie about 40% of the land area. Typical evaporite-karst features observed in outcrops include sinkholes, caves, disappearing streams, and springs, whereas other evidence of active evaporite karst includes surface-collapse structures and saline springs or saline plumes that result from salt dissolution. Many evaporites also contain evidence of paleokarst, such as dissolution breccias, breccia pipes, slumped beds, and collapse structures. All these natural karst phenomena can be sources of engineering or environmental problems. Dangerous sinkholes and caves can form rapidly in evaporite rocks, or pre-existing karst features can be reactivated and open up (collapse) under certain hydrologic conditions or when the land is put to new uses. Many karst features also propagate upward through overlying surficial deposits. Human activities also have caused development of evaporite karst, primarily in salt deposits. Boreholes (petroleum tests or solution-mining operations) or underground mines may enable unsaturated water to flow through or against salt deposits, either intentionally or accidentally, thus allowing development of small to large dissolution cavities. If the dissolution cavity is large enough and shallow enough, successive roof failures can cause land subsidence and/or catastrophic collapse. Evaporite karst, natural and human-induced, is far more prevalent than is commonly believed. ?? 2007 Springer-Verlag.

Nitrogen Source Inventory and Loading Tool: An integrated approach toward restoration of water-quality impaired karst springs.

PubMed

Eller, Kirstin T; Katz, Brian G

2017-07-01

Nitrogen (N) from anthropogenic sources has contaminated groundwater used as drinking water in addition to impairing water quality and ecosystem health of karst springs. The Nitrogen Source Inventory and Loading Tool (NSILT) was developed as an ArcGIS and spreadsheet-based approach that provides spatial estimates of current nitrogen (N) inputs to the land surface and loads to groundwater from nonpoint and point sources within the groundwater contributing area. The NSILT involves a three-step approach where local and regional land use practices and N sources are evaluated to: (1) estimate N input to the land surface, (2) quantify subsurface environmental attenuation, and (3) assess regional recharge to the aquifer. NSILT was used to assess nitrogen loading to groundwater in two karst spring areas in west-central Florida: Rainbow Springs (RS) and Kings Bay (KB). The karstic Upper Floridan aquifer (UFA) is the source of water discharging to the springs in both areas. In the KB study area (predominantly urban land use), septic systems and urban fertilizers contribute 48% and 22%, respectively, of the estimated total annual N load to groundwater 294,400 kg-N/yr. In contrast for the RS study area (predominantly agricultural land use), livestock operations and crop fertilizers contribute 50% and 13%, respectively, of the estimated N load to groundwater. Using overall groundwater N loading rates for the KB and RS study areas, 4.4 and 3.3 kg N/ha, respectively, and spatial recharge rates, the calculated groundwater nitrate-N concentration (2.1 mg/L) agreed closely with the median nitrate-N concentration (1.7 mg/L) from groundwater samples in agricultural land use areas in the RS study area for the period 2010-2014. NSILT results provide critical information for prioritizing and designing restoration efforts for water-quality impaired springs and spring runs affected by multiple sources of nitrogen loading to groundwater. The calculated groundwater N concentration for

The role of tributary mixing in chemical variations at a karst spring, Milandre, Switzerland

NASA Astrophysics Data System (ADS)

Perrin, J.; Jeannin, P.-Y.; Cornaton, F.

2007-01-01

SummarySolute concentration variations during flood events were investigated in a karst aquifer of the Swiss Jura. Observations were made at the spring, and at the three main subterraneous tributaries feeding the spring. A simple transient flow and transport numerical model was able to reproduce chemographs and hydrographs observed at the spring, as a result of a mixing of the concentration and discharge of the respective tributaries. Sensitivity analysis carried out with the model showed that it is possible to produce chemical variations at the spring even if all tributaries have constant (but different for each of them) solute concentrations. This process is called tributary mixing. The good match between observed and modelled curves indicate that, in the phreatic zone, tributary mixing is probably an important process that shapes spring chemographs. Chemical reactions and other mixing components (e.g. from low permeability volumes) have a limited influence. Dissolution-related (calcium, bicarbonate, specific conductance) and pollution-related parameters (nitrate, chloride, potassium) displayed slightly different behaviours: during moderate flood events, the former showed limited variations compared to the latter. During large flood events, both presented chemographs with significant changes. No significant event water participates in moderate flood events and tributary mixing will be the major process shaping chemographs. Variations are greater for parameters with higher spatial variability (e.g. pollution-related). Whereas for large flood events, the contribution of event water becomes significant and influences the chemographs of all the parameters. As a result, spring water vulnerability to an accidental pollution is low during moderate flood events and under base flow conditions. It strongly increases during large flood events, because event water contributes to the spring discharge.

Heterotrophic prokaryotic production in ultra-oligotrophic alpine karst aquifers and ecological implications

PubMed Central

Wilhartitz, Inés C.; Kirschner, Alexander K.T.; Stadler, Hermann; Herndl, Gerhard J.; Dietzel, Martin; Latal, Christine; Mach, Robert L.; Farnleitner, Andreas H.

2011-01-01

Spring waters from alpine karst aquifers are important drinking water resources. To investigate in situ prokaryotic heterotrophic production (HP) and its controlling factors, two alpine karst springs of contrasting hydrogeology but of nearby catchments were studied over two annual cycles. Heterotrophic production in spring water, as determined by [3H]leucine incorporation, was low but revealed strong seasonal variations ranging from 0.06 to 6.83 pmol C l−1 h−1 (DKAS1, dolomitic karst-spring) and from 0.50 to 75.6 pmol C l−1 h−1 (LKAS2, limestone karst-spring). Microautoradiography combined with catalyzed reporter deposition - fluorescence in situ hybridization (MAR-CARD-FISH) showed that only about 7 % of the picoplankton community took up [3H]leucine resulting in generation times of 3 to 684 days. Principal component analysis, applying hydrological, chemical and biological parameters demonstrated that planktonic heterotrophic production in LKAS2 was strongly governed by hydrogeographical components (e.g. discharge), whereas variations in DKAS1 are also strongly influenced by changes within the aquifer itself. Measurements in sediments recovered from LKAS2, DKAS1 and similar alpine karst aquifers (n=12) revealed an 106-fold higher heterotrophic production (average 19 μmol C dm−3 h−1) with significantly lower generation times as compared to the planktonic fraction, highlighting the metabolic potential of surface associated endokarst communities to add to self-purification processes. Estimates of microbially mediated CO2 in this compartment indicated a possible contribution to karstification. PMID:19490127

Opening the black box of spring water microbiology from alpine karst aquifers to support proactive drinking water resource management

PubMed Central

Savio, Domenico; Stadler, Philipp; Reischer, Georg H.; Kirschner, Alexander K.T.; Demeter, Katalin; Linke, Rita; Blaschke, Alfred P.; Sommer, Regina; Szewzyk, Ulrich; Wilhartitz, Inés C.; Mach, Robert L.; Stadler, Hermann

2018-01-01

Over the past 15 years, pioneering interdisciplinary research has been performed on the microbiology of hydrogeologically well‐defined alpine karst springs located in the Northern Calcareous Alps (NCA) of Austria. This article gives an overview on these activities and links them to other relevant research. Results from the NCA springs and comparable sites revealed that spring water harbors abundant natural microbial communities even in aquifers with high water residence times and the absence of immediate surface influence. Apparently, hydrogeology has a strong impact on the concentration and size of the observed microbes, and total cell counts (TCC) were suggested as a useful means for spring type classification. Measurement of microbial activities at the NCA springs revealed extremely low microbial growth rates in the base flow component of the studied spring waters and indicated the importance of biofilm‐associated microbial activities in sediments and on rock surfaces. Based on genetic analysis, the autochthonous microbial endokarst community (AMEC) versus transient microbial endokarst community (TMEC) concept was proposed for the NCA springs, and further details within this overview article are given to prompt its future evaluation. In this regard, it is well known that during high‐discharge situations, surface‐associated microbes and nutrients such as from soil habitats or human settlements—potentially containing fecal‐associated pathogens as the most critical water‐quality hazard—may be rapidly flushed into vulnerable karst aquifers. In this context, a framework for the comprehensive analysis of microbial pollution has been proposed for the NCA springs to support the sustainable management of drinking water safety in accordance with recent World Health Organization guidelines. Near‐real‐time online water quality monitoring, microbial source tracking (MST) and MST‐guided quantitative microbial‐risk assessment (QMRA) are examples of

Opening the black box of spring water microbiology from alpine karst aquifers to support proactive drinking water resource management.

PubMed

Savio, Domenico; Stadler, Philipp; Reischer, Georg H; Kirschner, Alexander K T; Demeter, Katalin; Linke, Rita; Blaschke, Alfred P; Sommer, Regina; Szewzyk, Ulrich; Wilhartitz, Inés C; Mach, Robert L; Stadler, Hermann; Farnleitner, Andreas H

2018-01-01

Over the past 15 years, pioneering interdisciplinary research has been performed on the microbiology of hydrogeologically well-defined alpine karst springs located in the Northern Calcareous Alps (NCA) of Austria. This article gives an overview on these activities and links them to other relevant research. Results from the NCA springs and comparable sites revealed that spring water harbors abundant natural microbial communities even in aquifers with high water residence times and the absence of immediate surface influence. Apparently, hydrogeology has a strong impact on the concentration and size of the observed microbes, and total cell counts (TCC) were suggested as a useful means for spring type classification. Measurement of microbial activities at the NCA springs revealed extremely low microbial growth rates in the base flow component of the studied spring waters and indicated the importance of biofilm-associated microbial activities in sediments and on rock surfaces. Based on genetic analysis, the autochthonous microbial endokarst community (AMEC) versus transient microbial endokarst community (TMEC) concept was proposed for the NCA springs, and further details within this overview article are given to prompt its future evaluation. In this regard, it is well known that during high-discharge situations, surface-associated microbes and nutrients such as from soil habitats or human settlements-potentially containing fecal-associated pathogens as the most critical water-quality hazard-may be rapidly flushed into vulnerable karst aquifers. In this context, a framework for the comprehensive analysis of microbial pollution has been proposed for the NCA springs to support the sustainable management of drinking water safety in accordance with recent World Health Organization guidelines. Near-real-time online water quality monitoring, microbial source tracking (MST) and MST-guided quantitative microbial-risk assessment (QMRA) are examples of the proposed analytical

Fluorescence-based multi-parameter approach to characterize dynamics of organic carbon, faecal bacteria and particles at alpine karst springs.

PubMed

Frank, Simon; Goeppert, Nadine; Goldscheider, Nico

2018-02-15

Karst springs, especially in alpine regions, are important for drinking water supply but also vulnerable to contamination, especially after rainfall events. This high variability of water quality requires rapid quantification of contamination parameters. Here, we used a fluorescence-based multi-parameter approach to characterize the dynamics of organic carbon, faecal bacteria, and particles at three alpine karst springs. We used excitation emission matrices (EEMs) to identify fluorescent dissolved organic material (FDOM). At the first system, peak A fluorescence and total organic carbon (TOC) were strongly correlated (Spearman's r s of 0.949), indicating that a large part of the organic matter is related to humic-like substances. Protein-like fluorescence and cultivation-based determination of coliform bacteria also had a significant correlation with r s =0.734, indicating that protein-like fluorescence is directly related to faecal pollution. At the second system, which has two spring outlets, the absolute values of all measured water-quality parameters were lower; there was a significant correlation between TOC and humic-like fluorescence (r s =0.588-0.689) but coliform bacteria and protein-like fluorescence at these two springs were not correlated. Additionally, there was a strong correlation (r s =0.571-0.647) between small particle fractions (1.0 and 2.0μm), a secondary turbidity peak and bacteria. At one of these springs, discharge was constant despite the reaction of all other parameters to the rainfall event. Our results demonstrated that i) all three springs showed fast and marked responses of all investigated water-quality parameters after rain events; ii) a constant discharge does not necessarily mean constant water quality; iii) at high contamination levels, protein-like fluorescence is a good indicator of bacterial contamination, while at low contamination levels no correlation between protein-like fluorescence and bacterial values was detected; and

Water quality modelling of Jadro spring.

PubMed

Margeta, J; Fistanic, I

2004-01-01

Management of water quality in karst is a specific problem. Water generally moves very fast by infiltration processes but far more by concentrated flows through fissures and openings in karst. This enables the entire surface pollution to be transferred fast and without filtration into groundwater springs. A typical example is the Jadro spring. Changes in water quality at the spring are sudden, but short. Turbidity as a major water quality problem for the karst springs regularly exceeds allowable standards. Former practice in problem solving has been reduced to intensive water disinfection in periods of great turbidity without analyses of disinfection by-products risks for water users. The main prerequisite for water quality control and an optimization of water disinfection is the knowledge of raw water quality and nature of occurrence. The analysis of monitoring data and their functional relationship with hydrological parameters enables establishment of a stochastic model that will help obtain better information on turbidity in different periods of the year. Using the model a great number of average monthly and extreme daily values are generated. By statistical analyses of these data possibility of occurrence of high turbidity in certain months is obtained. This information can be used for designing expert system for water quality management of karst springs. Thus, the time series model becomes a valuable tool in management of drinking water quality of the Jadro spring.

Contamination investigation in a karst region

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bentowski, J.E.

1993-03-01

A series of springs in the karst region of north central Kentucky appeared to have been contaminated. These springs are within 1/2 mile of two sinkholes which were filled-in as permitted landfills for inert waste and then developed into an industrial park. A pre-remedial site inspection was performed under the authority of the Superfund laws in late 1989. A preliminary site visit included site reconnaissance and geologic field work to locate the springs. A review of historical serial photos aided in the planning the investigation program consisting of magnetic and soil gas surveys and the taking environmental soil and watermore » samples. The soil gas survey indicated potential soil sampling locations. Seventeen surface and subsurface soil samples were taken. Eleven water samples were taken from various springs, rivers and the local public water supply. The analytical results from soil samples taken over the largest sinkhole matched nine inorganic and eleven volatile organic compounds also found in the spring water and sediment samples. The springs are roughly on strike with major fracture systems reported in the literature. The success of this investigation emphasizes the importance of proper geologic consideration for contaminant monitoring in karst regions.« less

Review: Characterization, evolution, and environmental issues of karst water systems in Northern China

NASA Astrophysics Data System (ADS)

Liang, Yongping; Gao, Xubo; Zhao, Chunhong; Tang, Chunlei; Shen, Haoyong; Wang, Zhiheng; Wang, Yanxin

2018-05-01

In Northern China, karst systems in widely distributed carbonate rocks are one of the most important water supplies for local inhabitants. Constrained by the specific geological and geomorphological conditions, most karst water in this region is discharged as individual or groups of springs. This paper summarizes the characteristics, chemistry, and environmental quality of these karst systems in Northern China. Five structural models of karst water systems were identified based on the relationships between the karst geological strata and karst groundwater flow fields. These specific structural models may closely relate to the attendant environmental geological issues and consistent risks from pollution. Over the past 40 years, the karst water systems in Northern China have suffered from various environmental problems, including deteriorating water quality, the drying up of springs, a continuous decline in the level of karst water, and so on. Based on the field investigation and previous data, a preliminary summary is provided of the environmental problems related to the development and evolutionary trends of karst water in this region. The results highlight the significant challenges associated with karst water, and it is essential that all segments of society be made aware of the situation in order to demand change. In addition, the study provides a scientific basis for the management, protection, and sustainable utilization of karst water resources.

Some new cave diving exploration results from Croatian karst area

NASA Astrophysics Data System (ADS)

Garasic, Davor; Garasic, Mladen

2017-04-01

In the recent years, several international cave diving expeditions took place in the Dinaric karst of Croatia. The objectives were conducting a new research of previously known karstic springs and also exploring new ones. The deepest karst cave in Croatia filled with water is Crveno jezero (lake) near Imotski town, with water depth of 281 meters and total cave depth of 528 meters. Volume of water in this cave is about 16 millions m3. Diving expeditions were held in 1997 and 1998.The deepest karst spring in the Dinaric karst of Croatia is Vrelo of Una River (with max discharge about 100 m3/s), where divers measured depth of -248 meters. Explorations were made in 2007 and 2016. Sinac spring in Pla\\vsko Polje has been dived to the depth of -203 meters. Cave diving was done in 1984, 1999, 2003, 2007 - 2016. Furthermore, very popular springs of the river Kupa (-155 m) in Gorski Kotar (explored since1995 till 2015), river Gacka (-105 in depth, 1150m in length) in Lika, explored from 1992 to 2016, river Cetina (-110 m in depth, 1300 m in length), cave diving explored from 2000 to 2016 in the Dalmatinska Zagora, Rumin Veliki spring (- 150 m in depth) in the Sinjska Krajina (explored and dived in 2006 and 2010), than rivers Krnjeza and Krupa in Ravni kotari with diving depths of over 100 meters (in 2004 and 2005) and so on. Along the Adriatic coast in Croatia there are many deep and long submarine springs (vrulje), ie. caves under seawater springs. called - vruljas for example Vrulja Zecica with over 900 meters ine length and Vrulja Modrič with completely flooded cave channels that extend over 2300 meters in length. Cave diving was conducted from 2010 to 2016. Vrulja Dubci is also worth mentioning (dived and explored in 2000), 161 meters deep and so on. Tectonic activity plays a dominant role in the creation and function of these caves. Geological, hydrogeological and lithostratigraphic conditions are also very important in speleogenesis of these caves in Croatian karst

Selected Micropollutants as Indicators in a Karst Catchment

NASA Astrophysics Data System (ADS)

Zirlewagen, Johannes; Schiperski, Ferry; Hillebrand, Olav; Nödler, Karsten; Licha, Tobias; Scheytt, Traugott

2015-04-01

High flow dynamics and variations in water quality are typical for karst springs and reflect the complex interaction of different flow and storage components within a karst system. Event-based monitoring of mobile micropollutants in spring water combined with information on their input is used (1) to quantify the impact of certain contamination scenarios on spring water quality and (2) to gain additional information on the intrinsic characteristics of a karst system. We employ the artificial sweeteners acesulfame and cyclamate as source specific indicators for sewage along with the herbicides atrazine and isoproturon for agriculture. The study site is the 45 km² rural catchment of the perennial karst spring Gallusquelle in SW-Germany (mean discharge: 0.5 m³/s). Overflow events of a stormwater detention basin (SDB, combined sewer system) are known to impact water quality. Most of the sewer system is situated in the SW of the catchment. Most agricultural land is found in the NE. Neither atrazine nor significant amounts of isoproturon were detected in wastewater. Concentrations and mass fluxes of acesulfame and cyclamate in wastewater were determined. The combined evaluation of the persistent compound acesulfame with the rather degradable cyclamate allows for the distinction of long and short transit times and thus slow and fast flow components. The same applies for atrazine (persistent) and isoproturon (degradable). In Germany, acesulfame was licensed in 1990, atrazine was banned shortly after, in 1991. During low flow conditions only atrazine (max. 4 ng/L) and acesulfame (max. 20 ng/L) were detected in spring water. After a recharge event without SDB overflow concentrations as well as mass fluxes of both compounds decreased, reflecting an increasing portion of event water in spring discharge. A breakthrough of isoproturon (max. 9 ng/L) indicated the arrival of water from croplands. After a recharge event accompanied by a SDB overflow cyclamate was detected at max

A sampling plan for conduit-flow karst springs: Minimizing sampling cost and maximizing statistical utility

USGS Publications Warehouse

Currens, J.C.

1999-01-01

Analytical data for nitrate and triazines from 566 samples collected over a 3-year period at Pleasant Grove Spring, Logan County, KY, were statistically analyzed to determine the minimum data set needed to calculate meaningful yearly averages for a conduit-flow karst spring. Results indicate that a biweekly sampling schedule augmented with bihourly samples from high-flow events will provide meaningful suspended-constituent and dissolved-constituent statistics. Unless collected over an extensive period of time, daily samples may not be representative and may also be autocorrelated. All high-flow events resulting in a significant deflection of a constituent from base-line concentrations should be sampled. Either the geometric mean or the flow-weighted average of the suspended constituents should be used. If automatic samplers are used, then they may be programmed to collect storm samples as frequently as every few minutes to provide details on the arrival time of constituents of interest. However, only samples collected bihourly should be used to calculate averages. By adopting a biweekly sampling schedule augmented with high-flow samples, the need to continuously monitor discharge, or to search for and analyze existing data to develop a statistically valid monitoring plan, is lessened.Analytical data for nitrate and triazines from 566 samples collected over a 3-year period at Pleasant Grove Spring, Logan County, KY, were statistically analyzed to determine the minimum data set needed to calculate meaningful yearly averages for a conduit-flow karst spring. Results indicate that a biweekly sampling schedule augmented with bihourly samples from high-flow events will provide meaningful suspended-constituent and dissolved-constituent statistics. Unless collected over an extensive period of time, daily samples may not be representative and may also be autocorrelated. All high-flow events resulting in a significant deflection of a constituent from base-line concentrations

Karst in evaporite rocks of the United States

USGS Publications Warehouse

Johnson, Kenneth S.

2002-01-01

Evaporites are the most soluble of common rocks; they are dissolved readily to form the same range of karst features that typically are found in limestones and dolomites. Evaporites, including gypsum (or anhydrite) and salt, are present in 32 of the 48 contiguous United States, and they underlie about 35-40% of the land area. Evaporite outcrops typically contain sinkholes, caves, disappearing streams, and springs. Other evidence of active karst in evaporites includes surface-collapse features and saline springs or saline plumes that result from dissolution of salt. Many evaporites, including some in the deeper subsurface, also contain evidence of paleokarst that is no longer active; this evidence includes dissolution breccias, breccia pipes, slumped beds, and collapse structures. Evaporites occur in 24 separate structural basins or geographic districts in the United States, and either local or extensive evaporite karst is known in almost all of these basins or districts. Human activities also have caused development of evaporite karst, primarily in salt deposits. Boreholes or underground mines may enable (either intentionally or inadvertently) unsaturated water to flow through or against salt deposits, thus allowing development of small to large dissolution cavities. If the dissolution cavity is large enough and shallow enough, successive roof failures can cause land subsidence or catastrophic collapse. Evaporite karst, both natural and human-induced, is far more prevalent than commonly believed.

Relation between flow and temporal variations of nitrate and pesticides in two karst springs in northern Alabama

USGS Publications Warehouse

Kingsbury, J.A.

2008-01-01

Two karst springs in the Mississippian Carbonate Aquifer of northern Alabama were sampled between March 1999 and March 2001 to characterize the variability in concentration of nitrate, pesticides, selected pesticide degradates, water temperature, and inorganic constituents. Water temperature and inorganic ion data for McGeehee Spring indicate that this spring represents a shallow flow system with a relatively short average ground-water residence time. Water issuing from the larger of the two springs, Meridianville Spring, maintained a constant temperature, and inorganic ion data indicate that this water represents a deeper flow system having a longer average ground-water residence time than McGeehee Spring. Although water-quality data indicate differing short-term responses to rainfall at the two springs, the seasonal variation of nitrate and pesticide concentrations generally is similar for the two springs. With the exception of pesticides detected at low concentrations, the coefficient of variation for most constituent concentrations was less than that of flow at both springs, with greater variability in concentration at McGeehee Spring. Degradates of the herbicides atrazine and fluometuron were detected at concentrations comparable to or greater than the parent pesticides. Decreases in concentration of the principal degradate of fluometuron from about July to November indicate that the degradation rate may decrease as fluometuron (demethylfluometuron) moves deeper into the soil after application. Data collected during the study show that from about November to March when recharge rates increase, nitrate and residual pesticides in the soil, unsaturated zone, and storage within the aquifer are transported to the spring discharges. Because of the increase in recharge, fluometuron loads discharged from the springs during the winter were comparable to loads discharged at the springs during the growing season. ?? 2008 American Water Resources Association.

Karst of the Mid-Atlantic region in Maryland, West Virginia, and Virginia

USGS Publications Warehouse

Doctor, Daniel H.; Weary, David J.; Brezinski, David K.; Orndorff, Randall C.; Spangler, Lawrence E.; Brezinski, David K.; Halka, Jeffrey; Ortt, Richard A.

2015-01-01

The Mid-Atlantic region hosts some of the most mature karst landscapes in North America, developed in highly deformed rocks within the Piedmont and Valley and Ridge physiographic provinces. This guide describes a three-day excursion to examine karst development in various carbonate rocks by following Interstate 70 west from Baltimore across the eastern Piedmont, across the Frederick Valley, and into the Great Valley proper. The localities were chosen in order to examine the structural and lithological controls on karst feature development in marble, limestone, and dolostone rocks with an eye toward the implications for ancient landscape evolution, as well as for modern subsidence hazards. A number of caves will be visited, including two commercial caverns that reveal strikingly different histories of speleogenesis. Links between karst landscape development, hydrologic dynamics, and water resource sustainability will also be emphasized through visits to locally important springs. Recent work on quantitative dye tracing, spring water geochemistry, and groundwater modeling reveal the interaction between shallow and deep circulation of groundwater that has given rise to the modern karst landscape. Geologic and karst feature mapping conducted with the benefit of lidar data help reveal the strong bedrock structural controls on karst feature development, and illustrate the utility of geologic maps for assessment of sinkhole susceptibility.

Geologic context of large karst springs and caves in the Ozark National Scenic Riverways, Missouri

USGS Publications Warehouse

Weary, David J.; Orndorff, Randall C.

2016-01-01

The ONSR is a karst park, containing many springs and caves. The “jewels” of the park are large springs, several of first magnitude, that contribute significantly to the flow and water quality of the Current River and its tributaries. Completion of 1:24,000-scale geologic mapping of the park and surrounding river basin, along with synthesis of published hydrologic data, allows us to examine the spatial relationships between the springs and the geologic framework to develop a conceptual model for genesis of these springs. Based on their similarity to mapped spring conduits, many of the caves in the ONSR are fossil conduit segments. Therefore, geologic control on the evolution of the springs also applies to speleogenesis in this part of the southern Missouri Ozarks.Large springs occur in the ONSR area because: (1) the Ozark aquifer, from which they rise, is chiefly dolomite affected by solution via various processes over a long time period, (2) Paleozoic hypogenic fluid migration through these rocks exploited and enhanced flow-paths, (3) a consistent and low regional dip of the rocks off of the Salem Plateau (less than 2° to the southeast) allows integration of flow into large groundwater basins with a few discreet outlets, (4) the springs are located where the rivers have cut down into structural highs, allowing access to water from stratigraphic units deeper in the aquifer thus allowing development of springsheds that have volumetrically larger storage than smaller springs higher in the section, and (5) quartz sandstone and bedded chert in the carbonate stratigraphic succession that are locally to regionally continuous, serve as aquitards that locally confine groundwater up dip of the springs creating artesian conditions. This subhorizontal partitioning of the Ozark aquifer allows contributing areas for different springs to overlap, as evidenced by dye traces that cross adjacent groundwater basin boundaries, and possibly contributes to alternate flow routes

Estimating exposure to groundwater contaminants in karst areas

NASA Astrophysics Data System (ADS)

Butscher, C.

2012-12-01

Large multidisciplinary projects investigate health effects and environmental impacts of contamination. Such multidisciplinary projects challenge groundwater hydrologist because they demand estimations of human or environmental exposure to groundwater contaminants. But especially in karst regions, groundwater quality is subject to rapid changes resulting from highly dynamic flow systems with rapid groundwater recharge and contaminant transport in karst conduits. There is a strong need for tools that allow the quantification of the risk of contaminant exposure via the karst groundwater and its temporal variation depending on rainfall events and overall hydrological conditions. A fact that makes the assessment of contaminant exposure even more difficult is that many contaminants behave differently in the subsurface than the groundwater, because they do not dissolve and exist as a separate phase. Important examples are particulate contaminants, such as bacteria, and non-aqueous phase liquids (NAPLs), such as many organic compounds. Both are ubiquitous in the environment and have large potential for health impacts. It is known from bacterial contamination of karst springs that such contamination is strongly related to flow conditions. Bacteria, which are present at the land surface, in the soil, rock matrix or the conduit system, are immobile during base flow conditions. During storm events however, they become mobilized and are rapidly transported through the conduit flow system from sources to areas of potential exposure. As a result, bacteria concentrations that most times are low at a spring can show a high peak during storm flow. Conceptual models exist that suggest that the transport of NAPLs in karst aquifers is, just like bacterial contamination, related to flow conditions. Light NAPLs that reach the saturated zone float and accumulate on the water table; and dense NAPLs sink downward in the aquifer until they are trapped in pores, fractures and conduits where

Pesticides and biocides in a karst catchment: Identification of contaminant sources and related flow components

NASA Astrophysics Data System (ADS)

Wagner, Thomas; Bollmann, Ulla E.; Bester, Kai; Birk, Steffen

2013-04-01

Karst aquifers are widely used as drinking water resources. However, their high vulnerability to chemical and bacterial contamination due to the heterogeneity in aquifer properties (highly conductive solution conduits embedded in the less conductive fissured rock) is difficult to assess and thus poses major challenges to the management of karst water resources. Contamination of karst springs by organic micro-pollutants has been observed in recent studies. Within this study the water from different springs draining one karst aquifer as well as the main sinking stream replenishing it were analysed before, during and after a storm water event in order to examine the occurrence of different pesticides and biocides. Contaminants from both urban as well as agricultural origin could be detected in the water with concentrations in the low ng/L range (tebuconazole, carbendazim, diuron, isoproturon, terbutryn, atrazine, dichlorobenzamide (BAM), which is a metabolite of dichlobenil). While some compounds could be followed from the sinking stream to the springs (e.g. dichlorobenzamide) some seem to have a source in the autogenic recharge from the karst plateau (Tebuconazole: wood preservative in buildings). These compounds appear to be related to fast flow components with residence times in the order of days, which are known from a number of tracer tests with fluorescent dyes. However, the occurrence of the pesticide atrazine (banned since 1995 in Austria) in the springs, while on the other hand no current input into the karst occurs, shows that some compounds have long residence times in the karst aquifer. These differences in residence times can hardly be attributed to differences in physico-chemical properties of the compounds and must thus be due to the presence of slow and fast flow components. This is in agreement with the duality of karst aquifers due to highly conductive networks of solution conduits embedded in less conductive fissured carbonate rocks.

Climate control of decadal-scale increases in apparent ages of eogenetic karst spring water

NASA Astrophysics Data System (ADS)

Martin, Jonathan B.; Kurz, Marie J.; Khadka, Mitra B.

2016-09-01

Water quantity and quality in karst aquifers may depend on decadal-scale variations in recharge or withdrawal, which we hypothesize could be assessed through time-series measurements of apparent ages of spring water. We tested this hypothesis with analyses of various age tracers (3H/3He, SF6, CFC-11, CFC-12, CFC-113) and selected solute concentrations [dissolved oxygen (DO), NO3, Mg, and SO4] from 6 springs in a single spring complex (Ichetucknee springs) in northern Florida over a 16-yr period. These springs fall into two groups that reflect shallow short (Group 1) and deep long (Group 2) flow paths. Some tracer concentrations are altered, with CFC-12 and CFC-113 concentrations yielding the most robust apparent ages. These tracers show a 10-20-yr monotonic increase in apparent age from 1997 to 2013, including the flood recession that followed Tropical Storm Debby in mid-2012. This increase in age indicates most water discharged during the study period recharged the aquifer within a few years of 1973 for Group 2 springs and 1980 for Group 1 springs. Inverse correlations between apparent age and DO and NO3 concentrations reflect reduced redox state in older water. Positive correlations between apparent age and Mg and SO4 concentrations reflect increased water-rock reactions. Concentrated recharge in the decade around 1975 resulted from nearly 2 m of rain in excess of the monthly average that fell between 1960 and 2014, followed by a nearly 4 m deficit to 2014. This excess rain coincided with two major El Niño events during the maximum cool phase in the Atlantic Multidecadal Oscillation. Although regional water withdrawal increased nearly 5-fold between 1980 and 2005, withdrawals represent only 2-5% of Ichetucknee River flow and are less important than decadal-long variations in precipitation. These results suggest that groundwater management should consider climate cycles as predictive tools for future water resources.

Negative grouting consequences on karst environment

NASA Astrophysics Data System (ADS)

Bonacci, O.; Roje-Bonacci, T.; Gottstein, S.

2009-04-01

Grouting is a procedure by means of which grout is injected into different kinds of karst spaces (cracks, fissures, conduits and caves). It has a wide application in modern civil engineering, especially in karst terrains. It started nearly 200 years ago. In most cases the ingredients for the preparation of mortars and grouting suspensions are: cement, bentonite, clay and fillers, additives for stability and water. In practice the composition of grouting suspension is not standardized. A suspension injected under pressure will circulate in the karst spaces like a more or less viscous fluid until some of the larger suspended particles are blocked where the karst voids get narrower than the size of injected grains. The injection of materials into karst groundwater, i.e. the construction of grouting curtains, definitely could be the cause of unpredictable negative consequences on karst groundwater environments. The building of dams in karst areas always go along the construction of grouting curtains. During the construction of most dams in karst all over the world millions tons of injection mass have been injected in karst underground. It may impact water quantity in vadose zone and in karstic aquifer causing water table lowering and spring desiccation. In such cases the negative impact on local karst environment could be very dangerous. Physically as well as chemically this mass voraciously and quickly destroyed underground habitats and killed an enormous number of endangered and endemic species. Very often this is extremely expensive procedure and in many cases not very successful from the engineering point of view. From the ecological point of view it could causes catastrophic consequences. The greatest problem is that until now neither engineers nor ecologists took care of these great and massive negative influences on underground karst environments. In this paper few examples of different consequences of grouting on the hydrogeological as well as ecological regime

Prediction of daily spring hydrographs for future climatic scenarios based on an integrated numerical modelling approach: Application on a snow-governed semi- arid karst catchment area.

NASA Astrophysics Data System (ADS)

Doummar, J.; Kassem, A.; Gurdak, J. J.

2017-12-01

In the framework of a three-year USAID/NSF- funded PEER Science project, flow in a karst system in Lebanon (Assal Spring; discharge 0.2-2.5 m3/s yearly volume of 22-30 Mm3) dominated by snow and semi arid conditions was simulated using an integrated numerical model (Mike She 2016). The calibrated model (Nash-Sutcliffe coefficient of 0.77) is based on high resolution input data (2014-2017) and detailed catchment characterization. The approach is to assess the influence of various model parameters on recharge signals in the different hydrological karst compartments (Atmosphere, unsaturated zone, and saturated zone) based on an integrated numerical model. These parameters include precipitation intensity and magnitude, temperature, snow-melt parameters, in addition to karst specific spatially distributed features such as fast infiltration points, soil properties and thickness, topographical slopes, Epikarst and thickness of unsaturated zone, and hydraulic conductivity among others. Moreover, the model is currently simulated forward using various scenarios for future climate (Global Climate Models GCM; daily downscaled temperature and precipitation time series for Lebanon 2020-2045) in order to depict the flow rates expected in the future and the effect of climate change on hydrographs recession coefficients, discharge maxima and minima, and total spring discharge volume . Additionally, a sensitivity analysis of individual or coupled major parameters allows quantifying their impact on recharge or indirectly on the vulnerability of the system (soil thickness, soil and rock hydraulic conductivity appear to be amongst the highly sensitive parameters). This study particularly unravels the normalized single effect of rain magnitude and intensity, snow, and temperature change on the flow rate (e.g., a change of temperature of 3° on the catchment yields a Residual Mean Square Error RMSE of 0.15 m3/s in the spring discharge and a 16% error in the total annual volume with

Karst groundwater vulnerability mapping to the pollution: Case of Dir springs located between EL KSIBA and Ouaoumana (High Atlas, Morocco)

NASA Astrophysics Data System (ADS)

Alili, L.; Boukdir, A.; Maslouhi, M. R.; Ikhmerdi, H.

2018-05-01

The study area is located in the north of the province of Beni Mellal, it covers the Piedmont of the high Atlas between El Ksiba and Ouaoumana. It is characterized by a poorly developed hydrographic network and the presence of very important karstic forms. These forms condition the rapid infiltration to the karstic springs are the subject of this study. In this work we presented a method of mapping the vulnerability to pollution of Karstic springs located between El Ksiba and Ouaoumana. To do this, we have introduced a vulnerability index called F which takes into account four parameters (EPIK): Development of the Epikarst, importance of the protective cover, infiltration conditions and development of the Karst network. The overlay of the thematic maps of these parameters through a GIS software (ArcGIS) gave us a map of the vulnerability to contamination on the whole hydrogeological basin of the springs.

Water exchange and pressure transfer between conduits and matrix and their influence on hydrodynamics of two karst aquifers with sinking streams

NASA Astrophysics Data System (ADS)

Bailly-Comte, Vincent; Martin, Jonathan B.; Jourde, Hervé; Screaton, Elizabeth J.; Pistre, Séverin; Langston, Abigail

2010-05-01

SummaryKarst aquifers are heterogeneous media where conduits usually drain water from lower permeability volumes (matrix and fractures). For more than a century, various approaches have used flood recession curves, which integrate all hydrodynamic processes in a karst aquifer, to infer physical properties of the movement and storage of groundwater. These investigations typically only consider flow to the conduits and thus have lacked quantitative observations of how pressure transfer and water exchange between matrix and conduit during flooding could influence recession curves. We present analyses of simultaneous discharge and water level time series of two distinctly different karst systems, one with low porosity and permeability matrix rocks in southern France, and one with high porosity and permeability matrix rocks in north-central Florida (USA). We apply simple mathematical models of flood recession using time series representations of recharge, storage, and discharge processes in the karst aquifer. We show that karst spring hydrographs can be interpreted according to pressure transfer between two distinct components of the aquifer, conduit and matrix porosity, which induce two distinct responses at the spring. Water exchange between conduits and matrix porosity successively control the flow regime at the spring. This exchange is governed by hydraulic head differences between conduits and matrix, head gradients within conduits, and the contrast of permeability between conduits and matrix. These observations have consequences for physical interpretations of recession curves and modeling of karst spring flows, particularly for the relative magnitudes of base flow and quick flow from karst springs. Finally, these results suggest that similar analyses of recession curves can be applied to karst aquifers with distinct physical characteristics utilizing well and spring hydrograph data, but information must be known about the hydrodynamics and physical properties of

Caffeine as an indicator for the quantification of untreated wastewater in karst systems.

PubMed

Hillebrand, Olav; Nödler, Karsten; Licha, Tobias; Sauter, Martin; Geyer, Tobias

2012-02-01

Contamination from untreated wastewater leakage and related bacterial contamination poses a threat to drinking water quality. However, a quantification of the magnitude of leakage is difficult. The objective of this work is to provide a highly sensitive methodology for the estimation of the mass of untreated wastewater entering karst aquifers with rapid recharge. For this purpose a balance approach is adapted. It is based on the mass flow of caffeine in spring water, the load of caffeine in untreated wastewater and the daily water consumption per person in a spring catchment area. Caffeine is a source-specific indicator for wastewater, consumed and discharged in quantities allowing detection in a karst spring. The methodology was applied to estimate the amount of leaking and infiltrating wastewater to a well investigated karst aquifer on a daily basis. The calculated mean volume of untreated wastewater entering the aquifer was found to be 2.2 ± 0.5 m(3) d(-1) (undiluted wastewater). It corresponds to approximately 0.4% of the total amount of wastewater within the spring catchment. Copyright © 2011 Elsevier Ltd. All rights reserved.

Sediment discharges during storm flow from proximal urban and rural karst springs, central Kentucky, USA

USGS Publications Warehouse

Reed, T.M.; Todd, McFarland J.; Fryar, A.E.; Fogle, A.W.; Taraba, J.L.

2010-01-01

Since the mid-1990s, various studies have addressed the timing of sediment transport to karst springs during storm flow or the composition and provenance of sediment discharged from springs. However, relatively few studies have focused on the flow thresholds at which sediment is mobilized or total sediment yields across various time scales. We examined each of these topics for a mainly urban spring (Blue Hole) and a rural spring (SP-2) in the Inner Bluegrass region of central Kentucky (USA). Suspended sediment consisted mostly of quartz silt and sand, with lesser amounts of calcite and organic matter. Total suspended sediment (TSS) values measured during storm flow were greater at SP-2 than at Blue Hole. By aggregating data from four storms during 2 years, we found that median suspended-sediment size jumped as Q exceeded ???0.5 m3/s for both springs. At Blue Hole, TSS tended to vary with Q and capacity approached 1 g/L, but no systematic relationship between TSS and Q was evident at SP-2. Sediment fluxes from the Blue Hole basin were ???2 orders of magnitude greater for storms in March (2002 and 2004) than September (2002 and 2003). In contrast, sediment fluxes from the SP-2 basin were of similar magnitude in September 2003 and March 2004. The overall range of area-normalized fluxes for both springs, 9.16 ?? 10-3-4.45 ?? 102 kg/(ha h), overlaps values reported for farm plots and a stream in the Inner Bluegrass region and for other spring basins in the eastern USA and western Europe. Sediment compositions, sizes, and responses to storms in the basins may differ because of land use (e.g., the extent of impervious cover in the Blue Hole basin), basin size (larger for Blue Hole), conduit architecture, which appears to be more complex in the Blue Hole basin, and the impoundment of SP-2, which may have promoted decadal-scale storage of sediment upgradient. ?? 2009 Elsevier B.V. All rights reserved.

Modeling Flow and Pollutant Transport in a Karst Watershed with SWAT

USDA-ARS?s Scientific Manuscript database

Karst hydrology is characterized by multiple springs, sinkholes, and losing streams resulting from acidic water percolating through limestone. These features provide direct connections between surface water and groundwater and increase the risk of groundwater, springs and stream contamination. Anthr...

Quantitative Analysis of Karst Conduit Structure Parameters and Hydraulic Parameters Based on Tracer Test

NASA Astrophysics Data System (ADS)

Qiang, Z.; Zhiqiang, Z.; Xu, M.; Jinyu, S.; Jihong, Q.

2017-12-01

The Old Town of Lijiang is famous as the world cultural heritage since 1997, while characterized by its ancient buildings and natural scenery, water is the soul of the town. Around Heilongtan Springs, there are a large quantity of springs at the Old Town of Lijiang , which is an important part of the World Cultural Heritage. Heilongtan Springs is 2420m above the sea level, the annual variation of the flow rate varies greatly (0 8042 x 104 m3 / year). Recharge area Jiuzihai depressions is 6km long, 3km wide and 2800m above sea level, as main karst water recharge area karst funnel and the sink hole are developing on this planation surface, in the research area medium to thick layers of limestone made up Beiya formation (T2b) of Triassic system distributed widely, karst is strongly developed and the fissure caves water occurrence. In order to exploring the application of tracer test in karst hydrogeology, a tracer test was conducted from Jiuzihai depressions to Ganze Spring. Based on the hydrogeological conditions in the study area, tracer test was used for analysis of groundwater connectivity and flow field characteristics, quantitative analysis of Tracer Breakthrough Curves (BTC) with code Qtracer2. The results demonstated that there are hydraulic connection between Jiuzihai depressions with Ganze Spring, and there are other karst conduits in this area. The longitudinal dispersivity coefficient is 0.24 m2/s, longitudinal dispersivity is 12.06m, flow-channel volume is 3.08×104 m3, flow-channel surface area is 3.27×107m2, mean diameter is 1.42m, Reynolds number is 25187, Froude number is 0.0061, respectively. The groundwater in this area is in a slow turbulent state. The results are of great significance to understand the law of groundwater migration, establish groundwater quality prediction model and exploit karst water resources effectively.

Spatial distribution of nitrogen on grazed karst landscapes.

PubMed

Boyer, D G; Alloush, G A

2001-11-27

The impact on water quality by agricultural activity in karst terrain is an important consideration for resource management within the Appalachian region. Karst areas comprise about 18% of the region"s land area. An estimated one-third of the region"s farms, cattle, and agricultural market value are located on karst terrain. Mean nitrate concentrations in several karst springs in southeastern West Virginia exhibit a strong linear relationship with the percentage of agriculture land cover. Development of best management practices for efficient nitrogen (N) use and reduction of outflow of N to water from karst areas requires knowledge about N dynamics on those landscapes. Water extractable NO3-N and NH4-N were measured along transects at four soil depths in two grazed sinkholes and one wooded sinkhole. Distribution of soil NO3-N and NH4-N were related to frequency of animal presence and to topographic and hydrologic redistribution of soil and fecal matter in the grazed sinkholes. Karst pastures are characterized by under drainage and funneling of water and contaminants to the shallow aquifer. Control of NO3-N leaching from karst pasture may depend on management strategies that change livestock grazing behavior in sinkholes and reduce the opportunity for water and contaminants to quickly reach sinkhole drains.

Numerical Study of Groundwater Flow and Salinity Distribution Cycling Controlled by Seawater/Freshwater Interaction in Karst Aquifer Using SEAWAT

NASA Astrophysics Data System (ADS)

Xu, Z.; Hu, B.

2017-12-01

The interest to predict seawater intrusion and salinity distribution in Woodville Karst Plain (WKP) has increased due to the huge challenge on quality of drinkable water and serious environmental problems. Seawater intrudes into the conduit system from submarine karst caves at Spring Creek Spring due to density difference and sea level rising, nowadays the low salinity has been detected at Wakulla Spring which is 18 km from coastal line. The groundwater discharge at two major springs and salinity distribution in this area is controlled by the seawater/freshwater interaction under different rainfall conditions: during low rainfall periods, seawater flow into the submarine spring through karst windows, then the salinity rising at the submarine spring leads to seawater further intrudes into conduit system; during high rainfall periods, seawater is pushed out by fresh water discharge at submarine spring. The previous numerical studies of WKP mainly focused on the density independent transport modeling and seawater/freshwater discharge at major karst springs, in this study, a SEAWAT model has been developed to fully investigate the salinity distribution in the WKP under repeating phases of low rainfall and high rainfall periods, the conduit system was simulated as porous media with high conductivity and porosity. The precipitation, salinity and discharge at springs were used to calibrate the model. The results showed that the salinity distribution in porous media and conduit system is controlled by the rainfall change, in general, the salinity distribution inland under low rainfall conditions is much higher and wider than the high rainfall conditions. The results propose a prediction on the environmental problem caused by seawater intrusion in karst coastal aquifer, in addition, provide a visual and scientific basis for future groundwater remediation.

Hydrogeological characterization and environmental effects of the deteriorating urban karst groundwater in a karst trough valley: Nanshan, SW China

NASA Astrophysics Data System (ADS)

Jiang, Yongjun; Cao, Min; Yuan, Daoxian; Zhang, Yuanzhu; He, Qiufang

2018-02-01

The unique hydrogeology of karst makes the associated groundwater respond quickly to rainfall events and vulnerable to anthropogenic pollutions. In this study, high-frequency monitoring of spring discharge, temperature, electrical conductivity (EC) and pH, along with monthly hydrochemical and microbial analyses, was undertaken at the outlet of Laolondong karst underground river in Nanshan, southwestern China. The aim was to explore the environmental effects of the catchment's urban area on the karst groundwater resources. The monitoring data of a tracer test and the response of discharge to rainfall events demonstrate that conduits and narrow fissures coexist in the Laolongdong karst aquifer. The EC, Na+, Cl- and SO4 2- values (840 μS/cm, 33.7, 38.6 and 137.2 μg/L, respectively), along with high concentrations of fecal coliform bacteria, at the outlet indicate considerable urban pollution in this area. The contaminants sulfate and nitrate showed different relationships with discharge and EC in different stages of a rainfall event. This behavior provided information about aquifer structure and the influence of transport properties. Meanwhile, the hydrological processes of groundwater flow could be modified by urbanization and result in increasing magnitude of urban floods in the underground river. In addition, sulfuric and nitric acids introduced by urbanization not only impact the karst groundwater quality, but also result in a significant perturbation to the carbon cycling system in the karst area.

Water-quality characteristics and contaminants in the rural karst-dominated Spring Mill Lake watershed, southern Indiana

USGS Publications Warehouse

Hasenmueller, N.R.; Buehler, M.A.; Krothe, N.C.; Comer, J.B.; Branam, T.D.; Ennis, M.V.; Smith, R.T.; Zamani, D.D.; Hahn, L.; Rybarczyk, J.P.

2006-01-01

The Spring Mill Lake watershed is located in the Mitchell Plateau, a karst area that developed on Mississippian carbonates in southern Indiana. Spring Mill Lake is a reservoir built in the late 1930s and is located in Spring Mill State Park. Within the park, groundwater from subsurface conduits issues as natural springs and then flows in surface streams to the lake. From 1998 to 2002, surface and subsurface hydrology and water quality were investigated to determine the types and sources of potential contaminants entering the lake. Water samples collected during base flow and a February 2000 storm event were analyzed for selected cations, anions, trace elements, selected U.S. Environmental Protection Agency (EPA) primary and secondary drinkingwater contaminants, nitrogen isotopes, suspended solids, Escherichia coli, and pesticides. All of the water samples met the EPA drinking-water standards for inorganic constituents, except those collected at five sites in August 1999 during a drought. Nitrate nitrogen (NO3-N) concentrations were highest during base-flow conditions and displayed a dilutional trend during peak-flow periods. The NO3-N concentrations in water samples collected during the 2001 spring fertilizer applications tended to increase from early to late spring. All of the ??15N values were low, which is indicative of either an inorganic source or soil organic matter. Storm discharge contained increased concentrations of total suspended solids; thus, storms are responsible for most of the sediment accumulation in the lake. E. coli levels in 24% of the samples analyzed contained a most probable number (MPN) greater than 235/100 mL, which is the maximum acceptable level set for recreational waters in Indiana. E. coli does appear to be a potential health risk, particularly at Rubble spring. The sources of E. coli found at this spring may include barnyard runoff from a horse barn or wastes from a wastewater treatment facility. The pesticides atrazine, metolachlor

Speleogenesis in Dinaric karst area

NASA Astrophysics Data System (ADS)

Garasic, Mladen; Garasic, Davor

2015-04-01

remarkable variety in types of caves. It is estimated that the Dinaric Karst has at least 100,000 caves, only a fifth of which have been explored and suitably documented so far. Karst caves are truly unique by a variety of their types (dry caves, water caves, cave systems, shafts, spring caves, etc.), by their dimensions (the longest cave systems can reach over 100 km, the deepest ones are more than 1,430 metres deep), and by their great spatial frequency. In the Classical Karst, in area around the town Sežana and Fernetti/Fernetiči there are up to 60 caves/km2 - the number which is unprecedented. The great numbers of cave channels covered in dripstone, types of dripstone and its forms (stalactites, stalagmite, curtains, cave pearls, etc.) only contribute to this abundance. One should not forget the significance of cave sediments for scientific explorations. Their dating was used to determine the age of caves and scientifically explain the dynamics of karst evolution. Another important set of karst features are numerous submarine springs. This is the area where the science of karstology and speleology started to develop, where the basic ideas about the karstification processes (corrosion) and karst hydrology were born. The international term karst and the scientific investigation of karst originate in this region as well as many other international professional terms. Many words, describing karst features, originate from the Dinaric Karst Area, and belong to internationally accepted karst terminology (karst, dolina, polje, vrtača, ponikva, vrulja etc.). The word "karst" was first mentioned in Charter of Juraj Pariježić in 1230 in which "kras" locality near Dobrinj on the Island Krk in Croatia was subject of donation. The first written note that mentions the Italian word "Carso" dates back to the year 1292. In an Austrian document term "Karst" was cited for the first time in 1423. From the etymological point of view the word "Karst" is expression of Indo

Extending GIS Technology to Study Karst Features of Southeastern Minnesota

NASA Astrophysics Data System (ADS)

Gao, Y.; Tipping, R. G.; Alexander, E. C.; Alexander, S. C.

2001-12-01

This paper summarizes ongoing research on karst feature distribution of southeastern Minnesota. The main goals of this interdisciplinary research are: 1) to look for large-scale patterns in the rate and distribution of sinkhole development; 2) to conduct statistical tests of hypotheses about the formation of sinkholes; 3) to create management tools for land-use managers and planners; and 4) to deliver geomorphic and hydrogeologic criteria for making scientifically valid land-use policies and ethical decisions in karst areas of southeastern Minnesota. Existing county and sub-county karst feature datasets of southeastern Minnesota have been assembled into a large GIS-based database capable of analyzing the entire data set. The central database management system (DBMS) is a relational GIS-based system interacting with three modules: GIS, statistical and hydrogeologic modules. ArcInfo and ArcView were used to generate a series of 2D and 3D maps depicting karst feature distributions in southeastern Minnesota. IRIS ExplorerTM was used to produce satisfying 3D maps and animations using data exported from GIS-based database. Nearest-neighbor analysis has been used to test sinkhole distributions in different topographic and geologic settings. All current nearest-neighbor analyses testify that sinkholes in southeastern Minnesota are not evenly distributed in this area (i.e., they tend to be clustered). More detailed statistical methods such as cluster analysis, histograms, probability estimation, correlation and regression have been used to study the spatial distributions of some mapped karst features of southeastern Minnesota. A sinkhole probability map for Goodhue County has been constructed based on sinkhole distribution, bedrock geology, depth to bedrock, GIS buffer analysis and nearest-neighbor analysis. A series of karst features for Winona County including sinkholes, springs, seeps, stream sinks and outcrop has been mapped and entered into the Karst Feature Database

Microbial source tracking in highly vulnerable karst drinking water resources.

PubMed

Diston, D; Robbi, R; Baumgartner, A; Felleisen, R

2018-02-01

Water resources situated in areas with underlying karst geology are particularly vulnerable to fecal pollution. In such vulnerable systems, microbial source tracking (MST) methods are useful tools to elucidate the pathways of both animal and human fecal pollution, leading to more accurate water use risk assessments. Here, we describe the application of a MST toolbox using both culture-dependent bacteriophage and molecular-dependent 16S rRNA assays at spring and well sites in the karstic St Imier Valley, Switzerland. Culture-dependent and molecular-dependent marker performance varied significantly, with the 16S rRNA assays displaying greater sensitivity than their phage counterpart; HF183 was the best performing human wastewater-associated marker while Rum2Bac was the best performing ruminant marker. Differences were observed in pollution regimes between the well and spring sampling sites, with the spring water being more degraded than the well site. Our results inform the choice of marker selection for MST studies and highlight differences in microbial water quality between well and spring karst sites.

Natural and Artificial (fluorescent) Tracers to Characterise Hydrogeological Functioning and to Protect Karst Aquifers

NASA Astrophysics Data System (ADS)

Andreo, B.; Mudarra, M.; Marin, A. I.; Barberá, J. A.

2012-12-01

The hydrogeological functioning and response of karst aquifers can be determined by the joint use of natural hydrogeochemical tracers, especially total organic carbon (TOC) and intrinsic fluorescence of water, together with artificial (fluorescent) tracers, under the same hydrodynamic conditions. Sharp and rapid variations in discharge, temperature, electrical conductivity and water chemistry, particularly of natural tracers of infiltration (TOC, intrinsic fluorescence and NO3-) recorded in karst spring water, confirm the existence of well developed karst conduits in the sector of the aquifer being drained, with rapid flows and very short water transit times from the surface to the springs (Mudarra et al., 2011). This is in agreement with the evidence obtained from breakthrough curves of fluorescent dye tracers (uranine, eosine, etc.). However, time lags between maximum concentrations of natural (especially TOC and intrinsic fluorescence) and artificial tracers show that the global system response is faster than that produced from a recharge concentrated at a point on the surface, even in karst sinkholes. Response and transit times of water through the karst can be calculated using both natural and artificial tracers, but flow velocities can really only be quantified using artificial tracers. Analysis of the responses obtained by natural tracers of infiltration (global system response) and artificial tracers (single response) in karst waters has revealed the usefulness and complementarity of both techniques for characterising the hydrogeological functioning of karst aquifers and, even more important, for validating contamination vulnerability mapping in these medium (Zwahlen, 2004; Andreo et al., 2006). In recent decades, several methods have been developed for such vulnerability mapping, but little progress has been made in validating their results. This validation is essential for the adequate protection of water resources in karst media, as has been shown in

Vulnerability of karst aquifers to agricultural contaminants: A case study in the Pennyroyal Plateau of Kentucky

USDA-ARS?s Scientific Manuscript database

Karst landscapes are common in many agricultural regions in the US. Well-developed karst landscapes are characterized by shallow soils, sinkholes, sinking streams, underground conduits, and springs. In these landscapes surface runoff is minimal and most recharge enters the subsurface relatively quic...

U.S. Geological Survey Karst Interest Group Proceedings, Bowling Green, Kentucky, May 27-29, 2008

USGS Publications Warehouse

Kuniansky, Eve L.

2008-01-01

*INTRODUCTION AND ACKNOWLEDGMENTS* Karst aquifer systems are present throughout parts of the United States and some of its territories. The complex depositional environments that form carbonate rocks combined with post-depositional tectonic events and the diverse climatic regimes under which these rocks were formed result in unique hydrologic systems. The dissolution of calcium carbonate and the subsequent development of distinct and beautiful landscapes, caverns, and springs have resulted in some karst areas of the United States being designated as national or state parks and commercial caverns. Karst aquifers and landscapes that form in tropical areas, such as the north coast of Puerto Rico, differ greatly from karst areas in more arid climates, such as central Texas or western South Dakota. Many of these public and private lands contain unique flora and fauna associated with the hydrologic systems in these karst areas. As a result, multiple Federal, State, and local agencies have an interest in the study of karst terrains. Carbonate sediments and rocks (limestone and dolomite) are composed of greater than 50 percent carbonate minerals and the predominant carbonate mineral is calcium carbonate or limestone (CaCO3). Unlike terrigenous clastic sedimentation, the depositional processes that produce carbonate rocks are complex, involving both biological and physical processes. These depositional processes impact greatly the development of permeability of the sediments. Carbonate minerals readily dissolve or precipitate depending on the chemistry of the water flowing through the rock, thus the study of both marine and meteoric diagenesis of carbonate sediments is multidisciplinary. Even with a better understanding of the depositional environment and subsequent diagenesis, the dual porosity nature of karst aquifers presents challenges to scientists attempting to study ground-water flow and contaminant transport. Many of the major springs and aquifers in the United

Simulating flow in karst aquifers at laboratory and sub-regional scales using MODFLOW-CFP

NASA Astrophysics Data System (ADS)

Gallegos, Josue Jacob; Hu, Bill X.; Davis, Hal

2013-12-01

Groundwater flow in a well-developed karst aquifer dominantly occurs through bedding planes, fractures, conduits, and caves created by and/or enlarged by dissolution. Conventional groundwater modeling methods assume that groundwater flow is described by Darcian principles where primary porosity (i.e. matrix porosity) and laminar flow are dominant. However, in well-developed karst aquifers, the assumption of Darcian flow can be questionable. While Darcian flow generally occurs in the matrix portion of the karst aquifer, flow through conduits can be non-laminar where the relation between specific discharge and hydraulic gradient is non-linear. MODFLOW-CFP is a relatively new modeling program that accounts for non-laminar and laminar flow in pipes, like karst caves, within an aquifer. In this study, results from MODFLOW-CFP are compared to those from MODFLOW-2000/2005, a numerical code based on Darcy's law, to evaluate the accuracy that CFP can achieve when modeling flows in karst aquifers at laboratory and sub-regional (Woodville Karst Plain, Florida, USA) scales. In comparison with laboratory experiments, simulation results by MODFLOW-CFP are more accurate than MODFLOW 2005. At the sub-regional scale, MODFLOW-CFP was more accurate than MODFLOW-2000 for simulating field measurements of peak flow at one spring and total discharges at two springs for an observed storm event.

Karst geomorphology and hydrology of the Shenandoah Valley near Harrisonburg, Virginia

USGS Publications Warehouse

Doctor, Daniel H.; Orndorff, Wil; Maynard, Joel; Heller, Matthew J.; Casile, Gerolamo C.

2014-01-01

The karst of the central Shenandoah Valley has characteristics of both shallow and deep phreatic formation. This field guide focuses on the region around Harrisonburg, Virginia, where a number of these karst features and their associated geologic context can be examined. Ancient, widespread alluvial deposits cover much of the carbonate bedrock on the western side of the valley, where shallow karstification has resulted in classical fluviokarst development. However, in upland exposures of carbonate rock, isolated caves exist atop hills not affected by surface processes other than exposure during denudation. The upland caves contain phreatic deposits of calcite and fine-grained sediments. They lack any evidence of having been invaded by surface streams. Recent geologic mapping and LIDAR (light detection and ranging) elevation data have enabled interpretive association between bedrock structure, igneous intrusions, silicification and brecciation of host carbonate bedrock, and the location of several caves and karst springs. Geochemistry, water quality, and water temperature data support the broad categorization of springs into those affected primarily by shallow near-surface recharge, and those sourced deeper in the karst aquifer. The deep-seated karst formation occurred in the distant past where subvertical fracture and fault zones intersect thrust faults and/or cross-strike faults, enabling upwelling of deep-circulating meteoric groundwater. Most caves formed in such settings have been overprinted by later circulation of shallow groundwater, thus removing evidence of the history of earliest inception; however, several caves do preserve evidence of an earlier formation.

Transport of suspended solids from a karstic to an alluvial aquifer: The role of the karst/alluvium interface

USGS Publications Warehouse

Massei, N.; Lacroix, M.; Wang, H.Q.; Mahler, B.J.; Dupont, J.P.

2002-01-01

This study focuses on the coupled transport of dissolved constituents and particulates, from their infiltration on a karst plateau to their discharge from a karst spring and their arrival at a well in an alluvial plain. Particulate markers were identified and the transport of solids was characterised in situ in porous and karstic media, based on particle size analyses, SEM, and traces. Transport from the sinkhole to the spring appeared to be dominated by flow through karst: particulate transport was apparently conservative between the two sites, and there was little difference in the overall character of the particle size distribution of the particulates infiltrating the sinkhole and of those discharging from the spring. Qualitatively, the mineralogy of the infiltrating and discharging material was similar, although at the spring an autochthonous contribution from the aquifer was noted (chalk particles eroded from the parent rock by weathering). In contrast, transport between the spring and the well appears to be affected by the overlying alluvium: particles in the water from the well, showed evidence of considerable size-sorting. Additionally, SEM images of the well samples showed the presence of particles originating from the overlying alluvial system; these particles were not found in samples from the sinkhole or the spring. The differences between the particulates discharging from the spring and the well indicate that the water pumped from the alluvial plain is coming from the karst aquifer via the very transmissive, complex geologic interface between the underlying chalk formation and the gravel at the base of the overlying alluvial system. ?? 2002 Elsevier Science B.V. All rights reserved.

Assessment of vulnerability in karst aquifers using a quantitative integrated numerical model: catchment characterization and high resolution monitoring - Application to semi-arid regions- Lebanon.

NASA Astrophysics Data System (ADS)

Doummar, Joanna; Aoun, Michel; Andari, Fouad

2016-04-01

Karst aquifers are highly heterogeneous and characterized by a duality of recharge (concentrated; fast versus diffuse; slow) and a duality of flow which directly influences groundwater flow and spring responses. Given this heterogeneity in flow and infiltration, karst aquifers do not always obey standard hydraulic laws. Therefore the assessment of their vulnerability reveals to be challenging. Studies have shown that vulnerability of aquifers is highly governed by recharge to groundwater. On the other hand specific parameters appear to play a major role in the spatial and temporal distribution of infiltration on a karst system, thus greatly influencing the discharge rates observed at a karst spring, and consequently the vulnerability of a spring. This heterogeneity can only be depicted using an integrated numerical model to quantify recharge spatially and assess the spatial and temporal vulnerability of a catchment for contamination. In the framework of a three-year PEER NSF/USAID funded project, the vulnerability of a karst catchment in Lebanon is assessed quantitatively using a numerical approach. The aim of the project is also to refine actual evapotranspiration rates and spatial recharge distribution in a semi arid environment. For this purpose, a monitoring network was installed since July 2014 on two different pilot karst catchment (drained by Qachqouch Spring and Assal Spring) to collect high resolution data to be used in an integrated catchment numerical model with MIKE SHE, DHI including climate, unsaturated zone, and saturated zone. Catchment characterization essential for the model included geological mapping and karst features (e.g., dolines) survey as they contribute to fast flow. Tracer experiments were performed under different flow conditions (snow melt and low flow) to delineate the catchment area, reveal groundwater velocities and response to snowmelt events. An assessment of spring response after precipitation events allowed the estimation of the

Unprotected karst resources in western Iran: the environmental impacts of intensive agricultural pumping on the covered karstic aquifer, a case in Kermanshah province

NASA Astrophysics Data System (ADS)

Taheri, Kamal; Taheri, Milad; Parise, Mario

2015-04-01

Bare and covered karst areas, with developed karstic aquifers, cover 35 percent of the Kermanshah province in western Iran. These aquifers are the vital sources for drinking and agricultural water supplies. Over the past decade, intensive groundwater use (exploitation) for irrigation imposed a significant impact on the carbonate environments. The huge amount of groundwater over-exploitations has been carried out and still goes on by local farmers in the absence of appropriate governance monitoring control. Increasing in water demands, for more intense crop production, is an important driving force toward groundwater depletion in alluvial aquifers. Progressive groundwater over-exploitations from underlying carbonate rocks have led to dramatic drawdown in alluvial aquifers and deep karst water tables. Detecting new sources of groundwater extractions and prohibiting the karst water utilization for agricultural use could be the most effective strategy to manage the sustainability of covered karst aquifers. Anthropogenic pressures on covered karst aquifers have magnified the drought impacts and caused dryness of most of the karst springs and deep wells. In this study, the combination of geophysical and geological studies was used to estimate the most intensively exploited agricultural zones of Islam Abad plain in the southwestern Kermanshah province using GIS. The results show that in the past decade a great number of deep wells were drilled through the overburden alluvial aquifer and reached the deep karst water resources. However, the difficulties involved in monitoring deep wells in covered karst aquifer were the main cause of karst water depletion. Overexploitation from both alluvial and karst aquifers is the main reason for drying out the Arkawazi, Sharafshah, Gawrawani karst springs, and the karst drinking water wells 1, 3 and 5 of Islam Abad city. Karst spring landscape destructions, fresh water supply deficit for inhabitants, decreasing of tourism and

SWISSKARST Project - how to document the karst aquifers in Switzerland using the KARSYS approach.

NASA Astrophysics Data System (ADS)

Malard, A.; Vouillamoz, J.; Jeannin, P.-Y.; Weber, E.; Eichenberger, U.

2012-04-01

Swiss karst aquifers are poorly documented although they represent a resource estimated to around 120 km3 of fresh water - which is comparable to the water volume of all Swiss lakes. Within the framework of the Swiss National Research Program 61 an opportunity was given to develop a systematic way to characterize karst aquifers and to describe their hydrological behaviour. The project aims at providing methodologies or guidelines to approach karst systems and to improve their management. This covers a large range of fields such as water supply, civil engineering, renewable energies, natural hazards, etc. In this context SISKA developed a dedicated approach named KARSYS for KARst SYStems characterization. It is based on iterations of 3D geological models combined with some basic hydraulic principles taking place in karst media. The main principles are: (i) The 3D geometry of the aquifer set the framework in which flow processes take place (ii) Aquifers are flooded below the level of the main perennial springs (iii) The expansion of the water table upstream of the main springs is lower than 1% (low water stage). High water gradients are simulated according to the elevation of temporary springs or observations in existing boreholes or caves. The approach explicitly shows through 3D visual that some groundwater bodies may be separated at low water stage and connected at high water. Such 3D views bring often explanations to the interpretation of "strange" or "not repeatable" dye tracer's results. A major input of KARSYS approach is to provide a systematic construction of a conceptual model for all hydrological karst systems. It also considers interactions between adjacent systems, providing new concepts on the delineation of karst systems. KARSYS approach can be applied in a quick and approximate way and improved along in order to reach a precision according to the question to be addressed. Results of KARSYS applications are: (i) The delineation of catchment areas of

Possibilities and Challenges for Modeling Flow and Pollutant Transport in a Karst Watershed with SWAT

USDA-ARS?s Scientific Manuscript database

Karst hydrology is characterized by multiple springs, sinkholes, and losing streams resulting from acidic water percolating through limestone. These features provide direct connections between surface water and groundwater and increase the risk of groundwater, spring and stream contamination. Anthro...

Effectiveness of airborne multispectral thermal data for karst groundwater resources recognition in coastal areas

NASA Astrophysics Data System (ADS)

Pignatti, Stefano; Fusilli, Lorenzo; Palombo, Angelo; Santini, Federico; Pascucci, Simone

2013-04-01

Currently the detection, use and management of groundwater in karst regions can be considered one of the most significant procedures for solving water scarcity problems during periods of low rainfall this because groundwater resources from karst aquifers play a key role in the water supply in karst areas worldwide [1]. In many countries of the Mediterranean area, where karst is widespread, groundwater resources are still underexploited, while surface waters are generally preferred [2]. Furthermore, carbonate aquifers constitute a crucial thermal water resource outside of volcanic areas, even if there is no detailed and reliable global assessment of thermal water resources. The composite hydrogeological characteristics of karst, particularly directions and zones of groundwater distribution, are not up till now adequately explained [3]. In view of the abovementioned reasons the present study aims at analyzing the detection capability of high spatial resolution thermal remote sensing of karst water resources in coastal areas in order to get useful information on the karst springs flow and on different characteristics of these environments. To this purpose MIVIS [4, 5] and TASI-600 [6] airborne multispectral thermal imagery (see sensors' characteristics in Table 1) acquired on two coastal areas of the Mediterranean area interested by karst activity, one located in Montenegro and one in Italy, were used. One study area is located in the Kotor Bay, a winding bay on the Adriatic Sea surrounded by high mountains in south-western Montenegro and characterized by many subaerial and submarine coastal springs related to deep karstic channels. The other study area is located in Santa Cesarea (Italy), encompassing coastal cold springs, the main local source of high quality water, and also a noticeable thermal groundwater outflow. The proposed study shows the preliminary results of the two airborne deployments on these areas. The preprocessing of the multispectral thermal imagery

Chemical Source Tracking of Bacterial Contamination Using Micropollutants - A Karst Aquifer Case Study

NASA Astrophysics Data System (ADS)

Zirlewagen, Johannes; Hillebrand, Olav; Nödler, Karsten; Licha, Tobias; Schiperski, Ferry; Stange, Claudia; Tiehm, Andreas; Scheytt, Traugott

2015-04-01

Karst aquifers are important drinking water resources in many parts of the world, though they are well known for their high vulnerability to contamination. Rainfall and snowmelt often trigger temporary contamination of karst water resources. Free-range animal breeding and application of manure on the one hand and sewage leakage or spillage on the other hand are usually regarded as main sources for fecal contamination. But distinction of their respective contributions is difficult. This study investigates the feasibility to track the origin of fecal contamination from the occurrences of indicator bacteria and chemical source indicators in karst spring water. The study site is the 45 km² rural catchment of the perennial karst spring Gallusquelle in SW-Germany (mean discharge: 0.5 m³/s). Overflow events of a stormwater detention basin (combined sewer system) are known to impact water quality at the spring. There is no free-range animal breeding in the catchment but intense application of manure. Following two heavy rainfall events with overflow of the stormwater detention basin, spring water was sampled over several days. Samples were analysed for indicator bacteria (total Coliform, E. coli, Enterococci) and 57 micropollutants, among them cyclamate and metazachlor. For the Gallusquelle catchment the artificial sweetener cyclamate and the herbicide metazachlor have been established as source specific indicators, the former for the sewer system and the latter for cropland. Though recharge in the Gallusquelle catchment is predominantly diffuse, there is a significant portion of direct recharge reflected by distinct breakthrough curves for cyclamate and metazachlor. The breakthrough of indicator bacteria coincides very well with the occurrence of both, cyclamate and metazachlor. However, indicator bacteria cannot be unambiguously tracked back to a specific source.

Characterizing fate and transport properties in karst aquifers under different hydrologic conditions

NASA Astrophysics Data System (ADS)

Rodriguez, E.; Padilla, I. Y.

2017-12-01

Karst landscapes contain very productive aquifers. The hydraulic and hydrogeological characteristics of karst aquifers make these systems capable of storing and transporting large amount of water, but also highly vulnerable to contamination. Their extremely heterogeneous nature prevents accurate prediction in contaminant fate and transport. Even more challenging is to understand the impact of hydrologic conditions changes on fate and transport processes. This studies aims at characterizing fate and transport processes in the karst groundwater system of northern Puerto Rico under different hydrologic conditions. The study involves injecting rhodamine and uranine dyes into a sinkhole, and monitoring concentrations at a spring. Results show incomplete recovery of tracers, but breaking curves can be used to estimate advective, dispersive and mass transfer characteristic of the karst system. Preliminary results suggest significant differences in fate and transport characteristics under different hydrologic conditions.

Using nitrate to quantify quick flow in a karst aquifer

USGS Publications Warehouse

Mahler, B.J.; Garner, B.D.

2009-01-01

In karst aquifers, contaminated recharge can degrade spring water quality, but quantifying the rapid recharge (quick flow) component of spring flow is challenging because of its temporal variability. Here, we investigate the use of nitrate in a two-endmember mixing model to quantify quick flow in Barton Springs, Austin, Texas. Historical nitrate data from recharging creeks and Barton Springs were evaluated to determine a representative nitrate concentration for the aquifer water endmember (1.5 mg/L) and the quick flow endmember (0.17 mg/L for nonstormflow conditions and 0.25 mg/L for stormflow conditions). Under nonstormflow conditions for 1990 to 2005, model results indicated that quick flow contributed from 0% to 55% of spring flow. The nitrate-based two-endmember model was applied to the response of Barton Springs to a storm and results compared to those produced using the same model with ??18O and specific conductance (SC) as tracers. Additionally, the mixing model was modified to allow endmember quick flow values to vary over time. Of the three tracers, nitrate appears to be the most advantageous because it is conservative and because the difference between the concentrations in the two endmembers is large relative to their variance. The ??18O- based model was very sensitive to variability within the quick flow endmember, and SC was not conservative over the timescale of the storm response. We conclude that a nitrate-based two-endmember mixing model might provide a useful approach for quantifying the temporally variable quick flow component of spring flow in some karst systems. ?? 2008 National Ground Water Association.

The World Karst Aquifer Mapping project: concept, mapping procedure and map of Europe

NASA Astrophysics Data System (ADS)

Chen, Zhao; Auler, Augusto S.; Bakalowicz, Michel; Drew, David; Griger, Franziska; Hartmann, Jens; Jiang, Guanghui; Moosdorf, Nils; Richts, Andrea; Stevanovic, Zoran; Veni, George; Goldscheider, Nico

2017-05-01

Karst aquifers contribute substantially to freshwater supplies in many regions of the world, but are vulnerable to contamination and difficult to manage because of their unique hydrogeological characteristics. Many karst systems are hydraulically connected over wide areas and require transboundary exploration, protection and management. In order to obtain a better global overview of karst aquifers, to create a basis for sustainable international water-resources management, and to increase the awareness in the public and among decision makers, the World Karst Aquifer Mapping (WOKAM) project was established. The goal is to create a world map and database of karst aquifers, as a further development of earlier maps. This paper presents the basic concepts and the detailed mapping procedure, using France as an example to illustrate the step-by-step workflow, which includes generalization, differentiation of continuous and discontinuous carbonate and evaporite rock areas, and the identification of non-exposed karst aquifers. The map also shows selected caves and karst springs, which are collected in an associated global database. The draft karst aquifer map of Europe shows that 21.6% of the European land surface is characterized by the presence of (continuous or discontinuous) carbonate rocks; about 13.8% of the land surface is carbonate rock outcrop.

Conduit enlargement in an eogenetic karst aquifer

NASA Astrophysics Data System (ADS)

Moore, Paul J.; Martin, Jonathan B.; Screaton, Elizabeth J.; Neuhoff, Philip S.

2010-11-01

SummaryMost concepts of conduit development have focused on telogenetic karst aquifers, where low matrix permeability focuses flow and dissolution along joints, fractures, and bedding planes. However, conduits also exist in eogenetic karst aquifers, despite high matrix permeability which accounts for a significant component of flow. This study investigates dissolution within a 6-km long conduit system in the eogenetic Upper Floridan aquifer of north-central Florida that begins with a continuous source of allogenic recharge at the Santa Fe River Sink and discharges from a first-magnitude spring at the Santa Fe River Rise. Three sources of water to the conduit include the allogenic recharge, diffuse recharge through epikarst, and mineralized water upwelling from depth. Results of sampling and inverse modeling using PHREEQC suggest that dissolution within the conduit is episodic, occurring only during 30% of 16 sampling times between March 2003 and April 2007. During low flow conditions, carbonate saturated water flows from the matrix to the conduit, restricting contact between undersaturated allogenic water with the conduit wall. When gradients reverse during high flow conditions, undersaturated allogenic recharge enters the matrix. During these limited periods, estimates of dissolution within the conduit suggest wall retreat averages about 4 × 10 -6 m/day, in agreement with upper estimates of maximum wall retreat for telogenetic karst. Because dissolution is episodic, time-averaged dissolution rates in the sink-rise system results in a wall retreat rate of about 7 × 10 -7 m/day, which is at the lower end of wall retreat for telogenetic karst. Because of the high permeability matrix, conduits in eogenetic karst thus enlarge not just at the walls of fractures or pre-existing conduits such as those in telogenetic karst, but also may produce a friable halo surrounding the conduits that may be removed by additional mechanical processes. These observations stress the

Geologic map of the Alley Spring quadrangle, Shannon County, Missouri

USGS Publications Warehouse

Weary, David J.; Orndorff, Randall C.

2012-01-01

The Alley Spring 7.5-minute quadrangle is located in south-central Missouri within the Salem Plateau region of the Ozark Plateaus physiographic province. About 1,990 feet (ft) of flat-lying to gently dipping Lower Paleozoic sedimentary rocks, mostly dolomite, chert, sandstone, and orthoquartzite, overlie Mesoproterozoic volcanic rocks. A small exposure of the volcanic rocks exists near the eastern edge of the quadrangle. Unconsolidated residuum, colluvium, terrace deposits, and alluvium overlie the sedimentary rocks. Karst features, such as sinkholes, caves, and springs, have formed in the carbonate rocks. Many streams are spring fed. Alley Spring, the largest karst spring in the quadrangle, has an average discharge of 81 million gallons per day. The topography is a dissected karst plain with elevation ranging from 630 ft where the Jacks Fork River exits the quadrangle to more than 1,140 ft at numerous places in the northern half of the quadrangle. The most prominent physiographic feature is the valley of the Jacks Fork River. Most of the land in the quadrangle is privately owned and used primarily for grazing cattle and horses and growing timber. A large minority of the land within the quadrangle is publicly owned, either by the Missouri State Forests or by the Ozark National Scenic Riverways of the National Park Service. Geologic mapping for this investigation was conducted in 2003 and 2004.

[Substances transport in an underground river of typical karst watershed during storm events].

PubMed

Yang, Ping-Heng; Kuang, Ying-Lun; Yuan, Wen-Hao; Jia, Peng; He, Qiu-Fang; Lin, Yu-Shi

2009-11-01

Hydrologic process, turbidity, suspended particles matters (SPM), major cations and TOC concentrations during two storm events in late April 2008 were monitored at Jiangjia Spring which is the outlet of Qingmu Guan underground river system. Scanning electron microscopy (SEM) and energy disperse spectroscopy (EDS) analyses of SPM were also performed in order to investigate the transport characteristics of substances, such as SPM, turbidity and major cations in the underground river of typical karst watershed. The results show that at a single and well-developed karst conduit of Jiangjia Spring, discharge, turbidity, and concentrations of SPM, major cations and TOC respond promptly to the rainfall. The carbonate-derived cations including Ca2+, Mg2+ and Sr2+ are subject to dilution effect during the rising limb of discharge. The elevation in turbidity and SPM concentration is a result of the gradual increase of allochthonous substances (soil) flux input from the surface. Al3+, Fe, Mn, Ba2+ and TOC are concomitant substances of SPM. And their concentrations are ascending with turbid rise. The flux of SPM in diameter > 0.45 microm in the underground river is about 9.7 tons during the events. The bad water quality suggests us that the spring water is unfit to drink without purification during the period of rising and recession time of discharge at Jiangjia Spring. Thus, soil erosion and nutrient losing not only strongly destroy the fragile karst ecological environment, but also lead to non-point source pollution, and seriously threaten the drinking water safety of locals.

Numerical study of groundwater flow cycling controlled by seawater/freshwater interaction in a coastal karst aquifer through conduit network using CFPv2

NASA Astrophysics Data System (ADS)

Xu, Zexuan; Hu, Bill X.; Davis, Hal; Kish, Stephen

2015-11-01

In this study, a groundwater flow cycling in a karst springshed and an interaction between two springs, Spring Creek Springs and Wakulla Springs, through a subground conduit network are numerically simulated using CFPv2, the latest research version of MODFLOW-CFP (Conduit Flow Process). The Spring Creek Springs and Wakulla Springs, located in a marine estuary and 11 miles inland, respectively, are two major groundwater discharge spots in the Woodville Karst Plain (WKP), North Florida, USA. A three-phase conceptual model of groundwater flow cycling between the two springs and surface water recharge from a major surface creek (Lost Creek) was proposed in various rainfall conditions. A high permeable subground karst conduit network connecting the two springs was found by tracer tests and cave diving. Flow rate of discharge, salinity, sea level and tide height at Spring Creek Springs could significantly affect groundwater discharge and water stage at Wakulla Springs simultaneously. Based on the conceptual model, a numerical hybrid discrete-continuum groundwater flow model is developed using CFPv2 and calibrated by field measurements. Non-laminar flows in conduits and flow exchange between conduits and porous medium are implemented in the hybrid coupling numerical model. Time-variable salinity and equivalent freshwater head boundary conditions at the submarine spring as well as changing recharges have significant impacts on seawater/freshwater interaction and springs' discharges. The developed numerical model is used to simulate the dynamic hydrological process and quantitatively represent the three-phase conceptual model from June 2007 to June 2010. Simulated results of two springs' discharges match reasonably well to measurements with correlation coefficients 0.891 and 0.866 at Spring Creeks Springs and Wakulla Springs, respectively. The impacts of sea level rise on regional groundwater flow field and relationship between the inland springs and submarine springs are

Modeling a network of turloughs in lowland karst

NASA Astrophysics Data System (ADS)

Gill, L. W.; Naughton, O.; Johnston, P. M.

2013-06-01

In lowland karst areas of Ireland topographic depressions which get intermittently flooded on an annual cycle via groundwater sources are termed turloughs. These are sites of high ecological interest as they have communities and substrate characteristic of wetlands. The flooding in many turlough basins is due to insufficient capacity of the underground karst system to take increased flows following excessive precipitation events, causing the conduit-type network to surcharge. Continuous water level measurements have been taken in five linked turloughs in the lowland karst area of south Galway over a 3 year period. These water level fluctuations, in conjunction with river inputs and precipitation, were then used to elucidate the hydrogeological controls forming the hydraulic system beneath the ground. A model of the karst network has been developed using a pipe network model with the turloughs represented as ponds. The contribution to the karst network from diffuse flow through the epikarst via the matrix and fracture flow has also been modeled using a combination of an infiltration module and network of permeable pipes. The final model was calibrated against two separate hydrological years and in general provided a good simulation for all of the turloughs water levels particularly for the year with one main filling event. The model also accurately picked up the tidal response observed in these turloughs at shallow depths. The model has been used to predict the groundwater discharge to the coast via the main spring which had not heretofore been possible to measure, being below the sea level.

Hydrogeological controls of variable microbial water quality in a complex subtropical karst system in Northern Vietnam

NASA Astrophysics Data System (ADS)

Ender, Anna; Goeppert, Nadine; Goldscheider, Nico

2018-05-01

Karst aquifers are particularly vulnerable to bacterial contamination. Especially in developing countries, poor microbial water quality poses a threat to human health. In order to develop effective groundwater protection strategies, a profound understanding of the hydrogeological setting is crucial. The goal of this study was to elucidate the relationships between high spatio-temporal variability in microbial contamination and the hydrogeological conditions. Based on extensive field studies, including mapping, tracer tests and hydrochemical analyses, a conceptual hydrogeological model was developed for a remote and geologically complex karst area in Northern Vietnam called Dong Van. Four different physicochemical water types were identified; the most important ones correspond to the karstified Bac Son and the fractured Na Quan aquifer. Alongside comprehensive investigation of the local hydrogeology, water quality was evaluated by analysis for three types of fecal indicator bacteria (FIB): Escherichia coli, enterococci and thermotolerant coliforms. The major findings are: (1) Springs from the Bac Son formation displayed the highest microbial contamination, while (2) springs that are involved in a polje series with connections to sinking streams were distinctly more contaminated than springs with a catchment area characterized by a more diffuse infiltration. (3) FIB concentrations are dependent on the season, with higher values under wet season conditions. Furthermore, (4) the type of spring capture also affects the water quality. Nevertheless, all studied springs were faecally impacted, along with several shallow wells within the confined karst aquifer. Based on these findings, effective protection strategies can be developed to improve groundwater quality.

Seismic Signals Recorded During Artificial and Natural Karst Recharge Events

NASA Astrophysics Data System (ADS)

Bilek, S. L.; Luhmann, A. J.; Diniakos, R. S.; Morton, E.; Rinehart, A. J.; Alexander, E. C., Jr.; Alexander, S. C.; Larsen, M.; Green, J. A.

2016-12-01

Seismology has recently been used to explore a variety of surficial processes, including tracking landslides, glaciers, and river flow. The seismic data collected can provide useful information about these flow processes, particularly in areas where other flow-related observations are difficult to make. Underground flow through karst aquifers is an area of significant interest, where most of the flow occurs through preferential flow conduits whose locations are largely unknown. We investigate seismic signals generated by both controlled and natural recharge into a karst aquifer system located near Bear Spring, near Eyota, MN, USA. The controlled recharge experiments involved injecting a pool full of water ( 13,000 L) into a dry overflow spring, which then flowed underground until it was discharged at Bear Spring. The natural recharge fortuitously involved a large rainstorm that supplied over 2 inches of rain in a few hour period, which caused the overflow spring to start flowing and total discharge to increase from a background of 100 L/s to 300 L/s. These events were recorded by 12 seismometers (11 short period and 1 broadband with 500 Hz sampling rate) all placed within the 4500 m2 area containing the dry overflow spring and predicted underground flow path. Spectrograms for the artificial and natural recharge events show significant seismic energy over a broad frequency range (few to nearly 220 Hz) during the periods of artificial recharge, largely contained during the period of water injection. Stations closest to Bear Spring see peak seismic energy in the 20-30 Hz range during these tests, likely related to changes in the underground water flow. During the natural recharge event, we find much longer duration of seismic energy over the broad frequency range. We compare these seismic results with discharge measurements conducted during all tests at Bear Spring, as well as with rainfall measurements recorded for the natural recharge event.

Hochauflösendes Monitoring von Karst-Grundwasserressourcen beiderseits des Jordangrabens - Konzepte und Anwendungsbeispiele

NASA Astrophysics Data System (ADS)

Schmidt, Sebastian; Grimmeisen, Felix; Ries, Fabian; Goldscheider, Nico; Sauter, Martin

2018-03-01

In the semi-arid eastern Mediterranean water supply is highly dependent on karst aquifers. The region is characterized by multi-year dry and wet cycles combined with high hydrological dynamics, especially during intense precipitation events. The investigated karst regions in the West Bank and Jordan are experiencing strong urbanization within the groundwater catchments and hence a rising impact on water quality. Therefore, high resolution monitoring data are required for the assessment of available water resources and the hydrogeological characterization of the karst systems. These measurements are focused on the (natural) meteorological input signals and the system output signals at the karst springs. Also soil moisture and ephemeral runoff dynamics are investigated. The monitoring data enable (1) hydrogeological characterization of the aquifers, (2) estimation of groundwater recharge via soil water balance and reservoir models, and (3) assessment of contamination dynamics in groundwater (e. g. nitrate and E. coli concentrations), allowing an optimized raw water management. Several examples illustrate the importance of high-resolution hydrological monitoring data.

Recharge mixing in a complex distributary spring system in the Missouri Ozarks, USA

USDA-ARS?s Scientific Manuscript database

Toronto Springs is a complex distributary karst spring system with 11 perennial springs in the central Missouri Ozarks, USA. Carroll Cave (CC) and Wet Glaize Creek (WG) were previously identified as principal recharge sources. This study 1) characterized physical and chemical properties of the sprin...

CO2 outgassing in a combined fracture and conduit karst aquifer near lititz spring, Pennsylvania

USGS Publications Warehouse

Toran, L.; Roman, E.

2006-01-01

Lititz Spring in southeastern Pennsylvania and a nearby domestic well were sampled for 9 months. Although both locations are connected to conduits (as evidenced by a tracer test), most of the year they were saturated with respect to calcite, which is more typical of matrix flow. Geochemical modeling (PHREEQC) was used to explain this apparent paradox and to infer changes in matrix and conduit contribution to flow. The saturation index varied from 0.5 to 0 most of the year, with a few samples in springtime dropping below saturation. The log PCO2 value varied from -2.5 to -1.7. Lower log PCO2 values (closer to the atmospheric value of -3.5) were observed when the solutions were at or above saturation with respect to calcite. In contrast, samples collected in the springtime had high PCO2, low saturation indices, and high water levels. Geochemical modeling showed that when outgassing occurs from a water with initially high PCO2, the saturation index of calcite increases. In the Lititz Spring area, the recharge water travels through the soil zone, where it picks up CO2 from soil gas, and excess CO 2 subsequently is outgassed when this recharge water reaches the conduit. At times of high water level (pipe full), recharge with excess CO 2 enters the system but the outgassing does not occur. Instead the recharge causes dilution, reducing the calcite saturation index. Understanding the temporal and spatial variation in matrix and conduit flow in karst aquifers benefited here by geochemical modeling and calculation of PCO2 values. ?? 2006 Geological Society of America.

Geologic Map of the Round Spring Quadrangle, Shannon County, Missouri

USGS Publications Warehouse

Orndorff, Randall C.; Weary, David J.

2009-01-01

The Round Spring 7.5-minute quadrangle is located in Shannon County, south-central Missouri on the Salem Plateau of the Ozark Plateaus physiographic province. As much as 1,350 feet (ft) of flat-lying to gently dipping Upper Cambrian and Lower Ordovician rocks, mostly dolomite, overlie Mesoproterozoic volcanic rocks. The bedrock is overlain by unconsolidated residuum, colluvium, terrace deposits, and alluvium. Karst features, such as small sinkholes and caves, have formed in the carbonate rocks, and many streams are spring fed. The topography is a dissected karst plain with elevation ranging from 650 ft along the Current River on the eastern edge of the quadrangle to almost 1,200 ft at various places on the ridge tops. The area is mostly forested but contains some farmlands and includes sections of the Ozark National Scenic Riverways of the National Park Service along the Current River. Geologic mapping for this investigation began in the spring of 2001 and was completed in the spring of 2002.

Importance of nonlocal electron correlation in the BaNiS2 semimetal from quantum oscillations studies

NASA Astrophysics Data System (ADS)

Klein, Yannick; Casula, Michele; Santos-Cottin, David; Audouard, Alain; Vignolles, David; Fève, Gwendal; Freulon, Vincent; Plaçais, Bernard; Verseils, Marine; Yang, Hancheng; Paulatto, Lorenzo; Gauzzi, Andrea

2018-02-01

By means of Shubnikov-de Haas and de Haas-van Alphen oscillations, and ab initio calculations, we have studied the Fermi surface of high-quality BaNiS2 single crystals, with mean free path l ˜400 Å . The angle and temperature dependence of quantum oscillations indicates a quasi-two-dimensional Fermi surface, made of an electronlike tube centered at Γ , and of four holelike cones, generated by Dirac bands, weakly dispersive in the out-of-plane direction. Ab initio electronic structure calculations, in the density functional theory framework, show that the inclusion of screened exchange is necessary to account for the experimental Fermi pockets. Therefore, the choice of the functional becomes crucial. A modified HSE hybrid functional with 7% of exact exchange outperforms both GGA and GGA +U density functionals, signaling the importance of nonlocal screened-exchange interactions in BaNiS2, and, more generally, in 3 d compensated semimetals.

Numerical study of groundwater flow cycling controlled by seawater/freshwater interaction in a coastal karst aquifer through conduit network using CFPv2.

PubMed

Xu, Zexuan; Hu, Bill X; Davis, Hal; Kish, Stephen

2015-11-01

In this study, a groundwater flow cycling in a karst springshed and an interaction between two springs, Spring Creek Springs and Wakulla Springs, through a subground conduit network are numerically simulated using CFPv2, the latest research version of MODFLOW-CFP (Conduit Flow Process). The Spring Creek Springs and Wakulla Springs, located in a marine estuary and 11 miles inland, respectively, are two major groundwater discharge spots in the Woodville Karst Plain (WKP), North Florida, USA. A three-phase conceptual model of groundwater flow cycling between the two springs and surface water recharge from a major surface creek (Lost Creek) was proposed in various rainfall conditions. A high permeable subground karst conduit network connecting the two springs was found by tracer tests and cave diving. Flow rate of discharge, salinity, sea level and tide height at Spring Creek Springs could significantly affect groundwater discharge and water stage at Wakulla Springs simultaneously. Based on the conceptual model, a numerical hybrid discrete-continuum groundwater flow model is developed using CFPv2 and calibrated by field measurements. Non-laminar flows in conduits and flow exchange between conduits and porous medium are implemented in the hybrid coupling numerical model. Time-variable salinity and equivalent freshwater head boundary conditions at the submarine spring as well as changing recharges have significant impacts on seawater/freshwater interaction and springs' discharges. The developed numerical model is used to simulate the dynamic hydrological process and quantitatively represent the three-phase conceptual model from June 2007 to June 2010. Simulated results of two springs' discharges match reasonably well to measurements with correlation coefficients 0.891 and 0.866 at Spring Creeks Springs and Wakulla Springs, respectively. The impacts of sea level rise on regional groundwater flow field and relationship between the inland springs and submarine springs are

Source, variability, and transformation of nitrate in a regional karst aquifer: Edwards aquifer, central Texas.

USGS Publications Warehouse

Musgrove, MaryLynn; Opsahl, Stephen P.; Mahler, Barbara J.; Herrington, Chris; Sample, Thomas; Banta, John

2016-01-01

Many karst regions are undergoing rapid population growth and expansion of urban land accompanied by increases in wastewater generation and changing patterns of nitrate (NO3−) loading to surface and groundwater. We investigate variability and sources of NO3− in a regional karst aquifer system, the Edwards aquifer of central Texas. Samples from streams recharging the aquifer, groundwater wells, and springs were collected during 2008–12 from the Barton Springs and San Antonio segments of the Edwards aquifer and analyzed for nitrogen (N) species concentrations and NO3− stable isotopes (δ15N and δ18O). These data were augmented by historical data collected from 1937 to 2007. NO3− concentrations and discharge data indicate that short-term variability (days to months) in groundwater NO3− concentrations in the Barton Springs segment is controlled by occurrence of individual storms and multi-annual wet-dry cycles, whereas the lack of short-term variability in groundwater in the San Antonio segment indicates the dominance of transport along regional flow paths. In both segments, longer-term increases (years to decades) in NO3− concentrations cannot be attributed to hydrologic conditions; rather, isotopic ratios and land-use change indicate that septic systems and land application of treated wastewater might be the source of increased loading of NO3−. These results highlight the vulnerability of karst aquifers to NO3− contamination from urban wastewater. An analysis of N-species loading in recharge and discharge for the Barton Springs segment during 2008–10 indicates an overall mass balance in total N, but recharge contains higher concentrations of organic N and lower concentrations of NO3−than does discharge, consistent with nitrification of organic N within the aquifer and consumption of dissolved oxygen. This study demonstrates that subaqueous nitrification of organic N in the aquifer, as opposed to in soils, might be a previously

Single event time series analysis in a binary karst catchment evaluated using a groundwater model (Lurbach system, Austria).

PubMed

Mayaud, C; Wagner, T; Benischke, R; Birk, S

2014-04-16

The Lurbach karst system (Styria, Austria) is drained by two major springs and replenished by both autogenic recharge from the karst massif itself and a sinking stream that originates in low permeable schists (allogenic recharge). Detailed data from two events recorded during a tracer experiment in 2008 demonstrate that an overflow from one of the sub-catchments to the other is activated if the discharge of the main spring exceeds a certain threshold. Time series analysis (autocorrelation and cross-correlation) was applied to examine to what extent the various available methods support the identification of the transient inter-catchment flow observed in this binary karst system. As inter-catchment flow is found to be intermittent, the evaluation was focused on single events. In order to support the interpretation of the results from the time series analysis a simplified groundwater flow model was built using MODFLOW. The groundwater model is based on the current conceptual understanding of the karst system and represents a synthetic karst aquifer for which the same methods were applied. Using the wetting capability package of MODFLOW, the model simulated an overflow similar to what has been observed during the tracer experiment. Various intensities of allogenic recharge were employed to generate synthetic discharge data for the time series analysis. In addition, geometric and hydraulic properties of the karst system were varied in several model scenarios. This approach helps to identify effects of allogenic recharge and aquifer properties in the results from the time series analysis. Comparing the results from the time series analysis of the observed data with those of the synthetic data a good agreement was found. For instance, the cross-correlograms show similar patterns with respect to time lags and maximum cross-correlation coefficients if appropriate hydraulic parameters are assigned to the groundwater model. The comparable behaviors of the real and the

Single event time series analysis in a binary karst catchment evaluated using a groundwater model (Lurbach system, Austria)

PubMed Central

Mayaud, C.; Wagner, T.; Benischke, R.; Birk, S.

2014-01-01

Summary The Lurbach karst system (Styria, Austria) is drained by two major springs and replenished by both autogenic recharge from the karst massif itself and a sinking stream that originates in low permeable schists (allogenic recharge). Detailed data from two events recorded during a tracer experiment in 2008 demonstrate that an overflow from one of the sub-catchments to the other is activated if the discharge of the main spring exceeds a certain threshold. Time series analysis (autocorrelation and cross-correlation) was applied to examine to what extent the various available methods support the identification of the transient inter-catchment flow observed in this binary karst system. As inter-catchment flow is found to be intermittent, the evaluation was focused on single events. In order to support the interpretation of the results from the time series analysis a simplified groundwater flow model was built using MODFLOW. The groundwater model is based on the current conceptual understanding of the karst system and represents a synthetic karst aquifer for which the same methods were applied. Using the wetting capability package of MODFLOW, the model simulated an overflow similar to what has been observed during the tracer experiment. Various intensities of allogenic recharge were employed to generate synthetic discharge data for the time series analysis. In addition, geometric and hydraulic properties of the karst system were varied in several model scenarios. This approach helps to identify effects of allogenic recharge and aquifer properties in the results from the time series analysis. Comparing the results from the time series analysis of the observed data with those of the synthetic data a good agreement was found. For instance, the cross-correlograms show similar patterns with respect to time lags and maximum cross-correlation coefficients if appropriate hydraulic parameters are assigned to the groundwater model. The comparable behaviors of the real and

Spring hydrograph simulation of karstic aquifers: Impacts of variable recharge area, intermediate storage and memory effects

NASA Astrophysics Data System (ADS)

Hosseini, Seiyed Mossa; Ataie-Ashtiani, Behzad; Simmons, Craig T.

2017-09-01

A simple conceptual rainfall-runoff model is proposed for the estimation of groundwater balance components in complex karst aquifers. In the proposed model the effects of memory length of different karst flow systems of base-flow, intermediate-flow, and quick-flow and also time variation of recharge area (RA) during a hydrological year were investigated. The model consists of three sub-models: soil moisture balance (SMB), epikarst balance (EPB), and groundwater balance (GWB) to simulate the daily spring discharge. The SMB and EPB sub-models utilize the mass conservation equation to compute the variation of moisture storages in the soil cover and epikarst, respectively. The GWB sub-model computes the spring discharge hydrograph through three parallel linear reservoirs for base-flow, intermediate-flow, and quick-flow. Three antecedent recharge indices are defined and embedded in the model structure to deal with the memory effect of three karst flow systems to antecedent recharge flow. The Sasan Karst aquifer located in the semi-arid region of south-west Iran with a continuous long-term (21-years) daily meteorological and discharge data are considered to describe model calibration and validation procedures. The effects of temporal variations of RA of karst formations during the hydrological year namely invariant RA, two RA (winter and summer), four RA (seasonal), and twelve RA (monthly) are assessed to determine their impact on the model efficiency. Results indicated that the proposed model with monthly-variant RA is able to reproduce acceptable simulation results based on modified Kling-Gupta efficiency (KGE = -0.83). The results of density-based global sensitivity analysis for dry (June to September) and a wet (October to May) period reveal the dominant influence of RA (with sensitivity indices equal to 0.89 and 0.93, respectively) in spring discharge simulation. The sensitivity of simulated spring discharge to memory effect of different karst formations during the

A Compilation of Provisional Karst Geospatial Data for the Interior Low Plateaus Physiographic Region, Central United States

USGS Publications Warehouse

Taylor, Charles J.; Nelson, Hugh L.

2008-01-01

Geospatial data needed to visualize and evaluate the hydrogeologic framework and distribution of karst features in the Interior Low Plateaus physiographic region of the central United States were compiled during 2004-2007 as part of the Ground-Water Resources Program Karst Hydrology Initiative (KHI) project. Because of the potential usefulness to environmental and water-resources regulators, private consultants, academic researchers, and others, the geospatial data files created during the KHI project are being made available to the public as a provisional regional karst dataset. To enhance accessibility and visualization, the geospatial data files have been compiled as ESRI ArcReader data folders and user interactive Published Map Files (.pmf files), all of which are catalogued by the boundaries of surface watersheds using U.S. Geological Survey (USGS) eight-digit hydrologic unit codes (HUC-8s). Specific karst features included in the dataset include mapped sinkhole locations, sinking (or disappearing) streams, internally drained catchments, karst springs inventoried in the USGS National Water Information System (NWIS) database, relic stream valleys, and karst flow paths obtained from results of previously reported water-tracer tests.

Using MODFLOW drains to simulate groundwater flow in a karst environment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Quinn, J.; Tomasko, D.; Glennon, M.A.

1998-07-01

Modeling groundwater flow in a karst environment is both numerically challenging and highly uncertain because of potentially complex flowpaths and a lack of site-specific information. This study presents the results of MODFLOW numerical modeling in which drain cells in a finite-difference model are used as analogs for preferential flowpaths or conduits in karst environments. In this study, conduits in mixed-flow systems are simulated by assigning connected pathways of drain cells from the locations of tracer releases, sinkholes, or other karst features to outlet springs along inferred flowpaths. These paths are determined by the locations of losing stream segments, ephemeral streammore » beds, geophysical surveys, fracture lineaments, or other surficial characteristics, combined with the results of dye traces. The elevations of the drains at the discharge ends of the inferred flowpaths are estimated from field data and are adjusted when necessary during model calibration. To simulate flow in a free-flowing conduit, a high conductance is assigned to each drain to eliminate the need for drain-specific information that would be very difficult to obtain. Calculations were performed for a site near Hohenfels, Germany. The potentiometric surface produced by the simulations agreed well with field data. The head contours in the vicinity of the karst features behaved in a manner consistent with a flow system having both diffuse and conduit components, and the sum of the volumetric flow out of the drain cells agreed closely with spring discharges and stream flows. Because of the success of this approach, it is recommended for regional studies in which little site-specific information (e.g., location, number, size, and conductivity of fractures and conduits) is available, and general flow characteristics are desired.« less

Biodegradation of chlorinated ethenes at a karst site in middle Tennessee

USGS Publications Warehouse

Byl, Thomas Duane; Williams, Shannon D.

2000-01-01

This report presents results of field and laboratory investigations examining the biodegradation of chlorinated ethenes in a karst aquifer contaminated with trichloroethylene (TCE). The study site, located in Middle Tennessee, was selected because of the presence of TCE degradation byproducts in the karst aquifer and available site hydrologic and chlorinated-ethene information. Additional chemical, biological, and hydrologic data were gathered to evaluate whether the occurrence of TCE degradation byproducts in the karst aquifer was the result of biodegradation within the aquifer or simply transport into the aquifer. Geochemical analysis established that sulfate-reducing conditions, essential for reductive dechlorination of chlorinated solvents, existed in parts of the contaminated karst aquifer. Other areas of the aquifer fluctuated between anaerobic and aerobic conditions and contained compounds associated with cometabolism, such as ethane, methane, ammonia, and dissolved oxygen. A large, diverse bacteria population inhabits the contaminated aquifer. Bacteria known to biodegrade TCE and other chlorinated solvents, such as sulfate-reducers, methanotrophs, and ammonia-oxidizers, were identified from karst-aquifer water using the RNA-hybridization technique. Results from microcosms using raw karst-aquifer water found that aerobic cometabolism and anaerobic reductive-dechlorination degradation processes were possible when appropriate conditions were established in the microcosms. These chemical and biological results provide circumstantial evidence that several biodegradation processes are active in the aquifer. Additional site hydrologic information was developed to determine if appropriate conditions persist long enough in the karst aquifer for these biodegradation processes to be significant. Continuous monitoring devices placed in four wells during the spring of 1998 indicated that pH, specific conductance, dissolved oxygen, and oxidation-reduction potentials

Agriculture and Karst in Kentucky

USDA-ARS?s Scientific Manuscript database

This publication describes the unique hydrologic and environmental issues found in karst environments. The publication describes karst landscapes, the importance of karst, different types of karst features, and how water moves through karst landscapes. The publication includes details on methods for...

Karst aquifer characterization using geophysical remote sensing of dynamic recharge events

NASA Astrophysics Data System (ADS)

Grapenthin, R.; Bilek, S. L.; Luhmann, A. J.

2017-12-01

Geophysical monitoring techniques, long used to make significant advances in a wide range of deeper Earth science disciplines, are now being employed to track surficial processes such as landslide, glacier, and river flow. Karst aquifers are another important hydrologic resource that can benefit from geophysical remote sensing, as this monitoring allows for safe, noninvasive karst conduit measurements. Conduit networks are typically poorly constrained, let alone the processes that occur within them. Geophysical monitoring can also provide a regionally integrated analysis to characterize subsurface architecture and to understand the dynamics of flow and recharge processes in karst aquifers. Geophysical signals are likely produced by several processes during recharge events in karst aquifers. For example, pressure pulses occur when water enters conduits that are full of water, and experiments suggest seismic signals result from this process. Furthermore, increasing water pressure in conduits during recharge events increases the load applied to conduit walls, which deforms the surrounding rock to yield measureable surface displacements. Measureable deformation should also occur with mass loading, with subsidence and rebound signals associated with increases and decreases of water mass stored in the aquifer, respectively. Additionally, geophysical signals will likely arise with turbulent flow and pore pressure change in the rock surrounding conduits. Here we present seismic data collected during a pilot study of controlled and natural recharge events in a karst aquifer system near Bear Spring, near Eyota, MN, USA as well as preliminary model results regarding the processes described above. In addition, we will discuss an upcoming field campaign where we will use seismometers, tiltmeters, and GPS instruments to monitor for recharge-induced responses in a FL, USA karst system with existing cave maps, coupling these geophysical observations with hydrologic and

Water resources management in karst aquifers - concepts and modeling approaches

NASA Astrophysics Data System (ADS)

Sauter, M.; Schmidt, S.; Abusaada, M.; Reimann, T.; Liedl, R.; Kordilla, J.; Geyer, T.

2011-12-01

Water resources management schemes generally imply the availability of a spectrum of various sources of water with a variability of quantity and quality in space and time, and the availability and suitability of storage facilities to cover various demands of water consumers on quantity and quality. Aquifers are generally regarded as suitable reservoirs since large volumes of water can be stored in the subsurface, water is protected from contamination and evaporation and the underground passage assists in the removal of at least some groundwater contaminants. Favorable aquifer properties include high vertical hydraulic conductivities for infiltration, large storage coefficients and not too large hydraulic gradients / conductivities. The latter factors determine the degree of discharge, i.e. loss of groundwater. Considering the above criteria, fractured and karstified aquifers appear to not really fulfill the respective conditions for storage reservoirs. Although infiltration capacity is relatively high, due to low storativity and high hydraulic conductivities, the small quantity of water stored is rapidly discharged. However, for a number of specific conditions, even karst aquifers are suitable for groundwater management schemes. They can be subdivided into active and passive management strategies. Active management options include strategies such as overpumping, i.e. the depletion of the karst water resources below the spring outflow level, the construction of subsurface dams to prevent rapid discharge. Passive management options include the optimal use of the discharging groundwater under natural discharge conditions. System models that include the superposition of the effect of the different compartments soil zone, epikarst, vadose and phreatic zone assist in the optimal usage of the available groundwater resources, while taking into account the different water reservoirs. The elaboration and implementation of groundwater protection schemes employing well

Artificial sweeteners: Sucralose and Acesulfame-K; emerging pollutants indicators of specific transport in karst systems: Application to semi-arid regions.

NASA Astrophysics Data System (ADS)

Doummar, J.; Aoun, M. E.

2016-12-01

The assessment of vulnerability in karst system is highly challenging as it highly depends on the identification of diffuse and concentrated infiltration from surface karst features, the latter varying with time. This work shows that the artificial sweeteners Sucralose (SUC) and Acesulfame-K (ACE-K) can be used as transport indicators for persistent waste water effluent in karst systems. In the framework of a PEER NSF/USAID funded project, a karst spring (Qachqouch; yearly discharge of circa 50 Mm3) in Mount Lebanon was monitored following a multi-precipitation event. Acesulfame-K (ACE-K) and Sucralose (SUC), indicative of domestic waste water, Chloride and Calcium ions, Electrical conductivity (EC), and turbidity along with discharge were collected at the spring for nine days after the rain events at time intervals varying between 30 min and 4 hours. The samples were analyzed for ACE-K and SUC at Eaton Eurofins in California. A first sampling campaign was undertaken to assess the base flow concentrations in wells, waste water, and the main losing river on the catchment area along with Spring Qachqouch. It revealed that ACE-K and SUC are found in the spring at base flow concentrations of 170 ng/l, and 120 ng/l respectively. A two-end mixing model based on Chloride and Calcium allowed the quantification of newly recharged water (11% of total flow) reaching the springs at specific monitoring intervals through fast flow pathways. The results revealed that the artificial sweeteners are persistent in the system outside rain events. They are mostly transported to the springs through fast pathways from flushed wastewater; their breakthrough curves coincide with the arrival of new waters (from the sinking stream or sinkholes). About 120 grams of SUC and 160 grams of ACE-K reached the springs during peak response in three consecutive events. Based on the quantities, and given that both acesulfame and SUC are excreted mostly unchanged in wastewater, estimates of consumption

Evolution of structure and superconductivity in Ba(Ni 1 -xCox)2As2

NASA Astrophysics Data System (ADS)

Eckberg, Chris; Wang, Limin; Hodovanets, Halyna; Kim, Hyunsoo; Campbell, Daniel J.; Zavalij, Peter; Piccoli, Philip; Paglione, Johnpierre

2018-06-01

The effects of Co substitution on Ba (Ni1-xCox) 2As2 (0 ≤x ≤0.251 ) single crystals grown out of Pb flux are investigated via transport, magnetic, and thermodynamic measurements. BaNi2As2 exhibits a first-order tetragonal to triclinic structural phase transition at Ts=137 K upon cooling, and enters a superconducting phase below Tc=0.7 K. The structural phase transition is sensitive to cobalt content and is suppressed completely by x ≥0.133 . The superconducting critical temperature, Tc, increases continuously with x , reaching a maximum of Tc=2.3 K at x =0.083 and then decreases monotonically until superconductivity is no longer observable well into the tetragonal phase. In contrast to similar BaNi2As2 substitutional studies, which show an abrupt change in Tc at the triclinic-tetragonal boundary that extends far into the tetragonal phase, Ba (Ni1-xCox) 2As2 exhibits a domelike phase diagram centered around the zero-temperature tetragonal-triclinic boundary. Together with an anomalously large heat capacity jump Δ Ce/γ T ˜2.2 near optimal doping, the smooth evolution of Tc in the Ba (Ni1-xCox) 2As2 system suggests a mechanism for pairing enhancement other than phonon softening.

Transport of environmental tracers through a karst system with a thick unsaturated zone

NASA Astrophysics Data System (ADS)

Geyer, Tobias; Sültenfuss, Jürgen; Eichinger, Florian; Sauter, Martin

2010-05-01

The transport of the environmental tracers tritium (3H), krypton-85 (85Kr) and helium (3He) in a karst system is investigated. Differences between mean tracer ages determined in spring water are explained by slow percolation of water through the thick unsaturated zone reflecting the importance of slow and diffuse unsaturated flow processes in these systems. Mean tracer ages on the Gallusquelle spring (Swabian Alb) were determined with lumped parameter modeling and decrease in the following order: 3H >> 85Kr > 3He. Since 3H is part of the water molecule it enters a karst system via precipitation, i.e. the mean 3H age is a measure of water flow through the whole karst system, including the unsaturated and saturated zone. The mean 85Kr age and 3H/3He age are measures of time since groundwater recharge arrived at the water table. Therefore our results indicate a long travel time of 3H through the unsaturated zone of the karst system. The interpretation is supported by a two-dimensional numerical simulation of flow and transport in a fissured matrix block that contains a thick unsaturated zone (ca. 100 m) and is drained by a conduit. Transport simulation is performed in the sense of backtracking, i.e. the flow field is reversed, and the boundary conditions are adapted accordingly. At any position in the model domain, the time required for a water molecule to reach the outlet is estimated corresponding to the "life expectancy" (Cornaton and Perrochet 2006), i.e. the life expectancy on the outlet is zero. The simulation of life expectancy of water in the matrix block shows (1) the importance of heterogeneities for interpretation of groundwater ages, (2) the location of stagnant zones in areas of low hydraulic permeability and/or low hydraulic gradient and (3) that flow through unsaturated fissured matrix blocks may cause a considerable travel time of water through a karst system. The travel time of water from the recharge area to the discharge point for the shown example

Comparing and refining karst disturbance index methods through application in an island karst setting

NASA Astrophysics Data System (ADS)

Porter, Brandon L.; North, Leslie A.; Polk, Jason S.

2016-12-01

The interconnected nature of surface and subsurface karst environments allows easy disturbance to their aquifers and specialized ecosystems from anthropogenic impacts. The karst disturbance index is a holistic tool used to measure disturbance to karst environments and has been applied and refined through studies in Florida and Italy, among others. Through these applications, the karst disturbance index has evolved into two commonly used methods of application; yet, the karst disturbance index is still susceptible to evaluation and modification for application in other areas around the world. The geographically isolated and highly vulnerable municipality of Arecibo, Puerto Rico's karst area provides an opportunity to test the usefulness and validity of the karst disturbance index in an island setting and to compare and further refine the application of the original and modified methods. This study found the both methods of karst disturbance index application resulted in high disturbance scores (Original Method 0.54 and Modified Method 0.69, respectively) and uncovered multiple considerations for the improvement of the karst disturbance index. An evaluation of multiple methods together in an island setting also resulted in the need for adding additional indicators, including Mogote Removal and Coastal Karst. Collectively, the results provide a holistic approach to using the karst disturbance index in an island karst setting and suggest a modified method by which scaling and weighting may compensate for the difference between the original and modified method scores and allow interested stakeholders to evaluate disturbance regardless of his or her level of expertise.

A quantitative comparison of moldic and vuggy porosity structure in karst aquifers using image and geospatial analysis

NASA Astrophysics Data System (ADS)

Culpepper, A. R.; Manda, A. K.

2011-12-01

Limestone aquifers are vital sources of groundwater for domestic and industrial use throughout the world. To sustain rising population throughout the southeastern United States, aquifers are increasingly exploited to provide the populace clean and reliable water resources. The moldic Castle Hayne and the vuggy Biscayne aquifer systems are two highly productive aquifers that provide critical water resources to millions of citizens in eastern North Carolina and southeastern Florida, respectively. In order to better understand karst aquifers and evaluate the potential for contaminant transport, detailed investigation of 2D porosity and pore geometry using image and geospatial analysis were undertaken. The objective of this study is to compare and contrast the porosity structure of moldic and vuggy karst aquifers by quantifying 2D porosity and pore geometry from images of slabbed core samples and optical televiewer images. Televiewer images and images of painted core samples from the Spring Garden Member of the Castle Hayne aquifer and Miami Limestone Formation of the Biscayne aquifer were acquired for analysis of porosity structure. The procedure for converting images of slabbed core and televiewer images to a GIS useable format consisted of rectification, calibration, image enhancement, classification, recoding and filtering. In GIS, raster or vector formats were used to assess pore attributes (e.g., area and perimeter) and structure. Preliminary results show that both pore area and perimeter for the Spring Garden Member of the Castle Hayne and Miami Limestone Formation of the Biscayne aquifers can be described by exponential distributions. In both sets of slabbed core images the relatively small pores have the highest occurrence, whereas larger pores occur less frequently. However, the moldic Spring Garden Member of the Castle Hayne aquifer has larger pore sizes derived from cores images than the vuggy Miami Limestone Formation of Biscayne aquifer. Total porosity

Online analysis: Deeper insights into water quality dynamics in spring water.

PubMed

Page, Rebecca M; Besmer, Michael D; Epting, Jannis; Sigrist, Jürg A; Hammes, Frederik; Huggenberger, Peter

2017-12-01

We have studied the dynamics of water quality in three karst springs taking advantage of new technological developments that enable high-resolution measurements of bacterial load (total cell concentration: TCC) as well as online measurements of abiotic parameters. We developed a novel data analysis approach, using self-organizing maps and non-linear projection methods, to approximate the TCC dynamics using the multivariate data sets of abiotic parameter time-series, thus providing a method that could be implemented in an online water quality management system for water suppliers. The (TCC) data, obtained over several months, provided a good basis to study the microbiological dynamics in detail. Alongside the TCC measurements, online abiotic parameter time-series, including spring discharge, turbidity, spectral absorption coefficient at 254nm (SAC254) and electrical conductivity, were obtained. High-density sampling over an extended period of time, i.e. every 45min for 3months, allowed a detailed analysis of the dynamics in karst spring water quality. Substantial increases in both the TCC and the abiotic parameters followed precipitation events in the catchment area. Differences between the parameter fluctuations were only apparent when analyzed at a high temporal scale. Spring discharge was always the first to react to precipitation events in the catchment area. Lag times between the onset of precipitation and a change in discharge varied between 0.2 and 6.7h, depending on the spring and event. TCC mostly reacted second or approximately concurrent with turbidity and SAC254, whereby the fastest observed reaction in the TCC time series occurred after 2.3h. The methodological approach described here enables a better understanding of bacterial dynamics in karst springs, which can be used to estimate risks and management options to avoid contamination of the drinking water. Copyright © 2017 Elsevier B.V. All rights reserved.

Thermographic Data Analyses for Karst Watersheds

NASA Technical Reports Server (NTRS)

Campbell, C. Warren; McCaleb, Rebecca C. (Technical Monitor)

2001-01-01

Aerial thermography is an emerging technology unsurpassed for locating groundwater discharges. Thermography can be used to locate submerged discharges that are extremely difficult to find by other means. In two large projects, thermography was used to identify almost every significant spring at sites underlain by karst aquifers. This technology effectively converts Brown's Type 5 topology to types 1 or 2 (all discharges known), which has a significant impact on dye tracing. At a north Alabama site, springs located by thermography quadrupled the known groundwater discharge in and around the site. For submerged discharges, thermographic temperatures can be measured down the center of the groundwater plume that rises to the surface in the winter. Using the Cornell Mixing (CORMIX) model, flow rate for one submerged spring was estimated. Once identified, estimates of spring recharge area were desired. The size of the area of recharge was estimated by hydrograph separation of flow data from nearby, unregulated surface streams. Monthly recharge estimates were also made and used to show that in north Alabama the mean annual recharge/discharge occurs during May and December. Spring flow measurements for the same county of north Alabama were averaged to obtain mean flows. Then measurements for May only, were averaged. The two averages usually agreed to within 20 percent. This provides evidence that hydrograph separation determinations of recharge are valid.

Regional scale hydrologic modeling of a karst-dominant geomorphology: The case study of the Island of Crete

NASA Astrophysics Data System (ADS)

Malagò, Anna; Efstathiou, Dionissios; Bouraoui, Fayçal; Nikolaidis, Nikolaos P.; Franchini, Marco; Bidoglio, Giovanni; Kritsotakis, Marinos

2016-09-01

Crete Island (Greece) is a karst dominated region that faces limited water supply and increased seasonal demand, especially during summer for agricultural and touristic uses. In addition, due to the mountainous terrain, interbasin water transfer is very limited. The resulting water imbalance requires a correct quantification of available water resources in view of developing appropriate management plans to face the problem of water shortage. The aim of this work is the development of a methodology using the SWAT model and a karst-flow model (KSWAT, Karst SWAT model) for the quantification of a spatially and temporally explicit hydrologic water balance of karst-dominated geomorphology in order to assess the sustainability of the actual water use. The application was conducted in the Island of Crete using both hard (long time series of streamflow and spring monitoring stations) and soft data (i.e. literature information of individual processes). The KSWAT model estimated the water balance under normal hydrological condition as follows: 6400 Mm3/y of precipitation, of which 40% (2500 Mm3/y) was lost through evapotranspiration, 5% was surface runoff and 55% percolated into the soil contributing to lateral flow (2%), and recharging the shallow (9%) and deep aquifer (44%). The water yield was estimated as 22% of precipitation, of which about half was the contribution from spring discharges (9% of precipitation). The application of the KSWAT model increased our knowledge about water resources availability and distribution in Crete under different hydrologic conditions. The model was able to capture the hydrology of the karst areas allowing a better management and planning of water resources under scarcity.

Recent Trends in Karst Geomorphology.

ERIC Educational Resources Information Center

Palmer, Arthur N.

1984-01-01

Recent trends related to the karst processes and the evolution of karst landscapes are discussed. The hydrochemical processes responsible for the origin of karst are expanded on to illustrate the present scope of karst studies. These geomorphological studies are combined with concepts and techniques from hydraulics, chemistry, and mathematics. (JN)

Solute transport characterization in karst aquifers by tracer injection tests for a sustainable water resource management

NASA Astrophysics Data System (ADS)

Morales, T.; Angulo, B.; Uriarte, J. A.; Olazar, M.; Arandes, J. M.; Antiguedad, I.

2017-04-01

Protection of water resources is a major challenge today, given that territory occupation and land use are continuously increasing. In the case of karst aquifers, its dynamic complexity requires the use of specific methodologies that allow establishing local and regional flow and transport patterns. This information is particularly necessary when springs and wells harnessed for water supply are concerned. In view of the present state of the art, this work shows a new approach based on the use of a LiCl based tracer injection test through a borehole for transport characterization from a local to a regional scale. Thus a long term tracer injection test was conducted in a particularly sensitive sector of the Egino karst massif (Basque Country, Spain). The initial displacement of tracer in the vicinity of the injection was monitored in a second borehole at a radial distance of 10.24 m. This first information, assessed by a radial divergent model, allows obtaining transport characteristic parameters in this immediate vicinity during injection. At a larger (regional) scale, the tracer reaches a highly transmissive network with mean traveling velocities to the main springs being from 4.3 to 13.7 m/h. The responses obtained, particularly clear in the main spring used for water supply, and the persistence of part of the tracer in the injection zone, pose reconsidering the need for their protection. Thus, although the test allows establishing the 24-h isochrone, which is the ceiling value in present European vulnerability approaches, the results obtained advise widening the zone to protect in order to guarantee water quality in the springs. Overall, this stimulus-response test allows furthering the knowledge on the dynamics of solute transport in karst aquifers and is a particularly useful tool in studies related to source vulnerability and protection in such a complex medium.

How does the anthropogenic activity affect the spring discharge?

NASA Astrophysics Data System (ADS)

Hao, Yonghong; Zhang, Juan; Wang, Jiaojiao; Li, Ruifang; Hao, Pengmei; Zhan, Hongbin

2016-09-01

Karst hydrological process has largely been altered by climate change and human activity. In many places throughout the world, human activity (e.g. groundwater pumping and dewatering from mining) has intensified and surpassed climate change, where human activity becomes the primary factor that affects groundwater system. But it is still largely unclear how the human activity affects spring discharge in magnitude and periodicity. This study investigates the effects of anthropogenic activity on spring discharge, using the Xin'an Springs of China as an example. The Xin'an Spring discharge were divided into two time periods: the pre-development period from 1956 to 1971 and the post-development period from 1972 to 2013. We confirm the dividing time (i.e. 1971) of these two periods using the Wilcoxon rank-sum test. Then the wavelet transform and wavelet coherence were used to analyze the karst hydrological processes for the two periods respectively. We analyze the correlations of precipitation and the Xin'an spring discharge with the monsoons including the Indian Summer Monsoon (ISM) and the West North Pacific Monsoon (WNPM) and the climate teleconnections including El Niño Southern Oscillation (ENSO) and Pacific Decadal Oscillation (PDO), respectively. The results indicated that the spring discharge was attenuated about 19.63% under the influence of human activity in the Xin'an Springs basin. However, human activity did not alter the size of the resonance frequencies between the spring discharge and the monsoons. In contrast, it reinforced the periodicities of the monsoons-driven spring discharge. It suggested that human has adapted to the major climate periodicities, and human activity had the same rhyme with the primary climate periodicity. In return, human activity enhances the correlation between the monsoons and the spring discharge.

Occurrence and transport of pharmaceuticals in a karst groundwater system affected by domestic wastewater treatment plants.

PubMed

Einsiedl, Florian; Radke, Michael; Maloszewski, Piotr

2010-09-20

The occurrence of two pharmaceuticals, ibuprofen and diclofenac, in a vulnerable karst groundwater system was investigated. The hydrogeology of the karst system was identified by collecting (3)H samples in groundwater over 27years and by performing tracer tests. The isotopes and tracer data were interpreted by mathematical modeling to estimate the mean transit time of water and to characterize the hydrogeological flow paths in the groundwater system. By this approach, a mean (3)H transit time of 4.6 years for the fissured-porous karst aquifer was determined, whereas the fast flowing water in the conduit system showed a mean transit time of days. Both pharmaceuticals which infiltrated along sinkholes and small streams into the karst system were detected in concentrations of up to approximately 1 microg/L in effluent water of the wastewater treatment plants. Diclofenac was present in most samples collected from four springs discharging the karst groundwater to the rivers Altmühl and Anlauter in concentrations between 3.6 and 15.4 ng/L. In contrast, ibuprofen was rarely detected in groundwater. The results of this study suggest that both pharmaceuticals move into the fractured system of the karst system and go into storage. Thus dilution processes are the dominant control on the concentrations of both pharmaceuticals in the fractured system, whereas biodegradation is likely less important. Copyright (c) 2010 Elsevier B.V. All rights reserved.

U.S. Geological Survey Karst Interest Group Proceedings, San Antonio, Texas, May 16–18, 2017

USGS Publications Warehouse

Kuniansky, Eve L.; Spangler, Lawrence E.

2017-05-15

Introduction and AcknowledgmentsKarst aquifer systems are present throughout parts of the United States and some of its territories, and have developed in carbonate rocks (primarily limestone and dolomite) and evaporites (gypsum, anhydrite, and halite) that span an interval of time encompassing more than 550 million years. The depositional environments, diagenetic processes, post-depositional tectonic events, and geochemical weathering processes that form karst aquifers are varied and complex. These factors involve biological, chemical, and physical changes that when combined with the diverse climatic regimes in which karst development has taken place, result in the unique dual- or triple-porosity nature of karst aquifers. These complex hydrogeologic systems typically represent challenging and unique conditions to scientists attempting to study groundwater flow and contaminant transport in these terrains.The dissolution of carbonate rocks and the subsequent development of distinct and beautiful landscapes, caverns, and springs have resulted in the most exceptional karst areas being designated as national or state parks. Tens of thousands of similar areas in the United States have been developed into commercial caverns and known privately owned caves. Both public and private properties provide access for scientists to study the flow of groundwater in situ. Likewise, the range and complexity of landforms and groundwater flow systems associated with karst terrains are enormous, perhaps more than for any other aquifer type. Karst aquifers and landscapes that form in tropical areas, such as the cockpit karst along the north coast of Puerto Rico, differ greatly from karst landforms in more arid climates, such as the Edwards Plateau in west-central Texas or the Guadalupe Mountains near Carlsbad, New Mexico, where hypogenic processes have played a major role in speleogenesis. Many of these public and private lands also contain unique flora and fauna associated with these

Geological structure, recharge processes and underground drainage of a glacierised karst aquifer system, Tsanfleuron-Sanetsch, Swiss Alps

NASA Astrophysics Data System (ADS)

Gremaud, Vivian; Goldscheider, Nico; Savoy, Ludovic; Favre, Gérald; Masson, Henri

2009-12-01

The relationships between stratigraphic and tectonic setting, recharge processes and underground drainage of the glacierised karst aquifer system ‘Tsanfleuron-Sanetsch’ in the Swiss Alps have been studied by means of various methods, particularly tracer tests (19 injections). The area belongs to the Helvetic nappes and consists of Jurassic to Palaeogene sedimentary rocks. Strata are folded and form a regional anticlinorium. Cretaceous Urgonian limestone constitutes the main karst aquifer, overlain by a retreating glacier in its upper part. Polished limestone surfaces are exposed between the glacier front and the end moraine of 1855/1860 (Little Ice Age); typical alpine karrenfields can be observed further below. Results show that (1) large parts of the area are drained by the Glarey spring, which is used as a drinking water source, while marginal parts belong to the catchments of other springs; (2) groundwater flow towards the Glarey spring occurs in the main aquifer, parallel to stratification, while flow towards another spring crosses the entire stratigraphic sequence, consisting of about 800 m of marl and limestone, along deep faults that were probably enlarged by mass movements; (3) the variability of glacial meltwater production influences the shape of the tracer breakthrough curves and, consequently, flow and transport in the aquifer.

Spheres of discharge of springs

NASA Astrophysics Data System (ADS)

Springer, Abraham E.; Stevens, Lawrence E.

2009-02-01

Although springs have been recognized as important, rare, and globally threatened ecosystems, there is as yet no consistent and comprehensive classification system or common lexicon for springs. In this paper, 12 spheres of discharge of springs are defined, sketched, displayed with photographs, and described relative to their hydrogeology of occurrence, and the microhabitats and ecosystems they support. A few of the spheres of discharge have been previously recognized and used by hydrogeologists for over 80 years, but others have only recently been defined geomorphologically. A comparison of these spheres of discharge to classification systems for wetlands, groundwater dependent ecosystems, karst hydrogeology, running waters, and other systems is provided. With a common lexicon for springs, hydrogeologists can provide more consistent guidance for springs ecosystem conservation, management, and restoration. As additional comprehensive inventories of the physical, biological, and cultural characteristics are conducted and analyzed, it will eventually be possible to associate spheres of discharge with discrete vegetation and aquatic invertebrate assemblages, and better understand the habitat requirements of rare or unique springs species. Given the elevated productivity and biodiversity of springs, and their highly threatened status, identification of geomorphic similarities among spring types is essential for conservation of these important ecosystems.

Assessing submarine groundwater discharge (SGD) and nitrate fluxes in highly heterogeneous coastal karst aquifers: Challenges and solutions

NASA Astrophysics Data System (ADS)

Montiel, Daniel; Dimova, Natasha; Andreo, Bartolomé; Prieto, Jorge; García-Orellana, Jordi; Rodellas, Valentí

2018-02-01

Groundwater discharge in coastal karst aquifers worldwide represents a substantial part of the water budget and is a main pathway for nutrient transport to the sea. Groundwater discharge to the sea manifests under different forms, making its assessment very challenging particularly in highly heterogeneous coastal systems karst systems. In this study, we present a methodology approach to identify and quantify four forms of groundwater discharge in a mixed lithology system in southern Spain (Maro-Cerro Gordo) that includes an ecologically protected coastal area comprised of karstic marble. We found that groundwater discharge to the sea occurs via: (1) groundwater-fed creeks, (2) coastal springs, (3) diffuse groundwater seepage through seabed sediments, and (4) submarine springs. We used a multi-method approach combining tracer techniques (salinity, 224Ra, and 222Rn) and direct measurements (seepage meters and flowmeters) to evaluate the discharge. Groundwater discharge via submarine springs was the most difficult to assess due to their depth (up to 15 m) and extensive development of the springs conduits. We determined that the total groundwater discharge over the 16 km of shoreline of the study area was at least 11 ± 3 × 103 m3 d-1 for the four types of discharge assessed. Groundwater-derived nitrate (NO3-) fluxes to coastal waters over ∼3 km (or 20%) in a highly populated and farmed section of Maro-Cerro Gordo was 641 ± 166 mol d-1, or ∼75% of the total NO3- loading in the study area. We demonstrate in this study that a multi-method approach must be applied to assess all forms of SGD and derived nutrient fluxes to the sea in highly heterogeneous karst aquifer systems.

Biogeography, phylogeny, and morphological evolution of central Texas cave and spring salamanders

PubMed Central

2013-01-01

Background Subterranean faunal radiations can result in complex patterns of morphological divergence involving both convergent or parallel phenotypic evolution and cryptic species diversity. Salamanders of the genus Eurycea in central Texas provide a particularly challenging example with respect to phylogeny reconstruction, biogeography and taxonomy. These predominantly aquatic species inhabit karst limestone aquifers and spring outflows, and exhibit a wide range of morphological and genetic variation. We extensively sampled spring and cave populations of six Eurycea species within this group (eastern Blepsimolge clade), to reconstruct their phylogenetic and biogeographic history using mtDNA and examine patterns and origins of cave- and surface-associated morphological variation. Results Genetic divergence is generally low, and many populations share ancestral haplotypes and/or show evidence of introgression. This pattern likely indicates a recent radiation coupled with a complex history of intermittent connections within the aquatic karst system. Cave populations that exhibit the most extreme troglobitic morphologies show no or very low divergence from surface populations and are geographically interspersed among them, suggesting multiple instances of rapid, parallel phenotypic evolution. Morphological variation is diffuse among cave populations; this is in contrast to surface populations, which form a tight cluster in morphospace. Unexpectedly, our analyses reveal two distinct and previously unrecognized morphological groups encompassing multiple species that are not correlated with spring or cave habitat, phylogeny or geography, and may be due to developmental plasticity. Conclusions The evolutionary history of this group of spring- and cave-dwelling salamanders reflects patterns of intermittent isolation and gene flow influenced by complex hydrogeologic dynamics that are characteristic of karst regions. Shallow genetic divergences among several species

U.S. Geological Survey Karst Interest Group Proceedings, Carlsbad, New Mexico, April 29-May 2, 2014

USGS Publications Warehouse

Kuniansky, Eve L.; Spangler, Lawrence E.; Kuniansky, Eve L.; Spangler, Lawrence E.

2014-01-01

Karst aquifer systems are present throughout parts of the United States and some of its territories, and have developed in carbonate rocks (primarily limestone and dolomite) that span an interval of time encompassing more than 550 million years. The depositional environments, diagenetic processes, post-depositional tectonic events, and geochemical weathering processes that form karst aquifers are varied and complex, and involve biological, chemical, and physical changes. These factors, combined with the diverse climatic regimes under which karst development in these rocks has taken place, result in the unique dual- or triple-porosity nature of karst aquifers. These complex hydrogeologic systems typically represent challenging and unique conditions to scientists attempting to study groundwater flow and contaminant transport in these terrains.The dissolution of carbonate rocks and the subsequent development of distinct and beautiful landscapes, caverns, and springs has resulted in the most exceptional karst areas of the United States being designated as national or state parks; commercial caverns and known privately owned caves number in the tens of thousands. Both public and private properties provide access for scientists to study the flow of groundwater in situ. Likewise, the range and complexity of landforms and groundwater flow systems associated with karst terrains are enormous, perhaps more than for any other aquifer type. Karst aquifers and landscapes that form in tropical areas, such as the cockpit karst along the north coast of Puerto Rico, differ greatly from karst landforms in more arid climates, such as the Edwards Plateau in west-central Texas or the Guadalupe Mountains near Carlsbad, New Mexico, where hypogenic processes have played a major role in speleogenesis. Many of these public and private lands also contain unique flora and fauna associated with these karst hydrogeologic systems. As a result, numerous federal, state, and local agencies have a

Review: Groundwater flow and transport modeling of karst aquifers, with particular reference to the North Coast Limestone aquifer system of Puerto Rico

PubMed Central

Ghasemizadeh, Reza; Hellweger, Ferdinand; Butscher, Christoph; Padilla, Ingrid; Vesper, Dorothy; Field, Malcolm; Alshawabkeh, Akram

2013-01-01

Karst systems have a high degree of heterogeneity and anisotropy, which makes them behave very differently from other aquifers. Slow seepage through the rock matrix and fast flow through conduits and fractures result in a high variation in spring response to precipitation events. Contaminant storage occurs in the rock matrix and epikarst, but contaminant transport occurs mostly along preferential pathways that are typically inaccessible locations, which makes modeling of karst systems challenging. Computer models for understanding and predicting hydraulics and contaminant transport in aquifers make assumptions about the distribution and hydraulic properties of geologic features that may not always apply to karst aquifers. This paper reviews the basic concepts, mathematical descriptions, and modeling approaches for karst systems. The North Coast Limestone aquifer system of Puerto Rico (USA) is introduced as a case study to illustrate and discuss the application of groundwater models in karst aquifer systems to evaluate aquifer contamination. PMID:23645996

Karst Groundwater Hydrologic Analyses Based on Aerial Thermography

NASA Technical Reports Server (NTRS)

Campbell, C. Warren; Keith, A. G.

2000-01-01

On February 23, 1999, thermal imagery of Marshall Space Flight Center, Alabama was collected using an airborne thermal camera. Ground resolution was I in. Approximately 40 km 2 of thermal imagery in and around Marshall Space Flight Center (MSFC) was analyzed to determine the location of springs for groundwater monitoring. Subsequently, forty-five springs were located ranging in flow from a few ml/sec to approximately 280 liter/sec. Groundwater temperatures are usually near the mean annual surface air temperature. On thermography collected during the winter, springs show up as very warm spots. Many of the new springs were submerged in lakes, streams, or swamps; consequently, flow measurements were difficult. Without estimates of discharge, the impacts of contaminated discharge on surface streams would be difficult to evaluate. An approach to obtaining an estimate was developed using the Environmental Protection Agency (EPA) Cornell Mixing Zone Expert System (CORMIX). The thermography was queried to obtain a temperature profile down the center of the surface plume. The spring discharge was modeled with CORMIX, and the flow adjusted until the surface temperature profile was matched. The presence of volatile compounds in some of the new springs also allowed MSFC to unravel the natural system of solution cavities of the karst aquifer. Sampling results also showed that two springs on either side of a large creek had the same water source so that groundwater was able to pass beneath the creek.

Karst map of Puerto Rico

USGS Publications Warehouse

Alemán González, Wilma B.

2010-01-01

This map is a digital compilation, combining the mapping of earlier geologists. Their work, cited on the map, contains more detailed descriptions of karst areas and landforms in Puerto Rico. This map is the basis for the Puerto Rico part of a new national karst map currently being compiled by the U.S. Geological Survey. In addition, this product is a standalone, citable source of digital karst data for Puerto Rico. Nearly 25 percent of the United States is underlain by karst terrain, and a large part of that area is undergoing urban and industrial development. Accurate delineations of karstic rocks are needed at scales suitable for national, State, and local maps. The data on this map contribute to a better understanding of subsidence hazards, groundwater contamination potential, and cave resources as well as serve as a guide to topical research on karst. Because the karst data were digitized from maps having a different scale and projection from those on the base map used for this publication, some karst features may not coincide perfectly with physiographic features portrayed on the base map.

How important is exact knowledge of preferential flowpath locations and orientations for understanding spatiotemporally integrated spring hydrologic and transport response?

NASA Astrophysics Data System (ADS)

Henson, W.; De Rooij, R.; Graham, W. D.

2016-12-01

The Upper Floridian Aquifer is hydrogeologically complex; limestone dissolution has led to vertical and horizontal preferential flow paths. Locations of karst conduits are unknown and conduit properties are poorly constrained. Uncertainty in effects of conduit location, size, and density, network geometry and connectivity on hydrologic and transport responses is not well quantified, leading to limited use of discrete-continuum models that incorporate conduit networks for regional-scale hydrologic regulatory models. However, conduit networks typically dominate flow and contaminant transport in karst aquifers. We evaluated sensitivity of simulated water and nitrate fluxes and flow paths to karst conduit geometry in a springshed representative of Silver Springs, Florida, using a novel calcite dissolution conduit-generation algorithm coupled with a discrete-continuum flow and transport model (DisCo). Monte Carlo simulations of conduit generation, groundwater flow, and conservative solute transport indicate that, if a first magnitude spring system conduit network developed (i.e., spring flow >2.8 m3/s), the uncertainty in hydraulic and solute pulse response metrics at the spring vent was minimally related to locational uncertainty of network elements. Across the ensemble of realizations for various distributions of conduits, first magnitude spring hydraulic pulse metrics (e.g., steady-flow, peak flow, and recession coefficients) had < 0.01 coefficient of variation (CV). Similarly, spring solute breakthrough curve moments had low CV (<0.08); peak arrival had CV=0.06, mean travel time had CV=0.05, and travel time standard deviation had CV=0.08. Nevertheless, hydraulic and solute pulse response metrics were significantly different than those predicted by an equivalent porous-media model. These findings indicate that regional-scale decision models that incorporate karst preferential flow paths within an uncertainty framework can be used to better constrain aquifer

Geologic and anthropogenic factors influencing karst development in the Frederick region of Maryland

USGS Publications Warehouse

Brezinski, D.K.

2007-01-01

Karst features pervade the outcrop belts of Triassic, Ordovician, and Cambrian rocks in the Frederick Valley region of Maryland's western Piedmont. Detailed stratigraphic analysis and geologic and karst mapping demonstrate that individual stratigraphic units have differing susceptibilities of karst feature creation. Although the Triassic Leesburg Member of the Bull Run Formation and Rocky Springs Station Member of the Cambrian Frederick Formation have many surface depressions within their outcrop belts, the Lime Kiln Member of the Frederick Formation and the Ceresville, Fountain Rock, and Woodsboro members of the Ordovician Grove Formation have the greatest potential for development of catastrophic collapse sinkholes. Although these four members have the highest relative susceptibility, human activity can increase the potential for sinkhole activation in all units. Rerouting of surface drainage patterns, unlined drainage, and storm-water management areas and removal of significant overburden deposits significantly increase sinkhole development, but mainly, these units are inherently more susceptible to begin with. Copyright ?? 2007. The American Association of Petroleum Geologists/Division of Environmental Geosciences. All rights reserved.

Groundwater flow cycling between a submarine spring and an inland fresh water spring.

PubMed

Davis, J Hal; Verdi, Richard

2014-01-01

Spring Creek Springs and Wakulla Springs are large first magnitude springs that derive water from the Upper Floridan Aquifer. The submarine Spring Creek Springs are located in a marine estuary and Wakulla Springs are located 18 km inland. Wakulla Springs has had a consistent increase in flow from the 1930s to the present. This increase is probably due to the rising sea level, which puts additional pressure head on the submarine Spring Creek Springs, reducing its fresh water flow and increasing flows in Wakulla Springs. To improve understanding of the complex relations between these springs, flow and salinity data were collected from June 25, 2007 to June 30, 2010. The flow in Spring Creek Springs was most sensitive to rainfall and salt water intrusion, and the flow in Wakulla Springs was most sensitive to rainfall and the flow in Spring Creek Springs. Flows from the springs were found to be connected, and composed of three repeating phases in a karst spring flow cycle: Phase 1 occurred during low rainfall periods and was characterized by salt water backflow into the Spring Creek Springs caves. The higher density salt water blocked fresh water flow and resulted in a higher equivalent fresh water head in Spring Creek Springs than in Wakulla Springs. The blocked fresh water was diverted to Wakulla Springs, approximately doubling its flow. Phase 2 occurred when heavy rainfall resulted in temporarily high creek flows to nearby sinkholes that purged the salt water from the Spring Creek Springs caves. Phase 3 occurred after streams returned to base flow. The Spring Creek Springs caves retained a lower equivalent fresh water head than Wakulla Springs, causing them to flow large amounts of fresh water while Wakulla Springs flow was reduced by about half. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.

Groundwater flow cycling between a submarine spring and an inland fresh water spring

USGS Publications Warehouse

Davis, J. Hal; Verdi, Richard

2014-01-01

Spring Creek Springs and Wakulla Springs are large first magnitude springs that derive water from the Upper Floridan Aquifer. The submarine Spring Creek Springs are located in a marine estuary and Wakulla Springs are located 18 km inland. Wakulla Springs has had a consistent increase in flow from the 1930s to the present. This increase is probably due to the rising sea level, which puts additional pressure head on the submarine Spring Creek Springs, reducing its fresh water flow and increasing flows in Wakulla Springs. To improve understanding of the complex relations between these springs, flow and salinity data were collected from June 25, 2007 to June 30, 2010. The flow in Spring Creek Springs was most sensitive to rainfall and salt water intrusion, and the flow in Wakulla Springs was most sensitive to rainfall and the flow in Spring Creek Springs. Flows from the springs were found to be connected, and composed of three repeating phases in a karst spring flow cycle: Phase 1 occurred during low rainfall periods and was characterized by salt water backflow into the Spring Creek Springs caves. The higher density salt water blocked fresh water flow and resulted in a higher equivalent fresh water head in Spring Creek Springs than in Wakulla Springs. The blocked fresh water was diverted to Wakulla Springs, approximately doubling its flow. Phase 2 occurred when heavy rainfall resulted in temporarily high creek flows to nearby sinkholes that purged the salt water from the Spring Creek Springs caves. Phase 3 occurred after streams returned to base flow. The Spring Creek Springs caves retained a lower equivalent fresh water head than Wakulla Springs, causing them to flow large amounts of fresh water while Wakulla Springs flow was reduced by about half.

Geologic Map of the Big Spring Quadrangle, Carter County, Missouri

USGS Publications Warehouse

Weary, David J.; McDowell, Robert C.

2006-01-01

The bedrock exposed in the Big Spring quadrangle of Missouri comprises Late Cambrian and Early Ordovician aged dolomite, sandstone, and chert. The sedimentary rocks are nearly flat lying except where they are adjacent to faults. The carbonate rocks are karstified, and the area contains numerous sinkholes, springs, caves, and losing streams. This map is one of several being produced under the U.S. Geological Survey (USGS) National Cooperative Geologic Mapping Program to provide geologic data applicable to land-use problems in the Ozarks of south-central Missouri. Ongoing and potential industrial and agricultural development in the Ozarks region has presented issues of ground-water quality in karst areas. A national park in this region (Ozark National Scenic Riverways, Missouri) is concerned about the effects of activities in areas outside of their stewardship on the water resources that define the heart of this park. This task applies geologic mapping and karst investigations to address issues surrounding competing land use in south-central Missouri. This task keeps geologists from the USGS associated with the park and allows the park to utilize USGS expertise and aid the NPS on how to effectively use geologic maps for park management. For more information, see: http://geology.er.usgs.gov/eespteam/Karst/index.html

Nutrient dynamics as indicators of karst processes: Comparison of the Chalk aquifer (Normandy, France) and the Edwards aquifer (Texas, U.S.A.)

USGS Publications Warehouse

Mahler, B.J.; Valdes, D.; Musgrove, M.; Massei, N.

2008-01-01

Karst aquifers display a range of geologic and geomorphic characteristics in a wide range of climatic and land-use settings; identification of transport dynamics representative of karst aquifers in general could help advance our understanding of these complex systems. To this end, nutrient, turbidity, and major ion dynamics in response to storms were compared at multiple sites in two karst aquifers with contrasting characteristics and settings: the Chalk aquifer (Eure Department, Normandy, France) and the Barton Springs segment of the Edwards Aquifer (Texas, U.S.A.). The Chalk aquifer is typified by high matrix porosity, thick surficial deposits (up to 30??m thick), and agricultural land use; the Barton Springs segment is typified by low matrix porosity, outcropping limestone, and urban land use. Following one to three storms, from 5 to 16 samples from springs and wells were analyzed for major ions, and specific conductance and turbidity were monitored continuously. Comparison of the chemographs indicated some generalized responses, including an increase in turbidity and potassium concentrations and a decrease in major ion and nitrate concentrations with infiltrating storm runoff. Factor analysis of major ions and turbidity revealed strikingly similar behavior of the chemical variables for the two aquifers: The first two factors, explaining more than 75% of the variability, illustrate that dynamics of most major ions (including nitrate) are opposed to those of turbidity and of potassium. The results demonstrate that potassium and nitrate are effective tracers of infiltrating storm runoff and resident ground water, respectively, and the similar results for these two highly contrasting aquifers suggest that the dynamics identified might be applicable to karst systems in general. ?? 2008 Elsevier B.V. All rights reserved.

Nutrient dynamics as indicators of karst processes: comparison of the Chalk aquifer (Normandy, France) and the Edwards aquifer (Texas, U.S.A.).

PubMed

Mahler, B J; Valdes, D; Musgrove, M; Massei, N

2008-05-26

Karst aquifers display a range of geologic and geomorphic characteristics in a wide range of climatic and land-use settings; identification of transport dynamics representative of karst aquifers in general could help advance our understanding of these complex systems. To this end, nutrient, turbidity, and major ion dynamics in response to storms were compared at multiple sites in two karst aquifers with contrasting characteristics and settings: the Chalk aquifer (Eure Department, Normandy, France) and the Barton Springs segment of the Edwards Aquifer (Texas, U.S.A.). The Chalk aquifer is typified by high matrix porosity, thick surficial deposits (up to 30 m thick), and agricultural land use; the Barton Springs segment is typified by low matrix porosity, outcropping limestone, and urban land use. Following one to three storms, from 5 to 16 samples from springs and wells were analyzed for major ions, and specific conductance and turbidity were monitored continuously. Comparison of the chemographs indicated some generalized responses, including an increase in turbidity and potassium concentrations and a decrease in major ion and nitrate concentrations with infiltrating storm runoff. Factor analysis of major ions and turbidity revealed strikingly similar behavior of the chemical variables for the two aquifers: The first two factors, explaining more than 75% of the variability, illustrate that dynamics of most major ions (including nitrate) are opposed to those of turbidity and of potassium. The results demonstrate that potassium and nitrate are effective tracers of infiltrating storm runoff and resident ground water, respectively, and the similar results for these two highly contrasting aquifers suggest that the dynamics identified might be applicable to karst systems in general.

[Impact of Rocky Desertification Treatment on Underground Water Chemistry and Dissolved Inorganic Carbon Isotope in Karst Areas].

PubMed

Xiao, Shi-zhen; Xiong, Kang-ning; Lan, Jia-cheng; Zhang, Hui; Yang, Long

2015-05-01

Five springs representing different land-use types and different karst rocky desertification treatment models were chosen at the Huajiang Karst Rocky Desertification Treatment Demonstration Site in Guanling-Zhenfeng Counties in Guizhou, to analyze the features of underground water chemistry and dissolved inorganic carbon isotopes (δ13C(DIC)) and reveal the effect of rocky desertification treatment on karstification and water quality. It was found that, the underground water type of the research area was HCO3-Ca; the water quality of the springs which were relatively less affected by human activities including Shuijingwan Spring (SJW) , Gebei Spring (GB), and Maojiawan Spring (MJW) was better than those relatively more affected by human activities including Diaojing Spring (DJ) and Tanjiazhai Spring (TJZ) , the main ion concentrations and electrical conductivity of which were higher; pH, SIc and pCO2 were sensitive to land-use types and rocky desertification treatment, which could be shown by the higher pH and SIc and lower pCO2 in MJW than those in the other four springs; (Ca(2+) + Mg2+)/HCO(3-) of SJW, MJW and GB were nearly 1:1, dominated by carbonate rock weathering by carbon acid, while the (Ca(2+) + Mg2+) of DJ and TJZ was much higher than HCO3-, suggesting that sulfate and nitrate might also dissolve carbonate rock because of the agricultural activities; δ13C(DIC) was lighter in wet season because of the higher biological activities; the average δ13C(DIC) was in the order of DJ (-12.79 per thousand) < SJW (-12.48 per thousand) < GB (-10.76 per thousand)) < MJW (-10.30 per thousand) < TJZ (-6.70 per thousand), which demonstrated that δ13C(DIC) would be heavier after rocky desertification and lighter after the rocky desertification are treated and controlled.

Characterisation of hydrogeological connections in a lowland karst network using time series analysis of water levels in ephemeral groundwater-fed lakes (turloughs)

NASA Astrophysics Data System (ADS)

Gill, L. W.; Naughton, O.; Johnston, P. M.; Basu, B.; Ghosh, B.

2013-08-01

This research has used continuous water level measurements five groundwater-fed lakes (or turloughs) in a linked lowland karst network of south Galway in Ireland over a 3 year period in order to elucidate the hydrogeological controls and conduit configurations forming the flooded karstic hydraulic system beneath the ground. The main spring outflow from this network discharges below mean sea level making it difficult to determine the hydraulic nature of the network using traditional rainfall-spring flow cross analysis, as has been done in many other studies on karst systems. However, the localised groundwater-surface water interactions (the turloughs) in this flooded lowland karst system can yield information about the nature of the hydraulic connections beneath the ground. Various different analytical techniques have been applied to the fluctuating turlough water level time series data in order to determine the nature of the linkage between them as well as hydraulic pipe configurations at key points in order to improve the conceptual model of the overall karst network. Initially, simple cross correlations between the different turlough water levels were carried out applying different time lags. Frequency analysis of the signals was then carried out using Fast Fourier transform analysis and then both discrete and continuous wavelet analyses have been applied to the data sets to characterise these inherently non-stationary time-series of fluctuating water levels. The analysis has indicated which turloughs are on the main line conduit system and which are somewhat off-line, the relative size of the main conduit in the network including evidence of localised constrictions, as well as clearly showing the tidal influence on the water levels in the three lower turloughs at shallow depths ∼8 km from the main spring outfall at the sea. It has also indicated that the timing of high rainfall events coincident with maximum spring tide levels may promote more consistent, long

Intensive exploitation of a karst aquifer leads to Cryptosporidium water supply contamination.

PubMed

Khaldi, S; Ratajczak, M; Gargala, G; Fournier, M; Berthe, T; Favennec, L; Dupont, J P

2011-04-01

Groundwater from karst aquifers is an important source of drinking water worldwide. Outbreaks of cryptosporidiosis linked to surface water and treated public water are regularly reported. Cryptosporidium oocysts are resistant to conventional drinking water disinfectants and are a major concern for the water industry. Here, we examined conditions associated with oocyst transport along a karstic hydrosystem, and the impact of intensive exploitation on Cryptosporidium oocyst contamination of the water supply. We studied a well-characterized karstic hydrosystem composed of a sinkhole, a spring and a wellbore. Thirty-six surface water and groundwater samples were analyzed for suspended particulate matter, turbidity, electrical conductivity, and Cryptosporidium and Giardia (oo)cyst concentrations. (Oo)cysts were identified and counted by means of solid-phase cytometry (ChemScan RDI(®)), a highly sensitive method. Cryptosporidium oocysts were detected in 78% of both surface water and groundwater samples, while Giardia cysts were found in respectively 22% and 8% of surface water and groundwater samples. Mean Cryptosporidium oocyst concentrations were 29, 13 and 4/100 L at the sinkhole, spring and wellbore, respectively. Cryptosporidium oocysts were transported from the sinkhole to the spring and the wellbore, with respective release rates of 45% and 14%, suggesting that oocysts are subject to storage and remobilization in karst conduits. Principal components analysis showed that Cryptosporidium oocyst concentrations depended on variations in hydrological forcing factors. All water samples collected during intensive exploitation contained oocysts. Control of Cryptosporidium oocyst contamination during intensive exploitation is therefore necessary to ensure drinking water quality. Copyright © 2011. Published by Elsevier Ltd.

Changes in sources and storage in a karst aquifer during a transition from drought to wet conditions

USGS Publications Warehouse

Wong, C.I.; Mahler, B.J.; Musgrove, M.; Banner, J.L.

2012-01-01

Understanding the sources and processes that control groundwater compositions and the timing and magnitude of groundwater vulnerability to potential surface-water contamination under varying meteorologic conditions is critical to informing groundwater protection policies and practices. This is especially true in karst terrains, where infiltrating surface water can rapidly affect groundwater quality. We analyzed the evolution of groundwater compositions (major ions and Sr isotopes) during the transition from extreme drought to wetconditions, and used inverse geochemical modeling (PHREEQC) to constrain controls on groundwater compositions during this evolution. Spring water and groundwater from two wells dominantly receiving diffuse and conduit flow (termed diffuse site and conduit site, respectively) in the Barton Springs segment of the Edwards aquifer (central Texas, USA) and surface water from losing streams that recharge the aquifer were sampled every 3–4 weeks during November 2008–March 2010. During this period, water compositions at the spring and conduit sites changed rapidly but there was no change at the diffuse site, illustrating the dual nature (i.e., diffuse vs. conduit) of flow in this karst system. Geochemical modeling demonstrated that, within a month of the onset of wetconditions, the majority of spring water and groundwater at the conduit site was composed of surface water, providing quantitative information on the timing and magnitude of the vulnerability of groundwater to potential surface-water contamination. The temporal pattern of increasing spring discharge and changing pattern of covariation between spring discharge and surface-water (steam) recharge indicates that that there were two modes of aquifer response—one with a small amount of storage and a second that accommodates more storage.

Use of isotopically-tagged isolates of E. coli for tracking bacterial movement in karst environments

NASA Astrophysics Data System (ADS)

Bandy, A.; Fryar, A. E.; Macko, S. A.; Cook, K.

2014-12-01

Because of limited filtration and turbulent flow, karst aquifers are more susceptible to microbial contamination than clastic aquifers. Assessment of microbial transport in groundwater is complicated by the need to identify tracers that have a low detection limit, have minimal background concentrations, behave like the organisms of interest, and are non-pathogenic. We are assessing transport of two non-pathogenic isolates of Escherichia coli (E. coli) compared to traditional groundwater tracers in epikarst above Cave Springs Cavern near Bowling Green, KY, and in a karst conduit that emerges at Royal Spring in Georgetown, KY. The E. coli isolate exhibiting higher attachment efficiency in saturated granular columns contains the iha gene, while the isolate exhibiting lower attachment efficiency contains the kps gene. For the field experiments, bacteria are being grown on media enriched in 13C or 15N. Isotopically-tagged bacteria will be injected with rhodamine WT as a solute tracer and fluorescent microspheres as an abiotic particulate tracer. We will monitor breakthrough of the tracers in the cave and at the spring; based on a previous field test, we anticipate that particulate tracers may be remobilized during subsequent storm events. E. coli will be quantified by molecular methods (qPCR) and dual isotope analysis. Preliminary findings suggest that these two methods may be complementary, with each method having detection limitations.

A LEXICON OF CAVE AND KARST TERMINOLOGY WITH SPECIAL REFERENCE TO ENVIRONMENTAL KARST HYDROLOGY (2002 EDITION)

EPA Science Inventory

Several attempts to classify karst terminology in an organized manner have been attempted in the past. The last few glossaries of karst terminology were organized in the late 1960s and published in the early 1970s. Since that time, many new terms related to karst in general hav...

Fractal And Multi-fractal Analysis Of The Hydraulic Property Variations Of Karst Aquifers

NASA Astrophysics Data System (ADS)

Majone, B.; Bellin, A.; Borsato, A.

Karst aquifers are very heterogeneous systems with hydraulic property variations acting at several continuous and discrete scales, as a result of the fact that macro- structural elements, such as faults and karst channels, and fractures are intertwined in a complex, and largely unknown, manner. Many experimental studies on karst springs showed that the recession limb of the typical storm hydrograph can be divided into several regions with different decreasing rate, suggesting that the discharge is com- posed of contributions experiencing different travel times. Despite the importance of karst aquifers as a source of fresh water for most Mediterranean countries fostered the attention of scientists and practitioners, the mechanisms controlling runoff production in such a complex subsurface environment need to be further explored. A detailed sur- vey, lasting for one year and conducted by the Museo Tridentino di Scienze Naturali of Trento, represents a unique opportunity to analyze the imprint of hydraulic prop- erty variations on the hydrological signal recorded at the spring of Prese Val, located in the Dolomiti group near Trento. Data include water discharge (Q), temperature (T) and electric conductivity of water (E). Analysis of the data revealed that the power spectrum of E scales as 1/f, with slightly, but significantly, smaller than 1. The scaling nature of the E-signal has been confirmed by rescaled range analysis of the time series. Since the electric conductivity is proportional to the concentration of ions in the spring water, which increases with the residence time, one may conclude that the fractal structure of the E signal is the consequence of a similar structure in the hydraulic property variations. This finding confirms previous results of Kirchner et al. (2000), who reported a similar behavior for chloride concentration in the streamflow of three small Welsh catchments. A more detailed analysis revealed that E and T are both multifractal signals

Assessment of key transport parameters in a karst system under different dynamic conditions based on tracer experiments: the Jeita karst system, Lebanon

NASA Astrophysics Data System (ADS)

Doummar, Joanna; Margane, Armin; Geyer, Tobias; Sauter, Martin

2018-03-01

Artificial tracer experiments were conducted in the mature karst system of Jeita (Lebanon) under various flow conditions using surface and subsurface tracer injection points, to determine the variation of transport parameters (attenuation of peak concentration, velocity, transit times, dispersivity, and proportion of immobile and mobile regions) along fast and slow flow pathways. Tracer breakthrough curves (TBCs) observed at the karst spring were interpreted using a two-region nonequilibrium approach (2RNEM) to account for the skewness in the TBCs' long tailings. The conduit test results revealed a discharge threshold in the system dynamics, beyond which the transport parameters vary significantly. The polynomial relationship between transport velocity and discharge can be related to the variation of the conduit's cross-sectional area. Longitudinal dispersivity in the conduit system is not a constant value (α = 7-10 m) and decreases linearly with increasing flow rate because of dilution effects. Additionally, the proportion of immobile regions (arising from conduit irregularities) increases with decreasing water level in the conduit system. From tracer tests with injection at the surface, longitudinal dispersivity values are found to be large (8-27 m). The tailing observed in some TBCs is generated in the unsaturated zone before the tracer actually arrives at the major subsurface conduit draining the system. This work allows the estimation and prediction of the key transport parameters in karst aquifers. It shows that these parameters vary with time and flow dynamics, and they reflect the geometry of the flow pathway and the origin of infiltrating (potentially contaminated) recharge.

Effects of projected climate (2011–50) on karst hydrology and species vulnerability—Edwards aquifer, south-central Texas, and Madison aquifer, western South Dakota

USGS Publications Warehouse

Mahler, Barbara J.; Stamm, John F.; Poteet, Mary F.; Symstad, Amy J.; Musgrove, MaryLynn; Long, Andrew J.; Norton, Parker A.

2015-12-22

Karst aquifers—formed by the dissolution of soluble rocks such as limestone—are critical groundwater resources in North America, and karst springs, caves, and streams provide habitat for unique flora and fauna. Springflow and groundwater levels in karst terrane can change greatly over short time scales, and therefore are likely to respond rapidly to climate change. How might the biological communities and ecosystems associated with karst respond to climate change and accompanying changes in groundwater levels and springflow? Sites in two central U.S. regions—the Balcones Escarpment of south-central Texas and the Black Hills of western South Dakota (fig. 1)—were selected to study climate change and its potential effects on the local karst hydrology and ecosystem. The ecosystems associated with the Edwards aquifer (Balcones Escarpment region) and Madison aquifer (Black Hills region) support federally listed endangered and threatened species and numerous State-listed species of concern, including amphibians, birds, insects, and plants. Full results are provided in Stamm and others (2014), and are summarized in this fact sheet.

[Nitrate storage and transport within a typical karst aquifer system in the paralleled ridge-valley of east Sichuan].

PubMed

Yang, Ping-Heng; Yuan, Dao-Xian; Ren, You-Rong; Xie, Shi-You; He, Qiu-Fang; Hu, Xiao-Feng

2012-09-01

In order to investigate the nitrate storage and transport in the karst aquifer system, the hydrochemical dynamics of Qingmuguan underground river system was monitored online by achieving high-resolution data during storm events and monthly data in normal weather. The principal component analysis was employed to analyze the karst water geochemistry. Results showed that nitrate in Jiangjia spring did not share the same source with soluble iron, manganese and aluminum, and exhibited different geochemical behaviors. Nitrate was derived from land surface and infiltrated together with soil water, which was mainly stored in fissure, pore and solution crack of karst unsaturated zone, whereas soluble iron, manganese and aluminum were derived from soil erosion and directly recharged the underground river through sinkholes and shafts. Nitrate transport in the karst aquifer system could be ideally divided into three phases, including input storage, fast output and re-inputting storage. Under similar external conditions, the karstification intensity of vadose zone was the key factor to determine the dynamics of nitrate concentrations in the groundwater during storm events. Nitrate stored in the karst vadose zone was easily released, which would impair the aquatic ecosystem and pose seriously threats to the local health. Thus, to strengthen the management of ecological system, changing the land-use patterns and scientifically applying fertilizer could effectively make a contribution to controlling mass nutrient input from the surface.

Freshwater biodissolution rates of limestone in the temperate climate of the Dinaric karst in Slovenia

NASA Astrophysics Data System (ADS)

Mulec, J.; Prelovšek, M.

2015-01-01

Dissolution rates in two freshwater karst systems were determined by using tablets of dense micrite-biopelmicrite Cretaceous limestone. Submerged limestone tablets in riverbeds were subjected to a natural gradient from complete darkness to direct sunlight. Higher light rates significantly (p < 0.05) increased the epilithic biomass of phototrophs and the overall dissolution rates, which were highest at the Unica spring (- 49.2 μm a- 1), but the exact portion of light-dependent dissolution remains elusive. In the karst river Unica, with its big fluctuations in environmental parameters (e.g., discharge), light rates can be used in estimating the dissolution rates enhanced by phototrophs. Natural biofilms in aquatic systems have important implications for landform evolution, and the impact on limestone dissolution rates is comparable with rates of debris falling from steep slopes.

Evaluation of onsite sewage treatment and disposal systems in shallow karst terrain.

PubMed

Harden, Harmon S; Roeder, Eberhard; Hooks, Mark; Chanton, Jeffrey P

2008-05-01

Two conventional onsite sewage treatment and disposal systems (OSTDSs) at Manatee Springs State Park, Florida, USA, were studied to assess their impact on groundwater quality in a shallow karst environment. Sulfur hexafluoride (SF6) and fluorescein were used as tracers to establish connections between the drainfields and monitoring wells. Elevated nutrients were found in all wells where significant concentrations of both tracers were observed, with the mean of the highest nitrate (NO3) concentration observed at each well being 47.8+/-14.9 (n=11) mg/L NO3-N. The most elevated nutrient concentrations were found directly in the flow path of the effluent. Fecal coliform densities above 10 colony-forming units (cfu)/100 mL were observed in wells with the most rapid connection to the drainfield. The proximity and connectivity of the 0.4-4m thick sandy surficial soils and the underlying karst aquifer allow rapid contaminant transport and limit the ability of conventional OSTDSs to attenuate NO3.

Simulating long term nitrate-N contamination processes in the Woodville Karst Plain using CFPv2 with UMT3D

NASA Astrophysics Data System (ADS)

Xu, Zexuan; Hu, Bill X.; Davis, Hal; Cao, Jianhua

2015-05-01

A research version of CFP (Conduit Flow Process) code, CFPv2, is applied with UMT3D to simulate long term (1966-2018) nitrate-N contamination transport processes in the Woodville Karst Plain (WKP), northern Florida, where karst conduit networks are well developed. Groundwater flow in the WKP limestone porous matrix is simulated using Darcy's law, and non-laminar flow within conduits is described by Darcy-Weisbach equation. Nitrate-N conduit transport and advective exchanges of groundwater and nitrate-N between conduits and limestone matrix are calculated by CFPv2 and UMT3D, instead of MODFLOW and MT3DMS since Reynolds numbers for flows in conduits are over the criteria of laminar flow. The developed numerical model is calibrated by field observations and then applied to simulate nitrate-N transport in the WKP. The numerical simulations verify the theories that two sprayfields near the City of Tallahassee and septic tanks in the rural area are major nitrate-N point sources within the WKP. High nitrate-N concentrations occur near Lost Creek Sink, and conduits of Wakulla Spring and Spring Creek Springs where aquifer discharge groundwater. Conduit networks control nitrate-N transport and regional contaminant distributions in the WKP, as nitrate-N is transported through conduits rapidly and spread over large areas.

Use of Nitrogen-15-Enriched Escherichia coli as a Bacterial Tracer in Karst Aquifers.

PubMed

Ward, James W; Warden, John G; Bandy, Ashley M; Fryar, Alan E; Brion, Gail M; Macko, Stephen A; Romanek, Christopher S; Coyne, Mark S

2016-11-01

Karst aquifers are susceptible to contamination by microorganisms, but relatively few studies have used bacteria as tracers. We demonstrate the utility of Escherichia coli enriched in the stable isotope nitrogen-15 ( 15 N) as a novel bacterial tracer. Nonpathogenic E. coli from two springs in central Kentucky were grown on 15 N-enriched media. Survival of E. coli and persistence of the isotopic signal were assessed in two sets of laboratory experiments conducted with sterilized spring water in dark microcosms at 14 °C. First, isotopically labeled bacteria survived for 130 d at concentrations within one log unit of the average initial value, and there was no significant difference in δ 15 N values from Day 1 to Day 130. Second, water samples with E. coli were inoculated with either of two different species of protozoa (Tetrahymena pyriformis or Colpoda steinii). During 7 d, δ 15 N values increased in T. pyriformis while bacterial populations decreased. In a field test, following a 2.1-cm rainfall, 15 N-labeled E. coli, solutes (rhodamine WT dye and bromide), and latex microspheres were injected into a sinkhole approximately 530 m upgradient of a spring. Breakthrough of all tracers coincided, but microspheres were remobilized by subsequent storms, unlike other tracers. Enriched E. coli exhibited more tailing than solute tracers during the initial storm-flow recession. These results indicate that 15 N-enriched E. coli is a viable tracer of bacterial transport in karst aquifers, although predation may attenuate the isotopic signal in systems that are not rapidly flushed. © 2016, National Ground Water Association.

Spatial heterogeneities and variability of karst hydro-system : insights from geophysics

NASA Astrophysics Data System (ADS)

Champollion, C.; Fores, B.; Lesparre, N.; Frederic, N.

2017-12-01

Heterogeneous systems such as karsts or fractured hydro-systems are challenging for both scientist and groundwater resources management. Karsts heterogeneities prevent the comparison and moreover the combination of data representative of different scales: borehole water level can generally not be used directly to interpret spring flow dynamic for example. The spatial heterogeneity has also an impact on the temporal variability of groundwater transfer and storage. Karst hydro-systems have characteristic non linear relation between precipitation amount and discharge at the outlets with threshold effects and a large variability of groundwater transit times In the presentation, geophysical field experiments conducted in karst hydro-system in the south of France are used to investigate groundwater transfer and storage variability at a scale of a few hundred meters. We focus on the added value of both geophysical time-lapse gravity experiments and 2D ERT imaging of the subsurface heterogeneities. Both gravity and ERT results can only be interpreted with large ambiguity or some strong a priori: the relation between resistivity and water content is not unique; almost no information about the processes can be inferred from the groundwater stock variations. The present study demonstrate how the ERT and gravity field experiments can be interpreted together in a coherent scheme with less ambiguity. First the geological and hydro-meteorological context is presented. Then the ERT field experiment including the processing and the results are detailed in the section about geophysical imaging of the heterogeneities. The gravity double difference (S2D) time-lapse experiment is described in the section about geophysical monitoring of the temporal variability. The following discussion demonstrate the impact of both experiments on the interpretation in terms of processes and heterogeneities.

Comparison of age distributions estimated from environmental tracers by using binary-dilution and numerical models of fractured and folded karst: Shenandoah Valley of Virginia and West Virginia, USA

USGS Publications Warehouse

Yager, Richard M.; Plummer, Niel; Kauffman, Leon J.; Doctor, Daniel H.; Nelms, David L.; Schlosser, Peter

2013-01-01

Measured concentrations of environmental tracers in spring discharge from a karst aquifer in the Shenandoah Valley, USA, were used to refine a numerical groundwater flow model. The karst aquifer is folded and faulted carbonate bedrock dominated by diffuse flow along fractures. The numerical model represented bedrock structure and discrete features (fault zones and springs). Concentrations of 3H, 3He, 4He, and CFC-113 in spring discharge were interpreted as binary dilutions of young (0–8 years) water and old (tracer-free) water. Simulated mixtures of groundwater are derived from young water flowing along shallow paths, with the addition of old water flowing along deeper paths through the model domain that discharge to springs along fault zones. The simulated median age of young water discharged from springs (5.7 years) is slightly older than the median age estimated from 3H/3He data (4.4 years). The numerical model predicted a fraction of old water in spring discharge (0.07) that was half that determined by the binary-dilution model using the 3H/3He apparent age and 3H and CFC-113 data (0.14). This difference suggests that faults and lineaments are more numerous or extensive than those mapped and included in the numerical model.

Anthropogenic contaminants as tracers in an urbanizing karst aquifer

USGS Publications Warehouse

Mahler, B.; Massei, N.

2007-01-01

Karst aquifers are uniquely vulnerable to contamination. In the Barton Springs segment of the karstic Edwards aquifer (Texas, U.S.A.), urban contaminants such as pesticides and volatile organic compounds frequently are detected in spring base flow. To determine whether contaminant concentrations change in response to storms, and if they therefore might act as tracers of focused recharge, samples were collected from Barton Springs at closely spaced intervals following three storms. Two herbicides (atrazine and simazine), two insecticides (carbaryl and diazinon), and a solvent (tetrachloroethene) described breakthrough curves over a 1-week period following one or more storms. The breakthrough curves were decomposed into two to five log-normal subcurves, which were interpreted as representing pulses of contaminants moving through the aquifer. Each subcurve could be used in the same way as an artificial tracer to determine travel time to and recovery at the spring. The contaminants have several advantages over artificial tracers: they represent the actual compounds of interest, they are injected essentially simultaneously at several points, and they are injected under those conditions when transport is of the most interest, i.e., following storms. The response of storm discharge, specific conductance, and contaminant loading at the spring depended on initial aquifer flow conditions, which varied from very low (spring discharge of 0.48??m3/s) to high (spring discharge of 2.7??m3/s): concentrations and recovery were the highest when initial aquifer flow conditions were low. This behavior provides information about aquifer structure and the influence of aquifer flow condition on transport properties. ?? 2006 Elsevier B.V. All rights reserved.

Geophysical imaging of karst features in Missouri

NASA Astrophysics Data System (ADS)

Obi, Jeremiah Chukwunonso

Automated electrical resistivity tomography (ERT) supported with multichannel analysis of surface waves (MASW) and boring data were used to map karst related features in Missouri in order to understand karst processes better in Missouri. Previous works on karst in Missouri were mostly surficial mapping of bedrock outcrops and joints, which are not enough to define the internal structure of karst system, since most critical processes in karst occur underground. To understand these processes better, the density, placement and pattern of karst related features like solution-widened joints and voids, as well as top of bedrock were mapped. In the course of the study, six study sites were visited in Missouri. The sites were in Nixa, Gasconade River Bridge in Lebanon, Battlefield, Aurora, Protem and Richland. The case studies reflect to a large extent some of the problems inherent in karst terrain, ranging from environmental problems to structural problems especially sinkhole collapses. The result of the study showed that karst in Missouri is mostly formed as a result of piping of sediments through solution-widened joints, with a pattern showing that the joints/fractures are mostly filled with moist clay-sized materials of low resistivity values. The highest density of mapped solution-widened joints was one in every one hundred and fifty feet, and these areas are where intense dissolution is taking place, and bedrock pervasively fractured. The study also showed that interpreted solution-widened joints trend in different directions, and often times conform with known structural lineaments in the area. About 40% of sinkhole collapses in the study areas are anthropogenic. Karst in Missouri varies, and can be classified as a combination of kI (juvenile), kIII (mature) and kIV (complex) karsts.

Puerto Rican Karst-A Vital Resource

Treesearch

Ariel E. Lugo; Leopoldo Miranda Castro; Abel Vale; Tania del Mar López; Enrique Hernández Prieto; Andrés García Martinó; Alberto R. Puente Rolón; Adrianne G. Tossas; Donald A. McFarlane; Tom Miller; Armando Rodríguez; Joyce Lundberg; John Thomlinson; José Colón; Johannes H. Schellekens; Olga Ramos; Eileen Helmer

2001-01-01

The limestone region of Puerto Rico covers about 27.5 percent of the island’s surface and is subdivided into the northern, southern, and dispersed limestone areas. All limestone areas have karst features. The karst belt is that part of the northern limestone with the most spectacular surficial karst landforms. It covers 142,544 ha or 65 percent of the northern...

Stochastic simulation of karst conduit networks

NASA Astrophysics Data System (ADS)

Pardo-Igúzquiza, Eulogio; Dowd, Peter A.; Xu, Chaoshui; Durán-Valsero, Juan José

2012-01-01

Karst aquifers have very high spatial heterogeneity. Essentially, they comprise a system of pipes (i.e., the network of conduits) superimposed on rock porosity and on a network of stratigraphic surfaces and fractures. This heterogeneity strongly influences the hydraulic behavior of the karst and it must be reproduced in any realistic numerical model of the karst system that is used as input to flow and transport modeling. However, the directly observed karst conduits are only a small part of the complete karst conduit system and knowledge of the complete conduit geometry and topology remains spatially limited and uncertain. Thus, there is a special interest in the stochastic simulation of networks of conduits that can be combined with fracture and rock porosity models to provide a realistic numerical model of the karst system. Furthermore, the simulated model may be of interest per se and other uses could be envisaged. The purpose of this paper is to present an efficient method for conditional and non-conditional stochastic simulation of karst conduit networks. The method comprises two stages: generation of conduit geometry and generation of topology. The approach adopted is a combination of a resampling method for generating conduit geometries from templates and a modified diffusion-limited aggregation method for generating the network topology. The authors show that the 3D karst conduit networks generated by the proposed method are statistically similar to observed karst conduit networks or to a hypothesized network model. The statistical similarity is in the sense of reproducing the tortuosity index of conduits, the fractal dimension of the network, the direction rose of directions, the Z-histogram and Ripley's K-function of the bifurcation points (which differs from a random allocation of those bifurcation points). The proposed method (1) is very flexible, (2) incorporates any experimental data (conditioning information) and (3) can easily be modified when

Destruction of dolines: the examples from Slovene karst

NASA Astrophysics Data System (ADS)

Kovacic, G.; Ravbar, N.

2012-04-01

Due to the absence of soil and flat agricultural land, in karst regions, the cultivation of doline bottoms and the clearing of stones on fields and meadows were traditional methods of adapting farming practices to the landscape with limited agricultural potential. In recent years, a variety of activities resulting from comprehensive economic and urban development have increased pressure on karst landscapes. In some areas the surface and the underground are increasingly threatened by industrial activities, uncontrolled settlement and spread of infrastructure, the development of tourism, and intensive agrarian land use. Unsupervised human encroachment on karst landscapes is causing the increasingly more frequent and more widespread degradation of karst relief forms. The intensive reshaping of the landscape has expanded beyond control largely as a result of technological development and mechanization. The excessive modern filling of dolines, as one of the most distinctive karst surface features, has become a major encroachment on the environment for leveling purposes. Such kind of human influence affects the shape of karst features and the appearance of the landscape as well as the intensity of karst processes such as corrosion. Many dolines are filled with general and construction waste, which threatens the existence of unique habitats and quality of groundwater and consequently water supply. This contribution presents some cases of inappropriate management of karst landscape in Slovenia and examines the national legislative framework on spatial planning in karst regions. Unfortunately, in the current legislation, the standards and conditions for the protection of karst landscape characteristics (e.g. dolines) are loose and not fully elaborated. Principally, there are no uniform mechanisms to protect specific relief forms or for the adequate protection of karst. To a large extent, the preservation of the characteristic karst landscape is left to local communities

Concentrations of nutrients, pesticides, and suspended sediment in the karst terrane of the Sinking Creek basin, Kentucky, 2004

USGS Publications Warehouse

Crain, Angela S.

2006-01-01

Water samples were collected in streams and springs in the karst terrane of the Sinking Creek Basin in 2004 as part of study in cooperation with the Kentucky Department of Agriculture. A total of 48 water samples were collected at 7 sites (4 springs, 2 streams, and 1 karst window) from April through November 2004. The karst terrane of the Sinking Creek Basin (also known as Boiling Spring Basin) encompasses about 125 square miles in Breckinridge County and portions of Meade and Hardin Counties in Kentucky. Fourteen pesticides were detected of the 52 pesticides analyzed in the stream and spring samples. Of the 14 detected pesticides, 12 were herbicides and 2 were insecticides. The most commonly detected pesticides?atrazine, simazine, metolachlor, and acetochlor?were those most heavily used on crops during the study. Atrazine was detected in 100 percent of all samples; simazine, metolachlor, and acetochlor were detected in more than 35 percent of all samples. The pesticide-transformation compound, deethylatrazine, was detected in 98 percent of the samples. Only one nonagricultural herbicide, prometon, was detected in more than 30 percent of the samples. Malathion, the most commonly detected insecticide, was found in 4 percent of the samples, which was followed by carbofuran (2 percent). Most of the pesticides were present in low concentrations; however, atrazine was found in springs exceeding the U.S. Environmental Protection Agency?s (USEPA) standards for drinking water. Atrazine exceeded the USEPA?s maximum contaminant level 2 times in 48 detections. Concentrations of nitrate greater than 10 milligrams per liter (mg/L) were not found in water samples from any of the sites. Concentrations of nitrite plus nitrate ranged from 0.21 to 3.9 mg/L at the seven sites. The median concentration of nitrite plus nitrate for all sites sampled was 1.5 mg/L. Concentrations of nitrite plus nitrate generally were higher in the springs than in the main stem of Sinking Creek. Forty

Results of a hydrogeological and hydrogeochemical study of a semi-arid karst aquifer in Tezbent plateau, Tebessa region, northeast of Algeria

NASA Astrophysics Data System (ADS)

Belfar, Dalila; Fehdi, Chemseddine; Baali, Fethi; Salameh, Elias

2017-06-01

The Hammamet Plain, situated in the northwest of the Tezbent mountain range, northeast of Algeria, drains carbonate aquifers through some important karst springs. The physical and chemical characteristics of spring and well water samples were studied for 2 years to assess the origin of groundwater and determine the factors driving the geochemical composition. The ionic speciation and mineral dissolution/precipitation was calculated. Water wells, characterizing groundwater circulation at shallow depths, are moderate to high mineralized waters of Na-HCO3 type. In contrast to the shallow environment, the CO2-rich, deeper waters are of the Ca-HCO3-SO4 type and undergo significant changes in the baseline chemistry along flow lines with increasing residence time. The main factors controlling the groundwater composition and its seasonal variations are the geology, because of the presence of carbonate formations, the elevation and the rate of karst development. In both groups, the carbonate chemistry is diagnostic of the effect of karst development. The supersaturation with respect to calcite indicates CO2 degassing, occurring either inside the aquifer in open conduits, or at the outlet in reservoirs. The undersaturation with respect to calcite shows the existence of fast flow and short residence time conditions inside the aquifer. Interaction between groundwater and surrounding host rocks is believed to be the main process responsible for the observed chemical characteristics of groundwater in the study area.

Hydrological connectivity in the karst critical zone: an integrated approach

NASA Astrophysics Data System (ADS)

Chen, X.; Zhang, Z.; Soulsby, C.; Cheng, Q.; Binley, A. M.; Tao, M.

2017-12-01

Spatial heterogeneity in the subsurface is high, evidenced by specific landform features (sinkholes, caves etc.) and resulting in high variability of hydrological processes in space and time. This includes complex exchange of various flow sources (e.g. hillslope springs and depression aquifers) and fast conduit flow and slow fracture flow. In this paper we integrate various "state-of-the-art" methods to understand the structure and function of this understudied critical zone environment. Geophysical, hydrometric and hydrogeochemical tools are used to characterize the hydrological connectivity of the cockpit karst critical zone in a small catchment of Chenqi, Guizhou province, China. Geophysical surveys, using electrical resistivity tomography (ERT), identified the complex conduit networks that link flows between hillslopes and depressions. Statistical time series analysis of water tables and discharge responses at hillslope springs and in depression wells and underground channels showed different threshold responses of hillslope and depression flows. This reflected the differing relative contribution of fast and slow flow paths during rainfall events of varying magnitude in the hillslope epikarst and depression aquifer in dry and wet periods. This showed that the hillslope epikarst receives a high proportion of rainfall recharge and is thus a main water resource in the catchment during the drought period. In contrast, the depression aquifer receives fast, concentrated hillslope flows during large rainfall events during the wet period, resulting in the filling of depression conduits and frequent flooding. Hydrological tracer studies using water temperatures and stable water isotopes (δD and δ18O) corroborated this and provided quantitative information of the mixing proportions of various flow sources and insights into water travel times. This revealed how higher contributions of event "new" water (from hillslope springs and depression conduits displaces "old" pre

Hydrologic Contributions of Springs to the Logan River, Utah

NASA Astrophysics Data System (ADS)

Gooseff, M. N.; Evans, J.; Kolesar, P.; Lachmar, T.; Payn, R.

2005-05-01

The Logan River flows through a fractured karst watershed of the Bear River mountain range in northern Utah, and provides significant water supply to the city of Logan, Utah. Springs flowing into the Logan River are important sources of water after annual snowmelt has been exhausted. In this work, we present results from a year of monitoring water chemistry and stable isotopes (D, 18O, and 13C) in two major springs and in the Logan River upstream and downstream of the combined spring inputs. The two springs, DeWitt and Spring Hollow, flow into the river within 1.5 km of each other. Annual patterns of Si and Mg suggest a flushing pattern, with reduced concentrations during snowmelt, and increasing concentrations throughout baseflow recession, at all for sampling locations. Cl concentrations are likewise greatly depressed after the snowmelt pulse but afterward remain consistently low at all four sites. Stable isotope data show that spring water is generally more enriched in D and 18O than river water, with an enriching pattern throughout annual stream flow recession.

The impact of river water intrusion on trace metal cycling in karst aquifers: an example from the Floridan aquifer system at Madison Blue Spring, Florida

NASA Astrophysics Data System (ADS)

Brown, A. L.; Martin, J. B.; Screaton, E.; Spellman, P.; Gulley, J.

2011-12-01

Springs located adjacent to rivers can serve as recharge points for aquifers when allogenic runoff increases river stage above the hydraulic head of the spring, forcing river water into the spring vent. Depending on relative compositions of the recharged water and groundwater, the recharged river water could be a source of dissolved trace metals to the aquifer, could mobilize solid phases such as metal oxide coatings, or both. Whether metals are mobilized or precipitated should depend on changes in redox and pH conditions as dissolved oxygen and organic carbon react following intrusion of the river water. To assess how river intrusion events affect metal cycling in springs, we monitored a small recharge event in April 2011 into Madison Blue Spring, which discharges to the Withlacoochee River in north-central Florida. Madison Blue Spring is the entrance to a phreatic cave system that includes over 7.8 km of surveyed conduits. During the event, river stage increased over base flow conditions for approximately 25 days by a maximum of 8%. Intrusion of the river water was monitored with conductivity, temperature and depth sensors that were installed within the cave system and adjacent wells. Decreased specific conductivity within the cave system occurred for approximately 20 days, reflecting the length of time that river water was present in the cave system. During this time, grab samples were collected seven times over a period of 34 days for measurements of major ion and trace metal concentrations at the spring vent and at Martz sink, a karst window connected to the conduit system approximately 150 meters from the spring vent. Relative fractions of surface water and groundwater were estimated based on Cl concentrations of the samples, assuming conservative two end-member mixing during the event. This mixing model indicates that maximum river water contribution to the groundwater system was approximately 20%. River water had concentrations of iron, manganese, and other

Seasonal changes of organic matter quality and quantity at the outlet of a forested karst system (La Roche Saint Alban, French Alps)

NASA Astrophysics Data System (ADS)

Tissier, Grégory; Perrette, Yves; Dzikowski, Marc; Poulenard, Jérome; Hobléa, Fabien; Malet, Emmanuel; Fanget, Bernard

2013-03-01

SummaryBecause of its impact on water quality, organic matter (OM) in karst groundwater has been widely studied. The present article describes a method for monitoring OM in karst aquifers characterized by quick responses to rainfall. This method combines weekly manual sampling and continuous monitoring to provide, qualitative and quantitative information about OM flow. Weekly samples were analyzed for Total Organic Carbon (TOC) content and spectrofluorescence, while continuous monitoring was carried out at the main spring, using a field fluorimeter (310/400-700 nm and 280/300-600 nm) to quantify chromophoric organic matter (COM). The type and quantity of COM were defined by decomposing Excitation Emission Matrices (EEMs) and by applying a 2D fluorescence decomposition method. Continuous monitoring data showed that the dominant COM was humic-like (HL). We found three types of relationship between HL and discharge and between HL and TOC, showing that caution must be exercised when using field fluorimeter measurements to quantify TOC. Each relationship was characterized by global differences in OM content and by the presence of different percentages of non-chromophoric organic matter. These three relationships are associated with changes in hydrology and microorganism activity during the year. We used these relationships to estimate the annual OM flow (about 15 kg/ha/year) and thereby quantify OM flow during the year. Our results show the importance of the non-chromophoric organic matter in such estimation. That work illustrates the need to couple qualitative and quantitative monitoring of OM in karst spring to improve the global comprehension of karst system and of the sources implies in the OM flow.

Pioneering Techniques to Determine Wastewater and Urban Runoff Loads in Karst Spring Systems

NASA Astrophysics Data System (ADS)

Hasenmueller, E. A.; Criss, R. E.

2010-12-01

Comparison of urban and rural springs quantifies the magnitude and sources of water quality degradation in east-central Missouri. Urban springs consistently display a suite of impairment characteristics including increases in: (1) specific conductance; (2) coliform bacteria; (3) total suspended solids (TSS); (4) nutrient concentrations including N, P, and S species; (5) B concentration; (6) heavy metal concentrations such as Cd, Cr, and Pb; and (7) temperature variability. Several dozen springs, representing a range in magnitude and recharge area land use, were sampled in and around St. Louis, MO. In addition, effluent from the Duckett Creek Treatment Plant was sampled to ascertain the chemistry of municipal waste waters in the area. Sodium perborate is a primary ingredient in bleaching agents for detergents, and therefore B is found in very high concentrations in waste waters (> 240 ppb) compared to background levels (< 20 ppb) in carbonate-hosted springs. Consequently, B provides an excellent, conservative tracer of sewage contributions to groundwater systems, and this study has shown that several urban springs comprise > 25% waste water. High B concentrations correlate well with increased nutrient contents and high E. coli and total coliform levels, which also suggest large sewage contributions to the shallow groundwater. Elevated specific conductance in these springs is primarily due to road salt contamination of these Ca-Mg-bicarbonate waters. In marked contrast to natural springs, Na and Cl can even be the dominant ions in urban springs, so they are useful indicators of urban runoff. High concentrations of Na and Cl ions persist well into late summer, confirming stable isotope models for the ~ 1 year residence time of these shallow groundwaters. Further, specific conductance, temperature, and TSS are highly variable in urban springs because of amplified throughput of storm water runoff; in fact, many detention basins directly feed into cave systems. Dissolved

A generalized genetic framework for the development of sinkholes and Karst in Florida, U.S.A.

NASA Astrophysics Data System (ADS)

Beck, Barry F.

1986-03-01

Karst topography in Florida is developed on the Tertiary limestones of the Floridan aquifer Post-depositional diagenesis and solution have made these limestones highly permeable, T=ca. 50,000 m2/d. Zones of megaporosity have formed at unconformities, and dissolution has enlarged joints and fractures Erosion of the overlying clastic Miocene Hawthorn group strata on one flank of a structural arch has exposed the limestone The elevated edge of the Hawthorn cover forms the Cody scarp Ubiquitous solution pipes have previously formed at joint intersections and are now filled Downwashing of the fill deeper into solution cavities in the limestone and subsidence of the overlying unconsolidated sediments causes surface collapse a subsidence doline or sinkhole This process may penetrate up to 60 m of the semi-consolidated Hawthorn cover, as occurred when the Winter Park sinkhole developed Dense clusters of solution pipes may have formed cenotes which are now found on the exposed limestone terrain Groundwater moves laterally as diffuse flow except where input or outflow is concentrated. At sinking streams, vertical shafts, and springs, karst caves have formed, but only the major sinking streams form through-flowing conduit systems Shaft recharge dissipates diffusely. Spring discharge is concentrated from diffuse flow In both cases, conduits taper and merge into a zone of megaporosity

A new species of karst-adapted Cnemaspis Strauch, 1887 (Squamata: Gekkonidae) from a threatened karst region in Pahang, Peninsular Malaysia.

PubMed

Grismer, L Lee; Wood, Perry L; Mohamed, Maketab; Chan, Kin Onn; Heinz, Heather M; Sumarli, Alex S-I; Chan, Jacob A; Loredo, Ariel I

2013-12-12

A new species of karst-adapted gekkonid lizard of the genus Cnemaspis Strauch is described from Gua Gunting and Gua Goyang in a karst region of Merapoh, Pahang, Peninsular Malaysia whose unique limestone formations are in immediate danger of being quarried. The new species differs from all other species of Cnemaspis based on its unique suite of morphological and color pattern characters. Its discovery underscores the unique biodiversity endemic to karst regions and adds to a growing list of karst-adapted reptiles from Peninsular Malaysia. We posit that new karst-adapted species endemic to limestone forests will continue to be discovered and these regions will harbor a significant percentage of Peninsular Malaysia's biodiversity and thusly should be conserved rather than quarried.

Identification of the dominant hydrological process and appropriate model structure of a karst catchment through stepwise simplification of a complex conceptual model

NASA Astrophysics Data System (ADS)

Chang, Yong; Wu, Jichun; Jiang, Guanghui; Kang, Zhiqiang

2017-05-01

Conceptual models often suffer from the over-parameterization problem due to limited available data for the calibration. This leads to the problem of parameter nonuniqueness and equifinality, which may bring much uncertainty of the simulation result. How to find out the appropriate model structure supported by the available data to simulate the catchment is still a big challenge in the hydrological research. In this paper, we adopt a multi-model framework to identify the dominant hydrological process and appropriate model structure of a karst spring, located in Guilin city, China. For this catchment, the spring discharge is the only available data for the model calibration. This framework starts with a relative complex conceptual model according to the perception of the catchment and then this complex is simplified into several different models by gradually removing the model component. The multi-objective approach is used to compare the performance of these different models and the regional sensitivity analysis (RSA) is used to investigate the parameter identifiability. The results show this karst spring is mainly controlled by two different hydrological processes and one of the processes is threshold-driven which is consistent with the fieldwork investigation. However, the appropriate model structure to simulate the discharge of this spring is much simpler than the actual aquifer structure and hydrological processes understanding from the fieldwork investigation. A simple linear reservoir with two different outlets is enough to simulate this spring discharge. The detail runoff process in the catchment is not needed in the conceptual model to simulate the spring discharge. More complex model should need more other additional data to avoid serious deterioration of model predictions.

What Can We Learn About Karst Aquifer Heterogeneity From Pumping Tests

NASA Astrophysics Data System (ADS)

Marechal, J. C.; Dewandel, B.; Ladouche, B.; Fleury, P.

2016-12-01

Due to the complexity and duality of flows, well-test interpretation into karst systems constitutes a challenging task for hydrogeologists. This is especially true when the pumping well intersects karst heterogeneities such as the conduit network. The method of diagnostic plots, widely used in oil industry, can be applied to karst hydrogeology. In this paper, the classical response of a well-test into a karst conduit is described on a log-log drawdown derivative curve. It allows identifying successive flow regimes corresponding to the contribution of various karst aquifer subsystems (fractured matrix, karst conduit, main karst drainage network) to the pumped well. In heterogeneous karst systems, the log-log diagnostic plot of drawdown and its derivative in the pumping well can help identifying departures in flow-geometry from the classical homogeneous radial case. Classically, the diagnostic plot can be divided into several portions with: (a) early data used for identifying the karst conduit storage; (b) intermediate data for identifying the type of aquifer model that should be used (e.g. double porosity, anisotropy...); and (c) late data for identifying the possible boundaries. This is illustrated on three examples from Mediterranean karsts in southern France. A one-month duratio pumping test on a well intersecting the main karst drainage network of the Cent-Fonts karst system shows (i) a preliminary contribution of the karst conduit storage capacity followed by (ii) linear flows into the fractured matrix. A pumping test on a well intersecting a small karst conduit of the Corbières karst system shows the existence of (i) bi-linear flow within both the karst conduit and the fractured matrix at early times, followed by (ii) radial flows within the fractured matrix and (iii) finally the contribution of a major karst cavity. A two-months duration pumping test on a deep confined karst aquifer under low permeability rocks into the Gardanne basin shows the existence of

The Trends of the Male and Female Teachers of the Basic Elementary Stages towards Using the Smart Board in Bani Kinanah Directorate of Education

ERIC Educational Resources Information Center

Hamadneh, Qaseem Mohammad Salim; Ghazal, Asem Ali Abu

2016-01-01

The study aimed to explore the trends of the male and female teachers of the basic elementary stages towards using the Smart Board in Bani Kinanah Directorate of Education and the relationship of some variables such as sex, academic qualification, and years of experience. The study sample consisted of (130) male and female teachers. To achieve the…

Gypsum karst in Italy: a review

NASA Astrophysics Data System (ADS)

De Waele, Jo; Chiarini, Veronica; Columbu, Andrea; D'Angeli, Ilenia M.; Madonia, Giuliana; Parise, Mario; Piccini, Leonardo; Vattano, Marco; Vigna, Bartolomeo; Zini, Luca; Forti, Paolo

2016-04-01

Although outcropping only rarely in Italy, gypsum karst has been described in detail since the early XXth century (Marinelli, 1917). Gypsum caves are now known from almost all Italian regions (Madonia & Forti, 2003), but are mainly localised along the northern border of the Apennine chain (Emilia Romagna and Marche regions), Calabria, and Sicily, where the major outcrops occur. Recently, important caves have also been discovered in the underground gypsum quarries in Piedmont (Vigna et al., 2010). During the late 80s and 90s several multidisciplinary studies have been carried out in many gypsum areas. All this work converged into a comprehensive overview in 2003 (Madonia & Forti, 2003). Further detailed studies focused on the gypsum areas of Emilia Romagna (Chiesi et al., 2010; Forti & Lucci, 2010; Demaria et al., 2012; De Waele & Pasini, 2013; Ercolani et al., 2013; Columbu et al., 2015; Lucci & Piastra, 2015; Tedeschi et al., 2015) and of Sicily (Madonia & Vattano, 2011). Sinkholes related to Permo-Triassic gypsum have been studied in Friuli Venezia Giulia (Zini et al., 2015). This presentation will review the state of the art regarding different aspects of evaporite karst in Italy focusing on the main new results. References Chiesi M., et al. (2010) - Origin and evolution of a salty gypsum/anhydrite karst spring: the case of Poiano (Northern Apennines, Italy). Hydrogeology Journal, 18, pp. 1111-1124. Columbu A. et al. (2015) - Gypsum caves as indicators of climate-driven river incision and aggradation in a rapidly uplifting region. Geology, 43(6), 539-542. Demaria D. et al. (Eds.) (2012), Le Grotte Bolognesi, GSB-USB, 431 p. De Waele J., Pasini G. (2013) - Intra-messinian gypsum palaeokarst in the northern Apennines and its palaeogeographic implications. Terra Nova 25, pp. 199-205. Ercolani M., et al. (Eds.) (2013), I Gessi e la Cave i Monte Tondo. Studio multidisciplinare di un'area carsica nella Vena del Gesso Romagnola. Memorie Ist. It. Spel. II(26), 559 p

Analysis of hydrologic and geochemical time-series data at James Cave, Virginia: Implications for epikarst influence on recharge in Appalachian karst aquifers

USGS Publications Warehouse

Eagle, Sarah D.; Orndorff, William; Schwartz, Benjamin F.; Doctor, Daniel H.; Gerst, Jonathan D.; Schreiber, Madeline E.

2016-01-01

The epikarst, which consists of highly weathered rock in the upper vadose zone of exposed karst systems, plays a critical role in determining the hydrologic and geochemical characteristics of recharge to an underlying karst aquifer. This study utilized time series (2007–2014) of hydrologic and geochemical data of drip water collected within James Cave, Virginia, to examine the influence of epikarst on the quantity and quality of recharge in a mature, doline-dominated karst terrain. Results show a strong seasonality of both hydrology and geochemistry of recharge, which has implications for management of karst aquifers in temperate climatic zones. First, recharge (discharge from the epikarst to the underlying aquifer) reaches a maximum between late winter and early spring, with the onset of the recharge season ranging from as early as December to as late as March during the study period. The timing and duration of the recharge season were found to be a function of precipitation in excess of evapotranspiration on a seasonal time scale. Secondly, seasonally variable residence times for water in the epikarst influence rock-water interaction and, hence, the geochemical characteristics of recharge. Overall, results highlight the strong and complex influence that the epikarst has on karst recharge, which requires long-term and high-resolution data sets to accurately understand and quantify.

Parameter identification of the SWAT model on the BANI catchment (West Africa) under limited data condition

NASA Astrophysics Data System (ADS)

Chaibou Begou, Jamilatou; Jomaa, Seifeddine; Benabdallah, Sihem; Rode, Michael

2015-04-01

Due to the climate change, drier conditions have prevailed in West Africa, since the seventies, and the consequences are important on water resources. In order to identify and implement management strategies of adaptation to climate change in the sector of water, it is crucial to improve our physical understanding of water resources evolution in the region. To this end, hydrologic modelling is an appropriate tool for flow predictions under changing climate and land use conditions. In this study, the applicability and performance of the recent version of Soil and Water Assessment Tool (SWAT2012) model were tested on the Bani catchment in West Africa under limited data condition. Model parameters identification was also tested using one site and multisite calibration approaches. The Bani is located in the upper part of the Niger River and drains an area of about 101, 000 km2 at the outlet of Douna. The climate is tropical, humid to semi-arid from the South to the North with an average annual rainfall of 1050 mm (period 1981-2000). Global datasets were used for the model setup such as: USGS hydrosheds DEM, USGS LCI GlobCov2009 and the FAO Digital Soil Map of the World. Daily measured rainfall from nine rain gauges and maximum and minimum temperature from five weather stations covering the period 1981-1997 were used for model setup. Sensitivity analysis, calibration and validation are performed within SWATCUP using GLUE procedure at Douna station first (one site calibration), then at three additional internal stations, Bougouni, Pankourou and Kouoro1 (multi-site calibration). Model parameters were calibrated at daily time step for the period 1983-1992, then validated for the period 1993-1997. A period of two years (1981-1982) was used for model warming up. Results of one-site calibration showed that the model performance is evaluated by 0.76 and 0.79 for Nash-Sutcliffe (NS) and correlation coefficient (R2), respectively. While for the validation period the performance

Effects of dynamically variable saturation and matrix-conduit coupling of flow in karst aquifers

USGS Publications Warehouse

Reimann, T.; Geyer, T.; Shoemaker, W.B.; Liedl, R.; Sauter, M.

2011-01-01

Well-developed karst aquifers consist of highly conductive conduits and a relatively low permeability fractured and/or porous rock matrix and therefore behave as a dual-hydraulic system. Groundwater flow within highly permeable strata is rapid and transient and depends on local flow conditions, i.e., pressurized or nonpressurized flow. The characterization of karst aquifers is a necessary and challenging task because information about hydraulic and spatial conduit properties is poorly defined or unknown. To investigate karst aquifers, hydraulic stresses such as large recharge events can be simulated with hybrid (coupled discrete continuum) models. Since existing hybrid models are simplifications of the system dynamics, a new karst model (ModBraC) is presented that accounts for unsteady and nonuniform discrete flow in variably saturated conduits employing the Saint-Venant equations. Model performance tests indicate that ModBraC is able to simulate (1) unsteady and nonuniform flow in variably filled conduits, (2) draining and refilling of conduits with stable transition between free-surface and pressurized flow and correct storage representation, (3) water exchange between matrix and variably filled conduits, and (4) discharge routing through branched and intermeshed conduit networks. Subsequently, ModBraC is applied to an idealized catchment to investigate the significance of free-surface flow representation. A parameter study is conducted with two different initial conditions: (1) pressurized flow and (2) free-surface flow. If free-surface flow prevails, the systems is characterized by (1) a time lag for signal transmission, (2) a typical spring discharge pattern representing the transition from pressurized to free-surface flow, and (3) a reduced conduit-matrix interaction during free-surface flow. Copyright 2011 by the American Geophysical Union.

Multitracer experiment to evaluate the attenuation of selected organic micropollutants in a karst aquifer.

PubMed

Hillebrand, Olav; Nödler, Karsten; Sauter, Martin; Licha, Tobias

2015-02-15

The increasing pressure on drinking water resources necessitates an efficient management of potential and actual drinking water resources. Karst aquifers play a key role in the supply of the world's population with drinking water. Around one quarter of all drinking water is produced from these types of aquifers. Unfortunately due to the aquifer characteristics with extremely high hydraulic conductivities and short residence times, these systems are vulnerable to contamination. For successful management, a fundamental understanding of mass transport and attenuation processes with respect to potential contaminants is vital. In this study, a multitracer experiment was performed in a karst aquifer in SW-Germany for determining the attenuation capacity of a karst environment by assessing the environmental fate of selected relevant micropollutants. Uranine, acesulfame and carbamazepine were injected into a sinkhole as reference tracers together with the reactive compounds atenolol, caffeine, cyclamate, ibuprofen and paracetamol (also known as acetaminophen). The breakthrough of the tracers was monitored at a karst spring at a distance of ca. 3 km. The breakthrough curves of the reactive compounds were interpreted relative to the reference substances. No significant retardation was found for any of the investigated micropollutants. The determined half-lives of the reactive compounds range from 38 to 1,400 h (i.e. persistent within the investigation period) in the following order (from high to no observed attenuation): paracetamol>atenolol≈ibuprofen>caffeine≫cyclamate. The attenuation rates are generally in agreement with studies from other environmental compartments. The occurrence of the biotransformation product atenolol acid served as evidence for in-situ biodegradation within the aquifer system. Copyright © 2014 Elsevier B.V. All rights reserved.

Modern and Unconventional Approaches to Karst Hydrogeology

NASA Astrophysics Data System (ADS)

Sukop, M. C.

2017-12-01

Karst hydrogeology is frequently approached from a hydrograph/statistical perspective where precipitation/recharge inputs are converted to output hydrographs and the conversion process reflects the hydrology of the system. Karst catchments show hydrological response to short-term meteorological events and to long-term variation of large-scale atmospheric circulation. Modern approaches to analysis of these data include, for example, multiresolution wavelet techniques applied to understand relations between karst discharge and climate fields. Much less effort has been directed towards direct simulation of flow fields and transport phenomena in karst settings. This is primarily due to the lack of information on the detailed physical geometry of most karst systems. New mapping, sampling, and modeling techniques are beginning to enable direct simulation of flow and transport. A Conduit Flow Process (CFP) add-on to the USGS ModFlow model became available in 2007. FEFLOW and similar models are able to represent flows in individual conduits. Lattice Boltzmann models have also been applied to flow modeling in karst systems. Regarding quantitative measurement of karst system geometry, at scales to 0.1 m, X-ray computed tomography enables good detection of detailed (sub-millimeter) pore space in karstic rocks. Three-dimensional printing allows reconstruction of fragile high porosity rocks, and surrogate samples generated this way can then be subjected to laboratory testing. Borehole scales can be accessed with high-resolution ( 0.001 m) Digital Optical Borehole Imaging technologies and can provide virtual samples more representative of the true nature of karst aquifers than can obtained from coring. Subsequent extrapolation of such samples can generate three-dimensional models suitable for direct modeling of flow and transport. Finally, new cave mapping techniques are beginning to provide information than can be applied to direct simulation of flow. Due to flow rates and cave

Karst landscapes and associated resources: a resource assessment.

Treesearch

James F. Baichtal; Douglas N. Swanston

1996-01-01

The Tongass National Forest contains world-class karst features and the largest concentration of associated dissolved caves known in the state of Alaska. This paper describes the dominant karst formation processes operating in southeast Alaska, the controlling geologic and hydrologic characteristics, and the influence of karst landscapes on associated forest resources...

Transient deformation of karst aquifers observed by GPS: improved knowledge from Central Apennines (Italy)

NASA Astrophysics Data System (ADS)

Silverii, F.; D'Agostino, N.; Borsa, A. A.

2017-12-01

The redistribution of water masses due to temporal variations of hydrological conditions can produce observable deformation of the shallow crust. Space geodesy, e.g., GPS and InSAR, has provided a considerable improvement in terms of data accuracy and spatial and temporal resolution for the detection and investigation of this kind of deformation. In particular, in the areas where snow and water accumulate for long periods, such as aquifers, relatively high deformation (up to several millimeters) has been observed. Karst aquifers are able to store huge amounts of water and a clear deformation related to the groundwater storage variations has been observed in some regions. In a recent study we showed that the karst aquifers of Southern Apennines deform in response of seasonal and interannual variations of groundwater content, producing a visible transient signal in the time series of the surrounding GPS sites. In this work, we analyze the GPS time series and hydrological data of Central Italy, an interesting and complex area which hosts huge karst aquifers and is characterized by high seismic activity. We show that a noticeable transient signal with features similar to those of Southern Apennines affects also the time series of Central Apennines, suggesting that the large karst aquifers of this region experience a process analogue to the ones in Southern Italy. Thanks to the availability of a dense GPS network and different kinds of hydrological data (rainfall, spring discharge, groundwater level) we focus on the process causing the observed deformation. In particular, we model the observed deformation by inverting the GPS data using Green's functions for finite strain cuboid sources (Barbot et al. 2017). An enhanced understanding of the causes and implications of the highlighted deformation of karst aquifers is of primary interest for an improved management of this important water resource and for a better understanding of the possible interactions between

The Effect of Using Jigsaw Strategy in Teaching Science on the Acquisition of Scientific Concepts among the Fourth Graders of Bani Kinana Directorate of Education

ERIC Educational Resources Information Center

Hamadneh, Qaseem Mohammad Salim

2017-01-01

The study aimed to identify the effect of using Jigsaw strategy in teaching science on the acquisition of scientific concepts among the fourth graders of Bani Kinana Directorate of Education compared to the traditional way. The study sample consisted of 70 male and female students, divided into two groups: experimental and control where the…

A remote sensing study of regional variation in sinkhole morphology-Florida karst vs. Minnesota karst

NASA Astrophysics Data System (ADS)

Ernst, C. L.; Hadizadeh, J.; McCarty, J. L.

2010-12-01

In many regions of the United States, database technologies and GIS have facilitated spatial analysis of karst. The purpose of this research was to compare regional latitudinal variation in sinkhole karst morphology via remote sensing techniques. Such comparison may be significant because the development of a karst landscape depends primarily on climate and availability of water as well as lithology. Sinkhole karst, a common karst in the U.S., is morphologically defined as cone-shaped depressions with circular or oval opening to the surface that result from the dissolution of relatively soluble bedrock such as limestone or gypsum. The two regions of interest, north-central Florida and southeastern Minnesota, were selected based on structural and lithological similarity of limestone bedrock and the fact that the bedrock study areas are located in clearly different climate zones. This approach utilized topographic maps, digital elevation models, state karst feature databases, and high resolution 0.6m QuickBirdTM and 0.5m WorldView 1TM satellite images in a GIS environment. Morphological parameters - area, perimeter, minor axis and major axis length - were calculated on a total of 80 sinkholes in the study regions using the zonal geometry function, a tool in the spatial analysis extension provided by ESRITM. Our results show that north-central Florida and southeastern Minnesota karst are statistically different in terms of sinkhole shape and size distribution. Florida has larger sinkholes (2,835 square meter Mean) that are closer to circular shape. Minnesota has smaller (1,213 square meter Mean) and more elliptical sinkholes with a comparatively shorter minor axis. Of the possible explanations, climate appears to be the most likely cause for the observed differences. The higher amount of precipitation in Florida coupled with warmer year round temperatures provides an environment conducive to a more chemically involved hydrological regime, which may be responsible for

Development, description, and application of a geographic information system data base for water resources in karst terrane in Greene County, Missouri

USGS Publications Warehouse

Waite, L.A.; Thomson, Kenneth C.

1993-01-01

A geographic information system data base was developed for Greene County, Missouri, to provide data for use in the protection of water resources. The geographic information system data base contains the following map layers: geology, cave entrances and passages, county and quadrangle boundary, dye traces, faults, geographic names, hypsography, hydrography, lineaments, Ozark aquifer potentio- metric surface, public land survey system, sink- holes, soils, springs, and transportation. Several serious incidents of ground-water contamination have been reported in the karst terrane developed in soluble carbonate rocks in Greene County. Karst terranes are environmentally sensitive because any contaminant carried by surface runoff has the potential for rapid transport through solution enlarged fractures to the ground-water system. In the karst terrane in Greene County, about 2,500 sinkholes have been located; these sinkholes are potential access points for contamination to the ground-water system. Recent examples of ground-water contamination by sewage, fertilizers, and hydrocarbon chemicals have demonstrated the sensitivity of ground water in the Greene County karst terrane to degradation. The ground-water system is a major source of drinking water for Greene County. The population in Greene County, which includes Springfield, the third largest city in Missouri, is rapidly increasing and the protection of the water resources of Greene County is an increasing concern.

Picos de Europa National and Regional parks (Northern Spain): the karst underground landscape

NASA Astrophysics Data System (ADS)

Ballesteros, Daniel; Jiménez-Sánchez, Montserrat; Rodríguez-Rodríguez, Laura; José Domínguez-Cuesta, María; Meléndez-Asensio, Mónica; García-Sansegundo, Joaquín

2015-04-01

, few fluvial deposits, some speleothems (dripstone, flowstone), few ice caves, many underground streams, and karst springs. The scientific value corresponds to the cave records related to the regional evolution of the Cantabrian Range. The scientific studies evidence that the caves are originated prior to, at least, the Middle Pleistocene, in relation to mountain uplift, glaciations, fluvial incision, and the erosion of the alpine lithological seriesthat were above the karst. The cultural value is related with the specific uses of the cavities by shepherds and speleologists, and the singularity of cave names. The uses include traditional customs, as the livestock farming, the water collection, the elaboration of five types of cheese with Certificated of Origin, and sport uses by speleologists from many countries of Europe. The educative values are low due to the limitations of access inside the caves, although two caves are touristic and the entrance of some caves can be used to explain vadose shafts, relations between caves and glaciers and rivers or the underground water flow. GEOCAVE project (MAGRAMA-580/12 OAPN)

[Difference of Karst Carbon Sink Under Different Land Use and Land Cover Areas in Dry Season].

PubMed

Zhao, Rui-yi; Liang, Zuo-bing; Wang, Zun-bo; Yu, Zheng-liang; Jiang, Ze-li

2015-05-01

In order to identify the distinction of soil CO2 consumed by carbonate rock dissolution, Baishuwan spring, Lanhuagou spring and Hougou spring were selected as objects to monitor the hydrochemistry from November 2013 to May 2014. The results showed that the highest HCO3- concentration was observed in Baishuwan spring which is covered by pine forest, while the lowest HCO3- concentration was observed in Hougou spring which is mainly covered by cultivated land. In Baishuwan spring, HCO3- was mainly derived from carbonic acid dissolving carbonate rock and the molar ratio between Ca(2+) + Mg2+ and HCO3- was close to 0. 5; while the molar ratio between Ca(2+) + Mg2+ and HCO3- exceeded 0.5 because the carbonate rock in Lanhuagou spring and Hougou spring was mainly dissolved by nitric acid and sulfuric acid. Because of the input of litter and the fact that gas-permeability of soil was limited in Baishuwan spring catchment, most of soil CO2 was dissolved in infiltrated water and reacted with bedrock. However, in Lanhuagou spring catchment and Hougou spring catchment, porous soil made soil CO2 easier to return to the atmosphere in the form of soil respiration. Therefore, in order to accurately estimate karst carbon sink, it was required to clarify the distinction of CO2 consumption by carbonate rock dissolution under different land use and land cover areas.

Delineating Fecal Contaminant Sources and Travel Times in a Karst Groundwater Basin, Inner Bluegrass Region, Kentucky

NASA Astrophysics Data System (ADS)

Ward, J. W.; Reed, T. M.; Fryar, A. E.; Brion, G. M.

2006-12-01

Because of preferential flowpaths via features such as sinkholes and conduits, karst aquifers are susceptible to non-point-source pollution from agricultural and urban drainage. With many karst aquifers being drinking- water sources, pathogens are contaminants of public health concern. Monitoring of microbial parameters (total coliforms [TC], atypical colonies [AC] and fecal coliform bacteria [FC]) transpired biweekly from December 2002 March 2004 and weekly from February October 2005 at Blue Hole Spring, which drains outlying farm lands and the town of Versailles in the Inner Bluegrass Region of Kentucky. Physicochemical parameters (discharge, temperature, specific conductance, and pH) were measured continuously during the entire period. The AC/TC ratio, which had been employed only in surface water-quality studies, was used with FC counts, precipitation and discharge data to determine sources of fecal loading to ground water as result of land-use practices. An AC/TC ratio < 10 demonstrates fresh input of fecal matter, while a larger ratio can represent a variety of occurrences, including aged fecal material input and/or lack of nutrient input into the system. AC/TC ratio data in the 2002 04 dataset behaved similarly to surface waters, with ratios > 10 during dry periods and < 10 during wet periods, while the 2005 data demonstrated a very irregular pattern. The difference in these two data sets indicated a compositional change within the groundwater basin between the two sampling periods, perhaps as a result of construction at a sewage treatment plant adjoining the spring. Solute (rhodamine WT fluorescent dye and bromide) and particle (1-μm diameter fluorescent latex microspheres) tracer tests were conducted during summer 2006 to examine contaminant mobility within the system under base-flow and storm-flow conditions. Rainfall was limited prior to the base-flow trace, totaling 0.025 cm within 2 weeks prior to the slug injection. Base-flow discharge averaged 400 m

The Level of Diagnostic Tests' Preparation Skills among the Teachers of the First Three Elementary Grades' Teachers at the Directorate of Education of Bani Kinana District

ERIC Educational Resources Information Center

Yaghmour, Kholoud Subhi; Obaidat, Luai Taleb; Hamadneh, Qaseem Mohammad

2016-01-01

This study aimed at exploring the level of Diagnostic Tests' Preparation Skills among the teachers of the first Three Elementary Grades at the Directorate of Education of Bani Kinana District, and its relationship to the variables of gender, academic qualification, and years of experience. The sample of the study consisted of (264) male and female…

Highway runoff in areas of karst topography.

DOT National Transportation Integrated Search

2004-01-01

Karst terrain is characterized by sinkholes, depressions, caves, and underground drainage, generally underlain by soluble rocks such as limestone and dolomite. Because natural filtration through soil is limited in karst areas, pollutants in highway s...

ERT, GPR, InSAR, and tracer tests to characterize karst aquifer systems under urban areas: The case of Quebec City

NASA Astrophysics Data System (ADS)

Martel, Richard; Castellazzi, Pascal; Gloaguen, Erwan; Trépanier, Luc; Garfias, Jaime

2018-06-01

Urban infrastructures built over karst settings may be at risk of collapse due to hydro-chemical erosion of underlying rock structures. In such settings, mapping cave networks and monitoring ground stability is important to assure civil safety and guide future infrastructure development decisions. However, no technique can directly and comprehensively map these hydrogeological features and monitor their stability. The most reliable method to map a cave network is through speleological exploration, which is not always possible due to restrictions, narrow corridors/passages, or high water levels. Borehole drilling is expensive and is often only performed where the presence of karsts is suggested by other techniques. Numerous indirect and cost-effective methods exist to map a karst flow system, such as geophysics, geodesy, and tracer tests. This paper presents the outcomes from a challenging application in Quebec City, Canada, where a multidisciplinary approach was designed to better understand the groundwater dynamics and cave paths. Two tracer tests in groundwater flowing through the cave system indicated that water flows along an approximately straight path from the sinking stream to the spring. It also suggests the presence of a parallel flow path close to the one already partially mapped. This observation was confirmed by combining Ground Penetrating Radar (GPR) and Electrical Resistivity Tomography (ERT) techniques, and ultimately by observing voids in several boreholes drilled close to the main cave path. Lowering the water levels at the suspected infiltration zone and inside the karst, the infiltration cracks were identified and the hydraulic link between them was confirmed. In fact, almost no infiltration occurs into the karst system when the water level at the sinking stream drops below a threshold level. Finally, SAR interferometry (InSAR) using RADARSAT-2 images detected movements on few buildings located over a backfilled sinkhole intercepted by the karst

GIS thematic layers for assessing karst hazard in Murgia region (Italy)

NASA Astrophysics Data System (ADS)

Canora, Filomena; D'Angella, Annachiara; Fidelibus, Dolores; Lella, Angela; Pellicani, Roberta; Spilotro, Giuseppe

2013-04-01

The assessment of karst hazard in a carbonate area may be somewhat complex for the multiplicity of involved factors (geological, hydrological, morphological, anthropogenic, etc.), their history and the slow rate of evolution of the processes. In coastal areas, moreover, the long term sea level variations and the short term oscillations generally influence the generation and evolution of the karst process. Another peculiarity of the karst hazard assessment consists in the difficulty for identifying the location of subsurface forms, which may develop over very large areas without any kind of surface signal. The karst processes and landforms often require specific methods of investigation and mitigation, due to the unique and highly variable characters of karst environments. In addition, the hidden character of the karst processes, often accelerated by human activity, is an issue with significant economic impact, affecting many regions of the world. The assessment of karst hazard in the Murgia plateau (in central-west of Apulia region) is the main goal of this research. For this aim, the typologies of karst phenomena, able to produce hazard in the study area, were individuated and collected in a specific database. The hazard was evaluated on the basis of the probability of occurrence of a phenomenon of instability, active (produced by human activities) or passive (natural evolution of karst process), in relation to the presence, evolution or generation of karst forms on surface or at critical distance from the surface. The critical distance from the surface is defined as the distance at which the local or general destructive evolution of a karst process can produce a variation of the usability of the area or of the value of elements involved in the instability. The thematic layers relative to the factors influencing karst processes and landforms (doline, sinkholes, polje, lame, gravine, caves) were elaborated and managed in a GIS system. The archives of the main karst

Imaging groundwater infiltration dynamics in the karst vadose zone with long-term ERT monitoring

NASA Astrophysics Data System (ADS)

Watlet, Arnaud; Kaufmann, Olivier; Triantafyllou, Antoine; Poulain, Amaël; Chambers, Jonathan E.; Meldrum, Philip I.; Wilkinson, Paul B.; Hallet, Vincent; Quinif, Yves; Van Ruymbeke, Michel; Van Camp, Michel

2018-03-01

Water infiltration and recharge processes in karst systems are complex and difficult to measure with conventional hydrological methods. In particular, temporarily saturated groundwater reservoirs hosted in the vadose zone can play a buffering role in water infiltration. This results from the pronounced porosity and permeability contrasts created by local karstification processes of carbonate rocks. Analyses of time-lapse 2-D geoelectrical imaging over a period of 3 years at the Rochefort Cave Laboratory (RCL) site in south Belgium highlight variable hydrodynamics in a karst vadose zone. This represents the first long-term and permanently installed electrical resistivity tomography (ERT) monitoring in a karst landscape. The collected data were compared to conventional hydrological measurements (drip discharge monitoring, soil moisture and water conductivity data sets) and a detailed structural analysis of the local geological structures providing a thorough understanding of the groundwater infiltration. Seasonal changes affect all the imaged areas leading to increases in resistivity in spring and summer attributed to enhanced evapotranspiration, whereas winter is characterised by a general decrease in resistivity associated with a groundwater recharge of the vadose zone. Three types of hydrological dynamics, corresponding to areas with distinct lithological and structural features, could be identified via changes in resistivity: (D1) upper conductive layers, associated with clay-rich soil and epikarst, showing the highest variability related to weather conditions; (D2) deeper and more resistive limestone areas, characterised by variable degrees of porosity and clay contents, hence showing more diffuse seasonal variations; and (D3) a conductive fractured zone associated with damped seasonal dynamics, while showing a great variability similar to that of the upper layers in response to rainfall events. This study provides detailed images of the sources of drip

Changes in groundwater quality in a conduit-flow-dominated karst aquifer, following BMP implementation

USGS Publications Warehouse

Currens, J.C.

2002-01-01

Water quality in the Pleasant Grove Spring karst groundwater basin, Logan County, Kentucky, was monitored to determine the effectiveness of best management practices (BMPs) in protecting karst aquifers. Ninety-two percent of the 4,069-ha (10,054-acre) watershed is used for agriculture. Water-quality monitoring began in October 1992 and ended in November 1998. By the fall of 1995 approximately 72% of the watershed was enrolled in BMPs sponsored by the US Department of Agriculture Water Quality Incentive Program (WQIP). Pre-BMP nitrate-nitrogen concentration averaged 4.65 mg/1. The median total suspended solids concentration was 127 mg/1. The median triazine concentration measured by immunosorbent assay was 1.44 ??tg/l. Median bacteria counts were 418 colonies per 100 ml (col/100 ml) for fecal coliform and 540 col/100 ml for fecal streptococci. Post-BMP, the average nitrate-nitrogen concentration was 4.74 mg/1. The median total suspended solids concentration was 47.8 mg/1. The median triazine concentration for the post-BMP period was 1.48 ??g/1. The median fecal coliform count increased to 432 col/100 ml after BMP implementation, but the median fecal streptococci count decreased to 441 col/100 ml. The pre- and post-BMP water quality was statistically evaluated by comparing the annual mass flux, annual descriptive statistics, and population of analyses for the two periods. Nitrate-nitrogen concentration was unchanged. Increases in atrazine-equivalent flux and triazine geometric averages were not statistically significant. Total suspended solids concentration decreased slightly, whereas orthophosphate concentration increased slightly. Fecal streptococci counts were reduced. The BMPs were only partially successful because the types available and the rules for participation resulted in less effective BMPs being chosen. Future BMP programs in karst areas should emphasize buffer strips around sinkholes, excluding livestock from streams and karst windows, and withdrawing

Modeling turbidity and flow at daily steps in karst using ARIMA/ARFIMA-GARCH error models

NASA Astrophysics Data System (ADS)

Massei, N.

2013-12-01

Hydrological and physico-chemical variations recorded at karst springs usually reflect highly non-linear processes and the corresponding time series are then very often also highly non-linear. Among others, turbidity, as an important parameter regarding water quality and management, is a very complex response of karst systems to rain events, involving direct transfer of particles from point-source recharge as well as resuspension of particles previously deposited and stored within the system. For those reasons, turbidity modeling has not been well taken in karst hydrological models so far. Most of the time, the modeling approaches would involve stochastic linear models such ARIMA-type models and their derivatives (ARMA, ARMAX, ARIMAX, ARFIMA...). Yet, linear models usually fail to represent well the whole (stochastic) process variability, and their residuals still contain useful information that can be used to either understand the whole variability or to enhance short-term predictability and forecasting. Model residuals are actually not i.i.d., which can be identified by the fact that squared residuals still present clear and significant serial correlation. Indeed, high (low) amplitudes are followed in time by high (low) amplitudes, which can be seen on residuals time series as periods of time during which amplitudes are higher (lower) then the mean amplitude. This is known as the ARCH effet (AutoRegressive Conditional Heteroskedasticity), and the corresponding non-linear process affecting residuals of a linear model can be modeled using ARCH or generalized ARCH (GARCH) non-linear modeling, which approaches are very well known in econometrics. Here we investigated the capability of ARIMA-GARCH error models to represent a ~20-yr daily turbidity time series recorded at a karst spring used for water supply of the city of Le Havre (Upper Normandy, France). ARIMA and ARFIMA models were used to represent the mean behavior of the time series and the residuals clearly

Karst database development in Minnesota: Design and data assembly

USGS Publications Warehouse

Gao, Y.; Alexander, E.C.; Tipping, R.G.

2005-01-01

The Karst Feature Database (KFD) of Minnesota is a relational GIS-based Database Management System (DBMS). Previous karst feature datasets used inconsistent attributes to describe karst features in different areas of Minnesota. Existing metadata were modified and standardized to represent a comprehensive metadata for all the karst features in Minnesota. Microsoft Access 2000 and ArcView 3.2 were used to develop this working database. Existing county and sub-county karst feature datasets have been assembled into the KFD, which is capable of visualizing and analyzing the entire data set. By November 17 2002, 11,682 karst features were stored in the KFD of Minnesota. Data tables are stored in a Microsoft Access 2000 DBMS and linked to corresponding ArcView applications. The current KFD of Minnesota has been moved from a Windows NT server to a Windows 2000 Citrix server accessible to researchers and planners through networked interfaces. ?? Springer-Verlag 2005.

Estimating the proportion of groundwater recharge from flood events in relation to total annual recharge in a karst aquifer

NASA Astrophysics Data System (ADS)

Dvory, N. Z.; Ronen, A.; Livshitz, Y.; Adar, E.; Kuznetsov, M.; Yakirevich, A.

2017-12-01

Sustainable groundwater production from karstic aquifers is primarily dictated by its recharge rate. Therefore, in order to limit over-exploitation, it is essential to accurately quantify groundwater recharge. Infiltration during erratic floods in karstic basins may contribute substantial amount to aquifer recharge. However, the complicated nature of karst systems, which are characterized in part by multiple springs, sinkholes, and losing/gaining streams, present a large obstacle to accurately assess the actual contribution of flood water to groundwater recharge. In this study, we aim to quantify the proportion of groundwater recharge during flood events in relation to the annual recharge for karst aquifers. The role of karst conduits on flash flood infiltration was examined during four flood and artificial runoff events in the Sorek creek near Jerusalem, Israel. The events were monitored in short time steps (four minutes). This high resolution analysis is essential to accurately estimating surface flow volumes, which are of particular importance in arid and semi-arid climate where ephemeral flows may provide a substantial contribution to the groundwater reservoirs. For the present investigation, we distinguished between direct infiltration, percolation through karst conduits and diffused infiltration, which is most affected by evapotranspiration. A water balance was then calculated for the 2014/15 hydrologic year using the Hydrologic Engineering Center - Hydrologic Modelling System (HEC-HMS). Simulations show that an additional 8% to 24% of the annual recharge volume is added from runoff losses along the creek that infiltrate through the karst system into the aquifer. The results improve the understanding of recharge processes and support the use of the proposed methodology for quantifying groundwater recharge.

Gypsum-karst problems in constructing dams in the USA

USGS Publications Warehouse

Johnson, K.S.

2008-01-01

Gypsum is a highly soluble rock and is dissolved readily to form caves, sinkholes, disappearing streams, and other karst features that typically are also present in limestones and dolomites. Gypsum karst is widespread in the USA and has caused problems at several sites where dams were built, or where dam construction was considered. Gypsum karst is present (at least locally) in most areas where gypsum crops out, or is less than 30-60 m below the land surface. These karst features can compromise on the ability of a dam to hold water in a reservoir, and can even cause collapse of a dam. Gypsum karst in the abutments or foundation of a dam can allow water to pass through, around, or under a dam, and solution channels can enlarge quickly, once water starts flowing through such a karst system. The common procedure for controlling gypsum karst beneath the dam is a deep cut-off trench, backfilled with impermeable material, or a close-spaced grout curtain that hopefully will fill all cavities. In Oklahoma, the proposed Upper Mangum Dam was abandoned before construction, because of extensive gypsum karst in the abutments and impoundment area. Catastrophic failure of the Quail Creek Dike in southwest Utah in 1989 was due to flow of water through an undetected karstified gypsum unit beneath the earth-fill embankment. The dike was rebuilt, at a cost of US $12 million, with construction of a cut-off trench 600 m long and 25 m deep. Other dams in the USA with severe gypsum-karst leakage problems in recent years are Horsetooth and Carter Lake Dams, in Colorado, and Anchor Dam, in Wyoming. ?? 2007 Springer-Verlag.

Verification of the karst flow model under laboratory controlled conditions

NASA Astrophysics Data System (ADS)

Gotovac, Hrvoje; Andric, Ivo; Malenica, Luka; Srzic, Veljko

2016-04-01

Karst aquifers are very important groundwater resources around the world as well as in coastal part of Croatia. They consist of extremely complex structure defining by slow and laminar porous medium and small fissures and usually fast turbulent conduits/karst channels. Except simple lumped hydrological models that ignore high karst heterogeneity, full hydraulic (distributive) models have been developed exclusively by conventional finite element and finite volume elements considering complete karst heterogeneity structure that improves our understanding of complex processes in karst. Groundwater flow modeling in complex karst aquifers are faced by many difficulties such as a lack of heterogeneity knowledge (especially conduits), resolution of different spatial/temporal scales, connectivity between matrix and conduits, setting of appropriate boundary conditions and many others. Particular problem of karst flow modeling is verification of distributive models under real aquifer conditions due to lack of above-mentioned information. Therefore, we will show here possibility to verify karst flow models under the laboratory controlled conditions. Special 3-D karst flow model (5.6*2.6*2 m) consists of concrete construction, rainfall platform, 74 piezometers, 2 reservoirs and other supply equipment. Model is filled by fine sand (3-D porous matrix) and drainage plastic pipes (1-D conduits). This model enables knowledge of full heterogeneity structure including position of different sand layers as well as conduits location and geometry. Moreover, we know geometry of conduits perforation that enable analysis of interaction between matrix and conduits. In addition, pressure and precipitation distribution and discharge flow rates from both phases can be measured very accurately. These possibilities are not present in real sites what this model makes much more useful for karst flow modeling. Many experiments were performed under different controlled conditions such as different

The genetic structure of the chloride ion runoff on the example of karst and non-karst geosystems of Arkhangelsk oblast

NASA Astrophysics Data System (ADS)

Khayrullina, D. N.; Kurzhanova, A. A.

2018-01-01

This paper deals with the estimate the structure of the chloride ion runoff from the karst (on the example of the Sula river basin) and non-karst (on the example of the Vaga river basin) geosystems of Arkhangelsk oblast. The contribution of the surface component predominates in the structure of the chloride ion runoff.For example, the input of surface ion runoff is 49% (for the Sula river basin), 55% (for the Vaga river basin). In time aspect the highest values of variability of the components of the chloride ion runoff are noted for karst geosystems and vary from 38.5% to 55.4% and from 24.7% to 42.9% - for non-karst geosystems.Finally, there is prevalence of the local factors influence because the atmospheric component decreases while ion runoff increases.

A tracer test to determine a hydraulic connection between the Lauchert and Danube karst catchments (Swabian Alb, Germany)

NASA Astrophysics Data System (ADS)

Knöll, Paul; Scheytt, Traugott

2018-03-01

A dye tracer experiment was conducted between the rivers Lauchert and Danube near Sigmaringen (Swabian Alb, southern Germany). After a flood event in the River Lauchert, it was suspected that flood water infiltrated into the karst system and drained towards springs in the Danube Valley. A potential connection of the two rivers is provided by the margin of a tectonic graben crossing the valleys. The aim of the tracer experiment was to gain insight into the dominant groundwater flow direction as well as to study a possible preferential connection between the Lauchert surface catchment area and springs in the Danube Valley. After introducing sodium-fluorescein into the unsaturated zone, six springs in the Danube Valley and the River Lauchert itself were observed. Tracer breakthrough at three springs showed that these springs are fed by groundwater originating in the Lauchert surface catchment. Adjacent springs were not affected by the experiment, indicating a rather sharp divide between separate spring catchments. Analyses of tracer breakthrough curves suggest that springs with a tracer occurrence are fed by the same conduit system. It was possible to show that spring catchments in Sigmaringen reach significantly into the Lauchert surface catchment. As a consequence, a drinking-water supplier has changed its supply strategy. The results also help to explain significant differences between flood damage in the central and lower courses of the River Lauchert.

Using stable isotopes and multi-spatial variable parameters in characterising the karstic aquifer of the Ajloun area, NW-Jordan - A case study of the Tanour and Rasoun springs

NASA Astrophysics Data System (ADS)

Hamdan, Ibraheem; Wiegand, Bettina; Ptak, Thomas; Licha, Tobias; Toll, Mathias; Margane, Armin; Sauter, Martin

2015-04-01

Key words: Karst systems, Groundwater vulnerability, Stable isotopes, Jordan. Water resources are extremely scarce in Jordan, which is considered as one of the poorest countries in the world with respect to water resources availability (UNDP 2014), with more than 90% of the country receiving less than 200 mm/year of rainfall (Al Kharadsheh et al. 2012). The most important aquifer for drinking-water purposes in Jordan is the upper Cretaceous limestone aquifer. The karstic springs of Tanour and Rasoun, located in the Ajloun governorate around 75 kilometres northwest of the capital of Amman, have been selected for this study. These springs are the main source for the local domestic water supply, with an average discharge between the years 2000 and 2012 of 200 m3/h and 60 m3/h, respectively (MWI, 2013). During the past few years, the water supply from these two springs had to be discontinued due to high contamination of the groundwater either by microbiological contaminants or by wastewater from local olive oil presses. This wastewater is locally called 'Zeebar'. Understanding of the karst aquifer system, the pathways and movement within the epikarst, and estimation of the travel and residence time within the aquifer is important for managing and evaluating the pollution risk, which affects the usability of groundwater for drinking purposes. For a better understanding of the karstic system and its behaviour, different methods are applied: 1. Analysis of the stable isotope composition of δ2H and δ18O during the winter season for both (a) Tanour and Rasoun groundwater, and (b) rainfall samples collected from several locations at different elevations within the catchment. 2. Analysis of major ion concentrations in groundwater of the Tanour and Rasoun springs. 3. Long-term measurements of different physico-chemical parameters from the Tanour and Rasoun springs (temperature, conductivity, turbidity, TOC, etc.) using multiparameter probes with telemetric data transfer. 4

Viruses and bacteria in karst and fractured rock aquifers in east Tennessee, USA

USGS Publications Warehouse

Johnson, T.B.; McKay, L.D.; Layton, A.C.; Jones, S.W.; Johnson, G.C.; Cashdollar, J.L.; Dahling, D.R.; Villegas, L.F.; Fout, G.S.; Williams, D.E.; Sayler, G.

2011-01-01

A survey of enteric viruses and indicator bacteria was carried out in eight community water supply sources (four wells and four springs) in East Tennessee. Seven sites derived their water from carbonate aquifers and one from fractured sandstone. Four of the sites were deemed "low-risk" based on prior monitoring of fecal indicators and factors such as presence of thick layers of overlying sediments. The remaining sites were deemed "high-risk." Enteric viruses (enterovirus and reovirus) were detected by cell culture at least once in seven of the eight wells or springs including all but one of the four low-risk sites. Viral RNA, however, was not detected in any of the samples by reverse transcription-polymerase chain reaction. Conventional indicators of microbial contamination (Escherichia coli and total coliform bacteria) were detected together with culturable viruses in seven of nine virus positive samples. Bacteroides, an alternative fecal indicator which has not previously been used in groundwater investigations, was also detected in all but one of the samples containing E. coli or total coliform bacteria, as well as in one sample where viruses were present in the absence of other bacterial indicators. The study highlights some of the challenges involved in surveys of virus occurrence and indicates that culturable enteric viruses in East Tennessee karst aquifers may be more widespread than previously observed in studies of karst aquifers in Pennsylvania (8%), the Ozark region of Missouri (< 1%), or several other states covered in a national microbial water quality survey conducted by the U.S. Environmental Protection Agency (43%). Copyright ?? 2010 The Author(s). Journal compilation ?? 2010 National Ground Water Association.

Bacterial Activity and Geochemical Reactions in Submerged Cave Development -- Impact on Karst Aquifers in Florida

NASA Astrophysics Data System (ADS)

Herman, J. S.; Franklin, R. B.; Mills, A. L.; Giannotti, A. L.; Tysall, T. N.

2008-05-01

Elucidation of coupled mechanisms of sulfide oxidation and biomass generation supports an improved understanding the driving forces behind acid production, calcite dissolution, cave development, and karst aquifers characterization. Wekiwa Springs Cave and DeLeon Springs Cave, located in central Florida, both contain prolific bacterial mats from which sulfur-oxidizing bacteria have been identified. Wekiwa Springs Cave, a submerged cave developed in the Hawthorne Formation and located near Orlando, Florida, has groundwater discharge from the Floridian aquifer system, with some contribution from surficial and intermediate aquifers. The spring is the headwater of the Wekiwa River and releases a total of 170,000 m3 of water per day. The ceiling and walls are heavily covered (10 cm thick) with three morphologically distinct types of microbial mats largely comprising sulfur-oxidizing bacteria. Analysis of nearby groundwater collected from wells confirms sulfide concentrations in the regional groundwater of ~ 1.5 mg/L, though sulfide concentrations for water collected in the cave are below detection. Dissolved oxygen concentration in the water is low (<0.5 mg/L). DeLeon Springs Cave, a submerged cave located in Volusia County, Florida, is a single conduit with an average discharge of ~ 70,000 m3 of water per day, and water chemistry data suggest the presence of a saline seep in the system. Dense microbial mats cover the rock surfaces of the cave; the mats are highly filamentous, with long white streamers that often extend 1-2 feet from the cave wall. Microscopic analysis has confirmed the presence of sulfur granules within these bacterial cells, similar to those observed in the Wekiwa cave organisms. The water chemistry in DeLeon Springs Cave, however, is distinct from that of Wekiwa Springs Cave. Though DO, Fetotal, and HS- values are similar for the two sites, the concentration of ions such as Cl-, Na+, and SO42- are considerably higher at DeLeon. A similar contrast

Soil nitrogen biogeochemical cycles in karst ecosystems, southwest China

NASA Astrophysics Data System (ADS)

Li, Dejun; Chen, Hao; Xiao, Kongcao; Wang, Kelin

2017-04-01

Soil nitrogen (N) status are crucial for ecosystem development and carbon sequestration. Although most terrestrial ecosystems are proposed to be limited by N, some tropical low-land forests have been found to be N saturated. Nevertheless, soil N status in the karst ecosystems of southwest China have not been well assessed so far. In the present study, N status in the karst ecosystems were evaluated based on several lines of evidence. Bulk N content increased rapidly along a post-agricultural succession sequence including cropland, grassland, shrubland, secondary forest and primary forest. Across the sequence, soil N accumulated with an average rate of 12.4 g N m-2 yr-1. Soil N stock recovered to the primary forest level in about 67 years following agricultural abandonment. Nitrate concentrations increased while ammonium concentrations decreased with years following agricultural abandonment. N release from bedrock weathering was likely a potential N source in addition to atmospheric N deposition and biological N fixation. Both gross N mineralization and nitrification (GN) rates decreased initially and then increased greatly following agricultural abandonment. The rate of dissimilatory nitrate reduction to ammonium (DNRA) was highest in the shrubland while lowest in the cropland and forest. Across the vegetation types, DNRA was lowest among the gross rates. Gross ammonium immobilization (GAI) tended to decrease while there was no clear variation pattern for gross nitrate immobilization during the post-agricultural succession. DNRA and nitrate assimilation combined only accounted for 22% to 57% of gross nitrification across the vegetation types. Due to the high nitrate production while low nitrate consumption, net nitrate production was found to vary following the pattern of gross nitrification and explained 69% of soil nitrate variance. Comparison of gross N transformations between a secondary karst forest and an adjacent non-karst forest showed that the gross rates

Sediment carbon fate in phreatic karst (Part 1): Conceptual model development

NASA Astrophysics Data System (ADS)

Husic, A.; Fox, J.; Agouridis, C.; Currens, J.; Ford, W.; Taylor, C.

2017-06-01

Recent research has paid increased attention to quantifying the fate of carbon pools within fluvial networks, but few, if any, studies consider the fate of sediment organic carbon in fluviokarst systems despite that karst landscapes cover 12% of the earth's land surface. The authors develop a conceptual model of sediment carbon fate in karst terrain with specific emphasis upon phreatic karst conduits, i.e., those located below the groundwater table that have the potential to trap surface-derived sediment and turnover carbon. To assist with their conceptual model development, the authors study a phreatic system and apply a mixture of methods traditional and novel to karst studies, including electrical resistivity imaging, well drilling, instantaneous velocimetry, dye tracing, stage recording, discrete and continuous sediment and water quality sampling, and elemental and stable carbon isotope fingerprinting. Results show that the sediment transport carrying capacity of the phreatic karst water is orders of magnitude less than surface streams during storm-activated periods promoting deposition of fine sediments in the phreatic karst. However, the sediment transport carrying capacity is sustained long after the hydrologic event has ended leading to sediment resuspension and prolonged transport. The surficial fine grained laminae occurs in the subsurface karst system; but unlike surface streams, the light-limited conditions of the subsurface karst promotes constant heterotrophy leading to carbon turnover. The coupling of the hydrological processes leads to a conceptual model that frames phreatic karst as a biologically active conveyor of sediment carbon that recharges degraded organic carbon back to surface streams. For example, fluvial sediment is estimated to lose 30% of its organic carbon by mass during a one year temporary residence within the phreatic karst. It is recommended that scientists consider karst pathways when attempting to estimate organic matter stocks

Karst Landscape, China

NASA Image and Video Library

2014-04-28

Karst topography is a geological formation shaped by the dissolution of layers of soluble rock such as limestone. A good example is found in Guangxi Province in southeast China, as seen by NASA Terra spacecraft.

Research approach to teaching groundwater biodegradation in karst aquifers

USGS Publications Warehouse

King, L.; Byl, T.; Painter, R.

2006-01-01

TSU in partnership with the USGS has conducted extensive research regarding biode??gradation of contaminants in karst aquifers. This research resulted in the development of a numerical approach to modeling biodegradation of contaminants in karst aquifers that is taught to environmental engineering students in several steps. First, environmental engineering students are taught chemical-reaction engineering principles relating to a wide variety of environmental fate and transport issues. Second, as part of TSU's engineering course curriculum, students use a non-ideal flow laboratory reactor system and run a tracer study to establish residence time distribution (RTD). Next, the students couple that formula to a first-order biodegradation rate and predict the removal of a biodegradable contaminant as a function of residence time. Following this, students are shown data collected from karst bedrock wells that suggest that karst aquifers are analogous to non-ideal flow reactors. The students are challenged to develop rates of biodegradation through lab studies and use their results to predict biodegradaton at an actual contaminated karst site. Field studies are also conducted to determine the accuracy of the students' predictions. This academic approach teaches biodegradation processes, rate-kinetic processes, hydraulic processes and numerical principles. The students are able to experience how chemical engineering principles can be applied to other situations, such as, modeling biodegradation of contaminants in karst aquifers. This paper provides background on the chemical engineering principles and karst issues used in the research-enhanced curriculum. ?? American Society for Engineering Education, 2006.

Existence of both culturable and viable but non culturable (VNC) E. coli populations with distinct settling velocities in karst aquifer

NASA Astrophysics Data System (ADS)

Petit, F.; Ratajczak, M.; Massei, N.; Lafite, R.; Clermont, O.; Denamur, E.; Berthe, T.

2012-12-01

associated to "non settleable" particles, decreased from the sinkhole to the spring. In contrast in dry period while the turbidity and the contamination by culturable E. coli is low, the three populations of viable, culturable and VNC E. coli are introduced in the karst. Within the population of culturable E. coli, persistent strains mainly belonging to B1 phylogroup and growing at 7°C were introduced in karst aquifer. At the spring, whatever the class of particles up to 96% of viable cells were in VNC state suggesting that a physiological change occurred within aquifer, independently of the association of E. coli with particles. At the well, the pumping of the water induced an input of resident VNC E. coli consecutively to a resuspension of particles previously settled within the karstic network, during a past turbid event.

Imaging of karsts on buried carbonate platform in Central Luconia Province, Malaysia

NASA Astrophysics Data System (ADS)

Nur Fathiyah Jamaludin, Siti; Mubin, Mukhriz; Latiff, Abdul Halim Abdul

2017-10-01

Imaging of carbonate rocks in the subsurface through seismic method is always challenging due to its heterogeneity and fast velocity compared to the other rock types. Existence of karsts features on the carbonate rocks make it more complicated to interpret the reflectors. Utilization of modern interpretation software such as PETREL and GeoTeric® to image the karsts morphology make it possible to model the karst network within the buried carbonate platform used in this study. Using combination of different seismic attributes such as Variance, Conformance, Continuity, Amplitude, Frequency and Edge attributes, we are able to image the karsts features that are available in the proven gas-field in Central Luconia Province, Malaysia. The mentioned attributes are excellent in visualize and image the stratigraphic features based on the difference in their acoustic impedance as well as structural features, which include karst. 2D & 3D Karst Models were developed to give a better understanding on the characteristics of the identified karsts. From the models, it is found that the karsts are concentrated in the top part of the carbonate reservoir (epikarst) and the middle layer with some of them becomes extensive and create karst networks, either laterally or vertically. Most of the vertical network karst are related to the existence of faults that displaced all the horizons in the carbonate platform.

A one-dimensional heat-transport model for conduit flow in karst aquifers

USGS Publications Warehouse

Long, Andrew J.; Gilcrease, P.C.

2009-01-01

A one-dimensional heat-transport model for conduit flow in karst aquifers is presented as an alternative to two or three-dimensional distributed-parameter models, which are data intensive and require knowledge of conduit locations. This model can be applied for cases where water temperature in a well or spring receives all or part of its water from a phreatic conduit. Heat transport in the conduit is simulated by using a physically-based heat-transport equation that accounts for inflow of diffuse flow from smaller openings and fissures in the surrounding aquifer during periods of low recharge. Additional diffuse flow that is within the zone of influence of the well or spring but has not interacted with the conduit is accounted for with a binary mixing equation to proportion these different water sources. The estimation of this proportion through inverse modeling is useful for the assessment of contaminant vulnerability and well-head or spring protection. The model was applied to 7 months of continuous temperature data for a sinking stream that recharges a conduit and a pumped well open to the Madison aquifer in western South Dakota. The simulated conduit-flow fraction to the well ranged from 2% to 31% of total flow, and simulated conduit velocity ranged from 44 to 353 m/d.

Hydrologic connections and dynamics of water movement in the classical Karst (Kras) Aquifer: evidence from frequent chemical and stable isotope sampling

USGS Publications Warehouse

Doctor, Daniel H.

2008-01-01

A review of past research on the hydrogeology of the Classical Karst (Kras) region and new information obtained from a two- year study using environmental tracers are presented in this paper. The main problems addressed are 1) the sources of water to the Kras aquifer resurgence zone-including the famous Timavo springs-under changing flow regimes; 2) a quantification of the storage volumes of the karst massif corresponding to flow regimes defined by hydrograph recessions of the Timavo springs; and 3) changing dynamics between deep phreatic conduit flow and shallow phreatic and epiphreatic storage within the aquifer resurgence zone as determined through changes in chemical and isotopic composition at springs and wells. Particular focus was placed on addressing the long-standing question of the influence of the Soca River on the ground waters of the aquifer resurgence zone. The results indicate that the alluvial aquifer supplied by the sinking of the Soca River on the northwestern edge of the massif contributes approximately 75% of the mean annual outflow to the smaller springs of the aquifer resurgence zone, and as much as 53% to the mean annual outflow of the Timavo springs. As a whole, the Soca River is estimated to contribute 56% of the average outflow of the Kras aquifer resurgence. The proportions of Soca River water increase under drier conditions, and decrease under wetter conditions. Time series analysis of oxygen stable isotope records indicate that the transit time of Soca River water to the Timavo springs, Sardos spring, and well B-4 is on the order of 1-2 months, depending on hydrological conditions. The total baseflow storage of the Timavo springs is estimated to be 518 million m3, and represents 88.5% of the storage capacity estimated for all flow regimes of the springs. The ratio of baseflow storage volume to the average annual volume discharged at the Timavo springs is 0.54. The Reka River sinking in Slovenia supplies substantial allogenic recharge to

Challenges of using electrical resistivity method to locate karst conduits-A field case in the Inner Bluegrass Region, Kentucky

USGS Publications Warehouse

Zhu, J.; Currens, J.C.; Dinger, J.S.

2011-01-01

Conduits serve as major pathways for groundwater flow in karst aquifers. Locating them from the surface, however, is one of the most challenging tasks in karst research. Geophysical methods are often deployed to help locate voids by mapping variations of physical properties of the subsurface. Conduits can cause significant contrasts of some physical properties that can be detected; other subsurface features such as water-bearing fractures often yield similar contrasts, which are difficult to distinguish from the effects of the conduits. This study used electrical resistivity method to search for an unmapped karst conduit that recharges Royal Spring in the Inner Bluegrass karst region, Kentucky, USA. Three types of resistivity techniques (surface 2D survey, quasi-3D survey, and time-lapse survey) were used to map and characterize resistivity anomalies. Some of the major anomalies were selected as drilling targets to verify the existence of the conduits. Drilling near an anomaly identified by an electrical resistivity profile resulted in successful penetration of a major water-filled conduit. The drilling results also suggest that, in this study area, low resistivity anomalies in general are associated with water-bearing features. However, differences in the anomaly signals between the water-filled conduit and other water-bearing features such as water-filled fracture zones were undistinguishable. The electrical resistivity method is useful in conduit detection by providing potential drilling targets. Knowledge of geology and hydrogeology about the site and professional judgment also played important roles in locating the major conduit. ?? 2011 Elsevier B.V.

The current status of mapping karst areas and availability of public sinkhole-risk resources in karst terrains of the United States

USGS Publications Warehouse

Kuniansky, Eve L.; Weary, David J.; Kaufmann, James E.

2016-01-01

Subsidence from sinkhole collapse is a common occurrence in areas underlain by water-soluble rocks such as carbonate and evaporite rocks, typical of karst terrain. Almost all 50 States within the United States (excluding Delaware and Rhode Island) have karst areas, with sinkhole damage highest in Florida, Texas, Alabama, Missouri, Kentucky, Tennessee, and Pennsylvania. A conservative estimate of losses to all types of ground subsidence was $125 million per year in 1997. This estimate may now be low, as review of cost reports from the last 15 years indicates that the cost of karst collapses in the United States averages more than $300 million per year. Knowing when a catastrophic event will occur is not possible; however, understanding where such occurrences are likely is possible. The US Geological Survey has developed and maintains national-scale maps of karst areas and areas prone to sinkhole formation. Several States provide additional resources for their citizens; Alabama, Colorado, Florida, Indiana, Iowa, Kentucky, Minnesota, Missouri, Ohio, and Pennsylvania maintain databases of sinkholes or karst features, with Florida, Kentucky, Missouri, and Ohio providing sinkhole reporting mechanisms for the public.

The current status of mapping karst areas and availability of public sinkhole-risk resources in karst terrains of the United States

NASA Astrophysics Data System (ADS)

Kuniansky, Eve L.; Weary, David J.; Kaufmann, James E.

2016-05-01

Subsidence from sinkhole collapse is a common occurrence in areas underlain by water-soluble rocks such as carbonate and evaporite rocks, typical of karst terrain. Almost all 50 States within the United States (excluding Delaware and Rhode Island) have karst areas, with sinkhole damage highest in Florida, Texas, Alabama, Missouri, Kentucky, Tennessee, and Pennsylvania. A conservative estimate of losses to all types of ground subsidence was 125 million per year in 1997. This estimate may now be low, as review of cost reports from the last 15 years indicates that the cost of karst collapses in the United States averages more than 300 million per year. Knowing when a catastrophic event will occur is not possible; however, understanding where such occurrences are likely is possible. The US Geological Survey has developed and maintains national-scale maps of karst areas and areas prone to sinkhole formation. Several States provide additional resources for their citizens; Alabama, Colorado, Florida, Indiana, Iowa, Kentucky, Minnesota, Missouri, Ohio, and Pennsylvania maintain databases of sinkholes or karst features, with Florida, Kentucky, Missouri, and Ohio providing sinkhole reporting mechanisms for the public.

Estimation of transit times in a Karst Aquifer system using environmental tracers: Application on the Jeita Aquifer system-Lebanon.

NASA Astrophysics Data System (ADS)

Doummar, Joanna; Hamdan, Ahmad

2016-04-01

Estimating transit times is essential for the assessment of aquifer vulnerability to contaminants. Groundwater in karst aquifer is assumed to be relatively young due to fast preferential pathways; slow flow components are present in water stored in the fissured matrix. Furthermore, transit times are site specific as they depend on recharge rates, temperatures, elevation, and flow media; saturated and unsaturated zones. These differences create significant variation in the groundwater age in karst systems as the water sampled will be a mix of different water that has been transported through different flow pathways (fissured matrix and conduits). Several methods can be applied to estimate water transit time of an aquifer such as artificial tracers, which provide an estimate for fast flow velocities. In this study, groundwater residence times in the Jeita spring aquifer (Lebanon) were estimated using several environmental tracers such as Chlorofluorocarbons (CFCs), Sulfur Hexafluoride (SF6), Helium-Tritium (3H, 3H- 3He). Additional stable isotope and major ion analysis was performed to characterize water types. Groundwater samples were collected from six different wells in the Jeita catchment area (Jurassic Kesrouane aquifer) as well as from the spring and cave itself. The results are reproducible for the Tritium-Helium method, unlike for the CFC/SF6 methods that yielded poor results due to sampling problems. Tritium concentrations in all groundwater samples show nearly the same concentration (~2.73 TU) except for one sample with relatively lower tritium concentration (~2.26 TU). Ages ranging from 0.07 ± 0.07 years to 23.59 ± 0.00 years were obtained. The youngest age is attributed to the spring/ cave while the oldest ages were obtained in wells tapping the fissured matrix. Neon in these samples showed considerable variations and high delta Ne in some samples indicating high excess air. Four (4) samples showed extreme excess air (Delta-Ne is greater than 70 %) and

Karst mapping in the United States: Past, present and future

USGS Publications Warehouse

Weary, David J.; Doctor, Daniel H.

2015-01-01

The earliest known comprehensive karst map of the entire USA was published by Stringfield and LeGrand (1969), based on compilations of William E. Davies of the U.S. Geological Survey (USGS). Various versions of essentially the same map have been published since. The USGS recently published new digital maps and databases depicting the extent of known karst, potential karst, and pseudokarst areas of the United States of America including Puerto Rico and the U.S. Virgin Islands (Weary and Doctor, 2014). These maps are based primarily on the extent of potentially karstic soluble rock types, and rocks with physical properties conducive to the formation of pseudokarst features. These data were compiled and refined from multiple sources at various spatial resolutions, mostly as digital data supplied by state geological surveys. The database includes polygons delineating areas with potential for karst and that are tagged with attributes intended to facilitate classification of karst regions. Approximately 18% of the surface of the fifty United States is underlain by significantly soluble bedrock. In the eastern United States the extent of outcrop of soluble rocks provides a good first-approximation of the distribution of karst and potential karst areas. In the arid western states, the extent of soluble rock outcrop tends to overestimate the extent of regions that might be considered as karst under current climatic conditions, but the new dataset encompasses those regions nonetheless. This database will be revised as needed, and the present map will be updated as new information is incorporated.

The role of sandstone in the development of an Ozark karst system, south-central Missouri

USGS Publications Warehouse

Orndorff, R.C.; Weary, D.J.; Harrison, R.W.

2006-01-01

Cave, spring, and sinkhole development in the Ozarks of south-central Missouri is placed in a geologic framework through detailed geologic mapping. Geologic mapping shows that initial dissolution and inception of cave development is concentrated just beneath sandstone beds within Upper Cambrian and Lower Ordovician dolostone. Although rocks of the Ozarks have systematic and pervasive vertical joints, the development of karst conduits is controlled by bedding planes and stratigraphic variability. In the Salem Plateau of south-central Missouri, sinkholes occur in the lower part of the Ordovician Roubidoux Formation, where sinkholes are rimmed with and contain sandstone that has collapsed into voids in the underlying Ordovician Gasconade Dolomite. Cave diving by the Ozark Cave Diving Alliance into Alley Spring, a large (average flow 3.7 m3/s) spring along the Jacks Fork in the Ozark National Scenic Riverways, shows that although the spring discharges from the middle part of the Gasconade, the source of water is a cave passage just beneath the Gunter Sandstone Member of the Gasconade Dolomite. Artesian conditions cause the upward movement of groundwater from cavernous dolostone beneath the sandstone aquitards to the large springs. We hypothesize that sandstone, which is largely impermeable due to silica cementation, acts as a confining unit where hydraulic pressure, combined with mixing of water of differing chemistry, increases dissolution in the underlying dolostone beds. ?? 2006 Geological Society of America.

Residence times and age distributions of spring waters at the Semmering catchment area, Eastern Austria, as inferred from tritium, CFCs and stable isotopes.

PubMed

Han, Liangfeng; Hacker, Peter; Gröning, Manfred

2007-03-01

The groundwater system in the mountainous area of Semmering, Austria, was studied by environmental tracers in several karst springs. The tracers used included stable isotopes ((18)O, (2)H), tritium ((3)H) and chlorofluorocarbons (CFCs). The tracers provided valuable information in regard to (1) the mean altitude of the spring catchment areas; (2) the residence time and age distribution of the spring waters; and (3) the interconnection of the springs to a sinkhole. The combination of the stable isotopic data and the topography/geology provided the estimates of the mean altitudes of the catchment areas. Based on the stable isotopic data the recharge temperature of the spring waters was estimated. The smoothing of precipitation's isotopic signal in spring discharge provided information on the minimum transit time of the spring waters. Due to short observation time, (3)H data alone cannot be used for describing the mean residence time of the karst waters. CFCs, though useful in recognizing the co-existence of young (post-1993) water with old (CFC-free) water, could not be used to resolve age distribution models. It is shown in this article, however, that the combined use of tritium and CFCs can provide a better assessment of models to account for different groundwater age distributions. In Appendix A, a simplified method for collecting groundwater samples for the analysis of CFCs is described. The method provides a real facilitation for fieldwork. Test data are given for this sampling method in regard to potential contamination by atmospheric CFCs.

The spectral absorption coefficient at 254 nm as a real-time early warning proxy for detecting faecal pollution events at alpine karst water resources.

PubMed

Stadler, H; Klock, E; Skritek, P; Mach, R L; Zerobin, W; Farnleitner, A H

2010-01-01

Because spring water quality from alpine karst aquifers can change very rapidly during event situations, water abstraction management has to be performed in near real-time. Four summer events (2005-2008) at alpine karst springs were investigated in detail in order to evaluate the spectral absorption coefficient at 254 nm (SAC254) as a real-time early warning proxy for faecal pollution. For the investigation Low-Earth-Orbit (LEO) Satellite-based data communication between portable hydrometeorological measuring stations and an automated microbiological sampling device was used. The method for event triggered microbial sampling and analyzing was already established and described in a previous paper. Data analysis including on-line event characterisation (i.e. precipitation, discharge, turbidity, SAC254) and comprehensive E. coli determination (n>800) indicated that SAC254 is a useful early warning proxy. Irrespective of the studied event situations SAC254 always increased 3 to 6 hours earlier than the onset of faecal pollution, featuring different correlation phases. Furthermore, it seems also possible to use SAC254 as a real-time proxy parameter for estimating the extent of faecal pollution after establishing specific spring and event-type calibrations that take into consideration the variability of the occurrence and the transferability of faecal material It should be highlighted that diffuse faecal pollution from wildlife and live stock sources was responsible for spring water contamination at the investigated catchments. In this respect, the SAC254 can also provide useful information to support microbial source tracking efforts where different situations of infiltration have to be investigated.

New Electrical Resistivity Tomography approach for karst cave characterization: Castello di Lepre karst cave (Marsico Nuovo, Southern Italy).

NASA Astrophysics Data System (ADS)

Guerriero, Merilisa; Capozzoli, Luigi; De Martino, Gregory; Perciante, Felice; Gueguen, Erwan; Rizzo, Enzo

2017-04-01

Geophysical methods are commonly applied to characterize karst cave. Several geophysical method are used such as electrical resistivity tomography (ERT), gravimetric prospecting (G), ground penetrating radar (GPR) and seismic methods (S), in order to provide information on cave geometry and subsurface geological structure. In detail, in some complex karst systems, each geophysical method can only give partial information if used in normal way due to a low resolution for deep target. In order to reduce uncertainty and avoid misinterpretations based on a normal use of the electrical resistivity tomography method, a new ERT approach has been applied in karst cave Castello di Lepre (Marsico Nuovo, Basilicata region, Italy) located in the Mezo-Cenozoic carbonate substratum of the Monti della Maddalena ridge (Southern Appenines). In detail, a cross-ERT acquisition system was applied in order to improve the resolution on the electrical resistivity distribution on the surrounding geological structure of a karst cave. The cross-ERT system provides a more uniform model resolution vertically, increasing the resolution of the surface resistivity imaging. The usual cross-ERT is made by electrode setting in two or more borehole in order to acquire the resistivity data distribution. In this work the cross-ERT was made between the electrodes located on surface and along a karst cave, in order to obtain an high resolution of the electrical resistivity distributed between the cave and the surface topography. Finally, the acquired cross-ERT is potentially well-suited for imaging fracture zones since electrical current flow in fractured rock is primarily electrolytic via the secondary porosity associated with the fractures.

Turbidity forecasting at a karst spring using combined machine learning and wavelet multiresolution analysis.

NASA Astrophysics Data System (ADS)

Savary, M.; Massei, N.; Johannet, A.; Dupont, J. P.; Hauchard, E.

2016-12-01

25% of the world populations drink water extracted from karst aquifer. The comprehension and the protection of these aquifers appear as crucial due to an increase of drinking water needs. In Normandie(North-West of France), the principal exploited aquifer is the chalk aquifer. The chalk aquifer highly karstified is an important water resource, regionally speaking. Connections between surface and underground waters thanks to karstification imply turbidity that decreases water quality. Both numerous parameters and phenomenons, and the non-linearity of the rainfall/turbidity relation influence the turbidity causing difficulties to model and forecast turbidity peaks. In this context, the Yport pumping well provides half of Le Havreconurbation drinking water supply (236 000 inhabitants). The aim of this work is thus to perform prediction of the turbidity peaks in order to help pumping well managers to decrease the impact of turbidity on water treatment. Database consists in hourly rainfalls coming from six rain gauges located on the alimentation basin since 2009 and hourly turbidity since 1993. Because of the lack of accurate physical description of the karst system and its surface basin, the systemic paradigm is chosen and a black box model: a neural network model is chosen. In a first step, correlation analyses are used to design the original model architecture by identifying the relation between output and input. The following optimization phases bring us four different architectures. These models were experimented to forecast 12h ahead turbidity and threshold surpassing. The first model is a simple multilayer perceptron. The second is a two-branches model designed to better represent the fast (rainfall) and low (evapotranspiration) dynamics. Each kind of model is developed using both a recurrent and feed-forward architecture. This work highlights that feed-forward multilayer perceptron is better to predict turbidity peaks when feed-forward two-branches model is

Karst groundwater: a challenge for new resources

NASA Astrophysics Data System (ADS)

Bakalowicz, Michel

2005-03-01

Karst aquifers have complex and original characteristics which make them very different from other aquifers: high heterogeneity created and organised by groundwater flow; large voids, high flow velocities up to several hundreds of m/h, high flow rate springs up to some tens of m3/s. Different conceptual models, known from the literature, attempt to take into account all these particularities. The study methods used in classical hydrogeology—bore hole, pumping test and distributed models—are generally invalid and unsuccessful in karst aquifers, because the results cannot be extended to the whole aquifer nor to some parts, as is done in non-karst aquifers. Presently, karst hydrogeologists use a specific investigation methodology (described here), which is comparable to that used in surface hydrology. Important points remain unsolved. Some of them are related to fundamental aspects suc h as the void structure - only a conduit network, or a conduit network plus a porous matrix -, the functioning - threshold effects and non-linearities -, the modeling of the functioning - double or triple porosity, or viscous flow in conduits - and of karst genesis. Some other points deal with practical aspects, such as the assessment of aquifer storage capacity or vulnerability, or the prediction of the location of highly productive zones. Los acuíferos kársticos tienen características originales y complejas que los hacen muy diferentes de otros acuíferos: alta heterogeneidad creada y organizada por el flujo de agua subterránea, espacios grandes, velocidades altas de flujo de hasta varios cientos de m/h, manantiales con ritmo alto de flujo de hasta algunas decenas de m3/s. Diferentes modelos conceptuales que se conocen en la literatura tratan de tomar en cuenta todas estas particularidades. Los métodos de estudio usados en hidrogeología clásica- pozos, pruebas de bombeo y modelos distribuidos- son generalmente inválidos y no exitosos en acu

Use of chemical and isotopic tracers to assess nitrate contamination and ground-water age, Woodville Karst Plain, USA

USGS Publications Warehouse

Katz, B.G.; Chelette, A.R.; Pratt, T.R.

2004-01-01

Concerns regarding ground-water contamination in the Woodville Karst Plain have arisen due to a steady increase in nitrate-N concentrations (0.25-0.90 mg/l) during the past 30 years in Wakulla Springs, a large regional discharge point for water (9.6 m3/s) from the Upper Floridan aquifer (UFA). Multiple isotopic and chemical tracers were used with geochemical and lumped-parameter models (exponential mixing (EM), dispersion, and combined exponential piston flow) to assess: (1) the sources and extent of nitrate contamination of ground water and springs, and (2) mean transit times (ages) of ground water. Delta 15N-NO3 values (1.7-13.8???) indicated that nitrate in ground water originated from localized sources of inorganic fertilizer and human/animal wastes. Nitrate in spring waters (??15N-NO3=5.3-8.9???) originated from both inorganic and organic N sources. Nitrate-N concentrations (1.0 mg/l) were associated with shallow wells (open intervals less than 15 m below land surface), elevated nitrate concentrations in deeper wells are consistent with mixtures of water from shallow and deep zones in the UFA as indicated from geochemical mixing models and the distribution of mean transit times (5-90 years) estimated using lumped-parameter flow models. Ground water with mean transit times of 10 years or less tended to have higher dissolved organic carbon concentrations, lower dissolved solids, and lower calcite saturation indices than older waters, indicating mixing with nearby surface water that directly recharges the aquifer through sinkholes. Significantly higher values of pH, magnesium, dolomite saturation index, and phosphate in springs and deep water (>45 m) relative to a shallow zone (<45 m) were associated with longer ground-water transit times (50-90 years). Chemical differences with depth in the aquifer result from deep regional flow of water recharged through low permeability sediments (clays and clayey sands of the Hawthorn Formation) that overlie the UFA

Geochemical and isotopic characterization of groundwater origins in a Mediterranean karst system (southern France)

NASA Astrophysics Data System (ADS)

Seidel, J. L.; Ladouche, B.; Batiot-Guilhe, C.

2013-12-01

Geochemical and isotopic ratio (11B/10B and 87Sr/86Sr) results are reported for better determining the groundwater origins in the Lez Karst system (southern France). The Lez spring is the main perennial outlet of the system and supplies with drinking water the metropolitan area of Montpellier. According to the hydrodynamic conditions, five water-types discharge at the Lez spring with important mineralization fluctuations (Caetano Bicalho et al., 2012). This geochemical response suggests that hydrodynamics targets groundwater circulation, resulting from different water end-member solicitation and mixing. Previous studies using conventional natural tracers do not succeed to identify all the water compartments supporting the flow during the hydrologic cycle (Marjolet & Salado, 1977; Joseph et al., 1988) and to explain the mineralization variation of the Lez spring. The present study combines a basic geochemical survey data with boron and strontium isotope ratio data for a better characterization of the Lez spring geochemical functioning. Groundwater samples were collected at the Lez spring and surrounding springs and wells under different hydrologic conditions from 2009 to 2011. Major, trace and rare earth elements were determined at AETE analytical platform (OREME, Univ. Montpellier 2) by ionic chromatography and Q-ICP-MS respectively. d11B and 87Sr/86Sr were determined at BRGM/MMA Orleans by TIMS. The geochemical survey has been extended at a larger scale by sampling the main geochemical end- members already identified to replace the Lez spring waters in the regional geochemical context. From this geochemical study, valuable informations have been provided on the reservoir types and water origins flowing in high and low stage periods. For the highly mineralized waters occurring in the fall first rainy events or severe low stages, a deep contribution is highlighted but B and Sr isotopic data do not ascertain the two Triassic end-members (halite or gypsum) as possible

Treating tar sands formations with karsted zones

DOEpatents

Vinegar, Harold J.; Karanikas, John Michael

2010-03-09

Methods for treating a tar sands formation are described herein. The tar sands formation may have one or more karsted zones. Methods may include providing heat from one or more heaters to one or more karsted zones of the tar sands formation to mobilize fluids in the formation. At least some of the mobilized fluids may be produced from the formation.

Carbon cycling in the mantled karst of the Ozark Plateaus, central United States

USGS Publications Warehouse

Knierim, Katherine J.; Pollock, Erik D.; Covington, Matthew D.; Hays, Phillip D.; Brye, Kristofor R.

2017-01-01

The nature of carbon (C) cycling in the unsaturated zone where groundwater is in contact with abundant gas-filled voids is poorly understood. The objective of this study was to trace inorganic-C cycling in a karst landscape using stable-C isotopes, with emphasis on a shallow groundwater flow path through the soil, to an underlying cave, and to the spring outlet of a cave stream in the Ozark Plateaus of northwestern Arkansas. Carbon dioxide (CO2) concentration and isotopic composition (δ13C-CO2) in gas and dissolved inorganic carbon (DIC) concentration and isotopic composition (δ13C-DIC) in water were measured in samples collected from two suction-cup soil samplers above the cave, three sites in the cave, and at the spring outlet of the cave stream. Soil-gas CO2 concentration (median 2,578 ppm) and δ13C-CO2 (median − 21.5‰) were seasonally variable, reflecting the effects of surface temperature changes on soil-CO2 production via respiration and organic-matter decomposition. Cave-air CO2 (median 1,026 ppm) was sourced from the soil zone and the surface atmosphere, with seasonally changing proportions of each source controlled by surface temperature-driven air density gradients. Soil-DIC concentration (median 1.7 mg L− 1) was lower and soil-δ13C-DIC (median − 19.5‰) was lighter compared to the cave (median 23.3 mg L− 1 and − 14.3‰, respectively) because carbonate-bedrock dissolution provided an inorganic source of C to the cave. Carbon species in the soil had a unique, light stable-C isotopic signature compared to the cave. Discrimination of soil-C sources to karst groundwater was achieved, which is critical for developing hydrologic budgets using environmental tracers such as C.

Using MODFLOW with CFP to understand conduit-matrix exchange in a karst aquifer during flooding

NASA Astrophysics Data System (ADS)

Spellman, P.; Screaton, E.; Martin, J. B.; Gulley, J.; Brown, A.

2011-12-01

Karst springs may reverse flow when allogenic runoff increases river stage faster than groundwater heads and may exchange of surface water with groundwater in the surrounding aquifer matrix. Recharged flood water is rich in nutrients, metals, and organic matter and is undersaturated with respect to calcite. Understanding the physical processes controlling this exchange of water is critical to understanding metal cycling, redox chemistry and dissolution in the subsurface. Ultimately the magnitude of conduit-matrix exchange should be governed by head gradients between the conduit and the aquifer which are affected by the hydraulic conductivity of the matrix, conduit properties and antecedent groundwater heads. These parameters are interrelated and it is unknown which ones exert the greatest control over the magnitude of exchange. This study uses MODFLOW-2005 coupled with the Conduit Flow Processes (CFP) package to determine how physical properties of conduits and aquifers influence the magnitude of surface water-groundwater exchange. We use hydraulic data collected during spring reversals in a mapped underwater cave that sources Madison Blue Spring in north-central Florida to explore which factors are most important in governing exchange. The simulation focused on a major flood in 2009, when river stage increased by about 10 meters over 9 days. In a series of simulations, we varied hydraulic conductivity, conduit diameter, roughness height and tortuosity in addition to antecedent groundwater heads to estimate the relative effects of each parameter on the magnitude of conduit-matrix exchange. Each parameter was varied across plausible ranges for karst aquifers. Antecedent groundwater heads were varied using well data recorded through wet and dry seasons throughout the spring shed. We found hydraulic conductivity was the most important factor governing exchange. The volume of exchange increased by about 61% from the lowest value (1.8x10-6 m/d) to the highest value (6 m

Study on Karst Information Identification of Qiandongnan Prefecture Based on RS and GIS Technology

NASA Astrophysics Data System (ADS)

Yao, M.; Zhou, G.; Wang, W.; Wu, Z.; Huang, Y.; Huang, X.

2018-04-01

Karst area is a pure natural resource base, at the same time, due to the special geological environment; there are droughts and floods alternating with frequent karst collapse, rocky desertification and other resource and environment problems, which seriously restrict the sustainable economic and social development in karst areas. Therefore, this paper identifies and studies the karst, and clarifies the distribution of karst. Provide basic data for the rational development of resources in the karst region and the governance of desertification. Due to the uniqueness of the karst landscape, it can't be directly recognized and extracted by computer in remote sensing images. Therefore, this paper uses the idea of "RS + DEM" to solve the above problems. this article is based on Landsat-5 TM imagery in 2010 and DEM data, proposes the methods to identify karst information research what is use of slope vector diagram, vegetation distribution map, distribution map of karst rocky desertification and other auxiliary data in combination with the signs for human-computer interaction interpretation, identification and extraction of peak forest, peaks cluster and isolated peaks, and further extraction of karst depression. Experiments show that this method achieves the "RS + DEM" mode through the reasonable combination of remote sensing images and DEM data. It not only effectively extracts karst areas covered with vegetation, but also quickly and accurately locks down the karst area and greatly improves the efficiency and precision of visual interpretation. The accurate interpretation rate of karst information in study area in this paper is 86.73 %.

Interregional comparison of karst disturbance: west-central Florida and southeast Italy.

PubMed

North, Leslie A; van Beynen, Philip E; Parise, Mario

2009-04-01

The karst disturbance index (KDI) consists of 31 environmental indicators contained within the five broad categories: geomorphology, hydrology, atmosphere, biota, and cultural. The purpose of this research is to apply the KDI to two distinct karst areas, west Florida, USA, and Apulia, Italy. Through its application, the utility of the index can be validated and other important comparisons can be made, such as differences in the karst legislations implemented in each region and the effect of time exposure to human occupation to each karst terrain. Humans have intensively impacted the karst of southeast Italy for thousands of years compared to only decades in west-central Florida. However, west-central Florida's higher population density allows the region to reach disturbance levels comparable to those reached over a longer period in Apulia. Similarly, Italian karst is more diverse than the karst found in west-central Florida, creating an opportunity to test all the KDI indicators. Overall, major disturbances for southeast Italy karst include quarrying, stone clearing, and the dumping of refuse into caves, while west-central Florida suffers most from the infilling of sinkholes, soil compaction, changes in the water table, and vegetation removal. The application of the KDI allows a benchmark of disturbance to be established and later revisited to determine the changing state of human impact for a region. The highlighting of certain indicators that recorded high levels of disturbance also allows regional planners to allocate resources in a more refined manner.

Quantifying the magnitude and spatiotemporal variation of aquatic CO2 fluxes in a sub-tropical karst catchment, Southwest China

NASA Astrophysics Data System (ADS)

Ding, Hu; Waldron, Susan; Newton, Jason; Garnett, Mark H.

2017-04-01

The role played by rivers in regional and global C budgets is receiving increasing attention. A large portion of the carbon transported via inland waters is returned to the atmosphere by carbon dioxide evasion from rivers and lakes. Karst landscapes represent an important C store on land, and are also considered to play an important role in climate regulation by consuming atmospheric CO2 during chemical weathering. However, we cannot be certain how effective this sink is if we do not know how efficiently the rivers draining karst landscapes remobilise weathered C to the atmosphere as CO2. pCO2 in karst waters is generally greater than atmospheric equilibrium, indicating that there can be a net CO2 efflux to the atmosphere. However, measurement confirming this and quantifying flux rates has been rarely conducted. Using a floating chamber method, in 2016 we directly measured CO2 fluxes from spatially distributed freshwaters (springs, sinkholes, streams and reservoirs/ponds) in the Houzhai Catchment, a karst region in SW China. Fluxes ranged from -0.5 to +267.4 μmol CO2 m-2s-1, and most sites showed seasonal variations with higher CO2 efflux rates in the wet (April - September) than dry season (October - March). There was a significant positive relationship between CO2 efflux and flow velocity, indicating that hydraulic controls on CO2 efflux from flowing water are important, while for water with little movement (sinkholes and reservoirs/ponds), pCO2 appears a more important control on efflux rates. Conditions similar to this study area may exist in many sub-tropical rivers that drain karst landscapes in South China. These waters are rich in DIC which can be an order of magnitude greater than some non-karst catchments. The large DIC pool has the potential to be a considerable source of free CO2 to the atmosphere. Considering that carbonate lithology covers a significant part of the Earth's surface, CO2 evasion in fluvial water from these regions is expected to

Low-temperature magnetothermal transport investigation of a Ni-based superconductor BaNi2As2: evidence for fully gapped superconductivity.

PubMed

Kurita, N; Ronning, F; Tokiwa, Y; Bauer, E D; Subedi, A; Singh, D J; Thompson, J D; Movshovich, R

2009-04-10

We have performed low-temperature specific heat and thermal conductivity measurements of the Ni-based superconductor BaNi2As2 (T{c}=0.7 K) in a magnetic field. In a zero field, thermal conductivity shows T-linear behavior in the normal state and exhibits a BCS-like exponential decrease below T{c}. The field dependence of the residual thermal conductivity extrapolated to zero temperature is indicative of a fully gapped superconductor. This conclusion is supported by the analysis of the specific heat data, which are well fit by the BCS temperature dependence from T{c} down to the lowest temperature of 0.1 K.

Preliminary characterization of an alpine karst aquifer in a complex geological setting using the KARSYS approach. Picos de Europa, North Spain

NASA Astrophysics Data System (ADS)

Ballesteros, Daniel; Malard, Arnauld; Jeannin, Pierre-Yves; Jiménez-Sánchez, Montserrat; García-Sansegundo, Joaquín; Meléndez, Mónica; Sendra, Gemma

2013-04-01

Research applied to karst aquifers linked to a homogeneous limestone in high mountain areas affected by several tectonic events is a hard task, due to methodological constraints and the uncertainties of the geological data. The KARSYS approach (Jeannin et al. 2012) is based on the combination of existing geological data and basic principles of karst hydraulic, allowing for characterizing the geometry of an aquifer considering a smaller amount of data than other methods. The Picos de Europa (North Spain) is an alpine karst massif with a surface area of 700 km2, peaks up to 2,648 m and fluvial gorges up to 2,000 m deep, including about 270 km of cave passage. The bedrock is mainly composed of Ordovician quartzite covered by massive Carboniferous limestone and is affected by two systems of thrusts and other faults. The most of the geological structures are from Variscan orogeny (Carboniferous in age), some of them could be originated or modified during the Permian-Mesozoic extensional episode, and the others were originated or reactivated during the Alpine Orogeny. Therefore, the Picos de Europa can be considered as a complex geological environment in which usual hydrogeological methods are difficult to use. The aim of this study is to characterize the geometry of the Picos de Europa aquifers applying the KARSYS approach. The approach includes: 1) the identification of aquifer and aquiclude formations; 2) the inventory of the main springs; 3) the establishment of a 3D geological model, focused on the aquifer boundaries; 4) the implementation of the hydraulic features within the 3D model and the delineation of the karst system. The main aquifer of the Picos de Europa is developed within the Carboniferous limestone and displays a complex geometry generally limited and divided into several unconfined groundwater bodies by Ordovician to Carboniferous rocks related to the thrusts. The lowest limit of the aquifer is marked by the N-dipping detachment level of the thrusts

Correlation of Spatio-Temporal Contaminant Distribution, Land Use, and Hydrogeological Factors in the Karst Aquifers of Northern Puerto Rico

NASA Astrophysics Data System (ADS)

Torres Torres, N. I.; Padilla, I. Y.

2015-12-01

Karst aquifers are characterized by caves, springs, and sinkholes, and typified by interconnected fissures, fractures and conduits. These characteristics make these aquifers highly productive, and vulnerable to contamination. Previous studies in the northern karst aquifers of Puerto Rico have shown significant distribution of contaminants, including volatile organic compounds, phthalates and other contaminants of emerging concern, beyond demarked sources of contamination. This study develops spatial-temporal distributions of phthalate contaminants in the karst system of northern Puerto Rico and assesses statistical correlations between hydrogeologic factors and groundwater contamination with phthalates. Geographic Information Systems (GIS) tools and technologies, and statistical models are applied to attain these objectives. Results show that there is an extensive contamination with phthalates that varies with time. Contamination is present in the confined and shallow aquifers. Di-(2-ethylhexyl) phthalate (DEHP) is the most detected contaminant (20.6% of the sites). Diethyl phthalate and and dibutyl phthalate are also detected in 6.7% and 8.24% of the sites, respectively. Phthalates detected as mixtures components are significantly detected in areas of high urban and industrial development. They are also detected in areas within 5 miles of superfund sites and landfills. The results indicate that phthalate contamination is highly related to land use. Statistical models show that the hydraulic conductivity of the aquifers, sinkholes density, and time are significantly related to the presence of phthalates in groundwater. The extensive spatio-temporal contamination suggests that contaminants can persist in the environment for long periods of time, and that land use and hydrogeological factors are important factors contributing to the presence of emerging contaminants in karst systems.

Retrieving hydrological connectivity from empirical causality in karst systems

NASA Astrophysics Data System (ADS)

Delforge, Damien; Vanclooster, Marnik; Van Camp, Michel; Poulain, Amaël; Watlet, Arnaud; Hallet, Vincent; Kaufmann, Olivier; Francis, Olivier

2017-04-01

Because of their complexity, karst systems exhibit nonlinear dynamics. Moreover, if one attempts to model a karst, the hidden behavior complicates the choice of the most suitable model. Therefore, both intense investigation methods and nonlinear data analysis are needed to reveal the underlying hydrological connectivity as a prior for a consistent physically based modelling approach. Convergent Cross Mapping (CCM), a recent method, promises to identify causal relationships between time series belonging to the same dynamical systems. The method is based on phase space reconstruction and is suitable for nonlinear dynamics. As an empirical causation detection method, it could be used to highlight the hidden complexity of a karst system by revealing its inner hydrological and dynamical connectivity. Hence, if one can link causal relationships to physical processes, the method should show great potential to support physically based model structure selection. We present the results of numerical experiments using karst model blocks combined in different structures to generate time series from actual rainfall series. CCM is applied between the time series to investigate if the empirical causation detection is consistent with the hydrological connectivity suggested by the karst model.

Karst topography : noninvasive geophysical detection methods and construction techniques.

DOT National Transportation Integrated Search

2013-10-01

The objective of this project was to investigate the current state of the practice with regards to karst detection : methods and current karst construction practices and to recommend the best practices for use by the Virginia : Department of Transpor...

Multitracer test for the determination of transport and in-situ degradation of organic micro-contaminants in karst aquifers on the example of caffeine

NASA Astrophysics Data System (ADS)

Hillebrand, O.; Nödler, K.; Licha, T.; Geyer, T.

2012-04-01

The application of organic micro-contaminants as indicators for contamination sources in aquifers and surface-water bodies has been increasingly discussed in the literature over the last years. One of the proposed substances was caffeine. It served as indicator for wastewater-leakage to various systems. As well, wastewater volumes could be estimated from caffeine concentrations. Although caffeine is known to be degradable, the degradation rates are normally only determined from mass balances or laboratory experiments. Degradation rates obtained from mass balances are relatively uncertain, as the input-function is difficult to be assessed. Laboratory experiments are hardly capable to consider the full complexity of natural systems and can rarely be transferred to those. To solve this problem, in-situ degradation rates of reactive indicators have to be determined. Especially multitracer tests can be used to access compound-specific transport parameters and degradation rates, relative to conservative tracers. A multitracer test with caffeine and uranine has been performed in a karst system (catchment of the Gallusquelle spring, SW Germany). From the breakthrough curves of the tracers, the transport behavior and the in-situ degradation rate of caffeine could be deduced. The tracers were injected into a sinkhole with a linear distance of 3000 m to the spring. The mean residence time of the tracers was found to be 84 h at a flow velocity of 35 m/h. Throughout the whole experiment, the spring discharge was constant at 187 L/s. Uranine served as conservative reference-tracer for the calibration of a one-dimensional transport model with respect to solute-unspecific parameters. Relative to that, the tracer breakthrough curve of caffeine was interpreted. As solute-specific parameters the retardation coefficient as well as degradation rate of caffeine in the investigated karst aquifer could be determined. The results indicate, that caffeine is slightly retarded in the

Contaminant transport in two central Missouri karst recharge areas

USDA-ARS?s Scientific Manuscript database

Karst watersheds with significant losing streams represent a particularly vulnerable setting for ground water contamination because of the direct connection to surface water. Because of the existing agricultural land-use and future threat of heavy urbanization, two losing stream karst basins were ch...

Contaminant transport in two central Missouri karst recharge areas

USDA-ARS?s Scientific Manuscript database

Karst watersheds with significant losing streams represent a particularly vulnerable setting for ground water contamination because of the direct connection to surface water. Because of the existing agricultural land-use and future likelihood of urbanization, two losing stream karst basins were chos...

Contaminant Transport in Two Central Missouri Karst Recharge Areas

USDA-ARS?s Scientific Manuscript database

Karst watersheds with significant losing streams represent a particularly vulnerable setting for ground water contamination because of the direct connection to surface water. Because of the existing agricultural land-use and future threat of heavy urbanization, two losing stream karst basins were ch...

Cansiglio Karst Plateau: 10 Years of Geodetic-Hydrological Observations in Seismically Active Northeast Italy

NASA Astrophysics Data System (ADS)

Grillo, Barbara; Braitenberg, Carla; Nagy, Ildikó; Devoti, Roberto; Zuliani, David; Fabris, Paolo

2018-04-01

Ten years' geodetic observations (2006-2016) in a natural cave of the Cansiglio Plateau (Bus de la Genziana), a limestone karstic area in northeastern Italy, are discussed. The area is of medium-high seismic risk: a strong earthquake in 1936 below the plateau (M m = 6.2) and the 1976 disastrous Friuli earthquake (M m = 6.5) are recent events. At the foothills of the karstic massif, three springs emerge, with average flow from 5 to 10 m3/s, and which are the sources of a river. The tiltmeter station is set in a natural cavity that is part of a karstic system. From March 2013, a multiparametric logger (temperature, stage, electrical conductivity) was installed in the siphon at the bottom of the cave to discover the underground hydrodynamics. The tilt records include signals induced by hydrologic and tectonic effects. The tiltmeter signals have a clear correlation to the rainfall, the discharge series of the river and the data recorded by multiparametric loggers. Additionally, the data of a permanent GPS station located on the southern slopes of the Cansiglio Massif (CANV) show also a clear correspondence with the river level. The fast water infiltration into the epikarst, closely related to daily rainfall, is distinguished in the tilt records from the characteristic time evolution of the karstic springs, which have an impulsive level increase with successive exponential decay. It demonstrates the usefulness of geodetic measurements to reveal the hydrological response of the karst. One outcome of the work is that the tiltmeters can be used as proxies for the presence of flow channels and the pressure that builds up due to the water flow. With 10 years of data, a new multidisciplinary frontier was opened between the geodetic studies and the karstic hydrogeology to obtain a more complete geologic description of the karst plateau.

Cansiglio Karst Plateau: 10 Years of Geodetic-Hydrological Observations in Seismically Active Northeast Italy

NASA Astrophysics Data System (ADS)

Grillo, Barbara; Braitenberg, Carla; Nagy, Ildikó; Devoti, Roberto; Zuliani, David; Fabris, Paolo

2018-05-01

Ten years' geodetic observations (2006-2016) in a natural cave of the Cansiglio Plateau (Bus de la Genziana), a limestone karstic area in northeastern Italy, are discussed. The area is of medium-high seismic risk: a strong earthquake in 1936 below the plateau ( M m = 6.2) and the 1976 disastrous Friuli earthquake ( M m = 6.5) are recent events. At the foothills of the karstic massif, three springs emerge, with average flow from 5 to 10 m3/s, and which are the sources of a river. The tiltmeter station is set in a natural cavity that is part of a karstic system. From March 2013, a multiparametric logger (temperature, stage, electrical conductivity) was installed in the siphon at the bottom of the cave to discover the underground hydrodynamics. The tilt records include signals induced by hydrologic and tectonic effects. The tiltmeter signals have a clear correlation to the rainfall, the discharge series of the river and the data recorded by multiparametric loggers. Additionally, the data of a permanent GPS station located on the southern slopes of the Cansiglio Massif (CANV) show also a clear correspondence with the river level. The fast water infiltration into the epikarst, closely related to daily rainfall, is distinguished in the tilt records from the characteristic time evolution of the karstic springs, which have an impulsive level increase with successive exponential decay. It demonstrates the usefulness of geodetic measurements to reveal the hydrological response of the karst. One outcome of the work is that the tiltmeters can be used as proxies for the presence of flow channels and the pressure that builds up due to the water flow. With 10 years of data, a new multidisciplinary frontier was opened between the geodetic studies and the karstic hydrogeology to obtain a more complete geologic description of the karst plateau.

Seasonal changes in Cyclobalanopsis glauca transpiration and canopy stomatal conductance and their dependence on subterranean water and climatic factors in rocky karst terrain

NASA Astrophysics Data System (ADS)

Huang, Yuqing; Li, Xiankun; Zhang, Zhongfeng; He, Chengxin; Zhao, Ping; You, Yeming; Mo, Ling

2011-05-01

SummaryThe presence of forest on south China karst is presumed to increase perennial epikarst spring flow, partly because there is adequate storage in bedrock fractures underlying the shallow soil in the forest. If true, transpiration of the ecosystem would not be strongly reduced by temperate drought if trees develop deep roots to reach the perched epikarst water. Therefore, in karst ecosystem the epikarst-soil-plant-atmosphere continuum (ESPAC) would be different from the SPAC in non-karst system. We measured transpiration and canopy conductance from a Cyclobalanopsis glauca (syn. Quercus glauca) stand on a rocky hill slope in South China during 2006-2007 by using the Granier's sap-flow method. Annual stand transpiration (836 mm y -1) accounted for 48.7% of the rainfall during the experimental year. Per month, daily stand transpiration ( E c) maximums varied between 2.1 mm d -1 in January (cool season) to 5.1 mm d -1 in July (hot season). In the driest months, September and October, E c of C. glauca was still high with maximum E c 3.82 mm d -1 and 2.96 mm d -1 respectively. Solar radiation ( PAR), vapor pressure deficiency ( VPD), and air temperature were simple influences on transpiration of C. glauca, which contributed to a quadratic power model, while soil water content ( SWC) moisture influence on transpiration was complicated, which SWC influenced E c greatly under higher VPD, but did not influence E c under low VPD. High stomatal openness occurred in C. glauca in the early morning and declined throughout the day. The relation coefficient between canopy stomatal conductance ( G c) and E c was high when VPD was more than 1.0 kPa, moderate when 0.5 kPa < VPD < 1.0 kPa, and low with VPD of less than 0.5 kPa. Under high VPD, stomatal control of transpiration is high. The pattern of seasonal change of transpiration and canopy stomatal conductance of the plant in karst regions is different from that in non-karst regions, with the stand transpiration and canopy

Hydrological controls on transient aquifer storage in a karst watershed

NASA Astrophysics Data System (ADS)

Spellman, P.; Martin, J.; Gulley, J. D.

2017-12-01

While surface storage of floodwaters is well-known to attenuate flood peaks, transient storage of floodwaters in aquifers is a less recognized mechanism of flood peak attenuation. The hydraulic gradient from aquifer to river controls the magnitude of transient aquifer storage and is ultimately a function of aquifer hydraulic conductivity, and effective porosity. Because bedrock and granular aquifers tend to have lower hydraulic conductivities and porosities, their ability to attenuate flood peaks is generally small. In karst aquifers, however, extensive cave systems create high hydraulic conductivities and porosities that create low antecedent hydraulic gradients between aquifers and rivers. Cave springs can reverse flow during high discharges in rivers, temporarily storing floodwaters in the aquifer thus reducing the magnitude of flood discharge downstream. To date however, very few studies have quantified the magnitude or controls of transient aquifer storage in karst watersheds. We therefore investigate controls on transient aquifer storage by using 10 years of river and groundwater data from the Suwannee River Basin, which flows over the karstic upper Floridan aquifer in north-central Florida. We use multiple linear regression to compare the effects of three hydrological controls on the magnitude of transient aquifer storage: antecedent stage, recharge and slope of hydrograph rise. We show the dominant control on transient aquifer storage is antecedent stage, whereby lower stages result in greater magnitudes of transient aquifer storage. Our results suggest that measures of groundwater levels prior to an event can be useful in determining whether transient aquifer storage will occur and may provide a useful metric for improving predictions of flood magnitudes.

Using isotopes of dissolved inorganic carbon species and water to separate sources of recharge in a cave spring, northwestern Arkansas, USA Blowing Spring Cave

USGS Publications Warehouse

Knierim, Katherine J.; Pollock, Erik; Hays, Phillip D.

2013-01-01

Blowing Spring Cave in northwestern Arkansas is representative of cave systems in the karst of the Ozark Plateaus, and stable isotopes of water (δ18O and δ2H) and inorganic carbon (δ13C) were used to quantify soil-water, bedrock-matrix water, and precipitation contributions to cave-spring flow during storm events to understand controls on cave water quality. Water samples from recharge-zone soils and the cave were collected from March to May 2012 to implement a multicomponent hydrograph separation approach using δ18O and δ2H of water and dissolved inorganic carbon (δ13C–DIC). During baseflow, median δ2H and δ18O compositions were –41.6‰ and –6.2‰ for soil water and were –37.2‰ and –5.9‰ for cave water, respectively. Median DIC concentrations for soil and cave waters were 1.8 mg/L and 25.0 mg/L, respectively, and median δ13C–DIC compositions were –19.9‰ and –14.3‰, respectively. During a March storm event, 12.2 cm of precipitation fell over 82 h and discharge increased from 0.01 to 0.59 m3/s. The isotopic composition of precipitation varied throughout the storm event because of rainout, a change of 50‰ and 10‰ for δ2H and δ18O was observed, respectively. Although, at the spring, δ2H and δ18O only changed by approximately 3‰ and 1‰, respectively. The isotopic compositions of precipitation and pre-event (i.e., soil and bedrock matrix) water were isotopically similar and the two-component hydrograph separation was inaccurate, either overestimating (>100%) or underestimating (<0%) the precipitation contribution to the spring. During the storm event, spring DIC and δ13C–DIC decreased to a minimum of 8.6 mg/L and –16.2‰, respectively. If the contribution from precipitation was assumed to be zero, soil water was found to contribute between 23 to 72% of the total volume of discharge. Although the assumption of negligible contributions from precipitation is unrealistic, especially in karst systems where rapid flow

Natural hazards in the karst areas of the Viñales National Park, Cuba

NASA Astrophysics Data System (ADS)

Govea Blanco, Darlenys; Farfan Gonzalez, Hermes; Dias Guanche, Carlos; Parise, Mario; Ramirez, Robert

2010-05-01

discharges have been mapped on the basis of the outcomes from inquiries carried out in the villages of the area, and of the documentation recorded in the Viñales National Park archives since the time of its foundation in year 2000. Slope movements in karst are quite difficult to map and survey, given the wilderness of the area. Thus, different methodologies were applied at this aim. Mass movements were mapped by using the PNUMA-FAO method, that allows to map the erosional features based upon a matrix analysis, and the results were checked in the field, and processed by means of GIS. As before mentioned, natural hazards from meteorological events are the most dangerous, even because of the peculiar characters of karst landforms, and the hydrologic recharge of karst territories. For instance, arrival of waters from allochtonous, non karst, territories has a great influence on the overall amount of water that is present in karst, both at the surface and underground, and the discharge from karst springs or rivers is strongly dependant upon such waters. Many caves are also conditioned by the presence of water, and periodically may become flooded, especially when located at the mountain or mogote foothills, well within the areas morelikely to be inundated. At the same time, flood occurrence greatly affects the anthropogenic activities, and is often at the origin of the main damage recorded to man and the human society. The other cited natural hazards are by far less disruptive to man, and cause minor damage when compared to floods. This because the great majority of mass movements and erosional phenomena have to be registered in sectors where the presence of man and his activities is much lower, so that economic activities are less affected; lightnings, on the other hand, are at the origin of wildfires generally limited to the highest peaks and mogotes (residual hills and ridges in Cuban tropical karst), once again rarely affecting man's activities.

A glossary of Karst terminology

USGS Publications Warehouse

Monroe, Watson Hiner

1970-01-01

This glossary includes most terms used in describing karst geomorphologic features and processes. The terms are primarily those used in the literature of English-speaking countries, but a few of the more common terms in French, German, and Spanish are included, with references to the corresponding English terms where they are available. The glossary also includes simple definitions of the more common rocks and minerals found in karst terrain, common terms of hydrology, and a number of the descriptive terms used by speleologists. The glossary does not include definitions of most biospeleological terms, geologic structure terms, varieties of carbonate rock that require microscopic techniques for identification, or names describing tools and techniques of cave exploration.

Informal Karst Education in the United States and Internationally

ERIC Educational Resources Information Center

North, Leslie A.

2011-01-01

Despite the abundance of karst terrains and the important role they play in a wide variety of roles including supplying freshwater drinking supplies, no single, comprehensive study investigates the role of informal education for the improved understanding and protection of the terrains. Commonly overlooked anthropogenic karst disturbances…

Spring response to precipitation events using δ(18)O and δ(2)H in the Tanour catchment, NW Jordan.

PubMed

Hamdan, Ibraheem; Wiegand, Bettina; Toll, Mathias; Sauter, Martin

2016-12-01

The Tanour spring is one of the several karst springs located in the northern part of Jordan. Water samples from the Tanour spring and precipitation were collected in the area of Ajloun in NW Jordan for the analysis of stable oxygen and hydrogen isotopes to evaluate the spring response to precipitation events. Rainwater and snow samples were collected from different elevations during winters of 2013-2014 and 2014-2015. In addition, spring samples were collected between December 2014 and March 2015. δ(18)O values in rainwater vary from -3.26 to -17.34 ‰ (average: -7.84 ± 3.23 ‰), while δ(2)H values range between -4.4 and -110.4 ‰ (average: -35.7 ± 25.0 ‰). Deuterium excess ranges from 17.8 to 34.1 ‰ (average: 27.1 ± 4.0 ‰). The Local Meteoric Water Line for the study area was calculated to be δ(2)H = 7.66*δ(18)O + 24.43 (R(2) = 0.98). Pre-event spring discharge showed variation in δ(18)O (range -6.29 to -7.17 ‰; average -6.58 ± 0.19 ‰) and δ(2)H values (range -28.8 to -32.7 ‰; average: -30.5 ± 1.0 ‰). In contrast, δ(18)O and δ(2)H rapidly changed to more negative values during rainfall and snowmelt events and persisted for several days before returning to background values. Spring water temperature, spring discharge, and turbidity followed the trend in isotopic composition during and after the precipitation events. The rapid change in the isotopic composition, spring discharge, water temperature, and turbidity in response to recharge events is related to fast water travel times and low storage capacity in the conduit system of the karst aquifer. Based on the changes in the isotopic composition of spring water after the precipitation events, the water travel time in the aquifer is in the order of 5-11 days.

Human impact on the karst of the Venetian Fore-Alps, Italy

NASA Astrophysics Data System (ADS)

Sauro, U.

1993-06-01

People have been exploiting the limestone massifs of the Venetian Fore-Alps since prehistory. The fluviokarstic style of the relief and the location of springs were important controls of settlement and land use. Six principal types of exploitation are recognized and overlapped in time: (1) hunting and early farming, Paleolithic to Iron Age, with the first soil erosion; (2) general deforestation for timber, charcoal, and fuel, Roman to early modern; (3) farm enclosure and improvement, with stone clearing, medieval to modern; (4) trench warfare in World War I; (5) quarrying and specialized farming (dairy, poultry, pigs) since 1950; and (6) developmnent of modern summer and winter tourist facilities. Soil erosion effects from many centuries can still be recognized, war damage remains visible and continues to pollute aquifers, and modern pressure on the karst land and water resources is often severe.

Spatiotemporal patterns of stable isotopes and hydrochemistry in springs and river flow of the upper Karkheh River Basin, Iran.

PubMed

Osati, Khaled; Koeniger, Paul; Salajegheh, Ali; Mahdavi, Mohammad; Chapi, Kamran; Malekian, Arash

2014-06-01

Karst springs of the Zagros Mountains contribute a significant amount to agricultural and human water demands of western and south-western Iran. For an adequate management of available water resources in semi-arid and arid regions, sufficient hydrological monitoring is needed, and hydro-chemical and isotope hydrological data provide important additional information. About 350 water samples were collected from precipitation, river water, and karst springs of the upper part of the Karkheh River Basin (20,895 km(2)) located between 33°35(') and 34°55(') North and 46°22(') and 49°10(') East with elevations ranging from 928 to 3563 m above sea level. Sampling was conducted in monthly time resolution from August 2011 to July 2012. All samples were analysed for hydro-chemical parameters (pH, electrical conductivity, and major ions) and stable isotopes (deuterium, oxygen-18). Isotope values of precipitation indicate a local meteoric water line (Zagros MWL δ(2)H=6.8 δ(18)O+10.1; R(2)=0.99) situated between the Mediterranean MWL and Global MWL. Spring and river water isotope values vary between-7.1 and-4.1 ‰, and-38 and-25 ‰ for δ(18)O and δ(2)H, respectively, responding to winter snowmelt and evaporation. This work implements stable isotopes and hydro-chemical information of springs and river water to understand hydrological and hydro-geological interrelations in karstic semi-arid areas and helps to improve the current water resources management practices of western Iran.

Use of stable isotope-labeled Escherichia coli as a tracer in karst aquifers

USDA-ARS?s Scientific Manuscript database

Bacterial contamination of karst aquifers is a large concern across the globe, yet bacterial transport in karst aquifers is not currently well understood. Groundwater tracers typically used in karst systems include fluorescent dyes and latex microspheres. Not only can these tracers can be cost-prohi...

Colonization by aerobic bacteria in karst: Laboratory and in situ experiments

USGS Publications Warehouse

Personne, J.-C.; Poty, F.; Mahler, B.J.; Drogue, C.

2004-01-01

Experiments were carried out to investigate the potential for bacterial colonization of different substrates in karst aquifers and the nature of the colonizing bacteria. Laboratory batch experiments were performed using limestone and PVC as substrates, a natural bacterial isolate and a known laboratory strain (Escherichia coli [E. coli]) as inocula, and karst ground water and a synthetic formula as growth media. In parallel, fragments of limestone and granite were submerged in boreholes penetrating two karst aquifers for more than one year; the boreholes are periodically contaminated by enteric bacteria from waste water. Once a month, rock samples were removed and the colonizing bacteria quantified and identified. The batch experiments demonstrated that the natural isolate and E. coli both readily colonized limestone surfaces using karst ground water as the growth medium. In contrast, bacterial colonization of both the limestone and granite substrates, when submerged in the karst, was less intense. More than 300 bacterial strains were isolated over the period sampled, but no temporal pattern in colonization was seen as far as strain, and colonization by E. coli was notably absent, although strains of Salmonella and Citrobacter were each observed once. Samples suspended in boreholes penetrating highly fractured zones were less densely colonized than those in the borehole penetrating a less fractured zone. The results suggest that contamination of karst aquifers by enteric bacteria is unlikely to be persistent. We hypothesize that this may be a result of the high flow velocities found in karst conduits, and of predation of colonizing bacteria by autochthonous zooplankton.

Past and present management of water resources in karst environments

NASA Astrophysics Data System (ADS)

Parise, Mario

2010-05-01

Karst is a very peculiar environment, and has a number of intrinsic features that clearly distinguish it from any other natural setting. Hydrology of karst is dominated by absence or very scarce presence of surface runoff, since water rapidly infiltrates underground through the complex network of conduits and fissures that are at the origin of the development of karst caves. The limited presence of water at the surface represented the main problem to be faced by man, starting from the very first historic phases of establishing settlements in karst territories. As often happens in areas with limited natural resources, man was however able to understand the local environment through observations and direct experience, develop technique in order to collect the limited available water resources, and adapt his way of life to the need of the natural environment. In a few words, a sustainable use of the water resources was reached, that went on for many centuries, allowing development of human settlements and agriculture, and, at the same time, protecting and safeguarding the precious hydric resources. Some of the most typical rural architectures built in karst areas of the Mediterranean Basin can be described as examples of such efforts: from the dry stone walls, to many types of storage-houses or dwellings, known with different names, depending upon the different countries and regions. Dry stone walls, in particular, deserve a particular attention, since they had multiple functions: to delimit the fields and properties, to act as a barrier to soil erosion, to allow terracing the high-gradient slopes, to collect and store water. At this latter aim, dry stone walls were build in order to create a small but remarkable micro-environment, functioning as collectors of moisture and water vapour. In the last centuries, with particular regard to the last decades of XX century, the attention paid by man to the need of the natural environment has dramatically changed. This

Relationships between groundwater contamination and major-ion chemistry in a karst aquifer

NASA Astrophysics Data System (ADS)

Scanlon, B. R.

1990-11-01

Groundwater contamination was examined within a rural setting of the Inner Bluegrass Karst Region of central Kentucky where potential contaminant sources include soil-organic matter, organic and inorganic fertilizer, and septic-tank effluent. To evaluate controls on groundwater contamination, data on nitrate concentrations and indicator bacteria in water from wells and springs were compared with physical and chemical attributes of the groundwater system. Bacterial densities greater than the recommended limit were found in all springs and approximately half of the wells, whereas nitrate concentrations >45 mg l -1 were restricted to 20% of the springs and 10% of the wells. Nitrate concentrations varied markedly in closely spaced wells and springs, which indicates that land use is not the primary control on groundwater contamination. Groundwater contamination is related to the distribution of chemical water types in the study area. All Ca subtype water was contaminated with nitrate and bacteria. Ca subtype water occurs in the shallow, rapidly circulating groundwater zone, which is most susceptible to contamination. The similarity in nitrate concentrations between local springs, major springs, and wells that contain Ca subtype water indicates that the occurrence of large conduits is not the main control on nitrate and bacterial contamination of groundwater. Temporal fluctuations in nitrate concentrations of Ca subtype water are attributed to seasonal fluctuations in recharge and in plant growth. Ca-Mg water subtype was generally not contaminated, and Na-HCO 3 and Na-Cl water types were not contaminated. Ca-Mg water subtype, and Na-HCO 3 and Na-Cl water types are associated with longer residence times and reducing conditions, which allow bacterial die-off and denitrification, respectively. Differences in residence time and reducing conditions among the chemical water types and subtypes are attributed to variations in rock permeability and to the occurrence of horizontal

Evaporite karst of northern lower Michigan

USGS Publications Warehouse

Black, T.J.

1997-01-01

Michigan has three main zones of evaporite karst: collapse breccia in Late Silurian deposits of the Mackinac Straits region; breccia, collapse sinks, and mega-block collapse in Middle Devonian deposits of Northern Lower Michigan, which overlaps the preceding area; and areas of soil swallows in sinks of Mississippian deposits between Turner and Alabaster in Arenac and Iosco counties, and near Grand Rapids in Kent County. The author has focused his study on evaporite karst of the Middle Devonian deposits. The Middle Devonian depos its are the Detroit River Group: a series consisting of limestone, dolomite, shale, salt, gypsum, and anhydrite. The group occurs from subcrop, near the surface, to nearly 1400 feet deep from the northern tip of the Southern Peninsula to the south edge of the "solution front" Glacial drift is from zero to 350 feet thick. Oil and gas exploration has encountered some significant lost-circulation zones throughout the area. Drilling without fluid returns, casing-seal failures, and lost holes are strong risks in some parts of the region. Lost fluid returns near the top of the group in nearby areas indicate some karst development shortly after deposition. Large and irregular lost-circulation zones, linear and patch trends of large sink holes, and 0.25 mile wide blocks of down-dropped land in the northern Lower Peninsula of Michigan were caused by surface- and ground-water movement along faults into the Detroit River Group. Glaciation has removed some evidence of the karst area at the surface. Sinkhole development, collapse valleys, and swallows developed since retreat of the glacier reveal an active solution front in the Detroit River Group.

Contamination, Transport, and Exposure Mapping and Assessment of Karst Groundwater Systems in Northern Puerto Rico Using GIS

NASA Astrophysics Data System (ADS)

Howard, J.; Schifman, L. A.; Irrizary, C.; Torres, P.; Padilla, I. Y.

2011-12-01

Ground waters from karst aquifer systems are one of the most important sources of freshwater worldwide and are highly vulnerable to both natural and anthropogenic contamination. Contaminants released into karst groundwater systems move through complex pathways from their sources to discharge areas of potential exposure. Points of exposure can include wells, springs, and surface waters that serve as drinking water sources. In Puerto Rico, the North Coast Limestone Aquifer System, which extends 90 miles across the north coast with an area of nearly 700 sq. miles, provides more than 50% of the potable water demand for industrial and drinking purposes. Historical reports from the 1980s revealed that volatile organic compounds, phthalates, and metals were close to or exceeded maximum contaminant levels. Exposure to such contaminants has been reported to cause reproductive and developmental issues, such as preterm birth. Since there is minimal understanding of the extent of contamination it is important to identify areas of potential concern. Preliminary analysis of 20 groundwater/springs and 20 tap water sites within the North Coast suggest that contamination is still a major concern. In addition, mixed effects models analyses suggest that >60% of pre-term birth rates may be explained by the presence of sites contaminated with volatile organic compounds, phthalates, and metals within the North Coast region. This presentation will focus primarily on how GIS was used as a tool for developing sampling strategies for collecting groundwater and tap water sources within the North Coast Limestone Aquifer System of Puerto Rico. In addition, the linkage of contamination, transport, and exposure to volatile organic compounds and phthalates will be addressed.

Deep water circulation, residence time, and chemistry in a karst complex.

PubMed

Aquilina, L; Ladouche, B; Doerfliger, N; Bakalowicz, M

2003-01-01

We investigated the hydrochemistry of a complex karst hydrosystem made of two carbonate units along a coastal lagoon. Ground water emerges on the lagoon floor from a submarine spring. In addition, thermal waters circulate through the limestone and mix with karst water near the lagoon shore. A distinction between the water from the two carbonate units is related to marine influences and human activities. In one of the massifs, the data show an incongruent dissolution of dolomite with time. In the other system, a slight contamination by saline fluids from the thermal reservoir has led to high calcium and magnesium concentrations. 36Cl, 14C, and 3H data constrain the residence time of the water, and allow for the distinguishing of four circulation types: (1) shallow surface circulation (primarily above sea level) in the karstic units with short residence times (<20 years); (2) shallow subsurface circulation (approximately 0 to -50 m) below the karstic units with residence time in the order of 50 years; (3) deep circulation at depth of 700 to 1500 m in the Jurassic limestones below thick sedimentary cover, with residence time of several thousand years for a part of the water; and (4) deep circulation at a depth of approximately 2500 m, which represents the thermal reservoir in the Jurassic units with residence time of approximately 100,000 years. An interpretative hydrogeological framework is based on the constraints of the geochemical analyses of the deep thermal system, and by water flow from the surface to the deep parts of the carbonate formations.

Study on comprehensive planning of rocky desertification in karst area of Chongqing

NASA Astrophysics Data System (ADS)

Zang, Yajun

2017-11-01

Chongqing is a key area for comprehensive treatment of rocky desertification in karst areas of china. Strengthening the comprehensive management of karst rocky desertification area, for the maintenance of ecological safety of Three Gorges Reservoir area, expanding the karst rocky desertification area people survival and development space, and improving the regional ecological conditions, have important practical significance to the construction of ecological civilization and building a harmonious society. Based on the investigation, analysis and arrangement of the data in the rocky desertification area, the paper puts forward the corresponding measures and phased targets for the treatment of the Rocky Desertification in the karst areas of Chongqing.

Karst in the United States: a digital map compilation and database

USGS Publications Warehouse

Weary, David J.; Doctor, Daniel H.

2014-01-01

This report describes new digital maps delineating areas of the United States, including Puerto Rico and the U.S. Virgin Islands, having karst or the potential for development of karst and pseudokarst. These maps show areas underlain by soluble rocks and also by volcanic rocks, sedimentary deposits, and permafrost that have potential for karst or pseudokarst development. All 50 States contain rocks with potential for karst development, and about 18 percent of their area is underlain by soluble rocks having karst or the potential for development of karst features. The areas of soluble rocks shown are based primarily on selection from State geologic maps of rock units containing significant amounts of carbonate or evaporite minerals. Areas underlain by soluble rocks are further classified by general climate setting, degree of induration, and degree of exposure. Areas having potential for volcanic pseudokarst are those underlain chiefly by basaltic-flow rocks no older than Miocene in age. Areas with potential for pseudokarst features in sedimentary rocks are in relatively unconsolidated rocks from which pseudokarst features, such as piping caves, have been reported. Areas having potential for development of thermokarst features, mapped exclusively in Alaska, contain permafrost in relatively thick surficial deposits containing ground ice. This report includes a GIS database with links from the map unit polygons to online geologic unit descriptions.

Significance of silica karst in ignimbrite landscapes in the Peruvian Andes and their vulnerability to land degradation

NASA Astrophysics Data System (ADS)

Cammeraat, Erik; Seijmonsbergen, Harry

2010-05-01

In the high Andes of Peru spectacular silicakarst landscapes have developed in ignimbrite deposits which have not yet been studied in detail. These striking geomorphological features are locally known as ‘Bosques de Rocca' and are widespread between 3200 and 4000 m altitude and until now believed to be the result of Aeolian processes. This study discusses their occurrence in the ‘Cumbemayo area' close to Cajamarca, in northern Peru. In this region, high rainfall amounts are combined with low temperatures and land use becomes more and more prominent. This studies aims at understanding the major factors explaining their occurrence and origin, as well as the vulnerability of this landscape for increased land use and degradation. For that, a geomorhological inventory was made, supplemented by morphometric measurements, geochemical analysis of surface water and groundwater originating from springs at the interface of ignimbrites and the underlying low permeable rock strata, as well as an assessment of soil degradation vulnerability. The ignimbrites are composed of predominantly fine grained silicate-rich deposits with at least 5-7 different superimposed beds. A major difference in grain-size exists between beds, which dictate the resistance to weathering. Large isolated, but also interwoven complexes of vertical pinnacles are present ranging from 5-30m height with often near vertical slopes. Local fracturing and the presence and spacing of joints strongly dominate the orientation and presence of the tower karst pinnacles. At the basement of the pinnacles concave foot slopes and narrow valleys are present. Soils here mainly consist of shallow vitric Andosols. The preferential occurrence in the landscape of such groups of pinnacles is at the front of horizontally bedded rock plateaus, which are often influenced by massive tensional fissuring, leading to toppling and widening of joints. This process speeds up the infiltration and karst processes. The rock towers also

U.S. Geological Survey Karst Interest Group: proceedings, St Petersburg, Florida February 13-16, 2001

USGS Publications Warehouse

Kuniansky, Eve L.

2001-01-01

Karst and similar landscapes are found in a wide range of biogeographic classes. In the U.S. for example, Everglades, Mammoth Cave, and Hawaii Volcanoes National Parks have little in common - except karst or pseudokarst, and a cultural past (even though these are very different). This diversity of geologic settings makes karst difficult to categorize and work with when designing a national program such as the recent NPS-USGS Geo-Indicators effort. A GIS-based approach with multiple datalayers is the only sane way to understand and convey the many relationships, in X, Y, and Z axes, between component ecosystems and cultural resources within karst and pseudokarst landscapes. Obviously, karst and cultural landscapes cross modern political as well as biogeographic boundaries. Here again, three-dimensional data are the foundation for understanding similar to that in anatomy and physiology: structure and function. In understanding where the most vulnerable 'pressure points' exist within karst landscapes, we can target landscape-scale ecosystem management to greatest effect. USGS and the National Cave and Karst research Institute could play an extremely significant role in cave and karst management on a national scale beyond NPS or other agency boundaries via cooperative management of three-dimensional karst datasets analogous to programs in several states.

Evolution of collapse valleys in karst - examples from the Carpatho-Balkanides of Serbia

NASA Astrophysics Data System (ADS)

Petrović, Aleksandar S.; Ćalić, Jelena; Spalević, Aleksandra; Pantić, Marko

2016-04-01

Development of valleys in karst is an issue which has not been sufficiently studied in karst surface morphology. THESE valleys are long linear forms whose orthogonal projections resemble normal valleys, but most of their characteristics are strongly influenced by karst process. In largest number of relevant references, this subject is either only briefly mentioned or completely lacking. This paper presents the examples of a particular type of valley in karst formed by cave ceiling collapse close to the topographical surface. Karst of the Carpatho-Balkanides in eastern Serbia is characterized by uneven spatial distribution in several large massifs, but also in a large number of relatively small outcrops (patches and belts), which enable the development of contact karst and fluviokarst. Many morphological elements are of fluvial origin, subsequently modified by karst process. Collapse valleys occur mostly at the downstream contacts (where a seasonal watercourse leaves limestones) or in karst/limestone belts. In the first phase, which is visible on the example of the Radovanska Reka, the river course sinks to the swallets in the riverbed and forms a blind valley. After sinking, the water flows through the tunnel cave, while largest part of the valley remains above the cave. The bottom of the dry valley is dissected by deep dolines, reaching almost to the cave roof. In this part of the study, the area was scanned by a multistation Leica Nova MS 50 (resolution 20 cm @ 10 m). In the second phase, the doline bottoms reach the cave ceilings which develop holes at certain points, as it is case at the Zamna River valley. These hollows tend to enlarge with time, and the surface of the cave ceiling is reduced. The third, final phase is characterised by collapse of larger segments of cave ceilings. Only the natural bridges remain, as the remnants of former caves (e.g. in the Vratna River valley, Ravna Reka valley). These parts of valleys in karst are usually narrow, steep

Cold-stenothermic spring fauna in mountainous headwaters of the National Park Kellerwald-Edersee in Germany

NASA Astrophysics Data System (ADS)

Reiss, Martin; Zaenker, Stefan; Chifflard, Peter

2017-04-01

,9). Due to nearly unaffected ecohydrological properties, in particular: relative consistently cold water temperature with low amplitudes (cold stenothermy), mostly low flow velocity and an intermittent discharge regime a very unique and specific adapted spring fauna composition for the German low mountain ranges can be characterized. Cold stenothermic and spring related species are very frequent in relative occurrence and abundance. We analyzed a map based and representative distribution for the entire large-scale protected area of the National Park Kellerwald-Edersee according to Bythinella dunkeri (spring snail), Crenobia alpina (planarian), Crunoecia irrorata (caddisfly) and Niphargus schellenbergi (groundwater amphipod). We discuss the potential of ecohydrological research on possible climate change predictions and consequences on the distribution of cold stenothermic and spring dwelling species within the special context of research goals in National Parks. Here, an idea of a new approach for an ecohydrological assessment by indicating cold stenothermic taxa is given as an outlook. References Reiss, M., Steiner, H. & S. Zaenker (2009): The Biospeleological Register of the Hesse Federation for Cave and Karst Research (Germany). Cave and Karst Science 35(1), pp.25-34.

Hydrochemical constraints between the karst Tabular Middle Atlas Causses and the Saïs basin (Morocco): implications of groundwater circulation

NASA Astrophysics Data System (ADS)

Miche, Hélène; Saracco, Ginette; Mayer, Adriano; Qarqori, Khaoula; Rouai, Mohamed; Dekayir, Abdelilah; Chalikakis, Konstantinos; Emblanch, Christophe

2018-02-01

The karst Tabular Middle Atlas Causses reservoir is the main drinking-water supply of Fez-Meknes region (Saïs Basin) in Morocco. Recent analyses showed a decline in associated groundwater chemical quality and increased turbidity. To understand this hydrosystem, four surveys were undertaken during fall and spring, 2009-2011. Hydrogeochemical studies coupled with isotopic analyses (δ18O, δD and 222Rn) showed that the aquifers between the causses (mountains) and the Saïs Basin are of Liassic origin and at the southern extremities are of Triassic origin. Five recharge zones of different altitudes have been defined, including two main mixing zones in the south. Deuterium excess results suggest local recharge, while a plot of δ18O versus δD characterizes a confined aquifer in the eastern sector. 222Rn results reveal areas of rapid exchanges with an upwelling time of less than 2 weeks. A schematic conceptual model is presented to explain the groundwater circulation system and the behavior of this karst system.

Folk use of medicinal plants in Karst and Gorjanci, Slovenia.

PubMed

Lumpert, Mateja; Kreft, Samo

2017-02-23

Information on the use of medicinal plants in Karst and Gorjanci is not available in the literature, but collection of plants is still an important and widespread practice in these regions. Karst and Gorjanci are two remote regions in Slovenia that are only 120 km apart but have different climates; one region is close to the Italian border, and the other is near the Croatian border. Our aim was to report and compare the use of medicinal plants in both regions. From October 2013 to September 2014, 25 informants each in Karst and Gorjanci were interviewed during field research. The age of the informants ranged from 33 to 89 years, with an average age of 61 years in Karst and 69 years in Gorjanci. The main question was "Which plants do or did you collect from nature and use?" Plants of medicinal, nutritive, veterinary or cosmetic use were considered. A total of 78 and 82 taxa were reported in Karst and Gorjanci, respectively; 65 taxa were reported in both regions. Approximately 64% of the plants in each region were distinctive for only a few informants (fewer than 7). The remaining plants were considered important, and the majority were mutual to both regions. Few reported plants were typical for just one region. Differences in the use of some common medicinal plants were observed, e.g., Matricaria chamomilla was used mostly for the treatment of gastrointestinal disorders, respiratory infections and sore eyes in Gorjanci but as a calmative in Karst. Altogether, 15 different oral and 15 different topical medicinal preparations were reported. Folk knowledge was found to be influenced by the media, particularly popular books about medicinal plants that were published in the 20th century. The present research documents the folk use of medicinal plants in Karst and Gorjanci, Slovenia. This rapidly changing practice needs to be documented before it disappears or changes.

Evaluating Weather Research and Forecasting Model Sensitivity to Land and Soil Conditions Representative of Karst Landscapes

NASA Astrophysics Data System (ADS)

Johnson, Christopher M.; Fan, Xingang; Mahmood, Rezaul; Groves, Chris; Polk, Jason S.; Yan, Jun

2018-03-01

Due to their particular physiographic, geomorphic, soil cover, and complex surface-subsurface hydrologic conditions, karst regions produce distinct land-atmosphere interactions. It has been found that floods and droughts over karst regions can be more pronounced than those in non-karst regions following a given rainfall event. Five convective weather events are simulated using the Weather Research and Forecasting model to explore the potential impacts of land-surface conditions on weather simulations over karst regions. Since no existing weather or climate model has the ability to represent karst landscapes, simulation experiments in this exploratory study consist of a control (default land-cover/soil types) and three land-surface conditions, including barren ground, forest, and sandy soils over the karst areas, which mimic certain karst characteristics. Results from sensitivity experiments are compared with the control simulation, as well as with the National Centers for Environmental Prediction multi-sensor precipitation analysis Stage-IV data, and near-surface atmospheric observations. Mesoscale features of surface energy partition, surface water and energy exchange, the resulting surface-air temperature and humidity, and low-level instability and convective energy are analyzed to investigate the potential land-surface impact on weather over karst regions. We conclude that: (1) barren ground used over karst regions has a pronounced effect on the overall simulation of precipitation. Barren ground provides the overall lowest root-mean-square errors and bias scores in precipitation over the peak-rain periods. Contingency table-based equitable threat and frequency bias scores suggest that the barren and forest experiments are more successful in simulating light to moderate rainfall. Variables dependent on local surface conditions show stronger contrasts between karst and non-karst regions than variables dominated by large-scale synoptic systems; (2) significant

Recharge Area, Base-Flow and Quick-Flow Discharge Rates and Ages, and General Water Quality of Big Spring in Carter County, Missouri, 2000-04

USGS Publications Warehouse

Imes, Jeffrey L.; Plummer, Niel; Kleeschulte, Michael J.; Schumacher, John G.

2007-01-01

Exploration for lead deposits has occurred in a mature karst area of southeast Missouri that is highly valued for its scenic beauty and recreational opportunities. The area contains the two largest springs in Missouri (Big Spring and Greer Spring), both of which flow into federally designated scenic rivers. Concerns about potential mining effects on the area ground water and aquatic biota prompted an investigation of Big Spring. Water-level measurements made during 2000 helped define the recharge area of Big Spring, Greer Spring, Mammoth Spring, and Boze Mill Spring. The data infer two distinct potentiometric surfaces. The shallow potentiometric surface, where the depth-to-water is less than about 250 feet, tends to mimic topographic features and is strongly controlled by streams. The deep potentiometric surface, where the depth-to-water is greater than about 250 feet represents ground-water hydraulic heads within the more mature karst areas. A highly permeable zone extends about 20 mile west of Big Spring toward the upper Hurricane Creek Basin. Deeper flowing water in the Big Spring recharge area is directed toward this permeable zone. The estimated sizes of the spring recharge areas are 426 square miles for Big Spring, 352 square miles for Greer Spring, 290 square miles for Mammoth Spring, and 54 square miles for Boze Mill Spring. A discharge accumulation curve using Big Spring daily mean discharge data shows no substantial change in the discharge pattern of Big Spring during the period of record (water years 1922 through 2004). The extended periods when the spring flow deviated from the trend line can be attributed to prolonged departures from normal precipitation. The maximum possible instantaneous flow from Big Spring has not been adequately defined because of backwater effects from the Current River during high-flow conditions. Physical constraints within the spring conduit system may restrict its maximum flow. The largest discharge measured at Big Spring

Submerged karst landforms observed by multibeam bathymetric survey in Nagura Bay, Ishigaki Island, southwestern Japan

NASA Astrophysics Data System (ADS)

Kan, Hironobu; Urata, Kensaku; Nagao, Masayuki; Hori, Nobuyuki; Fujita, Kazuhiko; Yokoyama, Yusuke; Nakashima, Yosuke; Ohashi, Tomoya; Goto, Kazuhisa; Suzuki, Atsushi

2015-01-01

Submerged tropical karst features were discovered in Nagura Bay on Ishigaki Island in the southern Ryukyu Islands, Japan. The coastal seafloor at depths shallower than ~ 130 m has been subjected to repeated and alternating subaerial erosion and sedimentation during periods of Quaternary sea-level lowstands. We conducted a broadband multibeam survey in the central area of Nagura Bay (1.85 × 2.7 km) and visualized the high-resolution bathymetric results over a depth range of 1.6-58.5 m. Various types of humid tropical karst landforms were found to coexist within the bay, including fluviokarst, doline karst, cockpit karst, polygonal karst, uvalas, and mega-dolines. Although these submerged karst landforms are covered by thick postglacial reef and reef sediments, their shapes and sizes are distinct from those associated with coral reef geomorphology. The submerged landscape of Nagura Bay likely formed during multiple glacial and interglacial periods. According to our bathymetric results and the aerial photographs of the coastal area, this submerged karst landscape appears to have developed throughout Nagura Bay (i.e., over an area of approximately 6 × 5 km) and represents the largest submerged karst in Japan.

Simulating groundwater flow in karst aquifers with distributed parameter models—Comparison of porous-equivalent media and hybrid flow approaches

USGS Publications Warehouse

Kuniansky, Eve L.

2016-09-22

Understanding karst aquifers, for purposes of their management and protection, poses unique challenges. Karst aquifers are characterized by groundwater flow through conduits (tertiary porosity), and (or) layers with interconnected pores (secondary porosity) and through intergranular porosity (primary or matrix porosity). Since the late 1960s, advances have been made in the development of numerical computer codes and the use of mathematical model applications towards the understanding of dual (primary [matrix] and secondary [fractures and conduits]) porosity groundwater flow processes, as well as characterization and management of karst aquifers. The Floridan aquifer system (FAS) in Florida and parts of Alabama, Georgia, and South Carolina is composed of a thick sequence of predominantly carbonate rocks. Karst features are present over much of its area, especially in Florida where more than 30 first-magnitude springs occur, numerous sinkholes and submerged conduits have been mapped, and numerous circular lakes within sinkhole depressions are present. Different types of mathematical models have been applied for simulation of the FAS. Most of these models are distributed parameter models based on the assumption that, like a sponge, water flows through connected pores within the aquifer system and can be simulated with the same mathematical methods applied to flow through sand and gravel aquifers; these models are usually referred to as porous-equivalent media models. The partial differential equation solved for groundwater flow is the potential flow equation of fluid mechanics, which is used when flow is dominated by potential energy and has been applied for many fluid problems in which kinetic energy terms are dropped from the differential equation solved. In many groundwater model codes (basic MODFLOW), it is assumed that the water has a constant temperature and density and that flow is laminar, such that kinetic energy has minimal impact on flow. Some models have

Hydrogeology and quality of ground water in the Boone Formation and Cotter Dolomite in karst terrain of northwestern Boone County, Arkansas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Leidy, V.A.; Morris, E.E.

1991-01-01

Shallow groundwater flow systems in karst terrain of northwestern Boone County, Arkansas, are particularly susceptible to contamination. The potential for groundwater contamination probably is greater in the northern one-half of the study area where there are more photolineaments and presumably subsurface fractures. Groundwater samples from 17 springs discharging from the Boone Formation and 17 wells completed in the Cotter Dolomite were analyzed to determine ambient groundwater quality and to document water quality variations. The chemical constituents in groundwater generally did not exceed US Environmental Protection Agency primary or secondary maximum contaminant levels. However, fecal coliform and fecal streptococcus bacteria weremore » detected in most springs and in three wells. One spring, located near an abandoned wood-treatment plant (a designated Superfund site), had maximum iron, manganese, lead, and pentachlorophenol concentration that exceeded US Environmental Protection Agency's primary or secondary maximum contamination levels for drinking water. Water samples collected from selected springs emerging from the Boone Formation exhibited an overall decrease in specific conductance and total alkalinity, calcium, magnesium, sodium, and chloride concentrations and an overall increase in nitrate, fecal coliform, and fecal streptococcus bacteria concentrations 3 to 8 hours after a rainstorm.« less

Advances in Dynamic Transport of Organic Contaminants in Karst Groundwater Systems

NASA Astrophysics Data System (ADS)

Padilla, I. Y.; Vesper, D.; Alshawabkeh, A.; Hellweger, F.

2011-12-01

Karst groundwater systems develop in soluble rocks such as limestone, and are characterized by high permeability and well-developed conduit porosity. These systems provide important freshwater resources for human consumption and ecological integrity of streams, wetlands, and coastal zones. The same characteristics that make karst aquifers highly productive make them highly vulnerable to contamination. As a result, karst aquifers serve as an important route for contaminants exposure to humans and wildlife. Transport of organic contaminants in karst ground-water occurs in complex pathways influenced by the flow mechanism predominating in the aquifer: conduit-flow dominated systems tend to convey solutes rapidly through the system to a discharge point without much attenuation; diffuse-flow systems, on the other hand, can cause significant solute retardation and slow movement. These two mechanisms represent end members of a wide spectrum of conditions found in karst areas, and often a combination of conduit- and diffuse-flow mechanisms is encountered, where both flow mechanisms can control the fate and transport of contaminants. This is the case in the carbonate aquifers of northern Puerto Rico. This work addresses advances made on the characterization of fate and transport processes in karst ground-water systems characterized by variable conduit and/or diffusion dominated flow under high- and low-flow conditions. It involves laboratory-scale physical modeling and field-scale sampling and historical analysis of contaminant distribution. Statistical analysis of solute transport in Geo-Hydrobed physical models shows the heterogeneous character of transport dynamics in karstic units, and its variability under different flow regimes. Field-work analysis of chlorinated volatile organic compounds and phthalates indicates a large capacity of the karst systems to store and transmit contaminants. This work is part of the program "Puerto Rico Testsite for Exploring Contamination

Hydraulic Evolution of Karst Microfracture

NASA Astrophysics Data System (ADS)

Windom, L. M.; Dragila, M. I.; Weisbrod, N.

2017-12-01

Karst terrain comprises an astounding 25% of our planet's potable water resources, yet the evolution of these systems from micro-fracture to open channel is poorly understood. Focusing on the unsaturated portion of an evolving karst system, we present a conceptual model for the hydraulic evolution of micro-fractures into larger conduits. Tensional micro-fractures (< 1mm thick) under unsaturated conditions may be eroded by water flowing either as seepage films or as capillary rivulets. In addition to general erosion, the narrow width of capillary rivulets may etch the beginning of preferential paths within the tensional micro-fractures that will lead to tubular channels. Both fluid mechanisms, seepage and rivulets, were tested in the laboratory, and data of the resulting geochemical erosion rates are presented in the form of calcium dissolution rates measured by inductively coupled plasma atomic emission spectroscopy (ICP-OES).

Identification of karst sinkholes in a forested karst landscape using airborne laser scanning data and water flow analysis

NASA Astrophysics Data System (ADS)

Hofierka, Jaroslav; Gallay, Michal; Bandura, Peter; Šašak, Ján

2018-05-01

Karst sinkholes (dolines) play an important role in a karst landscape by controlling infiltration of surficial water, air flow or spatial distribution of solar energy. These landforms also present a limiting factor for human activities in agriculture or construction. Therefore, mapping such geomorphological forms is vital for appropriate landscape management and planning. There are several mapping techniques available; however, their applicability can be reduced in densely forested areas with poor accessibility and visibility of the landforms. In such conditions, airborne laser scanning (ALS) provides means for efficient and accurate mapping of both land and landscape canopy surfaces. Taking the benefits of ALS into account, we present an innovative method for identification and evaluation of karst sinkholes based on numerical water flow modelling. The suggested method was compared to traditional techniques for sinkhole mapping which use topographic maps and digital terrain modelling. The approach based on simulation of a rainfall event very closely matched the reference datasets derived by manual inspection of the ALS digital elevation model and field surveys. However, our process-based approach provides advantage of assessing the magnitude how sinkholes influence concentration of overland water flow during extreme rainfall events. This was performed by calculating the volume of water accumulated in sinkholes during the simulated rainfall. In this way, the influence of particular sinkholes on underground geomorphological systems can be assessed. The method was demonstrated in a case study of Slovak Karst in the West Carpathians where extreme rainfalls or snow-thaw events occur annually. We identified three spatially contiguous groups of sinkholes with a different effect on overland flow concentration. These results are discussed in relation to the known underground hydrological systems.

Peculiarity and vulnerability of karst settings, analyzed through a review of available environmental indices

NASA Astrophysics Data System (ADS)

Parise, Mario; Mazzei, Marianna

2016-04-01

Karst is a unique environment on Earth, characterized by a variety of peculiar geological and hydrological features, that are expressed by typical landforms at the surface (doline, ponor, polje, etc.) and underground (single cave, sinkhole, complex hypogean systems consisting of sequences of pits and galleries, etc.). Among the main characters of karst, the direct connection between the surface and the underground is at the origin of the fragility of karst settings, and the related high vulnerability. Many different types of natural geological hazards (or geo-hazards) may potentially affect karst lands, with sinkholes and flash floods being the most frequent and typical. In addition, karst is exposed to a variety of anthropogenic disturbances as well, including loss of natural landscapes, destruction of caves and speleothems, and contamination and pollution problems. At this latter regard, it has to be reminded that karst aquifers host high quality groundwaters, that are used as source of drinking water worldwide, with estimates indicating that the supply of drinking water from karst is going to have a significant increase in the next decades, From all of this, the importance in fully defining the karst setting, and in a detail examination of all the natural and anthropogenic events that may cause negative effects on it, comes out. Uniqueness of karst has been acknowledged since a long time, but only in recent years efforts have been made to develop approaches and methods specifically dedicated to this peculiar environment. Such approaches represent definitely a mandatory step in the correct management of karst terranes, providing useful elements to stakeholders, land managers and people living in karst lands about their fragility, and the need to safeguard them and the natural resources therein contained. Starting from these considerations, in this contribution we review the main environmental indices dedicated to karst that have been recently proposed in the

Subterranean karst environments as a global sink for atmospheric methane

NASA Astrophysics Data System (ADS)

Webster, Kevin D.; Drobniak, Agnieszka; Etiope, Giuseppe; Mastalerz, Maria; Sauer, Peter E.; Schimmelmann, Arndt

2018-03-01

The air in subterranean karst cavities is often depleted in methane (CH4) relative to the atmosphere. Karst is considered a potential sink for the atmospheric greenhouse gas CH4 because its subsurface drainage networks and solution-enlarged fractures facilitate atmospheric exchange. Karst landscapes cover about 14% of earth's continental surface, but observations of CH4 concentrations in cave air are limited to localized studies in Gibraltar, Spain, Indiana (USA), Vietnam, Australia, and by incomplete isotopic data. To test if karst is acting as a global CH4 sink, we measured the CH4 concentrations, δ13CCH4, and δ2HCH4 values of cave air from 33 caves in the USA and three caves in New Zealand. We also measured CO2 concentrations, δ13CCO2, and radon (Rn) concentrations to support CH4 data interpretation by assessing cave air residence times and mixing processes. Among these caves, 35 exhibited subatmospheric CH4 concentrations in at least one location compared to their local atmospheric backgrounds. CH4 concentrations, δ13CCH4, and δ2HCH4 values suggest that microbial methanotrophy within caves is the primary CH4 consumption mechanism. Only 5 locations from 3 caves showed elevated CH4 concentrations compared to the atmospheric background and could be ascribed to local CH4 sources from sewage and outgassing swamp water. Several associated δ13CCH4 and δ2HCH4 values point to carbonate reduction and acetate fermentation as biochemical pathways of limited methanogenesis in karst environments and suggest that these pathways occur in the environment over large spatial scales. Our data show that karst environments function as a global CH4 sink.

Porosity Gradient Development Around Karst Features due to Tidal Pumping in Eastern Yucatan Peninsula

NASA Astrophysics Data System (ADS)

Maqueda, A.; Renard, P.

2016-12-01

Water exchange between karst features and the porous matrix around them has been observed in karst aquifers by previous research. The exchange is driven by hydraulic head gradients caused by stormwater runoff or sea tides and may cause mineral dissolution. The authors of this work proposed a conceptual model of porosity development under tidal variations of hydraulic head is proposed. Simulations of reactive transport and porosity evolution were conducted to explore the porosity gradient development around a karst feature. Simulations account for petrophysical properties of porous media and groundwater geochemical characteristics. Data used in simulations corresponds to an eogenetic karst aquifer found on the eastern coast of Yucatan Peninsula in Mexico. Simulations include both analytical and numerical solutions of porosity increase caused by mineral dissolution. The estimated rate of porosity development and associated wall retreat (3-30 cm/100 yr) are large enough to develop karst cavities on time periods relevant to karst formation in the study area (10K yr). The analytical solution could be used to assess porosity increase in rock samples and can be also applied to model slow reactions in porous media under flow driven by sinusoidal hydraulic boundary conditions. The results show a possible alternative mechanism of karst cavity development in a high conductive limestone rock matrix aquifer.

Linking climate change and karst hydrology to evaluate species vulnerability: The Edwards and Madison aquifers (Invited)

NASA Astrophysics Data System (ADS)

Mahler, B. J.; Long, A. J.; Stamm, J. F.; Poteet, M.; Symstad, A.

2013-12-01

Karst aquifers present an extreme case of flow along structurally variable pathways, making them highly dynamic systems and therefore likely to respond rapidly to climate change. In turn, many biological communities and ecosystems associated with karst are sensitive to hydrologic changes. We explored how three sites in the Edwards aquifer (Texas) and two sites in the Madison aquifer (South Dakota) might respond to projected climate change from 2011 to 2050. Ecosystems associated with these karst aquifers support federally listed endangered and threatened species and state-listed species of concern, including amphibians, birds, insects, and plants. The vulnerability of selected species associated with projected climate change was assessed. The Advanced Research Weather and Research Forecasting (WRF) model was used to simulate projected climate at a 36-km grid spacing for three weather stations near the study sites, using boundary and initial conditions from the global climate model Community Climate System Model (CCSM3) and an A2 emissions scenario. Daily temperature and precipitation projections from the WRF model were used as input for the hydrologic Rainfall-Response Aquifer and Watershed Flow (RRAWFLOW) model and the Climate Change Vulnerability Index (CCVI) model. RRAWFLOW is a lumped-parameter model that simulates hydrologic response at a single site, combining the responses of quick and slow flow that commonly characterize karst aquifers. CCVI uses historical and projected climate and hydrologic metrics to determine the vulnerability of selected species on the basis of species exposure to climate change, sensitivity to factors associated with climate change, and capacity to adapt to climate change. An upward trend in temperature was projected for 2011-2050 at all three weather stations; there was a trend (downward) in annual precipitation only for the weather station in Texas. A downward trend in mean annual spring flow or groundwater level was projected for

Hazard connected to tunnel construction in Mt Stena karstic area (Rosandra Valley, Classical Karst)

NASA Astrophysics Data System (ADS)

Cucchi, F.; Boschin, W.; Visintin, L.; Zini, L.

2009-04-01

Rosandra Valley -a unique geomorphological environment- is located in the western side of the Classical Karst plateau. This deep limestone gorge is crossed by a stream that is fed by a large basin located in Slovenia. Rosandra Valley is the only example of Classical Karst river valley with surface hydrography; the torrent digs a deep gully into the rock, rich in rapids, swirl holes, small waterfalls, enclosed meanders and basins; here, the first seepage phenomena occur, and part of the water feeds the underground aquifer. Rosandra Valley is theatre to complex structural situation; the NE slope culminates in the structure of Mt Stena, a limestone tectonic scale located between two faults and firmly rooted in the karst platform. Tectonics is quite important for the development of deep karst in this area; Mt Stena, in particular, hosts a comprehensive net of articulated and diversely shaped caves, basically organised on several levels, which stretches over a total of 9,000 metres, bearing testimony to ancient geological and hydrogeological origins. The deepest areas of the system reach a suspended aquifer that is probably sustained by an overthrust and placed about 100 meters above Rosandra torrent underground aquifer. During feasibility studies about Trieste-Divača high velocity railway link, interaction between project and karst features was examined; in fact the proximity of proposal project and Mt Stena karst system suggest to improve the knowledge related to karst and hydrogeological aspects of the massif. Compatibly with the project requirements, risk of voids intersection and water contamination were analyzed. In fact the Mt Stena suspended aquifer partially feeds Rosandra torrent which flows in a protected natural area. Karst features were represented in a 3D model in order to better understand the spatial relationship between railway project and karst system.

Prevalence of Cryptosporidium parvum in private drinking water cisterns in Bani-Kenanah district, northern Jordan.

PubMed

Abo-Shehada, Mahmoud; Hindyia, Mona; Saiah, Abbass

2004-10-01

Due to water scarcity in Jordan, the water authority only pump the water once or twice a week to the population. Thus people in rural areas, including the Bani-Kenanah district, make the most of their water resources by storing rainwater in private reservoirs for use during periods of water shortage. These reservoirs include; underground cisterns and concrete or metal tanks. The water collected in these reservoirs is at risk of contamination. During the period March-July 2002, the three types of reservoirs from 368 households were surveyed for presence of Escherichia coli and Cryptosporidium parvum, indicators of contamination. The cistern was the most contaminated reservoir with 17% (95% CI: 13,22) for E. coli (significant, P<0.05), and 2% (95% CI: 1,4) for C. parvum. Only 1% (95% CI: 1,6) of the metal reservoirs had E. coli, while concrete reservoirs were free. No C. parvum oocysts were detected in either the concrete or metal reservoirs. Reservoirs opening at floor level and the bucket kept outside the reservoir were significant (P<0.05) enhancing risk factors for contamination with C. parvum.

Solving Wakulla Springs underwater mysteries. Using GPS to map Florida's underground caverns

USGS Publications Warehouse

Am, Ende B.

2002-01-01

Located in the Woodville Karst Plain stretching south from Tallahassee to the Gulf of Mexico, Florida's Wakulla Springs is one of the largest and deepest freshwater Springs in the world. It is also a gateway into one of the longest underwater cave system in the United States, a system that remained largely unexplored until recently. Soon, however, thanks to one of the world's most extreme scientific and exploration-related diving projects ever undertaken, visitors to Wakulla Springs State Park will be able to take a virtual tour through the Spring's huge underwater labyrinth. Using such cutting-edge technology as a 3D Digital Wall Mapper (DWM) and the Global Positioning System (GPS), the Wakulla 2 Expedition - with 151 volunteer cave divers, scientists and engineers from all over the world - created the world's first three-dimensional digital map of an underwater cave. Underwater caves are priceless treasures, helping supply fresh water to the region as well as acting as 'time capsules' to the past. Home to creatures found in few other places, areas such as Wakulla face threats of pollution and over-development. Wakulla 2 hopes their 3D interactive 'swim through' will help increase the understanding and preservation of these important areas.

Prediction, time variance, and classification of hydraulic response to recharge in two karst aquifers

USGS Publications Warehouse

Long, Andrew J.; Mahler, Barbara J.

2013-01-01

Many karst aquifers are rapidly filled and depleted and therefore are likely to be susceptible to changes in short-term climate variability. Here we explore methods that could be applied to model site-specific hydraulic responses, with the intent of simulating these responses to different climate scenarios from high-resolution climate models. We compare hydraulic responses (spring flow, groundwater level, stream base flow, and cave drip) at several sites in two karst aquifers: the Edwards aquifer (Texas, USA) and the Madison aquifer (South Dakota, USA). A lumped-parameter model simulates nonlinear soil moisture changes for estimation of recharge, and a time-variant convolution model simulates the aquifer response to this recharge. Model fit to data is 2.4% better for calibration periods than for validation periods according to the Nash–Sutcliffe coefficient of efficiency, which ranges from 0.53 to 0.94 for validation periods. We use metrics that describe the shapes of the impulse-response functions (IRFs) obtained from convolution modeling to make comparisons in the distribution of response times among sites and between aquifers. Time-variant IRFs were applied to 62% of the sites. Principal component analysis (PCA) of metrics describing the shapes of the IRFs indicates three principal components that together account for 84% of the variability in IRF shape: the first is related to IRF skewness and temporal spread and accounts for 51% of the variability; the second and third largely are related to time-variant properties and together account for 33% of the variability. Sites with IRFs that dominantly comprise exponential curves are separated geographically from those dominantly comprising lognormal curves in both aquifers as a result of spatial heterogeneity. The use of multiple IRF metrics in PCA is a novel method to characterize, compare, and classify the way in which different sites and aquifers respond to recharge. As convolution models are developed for

Karst medium characterization and simulation of groundwater flow in Lijiang Riversed, China

NASA Astrophysics Data System (ADS)

Hu, B. X.

2015-12-01

It is important to study water and carbon cycle processes for water resource management, pollution prevention and global warming influence on southwest karst region of China. Lijiang river basin is selected as our study region. Interdisciplinary field and laboratory experiments with various technologies are conducted to characterize the karst aquifers in detail. Key processes in the karst water cycle and carbon cycle are determined. Based on the MODFLOW-CFP model, new watershed flow and carbon cycle models are developed coupled subsurface and surface water flow models, flow and chemical/biological models. Our study is focused on the karst springshed in Mao village. The mechanisms coupling carbon cycle and water cycle are explored. Parallel computing technology is used to construct the numerical model for the carbon cycle and water cycle in the small scale watershed, which are calibrated and verified by field observations. The developed coupling model for the small scale watershed is extended to a large scale watershed considering the scale effect of model parameters and proper model structure simplification. The large scale watershed model is used to study water cycle and carbon cycle in Lijiang rivershed, and to calculate the carbon flux and carbon sinks in the Lijiang river basin. The study results provide scientific methods for water resources management and environmental protection in southwest karst region corresponding to global climate change. This study could provide basic theory and simulation method for geological carbon sequestration in China karst region.

Hydrological and geochemical processes constraining groundwater salinity in wetland areas related to evaporitic (karst) systems. A case study from Southern Spain

NASA Astrophysics Data System (ADS)

Gil-Márquez, J. M.; Barberá, J. A.; Andreo, B.; Mudarra, M.

2017-01-01

Chemical and isotopic evolution of groundwater in an evaporite karst plateau (including wetland areas and saline to hyper-saline springs) located at S Spain was studied. Physicochemical parameters, major ions and stable isotopes were analyzed in rain, brine spring, wetland and leakage water samples, from which the most common mineral saturation indexes were computed and geochemical and isotopic modelling were performed. Results show an apparent relationship between the elevation of brine springs and their water mineralization, indicating that drainage at higher altitude may be associated to gravity-driven flows, since brackish groundwater is isotopically fractionated due to evaporation. On the other hand, the lower altitude springs could drain deeper flows with longer residence time, resulting in highly mineralized and warmer (briny) groundwater. The dissolution of halite and gypsum has proved to be the main geochemical processes, which are favored by the great ionic strength of groundwater. Calcite precipitation occurs in brackish waters draining wetlands, being boosted by common ion effect (when CaSO4 waters are present) and solute concentration caused by evaporation. Modelling results strongly support the hypothesis that most of the selected springs geochemically evolve in a common (S-N) flowpath. The methods used in this research contribute to a better understanding of the hydrogeological processes occurring in the studied evaporitic system, but also in equivalent hydrological environments worldwide.

Continuous gravimetric monitoring as an integrative tool for exploring hydrological processes in the Lomme Karst System (Belgium)

NASA Astrophysics Data System (ADS)

Watlet, A.; Van Camp, M. J.; Poulain, A.; Hallet, V.; Rochez, G.; Quinif, Y.; Meus, P.; Kaufmann, O.; Francis, O.

2016-12-01

Karst systems are highly heterogeneous which makes their hydrology difficult to understand. Geophysical techniques offer non-invasive and integrative methods that help interpreting such systems as a whole. Among these techniques, gravimetry has been increasingly used in the last decade to characterize the hydrological behavior of complex systems, e.g. karst environments or volcanoes. We present a continuous microgravimetric monitoring of 3 years in the karstic area of Rochefort (Belgium), that shows multiple occurrences of caves and karstic features. The gravity record includes measurements of a GWR superconducting gravimeter, a Micro-g LaCoste gPhone and an absolute FG5 gravimeter. Together with meteorological measurements and a surface/in-cave hydrogeological monitoring, we were able to improve the knowledge of hydrological processes. On the one hand, the data allowed identifying seasonal groundwater content changes in the unsaturated zone of the karst area, most likely to be linked to temporary groundwater storage occurring in the most karstified layers closed to the surface. Combined with additional geological information, modelling of the gravity signal based on the vertical potential of the gravitational attraction was then particularly useful to estimate the seasonal recharge leading to the temporary subsurface groundwater storage. On the other hand, the gravity monitoring of flash floods occurring in deeper layers after intense rainfall events informed on the effective porosity gradient of the limestones. Modelling was then helpful to identify the hydrogeological role played by the cave galleries with respect to the hosting limestones during flash floods. These results are also compared with measurements of an in-cave gravimetric monitoring performed with a gPhone spring gravimeter. An Electrical Resistivity Tomography monitoring is also conducted at site and brings additional information useful to verify the interpretation made with the gravimetric

Karst Lands: The dissolution of carbonate rock produces unique landscapes and poses significant hydrological and environmental concerns

DOE Office of Scientific and Technical Information (OSTI.GOV)

White, W.B.; Culver, D.C.; Herman, J.S.

1995-09-01

Karst lands are produced by the action of water on soluble rocks, a process among the most dynamic of all erosive forces that counterbalance the uplifting forces of tectonics. The dissolution of carbonate rock, primarily limestone and dolomite, produces unique landscapes and poses significant hydrological and environmental concerns. The major topic areas discussed in this article include the following: processes that form karst; karst drainage basins; discharge from karst aquifers; caves as paleoclimatic recorders; caves as ecosystems; water issues in karst regions; and sinkholes, soil piping and subsidence. 20 refs., 9 figs.

Caves, Carbonates and Climate: Karst Landscape Development through Environmental Forcing, Little Cayman Island

NASA Astrophysics Data System (ADS)

Hsia, S.; Ouellette, G., Jr.; Manfrino, C.

2016-12-01

The Cayman Islands are situated in the west-central Caribbean Sea, between Cuba and the Yucatan Peninsula. Little Cayman Island (LCI) is relatively underdeveloped and understudied in comparison to its sister islands, Grand Cayman and Cayman Brac, and hosts less than 200 permanent residents over a 30 square kilometer area. However, like its sister islands, LCI is a small carbonate platform derived from reef building during the Oligocene, Miocene, and Quaternary. The shared geologic history of the Cayman Islands along with minimal human disturbance makes LCI an ideal site to study an island karst landscape. Conduction of field surveys, stratigraphic and petrologic comparisons between primary lithologic formations, and compilation of a geospatial inventory of karst features and lithology of LCI using GIS revealed novel insights into landscape evolution on LCI. In addition to surface karst surveys, several caves on the island were mapped. Cave morphologies suggest that evolution of LCI karst features have been driven by both hydroclimate, as well as salt and freshwater mixing, modulated by sea level fluctuations. These findings are mirrored in the lithology of partially dolomitized Miocene carbonates, which contain paleo-karst fill features and reveal hydroclimate influence, as well as enhanced resistance to dissolution in the present day, ostensibly from submersion in Mg-rich sea waters prior to the Quaternary. These findings shed light on the complex relationship of climate, geology, and karst landscape development on this particular carbonate island. This information is critical in anticipating structural and hydrogeological integrity on LCI under future climate change scenarios and serves as an example of the interplay linking climate and geologic processes to karst landscape development on small carbonate islands.

The soil biota composition along a progressive succession of secondary vegetation in a karst area.

PubMed

Zhao, Jie; Li, Shengping; He, Xunyang; Liu, Lu; Wang, Kelin

2014-01-01

Karst ecosystems are fragile and are in many regions degraded by anthropogenic activities. Current management of degraded karst areas focuses on aboveground vegetation succession or recovery and aims at establishing a forest ecosystem. Whether progressive succession of vegetation in karst areas is accompanied by establishment of soil biota is poorly understood. In the present study, soil microbial and nematode communities, as well as soil physico-chemical properties were studied along a progressive succession of secondary vegetation (from grassland to shrubland to forest) in a karst area in southwest China. Microbial biomass, nematode density, ratio of fungal to bacterial biomass, nematode structure index, and nematode enrichment index decreased with the secondary succession in the plant community. Overall, the results indicated a pattern of declines in soil biota abundance and food web complexity that was associated with a decrease in soil pH and a decrease in soil organic carbon content with the progressive secondary succession of the plant community. Our findings suggest that soil biota amendment is necessary during karst ecosystem restoration and establishment and management of grasslands may be feasible in karst areas.

Relationship among land surface temperature and LUCC, NDVI in typical karst area.

PubMed

Deng, Yuanhong; Wang, Shijie; Bai, Xiaoyong; Tian, Yichao; Wu, Luhua; Xiao, Jianyong; Chen, Fei; Qian, Qinghuan

2018-01-12

Land surface temperature (LST) can reflect the land surface water-heat exchange process comprehensively, which is considerably significant to the study of environmental change. However, research about LST in karst mountain areas with complex topography is scarce. Therefore, we retrieved the LST in a karst mountain area from Landsat 8 data and explored its relationships with LUCC and NDVI. The results showed that LST of the study area was noticeably affected by altitude and underlying surface type. In summer, abnormal high-temperature zones were observed in the study area, perhaps due to karst rocky desertification. LSTs among different land use types significantly differed with the highest in construction land and the lowest in woodland. The spatial distributions of NDVI and LST exhibited opposite patterns. Under the spatial combination of different land use types, the LST-NDVI feature space showed an obtuse-angled triangle shape and showed a negative linear correlation after removing water body data. In summary, the LST can be retrieved well by the atmospheric correction model from Landsat 8 data. Moreover, the LST of the karst mountain area is controlled by altitude, underlying surface type and aspect. This study provides a reference for land use planning, ecological environment restoration in karst areas.

Exploring the relationship between vegetation spectra and eco-geo-environmental conditions in karst region, Southwest China.

PubMed

Yue, Yuemin; Wang, Kelin; Zhang, Bing; Chen, Zhengchao; Jiao, Quanjun; Liu, Bo; Chen, Hongsong

2010-01-01

Remote sensing of local environmental conditions is not accessible if substrates are covered with vegetation. This study explored the relationship between vegetation spectra and karst eco-geo-environmental conditions. Hyperspectral remote sensing techniques showed that there were significant differences between spectral features of vegetation mainly distributed in karst and non-karst regions, and combination of 1,300- to 2,500-nm reflectance and 400- to 680-nm first-derivative spectra could delineate karst and non-karst vegetation groups. Canonical correspondence analysis (CCA) successfully assessed to what extent the variation of vegetation spectral features can be explained by associated eco-geo-environmental variables, and it was found that soil moisture and calcium carbonate contents had the most significant effects on vegetation spectral features in karst region. Our study indicates that vegetation spectra is tightly linked to eco-geo-environmental conditions and CCA is an effective means of studying the relationship between vegetation spectral features and eco-geo-environmental variables. Employing a combination of spectral and spatial analysis, it is anticipated that hyperspectral imagery can be used in interpreting or mapping eco-geo-environmental conditions covered with vegetation in karst region.

A new species of karst forest Bent-toed Gecko (genus Cyrtodactylus Gray) not yet threatened by foreign cement companies and a summary of Peninsular Malaysia's endemic karst forest herpetofauna and the need for its conservation.

PubMed

Grismer, L Lee; Wood, P L Jr; Anuar, Shahrul; Davis, H R; Cobos, A J; Murdoch, M L

2016-01-04

A new species of Bent-toed Gecko, Cyrtodactylus gunungsenyumensis sp. nov. of the sworderi complex, is described from Hutan Lipur Gunung Senyum, Pahang, Peninsular Malaysia and is differentiated from all other species in the sworderi complex by having a unique combination of characters including a maximum SVL of 74.7 mm; low, rounded, weakly keeled, body tubercles; 34-40 paravertebral tubercles; weak ventrolateral body fold lacking tubercles; 38-41 ventral scales; an abrupt transition between the posterior and ventral femoral scales; 20-23 subdigital lamellae on the fourth toe; enlarged femoral scales; no femoral or precloacal pores; no precloacal groove; wide caudal bands; and an evenly banded dorsal pattern. Cyrtodactylus gunungsenyumensis sp. nov. is a scansorial, karst forest-adapted specialist endemic to the karst ecosystem surrounding Gunung Senyum and occurs on the vertical walls of the limestone towers as well as the branches, trunks, and leaves of the vegetation in the associated karst forest. Cyrtodactylus gunungsenyumensis sp. nov. is the seventh species of karst forest-adapted Cyrtodactylus and the sixteenth endemic species of karst ecosystem reptile discovered in Peninsular Malaysia in the last seven years from only 12 different karst forests. This is a clear indication that many species remain to be discovered in the approximately 558 isolated karst ecosystems in Peninsular Malaysia not yet surveyed. These data continue to underscore the importance of karst ecosystems as reservoirs of biodiversity and microendemism and that they constitute an important component of Peninsular Malaysia's natural heritage and should be protected from the quarrying interests of foreign industrial companies.

Development of a 3D GIS and its application to karst areas

NASA Astrophysics Data System (ADS)

Wu, Qiang; Xu, Hua; Zhou, Wanfang

2008-05-01

There is a growing interest in modeling and analyzing karst phenomena in three dimensions. This paper integrates geology, groundwater hydrology, geographic information system (GIS), database management system (DBMS), visualization and data mining to study karst features in Huaibei, China. The 3D geo-objects retrieved from the karst area are analyzed and mapped into different abstract levels. The spatial relationships among the objects are constructed by a dual-linker. The shapes of the 3D objects and the topological models with attributes are stored and maintained in the DBMS. Spatial analysis was then used to integrate the data in the DBMS and the 3D model to form a virtual reality (VR) to provide analytical functions such as distribution analysis, correlation query, and probability assessment. The research successfully implements 3D modeling and analyses in the karst area, and meanwhile provides an efficient tool for government policy-makers to set out restrictions on water resource development in the area.

A compact field fluorometer and its application to dye tracing in karst environments

NASA Astrophysics Data System (ADS)

Poulain, Amaël; Rochez, Gaëtan; Van Roy, Jean-Pierre; Dewaide, Lorraine; Hallet, Vincent; De Sadelaer, Geert

2017-08-01

Dye tracing is a classic technique in hydrogeology to investigate surface-water or groundwater flow characteristics, and it is useful for many applications including natural or industrial issues. The Fluo-Green field fluorometer has been successfully tested in a karst environment and is specifically suitable for in-cave karst water monitoring. Karst research often uses dyes to obtain information about groundwater flow in unexplored cave passages. The compact device, alternatively named Fluo-G, meets the requirements of cave media: small (10 × 16 × 21 cm), lightweight (0.75 kg without ballast) and simple in conception. It is easy for cavers to set up and handle compared to other sampling methods. The fluorometer records uranine, turbidity and temperature with a user-defined time-step (1 min - 1 day). Very low energy consumption allows 9,000 measurements with six AA batteries. The device was calibrated and tested in the laboratory and in field conditions in Belgian karst systems. Results are in good fit with other sampling methods: in-situ fluorometers and automatic water sampling plus laboratory analysis. Recording high quality data (breakthrough curves) in karst with in-cave monitoring is valuable to improve knowledge of karst systems. Many hydrological and hydrogeological applications can benefit from such a low-cost and compact device, and finding the best compromise between resources and quality data is essential. Several improvements are possible but preliminary field tests are very promising.

Natural hazards in Slovene karst areas: Flood risk areas in the Upper Pivka valley

NASA Astrophysics Data System (ADS)

Ravbar, N.; Kovacic, G.

2009-04-01

An overview of exceptional natural processes or natural hazards from the human perspective in Slovene karst areas is made. Some types of natural hazards are typical for karst due to the process of karstification and resulting geomorphological and hydrological characteristics of karst landscapes (presence of voids within the rock, absence of superficial flow and presence of specific karst groundwater flow system), while the others occur evenly in all types of landscapes. However, their impact is different in karst as it is in the non-karst landscapes. Examples of particular phenomenon or events, their frequency of occurrence, expansion and caused damage are presented. Special emphasis is laid on high waters in karst poljes, shallow karst areas or contact karst, where flooding emerges due to the raise of karst groundwater table as a consequence of intensive precipitation or snowmelt. Flooding in karst can also appear due to insufficient swallow capacities of the underground channels, which are not capable of conducting surpluses of inflowing water. In opposite to flash floods, the karst floods are more predictable, since they usually occur in the same areas to the same elevation and in the same season of the year. Inhabitants are easily adapted to this phenomenon, setting the settlements and other important infrastructure on elevations above the highest recorded water level. Usually such flooding does not pose serious threat and causes no serious flood damage, except during extreme events, as it was in the case of the autumn 2000 floods. Case study of the Upper Pivka valley, where floods usually cover around 6.6 km2, is treated and explained. During the intensive rain period from September to November 2000, the groundwater table rose for about 20-35 m above the usual level, causing flooding also in the areas, where they have never been recorded before. Precise mapping of the flooded area extents in the discussed area and the height of the water levels was performed

Leaf trait variations associated with habitat affinity of tropical karst tree species.

PubMed

Geekiyanage, Nalaka; Goodale, Uromi Manage; Cao, Kunfang; Kitajima, Kaoru

2018-01-01

Karst hills, that is, jagged topography created by dissolution of limestone and other soluble rocks, are distributed extensively in tropical forest regions, including southern parts of China. They are characterized by a sharp mosaic of water and nutrient availability, from exposed hilltops with poor soil development to valleys with occasional flooding, to which trees show species-specific distributions. Here we report the relationship of leaf functional traits to habitat preference of tropical karst trees. We described leaf traits of 19 tropical tree species in a seasonal karst rainforest in Guangxi Province, China, 12 species in situ and 13 ex situ in a non-karst arboretum, which served as a common garden, with six species sampled in both. We examined how the measured leaf traits differed in relation to species' habitat affinity and evaluated trait consistency between natural habitats vs . the arboretum. Leaf mass per area (LMA) and optical traits (light absorption and reflectance characteristics between 400 and 1,050 nm) showed significant associations with each other and habitats, with hilltop species showing high values of LMA and low values of photochemical reflectance index (PRI). For the six species sampled in both the karst forest and the arboretum, LMA, leaf dry matter content, stomatal density, and vein length per area showed inconsistent within-species variations, whereas some traits (stomatal pore index and lamina thickness) were similar between the two sites. In conclusion, trees specialized in exposed karst hilltops with little soils are characterized by thick leaves with high tissue density indicative of conservative resources use, and this trait syndrome could potentially be sensed remotely with PRI.

An Examination of the Application of Professional Reliance To Management of Karst Resources In British Columbia (Canada)

NASA Astrophysics Data System (ADS)

Ramsey, Carolyn L.; Griffiths, Paul A.

2010-05-01

British Columbia (BC), Canada's most ecologically diverse province, is home to some of the nation's finest karst resources. Many of these are in forested settings, and are often associated with special/unique natural attributes ranging from geomorphology to hydrology, biology and ecology. Karst management in BC forests was shaped initially by concerns for caves and their recreation management, but as of 1997 there was a significant shift to an ecosystem approach to management of karst and cave resources. This new management approach was supported in due course by standards and guidelines for karst assessment and management. The approach also recognized the inherently multidisciplinary nature of this type of work and the frequent need to engage professionals with specialized knowledge of karst, and its natural and cultural resource values. In 2004, the BC Government introduced the Forest and Range Practices Act, a new results-based regulatory framework for forest practices. Government orders made pursuant to regulations under the Act identify categories of karst terrain and associated resource features that must be protected from the potentially damaging effects of roadbuilding and road maintenance, timber harvesting, and silviculture activities. In support of a general shift toward more results-based regulation and "freedom to manage" forest resources, it was argued that the forestry sector and its professionals are qualified, and competent enough, to formulate strategies for protecting and managing forest resources (including karst) without as much government oversight. As a result, forest tenure holders and their professionals are now responsible for assessing protected categories of karst resource features and developing and applying appropriate forest practices for them. Where knowledge beyond the area of forest professionals' expertise is required, the knowledge gaps are to be addressed by hiring suitably qualified professional consultants for advice and

The Soil Biota Composition along a Progressive Succession of Secondary Vegetation in a Karst Area

PubMed Central

He, Xunyang; Liu, Lu; Wang, Kelin

2014-01-01

Karst ecosystems are fragile and are in many regions degraded by anthropogenic activities. Current management of degraded karst areas focuses on aboveground vegetation succession or recovery and aims at establishing a forest ecosystem. Whether progressive succession of vegetation in karst areas is accompanied by establishment of soil biota is poorly understood. In the present study, soil microbial and nematode communities, as well as soil physico-chemical properties were studied along a progressive succession of secondary vegetation (from grassland to shrubland to forest) in a karst area in southwest China. Microbial biomass, nematode density, ratio of fungal to bacterial biomass, nematode structure index, and nematode enrichment index decreased with the secondary succession in the plant community. Overall, the results indicated a pattern of declines in soil biota abundance and food web complexity that was associated with a decrease in soil pH and a decrease in soil organic carbon content with the progressive secondary succession of the plant community. Our findings suggest that soil biota amendment is necessary during karst ecosystem restoration and establishment and management of grasslands may be feasible in karst areas. PMID:25379741

Physical and hydrochemical evidence of lake leakage near Jim Woodruff lock and dam and ground-water inflow to Lake Seminole, and an assessment of karst features in and near the lake, southwestern Georgia and northwestern Florida

USGS Publications Warehouse

Torak, Lynn J.; Crilley, Dianna M.; Painter, Jaime A.

2006-01-01

Hydrogeologic data and water-chemistry analyses indicate that Lake Seminole leaks into the Upper Floridan aquifer near Jim Woodruff Lock and Dam, southwestern Georgia and northwestern Florida, and that ground water enters Lake Seminole along upstream reaches of the lake's four impoundment arms (Chattahoochee and Flint Rivers, Spring Creek, and Fishpond Drain). Written accounts by U.S. Army Corps of Engineers geologists during dam construction in the late 1940s and early 1950s, and construction-era photographs, document karst-solution features in the limestone that comprise the lake bottom and foundation rock to the dam, and confirm the hydraulic connection of the lake and aquifer. More than 250 karst features having the potential to connect the lake and aquifer were identified from preimpoundment aerial photographs taken during construction. An interactive map containing a photomosaic of 53 photographic negatives was orthorectfied to digital images of 1:24,000-scale topographic maps to aid in identifying karst features that function or have the potential to function as locations of water exchange between Lake Seminole and the Upper Floridan aquifer. Some identified karst features coincide with locations of mapped springs, spring runs, and depressions that are consistent with sinkholes and sinkhole ponds. Hydrographic surveys using a multibeam echosounder (sonar) with sidescan sonar identified sinkholes in the lake bottom along the western lakeshore and in front of the dam. Dye-tracing experiments indicate that lake water enters these sinkholes and is transported through the Upper Floridan aquifer around the west side of the dam at velocities of about 500 feet per hour to locations where water 'boils up' on land (at Polk Lake Spring) and in the channel bottom of the Apalachicola River (at the 'River Boil'). Water discharging from Polk Lake Spring joins flow from a spring-fed ground-water discharge zone located downstream of the dam; the combined flow disappears into

Field Investigation and Modeling Development for Hydrological and Carbon Cycles in Southwest Karst Region of China

NASA Astrophysics Data System (ADS)

Hu, X. B.

2017-12-01

It is required to understanding water cycle and carbon cycle processes for water resource management and pollution prevention and global warming influence in southwest karst region of China. Lijiang river basin is selected as our study region. Interdisciplinary field and laboratory experiments with various technologies are conducted to characterize the karst aquifers in detail. Key processes in the karst water cycle and carbon cycle are determined. Based on the MODFLOW-CFP model, new watershed flow and carbon cycle models are developed coupled subsurface and surface water flow models. Our study focus on the karst springshed in Mao village, the mechanisms coupling carbon cycle and water cycle are explored. This study provides basic theory and simulation method for water resource management and groundwater pollution prevention in China karst region.

Combined use of natural and artificial tracers to determine the hydrogeological functioning of a karst aquifer: the Villanueva del Rosario system (Andalusia, southern Spain)

NASA Astrophysics Data System (ADS)

Mudarra, M.; Andreo, B.; Marín, A. I.; Vadillo, I.; Barberá, J. A.

2014-08-01

Analysis of natural responses of karst springs provides information on the behavior of the aquifers they drain. Detailed monitoring and qualitative and quantitative analyses of natural responses, and environmental—total organic carbon (TOC), NO3 -, Cl- and intrinsic fluorescence—and artificial (fluorescent dye) tracers, in the water drained by Villanueva del Rosario spring (southern Spain), suggest the existence of a conduit flow system with rapid flows and very short transit times of water through the aquifer. This is in agreement with uranine and eosin breakthrough curves and with simple numerical models done using these data. However, due to the low capacity for natural regulation, not all the recharge effects are simultaneously transmitted to the spring water; given a single input, the system modulates and transfers hydrodynamic variations faster than variations of chemical composition and of water temperature. Additionally, time lags between maximum concentrations of natural and artificial tracers show that the global system response (including diffuse infiltration) is faster and more sensitive than that produced from infiltration concentrated at a single point on the surface (sinkholes).

Evaluating disturbance on mediterranean karst areas: the example of Sardinia (Italy)

NASA Astrophysics Data System (ADS)

de Waele, Jo

2009-07-01

Evaluating the human disturbance on karst areas is a difficult task because of the complexity of these peculiar and unique environments. The human impact on karstic geo-ecosystems is increasingly important and there is an increasing need for multidisciplinary tools to assess the environmental changes in karst areas. Many disciplines, such as biology, geomorphology, hydrology and social-economical sciences are to be considered to sufficiently evaluate the impact on these intrinsically vulnerable areas. This article gives an overview of the evolution of environmental impact on karst areas of the island Sardinia (Italy). For this particular case, the most important impacts in the past 50 years are derived from the following activities, in decreasing importance: (1) mining and quarrying; (2) deforestation, agriculture and grazing; (3) building (widespread urbanisation, isolated homes, etc.) and related infrastructures (roads, sewer systems, aqueducts, waste dumps, etc.); (4) tourism; (5) military activities. To evaluate the present environmental state of these areas the Disturbance Index for Karst environments [Van Beynen and Townsend (Environ Manage 36:101-116)] is applied in a slightly modified version. Instead of considering the indicators of environmental disturbances used in the original method, this slightly modified index evaluates the disturbances causing the deterioration of the environmental attributes. In the Sardinian case study, 27 disturbances have been evaluated, giving rise to the definition of a Disturbance Index ranging between 0 (Pristine) and 1 (highly disturbed). This Disturbance Index simplifies the original KDI method, appears to adequately measure disturbance on Mediterranean karst areas and could be applied with success to other similar regions.

Variations of the spatiotemporal patterns of CVOCs concentrations in northern karst of Puerto Rico

NASA Astrophysics Data System (ADS)

Yu, X.; Ghasemizadeh, R.; Padilla, I. Y.; Irizarry, C.; Yegen, C.; Kaeli, D.; Alshawabkeh, A. N.

2013-12-01

The northern Puerto Rico is characterized as karst topography, where the groundwater is a major source of water use to the island. Various types of Chlorinated Volatile Organic Compounds (CVOCs), which are due to improper disposal of industrial waste, are detected in these karst aquifers. It is important to study the spatiotemporal distribution patterns of the CVOCs in this region, which are posing a serious threat to both the ecological and human health. In this study, various historical CVOCs data from 264 wells across the northern karst region from January 1982 to December 2000 were collected from a number of reports and studies. We found that 38% (99 out of 264) of the sites had at least one sample with CVOC concentration above the standards established to protect human health over the study period. We found that the distribution of the CVOCs spatially varied with areas containing clusters of sites contaminated by different organic compound. The response of CVOC concentrations were occasionally retarded even though they were depleted significantly in the source zones. The study confirmed that the measured CVOC concentrations decreased during the study period at most of the sites. The source origin (toxics release locations and quantities) and the intrinsic characteristics of the karst (high heterogeneity and complex hydraulic behavior) are most likely related with the spatial and temporal distribution patterns of CVOCs. The study of the spatiotemporal patterns of CVOCs concentrations in the northern karst aquifers has important implications on the public water use, especially when it coincides with the recent population growth in this region. Locations of Puerto Rico, the northern karst region of Puerto Rico and 264 sampling sites in the karst region.

Accidental contamination during hydrocarbon exploitation and the rapid transfer of heavy-mineral fines through an overlying highly karstified aquifer (Paradiso Spring, SE Sicily)

NASA Astrophysics Data System (ADS)

Ruggieri, Rosario; Forti, Paolo; Antoci, Maria Lucia; De Waele, Jo

2017-03-01

The area around Ragusa in Sicily is well known for the exploration of petroleum deposits hosted in Mesozoic carbonate rocks. These reservoirs are overlain by less permeable rocks, whereas the surface geology is characterized by outcrops of Oligo-Miocene carbonate units hosting important aquifers. Some of the karst springs of the area are used as drinking water supplies, and therefore these vulnerable aquifers should be monitored and protected adequately. In the early afternoon (14:00) of 27 May until the late evening (19:30) of 28 May 2011, during the construction of an exploitation borehole (Tresauro 2), more than 1000 m3 of drilling fluids were lost in an unknown karst void. Two days later, from 06:30 on 30 May, water flowing from Paradiso Spring, lying some 13.7 km SW of the borehole and 378 m lower, normally used as a domestic water supply, was so intensely coloured that it was unfit for drinking. Bulk chemical analyses carried out on the water have shown a composition that is very similar to that of the drilling fluids lost at the Tresauro borehole, confirming a hydrological connection. Estimations indicate that the first signs of the drilling fluids took about 59 h to flow from their injection point to the spring, corresponding to a mean velocity of ∼230 m/h. That Paradiso Spring is recharged by a well-developed underground drainage system is also confirmed by the marked flow rate changes measured at the spring, ranging from a base flow of around 10-15 l/s to flood peaks of 2-3 m3/s. Reflecting the source and nature of the initial contamination, the pollution lasted for just a few days, and the water returned to acceptable drinking-water standards relatively quickly. However, pollution related to heavy-mineral fines continues to be registered during flooding of the spring, when the aqueducts are normally shut down because of the high turbidity values. This pollution event offers an instructive example of how hydrocarbon exploitation in intensely karstified

Karst connections between unconfined aquifers and the Upper Floridan aquifer in south Georgia: geophysical evidence and hydrogeological models

NASA Astrophysics Data System (ADS)

Thieme, D. M.; Denizman, C.

2011-12-01

Buried karst features in sedimentary rocks of the south Georgia Coastal Plain present a challenge for hydrogeological models of recharge and confined flow within the underlying Upper Floridan aquifer. The Withlacoochee River, the trunk stream for the area, frequently disappears into subsurface caverns as it makes its way south to join the Suwannee River in northern Florida. The Withlacoochee also receives inputs from small ponds and bays which in turn receive spring and seep groundwater inputs. We have mapped karst topography at the "top of rock" using ground-penetrating radar (GPR). Up to seven meters of relief is indicated for the paleotopography on Miocene to Pliocene rocks, contrasting with the more subdued relief of the modern landscape. Current stratigraphic and hydrogeological reconstructions do not incorporate this amount of relief or lateral variation in the confining beds. One "pipe" which is approximately four meters in diameter is being mapped in detail. We have field evidence at this location for rapid movement of surficial pond and river water with a meteoric signature through several separate strata of sedimentary rock into an aquifer in the Hawthorn formation. We use our geophysical and hydrological field evidence to constrain quantitative hydrogeological models for the flow rates into and out of both this upper aquifer and the underlying Upper Floridan aquifer, which is generally considered to be confined by the clays of the Hawthorn.

The newest findings on Red Lake (Dinaric karst of Croatia)

NASA Astrophysics Data System (ADS)

Andrić, Ivo; Jukić, Branimir

2014-05-01

Red Lake in the Dinaric karst (Croatia) is of the deepest karst lakes in the world. Even so, through the history of Red Lake's research there were many controversies in the conclusions and the theories concerning its genesis, geomorphology and hydrology. This work has for a goal to present the newest research results won with the help of emerging technologies based on LiDAR and SoNAR methods. The measurements took place during September 2013. New generation of equipment developed to advance the geoscientific research has been deployed during the field work and the gathered data enabled the analysis which led to a new understanding of the lake's morphology. Some of the results confirmed already known and well documented features of Red Lake whereas others disputed widely accepted assumptions in the scientific community and general public. The objective of this paper is also groundwork for further research in the field of karst hydrology and a new insight on local and regional scale.

Evaluation of karst water quality as an early reference of land suitability mapping for vaname shrimp (Litopenaeusvannamei) culture media

NASA Astrophysics Data System (ADS)

Wildan, D. M.; Affandi, R.; Pratiwi, N. T. M.; Krisanti, M.; Ayu, I. P.; Iswantari, A.

2017-01-01

Vaname shrimp (Litopenaeusvannamei) is one of the excellent fishery commodities in Indonesia. Vaname shrimp farming can be conducted in low salinity water. Low salinity water sources which could be used as culture media is karst water because it has a high mineral. The research was aimedto evaluate land suitability mapping for pond as the vaname shrimpculture mediaseen from the water quality. Research was conducted in May and August 2016. Water sampling was conducted in several locations; Ancol-Jakarta (seawater), Ciseeng-Bogor (karst water salinity), Ciampea-Bogor (karst freshwater), and Situ Gede Bogor (freshwater). Evaluating the suitability of karst water quality for vaname shrimp culture media, done by the results of karst water quality analysis compared with seawater and SNI 01-7246-2006 on shrimp vaname culture media. The results showed that Karst water of Ciseeng and Ciampea could not directly use as vaname shrimp culture media. It is needed water quality treatment of ozonation and aeration of karst water to improve water quality. Ozonation and aeration treatments were able to improve the quality of karst water up to approach the living quality standard of vaname shrimp media.

Organic Carbon Storage in Four Ecosystem Types in the Karst Region of Southwestern China

PubMed Central

Wang, Shijie; Guo, Ke; Yang, Jun; Zhang, Xinshi; Li, Guoqing

2013-01-01

Karst ecosystems are important landscape types that cover about 12% of the world's land area. The role of karst ecosystems in the global carbon cycle remains unclear, due to the lack of an appropriate method for determining the thickness of the solum, a representative sampling of the soil and data of organic carbon stocks at the ecosystem level. The karst region in southwestern China is the largest in the world. In this study, we estimated biomass, soil quantity and ecosystem organic carbon stocks in four vegetation types typical of karst ecosystems in this region, shrub grasslands (SG), thorn shrubbery (TS), forest - shrub transition (FS) and secondary forest (F). The results showed that the biomass of SG, TS, FS, and F is 0.52, 0.85, 5.9 and 19.2 kg m−2, respectively and the corresponding organic cabon storage is 0.26, 0.40, 2.83 and 9.09 kg m−2, respectively. Nevertheless, soil quantity and corresponding organic carbon storage are very small in karst habitats. The quantity of fine earth overlaying the physical weathering zone of the carbonate rock of SG, TS, FS and F is 38.10, 99.24, 29.57 and 61.89 kg m−2, respectively, while the corresponding organic carbon storage is only 3.34, 4.10, 2.37, 5.25 kg m−2, respectively. As a whole, ecosystem organic carbon storage of SG, TS, FS, and F is 3.81, 4.72, 5.68 and 15.1 kg m−2, respectively. These are very low levels compared to other ecosystems in non-karst areas. With the restoration of degraded vegetation, karst ecosystems in southwestern China may play active roles in mitigating the increasing CO2 concentration in the atmosphere. PMID:23451047

Hazards in the coastal karst of Balai (NW Sardinia, Italy)

NASA Astrophysics Data System (ADS)

Sanna, Laura; Uda, Michele; Pascucci, Vincenzo

2016-04-01

The coastal karst area of Balai headland is located in the central part of the Gulf of Asinara (North-West Sardinia, Italy) near the city of Porto Torres, comprised between the homonymous harbour and Platamona beach. This karst plateau has a monocline geometry truncated by the coastal escarpment, up to 40 m-high, that in the last decades has been affected by slope instability related to human activities and/or climate change. The area is characterised by a flat morphology constituted of Miocene limestone gently dipping towards the North-West. Its altitude ranges from 0 to 50 m asl. The 3 km-long cliff is locally interrupted by some small gravelly coves. Along the longitudinal profile of the headland, three main morphological steps have been identified at 15, 8 and 6.5 m asl. They represent past wave cut platforms. The shoreline is well marked and the coves cut into the land up to 50 m in length, perpendicularly to the coast. They follow the direction of a series of parallel NE-facing fractures. The modern tidal notch is well exposed along the carbonate cliff at the present sea level. Along the limestone cliff, notch development is amplified by mixing of sea and fresh water coming from submerged springs. Moreover, this marine erosion feature is a good sea level marker in microtidal conditions, such as Mediterranean Sea, and an indicator of tectonic stability, of the Sardinian microplate. In some coves, two generations of fossil notches have been observed at 6.5 m asl and -1 m bsl, respectively, along with lithophaga boreholes up to 8 m asl. Both indicate the past eustatic conditions. All these geomorphic features make Balai promontory an interesting geological spot for studying past sea level fluctuations and present slope movements, trying to distinguish hazards due to climate change from those directly related to anthropogenic forces such as wave-induced damage due to waterborne navigation.

High frequency longitudinal profiling reveals hydrologic controls on solute sourcing, transport and processing in a karst river

NASA Astrophysics Data System (ADS)

Hensley, R. T.; Cohen, M. J.; Spangler, M.; Gooseff, M. N.

2017-12-01

The lower Santa Fe River is a large, karst river of north Florida, fed by numerous artesian springs and also containing multiple sink-rise systems. We performed repeated longitudinal profiles collecting very high frequency measurements of multiple stream parameters including temperature, dissolved oxygen, carbon dioxide, pH, dissolved organic matter, nitrate, ammonium, phosphate and turbidity. This high frequency dataset provided a spatially explicit understanding of solute sources and coupled biogeochemical processing rates along the 25 km study reach. We noted marked changes in river profiles as the river transitioned from low to high flow during the onset of the wet season. The role of lateral inflow from springs as the primary solute source was greatly reduced under high flow conditions. Effects of sink-rise systems, which under low flow conditions allow the majority of flow to bypass several kilometer long sections of the main channel, virtually disappeared under high flow conditions. Impeded light transmittance at high flow reduced primary production and by extension assimilatory nutrient uptake. This study demonstrates how high frequency longitudinal profiling can be used to observe how hydrologic conditions can alter groundwater-surface water interactions and modulate the sourcing, transport and biogeochemical processing of stream solutes.

Research on Evaluation and Control of Karst Water Resources in a Certain Tunnel of Dalian Subway

NASA Astrophysics Data System (ADS)

Wang, Guang Qiang

2018-05-01

Taking a certain tunnel in Dalian Metro as the research object, to evaluate the situation of karst development through geophysical prospecting and drilling data in study area. Karst water resources can be evaluated by quality and quantity in the study area, the correlation of the ion content can be analyzed according to the analysis results of chemical composition of groundwater and the maximum water inflow in karst water section tunnel can be calculated by using the Oshima Yoshi formula. Put forward measures and methods of groundwater control and tube well dewatering based on these evaluation, it has certain guiding significance for tunnel construction in karst area.

Particles in a karstic spring, Swabian Alb: Physicochemical and hydraulic effects during a snow melt event.

NASA Astrophysics Data System (ADS)

Schiperski, Ferry; Zirlewagen, Johannes; Hillebrand, Olav; Scheytt, Traugott; Licha, Tobias

2013-04-01

The studied karst spring 'Gallusquelle' is located on the Swabian Alb in Southwest Germany. The catchment area of the 'Gallusquelle' measures about 45 km². An average annual discharge of 0.5 m³/s serves drinking water to about 40,000 people via a waterworks. The study is part of the research project 'AGRO' (www.projekt-agro.de). The main objective of the project 'AGRO' is to develop a tool for the process-based risk management of micropollutants and pathogens in rural karst aquifers on catchment scale. As particle related transport could play an important role for micropollutants and pathogens, the characterization of particles in the spring water is one focus of this work. Furthermore we will attempt to correlate physicochemical parameters with the characteristics of particles in the spring water in order to enhance the knowledge of the transport mechanisms within the karst aquifer. For the measurement of the particle concentration and the particle size distribution the CIS 1 (GALAI) was used. The system works in a range of 0.5 to 150 µm with a resolution of at least 0.5 µm. The measurement is based on time-of-transition method using a laser beam. The turbidity was measured with an ULTRATURB PLUS (DR.LANGE) and a Fluorometer (GGUN-FL30, ALBILLIA), both working with scattering light method. To verify these measurements we used a portable turbidimeter (2100P IS PORTABLE TURBIDIMETER, HACH) working with the ratio of the signals from the scattered and the transmitted light. Temperature and electrical conductivity where also measured with the GGUN-FL30, whereby the electrical conductivity was verified with a portable multimeter (HQ 40D, HACH). Discharge, pH, water hardness, anion- and cation concentration, total organic carbon (TOC) and dissolved organic carbon (DOC) were also determined. To characterize the particles, the spring water was filtered onsite and the filter cake was analyzed in the laboratory. For SEM (scanning electron microscopy) including EDAX

Evaluation of subsidence hazard in mantled karst setting: a case study from Val d'Orléans (France)

NASA Astrophysics Data System (ADS)

Perrin, Jérôme; Cartannaz, Charles; Noury, Gildas; Vanoudheusden, Emilie

2015-04-01

Soil subsidence/collapse is a major geohazard occurring in karst region. It occurs as suffosion or dropout sinkholes developing in the soft cover. Less frequently it corresponds to a breakdown of karst void ceiling (i.e., collapse sinkhole). This hazard can cause significant engineering challenges. Therefore decision-makers require the elaboration of methodologies for reliable predictions of such hazards (e.g., karst subsidence susceptibility and hazards maps, early-warning monitoring systems). A methodological framework was developed to evaluate relevant conditioning factors favouring subsidence (Perrin et al. submitted) and then to combine these factors to produce karst subsidence susceptibility maps. This approach was applied to a mantled karst area south of Paris (Val d'Orléans). Results show the significant roles of the overburden lithology (presence/absence of low-permeability layer) and of the karst aquifer piezometric surface position within the overburden. In parallel, an experimental site has been setup to improve the understanding of key processes leading to subsidence/collapse and includes piezometers for measurements of water levels and physico-chemical parameters in both the alluvial and karst aquifers as well as surface deformation monitoring. Results should help in designing monitoring systems to anticipate occurrence of subsidence/collapse. Perrin J., Cartannaz C., Noury G., Vanoudheusden E. 2015. A multicriteria approach to karst subsidence hazard mapping supported by Weights-of-Evidence analysis. Submitted to Engineering Geology.

Fractal dimension, walk dimension and conductivity exponent of karst networks around Tulum.

NASA Astrophysics Data System (ADS)

Hendrick, Martin; Renard, Philippe

2016-06-01

Understanding the complex structure of karst networks is a challenge. In this work, we characterize the fractal properties of some of the largest coastal karst network systems in the world. They are located near the town of Tulum (Quintana Roo, Mexico). Their fractal dimension d_f, conductivity exponent ˜{μ} and walk dimension d_w are estimated using real space renormalization and numerical simulations. We obtain the following values for these exponents: d_f≈ 1.5, d_w≈ 2.4, ˜{μ}≈ 0.9. We observe that the Einstein relation holds for these structures ˜{μ} ≈ -d_f + d_w. These results indicate that coastal karst networks can be considered as critical systems and this provides some foundations to model them within this framework.

Preliminary conceptual models of the occurrence, fate, and transport of chlorinated solvents in karst regions of Tennessee

USGS Publications Warehouse

Wolfe, W.J.; Haugh, C.J.; Webbers, Ank; Diehl, T.H.

1997-01-01

Published and unpublished reports and data from 22 contaminated sites in Tennessee were reviewed to develop preliminary conceptual models of the behavior of chlorinated solvents in karst aquifers. Chlorinated solvents are widely used in many industrial operations. High density and volatility, low viscosity, and solubilities that are low in absolute terms but high relative to drinkingwater standards make chlorinated solvents mobile and persistent contaminants that are difficult to find or remove when released into the groundwater system. The major obstacle to the downward migration of chlorinated solvents in the subsurface is the capillary pressure of small openings. In karst aquifers, chemical dissolution has enlarged joints, bedding planes, and other openings that transmit water. Because the resulting karst conduits are commonly too large to develop significant capillary pressures, chlorinated solvents can migrate to considerable depth in karst aquifers as dense nonaqueous-phase liquids (DNAPL?s). Once chlorinated DNAPL accumulates in a karst aquifer, it becomes a source for dissolved-phase contamination of ground water. A relatively small amount of chlorinated DNAPL has the potential to contaminate ground water over a significant area for decades or longer. Conceptual models are needed to assist regulators and site managers in characterizing chlorinated-solvent contamination in karst settings and in evaluating clean-up alternatives. Five preliminary conceptual models were developed, emphasizing accumulation sites for chlorinated DNAPL in karst aquifers. The models were developed for the karst regions of Tennessee, but are intended to be transferable to similar karst settings elsewhere. The five models of DNAPL accumulation in karst settings are (1) trapping in regolith, (2) pooling at the top of bedrock, (3) pooling in bedrock diffuse-flow zones, (4) pooling in karst conduits, and (5) pooling in isolation from active ground-water flow. More than one conceptual

Factors Affecting Public-Supply Well Vulnerability in Two Karst Aquifers

PubMed Central

Musgrove, MaryLynn; Katz, Brian G; Fahlquist, Lynne S; Crandall, Christy A; Lindgren, Richard J

2014-01-01

Karst aquifers occur in a range of climatic and geologic settings. Nonetheless, they are commonly characterized by their vulnerability to water-quality impairment. Two karst aquifers, the Edwards aquifer in south-central Texas and the Upper Floridan aquifer in western Florida, were investigated to assess factors that control the movement of contaminants to public-supply wells (PSWs). The geochemistry of samples from a selected PSW or wellfield in each aquifer was compared with that from nearby monitoring wells and regional PSWs. Geochemistry results were integrated with age tracers, flow modeling, and depth-dependent data to refine aquifer conceptual models and to identify factors that affect contaminant movement to PSWs. The oxic Edwards aquifer is vertically well mixed at the selected PSW/wellfield, although regionally the aquifer is geochemically variable downdip. The mostly anoxic Upper Floridan aquifer is affected by denitrification and also is geochemically variable with depth. In spite of considerable differences in geology and hydrogeology, the two aquifers are similarly vulnerable to anthropogenic contamination. Vulnerability in studied PSWs in both aquifers is strongly influenced by rapid karst flowpaths and the dominance of young (<10 years) groundwater. Vulnerability was demonstrated by the frequent detection of similar constituents of concern in both aquifers (nitrate, atrazine, deethylatrazine, tetrachloroethene, and chloroform). Specific consideration of water-quality protection efforts, well construction and placement, and aquifer response times to land-use changes and contaminant loading are discussed, with implications for karst groundwater management. PMID:24841501

Factors affecting public-supply well vulnerability in two karst aquifers

USGS Publications Warehouse

Musgrove, MaryLynn; Katz, Brian G.; Fahlquist, Lynne S.; Crandall, Christy A.; Lindgren, Richard J.

2014-01-01

Karst aquifers occur in a range of climatic and geologic settings. Nonetheless, they are commonly characterized by their vulnerability to water-quality impairment. Two karst aquifers, the Edwards aquifer in south-central Texas and the Upper Floridan aquifer in western Florida, were investigated to assess factors that control the movement of contaminants to public-supply wells (PSWs). The geochemistry of samples from a selected PSW or wellfield in each aquifer was compared with that from nearby monitoring wells and regional PSWs. Geochemistry results were integrated with age tracers, flow modeling, and depth-dependent data to refine aquifer conceptual models and to identify factors that affect contaminant movement to PSWs. The oxic Edwards aquifer is vertically well mixed at the selected PSW/wellfield, although regionally the aquifer is geochemically variable downdip. The mostly anoxic Upper Floridan aquifer is affected by denitrification and also is geochemically variable with depth. In spite of considerable differences in geology and hydrogeology, the two aquifers are similarly vulnerable to anthropogenic contamination. Vulnerability in studied PSWs in both aquifers is strongly influenced by rapid karst flowpaths and the dominance of young (<10 years) groundwater. Vulnerability was demonstrated by the frequent detection of similar constituents of concern in both aquifers (nitrate, atrazine, deethylatrazine, tetrachloroethene, and chloroform). Specific consideration of water-quality protection efforts, well construction and placement, and aquifer response times to land-use changes and contaminant loading are discussed, with implications for karst groundwater management.

Techniques to better understand complex epikarst hydrogeology and contaminant transport in telogenetic karst settings

USDA-ARS?s Scientific Manuscript database

The movement of autogenic recharge through the shallow epikarstic zone in soil-mantled karst aquifers is important in understanding recharge areas and rates, groundwater storage, and contaminant transport processes. The groundwater flow in agricultural karst areas, such as Kentucky’s Pennyroyal Plat...

Applications of GIS and database technologies to manage a Karst Feature Database

USGS Publications Warehouse

Gao, Y.; Tipping, R.G.; Alexander, E.C.

2006-01-01

This paper describes the management of a Karst Feature Database (KFD) in Minnesota. Two sets of applications in both GIS and Database Management System (DBMS) have been developed for the KFD of Minnesota. These applications were used to manage and to enhance the usability of the KFD. Structured Query Language (SQL) was used to manipulate transactions of the database and to facilitate the functionality of the user interfaces. The Database Administrator (DBA) authorized users with different access permissions to enhance the security of the database. Database consistency and recovery are accomplished by creating data logs and maintaining backups on a regular basis. The working database provides guidelines and management tools for future studies of karst features in Minnesota. The methodology of designing this DBMS is applicable to develop GIS-based databases to analyze and manage geomorphic and hydrologic datasets at both regional and local scales. The short-term goal of this research is to develop a regional KFD for the Upper Mississippi Valley Karst and the long-term goal is to expand this database to manage and study karst features at national and global scales.

Transport of free and particulate-associated bacteria in karst

NASA Astrophysics Data System (ADS)

Mahler, B. J.; Personné, J.-C.; Lods, G. F.; Drogue, C.

2000-12-01

Karst aquifers, because of their unique hydrogeologic characteristics, are extremely susceptible to contamination by pathogens. Here we present the results of an investigation of contamination of a karst aquifer by fecal indicator bacteria. Two wells intercepting zones with contrasting effective hydraulic conductivities, as determined by pump test, were monitored both during the dry season and in response to a rain event. Samples were also collected from the adjacent ephemeral surface stream, which is known to be impacted by an upstream wastewater treatment plant after rainfall. Whole water and suspended sediment samples were analyzed for fecal coliforms and enterococci. During the dry season, pumping over a 2-day period resulted in increases in concentrations of fecal coliforms to greater than 10,000 CFU/100 ml in the high-conductivity well; enterococci and total suspended solids also increased, to a lesser degree. Toward the end of the pumping period, as much as 50% of the fecal coliforms were associated with suspended sediment. Irrigation of an up-gradient pine plantation with primary-treated wastewater is the probable source of the bacterial contamination. Sampling after a rain event revealed the strong influence of water quality of the adjacent Terrieu Creek on the ground water. Bacterial concentrations in the wells showed a rapid response to increased concentrations in the surface water, with fecal coliform concentrations in ground water ultimately reaching 60,000 CFU/100 ml. Up to 100% of the bacteria in the ground water was associated with suspended sediment at various times. The results of this investigation are evidence of the strong influence of surface water on ground water in karst terrain, including that of irrigation water. The large proportion of bacteria associated with particulates in the ground water has important implications for public health, as bacteria associated with particulates may be more persistent and more difficult to inactivate. The

FATE AND TRANSPORT OF PETROLEUM RELEASED FROM UNDERGROUND STORAGE TANKS in Areas of Karst Topography

EPA Science Inventory

The study determines the transport and ultimate fate of petroleum products within a region of karst geomorphology. The paper entails a complete literature review, including references that pertain to contaminant transport within karst aquifers

Submerged Humid Tropical Karst Landforms Observed By High-Resolution Multibeam Survey in Nagura Bay, Ishigaki Island, Southwestern Japan

NASA Astrophysics Data System (ADS)

Kan, H.; Urata, K.; Nagao, M.; Hori, N.; Fujita, K.; Yokoyama, Y.; Nakashima, Y.; Ohashi, T.; Goto, K.; Suzuki, A.

2014-12-01

Submerged tropical karst features were discovered in Nagura Bay on Ishigaki Island in the South Ryukyu Islands, Japan. This is the first description of submerged humid tropical karst using multibeam bathymetry. We conducted a broadband multibeam survey in the central area of Nagura Bay (1.85 × 2.7 km) and visualized the high-resolution bathymetric results with a grid size of 1 m over a depth range of 1.6-58.5 m. Various types of humid tropical karst landforms were found to coexist within the bay, including fluviokarst, doline karst, cockpit karst, polygonal karst, uvalas, and mega-dolines. We assume that Nagura Bay was a large karst basin in which older limestone remained submerged, thus preventing corrosion and the accumulation of reef sediments during periods of submersion, whereas the limestone outcropping on land was corroded during multiple interglacial and glacial periods. Based on our bathymetric result together with aerial photographs of the coastal area, we conclude that the submerged karst landscape has likely developed throughout the whole of Nagura Bay, covering an area of ~6 × 5 km. Accordingly, this area hosts the largest submerged karst in Japan. We also observed abundant coral communities during our SCUBA observations. The present marine conditions of Nagura Bay are characterized by low energy (calm sea) and low irradiance owing to the terrestrial influence. Such conditions have been emphasized by the presence of large undulating landforms, which cause decreases in wave intensity and irradiance with depth. These characteristics have acted to establish unique conditions compared to other coral reef areas in the Ryukyu Islands. It may play an important role in supporting the regional coral reef ecosystem.

[Characteristic of ammonia nitrogen adsorption on karst underground river sediments].

PubMed

Guo, Fang; Chen, Kun-Kun; Jiang, Guang-Hui

2011-02-01

Karst aquifers are one of the most important aquifers in Southwestern China. One of the characteristics of karst aquifers is the enhanced permeability permits high flow velocities are capable of transporting suspended and bedload sediments. Mobile sediment in karst may act as a vector for the transport of contaminates. 14 sediment samples were collected from two underground rivers in two typical karst areas in Liuzhou city, Guangxi Autonomous Region, China. According to simulated experiment methods, characteristic of adsorption of ammonia nitrogen on sediment was studied. The results of ammonia nitrogen adsorption dynamics on sediments showed that the maximum adsorption velocity was less than 2 h. The adsorption balance quantity in 5 h accounted for 71% - 98% of the maximum adsorption quantity. The maximum adsorption quantity of ammonia nitrogen was 385.5 mg/kg, which was sediment from a cave in the middle areas of Guancun underground river system. The study of isotherm adsorption indicated adsorption quantity of NH4+ increase followed by incremental balance concentration of NH4+ in the aquatic phase. Adsorption quantity of ammonia nitrogen in sediments has a relative linear relationship with adsorption balance concentrations. Adsorption-desorption balance concentrations were all low, indicating sediments from underground rivers have great adsorption potential. Under the condition of low and high concentrations of ammonia nitrogen in overlying water, Langmuir and Tempkin couldn't simulate or simulate results couldn't reach remarkable level, whilst Linear and Freundlich models could simulate well. Research on different type sediments, sampling times and depths from two underground rivers shows characteristic of ammonia nitrogen adsorption on karst underground river sediments doesn't have good correspondence with the type of sediments. One of the reasons is there is no big difference between sediments in the development of climate, geology, hydrological conditions

Hydraulics of Reka-Timavo system, Classical Karst (Carso), Slovenia-Italy

NASA Astrophysics Data System (ADS)

Gabrovsek, Franci; Kaufmann, Georg; Peric, Borut

2016-04-01

In tectonically active areas, karst systems continuously adapt to the relatively rapid changes of the structural and boundary conditions. The flow pathways in such systems are characterised by high variability of channel cross-sections and breakdowns, which restrict the flow and cause high fluctuations of groundwater level, particularly if the recharge variations are high. One of the world's most prominent karst systems with such characteristics is the Kras/Carso plateau (Classical Karst), which extends between SW Slovenia and NE Italy. The ground water dynamics is mainly influenced by the allogenic input of Reka river which sinks at the Škocjanske jame (Škocjan caves) and emerges about 40 km north-west at the coast of Adria near Duino in springs of Timavo. The ratio between highest and lowest flow of Reka reaches 1700 with the maximum measured discharge 305 m3/s, and minimum 0.18 m3/s. This work is based on the long-term continuous monitoring of basic physical parameters of underground flow within six active caves of the Reka-Timavo system. Using stage, temperature and specific electric conductivity hydrographs, following questions were addressed: How do different signals (flood pulse, temperature, SEP) propagate through the system? How does the known geometry relate to the recorded hydrographs in caves? Can we infer on the structure of unknown parts of the system from the recorded hydrographs ? Where are the restrictions causing floods in different parts of the system? The data analysis includes heuristic and statistical analysis of the hydrographs and optimisation based hydraulic modelling. The response to recharge events is vigorous; high flow variability causes extreme stage variations along the whole observed system, with more than 100 m difference between the base and highest water levels at rising and recession rates reaching almost 10 m/h. By analysing large recharge events, we show that high floods in the two most upstream caves (Škocjanske jame and Ka

A review of stormwater management in karst

USDA-ARS?s Scientific Manuscript database

Stormwater management can be a challenge in any environment, but it is especially difficult in karst terrain. The characteristic dissolution of bedrock creates depressions in topography as well as voids in the subsurface, resulting in problems such as collapse sinkhole development, groundwater cont...

Studying the flow dynamics of a karst aquifer system with an equivalent porous medium model.

PubMed

Abusaada, Muath; Sauter, Martin

2013-01-01

The modeling of groundwater flow in karst aquifers is a challenge due to the extreme heterogeneity of its hydraulic parameters and the duality in their discharge behavior, that is, rapid response of highly conductive karst conduits and delayed drainage of the low-permeability fractured matrix after recharge events. There are a number of different modeling approaches for the simulation of the karst groundwater dynamics, applicable to different aquifer as well as modeling problem types, ranging from continuum models to double continuum models to discrete and hybrid models. This study presents the application of an equivalent porous model approach (EPM, single continuum model) to construct a steady-state numerical flow model for an important karst aquifer, that is, the Western Mountain Aquifer Basin (WMAB), shared by Israel and the West-Bank, using MODFLOW2000. The WMAB was used as a catchment since it is a well-constrained catchment with well-defined recharge and discharge components and therefore allows a control on the modeling approach, a very rare opportunity for karst aquifer modeling. The model demonstrates the applicability of equivalent porous medium models for the simulation of karst systems, despite their large contrast in hydraulic conductivities. As long as the simulated saturated volume is large enough to average out the local influence of karst conduits and as long as transport velocities are not an issue, EPM models excellently simulate the observed head distribution. The model serves as a starting basis that will be used as a reference for developing a long-term dynamic model for the WMAB, starting from the pre-development period (i.e., 1940s) up to date. © 2012, The Author(s). GroundWater © 2012, National Ground Water Association.

Management Can Reduce Mobility of Escherichia coli compared to traditional groundwater tracers within karst terrains

USDA-ARS?s Scientific Manuscript database

An understanding of fundamental processes controlling pathogen movement is necessary to protect water resources across the globe. Limited filtration and turbulent flow make karst aquifers susceptible to microbial contamination. Groundwater tracers typically used in karst terrains include fluorescent...

Imaging of underground karst water channels using an improved multichannel transient Rayleigh wave detecting method

PubMed Central

Zheng, Xuhui; Liu, Lei; Li, Gao; Zhou, Fubiao; Xu, Jiemin

2018-01-01

Geological and hydrogeological conditions in karst areas are complicated from the viewpoint of engineering. The construction of underground structures in these areas is often disturbed by the gushing of karst water, which may delay the construction schedule, result in economic losses, and even cause heavy casualties. In this paper, an innovative method of multichannel transient Rayleigh wave detecting is proposed by introducing the concept of arrival time difference phase between channels (TDP). Overcoming the restriction of the space-sampling law, the proposed method can extract the phase velocities of different frequency components from only two channels of transient Rayleigh wave recorded on two adjacent detecting points. This feature greatly improves the work efficiency and lateral resolution of transient Rayleigh wave detecting. The improved multichannel transient Rayleigh wave detecting method is applied to the detection of karst caves and fractures in rock mass of the foundation pit of Yan’an Road Station of Guiyang Metro. The imaging of the detecting results clearly reveals the distribution of karst water inflow channels, which provided significant guidance for water plugging and enabled good control over karst water gushing in the foundation pit. PMID:29883492

Imaging of underground karst water channels using an improved multichannel transient Rayleigh wave detecting method.

PubMed

Zheng, Xuhui; Liu, Lei; Sun, Jinzhong; Li, Gao; Zhou, Fubiao; Xu, Jiemin

2018-01-01

Geological and hydrogeological conditions in karst areas are complicated from the viewpoint of engineering. The construction of underground structures in these areas is often disturbed by the gushing of karst water, which may delay the construction schedule, result in economic losses, and even cause heavy casualties. In this paper, an innovative method of multichannel transient Rayleigh wave detecting is proposed by introducing the concept of arrival time difference phase between channels (TDP). Overcoming the restriction of the space-sampling law, the proposed method can extract the phase velocities of different frequency components from only two channels of transient Rayleigh wave recorded on two adjacent detecting points. This feature greatly improves the work efficiency and lateral resolution of transient Rayleigh wave detecting. The improved multichannel transient Rayleigh wave detecting method is applied to the detection of karst caves and fractures in rock mass of the foundation pit of Yan'an Road Station of Guiyang Metro. The imaging of the detecting results clearly reveals the distribution of karst water inflow channels, which provided significant guidance for water plugging and enabled good control over karst water gushing in the foundation pit.

The development of deep karst in the anticlinal aquifer structure based on the coupling of multistage flow systems

NASA Astrophysics Data System (ADS)

Xu, M.; Zhong, L.; Yang, Y.

2017-12-01

Under the background of neotectonics, the multistage underground flow system has been form due the different responses of main stream and tributaries to crust uplift. The coupling of multistage underground flow systems influences the development of karst thoroughly. At first, the research area is divided into vadose area, shunted area and exorheic area based on the development characteristics of transverse valley. Combining the controlling-drain action with topographic index and analyzing the coupling features of multistage underground flow system. And then, based on the coupling of multistage underground flow systems, the characteristics of deep karst development were verified by the lossing degree of surface water, water bursting and karst development characteristics of tunnels. The vadose area is regional water system based, whose deep karst developed well. It resulted the large water inflow of tunnels and the surface water drying up. The shunted area, except the region near the transverse valleys, is characterized by regional water system. The developed deep karst make the surface water connect with deep ground water well, Which caused the relatively large water flow of tunnels and the serious leakage of surface water. The deep karst relatively developed poor in the regions near transverse valleys which is characterized by local water system. The exorheic area is local water system based, whose the deep karst developed poor, as well as the connection among surface water and deep ground water. It has result in the poor lossing of the surface water under the tunnel construction. This study broadens the application field of groundwater flow systems theory, providing a new perspective for the study of Karst development theory. Meanwhile it provides theoretical guidance for hazard assessment and environmental negative effect in deep-buried Karst tunnel construction.

A large-scale integrated karst-vegetation recharge model to understand the impact of climate and land cover change

NASA Astrophysics Data System (ADS)

Sarrazin, Fanny; Hartmann, Andreas; Pianosi, Francesca; Wagener, Thorsten

2017-04-01

Karst aquifers are an important source of drinking water in many regions of the world, but their resources are likely to be affected by changes in climate and land cover. Karst areas are highly permeable and produce large amounts of groundwater recharge, while surface runoff is typically negligible. As a result, recharge in karst systems may be particularly sensitive to environmental changes compared to other less permeable systems. However, current large-scale hydrological models poorly represent karst specificities. They tend to provide an erroneous water balance and to underestimate groundwater recharge over karst areas. A better understanding of karst hydrology and estimating karst groundwater resources at a large-scale is therefore needed for guiding water management in a changing world. The first objective of the present study is to introduce explicit vegetation processes into a previously developed karst recharge model (VarKarst) to better estimate evapotranspiration losses depending on the land cover characteristics. The novelty of the approach for large-scale modelling lies in the assessment of model output uncertainty, and parameter sensitivity to avoid over-parameterisation. We find that the model so modified is able to produce simulations consistent with observations of evapotranspiration and soil moisture at Fluxnet sites located in carbonate rock areas. Secondly, we aim to determine the model sensitivities to climate and land cover characteristics, and to assess the relative influence of changes in climate and land cover on aquifer recharge. We perform virtual experiments using synthetic climate inputs, and varying the value of land cover parameters. In this way, we can control for variations in climate input characteristics (e.g. precipitation intensity, precipitation frequency) and vegetation characteristics (e.g. canopy water storage capacity, rooting depth), and we can isolate the effect that each of these quantities has on recharge. Our results

Stable isotope tracing of trout hatchery carbon to sediments and foodwebs of limestone spring creeks.

PubMed

Hurd, Todd M; Jesic, Slaven; Jerin, Jessica L; Fuller, Nathan W; Miller, David

2008-11-01

Limestone springs support productive ecosystems and fisheries, yet aquaculture may modify or impair these ecosystems. We determined trout hatchery organic contribution to spring creek sediments and foodwebs with natural abundance stable isotope methods. Hatchery feed, waste, and trout were significantly enriched in delta(13)C relative to autotrophs and wild fish. Spring creek sediments were enriched in delta(13)C toward the hatchery endmember relative to reference streams without hatcheries and relative to a larger larger-order, spring-influenced stream. Contribution of hatchery C to spring creek sediments was greatest during March and associated with greatest sediment %C. Contribution of hatchery C to pollution-tolerant isopod diet was 39-51% in a stream receiving limestone spring water via hatchery effluent. Isopods of one spring creek also relied on hatchery-derived C within one month of hatchery closure. Four years later, less pollution pollution-tolerant amphipods dominated and consumed non-vascular over vascular autotrophs (86%). Isopods of a second spring creek with an active hatchery did not appear to be using hatchery matter directly, but were enriched in delta(34)S relative to a spring creek tributary with no hatchery influence. Isopods in both of these streams were relatively enriched in delta(15)N, indicating general nutrient enrichment from surrounding agricultural land use. The contribution of hatchery vs. wild fish in diet of herons and egrets was traced with delta(13)C of guano. These birds were strongly dependent on stocked trout in a spring creek with a recently closed state trout hatchery, and also near another large, state-run hatchery. Heron dependence on hatchery fish in the spring creek decreased with time since hatchery closure. Use of stable isotope natural abundance techniques in karst spring creeks can reveal stream impairment due to aquaculture, specific C sources to bio-indicating consumers, losses of farmed fish to predation, and

Geomorphometric correlations of vegetation cover properties and topographic karst features based on high-resolution LiDAR DTM of Aggtelek Karst, NE Hungary

NASA Astrophysics Data System (ADS)

Székely, Balázs; Telbisz, Tamás; Koma, Zsófia; Kelemen, Kristóf; Szmorad, Ferenc; Deák, Márton; Látos, Tamás; Standovár, Tibor

2015-04-01

Topography and lithology are two major factors influencing the vegetation cover, its mosaic pattern and lateral transitions. In karstic areas the topography has a high diversity, microtopographic landforms influence the local ecological setting, vegetation structure. Presence of sinkholes of various sizes and geometric arrangements causes rapid lateral variation of the slope, aspect patterns as well as highly modify the soil water balance in time and space. These diversity of factors defines a mosaicked habitat pattern for vegetation assemblages. The World Heritage Site Aggtelek Karst/Slovakian Karst Caves has characteristic natural and environmental properties concerning the geomorphological as well as the ecological values. In order to be able to study the topographic influence on the ecological setting, a high-resolution digital terrain model (DTM) and digital surface model (DSM) have been derived from airborne laser scanning data depicting the karstic micro- and macrotopographic Landscape elements and the envelope surface of the canopy. Additional vegetation parameters like closure and average height have been derived from a normalized digital surface model (nDSM). Extensive mapping of vegetation properties has been carried out: centered on points of a grid array several vegetation-specific data - including composition and structure of tree and shrub layers, herbacesous vegetation and tree regeneration - have been acquired. Various classification patterns - based on trees pecies composition, vertical vegetation structure - have been derived from this data set. The comparison of the vegetation classification data and the geomorphometric DTM derivatives yielded interesting results. Certain vegetation characteristics often correlate with the geomorphometric properties. We interpret this similarity as sensitivity of vegetion to fine-scale variations in geomorphic properties like aspect, illumination conditions and soil properties. However, in many cases the

Factors affecting public-supply well vulnerability in two karst aquifers.

PubMed

Musgrove, MaryLynn; Katz, Brian G; Fahlquist, Lynne S; Crandall, Christy A; Lindgren, Richard J

2014-09-01

Karst aquifers occur in a range of climatic and geologic settings. Nonetheless, they are commonly characterized by their vulnerability to water-quality impairment. Two karst aquifers, the Edwards aquifer in south-central Texas and the Upper Floridan aquifer in western Florida, were investigated to assess factors that control the movement of contaminants to public-supply wells (PSWs). The geochemistry of samples from a selected PSW or wellfield in each aquifer was compared with that from nearby monitoring wells and regional PSWs. Geochemistry results were integrated with age tracers, flow modeling, and depth-dependent data to refine aquifer conceptual models and to identify factors that affect contaminant movement to PSWs. The oxic Edwards aquifer is vertically well mixed at the selected PSW/wellfield, although regionally the aquifer is geochemically variable downdip. The mostly anoxic Upper Floridan aquifer is affected by denitrification and also is geochemically variable with depth. In spite of considerable differences in geology and hydrogeology, the two aquifers are similarly vulnerable to anthropogenic contamination. Vulnerability in studied PSWs in both aquifers is strongly influenced by rapid karst flowpaths and the dominance of young (<10 years) groundwater. Vulnerability was demonstrated by the frequent detection of similar constituents of concern in both aquifers (nitrate, atrazine, deethylatrazine, tetrachloroethene, and chloroform). Specific consideration of water-quality protection efforts, well construction and placement, and aquifer response times to land-use changes and contaminant loading are discussed, with implications for karst groundwater management. © 2014 The Authors. Groundwater published by Wiley Periodicals, Inc. on behalf of National Ground Water Association.

Springwater geochemistry at Honey Creek State Natural Area, central Texas: Implications for surface water and groundwater interaction in a karst aquifer

NASA Astrophysics Data System (ADS)

Musgrove, M.; Stern, L. A.; Banner, J. L.

2010-06-01

SummaryA two and a half year study of two adjacent watersheds at the Honey Creek State Natural Area (HCSNA) in central Texas was undertaken to evaluate spatial and temporal variations in springwater geochemistry, geochemical evolution processes, and potential effects of brush control on karst watershed hydrology. The watersheds are geologically and geomorphologically similar, and each has springs discharging into Honey Creek, a tributary to the Guadalupe River. Springwater geochemistry is considered in a regional context of aquifer components including soil water, cave dripwater, springwater, and phreatic groundwater. Isotopic and trace element variability allows us to identify both vadose and phreatic groundwater contributions to surface water in Honey Creek. Spatial and temporal geochemical data for six springs reveal systematic differences between the two watersheds. Springwater Sr isotope values lie between values for the limestone bedrock and soils at HCSNA, reflecting a balance between these two primary sources of Sr. Sr isotope values for springs within each watershed are consistent with differences between soil compositions. At some of the springs, consistent temporal variability in springwater geochemistry (Sr isotopes, Mg/Ca, and Sr/Ca values) appears to reflect changes in climatic and hydrologic parameters (rainfall/recharge) that affect watershed processes. Springwater geochemistry was unaffected by brush removal at the scale of the HCSNA study. Results of this study build on previous regional studies to provide insight into watershed hydrology and regional hydrologic processes, including connections between surface water, vadose groundwater, and phreatic groundwater.

Spatial resolution of transport parameters in a subtropical karst conduit system during dry and wet seasons

NASA Astrophysics Data System (ADS)

Ender, Anna; Goeppert, Nadine; Goldscheider, Nico

2018-04-01

Karst aquifers are characterized by a high degree of hydrologic variability and spatial heterogeneity of transport parameters. Tracer tests allow the quantification of these parameters, but conventional point-to-point experiments fail to capture spatiotemporal variations of flow and transport. The goal of this study was to elucidate the spatial distribution of transport parameters in a karst conduit system at different flow conditions. Therefore, six tracer tests were conducted in an active and accessible cave system in Vietnam during dry and wet seasons. Injections and monitoring were done at five sites along the flow system: a swallow hole, two sites inside the cave, and two springs draining the system. Breakthrough curves (BTCs) were modeled with CXTFIT software using the one-dimensional advection-dispersion model and the two-region nonequilibrium model. In order to obtain transport parameters in the individual sections of the system, a multi-pulse injection approach was used, which was realized by using the BTCs from one section as input functions for the next section. Major findings include: (1) In the entire system, mean flow velocities increase from 183 to 1,043 m/h with increasing discharge, while (2) the proportion of immobile fluid regions decrease; (3) the lowest dispersivity was found at intermediate discharge; (4) in the individual cave sections, flow velocities decrease along the flow direction, related to decreasing gradients, while (5) dispersivity is highest in the middle section of the cave. The obtained results provide a valuable basis for the development of an adapted water management strategy for a projected water-supply system.

A New Methodology for Open Pit Slope Design in Karst-Prone Ground Conditions Based on Integrated Stochastic-Limit Equilibrium Analysis

NASA Astrophysics Data System (ADS)

Zhang, Ke; Cao, Ping; Ma, Guowei; Fan, Wenchen; Meng, Jingjing; Li, Kaihui

2016-07-01

Using the Chengmenshan Copper Mine as a case study, a new methodology for open pit slope design in karst-prone ground conditions is presented based on integrated stochastic-limit equilibrium analysis. The numerical modeling and optimization design procedure contain a collection of drill core data, karst cave stochastic model generation, SLIDE simulation and bisection method optimization. Borehole investigations are performed, and the statistical result shows that the length of the karst cave fits a negative exponential distribution model, but the length of carbonatite does not exactly follow any standard distribution. The inverse transform method and acceptance-rejection method are used to reproduce the length of the karst cave and carbonatite, respectively. A code for karst cave stochastic model generation, named KCSMG, is developed. The stability of the rock slope with the karst cave stochastic model is analyzed by combining the KCSMG code and the SLIDE program. This approach is then applied to study the effect of the karst cave on the stability of the open pit slope, and a procedure to optimize the open pit slope angle is presented.

All in the Training: Techniques for Enhancing Karst Landscape Education through Show Cave Interpretation

ERIC Educational Resources Information Center

North, Leslie; van Beynen, Philip

2016-01-01

Despite the abundance of karst terrains and a universal lack of knowledge about the role they play in supplying freshwater resources, informal environmental education through guided show cave tours is poorly understood. This study evaluated techniques for educating cave guides on how to disseminate information about human-karst interactions to…

Integrated Research Methods for Applied Urban Hydrogeology of Karst Sites

NASA Astrophysics Data System (ADS)

Epting, J.; Romanov, D. K.; Kaufmann, G.; Huggenberger, P.

2008-12-01

Integrated and adaptive surface- and groundwater monitoring and management in urban areas require innovative process-oriented approaches. To accomplish this, it is necessary to develop and combine interdisciplinary instruments that facilitate adequately quantifying cumulative effects on groundwater flow regimes. While the characterization and modeling of flow in heterogeneous and fractured media has been investigated intensively, there are no well-developed long-term hydrogeological research sites for gypsum karst. Considering that infrastructures in karst regions, particularly in gypsum, are prone to subsidence, severe problems can arise in urban areas. In the 1880's, a river dam was constructed on gypsum-containing rock, Southeast of Basel, Switzerland. Over the last 30 years, subsidence of the dam and an adjacent highway has been observed. Surface water infiltrates upstream of the dam, circulates in the gravel deposits and in the weathered bedrock around and beneath the dam and exfiltrates downstream into the river. These processes enhance karstification processes in the soluble units of the gypsum. As a result an extended weathering zone within the bedrock and the development of preferential flow paths within voids and conduits can be observed. To prevent further subsidence, construction measures were conducted in two major project phases in 2006 and 2007. The highway was supported by a large number of pillars embedded in the non- weathered rock and by a sealing pile wall, to prevent infiltrating river water circulating around the dam and beneath the foundation of the highway. To safeguard surface and subsurface water resources during the construction measures, an extensive observation network was set up. Protection schemes and geotechnical investigations that are necessary for engineering projects often provide "windows of opportunity", bearing the possibility to change perceptions concerning the sustainable development of water resources and coordinate future

Timescales for nitrate contamination of spring waters, northern Florida, USA

USGS Publications Warehouse

Katz, B.G.; Böhlke, J.K.; Hornsby, H.D.

2001-01-01

Residence times of groundwater, discharging from springs in the middle Suwannee River Basin, were estimated using chlorofluorocarbons (CFCs), tritium (3H), and tritium/helium-3 (3H/3He) age-dating methods to assess the chronology of nitrate contamination of spring waters in northern Florida. During base-flow conditions for the Suwannee River in 1997–1999, 17 water samples were collected from 12 first, second, and third magnitude springs discharging groundwater from the Upper Floridan aquifer. Extending age-dating techniques, using transient tracers to spring waters in complex karst systems, required an assessment of several models [piston-flow (PFM), exponential mixing (EMM), and binary-mixing (BMM)] to account for different distributions of groundwater age. Multi-tracer analyses of four springs yielded generally concordant PFM ages of around 20±2 years from CFC-12, CFC-113, 3H, and 3He, with evidence of partial CFC-11 degradation. The EMM gave a reasonable fit to CFC-113, CFC-12, and 3H data, but did not reproduce the observed 3He concentrations or 3H/3He ratios, nor did a combination PFM–EMM. The BMM could reproduce most of the multi-tracer data set only if both endmembers had 3H concentrations not much different from modern values. CFC analyses of 14 additional springs yielded apparent PFM ages from about 10 to 20 years from CFC-113, with evidence of partial CFC-11 degradation and variable CFC-12 contamination. While it is not conclusive, with respect to the age distribution within each spring, the data indicate that the average residence times were in the order of 10–20 years and were roughly proportional to spring magnitude. Applying similar models to recharge and discharge of nitrate based on historical nitrogen loading data yielded contrasting trends for Suwanee County and Lafayette County. In Suwanee County, spring nitrate trends and nitrogen isotope data were consistent with a peak in fertilizer input in the 1970s and a relatively high overall ratio

Delineation of karst terranes in complex environments: Application of modern developments in the wavelet theory and data mining

NASA Astrophysics Data System (ADS)

Alperovich, Leonid; Averbuch, Amir; Eppelbaum, Lev; Zheludev, Valery

2013-04-01

Karst areas occupy about 14% of the world land. Karst terranes of different origin have caused difficult conditions for building, industrial activity and tourism, and are the source of heightened danger for environment. Mapping of karst (sinkhole) hazards, obviously, will be one of the most significant problems of engineering geophysics in the XXI century. Taking into account the complexity of geological media, some unfavourable environments and known ambiguity of geophysical data analysis, a single geophysical method examination might be insufficient. Wavelet methodology as whole has a significant impact on cardinal problems of geophysical signal processing such as: denoising of signals, enhancement of signals and distinguishing of signals with closely related characteristics and integrated analysis of different geophysical fields (satellite, airborne, earth surface or underground observed data). We developed a three-phase approach to the integrated geophysical localization of subsurface karsts (the same approach could be used for following monitoring of karst dynamics). The first phase consists of modeling devoted to compute various geophysical effects characterizing karst phenomena. The second phase determines development of the signal processing approaches to analyzing of profile or areal geophysical observations. Finally, at the third phase provides integration of these methods in order to create a new method of the combined interpretation of different geophysical data. In the base of our combine geophysical analysis we put modern developments in the wavelet technique of the signal and image processing. The development of the integrated methodology of geophysical field examination will enable to recognizing the karst terranes even by a small ratio of "useful signal - noise" in complex geological environments. For analyzing the geophysical data, we used a technique based on the algorithm to characterize a geophysical image by a limited number of parameters

Assessment of the potential for karst in the Rustler Formation at the WIPP site.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lorenz, John Clay

2006-01-01

This report is an independent assessment of the potential for karst dissolution in evaporitic strata of the Rustler Formation at the Waste Isolation Pilot Plant (WIPP) site. Review of the available data suggests that the Rustler strata thicken and thin across the area in depositional patterns related to lateral variations in sedimentary accommodation space and normal facies changes. Most of the evidence that has been offered for the presence of karst in the subsurface has been used out of context, and the different pieces are not mutually supporting. Outside of Nash Draw, definitive evidence for the development of karst inmore » the Rustler Formation near the WIPP site is limited to the horizon of the Magenta Member in drillhole WIPP-33. Most of the other evidence cited by the proponents of karst is more easily interpreted as primary sedimentary structures and the localized dissolution of evaporitic strata adjacent to the Magenta and Culebra water-bearing units. Some of the cited evidence is invalid, an inherited baggage from studies made prior to the widespread knowledge of modern evaporite depositional environments and prior to the existence of definitive exposures of the Rustler Formation in the WIPP shafts. Some of the evidence is spurious, has been taken out of context, or is misquoted. Lateral lithologic variations from halite to mudstone within the Rustler Formation under the WIPP site have been taken as evidence for the dissolution of halite such as that seen in Nash Draw, but are more rationally explained as sedimentary facies changes. Extrapolation of the known karst features in Nash Draw eastward to the WIPP site, where conditions are and have been significantly different for half a million years, is unwarranted. The volumes of insoluble material that would remain after dissolution of halite would be significantly less than the observed bed thicknesses, thus dissolution is an unlikely explanation for the lateral variations from halite to mudstone and

Karst features detection and mapping using airphotos, DSMs and GIS techniques

NASA Astrophysics Data System (ADS)

Kakavas, M. P.; Nikolakopoulos, K. G.; Zagana, E.

2015-10-01

The aim of this work is to detect and qualify natural karst depressions in the Aitoloakarnania Prefecture, Western Greece, using remote sensing data in conjunction with the Geographical Information Systems - GIS. The study area is a part of the Ionian geotectonic zone, and its geological background consists of the Triassic Evaporates. The Triassic carbonate breccias where formed as a result of the tectonic and orogenetic setting of the external Hellenides and the diaper phenomena of the Triassic Evaporates. The landscape characterized by exokarst features closed depressions in the Triassic carbonate breccias. At the threshold of this study, an in situ observation was performed in order to identify dolines and swallow holes. The creation of sinkholes, in general, is based on the collapse of the surface layer due to chemical dissolution of carbonate rocks. In the current study airphotos stereopairs, DSMs and GIS were combined in order to detect and map the karst features. Thirty seven airphotos were imported in Leica Photogrammetry Suite and a stereo model of the study area was created. Then in 3D view possible karst features were detected and digitized. Those sites were verified during the in situ survey. ASTER GDEM, SRTM DEM, high resolution airphoto DSM created from the Greek Cadastral and a DEM from digitized contours from the 1/50,000 topographic were also evaluated in GIS environment for the automatic detection of the karst depressions. The results are presented in this study.

The use of karst geomorphology for planning, hazard avoidance and development in Great Britain

NASA Astrophysics Data System (ADS)

Cooper, Anthony H.; Farrant, Andrew R.; Price, Simon J.

2011-11-01

Within Great Britain five main types of karstic rocks - dolomite, limestone, chalk, gypsum and salt - are present. Each presents a different type and severity of karstic geohazard which are related to the rock solubility and geological setting. Typical karstic features associated with these rocks have been databased by the British Geological Survey (BGS) with records of sinkholes, cave entrances, stream sinks, resurgences and building damage; data for more than half of the country has been gathered. BGS has manipulated digital map data, for bedrock and superficial deposits, with digital elevation slope models, superficial deposit thickness models, the karst data and expertly interpreted areas, to generate a derived dataset assessing the likelihood of subsidence due to karst collapse. This dataset is informed and verified by the karst database and marketed as part of the BGS GeoSure suite. It is currently used by environmental regulators, the insurance and construction industries, and the BGS semi-automated enquiry system. The database and derived datasets can be further combined and manipulated using GIS to provide other datasets that deal with specific problems. Sustainable drainage systems, some of which use soak-aways into the ground, are being encouraged in Great Britain, but in karst areas they can cause ground stability problems. Similarly, open loop ground source heat or cooling pump systems may induce subsidence if installed in certain types of karstic environments such as in chalk with overlying sand deposits. Groundwater abstraction also has the potential to trigger subsidence in karst areas. GIS manipulation of the karst information is allowing Great Britain to be zoned into areas suitable, or unsuitable, for such uses; it has the potential to become part of a suite of planning management tools for local and National Government to assess the long term sustainable use of the ground.

Use of dye tracing to determine ground-water movement to Mammoth Crystal Springs, Sylvan Pass area, Yellowstone National Park, Wyoming

USGS Publications Warehouse

Spangler, Lawrence E.; Susong, David D.

2006-01-01

At the request of and in cooperation with the Geology Program at Yellowstone National Park, the U.S. Geological Survey conducted a hydrologic investigation of the Sylvan Pass area in June 2005 to determine the relation between surface water and ground-water flow to Mammoth Crystal Springs. Results of a dye-tracing investigation indicate that streamflow lost into talus deposits on Sylvan Pass enters the ground-water system and moves to the southeast to discharge at Mammoth Crystal Springs. Ground-water travel times to the springs from a distance of 1.45 miles and a vertical relief of 500 feet were less than 1 day, indicating apparent rates of movement of at least 8,000 feet per day, values that are similar to those in karst aquifers. Peak dye concentrations were reached about 2 days after dye injection, and transit time of most of the dye mass through the system was about 3 weeks. High permeability and rapid travel times within this aquifer also are indicated by the large variation in springflow in response to snowmelt runoff and precipitation, and by the high concentration of suspended sediment (turbidity) in the water discharging into the spring-fed lake.

Intrinsic vulnerability, hazard and risk mapping for karst aquifers: A case study

NASA Astrophysics Data System (ADS)

Mimi, Ziad A.; Assi, Amjad

2009-01-01

SummaryGroundwater from karst aquifers is among the most important resources of drinking water supply of the worldwide population. The European COST action 620 proposed a comprehensive approach to karst groundwater protection, comprising methods of intrinsic and specific vulnerability mapping, hazard and risk mapping. This paper presents the first application of all components of this European approach to the groundwater underlying the Ramallah district, a karst hydrogeology system in Palestine. The vulnerability maps which were developed can assist in the implementation of groundwater management strategies to prevent degradation of groundwater quality. Large areas in the case study area can be classified as low or very low risk area corresponding to the pollution sources due to the absence of hazards and also due to low vulnerabilities. These areas could consequently be interesting for future development as they are preferable in view of ground water protection.

Tile drainage as karst: Conduit flow and diffuse flow in a tile-drained watershed

USGS Publications Warehouse

Schilling, K.E.; Helmers, M.

2008-01-01

The similarity of tiled-drained watersheds to karst drainage basins can be used to improve understanding of watershed-scale nutrient losses from subsurface tile drainage networks. In this study, short-term variations in discharge and chemistry were examined from a tile outlet collecting subsurface tile flow from a 963 ha agricultural watershed. Study objectives were to apply analytical techniques from karst springs to tile discharge to evaluate water sources and estimate the loads of agricultural pollutants discharged from the tile with conduit, intermediate and diffuse flow regimes. A two-member mixing model using nitrate, chloride and specific conductance was used to distinguish rainwater versus groundwater inputs. Results indicated that groundwater comprised 75% of the discharge for a three-day storm period and rainwater was primarily concentrated during the hydrograph peak. A contrasting pattern of solute concentrations and export loads was observed in tile flow. During base flow periods, tile flow consisted of diffuse flow from groundwater sources and contained elevated levels of nitrate, chloride and specific conductance. During storm events, suspended solids and pollutants adhered to soil surfaces (phosphorus, ammonium and organic nitrogen) were concentrated and discharged during the rapid, conduit flow portion of the hydrograph. During a three-day period, conduit flow occurred for 5.6% of the time but accounted for 16.5% of the total flow. Nitrate and chloride were delivered primarily with diffuse flow (more than 70%), whereas 80-94% of total suspended sediment, phosphorus and ammonium were exported with conduit and intermediate flow regimes. Understanding the water sources contributing to tile drainage and the manner by which pollutant discharge occurs from these systems (conduit, intermediate or diffuse flow) may be useful for designing, implementing and evaluating non-point source reduction strategies in tile-drained landscapes. ?? 2007 Elsevier B.V. All

Addressing secondary school students' everyday ideas about freshwater springs in order to develop an instructional tool to promote conceptual reconstruction

NASA Astrophysics Data System (ADS)

Reinfried, S.; Tempelmann, S.; Aeschbacher, U.

2012-05-01

"Water knowledge" has now become a socio-political and future-orientated necessity. Everyday ideas or preconceptions of hydrology can have a deleterious effect one people's understanding of the scientific facts and their interrelations that are of relevance to sustainable water management. This explorative pilot study shows that preconceived notions about the origin of freshwater springs are common at the lower secondary school level. The purpose of this study was two-fold: (1) to investigate the nature of everyday ideas about freshwater springs among 81 13-yr-old Swiss students, and (2) to develop an efficient instructional tool that promotes conceptual reconstruction in the learners' minds. To assess students' everyday ideas we conducted interviews, examined student work, and asked students to fill in a questionnaire. The results indicate that half of the students have some basic hydrological knowledge. However, several preconceived notions that can significantly impede the understanding of hydrological concepts have been found. A common preconception concerns the idea that solid rocks cannot be permeable and that large underground cavities constitute a necessary precondition for the formation of springs. While these ideas may well be true for karst springs they inhibit the understanding of the concept of other spring types due to their plausibility and intelligibility. We therefore chose the concept of the hillslope spring to construct an instructional tool that takes into account the findings of the psychology of learning aimed at promoting deep learning, thus facilitating a lasting conceptual reconstruction of the concept of springs.

Structural control in sinkhole development and speleogenesis: a case study from the High Murge karst landscape (Apulia, Italy)

NASA Astrophysics Data System (ADS)

Pepe, M.; Parise, M.

2012-04-01

The Murge plateau is the main karst sector of Apulia, an almost entirely carbonate region of SE Italy. It can be, in turn, subdivided into two sectors: High Murge, the inland plateau, where remnants of an ancient tropical karst are still recognizable; and Low Murge, closer to the Adriatic Sea, with smoother karst morphologies and landforms, but, at the same time, hosting some of the longest underground karst system in the region (Parise, 1998, 2006). Even though showing low energy relief, the landscape of High Murge is very articulated when examined at greater detail, with several interesting karst features. Among these, sinkholes are definitely the most significant, showing a variety of typologies and, at the same time, a high frequency, both as individual features and as coalescent landforms, giving origin to more complex depressions (Parise, 2011). Previous studies carried out in the High Murge through morphometric analysis of the main sinkholes identified on the 1:25,000 scale topographic maps from the Italian Army Geographical Institute indicated their likely genesis in a low relief cockpit karst (Sauro, 1991). Over such landscape, developed in Upper Tertiary, a hydrographic pattern was superimposed, that partly opened some of the depressions, also dismantling sectors of the karst relief and producing talus deposits (Caldara & Ciaranfi, 1988). In the present work we take into consideration the southern countryside of Ruvo di Puglia. Choice of the area, which extends over 15 km2, was dictated by presence of a high number of sinkholes, and of several important caves with prevailing vertical development, including the deepest pit ever explored in Apulia (Grave della Ferratella, depth - 320 m). The cave is nowadays not accessible, due to clogging caused by land use changes during the 80's. Based upon extensive field surveys and interpretation of multi-year aerial photographs (time range 1955-2003), integrated by surveying in selected caves, the main hydro

[Distribution of 137Cs and relative influencing factors on typical karst sloping land].

PubMed

Zhang, Xiao-Nan; Wang, Ke-Lin; Zhang, Wei; Chen, Hong-Song; He, Xun-Yang; Zhang, Xin-Bao

2009-11-01

Based on the field survey and the analysis of a large number of soil samples, the distribution of 137 Cs and its influencing factors were studied using 137 Cs tracer technology on typical karst sloping land. The results indicate that the distribution of 137 Cs in soil profile in karst areas show the similar characteristics as that in non-karst areas, fitted an exponential pattern in forest soils and a uniform pattern in cultivated soils. In the sinkhole points in karst areas, 137 Cs exists in deep soil layers and its specific activity vary from 1.7 to 3.3 Bq/kg in soil layers above 45cm, suggesting the existing soil around karst sinkhole is mainly formed by the accumulation of erosion materials. The 137 Cs specific activity in the soil from two rock cracks are 16.8 Bq/kg and 37.6 Bq/kg respectively, which are much higher than that in the soil around the rock, this phenomenon indicates that bare rock is an important influencing factor for 137 Cs spatial movement. With the increment of altitude, the 137 Cs area activity exhibits an irregular fluctuation and evident spatial heterogeneity. On the forest land, the 137 Cs area activities which range from 299.4 to 1 592.6 Bq/m2 are highly positively correlated with the slope gradient and positively correlated with the altitude; while on the cultivated land, the 137 Cs area activities which range from 115.8 to 1478.6 Bq/m2 are negatively correlated with the slope gradient but negatively correlated with the altitude. Topography, geomorphology and human disturbance intensity are the key factors influencing 137 Cs spatial distribution.

New Approaches for Responsible Management of Offshore Springs in Semi-arid Regions

NASA Astrophysics Data System (ADS)

Shaban, Amin; de Jong, Carmen; Al-Sulaimani, Zaher

2017-04-01

In arid and semi-arid regions, such as the Mediterranean and Gulf Region where water is scarce water demand has been exacerbated and become a major environmental challenge. Presently there is massive pressure to develop new water sources to alleviate existing water stress. In the quest for more freshwater even groundwater discharge into the sea in the form of "off-shore freshwater springs" (or submarine groundwater discharge) has been contemplated as a potential source of unconventional water in coastal zones. Offshore-springs are derived from aquifers with complex geological controls mainly in the form of faults and karst conduits. Representing a border-line discipline, they have been poorly studied with only few submarine groundwater monitoring sites existing worldwide. Recently, innovative techniques have been developed enabling springs to be detected via remote sensing such as airborne surveys or satellite images. "Thermal Anomalies" can be clearly identified as evidence for groundwater discharge into the marine environment. A diversity of groundwater routes along which off-shore springs are fed from land sources can be recognized and near-shore and offshore springs differentiated and classified according to their geometry. This is well pronounced along the coast of Lebanon and offshore of Oman. Offshore springs play an important role in the marine ecosystem as natural sources of mercury, metals, nutrients, dissolved carbon species and in cooling or warming ocean water. However, they are extremely sensitive to variations in qualitative and quantitative water inputs triggered by climate change and anthropogenic impacts especially in their recharge zones. Pollutants such as sewage, detergents, heavy metals or herbicides that negatively affect water quality of offshore springs can transit the groundwater rapidly. Recently these springs have also been severely affected by uncontrolled water abstraction from land aquifers. In Bahrain, overpumping combined with

SWAT-based streamflow and embayment modeling of Karst-affected Chapel branch watershed, South Carolina

Treesearch

Devendra Amatya; M. Jha; A.E. Edwards; T.M. Williams; D.R. Hitchcock

2011-01-01

SWAT is a GIS-based basin-scale model widely used for the characterization of hydrology and water quality of large, complex watersheds; however, SWAT has not been fully tested in watersheds with karst geomorphology and downstream reservoir-like embayment. In this study, SWAT was applied to test its ability to predict monthly streamflow dynamics for a 1,555 ha karst...

Comparison of Recharge Estimation Methods During a Wet Period in a Karst Aquifer.

PubMed

Guardiola-Albert, Carolina; Martos-Rosillo, Sergio; Pardo-Igúzquiza, Eulogio; Durán Valsero, Juan José; Pedrera, Antonio; Jiménez-Gavilán, Pablo; Liñán Baena, Cristina

2015-01-01

Management of water resources, implying their appropriate protection, calls for a sound evaluation of recharge. Such assessment is very complex in karst aquifers. Most methods are developed for application to detrital aquifers, without taking into account the extraordinary heterogeneity of porosity and permeability of karst systems. It is commonly recommended to estimate recharge using multiple methods; however, differences inherent to the diverse methods make it difficult to clarify the accuracy of each result. In this study, recharge was estimated in a karst aquifer working in a natural regime, in a Mediterranean-type climate, in the western part of the Sierra de las Nieves (southern Spain). Mediterranean climate regions are characterized by high inter-annual rainfall variability featuring long dry periods and short intense wet periods, the latter constituting the most important contribution to aquifer water input. This paper aims to identify the methods that provide the most plausible range of recharge rate during wet periods. Six methods were tested: the classical method of Thornthwaite-Mather, the Visual Balan code, the chloride balance method, and spatially distributed methods such as APLIS, a novel spatiotemporal estimation of recharge, and ZOODRM. The results help determine valid methods for application in the rest of the unit of study and in similar karst aquifers. © 2014, National Ground Water Association.

[Variation Characteristics and Sources of Heavy Metals in an Urban Karst Groundwater System during Rainfall Event].

PubMed

Ren, Kun; Yang, Ping-heng; Jiang, Ze-li; Wang, Zun-bo; Shi, Yang; Wang, Feng-kang; Li, Xiao-chun

2015-04-01

The groundwater discharge and heavy metal concentrations (Mn, Pb, Cu and As) at the outlet of Nanshan Laolongdong karst subterranean river, located at the urban region in Chongqing, were observed during the rainfall events. Analysis of flow and concentrations curves was employed to study their responses to the rainfall events and explore the internal structure of karst hydrological system. Principal component analysis (PCA) and measurements were used to identify the sources of heavy metals during rainfall. The result showed that the discharge and concentrations of the heavy metals responded promptly to the rainfall event. The variation characteristics of flow indicated that Laolongdong subterranean river system belonged to a karst hydrological system including fractures together with conduits. Urban surface runoff containing large amounts of Mn, Pb and Cu went directly to subterranean river via sinkholes, shafts and karst windows. As a result, the peak concentrations of contaminants (Mn, Pb and Cu) flowed faster than those of discharge. The major sources of water pollution were derived from urban surface runoff, soil and water loss. Cave dripwater and rainwater could also bring a certain amount of Mn, Pb and As into the subterranean river. Urban construction in karst areas needs scientific and rational design, perfect facilities and well-educated population to prevent groundwater pollution from the source.

Coho Salmon populations in the Karst landscape of north Prince of Wales Island, southeast Alaska.

Treesearch

M.D. Bryant; D.N. Swanston

1998-01-01

Karst topography is a unique and distinct landscape and its geology may have important implications for salmon productivity in streams. The relationship between salmonid communities and water chemistry and the influence of habitat was examined in a set of streams on north Prince of Wales Island, southeast Alaska. Streams in karst landscapes showed higher alkalinities (...

Sedimentary patterns in perched spring travertines near Granada (Spain) as indicators of the paleohydrological and paleoclimatological evolution of a karst massif

NASA Astrophysics Data System (ADS)

Martín-Algarra, Agustín.; Martín-Martín, Manuel; Andreo, Bartolomé; Julià, Ramón; González-Gómez, Cecilio

2003-10-01

Perched spring travertines of the Granada basin (South Spain) constitute a perched system with four well-defined steps, which are formed by several facies associations deposited in different sub-environments (travertine pools, dams and cascades). These perched travertines are considered as a freshwater reef system with a facies zonation and stratigraphic architecture closely resembling that of marine reef terraces and prograding carbonate platforms. The travertine deposits have been dated by 230Th/ 234U and 14C methods. As in other Mediterranean areas, the travertine deposition occurred episodically during warm and wet interglacial periods coinciding with isotopic stages 9, 7 and 5, and with the transition between isotopic stages 2/1. During these periods, underground dissolution, large outflow in the springs and subsequent calcium carbonate precipitation occurred. In the same way that evolution of reef systems indicates sea level changes, the geomorphology, age and architecture of perched spring travertine systems may be used to interpret former climatically controlled changes in outflow, in base level marked by the altitude of springs and in the chemistry of spring waters. Thus, aggradation or climbing progradation may indicate an increase of outflow at the spring, progradation with toplap is due to a stable base level and, conversely, dowlapping progradation may signify that the base level was gradually dropping. Therefore, the travertines can be considered semiquantitative indicators of the paleohydrological evolution of karstic massifs and used as an important terrestrial proxy climate record.

The cost of karst subsidence and sinkhole collapse in the United States compared with other natural hazards

USGS Publications Warehouse

Weary, David J.

2015-01-01

Rocks with potential for karst formation are found in all 50 states. Damage due to karst subsidence and sinkhole collapse is a natural hazard of national scope. Repair of damage to buildings, highways, and other infrastructure represents a significant national cost. Sparse and incomplete data show that the average cost of karst-related damages in the United States over the last 15 years is estimated to be at least $300,000,000 per year and the actual total is probably much higher. This estimate is lower than the estimated annual costs for other natural hazards; flooding, hurricanes and cyclonic storms, tornadoes, landslides, earthquakes, or wildfires, all of which average over $1 billion per year. Very few state organizations track karst subsidence and sinkhole damage mitigation costs; none occurs at the Federal level. Many states discuss the karst hazard in their State hazard mitigation plans, but seldom include detailed reports of subsidence incidents or their mitigation costs. Most State highway departments do not differentiate karst subsidence or sinkhole collapse from other road repair costs. Amassing of these data would raise the estimated annual cost considerably. Information from insurance organizations about sinkhole damage claims and payouts is also not readily available. Currently there is no agency with a mandate for developing such data. If a more realistic estimate could be made, it would illuminate the national scope of this hazard and make comparison with costs of other natural hazards more realistic.

Transport of free and particulate-associated bacteria in karst

USGS Publications Warehouse

Mahler, B.J.; Personne, J.-C.; Lods, G.F.; Drogue, C.

2000-01-01

Karst aquifers, because of their unique hydrogeologic characteristics, are extremely susceptible to contamination by pathogens. Here we present the results of an investigation of contamination of a karst aquifer by fecal indicator bacteria. Two wells intercepting zones with contrasting effective hydraulic conductivities, as determined by pump test, were monitored both during the dry season and in response to a rain event. Samples were also collected from the adjacent ephemeral surface Stream, which is known to be impacted by an upstream wastewater treatment plant after rainfall. Whole water and suspended sediment samples were analyzed for fecal coliforms and enterococci. During the dry season, pumping over a 2-day period resulted in increases in concentrations of fecal coliforms to greater than 10,000 CFU/100 ml in the high-conductivity well; enterococci and total suspended solids also increased, to a lesser degree. Toward the end of the pumping period, as much as 50% of the fecal coliforms were associated with suspended sediment. Irrigation of an up-gradient pine plantation with primary-treated wastewater is the probable source of the bacterial contamination. Sampling after a rain event revealed the strong influence of water quality of the adjacent Terrieu Creek on the ground water. Bacterial concentrations in the wells showed a rapid response to increased concentrations in the surface water, with fecal coliform concentrations in ground water ultimately reaching 60,000 CFU/100 ml. Up to 100% of the bacteria in the ground water was associated with suspended sediment at various times. The results of this investigation are evidence of the strong influence of surface water on ground water in karst terrain, including that of irrigation water. The large proportion of bacteria associated with particulates in the ground Water has important implications for public health, as bacteria associated with particulates may be more persistent and more difficult to inactivate. The

Bacterial and archaeal phylogenetic diversity of a cold sulfur-rich spring on the shoreline of Lake Erie, Michigan

USGS Publications Warehouse

Chaudhary, A.; Haack, S.K.; Duris, J.W.; Marsh, T.L.

2009-01-01

Studies of sulfidic springs have provided new insights into microbial metabolism, groundwater biogeochemistry, and geologic processes. We investigated Great Sulphur Spring on the western shore of Lake Erie and evaluated the phylogenetic affiliations of 189 bacterial and 77 archaeal 16S rRNA gene sequences from three habitats: the spring origin (11-m depth), bacterial-algal mats on the spring pond surface, and whitish filamentous materials from the spring drain. Water from the spring origin water was cold, pH 6.3, and anoxic (H2, 5.4 nM; CH4, 2.70 ??M) with concentrations of S2- (0.03 mM), SO42- (14.8 mM), Ca2+ (15.7 mM), and HCO3- (4.1 mM) similar to those in groundwater from the local aquifer. No archaeal and few bacterial sequences were >95% similar to sequences of cultivated organisms. Bacterial sequences were largely affiliated with sulfur-metabolizing or chemolithotrophic taxa in Beta-, Gamma-, Delta-, and Epsilonproteobacteria. Epsilonproteobacteria sequences similar to those obtained from other sulfidic environments and a new clade of Cyanobacteria sequences were particularly abundant (16% and 40%, respectively) in the spring origin clone library. Crenarchaeota sequences associated with archaeal-bacterial consortia in whitish filaments at a German sulfidic spring were detected only in a similar habitat at Great Sulphur Spring. This study expands the geographic distribution of many uncultured Archaea and Bacteria sequences to the Laurentian Great Lakes, indicates possible roles for epsilonproteobacteria in local aquifer chemistry and karst formation, documents new oscillatorioid Cyanobacteria lineages, and shows that uncultured, cold-adapted Crenarchaeota sequences may comprise a significant part of the microbial community of some sulfidic environments. Copyright ?? 2009, American Society for Microbiology. All Rights Reserved.

Unconventional antiferromagnetic correlations of the doped Haldane gapsystem Y 2 BaNi 1 - x Zn x O 5

NASA Astrophysics Data System (ADS)

Villar, V.; Mélin, R.; Paulsen, C.; Souletie, J.; Janod, E.; Payen, C.

2002-01-01

We make a new proposal to describe the very low temperature susceptibility of the doped Haldane gap compound Y2BaNi1-xZnxO5. We propose a new mean field model relevant for this compound. The ground state of this mean field model is unconventional because antiferromagnetism coexists with random dimers. We present new susceptibility experiments at very low temperature. We obtain a Curie-Weiss susceptibility χ(T) C/(Θ + T) as expected for antiferromagnetic correlations but we do not obtain a direct signature of antiferromagnetic long range order. We explain how to obtain the ``impurity'' susceptibility (T) by subtracting the Haldane gap contribution to the total susceptibility. In the temperature range [1 K, 300 K] the experimental data are well fitted by T (T) = Cimp 1 + Timp/T . In the temperature range [100 mK, 1 K] the experimental data are well fitted by T (T) = A ln(T/Tc), where Tc increases with x. This fit suggests the existence of a finite Néel temperature which is however too small to be probed directly in our experiments. We also obtain a maximum in the temperature dependence of the ac-susceptibility (T) which suggests the existence of antiferromagnetic correlations at very low temperature.

Characterisation of the heterogeneity of karst using electrical geophysics - applications in SW China

NASA Astrophysics Data System (ADS)

Binley, A. M.; Cheng, Q.; Tao, M.; Chen, X.

2017-12-01

The southwest China karst region is one of the largest globally continuous karst areas. The great (structural, hydrological and geochemical) complexity of karstic environments and their rapidly evolving nature make them extremely vulnerable to natural and anthropogenic processes/activities. Characterising the location and properties of structures within the karst critical zone, and understanding how the landform is evolving is essential for the mitigation and adaption to locally- and globally-driven changes. Because of the specific nature of karst geology and geomorphology in the humid tropics and subtropics, spatial heterogeneity is high, evidenced by specific landforms features. Such heterogeneity leads to a high dynamic variability of hydrological processes in space and time, along with a complex exchange of surface water and groundwater. Investigating karst hydrogeological features is extremely challenging because of the three-dimensional nature of the system. Observations from boreholes can vary significantly over several metres, making conventional aquifer investigative methods limited. Geophysical methods have emerged as potentially powerful tools for hydrogeological investigations. Geophysical surveys can help to obtain more insight into the complex conduit networks and depth of weathering, both of which can provide quantitative information about the hydrological and hydrochemical dynamics of the system, in addition to providing a better understanding of how critical zone structures have been established and how the landscape is evolving. We present here results from recent geophysical field campaigns in SW China. We illustrate the effectiveness of electrical methods for mapping soil infil in epikarst and report results from field-based investigations along hillslope and valley transects. Our results reveal distinct zones of relatively high electrical conductivity to depths of tens of metres, which we attribute to localised increased fracture density. We

TEAM Science Advances STEM through Experiential Learning about Karst Geology at the Ozark Underground Laboratory.

NASA Astrophysics Data System (ADS)

Haskins, M. F.; Patterson, J. D.; Ruckman, B.; Keith, N.; Aley, C.; Aley, T.

2017-12-01

Carbonate karst represents approximately 14% of the world's land area and 20-25% of the land area in the United States. Most people do not understand this three dimensional landscape because they lack direct experience with this complicated geology. For the last 50 years, Ozark Underground Laboratory (OUL), located in Protem, MO, has been a pioneer in the research of karst geology and its influence on groundwater. OUL has also provided surface and sub-surface immersion experiences to over 40,000 individuals including students, educators, and Department of Transportation officials helping those individuals better understand the challenges associated with karst. Rockhurst University has incorporated OUL field trips into their educational programming for the last 30 years, thus facilitating individual understanding of karst geology which comprises approximately 60% of the state. Technology and Educators Advancing Missouri Science (TEAM Science) is a grant-funded professional development institute offered through Rockhurst University. The institute includes an immersion experience at OUL enabling in-service teachers to better understand natural systems, the interplay between the surface, sub-surface, and cave fauna, as well as groundwater and energy dynamics of karst ecosystems. Educating elementary teachers about land formations is especially important because elementary teachers play a foundational role in developing students' interest and aptitude in STEM content areas. (Funding provided by the U.S. Department of Education's Math-Science Partnership Program through the Missouri Department of Elementary and Secondary Education.)

Hydrological processes in glacierized high-altitude basins of the western Himalayas

NASA Astrophysics Data System (ADS)

Jeelani, Ghulam; Shah, Rouf A.; Fryar, Alan E.; Deshpande, Rajendrakumar D.; Mukherjee, Abhijit; Perrin, Jerome

2018-03-01

Western Himalaya is a strategically important region, where the water resources are shared by China, India and Pakistan. The economy of the region is largely dependent on the water resources delivered by snow and glacier melt. The presented study used stable isotopes of water to further understand the basin-scale hydro-meteorological, hydrological and recharge processes in three high-altitude mountainous basins of the western Himalayas. The study provided new insights in understanding the dominant factors affecting the isotopic composition of the precipitation, snowpack, glacier melt, streams and springs. It was observed that elevation-dependent post-depositional processes and snowpack evolution resulted in the higher isotopic altitude gradient in snowpacks. The similar temporal trends of isotopic signals in rivers and karst springs reflect the rapid flow transfer due to karstification of the carbonate aquifers. The attenuation of the extreme isotopic input signal in karst springs appears to be due to the mixing of source waters with the underground karst reservoirs. Basin-wise, the input-output response demonstrates the vital role of winter precipitation in maintaining the perennial flow in streams and karst springs in the region. Isotopic data were also used to estimate the mean recharge altitude of the springs.

Estimating the input of wastewater-born micropollutants in a rural karst catchment (Gallusquelle, Germany)

NASA Astrophysics Data System (ADS)

Zirlewagen, Johannes; Hillebrand, Olav; Nödler, Karsten; Schiperski, Ferry; Scheytt, Traugott; Licha, Tobias

2013-04-01

The main focus of the AGRO research project is on the use of various micropollutants as indicators (e.g. for wastewater) in the catchment of the karst spring Gallusquelle, Swabian Alb. For modeling the micropollutants' fate in the subsurface and their occurrence in spring water, reliable estimates of the spatio-temporal input, i.e. input functions, are crucial. Therefore potential sources for wastewater-born substances are identified. These are the combined sewer system with a stormwater retention basin (untreated wastewater) and the river Fehla (treated wastewater). The micropollutants' concentrations and loads in the potentially infiltrating waters are estimated on the one hand by local water and substance consumption data and on the other hand by water sample analysis and stream gauging. The spring's discharge varies from 0.2-2.0 m³/s with an average of 0.5 m³/s. Treated spring water serves as drinking water for 45 000 people. The catchment area measures 45 km² and is rural in character with 55% forest, 27% grassland, 15% agriculture and 3% residential/industrial. Industrial activity is restricted to a few minor textile and metal works. There are around 4 000 inhabitants and except for a few farms, all households are connected to the public sewer system. The only surface water within the catchment is the stream Fehla, which forms a part of the catchment boundary. It was formerly identified as a sinking stream with an ephemeral part in the lower course. Connections to the Gallusquelle spring were proven by several tracer tests conducted in the 1960's, when the river started to become perennial over the whole course due to heavy colmatation. During a one week campaign, samples of wastewater and river water were taken three times per day. Additionally, hourly samples were taken during a 24 h period. Water samples were analysed for major ions and 58 micropollutants, including pharmaceuticals, stimulants (as caffeine), the artificial sweeteners acesulfame and

Estimation of underground river water availability based on rainfall in the Maros karst region, South Sulawesi

NASA Astrophysics Data System (ADS)

Arsyad, Muhammad; Ihsan, Nasrul; Tiwow, Vistarani Arini

2016-02-01

Maros karst region, covering an area of 43.750 hectares, has water resources that determine the life around it. Water resources in Maros karst are in the rock layers or river underground in the cave. The data used in this study are primary and secondary data. Primary data includes characteristics of the medium. Secondary data is rainfall data from BMKG, water discharge data from the PSDA, South Sulawesi province in 1990-2010, and the other characteristics data Maros karst, namely cave, flora and fauna of the Bantimurung Bulusaraung National Park. Data analysis was conducted using laboratory test for medium characteristics Maros karst, rainfall and water discharge were analyzed using Minitab Program 1.5 to determine their profile. The average rainfall above 200 mm per year occurs in the range of 1999 to 2005. The availability of the water discharge at over 50 m3/s was happened in 1993 and 1995. Prediction was done by modeling Autoregressive Integrated Moving Average (ARIMA), with the rainfall data shows that the average precipitation for four years (2011-2014) will sharply fluctuate. The prediction of water discharge in Maros karst region was done for the period from January to August in 2011, including the type of 0. In 2012, the addition of the water discharge started up in early 2014.

Analysis of interrelation between water quality and hydrologic conditions on a small karst catchment area of sinking watercourse Trbuhovica

NASA Astrophysics Data System (ADS)

Hinić, V.; Rubinić, J.; Vučković, I.; Ružić, I.; Gržetić, A.; Volf, G.; Ljubotina, M.; Kvas, N.

2008-11-01

Sinking watercourse Trbuhovica is located at the topping karst of Gorski Kotar in Croatia, near the Slovenian border. About 900 inhabitants live in Trbuhovica catchment area. Sewage system had not been built. The project KEEP WATERS CLEAN (INTERREG III A project) was approved by EU commission and has a purpose of investigating water resources of that area, their appropriate protection and improving management of those resources. This paper presents project's 1st phase investigation results: hydrologic conditions and water quality at several locations on stream and at the springs of Trbuhovica, Mlake and Obrh. Climatologic (precipitation, air temperature and snow cover), basic hydrologic characteristics (flow and water temperature), water quality parameters (pH, electric conductivity, alkalinity, oxygen regime, nutrients and mineral oils) and microbiology indicators have been monitored. Samples of micro invertebrates and samples of periphyton have been collected in the field. Biological results have been elaborated via Saprobial Index according to Pantle-Buck. Analyses results showed a strong connection between hydrologic condition and selected water quality parameters. The groundwater quality changes are very quick. Maximum pollutions occur during the period of intensive rain. Water at the spring of Mlaka is very clean and is classified in the first to second water category, while Trbuhovica shows higher organic pollution.

Modeling of karst deformation and analysis of acoustic emission during sinkhole formation

NASA Astrophysics Data System (ADS)

Bakeev, R. A.; Stefanov, Yu. P.; Duchkov, A. A.; Myasnikov, A. V.

2017-12-01

In this paper, the fracture pattern and formation of a sinkhole are estimated depending on the rock properties. The possibility of using geophysical methods for recording and analyzing acoustic emission to monitor and predict the state of the medium is considered. The problem of deformation of the sedimentary cover over the growing karst cavity is solved on the basis of the elastoplastic Drucker-Prager-Nikolaevsky model and the equation of damage accumulation. The specified kinetics of accumulation of damages allows us to describe slow processes of degradation of the strength of the medium under stresses that are low for the development of inelastic deformations. The results are obtained for different values of the strength of karst rock; we show the influence of the kinetic parameters of damage accumulation on the shape of collapse depressions. We also model acoustic emission caused by the material fracture. One can follow different stages of the karst development by looking at patterns of cells which fail at a given time. Our observations show the relation between the intensity of material fracture and the intensity of seismic emission.

Preliminary Map of Potentially Karstic Carbonate Rocks in the Central and Southern Appalachian States

USGS Publications Warehouse

Weary, David J.

2008-01-01

Karst is a landscape produced by dissolution of rocks and the development of integrated subterranean drainages dominated by the flow of ground water in solutionally enlarged conduits. Karst landscapes typically include cave entrances, sinkholes, blind valleys, losing streams, springs, and large and small-scale solution features on bedrock surfaces. Water-bearing rocks beneath the surface containing solutionally enlarged pores, fractures, or conduits are referred to as karst aquifers. About 40 percent of all ground water extracted in the United States comes from karst aquifers (Karst Waters Institute). Karst means many things to many people. To most cavers and many speleologists, karst means areas containing caves. To engineers, home builders, local governments, and insurance companies, karst is exemplified by the occurrence of sinkholes and subsidence hazard. To hydrologists, well drillers, and environmental consultants, the focus on karst may be more limited to karst aquifers and springs. Precise figures are not available, but ground collapses in karst areas in the United States require hundreds of millions of dollars in repair and mitigation costs each year. Most karst in the United States is formed in either carbonate or evaporite rocks. This map depicts only areas of carbonate rock outcrop, the chief host for karst formation in the eastern United States. The U.S. Geological Survey (USGS), in cooperation with the National Cave and Karst Research Institute (NCKRI), the National Speleological Society (NSS), and various State geological surveys, is working on a new national karst map that will delineate areas of karst and karst-like features nationwide. This product attempts to identify potentially karstic areas of the Appalachian states as defined by the Appalachian Regional Commission (ARC), with the addition of the state of Delaware. This map is labeled preliminary because there is an expectation that it will be revised and updated as part of a new national

Identification, prediction, and mitigation of sinkhole hazards in evaporite karst areas

USGS Publications Warehouse

Gutierrez, F.; Cooper, A.H.; Johnson, K.S.

2008-01-01

Sinkholes usually have a higher probability of occurrence and a greater genetic diversity in evaporite terrains than in carbonate karst areas. This is because evaporites have a higher solubility and, commonly, a lower mechanical strength. Subsidence damage resulting from evaporite dissolution generates substantial losses throughout the world, but the causes are only well understood in a few areas. To deal with these hazards, a phased approach is needed for sinkhole identification, investigation, prediction, and mitigation. Identification techniques include field surveys and geomorphological mapping combined with accounts from local people and historical sources. Detailed sinkhole maps can be constructed from sequential historical maps, recent topographical maps, and digital elevation models (DEMs) complemented with building-damage surveying, remote sensing, and high-resolution geodetic surveys. On a more detailed level, information from exposed paleosubsidence features (paleokarst), speleological explorations, geophysical investigations, trenching, dating techniques, and boreholes may help in investigating dissolution and subsidence features. Information on the hydrogeological pathways including caves, springs, and swallow holes are particularly important especially when corroborated by tracer tests. These diverse data sources make a valuable database-the karst inventory. From this dataset, sinkhole susceptibility zonations (relative probability) may be produced based on the spatial distribution of the features and good knowledge of the local geology. Sinkhole distribution can be investigated by spatial distribution analysis techniques including studies of preferential elongation, alignment, and nearest neighbor analysis. More objective susceptibility models may be obtained by analyzing the statistical relationships between the known sinkholes and the conditioning factors. Chronological information on sinkhole formation is required to estimate the probability of

Karst system vadose zone hydrodynamics highlighted by an integrative geophysical and hydrogeological monitoring

NASA Astrophysics Data System (ADS)

Watlet, A.; Van Camp, M. J.; Francis, O.; Poulain, A.; Hallet, V.; Rochez, G.; Kaufmann, O.

2015-12-01

The vadose zone of karst systems plays an important role on the water dynamics. In particular, temporary perched aquifers can appear in the subsurface due to changes of climate conditions, diminished evapotranspiration and differences of porosity relative to deeper layers. It is therefore crucial, but challenging, to separate the hydrological signature of the vadose zone from the one of the saturated zone for understanding hydrological processes that occur in the vadose zone. Although many difficulties are usually encountered when studying karst environments due to their heterogeneities, cave systems offer an outstanding opportunity to investigate vadose zone from the inside with various techniques. We present results covering two years of hydrogeological and geophysical monitoring at the Rochefort Cave Laboratory (RCL), located in the Variscan fold-and-thrust belt (Belgium), a region that shows many karstic networks within Devonian limestone units. Hydrogeological data such as flows and levels monitoring or tracer tests performed in both vadose and saturated zones bring valuable information on the hydrological context of the studied area. Combining those results with geophysical measurements allows validating and imaging them with more integrative techniques. A microgravimetric monitoring involves a superconducting gravimeter continuously measuring at the surface of the RCL. Early in 2015, a second relative gravimeter was installed in the underlying cave system located 35 meters below the surface. This set up allows highlighting vadose gravity changes. These relative measurements are calibrated using an absolute gravimeter. 12 additional stations (7 at the surface, 5 in the cave) are monitored on a monthly basis by a spring gravimeter. To complete these gravimetric measurements, the site has been equipped with a permanent Electrical Resistivity Tomography (ERT) monitoring system comprising an uncommon array of surface, borehole and cave electrodes. Although such

[Contamination and ecological risk assessment of polycyclic aromatic hydrocarbons in water and in Karst underground river catchment].

PubMed

Lan, Jia-Cheng; Sun, Yu-Chuan; Tian, Ping; Lu, Bing-Qing; Shi, Yang; Xu, Xin; Liang Zuo-Bing; Yang, Ping-Heng

2014-10-01

Water samples in Laolongdong underground river catchment were collected to determine the concentration, compositional profiles, and evaluate ecological risk of 16 priority polycyclic aromatic hydrocarbons (PAHs). PAHs were measured by GC/MS. The total concentrations of 16 PAH ranged from 81.5-8019 ng · L(-1) in underground river, 288.7-15,200 ng · L(-1) in karst springs, and 128.4-2,442 ng · L(-1) in surface water. Affected by waste water from Huangjueya town, concentrations of PAHs in underground river were higher than those in surface water and waste water from sinkhole. The PAHs profiles were dominated by 3 ring PAHs. There were differences of monthly variations of PAHs contents in the water, due to waste water, season and different characteristics of PAH. Surface water and waste water from sinkhole played an important role on contamination in the river. The levels of ecological risk were generally moderately polluted and heavily polluted according to all detected PAH compounds in the water.

Use of limestone karst forests by Bornean orangutans (Pongo pygmaeus morio) in the Sangkulirang peninsula, east Kalimantan, Indonesia.

PubMed

Marshall, Andrew J; Salas, Leonardo A; Stephens, Suzette; Engström, Linda; Meijaard, Erik; Stanley, Scott A

2007-02-01

The Indonesian province of East Kalimantan is home to some of the largest remaining contiguous tracts of lowland Dipterocarp forest on the island of Borneo. Nest surveys recently conducted in these forests indicated the presence of a substantial population of Eastern Bornean orangutans (Pongo pygmaeus morio) in the Berau and East Kutai regencies in the northern half of the province. The Sangkulirang Peninsula contains extensive limestone karst forests in close proximity to the lowland Dipterocarp forests inhabited by orangutans in these regencies. Orangutans have been sighted in these limestone karst forests, but the importance of this forest type for orangutans has been unclear. Therefore, we conducted 49 km of nest surveys in limestone karst forest to obtain the first quantitative estimates of orangutan densities in this habitat, and walked 28 km of surveys in nearby lowland Dipterocarp forests for comparison. We also gathered basic ecological data along our transects in an attempt to identify correlates of orangutan abundance across these habitat types. Undisturbed limestone karst forests showed the lowest orangutan densities (147 nests/km(2), 0.82 indiv/km(2)), disturbed limestone forests had intermediate densities (301 nests/km(2), 1.40 indiv/km(2)), and undisturbed lowland Dipterocarp forests contained the highest density (987 nests/km(2), 5.25 indiv/km(2)), significantly more than the undisturbed limestone karst forests. This difference was not correlated with variation in liana abundance, fig stem density, or stump density (an index of forest disturbance). Therefore, other factors, such as the relatively low tree species diversity of limestone karst forests, may explain why orangutans appear to avoid these areas. We conclude that limestone karst forests are of low relevance for safeguarding the future of orangutans in East Kalimantan.

Evaluation of Karst Soil Erosion and Nutrient Loss Based on RUSLE Model in Guizhou Province

NASA Astrophysics Data System (ADS)

Zeng, Cheng; Li, Yangbing; Bai, Xiaoyong; Luo, Guangjie

2018-01-01

Based on GIS technology and RUSLE model, the spatial variation characteristics of soil erosion were analyzed in karst areas, and the relationship between soil erosion and soil nutrient loss was discussed. The results showed that the soil differences in spatial variation between nutrient losses. The results illustrate the total soil erosion in is 10316.31 × 104t • a-1, accounting for 84.95% of the total land area in Guizhou Province. The spatial distribution of soil erosion showing the characteristics of the southeast to the northwest strip. The annual average soil erosion modulu is 691.94 t • km-2 • a-1, of which karst is 720.28t • km-2 • a-1 and non-karst is 689.53 t • km-2 • a-1. The total nutrient losses such as soil organic carbon (SOC), total nitrogen (TN), total phosphorus (TP) and total potassium (TK) were 596.72 × 104t • a-1 due to soil erosion, and SOC, TN and TP and TK were 38.13, 1.61, 0.41 and 14.70t • km-2 • a-1, respectively. The average amount of loss and total loss are the largest in non-karst, and four kinds of nutrient is the smallest in karst gorge. The spatial variation of soil erosion in the study area is the process of increasing the erosion area with the increase of the erosion rate, and the difference of the spatial distribution of soil erosion determines the spatial distribution of soil nutrient loss.

Adaptations of indigenous bacteria to fuel contamination in karst aquifers in south-central Kentucky

USGS Publications Warehouse

Byl, Thomas D.; Metge, David W.; Agymang, Daniel T.; Bradley, Michael W.; Hileman, Gregg; Harvey, Ronald W.

2014-01-01

The karst aquifer systems in southern Kentucky can be dynamic and quick to change. Microorganisms that live in these unpredictable aquifers are constantly faced with environmental changes. Their survival depends upon adaptations to changes in water chemistry, taking advantage of positive stimuli and avoiding negative environmental conditions. The U.S. Geological Survey conducted a study in 2001 to determine the capability of bacteria to adapt in two distinct regions of water quality in a karst aquifer, an area of clean, oxygenated groundwater and an area where the groundwater was oxygen depleted and contaminated by jet fuel. Water samples containing bacteria were collected from one clean well and two jet fuel contaminated wells in a conduit-dominated karst aquifer. Bacterial concentrations, enumerated through direct count, ranged from 500,000 to 2.7 million bacteria per mL in the clean portion of the aquifer, and 200,000 to 3.2 million bacteria per mL in the contaminated portion of the aquifer over a twelve month period. Bacteria from the clean well ranged in size from 0.2 to 2.5 mm, whereas bacteria from one fuel-contaminated well were generally larger, ranging in size from 0.2 to 3.9 mm. Also, bacteria collected from the clean well had a higher density and, consequently, were more inclined to sink than bacteria collected from contaminated wells. Bacteria collected from the clean portion of the karst aquifer were predominantly (,95%) Gram-negative and more likely to have flagella present than bacteria collected from the contaminated wells, which included a substantial fraction (,30%) of Gram-positive varieties. The ability of the bacteria from the clean portion of the karst aquifer to biodegrade benzene and toluene was studied under aerobic and anaerobic conditions in laboratory microcosms. The rate of fuel biodegradation in laboratory studies was approximately 50 times faster under aerobic conditions as compared to anaerobic, sulfur-reducing conditions. The

Calculation of the Strip Foundation on Solid Elastic Base, Taking into Account the Karst Collapse

NASA Astrophysics Data System (ADS)

Sharapov, R.; Lodigina, N.

2017-07-01

Karst processes greatly complicate the construction and operation of buildings and structures. Due to the karstic deformations at different times there have been several major accidents, which analysis showed that in all cases the fundamental errors committed at different stages of building development: site selection, engineering survey, design, construction or operation of the facilities. Theory analysis of beams on elastic foundation is essential in building practice. Specialist engineering facilities often have to resort to multiple designing in finding efficient forms of construction of these facilities. In work the calculation of stresses in cross-sections of the strip foundation evenly distributed load in the event of karst. A comparison of extreme stress in the event of karst and without accounting for the strip foundation as a beam on an elastic foundation.

Quantifying hyporheic exchange in a karst stream using 222Rn

NASA Astrophysics Data System (ADS)

Khadka, M. B.; Martin, J. B.; Kurz, M. J.

2013-12-01

conventional in-stream tracer injection method which estimates exchange between the stream and both the hyporheic zone and the surface transient storage zone, the 222Rn approach measures the water exchange between stream and hyporheic sediments only. Although the present method is tested on a spring-fed karst stream, it has potential for any freshwater system (e.g. wetland, lake) where distinct radon activity and production between surface water and underlying sediments occur.

Stable sulfur and oxygen isotopes as geochemical tracers of sulfate in karst waters

NASA Astrophysics Data System (ADS)

Sun, Jing; Kobayashi, Tatsuaki; Strosnider, William H. J.; Wu, Pan

2017-08-01

Karst water resources, which are extremely sensitive to mining activities, are critical for the support of human societies and ecological systems in many regions worldwide. In order to determine the sources and fate of dissolved sulfate in low-pH karst waters, hydrochemical variations of karst waters with and without acid mine drainage (AMD) impacts were investigated along with stable isotope dynamics. As expected, hydrochemical characteristics and isotopic compositions of the AMD and AMD-downstream water (ADW) were dramatically different from that of the non-AMD-impacted water (NAW). The sources of sulfur isotopes in sulfate were predominantly pyrite oxidation for the AMD and ADW, and atmospheric deposition for the NAW. Based on the general isotope-balance model, the relative proportions of sulfate oxygen derived from water and air were calculated. The mean proportion of sulfate oxygen derived from water in ADW was roughly double that of AMD. This suggests that the sulfate associated with AMD is predominantly influenced by aerobic pyrite oxidation, while that of ADW is likely affected by the dissolution of pyrite under anaerobic conditions in reservoir sediment. This observation was coincident with the noted variations of hydrochemical characteristics and was supported by principal component analysis. These results provide a better understanding of how stable isotopes of sulfate and water can be used to track mining contamination in karst aquifers, which could benefit remediation planning for these distinctive systems.

Molecular characters of melon (Cucumismelo L. "Tacapa") in response to karst critical land

NASA Astrophysics Data System (ADS)

Rachmawati, Yuanita; Daryono, Budi Setiadi; Aristya, Ganies Riza

2017-06-01

Yogyakarta district has 158.600 ha critical land and spread off in three Agro Ecosystem zones. Two of them are karsts critical land. Critical lands which contain calcium carbonate in high concentration and water dehydration in upper surface give abiotic stress in wide range of plant. Melon cultivar TACAPA has superior characteristic derived from parental crossing, ♀ Action 434 and ♂ PI 371795 and potential to be developed in karsts critical land. Abscicic acid (ABA) is a phytohormone expressed by plant in abiotic stress condition. CmBG1 is a gene which regulate ABA hormone in melon. The purposes of this research were examining the molecular character of melon cultivar TACAPA in response to karsts critical land in order to study molecular characterization of CmBG1 gene. Analysis was done qualitatively by using Reverse Transcriptase-PCR (RT-PCR) and Electrophoresis, while quantitative analysis was conducted by observing absorbance score in spectrophotometer. CmBG1 gene expression is examined by using Real time PCR (qPCR). Molecular characters obtained are CmBG1 detected in size ±1258 bp, CmBG1 gene concentrations in melon which planted in control media are lower than melon in critical lands media. These results are similar with the real time quantitative analysis method. It also be revealed that melon TACAPA is more potential plant compared to another cultivar that can be developed in karst critical land area.

Speleogenesis, geometry, and topology of caves: A quantitative study of 3D karst conduits

NASA Astrophysics Data System (ADS)

Jouves, Johan; Viseur, Sophie; Arfib, Bruno; Baudement, Cécile; Camus, Hubert; Collon, Pauline; Guglielmi, Yves

2017-12-01

Karst systems are hierarchically spatially organized three-dimensional (3D) networks of conduits behaving as drains for groundwater flow. Recently, geostatistical approaches proposed to generate karst networks from data and parameters stemming from analogous observed karst features. Other studies have qualitatively highlighted relationships between speleogenetic processes and cave patterns. However, few studies have been performed to quantitatively define these relationships. This paper reports a quantitative study of cave geometries and topologies that takes the underlying speleogenetic processes into account. In order to study the spatial organization of caves, a 3D numerical database was built from 26 caves, corresponding to 621 km of cumulative cave passages representative of the variety of karst network patterns. The database includes 3D speleological surveys for which the speleogenetic context is known, allowing the polygenic karst networks to be divided into 48 monogenic cave samples and classified into four cave patterns: vadose branchwork (VB), water-table cave (WTC), looping cave (LC), and angular maze (AM). Eight morphometric cave descriptors were calculated, four geometrical parameters (width-height ratio, tortuosity, curvature, and vertical index) and four topological ones (degree of node connectivity, α and γ graph indices, and ramification index) respectively. The results were validated by statistical analyses (Kruskal-Wallis test and PCA). The VB patterns are clearly distinct from AM ones and from a third group including WTC and LC. A quantitative database of cave morphology characteristics is provided, depending on their speleogenetic processes. These characteristics can be used to constrain and/or validate 3D geostatistical simulations. This study shows how important it is to relate the geometry and connectivity of cave networks to recharge and flow processes. Conversely, the approach developed here provides proxies to estimate the evolution of

Temporal variation of chemical and isotopic signals in major discharges of an alpine karst aquifer in Turkey: implications with respect to response of karst aquifers to recharge

NASA Astrophysics Data System (ADS)

Ozyurt, N. Nur; Bayari, C. Serdar

2008-03-01

Proper management of karst aquifers requires a better understanding of flow and transport mechanisms in these systems. Flow in karst aquifers is inherently very complex due to the non-linear and non-stationary relationship between recharge and discharge. Information on this relationship has been acquired for a large (1,000 km2), mountainous (>3,500 m asl) karst aquifer with a deep unsaturated zone (>2,000 m) in the Aladaglar mountain range of south-central Turkey. All major discharges from the aquifer, which drain almost all the recharge, have been observed periodically for specific electrical conductivity, tritium and oxygen-18 variations during a period of 12 months. Observations reveal that the system’s response to recharge depends strongly on the competition between the infiltration and drainage velocities. These velocities, which are controlled by variables such as the time of precipitation, time of infiltration, intensity, and continuity of recharge, determine the degree of dominance of different types of flow mechanisms in the aquifer. Bypass, well-mixed and piston flow mechanisms are used to explain the response of the aquifer to the spatio-temporal variations in recharge. It appears that the aquifer switches among these flow mechanisms depending on the prevailing recharge mode and the competition between infiltration and drainage velocities.

Evaluating susceptibility of karst dolines (sinkholes) for collapse in Sango, Tennessee, USA.

PubMed

Siska, Peter P; Goovaerts, Pierre; Hung, I-K

2016-08-01

Dolines or sinkholes are earth depressions that develop in soluble rocks complexes such as limestone, dolomite, gypsum, anhydrite, and halite; dolines appear in a variety of shapes from nearly circular to complex structures with highly curved perimeters. The occurrence of dolines in the studied karst area is not random; they are the results of geomorphic, hydrologic, and chemical processes that have caused partial subsidence, even the total collapse of the land surface when voids and caves are present in the bedrock and the regolith arch overbridging these voids is unstable. In the study area, the majority of collapses occur in the regolith (bedrock cover) that bridges voids in the bedrock. Because these collapsing dolines may result in property damage and even cause the loss of lives, there is a need to develop methods for evaluating karst hazards. These methods can then be used by planners and practitioners for urban and economic development, especially in regions with a growing population. The purpose of this project is threefold: 1) to develop a karst feature database, 2) to investigate critical indicators associated with doline collapse, and 3) to develop a doline susceptibility model for potential doline collapse based on external morphometric data. The study has revealed the presence of short range spatial dependence in the distribution of the dolines' morphometric parameters such as circularity, the geographic orientation of the main doline axes, and the length-to-width doline ratios; therefore, geostatistics can be used to spatially evaluate the susceptibility of the karst area for doline collapse. The partial susceptibility estimates were combined into a final probability map enabling the identification of areas where, until now, undetected dolines may cause significant hazards.

Bioindication of human-induced soil degradation in enclosed karst depressions (dolines) using Ellenberg indicator values (Classical Karst, Slovenia).

PubMed

Breg Valjavec, Mateja; Zorn, Matija; Čarni, Andraž

2018-05-29

One of the frequently used bioindication methods is Ellenberg indicator values (EIVs), which are commonly applied in Central Europe as bioindicators of ecological characteristics. However, very few studies have tested EIVs as a bioindication of human-induced soil degradation. We tested the ability of EIVs to distinguish between localities of degraded karst depressions (dolines) and localities of semi-natural (agricultural) soils in preserved dolines on the Kras Plateau (Classical Karst, SW Slovenia). We compared the results of bioindications of soil nutrient content (N), soil reaction (R) and soil moisture (M) with measured soil parameters. Low values of organic carbon, a slightly alkaline soil reaction and low organic sulphur content are chemical indicators of soil degradation in dolines, in comparison with preserved reference dolines (high organic carbon, slightly acid reaction, higher S). EIV reaction is the most reliable plant indicator value that can distinguish between degraded and non-degraded soil plots. According to a regression tree, sulphur (S) and C/N are the most important factors for division on the basis of EIV reaction. By applying the EIV reaction of diagnostic plant species, we significantly improved bioindication of soil degradation, although in the case of EIV nutrients, bioindication was not improved. Copyright © 2018. Published by Elsevier B.V.

Fate of Organic Matters in a Soil Erosion Context : Qualitative and Quantitative Monitoring in a Karst Hydrosystem

NASA Astrophysics Data System (ADS)

Quiers, M.; Gateuille, D.; Perrette, Y.; Naffrechoux, E.; David, B.; Malet, E.

2017-12-01

Soils are a key compartments of hydrosystems, especially in karst aquifers which are characterized by fast hydrologic responses to rainfalls. In steady state, soils are efficient filters preventing karst water from pollutions. But agricultural or forestry land uses can alter or even reverse the role of soils. Thus , soils can act as pollution sources rather than pollution filters. In order to manage water quality together with man activities in karst environment, the development of new tools and procedures designed to monitor the fate of soil organic matter are needed. This study reports two complementary methods applied in a moutain karst system impacted by anthropic activities and environmental stresses. A continuous monitoring of water fluorescence coupled with punctual sampling was analyzed by chemiometric methods and allowed to discriminate the type of organic matter transferred through the karst system along the year (winter / summer) and hydrological stages. As a main result, the modelisation of organic carbone fluxes is dominated by a colloidal or particulate part during highwaters, and a main part dissolved in solution during low water, demonstrating the change of organic carbone source. To confirm this result, a second method was used based on the observation of Polycyclic Aromatic Hydrocarbons (PAH) profiles. Two previous studies (Perrette et al 2013, Schwarz et al 2011) led to opposite conclusions about the fate of PAH from soil to groundwaters. This opposition leads to a potential use of PAH profiles (low molecular weight less hydrophobic ones versus high molecular weight more hydrophobic ones) as an indicator of soil erosion. We validate that use by the anaylsis of these PAH profiles for low and high waters (floods). These results demonstrate if needed the high vulnerability of karst system to soil erosion, and propose a new proxy to record soils erosion in groundwaters and in natural archives as stalagmites or sediments.

Electrical Resistivity Tomography monitoring reveals groundwater storage in a karst vadose zone

NASA Astrophysics Data System (ADS)

Watlet, A.; Kaufmann, O.; Van Camp, M. J.; Triantafyllou, A.; Cisse, M. F.; Quinif, Y.; Meldrum, P.; Wilkinson, P. B.; Chambers, J. E.

2016-12-01

Karst systems are among the most difficult aquifers to characterize, due to their high heterogeneity. In particular, temporary groundwater storage that occurs in the unsaturated zone and the discharge to deeper layers are difficult processes to identify and estimate with in-situ measurements. Electrical Resistivity Tomography (ERT) monitoring is meant to track changes in the electrical properties of the subsurface and has proved to be applicable to evidence and quantify hydrological processes in several types of environments. Applied to karst systems, it has particularly highlighted the challenges in linking electrical resistivity changes to groundwater content with usual approaches of petrophysical relationships, given the high heterogeneity of the subsurface. However, taking up the challenge, we undertook an ERT monitoring at the Rochefort Cave Laboratory (Belgium) lasting from Spring 2014 to Winter 2016. This includes 3 main periods of several months with daily measurements, from which seasonal groundwater content changes in the first meters of the vadose zone were successfully imaged. The monitoring concentrates on a 48 electrodes profile that goes from a limestone plateau to the bottom of a sinkhole. 3D UAV photoscans of the surveyed sinkhole and of the main chamber of the nearby cave were performed. Combined with lithological observations from a borehole drilled next to the ERT profile, the 3D information made it possible to project karstified layers visible in the cave to the surface and assess their potential locations along the ERT profile. Overall, this helped determining more realistic local petrophysical properties in the surveyed area, and improving the ERT data inversion by adding structural constraints. Given a strong air temperature gradient in the sinkhole, we also developed a new approach of temperature correction of the raw ERT data. This goes through the solving (using pyGIMLI package) of the 2D ground temperature field and its temporal

Adapted hydropower-driven water supply system: assessment of an underground application in an Indonesian karst area

NASA Astrophysics Data System (ADS)

Oberle, P.; Ikhwan, M.; Stoffel, D.; Nestmann, F.

2016-09-01

Populated karst landscapes can be found all over the world, although their natural boundary conditions mostly lead to distinct challenges regarding a sustainable water supply. Especially in developing and emerging countries, this situation aggravates since appropriate technologies and water management concepts are rarely available. Against this background, the interdisciplinary, German-Indonesian joint project " Integrated Water Resources Management (IWRM) Indonesia", funded by the German Federal Ministry of Education and Research (BMBF), focused on the development and exemplary implementation of adapted techniques to remedy the partly severe water scarcity in the region Gunung Sewu. This karst area, widely known as " Java's poorhouse", is located on the southern coast of Java Island and distinctly suffers from the mentioned constraints. Under the aegis of the Karlsruhe Institute of Technology (KIT), the conceptual and technical achievements of the "IWRM Indonesia" joint research project are characterized by a high potential for multiplication not only for karst areas but also for non-karst regions. One of the project's major accomplishments is the erection of an innovative hydropower-driven water supply facility located in a karst cave 100 m below ground and continuously supplying tens of thousands of people with fresh water. Referring to the plant's innovative character and the demanding conditions on-site, the implementation was a highly iterative process leading to today's autonomous operation by an Indonesian public authority. Based on the experiences gained during design, construction, operation and monitoring phase, this paper introduces an implementation approach for adapted technologies as well as a comprising technical and economical assessment of the plant's operation.

Geomorphic interaction among climate, sea levels and karst groundwater: the Taranto area (South of Italy)

NASA Astrophysics Data System (ADS)

Spilotro, Giuseppe; Fidelibus, Maria Dolores; Argentiero, Ilenia; Pellicani, Roberta; Parisi, Alessandro; Di Modugno, Antonella

2017-04-01

The area of Taranto (Apulia region, Italy) has an extraordinary environmental and landscape value, which derives from its specific geological, geomorphological and hydrogeological conditions: they represent the effect of a complex mechanism of interaction in the geological time among the sea, its level variations and stands driven by climate changes, karst groundwater and the geo lithological frame. The knowledge of this interaction spans over two very different time duration: the first is subsequent to the sedimentary pleistocenic deposition and diagenesis and lasts until the late Holocene; the second spans over a more limited time durations, from the LIA until today, and its knowledge is mainly based on hystorical topographic records and reports. The general geological and stratigraphical setting is represented by marine deposits, which fill the Bradanic Trough, shaped in the upper part as marine terraces bordering the W and SW side of the Murgian carbonate platform (Apulia, South of Italy) as well. This latter constitutes an important karst hydro-structure, fed by precipitation, bordered on the opposite side of the Bradanic Trough by the Adriatic Sea. Fresh groundwater hosted in the huge coastal aquifer freely flows towards the Adriatic coast, while on the opposite W-NW side, the continuous confinement by the impermeable filling of the trough, forces the underground drainage of the aquifer towards the Ionian Sea just in the Taranto area. The overall flow rate of the groundwater through submarine and subaerial coastal springs, according to the current sea level, is significant and currently estimated in about 18 m3/sec. Climate changes have forced over geological time, but also in shorter periods, sea level changes and stands, consequently correlated to groundwater levels. This allowed genesis of selected karst levels, of regional extension, both at the surface or underground, which arise as typical forms, namely polje and karst plane inland, terraces on the sea

Lanthanide-labeled clay: A new method for tracing sediment transport in Karst

USGS Publications Warehouse

Mahler, B.J.; Bennett, P.C.; Zimmerman, M.

1998-01-01

Mobile sediment is a fundamental yet poorly characterized aspect of mass transport through karst aquifers. Here the development and field testing of an extremely sensitive particle tracer that may be used to characterize sediment transport in karst aquifers is described. The tracer consists of micron-size montmorillonite particles homoionized to the lanthanide form; after injection and retrieval from a ground water system, the lanthanide ions are chemically stripped from the clay and quantified by high performance liquid chromatography. The tracer meets the following desired criteria: low detection limit; a number of differentiable signatures; inexpensive production and quantification using standard methods; no environmental risks; and hydrodynamic properties similar to the in situ sediment it is designed to trace. The tracer was tested in laboratory batch experiments and field tested in both surface water and ground water systems. In surface water, arrival times of the tracer were similar to those of a conservative water tracer, although a significant amount of material was lost due to settling. Two tracer tests were undertaken in a karst aquifer under different flow conditions. Under normal flow conditions, the time of arrival and peak concentration of the tracer were similar to or preceded that of a conservative water tracer. Under low flow conditions, the particle tracer was not detected, suggesting that in low flow the sediment settles out of suspension and goes into storage.Mobile sediment is a fundamental yet poorly characterized aspect of mass transport through karst aquifers. Here the development and field testing of an extremely sensitive particle tracer that may be used to characterize sediment transport in karst aquifers is described. The tracer consists of micron-size montmorillonite particles homoionized to the lanthanide form; after injection and retrieval from a ground water system, the lanthanide ions are chemically stripped from the clay and

Assessing Spatio-temporal Variability of Karst Water Storage over Southwest China from GRACE and Reservoir Storage

NASA Astrophysics Data System (ADS)

Yao, C.; Luo, Z.; Lo, M. H.; Li, Q.

2016-12-01

This study assesses spatio-temporal variability of terrestrial water storage (TWS) over the world's largest karst aquifer with continuous coverage in Southwest China (SWC) from Gravity Recovery and Climate Experiment (GRACE), along with hydrological model outputs, precipitation and reservoir water level data. GRACE shows karst water increases for the period 2003/01-2014/06 with a total volume ranging from 29.0 to 49.1 km3, and observes an extremely wet condition in 2008/2009 caused by the increase in precipitation and Longtan Reservoir (LTR) storage. The subsequent two droughts in 2009/2010 and 2011 have resulted in significant aquifer water depletion, with abnormal karst water losses of 180.2±43.3 km3 and 269.8±34.6 km3 respectively. In particular, the sustained reduction in peaks of the LTR storage is associated with the long-term dry condition over the upper Pearl River. Nonseasonal karst TWS variations are considerably impacted by LTR impoundment in the post-dam period, especially for the impounding episode of autumn and the dry season of winter, with correlations of 0.71 and 0.93 between TWS and reservoir volume variations respectively. Additionally, the nonseasonal GRACE TWS deficit provides an alternative and valuable drought indicator for the study karst region since large differences exist in modeled soil moisture and drought indices. This study demonstrates that the combination of GRACE and other hydrological variables could be beneficial for studying karst hydrologic dynamics. Acknowledgments: This work was supported by the National Natural Science Foundation of China (Grant Nos. 41174020, 41131067, 41174021), the National Basic Research Program of China (973 Program) (Grant No. 2013CB733302), the Fundamental Research Funds for the Central Universities (Grant No. 2014214020203), the open fund of Key Laboratory of Geospace Environment and Geodesy, Ministry of Education (Grant No. 14-02-011), the open fund of Guangxi Key Laboratory of Spatial Information

Simulation of Cavern Formation and Karst Development Using Salt

ERIC Educational Resources Information Center

Kent, Douglas C.; Ross, Alex R.

1975-01-01

A salt model was developed as a teaching tool to demonstrate the development of caverns and karst topography. Salt slabs are placed in a watertight box to represent fractured limestone. Erosion resulting from water flow can be photographed in time-lapse sequence or demonstrated in the laboratory. (Author/CP)

Genesis analysis of karst water trichloroethylene pollution in the east of a city

NASA Astrophysics Data System (ADS)

Jiang, Peng; Ma, Zhenmin; Wen, Ming

2017-04-01

To understand the situation of Karst water Trichloroethylene (TCE) pollution in the east of city, Karst water samples sampled at 43 monitoring sites were analyzed. Result shows that relevance ratio of TCE is 100%, over the standard rate of 97.67% and the maximum value is 73.64μg/L, as 14.73 times as the standard value(5μg/L). Causes of groundwater TCE pollution were analyzed. Result shows that indiscriminate discharge of waste water and poor groundwater vulnerability are the main reasons. And based on the reasons, the pollution ways of TCE were found out.

Carbon Storage in an Extensive Karst-distributed Region of Southwestern China based on Multiple Methods

NASA Astrophysics Data System (ADS)

Guo, C.; Wu, Y.; Yang, H.; Ni, J.

2015-12-01

Accurate estimation of carbon storage is crucial to better understand the processes of global and regional carbon cycles and to more precisely project ecological and economic scenarios for the future. Southwestern China has broadly and continuously distribution of karst landscapes with harsh and fragile habitats which might lead to rocky desertification, an ecological disaster which has significantly hindered vegetation succession and economic development in karst regions of southwestern China. In this study we evaluated the carbon storage in eight political divisions of southwestern China based on four methods: forest inventory, carbon density based on field investigations, CASA model driven by remote sensing data, and BIOME4/LPJ global vegetation models driven by climate data. The results show that: (1) The total vegetation carbon storage (including agricultural ecosystem) is 6763.97 Tg C based on the carbon density, and the soil organic carbon (SOC) storage (above 20cm depth) is 12475.72 Tg C. Sichuan Province (including Chongqing) possess the highest carbon storage in both vegetation and soil (1736.47 Tg C and 4056.56 Tg C, respectively) among the eight political divisions because of the higher carbon density and larger distribution area. The vegetation carbon storage in Hunan Province is the smallest (565.30 Tg C), and the smallest SOC storage (1127.40 Tg C) is in Guangdong Province; (2) Based on forest inventory data, the total aboveground carbon storage in the woody vegetation is 2103.29 Tg C. The carbon storage in Yunnan Province (819.01 Tg C) is significantly higher than other areas while tropical rainforests and seasonal forests in Yunnan contribute the maximum of the woody vegetation carbon storage (account for 62.40% of the total). (3) The net primary production (NPP) simulated by the CASA model is 68.57 Tg C/yr, while the forest NPP in the non-karst region (account for 72.50% of the total) is higher than that in the karst region. (4) BIOME4 and LPJ

[Kriging analysis of vegetation index depression in peak cluster karst area].

PubMed

Yang, Qi-Yong; Jiang, Zhong-Cheng; Ma, Zu-Lu; Cao, Jian-Hua; Luo, Wei-Qun; Li, Wen-Jun; Duan, Xiao-Fang

2012-04-01

In order to master the spatial variability of the normal different vegetation index (NDVI) of the peak cluster karst area, taking into account the problem of the mountain shadow "missing" information of remote sensing images existing in the karst area, NDVI of the non-shaded area were extracted in Guohua Ecological Experimental Area, in Pingguo County, Guangxi applying image processing software, ENVI. The spatial variability of NDVI was analyzed applying geostatistical method, and the NDVI of the mountain shadow areas was predicted and validated. The results indicated that the NDVI of the study area showed strong spatial variability and spatial autocorrelation resulting from the impact of intrinsic factors, and the range was 300 m. The spatial distribution maps of the NDVI interpolated by Kriging interpolation method showed that the mean of NDVI was 0.196, apparently strip and block. The higher NDVI values distributed in the area where the slope was greater than 25 degrees of the peak cluster area, while the lower values distributed in the area such as foot of the peak cluster and depression, where slope was less than 25 degrees. Kriging method validation results show that interpolation has a very high prediction accuracy and could predict the NDVI of the shadow area, which provides a new idea and method for monitoring and evaluation of the karst rocky desertification.

Hydrological deformation signals in karst systems: new evidence from the European Alps

NASA Astrophysics Data System (ADS)

Serpelloni, E.; Pintori, F.; Gualandi, A.; Scoccimarro, E.; Cavaliere, A.; Anderlini, L.; Belardinelli, M. E.; Todesco, M.

2017-12-01

The influence of rainfall on crustal deformation has been described at local scales, using tilt and strain meters, in several tectonic settings. However, the literature on the spatial extent of rainfall-induced deformation is still scarce. We analyzed 10 years of displacement time-series from 150 continuous GPS stations operating across the broad zone of deformation accommodating the N-S Adria-Eurasia convergence and the E-ward escape of the Eastern Alps toward the Pannonian basin. We applied a blind-source-separation algorithm based on a variational Bayesian Independent Component Analysis method to the de-trended time-series, being able to characterize the temporal and spatial features of several deformation signals. The most important ones are a common mode annual signal, with spatially uniform response in the vertical and horizontal components and a time-variable, non-cyclic, signal characterized by a spatially variable response in the horizontal components, with stations moving (up to 8 mm) in the opposite directions, reversing the sense of movement in time. This implies a succession of extensional/compressional strains, with variable amplitudes through time, oriented normal to rock fractures in karst areas. While seasonal displacements in the vertical component (with an average amplitude of 4 mm over the study area) are satisfactorily reproduced by surface hydrological loading, estimated from global assimilation models, the non seasonal signal is associated with groundwater flow in karst systems, and is mainly influencing the horizontal component. The temporal evolution of this deformation signal is correlated with cumulated precipitation values over periods of 200-300 days. This horizontal deformation can be explained by pressure changes associated with variable water levels within vertical fractures in the vadose zones of karst systems, and the water level changes required to open or close these fractures are consistent with the fluctuations of precipitation

Origin and development of inland notches in the Classical Karst (NE Adriatic)

NASA Astrophysics Data System (ADS)

Furlani, Stefano; Biolchi, Sara; Devoto, Stefano; Raad, Fadl

2017-04-01

Karst landscapes show morphological features that are different compared to other lithological settings. Inland notches, sub-horizontal indentations extending along carbonate cliffs, are common in the Mediterranean area, in tropical, alpine and semi-arid environments, and develop because of higher erosion rates in correspondence of lithological differences. They can be extended over maximum some hundreds of meters, with an amplitude ranging from 0.5 to 3 m. There is a lack of quantitative data on inland notches with respect to marine notches. We aim at discussing their genesis and evolution by means of morphometric, thermal lithological and micro erosion meter data collected in the Classical Karst area. Rock type is thought to be important in the development of inland notches. Thin sections show that the central part of inland notches are made of more soluble limestones, so lowering rates are higher inside notches rather than outside. Preliminary data on mean lowering rates support the idea that small differences in limestone texture produce differences up to 5 μm/year in lowering rates. For this purpose, their formation is usually associated with limestone beds, although the role and magnitude of karst processes is not completely known. Thermal data show that inland notches are always warmer than the surrounding slopes, with maximum measured differences of 7.5°C. The difference in temperature is higher during the day with respect to the night mainly because of insolation. Data support the hypothesis that inland notches are presently carved in correspondence of even very small differences in lowering rates mainly along bedding planes and, secondly, along geological weakness, such as joints or fractures, as long as lithological differences occur. We assess present understanding of the roles of climate, structural and lithological conditions in inland notches development by new data collected in the Classical Karst area.

Evaluating susceptibility of karst dolines (sinkholes) for collapse in Sango, Tennessee, USA

PubMed Central

Siska, Peter P.; Goovaerts, Pierre; Hung, I-K

2016-01-01

Dolines or sinkholes are earth depressions that develop in soluble rocks complexes such as limestone, dolomite, gypsum, anhydrite, and halite; dolines appear in a variety of shapes from nearly circular to complex structures with highly curved perimeters. The occurrence of dolines in the studied karst area is not random; they are the results of geomorphic, hydrologic, and chemical processes that have caused partial subsidence, even the total collapse of the land surface when voids and caves are present in the bedrock and the regolith arch overbridging these voids is unstable. In the study area, the majority of collapses occur in the regolith (bedrock cover) that bridges voids in the bedrock. Because these collapsing dolines may result in property damage and even cause the loss of lives, there is a need to develop methods for evaluating karst hazards. These methods can then be used by planners and practitioners for urban and economic development, especially in regions with a growing population. The purpose of this project is threefold: 1) to develop a karst feature database, 2) to investigate critical indicators associated with doline collapse, and 3) to develop a doline susceptibility model for potential doline collapse based on external morphometric data. The study has revealed the presence of short range spatial dependence in the distribution of the dolines’ morphometric parameters such as circularity, the geographic orientation of the main doline axes, and the length-to-width doline ratios; therefore, geostatistics can be used to spatially evaluate the susceptibility of the karst area for doline collapse. The partial susceptibility estimates were combined into a final probability map enabling the identification of areas where, until now, undetected dolines may cause significant hazards. PMID:27616807

Experimental study of solute transport in pool-pipe system and its significance on karst hydrogeology

NASA Astrophysics Data System (ADS)

Zhao, X.; Chang, Y.; Peng, F.; Wu, J.

2016-12-01

Study of solute transport in karst conduit is of great significance for prediction and prevention of groundwater pollution in southwest karst region. Solute transport in karst conduit is strongly influenced by pools which often develop along karst conduit. In order to investigate the effect of transient storage within pools on solute transport in the conduit, a pool-pipe system was built in the laboratory and some tracer tests were performed in various flow conditions to characterize the solute transport in different pool-pipe structures. The Qtracer2 program was used to obtain solute transport parameters. We used retardation coefficient R to characterize the difference between the 1-D analytical solution of the classical advection-dispersion equation and experimental results. The experimental results reveal that the concentration peak decreases with the number of pools whereas the dispersion coefficient and dispersivity increase gradually. Adding transient storage increases retardation as tailing of the breakthrough curve(BTC) is growing with the number of pools. This demonstrates that transient storage within pools is transformed to retardation. The symmetrical pool has longer tails compared to the asymmetrical pool. The concentration peak lag behind significantly due to the asymmetrical pool. A decrease in dispersivity and tailing of the BTC is observed in all pipes with the increase of flow velocities. The 1-D analytical solution of the classical advection-dispersion equation is well fitted to BTC of a single pipe in maximum flow velocity but is poorly fitted to other BTCs with appreciable tails. Therefore, it requires an appropriate model to explain tailing of the BTC. The conclusion has important significance for understanding of solute transport process in karst conduit. Future work will focus on using the appropriate model to explain tailing of the BTC.

Runoff response to climate change and human activities in a typical karst watershed, SW China.

PubMed

Xu, Yan; Wang, Shijie; Bai, Xiaoyong; Shu, Dongcai; Tian, Yichao

2018-01-01

This study aims to reveal the runoff variation characteristics of long time series in a karst region, analyse comprehensively its different driving factors, and estimate quantitatively the contribution rates of climate change and human activities to net runoff variation. Liudong river basin, a typical karst watershed in southwest China, is the study site. Statistical methods, such as linear fitting, the Morlet wavelet analysis, normalized curve and double mass curve, are applied to analyse the runoff of the watershed. Results show that the runoff in the karst watershed during the research period exhibits a three-stage change and the abrupt change points are the years 1981 and 2007: (1) 1968-1980, the runoff initially exhibited a trend of sustained decreasing and then an abrupt fluctuation. The runoff was obviously destroyed through precipitation-producing processes. Improper land utilisation and serious forest and grass destruction intensified the fluctuation variation amplitude of the runoff. (2) 1981-2006, the changing processes of runoff and precipitation exhibited good synchronism. Precipitation significantly affected runoff variation and human activities had a slight interference degree. (3) 2007-2013, the fluctuation range of runoff was considerably smaller than that of precipitation. The significant growth of forest and grassland areas and the increase in water consumption mitigated runoff fluctuation and greatly diminished runoff variation amplitude. According to calculation, the relative contribution rates of precipitation and human activities to net runoff variation with 1981-2007 as the reference period were -81% and 181% in average, respectively, during 1968-1980, and -117% and 217% in average, respectively, during 2007-2013. In general, the analysis of runoff variation trend and of the contribution rate of its main influencing factors in the typical karst watershed for nearly half a century may be significant to solve the drought problem in the karst

Transit time distributions to assess present and future contamination risk of karst aquifers over Europe and the Mediterranean

NASA Astrophysics Data System (ADS)

Hartmann, Andreas; Gleeson, Tom; Wada, Yoshihide; Wagener, Thorsten

2016-04-01

Karst develops through the dissolution of carbonate rock. Karst groundwater in Europe is a major source of fresh water contributing up to half of the total drinking water supply in some countries. Climate model projections suggest that in the next 100 years, karst regions will experience a strong increase in temperature and a serious decrease of precipitation - especially in the Mediterranean region. Previous work showed that the karstic preferential recharge processes result in enhanced recharge rates and future climate sensitivity. But as there is fast water flow form the surface to the aquifer, there is also an enhanced risk of groundwater contamination. In this study we will assess the contamination risk of karst aquifers over Europe and the Mediterranean using simulated transit time distributions. Using a new type of semi-distributed model that considers the spatial heterogeneity of the karst system by distribution functions we simulated a range of spatially variable pathways of karstic groundwater recharge. The model is driven by the bias-corrected 5 GCMs of the ISI-MIP project (RCP8.5). Transit time distributions are calculated by virtual tracer experiments. These are repeated several times in the present (1991-2010) and the future (2080-2099). We can show that regions with larger fractions of preferential recharge show higher risks of contamination and that spatial patterns of contamination risk change towards the future.

Physicochemical and microbial assessment of spring water quality for drinking supply in Piedmont of Béni-Mellal Atlas (Morocco)

NASA Astrophysics Data System (ADS)

Barakat, Ahmed; Meddah, Redouane; Afdali, Mustapha; Touhami, Fatima

2018-04-01

The present study was conducted to examine the water quality of karst springs located along the Piedmont of Béni-Mellal Atlas (Morocco) for drinking purposes. Twenty-five water samples were collected from seven springs in June, July, August and September 2013, and May 2016 have been analyzed for their physicochemical and microbial characteristics. The analytical data of temperature, pH, DO, TAC, TH, oxidizability and NH4+ showed that all sampled springs are suitable as drinking water according to Moroccan and the World Health Organization (WHO) standards. Nevertheless, EC, turbidity, and NO3- were sometimes noted higher than the allowable limits, what would be ascribed to erosion and leaching of soil and karstic rocks. The microbial analysis revealed the presence of fecal contamination (total coliforms, E. coli, and intestinal enterococci) in all springs at various times. The water quality index (WQI) calculated based on physicochemical and microbial data reveled that water quality categorization for all sampling springs was found to be 'medium' to 'good' for drinking uses in the National Sanitation Foundation WQI (NSF-WQI), and ''necessary treatment becoming more extensive'' to ''purification not necessary'' in the Dinius' Second Index (D-WQI). The Aine Asserdoune and Foum el Anceur springs showed the good quality of drinking water. According to Moroccan standards for water used for drinking purposes, the waters belong to category A1 that requires becoming drinkable a simple physical treatment and disinfection. From the type of parameters present in quantities exceeding drinking water limits, it is very obvious that these water resources are under the influence of anthropogenic activities such as sewage, waste disposal, deforestation and agricultural activities, caused land degradation and nonpoint pollution sources. Environmental attention, such as systematic quality control and adequate treatment before being used for drinking use and access to sewage