Sample records for klab maailm nii

  1. National information infrastructure (NII) at supercomputing `93

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shay, H.D.

    1993-12-31

    The author anticipates that NII will actually encompass many different kinds of institutions and enterprises. The kinds of players may be technology providers (hardware or software), carriers (telcos), service providers (libraries, etc.), regulators, or users. The spectrum of possible NII functions includes digital libraries, education, health services, and enterprise integration. The participating institutions comprise federal, state, and local governments, educational systems, GOCO laboratories, commercial enterprises, regulated utilities, and individual citizens. The level of NII technology will be both high and low. Some aspects of NII are actively being implemented today, and other will not commence for several years. The relevantmore » issues span a gamut as broad as any public policy arena: politics, commercial profitability, laws and regulations, national well-being, sociology, and technology. This panel discussion juxtaposes individuals responsible for driving radically different kinds of NII-like activities. The intent is to explore the many aspects of NII by contrasting their perspectives.« less

  2. The NII and the New World Trade Agreement.

    ERIC Educational Resources Information Center

    Smoot, Oliver

    1994-01-01

    Examines the relationship between the National Information Infrastructure (NII) and the new General Agreement on Tariffs and Trade. Topics discussed include the reduction or elimination of tariffs on NII products; protection of copyrighted works; unresolved trade issues, including the European telecommunications market; standards; and privacy and…

  3. Herschel Galactic plane survey of ionized gas traced by [NII

    NASA Astrophysics Data System (ADS)

    Yildiz, Umut; Goldsmith, Paul; Pineda, Jorge; Langer, William

    2015-01-01

    Far infrared and sub-/millimeter atomic & ionic fine structure and molecular rotational lines are powerful tracers of star formation on both Galactic and extragalactic scales. Although CO lines trace cool to moderately warm molecular gas, ionized carbon [CII] produces the strongest lines, which arise from almost all reasonably warm (T>50 K) parts of the ISM. However, [CII] alone cannot distinguish highly ionized gas from weakly ionized gas. [NII] plays a significant role in star formation as it is produced only in ionized regions; in [HII] regions as well as diffuse ionized gas. The ionization potential of nitrogen (14.5 eV) is greater than that of hydrogen (13.6 eV), therefore the ionized nitrogen [NII] lines reflect the effects of massive stars, with possible enhancement from X-ray and shock heating from the surroundings. Two far-infrared 122 um and 205 um [NII] fine structure spectral lines are targeted via Photodetector Array Camera and Spectrometer (PACS) onboard Herschel Space Observatory. The sample consists of 149 line-of-sight (LOS) positions in the Galactic plane. These positions overlap with the [CII] 158 um observations obtained with the GOT C+ survey. With a reasonable assumption that the emission from both 122 um and 205 um lines originate in the same gas; [NII] 122/205 um line ratio indicates the a good measure of the electron density of each of the LOS positions. [NII] detections are mainly toward the Galactic center direction and the [NII] electron densities are found between 7-50 cm^-3, which is enhanced WIM (Warm Ionized Medium). WIM densities are expected to be much lower (~1 cm-3), therefore non-detections toward the opposite side of the Galactic Center shows abundant of this gas. The pixel to pixel variation of the emission within a single Herschel pointing is relatively small, which is interpreted as the [NII] emission comes from an extended gas. It is important to quantify what fraction of [CII] emission arises in the ionized gas. Thus, with

  4. The Information Superhighway and the National Information Infrastructure (NII).

    ERIC Educational Resources Information Center

    Griffith, Jane Bortnick; Smith, Marcia S.

    1994-01-01

    Discusses issues connected with the information superhighway and the National Information Infrastructure (NII). Topics addressed include principles for government action; economic benefits; regulations; applications; information policy; pending federal legislation; private sector/government relationship; open access and universal service; privacy…

  5. VizieR Online Data Catalog: NiI transition probability measurements (Wood+, 2014)

    NASA Astrophysics Data System (ADS)

    Wood, M. P.; Lawler, J. E.; Sneden, C.; Cowan, J. J.

    2014-04-01

    As in much of our previous branching fraction work, this NiI branching fraction study makes use of archived FTS data from both the 1.0m Fourier Transform Spectrometer (FTS) previously at the National Solar Observatory (NSO) on Kitt Peak and the Chelsea Instruments FT500 UV FTS at Lund University in Sweden. Table 1 lists the 37 FTS spectra used in our NiI branching fraction study. All NSO spectra, raw interferograms, and header files are available in the NSO electronic archives. The 80 CCD frames of spectra from commercial Ni HCD lamps of the echelle spectrograph are listed in Table 2. (6 data files).

  6. The [CII]/[NII] far-infrared line ratio at z>5: extreme conditions for “normal” galaxies

    NASA Astrophysics Data System (ADS)

    Pavesi, Riccardo; Riechers, Dominik; Capak, Peter L.; Carilli, Chris Luke; Sharon, Chelsea E.; Stacey, Gordon J.; Karim, Alexander; Scoville, Nicholas; Smolcic, Vernesa

    2017-01-01

    Thanks to the Atacama Large (sub-)Millimeter Array (ALMA), observations of atomic far-infrared fine structure lines are a very productive way of measuring physical properties of the interstellar medium (ISM) in galaxies at high redshift, because they provide an unobscured view into the physical conditions of star formation. While the bright [CII] line has become a routine probe of the dynamical properties of the gas, its intensity needs to be compared to other lines in order to establish the physical origin of the emission. [NII] selectively traces the emission coming from the ionized fraction of the [CII]-emitting gas, offering insight into the phase structure of the ISM. Here we present ALMA measurements of [NII] 205 μm fine structure line emission from a representative sample of galaxies at z=5-6 spanning two orders of magnitude in star formation rate (SFR). Our results show at least two different regimes of ionized gas properties for galaxies in the first billion years of cosmic time, separated by their L[CII]/L[NII] ratio. First, we find extremely low [NII] emission compared to [CII] from a “typical” Lyman Break Galaxy (LBG-1), likely due to low dust content and reminiscent of local dwarfs. Second, the dusty Lyman Break Galaxy HZ10 and the extreme starburst AzTEC-3 show ionized gas fractions typical of local star-forming galaxies and show hints of spatial variations in their [CII]/[NII] line ratio. These observations of far-infrared lines in “normal” galaxies at z>5 yield some of the first constraints on ISM models for young galaxies in the first billion years of cosmic time and shed light on the observed evolution of the dust and gas properties.

  7. Field evaluations of a forestry version of DRAINMOD-NII model

    Treesearch

    S. Tian; M. A. Youssef; R.W. Skaggs; D.M. Amatya; G.M. Chescheir

    2010-01-01

    This study evaluated the performance of the newly developed forestry version of DRAINMOD-NII model using a long term (21-year) data set collected from an artificially drained loblolly pine (Pinus taeda L.) plantation in eastern North Carolina, U.S.A. The model simulates the main hydrological and biogeochemical processes in drained forested lands. The...

  8. A Transformation of Learning: Use of the NII for Education and Lifelong Learning.

    ERIC Educational Resources Information Center

    Microcomputers for Information Management, 1995

    1995-01-01

    Suggests uses for the NII (National Information Infrastructure) for education and lifelong learning. Highlights include educational benefits of technology; current uses of telecommunications for education, including instructional video and distance learning; the role of various federal, state, and local agencies; telecommunications in the…

  9. OT2_pgolds01_6: Herschel [NII] Observations to Define the Source of [CII] Emission

    NASA Astrophysics Data System (ADS)

    Goldsmith, P.

    2011-09-01

    The 158 micron line of ionized carbon is the strongest single long-wavelength emission feature from the interstellar medium and is the most important coolant of gas in which hydrogen is in atomic form. It is a key determinant of the evolution of these largely atomic regions into denser, cooler molecular clouds in which new stars are formed, and is widely used as a tracer of star formation in the Milky Way and other galaxies. There is, however, an ongoing, serious controversy about the origin of the [CII] emission, which has been asserted to come from the extended low-density warm interstellar medium, but has more generally been associated with the primarily molecular photon dominated regions (PDRs) intimately associated with massive, young stars. We propose a combined HIFI and PACS study of the two far-infrared [NII] fine structure lines in order to resolve the important question of the fraction of CII emission that arises in ionized gas. Specifically, we will (1) utilize the fact that due to its ionization potential NII is found only in HII regions, and with PACS 122 and 205 micron observations, determine electron densities in a sample of such regions in the Galactic plane; (2) utilize available data on radio free-free and H-alpha emission to determine the NII column densities and from this the CII column densities in the HII regions; (3) use the electron densities to determine the fraction of CII emission arising in the ionized interstellar medium. These observations will be carried out at 150 of the positions in the Galactic plane observed in [CII] by the GOT-C+ project. We will also carry out HIFI observations of 10 selected positions in the 205 micron line to determine spectral characteristics of the NII emission line, which with CII, CI, and CO profiles already in hand will serve as a further discriminant among the proposed sources of CII emission.

  10. Isolation and characterization of novel plant growth promoting Micrococcus sp NII-0909 and its interaction with cowpea.

    PubMed

    Dastager, Syed G; Deepa, C K; Pandey, Ashok

    2010-12-01

    A phosphate-solubilizing bacterial strain NII-0909 isolated from the Western ghat forest soil in India was identified as Micrococcus sp on the basis of phenotypic characteristics, carbon source utilization pattern, fatty acid methyl esters analysis, and 16S rRNA gene sequence. The strain exhibited the plant growth-promoting attributes of phosphate solubilization, auxin production, 1-aminocyclopropane-1-carboxylate deaminase activity, and siderophore production. It was able to solubilize (122.4μg of Ca(3)PO(4) ml(-1)), and produce IAA (109μgml(-1)) at 30°C. P-solubilizing activity of the strain NII-0909 was associated with the release of organic acids and a drop in the pH of the NBRIP medium. HPLC analysis detected two organic acids in the course of P-solubilization. A significant increase in the growth of cow pea was recorded for inoculations under controlled conditions. Scanning electron microscopic study revealed the root colonization of strain on cow pea seedlings. These results demonstrate that isolates NII-0909 has the promising PGPR attributes to be develop as a biofertilizer to enhance soil fertility and promote the plant growth. Copyright © 2010 Elsevier Masson SAS. All rights reserved.

  11. 78 FR 21320 - Unlicensed National Information Infrastructure (U-NII) Devices in the 5 GHz Band

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-04-10

    ... provide a wide array of high data rate mobile and fixed communications for individuals, businesses, and... FEDERAL COMMUNICATIONS COMMISSION 47 CFR Part 15 [ET Docket No. 13-49; FCC 13-22] Unlicensed National Information Infrastructure (U-NII) Devices in the 5 GHz Band AGENCY: Federal Communications...

  12. Emergency Preparedness technology support to the Health and Safety Executive (HSE), Nuclear Installations Inspectorate (NII) of the United Kingdom. Appendix A

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    O`Kula, K.R.

    1994-03-01

    The Nuclear Installations Inspectorate (NII) of the United Kingdom (UK) suggested the use of an accident progression logic model method developed by Westinghouse Savannah River Company (WSRC) and Science Applications International Corporation (SAIC) for K Reactor to predict the magnitude and timing of radioactivity releases (the source term) based on an advanced logic model methodology. Predicted releases are output from the personal computer-based model in a level-of-confidence format. Additional technical discussions eventually led to a request from the NII to develop a proposal for assembling a similar technology to predict source terms for the UK`s advanced gas-cooled reactor (AGR) type.more » To respond to this request, WSRC is submitting a proposal to provide contractual assistance as specified in the Scope of Work. The work will produce, document, and transfer technology associated with a Decision-Oriented Source Term Estimator for Emergency Preparedness (DOSE-EP) for the NII to apply to AGRs in the United Kingdom. This document, Appendix A is a part of this proposal.« less

  13. Spermine stimulation of a nuclear NII kinase from pea plumules and its role in the phosphorylation of a nuclear polypeptide

    NASA Technical Reports Server (NTRS)

    Datta, N.; Schell, M. B.; Roux, S. J.

    1987-01-01

    We have previously demonstrated that spermine stimulates the phosphorylation of a 47 kilodalton nuclear polypeptide from pea plumules (N Datta, LK Hardison, SJ Roux 1986 Plant Physiol 82: 681-684). In this paper we report that spermine stimulates the activity of a cyclic AMP independent casein kinase, partially purified from a chromatin fraction of pea plumule nuclei. This effect of spermine was substrate specific; i.e. with casein as substrate, spermine stimulated the kinase activity, and with phosvitin as substrate, spermine completely inhibited the activity. The stimulation by spermine of the casein kinase was, in part, due to the lowering of the Mg2+ requirement of the kinase. Heparin could partially inhibit this casein kinase activity and spermine completely overcame this inhibition. By further purification of the casein kinase extract on high performance liquid chromatography, we fractionated it into an NI and an NII kinase. Spermine stimulated the NII kinase by 5- to 6-fold but had no effect on the NI kinase. Using [gamma-32P]GTP, we have shown that spermine promotes the phosphorylation of the 47 kilodalton polypeptide(s) in isolated nuclei, at least in part by stimulating an NII kinase.

  14. The fallacy of using NII in analyzing aircraft operations. [Noise Impact Index

    NASA Technical Reports Server (NTRS)

    Melton, R. G.; Jacobson, I. D.

    1984-01-01

    Three measures of noise annoyance (Noise Impact Index, Level-Weighted Population, and Annoyed Population Number) are compared, regarding their utility in assessing noise reduction schemes for aircraft operations. While NII is intended to measure the average annoyance per person in a community, it is found that the method of averaging can lead to erroneous conclusions, particularly if the population does not have uniform spatial distribution. Level-Weighted Population and Annoyed Population Number are shown to be better indicators of noise annoyance when rating different strategies for noise reduction in a given community.

  15. Comprehensive theoretical studies on the low-lying electronic states of NiF, NiCl, NiBr, and NiI.

    PubMed

    Zou, Wenli; Liu, Wenjian

    2006-04-21

    The low-lying electronic states of the nickel monohalides, i.e., NiF, NiCl, NiBr, and NiI, are investigated by using multireference second-order perturbation theory with relativistic effects taken into account. For the energetically lowest 11 lambda-S states and 26 omega states there into, the potential energy curves and corresponding spectroscopic constants (vertical and adiabatic excitation energies, equilibrium bond lengths, vibrational frequencies, and rotational constants) are reported. The calculated results are grossly in very good agreement with those solid experimental data. In particular, the ground state of NiI is shown to be different from those of NiF, NiCl, and NiBr, being in line with the recent experimental observation. Detailed analyses are provided on those states that either have not been assigned or have been incorrectly assigned by previous experiments.

  16. Understanding Emission From The Ism In The Milky Way And Other Galaxies Using [Nii] And Other Tracers

    NASA Astrophysics Data System (ADS)

    Goldsmith, Paul

    We propose to combine recently-obtained data on the far-infrared fine structure lines of ionized nitrogen ([NII]) with studies of radio continuum and other far-infrared lines, to address a number of key questions about the structure of the interstellar medium, star formation, and to bootstrap our detailed understanding of processes in the Milky Way to more distant galaxies. The [CII] 158 μm line is the most powerful single far-infrared line emitted by galaxies, but since carbon can be ionized by photons having wavelengths longer than required to ionized hydrogen, [CII] emission can originate in atomic, molecular, and ionized regions. Due to its ionization potential being higher than that of hydrogen, nitrogen is a more selective tracer than carbon, and can serve as a critical ingredient to determine how much of the [CII] emission is produced in HII regions powered by massive young stars. We propose to take advantage of a newly-completed Herschel survey of the Galactic plane in both of the [NII] lines at 205 μm and 122 μm wavelength, complementing the GOT C+ survey of [CII]. The relative intensity of the two [NII] lines is a direct indicator of the electron density, and thus allows determination of the N+ column density. With the two data sets we can then determine what fraction of the [CII] emission is produced in HII regions, and what may be from the more diffuse components, thus enabling reconciliation of the Herschel and COBE measurements of this critical tracer. We also propose to use Planck and WMAP all-sky maps of the radio free-free emission to determine the emission measure. Comparison with the electron density and ionized nitrogen column density enables a novel probe of clumpiness in this component of the interstellar medium in addition to giving an improved method of determining the overall Galactic electron density distribution. A second aspect of our investigation of clumpiness will be to utilize the fact that each [NII] observation with the PACS

  17. Arrested 1,2-hydrogen migration from silicon to nickel upon oxidation of a three-coordinate Ni(I) silyl complex.

    PubMed

    Iluc, Vlad M; Hillhouse, Gregory L

    2010-09-01

    Reaction of the dimeric Ni(I) chloride complex [(dtbpe)NiCl](2) (1) with dimesitylsilyl potassium affords the three-coordinate Ni(I) silyl complex (dtbpe)Ni(SiHMes(2)) (2). Alternatively, 2 can be prepared by an oxidative-addition reaction of Mes(2)Si(H)OTf (Tf = CF(3)SO(3)) with the nickel(0) complex [(dtbpe)Ni](2)(mu-C(6)H(6)) (3), with (dtbpe)Ni(OTf) (4) formed as an easily separable byproduct. The one-electron oxidation of 2 by ferrocenium affords diamagnetic [(dtbpe)Ni(mu-H)SiMes(2)][BAr(F)(4)] (5), a Ni(II) complex formed by partial 1,2-H migration from silicon to nickel and featuring an unusual 3-center, 2-electron bonding motif between Ni, Si, and the bridging H. Complex 5 was also obtained from Mes(2)SiH(2) activation by the neopentyl complex salt [(dtbpe)Ni(CH(2)CMe(3))][BAr(F)(4)] (6) with elimination of neopentane.

  18. Access to Formally Ni(I) States in a Heterobimetallic NiZn System

    PubMed Central

    Uyeda, Christopher

    2014-01-01

    Heterobimetallic NiZn complexes featuring metal centers in distinct coordination environments have been synthesized using diimine-dioxime ligands as binucleating scaffolds. A tetramethylfuran-containing ligand derivative enables a stable one-electron-reduced S = 1/2 species to be accessed using Cp2Co as a chemical reductant. The resulting pseudo-square planar complex exhibits spectroscopic and crystallographic characteristics of a ligand-centered radical bound to a Ni(II) center. Upon coordination of a π-acidic ligand such as PPh3, however, a five-coordinate Ni(I) metalloradical is formed. The electronic structures of these reduced species provide insight into the subtle effects of ligand structure on the potential and reversibility of the NiII/I couple for complexes of redox-active tetraazamacrocycles. PMID:25614786

  19. Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction

    NASA Astrophysics Data System (ADS)

    Yang, Hong Bin; Hung, Sung-Fu; Liu, Song; Yuan, Kaidi; Miao, Shu; Zhang, Liping; Huang, Xiang; Wang, Hsin-Yi; Cai, Weizheng; Chen, Rong; Gao, Jiajian; Yang, Xiaofeng; Chen, Wei; Huang, Yanqiang; Chen, Hao Ming; Li, Chang Ming; Zhang, Tao; Liu, Bin

    2018-02-01

    Electrochemical reduction of CO2 to chemical fuel offers a promising strategy for managing the global carbon balance, but presents challenges for chemistry due to the lack of effective electrocatalyst. Here we report atomically dispersed nickel on nitrogenated graphene as an efficient and durable electrocatalyst for CO2 reduction. Based on operando X-ray absorption and photoelectron spectroscopy measurements, the monovalent Ni(i) atomic center with a d9 electronic configuration was identified as the catalytically active site. The single-Ni-atom catalyst exhibits high intrinsic CO2 reduction activity, reaching a specific current of 350 A gcatalyst-1 and turnover frequency of 14,800 h-1 at a mild overpotential of 0.61 V for CO conversion with 97% Faradaic efficiency. The catalyst maintained 98% of its initial activity after 100 h of continuous reaction at CO formation current densities as high as 22 mA cm-2.

  20. ISM band to U-NII band frequency transverter and method of frequency transversion

    DOEpatents

    Stepp, Jeffrey David [Grandview, MO; Hensley, Dale [Grandview, MO

    2006-04-04

    A frequency transverter (10) and method for enabling bi-frequency dual-directional transfer of digitally encoded data on an RF carrier by translating between a crowded or otherwise undesirable first frequency band, such as the 2.4 GHz ISM band, and a less-crowded or otherwise desirable second frequency band, such as the 5.0 GHz-6.0 GHz U-NII band. In a preferred embodiment, the transverter (10) connects between an existing data radio (11) and its existing antenna (30), and comprises a bandswitch (12); an input RF isolating device (14); a transmuter (16); a converter (18); a dual output local oscillator (20); an output RF isolating device (22); and an antenna (24) tuned to the second frequency band. The bandswitch (12) allows for bypassing the transverter (10), thereby facilitating its use with legacy systems. The transmuter (14) and converter (16) are adapted to convert to and from, respectively, the second frequency band.

  1. ISM band to U-NII band frequency transverter and method of frequency transversion

    DOEpatents

    Stepp, Jeffrey David [Grandview, MO; Hensley, Dale [Grandview, MO

    2006-09-12

    A frequency transverter (10) and method for enabling bi-frequency dual-directional transfer of digitally encoded data on an RF carrier by translating between a crowded or otherwise undesirable first frequency band, such as the 2.4 GHz ISM band, and a less-crowded or otherwise desirable second frequency band, such as the 5.0 GHz 6.0 GHz U-NII band. In a preferred embodiment, the transverter (10) connects between an existing data radio (11) and its existing antenna (30), and comprises a bandswitch (12); an input RF isolating device (14); a transmuter (16); a converter (18); a dual output local oscillator (20); an output RF isolating device (22); and an antenna (24) tuned to the second frequency band. The bandswitch (12) allows for bypassing the transverter (10), thereby facilitating its use with legacy systems. The transmuter (14) and converter (16) are adapted to convert to and from, respectively, the second frequency band.

  2. X-ray Crystallographic, Multifrequency Electron Paramagnetic Resonance, and Density Functional Theory Characterization of the Ni(P(Cy)2N(tBu)2)2(n+) Hydrogen Oxidation Catalyst in the Ni(I) Oxidation State.

    PubMed

    Niklas, Jens; Westwood, Mark; Mardis, Kristy L; Brown, Tiara L; Pitts-McCoy, Anthony M; Hopkins, Michael D; Poluektov, Oleg G

    2015-07-06

    The Ni(I) hydrogen oxidation catalyst [Ni(P(Cy)2N(tBu)2)2](+) (1(+); P(Cy)2N(tBu)2 = 1,5-di(tert-butyl)-3,7-dicyclohexyl-1,5-diaza-3,7-diphosphacyclooctane) has been studied using a combination of electron paramagnetic resonance (EPR) techniques (X-, Q-, and D-band, electron-nuclear double resonance, hyperfine sublevel correlation spectroscopy), X-ray crystallography, and density functional theory (DFT) calculations. Crystallographic and DFT studies indicate that the molecular structure of 1(+) is highly symmetrical. EPR spectroscopy has allowed determination of the electronic g tensor and the spin density distribution on the ligands, and revealed that the Ni(I) center does not interact strongly with the potentially coordinating solvents acetonitrile and butyronitrile. The EPR spectra and magnetic parameters of 1(+) are found to be distinctly different from those for the related compound [Ni(P(Ph)2N(Ph)2)2](+) (4(+)). One significant contributor to these differences is that the molecular structure of 4(+) is unsymmetrical, unlike that of 1(+). DFT calculations on derivatives in which the R and R' groups are systematically varied have allowed elucidation of structure/substituent relationships and their corresponding influence on the magnetic resonance parameters.

  3. Regional colorectal cancer screening program using colonoscopy on an island: a prospective Nii-jima study.

    PubMed

    Hotta, Kinichi; Matsuda, Takahisa; Kakugawa, Yasuo; Ikematsu, Hiroaki; Kobayashi, Nozomu; Kushima, Ryoji; Hozawa, Atsushi; Nakajima, Takeshi; Sakamoto, Taku; Mori, Mika; Fujii, Takahiro; Saito, Yutaka

    2017-02-13

    Colorectal cancer screening program using fecal immunochemical test had been conducted on an isolated island named Nii-jima. However, the participation rate of the program had been approximately 12%, which was lower than average level of Japan. This study aimed to evaluate the participation rate, safety and efficacy of a colorectal cancer screening program using colonoscopy on the island. Educational campaigns were actively conducted every month using information bulletins and special propaganda pamphlets. The primary recommended modality was colonoscopy, followed by fecal immunochemical test. The participants of this program were 1671 individuals aged 40–79 years (men, 819; women, 852). A total of 789 (47.2%) individuals provided consent for this screening program, and 89.2% (704/789) of participants chose colonoscopy as the primary screening procedure. The completion rate of total colonoscopy was 99.7%, and there was no complication during this program. Detection rates of invasive cancer, intramucosal cancer, advanced neoplasia and any adenoma were 0.9% (n = 6), 2.4% (n = 17), 11.8% (n = 83) and 50.0% (n = 352), respectively. The adenoma detection rate and incidence of advanced neoplasia were significantly higher in men than in women in all age groups. The colorectal cancer screening program using colonoscopy that was conducted on an island achieved considerably higher participation rate than the conventional screening program using fecal immunochemical test. Completion rate and safety of screening colonoscopy were excellent during this program.

  4. The discrimination between star-forming and AGN galaxies in the absence of Hαand [NII]: A machine learning approach

    NASA Astrophysics Data System (ADS)

    Teimoorinia, H.; Keown, J.

    2018-05-01

    In the absence of the two emission lines Hαand [NII] (6584Å) in a BPT diagram, we show that other spectral information is sufficiently informative to distinguish AGN galaxies from star-forming galaxies. We use pattern recognition methods and a sample of galaxy spectra from the Sloan Digital Sky Survey (SDSS) to show that, in this survey, the flux and equivalent width of [OIII] (5007Å) and Hβ, along with the 4000Å break, can be used to classify galaxies in a BPT diagram. This method provides a higher accuracy of predictions than those which use stellar mass and [OIII]/Hβ. First, we use BPT diagrams and various physical parameters to re-classify the galaxies. Next, using confusion matrices, we determine the `correctly' predicted classes as well as confused cases. In this way, we investigate the effect of each parameter in the confusion matrices and rank the physical parameters used in the discrimination of the different classes. We show that in this survey, for example, {g - r} colour can provide the same accuracy as galaxy stellar mass to predict whether or not a galaxy hosts an AGN. Finally, with the same information, we also rank the parameters involved in the discrimination of Seyfert and LINER galaxies.

  5. EEE Links, Volume 9, No. 1, January 2003 Focus on Plastic Parts

    NASA Technical Reports Server (NTRS)

    2003-01-01

    The January 2003 issue of Electronic, Electromechanical, Electric (EEE) Links is presented. The Programmable Logic Application Notes column has been reinstated in this newsletter. Written by Rich Katz of NASA's Office of Logic Design (OLD), the application notes offer technical tips intended to prevent flight design errors and enhance research, development, and use of programmable logic and elements for space flight applications. An archive of these notes columns from previous issues of EEE Links is available at http://www.klabs.org/richcontent/eeelink s/EEE Links.htm.

  6. Building the National Information Infrastructure in K-12 Education: A Comprehensive Survey of Attitudes towards Linking Both Sides of the Desk. A Report of the Global Telecommunications Infrastructure Research Project. Research Report Series.

    ERIC Educational Resources Information Center

    Pereira, Francis; And Others

    This survey was designed to elicit the perceptions of the members of the educational community on four issues concerning the NII (National Information Infrastructure), and to test whether these visions of the NII were shared by educators. The issues were: (1) the benefits of the NII to the education sector and specifically whether the NII will be…

  7. Neuronal intranuclear inclusions are ultrastructurally and immunologically distinct from cytoplasmic inclusions of neuronal intermediate filament inclusion disease

    PubMed Central

    Mosaheb, Sabrina; Thorpe, Julian R.; Hashemzadeh-Bonehi, Lida; Bigio, Eileen H.; Gearing, Marla; Cairns, Nigel J.

    2006-01-01

    Abnormal neuronal cytoplasmic inclusions (NCIs) containing aggregates of α-internexin and the neurofilament (NF) subunits, NF-H, NF-M, and NF-L, are the signature lesions of neuronal intermediate filament (IF) inclusion disease (NIFID). The disease has a clinically heterogeneous phenotype, including fronto-temporal dementia, pyramidal and extrapyramidal signs presenting at a young age. NCIs are variably ubiquitinated and about half of cases also have neuronal intranuclear inclusions (NIIs), which are also ubiquitinated. NIIs have been described in polyglutamine-repeat expansion diseases, where they are strongly ubiquitin immunoreactive. The fine structure of NIIs of NIFID has not previously been described. Therefore, to determine the ultrastructure of NIIs, immunoelectron microscopy was undertaken on NIFID cases and normal aged control brains. Our results indicate that the NIIs of NIFID are strongly ubiquitin immunoreactive. However, unlike NCIs which contain ubiquitin, α-internexin and NF epitopes, NIIs contain neither epitopes of α-internexin nor NF subunits. Neither NIIs nor NCIs were recognised by antibodies to expanded polyglutamine repeats. The NII of NIFID lacks a limiting membrane and contains straight filaments of 20 nm mean width (range 11–35 nm), while NCIs contain filaments with a mean width of 10 nm (range 5–18 nm; t-test, P<0.001). Biochemistry revealed no differences in neuronal IF protein mobilities between NIFID and normal brain tissue. Therefore, NIIs of NIFID contain filaments morphologically and immunologically distinct from those of NCIs, and both types of inclusion lack expanded polyglutamine tracts of the triplet-repeat expansion diseases. These observations indicate that abnormal protein aggregation follows separate pathways in different neuronal compartments of NIFID. PMID:16025283

  8. Services and the National Information Infrastructure. Report of the Information Infrastructure Task Force Committee on Applications and Technology, Technology Policy Working Group. Draft for Public Comment.

    ERIC Educational Resources Information Center

    Office of Science and Technology Policy, Washington, DC.

    In this report, the National Information Infrastructure (NII) services issue is addressed, and activities to advance the development of NII services are recommended. The NII is envisioned to grow into a seamless web of communications networks, computers, databases, and consumer electronics that will put vast amounts of information at users'…

  9. Spatially Resolved Analysis of the Interstellar Medium in the Cosmic Eye, a Lensed Lyman Break Galaxy at z=3.074

    NASA Astrophysics Data System (ADS)

    Ball, Catherine; Riechers, Dominik A.; Pavesi, Riccardo

    2018-01-01

    The [CII]/[NII] ratio combines the [CII] line, a tracer of photodissociation and HII regions emerging from the neutral and ionized phases of the interstellar medium (ISM), with [NII] emission, which only originates from the ionized ISM. In this, the [CII]/[NII] ratio can be used to separate the fractions of [CII] emission emerging from the different phases of the ISM. We present Atacama Large sub-Millimeter Array (ALMA) observations of the Cosmic Eye, a gravitationally lensed Lyman Break Galaxy (LBG). As an LBG, the Cosmic Eye represents a "normal" star forming galaxy in the z>2 universe. LBGs were host to the bulk of star formation during the peak epoch of star formation. Diagnosing star formation in these galaxies provides insight into the evolution of “normal” galaxies in a cosmic sense. The high magnification (30x) allows us to resolve the [CII] 158μm and the [NII] 205μm lines in detail, allowing for a position-resolved analysis of their ratio. We find variations of the line ratio across the galaxy, suggesting the galaxy’s internal structure affects this ratio. We consider the Cosmic Eye in the context of both higher redshift LBGs and local luminous and ultraluminous infrared galaxies, finding that the Cosmic Eye’s line ratio is similar to those of both higher- and lower- redshift galaxies. The Cosmic Eye’s global [CII]/[NII] ratio sits between two previous measurements of z>5 LBGs at low resolution, suggesting that the ratio may correlate more significantly with LFIR than with redshift in this epoch. Furthermore, the Cosmic Eye’s [CII]/[NII] ratio is similar to those of the nearby LIRG/ULIRGs, though we expect local [CII]/[NII] values to be lower due to their different metallicities and dust content. High-resolution studies like this one probe the evolution of [CII]/[NII] over cosmic time by examining the evolution of the ISM’s structure. With a better understanding of the [CII]/[NII] line ratio, we can more effectively use it as a probe of the

  10. Have a little faith: measuring the impact of illness on positive and negative aspects of faith.

    PubMed

    Salsman, John M; Garcia, Sofia F; Lai, Jin-Shei; Cella, David

    2012-12-01

    The importance of faith and its associations with health are well documented. As part of the Patient Reported Outcomes Measurement Information System, items tapping positive and negative impact of illness (PII and NII) were developed across four content domains: Coping/Stress Response, Self-Concept, Social Connection/Isolation, and Meaning and Spirituality. Faith items were included within the concept of meaning and spirituality. This measurement model was tested on a heterogeneous group of 509 cancer survivors. To evaluate dimensionality, we applied two bi-factor models, specifying a general factor (PII or NII) and four local factors: Coping/Stress Response, Self-Concept, Social Connection/Isolation, and Meaning and Spirituality. Bi-factor analysis supported sufficient unidimensionality within PII and NII item sets. The unidimensionality of both PII and NII item sets was enhanced by extraction of the faith items from the rest of the questions. Of the 10 faith items, nine demonstrated higher local than general factor loadings (range for local factor loadings = 0.402 to 0.876), suggesting utility as a separate but related 'faith' factor. The same was true for only two of the remaining 63 items across the PII and NII item sets. Although conceptually and to a degree empirically related to Meaning and Spirituality, Faith appears to be a distinct subdomain of PII and NII, better handled by distinct assessment. A 10-item measure of the impact of illness upon faith (II-Faith) was therefore assembled. Copyright © 2011 John Wiley & Sons, Ltd.

  11. Autophagy-related proteins (p62, NBR1 and LC3) in intranuclear inclusions in neurodegenerative diseases.

    PubMed

    Mori, Fumiaki; Tanji, Kunikazu; Odagiri, Saori; Toyoshima, Yasuko; Yoshida, Mari; Kakita, Akiyoshi; Takahashi, Hitoshi; Wakabayashi, Koichi

    2012-08-01

    Incorporation of ubiquitin and ubiquitin-related proteins including p62 into neuronal intranuclear inclusions (NIIs) has been reported in a variety of neurodegenerative diseases. However, involvement of autophagy-specific proteins (NBR1 and LC3) in NIIs has not been mentioned. We immunohistochemically examined the brain of patients with Machado-Joseph disease (MJD; n=5), dentatorubral-pallidoluysian atrophy (DRPLA; n=5) and intranuclear inclusion body disease (INIBD; n=5), using antibodies against ubiquitin, p62, NBR1 and LC3. The proportion of p62-, NBR1- and LC3-positive inclusions relative to the number of ubiquitin-positive inclusions was calculated in each case. NIIs were positive for p62 in MJD (19.3%), DRPLA (49.7%) and INIBD (99.8%). As for autophagy-specific proteins, NIIs were positive for NBR1 in MJD (4.2%), DRPLA (5.5%) and INIBD (13.2%) and negative for LC3 in MJD, DRPLA and INIBD, except for one case of INIBD. These findings suggest that autophagy-lysosome pathway is not involved in the formation/degradation of NIIs. Copyright © 2012 Elsevier Ireland Ltd. All rights reserved.

  12. First Detections of the [NII] 122 Micrometer Line at High Redshift: Demonstrating the Utility of the Line for Studying Galaxies in the Early Universe

    NASA Technical Reports Server (NTRS)

    Ferkinhoff, Carl; Brisbin, Drew; Nikola, Thomas; Parshley, Stephen C.; Stacey, Gordon J.; Phillips, Thomas G.; Falgarone, Edith; Benford, Dominic J.; Staguhn, Johannes G.; Tucker, Carol E.

    2011-01-01

    We report the first detections of the [NIl] 122 {\\mu} m line from a high redshift galaxy. The line was strongly (> 6{\\sigma}) detected from SMMJ02399-0136, and HI413+ 117 (the Cloverleaf QSO) using the Redshift(z) and Early Universe Spectrometer (ZEUS) on the CSO. The lines from both sources are quite bright with line-to-FIR continuum luminosity ratios that are approx.7.0x10(exp -4) (Cloverleaf) and 2.1x10(exp -3) (SMMJ02399). With ratios 2-10 times larger than the average value for nearby galaxies, neither source exhibits the line-to-continuum deficits seen in nearby sources. The line strengths also indicate large ionized gas fractions, approx.8 to 17% of the molecular gas mass. The [OIII]/[NII] line ratio is very sensitive to the effective temperature of ionizing stars and the ionization parameter for emission arising in the narrow-line region (NLR) of an AGN. Using our previous detection of the [01II] 88 {\\mu}m line, the [OIII]/ [NIl] line ratio for SMMJ02399-0136 indicates the dominant source of the line emission is either stellar HII regions ionized by 09.5 stars, or the NLR of the AGN with ionization parameter 10g(U) = -3.3 to -4.0. A composite system, where 30 to 50% of the FIR lines arise in the NLR also matches the data. The Cloverleaf is best modeled by a superposition of approx.200 M82like starbursts accounting for all of the FIR emission and 43% of the [NIl] line. The remainder may come from the NLR. This work demonstrates the utility of the [NIl] and [OIII] lines in constraining properties of the ionized medium.

  13. The High-Performance Computing and Communications program, the national information infrastructure and health care.

    PubMed Central

    Lindberg, D A; Humphreys, B L

    1995-01-01

    The High-Performance Computing and Communications (HPCC) program is a multiagency federal effort to advance the state of computing and communications and to provide the technologic platform on which the National Information Infrastructure (NII) can be built. The HPCC program supports the development of high-speed computers, high-speed telecommunications, related software and algorithms, education and training, and information infrastructure technology and applications. The vision of the NII is to extend access to high-performance computing and communications to virtually every U.S. citizen so that the technology can be used to improve the civil infrastructure, lifelong learning, energy management, health care, etc. Development of the NII will require resolution of complex economic and social issues, including information privacy. Health-related applications supported under the HPCC program and NII initiatives include connection of health care institutions to the Internet; enhanced access to gene sequence data; the "Visible Human" Project; and test-bed projects in telemedicine, electronic patient records, shared informatics tool development, and image systems. PMID:7614116

  14. Analysis of NASA communications (Nascom) II network protocols and performance

    NASA Technical Reports Server (NTRS)

    Omidyar, Guy C.; Butler, Thomas E.

    1991-01-01

    The NASA Communications (Nascom) Division of the Mission Operations and Data Systems Directorate is to undertake a major initiative to develop the Nascom II (NII) network to achieve its long-range service objectives for operational data transport to support the Space Station Freedom Program, the Earth Observing System, and other projects. NII is the Nascom ground communications network being developed to accommodate the operational traffic of the mid-1990s and beyond. The authors describe various baseline protocol architectures based on current and evolving technologies. They address the internetworking issues suggested for reliable transfer of data over heterogeneous segments. They also describe the NII architecture, topology, system components, and services. A comparative evaluation of the current and evolving technologies was made, and suggestions for further study are described. It is shown that the direction of the NII configuration and the subsystem component design will clearly depend on the advances made in the area of broadband integrated services.

  15. Putting the Information Infrastructure to Work. Report of the Information Infrastructure Task Force Committee on Applications and Technology. NIST Special Publication 857.

    ERIC Educational Resources Information Center

    National Inst. of Standards and Technology, Gaithersburg, MD.

    An interconnection of computer networks, telecommunications services, and applications, the National Information Infrastructure (NII) can open up new vistas and profoundly change much of American life. This report explores some of the opportunities and obstacles to the use of the NII by people and organizations. The goal is to express how…

  16. Connecting the Nation: Classrooms, Libraries, and Health Care Organizations in the Information Age. Update 1995.

    ERIC Educational Resources Information Center

    Gonzalez, Emilio

    Connecting every classroom, library, hospital, and clinic in the United States to the National Information Infrastructure (NII) is a priority for the Clinton Administration. This document provides a status report on this initiative by drawing from current data regarding Internet connectivity, a benchmark for NII access. Chapter 1 of the report…

  17. Aa Ah Nak

    ERIC Educational Resources Information Center

    Tha, Na Gya; Wus, Thay

    2017-01-01

    In this article, Aa Ah Nak, the authors' methodology presents not only various reflections but also diverse contradictions about the Aa Nii language as well as language revitalization. This article explores language foundation and how the Aa Nii language revitalization is inextricably linked to the genocide and resulting historic trauma pervasive…

  18. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bosio, J.; Wilcox, P.; Sembsmoen, O.

    A joint-venture, high-pressure, large-flow-rate facility to test, qualify, and research new natural-gas metering systems has been built by Den Norske Stats Oljeselskap A.S. (Statoil) and Total Marine Norsk A.S. Located near Haugesund in the Stavanger area, the lab, designated the Karsto Metering and Technology Laboratory, or K-Lab, is adjacent to Norway's first natural-gas-processing plant. It receives natural gas from across the Norwegian Trench from the Statfjord complex and after processing it sends it on to Emden, West Germany. The gas, which is produced in the North Sea, is transported to United Kingdom and the European continent through a high-pressure pipelinemore » network. The importance of gas-metering technology has been emphasized by oil and gas companies as well as by national regulatory authorities.« less

  19. The Uses of the National Information Infrastructure in Providing Services to Small Industry, State and Local Governments, and Education in Rural Areas. Hearing before the Subcommittee on Science, Technology, and Space of the Committee on Commerce, Science, and Transportation. United States Senate, One Hundred Fourth Congress, First Session (Billings, Montana).

    ERIC Educational Resources Information Center

    Congress of the U.S., Washington, DC. Senate Committee on Commerce, Science, and Transportation.

    The Senate Subcommittee on Science, Technology, and Space held a hearing in Billings, Montana, on rural America's access to the National Information Infrastructure (NII) and uses of NII in the provision of rural education and services. An Assistant Secretary of Commerce discussed the development of the Internet, problems in rural access to the…

  20. Negative Interpersonal Interactions in Student Training Settings

    ERIC Educational Resources Information Center

    Ferris, Patricia A.; Kline, Theresa J. B.

    2009-01-01

    Studies demonstrate that negative interpersonal interaction(s) (NII) such as bullying are frequent and harmful to individuals in workplace and higher education student settings. Nevertheless, it is unclear whether the degree of perceived severity of NII varies by the status of the actor. The present study explored the moderating effect of actor…

  1. Technical Note: On the possibly missing mechanism of 15 μm emission in the mesosphere-lower thermosphere (MLT)

    NASA Astrophysics Data System (ADS)

    Sharma, R. D.

    2015-02-01

    Accurate knowledge of the rate as well as the mechanism of excitation of the bending mode of CO2 is necessary for reliable modeling of the mesosphere-lower thermosphere (MLT) region of the atmosphere. Assuming the excitation mechanism to be thermal collisions with atomic oxygen, the rate coefficient derived from the observed 15 μm emission by space-based experiments (kATM = 6.0 × 10-12 cm3s-1) differs from the laboratory measurements (kLAB =(1.5-2.5) × 10-12 cm3s-1) by a factor of 2-4. The general circulation models (GCMs) of Earth, Venus, and Mars have chosen to use a median value of kGCM = 3.0 × 10-12 cm3s-1 for this rate coefficient. As a first step to resolve the discrepancies between the three rate coefficients, we attempt to find the source of disagreement between the first two. It is pointed out that a large magnitude of the difference between these two rate coefficients (kx ≡ kATM - kLAB) requires that the unknown mechanism involve one or both major species: N2, O. Because of the rapidly decreasing volume mixing ratio (VMR) of CO2 with altitude, the exciting partner must be long lived and transfer energy efficiently. It is shown that thermal collisions with N2, mediated by a near-resonant rotation-to-vibration (RV) energy transfer process, while giving a reasonable rate coefficient kVR for de-excitation of the bending mode of CO2, lead to vibration-to-translation kVT rate coefficients in the terrestrial atmosphere that are 1-2 orders of magnitude larger than those observed in the laboratory. It is pointed out that the efficient near-resonant rotation-to-vibration (RV) energy transfer process has a chance of being the unknown mechanism if very high rotational levels of N2, produced by the reaction of N and NO and other collisional processes, have a super-thermal population and are long lived. Since atomic oxygen plays a critical role in the mechanisms discussed here, it suggested that its density be determined experimentally by ground- and space

  2. A Novel Multiple-Access Correlation-Delay-Shift-Keying

    NASA Astrophysics Data System (ADS)

    Duan, J. Y.; Jiang, G. P.; Yang, H.

    In Correlation-Delay-Shift-Keying (CDSK), the reference signal and the information-bearing signal are added together during a certain time delay. Because the reference signal is not strictly orthogonal to the information-bearing signal, the cross-correlation between the adjacent chaotic signal (Intra-signal Interference, ISI) will be introduced into the demodulation at the receiver. Therefore, the Bit-Error Ratio (BER) of CDSK is higher than that of Differential-Chaos-Shift-Keying (DCSK). To avoid the ISI component and enhance the BER performance of CDSK in multiuser scenario, Multiple-Access CDSK with No Intra-signal Interference (MA-CDSK-NII) is proposed. By constructing the repeated chaotic generator and applying the Walsh code sequence to modulate the reference signal, in MA-CDSK-NII, the ISI component will be eliminated during the demodulation. Gaussian approximation method is adopted here to obtain the exact performance analysis of MA-CDSK-NII over additive white Gaussian noise (AWGN) channel and Rayleigh multipath fading channels. Results show that, due to no ISI component and lower transmitting power, the BER performance of MA-CDSK-NII can be better than that of multiple-access CDSK and Code-Shifted Differential-Chaos-Shift-Keying (CS-DCSK).

  3. Site preference of alloying elements in DO22-Ni3V phase: Phase-field and first-principles study

    NASA Astrophysics Data System (ADS)

    Zhang, Ding-Ni; Shangguan, Qian-Qian; Liu, Fu; Zhang, Ming-Yi

    2015-07-01

    Site preference of alloying elements in DO22-Ni3V phase was investigated using phase-field and first-principles method. The concentrations of alloying elements on sublattices of DO22-Ni3V phase were quantitatively studied using phase-field model based on microscopic diffusion equations. The phase-field computation results demonstrate that the concentration differences of alloying elements on the NiI and NiII site are attributed to the coordination environment difference. Host atoms Ni and substitutional ternary additions Al prefer to occupy NiI site. Antisite atoms V show site preference on the NiII site. Further reason of site preference of alloying elements on the two different Ni sites were studied using first-principles method to calculate the electronic structure of DO22-Ni3V phase. Calculation of density of states, orbitals population and charge population of the optimized Ni3V structure found that the electronic structures of NiI and NiII sites are different. Electronic structure difference, which is caused by coordination environment difference, is the essential reason for site selectivity behaviors of alloying elements on NiI and NiII sites.

  4. EUV studies of N2 and O2 produced by low energy electron impact

    NASA Technical Reports Server (NTRS)

    Morgan, H. D.; Mentall, J. E.

    1983-01-01

    The emission spectra resulting from electron impact excitation on molecular nitrogen and oxygen in the 500-1200 A spectral region are investigated. Electron energies are from 0 to 300 eV. Numerous bands of N2 are found between 800 and 1000 A. Excitation functions are measured for the NII 916 A, the OI 879 A, and the OII 834 multiplets, and nitrogen band emission. Cross sections were measured at 200 eV for several of the band emissions plus the NI 1135 A, NI 1164 A, NI 1177 A, NII 776 A, NII 1084 A, OI 1152 A, OI 1041 A, OI 999 A, OI 989 A, OI 879 A, OII 834 A, OII 616 A, OII 555 A, OII 539 A, and OII 718 A multiplets.

  5. Local Electric Field Effects on Rhodium-Porphyrin and NHC-Gold Catalysts

    DTIC Science & Technology

    2015-01-05

    AFRL-OSR-VA-TR-2015-0023 (NII) - Local Electric Field Effects on Rhodium -Porphyrin and NHC-Gold Catalysts MATTHEW KANAN LELAND STANFORD JUNIOR UNIV...Effects on Rhodium -Porphyrin and NHC-Gold Catalysts Principal Investigator: Matthew W. Kanan Project Publications: 1. “An Electric Field–Induced Change...Stanford University Grant/Contract Title The full title of the funded effort. (NII)-Local Electric Field Effects on Rhodium -Porphyrin and NHC-Gold

  6. Communications satellites in the national and global health care information infrastructure: their role, impact, and issues

    NASA Technical Reports Server (NTRS)

    Zuzek, J. E.; Bhasin, K. B.

    1996-01-01

    Health care services delivered from a distance, known collectively as telemedicine, are being increasingly demonstrated on various transmission media. Telemedicine activities have included diagnosis by a doctor at a remote location, emergency and disaster medical assistance, medical education, and medical informatics. The ability of communications satellites to offer communication channels and bandwidth on demand, connectivity to mobile, remote and under served regions, and global access will afford them a critical role for telemedicine applications within the National and Global Information Infrastructure (NII/GII). The importance that communications satellites will have in telemedicine applications within the NII/GII the differences in requirements for NII vs. GII, the major issues such as interoperability, confidentiality, quality, availability, and costs, and preliminary conclusions for future usability based on the review of several recent trails at national and global levels are presented.

  7. Radiation dose equivalent to stowaways in vehicles.

    PubMed

    Khan, Siraj M; Nicholas, Paul E; Terpilak, Michael S

    2004-05-01

    The U.S. Bureau of Customs and Border Protection has deployed a large number of non-intrusive inspection (NII) systems at land border crossings and seaports throughout the United States to inspect cars, trucks, and sea containers. These NII systems use x rays and gamma rays for the detection of contraband. Unfortunately, undocumented aliens infrequently stow away in these same conveyances to illegally enter the United States. It is extremely important that the radiation dose equivalent imparted to these stowaways be within acceptable limits. This paper discusses the issues involved and describes a protocol the U.S. Bureau of Customs and Border Protection has used in a study to measure and document these levels. The results of this study show that the radiation dose equivalent to the stowaways from the deployed NII systems is negligibly small and does not pose a health hazard.

  8. [Ni(cod) 2][Al(OR F) 4], a Source for Naked Nickel(I) Chemistry

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Schwab, Miriam M.; Himmel, Daniel; Kacprzak, Sylwia

    The straightforward synthesis of the cationic, purely organometallic Ni I salt [Ni(cod) 2] +[Al(OR F) 4] - was realized through a reaction between [Ni(cod) 2] and Ag[Al(OR F) 4] (cod=1,5-cyclooctadiene). Crystal-structure analysis and EPR, XANES, and cyclic voltammetry studies confirmed the presence of a homoleptic NiI olefin complex. Weak interactions between the metal center, the ligands, and the anion provide a good starting material for further cationic NiI complexes.

  9. Applications drivers for data parking on the Information Superhighway

    NASA Technical Reports Server (NTRS)

    Johnson, Clark E., Jr.; Foeller, Thomas

    1994-01-01

    As the cost of data storage continues to decline (currently about one-millionth of its cost four decades ago) entirely new applications areas become economically feasible. Many of these new areas involved the extraordinarily high data rates and universal connectivity soon to be provided by the National Information Infrastructure (NII). The commonly held belief is that the main driver for the NII will be entertainment applications. We believe that entertainment applications as currently touted (multi-media, 500 video channels, video-on-demand, etc.) will play an important but far from dominant role in the development of the NII and its data storage components. The most pervasively effective drivers will be medical applications such as telemedicine and remote diagnosis, education and environmental monitoring. These applications have a significant funding base and offer a clearly perceived opportunity to improve the nation's standard of living. The NII's wideband connectivity both nationwide and worldwide requires a broad spectrum of data storage devices with a wide-range of performance capabilities. These storage centers will be dispersed throughout the system. Magnetic recording devices will fill the majority of these new data storage requirements for at least the rest of this century. The storage needs of various application areas and their respective market sizes will be explored. The comparative performance of various magnetic technologies and competitive alternative storage systems will be discussed.

  10. VizieR Online Data Catalog: CCD Hα and R photometry of 334 galaxies (James+, 2004)

    NASA Astrophysics Data System (ADS)

    James, P. A.; Shane, N. S.; Beckman, J. E.; Cardwell, A.; Collins, C. A.; Etherton, J.; de Jong, R. S.; Fathi, K.; Knapen, J. H.; Peletier, R. F.; Percival, S. M.; Pollacco, D. L.; Seigar, M. S.; Stedman, S.; Steele, I. A.

    2004-01-01

    Hα plus [NII] and R-band CCD photometry and derived parameters are presented for the full sample of 334 spiral and irregular galaxies. Galaxy distances are derived using a Virgo-infall corrected model which is described in the paper, and star formation rates are derived from Hα plus [NII] fluxes using the conversion defined by Kennicutt et al. (1994ApJ...435...22K). The entries are arranged within five bins in recession velocity, and in order of increasing Right Ascension within these bins. (1 data file).

  11. Combined Spectroscopic and Electrochemical Detection of a NiI•••H–N Bonding Interaction with Relevance to Electrocatalytic H2 Production

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kochem, Amelie; O'Hagan, Molly J.; Wiedner, Eric S.

    2015-07-13

    The [Ni(PR2NR’2)2]2+ family of complexes are exceptionally active catalysts for proton reduction to H2. In this manuscript, we explore the first protonation step of the proposed catalytic cycle by using a catalytically inactive NiI complex possessing a sterically demanding variation of the ligand. Due to the paramagnetic nature of the NiI oxidation state, the protonated NiI intermediate has been characterized through a combination of cyclic voltammetry, ENDOR, and HYSCORE spectroscopy. Both the electrochemical and spectroscopic studies indicate that the NiI complex is protonated at a pendant amine that is endo to Ni, which suggests the presence of an intramolecular NiI•••HNmore » bonding interaction. Using density functional theory, the proton was found to hydrogen bond to three doubly-occupied, localized molecular orbitals: the 3dxz, 3dz2, and 3dyz orbitals of nickel. These studies provide the first direct experimental evidence for this critical catalytic intermediate, and implications for catalytic H2 production are discussed. Research was supported by the Max Planck Society (EPR, ENDOR, and HYSCORE spectroscopy, computational studies), and as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences (electrochemistry, NMR spectroscopy). Pacific Northwest National Laboratory is operated by Battelle for DOE.« less

  12. The development of regulatory expectations for computer-based safety systems for the UK nuclear programme

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hughes, P. J.; Westwood, R.N; Mark, R. T.

    2006-07-01

    The Nuclear Installations Inspectorate (NII) of the UK's Health and Safety Executive (HSE) has completed a review of their Safety Assessment Principles (SAPs) for Nuclear Installations recently. During the period of the SAPs review in 2004-2005 the designers of future UK naval reactor plant were optioneering the control and protection systems that might be implemented. Because there was insufficient regulatory guidance available in the naval sector to support this activity the Defence Nuclear Safety Regulator (DNSR) invited the NII to collaborate with the production of a guidance document that provides clarity of regulatory expectations for the production of safety casesmore » for computer based safety systems. A key part of producing regulatory expectations was identifying the relevant extant standards and sector guidance that reflect good practice. The three principal sources of such good practice were: IAEA Safety Guide NS-G-1.1 (Software for Computer Based Systems Important to Safety in Nuclear Power Plants), European Commission consensus document (Common Position of European Nuclear Regulators for the Licensing of Safety Critical Software for Nuclear Reactors) and IEC nuclear sector standards such as IEC60880. A common understanding has been achieved between the NII and DNSR and regulatory guidance developed which will be used by both NII and DNSR in the assessment of computer-based safety systems and in the further development of more detailed joint technical assessment guidance for both regulatory organisations. (authors)« less

  13. HPCC and the National Information Infrastructure: an overview.

    PubMed Central

    Lindberg, D A

    1995-01-01

    The National Information Infrastructure (NII) or "information superhighway" is a high-priority federal initiative to combine communications networks, computers, databases, and consumer electronics to deliver information services to all U.S. citizens. The NII will be used to improve government and social services while cutting administrative costs. Operated by the private sector, the NII will rely on advanced technologies developed under the direction of the federal High Performance Computing and Communications (HPCC) Program. These include computing systems capable of performing trillions of operations (teraops) per second and networks capable of transmitting billions of bits (gigabits) per second. Among other activities, the HPCC Program supports the national supercomputer research centers, the federal portion of the Internet, and the development of interface software, such as Mosaic, that facilitates access to network information services. Health care has been identified as a critical demonstration area for HPCC technology and an important application area for the NII. As an HPCC participant, the National Library of Medicine (NLM) assists hospitals and medical centers to connect to the Internet through projects directed by the Regional Medical Libraries and through an Internet Connections Program cosponsored by the National Science Foundation. In addition to using the Internet to provide enhanced access to its own information services, NLM sponsors health-related applications of HPCC technology. Examples include the "Visible Human" project and recently awarded contracts for test-bed networks to share patient data and medical images, telemedicine projects to provide consultation and medical care to patients in rural areas, and advanced computer simulations of human anatomy for training in "virtual surgery." PMID:7703935

  14. Novel method for quantitative ANA measurement using near-infrared imaging.

    PubMed

    Peterson, Lisa K; Wells, Daniel; Shaw, Laura; Velez, Maria-Gabriela; Harbeck, Ronald; Dragone, Leonard L

    2009-09-30

    Antinuclear antibodies (ANA) have been detected in patients with systemic rheumatic diseases and are used in the screening and/or diagnosis of autoimmunity in patients as well as mouse models of systemic autoimmunity. Indirect immunofluorescence (IIF) on HEp-2 cells is the gold standard for ANA screening. However, its usefulness is limited in diagnosis, prognosis and monitoring of disease activity due to the lack of standardization in performing the technique, subjectivity in interpreting the results and the fact that it is only semi-quantitative. Various immunological techniques have been developed in an attempt to improve upon the method to quantify ANA, including enzyme-linked immunosorbent assays (ELISAs), line immunoassays (LIAs), multiplexed bead immunoassays and IIF on substrates other than HEp-2 cells. Yet IIF on HEp-2 cells remains the most common screening method for ANA. In this study, we describe a simple quantitative method to detect ANA which combines IIF on HEp-2 coated slides with analysis using a near-infrared imaging (NII) system. Using NII to determine ANA titer, 86.5% (32 of 37) of the titers for human patient samples were within 2 dilutions of those determined by IIF, which is the acceptable range for proficiency testing. Combining an initial screening for nuclear staining using microscopy with titration by NII resulted in 97.3% (36 of 37) of the titers detected to be within two dilutions of those determined by IIF. The NII method for quantitative ANA measurements using serum from both patients and mice with autoimmunity provides a fast, relatively simple, objective, sensitive and reproducible assay, which could easily be standardized for comparison between laboratories.

  15. Synthesis and characterization of novel ion-imprinted guanyl-modified cellulose for selective extraction of copper ions from geological and municipality sample.

    PubMed

    Kenawy, I M; Ismail, M A; Hafez, M A H; Hashem, M A

    2018-04-21

    The new ion-imprinted guanyl-modified cellulose (II.Gu-MC) was prepared for the separation and determination of Cu (II) ions in different real samples. Several techniques such as Fourier Transform Infrared (FT-IR), scanning electron microscope (SEM), thermal analysis, potentiograph and elemental analysis have been utilized for the characterization of II.Gu-MC. The adsorption behavior of the ion imprinted polymer (II.Gu-MC) was evaluated and compared to the non ion-imprinted polymer (NII.Gu-MC) at the optimum conditions. The selectivity and the adsorption capacity were greatly enhanced by using the ion-imprinted polymer, indicating its validation for the separation and determination of Cu 2+ ions in different matrices. The adsorption capacity by chelating fibers II.Gu-MC & NII.Gu-MC agreed with the second-order model, and the sorption-isotherm experiments revealed best agreement with Langmuir model. The adsorption capacity of II.Gu-MC and NII.Gu-MC were 115 and 55 mg·g -1 , respectively. The II.Gu-MC was successfully employed for the selective separation and determination of Cu(II) ions with high accuracy. Copyright © 2018 Elsevier B.V. All rights reserved.

  16. Kinematics of the symbiotic system R Aqr

    NASA Astrophysics Data System (ADS)

    Navarro, S.; Corral, L. J.; Steffen, W.

    2014-04-01

    We present the results of the kinematical analysis of the symbiotic system R Aqr. We obtained high dispersion spectra with the MES spectrograph at the 2.1 m telescope of San Pedro Mártir (MEZCAL). The used filter were Ha + [NII], (λc = 6575Å, Δλ = 90Å). We analyse the [NII] λλ6583 line. When the observations are compared with previous ones by Solf (1992) we detected an important change in the projected velocities of the observed knots, supporting the idea of a precessing jet. We are working also in a 3-D kinematic model for the object using the measured velocities and the state of the model is presented.

  17. Polarity-defective mutants of Aspergillus nidulans.

    PubMed

    Osherov, N; Mathew, J; May, G S

    2000-12-01

    We have identified two polarity-defective (pod) mutants in Aspergillus nidulans from a collection of heat-sensitive lethal mutants. At restrictive temperature, these mutants are capable of nuclear division but are unable to establish polar hyphal growth. We cloned the two pod genes by complementation of their heat-sensitive lethal phenotypes. The libraries used to clone the pod genes are under the control of the bidirectional niaD and niiA promoters. Complementation of the pod mutants is dependent on growth on inducing medium. We show that rescue of the heat-sensitive phenotype on inducing media is independent of the orientation of the gene relative to the niaD or niiA promoters, demonstrating that the intergenic region between the niaD and the niiA genes functions as an orientation-independent enhancer and repressor that is capable of functioning over long distances. The products of the podG and the podH genes were identified as homologues of the alpha subunit of yeast mitochondrial phenylalanyl--tRNA synthetase and transcription factor IIF interacting component of the CTD phosphatase. Neither of these gene products would have been predicted to produce a pod mutant phenotype based on studies of cellular polarity mutants in other organisms. The implications of these results are discussed. Copyright 2000 Academic Press.

  18. Poly- Versus Mono-Energetic Dual-Spectrum Non-Intrusive Inspection of Cargo Containers

    NASA Astrophysics Data System (ADS)

    Martz, Harry E.; Glenn, Steven M.; Smith, Jerel A.; Divin, Charles J.; Azevedo, Stephen G.

    2017-07-01

    In this paper, based on an invited talk at SORMA (May 2016), we present an overview of x-ray sources, detectors and system configurations for non-intrusive inspection (NII) of cargo containers. Our emphasis is on dual-energy x-ray NII for detecting high-atomic-number (Z ≥ 72) materials such as tungsten shielding and special nuclear materials (SNM). Standard single-energy (MeV and above) x-rays needed to penetrate and image cargo provide little SNM contrast, whereas dual-energy x-ray NII is demonstrated as a way to improve the selectivity of materials with Z<;72 vs. those with Z ≥ 72. For two possible dual-energy x-ray source technologies - polyenergetic dual-energy (PDE) and quasi-monoenergetic x-ray sources (QMXS) - we investigate their trade-offs and future prospects using experimental and simulated results. The reduced scatter and larger separation of low- and high-energy photons provided by QMXS offers improved high-Z material contrast, but practical considerations such as flux and pulse rate need to be solved before making a deployable system. Straight-ray simulations show factor of four increases in contrast for QMXS over PDE scans of tin (Z=50) and iron (Z=26) relative to a uranium plate (Z=92) behind 20 cm of iron simulated cargo.

  19. Radiation Detection and Dual-Energy X-Ray Imaging for Port Security

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Pashby, J.; Glenn, S.; Divin, C.

    Millions of cargo containers are transported across the United States border annually and are inspected for illicit radioactive material and contraband using a combination of passive radiation portal monitors (RPM) and high energy X-ray non-intrusive inspection (NII) systems. As detection performance is expected to vary with the material composition of cargo, characterizing the types of material present in cargo is important to national security. This work analyzes the passive radiation and dual energy radiography signatures from on RPM and two NII system, respectively. First, the cargos were analyzed to determine their ability to attenuate emissions from an embedded radioactive source.more » Secondly, dual-energy X-ray discrimination was used to determine the material composition and density of the cargos.« less

  20. Impact of Incremental Perfusion Loss on Oxygen Transport in a Capillary Network Mathematical Model.

    PubMed

    Fraser, Graham M; Sharpe, Michael D; Goldman, Daniel; Ellis, Christopher G

    2015-07-01

    To quantify how incremental capillary PL, such as that seen in experimental models of sepsis, affects tissue oxygenation using a computation model of oxygen transport. A computational model was applied to capillary networks with dimensions 84 × 168 × 342 (NI) and 70 × 157 × 268 (NII) μm, reconstructed in vivo from rat skeletal muscle. FCD loss was applied incrementally up to ~40% and combined with high tissue oxygen consumption to simulate severe sepsis. A loss of ~40% FCD loss decreased median tissue PO2 to 22.9 and 20.1 mmHg in NI and NII compared to 28.1 and 27.5 mmHg under resting conditions. Increasing RBC SR to baseline levels returned tissue PO2 to within 5% of baseline. HC combined with a 40% FCD loss, resulted in tissue anoxia in both network volumes and median tissue PO2 of 11.5 and 8.9 mmHg in NI and NII respectively; median tissue PO2 was recovered to baseline levels by increasing total SR 3-4 fold. These results suggest a substantial increase in total SR is required in order to compensate for impaired oxygen delivery as a result of loss of capillary perfusion and increased oxygen consumption during sepsis. © 2015 John Wiley & Sons Ltd.

  1. Mutant Huntingtin Gene-Dose Impacts on Aggregate Deposition, DARPP32 Expression and Neuroinflammation in HdhQ150 Mice

    PubMed Central

    Young, Douglas; Mayer, Franziska; Vidotto, Nella; Schweizer, Tatjana; Berth, Ramon; Abramowski, Dorothee; Shimshek, Derya R.; van der Putten, P. Herman; Schmid, Peter

    2013-01-01

    Huntington's disease (HD) is an autosomal dominant, progressive and fatal neurological disorder caused by an expansion of CAG repeats in exon-1 of the huntingtin gene. The encoded poly-glutamine stretch renders mutant huntingtin prone to aggregation. HdhQ150 mice genocopy a pathogenic repeat (∼150 CAGs) in the endogenous mouse huntingtin gene and model predominantly pre-manifest HD. Treating early is likely important to prevent or delay HD, and HdhQ150 mice may be useful to assess therapeutic strategies targeting pre-manifest HD. This requires appropriate markers and here we demonstrate, that pre-symptomatic HdhQ150 mice show several dramatic mutant huntingtin gene-dose dependent pathological changes including: (i) an increase of neuronal intra-nuclear inclusions (NIIs) in brain, (ii) an increase of extra-nuclear aggregates in dentate gyrus, (iii) a decrease of DARPP32 protein and (iv) an increase in glial markers of neuroinflammation, which curiously did not correlate with local neuronal mutant huntingtin inclusion-burden. HdhQ150 mice developed NIIs also in all retinal neuron cell-types, demonstrating that retinal NIIs are not specific to human exon-1 R6 HD mouse models. Taken together, the striking and robust mutant huntingtin gene-dose related changes in aggregate-load, DARPP32 levels and glial activation markers should greatly facilitate future testing of therapeutic strategies in the HdhQ150 HD mouse model. PMID:24086450

  2. An Examination of Strong-line Metallicity Diagnostics with Direct Gas-Phase Metallicities at Higher Redshifts

    NASA Astrophysics Data System (ADS)

    Ly, Chun; Rigby, Jane R.; Malkan, Matthew Arnold; Malhotra, Sangeeta

    2016-01-01

    The [OIII]λ4363 nebular emission line, which provides the most reliable determination of the gas metallicity by measuring the electron temperature of the gas, is intrinsically weak. As such, most metallicity studies at both low and high redshifts have utilized "strong-line" metallicity calibrations, such as [NII]λ6583/Hα or R23 = ([OII]+[OIII])/Hβ. However, there are growing concerns that these diagnostics may not be used for evolutionary studies due to differences in the physical conditions (e.g., density, ionization, abundance ratios) of the interstellar gas in galaxies. A clear demonstration for this concern is the offset on the Baldwin-Phillips-Terlevich diagnostic diagram ([OIII]λ5007/Hβ vs. [NII]λ6583/Hα) for high-z star-forming galaxies from local star-forming galaxies.To examine this issue, we investigate the accuracy that commonly-used strong-line diagnostics can explain the direct oxygen abundances. Here, we use a sample of ~100 low-mass galaxies at z=0.07 to 1.0 with detections of the [OIII]λ4363 emission line from Keck and MMT optical spectroscopy. These galaxies are pre-selected for their strong nebular emission lines from the Subaru Deep Field and the DEEP2 Survey. Utilizing the optical emission lines, we argue that "R23" is not a reliable diagnostic and that discrepancies from [OIII]λ4363-based metallicity cannot be explained simply by higher gas densities or higher ionization parameter. We do find that the [NII]-based metallicity diagnostics of Pettini & Pagel (2004) are in agreement with [OIII]λ4363-based metallicity at z~0.5. There is, however, a sub-population (25%) where [NII]-based estimates are overestimating the oxygen metallicities. We argue that enhanced nitrogen abundances, relative to oxygen, is responsible for this significant (~0.5 dex) offset in metallicity. We present preliminary results for a revised metallicity calibration that considers the N/O abundance ratio.

  3. Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex

    PubMed Central

    2015-01-01

    First-row metal complexes often undergo undesirable one-electron redox processes during two-electron steps of catalytic cycles. We report the amination of aryl chlorides and bromides with primary aliphatic amines catalyzed by a well-defined, single-component nickel precursor (BINAP)Ni(η2-NC-Ph) (BINAP = 2,2′-bis(biphenylphosphino)-1,1′-binaphthalene) that minimizes the formation of Ni(I) species and (BINAP)2Ni. The scope of the reaction encompasses electronically varied aryl chlorides and nitrogen-containing heteroaryl chlorides, including pyridine, quinoline, and isoquinoline derivatives. Mechanistic studies support the catalytic cycle involving a Ni(0)/Ni(II) couple for this nickel-catalyzed amination and are inconsistent with a Ni(I) halide intermediate. Monitoring the reaction mixture by 31P NMR spectroscopy identified (BINAP)Ni(η2-NC-Ph) as the resting state of the catalyst in the amination of both aryl chlorides and bromides. Kinetic studies showed that the amination of aryl chlorides and bromides is first order in both catalyst and aryl halide and zero order in base and amine. The reaction of a representative aryl chloride is inverse first order in PhCN, but the reaction of a representative aryl bromide is zero order in PhCN. This difference in the order of the reaction in PhCN indicates that the aryl chloride reacts with (BINAP)Ni(0), formed by dissociation PhCN from (BINAP)Ni(η2-NC-Ph), but the aryl bromide directly reacts with (BINAP)Ni(η2-NC-Ph). The overall kinetic behavior is consistent with turnover-limiting oxidative addition of the aryl halide to Ni(0). Several pathways for catalyst decomposition were identified, such as the formation of the catalytically inactive bis(amine)-ligated arylnickel(II) chloride, (BINAP)2Ni(0), and the Ni(I) species [(BINAP)Ni(μ-Cl)]2. By using a well-defined nickel complex as catalyst, the formation of (BINAP)2Ni(0) is avoided and the formation of the Ni(I) species [(BINAP)Ni(μ-Cl)]2 is minimized. PMID:24397570

  4. Differences in Autism Spectrum Disorders Incidence by Sub-Populations in Israel 1992-2009: A Total Population Study

    PubMed Central

    Raz, Raanan; Weisskopf, Marc G; Davidovitch, Michael; Pinto, Ofir; Levine, Hagai

    2014-01-01

    We analyzed data from the Israeli National Insurance Institute (NII). Autism Spectrum Disorder (ASD) incidence was calculated for all children born in Israel 1992-2009, and by population groups. Overall, 9,109 ASD cases among 2,431,649 children were identified. ASD cumulative incidence by age 8 years increased 10-fold during 2000-2011, from 0.049% to 0.49%, while other child disabilities in NII increased only 1.65-fold. There was a consistent increase in ASD incidence with advancing birth cohorts born 1992-2004, stabilizing among those born 2005-2009. ASD rates among Israeli Arabs were substantially lower, and increased about 10 years later than the general population. The findings suggest a role for ASD awareness, accessing of the government benefit, or the way the concept of ASD is perceived. PMID:25287899

  5. National positioning, navigation, and timing architecture : implementation plan.

    DOT National Transportation Integrated Search

    2010-04-01

    The Assistant Secretary of Defense for Networks and Information Integration (ASD/NII) and the : Under Secretary of Transportation for Policy (UST/P) sponsored a National Positioning, : Navigation, and Timing (PNT) Architecture Study to provide mor...

  6. (NII) Novel Catalytic, Synthesis Methods for Main Group

    DTIC Science & Technology

    2014-12-23

    Hydride Complex.” Dalt. Trans. 2014, 43, 10046–10056. 7. Johnson, M. W.; Bagley , S . W.; Mankad, N. P.; Bergman, R. G.; Mascitti, V.; Toste, F. D...6. AUTHOR( S ) Bergman, Robert G. Arnold, John Toste, F. Dean 5d. PROJECT NUMBER 5e. TASK NUMBER 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION...NAME( S ) AND ADDRESS(ES) Regents of the University of California, Berkeley 2220 Piedmont Ave, Berkeley, CA 94720 8. PERFORMING ORGANIZATION REPORT

  7. National Positioning, Navigation, and Timing Architecture Study Final Report

    DOT National Transportation Integrated Search

    2008-09-01

    The Assistant Secretary of Defense for Networks and Information Integration (ASD/NII) and the Under Secretary of Transportation for Policy (UST/P) sponsored a National Positioning, Navigation, and Timing (PNT) Architecture Study to "provide more effe...

  8. Capstone Report - The Technology Readiness of Alternative Fuels : Alternative Fuels & Life-Cycle Engineering Program : November 29, 2006 to November 28, 2011

    DOT National Transportation Integrated Search

    2011-12-20

    The Assistant Secretary of Defense for Networks and Information Integration (ASD/NII) and the Under Secretary of Transportation for Policy (UST/P) sponsored a National Positioning, Navigation, and Timing (PNT) Architecture Study to "provide more effe...

  9. Trypanosoma cruzi -infected Triatoma gerstaeckeri (Hemiptera: Reduviidae) from Nuevo León, México, and pathogenicity of the regional strain.

    PubMed

    Molina-Garza, Zinnia J; Mercado-Hernández, Roberto; Molina-Garza, Daniel P; Galaviz-Silva, Lucio

    2015-01-01

    Four species of triatomines have been reported in Nuevo León, northeast (NE) México, but Triatoma gerstaeckeri has only been recorded from a peridomestic dwelling. To assess the natural infection index (NII) of Trypanosoma cruzi in triatomines and the infestation index (II) of T. gerstaeckeri collected in a suburban locality, and to collect histopathological data to understand tissue tropism of the regional T. cruzi strain (strain NE) obtained from the vectors collected after an experimental inoculation in Mus musculus . Triatomines were collected from 85 houses and peridomiciles in Allende, Nuevo León. Stool samples were obtained to determine the T. cruzi NII and were used in an experimental mice infection. A total of 118 T . gerstaeckeri were captured, and 46 (adults and nymphs) were collected inside the same house (II=1.17%). Thirty-seven reduvids were infected with T. cruzi (NII=31.3%). Tissue tropism of the T. cruzi NE strain was progressive in skeletal muscle, myocardial, and adipose tissues and was characterized by the presence of intracellular amastigotes and destruction of cardiac myocells. The presence of naturally infected domiciliary vectors is an important risk factor for public health in the region considering that these vectors are the principal transmission mechanism of the parasite. The T. cruzi NE strain has similar virulence to that of other Mexican and Texan strains and caused chagasic infections in 11 of 12 mice.

  10. Space-based communications infrastructure for developing countries

    NASA Astrophysics Data System (ADS)

    Barker, Keith; Barnes, Carl; Price, K. M.

    1995-08-01

    This study examines the potential use of satellites to augment the telecommunications infrastructure of developing countries with advanced satellites. The study investigated the potential market for using satellites in developing countries, the role of satellites in national information infrastructures (NII), the technical feasibility of augmenting NIIs with satellites, and a nation's financial conditions necessary for procuring satellite systems. In addition, the study examined several technical areas including onboard processing, intersatellite links, frequency of operation, multibeam and active antennas, and advanced satellite technologies. The marketing portion of this study focused on three case studies: China, Brazil, and Mexico. These cases represent countries in various stages of telecommunication infrastructure development. The study concludes by defining the needs of developing countries for satellites, and recommends steps that both industry and NASA can take to improve the competitiveness of U.S. satellite manufacturing.

  11. Space-based Communications Infrastructure for Developing Countries

    NASA Technical Reports Server (NTRS)

    Barker, Keith; Barnes, Carl; Price, K. M.

    1995-01-01

    This study examines the potential use of satellites to augment the telecommunications infrastructure of developing countries with advanced satellites. The study investigated the potential market for using satellites in developing countries, the role of satellites in national information infractructures (NII), the technical feasibility of augmenting NIIs with satellites, and a nation's financial conditions necessary for procuring satellite systems. In addition, the study examined several technical areas including onboard processing, intersatellite links, frequency of operation, multibeam and active antennas, and advanced satellite technologies. The marketing portion of this study focused on three case studies: China, Brazil, and Mexico. These cases represent countries in various stages of telecommunication infrastructure development. The study concludes by defining the needs of developing countries for satellites, and recommends steps that both industry and NASA can take to improve the competitiveness of U.S. satellite manufacturing.

  12. Near infrared and optical spectroscopy of FSC10214+4724

    NASA Technical Reports Server (NTRS)

    Soifer, B. T.; Cohen, J. G.; Armus, L.; Matthews, K.; Neugebauer, G.; Oke, J. B.

    1995-01-01

    New infrared and optical spectroscopic observations, obtained with the W.M. Keck Telescope, are reported for the highly luminous infrared source FSC10214+4724. The rest frame optical spectrum shows new emission lines of (NeIII, (NeV), (OI), (OII), (SII), and He(+) while the rest frame ultraviolet spectrum shows new lines of OIV+SiIV, NII, NIV, SiII, NeIV and possibly NII and (NeIII), as well as clearly showing the L alpha is self-absorbed. The emission line spectrum is most characteristic of a Seyfert 2 nucleus. The preponderance of spectroscopic evidence strengthens the case of a dust enshrouded AGN powering much or most of the observed luminosity. The various spectral lines lead to a wide range in the inferred reddening and ionization parameter for this system, suggesting that we are viewing several environments through differing extinctions.

  13. EFFECT OF ORGANOPHOSPHORUS FLAME RETARDANTS ON NEURONAL DEVELOPMENT IN VITRO

    EPA Science Inventory

    The increased use of organophosphorus compounds as alternatives to brominated flame retardants (BFRs) has led to widespread human exposure, There is, however, limited information on their potential health effects. This study compared the effects of nii ne organophosphorus flame...

  14. Ternary semiconductors NiZrSn and CoZrBi with half-Heusler structure: A first-principles study

    NASA Astrophysics Data System (ADS)

    Fiedler, Gregor; Kratzer, Peter

    2016-08-01

    The ternary semiconductors NiZrSn and CoZrBi with C 1b crystal structure are introduced by calculating their basic structural, electronic, and phononic properties using density functional theory. Both the gradient-corrected PBE functional and the hybrid functional HSE06 are employed. While NiZrSn is found to be a small-band-gap semiconductor (Eg=0.46 eV in PBE and 0.60 eV in HSE06), CoZrBi has a band gap of 1.01 eV in PBE (1.34 eV in HSE06). Moreover, effective masses and deformation potentials are reported. In both materials A B C , the intrinsic point defects introduced by species A (Ni or Co) are calculated. The Co-induced defects in CoZrBi are found to have a higher formation energy compared to Ni-induced defects in NiZrSn. The interstitial Ni atom (Nii) as well as the VNiNii complex introduce defect states in the band gap, whereas the Ni vacancy (VNi) only reduces the size of the band gap. While Nii is electrically active and may act as a donor, the other two types of defects may compensate extrinsic doping. In CoZrBi, only the VCoCoi complex introduces a defect state in the band gap. Motivated by the reported use of NiZrSn for thermoelectric applications, the Seebeck coefficient of both materials, both in the p -type and the n -type regimes, is calculated. We find that CoZrBi displays a rather large thermopower of up to 500 μ V /K when p doped, whereas NiZrSn possesses its maximum thermopower in the n -type regime. The reported difficulties in achieving p -type doping in NiZrSn could be rationalized by the unintended formation of Nii2 + in conjunction with extrinsic acceptors, resulting in their compensation. Moreover, it is found that all types of defects considered, when present in concentrations as large as 3%, tend to reduce the thermopower compared to ideal bulk crystals at T =600 K. For NiZrSn, the calculated thermodynamic data suggest that additional Ni impurities could be removed by annealing, leading to precipitation of a metallic Ni2ZrSn phase.

  15. Information Technology Standards: A Component of Federal Information Policy.

    ERIC Educational Resources Information Center

    Moen, William E.

    1994-01-01

    Discusses the need for proposing and implementing an information technology standards policy for the federal government. Topics addressed include the National Information Infrastructure (NII); voluntary standards among federal agencies; private sector organizations; coordinating the use of standards; enforcing compliance; policy goals; a framework…

  16. VizieR Online Data Catalog: [CII] emission in the ISM of 20 nearby galaxies (Croxall+, 2017)

    NASA Astrophysics Data System (ADS)

    Croxall, K. V.; Smith, J. D.; Pellegrini, E.; Groves, B.; Bolatto, A.; Herrera-Camus, R.; Sandstrom, K. M.; Draine, B.; Wolfire, M. G.; Armus, L.; Boquien, M.; Brandl, B.; Dale, D.; Galametz, M.; Hunt, L.; Kennicutt, R.; Kreckel, K.; Rigopoulou, D.; van der Werf, P.; Wilson, C.

    2018-04-01

    Our observations include photometric and spectral-line observations from both the PACS and SPIRE instruments onboard Herschel, obtained as part of the large KINGFISH (Key Insights on Nearby Galaxies: a Far- Infrared Survey with Herschel, Kennicutt+ 2011PASP..123.1347K) and BtP (Beyond the Peak; OT1_jsmith1; P.I. J.D. Smith) projects. [NII]205um BtP observations were performed with SPIRE-FTS intermediate mapping, which is a 4-point dither. E. Pellegrini et al. (2017, in preparation) will contain a full description of the observations and reductions. [CII]158um and [NII]122um emission lines, and 70 and 160um continuum maps have been observed as part the Herschel Open Time Key Program KINGFISH. The data and the associated reduction are described in Kennicutt+ (2011PASP..123.1347K) and Croxall+ (2013ApJ...777...96C). (2 data files).

  17. An ALMA view of the interstellar medium of the z = 4.77 lensed starburst SPT-S J213242-5802.9

    NASA Astrophysics Data System (ADS)

    Béthermin, M.; De Breuck, C.; Gullberg, B.; Aravena, M.; Bothwell, M. S.; Chapman, S. C.; Gonzalez, A. H.; Greve, T. R.; Litke, K.; Ma, J.; Malkan, M.; Marrone, D. P.; Murphy, E. J.; Spilker, J. S.; Stark, A. A.; Strandet, M.; Vieira, J. D.; Weiß, A.; Welikala, N.

    2016-02-01

    We present ALMA detections of the [NII] 205 μm and CO(12-11) emission lines, and the tentative detection of [CI] - for the strongly lensed (μ = 5.7 ± 0.5) dusty, star-forming galaxy SPT-S J213242-5802.9 (hereafter SPT2132-58) at z = 4.77. The [NII] and CO(12-11) lines are detected at 11.5 and 8.5σ levels, respectively, by our band 6 observations. The [CI] line is detected at 3.2σ after a reanalysis of existing band 3 data. The [CI] luminosity implies a gas mass of (3.8 ± 1.2) × 1010M⊙, and, consequently, a very short depletion timescale of 34 ± 13 Myr and a CO luminosity to gas mass conversion factor αCO of 1.0 ± 0.3 M⊙ (K km s-1 pc2)-1. SPT2132-58 is an extreme starburst with an intrinsic star formation rate of 1100 ± 200 M⊙/yr. We find a [CII]/[NII] ratio of 26 ± 6, which is the highest ratio reported at z > 4. This suggests that SPT2132-58 hosts an evolved interstellar medium (0.5 Z⊙< Z < 1.5 Z⊙), which may be dominated by photodissociation regions. The CO(2-1) and CO(5-4) transitions have lower CO to far-infrared ratios than local and high-redshift samples, while CO(12-11) is similar to these samples, suggesting the presence of an additional very excited component or an active galactic nucleus.

  18. The Impact of Diffuse Ionized Gas on Emission-line Ratios and Gas Metallicity Measurements

    NASA Astrophysics Data System (ADS)

    Zhang, Kai; Yan, Renbin; MaNGA Team

    2016-01-01

    Diffuse Ionized Gas (DIG) is prevalent in star-forming galaxies. Using a sample of galaxies observed by MaNGA, we demonstrate how DIG in star-forming galaxies impact the measurements of emission line ratios, hence the gas-phase metallicity measurements and the interpretation of diagnostic diagrams. We demonstrate that emission line surface brightness (SB) is a reasonably good proxy to separate HII regions from regions dominated by diffuse ionized gas. For spatially-adjacent regions or regions at the same radius, many line ratios change systematically with emission line surface brightness, reflecting a gradual increase of dominance by DIG towards low SB. DIG could significantly bias the measurement of gas metallicity and metallicity gradient. Because DIG tend to have a higher temperature than HII regions, at fixed metallicity DIG displays lower [NII]/[OII] ratios. DIG also show lower [OIII]/[OII] ratios than HII regions, due to extended partially-ionized regions that enhance all low-ionization lines ([NII], [SII], [OII], [OI]). The contamination by DIG is responsible for a substantial portion of the scatter in metallicity measurements. At different surface brightness, line ratios and line ratio gradients can differ systematically. As DIG fraction could change with radius, it can affect the metallicity gradient measurements in systematic ways. The three commonly used strong-line metallicity indicators, R23, [NII]/[OII], O3N2, are all affected in different ways. To make robust metallicity gradient measurements, one has to properly isolate HII regions and correct for DIG contamination. In line ratio diagnostic diagrams, contamination by DIG moves HII regions towards composite or LINER-like regions.

  19. Intellectual Property and the National Information Infrastructure. The Report of the Working Group on Intellectual Property Rights.

    ERIC Educational Resources Information Center

    Lehman, Bruce A.

    In February 1993, the Information Infrastructure Task Force (IITF) was formed to articulate and implement the Clinton Administration's vision for the National Information Infrastructure (NII). The Working Group on Intellectual Property Rights was established within the Information Policy Committee to examine the intellectual property implications…

  20. 78 FR 27416 - Notice of Availability of the Final Record of Decision for the Programmatic Environmental Impact...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-05-10

    ... improved personal radiation detectors (PRD), RIDs, and NII tools, such as high-energy container scanners... DEPARTMENT OF HOMELAND SECURITY U.S. Customs and Border Protection Notice of Availability of the... Border Activities AGENCY: U.S. Customs and Border, Protection, DHS. ACTION: Notice of availability...

  1. The National Information Infrastructure: Requirements for Education and Training: Executive Summary.

    ERIC Educational Resources Information Center

    TechTrends, 1994

    1994-01-01

    Includes 19 requirements prepared by the National Coordinating Committee for Technology in Education (NCC-TET) to ensure that the national information infrastructure (NII) provides expanded opportunities for education and training. The requirements, which cover access, education and training applications, and technical needs, are intended as…

  2. The Federal Government and Information Technology Standards: Building the National Information Infrastructure.

    ERIC Educational Resources Information Center

    Radack, Shirley M.

    1994-01-01

    Examines the role of the National Institute of Standards and Technology (NIST) in the development of the National Information Infrastructure (NII). Highlights include the standards process; voluntary standards; Open Systems Interconnection problems; Internet Protocol Suite; consortia; government's role; and network security. (16 references) (LRW)

  3. 20/20 Vision: The Development of a National Information Infrastructure.

    ERIC Educational Resources Information Center

    National Telecommunications and Information Administration (DOC), Washington, DC.

    After the publication of the Clinton Administration's "The National Information Infrastructure: Agenda for Action," a group of telecommunication specialists were asked to evaluate the proposals in order to broaden the policy discussion concerning the National Information Infrastructure (NII). This collection contains their visions of the…

  4. Herschel Galactic Plane Survey of [NII] Fine Structure Emission

    NASA Astrophysics Data System (ADS)

    Goldsmith, Paul F.; Yıldız, Umut A.; Langer, William D.; Pineda, Jorge L.

    2015-12-01

    We present the first large-scale high angular resolution survey of ionized nitrogen in the Galactic Plane through emission of its two fine structure transitions ([N ii]) at 122 and 205 μm. The observations were largely obtained with the PACS instrument onboard the Herschel Space Observatory. The lines of sight were in the Galactic plane, following those of the Herschel OTKP project GOT C+. Both lines are reliably detected at the 10-8-10-7 Wm-2 sr-1 level over the range -60° ≤ l ≤ 60°. The rms of the intensity among the 25 PACS spaxels of a given pointing is typically less than one third of the mean intensity, showing that the emission is extended. [N ii] is produced in gas in which hydrogen is ionized, and collisional excitation is by electrons. The ratio of the two fine structure transitions provides a direct measurement of the electron density, yielding n(e) largely in the range 10-50 cm-3 with an average value of 29 cm-3 and N+ column densities 1016-1017 cm-2. [N ii] emission is highly correlated with that of [C ii], and we calculate that between 1/3 and 1/2 of the [C ii] emission is associated with the ionized gas. The relatively high electron densities indicate that the source of the [N ii] emission is not the warm ionized medium (WIM), which has electron densities more than 100 times smaller. Possible origins of the observed [N ii] include the ionized surfaces of dense atomic and molecular clouds, the extended low-density envelopes of H ii regions, and low-filling factor high-density fluctuations of the WIM.

  5. Access to the Information Superhighway and Emerging Information Technologies by People with Disabilities.

    ERIC Educational Resources Information Center

    National Council on Disability, Washington, DC.

    This report discusses the growth of the National Information Infrastructure (NII), or the information superhighway, and its implications for people with disabilities. Advantages for people with disabilities include: increasing the ability of individuals with some types of disabilities to access and use information; decreasing personal isolation…

  6. Terrorism reports: The tip of the iceberg.

    PubMed

    Ellenberg, Eytan; Taragin, Mark; Bar-On, Zvia; Cohen, Osnat; Ostfeld, Ishay

    2017-01-01

    Medical impact of terror is a public health issue as the threat is growing all over the world. Our objective was to compare the number of injured and incidents in the three different databases and reports [Global Terrorism Database (GTD), Israeli Security Agency (ISA) and National Insurance Institute (NII)] in Israel. Retrospective study. Analyses of three different databases (GTD, ISA and NII) and basic comparison. The victims reimbursed for medical expenses are the largest population. The number of injured as described by GTD and ISA database are less important. The 2010-2013 years are marked by more incidents recognized in Israel vs GTD assessment (except in 2014). The number of victims being reimbursed for medical and mental health services is radically different from the GTD and the ISA reports. Public Health specialists should be advised of this phenomenon to deliver their right approach (including mental health) to growing threat and develop new definition of victim of terror.

  7. Identifying Distant AGNs

    NASA Astrophysics Data System (ADS)

    Trouille, Laura; Barger, Amy; Tremonti, Christy

    2014-07-01

    The Baldwin, Phillips, and Terlevich emission-line ratio diagnostic ([OIII]/Hβ versus [NII]/Hα, hereafter BPT diagram) efficiently separates galaxies whose signal is dominated by star formation (BPT-SF) from those dominated by AGN activity (BPT-AGN). Yet the BPT diagram is limited to z<0.5, the redshift at which [NII]λ6584 leaves the optical spectral window. Using the Sloan Digital Sky Survey (SDSS), we construct a new diagnostic, or TBT diagram, that is based on rest-frame g-z color, [NeIII]λ3869, and [OII]λλ3726+3729 and can be used for galaxies out to z<1.4. The TBT diagram identifies 98.7% of the SDSS BPT-AGN as TBT-AGN and 97% of the SDSS BPT-SF as TBT-SF. Furthermore, it identifies 97% of the OPTX Chandra X-ray selected AGNs as TBT-AGN. This is in contrast to the BPT diagram, which misidentifies 20% of X-ray selected AGNs as BPT-SF.

  8. Estimation of waste component-specific landfill decay rates using laboratory-scale decomposition data.

    PubMed

    De la Cruz, Florentino B; Barlaz, Morton A

    2010-06-15

    The current methane generation model used by the U.S. EPA (Landfill Gas Emissions Model) treats municipal solid waste (MSW) as a homogeneous waste with one decay rate. However, component-specific decay rates are required to evaluate the effects of changes in waste composition on methane generation. Laboratory-scale rate constants, k(lab), for the major biodegradable MSW components were used to derive field-scale decay rates (k(field)) for each waste component using the assumption that the average of the field-scale decay rates for each waste component, weighted by its composition, is equal to the bulk MSW decay rate. For an assumed bulk MSW decay rate of 0.04 yr(-1), k(field) was estimated to be 0.298, 0.171, 0.015, 0.144, 0.033, 0.02, 0.122, and 0.029 yr(-1), for grass, leaves, branches, food waste, newsprint, corrugated containers, coated paper, and office paper, respectively. The effect of landfill waste diversion programs on methane production was explored to illustrate the use of component-specific decay rates. One hundred percent diversion of yard waste and food waste reduced the year 20 methane production rate by 45%. When a landfill gas collection schedule was introduced, collectable methane was most influenced by food waste diversion at years 10 and 20 and paper diversion at year 40.

  9. The National Information Infrastructure: Agenda for Action.

    ERIC Educational Resources Information Center

    Department of Commerce, Washington, DC. Information Infrastructure Task Force.

    The National Information Infrastructure (NII) is planned as a web of communications networks, computers, databases, and consumer electronics that will put vast amounts of information at the users' fingertips. Private sector firms are beginning to develop this infrastructure, but essential roles remain for the Federal Government. The National…

  10. The National Information Infrastructure: Requirements for Education and Training.

    ERIC Educational Resources Information Center

    National Coordinating Committee on Technology in Education and Training, Alexandria, VA.

    The National Coordinating Committee for Technology in Education and Training (NCC-TET) has developed these requirements to ensure that the National Information Infrastructure (NII) provides expanded opportunities for education and training. A number of national organizations have contributed to these requirements, which are intended to be used in…

  11. Libraries and Their Role in the Information Infrastructure. Hearing on Examining the Role of Libraries in Developing America's New Information Infrastructure, before the Subcommittee on Education, Arts and Humanities of the Committee on Labor and Human Resources. United States Senate, One Hundred Third Congress, Second Session.

    ERIC Educational Resources Information Center

    Congress of the U.S., Washington, DC. Senate Committee on Labor and Human Resources.

    The purpose of this congressional hearing was to determine how libraries fit into the emerging national information infrastructure (NII). Testimony and prepared statements include those from Howard F. McGinn, Director, Emporia Public Library, Emporia, Kansas; James H. Billington, Librarian of Congress, Library of Congress, Washington D.C.,…

  12. Dynamics of the CMZ - Giant Magnetic Loops Connection in the Galactic Center

    NASA Astrophysics Data System (ADS)

    Langer, William

    2012-10-01

    Understanding the mass transfer and dynamics among the Galactic Center, the disk, and the halo of the Milky Way is fundamental to the study of the evolution of galaxies and star formation. Several giant molecular loops (GML), detected in CO maps of the Galactic Center, are likely the result of the magnetic Parker instability. We have new evidence of a possible dynamical connection between these loops and the Central Molecular Zone (CMZ) from a sparse [CII] sampling from our Herschel Open Time Key Project GOT C+. The CMZ-GML region is dynamically active and is likely to have a significant ionized component. However, we have no information on the distribution and dynamics of the ionized gas. The fine-structure lines of [NII] are key probes of the warm ionized medium (WIM) and along with the [CII] can isolate the different ionization components. We have a Herschel OT2 Priority 1 program to map the GML and the CMZ-GML connection in [CII] in more detail. However, we did not propose needed [NII] observations due to an incomplete analysis of our limited GOT C+ data at the time. Here we propose to observe with the SOFIA/GREAT instrument, [NII] in the CMZ-GML interface region using the L1b band, and serendipitously CO (16-15) using band L2. With this data, combined with our Herschel HIFI [CII], Mopra 12CO (1-0) and 13CO (1-0), and HI, we will characterize these important ISM components and their motions in these Galactic Center features. These observations of the nearest such regions of galactic center activity, also have bearing on the dynamics of other galactic nuclei.

  13. Vestibular evoked myogenic potentials in young children: test parameters and normative data.

    PubMed

    Kelsch, Timothy A; Schaefer, Lynne A; Esquivel, Carlos R

    2006-06-01

    The vestibular evoked myogenic potential (VEMP) is a test of the vestibulocollic reflex that has been extensively studied in adults. Much is known about the normal values in adults as well as their changes with age. In children, the expected test values and their possible changes in development have not yet been described nor has the feasibility of reliable testing in this group. The aim of this prospective study is to accumulate normative data and to verify the viability of testing in young children. The study focused on optimal test parameters, reproducibility, and subject compliance in a pediatric population. Thirty normal-hearing children (60 ears) ages 3 to 11 completed VEMP testing and audiograms for analysis. VEMP testing was performed with alternating clicks at three intensities (80-, 85-, and 90-dB normalized hearing level) using averaged, unrectified electromyograms recorded by surface electrode on the sternocleidomastoid muscle ipsilateral to the stimulus. VEMP latencies, amplitude, compliance, and length of testing were recorded for each patient, as well as their feedback on the testing session. The subjects were divided into four age groups for analysis. All but one of the subjects attempting VEMP testing was able to finish. Of 30 children completing VEMP tests, bilateral reflexes were recorded for all subjects with symmetric responses in 28 of 30 subjects (93%). The mean peak latencies (+/- standard deviation [SD]) of pI and nII were 11.3 msec (1.3 ms) and 17.6 msec (1.4 ms), respectively. The mean pI-nII amplitude (+/- SD) was 122 muV (68 muV). There was a significantly shorter nII mean peak latency of group I (ages 3-5) left ear in comparison to other groups, with an absolute shorter mean latency nII in the right ear of group I (not significant). Average test time was 15 minutes with two researchers testing, and subjects were highly compliant. VEMP is a well-tolerated test for screening vestibular function in young children, performed with minimal

  14. 47 CFR 15.403 - Definitions.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... between several transmission power levels in the data transmission process. (s) U-NII devices. Intentional... bridge in a peer-to-peer connection or as a connector between the wired and wireless segments of the... the presence of a radar. (c) Average Symbol Envelope Power. The average symbol envelope power is the...

  15. 47 CFR 15.37 - Transition provisions for compliance with the rules.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... that were in effect immediately prior to September 9, 2002. (d) Radar detectors manufactured or... specified in this part. Radar detectors manufactured or imported prior to January 27, 2003 may be labeled...-NII equipment operating in the 5.25-5.35 GHz band for which applications for certification are filed...

  16. 47 CFR 15.37 - Transition provisions for compliance with the rules.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... that were in effect immediately prior to September 9, 2002. (d) Radar detectors manufactured or... specified in this part. Radar detectors manufactured or imported prior to January 27, 2003 may be labeled...-NII equipment operating in the 5.25-5.35 GHz band for which applications for certification are filed...

  17. 47 CFR 15.37 - Transition provisions for compliance with the rules.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... that were in effect immediately prior to September 9, 2002. (d) Radar detectors manufactured or... specified in this part. Radar detectors manufactured or imported prior to January 27, 2003 may be labeled...-NII equipment operating in the 5.25-5.35 GHz band for which applications for certification are filed...

  18. Atomic and Nuclear Interactions of High Energy Photons and Electrons with Matter.

    DTIC Science & Technology

    1975-09-29

    IJ / VIh /hh1 ij~ ~ 111/ ~ ~~~~ ‘a” • •- • ~~ iitjiJ ~t~I~I1 J(I’,n) 17iTI~f ( ~ ,2n)II ~~~~~ I . a p g ~ ~ p p0 . — T:I Shacklston (Sh?t) LI

  19. 47 CFR 15.403 - Definitions.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... Network. (r) Transmit Power Control (TPC). A feature that enables a U-NII device to dynamically switch... control level. Power must be summed across all antennas and antenna elements. The average must not include... modulation techniques and provide a wide array of high data rate mobile and fixed communications for...

  20. 47 CFR 15.403 - Definitions.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... Network. (r) Transmit Power Control (TPC). A feature that enables a U-NII device to dynamically switch... control level. Power must be summed across all antennas and antenna elements. The average must not include... modulation techniques and provide a wide array of high data rate mobile and fixed communications for...

  1. 47 CFR 15.403 - Definitions.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... power control level. Power must be summed across all antennas and antenna elements. The average must not... symbols, during which the average symbol envelope power is constant. (q) RLAN. Radio Local Area Network. (r) Transmit Power Control (TPC). A feature that enables a U-NII device to dynamically switch between...

  2. Connecting K-12 Schools to the Information Superhighway.

    ERIC Educational Resources Information Center

    McKinsey & Co., Inc., Washington, DC.

    This report summarizes an analysis of options for connecting the nation's public K-12 schools to the national information infrastructure (NII)--or information superhighway. It incorporates insights drawn from visits to schools and interviews with educators, policymakers, and technology experts around the country, as well as from a review of the…

  3. The Information Infrastructure: Reaching Society's Goals. A Report of the Information Infrastructure Task Force Committee on Applications and Technology.

    ERIC Educational Resources Information Center

    National Inst. of Standards and Technology, Gaithersburg, MD.

    Intended for public comment and discussion, this document is the second volume of papers in which the Information Infrastructure Task Force has attempted to articulate in clear terms, with sufficient detail, how improvements in the National Information Infrastructure (NII) can help meet other social goals. These are not plans to be enacted, but…

  4. Innovation, TIDE Teachers, and the Global Economy: The Direct Ability of a TIDE Education to Create Investors and Innovators is Simply Overlooked and Underestimated

    ERIC Educational Resources Information Center

    Starkweather, Kendall N.

    2005-01-01

    The National Innovation Initiative (NII) defines innovation as "the intersection of invention and insight, leading to the creation of social and economic value." Innovation has been fundamental in exploration, opportunity, and discovery. It is the story of how technology has advanced, is used, and powers the economic engines of a country. NII…

  5. 47 CFR 15.407 - General technical requirements.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... interval of continuous transmission using instrumentation calibrated in terms of an rms-equivalent voltage... Function of Dynamic Frequency Selection (DFS). U-NII devices operating in the 5.25-5.35 GHz and 5.47-5.725...) For the band 5.15-5.25 GHz, the maximum conducted output power over the frequency band of operation...

  6. Attempted Synthesis of 1,4-Dinitro(3,4-b)-(3,4-e)Difurazanopiperazine

    DTIC Science & Technology

    1989-07-01

    nitrolysis or hydrolysis followed by nitration would yield 1. Unfortunately, all oxidation attempts failed. Using pyridinium SCHEME 11 PCC//&_ / :\\ NitiRly!is...26c or 71 - 0 / 0*---. w. 1 Jones’ NX NII N Reagent "- Hydrolysis ’NO2+" 32 5 chlorochromate (Reference 23) or Jones’ reagent (Reference 24) yielded

  7. New Bedford, Sampling and Analysis Data: References 34-60, 1976-1983

    EPA Pesticide Factsheets

    2012-04-22

    ... HIV u;nM in in :;i inn 'in iraii'MiLncniii, !i,i IB ii i T 11^1,111:111 imii«'; ncnl.Mr; i': 'ii ... r ii |: 'nii>i>eiri I: ji; I: :i vnn CD II: |M:I|:'',I. lu I: i i:>i: ej:p» i; Mire ILu nn ...

  8. 32 CFR 241.10 - Small business consideration.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 32 National Defense 2 2012-07-01 2012-07-01 false Small business consideration. 241.10 Section 241...) § 241.10 Small business consideration. The ASD(NII)/DoD CIO on behalf of the Secretary of Defense shall: (a) Ensure that, of the assignments made each year, at least 20 percent are small business concerns...

  9. Security Assessment Simulation Toolkit (SAST) Final Report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Meitzler, Wayne D.; Ouderkirk, Steven J.; Hughes, Chad O.

    2009-11-15

    The Department of Defense Technical Support Working Group (DoD TSWG) investment in the Pacific Northwest National Laboratory (PNNL) Security Assessment Simulation Toolkit (SAST) research planted a technology seed that germinated into a suite of follow-on Research and Development (R&D) projects culminating in software that is used by multiple DoD organizations. The DoD TSWG technology transfer goal for SAST is already in progress. The Defense Information Systems Agency (DISA), the Defense-wide Information Assurance Program (DIAP), the Marine Corps, Office Of Naval Research (ONR) National Center For Advanced Secure Systems Research (NCASSR) and Office Of Secretary Of Defense International Exercise Program (OSDmore » NII) are currently investing to take SAST to the next level. PNNL currently distributes the software to over 6 government organizations and 30 DoD users. For the past five DoD wide Bulwark Defender exercises, the adoption of this new technology created an expanding role for SAST. In 2009, SAST was also used in the OSD NII International Exercise and is currently scheduled for use in 2010.« less

  10. Efficient convex-elastic net algorithm to solve the Euclidean traveling salesman problem.

    PubMed

    Al-Mulhem, M; Al-Maghrabi, T

    1998-01-01

    This paper describes a hybrid algorithm that combines an adaptive-type neural network algorithm and a nondeterministic iterative algorithm to solve the Euclidean traveling salesman problem (E-TSP). It begins with a brief introduction to the TSP and the E-TSP. Then, it presents the proposed algorithm with its two major components: the convex-elastic net (CEN) algorithm and the nondeterministic iterative improvement (NII) algorithm. These two algorithms are combined into the efficient convex-elastic net (ECEN) algorithm. The CEN algorithm integrates the convex-hull property and elastic net algorithm to generate an initial tour for the E-TSP. The NII algorithm uses two rearrangement operators to improve the initial tour given by the CEN algorithm. The paper presents simulation results for two instances of E-TSP: randomly generated tours and tours for well-known problems in the literature. Experimental results are given to show that the proposed algorithm ran find the nearly optimal solution for the E-TSP that outperform many similar algorithms reported in the literature. The paper concludes with the advantages of the new algorithm and possible extensions.

  11. Childrens' health, community networks, and the NII: making the connections

    NASA Astrophysics Data System (ADS)

    Deutsch, Larry; Bronzino, Joseph D.; Farmer, Samuel J.

    1996-02-01

    To provide quality health care, clinicians need to be well informed. For health care to be cost effective and efficient, redundant services must be eliminated. Urban centers and rural areas need regional health information networks to ensure that primary health care is delivered with good continuity and coordination among providers. This paper describes the development of a city-wide computer-based pediatric health care network to improve decision-making and follow-through, and to provide aggregate data for public health purposes. The design criteria and process for this regional system are presented, addressing issues of network architecture, establishment of a uniform data base, and confidentiality.

  12. Investigate existing non-intrusive (NII) technologies for port cargo inspections.

    DOT National Transportation Integrated Search

    2011-09-01

    "The quantity of cargo handled by United States ports has increased significantly in recent years. Based on : 2004 data, almost 2.7 billion tons of cargo passed through the ports in one year. To protect the U.S., all of this : cargo must be inspected...

  13. Making Stability Operations Less Complex While Improving Interoperability

    DTIC Science & Technology

    2008-06-01

    Concepts, Theory, Policy Multinational Endeavors Civil Military Endeavors by Erik Chaum , Gerard Christman Point of Contact: Gerard Christman...Interoperability” Mr. Erik Chaum Naval Undersea Warfare Center ChaumE @npt.nuwc.navy.mil Mr. Gerry Christman OASD NII (IICT) Gerard.christman.ctr...awareness and understanding. In a context as complex as StabOps effective com- 5 Alberts, David S. 2007

  14. College Psychotherapy at a Taiwanese Counseling Center

    ERIC Educational Resources Information Center

    Lin, Yii-nii

    2014-01-01

    This article introduces Yii-nii Lin, Professor in the Center for Teacher Education at the National Tsing Hua University in Taiwan, and prior director of the university's counseling center for a 3 year term. She has worked as a university counselling psychologist for more than 15 years when she participated in an online interview that questioned…

  15. Differences in Autism Spectrum Disorders Incidence by Sub-Populations in Israel 1992-2009: A Total Population Study

    ERIC Educational Resources Information Center

    Raz, Raanan; Weisskopf, Marc G.; Davidovitch, Michael; Pinto, Ofir; Levine, Hagai

    2015-01-01

    We analyzed data from the Israeli National Insurance Institute (NII). Autism Spectrum Disorder (ASD) incidence was calculated for all children born in Israel 1992-2009, and by population groups. Overall, 9,109 ASD cases among 2,431,649 children were identified. ASD cumulative incidence by age 8 years increased 10-fold during 2000-2011, from 0.49 %…

  16. Joint Operations 2030 - Phase III Report: The JO 2030 Capability Set (Operations interarmees 2030 - Rapport Phase III: L’ensemble capacitaire JO 2030)

    DTIC Science & Technology

    2011-04-01

    a ‘strategy as process’ manner to develop capabilities that are flexible, adaptable and robust. 3.4 Future structures The need for agile...to develop models of the future security environment 3.4.10 Planning Under Deep Uncertainty Future structures The need for agile, flexible and... Organisation NEC Network Enabled Capability NGO Non Government Organisation NII Networking and Information Infrastructure PVO Private Voluntary

  17. Children's Depression Screener (ChilD-S): Development and Validation of a Depression Screening Instrument for Children in Pediatric Care

    ERIC Educational Resources Information Center

    Fruhe, Barbara; Allgaier, Antje-Kathrin; Pietsch, Kathrin; Baethmann, Martina; Peters, Jochen; Kellnar, Stephan; Heep, Axel; Burdach, Stefan; von Schweinitz, Dietrich; Schulte-Korne, Gerd

    2012-01-01

    The aim of the present study was to develop and validate the Children's Depression Screener (ChilD-S) for use in pediatric care. In two pediatric samples, children aged 9-12 (NI = 200; NII = 246) completed an explorative item pool (subsample I) and a revised item pool (subsample II). Diagnostic accuracy of each of the 22 items from the revised…

  18. Power to the Edge: Command...Control...in the Information Age

    DTIC Science & Technology

    2003-01-01

    Major Findings. Dec 17-19, 2002. OSD(NII) in conjunction with RAND and EBR, Inc. 12 Plummer, Anne. “Expeditionary Test.” Air Force Magazine . Arlington...Command... Control... in the Information Age...to 00-00-2003 4. TITLE AND SUBTITLE Power to the Edge. Command...Control... in the Information Age 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c

  19. Structural Changes and Convective Processes in Tropical Cyclones as Seen in Infrared and Water Vapor Satellite Data

    DTIC Science & Technology

    2013-05-10

    tropical depression; yellow, a tropical storm ; red, a typhoon; and purple, an extratropical cyclone (after http://agora.ex.nii.ac.jp/digital- typhoon... storm (JTWC 2012). Tropical Storm Jelawat continued into the Sea of Japan, where it completed extratropical transition (JTWC 2012...including strong winds, storm surge, high waves, and heavy rainfall, threaten archipelagos, densely crowded coastlines, and naval forces ashore and

  20. OSI and TCP/IP

    NASA Technical Reports Server (NTRS)

    Randolph, Lynwood P.

    1994-01-01

    The Open Systems Interconnection Transmission Control Protocol/Internet Protocol (OSI TCP/IP) and the Government Open Systems Interconnection Profile (GOSIP) are compared and described in terms of Federal internetworking. The organization and functions of the Federal Internetworking Requirements Panel (FIRP) are discussed and the panel's conclusions and recommendations with respect to the standards and implementation of the National Information Infrastructure (NII) are presented.

  1. Charge separation related to photocatalytic H 2 production from a Ru–apoflavodoxin–Ni biohybrid

    DOE PAGES

    Soltau, Sarah R.; Niklas, Jens; Dahlberg, Peter D.; ...

    2016-12-27

    The direct creation of a fuel from sunlight and water via photochemical energy conversion provides a sustainable method for producing a clean source of energy. Here we report the preparation of a solar fuel biohybrid that embeds a nickel diphosphine hydrogen evolution catalyst into the cofactor binding pocket of the electron shuttle protein, flavodoxin (Fld). The system is made photocatalytic by linking a cysteine residue in Fld to a ruthenium photosensitizer. Importantly, the protein environment enables the otherwise insoluble Ni catalyst to perform photocatalysis in aqueous solution over a pH range of 3.5–12.0, with optimal turnover frequency 410 ± 30more » h –1 and turnover number 620 ± 80 mol H 2/mol hybrid observed at pH 6.2. For the first time, a reversible light-induced charge-separated state involving a Ni(I) intermediate was directly monitored by electron paramagnetic resonance spectroscopy. As a result, transient optical measurements reflect two conformational states, with a Ni(I) state formed in ~1.6 or ~185 μs that persists for several milliseconds as a long-lived charge-separated state facilitated by the protein matrix.« less

  2. Assessing risks to adults and preschool children posed by PM2.5-bound polycyclic aromatic hydrocarbons (PAHs) during a biomass burning episode in Northern Thailand.

    PubMed

    Pongpiachan, Siwatt; Tipmanee, Danai; Khumsup, Chukkapong; Kittikoon, Itthipon; Hirunyatrakul, Phoosak

    2015-03-01

    To investigate the potential cancer risk resulting from biomass burning, polycyclic aromatic hydrocarbons (PAHs) bound to fine particles (PM2.5) were assessed in nine administrative northern provinces (NNP) of Thailand, before (N-I) and after (N-II) a haze episode. The average values of Σ 3,4-ring PAHs and B[a] P Equivalent concentrations in world urban cities were significantly (p<0.05) much higher than those in samples collected from northern provinces during both sampling periods. Application of diagnostic binary ratios of PAHs underlined the predominant contribution of vehicular exhaust to PM2.5-bound PAH levels in NNP areas, even in the middle of the agricultural waste burning period. The proximity of N-I and N-II values in three-dimensional (3D) principal component analysis (PCA) plots also supports this conclusion. Although the excess cancer risk in NNP areas is much lower than those of other urban area and industrialized cities, there are nevertheless some concerns relating to adverse health impacts on preschool children due to non-dietary exposure to PAHs in home environments. Copyright © 2014 Elsevier B.V. All rights reserved.

  3. Ionization of the diffuse gas in galaxies: Hot low-mass evolved stars at work

    NASA Astrophysics Data System (ADS)

    Flores-Fajardo, N.; Morisset, C.; Stasinska, G.; Binette, L.

    2011-10-01

    The Diffuse Ionized Medium (DIG) is visible through its faint optical line emission outside classical HII regions (Reynolds 1971) and turns out to be a major component of the interstellar medium in galaxies. OB stars in galaxies likely represent the main source of ionizing photons for the DIG. However, an additional source is needed to explain the increase of [NII]/Hα, [SII]/Hα with galactic height.

  4. Information Technology. DOD Needs to Strengthen Management of Its Statutorily Mandated Software and System Process Improvement Efforts

    DTIC Science & Technology

    2009-09-01

    NII)/CIO Assistant Secretary of Defense for Networks and Information Integration/Chief Information Officer CMMI Capability Maturity Model...a Web-based portal to share knowledge about software process-related methodologies, such as the SEI’s Capability Maturity Model Integration ( CMMI ...19 SEI’s IDEALSM model, and Lean Six Sigma.20 For example, the portal features content areas such as software acquisition management, the SEI CMMI

  5. Algorithms for Developing Test Questions from Sentences in Instructional Materials: an Extension of an Earlier Study

    DTIC Science & Technology

    1980-01-01

    Silverfish, Canine, and Cicadas . b. ’Mgorithinically--Sdverfish, Females, Individuals, and Wasps. This process resulted in 16.0 multiple-choice items: 20...and Their Text Frequency Nouns Adjectives Rare Singleton Keyword Rare Singleton Keyword Instars Insect (8) Plant-feeding Immature (3) Cicadas ...Sllverflsh (c) Caniru’S (d) Cicadas c. Foils Produced Algorl ..nii-allv: Sllverflsh Fenvilea ItuliviJu.i Is Wanps ?. Kevword Adjective—Immature

  6. Engine Oils with a New Composition of Additives

    DTIC Science & Technology

    A lubricant additive composition IKhP (2.6% BFK, a Ba salt of a CH2O- alkylphenol condensation product; 1.4% SB-3, a Ba sulfonate; 1.2% IN-KhP-21, a...Ba salt of a CH2O-NH3- alkylphenol condensation product; 0.005% PMS-200A; and 0. 5% AzNII) is discussed in relationship to its use as an automobile oil

  7. SCIENTIFIC-RESEARCH WORK IN THE FIELD OF ADDITIVE CHEMISTRY,

    DTIC Science & Technology

    multifunctional oil additives is reviewed. Antioxidants based on nitrogen-containing compounds were prepared by condensation of alkylphenols with formaldehyde and... alkylphenols or their sulfides with formaldehyde and amines or aniline and reaction with phosphorus trichloride are effective additives. AzNII-10 is based...on p-tert. amylphenol. INKhP-21 and INKhP-25, condensation products of alkylphenols , formaldehyde, and an amine treated with phosphorus pentachloride

  8. Electronic Commerce: A National Performance Review Initiative.

    DTIC Science & Technology

    1995-09-01

    This study of the National Information Infrastructure (NII) was conducted as part of IDA’s Central Research Program. Electronic commerce is one of... commerce is nothing more than conducting business via electronic means. An outgrowth of the NPR, the electronic commerce initiative, commits the...private, and public sectors are committed to implementing electronic commerce throughout the United States. The objective ol this paper is to enhance

  9. Kinetic Analysis of Competitive Electrocatalytic Pathways: New Insights into Hydrogen Production with Nickel Electrocatalysts

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wiedner, Eric S.; Brown, Houston J.; Helm, Monte L.

    2016-01-20

    The hydrogen production electrocatalyst Ni(PPh2NPh2)22+ (1) is capable of traversing multiple electrocatalytic pathways. When using dimethylformamidium, DMF(H)+, the mechanism of formation of H2 catalyzed by 1 changes from an ECEC to an EECC mechanism as the potential approaches the Ni(I/0) couple. Two recent electrochemical methods, current-potential analysis and foot-of-the-wave analysis (FOWA), were performed on 1 to measure the detailed chemical kinetics of the competing ECEC and EECC pathways. A sensitivity analysis was performed on the electrochemical methods using digital simulations to gain a better understanding of their strengths and limitations. Notably, chemical rate constants were significantly underestimated when not accountingmore » for electron transfer kinetics, even when electron transfer was fast enough to afford a reversible non-catalytic wave. The EECC pathway of 1 was found to be faster than the ECEC pathway under all conditions studied. Using buffered DMF: DMF(H)+ mixtures led to an increase in the catalytic rate constant (kobs) of the EECC pathway, but kobs for the ECEC pathway did not change when using buffered acid. Further kinetic analysis of the ECEC path revealed that added base increases the rate of isomerization of the exo-protonated Ni(0) isomers to the catalytically active endo-isomers, but decreases the net rate of protonation of Ni(I). FOWA on 1 did not provide accurate rate constants due to incomplete reduction of the exo-protonated Ni(I) intermediate at the foot of the wave, but FOWA could be used to estimate the reduction potential of this previously undetected intermediate. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.« less

  10. Transfer and utilization of government technology assets to the private sector in the fields of health care and information technologies

    NASA Astrophysics Data System (ADS)

    Kun, Luis G.

    1995-10-01

    During the first Health Care Technology Policy conference last year, during health care reform, four major issues were brought up in regards to the efforts underway to develop a computer based patient record (CBPR), the National Information Infrastructure (NII) as part of the high performance computers and communications (HPCC), and the so-called 'patient card.' More specifically it was explained how a national information system will greatly affect the way health care delivery is provided to the United States public and reduce its costs. These four issues were: (1) Constructing a national information infrastructure (NII); (2) Building a computer based patient record system; (3) Bringing the collective resources of our national laboratories to bear in developing and implementing the NII and CBPR, as well as a security system with which to safeguard the privacy rights of patients and the physician-patient privilege; (4) Utilizing government (e.g., DOD, DOE) capabilities (technology and human resources) to maximize resource utilization, create new jobs, and accelerate technology transfer to address health care issues. This year a section of this conference entitled: 'Health Care Technology Assets of the Federal Government' addresses benefits of the technology transfer which should occur for maximizing already developed resources. This section entitled: 'Transfer and Utilization of Government Technology Assets to the Private Sector,' will look at both health care and non-health care related technologies since many areas such as information technologies (i.e. imaging, communications, archival/retrieval, systems integration, information display, multimedia, heterogeneous data bases, etc.) already exist and are part of our national labs and/or other federal agencies, i.e., ARPA. These technologies although they are not labeled under health care programs they could provide enormous value to address technical needs. An additional issue deals with both the technical

  11. The bipolar jet of the symbiotic star R Aquarii: A study of its morphology using the high-resolution HST WFC3/UVIS camera

    NASA Astrophysics Data System (ADS)

    Melnikov, Stanislav; Stute, Matthias; Eislöffel, Jochen

    2018-04-01

    Context. R Aqr is a symbiotic binary system consisting of a Mira variable with a pulsation period of 387 days and a hot companion which is presumably a white dwarf with an accretion disk. This binary system is the source of a prominent bipolar gaseous outflow. Aims: We use high spatial resolution and sensitive images from the Hubble Space Telescope (HST) to identify and investigate the different structural components that form the complex morphology of the R Aqr jet. Methods: We present new high-resolution HST WFC3/UVIS narrow-band images of the R Aqr jet obtained in 2013/14 using the [OIII]λ5007, [OI]λ6300, [NII]λ6583, and Hα emission lines. These images also allow us to produce detailed maps of the jet flow in several line ratios such as [OIII]λ5007/[OI]λ6300 and [NII]λ6583/[OI]λ6300 which are sensitive to the outflow temperature and its hydrogen ionisation fraction. The new emission maps together with archival HST data are used to derive and analyse the proper motion of prominent emitting features which can be traced over 20 years with the HST observations. Results: The images reveal the fine gas structure of the jet out to distances of a few tens of arcseconds from the central region, as well as in the innermost region, within a few arcseconds around the stellar source. They reveal for the first time the straight, highly collimated jet component which can be traced to up to 900 AU in the NE direction. Images in [OIII]λ5007, [OI]λ6300, and [NII]λ6583 clearly show a helical pattern in the jet beams which may derive from the small-scale precession of the jet. The highly collimated jet is accompanied by a wide opening angle outflow which is filled by low excitation gas. The position angles of the jet structures as well as their opening angles are calculated. Our measurements of the proper motions of some prominent emission knots confirm the scenario of gas acceleration during the propagation of the outflow. Finally, we produce several detailed line ratio

  12. Evaluating and minimizing noise impact due to aircraft flyover

    NASA Technical Reports Server (NTRS)

    Jacobson, I. D.

    1980-01-01

    The results of a study on the evaluation and reduction of noise impact to a community due to aircraft landing and takeoff operations are presented. The case of multiple aircrafts flying on several trajectories, for either approach/landings or takeoffs was examined. An extremely realistic model of the flight path was developed. The annoyance criterion used was the noise impact index (NII). The algorithm was applied to Patrick Henry International Airport.

  13. Report of the Defense Science Board Task Force on Wideband Radio Frequency Modulation: Dynamic Access to Mobile Information Networks

    DTIC Science & Technology

    2003-07-01

    Centric Architecture Office ( NCAO ) should develop an RF communications/network management technology roadmap. The roadmap should serve two purposes: a...Centric Architecture Office ( NCAO ) chartered with integrating diverse DoD efforts to provide technical alternatives to the current form of radio...American people as a cornerstone of DoD’s leadership of the public trust in this area. The NCAO should be consolidated from ongoing NII, JTRS JPO and DDR

  14. National Positioning, Navigation, and Timing Architecture Study

    DTIC Science & Technology

    2008-09-01

    Ballooning • Trip Planning Environment • Tide / Current Measures • BLM Tract Management • Oil Spill Containment • Hazardous Waste Remediation...SMC/GPSW (Aerospace) Adde, Barbara GOVT NASA Alexander, Dexter LTC USA SMDC Alexander, Ken GOVT FAA Rep to NCO Allen, Leonard GOVT FRA...Shawn Lt Col USAF NSSO/PNT Brewer, Mike Col USAF OASD/NII Space Programs Brodsky, Beryl CTR NASA (Overlook) Broussard, Robert CTR AFSPC/A5

  15. The Federal Role in Bringing Education into the National Information Infrastructure

    NASA Technical Reports Server (NTRS)

    Cradler, John

    1995-01-01

    One of the most important issues facing Congress is to work with business, education, and the states to enable the nation's shools to better prepare students for a technological work force and to ensure that education has a place on the National Information Infrastructure (NII). This document provides background and important information for national leaders concerned about education, the information infrastructure, and related issues for the Federal government.

  16. Disruption of the nitrogen regulatory gene AcareA in Acremonium chrysogenum leads to reduction of cephalosporin production and repression of nitrogen metabolism.

    PubMed

    Li, Jinyang; Pan, Yuanyuan; Liu, Gang

    2013-12-01

    AcareA, encoding a homologue of the fungal nitrogen regulatory GATA zinc-finger proteins, was cloned from Acremonium chrysogenum. Gene disruption and genetic complementation revealed that AcareA was required for nitrogen metabolism and cephalosporin production. Disruption of AcareA resulted in growth defect in the medium using nitrate, uric acid and low concentration of ammonium, glutamine or urea as sole nitrogen source. Transcriptional analysis showed that the transcription of niaD/niiA was increased drastically when induced with nitrate in the wild-type and AcareA complemented strains but not in AcareA disruption mutant. Consistent with the reduction of cephalosporin production, the transcription of pcbAB, cefD2, cefEF and cefG encoding the enzymes for cephalosporin production was reduced in AcareA disruption mutant. Band shift assays showed that AcAREA bound to the promoter regions of niaD, niiA and the bidirectional promoter region of pcbAB-pcbC. Sequence analysis showed that all the AcAREA binding sites contain the consensus GATA elements. These results indicated that AcAREA plays an important role both in the regulation of nitrogen metabolism and cephalosporin production in A. chrysogenum. Copyright © 2013 Elsevier Inc. All rights reserved.

  17. The Image Understanding Architecture Project

    DTIC Science & Technology

    1988-04-01

    The error resulted in the frame being reduced in size and incorrectly bonded . The problem has been corrected and3 the design has been re-submitted...Promotional literature, Beaverton, OR, 1985. Nii, 1986] Nil, H.P., The Blackboard Model of Problem Solving and the Evolution of Blackboard...microns. This resulted in a reduction in pad sizes to two thirds of the minimum required for safe bonding . All chips had many wire bonds on the die

  18. A comparison of FUV dayglows measured by STSAT-1/FIMS with the AURIC model in a geomagnetic quiet condition

    NASA Astrophysics Data System (ADS)

    Kam, Hosik; Kim, Yong Ha; Hong, Jun-Seok; Lee, Joon-Chan; Choi, Yeon-Ju; Min, Kyung Wook

    2014-09-01

    The Korea scientific microsatellite, STSAT-1 (Science and Technology Satellite-1), was launched in 2003 and observed far ultraviolet (FUV) airglow from the upper atmosphere with a Far-ultraviolet IMaging Spectrograph (FIMS) at an altitude of 690 km. The FIMS consists of a dual-band imaging spectrograph of 900-1150 Å (S-band) and 1340-1715 Å (L-band). Limb scanning observations were performed only at the S-band, resulting in intensity profiles of OI 989 Å, OI 1026 Å, NII 1085 Å and NI 1134 Å emission lines near the horizon. We compare these emission intensities with those computed by using a theoretical model, the AURIC (Atmospheric Ultraviolet Radiance Integrated Code). The intensities of the OI 1026 Å, NII 1085 Å and NI 1134 Å emissions measured by using the FIMS are overall consistent with the values computed by using AURIC under the thermospheric and solar activity conditions on August 6, 1984, which is close to the FIMS's observation condition. We find that the FIMS dayglow intensity profiles match reasonably well with AURIC intensity profiles for the MSIS90 oxygen atom density profiles within factors of 0.5 and 2. However, the FIMS intensities of the OI 989 Å line are about 2 ˜ 4 times stronger than the AURIC intensities, which is expected because AURIC does not properly simulate resonance scattering of airglow and solar photons at 989 Å by atomic oxygen in the thermosphere. We also find that the maximum tangential altitudes of the oxygen bearing dayglows (OI 989 Å, OI 1026 Å) are higher than those of the nitrogen-bearing dayglows (NII 1085 Å, NI 1134 Å), which is confirmed by using AURIC model calculations. This is expected because the oxygen atoms are distributed at higher altitudes in the thermosphere than the nitrogen molecules. Validations of the qualities of both the FIMS instrument and the AURIC model indicate that AURIC should be updated with improved thermospheric models and with measured solar FUV spectra for better agreement with the

  19. Department of Defense counterdrug technology development of non-intrusive inspection systems

    NASA Astrophysics Data System (ADS)

    Pennella, John J.

    1997-02-01

    The Naval Surface Warfare Center Dahlgren Division serves as the executive agent for the DoD's Contraband Detection and Cargo Container Inspection Technology Development Program. The goal of the DoD non-intrusive inspection (NII) program is to develop prototype equipment that can be used to inspect containers and vehicles, quickly and in large numbers without unnecessary delays in the movement of legitimate cargo. This paper summaries the past accomplishments of the program, current status, and future plans.

  20. Studies on the Preparation and Properties of RDX

    DTIC Science & Technology

    1943-08-24

    OF SCIENTIFIC RESEARCH AND DEVELOPMENT Report on " Studies on the Preparation and Properties of RDXn to August 15, 1942 by W. E. Bachmann OSRD...University of i"ichi|*an. I- i Roger Adaa»# Chairnan by Harris 1.. Chadwcll Technical .«tdo ! ’■JHUtNii/i : B. STUDIES ON THE PREPARATION AND...Rocovory of Anconiun Nitrate . . • »34 E. STUDIES ON BSX . . . . . • .35 1. Proparr.ticn of BSX . . • • • .36 2

  1. Interstellar Deuterium, Nitrogen and Oxygen Towards HZ43A: Results from the Far Ultraviolet Spectroscopic Explorer (FUSE) Mission

    NASA Technical Reports Server (NTRS)

    Kruk, J. W.; Howk, J. C.; Andre, M.; Moos, H. W.; Oegerle, William R.; Oliveira, C.; Sembach, K. R.; Chayer, P.; Linsky, J. L.; Wood, B. E.

    2002-01-01

    We present an analysis of interstellar absorption along the line of sight to the nearby white dwarf star HZ43A. The distance to this star is 68+/-13 pc, and the line of sight extends toward the north Galactic pole. Column densities of O(I), N(I), and N(II) were derived from spectra obtained by the Far Ultraviolet Spectroscopic Explorer (FUSE), the column density of D(I) was derived from a combination of our FUSE spectra and an archival HST GARDENS spectrum, and the column density of H(I) was derived from a combination of the GARDENS spectrum and values derived from EUVE data obtained from the literature. We find the following abundance ratios (with 2 sigma uncertainties): D(I)/H(I)=(1.66+/-0.28)x10(exp -5), O(I)/H(I)=(3.63+/-0.84)x10(exp -4), and N(I)/H(I)=(3.80+/-0.74)x10(exp -5). The N(II) column density was slightly greater than that of N(I), indicating that ionization corrections are important when deriving nitrogen abundances. Other interstellar species detected along the line of sight were C(II), C(III), O(VI), Si(II), Ar(I), Mg(II) and Fe(II); an upper limit was determined for N(III). No elements other than H(I) were detected in the stellar photosphere.

  2. VizieR Online Data Catalog: NIR spectral analysis of star-forming galaxies (Genzel+, 2014)

    NASA Astrophysics Data System (ADS)

    Genzel, R.; Forster Schreiber, N. M.; Rosario, D.; Lang, P.; Lutz, D.; Wisnioski, E.; Wuyts, E.; Wuyts, S.; Bandara, K.; Bender, R.; Berta, S.; Kurk, J.; Mendel, J. T.; Tacconi, L. J.; Wilman, D.; Beifiori, A.; Brammer, G.; Burkert, A.; Buschkamp, P.; Chan, J.; Carollo, C. M.; Davies, R.; Eisenhauer, F.; Fabricius, M.; Fossati, M.; Kriek, M.; Kulkarni, S.; Lilly, S. J.; Mancini, C.; Momcheva, I.; Naab, T.; Nelson, E. J.; Renzini, A.; Saglia, R.; Sharples, R. M.; Sternberg, A.; Tacchella, S.; van Dokkum, P.

    2017-02-01

    For the analysis in this paper, we included a total of 110 SFGs at z~1-3 with near-IR integral field or slit spectroscopy covering the Hα+[NII] line emission from surveys carried out with SINFONI, KMOS, LUCI, and GNIRS. The targets for these surveys were originally drawn from rest-frame optical, UV, and near-IR selected samples in broadband imaging surveys with optical spectroscopic redshifts, and from stellar mass-selected samples with near-IR or optical spectroscopic redshifts. (2 data files).

  3. Government Information Locator Service (GILS). Draft report to the Information Infrastructure Task Force

    NASA Technical Reports Server (NTRS)

    1994-01-01

    This is a draft report on the Government Information Locator Service (GILS) to the National Information Infrastructure (NII) task force. GILS is designed to take advantage of internetworking technology known as client-server architecture which allows information to be distributed among multiple independent information servers. Two appendices are provided -- (1) A glossary of related terminology and (2) extracts from a draft GILS profile for the use of the American National Standard Information Retrieval Application Service Definition and Protocol Specification for Library Applications.

  4. Highly Regioselective Indoline Synthesis under Nickel/Photoredox Dual Catalysis.

    PubMed

    Tasker, Sarah Z; Jamison, Timothy F

    2015-08-05

    Nickel/photoredox catalysis is used to synthesize indolines in one step from iodoacetanilides and alkenes. Very high regioselectivity for 3-substituted indoline products is obtained for both aliphatic and styrenyl olefins. Mechanistic investigations indicate that oxidation to Ni(III) is necessary to perform the difficult C-N bond-forming reductive elimination, producing a Ni(I) complex, which in turn is reduced to Ni(0). This process serves to further demonstrate the utility of photoredox catalysts as controlled single electron transfer agents in multioxidation state nickel catalysis.

  5. R2D2-A Fortran Program for Two-Dimensional Chemically Reacting, Hyperthermal, Internal Flows, Volume II.

    DTIC Science & Technology

    1980-01-01

    is identified in the flow chart simply as "Compute VECT’s ( predictor solution)" and "Compute V’s ( corrector solution)." A significant portion of the...TrintoTo Tm ANDera ionT SToION 28 ITIME :1 PRINCIPAL SUBROUTINES WALLPOINT (ITER,DT) ITER - iteration index for MacCormack Algorithm (ITER=1 for predictor ...WEILERSTEIN, R RAY, 6 MILLER F33615-7- C -3016UNLASSIFIED GASL-TR-254-VBL-2 AFFDL-TR-79-3162-VOL-2 NII III hImllllllllll EIEIIIIIIEIIEE EEIIIIIIIIIIII H

  6. Job Satisfaction and Race Among Military Enlistees.

    DTIC Science & Technology

    1987-06-01

    James , Bruni, and Sells (1977) suggested that black-white...V-65, no. 3. 1980 16. Jones, Allen P., James , Lawrence R., Bruni, John R. and Sells, S.B., Black-White Differences in Work Environment Perceptions...Ignatius Manggolo 51 Srenal Mabes TNI-AL 7’ Cilangkap, Jakarta Selatan Indonesia 6. ,1 67 iU ’I,, t~p I Z I. U’ p.. ’V.. up. uP V. up I. ’up. V. .pp up, up"’*6 ’up *.* .*. n~-.Ii. - .*- up.:. -. -. -

  7. Overview of Megaprogramming Course: Lectures and Exercises

    DTIC Science & Technology

    1995-02-01

    U) aci r0- :3 0- - -aC: +Z.- CO( a00 4-M.2 c E- En (D aCd02 W ~ W > 0 C" a)a : 4r=D = zEC -M Z 0 - whC a)- i-u H0o-0 m 0W coo #C0 00 *z m UE Lu.L 0)r...theACM32:1397-1414. Coad, Peter , and Object-Oriented Analysis. Englewood Cliffs, New Ji,-rscy- Edward Yourdon Prentice-Hall. 1990 Datamation NII I

  8. A Virgo Environmental Survey Tracing Ionised Gas Emission (VESTIGE). I. Introduction to the survey

    NASA Astrophysics Data System (ADS)

    Boselli, A.; Fossati, M.; Ferrarese, L.; Boissier, S.; Consolandi, G.; Longobardi, A.; Amram, P.; Balogh, M.; Barmby, P.; Boquien, M.; Boulanger, F.; Braine, J.; Buat, V.; Burgarella, D.; Combes, F.; Contini, T.; Cortese, L.; Côté, P.; Côté, S.; Cuillandre, J. C.; Drissen, L.; Epinat, B.; Fumagalli, M.; Gallagher, S.; Gavazzi, G.; Gomez-Lopez, J.; Gwyn, S.; Harris, W.; Hensler, G.; Koribalski, B.; Marcelin, M.; McConnachie, A.; Miville-Deschenes, M. A.; Navarro, J.; Patton, D.; Peng, E. W.; Plana, H.; Prantzos, N.; Robert, C.; Roediger, J.; Roehlly, Y.; Russeil, D.; Salome, P.; Sanchez-Janssen, R.; Serra, P.; Spekkens, K.; Sun, M.; Taylor, J.; Tonnesen, S.; Vollmer, B.; Willis, J.; Wozniak, H.; Burdullis, T.; Devost, D.; Mahoney, B.; Manset, N.; Petric, A.; Prunet, S.; Withington, K.

    2018-06-01

    The Virgo Environmental Survey Tracing Ionised Gas Emission (VESTIGE) is a blind narrow-band (NB) Hα+[NII] imaging survey carried out with MegaCam at the Canada-France-Hawaii Telescope. The survey covers the whole Virgo cluster region from its core to one virial radius (104 deg2). The sensitivity of the survey is of f(Hα) 4 × 10-17 erg s-1 cm-2 (5σ detection limit) for point sources and Σ(Hα) 2 × 10-18 erg s-1 cm-2 arcsec-2 (1σ detection limit at 3 arcsec resolution) for extended sources, making VESTIGE the deepest and largest blind NB survey of a nearby cluster. This paper presents the survey in all its technical aspects, including the survey design, the observing strategy, the achieved sensitivity in both the NB Hα+[NII] and in the broad-band r filter used for the stellar continuum subtraction, the data reduction, calibration, and products, as well as its status after the first observing semester. We briefly describe the Hα properties of galaxies located in a 4 × 1 deg2 strip in the core of the cluster north of M87, where several extended tails of ionised gas are detected. This paper also lists the main scientific motivations for VESTIGE, which include the study of the effects of the environment on galaxy evolution, the fate of the stripped gas in cluster objects, the star formation process in nearby galaxies of different type and stellar mass, the determination of the Hα luminosity function and of the Hα scaling relations down to 106 M⊙ stellar mass objects, and the reconstruction of the dynamical structure of the Virgo cluster. This unique set of data will also be used to study the HII luminosity function in hundreds of galaxies, the diffuse Hα+[NII] emission of the Milky Way at high Galactic latitude, and the properties of emission line galaxies at high redshift. Based on observations obtained with MegaPrime/MegaCam, a joint project of CFHT and CEA/DAPNIA, at the Canada-France-Hawaii Telescope (CFHT) which is operated by the National Research

  9. Lessons From Analyzing the Medical Costs of Civilian Terror Victims: Planning Resources Allocation for a New Era of Confrontations.

    PubMed

    Ellenberg, Eytan; Taragin, Mark I; Hoffman, Jay R; Cohen, Osnat; Luft-Afik, Daniella; Bar-On, Zvia; Ostfeld, Ishay

    2017-12-01

    Policy Points: Across the globe, the threat from terrorist attacks is rising, which requires a careful assessment of long-term medical support. We found 3 major sources of costs: hospital expenditures, mental health services dedicated to acute stress reactions, and ambulatory follow-up. During the first year, most of the costs were related to hospitalization and support for stress relief. During the second year, ambulatory and rehabilitation costs continued to grow. Public health specialists should consider these major components of costs and their evolution over time to properly advise the medical and social authorities on allocating resources for the medical and nonmedical support of civilian casualties resulting from war or terror. Across the globe, the threat from terrorist attacks is rising, which requires a careful assessment of long-term medical support. Based on an 18-month follow-up of the Israeli civilian population following the 2014 war in Gaza, we describe and analyze the medical costs associated with rocket attacks and review the demography of the victims who filed claims for disability compensation. We then propose practical lessons to help health care authorities prepare for future confrontations. Using the National Insurance Institute of Israel's (NII) database, we conducted descriptive and comparative analyses using statistical tests (Fisher's Exact Test, chi-square test, and students' t-tests). The costs were updated until March 30, 2016, and are presented in US dollars. We included only civilian expenses in our analysis. We identified 5,189 victims, 3,236 of whom presented with acute stress reactions during the conflict. Eighteen months after the conflict, the victims' total medical costs reached $4.4 million. The NII reimbursed $2,541,053 for associated medical costs and $1,921,792 for associated mental health costs. A total of 709 victims filed claims with the NII for further support, including rehabilitation, medical devices, and disability

  10. Perfis de temperatura eletrônica em regiões HII

    NASA Astrophysics Data System (ADS)

    Copetti, M. V. F.

    2003-08-01

    As flutuações de temperatura eletrônica em regiões HII, inicialmente propostas para explicar as discrepâncias entre os valores de temperatura obtidos por diferentes métodos, têm sido apontadas como a causa mais provável das enormes diferenças encontradas entre as abundâncias químicas medidas através de linhas excitadas colisionalmente e de linhas de recombinação. Recentemente têm sido reportadas tentativas de detecção e quantificação diretas das flutuações de temperatura eletrônica através de medidas ponto a ponto, obtidas por meio de espectroscopia de fenda longa, das razões de linhas [OIII]l4263/l5007 e [NII]l5755/l6584, principais sensores de temperatura. Neste trabalho, utilizamos o código numérico de fotoionização Cloudy para avaliar a confiabilidade desse procedimento. Concluímos que, para valores de densidade eletrônica e de temperatura efetiva da estrela ionizante típicos das regiões HII, os perfis superficiais de temperatura obtidos via medidas do sensor [OIII]l4263/l5007 são bons traçadores dos gradientes internos de temperatura eletrônica. Já os perfis de temperatura eletrônica medidos por meio da razão [NII]l5755/l6584 não reproduzem os gradientes verdadeiros de temperatura.

  11. Subsize Charpy Correlation with Standard Charpy

    DTIC Science & Technology

    1959-12-01

    WATERTOWN4A8N’rM1 (jr) WATERTOWN 72, MASS. SWATERTOWN’ ARSENAL-LABORATORIES - SUBSIZE , CHARPY CORRELAtION WITH, STANDARD ’ CHARPY , TECHNCAL EPORT NO...MAY 8 1981 1This document ’b*~n’u -dt ub16nii reflixs nd f .V W4 ATETOWNASEA WvTEROWN 729 , MASS., AD Impact tests Charpy , subsize /41 Technica 5, o...WAL-TR--112/95 / By ICharle~s HI. urli Decombwr 1#59 0.0. Project: Industrial Preparedness Measure Development of Subsize Charpy Standard P.E.S.D. No

  12. Z39.50 and GILS model. [Government Information Locator Service

    NASA Technical Reports Server (NTRS)

    Christian, Eliot

    1994-01-01

    The Government Information Locator System (GILS) is a component of the National Information Infrastructure (NII) which provides electronic access to sources of publicly accessible information maintained throughout the Federal Government. GILS is an internetworking information resource that identifies other information resources, describes the information available in the referenced resources, and provides assistance in how to obtain the information either directly or through intermediaries. The GILS core content which references each Federal information system holding publicly accessible data or information is described in terms of mandatory and optional core elements.

  13. Fibers and materials of medical application

    NASA Technical Reports Server (NTRS)

    Fridman, L. I.

    1993-01-01

    Efferent sorption methods of organism detoxication (by medical trend) are presented. Recently, specialists have shown their keen interest in the problem of treating exogenous and endogenous intoxications. This was stipulated by the growing production and accumulation of chemical products for industrial, agricultural, and domestic needs. To solve this problem the industrial production of carbon fibrous adsorbents was developed and implemented at NII Chimvolokno in St. Petersburg. A description of the carbon fibers is given. Also, application of modern composite materials for manufacturing compression-distraction apparatus used for setting fractured bones is described.

  14. Light responses and morphology of bNOS-immunoreactive neurons in the mouse retina

    PubMed Central

    Pang, Ji-Jie; Gao, Fan; Wu, Samuel M.

    2010-01-01

    Nitric oxide (NO), produced by NO synthase (NOS), modulates the function of all retinal neurons and ocular blood vessels and participates in the pathogenesis of ocular diseases. To further understand the regulation of ocular NO release, we systematically studied the morphology, topography and light responses of NOS-containing amacrine cells (NOACs) in dark-adapted mouse retina. Immunohistological staining for neuronal NOS (bNOS), combined with retrograde labeling of ganglion cells (GCs) with Neurobiotin (NB, a gap junction permeable dye) and Lucifer yellow (LY, a less permeable dye), was used to identify NOACs. The light responses of ACs were recorded under whole-cell voltage clamp conditions and cell morphology was examined with a confocal microscope. We found that in dark-adapted conditions bNOS-immunoreactivity (IR) was present primarily in the inner nuclear layer and the ganglion cell layer. bNOS-IR somas were negative for LY, thus they were identified as ACs; nearly 6 % of the cells were labeled by NB but not by LY, indicating that they were dye-coupled with GCs. Three morphological subtypes of NOACs (NI, NII and displaced) were identified. The cell density, inter-cellular distance and the distribution of NOACs were studied in whole retinas. Light evoked depolarizing highly sensitive ON-OFF responses in NI cells and less sensitive OFF responses in NII cells. Frequent (1 to 2 Hz) or abrupt change of light-intensity evoked larger peak responses. The possibility for light to modify NO release from NOACs is discussed. PMID:20503422

  15. Solid State Power Controller Fuse Development Program.

    DTIC Science & Technology

    1983-10-01

    4NYP Appendix A nic =,-, ’XW LX, nII4CD1AFam" CC,’AP44 257-290 TABLE I - FAULT CURRENT TRIP TJMWS Fa’ Ii AC Volts Seconds Rema:ks 1. 1.6 100Z 234.0 417.0...calibration date: 12 July 1983 Biddle Power Rheostat, 1000 W, Cat. No. 20 4.2 Procedure Testing was accomplished in two lots, one consisting of the SPC-2A and...Last calibration date: 12 July 1983 Biddle 100dW Power Rheostat, Cat. No. 20 Variac, Environ No. 380-503 4.2 Procedure The test specimens were suspended

  16. Determining the Nature of [CII] 158 Micron Emission: an Improved Star Formation Rate Indicator

    NASA Astrophysics Data System (ADS)

    Sutter, Jessica; Dale, Daniel A.; KINGFISH Team

    2018-06-01

    The brightest observed emission line from most normal star-forming galaxies is the 158 micron line arising from singly-ionized carbon (also known as C+ or CII). In fact, astronomers have recently begun using the bright emission line to detect and characterize galaxies in the furthermost reaches of the universe. It is thus imperative that we have the tools to fully understand how this emission line could be utilized as an indicator of star formation rate, a primary parameter by which galaxies and their constituent star-forming regions are characterized. There are two main challenges to utilizing the [CII] 158 micron line as a star formation rate indicator. First, advances in long-wavelength astronomical instrumentation have only recently enabled its detection in statistically-significant samples of galaxies. Second, it is both a blessing and a curse that singly-ionized carbon can be created in both star-forming regions (ionized HII regions) and in non-star forming regions (neutral photo-dissociation regions). In order to better understand and quantify the [CII] emission as an indicator of star-formation rate, the relationship between the [NII] 205 micron emission, which can only arise from the ionized interstellar medium (ISM), and the [CII] 158 micron emission has been employed to determine the fraction of [CII] emission that originates from each phase of the ISM. Sub-kiloparsec measurements of the [NII] 205 micron line in nearby galaxies have recently become available as part of the KINGFISH program. We use these two far-infrared lines along with the full suite of KINGFISH panchromatic data to present an improved calibration of the [CII] emission line as a star formation rate indicator.

  17. Identification and multi-filter photometry of HII regions from nearby galaxies with J-PLUS

    NASA Astrophysics Data System (ADS)

    Logroño-García, R.; Vilella-Rojo, G.; López-Sanjuan, C.; Varela, J.; Muniesa, D.; Lamadrid, J. L.; Cenarro, A. J.; J-PLUS, T.

    2017-03-01

    The Javalambre Photometric Local Universe Survey (J-PLUS) has already started the data acquisition phase at the Observatorio Astrofísico de Javalambre (OAJ) in Teruel, Spain. Benefiting from the large field of view (2 deg^2) and the 12 filters set of the T80Cam at the T80/JAST telescope, we aim to study the properties of HII regions in nearby galaxies (z < 0.015). In this poster, we apply our procedures to the galaxy Messier 101. We have developed a fully automatized pipeline to identify and characterize the nearby universe HII regions. This pipeline: (1) Homogenizes the PSF in the 12 images of the different filters. (2) Estimates realistic photometric errors following Labbé et al. (2003) method. (3) Constructs a detection image showing the excess of Hα+[NII], following Vilella-Rojo et al. (2015) prescriptions. (4) Performs the photometry in the 12 J-PLUS bands using as reference the Hα+NII detection image. (5) Constructs the photo-spectra for each identified HII region. We demonstrate the capabilities of this method by comparing synthetic aperture photometry from SDSS spectra with the Hα flux measured with J-PLUS data. Such comparison can be found in the poster by Vilella-Rojo et al. Once the pipeline is implemented, we will generate a catalog of nearby HII regions at z<0.015 in the 8500deg^2 of J-PLUS. With this catalog, we will study the impact of environment in the 2D star formation properties of nearby galaxies, taking advantage of the unprecedented large contiguous area that J-PLUS will offer.

  18. Comparison of cumulative dissipated energy delivered by active-fluidic pressure control phacoemulsification system versus gravity-fluidics.

    PubMed

    Gonzalez-Salinas, Roberto; Garza-Leon, Manuel; Saenz-de-Viteri, Manuel; Solis-S, Juan C; Gulias-Cañizo, Rosario; Quiroz-Mercado, Hugo

    2017-08-22

    To compare the cumulative dissipated energy (CDE), aspiration time and estimated aspiration fluid utilized during phacoemulsification cataract surgery using two phacoemulsification systems . A total of 164 consecutive eyes of 164 patients undergoing cataract surgery, 82 in the active-fluidics group and 82 in the gravity-fluidics group were enrolled in this study. Cataracts graded NII to NIII using LOCS II were included. Each subject was randomly assigned to one of the two platforms with a specific configuration: the active-fluidics Centurion ® phacoemulsification system or the gravity-fluidics Infiniti ® Vision System. CDE, aspiration time (AT) and the mean estimated aspiration fluid (EAF) were registered and compared. A mean age of 68.3 ± 9.8 years was found (range 57-92 years), and no significant difference was evident between both groups. A positive correlation between the CDE values obtained by both platforms was verified (r = 0.271, R 2  = 0.073, P = 0.013). Similarly, a significant correlation was evidenced for the EAF (r = 0.334, R 2  = 0.112, P = 0.046) and AT values (r = 0.156, R 2  = 0.024, P = 0.161). A statistically significantly lower CDE count, aspiration time and estimated fluid were obtained using the active-fluidics configuration when compared to the gravity-fluidics configuration by 19.29, 12.10 and 9.29%, respectively (P = 0.001, P < 0.0001 and P = 0.001). The active-fluidics Centurion ® phacoemulsification system achieved higher surgical efficiency than the gravity-fluidics Infiniti ® IP system for NII and NIII cataracts.

  19. Liquefied Noble Gas (LNG) detectors for detection of nuclear materials

    NASA Astrophysics Data System (ADS)

    Nikkel, J. A.; Gozani, T.; Brown, C.; Kwong, J.; McKinsey, D. N.; Shin, Y.; Kane, S.; Gary, C.; Firestone, M.

    2012-03-01

    Liquefied-noble-gas (LNG) detectors offer, in principle, very good energy resolution for both neutrons and gamma rays, fast response time (hence high-count-rate capabilities), excellent discrimination between neutrons and gamma rays, and scalability to large volumes. They do, however, need cryogenics. LNG detectors in sizes of interest for fissionable material detection in cargo are reaching a certain level of maturity because of the ongoing extensive R&}D effort in high-energy physics regarding their use in the search for dark matter and neutrinoless double beta decay. The unique properties of LNG detectors, especially those using Liquid Argon (LAr) and Liquid Xenon (LXe), call for a study to determine their suitability for Non-Intrusive Inspection (NII) for Special Nuclear Materials (SNM) and possibly for other threats in cargo. Rapiscan Systems Laboratory, Yale University Physics Department, and Adelphi Technology are collaborating in the investigation of the suitability of LAr as a scintillation material for large size inspection systems for air and maritime containers and trucks. This program studies their suitability for NII, determines their potential uses, determines what improvements in performance they offer and recommends changes to their design to further enhance their suitability. An existing 3.1 liter LAr detector (microCLEAN) at Yale University, developed for R&}D on the detection of weakly interacting massive particles (WIMPs) was employed for testing. A larger version of this detector (15 liters), more suitable for the detection of higher energy gamma rays and neutrons is being built for experimental evaluation. Results of measurements and simulations of gamma ray and neutron detection in microCLEAN and a larger detector (326 liter CL38) are presented.

  20. Role of information systems in controlling costs: the electronic medical record (EMR) and the high-performance computing and communications (HPCC) efforts

    NASA Astrophysics Data System (ADS)

    Kun, Luis G.

    1994-12-01

    On October 18, 1991, the IEEE-USA produced an entity statement which endorsed the vital importance of the High Performance Computer and Communications Act of 1991 (HPCC) and called for the rapid implementation of all its elements. Efforts are now underway to develop a Computer Based Patient Record (CBPR), the National Information Infrastructure (NII) as part of the HPCC, and the so-called `Patient Card'. Multiple legislative initiatives which address these and related information technology issues are pending in Congress. Clearly, a national information system will greatly affect the way health care delivery is provided to the United States public. Timely and reliable information represents a critical element in any initiative to reform the health care system as well as to protect and improve the health of every person. Appropriately used, information technologies offer a vital means of improving the quality of patient care, increasing access to universal care and lowering overall costs within a national health care program. Health care reform legislation should reflect increased budgetary support and a legal mandate for the creation of a national health care information system by: (1) constructing a National Information Infrastructure; (2) building a Computer Based Patient Record System; (3) bringing the collective resources of our National Laboratories to bear in developing and implementing the NII and CBPR, as well as a security system with which to safeguard the privacy rights of patients and the physician-patient privilege; and (4) utilizing Government (e.g. DOD, DOE) capabilities (technology and human resources) to maximize resource utilization, create new jobs and accelerate technology transfer to address health care issues.

  1. An NQR Study of TNT Characteristics.

    DTIC Science & Technology

    1977-09-01

    RDX , HMX , a r d some of t he heavy me t al 3~~: id~.s h~~’n for rn.nn ye.~rs been use d as rn~~lit~~ry nii p lns i n’t-~~~~, Thr p h y s i c a l...ambient temperatures of more than one coexisting crystal phase. This polymorphism is known to occur in TNT , HMX and PbN3, and is responsible for a...specific problems of TNT polymorphism and phase transitions were researched . This is one of the problems which is relevant to present day concerns . The

  2. Prime Contract Awards Alphabetically by Contractor, by State or Country, and Place, Fiscal Year 1987. Part 12. Mantech International Corporation-Modular Devices, Incorporated.

    DTIC Science & Technology

    1987-01-01

    VLA00- VN00-.t0CO 00-4 000 -I 00 zo 00:< I-0.O- 4"NNmOOO t rNN 3-4-- 4CioL C) r ol0 00(1 300 0 )NO O <-0 :I Z v f- 0)(m(0( MOLA 0)4 40 ZIiIf0 N _( t- l...V0 < 0) lac .- 4I -4 .. 40) WI)v 4󈧄)Ř 4.--4 0 ~ ~ ~ ~ ~ -O c (00 0)-04-00- . -4 MOLA , C0) m -4 e -41-" .1 LA nII ’III IX (00< I 4 4-f-4 -- 4

  3. Fundamental Studies on MPD Thrusters.

    DTIC Science & Technology

    1987-09-02

    WSCLASSIFIED WMS-93-0633 F/0s 21/3 ML L4 0 ’i JJJJJQ252 / .3 NII1~~ 33 fjffJ~* e 3- 11111 111 v 11 qP v lP IP qP P IP IP8 UNCLASSIFIED FlC ILE COPy AD-A 190...DATE OF REPORT (YtadI Month Day) IS. PAGE. COUNTN ’Final Scientific Report -62~r .𔄂To e .,861 1987- Sept. 2 259 16SUPPLEMENTARY NOTATION 4% COSAII...two earlier annual progress reports, summarizes . progress made under grant AFOSR-83-0033. %S 20 UiST1MIBUTIONIAVAILABILITY Of ABSTRACT 21. ASTRAW ~~ e

  4. Reforming the Joint Chiefs of Staff.

    DTIC Science & Technology

    1983-08-01

    i . 1. 1 e, * vJ. r ŗi. - .- F-S.., Ar;:it:d ’t i . i . A i r For -::. r ic c.r .m’, I 蟙 a...understandi rig of Lhe Is i ev c:i. tt i on c-f u?e i r -. i t L jon,, Wi thoh U t he benef it of a hi t:or i c.- 1 n-Ii :z I s, there i s a tendency...by criticez- of t. he JCS L i gl IDre t s or i . gi i al purpose& and 1 i mi tat i ons. e r

  5. New Methods for the Detection and Interception of Frequency-Hopped Waveforms

    DTIC Science & Technology

    1990-11-01

    that £[p2 Q2 /O] = uF + 2 + o(cos 0 + 6 sin9)2 + 4n(acos0+/3sin)(7ycos0+6sinO)+o r(acos0+sinO)2 I + ( acosO +/3sinO) 2(Tcos9+ 6sin O)2 (3.134) i which...Jcins I lopk ins lI mvtrsi! t3 A pplied Physics Laborator Before1 NII After Figure 4.4: Deconvolut ion Applivod to Oi-fFci i r 100 The Johns 11opkins...Arlington, VA 20360 Library 2 Naval Postgraduate School Monterey, CA 92940 Library 2 Naval Research Laborator . Washington, DC 20375 Library 2 J. W

  6. All Prime Contract Awards by State or Country, Place, and Contractor, FY 85. Part 14 (Aberdeen, North Carolina - Zanesville, Ohio).

    DTIC Science & Technology

    1985-01-01

    I nr)MC)C) MeM V r I McI ( MV)CI MMCI C I)MC I) (( 4 N) l 1 MC)c) l< 43 I004COOOOOOOOOO)OOOOOOOOO 000 - -0 I WW C’J(WJ W’J(N C𔃾CNIC’IC’J ww C’.IC’IC’J...N)( OhP .0.( 0 <It (n0ON(0a)t- " -. I-boO( 444~~o N- WZ0n((P0~ r.-I (0 0.4 W LP n aN ODNCj)-la)In 014 NII-0000000000000000000 0 LaJo 040000 W0 4000000

  7. Electrocatalytic reduction of CO2 with CCC-NHC pincer nickel complexes.

    PubMed

    Cope, James D; Liyanage, Nalaka P; Kelley, Paul J; Denny, Jason A; Valente, Edward J; Webster, Charles Edwin; Delcamp, Jared H; Hollis, T Keith

    2017-08-22

    A CCC-NHC pincer Ni(ii)Cl complex was prepared according to the metallation/transmetallation methodology. It was fully characterized by electrochemical, NMR spectroscopic, theoretical, and X-ray crystallographic methods. The complex and its cation were evaluated for electrocatalytic reduction of CO 2 under a variety of conditions and found to provide some of the fastest catalytic rates and highest substrate selectivities (CO 2 vs. H + ) reported. Rates improved in the presence of water and, significantly, catalysis occurred at the first reduction potential, presumably at the Ni(i) state. Controlled potential electrolysis (CPE) was found to yield CO at 34% and formate at 47% Faradaic efficiency (FE).

  8. VizieR Online Data Catalog: Spectroscopy and HST imaging in ONC (O'Dell+, 2015)

    NASA Astrophysics Data System (ADS)

    O'Dell, C. R.; Ferland, G. J.; Henney, W. J.; Peimbert, M.; Garcia-Diaz, Ma. T.; Rubin, R. H.

    2016-02-01

    We are able to draw on both new and existing observational data for both imaging and spectroscopy. Since the ionization range of the Orion Nebula is quite low, we use the high signal-to-noise ratio (S/N) F658N and F502N images in our analysis Our new imaging observations were made with Hubble Space Telescope (HST)'s WFC3 as part of program GO 12543. Observations were made (2012 January 7) with the narrowband emission line filters F487N (Hβ409s), F502N ([OIII]348s), F656N (Hα349s), F658N ([NII]602s), and F673N ([SII]700s), in addition to observations with the continuum sampling intermediate-width filter F547M (348s). The characteristics of these filters and their calibration have been described by O'Dell et al. (2013AJ....145...92O). The images are the highest angular resolution (0.04''/pixel sampling) optical images of a portion of the Huygens Region. When used alone, we employed the original images in combination with one another. When used for comparison with earlier (undersampled) WFPC2 images (0.0996''/pixel), we processed them with IRAF task "Gauss" to match their broader image cores. We have been able to use earlier HST observations made with the WFPC2 (program GO 5085 (FOV5) on MJD49737; program GO 5469 on MJD49797; program GO 11038 (FOV1) on MJD54406; program GO 12543 on MJD55935). The most useful data set of spectra is the compilation of north-south orientation long-slit spectra by Garcia-Diaz et al. (2008RMxAA..44..181G). In addition to their original observations (Garcia-Diaz & Henney, 2007AJ....133..952G) in low-ionization lines, they recalibrate the high-ionization spectra of Doi et al. 2004 (cat. J/AJ/127/3456) and present combined results for emission lines from a wide variety of ionization states ([OI]630.0nm, [SII]671.6nm+673.1nm, [NII]658.4nm, [SIII]631.2nm, Hα656.3nm, [OIII]500.7nm) calibrated to 2km/s accuracy and a resolution of about 10km/s. We will refer to this as the Spectroscopic Atlas, or simply the Atlas. New observations were made at

  9. VizieR Online Data Catalog: [NII]/Hα ratio in galaxies with KMOS3D (Wuyts+,

    NASA Astrophysics Data System (ADS)

    Wuyts, E.; Wisnioski, E.; Fossati, M.; Forster Schreiber, N. M.; Genzel, R.; Davies, R.; Mendel, J. T.; Naab, T.; Rottgers, B.; Wilman, D. J.; Wuyts, S.; Bandara, K.; Beifiori, A.; Belli, S.; Bender, R.; Brammer, G. B.; Burkert, A.; Chan, J.; Galametz, A.; Kulkarni, S. K.; Lang, P.; Lutz, D.; Momcheva, I. G.; Nelson, E. J.; Rosario, D.; Saglia, R. P.; Seitz, S.; Tacconi, L. J.; Tadaki, K.-I.; Ubler, H.; van Dokkum, P.

    2016-11-01

    The galaxies analyzed here are taken from the first 2yr of the KMOS3D survey, which covers observations up to 2015 April. The survey is described in detail by Wisnioski+ (2015ApJ...799..209W). KMOS3D is a 5yr GTO survey with the multi-object near-IR integral field spectrograph KMOS at the Very Large Telescope (VLT). (1 data file).

  10. VizieR Online Data Catalog: CO, [CI] and [NII] lines from Herschel spectra (Kamenetzky+, 2016)

    NASA Astrophysics Data System (ADS)

    Kamenetzky, J.; Rangwala, N.; Glenn, J.; Maloney, P. R.; Conley, A.

    2016-11-01

    We compiled a list of successful extragalactic Herschel/SPIRE FTS proposals (301 spectra) and searched the Herschel Science Archive (HSA) for the available data. Table 1 lists the basic galaxy information and observation IDs for all galaxies for which at least one FTS line measurement or upper limit is reported. The bandpass of the Herschel FTS starts around the CO J=4-3 line, but the majority of the molecular mass in galaxies is cool and populates the lower rotational levels. We complement the line fluxes derived from the FTS with the CO J=1-0, J=2-1, and J=3-2 lines available from ground-based observatories. Many of these galaxies have already been studied in the literature, particularly in large CO surveys. For some galaxies, we also performed single-dish measurements using the Arizona Radio Observatory (ARO). Measurements of the CO J=1-0 line were conducted with the 12m dish on Kitt Peak in 2015 May, and those of CO J=2-1 and J=3-2 were conducted with the Submillimeter Telescope (SMT) located on Mt. Graham from 2014 November to 2015 February. (4 data files).

  11. VizieR Online Data Catalog: Hα and [NII] survey in local 11 Mpc (Kennicutt+, 2008)

    NASA Astrophysics Data System (ADS)

    Kennicutt, R. C. Jr; Lee, J. C.; Funes, J. G.; Sakai, S.; Akiyama, S.

    2009-11-01

    Most of the Hα and R imaging reported in this paper was obtained in 2001-2004 using CCD direct imagers on the Steward Observatory Bok 2.3m telescope on Kitt Peak (Bok), the Lennon 1.8m Vatican Advanced Technology Telescope (VATT), and the 0.9m telescope at Cerro Tololo Interamerican Observatory (CTIO). (3 data files).

  12. 78 FR 37499 - Unlicensed National Information Infrastructure (U-NII) Devices in the 5 GHz Band

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-06-21

    ... comments by the current deadline. On June 6, 2013, the Wi-Fi Alliance also requested a 30 day extension of... proceeding. The Wi-Fi Alliance points out that the current reply comment filing deadline falls before both the 2013 Wi-Fi Alliance Member Meeting and IEEE 802's Plenary Session, and that the parties' reply...

  13. Prime Contract Awards Alphabetically by Contractor, by State or Country, and Place. Part 2 (Allied Supply Co Inc-Ashley Machine & Tool Co)

    DTIC Science & Technology

    1990-01-01

    I M1.-NII 0i0 0 0Q 00 0 0000000 0 UrO I 00..4N0 it 0> 00 0> 0> 00DC 4 > 0a(0 0 000000000 0 U 0)-4N KfC 0 00 0 00C 00 00000000 00 000 0 a m -4N0 C1 M...0 IN In 1 1( II< 00 o0 oCUo)_ In Infin nIn 00Co00> 0 Olin in CL if - I Cow< I CI0) 0CC 00 4n R ’D 0 NI N N oIn In inin in 0> -4r-- cn WIf 0 1C o i

  14. Prime Contract Awards Over $25,000 by Major System, Contractor and State. Part 2. (BSH-SMR)

    DTIC Science & Technology

    1989-01-01

    tI CI 4) 0 w- - 4~4 C -*. nowO )-4o -040 0 OL*l (M m 100m-1-1v-qmm 00L -t(M- 04-X 4nII W- --4Ww .nw -. 4-.M -- 4WC W-4LA -4 0QW U C W 40Ř 0-* W...L AL 0 0. J 2W -4~ 00 00L37 00 00 0U 00: 0v a0 0 04 0A < ) - 347 =N- -440 C’ ) .rN- . )-4 ~4 -4l C) M - 0 0(I) -IL.I0 Lb f 0UC0 C’ 03 U7-t0U -4N U

  15. VizieR Online Data Catalog: FIR spectra of AGNs from Herschel (Fernandez-Ontiveros+, 2016)

    NASA Astrophysics Data System (ADS)

    Fernandez-Ontiveros, J. A.; Spinoglio, L.; Pereira-Santaella, M.; Malkan, M. A.; Andreani, P.; Dasyra, K. M.

    2016-11-01

    The combination of Herschel/PACS during its 3.5yr of operational life and Spitzer/IRS allows us to cover the fine-structure emission lines from the mid- to the far-IR (10-200um in the rest-frame) for all the galaxies in the sample. This database was completed with the Herschel/SPIRE published values of the [NII]205um, and [CI]371,609um line fluxes (mainly from Kamenetzky+ 2016ApJ...829...93K). Table 8 collects published mid-IR (10-35um) fine-structure line fluxes measured with Spitzer/IRS for our samples of AGN and starburst galaxies. These values were complemented with unpublished IRS observations from the Spitzer archive. (10 data files).

  16. Qualitative spectroscopic study of magnetic nozzle flow

    NASA Technical Reports Server (NTRS)

    Umeki, T.; Turchi, P. J.

    1992-01-01

    The physics of the magnetic nozzle flow for a 100-kW-level quasi-steady MPD thruster was studied by photographic spectroscopy focusing on the plasma model in the flow and the acceleration mechanism. Spectroscopic visualization for the flow-species analysis indicates that the plasma-exhaust flow dominated by NII species were confined by the magnetic nozzle effect to collimate the flow for the better thruster performance. Inside the nozzle, the plasma flow was found to be in nonhomogeneous collisional-radiative condition. There appears to be a substantial flow acceleration from the magnetic nozzle inlet to the outlet with slight expansion. This suggests that the flow resembles that of constant area supersonic duct flow with cooling.

  17. An Interactive Computer Package for Use with Simulation Models Which Performs Multidimensional Sensitivity Analysis by Employing the Techniques of Response Surface Methodology.

    DTIC Science & Technology

    1984-12-01

    total sum of squares at the center points minus the correction factor for the mean at the center points ( SSpe =Y’Y-nlY), where n1 is the number of...SSlac=SSres- SSpe ). The sum of squares due to pure error estimates 0" and the sum of squares due to lack-of-fit estimates 0’" plus a bias term if...Response Surface Methodology Source d.f. SS MS Regression n b’X1 Y b’XVY/n Residual rn-n Y’Y-b’X’ *Y (Y’Y-b’X’Y)/(n-n) Pure Error ni-i Y’Y-nl1Y SSpe / (ni

  18. VizieR Online Data Catalog: M31 center emission-line point-like sources (Martin+, 2018)

    NASA Astrophysics Data System (ADS)

    Martin, T. B.; Drissen, L.; Melchior, A.-L.

    2017-11-01

    We present a catalogue of the point-like sources in the central 11'x11' part of M31 obtained with SITELLE. For each source we report the radial velocity as long as the spectrophotmetric flux of H-alpha, [NII]6584 and the sum of the [SII]6717,6731 doublet. The ID of the sources cross-matched with the catalogues from Merrett et al. (2006MNRAS.369..120M, J/MNRAS/369/120) and Halliday et al. (2006MNRAS.369...97H, J/MNRAS/369/97) are also indicated. We also report the detection of the sources in the images of the Local Group Galaxies Survey (Massey et al., 2006, 2006AJ....131.2478M). (1 data file).

  19. High Frequency Active Auroral Research Program (HAARP) Imager

    DTIC Science & Technology

    1993-09-30

    T-3 HCTL!; *WR-EN HCTL@ F- 3 HC7L! ; * HACK H(TL-@ F-4 HCTL!; ]NIiT-HOST 00 HB! F8 HCrL!; DSP-RESET INIT-HOST HCTL@ DUP F-6 HCTh! T-6 HCTU! DSP-IRQB...CONSTANTPS2 PI_HI P2-11 OR 3_-1O OR TG..LO OR CONSTANT PS3 P1I.,O P2_.i OR P3..LO OR TG_.LO OR CONSTANT PS4 PlLO P21-1I OR P3_H1 OR TGIIl OR CONSTANTPS5 P1_LO...CONSTANT PSTATEI PS2 SER-IDLE OR CONSTANT PSTATE2 PS3 SERIDLE OR CONSTANT PSTATE3 PS4 SERIDLE OR CONSTANT PSTATE4 PS5 SERIDLE OR CONSTANT PSTATES PS6

  20. Biochemistry of methyl-coenzyme M reductase: the nickel metalloenzyme that catalyzes the final step in synthesis and the first step in anaerobic oxidation of the greenhouse gas methane.

    PubMed

    Ragsdale, Stephen W

    2014-01-01

    Methane, the major component of natural gas, has been in use in human civilization since ancient times as a source of fuel and light. Methanogens are responsible for synthesis of most of the methane found on Earth. The enzyme responsible for catalyzing the chemical step of methanogenesis is methyl-coenzyme M reductase (MCR), a nickel enzyme that contains a tetrapyrrole cofactor called coenzyme F430, which can traverse the Ni(I), (II), and (III) oxidation states. MCR and methanogens are also involved in anaerobic methane oxidation. This review describes structural, kinetic, and computational studies aimed at elucidating the mechanism of MCR. Such studies are expected to impact the many ramifications of methane in our society and environment, including energy production and greenhouse gas warming.

  1. Evolution of In-Situ Generated Reinforcement Precipitates in Metal Matrix Composites

    NASA Technical Reports Server (NTRS)

    Sen, S.; Kar, S. K.; Catalina, A. V.; Stefanescu, D. M.; Dhindaw, B. K.

    2004-01-01

    Due to certain inherent advantages, in-situ production of Metal Matrix Composites (MMCs) have received considerable attention in the recent past. ln-situ techniques typically involve a chemical reaction that results in precipitation of a ceramic reinforcement phase. The size and spatial distribution of these precipitates ultimately determine the mechanical properties of these MMCs. In this paper we will investigate the validity of using classical growth laws and analytical expressions to describe the interaction between a precipitate and a solid-liquid interface (SLI) to predict the size and spatial evolution of the in-situ generated precipitates. Measurements made on size and distribution of Tic precipitates in a Ni&I matrix will be presented to test the validity of such an approach.

  2. On-Board Switching and Routing Advanced Technology Study

    NASA Technical Reports Server (NTRS)

    Yegenoglu, F.; Inukai, T.; Kaplan, T.; Redman, W.; Mitchell, C.

    1998-01-01

    Future satellite communications is expected to be fully integrated into National and Global Information Infrastructures (NII/GII). These infrastructures will carry multi gigabit-per-second data rates, with integral switching and routing of constituent data elements. The satellite portion of these infrastructures must, therefore, be more than pipes through the sky. The satellite portion will also be required to perform very high speed routing and switching of these data elements to enable efficient broad area coverage to many home and corporate users. The technology to achieve the on-board switching and routing must be selected and developed specifically for satellite application within the next few years. This report presents evaluation of potential technologies for on-board switching and routing applications.

  3. Evaluation of the Impact of Towing DC-9 Transport Airplanes at Boston-Logan Airport.

    DTIC Science & Technology

    1980-05-01

    42- 22’ 71’ 02’ 12 1617 [t6 -96 F6p olt ln, slotr ADHA ,- r ’ C is on 11 f / 1 -3 . P o s.Nt Ofic /29/3 / 06/64 70 0 ftj. SE 42- 21’ 71’ W1 20 360 337 336...34A-A8 $64 DOUGLAS AIRCRAFT CO LONG BEACH CA PIG/ 1 /2 GG EVALUATION OF THE IMPACT OF TOWING DC-9 TRANSPORT AIRPLANES AT -ETC(U) MAY G0 E A HOOVER DOT...a -ib’f t0 tie U S. pubic through the Nat onj T, r ,ca, h -nrrmatior Ser\\ice, St 1 ’ o c: a q~nii 22161 - - ,.......~ - r’) C 2 TAINKD A ,4

  4. Atmospheric Transmittance from 0.25 to 28.5 Microns: Computer Code LOWTRAN 3

    DTIC Science & Technology

    1975-05-07

    thait worKe’S whIo arc iirca~i) risinig I.A M’ Il V\\ 2 c~in ilwl(ite thir ciu -rd dvciks- ,Aith i nii~wimun of effort. \\ll rh ’,n ; and diir<to the lIt...specified on CARD I. The appropriate meteorological parameters and format for thr atmospheric data are given below. Z, P. T. DP. RH . WHL WO, AHAZE [FORMAT...M.GTOIREA!) 4Z9,ZfKJP(?,K),TM?,)P, RH ,HH(7.KI ,NO(1,KIANAZý (KI A &2,3E .JTIF!W(Z(K) b1.0E-6)#1. A 1:0sF IV(M.EQ.0) UK)=mil A U𔃽G IF(7(KI .GF..35.0I Jr(Z

  5. Heterodyne Arrays for Terahertz/Sub-millimeter Astronomy

    NASA Astrophysics Data System (ADS)

    Kloosterman, Jenna; Walker, C. K.; SORAL; SRON; TU-Delft; JPL; APL; ASU; MIT

    2014-01-01

    The clouds of gas and dust that constitute the Interstellar Medium (ISM) within the Milky Way and other galaxies can be studied through the emission from atoms and molecules such as CO, [CI], [CII], [NII], and [OI]. Spectroscopic surveys of these tracers are necessary to disentangle large-scale structure and kinematics within the ISM. Each of these tracers has transitions in the Terahertz (THz) region of the electromagnetic spectrum, loosely defined as 0.3 - 3 THz, thus creating a need for large format THz heterodyne arrays. My dissertation research in radio instrumentation has focused on three main projects. The first, the Superheterodyne Camera (SuperCam), is a ground-based instrument for the Sub-millimeter Telescope (SMT) on Mt. Graham, Arizona. The receiver contains 64 heterodyne pixels designed to detect the J=3-2 rotational line of CO at 345 GHz. SuperCam had its first engineering run in Spring 2012 and its commissioning run in Spring 2013. The second project, the Stratospheric Terahertz Observatory (STO), is a balloon-borne, 0.8 m telescope, designed to observe the fine structure lines of [NII] and [CII] at 1.46 and 1.9 THz from an altitude of ~120,000 ft. STO had its first flight around Antarctica in January 2012 and is scheduled to have a second flight (as STO-2) in 2015. The last project is the building of a 4.74 THz heterodyne receiver to look for the fine structure line of the high density tracer [OI]. With an 815 K double sideband noise temperature (e.g. ~7 times the quantum noise limit), this is the most sensitive heterodyne receiver reported above 3 THz. It will be flown on STO-2 and was developed as part of the Galactic/extra-galactic Ultra-Long Duration Stratospheric Spectroscopic THz Observatory (GUSSTO) concept study. This dissertation talk will briefly cover the results of these instrumentation efforts and the science that drives them.

  6. New Perspectives on the Dynamical State of Extraplanar Diffuse Ionized Gas Layers

    NASA Astrophysics Data System (ADS)

    Boettcher, Erin; Zweibel, Ellen; Gallagher, John S.; Benjamin, Robert A.

    2018-01-01

    Gaseous, disk-halo interfaces are an important boundary in the baryon cycle in galaxies like the Milky Way, and their structure, support, and kinematics carry clues about the star formation feedback and accretion processes that produce them. Due to their unexpectedly large scale heights, which are often several times greater than their thermal scale heights, it is unclear whether they are in dynamical equilibrium, or are evidence of a galactic fountain, wind, or accretion flow. In the nearby, edge-on disk galaxies NGC 891 and NGC 5775, we test a dynamical equilibrium model of the extraplanar diffuse ionized gas (eDIG) layer by quantifying the thermal, turbulent, magnetic field, and cosmic ray pressure gradients using optical emission-line spectroscopy from the SparsePak IFU at the WIYN Observatory and the Robert Stobie Spectrograph on the Southern African Large Telescope and radio continuum observations from Continuum Halos in Nearby Galaxies - an EVLA Survey. The vertical pressure gradients are too shallow to produce the observed scale heights at the moderate galactocentric radii where the gas is believed to be found (R < 8 kpc). For the low-inclination galaxy M83, we develop a Markov Chain Monte Carlo method to decompose the [NII]λλ6548, 6583, Hα, and [SII]λλ6717, 6731 emission lines into multiple components, and identify eDIG emission based on its rotational velocity lag and elevated [NII]/Hα and [SII]/Hα line ratios. The median, line-of-sight velocity dispersion of the eDIG layer, σ = 96 km/s, greatly exceeds the horizontal velocity dispersions observed in edge-on eDIG layers (σ = 20 - 60 km/s), presenting the possibility that these layers have anisotropic random motions. The role of an anisotropic velocity dispersion in producing eDIG scale heights, as well as the absence of evidence for large-scale inflow or outflow, motivates further study of eDIG dynamics in face-on galaxies with a range of star formation rates. This work was supported by the NSF

  7. Tertiary structural changes and iron release from human serum transferrin.

    PubMed

    Mecklenburg, S L; Donohoe, R J; Olah, G A

    1997-08-01

    Iron release from human serum transferrin was investigated by comparison of the extent of bound iron, measured by charge transfer absorption band intensity (465 nm), with changes observed by small-angle solution X-ray scattering (SAXS) for a series of equilibrated samples between pH 5.69 and 7.77. The phosphate buffers used in this study promote iron release at relatively high pH values, with an empirical pK of 6.9 for the convolved release from the two sites. The spectral data reveal that the N-lobe release is nearly complete by pH 7.0, while the C-lobe remains primarily metal-laden. Conversely, the radius of gyration, Rg, determined from the SAXS data remains constant between pH 7.77 and 7.05, and the evolution of Rg between its value observed for the diferric protein at pH 7.77 (31.2+/-0.2 A) and that of the apo protein at pH 5.69 (33.9+/-0.4 A) exhibits an empirical pK of 6.6. While Rg is effectively constant in the pH range associated with iron release from the N-lobe, the radius of gyration of cross-section, Rc, increases from 16.9+/-0.2 A to 17.6+/-0.2 A. Model simulations suggest that two different rotations of the NII domain relative to the NI domain about a hinge deep in the iron-binding cleft of the N-lobe, one parallel with and one perpendicular to the plane of the iron-binding site, can be significantly advanced relative to their holo protein positions while yielding constant Rg and increased Rc values consistent with the scattering data. Rotation of the CII domain parallel with the C-lobe iron-binding site plane can partially account for the increased Rg values measured at low pH; however, no reasonable combined repositioning of the NII and CII domains yields the experimentally observed increase in Rg.

  8. Non-invasive pneumococcal serotypes and antimicrobial susceptibilities in a paediatric hospital in the era of conjugate vaccines.

    PubMed

    McElligott, Martha; Vickers, Imelda; Cafferkey, Mary; Cunney, Robert; Humphreys, Hilary

    2014-06-12

    To evaluate the effects of 7-valent pneumococcal conjugate vaccine (PCV7) introduction to the routine childhood immunisation schedule in 2008 and its replacement by PCV13 in 2010 in Ireland, we surveyed the serotypes and antimicrobial susceptibilities of 339 pneumococci associated with carriage and non-invasive infection (NII) in a Dublin paediatric hospital from 2009 to 2012. Furthermore, we compared the distribution of pneumococcal serotypes collected from 2009 to 2012 to 105 NII pneumococci isolated in 2007, the year before conjugate vaccine introduction. PCV7 serotypes declined from 2007 to 2012 as follows: carriage, 67-23% (p=0.0004); conjunctivitis, 58-0% (p<0.0001); non-bacteraemic lower respiratory tract infection, 50-19% (p=0.0363) and otitis media 54-27%. Notably, antimicrobial resistant (AMR) PCV7 serotypes showed a significant decrease by the end of the study period (i.e. 2012) (p<0.0001). Compared with 2007 the overall occurrence of serotype 19A increased from 1.9 to 10% in 2010 (p=0.0132) and to 15% in 2011 (p=0.0005). Importantly, serotype 19A declined significantly from 2011 levels to an overall prevalence of 4.8% in 2012 (p=0.0243). Most striking was the significant reduction of AMR 19A (p=0.0195). Conversely, increases were observed in non-vaccine type (NVT) pneumococci in 2009-2012, of which serotypes 11A (n=30), 15B/C (n=17), 22F (n=14), 35Bn=13), non-typeable pneumococci (n=13) and 23A (n=12) were the most prevalent. Moreover, an increase in NVT non-susceptible to at least one antimicrobial in 2009-2012 was noted, attributable to serotypes 35B (n=10) and 15A (n=7). In summary, this study has shown that PCV7 and PCV13 introduction has had a positive impact on their target serotypes and antimicrobial resistance amongst pneumococci within a paediatric hospital within a short time period. However, the increase in NVT prevalence highlights the need for continued surveillance. Copyright © 2014 Elsevier Ltd. All rights reserved.

  9. THE IONIZED GAS IN NEARBY GALAXIES AS TRACED BY THE [NII] 122 AND 205 μm TRANSITIONS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Herrera-Camus, R.; Bolatto, A.; Wolfire, M.

    2016-08-01

    The [N ii] 122 and 205 μ m transitions are powerful tracers of the ionized gas in the interstellar medium. By combining data from 21 galaxies selected from the Herschel KINGFISH and Beyond the Peak surveys, we have compiled 141 spatially resolved regions with a typical size of ∼1 kpc, with observations of both [N ii] far-infrared lines. We measure [N ii] 122/205 line ratios in the ∼0.6–6 range, which corresponds to electron gas densities of n {sub e} ∼ 1–300 cm{sup −3}, with a median value of n {sub e} = 30 cm{sup −3}. Variations in the electron densitymore » within individual galaxies can be as high as a factor of ∼50, frequently with strong radial gradients. We find that n {sub e} increases as a function of infrared color, dust-weighted mean starlight intensity, and star-formation rate (SFR) surface density (Σ{sub SFR}). As the intensity of the [N ii] transitions is related to the ionizing photon flux, we investigate their reliability as tracers of the SFR. We derive relations between the [N ii] emission and SFR in the low-density limit and in the case of a log-normal distribution of densities. The scatter in the correlation between [N ii] surface brightness and Σ{sub SFR} can be understood as a property of the n {sub e} distribution. For regions with n {sub e} close to or higher than the [N ii] line critical densities, the low-density limit [N ii]-based SFR calibration systematically underestimates the SFR because the [N ii] emission is collisionally quenched. Finally, we investigate the relation between [N ii] emission, SFR, and n {sub e} by comparing our observations to predictions from the MAPPINGS-III code.« less

  10. Information Infrastructure Technology and Applications (IITA) Program: Annual K-12 Workshop

    NASA Technical Reports Server (NTRS)

    Hunter, Paul; Likens, William; Leon, Mark

    1995-01-01

    The purpose of the K-12 workshop is to stimulate a cross pollination of inter-center activity and introduce the regional centers to curing edge K-1 activities. The format of the workshop consists of project presentations, working groups, and working group reports, all contained in a three day period. The agenda is aggressive and demanding. The K-12 Education Project is a multi-center activity managed by the Information Infrastructure Technology and Applications (IITA)/K-12 Project Office at the NASA Ames Research Center (ARC). this workshop is conducted in support of executing the K-12 Education element of the IITA Project The IITA/K-12 Project funds activities that use the National Information Infrastructure (NII) (e.g., the Internet) to foster reform and restructuring in mathematics, science, computing, engineering, and technical education.

  11. VizieR Online Data Catalog: Warm ISM in the Sagittarius A Complex (Garcia+, 2016)

    NASA Astrophysics Data System (ADS)

    Garcia, P.; Simon, R.; Stutzki, J.; Gusten, R.; Requena-Torres, M. A.; Higgins, R.

    2016-03-01

    Files contain the observations of CI 1-0 and CI 2-1, NII 1-0, and CII 3/2-1/2 observed with Herschel-HIFI and 12CO 4-3 observed with NANTEN2/SMART telescope of the SgrA Complex in the GC. The data analysis was done via GILDAS-CLASS, where raw data are processed to obtain regularly sampled data. ************************* IMPORTANT NOTE ************************ These data sets will be blocked until 31.12.16 as agreed on with the A&A Editor. Access to channel maps of all observed transitions is immediately available in electronic format in the link provided in the paper, https://www.astro.uni-koeln.de/online-data/GarciaPSgrA_AA588/. For contact information refer to Dr. Pablo Garcia e-mail: pgarcia@iram.es ******************************************************************* (1 data file).

  12. Dust and ionized gas in active radio elliptical galaxies

    NASA Technical Reports Server (NTRS)

    Forbes, D. A.; Sparks, W. B.; Macchetto, F. D.

    1990-01-01

    The authors present broad and narrow bandwidth imaging of three southern elliptical galaxies which have flat-spectrum active radio cores (NGC 1052, IC 1459 and NGC 6958). All three contain dust and extended low excitation optical line emission, particularly extensive in the case of NGC 1052 which has a large H alpha + (NII) luminosity. Both NGC 1052 and IC 1459 have a spiral morphology in emission-line images. All three display independent strong evidence that a merger or infall event has recently occurred, i.e., extensive and infalling HI gas in NGC 1052, a counter-rotating core in IC 1459 and Malin-Carter shells in NGC 6958. This infall event is the most likely origin for the emission-line gas and dust, and the authors are currently investigating possible excitation mechanisms (Sparks et al. 1990).

  13. VizieR Online Data Catalog: SFR & AGN in most luminous local universe LINERs (Povic+, 2016)

    NASA Astrophysics Data System (ADS)

    Povic, M.; Marquez, I.; Netzer, H.; Masegosa, J.; Nordon, R.; Perez, E.; Schoenell, W.

    2018-02-01

    The sources were initially selected from the SDSS/DR4 (Kauffmann et al., 2003MNRAS.341...33K; Brinchmann et al., 2004MNRAS.351.1151B) catalogue in Garching MPA-JHU based on the SDSS (http://www.sdss.org/) DR4 data (Adelman-McCarthy et al. (2006ApJS..162...38A, Cat. II/267), and references therein). LINERs were first selected using both [NII]6584/Hα and [OI]6300/Hα criteria of Kewley et al. (2006MNRAS.372..961K). Taking into account the completeness of the SDSS survey, only LINERs with 0.042.5Å (Cid-Fernandes et al., 2011MNRAS.413.1687C). (8 data files).

  14. The Hawaii Imaging Fabry-Perot Interferometer (HIFI)

    NASA Technical Reports Server (NTRS)

    Bland, Jonathan; Cecil, Gerald; Tully, Brent

    1990-01-01

    At Mauna Kea Observatory, researchers conducted optical, imaging spectrophotometric studies of selected active galaxies using both the Canada-France-Hawaii 3.6m and University of Hawaii 2.2m telecopes (Tully, Bland and Cecil 1988). To maximize spatial resolution, researchers select galaxies independent of luminosity but known to possess interesting morphologies or high-velocity, extranuclear ionized gas (Walker 1968; Rubin and Ford 1968). They study both the large-scale patterns produced in IR-luminous, starburst systems (e.g., M82, NGC 253, NGC 6240) and those with compact, but spatially extended, circumnuclear, narrow line regions (e.g., M51, NGC 1068, NGC 4151). Current studies are restricted to the optical (SII), (NII) and (OIII) lines and the brightest Balmer recombination lines. These lines are, in principle, sufficient to constrain the dynamical structure and dominant excitation mechanism of the ionized component.

  15. National Coordinating Committee for Technology in Education and Training (NCC-TET) Requirements for the National Information Infrastructure (NII).

    ERIC Educational Resources Information Center

    Yrchik, John; Cradler, John

    1994-01-01

    Discusses guidelines that were developed to ensure that the National Information Infrastructure provides expanded opportunities for education and training. Topics include access requirements for homes and work places as well as schools; education and training application requirements, including coordination by federal departments and agencies; and…

  16. Alleviation of Nitrogen and Sulfur Deficiency and Enhancement of Photosynthesis in Arabidopsis thaliana by Overexpression of Uroporphyrinogen III Methyltransferase (UPM1)

    PubMed Central

    Garai, Sampurna; Tripathy, Baishnab C.

    2018-01-01

    Siroheme, an iron-containing tetrapyrrole, is the prosthetic group of nitrite reductase (NiR) and sulfite reductase (SiR); it is synthesized from uroporphyrinogen III, an intermediate of chlorophyll biosynthesis, and is required for nitrogen (N) and sulfur (S) assimilation. Further, uroporphyrinogen III methyltransferase (UPM1), responsible for two methylation reactions to form dihydrosirohydrochlorin, diverts uroporphyrinogen III from the chlorophyll biosynthesis pathway toward siroheme synthesis. AtUPM1 [At5g40850] was used to produce both sense and antisense plants of Arabidopsis thaliana in order to modulate siroheme biosynthesis. In our experiments, overexpression of AtUPM1 signaled higher NiR (NII) and SiR gene and gene product expression. Increased NII expression was found to regulate and enhance the transcript and protein abundance of nitrate reductase (NR). We suggest that elevated NiR, NR, and SiR expression must have contributed to the increased synthesis of S containing amino acids in AtUPM1overexpressors, observed in our studies. We note that due to higher N and S assimilation in these plants, total protein content had increased in these plants. Consequently, chlorophyll biosynthesis increased in these sense plants. Higher chlorophyll and protein content of plants upregulated photosynthetic electron transport and carbon assimilation in the sense plants. Further, we have observed increased plant biomass in these plants, and this must have been due to increased N, S, and C assimilation. On the other hand, in the antisense plants, the transcript abundance, and protein content of NiR, and SiR was shown to decrease, resulting in reduced total protein and chlorophyll content. This led to a decrease in photosynthetic electron transport rate, carbon assimilation and plant biomass in these antisense plants. Under nitrogen or sulfur starvation conditions, the overexpressors had higher protein content and photosynthetic electron transport rate than the wild type

  17. pH-dependent reduction potentials and proton-coupled electron transfer mechanisms in hydrogen-producing nickel molecular electrocatalysts.

    PubMed

    Horvath, Samantha; Fernandez, Laura E; Appel, Aaron M; Hammes-Schiffer, Sharon

    2013-04-01

    The nickel-based P2(Ph)N2(Bn) electrocatalysts comprised of a nickel atom and two 1,5-dibenzyl-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane ligands catalyze H2 production in acetonitrile. Recent electrochemical experiments revealed a linear dependence of the Ni(II/I) reduction potential on pH with a slope of 57 mV/pH unit, implicating a proton-coupled electron transfer (PCET) process with the same number of electrons and protons transferred. The combined theoretical and experimental studies herein provide an explanation for this pH dependence in the context of the overall proposed catalytic mechanism. In the proposed mechanisms, the catalytic cycle begins with a series of intermolecular proton transfers from an acid to the pendant amine ligand and electrochemical electron transfers to the nickel center to produce the doubly protonated Ni(0) species, a precursor to H2 evolution. The calculated Ni(II/I) reduction potentials of the doubly protonated species are in excellent agreement with the experimentally observed reduction potential in the presence of strong acid, suggesting that the catalytically active species leading to the peak observed in these cyclic voltammetry (CV) experiments is doubly protonated. The Ni(I/0) reduction potential was found to be slightly more positive than the Ni(II/I) reduction potential, indicating that the Ni(I/0) reduction occurs spontaneously after the Ni(II/I) reduction, as implied by the experimental observation of a single CV peak. These results suggest that the PCET process observed in the CV experiments is a two-electron/two-proton process corresponding to an initial double protonation followed by two reductions. On the basis of the experimental and theoretical data, the complete thermodynamic scheme and the Pourbaix diagram were generated for this catalyst. The Pourbaix diagram, which identifies the most thermodynamically stable species at each reduction potential and pH value, illustrates that this catalyst undergoes

  18. STARFIRE: The Spectroscopic Terahertz Airborne Receiver for Far-InfraRed Exploration

    NASA Astrophysics Data System (ADS)

    Aguirre, James; STARFIRE Collaboration

    2018-01-01

    Understanding the formation and evolution of galaxies is one of the foremost goals of astrophysics and cosmology today. The cosmic star formation rate has undergone a dramatic evolution over the course of the last seven billion years, with a peak in cosmic star formation near z ~ 1, largely in dust-obscured star forming galaxies (DSFGs), followed by a dramatic fall in both the star formation rate and the fraction of star formation occurring in DSFGs. A variety of unextincted diagnostic lines are present in the far-infrared (FIR) which can provide insight into the conditions of star formation in DSFGs. Spectroscopy in the far-infrared is thus scientifically crucial for understanding galaxy evolution, yet remains technically difficult, particularly for wavelengths shorter than those accessible to ALMA.STARFIRE (the Spectroscopic Terahertz Airborne Receiver for Far-InfraRed Exploration) is a proposed integral-field spectrometer using kinetic inductance detectors, operating from 240 - 420 μm and coupled to a 2.5 meter low-emissivity carbon-fiber balloon-borne telescope. Using dispersive spectroscopy and the stratospheric platform, STARFIRE can achieve better performance than SOFIA or Herschel-SPIRE FTS. STARFIRE is designed to study the ISM of galaxies from 0.5 < z < 1.5, primarily in the [CII](158 μm) line, and also in cross-correlation with [NII] (122 μm). This offers a view of the star-forming medium with minimal impact from dust extinction through the period of peak cosmic star formation and into the current epoch where the star formation rate begins to decline. STARFIRE will be capable of making a high significance detection of the [CII] power spectrum in at least 4 redshift bins and measuring the [CII] x [NII] power spectrum at z ~ 1. The intensity mapped power spectra will be sensitive to one- and two-halo clustering, as well as shot noise, and will relate the mean [CII] intensity as a function of redshift (a proxy for star formation rate density) to the

  19. Effects of inorganic nitrogen sources on the production of PP-V [(10Z)-12-carboxyl-monascorubramine] and the Expression of the nitrate assimilation gene cluster by Penicillium sp. AZ.

    PubMed

    Arai, Teppei; Umemura, Sara; Ota, Tamaki; Ogihara, Jun; Kato, Jun; Kasumi, Takafumi

    2012-01-01

    A fungal strain, Penicillium sp. AZ, produced the azaphilone Monascus pigment homolog when cultured in a medium composed of soluble starch, ammonium nitrate, yeast extract, and citrate buffer, pH 5.0. One of the typical features of violet pigment PP-V [(10Z)-12-carboxyl-monascorubramine] is that pyranoid oxygen is replaced with nitrogen. In this study, we found that ammonia and nitrate nitrogen are available for PP-V biosynthesis, and that ammonia nitrogen was much more effective than nitrate nitrogen. Further, we isolated nitrate assimilation gene cluster, niaD, niiA, and crnA, and analyzed the expression of these genes. The expression levels of all these genes increased with sodium nitrate addition to the culture medium. The results obtained here strongly suggest that Penicillium sp. AZ produced PP-V using nitrate in the form of ammonium reduced from nitrate through a bioprocess assimilatory reaction.

  20. Herschel Far Infrared Spectra of Dusty Star-Forming Galaxies

    NASA Astrophysics Data System (ADS)

    Wilson, Derek; Cooray, Asantha R.; Nayyeri, Hooshang

    2017-01-01

    We stack archival spectra from the Herschel Space Observatory's SPIRE Spectrometer in three redshift bins from low redshifts (z < 0.2), through intermediate redshifts (0.2 < z < 1), and up to high redshifts (z > 1) in order to determine the average properties of the gas and dust in dusty, star-forming galaxies and (U)LIRGs. In the lower-redshift stack, we detect a host of water and carbon monoxide rotational transition lines, as well as some fine structure lines such as [NII]. At intermediate redshifts, only a [CII] line appears. The high-redshift stack displays strong [CII] emission, as well as faint emission from [OI] and [OIII]. The observed emission lines are used to model the average number density and radiation field strength in the photodissociation regions of our high-redshift sample, and the spectral line energy distributions of CO rotational transitions from the low-redshift stack are presented.

  1. Lidar observation of marine mixed layer

    NASA Technical Reports Server (NTRS)

    Yamagishi, Susumu; Yamanouchi, Hiroshi; Tsuchiya, Masayuki

    1992-01-01

    Marine mixed layer is known to play an important role in the transportation of pollution exiting ship funnels. The application of a diffusion model is critically dependent upon a reliable estimate of a lid. However, the processes that form lids are not well understood, though considerable progress toward marine boundary layer has been achieved. This report describes observations of the marine mixed layer from the course Ise-wan to Nii-jima with the intention of gaining a better understanding of their structure by a shipboard lidar. These observations were made in the summer of 1991. One interesting feature of the observations was that the multiple layers of aerosols, which is rarely numerically modeled, was encountered. No attempt is yet made to present a systematic analysis of all the data collected. Instead we focus on observations that seem to be directly relevant to the structure of the mixed layer.

  2. Modification to Math Model for Small Independent Action Forces (SIAF)

    DTIC Science & Technology

    1973-12-15

    counterdetection situations. 1 6905-6008-RO-00 Page 2-44 WOcc = &&ls-.4 ZI- Lw _ _ _c__ _ _ _c z I.- 1 0 & a dC n u4.3C w 4.3 4n4 WLU cs td .~ 1--AiI I.- .C uj w...i et. - - S - U , )UU U aIA ~ U tiu W WQ wi W W U w td - l l -i M iA .j CA -o *m *o mc mc fP6-133 󈨁 a~ Ac a S o- I N S ag I 9E 30. Q CY " a𔃻 aac...I- 4f ow060 0 OLCO0 wuCo; O ~"-j~ I UzAc 30 1bd 4 OW b D- 6- 4bd d fo 6 udOw od Ś.464 .4 d Ot 6- 64W 6 b*64t PaI 7-55 NiI II a j l! I 1/. a

  3. The radical mechanism of biological methane synthesis by methyl-coenzyme M reductase

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wongnate, T.; Sliwa, D.; Ginovska, B.

    2016-05-19

    Methyl-coenzyme M reductase (MCR), the rate-limiting enzyme in methanogenesis and anaerobic methane oxidation, is responsible for the production of over one billion tons of methane per year. The mechanism of methane synthesis is unknown, with the two leading proposals involving either a methyl-nickel(III) (Mechanism I) or methyl radical/Ni(II)-thiolate (Mechanism II) intermediate(s). When the reaction between the active Ni(I) enzyme with substrates was studied by transient kinetic, spectroscopic and computational methods, formation of an EPR-silent Ni(II)-thiolate intermediate was positively identified by magnetic circular dichroism spectroscopy. There was no evidence for an EPR-active methyl-Ni(III) species. Temperature-dependent transient kinetic studies revealed that themore » activation energy for the initial catalytic step closely matched the value computed by density functional theory for Mechanism II. Thus, our results demonstrate that biological methane synthesis occurs by generation of a methyl radical.« less

  4. graphkernels: R and Python packages for graph comparison

    PubMed Central

    Ghisu, M Elisabetta; Llinares-López, Felipe; Borgwardt, Karsten

    2018-01-01

    Abstract Summary Measuring the similarity of graphs is a fundamental step in the analysis of graph-structured data, which is omnipresent in computational biology. Graph kernels have been proposed as a powerful and efficient approach to this problem of graph comparison. Here we provide graphkernels, the first R and Python graph kernel libraries including baseline kernels such as label histogram based kernels, classic graph kernels such as random walk based kernels, and the state-of-the-art Weisfeiler-Lehman graph kernel. The core of all graph kernels is implemented in C ++ for efficiency. Using the kernel matrices computed by the package, we can easily perform tasks such as classification, regression and clustering on graph-structured samples. Availability and implementation The R and Python packages including source code are available at https://CRAN.R-project.org/package=graphkernels and https://pypi.python.org/pypi/graphkernels. Contact mahito@nii.ac.jp or elisabetta.ghisu@bsse.ethz.ch Supplementary information Supplementary data are available online at Bioinformatics. PMID:29028902

  5. Department of the Army Justification of Estimates for FY 1991 Submitted to Congress January 1990. Operation and Maintenance, Army Justification Book. Volume 1

    DTIC Science & Technology

    1990-01-01

    8217 - ’"I Si _ Cr ~J-1 IL tJ -4; 4* V -) a- Nii :1-1 N - *~- ~ - - Flh 31 - ’,- I - , - 241 m -18 ’TNJN V _, ZA- E -t 4 3R 2 u : aF - - *>- -- Lj 0 00...0J~ . -4 4. C C rn~ 00. m * a ) ca Z4 :) af -4 4j Z. Ci o a) rn C.) to ~L C"W.o ) ) u) /3 0 MJ 0 r_4-4- 4-j go u 0 a0 W >to-44L-Ui 4-CJ J4 4J u) u~ E...t J m w-0~ w ~ 0 Z z~ 0 to u wm D m. -X 00’> Q) -~ U cn .- 1~. - 0 Uf.- 0> u0 -j t >C - cn uu 4z vC*-4J mu4- w v Ř-J W~c w w w wCCu ’ Af ~-a ju 0 0 z

  6. Role of pendant proton relays and proton-coupled electron transfer on the hydrogen evolution reaction by nickel hangman porphyrins

    DOE PAGES

    Bediako, D. Kwabena; Solis, Brian H.; Dogutan, Dilek K.; ...

    2014-10-08

    Here, the hangman motif provides mechanistic insights into the role of pendant proton relays in governing proton-coupled electron transfer (PCET) involved in the hydrogen evolution reaction (HER). We now show improved HER activity of Ni compared with Co hangman porphyrins. Cyclic voltammogram data and simulations, together with computational studies using density functional theory, implicate a shift in electrokinetic zone between Co and Ni hangman porphyrins due to a change in the PCET mechanism. Unlike the Co hangman porphyrin, the Ni hangman porphyrin does not require reduction to the formally metal(0) species before protonation by weak acids in acetonitrile. We concludemore » that protonation likely occurs at the Ni(I) state followed by reduction, in a stepwise proton transfer–electron transfer pathway. Spectroelectrochemical and computational studies reveal that upon reduction of the Ni(II) compound, the first electron is transferred to a metal-based orbital, whereas the second electron is transferred to a molecular orbital on the porphyrin ring.« less

  7. Role of pendant proton relays and proton-coupled electron transfer on the hydrogen evolution reaction by nickel hangman porphyrins

    PubMed Central

    Bediako, D. Kwabena; Solis, Brian H.; Dogutan, Dilek K.; Roubelakis, Manolis M.; Maher, Andrew G.; Lee, Chang Hoon; Chambers, Matthew B.; Hammes-Schiffer, Sharon; Nocera, Daniel G.

    2014-01-01

    The hangman motif provides mechanistic insights into the role of pendant proton relays in governing proton-coupled electron transfer (PCET) involved in the hydrogen evolution reaction (HER). We now show improved HER activity of Ni compared with Co hangman porphyrins. Cyclic voltammogram data and simulations, together with computational studies using density functional theory, implicate a shift in electrokinetic zone between Co and Ni hangman porphyrins due to a change in the PCET mechanism. Unlike the Co hangman porphyrin, the Ni hangman porphyrin does not require reduction to the formally metal(0) species before protonation by weak acids in acetonitrile. We conclude that protonation likely occurs at the Ni(I) state followed by reduction, in a stepwise proton transfer–electron transfer pathway. Spectroelectrochemical and computational studies reveal that upon reduction of the Ni(II) compound, the first electron is transferred to a metal-based orbital, whereas the second electron is transferred to a molecular orbital on the porphyrin ring. PMID:25298534

  8. Pentanuclear Cyanide-Bridged Complexes with High Spin Ground States S=6 and 9: Characterization and Magnetic Properties

    NASA Astrophysics Data System (ADS)

    Marvilliers, Arnaud; Hortholary, Cédric; Rogez, Guillaume; Audière, Jean-Paul; Rivière, Eric; Cano Boquera, Joan; Paulsen, Carley; Villar, Vincent; Mallah, Talal

    2001-07-01

    Two pentanuclear complexes are obtained from the reaction of hexacyanochromate(III) with one to two molar equivalents of [Ni(H2O)6]2+ and bidentate organic ligands that chelate the metal ion, leaving two coordination sites in cis positions. Even though the crystal structure was not solved, the full characterization supports the formation of pentanuclear discrete species. [Cr(CN)6]2[Ni(HIM2-py)2]3·7H2O, 1, has a ground spin state S=6 owing to the ferromagnetic interaction between CrIII (S=3/2) and NII (S=1). The presence of six organic radicals that couple ferromagnetically with NiII in [Cr(CN)6]2[Ni(IM2-py)2]3·7H2O, 2, leads to an S=9 ground state. A.c. susceptibility measurements below 2K indicate the occurrence of an antiferromagnetic order at 1.5 K in 2.

  9. HESCOMP. The Helicopter Sizing and Performance Computer Program. User’s Manual. Revision 2.

    DTIC Science & Technology

    1979-10-01

    uruieGlwChr)Pr f7 GO TO4100 ja I IDS CXS!G-CXS!GL* (1 CXS!G;I.CXS!G ~~~~ IF.X.T I X. NE. 0) jrWRTEi6.q90u IF XOL2MT(I)- CXS!G/CTPSL XCT2ILq II CTPSL 660...1 AO F ( F7 ~ ~ ~ 1 -I-3weN C3 77 C e0uffM~m1~asa~Y ~ rC -13 cS., 1 ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ G 7CI4I*11t~~l~ I TI.V’,ITt- Figure 4-62. PARA Function, Flow...7-255 L C4SA. a ACA ANA ACCA I r- I r4. .m Q. . 7.f kJim p41 oml Ni Nii ’e N~6 a. aQa OL a -0 c .. -7 4.;- C~ 4c>.Q a,1 ci ~ ~ % a cam p- F. . a a a

  10. Detection System of the First Rapidly Relocatable Tagged Neutron Inspection System (RRTNIS), Developed in the Framework of the European H2020 C-BORD Project

    NASA Astrophysics Data System (ADS)

    Fontana, Cristiano Lino; Carnera, Alberto; Lunardon, Marcello; Pino, Felix; Sada, Cinzia; Soramel, Francesca; Stevanato, Luca; Nebbia, Giancarlo; Carasco, Cédric; Perot, Bertrand; Sardet, Alix; Sannie, Guillaume; Iovene, Alessandro; Tintori, Carlo; Grodzicki, Krystian; Moszyński, Marek; Sibczyński, Paweł; Swiderski, Lukasz; Moretto, Sandra

    The European project entitled ;effective Container inspection at BORDer control points; (C-BORD) focuses on the development and in-situ tests of a comprehensive cost-effective solution for the generalized Non-Intrusive Inspection (NII) of containers and large-volume freight at the European Union (EU) border. It copes with a large range of targets, including explosives, chemical warfare agents, illicit drugs, tobacco and Special Nuclear Materials. Within the C-BORD project, a new generation of Tagged Neutron Inspection System (TNIS) for cargo containers is foreseen. Unlike its predecessors, this system would be the first Rapidly Relocatable TNIS (RRTNIS). It will be a second-line defense system, to be used on sealed containers in order to detect explosives, illicit drugs and chemical agents in a suspect voxel (elementary volume unit). We report on the status of the RRTNIS system, in particular the overall design, the characterization of the large-volume NaI(Tl) gamma detectors, the digital analysis of the time measurements and the Data Acquisition System (DAQ).

  11. graphkernels: R and Python packages for graph comparison.

    PubMed

    Sugiyama, Mahito; Ghisu, M Elisabetta; Llinares-López, Felipe; Borgwardt, Karsten

    2018-02-01

    Measuring the similarity of graphs is a fundamental step in the analysis of graph-structured data, which is omnipresent in computational biology. Graph kernels have been proposed as a powerful and efficient approach to this problem of graph comparison. Here we provide graphkernels, the first R and Python graph kernel libraries including baseline kernels such as label histogram based kernels, classic graph kernels such as random walk based kernels, and the state-of-the-art Weisfeiler-Lehman graph kernel. The core of all graph kernels is implemented in C ++ for efficiency. Using the kernel matrices computed by the package, we can easily perform tasks such as classification, regression and clustering on graph-structured samples. The R and Python packages including source code are available at https://CRAN.R-project.org/package=graphkernels and https://pypi.python.org/pypi/graphkernels. mahito@nii.ac.jp or elisabetta.ghisu@bsse.ethz.ch. Supplementary data are available online at Bioinformatics. © The Author(s) 2017. Published by Oxford University Press.

  12. Prime Contract Awards Alphabetically by Contractor, By State or Country, and Place, FY 84. Part 2. (Bay Area Controls - Cirtech Corporation).

    DTIC Science & Technology

    1984-01-01

    AC._E All ot ter edotons are oosolete. 747 to z ’ -’ (1 0A co 0 Y N N M) ( D ) D ) () C) ftN NII C N ~ N ID 0 Iq N N Q0I ) e D0 N I-’ N 17 -0 CDN Z O...L) C ) 0 0q D C .0~ ~ ~ ~ ~ C -)0 )- C- - C- I- - C-----)- NNN- 0 w iIw w r I ca - - N NNc N N IN ’mN N NNNNidN N CC N N: N - 0 0’ L)W C YWa*i c N Y...W N’ K) c) X K x K)4 K) Y a) w0 N)~ N--4 N N- K) d K)- ---------- ) N ) N )- N CO D0 .0 0N 0 00 0 0 0 K)NNN 0) K) 0 0 0 Vi0ac.o )0 0OO N NON C) 0 0D K

  13. Development of the 2nd generation z(Redshift) and early universe spectrometer & the study of far-IR fine structure emission in high-z galaxies

    NASA Astrophysics Data System (ADS)

    Ferkinhoff, Carl

    The 2nd generation z (Redshift) and Early Universe Spectrometer (ZEUS-2), is a long-slit echelle-grating spectrometer (R~1000) for observations at submillimeter wavelengths from 200 to 850 microm. Its design is optimized for the detection of redshifted far-infrared spectral lines from galaxies in the early universe. Combining exquisite sensitivity, broad wavelength coverage, and large (˜2.5%) instantaneous bandwidth, ZEUS-2 is uniquely suited for studying galaxies between z˜0.2 and 5---spanning the peaks in both the star formation rate and number of AGN in the universe. ZEUS-2 saw first light at the Caltech Submillimeter Observatory (CSO) in the Spring of 2012 and was commissioned on the Atacama Pathfinder Experiment (APEX) in November 2012. Here we detail the design and performance of ZEUS-2, first however we discuss important science results that are examples of the science enabled by ZEUS-2. Using the first generation z (Redshift) and Early Universe Spectrometer (ZEUS-1) we made the first high-z detections of the [NII] 122 microm and [OIII] 88 microm lines. We detect these lines from starburst galaxies between z ˜2.5 and 4 demonstrating the utility of these lines for characterizing the properties of early galaxies. Specifically we are able to determine the most massive star still on the main sequence, the number of those stars and a lower limit on the mass of ionized gas in the source. Next we present ZEUS-2's first science result. Using ZEUS-2 on APEX we have detected the [CII] 158 microm line from the z = 1.78 galaxy H-ATLAS J091043.1-000322 with a line flux of (6.44 +/- 0.42) ˜ 10-18 W m-2. Combined with its far-infrared luminosity and a new Herschel-PACS detection of the [OI] 63 microm line we are able to conclude that H-ATLAS J091043.1-000322 is a high redshift analogue of a local ultra-luminous infrared galaxy, i.e. it is likely the site of a compact starburst due to a major merger. This detection, combined with the ZEUS-1 observations of the [NII

  14. Interstellar matter in Shapley-Ames elliptical galaxies. II. The distribution of dust and ionized gas

    NASA Astrophysics Data System (ADS)

    Goudfrooij, P.; Hansen, L.; Jorgensen, H. E.; Norgaard-Nielsen, H. U.

    1994-06-01

    We present results of deep optical CCD imaging for a complete, optical magnitude-limited sample of 56 elliptical galaxies from the RSA catalog. For each galaxy we have obtained broad-band images (in B, V, and I) and narrow-band images using interference filters isolating the Hα+[NII] emission lines to derive the amount and morphology of dust and ionized gas. Detailed consideration of systematic errors due to effects of sky background subtraction and removal of stellar continuum light from the narrow-band images is described. The flux calibration of the narrow-band images is performed by deconvolving actually measured spectral energy distributions with the filter transmission curves. We also present optical long-slit spectroscopy to determine the [NII]/Hα intensity ratio of the ionized gas. Dust lanes and/or patches have been detected in 23 galaxies (41%) from this sample using both colour-index images and division by purely elliptical model images. We achieved a detection limit for dust absorption of A_B_~0.02. Accounting for selection effects, the true fraction of elliptical galaxies containing dust is estimated to be of order 80%. This detection rate is comparable to that of the IRAS satellite, and significantly larger than results of previous optical studies. Ionized gas has been detected in 32 galaxies (57%). The spectroscopic data confirm the presence and distribution of ionized gas as seen in the direct imaging. All elliptical galaxies in our sample in which a number of emission lines is detected show very similar emission-line intensity ratios, which are typical of LINER nuclei. The amounts of detectable dust and ionized gas are generally small--of order 10^4^-10^5^Msun_ of dust and 10^3^-10^4^Msun_ of ionized gas. The dust and ionized gas show a wide variety of distributions-extended along either the apparent major axis, or the minor axis, or a skewed axis, indicating that triaxiality is in general required as a galaxy figure. In some cases (NGC 1275, NGC

  15. ZEUS-2: a second generation submillimeter grating spectrometer for exploring distant galaxies

    NASA Astrophysics Data System (ADS)

    Ferkinhoff, Carl; Nikola, Thomas; Parshley, Stephen C.; Stacey, Gordon J.; Irwin, Kent D.; Cho, Hsiao-Mei; Halpern, Mark

    2010-07-01

    ZEUS-2, the second generation (z)Redshift and Early Universe Spectrometer, like its predecessor is a moderate resolution (R~1000) long-slit, echelle grating spectrometer optimized for the detection of faint, broad lines from distant galaxies. It is designed for studying star-formation across cosmic time. ZEUS-2 employs three TES bolometer arrays (555 pixels total) to deliver simultaneous, multi-beam spectra in up to 4 submillimeter windows. The NIST Boulder-built arrays operate at ~100mK and are readout via SQUID multiplexers and the Multi-Channel Electronics from the University of British Columbia. The instrument is cooled via a pulse-tube cooler and two-stage ADR. Various filter configurations give ZEUS-2 access to 7 different telluric windows from 200 to 850 micron enabling the simultaneous mapping of lines from extended sources or the simultaneous detection of the 158 micron [CII] line and the [NII] 122 or 205 micron lines from z = 1-2 galaxies. ZEUS-2 is designed for use on the CSO, APEX and possibly JCMT.

  16. Analysis of the diffuse ionized gas database: DIGEDA

    NASA Astrophysics Data System (ADS)

    Flores-Fajardo, N.; Morisset, C.; Binette, L.

    2009-10-01

    Studies of the Diffuse Ionized Gas (DIG) have progressed without providing so far any strict criterion to distinguish DIGs from H II regions. In this work, we compile the emission line measurements of 29 galaxies that are available in the scientific literature, thereby setting up the first DIG database (DIGEDA). Making use of this database, we proceed to analyze the global properties of the DIG using the [NII]λ6583/Hα, [O I]λ6300/Hα, [O III]λ5007/Hβ and [SII]λ6716/Hα lines ratios, including the H α emission measure. This analysis leads us to conclude that the [N II]/Hα ratio provides an objective criterion for distinguishing whether an emission region is a DIG or an H II region, while the EM(Hα) is a useful quantity only when the galaxies are considered individually. Finally, we find that the emission regions of Irr galaxies classified as DIG in the literature appear in fact to be much more similar to H II regions than to the DIGs of spiral galaxies.

  17. Weak hydrogen bond topology in 1,1-difluoroethane dimer: A rotational study

    NASA Astrophysics Data System (ADS)

    Chen, Junhua; Zheng, Yang; Wang, Juan; Feng, Gang; Xia, Zhining; Gou, Qian

    2017-09-01

    The rotational spectrum of the 1,1-difluoroethane dimer has been investigated by pulsed-jet Fourier transform microwave spectroscopy. Two most stable isomers have been detected, which are both stabilized by a network of three C—H⋯F—C weak hydrogen bonds: in the most stable isomer, two difluoromethyl C—H groups and one methyl C—H group act as the weak proton donors whilst in the second isomer, two methyl C—H groups and one difluoromethyl C—H group act as the weak proton donors. For the global minimum, the measurements have also been extended to its four 13C isotopologues in natural abundance, allowing a precise, although partial, structural determination. Relative intensity measurements on a set of μa-type transitions allowed estimating the relative population ratio of the two isomers as NI/NII ˜ 6/1 in the pulsed jet, indicating a much larger energy gap between these two isomers than that expected from ab initio calculation, consistent with the result from pseudo-diatomic dissociation energies estimation.

  18. Broadband Satellite Technologies and Markets Assessed

    NASA Technical Reports Server (NTRS)

    Wallett, Thomas M.

    1999-01-01

    The current usage of broadband (data rate greater than 64 kilobits per second (kbs)) for multimedia network computer applications is increasing, and the need for network communications technologies and systems to support this use is also growing. Satellite technology will likely be an important part of the National Information Infrastructure (NII) and the Global Information Infrastructure (GII) in the next decade. Several candidate communications technologies that may be used to carry a portion of the increased data traffic have been reviewed, and estimates of the future demand for satellite capacity have been made. A study was conducted by the NASA Lewis Research Center to assess the satellite addressable markets for broadband applications. This study effort included four specific milestones: (1) assess the changing nature of broadband applications and their usage, (2) assess broadband satellite and terrestrial technologies, (3) estimate the size of the global satellite addressable market from 2000 to 2010, and (4) identify how the impact of future technology developments could increase the utility of satellite-based transport to serve this market.

  19. Acupuncture for treating sciatica: a systematic review protocol

    PubMed Central

    Qin, Zongshi; Liu, Xiaoxu; Yao, Qin; Zhai, Yanbing; Liu, Zhishun

    2015-01-01

    Introduction This systematic review aims to assess the effectiveness and safety of acupuncture for treating sciatica. Methods The following nine databases will be searched from their inception to 30 October 2014: MEDLINE, EMBASE, the Cochrane Central Register of Controlled Trials (CENTRAL), the Chinese Biomedical Literature Database (CBM), the Chinese Medical Current Content (CMCC), the Chinese Scientific Journal Database (VIP database), the Wan-Fang Database, the China National Knowledge Infrastructure (CNKI) and Citation Information by National Institute of Informatics (CiNii). Randomised controlled trials (RCTs) of acupuncture for sciatica in English, Chinese or Japanese without restriction of publication status will be included. Two researchers will independently undertake study selection, extraction of data and assessment of study quality. Meta-analysis will be conducted after screening of studies. Data will be analysed using risk ratio for dichotomous data, and standardised mean difference or weighted mean difference for continuous data. Dissemination This systematic review will be disseminated electronically through a peer-reviewed publication or conference presentations. Trial registration number PROSPERO CRD42014015001. PMID:25922105

  20. Geographic List of Prime Contract Awards. Oct 91 - Sep 92. FY92. (Fort Hood Texas - Northfield Vermont)

    DTIC Science & Technology

    1993-01-01

    00N00LALAm00)LA0 -- n, o-, nc4-- n( )m-zTI o-ir -- * 0)CIO 1C) -- i-s a) CI W N 1wo jini nI-I 0 o o01 o ,w 4-1t in WL L L L 0 00 0 0 A 0 01"C4 0 ’ ~ 0C14r...411 N ,N 1`4 NJ I Q -4-4 to >-.-- zzzzzzz z zz ZZ ZZ> >>--> - Uf C41I 0-40 11 au Mə <<- JINI 4- (04 4N014INN Uf 00(n o U n (inl ý4 - I4-4- 4 -4 i...N Is 1(000o atoz z z z z z z z zz z motto00 It 7) 00 0U)..VN(to-4 N l (a0 000 0 0 In01C* an 0 Ga I(00 Gao If 0)C0an.0(0 In O0NC 0 0 0 -*MM’ N o A IC

  1. Beyond telecommuting: A new paradigm for the effect of telecommunications on travel

    NASA Astrophysics Data System (ADS)

    Niles, J. S.

    1994-09-01

    Conventional wisdom about social and economic behavior holds that the use of telecommunications is a natural substitute for transportation. For example, telephone calls can replace travel to meetings, and facsimile or electronic-mail transmission of documents substitutes for courier or postal delivery. The moving of information can replace the moving of people and goods. Vehicle traffic on the national transportation infrastructure can be replaced by digital traffic on what is now called the national information infrastructure (NII). A leading example is telecommuting. This means using telecommunications to replace commuting between home and work. Telecommuting is an optional way of expanding employees' work locations in those circumstances where it yields both improved organizational performance and employee satisfaction. Telecommuting accounts for 7.6 million U.S. workers as of early 1993, up 15% from the 6.6 million counted in 1992. The growth of telecommuting has been strong for the past five years. No one has identified any reasons to suggest that this growth will abate in the forseeable future.

  2. The ZEUS 1 & 2 INvestigated Galaxy Reference Sample (ZINGRS): A window into galaxies in the early Universe.

    NASA Astrophysics Data System (ADS)

    Ferkinhoff, Carl; Hershey, Deborah; Scrabeck, Alex; Higdon, Sarah; Higdon, James L.; Tidwell, Hannah; Lamarche, Cody; Vishwas, Amit; Nikola, Thomas; Stacey, Gordon J.; Brisbin, Drew

    2018-06-01

    Galaxies have evolved significantly from the early Universe until today. Star formation rates, stellar and molecular gas masses, sizes and metal enrichment of galaxies have all changed significantly from early epochs until the present. Probing the physical conditions of galaxy at high redshift is vital to understanding this evolution. ZINGRS, the ZEUS 1 and 2 INvestigated Galaxy Reference Sample, provides a unique and powerful window for this work. The sample consists of more than ~30 galaxies from z ~ 1 - 4.5 for which the far-IR fine-structure lines (e.g. [CII] 158 micron, [NII] 122micron, [OIII] 88 micron) have been observed with the ZEUS-1 and 2 instruments. These lines are ideal for studying high-z systems since they require low energies for excitation, are typically optically thin, and are not susceptible to extinction from dust. ZINGRS is the largest collection of far-IR fine-structure line detections at high-z. Here we describe the sample, including extensive multifrequency supporting observations like CO & radio continuum, and summarize what we have learned so far.

  3. Beyond telecommuting: A new paradigm for the effect of telecommunications on travel

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Niles, J.S.

    1994-09-01

    Conventional wisdom about social and economic behavior holds that the use of telecommunications is a natural substitute for transportation. For example, telephone calls can replace travel to meetings, and facsimile or electronic-mail transmission of documents substitutes for courier or postal delivery. The moving of information can replace the moving of period and goods. Vehicle traffic on the national transportation infrastructure can be replaced by digital traffic on what is now called the National Information Infrastructure (NII). A leading example is telecommuting. This means using telecommunications to replace commuting between home and work. Telecommuting is an optional way of expanding employees`more » work locations in those circumstances where it yields both improved organizational performance and employee satisfication. Telecommuting accounts for 7.6 million U.S. workers as of early 1993, up 15% from the 6.6 million counted in 1992. The growth of telecommuting has been strong for the past five years. No one has identified any reasons to suggest that this growth will abate in the forseeable future.« less

  4. Combinatorial function of velvet and AreA in transcriptional regulation of nitrate utilization and secondary metabolism.

    PubMed

    López-Berges, Manuel S; Schäfer, Katja; Hera, Concepción; Di Pietro, Antonio

    2014-01-01

    Velvet is a conserved protein complex that functions as a regulator of fungal development and secondary metabolism. In the soil-inhabiting pathogen Fusarium oxysporum, velvet governs mycotoxin production and virulence on plant and mammalian hosts. Here we report a previously unrecognized role of the velvet complex in regulation of nitrate metabolism. F. oxysporum mutants lacking VeA or LaeA, two key components of the complex, were impaired in growth on the non-preferred nitrogen sources nitrate and nitrite. Both velvet and the general nitrogen response GATA factor AreA were required for transcriptional activation of nitrate (nit1) and nitrite (nii1) reductase genes under de-repressing conditions, as well as for the nitrate-triggered increase in chromatin accessibility at the nit1 locus. AreA also contributed to chromatin accessibility and expression of two velvet-regulated gene clusters, encoding biosynthesis of the mycotoxin beauvericin and of the siderophore ferricrocin. Thus, velvet and AreA coordinately orchestrate primary and secondary metabolism as well as virulence functions in F. oxysporum. Copyright © 2013 Elsevier Inc. All rights reserved.

  5. The Sunrise project: An R&D project for a national information infrastructure prototype

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lee, Juhnyoung

    1995-02-01

    Sunrise is a Los Alamos National Laboratory (LANL) project started in October 1993. It is intended to a prototype National Information Infrastructure (NII) development project. A main focus of Sunrise is to tie together enabling technologies (networking, object-oriented distributed computing, graphical interfaces, security, multimedia technologies, and data mining technologies) with several specific applications. A diverse set of application areas was chosen to ensure that the solutions developed in the project are as generic as possible. Some of the application areas are materials modeling, medical records and image analysis, transportation simulations, and education. This paper provides a description of Sunrise andmore » a view of the architecture and objectives of this evolving project. The primary objectives of Sunrise are three-fold: (1) To develop common information-enabling tools for advanced scientific research and its applications to industry; (2) To enhance the capabilities of important research programs at the Laboratory; and (3) To define a new way of collaboration between computer science and industrially relevant research.« less

  6. National Security Science and Technology Initiative: Air Cargo Screening, Final Report for CRADA Number NFE-07-01081

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bingham, Philip; Bush, John; Bowerman, Biays

    The non-intrusive inspection (NII) of consolidated air cargo carried on commercial passenger aircraft continues to be a technically challenging, high-priority requirement of the Department of Homeland Security’s Science and Technology Directorate (DHS S&T), the Transportation Security Agency and the Federal Aviation Administration. The goal of deploying a screening system that can reliably and cost-effectively detect explosive threats in consolidated cargo without adversely affecting the flow of commerce will require significant technical advances that will take years to develop. To address this critical National Security need, the Battelle Memorial Institute (Battelle), under a Cooperative Research and Development Agreement (CRADA) with fourmore » of its associated US Department of Energy (DOE) National Laboratories (Oak Ridge, Pacific Northwest, Idaho, and Brookhaven), conducted a research and development initiative focused on identifying, evaluating, and integrating technologies for screening consolidated air cargo for the presence of explosive threats. Battelle invested $8.5M of internal research and development funds during fiscal years 2007 through 2009.« less

  7. A study on an unusual SN2 mechanism in the methylation of benzyne through nickel-complexation.

    PubMed

    Hatakeyama, Makoto; Sakamoto, Yuki; Ogata, Koji; Sumida, Yuto; Sumida, Tomoe; Hosoya, Takamitsu; Nakamura, Shinichiro

    2017-10-11

    In this study, three reaction mechanisms of a benzyne-nickel (Ni) complex ([Ni(C 6 H 4 )(dcpe)]) with iodomethane during the methylation process were investigated, namely (a) S N 2 reaction of the benzyne-Ni complex with iodomethane, (b) concerted σ-bond metathesis during the bond breaking/forming processes, and (c) oxidative addition of iodomethane to the Ni-center and the subsequent reductive elimination process. DFT calculations revealed that the reaction barrier of the S N 2 reaction is slightly lower than those of the other mechanisms. The results of orbital analyses suggest that [Ni(C 6 H 4 )(dcpe)] forms a metallacycle structure between benzyne and the Ni II (3d 8 ) center instead of the η 2 -structure with the Ni 0 (3d 10 ) center. The metallacycle structures became inappropriate as the intermediates of oxidative addition in the formation of the Ni II -Me bond, avoiding further oxidation to the high-valent Ni IV . The high free energy along σ-bond metathesis was generated from the steric hindrance, thus invoking methylation and Ni-I bond formation concertedly.

  8. Motivational, proteostatic and transcriptional deficits precede synapse loss, gliosis and neurodegeneration in the B6.HttQ111/+ model of Huntington's disease.

    PubMed

    Bragg, Robert M; Coffey, Sydney R; Weston, Rory M; Ament, Seth A; Cantle, Jeffrey P; Minnig, Shawn; Funk, Cory C; Shuttleworth, Dominic D; Woods, Emily L; Sullivan, Bonnie R; Jones, Lindsey; Glickenhaus, Anne; Anderson, John S; Anderson, Michael D; Dunnett, Stephen B; Wheeler, Vanessa C; MacDonald, Marcy E; Brooks, Simon P; Price, Nathan D; Carroll, Jeffrey B

    2017-02-08

    We investigated the appearance and progression of disease-relevant signs in the B6.Htt Q111/+ mouse, a genetically precise model of the mutation that causes Huntington's disease (HD). We find that B6.Htt Q111/+ mice are healthy, show no overt signs of central or peripheral inflammation, and no gross motor impairment as late as 12 months of age. Behaviorally, we find that 4-9 month old B6.Htt Q111/+ mice have normal activity levels and show no clear signs of anxiety or depression, but do show clear signs of reduced motivation. The neuronal density, neuronal size, synaptic density and number of glia is normal in B6.Htt Q111/+ striatum, the most vulnerable brain region in HD, up to 12 months of age. Despite this preservation of the synaptic and cellular composition of the striatum, we observe clear progressive, striatal-specific transcriptional dysregulation and accumulation of neuronal intranuclear inclusions (NIIs). Simulation studies suggest these molecular endpoints are sufficiently robust for future preclinical studies, and that B6.Htt Q111/+ mice are a useful tool for modeling disease-modifying or neuroprotective strategies for disease processes before the onset of overt phenotypes.

  9. Chemical Composition of Nebulosities in the Magellanic Clouds

    PubMed Central

    Aller, L. H.; Czyzak, S. J.; Keyes, C. D.; Boeshaar, G.

    1974-01-01

    From photoelectric spectrophotometric data secured at Cerro Tololo Interamerican Observatory we have attempted to derive electron densities and temperatures, ionic concentrations, and chemical abundances of He, C, N, O, Ne, S, and Ar in nebulosities in the Magellanic Clouds. Although 10 distinct nebulosities were observed in the Small Cloud and 20 such objects in the Large Cloud, the most detailed observations were secured only for the brighter objects. Results for 30 Doradus are in harmony with those published previously and recent work by Peimbert and Torres-Peimbert. Nitrogen and heavier elements appear to be less abundant in the Small Cloud than in the Large Cloud, in accordance with the conclusions of Dufour. A comparison with the Orion nebula suggests He, N, Ne, O, and S may all be less abundant in the Megellanic Clouds, although adequate evaluations will require construction of detailed models. For example, if we postulate that the [NII], [OII], and [SII] radiations originate primarily in regions with electron temperatures near 8000°K, while the [OIII], [NeIII], [ArIII], and H radiations are produced primarily in regions with Tε = 10,000° K, the derived chemical abundances in the clouds are enhanced. PMID:16592199

  10. Deciphering kinase-substrate relationships by analysis of domain-specific phosphorylation network.

    PubMed

    Damle, Nikhil Prakash; Mohanty, Debasisa

    2014-06-15

    In silico prediction of site-specific kinase-substrate relationships (ssKSRs) is crucial for deciphering phosphorylation networks by linking kinomes to phosphoproteomes. However, currently available predictors for ssKSRs give rise to a large number of false-positive results because they use only a short sequence stretch around phosphosite as determinants of kinase specificity and do not consider the biological context of kinase-substrate recognition. Based on the analysis of domain-specific kinase-substrate relationships, we have constructed a domain-level phosphorylation network that implicitly incorporates various contextual factors. It reveals preferential phosphorylation of specific domains by certain kinases. These novel correlations have been implemented in PhosNetConstruct, an automated program for predicting target kinases for a substrate protein. PhosNetConstruct distinguishes cognate kinase-substrate pairs from a large number of non-cognate combinations. Benchmarking on independent datasets using various statistical measures demonstrates the superior performance of PhosNetConstruct over ssKSR-based predictors. PhosNetConstruct is freely available at http://www.nii.ac.in/phosnetconstruct.html. © The Author 2014. Published by Oxford University Press. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com.

  11. The federal role in the health information infrastructure: a debate of the pros and cons of government intervention.

    PubMed Central

    Shortliffe, E H; Bleich, H L; Caine, C G; Masys, D R; Simborg, D W

    1996-01-01

    Some observers feel that the federal government should play a more active leadership role in educating the medical community and in coordinating and encouraging a more rapid and effective implementation of clinically relevant applications of wide-area networking. Other people argue that the private sector is recognizing the importance of these issues and will, when the market demands it, adopt and enhance the telecommunications systems that are needed to produce effective uses of the National Information Infrastructure (NII) by the healthcare community. This debate identifies five areas for possible government involvement: convening groups for the development of standards; providing funding for research and development; ensuring the equitable distribution of resources, particularly to places and people considered by private enterprise to provide low opportunities for profit; protecting rights of privacy, intellectual property, and security; and overcoming the jurisdictional barriers to cooperation, particularly when states offer conflicting regulations. Arguments against government involvement include the likely emergence of an adequate infrastructure under free market forces, the often stifling effect of regulation, and the need to avoid a common-and-control mentality in an infrastructure that is best promoted collaboratively. PMID:8816347

  12. Production and application of chemical fibers with special properties for manufacturing composite materials and goods of different usage

    NASA Technical Reports Server (NTRS)

    Levit, R.

    1993-01-01

    The development of modern technologies demands the creation of new nonmetallic, fibrous materials with specific properties. The fibers and materials developed by NII 'Chimvolokno', St. Petersburg, can be divided into two groups. The first group includes heat-resistant fibers, fire-resistant fibers, thermotropic fibers, fibers for medical application, and textile structures. The second group contains refractory fibers, chemoresistant and antifriction fibers, fibers on the basis of polyvinyl alcohol, microfiltering films, and paperlike and nonwoven materials. In cooperation with NPO 'Chimvolokno' MYTITSHI, we developed and started producing heat-resistant high-strength fibers on the base of polyhetarearilin and aromatic polyimides (SVM and terlon); heat-resistant fibers on the base of polyemede (aramid); fire-retardant fibers (togilen); chemoresistant and antifriction fibers on the basis of homo and copolymers of polytetrafluoroethylene (polyfen and ftorin); and water soluble, acetylated, and high-modulus fibers from polyvinyl alcohol (vylen). Separate reports will deal with textile structures and thermotropic fibers, as well as with medical fibers. One of the groups of refractory fibers carbon fibers (CF) and the corresponding paperlike nonwoven materials are discussed in detail. Also, composite materials (CM) and their base, which is the subject of the author's research since 1968, is discussed.

  13. Combined Spectroscopic and Electrochemical Detection of a Ni I ---H-N Bonding Interaction with Relevance to Electrocatalytic H 2 Production

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kochem, Amélie; O'Hagan, Molly; Wiedner, Eric S.

    2015-06-03

    The [Ni(P R 2N R' 2) 2] 2+ family of complexes are exceptionally active catalysts for proton reduction to H 2. In this manuscript, we explore the first protonation step of the proposed catalytic cycle by using a catalytically inactive Ni I complex possessing a sterically demanding variation of the ligand. Due to the paramagnetic nature of the Ni I oxidation state, the protonated Ni I intermediate has been characterized through a combination of cyclic voltammetry, electron nuclear double resonance (ENDOR) spectroscopy, and hyperfine sublevel correlation (HYSCORE) spectroscopy. Both the electrochemical and spectroscopic studies indicate that the NiI complex ismore » protonated at a pendant amine that is endo to Ni, which suggests the presence of an intramolecular Ni I---HN bonding interaction. Using density functional theory, the hydrogen bond was found to involve three doubly-occupied, localized molecular orbitals: the 3d xz, 3d z2, and 3d yz orbitals of nickel. These studies provide the first direct experimental evidence for this critical catalytic intermediate, and implications for catalytic H 2 production are discussed.« less

  14. Geoengineering and seismological aspects of the Niigata-Ken Chuetsu-Oki earthquake of 16 July 2007

    USGS Publications Warehouse

    Kayen, R.; Brandenberg, S.J.; CoIlins, B.D.; Dickenson, S.; Ashford, S.; Kawamata, Y.; Tanaka, Y.; Koumoto, H.; Abrahamson, N.; Cluff, L.; Tokimatsu, K.

    2009-01-01

    The M6.6 Niigata-Ken Chuetsu-Oki earthquake of 16 July 2007 occurred off the west coast of Japan with a focal depth of 10 km, immediately west of Kashiwazaki City and Kariwa Village in southern Niigata Prefecture. Peak horizontal ground accelerations of 0.68 g were measured in Kashiwazaki City, as well as at the reactor floor level of the world's largest nuclear reactor, located on the coast at Kariwa Village. Liquefaction of historic and modern river deposits, aeolian dune sand, and manmade fill was widespread in the coastal region nearest the epicenter and caused ground deformations that damaged bridges, embankments, roadways, buildings, ports, railways and utilities. Landslides along the coast of southern Niigata Prefecture and in mountainous regions inland of Kashiwazaki were also widespread affecting transportation infrastructure. Liquefaction and a landslide also damaged the nuclear power plant sites. This paper, along with a companion digital map database available at http://walrus.wr.usgs.gOv/infobank/n/nii07jp/html/n-ii-07-jp.sites.kmz, describes the seismological and geo-engineering aspects of the event. ?? 2009, Earthquake Engineering Research Institute.

  15. Influence of mixed thiolate/thioether versus dithiolate coordination on the accessibility of the uncommon +I and +III oxidation states for the nickel ion: an experimental and computational study.

    PubMed

    Gennari, Marcello; Orio, Maylis; Pécaut, Jacques; Bothe, Eberhard; Neese, Frank; Collomb, Marie-Noëlle; Duboc, Carole

    2011-04-18

    Sulfur-rich nickel metalloenzymes are capable of stabilizing Ni(I) and Ni(III) oxidation states in catalytically relevant species. In an effort to better understand the structural and electronic features that allow the stabilization of such species, we have investigated the electrochemical properties of two mononuclear N(2)S(2) Ni(II) complexes that differ in their sulfur environment. Complex 1 features aliphatic dithiolate coordination ([NiL], 1), and complex 2I is characterized by mixed thiolate/thioether coordination ([NiL(Me)]I, 2I). The latter results from the methylation of a single sulfur of 1. The X-ray structure of 2I reveals a distorted square planar geometry around the Ni(II) ion, similar to what was previously reported by us for 1. The electrochemical investigation of 1 and 2(+) shows that the addition of a methyl group shifts the potentials of both redox Ni(II)/Ni(I) and Ni(III)/Ni(II) redox couples by about 0.7 and 0.6 V to more positive values. Through bulk electrolyses, only the mononuclear dithiolate [Ni(I)L](-) (1(-)) and the mixed thiolate/thioether [Ni(III)L(Me)](2+) (2(2+)) complexes were generated, and their electronic properties were investigated by UV-vis and EPR spectroscopy. For 1(-) (Ni(I), d(9) configuration) the EPR data are consistent with a d(x(2))(-)(y(2)) based singly occupied molecular orbitals (SOMOs). However, DFT calculations suggest that there is also pronounced radical character. This is consistent with the small g-anisotropy observed in the EPR experiments. The spin population (Mulliken analysis) analysis of 1(-) reveals that the main contribution to the SOMO (64%) is due to the bipyridine unit. Time dependent density functional theory (TD-DFT) calculations attribute the most prominent features observed in the electronic absorption spectrum of 1(-) to metal to ligand charge transfer (MLCT) transitions. Concerning 2(2+), the EPR spectrum displays a rhombic signal with g(x) = 2.236, g(y) = 2.180, and g(z) = 2.039 in CH(3)CN

  16. Shock Energy in Merging Systems: The Elephant in the Room.

    NASA Astrophysics Data System (ADS)

    Kewley, Lisa

    2011-10-01

    The relationship between shocks, star formation and the evolution of merging galaxies is not well understood. We are now poised to gain major insight in this area, thanks to the high resolution narrow-band imaging capabilities of WFC3 and recent major advances in theoretical shock and and photoionization models. Shocks and star formation in merging galaxies are regulated by fundamental physical properties of the ISM such as dust, gas density, ionized gas structure, and the presence of galactic winds and outflows. We aim to uncover the relationship between shocks, galactic winds, and the fundamental ISM properties in two famous mergers NGC 6240 and Arp 220. These two galaxies are currently transitioning from disk galaxies into spheroids and they are close enough to achieve the spatial scales required to resolve individual supernova remnants with WFC3 imaging. We propose to image NGC 6240 and Arp 220 in key shock and photoionization sensitive diagnostic lines [OII], [OIII], H-beta, [NII]+H-alpha, [SII], and {where possible} [OI] to {1} resolve the source of the ionizing radiation field {shocks versus photoionization by hot stars} at spatial scales of 25-35 pc, and {2} map the distribution of the star formation and ionized gas to search for links with merger-driven shocks and large-scale gas flows.

  17. Kinematics of the Diffuse Ionized Gas Disk of Andromeda

    NASA Astrophysics Data System (ADS)

    Thelen, Alexander; Howley, K.; Guhathakurta, P.; Dorman, C.; SPLASH Collaboration

    2012-01-01

    This research focuses on the flattened rotating diffuse ionized gas (DIG) disk of the Andromeda Galaxy (M31). For this we use spectra from 25 multislit masks obtained by the SPLASH collaboration using the DEIMOS spectrograph on the Keck-II 10-meter telescope. Each mask contains 200 slits covering the region around M32 (S of the center of M31), the major axis of M31, and the SE minor axis. DIG emission was serendipitously detected in the background sky of these slits. By creating a normalized "sky spectrum” to remove various other sources of emission (such as night sky lines) in the background of these slits, we have examined the rotation of the DIG disk using individual line-of-sight velocity measurements of Hα, [NII] and [SII] emission. his emission is probably the result of newly formed stars ionizing the gas in the disk. The measured IG rotation will be compared to the rotation of M31's stellar disk and HI gas disk, as well as models of an infinitely thin rotating disk, to better understand the relationship between the components of the galactic disk and its differential rotation. We wish to acknowledge the NSF for funding on this project.

  18. An Infrared Method for Discovering AGN: Lick Spectroscopy of New Seyfert I’s in the Kepler Fields

    NASA Astrophysics Data System (ADS)

    Tsan, Tran; Edelson, Rick; Smith, Krista Lynne; Malkan, Matthew Arnold

    2016-06-01

    Spectra of Active Galactic Nuclei (AGN) candidates in the Kepler fields were observed at Lick Observatory. We used the Shane 3.0-meter telescope with the Kast double spectrograph, covering from 0.35-0.8 μm. Using IRAF, we extracted 1D spectra from the original 2D long-slit images of the candidates. Our main goals are to determine the redshift of the candidates and identify any new AGN. The wavelength and flux calibration are fairly accurate, and most spectra have a good signal-to-noise ratio. Twenty- seven nights of data (consisting of 106 candidates) have been analyzed. For 89% of them, we have determined the redshifts to a precision of δz = 0.0005 in most cases. The rest give inconclusive results. 19 of the candidates turn out to be galactic stars. The most commonly identified emission lines are Hα+[NII], the [OIII] doublet, and Hβ. 44 of the candidates show a Broad Line Region, meaning that their wide permitted lines classify them as either Seyfert I’s or quasars. 6 of these have redshifts above 0.5, indicating that they are highly luminous quasars. One candidate appears to be a bl-lac object. We are now analyzing the Kepler light curves of these Seyfert galaxies.

  19. Physical Parameters of the Pre-WN Candidate HD326823

    NASA Astrophysics Data System (ADS)

    de Araujo, F. X.; Marcolino, W. L. F.; Borges Fernándes, M.

    2006-06-01

    HD326823 is a massive and luminous star characterized mainly by the presence of very intense HeI emission lines. From qualitative spectroscopic studies it was proposed by Lopes et al. (1992, A&A, 261, 482) and Borges Fernándes et al. (2001, ApJS, 136, 747) that this interesting object is in a pre-WN stage of evolution. In the present work we reinforce this conclusion, thanks to the estimate of its physical parameters like mass loss rate and especially chemical abundances. The data analysed by us were obtained at ESO 2.2-m telescope, with the spectrograph FEROS (R=48000) on April, 2005. The method employed to obtain the parameters is the fitting of HI, HeI and NII emission lines. In order to do this we have used the CMFGEN code, developed by J. Hilliers and colaborators (see, for instance, Hiller & Miller 1998, ApJ, 496, 407). This code is adequate for the modelling of lines produced in an expanding atmosphere and it includes important effects like line-blanketting and clumping. Preliminary results indicate a mass loss rate in the range and a clear overabundance of helium. As nitrogen abundance is concerned, it also indicates a tendency of increased abundance, but the result is not so firm in this case.

  20. Towards cross-lingual alerting for bursty epidemic events.

    PubMed

    Collier, Nigel

    2011-10-06

    Online news reports are increasingly becoming a source for event-based early warning systems that detect natural disasters. Harnessing the massive volume of information available from multilingual newswire presents as many challanges as opportunities due to the patterns of reporting complex spatio-temporal events. In this article we study the problem of utilising correlated event reports across languages. We track the evolution of 16 disease outbreaks using 5 temporal aberration detection algorithms on text-mined events classified according to disease and outbreak country. Using ProMED reports as a silver standard, comparative analysis of news data for 13 languages over a 129 day trial period showed improved sensitivity, F1 and timeliness across most models using cross-lingual events. We report a detailed case study analysis for Cholera in Angola 2010 which highlights the challenges faced in correlating news events with the silver standard. The results show that automated health surveillance using multilingual text mining has the potential to turn low value news into high value alerts if informed choices are used to govern the selection of models and data sources. An implementation of the C2 alerting algorithm using multilingual news is available at the BioCaster portal http://born.nii.ac.jp/?page=globalroundup.

  1. The SAMI Galaxy Survey: Publicly Available Spatially Resolved Emission Line Data Products

    NASA Astrophysics Data System (ADS)

    Medling, Anne; Green, Andrew W.; Ho, I.-Ting; Groves, Brent; Croom, Scott; SAMI Galaxy Survey Team

    2017-01-01

    The SAMI Galaxy Survey is collecting optical integral field spectroscopy of up to 3400 nearby (z<0.1) galaxies with a range of stellar masses and in a range of environments. The first public data release contains nearly 800 galaxies from the Galaxy And Mass Assembly (GAMA) Survey. In addition to releasing the reduced data cubes, we also provide emission line fits (flux and kinematic maps of strong emission lines including Halpha and Hbeta, [OII]3726,29, [OIII]4959,5007, [OI]6300, [NII]6548,83, and [SII]6716,31), extinction maps, star formation classification masks, and star formation rate maps. We give an overview of the data available for your favorite emission line science and present a few early science results. For example, a sample of edge-on disk galaxies show enhanced extraplanar emission related to SF-driven outflows, which are correlated with a bursty star formation history and higher star formation rate surface densities. Interestingly, the star formation rate surface densities of these wind hosts are 5-100 times lower than the canonical threshold for driving winds (0.1 MSun/yr/kpc2), indicating that galactic winds may be more important in normal star-forming galaxies than previously thought.

  2. Motivational, proteostatic and transcriptional deficits precede synapse loss, gliosis and neurodegeneration in the B6.HttQ111/+ model of Huntington’s disease

    PubMed Central

    Bragg, Robert M.; Coffey, Sydney R.; Weston, Rory M.; Ament, Seth A.; Cantle, Jeffrey P.; Minnig, Shawn; Funk, Cory C.; Shuttleworth, Dominic D.; Woods, Emily L.; Sullivan, Bonnie R.; Jones, Lindsey; Glickenhaus, Anne; Anderson, John S.; Anderson, Michael D.; Dunnett, Stephen B.; Wheeler, Vanessa C.; MacDonald, Marcy E.; Brooks, Simon P.; Price, Nathan D.; Carroll, Jeffrey B.

    2017-01-01

    We investigated the appearance and progression of disease-relevant signs in the B6.HttQ111/+ mouse, a genetically precise model of the mutation that causes Huntington’s disease (HD). We find that B6.HttQ111/+ mice are healthy, show no overt signs of central or peripheral inflammation, and no gross motor impairment as late as 12 months of age. Behaviorally, we find that 4–9 month old B6.HttQ111/+ mice have normal activity levels and show no clear signs of anxiety or depression, but do show clear signs of reduced motivation. The neuronal density, neuronal size, synaptic density and number of glia is normal in B6.HttQ111/+ striatum, the most vulnerable brain region in HD, up to 12 months of age. Despite this preservation of the synaptic and cellular composition of the striatum, we observe clear progressive, striatal-specific transcriptional dysregulation and accumulation of neuronal intranuclear inclusions (NIIs). Simulation studies suggest these molecular endpoints are sufficiently robust for future preclinical studies, and that B6.HttQ111/+ mice are a useful tool for modeling disease-modifying or neuroprotective strategies for disease processes before the onset of overt phenotypes. PMID:28176805

  3. Flue-gas and direct-air capture of CO2 by porous metal–organic materials

    PubMed Central

    2017-01-01

    Sequestration of CO2, either from gas mixtures or directly from air (direct air capture), is a technological goal important to large-scale industrial processes such as gas purification and the mitigation of carbon emissions. Previously, we investigated five porous materials, three porous metal–organic materials (MOMs), a benchmark inorganic material, Zeolite 13X and a chemisorbent, TEPA-SBA-15, for their ability to adsorb CO2 directly from air and from simulated flue-gas. In this contribution, a further 10 physisorbent materials that exhibit strong interactions with CO2 have been evaluated by temperature-programmed desorption for their potential utility in carbon capture applications: four hybrid ultramicroporous materials, SIFSIX-3-Cu, DICRO-3-Ni-i, SIFSIX-2-Cu-i and MOOFOUR-1-Ni; five microporous MOMs, DMOF-1, ZIF-8, MIL-101, UiO-66 and UiO-66-NH2; an ultramicroporous MOM, Ni-4-PyC. The performance of these MOMs was found to be negatively impacted by moisture. Overall, we demonstrate that the incorporation of strong electrostatics from inorganic moieties combined with ultramicropores offers improved CO2 capture performance from even moist gas mixtures but not enough to compete with chemisorbents. This article is part of the themed issue ‘Coordination polymers and metal–organic frameworks: materials by design’. PMID:27895255

  4. Mapping the Extent of M82's outlfows with VIRUS-P

    NASA Astrophysics Data System (ADS)

    Indahl, Briana; Hill, Gary J.; Drory, Niv; McLinden, Emily

    2017-06-01

    Starburst-driven outflows (SBDOs) and other feedback processes play a critical role in the evolution of galaxies through the regulation and disruption of star formation. However, our ability to observe and quantify feedback from SBDOs directly has been limited by the inability to obtain the spectroscopy needed for physical diagnostics over the large areas of local SBDOs. We present integral field spectroscopy taken with the George and Cynthia Mitchell Spectrograph (VIRUS-P) on the 2.7 meter Harlan J. Smith Telescope at McDonald Observatory mapping the full extent of M82’s northern outflow out to ~12kpc covering ~139 square arcminutes. We measured line ratios ([OIII]/Hβ, [OI]/Hα, [NII]/Hα), [SII]/Hα) for each spaxel in our fields. Using Ionization Diagnostic Diagrams (IDDs) we spatially map shock dominated regions which we show trace the biconical structure of the outflow. M82 is a local galaxy (z~0.000677) and the classical example of a starburst galaxy with vigorous outflows. As a result it has been comprehensively studied for nearly 50 years. However, we present the most sensitive and extensive map of the warm ionized gas to date from the disk to the Hα cap at ~12kpc.

  5. ZINGRS: Understanding Hot DOGs via the resolved radio continuum of W2246-0526

    NASA Astrophysics Data System (ADS)

    Hershey, Deborah; Ferkinhoff, Carl; Higdon, Sarah; Higdon, James L.; Tidwell, Hannah; Brisbin, Drew; Lamarche, Cody; Vishwas, Amit; Nikola, Thomas; Stacey, Gordon J.

    2018-06-01

    We present new high-resolution (~0.5”) radio-continuum images of the high-redshift galaxy W2246-0526 obtained with the Jansky Very Large Array. W2246 at z~4.6 is a hot dust obscured galaxy (Hot DOG) that have extreme luminosities, LIR > 1014 L⊙ produced by hot T~450 K dust. It hosts both an active galactic nucleus and significant star formation. Having observed the [OIII] 88 micron line from W2246 with our ZEUS spectrometer, the source is part of our ZEUS INvestigate Galaxy Reference Sample (ZINGRS). The radio images are initial observations from the ZINGRS Radio Survey where we observe the free-free and non-thermal emissions of high-z galaxies. Combining the radio emission with ALMA and ZEUS observations of the [CII] 158 micron, [OIII] 88 micron and [NII] 122 micron lines we probe the metallicity, age of stellar population, and ionization parameter. For W2246 we pay special attention to gradients of the stellar age and metallicity to determine the impact of the AGN on the host galaxy. Our work here is our initial analysis. When complete for all of ZINGRS ours findings will improve our understanding of early galaxies, including helping to explain Hot DOGs like W2246.

  6. Sharing lattice QCD data over a widely distributed file system

    NASA Astrophysics Data System (ADS)

    Amagasa, T.; Aoki, S.; Aoki, Y.; Aoyama, T.; Doi, T.; Fukumura, K.; Ishii, N.; Ishikawa, K.-I.; Jitsumoto, H.; Kamano, H.; Konno, Y.; Matsufuru, H.; Mikami, Y.; Miura, K.; Sato, M.; Takeda, S.; Tatebe, O.; Togawa, H.; Ukawa, A.; Ukita, N.; Watanabe, Y.; Yamazaki, T.; Yoshie, T.

    2015-12-01

    JLDG is a data-grid for the lattice QCD (LQCD) community in Japan. Several large research groups in Japan have been working on lattice QCD simulations using supercomputers distributed over distant sites. The JLDG provides such collaborations with an efficient method of data management and sharing. File servers installed on 9 sites are connected to the NII SINET VPN and are bound into a single file system with the GFarm. The file system looks the same from any sites, so that users can do analyses on a supercomputer on a site, using data generated and stored in the JLDG at a different site. We present a brief description of hardware and software of the JLDG, including a recently developed subsystem for cooperating with the HPCI shared storage, and report performance and statistics of the JLDG. As of April 2015, 15 research groups (61 users) store their daily research data of 4.7PB including replica and 68 million files in total. Number of publications for works which used the JLDG is 98. The large number of publications and recent rapid increase of disk usage convince us that the JLDG has grown up into a useful infrastructure for LQCD community in Japan.

  7. Cosmic Dawn Intensity Mapper (CDIM): a New Probe of Cosmic Dawn and Reionization

    NASA Astrophysics Data System (ADS)

    Chang, Tzu-Ching; CDIM Team

    2018-01-01

    The Cosmic Dawn Intensity Mapper, CDIM, is a NASA Probe-class Mission Study currently under study. CDIM is designed to be a near-IR survey instrument optimized for Cosmic Dawn and reionization sciences, answering critical questions on how and when galaxies and quasars first formed, the history of metal build-up, and the history and topology of reionization, among other questions. CDIM will provide R=300 spectroscopic imaging over ~10 sq. degree instantaneous field of view at 1 arcsecond resolution, over the wavelength range of 0.75 to 7.5 mm. A two-tiered wedding-cake survey will consist of a shallow tier spanning close to 300 deg2 and a deep tier of about 25 deg2. CDIM survey data will allow us to (i) determine spectroscopic redshifts of WFIRST-detected Lyman-break galaxies (LBGs) out to a redshift of 10; (ii) establish the environmental dependence of star formation during reionization through clustering and other environmental measurements; (iii) establish the metal abundance of first-light galaxies during reionization over two decades of stellar mass by spectrally separating NII from Hα, and detecting both Hβ and [OIII]; (iv) measure 3D tomographic intensity fluctuations during reionization in both Lyα at z > 6 and Hα at 0 < z < 10; and (v) cross-correlating intensity fluctuations with 21-cm data to establish the topology of reionization bubbles.

  8. A dataset of multiresolution functional brain parcellations in an elderly population with no or mild cognitive impairment.

    PubMed

    Tam, Angela; Dansereau, Christian; Badhwar, AmanPreet; Orban, Pierre; Belleville, Sylvie; Chertkow, Howard; Dagher, Alain; Hanganu, Alexandru; Monchi, Oury; Rosa-Neto, Pedro; Shmuel, Amir; Breitner, John; Bellec, Pierre

    2016-12-01

    We present group eight resolutions of brain parcellations for clusters generated from resting-state functional magnetic resonance images for 99 cognitively normal elderly persons and 129 patients with mild cognitive impairment, pooled from four independent datasets. This dataset was generated as part of the following study: Common Effects of Amnestic Mild Cognitive Impairment on Resting-State Connectivity Across Four Independent Studies (Tam et al., 2015) [1]. The brain parcellations have been registered to both symmetric and asymmetric MNI brain templates and generated using a method called bootstrap analysis of stable clusters (BASC) (Bellec et al., 2010) [2]. We present two variants of these parcellations. One variant contains bihemisphereic parcels (4, 6, 12, 22, 33, 65, 111, and 208 total parcels across eight resolutions). The second variant contains spatially connected regions of interest (ROIs) that span only one hemisphere (10, 17, 30, 51, 77, 199, and 322 total ROIs across eight resolutions). We also present maps illustrating functional connectivity differences between patients and controls for four regions of interest (striatum, dorsal prefrontal cortex, middle temporal lobe, and medial frontal cortex). The brain parcels and associated statistical maps have been publicly released as 3D volumes, available in .mnc and .nii file formats on figshare and on Neurovault. Finally, the code used to generate this dataset is available on Github.

  9. Spin tuning of electron-doped metal-phthalocyanine layers.

    PubMed

    Stepanow, Sebastian; Lodi Rizzini, Alberto; Krull, Cornelius; Kavich, Jerald; Cezar, Julio C; Yakhou-Harris, Flora; Sheverdyaeva, Polina M; Moras, Paolo; Carbone, Carlo; Ceballos, Gustavo; Mugarza, Aitor; Gambardella, Pietro

    2014-04-09

    The spin state of organic-based magnets at interfaces is to a great extent determined by the organic environment and the nature of the spin-carrying metal center, which is further subject to modifications by the adsorbate-substrate coupling. Direct chemical doping offers an additional route for tailoring the electronic and magnetic characteristics of molecular magnets. Here we present a systematic investigation of the effects of alkali metal doping on the charge state and crystal field of 3d metal ions in Cu, Ni, Fe, and Mn phthalocyanine (Pc) monolayers adsorbed on Ag. Combined X-ray absorption spectroscopy and ligand field multiplet calculations show that Cu(II), Ni(II), and Fe(II) ions reduce to Cu(I), Ni(I), and Fe(I) upon alkali metal adsorption, whereas Mn maintains its formal oxidation state. The strength of the crystal field at the Ni, Fe, and Mn sites is strongly reduced upon doping. The combined effect of these changes is that the magnetic moment of high- and low-spin ions such as Cu and Ni can be entirely turned off or on, respectively, whereas the magnetic configuration of MnPc can be changed from intermediate (3/2) to high (5/2) spin. In the case of FePc a 10-fold increase of the orbital magnetic moment accompanies charge transfer and a transition to a high-spin state.

  10. J-Plus: Measuring Ha Emission Line Flux In The Nearby Universe

    NASA Astrophysics Data System (ADS)

    Logroño-García, Rafael; Vilella-Rojo, Gonzalo; López-San Juan, Carlos; Varela, Jesús; Viironen, Kerttu

    2017-10-01

    In the present presentation we aim to validate the methodology designed to extract the Ha emission line flux from J-PLUS data, a twelve optical filter survey carried out with the 2 deg² field of view T80Cam camera, mounted at the JAST/T80 telescope in the OAJ, Teruel, Spain. We use the information of the twelve J-PLUS bands, including the J0660 narrow-band filter located at rest-frame Ha, over 42 deg² to extract de-reddened and [NII] decontaminated Ha emission line fluxes of 46 star-forming regions with previous SDSS and/or CALIFA spectroscopic information. The agreement of the J-PLUS photometric Ha flux and the spectroscopic one is remarkable, with a ratio R = 1,01 +/- 0,27. This demonstrates that we are able to recover reliable Ha fluxes from J-PLUS photometric data. With an expected final area of 8,500 deg2, the large J-PLUS footprint will permit the study of the spatially resolved star formation rate of thousands nearby galaxies at z 0,015, as well as the influence of the close environment. As an illustrative example, we looked to the close pair of interacting galaxies NGC3994 and NGC3995, finding an enhancement of the star formation rate not only in the central part of NGC3994 but also in outer parts of the disc.

  11. novPTMenzy: a database for enzymes involved in novel post-translational modifications

    PubMed Central

    Khater, Shradha; Mohanty, Debasisa

    2015-01-01

    With the recent discoveries of novel post-translational modifications (PTMs) which play important roles in signaling and biosynthetic pathways, identification of such PTM catalyzing enzymes by genome mining has been an area of major interest. Unlike well-known PTMs like phosphorylation, glycosylation, SUMOylation, no bioinformatics resources are available for enzymes associated with novel and unusual PTMs. Therefore, we have developed the novPTMenzy database which catalogs information on the sequence, structure, active site and genomic neighborhood of experimentally characterized enzymes involved in five novel PTMs, namely AMPylation, Eliminylation, Sulfation, Hydroxylation and Deamidation. Based on a comprehensive analysis of the sequence and structural features of these known PTM catalyzing enzymes, we have created Hidden Markov Model profiles for the identification of similar PTM catalyzing enzymatic domains in genomic sequences. We have also created predictive rules for grouping them into functional subfamilies and deciphering their mechanistic details by structure-based analysis of their active site pockets. These analytical modules have been made available as user friendly search interfaces of novPTMenzy database. It also has a specialized analysis interface for some PTMs like AMPylation and Eliminylation. The novPTMenzy database is a unique resource that can aid in discovery of unusual PTM catalyzing enzymes in newly sequenced genomes. Database URL: http://www.nii.ac.in/novptmenzy.html PMID:25931459

  12. The ZINGRS Radio Survey: Probing metallicities at high-z with far-IR fine-structure lines and the radio continuum

    NASA Astrophysics Data System (ADS)

    Ferkinhoff, Carl; Higdon, Sarah; Higdon, James L.; Tidwell, Hannah; Rangel, Miguel; Vishwas, Amit; Nikola, Thomas; Stacey, Gordon J.; Brisbin, Drew

    2017-01-01

    The present day Universe is rich in metals that enable efficient cooling of gas in the ISM in order to form stars, create planets and make the building blocks of life as we know it. The Universe did not start in this state - we know that metals had to build up over time with successive generations of stars. Revealing the details of this evolution, however, is challenging and requires probes of metallicity that are not susceptible to dust extinction nor exhibit the degeneracies common to tracers in the visible regime. One possible indicator combines the far-IR fine structure lines with the radio continuum. Recently we have undertaken a multi-band radio continuum survey with the JVLA of high-z galaxies from ZINGRS. These observations will constrain the galaxies’ thermal and nonthermal radio emissions and demonstrate the use of far-IR lines together with radio continuum as a metallicity indicator. ZINGRS, the ZEUS 1 and 2 INvestigated Galaxy Reference Sample, includes ~30 galaxies from z ~ 1 - 4.5 for which the far-IR fine-structure lines (e.g. [CII] 158, [NII] 122, [OIII] 88) have been observed with the ZEUS-1 and 2 instruments. This is the largest collection of far-IR fine-structure line detections at high-z and is ideal for demonstrating the use of this new indicator. Here we describe the theory behind the new indicator, give an overview of ZINGRS, and report on the status of our radio survey.

  13. An Isotopic Exchange Kinetic Model to Assess the Speciation of Metal Available Pool in Soil: The Case of Nickel.

    PubMed

    Zelano, I O; Sivry, Y; Quantin, C; Gélabert, A; Maury, A; Phalyvong, K; Benedetti, M F

    2016-12-06

    In this study an innovative approach is proposed to predict the relative contribution of each mineral phase to the total metal availability in soils, which, in other words, could be called the available metal fractionation. Through the use of isotopic exchange kinetics (IEK) performed on typical Ni bearing phases (i.e., two types of serpentines, chlorite, smectite, goethite, and hematite) the isotopic exchange and metal-solid interaction processes are connected, considering both the thermodynamic and kinetic aspects. Results of Ni IEK experiments on mineral phases are fitted with a pseudo-first order kinetic model. For each Ni bearing phase, this allows to (i) determine the number and size of exchangeable pools (E Ni(i) ), (ii) assess their corresponding kinetic constants (k (i) ), and (iii) discuss the mechanism of Ni isotopic exchange at mineral surfaces. It is shown that all the phases investigated, with the only exception of hematite, present at least two distinct reactive pools with significantly different k (i) values. Results suggest also that metal involved in outer-sphere complexes would display isotopic exchange between 100 and 1000 times faster than metal involved in inner-sphere complexes, and that the presence of high and low affinity sites may influence the rate of isotopic exchange up to 1 order of magnitude. Moreover, the method developed represents a tool to predict and estimate Ni mobility and availability in natural soil samples on the basis of soil mineral composition, providing information barely obtained with other techniques.

  14. Pentaarylcyclopentadienyl Iron, Cobalt, and Nickel Halides.

    PubMed

    Chakraborty, Uttam; Modl, Moritz; Mühldorf, Bernd; Bodensteiner, Michael; Demeshko, Serhiy; van Velzen, Niels J C; Scheer, Manfred; Harder, Sjoerd; Wolf, Robert

    2016-03-21

    The preparation of new stable half-sandwich transition metal complexes, having a bulky cyclopentadienyl ligand C5(C6H4-4-Et)5 (Cp(Ar1)) or C5(C6H4-4-nBu)5 (Cp(Ar2)), is reported. The tetrahydrofuran (THF) adduct [Cp(Ar1)Fe(μ-Br)(THF)]2 (1a) was synthesized by reacting K[Cp(Ar1)] with [FeBr2(THF)2] in THF, and its molecular structure was determined by X-ray crystallography. Complex 1a easily loses its coordinated THF molecules under vacuum to form the solvent-free complex [Cp(Ar1)Fe(μ-Br)]2 (1b). The analogous complexes [Cp(Ar1)Co(μ-Br)]2 (2), [Cp(Ar1)Ni(μ-Br)]2 (3), and [Cp(Ar2)Ni(μ-Br)]2 (4) were synthesized from CoBr2 and [NiBr2(1,2-dimethoxyethane)]. The mononuclear, low-spin cobalt(III) and nickel(III) complexes [Cp(Ar2)MI2] (5, M = Co; 6, M = Ni) were prepared by reacting the radical Cp(Ar2) with NiI2 and CoI2. The complexes were characterized by NMR and UV-vis spectroscopies and by elemental analyses. Single-crystal X-ray structure analyses revealed that the dimeric complexes 1a, 1b, and 3 have a planar M2Br2 core, whereas 2 and 4 feature a puckered M2Br2 ring.

  15. Star Formation and AGN Activity in Ultraluminous Infrared Galaxies at z > 1.15

    NASA Astrophysics Data System (ADS)

    Baldassare, Vivienne; Kartaltepe, J.

    2012-01-01

    We studied active galactic nucleus (AGN) activity and star formation in a sample of 52 luminous and ultraluminous infrared galaxies ((U)LIRGs) with 1.17 < z < 1.602 and LIR > 1011.5 Lsolar. ULIRGs get their extreme infrared luminosities from the heating of dust by star formation and/or AGN. Studies done in the local universe have revealed that all local ULIRGs are mergers (Sanders & Mirabel 1996), and have proposed evolutionary schemes in which early merger stages are dominated by starbursts, intermediate merger stages are dominated by starburst-AGN composite objects, and late merger stages are dominated by AGN (Yuan et al. 2010). They have also shown that most ULIRGs with LIR > 1012.4-12.5 Lsolar appear AGN-like (Tran et al. 2001). We used near infrared spectroscopy in order to determine whether these trends extend to high redshift, utilizing the [NII]/H-alpha and [OIII]/H-beta line ratios to plot our objects on a BPT diagram which classifies them as star forming, AGN, or composite. We find that many of the objects in our sample show evidence of mergers or interactions, and that all objects in our sample with LIR >1012.5 Lsolar are AGN or composite objects. Vivienne Baldassare was supported by the NOAO/KPNO Research Experiences for Undergraduates (REU) Program which is funded by the National Science Foundation Research Experiences for Undergraduates Program and the Department of Defense ASSURE program through Scientific Program Order No. 13 (AST-0754223) of the Cooperative Agreement No. AST-0132798 between the Association of Universities for Research in Astronomy (AURA) and the NSF.

  16. Nuclear Rings in the IR: Hidden Super Star Clusters

    NASA Astrophysics Data System (ADS)

    Maoz, Dan

    1997-07-01

    We propose NICMOS broad-band {F160W, F187W} and Paschen Alpha {F187N} imaging of nuclear starburst rings in two nearby galaxies. We already have UV {F220W} FOC data, and are scheduled to obtain WFPC2 images in U, V, I, and Halpha+[NII] of these rings. The rings contain large populations of super star clusters similar to those recently discovered in other types of starburst systems. Nuclear rings contain large numbers of these clusters in relatively unobscured starburst environments. Measurement of the age, size, and stellar contents of the clusters can test the hypothesis that super star clusters are young globular clusters. Together with our UV and optical data, NICMOS images will provide the SED of numerous super star clusters over a decade in wavelength. Our already-approved observations will allow us to estimate, by comparison with evolutionary synthesis models, the masses and ages of the clusters. The proposed IR data will be sensitive to the number of supergiants {1.6 micron} and O-stars {Paschen Alpha} in each of the clusters. The observations will provide an independent determination of the reddening, mass, and age of each cluster. We expect to see in the IR numerous clusters that are obscured in the UV and optical. These clusters may be the younger ones, which are still embedded in their molecular clouds. By measuring the mass, age, and size of a large number of clusters, we can actually obtain an evolutionary picture of these objects at different stages in their lives.

  17. Newly Discovered Be Stars in the Large Magellanic Cloud

    NASA Astrophysics Data System (ADS)

    Reid, W. A.

    2016-11-01

    The Large Magellanic Cloud (LMC) is a excellent laboratory in which to analyse and compare the distinctive characteristics of massive and luminous emission-line stars. In particular, the known and almost co-equal distance to all objects greatly assists the study of comparative luminosities. The original UKST Hα survey covering the central 25deg2 of the LMC revealed 518 Be stars, 413 of which were new discoveries. By extending the survey to cover the entire LMC area of 64 deg2, an additional 415 emission-line stars were identified. Most of the additions have now been spectroscopically observed, with the majority being confirmed as Be stars. The flux, equivalent width, and width at half maximum of the main emission-lines for each of the ˜800 spectroscopically observed LMC Be stars were measured in order to understand their elemental composition and the interaction of the extended circumstellar disk. After subtracting foreground or ambient dust and gas emission, 130 or 22% of B stars were classified as type B[e], characterized by the presence of forbidden emission lines such as [SII], [NII], [OIII] and [OII]. With de-reddened data, the first V-band and Hα luminosity functions were constructed for these stars in the LMC. The magnitudes were then compared using U, B, V, I, R, near-IR J, H, K and mid-IR photometry from the Magellanic Cloud Emission-Line Survey, SuperCOSMOS, 2MASS, and WISE where available. Correlations of varying strength between the optical, IR and Hα magnitudes are shown and discussed.

  18. Characteristics of the Japanese Diet Described in Epidemiologic Publications: A Qualitative Systematic Review.

    PubMed

    Suzuki, Nozomu; Goto, Yoshihito; Ota, Haruka; Kito, Kumiko; Mano, Fumika; Joo, Erina; Ikeda, Kaori; Inagaki, Nobuya; Nakayama, Takeo

    2018-01-01

    International interest in the Japanese diet has grown in recent years. The aim of this systematic review was to evaluate and organize the Japanese diet and dietary characteristics from an epidemiological perspective, mainly focusing on the nutritional and dietary elements. PubMed, Web of Science, Japan Medical Abstracts Society, JDream III, and CiNii databases were searched. The eligibility criteria included research with an epidemiological study design that was either cross-sectional, cohort, or case-control-based that defined the dietary patterns of the Japanese diet using dietary pattern analysis. A total of 39 research articles that described the Japanese diet were included. The data that were extracted included the following: implementing country, location, study design, participant characteristics, key outcomes, methods used in the analysis of dietary patterns, and descriptions of the Japanese diet. As a result of the systematic review analyzing the descriptions of the Japanese diet from 39 selected articles, we were able to aggregate the descriptions into 16 categories from 33 factors. After performing a content analysis using a further aggregation of categories, we found that the top three applicable categories were soybeans/soybean-derived products, seafood, and vegetables; these were followed by rice and miso soup. The Japanese dietary content was found to be diverse based on an examination of epidemiological studies; however, we were able to aggregate the content into 16 categories. The Japanese diet is considered to be a dietary pattern that contains a combination of factors: the dietary staple, side dishes, and soup.

  19. Two pathways for electrocatalytic oxidation of hydrogen by a nickel bis(diphosphine) complex with pendant amines in the second coordination sphere.

    PubMed

    Yang, Jenny Y; Smith, Stuart E; Liu, Tianbiao; Dougherty, William G; Hoffert, Wesley A; Kassel, W Scott; Rakowski DuBois, M; DuBois, Daniel L; Bullock, R Morris

    2013-07-03

    A nickel bis(diphosphine) complex containing pendant amines in the second coordination sphere, [Ni(P(Cy)2N(t-Bu)2)2](BF4)2 (P(Cy)2N(t-Bu)2 = 1,5-di(tert-butyl)-3,7-dicyclohexyl-1,5-diaza-3,7-diphosphacyclooctane), is an electrocatalyst for hydrogen oxidation. The addition of hydrogen to the Ni(II) complex gives three isomers of the doubly protonated Ni(0) complex [Ni(P(Cy)2N(t-Bu)2H)2](BF4)2. Using the pKa values and Ni(II/I) and Ni(I/0) redox potentials in a thermochemical cycle, the free energy of hydrogen addition to [Ni(P(Cy)2N(t-Bu)2)2](2+) was determined to be -7.9 kcal mol(-1). The catalytic rate observed in dry acetonitrile for the oxidation of H2 depends on base size, with larger bases (NEt3, t-BuNH2) resulting in much slower catalysis than n-BuNH2. The addition of water accelerates the rate of catalysis by facilitating deprotonation of the hydrogen addition product before oxidation, especially for the larger bases NEt3 and t-BuNH2. This catalytic pathway, where deprotonation occurs prior to oxidation, leads to an overpotential that is 0.38 V lower compared to the pathway where oxidation precedes proton movement. Under the optimal conditions of 1.0 atm H2 using n-BuNH2 as a base and with added water, a turnover frequency of 58 s(-1) is observed at 23 °C.

  20. Imaging ultrafast excited state pathways in transition metal complexes by X-ray transient absorption and scattering using X-ray free electron laser source

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chen, Lin X.; Shelby, Megan L.; Lestrange, Patrick J.

    2016-01-01

    This report will describe our recent studies of transition metal complex structural dynamics on the fs and ps time scales using an X-ray free electron laser source, Linac Coherent Light Source (LCLS). Ultrafast XANES spectra at the Ni K-edge of nickel(II) tetramesitylporphyrin (NiTMP) were successfully measured for optically excited state at a timescale from 100 fs to 50 ps, providing insight into its sub-ps electronic and structural relaxation processes. Importantly, a transient reduced state Ni(I) (π, 3dx2-y2) electronic state is captured through the interpretation of a short-lived excited state absorption on the low-energy shoulder of the edge, which is aidedmore » by the computation of X-ray transitions for postulated excited electronic states. The observed and computed inner shell to valence orbital transition energies demonstrate and quantify the influence of electronic configuration on specific metal orbital energies. A strong influence of the valence orbital occupation on the inner shell orbital energies indicates that one should not use the transition energy from 1s to other orbitals to draw conclusions about the d-orbital energies. For photocatalysis, a transient electronic configuration could influence d-orbital energies up to a few eV and any attempt to steer the reaction pathway should account for this to ensure that external energies can be used optimally in driving desirable processes. NiTMP structural evolution and the influence of the porphyrin macrocycle conformation on relaxation kinetics can be likewise inferred from this study.« less

  1. Biosensing and bioremediation of Cr(VI) by cell free extract of Enterobacter aerogenes T2.

    PubMed

    Panda, Jigisha; Sarkar, Priyabrata

    2014-01-01

    Hexavalent chromium or Cr(VI) enters the environment through several anthropogenic activities and it is highly toxic and carcinogenic. Hence it is required to be detected and remediated from the environment. In this study, low-cost and environment-friendly methods of biosensing and bioremediation of Cr(VI) have been proposed. Crude cell free extract (CFE) of previously isolated Enterobacter aerogenes T2 (GU265554; NII 1111) was prepared and exploited to develop a stable biosensor for direct estimation of Cr(VI) in waste water, by using three electrodes via cyclic voltammetry. For bioremediation studies, a homogeneous solution of commercially available sodium alginate and CFE was added dropwise in a continuously stirred calcium chloride solution. Biologically modified calcium alginate beads were produced and these were further utilized for bioremediation studies. The proposed sensor showed linear response in the range of 10-40 μg L(-1) Cr(VI) and the limit of detection was found to be 6.6 μg L(-1) Cr(VI). No interference was observed in presence of metal ions, e.g., lead, cadmium, arsenic, tin etc., except for insignificant interference with molybdenum and manganese. In bioremediation studies, modified calcium alginate beads showed encouraging removal rate 900 mg Cr(VI)/m(3) water per day with a removal efficiency of 90%, much above than reported in literature. The proposed sensing system could be a viable alternative to costly measurement procedures. Calcium alginate beads, modified with CFE of E. aerogenes, could be used in bioremediation of Cr(VI) since it could work in real conditions with extraordinarily high capacity.

  2. A study of the trace sulfide mineral assemblages in the Stillwater Complex, Montana, USA

    NASA Astrophysics Data System (ADS)

    Aird, Hannah M.; Ferguson, Katherine M.; Lehrer, Malia L.; Boudreau, Alan E.

    2017-03-01

    The sulfide assemblages of the Stillwater Complex away from the well-studied ore zones are composed mainly of variable proportions of pyrrhotite, chalcopyrite, pentlandite, and ±pyrite. Excluding vein assemblages and those affected by greenschist and lower temperature alteration, the majority can be classified into two broad assemblages, defined here as pristine (multiphase, often globular in shape) or volatile-bearing (multiphase, high-temperature, volatile-rich minerals such as biotite, hornblende, or an unmixed calcite-dolomite assemblage). The volatile-bearing assemblages are mainly found within and below the J-M reef, where native copper and sphalerite are also locally present. Pristine sulfides are found throughout the stratigraphy. Both groups can be affected by apparent S loss in the form of pyrite being converted to magnetite and chalcopyrite to a Cu-Fe-oxide (delafossite), with little to no silicate alteration. An upward trend from pentlandite-rich to pyrrhotite-rich to pyrite-rich assemblages is observed in the footwall rocks in upper GN-I, and the same trend repeats from just below the reef and continues into the overlying N-II and GN-II. Modeling suggests that the sulfide Ni in the Peridotite Zone is largely controlled by silicate Ni. When taken together, observations are most readily explained by the remobilization of selected elements by a high-temperature fluid with the apparent loss of S > Cu > Ni. This could concentrate ore metals by vapor refining, eventually producing a platinum group element-enriched sulfide ore zone, such as the J-M reef.

  3. L'CO/LFIR Relations with CO Rotational Ladders of Galaxies Across the Herschel SPIRE Archive

    NASA Technical Reports Server (NTRS)

    Kamenetzky, J.; Rangwala, N.; Glenn, J.; Maloney, P. R.; Conley, A.

    2015-01-01

    We present a catalog of all CO (carbon monoxide) (J (total angular momentum quantum number) equals 1-0 through J equals 13-12), [CI], and [NII] lines available from extragalactic spectra from the Herschel SPIRE (Spectral and Photometric Imaging Receiver) Fourier Transform Spectrometer (FTS) archive combined with observations of the low-J CO lines from the literature and from the Arizona Radio Observatory. This work examines the relationships between L (sub FIR (Far Infra Red)), L prime (sub CO), and L (sub CO) / L (sub CO, 1-0). We also present a new method for estimating probability distribution functions (PDFs) from marginal signal-to-noise ratio Herschel FTS spectra, which takes into account the instrumental "ringing" and the resulting highly correlated nature of the spectra. The slopes of Log (L (sub FIR)) versus Log (L prime (sub CO)) are linear for all mid- to high-J CO lines. The mid- to high-J CO luminosity relative to CO J equals 1-0 increases with increasing L (sub FIR), indicating higher excitement of the molecular gas, though these ratios do not exceed approximately 100. The luminosities relative to CO J equals 1-0 remain relatively at from J equals 6-5 through J equals13-2, across many orders of magnitude of L (sub FIR). Qualitative comparisons to current theoretical models do not match these flat SLED (spectral line energy distributions) shapes, indicating the need for more comprehensive modeling of the excitation processes of warm molecular gas in nearby galaxies.

  4. Preparation for Retrievals from Sellafield Legacy Ponds Installation of the Gantry Refurbishment System

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ellison, M.

    2008-07-01

    Retrieval of sludge and fuel from the First Generation Magnox Fuel Storage Pond, and its safe long term storage is one of the NDA's top priorities in the UK clean up programme. The plant is currently undergoing a series of major modifications in preparation for the retrievals operations. The most visible example of these modifications is the Gantry Refurbishment System (GRS), a major work platform which has recently been lifted onto the pond long travel girders used by the Skip Handler. This paper describes the design, manufacture, works test, and site installation of this major piece of equipment. The installationmore » lift, involving the use of an 800Te crane was one of the largest lifts undertaken at Sellafield. The GRS is a mobile platform structure which is designed to be pushed or pulled along the long travel girders by the Skip Handler. Its principle function is to provide a safe and shielded working platform from which to undertake refurbishment of the Skip Handler long travel girders and support structure. The potential hazards and consequences resulting from the modification were fully understood and controls were put in place to ensure that the risk of carrying out the work was as low as reasonably practicable. The work was authorised by the NII, Sellafield Nuclear Safety Committee and an independent readiness review panel. Despite less than perfect weather in the run up to the lift, the GRS was successfully and safely lifted onto the pond on 18 October 2006, the culmination of three years of planning, engineering and construction. (authors)« less

  5. Studies on Anthropogenic Impact on Water Quality in Hilo (Hawaii) Bay and Mapping the Study Stations Using Geospatial Technologies

    NASA Astrophysics Data System (ADS)

    Cartier, A. J.; Williams, M. S.; Adolf, J.; Sriharan, S.

    2015-12-01

    Hilo Bay has uncharacteristically brown waters compared to other waters found in Hawai'i. The majority of the freshwater entering Hilo Bay is from storm and surface water runoff. The anthropogenic impact on water quality at Hilo Bay is due to sediment entrance, cesspools (Bacteria), and invasive species (Albizia). This poster presentation will focus on the water quality and phytoplankton collected on a weekly basis at a buoy positioned one meter from the shore of Hilo Bay, preserving the phytoplankton intact, concentrating and dehydrating the sample with ethanol, and viewing the phytoplankton with a scanning electron microscope (Hitachi S-3400NII). The GPS (Global Positioning System) points were collected at the sampling stations. Three transects on three separate dates were performed in Hilo Bay with salinity, percent dissolved oxygen, turbidity, secchi depth, temperature, and chlorophyll fluorescence data collected at each sampling station. A consistent trend observed in all transects was as distance from the river increased turbidity decreased and salinity increased. The GPS data on June 30, 2015 showed a major correlation between stations and their distance from shore. There is a decrease in the turbidity but not the temperature for these stations. The GPS points collected on July 7, 2015 at thirteen stations starting with station one being at the shore to the water, showed that the salinity concentration fluctuate noticeably at the first 6 stations. As we proceed further away from the shore, the salinity concentration increases from stations seven through thirteen. The water temperature shows little variation throughout the thirteen stations. The turbidity level was high at the shore and shows a noticeable drop at station thirteen.

  6. Virtual collaborative environments: programming and controlling robotic devices remotely

    NASA Astrophysics Data System (ADS)

    Davies, Brady R.; McDonald, Michael J., Jr.; Harrigan, Raymond W.

    1995-12-01

    This paper describes a technology for remote sharing of intelligent electro-mechanical devices. An architecture and actual system have been developed and tested, based on the proposed National Information Infrastructure (NII) or Information Highway, to facilitate programming and control of intelligent programmable machines (like robots, machine tools, etc.). Using appropriate geometric models, integrated sensors, video systems, and computing hardware; computer controlled resources owned and operated by different (in a geographic sense as well as legal sense) entities can be individually or simultaneously programmed and controlled from one or more remote locations. Remote programming and control of intelligent machines will create significant opportunities for sharing of expensive capital equipment. Using the technology described in this paper, university researchers, manufacturing entities, automation consultants, design entities, and others can directly access robotic and machining facilities located across the country. Disparate electro-mechanical resources will be shared in a manner similar to the way supercomputers are accessed by multiple users. Using this technology, it will be possible for researchers developing new robot control algorithms to validate models and algorithms right from their university labs without ever owning a robot. Manufacturers will be able to model, simulate, and measure the performance of prospective robots before selecting robot hardware optimally suited for their intended application. Designers will be able to access CNC machining centers across the country to fabricate prototypic parts during product design validation. An existing prototype architecture and system has been developed and proven. Programming and control of a large gantry robot located at Sandia National Laboratories in Albuquerque, New Mexico, was demonstrated from such remote locations as Washington D.C., Washington State, and Southern California.

  7. Human atrial natriuretic peptide treatment for acute heart failure: a systematic review of efficacy and mortality.

    PubMed

    Kobayashi, Daiki; Yamaguchi, Norihiro; Takahashi, Osamu; Deshpande, Gautam A; Fukui, Tsuguya

    2012-01-01

    The objectives of this study were to assess the effect of human atrial natriuretic peptide (hANP) treatment on physiological parameters and mortality in acute heart failure. The MEDLINE (1966-2009), EMBASE (1980-2009), Cochrane Central Register of Controlled Trials (1991-2009), American College of Physicians Journal Club (1991), Ichushi (Japana Centra Revuo Medicina) (1983-2009), Cinni (NII Scholarly and Academic Information Navigator) (1959-2009), National Diet Library Online Public Access Catalog (1969-2009), Webcat Plus (Japanese National Institute of Informatics) (1986-2009), Medical Online (1947-2009), and JST China (1981-2009) databases were searched for studies that compared the efficacy of hANP and the mortality in patients with acute heart failure with placebo controls. Only randomized controlled trials (RCTs) were included in the study. Out of 347 articles, a total of 4 studies involving 220 patients with acute heart failure fulfilled the predefined inclusion criteria. There were significant differences in the hemodynamic parameters between the hANP and placebo groups, especially in the pulmonary capillary wedge pressure (PCWP) reduction (standard mean difference [SMD] 2.07; 95% confidence interval [CI], 0.34-3.81) and the cardiac index (SMD 1.79; 95% CI, 0.12-3.47). No statistically significant differences in mortality rates were found (relative risk 1.03; 95% CI, 0.27-3.92). In a limited number of studies, hANP appears to improve several hemodynamic parameters, including pulmonary capillary wedge pressure and cardiac index, but not mortality. Further high-quality studies are needed to corroborate these results. Copyright © 2012 Canadian Cardiovascular Society. Published by Elsevier Inc. All rights reserved.

  8. The Distance to the Coma Cluster from the Tully--Fisher Relation

    NASA Astrophysics Data System (ADS)

    Herter, T.; Vogt, N. P.; Haynes, M. P.; Giovanelli, R.

    1993-12-01

    As part of a survey to determine the distances to nearby (z < .04) Abell clusters via application of the Tully--Fisher (TF) relation, we have obtained 21 cm HI line widths, optical rotation curves and photometric I--band CCD images of galaxies within and near the Coma cluster. Because spiral galaxies within the cluster itself are HI deficient and thus are detected marginally or not at all in HI, distance determinations using only the radio TF relation exclude true cluster members. Our sample includes eight HI deficient galaxies within 1.5 degrees of the cluster center, for which optical velocity widths are derived from their Hα and [NII] rotation curves. The 21 cm line widths have been extracted using a new algorithm designed to optimize the measurement for TF applications, taking into account the effects of spectral resolution and smoothing. The optical width is constructed from the velocity histogram, and is therefore a global value akin to the HI width. A correction for turbulent broadening of the HI is derived from comparison of the optical and HI widths. Using a combined sample of 260 galaxies in 11 clusters and an additional 30 field objects at comparable distances, we have performed a calibration of the radio and optical analogs of the TF relation. Preliminary results show a clear linear relationship with a small offset between optical and radio widths, and good agreement in deriving Tully--Fisher distances to clusters. Our Coma sample consists of 28 galaxies with optical widths and 42 with HI line widths, with an overlapping set of 20 galaxies. We will present the data on the Coma cluster, and discuss the results of our analysis.

  9. The BAT AGN Spectroscopic Survey (BASS) DR1-Spectral Measurements, Derived Quantities, and AGN Demographics

    NASA Astrophysics Data System (ADS)

    Koss, Michael; BASS Team

    2018-01-01

    We present the first catalog and data release of the Swift-BAT AGN Spectroscopic Survey (BASS). We analyze optical spectra of the majority of AGN (77%, 641/836) detected based on their 14-195 keV emission in the 70-month Swift BAT all-sky catalog. This includes redshift determination, absorption and emission line measurements, and black hole mass and accretion rate estimates for the majority of obscured and un-obscured AGN (74%, 473/641) with 340 measured for the first time. With ~90% of sources at z<0.2, the survey represents a significant census of hard-X-ray selected AGN in the local universe. In this first catalog paper, we describe the spectroscopic observations and datasets, and our initial spectral analysis. The FWHM of the emission lines show broad agreement with the X-ray obscuration (~94%), such that Sy 1-1.8 have NH<10^21.9 cm^-2, and Seyfert 2, have NH>10^21.9 cm^-2. Seyfert 1.9 show a range of column densities. Compared to narrow line AGN in the SDSS, the X-ray selected AGN have a larger fraction of dusty host galaxies suggesting these types of AGN are missed in optical surveys. Using the most sensitive [OIII]/Hbeta and [NII]/Halpha emission line diagnostic, about half of the sources are classified as Seyferts, ~15% reside in dusty galaxies that lack an Hbeta detection, but for which the line upper limits imply either a Seyfert or LINER, ~15% are in galaxies with weak or no emission lines despite high quality spectra, and a few percent each are LINERS, composite galaxies, HII regions, or in known beamed AGN.

  10. Star-Formation in Free-Floating Evaporating Gaseous Globules

    NASA Astrophysics Data System (ADS)

    Sahai, Raghvendra

    2017-08-01

    We propose to study the stellar embryos in select members of a newly recognized class of Free-floating Evaporating Gaseous Globules (frEGGS) embedded in HII regions and having head-tail shapes. We discovered two of these in the Cygnus massive star-forming region (MSFR) with HST, including one of the most prominent members of this class (IRAS20324). Subsequent archival searches of Spitzer imaging of MSFRs has allowed us to build a statistical sample of frEGGs. Our molecular-line observations show the presence of dense molecular cores with total gas masses of (0.5-few) Msun in these objects, and our radio continuum images and Halpha images (from the IPHAS survey) reveal bright photo-ionized peripheries around these objects. We hypothesize that frEGGs are density concentrations originating in giant molecular clouds, that, when subject to the sculpting and compression by strong winds and UV radiation from massive stars, become active star-forming cores. For the 4 frEGGs with HST or near-IR AO images showing young stars and bipolar cavities produced by their jets or collimated outflows, the symmetry axis points roughly toward the external ionizing star or star cluster - exciting new evidence for our overpressure-induced star formation hypothesis. We propose to test this hypothesis by imaging 24 frEGGs in two nearby MSFRs that represent different radiation-dominated environments. Using ACS imaging with filters F606W, F814W, & F658N (Ha+[NII]), we will search for jets and outflow-excavated cavities, investigate the stellar nurseries inside frEGGs, and determine whether the globules are generally forming multiple star systems or small clusters, as in IRAS20324.

  11. Understanding The Heating And Cooling Of Galaxies Over Cosmic Time With BLISS on SPICA

    NASA Astrophysics Data System (ADS)

    Armus, Lee; Helou, G.; Bradford, M.; Murphy, E.; Appleton, P.

    2011-05-01

    In order to gain a comprehensive picture of galaxy evolution, we need to accurately measure the growing population of stars and super-massive black holes in dark matter halos. The processes that regulate this evolution are invariably those that are the most difficult to simulate, namely gas heating and cooling, star formation, black hole fueling and feedback from supernovae and AGN. Measurements of the PAH features, atomic fine-structure and H2 lines in the mid-infrared with Spitzer have been used successfully to probe the dust properties, power sources and state of the ISM in normal, starburst and AGN host galaxies at 0 < z < 3. At high redshifts, these lines enter the far-infrared, which is also home to critical diagnostics of the neutral and ionized ISM, such as [OI], [OIII], [NII], and [CII]. Recent results from Herschel, CSO, IRAM and APEX suggest that there is an extremely large range in far-infrared line fluxes and physical conditions among the most luminous, high-z galaxies. However, to measure the rest-frame far-infrared cooling lines in galaxies that dominate the far-infrared background, along with the full suite of mid-infrared atomic and molecular gas and dust features in ULIRGs over a wide range in redshift, a broadband spectrometer capable of reaching the natural astrophysical background over the 30-400 micron range is required. The Background Limited Infrared Sub-millimeter Spectrometer (BLISS) on the Japanese-led SPICA mission, would deliver unmatched sensitivity to evolving, dusty galaxies over all epochs. Here we discuss the scientific rationale behind BLISS and the opportunities afforded by US participation in the SPICA mission.

  12. Application of bimodal distribution to the detection of changes in uranium concentration in drinking water collected by random daytime sampling method from a large water supply zone.

    PubMed

    Garboś, Sławomir; Święcicka, Dorota

    2015-11-01

    The random daytime (RDT) sampling method was used for the first time in the assessment of average weekly exposure to uranium through drinking water in a large water supply zone. Data set of uranium concentrations determined in 106 RDT samples collected in three runs from the water supply zone in Wroclaw (Poland), cannot be simply described by normal or log-normal distributions. Therefore, a numerical method designed for the detection and calculation of bimodal distribution was applied. The extracted two distributions containing data from the summer season of 2011 and the winter season of 2012 (nI=72) and from the summer season of 2013 (nII=34) allowed to estimate means of U concentrations in drinking water: 0.947 μg/L and 1.23 μg/L, respectively. As the removal efficiency of uranium during applied treatment process is negligible, the effect of increase in uranium concentration can be explained by higher U concentration in the surface-infiltration water used for the production of drinking water. During the summer season of 2013, heavy rains were observed in Lower Silesia region, causing floods over the territory of the entire region. Fluctuations in uranium concentrations in surface-infiltration water can be attributed to releases of uranium from specific sources - migration from phosphate fertilizers and leaching from mineral deposits. Thus, exposure to uranium through drinking water may increase during extreme rainfall events. The average chronic weekly intakes of uranium through drinking water, estimated on the basis of central values of the extracted normal distributions, accounted for 3.2% and 4.1% of tolerable weekly intake. Copyright © 2015 Elsevier Ltd. All rights reserved.

  13. New perspectives for undoped CaF2 scintillator as a threshold activation neutron detector

    NASA Astrophysics Data System (ADS)

    Sibczynski, Pawel; Dziedzic, Andrzej; Grodzicki, Krystian; Iwanowska-Hanke, Joanna; Moszyński, Marek; Swiderski, Lukasz; Syntfeld-Każuch, Agnieszka; Wolski, Dariusz; Carrel, Frédérick; Grabowski, Amélie; Hamel, Matthieu; Laine, Frederic; Sari, Adrien; Iovene, Alessandro; Tintori, Carlo; Fontana, Cristiano; Pino, Felix

    2018-01-01

    In this paper we present the prompt photofission neutron detection performance of undoped CaF2 scintillator using Threshold Activation Detection (TAD). The study is carried out in the frame of C-BORD Horizon 2020 project, during which an efficient toolbox for high volume freight non-intrusive inspection (NII) is under development. Technologies for radiation monitoring are the part of the project. Particularly, detection of various radiological threats on country borders plays an important significant role in Homeland Security applications. Detection of illegal transfer of Special Nuclear Material (SNM) - 235U, 233U and 239Pu - is particular due to the potential use for production of nuclear weapon as well as radiological dispersal device (RDD) V known also as a "dirty bomb". This technique relies on activation of 19F nuclei in the scintillator medium by fast neutrons and registration of high-energy β particles and γ-rays from the decay of reaction products. The radiation from SNM is detected after irradiation in order to avoid detector blinding. Despite the low 19F(n,α)16N or 19F(n,p)19O reaction cross-section, the method could be a good solution for detection of shielded nuclear material. Results obtained with the CaF2 detector were compared with the previous study done for BaF2 and 3He detector. These experimental results were obtained using 252Cf source and 9 MeV Varian Linatron M9 linear accelerator (LINAC). Finally, performance of the prompt neutron detection system based on CaF2 will be validated at Rotterdam Seaport during field trails in 2018.

  14. GUSTO: Gal/Xgal U/LDB Spectroscopic-Stratospheric TeraHertz Observatory

    NASA Astrophysics Data System (ADS)

    Kidd Walker, Christopher; Kulesa, Craig; Goldsmith, Paul; Groppi, Christopher; Helmich, Frank; Hollenbach, David; Kawamura, Jonathan; Langer, William; Melnick, Gary; Neufeld, David; Pineda, Jorge; Stacey, Gordon; Stark, Antony; Tielens, Alexander; Wolfire, Mark; Yorke, Harold; Young, Erick

    2018-01-01

    GUSTO is a recently selected NASA Explorer mission that will map in unprecedented detail the structure, dynamics, energy balance, and evolution of the interstellar medium within the Milky Way and Large Magellanic Cloud. GUSTO is a balloon-borne, 0.85-m on-axis telescope that will observe in three important interstellar lines: [CII], [OI], and [NII] at 158, 63, and 205 microns, respectively. With its 60" angular resolution, high-velocity resolution, and efficient “On-The-Fly” mapping strategy, GUSTO will address key unanswered questions about the stellar life cycle and provide new insights into the birth and evolution of stars and galaxies. From its Ultra-Long-Duration Balloon (ULDB) platform at an altitude of 33 km, GUSTO will survey ~100 deg2 of the Milky Way and 24 deg2 of the LMC at 60" angular resolution using three 8-pixel heterodyne array receivers. The GUSTO receivers provide sub-km/s velocity resolution and bandwidths sufficiently wide to track all clouds orbiting in the Milky Way and LMC. GUSTO will detect and locate in three dimensions every important interstellar cloud (AV > 0.5–1) in the surveyed regions. The baseline mission of 100 days can be completed in one ULDB Antarctic balloon flight, and an extended mission of up to 169 days is possible. GUSTO’s observing campaign comprises three distinct surveys: GPS: A Galactic Plane Survey (42 days); LMCS: An LMC Survey (36 days); TDS: Targeted Deep Surveys of selected regions in the Galaxy and LMC (18 days). In our presentation we will discuss both the science goals of GUSTO and the mission implementation.

  15. Long-Term Functional Outcome of Symptomatic Unruptured Intracranial Aneurysms in an Interdisciplinary Treatment Concept.

    PubMed

    Kunz, Mathias; Dorn, Franziska; Greve, Tobias; Stoecklein, Veit; Tonn, Joerg-Christian; Brückmann, Hartmut; Schichor, Christian

    2017-09-01

    In symptomatic unruptured intracranial aneurysms (UIAs), data on long-term functional outcome are sparse in the literature, even in the light of modern interdisciplinary treatment decisions. We therefore analyzed our in-house database for prognostic factors and long-term outcome of neurologic symptoms after microsurgical/endovascular treatment. Patients treated between 2000 and 2016 after interdisciplinary vascular board decision were included. UIAs were categorized as symptomatic in cases of cranial nerve or brainstem compression. Symptoms were categorized as mild/severe. Long-term development of symptoms after treatment was assessed in a standardized and independent fashion. Of 98 symptomatic UIAs (microsurgery/endovascular 43/55), 84 patients presented with cranial nerve (NII-VI) compression and 14 patients with brainstem compression symptoms. Permanent morbidity occurred in 9% of patients. Of 119 symptoms (mild/severe 71/48), 60.4% recovered (full/partial 22%/39%) and 29% stabilized by the time of last follow-up; median follow-up was 19.5 months. Symptom recovery was higher in the long-term compared with that at discharge (P = 0.002). Optic nerve compression symptoms were less likely to improve compared with abducens nerve palsies and brainstem compression. Prognostic factors for recovery were duration and severity of symptoms, treatment modality (microsurgery) and absence of ischemia in the multivariate analysis. This recent study presents for the first time a detailed analysis of relevant prognostic factors for long-term recovery of cranial nerve/brainstem compression symptoms in an interdisciplinary treatment concept, which was excellent in most patients, with lowest recovery rates in optic nerve compression. Symptom recovery was remarkably higher in the long-term compared with recovery at discharge. Copyright © 2017 Elsevier Inc. All rights reserved.

  16. Martensitic transformations, structure, and strengthness of processed high-nitrogen and high-carbon ferrous alloys

    NASA Astrophysics Data System (ADS)

    Kaputkina, L. M.; Prokoshkina, V. G.

    2003-10-01

    Structures and properties of metastable austenitic alloys Fe-18Cr-16Ni-I2Mn-(0.17 to 0. 50)N, Fe-18Cr-12Mn-(0.48 to 1.12)N, Fe-18Cr-(0.1 to 1.18)N, and Fe-(12 to 20)Ni-(0.6 to 1.3)C, Fe-(6 to 8)Mn-(0.6 to 1.0)C, Fe-(5 to 6)Cr-(4 to 5)Mn-(0.6 to 0.8)C, Fe-6Cr-(1.0 to 1.3)C resulting from martensitic transformations under cooling and cold deformation (CD), as well as following tempering processes, were studied by magnetometry, X-ray and electron microscopy analyses, hardness measurements and mechanical properties tests. Martensite with a b.c.t. lattice was formed in all alloys with M_s{>}-196^circC during cooling. Under CD transformations of γ{to}α, γ{to}\\varepsilon{to}α, or γ{to}\\varepsilon types were realized depending on the alloy composition. Carbon increased but nitrogen decreased stacking fault energy. Thus carbon assists α-martensite formation but nitrogen promotese. As CD level and/or concentration of carbon and nitrogen increase residual stresses resulting from the CD also increase. The martensitic transformation during CD can decrease the residual stresses. Kinetic of tempering of b.c.t. thermal martensite differs from those of CD-induced martensite. In the second case, deformation aging, texture, and residual stresses are more visible. The maximal strengthening under CD takes place in (Mn+N)-steels. (Cr+N) and (Cr+Mn+N)-steels are high-strength, non-magnetic and corrosion resistant and are easily hardened by a low level of plastic deformation.

  17. Hot interstellar gas and ionization of embedded clouds

    NASA Technical Reports Server (NTRS)

    Cheng, K.-P.; Bruhweiler, F.

    1990-01-01

    Researchers present detailed photoionization calculations for the instellar cloud in which the Sun is embedded. They consider the EUV radiation field with contribution from discrete stellar sources and from a thermal bremsstrahlung-radiative recombination spectrum emitted from the surrounding 10 to the 6th power k coronal substrate. They establish lower limits to the fractional ionization of hydrogen and helium of 0.17 and 0.29 respectively. The high He ionization fraction results primarily from very strong line emission below 500 A originating in the surrounding coronal substrate while the H ionization is dominated by the EUV radiation from the discrete stellar sources. The dual effects of thermal conduction and the EUV spectrum of the 10 to the 6th k plasma on ionization in the cloud skin are explored. The EUV radiation field and Auger ionization have insignificant effects on the resulting ionic column densities of Si IV, C IV, N V and O VI through the cloud skin. Calculations show that the abundances of these species are dominated by collisional ionization in the thermal conduction front. Because of a low charge exchange rate with hydrogen, the ionic column density ratios of N (CIII)/N (CII) and N (NII)/N (NI) are dominated by the EUV radiation field in the local interstellar medium. These ratios should be important diagnostics for the EUV radiation field and serve as surrogate indicators of the interstellar He and H ionization fraction respectively. Spacecraft such as Lyman which is designed to obtain high resolution spectral data down to the Lyman limit at 912 A could sample interstellar lines of these ions.

  18. Distant intense starbursts: evidence for self-regulated star formation?

    NASA Astrophysics Data System (ADS)

    Lehnert, M. D.

    From an analysis of the Halpha and [NII]∼λ6583 rest-frame optical emission lines in a large sample of intensely star forming galaxies at z=1.3 to 2.7 observed with SINFONI on the ESO-VLT, we have reached a number of conclusions. The galaxies all have broad optical emission lines (sigma ˜50-250 km s-1) which are a function of the underlying star formation intensity as determined from the Halpha surface brightness. These broad lines are intrinsic to the galaxies and not due to beam smearing. The velocity dispersions appear to be related to the star formation intensity (Sigma SFR, star formation rate per unit area) of the form, sigma ˜ epsilon Sigma SFR1/2. This is a simple and direct relationship between the energy injection rate and the kinetic energy of the emission line gas with a coupling efficiency of epsilon . In this contribution, we outline a simple model whereby the energy output of massive stars, both mechanical and radiative, feeds a mass and energy cycle within the interstellar media of these distant galaxies. The mass and energy cycle pushes the global ISM towards the line of stability, Toomre parameter Q˜1, but only if the molecular gas captures, to some extent, the kinematics of the warm ionized gas as probed by the optical emission lines. In such a picture, the star formation intensity is self-regulating.} This work and many of the ideas presented here were developed in collaboration with L. Le Tiran, W. van Driel, P. Di Matteo (GEPI), N. Nesvadba, and F. Boulanger (IAS, Orsay, France).

  19. VizieR Online Data Catalog: Herschel FIR spectra of GOALS galaxies (Diaz-Santos+, 2017)

    NASA Astrophysics Data System (ADS)

    Diaz-Santos, T.; Armus, L.; Charmandaris, V.; Lu, N.; Stierwalt, S.; Stacey, G.; Malhotra, S.; van der Werf, P. P.; Howell, J. H.; Privon, G. C.; Mazzarella, J. M.; Goldsmith, P. F.; Murphy, E. J.; Barcos-Munoz, L.; Linden, S. T.; Inami, H.; Larson, K. L.; Evans, A. S.; Appleton, P.; Iwasawa, K.; Lord, S.; Sanders, D. B.; Surace, J. A.

    2018-04-01

    We have obtained FIR spectroscopic observations for 200 luminous infrared galaxies (LIRG) systems from the Great Observatories All-Sky LIRG Survey (GOALS; Armus+ 2009PASP..121..559A) using the Integral Field Spectrometer (IFS) of the PACS instrument on board Herschel. Since some targets contain multiple components, there are 241 individual galaxies with available spectra in at least one emission line. Most of the data were collected as part of our OT1 and OT2 programs (OT1larmus1, OT2larmus1; P.I.: L. Armus), accounting for more than 200hr of observing time in total. Additional observations that are publicly available in the Herschel archive were included from various projects. The main programs from where these complementary data were gathered are KPGTesturm1 (P.I.: E. Sturm), KPOTpvanderw1 (PI: P. van der Werf), and OT1dweedman1 (P.I.: D. Weedman). The IFS on PACS is able to perform simultaneous spectroscopy in the 51-73 or 70-105um and the 102-210um ranges. In addition to the PACS/IFS spectra, we obtained observations of the [NII]205 emission line using the SPIRE FTS for 121 galaxies in the GOALS sample (Lu+ 2017, J/ApJS/230/1 ; OT1nlu1; P.I.: N. Lu). As part of the Spitzer GOALS legacy program, all galaxies observed with Herschel/PACS have available Spitzer/IRS low-resolution, R~60-120 (SL module: 5.2-14.5um; LL module: 14-38um), and medium-resolution, R~600 (SH module: 9.9-19.6um; LH module: 18.7-37.2um), slit spectroscopy. (3 data files).

  20. The CCAT-prime Extreme Field-of-View Submillimeter Telescope on Cerro Chajnantor

    NASA Astrophysics Data System (ADS)

    Koopman, Brian; Bertoldi, Frank; Chapman, Scott; Fich, Michel; Giovanelli, Riccardo; Haynes, Martha P.; Herter, Terry L.; Murray, Norman W.; Niemack, Michael D.; Riechers, Dominik; Schilke, Peter; Stacey, Gordon J.; Stutzki, Juergen; CCAT-prime Collaboration

    2017-01-01

    CCAT-prime is a six meter aperture off-axis submillimeter telescope that we plan to build at 5600m elevation on Cerro Chajnantor in Chile. The CCAT-prime optics are based on a cross-Dragone design with high throughput and a wide field-of-view optimized to increase the mapping speed of next generation cosmic microwave background (CMB) observations. These characteristics make CCAT-prime an excellent platform for a wide range of next generation millimeter and submillimeter science goals, and a potential platform for CMB stage-IV measurements. Here we present the telescope design for CCAT-prime and review the science goals.Taking advantage of the high elevation site, the first generation instrument for CCAT-prime will measure seven different frequency bands from 350um to 3mm. These seven bands will enable precise measurements of the Sunyaev-Zel’dovich effects (SZE) by separating contributions from CMB, thermal SZE, kinetic SZE, bright submm galaxies, and radio sources with a goal of extracting the peculiar velocities from a large number of galaxy clusters. Additional science priorities for CCAT-prime include: Galactic Ecology studies of the dynamic intersteller medium by mapping the fine structure lines [CI], [CII] and [NII] as well as high-excitation CO lines at the shortest wavelength bands; high redshift intensity mapping of [CII] emission from star-forming galaxies that likely dominates cosmic reionization at z~5-9 to probe the Epoch of Reionization; and next generation CMB polarization measurements to constrain inflation and cosmological models. The CCAT-prime facility will further our understanding of astrophysical processes from moments after the Big Bang to the present-day evolution of the Milky Way.

  1. Measuring the Evolution of Stellar Populations And Gas Metallicity in Galaxies with Far-Infrared Space Spectroscopy

    NASA Astrophysics Data System (ADS)

    Stacey, Gordon

    We propose a study of the evolution of stellar populations and gas metallicities in about 80 nearby star forming galaxies based on mining the NASA data archives for observations of the [NIII] 57 µm, [OIII] 52 µm and/or 88 µm, [NII] 122 and [CII] 158 µm far-infrared (FIR) fine- structure lines and other archives for thermal radio continuum. These lines are powerful probes of both stellar populations and gas properties and our primary science derives from these tracers. For sources that show both signs of active galactic nuclei (AGN) and star formation, we will take advantage of the readily available NASA Spitzer IRS data base that includes mid-IR [NeII] 12.8 µm, [NeIII] 15.6 µm and [NeV] 14.3 µm, [OIV] 25.9 µm and PAH observations. These complementary data reveal the relative fractions of the FIR line emission that might arise from star formation and the narrow line regions (NLR) associated with an AGN, thereby providing a robust set of observations to compare with star formation models. Subsets of the FIR lines have been detected from hundreds of nearby galaxies. From both theoretical studies and the results of these pioneering observations we know that these lines can be powerful probes of stellar populations and star formation in galaxies. Here we plan to use various combinations of the lines to constrain (1) the age of the stellar populations (through lines that trace the hardness of the stellar radiation fields, hence stellar spectral type), (2) the degree of processing of the interstellar medium (through lines that trace growth of secondary to primary element abundances for example, the N/O ratio), (3) the efficiency of star formation (through growth in absolute abundances of N and O, the N/H and O/H ratios), and (4) the current day mass function of upper main sequence stars. Surprisingly, there has been no systematic study of the large sample of these line detections made with PACS on Herschel in order to truly assess and calibrate their diagnostic

  2. Herbal medicine (Hyeolbuchukeo-tang or Xuefu Zhuyu decoction) for treating primary dysmenorrhoea: protocol for a systematic review of randomised controlled trials.

    PubMed

    Jo, Junyoung; Leem, Jungtae; Lee, Jin Moo; Park, Kyoung Sun

    2017-06-15

    Primary dysmenorrhoea is menstrual pain without pelvic pathology and is the most common gynaecological condition in women. Xuefu Zhuyudecoction (XZD) or Hyeolbuchukeo-tang, a traditional herbal formula, has been used as a treatment for primary dysmenorrhoea. The purpose of this study is to assess the current published evidence regarding XZD as treatment for primary dysmenorrhoea. The following databases will be searched from their inception until April 2017: MEDLINE (via PubMed), Allied and Complementary Medicine Database (AMED), EMBASE, The Cochrane Library, six Korean medical databases (Korean Studies Information Service System, DBPia, Oriental Medicine Advanced Searching Integrated System, Research Information Service System, Korea Med and the Korean Traditional Knowledge Portal), three Chinese medical databases (China National Knowledge Infrastructure (CNKI), Wan Fang Database and Chinese Scientific Journals Database (VIP)) and one Japanese medical database (CiNii). Randomised clinical trials (RCTs) that will be included in this systematic review comprise those that used XZD or modified XZD. The control groups in the RCTs include no treatment, placebo, conventional medication or other treatments. Trials testing XZD as an adjunct to other treatments and studies where the control group received the same treatment as the intervention group will be also included. Data extraction and risk of bias assessments will be performed by two independent reviewers. The risk of bias will be assessed with the Cochrane risk of bias tool. All statistical analyses will be conducted using Review Manager software (RevMan V.5.3.0). This systematic review will be published in a peer-reviewed journal. The review will also be disseminated electronically and in print. The review will benefit patients and practitioners in the fields of traditional and conventional medicine. CRD42016050447. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2017

  3. Calibrating Star Formation: The Link between Feedback and Galaxy Evolution

    NASA Astrophysics Data System (ADS)

    Calzetti, Daniela

    2005-07-01

    Stellar feedback - the return of mass and energy from star formation to the interstellar medium - is one of the primary engines of galaxy evolution. Yet, the theoretical foundation of mechanical feedback is, to date, unconstrained by observations. We propose to investigate this fundamental aspect of star formation on a sample of two local actively star-forming galaxies, NGC4449, and Holmberg II. The two galaxies have been selected to occupy an unexplored, yet crucial for quantifying mechanical feedback, niche in the two-parameter space of star formation intensity and galaxy mass. ACS/WFC and WFPC2 narrow-band observations in the light of H-beta, [OIII], H-alpha, and [NII] will be obtained for both galaxies, in order to: {1} discriminate the feedback-induced shock fronts from the photoionization regions; {2} map the shocks inside and around the starburst regions; and {3} measure the energy budget of the star-formation-produced shocks. These observations, complemented by existing data, will yield: {1} the efficiency of the feedback, i.e. the fraction of the star formation's mechanical energy that is transported out of the starburst volume rather than confined or radiated away; {2} the dependence of this efficiency on the two fundamental parameters of star formation intensity and stellar mass. The high angular resolution of HST is crucial for separating the spatially narrow shock fronts { 5 pc, 0.25" at 4 Mpc} from the more extended photoionization fronts. The legacy from this project will be the most complete quantitative measurement of the energetics associated with feedback processes. We will secure the first milestone for placing feedback mechanisms on a solid physical ground, and for understanding quantitatively their role on the energetics, structure, and star formation history of galaxies at all redshifts.

  4. Reliability of Self-Reported Mobile Phone Ownership in Rural North-Central Nigeria: Cross-Sectional Study.

    PubMed

    Menson, William Nii Ayitey; Olawepo, John Olajide; Bruno, Tamara; Gbadamosi, Semiu Olatunde; Nalda, Nannim Fazing; Anyebe, Victor; Ogidi, Amaka; Onoka, Chima; Oko, John Okpanachi; Ezeanolue, Echezona Edozie

    2018-03-01

    mHealth practitioners seek to leverage the ubiquity of the mobile phone to increase the impact and robustness of their interventions, particularly in resource-limited settings. However, data on the reliability of self-reported mobile phone access is minimal. We sought to ascertain the reliability of self-reported ownership of and access to mobile phones among a population of rural dwellers in north-central Nigeria. We contacted participants in a community-based HIV testing program by phone to determine actual as opposed to self-reported mobile phone access. A phone script was designed to conduct these calls and descriptive analyses conducted on the findings. We dialed 349 numbers: 110 (31.5%) were answered by participants who self-reported ownership of the mobile phone; 123 (35.2%) of the phone numbers did not ring at all; 28 (8.0%) rang but were not answered; and 88 (25.2%) were answered by someone other than the participant. We reached a higher proportion of male participants (68/133, 51.1%) than female participants (42/216, 19.4%; P<.001). Self-reported access to mobile phones in rural and low-income areas in north-central Nigeria is higher than actual access. This has implications for mHealth programming, particularly for women's health. mHealth program implementers and researchers need to be cognizant of the low reliability of self-reported mobile phone access. These observations should therefore affect sample-size calculations and, where possible, alternative means of reaching research participants and program beneficiaries should be established. ©William Nii Ayitey Menson, John Olajide Olawepo, Tamara Bruno, Semiu Olatunde Gbadamosi, Nannim Fazing Nalda, Victor Anyebe, Amaka Ogidi, Chima Onoka, John Okpanachi Oko, Echezona Edozie Ezeanolue. Originally published in JMIR Mhealth and Uhealth (http://mhealth.jmir.org), 01.03.2018.

  5. Activation of heteroallenes by coordinatively unsaturated nickel(ii) alkyl complexes supported by the hydrotris(3-phenyl-5-methyl)pyrazolyl borate (Tp(Ph,Me)) ligand.

    PubMed

    Abubekerov, Mark; Eymann, Léonard Y M; Gianetti, Thomas L; Arnold, John

    2016-10-07

    Activation of sulfur containing heteroallenes by nickel(ii) alkyl complexes supported by the bulky hydrotris(3-phenyl-5-methylpyrazolyl)borate (Tp(Ph,Me)) ligand is described. Exposure of Tp(Ph,Me)NiCH2Ph (1a) and Tp(Ph,Me)NiCH2Si(CH3)3 (1b) to CS2 resulted in formation of the insertion products Tp(Ph,Me)Ni(η(2)-CS2)CH2Ph (2a) and Tp(Ph,Me)Ni(η(2)-CS2)CH2Si(CH3)3 (2b) in moderate yields. Reaction of 1a and MeNCS produced two species in a 1 : 1 ratio, identified as Tp(Ph,Me)Ni(η(2)-MeNC)CH2Ph (3) and Tp(Ph,Me)Ni(η(2)-MeNCS)SCH2Ph (4). Isolation of the unexpected insertion product (3) prompted an investigation into the activity of 1a-b in the presence of isocyanides (i.e.(t)BuNC), which resulted in isolation of Tp(Ph,Me)Ni(η(2-t)BuNC)CH2Ph (5a) and Tp(Ph,Me)Ni(η(2-t)BuNC)CH2Si(CH3)3 (5b). Similarly, reaction of 1a with OCS led to the isolation of a rare example of a Ni(i) carbonyl species Tp(Ph,Me)NiCO (6). Alternatively, complex 6 was also formed by exposure of 1a-b to an atmosphere of CO. Isolation of the intermediate species (Tp(Ph,Me)Ni(η(2)-CO)CH2TMS (7b) and Tp(Ph,Me)Ni(CO)(C(O)R, (8a-b) with R = Ph, TMS)) shed light on the formation of such species.

  6. The spatially resolved stellar population and ionized gas properties in the merger LIRG NGC 2623

    NASA Astrophysics Data System (ADS)

    Cortijo-Ferrero, C.; González Delgado, R. M.; Pérez, E.; Sánchez, S. F.; Cid Fernandes, R.; de Amorim, A. L.; Di Matteo, P.; García-Benito, R.; Lacerda, E. A. D.; López Fernández, R.; Tadhunter, C.; Villar-Martín, M.; Roth, M. M.

    2017-10-01

    We report on a detailed study of the stellar populations and ionized gas properties in the merger LIRG NGC 2623, analyzing optical integral field spectroscopy from the CALIFA survey and PMAS LArr, multiwavelength HST imaging, and OSIRIS narrow band Hα and [NII]λ6584 imaging. The spectra were processed with the starlight full spectral fitting code, and the results are compared with those for two early-stage merger LIRGs (IC 1623 W and NGC 6090), together with CALIFA Sbc/Sc galaxies. We find that NGC 2623 went through two periods of increased star formation (SF), a first and widespread episode, traced by intermediate-age stellar populations ISP (140 Myr-1.4 Gyr), and a second one, traced by young stellar populations YSP (<140 Myr), which is concentrated in the central regions (<1.4 kpc). Our results are in agreement with the epochs of the first peri-center passage ( 200 Myr ago) and coalescence (<100 Myr ago) predicted by dynamical models, and with high-resolution merger simulations in the literature, consistent with NGC 2623 representing an evolved version of the early-stage mergers. Most ionized gas is concentrated within <2.8 kpc, where LINER-like ionization and high-velocity dispersion ( 220 km s-1) are found, consistent with the previously reported outflow. As revealed by the highest-resolution OSIRIS and HST data, a collection of HII regions is also present in the plane of the galaxy, which explains the mixture of ionization mechanisms in this system. It is unlikely that the outflow in NGC 2623 will escape from the galaxy, given the low SFR intensity ( 0.5 M⊙ yr-1 kpc-2), the fact that the outflow rate is three times lower than the current SFR, and the escape velocity in the central areas is higher than the outflow velocity.

  7. Carbon-hydrogen bond activation, C-N bond coupling, and cycloaddition reactivity of a three-coordinate nickel complex featuring a terminal imido ligand.

    PubMed

    Mindiola, Daniel J; Waterman, Rory; Iluc, Vlad M; Cundari, Thomas R; Hillhouse, Gregory L

    2014-12-15

    The three-coordinate imidos (dtbpe)Ni═NR (dtbpe = (t)Bu2PCH2CH2P(t)Bu2, R = 2,6-(i)Pr2C6H3, 2,4,6-Me3C6H2 (Mes), and 1-adamantyl (Ad)), which contain a legitimate Ni-N double bond as well as basic imido nitrogen based on theoretical analysis, readily deprotonate HC≡CPh to form the amide acetylide species (dtbpe)Ni{NH(Ar)}(C≡CPh). In the case of R = 2,6-(i)Pr2C6H3, reductive carbonylation results in formation of the (dtbpe)Ni(CO)2 along with the N-C coupled product keteneimine PhCH═C═N(2,6- (i)Pr2C6H3). Given the ability of the Ni═N bond to have biradical character as suggested by theoretical analysis, H atom abstraction can also occur in (dtbpe)Ni═N{2,6-(i)Pr2C6H3} when this species is treated with HSn((n)Bu)3. Likewise, the microscopic reverse reaction--conversion of the Ni(I) anilide (dtbpe)Ni{NH(2,6-(i)Pr2C6H3)} to the imido (dtbpe)Ni═N{2,6-(i)Pr2C6H3}--is promoted when using the radical Mes*O(•) (Mes* = 2,4,6-(t)Bu3C6H2). Reactivity studies involving the imido complexes, in particular (dtbpe)Ni═N{2,6-(i)Pr2C6H3}, are also reported with small, unsaturated molecules such as diphenylketene, benzylisocyanate, benzaldehyde, and carbon dioxide, including the formation of C-N and N-N bonds by coupling reactions. In addition to NMR spectroscopic data and combustion analysis, we also report structural studies for all the cycloaddition reactions involving the imido (dtbpe)Ni═N{2,6-(i)Pr2C6H3}.

  8. Carbon–Hydrogen Bond Activation, C–N Bond Coupling, and Cycloaddition Reactivity of a Three-Coordinate Nickel Complex Featuring a Terminal Imido Ligand

    PubMed Central

    2015-01-01

    The three-coordinate imidos (dtbpe)Ni=NR (dtbpe = tBu2PCH2CH2PtBu2, R = 2,6-iPr2C6H3, 2,4,6-Me3C6H2 (Mes), and 1-adamantyl (Ad)), which contain a legitimate Ni–N double bond as well as basic imido nitrogen based on theoretical analysis, readily deprotonate HC≡CPh to form the amide acetylide species (dtbpe)Ni{NH(Ar)}(C≡CPh). In the case of R = 2,6-iPr2C6H3, reductive carbonylation results in formation of the (dtbpe)Ni(CO)2 along with the N–C coupled product keteneimine PhCH=C=N(2,6- iPr2C6H3). Given the ability of the Ni=N bond to have biradical character as suggested by theoretical analysis, H atom abstraction can also occur in (dtbpe)Ni=N{2,6-iPr2C6H3} when this species is treated with HSn(nBu)3. Likewise, the microscopic reverse reaction—conversion of the Ni(I) anilide (dtbpe)Ni{NH(2,6-iPr2C6H3)} to the imido (dtbpe)Ni=N{2,6-iPr2C6H3}—is promoted when using the radical Mes*O• (Mes* = 2,4,6-tBu3C6H2). Reactivity studies involving the imido complexes, in particular (dtbpe)Ni=N{2,6-iPr2C6H3}, are also reported with small, unsaturated molecules such as diphenylketene, benzylisocyanate, benzaldehyde, and carbon dioxide, including the formation of C–N and N–N bonds by coupling reactions. In addition to NMR spectroscopic data and combustion analysis, we also report structural studies for all the cycloaddition reactions involving the imido (dtbpe)Ni=N{2,6-iPr2C6H3}. PMID:25437507

  9. Young Stellar Objects in Lynds 1641: Disks and Accretion

    NASA Astrophysics Data System (ADS)

    Fang, Min; Kim, Jinyoung Serena; van Boekel, Roy; Sicilia-Aguilar, Aurora; Henning, Thomas; Flaherty, Kevin

    2013-07-01

    We investigate the young stellar objects (YSOs) in the Lynds 1641 (L1641) cloud using multi-wavelength data including Spitzer, WISE, 2MASS, and XMM covering 1390 YSOs across a range of evolutionary stages. In addition, we targeted a sub-sample of YSOs for optical spectroscopy with the MMT/Hectospec and the MMT/Hectochelle. We use this data, along with archival photometric data, to derive spectral types, masses, ages and extinction values. We also use the H_alpha and H_beta lines to derive accretion rates. We calculate the disk fraction as N(II)/N(II+III), where N(II) and N(III) are numbers of Class\\ II and Class\\ III sources, respectively, and obtain a disk fraction of 50% in L1641. We find that the disk frequency is almost constant as a function of stellar mass with a slight peak at log(M_*/M_sun) -0.25. The analysis of multi-epoch data indicates that the accretion variability of YSOs cannot explain the two orders of magnitude of scatter for YSOs with similar masses in the M_acc vs. M_* plot. Forty-six new transition disk objects are confirmed in our spectroscopic survey and we find that the fraction of transition disks that are actively accreting is lower than for optically thick disks (40-45% vs. 77-79% respectively). We confirm our previous result that the accreting YSOs with transition disks have a similar median accretion rate to normal optically thick disks. Analyzing the age distributions of various populations, we find that the diskless YSOs are statistically older than the YSOs with optically-thick disks and the transition disk objects have a median age which is intermediate between the two populations.

  10. Studies of a series of [Ni(P(R)2N(Ph)2)2(CH3CN)]2+ complexes as electrocatalysts for H2 production: substituent variation at the phosphorus atom of the P2N2 ligand.

    PubMed

    Kilgore, Uriah J; Stewart, Michael P; Helm, Monte L; Dougherty, William G; Kassel, W Scott; DuBois, Mary Rakowski; DuBois, Daniel L; Bullock, R Morris

    2011-11-07

    A series of [Ni(P(R)(2)N(Ph)(2))(2)(CH(3)CN)](BF(4))(2) complexes containing the cyclic diphosphine ligands [P(R)(2)N(Ph)(2) = 1,5-diaza-3,7-diphosphacyclooctane; R = benzyl (Bn), n-butyl (n-Bu), 2-phenylethyl (PE), 2,4,4-trimethylpentyl (TP), and cyclohexyl (Cy)] have been synthesized and characterized. X-ray diffraction studies reveal that the cations of [Ni(P(Bn)(2)N(Ph)(2))(2)(CH(3)CN)](BF(4))(2) and [Ni(P(n-Bu)(2)N(Ph)(2))(2)(CH(3)CN)](BF(4))(2) have distorted trigonal bipyramidal geometries. The Ni(0) complex [Ni(P(Bn)(2)N(Ph)(2))(2)] was also synthesized and characterized by X-ray diffraction studies and shown to have a distorted tetrahedral structure. These complexes, with the exception of [Ni(P(Cy)(2)N(Ph)(2))(2)(CH(3)CN)](BF(4))(2), all exhibit reversible electron transfer processes for both the Ni(II/I) and Ni(I/0) couples and are electrocatalysts for the production of H(2) in acidic acetonitrile solutions. The heterolytic cleavage of H(2) by [Ni(P(R)(2)N(Ph)(2))(2)(CH(3)CN)](BF(4))(2) complexes in the presence of p-anisidine or p-bromoaniline was used to determine the hydride donor abilities of the corresponding [HNi(P(R)(2)N(Ph)(2))(2)](BF(4)) complexes. However, for the catalysts with the most bulky R groups, the turnover frequencies do not parallel the driving force for elimination of H(2), suggesting that steric interactions between the alkyl substituents on phosphorus and the nitrogen atom of the pendant amines play an important role in determining the overall catalytic rate. © 2011 American Chemical Society

  11. [Effects of mixed decomposition of Populus simonii and other tree species leaf litters on soil properties in Loess Plateau].

    PubMed

    Li, Qian; Liu, Zeng-Wen; Du, Liang-Zhen

    2012-03-01

    In this study, the leaf litters of Populus simonii and other 11 tree species were put into soil separately or in mixture after grinding, and incubated in laboratory to analyze the effects of their decomposition on soil properties and the interactions between the litters decomposition. The decomposition of each kind of the leaf litters in soil increased the soil urease, dehydrogenase, and phosphatase activities and the soil organic matter and available N contents markedly, but had greater differences in the effects on the soil available P content and CEC. The decomposition of the leaf litters of Caragana microphylla and of Amorpha fruticosa showed obvious effects in improving soil properties. The decomposition of the mixed leaf litters of P. simonii and Pinus tabulaeformis, Platycladus orientalis, Robinia pseudoacacia, or Ulmus pumila showed interactive promotion effects on the abundance of soil microbes, and that of the mixed leaf litters of P. simonii and P. orientalis or C. microphylla showed interactive promotion effects on the soil organic matter, available P, and available K contents and soil CEC but interactive inhibition effects on the activities of most of the soil enzymes tested. The decomposition of the mixed leaf litters of P. simonii and Larix principis-rupprechtii showed interactive promotion effects on the activities of most of the soil enzymes and soil nutrient contents, while that of the mixed leaf litters of P. simonii and P. sylvestris var. mongolica showed interactive inhibition effects. Overall, the decomposition of the mixed leaf litters of P. simo- nii and U. pumila, P. tabulaeformis, L. principis-rupprechtii, or R. pseudoacacia could improve soil quality, but the mixed leaf litters of P. simonii and P. orientalis, C. microphylla, P. sylvestris var. mongolica, Hippophae rhamnoides, or A. fruticosa showed an interactive inhibition effect during their decomposition.

  12. Design and Analysis Tools for Concurrent Blackboard Systems

    NASA Technical Reports Server (NTRS)

    McManus, John W.

    1991-01-01

    A blackboard system consists of a set of knowledge sources, a blackboard data structure, and a control strategy used to activate the knowledge sources. The blackboard model of problem solving is best described by Dr. H. Penny Nii of the Stanford University AI Laboratory: "A Blackboard System can be viewed as a collection of intelligent agents who are gathered around a blackboard, looking at pieces of information written on it, thinking about the current state of the solution, and writing their conclusions on the blackboard as they generate them. " The blackboard is a centralized global data structure, often partitioned in a hierarchical manner, used to represent the problem domain. The blackboard is also used to allow inter-knowledge source communication and acts as a shared memory visible to all of the knowledge sources. A knowledge source is a highly specialized, highly independent process that takes inputs from the blackboard data structure, performs a computation, and places the results of the computation in the blackboard data structure. This design allows for an opportunistic control strategy. The opportunistic problem-solving technique allows a knowledge source to contribute towards the solution of the current problem without knowing which of the other knowledge sources will use the information. The use of opportunistic problem-solving allows the data transfers on the blackboard to determine which processes are active at a given time. Designing and developing blackboard systems is a difficult process. The designer is trying to balance several conflicting goals and achieve a high degree of concurrent knowledge source execution while maintaining both knowledge and semantic consistency on the blackboard. Blackboard systems have not attained their apparent potential because there are no established tools or methods to guide in their construction or analyze their performance.

  13. The reaction mechanism of methyl-coenzyme M reductase: How an enzyme enforces strict binding order

    DOE PAGES

    Wongnate, Thanyaporn; Ragsdale, Stephen W.

    2015-02-17

    Methyl-coenzyme M reductase (MCR) is a nickel tetrahydrocorphinoid (coenzyme F430) containing enzyme involved in the biological synthesis and anaerobic oxidation of methane. MCR catalyzes the conversion of methyl-2-mercaptoethanesulfonate (methyl-SCoM) and N-7-mercaptoheptanoylthreonine phosphate (CoB 7SH) to CH 4 and the mixed disulfide CoBS-SCoM. In this study, the reaction of MCR from Methanothermobacter marburgensis, with its native substrates was investigated using static binding, chemical quench, and stopped-flow techniques. Rate constants were measured for each step in this strictly ordered ternary complex catalytic mechanism. Surprisingly, in the absence of the other substrate, MCR can bind either substrate; however, only one binary complex (MCR·methyl-SCoM)more » is productive whereas the other (MCR·CoB 7SH) is inhibitory. Moreover, the kinetic data demonstrate that binding of methyl-SCoM to the inhibitory MCR·CoB 7SH complex is highly disfavored ( Kd = 56 mM). However, binding of CoB 7SH to the productive MCR·methyl-SCoM complex to form the active ternary complex (CoB 7SH·MCR(Ni I)·CH 3SCoM) is highly favored ( Kd = 79 μM). Only then can the chemical reaction occur ( kobs = 20 s -1 at 25 °C), leading to rapid formation and dissociation of CH 4 leaving the binary product complex (MCR(Ni II)·CoB 7S -·SCoM), which undergoes electron transfer to regenerate Ni(I) and the final product CoBS-SCoM. In conclusion, this first rapid kinetics study of MCR with its natural substrates describes how an enzyme can enforce a strictly ordered ternary complex mechanism and serves as a template for identification of the reaction intermediates.« less

  14. Effect of excess iodine intake on thyroid diseases in different populations: A systematic review and meta-analyses including observational studies

    PubMed Central

    Katagiri, Ryoko; Yuan, Xiaoyi; Kobayashi, Satomi; Sasaki, Satoshi

    2017-01-01

    Background Although several reports concerning the association of iodine excess and thyroid disease have appeared, no systematic review of the association between iodine excess intake and thyroid diseases, especially hyperthyroidism and hypothyroidism, has yet been reported. Method We conducted a systematic search of Ovid MEDLINE, PubMed, Cochrane Central Register of Controlled Trials databases, Ichushi-Web and CiNii database for intervention trials and observational studies. Search terms were constructed from related words for excess AND iodine intake or excretion AND thyroid hormones or diseases AND study designs. After considering the qualitative heterogeneity among studies, a meta-analysis was conducted and odds ratios and 95% confidence intervals (CI) were estimated in random-effects models. A protocol was registered with PROSPERO (No. CRD42015028081). Results 50 articles were included, including three intervention trials, six case-control studies, six follow-up studies and 35 cross-sectional studies. Three cross-sectional studies in adults included in meta-analysis. Odds ratio of overt and subclinical hypothyroidism between excess and adequate populations were 2.78 (CI:1.47 to 5.27) and 2.03 (CI:1.58 to 2.62) in adults, respectively. Source of excess iodine status was mainly iodized salt or water in included studies. Conclusion Although universal salt iodization has improved goiter rates, chronic exposure to excess iodine from water or poorly monitored salt are risk factors for hypothyroidism in free-living populations. Monitoring of both iodine concentration in salt as well as the iodine concentration in local drinking water are essential to preventing thyroid diseases. Hypothyroidism should be also carefully monitored in areas with excess iodine. Because of the low quality and limited number of included studies, further evidence and review are required. PMID:28282437

  15. A deep narrowband survey for planetary nebulae at the outskirts of M 33

    NASA Astrophysics Data System (ADS)

    Galera-Rosillo, R.; Corradi, R. L. M.; Mampaso, A.

    2018-04-01

    Context. Planetary nebulae (PNe) are excellent tracers of stellar populations with low surface brightness, and therefore provide a powerful method to detect and explore the rich system of substructures discovered around the main spiral galaxies of the local group. Aim. We searched the outskirts of the local group spiral galaxy M 33 (the Triangulum) for PNe to gain new insights into the extended stellar substructure on the northern side of the disc and to study the existence of a faint classical halo. Methods: The search is based on wide field imaging covering a 4.5 square degree area out to a maximum projected distance of about 40 kpc from the centre of the galaxy. The PN candidates are detected by the combination of images obtained in narrowband filters selecting the [OIII]λ5007 Å and Hα + [NII] nebular lines and in the continuum g' and r' broadband filters. Results: Inside the bright optical disc of M 33, eight new PN candidates were identified, three of which were spectroscopically confirmed. No PN candidates were found outside the limits of the disc. Fourteen additional sources showing [OIII] excess were also discovered. Conclusions: The absence of bright PN candidates in the area outside the galaxy disc covered by this survey sets an upper limit to the luminosity of the underlying population of 1.6 × 107 L⊙, suggesting the lack of a massive classical halo, which is in agreement with the results obtained using the red giant branch population. Based on observations made with the Isaac Newton Telescope and service observations made with the William Herschel Telescope operated on the island of La Palma by the Isaac Newton Group of Telescopes in the Spanish Observatorio del Roque de los Muchachos of the Instituto de Astrofísica de Canarias.

  16. A Virgo Environmental Survey Tracing Ionised Gas Emission (VESTIGE). II. Constraining the quenching time in the stripped galaxy NGC 4330

    NASA Astrophysics Data System (ADS)

    Fossati, M.; Mendel, J. T.; Boselli, A.; Cuillandre, J. C.; Vollmer, B.; Boissier, S.; Consolandi, G.; Ferrarese, L.; Gwyn, S.; Amram, P.; Boquien, M.; Buat, V.; Burgarella, D.; Cortese, L.; Côté, P.; Côté, S.; Durrell, P.; Fumagalli, M.; Gavazzi, G.; Gomez-Lopez, J.; Hensler, G.; Koribalski, B.; Longobardi, A.; Peng, E. W.; Roediger, J.; Sun, M.; Toloba, E.

    2018-06-01

    The Virgo Environmental Survey Tracing Ionised Gas Emission (VESTIGE) is a blind narrow-band Hα + [NII] imaging survey carried out with MegaCam at the Canada-France-Hawaii Telescope. During pilot observations taken in the spring of 2016 we observed NGC 4330, an intermediate mass (M* ≃ 109.8 M⊙) edge-on star forming spiral currently falling into the core of the Virgo cluster. While previous Hα observations showed a clumpy complex of ionised gas knots outside the galaxy disc, new deep observations revealed a low surface brightness 10 kpc tail exhibiting a peculiar filamentary structure. The filaments are remarkably parallel to one another and clearly indicate the direction of motion of the galaxy in the Virgo potential. Motivated by the detection of these features which indicate ongoing gas stripping, we collected literature photometry in 15 bands from the far-UV to the far-IR and deep optical long-slit spectroscopy using the FORS2 instrument at the ESO Very Large Telescope. Using a newly developed Monte Carlo code that jointly fits spectroscopy and photometry, we reconstructed the star formation histories in apertures along the major axis of the galaxy. Our results have been validated against the output of CIGALE, a fitting code which has been previously used for similar studies. We found a clear outside-in gradient with radius of the time when the quenching event started: the outermost radii were stripped 500 Myr ago, while the stripping reached the inner 5 kpc from the centre in the last 100 Myr. Regions at even smaller radii are currently still forming stars fueled by the presence of HI and H2 gas. When compared to statistical studies of the quenching timescales in the local Universe we find that ram pressure stripping of the cold gas is an effective mechanism to reduce the transformation times for galaxies falling into massive clusters. Future systematic studies of all the active galaxies observed by VESTIGE in the Virgo cluster will extend these results

  17. modPDZpep: a web resource for structure based analysis of human PDZ-mediated interaction networks.

    PubMed

    Sain, Neetu; Mohanty, Debasisa

    2016-09-21

    PDZ domains recognize short sequence stretches usually present in C-terminal of their interaction partners. Because of the involvement of PDZ domains in many important biological processes, several attempts have been made for developing bioinformatics tools for genome-wide identification of PDZ interaction networks. Currently available tools for prediction of interaction partners of PDZ domains utilize machine learning approach. Since, they have been trained using experimental substrate specificity data for specific PDZ families, their applicability is limited to PDZ families closely related to the training set. These tools also do not allow analysis of PDZ-peptide interaction interfaces. We have used a structure based approach to develop modPDZpep, a program to predict the interaction partners of human PDZ domains and analyze structural details of PDZ interaction interfaces. modPDZpep predicts interaction partners by using structural models of PDZ-peptide complexes and evaluating binding energy scores using residue based statistical pair potentials. Since, it does not require training using experimental data on peptide binding affinity, it can predict substrates for diverse PDZ families. Because of the use of simple scoring function for binding energy, it is also fast enough for genome scale structure based analysis of PDZ interaction networks. Benchmarking using artificial as well as real negative datasets indicates good predictive power with ROC-AUC values in the range of 0.7 to 0.9 for a large number of human PDZ domains. Another novel feature of modPDZpep is its ability to map novel PDZ mediated interactions in human protein-protein interaction networks, either by utilizing available experimental phage display data or by structure based predictions. In summary, we have developed modPDZpep, a web-server for structure based analysis of human PDZ domains. It is freely available at http://www.nii.ac.in/modPDZpep.html or http://202.54.226.235/modPDZpep.html . This

  18. Shuttling of nickel oxidation states in N4S2 coordination geometry versus donor strength of tridentate N2S donor ligands.

    PubMed

    Chatterjee, Sudip K; Roy, Suprakash; Barman, Suman Kumar; Maji, Ram Chandra; Olmstead, Marilyn M; Patra, Apurba K

    2012-07-16

    Seven bis-Ni(II) complexes of a N(2)S donor set ligand have been synthesized and examined for their ability to stabilize Ni(0), Ni(I), Ni(II) and Ni(III) oxidation states. Compounds 1-5 consist of modifications of the pyridine ring of the tridentate Schiff base ligand, 2-pyridyl-N-(2'-methylthiophenyl)methyleneimine ((X)L1), where X = 6-H, 6-Me, 6-p-ClPh, 6-Br, 5-Br; compound 6 is the reduced amine form (L2); compound 7 is the amide analog (L3). The compounds are perchlorate salts except for 7, which is neutral. Complexes 1 and 3-7 have been structurally characterized. Their coordination geometry is distorted octahedral. In the case of 6, the tridentate ligand coordinates in a facial manner, whereas the remaining complexes display meridional coordination. Due to substitution of the pyridine ring of (X)L1, the Ni-N(py) distances for 1~5 < 3 < 4 increase and UV-vis λ(max) values corresponding to the (3)A(2g)(F)→(3)T(2g)(F) transition show an increasing trend 1~5 < 2 < 3 < 4. Cyclic voltammetry of 1-5 reveals two quasi-reversible reduction waves that correspond to Ni(II)→Ni(I) and Ni(I)→Ni(0) reduction. The E(1/2) for the Ni(II)/Ni(I) couple decreases as 1 > 2 > 3 > 4. Replacement of the central imine N donor in 1 by amine 6 or amide 7 N donors reveals that complex 6 in CH(3)CN exhibits an irreversible reductive response at E(pc) = -1.28 V, E(pa) = +0.25 V vs saturated calomel electrode (SCE). In contrast, complex 7 shows a reversible oxidation wave at E(1/2) = +0.84 V (ΔE(p) = 60 mV) that corresponds to Ni(II)→Ni(III). The electrochemically generated Ni(III) species, [(L3)(2)Ni(III)](+) is stable, showing a new UV-vis band at 470 nm. EPR measurements have also been carried out.

  19. Correlation between patients' reasons for encounters/health problems and population density in Japan: a systematic review of observational studies coded by the International Classification of Health Problems in Primary Care (ICHPPC) and the International Classification of Primary care (ICPC).

    PubMed

    Kaneko, Makoto; Ohta, Ryuichi; Nago, Naoki; Fukushi, Motoharu; Matsushima, Masato

    2017-09-13

    The Japanese health care system has yet to establish structured training for primary care physicians; therefore, physicians who received an internal medicine based training program continue to play a principal role in the primary care setting. To promote the development of a more efficient primary health care system, the assessment of its current status in regard to the spectrum of patients' reasons for encounters (RFEs) and health problems is an important step. Recognizing the proportions of patients' RFEs and health problems, which are not generally covered by an internist, can provide valuable information to promote the development of a primary care physician-centered system. We conducted a systematic review in which we searched six databases (PubMed, the Cochrane Library, Google Scholar, Ichushi-Web, JDreamIII and CiNii) for observational studies in Japan coded by International Classification of Health Problems in Primary Care (ICHPPC) and International Classification of Primary Care (ICPC) up to March 2015. We employed population density as index of accessibility. We calculated Spearman's rank correlation coefficient to examine the correlation between the proportion of "non-internal medicine-related" RFEs and health problems in each study area in consideration of the population density. We found 17 studies with diverse designs and settings. Among these studies, "non-internal medicine-related" RFEs, which was not thought to be covered by internists, ranged from about 4% to 40%. In addition, "non-internal medicine-related" health problems ranged from about 10% to 40%. However, no significant correlation was found between population density and the proportion of "non-internal medicine-related" RFEs and health problems. This is the first systematic review on RFEs and health problems coded by ICHPPC and ICPC undertaken to reveal the diversity of health problems in Japanese primary care. These results suggest that primary care physicians in some rural areas of Japan

  20. Carbon–hydrogen bond activation, C–N bond coupling, and cycloaddition reactivity of a three-coordinate nickel complex featuring a terminal imido ligand

    DOE PAGES

    Mindiola, Daniel J.; Waterman, Rory; Iluc, Vlad M.; ...

    2014-12-01

    Here, the three-coordinate imidos (dtbpe)Ni=NR (dtbpe = tBu 2PCH 2CH 2PtBu 2, R = 2,6- iPr 2C 6H 3, 2,4,6-Me 3C 6H 2 (Mes), and 1-adamantyl (Ad)), which contain a legitimate Ni–N double bond as well as basic imido nitrogen based on theoretical analysis, readily deprotonate HC≡CPh to form the amide acetylide species (dtbpe)Ni{NH(Ar)}(C≡CPh). In the case of R = 2,6- iPr 2C 6H 3, reductive carbonylation results in formation of the (dtbpe)Ni(CO) 2 along with the N–C coupled product keteneimine PhCH=C=N(2,6- iPr 2C 6H 3). Given the ability of the Ni=N bond to have biradical character as suggested bymore » theoretical analysis, H atom abstraction can also occur in (dtbpe)Ni=N{2,6- iPr 2C 6H 3} when this species is treated with HSn( nBu) 3. Likewise, the microscopic reverse reaction—conversion of the Ni(I) anilide (dtbpe)Ni{NH(2,6- iPr 2C 6H 3)} to the imido (dtbpe)Ni=N{2,6- iPr 2C 6H 3}—is promoted when using the radical Mes*O • (Mes* = 2,4,6- tBu 3C 6H 2). Reactivity studies involving the imido complexes, in particular (dtbpe)Ni=N{2,6- iPr 2C 6H 3}, are also reported with small, unsaturated molecules such as diphenylketene, benzylisocyanate, benzaldehyde, and carbon dioxide, including the formation of C–N and N–N bonds by coupling reactions. In addition to NMR spectroscopic data and combustion analysis, we also report structural studies for all the cycloaddition reactions involving the imido (dtbpe)Ni=N{2,6- iPr 2C 6H 3}.« less

  1. Carbon–hydrogen bond activation, C–N bond coupling, and cycloaddition reactivity of a three-coordinate nickel complex featuring a terminal imido ligand

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mindiola, Daniel J.; Waterman, Rory; Iluc, Vlad M.

    Here, the three-coordinate imidos (dtbpe)Ni=NR (dtbpe = tBu 2PCH 2CH 2PtBu 2, R = 2,6- iPr 2C 6H 3, 2,4,6-Me 3C 6H 2 (Mes), and 1-adamantyl (Ad)), which contain a legitimate Ni–N double bond as well as basic imido nitrogen based on theoretical analysis, readily deprotonate HC≡CPh to form the amide acetylide species (dtbpe)Ni{NH(Ar)}(C≡CPh). In the case of R = 2,6- iPr 2C 6H 3, reductive carbonylation results in formation of the (dtbpe)Ni(CO) 2 along with the N–C coupled product keteneimine PhCH=C=N(2,6- iPr 2C 6H 3). Given the ability of the Ni=N bond to have biradical character as suggested bymore » theoretical analysis, H atom abstraction can also occur in (dtbpe)Ni=N{2,6- iPr 2C 6H 3} when this species is treated with HSn( nBu) 3. Likewise, the microscopic reverse reaction—conversion of the Ni(I) anilide (dtbpe)Ni{NH(2,6- iPr 2C 6H 3)} to the imido (dtbpe)Ni=N{2,6- iPr 2C 6H 3}—is promoted when using the radical Mes*O • (Mes* = 2,4,6- tBu 3C 6H 2). Reactivity studies involving the imido complexes, in particular (dtbpe)Ni=N{2,6- iPr 2C 6H 3}, are also reported with small, unsaturated molecules such as diphenylketene, benzylisocyanate, benzaldehyde, and carbon dioxide, including the formation of C–N and N–N bonds by coupling reactions. In addition to NMR spectroscopic data and combustion analysis, we also report structural studies for all the cycloaddition reactions involving the imido (dtbpe)Ni=N{2,6- iPr 2C 6H 3}.« less

  2. Influence of Sulfur Metalation on the Accessibility of the Ni(II/I) Couple in [N,N'-Bis(2-mercaptoethyl)-1,5-diazacyclooctanato]nickel(II): Insight into the Redox Properties of [NiFe]-Hydrogenase.

    PubMed

    Musie, Ghezai; Farmer, Patrick J.; Tuntulani, Thawatchai; Reibenspies, Joseph H.; Darensbourg, Marcetta Y.

    1996-04-10

    A redox model study of [NiFe] hydrogenase has examined a series of five polymetallics based on the metalation of the dithiolate complex [1,5-bis(mercaptoethyl)-1,5-diazacyclooctane]Ni(II), Ni-1. Crystal structures of three polymetallics of the series have been reported earlier: [(Ni-1)(2)()Ni]Cl(2)(), [(Ni-1)(2)()FeCl(2)()](2)(), and [(Ni-1)(3)()(ZnCl)(2)()]Cl(2)(). Two are described here: [(Ni-1)(2)()Pd]Cl(2)().2H(2)()Ocrystallizes in the monoclinic system, space group P2(1)/c with cell constants a = 12.212(4) Å, b = 7.642(2) Å, c = 16.625(3) Å, beta = 107.69(2) degrees, V = 1443.230(0) Å(3), Z = 2, R = 0.051, and R(w) = 0.056. [(Ni-1)(2)()CoCl]PF(6)() crystallizes in the triclinic system, space group P&onemacr;, with cell constants a = 8.14(2) Å, b = 13.85(2) Å, c = 15.67(2) Å, alpha = 113.59(10) degrees, beta = 101.84(14) degrees, gamma = 94.0(2) degrees, V = 1561.620(0)Å(3), Z = 2, R = 0.072, and R(w) = 0.077. In all Ni-1 serves as a bidentate metallothiolate ligand with a "hinge" angle in the range 105-118 degrees and Ni-M distances of 2.7- 3.7 Å. The most accessible redox event is shown by EPR and electrochemistry to reside in the N(2)S(2)Ni unit and is the Ni(II/I) couple. Charge neutralization of the thiolate sulfurs by metalation can (dependent on the interacting metal) stabilize the Ni(I) state as efficiently as methylation forming a thioether. The implication of these results for the heterometallic active site of [NiFe]-hydrogenase as structured from Desulfovibrio gigas (Volbeda, A., et al. Nature, 1995, 373, 580), the generality of the Ni(&mgr;-SR)(2)M hinge structure, and a possible explanation for the unusual redox potentials are discussed.

  3. The Music Attentiveness Screening Assessment, Revised (MASA-R): A Study of Technical Adequacy.

    PubMed

    Waldon, Eric G; Lesser, Alexander; Weeden, Lydia; Messick, Emily

    2016-01-01

    Evidence suggests that attention is an important consideration when designing procedural support interventions for children undergoing distressing medical procedures. As such, the extent to which children can attend to musical stimuli used during music-based procedural support interventions would seem important. The Music Attentiveness Screening Assessment (MASA) was designed to assess a child's ability to attend to musical stimuli, but further revisions were deemed necessary to improve administration, test-retest reliability, and interobserver agreement for the measure's items. This study investigated the technical adequacy of the Music Attentiveness Screening Assessment, Revised (MASA-R), with a non-clinical sample of children aged 4 to 9 years by examining (a) Construct validity using comparator instruments measuring auditory attention; (b) Test-retest reliability following a two-week delay; and (c) Interobserver agreement when administered by two independent examiners. This non-clinical sample included 69 children who were administered both items from MASA-R and two comparator instruments: the Auditory Attention subtest from the NEPSY-II (NII-AA) for children aged 5 to 9 years (n = 47); and the Auditory Attention subtest from the Woodcock-Johnson Tests of Cognitive Abilities, 3rd ed. (WJIII-AA), for children aged 4 years (n = 22). A significant proportion of score variance was shared by both MASA-R items and the comparator measures: R (2) = .16, F(2, 66) = 6.30, p = .003. MASA-R score estimates with regard to test-retest reliability (Item I, intra-class correlation [ICC] = .88; Item II, ICC = .91) and interobserver agreement (Item I, ICC = .99; Item II, ICC = .98) also fell into acceptable ranges. Estimates of MASA-R score construct validity, test-retest reliability, and interobserver agreement appear improved over its predecessor, MASA. While findings are promising, additional investigation of its use with a clinical sample is needed before it can be

  4. Supernova remnants and diffuse ionized gas in M31

    NASA Technical Reports Server (NTRS)

    Walterbos, Rene; Braun, Robert

    1990-01-01

    Researchers have compiled an initial list of radio/optical supernova remnants (SNRs) in M31, by searching for radio identifications of emission-line sources with a high (SII)/H alpha ratio (greater than 0.60). The (SII) filter included both sulfur lines and the H alpha filter did not include (NII). This search revealed 11 SNRs, of which only two were known. In addition, researchers detected radio emission from 3 SNRs that were identified in previous optical surveys (D'Odorico et al., 1980), but that were outside the charge coupled device (CCD) fields. The 14 objects only include the most obvious candidates, but a full search is in progress and the researchers expect to find several more SNRs. Also not all optical SNRs show detectable radio emission and a pure optical list of SNR candidates based only on the ratio of (SII)/H alpha emission contains many more objects. Two conclusions are apparent. First, the radio properties of the SNRs in M31 are quite similar to those of Galactic SNRs as is illustrated. The brightnesses are not systematically lower as has been suggested in the past (Dickel and D'Odorico, 1984). Second, the slope of the relation is close to -2; this slope is expected from the intrinsic dependence between surface brightness and diameter. The radio luminosity of the SNRs does not seem to depend strongly on diameter, or age, contrary to model predictions. Selection effects, however, play an important role in these plots. The CCD images show widespread diffuse ionized gas with a ratio of (SII)/H alpha that is higher than that of discrete HII regions. Discrete HII regions typically show ratios between 0.2 to 0.3, while the diffuse gas in the arms consistently shows ratios of 0.5. Researchers can trace this gas across the spiral arms to emission measures below 5 pc cm (-6). Its properties seem to be similar to that of the diffuse gas in the solar neighborhood.

  5. Systematic Review of Acupuncture for Chronic Prostatitis/Chronic Pelvic Pain Syndrome

    PubMed Central

    Qin, Zongshi; Wu, Jiani; Zhou, Jing; Liu, Zhishun

    2016-01-01

    Abstract Acupuncture is a promising therapy for relieving symptoms in chronic prostatitis/chronic pelvic pain syndrome (CP/CPPS), which affects >15% of adult men worldwide. The aim of the study was to assess the effects and safety of the use of acupuncture for CP/CPPS. MEDLINE, EMBASE, CENTRAL, Web of Science, CBM, CNKI, Wang-Fang Database, JCRM, and CiNii were searched from their inception through 30 November 2015. Grey literature databases and websites were also searched. No language limits were applied. Only randomized controlled trials (RCTs) with CP/CPPS treated by acupuncture were included. Two reviewers extracted data and assessed the risk of bias of RCTs using the Cochrane Risk of Bias Tools, respectively. Seven trials were included, involving 471 participants. The result of meta-analysis indicated that compared with sham acupuncture (MD: −6.09 [95%CI: −8.12 to −5.68]) and medicine (Levofloxacinand, Ibuprofen, and Tamsulosin) (MD: −4.57 [95%CI: −7.58 to −1.56]), acupuncture was more effective at decreasing the total NIH-CPSI score. Real acupuncture was superior to sham acupuncture in improving symptoms (pain, voiding) and quality of life (Qof) domain subscores. Compared to sham acupuncture and medicine, acupuncture appears to be more effective at improving the global assessment. Two trials found that there is no significant difference between acupuncture and sham acupuncture in decreasing the IPSS score. Acupuncture failed to show more favorable effects in improving both symptoms and the Qof domain compared with medicine. Overall, current evidence supports acupuncture as an effective treatment for CP/CPPS-induced symptoms, particularly in relieving pain. Based on the meta-analysis, acupuncture is superior to sham acupuncture in improving symptoms and Qof. Acupuncture might be similar to medicine (Levofloxacinand, Ibuprofen, and Tamsulosin) in its long-term effects, but evidence was limited due to high ROB among included trials as well as

  6. Ionization processes in a local analogue of distant clumpy galaxies: VLT MUSE IFU spectroscopy and FORS deep images of the TDG NGC 5291N

    NASA Astrophysics Data System (ADS)

    Fensch, J.; Duc, P.-A.; Weilbacher, P. M.; Boquien, M.; Zackrisson, E.

    2016-01-01

    Context. We present Integral Field Unit (IFU) observations with MUSE and deep imaging with FORS of a dwarf galaxy recently formed within the giant collisional HI ring surrounding NGC 5291. This Tidal Dwarf Galaxy (TDG) -like object has the characteristics of typical z = 1-2 gas-rich spiral galaxies: a high gas fraction, a rather turbulent clumpy interstellar medium, the absence of an old stellar population, and a moderate metallicity and star formation efficiency. Aims: The MUSE spectra allow us to determine the physical conditions within the various complex substructures revealed by the deep optical images and to scrutinize the ionization processes at play in this specific medium at unprecedented spatial resolution. Methods: Starburst age, extinction, and metallicity maps of the TDG and the surrounding regions were determined using the strong emission lines Hβ, [OIII], [OI], [NII], Hα, and [SII] combined with empirical diagnostics. Different ionization mechanisms were distinguished using BPT-like diagrams and shock plus photoionization models. Results: In general, the physical conditions within the star-forming regions are homogeneous, in particular with a uniform half-solar oxygen abundance. On small scales, the derived extinction map shows narrow dust lanes. Regions with atypically strong [OI] emission line immediately surround the TDG. The [OI]/ Hα ratio cannot be easily accounted for by the photoionization by young stars or shock models. At greater distances from the main star-foming clumps, a faint diffuse blue continuum emission is observed, both with the deep FORS images and the MUSE data. It does not have a clear counterpart in the UV regime probed by GALEX. A stacked spectrum towards this region does not exhibit any emission line, excluding faint levels of star formation, or stellar absorption lines that might have revealed the presence of old stars. Several hypotheses are discussed for the origin of these intriguing features. Based on observations

  7. Japan Data Exchange Network JDXnet and Cloud-type Data Relay Server for Earthquake Observation Data

    NASA Astrophysics Data System (ADS)

    Takano, K.; Urabe, T.; Tsuruoka, H.; Nakagawa, S.

    2015-12-01

    In Japan, high-sensitive seismic observation and broad-band seismic observation are carried out by several organization such as Japan Meteorological Agency (JMA) , National Research Institute for Earth Science and Disaster Prevention (NIED), nine National Universities, Japan Agency for Marine-Earth Science and Technology (JAMSTEC) , etc. The total number of the observation station is about 1400 points. The total volume of the seismic waveform data collected from all these observation station is about 1MByte for 1 second (about 8 to 10Mbps) by using the WIN system(Urabe 1991). JDXnet is the Japan Data eXchange network for earthquake observation data. JDXnet was started from 2007 by cooperation of the researchers of each organization. All the seismic waveform data are available at the all organizations in real-time. The core of JDXnet is the broadcast type real-time data exchange by using the nationwide L2-VPN service offered in JGN-X of NICT and SINET4 of NII. Before the Tohoku earthquake, the nine national universities had collected seismic data to each data center and then exchanged with other universities and institutions by JDXnet. However, in this case, if the center of the university was stopped, all data of the university could not use even though there are some alive observation stations. Because of this problem, we have prepared the data relay server in the data center of SINET4 ie the cloud center. This data relay server collects data directly from the observation stations of the universities and delivers data to all universities and institutions by JDXnet. By using the relay server on cloud center, even if some universities are affected by a large disaster, it is eliminated that the data of the living station is lost. If the researchers set up seismometers and send data to the relay server, then data are available to all researchers. This mechanism promotes the joint use of the seismometers and joint research activities in nationwide researchers.

  8. Correlation Between Bone Density and Instantaneous Torque at Implant Site Preparation: A Validation on Polyurethane Foam Blocks of a Device Assessing Density of Jawbones.

    PubMed

    Di Stefano, Danilo Alessio; Arosio, Paolo

    2016-01-01

    Bone density at implant placement sites is one of the key factors affecting implant primary stability, which is a determinant for implant osseointegration and rehabilitation success. Site-specific bone density assessment is, therefore, of paramount importance. Recently, an implant micromotor endowed with an instantaneous torque-measuring system has been introduced. The aim of this study was to assess the reliability of this system. Five blocks with different densities (0.16, 0.26, 0.33, 0.49, and 0.65 g/cm(3)) were used. A single trained operator measured the density of one of them (0.33 g/cm(3)), by means of five different devices (20 measurements/device). The five resulting datasets were analyzed through the analysis of variance (ANOVA) model to investigate interdevice variability. As differences were not significant (P = .41), the five devices were each assigned to a different operator, who collected 20 density measurements for each block, both under irrigation (I) and without irrigation (NI). Measurements were pooled and averaged for each block, and their correlation with the actual block-density values was investigated using linear regression analysis. The possible effect of irrigation on density measurement was additionally assessed. Different devices provided reproducible, homogenous results. No significant interoperator variability was observed. Within the physiologic range of densities (> 0.30 g/cm(3)), the linear regression analysis showed a significant linear correlation between the mean torque measurements and the actual bone densities under both drilling conditions (r = 0.990 [I], r = 0.999 [NI]). Calibration lines were drawn under both conditions. Values collected under irrigation were lower than those collected without irrigation at all densities. The NI/I mean torque ratio was shown to decrease linearly with density (r = 0.998). The mean error introduced by the device-operator system was less than 10% in the range of normal jawbone density

  9. Atomic and molecular emissions in the middle ultraviolet dayglow

    NASA Astrophysics Data System (ADS)

    Bucsela, Eric J.; Cleary, David D.; Dymond, Kenneth F.; McCoy, Robert P.

    1998-12-01

    Dayglow spectra in the middle ultraviolet, obtained during a sounding rocket flight from White Sands Missile Range in 1992, have been analyzed to determine the altitude distributions of thermospheric atomic and molecular species and to address a number of problems related to airglow excitation mechanisms. Among the atomic and molecular profiles retrieved are the N2 second positive, N2 Vegard-Kaplan and NO gamma band systems, and the OI 297.2 nm, OII 247.0 nm, and NII 214.3 nm emissions. A self-consistent study of the emission profiles was conducted by comparing observed intensities with one another and to forward models. Model photoelectron and photon fluxes were generated by the field line interhemispheric plasma model (FLIP) and two solar flux models. Neutral densities were obtained from mass-spectrometer/incoherent scatter (MSIS)-90. The results from the data analysis suggest that the major species' densities are within 40% of MSIS values. Evidence for the accuracy of the modeled densities and fluxes is seen in the close agreement between the calculated and observed intensities of the N2 second positive emission. Analysis of the OI 297.2 nm emission shows that the reaction N2(A)+O is the dominant source of O(1S) in the daytime thermosphere. The data imply that the vibrationally averaged yield of O(1S) from the reaction is 0.43+/-0.12, which is smaller than the laboratory value measured for the N2(A,v'=0) level. The cause of a disagreement between model and data for the Vegard-Kaplan emission is unclear, but the discrepancy can be eliminated if the N2(A)+O quenching coefficient or the A state lifetime is increased by a factor between 2 and 4. The observed intensity of OII 247.0 nm is greater than expected by a factor of 2, implying possible inadequacies in the EUVAC and/or EUV91 solar models used in the analysis.

  10. Education in nuclear decommissioning in the north of Scotland

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Catlow, F.; Reeves, G.M.

    2007-07-01

    This paper describes the work covered and experience gained in the first two years of operation of DERC, a Centre for Decommissioning and Environmental Remediation in the Highlands of Scotland. The Centre is a unique development which was set up to teach nuclear decommissioning as a separate discipline, address the problem of a declining skills base in the field of nuclear technologies and to take advantage of the unique and exceptional innovative, technical and research opportunities offered through the decommissioning of Britain's fast reactor site at Dounreay. The Centre is an offshoot from North Highland College which is a membermore » of UHI, the University in embryo of the Highlands and Islands. The Centre currently supports ten PhD students completing various diverse projects mainly in the field of nuclear environmental remediation. In addition there area number of full and part time MSc students who participate in NTEC (Nuclear Technology Education Consortium) a consortium of British Universities set up specifically to engender interest and skills in nuclear technology at postgraduate level. At undergraduate level, courses are offered in Nuclear Decommissioning and related subjects as part of Electrical and Mechanical degree courses. In addition to our relationship with the United Kingdom Atomic Energy Authority (UKAEA) the Dounreay site licensee, we have links with Rolls-Royce and the Ministry of Defence who also share the Dounreay site and with other stakeholders such as, the UK regulator (HSE/NII), the Scottish Environmental Protection Agency (SEPA), local and international contractors and we liaise with the newly formed Nuclear Decommissioning Authority (NDA), who provide some sponsorship and support. We possess our own equipment and laboratories for taking and analysing soil samples and for conducting environmental surveys. Recently we commissioned an aerial survey of contamination in the locality from natural sources, other background levels such as

  11. Extended Red Emission in the Evil Eye Galaxy

    NASA Astrophysics Data System (ADS)

    Pierini, D.; Majeed, A.; Boroson, T. A.; Witt, A. N.

    2001-05-01

    The Evil Eye Galaxy (NGC 4826) is a nearby galaxy with an asymmetrically placed, strongly absorbing dust lane across its prominent bulge, associated to an active star formation (SF) region. We obtained accurate low--resolution (4.2 Å/pixel) spectroscopy (KPNO 4-m) of NGC 4826 in the wavelength range 5300--9100Å with a slit of 4.4' length, positioned across the nucleus of the galaxy and encompassing its bulge size. We were able to study the wavelength dependent effects of absorption and scattering by the dust by comparing the stellar SEDs at corresponding positions on the bulge, symmetrically placed with respect to the nucleus, under the assumption that the intrinsic (i.e. unobscured by the dust lane) ISRF is radially symmetric, except for the ongoing SF region. We report on the detection of strong extended red emission (ERE) from the dust lane of NGC 4826 within a radial distance of about 15{' '} from its nucleus, adjacent to the active SF region. At the nucleus, the ERE band extends from about 5800 Å to 9100 Å, with peak near 8300 Å, and the ERE-to-scattered light integrated intensity ratio is about 0.7. At farther distances, approaching the ongoing SF region, the ERE band and peak shift to longer wavelengths, while the integrated ERE intensity diminishes and, finally, vanishes there. The H α line intensity and the index [NII]λ 6583/H α constrain the Lyman continuum photon rate and the effective temperatures of the OB association stars. The ERE-to-scattered light ratio decreases as well but shows a secondary maximum where the opacity of the dust lane peaks. We interpret the ERE nature as photoluminescence by nanometer--sized clusters, illuminated by UV/visible photons of the local radiation field. When examined within the context of ERE observations in the diffuse ISM of our Galaxy and in a variety of other dusty environments, we conclude that the ERE photon conversion efficiency in NGC 4826 is as high as found elsewhere, but that the characteristic size

  12. MUSE sneaks a peek at extreme ram-pressure events. III. Tomography of UGC 6697, a massive galaxy falling into Abell 1367

    NASA Astrophysics Data System (ADS)

    Consolandi, G.; Gavazzi, G.; Fossati, M.; Fumagalli, M.; Boselli, A.; Yagi, M.; Yoshida, M.

    2017-10-01

    We present the MUSE observations of UGC 6697, a giant (M∗ ≈ 1010M⊙) spiral galaxy infalling in the nearby cluster Abell 1367. During its high-velocity transit through the intracluster medium (ICM), the hydrodynamical interactions with the ICM produce a ≈ 100 kpc tail of ionized gas that we map with a mosaic of five MUSE pointings up to 60 kpc from the galaxy. CGCG 97087N, a small companion that lies at few arcminutes in projection from UGC 6697, is also showing signs of the hydrodynamic action of the ICM of the cluster. Along the whole extent of the tail, we detect diffuse Hα emission, and to a lesser extent, Hβ, [OIII]λ5007, and [OI]λ6300. By comparing the kinematics and distribution of gas and stars (as traced by the CaII triplet) for both galaxies, we separate the ionized gas, as traced by the Hα line, into a component that is still bound to the galaxy and a component that is stripped. We find that the bound component shows a low-velocity dispersion and line ratios consistent with photoionization by hot stars. The stripped gas is more turbulent, with velocity dispersions up to ≳100 km s-1, and is excited by shocks, as traced by high values of [OI]/Hα and [NII]/Hα ratio. In the tail of UGC 6697, we identify numerous bright compact knots with line ratios typical of HII regions. These are distributed along the only streams of stripped gas that retain low-velocity dispersions (≲35 km s-1). Despite being in the stripped gas, their physical properties are not different from normal HII regions in galactic disks. We find evidence of a past fast encounter between the two galaxies in the form of a double tail emerging from CGCG 97087N that connects with UGC 6697. This encounter might have increased the efficiency of the stripping process, leaving the stellar distribution and kinematics unaltered. The composite data cube is only available at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http

  13. A 2 THz Heterodyne Array Receiver for SOFIA: Summary of Research

    NASA Technical Reports Server (NTRS)

    Walker, Christopher K.

    1998-01-01

    We proposed to perform a comprehensive design study of a 16-element heterodyne array receiver for SOFIA. The array was designed to utilize hot-electron bolometers in an efficient, low-cost waveguide mount to achieve low noise performance between approximately 1500 and 2400 GHz. Due to the prevailing physical conditions in the interstellar medium, this frequency range is one of the richest in the Far-Infra Red (FIR) portion of the spectrum. An array designed for this wavelength range will make excellent use of the telescope and the available atmospheric transmission, and will provide a new perspective on stellar, chemical, and galactic evolution in the present as well as past epochs. A few of the most important molecular and atomic species which the instrument will sample are CII, OI, CO, OH, NII, and CH. The system used the most sensitive detectors available in an efficient optical system. The local oscillator was a compact CO2 pumped far-infrared laser currently under development for SOFIA. The backend spectrometer was an array acousto-optic spectrometer (aAOS). The spectrometer utilizes proven hardware and technologies to provide broadband performance (> 1 GHz per AOS channel) and high spectral resolution (1 MHz) with the maximum sensitivity and minimum complexity and cost. The proposed instrument would be the fastest and most sensitive heterodyne receiver ever to operate in the 1.5 - 2.4 THz band. One of the key technologies developed for the proposed instrument is the laser micromachining of waveguide structures. These structures provide both the optical link between the instrument and the telescope (via an array of efficient feedhorns) and the impedance transformation between the detectors and free space. With the assistance of funds provided from this grant, we were able to fabricate and test the world's first laser micromachined feedhorns. The quality of the waveguide structure is far better than that obtainable using any other fabrication technique. The

  14. Drug-target interaction prediction: A Bayesian ranking approach.

    PubMed

    Peska, Ladislav; Buza, Krisztian; Koller, Júlia

    2017-12-01

    In silico prediction of drug-target interactions (DTI) could provide valuable information and speed-up the process of drug repositioning - finding novel usage for existing drugs. In our work, we focus on machine learning algorithms supporting drug-centric repositioning approach, which aims to find novel usage for existing or abandoned drugs. We aim at proposing a per-drug ranking-based method, which reflects the needs of drug-centric repositioning research better than conventional drug-target prediction approaches. We propose Bayesian Ranking Prediction of Drug-Target Interactions (BRDTI). The method is based on Bayesian Personalized Ranking matrix factorization (BPR) which has been shown to be an excellent approach for various preference learning tasks, however, it has not been used for DTI prediction previously. In order to successfully deal with DTI challenges, we extended BPR by proposing: (i) the incorporation of target bias, (ii) a technique to handle new drugs and (iii) content alignment to take structural similarities of drugs and targets into account. Evaluation on five benchmark datasets shows that BRDTI outperforms several state-of-the-art approaches in terms of per-drug nDCG and AUC. BRDTI results w.r.t. nDCG are 0.929, 0.953, 0.948, 0.897 and 0.690 for G-Protein Coupled Receptors (GPCR), Ion Channels (IC), Nuclear Receptors (NR), Enzymes (E) and Kinase (K) datasets respectively. Additionally, BRDTI significantly outperformed other methods (BLM-NII, WNN-GIP, NetLapRLS and CMF) w.r.t. nDCG in 17 out of 20 cases. Furthermore, BRDTI was also shown to be able to predict novel drug-target interactions not contained in the original datasets. The average recall at top-10 predicted targets for each drug was 0.762, 0.560, 1.000 and 0.404 for GPCR, IC, NR, and E datasets respectively. Based on the evaluation, we can conclude that BRDTI is an appropriate choice for researchers looking for an in silico DTI prediction technique to be used in drug

  15. Radiative and mechanical feedback into the molecular gas in the Large Magellanic Cloud. I. N159W

    NASA Astrophysics Data System (ADS)

    Lee, M.-Y.; Madden, S. C.; Lebouteiller, V.; Gusdorf, A.; Godard, B.; Wu, R.; Galametz, M.; Cormier, D.; Le Petit, F.; Roueff, E.; Bron, E.; Carlson, L.; Chevance, M.; Fukui, Y.; Galliano, F.; Hony, S.; Hughes, A.; Indebetouw, R.; Israel, F. P.; Kawamura, A.; Le Bourlot, J.; Lesaffre, P.; Meixner, M.; Muller, E.; Nayak, O.; Onishi, T.; Roman-Duval, J.; Sewiło, M.

    2016-12-01

    We present Herschel SPIRE Fourier Transform Spectrometer (FTS) observations of N159W, an active star-forming region in the Large Magellanic Cloud (LMC). In our observations, a number of far-infrared cooling lines, including carbon monoxide (CO) J = 4 → 3 to J = 12 → 11, [CI] 609 μm and 370 μm, and [NII] 205 μm, are clearly detected. With an aim of investigating the physical conditions and excitation processes of molecular gas, we first construct CO spectral line energy distributions (SLEDs) on 10 pc scales by combining the FTS CO transitions with ground-based low-J CO data and analyze the observed CO SLEDs using non-LTE (local thermodynamic equilibrium) radiative transfer models. We find that the CO-traced molecular gas in N159W is warm (kinetic temperature of 153-754 K) and moderately dense (H2 number density of (1.1-4.5) × 103 cm-3). To assess the impact of the energetic processes in the interstellar medium on the physical conditions of the CO-emitting gas, we then compare the observed CO line intensities with the models of photodissociation regions (PDRs) and shocks. We first constrain the properties of PDRs by modeling Herschel observations of [OI] 145 μm, [CII] 158 μm, and [CI] 370 μm fine-structure lines and find that the constrained PDR components emit very weak CO emission. X-rays and cosmic-rays are also found to provide a negligible contribution to theCO emission, essentially ruling out ionizing sources (ultraviolet photons, X-rays, and cosmic-rays) as the dominant heating source for CO in N159W. On the other hand, mechanical heating by low-velocity C-type shocks with 10 km s-1 appears sufficient enough to reproduce the observed warm CO. Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.The final reduced Herschel data (FITS files) are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or

  16. Synthesis, characterization and some properties of mononuclear Ni and trinuclear NiFe2 complexes related to the active site of [NiFe]-hydrogenases.

    PubMed

    Song, Li-Cheng; Sun, Xiao-Jing; Zhao, Pei-Hua; Li, Jia-Peng; Song, Hai-Bin

    2012-08-07

    The [N(2)S(2)]-type ligand 1,2-(2-C(5)H(4)NCH(2)S)(2)C(6)H(4) (L) is prepared in 84% yield by a new method and its structure has been confirmed by X-ray crystallography. The new synthetic method involves sequential reaction of 1,2-phenylenedithiol with EtONa followed by treatment of the resulting disodium salt of 1,2-phenylenedithiol with in situ generated 2-(chloromethyl)pyridine from its HCl salt. Further treatment of ligand L with NiCl(2)·6H(2)O or NiI(2) affords the expected new mononuclear Ni complexes Ni[1,2-(2-C(5)H(4)NCH(2)S)(2)C(6)H(4)]Cl(2) (1) and Ni[1,2-(2-C(5)H(4)NCH(2)S)(2)C(6)H(4)]I(2) (3) in 87-88% yields, whereas reaction of L with NiBr(2) under similar conditions results in formation of the expected new mononuclear complex Ni[1,2-(2-C(5)H(4)NCH(2)S)(2)C(6)H(4)]Br(2) (2) and one unexpected new mononuclear complex Ni[1-(2-C(5)H(4)NCH(2)S)-2-(2-C(5)H(4)NCH(2)SC(6)H(4)S)C(6)H(4)]Br(2) (2*) in 82% and 5% yields, respectively. More interestingly, the ligand L-containing novel trinuclear NiFe(2) complex Ni{[1,2-(2-C(5)H(4)NCH(2)S)(2)C(6)H(4)}Fe(2)(CO)(6)(μ(3)-S)(2) (4) is found to be prepared by sequential reaction of (μ-S(2))Fe(2)(CO)(6) with Et(3)BHLi, followed by treatment of the resulting (μ-LiS)(2)Fe(2)(CO)(6) with mononuclear complex 1, 2, or 3 in 12-20% yields. The new complexes 1-4 and 2* are fully characterized by elemental analysis and various spectroscopies, and the crystal structures of 1, 2* and 3 as well as some electrochemical properties of 1-4 are also reported.

  17. Anthropogenic heavy metals in the environment of Eurasian Arctic Nature Reserves

    NASA Astrophysics Data System (ADS)

    Vinogradova, Anna; Ivanova, Yulia; Karpov, Alexey

    2014-05-01

    The Russian Arctic Nature Reserves are situated far from the main industrial regions. In spite of this, there are anthropogenic constituents (for example, heavy metals - HM) in the environmental objects (air, water, etc.) and in food chains (plants, birds, and so on). We studied the long-range atmospheric transport of some heavy metals (such as nickel, copper, lead, arsenic, and so on) to four Nature Reserves situated near the shore of the Arctic Ocean - in the Deltas of the Pechora River (Nenets reserve), the Ob River (Gydansky reserve), the Lena River (Ust-Lensky reserve), and at Wrangel Island. The air mass trajectories to each reserve were calculated with the help of the site (www.arl.noaa.gov/ready) for each day of January, April, July, and October for the period of 2001-2010. Analyzing the spatial distributions of these trajectories we studied seasonal variations in air transport of pollution to different Russian Arctic points. Modeling the HM transport in the atmosphere was as in [1]. The main assumption is that HM are transported with submicron aerosol particles. The annual source emissions for the last decade are generalized from the data published by Roshydromet of Russia (http://www.nii-atmosphere.ru/files/PUBL/Eg_2008.doc). The main important source-regions were found for each point. Mean anthropogenic HM concentrations in air and precipitations, as well as HM fluxes onto the surface were estimated at different arctic regions. The spatial distributions of so called "potential function of pollution" were calculated and presented on the maps. These results allow to analyze the role of a real pollution source or of a planned source for each reserve. So, the influence of northern oil and gas industry may be of great importance because of its proximity to the reserves under investigation. The work was partly supported by RFBR, grant No. 14-05-00059. Authors thank the NOAA service for possibility to use their data and products. ________________ 1. Vinogradova

  18. Optical-NIR spectroscopy of the puzzling γ-ray source 3FGL 1603.9-4903/PMN J1603-4904 with X-Shooter

    NASA Astrophysics Data System (ADS)

    Goldoni, P.; Pita, S.; Boisson, C.; Müller, C.; Dauser, T.; Jung, I.; Krauß, F.; Lenain, J.-P.; Sol, H.

    2016-02-01

    Context. The Fermi/LAT instrument has detected about two thousand extragalactic high energy (E ≥ 100 MeV) γ-ray sources. One of the brightest is 3FGL J1603.9-4903; it is associated to the radio source PMN J1603-4904. Its nature is not yet clear, it could be either a very peculiar BL Lac or a compact symmetric object radio source which are considered as the early stage of a radio galaxy. The latter, if confirmed, would be the first detection in γ-rays for this class of objects. A redshift z = 0.18 ± 0.01 has recently been claimed on the basis of the detection of a single X-ray line at 5.44 ± 0.05 keV which has been interpreted as a 6.4 keV (rest frame) fluorescent line. Aims: We aim to investigate the nature of 3FGL J1603.9-4903/PMN J1603-4904 using optical-to near-IR (NIR) spectroscopy. Methods: We observed PMN J1603-4904 with the UV-NIR VLT/X-Shooter spectrograph for two hours. We extracted spectra in the visible and NIR range that we calibrated in flux and corrected for telluric absorption. We systematically searched for absorption and emission features. Results: The source was detected starting from ~6300 Å down to 24 000 Å with an intensity similar to that of its 2MASS counterpart and a mostly featureless spectrum. The continuum lacks absorption features and thus is non-stellar in origin and most likely non-thermal. In addition to this spectrum, we detected three emission lines that we interpret as the Hα-[NII] complex, the [SII]λ,λ6716, 6731 doublet and the [SIII]λ 9530 line; we obtain a redshift estimate of z = 0.2321 ± 0.0004. The line ratios suggest that a LINER/Seyfert nucleus powers the emission. This new redshift measurement implies that the X-ray line previously detected should be interpreted as a 6.7 keV line which is very peculiar. Based on observations collected at the European Organisation for Astronomical Research in the Southern Hemisphere, Chile, under program 095.B-0400(A). The raw FITS data files are available in the ESO archive.

  19. Is computerised CBT really helpful for adult depression?-A meta-analytic re-evaluation of CCBT for adult depression in terms of clinical implementation and methodological validity.

    PubMed

    So, Mirai; Yamaguchi, Sosei; Hashimoto, Sora; Sado, Mitsuhiro; Furukawa, Toshi A; McCrone, Paul

    2013-04-15

    Depression is a major cause of disability worldwide, and computerised cognitive behavioural therapy (CCBT) is expected to be a more augmentative and efficient treatment. According to previous meta-analyses of CCBT, there is a need for a meta-analytic revaluation of the short-term effectiveness of this therapy and for an evaluation of its long-term effects, functional improvement and dropout. Five databases were used (MEDLINE, PsycINFO, EMBASE, CENTRAL and CiNii). We included all RCTs with proper concealment and blinding of outcome assessment for the clinical effectiveness of CCBT in adults (aged 18 and over) with depression. Using Cohen's method, the standard mean difference (SMD) for the overall pooled effects across the included studies was estimated with a random effect model. The main outcome measure and the relative risk of dropout were included in the meta-analysis. Fourteen trials met the inclusion criteria, and sixteen comparisons from these were used for the largest meta-analysis ever. All research used appropriate random sequence generation and Intention-to-Treat analyses (ITT), and employed self-reported measures as the primary outcome. For the sixteen comparisons (2807 participants) comparing CCBT and control conditions, the pooled SMD was -0.48 [95% IC -0.63 to -0.33], suggesting similar effect to the past reviews. Also, there was no significant clinical effect at long follow-up and no improvement of function found. Furthermore, a significantly higher drop-out rate was found for CCBT than for controls. When including studies without BDI as a rating scale and with only modern imputation as sensitivity analysis, the pooled SMD remained significant despite the reduction from a moderate to a small effect. Significant publication bias was found in a funnel plot and on two tests (Begg's p = 0.09; Egger's p = 0.01). Using a trim and fill analysis, the SMD was -0.32 [95% CI -0.49 to -0.16]. Despite a short-term reduction in depression at post-treatment, the

  20. MUSE discovers perpendicular arcs in the inner filament of Centaurus A

    NASA Astrophysics Data System (ADS)

    Hamer, S.; Salomé, P.; Combes, F.; Salomé, Q.

    2015-03-01

    Context. Evidence of active galactic nuclei (AGN) interaction with the intergalactic medium is observed in some galaxies and many cool core clusters. Radio jets are suspected to dig large cavities into the surrounding gas. In most cases, very large optical filaments (several kpc) are also seen all around the central galaxy. The origin of these filaments is still not understood. Star-forming regions are sometimes observed inside the filaments and are interpreted as evidence of positive feedback (AGN-triggered star formation). Aims: Centaurus A is a very nearby galaxy with huge optical filaments aligned with the AGN radio-jet direction. Here, we searched for line ratio variations along the filaments, kinematic evidence of shock-broadend line widths, and large-scale dynamical structures. Methods: We observed a 1' × 1' region around the so-called inner filament of Cen A with the Multi Unit Spectroscopic Explorer (MUSE) on the Very Large Telescope (VLT) during the Science Verification period. Results: (i) The brightest lines detected are the Hαλ6562.8, [NII]λ6583, [OIII]λ4959+5007 and [SII]λ6716+6731. MUSE shows that the filaments are made of clumpy structures inside a more diffuse medium aligned with the radio-jet axis. We find evidence of shocked shells surrounding the star-forming clumps from the line profiles, suggesting that the star formation is induced by shocks. The clump line ratios are best explained by a composite of shocks and star formation illuminated by a radiation cone from the AGN. (ii) We also report a previously undetected large arc-like structure: three streams running perpendicular to the main filament; they are kinematically, morphologically, and excitationally distinct. The clear difference in the excitation of the arcs and clumps suggests that the arcs are very likely located outside of the radiation cone and match the position of the filament only in projection. The three arcs are thus most consistent with neutral material swept along by a

  1. Seafloor Geodetic Observations West off Miyake-jima Island During January to April, 2001

    NASA Astrophysics Data System (ADS)

    Mochizuki, M.; Sato, M.; Yabuki, T.; Yoshida, Z.; Asada, A.

    2001-12-01

    An intensive earthquake swarm started under Miyake-jima Island, 180km south off Honshu, Japan, on June 26, 2000. The earthquake swarm migrated towards northwest off from Miyake-jima Island, where numerous earthquakes, more than 100,000, were detected within about two months and an extensive crustal deformation was observed by on-land geodetic observations. We started seafloor geodetic observation in this area to monitor seafloor deformation for the better understandings of underground magmatic activities. This poster presents summary of the observations and preliminary results from them. IIS has been developing a method of seafloor geodesy in corporation with JHD. A combination of kinematic GPS measurements and precise acoustic ranging techniques is employed to achieve centimeter-level seafloor geodesy. First observation site using the method was Kumano trough, where the Philippine Sea Plate subducts beneath Japan Islands arc. It was confirmed that the method could locate horizontal position of the seafloor reference points within 4 cm standard deviation ( Asada and Yabuki, 2001). We apply this seafloor positioning method to the observations conducted in the area west off Miyake-jima Island. Three seafloor reference systems ( Stations A, B, and C ), which consist of three or four acoustic mirror transponders, were built in triangle area surrounded by three islands, Miyake-jima, Nii-jima and Koudu-jima Islands, in November and December, 2000. This area would be deformed remarkably due to underground magma movement including magma injections from deeper part. Distances among three reference systems were set about 15 km. Stations A and B were located on the two sides of NW-SE trending seismically active area. The observations have been conducted three times until present, in January, February and April 2001. We obtained less data than we had expected due to bad sea condition in January and February observations. Also, a fast and quickly varying ocean current prevented

  2. A 2 THz Heterodyne Array Receiver for SOFIA

    NASA Technical Reports Server (NTRS)

    Walker, Christopher K.

    1996-01-01

    We proposed to perform a comprehensive design study of a 16-element heterodyne array receiver for SOFIA. The array was designed to utilize hot-electron bolometers in an efficient, low-cost waveguide mount to achieve low noise performance between approx. 1500 and 2400 GHz. Due to the prevailing physical conditions in the interstellar medium, this frequency range is one of the richest in the FIR portion of the spectrum. An array designed for this wavelength range will make excellent use of the telescope and the available atmospheric transmission, and will provide a new perspective on stellar, chemical, and galaxy evolution in the present as well as past epochs. A few of the most important molecular and atomic species which the instrument will sample are CII, OI, CO, OH, NII, and CH. The system used the most sensitive detectors available in an efficient optical system. The local oscillator was a compact CO2 pumped far-infrared laser currently under development for SOFIA. The backend spectrometer was an array acousto-optic spectrometer (aAOS). The spectrometer utilizes proven hardware and technologies to provide broadband performance (greater than or equal to 1 GHz per AOS channel) and high spectral resolution (1 MHz) with the maximum sensitivity and minimum complexity and cost. The proposed instrument would be the fastest and most sensitive heterodyne receiver ever to operate in the 1.5 - 2.4 THz band. One of the key technologies developed for the proposed instrument is the laser micromachining of waveguide structures. These structures provide both the optical link between the instrument and the telescope (via an array of efficient feedhorns) and the impedance transformation between the detectors and free space. With the assistance of funds provided from this grant, we were able to fabricate and test the world's first laser micromachined feedhorns. The quality of the waveguide structure is far better than that obtainable using any other fabrication technique. The beam

  3. VizieR Online Data Catalog: Star-forming dwarfs at intermediate-z in VUDS (Calabro+, 2017)

    NASA Astrophysics Data System (ADS)

    Calabro, A.; Amorin, R.; Fontana, A.; Perez-Montero, E.; Lemaux, B. C.; Ribeiro, B.; Bardelli, S.; Castellano, M.; Contini, T.; de Barros, S.; Garilli, B.; Grazian, A.; Guaita, L.; Hathi, N. P.; Koekemoer, A. M.; Le Fevre, O.; Maccagni, D.; Pentericci, L.; Schaerer, D.; Talia, M.; Tasca, L. A. M.; Zucca, E.

    2017-02-01

    Stellar masses (Ms) and 1-sigma uncertainties have been derived from the SED fitting code Le Phare (Ilbert et al., 2006A&A...524A..76B). A Chabrier (2003PASP..115..763C) IMF and Calzetti et al. (2000ApJ...533..682C) extinction law are adopted, while the contribution of emission lines to the stellar templates have been considered following Ilbert et al. (2009ApJ..690..1236I). Typical 1-sigma uncertainties in Ms are ~0.2dex and are obtained from the median of the probability distribution function (PDF). Thus, they do not account for possible systematic error (e.g., IMF variations). Star formation rates have been derived from Hα or Hβ luminosity (IMF from Chabrier et al. (2003PASP..115..763C) and assuming a theoretical ratio Hα/Hβ=2.82) following Kennicutt (1998ApJ...498..541K). Uncertainties in SFR account for the propagation of errors in line fluxes. Gas-phase metallicities, ionization parameters, and their uncertainties, have been derived using the code HII-CHI-mistry (HCm, Perez-Montero et al., 2014MNRAS.441.2663P), which is based on the comparison between a set of observed line ratios ([OII]3727,[OIII]4363,[OIII]5007,[NII]6584, [SII]6717+6731, all relative to Hβ) and the predictions of photoionization models. HCm provides abundances that are consistent with those derived from the direct method. Morphological type for each galaxy is based on HST-ACS F814W band images, available for COSMOS and ECDFS fields, and follows the criteria of Amorin et al. (2015A&A...578A.105A). The effective radius and axis ratio have been derived on the same images using GALFIT (Peng et al., 2002AJ....124..266P, 2010AJ....139.2097P) , following the methodology presented in Ribeiro et al. (2016A&A...593A..22R), in those cases when no error is found in the fitting procedure. The gas surface densities 'sgas' and total gas masses 'Mgas' were derived by inverting an assumedly non-variable Kennicutt-Schmidt (KS) law (Kennicutt & Evans, 2012ARA&A..50..531K) with exponent n=1.4. Then, gas

  4. Dithiolato- and halogenido-bridged nickel-iron complexes related to the active site of [NiFe]-H2ases: preparation, structures, and electrocatalytic H2 production.

    PubMed

    Song, Li-Cheng; Han, Xiao-Feng; Chen, Wei; Li, Jia-Peng; Wang, Xu-Yong

    2017-08-14

    A new series of the structural and functional models for the active site of [NiFe]-H 2 ases has been prepared by a simple and convenient synthetic route. Thus, treatment of diphosphines RN(PPh 2 ) 2 (1a, R = p-MeC 6 H 4 CH 2 ; 1b, R = EtO 2 CCH 2 ) with an equimolar NiCl 2 ·6H 2 O, NiBr 2 ·3H 2 O, and NiI 2 in refluxing CH 2 Cl 2 /MeOH or EtOH gave the mononuclear Ni complexes RN(PPh 2 ) 2 NiX 2 (2a, R = p-MeC 6 H 4 CH 2 , X = Cl; 2b, R = EtO 2 CCH 2 , X = Cl; 3a, R = p-MeC 6 H 4 CH 2 , X = Br; 3b, R = EtO 2 CCH 2 , X = Br; 4a, R = p-MeC 6 H 4 CH 2 , X = I; 4b, R = EtO 2 CCH 2 , X = I) in 67-97% yields. Further treatment of complexes 2a,b-4a,b with an equimolar mononuclear Fe complex (dppv)(CO) 2 Fe(pdt) and NaBF 4 resulted in formation of the targeted model complexes [RN(PPh 2 ) 2 Ni(μ-pdt)(μ-X)Fe(CO)(dppv)](BF 4 ) (5a, R = p-MeC 6 H 4 CH 2 , X = Cl; 5b, R = EtO 2 CCH 2 , X = Cl; 6a, R = p-MeC 6 H 4 CH 2 , X = Br; 6b, R = EtO 2 CCH 2 , X = Br; 7a, R = p-MeC 6 H 4 CH 2 , X = I; 7b, R = EtO 2 CCH 2 , X = I) in 60-96% yields. All the new complexes 3a,b-4a,b and 5a,b-7a,b have been characterized by elemental analysis and spectroscopy, and particularly for some of them (3a,b/4a,b and 5b/6b) by X-ray crystallography. More interestingly, the electrochemical and electrocatalytic properties of such halogenido-bridged model complexes are first studied systematically and particularly they have been found to be pre-catalysts for proton reduction to H 2 under CV conditions.

  5. A radical pathway in catecholase activity with nickel(II) complexes of phenol based "end-off" compartmental ligands.

    PubMed

    Ghosh, Totan; Adhikary, Jaydeep; Chakraborty, Prateeti; Sukul, Pradip K; Jana, Mahendra Sekhar; Mondal, Tapan Kumar; Zangrando, Ennio; Das, Debasis

    2014-01-14

    Seven dinuclear and one dinuclear based dicyanamide bridged polymeric Ni(II) complexes of phenol based compartmental ligands (HL(1)-HL(4)) have been synthesized with the aim to investigate their catecholase-like activity and to evaluate the most probable mechanistic pathway involved in this process. The complexes have been characterized by routine physicochemical studies as well as by X-ray single crystal structure analyses namely [Ni2(L(2))(SCN)3(H2O)(CH3OH)] (), [Ni2(L(4))(SCN)3(CH3OH)2] (), [Ni2(L(2))(SCN)2(AcO)(H2O)] (), [Ni2(L(4))(SCN)(AcO)2] (), [Ni2(L(2))(N3)3(H2O)2] (), [Ni2(L(4))(N3)3(H2O)2] (), [Ni2(L(1))(AcO)2(N(CN)2)]n () and [Ni2(L(3))(AcO)2(N(CN)2)] (), [SCN = isothiocyanate, AcO = acetate, N3 = azide, and N(CN)2 = dicyanamide anion; L(1-4) = 2,6-bis(R2-iminomethyl)-4-R1-phenolato, where R1 = methyl and tert-butyl, R2 = N,N-dimethyl ethylene for L(1-2) and R1 = methyl and tert-butyl, R2 = 2-(N-ethyl) pyridine for L(3-4)]. A UV-vis spectrophotometric study using 3,5-di-tert butylcatechol (3,5-DTBC) reveals that all the complexes are highly active in catalyzing the aerobic oxidation of (3,5-DTBC) to 3,5-di-tert-butylbenzoquinone (3,5-DTBQ) in methanol medium with the formation of hydrogen peroxide. An EPR study confirms the generation of radicals during the catalysis. Cyclic voltammetric studies of the complexes in the presence and absence of 3,5-DTBC have been performed. Reduction of Ni(II) to Ni(I) and that of the imine bond of the ligand system have been detected at ∼-1.0 V and ∼-1.5 V, respectively. Coulometric separation of the species at -1.5 V followed by the EPR study at 77 K confirms the species as an organic radical and thus most probably reduced imine species. Spectroelectrochemical analysis at -1.5 V clearly indicates the oxidation of 3,5-DTBC and thus suggests that the radical pathway is supposed to be responsible for the catecholase-like activity exhibited by the nickel complexes. The ligand centred radical generation has further been

  6. Hα imaging observations of early-type galaxies from the ATLAS3D survey

    NASA Astrophysics Data System (ADS)

    Gavazzi, G.; Consolandi, G.; Pedraglio, S.; Fossati, M.; Fumagalli, M.; Boselli, A.

    2018-03-01

    Context. The traditional knowledge of the mechanisms that brought to the formation and evolution of early type galaxies (ETG) in a hierarchical Universe was challenged by the unexpected finding by ATLAS3D that 86% ETGs show signs of a fast rotating disk at their interior, implying an origin common to most spiral galaxies, followed by a quenching phase, while only a minority of the most massive systems are slow rotators and were likely to be the products of merger events. Aims: Our aim is to improve our knowledge on the content and distribution of ionised hydrogen and their usage to form stars in a representative sample of ETGs for which the kinematics and detailed morphological classification were known from ATLAS3D. Methods: Using narrow-band filters centered on the redshifted Hα line along with a broad-band (r-Gunn) filter to recover the stellar continuum, we observed or collected existing imaging observations for 147 ETG (including members of the Virgo cluster), representative of the whole ATLAS3D survey. Results: 55 ETGs (37%) were detected in the Hα line above our detection threshold (HαEW ≤ -1 Å) and 21 harbour a strong source (HαEW ≤ -5 Å) . Conclusions: The strong Hα emitters appear associated with mostly low-mass (M* 1010 M⊙) S0 galaxies which contain conspicuous stellar and gaseous disks, harbouring significant star formation at their interior, including their nuclei. The weak Hα emitters are almost one order of magnitude more massive, contain gas-poor disks and harbour an AGN at their centers. Their emissivity is dominated by [NII] and does not imply star formation. The 92 undetected ETGs constitute the majority in our sample and are gas-free systems which lack a disk and exhibit passive spectra even in their nuclei. These pieces of evidence reinforce the conclusion of Cappellari (2016, ARA&A, 54, 597) that the evolution of ETGs followed the secular channel for the less massive systems and the dry merging channel for the most massive

  7. Repeated Seafloor Geodetic Observation west off Miyake-jima volcanic island

    NASA Astrophysics Data System (ADS)

    Mochizuki, M.; Sato, M.; Fujita, M.; Katayama, M.; Yoshida, Z.; Yabuki, T.; Asada, A.

    2003-12-01

    An intensive earthquake swarm started under Miyake-jima island, 180 km south off Japan main island, on June 26, 2000. The earthquake swarm migrated towards northwest off Miyake-jima island, where numerous earthquakes, more than 100,000, were detected within about two months and an extensive crustal deformation was observed by on-land geodetic observations. Inst. of Industrial Science, Univ. of Tokyo and Hydrographic and Oceanographic Dept, Japan Coast Guard deployed three seafloor geodetic reference stations (St.A, St.B & St.C) in triangle area surrounded by three islands, Miyake-jima, Nii-jima and Kouzu-jima islands, in November and December, 2000, and have been conducting observations using these three stations to monitor seafloor deformation for the better understandings of underground magmatic activities. The observations have been conducted thirteen times until present. Fast and quickly varying ocean current in this area prevented us from stable observation. The surface current makes the pole, which connects the GPS antenna and the ship-board transducer, bend. This bending of the pole gave uncertainty to the analyses of locating the positions of the seafloor geodetic reference stations. The pole was replaced new, more rigid pole to overcome the problem in August 2002. The first observation with this new system was conducted at the reference station in the Sagami-bay. Smaller amount of bending with the new pole than that with the old one against both roll and pitch components could be seen in the data from this observation. This shows that the replacement of the pole provided stability to the observation system. We started to adopt the new system to the observation at the three stations west-off Miyake-jima island area, too. Station C, that is located nearest one to the Miyake-jima island, is one where we had most frequent observation after improvement of the system. The observations with the new system have been conducted four times in September, December 2002

  8. Crustal Deformation in the Kanto District, Central Japan, Following the 2000 Seismo-volcanic Activity of the Izu Islands

    NASA Astrophysics Data System (ADS)

    Sagiya, T.

    2004-12-01

    Starting from June 26, 2000, an unprecedented seismic activity occurred around the Miyake-jima, Kohzu-shima, and Nii-jima Islands, in the northern Izu islands. This seismic swarm activity was initiated by the volcanic magma intrusion beneath the Miyake-jima volcano. An intrusion of massive (about 1km3) magma caused the seismic swarm activity and magnificent crustal deformation in the surrounding area within about 200km from the source region. After the seismic swarm activity calmed down, we detect a change in crustal displacement rates in the southern Kanto region from daily coordinate solutions of the continuous GPS network. Interestingly, the change appears mostly in the E-W components. Comparison of GPS velocity data for two time periods (1996-200 and 2001-2002) indicate that the westward displacement rate decreased by about 25% (from 23 mm/yr to 17 mm/yr) at Tateyama, the southern tip of the Boso Peninsula. On the other hand, we do not see significant changes in the N-S and vertical components. Continuous monitoring of crustal displacements with GPS has revealed that the post-swarm deformation is now coming back to the pre-swarm steady state. That is, the time series of E-W component show transient curves, converging into the original steady state. The transient curve can be equally well reproduced by an exponential decay or a logarithmic function. The relaxation time for the exponential curve is estimated as about 3 years. One possible explanation for this transient deformation is viscoelastic relaxation. Since the Izu Islands are situated on the oceanic Philippine Sea plate, the upper mantle with a low viscosity would response to the huge stress change cause by the magma intrusion. The other possibility is a change of frictional property on the plate interface between the Philippine Sea and the Pacific plate. Under the southern Kanto area, the subducted Philippine Sea slab leans on the subdcted Pacific slab. Interaction between these two oceanic plates is

  9. Homogeneous Electrocatalytic Reduction of Carbon Dioxide to Carbon Monoxide by Ni(cyclam)

    NASA Astrophysics Data System (ADS)

    Froehlich, Jesse Dan

    The homogeneous electrochemical reduction of CO2 by the molecular catalyst [Ni(cyclam)]2+ was studied by electrochemistry and infrared spectroelectrochemistry. This catalyst has been previously shown to have increased CO2 reduction activity when adsorbed on a mercury electrode. The homogeneous reactivity, without a mercury electrode, was often ignored in the literature. Ni(cyclam) was found to efficiently and selectively produce CO at moderate overpotentials in both aqueous and mixed organic solvent systems in a homogenous fashion at an inert glassy carbon electrode. Methylated analogs of Ni(cyclam) were also studied and observed to have more positive reduction potentials and attenuated CO2 reduction activity. The electrochemical kinetics were probed by varying CO2 substrate and proton concentrations. Products of CO2 reduction are observed in infrared spectra obtained from spectroelectrochemical experiments. The two major species observed were a Ni(I) carbonyl, [Ni(cyclam)(CO)]+, and a Ni(II) coordinated bicarbonate, [Ni(cyclam)(CO2OH)] +. The rate-limiting step during electrocatalysis was determined to be CO loss from the deactivated species, [Ni(cyclam)(CO)]+, to produce the active catalyst, [Ni(cyclam)]+. Another macrocyclic complex, [Ni(TMC)]+, was deployed as a CO scavenger in order to inhibit the deactivation of [Ni(cyclam)] + by CO. Addition of the CO scavenger was shown to dramatically increase the catalytic current observed for CO2 reduction by [Ni(cyclam)] +. Evidence for the [Ni(TMC)]+ acting as a CO scavenger includes the observation of [Ni(TMC)(CO)]+ by IR. Density functional theory calculations, probing the optimized geometry of the [Ni(cyclam)(CO)] + species, are also presented. These findings have implications on the increased activity for CO2 reduction when [Ni(cyclam)] + is adsorbed on a mercury electrode. The [Ni(cyclam)(CO)] + structure has significant distortion of the Ni center out of the plane of the cyclam nitrogens. This distortion

  10. Natural 'background' soil water repellency in conifer forests: its prediction and relationship to wildfire occurrence

    NASA Astrophysics Data System (ADS)

    Doerr, Stefan; Woods, Scott; Martin, Deborah; Casimiro, Marta

    2013-04-01

    Soils under a wide range of vegetation types exhibit water repellency following the passage of a fire. This is viewed by many as one of the main causes for accelerated post-fire runoff and soil erosion and it has often been assumed that strong soil water repellency present after wildfire is fire-induced. However, high levels of repellency have also been reported under vegetation types not affected by fire, and the question arises to what degree the water repellency observed at burnt sites actually results from fire. This study aimed at determining 'natural background' water repellency in common coniferous forest types in the north-western USA. Mature or semi-mature coniferous forest sites (n = 81), which showed no evidence of recent fires and had at least some needle cast cover, were sampled across six states. After careful removal of litter and duff at each site, soil water repellency was examined in situ at the mineral soil surface using the Water Drop Penetration Time (WDPT) method for three sub-sites, followed by col- lecting near-surface mineral soil layer samples (0-3 cm depth). Following air-drying, samples were fur- ther analyzed for repellency using WDPT and contact angle (hsl) measurements. Amongst other variables examined were dominant tree type, ground vegetation, litter and duff layer depth, slope angle and aspect, elevation, geology, and soil texture, organic carbon content and pH. 'Natural background' water repellency (WDPT > 5 s) was detected in situ and on air-dry samples at 75% of all sites examined irrespective of dominant tree species (Pinus ponderosa, Pinus contorta, Picea engelma- nii and Pseudotsuga menziesii). These findings demonstrate that the soil water repellency commonly observed in these forest types following burning is not necessarily the result of recent fire but can instead be a natural characteristic. The notion of a low background water repellency being typical for long- unburnt conifer forest soils of the north-western USA is

  11. Extreme Ultraviolet Spectroscopy of the Thermosphere from the RAIDS Experiment on the ISS

    NASA Astrophysics Data System (ADS)

    Bishop, R. L.; Stephan, A. W.; Christensen, A. B.; Budzien, S. A.; Straus, P. R.; van Epps, Z.

    2009-12-01

    The RAIDS experiment is a suite of eight instruments to be flown aboard the Japanese Experiment Module-Exposed Facility on the International Space Station (ISS) in 2009. One of the sensors is the Extreme Ultraviolet Spectrograph (EUVS). The EUVS measures the radiance of the Earth’s airglow with a f/5 Wadsworth spectrograph fronted by a mechanical grid collimator. The 0.1 x 2.3 degree field of view is imaged onto a wedge-and-strip two dimensional detector and collapsed into a one-dimensional spectrum. The vertical profile is assembled from a series of these spectra obtained as the RAIDS platform scans in altitude. Two grating positions provide coverage of the 50.0-85.0 nm region or the 77.0-110.0 nm region at 1.2 nm spectral resolution. We will present a discussion of the scientific targets for the RAIDS EUVS and, if launched on schedule, also the first spectra observed from this sensor. The EUVS is sensitive to a number of emissions in the Earth’s dayglow including atomic and ionized oxygen and argon, ionized nitrogen, and atomic helium. One of the primary RAIDS science objectives is to use the EUVS to obtain simultaneous OII 83.4 nm and 61.7 nm limb profiles to perform an in-depth investigation of the OII excitation and emission processes in the daytime ionosphere. Some of the more dominant spectral features such as the OI (98.9, 102.7 nm), OII (83.4, 61.7 nm), and NII (108.5, 91.6 nm) lines will provide the opportunity to develop new methods to monitor thermospheric O and N2. The OI (102.7 nm) observations may also be used, in conjunction with other RAIDS measurements, to retrieve the spectrally unresolved H Lyman beta and thus a measure of atomic hydrogen. The argon emissions Ar I (104.8, 106.7 nm) and Ar II (91.96, 93.21 nm) will provide information on its relative abundance in the lower thermosphere. . Combinations of measurements, such as the EUVS OI (98.9 nm) and the RAIDS Near Infrared Spectrometer OI (799.0 nm) emission can be used to probe the details

  12. NGC 6334 and NGC 6357. Insights from spectroscopy of their OB star populations

    NASA Astrophysics Data System (ADS)

    Russeil, D.; Adami, C.; Bouret, J. C.; Hervé, A.; Parker, Q. A.; Zavagno, A.; Motte, F.

    2017-11-01

    NGC 6334. Finally, from the analysis of nebular lines (Hα, [NII], and [SII]) from spectra from several regions of ionised gas, we confirm that the filaments in NGC 6357 are shock heated. Full Tables 2 and A.1 and the normalised observed spectra displayed in Figs. B.1 are available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/607/A86

  13. Ionized haloes in planetary nebulae: new discoveries, literature compilation and basic statistical properties

    NASA Astrophysics Data System (ADS)

    Corradi, R. L. M.; Schönberner, D.; Steffen, M.; Perinotto, M.

    2003-04-01

    We present a comprehensive observational study of haloes around planetary nebulae (PNe). Deep Hα+[NII] and/or [OIII] narrow-band images have been obtained for 35 PNe, and faint extended haloes have been newly discovered in the following 10 objects: Cn 1-5, IC 2165, IC 2553, NGC 2792, NGC 2867, NGC 3918, NGC 5979, NGC 6578, PB 4, and possibly IC 1747. New deep images have also been obtained of other known or suspected haloes, including the huge extended emission around NGC 3242 and Sh 2-200. In addition, the literature was searched, and together with the new observations an improved data base containing some 50 PN haloes has been compiled. The halo sample is illustrated in an image atlas contained in this paper, and the original images are made available for use by the scientific community at http://www.ing. iac.es/~rcorradi/HALOES/. The haloes have been classified following the predictions of modern radiation-hydrodynamical simulations that describe the formation and evolution of ionized multiple shells and haloes around PNe. According to the models, the observed haloes have been divided into the following groups: (i) circular or slightly elliptical asymptotic giant branch (AGB) haloes, which contain the signature of the last thermal pulse on the AGB; (ii) highly asymmetrical AGB haloes; (iii) candidate recombination haloes, i.e. limb-brightened extended shells that are expected to be produced by recombination during the late post-AGB evolution, when the luminosity of the central star drops rapidly by a significant factor; (iv) uncertain cases which deserve further study for a reliable classification; (v) non-detections, i.e. PNe in which no halo is found to a level of <~10-3 the peak surface brightness of the inner nebulae. We discuss the properties of the haloes: detection rate, morphology, location of the central stars in the Hertzsprung-Russell diagram, sizes, surface brightness profiles, and kinematical ages. Among the most

  14. Feeding and feedback in radio galaxies of the local universe

    NASA Astrophysics Data System (ADS)

    Couto, Guilherme dos Santos

    2016-10-01

    We present integral field spectroscopic data covering the inner kiloparsecs of four radio galaxies of the local Universe (z<0.07), Arp 102B, Pictor A, 3C 33 and 4C +29.30, obtained with the GMOS-IFU instrument of the Gemini telescopes. We use these data to analyze the gas excitation and kinematics via two-dimensional maps. Using the flux distributions of the emission lines, we identify extended emission in ionized gas up to the edges of the observed field, which corresponds to 1.7 kpc x 2.5 kpc for Arp 102B, 2.5 kpc x 3.4 kpc for Pictor A, 4.0 kpc x 5.8 kpc for 3C 33 and 4.3 kpc x 6.2 kpc for 4C +29.30. The extended line emitting gas displays structures resembling rotating disks, spiral arms and bars. Line ratios indicate that both photons from the nuclear source and shocks originated in the interaction of the radio jet with circumnuclear gas are ionizing mechanisms of the gas. Line ratio values are typical of Seyfert galaxies for 3C 33 and 4C +29.30, while intermediate values between Seyferts and LINERs are observed in Arp 102B. Pictor A galaxy, however, shows low values of [NII]/Ha=0.15-0.25, expected for HII regions. We suggest that these values are observed due to the low gas metallicity (12+log(O/H)=8.39). Centroid velocity maps show that the gas kinematics is dominated by rotation only in Arp 102B and 3C 33. Outflows are observed in the galaxies Arp 102B, 3C 33 and 4C +29.30. We obtain mass outflow rates of 0.32-0.49 Msun per year, but the outflow kinetic power is small, ranging 0.04-0.07% of the AGN bolometric luminosity, indicating that the feedback has little impact in the host galaxies evolution. The high masses of ionized gas, ranging from 7.4E7 to 4.6E8 Msun, and the fact that these galaxies are early-type, suggest an external origin of the gas. Indeed, it is observed evidence of interaction with companion galaxies in Arp 102B, Pictor A and 4C +29.30. We suggest that the capture of mass has triggered the nuclear activity in these galaxies, with the high

  15. Planetary Nebulae in the Solar Neighbourhood: Statistics, Distance Scale and Luminosity Function

    NASA Astrophysics Data System (ADS)

    Frew, David J.

    2008-07-01

    An accurate census of the nearest planetary nebulae (PNe) is needed for calculations of the total number, space density, scale height, and birth rate of PNe in the Galaxy, to understand the dynamics of an evolving nebula and its relationship to the cooling history of the central star, and also to provide an unbiased sample to investigate the frequency of binary central stars and their role in the formation and shaping of these objects. This study presents the most refined volume-limited survey of PNe known to date. Integrated H-alpha fluxes for over 400 mostly evolved PNe are presented, based primarily on data from the Southern H-alpha Sky Survey Atlas (SHASSA) and the Virginia Tech Spectral-Line Survey (VTSS). Aperture photometry on the digital images was performed to extract H-alpha+[NII] fluxes. The [NII] contribution was then de-convolved using literature data, new data from slit spectra, or spectrophotometric data from the Wisconsin H-Alpha Mapper (WHAM) also obtained as part of this project. Comparison with previous work shows that the flux scale presented here has no significant zero-point error. The H-alpha fluxes are used to determine new Zanstra temperatures for those PNe with accurate central star photometry, calculating surface-brightness distances for each PN in the sample, and in conjunction with accurate [OIII] fluxes, new absolute PN magnitudes for delineating the faint end of the PN luminosity function. A spectroscopic survey of a range of MASH PNe is also presented. New emission-line intensities for 60 PNe are given, including a preliminary discussion of the chemical abundances of this sample. New distances have been determined for a large number of PNe, by either critically examining the literature, or by deriving new extinction and kinematic distances where suitable. For all PNe not amenable to these approaches, distances were estimated from a new H-alpha surface brightness-radius (SB-r) relation. The Hα SB-r relation covers >6 dex in SB, and

  16. ALMA reveals a warm and compact starburst around a heavily obscured supermassive black hole at z = 4.75

    NASA Astrophysics Data System (ADS)

    Gilli, R.; Norman, C.; Vignali, C.; Vanzella, E.; Calura, F.; Pozzi, F.; Massardi, M.; Mignano, A.; Casasola, V.; Daddi, E.; Elbaz, D.; Dickinson, M.; Iwasawa, K.; Maiolino, R.; Brusa, M.; Vito, F.; Fritz, J.; Feltre, A.; Cresci, G.; Mignoli, M.; Comastri, A.; Zamorani, G.

    2014-02-01

    km s-1 velocity shift observed between the Lyα emission and the submm lines ([CII], CO(2-1), [NII]) and with the highly-ionized Fe emission line at ~6.9 keV rest-frame tentatively observed in the X-ray spectrum. Finally, our observations show that, besides the mass, star formation rate and gas depletion timescale, XID403 has also the right size to be one of the progenitors of the compact quiescent massive galaxies seen at z ~ 3.

  17. The ionized gas in the CALIFA early-type galaxies. I. Mapping two representative cases: NGC 6762 and NGC 5966

    NASA Astrophysics Data System (ADS)

    Kehrig, C.; Monreal-Ibero, A.; Papaderos, P.; Vílchez, J. M.; Gomes, J. M.; Masegosa, J.; Sánchez, S. F.; Lehnert, M. D.; Cid Fernandes, R.; Bland-Hawthorn, J.; Bomans, D. J.; Marquez, I.; Mast, D.; Aguerri, J. A. L.; López-Sánchez, Á. R.; Marino, R. A.; Pasquali, A.; Perez, I.; Roth, M. M.; Sánchez-Blázquez, P.; Ziegler, B.

    2012-04-01

    As part of the ongoing CALIFA survey, we have conducted a thorough bidimensional analysis of the ionized gas in two E/S0 galaxies, NGC 6762 and NGC 5966, aiming to shed light on the nature of their warm ionized ISM. Specifically, we present optical (3745-7300 Å) integral field spectroscopy obtained with the PMAS/PPAK integral field spectrophotometer. Its wide field-of-view (1' × 1') covers the entire optical extent of each galaxy down to faint continuum surface brightnesses. To recover the nebular lines, we modeled and subtracted the underlying stellar continuum from the observed spectra using the STARLIGHT spectral synthesis code. The pure emission-line spectra were used to investigate the gas properties and determine the possible sources of ionization. We show the advantages of IFU data in interpreting the complex nature of the ionized gas in NGC 6762 and NGC 5966. In NGC 6762, the ionized gas and stellar emission display similar morphologies, while the emission line morphology is elongated in NGC 5966, spanning ~6 kpc, and is oriented roughly orthogonal to the major axis of the stellar continuum ellipsoid. Whereas gas and stars are kinematically aligned in NGC 6762, the gas is kinematically decoupled from the stars in NGC 5966. A decoupled rotating disk or an "ionization cone" are two possible interpretations of the elongated ionized gas structure in NGC 5966. The latter would be the first "ionization cone" of such a dimension detected within a weak emission-line galaxy. Both galaxies have weak emission-lines relative to the continuum[EW(Hα) ≲ 3 Å] and have very low excitation, log([Oiii]λ5007/Hβ) ≲ 0.5. Based on optical diagnostic ratios ([Oiii]λ5007/Hβ, [Nii]λ6584/Hα, [Sii]λ6717, 6731/Hα, [Oi]λ6300/Hα), both objects contain a LINER nucleus and an extended LINER-like gas emission. The emission line ratios do not vary significantly with radius or aperture, which indicates that the nebular properties are spatially homogeneous. The gas emission

  18. RCoronae Borealis at the 2003 light minimum

    NASA Astrophysics Data System (ADS)

    Kameswara Rao, N.; Lambert, David L.; Shetrone, Matthew D.

    2006-08-01

    A set of five high-resolution optical spectra of R CrB obtained in 2003 March is discussed. At the time of the first spectrum (March 8), the star was at V = 12.6, a decline of more than six magnitudes. By March 31, the date of the last observation, the star at V = 9.3 was on the recovery to maximum light (V = 6). The 2003 spectra are compared with the extensive collection of spectra from the 1995-1996 minimum presented previously. Spectroscopic features common to the two minima include the familiar ones also seen in spectra of other R Coronae Borealis stars (RCBs) in decline: sharp emission lines of neutral and singly ionized atoms, broad emission lines including HeI, [NII] 6583 Å, Na D and CaII H & K lines, and blueshifted absorption lines of Na D, and KI resonance lines. Prominent differences between the 2003 and 1995-1996 spectra are seen. The broad Na D and Ca H & K lines in 2003 and 1995-1996 are centred approximately on the mean stellar velocity. The 2003 profiles are fit by a single Gaussian, but in 1995-1996 two Gaussians separated by about 200 km s-1 were required. However, the HeI broad emission lines are fit by a single Gaussian at all times; the emitting He and Na-Ca atoms are probably not colocated. The C2 Phillips 2-0 lines were detected as sharp absorption lines and the C2 Swan band lines as sharp emission lines in 2003, but in 1995-1996 the Swan band emission lines were broad and the Phillips lines were undetected. The 2003 spectra show CI sharp emission lines at minimum light with a velocity changing in 5 d by about 20 km s-1 when the velocity of `metal' sharp lines is unchanged; the CI emission may arise from shock-heated gas. Reexamination of spectra obtained at maximum light in 1995 shows extended blue wings to strong lines with the extension dependent on a line's lower excitation potential; this is the signature of a stellar wind, also revealed by published observations of the HeI 10830 Å line at maximum light. Changes in the cores of the

  19. Approximate theoretical model for the five electronic states ( Ω = 5/2, 3/2, 3/2, 1/2, 1/2) arising from the ground 3d 9 configuration in nickel halide molecules and for rotational levels of the two Ω = 1/2 states in that manifold

    NASA Astrophysics Data System (ADS)

    Hougen, Jon T.

    2011-05-01

    their difference can vary between -10 B and +10 B. These theoretical results are in good agreement with the two observed p values for both NiF and NiCl. The present formalism should in principle be applicable to NiBr and NiI, and to the halides of palladium, since Pd + has a well isolated 4d 9 electronic ground configuration. Extension to metal halides having d n configurations with n < 9, or to platinum halides may present difficulties, since manifolds from the d n and d n-1s configurations may be heavily mixed, thus requiring "too many" parameters in the electronic part of the problem. Application to linear triatomic molecules may also present problems because of the large number of vibronic perturbations made possible by their four vibrational degrees of freedom.

  20. A 2 THz Heterodyne Array Receiver for SOFIA

    NASA Technical Reports Server (NTRS)

    Walker, Christopher K.

    1998-01-01

    We proposed to perform a comprehensive design study of a 16-element heterodyne array receiver for SOFIA. The array was designed to utilize hot-electron bolometers in an efficient, low-cost waveguide mount to achieve low noise performance between approx. 1500 and 2400 GHz. Due to the prevailing physical conditions in the interstellar medium, this frequency range is one of the richest in the FIR portion of the spectrum. An array designed for this wavelength range will make excellent use of the telescope and the available atmospheric transmission, and will provide a new perspective on stellar, chemical, and galaxy evolution in the present as well as past epochs. A few of the most important molecular and atomic species which the instrument will sample are CII, OI, CO, OH, NII, and CH. The system used the most sensitive detectors available in an efficient optical system. The local oscillator was a compact CO2 pumped far-infrared laser currently under development for SOFIA. The backend spectrometer was an array acousto-optic spectrometer (aAOS). The spectrometer utilizes proven hardware and technologies to provide broadband performance (greater than or equal to 1 GHz per AOS channel) and high spectral resolution (1 MHz) with the maximum sensitivity and minimum complexity and cost. The proposed instrument would be the fastest and most sensitive heterodyne receiver ever to operate in the 1.5 - 2.4 THz band. One of the key technologies developed for the proposed instrument is the laser micromachining of waveguide structures. These structures provide both the optical link between the instrument and the telescope (via an array of efficient feedhorns) and the impedance transformation between the detectors and free space. With the assistance of funds provided from this grant, we were able to fabricate and test the world's first laser micromachined feedhorns. Figure 1 is a photograph of the 2 THz double feedhorn structure designed and constructed under the auspices of this grant

  1. A VLT VIMOS study of the anomalous BCD Mrk996: mapping the ionized gas kinematics and abundances

    NASA Astrophysics Data System (ADS)

    James, B. L.; Tsamis, Y. G.; Barlow, M. J.; Westmoquette, M. S.; Walsh, J. R.; Cuisinier, F.; Exter, K. M.

    2009-09-01

    A study of the blue compact dwarf (BCD) galaxy Mrk996 based on high-resolution optical Very Large Telescope Visible Multi-Object Spectrograph integral field unit spectroscopy is presented. Mrk996 displays multicomponent line emission, with most line profiles consisting of a narrow, central Gaussian [full width at half-maximum (FWHM) ~ 110kms-1] with an underlying broad component (FWHM ~ 400kms-1). The broad HI Balmer component splits into two separate broad components inside a 1.5-arcsec radius from the nucleus; these are attributed to a two-armed minispiral. This spiral-like nucleus rotates in the same sense as the extended narrow line ionized gas but is offset by ~50kms-1 from the systemic velocity of the galaxy. The rotation curve of Mrk996 derived from the Hα narrow component yields a total mass of 5 × 108Msolar within a radius of 3kpc. From the Hα luminosity we infer a global star formation rate of ~2Msolaryr-1. The high excitation energy, high critical density [OIII] λ4363 and [NII] λ5755 lines are only detected from the inner region and exist purely in broad component form, implying unusual excitation conditions. Surface brightness, radial velocity and FWHM maps for several emission components are presented. A separate physical analysis of the broad and narrow emission line regions is undertaken. We derive an upper limit of 10000K for the electron temperature of the narrow line gas, together with an electron density of 170cm-3, typical of normal HII regions. For the broad line component, measured [OIII] and [FeIII] diagnostic line ratios are consistent with a temperature of 11000K and an electron density of 107cm-3. The broad line emission regions show N/H and N/O enrichment factors of ~20 relative to the narrow line regions, but no He/H, O/H, S/H or Ar/H enrichment is inferred. Previous studies indicated that Mrk996 showed anomalously high N/O ratios compared with BCDs of a similar metallicity. Our multicomponent analysis yields a revised metallicity

  2. Towards more stable operation of the Tokyo Tier2 center

    NASA Astrophysics Data System (ADS)

    Nakamura, T.; Mashimo, T.; Matsui, N.; Sakamoto, H.; Ueda, I.

    2014-06-01

    The Tokyo Tier2 center, which is located at the International Center for Elementary Particle Physics (ICEPP) in the University of Tokyo, was established as a regional analysis center in Japan for the ATLAS experiment. The official operation with WLCG was started in 2007 after the several years development since 2002. In December 2012, we have replaced almost all hardware as the third system upgrade to deal with analysis for further growing data of the ATLAS experiment. The number of CPU cores are increased by factor of two (9984 cores in total), and the performance of individual CPU core is improved by 20% according to the HEPSPEC06 benchmark test at 32bit compile mode. The score is estimated as 18.03 (SL6) per core by using Intel Xeon E5-2680 2.70 GHz. Since all worker nodes are made by 16 CPU cores configuration, we deployed 624 blade servers in total. They are connected to 6.7 PB of disk storage system with non-blocking 10 Gbps internal network backbone by using two center network switches (NetIron MLXe-32). The disk storage is made by 102 of RAID6 disk arrays (Infortrend DS S24F-G2840-4C16DO0) and served by equivalent number of 1U file servers with 8G-FC connection to maximize the file transfer throughput per storage capacity. As of February 2013, 2560 CPU cores and 2.00 PB of disk storage have already been deployed for WLCG. Currently, the remaining non-grid resources for both CPUs and disk storage are used as dedicated resources for the data analysis by the ATLAS Japan collaborators. Since all hardware in the non-grid resources are made by same architecture with Tier2 resource, they will be able to be migrated as the Tier2 extra resource on demand of the ATLAS experiment in the future. In addition to the upgrade of computing resources, we expect the improvement of connectivity on the wide area network. Thanks to the Japanese NREN (NII), another 10 Gbps trans-Pacific line from Japan to Washington will be available additionally with existing two 10 Gbps lines

  3. Microbial activity and soil organic matter decay in roadside soils polluted with petroleum hydrocarbons

    NASA Astrophysics Data System (ADS)

    Mykhailova, Larysa; Fischer, Thomas; Iurchenko, Valentina

    2015-04-01

    positively correlated with the carbohydrate fraction and negatively correlated with the aliphatic fraction of the soil C, while carbohydrate-C and alkyl-C increased and decreased with distance from the road, respectively. It is proposed that petroleum hydrocarbons supress soil biological activity at concentrations above 1500 mg kg-1, and that soil organic matter priming primarily affects the carbohydrate fraction of soil organic matter. It can be concluded that the abundance of solid carbohydrates (O-alkyl C) is of paramount importance for the hydrocarbon mineralization under natural conditions, compared to more recalcitrant SOM fractions (mainly aromatic and alkyl C). References Mykhailova, L., Fischer, T., Iurchenko, V. (2013) Distribution and fractional composition of petroleum hydrocarbons in roadside soils. Applied and Environmental Soil Science, vol. 2013, Article ID 938703, 6 pages, DOI 10.1155/2013/938703 Mykhailova, L., Fischer, T., Iurchenko, V. (2014) Deposition of petroleum hydrocarbons with sediment trapped in snow in roadside areas. Journal of Environmental Engineering and Landscape Management 22(3):237-244, DOI 10.3846/16486897.2014.889698 Nelson P.N. and Baldock J.A. (2005) Estimating the molecular composition of a diverse range of natural organic materials from solid-state 13C NMR and elemental analyses, 2005, Biogeochemistry (2005) 72: 1-34, DOI 10.1007/s10533-004-0076-3 Zyakun, A., Nii-Annang, S., Franke, G., Fischer, T., Buegger, F., Dilly, O. (2011) Microbial Actvity and 13C/12C Ratio as Evidence of N-Hexadecane and N-Hexadecanoic Acid Biodegradation in Agricultural and Forest Soils. Geomicrobiology Journal 28:632-647, DOI 10.1080/01490451.2010.489922

  4. Spectroscopic aperture biases in inside-out evolving early-type galaxies from CALIFA

    NASA Astrophysics Data System (ADS)

    Gomes, J. M.; Papaderos, P.; Vílchez, J. M.; Kehrig, C.; Iglesias-Páramo, J.; Breda, I.; Lehnert, M. D.; Sánchez, S. F.; Ziegler, B.; Dos Reis, S. N.; Bland-Hawthorn, J.; Galbany, L.; Bomans, D. J.; Rosales-Ortega, F. F.; Walcher, C. J.; García-Benito, R.; Márquez, I.; Del Olmo, A.; Mollá, M.; Marino, R. A.; Catalán-Torrecilla, C.; González Delgado, R. M.; López-Sánchez, Á. R.; Califa Collaboration

    2016-02-01

    Integral field spectroscopy (IFS) studies based on CALIFA survey data have recently revealed ongoing low-level star formation (SF) in the periphery of a small fraction (~10%) of local early-type galaxies (ETGs), witnessing a still ongoing inside-out galaxy growth process. A distinctive property of the nebular component in these ETGs, classified I+, is a structure with two radial zones, the inner of which displays LINER emission with a Hα equivalent width EW(Hα) ≃ 1 Å, the outer (3 Å Nii]/Hα vs. [Oiii]/Hβ emission-line (BPT) ratios consists of a monotonic shift upward and to the right precisely along the upper right wing of the "seagull" distribution on the BPT plane, that is, along the pathway connecting composite SF/Hii galaxies with AGN/LINERs. Motivated by these observational insights, we also investigate theoretically observational biases in aperture-limited studies of inside-out growing galaxies as a function of z. To this end, we devise a simple 1D model that involves an outward-propagating exponentially decreasing SF process since z ~ 10 and reproduces the radial extent and two-zone EW

  5. Spectral properties of X-ray selected narrow emission line galaxies

    NASA Astrophysics Data System (ADS)

    Romero-Colmenero, E.

    1998-03-01

    constitute it. Furthermore, by combining both samples of NELGs, I find a tendency for sources at lower fluxes to display harder slopes (95% confidence level), further strengthening the case for NELGs to be major contributors to the XRB at the fainter fluxes. The analysis of optical spectroscopy, obtained on La Palma and Hawaii, shows that NELGs form a very heterogeneous group, made up of a mixture of Seyfert 2, LINER and HII-region like galaxies. Seyfert 2 galaxies are found to possess in general the steepest X-ray slopes. Ways to explain this in the context of the unified model of AGN are discussed. The FWHM of some emission lines (Halpha, Hbeta, [NII]) in the NELGs appears to increase with steepening X-ray spectral slope. In the case of the Balmer lines, this is at variance with what is observed in broad line AGN. The FWHM of the Balmer lines is also correlated to the FWHM of the forbidden lines, indicating that they must originate in regions of similar velocity fields. Unfortunately, the number of sources uniquely classified is not sufficient to investigate these relationships on a source type basis. The optical emission line ratios of a bright RIXOS source (aka Arp 185, NGC 6217), classified as a starburst galaxy in the literature, indicate that this is in fact a weak-[OI] LINER, powered either by emission from hot O stars or by hot stars together with a non-stellar continuum. Spatially resolved spectroscopic analysis suggests that the Balmer emission lines are concentrated in the inner regions of the nucleus, while the forbidden lines arise from a more extended region. Line ratios do not indicate a change in the ionizing continuum of this source with distance from the centre.

  6. National Security Science and Technology Initiative: Air Cargo Screening

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bingham, Philip R; White, Tim; Cespedes, Ernesto

    The non-intrusive inspection (NII) of consolidated air cargo carried on commercial passenger aircraft continues to be a technically challenging, high-priority requirement of the Department of Homeland Security's Science and Technology Directorate (DHS S&T), the Transportation Security Agency and the Federal Aviation Administration. The goal of deploying a screening system that can reliably and cost-effectively detect explosive threats in consolidated cargo without adversely affecting the flow of commerce will require significant technical advances that will take years to develop. To address this critical National Security need, the Battelle Memorial Institute (Battelle), under a Cooperative Research and Development Agreement (CRADA) with fourmore » of its associated US Department of Energy (DOE) National Laboratories (Oak Ridge, Pacific Northwest, Idaho, and Brookhaven), conducted a research and development initiative focused on identifying, evaluating, and integrating technologies for screening consolidated air cargo for the presence of explosive threats. Battelle invested $8.5M of internal research and development funds during fiscal years 2007 through 2009. The primary results of this effort are described in this document and can be summarized as follows: (1) Completed a gap analysis that identified threat signatures and observables, candidate technologies for detection, their current state of development, and provided recommendations for improvements to meet air cargo screening requirements. (2) Defined a Commodity/Threat/Detection matrix that focuses modeling and experimental efforts, identifies technology gaps and game-changing opportunities, and provides a means of summarizing current and emerging capabilities. (3) Defined key properties (e.g., elemental composition, average density, effective atomic weight) for basic commodity and explosive benchmarks, developed virtual models of the physical distributions (pallets) of three commodity types and three

  7. The Influence Of Environment On The Star Formation Properties Of Galaxies

    NASA Astrophysics Data System (ADS)

    Rodriguez Del Pino, Bruno

    2015-10-01

    star formation properties and nuclear activity in galaxies in a multi-cluster system at z 0.165. We employ Tuneable Filter observations to map the Halpha and N[II] emission lines. We show the feasibility and advantages of using these type of observations to map emission lines in a large number of objects at a single redshift, and developed a procedure for the reduction and analysis of the data. We find a large number of optical AGN that were not previously detected as X-ray point sources. The probability that a galaxy hosts an AGN is not found to correlate with environment. From the analysis of the integrated star formation properties of the galaxies in the multi-cluster system we observe a significant number of galaxies with suppressed star formation with respect to the field. Although stellar mass is the main driver of the suppression of star formation, once its effect is removed, we find that galaxies in the core regions have reduced specific star formation rates (SSFRs) with respect to the infall regions. Moreover, the environment influences galaxies differently depending on their stellar mass. Galaxies with low masses experience a change in morphology (from irregulars and spirals to early-types) and colour (blue to red) as they fall into regions of higher density. However, many massive spiral galaxies retain their disk morphologies and the visibility of their spiral arms all the way to the core regions. Before becoming passive, these galaxies experience a phase exhibiting red colours and relatively high SSFRs. A significant fraction of the spiral galaxies with relatively high masses go through this phase, which could represent the transition towards becoming S0s. We finish by presenting some interesting results on the spatial distribution of the emission-line regions in the cluster galaxies. We develop a method to create emission-line images, which successfully preserves the flux within the emission lines. Our analysis on the concentrations and sizes of the star